Energy Technology Data Exchange (ETDEWEB)

The authors measured the absorption of CO{sub 2} in alkaline 0.5 M/0.5 M sodium carbonate/bicarbonate buffers containing either saccharose and sodium arsenite or saccharose and formaldehyde. Absorption enhancement increased upon increasing the concentration of either of the catalysts, but the joint action of the two was always less than the sum of their individual effects, the difference being a function of the acidities and concentrations of the catalysts and the pH of the carbonate/bicarbonate buffer solution

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The values of -{delta}G{sub A}{sup O} of n-alkanes on calcite are lower on the stearic acid treated calcite than on the untreated calcite. The value of -{delta}G{sub A}{sup O} of n-alkanes on calcite increase with increasing carbon numbers of n-alkanes. The values of -{delta}G{sub A}{sup O} measured on the treated calcite are significantly lower than those measured on the untreated calcite. The -{delta}G{sub A}{sup O} of n-alkanes on the treated calcite are close to the heat of liquefaction of n-alkanes. All the experimental values of -{delta}G{sub A}{sup O} of n-alkanes on calcite are larger than theoretical entropy decrease particularly for the higher molecular mass n-alkanes. Thus the important entropy decrease observed upon adsorption can not only be attributed to the loss of one degree of freedom of the adsorbed ...

British Library Electronic Table of Contents (United Kingdom)

The main objective of this work was to investigate the biosorption performance of unmodified and Cetylpyridinium chloride (CPC)-modified biomass of Penicillium YW 01 for Acid Blue 25 (AB 25). Maximum biosorption capacity of AB 25 onto CPC-modified biosorbent was 118.48mgg^-^1 under phosphoric-phosphate buffer with initial dye concentration of 200mgL^-^1 at 30^oC. The biosorption pattern of AB 25 onto unmodified biosorbent in aqueous solution and phosphoric-phosphate buffer was well fitted with both Langmuir and Freundlich isotherm models. While the equilibrium data of CPC-modified biosorbent in aqueous solution and phosphoric-phosphate buffer failed to fit the Freundlich isotherm model, indicating the monolayer biosorption formed onto CPC-modified biosorbent. The values of initial biosorpt...

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Semiconductor properties of passive films formed on the Fe-18Cr alloy in a borate buffer solution (pH = 8.4) and 0.1 M H{sub 2}SO{sub 4} solution were examined using a photoelectrochemical spectroscopy and an electrochemical impedance spectroscopy. Photo current reveals two photo action spectra that derived from outer hydroxide and inner oxide layers. A typical n-type semiconductor behaviour is observed by both photo current and impedance for the passive films formed in the borate buffer solution. On the other hand, a negative photo current generated, the absolute value of which decreased as applied potential increased in the sulfuric acid solution. This indicates that the passive film behaves as a p-type semiconductor. However, Mott-Schottky plot revealed the typical n-type semiconductor property. It is concluded that the passive film on the Fe-18Cr alloy ...

British Library Electronic Table of Contents (United Kingdom)

Variability in production is one of the largest factors that negatively impacts construction project performance. A common construction practice to protect production systems from variability is the use of buffers (Bf). Construction practitioners and researchers have proposed buffering approaches for different production situations, but these approaches have faced practical limitations in their application. A multiobjective analytic model (MAM) is proposed to develop a graphical solution for the design of Work-In-Process (WIP) Bf in order to overcome these practical limitations to Bf application, being demonstrated through the scheduling of repetitive building projects. Multiobjective analytic modeling is based on Simulation?Optimization (SO) modeling and Pareto Fronts concepts. Simulation...

British Library Electronic Table of Contents (United Kingdom)

SUMMARY Spontaneous potentials associated with volcanic activity are often interpreted by means of the electrokinetic potential, which is usually positive in the flow direction (i.e. Zeta potential of the rock is negative). The water-rock interactions in hydrothermal zones alter the primary minerals leading to the formation of secondary minerals. This work addresses the study of calcite precipitation in a sand composed of 98 per cent quartz and 2 per cent calcite using streaming potential measurements. The precipitation of calcite as a secondary mineral phase, inferred by high calcite saturation indices and by a fall in permeability, has a significant effect on the electrokinetic behaviour, leading to a significant reduction in the Zeta potential (in absolute value) and even a change in si...

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Adsorption of phosphate (PO{sub 4}{sup 3{minus}}) from aqueous solution on activated red mud (ARM) was studied as a function of time, pH, temperature, concentration of adsorbent and adsorbate in acetic acid-sodium acetate buffer medium. The adsorption of phosphate follows Langmuir as well as Freundlich adsorption isotherms. The process efficiency was found to be 80--90% at room temperature. This can be extended to the treatment of industrial effluents containing phosphates like that from phosphatic fertilizer plants.

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A process model was used to better understand the controls on the chemical evolution of drainage in a historic mining district. At the Pecos Mine Operable Unit, New Mexico, drainage near the waste rock pile is acidic (pH varies from 3.0--5.0) and carries high concentrations of Zn, Al, Cu and Pb. As drainage flows toward the Pecos River, pH increases to greater than 7 and heavy metal content decreases. A process model of natural attenuation in this drainage shows the main controls on pH are reaction with a local bedrock that contains limestone, and concurrent mixing with tributary streams. Models that account for both calcite dissolution and mixing reproduce the observed decrease in aqueous metal concentrations with increasing pH. Contaminant concentrations attenuate primarily via two distinct pathways: Al, Cu, Fe and Pb precipitate directly from solution, whereas Zn, Mg, Mn and SO{sub 4} concentrations decrease primarily through dilution. ...

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The chemical composition and the semiconducting properties of passive films formed on nickel based alloy (Alloy 600) in acidic sulphate solution, pH 2.0 at room temperature were studied using Auger analysis, voltammetric techniques and the Mott-Schottky approach. The results obtained revealed that the presence of both chromium and mixed nickel-iron oxides in the films leads to the development of a p-n heterojunction, which controls their electronic structure, similarly manner to the case of stainless steels and Alloy 600 in borate buffer solution. This behavior has been interpreted as representing of an oxide system, which has a duplex character, with an inner p-type semiconducting region, mainly formed by chromium oxide and an outer n-type semiconducting region, containing iron oxide. It could also be observed that the nickel oxide present in the films acts as a barrier layer conferring improved protection.

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The influence of small amounts of alloying elements (0.36% Cu and 0.47% Cr) on the semiconducting properties of passive films formed on weathering steels was investigated either in tetraborate/boric acid buffer solution (pH 9.2) or artificial atmospheric environment (SO{sub 2}-containing environment). The electrochemical behaviour was assessed by potentiodynamic polarisation, capacitance measurements and photoelectrochemistry. The chemical characterisation of the films was carried by Auger electron spectroscopy. The polarization results obtained in the buffer solution show that the addition of chromium decreases the passive current density. The capacitance results show that the films behave as an n-type semiconductor with shallow and deep donor levels situated in the forbidden gap. The presence of copper seems to affect the density of the shallow and of the deep donor levels in the forbidden gap, and as ...

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Research highlights: {yields} The polarization curve of 316L SS possesses five turning potentials in passive region. {yields} Films formed at turning potentials perform different electrochemical and semiconductor properties. {yields} Dissolutions and regenerations of passive film at turning potentials are obtained by AAS and XPS. {yields} Turning potentials appearing in passive region are ascribed to the changes of the compositions of the passive films. - Abstract: The passivity of 316L stainless steel in borate buffer solution has been investigated by Mott-Schottky, atomic absorption spectrometry (AAS) and X-ray photoelectron spectroscopy (XPS). The results indicate that the polarization curve in the passive region possesses several turning potentials (0 V{sub SCE}, 0.2 V{sub SCE}, 0.4 V{sub SCE}, 0.6 V{sub SCE} and 0.85 V{sub SCE}). The passive films formed at turning potentials perform different electrochemical and semiconductor properties. ...

British Library Electronic Table of Contents (United Kingdom)

Abstract Dispersions of single-walled carbon nanotubes (SWNTs) in various surfactant solutions have been systematically evaluated as additives in MEEKC. The compounds examined were catechins, phenolic acids, and flavonoids. Compared with zwitterionic and neutral surfactants, the addition of anionic dispersion seemed to be better at separating the three types of analytes in microemulsion system. In order to achieve low operating currents, an in situ-synthesized surfactant system based on the combination of a long-chain alkyl acid with an organic base was used in MEEKC. The optimized buffer contained 0.5% (57-mM) ethyl acetate, 0.6% (30-mM) lauric acid, 4.0% (666-mM) propanol, 50-mM Tris solution, and 4.5-mg/L the dispersion of SWNTs. Under optimized conditions, the established method was ap...

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The possibilities to electrodeposit thick coatings composed of nanoparticles of Sb and Sb{sub 2}O{sub 3} for use as high-capacity anode materials in Li-ion batteries have been investigated. It is demonstrated that the stability of the coatings depends on their Sb{sub 2}O{sub 3} concentrations as well as microstructure. The electrodeposition reactions in electrolytes with different pH and buffer capacities were studied using chronopotentiometry and electrochemical quartz crystal microbalance measurements. The obtained deposits, which were characterised with XRD and SEM, were also tested as anode materials in Li-ion batteries. The influence of the pH and buffer capacity of the deposition solution on the composition and particle size of the deposits were studied and it is concluded that depositions from a poorly buffered solution of antimony-tartrate give rise to good anode materials ...

Science.gov (United States)

... a buffer of all biological resources in the Kenai Fjords National Park Area. Data from Alaska Fish ... ...

International Nuclear Information System (INIS)

Microsecond pulse radiolysis of oxygenated aqueous solutions containing 0.02 mol dm"-"3 sodium formate and 2 mmol dm"-"3 phosphate buffer at pH 7 was used to generate superoxide anion radicals. The influence of some biologically important compounds upon the rate of O_2"."-"b"a"r decay as monitored spectrophotometrically in the range of 245-300 nm. Hematoporphyrin (HP), hemin C (HC), catalase (Cat), cobalt sulfophthalocyanine (CoTSPc) were studied. Among the investigated compounds only Cat was found to show a high catalytic efficiency towards the self-decay of O_2"."-"b"a"r. A red shift of 0_2"."-"b"a"r absorption band and slowing down of its decay were observed to take place by adding HP or CoTSPc to the solutions containing formate ions in excess. This effect is associated with the formation of a transient superoxo-complex. An appearance of an intermediate species with absorption maxima at 350 nm and half-life of about 2 s ...

Energy Technology Data Exchange (ETDEWEB)

We have grown ferroelectric Pb{sub 0.92}La{sub 0.08}Zr{sub 0.52}Ti{sub 0.48}O{sub 3} (PLZT) films on platinized silicon and LaNiO{sub 3}-buffered nickel substrates by chemical solution deposition using a sol-gel process based on acetic acid chemistry. The following measurements were obtained under zero-bias field: relative permittivity of {approx}960 and dielectric loss of {approx}0.04 on the PLZT film grown on Pt/Si substrates, and relative permittivity of {approx}820 and dielectric loss of {approx}0.06 on the PLZT film grown on LNO-buffered Ni substrates. In addition, a relative permittivity of 125 and dielectric loss of 0.02 were measured at room temperature under a high bias field of 1 x 10{sup 6} V/cm on PLZT deposited on LNO-buffered nickel substrate. Furthermore, a steady-state leakage current density of {approx}8.1 x 10{sup -9} A/cm{sup 2} and mean breakdown field strength of 1.7 x 10{sup 6} ...

International Nuclear Information System (INIS)

Reliable and consistent characterization of the stable isotope composition of atmospheric water vapour and its temporal variability are important prerequisites to the wider application of isotope mass balance methods in atmospheric and water balance studies. A new approach is proposed which utilizes standard class-A evaporation pans, which have sufficient volume to buffer short-term transient variations in atmospheric conditions, justifying the assumption of constant kinetic isotopic fractionation effects in concert with precisely measured temperature and relative humidity to derive vapour isotopic composition. The results of the studies suggest that isotopic sampling of existing, conventionally operated class-A evaporation pans could offer a straightforward and cost-effective solution to the problem of documenting the shifting isotopic distribution in atmospheric moisture

Energy Technology Data Exchange (ETDEWEB)

Passive films formed on stainless steels in a borate buffer solution (pH 9.2) have been investigated by capacitance measurements and photoelectrochemistry. The study was carried out on films formed on AISI type 304 and 316 stainless steels and high purity alloys with differing chromium, nickel, and molybdenum contents. Complementary research by Auger analysis shows that the passive films are composed essentially of an inner chromium region in contact with the metallic substrate and an outer iron oxide region developed at the film/electrolyte interface. The semiconducting properties of the passive films are determined by those of the constituent chromium and iron oxides which are of p-type and n-type, respectively. Thus the influence of the alloying elements on the semiconducting properties of the passive films is explained by changes in the electronic structure of each of these two oxide regions.

Energy Technology Data Exchange (ETDEWEB)

The rate of the oxygen-exchange reaction in an aqueous solution of a heterocyclic oxygen compound, 2,4,6-trimethylpyrylium perchlorate, was quantitated. The /sup 18/O isotope effect in /sup 13/C NMR spectroscopy affords a direct, continuous, and relatively simple analysis of the reaction and was used to obtain data on the incorporation of /sup 18/O from solvent H/sub 2//sup 18/O into the pyrylium salt. Due to the low solubility of this salt in aqueous solutions, 2,4,6-trimethyl(2-/sup 13/C)pyrylium perchlorate and 2,4,6-trimethyl(2,6-/sup 13/C/sub 2/)pyrylium perchlorate were synthesized to facilitate the acquisition of the data on an NTC-200 spectrometer operating at 50.31 MHz. Upon incorporation of /sup 18/O into the pyrylium salt, the /sup 13/C NMR signal of the directly bonded carbon atom is shifted upfield 0.038 ppm. A /sup 13/C isotope effect is also detected in the doubly /sup 13/C-enriched pyrylium salt where the /sup 13/C NMR signal ...

Energy Technology Data Exchange (ETDEWEB)

A computational model has been developed to calculate the potential and current distributions in the electrolyte phase and on the electrode surface for a system in which a part of the anode is passivated while the rest remains in the active dissolution state. The computation employs the finite element method allied with a boundary variation and a trial and error technique. From the obtained distributions, the location of the boundary between the active and passive regions on the anode can be predicted. In the case of a crevice, this means that a critical distance into the crevice exists beyond which active corrosion (crevice corrosion) takes place. In addition to the active/passive behavior of the material, solution conductivity, applied potential at the sample's outer surface, crevice gap and depth dimensions, and passive current density influence this critical distance to different degrees. The developed software package may also be used for (i) ...

Energy Technology Data Exchange (ETDEWEB)

The comprehension of passivity and its protective character against corrosion is closely connected with the electronic properties of passive films. Passive films formed anodically on carbon steel in borate/boric acid solution, pH 9.2, have been characterised by electrochemical impedance spectroscopy (EIS). Mott-Schottky plots and impedance measurements were made on films formed at different potentials and times. The investigation allowed the determination of the semiconductive properties of the films. The results of the capacitance response indicate that the passive films behave like highly doped n-type semiconductors, showing that the passive film properties are dominated by iron. The value of donors density (N {sub D}) for the passive film is of the order of 10{sup 21} cm{sup -3} and decreases with increasing formation time and potential, indicating that defects decrease with increasing film thickness. Based on the information about the physical phenomena, an ...

British Library Electronic Table of Contents (United Kingdom)

After presenting a geochemical model for the interaction between calcite and varying environmental conditions, the paper discusses the experimental results of long duration electrokinetic tests, run on a natural clayey soil in unbuffered conditions. Local measurements of electrical potential, temperature and water flow were performed during the tests, while pH and fluid conductivity were measured locally once the tests had been dismantled. Sharp change of pH and reduction of the soil electrical conductivity, that in pure clays usually occur in the proximity of the cathode, were observed in the region close to the anode. As well, the soil in the anode area systematically tended to develop fractures, that mostly persisted until the end of the experiments. The features observed, that are not ...

Energy Technology Data Exchange (ETDEWEB)

The carbonate rocks of the Lower Ordovician Majiagou Formation represent important hydrocarbon reservoirs in the Ordos basin in the western part of the North China plate. Cores and thin sections from more than 60 wells were examined. The main reservoir in the Majiagou Formation consists of fine crystalline dolomite, which was altered by meteoric water during an extended subaerial exposure. Three phreatic zones have been identified in the Majiagou Formation in the northern part of the basin. Oxygen isotopes and fluid inclusion microthermometry data indicates that the porosity developed during the early karst event was considerably reduced by the late-stage, coarse crystalline calcite cements that appear to be related to hydrothermal fluids during deep burial. It was concluded that the main factors that determine the porosity and permeability of these carbonate reservoirs are dolomitization, karstification, and calcite cementation.

Science.gov (United States)

... a way to model a munition's terminal effects in a ... following attributes are handled in a stochastic fashion ... be improved by managing a queue of buffers ...

Energy Technology Data Exchange (ETDEWEB)

Iofetamine HCI {sup 123}I is the generic name for the hydrochloride salt of N-isopropyl-p-iodoamphetamine labeled with {sup 123}I, commonly called IMP. Iofetamine HCI {sup 123}I is prepared by isotopic exchange with [{sup 123}I]Nal and is formulated in isotonic aqueous NaCl solution containing 1 mCi/ml iofetamine HCI I 123, 0.15 mg/ml iofetamine HCI carrier, and phosphate buffer for pH control. The radiochemical purity is >97%, and the product is stable for more than 24 hours; the commercial product distributed today is prepared with high purity {sup 123}I with >98% radionuclidic purity. Two radioiodinated agents have seen significant clinical application for functional brain imaging: iofetamine HCI (IMP) (1) and N,N,N{prime}-trimethyl-N{prime}-(2-hydroxy-3-methyl-5-iodobenzyl)-1,3-propanediamine HIPDM (2). lofetamine HCI {sup 123}I is commercially available in the United States, Europe, and Japan. Although their primary use is for ...

Energy Technology Data Exchange (ETDEWEB)

A new spectrofluorimetric method was developed for the determination of trace amount of nicotinamide adenine dinucleotide phosphate (NADP). Using europium (Eu{sup 3+})-tetracycline (TC) complex as a fluorescent probe, in the buffer solution of pH 7.60. NADP can remarkably enhance the fluorescence intensity of the Eu{sup 3+}-TC complex at {lambda} = 612 nm and the enhanced fluorescence intensity of Eu{sup 3+} ion is in proportion to the concentration of NADP. Optimum conditions for the determination of NADP were also investigated. The dynamic range for the determination of NADP is 4.4 x 10{sup -7} to 2.2 x 10{sup -6} mol l{sup -1} with detection limit of 6.9 x 10{sup -8} mol l{sup -1}. This method is simple, practical and relatively free interference from coexisting substances and can be successfully applied to determination of NADP in synthetic water samples and in serum samples. Moreover, the enhancement mechanisms of the fluorescence ...

International Nuclear Information System (INIS)

As part of efforts to develop improved methods for NMR protein sample preparation and structure determination, the Northeast Structural Genomics Consortium (NESG) has implemented an NMR screening pipeline for protein target selection, construct optimization, and buffer optimization, incorporating efficient microscale NMR screening of proteins using a micro-cryoprobe. The process is feasible because the newest generation probe requires only small amounts of protein, typically 30-200 ?g in 8-35 ?l volume. Extensive automation has been made possible by the combination of database tools, mechanization of key process steps, and the use of a micro-cryoprobe that gives excellent data while requiring little optimization and manual setup. In this perspective, we describe the overall process used by the NESG for screening NMR samples as part of a sample optimization process, assessing optimal construct design and solution conditions, as well as for ...

Energy Technology Data Exchange (ETDEWEB)

Interest in finding out passive ways to keep the variation in the indoor climate within the comfort zone is gaining in popularity. One possible solution is the use of the moisture-buffering property of materials. In this study, the effects of the ventilation system and moisture-buffering properties of the building fabric on the stability of the indoor temperature and humidity are analysed by means of long-term field measurements. Indoor climate measurements were carried out in 170 detached houses (248 rooms). Temperature and relative humidity were measured continuously in bedrooms and living rooms at one-hour intervals over a one-year period. In general, it may be concluded that in this study, the ventilation had a greater effect on the indoor climate than the properties of the building fabric. The dampening effect of hygroscopic materials was remarkably less in the field measurements than it was in simulations in different ...

Science.gov (United States)

... 5.12 Terminal Value for Performance Measure P ... As examples, a stochastic communication network containing a buffer queue at each ...

Energy Technology Data Exchange (ETDEWEB)

In this paper, the moisture buffering capacity of spruce plywood is measured by recording the change in mass of a test specimen when the air relative humidity (RH) is changed between 33% RH and 75% RH. The aim is to represent diurnal cycles in indoor humidity with 33% RH maintained for 16 h and 75% RH maintained for 8 h. Measurements are taken using two different apparatuses, which provide different convective transfer coefficients between the air and the plywood, and the results are compared to a numerical model for validation. The validated numerical model is then used to investigate the effect of initial conditions, boundary conditions and thickness on the moisture buffering capacity of plywood. The results show that the buffering capacity of plywood depends on the initial conditions and thickness of the plywood as well as the surface film coefficient and humidity cycle. (author)

International Nuclear Information System (INIS)

A method was proposed and examined to deposit thick cubic boron nitride (cBN)-rich layer of good adhesion to silicon substrate. The method combined (i) the insertion of a thick sp"2 buffer layer, and (ii) the use of an appropriate assist ion beam energy for the growth of the cBN-rich top layer. The sp"2-bonded boron nitride buffer layer was deposited under irradiation of ions with energies in the range of 200-360 eV. The buffer layer was found to contain curled graphitic basal planes, and so was supposed to be relatively deformable, and facilitate the relaxation of stresses in the cBN-rich top layer. The ion assist introduced during the growth of the cBN-rich layer was supposed to both create and annihilate defects, and so resulted in the generation and relaxation of internal stresses. Results showed that the insertion of a 492 nm sp"2 buffer layer, and the use of a beam energy of 450 eV for assisting ...

International Nuclear Information System (INIS)

This paper presents a group's efforts to introduce national newborn screening in Lebanon. Tandem mass spectrometry (MS) technology offers the prospect of utilizing filter paper blood specimens to screen newborns for several metabolic disorders. In order to be cost-effective, it is necessary to have a mandatory newborn screening policy. At present such a policy is not available in Lebanon. A national screening survey for congenital hypothyroidism (CH) was carried out to assess the incidence of this anomaly in the Lebanese population. Such an initiative is essential as a first step for assessing the feasibility and cost of a national screening programme. Coated beads, blood spot standards for quality control and buffer solutions used for assays were prepared in-house to minimize costs. At first, samples of umbilical cord blood spots were assayed for TSH using IRMA technique. Those samples showing borderline or high values of TSH were then assayed ...

Energy Technology Data Exchange (ETDEWEB)

The electrochemical behavior of the anti-thalassemia and anti-HIV replication drug, deferiprone, was investigated on a carbon nanotube-modified glassy carbon (GC-CNT) electrode in phosphate buffer solution, pH 7.40 (PBS). During oxidation of deferiprone, two irreversible anodic peaks, with E{sub 1}{sup 0}=452 and E{sub 2}{sup 0}=906mV, appeared, using GC-CNT. Cyclic voltammetric study indicated that the oxidation process is irreversible and diffusion controlled. The number of exchanged electrons in the electro-oxidation process was obtained, and the data indicated that deferiprone is oxidized via two two-electron steps. The results revealed that carbon nanotube (CNT) promotes the rate of oxidation by increasing the peak current, so that deferiprone is oxidized at lower potentials, which thermodynamically is more favorable. This result was confirmed by impedance measurements. The diffusion coefficient, electron-transfer coefficient and ...

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Hepatocellular carcinoma (HCC) is the most common primary liver cancer and has very limited therapeutic options. Recently, it has been found that hyaluronic acid (HA) shows selective binding to CD44 receptors expressed in most cancer histotypes. Since the trend in cancer treatment is the use of targeted radionuclide therapy, the aim of this research was to label HA with rhenium-188 and to evaluate its potential use as a hepatocarcinoma therapeutic radiopharmaceutical. Methods: {sup 188}Re-HA was prepared by a direct labelling method to produce a ReO(O-COO){sub 2}-type coordination complex. {sup 188}Re-HA protein binding and its stability in saline, phosphate buffer, human serum and cysteine solutions were determined. Biokinetic and dosimetric data were estimated in healthy mice (n=60) using the Medical Internal Radiation Dose methodology and mouse model beta-absorbed fractions. To evaluate liver toxicity, alanine aminotranferase (AST) and ...

British Library Electronic Table of Contents (United Kingdom)

Summary 1. The EU -Nitrates Directive- (Directive 91/676/EEC) and the WFD (Water Framework Directive 2000/60/EEC) introduced a series of measures designed to reduce and prevent water pollution caused or induced by nitrates from agricultural sources. Therefore, there is an urgent requirement to control the nitrate concentration in freshwater. The objective of this paper was to verify the potential capacity of a specifically designed afforested riparian zone in removing the excess of nitrogen from river water. 2. A buffer zone was set with irrigation ditches, to produce a subsurface water flow carrying water from the study river through the buffer strip to drainage ditches. This experimental system enables the co-occurrence of two main processes: vegetation/microbial nitrogen uptake and deni...

Energy Technology Data Exchange (ETDEWEB)

Mineral matter in coals is important in various senses for coal liquefaction. It is possible that the catalytic activity is affected by the interaction between catalyst and mineral matter. Iron-based catalyst forms pyrrhotite in the process of liquefaction, but the interaction between it and mineral matter is not known in detail. In this study, the interaction between mineral matter and catalyst and the selective reaction between them were investigated. Tanito Harum coal was used for this study. This coal contains a slight amount of siderite and jarosite besides pyrite as iron compounds. Liquefaction samples were obtained from the 1 t/d NEDOL process PSU. The solid deposits in the reactor mainly contained pyrrhotite and quartz. A slight amount of kaolinite was observed, and pyrite was little remained. It was found that the catalyst (pyrrhotite) often coexisted with quartz, clay and calcite. 8 figs., 2 tabs.

UK PubMed Central (United Kingdom)

Testes of jellyfish Phialidium gregarium were fixed in 2 per cent OsO₄ in Veronal-acetate buffer at pH 7.4. Thin sections showed that in young spermatids the spindle fibers...Full Text Available

UK PubMed Central (United Kingdom)

Cd-binding protein was extracted from tomato roots and purified on QAE-Sephadex A-25 and on Sephadex G-75 in 1 molar KCl buffer. The protein preparation was light brown and contained predominantly Cd...Full Text Available

UK PubMed Central (United Kingdom)

Understanding the mechanisms by which climate and predation patterns by top predators co-vary to affect community structure accrues added importance as humans exert growing influence over both climate...Full Text Available

UK PubMed Central (United Kingdom)

1. Digital imaging and photometry were used in conjunction with the fluorescent Ca2+ indicator, Fura-2, to examine intracellular Ca2+ signals produced by depolarization of single adrenal chromaffin...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

A shear acoustic transducer-lens system in which a shear polarized piezoelectric material excites shear polarized waves at one end of a buffer rod having a lens at the other end which excites longitudinal waves in a coupling medium by mode conversion at selected locations on the lens.

Energy Technology Data Exchange (ETDEWEB)

Significant ion irradiation during film growth is required for the formation of cubic boron nitride (cBN) films. Meanwhile, a huge level of intrinsic stress possibly induced by the ion bombardment has been frequently reported to result in cracking and/or lack of adhesion of deposited cBN films. The present work has been performed to investigate the interfacial and/or the buffer layer structures with better matching to the cBN film by relaxation of the film stress using ion-beam-assisted deposition (IBAD). Boron nitride films have been synthesized on Si(100) wafer and tungsten carbide (WC) substrates by depositing boron vapor under simultaneous bombardment with nitrogen ions and nitrogen-argon mixture ions in the energy range of 0.5-10 keV. Cubic BN films with enhanced tribological properties have been explored by inserting a BN layer with various B/N compositions as a controlled buffer at the interface. Significant relaxation of the film stress ...

Energy Technology Data Exchange (ETDEWEB)

The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, is conducting a study to determine the natural geochemistry of the Snake River Plain aquifer system at the Idaho National Engineering Laboratory (INEL), Idaho. As part of this study, a group of geochemical reactions that partially control the natural chemistry of ground water at the INEL were identified. Mineralogy of the aquifer matrix was determined using X-ray diffraction and thin-section analysis and theoretical stabilities of the minerals were used to identify potential solid-phase reactants and products of the reactions. The reactants and products that have an important contribution to the natural geochemistry include labradorite, olivine, pyroxene, smectite, calcite, ferric oxyhydroxide, and several silica phases. To further identify the reactions, analyses of 22 representative water samples from sites tapping the Snake River Plain aquifer system were used to determine the ...

Energy Technology Data Exchange (ETDEWEB)

A geological study was conducted to better understand the nature of cleat development and degree of mineralization in coal seams of the Scollard and Coalspur Formations in western Alberta. The results can be applied to equivalent formations. The source and reservoir rocks of a coalbed methane (CBM) system were described. Coal seams are basically fractured reservoirs with 7 types of cleats. The field work involved cleat minerals sampling and determining cleat attributes such as type, strike and spacing from open-cut mines and outcrops. The laboratory work involved X-Ray diffraction, scanning electron microscopy, energy dispersive microscopy, stable isotope analysis, and fluid inclusions analysis. The study showed that coal seams of the Scollard and Coalspur Formations are widespread and cleated to various degrees. The face and butt cleats strike northeast-southwest and northwest southeast respectively along the structural grain of the Laramide Orogeny. The major cleat mineral is ...

Energy Technology Data Exchange (ETDEWEB)

The aim of this study was to investigate whether sub-ablative pulsed C0{sub 2} laser (1 0,6 {mu}m) irradiation is capable of reducing the susceptibility of the dental enamel to demineralization, and thus achieving a potential caries-protective effect. The crowns of 51 bovine front teeth, embedded in acrylic resin and polished until exposure of flat enamel surface, were used. The samples were cut in cubes of 10x10 mm, and totally coated with acid-resistant nail varnish, except for an enamel exposed window of 16 mm square. Three groups (n=17) were obtained: control group (CG) not irradiated; group laser A (LA) and group laser B (LB) where the samples were irradiated. The conditions were 60 mJ, 100 Hz, 0,3 J/cm{sup 2} for LA and 135 mJ, 10 Hz, 0,7 J/cm{sup 2} for LB. Two samples of each group were submitted to SEM analysis and fifteen to demineralization in 3 ml acetate buffer solution (0,1 mol/L) with pH 4,5 for 24h at 37 deg C, with regular ...

Energy Technology Data Exchange (ETDEWEB)

Successful interface engineering requires compositional and electronic material characterization as a prerequisite for understanding and intentionally generating interfaces in photovoltaic devices. The paper gives an overview with several examples, all referring to Cu(In,Ga)(S,Se){sub 2} ('CIGSSe')-based solar cells, with an emphasis on characterization using highly specialized methods, such as elastic recoil detection analysis, X-ray emission spectroscopy and photoelectron spectroscopy using synchrotron and ultraviolet light for excitation, inverse photoemission spectroscopy and Kelvin probe force microscopy. First, the determination of the depth profile of the band gap energy E{sub g} in the absorber layer is demonstrated. The modification of E{sub g} towards both interfaces is discussed in terms of beneficial electronic effects. Next, the interface between absorber and buffer layers with alternative and promising non-toxic materials is ...

Energy Technology Data Exchange (ETDEWEB)

Polycyclic aromatic hydrocarbons (PAH`s) are ubiquitous hydrophobic organic pollutants in the marine environment. Many of the PAM`s are classified as possible carcinogens or mutagens, therefore they are of considerable concern to human and environmental health. The highest concentrations are found in coastal regions due to anthropogenic activities including oil spills, tanker operations, incomplete fossil fuel combustion and runoff. The sources and distribution of PAM`s in sediments are fairly well known, while the fate and transport of PAH`s in the marine environment are less known. Desorption is an important factor influencing the fate and transport of hydrophobic molecules at the seawater/sediment interface. The desorption of PAH`s from contaminated marine sediments to the water column/pore water affects the availability of the pollutant to biota. The sorption of PAH`s is determined in part by the organic carbon content of the sediments. The presence of dissolved organic carbon ...

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Monitoring brine chemistry to determine the extent of potential adverse reactions has been simplified by the development of a field-brine test kit and a series of nomographs. Results of the kit analyses serve as input to the nomographs, which provide a graphic means of determining the scaling tendency (Saturation Index value) of a brine. Brines that do not tend to form scale may be corrosive. Saturation Index values were correlated with various processes using data from geopressured wells in the Gulf Coast area. Control of scale in surface equipment with chemical inhibitors has been successful. Numerous laboratory simulations of inhibitor squeeze operations were completed using core material with calcite present and absent. The corresponding wells were squeezed with phosphorous-containing inhibitors, and the flowback of brine was monitored for phosphorous concentrations vs time. A new procedure to measure the concentration of phosphorous-containing inhibitors down ...

Energy Technology Data Exchange (ETDEWEB)

The mechanical stability of diamond-like carbon (DLC) films coated on nitinol vascular stents was investigated under cyclic loading condition by employing a stent crimping system. DLC films were coated on the vascular stent of a three dimensional structure by using a hybrid ion beam system with rotating jig. The cracking or delamination of the DLC coating occurred dominantly near the hinge connecting the V-shaped segments of the stent where the maximum strain was induced by a cyclic loading of contraction and extension. However the failures were significantly suppressed as the amorphous Si (a-Si) buffer layer thickness increased. Interfacial adhesion strength was estimated from the spalled crack size in the DLC coating for various values of the a-Si buffer layer thickness.

UK PubMed Central (United Kingdom)

The values of the second dissociation constant pK₂ and related thermodynamic quantities of the ampholyte 3-(N-morpholino)-2-hydroxypropanesulfonic acid (MOPSO) have...Full Text Available

Science.gov (United States)

... been possible to prove the existence and uniqueness of a classical solution which tends to the well-known solution of the Stefan problem as the ...

British Library Electronic Table of Contents (United Kingdom)

Abstract The present work, regarding the determination of ultratrace Os(VIII), Ru(III) and Ir(III) in superficial waters is an interesting example of the possibility to simultaneously, or better sequentially determine each single element in real samples by voltammetry. The method is based on the catalytic current of the Os(VIII)- and Ru(III)-bromate systems by square wave voltammetry and on the Ir(III) determination by square wave catalytic adsorptive stripping voltammetry. 0.5-mol-L-1 acetate buffer pH-4.9+7.710-2-mol-L-1 NaBrO3 and 0.5-mol-L-1 acetate buffer pH-4.9+7.710-2-mol-L-1 NaBrO3+2.310-5-mol-L-1 cetyltrimethylammonium bromide (CTAB) +0.2-mol-L-1 KCl were employed as the supporting electrolytes. The analytical procedure was verified by the analysis of the standard reference materi...

International Nuclear Information System (INIS)

The lateral bearing device is made of 7 lateral supports, each positioned to allow the displacement of the steam generator due to thermal or seismic effects. Each support includes a buffer plate that can be positioned on the steam generator using a position control assembly. This control assembly consists of a screw jack arrangement where the nut is fastened via an energy absorbing layer to a footplate that is fixed to the concrete wall of the steam generator enclosure. 4 figs.

Energy Technology Data Exchange (ETDEWEB)

The Data Acquisition System for the CDMS II dark matter experiment was designed and built when the experiment moved to its new underground installation at the Soudan Lab. The combination of remote operation and increased data load necessitated a completely new design. Elements of the original LabView system remained as stand-alone diagnostic programs, but the main data processing moved to a VME-based system with custom electronics for signal conditioning, trigger formation and buffering. The data rate was increased 100-fold and the automated cryogenic system was linked to the data acquisition. A modular server framework with associated user interfaces was implemented in Java to allow control and monitoring of the entire experiment remotely.

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A procedure for high level tritium labelling at the C2-H position of adenosine 5`-triphosphate ([2-{sup 3}H]-ATP, 1), based on the tritiodehalogenation reaction of 2-bromoadenosine 5`-triphosphate (2) has been elaborated. This precursor was prepared in a six-step synthesis from guanosine. The tritiodehalogenation of (2) for three hours over palladium oxide in phosphate buffer yielded tritium labelled ATP with high specific activity, in good chemical yield. (author).

CERN Document Server

In this paper, we present FASE (Faster Asynchronous Systems Evaluation), a tool for evaluating the worst-case efficiency of asynchronous systems. The tool is based on some well-established results in the setting of a timed process algebra (PAFAS: a Process Algebra for Faster Asynchronous Systems). To show the applicability of FASE to concrete meaningful examples, we consider three implementations of a bounded buffer and use FASE to automatically evaluate their worst-case efficiency. We finally contrast our results with previous ones where the efficiency of the same implementations has already been considered.

Energy Technology Data Exchange (ETDEWEB)

This executive summary presents the motivation, structure, objectives, methodologies and results of the first stage of the international DECOVALEX project - DECOVALEX I (1992-1995). The acronym stands for Development of Coupled Models and their Validation against Experiment in Nuclear Waste Isolation, and the project is an international effort to develop mathematical models, numerical methods and computer codes for coupled thermo-hydro-mechanical processes in fractured rocks and buffer materials for geological isolation of spent nuclear fuel and other radioactive wastes, and validate them against laboratory and field experiments. 24 refs.

Science.gov (United States)

A colony PCR technique was applied for both genomic and chloroplast DNA in the green microalgae Chlorella. Of five different lysis buffers, Chelex-100 was superior for DNA extraction, PCR and DNA storage. It also was insensitive to variations in cell density. The conditions established for an improved PCR formulation are applicable for screening of genetically-engineered transformants as well as bioprospecting of natural microalgal isolates. Besides multiple Chlorella species, we also demonstrate the efficacy of Chelex-100 for colony PCR with a number of other microalgal strains, including Chlamydomonas reinhardtii, Dunaliella salina, Nannochloropsis sp., Coccomyxa sp., and Thalassiosira pseudonana. PMID:21431847

Energy Technology Data Exchange (ETDEWEB)

We have investigated the generation and propagation of misfit dislocations in strained In/sub y/Ga/sub 1-//sub y/As/GaAs multiquantum wells grown by molecular-beam epitaxy, with cross-sectional transmission electron microscopy. The samples are of excellent optical quality, with multiquantum wells having well widths of 100 A, being characterized by excitonic linewidths and Stokes shifts of 1.5--2.5 and 1--2 meV, respectively. We have examined the growth of 2-..mu..m-thick multiquantum-well samples grown either directly on GaAs, or with an intermediate composition buffer layer, and for the cases of small (y = 0.07) and large (y = 0.16) misfits. It is seen that for the case of quantum wells with small misfit, grown directly on GaAs, metastable growth can be achieved. This is confirmed by low-temperature absorption measurements and from transmission electron microscopy experiments performed both before and after post-growth thermal annealing. In the case of quantum ...

International Nuclear Information System (INIS)

Tumor imaging using radioiodinated monoclonal antibodies (Mab) suffered from rapid in vivo deiodination. This problem can be circumvented by covalent attachment of a bifunctional chelating group to the Mab followed by chelation with a suitable cationic radionuclide such as In-111. Competition of trace metal contaminants with In-111 for chelating sites, however, is known to lower the labeling yield. Since commercially available reagents may be contaminated with other trace metal ions, the effect of trace metals on Mab-DTPA chelation and the possibility of masking the trace metal effect on the In-111 labeling of Mab-DTPA were, therefore, investigated. Labeling yield of 93% was obtained when 1 mg (20mg/ml) of Mab F(ab')/sub 2/-DTPA (protein to DTPA ratio of --1) was allowed to incubate with 3 mCi In-111 in 2 ml acetate buffer (0.5M, pH 5.5) for 30 min. The yield was drastically decreased to 13-76% when the reactions were carried out with the addition of 1-2 #mu#g of ...

Energy Technology Data Exchange (ETDEWEB)

Field and laboratory work sponsored by the Gas Research Institute (GRI) and the Department of Energy (DOE) have shown that calcium-carbonate scale formation in waters produced with natural gas and oil can be prevented by injection of phosphonate inhibitor into the formation, even if the formation is sandstone without calcite binding material. Inhibitor squeeze jobs have been carried out on DOE's geopressured-geothermal Gladys MaCall brine-gas well and GRI's co-production wells in the Hitchcock field. Following the inhibitor squeeze on Gladys McCall, the well produced over five million barrels of water at a rate of approximately 30,000 BPD without calcium-carbonate scaling. Before the inhibitor squeeze, the well could not be produced above 15,000 BPD without significant scale formation. In the GRI brine-gas co-production field tests, inhibitor squeezes have been used to successfully prevent scaling. Laboratory work has been conducted to determine ...

International Nuclear Information System (INIS)

Manganese is a common contaminant of mine water and other waste waters. Due to its high solubility over a wide pH range, it is notoriously difficult to remove from contaminated waters. Previous systems that effectively remove Mn from mine waters have involved oxidising the soluble Mn(II) species at an elevated pH using substrates such as limestone and dolomites. However it is currently unclear what effect the substrate type has upon abiotic Mn removal compared to biotic removal by in situ micro-organisms (biofilms). In order to investigate the relationship between substrate type, Mn precipitation and the biofilm community, net-alkaline Mn-contaminated mine water was treated in reactors containing one of the pure materials: dolomite, limestone, magnesite and quartzite. Mine water chemistry and Mn removal rates were monitored over a 3-month period in continuous-flow reactors. For all substrates except quartzite, Mn was removed from the mine water during this period, and Mn minerals ...

Energy Technology Data Exchange (ETDEWEB)

Interbedded limestones and dolomites of the Cambrian Conococheague Formation cropping out northwest of Lancaster exhibit contrasting rheological behavior during deformation. Dolomite beds are uncleaved and form concentric F[sub 1] recumbent folds with hinges trending northeast, parallel to the trend of the Appalachian orogen. Limestone beds show subhorizontal S[sub 1] cleavage with southeast-plunging extension lineations defined by fibrous calcite and ubiquitous smear lineations. In limestone beds, intrafolial F[sub 1] folds with curvilinear hinges are sheath folds flattened in the S[sub 1] cleavage. In zones of most intense shear, F[sub 1] hinges parallel the regional northwest directed tectonic transport direction. In 1969, the author attributed the variation in intrafolial F[sub 1] fold-hinge orientation to hinge-parallel buckling due to constrictional bulk strain. This interpretation, however, is not consistent with the absence of comparable hinge-line ...

International Nuclear Information System (INIS)

Information is presented concerning solute concentration in a porous layer; solute concentration in a packed crevice; corrosion of a packed carbon steel crevice in NaCl-O"2 solutions; and effect of copper on corrosion in NaCl-O"2 solutions.

Science.gov (United States)

No abstract prepared.

Science.gov (United States)

Turbidimetric method for determining sulfite in inhibited ethylene glycol-water solutions

British Library Electronic Table of Contents (United Kingdom)

The ultrafast dynamics of the DNA fluorescent dye Sybr Green I (SG) has been studied in buffer, single-stranded (ssDNA), double-stranded (dsDNA) and triple-stranded DNA (tsDNA). The fluorescence quantum yield of SG increases dramatically when bound to DNA (including tsDNA). The fluorescence dynamics of the free SG has shown two decay components with 0.15-0.4ps and 1.3-2.1ps time constants, depending on the fluorescence wavelength. Upon binding to DNA, the dynamics becomes slower exhibiting four decay components. This is mainly due to the restriction of the internal motions of the dye caused by the relatively rigid environment of the dye complexed with DNA.

British Library Electronic Table of Contents (United Kingdom)

Terror management theory (TMT) proposes that people who are reminded of their mortality should be motivated to defend their cultural worldview. Studies 1 and 2 examined whether the TMT worldview defence-buffering effect found in Western cultures could be generalized to Asians in Taiwan. No such effect was found in the present studies. This non-significant result was robust when either a stronger distraction task was used (study 1) or when a subliminal manipulation of mortality salience was utilized (study 2). A meta-analysis, including 24 TMT experiments in East Asia, was also conducted (study 3). The average effect size (d = 0.11, r = 0.055) of worldview defence among these experiments was not significantly different from zero. Study 4 found that mortality salience manipulation also did n...

Energy Technology Data Exchange (ETDEWEB)

Creation of new multi-composite materials is an essential issue to attain an innovative improvement of the current nuclear technology. In this paper, some highlights are focused on the research of creation of those materials and the relating subjects in NIRIM. (1) The KOH corrosion test method are expected to be efficiently available in the limited cases instead of Na corrosion test one. (2) The preliminary creation of the multi-composite ceramics were achieved by Y- ion implantation into sapphire and the RF sputtering, of which the specified orientation was realized by the existence of the buffer layer. The importance of the defect control are described with the relation to the corrosion resistance improvement. (3) The ion beam induced phenomena have been investigated on the surface change of silica glass and the crystallization of Cu film on SrTiO{sub 3}. (4) The electronic states of the alkali-metal adsorbed surfaces and that of the collision ion have been ...

British Library Electronic Table of Contents (United Kingdom)

SnO2/graphene nanocomposites have been fabricated by a simple chemical method. In the fabrication process, the control of surface charge causes echinoid-like SnO2 nanoparticles to be formed and uniformly decorated on the graphene. The electrostatic attraction between a graphene nanosheet (GNS) and the echinoid-like SnO2 particles under controlled pH creates a unique nanostructure in which extremely small SnO2 particles are uniformly dispersed on the GNS. The SnO2/graphene nanocomposite has been shown to perform as a high capacity anode with good cycling behavior in lithium rechargeable batteries. The anode retained a reversible capacity of 634 mA?h?g?1 with a coulombic efficiency of 98% after 50 cycles. The high reversibility can be attributed to the mechanical buffering by the GNS against...

British Library Electronic Table of Contents (United Kingdom)

Purpose The mangroves of New Caledonia, in the south Pacific, act as a buffer between a lagoon of more than 20,000?km2 and the island, which is characterized by ultramafic rocks and lateritic soils that are exploited for their richness in heavy metals. We will provide a better understanding of the redox conditions, and of heavy metal distributions in mangroves receiving shrimp farm effluents. Materials and methods Samples were collected from four areas defined in terms of vegetation composition: a salt flat, an Avicennia marina forest, in which effluents are released; a Rhizophora stylosa forest, and a dead Rhizophora forest. They were collected during times of maximum effluent release. Some measurements on pore water were also done during a period without effluent. Cores (70?cm deep) were...

British Library Electronic Table of Contents (United Kingdom)

The present study was carried out to exploit the feasibility of using polymeric nanosponges as an alternative carrier for targeting econazole nitrate (EN) to the skin through topical hydrogel formulation. Nanosponges prepared by emulsion solvent diffusion method were evaluated for various physicochemical parameters and in vitro drug release. The nanosponges of EN were discrete free flowing nanosized particles with perforated orange peel like morphology as visualized by SEM. The nanosponge formulated using PVA:EC (3:2) displayed highest in vitro release after 12 ?h in phosphate buffer (pH 6.8) that fitted matrix model. Selected nanosponge was formulated as Carbopol 934 NF hydrogel using varying concentrations of permeation enhancers propylene glycol and N-methyl-2-pyrrolidone. The EN nanosp...

British Library Electronic Table of Contents (United Kingdom)

Women who have academic careers in engineering have successfully navigated the social identity threats that prevent many other women from feeling that they belong in science, technology, engineering, and math fields. In this research, we examined what factors may be related to resilience in these academic environments. Female academics in engineering and nonengineering fields watched a fictitious conference video depicting either an unbalanced ratio of men to women or a balanced ratio. Subjective measures of identity threat were collected. Past experience with discrimination, positive experience with female role models, family support, and general social support were associated with a greater sense of belonging to or desire to participate in the conference. These variables all buffered neg...

International Nuclear Information System (INIS)

Continuing high rates of acidic deposition in the eastern United States may lead to long-term effects on stream communities, because sensitive catchments are continuing to lose anions and cations. A two-year study of the effects of pH and associated water chemistry variables on detrital processing in three streams with different bedrock geology in the Monongahela National Forest, West Virginia were investigated. Leaf pack processing rates and macroinvertebrate colonization and microbial biomass (ATP concentration) on the packs in the three stream were compared. It was found that macroinvertebrate and microbial communities differed both among streams that differed in their capacity to buffer the effects of acidic precipitation and among years in the same stream; these differences in biotic communities were not large enough to affect rates of leaf processing between the two years of the study, but they did significantly affect processing rates between acidic and ...

Energy Technology Data Exchange (ETDEWEB)

FeSi{sub 6}/graphite composite was prepared by mechanical ball milling. The FeSi{sub 6} alloy particles consist of an electrochemically active silicon phase and inactive phases FeSi{sub 2}, distributed uniformly in the graphite matrix. The composite anode offers a large reversible capacity (about 800 mAh g{sup -1}) and good cycleability, due to the buffering effect of the inactive FeSi{sub 2} phase and graphite layers on the volumetric changes of Si phase during lithium-Si alloying reaction. Since FeSi{sub 6} alloy is a low-cost industrial material, this alloy compound provides a possible alternative for development of high capacity lithium-ion batteries. (author)

Energy Technology Data Exchange (ETDEWEB)

Methods were developed for the separation of radioactively labeled carbohydrate components of proteoglycans by isocratic ion-moderated partition HPLC. Neutral sugars were separated after hydrolysis in trifluoroacetic acid with baseline separation between glucose, xylose, galactose, fucose, and mannose. N-Acetylneuraminic acid, N-acetylated hexosamines, glucose, galactose, and xylitol were likewise well separated from each other under isocratic elution conditions. Glucuronic acid, iduronic acid, and their lactones were separated after hydrolysis in formic acid and sulfuric acid. Glucosamine, galactosamine, galactosaminitol, and glucosaminitol were separated by HPLC on a cation exchanger with neutral buffer after hydrolysis in hydrochloric acid. THe separation techniques also proved useful in fractionation of exoglycosidase digests of O- and N-linked oligosaccharides. Separations of aldoses, hexosamines, and uronic acids were adapted to sensitive photometric ...

Energy Technology Data Exchange (ETDEWEB)

A process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having a platinum based amorphous metal alloy anode.

International Nuclear Information System (INIS)

... adsorption aqueous solutions astatine complexes astatine ions enthalpy organic

Science.gov (United States)

The effects of a maltodextrin (dextrose equivalent 12)-electrolyte solution and a maltodextrin-electrolyte solution with added nutrients on net water and electrolyte transport in the secreting rat intestine was compared with the citrate-World Health Organization oral rehydration solution to determine the need for a clinical trial to evaluate the efficacy of these maltodextrin solutions in acute diarrhoea treatment. Cholera toxin consistently produced net water secretion (-36.5 +/- 9.9 mean +/- SEM microliter/min/g dry weight of intestine). All three solutions reversed the cholera toxin-induced net intestinal water secretion to net absorption. Significantly greater net water absorption occurred from the maltodextrin-electrolyte solution compared to the World Health Organization solution (P < 0.05) but not when compared to the ...

Energy Technology Data Exchange (ETDEWEB)

In order to fabricate high temperature superconducting tapes for power applications, the authors have analyzed different buffer layer architectures grown on textured Ni substrates suitable for YBCO deposition. Due to its optimal lattice matching the studied structures present as top layer a CeO{sub 2} film. The deposition of CeO{sub 2} on Ni substrates was performed by pulsed laser ablation and by e-beam evaporation at different temperatures. The films obtained by the two deposition techniques have not optimal structural properties, having a polycrystalline component. The misorientation of CeO{sub 2} is probably due to the formation of NiO at the interface between the film and the substrate during the deposition process even if no oxygen is introduced. In order to prevent Ni oxidation an intermediate 2000 {angstrom} Pd thick film was deposited by e-beam. Furthermore, the lattice mismatch between Pd and CeO{sub 2} is smaller than that between Ni and CeO{sub 2}. The ...

International Nuclear Information System (INIS)

The hypothesis that intracellular Ca"2"+ is an essential component of the intracellular mechanism of insulin action in the adipocyte was evaluated. Cells were loaded with the Ca"2"+ chelator quin-2, by preincubating them with quin-2 AM, the tetrakis(acetoxymethyl) ester of quin-2. Quin-2 loading inhibited insulin-stimulated glucose transport without affecting basal activity. The ability of insulin to stimulate glucose uptake in quin-2-loaded cells could be partially restored by preincubating cells with buffer supplemented with 1.2 mM CaCl_2 and the Ca"2"+ ionophore A23187. These conditions had no effect on basal activity and omission of CaCl_2 from the buffer prevented the restoration of insulin-stimulated glucose uptake by A23187. Quin-2 loading also inhibited insulin-stimulated glucose oxidation and the ability of insulin to inhibit cAMP-stimulated lipolysis without affecting their basal activities. Incubation of cells with 100 #mu#M quin-2 ...

International Nuclear Information System (INIS)

... v. 1267(1) RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR

British Library Electronic Table of Contents (United Kingdom)

My proposed econometric solution to the forward-bias puzzle provoked several comments. Those comments raise three primary objections to my solution. (1) It suffers from multicollinearity, miss-specification and other serious econometric problems. (2) My key test equation is a tautology or identity. (3) My econometric solution has nothing to do with either the forward-bias puzzle or uncovered interest parity. This is my reply to those objections.

International Nuclear Information System (INIS)

The rod drop time event of the Daya Bay Nuclear Power Plant is caused by the malfunction of the guide tube developed by Framatome. Three temporary solutions were implemented successively and the long term solution was found in the process of searching for the root cause. The different solutions and the root cause are introduced. The safety analysis and license of the solutions are mainly discussed. Experiences and lessons are drawn by summarizing the important items related to nuclear safety.

International Nuclear Information System (INIS)

Analytical expression of the dependence of freezing temperature of electrolyte (CdCl_2, CdSO_4, BeSO_4) aqueous solutions on their composition was found. Three different methods were suggested were suggested for calculation of water activity in multicomponent solution. It was established that sublinear extrapolation of freezing temperature of salt aqueous solutions was possible not up to -5 deg C, but up to -15 deg C, independently of their composition. 6 refs.; 2 figs.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

KoreaScience (Korea)

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KoreaScience (Korea)

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KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This paper investigates the spectral characteristics of three-dimensionally porous carbon dioxide indicators based on a porous silicate glass and phenolphthalein. The absorption spectra of the original solutions of phenolphthalein in alkaline and acid solutions are shown. The solutions were acidified by bubbling CO/sub 2/ through an alkaline phenolphthalein solution. The authors have succeeded in producing a reversible colorimetric adsorption indicator for carbon dioxide which after proper calibration enables the CO/sub 2/ content of an atmosphere to be estimated quantitatively.

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

We investigate the construction of five-dimensional supergravity solutions that do not have any triholomorphic U(1) isometries. We construct a class of solutions that in various limits of parameters reduces to many of previously constructed five-dimensional supergravity solutions based on both hyper-Kaehler base spaces that can be put into a Gibbons-Hawking form and hyper-Kaehler base spaces that cannot be put into a Gibbons-Hawking form. We find a new solution which is over triaxial Bianchi type IX Einstein-hyper-Kaehler base space with no triholomorphic U(1) symmetry. One special case of this solution corresponds to a five-dimensional solution based on Eguchi-Hanson type II geometry.

International Nuclear Information System (INIS)

The anodic behaviour and passivity breakdown of Alloy 800 in aqueous solutions of sodium chloride, sodium sulphate and sodium bicarbonate were studied by electrochemical techniques in the temperature range from 60 C to 280 C. The pitting resistance and pitting morphology of the alloy in chloride plus sulphate and chloride plus bicarbonate mixtures, at 60 C and 280 C, were also examined. Increasing bicarbonate or sulphate additions to chloride solutions shift the characteristic pitting potential of Alloy 800 to higher values, both at low and high temperatures. Changes in pitting morphology were observed in sulphate containing solutions while the morphology of the attack found in bicarbonate containing solutions was similar to that in pure chloride solutions. Finally, no localized or substantial generalized corrosion was detected in pure sulphate or bicarbonate ...

Energy Technology Data Exchange (ETDEWEB)

The crystallization of calcium sulfate from aqueous solutions with NaCl is both geological and industrial interest because NaCl is the dominant solute in natural brines and many industrial fluids. Induction periods for the nucleation of calcium sulfate dihydrate were experimentally determined as a function of supersaturation in NaCl solutions from 0 to 6 m at 25 C and in 3.0-m NaCl solutions at temperatures from 25 to 90 C. Using classic nucleation theory, the interfacial tension between gypsum and 3.0-m NaCl solution was estimated to be about 39 mJ/m[sup 2] at 25 C and increases with increasing temperature (to 63 mJ/m[sup 2] at 90 C). It was observed that the induction period decreases with increasing NaCl concentrations up to 3 m and then starts to increase slightly at a given temperature and saturation state. The electrolyte effect on nucleation was proportional to the enhanced ...

Science.gov (United States)

The Stefan problem involving a source term is considered in this technical note. As an example, planar solidification with time-dependent heat generation in a semi-infinite plane is solved by use of a perturbation technique. The perturbation solution is validated by reducing the problem to the case without heat generation whose exact solution is available. An application to the case with constant heat generation is presented, for which a closed-form solution is obtained. The effects of heat generation and Stefan number on the evolution of solidification are examined using the perturbation solution.

International Nuclear Information System (INIS)

A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO_2) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO_2 were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.

Energy Technology Data Exchange (ETDEWEB)

The rate of corrosion of hardened cement paste in solutions of nitric, hydrochloric, sulfuric, acetic and formic acids was compared. Corrosion in solutions of acetic and nitric acids with different concentrations was studied in more detail. The results made it possible to obtain the relationships expressing the influence of concentration and the time of action of acid solutions on the depth of corrosion. The rates of corrosion in nitric acid solutions during the first 3 years were about 2 to 4 times that in acetic acid solutions, depending on the concentration.

Energy Technology Data Exchange (ETDEWEB)

The effects of thiosulfate ion and solution pH on pitting corrosion of Alloy 690 in chloride solution were explored. Potentiodynamic polarization measurements were conducted to evaluate pitting corrosion susceptibility of Alloy 690 in these environments. The results showed that pitting corrosion occurred in the mill-annealed (1050 deg. C/5min) Alloy 690 in 1 wt% NaCl solution but not in 0.1 M Na{sub 2}S{sub 2}O{sub 3} solution. The value of pitting nucleation potential (E{sub np}) determined in 1 wt% NaCl solution (without Na{sub 2}S{sub 2}O{sub 3} ) increased with increasing solution pH value in the range of 2-10. The addition of Na{sub 2}S{sub 2}O{sub 3} to 1 wt% NaCl solution greatly affected the pitting corrosion behavior, which was dependent on concentration. The preformed nickel sulfide surface film due to the presence of Na{sub ...

Energy Technology Data Exchange (ETDEWEB)

We find instanton/cosmological solutions with biaxial Bianchi-IX symmetry, involving nontrivial spatial dependence of the CP{sup 1}-CP{sup 2}-sigma-models coupled to gravity. Such manifolds arise in N = 1, d 4 supergravity with supermatter actions and hence the solutions can be embedded in supergravity. There is a natural way in which the standard coordinates of these manifolds can be mapped into the four-dimensional physical space. Due to its special symmetry, we start with CP{sup 2} with its corresponding scalar ansatz; this further requires the spacetime to be SU(2) x U(1)-invariant. The problem then reduces to a set of ordinary differential equations whose analytical properties and solutions are discussed. Among the solutions there is a surprising, special family of exact solutions which owe their existence to the nontrivial topology of CP{sup 2} and are in 1-1 correspondence ...

British Library Electronic Table of Contents (United Kingdom)

The aim of this study is to evaluate the specificities of the irradiation of drugs in frozen aqueous solution. The structures of the degradation products were determined to gain insight into the radiolysis mechanisms occurring in frozen aqueous solutions. Metoclopramide hydrochloride and metoprolol tartrate were chosen as models. The frozen solutions were irradiated at dry ice temperature by high energy electrons at various doses. The drug purity (chemical potency) and the radiolysis products were quantified by HPLC-DAD. Characterization of the degradation products was performed by LC-APCI-MS-MS. The structures of the radiolysis products detected in irradiated frozen aqueous solutions were compared to those detected in solid-state and aqueous solutions (previous studies). For both metoclop...

International Nuclear Information System (INIS)

High temperature thermochemistry of thoria-urania fuel for Advanced Heavy Water Reactor was investigated. Oxygen potential development within the matrix and distribution behaviors of the fission products (fps) in different phases were worked out with the help of thermodynamic and transport properties of the fps as well as fission generated oxygen and the detailed balance of the elements. Some of the necessary data for different properties were generated in this laboratory while others were taken from literatures. Noting the behavior of poor transports of gases and volatile species in the thoria rich fuel (thoria-3 mol% urania), the evaluation shows that the fuel will generally bear higher oxygen potential right from early stage of burnup, and Mo will play vital role to buffer the potential through the formation of its oxygen rich chemical states. The problems related to the poor transport and larger retention of fission gases (Xe) and volatiles (I, Te, Cs) are ...

Energy Technology Data Exchange (ETDEWEB)

Optical Isotope shift measurements have been performed for the {sup 240f,242f}Am fission isomers to test the stability of nuclear deformation as function of the neutron number. The method is based on resonance ionization spectroscopy (RIS) in a buffer gas cell with fission detection of the ionization process. The {sup 240f,242f}Am fission isomers have been produced by {sup 242}Pu(p, 3n), {sup 242}Pu(d, 2n) reactions, respectively. Relative isotope shift ratios X{sub exp}{sup 242f}(500 nm)=IS{sup 242f,241}/IS{sup 243,241}=41.4(8) and X{sub exp}{sup 240f}(500 nm)=IS{sup 240f,241}/IS{sup 243,241}=39.2(8) were measured. From these ratios a small difference {delta}{beta}{sub 2}{sup 242f,240f}=0.0076(14) of the deformation parameter {beta}{sub 2} can be deduced assuming that the isotope shift between the reference isotopes {sup 241,243}Am is caused by a pure volume change. (orig.)

International Nuclear Information System (INIS)

Self-assembled quantum dots (QDs) are envisioned as building blocks for realization of novel nanoelectronic devices, for which the site-selective growth is highly desirable. This thesis presents a successful route toward selective positioning of self-assembled InAs QDs on patterned GaAs surface by combination of in situ focused ion beam (FIB) implantation and molecular beam epitaxy (MBE) technology. First, a buffer layer of GaAs was grown by MBE before a square array of holes with a pitch of 1-2 #mu#m was fabricated by FIB implantation of Ga and In, ions respectively. Later, an in-situ annealing step followed by InAs deposition was performed. The InAs QDs were preferentially formed in the holes generated by FIB. The influence of ion dose, annealing parameters and InAs amount was investigated in this work. With optimized parameters, more than 50 % single dot occupancy per hole is achieved. Furthermore, the photoluminescence spectra from positioned QDs confirm their ...

Energy Technology Data Exchange (ETDEWEB)

The neutron radiography system installed at the E-2 experimental hole of the KUR (Kyoto University Reactor) has been used for some NDT applications in the nuclear field. The on-line video image processing system of this facility is introduced in this paper. A 0.5 mm resolution in images was obtained by using a super high quality TV camera developed for X-radiography viewing a NE-426 neutron-sensitive scintillator. The image of the NE-426 on a CRT can be observed directly and visually, thus many test samples can be sequentially observed when necessary for industrial purposes. The video image signals from the TV camera are digitized, with a 33 ms delay, through a video A/D converter (ADC) and can be stored in the image buffer (32 KB DRAM) of a microcomputer (Z-80) system. The digitized pictures are taken with 16 levels of gray scale and resolved to 240 x 256 picture elements (pixels) on a monochrome CRT, with the capability also to display 16 distinct colors on a RGB ...

International Nuclear Information System (INIS)

In developing new Tc-99m brain perfusion imaging agents for SPECT, a series of BAT (bis-aminoethanethiol) derivatives was prepared. These N/sub 2/S/sub 2/ ligands formed stable and neutral complexes with reduced Tc-99m, either by Sn(II)-PPi or sodium borohydride reduction. The purity of the Tc-99m complexes was >95% (HPLC reverse-phase column, acetonitrile: pH 7.0 buffer, 85:15). The biodistribution in rats was evaluated using I-125 iodoantipyrine (IAP), a free diffusible tracer, as the internal reference. Compounds with a free hydroxyl group (I and IV) showed lower brain uptake, inspite of high P.C.; this may be related to in vivo instability of the complexes. High initial brain uptake was observed for three compounds (II, III and V), however, only compound V (P.C.=384) showed significant brain retention. Planar imaging with compound V in a monkey demonstrated that the compound localized in brain and the retention time was T/sub 1/2/=35 min. Compounds of this ...

Energy Technology Data Exchange (ETDEWEB)

Lyophilized human whole blood control material containing lead was prepared for internal and external quality assurance to evaluate and improve the analytical performance of lead. The samples were prepared in four different concentrations from outdated human whole blood stabilized with glucose and a citrate/phosphate buffer and provided under clean room conditions to avoid contamination. The lyophilized samples are easy to reconstitute with water. The materials were evaluated according to a statistical model. The lead concentrations in the specimens are close to blood lead levels usually following environmental and industrial exposure, particular in occupational health to the control of lead exposure at work regulations. The materials are available to the commercial as well as the scientific community. The Danish External Quality Assessment Scheme (DEQAS) for lead in blood is intended to complement the internal quality control for the Danish laboratories assaying ...

International Nuclear Information System (INIS)

A nuclear fuel waste disposal vault would not likely be a sterile environment. Bacterial activity would be expected in those areas of the vault conducive to bacterial life, i.e., where effects of heat, moisture content, radiation and compaction would not prevent or severely restrict bacterial life and where suitable and sufficient nutrients would be present. An inventory of bacterial nutrients that would be emplaced 'intentionally' with vault materials (fuel waste, waste containers, buffer and backfill materials) has been made previously. This report assesses bacterial nutrients that would be added 'inadvertently' to a vault in the form of residues of materials used to excavate and operate a vault. Measurements of blasting material residues in the various water supplies, excavated broken rock (muck) and in cores drilled in old and new tunnel walls were made at AECL's Underground Research Laboratory. Results show that the largest potential nutrient addition (both ...

Energy Technology Data Exchange (ETDEWEB)

The temperature dependence of the spontaneous magnetization of epitaxial iron films with a thickness ranging from d=20 to 200nm has been measured. The films are grown on GaAs (100) substrates which are covered by a 150nm thick silver (100) buffer layer. For three-dimensional BCC iron it was observed already in 1929 that saturation of the spontaneous magnetization for T->0 is perfectly described by a T{sup 2} power law. On the other hand, for thin two-dimensional (2D) iron films a T{sup 3/2} law has been established in many recent experimental investigations. In our iron films grown on diamagnetic silver, this dimensionality change occurs at a thickness between d=100 and 200nm. Comparison of the here-observed T{sup 3/2} coefficients with those on iron films grown on paramagnetic tungsten (110) shows that the 2D interactions are {approx}20 times larger in the films on tungsten. Recent results on Fe films which are grown directly on GaAs (100) confirm that the ...

Energy Technology Data Exchange (ETDEWEB)

Porous SnO{sub 2} nanotubes were prepared via electrospinning followed by calcination in air. As anode materials for lithium ion batteries, the porous nanotubes delivered a high discharge capacity of 807 mAh g{sup -1} after 50 cycles. Even after cycled at high rates, the electrode still retained a high fraction of its theoretical capacity. Such excellent performances of porous SnO{sub 2} nanotubes could be attributed to the porous and hollow structure which facilitated liquid electrolyte diffusion into the bulk materials and buffered large volume changes during lithium ions insertion/extraction. Furthermore, the nanoparticles of nanotubes provided the shorter diffusion length for lithium ions insertion which benefited in retaining the structural stability and good rate performance. Our results demonstrated that this simple method could be extended for the synthesis of porous metal oxide nanotubes with high performances in the applications of lithium ion batteries ...

Energy Technology Data Exchange (ETDEWEB)

W have introduced template-synthesized metal phosphate nanoparticle labels for electrochemical immunoassay. Such use of an apoferritin template offers a simple and convenient route to prepare metallic nanoparticle labels for electrochemical immunoassays and avoid the complicated and time-consuming nanoparticle synthesis process (QD synthesis). Releasing metal ions from metal phosphate in an acetate buffer (pH 4.6) eliminates the harsh condition in the traditional metallic nanoparticle dissolution (e.g., strong acid dissolution of QDs and gold nanoparticles). This method is ultrasensitive and its DL is low to 77fM. The simultaneous detection of multiple protein targets is easily performed by using different metal phosphate nanoparticle labels (cadmium phosphate and lead phosphate). This approach can be extended to prepare multiple metal (such as zinc, lead, cadmium, copper, indium, gold, silver) phosphate nanoparticle labels or hybrid metal (bimetallic or ...

International Nuclear Information System (INIS)

The neutron radiography system installed at the E-2 experimental hole of the KUR (Kyoto University Reactor) has been used for some NDT applications in the nuclear field. The on-line video image processing system of this facility is introduced in this paper. A 0.5 mm resolution in images was obtained by using a super high quality TV camera developed for X-radiography viewing a NE-426 neutron-sensitive scintillator. The image of the NE-426 on a CRT can be observed directly and visually, thus many test samples can be sequentially observed when necessary for industrial purposes. The video image signals from the TV camera are digitized, with a 33 ms delay, through a video A/D converter (ADC) and can be stored in the image buffer (32 KB DRAM) of a microcomputer (Z-80) system. The digitized pictures are taken with 16 levels of gray scale and resolved to 240 x 256 picture elements (pixels) on a monochrome CRT, with the capability also to display 16 distinct colors on a RGB ...

Energy Technology Data Exchange (ETDEWEB)

Deposition of hard coatings may influence the mechanical properties of the bulk material and its corrosion resistance. In this work we study the hardness of the coated and the back side of 100Cr6 steel plates. Electrochemical corrosion tests were performed in O{sub 2}-saturated acetate buffer of pH 5.6 at 25degC. Chromium nitride and titanium nitride coatings prepared by different physical vapour deposition processes, such as arc, thermionic arc evaporation, magnetron sputtering and ion-beam-assisted deposition (IBAD) were compared. The results show that, for sufficient corrosion protection, chromium nitride layers have to be thicker than 500 nm. An increased nitrogen partial pressure in the evaporation chamber of the IBAD process improves the corrosion resistance significantly. The hardness of the substrates was reduced in the case of thermoionic arc evaporation only, indicating a deposition temperature of more than 250degC. For this process, however, we obtained ...

Science.gov (United States)

The wrms of postfit residuals is 23.003 ps and chi-sq/ndg = 1.089. .... 1555-140 1556-245 1600+43A 1600+43B 1600-489 1606-398 \\ 1608+243 1611-710 1628+216 ...

Energy Technology Data Exchange (ETDEWEB)

We study the role of rolling tachyons in the cosmological model with dilatonic gravity. In the string frame, flat space solutions of both initial-stage and late-time are obtained in closed form. In the Einstein frame, we show that every expanding solution is decelerating.

Science.gov (United States)

Finely divided ash-containing coal is immersed in an aqueous solution of hydrochloric acid or citric acid, and acidic ammonium fluoride to cause the ash to react with the acid and the acidic ammonium fluoride, and the deashed coal is thereafter separated from the solution.

Energy Technology Data Exchange (ETDEWEB)

Platinized cadmium sulfide powder suspended in a solution of sodium sulfite produces hydrogen efficiently by visible light. Sulfite ions are oxidized to sulfate and dithionate ions. 4 figures.

UK PubMed Central (United Kingdom)

In this paper, we report a method of precise in situ x-ray scattering measurements on protein solutions using small stationary sample cells. Although reduction in the radiation damage...Full Text Available

UK PubMed Central (United Kingdom)

Severance of the ureter beyond the renal papilla causes a fall in urinary osmolality, which suggests that exchange of water or solute between urine and renal parenchyma normally occurs in the intact...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

The effect of associative interactions of monomers and propagating macroradicals in homopolymerization of N-[3-(dimethylamino)propyl]methacrylamide salts and their copolymerization with acrylonitrile and acrylamide in aqueous solution was studied.

International Nuclear Information System (INIS)

The applicability of two nuclear analytical methods: radionuclide X-ray fluorescence analysis and radiometric titrations based on precipitate formations was studied in order to determine the heptacaine hydrochloride in solutions. The applied methods were evaluated based on the obtained sensitivity values. (author).

Energy Technology Data Exchange (ETDEWEB)

Concentration of an amine solution for removal of hydrogen sulfides and carbon dioxide from natural gas, is tested by carbon dioxide absorption measurement in an apparatus allowing complete reaction to give reliable results.

British Library Electronic Table of Contents (United Kingdom)

The effects of the time and temperature of alkaline pretreatment and the time and temperature of the carboxymethylation of peat in 2-propanol on the concentration of carboxymethyl groups and the solubility of the resulting products in water and an aqueous alkali solution were studied. The viscosity characteristics of the aqueous and aqueous alkaline solutions of peat carboxymethylation products were studied.

UK PubMed Central (United Kingdom)

The antibacterial activity of aqueous solutions of paraformaldehyde in concentrations from 0.1 to 0.4% (w/v) is bacteriostatic rather than bactericidal in the presence or absence of ammonium chloride....Full Text Available

Energy Technology Data Exchange (ETDEWEB)

New partial differential equations (PDEs) for the full order weak schemes of the Langevin simulations are formulated. They are solved recursively in full order series solutions with respect to {radical}(t) (the full order weak Taylor schemes). Arbitrariness involved in the solutions is analyzed and clarified in detail. Specific solutions within some orders are presented as examples of the weak Taylor schemes. These PDEs and their solutions will serve for further developments of efficient higher order Runge-Kutta-like schemes. The similar formulation is possible for the imaginary time Hamiltonian evolution kernels as well. (orig.). 9 refs.

British Library Electronic Table of Contents (United Kingdom)

We apply the group theory to Kadomtsev-Petviashvili-Burgers (KPBII) equation which is a natural model for the propagation of the two-dimensional damped waves. In correspondence with the generators of the symmetry group allowed by the equation, new types of symmetry reductions are performed. Some new exact solutions are obtained, which can be in the form of solitary waves and periodic waves. Specially, our solutions indicate that the equation may have time-dependent nonlinear shears. Such exact explicit solutions and symmetry reductions are important in both applications and the theory of nonlinear science.

Science.gov (United States)

... at the end of this report. A. Low-Velocity Impact of Composite Sandwich Panels In 2007, the PI developed analytical solutions ...

International Nuclear Information System (INIS)

1982. p. 74. Hungary Karimov, A. Musaev, UN Ynusov, G.Sh. Tashkentskij

Energy Technology Data Exchange (ETDEWEB)

In order to remove ash from coal, it is introduced into an aqueous ash removal solution, which contains nitric acid or citric acid and ammonium hydrogen fluoride. The coal without ash is then separated from the aqueous solution. According to the process, either finely ground coal is introduced into the ash removel solution or the coal with the solution is ground in a wet pulveriser.

International Nuclear Information System (INIS)

Drell-Yan pair production is investigated. We reexamine a model where the quark momentum fraction is defined as the ratio of the corresponding light-cone components of the quark and parent nucleon in a naive parton-model approach. It is shown that the results differ from the standard parton model. This is due to unphysical solutions for the momentum fractions within the naive approach which are not present in the standard parton model. In a calculation employing full quark kinematics, i.e., including primordial quark transverse momentum, these solutions also appear. A prescription is given to handle these solutions in order to avoid incorrect results. The impact of these solutions in the full kinematical approach is demonstrated and compared to the modified result.

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

(Aug 1973). United States Moser, AR Matzner, RA Ryan, MP Jr. Center

Science.gov (United States)

Black holes have been predicted since the 1940's from solutions of Einstein's general relativity

Energy Technology Data Exchange (ETDEWEB)

Possibilities of applying the Pb/sup 203/ isotonic solution without a carrier as a label of blood erythrocytes, are found. There is a number of advantages in the Pb/sup 203/ isotonic solution without a carrier, such as a high label efficiency (above 95%), a short half-life (52 hours), and a low radiation dose. These factors prove to be favourable as compared with Cr/sup 51/ widely used for these purposes. Besides, of all preparations used up to now to treat erythrocytes and to scan the spleen, it is only in the case of Pb/sup 203/ isotonic solution without a carrier that no weight amounts of chemical substances do not enter the organism.

CERN Document Server

We find a large family of solutions to the Dirac equation on a manifold of $G_2$ holonomy asymptotic to a cone over $S^3 \\times S^3$, including all radial solutions. The behaviour of these solutions is studied as the manifold developes a conical singularity. None of the solutions found are both localised and square integrable at the origin. This result suggests that M-theory on the conifold over $S^3\\times S^3$ does not produce a chiral theory. The approach here is complementary to previous analyses using dualities and anomaly cancellation which found chiral fermions on all known $G_2$ conifolds except that over $S^3\\times S^3$.

Science.gov (United States)

PMID:20656353

Energy Technology Data Exchange (ETDEWEB)

A comparative study has been performed to compare the 30 wt% of 2-amino-2-methyl-1-propanol (AMP) aqueous solution and 30 wt% of methyldiethanol amine (MDEA) aqueous solution to capture carbon dioxide contained in the flue gas stream. The equilibrium constants for each electrolyte reactions have been used to estimate the carbon dioxide absorption process. Henry's constants for each binary pairs between solute gases and solvent have been used to estimate solubility of the gas components.

Science.gov (United States)

The authors solve the two-dimensional stefan problem of solidification in a half-space, where the heat flux at the wall is a slightly varying function of positioning along the wall, by means of a large Stefan number approximation (which turns out to be equivalent to a small time solution), and then by means of the Heat Balance Integral Method, which is valid for all time, and which agrees with the large Stefan number solution for small times. A representative solution is given for a particular form of the heat flux perturbation.

Energy Technology Data Exchange (ETDEWEB)

Binding of Cd/sup 2 +/ ions in aqueous solutions of statistical copolymers of acrylamide with cadmium acrylate with different content of ionogenic groups in copolymers was investigated by polarography, conductometry, viscometry and dialysis. It is shown that the degree of binding of Cd/sup 2 +/ ions increases with increasing of the content of ionogenic groups in the copolymer and with decreasing of ionic strength of the solution. The values of the degree of binding of Cd/sup 2 +/ ions obtained by polarography and dialysis show satisfactory agreement.

CERN Document Server

In this paper, we study the existence and uniqueness of periodic solutions of the differential equation of the form . Here, we obtain some sufficient conditions which guarantee the existence of periodic solutions. This equation is a quite general third- order nonlinear vector differential equation, and one example is given for illustration of the subject.

International Nuclear Information System (INIS)

Molar extinction coefficients for the solid solutes in aqueous solutions of some alkaline earth chlorides such as MgCl_2.6H_2O, CaCl_2, SrCl_2.6H_2O and BaCl_2.2H_2O have been determined at 81, 356, 511, 662, 1173 and 1332 keV energies in different concentration using the narrow beam transmission methods. (author)

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for deriving hydrolized polyacrylonitrile from a water-based alkali solution. This process is meant to improve the thermal stability of clay drilling solutions by employing the hydrolized product to treat aliphatic non-water-soluble C/sub 8/-C/sub 16/ spirits in an organic dispersant during the presence of acidity and while the solution is being heated.

Energy Technology Data Exchange (ETDEWEB)

The hierarchy of integrable nonlinear equations associated with the quadratic bundle is considered. The expressions for the solution of linearization of these equations and their conservation law in the terms of solutions of corresponding Lax pairs are found. It is shown for the first member of the hierarchy that the conservation law is connected with the solution of linearized equation due to the Noether's theorem. The local hierarchy and three nonlocal ones of the infinitesimal symmetries and conservation laws explicitly expressed through the variables of the nonlinear equations are derived. (author)

International Nuclear Information System (INIS)

During electrolysis of a "2"4"8Cm(III) solution in 2M K_2CO_3 at pH=13, partial oxidation of curium to a higher oxidation state, probably Cm(IV), was observed. The absorption spectra of Cm(III) and Cm(IV) in K_2CO_3 solution were recorded and the molar extinction coefficients of main absorption bands of curium were evaluated. (author).

International Nuclear Information System (INIS)

Peculiarities of metastable #beta#-solid solution decmposition in titanium alloy VT30 in the process of isothermal ageing in the range 500-650 deg C are investigated. Using the methods of transmittion electron microscopy, X-ray diffraction analysis, etc., it is shown that in the case of alloy quenching from the temperature below the point of complete polymorphous transformation (T_t_._t_.), as well as after warm rolling the course of subsequent decomposition of solid solution can be consierably complicated.

Wastenet

...Chapter 11 Aqueous Solutions Chapter 11 Aqueous Solutions Download the entire chapter (PDF-136k) Drilling to China More water than rivers Saving the aquifer Drying with Xeriscapes Everywhere in the house Rainwater and graywater Creating urban watersheds Wastewater equals ...3851 Powered by Intrcomm Technology's SMC ...

CERN Document Server

An S-brane solution with two non-composite electric branes and a set of l scalar fields is considered. The intersection rule for branes corresponds to the Lie algebra A_2. The solution contains five factor spaces with the fifth one interpreted as ``our'' 3-dimensional space. It is shown that there exists a time interval where accelerating expansion of ``our'' 3-dimensional space is compatible with small enough value of effective gravitational ``constant'' variation.

International Nuclear Information System (INIS)

Interfacial tension in the system toluene solution of di-2-ethylhexylphosphoric acid HDEHP-aqueous solutions of inorganic salts has been measured by the drop volume method. The ion-exchange constants in the monolayers formed by HDEHP and alkaline-earth metals have been measured.

Science.gov (United States)

A nonlinear partial differential equation modeling the propagation of a vertical hydraulic fracture first derived by Nordgren is studied. When properly posed, Nordgren's derivation constitutes a Stefan problem and requires another boundary condition-namely, that the velocity of the fluid at the crack tip equals the velocity of crack propagation. With this addition, Nordgren's similarity solution in the no-leakoff case is perfected by a power-series solution. New shut-in solutions are derived in the large-and-no-leakoff cases where the crack of the large-leakoff shut-in solution retracts and the crack of the no-leakoff shut-in solution extends forever. This study ignores the effect of crack-tip rock strength on crack propagation.

International Nuclear Information System (INIS)

The possibility has been studied of oxidizing Prsup((3)) to Prsup((4)) when Prsup((3)) is added to an aqueous weakly-acid solution containing K_1_0[P_2W_1_7O_6_1H_2O] x H_2O. A sharp change in the solution colouring has been observed as a result of Prsup((3)) oxidation to Prsup((4)). The absorption spectra of solution of Prsup((4)) have been recorded and the values of the molar extinction coefficients have been determined. On storage of the solution, Prsup((4))reduces to Prsup((3)) with a half-reduction period of 0.2-0.5 hour.

Energy Technology Data Exchange (ETDEWEB)

Algorithms for generating new exact solutions of the Einstein-Klein-Gordon field equations, which describe inhomogeneous universes with S/sup 3/ topology of spatial sections, are developed. The known exact vacuum and still-fluid solutions with S/sup 3/ topology are used as an input. The methods developed are further applied to derive inhomogeneous generalizations of Bianchi type IX solutions and inhomogeneous S/sup 3/ Gowdy models with gravitational and scalar waves. It is shown that the new solutions, which are generalizations of the Bianchi type IX models, permit identification of the scalar field with the velocity potential of the stiff irrotational fluid. The latter result is further used to study the growth rate of density perturbations of the isotropic and anisotropic Bianchi type IX universes in a fully nonlinear relativistic regime. The role of anisotropy on the rate of growth of density ...

International Nuclear Information System (INIS)

Americium extraction in different oxidation states in two-phase aqueous system based on polyethylene glycol is investigated. Conditions for quantitative extraction of americium (3) and americium (5) from ammonium sulfate solutions within pH=3-5 interval in the presence of arsenazo 3 are found. Composition of the produced americium complexes with reagent is determined; americium (3) interacts with arsenazo 3 in ammonium sulfate solutions with the formation of MeR and Me_2R composition complexes. Absorption spectrum characteristics of americium (3) and- (5) complexes with arsenazo 3 in ammonium sulfate solutions and extracts based polyethylene glycol aqueous solutions are given. Molar extinction coefficients of americium complexes with arsenazo (3) in these solutions are determined.

CERN Document Server

The work identifies the first lattice decoding solution that achieves, in the general outage-limited MIMO setting and in the high-rate and high-SNR limit, both a vanishing gap to the error-performance of the (DMT optimal) exact solution of preprocessed lattice decoding, as well as a computational complexity that is subexponential in the number of codeword bits. The proposed solution employs lattice reduction (LR)-aided regularized (lattice) sphere decoding and proper timeout policies. These performance and complexity guarantees hold for most MIMO scenarios, all reasonable fading statistics, all channel dimensions and all full-rate lattice codes. In sharp contrast to the above manageable complexity, the complexity of other standard preprocessed lattice decoding solutions is shown here to be extremely high. Specifically the work is first to quantify the complexity of these lattice (sphere) decoding ...

International Nuclear Information System (INIS)

Cyclic voltammograms of SUS 304 stainless steel in various neutral solutions such as Na_2SO_4 at high temperature were measured, as a successive study to previous report in which effects of temperature and pH on polarization behavior of stainless steel were studied. In this measurement Ag/AgCl reference electrode and platinum counter electrode were used in a static autoclave lined with inconel. Passive films formed in various conditions were analysed by electron diffraction and Auger spectroscopy. Results obtained were compared with anodic behavior of iron, chromium and nickel and with thermodynamical stabilities of their compounds. The main results are summarized as follows. (1) Stainless steel shows such electrochemical behavior as active dissolution, passivation and transpassivation in a deaerated neutral solution at 250"0C after fully reductive treatment of the specimen. In air-saturated solution, the peak of active ...

Energy Technology Data Exchange (ETDEWEB)

The quantum behavior of the vacuum Bianchi type-IX universe with the cosmological constant is investigated in terms of the Ashtekar variables. An exact solution to the quantum Hamiltonian constraint in the holomorphic representation is given. This solution reduces to the Hartle-Hawking wave function in the spatially isotropic sector and extends in the triad representation to the classically forbidden region where the determinant of the spatial metric becomes negative. The analysis of the quantum Robertson-Walker universe indicates that if the superspace is extended to such a classically forbidden region, the holomorphic representation picks up some restricted class of solutions in general. This observation leads to a new ansatz on the boundary condition of the Universe. In particular, the behavior of the Lorentzian and Euclidean WKB orbits corresponding to the solution suggests a new picture on the ...

Energy Technology Data Exchange (ETDEWEB)

Anode polarization measurement is performed in mixed solution of NaCl and NaF using SUS 304 steel to investigate whether F[sup -] promotes or inhibits pitting corrosion. Pitting corrosion does not occur in the solution of NaF only, but passive state is broken above a certain critical potential, resulting in overall dissolution. When anode polarization measurement is made in a solution of fixed concentration NaCl added with NaF, pitting corrosion is inhibited at a certain critical concentration. F[sup -] has no effect on corrosion potential in the solution up to this critical concentration. Overall dissolution occurs in the solution with higher concentration than the critical concentration, the current value at that time agrees with that in the solution of NaF alone, and no effect of Cl[sup -] is shown. The concentration range where pitting corrosion occurs and ...

International Nuclear Information System (INIS)

The interaction of Np(V), Pu(VI) and Tc(VII) with metal reductants Zn, Cr, Sn and their alloys was investigated in 0.5-4 mol l"-"1 NaOH solutions in static and dynamic conditions (by filtration of solutions through the column filled with grains of metal). In this paper, it was found that the reduction and succeeding precipitation hydroxides of these elements, on the surface of metal grains from 0.5 to 4 mol l"-"1 NaOH solutions, gives a decontamination factor (DF) from 1.1 to 67. The best result was achieved for Pu (DF=67) on Cr grains after 2.5 h contact at 60 C with 0.5 mol l"-"1 NaOH solution containing Pu(VI). Increasing the NaOH concentration, and the addition of chromate ions and complex-forming agents to alkaline solution results in a decrease of the decontamination factor (DF). A better result for Np sorption from 1 mol l"-"1 NaOH solutions was achieved ...

International Nuclear Information System (INIS)

Passivity of aluminum (Al) alloy 3003 in air and in aqueous solutions without and with chloride ions was characterized by electrochemical measurements, including cyclic polarization, electrochemical impedance spectroscopy (EIS), localized EIS and potential of zero charge, Mott-Schottky analysis and secondary ion mass spectroscopy (SIMS) technique. Stability, pitting susceptibility and repassivation ability of Al alloy 3003 under various film-forming conditions were determined. Results demonstrated that passive films formed on 3003 Al alloy in air and in Na2SO4 solution without and with NaCl addition show an n-type semiconductor in nature. The passive film formed in chloride-free solution is most stable, and that formed in chloride-containing solution is most unstable, with the film formed in air in between. Pitting of Al alloy 3003 passivated both in air and in aqueous solutions is ...

International Nuclear Information System (INIS)

In order to investigate the relation between the pitting corrosion and precipitated carbides, the heat treatment of specimens was carried out in two ways: Solution treatment and carbides precipitation treatment. The experiment was focused on the polarization curves of specimens immersed in HCL solution and on the microscopic analysis of the corroded specimens through a potentiodynamic method. It was found out that the intergranular and pitting corrosion occurred remarkably in 0.1N and 1N KCL solution when carbides were precipitated around the grain boundary of the 304 stain steel. The intergranular corrosion was noticed in the region of passivation and the pitting was prominent in the region of passivation break-down. The distribution of pits on the solution treated 304 stainless steel was random, while that of pits on carbides precipitated specimen was concentrated around the grain boundary in 0.1N and ...

Energy Technology Data Exchange (ETDEWEB)

The single-electrode capacitance of a nano-porous carbon electrode used as an electric double layer capacitor was measured. The charged state of the electrolyte ion was discussed from the results. Single-electrode capacitance was not proportional to the specific surface area of the electrode. This implies that the whole surface of the electrode is not effective for the formation of an electric double layer. It is considered that edge orientation of the carbon structure would give a dominant contribution to capacitance. For measurements with aqueous solutions of various electrolytes, capacitance was about the same value for each salt compound. For aqueous acid solution, on the other hand, capacitance was twice to three times as large as that for salt compounds. This difference, however, became negligibly small if the concentration of electrolyte solution was lowered. Taking account of the hydrated ionic radius of each ion, ...

Energy Technology Data Exchange (ETDEWEB)

The objective of this study is to develop an artificial neural network (ANN) model to predict the thermal conductivity of ethylene glycol-water solutions based on experimentally measured variables. The thermal conductivity of solutions at different concentrations and various temperatures was measured using the cylindrical cell method that physical properties of the solution are being determined fills the annular space between two concentric cylinders. During the experiment, heat flows in the radial direction outwards through the test liquid filled in the annual gap to cooling water. In the steady state, conduction inside the cell was described by the Fourier equation in cylindrical coordinates, with boundary conditions corresponding to heat transfer between the solution and cooling water. The performance of ANN was evaluated by a regression analysis between the predicted and the experimental values. The ...

Energy Technology Data Exchange (ETDEWEB)

The temperature effect on corrosion behaviors of PbCaSnCe alloy in 4.5 M H{sub 2}SO{sub 4} solution was investigated by using potentiodynamic curve, electrochemical impedance spectra (EIS), Mott-Schottky plot and photocurrent response methods. It was found that PbCaSnCe alloy was in passive state in sulfuric acid solution, a passive film can be formed on alloy surface. The compositions of passive films formed at 0.9 V for 2 h under different temperatures were detected by X-ray photoelectron spectroscopy (XPS). The results showed that the film resistance and the transfer resistance decreased with the increment of the solution temperature. Mott-Schottky analysis and the photocurrent response revealed that the passive film exhibited n-type semi-conductive character, the donor density of the passive film decreased with increasing the solution temperature. Photocurrent response revealed that the photocurrent ...

Energy Technology Data Exchange (ETDEWEB)

We present a new class of exact solutions of Deser, Jackiw, and Templeton's theory (DJT) of topologically massive gravity which consists of homogeneous, anisotropic manifolds. In these solutions the coframe is given by the left-invariant 1-forms of 3-dimensional Lie algebras up to constant scale factors. These factors are fixed in terms of the DJT coupling constant {mu}m which is the constant of proportionality between the Einstein and Cotton tensors in 3-dimensions. Differences between the scale factors result in anisotropy which is a common feature of topologically massive 3-manifolds. We have found that only Bianchi Types VI, VIII, and IX lead to nontrivial solutions. Among these, a Bianchi Type IX, squashed 3-sphere solution of the Euclideanized DJT theory has finite action, Bianchi Type VIII, IX solutions can variously be embedded in the de Sitter/anti-de Sitter space. ...

International Nuclear Information System (INIS)

We make the supergravity solutions describing the branes (D3 branes and D4 branes) localized within the D6 branes in the near core region of D6 brane. From the D=11 solutions (M3 branes and M4 branes with the Z_N identifications in the transverse space) we obtain the D=10 supergravity solutions of D3 branes localized within D6 branes and D4 branes localized within D6 branes by reducing the dimension down to D=10 along a circular direction of S"3 part of the transverse space. M3 brane solution leads to D=10 background representing D3 branes localized on D6 branes in the region close to the D6 branes core. M4 branes lead to the D4 branes localized on D6 branes in the region close to the D6 brane core.

International Nuclear Information System (INIS)

Wood plastic composite (WPC) has been prepared with a low grade wood simul (Salmalia malabarica) of Bangladesh under Co-60 gamma irradiation using MMA as the bulk monomer combined with methanol as the swelling solvent at different urea concentrations. Effect of a second solute such as NVP, TPGDA and TMPTA in the impregnating solution is evaluated. NVP appears to be the best co-additive/second solute among all the additives used to yield the composite with the highest polymer loading (PL) and tensile strength (TS) at 0.5% urea concentration. (author).

Energy Technology Data Exchange (ETDEWEB)

Reverse osmosis is a simple process and has relatively high decontamination factor compared to other processes used for the treatment of radioactive liquid waste. Furthermore the quantity of secondary waste of this process is small. In this study, test solution containing nine elements such as cesium, strontium, cobalt etc. in chloride forms are treated by reverse osmosis. Permeate rate decreases as the increase of osmotic pressure of feed solution and is expressed by linear equation. Decontamination factor of cations of univalency is more than ten, and about one tenth of that of bivalency. Decontamination factors of all the elements used in this experiment are approximately estimated using the solution-diffusion model.

Energy Technology Data Exchange (ETDEWEB)

Polyhalogenide ions of the type AtX/sub 2//sup -/ (X=Cl, Br, I) were synthesized via reactions of /sup 211/At(THETA)/sup +/ with halogenides in acidic solutions. The formation and stability of these compounds were investigated using electromigration methods. AtI/sub 2//sup -/ is stable in solution down to pH=12, whereas AtCl/sub 2//sup -/ and AtBr/sub 2//sup -/ under these conditions are reduced to astatide. In the absence of halogenides in alkaline solution At(THETA)/sup +/ changes also to At/sup -/.

CERN Document Server

In symmetrical nuclear matter the solutions of pion dispersion equation are investigated in the complex plane of the pion frequency $\\omega$. There are three well-known branches of solutions on the physical sheet : sound, pion and isobar, at the matter density less than the critical one $\\rho <\\rho_c$. At the condition $\\omega^2_c\\leq0$ (in general case Re$ \\omega^2_c\\leq0$) takes place. This points out the instability of the ground state which is possibly related to the pion condensation.

International Nuclear Information System (INIS)

Crystallization points of aqueous solution of the systems M(ClO_4)_2-H_2O (M"2 = Mg"2"+, Ca"2"+, Sr"2"+, Ba"2"+), depending on the salt concentration, were identified by visual-polythermal method. Relying on model notions on the structure of the electrolyte solutions, specific features of strontium perchlorate solubility polytherm and concentration dependence of the relative dynamic viscosity of the salt aqueous solutions are discussed

Energy Technology Data Exchange (ETDEWEB)

We discuss various superstring effective actions and, in particular, their common sector which leads to the so-called pre-big-bang cosmology (cosmology in a weak coupling limit of heterotic superstring theory). Using the conformal relationship between these two theories we present Kasner asymptotic solutions of Bianchi type IX geometries within these theories and make predictions about possible emergence of chaos. Finally, we present a possible method of generating Horava-Witten cosmological solutions out of the well-known general relativistic or pre-big-bang solutions.

CERN Document Server

In aqueous solutions, dissolved ions interact strongly with the surrounding water, thereby modifying the solution properties in an ion-specific manner. These ion-hydration interactions can be accounted for theoretically on a mean-field level by including phenomenological terms in the free energy that correspond to the most dominant ion-specific interactions. Minimizing this free energy leads to modified Poisson-Boltzmann equations with appropriate boundary conditions. Here, we review how this strategy has been used to predict some of the ways ion-specific effects can modify the forces acting within and between charged interfaces immersed in salt solutions.

British Library Electronic Table of Contents (United Kingdom)

Spectral and energy luminescence characteristics of R6G dye solutions in ethanol with addition of Ag nanoparticle suspensions in different aggregate states are experimentally investigated. It is demonstrated that incorporation of non-aggregated and aggregated nanoparticles causes the superluminescence thresholds in R6G solutions to decrease. It is established that the optical properties of the laser beam propagation channel are transformed when low-power (20?mW) cw laser radiation passes through the suspension of nanoparticles. This is manifested through the occurrence of a region with enhanced nanoparticle density in the laser beam center, on which diffraction of laser radiation is observed.

International Nuclear Information System (INIS)

Rats and guinea pigs were fed "2"3"8Pu either biologically incorporated into alfalfa (by growth of the plant on soil containing Pu) or added as a solution to alfalfa, or were gavaged with a Pu solution. Depending upon the plant material fed, there appeared to be a twofold increase in "2"3"8Pu-gut absorption by the rat and a two- to fourfold increase in the guinea pig as compared with absorption from the Pu solution. The data, though limited and variable, suggest that Pu bound to plant tissue may have higher gut absorptivity than inorganic Pu in both herbivorous and nonherbivorous rodents.

Energy Technology Data Exchange (ETDEWEB)

We investigated the effects of additives to the etching solution of 1 M hydrochloric acid on the electrochemical etching behavior for aluminum electrolytic capacitors, using scanning and transmission electron microscopy, and AC impedance spectroscopy. For the addition of 1 M sulfuric acid or 5% ethylene glycol to the hydrochloric acid solution, the distribution of etch tunnels was more uniform with high density of etch pits compared with that without addition. The highest specific surface area was obtained from the electrolyte with 5% ethylene glycol additive. The correlation of internal morphologies of etched foils with impedance parameters was interpreted by impedance techniques.

Energy Technology Data Exchange (ETDEWEB)

Selected samples of waste microbial biomass originating from various industrial fermentation processes and biological treatment plants have been screened for biosorbent properties in conjunction with uranium and thorium in aqueous solutions. Biosorption isotherms have been used for the evaluation of biosorptive uptake capacity of the biomass which was also compared to an activated carbon and the ion exchange resin currently used in uranium production processes. Determined uranium and thorium biosorption isotherms were independent of the initial U or Th solution concentration. Solution pH affected the exhibited uptake. 24 refs.

International Nuclear Information System (INIS)

Enhancing transport sustainability is the password of national, European, and international policies. The development of innovative solutions is ranging from bio fuels to transport analysis models, materials, traction technologies, mobility management, freight villages.

UK PubMed Central (United Kingdom)

Cultures of chick skin fibroblasts were dissolved in solutions of sodium dodecyl sulphate, and their entire protein content was examined by gel electrophoresis. The most abundant species migrated in...Full Text Available

Scientific Electronic Library Online (English)

Abstract in english Structural characterisations using the SAXS technique in a number of nanoheterogeneous materials and liquid solutions are reviewed. The studied systems are protein (lysozyme)/water solutions, colloidal ZnO particles/water sols, nanoporous NiO-based xerogels, hybrid organic-inorganic siloxane-PEG and PPG nanocomposites and PbTe semiconductor nanocrystals embedded in a glass matrix. These investigations also focus on the transformations of time-varying structures and on str (more) uctural changes related to variations in temperature and composition. The reviewed investigations aim at explaining the unusual and often interesting properties of nanostructured materials and solutions. Most of the reported studies were carried out using the SAXS beamline at the National Synchrotron Light Laboratory (LNLS), Campinas, Brazil.

Energy Technology Data Exchange (ETDEWEB)

We have studied freshly prepared lysozyme solutions in heavy water for two NaCl concentrations as a function of temperature. Lysozyme solubilities in this solvent are determined by static light scattering. By small angle neutron scattering, we evidence that interactions between lysozyme molecules are characterized by a second virial coefficient A{sub 2} whether the solution is under-saturated or supersaturated. From the variation of A{sub 2} as a function of temperature we have evaluated the enthalpy corresponding to the interaction between lysozyme molecules. We show that the interactions between protein molecules are higher in heavy water than in light water. (authors). 13 refs., 3 figs.

International Nuclear Information System (INIS)

English 2009 p. 161-162 Brazil Paula, Viviane Silva de Almeida, Fabio

Energy Technology Data Exchange (ETDEWEB)

The effect of counter-ion species on the local conformation of fully-charged poly(L-glutamate) in added-salt aqueous solutions were studied by small-angle X-ray scattering(SAXS). In the case of presence of monovalent counter-ion, the scattering behaviour could be explained by taking into consideration the excluded volume effect and intermolecular-interface interaction on the scattering function of wormlike chain. On the other hand, since SAXS profile of the solution in the presence of divalent counter-ion well fitted to the scattering function of dendrimer, it suggested that the conformation of polymer chain in such solution would be more compact conformation than that of presence of monovalent ion.

International Nuclear Information System (INIS)

... Fuel Limited, Reprocessing Business Division, Rokkasho, Aomori (Japan)

British Library Electronic Table of Contents (United Kingdom)

The aim of this study was to assess the feasibility of radiosterilization of drugs aqueous solutions and to evaluate the effects of some additives, such as mannitol, nicotinamide and pyridoxine, which might protect the drug from degradation. Metoclopramide was selected as a model drug. The structures of the degradation products were determined to gain insight on the radiolysis mechanisms in aqueous solution in order to design strategies to lower the drug degradation.Metoclopramide hydrochloride aqueous solutions with and without excipients were irradiated either with gamma rays or high-energy electrons. HPLC-DAD was used to measure the loss of chemical potency and to quantify the degradation products which were also characterized by LC-APCI-MS-MS. Metoclopramide recovery for gamma and elec...

International Nuclear Information System (INIS)

Russian 1985. p. 114. USSR Levitskaya, GD Ture, MF Lata, LP L'vovskij

British Library Electronic Table of Contents (United Kingdom)

Abstract Purpose: We investigated the effects of various rinsing and healing protocols on corneal wound repair and inflammation following alkali burn in rabbits. Methods: We conducted in vitro, in vivo and ex vivo studies. First, different rinse solutions were tested in vitro after incubation of ocular cells with methanol or NaOH. Cell viability was then assessed using the neutral red test (cytofluorometry). Second, NaOH was applied to rabbit corneas and associations of rinse solutions (NaCl 0.9% or controlled ionization marine solutions) with N-acetylcysteine or vegetable oils (from Calophyllum inophyllum and Aleurites moluccana) were tested in vivo. The regeneration of the corneal epithelium and the infiltration of inflammatory cells were evaluated using in vivo confocal microscopy and e...

Science.gov (United States)

_! Packaging, Cleanlines_, Preparation j Handling ..... 35. 'I. 40. WATER ................ , ......... Sterile, High Purity, Ethylene Glycol-Water Solutions. Requirement For . ...

Energy Technology Data Exchange (ETDEWEB)

X-Ray reflectivity has been used to investigate the microstructural changes of solution-cast stearic acid films before and after immersion in CoCl{sub 2} solutions. Before immersion, the films possess a well-defined layered structure with an interlayer spacing of 4.01{+-}0.05 nm. After the films were immersed in the CoCl{sub 2} solutions, a new set of equidistant diffraction peaks emerge, the corresponding interlayer spacing of which is 5.13{+-}0.05 nm. The X-ray photoelectron spectra of the films indicate the existence of cobalt ions inside the films after immersion. It is concluded that the permeation of the cobalt ions into the hydrophilic interlayer causes the stearic acid molecules to reorient perpendicular to the films, resulting in the increase of interlayer spacing and the roughening of the interfaces.

Science.gov (United States)

PMID:11004287

Science.gov (United States)

Group deal delay solution has fit 42 psec with 2.4% outliers. Group delay ambiguities with spacing 3.9 ns (another world record!) were successfully resolved. ...

Science.gov (United States)

Pulse radiolysis studies of the formation kinetics and the yields of various phenylcarbenium ions from several different solutes in 1,2-dichloroethane solution have been carried out. The results indicate that there are two kinetically distinguishable cationic species of the solvent which react selectively with the different solutes to form the phenylcarbenium ions. It is suggested that one is a cation radical (yield 0.68 molecule/100 eV) and the other a carbocation (yield 0.20 molecule/100 eV). Rate constants for their separate reactions with selected aromatic compounds and with ammonia have been determined. Molar extinction coefficients have been estimated for benzyl cation, diphenyl cation radical, and anthracene cation radical. 6 figures, 1 table.