WorldWideScience

Sample records for off-gas performance test

  1. Off gas condenser performance modelling

    A suite of three programmes has been developed to model the ruthenium decontamination performance of a vitrification plant off-gas condenser. The stages of the model are: condensation of water vapour, NOx absorption in the condensate, RuO4 absorption in the condensate. Juxtaposition of these stages gives a package that may be run on an IBM-compatible desktop PC. Experimental work indicates that the criterion [HNO2] > 10 [RuO4] used to determine RuO4 destruction in solution is probably realistic under condenser conditions. Vapour pressures of RuO4 over aqueous solutions at 70o-90oC are slightly lower than the values given by extrapolating the ln Kp vs. T-1 relation derived from lower temperature data. (author)

  2. ART CCIM Phase II-A Off-Gas System Evaluation Test Plan

    Nick Soelberg; Jay Roach

    2009-01-01

    This test plan defines testing to be performed using the Idaho National Laboratory (INL) engineering-scale cold crucible induction melter (CCIM) test system for Phase II-A of the Advanced Remediation Technologies (ART) CCIM Project. The multi-phase ART-CCIM Project is developing a conceptual design for replacing the joule-heated melter (JHM) used to treat high level waste (HLW) in the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) with a cold crucible induction melter. The INL CCIM test system includes all feed, melter off-gas control, and process control subsystems needed for fully integrated operation and testing. Testing will include operation of the melter system while feeding a non-radioactive slurry mixture prepared to simulate the same type of waste feed presently being processed in the DWPF. Process monitoring and sample collection and analysis will be used to characterize the off-gas composition and properties, and to show the fate of feed constituents, to provide data that shows how the CCIM retrofit conceptual design can operate with the existing DWPF off-gas control system.

  3. Test results from the GA Technologies engineering-scale off-gas treatment system

    Test results are available from the GA Technologies (GA) off-gas treatment facilities using gas streams from both the graphite fuel element burner system and from the spent fuel dissolver. The off-gas system is part of a pilot plant for development of processes for treating spent fuel from high temperature gas-cooled reactors (HTGRs). One method for reducing the volume of HTGR fuel prior to reprocessing or spent fuel storage is to crush and burn the graphite fuel elements. The burner off-gas (BOG) contains radioactive components, principally H-3, C-14, Kr-85, I-129, and Rn-220, as well as chemical forms such as CO2, CO, O2, and SO2. The BOG system employs components designed to remove these constituents. Test results are reported for the iodine and SO2 adsorbers and the CO/HT oxidizer. Integrated testing of major BOG system components confirmed the performance of units evaluated in individual tests. Design decontamination and conversion factors were maintained for up to 72 h. In a reprocessing flowsheet, the solid product from the burners is dissolved in nitric or Thorex acid. The dissolver off-gas (DOG) contains radioactive components H-3, Kr-85, I-129, Rn-220 plus chemical forms such as nitrogen oxides (NO/sub x/). In the pilot-scale system iodine is removed from the DOG by adsorption. Tests of iodine removal have been conducted using either silver-exchanged mordenite (AgZ) or AgNO3-impregnated silica gel (AC-6120). Although each sorbent performed well in the presence of NO/sub x/, the silica gel adsorbent proved more efficient in silver utilization and, thus, more cost effective

  4. Development of high performance catalyst for off-gas treatment system in BWR

    A high performance catalyst for off-gas treatment system in boiling water reactor (BWR) has been developed. The hydrogen concentration in the outlets of off-gas recombiners increased at several BWR plants in Japan. These phenomena were caused by deactivation of catalysts for the recombiners, and we assumed two types of deactivation mechanisms. The first cause was an increase of the amount of boehmite in the catalyst support due to alternation of the manufacturing process. The other cause was catalysts being poisoned by cyclic siloxanes that were introduced from the silicone sealant used in the upstream of the off-gas recombiners. The catalysts were manufactured by Pt adhering on alumina support. The conventional catalyst (CAT-A) used the aqueous solution of the chloroplatinic acid for adhesion of Pt. A dechlorination process by autoclave was applied to prevent the equipment at the downstream of the recombiners from stress corrosion cracking, but this process caused the support material to transform into boehmite. The boehmite-rich catalysts were deactivated more easily by organic silicon than gamma alumina-rich catalysts. Therefore, the CAT-A was replaced at many Japanese BWR plants by the improved catalyst (CAT-B), and their support was transformed into more stable gamma alumina by heating at 500degC. However, the siloxanes keep being detected in the off-gas though the source of siloxane had been removed and there still remain possibilities to deactivate the catalysts. Therefore, we have been developing high performance catalyst (CAT-C) that has higher activity and durability against poisoning. We investigated the properties of CAT-C by performance tests and instrumental analyses. The dependency of thermal output of nuclear reactor, and durability against siloxane poisoning were investigated. We found that CAT-C showed higher performance and better properties than CAT-B did. Moreover, we have been developing a modeling method to evaluate the hydrogen recombination

  5. ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT

    Nick Soelberg

    2009-04-01

    AREVA Federal Services (AFS) is performing a multi-year, multi-phase Advanced Remediation Technologies (ART) project, sponsored by the U.S. Department of Energy (DOE), to evaluate the feasibility and benefits of replacing the existing joule-heated melter (JHM) used to treat high level waste (HLW) in the Defense Waste Processing Facility (DWPF) at the Savannah River Site with a cold crucible induction melter (CCIM). The AFS ART CCIM project includes several collaborators from AREVA subsidiaries, French companies, and DOE national laboratories. The Savannah River National Laboratory and the Commissariat a l’Energie Atomique (CEA) have performed laboratory-scale studies and testing to determine a suitable, high-waste-loading glass matrix. The Idaho National Laboratory (INL) and CEA are performing CCIM demonstrations at two different pilot scales to assess CCIM design and operation for treating SRS sludge wastes that are currently being treated in the DWPF. SGN is performing engineering studies to validate the feasibility of retrofitting CCIM technology into the DWPF Melter Cell. The long-term project plan includes more lab-testing, pilot- and large-scale demonstrations, and engineering activities to be performed during subsequent project phases. A simulant of the DWPF SB4 feed was successfully fed and melted in a small pilot-scale CCIM system during two test series. The OGSE tests provide initial results that (a) provide melter operating conditions while feeding a DWPF SB4 simulant feed, (b) determine the fate of feed organic and metal feed constituents and metals partitioning, and (c) characterize the melter off-gas source term to a downstream off-gas system. The INL CCIM test system was operated continuously for about 30 hours during the parametric test series, and for about 58 hours during the OGSE test. As the DWPF simulant feed was continuously fed to the melter, the glass level gradually increased until a portion of the molten glass was drained from the melter

  6. Test results from the GA technologies engineering-scale off-gas treatment system

    One method for reducing the volume of HTGR fuel prior to reprocessing or spent fuel storage is to crush and burn the graphite fuel elements. The burner off-gas (BOG) contains radioactive components, principally H-3, C-14, Kr-85, I-129, and Rn-220, as well as chemical forms such as CO2, CO, O2, and SO2. The BOG system employs components designed to remove these constitutents. Test results are reported for the iodine and SO2 adsorbers and the CO/HT oxidizer. Silver-based iodine adsorbents were found to catalyze the premature conversion of CO to CO2. Subsequent tests showed that iodine removal could not be performed downstream of the CO/HT oxidizer since iodine in the BOG system rapidly deactivated the Pt-coated alumina CO catalyst. Lead-exchanged zeolite (PbX) was found to be an acceptable alternative for removing iodine from BOG without CO conversion. Intermittent and steady-state tests of the pilot-plant SO2 removal unit containing sodium-exchanged zeolite (NaX) demonstrated that decontamination factors greater than or equal to 100 could be maintained for up to 50 h. In a reprocessing flowsheet, the solid product from the burners is dissolved in nitric or Thorex acid. The dissolver off-gas (DOG) contains radioactive components H-3, Kr-85, I-129, Rn-220 plus chemical forms such as nitrogen oxides (NO/sub x/). In the pilot-scale system at GA, iodine is removed from the DOG by adsorption. Tests of iodine removal have been conducted using either silver-exchanged mordenite (AgZ) or AgNO3-impregnated silica gel (AC-6120). Although each sorbent performed well in the presence of NO/sub x/, the silica gel adsorbent proved more efficient in silver utilization and, thus, more cost effective

  7. Test results in the treatment of HTR reprocessing off-gas

    The AKUT II-facility (throughput 10 m3/h, STP) for the clean up of the burner off-gas has been tested with synthetic off-gas and with off-gas from cold burner tests. The results are reported. During dissolution of the burner ash in nitric acid an off-gas is formed whose main component is air and which, besides the gaseous fission products, contains NO/sub x/. Before the separation of the gaseous fission products NO/sub x/ and/or O2 are removed by reaction with H2 or NH3. For these reactions catalysts were used. Because of the known disadvantages of catalytic systems, like reduction in efficiency by poisoning or thermal influence, the alternative method of thermal, flameless reduction was tested. The reactions were carried out in a stainless steel and a quartz reactor. Throughput, reaction temperature, O2-, NO/sub x/-, H2-, and NH3-concentrations respectively were varied. The goal of these tests was to remove O2 and NO/sub x/ to below 1 ppM behind the reactor and NH3 to below the detection limit of 50 ppM. It was found that at a reaction temperature of 7500C in the stainless steel reactor these goals can be reached for both H2 and NH3 as reducing agents. In the quartz reactor only the O2-H2-reaction takes place. Obviously stainless steel acts as a catalyst for all other reactions

  8. Off-gas treatment and characterization for a radioactive in situ vitrification test

    Effluents released to the off gas during the in situ vitrification (ISV) of a test site have been characterized. The site consisted of a 19 L waste package of soil containing 600 nCi/g transuranic and 30,000 nCi/g mixed fission products surrounded by uncontaminated soil. Radioactive isotopes present in the package were 241Am, /sup 238/239/Pu, 137Cs, 106Ru, 90Sr, and 60Co. The ISV process melted the waste package and surrounding soil and immobilized the radionuclides in place, producing a durable, 8.6 metric ton glass and crystalline monolith. The test successfully demonstrated that the process provides containment of radioactive material. No release to the environment was detected during processing or cooldown. Due to the high temperatures during processing, some gases were released into the off-gas hood that was placed over the test site. The hood was maintained at a light negative pressure to contain any volatile or entrained material during processing. Gases passed from the hood to an off-gas treatment system where they were treated using a venturi-ejector scrubber, a tandem nozzle gas cleaner scrubber followed by a condenser, heater, and two stages of HEPA filters. The off-gas treatment system is located in the semi-trailer to allow transport of the process to other potential test sites. Retention of all radionuclides by the vitrified zone was greater than 99%. Soil-to-off-gas decontamination factors (DFs) for transuranic elements averaged greater than 4000 and for fission products, DFs ranged from 130 for 137Cs to 3100 for 90Sr

  9. Off-gas treatment and characterization for a radioactive in situ vitrification test

    Effluents released to the off gas during the in situ vitrification (ISV) of a test site have been characterized by Pacific Northwest Laboratory. The site consisted of a 19 L waste package of soil containing 600 nCi/g transuranic and 30,000 nCi/g mixed fission products surrounded by uncontaminated soil. Radioactive isotopes present in the package were 241Am, 238/239Pu, 137Cs, 106Ru, 90Sr, and 60Co. The ISV process melted the waste package and surrounding soil and immobilized the radionuclides in place, producing a durable, 8.6 metric ton glass and crystalline monolith. The test successfully demonstrated that the process provides containment of radioactive material. No release to the environment was detected during processing of cooldown. Due to the high temperature during processing, some gases were released into the off-gas hood that was over the test site. The hood was maintained at a slight negative pressure to contain any volatile or entrained material during processing. Gases passed from the hood to an off-gas treatment system where they were treated using a venturi-ejector scrubber, a tandem nozzle gas cleaner scrubber followed by a condenser, heater, and two stages of HEPA filters. The off-gas treatment system is located in the semi-trailer to allow transport of the process to other potential test sites. Retention of all radionuclides by the vitrified zone was greater than 99%. Soil-to-off-gas decontamination factors (DFs) for transuranic elements averaged greater than 4000 and for fission products, DFs ranged from 130 for 137Cs to 3100 for 90Sr. 7 references, 15 figures, 4 tables

  10. Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    Adamson, Duane J.; Nash, Charles A.; McCabe, Daniel J.; Crawford, Charles L.; Wilmarth, William R.

    2014-01-27

    (chloride, fluoride, sulfur), will have high ammonia, and will contain carryover particulates of glass-former chemicals. These species have potential to cause corrosion of tanks and equipment, precipitation of solids, release of ammonia gas vapors, and scale in the tank farm evaporator. Routing this stream to the tank farms does not permanently divert it from recycling into the WTP, only temporarily stores it prior to reprocessing. Testing is normally performed to demonstrate acceptable conditions and limits for these compounds in wastes sent to the tank farms. The primary parameter of this phase of the test program was measuring the formation of solids during evaporation in order to assess the compatibility of the stream with the evaporator and transfer and storage equipment. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW facility melter offgas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet, and, thus, the composition will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. This report discusses results of evaporation testing of the simulant. Two conditions were tested, one with the simulant at near neutral pH, and a second at alkaline pH. The neutral pH test is comparable to the conditions in the Hanford Effluent Treatment Facility (ETF) evaporator, although that evaporator operates at near atmospheric pressure and tests were done under vacuum. For the alkaline test, the target pH was based on the tank farm corrosion control program requirements, and the test protocol and equipment was comparable to that

  11. Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    (chloride, fluoride, sulfur), will have high ammonia, and will contain carryover particulates of glass-former chemicals. These species have potential to cause corrosion of tanks and equipment, precipitation of solids, release of ammonia gas vapors, and scale in the tank farm evaporator. Routing this stream to the tank farms does not permanently divert it from recycling into the WTP, only temporarily stores it prior to reprocessing. Testing is normally performed to demonstrate acceptable conditions and limits for these compounds in wastes sent to the tank farms. The primary parameter of this phase of the test program was measuring the formation of solids during evaporation in order to assess the compatibility of the stream with the evaporator and transfer and storage equipment. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW facility melter offgas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet, and, thus, the composition will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. This report discusses results of evaporation testing of the simulant. Two conditions were tested, one with the simulant at near neutral pH, and a second at alkaline pH. The neutral pH test is comparable to the conditions in the Hanford Effluent Treatment Facility (ETF) evaporator, although that evaporator operates at near atmospheric pressure and tests were done under vacuum. For the alkaline test, the target pH was based on the tank farm corrosion control program requirements, and the test protocol and equipment was comparable to that

  12. Design, Fabrication, and Shakeout Testing of ATALANTE Dissolver Off-Gas Sorbent-Based Capture System

    Walker, Jr, Joseph Franklin [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jubin, Robert Thomas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jordan, Jacob A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Bruffey, Stephanie H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-07-31

    A sorbent-based capture system designed for integration into the existing dissolver off-gas (DOG) treatment system at the ATelier Alpha et Laboratoires pour ANalyses, Transuraniens et Etudes de retraitement (ATALANTE) facility has been successfully designed and fabricated and has undergone shakeout testing. Discussions with personnel from the ATALANTE facility provided guidance that was used for the design. All components for this system were specified, procured, and received on site at Oak Ridge National Laboratory (ORNL). The system was then fabricated and tested at ORNL to verify operation. Shakeout testing resulted in a simplified system. This system should be easily installed into the existing facility and should be straightforward to operate during future experimental testing. All parts were selected to be compatible with ATALANTE power supplies, space requirements, and the existing DOG treatment system. Additionally, the system was demonstrated to meet all of four design requirements. These include (1) a dissolver off-gas flow rate of ≤100 L/h (1.67 L/min), (2) an external temperature of ≤50°C for all system components placed in the hot cell, (3) a sorbent bed temperature of ~150°C, and (4) a gas temperature of ~150°C upon entry into the sorbent bed. The system will be ready for shipment and installation in the existing DOG treatment system at ATALANTE in FY 2016.

  13. Development and testing of prototype alpha waste incinerator off-gas systems

    A test program is in progress at Savannah River Laboratory (SRL) to confirm and develop incinerator design technology for an SRP production Alpha Waste Incinerator (AWI) to be built in the mid-1980's. The Incinerator Components Test Facility (ICTF) is a full-scale (5 kg/h), electrically heated, controlled-air prototype incinerator built to burn nonradioactive solid waste. The incinerator has been operating successfully at SRL since March 1979 and has met or exceeded all design criteria. During the first 1-1/2 years of operation, liquid scrubbers were used to remove particulates and hydrochloric acid from the incinerator exhaust gases. A dry off-gas system is currently being tested to provide data to Savannah River Plant's proposed AWI

  14. Interim report on testing of off-gas treatment technologies for abatement of atmospheric emissions of chlorinated volatile organic compounds

    Haselow, J.S.; Jarosch, T.R.; Rossabi, J.; Burdick, S.; Lombard, K.

    1993-12-01

    The purpose of this report is to briefly summarize the results to date of the off-gas treatment program for atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program is part of the Department of Energy`s Office of Technology Development`s Integrated Demonstration for Treatment of Organics in Soil and Water at a Non-Arid Site. The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed. That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment program would complement the Integrated Demonstration not only because off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the US to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate systematic and unbiased evaluation of the emerging technologies.

  15. Interim report on testing of off-gas treatment technologies for abatement of atmospheric emissions of chlorinated volatile organic compounds

    The purpose of this report is to briefly summarize the results to date of the off-gas treatment program for atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program is part of the Department of Energy's Office of Technology Development's Integrated Demonstration for Treatment of Organics in Soil and Water at a Non-Arid Site. The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed. That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment program would complement the Integrated Demonstration not only because off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the US to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate systematic and unbiased evaluation of the emerging technologies

  16. Final Report on Testing of Off-Gas Treatment Technologies for Abatement of Atmospheric Emissions of Chlorinated Volatile Organic Compounds

    The purpose of this report is to summarize the results of the program for off-gas treatment of atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program was funded through the Department of Energy Office of Technology Development's VOC's in Non-Arid Soils Integrated Demonstration (VNID). The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed (Looney et al., 1991). That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the United States to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate cost effective evaluation of the emerging technologies. Another motivation for the program is that many CVOCs will be regulated under the Clean Air Act Amendments of 1990 and are already regulated by many state regulatory programs. Additionally, compounds such as TCE and PCE are pervasive subsurface environmental contaminants, and, as a result, a small improvement in terms of abatement efficiency or cost will significantly reduce CVOC discharges to the environment as well as costs to United States government and industry

  17. Laboratory Scoping Tests Of Decontamination Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    Taylor-Pashow, Kathryn M.; Nash, Charles A.; Crawford, Charles L.; McCabe, Daniel J.; Wilmarth, William R.

    2014-01-21

    compatible with longterm tank storage and immobilization methods. For this new application, testing is needed to demonstrate acceptable treatment sorbents and precipitating agents and measure decontamination factors for additional radionuclides in this unique waste stream. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet and will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. One of the radionuclides that is volatile and expected to be in high concentration in this LAW Off-Gas Condensate stream is Technetium-99 ({sup 99}Tc). Technetium will not be removed from the aqueous waste in the Hanford WTP, and will primarily end up immobilized in the LAW glass by repeated recycle of the off-gas condensate into the LAW melter. Other radionuclides that are also expected to be in appreciable concentration in the LAW Off-Gas Condensate are {sup 129}I, {sup 90}Sr, {sup 137}Cs, and {sup 241}Am. This report discusses results of preliminary radionuclide decontamination testing of the simulant. Testing examined use of Monosodium Titanate (MST) to remove {sup 90}Sr and actinides, inorganic reducing agents for {sup 99}Tc, and zeolites for {sup 137}Cs. Test results indicate that excellent removal of {sup 99}Tc was achieved using Sn(II)Cl{sub 2} as a reductant, coupled with sorption onto hydroxyapatite, even in the presence of air and at room temperature. This process was very effective at neutral pH, with a Decontamination Factor (DF) >577 in two hours. It was less

  18. Laboratory Scoping Tests Of Decontamination Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    compatible with longterm tank storage and immobilization methods. For this new application, testing is needed to demonstrate acceptable treatment sorbents and precipitating agents and measure decontamination factors for additional radionuclides in this unique waste stream. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet and will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. One of the radionuclides that is volatile and expected to be in high concentration in this LAW Off-Gas Condensate stream is Technetium-99 (99Tc). Technetium will not be removed from the aqueous waste in the Hanford WTP, and will primarily end up immobilized in the LAW glass by repeated recycle of the off-gas condensate into the LAW melter. Other radionuclides that are also expected to be in appreciable concentration in the LAW Off-Gas Condensate are 129I, 90Sr, 137Cs, and 241Am. This report discusses results of preliminary radionuclide decontamination testing of the simulant. Testing examined use of Monosodium Titanate (MST) to remove 90Sr and actinides, inorganic reducing agents for 99Tc, and zeolites for 137Cs. Test results indicate that excellent removal of 99Tc was achieved using Sn(II)Cl2 as a reductant, coupled with sorption onto hydroxyapatite, even in the presence of air and at room temperature. This process was very effective at neutral pH, with a Decontamination Factor (DF) >577 in two hours. It was less effective at alkaline pH. Conversely, removal of the cesium

  19. Removal efficiency of silver impregnated filter materials and performance of iodie filters in the off-gas of the Karlsruhe reprocessing plant WAK

    Herrmann, F.J.; Herrmann, B.; Hoeflich, V. [Wiederaufarbeitungsanlage Karlsruhe (Germany)] [and others

    1997-08-01

    An almost quantitative retention of iodine is required in reprocessing plants. For the iodine removal in the off-gas streams of a reprocessing plant various sorption materials had been tested under realistic conditions in the Karlsruhe reprocessing plant WAK in cooperation with the Karlsruhe research center FZK. The laboratory results achieved with different iodine sorption materials justified long time performance tests in the WAK Plant. Technical iodine filters and sorption materials for measurements of iodine had been tested from 1972 through 1992. This paper gives an overview over the most important results, Extended laboratory, pilot plant, hot cell and plant experiences have been performed concerning the behavior and the distribution of iodine-129 in chemical processing plants. In a conventional reprocessing plant for power reactor fuel, the bulk of iodine-129 and iodine-127 is evolved into the dissolver off-gas. The remainder is dispersed over many aqueous, organic and gaseous process and waste streams of the plant. Iodine filters with silver nitrate impregnated silica were installed in the dissolver off-gas of the Karlsruhe reprocessing plant WAK in 1975 and in two vessel vent systems in 1988. The aim of the Karlsruhe iodine research program was an almost quantitative evolution of the iodine during the dissolution process to remove as much iodine with the solid bed filters as possible. After shut down of the WAK plant in December 1990 the removal efficiency of the iodine filters at low iodine concentrations had been investigated during the following years. 12 refs., 2 figs., 2 tabs.

  20. LABORATORY OPTIMIZATION TESTS OF TECHNETIUM DECONTAMINATION OF HANFORD WASTE TREATMENT PLANT LOW ACTIVITY WASTE OFF-GAS CONDENSATE SIMULANT

    Taylor-Pashow, K.; Nash, C.; McCabe, D.

    2014-09-29

    compatible with longterm tank storage and immobilization methods. For this new application, testing is needed to demonstrate acceptable treatment sorbents and precipitating agents and measure decontamination factors for additional radionuclides in this unique waste stream. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet and will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. One of the radionuclides that is volatile and expected to be in greatest abundance in this LAW Off-Gas Condensate stream is Technetium-99 ({sup 99}Tc). Technetium will not be removed from the aqueous waste in the Hanford WTP, and will primarily end up immobilized in the LAW glass by repeated recycle of the off-gas condensate into the LAW melter. Other radionuclides that are low but are also expected to be in measurable concentration in the LAW Off-Gas Condensate are {sup 129}I, {sup 90}Sr, {sup 137}Cs, {sup 241}Pu, and {sup 241}Am. These are present due to their partial volatility and some entrainment in the off-gas system. This report discusses results of optimized {sup 99}Tc decontamination testing of the simulant. Testing examined use of inorganic reducing agents for {sup 99}Tc. Testing focused on minimizing the quantity of sorbents/reactants added, and minimizing mixing time to reach the decontamination targets in this simulant formulation. Stannous chloride and ferrous sulfate were tested as reducing agents to determine the minimum needed to convert soluble pertechnetate

  1. Development And Initial Testing Of Off-Gas Recycle Liquid From The WTP Low Activity Waste Vitrification Process - 14333

    The Waste Treatment and Immobilization Plant (WTP) process flow was designed to pre-treat feed from the Hanford tank farms, separate it into a High Level Waste (HLW) and Low Activity Waste (LAW) fraction and vitrify each fraction in separate facilities. Vitrification of the waste generates an aqueous condensate stream from the off-gas processes. This stream originates from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrospray Precipitator (WESP). Currently, the baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed into the LAW melter again. If the Pretreatment facility is not available, the baseline disposition pathway is not viable. Additionally, some components in the stream are volatile at melter temperatures, thereby accumulating to high concentrations in the scrubbed stream. It would be highly beneficial to divert this stream to an alternate disposition path to alleviate the close-coupled operation of the LAW vitrification and Pretreatment facilities, and to improve long-term throughput and efficiency of the WTP system. In order to determine an alternate disposition path for the LAW SBS/WESP Recycle stream, a range of options are being studied. A simulant of the LAW Off-Gas Condensate was developed, based on the projected composition of this stream, and comparison with pilot-scale testing. The primary radionuclide that vaporizes and accumulates in the stream is Tc-99, but small amounts of several other radionuclides are also projected to be present in this stream. The processes being investigated for managing this stream includes evaporation and radionuclide removal via precipitation and adsorption. During evaporation, it is of interest to investigate the formation of insoluble solids to avoid scaling and plugging of equipment. Key parameters for radionuclide removal include identifying effective precipitation or ion

  2. Development And Initial Testing Of Off-Gas Recycle Liquid From The WTP Low Activity Waste Vitrification Process - 14333

    McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.; Taylor-Pashow, Kathryn M.; Adamson, Duane J.; Crawford, Charles L.; Morse, Megan M.

    2014-01-07

    The Waste Treatment and Immobilization Plant (WTP) process flow was designed to pre-treat feed from the Hanford tank farms, separate it into a High Level Waste (HLW) and Low Activity Waste (LAW) fraction and vitrify each fraction in separate facilities. Vitrification of the waste generates an aqueous condensate stream from the off-gas processes. This stream originates from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrospray Precipitator (WESP). Currently, the baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed into the LAW melter again. If the Pretreatment facility is not available, the baseline disposition pathway is not viable. Additionally, some components in the stream are volatile at melter temperatures, thereby accumulating to high concentrations in the scrubbed stream. It would be highly beneficial to divert this stream to an alternate disposition path to alleviate the close-coupled operation of the LAW vitrification and Pretreatment facilities, and to improve long-term throughput and efficiency of the WTP system. In order to determine an alternate disposition path for the LAW SBS/WESP Recycle stream, a range of options are being studied. A simulant of the LAW Off-Gas Condensate was developed, based on the projected composition of this stream, and comparison with pilot-scale testing. The primary radionuclide that vaporizes and accumulates in the stream is Tc-99, but small amounts of several other radionuclides are also projected to be present in this stream. The processes being investigated for managing this stream includes evaporation and radionuclide removal via precipitation and adsorption. During evaporation, it is of interest to investigate the formation of insoluble solids to avoid scaling and plugging of equipment. Key parameters for radionuclide removal include identifying effective precipitation or ion

  3. TREATMENT TANK OFF-GAS TESTING FOR THE ENHANCED CHEMICAL CLEANING PROCESS

    Wiersma, B.

    2011-08-29

    The purpose of this activity was to provide a bounding estimate of the volume of hydrogen gas generated during Enhanced Chemical Cleaning (ECC) of residual sludge remaining in a Type I or Type II treatment tank as well as to provide results independent of the sludge volume in the waste tank to be cleaned. Previous testing to support Chemical Cleaning was based on a 20:1 oxalic acid to sludge ratio. Hydrogen gas evolution is the primary safety concern. Sealed vessel coupon tests were performed to estimate the hydrogen generation rate due to corrosion of carbon steel by 2.5 wt.% oxalic acid. These tests determined the maximum instantaneous hydrogen generation rate, the rate at which the generation rate decays, and the total hydrogen generated. These values were quantified based on a small scale methodology similar to the one described in WSRC-STI-2007-00209, Rev. 0. The measured rates support identified Safety Class functions. The tests were performed with ASTM A285 Grade C carbon steel coupons. Bounding conditions were determined for the solution environment. The oxalic acid concentration was 2.5 wt.% and the test temperature was 75 C. The test solution was agitated and contained no sludge simulant. Duplicate tests were performed and showed excellent reproducibility for the hydrogen generation rate and total hydrogen generated. The results showed that the hydrogen generation rate was initially high, but decayed rapidly within a couple of days. A statistical model was developed to predict the instantaneous hydrogen generation rate as a function of exposure time by combining both sets of data. An upper bound on the maximum hydrogen generation rate was determined from the upper 95% confidence limit. The upper bound confidence limit for the hydrogen generation rate is represented by the following equation. ln (G{sub v}) = -8.22-0.0584 t + 0.0002 t{sup 2}. This equation should be utilized to estimate the instantaneous hydrogen generation rate per unit surface area, G

  4. FINAL REPORT REGULATORY OFF GAS EMISSIONS TESTING ON THE DM1200 MELTER SYSTEM USING HLW AND LAW SIMULANTS VSL-05R5830-1 REV 0 10/31/05

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D' ANGELO NA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    The operational requirements for the River Protection Project - Waste Treatment Plant (RPP-WTP) Low Activity Waste (LAW) and High Level Waste (HLW) melter systems, together with the feed constituents, impose a number of challenges to the off-gas treatment system. The system must be robust from the standpoints of operational reliability and minimization of maintenance. The system must effectively control and remove a wide range of solid particulate matter, acid mists and gases, and organic constituents (including those arising from products of incomplete combustion of sugar and organics in the feed) to concentration levels below those imposed by regulatory requirements. The baseline design for the RPP-WTP LAW primary off-gas system includes a submerged bed scrubber (SBS), a wet electrostatic precipitator (WESP), and a high efficiency particulate air (HEPA) filter. The secondary off-gas system includes a sulfur-impregnated activated carbon bed (AC-S), a thermal catalytic oxidizer (TCO), a single-stage selective catalytic reduction NOx treatment system (SCR), and a packed-bed caustic scrubber (PBS). The baseline design for the RPP-WTP HLW primary off-gas system includes an SBS, a WESP, a high efficiency mist eliminator (HEME), and a HEPA filter. The HLW secondary off-gas system includes a sulfur-impregnated activated carbon bed, a silver mordenite bed, a TCO, and a single-stage SCR. The one-third scale HLW DM1200 Pilot Melter installed at the Vitreous State Laboratory (VSL) was equipped with a prototypical off-gas train to meet the needs for testing and confirmation of the performance of the baseline off-gas system design. Various modifications have been made to the DM1200 system as the details of the WTP design have evolved, including the installation of a silver mordenite column and an AC-S column for testing on a slipstream of the off-gas flow; the installation of a full-flow AC-S bed for the present tests was completed prior to initiation of testing. The DM1200

  5. Low-Level waste phase 1 melter testing off gas and mass balance evaluation

    Wilson, C.N.

    1996-06-28

    Commercially available melter technologies were tested during 1994-95 as part of a multiphase program to test candidate technologies for vitrification of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of Hanford Site tank wastes. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes were also tested. Various feed material samples, product glass samples, and process offgas streams were characterized to provide data for evaluation of process decontamination factors and material mass balances for each vitrification technology. This report describes the melter mass balance evaluations and results for six of the Phase 1 LLW melter vendor demonstration tests.

  6. Laboratory optimization tests of technetium decontamination of Hanford Waste Treatment Plant low activity waste melter off-gas condensate simulant

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable simplified operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste.

  7. Laboratory optimization tests of technetium decontamination of Hanford Waste Treatment Plant low activity waste melter off-gas condensate simulant

    Taylor-Pashow, Kathryn M.L. [Savannah River Site (SRS), Aiken, SC (United States); McCabe, Daniel J. [Savannah River Site (SRS), Aiken, SC (United States)

    2015-11-01

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable simplified operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste.

  8. Results of cleaning dissolver off-gas in the PASSAT prototype dissolver off-gas filter system

    For demonstration of an advanced dissolver off-gas cleaning system the new PASSAT filter system has been developed, set up under licensing conditions pertinent to industrial scale reprocessing facilities and commissioned for trial operation. Major components of the PASSAT off-gas cleaning system are the packed fiber mist eliminator with flushing capability (Brink filter) for initial removal of droplet and solid aerosols, which has been installed to extend the service life of HEPA filters, and the series connected iodine adsorption filters for optimum utilization of the iodine adsorption material, AC 6120. The tests performed so far and the experience accumulated in testing these remotely operated filter components under simulated dissolver off-gas conditions, are described and discussed

  9. FY'99 final report for the expedited technology demonstration project: demonstration test results for the MSO/off-gas and salt recycle system

    Molten Salt Oxidation (MSO) is a promising alternative to incineration for the treatment of a variety of organic wastes. Lawrence Livermore National Laboratory (LLNL) has prepared a facility in which an integrated pilot-scale MSO treatment system is being tested and demonstrated. The system consists of a MSO vessel with a dedicated off-gas treatment system, a salt recycle system, feed preparation equipment, and a ceramic final waste forms immobilization system. This integrated system was designed and engineered based on operational experience with an engineering-scale reactor unit and extensive laboratory development on salt recycle and final forms preparation. The MSO/off-gas system has been operational since December 1997. The salt recycle system and the ceramic final forms immobilization became operational in May 1998. In FY98, we have tested the MSO facility with various organic feeds, including chlorinated solvents, tributyl phosphate/kerosene, PCB-contaminated waste oils and solvents, booties, plastic pellets, ion exchange resins, activated carbon, radioactive-spiked organics, and well-characterized low-level liquid mixed wastes. MSO is shown to be a versatile technology for hazardous waste treatment and may be a solution to many waste disposal problems in DOE sites. The results of the demonstration conducted in FY98 has been reported [1]. In FY99 (October 1998 to April 1999) we conducted further testing in the MSO/off-gas system with ion exchange resins, two real waste specimens, activated carbon, and TNT-loaded activated carbon, both at regular feed rates and higher feed rates up to a superficial gas velocity of 1.75 ft/s. We also drained the salt three times (SR7, SR8, SR9) in FY99 and sent the spent salts to the salt recycle system for further processing. This report presents the results obtained from the demonstration of the MSO/off-gas system and the salt recycle system from October 1998 to April 1999. We then shut down the operation and cleaned the

  10. Method for freezing out xenon from the dissolver off-gas from fuel reprocessing plants

    A laboratory arrangement on the basis of an evaporator-type cryostatic temperature regulator with LN2 cooling has been developed to separate radioactive xenon impurities by freezing out from the dissolver off-gas from fuel reprocessing plants. This simple cryotrapping principle enables freezing out of xenon controlled only by temperature. This is confirmed by the results of extensive test performed with simulated dissolver off-gas mixes (having a xenon content <= 2 vol%). (orig./HP)

  11. Antifoam Degradation Products in Off Gas and Condensate of Sludge Batch 9 Simulant Nitric-Formic Flowsheet Testing for the Defense Waste Processing Facility

    Smith, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-04-14

    Ten chemical processing cell (CPC) experiments were performed using simulant to evaluate Sludge Batch 9 for sludge-only and coupled processing using the nitric-formic flowsheet in the Defense Waste Processing Facility (DWPF). Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) cycles were performed on eight of the ten. The other two were SRAT cycles only. Samples of the condensate, sludge, and off gas were taken to monitor the chemistry of the CPC experiments. The Savannah River National Laboratory (SRNL) has previously shown antifoam decomposes to form flammable organic products, (hexamethyldisiloxane (HMDSO), trimethylsilanol (TMS), and propanal), that are present in the vapor phase and condensate of the CPC vessels. To minimize antifoam degradation product formation, a new antifoam addition strategy was implemented at SRNL and DWPF to add antifoam undiluted.

  12. Laboratory Optimization Tests of Technetium Decontamination of Hanford Waste Treatment Plant Direct Feed Low Activity Waste Melter Off-Gas Condensate Simulant

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable less integrated operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste.

  13. Laboratory Optimization Tests of Technetium Decontamination of Hanford Waste Treatment Plant Direct Feed Low Activity Waste Melter Off-Gas Condensate Simulant

    Taylor-Pashow, K. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-12-23

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable less integrated operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste.

  14. Off-gas behavior in the Harvest pot vitrification process

    The conversion of highly radioactive waste liquor into glass by the pot vitrification process has been studied at Harwell using a full-scale inactive pilot plant. A summary of the off-gas behavior and its interpretation is presented. Experimental runs were carried out on 3 representative wastes (MAGNOX - thermal reactor, metal fuel, THORP - thermal oxide fuel and PFR - fast reactor oxide fuel) using 2 methods of feeding the glass-formers (slurry and crizzle). Materials were carried over from the vitrification vessel into the off-gas system by entrainment supplemented by volatilization. The overall behavior of the off-gas was consistent with the presence in it of 5 separate aerosols of particulate matter. Sources of entrainment gave rise to 3 aerosols, and a further 2 aerosols were formed as a result of chemical reaction (Ru) and condensation (Cs) processes involving the volatile species. Entrainment was enhanced when the feed contained free alkali nitrate. The Ru volatility correlated directly with the amount of salt nitrates in the feed. The off-gas equipment consisted of a condenser followed by two packed tower scrubbers. The variation in equipment performance between different sets of experiments could be attributed entirely to changes in the proportion of air present in the off-gas. The entrainment aerosols were the easiest to remove from the off-gas, whilst the Cs aerosol proved to the most difficult. The overall process decontamination factors of the pilot was about 2x104 for vapor-Ru, 2.5-5x103 for particulate-Ru, and 5x103-1x104 for Cs. Non-volatile fission products were about 103 better. These results emphasize the need for a high efficiency filter and a Ru vapor absorber in an off-gas system. (Auth.)

  15. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel

  16. Nuclear off-gas treatment...the cryogenic distillation method

    Instrumentation for the cryogenic distillation method of treating off-gas from a BWR nuclear power plant is described. A review of control valve reliability and leakage tests is presented. The design and testing of monitor and control analyzers to ensure process safety are considered, along with the seismic requirements applicable to all the instrumentation

  17. Performance tests.

    Wetherell, A

    1996-01-01

    This paper discusses the use of psychological performance tests to assess the effects of environmental stressors. The large number and the variety of performance tests are illustrated, and the differences between performance tests and other psychological tests are described in terms of their design, construction, use, and purpose. The stressor emphasis is on the effects of drugs since that is where most performance tests have found their main application, although other stressors, e.g., fatig...

  18. Hanford Low-Activity Waste Processing: Demonstration of the Off-Gas Recycle Flowsheet - 13443

    Vitrification of Hanford Low-Activity Waste (LAW) is nominally the thermal conversion and incorporation of sodium salts and radionuclides into borosilicate glass. One key radionuclide present in LAW is technetium-99. Technetium-99 is a low energy, long-lived beta emitting radionuclide present in the waste feed in concentrations on the order of 1-10 ppm. The long half-life combined with a high solubility in groundwater results in technetium-99 having considerable impact on performance modeling (as potential release to the environment) of both the waste glass and associated secondary waste products. The current Hanford Tank Waste Treatment and Immobilization Plant (WTP) process flowsheet calls for the recycle of vitrification process off-gas condensates to maximize the portion of technetium ultimately immobilized in the waste glass. This is required as technetium acts as a semi-volatile specie, i.e. considerable loss of the radionuclide to the process off-gas stream can occur during the vitrification process. To test the process flowsheet assumptions, a prototypic off-gas system with recycle capability was added to a laboratory melter (on the order of 1/200 scale) and testing performed. Key test goals included determination of the process mass balance for technetium, a non-radioactive surrogate (rhenium), and other soluble species (sulfate, halides, etc.) which are concentrated by recycling off-gas condensates. The studies performed are the initial demonstrations of process recycle for this type of liquid-fed melter system. This paper describes the process recycle system, the waste feeds processed, and experimental results. Comparisons between data gathered using process recycle and previous single pass melter testing as well as mathematical modeling simulations are also provided. (authors)

  19. Hanford Low-Activity Waste Processing: Demonstration of the Off-Gas Recycle Flowsheet - 13443

    Ramsey, William G.; Esparza, Brian P. [Washington River Protection Solutions, LLC, Richland, WA 99532 (United States)

    2013-07-01

    Vitrification of Hanford Low-Activity Waste (LAW) is nominally the thermal conversion and incorporation of sodium salts and radionuclides into borosilicate glass. One key radionuclide present in LAW is technetium-99. Technetium-99 is a low energy, long-lived beta emitting radionuclide present in the waste feed in concentrations on the order of 1-10 ppm. The long half-life combined with a high solubility in groundwater results in technetium-99 having considerable impact on performance modeling (as potential release to the environment) of both the waste glass and associated secondary waste products. The current Hanford Tank Waste Treatment and Immobilization Plant (WTP) process flowsheet calls for the recycle of vitrification process off-gas condensates to maximize the portion of technetium ultimately immobilized in the waste glass. This is required as technetium acts as a semi-volatile specie, i.e. considerable loss of the radionuclide to the process off-gas stream can occur during the vitrification process. To test the process flowsheet assumptions, a prototypic off-gas system with recycle capability was added to a laboratory melter (on the order of 1/200 scale) and testing performed. Key test goals included determination of the process mass balance for technetium, a non-radioactive surrogate (rhenium), and other soluble species (sulfate, halides, etc.) which are concentrated by recycling off-gas condensates. The studies performed are the initial demonstrations of process recycle for this type of liquid-fed melter system. This paper describes the process recycle system, the waste feeds processed, and experimental results. Comparisons between data gathered using process recycle and previous single pass melter testing as well as mathematical modeling simulations are also provided. (authors)

  20. CHARACTERIZATION OF DWPF MELTER OFF-GAS QUENCHER SAMPLE

    Newell, J.

    2011-11-14

    mixture of sludge and glass frit. The major component was Si along with Fe, Al, and other elements in the radioactive waste being processed. The deposits analyzed also contained U-235 fission products and actinide elements. Prior to that, deposits in the off-gas system in the DWPF nonradioactive half scale melter and the one-tenth scale integrated DWPF melter system were analyzed and determined to be mixtures of alkali rich chlorides, sulfates, borates, and fluorides entrained with iron oxides, spinels and frit particles formed by vapor-phase transport and condensation. Additional work was performed in 2007 in which researchers similarly found the deposits to be a combination of sludge and frit particles.

  1. Literature search for offsite data to improve the DWPF melter off-gas model

    Daniel, W.E.

    2000-05-04

    This report documents the literature search performed and any relevant data that may help relax some of the constraints on the DWPF melter off-gas model. The objective of this task was to look for outside sources of technical data to help reduce some of the conservatism built in the DWPF melter off-gas model.

  2. FY-12 INL KR CAPTURE ACTIVITIES SUPPORTING THE OFF-GAS SIGMA TEAM

    Troy G. Garn; Mitchell R. Greenhalgh; Jack D Law

    2012-08-01

    Tasks performed this year by INL Kr capture off-gas team members can be segregated into three separate task sub-sections which include: 1) The development and testing of a new engineered form sorbent, 2) An initial NDA gamma scan effort performed on the drum containing the Legacy Kr-85 sample materials, and 3) Collaborative research efforts with PNNL involving the testing of the Ni-DOBDC MOF and an initial attempt to make powdered chalcogel material into an engineered form using our binding process. This document describes the routes to success for the three task sub-sections.

  3. Technology of off-gas treatment for liquid-fed ceramic melters

    Scott, P.A.; Goles, R.W.; Peters, R.D.

    1985-05-01

    The technology for treating off gas from liquid-fed ceramic melters (LFCMs) has been under development at the Pacific Northwest Laboratory since 1977. This report presents the off-gas technology as developed at PNL and by others to establish a benchmark of development and to identify technical issues. Tests conducted on simulated (nonradioactive) wastes have provided data that allow estimation of melter off-gas composition for a given waste. Mechanisms controlling volatilization of radionuclides and noxious gases are postulated, and correlations between melter operation and emissions are presented. This report is directed to those familiar with LFCM operation. Off-gas treatment systems always require primary quench scrubbers, aerosol scrubbers, and final particulate filters. Depending on the composition of the off gas, equipment for removal of ruthenium, iodine, tritium, and noxious gases may also be needed. Nitrogen oxides are the most common noxious gases requiring treatment, and can be controlled by aqueous absorption or catalytic conversion with ammonia. High efficiency particulate air (HEPA) filters should be used for final filtration. The design criteria needed for an off-gas system can be derived from emission regulations and composition of the melter feed. Conservative values for melter off-gas composition can be specified by statistical treatment of reported off-gas data. Statistical evaluation can also be used to predict the frequency and magnitude of normal surge events that occur in the melter. 44 refs., 28 figs., 17 tabs.

  4. Technology of off-gas treatment for liquid-fed ceramic melters

    The technology for treating off gas from liquid-fed ceramic melters (LFCMs) has been under development at the Pacific Northwest Laboratory since 1977. This report presents the off-gas technology as developed at PNL and by others to establish a benchmark of development and to identify technical issues. Tests conducted on simulated (nonradioactive) wastes have provided data that allow estimation of melter off-gas composition for a given waste. Mechanisms controlling volatilization of radionuclides and noxious gases are postulated, and correlations between melter operation and emissions are presented. This report is directed to those familiar with LFCM operation. Off-gas treatment systems always require primary quench scrubbers, aerosol scrubbers, and final particulate filters. Depending on the composition of the off gas, equipment for removal of ruthenium, iodine, tritium, and noxious gases may also be needed. Nitrogen oxides are the most common noxious gases requiring treatment, and can be controlled by aqueous absorption or catalytic conversion with ammonia. High efficiency particulate air (HEPA) filters should be used for final filtration. The design criteria needed for an off-gas system can be derived from emission regulations and composition of the melter feed. Conservative values for melter off-gas composition can be specified by statistical treatment of reported off-gas data. Statistical evaluation can also be used to predict the frequency and magnitude of normal surge events that occur in the melter. 44 refs., 28 figs., 17 tabs

  5. Investigation of Discharge Performance of SOFC Using Biogas and Its Off-gas%生物气及其电池尾气 SOFC 放电性能研究

    王德震; 左薇; 张军; 吴晓燕; 孔晓伟

    2015-01-01

    To investigate the discharge performance of Ni-YSZ anode solid oxide fuel cell using various biogas and evaluate the valve of reusing its off-gas, electrochemical performance and gas properties were studied when two SOFC operated in tandem using diverse ratio of CH4/CO2 at 750 ℃. Compared with the cell performance using H2, two SOFC both operated at high power density with the first stage SOFC using various CH4/CO2 biogas and the second stage using the off-gas of the first stage. Both of two SOFC worked mostly steadily at constant current density for short time with little carbon deposition. The analysis of the gas properties at 566 mA•cm-2 indicated that the dry reforming rate was the highest when the ratio of CH4/CO2 was 2. The research results show that power generation of SOFC using biogas and its off-gas is feasible. This research can be useful for designing gas circuit of SOFC piles using biogas.%为探究以不同浓度生物气为燃料的固体氧化物燃料电池(SOFC)发电性能及该类电池尾气的再发电价值,通过模拟含不同比例甲烷和二氧化碳的生物气,在750℃下对气路串联 Ni/YSZ 阳极支撑 SOFC 进行放电性能测试和气体特性分析。放电结果显示燃料气经第一级 SOFC 利用后通入第二级 SOFC,同氢气经过两级 SOFC 相比,不同浓度下生物气均获得了较高的功率密度,且短时间恒流时,两级电池均能稳定运行;两级电池均以566 mA· cm-2电流密度恒流放电时的气体分析表明,当 CO2/CH4为2时,电池内甲烷的干重整率最高。研究结果表明两级 SOFC 使用生物气及其电池尾气发电是可行的,可为以生物气为燃料 SOFC 电堆气路设计提供依据。

  6. Processing device for volatile ruthenium in off-gas

    Volatile ruthenium has a nature of forming stable non-volatile ruthenium dioxide solids upon contact with an organic solvent. In view of the above, in a volatile ruthenium processing device comprising an off-gas inlet pipeway, a cooler, a demister and a heater connected to each other, a gas scrubbing tower having an organic solvent as a cleaning solution is disposed between the off-gas inlet pipeway and tahe cooler and the organic solvent and the off-gases are brought into contact in a counter-current manner in the gas scrubging tower. This enables to convert the volatile ruthenium in the gases into stabale ruthenium dioxide solids and deposit them into the organic solvent. Further, since the deposited ruthenium dioxide solides can easily be separated by filters, the organic solvent as the cleaning solution can always be kept clean and the adsorption performance for volatile ruthenium is not reduced even after repeating use. (T.M.)

  7. Sorption Modeling and Verification for Off-Gas Treatment

    Tavlarides, Lawrence L. [Syracuse Univ., NY (United States); Lin, Ronghong [Syracuse Univ., NY (United States); Nan, Yue [Syracuse Univ., NY (United States); Yiacoumi, Sotira [Georgia Inst. of Technology, Atlanta, GA (United States); Tsouris, Costas [Georgia Inst. of Technology, Atlanta, GA (United States); Ladshaw, Austin [Georgia Inst. of Technology, Atlanta, GA (United States); Sharma, Ketki [Georgia Inst. of Technology, Atlanta, GA (United States); Gabitto, Jorge [Prairie View A & M Univ., Prairie View, TX (United States); DePaoli, David [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-04-29

    The project has made progress toward developing a comprehensive modeling capability for the capture of target species in off gas evolved during the reprocessing of nuclear fuel. The effort has integrated experimentation, model development, and computer code development for adsorption and absorption processes. For adsorption, a modeling library has been initiated to include (a) equilibrium models for uptake of off-gas components by adsorbents, (b) mass transfer models to describe mass transfer to a particle, diffusion through the pores of the particle and adsorption on the active sites of the particle, and (c) interconnection of these models to fixed bed adsorption modeling which includes advection through the bed. For single-component equilibria, a Generalized Statistical Thermodynamic Adsorption (GSTA) code was developed to represent experimental data from a broad range of isotherm types; this is equivalent to a Langmuir isotherm in the two-parameter case, and was demonstrated for Kr on INL-engineered sorbent HZ PAN, water sorption on molecular sieve A sorbent material (MS3A), and Kr and Xe capture on metal-organic framework (MOF) materials. The GSTA isotherm was extended to multicomponent systems through application of a modified spreading pressure surface activity model and generalized predictive adsorbed solution theory; the result is the capability to estimate multicomponent adsorption equilibria from single-component isotherms. This advance, which enhances the capability to simulate systems related to off-gas treatment, has been demonstrated for a range of real-gas systems in the literature and is ready for testing with data currently being collected for multicomponent systems of interest, including iodine and water on MS3A. A diffusion kinetic model for sorbent pellets involving pore and surface diffusion as well as external mass transfer has been established, and a methodology was developed for determining unknown diffusivity parameters from transient

  8. Sorption Modeling and Verification for Off-Gas Treatment

    The project has made progress toward developing a comprehensive modeling capability for the capture of target species in off gas evolved during the reprocessing of nuclear fuel. The effort has integrated experimentation, model development, and computer code development for adsorption and absorption processes. For adsorption, a modeling library has been initiated to include (a) equilibrium models for uptake of off-gas components by adsorbents, (b) mass transfer models to describe mass transfer to a particle, diffusion through the pores of the particle and adsorption on the active sites of the particle, and (c) interconnection of these models to fixed bed adsorption modeling which includes advection through the bed. For single-component equilibria, a Generalized Statistical Thermodynamic Adsorption (GSTA) code was developed to represent experimental data from a broad range of isotherm types; this is equivalent to a Langmuir isotherm in the two-parameter case, and was demonstrated for Kr on INL-engineered sorbent HZ PAN, water sorption on molecular sieve A sorbent material (MS3A), and Kr and Xe capture on metal-organic framework (MOF) materials. The GSTA isotherm was extended to multicomponent systems through application of a modified spreading pressure surface activity model and generalized predictive adsorbed solution theory; the result is the capability to estimate multicomponent adsorption equilibria from single-component isotherms. This advance, which enhances the capability to simulate systems related to off-gas treatment, has been demonstrated for a range of real-gas systems in the literature and is ready for testing with data currently being collected for multicomponent systems of interest, including iodine and water on MS3A. A diffusion kinetic model for sorbent pellets involving pore and surface diffusion as well as external mass transfer has been established, and a methodology was developed for determining unknown diffusivity parameters from transient

  9. Adsorption Model for Off-Gas Separation

    The absence of industrial scale nuclear fuel reprocessing in the U.S. has precluded the necessary driver for developing the advanced simulation capability now prevalent in so many other countries. Thus, it is essential to model complex series of unit operations to simulate, understand, and predict inherent transient behavior and feedback loops. A capability of accurately simulating the dynamic behavior of advanced fuel cycle separation processes will provide substantial cost savings and many technical benefits. The specific fuel cycle separation process discussed in this report is the off-gas treatment system. The off-gas separation consists of a series of scrubbers and adsorption beds to capture constituents of interest. Dynamic models are being developed to simulate each unit operation involved so each unit operation can be used as a stand-alone model and in series with multiple others. Currently, an adsorption model has been developed in gPROMS software. Inputs include gas stream constituents, sorbent, and column properties, equilibrium and kinetic data, and inlet conditions. It models dispersed plug flow in a packed bed under non-isothermal and non-isobaric conditions for a multiple component gas stream. The simulation outputs component concentrations along the column length as a function of time from which the breakthrough data is obtained. It also outputs temperature along the column length as a function of time and pressure drop along the column length. Experimental data will be input into the adsorption model to develop a model specific for iodine adsorption on silver mordenite as well as model(s) specific for krypton and xenon adsorption. The model will be validated with experimental breakthrough curves. Another future off-gas modeling goal is to develop a model for the unit operation absorption. The off-gas models will be made available via the server or web for evaluation by customers.

  10. Adsorption Model for Off-Gas Separation

    Veronica J. Rutledge

    2011-03-01

    The absence of industrial scale nuclear fuel reprocessing in the U.S. has precluded the necessary driver for developing the advanced simulation capability now prevalent in so many other countries. Thus, it is essential to model complex series of unit operations to simulate, understand, and predict inherent transient behavior and feedback loops. A capability of accurately simulating the dynamic behavior of advanced fuel cycle separation processes will provide substantial cost savings and many technical benefits. The specific fuel cycle separation process discussed in this report is the off-gas treatment system. The off-gas separation consists of a series of scrubbers and adsorption beds to capture constituents of interest. Dynamic models are being developed to simulate each unit operation involved so each unit operation can be used as a stand-alone model and in series with multiple others. Currently, an adsorption model has been developed in gPROMS software. Inputs include gas stream constituents, sorbent, and column properties, equilibrium and kinetic data, and inlet conditions. It models dispersed plug flow in a packed bed under non-isothermal and non-isobaric conditions for a multiple component gas stream. The simulation outputs component concentrations along the column length as a function of time from which the breakthrough data is obtained. It also outputs temperature along the column length as a function of time and pressure drop along the column length. Experimental data will be input into the adsorption model to develop a model specific for iodine adsorption on silver mordenite as well as model(s) specific for krypton and xenon adsorption. The model will be validated with experimental breakthrough curves. Another future off-gas modeling goal is to develop a model for the unit operation absorption. The off-gas models will be made available via the server or web for evaluation by customers.

  11. Spent fuel dissolution test including dissolver off-gas treatment in the NUCEF (Nuclear Fuel Cycle Safety Engineering Facility) alpha-gamma cell: Spent fuels with burnups up to 44 GWDT-1

    Spent fuel dissolution test was carried out to study the dissolution behavior of nuclides and the behavior of volatile nuclides, using a bench-scale reprocessing test rig in the NUCEF alpha-gamma cell. 29 and 44 GWdt-1 spen fuels were respectively dissolved. Study on the dissolution behavior showed that the dissolution rate of uranium and plutonium were similar. Also, other species: Cesium, Americium, Strontium and Neodymium were found to dissolve in the similar manor to uranium. The fraction of Mo dissolved was found to decrease during the dissolution. Zirconium molybdate (Zr(Mo2O7)(OH)2(H2O)2) was identified from the XRD pattern of residue in the 29 GWdt-1 spent fuel dissolution. Those results suggested the precipitation of the hydrate during dissolution. As for the iodine-129 removal, decontamination factor of AGS (silica-gel impregnated with silver nitrate) column was more than 36,000. Measurement of iodine-129 in the dissolver solution revealed that less than 0.57% of total iodine-129 generated, which was estimated by ORIGEN II calculation, was remained in the dissolver solution. Also, measurement of iodine-129 by an iodine-stripping operation from dissolver solution using potassium iodate suggested that another 2.72% of total iodine-129 precipitated as iodide. In addition, about 70% of total iodine generated was measured in the AGS columns. Rest of iodine-129 was supposed to adsorb to the HEPA filter and the inner surface of dissolver off-gas lines. Those results on iodine-129 distribution were found to be almost identical to the results obtained in the study using iodine-131 as tracer. Release of carbon-14 as carbon dioxide during dissolution was found to occur when the release of Kr-85. From the measurement of carbon-14, initial nitrogen-14 concentration in the fuel was estimated to be about several ppms, which was within the range reported. (author)

  12. Cleanable sintered metal filters in hot off-gas systems

    Filters with sintered metal elements, arranged as tube bundles with backflush air cleaning, are the equivalent of bag filters for high-temperature, harsh environments. They are virtually the only alternative for high-temperature off-gas systems where a renewable, highly efficient particle trap is required. Tests were conducted which show that the sintered metal elements installed in a filter system provide effective powder collection in high-temperature atmospheres over thousands of cleaning cycles. Such a sintered metal filter system is now installed on the experimental defense waste calciner at the Savannah River Laboratory. The experimental results included in this paper were used as the basis for its design

  13. Literature review: Assessment of DWPF melter and melter off-gas system lifetime

    Reigel, M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-07-30

    A glass melter for use in processing radioactive waste is a challenging environment for the materials of construction (MOC) resulting from a combination of high temperatures, chemical attack, and erosion/corrosion; therefore, highly engineered materials must be selected for this application. The focus of this report is to review the testing and evaluations used in the selection of the Defense Waste Processing Facility (DWPF), glass contact MOC specifically the Monofrax® K-3 refractory and Inconel® 690 alloy. The degradation or corrosion mechanisms of these materials during pilot scale testing and in-service operation were analyzed over a range of oxidizing and reducing flowsheets; however, DWPF has primarily processed a reducing flowsheet (i.e., Fe2+/ΣFe of 0.09 to 0.33) since the start of radioactive operations. This report also discusses the materials selection for the DWPF off-gas system and the corrosion evaluation of these materials during pilot scale testing and non-radioactive operations of DWPF Melter #1. Inspection of the off-gas components has not been performed during radioactive operations with the exception of maintenance because of plugging.

  14. Literature review: Assessment of DWPF melter and melter off-gas system lifetime

    Reigel, M. M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-07-30

    A glass melter for use in processing radioactive waste is a challenging environment for the materials of construction (MOC) resulting from a combination of high temperatures, chemical attack, and erosion/corrosion; therefore, highly engineered materials must be selected for this application. The focus of this report is to review the testing and evaluations used in the selection of the Defense Waste Processing Facility (DWPF), glass contact MOC specifically the Monofrax® K-3 refractory and Inconel® 690 alloy. The degradation or corrosion mechanisms of these materials during pilot scale testing and in-service operation were analyzed over a range of oxidizing and reducing flowsheets; however, DWPF has primarily processed a reducing flowsheet (i.e., Fe2+/ΣFe of 0.09 to 0.33) since the start of radioactive operations. This report also discusses the materials selection for the DWPF off-gas system and the corrosion evaluation of these materials during pilot scale testing and non-radioactive operations of DWPF Melter #1. Inspection of the off-gas components has not been performed during radioactive operations with the exception of maintenance because of plugging.

  15. Enhancing energy recovery in the steel industry: Matching continuous charge with off-gas variability smoothing

    Highlights: • A system based on phase change material is inserted into the off-gas-line of a continuous charge electric arc furnace. • The off-gas temperature profile after scrap preheating is smoothed. • A heat transfer fluid through phase change material containers allows to control overheating issues. • The smoothed off-gas profiles enable efficient downstream power generation. • The recovery system investment cost is decreased due to lower sizes of components. - Abstract: In order to allow an efficient energy recovery from off-gas in the steel industry, the high variability of heat flow should be managed. A temperature smoothing device based on phase change materials at high temperatures is inserted into the off-gas line of a continuous charge electric arc furnace process with scrap preheating. To address overheating issues, a heat transfer fluid flowing through containers is introduced and selected by developing an analytical model. The performance of the smoothing system is analyzed by thermo-fluid dynamic simulations. The reduced maximum temperature of off-gas allows to reduce the size and investment cost of the downstream energy recovery system, while the increased minimum temperature enhances the steam turbine load factor, thus increasing its utilization. Benefits on environmental issues due to dioxins generation are also gained

  16. Development of membrane moisture separator for BWR off-gas system

    In BWR plant off-gas treatment systems, dehumidifiers are used to maintain noble gas adsorption efficiency in the first half of the charcoal hold-up units. From the perspective of simplifying and reducing the cost of such a dehumidification system, Japanese BWR utilities and plant fabricators have been developing a dehumidification system employing moisture separation membrane of the type already proven in fields such as medical instrumentation and precision measuring apparatus. The first part of this development involved laboratory testing to simulate the conditions found in an actual off-gas system, the results of which demonstrated satisfactory results in terms of moisture separation capability and membrane durability, and suggested favorable prospects for application in actual off-gas systems. Further, in-plant testing to verify moisture separation capability and membrane durability in the presence of actual gases is currently underway, with results so far suggesting that the system is capable of obtaining good moisture separation capability. (author)

  17. Biological off-gas treatment: let's make things better

    Groenestijn, J.W. van

    1998-01-01

    Biological off-gas treatment is the most effective cleaning method for many off-gases which contain low concentration of pollutants (<5 g/m3). The world market share in off-gas treatment is a few percent. Potential buyers are reserved because of existing biofilter quality differences and lack of exp

  18. Heat exchangers and thermal energy storage concepts for the off-gas heat of steelmaking devices

    The fluctuating thermal emissions of electric arc furnaces require energy storage systems to provide downstream consumers with a continuous amount of thermal energy or electricity. Heat recovery systems based on thermal energy storage are presented. A comparison of different thermal energy storage systems has been performed. For the purpose, suitable heat exchangers for the off-gas heat have been developed. Dynamic process simulations of the heat recovery plants were necessary to check the feasibility of the systems and consider the non-steady-state off-gas emissions of the steelmaking devices. The implementation of a pilot plant into an existing off-gas duct of an electric arc furnace was required to check the real behavior of the heat exchanger and determine suitable materials in view of corrosion issues. The pilot plant is presented in this paper.

  19. Innovative method for increased methane recovery from two-phase anaerobic digestion of food waste through reutilization of acidogenic off-gas in methanogenic reactor.

    Yan, Bing Hua; Selvam, Ammaiyappan; Wong, Jonathan W C

    2016-10-01

    In this study, the performance of a two-phase anaerobic digestion reactor treating food waste with the reutilization of acidogenic off-gas was investigated with the objective to improve the hydrogen availability for the methanogenic reactor. As a comparison a treatment without off-gas reutilization was also set up. Results showed that acidogenic off-gas utilization in the upflow anaerobic sludge blanket (UASB) reactor increased the methane recovery up to 38.6%. In addition, a 27% increase in the production of cumulative chemical oxygen demand (COD) together with an improved soluble microbial products recovery dominated by butyrate was observed in the acidogenic leach bed reactor (LBR) with off-gas reutilization. Of the increased methane recovery, ∼8% was contributed by the utilization of acidogenic off-gas in UASB. Results indicated that utilization of acidogenic off-gas in methanogenic reactor is a viable technique for improving overall methane recovery. PMID:27039352

  20. Textiles Performance Testing Facilities

    Federal Laboratory Consortium — The Textiles Performance Testing Facilities has the capabilities to perform all physical wet and dry performance testing, and visual and instrumental color analysis...

  1. Boiling water reactor off-gas systems evaluation

    An evaluation of the off-gas systems for all 25 operating Boiling Water Reactors (BWR) was made to determine the adequacy of their design and operating procedures to reduce the probability of off-gas detonations. The results of the evaluations are that, of the 25 operable units, 13 meet all the acceptance criteria. The other 12 units do not have the features needed to meet the criteria, but have been judged to have, or are committed to provide, features which give reasonable assurance that the potential for external off-gas detonations is minimized. The 12 units which did not originally meet the criteria are aware of the potential hazards associated with off-gas detonations and have agreed to take action to minimize the probability of future detonations

  2. Treatment of off-gas from radioactive waste incinerators

    An effective process reducing volume of radioactive wastes is incineration of combustible wastes. Appropriate design of the off-gas treatment system is necessary to ensure that any releases of airborne radionuclides into the environment are kept below acceptable limits. In many cases, the off-gas system must be designed to accommodate chemical constituents in the gas stream. The purpose of this publication is to provide the most up-to-date information regarding off-gas treatment as well as an account of some of the developments so as to aid users in the selection of an integrated system for a particular application. The choice of incinerator/off-gas system combination depends on the wastes to be treated, as well as other factors, such as regulatory requirements. Current problems and development needs are discussed. Following comprehensive discussions of the various factors affecting a choice, various incinerator and off-gas treatment systems are recommended for the various types of wastes that may be treated: low PVC content solid, high PVC content solid, organic liquid and resins. The economics or costs of the off-gas system and an evaluation of the overall cost effectiveness of incineration or direct burial is not discussed in detail. This publication is specifically directed toward technical aspects and addresses: incineration types and origin, sources and characteristics of off-gas streams; descriptions of available technologies for off-gas treatment; basic component design requirements and component description; operational experience of plants in active operation and their current practices; legal aspects and safety requirements; remaining problems to be solved and development trends in plant design and component structure. This report seeks to broaden and enhance the understanding of the developed technology and to indicate areas where improvements can be made by further research and development. 110 refs

  3. Preliminary Results from Electric Arc Furnace Off-Gas Enthalpy Modeling

    Nimbalkar, Sachin U [ORNL; Thekdi, Arvind [E3M Inc; Keiser, James R [ORNL; Storey, John Morse [ORNL

    2015-01-01

    This article describes electric arc furnace (EAF) off-gas enthalpy models developed at Oak Ridge National Laboratory (ORNL) to calculate overall heat availability (sensible and chemical enthalpy) and recoverable heat values (steam or power generation potential) for existing EAF operations and to test ORNL s new EAF waste heat recovery (WHR) concepts. ORNL s new EAF WHR concepts are: Regenerative Drop-out Box System and Fluidized Bed System. The two EAF off-gas enthalpy models described in this paper are: 1.Overall Waste Heat Recovery Model that calculates total heat availability in off-gases of existing EAF operations 2.Regenerative Drop-out Box System Model in which hot EAF off-gases alternately pass through one of two refractory heat sinks that store heat and then transfer it to another gaseous medium These models calculate the sensible and chemical enthalpy of EAF off-gases based on the off-gas chemical composition, temperature, and mass flow rate during tap to tap time, and variations in those parameters in terms of actual values over time. The models provide heat transfer analysis for the aforementioned concepts to confirm the overall system and major component sizing (preliminary) to assess the practicality of the systems. Real-time EAF off-gas composition (e.g., CO, CO2, H2, and H2O), volume flow, and temperature data from one EAF operation was used to test the validity and accuracy of the modeling work. The EAF off-gas data was used to calculate the sensible and chemical enthalpy of the EAF off-gases to generate steam and power. The article provides detailed results from the modeling work that are important to the success of ORNL s EAF WHR project. The EAF WHR project aims to develop and test new concepts and materials that allow cost-effective recovery of sensible and chemical heat from high-temperature gases discharged from EAFs.

  4. Development of silver impregnated alumina for iodine separation from off-gas streams

    Funabashi, Kiyomi; Fukasawa, Tetsuo; Kikuchi, Makoto [Energy Research Laboratory, Hitachi (Japan)] [and others

    1995-02-01

    An inorganic iodine adsorbent, silver impregnated alumina (AgA), has been developed to separate iodine effectively from off-gas streams of nuclear facilities and to decrease the volume of waste (spent adsorbent). Iodine removal efficiency was improved at relatively high humidity by using alumina carrier with two different pore diameters. Waste volume reduction was achieved by impregnating relatively large amounts of silver into the alumina pores. The developed adsorbent was tested first with simulated off-gas streams under various experimental conditions and finally with actual off-gas streams of the Karlsruhe reprocessing plant. The decontamination factor (DF) was about 100 with the AgA bed depth of 2cm at 70% relative humidity, which was a DF one order higher than that when AgA with one pore size was used. Iodine adsorption capacity was checked by passing excess iodine into the AgA bed. Values were about 0.12 and 0.35 g-I/cm`-AgA bed for 10 and 24wt% silver impregnated AgA, respectively. The results obtained in this study demonstrated the applicability of the developed AgA to the off-gas treatment system of nuclear facilities.

  5. Integrated DM 1200 Melter Testing Of HLW C-106/AY-102 Composition Using Bubblers VSL-03R3800-1, Rev. 0, 9/15/03

    This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of simulated HLW C-106/AY-102 feed. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW C-106/AY-102 feed; determine the effect of bubbling rate on production rate; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and to perform pre- and post test inspections of system components.

  6. INTEGRATED DM 1200 MELTER TESTING OF HLW C-106/AY-102 COMPOSITION USING BUBBLERS VSL-03R3800-1 REV 0 9/15/03

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D' ANGELO NA; KOT WK; PEGG IL

    2011-12-29

    This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of simulated HLW C-106/AY-102 feed. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW C-106/AY-102 feed; determine the effect of bubbling rate on production rate; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and to perform pre- and post test inspections of system components.

  7. Treatment of nitrous off-gas from dissolution of sludges

    Several configurations have been reviewed for the NOx removal of dissolver off-gas. A predesign has been performed and operating conditions have been optimized. Simple absorption columns seems to be sufficient. NHC is in charge of the treatment of sludges containing mainly uranium dioxide and metallic uranium. The process is based on the following processing steps a dissolution step to oxidize the pyrophoric materials and to dissolve radionuclides (uranium, plutonium, americium and fission products), a solid/liquid separation to get rid of the insoluble solids (to be disposed at ERDF), an adjustment of the acid liquor with neutronic poisons, and neutralization of the acid liquor with caustic soda. The dissolution step generates a flow of nitrous fumes which was evaluated in a previous study. This NOx flow has to be treated. The purpose of this report is to study the treatment process of the nitrous vapors and to 0482 perform a preliminary design. Several treatment configurations are studied and the most effective process option with respect to the authorized level of discharge into atmosphere is discussed. As a conclusion, recommendations concerning the unit preliminary design are given

  8. Off-Gas Adsorption Model Capabilities and Recommendations

    Lyon, Kevin L. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Welty, Amy K. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Law, Jack [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ladshaw, Austin [Georgia Inst. of Technology, Atlanta, GA (United States); Yiacoumi, Sotira [Georgia Inst. of Technology, Atlanta, GA (United States); Tsouris, Costas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-03-01

    Off-gas treatment is required to reduce emissions from aqueous fuel reprocessing. Evaluating the products of innovative gas adsorption research requires increased computational simulation capability to more effectively transition from fundamental research to operational design. Early modeling efforts produced the Off-Gas SeParation and REcoverY (OSPREY) model that, while efficient in terms of computation time, was of limited value for complex systems. However, the computational and programming lessons learned in development of the initial model were used to develop Discontinuous Galerkin OSPREY (DGOSPREY), a more effective model. Initial comparisons between OSPREY and DGOSPREY show that, while OSPREY does reasonably well to capture the initial breakthrough time, it displays far too much numerical dispersion to accurately capture the real shape of the breakthrough curves. DGOSPREY is a much better tool as it utilizes a more stable set of numerical methods. In addition, DGOSPREY has shown the capability to capture complex, multispecies adsorption behavior, while OSPREY currently only works for a single adsorbing species. This capability makes DGOSPREY ultimately a more practical tool for real world simulations involving many different gas species. While DGOSPREY has initially performed very well, there is still need for improvement. The current state of DGOSPREY does not include any micro-scale adsorption kinetics and therefore assumes instantaneous adsorption. This is a major source of error in predicting water vapor breakthrough because the kinetics of that adsorption mechanism is particularly slow. However, this deficiency can be remedied by building kinetic kernels into DGOSPREY. Another source of error in DGOSPREY stems from data gaps in single species, such as Kr and Xe, isotherms. Since isotherm data for each gas is currently available at a single temperature, the model is unable to predict adsorption at temperatures outside of the set of data currently

  9. Method for treating a nuclear process off-gas stream

    A method is described for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. The method involves a sequence of adsorption and desorption steps which are specified. Particular reference is made to the separation of xenon and krypton from the off-gas stream, and to the use of silver-exchanged mordenite as the adsorbent. (U.K.)

  10. High-level waste vitrification off-gas cleanup technology

    This brief overview is intended to be a basis for discussion of needs and problems existing in the off-gas clean-up technology. A variety of types of waste form and processes are being developed in the United States and abroad. A description of many of the processes can be found in the Technical Alternative Documents (TAD). Concurrently, off-gas processing systems are being developed with most of the processes. An extensive review of methodology as well as decontamination factors can be found in the literature. Since it is generally agreed that the most advanced solidification process is vitrification, discussion here centers about the off-gas problems related to vitrification. With a number of waste soldification facilities around the world in operation, it can be shown that present technology can satisfy the present requirement for off-gas control. However, a number of areas within the technology base show potential for improvement. Fundamental as well as verification studies are needed to obtain the improvements

  11. Advanced Off-Gas Control System Design For Radioactive And Mixed Waste Treatment

    Nick Soelberg

    2005-09-01

    Treatment of radioactive and mixed wastes is often required to destroy or immobilize hazardous constituents, reduce waste volume, and convert the waste to a form suitable for final disposal. These kinds of treatments usually evolve off-gas. Air emission regulations have become increasingly stringent in recent years. Mixed waste thermal treatment in the United States is now generally regulated under the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. These standards impose unprecedented requirements for operation, monitoring and control, and emissions control. Off-gas control technologies and system designs that were satisfactorily proven in mixed waste operation prior to the implementation of new regulatory standards are in some cases no longer suitable in new mixed waste treatment system designs. Some mixed waste treatment facilities have been shut down rather than have excessively restrictive feed rate limits or facility upgrades to comply with the new standards. New mixed waste treatment facilities in the U. S. are being designed to operate in compliance with the HWC MACT standards. Activities have been underway for the past 10 years at the INL and elsewhere to identify, develop, demonstrate, and design technologies for enabling HWC MACT compliance for mixed waste treatment facilities. Some specific off-gas control technologies and system designs have been identified and tested to show that even the stringent HWC MACT standards can be met, while minimizing treatment facility size and cost.

  12. Advanced Off-Gas Control System Design For Radioactive And Mixed Waste Treatment

    Treatment of radioactive and mixed wastes is often required to destroy or immobilize hazardous constituents, reduce waste volume, and convert the waste to a form suitable for final disposal. These kinds of treatments usually evolve off-gas. Air emission regulations have become increasingly stringent in recent years. Mixed waste thermal treatment in the United States is now generally regulated under the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. These standards impose unprecedented requirements for operation, monitoring and control, and emissions control. Off-gas control technologies and system designs that were satisfactorily proven in mixed waste operation prior to the implementation of new regulatory standards are in some cases no longer suitable in new mixed waste treatment system designs. Some mixed waste treatment facilities have been shut down rather than have excessively restrictive feed rate limits or facility upgrades to comply with the new standards. New mixed waste treatment facilities in the U. S. are being designed to operate in compliance with the HWC MACT standards. Activities have been underway for the past 10 years at the INL and elsewhere to identify, develop, demonstrate, and design technologies for enabling HWC MACT compliance for mixed waste treatment facilities. Some specific off-gas control technologies and system designs have been identified and tested to show that even the stringent HWC MACT standards can be met, while minimizing treatment facility size and cost

  13. Remotely replaceable and testable off-gas filter system for the NWCF

    The process off-gas filter system designed for use in the New Waste Calcining Facility (NWCF) requires remote filter removal, replacement and in-place DOP testing. A series of full-scale mockup tests, modifications and retesting at the Remote Maintenance Development Facility (RMDF) resulted in a system in which a commercial High Efficiency Particulate Air (HEPA) filter can be installed, tested for leaks, operated and removed from a sealed filter housing using remote handling methods. This paper describes the development, testing and results of this effort

  14. Design of off-gas and air cleaning systems at nuclear power plants

    The primary purpose of this report is to describe the current design of air and process off-gas cleaning technologies used in nuclear power plants (NPPs). Because of the large inventory of fission products that are produced in the fuel (i.e. in the range of 5x1019Bq per GW(e)·a) and the highly restrictive airborne radionuclide release limits being established by Member States, air and process off-gas cleaning technologies are constantly being improved to provide higher airborne radionuclide recovery efficiencies and a smaller probability of malfunction. For various technologies considered an attempt has been made to provide the following information: (a) Process description in terms of principles of off-gas and air cleaning, operating parameters and system performance; (b) Design for normal and accident situations; (c) Design of components with regard to construction materials, size, shape and geometry of the system, resistance to chemical and physical degradation from the operational environment, safety and quality assurance requirements

  15. Continuous chemical cold traps for reprocessing off-gas purification

    Absorption of nitrogen oxides and iodine from simulated reprocessing plant off-gas streams has been studied using nitric acid and nitric acid/hydrogen peroxide mixtures at low temperatures. The experiments were carried out at the laboratory and on the engineering scale. The pilot plant scale column has 0.8 m diameter and 16 absorption plates at 0.2 m spacing. Cooling coils on the plates allow operating temperatures down to -600C. The NO concentration in the feed gas usually has been 1% by volume and the flow rate 4-32 m3 (STP) per hour. The iodine behavior has been studied using I-123 tracer. Results of the study are presented. The chemistry of the processes and the advantages and disadvantages in correlation to the various applications for an off-gas purification in a reprocessing plant are compared and discussed. The processes are compatible with the PUREX process and do not produce additional waste

  16. Carbon dioxide-krypton separation and radon removal from nuclear-fuel-reprocessing off-gas streams

    General Atomic Company (GA) is conducting pilot-plant-scale tests that simulate the treatment of radioactive and other noxious volatile and gaseous constituents of off-gas streams from nuclear reprocessing plants. This paper reports the results of engineering-scale tests performed on the CO2/krypton separation and radon holdup/decay subsystems of the GA integrated off-gas treatment system. Separation of CO2 from krypton-containing gas streams is necessary to facilitate subsequent waste processing and krypton storage. Molecular sieve 5A achieved this separation in dissolver off-gas streams containing relatively low krypton and CO2 concentrations and in krypton-rich product streams from processes such as the krypton absorption in liquid carbon dioxide (KALC) process. The CO2/krypton separation unit is a 30.5-cm-diameter x 1.8-m-long column containing molecular sieve 5A. The loading capacity for CO2 was determined for gas mixtures containing 250 ppM to 2.2% CO2 and 170 to 750 ppM krypton in either N2 or air. Gas streams rich in CO2 were diluted with N2 to reduce the temperature rise from the heat of adsorption, which would otherwise affect loading capacity. The effluent CO2 concentration prior to breakthrough was less than 10 ppM, and the adsorption capacity for krypton was negligible. Krypton was monitored on-line with a time-of-flight mass spectrometer and its concentration determined quantitatively by a method of continuous analysis, i.e., selected-ion monitoring. Radon-220 was treated by holdup and decay on a column of synthetic H-mordenite. The Rn-220 concentration was monitored on-line with flow-through diffused-junction alpha detectors. Single-channel analyzers were utilized to isolate the 6.287-MeV alpha energy band characteristic of Rn-220 decay from energy bands due to daughter products

  17. Test and Performance Anxiety

    Huberty, Thomas J.

    2010-01-01

    Test and performance anxiety is not recognized easily in schools, in large part because adolescents rarely refer themselves for emotional concerns. Not wanting to risk teasing or public attention, anxious adolescents suffer in silence and under perform on school-related tasks. In school, anxiety is experienced often by students when being…

  18. Off-gas adsorption model and simulation - OSPREY

    A capability of accurately simulating the dynamic behavior of advanced fuel cycle separation processes is expected to provide substantial cost savings and many technical benefits. To support this capability, a modeling effort focused on the off-gas treatment system of a used nuclear fuel recycling facility is in progress. The off-gas separation consists of a series of scrubbers and adsorption beds to capture constituents of interest. Dynamic models are being developed to simulate each unit operation involved so each unit operation can be used as a stand-alone model and in series with multiple others. Currently, an adsorption model has been developed within Multi-physics Object Oriented Simulation Environment (MOOSE) developed at the Idaho National Laboratory (INL). Off-gas Separation and Recovery (OSPREY) models the adsorption of offgas constituents for dispersed plug flow in a packed bed under non-isothermal and non-isobaric conditions. Inputs to the model include gas composition, sorbent and column properties, equilibrium and kinetic data, and inlet conditions. The simulation outputs component concentrations along the column length as a function of time from which breakthrough data can be obtained. The breakthrough data can be used to determine bed capacity, which in turn can be used to size columns. In addition to concentration data, the model predicts temperature along the column length as a function of time and pressure drop along the column length. A description of the OSPREY model, results from krypton adsorption modeling and plans for modeling the behavior of iodine, xenon, and tritium will be discussed. (author)

  19. Off-gas cleaning of a liquid waste vitrifier

    Solid radio-active aerosols and semi-volatile fission products e.g. Ru, Cs, Sb are generated during high level liquid waste vitrification processes. The behaviour of these semi-volatile products during the vitrification of simulated liquid waste in a liquid fed melter and the off-gas cleaning with a wet purification system has been studied. It was found that the melter releases to the off-gas depended on different melter situations associated with different melt surface temperature. At the melter outlet, the over-all size distribution of the dust is composed of two components. The large component is associated with a gross entrainment mechanism whereas the small diameter component is associated with a volatilization/condensation process. The submicronic fraction of the dust is generally enriched in cesium and ruthenium. Moreover, volatile ruthenium species can still exist at the low outlet temperature of the melter. The wet purification system comprises in series a packed bed dust scrubber, a condenser, an ejector venturi and an NOsub(x) column. The dust scrubber removes the gross part of the dust and the ejector-venturi has a high removal efficiency for the submicronic aerosol fraction. The global efficiency of the wet purification system ranged from 99.7% for the cesium species to 99.95% for the ruthenium species. (author)

  20. Design report: An off gas trapping system for a voloxidizer in INL of US

    Jung, I. H.; Shin, J. M.; Park, J. J.; Park, G. I.; Lee, H. H

    2006-09-15

    This reports on the 'Development of Voloxidation Process for Treatment of LWR Spent Fuel', and it is the second year since it has started from June 2004 as a tripartite cooperation project among KAERI(Korea Atomic Energy Research Institute), INL(Idaho National Laboratory) and ORNL(Oak Ridge National Laboratory). This report is described mainly for the Task B2 accomplished during the second project year. The Task B2 in proposal contains two sub-tasks. The first one is design of an off-gas treatment system for a voloxidizer to be used in HFEF of INL. For this, KAERI team developed the design of INL OTS (Off-gas Treatment System) for hot experiment in the HFEF. INL team modified and completed the design of the INL OTS. The second task is manufacturing and test operation of the INL OTS for a voloxidizer in the INL. Manufacturing of the OTS is accomplished by INL team with co-work of KAERI. KAERI provided four sets of trapping filters needed for conducting hot experiment in the INL HFEF.

  1. ASSESSMENT OF THE IMPACT OF TOA PARTITIONING ON DWPF MELTER OFF-GAS FLAMMABILITY

    Daniel, G.

    2013-06-18

    An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of increasing the amount of TOA in the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process. The results of this study showed that the concentrations of nonvolatile carbon of the current solvent limit (150 ppm) in the Slurry Mix Evaporator (SME) product would be about 7% higher and the nonvolatile hydrogen would be 2% higher than the actual current solvent (126 ppm) with an addition of up to 3 ppm of TOA when the concentration of Isopar L in the effluent transfer is controlled below 87 ppm and the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle. Therefore, the DWPF melter off-gas flammability assessment is conservative for up to an additional 3 ppm of TOA in the effluent based on these assumptions. This report documents the calculations performed to reach this conclusion.

  2. Experimental determination of the solubilities of dissolver off-gas constituents in a Kr-85 recovery solvent (CCl2F2). Final report

    The experimental determination of the solubility of the major off-gas constituent-Nitrogen was performed with a new solubility measurement apparatus. The new apparatus was designed, built and tested; an algorithm for thermodynamic consistency testing of P-T-x-y data for solubility systems was developed, and thermodynamically consistent Nitrogen-R-12 solubility data were taken. The Henry's Law constant for the Nitrogen-R-12 system can be represented by the equation ln H/sub N2-R-12/ (atm) = 0.44 + 1.0708 lnT (0K). The solubility data extend the range of known equilibrium data into a region where process equipment operate and are consistent with both other data at lower temperatures by other researchers and with regular solution theory

  3. CALCULATION OF DEMONSTRATION BULK VITRIFICATION SYSTEM MELTER INLEAKAGE AND OFF-GAS GENERATION RATE

    MAY TH

    2008-04-16

    The River Protection Project (RPP) mission is to safely store, retrieve, treat, immobilize, and dispose of the Hanford Site tank waste. The Demonstration Bulk Vitrification System (DBVS) is a research and development project whose objective is to demonstrate the suitability of Bulk Vitrification treatment technology waste form for disposing of low-activity waste from the Tank Farms. The objective of this calculation is to determine the DBVS melter inleakage and off-gas generation rate based on full scale testing data from 38D. This calculation estimates the DBVS melter in leakage and gas generation rate based on test data. Inleakage is estimated before the melt was initiated, at one point during the melt, and at the end of the melt. Maximum gas generation rate is also estimated.

  4. Peer review panel summary report for technical determination of mixed waste incineration off-gas systems for Rocky Flats

    A Peer Review Panel was convened on September 15-17, 1992 in Boulder, Co. The members of this panel included representatives from DOE, EPA, and DOE contractors along with invited experts in the fields of air pollution control and waste incineration. The primary purpose of this review panel was to make a technical determination of a hold, test and release off gas capture system should be implemented in the proposed RF Pland mixed waste incineration system; or if a state of the art continuous air pollution control and monitoring system should be utilized as the sole off-gas control system. All of the evaluations by the panel were based upon the use of the fluidized bed unit proposed by Rocky Flats and cannot be generalized to other systems

  5. The development and design of the off-gas treatment system for the thermal oxide reprocessing plant (THORP) at Sellafield

    British Nuclear Fuels completed construction of its Thermal Oxide Reprocessing Plant (THORP) at Sellafield in 1992, at a cost of 1,850M. After Government and Regulatory approval, active commissioning was initiated on 17 January 1994. From the outset, the need to protect the workforce, the public and the environment in general from the plant's discharges was clearly recognised. The design intent was to limit radiation exposure of members of the general public to As Low as Reasonably Practicable. Furthermore no member of the most highly exposed group should receive an annual dose exceeding 50 microsieverts from either the aerial or marine discharge routes. This paper describes how the design intent has been met with respect to aerial discharges. It outlines the development programme which was undertaken to address the more demanding aspects of the performance specification. This ranged from small-scale experiments with irradiated fuel to inactive pilot plant trials and full-scale plant measurements. The resulting information was then used, with the aid of mathematical models, in the design of an off-gas treatment system which could achieve the overall goal. The principal species requiring treatment in the THORP off-gas system are iodine-129, carbon-14, nitrogen oxides (NOx), fuel dust particles and aerosols containing plutonium or mixed fission products. The paper describes the combination of abatement equipment used in different parts of the plant, including counter-current absorption columns, electrostatic precipitators, dehumidifiers and High Efficiency Particulate Air filters. Because a number of separate off-gas streams are combined before discharge, special depression control systems were developed which have already proved successful during plant commissioning. BNFL is confident that the detailed attention given to the development and design phases of the THORP off-gas system will ensure good performance when the plant moves into fully radioactive operation

  6. Time-dependent analysis of dissolver off-gas cleaning installations in a reprocessing plant

    The iodine- and aerosol-filtering test facility PASSAT of the Nuclear Research Centre in Karlsruhe has been investigated using a method which allows time-dependent analyses under accident conditions. This method which is closely related to fault-tree analysis needs subdivision in barriers of the system, and their logical combination in a tree. The barriers have binary states: defect and intact. The defect state will be described by a fault tree, whereas the intact state includes dependences of a barrier operation on physical parameters. The intact state enables time-dependent calculations. Calculations have been done for iodine filtering, because the best known entrance data are given. Results demonstrate clearly that the amount of iodine released increases only if both heaters failed, which heat the off-gas from 300C to 800C and then to 1300C. Additionally the integrated amount of iodine released depends on time period between the failures of the heaters

  7. Final Report DM1200 Tests With AZ 101 HLW Simulants VSL-03R3800-4, Rev. 0, 2/17/04

    This report documents melter and off-gas performance results obtained on the DM 1200 HLW Pilot Melter during processing of simulated HLW AZ-101 feed. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW AZ-101 feed; determine the effect of bubbling rate and feed solids content on production rate; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and to perform pre- and post-test inspections of system components. The test objectives (including test success criteria), along with how they were met, are outlined in a table.

  8. FINAL REPORT DM1200 TESTS WITH AZ 101 HLW SIMULANTS VSL-03R3800-4 REV 0 2/17/04

    KRUGER AA; MATLACK KS; BARDAKCI T; D' ANGELO NA; GONG W; KOT WK; PEGG IL

    2011-12-29

    This report documents melter and off-gas performance results obtained on the DM 1200 HLW Pilot Melter during processing of simulated HLW AZ-101 feed. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW AZ-101 feed; determine the effect of bubbling rate and feed solids content on production rate; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and to perform pre- and post-test inspections of system components. The test objectives (including test success criteria), along with how they were met, are outlined in a table.

  9. Infiniband Performance Testing

    Minich, M

    2005-10-13

    A look at the performance of the infiniband interconnect using the Voltaire host stack. This will attempt to compare not only infiniband to other high-performance interconnects, but will also take a look at comparing some of the different hardware choices available at the time of writing (e.g. Opteron, EM64T, pci-express and pci-x).

  10. Assessment of the impact of the next generation solvent on DWPF melter off-gas flammability

    An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of replacing the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process with the Next Generation Solvent (NGS-MCU) and blended solvent. The results of this study showed that the concentrations of nonvolatile carbon and hydrogen of the current solvent in the Slurry Mix Evaporator (SME) product would both be about 29% higher than their counterparts of the NGS-MCU and blended solvent in the absence of guanidine partitioning. When 6 ppm of guanidine (TiDG) was added to the effluent transfer to DWPF to simulate partitioning for the NGS-MCU and blended solvent cases and the concentration of Isopar®L in the effluent transfer was controlled below 87 ppm, the concentrations of nonvolatile carbon and hydrogen of the NGS-MCU and blended solvent were still about 12% and 4% lower, respectively, than those of the current solvent. It is, therefore, concluded that as long as the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle and the concentration of Isopar®L in the effluent transfer is controlled below 87 ppm, using the current solvent assumption of 105 ppm Isoparsign L or 150 ppm solvent in lieu of NGS-MCU or blended solvent in the DWPF melter off-gas flammability assessment is conservative for up to an additional 6 ppm of TiDG in the effluent due to guanidine partitioning. This report documents the calculations performed to reach this conclusion

  11. Cryogenic system for collecting noble gases from boiling water reactor off-gas

    In boiling water reactors, noncondensible gases are expelled from the main condenser. This off-gas stream is composed largely of radiolytic hydrogen and oxygen, air in-leakage, and traces of fission product krypton and xenon. In the Air Products' treatment system, the stoichiometric hydrogen and oxygen are reacted to form water in a catalytic recombiner. The design of the catalytic recombiner is an extension of industrial gas technology developed for purification of argon and helium. The off-gas after the recombiner is processed by cryogenic air-separation technology. The gas is compressed, passed into a reversing heat exchanger where water vapor and carbon dioxide are frozen out, further cooled, and expanded into a distillation column where refrigeration is provided by addition of liquid nitrogen. More than 99.99 percent of the krypton and essentially 100 percent of the xenon entering the column are accumulated in the column bottoms. Every three to six months, the noble-gas concentrate accumulated in the column bottom is removed as liquid, vaporized, diluted with steam, mixed with hydrogen in slight excess of oxygen content, and fed to a small recombiner where all the oxygen reacts to form water. The resulting gas stream, containing from 20 to 40 percent noble gases, is compressed into small storage cylinders for indefinite retention or for decay of all fission gases except krypton-85, followed by subsequent release under controlled conditions and favorable meteorology. This treatment system is based on proven technology that is practiced throughout the industrial gas industry. Only the presence of radioactive materials in the process stream and the application in a nuclear power plant environment are new. Adaptations to meet these new conditions can be made without sacrificing performance, reliability, or safety

  12. Remediation on off-gas system deposits in a radioactive waste glass melter

    Since the early 1980's, research glass melters have been used at the Savannah River Laboratory (SRL) to develop the reference vitrification process for immobilization of high level radioactive waste. One of the operating concerns for these melters has been the pluggage of the off-gas system with solid deposits. Samples of these deposits were analyzed to be mixture of alkali-rich chlorides, sulfates, borates, and fluorides with entrained Fe2O3 spinel, and frit particles. The spatial distribution of these deposits throughout the off-gas system indicates that they form by vapor-phase transport and subsequently condensation. Condensation of the alkali-rich phases cements entrained particulates causing the off-gas line to plug. It is concluded that off-gas system pluggage can be effectively controlled by maintaining the off-gas velocity above 16 m/s, while maintaining the off-gas temperature as high as practical below the glass softening point. This paper summarizes the results of chemical and physical analyses of off-gas deposit samples from various melters at SRL. Recent design changes made to the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) to alleviate the pluggage problem are also discussed

  13. Airborne waste management technology applicable for use in reprocessing plants for control of iodine and other off-gas constituents

    Extensive work in the area of iodine removal from reprocessing plant off-gas streams using various types of solid sorbent materials has been conducted worldwide over the past two decades. This work has focused on the use of carbon filters, primarily for power plant applications. More recently, the use of silver-containing sorbents has been the subject of considerable research. The most recent work in the United States has addressed the use of silver-exchanged faujasites and mordenites. The chemical reactions of iodine with silver on the sorbent are not well defined, but it is generally believed that chemisorbed iodides and iodates are formed. The process for iodine recovery generally involves passage of the iodine-laden gas stream through a packed bed of the adsorbent material preheated to a temperature of about 150/degree/C. Most iodine removal system designs utilizing silver-containing solid sorbents assume only a 30 to 50% silver utilization. Based on laboratory tests, potentially 60 to 70% of the silver contained in the sorbents can be reacted with iodine. To overcome the high cost of silver associated with these materials, various approaches have been explored. Among these are the regeneration of the silver-containing sorbent by stripping the iodine and trapping the iodine on a sorbent that has undergone only partial silver exchange and is capable of attaining a much higher silver utilization. This summary report describes the US work in regeneration of iodine-loaded solid sorbent material. In addition, the report discusses the broader subject of plant off-gas treatment including system design. The off-gas technologies to recovery No/sub x/ and to recover and dispose of Kr, 14C, and I are described as to their impacts on the design of an integrated off-gas system. The effect of ventilation philosophy for the reprocessing plant is discussed as an integral part of the overall treatment philosophy of the plant off-gas. 103 refs., 5 figs., 8 tabs

  14. Anode shroud for off-gas capture and removal from electrolytic oxide reduction system

    Bailey, James L.; Barnes, Laurel A.; Wiedmeyer, Stanley G.; Williamson, Mark A.; Willit, James L.

    2014-07-08

    An electrolytic oxide reduction system according to a non-limiting embodiment of the present invention may include a plurality of anode assemblies and an anode shroud for each of the anode assemblies. The anode shroud may be used to dilute, cool, and/or remove off-gas from the electrolytic oxide reduction system. The anode shroud may include a body portion having a tapered upper section that includes an apex. The body portion may have an inner wall that defines an off-gas collection cavity. A chimney structure may extend from the apex of the upper section and be connected to the off-gas collection cavity of the body portion. The chimney structure may include an inner tube within an outer tube. Accordingly, a sweep gas/cooling gas may be supplied down the annular space between the inner and outer tubes, while the off-gas may be removed through an exit path defined by the inner tube.

  15. Off-Gas Analysis During the Vitrification of Hanford Radioactive Waste Samples

    This paper describes the off-gas analysis of samples collected during the radioactive vitrification experiments. Production and characterization of the Hanford waste-containing LAW and HAW glasses are presented in related reports from this conference

  16. Design and optimization of a combined fuel reforming and solid oxide fuel cell system with anode off-gas recycling

    Highlights: → In this work, an analytical, parametric study is performed to evaluate the feasibility and performance of a combined fuel reforming and SOFC system. → Specifically the effects of adding the anode off-gas recycling and recirculation components and the CO2 absorbent unit are investigated. → The AOG recycle ratio increases with increasing S/C ratio and the addition of AOG recycle eliminates the need for external water consumption. → The key finding is that for the SOFC operating at 900 deg. C with the steam to carbon ratio at 5 and no AOG recirculation, the system efficiency peaks. - Abstract: An energy conversion and management concept for a combined system of a solid oxide fuel cell coupled with a fuel reforming device is developed and analyzed by a thermodynamic and electrochemical model. The model is verified by an experiment and then used to evaluate the overall system performance and to further suggest an optimal design strategy. The unique feature of the system is the inclusion of the anode off-gas recycle that eliminates the need of external water consumption for practical applications. The system performance is evaluated as a function of the steam to carbon ratio, fuel cell temperature, anode off gas recycle ratio and CO2 adsorption percentage. For most of the operating conditions investigated, the system efficiency starts at around 70% and then monotonically decreases to the average of 50% at the peak power density before dropping down to zero at the limiting current density point. From an engineering application point of view, the proposed combined fuel reforming and SOFC system with a range of efficiency between 50% and 70% is considered very attractive. It is suggested that the optimal system is the one where the SOFC operates around 900 deg. C with S/C ratio higher than 3, maximum CO2 capture, and minimum AOG recirculation.

  17. Off gas filtration system in fuel reprocessing plants - engineering design approach based on operating experience

    A few observations are made based on an overview of the experience over several years of operation of the off gas filtration systems in the Fuel Reprocessing Plants in India. Broad profiles of the nature of problem areas are indicated emphasising the need to accord at design stage due care and consideration to such relatively conventional aspects as filter containers, off gas exhausters, coolers/chillers, demisters, vibration isolators, condensate drainage and logistics of filter cartridge replacement. (author)

  18. Technology status report: Off-gas treatment technologies for chlorinated volatile organic compound air emissions

    Rossabi, J.; Haselow, J.S.

    1992-04-15

    The purpose of this document is to review technologies for treatment of air streams that contain chlorinated volatile organic compounds (CVOCS) and to describe a Department of Energy Office of Technology Development program that is planned to demonstrate innovative technologies for the abatement of CVOC emissions. This report describes the first phase of testing of off-gas treatment technologies. At least one more phase of testing is planned. Guidance for the preparation of this document was provided by a predecisional draft outline issued by the Department of Energy's Office of Technology Development. The report is intended to evaluate the technical and regulatory aspects, public acceptance, and estimated costs of technologies selected for development and testing. These technologies are compared to currently practiced or baseline methods for treatment of CVOC-laden airstreams. A brief overview is provided rather than detailed cost and data comparisons because many of these technologies have not yet been field tested. A description of other promising technologies for the treatment of CVOC emissions is also included. Trichloroethylene (TCE) and perchloroethylene (PCE) were used for industrial cleaning and solvent applications for several decades. These chemicals can be classified as CVOCS. As a result of past standard disposal practices, these types of compounds are persistent groundwater and soil contaminants throughout the United States and the Department of Energy Complex.

  19. Technology status report: Off-gas treatment technologies for chlorinated volatile organic compound air emissions

    Rossabi, J.; Haselow, J.S.

    1992-04-15

    The purpose of this document is to review technologies for treatment of air streams that contain chlorinated volatile organic compounds (CVOCS) and to describe a Department of Energy Office of Technology Development program that is planned to demonstrate innovative technologies for the abatement of CVOC emissions. This report describes the first phase of testing of off-gas treatment technologies. At least one more phase of testing is planned. Guidance for the preparation of this document was provided by a predecisional draft outline issued by the Department of Energy`s Office of Technology Development. The report is intended to evaluate the technical and regulatory aspects, public acceptance, and estimated costs of technologies selected for development and testing. These technologies are compared to currently practiced or baseline methods for treatment of CVOC-laden airstreams. A brief overview is provided rather than detailed cost and data comparisons because many of these technologies have not yet been field tested. A description of other promising technologies for the treatment of CVOC emissions is also included. Trichloroethylene (TCE) and perchloroethylene (PCE) were used for industrial cleaning and solvent applications for several decades. These chemicals can be classified as CVOCS. As a result of past standard disposal practices, these types of compounds are persistent groundwater and soil contaminants throughout the United States and the Department of Energy Complex.

  20. Glass melter off-gas system pluggages: Cause, significance, and remediation

    Liquid high-level nuclear waste will be immobilized at the Savannah River Site (SRS) by vitrification in borosilicate glass. Experimental glass melters, used to develop the vitrification process, have occasionally experienced problems with pluggage of the off-gas line with solid deposits. The deposits were determined to be mixtures of alkali rich chlorides, sulfates, borates, and fluorides with entrained insoluble particles of Fe2O3 spinel, and frit. The distribution and location of the alkali deposits throughout the off-gas system indicate that the deposits form by vapor-phase transport and condensation. Condensation of the alkali-rich phases cements the entrained particulates causing the off-gas system pluggages. The identification of vapor phase transport as the operational mechanism causing off-gas system pluggages indicates that deposition can be effectively eliminated by increasing the off-gas velocity. The cementitious alkali borates, halides, and sulfates comprising the off-gas line deposits were determined to be water soluble. Thus pluggage can be effectively removed with water and/or steam

  1. Exergetic Optimization of a Refrigeration Cycle for Re-Liquefaction of LNG Boil-Off Gas

    Mojtaba Babaelahi

    2010-11-01

    Full Text Available The development of liquefaction process for liquefied natural gas boil-off re-liquefaction plants will be addressed to provide an environmentally friendly and cost effective solution for gas transport. Onboard boil-off gas (BOG re-liquefaction is a new technology that liquefies BOG and returns it to the cargo tanks instead of burning it. Exergetic efficiency optimization for cryogenic refrigeration cycle for re-liquefaction of LNG boil-off gas is performed. Thermodynamic modeling has been performed based on the energy and exergy analyses. Objective problem is developed based on maximization of the plant exergetic efficiency and selected decision variables and constraints. Optimization process is performed using MATLAB genetic algorithm optimization

  2. Study of degradation of off-gas H2/O2 recombination catalyst at Hamaoka Unit 4 and 5

    By evaluating the phenomena that hydrogen concentration of outlet gas in the off-gas treatment system at Hamaoka Unit 4 and 5 had increased, it was concluded that the causes of the phenomena were transformation of support alumina by alteration of manufacturing process of catalysts and the deactivation by catalyst poisoning material. Therefore, the manufacturing process was modified and the poisoning material was identified and removed. Moreover, developments such as catalyzer performance monitoring technology with thermometers have been continued in order to improve the reliability of the system. (author)

  3. Inspection system performance test procedure

    This procedure establishes requirements to administer a performance demonstration test. The test is to demonstrate that the double-shell tank inspection system (DSTIS) supplied by the contractor performs in accordance with the WHC-S-4108, Double-Shell Tank Ultrasonic Inspection Performance Specification, Rev. 2-A, January, 1995. The inspection system is intended to provide ultrasonic (UT) and visual data to determine integrity of the Westinghouse Hanford Company (WHC) site underground waste tanks. The robotic inspection system consists of the following major sub-systems (modules) and components: Mobile control center; Deployment module; Cable management assembly; Robot mechanism; Ultrasonic testing system; Visual testing system; Pneumatic system; Electrical system; and Control system

  4. Diesel auto-thermal reforming for solid oxide fuel cell systems: Anode off-gas recycle simulation

    Highlights: • Diesel reformation with solid oxide fuel cell anode off-gas recycle simulation. • Thermodynamic modeling complemented experiments to optimize fuel reformation. • Comparisons of diesel reforming with anode off-gas recycle and direct water/air. • Single-tube reformer with Rh/CeO2–ZrO2 catalyst for diesel autothermal reforming. - Abstract: Diesel auto-thermal reformation (ATR) with solid oxide fuel cell (SOFC) stack anode off-gas recycle (AOGR) has a reliable steam recycling supply to the reformer and improves overall system efficiency. For the lab-scale experiments, it is crucial to develop a cost-effective technique to simulate the AOGR effects on hydrocarbon catalytic reformation due to safety and cost considerations of providing the full recycle composition in the absence of fuel cell stack hardware. The present work combined thermodynamic modeling and experiments to compare diesel ATR performance with AOGR and with direct water/air inputs as recycle simulation (RS). Variations of input water and air flow were employed to simulate the effects of recycle gas on syngas production and to analyze the contribution of recycled CO2 dry reforming. A single-tube reformer with Rh/CeO2–ZrO2 catalyst was used for diesel ATR experiments with a photo-acoustic micro-soot meter to monitor carbon formation in the reformate effluent. Experimental results suggest water and air input flows are two key variables to simulate performance of diesel ATR with AOGR, whereas gas hourly space velocity and reforming temperature do not significantly affect the recycle simulation process in syngas production. The optimum AOGR ratio for an SOFC stack with 65% fuel utilization was identified as 45% for diesel ATR to achieve maximum syngas production and reforming efficiency with a given input air flow

  5. Present status and problems of conventional off-gas cleaning system

    The off-gas from reprocessing dissolution process contains volatile radioactive nuclides such as H-3, Kr-85, I-129 and C-14. The establishment of the method for removing or fixing them in order to prevent the release into environment is a social concern. The study group investigated the present status of the research and development on the volatile nuclides from the generation to the disposal, and attempted to set up the off-gas cleaning system which is considered to be more rational. It is important that the dissolution off-gas cleaning system is composed of the processes which are highly safe and reliable, economical and simple. It is necessary to pay attention to use the techniques of high reliability, to remove strongly corrosive nuclides such as iodine at the first step, to make the system into a continuous type or close to it to prevent the accumulation of radioactive substances, to avoid high temperature, high pressure operation as far as possible, to avoid the use of toxic and highly explosive chemical substances and to make the process flexible so as to be able to cope with the variation of operational condition. From these viewpoints, the existing off-gas cleaning system was examined, and the plan of its improvement was proposed as a total off-gas cleaning system. (Kako, I.)

  6. Detailed Design Data Package item 3.9a: Cadmium buildup in off-gas lines

    Waste currently stored at the Hanford Reservation in underground double-shell and single-shell tanks is being considered for vitrification and disposal. To achieve this, Hanford is conducting a Hanford Waste Vitrification Plant Technology Development Project melter campaign. In this campaign, a requirement was identified to quantify the amount of cadmium depositing in the off-gas line between the liquid-fed ceramic melter and the submerged bed scrubber. This issue of cadmium volatility was raised due to the limited data on cadmium volatility in HLW vitrification. Prior to the start of slurry processing, the off-gas line sections were removed and inspects. Any pre-existing deposits were removed. Following the melter campaign, the lines were again removed and solids deposits were sampled and the quantity of deposits were estimated. The data presented in this package include chemical analysis of feed, glass, line deposits, in-ling off-gas stream, and SBS condensate samples. Process data includes melter feeding and glass production rates, off- gas flow rate, and plenum and off-gas stream temperatures

  7. Organic iodine removal from simulated dissolver off-gas streams using silver-exchanged mordenite

    The removal of methyl iodide by absorption onto silver mordenite was studied using a simulated off-gas from the fuel dissolution step of a nuclear fuel reprocessing plant. The methyl iodide absorption of silver mordenite was examined for the effects of NO/sub x/, humidity, iodine concentration, filter temperature, and filter pretreatment. The highest iodine loading achieved in these tests has been 34 mg CH3I per g of substrate, approximately five times less than the elemental iodine loadings. Results indicate that a filter operating at a temperature of 1500C obtained higher iodine loadings than a similar filter operating at 1000C. Pretreatment of the sorbent bed with hydrogen, rather than dry air, at a temperature of 2000C also improved the loading. Variations in the methyl iodide concentration had minimal effects on the overall loading. Filters exposed to moist air streams attained higher loadings than those in contact with dry air. A study of the regeneration characteristics of silver mordenite indicates limited adsorbent capacity after complete removal of the iodine with 4% hydrogen in the regeneration gas stream at 5000C. 9 figures

  8. Self absorption and geometric correction factors for reactor off-gas samples relative to NBS standards

    Although they can be counted in identical bottles using identical counting systems, real gas samples differ from the NBS solution standards (e.g., mock reactor off-gas) in two respects--geometry and self absorption. Because both detector and source are real and finite, the simple ''narrow beam'' linear attenuation coefficient approximations currently used in the industry are quite inadequate for correction. Accordingly, the well-tested, complete-analog program, BIM 130, was used to compute the fraction of photons, and the photon energy spectra, reaching typical detectors used in the industry. Using this method, it was possible to correct the given NBS standard activity to its effective activity relative to a gas sample in an identical bottle. Factors were much closer to unity than predictions based on ''narrow beam'' linear attenuation coefficient approximations. At 80 keV, for example, such approximations gave 0.76, whereas the factor proved to be 1.03 for a 3'' x 3'' NaI(Tl) crystal and a 3 cm distance. Results are presented for various gamma energies of interest from 80 keV to 1,830 keV, and for the commonly used industrial distances of 3, 10, and 30 cm from the bottom of the sample bottle to the top of the detector container. Complete spectra for photons entering the detectors, as well as factors derived from these for typical NaI(Tl) and Ge(Li) detector resolutions, are given

  9. Performance testing With JMeter 29

    Erinle, Bayo

    2013-01-01

    Performance Testing With JMeter 2.9 is a standard tutorial that will help you polish your fundamentals, guide you through various advanced topics, and along the process help you learn new tools and skills.This book is for developers, quality assurance engineers, testers, and test managers new to Apache JMeter, or those who are looking to get a good grounding in how to effectively use and become proficient with it. No prior testing experience is required.

  10. Development of the krypton absorption in liquid carbon dioxide (KALC) process for HTGR off-gas reprocessing

    Reprocessing of High-Temperature Gas-Cooled Reactor (HTGR) fuel involves burning of the graphite-matrix elements to release the fuel for recovery purposes. The resulting off-gas is primarily CO2 with residual amounts of N2, O2, and CO, together with fission products. Trace quantities of krypton-85 must be recovered in a concentrated form from the gas stream, but processes commonly employed for rare gas removal and concentration are not suitable for use with off-gas from graphite burning. The KALC (Krypton Absorption in Liquid CO2) process employs liquid CO2 as a volatile solvent for the krypton and is, therefore, uniquely suited to the task. Engineering development of the KALC process is currently under way at the Oak Ridge National Laboratory (ORNL) and the Oak Ridge Gaseous Diffusion Plant (ORGDP). The ORNL system is designed for close study of the individual separation operations involved in the KALC process, while the ORGDP system provides a complete pilot facility for demonstrating combined operations on a somewhat larger scale. Packed column performance and process control procedures have been of prime importance in the initial studies. Computer programs have been prepared to analyze and model operational performance of the KALC studies, and special sampling and in-line monitoring systems have been developed for use in the experimental facilities. (U.S.)

  11. Team Performance with Test Scores

    Kleinberg, Jon; Raghu, Maithra

    2015-01-01

    Team performance is a ubiquitous area of inquiry in the social sciences, and it motivates the problem of team selection -- choosing the members of a team for maximum performance. Influential work of Hong and Page has argued that testing individuals in isolation and then assembling the highest-scoring ones into a team is not an effective method for team selection. For a broad class of performance measures, based on the expected maximum of random variables representing individual candidates, we...

  12. The off-gas cleaning system of the INER'S incinerator in Taiwan, Republic of China

    The incinerator designed and constructed by INER has been operated since 1976. It handles the radioactive wastes from INER and Taiwan Power Company. The dry off-gas cleaning system consists of two types of cyclones in series, two bag filters and two HEPA filters in parallel. One of each filter sets is provided as stand-by. The first cyclone is lined with refractory material and operated at 11000C to treat the high-temperature off-gas directly from the top of the incinerator. The off-gas of the first cyclone is mixed with ambient air for controlling the gas flow rate and reducing its temperature to about 2000C. After 10 years' operation, it is found that the radioactivity released in the gaseous effluent meets the MPC air requirement and the implementation of the refractory-lined cyclone extends the service lives of bag filter as well as HEPA filter

  13. Design of an engineering scale off-gas trapping system at KAERI

    KAERI has been developing a high temperature voloxidation process as a head-end process for pyroprocessing technology. This process may remove volatile fission products (Kr, H-3, C-14, I-129 etc.) and other semi-volatiles (Cs, Tc, Te, Mo etc.) that are problematic in the main pyroprocess. Engineering off-gas treatment system was designed to recover the primary semi-volatile products (Cs, Tc, Te, Mo, I, etc.) released from simulated reagents during the high temperature voloxidation process. The off-gas trapping system will trap selectively gaseous nuclides evolved from high temperature voloxidation process, this will also reduce the high level waste due to the separation of Cs. This paper describes design of the off-gas treatment systems for high temperature voloxidation process. Design of an engineering-scale semi-volatile trapping system of 50 kg-SF/batch was done. The gaseous waste arising for off-gas trapping system was estimated considering the release rate of each target fission product. Each unit process in the trapping system is arranged to effectively remove the species of interest by considering the chemical properties of the target fission products to be trapped. Cs and Rb are trapped on a fly ash filter at around 900degC. Tc(Re), Te, Se, and Mo on a calcium filter are trapped at about 700degC, and I on a AgX is trapped at about 250degC. Off-gas trapping system was designed based on the design requirements such as trapping media, fission products to be trapped, design temperatures of the trapping units, optimum operation temperatures and specifications of the filters. Off-gas trapping system was also designed based on the design requirements such as remote operability, accessibility, and flexibility of instrument, separability of trapping basket, material of instrument. (author)

  14. Trends in the design and operation of off-gas cleaning systems in nuclear facilities

    Trends in the design and operation of off-gas cleaning systems in nuclear facilities reflect the normal development by manufacturers of new and improved equipment and the demand for more safety, greater reliability, and higher collection efficiency as an aftermath of the well publicized accident at Three Mile Island. The latter event has to be viewed as a watershed in the history of off-gas treatment requirements for nuclear facilities. It is too soon to predict what these will be with any degree of assurance but it seems reasonable to expect greatly increased interest in containment venting systems for light water and LMFBR nuclear power reactors and more stringent regulatory requirements for auxiliary off-gas cleaning systems. Although chemical and waste handling plants share few characteristics with reactors other than the presence of radioactive materials, often in large amounts, tighter requirements for handling reactor off-gases will surely be transferred to other kinds of nuclear facilities without delay. Currently employed nuclear off-gas cleaning technology was largely developed and applied during the decade of the 1950s. It is regrettable that the most efficient and most economical off-gas treatment systems do not always yield the best waste forms for storage or disposal. It is even more regrettable that waste management has ceased to be solely a technical matter but has been transformed instead into a highly charged political posture of major importance in many western nations. Little reinforcement has been provided by detailed studies of off-gas treatment equipment failures that show that approximately 13% of over 9000 licensee event reports to the United States Nuclear Regulatory Commission pertained to failures in ventilating and cleaning systems and their monitoring instruments

  15. Performance testing of extremity dosimeters

    The Health Physics Society Standing Committee (HPSSC) Working Group on Performance Testing of Extremity Dosimeters has issued a draft of a proposed standard for extremity dosimeters. The draft standard proposes methods to be used for testing dosimetry systems that determine occupational radiation dose to the extremities and the performance criterion used to determine compliance. The draft standard has been evaluated by testing the performance of existing processors of extremity dosimeters against the standard's proposed criterion. The proposed performance criterion is: absolute value of B + S ≤ 0.35, where B is the bias (calculated as the average of the performance quotients) of 15 dosimeter measurements and S is the standard deviation of the performance quotients. Dosimeter performance was tested in seven irradiation categories: low-energy photons (general and accident dosimetry), high-energy photons (general and accident dosimetry), beta particles, neutrons, and a mixture category. Twenty-one types of extremity dosimeters (both finger ring and wrist/ankle dosimeters) were received from 11 processors. The dosimeters were irradiated by the Pacific Northwest Laboratory (PNL) to specific dose levels in one or more of the seven categories as specified in the draft standard and were returned to the processors. The processors evaluated the doses and returned the results to PNL for analysis. The results were evaluated against the performance criterion specified in the draft standard. The results indicate that approximately 60% of both the finger ring and the wrist/ankle dosimeters met the performance criterion. Two-thirds of the dosimeters that did not meet the performance criterion had large biases (ranging from 0.25 to 0.80) but small standard deviations (less than 0.15). 21 refs., 3 figs., 20 tabs

  16. Behaviour of selected contaminants in spray calciner/in-can melter waste vitrification off-gas

    Product loss from spray calciner/in-can melter vitrification of high-level wastes was evaluated with respect to volatile, gaseous and particulate materials. Investigations of the off-gases in a non-radioactive system are discussed, including gaseous constituents, particulate size distributions and loadings. Monitoring of gases leaving the off-gas system during spray calcination/in-can melting of radioactive waste gave material concentrations and material forms in the gases. The most significant conclusion drawn from these studies was that particulate loss accounts for a significant portion of the fission products in the off-gas system. (author)

  17. Removal of CO2 in closed loop off-gas treatment systems

    A closed loop test system has been installed at Argonne National Laboratory (ANL) to demonstrate off-gas treatment, absorption, and purification systems to be used for incineration and vitrification of hazardous and mixed waste. Closed loop systems can virtually eliminate the potential for release of hazardous or toxic materials to the atmosphere during both normal and upset conditions. In initial tests, a 250,000 Btu/h (75 kW thermal) combustor was operated in an open loop to produce a combustion product gas. The CO2 in these tests was removed by reaction with a fluidized bed of time to produce CaCO3. Subsequently, recirculation system was installed to allow closed loop operation with the addition of oxygen to the recycle stream to support combustion. Commercially marketed technologies for removal of CO2 can be adapted for use on closed loop incineration systems. The paper also describes the Absorbent Solution Treatment (AST) process, based on modifications to commercially demonstrated gas purification technologies. In this process, a side loop system is added to the main loop for removing CO2 in scrubbing towers using aqueous-based CO2 absorbents. The remaining gas is returned to the incinerator with oxygen addition. The absorbent is regenerated by driving off the CO2 and water vapor, which are released to the atmosphere. Contaminants are either recycled for further treatment or form precipitates which are removed during the purification and regeneration process. There are no direct releases of gases or particulates to the environment. The CO2 and water vapor go through two changes of state before release, effectively separating these combustion products from contaminants released during incineration. The AST process can accept a wide range of waste streams. The system may be retrofitted to existing Facilities or included in the designs for new installations

  18. LFK, FORTRAN Application Performance Test

    1 - Description of program or function: LFK, the Livermore FORTRAN Kernels, is a computer performance test that measures a realistic floating-point performance range for FORTRAN applications. Informally known as the Livermore Loops test, the LFK test may be used as a computer performance test, as a test of compiler accuracy (via checksums) and efficiency, or as a hardware endurance test. The LFK test, which focuses on FORTRAN as used in computational physics, measures the joint performance of the computer CPU, the compiler, and the computational structures in units of Mega-flops/sec or Mflops. A C language version of subroutine KERNEL is also included which executes 24 samples of C numerical computation. The 24 kernels are a hydrodynamics code fragment, a fragment from an incomplete Cholesky conjugate gradient code, the standard inner product function of linear algebra, a fragment from a banded linear equations routine, a segment of a tridiagonal elimination routine, an example of a general linear recurrence equation, an equation of state fragment, part of an alternating direction implicit integration code, an integrate predictor code, a difference predictor code, a first sum, a first difference, a fragment from a two-dimensional particle-in-cell code, a part of a one-dimensional particle-in-cell code, an example of how casually FORTRAN can be written, a Monte Carlo search loop, an example of an implicit conditional computation, a fragment of a two-dimensional explicit hydrodynamics code, a general linear recurrence equation, part of a discrete ordinates transport program, a simple matrix calculation, a segment of a Planck distribution procedure, a two-dimensional implicit hydrodynamics fragment, and determination of the location of the first minimum in an array. 2 - Method of solution: CPU performance rates depend strongly on the maturity of FORTRAN compiler machine code optimization. The LFK test-bed executes the set of 24 kernels three times, resetting the DO

  19. Performance Testing of Cutting Fluids

    Belluco, Walter

    The importance of cutting fluid performance testing has increased with documentation requirements of new cutting fluid formulations based on more sustainable products, as well as cutting with minimum quantity of lubrication and dry cutting. Two sub-problems have to be solved: i) which machining t...

  20. Removal of I, Rn, Xe and Kr from off gas streams using PTFE membranes

    Siemer, Darryl D.; Lewis, Leroy C.

    1990-01-01

    A process for removing I, R, Xe and Kr which involves the passage of the off gas stream through a tube-in-shell assembly, whereby the tubing is a PTFE membrane which permits the selective passages of the gases for removing and isolating the gases.

  1. DWPF Melter Off-Gas Flammability Assessment for Sludge Batch 9

    Choi, A. S. [Savannah River Site (SRS), Aiken, SC (United States)

    2016-07-11

    The slurry feed to the Defense Waste Processing Facility (DWPF) melter contains several organic carbon species that decompose in the cold cap and produce flammable gases that could accumulate in the off-gas system and create potential flammability hazard. To mitigate such a hazard, DWPF has implemented a strategy to impose the Technical Safety Requirement (TSR) limits on all key operating variables affecting off-gas flammability and operate the melter within those limits using both hardwired/software interlocks and administrative controls. The operating variables that are currently being controlled include; (1) total organic carbon (TOC), (2) air purges for combustion and dilution, (3) melter vapor space temperature, and (4) feed rate. The safety basis limits for these operating variables are determined using two computer models, 4-stage cold cap and Melter Off-Gas (MOG) dynamics models, under the baseline upset scenario - a surge in off-gas flow due to the inherent cold cap instabilities in the slurry-fed melter.

  2. Characterization of magnesium phosphate ceramics incorporating off-gas filters

    Radioactive cesium (Cs-137) and technetium (Tc-99) are discharged from the spent fuel as gaseous forms during the head-end process in pyroprocess. These off-gases are safely trapped via porous ceramic filters made of fly ash and calcium based material. Spent filters have to be treated, converted into proper waste forms in order to be disposed safely at a repository. Conventional technology used to make waste forms such as vitrification requires high temperature and complex process. In this study, we report a promising method to stabilize spent filters containing cesium and technetium using magnesium phosphate ceramics. Simulated spent filters were fabricated by vaporizing nonradioactive cesium and rhenium (a surrogate of Tc) through the voloxidizer. The crushed filters were mixed with raw materials of magnesium phosphate ceramics, to be stabilized in the phosphate ceramic matrix. Characterization of the waste forms was made by the compressive strength test, apparent porosity, XRD analysis, and SEM analysis. The sample containing filters showed the excellent mechanical property, with the highest compressive strength of 38.1 MPa in the sample with 30 wt% of Cs-filter. Microstructural analysis suggests that wastes are embedded in the crystalline phase formed by an acid-base reaction. (author)

  3. Ecotoxicological testing of performance fluids

    Källqvist, T.

    1990-01-01

    Two performance fluids were tested for toxic effects on marine algae and biological degradability. A fluid based on mineral oil was readily degradable (98% DOC removal in 28 days) while a either based oil degraded more slowly (56 % DOC removal in 28 days). The toxicity of both fluids was tested after emulsification of the oils in water and separating the oil and water phase after equilibration. The EC50 values obtained with this approach were 8.15 g/l for the oil based fluid and 116 g/l for t...

  4. Reflectors for SAR performance testing.

    Doerry, Armin Walter

    2008-01-01

    Synthetic Aperture Radar (SAR) performance testing and estimation is facilitated by observing the system response to known target scene elements. Trihedral corner reflectors and other canonical targets play an important role because their Radar Cross Section (RCS) can be calculated analytically. However, reflector orientation and the proximity of the ground and mounting structures can significantly impact the accuracy and precision with which measurements can be made. These issues are examined in this report.

  5. Analysis and efficiency enhancement of a boil-off gas reliquefaction system with cascade cycle on board LNG carriers

    Highlights: • An LNG boil-off gas reliquefaction plant on board LNG carriers is improved. • Relevant improvements deals with a study on BOG–C2H4–C3H6 cascade system. • A novel design is proposed to reduce power consumption and COP improvement. • Efficiency improvement by BOG cold energy recovery and compression heat rejection. • Efficiency increase operating in parallel with the engine fuel gas supply system. - Abstract: In this paper, an LNG boil-off gas (BOG) reliquefaction plant operating in accordance with cascade vapor compression cycles, using propylene and ethylene as refrigerants, on board LNG carriers is investigated. As consequence of the analysis results, a new and original design is proposed to reduce power consumption and improve its exergy efficiency. Through energy and exergy analysis, a thermodynamic model is carried out to analyse and evaluate operating conditions as well as to obtain performance values such as the Coefficient of Performance (COP), exergy efficiency, irreversibilities and specific energy consumption. The thermodynamic analysis is performed using the Engineering Equation Solver (EES) software environment. The results of the improved design implemented on the reliquefaction plant for LNG tank conditions of -160.82 °C, a plant BOG input temperature of −125 °C and 25 °C seawater, give COP values of 0.22 and an exergetic efficiency of 37%, such values being 22.22% and 19.35% greater than the original design. The specific energy consumption decreases 14.66% to 0.64 kW h per kg/s of natural BOG. The proposal for improving efficiency is founded on BOG cold energy recovery and BOG compression heat rejection with cooling water in the intercoolers

  6. Off-gas purification in waste incineration plants: Wet scrubbing solution; Abgasreinigung in Muellverbrennungsanlagen: Nass-Wasch-Loesung

    Johansson, T. [ABB Vaaxjoo (Sweden); Eriksson, J. [ABB Vaaxjoo (Sweden); Burdis, V. [ABB Umwelttechnik GmbH, Butzbach (Germany)

    1995-08-01

    The article describes an off-gas purification process for a waste incineration plant. It is a two-stage process. In the first alkaline stage, sulphur dioxide is removed with the aid of sodium hydroxide. In the second stage, calcium hydroxide is added to the solution, and gypsum is produced. The wet scrubber technology was installed and tested in a waste incineration plant in Denmark. (orig.) [Deutsch] Der vorliegende Artikel beschreibt die Abgasreinigung in einer Muellverbrennungsanlage. Mit dem zweistufigen Prozess wird in einem Nasswaescher zunaechst in einer alkalischen Stufe Schwefeldioxid mit Hilfe von Natriumhydroxid entfernt. In einer nachgeschalteten zweiten Stufe wird zu der abgezogenen Loesung des Waeschers Calciumhydroxid gegeben und Gips produziert. Diese Nasswaeschertechnik wurde in einer Muellverbrennungsanlage in Daenemark installiert und erfolgreich getestet. (orig.)

  7. Development of a hydrogen mordenite sorbent for the capture of krypton from used nuclear fuel reprocessing off-gas streams

    A novel new sorbent for the separation of krypton from off-gas streams resulting from the reprocessing of used nuclear fuel has been developed and evaluated. A hydrogen mordenite powder was successfully incorporated into a macroporous polymer binder and formed into spherical beads. The engineered form sorbent retained the characteristic surface area and microporosity indicative of mordenite powder. The sorbent was evaluated for krypton adsorption capacities utilizing thermal swing operations achieving capacities of 100 mmol of krypton per kilogram of sorbent at a temperature of 191 K. A krypton adsorption isotherm was also obtained at 191 K with varying krypton feed gas concentrations. Adsorption/desorption cycling effects were also evaluated with results indicating that the sorbent experienced no decrease in krypton capacity throughout testing. (author)

  8. The effect of pranayama on test anxiety and test performance

    Azadeh Nemati

    2013-01-01

    Conclusions: Pranayama seems to have a significant positive effect on test anxiety and test performance. It could be used as an important technique by students prior to their examinations, to reduce their test anxiety and increase their test performance.

  9. Analysis of fire and smoke threat to off-gas HEPA filters in a transuranium processing plant

    The author performed an analysis of fire risk to the high-efficiency particulate air (HEPA) filters that provide ventilation containment for a transuranium processing plant at the Oak Ridge National Laboratory. A fire-safety survey by an independent fire-protection consulting company had identified the HEPA filters in the facility's off-gas containment ventilation system as being at risk from fire effects. Independently studied were the ventilation networks and flow dynamics, and typical fuel loads were analyzed. It was found that virtually no condition for fire initiation exists and that, even if a fire started, its consequences would be minimal as a result of standard shut-down procedures. Moreover, the installed fire-protection system would limit any fire and thus would further reduce smoke or heat exposure to the ventilation components. 4 references, 4 figures, 5 tables

  10. Design and operational experience with the off-gas cleaning system of the Seibersdorf incinerator plant

    After a description of the design and the construction principles of the incinerator building, the furnace and its attached auxilary devices are explained. The incinerator is layed out for low level wastes. It has a vertical furnace, operates with discontinuous feeding for trashes with heat-values between 600 and 10000 kcal/kg waste. The maximum throughput ammounts 40 kg/h. The purification of the off-gas is guaranteed by a multistage filter system: 2 stages with ceramic candles, an electrostatic filter and a HEPA-filter system. The control of the off-gas cleaning is carried out by a stack instrumentation, consisting of an aerosol-, gas-, iodine- and tritium-monitor; the building is surveilled by doserate- and aerosolmonitors. Finally the experiences of the first year of operation and the main problems in running the plant are described. (Author)

  11. The integrated melter off-gas treatment systems at the West Valley Demonstration Project

    The West Valley Demonstration project was established by an act of Congress in 1980 to solidify the high level radioactive liquid wastes produced from operation of the Western New York Nuclear Services Center from 1966 to 1972. The waste will be solidified as borosilicate glass. This report describes the functions, the controlling design criteria, and the resulting design of the melter off-gas treatment systems

  12. Test Performance Related Dysfunctional Beliefs

    Recep TÜTÜNCÜ

    2012-11-01

    Full Text Available Objective: Examinations by using tests are very frequently used in educational settings and successful studying before the examinations is a complex matter to deal with. In order to understand the determinants of success in exams better, we need to take into account not only emotional and motivational, but also cognitive aspects of the participants such as dysfunctional beliefs. Our aim is to present the relationship between candidates’ characteristics and distorted beliefs/schemata just before an examination. Method: The subjects of the study were 30 female and 30 male physicians who were about to take the medical specialization exam (MSE in Turkey. Dysfunctional Attitude Scale (DAS and Young Schema Questionnaire Short Form (YSQ-SF were applied to the subjects. The statistical analysis was done using the F test, Mann-Whitney, Kruskal-Wallis, chi-square test and spearman’s correlation test. Results: It was shown that some of the DAS and YSQ-SF scores were significantly higher in female gender, in the group who could not pass the exam, who had repetitive examinations, who had their first try taking an examination and who were unemployed at the time of the examination. Conclusion: Our findings indicate that candidates seeking help before MSE examination could be referred for cognitive therapy or counseling even they do not have any psychiatric diagnosis due to clinically significant cognitive distortion. Measurement and treatment of cognitive distortions that have negative impact on MSE performance may improve the cost-effectiveness and mental well being of the young doctors.

  13. Treatment of off-gas evolved from thermal decomposition of sludge waste

    Korea Atomic Energy Research Institute (KAERI) started a decommissioning program of a uranium conversion plant. The treatment of the sludge waste, which was generated during the operation of the plant, is one of the most important tasks in the decommissioning program of the plant. The major compounds of sludge waste are nitrate salts and uranium. The sludge waste is denitrated by thermal decomposition. The treatment of off-gas evolved from the thermal decomposition of nitrate salts in the sludge waste is investigated. The nitrate salts in the sludge were decomposed in two steps: the first decomposition is due to the ammonium nitrate, and the second is due to the sodium and calcium nitrate and calcium carbonate. The components of off-gas from the decomposition of ammonium nitrate at low temperature are NH3, N2O, NO2, and NO. In addition, the components from the decomposition of sodium and calcium nitrate at high temperature are NO2 and NO. Off-gas from the thermal decomposition is treated by the catalytic oxidation of ammonia and selective catalytic reduction (SCR). Ammonia is converted into nitrogen oxides through the oxidation catalyst and all nitrogen oxides are removed by SCR treatment besides nitrous oxide, which is greenhouse gas. An additional process is needed to remove nitrous oxide, and the feeding rate of ammonia in SCR should be controlled properly for evolved nitrogen oxides. (author)

  14. Regulatory off-gas analysis from the evaporation of Hanford simulated waste spiked with organic compounds.

    Saito, Hiroshi H; Calloway, T Bond; Ferrara, Daro M; Choi, Alexander S; White, Thomas L; Gibson, Luther V; Burdette, Mark A

    2004-10-01

    After strontium/transuranics removal by precipitation followed by cesium/technetium removal by ion exchange, the remaining low-activity waste in the Hanford River Protection Project Waste Treatment Plant is to be concentrated by evaporation before being mixed with glass formers and vitrified. To provide a technical basis to permit the waste treatment facility, a relatively organic-rich Hanford Tank 241-AN-107 waste simulant was spiked with 14 target volatile, semi-volatile, and pesticide compounds and evaporated under vacuum in a bench-scale natural circulation evaporator fitted with an industrial stack off-gas sampler at the Savannah River National Laboratory. An evaporator material balance for the target organics was calculated by combining liquid stream mass and analytical data with off-gas emissions estimates obtained using U.S. Environmental Protection Agency (EPA) SW-846 Methods. Volatile and light semi-volatile organic compounds (1 mm Hg vapor pressure) in the waste simulant were found to largely exit through the condenser vent, while heavier semi-volatiles and pesticides generally remain in the evaporator concentrate. An OLI Environmental Simulation Program (licensed by OLI Systems, Inc.) evaporator model successfully predicted operating conditions and the experimental distribution of the fed target organics exiting in the concentrate, condensate, and off-gas streams, with the exception of a few semi-volatile and pesticide compounds. Comparison with Henry's Law predictions suggests the OLI Environmental Simulation Program model is constrained by available literature data. PMID:15540577

  15. Cut performance levels and testing.

    Bennett, Bill; Moreland, Jeff

    2011-11-01

    While the ISEA performance levels and general recommendations detailed above can help tp provide guidance when selecting hand protection products, the responsibility for testing products for specific end-user applications still rests with the end user. We can indicate, for example, that a medium-weight, uncoated Kevlar glove will typically have an ISEA cut rating of 3, but we cannot say the glove will provide the level of protection needed for the range of jobs on an automobile assembly line. Another Level 3 glove might be better suited to an application the require the worker to have an oil grip. As glove manufacturers, we know gloves. We do not know the details about every workplace. We therefore, must look to our customers to provide us the properties they need for hand protection products that will sufficiently protect their workers on the job. PMID:22135955

  16. 40 CFR 60.8 - Performance tests.

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Performance tests. 60.8 Section 60.8... PERFORMANCE FOR NEW STATIONARY SOURCES General Provisions § 60.8 Performance tests. (a) Except as specified in... conduct performance test(s) and furnish the Administrator a written report of the results of...

  17. Formation rate of ammonium nitrate in the off-gas line of SRAT and SME in DWPF

    A mathematical model for the formation rate of ammonium nitrate in the off-gas line of the Sludge Receipt and Adjustment Tank (SRAT) and the Slurry Mixed Evaporator (SME) in DWPF has been developed. The formation rate of ammonium nitrate in the off-gas line depends on pH, temperature, volume and total concentration of ammonia and ammonium ion. Based on a typical SRAT and SME cycle in DWPF, this model predicts the SRAT contributes about 50 lbs of ammonium nitrate while SME contributes about 60 lbs of ammonium nitrate to the off-gas line

  18. Structure-property relationship of metal-organic frameworks (MOFs) and physisorbed off-gas radionuclides

    We report on the host-guest interactions between metal-organic frameworks (MOFs) with various profiles and highly polarizable molecules (iodine), with emphasis on identifying preferential sorption sites in these systems. Radioactive iodine 129I, along with other volatile radionuclides (3H, 14C, Xe and Kr), represents a relevant component in the off-gas resulted during nuclear fuel reprocessing. Due to its very long half-life, 15.7 x 106 years, and potential health risks in humans, its efficient capture and long-term storage is of great importance. The leading iodine capture technology to date is based on trapping iodine in silver-exchanged mordenite. Our interests are directed towards improving existent capturing technologies, along with developing novel materials and alternative waste forms. Herein we report the first study that systematically monitors iodine loading onto MOFs, an emerging new class of porous solid-state materials. In this context, MOFs are of particular interest as: (i) they serve as ideal high capacity storage media, (ii) they hold potential for the selective adsorption from complex streams, due to their high versatility and tunability. This work highlights studies on both newly developed in our lab, and known highly porous MOFs that all possess distinct characteristics (specific surface area, pore volume, pore size, and dimension of the window access to the pore). The materials were loaded to saturation, where elemental iodine was introduced from solution, as well as from vapor phase. Uptakes in the range of ∼125-150 wt% I2 sorbed were achieved, indicating that these materials outperform all other solid adsorbents to date in terms of overall capacity. Additionally, the loaded materials can be efficiently encapsulated in stable waste forms, including as low temperature sintering glasses. Ongoing studies are focused on gathering qualitative information with respect to localizing the physisorbed iodine molecules within the frameworks: X

  19. Structure-property relationship of metal-organic frameworks (MOFs) and physisorbed off-gas radionuclides.

    Nenoff, Tina Maria; Chupas, Peter J. (Argonne National Laboratory); Garino, Terry J.; Rodriguez, Mark Andrew; Chapman, Karena W. (Argonne National Laboratory); Sava, Dorina Florentina

    2010-11-01

    We report on the host-guest interactions between metal-organic frameworks (MOFs) with various profiles and highly polarizable molecules (iodine), with emphasis on identifying preferential sorption sites in these systems. Radioactive iodine 129I, along with other volatile radionuclides (3H, 14C, Xe and Kr), represents a relevant component in the off-gas resulted during nuclear fuel reprocessing. Due to its very long half-life, 15.7 x 106 years, and potential health risks in humans, its efficient capture and long-term storage is of great importance. The leading iodine capture technology to date is based on trapping iodine in silver-exchanged mordenite. Our interests are directed towards improving existent capturing technologies, along with developing novel materials and alternative waste forms. Herein we report the first study that systematically monitors iodine loading onto MOFs, an emerging new class of porous solid-state materials. In this context, MOFs are of particular interest as: (i) they serve as ideal high capacity storage media, (ii) they hold potential for the selective adsorption from complex streams, due to their high versatility and tunability. This work highlights studies on both newly developed in our lab, and known highly porous MOFs that all possess distinct characteristics (specific surface area, pore volume, pore size, and dimension of the window access to the pore). The materials were loaded to saturation, where elemental iodine was introduced from solution, as well as from vapor phase. Uptakes in the range of {approx}125-150 wt% I2 sorbed were achieved, indicating that these materials outperform all other solid adsorbents to date in terms of overall capacity. Additionally, the loaded materials can be efficiently encapsulated in stable waste forms, including as low temperature sintering glasses. Ongoing studies are focused on gathering qualitative information with respect to localizing the physisorbed iodine molecules within the frameworks: X

  20. Stereotype Threat, Test Anxiety, and Mathematics Performance

    Tempel, Tobias; Neumann, Roland

    2014-01-01

    We investigated the combined effects of stereotype threat and trait test anxiety on mathematics test performance. Stereotype threat and test anxiety interacted with each other in affecting performance. Trait test anxiety predicted performance only in a diagnostic condition that prevented stereotype threat by stereotype denial. A state measure of…

  1. Trinity Acceptance Tests Performance Summary.

    Rajan, Mahesh [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-12-01

    Ensuring Real Applications perform well on Trinity is key to success. Four components: ASC applications, Sustained System Performance (SSP), Extra-Large MiniApplications problems, and Micro-benchmarks.

  2. A study of mineral zeolite as a nitrogen oxides adsorbent for dissolver off-gas treatment

    In the nuclear fuel reprocessing plant, dissolver off-gas (DOG) is supposed to include nitrogen oxides (NOX) during the operation. An adsorption process by mineral zeolite has been studied for DOG treatment that follows a dehydration and iodine removal process. According to the results, the characteristics of the mineral zeolite hydrogenated by 1 N HCl are very favorable for this purpose. As for the actual operation, a small fraction of iodine is supposed to penetrate the I/sub 2/ removal process to the NOX adsorption process. No degradation has been observed for the NOX adsorption of mineral zeolite by the presence of I/sub 2/

  3. Critique of Hanford Waste Vitrification Plant off-gas sampling requirements

    Off-gas sampling and monitoring activities needed to support operations safety, process control, waste form qualification, and environmental protection requirements of the Hanford Waste Vitrification Plant (HWVP) have been evaluated. The locations of necessary sampling sites have been identified on the basis of plant requirements, and the applicability of Defense Waste Processing Facility (DWPF) reference sampling equipment to these HWVP requirements has been assessed for all sampling sites. Equipment deficiencies, if present, have been described and the bases for modifications and/or alternative approaches have been developed

  4. Modelling of Boil-Off Gas in LNG Tanks: A Case Study

    Sheikh Zahidul Islam; Ebenezer Adom; Xianda Ji

    2010-01-01

    This paper focuses on the effect of pressure and heat leakages on Boil-off Gas (BOG) in Liquefied Natural Gas (LNG) tanks. The Lee-Kesler-Plocker (LKP) and the Starling modified Benedict-Webb-Rubin (BWRS) empirical models were used to simulate the compressibility factor, enthalpy and hence heat leakage at various pressures to determine the factors that affect the BOG in typical LNG tanks of different capacities. Using a case study data the heat leakage of 140,000kl, 160,00kl, 180,000kl and 20...

  5. Operator performance in non-destructive testing: A study of operator performance in a performance test

    Enkvist, J.; Edland, A.; Svenson, Ola [Stockholm Univ. (Sweden). Dept. of Psychology

    2000-05-15

    In the process industries there is a need of inspecting the integrity of critical components without disrupting the process. Such in-service inspections are typically performed with non-destructive testing (NDT). In NDT the task of the operator is to (based on diagnostic information) decide if the component can remain in service or not. The present study looks at the performance in NDT. The aim is to improve performance, in the long run, by exploring the operators' decision strategies and other underlying factors and to this way find out what makes some operators more successful than others. Sixteen operators performed manual ultrasonic inspections of four test pieces with the aim to detect (implanted) cracks. In addition to these performance demonstration tests (PDT), the operators performed independent ability tests and filled out questionnaires. The results show that operators who trust their gut feeling more than the procedure (when the two come to different results) and that at the same time have a positive attitude towards the procedure have a higher PDT performance. These results indicate the need for operators to be motivated and confident when performing NDT. It was also found that the operators who performed better rated more decision criteria higher in the detection phase than the operators who performed worse. For characterizing it was the other way around. Also, the operators who performed better used more time, both detecting and characterizing, than the operators who performed worse.

  6. Operator performance in non-destructive testing: A study of operator performance in a performance test

    In the process industries there is a need of inspecting the integrity of critical components without disrupting the process. Such in-service inspections are typically performed with non-destructive testing (NDT). In NDT the task of the operator is to (based on diagnostic information) decide if the component can remain in service or not. The present study looks at the performance in NDT. The aim is to improve performance, in the long run, by exploring the operators' decision strategies and other underlying factors and to this way find out what makes some operators more successful than others. Sixteen operators performed manual ultrasonic inspections of four test pieces with the aim to detect (implanted) cracks. In addition to these performance demonstration tests (PDT), the operators performed independent ability tests and filled out questionnaires. The results show that operators who trust their gut feeling more than the procedure (when the two come to different results) and that at the same time have a positive attitude towards the procedure have a higher PDT performance. These results indicate the need for operators to be motivated and confident when performing NDT. It was also found that the operators who performed better rated more decision criteria higher in the detection phase than the operators who performed worse. For characterizing it was the other way around. Also, the operators who performed better used more time, both detecting and characterizing, than the operators who performed worse

  7. Confidence and Cognitive Test Performance

    Stankov, Lazar; Lee, Jihyun

    2008-01-01

    This article examines the nature of confidence in relation to abilities, personality, and metacognition. Confidence scores were collected during the administration of Reading and Listening sections of the Test of English as a Foreign Language Internet-Based Test (TOEFL iBT) to 824 native speakers of English. Those confidence scores were correlated…

  8. A Formal Approach to Protocol Performance Testing

    XU Mingwei; WU Jianping

    1999-01-01

    This paper proposes a formal approach to protocol performance testing based on the extended concurrent TTCN. To meet the needs of protocol performance testing, concurrent TTCN is extended, and the extended concurrent TTCN's operational semantics is defined in terms of Input-Output Labeled Transition System. An architecture design of protocol performance test system is described, and an example of test cases and its test resultare given.

  9. Summary of functional and performance test procedures

    Mitzel, Jens; Gülzow, Erich; Friedrich, K. Andreas; Araya, Samuel; Kaer, Soeren

    2015-01-01

    The EU-funded research project Stack-Test has developed different test procedures for the functional and performance characterization of PEMFC stacks. The different test procedures are pointed out in the current form and the example Performance Mapping Test program is introduced.

  10. Canadian development program for off-gas management in nuclear facilities

    The Canadian program for the development and evaluation of processes and technology for the separation and containment of radioactive species in off-gases is directed towards the following specific aspects: 1) assessment of available treatment technology and evaluation of future clean-up requirements; 2) development and engineering evaluation, under realistic conditions, of promising new processes that would be inherently simpler and safer; and 3) specification of off-gas emission control systems for future nuclear facilities based on the most favourable technology. The program is being carried out by Atomic Energy of Canada Limited in collaboration with the electrical utility, Ontario Hydro, and selected Canadian universities. A brief description is presented of methods for removing tritium and carbon-14 from the moderator systems of CANDU power reactors, methods for removing iodine from the off-gases of a molybdenum-99 production facility at the Chalk River Nuclear Laboratories, and procedures for monitoring the off-gas effluent composition in the Thorium Fuel Reprocessing Experiment (TFRE) facility at the Whiteshell Nuclear Research Establishment

  11. The performance tests used the water scrubber for ruthenium rejection

    LEDF (Large Equipment Dismantling Facility) will be constructed for the purpose of decontaminating the high level α solid waste generated in oarai engineering center of JNC. And, main processing process of LEDF is incineration and melting system. LEDF will be intended to reduce the secondary waste that occurs along with the operation of the off gas processing equipment of incineration and melting system. It assumed that we are able to eliminate the adsorption tower using silica gel, if the decontamination factor to volatile ruthenium is able to expect in the packed scrubber that is established to remove harmful gas. Thereupon, we carried out this tests that eliminates the adsorption tower and reduces the secondary waste. The decontamination factor (DF) to the volatile ruthenium by the water scrubber is confirmed in the established institution which is in Tokai Works. However, decontamination factor differs and depends on the ruthenium concentration, harmful gas concentration, washing method and also washing condition. Also, the DF value to the volatile ruthenium in the off gas that occurs from incineration and melting system is obtained, does not exist under the same condition as LEDF. Therefore, the decontamination factor to the volatile ruthenium of the packed scrubber under the operating condition of LEDF is confirmed by this test. The main result of this study is as follows. (1) In the examination of the test device specification, the packed scrubber design method was investigated. And, the test device the maintained the resemblance nature with a real machine was produced on the basis of this result. (2) In the result of the ruthenium occurrence condition confirmation test, it was confirmed that the test condition such as the kind of the oxidizer, hold temperature of the oxidization reaction container that produce volatile ruthenium continuously. (3) In the result of the occurrence temperature influence confirmation test, it was confirmed that the ruthenium

  12. Ecotoxicological testing of performance fluids

    The report deals with a project comprising the testing of drilling fluids concerning ecotoxicology, biological degradation, and toxicity. Two types of drilling fluids were tested for toxic effects on marine algae and biological degradability. A fluid based on mineral oil was readily degradable (98% DOC removal in 28 days) while an ether based oil degraded more slowly (56% DOC removal in 28 days). The toxicity of both fluids was tested after emulsification of the oils in water and separating the oil and water phase after equilibration. The EC50 values obtained with this approach were 8.15 g/l for the oil based fluid and 116 g/l for the ether fluid. 9 figs., 8 tabs

  13. NOx Abatement Pilot Plant 90-day test results report

    High-level radioactive liquid wastes produced during nuclear fuel reprocessing at the Idaho Chemical Processing Plant are calcined in the New Waste Calcining Facility (NWCF) to provide both volume reduction and a more stable waste form. Because a large component of the HLW is nitric acid, high levels of oxides of nitrogen (NOx) are produced in the process and discharged to the environment via the calciner off-gas. The NOx abatement program is required by the new Fuel Processing Restoration (FPR) project permit to construct to reduce NOx emissions from the NWCF. Extensive research and development has indicated that the selective catalytic reduction (SCR) process is the most promising technology for treating the NWCF off-gas. Pilot plant tests were performed to determine the compatibility of the SCR process with actual NWCF off-gas. Test results indicate that the SCR process is a viable method for abating the NOx from the NWCF off-gas. Reduction efficiencies over 95% can be obtained, with minimal amounts of ammonia slip, provided favorable operating conditions exist. Two reactors operated with series flow will provide optimum reduction capabilities. Typical operation should be performed with a first reactor stage gas space velocity of 20,000 hr-1 and an inlet temperature of 320 degrees C. The first stage exhaust NOx concentration will then dictate the parameter settings for the second stage. Operation should always strive for a peak reactor temperature of 520 degrees C in both reactors, with minimal NH3 slip from the second reactor. Frequent fluctuations in the NWCF off-gas NOx concentration will require a full-scale reduction facility that is versatile and quick-responding. Sudden changes in NWCF off-gas NOx concentrations will require quick detection and immediate response to avoid reactor bed over-heating and/or excessive ammonia slip

  14. Test Software Functionality, but Test its Performance as Well

    Jovica Đurković; Jelica Trninić; Vuk Vuković

    2011-01-01

    Software product testing has great importance in the detection of errors appearing in the course of software development and reflecting directly on software quality enhancement before its implementation in the working environment. Special priority in the software product testing phase is given to testing software performance. In contrast to functional testing, which should show if software is capable of carrying out planned functions without making errors, performance testing should show if t...

  15. Sustainable test cell : performance evaluation

    Silva, Pedro Correia Pereira da; Bragança, L.; Mendonça, Paulo; Almeida, Manuela Guedes de

    2006-01-01

    Energy is one of the main causes of the environmental pollution. In the European Union, buildings are responsible for 40% of the final energy demand and 1/3 of the emissions of greenhouse gases. Therefore, in order to promote the energy consumption reduction, it is fundamental to employ sustainable development principles in the construction sector. In order to demonstrate and show the potentialities of Sustainable building technologies two Test Cells were built. Comparing the solutions obtain...

  16. Performing and evaluating creep tests

    Dvořák, Jiří; Blum, W.; Král, Petr; Eisenlohr, P.; Sklenička, Václav

    Toulouse: Institut Carnot CIRIMAT, 2015. s. 303-304. [CREEP 2015 - International Conference on Creep and Fracture of Engineering Materials and Structures /13./. 31.05.2015-04.06.2015, Toulouse] R&D Projects: GA MŠk(CZ) ED1.1.00/02.0068 Institutional support: RVO:68081723 Keywords : creep test * inelastic strain rate * crystallite boundaries * coper * dynamic recovery Subject RIV: JG - Metallurgy

  17. Performance Test on Polymer Waste Form - 12137

    Lee, Se Yup [Korea Nuclear Engineering Co., Ltd., C-504 Bundang Techno-Park 145, Yatap-dong, Bundang-gu, Seongnam-si, Gyeonggi-do, 463-760 (Korea, Republic of)

    2012-07-01

    Polymer solidification was attempted to produce stable waste form for the boric acid concentrates and the dewatered spent resins. The polymer mixture was directly injected into the mold or drum which was packed with the boric acid concentrates and the dewatered spent resins, respectively. The waste form was produced by entirely curing the polymer mixture. A series of performance tests was conducted including compressive strength test, water immersion test, leach test, thermal stability test, irradiation stability test and biodegradation stability test for the polymer waste forms. From the results of the performance tests for the polymer waste forms, it is believed that the polymer waste form is very stable and can satisfy the acceptance criteria for permanent disposal. At present, performance tests with full scale polymer waste forms are being carried out in order to obtain qualification certificate by the regulatory institute in Korea. Polymer waste forms were prepared with the surrogate of boric acid concentrates and the surrogate of spent ion exchange resins respectively. Waste forms were also made in lab scale and in full scale. Lab. scale waste forms were directly subjected to a series of the performance tests. In the case of full scale waste form, the test specimens for the performance test were taken from a part of waste form by coring. A series of performance tests was conducted including compressive strength test, thermal stability test, irradiation stability test and biodegradation stability test, water immersion test, leach test, and free standing water for the polymer waste forms. In addition, a fire resistance test was performed on the waste forms by the requirement of the regulatory institute in Korea. Every polymer waste forms containing the boric acid concentrates and the spent ion exchange resins had exhibited excellent structural integrity of more than 27.58 MPa (4,000 psi) of compressive strength. On thermal stability testing, biodegradation

  18. Performance Test on Polymer Waste Form - 12137

    Polymer solidification was attempted to produce stable waste form for the boric acid concentrates and the dewatered spent resins. The polymer mixture was directly injected into the mold or drum which was packed with the boric acid concentrates and the dewatered spent resins, respectively. The waste form was produced by entirely curing the polymer mixture. A series of performance tests was conducted including compressive strength test, water immersion test, leach test, thermal stability test, irradiation stability test and biodegradation stability test for the polymer waste forms. From the results of the performance tests for the polymer waste forms, it is believed that the polymer waste form is very stable and can satisfy the acceptance criteria for permanent disposal. At present, performance tests with full scale polymer waste forms are being carried out in order to obtain qualification certificate by the regulatory institute in Korea. Polymer waste forms were prepared with the surrogate of boric acid concentrates and the surrogate of spent ion exchange resins respectively. Waste forms were also made in lab scale and in full scale. Lab. scale waste forms were directly subjected to a series of the performance tests. In the case of full scale waste form, the test specimens for the performance test were taken from a part of waste form by coring. A series of performance tests was conducted including compressive strength test, thermal stability test, irradiation stability test and biodegradation stability test, water immersion test, leach test, and free standing water for the polymer waste forms. In addition, a fire resistance test was performed on the waste forms by the requirement of the regulatory institute in Korea. Every polymer waste forms containing the boric acid concentrates and the spent ion exchange resins had exhibited excellent structural integrity of more than 27.58 MPa (4,000 psi) of compressive strength. On thermal stability testing, biodegradation

  19. Research of laser stealth performance test technology

    Chen, Zhen-xing; Shi, Sheng-bing; Han, Fu-li; Wu, Yan-lin; Song, Chun-yan

    2014-09-01

    Laser stealth is an important way of photoelectric stealth weapons systems. According to operational principle of laser range finder, we actively explore and study the stealth performance approval testing technology of laser stealth materials, and bring forward and establish the stealth performance field test methods of stealth efficiency evaluation. Through contrastive test of two kinds of materials, the method is correct and effective.

  20. Novel Sorbent Development and Evaluation for the Capture of Krypton and Xenon from Nuclear Fuel Reprocessing Off-Gas Streams

    Troy G. Garn; Mitchell R. Greenhalgh; Jack D. Law

    2013-09-01

    The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbent development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, INL sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up.

  1. Novel Sorbent Development and Evaluation for the Capture of Krypton and Xenon from Nuclear Fuel Reprocessing Off-Gas Streams

    Troy G. Garn; Mitchell R. Greenhalgh; Jack D. Law

    2013-10-01

    The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbent development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, INL sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up.

  2. Performance test on shielding concrete

    The cylinder of the shielding concrete is made from common Portland cement and home-made coarse or fine aggregates. Orthogonal design experiment and regression analysis are adopted to study the effects of the water content, sand percentage and water-cement ratio on the property of shielding concrete and the difference between them. The test shows that the tensile strength is in inverse proportion with water-cement ratio, and the influence is quite significant. Another factor is the type of aggregates. The effect of the age on its density is not obvious. Similarly, the concrete shielding γ rays shares the same influencing factors with that shielding neutron rays on density, slump and tensile strength. And both have the same change rules regarding to mechanical property. (authors)

  3. Integrated Performance Testing Workshop, Modules 6 - 11

    Leach, Janice; Torres, Teresa M.

    2012-10-01

    These modules cover performance testing of: Interior Detection Systems; Access Controls; Exterior Detection Systems; Video Assessment Systems; SNM / Contraband Detection Systems; Access Delay Elements

  4. Decomposition of volatile organic compounds and polycyclic aromatic hydrocarbons in industrial off-gas by electron beams: A review

    The electron beam induced decomposition of volatile organic compounds (e.g. aromatic compounds, esters, chlorinated hydrocarbons) and polycyclic aromatic hydrocarbons (e.g. chlorinated dibenzo-dioxins) in industrial off gas has been investigated by several research groups in Germany and Japan. The method was shown to be effective for cleaning the waste gas of a paint factory, the waste air discharged from an automobile tunnel, the off gas cleaning from a groundwater remediation plant and the flue gas of a waste incinerator. The electron beam process achieves high removal efficiencies for volatile organic compounds. Reaction models have been developed, which suggest that the organic compounds are oxidized by hydroxyl radicals. The electron beam process may treat very large off-gas volumes at ambient temperatures and has a low energy consumption. The production of secondary wastes can be avoided or minimized. Compared to conventional methods the investment and operation costs of the process seem to be attractive for selected applications

  5. Iodine Pathways and Off-Gas Stream Characteristics for Aqueous Reprocessing Plants – A Literature Survey and Assessment

    R. T. Jubin; D. M. Strachan; N. R. Soelberg

    2013-09-01

    Used nuclear fuel is currently being reprocessed in only a few countries, notably France, England, Japan, and Russia. The need to control emissions of the gaseous radionuclides to the air during nuclear fuel reprocessing has already been reported for the entire plant. But since the gaseous radionuclides can partition to various different reprocessing off-gas streams, for example, from the head end, dissolver, vessel, cell, and melter, an understanding of each of these streams is critical. These off-gas streams have different flow rates and compositions and could have different gaseous radionuclide control requirements, depending on how the gaseous radionuclides partition. This report reviews the available literature to summarize specific engineering data on the flow rates, forms of the volatile radionuclides in off-gas streams, distributions of these radionuclides in these streams, and temperatures of these streams. This document contains an extensive bibliography of the information contained in the open literature.

  6. The effect of pranayama on test anxiety and test performance

    Azadeh Nemati

    2013-01-01

    Objectives: In an educational setting, anxiety is often experienced by students when taking a test; which is called ‘test anxiety’. This study intends to investigate the effect of doing pranayama on test anxiety and test performance. Materials and Methods: The participants consisted of 107 MA students who were randomly assigned to the control and experimental groups. The students of the experimental group practiced pranayama for one full semester. Sarason's (1980) test anxiety scale was given...

  7. Data quality objectives summary report for the 105-N monolith off-gas issue

    The 105-N Basin hardware waste with radiation exposure rates high enough to make above-water handling and packaging impractical has been designated high exposure rate hardware (HERH) waste. This material, consisting primarily of irradiated reactor components, is packaged underwater for subsequent disposal as a grout-encapsulated solid monolith. The third HERH waste package that was created (Monolith No. 3) was not immediately removed from the basin because of administrative delays. During a routine facility walkdown, Monolith No. 3 was observed to be emitting bubbles. Mass spectroscopic analysis of a gas sample from Monolith No. 3 indicated that the gas was 85.2% hydrogen along with a trace of fission gases (stable isotopes of xenon). Gamma energy analysis of a gas sample from Monolith No. 3 also identified trace quantities of 85Kr. The monolith off-gas Data Quality Objective (DQO) process concluded the following: Monolith No. 3 and similar monoliths can be safely transported following installation of spacers between the lids of the L3-181 transport cask to vent the hydrogen gas; The 85Kr does not challenge personnel or environmental safety; Fumaroles in the surface of gassing monoliths renders them incompatible with Hanford Site Solid Waste Acceptance Criteria requirements unless placed in a qualified high integrity container overpack; and Gassing monoliths do meet Environmental Restoration Disposal Facility Waste Acceptance Criteria requirements. This DQO Summary Report is both an account of the Monolith Off-Gas DQO Process and a means of documenting the concurrence of each of the stakeholder organizations

  8. A model for utilizing industrial off-gas to support microalgae cultivation for biodiesel in cold climates

    Highlights: • Development of a model to assess process-coupled algae production in cold climates. • Algae growth temperatures in open tanks can be maintained with industrial off-gas. • Indirect and direct heat application from industrial off-gasses are assessed. • CO2-rich off-gas can be bubbled into algae tanks to provide a carbon source. • A nickel smelter’s off-gas is used to demonstrate how waste heat can be repurposed. - Abstract: Lipids produced by microalgae are a promising biofuel feedstock. However, as most commercial mass production of microalgae is in open raceway ponds it is generally considered only a practical option in regions where year-round ambient temperatures remain above 15 °C. To address this issue it has been proposed to couple microalgae production with industries that produce large amounts of waste heat and carbon dioxide (CO2). The CO2 would provide a carbon source for the microalgae and the waste heat would allow year-round cultivation to be extended to regions that experience seasonal ambient temperatures well below 15 °C. To demonstrate this concept, a dynamic model has been constructed that predicts the impact on algal pond temperature from both bubbled-in off-gas and heat indirectly recovered from off-gas. Simulations were carried out for a variety of global locations using the quantity off-gas and waste energy from a smelter’s operations to determine the volume of microalgae that could be maintained above 15 °C. The results demonstrate the feasibility of year-round microalgae production in climates with relatively cold winter seasons

  9. Performance of a large-scale melter off-gas system utilizing simulated SRP DWPF waste

    The Department of Energy and the DuPont Company have begun construction of a Defense Waste Processing Facility to immobilize radioactive waste now stored as liquids at the Department of Energy's Savannah River Plant. The immobilization process solidifies waste sludge by vitrification into a leach-resistant borosilicate glass. Development of the process has been the responsibility of the Savannah River Laboratory. As part of the development, two large-scale glass melter systems have been designed and operated with simulated waste. Experimental data from these operations show that process requirements will be met. 6 references, 8 figures, 4 tables

  10. 40 CFR 63.1161 - Performance testing and test methods.

    2010-07-01

    ... concentration standard for that plant. (d) Test methods. (1) The following test methods in appendix A of 40 CFR... 6 ppmv when operated within its design parameters. The alternative concentration standard shall be established through performance testing while the plant is operated at maximum design temperature and with...

  11. Hanford Waste Vitrification program pilot-scale ceramic melter Test 23

    Goles, R.W.; Nakaoka, R.K.

    1990-02-01

    The pilot-scale ceramic melter test, was conducted to determine the vitrification processing characteristics of simulated Hanford Waste Vitrification Plant process slurries and the integrated performance of the melter off-gas treatment system. Simulated melter feed was prepared and processed to produce glass. The vitrification system, achieved an on-stream efficiency of greater than 98%. The melter off-gas treatment system included a film cooler, submerged bed scrubber, demister, high-efficiency mist eliminator, preheater, and high-efficiency particulate air filter (HEPA). Evaluation of the off-gas system included the generation, nature, and capture efficiency of gross particulate, semivolatile, and noncondensible melter products. 17 refs., 48 figs., 61 tabs.

  12. Performance Test on Polymer Waste Form

    Lee, Se Yup [Korea Nuclear Engineering Co., Ltd, Seongnam (Korea, Republic of)

    2012-07-01

    Boric acid wastewater and spent ion exchange resins are generated as a low- and medium- level radioactive wastes from pressurized light water reactors. In Korea, boric acid wastewater is concentrated and dried in the form of granules, and finally solidified by using paraffin wax. In this study, polymer solidification was attempted to produce the stable waste form for the boric acid concentrates and the dewatered spent ion exchange resins. The polymer mixture which consists of epoxy resin, amine compounds and antimony trioxide was used to solidify the boric acid concentrates and the dewatered spent ion exchange resins. To evaluate the stability of polymer waste forms, a series of standardized performance tests was conducted. Also, by the requirement of the regulatory institute in Korea, an additional test was performed to estimate fire resistance and gas generation of the waste forms. A series of performance tests was conducted including compressive strength test, thermal stability test, irradiation stability test and biodegradation stability test, water immersion test, leach test, and free standing water for the polymer waste forms. In addition, a fire resistance test and an analysis of gas generation were performed on the waste forms by the requirement of the regulatory institute in Korea. From the results of the performance tests, it is believed that the polymer waste form is very stable and can satisfy the acceptance criteria for permanent disposal.

  13. Performance Test on Polymer Waste Form

    Boric acid wastewater and spent ion exchange resins are generated as a low- and medium- level radioactive wastes from pressurized light water reactors. In Korea, boric acid wastewater is concentrated and dried in the form of granules, and finally solidified by using paraffin wax. In this study, polymer solidification was attempted to produce the stable waste form for the boric acid concentrates and the dewatered spent ion exchange resins. The polymer mixture which consists of epoxy resin, amine compounds and antimony trioxide was used to solidify the boric acid concentrates and the dewatered spent ion exchange resins. To evaluate the stability of polymer waste forms, a series of standardized performance tests was conducted. Also, by the requirement of the regulatory institute in Korea, an additional test was performed to estimate fire resistance and gas generation of the waste forms. A series of performance tests was conducted including compressive strength test, thermal stability test, irradiation stability test and biodegradation stability test, water immersion test, leach test, and free standing water for the polymer waste forms. In addition, a fire resistance test and an analysis of gas generation were performed on the waste forms by the requirement of the regulatory institute in Korea. From the results of the performance tests, it is believed that the polymer waste form is very stable and can satisfy the acceptance criteria for permanent disposal

  14. Performance Testing of Download Services of COSMC

    Jiří Horák

    2013-11-01

    Full Text Available The paper presents results of performance tests of download services of Czech Office of Surveying, Mapping and Cadastre according to INSPIRE  requirements. Methodology of testing is explained, including monitoring performance  of reference servers. 26 millions of random requests were generated for each monitored operation, layer and coordinate system. The temporal development of performance indicators are analyzed and discussed. Results of performance tests approve the compliance with INSPIRE qualitative requirements for download services. All monitored services satisfy requirements of latency, capacity and availability. The latency and availability requirements are fulfilled with an abundant reserve. No problems in structure and content of responses were detected.

  15. Summary of performance test for filtered vent

    TOSHIBA has been carried tests to evaluate performance of the filtered vent system. In order to apply several parameters and functions, test facility is useful and has much flexibility. The filtered vent system has 2 functions, one is scrubbing in water and the other is metal filter. Test results show a good performance. We will introduce a outline of the filtered vent system examination. (author)

  16. Off-gas characteristics of defense waste vitrification using liquid-fed Joule-heated ceramic melters

    Off-gas and effluent characterization studies have been established as part of a PNL Liquid-Fed Ceramic Melter development program supporting the Savannah River Laboratory Defense Waste Processing Facility (SRL-DWPF). The objectives of these studies were to characterize the gaseous and airborne emission properties of liquid-fed joule-heated melters as a function of melter operational parameters and feed composition. All areas of off-gas interest and concern including effluent characterization, emission control, flow rate behavior and corrosion effects have been studied using alkaline and formic-acid based feed compositions. In addition, the behavioral patterns of gaseous emissions, the characteristics of melter-generated aerosols and the nature and magnitude of melter effluent losses have been established under a variety of feeding conditions with and without the use of auxiliary plenum heaters. The results of these studies have shown that particulate emissions are responsible for most radiologically important melter effluent losses. Melter-generated gases have been found to be potentially flammable as well as corrosive. Hydrogen and carbon monoxide present the greatest flammability hazard of the combustibles produced. Melter emissions of acidic volatile compounds of sulfur and the halogens have been responsible for extensive corrosion observed in melter plenums and in associated off-gas lines and processing equipment. The use of auxiliary plenum heating has had little effect upon melter off-gas characteristics other than reducing the concentrations of combustibles

  17. Vitrification Facility integrated system performance testing report

    This report provides a summary of component and system performance testing associated with the Vitrification Facility (VF) following construction turnover. The VF at the West Valley Demonstration Project (WVDP) was designed to convert stored radioactive waste into a stable glass form for eventual disposal in a federal repository. Following an initial Functional and Checkout Testing of Systems (FACTS) Program and subsequent conversion of test stand equipment into the final VF, a testing program was executed to demonstrate successful performance of the components, subsystems, and systems that make up the vitrification process. Systems were started up and brought on line as construction was completed, until integrated system operation could be demonstrated to produce borosilicate glass using nonradioactive waste simulant. Integrated system testing and operation culminated with a successful Operational Readiness Review (ORR) and Department of Energy (DOE) approval to initiate vitrification of high-level waste (HLW) on June 19, 1996. Performance and integrated operational test runs conducted during the test program provided a means for critical examination, observation, and evaluation of the vitrification system. Test data taken for each Test Instruction Procedure (TIP) was used to evaluate component performance against system design and acceptance criteria, while test observations were used to correct, modify, or improve system operation. This process was critical in establishing operating conditions for the entire vitrification process

  18. Canadian national internal dosimetry performance testing programme

    This paper describes the design and construction of new Performance Testing programme that was implemented in Canada in 2008. The Canadian Regulator (Canadian Nuclear Safety Commission - CNSC) had determined that their licensees, in addition to the existing In Vivo and In Vitro performance tests, needed to demonstrate their ability in interpreting bioassay results. The program is administered by the Canadian National Calibration Reference Centre for Bioassay and In Vivo Monitoring (NCRC). Currently the NCRC carries out the performance testing for the In Vitro and In Vivo. At time of writing, the first round has not been completed and the pass/fail criteria have not been determined. (author)

  19. SI PC104 Performance Test Report

    Montelongo, S

    2005-12-16

    The Spectral Instruments (SI) PC104 systems associated with the SI-1000 CCD camera exhibited intermittent power problems during setup, test and operations which called for further evaluation and testing. The SI PC104 System is the interface between the SI-1000 CCD camera and its associated Diagnostic Controller (DC). As such, the SI PC104 must be a reliable, robust system capable of providing consistent performance in various configurations and operating conditions. This SI PC104 system consists of a stackable set of modules designed to meet the PC104+ Industry Standard. The SI PC104 System consists of a CPU module, SI Camera card, Media converter card, Video card and a I/O module. The root cause of power problems was identified as failing solder joints at the LEMO power connector attached to the SI Camera Card. The recommended solution was to provide power to the PC104 system via a PC104+ power supply module configured into the PC104 stack instead of thru the LEMO power connector. Test plans (2) were developed to test SI PC104 performance and identify any outstanding issues noted during extended operations. Test Plan 1 included performance and image acquisition tests. Test Plan 2 verified performance after implementing recommendations. Test Plan 2 also included verifying integrity of system files and driver installation after bootup. Each test plan was implemented to fully test against each set of problems noted. Test Plan presentations and Test Plan results are attached as appendices. Anticipated test results will show successful operation and reliable performance of the SI PC104 system receiving its power via a PC104 power supply module. A SI PC104 Usage Recommendation Memo will be sent out to the SI PC104 User Community. Recommendation memo(s) are attached as appendices.

  20. FFTF absorber-pin performance verification test

    The FFTF (Fast Flux Test Facility) Absorber Pin Performance Verification Test - (HA006) is an irradiation test of neutron absorber pins with integral temperature and pressure monitoring instrumentation. The pins, containing boron carbide, are representative of the FFTF Row 3 Safety, Row 5 Control and Row 7 Fixed Shim Absorber Assemblies. In the 300 full power days (FPD) this test will reside in its 2610 Position in the reactor, it will generate test data that will be used to infer the effects of irradiation on the absorber assemblies it simulates. Design and fabrication of the test vehicle began in 1976 and the forty-foot test assembly was loaded in the FFTF on February 10, 1981. The test provided data in March 1981 during a series of natural circulation tests, and again in November 1981 during the eight-day full power run establishing base-line data

  1. Integrated Performance Testing for Nonproliferation Support Project

    Johns, Russell; Bultz, Garl Alan; Byers, Kenneth R.; Yaegle, William

    2013-08-20

    The objective of this workshop is to provide participants with training in testing techniques and methodologies for assessment of the performance of: Physical Protection system elements; Material Control and Accounting (MC&A) system elements.

  2. The environment and ASME performance test codes

    Today, federal, state and local governmental agencies have enacted comprehensive legislation on power generation emission limits which affects all aspects of the energy sector. This paper reviews the indirect impact of Performance Test Codes on environmental testing, reviewing past, current, and future practices. Existing codes and three new codes currently under development will be cited along with possible future code development

  3. The environment and ASME performance test codes

    Bannister, R.L. [Westinghouse Electric Corp., Orlando, FL (United States); Macak, J.J. III [Mostardi-Platt Associates, Inc., Elmhurst, IL (United States); Newby, R.A. [Westinghouse Science and Technology Center, Pittsburgh, PA (United States)

    1995-12-31

    Today, federal, state and local governmental agencies have enacted comprehensive legislation on power generation emission limits which affects all aspects of the energy sector. This paper reviews the indirect impact of Performance Test Codes on environmental testing, reviewing past, current, and future practices. Existing codes and three new codes currently under development will be cited along with possible future code development.

  4. Excess-air incineration with high temperature filtering for efficient off-gas cleaning

    When SGN started work on volume reduction of low-level and intermediate-level radioactive wastes in the early 1960s, in collaboration with the French Atomic Energy Commission (CEA), incineration was relatively undeveloped but its potential efficiency was immediately recognized. The incinerators then available divided more or less into proven designs used in municipal refuse incineration and so-called advanced systems: SGN's initial impression was that systems for municipal refuse incineration could be readily adapted to handle combustible nuclear wastes. These systems mainly employed excess-air fixed-bed combustion, rotary furnaces or fluidized-bed combustion, sometimes with partial or total pyrolysis. The ''advanced'' systems proposed by various inventors were far more sophisticated but, due to a lack of industrial experience, were often designed with inadequate regard to human safety. The result was a number of serious accidents, including some deaths. Nuclear-grade incineration was a rather esoteric subject at the time. Standard incinerators were not designed to handle radioactive wastes. They lacked essential safety features (e.g. leaktightness) and did not provide for repair and maintenance after contamination nor for affordable dismantling at end of life. Off-gas cleaning had neither the efficiency nor safety required in the nuclear industry. Extensive automation of control and monitoring was not envisaged, because unnecessary in traditional applications

  5. Membrane processes in off-gas purification; Membranverfahren in der Abluftreinigung

    Ohlrogge, K.; Wind, J. [GKSS-Forschungszentrum Geesthacht GmbH (Germany)

    2002-07-01

    Membrane processes for separation of organic vapours have gained wider acceptance during the past decade. In fuelling stations, they have achieved a market share of 60 %. In the chemical, petrochemical and pharmaceutical industries, membrane processes are used for separating solvents in off-gas and process gas purification. They are also used successfully as process-integrated systems in polymer production. Examples are vinyl chloride recovery in PVC production and propylene, ethylene and hexane recovery in polypropylene and polyethylene production. [German] Membranverfahren zur Abtrennung organischer Daempfe haben in den letzten 10 Jahren zunehmend an Bedeutung gewonnen. Bei den Tanklaegern fuer Otto-Kraftstoffe, die mit Benzindampf-Rueckgewinnungsanlagen ausgeruestet sind, betraegt der Marktanteil der Membrantechnik ca. 60%. Eine weitere Anwendung findet die Membrantechnik in der Emissionsreduzierung auf Tankstellen bei der Fahrzeugbetankung. In Produktionsstaetten der Chemie, Petrochemie und Pharmazie werden Membranverfahren zur Abtrennung von Loesungsmitteln sowohl in der Abgasreinigung als auch in der Prozessgasreinigung eingesetzt. Als prozessintegrierte Systeme werden Membranverfahren bei der Polymerherstellung erfolgreich eingesetzt. Beispiele sind die Vinylchlorid-Rueckgewinnung in der PVC-Produktion und die Propylen-, Ethylen- und Hexan-Rueckgewinnung bei der Polypropylen- und Polyethylenherstellung. (orig.)

  6. Multi-level computational chemistry study on hydrogen recombination catalyst of off-gas treatment system

    In order to reveal the deactivation mechanism of the hydrogen recombination catalyst of off-gas treatment system, we investigate by using multi-level computational chemistry simulation methods. The recombiner apparatus is modeled by the numerical mesh system in the axial coordinates, and unsteady, advection and reaction rate equations are solved by using a finite difference method. The chemical reactions are formulated to represent adsorption-desorption of hydrogen and oxygen on Pt catalyst, and time developments of the coverage factors of Pt are solved numerically. The computational simulations successfully reproduce the very similar behaviors observed by experiments, such as increasing of the inversion rates of H2 to H2O, the temperatures distributions along the flow direction, dependencies of experimental condition, and so on. Thus Pt poisoning is considered to cause the deactivation of the hydrogen recombination catalyst. To clarify the poisoning mechanism, the molecular level simulation is applied to the system of Pt on boehmite attacked by a cyclic siloxane which has been detected by experiments and considered as one of poisoning spices. The simulation shows ring-opening reaction of the cyclic siloxane on Pt, then attachment of two ends of the chain-like siloxane to Pt and boehmite, respectively, and that finally the recombination reaction is prevented. This may be the first study to find out the detailed dynamical mechanism of hydrogen recombination catalyst poisoning with cyclic siloxane. (author)

  7. Silica-based waste form for immobilization of iodine from reprocessing plant off-gas streams

    Matyáš, Josef; Canfield, Nathan; Sulaiman, Sannoh; Zumhoff, Mac

    2016-08-01

    A high selectivity and sorption capacity for iodine and a feasible consolidation to a durable SiO2-based waste form makes silver-functionalized silica aerogel (Ag0-aerogel) an attractive choice for the removal and sequestration of iodine compounds from the off-gas of a nuclear fuel reprocessing plant. Hot uniaxial pressing of iodine-loaded Ag0-aerogel (20.2 mass% iodine) at 1200 °C for 30 min under 29 MPa pressure provided a partially sintered product with residual open porosity of 16.9% that retained ∼93% of sorbed iodine. Highly iodine-loaded Ag0-aerogel was successfully consolidated by hot isostatic pressing at 1200 °C with a 30-min hold and under 207 MPa. The fully densified waste form had a bulk density of 3.3 × 103 kg/m3 and contained ∼39 mass% iodine. The iodine was retained in the form of nano- and micro-particles of AgI that were uniformly distributed inside and along boundaries of fused silica grains.

  8. The integrated melter off-gas treatment systems at the West Valley Demonstration Project

    The West Valley Demonstration Project was established by Public Law 96-368, the open-quotes West Valley Demonstration Project Act, close quotes on October 1, l980. Under this act, Congress directed the Department of Energy to carry out a high level radioactive waste management demonstration project at the Western New York Nuclear Service Center in West Valley, New York. The purpose of this project is to demonstrate solidification techniques which can be used for preparing high level radioactive waste for disposal. In addition to developing this technology, the West Valley Demonstration Project Act directs the Department of Energy to: (1) develop containers suitable for permanent disposal of the high level waste; (2) transport the solidified high level waste to a Federal repository; (3) dispose of low level and transuranic waste produced under the project; and (4) decontaminate and decommission the facilities and materials associated with project activities and the storage tanks originally used to store the liquid high level radioactive waste. The process of vitrification will be used to solidify the high level radioactive liquid wastes into borosilicate glass. This report describes the functions, the controlling design criteria, and the resulting design of the melter off-gas treatment systems which are used in the vitrification process

  9. Verification and performance tests of HYCAR program

    Bhatia, Veena

    1985-01-01

    The HYCAR program simulates the network protocols of HYPERchannel and Fiber Optic Demonstration System (FODS) and other related protocols. Verification tests of the program were conducted using the FODS protocol. The tests validated the operation of the program through deterministic and analytical means. Extensive experimentation with the simulator produced a set of performance characteristics for the FODS protocol under varied loading conditions. These characteristics are consistent with those expected, and are documented with the validation tests.

  10. RHIC sextant test: Accelerator systems and performance

    One sextant of the RHIC Collider was commissioned in early 1997 with beam. We describe here the performance of the accelerator systems, instrumentation subsystems and application software. We also describe a ramping test without beam that took place after the commissioning with beam. Finally, we analyze the implications of accelerator systems performance and their impact on the planning for RHIC installation and commissioning

  11. Design and performance test of spacecraft test and operation software

    Wang, Guohua; Cui, Yan; Wang, Shuo; Meng, Xiaofeng

    2011-06-01

    Main test processor (MTP) software is the key element of Electrical Ground Support Equipment (EGSE) for spacecraft test and operation used in the Chinese Academy of Space Technology (CAST) for years without innovation. With the increasing demand for a more efficient and agile MTP software, the new MTP software was developed. It adopts layered and plug-in based software architecture, whose core runtime server provides message queue management, share memory management and process management services and forms the framework for a configurable and open architecture system. To investigate the MTP software's performance, the test case of network response time, test sequence management capability and data-processing capability was introduced in detail. Test results show that the MTP software is common and has higher performance than the legacy one.

  12. Bias and spread in EVT performance tests.

    Smith, J. G.

    1971-01-01

    Performance tests (error probability measurements) of communications systems characterized by low bit rates and high reliability requirements frequently utilize classical extreme value theory (EVT) to avoid the excessive test times encountered with bit error rate (BER) tests. If the underlying noise is Gaussian or perturbed Gaussian, the EVT error estimates have either excessive bias or excessive variance if an insufficient number of test samples is used. EVT is examined to explain the cause of this bias and spread. Experimental verification is made by testing a known Gaussian source, and procedures that minimize these effects are described. It seems apparent that even under the best of conditions the EVT test results are not particularly better than those of BER tests.

  13. Literature Review: Assessment of DWPF Melter and Melter Off-gas System Lifetime

    Reigel, M. [Savannah River Site (SRS), Aiken, SC (United States)

    2015-07-30

    Testing to date for the MOC for the Hanford Waste Treatment and Immobilization Plant (WTP) melters is being reviewed with the lessons learned from DWPF in mind and with consideration to the changes in the flowsheet/feed compositions that have occurred since the original testing was performed. This information will be presented in a separate technical report that identifies any potential gaps for WTP processing.

  14. Virtual Shaker Testing: Simulation Technology Improves Vibration Test Performance

    Ricci, Stefano; Peeters, Bart; Fetter, Rebecca; Boland, Doug; Debille, Jan

    2008-01-01

    In the field of vibration testing, the interaction between the structure being tested and the instrumentation hardware used to perform the test is a critical issue. This is particularly true when testing massive structures (e.g. satellites), because due to physical design and manufacturing limits, the dynamics of the testing facility often couples with the test specimen one in the frequency range of interest. A further issue in this field is the standard use of a closed loop real-time vibration control scheme, which could potentially shift poles and change damping of the aforementioned coupled system. Virtual shaker testing is a novel approach to deal with these issues. It means performing a simulation which closely represents the real vibration test on the specific facility by taking into account all parameters which might impact the dynamic behavior of the specimen. In this paper, such a virtual shaker testing approach is developed. It consists of the following components: (1) Either a physical-based or an equation-based coupled electro-mechanical lumped parameter shaker model is created. The model parameters are obtained from manufacturer's specifications or by carrying out some dedicated experiments; (2) Existing real-time vibration control algorithm are ported to the virtual simulation environment; and (3) A structural model of the test object is created and after defining proper interface conditions structural modes are computed by means of the well-established Craig-Bampton CMS technique. At this stage, a virtual shaker test has been run, by coupling the three described models (shaker, control loop, structure) in a co-simulation routine. Numerical results have eventually been correlated with experimental ones in order to assess the robustness of the proposed methodology.

  15. Systematic selection of off-gas treatment at the Savannah River Site

    At the Savannah River Site (SRS), from 1958--1985, effluent waste from the reactor fuel and target rod fabrication area (M-Area) was discharged to a settling basin. In 1981, monitoring wells detected groundwater contamination, specifically trichloroethylene and tetrachloroethylene, in the immediate vicinity of the basin. Under the auspices of Resource Conservation and Recovery Act (RCRA) the M-Area contamination must be addressed by a corrective action program until the volatile organic compound (VOC) concentrations reach Drinking Water Standards. This was initiated in 1985 with startup of a full-scale pump-and-treat air stripper system. Recently, remediation efforts have focused on vacuum extraction to treat vadose zone contamination not addressed by the original recovery wells, and additional pump-and-treat systems to achieve hydraulic control of the plume. Regulatory requirements allowed for discharge of VOCs to the atmosphere when the original remediation system was installed; however, 1990 amendments to the Clean Air Act will eventually require treatment of VOC contaminated air prior to discharge. This has ramifications to systems currently being design, as well as the existing systems. In response to the 1990 Clean Air Act amendments, SRS initiated a study to assess commercially available off-gas treatment technologies. These included carbon adsorption, thermal incineration, catalytic oxidation, absorption, condensation, and UV/peroxide destruction, and xenon flashlamp. Criteria used to evaluate the technologies were the thirty (30) year life cycle cost, permitting considerations, and manpower requirements. The study concluded that catalytic oxidation provided the most desirable combination of these elements

  16. Advanced online monitoring of cell culture off-gas using proton transfer reaction mass spectrometry.

    Schmidberger, Timo; Gutmann, Rene; Bayer, Karl; Kronthaler, Jennifer; Huber, Robert

    2014-01-01

    Mass spectrometry has been frequently applied to monitor the O₂ and CO₂ content in the off-gas of animal cell culture fermentations. In contrast to classical mass spectrometry the proton transfer reaction mass spectrometry (PTR-MS) provides additional information of volatile organic compounds by application of a soft ionization technology. Hence, the spectra show less fragments and can more accurately assigned to particular compounds. In order to discriminate between compounds of non-metabolic and metabolic origin cell free experiments and fed-batch cultivations with a recombinant CHO cell line were conducted. As a result, in total eight volatiles showing high relevance to individual cultivation or cultivation conditions could be identified. Among the detected compounds methanethiol, with a mass-to-charge ratio of 49, qualifies as a key candidate in process monitoring due to its strong connectivity to lactate formation. Moreover, the versatile and complex data sets acquired by PTR MS provide a valuable resource for statistical modeling to predict non direct measurable parameters. Hence, partial least square regression was applied to the complete spectra of volatiles measured and important cell culture parameters such as viable cell density estimated (R²  = 0.86). As a whole, the results of this study clearly show that PTR-MS provides a powerful tool to improve bioprocess-monitoring for mammalian cell culture. Thus, specific volatiles emitted by cells and measured online by the PTR-MS and complex variables gained through statistical modeling will contribute to a deeper process understanding in the future and open promising perspectives to bioprocess control. PMID:24376199

  17. Modelling of Boil-Off Gas in LNG Tanks: A Case Study

    Sheikh Zahidul Islam

    2010-08-01

    Full Text Available This paper focuses on the effect of pressure and heat leakages on Boil-off Gas (BOG in Liquefied Natural Gas (LNG tanks. The Lee-Kesler-Plocker (LKP and the Starling modified Benedict-Webb-Rubin (BWRS empirical models were used to simulate the compressibility factor, enthalpy and hence heat leakage at various pressures to determine the factors that affect the BOG in typical LNG tanks of different capacities. Using a case study data the heat leakage of 140,000kl, 160,00kl, 180,000kl and 200,000kl LNG tanks were analyzed using the LKP and BWRS models. The heat leakage of LNG tanks depends on the structure of tanks, and the small tanks lose heatto the environment due to their large surface area to volume ratio. As the operation pressure was dropped to 200mbar, all four of the LNG tanks’ BOG levels reached 0.05vol%/day. In order to satisfy the BOG design requirement, the operating pressure of the four large LNG tanks in the case study was maintained above 200mbar. Thus, the operating pressure impacts BOG on LNG tanks, but this effect is limited under the extreme high operation pressure. An attempt was made to determine the relationship between the compositions of LNGand BOG; one been combustible and the other non-combustible gases. The main component of combustible gas was methane, and nitrogen was of non-combustible gases. The relationship between BOG and methane compositions was that, as the methane fraction increases in the LNG, the BOG volume also increases. In general, results showed a direct correlation between BOG and operating pressure. The study also found that larger LNG tanks have less BOG; however as the operation pressure is increased the differences in the quantity of BOGamong the four tanks decreased.

  18. Test score disclosure and school performance

    Camargo, Bráz Ministério de; Firpo, Sergio Pinheiro; Ponczek, Vladimir Pinheiro

    2012-01-01

    In this paper we test whether the disclosure of test scores has direct impacts on student performance, school composition and school inputs. We take advantage of the discontinuity on the disclosure rules of The National Secondary Education Examination (ENEM) run in Brazil by the Ministry of Education: In 2006 it was established that the 2005 mean score results would be disclosed for schools with ten or more students who took the exam in the previous year. We use a regression discontinuity des...

  19. Testing prospect theory in students’ performance

    Pérez Galdón, Patricia; Nicolau, Juan Luis

    2013-01-01

    This paper tests the existence of ‘reference dependence’ and ‘loss aversion’ in students’ academic performance. Accordingly, achieving a worse than expected academic performance would have a much stronger effect on students’ (dis)satisfaction than obtaining a better than expected grade. Although loss aversion is a well-established finding, some authors have demonstrated that it can be moderated – diminished, to be precise–. Within this line of research, we also examine whether the students’ e...

  20. Core support performance test in the component flow test loop

    A description is given of the Core Flow Test Loop at Oak Ridge National Laboratory. This is a closed-circuit, out-of-pile loop circulating helium at temperatures and pressures anticipated in gas-cooled reactors. It is operated as part of the Gas-Cooled Fast Reactor programme to determine the performance of core assemblies. (U.K.)

  1. Krypton absorption in liquid CO2 (KALC): Campaign III in the Experimental Engineering Section Off-Gas Decontamination Facility

    Results are presented for the third major campaign for quantifying krypton removal from simulated High-Temperature Gas-Cooled Reactor reprocessing off-gas by the KALC process. The Experimental Engineering Section Off-Gas Decontamination Facility used in the campaign provides engineering-scale experiments with nominal gas and liquid flows of 5 scfm and 0.5 gpm, respectively. Mass transfer experiments for the CO2--O2--Kr system are described for the absorption, fractionation, and stripping operations of the KALC process. A detailed discussion of the data analysis is included. The analysis indicates nominal HTU values for the absorber, fractionator, and stripper on the order of 0.4, 0.5, and 0.7 ft, respectively. Flooding data for the packed columns are combined with previous data and are shown to be well represented by an empirical flooding equation

  2. A laser-based sensor for measurement of off-gas composition and temperature in basic oxygen steelmaking

    We are developing an optical sensor for process control in basic oxygen steelmaking. The sensor measures gas temperature and relative CO/CO2 concentration ratios in the furnace off-gas by transmitting the laser probe beam directly above the furnace lip and below the exhaust hood during oxygen blowing. Dynamic off-gas information is being evaluated for optimizing variables such as lance height, oxygen flow, post-combustion control, and prediction of final melt-carbon content. The non-invasive nature of the optical sensor renders it robust and relatively maintenance-free. Additional potential applications of the method are process control for electric arc furnace and bottom-blown oxygen steelmaking processes. (author)

  3. Load responsive multilayer insulation performance testing

    Cryogenic insulation designed to operate at various pressures from one atmosphere to vacuum, with high thermal performance and light weight, is needed for cryogenically fueled space launch vehicles and aircraft. Multilayer insulation (MLI) performs well in a high vacuum, but the required vacuum shell for use in the atmosphere is heavy. Spray-on foam insulation (SOFI) is often used in these systems because of its light weight, but can have a higher heat flux than desired. We report on the continued development of Load Responsive Multilayer Insulation (LRMLI), an advanced thermal insulation system that uses dynamic beam discrete spacers that provide high thermal performance both in atmosphere and vacuum. LRMLI consists of layers of thermal radiation barriers separated and supported by micromolded polymer spacers. The spacers have low thermal conductance, and self-support a thin, lightweight vacuum shell that provides internal high vacuum in the insulation. The dynamic load responsive spacers compress to support the external load of a vacuum shell in one atmosphere, and decompress under reduced atmospheric pressure for lower heat leak. Structural load testing was performed on the spacers with various configurations. LRMLI was installed on a 400 liter tank and boil off testing with liquid nitrogen performed at various chamber pressures from one atmosphere to high vacuum. Testing was also performed with an MLI blanket on the outside of the LRMLI

  4. Formation of the ZnFe2O4 phase in an electric arc furnace off-gas treatment system

    Highlights: • EAF dust was characterized with particle size analysis, XRF, and EPMA. • Slag particles showed no sign of reaction with Zn vapor. • Fe2O3 particles showed different degrees of reaction based on their size. • The thermodynamic stability of Zn vapor in EAF off-gas ducts was reevaluated. • In presence of Fe2O3, Zn vapor reacts to form ZnFe2O4 and ZnO. - Abstract: To better understand the phenomena of ZnFe2O4 spinel formation in electric arc furnace dust, the dust was characterized with particle size analysis, X-ray fluorescence (XRF), electron backscatter diffraction (EBSD), and electron probe micro-analysis (EPMA). Different ZnFe2O4 formation reaction extents were observed for iron oxide particles with different particle sizes. ZnO particles were present as both individual particles and aggregated on the surface of larger particles. Also, the slag particles found in the off-gas were shown not to react with the zinc vapor. After confirming the presence of a ZnFe2O4 formation reaction, the thermodynamic feasibility of in-process separation – a new electric arc furnace dust treatment technology – was reevaluated. The large air intake and the presence of iron oxide particles in the off-gas were included into the thermodynamic calculations. The formation of the stable ZnFe2O4 spinel phase was shown to be thermodynamically favorable in current electric arc furnace off-gas ducts conditions even before reaching the post combustion chamber

  5. A performance benchmark test for geodynamo simulations

    Matsui, H.; Heien, E. M.

    2013-12-01

    In the last ten years, a number of numerical dynamo models have successfully represented basic characteristics of the geomagnetic field. As new models and numerical methods continue to be developed, it is important to update and extend benchmarks for testing these models. The first dynamo benchmark of Christensen et al. (2001) was applied to models based on spherical harmonic expansion methods. However, only a few groups have reported results of the dynamo benchmark using local methods (Harder and Hansen, 2005; Matsui and Okuda, 2005; Chan et al., 2007) because of the difficulty treating magnetic boundary conditions based on the local methods. On the other hand, spherical harmonics expansion methods perform poorly on massively parallel computers because global data communications are required for the spherical harmonics expansions to evaluate nonlinear terms. We perform benchmark tests to asses various numerical methods for the next generation of geodynamo simulations. The purpose of this benchmark test is to assess numerical geodynamo models on a massively parallel computational platform. To compare among many numerical methods as possible, we consider the model with the insulated magnetic boundary by Christensen et al. (2001) and with the pseudo vacuum magnetic boundary, because the pseudo vacuum boundaries are implemented easier by using the local method than the magnetic insulated boundaries. In the present study, we consider two kinds of benchmarks, so-called accuracy benchmark and performance benchmark. In the accuracy benchmark, we compare the dynamo models by using modest Ekman and Rayleigh numbers proposed by Christensen et. al. (2001). We investigate a required spatial resolution for each dynamo code to obtain less than 1% difference from the suggested solution of the benchmark test using the two magnetic boundary conditions. In the performance benchmark, we investigate computational performance under the same computational environment. We perform these

  6. Testing for Distortions in Performance Measures

    Sloof, Randolph; Van Praag, Mirjam

    Distorted performance measures in compensation contracts elicit suboptimal behavioral responses that may even prove to be dysfunctional (gaming). This paper applies the empirical test developed by Courty and Marschke (2008) to detect whether the widely used class of Residual Income based...... performance measures —such as Economic Value Added (EVA)— is distorted, leading to unintended agent behavior. The paper uses a difference-in-differences approach to account for changes in economic circumstances and the self-selection of firms using EVA. Our findings indicate that EVA is a distorted...... performance measure that elicits the gaming response....

  7. 47 CFR 76.601 - Performance tests.

    2010-10-01

    ... television and FM broadcasting (as described in §§ 73.603 and 73.210 of this chapter) is required to conduct... CABLE TELEVISION SERVICE Technical Standards § 76.601 Performance tests. (a) The operator of each cable television system shall be responsible for insuring that each such system is designed, installed,...

  8. NetBench. Automated Network Performance Testing

    Cadeddu, Mattia

    2016-01-01

    In order to evaluate the operation of high performance routers, CERN has developed the NetBench software to run benchmarking tests by injecting various traffic patterns and observing the network devices behaviour in real-time. The tool features a modular design with a Python based console used to inject traffic and collect the results in a database, and a web user

  9. Performance test of a TMS calorimeter

    Performance tests of a first calorimeter module using the room temperature liquid tetramethylsilane (TMS) as active element are described. Normal carbon steel has been used as absorber. The charge yield is 70% of that in a very pure sample of the liquid. A long term stability of the signal with a lifetime of half a year has been realized. (orig.)

  10. Performance tests for integral reactor nuclear fuel

    Sohn, Dong-Seong; Yim, Jeong-Sik; Lee, Chong-Tak; Kim, Han-Soo; Koo, Yang-Hyun; Lee, Byung-Ho; Cheon, Jin-Sik; Oh, Je-Yong

    2006-02-15

    An integral type reactor SMART plans to utilize metallic Zr-U fuel which is Zr-based alloy with 34{approx}38 wt% U. In order to verify the technologies for the design and manufacturing of the fuel and get a license, performance tests were carried out. Experimental Fuel Assembly (EFA) manufactured in KAERI is being successfully irradiated in the MIR reactor of RIAR from September 4 2004, and it has achieved burnup of 0.21 g/cc as of January 25 2006. Thermal properties of irradiated Zr-U fuel were measured. Up to the phase transformation temperature, thermal diffusivity increased linearly in proportion to temperature. However its dependence on the burnup was not significant. RIA tests with 4 unirradiated Zr-U fuel rods were performed in Kurchatov Institute to establish a safety criterion. In the case of the un-irradiated Zr-U fuel, the energy deposition during the control rod ejection accident should be less than 172 cal/g to prevent the failure accompanying fuel fragmentation and dispersal. Finally the irradiation tests of fuel rods have been performed at HANARO. The HITE-2 test was successfully completed up to a burnup of 0.31 g/cc. The HITE-3 test began in February 2004 and will be continued up to a target burnup of 0.6 g/cc.

  11. Performance tests for integral reactor nuclear fuel

    An integral type reactor SMART plans to utilize metallic Zr-U fuel which is Zr-based alloy with 34∼38 wt% U. In order to verify the technologies for the design and manufacturing of the fuel and get a license, performance tests were carried out. Experimental Fuel Assembly (EFA) manufactured in KAERI is being successfully irradiated in the MIR reactor of RIAR from September 4 2004, and it has achieved burnup of 0.21 g/cc as of January 25 2006. Thermal properties of irradiated Zr-U fuel were measured. Up to the phase transformation temperature, thermal diffusivity increased linearly in proportion to temperature. However its dependence on the burnup was not significant. RIA tests with 4 unirradiated Zr-U fuel rods were performed in Kurchatov Institute to establish a safety criterion. In the case of the un-irradiated Zr-U fuel, the energy deposition during the control rod ejection accident should be less than 172 cal/g to prevent the failure accompanying fuel fragmentation and dispersal. Finally the irradiation tests of fuel rods have been performed at HANARO. The HITE-2 test was successfully completed up to a burnup of 0.31 g/cc. The HITE-3 test began in February 2004 and will be continued up to a target burnup of 0.6 g/cc

  12. Testing for robust speech recognition performance

    Simpson, C. A.; Moore, C. A.; Ruth, J. C.

    Results are reported from two studies which evaluated speaker-dependent connected-speech template-matching algorithms. One study examined the recognition performance for vocabularies spoken within a spacesuit. Two token vocabularies were used that were recorded in different noise levels. The second study evaluated the rejection accuracy for two commercial speech recognizers. The spoken test tokens were variations on a single word. The tests underscored the inferiority of speech recognizers relative to the human capability for discerning among phonetically different words. However, one commercial recognizer exhibited over 96-percent rejection accuracy in a noisy environment.

  13. RHIC Sextant Test - Accelerator Systems and Performance

    Pilat, F.; Ahrens, L.; Brown, K.; Connolly, R.; dell, G. F.; Fischer, W.; Kewisch, J.; Mackay, W.; Mane, V.; Peggs, S.; Satogata, T.; Tepikian, S.; Thompson, P.; Trbojevic, D.; Tsoupas, N.; Wei, J.

    1997-05-01

    One sextant of the RHIC collider and the full AtR (AGS to RHIC) transfer line have been commissioned in early 1997 with beam. We describe here the design and performance of the accelerator systems during the test, such as the magnet and power supply systems, instrumentation subsystems and application software. After reviewing the main milestones of the commissioning we describe a ramping test without beam that took place after the commissioning with beam. Finally, we analyze the implications of accelerator systems preformance and their impact on the plannig for RHIC installation and commissioning.

  14. Eurados trial performance test for photon dosimetry

    Stadtmann, H.; Bordy, J.M.; Ambrosi, P.;

    2001-01-01

    Within the framework of the EURADOS Action entitled Harmonisation and Dosimetric Quality Assurance in Individual Monitoring for External Radiation, trial performance tests for whole-body and extremity personal dosemeters were carried out. Photon, beta and neutron dosemeters were considered. This...... paper summarises the results of the whole-body photon dosemeter test. Twenty-six dosimetry services from all EU Member States and Switzerland participated. Twelve different radiation fields were used to simulate various workplace irradiation fields. Dose values from 0.4 mSv to 80 mSv were chosen. From...

  15. Performance Test of CCTV in a Test Field

    On April 12-13, 2010, US President Obama hosted a Nuclear Security Summit in Washington, DC, to enhance international cooperation to prevent nuclear terrorism, an issue which he has identified as the most immediate and extreme threat to global security. The Summit focused on the security of nuclear materials, nonproliferation, disarmament, and peaceful nuclear energy. At the summit, the Republic of Korea was chosen as the host of the next Summit in 2012. This series of events reflects the growing global interest on 'Nuclear Security' and as the host country of the next Nuclear Summit it is the time for Korea to strengthen the physical protection regime for nuclear facilities as a first step of securing its nuclear security capability. KINAC has been operating Test field as a mean of preparing solid backup data for reviewing and revising DBT (Design Basis Threat) and to test components of the conventional physical protection system. CCTV is a key component which is used worldwide for the assessment measure of alarms. In terms of performance test of CCTV, there are several elements such as image quality, coverage and mechanical features (speed of zoom-in-out, capture, angle shift etc.). Speaking of image quality acquired by the CCTV, the quality is subject to resolution, monitor specification, camera housing, camera mounting and lightening. Thus it is clear that performance tests on image quality should consider those factors and vary the factors respectively in order to verify the influence and the interaction among those. Nevertheless due to the restrictions of the current Test field, this paper focuses on the image quality through resolution test under the various lightening conditions

  16. Motivation and Test Anxiety in Test Performance across Three Testing Contexts: The CAEL, CET, and GEPT

    Cheng, Liying; Klinger, Don; Fox, Janna; Doe, Christine; Jin, Yan; Wu, Jessica

    2014-01-01

    This study examined test-takers' motivation, test anxiety, and test performance across a range of social and educational contexts in three high-stakes language tests: the Canadian Academic English Language (CAEL) Assessment in Canada, the College English Test (CET) in the People's Republic of China, and the General English Proficiency…

  17. Testing for Distortions in Performance Measures

    Sloof, Randolph; Van Praag, Mirjam

    2015-01-01

    Distorted performance measures in compensation contracts elicit suboptimal behavioral responses that may even prove to be dysfunctional (gaming). This paper applies the empirical test developed by Courty and Marschke (Review of Economics and Statistics, 90, 428-441) to detect whether the widely...... used class of residual income-based performance measures-such as economic value added (EVA)-is distorted, leading to unintended agent behavior. The paper uses a difference-in-differences approach to account for changes in economic circumstances and the self-selection of firms using EVA. Our findings...

  18. MODELING THE IMPACT OF ELEVATED MERCURY IN DEFENSE WASTE PROCESSING FACILITY MELTER FEED ON THE MELTER OFF-GAS SYSTEM-PRELIMINARY REPORT

    Zamecnik, J.; Choi, A.

    2010-08-18

    chloride, only 6% of the mercury fed is expected to get oxidized, mostly as HgCl, while the remaining mercury would exist either as elemental mercury vapor (90%) or HgO (4%). Noting that the measured chloride level in the SB5 qualification sample was an order of magnitude lower than that used in the SB5 simulant, the degree of chloride shortage will be even greater. As a result, the projected level of HgCl in the actual SB5 melter exhaust will be even lower than 6% of the total mercury fed, while that of elemental mercury is likely to be greater than 90%. The homogeneous oxidation of mercury in the off-gas was deemed to be of primary importance based on the postulation that mercury and other volatile salts form submicron sized aerosols upon condensation and thus remain largely in the gas stream downstream of the quencher where they can deposit in the off-gas lines, Steam-Atomized Scrubbers (SAS), and High-Efficiency Mist Eliminator (HEME). Formation of these submicron semi-volatile salts in the condensate liquid is considered to be unlikely, so the liquid phase reactions were considered to be less important. However, subsequent oxidation of mercury in the liquid phase in the off-gas system was examined in a simplified model of the off-gas condensate. It was found that the condensate chemistry was consistent with further oxidation of elemental mercury to Hg{sub 2}Cl{sub 2} and conversion of HgO to chlorides. The results were consistent with the available experimental data. It should also be noted that the model predictions presented in this report do not include any physically entrained solids, which typically account for much of the off-gas carryover on a mass basis. The high elemental mercury vapor content predicted at the DWPF Quencher inlet means that physically entrained solids could provide the necessary surface onto which elemental mercury vapor could condense, thereby coating the solids as well as the internal surfaces of the off-gas system with mercury. Clearly

  19. Performance test of 100 W linear compressor

    In this paper, we present test results of developed 100 W class linear compressor for Stirling-type pulse tube refrigerator. The fabricated linear compressor has dual-opposed configuration, free piston and moving magnet type linear motor. Power transfer, efficiency and required pressure waveform are predicted with designed and measured specifications. In experiments, room temperature test with flow impedance is conducted to evaluate performance of developed linear compressor. Flow impedance is loaded to compressor with metering valve for flow resistance, inertance tube for flow inertance and buffer volumes for flow compliance. Several operating parameters such as input voltage, current, piston displacement and pressure wave are measured for various operating frequency and fixed input current level. Behaviors of dynamics and performance of linear compressor as varying flow impedance are discussed with measured experimental results. The developed linear compressor shows 124 W of input power, 86 % of motor efficiency and 60 % of compressor efficiency at its resonant operating condition.

  20. Performance test of 100 W linear compressor

    Ko, J; Ko, D. Y.; Park, S. J.; Kim, H. B.; Hong, Y. J.; Yeom, H. K. [Korea Institute of Machinery and Materials, Daejeon(Korea, Republic of)

    2013-09-15

    In this paper, we present test results of developed 100 W class linear compressor for Stirling-type pulse tube refrigerator. The fabricated linear compressor has dual-opposed configuration, free piston and moving magnet type linear motor. Power transfer, efficiency and required pressure waveform are predicted with designed and measured specifications. In experiments, room temperature test with flow impedance is conducted to evaluate performance of developed linear compressor. Flow impedance is loaded to compressor with metering valve for flow resistance, inertance tube for flow inertance and buffer volumes for flow compliance. Several operating parameters such as input voltage, current, piston displacement and pressure wave are measured for various operating frequency and fixed input current level. Behaviors of dynamics and performance of linear compressor as varying flow impedance are discussed with measured experimental results. The developed linear compressor shows 124 W of input power, 86 % of motor efficiency and 60 % of compressor efficiency at its resonant operating condition.

  1. Performance tests on the NRPB thermoluminescent dosemeter

    Shaw, K B

    1977-01-01

    Performance tests on the thermoluminescent dosemeter, designed at NRPB for use in the automated personal dosimetry system, are described. An ultra-thin lithium borate dosemeter has been developed for skin absorbed dose measurement. The X-ray, gamma-ray and beta-ray energy response of the dosemeter has been investigated and the angular response for the dosemeter has been examined. The annealing, read-out and stabilisation procedures for the dosemeter are described.

  2. RHIC Sextant Test -- Physics and performance

    This paper presents beam physics and machine performance results of the Relativistic Heavy Ion Collider (RHIC) Sextant and AGS-to-RHIC (AtR) transfer line during the Sextant Test in early 1997. Techniques used to measure both machine properties (difference orbits, dispersion, and beamline optics) and beam parameters (energy, intensity, transverse and longitudinal emittances) are described. Good agreement was achieved between measured and design lattice optics. The gold ion beam quality was shown to approach RHIC design requirements

  3. HSE performance tests for dosimetry services

    In the United Kingdom a dosimetry service that measures and assesses whole-body or part-body doses arising from external radiation must successfully complete a performance test. Results of the performance tests for routine whole-body, routine extremity/skin and special accident dosimetry, carried out over the past six years by the AEA Technology Calibration Service at Winfrith, and DRaStaC, the AWE Calibration Service at Aldermaston, are presented. The test involves irradiating groups of dosemeters to known doses of gamma radiation and determining the bias and relative standard deviations for each dose group. The results are compared with the pass criteria specified by the UK Health and Safety Executive. For routine whole-body dosimetry, both the film badge and thermoluminescent dosemeter (TLD) perform adequately for irradiations between 0.6 and 30 mSv. For higher doses up to 250 mSv, where the slow emulsion of the film is used, the film badge shows poorer performance with a tendency to overestimate the dose. For routine extremity/skin dosimetry there is a wider spread of relative standard deviation results than is seen for routine whole-body dosimetry. This is to be expected since the results will include dosemeters that are based on 'disposable' TLDs and ones based on lithium fluoride powder in sachets. For special accident dosimetry the dosemeters are tested between 0.26 and 6 Gy. For the highest dose group the film badge invariably underestimates the true dose, whereas the TLD has a tendency to overestimate it. (author)

  4. Performance test of a TMS calorimeter

    Performance tests of a first calorimeter module using the room temperature liquid tetramethylsilane (TMS) as active element are described in detail. As absorber planed carbon steel slabs had been used. The charge yield is 70% of that in a very pure sample of the liquid. A long term stability of the signal with a lifetime of half a year has been realized. Experiences are described and the results explained in detail. (orig.)

  5. MEMS performance challenges: packaging and shock tests

    Chang, Jiyoung; Yang, Chen; Zhang, Bin; Lin, Liwei

    2011-06-01

    This paper describes recent advances in the MEMS performance challenges with emphases on packaging and shock tests. In the packaging area, metal to metal bonding processes have been developed to overcome limitations of the glass frit bonding by means of two specific methods: (1) pre-reflow of solder for enhanced bonding adhesion, and (2) the insertion of thin metal layer between parent metal bonding materials. In the shock test area, multiscale analysis for a MEMS package system has been developed with experimental verifications to investigate dynamic responses under drop-shock tests. Structural deformation and stress distribution data are extracted and predicted for device fracture and in-operation stiction analyses for micro mechanical components in various MEMS sensors, including accelerometers and gyroscopes.

  6. DPM PERFORMANCE TESTING USING RASPBERRY PIS

    Regala, M

    2013-01-01

    This is the final report from attending CERN’s Summer Student Programme. The project goal was to do performance testing on the Disk Pool Manager (DPM), a lightweight, reliable, grid-aware storage software used to store and retrieve data produced by CERN’s LHC experiments using the small, low-end ARM powered devices named Raspberry Pis. The idea behind it was to reason if it’s possible to use a cluster of lower-end, under-capable devices to run DPM, and to conclude if it would be more energy efficient than running it on oversized machines, with the same or comparable performance. If this hypothesis was true, the power-hungry machines could be ditched in favour of these small devices, leading to an enormous saving in overall power consumption and hence, overall cost. In this report, I describe what was the initial project goal and intended outcomes, proceeding to explain the underlying technologies used. Afterwards, I’ll explain the setup used, the tests performed, and the conclusions reached. iii

  7. O2- and NOsub(x)-removal from the dissolver off-gas by thermal reduction with H2 or NH3

    The reference process for the removal of O2 and NOsub(x) from the dissolver off-gas is the catalytic reduction with H2. Because of the known disadvantages of catalysts, like reduction in efficiency by poisoning or thermal influence, the alternative method of thermal, flameless reduction with H2 and NH3 was tested. The reactions were carried out in a stainless steel and a quartz reactor. Both had a length of 850 mm, an inner diameter of 53 mm, and were heated by resistance heaters on the outside. The main component of the test gases was N2. Tested throughputs were 600, 800, and 1000 l/h (STP). Different amounts of O2 (0.5 and 1%), NO (750 and 1500 ppm) and H2 or NH3 (-40 to +100% of stoichiometric supply) were added. The reaction temperatures were varied between 450 and 750 deg. C. The goal of these tests was to remove O2 and NOsub(x) to below 1 ppm behind the reactor and NH3 (which is formed in the NOsub(x)-H2-reaction) to below the detection limit of 50 ppm

  8. EURADOS trial performance test for photon dosimetry

    Within the framework of the EURADOS Action entitled Harmonisation and Dosimetric Quality Assurance in Individual Monitoring for External Radiation, trial performance tests for whole-body and extremity personal dosemeters were carried out. Photon, beta and neutron dosemeters were considered. This paper summarises the results of the whole-body photon dosemeter test. Twenty-six dosimetry services from all EU Member States and Switzerland participated. Twelve different radiation fields were used to simulate various workplace irradiation fields. Dose values from 0.4 mSv to 80 mSv were chosen. From 312 single results, 26 fell outside the limits of the trumpet curve and 32 were outside the range 1/1.5. Most outliers resulted from high energy R-F irradiations without electronic equilibrium. These fields are not routinely encountered by many of the participating dosimetry services. If the results for this field are excluded, most participating services satisfied the evaluation criteria. (author)

  9. PERFORMANCE TESTING AND ANALYSIS OF CUPOLA FURNACE

    PROF.HEMANT R. BHAGAT-PATIL; MEGHA S. LONDHEKAR

    2013-01-01

    In today’s industrial scenario huge losses/wastage occur in the manufacturing shop floor and foundry industries. The efficiency of any foundry largely depends on the efficiency of the melting process amulti-step operation where the metal is heated, treated, alloyed, and transported into die or mold cavities to form a casting. In this paper we represents the performance testing and analysis of Cupola Furnace, and reduces the problems occurs to give the best results. Our main focus in this work...

  10. Performance testing of UK personal dosimetry laboratories

    Marshall, T O

    1985-01-01

    The proposed Ionising Radiations Regulations will require all UK personal dosimetry laboratories that monitor classified personnel to be approved for personal dosimetry by the Health and Safety Executive. It is suggested that these approvals should be based on general and supplementary criteria published by the British Calibration Service (BCS) for laboratory approval for the provision of personal dosimetry services. These criteria specify certain qualitative requirements and also indicate the need for regular tests of performance to be carried out to ensure constancy of dosimetric standards. This report concerns the latter. The status of the BCS criteria is discussed and the need for additional documents to cover new techniques and some modifications to existing documents is indicated. A means is described by which the technical performance of laboratories, concerned with personal monitoring for external radiations, can be assessed, both initially and ongoing. The costs to establish the scheme and operate it...

  11. Performance testing of UK personal dosimetry laboratories

    The proposed Ionising Radiations Regulations will require all UK personal dosimetry laboratories that monitor classified personnel to be approved for personal dosimetry by the Health and Safety Executive. It is suggested that these approvals should be based on general and supplementary criteria published by the British Calibration Service (BCS) for laboratory approval for the provision of personal dosimetry services. These criteria specify certain qualitative requirements and also indicate the need for regular tests of performance to be carried out to ensure constancy of dosimetric standards. This report concerns the latter. The status of the BCS criteria is discussed and the need for additional documents to cover new techniques and some modifications to existing documents is indicated. A means is described by which the technical performance of laboratories, concerned with personal monitoring for external radiations, can be assessed, both initially and ongoing. The costs to establish the scheme and operate it are also estimated. (author)

  12. SNL Sigma Off-Gas Team Contribution to the FY15 DOE/NE-MRWFD Campaign Accomplishments Report.

    Nenoff, Tina M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-08-21

    This program at Sandia is focused on Iodine waste form development for Fuel Cycle R&D needs. Our research has a general theme of “Capture and Storage of Iodine Fission Gas “ in which we are focused on silver loaded zeolite waste forms, evaluation of iodine loaded getter materials (eg., mordenite zeolite), and the development of low temperature glass waste forms that successfully incorporate iodine loaded getter materials from I2, organic iodide, etc. containing off-gas streams.

  13. Novel synthesis of bismuth-based adsorbents for the removal of 129I in off-gas

    New adsorbents based on bismuth were investigated for the capture of iodine-129 (129I) in off-gas produced from spent fuel reprocessing. Porous bulky materials were synthesized with polyvinyl alcohol (PVA) as a sacrificial template. Our findings showed that the iodine trapping capacity of as-synthesized samples could reach 1.9-fold that of commercial silver-exchanged zeolite (AgX). The thermodynamic stability of the reaction products explains the high removal efficiency of iodine. We also found that the pore volume of each sample was closely related to the ratio of the reaction products

  14. Standard specification for agencies performing nondestructive testing

    American Society for Testing and Materials. Philadelphia

    2009-01-01

    1.1 This specification covers minimum requirements for agencies performing nondestructive testing (NDT). 1.2 When using this specification to assess the capability of, or to accredit NDT agencies, Guide E 1359 shall be used as a basis for the survey. It can be supplemented as necessary with more detail in order to meet the auditor's specific needs. 1.3 This specification can be used as a basis to evaluate testing or inspection agencies, or both, and is intended for use for the qualifying or accrediting, or both, of testing or inspection agencies, public or private. 1.4 The use of SI or inch-pound units, or combination thereof, will be the responsibility of the technical committee whose standards are referred to in this standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to...

  15. CFC and HFC recycling equipments: Test performances

    Actual regulatory conditions about ozone layer depleting chemicals set problems on their disposal and on the management of plants still using illegal CFCs. Anyway fluids that will replace CFCs (i.e. HFCs) will not be allowed to be spread into the atmosphere, due to their high costs and to the greenhouse effect. A viable solution would be the recovery, purification and recycle of contaminated fluids. ENEA (National Agency for New Technology, Energy and the Environment), in cooperation with ICF (Industria Componenti Frigoriferi) Company leader in the field of air refrigerating and conditioning, patented a device able to extract, to clean and to recycle CFC 12 and HFC 134a in the refrigerating systems. This paper presents experimental data from the qualification tests on a device performing the above mentioned operations regarding systems that use HFC 134a as process fluid

  16. RHIC Sextant Test --- Physics and Performance

    Wei, J.; Fischer, W.; Ahrens, L.; Brennan, J. M.; Brown, K.; Connolly, R.; dell, G. F.; Harrison, M.; Kewisch, J.; Mackay, W. W.; Mane, V.; Peggs, S.; Pilat, F.; Satogata, T.; Tepikian, S.; Thompson, P.; Trahern, C. G.; Trbojevic, D.; Tsoupas, N.

    1997-05-01

    This paper presents beam physics and machine performance results of the Relativistic Heavy Ion Collider (RHIC) Sextant and AGS-to-RHIC (ATR) transfer line during the Sextant test in early 1997. Techniques used to measure both machine properties (difference orbits, dispersion, and beamline optics) and beam parameters (energy, intensity, transverse and longitudinal emittances) are described. The flexibility of the ATR and RHIC Sextant lattices is demonstrated by a widely tunable range of phase advance per cell. Longitudinal tomography is employed to reconstruct beam motion in phase space. Digitized two-dimensional video profile monitors are used to measure transverse beam emittances and beamline optics. The gold ion beam parameters are shown to be comparable to the RHIC design requirements.

  17. Detonation Performance Testing of LX-19

    Vincent, Samuel; Aslam, Tariq; Jackson, Scott

    2015-06-01

    CL-20 was developed at the Naval Surface Weapons Center at China Lake, CA in the mid 80's. Being less sensitive than PETN, but considerably more powerful than HMX, it is the highest energy and density compound known among organic chemicals. LX-19 was developed at LLNL in the early 90's. It is a high-energy plastic bonded explosive, composed of 95.8 wt% CL-20 and 4.2 wt% Estane binder, and is similar to LX-14 (composed of HMX and Estane), but with greater sensitivity characteristics with use of the more energetic CL-20 explosive. We report detonation performance results for unconfined cylindrical rate sticks of LX-19. The experimental diameter effects are shown, along with detonation front shapes, and reaction zone profiles for different test diameters. This data is critical for calibration to Detonation Shock Dynamics (DSD). LA-UR-15-20672.

  18. PERFORMANCE TESTING AND ANALYSIS OF CUPOLA FURNACE

    PROF.HEMANT R. BHAGAT-PATIL

    2013-05-01

    Full Text Available In today’s industrial scenario huge losses/wastage occur in the manufacturing shop floor and foundry industries. The efficiency of any foundry largely depends on the efficiency of the melting process amulti-step operation where the metal is heated, treated, alloyed, and transported into die or mold cavities to form a casting. In this paper we represents the performance testing and analysis of Cupola Furnace, and reduces the problems occurs to give the best results. Our main focus in this work is to improve continuous working hours,reducing preparation time, reducing losses in melting, reducing slag formation and to increase the combustion efficiency of coke and overall productivity and to improve the quality and Mechanical properties of steel using Cupola.

  19. Performance testing of passive autocatalytic recombiners (PARs)

    Passive autocatalytic recombiners (PARs) have been under consideration in the U.S. as a combustible gas control system in advanced light water reactor (ALWR) containments for design basis and severe accidents. PARs do not require a source of power. Instead they use palladium or platinum as a catalyst to recombine hydrogen and oxygen gases into water vapor upon contact with the catalyst. Energy from the recombination of hydrogen with oxygen is released at a relatively slow but continuous rate into the containment which prevents the pressure from becoming too high. The heat produced creates strong buoyancy effects which increases the influx of the surrounding gases to the recombiner. These natural convective flow currents promote mixing of combustible gases in the containment. PARs are self-starting and self-feeding under a very wide range of conditions. The recombination rate of the PAR system needs to be great enough to keep the concentration of hydrogen (or oxygen) below acceptable limits. There are several catalytic recombiner concepts under development worldwide. The USNRC is evaluating a specific design of a PAR which is in an advanced stage of engineering development and has been proposed for ALWR designs. Sandia National laboratories (SNL), under the sponsorship and the direction of the USNRC, is conducting an experimental program to evaluate the performance of PARs. The PAR will be tested at the SURTSEY facility at SNL. The test plan currently includes the following experiments: experiments will be conducted to define the startup characteristics of PARs (i.e., to define what is the lowest hydrogen concentration that the PAR starts recombining the hydrogen with oxygen); experiments will be used to define the hydrogen depletion rate of PARs as a function of hydrogen concentration; and experiments will be used to define the PAR performance in the presence of high concentrations of steam. (author)

  20. Performance tests on helical Savonius rotors

    Kamoji, M.A.; Kedare, S.B. [Department of Energy Science and Engineering, Indian Institute of Technology, Bombay (India); Prabhu, S.V. [Department of Mechanical Engineering, Indian Institute of Technology, Bombay (India)

    2009-03-15

    Conventional Savonius rotors have high coefficient of static torque at certain rotor angles and a negative coefficient of static torque from 135 to 165 and from 315 to 345 in one cycle of 360 . In order to decrease this variation in static torque from 0 to 360 , a helical Savonius rotor with a twist of 90 is proposed. In this study, tests on helical Savonius rotors are conducted in an open jet wind tunnel. Coefficient of static torque, coefficient of torque and coefficient of power for each helical Savonius rotor are measured. The performance of helical rotor with shaft between the end plates and helical rotor without shaft between the end plates at different overlap ratios namely 0.0, 0.1 and 0.16 is compared. Helical Savonius rotor without shaft is also compared with the performance of the conventional Savonius rotor. The results indicate that all the helical Savonius rotors have positive coefficient of static torque at all the rotor angles. The helical rotors with shaft have lower coefficient of power than the helical rotors without shaft. Helical rotor without shaft at an overlap ratio of 0.0 and an aspect ratio of 0.88 is found to have almost the same coefficient of power when compared with the conventional Savonius rotor. Correlation for coefficient of torque and power is developed for helical Savonius rotor for a range of Reynolds numbers studied. (author)

  1. I-129, Kr-85, C-14 and NO/sub x/ removal from spent fuel dissolver off-gas at atmospheric pressure and at reduced off-gas flow

    A dissolver off-gas (DOG) system suitable for a LWR, FBR or HTR spent fuel reprocessing plant is described, incorporating the following features: (1) the DOG flow is reduced to a reasonably small volume, using fumeless dissolution conditions, by maintaining high concentrations, the retention procedures are simplified and accompanied by an economic reduction of the equipment size; (2) all process operations are conducted at atmospheric or subatmospheric pressure, including noble gas removal by selective absorption, without using high temperature processes; (3) all processes, except HEPA filtering, are continuous and do not accumulate large amounts of waste nuclides, the DOG process sequence is mutually compatible with itself and with processing in the headend, showing on-line redundancy for the removal of the most radiotoxic nuclides; and (4) the DOG system only deviates slightly from proven technology. The stage of development and relevant results are given both for a lab. scale and a pilot plant scale

  2. Catalytic O2- and NOsub(x)-removal: a process step for an off-gas cleaning system in reprocessing plants

    The last step of an off-gas purification system for future reprocessing plants of spent nuclear fuels is the retention of the radioactive krypton. If a cryogenic distillation process is chosen for this step, O2 and NOsub(x) must be removed prior to the cryogenic part in order to avoid radiolytic formation of ozone and crystallization problems, respectively. Simultaneous catalytic reduction with H2 was chosen using ruthenium on A12O3 as catalyst. The process step was tested in a semiscale unit with a gas throughput of 50 m3/h. The feed-gas was diluted by N2 in a gas loop by a factor of 10, to prevent formation of explosive gas mixtures. Residual O2- and NOsub(x)-concentrations 1 ppmv were attained routinely in the temperature range of the catalyst between 3500C and 5500C and at space velocities (GHVS) between 10000 and 15000 h-1. Formation of CH4 is very low (2O). H2 feed control is carried out by means of chemical analysis of O2 and NOsub(x) in the feed gas by calculating the necessary H2 amount and controlling the main H2-valve with a microcomputer. An additional small H2-valve is controlled by analysis of the H2 excess behind the catalyst bed. Even large concentration transients of O2 and NOsub(x) can thus be handled by the catalyst without breakthrough. (author)

  3. Customized design of electronic noses placed on top of air-lift bioreactors for in situ monitoring the off-gas patterns.

    Rosi, Pablo E; Miscoria, Silvia A; Bernik, Delia L; Martín Negri, R

    2012-06-01

    A specially designed electronic nose was coupled to an air-lift bioreactor in order to perform on-line monitoring of released vapors. The sensor array was placed at the top of the bioreactor sensing the headspace in equilibrium with the evolving liquor at any time without the need of aspiration and pumping of gases into a separated sensor chamber. The device was applied to follow the off-gas of a bioreactor with Acidithiobacillus thiooxidans grown on beds of elemental sulfur under aerobic conditions. Evolution was monitored by acid titration, pH and optical density measurements. The electronic nose was capable to differentiate each day of reactor evolution since inoculation within periods marked off culture medium replacements using multivariate data analysis. Excellent discrimination was obtained indicating the potentiality for on-line monitoring in non-perturbed bioreactors. The prospects for electronic nose/bioreactor merging are valuable for whatever the bacterial strain or consortium used in terms of scent markers to monitor biochemical processes. PMID:22212349

  4. Comparison of thermochemically calculated and measured dioxin contents in the off-gas of a sinter plant

    Spencer, P.; Eriksson, G.; Neuschuelz, D. [Lehrstuhl fuer Theoretische Huettenkunde, Aachen (Germany)

    1997-12-31

    Polychlorinated dibenzo-p-dioxins and dibenzo-furans form a family of more than 200 compounds which are relatively stable in the biosphere and tend to accumulate in the human body. The tetra- to hexa-chlorinated dioxins and furans are considered highly toxic. To facilitate the assessment of the total toxicity of dioxin and furan mixtures, the estimated toxic effects of the individual compounds relative to the 2,3,7,8-tetrachloro-dibenzo-p-dioxin (TCDD) were introduced as Toxic Equivalent Factors which yield, when multiplied with the respective concentrations, the Toxic Equivalent (TE) of the mixture. Toxic dioxins and furans are unintentionally formed in a number of industrial combustion processes such as waste incineration and iron ore sintering, in the chemical industry and in household heating. To keep the emissions as low as possible, off-gas clearing systems for the collection of dioxins and furans are increasingly prescribed by the authorities. In addition, it appears desirable to select process conditions that are unfavourable for the formation of these compounds. A simulation of the relevant processes on the basis of thermodynamic data may be helpful in defining such process conditions. To simulate dioxin formation in the sintering process, all major gas-solid reactions taking place in the sinter bed must also be simulated. A sufficiently accurate reproduction of the off-gas compositions along the length of the sinter strand requires detailed assumptions concerning the relative amounts of `active` O{sub 2} as well as the distribution of reacting carbon and water over the strand length. From this basis, an equilibrium calculation for the gas/solid reactions at the sintering temperature of 1150 deg C and an equilibrium calculation restricted to the gas phase at 700 deg C produced values for the concentrations of the major off-gas constituents in very good agreement with the measured values. The further assumption that below 700 deg C all reactions are frozen

  5. A Literature Survey to Identify Potentially Volatile Iodine-Bearing Species Present in Off-Gas Streams

    Bruffey, S. H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Spencer, B. B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Strachan, D. M. [Strata-G, Knoxville, TN (United States); Jubin, R. T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Soelberg, N. R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Riley, B. J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-06-30

    Four radionuclides have been identified as being sufficiently volatile in the reprocessing of nuclear fuel that their gaseous release needs to be controlled to meet regulatory requirements (Jubin et al. 2011, 2012). These radionuclides are 3H, 14C, 85Kr, and 129I. Of these, 129I has the longest half-life and potentially high biological impact. Accordingly, control of the release of 129I is most critical with respect to the regulations for the release of radioactive material in stack emissions. It is estimated that current EPA regulations (EPA 2010) would require any reprocessing plant in the United States to limit 129I release to less than 0.05 Ci/MTIHM for a typical fuel burnup of 55 gigawatt days per metric tonne (GWd/t) (Jubin 2011). The study of inorganic iodide in off-gas systems has been almost exclusively limited to I2 and the focus of organic iodide studies has been CH3I. In this document, we provide the results of an examination of publically available literature that is relevant to the presence and sources of both inorganic and organic iodine-bearing species in reprocessing plants. We especially focus on those that have the potential to be poorly sequestered with traditional capture methodologies. Based on the results of the literature survey and some limited thermodynamic modeling, the inorganic iodine species hypoiodous acid (HOI) and iodine monochloride (ICl) were identified as potentially low-sorbing iodine species that could present in off-gas systems. Organic species of interest included both short chain alkyl iodides such as methyl iodide (CH3I) and longer alkyl iodides up to iodododecane (C10H21I). It was found that fuel dissolution may provide conditions conducive to HOI formation and has been shown to result in volatile long-chain alkyl iodides, though these may not volatilize until later in the reprocessing sequence. Solvent extraction processes were found to be significant sources of various organic iodine-bearing species; formation of these

  6. Separation of the fission product noble gases krypton and xenon from dissolver off-gas in reprocessing HTGR-fuel

    This paper describes a process developed for the retainment and separation of volatile (3H, 129+131I) and gaseous (85Kr, Xe) fission products from the off-gas produced during dissolution of HTGR-fuel. To prevent unnecessary dilution of liberated noble gases by surrounding atmosphere, a helium purge-gas cycle is applied to enable a coarse fractionating of krypton and xenon by cold-trapping at about 800K after precleaning the gas stream. The process consists of the following steps: deposition of droplets and solid aerosols; chemisorption of iodine on silver impregnated silica gel; catalytic removal of nitrogen oxides and oxygen; drying of the process gas stream; final filtering of abraded solids; deposition of xenon in solid form at 800K and low subpressure; deposition of krypton in solid form at 800K after compression to about 6 bar; decontamination of 85Kr-containing xenon by batch distillation for eventual industrial utilization; and removal of nitrogen and argon enrichment during continuous operation in the purge-gas stream by inleaking air with charcoal. A continuously operating dissolver vessel, closed to the surrounding atmosphere, yields a very high content of noble gases, i.e., 0.35 vol % krypton and 2.0 vol % xenon. The presented off-gas treatment unit is operated in cold runs with 1/3 of the full capacity and can treat about 1 m3 STP/h helium, corresponding to a quantity of about 10,000 MW/sub e/ HTGR-fuel reprocessing plant

  7. Integrated Performance Testing Workshop - Supplemental Materials (Scripts and Procedures)

    Baum, Gregory A.

    2014-02-01

    A variety of performance tests are described relating to: Material Transfers; Emergency Evacuation; Alarm Response Assessment; and an Enhanced Limited Scope Performance Test (ELSPT). Procedures are given for: nuclear material physical inventory and discrepancy; material transfers; and emergency evacuation.

  8. Testing Assumptions about Evaluating Strategic Alliance Performance

    Olk, Paul; Ariño, Africa

    2003-01-01

    Researchers have used a variety of measures to evaluate strategic alliance performance. In this paper we use data collected on performance of R&D consortia in the U.S. and of Spain-based equity and non-equity dyadic alliances to investigate empirically five basic assumptions made by strategic alliance researchers. We find that while several assumptions are supported, others are not. Results are consistent across samples. We conclude with recommendations for how to evaluate performance in futu...

  9. 40 CFR 60.543 - Performance test and compliance provisions.

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Performance test and compliance... Rubber Tire Manufacturing Industry § 60.543 Performance test and compliance provisions. (a) Section 60.8... measurement of capture system retention time or face velocity. The performance test shall be conducted...

  10. Off-gas treatment for pressurized water reactors by absorption of xenon and krypton in fluorocarbons

    Pilot plant tests showed selective absorption of krypton and xenon in dichlorodifluoromethane produced concentrations as low as 40 ppb and 3 ppb, respectively. Satisfactory operation was demonstrated for a variety of carrier gases including hydrogen, nitrogen, air, helium, and argon. Charcoal absorption, cryogenic absorption, and cryogenic distillation techniques were compared disadvantageously to the fluorocarbon solvent method. (PCS)