WorldWideScience
1

{Beta} decay and isomeric properties of neutron-rich Ca and Sc isotopes.  

Energy Technology Data Exchange (ETDEWEB)

The isomeric and {beta}-decay properties of neutron-rich {sup 53-57}Sc and {sup 53,54}Ca nuclei near neutron number N = 32 are reported, and the low-energy level schemes of {sup 53,54,56}Sc and {sup 53-57}Ti are presented. The low-energy level structures of the {sub 21}Sc isotopes are discussed in terms of the coupling of the valence 1f{sub 7/2} proton to states in the corresponding {sub 20}Ca cores. Implications with respect to the robustness of the N = 32 subshell closure are discussed, as well as the repercussions for a possible N = 34 subshell closure.

2010-07-21

2

? decay and isomeric properties of neutron-rich Ca and Sc isotopes  

International Nuclear Information System (INIS)

The isomeric and ?-decay properties of neutron-rich 53-57Sc and 53,54Ca nuclei near neutron number N=32 are reported, and the low-energy level schemes of 53,54,56Sc and 53-57Ti are presented. The low-energy level structures of the 21Sc isotopes are discussed in terms of the coupling of the valence 1f7/2 proton to states in the corresponding 20Ca cores. Implications with respect to the robustness of the N=32 subshell closure are discussed, as well as the repercussions for a possible N=34 subshell closure.

2010-07-01

3

{sup 48}Ti(n,xnpa{gamma}) reaction cross sections using spallation neutrons for E{sub n} = 1 to 20 MeV  

Energy Technology Data Exchange (ETDEWEB)

{gamma}-ray excitation functions have been measured for the interaction of fast neutrons with {sup 48}Ti (neutron energy from 1 MeV to 250 MeV). The Los Alamos National Laboratory spallation neutron source, at the LANSCE/WNR facility, provided a ''white'' neutron beam which is produced by bombarding a natural W target with a pulsed proton beam. The prompt-reaction {gamma} rays were measured with the large-scale Compton-suppressed Ge spectrometer, GEANIE. Neutron energies were determined by the time-of-flight technique. Excitation functions were converted to partial {gamma}-ray cross sections, taking into account the dead-time correction, the target thickness, the detector efficiency, and neutron flux (monitored with an in-line fission chamber). The data analysis is presented here for neutron energies between 1 to 20 MeV. Partial {gamma}-ray cross sections for transitions in {sup 47,48}Ti, {sup ...

2005-01-06

4

Shell-model calculations for neutron-rich nuclei in the 0f1p shell  

Energy Technology Data Exchange (ETDEWEB)

A new two-body interaction recently derived for nuclei in the 0f1p shell by fitting two-body matrix elements to 494 energy levels in A=41-66 nuclei, is used to investigate the neutron-rich nuclei in the vicinity of the doubly closed nuclide {sup 48}Ca. This study is of fundamental interest in providing a test for the new effective interaction away from the stability line. Masses and binding energies are calculated for a variety of neutron-rich nuclei and compared with experimental data, where available. In addition level schemes for {sup 50-52}Ca, {sup 51-52}Sc and {sup 51-52}Ti have been calculated and are compared with available experimental data. In general a good correspondence between theory and experiment is found, but some systematic discrepancies are apparent. ((orig.)).

1995-04-17

5

Shell-model calculations for neutron-rich nuclei in the 0f1p shell  

International Nuclear Information System (INIS)

A new two-body interaction recently derived for nuclei in the 0f1p shell by fitting two-body matrix elements to 494 energy levels in A=41-66 nuclei, is used to investigate the neutron-rich nuclei in the vicinity of the doubly closed nuclide "4"8Ca. This study is of fundamental interest in providing a test for the new effective interaction away from the stability line. Masses and binding energies are calculated for a variety of neutron-rich nuclei and compared with experimental data, where available. In addition level schemes for "5"0"-"5"2Ca, "5"1"-"5"2Sc and "5"1"-"5"2Ti have been calculated and are compared with available experimental data. In general a good correspondence between theory and experiment is found, but some systematic discrepancies are apparent. ((orig.)).

6

Grain growth in CeO{sub 2}: dopant effects, defect mechanism, and solute drag  

Energy Technology Data Exchange (ETDEWEB)

The effects of the dopants, Mg{sup 2+}, Ca{sup 2+}, Sr{sup 2+}, Sc{sup 3+}, Yb{sup 3+}, Y{sup 3+}, Gd{sup 3+}, La{sup 3+}, Ti{sup 4+}, Zr{sup 4+}, and Nb{sup 5+}, on the grain boundary mobility of dense CeO{sub 2} have been investigated from 1,270 to 1,420 C. Parabolic grain growth has been observed in all instances. Together with atmospheric effects, the results support the mechanism of cation interstitial transport being the rate-limiting step. A strong solute drag effect has been demonstrated for diffusion-enhancing dopants such as Mg{sup 2+} and Ca{sup 2+}, which, at high concentrations, can nevertheless suppress grain boundary mobility. Severely undersized dopants (Mg, Sc, Ti, and Nb) have a tendency to markedly enhance grain boundary mobility, probably due to the large distortion of the surrounding lattice that apparently facilitates defect migration. ...

1996-07-01

7

Choosing sustainable consumption: a capability perspective on indicators  

British Library Electronic Table of Contents (United Kingdom)

The concept of sustainable consumption (SC) has been proposed as a way of operationalising sustainable development (SD). However, until now, in view of the difficulties in conceptualising SC, emphasis has been placed mainly on a pragmatic approach. In an a-conceptual and pragmatic account of SC, many problems remain unaddressed, such as the danger of the notion becoming empty and lack of integration between the different dimensions of sustainability. In this paper, we propose that the informational space provided by the capability approach (CA) offers a conceptual framework to elaborate SC. The CA is employed here (i) to discuss the philosophical underpinnings of SC as part of a strategy for enhancing quality-of-life and (ii) to investigate the links between the different dimensions of SC....

2007-01-01

8

SC Development Programme  

CERN Document Server

SC Development Programme

1967-01-01

9

Proposal for the SC Improvement  

CERN Document Server

Proposal for the SC Improvement

1967-01-01

10

Upgrading low molecular weight hydrocarbons  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a process for the conversion of low molecular weight alkanes to higher molecular weight hydrocarbons. It comprises: contacting the low molecular weight alkanes, at an elevated temperature, with oxygen and a catalyst of the formula Zn{sub a}A{sub b}M{sub c}M'{sub d}O{sub x} wherein A is Li, Na, K, or mixtures thereof; M is Al, Ga, Cr, La, Y, Sc, V, Nb, Ta, Cu or mixtures thereof; M' is Cs, Rb, Mg, Ca, Sr, Ba, Sm, Pb, Mn, Sb, P, Sn, Bi, Ti, Zr, Hf, or mixtures thereof; a if from about 1 to about 20; b is from about 0.1 to about 20; c is from about 0 to about 5 d is from about 0 to about 20, and x is a number needed to fulfill the valence requirements of the other elements; provided that at least one c and d is a t least 0.1; and when M' is Sn, c must be at least 0.1.

1989-12-12

11

Ternary oxide nanostructures and methods of making same  

Energy Technology Data Exchange (ETDEWEB)

A single crystalline ternary nanostructure having the formula A.sub.xB.sub.yO.sub.z, wherein x ranges from 0.25 to 24, and y ranges from 1.5 to 40, and wherein A and B are independently selected from the group consisting of Ag, Al, As, Au, B, Ba, Br, Ca, Cd, Ce, Cl, Cm, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Gd, Ge, Hf, Ho, I, In, Ir, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Os, P, Pb, Pd, Pr, Pt, Rb, Re, Rh, Ru, S, Sb, Sc, Se, Si, Sm, Sn, Sr, Ta, Tb, Tc, Te, Ti, Tl, Tm, U, V, W, Y, Yb, and Zn, wherein the nanostructure is at least 95% free of defects and/or dislocations.

2009-09-08

12

Local structure of Ca dopant in BaTiO_3 by Ca K-edge X-ray absorption near-edge structure and first-principles calculations  

International Nuclear Information System (INIS)

The local environment of Ca dopants in barium titanate, BaTiO_3, is investigated by Ca K-edge X-ray absorption near-edge structure (XANES) spectroscopy. In conjunction with experiments, first-principles calculations by two methods are systematically made. The projector-augmented wave (PAW) method is used to optimize the local structure and obtain the formation energy. The augmented plane wave plus local orbitals method is adopted to obtain theoretical XANES spectra. A comparison between experimental and theoretical XANES spectra shows that Ca dopants are located at the Ba"2"+ sites forming Ca"2"+. Formation energy calculations of Ca doped BaTiO_3 by the PAW method also give the same results. The Ca atom in BaTiO_3 is off-centering in comparison with the Ba site in BaTiO_3. The ...

2010-06-01

13

"4"8Ca(d,n)"4"9Sc reaction at 79 MeV  

International Nuclear Information System (INIS)

We measured differential cross sections and vector analyzing powers for the "4"8Ca(d,n)"4"9Sc reaction at 79 MeV. An overall energy resolution of about 325 keV was achieved, and data were extracted for states up to 3.4 MeV of excitation. Both distorted-wave Born approximation and Johnson-Soper adiabatic approximation calculations were performed; in general, the Johnson-Soper adiabatic approximation calculations provide a better description of the data, and yield reasonable spectroscopic factors.

14

Gamow-Teller and spin-dipole strength in the "4"0","4"8Ca(p vector,n vector) reactions at 135 MeV  

International Nuclear Information System (INIS)

Spin-flip probabilities for "4"8Ca(p vector, n vector)"4"8Sc reveal that at 0"0 the apparent continuum under and adjacent to the Gamow-Teller giant resonance is also primarily 1"+ strength. A comparison of "4"0Ca(p vector,n vector)"4"8Sc shows no discernable signature of Gamow-Teller strength in the region -30 > Q(MeV) > -45. The spin-flip component of the dipole resonance for "4"0Ca is broader than the non-spin-flip component. (orig.).

15

The study of 25 MeV alpha particle elastic scattering from a wide range of targets from "4"4Ca to "9"4Zr  

International Nuclear Information System (INIS)

The elastic scattering angular distributions of 25 MeV alpha particles scattered from "7"3Ge, "8"9Y, "9"0Zr, "9"1Zr"9"4Zr, "9"3Nb, "4"4Ca and "4"5Sc have been measured experimentally, and fitted using a conventional optical model. (author).

16

K Depletion Enhances the Extracellular Ca2+-Induced Inhibition of the Apical K Channels in the Mtal of Rat Kidney  

UK PubMed Central (United Kingdom)

We have shown previously that raising extracellular Ca2+ inhibited the apical 70-pS K channel in the thick ascending limb (TAL; Wang, W.H., M. Lu, and S.C. Hebert. 1996. Am....Full Text Available

2002-01-01

17

SC Research Programme and Activities  

CERN Document Server

SC Research Programme and Activities

1958-01-01

18

Physicists'Comments on the SC Improvement Programme  

CERN Document Server

Physicists'Comments on the SC Improvement Programme

1967-01-01

19

K and L x-ray production cross sections excited by 14.00--34.16 MeV #alpha#-particle beams  

International Nuclear Information System (INIS)

K and L-shell x-ray production cross sections were measured using #alpha#-particle beams of 14.00 to 34.16 MeV. The K-shell measurements ranged from Z = 20 to Z = 50 and included Ca, Sc, Ti, V, Fe, Ni, Cu, Zn, Ga, Br, Rb, Sr, Y, Mo, Ag, In, and Sn while the L-shell measurements ranged from Z = 55 to Z = 92 and included Cs, Ba, Ce, Gd, Tm, Lu, Au, Pb, Th, and U. Thin metallic foils were used for the measurements and corrections for self-attenuation were negligible. A liquid nitrogen cooled Si(Li) detector and associated pulsed optical electronics were used in detecting x-rays. Absolute cross sections with an uncertainty of +-10 percent are presented for the elements measured. Also smoothed cross sections are presented which were generated by a three term polynomial fit of the experimental data points. By use of available fluorescence yields the K-shell data were converted to ionization cross sections and compared to various ...

20

Activation method for determination of Pb, La, Zr and Ti macrocomponents in lead-lanthanum zirconate-titanate materials on a neutron generator  

International Nuclear Information System (INIS)

Instrumental neutron activation analysis is used for simultaneously determination of macrocomponents in ferroelectric materials LLZT. Pb, Zr, Ti have been determined by "2"0"3Pb, "8"9Zr and "4"8Sc nuclides created by fast neutron (14.5 MeV) activation. Application of paraffine as neutron moderator and reflector allows to simultaneously determine lanthanum by "1"4"0La nuclide. It has been shown that zirconium, titanium and lanthanum can be determined with the accuracy of #+-#0.1 mas. % and lead - #+-#0.7 mas. %.

21

Fully relativistic analysis of the absorption spectra of Ca_3Sc_2Ge_3O_1_2:Ni"2"+  

International Nuclear Information System (INIS)

Systematic analysis of the energy level schemes, ground state absorption (GSA) and covalency effects for the Ni"2"+ ion in Ca_3Sc_2Ge_3O_1_2 was performed. The recently developed first-principles approach to the analysis of the absorption spectra of impurity ions in crystals based on the discrete variational multi-electron method (DV-ME) [K. Ogasawara et al., Phys. Rev. B 64, 115413 (2001)] was used in the calculations. As a result, complete energy level schemes of Ni"2"+ and its absorption spectra at both possible crystallographic positions (distorted octahedral Sc"3"+ and tetrahedral Ge"4"+ positions) were calculated, assigned and compared with experimental data. Energies of the charge transfer (CT) transitions for both positions are estimated. Numerical contributions of all possible electron configurations into the calculated energy states were determined. By performing analysis of the molecular orbitals (MO) population, ...

2006-10-01

22

Evidence of FCC titanium hydride formation in #beta# titanium alloy: An X-ray diffraction study  

International Nuclear Information System (INIS)

Three types of titanium hydrides have been reported: #delta#, #epsilon# and #gamma# hydrides. The #delta# hydride forms in the composition range from TiH/sub 1.5/ to TiH/sub 1.99/ and has a CaF/sub 2/ structure with metal atoms on an fcc lattice and hydrogen atoms randomly occupying tetrahedral interstitial sites. At higher hydrogen concentrations, TiH/sub 2/, the fct (c/a # #epsilon# transformation is apparently diffusionless, similar to that operating in the cubic/tetragonal transformation in zirconium hydride. The metastable fct #gamma# hydride having a c/a value of 1.09 or 1.12 forms from solid solutions of hydrogen in the hcp #alpha# matrix. While the titanium hydride precipitation in #alpha#-Ti and its alloys has attracted extensive investigation, hydride formation in bcc #beta#-Ti alloys has rarely been studied ...

23

Calcium phosphate glass-ceramics for bioactive coating on a #beta#-titanium alloy  

International Nuclear Information System (INIS)

The formation of a porous coating is the decisive feature for the bio-compatibility of silica-free calcium phosphate glass ceramics on alloy surfaces like the #beta#-Ti structured Ti-29Nb-13Ta-4.6Zr used in this work. The ceramic composition is highly important: 50CaO-40P_2O_5-7Na_2O-3TiO_2 glass powder produces a pore-free coating unable to bind hydroxyapatite, whereas 60CaO-30P_2O_5-7Na_2O-3TiO_2 glass incorporates pores from which a crystalline hydroxyapatite phase can grow over the surface from simulated body fluid (see Figure). (Abstract Copyright [2003], Wiley Periodicals, Inc.)

2003-07-01

24

Particle-hole strength excited in the /sup 40/Ca(p,n)/sup 40/Sc reaction at 134 MeV  

International Nuclear Information System (INIS)

The /sup 40/Ca(p,n)/sup 40/Sc reaction was studied at 134 MeV. Neutron energy spectra were measured by the time-of-flight technique with resolutions of 220 keV at angles from 0"0 to 41"0 and 415 keV out to 62"0. The 2"-,3"-,4"-,5"- band of states based on the (f/sub 7/2/,d/sub 3/2//sup -1/) 1p1h structure was observed at low excitation energies, in good agreement with known analog states in /sup 40/Ca and /sup 40/K. The shapes of the cross-section and analyzing-power angular distributions are in good agreement with distorted-wave impulse-approximation calculations using simple 1p1h (Tamm-Dancoff approximation) shell-model wave functions. A relatively strong transition to a state at E/sub x/ = 2.3 MeV with L = 3 is identified tentatively as a 4"- state with the predominant 1p1h structure (1f/sub 7/2/,2s/sub 1/2//sup -1/).

26

ZnO microsheet modified TiO2 nanoparticle composite films for dye-sensitized solar cells  

British Library Electronic Table of Contents (United Kingdom)

Randomly oriented ZnO microsheets were successfully self-assembled on TiO2 nanoparticle (TN) film to act as the scattering layer via a cathodic electrodeposition process. The light scattering properties of ZnO microsheets were studied by UV-Vis spectrometer in the 400?800 nm wavelength range. It was found that ZnO microsheets exhibited excellent ability to scatter the incident light for ZnO microsheet-TiO2 nanoparticle (ZT) composite films. The results showed that dye-sensitized solar cells (DSSCs) fabricated with ZT composite films showed higher short-circuit density (J sc) and conversion efficiency than TN-based DSSCs, due to the light scattering properties of ZnO microsheets.

2010-01-01

27

Commander's Handbook for Strategic Communication and ...  

Science.gov (United States)

... to integrate and synchronize SC efforts and capabilities, as noted in the SC Roadmap, the joint community needs to publish SC policy and expand ...

2009-10-27

28

Formation of nano-sized particles of a solid electrolyte by laser ablation  

Energy Technology Data Exchange (ETDEWEB)

Nano-sized particles of a lithium ion conductive solid electrolyte, LiTi{sub 2}(PO{sub 4}){sub 3}, were prepared by laser ablation. The obtained particles were ca. 10nm in diameter. X-ray powder diffraction and Raman spectroscopy showed that they were amorphous with local structure similar to the crystalline counterpart. They were crystallized by the heating at ca. 630{sup o}C. (author)

2005-08-26

29

Beta-decay studies of neutron-rich Sc-Cr nuclei  

International Nuclear Information System (INIS)

The neutron-rich nuclei"5"7","5"8_2_1Sc,"5"8"-"6"0_2_2Ti,"6"0"-"6"3_2_3V,"6"2"-"6"6_2_4Cr have been produced at Ganil via interactions of a 61.8A MeV "7"6Ge beam with a "5"8Ni target. Beta-decay studies have been performed using combined #beta#- and #gamma#-ray spectroscopy. Half-lives have been determined and #beta#-decay schemes are proposed for "5"8Ti, "6"1V and "6"2Cr. From these studies, new hints for the existence of #beta#-decaying isomers in "6"0V and in "6"2Mn are provided. These results are compared to shell model calculations. The role of the #pi#f_7_/_2- #nu#f_5_/_2 proton-neutron interaction is examined through its influence on the lifetime values. (orig.)

2005-01-01

30

SiAlON hardmetal materials  

International Nuclear Information System (INIS)

Sialons are phases in the Si-Al-O-N and M-Si-Al-O-N systems where M includes Li, Mg, Ca, Sc, Y and the rare earth elements. They are comparable in variety with the mineral silicates and are built up of one-, two-, and three-dimensional arrangements of (Si,Al)(O,N)/sub 4/ tetrahedra in the same way that the structural units of the silicates are SiO/sub 4/ tetrahedra. These new materials include N-containing ceramics, glasses and glass-ceramics that are being explored for their thermal, chemical and physical properties.

31

Determination of constituent elements in some Nigerian medicinal plants by thermal-neutron activation analysis  

Energy Technology Data Exchange (ETDEWEB)

This study of the inorganic chemical composition of 10 different Nigerian medicinal plant species, using the technique of instrumental neutron activation analysis (INAA), resulted in the determination of the concentrations of 18 major, minor, and trace elements: Al, Ba, Br, Ca, Cl, Eu, Fe, Ga, K, La, Mn, Na, Sb, Sc, Si, Sm, V, and Zn. The parts of the plants used were roots, leaves, and bark. The NBS SRM 1571 Orchard Leaves was also analyzed to assess the accuracy of the procedures used. 21 refs., 4 tables.

1984-04-02

32

Slide 1  

Wastenet

Sc.Technology & Policy (M.I.T., USA) M.Sc.

33

RXTE observations of Cas A  

International Nuclear Information System (INIS)

Rossi X-ray Timing Explorer (RXTE) observations of the bright supernova remnant Cas A have revealed a hard power law component above 10 keV in addition to two thermal components inferred from ASCA measurements of the many line centroids from low-Z elements. The power law can be shown to be consistent with synchrotron emission from radio to hard x-rays by electrons of up to 4 x 10"1"3 eV. Measurement of the 1157 keV line by CGRO from "4"4Sc in the chain of decay of "4"4Ti predicts that the two "4"4Ti lines at 68 and 78 keV should appear at the CGRO intensity. RXTE has placed upper limits on such lines that are marginally consistent with the CGRO measurement. Implications of these results on sites for cosmic ray acceleration and nucleosynthesis are discussed.

1999-01-01

34

Simultaneous production of "2"8Mg and "4"7Ca by high-energy heavy-ion irradiation for applications in biology  

International Nuclear Information System (INIS)

With the aim of preparing carrier-free "2"8Mg and "4"7Ca simultaneously, Ti, V and Fe targets were examined by irradiating with high-energy ions of "1"2C, "1"4N and "1"6O accelerated by the RIKEN ring cyclotron. Among the targets, V gave the highest cross section for the formation of both "2"8Mg and "4"7Ca irrespective of the kind of beams. The cross section for the formation of "2"8Mg by the reactions of Ti, V and Fe targets with ion beams increased in the order of "1"2C<"1"6O<"1"4N. On the other hand, the three beams exhibited almost the same cross sections for the formation of "4"7Ca by the reaction of a given target. Titanium and V were selected as prospective targets and "1"4N as a suitable beam for the production of "2"8Mg and "4"7Ca. Chemical separation procedures of the radiotracers in carrier- and salt-free states have been established by using ...

35

The use of x-ray fluorescence in the detection of inorganic elements in medicines drugs  

International Nuclear Information System (INIS)

Based on the instrumental wavelength dispersive X-ray fluorescence technique of analysis (W D-X R F), the inorganic elements in four samples of commercial medicines drugs were analyzed. The samples were used without any chemical separation of the elements or chemical pre-treatment. Eleven elements could be identified, namely Si, P, S, Cl, K, Ca, Ti, Mn, Fe, Cu and Zn. However, Si, Ti and Mn have not been mentioned in the printed instructions for the use of the medicines drugs by the producers. (author)

36

Fully relativistic analysis of the absorption spectra of Ca{sub 3}Sc{sub 2}Ge{sub 3}O{sub 12}:Ni{sup 2+}  

Energy Technology Data Exchange (ETDEWEB)

Systematic analysis of the energy level schemes, ground state absorption (GSA) and covalency effects for the Ni{sup 2+} ion in Ca{sub 3}Sc{sub 2}Ge{sub 3}O{sub 12} was performed. The recently developed first-principles approach to the analysis of the absorption spectra of impurity ions in crystals based on the discrete variational multi-electron method (DV-ME) [K. Ogasawara et al., Phys. Rev. B 64, 115413 (2001)] was used in the calculations. As a result, complete energy level schemes of Ni{sup 2+} and its absorption spectra at both possible crystallographic positions (distorted octahedral Sc{sup 3+} and tetrahedral Ge{sup 4+} positions) were calculated, assigned and compared with experimental data. Energies of the charge transfer (CT) transitions for both positions are estimated. Numerical contributions of all possible electron configurations into the calculated energy states were determined. By performing analysis of the ...

2006-10-15

37

Trace Elements in Human Myocardial Infarction Determined by Neutron Activation Analysis  

International Nuclear Information System (INIS)

By means of neutron activation analysis, injured and adjacent uninjured human heart tissue from 12 autopsy cases with myocardial infarction are investigated with respect to the concentration of 23 trace elements. The bulk elements K, Na and P are also determined. A recently developed ion-exchange technique, combined with subsequent y-spectrometry, is used. The following trace elements are determined: Ag, As, Au, Ba, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, Hg, La, Mo, Rb, Sb, Sc, Se, Sm, Zn and W. In the injured tissue compared to the uninjured, calculation on a wet weight basis showed a decrease in Co, Cs, K, Mo, P, Rb and Zn, and an increase in Br, Ca, Ce, La, Na, Sb and Sm. The differences in Ca, La, Mo, P and Zn are dependent on the age of the myocardial infarction, and the regression lines for these elements are given. The concentration of the trace elements in uninjured tissue from infarcted hearts is ...

1965-01-01

38
39

Nuclear structure of light Ca and heavy Cr isotopes  

Energy Technology Data Exchange (ETDEWEB)

In the present thesis, the shell structure in exotic nuclei has been investigated. The focus of the work was on finding new experimental data in neutron-rich Cr and proton-rich Ca isotopes. The investigation of light Ca isotopes concentrated on the nucleus {sup 36}Ca which was produced in a knockout reaction from a radioactive {sup 37}Ca beam. For {sup 36}Ca, the excitation energy of the first 2{sup +} state has been measured for the first time. Furthermore, momentum distributions were analyzed using a Monte-Carlo simulation of the knockout reaction. This analysis yielded the contributions of neutrons from individual orbitals to the total knockout cross section. In principle, these may be used to calculate spectroscopic factors, but such a calculation is hampered by difficulties of present knockout-reaction models in predicting precise single-particle cross sections. The measured ...

2007-07-01

40

Determination of macro, micro nutrient and trace element concentrations in Indian medicinal and vegetable leaves using instrumental neutron activation analysis  

Energy Technology Data Exchange (ETDEWEB)

Leafy samples often used as medicine in the Indian Ayurvedic system and vegetables were analyzed for 20 elements (As, Ba, Br, Ca, Ce, Cr, Cs, Co, Eu, Fe, K, La, Na, Rb, Sb, Sc, Sm, Sr, Th, Zn) by employing Instrumental Neutron Activation Analysis (INAA). The samples were irradiated at the 100 kW TRIGA-MAINZ nuclear reactor and the induced activities were counted by gamma ray spectrometry using an efficiency calibrated high resolution High Purity Germanium (HPGe) detector. The concentration of the elements in the medicinal and vegetable leaves and their biological effects on human beings are discussed.

1999-05-01

41

Availability of essential trace elements in Ayurvedic Indian medicinal herbs using instrumental neutron activation analysis  

Energy Technology Data Exchange (ETDEWEB)

Specific parts of several plants (fruits, leaves, stem, bark and roots) often used as medicines in the Indian Ayurvedic system have been analysed for 20 elements (As, Ba, Br, Ca, Cl, Co, Cr, Cu, Fe, K, Mn, Mo, Na, P, Rb, Sb, Sc, Se, Sr and Zn) by employing instrumental neutron activation analysis (INAA). The samples were irradiated with thermal neutrons in a nuclear reactor and the induced activity was counted using high resolution gamma ray spectrometry. Most of the medicinal herbs have been found to be rich in one or more of the elements under study. (Author).

1997-01-01

42

A statistical evaluation of recent SSC conductors produced at IGC/ASI  

International Nuclear Information System (INIS)

One of the requirements for uniform field quality in the SSC dipole magnets is the consistency in the superconducting strand characteristics from start to finish to the production phase. As full scale production of strand and cable approaches, the consistency in performance of the early batches of conductor needs to be examined. A number of 300 mm billets have been manufactured at IGC with tight process controls. The performance of the final conductor in terms of piece lengths, current density, Cu/Sc ratio and wire diameter has been evaluated. The data are analyzed in order to understand the variations that are related to the conductor design and processing. In this paper the current density of the strand is examined over the length of the billet to determine inherent variability in the Nb/Ti alloy itself.

1990-09-24

43

Grain boundary mobility in Y{sub 2}O{sub 3}: defect mechanism and dopant effects  

Energy Technology Data Exchange (ETDEWEB)

The effects of the dopants, Mg{sup 2+}, Sr{sup 2+}, Sc{sup 3+}, Yb{sup 3+}, Gd{sup 3+}, La{sup 3+}, Ti{sup 4+}, Zr{sup 4+}, Ce{sup 4+}, and Nb{sup 5+}, on the grain boundary mobility of dense Y{sub 2}O{sub 3} have been investigated from 1,500 to 1,650 C. Parabolic grain growth has been observed in all cases over a grain size from 0.31 to 12.5 {micro}m. Together with atmospheric effects, the results suggest that interstitial transport is the rate-limiting step for diffusive processes in Y{sub 2}O{sub 3}, which is also the case in CeO{sub 2}. The effect of solute drag cannot be ascertained but the anomalous effect of undersized dopants (Ti and Nb) on diffusion enhancement, previously reported in CeO{sub 2}, is again confirmed. Indications of very large binding energies between aliovalent dopants and oxygen defects are also observed. Overall, the most effective grain growth inhibitor is Zr{sup 4+}, while the most potent grain ...

1996-07-01

44

Grain boundary mobility in Y_2O_3: defect mechanism and dopant effects  

International Nuclear Information System (INIS)

The effects of the dopants, Mg"2"+, Sr"2"+, Sc"3"+, Yb"3"+, Gd"3"+, La"3"+, Ti"4"+, Zr"4"+, Ce"4"+, and Nb"5"+, on the grain boundary mobility of dense Y_2O_3 have been investigated from 1,500 to 1,650 C. Parabolic grain growth has been observed in all cases over a grain size from 0.31 to 12.5 microm. Together with atmospheric effects, the results suggest that interstitial transport is the rate-limiting step for diffusive processes in Y_2O_3, which is also the case in CeO_2. The effect of solute drag cannot be ascertained but the anomalous effect of undersized dopants (Ti and Nb) on diffusion enhancement, previously reported in CeO_2, is again confirmed. Indications of very large binding energies between aliovalent dopants and oxygen defects are also observed. Overall, the most effective grain growth inhibitor is Zr"4"+, while the most potent grain growth promoter is Sr"2"+, both at 1.0% concentration.

45

Application of neutron activation analysis method in leaves of Casearia obliqua medicinal plant; Aplicacao do metodo de analise por ativacao com neutrons na analise de folhas da planta medicinal Casearia obliqua  

Energy Technology Data Exchange (ETDEWEB)

The pharmacological properties of medicinal plants have been related to the presence of organic compounds, however elements are also known to have an important participation in the active compounds constitution process. In this study, instrumental neutron activation analysis (INAA) was applied to determine elements in leaves of Casearia obliqua medicinal plant collected at two different locations in the Atlantic Forest, Brazil, SP. Soil samples collected from where this plant was grown were also analyzed in order to verify if there is a correlation between the elements present in soils and plant leaves. Br, Ca, Cl, Co, Cr, Cs, Fe, K, La, Mn, Na, Rb, Sb, Sc and Zn were determined in C. obliqua leaves and the elements As, Ca, Ce, Eu, Fe, Hf, La, Lu, Nd, Rb, Sc, Sm, Tb, Th, U and Zn in soils. Soil samples collected from two different locations presented similar concentrations for most elements. Likewise, ...

2005-07-01

46

Nucleosynthesis in the Hot Convective Bubble in Core-Collapse Supernovae  

Energy Technology Data Exchange (ETDEWEB)

As an explosion develops in the collapsed core of a massive star, neutrino emission drives convection in a hot bubble of radiation, nucleons, and pairs just outside a proto-neutron star. Shortly thereafter, neutrinos drive a wind-like outflow from the neutron star. In both the convective bubble and the early wind, weak interactions temporarily cause a proton excess (Y{sub e} {approx}> 0.50) to develop in the ejected matter. This situation lasts for at least the first second, and the approximately 0.05-0.1 M{sub {circle_dot}} that is ejected has an unusual composition that may be important for nucleosynthesis. Using tracer particles to follow the conditions in a two-dimensional model of a successful supernova explosion calculated by Janka, Buras, and Rampp (2003), they determine the composition of this material. most of it is helium and {sup 56}Ni. The rest is relatively rare species produced by the decay of proton-rich isotopes unstable to positron emission. In the absence of ...

2004-09-02

47

High lithium ion conductive solid electrolytes. Ko lithium ion dodensei kotai denkaishitsu no kenkyu  

Energy Technology Data Exchange (ETDEWEB)

The paper describes a lithium battery researched on under the Moonlight Project which is a long life secondary battery with high energy density and high power density. Using as a base a Li4SiO4 system which exhibits stable and high Li[sup +] conductivity as solid electrolyte material, partial Si[sup 4+] is replaced with divalent ions such as B[sup 3+] and Al[sup 3+] or divalent ions such as Ni[sup 2+] and Co[sup 2+], by which Li[sup +] for electric charge compensation can be increased and conductivity is enhanced. As to a LiTi2P3O12 system, Ti[sup 4+] is replaced with Sc[sup 3+] and Y[sup 3+]. In both systems, by replaCing Si[sup 4+] or Ti[sup 4+] with trivalent metal ions and increasing mobile Li[sup +], those with ion conductivity exceeding that at 300[degree]C, 10[sup -3]Scm[sup -1], can be developed. TiS2 and NiPS3 are prepared as cathode material and miniature cells are trially ...

1993-02-26

48

Optical potentials and isoscalar transition rates from 104 MeV alpha-particle scattering by the N=28 isotones _4_8Ca, _5_0Ti and _5_2Cr  

International Nuclear Information System (INIS)

Precisely measured differential cross sections for elastic and inelastic scattering from 104 MeV alpha-particles by _4_8Ca, _5_0Ti and _5_2Cr are reported. The analyses aim primarily at the determination of strength, radial shapes and deformation of the scattering potentials, looking for isotonic differences of N=28 isotones. The mean square radii of the (real) potentials are discussed in terms of mean square radius differences of the matter distributions. The isoscalar transition rates derived by coupled channel analyses of the measured cross sections are compared with electromagnetic rates. In addition to the analyses on the basis of a slightly generalized extended optical model a semi-microscopic deformed folding model has been applied, using a density-dependent effective alpha-bound nucleon interaction. Though an excellent description of the data over the full angular range is obtained the resulting values of the deformation parameters ...

49

Optical potentials and isoscalar transition rates from 104 MeV alpha-particle scattering by the N=28 isotones /sup 48/Ca, /sup 50/Ti and /sup 52/Cr  

Energy Technology Data Exchange (ETDEWEB)

Precisely measured differential cross sections for elastic and inelastic scattering from 104 MeV alpha-particles by /sup 48/Ca, /sup 50/Ti and /sup 52/Cr are reported. The analyses aim primarily at the determination of strength, radial shapes and deformation of the scattering potentials, looking for isotonic differences of N=28 isotones. The mean square radii of the (real) potentials are discussed in terms of mean square radius differences of the matter distributions. The isoscalar transition rates derived by coupled channel analyses of the measured cross sections are compared with electromagnetic rates. In addition to the analyses on the basis of a slightly generalized extended optical model a semi-microscopic deformed folding model has been applied, using a density-dependent effective alpha-bound nucleon interaction. Though an excellent description of the data over the full angular range is obtained the resulting values of the deformation ...

1983-08-01

50

Strategic Communication: A Department of Defense Approach  

Science.gov (United States)

... development of SC policy within DOD, because it describes the necessary link between DOD ... strategy convolutes USG efforts to develop SC policy. ...

2007-03-28

51

Deep donor states of muonium in silicon and germanium (status report exp SC81)  

CERN Document Server

Deep donor states of muonium in silicon and germanium (status report exp SC81)

1979-01-01

52

Competition of ferromagnetism and superconductivity in Sc3InB  

Science.gov (United States)

We present results of electronic structure calculations for the intermetallic perovskite Sc3InB with the full-potential KKR-LDA method. Sc3InB is a very promising candidate for a new superconductor (related to 8 K MgCNi3) and can be regarded as a boron-inserted cubic Sc3In, which is a high-pressure allotropic form of the hexagonal weak ferromagnet Sc3In. We predict that cubic Sc3In can also be magnetic, whereas Sc3InB having large DOS in the vicinity of E F exhibits non-magnetic ground state. Estimation of the electron-phonon coupling for Sc3InB gives 1. Furthermore, the effect of vacancies in Sc3InB1-x and antisite disorder in Sc3(In-B) on critical parameters is also discussed using the KKR-CPA method. All theoretical results support the possibility of the superconductivity onset in ...

2006-01-01

53

Two Functional S100A4 Monomers Are Necessary for Regulating Nonmuscle Myosin-IIA and HCT116 Cell Invasion.  

Science.gov (United States)

S100A4, a member of the Ca(2+)-activated S100 protein family, regulates the motility and invasiveness of cancer cells. Moreover, high S100A4 expression levels correlate with poor patient survival in several cancers. Although biochemical, biophysical, and structural data indicate that S100A4 is a noncovalent dimer, it is unknown if two functional S100A4 monomers are required for the productive recognition of protein targets and the promotion of cell invasion. To address this question, we created covalently linked S100A4 dimers using a glycine rich flexible linker. The single-chain S100A4 (sc-S100A4) proteins exhibited wild-type affinities for calcium and nonmuscle myosin-IIA, retained the ability to regulate nonmuscle myosin-IIA assembly, and promoted tumor cell invasion when expressed in S100A4-deficient colon carcinoma cells. Mutation of the two calcium-binding EF-hands in one monomer, while leaving the other monomer intact, caused a ...

2011-07-13

54

Studies of metallofullerene primary soots by laser and thermal desorption mass spectrometry  

Energy Technology Data Exchange (ETDEWEB)

Laser desorption (LD) and thermal desorption (TD) mass spectra of the metallofullerenes found in arc-produced primary soots have been studied for a large variety of alkaline earth and lanthanide elements. The metallofullerene ratios found in the LD spectra indicate that two distinct groups are observed: Sc, Y, La, Ce, Pr, Nd, Gd, Tb, Ho, Er, and Lu (group A) and Ca, Sr, Sm, Eu, and Yb (group B). The TD spectra of most of these same soots also separate into two groups that contain the same elements as groups A and B. Group A metallofullerenes show strong signals in both LD and TD spectra. Group B metallofullerenes are distinguished by their presence in the LD spectra but absence in the TD spectra. From the general ionic behavior of the elements of these groups, and recent studies of the endohedral oxidation states, we propose that the oxidation states are +3 for group A and +2 for group B. C[sub 70] metallofullerenes are anomalous in that they ...

1993-07-01

55

Observing Evolution in the Supergranular Length Scale During Periods of Low Solar Activity  

CERN Document Server

We present the initial results of an observational study into the variation of the dominant length-scale of quiet solar emission: supergranulation. This length-scale reflects the radiative energy in the plasma of the upper solar chromosphere and transition region at the magnetic network boundaries forming as a result of the relentless interaction of magnetic fields and convective motions of the Sun's interior. We demonstrate that a net difference of ~0.5Mm in the supergranular emission length-scale occurs when comparing observations cycle 22/23 and cycle 23/24 minima. This variation in scale is reproduced in the datasets of multiple space- and ground-based instruments and using different diagnostic measures. By means of extension, we consider the variation of the supergranular length-scale over multiple solar minima by analyzing a subset of the Mt Wilson Solar Observatory (MWO) Ca II K image record. The observations and analysis presented provide a tantalizing look ...

2011-01-01

56

Analysis of medicinal plant extracts by neutron activation method; Analise de extratos de plantas medicinais pelo metodo de ativacao com neutrons  

Energy Technology Data Exchange (ETDEWEB)

This dissertation has presented the results from analysis of medicinal plant extracts using neutron activation method. Instrumental neutron activation analysis was applied to the determination of the elements Al, Br, Ca, Ce, Cl, Cr, Cs, Fe, K, La, Mg, Mn, Na, Rb, Sb, Sc and Zn in medicinal extracts obtained from Achyrolcline satureoides DC, Casearia sylvestris, Centella asiatica, Citrus aurantium L., Solano lycocarpum, Solidago microglossa, Stryphnondedron barbatiman and Zingiber officinale R. plants. The elements Hg and Se were determined using radiochemical separation by means of retention of Se in HMD inorganic exchanger and solvent extraction of Hg by bismuth diethyl-dithiocarbamate solution. Precision and accuracy of the results have been evaluated by analysing reference materials. The therapeutic action of some elements found in plant extracts analyzed was briefly discussed 70 refs., 13 figs., 15 tabs

1995-12-31

57

Use of neutron activation analysis for the control of air pollution of Algiers; Utilisation de l'analyse par activation neutronique pour le controle de la pollution de l'air d'Alger  

Energy Technology Data Exchange (ETDEWEB)

The urban zone needs clean air to assure public health. To achieve this goal several filter samples were collected in different sites in Algiers city. Toxic elements such as: Na, Mg, Cl, Sc, Cr, Ti, V, Fe, Co, Cu, Zn, Se, Br, Ag, Sb, Ce, La, Hf, Ta and Hg have been measured in the filters using neutron activation analysis technique. Irradiation of filter samples and standards were carried out in Es-Salem reactor. The experimental procedure and the results are discussed. We noted during this work that the upper limit values for suspended dusts and the high concentrations for some toxic elements found are due to the weather conditions and intense road traffic around collecting sites. (authors)

2010-07-15

58

Validation of cyanoacrylate method for collection of stratum corneum in human skin for lipid analysis  

DEFF Research Database (Denmark)

Lipids in the stratum corneum (SC) are of major importance for the skin barrier function. Many different methods have been used for the collection of SC for the analysis of SC lipids. The objective of the present study was to validate the cyanoacrylate method for the collection of SC in relation to lipid analysis.

2010-01-01

59

The DISAM Journal of International Security Assistance ...  

Science.gov (United States)

... civilian leadership. The leadership of the Marine Corps believes this represents somewhat of a benchmark for SC policy. It ...

2011-05-14

60

Isothermal high-temperature fatigue tests on {gamma}-TiAl in different atmospheres; Isotherme Hochtemperaturermuedungsversuche an {gamma}-TiAl in unterschiedlichen Atmosphaeren  

Energy Technology Data Exchange (ETDEWEB)

{gamma} Ti-Al have a higher temperature potential than commercial titanium alloys and a 50 percent lower density than nickel base superalloys. Application temperatures in aircraft turbines are 750 C and above. The authors investigated the high-temperature performance of {gamma} TiAl, i.e. isothermal high-temperature fatigue and the type and importance of damage. LCF experiments were made in the temperature range of brittle/ductile transition in air and vacuum. Damage mechanisms were characterized by microstructural investigations. [German] Unter den modernen Hochtemperaturwerkstoffen kommt den Legierungen auf Basis von {gamma}-TiAl eine zunehmend wichtige Bedeutung zu, da diese Werkstoffe ein hoeheres Temperaturpotential als alle kommerziellen Titanlegierungen haben und eine im Vergleich zu den Nickelbasis-Superlegierungen um ca. 50% geringere Dichte aufweisen. TiAl-Werkstoffe, die ...

1999-07-01

61

Estimation of trace elements in some anti-diabetic medicinal plants using PIXE technique  

Energy Technology Data Exchange (ETDEWEB)

Trace elemental analysis was carried out in various parts of some anti-diabetic medicinal plants using PIXE technique. A 3 MeV proton beam was used to excite the samples. The elements Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Br, Rb and Sr were identified and their concentrations were estimated. The results of the present study provide justification for the usage of these medicinal plants in the treatment of diabetes mellitus (DM) since they are found to contain appreciable amounts of the elements K, Ca, Cr, Mn, Cu, and Zn, which are responsible for potentiating insulin action. Our results show that the analyzed medicinal plants can be considered as potential sources for providing a reasonable amount of the required elements other than diet to the patients of DM. Moreover, these results can be used to set new standards for prescribing the dosage of the herbal drugs prepared from these plant materials.

2006-08-15

62

Alteration of leached glass surface  

Energy Technology Data Exchange (ETDEWEB)

The leached glass is subject to leachant attack and results in surface layer alteration which greatly affects the corrosion progress of glass forms. This work studied the composition change, precipitation, pitting corrosion as well as surface layer break and spallation of the leached glass forms. 6 conclusions can be made: 1. The extent of surface layer alteration is related to many factors such as temperature, pH, leachant chemistry, flow rate and leach duration, etc. 2. The alkali element Na is seriously depleted and the elements like U.Ti,Fe, Ca and Mg are enriched in the surface layer. The influence of media has such order: Fe{sub 2}O{sub 3} > Na-bentonite > Zeolite. 3. The precipitate formed in leach test for 56 days at 90 {infinity}C is mostly amorphous, but after 91 days has crystallized. There is K - Ca - Al - Si crystal,the amount of Al, K and Si is increasing, but the amount of ...

1997-07-01

63

Infrared monitoring of the Doublet III beam armor plate  

Energy Technology Data Exchange (ETDEWEB)

An 80 keV, 3.6 MW neutral beam injection system has recently been installed on Doublet III, and the installation of a second system is scheduled within several months. Armor plate consisting of /approximately equals/100 graphite tiles (10 cm x 10 cm) coated with TiC has been plated over portions of the inner vacuum wall lying in the line of sight of the ion sources. In order to monitor the condition of the armor plate an infrared camera and a set of optical pyrometers have been installed alongside the beamline and view the armor plate through a CaF/sub 2/ window. The pyrometers measure the temperature of the armor plate associated with the maximum of the intensity distribution of each ion source.

1981-01-01

64

Biosorption of scandium and yttrium from solutions  

International Nuclear Information System (INIS)

The usage of biosorbents allows separation of scandium and yttrium from each other and from Fe, Al, Ti, Si, and Ca in hydrometallurgical processing of ores and wastes. It was shown that sorption of scandium and yttrium increased with the increase of pH of solution. Initial rate of scandium sorption depended on the biomass type; however 85-98% of scandium was sorbed within 10-30 min with most biomass types tested. The presence of aluminium, iron (III), and titanium in the solution inhibited sorption of scandium and particularly yttrium. After four cycles of sorption, 98.8% of scandium and 87% of yttrium was extracted from red mud leach solution by the biomass of Saccharomyces cerevisiae and Aspergillus terreus, respectively. Selectively of the process of scandium and yttrium recovery could be achieved during sorption and also desorption, when solubilization of sorbed associated elements was inhibited by high pH values. (Author).

65

Automated three-dimensional X-ray analysis using a dual-beam FIB  

International Nuclear Information System (INIS)

We present a fully automated method for three-dimensional (3D) elemental analysis demonstrated using a ceramic sample of chemistry (Ca)MgTiO_x. The specimen is serially sectioned by a focused ion beam (FIB) microscope, and energy-dispersive X-ray spectrometry (EDXS) is used for elemental analysis of each cross-section created. A 3D elemental model is reconstructed from the stack of two-dimensional (2D) data. This work concentrates on issues arising from process automation, the large sample volume of approximately 17x17x10 #mu#m"3, and the insulating nature of the specimen. A new routine for post-acquisition data correction of different drift effects is demonstrated. Furthermore, it is shown that EDXS data may be erroneous for specimens containing voids, and that back-scattered electron images have to be used to correct for these errors.

2007-08-01

66

The formation and degradation of Ti-Ag and Ti-Pd-Ag solar cell contacts  

Science.gov (United States)

Ti-Ag and Ti-Pd-Ag solar cell contacts structure and degradation dependence on high temperature and humidity environmental exposure

1970-01-01

67

Processing of Titanium Alloys.  

Science.gov (United States)

... information about, utilized, or discussed these subjects: basic topics: overview materials and material types: ti-6al-4v, ti1100, ti17 , ti6242, imi 550 ...

69

Strategic Communication and the Combatant Commander  

Science.gov (United States)

... for International Development representatives. 3. If there is SC policy guidance, use it. If not, ask for it. In many cases, summaries ...

2009-10-01

70

Sc"4"5 NMR of scandium(3) salt aqueous solutions  

International Nuclear Information System (INIS)

Russian (Jul 1974). USSR Buslaev, Yu.A. Petrosyants, SP Tarasov,

71

ISO TC 20/SC 14 N  

Science.gov (United States)

runs are necessary, provision shall be made for expansion joints, motion of the units, or similar compensation to ensure that no excessive strains are ...

72

Electronic structure of one-to-one and defect scandium sulfide  

Energy Technology Data Exchange (ETDEWEB)

Self-consistent electronic structure calculations have been performed on two compositions of scandium sulfide ScS and Sc/sub 3/S/sub 4/. The results of the calculation of ScS are similar to those obtained for other transition metal chalcogenides and are in excellent agreement with heat capacity and reflectance measurements as well as UPS experiments. The calculation of the defect structure indicates the creation of sulfur p nonbonding states in metal-deficient ScS. The valency of the metal ions remains unchanged upon the creation of vacancies.

1984-03-01

73

Radiochromatographic separation of scandium(III) with inorganic ion exchanger zirconium phosphosilicate  

International Nuclear Information System (INIS)

A method has been developed for the adsorption of Sc"I"I"I employing inorganic ion exchanger zirconium phosphosilicate by batch method. Effects of various parameters have been evaluated on the percentage adsorption of Sc"I"I"I. Separation of Sc"I"I"I from various other elements is standardized. (author)

1998-03-01

74

ZZ KASHIL-E6, 175 N, 42 Gamma Groups Cross Sections in MATXS Format Based on ENDF/B-VI.5 for Shielding Applications  

International Nuclear Information System (INIS)

1 - Description of program or function: Format: MATXS; Number of groups: 175 neutron-, 42 photon-groups; 176 Nuclides: 1-H-1, 1-H-2, 1-H-3, 2-He-3, 2-He-4, 3-Li-6, 3-Li-7, 4-Be-9, 5-B-10, 5-B-11, 6-C- nat., 7-N-14, 7-N-15, 8-O-16, 8-O-17, 9-F-19, 11-Na-23, 12-Mg-nat., 13-Al-27, 14-Si-nat., 14-Si-28, 14-Si-29, 14-Si-30, 15-P-31, 16-S-32, 17-Cl-nat., 19-K-nat., 20-Ca-nat., 21-Sc-45, 22-Ti-nat., 23-V-nat., 24-Cr-50, 24-Cr-52, 24-Cr-53, 24-Cr-54, 25-Mn-25, 26-Fe-54, 26-Fe-56, 26-Fe-57, 26-Fe-58, 27-Co-59, 28-Ni-58, 28-Ni-60, 28-Ni-61, 28-Ni-62, 28-Ni-64, 29-Cu-63, 29-Cu-65, 31-Ga-nat., 39-Y-89, 40-Zr-nat., 40-Zr-90, 40-Zr-91, 40-Zr-92, 40-Zr-94, 40-Zr-96, 41-Nb-93, 42-Mo-nat., 46-Pd-102, 46-Pd-104, 46-Pd-105, 46-Pd-106, 46-Pd-108, 46-Pd-110, 47-Ag-107, 47-Ag-109, 48-Cd-106, 48-Cd-108, 48-Cd-110, 48-Cd-112, 48-Cd-113, 48-Cd-114, 48-Cd-116, 49-In-nat., 53-I-127, 54-Xe-124, 54-Xe-126, 54-Xe-128, 54-Xe-129, 54-Xe-130, 54-Xe-131, ...

75

Study on cell nucleation behavior of HDPE?wood composites/supercritical CO2 solution based on rheological properties  

British Library Electronic Table of Contents (United Kingdom)

In this study, the shear viscosities of wood?plastic composites (WPC)/supercritical CO2 (sc-CO2) solutions at different die temperatures and sc-CO2 contents were measured by a slit die attached on a single-screw extrusion system. A theoretical model based on the Carreau-Yasuda model and Arrhenius equation was then developed to describe the shear-thinning behavior of the WPC/sc-CO2 solution. This model was incorporated into a finite element method software, POLYFLOW, to simulate the pressure and velocity field of WPC/sc-CO2 solution flowing through a foaming die. Based on the simulation results, the pressure drop rate and the location of the supersaturation point were estimated to investigate the cell nucleation. The saturation pressure of sc-CO2 in WPC was determined by a magnetic suspensi...

2011-01-01

76

Comparison of intrinsic and extrinsic tracer methods for estimating calcium bioavailability to rats from dairy foods  

International Nuclear Information System (INIS)

Dairy products doubly labeled with 45Ca and 47Ca were used to evaluate an extrinsic labeling procedure for calcium bioavailability determination. Nonfat milk, yogurt, and fresh cheese curd were prepared from caprine milk that was intrinsically labeled with 45Ca. The products were then labeled extrinsically with 47Ca and administered to rats by gavage. The 47Ca to 45Ca ratio in bone and teeth averaged about 1.00 with either milk, yogurt, or CaCl2, but the ratio was about 1.04 when dosed with cheese curd. Ca absorption, determined by whole-body counting of 47Ca, was lower (P less than 0.05) in cheese curd (59%) than in either milk (69%), yogurt (72%), or CaCl2 (72%). Expressed as percent of dose, the absorption of 47Ca was highly correlated with bone ...

77

Solid electrolyte and lithium battery employing it. Kotai denkaishitsu oyobi sore wo shiyo shite naru richiumu denchi  

Energy Technology Data Exchange (ETDEWEB)

Recently, the lithium ion-conductive solid electrolyte draws attention because there is a possibility of producing the maintenance-free battery which is characterized by having such advantages as high energy density and no possibility of electrolyte leak because of solid state structure. The invented lithium ion-conductive solid electrolyte is formed by sintering the granular electrolyte expressed in the following general formula: Li(1+(4-n)x)MxTi(2-x)(PO4)3 (M = mono- or di-valent cation, x = 0.1 - 0.5). Examples of the monovalent cation are Na[sup +], K[sup +], Rb[sup +], Cs[sup +], and Cu[sup +]. Examples of divalent cation are Mg[sup 2+], Fe[sup 2+], Be[sup 2+], Ca[sup 2+], Sr[sup 2+], Ba[sup 2+], Ra[sup 2+], Mn[sup 2+], Co[sup 2+], Cu[sup 2+], Ni[sup 2+], Zn[sup 2+], and Cd[sup 2+]. The electric conductivity of lithium ion is increased with the increase in the content of Li[sup +] in the electrolyte. 4 figs.

1993-11-12

78

Open clusters as key tracers of Galactic chemical evolution. III. Element abundances in Berkeley 20, Berkeley 29, Collinder 261, and Melotte 66  

CERN Document Server

Galactic open clusters are since long recognized as one of the best tools for investigating the radial distribution of iron and other metals. We employed FLAMES at VLT to collect UVES spectra of bright giant stars in a large sample of open clusters, spanning a wide range of Galactocentric distances, ages, and metallicities. We present here the results for four clusters: Berkeley 20 and Berkeley 29, the two most distant clusters in the sample; Collinder 261, the oldest and the one with the minimum Galactocentric distance; Melotte 66. Equivalent width analysis was carried out using the spectral code MOOG and Kurucz model atmospheres to derive abundances of Fe, Al, Mg, Si, Ca, Ti, Cr, Ni, Ba; non-LTE Na abundances were derived by direct line-profile fitting. We obtain subsolar metallicities for the two anticenter clusters Be 20 ([Fe/H]=-0.30, rms=0.02) and Be 29 ([Fe/H]=-0.31, rms=0.03), and for Mel 66 ([Fe/H]=-0.33, rms=0.03), located in the ...

2008-01-01

79

Grain boundary segregation of cation dopants in {alpha}-Al{sub 2}O{sub 3} scales  

Energy Technology Data Exchange (ETDEWEB)

A Fe-20at.%Cr-10%Al matrix was dispersed with a wide range of different oxides in order to study the effect of oxygen-active dopants on the high-temperature growth and adhesion of {alpha}-Al{sub 2}O{sub 3} scales. Effect of these various cation dopants on the alumina scale microstructure was correlated with dopant ion segregation to the {alpha}-Al{sub 2}O{sub 3} grain boundaries using analytical electron microscopy. Elements such as Mn and V showed little effect on the oxide scale and were not observed to segregate. Elements such as Y and Gd resulted in finer, more columnar {alpha}-Al{sub 2}O{sub 3} grains and were segregated to scale grain boundaries. However, Ti, Ta, Ca, and Nb also were found to segregate but had a lesser effect on scale morphology. This indicates that cation segregation to scale grain boundaries is not a sufficient condition to achieve beneficial oxidation effects. The driving force for segregation in growing alumina scales ...

1996-12-31

80

Determination of impurities in sialon by ICP-AES  

International Nuclear Information System (INIS)

Impurities (Ca, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Ti, Y, Zn and Zr) in sialon powder were determined by the following procedure: A sample (0.5 g) was heated with a mixture of hydrofluoric acid (3 ml) and nitric acid (1 ml) in a Teflon pressure vessel at 170degC for 16 h. The contents of the vessel were transferred into a platinum crucible containing phosphoric acid (4 ml) and heated on a hot plate until the opaque appearance of the content changed to a clear-syrupy fluid. The fluid was diluted to 100 ml with water and used for ICP-AES analysis of all impurity elements except K, which was determined by AAS. It was necessary to match closely the matrix concentrations (H_3PO_4, Al and/or Y) of the standard solutions with those of sialon sample solutions for the determination of impurities because of interferences of the matrix components. This method was successfully applied to the determination of impurities in commercial sialon samples. (author).

81

Amorphous metal alloy compositions for reversible hydrogen storage and electrodes made therefrom  

Energy Technology Data Exchange (ETDEWEB)

This patent describes an energy storage device. It comprises: a working electrode, a counter electrode, electrically isolated from the working electrode; an electrolyte in contact with the working electrode and the counter electrode, and means for collecting electrical current therefrom; the working electrode consisting essentially of an amorphous metal alloy of the formula: A{sub {ital a}}M{sub {ital b}}M{prime}{sub {ital c}}, wherein A is at least one metal selected from the group consisting of Ag, Hg and Pt; M is at least one metal selected from the group consisting of Pb, Cu, Cr, Mo, W, Ni, Al, Co, Fe, Zn, Ru, Cd and Mn; M{prime} is at lest one of the elements selected from the group consisting of Ca, Mg, Ti, Zr, Hf, V, Nb and Ta; and wherein a ranges from about 0.005 to about 0.80; b ranges from 0.05 to about 0.70; and c ranges from about 0.08 to about 0.95.

1990-05-08

82

Processing of La/sub 1. 8/Sr/sub 0. 2/CuO/sub 4/ and YBa/sub 2/Cu/sub 3/O/sub 7/ superconducting thin films by dual-ion-beam sputtering  

Science.gov (United States)

High quality La/sub 1.8/Sr/sub 0.2/CuO/sub 4/ and YBa/sub 2/Cu/sub 3/O/sub 7/ superconducting thin films, with zero resistance at 88 K, have been made by dual-ion-beam sputtering of metal and oxide targets at elevated temperatures. The films are about 1.0 ..mu..m thick and are single phase after annealing. The substrates investigated are Nd-YAP, MgO, SrF/sub 2/, Si, CaF/sub 2/, ZrO/sub 2/-9% Y/sub 2/O/sub 3/, BaF/sub 2/, Al/sub 2/O/sub 3/, and SrTiO/sub 3/. Characterization of the films was carried out using Rutherford backscattering spectroscopy, resistivity measurements, transmission electron microscopy, x-ray diffraction, and secondary ion mass spectroscopy. Substrate/film interaction was observed in every case. This generally involves diffusion of the substrate into the film, which is accompanied by, for example, the replacement of Ba by Sr in the YBa/sub 2/Cu/sub 2/O/sub 7/ structure, in the case of SrTiO/sub 3/ ...

1988-03-15

83

Plasma nitriding of Ti and Ti-Al coatings  

Energy Technology Data Exchange (ETDEWEB)

The Ti and Ti-Al coatings were deposited onto hot-worked AISI H11 steel substrates and plasma nitrided at 900 C. The Ti coated samples were successfully nitrided, while cracking and delamination of the Ti-Al coating was observed during nitriding. The formation of [delta]-TiN and [epsilon]-Ti[sub 2]N phases were detected after plasma nitriding of the Ti coating. During plasma treatment of the Ti-Al coating, the initial Ti[sub 3]Al and Al phases were paartially transformed into TiAl phase. The martensite transformation of the substrate material was found. The as-deposited Ti coating has a fibrous structure, while the structure of the as-sputtered Ti-Al coating is columnar. The superficial Vickers microhardness of plasma-nitrided ...

1993-12-03

84

Strategic Communication Meets Public Diplomacy: DoD-DoS ...  

Science.gov (United States)

... PDOD on region- wide SC policy and initiatives, and would liaise with their COCOM colleagues (including the embedded ...

2010-10-27

85

Mechanical jacks meant to support the movable shielding wall (Proton Room side) of the SC  

CERN Document Server

This mechanical version was soon after changed into a hydraulic jack one (the reason being a number of serious constructional defects).

1955-01-01

86

Study of the inorganic constituents in different species of Casearia medicinal plant collected in distinct regions of the Atlantic Forest, SP State, Brazil; Estudo sobre os constituintes inorganicos presentes em diferentes especies da planta medicinal do genero Casearia coletadas em regioes distintas da Mata Atlantica, SP  

Energy Technology Data Exchange (ETDEWEB)

The use of medicinal plants in the treatment of diseases has increased significantly in the last years, as has research concerning chemical characterization of these plants. In this study, inorganic constituents were determined in leaves and in extracts from three medicinal plant species of the Casearia genus (C. sylvestris, C. decandra and C. obliqua) collected in distinct regions of the Atlantic Forest, SP. The elemental compositions of the soils in which these plants were grown were also determined. Traditionally, these plants are used due to their antiinflammatory, antiacid, antiseptic and cicatrizing properties. The antiulcer and the antitumor activities of the Casearia genus and its capacity to neutralize snake and bee venoms, have also been scientifically confirmed. The analytical methodology used was neutron activation analysis. Long and short irradiation periods of the samples and the standards were carried out at IPEN's IEA-R1 nuclear research reactor. In the leaf K ...

2006-07-01

87

Vegetable oil extraction using liquid CO/sub 2/  

Energy Technology Data Exchange (ETDEWEB)

SC-CO/sub 2/ extraction of oil from peanuts is an alternative to hexane extraction or the mechanical oil press. Oil was successfully extracted using SC-CO/sub 2/ at temperatures of 25-120/sup 0/C and pressures of 140 -690 Bar. Pressure, temperature and particle size affected the extraction of oil. In the range studied, the highest values of temperature and pressure gave highest solubilities.

1986-01-01

88

Establishment and Maintenance of Human Embryonic Stem Cell Lines on Human Feeder Cells Derived from Uterine Endometrium ...  

Science.gov (United States)

... and pathogen transmission. Because the ultimate object of stem cell research is cell-based clinical therapy, hES cells should ... 4%) Supported by grants (SC12021 and SC11012) from Stem Cell Research...

89

Detecting Sugarcane yellow leaf virus infection in asymptomatic leaves with hyperspectral remote sensing and associated leaf pigment analysis  

Science.gov (United States)

Sugarcane yellow leaf caused by Sugarcane yellow leaf virus (ScYLV) does not produce visual symptoms in most susceptible plants until late in the growing season. An experiment was conducted to determine if leaf reflectance and pigment analysis could be used to determine ScYLV infection prior to sym...

90

Analysis of the economic potential of the landfill in the municipality of Chapeco - SC, Brazil; Analise do potencial economico do aterro sanitario do municipio de Chapeco - SC  

Energy Technology Data Exchange (ETDEWEB)

This study aims to evaluate the economic and environmental viability of the exploitation of methane gas (CH4) - biogas - concentrated at the bottom of the mountains of waste from landfill Chapeco for power generation. The landfill receives approximately of 80 tons / day, the vast majority of domestic origin.

2006-07-01

91

35 years of Thermoluminescence Dosimetry (TLD) in personnel and environmental monitoring in India - a tribute to Dr. K G Vohra  

International Nuclear Information System (INIS)

Full text: Thermoluminescence (TL) is a phenomenon of light emission caused by heating a pre-irradiated material. When ionizing radiation hits a TL material, electrons are freed from some atoms and moved in the material, leaving behind 'holes' of positive charge. Subsequently when the TL material is heated, the electrons and the 'holes' re-combine, and release the extra energy in the form of light. The light intensity can be measured, and related to the amount of energy initially absorbed through exposure to the ionizing radiation. In nineteen sixties thermoluminescence dosimeters (TLD) became popular for dosimetric applications in view of their small size, sensitivity and accuracy. Consequently, in early seventies, several countries started adopting of TLD for personnel monitoring. The idea of introducing TLD to replace the then prevalent film dosimeter for personnel monitoring in India was mooted and successfully implemented by Dr. K G Vohra. Limitations of prevalent film dosimeters ...

92

A conceptual design study of superconducting proton linac for Neutron Science Project. 1  

Energy Technology Data Exchange (ETDEWEB)

The Neutron Science Project at Japan Atomic Energy Research Institute has been proposed for the research of nuclear transmutation technology and the basic science with a spallation neutron source. The project calls for an 8MW proton linac which accelerates 5.3mA average current cw and pulsed beams up to 1.5GeV. The superconducting (SC) rf-cavity is the main option for the energy part from 100MeV to 1.5GeV because by using the SC structure, less power is consumed in cw operation than by using a normal conducting (NC) structure. A conceptual design study of the superconducting proton linac is reported. The SC linac is composed of 8 {beta} sections. Each section has the identical 5-cell cavities with the surface peak field of 16MV/m. The total number of cavities is 284, and the length of the SC linac is 690m. The lattice design is determined with the equipartitioned condition and the matched envelope ...

1998-09-01

93

Phase reactions in Ti(C,N)/(Ti,W)C, Ti(C,N)/(Ti,Mo)C, (Ti,W)(C,N)/Co and (Ti,W)(C,N)/Ni diffusion couples  

International Nuclear Information System (INIS)

In order to investigate interactions of (Ti,W)(C,N) and (Ti,Mo)(C,N) with binder metals solid/solid diffusion couples were annealed. These two-dimensional arrangements provide good access to phase reactions occurring upon sintering already in the solid state. It was found in (Ti,W)(C,N)/Co- and (Ti,W)(C,N)/Ni-based couples that the reaction zone is thinner in contact with Co than with Ni. It was also observed that the reaction rate with both Co and Ni is lower if nitrogen is added to the hard phases. Beside a thickness variation of the diffusion zones a change in the microstructure was found. At the interface of nitrogen-free hard phases in contact with Co elongated microstructural constituents are formed with the main axis perpendicular to the interface, while at the interface of nitrogen-containing hard phases these elongated microstructural constituents were found in contact with Ni. Also phase ...

2001-05-01

94

Genome-Wide Transcriptome Profiling of Region-Specific Vulnerability to Oxidative Stress in the Hippocampus  

UK PubMed Central (United Kingdom)

Neurons in the hippocampal CA1 region are particularly sensitive to oxidative stress (OS), whereas those in CA3 are resistant. To uncover mechanisms for selective CA1 vulnerability to OS, we...Full Text Available

2007-08-01

95

Cell proliferation depends on mitochondrial Ca2+ uptake: inhibition by salicylate  

UK PubMed Central (United Kingdom)

Store-operated Ca2+ entry (SOCE) is a ubiquitous Ca2+ influx pathway involved in control of multiple cellular and physiological processes including cell proliferation. Recent evidence...Full Text Available

2006-02-15

96

CaF sub 2 passivation layers for high temperature superconductors  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a method comprising applying a passivation layer of CaF{sub 2} to the surface of a superconductive ceramic oxide by evaporation. The CaF{sub 2} layer is effective to passivate the oxide surface without disrupting the superconductive properties.

1990-10-23

97

Electrochemical behavior of Ti-Cr alloys in artificial saliva  

Energy Technology Data Exchange (ETDEWEB)

In this study, the corrosion behavior of commercially pure titanium (c.p. Ti), Ti-6Al-4V and five new experimental Ti-Cr alloys was evaluated through open-circuit potential (OCP) and potentiodynamic polarization measurement in an artificial saliva containing fluoride. Electron spectroscopy for chemical analysis (ESCA) was used to characterize the composition of the passive films on the alloy after potentiodynamic polarization measurement. It was found that in standard artificial saliva the OCP increases with higher Cr content in Ti-Cr alloys. In 0.5% NaF artificial saliva, the OCP decreases with decreasing Cr in Ti-Cr alloys, and all but Ti-5Cr remain consistently higher than those of c.p Ti and Ti-6Al-4V. Linear polarization results show that artificial saliva and artificial saliva containing 0.5% NaF result in ...

2009-11-13

98

Electrochemical behavior of Ti-Cr alloys in artificial saliva  

International Nuclear Information System (INIS)

In this study, the corrosion behavior of commercially pure titanium (c.p. Ti), Ti-6Al-4V and five new experimental Ti-Cr alloys was evaluated through open-circuit potential (OCP) and potentiodynamic polarization measurement in an artificial saliva containing fluoride. Electron spectroscopy for chemical analysis (ESCA) was used to characterize the composition of the passive films on the alloy after potentiodynamic polarization measurement. It was found that in standard artificial saliva the OCP increases with higher Cr content in Ti-Cr alloys. In 0.5% NaF artificial saliva, the OCP decreases with decreasing Cr in Ti-Cr alloys, and all but Ti-5Cr remain consistently higher than those of c.p Ti and Ti-6Al-4V. Linear polarization results show that artificial saliva and artificial saliva containing 0.5% NaF result in ...

2009-11-13

99

Materials compatibility during the chlorination of molten CaCl/sub 2/. CaO salts. [CaCl/sub 2/. CaO salt  

Energy Technology Data Exchange (ETDEWEB)

As part of our effort to develop a semicontinuous PuO/sub 2/ reduction process, we are investigating promising materials for containing a 900/sup 0/C molten CaCl/sub 2/ . CaO chlorination reaction. We want the material to contain this reaction and to be reusable. We tested candidate materials in a simulated salt (no plutonium) using anhydrous HCl as the chlorinating agent. Data are presented on the performance of 36 metals and alloys, 9 ceramics, and 3 coatings.

1987-01-01

100

Sunlight photocatalytic activity of CdS modified TiO2 loaded on activated carbon fibers  

British Library Electronic Table of Contents (United Kingdom)

To improve the photocatalytic application performances of TiO2, in this work, firstly CdS modified Degussa P25 TiO2 (CdS/TiO2) composites were prepared by two methods, sol-gel method and precipitation method. Next they, sol-gel-CdS/TiO2 (sg-CdS/TiO2) and precipitation-CdS/TiO2 (pp-CdS/TiO2), were loaded on activated carbon fibers (ACFs) by dip-coating method using the sodium carboxymethyl cellulose as adhesives. The composites were characterized by XRD, UV-vis absorbance spectra, SEM, EDS and BET. The photocatalytic activities under sunlight were investigated by the degradation of methylene blue. The results showed that CdS/TiO2 composites were mainly composed of anatase-TiO2 and little CdS cubic phases. The absorption wavelengths of sg-CdS/TiO2 and ...

2010-01-01

101

E 1  

Science.gov (United States)

3l the c I coir is ometimes ca I led "re I I "I angie of the IPP; ii) the cone ( sometimes ca I led "I coir") angle of the {PP . ...

102

DNA Hypermethylation Patterns Detected in Serum as a Tool ...  

Science.gov (United States)

... Grant support: National Cancer Institute Center grant CA 16087 and National Cancer Institute grant CA091892, Department of Defense grant ...

2009-09-01

103

Relations between structural and superconducting properties of bulk and thin film high-T_c materials  

International Nuclear Information System (INIS)

The structural ordering of oxygen deficient and Co-doped YBCO (YBa_2Cu_3_-_yCo_yO_6_+_x) have been studied experimentally, and by computer simulations of the oxygen ordering in the basal plane of the structure. The calculations are based on the two-dimensional ASYNNNI model and its modifications. Good agreement is established between the ASYNNNI calculations and the experimentally observed structural properties of the double cell ortho-II structure and the oxygen disordering process from Co-doping into the basal plane. A model that relates the superconducting transition temperature T_c(x) of undoped YBCO and T_c(y) of Co-doped YBCO to the formation of specific domains of the two orthorhombic ordered oxygen phases, ortho-I and ortho-II, shows a close agreement with experimental T_c(x) and T_c(y) data of samples prepared under equilibrium conditions. The structural changes as a result of metal ion substitutions and oxidation/reduction processes have been studied by neutron powder ...

1984-02-13

104

The effect of heat treatment on the electrochemical corrosion behavior of reactive plasma-sprayed TiN coatings  

British Library Electronic Table of Contents (United Kingdom)

The effect of heat treatment on the corrosion behavior of reactive plasma sprayed TiN coatings in simulated seawater was investigated by electrochemical methods such as the corrosion potential-time curve (Ecorr-t), potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and SEM, etc. The results showed that the corrosion potential of TiN coatings increased after heat treatment; the corrosion current of the TiN coatings after heat treatment (be hereafter referred to as HT-TiN) was 13.3% of the untreated coatings (be hereafter referred to as UT-TiN), and the polarization resistance of HT-TiN was 20 times of UT-TiN, which indicated that the heat treatment had significantly increased the corrosion resistance of the coatings. The corrosion behavior of the coatings was mainly ...

2011-01-01

105

THERMAL STABILITY OF ALPHA-BETA TITANIUM ALLOY Ti ...  

Science.gov (United States)

... Accession Number : ADD109273. Title : THERMAL STABILITY OF ALPHA-BETA TITANIUM ALLOY Ti-5Al-2Cr-1Fe,. Corporate Author : ...

1975-08-01

106

Plasma oxidation for achieving supported TiO2 photocatalysts derived from adsorbed TiCl4 using dielectric barrier discharge  

International Nuclear Information System (INIS)

At atmospheric pressure and room temperature, dielectric barrier discharge induced plasma oxidation for achieving supported TiO2 photocatalysts derived from TiCl4 adsorbed onto ?-Al2O3 pellets was studied. The supported TiO2/?-Al2O3photocatalysts prepared by a cyclic 'adsorption-discharge' approach, without requirement of heat treatment, exhibit high activity in the photocatalytic degradation reaction of formaldehyde. The mass spectra and optical emission spectra during O2/Ar discharge for oxidizing the adsorbed-state TiCl4 were measured. The mechanism for the TiO2 formation from adsorbed-state TiCl4 by plasma oxidation was discussed.

2007-03-21

107

Environmental Cracking of the Alpha-Beta Titanium Alloy, Ti ...  

Science.gov (United States)

... Accession Number : ADD120492. Title : Environmental Cracking of the Alpha-Beta Titanium Alloy, Ti-6Al-6V-2Sn,. Corporate ...

108

Alpha/Beta Heat Treatment of a Titanium Alloy with a Non ...  

Science.gov (United States)

... transformed at 705°C. The cooling rate and temperature dependence of matrix decomposition for Ti6242 was thus similar to that for Ti64 x [9]. ...

2006-08-01

109

Mixed-ligand complexes of scandium with 4-(2-pyridylazo)resorcinol and monocarboxylic acids  

International Nuclear Information System (INIS)

Scandium reacts with 4-(2-pyridylazo)resorcinol in the presence of monocarboxylic acids (X) to form mixed-ligand complexes with a Sc:PAR:x ratio of 1:2:2. The chemical nature of this interaction has been established, and the extraction of these mixed-ligand complexes has also been investigated; stability constants and molar extinction coefficients have been calculated. The values of the latter decrease in the order CH_3COOH > CH_2ClCOOH > CCl_3COOH. The formation and extraction of mixed-ligand complexes in Sc-PAR-HX systems make it possible to increase the sensitivity and selectivity of scandium determination in comparison with the use of the Sc-PAR mono-ligand complex.

1987-09-01

111

Radwaste economics using the RWCOST Program  

International Nuclear Information System (INIS)

(1981). United States Guenther, CF Tosetti, RJ Bechtel, Downey, CA 90241

112

Quality assurance requirements in nuclear systems  

International Nuclear Information System (INIS)

(1974). United States Lingafelter, JW Nuclear Services Corp., Campbell, CA

1974-09-23

114

Determination of the Sr/Ca ratio in bones by XRFA  

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence analysis was used for the determination of Sr/Ca ratio in bones to test the influence of a diet on this ratio. Significant differences were observed for Sr/Ca ratio in bones of various animals. Only small differences in the Ca/Sr ratio were observed for the samples of various prehistoric human bones. (author) 4 refs.; 4 tabs.

1989-11-01

115

Contributions of SERCA pump and ryanodine-sensitive stores to presynaptic residual Ca2+  

UK PubMed Central (United Kingdom)

The presynaptic Ca2+ signal, which triggers vesicle release, disperses to a broadly distributed residual [Ca2+] ([Ca2+]res) that plays an important...Full Text Available

2010-04-01

117

XRF analysis of rock and sediment using standard rock samples  

Energy Technology Data Exchange (ETDEWEB)

A simple and rapid method is described for the determination of major and trace elements in rock and sediment samples by wavelength dispersive XRF. Sample measured were made from cellulose powder pressed into 4 cm diameter aluminium ring 0.4 t cm/sup -2/, and then 1 g of powdered sample (0.08 g cm/sup -2/) was placed on the disk and repressed at 1.6 t cm/sup -2/. X-ray measurements were performed for total XRF intensity (I/sub p/) at the characteristic line of each element and background intensity (I/sub b/) in vicinity of the line. The correction of matrix effect was achieved by X-ray intensity ratio of peak to background for each element. Eight standard rock samples from Geological Survey of Japan were used as standard materials, and linear calibration curves were obtained by the plot of I/sub p/ - I/sub b/ vs. concentration for Ca, Na and Pb and by the plot of I/sub p//I/sub b/ ratio vs. concentration for Si, Fe, Ti, K, P, Cl, Cr, Mn, Ni, ...

1987-03-01

118

XRF analysis of rock and sediment using standard rock samples  

International Nuclear Information System (INIS)

A simple and rapid method is described for the determination of major and trace elements in rock and sediment samples by wavelength dispersive XRF. Sample measured were made from cellulose powder pressed into 4 cm diameter aluminium ring 0.4 t cm"-"2, and then 1 g of powdered sample (0.08 g cm"-"2) was placed on the disk and repressed at 1.6 t cm"-"2. X-ray measurements were performed for total XRF intensity (I_p) at the characteristic line of each element and background intensity (I_b) in vicinity of the line. The correction of matrix effect was achieved by X-ray intensity ratio of peak to background for each element. Eight standard rock samples from Geological Survey of Japan were used as standard materials, and linear calibration curves were obtained by the plot of I_p - I_b vs. concentration for Ca, Na and Pb and by the plot of I_p/I_b ratio vs. concentration for Si, Fe, Ti, K, P, Cl, Cr, Mn, Ni, Cu, Zn, Pb, Sr and Ba, respectively. The ...

119

Preparation and Crystal Structure of the Equiatomic Rare Earth Palladium Silicides NdPdSi, SmPdSi, alpha-GdPdSi, and alpha-TbPdSi  

Science.gov (United States)

The title compounds were prepared by arc-melting of the elemental components. Whereas NdPdSi and SmPdSi are already present after the arc-melting, alpha-GdPdSi and alpha-TbPdSi are formed only during the annealing at 800 degC. The four compounds crystallize with the recently reported alpha-YbAuGe type structure, which was refined for alpha-GdPdSi: Pnma, a=2108.0(4) pm, b=433.9(1) pm, c=745.6(1) pm, Z=12, R=0.026 for 1447 structure factors and 62 variable parameters. The lanthanoid atoms are situated between two-dimensionally infinite nets of condensed, puckered hexagons formed by alternating palladium and silicon atoms, with Pd-Si distances varying between 251 and 262 pm. In the third dimension these nets are linked via weak Pd-Pd (300 pm), Pd-Si (283 pm), and Si-Si bonds (261 pm). The refinements of the occupancy parameters suggested that ca. 2% of the palladium sites are occupied by silicon atoms and vice versa. The structural relationships between the two ...

1999-01-01

120

Fate of corrosion products released from stainless steel in marine sediments and seawater. Part 3. Calcareous ooze  

International Nuclear Information System (INIS)

The physicochemical forms and partitioning of corrosion products released from stainless steel upon exposure to selected environmental conditions is the subject of this investigation. This report describes the influence of calcareous sediment on the rate of release and fate of corrosion products produced when neutron-activated stainless steel specimens were exposed to a Globigerina ooze taken from the Northeast Pacific Ocean. The calcareous ooze used in this study consists largely of planktonic formanifera tests and was found to be about 90% CaCO_3. The trace metal content of this sediment was typical of average deep-sea carbonate sediments, and the ratios of trace elements to Ti were not remarkably different from a coastal clayey silt or a Northeast Pacific pelagic red clay. Most (>80%) of the trace metals extracted by sequential chemical treatment were associated with reductant-soluble materials, i.e., amorphous Mn and Fe oxides, or were ...

121

Characterization of trace elements and radionuclides and their risk assessment in red mud  

International Nuclear Information System (INIS)

Red mud is a waste and tail material from primary aluminum production, and is named for its color, coming from its iron oxide content. The quantity of red mud is almost equal to the primary aluminum production and leads to a considerable environmental issue. Red mud of the ETI Seydisehir Aluminum Plant is considered as detrimental waste for storage due to its content of various metal oxides, elements and caustics. This detrimental effect is classified into two groups: first, environmental health and second, the cost of storage. In order to minimize the negative effect of red mud, there have been or are presently many investigations carried out on usage of red mud in building materials. However, no effective way of utilizing red mud has yet been found. In this study domestic red mud was investigated and chemical analyses were performed by EDAX and XRF techniques. Radioactivity of the samples was also measured with gamma spectroscopy. The concentrations of elemental Na, Al, Si, ...

2008-04-01

122

A PIXE/PIGE study of gold mineralisation in lateritic terrain, Tanami Desert, Australia  

Energy Technology Data Exchange (ETDEWEB)

Proton induced X-ray and {gamma}-ray emission (PIXE/PIGE) have been used to analyze major and trace elements in a suite of 140 core samples from around of the Jim`s Find South gold anomaly in the Tanami desert, located in heavily weathered terrain. Simultaneous analyses were obtained for 30 elements, ranging in atomic number from {sup 3}Li to {sup 90}Th. The method was chosen because of its speed and the wide range of determination, its flexibility, precision and low detection limits. The regolith powder samples were treated by hot aqua regia before making them into pills. The PIXE/PIGE data of the acid insoluble residue give three factor analysis clusters. The first cluster comprises the elements F, Al, K, V, Mn, Fe, Ga, Rb, W and Au and is essentially related to sericitic wallrock alteration. The second cluster consists of Ti, As, Y, Zr, and Nb and is largely related to resistant minerals. The third cluster consists of Na, Ca and Sr and is ...

1997-12-31

123

Depression of calcium pump activity in renal cortex of vitamin D-deficient rats with secondary hyperparathyroidism  

Energy Technology Data Exchange (ETDEWEB)

To examine the hormonal regulation of the ATP-dependent Ca{sup 2+} pump in the kidneys, the ATP-dependent Ca{sup 2+} uptake by the basolateral membrane vesicles in the renal cortex was measured using radioactive calcium ({sup 45}Ca{sup 2+}) in rats with vitamin D deficiency or rats undergoing thyroparathyroidectomy. The V{sub max} of the Ca{sup 2+} pump activity was increased not only by administering calcitriol, but also by normalizing the serum calcium level in vitamin D-deficient rats. PTH suppressed the Ca{sup 2+} pump activity in normocalcemic vitamin D-deficient rats. Thyroparathyroidectomy did not affect the Ca{sup 2+} pump activity in the kidneys of normal rats. It was concluded that the ATP-dependent Ca{sup 2+} pump activity was depressed by secondary hyperparathyroidism in vitamin D-deficient rats. (author).

1990-01-01

124

Depression of calcium pump activity in renal cortex of vitamin D-deficient rats with secondary hyperparathyroidism  

International Nuclear Information System (INIS)

To examine the hormonal regulation of the ATP-dependent Ca"2"+ pump in the kidneys, the ATP-dependent Ca"2"+ uptake by the basolateral membrane vesicles in the renal cortex was measured using radioactive calcium ("4"5Ca"2"+) in rats with vitamin D deficiency or rats undergoing thyroparathyroidectomy. The V_m_a_x of the Ca"2"+ pump activity was increased not only by administering calcitriol, but also by normalizing the serum calcium level in vitamin D-deficient rats. PTH suppressed the Ca"2"+ pump activity in normocalcemic vitamin D-deficient rats. Thyroparathyroidectomy did not affect the Ca"2"+ pump activity in the kidneys of normal rats. It was concluded that the ATP-dependent Ca"2"+ pump activity was depressed by secondary hyperparathyroidism in vitamin D-deficient rats. (author).

125

Virtual adult ears reveal the roles of acoustical factors and experience in auditory space map development  

UK PubMed Central (United Kingdom)

Auditory neurons in the superior colliculus (SC) respond preferentially to sounds from restricted directions to form a map of auditory space. The development of this representation is shaped...Full Text Available

2008-11-05

126

Local design specifications for the CCN security controller (SC)  

Energy Technology Data Exchange (ETDEWEB)

This is a description of the preliminary local design specifications of the Central Computing Network Security Controller. The external interface to the Central Computing Network is not described, but the functions and services to be provided are included as justification for the local design.

1981-04-01

127

INVESTIGATION OF GLASS-METAL COMPOSITE ...  

Science.gov (United States)

... having high fluidity. The SC-51A alloy contains 4.5 to 5.5% silicon, 1 to 1.5% coppers .4 to .6% magnesium, o35% sine, .8% iron, .5% manganes*, ...

1957-09-01

128

A New Suchian Archosaur From The Upper Triassic Of North Carolina  

Science.gov (United States)

... rugose ridge along dorsolateral edge of skull; s, scapula; sc, supinator crest; sls, surface for articulation with ... robust supraglenoid buttress of the scapulocoracoid; immediately narrowing scapula po...

129

Macroscopic consequences of calcium signaling in microdomains: A first passage time approach  

CERN Document Server

Calcium (Ca) plays an important role in regulating various cellular processes. In a variety of cell types, Ca signaling occurs within microdomains where channels deliver localized pulses of Ca which activate a nearby collection of Ca-sensitive receptors. The small number of channels involved ensures that the signaling process is stochastic. The aggregate response of several thousand of these microdomains yields a whole-cell response which dictates the cell behavior. Here, we study analytically the statistical properties of a population of these microdomains in response to a trigger signal. We apply these results to understand the relationship between Ca influx and Ca release in cardiac cells. In this context, we use a first passage time approach to show analytically how Ca release in the whole cell depends on the single channel kinetics of ...

2007-01-01

130

Inhibition of calmodulin - regulated calcium pump activity in rat brain by toxaphene  

Energy Technology Data Exchange (ETDEWEB)

In vivo effects of toxaphene on calcium pump activity in rat brain synaptosomes was studied. Male Sprague-Dawley rats were dosed with toxaphene at 0,25,50, and 100 mg/kg/day for 3 days and sacrificed 24 h after last dose. Ca/sup 2 +/-ATPase activity and /sup 45/Ca uptake were determined in brain P/sub 2/ fraction. Toxaphene inhibited both Ca/sup 2 +/-ATPase activity and /sup 45/Ca/sup 2 +/ uptake and the inhibition was dose dependent. Both substrate and Ca/sup 2 +/ activation kinetics of Ca/sup 2 +/-ATPase indicated non-competitive type of inhibition as evidenced by decreased catalytic velocity but not enzyme-substrate affinity. The inhibited Ca/sup 2 +/-ATPase activity and Ca/sup 2 +/ uptake were restored to normal level by exogenously added calmodulin which increased both velocity and affinity. The inhibition of ...

1986-03-05

131

Inhibition of calmodulin - regulated calcium pump activity in rat brain by toxaphene  

International Nuclear Information System (INIS)

In vivo effects of toxaphene on calcium pump activity in rat brain synaptosomes was studied. Male Sprague-Dawley rats were dosed with toxaphene at 0,25,50, and 100 mg/kg/day for 3 days and sacrificed 24 h after last dose. Ca"2"+-ATPase activity and "4"5Ca uptake were determined in brain P_2 fraction. Toxaphene inhibited both Ca"2"+-ATPase activity and "4"5Ca"2"+ uptake and the inhibition was dose dependent. Both substrate and Ca"2"+ activation kinetics of Ca"2"+-ATPase indicated non-competitive type of inhibition as evidenced by decreased catalytic velocity but not enzyme-substrate affinity. The inhibited Ca"2"+-ATPase activity and Ca"2"+ uptake were restored to normal level by exogenously added calmodulin which increased both velocity and affinity. The inhibition of Ca"2"+-ATPase activity and ...

1986-04-13

132

Changes in intracellular Ca2+ levels induced by cytokines and P2 agonists differentially modulate proliferation or commitment with macrophage differentiation in murine hematopoietic cells.  

Science.gov (United States)

The role of intracellular Ca2+ (Ca2+i) on hematopoiesis was investigated in long term bone marrow cultures using cytokines and agonists of P2 receptors. Cytokines interleukin 3 and granulocyte/macrophage colony stimulator factor promoted a modest increase in Ca2+i concentration ([Ca2+]i) with activation of phospholipase Cgamma, MEK1/2, and Ca2+/calmodulin kinase II. Involvement of protein kinase C was restricted to stimulation with interleukin 3. In addition, these cytokines promoted proliferation (20 times) and an increase in the Gr-1(-)Mac-1+ population with participation of gap junctions (GJ). Nevertheless ATP, ADP, and UTP promoted a large increase in [Ca2+]i, moderate proliferation (6 times), a reduction in the primitive Gr-1(-)Mac-1(-)c-Kit+ population, and differentiation into macrophages without participation of GJ. It is likely that ...

2008-09-05

133

Calmodulin Kinase II Interacts with the Dopamine Transporter C Terminus to Regulate Amphetamine-Induced Reverse Transport  

DEFF Research Database (Denmark)

Efflux of dopamine through the dopamine transporter (DAT) is critical for the psychostimulatory properties of amphetamines, but the underlying mechanism is unclear. Here we show that Ca(2+)/calmodulin-dependent protein kinase II (CaMKII) plays a key role in this efflux. CaMKIIalpha bound to the distal C terminus of DAT and colocalized with DAT in dopaminergic neurons. CaMKIIalpha stimulated dopamine efflux via DAT in response to amphetamine in heterologous cells and in dopaminergic neurons. CaMKIIalpha phosphorylated serines in the distal N terminus of DAT in vitro, and mutation of these serines eliminated the stimulatory effects of CaMKIIalpha. A mutation of the DAT C terminus impairing CaMKIIalpha binding also impaired amphetamine-induced dopamine efflux. An in vivo role for CaMKII was supported by chronoamperometry ...

2006-01-01

141

High resolution transmission electron microscopy of a #beta#'-sialon-TiN nanocomposite  

International Nuclear Information System (INIS)

TEM and HRTEM have been used to characterise the microstructures of materials formed by hot-pressing silicon nitride with an Al_2O_3-SiO_2-TiO_2 densification aid system, to form #beta#'-sialon-TiN composites in which the TiN particles are of 20-100 nm dimension. (orig.).

1992-06-21

142

Fabrication of nanoscale Ti honeycombs by focused ion beam  

Energy Technology Data Exchange (ETDEWEB)

Ti honeycombs with the side of 800 and 400 nm were fabricated by focused ion beam (FIB), though the surfaces of the bottom and wall of the Ti honeycombs were rough, as compared with the surfaces of the bottom and wall of the Si honeycomb. It is demonstrated that the nanoscale Ti components can be fabricated in a short time by FIB.

2003-03-15

143

EFFECT OF MICROSTRUCTURE ON THE STRENGTH ...  

Science.gov (United States)

... THE STRENGTH, TOUGHNESS, AND STRESS-CORROSION CRACKING SUSCEPTIBILITY OF A METASTABLE BETA TITANIUM ALLOY (Ti-11. ...

1970-02-01

144

Study on reactor building structures using ultrahigh strength materials - Part 8: Results of mixed structure tests  

International Nuclear Information System (INIS)

The mixed structure of a nuclear reactor building is composed of SC-columns, S-beams, S-joints and PCa-panels. Following the last report (Part 7)[1], the main test results of the mixed structure, that is, the deformation mode, strain distribution and shear strength, are described. The S-joints using ultrahigh strength materials had no buckling nor shear slipping. The proposed mixed structure resisted the external horizontal forces under integrated uniformity among SC-columns, S-joints and PCa-panels. It could be confirmed that the mixed structure can be established. (author)

1993-08-15

145

Low cycle fatigue behaviour of a 4th generation Ni-base single-crystal superalloy TMS-138  

Energy Technology Data Exchange (ETDEWEB)

Low cycle fatigue (LCF) of a fourth-generation single-crystal (SC) Ni-base superalloy TMS-138 was studied by comparison with a typical third-generation (TMS-75) and a second-generation (CMSX-4) Ni-base SC superalloys. TMS-138 exhibits improved LCF behaviour under a condition of the R ratio of 0 at temperatures of 1073 K and 1173 K. The addition of refractory elements resulted in a remarkable improvement of the LCF properties compared to those of the reference superalloys due to the different microstructure developed in TMS-138. (orig.)

2004-07-01

146

Effect of intense plastic straining on microstructure and mechanical properties of an Al-Mg-Sc alloy  

International Nuclear Information System (INIS)

An Al-5%Mg-0.18%Mn-0.2%Sc-0.08%Zr-0.002%Be was subjected to equal-channel angular extrusion up to true strains of #approx#3 and #approx#8, that resulted in the formation of partially recrystallized and fully recrystallized structure, respectively. It was shown that the alloy with partially recrystallized structure exhibits highest strength and ductility. The material with fully recrystallized structure showed lowest fatigue crack growth rate and highest value of fracture toughness. Reasons of this unusual effect of microstructure on crack propagation resistance under fatigue are discussed.

2010-07-01

147

Dielectric properties of solid solutions on the base of PbSc_1_/_2Sb_1_/_2O_3 antiferroelectric material  

International Nuclear Information System (INIS)

The results of dielectric measurements in a wide frequency range have been used to find that solid solution samples on the basis of PbSc_1_/_2Sb_1_/_2O_3 have blurred phase transitions. The Curie-Weiss law is performed for different compositions in the temperature range 10-150 K above Curie point. The change of value and sign of the difference between Curie and Curie-Weiss temperatures is connected with the change of phase transition blurring degree.

1988-01-01

148

Corrosion resistance of #gamma#-solid solution and hardening #gamma#'-phase of nickel alloys in sodium sulfate and chloride melts  

International Nuclear Information System (INIS)

Corrosion testings of model alloys, corresponding by chemical composition to simple and complex-alloyed #gamma#- and #gamma#'-phases of nickel heat-resistant alloys are conducted in sodium sulfate and chloride melts. It is ascertained that heat resistant nickel alloys containing over 50 % of hardening #gamma#'-phase, are subject to disastrous sulfide corrosion (SC). Resistance against SC alloys containing below 50 % of #gamma#'-phase is determined by the resistance of #gamma#-solid solution. 10 refs., 3 figs., 2 tabs.

149

ZZ DECAYREM/C, Decay Spectra Library for EXREM Calculation  

International Nuclear Information System (INIS)

Description of problem or function: Format: EXREM III; Nuclides: radioactive decay data on 252 Nuclides: 1H-3, 4Be-7, 6C-11, 6C-14, 7N-13, 8O-15, 9F-18, 11Na-22, 11Na-24, 12Mg-28, 13Al-28, 15P-32, 15P-33, 16S-35, 17Cl-36, 17Cl-38, 18A-37, 18A-39, 19K-40, 19K-42, 19K-43, 20Ca-45, 20Ca-47, 20Ca-49, 21Sc-46, 21Sc-47, 21Sc-49, 24Cr-51, 25Mn-52M, 25Mn-52, 25Mn-54, 26Fe-52, 26Fe-55, 26Fe-59, 27Co-56, 27Co-57, 27Co-58, 27Co-60, 28Ni-56, 28Ni-63, 29Cu-64, 30Zn-65, 30Zn-69M, 30Zn-69, 31Ga-67, 31Ga-68, 32Ge-77, 33As-76, 33As-77, 34Se-75, 35Br-80M, 35Br-80, 35Br-82, 35Br-83, 35Br-84, 36Kr-79, 36Kr-83M, 36Kr-85M, 36Kr-85, 36Kr-87, 36Kr-88, 37Rb-84, 37Rb-86, 37Rb-87, 37Rb-88, 37Rb-89, 37Rb-90M, 37Rb-90, 38Sr-85, 38Sr-87M, 38Sr-89, 38Sr-90, 38Sr-91, 38Sr-92, 38Sr-93, 39Y-87, 39Y-88, 39Y-90, 39Y-91M, 39Y-91, 39Y-92, 39Y-93, 40Zr-93, 41Nb-93M, 40Zr-95, 40Zr-97, 41Nb-95M, ...

150

Nucleon momentum distributions of 39(K), 40(Ca) and 48(Ca)  

Energy Technology Data Exchange (ETDEWEB)

The proton momentum distributions of (39)K,(40)Ca and (48)Ca are calculated from the model-independent charge distributions obtained from analyses of electron elastic scattering and muonic atoms, and also from the charge distributions calculated from the single-particle potential method in the framework of the flucton model. The sensitivities of the momentum distribution to different regions of the charge distribution are determined. The analysis is extended to the neutron distributions using the single-particle potential method, and the differences between the proton and neutron momentum distributions are examined. The resulting momentum distribution in the case of (40)Ca is used for analyzing the quasielastic electron scattering.

1983-01-01

151

Photocatalytic oxidation of toluene to benzaldehyde over anatase TiO2 hollow spheres with exposed {001} facets  

British Library Electronic Table of Contents (United Kingdom)

A new series of anatase TiO2 hollow structures were prepared by a facile hydrothermal process. When the hydrothermal time was increased from 20min to 72h, the resulting TiO2 solid spheres gradually transformed into TiO2 hollow spheres with higher surface crystallinity and exposed {001} facets. The as-prepared TiO2-72h sample exhibited the highest activity comparing to other TiO2-based samples and commercial product Degussa P-25 towards the selective photocatalytic oxidation of toluene to benzaldehyde. Such great photocatalytic performance was mainly attributed to enhanced UV-adsorption and better charge separation efficiency due to higher surface crystallinity of TiO2-72h.

2011-01-01

152

Influence of Si on the microstructure of reactive sintered TiAl  

Energy Technology Data Exchange (ETDEWEB)

TiAl with between 0 and 20 volume percent (v%)Ti5Si3 was produced by reactive sintering of cold pressed compacts of elemental Ti, Al and Si powder mixtures at 700C for 15 minutes in vacuum. The results show that adding Si to Ti and Al reduces the swelling associated with reactive sintering of TiAl, as composites containing more than 5 v%Ti5Si3 densified during reactive sintering. However, composites containing more than 10v% Ti5Si3 did not retain their shape during processing, and the TiAl+20v% Ti5Si3 composite completely melted during the sintering process. The formation of pre-reaction liquid phase and the increase in adiabatic flame temperature with simultaneous compound formation resulted in the melting that occurred and the enhanced densification (minimization of swelling) during reactive ...

2005-02-01

153

Multiscale modeling of transdermal drug delivery  

Science.gov (United States)

This study addresses the modeling of transdermal diffusion of drugs, to better understand the permeation of molecules through the skin, and especially the stratum corneum, which forms the main permeation barrier of the skin. In transdermal delivery of systemic drugs, the drugs diffuse from a patch placed on the skin through the epidermis to the underlying blood vessels. The epidermis is the outermost layer of the skin and can be further divided into the stratum corneum (SC) and the viable epidermis layers. The SC consists of keratinous cells (corneocytes) embedded in the lipid multi-bilayers of the intercellular space. It is widely accepted that the barrier properties of the skin mostly arises from the ordered structure of the lipid bilayers. The diffusion path, at least for lipophilic molecules, seems to be mainly through the lipid bilayers. Despite the advantages of transdermal drug delivery compared to other drug delivery routes such as oral ...

2006-01-01

154

Investigation of (CeO_2)_x(Sc_2O_3)_(_0_._1_1_-_x_)(ZrO_2)_0_._8_9 (x = 0.01-0.10) electrolyte materials for intermediate-temperature solid oxide fuel cell  

International Nuclear Information System (INIS)

Oxide ionic conductivities of (CeO_2)_x(Sc_2O_3)_(_0_._1_1_-_x_)(ZrO_2)_0_._8_9 (x = 0.01-0.10) electrolytes were optimized for the application in intermediate-temperature solid oxide fuel cell (IT-SOFC). Powders with different contents of CeO_2 and Sc_2O_3 were prepared via a co-precipitation method. The obtained powders and pellets were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and impedance spectroscopy. Among all the compositions, (CeO_2)_0_._0_4(Sc_2O_3)_0_._0_7(ZrO_2)_0_._8_9(4Ce7ScZr) gives the highest ionic conductivity of 0.065 S cm"-"1 at 800 "oC. The effects on densification and electrical properties of different sintering additives, such as SiO_2, MgO, Co_3O_4, MoO_3 and Bi_2O_3, were studied and different conducting behavior with these additives were observed. The densification temperatures of CeO_2 and ...

2010-07-23

155

Comparison of sclerosing cholangitis with autoimmune pancreatitis and infiltrative extrahepatic cholangiocarcinoma. Multidetector-row computed tomography findings  

International Nuclear Information System (INIS)

The aim of this study was to compare multidetector-row computed tomography (MDCT) findings between cases of sclerosing cholangitis with autoimmune pancreatitis (SC-AIP) and infiltrative extrahepatic cholangiocarcinoma (IEC). We retrospectively assessed MDCT findings from 16 IEC cases and 13 SC-AIP cases. MDCT findings were analyzed with regard to location, length, wall thickness, contour, stricture wall enhancement pattern, proximal duct diameter, and the presence of diffuse concentric thickening in the proximal duct and gallbladder wall thickness. Stricture length, stricture wall thickness, and proximal duct diameter were significantly smaller for SC-AIP than for IEC: 19.3#+-#8.7 vs. 31.8#+-#12.0 mm (P=0.004), 2.1#+-#1.3 vs. 4.1#+-#1.3 mm (P<0.001), and 9.2#+-#3.9 vs. 13.3#+-#5.0 mm (P=0.012), respectively. SC-AIP was correlated with stricture location in both the intrapancreatic and hilar hepatic ...

2010-04-01

156

High extracellular calcium attenuates adipogenesis in 3T3-L1 preadipocytes  

International Nuclear Information System (INIS)

We studied the effect of extracellular Ca"2"+ concentration ([Ca"2"+]_e) on adipocyte differentiation. Preadipocytes exposed to continuous [Ca"2"+]_e higher than 2.5 mmol/l accumulated little or no cytoplasmic lipid compared to controls in 1.8 mmol/l [Ca"2"+]_e. Differentiation was monitored by Oil Red O staining of cytoplasmic lipid and triglyceride assay of accumulated lipid, by RT-PCR analysis of adipogenic markers, and by the activity of glycerol-3-phosphate dehydrogenase (GPDH). Elevated [Ca"2"+]_e inhibited expression of peroxisome proliferator-activated receptor #gamma#, CCAAT/enhancer binding protein #alpha#, and steroid regulatory binding element protein. High [Ca"2"+]_e significantly inhibited differentiation marker expression including adipocyte fatty acid binding protein, and GPDH. The decrease in Pref-1 expression that accompanied differentiation ...

2004-12-10

157

Wear resistant composite coatings deposited by electron enhanced closed field unbalanced magnetron sputtering  

Energy Technology Data Exchange (ETDEWEB)

There is presently considerable interest in wear resistant coatings produced using closed field unbalanced magnetron sputtering technology. For example, layered films of diamond-like carbon (DLC) with tungsten or titanium additions have been widely reported. The benefit is that the mechanical properties are enhanced (e.g. giving greater toughness); also it is possible to control the stress state and enhance adhesion. Here we report the further development of this concept by the addition of TiN, TiCN and TiC layers in DLC-based composites, utilizing an additional source of electrons in the vicinity of substrate to enhance ionisation of the plasma and increase coating density. Composite coatings of ceramics TiN, TiC{sub x}N{sub y}, TiC, CrN, TiCrN, TiCrCN, TiCrC, metal doped Ti{sub ...

1995-08-01

158

Photocatalytic degradation of gaseous benzene over TiO{sub 2}/Sr{sub 2}CeO{sub 4}: Preparation and photocatalytic behavior of TiO{sub 2}/Sr{sub 2}CeO{sub 4}  

Energy Technology Data Exchange (ETDEWEB)

The paper demonstrates that the photocatalytic activity of TiO{sub 2} towards the decomposition of gaseous benzene in a batch reactor can be greatly improved by loading TiO{sub 2} on the surface of Sr{sub 2}CeO{sub 4}. The research investigates the optimum loading amount of TiO{sub 2} on Sr{sub 2}CeO{sub 4} in enhancing the photocatalytic activity of TiO{sub 2}. The prepared photocatalyst was characterized by XRD, UV-vis diffuse reflectance and XPS analyses. TiO{sub 2} is loaded on Sr{sub 2}CeO{sub 4} at 773 K. TiO{sub 2}/Sr{sub 2}CeO{sub 4} absorbs much more visible light than TiO{sub 2}. The XPS spectrum shows that there are Ti, O, C, Sr elements on the surface of the TiO{sub 2}/Sr{sub 2}CeO{sub 4}, and that the binding energy value of Ti2p transfers to a lower value. ...

2007-02-09

159

Increased intracellular calcium concentration causes electrical turbulence in guinea pig ventricular myocytes  

British Library Electronic Table of Contents (United Kingdom)

Dysregulation of intracellular Ca2+ homeostasis is associated with various pathological conditions and arrhythmogenesis of the heart. The objective of this study was to investigate the effects of an acute increase in intracellular Ca2+ concentration ([Ca2+]i) on the electrophysiology of ventricular myocytes by mimicking intracellular Ca2+ overload. The [Ca2+]i was clamped to either a controlled (65?100 nmol L?1) or increased (1 ?mol L?1) level. The transmembrane action potentials and ionic currents were recorded using whole-cell patch clamp techniques. We found that the acute increase in [Ca2+]i shortened the action potential duration, reduced the action potential amplitude, maximum depolarization velocity and resting membrane potential, caused delayed after-depolarizations (DADs), and tri...

2011-01-01

160

Synthesis and electrorheological characteristics of sea urchin-like TiO2 hollow spheres  

British Library Electronic Table of Contents (United Kingdom)

TiO2 hollow microspheres with sea urchin-like hierarchical architectures were synthesized by a simple hydrothermal method. The as-synthesized hollow microspheres with hierarchical architectures consisting of many rhombic building units exhibit high specific surface area. Electrorheological (ER) properties of hierarchical hollow TiO2-based suspension were investigated under steady and oscillatory shear. The hollow TiO2-based suspensions show much higher yield stress and elasticity than pure TiO2 suspension at the same electric field strength. This phenomenon was elucidated well in view of their dielectric spectra analysis. The sea urchin-like architectures result in stronger interfacial polarization of hollow TiO2 suspension upon an electric field, showing higher ER activity. Also, hollow i...

2011-01-01

161

Particulate composites in the TiC-TiYTZP system  

International Nuclear Information System (INIS)

Twelve powders of TiO_2-Y_2O_3-ZrO_2 solid solution of the methodically changed composition were prepared by a coprecipitation-calcination technique. After mixing with phenol-formaldehyde resin, the powders were calcinated for 2 hours at 1200"oC in vacuum. The resultant composite powders contained TiC and non-reacted carbon. Green compacts were sintered in vacuum at 1500"oC for 2 hours. A temperature increase was stopped at 1200"oC to react remains of carbon. There were two carbides in the composites TiC and ZrC. TiC non-stoichiometry depended on carbon content in the system. Phase composition of the depended on of titania and yttria in zirconia solid solution. The majority of the samples showed two tetragonal zirconia phases differing in lattice parameter and tetragonality. (author)

2004-09-12

162

Non-Aqueous Preparation of High-Crystallinity Hierarchical TiO2 Hollow Spheres with Excellent Photocatalytic Efficiency  

British Library Electronic Table of Contents (United Kingdom)

Abstract High-crystallinity hierarchical anatase TiO2 hollow spheres were prepared by a high-temperature (350 C) and non-aqueous solvothermal method in the absence of water, templates, or additives. The hollow structures were assembled from highly crystallized TiO2 nanoparticles and exhibit superior photocatalytic properties relative to those of Degussa P25 TiO2 under irradiation with UV light. The influence of reaction temperature on the crystallinity, morphology, crystallite shape and size, band gap, specific surface area, and pore size distribution of TiO2 has been studied in detail. It is evident that reaction temperature is the most important factor to increase the crystallinity of TiO2 in order to improve its charge transfer and transport properties, which are important in photocatal...

2011-01-01

163

Mechanical properties of B-modified Ti-6Al-4V alloys  

International Nuclear Information System (INIS)

Minor addition of B to the Ti-6Al-4V alloy reduces the prior #beta# grain size by more than an order of magnitude. TiB formed in-situ in the process has been noted to decorate the grain boundaries. This microstructural modification influences the mechanical behavior of the Ti-6Al-4V alloy significantly. In this paper, an overview of our current research on tensile properties, fracture toughness as well as notched and un-notched fatigue properties of Ti-6Al-4V-xB with x varying between 0.0 to 0.55 wt.% is presented. A quantitative relationship between the microstructural length scales and the various mechanical properties have been developed. Moreover, the effect of the presence of hard and brittle TiB has also been studied.

2010-07-01

164

Bonding and microstructural stability in Ni55Ti45 studied by experimental and theoretical methods  

Energy Technology Data Exchange (ETDEWEB)

Spiral orbit tribometry friction tests performed on Ni-rich Ni55Ti45 titanium ball bearings indicate that this alloy is a promising candidate for future aerospace bearing applications. Microstructural characterization of the bearing specimens was performed using transmission electron microscopy and energy dispersive spectroscopy, with NiTi, Ni4Ti3, Ni3Ti, and Ni2Ti4Ox phases identified within the microstructure of the alloy. Density functional theory was applied to predict the electronic structure of the NixTiy phases, including the band structure and site projected density of states. Ultraviolet photoemission spectroscopy was used to verify the density of states results from the density functional theory calculations, with good agreement observed between experiment and theory.

2010-11-25

165

An X-ray photoelectron spectroscopic study of B-N-Ti system  

International Nuclear Information System (INIS)

Composite nitrides (such as BN, TiN) are widely used in various industrial applications because of their extreme wear and corrosion resistance, thermal and electrical properties. in order to obtain composite materials with these optimal properties, it is important to elucidate whether any chemical reactions occur at nitride/metal interfaces, e.g., those involving BN-Ti/TiN. Materials of interest include the deposition by PVD of Ti and TiN on BN substrates. Some of these systems were then subjected to varying degrees of physical and thermal alteration. Detailed X-ray photoelectron spectroscopy (XPS) has therefore been rendered of these interfaces using cross-sectional display and sputter etching. Resulting structural and morphological features have been investigated with transmission electron microscopy (TEM) and X-ray diffraction (XRD). Diffusion of the nitridation, oxynitride formation and interfacial ...

1997-04-04

166

[caCORE: core architecture of bioinformation on cancer research in America].  

Science.gov (United States)

A critical factor in the advancement of biomedical research is the ease with which data can be integrated, redistributed and analyzed both within and across domains. This paper summarizes the Biomedical Information Core Infrastructure built by National Cancer Institute Center for Bioinformatics in America (NCICB). The main product from the Core Infrastructure is caCORE--cancer Common Ontologic Reference Environment, which is the infrastructure backbone supporting data management and application development at NCICB. The paper explains the structure and function of caCORE: (1) Enterprise Vocabulary Services (EVS). They provide controlled vocabulary, dictionary and thesaurus services, and EVS produces the NCI Thesaurus and the NCI Metathesaurus; (2) The Cancer Data Standards Repository (caDSR). It provides a metadata registry for common data elements. (3) Cancer Bioinformatics Infrastructure Objects ...

2006-04-18

167

Metal contacts to n-GaN  

International Nuclear Information System (INIS)

Al, Au, Ti/Al and Ti/Au contacts were prepared on n-GaN and annealed up to 900 deg. C. The structure, phase and morphology were studied by cross-sectional transmission and scanning electron microscopy as well as by X-ray diffraction (XRD), the electrical behaviour by current-voltage measurements. It was obtained that annealing resulted in interdiffusion, lateral diffusion along the surface, alloying and bowling up of the metal layers. The current-voltage characteristics of as-deposited Al and Ti/Al contacts were linear, while the Au and Ti/Au contacts exhibited rectifying behaviour. Except the Ti/Au contact which became linear, the contacts degraded during heat treatment at 900 deg. C. The surface of Au and Ti/Au contacts annealed at 900 deg. C have shown fractal-like structures revealed by scanning electron microscopy. Transmission electron microscopy and XRD ...

2006-11-15

168

Single crystal growth of lithium ion conductive phosphates  

Energy Technology Data Exchange (ETDEWEB)

Single crystals of Li{sub 1.8}(In{sub 0.55}Zr{sub 0.45}){sub 2}(PO{sub 4}){sub 3} and Li{sub 3}(In{sub 1-x}Sc{sub x}){sub 2}(PO{sub 4}){sub 3} (x=0.67,0.73) were grown by a flux method. The crystal structure of Li{sub 1.8}(In{sub 0.55}Zr{sub 0.45}){sub 2}(PO{sub 4}){sub 3} was found to be similar to that of the high temperature {gamma}-phase of Li{sub 3}Sc{sub 2}(PO{sub 4}){sub 3}. However, Li ions were located on only one site among three available sites. On the other hand, those of Li{sub 3}In{sub 2}(PO{sub 4}){sub 3}-Li{sub 3}Sc{sub 2}(PO{sub 4}){sub 3} solid solutions were found to be similar to that of the low temperature {alpha}-phase of Li{sub 3}Sc{sub 2}(PO{sub 4}){sub 3}. The ionic conductivity of Li{sub 1.8}(In{sub 0.55}Sc{sub 0.45}){sub 2}(PO{sub 4}){sub 3} was measured along with the directions perpendicular and parallel to the a-axis. A relatively large anisotropic ...

2000-07-01

169

Luminescence Properties of ScPO{sub 4} Single Crystals  

Energy Technology Data Exchange (ETDEWEB)

Flux-grown ScPO{sub 4} single crystals exhibit a number of luminescence bands in their x-ray-excited luminescence spectra - including sharp lines arising from rare-earth elements plus a number of broad bands at 5.6 cV, 4.4 eV, and 3 eV. The band at 5.6 eV was attributed to a self-trapped exciton (STE) [l], and it could be excited at 7 eV and higher energies. This luminescence is strongly polarized (P = 70 %) along the optical axes of the crystal and exhibits a kinetic decay time constant that varies from several ns at room temperature to {approximately}10 {micro}s at 60 K and up to {approximately}1 ms at 10 K. It is assumed that the STE is localized on the SC ions. The band at 3 eV can be excited in the range of the ScPO{sub 4} crystal transparency (decay time = 3 to 4 {micro}s.) This band is attributed to a lead impurity that creates different luminescence centers. At high temperatures, the band at 4.4 eV is dominant in ...

1999-08-16

170

Regulation of Calcium Influx in Chara1  

UK PubMed Central (United Kingdom)

Measurements were made of 45Ca influx into isolated internodal cells of Chara corallina and also into internodal cells of intact plants. 45Ca influx was closely...Full Text Available

1992-10-01

171

Phytostabilization of a metal contaminated sandy soil. II: Influence of compost and/or inorganic metal immobilizing soil amendments on metal leaching  

International Nuclear Information System (INIS)

A lysimeter approach (under natural climatologic conditions) was used to evaluate the effect of four metal immobilizing soil treatments [compost (C), compost + cyclonic ashes (C + CA), compost + cyclonic ashes + steel shots (C + CA + SS)) and cyclonic ashes + steel shots (CA + SS)] on metal leaching through an industrially contaminated soil. All treatments decreased Zn and Cd leaching. Strongest reductions occurred after CA + SS and C + CA + SS treatments (Zn: -99.0% and -99.2% respectively; Cd: -97.2% and -98.3% respectively). Copper and Pb leaching increased after C (17 and >30 times for Cu and Pb respectively) and C + CA treatment (4.4 and >3.7 times for Cu and Pb respectively). C + CA + SS or CA + SS addition did not increase Cu leaching; the effect on Pb leaching was not completely clear. Our results ...

2006-11-01

172

Effect of physiological levels of caffeine on Ca2+ handling and fatigue development in Xenopus isolated single myofibers  

UK PubMed Central (United Kingdom)

The purpose of the present study was to determine whether exposure to exogenous physiological concentrations of caffeine influence contractility, Ca2+ handling, and fatigue development...Full Text Available

2009-05-01

173

Calcium gradients and buffers in bovine chromaffin cells.  

UK PubMed Central (United Kingdom)

1. Digital imaging and photometry were used in conjunction with the fluorescent Ca2+ indicator, Fura-2, to examine intracellular Ca2+ signals produced by depolarization of single adrenal chromaffin...Full Text Available

1992-05-01

174

Calcium - blood test: MedlinePlus Medical Encyclopedia  

Science.gov (United States)

Names Ca+2; Serum calcium; Ca++ References Wysolmerski JJ, Insogna KL. The parathyroid glands, hypercalcemia, and hypocalcemia. In: Goldman L, Ausiello D, eds. Cecil...

2011-08-30

176
177

Luminescence characteristics of LiCaAlF6:Eu phosphor  

British Library Electronic Table of Contents (United Kingdom)

A simple method for preparing LiCaAlF6:Eu2+ phosphor is reported. Photoluminescence (PL) and thermoluminescence (TL) studies were carried out. The TL sensitivity of the phosphor is nearly twice that of CaSO4:Dy TLD phosphor. Several other properties required for TL dosimetry are superior as well. It is suggested that the phosphor can be a suitable replacement for CaSO4:Dy. (Copyright 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)

2007-01-01

180

Surface treatment of Ti-6Al-4V alloy by rf plasma nitriding  

Energy Technology Data Exchange (ETDEWEB)

The Ti-6Al-4V alloy was treated by inductively coupled rf plasma nitriding. The effects of plasma-processing time in the range of 5-35 min on the microstructure and the mechanical properties of the plasma-nitrided Ti-6Al-4V samples were studied. The plasma power input was adjusted at 450 W and pure N{sub 2} gas was introduced to establish a treatment pressure of 8.0-8.4 x 10{sup -2} mbar. The characteristics of the nitrided layers have been investigated by microhardness testing, surface roughness measurements, optical microscopy, and x-ray diffraction. The results show that the surface microhardness increases as the plasma-processing time increases to reach 2000 HV0.1 at a plasma-processing time of 35 min. A high nitriding rate of 2.81 {mu}m{sup 2} s{sup -1} at a plasma-processing time of 25 min was achieved. The formation of the hard phases TiN, Ti{sub 2}N, and Ti(N) in the ...

2007-10-03

181

Surface treatment of Ti-6Al-4V alloy by rf plasma nitriding  

International Nuclear Information System (INIS)

The Ti-6Al-4V alloy was treated by inductively coupled rf plasma nitriding. The effects of plasma-processing time in the range of 5-35 min on the microstructure and the mechanical properties of the plasma-nitrided Ti-6Al-4V samples were studied. The plasma power input was adjusted at 450 W and pure N_2 gas was introduced to establish a treatment pressure of 8.0-8.4 x 10"-"2 mbar. The characteristics of the nitrided layers have been investigated by microhardness testing, surface roughness measurements, optical microscopy, and x-ray diffraction. The results show that the surface microhardness increases as the plasma-processing time increases to reach 2000 HV0.1 at a plasma-processing time of 35 min. A high nitriding rate of 2.81 #mu#m"2 s"-"1 at a plasma-processing time of 25 min was achieved. The formation of the hard phases TiN, Ti_2N, and Ti(N) in the Ti-6Al-4V ...

2007-10-03

182

Stress Ratio Effects on Small Fatigue Crack Growth in Ti-6Al ...  

Science.gov (United States)

... in Ti-6Al-4V has been studied quite thoroughly [5-7], much of the work resulting from the Air Force-sponsored High Cycle Fatigue initiative [8]. In ...

2008-11-01

183

Monotonic and Low-Cycle Fatigue Response of a Maraging Steel and Metastable Beta Titanium Alloy under Torsional Loading.  

Science.gov (United States)

This study deals with the torsional response of Ti-8823 and 18Ni (200) maraging steel. The effect of different heat treatments and the subsequent change in microstructure are investigated. In the case of the Ti-8823, a comparison was made between the solu...

1977-01-01

184

George C. Ma& Marshad Space Flight Center, Alabama - NASA ...  

Science.gov (United States)

tact materials ate Ti-Pd-Ag and the back surface reflector is formed from evaporated .... Ti-Pd-Ag, Dielectric Wraparound. BSR. Evaporated Aluminum ...

185

Effects of multi-ion irradiation on microstructural changes in lithium titanate  

Energy Technology Data Exchange (ETDEWEB)

The irradiation behavior of Li{sub 2}TiO{sub 3} under a fusion reactor environment was simulated by simultaneous irradiation of Li{sub 2}TiO{sub 3} by the triple ion beams and the respective single ion beams of O{sup 2+}, He{sup +} and H{sup +}. The microstructural changes in Li{sub 2}TiO{sub 3} caused by the irradiation were measured by FT-IR photoacoustic spectroscopy. The results suggest that the amount of TiO{sub 2} formed is proportional to the dpa and that the method of irradiation does not affect the dependence of formation of TiO{sub 2}. On the other hand, the amount of defects and/or radiolytic products generated by irradiation, which is considered to trap hydrogen near the surface, is found to be affected by the method of irradiation. Such phenomena are believed to affect the tritium release behavior from Li{sub 2}TiO{sub 3}, and durability of Li{sub ...

2009-04-30

186

Effects of multi-ion irradiation on microstructural changes in lithium titanate  

International Nuclear Information System (INIS)

The irradiation behavior of Li_2TiO_3 under a fusion reactor environment was simulated by simultaneous irradiation of Li_2TiO_3 by the triple ion beams and the respective single ion beams of O"2"+, He"+ and H"+. The microstructural changes in Li_2TiO_3 caused by the irradiation were measured by FT-IR photoacoustic spectroscopy. The results suggest that the amount of TiO_2 formed is proportional to the dpa and that the method of irradiation does not affect the dependence of formation of TiO_2. On the other hand, the amount of defects and/or radiolytic products generated by irradiation, which is considered to trap hydrogen near the surface, is found to be affected by the method of irradiation. Such phenomena are believed to affect the tritium release behavior from Li_2TiO_3, and durability of Li_2TiO_3 and compatibility of ...

2009-04-30

187

Development of a new wear-resistant material: TiC/TiNi composite  

Energy Technology Data Exchange (ETDEWEB)

In this work, an attempt was made to develop a novel type of wear-resistant composite employing a TiNi alloy matrix reinforced by hard particles. Titanium carbide was chosen as the reinforcing phase because of its high hardness and TiNi alloy as the matrix due to its pseudoelasticity and good toughness. TiC particles may sustain external load, while the TiNi matrix may accommodate deformation, absorb impact energy and retain the hard particles. Such a combination is expected to lead to an enhanced wear resistance, compared to TiNi alloy. As a matter of fact, some efforts were previously made to develop TiNi-matrix composite reinforced by ceramic particles. However, the emphasis of those studies was put on effects of the reinforcing particles on the phase transformation behavior, shape memory effect and some mechanical properties of the composite; no attempt was ...

1999-10-22

188

Composites in the TiC-TiYTZP system  

International Nuclear Information System (INIS)

Ceramic matrix composites in the TiC-Ti, Y-TZP system can be synthesized by the reaction between carbon and the TiO_2-Y_2O_3-ZrO_2 solid solution nanopowder. This method results in the more homogeneous powders than those prepared by the physical mixing of TiC and zirconia s.s. powders. Twelve TiO_2-Y_2O_3-ZrO_2 solid solution nanopowders differing in the proportions of the constituent oxides were prepared by the coprecipitation- calcination route. They were reacted with the pyrolytic carbon evenly distributed within the system. Carbon was introduced by the thermal decomposition of the phenol-formaldehyde resin dissolved in ethyl alcohol and mixed with the zirconia s.s. nanopowder. Reaction was performed in vacuum. Compacts of the composite powders sintered in vacuum give dense materials of evenly distributed TiC inclusions of sizes not surpassing 400 nm. Hardness of such materials ...

2003-09-25

189

Corrosion tests of high-alloy, stainless steels and nickel-chromium-molybdenum alloys under conditions typically encountered in the evaporation of flue gas desulfurization (FGD) scrubber solutions. Final report. Korrosionsuntersuchungen an hochlegierten nichtrostenden Staehlen und Nickel-Chrom-Molybdaen-Legierungen unter Eindampfbedingungen von Abwaessern aus Rauchgasentschwefelungsanlagen. Schlussbericht  

Energy Technology Data Exchange (ETDEWEB)

For evaporation crystallization of extremely corrosive FGD scrubber solutions which - depending on the process - can lead all the way to a product suitable for depositing, an economic equipment concept based on metallic construction materials was to be investigated. In a parameter study, electrochemical test methods were used to determine the influence of the pH value, the Fe{sup 3+}, F and So{sub 2} contents in a solution containing 200 g/l CaCl{sub 2}+30 g/l NaCl at 80deg C on the resistance to pitting corrosion of stainless steels and NiCrMo alloys. In addition, electrochemical and wet corrosion tests (e.g. crevice corrosion) were conducted using original FGD scrubber solutions with 43-50% dry substance from the power plants Reuter-West, Oberhavel and Rudow of the BEWAG, Berlin. The results were compared to those of standardized and non-standardized short-term tests for determining the critical pitting corrosion and crevice corrosion temperatures for the various ...

1991-08-05

190

Roles of mitochondria and temperature in the control of intracellular calcium in adult rat sensory neurons  

UK PubMed Central (United Kingdom)

SUMMARYWe recorded Ca2+ current and intracellular Ca2+ ([Ca2+]i) in isolated adult rat dorsal root ganglion (DRG) neurons at 20 and...Full Text Available

2008-04-01

191

Electrically Triggered All-or-None Ca2+-Liberation during Action Potential in the Giant Alga Chara  

UK PubMed Central (United Kingdom)

Electrically triggered action potentials in the giant alga Chara corallina are associated with a transient rise in the concentration of free Ca2+ in the cytoplasm (Ca2+cyt)....Full Text Available

2001-07-01

192

Contribution of first-principles energetics to the Ca-Mg thermodynamic modeling  

International Nuclear Information System (INIS)

The first-principles energetics of the constituent elements Ca and Mg and the Mg_2Ca C14 laves phase (C14) in the Ca-Mg binary system were used in the computational thermodynamic modeling, with models for the Gibbs energy of individual phases. C14 was modeled as (Ca,Mg)_2(Ca,Mg)_1 with four end-members. The first-principles calculations were performed using two computer codes: (i) WIEN2K based on the full-potential linearized augmented plane-wave (FLAPW) method and (ii) VASP based on the pseudo-potentials and a plane wave basis set. The total energies of the pure Ca and Mg in the fcc, bcc, and hcp structures, three laves phase structures of Mg_2Ca, and the four end-members of C14 were calculated at 0 K. The enthalpies of formation of the four end-members were obtained accordingly and used as input data in evaluating the Gibbs energy ...

2006-08-31

193

Wear resistance of a laser surface alloyed Ti-6Al-4V alloy  

Energy Technology Data Exchange (ETDEWEB)

Laser surface alloying with gaseous nitrogen was utilized to improve the wear resistance of a Ti-6Al-4V alloy. Wear-resistant composite coatings reinforced by hard TiN dendrites were produced 'in-situ' on a substrate of a Ti-6Al-4V alloy. The hardness and wear resistance of the laser alloyed coating under two-body abrasive and block-on-ring full-sliding wear conditions were significantly enhanced. (orig.)

2000-08-01

194

Synthesis and photonic band calculations of NCP face-centered cubic photonic crystals of TiO2 hollow spheres.  

Science.gov (United States)

With the help of self-assembly, thermal sintering, selective etching techniques and sol-gel process, the non-close packed (ncp) face-centered cubic (fcc) photonic crystals of titanium dioxide (TiO2) hollow spheres connected by TiO2 cylindrical tubes have been fabricated using silica template. The photonic bandgap calculations indicate that the ncp structure of TiO2 hollow spheres was easier to open the pseudogaps than close packed system at the lowest energy. PMID:17097102

2006-10-21

196

Preparation, properties, and application characteristics of metastable layers of the Ti-Si-C-N system; Herstellung, Aufbau, Eigenschaften und Anwendungsverhalten von metastabilen Schichten aus dem System Ti-Si-C-N  

Energy Technology Data Exchange (ETDEWEB)

In the Ti-Si-C and Ti-Si-C-N systems, metastable layers were precipitated by means of non-reactive magnetron sputtering of hot-pressed two-phase TiC/SiC and TiN/SiC targets with 20 mole% and 50 mole% SiC. The preparation parameters were varied as follows: ion bombardment during precipitation (bias sputtering), substrate temperature, and annealing times when annealing amorphous 50%:50% TiC/SiC and 50%:50% TiN/SiC layers. Sputtering of targets containing 20% SiC was found to result in monophase fcc layers (NaCl structure). This was documented on the basis of X-ray and electron diffraction patterns. Direct precipitation of targets with 50 mole% SiC resulted in amorphous layers. Increasing the ion bombardment during accretion, raising the substrate temperature, and annealing amorphous 50%:50% TiC/SiC and 50%:50% TiN/SiC ...

1992-10-01

197

Photoassisted hydrogen generation by integrated electroactive SPE membrane system  

Energy Technology Data Exchange (ETDEWEB)

Incorporation of TiO{sub 2}, into perfluoroionomer membrane by treatment with TiC1{sub 4}-methanol has been described. Platinum was used as an electrocatalyst. In order to make the system electronically as well as ionically conducting, the electrode was modified with polypyrrole (PPy). Photopolymerisation of pyrrole was accomplished by immersing TiO{sub 2}-Pt-NaF in pyrrole solution. UV-visible and FT-IR Spectroscopic studies were preformed with regards to the formation of the TiO{sub 2}, Pt and PPy within Nafion matrix. We report the construction and evaluation of this integrated system and establish the feasibility of hydrogen generation thereof. (Author)

2000-04-01

200

Development of a Stable-Beta Titanium Alloy, Quarterly Report Number 10, October 1 - December 31, 1964.  

Science.gov (United States)

Evaluation of ageable beta alloys Ti-17V-2Fe-2Co-3Al, Ti-17V-7.5Co-3A1 and Ti-8Mo-8V-5Co-3Al continued with room and elevated temperature smooth and notched tensile tests, creep stability, oxidation and stress-corrosion tests. Ti-17V-7.5Co-3Al aged more r...

1964-01-01

202

Structural transformations in Sc/Si multilayers irradiated by EUVlasers  

Energy Technology Data Exchange (ETDEWEB)

Multilayer mirrors for the extreme ultraviolet (EUV) are keyelements for numerous applications of coherent EUV sources such as newtabletop lasers and free-electron lasers. However the field ofapplications is limited by the radiation and thermal stability of themultilayers. Taking into account the growing power of EUV sources thestability of the optics becomes crucial. To overcome this problem it isnecessary to study the degradation of multilayers and try to increasetheir temporal and thermal stability. In this paper we report the resultsof detailed study of structural changes in Sc/Simultilayers when exposedto intense EUV laser pulses. Various types of surface damage such asmelting, boiling, shockwave creation and ablation were observed asirradiation fluencies increase. Cross-sectional TEM study revealed thatthe layer structure was completely destroyed in the upper part ofmultilayer, but still survived below. The layers adjacent tothe substrateremained intact even ...

2007-08-21

203

Functional expression of anti-hepatitis B virus (HBV) preS2 antigen scFv by cspA promoter system in Escherichia coli and application as a recognition molecule for single-walled carbon nanotube (SWNT) field effect transistor (FET)  

British Library Electronic Table of Contents (United Kingdom)

The preS2 antigens of hepatitis B virus (HBV), which causes a serious health problem in the world, have been implicated in hepatocyte cell binding and viral penetration. Therefore, the importance of antibody production against preS2 antigen for early diagnosis of HBV has been well established. In this study, the recombinant HBV preS2 single chain variable fragment (scFv) antibody was successfully expressed in E. coli with the novel cold shock vector (pCold) under the cspA promoter, and its expression level was compared with the pET vector under the T7 promoter. Additionally, a host with an oxidizing cytoplasm, E. coli trxB/gor double mutant, was used to improve the soluble expression. The anti-HBV preS2 scFv using pCold vector was successfully expressed in a soluble and functional form in ...

2010-01-01

204

Definition and means of maintaining the criticality detectors and alarms portion of the PFP safety envelope  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this document is to provide the definition and means of maintaining the Safety Envelope (SE) related to the Criticality Alarm System (CAS). This document provides amplification of the Limiting Condition for Operation (LCO) described in the Plutonium Finishing Plant (PFP) Operational Safety Requirements (OSR), WHC-SD-CP-OSR-010, Rev. 0, 1994, Section 3.1.2, Criticality Detectors and Alarms. This document, with its appendices, provides the following: (1) System functional requirements for determining system operability (Section 3); (2) A list of annotated system block diagrams which indicate the safety envelope boundaries (Appendix C); (3) A list of the Safety Class 1 and 2 Safety Envelope (SC-1/2 SE) equipment for input into the Master Component Index (Appendix B); (4) Functional requirements for individual SC-1/2 SE components, including appropriate setpoints and process parameters (Section 6 and Appendix A); (5) A list of the ...

1997-05-13

205

Tribological behaviour of Ti-Al-B-N-based PVD coatings  

Energy Technology Data Exchange (ETDEWEB)

PVD-coatings based on TiB{sub 2} are expected to show high wear resistance and low tendency of adhesion on metal forming tools. Coating adhesion and morphology can be modified over a wide range by varying the content of nitrogen (N{sub 2}) and the deposition parameters power and bias voltage. All coatings were deposited using commercial unbalanced magnetron equipment, the deposition was homogeneous in a volume of 400 x 400 x 400 mm{sup 3}. Hipped and hot pressed TiB{sub 2}-targets were used, nitrogen (N{sub 2}) was added as gas, Ti and Al by a solid Ti-Al-target. The tribological behaviour was tested by a pin-on-disc wear test. The coatings investigated were TiB{sub 2}, TiAlB(N), TiAl(N) and TiB{sub 2}/TiAl(N). As counterpart in the pin-on-disc wear test, 6 mm diameter spheres of steel (100Cr6), ...

1996-12-15

206

Analysis of TL glow curves in differently doped LiF:Mg,Ti  

International Nuclear Information System (INIS)

A computerised curve-fitting method was developed to calculate the trapping parameters in LiF TLD-100 and LiF:Mg, Ti. After irradiation in a "6"0Co field and with X rays emitted at different voltages the TL process is best described by first-order kinetics. A dependence of the trapping parameters on both the concentration of Mg and Ti and photon energy was detected. (author).

207

The central analgesia induced by antimigraine drugs is independent from Gi proteins: superiority of a fixed combination of indomethacin, prochlorperazine and caffeine, compared to sumatriptan, in an in vivo model  

British Library Electronic Table of Contents (United Kingdom)

A hypofunctionality of Gi proteins has been found in migraine patients. The fixed combination of indomethacin, prochlorperazine and caffeine (Indoprocaf) is a drug of well-established use in the acute treatment of migraine and tension-type headache. The aim of this study was to investigate if Indoprocaf was able to exert its central antinociceptive action when Gi proteins activity is abolished by pertussis toxin (PTX), compared to its single active ingredients and to sumatriptan. The mice model of abdominal constriction test induced by an i.p. injection of a 0.6% solution of acetic acid was used. The study showed that Indoprocaf (a fixed combination of indomethacin 1?mg/kg, prochlorperazine 1?mg/kg and caffeine 3?mg/kg, s.c.) and sumatriptan (20?mg/kg, s.c.) exert their central antinocicep...

2009-01-01

208

Policies to promote sustainable consumption: Innovative approaches in Europe  

British Library Electronic Table of Contents (United Kingdom)

Abstract Policy-makers are increasingly recognising that the promotion of more sustainable consumption patterns is an indispensable prerequisite for achieving sustainable development in the long term. Policy documents and action plans have been published, and a wide array of policy instruments has been implemented with the aim of reducing the environmental and social burdens of consuming goods and services. But what are the latest trends and innovative approaches in sustainable consumption (SC) policies? What could be learnt for future policy-making? Based on an overview of European policy instruments and several case studies, the paper discusses instructive examples of SC policy instruments, in particular the Danish information campaign "One Tonne Less", the Dutch tax incentive scheme "Gr...

2010-01-01

209

Phase stability, electronic and elastic properties of ScN  

International Nuclear Information System (INIS)

The structural stability, electronic and elastic properties of ScN under high pressure were investigated by using full-potential linearized augmented plane-wave (FP-LAPW) method. Our calculations indicate that there exists a pressure-induced structural phase transformation from the ambient rock-salt (B1) phase to CsCl-type (B2) phase above 335 GPa. The origin of moderate high bulk modulus, mechanical and high melting point was analyzed by electronic properties. The variations of elastic constants (C_i_j) with volume and pressure have been investigated. Moreover, the volume dependencies of Debye temperature, the longitudinal and transverse elastic wave velocities have been presented.

2010-06-01

210

Microstructure and mechanical behaviour of an elevated temperature Mg-rare earth based alloy  

International Nuclear Information System (INIS)

AM-SC1 is a heat treatable magnesium alloy that has been specifically developed to achieve the elevated temperature strength and creep properties necessary for engine block applications. This paper describes the interrelationship between the microstructure and the mechanical properties of AM-SC1. The compressive and tensile strengths are relatively insensitive to temperature up to and including 450 K and the tensile yield behaviour deviates from a standard Hall-Petch relationship at grain sizes below 200 ?m. The microstructural features contributing to the creep resistance are both inter- and intra-granular in nature and are on length scales from nanometers to micrometers. The creep behaviour at 423 K and 450 K is diffusion controlled, with any contribution from the grain boundaries being negligible.

2009-04-15

211

Linearized augmented-plane-wave method for quasi-unidimensional systems: Carbyne and nanotube (Sc@C{sub 20})  

Energy Technology Data Exchange (ETDEWEB)

The advent of carbon nanotubes, which are graphite layers convoluted in cylinders several nanometers in diameter and several micrometers in length, as well as the experiments on implanting metal atoms in such tubes open the way to producing nanoconductors and other materials with unique properties. For theorists, the basic challenge is interpreting and predicting the structure and properties of these systems. The linearized augmented-plane-wave method (LAPW) is one of the most accurate methods in the theory of the electronic structure of solids. A generalization of this method for quasi-two-dimensional systems, surface electronic states, and layered crystals is known. The LAPW theory for quasi-unidimensional systems, which exhibit translational symmetry in one direction, has been absent thus far. In this paper, the authors suggest a version of such a theory and use this method to calculate the electronic structure of carbyne (a linear chain of carbon atoms) and carbon nanotube with ...

1995-10-01

212

LLX separation of carrier-free {sup 47}Sc, {sup 48}V and {sup 48,49,51}Cr produced in {alpha}-particle activated titanium with HDEHP  

Energy Technology Data Exchange (ETDEWEB)

A LLX procedure for carrier-free separation of the radioisotopes, {sup 47}Sc, {sup 48}V and {sup 48},{sup 49},{sup 51}Cr, the 40 MeV {alpha}-particle activation products of titanium has been developed. Sequential separations of the radionuclides produced in the titanium matrix through the nuclear reactions ({alpha}, {alpha}p{chi}n), ({alpha}, p{chi}n) and {alpha}, ({chi}n) have been performed through LLX from aqueous H{sub 2}SO{sub 4} and HClO{sub 4} acid media using the liquid cation exchanger, HDEHP, as an extractant. Purity of the carrier-free radiotracers at different stages of their separations has been verified by {gamma}-ray spectrometry. (author).

1996-01-01

213

Growth Inhibition and Induction of Stress Protein, GroEL, of Bacillus cereus Exposed to Antibacterial Peptide Isolated from Bacillus subtilis SC-8  

British Library Electronic Table of Contents (United Kingdom)

This study was conducted to investigate the antibacterial effect of BSAP-254 on Bacillus cereus with the induced stress proteins. The BSAP-254 is an antimicrobial peptide isolated from soybean-fermenting bacteria, Bacillus subtilis SC-8. It had a narrow spectrum of activity against B. cereus group. The growth inhibitory effect of BSAP-254 (50??g/mL) reduced the population of B. cereus from >108 to 104 colony-forming units per milliliter within 30?min. In B. cereus exposed to BSAP-254, 14 intracellular proteins were differentially expressed as determined by 2-DE coupled with MS. Of the differentially expressed proteins identified, the stress protein GroEL, which is heat shock protein, was induced in B. cereus exposed to antibacterial peptide.

2011-01-01

214

Ferrihydrite phase transformation in the presence of aqueous sulfide and supercritical CO2  

British Library Electronic Table of Contents (United Kingdom)

The transformation of ferrihydrite to siderite (FeCO3) in the presence of supercritical CO2 (scCO2) and aqueous sulfide has been investigated by in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and ex situ X-ray diffraction (XRD). The chemical transformation of iron-bearing minerals to form iron carbonates may play a role in the chemistry related to the geological sequestration of carbon dioxide in the Earth's (sub)surface. The iron oxyhydroxide ferrihydrite in an aqueous solution containing sodium sulfide in contact with scCO2 at 100^oC reacts within 24h to form siderite and elemental sulfur. In situ studies of this reaction with ATR-FTIR show that ferrihydrite exists with an adsorbed layer of carbonate. However, the presence of the carbonate adsorbat...

2010-01-01

215

Developing Policies and Instruments for Sustainable Household Consumption: Irish Experiences and Futures  

British Library Electronic Table of Contents (United Kingdom)

In recent years, the concept of sustainable consumption (SC) has received increased attention. Overconsumption in industrialized countries still presents major challenges to achieving sustainable development goals despite the global economic crisis. This paper offers an in-depth analysis of national influences on consumption patterns in the Republic of Ireland, focusing in particular on the role of governance in the design of policy instruments for sustainable consumption. It is argued that country-specific political conditions and policy frameworks fundamentally shape everyday household consumption. After an initial discussion of the effectiveness of three key types of policy instruments?legislative, economic, communicative?the paper compares SC policy making and implementation in Ireland...

2011-01-01

216

Analysis on anomalous degradation in silicon solar cell designed for space use  

Energy Technology Data Exchange (ETDEWEB)

Recently, we have found the anomalous degradation of electrical performance in silicon solar cells irradiated with charged particles in a high-fluence region. This anomalous phenomenon has two typical features, which are sudden-drop-down of electrical performances in a high-fluence region and slight recovery of the short circuit current I{sub SC} just before the sudden-drop-down. These features cannot be understood by a conventional model coming from the decrease of minority-carriers life-time. We introduce this anomalous degradation of the electrical performance in Si solar cells irradiated with electrons or protons. We also report the result of simulation for the fluence dependence of the I{sub SC}, and discuss the mechanism of this anomalous phenomenon. (author)

1997-03-01

217

(#alpha#, t) reactions on "4"5Sc, "5"1V and "5"9Co nuclei at 27.2 MeV #alpha#-particle energy  

International Nuclear Information System (INIS)

Differential cross sections of the (#alpha#, t) reactions on "4"5Sc, "5"1V, and "5"9Co nuclei are measured in the 10-71 deg, 10-155 deg, and 10-171 deg angular ranges, respectively, with 27.2 MeV alpha particles. The cross sections have also been calculated on the basis of the distorted wave theory. The possibility of an unambiguous choice of the optical potential for alpha particles is discussed. The angular distribution calculations using several combinations of the optical potentials in the inlet and outlet channels of the reactions show that consistence between the calculations and the measurements is achieved (especially in angular range, less than 90 deg, if one of the potentials is chosen to be a sufficiently deep one.

218

The effects of counter cation on lithium ion conductivity: In the case of the perovskite-type titanium oxides of La2/3?x Li3xTiO3 and LaTiO3  

British Library Electronic Table of Contents (United Kingdom)

We performed hybrid-DFT calculations for La2/3?xLi3xTiO3 (LLT) with lithium ion conductivity, in order to investigate the detailed lithium ion conductive mechanism from the viewpoint of molecular orbital (MO) method. It was concluded that the very ionic lithium ion in bottleneck accelerates the lithium ion conduction. The calculated MO shows no chemical bonding between lithium ion and other ions. In comparison with the perovskite-type trivalent titanium oxide of LaTiO3, the effect of the titanium's reduction was also investigated. We showed the possibility of the high lithium conductivity in LaTiO3.

2009-01-01

219

Particle emission from low energy proton bombardment of TiH{sub 2} and TiD{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

TiH{sub 2} and TiD{sub 2} thick targets were bombarded with 100 to 200 keV protons. Evidence for nuclear reactions was obtained by means of a surface barrier particle detector. Proton irradiation of TiD{sub 2} produced the following observations: {alpha} particle emission identified as (p, {alpha}) reactions from {sup 11}B and {sup 7}Li impurities in the target at ppm concentrations; and {approx}3 MeV proton and {approx}1 MeV triton emission from secondary D-D reactions caused by elastic scattering of the primary proton with a target deuteron. A 3.9 MeV {alpha} particle peak measured by others was not observed. (author)

2002-03-01

220

Low temperature deposition and characterization of TiO{sub 2} photocatalytic film through cold spray  

Energy Technology Data Exchange (ETDEWEB)

Cold spray was employed as a novel low temperature approach to deposit titanium dioxide (TiO{sub 2}) photocatalytic film. The film microstructure was characterized using X-ray diffraction and scanning electron microscopy. The photocatalytic performance was examined through acetaldehyde degradation under ultraviolet illumination. Results showed that TiO{sub 2} film was successfully deposited on substrate surface through cold spray. The film thickness reached up to 15 {mu}m. The film presented a rough surface and porous structure. Owing to the low temperature of spray powder, no phase and particle size changes occurred to TiO{sub 2} during deposition. It was found that the cold-sprayed TiO{sub 2} film was active for photodegradation of acetaldehyde.

2008-04-30

221

Influence of some selected organic molecules on intensity of luminescence of TiO2:Eu3+ electrodes  

International Nuclear Information System (INIS)

Eu3+ ions are anchored on TiO2 matrix by coupling with 2,2'-bipyridyl 4,4'-dicarboxylic acid. Five different luminescence centers are observed for TiO2|2,2'-bipyridyl 4,4'-dicarboxylic acid|Eu3+ electrodes due to electron transitions between d and f orbitals. Photo-luminescence of TiO2|2,2'-bipyridyl 4,4'-dicarboxylic acid|Eu3+ electrodes is increased by attaching 2-thenoyltrifluoroacetone to Eu3+ ions. Immersion of TiO2|2,2'-bipyridyl 4,4'-dicarboxylic acid|Eu3+|2-thenoyltrifluoroacetone electrodes in propylsulfide is found to be further increased intensities of luminescence bands by a factor of three.

2009-05-01

222

Effect of minor alloying elements and their segregation on void suppression in modified 316 stainless steel  

International Nuclear Information System (INIS)

The effects of modification with Ti and Nb, heat treatment and solute segregation on void suppression in 316 stainless steel were studied using HVEM in the temperature range of 623-873 K after solution treatment at 1323-1473 K. Post-irradiation compositional analysis was performed by an energy dispersive X-ray analyzer. In Ti-modified stainless steel, void swelling peaks appeared at 723 K and 823 K. On the other hand, when the stainless steels modified by both Ti and Nb were irradiated, the void swelling was effectively suppressed, particularly the growth rate of a void was remarkedly retarded. This void suppression effect was easily recognized with increasing Nb concentration. Compositions such as Mo, Cr, Ti and Ni changed during irradiation and Ni, Si and Ti enriched around voids, whereas Cr and Mo depleted. (orig.).

1983-09-01

223

Synthesis and photo-degradation application of WO3/TiO2 hollow spheres.  

Science.gov (United States)

A WO(3)/TiO(2) composite, hollow-sphere photocatalyst with average diameter of 320 nm and shell thickness of 50 nm was successfully prepared using a template method. UV-vis diffuse reflectance spectra illustrated that the main absorption edges of the WO(3)/TiO(2) hollow spheres were red-shifted compared to the TiO(2) hollow spheres, indicating an extension of light absorption into the visible region of the composite photocatalyst. The WO(3) and TiO(2) phases were confirmed by X-ray diffraction analysis. BET isotherms revealed that the specific surface area and average pore diameter of the hollow spheres were 40.95 m(2)/g and 19 nm, respectively. Photocatalytic experiments indicate that 78% MB was degraded by WO(3)/TiO(2) hollow spheres under visible light within 80 min. Under the same conditions, only 24% MB can be photodegraded by TiO(2). The photocatalytic ...

2011-02-22

224

A simple template-free approach to TiO2 hollow spheres with enhanced photocatalytic activity.  

Science.gov (United States)

Mesporous anatase-phase TiO(2) hollow spheres with high photocatalytic activity were prepared by hydrothermal treatment and self-transformation of amorphous TiO(2) solid spheres in an NH(4)F aqueous solution. The prepared samples were characterized by X-ray diffraction, scanning and transmission electron microscopy, X-ray photoelectron spectroscopy, N(2) adsorption-desorption isotherms and UV-vis absorption spectroscopy. The photocatalytic activity was evaluated by photocatalytic oxidation decomposition of acetone in air under UV irradiation. It is found that F(-) plays an essential role in the formation of TiO(2) hollow spheres. F(-) not only induces the hollowing of TiO(2) solid spheres, but also promotes the crystallization of anatase TiO(2) nanocrystals. A possible formation mechanism for the TiO(2) hollow spheres by localized Ostwald ripening or chemically ...

2010-05-27

225

Stearic acid gel derived MgTiO{sub 3} nanoparticles: A low temperature intermediate phase of Mg{sub 2}TiO{sub 4}  

Energy Technology Data Exchange (ETDEWEB)

Stearic acid gel is employed to study the phase evolution of MgTiO{sub 3} nanoparticles by thermal gravimetric analysis, X-ray diffraction, and Fourier transform infrared. During the preparation of stearic acid gel, tetrabutyl titanate easily absorbed moisture to hydrolyze into Ti(OH){sub 4} firstly, and then reacts with stearic acid and magnesium stearate to form magnesium-titanium oxide network polymer gel, meanwhile n-butanol is generated. When stearic acid gel is calcined in air, a series of oxidation and combustion reactions occur, meanwhile apparent heat is given off. The results show that a metastable intermediate phase Mg{sub 2}TiO{sub 4} is generated at 450 {sup o}C and nearly disappeared at 550 {sup o}C. Simultaneously, a new solid phase of MgTiO{sub 3} appears. The metastable intermediate phase Mg{sub 2}TiO{sub 4} is successfully identified in the current work.

2010-03-04

226

Preparation and characterization of Co-doped BaTiO{sub 3} nanosized powders and ceramics  

Energy Technology Data Exchange (ETDEWEB)

The Co-doped BaTiO{sub 3} nanosized powders and ceramics were prepared via the sol-gel process. The powders and ceramics were characterized by methods of XRD, SEM and TEM. The dielectric properties of the ceramics were also determined by these methods. The influence of sintering temperature, sintering time and Co concentration on the microstructure and dielectric properties was discussed. The results revealed that the powders were in nanometer scale (30-50 nm) and were mainly composed of cubic BaTiO{sub 3} phase and small amount of BaCO{sub 3}. After sintering, both the cubic BaTiO{sub 3} and BaCO{sub 3} were transformed into tetrahedron BaTiO{sub 3}. The sintering temperatures of the Co-doped BaTiO{sub 3} ceramics decreased (about 100 deg. C) and the Curie temperatures of the ceramics were then moved to lower temperature. In addition, the dielectric constant of the ceramics doping ...

2006-08-25

227

A one-pot synthetic approach to prepare palladium nanoparticles embedded hierarchically porous TiO2 hollow spheres for hydrogen peroxide sensing  

Science.gov (United States)

A simple one-step method to fabricate hierarchically porous TiO2/Pd composite hollow spheres without any template was developed by using solvothermal treatment. Pd nanoparticles (2-5 nm) were well dispersed in the mesopores of the TiO2 hollow spheres via in-situ reduction. In our experiment, polyvinylpyrrolidone played an important role in the synthetic process as the reducing agent and the connective material between TiO2 and Pd nanoparticles. HF species generated from solvothermal reaction leaded to the formation of TiO2 hollow spheres and Ostwald ripening was another main factor that affected the size and structure of the hollow spheres. The as-prepared TiO2/Pd composite hollow spheres exhibited high electrocatalytic activity towards the reduction of H2O2. The sensitivity was about 226.72 ?A mM-1 cm-2 with a detection limit of 3.81 ?M at a signal-to-noise ratio of 3. These ...

2010-10-01

228

lla0857e.248  

Science.gov (United States)

... cj\\R`^x`VXWTd juaY^UiXSTUQTaLSOZ}ccn[]XUT\\coV]e`y}mZtwqtm jrhppeYy]Z\\_^`YTZh k^P^ l__qcPU NWeOYUN\\XMRV`]scZi bXXh qb^Riq^ mJLMSIRRNNMUjaU a^TTZK__dVaZ} ...

229

Vertical and Horizontal Variations in the Physiological Diversity of the Aerobic Chemoheterotrophic Bacterial Microflora in Deep Southeast Coastal Plain Subsurface Sediments  

UK PubMed Central (United Kingdom)

Aerobic chemoheterotrophic bacteria were isolated from surface soils and coastal plain subsurface (including deep aquifer) sediments (depths to 265 m) at a study site near Aiken, S.C., by plating on...Full Text Available

1989-05-01

230

Scintigraphic assessment of pericardio-peritoneal window patency. Relevance to peritoneal dialysis.  

Science.gov (United States)

To alleviate recurrent pericardial effusion secondary to systemic lupus erythematosus, pericardio-peritoneal window was performed. Subsequently, end stage renal disease developed and the patient required peritoneal dialysis. Patency of the pericardio-peritoneal window was demonstrated by intraperitoneal injection of Tc-99m SC through a Tenckhoff catheter, which prompted special counsel to the patient in order to prevent infectious pericarditis potentially complicating peritoneal dialysis induced-peritonitis. PMID:7554664

1995-07-01

231

Metabolomic analysis of the plant pathogenic fungi Fusarium graminearum and Fusarium culmorum  

Environmental Research Database

DescriptionThis project is part of the BBSRCs special initiative on plant and microbial metabolomics. The project will primarily focus on the trichothecene mycotoxin producing Ascomycete fungus Fusarium graminearum (Fg) which causes ear blight disease of small grain cereals. The project aims to explore the metabolome of various wild-type and single gene deletion Fg strains and to compare some of these with the identical gene mutation in the budding yeast, S. cerevisiae (Sc) and the saprophytic filamentous [continued...

2008-01-31

232

Analysis of Elements in The Baltic Sea Sediment by Using Gamma Spectrometry  

International Nuclear Information System (INIS)

We have done analysis of elements in the Baltic sea sediment by using gamma spectrometry in neutron activation analysis Goal of the analysis is to determine the rate of morsel elements which is contained in the Baltic sea sediment. Sample of the Baltic sea Sediment (IAEA-SED-1), Standard of Reference Material (SRM) 1646 Estuarine Sediment and Standard Ce, Fe, Sc, and Co are put into vial of capsule rabbit, then irradiated together for 30 minutes in rabbit facility Multi Purpose Reactor at power of 25 MW and then cooled for one week. Next sample, standard, and SRM which have irradiated, each is cut for 30 minutes using gamma spectrometer. Result of analysis of rate of elements Ce, Fe, Sc and Co in the baltic sea sediment successively equal to 141.20 ppm, 5.91 %, 14.88 ppm, and 19.59 ppm. Result of analysis in SRM Estuarine sediment successively equal to 96.60 ppm, 3.21 %, 10.25 ppm, and 9.63 ppm. Result of this analysis if compared to the value ...

2007-04-01

233

A s.c. 5-cell, Nb-cavity before cold test. It is surrounded by members of the EF-RF group  

CERN Multimedia

L. to r.: C. Ruivet, J.F. Malo, A. Insomby, R. Romijn, J. Tuckmantel, E. Chiaveri, H. Lengeler, D. Bloess, W. Weingarten, H. Preis, P. Marchand and G. Cavallari

1982-01-01

234

Uptake, transport, and storage of calcium and magnesium in spruce (Picea abies [L]Karst.) and pine (Pinus silvestris L.) as affected by variable nutrition and pollutant stress  

International Nuclear Information System (INIS)

Statements about the dynamic processes of uptake, transport, and deposition of Ca and Mg in norway spruce and Scots pine are made in this paper. Concerning the storage of these elements it is shown that there are great differences in their functional importance in cell metabolism. There is evidence that the role of Mg in enzyme and protein metabolism is of far greater significance for the understanding of Mg-deficiency symptoms than its function as the central atom of the chlorophyll complexes. In regard to the transport and especially to the incorporation of Ca into the needles differences between species were evident, expressing the special status of pine among the gymnosperms. With increasing needle age an accumulation of Ca-oxalate crystals, which are physiologically inert, could be proved for the studied conifers. This was interpreted as a 'detoxication' from surplus Ca to hold constant the level ...

235

Electrically triggered all-or-none Ca(2)+-liberation during action potential in the giant alga Chara.  

Science.gov (United States)

Electrically triggered action potentials in the giant alga Chara corallina are associated with a transient rise in the concentration of free Ca(2)+ in the cytoplasm (Ca(2)+(cyt)). The present measurements of Ca(2)+(cyt) during membrane excitation show that stimulating pulses of low magnitude (subthreshold pulse) had no perceivable effect on Ca(2)+(cyt). When the strength of a pulse exceeded a narrow threshold (suprathreshold pulse) it evoked the full extent of the Ca(2)+(cyt) elevation. This suggests an all-or-none mechanism for Ca(2)+ mobilization. A transient calcium rise could also be induced by one subthreshold pulse if it was after another subthreshold pulse of the same kind after a suitable interval, i.e., not closer than a few 100 ms and not longer than a few seconds. This dependency of Ca(2)+ mobilization on single and double pulses ...

2001-07-01

236

Electrically Triggered All-or-None Ca2+-Liberation during Action Potential in the Giant Alga Chara  

Science.gov (United States)

Electrically triggered action potentials in the giant alga Chara corallina are associated with a transient rise in the concentration of free Ca2+ in the cytoplasm (Ca2+cyt). The present measurements of Ca2+cyt during membrane excitation show that stimulating pulses of low magnitude (subthreshold pulse) had no perceivable effect on Ca2+cyt. When the strength of a pulse exceeded a narrow threshold (suprathreshold pulse) it evoked the full extent of the Ca2+cyt elevation. This suggests an all-or-none mechanism for Ca2+ mobilization. A transient calcium rise could also be induced by one subthreshold pulse if it was after another subthreshold pulse of the same kind after a suitable interval, i.e., not closer than a few 100 ms and not longer than a few seconds. This dependency of Ca2+ mobilization on single and double pulses can be simulated by a ...

2001-01-01

237

Effect of chlordecone (kepone) on calcium transport mechanisms in rat heart sarcoplasmic reticulum  

Energy Technology Data Exchange (ETDEWEB)

Since chlordecone (Kepone, CD) interferes with cardiac Na{sup +} ion translocases, we have studied CD effects on cardiac SR calcium pump activity. SR was isolated from heart ventricles of male Sprague-Dawley rats. Cardiac SR Ca{sup 2+}-ATPase, {sup 45}Ca-uptake and cAMP as well as calmodulin (CaM) dependent protein phosphorylation were measured. Ca{sup 2+}-ATPase was differentiated into low affinity and high affinity forms by measuring the activity using 50 and 0.7 {mu}M free Ca{sup 2+} respectively. CD in vitro inhibited {sup 45}Ca-uptake by SR in a concentration dependent manner with an IC50 value of 7 {mu}M and SR {sup 45}Ca-uptake was totally inhibited at 20-30 {mu}M CD. In agreement with this, both high affinity and low affinity Ca{sup 2+}-ATPases, which are involved in Ca{sup 2+} transport ...

1990-01-01

238

Synthesis and some properties of Ti{sub 3}SiC{sub 2} by hot pressing of Ti, Si and C powders. Part 2: Mechanical and other properties of Ti{sub 3}SiC{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

Some properties of the remarkable Ti{sub 3}SiC{sub 2} based ceramic synthesised by hot pressing of elemental Ti, Si, and C powders have been investigated. Its flexural strength by using three point bending tests and fracture toughness by using single edge notched beam tests were measured at room temperature to be in the range 310-427 MPa and about 7.MPa m{sup 1/2}, respectively. This material is a relative 'soft' ceramic with a low hardness of 4 GPa. Ti{sub 3}SiC{sub 2} is similar to the soft metals and is a damage tolerant material that is able to contain the extent of microdamage. An oxidation test has been performed in the temperature range 1000-1400{sup o}C in air for 20 h. The oxidation resistance below 1100{sup o}C was good. Two oxidized layers were formed, the outer layer consisting of pure rutile-type TiO{sub 2}, and the inner layer a mixture of SiO{sub 2} and ...

2005-09-15

239

Chlorophyll assembled electrode for photovoltaic conversion device  

Energy Technology Data Exchange (ETDEWEB)

Chlorophyll-a (Chl-a) assembled in hydrophobic domain by fatty acid with long alkyl hydrocarbon chain such as myristic acid (Myr), stearic acid (Ste) and cholic acid (Cho) modified onto nanocrystalline TiO{sub 2} electrode is prepared and the photovoltaic properties of the nanocrystalline TiO{sub 2} film by Chl-a are studied. Incident photon to current efficiency (IPCE) value at 660 nm in photocurrent action spectrum of Chl-a/Ste-TiO{sub 2}, Chl-a/Myr-TiO{sub 2} and Chl-a/Cho-TiO{sub 2} electrodes are 5.0%, 4.1% and 4.1%, respectively. Thus, the IPCE is maximum using Chl-a/Ste-TiO{sub 2} electrode. From the results of photocurrent responses with light intensity of 100 mW cm{sup -2} irradiation or monochromatic light with 660 nm, generated photocurrent increases using Chl-a/Ste-TiO{sub 2} electrode compared with the other Chl-a assembled ...

2007-11-20

240

Chemical and electrochemical dehydriding characteristics of TiV{sub 2.1}Ni{sub 0.3}-Raney Ni composite prepared by ball-milling in the presence of a reducing agent  

Energy Technology Data Exchange (ETDEWEB)

Composite particles represented as TiV{sub 2.1}Ni{sub 0.3}-Raney Ni(R) were prepared by ball-milling a TiV{sub 2.1}Ni{sub 0.3} alloy with Raney Ni in the presence of 0.01 M sodium hypophosphite (NaH{sub 2}PO{sub 2}) aqueous solution as a reducing agent. The composite particles had different morphology from original TiV{sub 2.1}Ni{sub 0.3} alloy particles and TiV{sub 2.1}Ni{sub 0.3}-Raney Ni composite particles prepared by the ball-milling in the absence of the NaH{sub 2}PO{sub 2} aqueous solution. In charge-discharge cycle tests, the TiV{sub 2.1}Ni{sub 0.3}-Raney Ni(R) composite electrode showed the maximum discharge capacity of 620 mAh g{sup -1}, while its cycle durability was similar to the TiV{sub 2.1}Ni{sub 0.3} alloy electrode, which was explained from depth profiles of constituent elements by Auger electron spectroscopy (AES). In thermogravimetry (TG) and ...

2004-02-25

241

Chemical and electrochemical dehydriding characteristics of TiV_2_._1Ni_0_._3-Raney Ni composite prepared by ball-milling in the presence of a reducing agent  

International Nuclear Information System (INIS)

Composite particles represented as TiV_2_._1Ni_0_._3-Raney Ni(R) were prepared by ball-milling a TiV_2_._1Ni_0_._3 alloy with Raney Ni in the presence of 0.01 M sodium hypophosphite (NaH_2PO_2) aqueous solution as a reducing agent. The composite particles had different morphology from original TiV_2_._1Ni_0_._3 alloy particles and TiV_2_._1Ni_0_._3-Raney Ni composite particles prepared by the ball-milling in the absence of the NaH_2PO_2 aqueous solution. In charge-discharge cycle tests, the TiV_2_._1Ni_0_._3-Raney Ni(R) composite electrode showed the maximum discharge capacity of 620 mAh g"-"1, while its cycle durability was similar to the TiV_2_._1Ni_0_._3 alloy electrode, which was explained from depth profiles of constituent elements by Auger electron spectroscopy (AES). In thermogravimetry (TG) and differential thermal analysis (DTA), two steps of ...

2004-02-25

242

Properties and performance of new metastable Ti-B-C-N hard coatings prepared by magnetron sputtering  

Energy Technology Data Exchange (ETDEWEB)

Thin films of new metastable materials from the system Ti-B-C-N were deposited on metallic substrates by d.c. magnetron sputtering in different Ar+N{sub 2} atmospheres. The multiphase compound targets used were based on various compositions on the TiC-TiB{sub 2} and TiB{sub 2}-C tie lines of the Ti-B-C phase diagram. The structure and chemical composition of the films were characterized by electron microprobe analysis, depth profiling Auger electron spectroscopy, X-ray diffraction and transmission electron microscopy. The hardness, critical load of failure and the tribological behavior of the coatings were investigated. Superhard single-phase crystalline metastable Ti-B-C-N layers with hardness values exceeding 5000 HV{sub 0.05} and extremely low sliding wear against 100Cr6 and Al{sub 2}O{sub 3} counterparts could be produced by reactive sputtering of various ...

1995-10-01

243

Superplastic deformation of nitrogen-rich Ca-#alpha#-sialon ceramics  

International Nuclear Information System (INIS)

Nitrogen-rich Ca-#alpha#-sialon ceramics, prepared with CaH_2 as one of the starting powders, were compressively deformed in spark plasma sintering equipment. Compared with the oxygen-rich Ca-#alpha#-sialons, increasing onset deformation temperatures (about 150 K higher) were observed for nitrogen-rich Ca-#alpha#-sialons deformed at a rate of 2 x 10"-"3 s"-"1. High hardness (H_V_1_0 = 18-20 GPa) and toughness (K_I_C = 4-7 MPa m"1"/"2) were maintained after the deformation. Anisotropic grain growth was found to take place during deformation, resulting in anisotropic microstructures, containing coarse and elongated grains. The observed differences in deformation behaviour and properties between nitrogen-rich and oxygen-rich Ca-#alpha#-sialons are, as indicated by transmission electron microscopy and electron energy loss spectroscopy analysis, attributed to the presence of reduced ...

2008-02-25

244

Coal demineralization with Ca(OH)2. Hydrothermal reaction between Ca(OH)2 and quartz; Ca(OH)2 wo mochiita sekitan no kagakuteki dakkai. Ca(OH)2 to sekitan no suinetsu hanno  

Energy Technology Data Exchange (ETDEWEB)

Coal demineralization mechanism and its optimum condition were studied by hydrothermal reaction between Ca(OH)2 and quartz as a coal demineralization model. In experiment, the mixture of powder quartz and Ca(OH)2 water slurry was subjected to reaction in an autoclave under spontaneous pressure at 175-340{degree}C. After dried in N2 gas atmosphere at 105{degree}C, the reaction product was analyzed by X-ray diffraction, thermo-balance and differential thermal analysis. In measurement of quartz conversion, the specimen was analyzed by X-ray diffraction after removal of bound water by heat treatment at 850{degree}C. The mixture of clean coal deashed by NaOH and a fixed amount of quartz was also used as specimen for experiment. As the experimental result, dicalcium silicate hydrate was mainly produced at 175{degree}C, and the product changed into xonotlite through tobermorite by longer treatment at higher temperature. For complete reaction of ...

1996-10-28

245

Charge transfer transitions and location of the rare earth ion energy levels in Ca-#alpha#-SiAlON  

International Nuclear Information System (INIS)

The broad bands in the room-temperature excitation spectra of Sm"3"+-, Dy"3"+- and Tm"3"+-activated Ca-#alpha#-SiAlON phosphors are interpreted as the N"3"--to-rare earth charge transfer transition (CTT). From the energies of the charge transfer transitions and from the optical data presented for the Eu"2"+ ion, the location of the divalent rare earth ion energy levels relative to the valence and the conduction band of Ca-#alpha#-SiAlON is derived. The salient features of the energy-level diagram are shown to be practical in explaining the temperature-dependent variations of the Eu"2"+ and Yb"2"+ luminescence efficiency in Ca-#alpha#-SiAlON. A comparative study pertaining to the nature of the Yb"2"+ and Eu"2"+ ion luminescence in Ca-#alpha#-SiAlON and in SrSi_2O_2N_2 is presented. A tentative energy-level diagram of the trivalent rare earth ions in Ca-#alpha#-SiAlON is also ...

2009-06-01

246

Optical properties of excitation spectra of (Ca,Y)-#alpha#-SiAlON:Eu yellow phosphors  

International Nuclear Information System (INIS)

Elemental substitution of Ca by Y was investigated for Ca-#alpha#-SiAlON:Eu yellow phosphors, which is useful for the white light-emitting diode lamps of phosphor conversion type. Depending on the ratio of the elemental substitution, not only the red shift of emission in wavelength occurred but also the figure of the excitation spectra changed. Their excitation band widths and flatness were discussed. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

2006-09-01

247

CaSnO3:. a high capacity anode material for Li-ion batteries  

Science.gov (United States)

Calcium stannate (CaSnO3) powders with the distorted perovskite structure have been synthesized by solid state and the sol-gel methods and their electrochemical performance was compared. The sol-gel CaSnO3 shows stable cycling performance with a reversible capacity of 430-440 mAh/g (0.005-1.0 V; 60 mA/g) up to 50 cycles. The role of preparatory conditions, morphology and cycling conditions (current density and potential window) on the anodic performance of the compounds are addressed.

2002-12-01

248

Synthesis and photo-degradation application of WO3/TiO2 hollow spheres  

British Library Electronic Table of Contents (United Kingdom)

A WO3/TiO2 composite, hollow-sphere photocatalyst with average diameter of 320nm and shell thickness of 50nm was successfully prepared using a template method. UV-vis diffuse reflectance spectra illustrated that the main absorption edges of the WO3/TiO2 hollow spheres were red-shifted compared to the TiO2 hollow spheres, indicating an extension of light absorption into the visible region of the composite photocatalyst. The WO3 and TiO2 phases were confirmed by X-ray diffraction analysis. BET isotherms revealed that the specific surface area and average pore diameter of the hollow spheres were 40.95m^2/g and 19nm, respectively. Photocatalytic experiments indicate that 78% MB was degraded by WO3/TiO2 hollow spheres under visible light within 80min. Under the same conditions, only 24% MB can ...

2011-01-01

249

Structural Characterization and Photoluminescent Properties of (La1-xSmx)2Ti2O7 Solid Solutions Synthesized by a Sol-Gel Route  

British Library Electronic Table of Contents (United Kingdom)

Abstract A series of compounds with the general formula (La1-xSmx)2Ti2O7 (0-- x --1.0) has been synthesized by a sol-gel method and characterized by XRD, Raman spectroscopy, and scanning electron microscopy (SEM). These compounds are structurally isomorphic to perovskite-type La2Ti2O7 until a substitution rate of x = 0.8. Above this substitution rate (x >-0.8), a biphasic mixture is obtained between the substituted perovskite layered phase and the pyrochlore Sm2Ti2O7 phase. The unusual phosphor (La1-xSmx)2Ti2O7 has been elaborated and its luminescent properties were investigated for low rates of substitution. The emission and excitation spectra were used to study the luminescent properties. The (La1.9Sm0.1)2Ti2O7 powders emit bright red-orange lightunder UV excitation. The emission propert...

2011-01-01

250

Stress-induced amorphization at moving crack tips in NiTi.  

Energy Technology Data Exchange (ETDEWEB)

In situ fracture studies on thin-film NiTi intermetallic compounds have been carried out in the high-voltage electron microscope at Argonne National Laboratory. Local stress-induced amorphization of regions directly in front of moving crack tips has been observed under tensile loading conditions. The stress-induced amorphization at crack tips exhibits a temperature dependence similar to that of ion-induced amorphization of NiTi. The upper limiting temperature for stress-induced amorphization is the same as that for ion-induced amorphization of crystalline NiTi and for amorphous phase formation during ion-beam mixing of Ni and Ti multilayer specimens. This upper limiting temperature of 600K is also the lowest temperature at which stress-induced amorphous phase crystallizes during isothermal annealing. This isothermal crystallization temperature is nearly 200K less than the kinetic crystallization ...

1998-01-29

251

Preparation, photocatalytic activities, and dye-sensitized solar-cell performance of submicron-scale TiO2 hollow spheres.  

Science.gov (United States)

We prepared submicron-scale spherical hollow particles of anatase TiO2 by using a polystyrene-bead template. The obtained particles were very uniform in size, with a diameter of 490 nm and a shell thickness of 30 nm. The Brunauer-Emmett-Teller surface area measurements revealed a large value of 70 m2/g. The photocatalytic property was investigated by the complete decomposition of gaseous isopropyl alcohol under UV irradiation. It was indicated that the activity of the hollow spheres was 1.8 times higher than that of the conventional P25 TiO2 nanoparticles with a diameter of 30 nm. Furthermore, we fabricated a dye-sensitized solar cell (DSC) using an electrode of the TiO2 hollow spheres, and examined the photovoltaic performance under simulated sunlight. Although the per-area efficiency was rather low (1.26%) because of a low area density of TiO2 on the electrode, the per-weight efficiency was 2.5 times ...

2007-12-19

252

Optimizing the microstructure of implant alloy TiAl5Fe2.5 by microprobe analysis  

International Nuclear Information System (INIS)

For optimizing the microstructure of the (#alpha# + #beta#)-titanium alloy TiAl5Fe2.5 the content of the two alloying elements aluminium and iron in the #alpha#- and #beta#-phase was determined by microprobe analysis. The alloys with the composition of the #alpha#- and of the #beta#-phase at 850 degC TiAl6Fe0.5 (#alpha#-phase) and TiAl3.5Fe6.5 (#beta#-phase) were prepared by arc melting and rolling at 850 degC. The mechanical properties of the '#alpha#'- and of the '#beta#'-phase-alloy are compared with the properties of the (#alpha# + #beta#)-alloy TiAl5Fe2.5 in the as rolled and swaged condition and after an additional aging at 550 degC. By this optimizing process it was possible to achieve a tensile strength of Rsub(m) = 1012 N/mm"2, an yield strength of Rsub(p0.2) 954 N/mm"2 and an elongation at fracture A = 14.5% in the TiAl5Fe2.5-alloy, although the degree of hot deformation ...

1985-05-13

253

Microwave absorption properties and infrared emissivities of ordered mesoporous C-TiO2 nanocomposites with crystalline framework  

International Nuclear Information System (INIS)

Ordered mesoporous C-TiO2 nanocomposites with crystalline framework were prepared by the evaporation-induced triconstituent co-assembly method. The products were characterized by XRD, TEM, N2 adsorption-desorption and TG. Their microwave absorption properties were investigated by mixing the product and epoxy resin. It is found that the peak with minimum reflection loss value moves to lower frequencies and the ordered mesoporous C-TiO2 nanocomposite possesses an excellent microwave absorbing property with the maximum reflection loss of -25.4 dB and the bandwidth lower than -10 dB is 6.6 GHz. The attenuation of microwave can be attributed to dielectric loss and their absorption mechanism is discussed in detail. The mesoporous C-TiO2 nanocomposites also exhibit a lower infrared emissivity in the wavelength from 8 to 14 ?m than that of TiO2-free powder. -- Graphical abstract: Ordered mesoporous ...

2010-12-01

254

Ferroelectric and magnetic properties of Ho{sub 2}CuTiO{sub 6} double perovskite  

Energy Technology Data Exchange (ETDEWEB)

Ho{sub 2}CuTiO{sub 6} double pervoskite is synthesized by solid state reaction method and the phase formation was confirmed by X-ray diffraction. Ho{sub 2}CuTiO{sub 6} crystallizes in space group P63 cm and are isostructural in AMnO{sub 3} structure. We have investigated the effect of the presence of a magnetic ion (Ho{sup 3+}{approx}10.4{mu}{sub B}) in Ho{sub 2}CuTiO{sub 6}, on the magnetic properties, compared to that of an isostructural double perovskite containing Y-ion (non-magnetic), i.e., Y{sub 2}CuTiO{sub 6}. Magnetization measurements on Ho{sub 2}CuTiO{sub 6} showed paramagnetic moment of 0.026{mu}{sub B}/Ho at room temperature in an applied field of 7 T although no saturation is observed at room temperature, whereas, at 5 K, the paramagnetic moment was 0.3{mu}{sub B}/Ho in the same field. Since this compound is non-centrosymmetric, it is of interest to look into the ...

2006-08-15

255

Dye-sensitized solar cells based on anatase TiO2 hollow spheres/carbon nanotube composite films  

British Library Electronic Table of Contents (United Kingdom)

Dye-sensitized solar cells (DSSCs) based on anatase TiO2 hollow spheres (TiO2HS)/multi-walled carbon nanotubes (CNT) nanocomposite films are prepared by a directly mechanical mixing and doctor blade method. The prepared samples are characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, UV-vis absorption spectroscopy and N2 adsorption-desorption isotherms. The photoelectric conversion performances of the DSSCs based on TiO2HS/CNT composite film electrodes are also compared with commercial-grade Degussa P25 TiO2 nanoparticles (P25)/CNT composite solar cells at the same film thickness. The results indicate that the photoelectric conversion efficiencies () of the TiO2HS/CNT composite DSSCs are dependent on CNT loading in the electrodes. A small amou...

2011-01-01

256

Creep ductility to failure of Alloy 800  

International Nuclear Information System (INIS)

Research is in progress to obtain a satisfactory creep ductility for alloy 800 when used as heat exchanger material in sodium-cooled fast reactors (LMFBR). The creep test characteristics at present available show that a pronounced tendency to reduced elongation by creep failure may arise after prolonged testing in the 500-700 deg C temperature range. This phenomenon is now agreed to be primarily inherent to the conditions for Ni_3(Ti,Al) precipitation in the material and hence to the Ti and Al concentrations. By structural studies and hardness measurements on material subjected to creep tests and taken from a large number of castings, the relationship was established between the (Ti+Al) content and the structural hardness effect of Ni_3(Ti,Al) at 600 deg C. Below a certain Ti+Al concentration, no precipitation occurs and hence the creep ductility to failure can be improved ...

257

caCORE version 3: Implementation of a model driven, service-oriented architecture for semantic interoperability  

British Library Electronic Table of Contents (United Kingdom)

One of the requirements for a federated information system is interoperability, the ability of one computer system to access and use the resources of another system. This feature is particularly important in biomedical research systems, which need to coordinate a variety of disparate types of data. In order to meet this need, the National Cancer Institute Center for Bioinformatics (NCICB) has created the cancer Common Ontologic Representation Environment (caCORE), an interoperability infrastructure based on Model Driven Architecture. The caCORE infrastructure provides a mechanism to create interoperable biomedical information systems. Systems built using the caCORE paradigm address both aspects of interoperability: the ability to access data (syntactic interoperability) and understand the ...

2008-01-01

260

The Huqf Supergroup of Oman: Basin development and context for Neoproterozoic glaciation  

British Library Electronic Table of Contents (United Kingdom)

The Huqf Supergroup of the Sultanate of Oman provides important information on the geological evolution of the Arabian?Persian Gulf region during a protracted period of continental dispersal and reassembly on the periphery of the Gondwanan supercontinent during the Neoproterozoic, and also provides important constraints on the nature of extreme climate swings during this critical period in the evolution of Earth's biosphere. The Huqf Supergroup spans the period ca. 725?540?Ma, and is composed of three groups. The Abu Mahara Group (ca. 725 to ca.ca. 547?540?Ma), which is known mostly from the subsurface, comprises carbonates, evaporites and organic-rich shales, with interbedded ashes, deposited in a large number of N?S trending troughs and platforms.The three groups of the Huqf Supergroup c...

2007-01-01

261

Studies about oxygen accumulation in palladium silicide formed at Pd/a-Si interface  

International Nuclear Information System (INIS)

Portuguese 1986. p. 186. Brazil Achete, CA Rio de Janeiro Univ. (Brazil).

1986-04-23

262

Small-molecule screen identifies inhibitors of a human intestinal calcium-activated chloride channel.  

Science.gov (United States)

Calcium-activated chloride channels (CaCCs) are widely expressed in mammalian tissues, including intestinal epithelia, where they facilitate fluid secretion. Potent, selective CaCC inhibitors have not been available. We established a high-throughput screen for identification of inhibitors of a human intestinal CaCC based on inhibition of ATP/carbachol-stimulated iodide influx in HT-29 cells after lentiviral infection with the yellow fluorescent halide-sensing protein YFP-H148Q/I152L. Screening of 50,000 diverse, drug-like compounds yielded six classes of putative CaCC inhibitors, two of which, 3-acyl-2-aminothiophenes and 5-aryl-2-aminothiazoles, inhibited by >95% iodide influx in HT-29 cells in response to multiple calcium-elevating agonists, including thapsigargin, without inhibition of calcium elevation, calcium-calmodulin kinase II activation, or cystic fibrosis transmembrane conductance ...

2007-12-14

263

Performance of Brazilian thermoluminescent CaSO{sub 4}: Dy pellets in standard diagnostic radiology beams  

Energy Technology Data Exchange (ETDEWEB)

The high sensitivity of CaSO{sub 4}: Dy as a thermoluminescent material is a great advantage when dealing with low dose levels, as in diagnostic radiology procedures. However, these kinds of dosemeters present a high energy dependence that must be precisely determined in the energy range of interest. Dosimetric pellets of CaSO{sub 4}: Dy are produced at IPEN since the end of the 80 Th decade. These pellets are produced in three forms: conventional CaSO{sub 4}: Dy (50 mg); thin CaSO{sub 4}: Dy (20 mg) and CaSO{sub 4}: Dy + 10% C (20 mg). The main applications of these dosemeters are in personal and environmental dosimetry. In this study, CaSO{sub 4}: Dy pellets produced at IPEN were evaluated in diagnostic radiology standard beams. These qualities are based on the IEC 61267 standard, and they were established at an industrial X-ray system Pantak/Seifert, model ...

2006-07-01

264

Minority Graduate Fellowship Awards  

Science.gov (United States)

... 60637 BIO-ORGAN U of Chicago/IL U of Michigan Ash, Marcus Alan 19C Escondido Village , Stanford CA ...

265

Light Weight Composite Mirrors for Science Instruments  

Science.gov (United States)

Light Weight Composite Mirrors for Science Instruments. Composite Optics, Inc. San Diego, CA. INNOVATION. Light weight, large aperture reflectors of graphite ...

266

Layered Organization in the Coastal Ocean: Acoustical Data ...  

Science.gov (United States)

... DV Holliday BAE SYSTEMS Applied Technologies, IES/ITS Analysis and Applied Research 4545A Viewridge Avenue San Diego, CA 92123 phone ...

2011-05-15

267

JPL Robotics: Group: Summer Employees ... - JPL Robotics - NASA  

Science.gov (United States)

Summer employees in the Robotics section for 2008. ... Activity: Will work on developing behaviors for UUV's. Alberto Ko, Caltech University, CA, SURF, Abhi ...

268

Intravascular pressure augments cerebral arterial constriction by inducing voltage insensitive Ca2+ waves  

British Library Electronic Table of Contents (United Kingdom)

This study examined whether elevated intravascular pressure stimulates asynchronous Ca2+ waves in cerebral arterial smooth muscle cells and if their generation contributes to myogenic tone development. The endothelium was removed from rat cerebral arteries, which were then mounted in an arteriograph, pressurized (20 100 mmHg) and examined under a variety of experimental conditions. Diameter and membrane potential (VM) were monitored using conventional techniques; Ca2+ wave generation and myosin light chain (MLC20)/MYPT1 (myosin phosphatase targeting subunit) phosphorylation were assessed by confocal microscopy and Western blot analysis, respectively. Elevating intravascular pressure increased the proportion of smooth muscle cells firing asynchronous Ca2+ waves as well as event frequency. C...

2010-01-01

269

Instrumental-activation analysis of Mo, Al, Ca, Mn, Cl, Na, and K in soil-plant samples  

International Nuclear Information System (INIS)

... activation analysis aluminium 28 calcium 49 chlorine 38 cotton plants li-drifted

270

Infrared Thermometer - NASA Spinoff  

Science.gov (United States)

May 1, 2011 ... Abstract: Diatek Corporation, San Diego, CA and the Jet Propulsion Lab developed the Diatek Model 7000 aural thermometer which weighs ...

271

Gastrointestinal absorption of lead in chicks: involvement of the cholecalciferol endocrine system  

Energy Technology Data Exchange (ETDEWEB)

The role of dietary calcium and phosphorus in modifying the intestinal absorption of lead and also the effect of lead ingestion on the metabolism of cholecalciferol were studied in chicks. The efficiency of absorption of /sup 203/Pb and /sup 47/Ca was increased when the animals were fed a low calcium diet and treated with cholecalciferol. The synthesis of the vitamin D-induced calcium-binding protein (CaBP) was correspondingly increased. When the chicks were depleted of vitamin D and repleted with 1,25-dihydroxycholecalciferol (1,25(OH)/sub 2/D/sub 3/) as their only source of the vitamin, the absorption of both /sup 47/Ca and /sup 203/Pb was unaffected by dietary calcium levels, and no change in CaBP levels occurred. Low dietary intake of phosphorus resulted in an increase in /sup 47/Ca and /sup 203/Pb absorption and in CaBP synthesis when the animals were ...

1984-04-01

272

Gastrointestinal absorption of lead in chicks: involvement of the cholecalciferol endocrine system  

International Nuclear Information System (INIS)

The role of dietary calcium and phosphorus in modifying the intestinal absorption of lead and also the effect of lead ingestion on the metabolism of cholecalciferol were studied in chicks. The efficiency of absorption of "2"0"3Pb and "4"7Ca was increased when the animals were fed a low calcium diet and treated with cholecalciferol. The synthesis of the vitamin D-induced calcium-binding protein (CaBP) was correspondingly increased. When the chicks were depleted of vitamin D and repleted with 1,25-dihydroxycholecalciferol [1,25(OH)_2D_3] as their only source of the vitamin, the absorption of both "4"7Ca and "2"0"3Pb was unaffected by dietary calcium levels, and no change in CaBP levels occurred. Low dietary intake of phosphorus resulted in an increase in "4"7Ca and "2"0"3Pb absorption and in CaBP synthesis when the animals were treated with cholecalciferol. ...

273

Effects of Climatic Variability and Land Use on American Drylands...  

Science.gov (United States)

Wildlife Refuge, CA Rare and endangered endemic plants Diana Anderson Northern Arizona University Geomorphology Kathryn Thomas USGS, Flagstaff, AZ Vegetation dynamics John...

2011-09-30

274

Don Edwards San Francisco Bay National Wildlife Refuge  

Science.gov (United States)

Don Edwards San Francisco Bay National Wildlife Refuge 9500 Thornton Ave. Newark, CA 94560 - 052...

275

Development and Performance of High Energy High ...  

Science.gov (United States)

... E. Liu, D. Soucy and J. Baughn GenCorp Aerojet, POBox 13222 Sacramento, CA 95813 J. Luoma BAE Systems Elk River, MN 55330 ABSTRACT ...

2006-11-01

277

Cape Mendocino, CA Earthquakes, April 25 & 26, 1992 - NASA  

Science.gov (United States)

Two additional earthquakes, magnitudes 6.6 and 6.7 occurred the next morning. The first earthquake was located six miles north of Petrolia, California, ...

278

7.5 Minute Hypsography for Timber Knob, CA  

Science.gov (United States)

(USGS Text) Digital line graph (DLG) data are digital representations of cartographic information. DLGs of map features are converted to digital form from ... ...

279

Theoretical investigations of strength of a flexible tube made of NiTi; Festigkeitstheoretische Untersuchungen einer flexiblen Huelse aus NiTi  

Energy Technology Data Exchange (ETDEWEB)

A flexible, steerable tube (distal end) of an endoscope for the application in the laparoscopic surgery has been analyzed by means of the finite-element-method (FEM). The unusual mechanical and thermal features of the used shape memory alloy (SMA) of NiTi were taken in account. The analyses showed that the strains remain in the super-elastic region up to the maximum bending of 90 and no plastic deformations occur. The application of the shape optimization (CAO) made possible finding the optimal structure of the distal end and therefore powerful reducing the maximum strains in the critical regions. (orig.)

2000-04-01

280

Radiation and thermal analysis of superconducting quadrupoles in the interaction region of linear collider  

Energy Technology Data Exchange (ETDEWEB)

CERN has encouraged the US-LARP collaboration to participate in Phase I of the LHC luminosity upgrade by analyzing the benefits gained by using Nb3Sn technology to replace the functionality of select NbTi magnets that CERN is committed to construct. Early studies have shown that the much higher gradients (shorter magnetic lengths) and temperature margins (quench stability) of Nb3Sn magnets compared to their NbTi counterparts is favorable--allowing the insertion of additional absorbers between Q1 and Q2, for example. This paper discusses the relative merits of the NbTi and Nb3Sn options.

2008-06-01

281

Processing and properties of novel high strength {gamma}-TiAl  

Energy Technology Data Exchange (ETDEWEB)

Extrusion and subsequent heat treatment of the alloys investigated can lead to reasonable room temperature ductilities and very high strengths being developed compared to the cast + HlPed material. In Ti-45Al-10Nb reasonably room temperature fracture toughness was developed which did not depend on extrusion temperature. For the alloy Ti-48Al-2Cr-0.2C a previously developed solution and ageing heat treatment did not increase the high temperature strength properties when compared to the 'annealed' condition. (orig.)

2000-07-01

282

Electron combinational light scattering in disordered Ti_x_-_1Fe_x alloys: theory and experiment  

International Nuclear Information System (INIS)

Theoretical description of Raman scattering in disordered alloys of Ti and Zr with transition metals of groups 5-8 of the Mendeleev Periodic System in critical range of concentrations (CRC) is given. Results of Raman scattering experiment in the system Ti_1_-_xF_x at 0.0005

283

tiAtiA ,', - NASA Technical Report Server (NTRS)  

Science.gov (United States)

the nozzle ring, the collector cup, and the impeller fuel-distribution ... sity of the vaned collector cup and the fuel-transfer passages ..... closure ...

284

Workability and Heat Treatment Characteristics of Beta ...  

Science.gov (United States)

... Accession Number : ADD135317. Title : Workability and Heat Treatment Characteristics of Beta Titanium Alloy, Ti-15V-3Cr-3Sn-3Al,. ...

1986-04-01

285

Two-step template-free route for synthesis of TiO2 hollow spheres  

British Library Electronic Table of Contents (United Kingdom)

The TiO2 hollow microspheres were prepared by microwave-assisted solvothermal treatment without template. The morphology and the phase of TiO2 hollow microspheres were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), high resolution transmission electron microscopy (HR-TEM), and BET surface areas. The results show that the particles have hollow structures and the shell was covered by nanocrystals and have higher specific surface area. The possible formation mechanism of hollow TiO2 spherical structures has simply been proposed. The activity was evaluated by the photocatalytic degradation of methyl orange (MO). The results show that the particles having specific surface area show higher photocatalytic activity. It can be attribute to the doped ...

2011-01-01

288

THE SUSCEPTAEILITY OF MATERIALS  

Science.gov (United States)

Hilled Bend Spechene of an Alpha-Beta Titanium Alloy. Ti-6M14V. ..... The all beta titanium alloy was nllled from both sides; only the edges were taped. ...

289

Structure and electric transport properties of LnSr_2FeTiO_7 (Ln = La, Nd and Gd)  

International Nuclear Information System (INIS)

Three new phases with compositions, LaSr_2FeTiO_7, NdSr_2FeTiO_7 and GdSr_2FeTiO_7, were prepared by the traditional ceramic method. Lazy-Pulverix analysis of the X-ray diffraction data suggests that the phases crystallize in the RP-type (n = 2) structure in the space group, I4/mmm. The cell dimensions along the c-axis decrease with decrease in size of the rare earth ions. Electrical resistivity, as a function of temperature, shows that the materials are insulators and the resistivity decreases with decrease in the size of the rare earth ion, which is attributed to increase in the three-dimensional character. (author)

2011-02-01

290

SCC mitigation method for BWR materials by TiO2 technique  

International Nuclear Information System (INIS)

TiO2 addition into boiling water reactor (BWR) primary system is being developed as a method to mitigate stress corrosion cracking (SCC) of the BWR structural materials. This technique aims for electrochemical corrosion potential (ECP) decrease of reactor materials by photo-excitation reaction under Cherenkov irradiation. ECP measurement tests have been conducted in the test loop in BWR to investigate the feasibility of the SCC mitigation method with TiO2. The test results showed that the ECP of TiO2 deposited materials was decreased to 2 technique was confirmed to be feasible as a SCC mitigation method for BWR structural materials without hydrogen injection. (author)

2008-10-13

291

Plane-wave-basis pseudopotential calculations of the surface relaxations of Ti(0001) and Zr(0001)  

International Nuclear Information System (INIS)

The relaxations of the Ti(0001) and Zr(0001) surfaces are studied using the plane-wave-basis pseudopotential method within the local-density approximation. We find that the first interlayer spacings of Ti(0001) and Zr(0001) are contracted with respect to the bulk spacings by 6.8% and 6.1%, respectively. Such large relaxations for the close-packed surfaces of Ti and Zr are in good agreement with recent linear-augmented-plane-wave calculations. In addition, we predict a weak vibrational effect on the surface relaxation of Zr(0001) by considering the free energy in the quasiharmonic approximation. This result can be attributed to a very strong bonding between the first- and second-layer Zr atoms as a consequence of the bond-order endash bond-length correlation. copyright 1997 The American Physical Society.

292

Part Repairing Using A Hybrid Manufacturing System (Preprint ...  

Science.gov (United States)

... [11]Richter, K., Orban, S., and Nowotny, S., Laser cladding of the titanium alloy TI6242 to restore damaged blades, Proceedings of the 23rd ...

2007-03-01

293

Observation of the microstructural changes in lithium titanate by multi-ion irradiation  

Energy Technology Data Exchange (ETDEWEB)

The irradiation behavior of Li{sub 2}TiO{sub 3} under a fusion reactor environment was simulated by simultaneous irradiation of Li{sub 2}TiO{sub 3} by the triple ion beams and the respective single ion beams of O{sup 2+}, He{sup +} and H{sup +}. The microstructural changes in Li{sub 2}TiO{sub 3} caused by the irradiation were measured by Raman spectroscopy and FT-IR photoacoustic spectroscopy. The results suggest that the formation of TiO{sub 2} due to displacements by irradiation occurs, and the irradiation defects generated by irradiation trap hydrogen and increase the amount of hydroxyl near the surface. Such phenomena are believed to significantly affect the chemical form of the released tritium and the tritium inventory in the breeding materials of a fusion reactor.

2004-08-01

294

Observation of the microstructural changes in lithium titanate by multi-ion irradiation  

International Nuclear Information System (INIS)

The irradiation behavior of Li_2TiO_3 under a fusion reactor environment was simulated by simultaneous irradiation of Li_2TiO_3 by the triple ion beams and the respective single ion beams of O"2"+, He"+ and H"+. The microstructural changes in Li_2TiO_3 caused by the irradiation were measured by Raman spectroscopy and FT-IR photoacoustic spectroscopy. The results suggest that the formation of TiO_2 due to displacements by irradiation occurs, and the irradiation defects generated by irradiation trap hydrogen and increase the amount of hydroxyl near the surface. Such phenomena are believed to significantly affect the chemical form of the released tritium and the tritium inventory in the breeding materials of a fusion reactor.

2004-08-01

295

Morphology evolution of Ir-Nb-X (X = Hf, Ta, or Ti) ternary alloys  

Energy Technology Data Exchange (ETDEWEB)

The microstructure evolution of nine samples from three Ir-base ternary systems, Ir-Nb-Hf, Ir-Nb-Ta, and Ir-Nb-Ti, was investigated by microstructure observation using scanning electron microscopy (SEM), composition map-analysis using electron probe microscopy analysis (EPMA), and phase determination using X-ray diffraction (XRD) patterns. The fcc/L1{sub 2} two-phase structure was detected in all the samples. Lattice misfits between fcc and L1{sub 2} phases were calculated. Ir-Nb-Ta and Ir-Nb-Ti alloys exhibited a microstructure quite similar to that of Ni-base superalloys, and the cuboidal L1{sub 2} precipitates in Ir-Nb-Ta and Ir-Nb-Ti alloys could maintain up to 1900 {sup o}C.

2007-01-31

297

Metal-Matrix Composite Processing Technologies for Aircraft ...  

Science.gov (United States)

... ge aircraft engines (geae) has taken to development an induction plasma deposition (ipd) processing method for the fabrication of ti6242/sic mmc ...

298

Mechanism of r. f. plasma nitriding of Ti-6Al-4V alloy  

Energy Technology Data Exchange (ETDEWEB)

The objective of the current study was the gradual development of the formation of the nitride layer during inductive r.f. plasma nitriding. The study centers on characterization of refined layers and plasma diagnostics in the vicinity of the sample, and raises critical questions of how the layers and interfacial microstructure might affect the near-surface properties. The composition of the plasma near the surface of the sample (plasma layer) was examined by optical emission spectroscopy and mass spectrometry during plasma nitriding and while sputtering the sample after the nitriding process. It was observed that during the nitriding process, the plasma layer contains Ti, NH[sub n] species, N (or/and N[sup +]), H[sub n] species (or/and H[sup +][sub 2]). However, when the nitrided sample was exposed to argon plasma, Ti, Al and NH were observed. It was found that two distinct sublayers, comprising [delta]-TiN and ...

1993-08-15

299

Mechanical properties, interface reactions and transport current densities of multi-core MgB_2/Ti/Cu/SS wire  

International Nuclear Information System (INIS)

Multi-core MgB_2/Ti/Cu/SS composite wire has been made by the in situ approach. Mechanical properties, interdiffusion reactions and critical currents were studied after heat treatments at temperatures between 500 and 850 "0C. Cu diffusion into the Ti layer occurs for all samples, resulting in the formation of intermetallic compounds at the Cu/Ti interface. EDX analysis has revealed the temperature dependence of all interface reactions. In spite of element reactions the critical current densities 10"5 A cm"-"2 and 10"4 A cm"-"2 were measured in liquid helium at magnetic fields 5 T and 9.5 T, respectively. 10"4 A cm"-"2 at 20 K is measured in an external field of 4 T.

2010-07-01

300

METAShield - NASA Technical Report Server (NTRS)  

Science.gov (United States)

alloy (Ti6242 or T i l 100) was utilized. Parametric studies were performed to investigate variations of displacements and stresses with sandwich and ...

301

Low temperature superplasticity of a metastable #beta#-titanium alloy  

International Nuclear Information System (INIS)

Superplasticity in Ti alloys has been widely investigated in the past and superplastic forming of aerospace components has thus been developed over the last two decades. The Ti alloy most studied in this framework is undoubtedly the Ti-6Al-4V (wt %) alloy, for which maximum elongations are obtained in the temperature range [880-900C]. The development of the superplastic properties has been demonstrated to be in close relation with quite similar volume fractions of the #alpha# and #beta# phases, the #beta# transus temperature for this alloy ranging from 980-1000 C. Attempts have been carried out to reduce the temperature of superplastic forming of Ti-6Al-4V by the addition of elements like Fe, Co, or Ni. Such an introduction of alloying elements indeed results in a decrease of the optimum forming temperature to values as low as 820 C. This decrease is mainly attributed to a change in the phase volume ...

302

Low cost fabrication of sheet structure using a new beta titanium alloy, Ti-15V-3Cr-3Al-3Sn  

Science.gov (United States)

Development efforts have been undertaken to improve the processing and structural efficiencies of

1982-01-01

303

Increased performance of bearings using TiC-coated balls  

Energy Technology Data Exchange (ETDEWEB)

The main purpose of solid or fluid lubricants in ball-bearings is to separate the balls and races from contacting each other in so-called asperity collisions. Steel to steel contacts lead to microwelds which roughen functional rolling-contacting surfaces and deteriorate the lubricant. By using balls with a ceramic TiC coating, two goals are achieved. First, there are fewer asperity collisions because of the extreme smoothness of the high precision polished TiC coated balls. Second, if collisions do occur, there is practically no microwelding taking place, leaving the surfaces and the lubricant in good condition. Examples are given where the bearing lifetime is increased up to 10 times if the steel balls are replaced by TiC-coated balls. (orig.).

1993-11-01

305

Effects of Yttrium Microalloying on the Epitaxial Grain Growth ...  

Science.gov (United States)

... Accession Number : ADA137272. Title : Effects of Yttrium Microalloying on the Epitaxial Grain Growth in Ti-6Al-4V Weld Fusion Zones. ...

1983-10-01

306

Dynamic Weapon-Target Assignment Problems with ...  

Science.gov (United States)

... defense's weapons are Space-based kinetic-kill vehicles ... I ti I obtained by dividing the weapons as ... of the optimal weapon-arge assigntments and ...

1988-06-01

307

Cooperative Effects on Transient Spectral Hole Burning  

Science.gov (United States)

... of Dist SpeA tI/ __LLL5' Page 5. 3 the coherent effects on the spontaneous radiation, we calculate the pump- field-induced ...

1992-06-01

308

Collaborative Research and Development (CR&D). Delivery ...  

Science.gov (United States)

... 7 Page 11. Figure 5. Diffraction pattern shown a and ~ slip directions with the associated misalignment for single colonies of Ti6242 [2]. 8 Page 12. -- ...

2005-10-01

309

Catalytic wet air oxidation of phenol over CeO{sub 2}-TiO{sub 2} catalyst in the batch reactor and the packed-bed reactor  

Energy Technology Data Exchange (ETDEWEB)

CeO{sub 2}-TiO{sub 2} catalysts are prepared by coprecipitation method, and the activity and stability in the catalytic wet air oxidation (CWAO) of phenol are investigated in a batch reactor and packed-bed reactor. CeO{sub 2}-TiO{sub 2} mixed oxides show the higher activity than pure CeO{sub 2} and TiO{sub 2}, and CeO{sub 2}-TiO{sub 2} 1/1 catalyst displays the highest activity in the CWAO of phenol. In a batch reactor, COD and TOC removals are about 100% and 77% after 120 min in the CWAO of phenol over CeO{sub 2}-TiO{sub 2} 1/1 catalyst at reaction temperature of 150 {sup o}C, the total pressure of 3 MPa, phenol concentration of 1000 mg/L, and catalyst dosage of 4 g/L. In a packed-bed reactor using CeO{sub 2}-TiO{sub 2} 1/1 particle catalyst, over 91% COD and 80% TOC removals are obtained at the reaction temperature of 140 {sup o}C, the air total pressure of ...

2008-05-30

310

Anisotropic exchange in frustrated pyrochlore Yb2Ti2O7  

International Nuclear Information System (INIS)

The local Yb3+ magnetic susceptibility tensor was recently measured in the frustrated pyrochlore compound Yb2Ti2O7 by means of in-field polarized neutron scattering in a single crystal. A very anisotropic effective exchange tensor was derived for the Yb3+ ion. Using this result, we reinterpret here the data for the powder susceptibility in Yb2Ti2O7. We show that, in the case of a well-isolated Kramers doublet with anisotropic g and exchange tensors, the inverse susceptibility for a powder sample does not strictly obey a Curie-Weiss law at low temperature. We discuss the consequences regarding the paramagnetic Curie temperature, usually taken as a measure of the exchange/dipolar interaction, and the exotic 'slow fluctuation' ground state of Yb2Ti2O7. (fast track communication)

2009-12-09

311

Amperometric biosensor for hydrogen peroxide based on horseradish peroxidase onto gold nanowires and TiO2 nanoparticles  

British Library Electronic Table of Contents (United Kingdom)

An electrochemical biosensor for determination of hydrogen peroxide (H2O2) was fabricated, based on the electrostatic immobilization of horseradish peroxidase (HRP) with one-dimensional gold nanowires (Au NWs) and TiO2 nanoparticles (nano-TiO2) on a gold electrode. The nano-TiO2 can give a biocompatible microenvironment and compact film, and the Au NWs can provide fast electron transferring rate and greatly add the amount of HRP molecules immobilized on the electrode surface. Au NWs were characterized by ultraviolet?visible spectra and transmission electron microscope. The electrode modification process was probed by cyclic voltammetry and electrochemical impedance spectroscopy. Chronoamperometry was used to study the electrochemical performance of the resulting biosensor. Under optimal co...

2011-01-01

312

Alcoa titanium alloy Ti-10V-2Fe-3Al forgings -- Data sheets  

International Nuclear Information System (INIS)

Ti-10V-2Fe-3Al is high strength, metastable beta titanium alloy developed by the Timet Division, Titanium Metals Corporation of America for enhanced forgeability and excellent mechanical property combinations, including deep hardening characteristics. Ti-10-2-3 has been the subject of intense thermomechanical processing (TMP) development and reduction to commercial practice for the full range of open die, closed-die and precision forged products utilized in aerospace and other applications. With commercially proven TMP, Ti-10-2-3 forgings provide a range of strength-fracture toughness combinations from 180 Ksi (1,240 MPa) minimum U.T.S. to 140 Ksi (965 MPa) minimum U.T.S with commensurate fracture toughness. With optimal TMP and these strength-toughness combinations, Ti-10-2-3 forgings are found provide superior smooth and notched fatigue properties critical to aerospace applications over incumbent ...

1993-02-21

313

A simple one-step fabrication of micrometer-scale hierarchical TiO2 hollow spheres  

British Library Electronic Table of Contents (United Kingdom)

Hierarchical TiO2 hollow spheres had been prepared based on bubble templates by a simple one-step hydrothermal method. The diameter of hollow spheres was about 700nm and the shell thickness of them was 69nm. They were composed of similar spindle- or needle-like building units. Furthermore, hydrothermal time had an important influence on the morphology and crystallinity of hollow spheres. Moreover, the UV-Vis diffuse reflectance spectra of TiO2 hollow spheres heated at 150^oC for 10h showed the strongest absorption in the UV-Vis region and the Raman spectrum demonstrated the anatase sample. Additionally, a possible formation mechanism of TiO2 hollow spheres was proposed. So this novel and simple method would provide a development direction to fabricate all kinds of inorganic hollow spheres ...

2010-01-01

314

A novel single-step synthesis of N-doped TiO"2 via a sonochemical method  

British Library Electronic Table of Contents (United Kingdom)

A novel single-step synthetic method for the preparation of anatase N-doped TiO"2 nanocrystalline at low temperature has been devoleped. The N-doped anatase TiO"2 nanoparticles were synthesized by sonication of the solution of tetraisopropyl titanium and urea in water and isopropyl alcohol at 80^oC for 150min. The as-prepared sample was characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy and UV-vis absorption spectrum. The product structure depends on the reaction temperature and reaction time. The photocatalytic activity of the as-prepared photocatalyst was evaluated via the photodegradation of an azo dye direct sky blue 5B. The results show that the N-doped TiO"2 nanocrystalline prepared via sonication exhibit an excellent photocatalytic...

2011-01-01

315

A micro-alloyed ferritic steel strengthened by nanoscale precipitates  

British Library Electronic Table of Contents (United Kingdom)

A ferritic steel with finely dispersed precipitates was investigated to reveal the fundamental strengthening mechanisms. The steel has a yield strength of 760MPa, approximately three times higher than that of conventional Ti-bearing high strength hot-rolled sheet steels, and its ultimate tensile strength reaches 850MPa with an elongation-to-failure value of 18%. Using energy dispersive X-ray spectroscopy (EDXS) and transmission electron microscope (TEM), fine carbides TiC with an average diameter of 10nm were observed in the ferrite matrix of the 0.08%Ti steel, and some cubic M23C6 precipitates were also observed at the grain boundaries and the interior of the grains. The finely dispersed TiC precipitates in the matrix provide matrix strengthening. The estimated magnitude of precipitation ...

2011-01-01

317

Follicle-stimulating hormone receptor-mediated uptake of "4"5Ca"2"+ by cultured rat Sertoli cells does not require activation of cholera toxin- or pertussis toxin-sensitive guanine nucleotide binding proteins or adenylate cyclase  

International Nuclear Information System (INIS)

We have previously reported that FSH stimulates flux of 45Ca2+ into cultured Sertoli cells from immature rats via voltage-sensitive and voltage-independent calcium channels. In the present study, we show that this effect of FSH does not require cholera toxin (CT)- or pertussis toxin (PT)-sensitive guanine nucleotide binding (G) protein or activation of adenylate cyclase (AC). Significant stimulation of 45Ca2+ influx was observed within 1 min, and maximal response (3.2-fold over basal levels) was achieved within 2 min after exposure to FSH. FSH-stimulated elevations in cellular cAMP paralleled increases in 45Ca2+ uptake, suggesting a possible coupling of AC activation to 45Ca2+ influx. (Bu)2cAMP, however, was not able to enhance 45Ca2+ uptake over basal levels at a final concentration of 1000 microM, although a concentration-related increase in androstenedione conversion to estradiol ...

1990-01-01

318

Effects of Multi-ion Irradiation on Microstructural Changes in Lithium Titanate  

Energy Technology Data Exchange (ETDEWEB)

Full text of publication follows: Li{sub 2}TiO{sub 3} is regarded as one of the most suitable candidates for the solid tritium breeder material of D-T fusion reactors. It is known that, in an operating fusion reactor, the radiation damage in Li{sub 2}TiO{sub 3} will be caused by fast neutrons, energetic tritons and helium ions generated in {sup 6}Li(n,{alpha}){sup 3}H reaction. The irradiation damage caused by such radiation may result in the microstructural changes, and the changes may affect the characteristics of Li{sub 2}TiO{sub 3} such as tritium release behavior. Thus the study of irradiation defects and microstructural changes caused by irradiation in Li{sub 2}TiO{sub 3} is essential to evaluate its irradiation performance. Simulation of the fusion reactor environment and hence the study of a synergistic effect of atomic displacement damage in Li{sub 2}TiO{sub 3} are ...

2007-07-01

319

Time-varying magnetic fields increase cytosolic free Ca sup 2+ in HL-60 cells  

Energy Technology Data Exchange (ETDEWEB)

Electromagnetic fields have been reported to cause a variety of biological effects. It has been hypothesized that many of these phenomena are mediated by a primary effect on the concentration of cytosolic free calcium ((Ca2+)i). We investigated the effects of exposure to electromagnetic fields on (Ca2+)i in HL-60 cells using the Ca2(+)-sensitive fluorescent indicator indo-1. Indo-1-loaded cell samples were exposed to a radiofrequency electromagnetic field, a static magnetic field, and a time-varying magnetic field, which were generated by a magnetic resonance imaging (MRI) unit. We found that a 23-min exposure to all three fields, in combination, induced a significant increase in (Ca2+)i of 31 +/- 8 (SE) nM (P less than 0.01, n = 13) from a basal level of 121 +/- 8 nM. Also, cells exposed to only the time-varying magnetic field had a mean (Ca2+)i that was 34 +/- 10 nM (P less than ...

1990-10-01

320

Thermographic studies of the interaction between hydrolyzed polyacrylonitrile and Ca/sup 2 +/, Fe/sup 3 +/, Cu/sup 2 +/ ions  

Energy Technology Data Exchange (ETDEWEB)

Reasons were revealed for the fresh water resistance of sediments of hydrolyzed polyacrylonitrile obtained from interaction of it with Fe/sup 3 +/, Ca/sup 2 +/ and Cu/sup 2 +/ cations which are in the saline solutions of these metals.

1982-01-01

321

Theoretical studies of metal-phosphate interactions: interaction of Li+, Na+, K+, Be++, Mg++, and Ca++ with H2PO4- and (CH3O)2PO2-: implications for nucleic acid solvation.  

UK PubMed Central (United Kingdom)

Model phosphate-metal solvation complexes have been studied by ab-initio self-consistent-field techniques. The complexes studied include (RO)2PO2-(R = H or CH3) with Li+, Na+, K+, Be++, Mg++, Ca++,...Full Text Available

1975-10-01

322

Selective Expression in Carotid Body Type I Cells of a Single Splice Variant of the Large Conductance Calcium- and Voltage-activated Potassium Channel Confers Regulation by AMP-activated Protein Kinase*  

UK PubMed Central (United Kingdom)

Inhibition of large conductance calcium-activated potassium (BKCa) channels mediates, in part, oxygen sensing by carotid body type I cells. However, BKCa channels remain active...Full Text Available

2011-04-08

323

Role of E-cadherin in the induction of apoptosis of HPV16-positive CaSki cervical cancer cells during multicellular tumor spheroid formation.  

Science.gov (United States)

Multicellular tumor spheroids (MCTS) are three dimensional cell culture systems induced by suspension culture. MCTS are widely used in cancer research because of their similarity to solid tumors. CaSki cells are derived from a metastatic cervical cancer containing human papillomavirus 16 (HPV16). Cell death of CaSki cells in MCTS has been previously reported, and our model is used to better characterize the mechanisms of cell death of HPV16-positive keratinocytes. In this study, we found that apoptosis of CaSki cells was induced by suspension culture along with the formation of MCTS after 24 h of incubation. In suspended CaSki cells, monoclonal antibodies blocking E-cadherin function inhibited MCTS formation and suppressed suspension-induced apoptosis in a dose-dependent manner. Western blot for E-cadherin detected upregulation of the authentic 120 kDa band from MCTS of CaSki cells ...

2008-01-01

324

Optical properties and infrared-stimulated luminescence from oxygen vacancies in CaO crystals containing hydrogen  

International Nuclear Information System (INIS)

Optical absorption measurements show that substitutional H"- ions, that is, protons with two electrons on anion sites, are thermally more stable than anion vacancies when thermochemically reduced CaO crystals are annealed in a reducing atmosphere. The H"- ions are identified by the infrared vibrational modes observed at 880 and 911 cm"-"1.

1985-03-01

325

Inactivating calcium-sensing receptor mutations in patients with primary hyperparathyroidism.  

Science.gov (United States)

Objective:? Primary hyperparathyroidism (HPT) is characterised by autonomous secretion of PTH from enlarged parathyroid glands leading, in most patients, to asymptomatic hypercalcaemia. Familial hypocalciuric hypercalcaemia (FHH) is an autosomal dominant disorder caused by inactivating mutations in the calcium sensing receptor (CaSR) gene; it is characterised by lifelong and usually asymptomatic hypercalcaemia. Establishing the correct diagnosis is important because surgery can be curative in HPT, but ineffective in FHH. There is overlap in the diagnostic criteria for the two disorders and some patients carrying inactivating mutations in the CaSR gene, which is suggestive of FHH, also have HPT with hyperplastic parathyroid glands or adenomas. Design and Patients:? CaSR gene mutations were analyzed and clinical and biochemical parameters evaluated in 139 consecutive out-patients presenting with hypercalcaemia and suspected ...

2011-03-29

326

Helminthosporium maydis T toxin decreased calcium transport into mitochondria of susceptible corn  

Energy Technology Data Exchange (ETDEWEB)

The effects of purified Helminthosporium maydis T (HmT) toxin on active Ca/sup 2 +/ transport into isolated mitochondria and microsomal vesicles were compared for a susceptible (T) and a resistant (N) strain of corn (Zea mays). ATP, malate, NADH, or succinate could drive /sup 45/Ca/sup 2 +/ transport into mitochondria of corn roots. Ca/sup 2 +/ uptake was dependent on the proton electrochemical gradient generated by the redox substrates or the reversible ATP synthetase, as oligomycin inhibited ATP-driven CA/sup 2 +/ uptake while KCN inhibited transport driven by the redox substrates. Purified native HmT toxin completely inhibited Ca/sup 2 +/ transport into T mitochondria at 5 to 10 nanograms per milliliter while transport into N mitochondria was decreased slightly by 100 nanograms per milliliter toxin. Malate-driven Ca/sup 2 +/ transport in T mitochondria was ...

1984-04-01

327

Effects of bladder outlet obstruction on properties of Ca2+-activated K+ channels in rat bladder  

UK PubMed Central (United Kingdom)

In this study, we investigated the effects of bladder outlet obstruction (BOO) on the expression and function of large conductance (BK) and small conductance (SK) Ca2+-activated K+...Full Text Available

2010-05-01

328

Effect of vitamin D on the intestinal absorption of 203Pb and 47Ca in chicks  

Energy Technology Data Exchange (ETDEWEB)

The transfer of 203Pb and/or 47Ca across the intestinal epithelium of the chick was investigated, with emphasis given to the functional role of cholecalciferol (vitamin D-3). 203Pb, after introduction in the intestinal lumen, is rapidly accumulated by the intestinal tissue, and only a fraction of 203Pb is translocated parenterally (absorbed). Cholecalciferol did not significantly affect the accumulation of 203Pb by intestinal tissue but did accelerate 203Pb movement across the basal-lateral membrane. In contrast, cholecalciferol both decreased 47Ca tissue levels and increased 47Ca absorption. In rachitic chicks, the rate of absorption of 203Pb was greater in the distal than in the proximal segments of the intestine; after cholecalciferol repletion, the degree of absorption in al segments was similar, indicting the order of cholecalciferol effectiveness as duodenum greater than or equal to jejunum greater than ileum. An ...

1982-03-01

329

Effect of vitamin D on the intestinal absorption of /sup 203/Pb and /sup 47/Ca in chicks  

Energy Technology Data Exchange (ETDEWEB)

The transfer of /sup 203/Pb and/or /sup 47/Ca across the intestinal epithelium of the chick was investigated, with emphasis given to the functional role of cholecalciferol (vitamin D-3). /sup 203/Pb, after introduction in the intestinal lumen, is rapidly accumulated by the intestinal tissue, and only a fraction of /sup 203/ Pb is translocated parenterally (absorbed). Cholecalciferol did not significantly affect the accumulation of /sup 203/Pb by intestinal tissue but did accelerate /sup 203/Pb movement across the basal-lateral membrane. In contrast, cholecalciferol both decreased /sup 47/Ca tissue levels and increased /sup 47/Ca absorption. In rachitic chicks, the rate of absorption of /sup 203/Pb was greater in the distal than in the proximal segments of the intestine; after cholecalciferol repletion, the degree of absorption in all segments was similar, indicating the order of cholecalciferol effectiveness as duodenum ...

1982-03-01

330

Effect of total pressure on sulfur capture of Ca-ion exchanged coal; Kaatsu jokenka ni okeru Ca-tanjitan no datsuryu koka  

Energy Technology Data Exchange (ETDEWEB)

In relation to coal gasification and combustion under high pressure as highly efficient coal utilization, the effect of total pressure and sintering on the SO2 capture ability of Ca-ion exchanged coal and other desulfurizing agents were studied. In experiment, specimens were filled into a small pressurized reactor to heat them under high-pressure N2 atmosphere. After the completion of combustion reaction of char at 850{degree}C, SO2, CO2 and CO gases were measured at an outlet while flowing SO2/N2. As the experimental result, all of the S content in Ca-ion exchanged coal was not absorbed by Ca content in coal during pyrolysis and combustion, resulting in discharge of 36% of the S content. Since Ca-ion exchanged coal is fast in combustion reaction, most of the S content was desulfurized by coal ash. The ash content yielded from Ca-ion exchanged coal was more excellent in SO2 capture ...

1996-10-28

331

Differential Roles for STIM1 and STIM2 in Store-Operated Calcium Entry in Rat Neurons  

UK PubMed Central (United Kingdom)

The interaction between Ca2+ sensors STIM1 and STIM2 and Ca2+ channel-forming protein ORAI1 is a crucial element of ...Full Text Available

332

Densities and molar volumes of molten alkaline earth bromide - alkali bromide salt mixtures  

International Nuclear Information System (INIS)

The temperature and concentration dependence of the densities of binary CaBr_2-(Li, Na, K, Rb, Cs)Br, NaBr-(Sr, Ba)Br_2 and KBr-SrBr_2 mixtures have been measured using the method of hydrostatic weighing. With exception of the systems LiBr-CaBr_2 and NaBr-(Sr, Ba)Br_2 the calculated molar excess volumes are positiv in the investigated mixtures. (author).

1980-01-01

333

A Real-Time US Army Tactical Telephone Network ...  

Science.gov (United States)

... To CA 2 TOM 2 L= DTO 2 4 9"ylem 2 a Systsm2OTO 3 Figure 25: Node I C-5 Internal Connectivity C5 DTO 2 GM I sy~stm I 1 RC-IOS L3 To CA ...

1993-09-01

334

The non-linear fitting method to analyze the measured M-S plots of bipolar passive films  

Energy Technology Data Exchange (ETDEWEB)

Mott-Schottky (M-S) analysis is an effective approach to investigate the electronic property of passive films of metals, and it is well suitable for the passive film with single space charge capacitance. But there is no proper method to analyze the C{sub sc}{sup -2} vs. V{sub m} plots of passive films with several space charge capacitances in series connection, such as bipolar passive films. In this paper, the relationship between the space charge capacitance of the bipolar passive film and the applied potential was deduced and the features of corresponding plots were given out simultaneously. Accordingly, a non-linear fitting method was presented to analyze the C{sub sc}{sup -2} vs. V{sub m} plots of bipolar passive films. Then the method was used to study the semiconductor characteristics of bipolar passive films formed on the surface of Nickel base alloy after being corroded in the environments with high temperatures and high partial ...

2010-02-28

335

Low-temperature properties of ternary magnetic rare-earth transition-metal germanides with the Sc sub 5 Co sub 4 Ge sub 10 -type structure  

Energy Technology Data Exchange (ETDEWEB)

DC resistivity, dc magnetization, and specific heat of eight Sc{sub 5}Co{sub 4}Ge{sub 10}-type crystal-structure compounds R{sub 5}T{sub 4}Ge{sub 10} for R = Dy, Ho, Er, Tm, and T = Rh and Ir are presented. The resistivity, single-crystal magnetization, and specific-heat results show that in all those compounds, the magnetic moments order antiferromagnetically in the c direction at low temperature. However, in the Er and Tm compounds, the magnetizations along x-y hard directions do not show any anomalies above 2.0 K. This suggests that the ordered Er and Tm ions, which have positive quadrupole coefficients, interact with a crystal field that has an electronic potential valley along the c axis. The fitting of the hard axis magnetizations to Curie-Weiss law suggests that the resulting antiferromagnetic-like {theta} reflects the strength of the crystal-field torque on the magnetic moments rather than the strength of antiferromagnetic exchange.

1988-01-01

336

Low temperature properties of ternary magnetic rare earth transition metal germanides with the Sc/sub 5/Co/sub 4/Ge/sub 10/-type structure  

Energy Technology Data Exchange (ETDEWEB)

DC resistivity, dc magnetization, and specific heat of eight Sc/sub 5/Co/sub 4/Ge/sub 10/-type crystal structure compounds R/sub 5/T/sub 4/Ge/sub 10/ for R = Dy, Ho, Er, Tm, and T = Rh and Ir are presented. The resistivity, single crystal magnetization, and specific heat results show that in all those compounds, the magnetic moments order antiferromagnetically in the c direction at low temperature. However, in the Er and Tm compounds, the magnetizations along x-y hard directions do not show any anomalies above 2.0 K. This suggests that the ordered Er and Tm ions, which have positive quadrupole coefficients ..cap alpha../sub j/, interact with a crystal field that has an electronic potential valley along the c axis. The fitting of the hard axis magnetizations to Curie-Weiss law suggests that the resulting antiferromagnetic-like theta reflects the strength of the crystal field torque on the magnetic moments rather than the strength of antiferromagnetic exchange. 123 ...

1988-07-01

337

Influence of sewage sludge compost applications on uptake of element by cultivated crops in a brown forest soil. Measurement by neutron activation analysis  

International Nuclear Information System (INIS)

A field study was conducted to investigate the absorption of various elements into oats and carrots cultivated in brown forest soil after three years' applications of chemical fertilizer and two types of sewage sludge compost mixed with sawdust (SD compost) or rice husk (RH compost). The results obtained in this study are summarized as follows. 1) The application of SD compost led to a significant increase on the concentrations of Mn, Zn, Ag and Ba in oat root, of Zn and Br in oat shoot, of Cl and Zn in oat ears, of Mg, Sc, Mn, Zn, Br, Ba and La in carrot peel, of Mn, Fe, Co and Zn in carrot edible portion and of Na, Sc, Mn, Fe, Co and Sm in carrot shoot. 2) The application of RH compost increased the concentrations of Mn, Zn, and Ag in oat root, of K, Cr, Mn, Zn and Br in oat shoot, of Zn and Br in oat ears, of Mg, Mn and Br in carrot peel, of Cl, Mn, Zn and Br in carrot edible portion and of Na, Mn, Zn, Br and Sm in carrot shoot. (author)

2006-03-01

338

Charged species in the radiolysis of supercritical CO{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

The pulse radiolysis technique has been employed in studying charge-transfer reactions of anionic C{sub 2}O{sub 4}{sup {minus}}, and cationic C{sub 2}O{sub 4}{sup +} species in supercritical carbon dioxide (scCO{sub 2}) over a range of reduced densities {rho}{sub r} = 0.36--1.5 and at a reduced temperature of T{sub r} = 1.03. The absorption spectrum measured in the visible region with a maximum around 700 nm is assigned to the dimer cation C{sub 2}O{sub 4}{sup +}. The pressure dependence of charge-transfer reactions was examined using dimethylaniline (DMA), benzoquinone (BQ), and oxygen as charge acceptors. The reaction rates of DMA with cations, and BQ with anions are at or near the diffusion-controlled limit. The rates decrease an order of magnitude with increase of pressure. The reaction of C{sub 2}O{sub 4}{sup +} with oxygen is much slower with an almost constant rate over the pressure range examined. The measured rate constants of electron-transfer reactions ...

2000-01-27

339

A thermal-hydraulic drift-flux based mixture-fluid model for the description of single- and two-phase flow along a general coolant channel  

Energy Technology Data Exchange (ETDEWEB)

Full text of publication follows: Different to the very simple class of homogeneous non-equilibrium models (HEM) an one dimensional thermal-hydraulic theoretical drift-flux based and thus non-homogeneous coolant channel model and, as a result, an in itself complete thermal-hydraulic coolant channel module CCM have been established allowing to simulate in a very general way the steady state and transient behaviour of the most important parameters of a single- or two-phase fluid flowing within any type of heated or non-heated coolant channel (with an eventually varying cross flow area). To avoid mathematical discontinuities at the transition from single- to two-phase flow the coolant channel will, in its general form, be split into different regions, i.e. be looked as a basic channel (BC) which can consist of a number of different flow regimes and can, accordingly, be subdivided into a number of sub-channels (SC-s). All of them belong, obviously, to only two types of ...

2005-07-01

340

A CD33-specific single-chain immunotoxin mediates potent apoptosis of cultured human myeloid leukaemia cells.  

Science.gov (United States)

A novel single-chain immunotoxin was constructed by combining a CD33-specific single chain Fv (scFv) antibody fragment with an engineered variant of Pseudomonas exotoxin A (ETA). The variant toxin carries the KDEL peptide at its C-terminus, a cellular peptide mediating improved retrograde transport to the endoplasmic reticulum. The purified recombinant fusion protein induced potent apoptosis of the human myeloid cell lines U937, HL-60 and THP-1. Up to 98% of U937 cells were eliminated after treatment for 72 h with a single dose of 500 ng/ml (c. 7 nmol/l). Killing was antigen-specific and occurred by apoptosis. A control protein, consisting of a CD19-specific scFv antibody fragment fused to the ETA-KDEL toxin, failed to induce death of the CD19-negative cell lines U937, HL-60 and THP-1. The CD33-ETA toxin also mediated apoptosis of fresh patient-derived acute myeloid leukaemia cells from bone marrow and peripheral blood. The pronounced ...

2006-04-01

341

{sup 3}H-tetracycline as a proxy for {sup 41}Ca for measuring dietary perturbations of bone resorption  

Energy Technology Data Exchange (ETDEWEB)

Our group is interested in evaluating early effects of dietary interventions on bone loss. Postmenopausal women lose bone following reduction in estrogen which leads to increased risk of fracture. Traditional means of monitoring bone loss and effectiveness of treatments include changes in bone density, which takes 6 months to years to observe effects, and changes in biochemical markers of bone turnover, which are highly variable and lack specificity. Prelabeling bone with {sup 41}Ca and measuring urinary {sup 41}Ca excretion with accelerator mass spectrometry provides a sensitive, specific, and rapid approach to evaluating effectiveness of treatment. To better understand {sup 41}Ca technology as a tool for measuring effective treatments on reducing bone resorption, we perturbed bone resorption by manipulating dietary calcium in rats. We used {sup 3}H-tetracycline ({sup 3}H-TC) as a proxy for {sup 41}Ca ...

2007-06-15

342

caCORE version 3: Implementation of a model driven, service-oriented architecture for semantic interoperability.  

Science.gov (United States)

One of the requirements for a federated information system is interoperability, the ability of one computer system to access and use the resources of another system. This feature is particularly important in biomedical research systems, which need to coordinate a variety of disparate types of data. In order to meet this need, the National Cancer Institute Center for Bioinformatics (NCICB) has created the cancer Common Ontologic Representation Environment (caCORE), an interoperability infrastructure based on Model Driven Architecture. The caCORE infrastructure provides a mechanism to create interoperable biomedical information systems. Systems built using the caCORE paradigm address both aspects of interoperability: the ability to access data (syntactic interoperability) and understand the data once retrieved (semantic interoperability). This infrastructure consists of an integrated set of three major components: a ...

2007-04-02

343

Role of E-cadherin in the induction of apoptosis of HPV16-positive CaSki cervical cancer cells during multicellular tumor spheroid formation  

British Library Electronic Table of Contents (United Kingdom)

Multicellular tumor spheroids (MCTS) are three dimensional cell culture systems induced by suspension culture. MCTS are widely used in cancer research because of their similarity to solid tumors. CaSki cells are derived from a metastatic cervical cancer containing human papillomavirus 16 (HPV16). Cell death of CaSki cells in MCTS has been previously reported, and our model is used to better characterize the mechanisms of cell death of HPV16-positive keratinocytes. In this study, we found that apoptosis of CaSki cells was induced by suspension culture along with the formation of MCTS after 24?h of incubation. In suspended CaSki cells, monoclonal antibodies blocking E-cadherin function inhibited MCTS formation and suppressed suspension-induced apoptosis in a dose-dependent manner. Western bl...

2008-01-01

344

Positron annihilation in high-T/sub c/ superconductors  

International Nuclear Information System (INIS)

We report ab initio calculations of positron wave functions in the high-T/sub c/ superconductors YBa_2Cu_3O_7, Bi_2Sr_2CaCu_2O_8, and Tl_2Ba_2CaCu_2O_8 using the general potential linearized augmented plane-wave method. The calculated positron wave functions are fairly insensitive to whether or not electron-positron correlation is included in the calculation for YBa_2Cu_3O_7 and Tl_2Ba_2CaCu_2O_8, but the calculated positron density is quite sensitive to correlation in Bi_2Sr_2CaCu_2O_8. While the positron wave function samples primarily the chain region in YBa_2Cu_3O_7, the results indicate that positrons should be good probes of the Cu-O layer-derived electronic states near the Fermi energy in Tl_2Ba_2CaCu_2O_8 since a large overlap with these states is predicted.

345

Elastic scattering of 27.2 MeV alpha particle on "4"0Ca nucleus  

International Nuclear Information System (INIS)

Elastic scattering of 27.2 MeV #alpha# particles on "4"0Ca has been investigated. Differential cross sections have been measured in the angular range from 10 deg to 175 deg in the lab. system. The theoretical analysis has proceeded from the proposition that the results of a calculation based on the optical model in the range of small angles (less than 20 deg for "4"0Ca) are independent of parameters and shape of the potential employed. Elastic scattering of #alpha# particles at angles up to 50 deg has been calculated using three sets of the optical potential parameters in the energy range 23.37-28.92 MeV. In the range of small angles a rather similar behaviour of the calculated curves can be observed whereas in the range of medium and large angles these curves behave very differently. The success in the reproduction of the angular distributions for the entire energy range is indicative of the weak energy dependence of the optical potential ...

346

The Relationship between the Microstructure and Age Hardening Response in the Metastable Beta Titanium Alloy Ti-11.5Mo-6Zr-4.5Sn (Beta III).  

Science.gov (United States)

The effect of solution treatment temperature and oxygen content on the microstructure and age hardening response of the metastable beta alloy Ti-11.5Mo-6Zr-4.5Sn have been studied. Kinetics of formation of the equilibrium alpha-phase and the metastable om...

1977-01-01

347

Sunlight-induced efficient and selective photocatalytic benzene oxidation on TiO(2)-supported gold nanoparticles under CO(2) atmosphere.  

Science.gov (United States)

The sunlight-induced photocatalytic oxidation of aqueous benzene on TiO(2)-supported gold nanoparticles was considerably improved when the reaction was conducted under a CO(2) atmosphere. 13% yield and 89% selectivity of phenol was obtained on P25-supported gold nanoparticles under 230 kPa of CO(2). PMID:21952312

2011-09-26

348

Study of superficial films and of electrochemical behaviour of some nickel base alloys and titanium base alloys in solution representation of granitic, argillaceous and salted ground waters  

Energy Technology Data Exchange (ETDEWEB)

The corrosion behaviour of the stainless steels 304, 316 Ti, 25Cr-20Ni-Mo-Ti, nickel base alloys Hastelloy C4, Inconel 625, Incoloy 800, Ti and Ti-0.2% Pd alloy has been studied in the aerated or deaerated solutions at 20/sup 0/C and 90/sup 0/C whose compositions are representative of interstitial ground waters: granitic or clay waters or salt brine. The electrochemical techniques used are voltametry, polarization resistance and complexe impedance measurements. Electrochemical data show the respective influence of the parameters such as temperature, solution composition and dissolved oxygen, addition of soluble species chloride, fluoride, sulfide and carbonates, on which depend the corrosion current density, the passivation and the pitting potential. The inhibition efficiency of carbonate and bicarbonate activities against pitting corrosion is determined. In clay water at 90/sup 0/C, ...

1985-01-01

349

Structural features of twins in transition class alloy Ti-Al-Mo-V-Cr  

International Nuclear Information System (INIS)

The alloy of Ti-Al-Mo-V-Cr system is studied for its structure in a strained state and specific features of #beta#-#alpha# transformation in a #beta#-matrix and deformation twins on ageing. It is determined that preliminary deformation initiates the decomposition of solid solution on aging. In a metastable #beta#-titanium alloy the substructure of deformation twins is shown to vary essentially with aluminium and chromium partial substitution for molybdenum and vanadium

1999-11-01

350

Report of the Government Industrial Research Institute, Osaka, No. 388, February 1993. High lithium ion conductive solid electrolytes  

Energy Technology Data Exchange (ETDEWEB)

Research investigating applicability of lithium salts for solid electrolyte batteries was described. The studies included determinations of lithium ion conductivities in solid electrolyte systems based on Li4SiO4, LiTi2(PO4)3, and ceramic materials. Research on all solid state lithium cells utilizing TiS2 NiPS3 electrodes was also reported.

1993-01-01

351

Reactive metal brazing of aluminum nitride  

Energy Technology Data Exchange (ETDEWEB)

The addition of titanium to eutectic braze compositions causes these alloys to readily wet and bond to A1N ceramics. Electron microscopic characterizations of the metal-ceramic interfaces reveal the presence of TiN, along with other Ti- and Al-containing phases. The formation of such interfacial reaction products is an additional thermodynamic driving force for the creation of useful metal-ceramic bonds. 12 refs., 4 figs., 1 tab.

1990-01-01

352

Large-scale fabrication of TiO2 hierarchical hollow spheres.  

Science.gov (United States)

In this Communication, we report the fabrication of well-crystallized rutile-phase TiO2 hollow spheres using potassium titanium oxalate as the precursor. The spheres exhibited unique three-dimensional hierarchical architectures and demonstrated a significantly improved photocatalytic performance. The synthetic strategy used in this process represents a general approach and therefore may contribute to the formation mechanisms of hollow nanostructures. PMID:16634578

2006-05-01

353

Fabrication of Porous TiO2 Hollow Spheres and Their Application in Gas Sensing  

UK PubMed Central (United Kingdom)

In this work, porous TiO2 hollow spheres with an average diameter of 100 nm and shell thickness of 20 nm were synthesized by a facile hydrothermal method with NH4HCO3...Full Text Available

354

Characterization of TiN coatings deposited on plasma nitrided tool steel surfaces  

Energy Technology Data Exchange (ETDEWEB)

Wear-resistant TiN coatings deposited on tool steels are used frequently in industry. There is a trend towards further optimizing these coatings, e.g. by plasma nitriding the tool surface prior to TiN deposition. In this work the influence of the nitriding conditions on the surface properties of AISI 304 and ASP 23 tool steels was investigated. The plasma nitriding was carried out in a triode ion plating configuration normally used to deposit TiN coatings. At the surface of AISI 304 stainless steel, only a thin compound layer (Fe{sub 4}N, Fe{sub 3}N) was found, probably as a consequence of the rather slow nitrogen diffusion in the austenite matrix. For ASP 23 high speed steel, the different nitriding behaviour of the martensitic matrix causes the formation of a diffusion layer which results in an increase in hardness at the surface. On an analogous set of specimens the TiN deposition was started ...

1991-07-07

355

Simple integral screenprinting process for selective emitter polycrystalline silicon solar cells  

Energy Technology Data Exchange (ETDEWEB)

This letter describes a new simple fabrication process, developed recently for blue response'' improvement in low-cost polycrystalline silicon solar cells. A selective emitter is created by heavily doping the emitter, followed by a wet etching-back of the cell area between the fingers. An improvement up to 17 mV in {ital V}{sub oc}, 1.5 mA/cm{sup 2} in {ital J}{sub sc}, and 1% (absolute value) in {eta} is obtained. Effective phosphorus gettering, self-alignment, and application in a low-cost full screenprinting technology are the main advantages of the proposed process.

1991-09-23

356

On the Suitability of Interleaved Switched Capacitor Converter as an Interface for Electric Vehicle Dual Energy Storage Systems  

Energy Technology Data Exchange (ETDEWEB)

This paper presents the analysis and novel hybrid controller design for an interleaved 2-quadrant switched capacitor (SC) bidirectional DC/DC converter for a hybrid electric vehicle (HEV) dual energy storage system. The designed novel control strategy enables simpler dynamics compared to a standard buck converter with input filter, good regulation capability, low EMI, lower source current ripple, ease of control, and continuous input current waveform in both buck as well as boost modes of operation.

2010-09-15

357

A peculiar distribution of radial velocities of faint radio-galaxies with 13.0<=msub(corr)<=15.5  

International Nuclear Information System (INIS)

A sample of 41 radio-galaxies with 13.0<=msub(corr)<=15.5 has been analyzed to test the angular redshift anisotropy discovered on Sc I galaxies by Rubin, Rubin and Ford (1973). The sample does not present their anisotropy but contains an even more curious distribution of radial velocities which suggests that the Rubin-Ford effect results from an anomalous redshift of light when it travels through clusters of galaxies. (Auth.).

358

Properties of duplex coatings prepared by plasma nitriding and PVD Ti-C:H deposition on X20Cr13 ferritic stainless steel  

Energy Technology Data Exchange (ETDEWEB)

Duplex-coating procedures consisting of plasma nitriding and Me-C:H hard coating lead to an improved performance of the devices because the Me-C:H coating is supported by the nitrided phase and, therefore, the `eggshell-effect` is avoided. Furthermore, this support leads to a higher load-bearing capacity of the thin film. Two standard procedures (classical high-pressure plasma nitriding and unbalanced magnetron sputtering of Ti-C:H) were performed subsequently to prepare the duplex coatings on X20Cr13 ferritic stainless steel. The corrosion resistance of the steel could be improved by nitriding at 450 C compared to the untreated ferritic substrate. The roughness is determined by the nitriding step. The weakest point of the coating is the transition zone between the nitrided and the untreated substrate and not the interface between the Ti-C:H coating and the nitrided substrate as shown by the Rockwell and scratch tests. The adhesion of the ...

1998-06-08

359

Physical properties of shape-controlled TiO_2 nanoparticles  

International Nuclear Information System (INIS)

The synthesis of narrowly dispersed nanocrystalline TiO_2 was investigated with a surfactant aided solvothermal synthetic method in toluene solutions. When a sufficient amount of titanium isopropoxide, Ti[OCH(CH_3)_2]_4 (TIP), was added to the solution, the shapes of TiO_2 nanoparticles changed from spheres to rods. The aggregated microstructures of the nano-sized TiO_2 in systems of spheres, rods, and mixtures of spheres and rods was studied using TEM. The morphological shape of the aggregation was described in terms of the fractal dimensions. We used a box-counting method to get the fractal dimension of these systems. The fitted fractal dimensions for spheres, sphere/rod mixtures, and rods are D = 1.54, D = 1.81, and D = 1.89, respectively. The fractal dimension changed from 1.54 to 1.9 with the TIP/toluene ratio, indicating that the growth mechanism for aggregations showed different behaviors.

2005-11-01

360

Microstructural evaluation of as-solidified and heat-treated [gamma]-TiAl based powders  

Energy Technology Data Exchange (ETDEWEB)

Powders with nominal compositions (in atomic percent) Ti-48Al and Ti-48Al-2Nb-2Cr were prepared by the plasma rotating electrode process (PREP) and gas atomization (GA) techniques. As-solidified and heat-treated (1000degC per 3 h) powder samples were examined by metallography, scanning electron microscopy, X-ray diffraction and transmission electron microscopy. The microstructures of the powders were characterized as a function of atomization technique, alloy content, powder particle size (solidification rate) and thermal history. All of the as-solidified powders were comprised of disordered [alpha], and ordered [alpha][sub 2]-Ti[sub 3]Al and [gamma]-TiAl. For both alloys, a larger volume fraction of [alpha] and [alpha][sub 2] was observed in the PREP powders relative to GA powders of comparable size. Additionally, for both alloys and both atomization techniques, the volume fraction of [alpha][sub 2] ...

1992-05-15

361

Influence of composite LiCl-KCl molten salt on microstructure and electrochemical performance of spinel Li4Ti5O12  

International Nuclear Information System (INIS)

A series of spinel Li4Ti5O12 samples were synthesized via a composite molten-salt method (CMSM) using the mixtures of LiCl and KCl with different L values (L is defined as the molar ratio of LiCl:KCl) as the reaction media. It is found that the melting point of the composite molten salt can effectively influence the formation of particles, and leads to different electrochemical performances of the as-prepare Li4Ti5O12. The investigations of X-ray diffraction (XRD), particle size distribution (PSD), Brunauer-Emmet-Teller (BET) surface area, and scanning electron microscopy (SEM) indicate that the as-prepared Li4Ti5O12 with L = 1.5 is a pure phase, and has uniform homogeneous octahedral shape particles, rather narrow PSD, and high BET surface area. Electrochemical tests show that the optimized Li4Ti5O12 with L = 1.5 has an initial discharge capacity of 169 mAh g-1 and an initial charge-discharge ...

2008-12-30

362

Effect of Suburban Development and Landscape Position on Water Quality in Three Small Watersheds Within the Croton System, New York.  

Science.gov (United States)

Internal hydrological processes in suburban watersheds and their effects on water quality warrant investigation. Instrument clusters (throughfall collectors, suction lysimeters, monitoring wells, and shallow and deep piezometers) were installed at several locations within three small (50 - 70 ha) watersheds (one forested, two with different degrees of suburban development) in the Croton Watershed, southeastern New York. Biweekly and storm samples were analyzed for base cations, selected anions, and DOC over a one-year period. The topographic index (TI) quantified landscape position; flowpath analyses determined degree of development at each cluster, using % impervious cover as the metric. Water quality degradation was observed in sites with medium and high TI values; no such effect was observed along the ridges, i.e., low TI values. At medium TI values, areas with more than 5% impervious had degraded ...

2003-12-01

363

Development of the fabrication process for SiC reinforced gamma-TiAl intermetallic composites; SiC sen`i kyoka TiAl kinzokukan kagobutsu fukugo zairyo no kaihatsu  

Energy Technology Data Exchange (ETDEWEB)

In case of airplane engine, technical development like increase of temperature at the turbine entrance or high speed rotation with a purpose of thrust up, and reduction of structural part single substance mass or reduction of number of parts in order to achieve lightness and so forth, has been promoted in order to improve the performance that is evaluated by thrust weight ratio (thrust/weight). Accordingly, research and development of high heat resistance, high strength, lightness and so forth of each material of the parts are in demand. As a representative material corresponding to such demand, L10 type {nu}-TiAl intermetallic compound which is light and has improved high temperature strength properties is paid attention and its development is promotes. The authors were successful for the first time in the world to manufacture composite material with CVD type SiC fiber that was difficult so far by using TiAl-Cr alloy having super plasticity at ...

1998-04-20

364

Characterization of coatings and the low cycle fatigue behaviour of 316L  

Energy Technology Data Exchange (ETDEWEB)

In the framework of the European Fusion Technology Programme ECN participates in a NET task PSM-8 `Coatings and Surface Effects on Stainless Steel 316L`. High emissivity coatings were developed for enhanced heat transfer from graphite tiles to a Stainless Steel First Wall. Four candidate materials, Cr{sub 2}O{sub 3}, Black Cr, Al{sub 2}O{sub 3}/TiO{sub 2} and TiC were tested as candidate high emissivity coatings. These coatings were manufactured by atmospheric and vacuum plasma spraying technique and the Black Chromium coatings were manufactured by a galvanic coating technique. The tests included total emissivity measurements and Low Cycle Fatigue (LCF) experiments. The total emissivity of two TiC coatings at 525 K appeared to be 0.62 and 0.64. The total emissivity of the TiC and 5 wt% TiO{sub 2}/Al{sub 2}O{sub 3} coating was about 0.7. (orig.)

1993-03-01

365

A facile one-pot hydrothermal method to prepare europium-doped titania hollow phosphors and their sensitized luminescence properties  

British Library Electronic Table of Contents (United Kingdom)

Monodisperse europium-activated titania hollow phosphors had been synthesized by a facile one-pot hydrothermal method using carbon spheres as hard templates. Samples were characterized by X-ray powder diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, energy dispersive spectrometer and photoluminescence spectrum. The strongest emission intensity was observed with TiO2:Eu0.2 hollow spheres and TiO2:Eu0.2 hollow spheres calcining at 550^oC. Moreover, the strongest excitation of TiO2:Eu0.2 hollow spheres transferred from 400 to 500^oC and the effective nonradiative energy transfer from the TiO2 hollow spheres host matrix to Eu^3^+ ions crystal field states was realized due to changes of crystalline field in the environment around Eu^3^+ ions occupying Ti^4^+ site...

2010-01-01

366

Syntheses and crystal structures of the compounds In_3_._7Mo_1_5S_1_9, In_1_._6Rb_2Mo_1_5S_1_9, In_2_._2CsMo_1_5S_1_9 and ScTl_2Mo_1_5S_1_9 containing Mo_6 and Mo_9 clusters  

International Nuclear Information System (INIS)

The new compounds In_3_._7Mo_1_5S_1_9, In_1_._6Rb_2Mo_1_5S_1_9, In_2_._2CsMo_1_5S_1_9, and ScTl_2Mo_1_5S_1_9 have been synthesized by solid-state reaction in sealed molybdenum crucible at about 1250 deg. C. Their crystal structures were solved and refined from X-ray single-crystal data in the hexagonal space group P63/m. Their Mo-S framework consists of an equal mixture of Mo_6S_8S_6 and Mo_9S_1_1S_6 cluster units interconnected through Mo-S bonds. In In_3_._7Mo_1_5S_1_9, the In atoms occupy crystallographically different positions depending on their formal oxidation states of +1 or +3. This was confirmed by replacing partially or totally the monovalent indium by another monovalent cation such as the rubidium, cesium or thallium and the trivalent indium by the scandium to get the new In_1_._6Rb_2Mo_1_5S_1_9, In_2_._2CsMo_1_5S_1_9, and ScTl_2Mo_1_5S_1_9 compounds, respectively.

2004-11-30

367

Wear and friction coefficient of particle reinforced Ti-alloys  

Energy Technology Data Exchange (ETDEWEB)

Particulate Reinforced Titanium matrix composites (PRTi) exhibit some improved specific mechanical properties in comparison with those of unreinforced titanium alloys as a result of the combination of the high strength and stiffness of ceramic particles with the toughness and damage tolerance provided by the metal matrix. The poor tribological properties of the titanium exclude titanium alloys from applications where wear resistance is required (brakes, rotating parts, sliding parts). The addition of ceramic particles improves the tribological properties of metals sensitive to adhesive and /or abrasive wear significantly. In this work, the wear resistance and the friction coefficient of Ti6Al-6V-2Sn reinforced with TiC particles and Ti6Al-4V reinforced with SiC particles (prototype material) are compared with the unreinforced alloys. Pin on disc and pin on ring tests were carried out against standard steel (100Cr6) as a ...

2004-11-01

368

Aurivillius phases of PbBi4Ti4O15 doped with Mn3+ synthesized by molten salt technique: Structure, dielectric, and magnetic properties  

International Nuclear Information System (INIS)

Doping of manganese (Mn3+/Mn4+) into the Aurivillius phase Pb1-xBi4+xTi4-xMnxO15 was carried out using the molten salt technique for various Mn concentrations (x=0, 0.2, 0.4, 0.6, 0.8, and 1). Single phase samples could be obtained in the composition range with x up to 0.6 as confirmed by X-ray and neutron diffraction analysis. Dielectric measurements show a peak at 801, 803, 813 and 850 K for samples with x=0, 0.2, 0.4, and 0.6, respectively, related to the ferroelectric transition temperature (Tc). The main contribution of the in-plane polarization for x?0.2 which was calculated from the atomic positions obtained by the structure analysis is the dipole moment in the Ti(1)O6 layer; however, for x?0.4 the polarization originates from the dipole moment in the Ti(2)O6 layer. Mn doping in the Pb1-xBi4+xTi4-xMnxO15 does not show any long range magnetic ordering. -- Graphical abstract: The dipole moment of ...

2011-05-01

369

Studies on the mechanism of action of enterotoxin-induced fluid secretion in the gut  

International Nuclear Information System (INIS)

The mechanism of action of Clostridium difficile enterotoxin A (CA), of Escherichia coli enterotoxin (STa) and of cholera toxin (CT), which are known to cause severe diarrhea, were studied in a preparation of ligated jejunal loops of anesthetized rats in vivo. The toxins were administered intraluminally. Pharmacological agents, which were tested for their potency to influence toxin-related effects, were administered subcutaneously. Net fluid transport was determined gravimetrically, prostaglandin (PG) E_2-output into the lumen, cyclic adenosine monophosphate (cAMP) and cyclic guanosine monophosphate (cGMP) contents in the mucosa were measured by radioimmunoassay, serotonin-(5-HT)-output into the lumen was determined by high performance liquid chromatography. The histopathological effects of CA and CT were examined by light- and scanning electron microscopy. All three toxins caused net fluid secretion (FS). 5-HT_2-(ketanserin) and ...

1992-01-01

370

Crystallographic data for new phases in the CaSO/sub 3/-H/sub 2/O system  

Energy Technology Data Exchange (ETDEWEB)

Among the three modifications of calcium sulfite hemihydrate, two of them, hexagonal ..beta..-CaSO/sub 3/.1/2H/sub 2/O with a rhombohedral lattice and ..gamma..-CaSO/sub 3/.1/2H/sub 2/O with a simple triangular hexagonal lattice, were found in the authors' recent work. By heating ..cap alpha..- and/or ..gamma..-hemihydrate at 330-360/sup 0/C in a nitrogen atmosphere, the orthorhombic anhydrate ..cap alpha..-CaSO/sub 3/ was formed, with lattice constants of 6.472, 15.93, and 23.44 angstrom for a, b, and c respectively, while the body-centered tetragonal anhydrate ..beta..-CaSO/sub 3/, with lattice constants of 15.68 and 19.44 angstrom for a and c respectively, was formed by heating the ..beta..-hemihydrate. The dehydration of three hemihydrates and the hydration of two anhydrates were discussed. Calcium sulfite hemihydrate (CaSO/sub 3/.1/2H/sub 2/O) is useful as an ...

1982-03-01

371

Chelation of intracellular calcium blocks insulin action in the adipocyte  

Energy Technology Data Exchange (ETDEWEB)

The hypothesis that intracellular Ca/sup 2 +/ is an essential component of the intracellular mechanism of insulin action in the adipocyte was evaluated. Cells were loaded with the Ca/sup 2 +/ chelator quin-2, by preincubating them with quin-2 AM, the tetrakis(acetoxymethyl) ester of quin-2. Quin-2 loading inhibited insulin-stimulated glucose transport without affecting basal activity. The ability of insulin to stimulate glucose uptake in quin-2-loaded cells could be partially restored by preincubating cells with buffer supplemented with 1.2 mM CaCl/sub 2/ and the Ca/sup 2 +/ ionophore A23187. These conditions had no effect on basal activity and omission of CaCl/sub 2/ from the buffer prevented the restoration of insulin-stimulated glucose uptake by A23187. Quin-2 loading also inhibited insulin-stimulated glucose oxidation and the ability of insulin to inhibit cAMP-stimulated ...

1987-02-01

372

Chelation of intracellular calcium blocks insulin action in the adipocyte  

International Nuclear Information System (INIS)

The hypothesis that intracellular Ca"2"+ is an essential component of the intracellular mechanism of insulin action in the adipocyte was evaluated. Cells were loaded with the Ca"2"+ chelator quin-2, by preincubating them with quin-2 AM, the tetrakis(acetoxymethyl) ester of quin-2. Quin-2 loading inhibited insulin-stimulated glucose transport without affecting basal activity. The ability of insulin to stimulate glucose uptake in quin-2-loaded cells could be partially restored by preincubating cells with buffer supplemented with 1.2 mM CaCl_2 and the Ca"2"+ ionophore A23187. These conditions had no effect on basal activity and omission of CaCl_2 from the buffer prevented the restoration of insulin-stimulated glucose uptake by A23187. Quin-2 loading also inhibited insulin-stimulated glucose oxidation and the ability of insulin to inhibit cAMP-stimulated lipolysis without affecting ...

373

Valence electronic structure of Ti, Cr, Fe and Co in some alloys from K{beta}-to-K{alpha} X-ray intensity ratio studies  

Energy Technology Data Exchange (ETDEWEB)

K{beta}-to-K{alpha} X-ray intensity ratios of Ti, Cr, Fe and Co in pure metals and in Cr{sub 0.26}Fe{sub 0.74}, Cr{sub 0.80}Co{sub 0.20} and Ti{sub 0.80}Cr{sub 0.20} alloys have been measured following excitation by 59.54 keV {gamma}-rays from a 7400 MBq (200 mCi) {sup 241}Am point-source. The valence electronic structure of Ti, Cr, Fe and Co in the samples have been evaluated by the comparison of the measured K{beta}-to-K{alpha} intensity ratios with the results of multiconfiguration Dirac-Fock calculations performed for various electronic configurations of these metals. The 3d-electron populations obtained for pure metallic Ti, Cr, Fe and Co agree well with the results of band structure calculations of Papaconstantopoulos (Handbook of band structure of elemental solids, Plenum Press, New York, 1986). Our analysis indicates significant increase of 3d-electron population of Ti, Cr ...

2002-10-01

374

Valence electronic structure of Ti, Cr, Fe and Co in some alloys from K#beta#-to-K#alpha# X-ray intensity ratio studies  

International Nuclear Information System (INIS)

K#beta#-to-K#alpha# X-ray intensity ratios of Ti, Cr, Fe and Co in pure metals and in Cr_0_._2_6Fe_0_._7_4, Cr_0_._8_0Co_0_._2_0 and Ti_0_._8_0Cr_0_._2_0 alloys have been measured following excitation by 59.54 keV #gamma#-rays from a 7400 MBq (200 mCi) "2"4"1Am point-source. The valence electronic structure of Ti, Cr, Fe and Co in the samples have been evaluated by the comparison of the measured K#beta#-to-K#alpha# intensity ratios with the results of multiconfiguration Dirac-Fock calculations performed for various electronic configurations of these metals. The 3d-electron populations obtained for pure metallic Ti, Cr, Fe and Co agree well with the results of band structure calculations of Papaconstantopoulos (Handbook of band structure of elemental solids, Plenum Press, New York, 1986). Our analysis indicates significant increase of 3d-electron population of Ti, Cr and Fe in the ...

2002-10-01

375

Synthesis, structure and characterisation of the n=4 Aurivillius phase Bi5Ti3CrO15  

International Nuclear Information System (INIS)

The n=4 Aurivillius phase, Bi5Ti3CrO15, was synthesised by solid state reaction. Rietveld analysis of high resolution neutron diffraction data demonstrated this material to adopt the polar space group A21am at room temperature, transforming to the aristotype I4/mmm structure above 650 oC. This phase transition is coincident with an anomaly in DSC signal and relative permittivity, which are characteristic of a ferroelectric-paraelectric phase transition. Bi5Ti3CrO15 exhibits paramagnetic behaviour at low temperature, with short range antiferromagnetic interactions, but no evidence for long range magnetic ordering. This is considered a consequence of significant disorder of Ti and Cr over the available octahedral sites, as demonstrated by analysis of neutron diffraction data. -- Graphical abstract: We report here the synthesis, structure and characterisation of the n=4 Aurivillius phase Bi5Ti3CrO15. ...

2011-02-01

376

Self-assembly of photo-reduced graphene-titania films.  

Energy Technology Data Exchange (ETDEWEB)

In an aim to develop photo-responsive composites, the UV photo-reduction of aqueous titanium oxide nanoparticle-graphene oxide (TiO{sub 2}-GO) dispersions (Lambert et al. J Phys. Chem. 2010 113 (46), 19812-19823) was undertaken. Photo-reduction led to the formation of a black precipitate as well as a soluble portion, comprised of titanium oxide nanoparticle-reduced graphene oxide (TiO{sub 2}-RGO). When allowed to slowly evaporate, self assembled titanium oxide nanoparticle-graphene oxide (SA-TiO{sub 2}-RGO) films formed at the air-liquid interface of the solution. The thickness of SARGO-TiO{sub 2} films range from {approx}30-100 nm when deposited on substrates, and appear to be comprised of a mosaic assembly of graphene nanosheets and TiO{sub 2}, as observed by scanning electron microscopy. Raman spectroscopy and X-ray photoelectron spectroscopy indicate that the graphene oxide is ...

2010-07-01

377

Saddle field fast atom beam source: A new low pressure plasma nitriding method for a alloy Ti-6Al-4V  

Energy Technology Data Exchange (ETDEWEB)

Ti and its alloys (Ti-6Al-4V) have been used in different engineering applications due to their several outstanding properties. Nevertheless, their use in practical applications is limited in many cases due to their poor tribological property. Researches are ongoing on surface modification of Ti based materials by different plasma and ion based techniques to overcome this problem. However, the conventional plasma nitriding techniques have several problems such as formation of an arc, increased possibility of surface contamination due to a comparatively higher operating pressure, production of a very thin nitrided layer after a long processing time, etc. In this present work, the possibility of a new low-pressure plasma nitriding process using a Plasma Enhanced Chemical Vapor Deposition (PECVD) based saddle field fast atom beam source on a Ti-6Al-4V alloy sample is investigated. Plasma nitriding was ...

2006-09-25

378

Saddle field fast atom beam source: A new low pressure plasma nitriding method for a alloy Ti-6Al-4V  

International Nuclear Information System (INIS)

Ti and its alloys (Ti-6Al-4V) have been used in different engineering applications due to their several outstanding properties. Nevertheless, their use in practical applications is limited in many cases due to their poor tribological property. Researches are ongoing on surface modification of Ti based materials by different plasma and ion based techniques to overcome this problem. However, the conventional plasma nitriding techniques have several problems such as formation of an arc, increased possibility of surface contamination due to a comparatively higher operating pressure, production of a very thin nitrided layer after a long processing time, etc. In this present work, the possibility of a new low-pressure plasma nitriding process using a Plasma Enhanced Chemical Vapor Deposition (PECVD) based saddle field fast atom beam source on a Ti-6Al-4V alloy sample is investigated. Plasma nitriding was ...

2006-09-25

379

Photooxidation of different organic dyes (RB, MO, TB, and BG) using Fe(III)-doped TiO{sub 2} nanophotocatalyst prepared by novel chemical method  

Energy Technology Data Exchange (ETDEWEB)

The nano-structured Fe(III)-doped TiO{sub 2} photocatalysts with anatase phase have been developed for the oxidation of non-biodegradable different organic dyes like methyl orange (MO), rhodamine B (RB), thymol blue (TB) and bromocresol green (BG) using UV-Hg-lamp. The different compositions of Fe{sub x}Ti{sub 1-x}O{sub 2} (x = 0.005, 0.01, 0.05, and 0.1) nanocatalysts synthesized by chemical method (CM), have been characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectra, specific surface area (BET), transmission electronic microscopy (TEM) analysis, XPS, ESR and zeta potential. From XRD analysis, the results indicate that all the compositions of Fe(III) doped in TiO{sub 2} catalysts gives only anatase phase not rutile phase. For complete degradation of all the solutions of the dyes (MO, RB, TB, and BG), the composition with x = 0.005 is more photoactive compared all other compositions of Fe{sub ...

2008-09-15

380

Uptake of Pb by human skeleton and comparative metabolism of Pb and alkaline earth elements  

Energy Technology Data Exchange (ETDEWEB)

Measurements of the retention of /sup 47/Ca and of /sup 203/Pb were made following their administration by intravenous injection. Translocation to bone was measured by ..gamma.. counting the feet of subjects. Uptake by bone of /sup 203/Pb was comparatively slow and extrapolation to the whole skeleton indicated that 20% of the dose has been taken up within 20 days. By time, a similar fraction of the dose has been excreted in urine. Uptake by bone of /sup 47/Ca was about 1.5-2 times the amount excreted in urine. Both the uptake by bone, and its excretion in urine, were more rapid than that of /sup 203/Pb due to the greater attachment of the latter to red blood cells. However, the plasma clearance rate for Pb, like that of Sr, was greater than that of Ca.

1984-12-01

381

Time-resolved neutron diffraction study of the superconducting phase formation process in the Bi(PB)-Sr-Ca-Cu-O system  

Energy Technology Data Exchange (ETDEWEB)

The results of real-time neutron diffraction measurements during the superconducting phase formation process in the Bi(Pb)-Sr-Ca-Cu-O system are reported. A Sr-Ca-Cu-O type precursor, with the same stoichiometry as the 2223 phase, was used as starting material, and the temperature range favorable to the formation of the 2223 phase was investigated. The diffraction patterns were processed by a multiphase Rietveld refinement. The formation and decomposition of the 2201 and 2212 phases were directly observed. Experimental evidence on the existence of a partially melted phase in the range 855-860[degrees]C, involved in the formation of the 2223 phase, is discussed. 14 refs., 9 figs., 1 tab.

1993-08-01

382

Time-resolved neutron diffraction study of the superconducting phase formation process in the Bi(PB)-Sr-Ca-Cu-O system  

International Nuclear Information System (INIS)

The results of real-time neutron diffraction measurements during the superconducting phase formation process in the Bi(Pb)-Sr-Ca-Cu-O system are reported. A Sr-Ca-Cu-O type precursor, with the same stoichiometry as the 2223 phase, was used as starting material, and the temperature range favorable to the formation of the 2223 phase was investigated. The diffraction patterns were processed by a multiphase Rietveld refinement. The formation and decomposition of the 2201 and 2212 phases were directly observed. Experimental evidence on the existence of a partially melted phase in the range 855-860 degrees C, involved in the formation of the 2223 phase, is discussed. 14 refs., 9 figs., 1 tab.

383

Prostate cancer immunology - an update for Urologists  

British Library Electronic Table of Contents (United Kingdom)

A better understanding of the immune processes in the pathogenesis and progression of prostate cancer (CaP) may point the way towards improved treatment modalities. The challenge is to amplify immune responses to combat tumour escape mechanisms. Infection and inflammation may have a role in prostate carcinogenesis, including the newly discovered xenotropic murine leukaemia virus (XMRV). These inflammatory states damage defence mechanisms and induce a high proliferative state favouring further mutation and impaired immune surveillance. With this knowledge we are able to explore the use of immunotherapy to rejuvenate the immune system in combating CaP. Recently Sipuleucel-T, an immunotherapeutic agent for metastatic androgen independent CaP, has resulted in improved survival and might be the...

2011-01-01

384

Pretreatment of empty palm fruit bunch for production of chemicals via catalytic pyrolysis  

British Library Electronic Table of Contents (United Kingdom)

The effect of chemical pretreatments using NaOH, H2O2, and Ca(OH)2 on Empty Palm Fruit Bunches (EPFB) to degrade EPFB lignin before pyrolyis was investigated. Spectrophotometer analysis proved consecutive addition of NaOH and H2O2 decomposed almost 100% of EPFB lignin compared to 44% for the Ca(OH)2, H2O2 system while NaOH and Ca(OH)2 used exclusively could not alter lignin much. Next, the pretreated EPFB was catalytically pyrolyzed. Experimental results indicated the phenolic yields over Al-MCM-41 and HZSM-5 catalysts were 90wt% and 80wt%, respectively compared to 67wt% yield for the untreated sample under the same set of conditions. Meanwhile, the experiments with HY zeolite yielded 70wt% phenols.

2009-01-01

385

Practical superconductor development for electrical power applications  

Energy Technology Data Exchange (ETDEWEB)

Development of useful high-critical-temperature (high-{Tc}) superconductors requires synthesis of superconducting compounds; fabrication of wires, tapes, and films from these compounds; production of composite structures that incorporate stabilizers or insulators; and design and testing of efficient components. This report describes technical progress of research and development efforts aimed at producing superconducting components based on the Y-Ba-Cu, Bi-Sr-Ca-Cu, Bi-Pb-Sr-Ca-Cu, and Tl-Ba-Ca-Cu oxides systems. Topics discussed are synthesis and heat treatment of high-{Tc} superconductors, formation of monolithic and composite wires and tapes, superconductor/metal connectors, characterization of structures and superconducting and mechanical properties, and fabrication and properties of thin films. Collaborations with industry and academia are also documented. 10 figs.

1991-10-01

386

Mode of action of membrane-disruptive lytic compounds from the marine dinoflagellate Alexandrium tamarense  

British Library Electronic Table of Contents (United Kingdom)

Certain allelochemicals of the marine dinoflagellate Alexandrium tamarense cause lysis of a broad spectrum of target protist cells but the lytic mechanism is poorly defined. We first hypothesized that membrane sterols serve as molecular targets of these lytic compounds, and that differences in sterol composition among donor and target cells may cause insensitivity of Alexandrium and sensitivity of targets to lytic compounds. We investigated Ca^2^+ influx after application of lytic fractions to a model cell line PC12 derived from a pheochromocytoma of the rat adrenal medulla to establish how the lytic compounds affect ion flux associated with lysis of target membranes. The lytic compounds increased permeability of the cell membrane for Ca^2^+ ions even during blockade of Ca^2^+ channels wit...

2011-01-01

387

Electrochemical performance of flowerlike CaSnO{sub 3} as high capacity anode material for lithium-ion batteries  

Energy Technology Data Exchange (ETDEWEB)

Nanosized CaSnO{sub 3} is synthesized by a hydrothermal process and characterized by X-ray diffraction (XRD), Raman spectroscopy, and scanning electron microscopy (SEM). The SEM observation shows the sample has a porous flowerlike morphology. The electrochemical results exhibit that the stable and reversible capacity of 547 mAh g{sup -1} is obtained after 50 cycles at 60 mA g{sup -1} (0.1 C) and the corresponding charge capacity is determined to be 316 mAh g{sup -1} at the current density of 2.5 C. Cyclic voltammetry and electrochemical impedance spectroscopy data are analyzed to complement the galvanostatic results. The observed excellent performance is attributed to the porous structure and large surface area of flowerlike CaSnO{sub 3}.

2010-04-30

388

Determination of Ca, Cr, Cu, Fe, K, Mg, Na and Zn in Brazilian medicinal plants by neutron activation and atomic absorption; Determinacao de Ca, Cr, Cu, Fe, K, Mg, Na e Zn em plantas medicinais brasileiras por ativacao neutronica e absorcao atomica  

Energy Technology Data Exchange (ETDEWEB)

Medicinal plants are available in the markets in Belo Horizonte, Minas Gerais. The objective of this work is to investigate the Ca, Cr, Cu, Fe, K, Mg, Na e Zn concentrations in two lots of usually known diuretics plants (azeitona do mato, cabelo de milho, cavalinha, cervejinha do campo, chapeu de couro, congonha de bugre, marmelinho do campo and quebra pedra) bought with an interval of time - six months - between the purchases. The elemental concentrations were determined applying k{sub 0} instrumental neutron activation analysis and atomic absorption spectrophotometry analysis. (author)

2002-07-01

389

Delayed Afterdepolarization in Intact Canine Sinoatrial Node as a Novel Mechanism for Atrial Arrhythmia  

British Library Electronic Table of Contents (United Kingdom)

Delayed Afterdepolarization in Sinoatrial Node. Introduction: Recent evidence indicates that spontaneous sarcoplasmic reticulum Ca release and Na-Ca exchanger current activation contribute to the sinoatrial node (SAN) automaticity. These findings suggest that SAN activity may share mechanisms that underlie both automaticity and triggered activity. The aim of this study is to test the hypothesis that spontaneous, nonvoltage gated, intracellular Ca (Cai) elevation may induce delayed afterdepolarization (DAD) in intact SAN during isoproterenol infusion. Methods and Results: We simultaneously mapped Cai and membrane potential in 31 isolated Langendorff-perfused canine right atriums (RA). Isoproterenol increased heart rate and late diastolic Cai elevation (LDCAE) of the superior SAN, leading to...

2011-01-01

390

Clean combustion of solid fuels  

International Nuclear Information System (INIS)

A chemical-looping process is proposed for the clean combustion of solid fuels for electric power or heat generation. The process is based on coal gasification with CO_2 to produce CO. The CO then reduces CaSO_4, which is used as an oxygen carrier, in a separate reactor to give CaS and CO_2. A portion of the CO_2 is recycled for the gasification stage and the rest can be sent for sequestration. The CaS is sent to another reactor for oxidation with air and to generate heat or power. The overall thermal effect is the same as direct combustion, but separation of CO_2 and other pollutants, such as sulphur, is achieved. In comparison with conventional chemical-looping combustion of natural gas, much less water is present in the CO_2 product, and hence the loss of heat energy and corrosion of the fuel-reactor system can be reduced.

2008-01-01

391

BLM issues final EIS for Tract C-a offsite lease  

Energy Technology Data Exchange (ETDEWEB)

In October, 1986, the US Bureau of Land Management, White River Resource Area, issued the Final Environmental Impact Statement concerning Rio Blanco Oil Shale Company's request to lease an offtract site for disposal of overburden and spent shale from Tract C-a. A major issue which pitted Rio Blanco Oil Shale Company against many other members of the oil shale community was the covering up of oil shale resources on 84 Mesa. The oil shale resource under 84 Mesa may contain as much oil in place as Tract C-a itself. Some of the significant points concerning this issue are discussed. A summary of environmental consequences is given. 5 figures.

1986-12-01

392

Phase formation, crystal structures and magnetic properties of perovskite-type phases in the system La2Co1+z(MgxTi1-x)1-zO6  

International Nuclear Information System (INIS)

Perovskite-type cobaltates in the system La2Co1+z(MgxTi1-x)1-zO6 were studied for z=0?x?0.6 and 0?xoC. The space group symmetry of the structure changes from P21/n via Pbnm to R3-bar c with both increasing Mg content and increasing Co content. The La2Co(MgxTi1-x)O6 (z=0) compounds show anti-ferromagnetic couplings of the magnetic moments for the Co below 15 K for x=0, 0.1 and 0.2. XANES spectra show for the compositions 0?x?0.5 a linear decrease in the L3/(L3+L2) Co-L2,3 edge branching ratio with x, in agreement with a decrease of the average Co ion spin-state, from a high-spin to a lower-spin-state, with decreasing nominal Co2+ ion content. -- Graphical abstract: XRPD patterns for perovskite compounds along the lines La2Co(MgxTi1-x)O6 and La2Co1+z(Mg0.5Ti0.5)1-zO6. Display Omitted Research Highlights: ?Tuning of the oxidation state of Co in the perovskite system La2Co1+z(Mtem ...

2011-01-01

393

Visible light photocatalytic activity and Photoelectrochemical property of Fe-doped TiO2 hollow spheres by sol?gel method  

British Library Electronic Table of Contents (United Kingdom)

Fe-doped TiO2 hollow spheres (Fe-THs) were synthesized by sol?gel process using carbon spheres as templates. The prepared samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV?vis diffuse reflectance spectrum (DRS), N2 adsorption?desorption isotherms, Electron paramagnetic resonance (EPR) spectroscopy and Photoluminescence emission spectroscopy (PL). UV?vis spectra showed that Fe3+ doping could extend the absorption edge to the visible region. EPR spectra showed that Fe3+ was incorporated into the crystal lattice of TiO2, which could inhibit the recombination of photo-induced electron?hole pairs and improve the photocatalytic activity. The photocatalytic activities of the prepared samples were evaluated for the degradation of dye Reactive Brillia...

2011-01-01

394

Synthesis and enhanced light absorption of alumina matrix nanocomposites containing multilayer oxide nanorods and silver nanoparticles  

British Library Electronic Table of Contents (United Kingdom)

In this paper, multilayer oxide nanorods were deposited in the nanopores of anodic aluminum oxide (AAO) via solution infiltration followed by heat treatment. The nanorods have a core-shell structure. First, the shell (nanotube) with the thickness of about 40nm was made of TiO"2 through the hydrolysis of (NH"4)"2TiF"6. Second, silver nanoparticles with the diameter of about 3nm were added into the TiO"2 layer through thermal decomposition of AgNO"3 at elevated temperatures. Then, cylindrical cores (nanorods) of CoO and ZnO with 200nm diameter were prepared, respectively. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to characterize the structure and composition of the nanorods. UV-vis light absorption measurements in the wavelength range from 350 to...

2011-01-01

395

Synthesis and characterization of conducting polymer composite (PAn/TiO{sup 2}) for cathode material in rechargeable battery  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the preparation and characterization of polyaniline/TiO{sub 2} composite by XRD, UV-VIS spectra, TGA/DTA and FTIR. The composite is used as a cathode material for rechargeable battery comprising of zinc container as the anode, cellulose acetate as the separator and polyvinyl sulfate and carboxy methyl cellulose as the solid polymer electrolytes (SPE). By using the PAn/TiO{sub 2} composite as the cathode material, the cylindrical AA type rechargeable battery was fabricated and the following output was observed. The open circuit voltage (OCV) is 1.4 V and current is 250 mA to 1.0 A, 50 recharge cycles, power density is 350 A h/kg and power efficiency is 70%.

2003-02-01

396

State of the art in fine filament NbTi superconductors at IGC  

International Nuclear Information System (INIS)

The proposed Superconducting Super Collider (SSC) in the US and plans for a Large Hadron Collider LHC at CERN are likely to require micron size filaments to reduce micron size filaments to reduce magnetization effects at the low injection fields envisioned. Superconductors of NbTi, designed to meet these requirements, are described. These conductors contain from 6000 to 36,613 filaments. Results are presented on NbTi conductors made by multiple extrusion techniques. Filament sizes of between 2.2 and 17 micron have been obtained. Current densities of between 2400 A/mm"2 and nearly 3400 A/mm"2 at 5 Tesla have been achieved. Metallurgical aspects of these conductors are presented using both optical and SEM views of conductor cross section and filament surface.

1986-05-12

397

Production of powder titanium alloys with Mo, Zr, Nb additions and their properties  

International Nuclear Information System (INIS)

In order to substitute expensive cast titanium alloys by powder ones the possibility of introduction of powder additions by mechanical stock mixing is studied. It is shown that microstructure of powder alloys of Ti-Zr(1-9%) system is typical for one-phase cast #alpha#-alloys. The Ti-Mo(1-9%) and Ti-Nb(1-9%) system alloys have microstructure typical for two-phase (#alpha#+#beta#)-alloys. For homogeneous structure to be obtained the high temprature annealing is advisable after hot pressing. Alloying with Mo, Zr and Nb permits to increase considerable the strength of powder titanium products (at 9% Mo more than two times).

398

Preparation and photocatalytic property of pyrochlore Bi2Ti2O7 and (Bi, La) 2Ti2O7 films  

British Library Electronic Table of Contents (United Kingdom)

Dopant-free Bi2Ti2O7 thin films with pyrochlore structure and La-doped bismuth titanate thin films have been fabricated by means of chemical solution decomposition, and characterized by X-ray diffraction, atomic force microscopy, scanning electron microscopy and UV?Vis spectrophotometry in this study. Their photocatalytic activities have been evaluated by photodegrading methyl orange solution, and the optimum processing parameters for the highest photocatalytic activity have been found. Moreover, the effects of La-doping on the phase transformation and the photocalalytic activity have been studied. It has been deduced from the experiment result that substituted La3+ ions can act as a stabilizer of Aurivillus phase BLT and a grain?growth inhibitor in BLT thin films.

2008-01-01

399

Optical properties and electronic structure of ceramics tetragonal PbTiO_3 by using full-potential linearized augmented plane wave  

International Nuclear Information System (INIS)

The electronic structure and optical properties in tetragonal ceramics PbTiO_3, are studied by using full-potential linearized augmented plane wave method in density functional theory with the generalized gradient approximation by WIEN2K package. The theoretical calculated optical properties and energy loss spectrum yield a static refractive index of 2.59 and a plasmon energy of 22.7eV for the tetragonal phase. The effective electron number at low energy saturates near 22-23eV with the value of 50 for the effective electron number. The results show a indirect band gap of 2.2eV at the I' point in the Brillouin zone. The :calculated band structure and density of states of PbTiO_3 agree with previous experimental and theoretical results.

2007-01-01

400

Microstructure characterization and tensile properties of b phase containing TiAl pancake  

British Library Electronic Table of Contents (United Kingdom)

The microstructure and tensile properties of Ti-44Al-6V-3Nb-0.3Y (at.%) alloy after canned forging were investigated. SEM results showed that the TiAl pancake exhibits inhomogeneous microstructure, which can be ascribed to the temperature drop and friction between billet and outer pack during forging, as well as the intrinsic anisotropy of lamellar colony. By means of TEM observation and EBSD analysis, the microstructure in the dominant area of the pancake was further characterized. This deformation area consists of 87.7% content of g grains plus some refined lamellar colonies and the rest of B2 grains. The grain size ranges between 1mm and 8.5mm. High-angle boundaries dominate the deformation microstructure, several substructures and twins are observed as well. Additionally, current forge...

2011-01-01

401

Microstructure and tool electrode erosion in EDMed of TiN/Si_3N_4 composites  

International Nuclear Information System (INIS)

Conductive TiN/Si_3N_4 ceramic composites were processed by electrical discharge machining (EDM) and their microstructure and conductivity were investigated. The whole process of tool electrode wear is evaluated by sinker-EDM. The machined surfaces of TiN/Si_3N_4 ceramic composites were examined by scanning electron microscopy (SEM) and profilometry to determine the surface finish. The electrode wear rate of brass is higher than copper electrode for all EDMed tests. The surface texture was found to have greater dependence on pulse energy. It was observed that the sinker-EDM at higher pulse energy caused severe microdamage in the surface. The surface roughness (Ra) values also increase with increasing pulse energy.

2003-12-20

402

Magnetic susceptibility and electrical properties of Ln/sub 2/3+x/TiO/sub 3+y/ (Ln = Ce, Nd) at 77-450/sup 0/K  

Energy Technology Data Exchange (ETDEWEB)

The magnetic susceptibility and electrical resistivity in cerium and neodymium titanate bronzes in Ln/sub 2/3+x/TiO/sub 3+y/ of the perovskite structure were investigated in the temperature range 77-450/sup 0/K. The deviation of the 1/x = f(T) dependence from the Curie-Weiss law, found for a majority of the compositions, was interpreted from the crystal-field effect based on the state of the Ce/sup 3 +/ and Nd/sup 3 +/ cations. For a number of the phases, a transition from metallic conductivity at high temperatures to semiconducting conductivity was detected at temperatures below 200-250/sup 0/K, which agrees well with the conclusion about the temperature dependence of x, related to the subsystem of Ti/sup 3 +/ cations.

1987-01-01

403

In situ composite coating of titania-hydroxyapatite on titanium substrate by micro-arc oxidation coupled with electrophoretic deposition processing  

British Library Electronic Table of Contents (United Kingdom)

In situ composite coating of hydroxyapatite (HA)/TiO2 were produced on titanium (Ti) substrate by micro-arc oxidation coupled with electrophoretic deposition (MAO&EPD) technique with different concentrations of HA particles in the 0.2M NaOH electrolyte solution. The surface morphology and chemical composition of the hybrid coating were effected by HA concentration. The amount of HA particles incorporated into coating layer increased with increasing HA concentration used in the electrolyte solution. The corrosion behavior of the coating layer in simulated body fluids (SBF) was evaluated using a potentiodynamic polarization test. The corrosion resistance of the coated sample was increased compared to the untreated Ti sample. The in vitro bioactivity assessment showed that the MAO&EPD treated...

2011-01-01

404

Evolution of lattice strain in Ti-6Al-4V during tensile loading at room temperature  

International Nuclear Information System (INIS)

The evolution of intergranular lattice strains in a textured, forged bar (Bar) sample of the #alpha# - #beta# titanium alloy Ti-6Al-4V has been characterised using in situ X-ray diffraction. A two-phase elastic-plastic self-consistent (EPSC) model has been developed to rationalise the results. Of the orientations analysed, it is found that the #left brace#2 0 0#right brace# #beta# orientation is the most compliant and that load partitions to this orientation during plasticity. The results from the bar material have then been used to predict the response of unidirectionally rolled plate (UD) Ti-6Al-4V. It is predicted that the residual lattice strains in the #left brace#101-bar0#right brace# and #left brace#112-bar0#right brace# orientations will be significantly higher in the UD material.

2008-12-01

405

Enhanced inactivation of bacteria by metal-oxide nanoparticles combined with visible light irradiation  

British Library Electronic Table of Contents (United Kingdom)

AbstractBackground In recent years nano-metaloxides which easily penetrate into the cells with special interest due to their higher chemical reactivity as compared to that of similar materials in the bulk form. Of particular interest are nano-TiO2 and ZnO, which have been widely used for their bactericidal and anticancerous properties. Purpose The aim of the present study was to examine the bactericidal properties of nano-TiO2 and ZnO combined with visible light on S. aureus and S. epidermitis, known for their high prevalence in infected wounds. Study Using the technique of electron-spin resonance (ESR) coupled with spin trapping, we examined the ability of TiO2 and ZnO nanoparticle suspensions in water to produce reactive oxygen species (ROS) with and without visible light irradiation. Th...

2011-01-01

406

Effect on substrate-film adherence of TiN film enhanced plasma nitriding  

International Nuclear Information System (INIS)

The combined process of low temperature plasma nitriding and TiN film deposition was realized on the plasma-assisted vacuum arc plating set. The process of plasma nitriding can be done below 200 degree C. The low temperature plasma nitriding and TiN film deposition was realized on the same device. By the SEM analysis of the plating structure, low hardness grads from the substrate to the film was obtained, and it was found that the mixed nitride plating formed at the interface between the substrate and the film. The quantitative measurement of substrate-film adherence showed that the adherence was improved notably by using the process. The adherence between film and substrate can reach to 59.6 MPa without the bias voltage supplying

2002-01-01

407

Effect of milling process on the core-shell structures and dielectric properties of fine-grained BaTiO3-based X7R ceramic materials  

British Library Electronic Table of Contents (United Kingdom)

Fine-grained BaTiO3-based X7R ceramic materials were prepared and the effects of milling process on the core-shell structures and dielectric properties were investigated using scanning electron microscope, transmission electron microscope, and energy dispersive spectroscopy (EDS). As the milling time extends, the dielectric constant of the ceramics increases, whereas the temperature coefficient of capacitance at 125degreeC drops quickly. The changes in dielectric properties are considered relevant to the microstructure evolution caused by the milling process. Defects on the surface of BaTiO3 particles increase because of the effects of milling process, which will make it easier for additives to diffuse into the interior grains. As the milling time increases, the shell region gets thicker a...

2009-01-01

408

Effect of metal selection and porcelain firing on the marginal accuracy of titanium-based metal ceramic restorations  

British Library Electronic Table of Contents (United Kingdom)

Statement of problem Titanium is the most biocompatible metal used for dental casting; however, there is concern about its marginal accuracy after porcelain application since this aspect has direct influence on marginal fit. Purpose The purpose of this study was to determine the effect that metal selection and the porcelain firing procedure have on the marginal accuracy of metal ceramic prostheses. Material and methods Cast CP Ti, milled CP Ti, cast Ti-6Al-7Nb, and cast Ni-Cr copings (n=5) were fired with compatible porcelains (Triceram for titanium-based metals and VITA VMK 95 for Ni-Cr alloy). The Ni-Cr alloy fired with its porcelain served as the control. Photographs of metal copings placed on a master die were made. Marginal discrepancy was determined on the photographs using an image ...

2010-01-01

409

Damage mechanisms around hardness indentations in Ti{sub 3}SiC{sub 2}  

Energy Technology Data Exchange (ETDEWEB)

Microstructural observations of damage around indentations in Ti{sub 3}SiC{sub 2} are presented. The Vickers hardness decreased with increasing load and asymptotically approached 4 GPa at the highest loads. No indentation cracks were observed even at loads as high as 300 N. Preliminary strength versus indentation plots indicate that, at least for the large-grained material ({approx}100 {micro}m) studied here, Ti{sub 3}SiC{sub 2} is a damage-tolerant material able to contain the extent of microdamage to a small area around the indent. The following multiple energy-absorbing mechanisms have been identified from scanning electron micrographs of areas in the vicinity of the indentation: diffuse microcracking, delamination, crack deflection, grain push-out, grain pull-out, and the buckling of individual grains.

1997-02-01

410

Application of polycrystalline diffusion barriers  

International Nuclear Information System (INIS)

Degradation of contacts of the electronic equipment at the raised temperatures is connected with active diffusion redistribution of components contact - metalized systems (CMS) and phase production on interphase borders. One of systems diffusion barriers (DB) are polycrystalline silicide a film, in particular silicides of the titan. Reception disilicide the titan (TiSi_2) which on the parameters is demanded for conditions of microelectronics from known silicides of system Ti-Si, is possible as a result of direct reaction of a film of the titan and a substrate of silicon, and at sedimentation of layer Ti-Si demanded stoichiometric structure. Simultaneously there is specific problem polycrystalline diffusion a barrier (PDB): the polycrystalline provides structural balance and metastability film disilicide, but leaves in it borders of grains - easy local ways of diffusion. In clause the analysis diffusion permeability ...

411

(Ti,Cr,Nb)CN coatings deposited on nitrided high-speed steel by cathodic arc method  

British Library Electronic Table of Contents (United Kingdom)

The combined processes of plasma nitriding and cathodic arc deposition of (Ti,Cr,Nb)CN coatings were applied to HSS substrates. The nitrided layers, obtained in a mixture of H2 (70%) and N2 (30%) at two different temperatures (480^oC and 510^oC), were examined for the microhardness depth profiles. Characterization of the duplex coatings was performed by investigating elemental and phase composition, texture, hardness, friction and wear. XRD and XPS analyses revealed the formation of a mixture of a carbonitride fcc solid solution, in a dominant proportion, and metallic chromium. The film hardness was measured to be ~34GPa. The duplex (Ti,Cr,Nb)CN coatings exhibited superior tribological behavior as compared to both nitrided layers and non-duplex coatings.

2011-01-01

412

caCORE version 3: Implementation of a model driven, service-oriented architecture for semantic interoperability  

UK PubMed Central (United Kingdom)

One of the requirements for a federated information system is interoperability, the ability of one computer system to access and use the resources of another system. This feature is particularly...Full Text Available

2008-02-01

413

Thermal State-of-Charge in Solar Heat Receivers - NASA Technical ...  

Science.gov (United States)

Thermal Cavity Receivers,". JPL. Publication. 83-97,. 1983. 5Hall, III, C.A., Glakpe, E.K., Cannon,. J.N., and. Kerslake,. T.W., "Modeling ...

415

The NADPH oxidase inhibitor diphenyleneiodonium is also a potent inhibitor of cholinesterases and the internal Ca2+ pump  

UK PubMed Central (United Kingdom)

Background and purpose:Diphenyleneiodonium (DPI) is often used as an NADPH oxidase inhibitor, but is increasingly being found to have unrelated side effects. We investigated its...Full Text Available

2009-10-01

416

Synthesis of nano-size Ca-#alpha# SiAlON Powders by carbothermal reduction-nitridation  

International Nuclear Information System (INIS)

Carbothermal reduction-nitridation (CRN) of SiO_2 is an attractive method for manufacturing Si_3N_4 powders with controlled grain morphology. Moreover, #beta#-sialon powders could also be synthesized from either pure powder mixtures or some inexpensive raw minerals by CRN. The resultant powders have shown some advantages, especially in manufacturing sialon products at low cost. However, there have been only a few works on preparing #alpha#-sialon powders. In this work, Ca-#alpha# sialon powder was synthesized by CRN of a SiO_2-Al_2O_3 and CaCO_3 powder mixture An unusual morphology of hollow balls of 200 to 500nm with many nano size #alpha#-sialon particles of 10 to 30nm was identified from the resultant Ca-#alpha# sialon powders. This has never been previously reported for sialon ceramics. It was consequently confirmed that the morphologies of the products were clearly related to the intermediate products appearing during ...

417

Suppression by IgA of IgG-mediated phagocytosis by human polymorphonuclear leucocytes  

UK PubMed Central (United Kingdom)

IgA from normal human serum, a myeloma IgA and human colostral IgA were found to inhibit the IgG-dependent phagocytosis of Candida albicans (CA) blastospores by polymorphonuclear leucocytes...Full Text Available

1978-12-01

418

Sensitivity limits for voltage control of P2Y receptor-evoked Ca2+ mobilization in the rat megakaryocyte  

UK PubMed Central (United Kingdom)

G-protein-coupled receptor signalling has been suggested to be voltage dependent in a number of cell types; however, the limits of sensitivity of this potentially important phenomenon are unknown. Using...Full Text Available

2004-02-15

419

Red-shift of emission wavelength caused by reabsorption mechanism of europium activated Ca-#alpha#-SiAlON ceramic phosphors  

International Nuclear Information System (INIS)

The optical properties of divalent europium activated Ca-#alpha#-SiAlON were investigated and the excitation and emission processes were discussed. The emission wavelength is influenced by the activator concentration of Eu more than the codopant concentration of Ca, in case of the same matrix composition of #alpha#-SiAlON. The red-shift of emission increases when the concentration of Eu increases. In addition, it was revealed that the red-shift of emission would be caused by the construction of the package of optical device. The correlated color temperature becomes low by the red-shift for the white light-emitting diode (LED) lamp using Ca-#alpha#-SiAlON:Eu phosphor when the phosphor powder concentration increases in the transparent resin which coats the primary light source of a blue LED die. The additional red-shift can be observed when the excessive amount of phosphor coating is intentionally poured to the white LED ...

2007-10-01

420

Protocadherin-PC Promotes Androgen-Independent Prostate Cancer Cell Growth  

UK PubMed Central (United Kingdom)

BACKGROUNDProtocadherin-PC (PCDH-PC) expression is upregulated in apoptosis-resistant sublines of the LNCaP human prostate cancer (CaP) cell line. Here, we assess...Full Text Available

2006-07-01

421

Preparation of multication #alpha#-SiAlON containing strontium  

International Nuclear Information System (INIS)

The possibility of having Sr as an interstitial metal cation in #alpha#-SiAlON has been investigated in two systems: a single-cation system (Si_3N_4-SrO-AlN) and a multication system (Si_3N_4-(Y_2O_3/SrO/CaO)-AlN). It was found that Sr alone does not form #alpha#-SiAlON and that Sr could only be accommodated in #alpha#-SiAlON in conjunction with Y and Ca. The Sr content of #alpha#-SiAlON increased as the total content of (Y + Ca) increased and appeared to reach a limit at 0.5 at.%, or 0.15 atom per #alpha#-SiAlON. Unexpectedly, some of the #alpha#-SiAlON that contained (Sr + Y + Ca) was present as laths or fibers with the c-axis perpendicular to the hot-press direction.

422

Prediction and diagnosis of bladder cancer recurrence based on urinary content of hTERT, SENP1, PPP1CA, and MCM5 transcripts  

UK PubMed Central (United Kingdom)

BackgroundIdentification of urinary biomarkers for detection of bladder cancer recurrence would be beneficial to minimize the frequency of cystoscopy. Our objective was to determine...Full Text Available

423

Pozzolanic behaviour of compound-activated red mud-coal gangue mixture  

Energy Technology Data Exchange (ETDEWEB)

The pozzolanic behaviour of compound-activated red mud-coal gangue has been investigated through TG, DTA, XRD, FTIR and {sup 27}Al MAS NMR. From viewpoint of reaction kinetics, it is found that the pozzolanic reaction mechanism of the compound-activated red mud-coal gangue-lime system is clearly consistent with diffusion control up to 14 days, and the reaction rate constant calculated from Jander equation decreases with the increase of CaO addition in the system. The hydration products formed in the red mud coal gangue-lime systems at ambient temperature are essentially aluminous C-S-H and Ca{sub 3}Al{sub 2}O{sub 6} center dot xH{sub 2}O. From TG analysis results, it is thought that the high amount of Ca(OH){sub 2} in the pastes of studied system is not conducive to the continual increase of non-evaporable water content of the hydration products. Of particular interest. {sup 27}Al MAS NMR proved to be an effective technique ...

2011-03-15

424

Pozzolanic behaviour of compound-activated red mud-coal gangue mixture  

International Nuclear Information System (INIS)

The pozzolanic behaviour of compound-activated red mud-coal gangue has been investigated through TG, DTA, XRD, FTIR and 27Al MAS NMR. From viewpoint of reaction kinetics, it is found that the pozzolanic reaction mechanism of the compound-activated red mud-coal gangue - lime system is clearly consistent with diffusion control up to 14 days, and the reaction rate constant calculated from Jander equation decreases with the increase of CaO addition in the system. The hydration products formed in the red mud-coal gangue - lime systems at ambient temperature are essentially aluminous C-S-H and Ca3Al2O6.xH2O. From TG analysis results, it is thought that the high amount of Ca(OH)2 in the pastes of studied system is not conducive to the continual increase of non-evaporable water content of the hydration products. Of particular interest, 27Al MAS NMR proved to be an effective technique to obtain valuable information of Al[4] in C-S-H ...

2011-03-01

425

Physiological calcium concentrations regulate calmodulin binding and catalysis of adenylyl cyclase exotoxins  

UK PubMed Central (United Kingdom)

Edema factor (EF) and CyaA are calmodulin (CaM)-activated adenylyl cyclase exotoxins involved in the pathogenesis of anthrax and whooping cough, respectively. Using spectroscopic, enzyme kinetic and...Full Text Available

2002-12-16

426

Muscle-Specific Calpain is Localized in Regions Near Motor Endplates in Differentiating Lobster Claw Muscles  

UK PubMed Central (United Kingdom)

Calpains are Ca2+-dependent proteinases that mediate protein turnover in crustacean skeletal muscles. We used an antibody directed against lobster muscle-specific calpain (Ha-CalpM)...Full Text Available

2007-11-01

427

Molecular Epidemiology of Methicillin-Resistant and Methicillin-Susceptible Staphylococcus aureus Isolated from the Eye  

UK PubMed Central (United Kingdom)

Purpose:Methicillin-resistant Staphylococcus aureus (MRSA) strains are commonly classified as hospital-acquired (HA) or community-acquired (CA). Typical HA-MRSA...Full Text Available

2011-02-01

428

Mass effect and Pu removal from rats with Ca- or Zn-DTPA  

International Nuclear Information System (INIS)

Eight percent of an intramuscular injection of 27.6 nCi of "2"3"7Pu(NO_3)_4 was retained by rats at the injection site, after 22 days. More than 30% is usually retained following injection of more massive quantities of "2"3"9Pu. Treatment with Ca- or Zn-DTPA showed the former to be more effective when treatments were initiated 1 hr after Pu administration. When treatments were begun 7 days after the Pu injection, 416 nmol Ca-DTPA/kg was more effective in removing Pu than 28.7 nmol/kg (human dose level) of Zn- or Ca-DTPA. Due to its high specific activity and ease of detection, "2"3"7Pu permits facile experimentation in small animals at Pu mass levels comparable to those encountered in most human exposures.

1977-05-01

429

Long-term synaptic transformation of hippocampal CA1 gamma-aminobutyric acid synapses and the effect of anandamide.  

UK PubMed Central (United Kingdom)

Evidence is presented for a distinctive type of hippocampal synaptic modification [previously described for a molluscan gamma-aminobutyric acid (GABA) synapse after paired pre- and postsynaptic excitation]:...Full Text Available

1995-10-24

430

Limestone Dissolution in Flue Gas Desulfurization Processes.  

Science.gov (United States)

The report gives results of the measurement of dissolution rates of reagent CaCO3 and commercial limestones (9 types/19 grinds) at constant pH and solution composition by batch titration with HC1. Conditions were selected to simulate flue gas desulfurizat...

1983-01-01

431

Initial Report of the Cancer PROMIS Supplement Sexual Function Committee: Review of Sexual Function Measures and Domains Used in Oncology  

UK PubMed Central (United Kingdom)

ObjectiveThis report describes initial activities of the Cancer Patient-Reported Outcomes Measurement Information System (PROMIS) Sexual Function domain group (CaPS-SF),...Full Text Available

2009-03-15

432

Imaging of calcium transients in skeletal muscle fibers.  

UK PubMed Central (United Kingdom)

Epifluorescence images of Ca2+ transients elicited by electrical stimulation of single skeletal muscle fibers were studied with fast imaging techniques that take advantage of the large fluorescence...Full Text Available

1991-01-01

433

Granule cells in the CA3 area  

UK PubMed Central (United Kingdom)

A fundamental property of neuronal networks in Ammon’s horn is that each area is comprised of a single glutamatergic cell population and various types of GABAergic neurons. Here we describe...Full Text Available

2010-06-16

434

Glass-cordierite-mullite ceramics of low dielectric constant; Tworzywa szklano-kordierytowo-mulitowe o malej przenikalnosci elektrycznej  

Energy Technology Data Exchange (ETDEWEB)

Glass-ceramic materials containing 0-60% glass, 0-40% cordierite and 0-40% mullite were developed with dielectric constant lower than of Al{sub 2}O{sub 3} (5.2-6.7). The following glasses were used: SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}, CaO-ZnO-B{sub 2}O{sub 3}, CaO-ZnO-Al{sub 2}O{sub 3}B{sub 2}O{sub 3}, BaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2} and BaO-ZnO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}. The influence of the content of the particular components on the value of dielectric constant of the ceramics was investigated. (author). 9 refs, 3 tabs.

1997-12-31

435

Genetic evidence of illegal trade in protected whales links Japan with the US and South Korea  

UK PubMed Central (United Kingdom)

We report on genetic identification of ‘whale meat’ purchased in sushi restaurants in Los Angeles, CA (USA) in October 2009 and in Seoul, South Korea in June and September 2009. Phylogenetic...Full Text Available

2010-10-23

436

First-principles calculations of the stability and local structure of #alpha#-sialon ceramics on the line Si_3N_4- 1/2 Ca_3N_2:3AlN  

International Nuclear Information System (INIS)

The atomic structures of calcium sialons Ca_xSi_1_2_-_mAl_mN_1_6 (m = 0.5, 1, 2, 4) with the #alpha#- or #beta#-Si_3N_4-type structure were calculated, using the ab initio DFT approach, including relaxations of both lattice parameters and positions of the atoms. For all m values the #alpha#-Si_3N_4-type structure has a lower energy than the #beta#-type. For m = 1, 2 and 4 the #alpha#-type structure is also stable against decomposition into the metal nitrides, in agreement with experimental data. For m = 0.5 stability becomes uncertain. Al ions prefer positions close to Ca. Rather strong structural relaxations occur around the Ca ion.

2004-04-28

437

Effect of capsaicin-sensitive sensory nerves on plasma glucose and catecholamine levels during 2-deoxyglucose-induced stress in conscious rats.  

UK PubMed Central (United Kingdom)

1. Sensory fibres innervate the adrenal medulla but their function is not known. In this paper we have studied the effect of capsaicin-sensitive sensory fibres on the adrenal catecholamine (CA) response...Full Text Available

1990-07-01

438

Effect of Na/sub 3/Zn- and Na/sub 3/Ca DTPA on the behaviour and biological effect of /sup 239/Pu in rats  

Energy Technology Data Exchange (ETDEWEB)

The effect of a complexon therapy scheme including early (in 1 h) administration of Na/sub 3/Ca DTPA and subsequent administration of Na/sub 3/Zn DTPA or Na/sub 3/Ca DTPA at a dose of 25 ..mu..Cimol/kg/day by three 2-week courses (5 times a week) with 2-week interruptions was studied in experiments on 541 male rats after intraperitoneal administration of /sup 239/Pu citrate complex (95 kBq/kg). The treatment resulted in a 3-fold lessening of the content of /sup 239/Pu and absorbed doses in the skeleton, a significant prolongation of the mean survival time (MST) from 452 to 593 days (Na/sub 3/Zn DTPA) and 643 days (Na/sub 3/Ca DTPA), and in a decrease of the osteosarcoma incidence from 76.4 to 32.6-41.2%. The ratio of osteosarcomas per 1 Gy retained in rats (0.076-0.083 %) did not differ from that in untreated animals.

1985-02-01

439

Early Life History of the Nurseryfish, Kurtus gulliveri (Perciformes: Kurtidae), from Northern Australia  

Science.gov (United States)

... Brill, Leiden, The Netherlands. Berra, T. M. 2001. Freshwater fish distribution. Academic Press: San Diego, CA. Berra, T. M. ... ...

440

Dr. Ellen Ochoa - Welcome to Latina Women of NASA home page  

Science.gov (United States)

Feb 28, 2001 ... Dr. Ellen Ochoa was born on May 10, 1958 in Los Angeles, CA, but considers Las Mesa, California to be her hometown. She received her ...

441

Dimeric subunit stoichiometry of the human voltage-dependent proton channel Hv1  

UK PubMed Central (United Kingdom)

In voltage-gated Na+, K+, and Ca2+ channels, four voltage-sensor domains operate on a central pore domain in response to membrane voltage. In contrast, the voltage-gated...Full Text Available

2008-06-03

442

Development of rat CA1 neurones in acute Versus organotypic slices: role of experience in synaptic morphology and activity  

UK PubMed Central (United Kingdom)

Despite their wide use, the physiological relevance of organotypic slices remains controversial. Such cultures are prepared at 5 days postnatal. Although some local circuitry remains intact, they develop...Full Text Available

2003-07-01

443

Defects in the Secretory Pathway and High Ca2+ Induce Multiple P-bodies  

UK PubMed Central (United Kingdom)

mRNA is sequestered and turned over in cytoplasmic processing bodies (PBs), which are induced by various cellular stresses. Unexpectedly, in Saccharomyces cerevisiae, mutants of the...Full Text Available

2010-08-01

444

Compatibilisation of starch/poly(butylene adipate co-terephthalate) blends in blown films  

British Library Electronic Table of Contents (United Kingdom)

Summary Reactive extrusion was utilised for starch/poly(butylene adipate co-terephthalate) (PBAT) blown film production, using maleic anhydride (MA) and citric acid (CA), alone or combined, as compatibilisers. These compounds (2% w/w) were added to the starch/PBAT (55:45) mixture after dispersion on glycerol. More rigid films, with greater tensile strength (9.82--0.45-MPa), were produced when 2.0% CA was used. The opposite, little homogeneity and poor tensile strength (0.77--0.12-MPa) and elongation (2.67--0.67%) were found in films produced using 2.0% MA. Barrier properties to water vapour were improved by compatibilisers. FTIR analysis showed that CA and MA were able to promote esterification/transesterification reactions. Blends containing CA also showed better phase compatibilisation i...

2011-01-01

445

Chronic Cocaine-Induced H3 Acetylation and Transcriptional Activation of CaMKII? in the Nucleus Accumbens Is Critical for Motivation for Drug Reinforcement  

UK PubMed Central (United Kingdom)

The regulation of gene expression in the brain reward regions is known to contribute to the pathogenesis and persistence of drug addiction. Increasing evidence suggests that the regulation of gene transcription...Full Text Available

2010-03-01

446

Chemical synthesis and characterization of Ca-substituted YAlO_3 as electrolyte for solid oxide fuel cells  

International Nuclear Information System (INIS)

In this study, perovskite type oxide YAlO_3 has been doped with different amounts of the divalent cation Ca to synthesize Y_1_-_xCa_xAlO_3_-_#delta# (x = 0-0.21) compositions. The effect of dopant concentration on the crystal structure and electrical properties of YAlO_3 synthesized by citrate gel route has been investigated. The phase purity of the samples has been carried out using X-ray diffraction. The microstructural evaluation of the samples has been conducted by scanning electron microscopy and energy dispersive spectrum analysis. Thermal analysis has been conducted to monitor the decomposition of the intermediate products. The electrical conductivity studies have been performed using a.c. impedance spectroscopy as a function of temperature in the range 200-800 "oC in air. The Y_0_._9_4Ca_0_._0_6AlO_3_-_#delta# composition exhibits a total conductivity of 2.5 mS/cm at 800 "oC.

2010-04-30

447

Capsaicin-sensitive sensory neurons are involved in the plasma catecholamine response of rats to selective stressors.  

UK PubMed Central (United Kingdom)

1. The effect of capsaicin pre-treatment on adrenal catecholamine (CA) secretion in response to stress is controversial. In earlier experiments performed under pentobarbitone anaesthesia, the release...Full Text Available

1991-02-01

448

Calcium/Calmodulin-Dependent Protein Kinase II Mediates Hippocampal Glutamatergic Plasticity During Benzodiazepine Withdrawal  

UK PubMed Central (United Kingdom)

Benzodiazepine withdrawal anxiety is associated with potentiation of α-amino-3-hydroxy-5-methyl-4-isoxazolepropionate receptor (AMPAR) currents in hippocampal CA1 pyramidal...Full Text Available

2010-08-01

449

Calcium Effects on Stomatal Movement in Commelina communis L. 1  

UK PubMed Central (United Kingdom)

Stomatal movements depend on both ion influx and efflux; attainment of steady state apertures reflects modulation of either or both processes. The role of Ca2+ in those two processes was...Full Text Available

1988-07-01

450

CTX-M ?-Lactamases in Escherichia coli from Community-acquired Urinary Tract Infections, Cambodia  

UK PubMed Central (United Kingdom)

Despite the recent global spread of CTX-M β-lactamases in Escherichia coli isolates from community-acquired urinary tract infections (CA-UTIs), their dissemination has been...Full Text Available

2009-05-01

451

Amelioration of acidic coal mine overburden from Collie, Western Australia  

Energy Technology Data Exchange (ETDEWEB)

Rehabilitation of open-cut coal mining spoils at Collie, Western Australia, requires amelioration before adequate survival and growth of rehabilitation species can occur. Lolium ridgidum was used in a greenhouse pot experiment to assess the ability of lime (CaCO/sub 3/) and two waste-products of regional industry, bauxite processing caustic waste (red mud) and timber milling refuse (sawdust), to render the low pH spoils suitable for plant growth. CaCO/sub 3/ at 1% and red mud at 18% were both effective in reducing acidity and levels of available Al in the overburden. Red-mud treatment produced 10-fold increases in plant dry matter accumulation over the CaCO/sub 3/ treatment when no fertilizer was used. This is due to the presence of significant amounts of phosphorus in the red mud. With additions of a balanced NPK fertilizer at 0.077%, CaCO/sub 3/ treatment produced the best plant growth in this ...

1983-09-01

452

Age-dependent changes in Ca2+ homeostasis in peripheral neurones: implications for changes in function  

UK PubMed Central (United Kingdom)

Calcium ions represent universal second messengers within neuronal cells integrating multiple cellular functions, such as release of neurotransmitters, gene expression, proliferation, excitability,...Full Text Available

2007-06-01

453

Acute atrial arrhythmogenicity and altered Ca2+ homeostasis in murine RyR2-P2328S hearts  

UK PubMed Central (United Kingdom)

AimsThe experiments explored for atrial arrhythmogenesis and its possible physiological background in recently developed hetero-(RyR2+/S) and homozygotic...Full Text Available

2011-03-01

454

Activity-Dependent Augmentation of Spontaneous Neurotransmission during Endoplasmic Reticulum Stress  

UK PubMed Central (United Kingdom)

The endoplasmic reticulum (ER) is an essential cellular compartment responsible for Ca2+ sequestration, signaling, protein translation, folding as well as transport. Several acute...Full Text Available

2010-05-26

455

A cytochrome P450 terpenoid hydroxylase linked to the suppression of insect juvenile hormone synthesis  

UK PubMed Central (United Kingdom)

A cDNA encoding a cytochrome P450 enzyme was isolated from a cDNA library of the corpora allata (CA) from reproductively active Diploptera punctata cockroaches. This P450 from the endocrine...Full Text Available

1998-10-27

456

A church-based intervention to promote informed decision-making for prostate cancer screening among African-American men  

UK PubMed Central (United Kingdom)

ObjectivesThis feasibility study developed and pilot tested an intervention to: (1) increase knowledge about prostate cancer (CaP) screening; and (2) promote self-efficacy...Full Text Available

2010-03-01

457

A caGRID-ENABLED, LEARNING BASED IMAGE SEGMENTATION METHOD FOR HISTOPATHOLOGY SPECIMENS  

UK PubMed Central (United Kingdom)

Accurate segmentation of tissue microarrays is a challenging topic because of some of the similarities exhibited by normal tissue and tumor regions. Processing speed is another consideration...Full Text Available

2009-07-01

458

Recovery of uranium from aqueous solutions using calcined powders of CaO-Al/sub 2/O/sub 3/-SO/sub 3/ system  

Energy Technology Data Exchange (ETDEWEB)

Aqueous solutions of Al/sub 2/(SO/sub 4/)/sub 3/ (1.05 g/100 ml), AlCl/sub 3/ (0.82 g/100 ml) and Ca(OH)/sub 2/ slurry (0.94 g/50 ml) were mixed in various volume ratios and passed through a filter. White cakes left on the filter consisted mainly of ettringite (6CaO.Al/sub 2/O/sub 3/.3SO/sub 3/.32H/sub 2/O). The cakes were then calcined at various temperatures of 300/sup 0/ -- 1000/sup 0/C for 30 and 60 min and pulverized to 80 -- 200 mesh powders. The adsorption capacity of the powders for U(VI) ions dissolved in aqueous solutions was determined by immersing 0.100 g of their powders in 50 ml of the aqueous solution containing 100 ppm of U(VI) ions mainly in the form of (UO/sub 2/(CO/sub 3/)/sub 3/)/sup 4 -/ for 2 hours. The results obtained were summarized as follows. 1) Among the powders prepared, those of the oxide compositions, 2.9CaO.Al/sub 2/O/sub 3/.1.4SO/sub 3/ and 2.5CaO.Al/sub 2/O/sub ...

1981-11-01

459

ZZ KAFAX-F22, 80 and 24 Groups Cross-Section Library in MATXS Format Based on JEF-2.2 for Fast Reactors  

International Nuclear Information System (INIS)

1 - Description: Format: MATXS. Number of groups: 80 neutron-, 24 photon-groups. 97 Nuclides: 1-H-1, 1-H-2, 2-He-3, 2-He-4, 3-Li-6, 3-Li-7, 4-Be-9, 5-B-10, 5-B-11, 6-C- nat., 7-N-14, 7-N-15, 8-O-16, 9-F-19, 11-Na-23, 12-Mg-nat., 13-Al-27, 14-Si-nat., 15-P-31, 17-Cl-nat., 18-Ar-40, 19-K-nat., 20-Ca-nat., 22-Ti-nat., 23-V-nat., 24-Cr-50, 24-Cr-52, 24-Cr-53, 24-Cr-54, 25-Mn-25, 26-Fe-54, 26-Fe-56, 26-Fe-57, 26-Fe-58, 27-Co-59, 28-Ni-58, 28-Ni-60, 28-Ni-61, 28-Ni-62, 28-Ni-64, 29-Cu-nat., 31-Ga-nat., 39-Y-89, 40-Zr-nat., 41-Nb-93, 42-Mo-nat., 47-Ag-107, 47-Ag-109, 48-Cd-nat., 50-Sn-nat., 63-Eu-151, 63-Eu-153, 64-Gd-152, 64-Gd-154, 64-Gd-155, 64-Gd-156, 64-Gd-157, 64-Gd-158, 64-Gd-160, 73-Ta-181, 74-W-182, 74-W-183, 74-W-184, 74-W-186, 75-Re-185, 75-Re-187, 79-Au-197, 82-Pb-nat., 83-Bi-209, 90-Th-232, 91-Pa-233, 92-U-232, 92-U-233, 92-U-234, 92-U-235, 92-U-236, 92-U-237, 92-U-238, 93-Np-237, 93-Np-238, 94-Pu-238, 94-Pu-239, 94-Pu-240, 94-Pu-241, ...

460

WLUP3.0, 69 and 172 Group Cross Section Libraries for WIMS  

International Nuclear Information System (INIS)

Description or function: WLUP contains validated WIMS-D formatted cross section libraries in 69 and 172 energy group structures for nuclear reactor calculations. Materials from recently released evaluated nuclear data libraries are included. The NJOY nuclear data processing system was applied for generating the cross section files following the models and conventions built into the WIMS-D lattice code. The relevant features for the WIMS users are: - Energy group structures: 69 and 172 energy groups. - List of materials: WIMS ID, general information, source of data. - Cross sections: 69 and 172 group plots. - Resonance data: WIMS ID, temperature, background cross sections. - Goldstein-Cohen factors: Goldstein-Cohen lambda values. - Thermal scattering data: thermal scattering laws and P1 matrixes. - Fission spectrum: fission spectrum data. - Burnup data: burnup chains. - Fission product yields: fission yield tables. - Pseudo lumped fission product: Description of pseudo fission product. ...

461

Use of X-ray fluorescence analysis in the study of archeological samples  

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence analysis (XFA) was used in the determination of the contents of metal residues in dosing plates for coin minting. XFA was also used for the determination of the strontium/calcium ratio in bone samples of different animals with the aim to obtain information on the food composition of these animals. It was found that bones of different animals can be distinguished based on the Sr/Ca ratio. No significant differences in the Sr/Ca ratio were observed in human bones of individuals from different social groups. (author). 1 fig., 5 tabs., 4 refs.

1988-09-26

462

Quantitative variations in the vaginal bacterial population associated with asymptomatic infections: a real-time polymerase chain reaction study.  

Science.gov (United States)

The real-time polymerase chain reaction (PCR) quantification of several vaginal bacterial groups in healthy women and patients developing asymptomatic bacterial vaginosis (BV) and candidiasis (CA) was performed. Statistical analysis revealed that the BV condition is characterised by a great variability among subjects and that it is associated with a significant increase of Prevotella, Atopobium, Veillonella and Gardnerella vaginalis, and a drop in Lactobacillus. On the contrary, the vaginal microflora of healthy women and patients developing CA was found to be homogeneous and stable over time. PMID:18762999

2008-09-02

463

Quantitative variations in the vaginal bacterial population associated with asymptomatic infections: a real-time polymerase chain reaction study  

British Library Electronic Table of Contents (United Kingdom)

The real-time polymerase chain reaction (PCR) quantification of several vaginal bacterial groups in healthy women and patients developing asymptomatic bacterial vaginosis (BV) and candidiasis (CA) was performed. Statistical analysis revealed that the BV condition is characterised by a great variability among subjects and that it is associated with a significant increase of Prevotella, Atopobium, Veillonella and Gardnerella vaginalis, and a drop in Lactobacillus. On the contrary, the vaginal microflora of healthy women and patients developing CA was found to be homogeneous and stable over time.

2009-01-01

464

Polythermal study of the M(ClO_4)_2-H_2O systems, where M"2 = Mg"2"+, Ca"2"+, Sr"2"+, Ba"2"+  

International Nuclear Information System (INIS)

Crystallization points of aqueous solution of the systems M(ClO_4)_2-H_2O (M"2 = Mg"2"+, Ca"2"+, Sr"2"+, Ba"2"+), depending on the salt concentration, were identified by visual-polythermal method. Relying on model notions on the structure of the electrolyte solutions, specific features of strontium perchlorate solubility polytherm and concentration dependence of the relative dynamic viscosity of the salt aqueous solutions are discussed

2005-03-01

465

Phase separation, transport and magnetic properties of La2/3A1/3Mn1-xCoxO3, A=Ca, Sr (0.5x1)  

British Library Electronic Table of Contents (United Kingdom)

We present the low-temperature physical properties of the polycrystalline perovskite systems La2/3A1/3Mn1-xCoxO3, A=Ca, Sr (0.5x1) including electrical resistance, magnetization, ac and dc susceptibilities. The experimental data suggest the presence of correlated ferromagnetic clusters embedded in some non-ferromagnetic matrix. The systems show semiconducting behavior and negative magnetoresistance.

2008-01-01

466

Performance optimization of the Packard 2000 CA/LL liquid scintillation counter for "1"4C dating  

International Nuclear Information System (INIS)

The ability of the Packard 2000 CA/LL liquid scintillation counter to reduce background count rates relies on pulse shape/duration analysis in which short duration organic scintillation events are discriminated from longer duration non-quenchable background events. A consequence of this is a loss in the counting efficiency. The results of this investigation indicate that much of the lost efficiency can be regained by sharpening the true #beta#"- pulse widths via the use of different scintillant combinations and by certain counter modifications. (author).

467

New diffractional approach to proton-nucleus scattering  

International Nuclear Information System (INIS)

A ''coherent flucton'' nuclear model is proposed which provides for new possibilities for particle scattering studies on nuclei. It is based on the data of nuclear matter density distribution and is used for calculating the ground state energy of Fermi system terminals. The ''coherent flucton'' model is applied to the distribution of 1 GeV protons on "2"8Si, "3"2S, "4"0Ca, "4"8Ca, "5"8Ni, "2"0"8Pb nuclei. The calculations by the model agree well with experimental data.

2002-11-01

468

NEUTRON-ABSORBING BRICKS MADE FROM CaB$sup 6$  

Science.gov (United States)

nsive neutron-absorbing bricks from commercially available CaB/sub 6/ powder. The bricks are 2 x 3 x 5 in., and are strong enough to withstand normal handling. They last indefinitely; the ones described are now 7 years old, used and stored under normal room temperatures and humidities. The procedure is to make a thick, dry mud with the powder and water, followed by compression in a mold at pressures of about 1 ton/in./sup 2/ or more. The bricks are then baked for 2 hours or longer at a temperature of about 750 deg C. (auth)

1960-05-01

469

Identification of elements in plant drugs and their water infusion using X-ray fluorescence analysis  

International Nuclear Information System (INIS)

The present work gives preliminary results of analysis of drug mixtures (NEPHROSAL tea bag) and its water infusion. In a sample of dried drugs the elements K, Ca, Mn, Fe, Ni, Cu, Zn, Br, Rb, Sr, Pb were identified, whereas in their water infusion only Ca, Mn, Zn and Sr were found. The method applied was radionuclide X-ray fluorescence analysis using a radionuclide source "1"0"9Cd, a Si/Li semiconductor detector and a multichannel analyzer Canberra 8100. (author) 6 refs.; 3 figs.

8100-01-01

470

High temperature crystalline superconductors from crystallized glasses  

Energy Technology Data Exchange (ETDEWEB)

A method of preparing a high temperature superconductor from an amorphous phase. The method involves preparing a starting material of a composition of Bi.sub.2 Sr.sub.2 Ca.sub.3 Cu.sub.4 Ox or Bi.sub.2 Sr.sub.2 Ca.sub.4 Cu.sub.5 Ox, forming an amorphous phase of the composition and heat treating the amorphous phase for particular time and temperature ranges to achieve a single phase high temperature superconductor.

1992-01-01

471

Coupled-channels calculations of elastic and inelastic scattering  

Energy Technology Data Exchange (ETDEWEB)

Cross sections for the elastic and inelastic scattering of /sup 16/O on /sup 58/Ni, /sup 88/Sr, /sup 40/Ca, and /sup 48/Ca have been calculated in a coupled-channels treatment, including the low-lying 2/sup +/ and 3/sup /minus// states of both projectile and target. Real, energy-independent ion-ion potentials and form factors were used, and fusion was simulated by ingoing wave boundary conditions in all channels. The agreement with the measured scattering data is qualitatively as good as obtained in previous optical-model calculations.

1989-07-01

472

Coupled-channels calculations of elastic and inelastic scattering  

International Nuclear Information System (INIS)

Cross sections for the elastic and inelastic scattering of "1"6O on "5"8Ni, "8"8Sr, "4"0Ca, and "4"8Ca have been calculated in a coupled-channels treatment, including the low-lying 2"+ and 3"- states of both projectile and target. Real, energy-independent ion-ion potentials and form factors were used, and fusion was simulated by ingoing wave boundary conditions in all channels. The agreement with the measured scattering data is qualitatively as good as obtained in previous optical-model calculations.

473

Collective charge excitation of Sr_1_4_-_xCa_xCu_2_4O_4_1. A fingerprint of novel charge ordered state?  

International Nuclear Information System (INIS)

We review recent progress on experimental studies of collective charge excitations in hole-doped spin ladder system Sr_1_4_-_xCa_xCu_2_4O_4_1, focusing on anomalous features of phase excitation. We also discuss possible candidates for related charge ordered state, together with a controversial issue of the hole density transferred from spin chain layers to spin ladder layers. (author)

2007-04-01

474

Alpha-particle scattering from Ca-nuclei  

International Nuclear Information System (INIS)

The possibilities, advantages, and difficulties of determining nuclear matter densities by elastic scattering of alpha-particles are generally discussed. On the basis of particular experimental data - 104 MeV alpha-particle scattering from "4"0,"4"2,"4"4,"4"8Ca - a refined folded potential is introduced using a density-dependent alpha-nucleon-interaction and target nucleus densities described by Fourier-Bessel-series. Thereby, the total nucleon densities of these isotopes were determined with little model dependence. The resulting root-mean-square radii and density differences are compared with other experimental results obtained by different methods. (orig.).

1979-07-01

475

X-ray absorption spectroscopy, EELS, and full-potential augmented plane wave study of the electronic structure of Ti_2AlC, Ti_2AlN, Nb_2AlC, and (Ti_0_._5Nb_0_._5)_2AlC  

International Nuclear Information System (INIS)

The structural parameters of various Haegg phases (H or M_n_+_1AX_n phases) are studied experimentally by x-ray and electron spectroscopies, x-ray diffraction, and ab initio full potential as well as full mutiple scattering theoretical calculations. Experimentally it was found that the structure of all ternary compounds analyzed herein are relaxed. The values of the lattice parameters and relaxations obtained from ab initio calculations are in excellent agreement with those deduced from the analysis of the experimental data. The bonding scheme has been analyzed and the charge transfer between constituting atoms determined. It is demonstrated that the strength and electrical transport properties in these materials are principally governed by the metallic planes. For the solid solution (Ti_0_._5Nb_0_._5)_2AlC, the most salient result is that the basal planes are corrugated, which could explain the solid solution scattering observed in this H phase.

2005-01-01

476

Thin TiO2 grown by metal?organic chemical vapor deposition on (NH4)2S x -treated InP  

British Library Electronic Table of Contents (United Kingdom)

The electrical characteristics of thin TiO2 films prepared by metal?organic chemical vapor deposition grown on a p-type InP substrate were studied. For a TiO2 film of 4.7?nm on InP without and with ammonium sulfide treatment, the leakage currents are 8.8?10?2 and 1.1?10?4?A/cm2 at +2 V bias and 1.6?10?1 and 8.3?10?4?A/cm2 at ?2?V bias. The lower leakage currents of TiO2 with ammonium sulfide treatment arise from the improvement of interface quality. The dielectric constant and effective oxide charge number density are 33 and 2.5?1013?cm2, respectively. The lowest mid-gap interface state density is around 7.6?1011?cm?2?eV?1. The equivalent oxide thickness is 0.52?nm. The breakdown electric field increases with decreasing thickness in the range of 2.5 to 7.6?nm and reaches 9.3?MV/cm at 2.5?n...

2011-01-01

477

The role of crystallographic and geometrical relationships between #alpha# and #beta# phases in an #alpha#/#beta# titanium alloy  

International Nuclear Information System (INIS)

The present study has examined for #alpha#/#beta#-Ti alloys the relationship between the morphology and crystallography of Widmanstaetten plates of #alpha#-Ti in colonies within a prior grain of #beta#-Ti. Thus, optical metallography, scanning electron microscopy and transmission electron microscopy have been used to characterize the morphological features of the microstructure, whereas orientation-imaging microscopy (OM) and transmission electron microscopy (TEM) have been employed to reveal crystallographic information. It has been discovered that within a prior #beta#-Ti grain, although the growth direction of the Widmanstaetten plates in given colonies may differ by large angles from #alpha#-plates in other colonies, they may exhibit very close crystallographic relationships. For example, inclined #alpha#-plates may share common basal planes and be related by a rotation of #approx#10.5 deg. about ...

2003-09-15

478

The effects of alloying elements and dilution on the hot cracking sensitivity of welds in alloy 800  

International Nuclear Information System (INIS)

Results of hot cracking on welds with compositions between alloy 800 and AWS ER NiCr 3. Investigation of the influence of Si, Mn, Ti and Al on the hot cracking suscpetibility of the alloy 800. (orig.).

479

Spectrophotometric determination of titanium and iron-application to Cherat volcanic ash, N.W.F.P  

International Nuclear Information System (INIS)

A rapid and sensitive method for the separation and determination of titanium and iron in thiocyanate system has been developed. The extractability of Ti(II) by high molecular weight (HMWA) in organic solvent (HCl/sub 3/) and its separation from Fe(III) was examined. The yellow coloured complex of Ti(II)-SCN in quantitatively extracted into the organic phase containing tribenzyl tribenzylamine (TBA) - a high molecular weight amine, whereas the blood red coloured complex of Fe(III)-SCN formed under the same conditions get separated in the aqueous phase. On the basis of the selective extractability, a method has been developed for the separation as well as simultaneous determination of Ti(II) and Fe(III) in presence of many other elements. The molar extinction coefficients were found to be 1.9 x 10/sup 5/ l mol/sup -1/ cm/sup -1/ and 1.11 x 10/sup 5/ l mol/sup -1/ cm/sup -1/ respectively for Ti(II) and ...

1998-08-01

480

Radio-frequency plasma nitriding and nitrogen plasma immersion ion implantation of Ti-6Al-4V alloy  

Energy Technology Data Exchange (ETDEWEB)

Nitrogen ion implantation improves the wear resistance of Ti-6Al-4V alloys by forming a hard TiN superficial passivation layer. However, the thickness of the layer formed by traditional ion implantation is typically 100-200 nm and may not be adequate for many industrial applications. We propose to use radio-frequency (RF) plasma nitriding and nitrogen plasma immersion ion implantation (PIII) to increase the layer thickness. By using a newly designed inductively coupled RF plasma source and applying a series of negative high voltage pulses to the Ti-6Al-4V samples. RF plasma nitriding and nitrogen PIII can be achieved. Our process yields a substantially thicker modified layer exhibiting more superior wear resistance characteristics, as demonstrated by data from micro-hardness testing, pin-on-disc wear testing, scanning electron microscopy (SEM), as well as Auger electron spectroscopy (AES). The performance of our newly ...

1997-09-01

481

Radio-frequency plasma nitriding and nitrogen plasma immersion ion implantation of Ti-6Al-4V alloy  

International Nuclear Information System (INIS)

Nitrogen ion implantation improves the wear resistance of Ti-6Al-4V alloys by forming a hard TiN superficial passivation layer. However, the thickness of the layer formed by traditional ion implantation is typically 100-200 nm and may not be adequate for many industrial applications. We propose to use radio-frequency (RF) plasma nitriding and nitrogen plasma immersion ion implantation (PIII) to increase the layer thickness. By using a newly designed inductively coupled RF plasma source and applying a series of negative high voltage pulses to the Ti-6Al-4V samples. RF plasma nitriding and nitrogen PIII can be achieved. Our process yields a substantially thicker modified layer exhibiting more superior wear resistance characteristics, as demonstrated by data from micro-hardness testing, pin-on-disc wear testing, scanning electron microscopy (SEM), as well as Auger electron spectroscopy (AES). The performance of our newly ...

1996-09-15

482

RENDEZVOUS AND DOCKING - NASA Technical Report Server (NTRS)  

Science.gov (United States)

An indicator of when the learning curve reaches a standard is when fuel consumption remains relatively ...... f4 7'tI. 1.i7J43t. F ,oo,. , F17i [ !i ...

483

Preparation of TiO2/NiO composite particles and their applications in dye-sensitized solar cells  

British Library Electronic Table of Contents (United Kingdom)

This study investigates the applicability of n-type TiO2 and p-type NiO on the FTO-glass (Fluorine doped tin oxide, SnO2:F) substrate of the working electrode in a dye-sensitized solar cell (DSSC). The working electrode was designed and fabricated by depositing a film of TiO2/NiO composite particles, which were prepared by mixing the Ni powder with TiO2 particles using dry mixing method, on a FTO-glass substrate using a spin coating process. The working electrode was then immersed in the solution of N-719 (Ruthenium) dye at a temperature of 70degreeC for 6h. Moreover, a thin film of platinum (Pt) was deposited on the FTO-glass substrate of the counter electrode using an E-beam evaporator. Finally, the DSSC was assembled, and the short-circuit photocurrent, the open-circuit photovoltage and...

2011-01-01

484

Optimization of microstructure and properties of in situ formed #beta#-O-sialon-TiN composite  

International Nuclear Information System (INIS)

A powder mixture of #alpha#-Si_3N_4, Al_2O_3, and TiO_2 was hot-pressed using different sintering cycles to search for an optimum in situ formed #beta#-O-sialon-TiN composite. The impulse excitation technique (IET), high-temperature X-ray diffraction (HTXRD), and scanning electron microscopy (SEM) were used to investigate the microstructure. Below the temperature of 1300 deg. C, the high-temperature internal friction (Q "-"1) decreases with the increase of sintering temperature, whereas the density of the material increases with the increase of sintering temperature. At a sintering temperature higher than 1850 deg. C, the ceramic could not be densified and O-sialon was not formed. Also, the mechanical properties of ceramics hot-pressed using different sintering cycles were assessed. The ceramic hot-pressed at 1700 deg. C for 10 min displays a combination of high hardness and good fracture toughness, due to an optimum combination of ...

2006-07-15

485

Multilayered Nano-Microcomposite Ti-Al-N/TiN/Al_2O_3 Coatings. Their Structure and Properties  

International Nuclear Information System (INIS)

This paper presents the first results on formation and study of structure and properties of micro- and nanocomposite combined coatings. By means of modeling the deposition processes (deposition conditions, current density-discharge, plasma composition and density, voltage) we formed the three-layer nanocomposite coatings of Ti-Al-N/Ti-N/Al_2O_3. The coating composition, structure and properties were studied using physical and nuclear-physical methods. The Rutherford proton and helium ion backscattering, scanning electron microscopy with microanalysis, grazing incidence X-ray diffraction, as well as nanohardness tests (hardness) were used. Measurements of wear resistance and corrosion resistance in NaCl, HCl and H_2SO_4 solutions were also performed. For testing mechanical properties such characteristics of layered structures as hardness H, elastic modulus E: H"3/E"2 etc. were measured. It is demonstrated that the formed three-layer nanocomposite coatings have ...

2011-07-01

486

Microstructure fracture toughness and fatigue crack growth rate in titanium alloys; Proceedings of the 1987 TMS-AIME Annual Symposium, Denver, CO, Feb. 24, 25, 1987  

Science.gov (United States)

The papers contained in this volume provide an overview of recent theoretical and experimental research related to the fracture toughness and fatigue crack growth characteristics of titanium alloys. Topics discussed include room temperature fatigue crack propagation in beta-titanium alloys, fatigue crack growth rate acceleration in alpha+beta Ti alloys, influence of transformed beta microstructures on fatigue crack growth rates in Ti-6Al-4V, and the role of inclusion and pore content on the fracture toughness of powder processed blended elemental Ti-10V-2Fe-3Al. Papers are also presented on fatigue crack growth measurements in an alpha-beta titanium alloy, the effects of thermal processing variation on the properties of Ti-6Al-4V, and the effect of microstructure on ductility and fracture toughness of alpha+beta titanium alloys.

1987-01-01

487

Laser hardening of titanium-zirconium alloy  

International Nuclear Information System (INIS)

The methods of surface modification of Ti-Zr alloy by laser treatment are considered. Characteristics of laser modification without- and with surface melting and with melting in different gaseous environments and with nickel microalloying are presented. Maximum depth, hardness and corrosion resistance are observed under nickel laser alloying.

488

LITERATURE SURVEY OF THE CORROSION BEHAVIOR OF TANTALUM, ZIRCONIUM, AND TITANIUM  

Science.gov (United States)

The corrosion behavior of Ta, Ti, and Zr in inorganic acids, bases, chlorides and miscellaneous salts, waters and gases, and organic acids and miscellaneous organic chemicals is summarized. (W.L.H)

1955-02-23

490

Influence of composite LiCl-KCl molten salt on microstructure and electrochemical performance of spinel Li4Ti5O12  

British Library Electronic Table of Contents (United Kingdom)

A series of spinel Li4Ti5O12 samples were synthesized via a composite molten-salt method (CMSM) using the mixtures of LiCl and KCl with different L values (L is defined as the molar ratio of LiCl:KCl) as the reaction media. It is found that the melting point of the composite molten salt can effectively influence the formation of particles, and leads to different electrochemical performances of the as-prepare Li4Ti5O12. The investigations of X-ray diffraction (XRD), particle size distribution (PSD), Brunauer-Emmet-Teller (BET) surface area, and scanning electron microscopy (SEM) indicate that the as-prepared Li4Ti5O12 with L=1.5 is a pure phase, and has uniform homogeneous octahedral shape particles, rather narrow PSD, and high BET surface area. Electrochemical tests show that the optimized...

2008-01-01

491

Ia-antigen-T-cell interactions for a thymus-independent antigen composed of D amino acids.  

UK PubMed Central (United Kingdom)

Synthetic polypeptide antigens of L amino acids, although bearing repeating sequences, are thymus-dependent (L-TD), whereas the same polymers composed of D amino acids are thymus-independent (D-TI),...Full Text Available

1993-02-01

493

Effect of iron and boron carbide on the densification and mechanical properties of titanium diboride ceramics  

Energy Technology Data Exchange (ETDEWEB)

The effects of Fe and B{sub 4}C on the sintering behavior and mechanical properties of TiB{sub 2} ceramics have been studied. Sintering was performed in an Ar atmosphere at 2000{degrees}C using attrition-milled TiB{sub 2} powder. When a small amount of Fe (0.5 wt%) was added, abnormal grain growth occurred and the sintered density was low. In the case of B{sub 4}C added along with 0.5 wt% Fe, however, abnormal grain growth was remarkably suppressed, and the sintered density was increased up to 95% of theoretical. But with excess Fe addition (5 wt%), B{sub 4}C grains did not act as a grain growth inhibitor, and B{sub 4}C grains were frequently trapped in large TiB{sub 2} grains. The best mechanical properties were obtained for the TiB{sub 2}-10 wt% B{sub 4}C-0.5 wt% Fe ceramics, which exhibited a three-point bending strength of 400 MPa and a fracture toughness of 5.5 MPa {center dot} m{sup 1/2}.

1989-10-01

494

Effect of iron and boron carbide on the densification and mechanical properties of titanium diboride ceramics  

International Nuclear Information System (INIS)

The effects of Fe and B_4C on the sintering behavior and mechanical properties of TiB_2 ceramics have been studied. Sintering was performed in an Ar atmosphere at 2000 degrees C using attrition-milled TiB_2 powder. When a small amount of Fe (0.5 wt%) was added, abnormal grain growth occurred and the sintered density was low. In the case of B_4C added along with 0.5 wt% Fe, however, abnormal grain growth was remarkably suppressed, and the sintered density was increased up to 95% of theoretical. But with excess Fe addition (5 wt%), B_4C grains did not act as a grain growth inhibitor, and B_4C grains were frequently trapped in large TiB_2 grains. The best mechanical properties were obtained for the TiB_2-10 wt% B_4C-0.5 wt% Fe ceramics, which exhibited a three-point bending strength of 400 MPa and a fracture toughness of 5.5 MPa #centre dot# m"1"/"2.

495

Batch test equilibration studies examining the removal of Cs, Sr, and Tc from supernatants from ORNL underground storage tanks by selected ion exchangers  

Energy Technology Data Exchange (ETDEWEB)

Bench-scale batch equilibration tests have been conducted with supernatants from two underground tanks at the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to determine the effectiveness of selected ion exchangers in removing cesium, strontium, and technetium. Seven sorbents were evaluated for cesium removal, nine for strontium removal, and four for technetium removal. The results indicate that granular potassium cobalt hexacyanoferrate was the most effective of the exchangers evaluated for removing cesium from the supernatants. The powdered forms of sodium titanate (NaTiO) and cystalline silicotitanate (CST) were superior in removing the strontium; however, for the sorbents of suitable particle size for column use, titanium monohydrogen phosphate (TiHP {phi}), sodium titanate/polyacrylonitrile (NaTiO-PAN), and titanium monohydrogen phosphate/polyacrylonitrile ...

1995-06-01

496

Assessment and influence of operational parameters on the TiO_2 photocatalytic degradation of sodium benzene sulfonate under highly concentrated solar light illumination  

International Nuclear Information System (INIS)

Sodium benzene sulfonate (BS) was decomposed in aqueous TiO_2 dispersions under highly concentrated solar light illumination to examine the photocatalytic characteristics of a parabolic round concentrator (PRC) reactor to degrade the pollutant without visible light absorption. The effects of such operational parameters as initial concentration, volume of the aqueous BS solution, oxygen purging, and TiO_2 loading on the kinetics of decomposition of BS were investigated. An effective photodegradation necessitates a suitable combination of initial volume and concentration of BS solution. Relative to atmospheric air, oxygen purging significantly accelerates the degradation process at high initial concentrations of BS (0.40 mM or 1.0 mM). Optimal TiO_2 loading was 9 gl "-"1, greater than previously reported. Elimination of TOC (total organic carbon) followed pseudo first-order kinetics in the initial stages of the ...

497

AN EMPIRICAL EQUATION ... - NASA Technical Reports Server  

Science.gov (United States)

Wood, R. A.; and Ogden, H. R.: The All-Beta Titanium Alloy (Ti-13V-llCr-3Al). DMIC Rept. 110 (ASTIA AD 214002), Battelle Mem. Inst., Apr. 17, 1959. 22. White ...

498

A novel photodiode made of hybrid organic/inorganic nanocomposite  

International Nuclear Information System (INIS)

Novel hybrid organic/inorganic nanocomposites made of metal oxide and conjugated polymer nanocomposite and its application in bulk-heterojunction solar cells were studied. The composite was composed of different concentrations of strontium titanate (SrTiO_3) and polyaniline doped phosphoric acid. The optimum concentration of strontium titanate was found to be 0.2 v/v. An inorganic-organic photovoltaic device with a structure of Ag/Pani-H_3PO_4-SrTiO_3/Al has been fabricated. The ideality factor value of the diode was found to be 1.8. This n value of the diode implies a deviation from ideal junction behaviour. The barrier height #phi#_b value for the diode was found to be 0.56 eV. The Ag/Pani-H_3PO_4-SrTiO_3/Al diode shows a photovoltaic behaviour with a maximum open-circuit voltage V_o_c of 2.49 V, and short-circuit current I_s_c of 5.6 mA under light illumination #lambda# = 460 nm. The conversion efficiency was found to be ...

2009-08-07

499

Porous silica ceramics prepared by sol-gel process-effect of H{sub 2}O/TEOS molar ratio-  

Energy Technology Data Exchange (ETDEWEB)

porous silica ceramics were prepared(with HCL catalyst)using H{sub 2}O/TEOS molar ratios of 2.6-59.0, with the EtOH/TEOS ratio fixed. After preparing 9 kinds of sol, the followings were investigated; measurement of the gelation time, thermal analyses by TG/DTA, property analyses of the intermediates by FT-IR and X-ray diffractometry with dried samples, analyses of SiO{sub 2} polymer by FT-IR, the investigation of specific surface area and pore size distribution by N{sub 2}-adsorption isotherm, and structural change of SiO{sub 2} polymer and pore morphology by TEM observation, with samples heat-treated to 500 deg. C. In the concentrations of investigated compositions and catalyst, gelation time showed a minimum at ca. 11 moles of water per one mole of TEOS, the highest degree of polymerization at ca.8-18 moles, and the largest specific surface area at ca. 11 moles, which means that the polymerization proceeded fastest at ...

1997-02-01

500

Effects of chronic swimming training on cardiac sarcolemmal function and composition.  

Science.gov (United States)

Cardiac contractile function is dependent on the integrity and function of the sarcolemmal membrane. Swimming exercise training is known to increase cardiac contractile performance. The purpose of the present study was to examine whether a swimming exercise program would alter sarcolemmal enzyme activity, ion flux, and composition in rat hearts. After approximately 11 wk of exercise training, cardiac myosin and actomyosin Ca2+-adenosinetriphosphatase (ATPase) activity was significantly higher in exercised rat hearts than in sedentary control rat hearts. Glycogen content was increased in plantaris and gastrocnemius muscles from exercised animals as was succinic dehydrogenase activity in gastrocnemius muscle of exercised rats in comparison to sedentary rat preparations. Sarcolemmal vesicles were isolated from hearts of exercise-trained and control rats. Sarcolemmal Na+-K+-ATPase and K+-p-nitrophenylphosphatase activities, Na+-Ca2+ exchange, and ...

1989-04-01