The renewable energies in France 1970-2005; Les energies renouvelables en France 1970-2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-06-15

This document provides statistical data on the renewable energies situation in France (metropolitan and overseas department) from 1970 to 2005. It concerns 1- the electric power production from renewable energies as the hydroelectric power, wind power, photovoltaic, geothermal energy and biomass and 2- the thermal power production from renewable energies as the wood energy, domestic wastes, heat pumps, geothermal energy, crops residues, biogas, thermal solar and biofuels. (A.L.B.)

Energy consumption 2005 with Danish industry

International Nuclear Information System (INIS)

Anon.

2006-01-01

The energy consumption in the Danish industries decreased with 4% from 2003 to 2005. The consumption of liquid fuels and district heat decreased with 27% and 21%, respectively. The consumption of solid fuels increased with 13%. The aim of the statistics is to elucidate the industry's energy consumption and its composition. The statistics present the development in the industry from 1973 to 2005, in which period the composition of the energy consumption has changed significantly. Especially, consumption of liquid fuels has decreased and consumption of gas and electricity has increased. (ln)

Photoelectron Emission Studies in CsBr at 257 nm

International Nuclear Information System (INIS)

Maldonado, Juan R.; Liu, Zhi; Sun, Yun; Pianetta, Piero A.; Pease, Fabian W.

2006-01-01

CsBr/Cr photocathodes were found [1,2] to meet the requirements of a multi-electron beam lithography system operating with a light energy of 4.8 eV (257nm). The fact that photoemission was observed with a light energy below the reported 7.3 eV band gap for CsBr was not understood. This paper presents experimental results on the presence of intra-band gap absorption sites (IBAS) in CsBr thin film photo electron emitters, and presents a model based on IBAS to explain the observed photoelectron emission behavior at energies below band gap. A fluorescence band centered at 330 nm with a FWHM of about 0.34 eV was observed in CsBr/Cr samples under 257 nm laser illumination which can be attributed to IBAS and agrees well with previously obtained synchrotron photoelectron spectra[1] from the valence band of CsBr films

Matrix isolation and computational study of isodifluorodibromomethane (F2CBr-Br): a route to Br2 formation in CF2Br2 photolysis.

Science.gov (United States)

George, Lisa; Kalume, Aimable; El-Khoury, Patrick Z; Tarnovsky, Alexander; Reid, Scott A

2010-02-28

The photolysis products of dibromodifluoromethane (CF(2)Br(2)) were characterized by matrix isolation infrared and UV/Visible spectroscopy, supported by ab initio calculations. Photolysis at wavelengths of 240 and 266 nm of CF(2)Br(2):Ar samples (approximately 1:5000) held at approximately 5 K yielded iso-CF(2)Br(2) (F(2)CBrBr), a weakly bound isomer of CF(2)Br(2), which is characterized here for the first time. The observed infrared and UV/Visible absorptions of iso-CF(2)Br(2) are in excellent agreement with computational predictions at the B3LYP/aug-cc-pVTZ level. Single point energy calculations at the CCSD(T)/aug-cc-pVDZ level on the B3LYP optimized geometries suggest that the isoform is a minimum on the CF(2)Br(2) potential energy surface, lying some 55 kcal/mol above the CF(2)Br(2) ground state. The energies of various stationary points on the CF(2)Br(2) potential energy surface were characterized computationally; taken with our experimental results, these show that iso-CF(2)Br(2) is an intermediate in the Br+CF(2)Br-->CF(2)+Br(2) reaction. The photochemistry of the isoform was also investigated; excitation into the intense 359 nm absorption band resulted in isomerization to CF(2)Br(2). Our results are discussed in view of the rich literature on the gas-phase photochemistry of CF(2)Br(2), particularly with respect to the existence of a roaming atom pathway leading to molecular products.

Matrix isolation and computational study of isodifluorodibromomethane (F2CBr-Br): A route to Br2 formation in CF2Br2 photolysis

International Nuclear Information System (INIS)

George, Lisa; Kalume, Aimable; Reid, Scott A.; El-Khoury, Patrick Z.; Tarnovsky, Alexander

2010-01-01

The photolysis products of dibromodifluoromethane (CF 2 Br 2 ) were characterized by matrix isolation infrared and UV/Visible spectroscopy, supported by ab initio calculations. Photolysis at wavelengths of 240 and 266 nm of CF 2 Br 2 :Ar samples (∼1:5000) held at ∼5 K yielded iso-CF 2 Br 2 (F 2 CBrBr), a weakly bound isomer of CF 2 Br 2 , which is characterized here for the first time. The observed infrared and UV/Visible absorptions of iso-CF 2 Br 2 are in excellent agreement with computational predictions at the B3LYP/aug-cc-pVTZ level. Single point energy calculations at the CCSD(T)/aug-cc-pVDZ level on the B3LYP optimized geometries suggest that the isoform is a minimum on the CF 2 Br 2 potential energy surface, lying some 55 kcal/mol above the CF 2 Br 2 ground state. The energies of various stationary points on the CF 2 Br 2 potential energy surface were characterized computationally; taken with our experimental results, these show that iso-CF 2 Br 2 is an intermediate in the Br+CF 2 Br→CF 2 +Br 2 reaction. The photochemistry of the isoform was also investigated; excitation into the intense 359 nm absorption band resulted in isomerization to CF 2 Br 2 . Our results are discussed in view of the rich literature on the gas-phase photochemistry of CF 2 Br 2 , particularly with respect to the existence of a roaming atom pathway leading to molecular products.

Pathways for the OH + Br2 → HOBr + Br and HOBr + Br → HBr + BrO Reactions.

Science.gov (United States)

Wang, Hongyan; Qiu, Yudong; Schaefer, Henry F

2016-02-11

The OH radical reaction with Br2 and the subsequent reaction HOBr + Br are of exceptional importance to atmospheric chemistry and environmental chemistry. The entrance complex, transition state, and exit complex for both reactions have been determined using the coupled-cluster method with single, double, and perturbative triple excitations CCSD(T) with correlation consistent basis sets up to size cc-pV5Z and cc-pV5Z-PP. Coupled cluster effects with full triples (CCSDT) and full quadruples (CCSDTQ) are explicitly investigated. Scalar relativistic effects, spin-orbit coupling, and zero-point vibrational energy corrections are evaluated. The results from the all-electron basis sets are compared with those from the effective core potential (ECP) pseudopotential (PP) basis sets. The results are consistent. The OH + Br2 reaction is predicted to be exothermic 4.1 ± 0.5 kcal/mol, compared to experiment, 3.9 ± 0.2 kcal/mol. The entrance complex HO···BrBr is bound by 2.2 ± 0.2 kcal/mol. The transition state lies similarly well below the reactants OH + Br2. The exit complex HOBr···Br is bound by 2.7 ± 0.6 kcal/mol relative to separated HOBr + Br. The endothermicity of the reaction HOBr + Br → HBr + BrO is 9.6 ± 0.7 kcal/mol, compared with experiment 8.7 ± 0.3 kcal/mol. For the more important reverse (exothermic) HBr + BrO reaction, the entrance complex BrO···HBr is bound by 1.8 ± 0.6 kcal/mol. The barrier for the HBr + BrO reaction is 6.8 ± 0.9 kcal/mol. The exit complex (Br···HOBr) for the HBr + BrO reaction is bound by 1.9 ± 0.2 kcal/mol with respect to the products HOBr + Br.

Annual energy reviews-2005

International Nuclear Information System (INIS)

2006-01-01

The important items related to energy in 2005 fiscal year on present state on 1) energy demand and supply, 2) development and research trends on application technology of energy resources, 3) development and research trends on technology of energy conversion, 4) environment, and 5) miscellaneous are described. On the first item, trend on energy demand and supply, present state of energy supply, and trend of business field on energy demand and supply are explained. On the second item, petroleum, coal, natural gas, nuclear energy, natural energy, waste resources, and secondary energy resources are explained. On the third item, combustion theory, trends on boiler, industrial furnace, engine, thermal energy system, high efficiency power generation technology are explained. And, on the last item, trend on environment problem and developmental trend on environmental conservation technology are explained. (J.P.N.)

Energy law - Actual problems 2004/2005; Energierecht - Aktuelle Probleme 2004/2005

Energy Technology Data Exchange (ETDEWEB)

Schwintowski, H.P. (ed.)

2006-07-01

The book under consideration contains contributions to current problems in the range of energy law which have led to intensive discussions in the years 2005 and 2006. These contributions consider franchise agreements, energy contracting, regional subset distribution systems and long-term supply contracts.

Energy of the 4(+) isomer and new bands in the odd-odd nucleus 74Br

International Nuclear Information System (INIS)

Doering, J.; Holcomb, J.W.; Johnson, T.D.; Riley, M.A.; Tabor, S.L.; Womble, P.C.; Winter, G.

1993-01-01

High-spin states of the odd-odd nucleus 74 Br were investigated via the reactions 58 Ni ( 19 F,2pn) 74 Br and 65 Cu( 12 C,3n) 74 Br at beam energies of 62 and 50 MeV, respectively. On the basis of coincidence data new levels have been introduced and partly grouped into rotational bands. Some of these new states decay to known levels of negative-parity bands built on both the ground state and the long-lived 4 (+) isomer. Thus, an excitation energy of 13.8 keV has been deduced for the long-lived isomer in 74 Br. The level sequences observed are interpreted in terms of Nilsson configurations in conjunction with collective excitations

The 2005 energy year in Finland: Electricity consumption down

International Nuclear Information System (INIS)

2006-01-01

Electricity consumption declined by 2.5% in 2005, largely as a result of a six-week labour dispute in the paper indusry and mild weather conditions, according to a report on energy industry develop rents in 2005 published by Finnish Energy Industries. Over the longer term, energy consumption is forecast to grow by close to 2% a year. Water levels in waterways and water systems across the Nordic countries returned to normal in 2005 after a long period of reduced resources, stabilising hydropower output generally Following high levels of electricity exports westwards in 2004, electricity imports from the West reached almost record levels in Finland in 2005. Together with imports from Russia, Finland imported more electricity last year than ever before - and a full fifth of Finland's energy needs were covered by net electricity imports in 2005. Two thirds of imports came from Russia, with imports reaching almost the maximum capacity of the countries' interconnectors

Energy in Croatia 2005, Annual Energy Report

International Nuclear Information System (INIS)

2006-12-01

Report presents the latest information on relations and trends in the Croatian energy sector. The reports gives a familiar overview of comprehensive data about and representative features of the Croatian energy sector, related to the supply and demand of energy at all levels. It produces a detailed analysis of energy trends and provides extensive data on capacity, reserves and prices as well as balances of individual energy sources - crude oil, petroleum products, natural gas, electricity, heat, coal and renewable source of energy. Basic economic and financial indicators, emissions of air pollutants and basic energy efficiency indicators for Croatia are also presented. In 2005, total primary energy supply in Croatia decreased slightly by 0.1 per cent with respect to the previous year. At the same time, GDP rose by 4.3 per cent, resulting in a drop in energy intensity of the total primary energy supply of 4.2 per cent. The energy intensity in Croatia was 20.1 per cent higher than the average energy intensity in the European Union, but a positive decreasing trend was noted during the past period. In 2005 the total primary energy production in Croatia fell by 3.5 per cent with respect to the previous year. The highest decrease was recorded in harnessing hydro power, and the production of crude oil and fuel wood also declined. Only the production of natural gas showed a growth of 3.5 per cent. Due to the decrease in the primary energy production, energy self-supply was also reduced to 47.9 per cent. A less value was achieved only in the year 2003. A continuing trend towards a gradual decline in energy self-supply was present throughout the past several years. Final energy demand increased by 3 per cent while demands in other sectors decreased. Energy transformation losses were reduced by 7 per cent, non-energy use declined by 5.6 per cent and energy transmission and distribution losses by 5.5 per cent, and there was a slight drop of 0.2 per cent in demand in energy

2005: risks and opportunities for the renewable energies; 2005: risques et opportunites pour les energies renouvelables

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-02-15

This press conference takes stock on the renewable energies in the world at the date of the first of february 2005. A first part presents the renewable energies activities in the world, and then more specially in France, the 2001 directive on the development of the electric power from renewable sources, the controversy around the public service charges due to the renewable energies and the fiscal advantages proposed. The second part details each renewable energies sources situation, cost, capacity: photovoltaic, wind energy, hydroelectricity, thermal solar energy, wood energy, biofuels and heat pumps. (A.L.B.)

DOE Solar Energy Technologies Program FY 2005 Annual Report

Energy Technology Data Exchange (ETDEWEB)

2006-03-01

The DOE Solar Energy Technologies Program FY 2005 Annual Report chronicles the R&D results of the U.S. Department of Energy Solar Energy Technologies Program for Fiscal Year 2005. In particular, the report describes R&D performed by the Program?s national laboratories (National Renewable Energy Laboratory, Sandia National Laboratories, Oak Ridge National Laboratory, and Brookhaven National Laboratory) and university and industry partners.

Photodissociation of C3H5Br and C4H7Br at 234 nm

International Nuclear Information System (INIS)

Kim, Hyun Kook; Paul, Dababrata; Hong, Ki Ryong; Cho, Ha Na; Kim, Tae Kyu; Lee, Kyoung Seok

2012-01-01

The photodissociation dynamics of cyclopropyl bromide (C-3H 5 Br) and cyclobutyl bromide (C 4 H 7 Br) at 234 nm was investigated. A two-dimensional photofragment ion-imaging technique coupled with a [2+1] resonance enhanced multiphoton ionization scheme was utilized to obtain speed and angular distributions of the nascent Br( 2 P 3/2 ) and Br*( 2 P 1/2 ) atoms. The recoil anisotropies for the Br and Br* channels were measured to be βBr = 0.92 ± 0.03 and βBr* = 1.52 ± 0.04 for C 3 H 5 Br and βBr = 1.10 ± 0.03 and βBr* = 1.49 ± 0.05 for C 4 H 7 Br. The relative quantum yield for Br was found to be ΦBr = 0.13 ± 0.03 and for C 3 H 5 Br and C 4 H 7 Br, respectively. The soft radical limit of the impulsive model adequately modeled the related energy partitioning. The nonadiabatic transition probability from the 3A' and 4A' potential energy surfaces was estimated and discussed

Canadian energy standards : residential energy code requirements

Energy Technology Data Exchange (ETDEWEB)

Cooper, K. [SAR Engineering Ltd., Burnaby, BC (Canada)

2006-09-15

A survey of residential energy code requirements was discussed. New housing is approximately 13 per cent more efficient than housing built 15 years ago, and more stringent energy efficiency requirements in building codes have contributed to decreased energy use and greenhouse gas (GHG) emissions. However, a survey of residential energy codes across Canada has determined that explicit demands for energy efficiency are currently only present in British Columbia (BC), Manitoba, Ontario and Quebec. The survey evaluated more than 4300 single-detached homes built between 2000 and 2005 using data from the EnerGuide for Houses (EGH) database. House area, volume, airtightness and construction characteristics were reviewed to create archetypes for 8 geographic areas. The survey indicated that in Quebec and the Maritimes, 90 per cent of houses comply with ventilation system requirements of the National Building Code, while compliance in the rest of Canada is much lower. Heat recovery ventilation use is predominant in the Atlantic provinces. Direct-vent or condensing furnaces constitute the majority of installed systems in provinces where natural gas is the primary space heating fuel. Details of Insulation levels for walls, double-glazed windows, and building code insulation standards were also reviewed. It was concluded that if R-2000 levels of energy efficiency were applied, total average energy consumption would be reduced by 36 per cent in Canada. 2 tabs.

French energy accounting in 2005

International Nuclear Information System (INIS)

2006-03-01

The energy accounting of 2005 in France continues to increase (+ 34,7%). This situation is the result of the increase of the crude oils and the fossil fuels prices. The document analyzes also the imports and exports. (A.L.B.)

Density Functional Study of Structures and Electron Affinities of BrO4F/BrO4F-

Directory of Open Access Journals (Sweden)

Wei Li

2009-07-01

Full Text Available The structures, electron affinities and bond dissociation energies of BrO4F/BrO4F− species have been investigated with five density functional theory (DFT methods with DZP++ basis sets. The planar F-Br…O2…O2 complexes possess 3A' electronic state for neutral molecule and 4A' state for the corresponding anion. Three types of the neutral-anion energy separations are the adiabatic electron affinity (EAad, the vertical electron affinity (EAvert, and the vertical detachment energy (VDE. The EAad value predicted by B3LYP method is 4.52 eV. The bond dissociation energies De (BrO4F → BrO4-mF + Om (m = 1-4 and De- (BrO4F- → BrO4-mF- + Om and BrO4F- → BrO4-mF + Om- are predicted. The adiabatic electron affinities (EAad were predicted to be 4.52 eV for F-Br…O2…O2 (3A'← 4A' (B3LYP method.

Energy transfer between the Eu2+ dipole and aggregate centers in CsBr:Eu crystals

International Nuclear Information System (INIS)

Zorenko, Yu.; Turchak, R.; Voznjak, T.

2007-01-01

The energy transfer between the Eu 2+ -V Cs dipole centers and presumable CsEuBr 3 aggregate centers has been studied in CsBr:Eu crystals by means of investigation of their time-resolved emission spectra and luminescence decay kinetics at 300 K

The 2005 energy situation in France

International Nuclear Information System (INIS)

2006-04-01

After a year 2004 of economic revival, 2005 shows a crisis of the energy prices and a slow economic activity. The year is characterized by again a petroleum consumption decrease, a poor hydro electric power which generates an increase of the fossil fuels consumption and finally a little increase of the primary energy consumption and CO 2 emissions. It provides more details on the economic and energy context, on the energy consumption and production and on the carbon dioxide emissions from the energy. (A.L.B.)

The world energy demand in 2005: confirmed increase in energy consumptions, despite soaring crude oil prices

International Nuclear Information System (INIS)

Chateau, Bertrand

2006-01-01

The world energy demand growth remains strong: 2004 experienced the highest growth since 19987, and brent prices had moderate impact in 2005: Very strong rise of energy consumptions despite high oil prices, Economic situation still favorable, Evolutions principally due to China. 2005 world energy consumption: 11,4 Gtoe: Asia accounts for 35% of the world energy consumption, China's weight (15%) continues to increase by one point every year (+5 points since 2000). Asia increases its pressure on the world energy growth in 2005: China accounts for almost half of the world energy consumption increase in 2005, the whole Asia accounts for 70%; The European consumption growth represents less than 5% of China's Growth; The American energy consumption decreases for the first time. 2005 world consumption by energy: With an increasing market share by 0,7 points, coal penetration increases; The oil market has lost 0,4 point, with an accelerating relative decrease; The relative weight of gas remains stable, with 21%. Energy efficiency and energy intensity of GDP: Slow-down of the world energy intensity decrease since 2001, whereas the economic growth is faster, due to changes in trends in China (increase in the recent years). Increase less sharp in China in 2005 (price effect). Energy intensity trends of GDP: Fast decrease in CIS since the recovery of the economic growth; Slow-down of the decrease in EU since 2000 and recovery in 2005 whereas the decrease has accelerated in the USA. Since 2000, the energy consumption increases less rapidly than the GDP almost everywhere, except for the Middle East. Projections until 2020: China and India could represent one third of the world energy growth, the whole of Asia more than 50%; Growth prospects for energy demand are low in the EU and CIS; America would account for 20% of the world energy growth (8% USA); In the rest of the world, high growth in Africa and in the Middle East. Gas could cover more than 40% of the world energy

Addition reaction of adamantylideneadamantane with Br2 and 2Br2: a computational study.

Science.gov (United States)

Islam, Shahidul M; Poirier, Raymond A

2008-01-10

Ab initio calculations were carried out for the reaction of adamantylideneadamantane (Ad=Ad) with Br2 and 2Br2. Geometries of the reactants, transition states, intermediates, and products were optimized at HF and B3LYP levels of theory using the 6-31G(d) basis set. Energies were also obtained using single point calculations at the MP2/6-31G(d)//HF/6-31G(d), MP2/6-31G(d)//B3LYP/6-31G(d), and B3LYP/6-31+G(d)//B3LYP/6-31G(d) levels of theory. Intrinsic reaction coordinate (IRC) calculations were performed to characterize the transition states on the potential energy surface. Only one pathway was found for the reaction of Ad=Ad with one Br2 producing a bromonium/bromide ion pair. Three mechanisms for the reaction of Ad=Ad with 2Br2 were found, leading to three different structural forms of the bromonium/Br3- ion pair. Activation energies, free energies, and enthalpies of activation along with the relative stability of products for each reaction pathway were calculated. The reaction of Ad=Ad with 2Br2 was strongly favored over the reaction with only one Br2. According to B3LYP/6-31G(d) and single point calculations at MP2, the most stable bromonium/Br3- ion pair would form spontaneously. The most stable of the three bromonium/Br3- ion pairs has a structure very similar to the observed X-ray structure. Free energies of activation and relative stabilities of reactants and products in CCl4 and CH2ClCH2Cl were also calculated with PCM using the united atom (UA0) cavity model and, in general, results similar to the gas phase were obtained. An optimized structure for the trans-1,2-dibromo product was also found at all levels of theory both in gas phase and in solution, but no transition state leading to the trans-1,2-dibromo product was obtained.

Analytical potential energy function for the Br + H2 system

International Nuclear Information System (INIS)

Kurosaki, Yuzuru

2001-01-01

Analytical functions with a many-body expansion for the ground and first-excited-state potential energy surfaces for the Br+H 2 system are newly presented in this work. These functions describe the abstraction and exchange reactions qualitatively well, although it has been found that the function for the ground-state potential surface is still quantitatively unsatisfactory. (author)

High Energy Performance Tests of Large Volume LaBr{sub 3}:Ce Detector

Energy Technology Data Exchange (ETDEWEB)

Naqvi, A.A.; Gondal, M.A.; Khiari, F.Z.; Dastageer, M.A. [Department of Physics, King Fahd University of Petroleum and Minerals, Dhahran (Saudi Arabia); Maslehuddin, M.M. [Center for Engineering Research, King Fahd University of Petroleum and Minerals, Dhahran (Saudi Arabia); Al-Amoudi, O.S.B. [Department of Civil Engineering, King Fahd University of Petroleum and Minerals, Dhahran (Saudi Arabia)

2015-07-01

High energy prompt gamma ray tests of a large volume cylindrical 100 mm x 100 mm (height x diameter) LaBr{sub 3}:Ce detector were carried out using a portable neutron generator-based Prompt Gamma Neutron Activation Analysis (PGNAA) setup. In this study prompt gamma-rays yield were measured from water samples contaminated with toxic elements such nickel, chromium and mercury compounds with gamma ray energies up to 10 MeV. The experimental yield of prompt gamma-rays from toxic elements were compared with the results of Monte Carlo calculations. In spite of its higher intrinsic background due to its larger volume, an excellent agreement between the experimental and calculated yields of high energy gamma-rays from Ni, Cr and Hg samples has been achieved for the large volume LaBr{sub 3}:Ce detector. (authors)

LaBr3 spectrometry for environmental monitoring

International Nuclear Information System (INIS)

Toivonen, Harri; Vesterbacka, Kaj; Pelikan, Andreas

2008-01-01

Full text: In 2005-2007 Finland renewed its country-wide monitoring network of 260 stations. As a result of the process, the ambient dose rate is measured with Geiger counters and transferred in real time to the headquarters of the Radiation and Nuclear Safety Authority (STUK) and to regional Emergency Response Centres. When the renewal was initiated, the use of NaI spectrometers was considered. These, however, do not have energy resolution good enough for resolving I-131 (364 keV) from natural radiation (Pb-214 at 352 keV). It was envisaged that in future better detectors will emerge and therefore, the station infrastructure must support spectrometric measurements. Nowadays detectors based LaBr 3 are on the markets. The devices are compatible with standard nuclear electronics and they can be easily connected to a data acquisition system, such as a Linux-based computer at the monitoring stations of STUK. LaBr 3 detector has excellent properties for environmental monitoring. The detector is large enough (sensitivity) and it has good energy resolution (2.5 - 3 %) as compared with NaI (6 - 7 %). There are two major technical drawbacks which may prevent the usage of LaBr 3 detector for monitoring purposes. Firstly, the material contains impurities of La-138 and Ac-227 which give a nasty background. Secondly, the light output of the material varies as a function of temperature deteriorating the quality of the spectrum (broadening of peaks). The detector background can be measured accurately in a lead castle. Then, after live-time correction, this spectrum can be subtracted from the monitoring spectra without disturbing statistics essentially. However, absolute stability of the energy calibration is required. This was solved by fitting the La-138 contamination multiplet at 1436-1468 keV (gamma + X rays) using a novel algorithm which treats peaks as a family, not as individuals. The analysis provides peak shift in channel units. The software then adjusts the gain of the

Energy forum 2005: Nuclear power - in competition with sustainable energy supply in Europe. Lectures

International Nuclear Information System (INIS)

2005-01-01

The forum of energy for future organized on 29st September 2005 the annual Energy Forum at Berlin. The Energy Forum 2005 dealt with nuclear power in competition with sustainable energy supply in Europe and didn't only give their members the possibility of a discussion on this actual theme. Furtheron demanding aims on CO2-reduction, increased raw material- and energy prices as the construction of a new Finnish nuclear power plant have countries moved to evaluate again the future-oriented role of nuclear power. (orig./GL)

Computer simulation of the structure of liquid metal halides RbBr, CuCl, CuBr, CuI, and AgBr

International Nuclear Information System (INIS)

Belashchenko, D.K.; Ostrovskij, O.I.

2003-01-01

The computerized models of the RbBr, AgBr, CuCl, CuBr and CuI liquid ion systems of 498 ions dimension are simulated at the temperatures of 753-960 K on the basis of the known diffraction data through the BELION algorithm. Good agreement of diffraction and model partial pair correlation functions (PPCF), excluding the PPCF first peaks heights, is obtained in all the cases. The simulation is carried out by the varied ion charges (the atomization energy values, close to the real ones, are obtained by ion charges ±1.00 for the RbBr, ±1.15 for AgBr, ±1.20 for CuCl, ±1.48 for CuBr and ±1.367 for CuI). The noncoulomb contributions in the interparticle potentials are calculated [ru

CO{sub 2} audit 1990/2005. Emissions from energy generation and transport; CO{sub 2}-Bilanz 1990/2005. Energie- und verkehrsbedingte Emissionen

Energy Technology Data Exchange (ETDEWEB)

Lueth, B.; Hoffmann-Kallen, A. (comps.)

2007-04-15

There were two studies investigating changes in energy related CO{sub 2} emissions (including CO{sub 2} equivalents) for Hannover (Federal Republic of Germany) within the period 1990 to 2005. CO{sub 2} emissions result from the combustion of fossil fuels. These have been divided into emissions due to energy consumption (electricity and heating) and the transport sector. The first study, 'Emissions caused by energy consumption (electricity and heating)' depicts the development of energy and CO{sub 2} audits for the years 1990 to 2005. Heating energy demand for 2005 was 8% lower than for 1990 due to increased energy efficiency. Furthermore, CO{sub 2} emissions were in effect reduced by 19% due to increases in the use of district heating and natural gas as alternatives to heating oil and coal. Although electricity consumption rose by 17% an increase of only 1% in CO{sub 2} emissions was registered due to improved energy efficiency through the deployment of combined heat and power plants for electricity generation. The second study, 'CO{sub 2} emissions from the transport sector' examined data for motorised traffic, local public transport, rail and air travel. Although traffic volume for these areas of transport increased during the period 1990 to 2005, effectively energy consumption for the total distance travelled decreased. Road traffic increased by 9% in Hannover over the period but fuel savings from more efficient vehicle engines resulted in an overall reduction of 6% in CO{sub 2} emissions. Despite an increase in carrying capacity of 31% (measured in seat-kilometres), CO{sub 2} emissions could be reduced by 22%. A similar trend was identified in the German rail traffic sector (local- and long-distance). Despite an overall increase in traveller kilometres across Germany, when relating this to the population of Hannover a local reduction in CO{sub 2} emissions of 17% was recorded. Air travel has doubled in Germany over the last 15 years. Thus

Referentieramingen energie en emissies 2005 - 2020

NARCIS (Netherlands)

Dril AWN van; Elzenga HE; ECN; KMD

2005-01-01

The Reference Projection 2005-2020 covers the future development of Dutch energy use, greenhouse gas emissions and air pollution up to 2020. The Reference projection is based on assumptions regarding economic, structural, technological and policy developments. Two scenarios have been used: the

Visible Light Driven Nanosecond Bromide Oxidation by a Ru Complex with Subsequent Br-Br Bond Formation.

Science.gov (United States)

Li, Guocan; Ward, William M; Meyer, Gerald J

2015-07-08

Visible light excitation of [Ru(deeb)(bpz)2](2+) (deeb = 4,4'-diethylester-2,2'-bipyridine; bpz = 2,2'-bipyrazine), in Br(-) acetone solutions, led to the formation of Br-Br bonds in the form of dibromide, Br2(•-). This light reactivity stores ∼1.65 eV of free energy for milliseconds. Combined (1)H NMR, UV-vis and photoluminescence measurements revealed two distinct mechanisms. The first involves diffusional quenching of the excited state by Br(-) with a rate constant of (8.1 ± 0.1) × 10(10) M(-1) s(-1). At high Br(-) concentrations, an inner-sphere pathway is dominant that involves the association of Br(-), most likely with the 3,3'-H atoms of a bpz ligand, before electron transfer from Br(-) to the excited state, ket = (2.5 ± 0.3) × 10(7) s(-1). In both mechanisms, the direct photoproduct Br(•) subsequently reacts with Br(-) to yield dibromide, Br(•) + Br(-) → Br2(•-). Under pseudo-first-order conditions, this occurs with a rate constant of (1.1 ± 0.4) × 10(10) M(-1) s(-1) that was, within experimental error, the same as that measured when Br(•) were generated with ultraviolet light. Application of Marcus theory to the sensitized reaction provided an estimate of the Br(•) formal reduction potential E(Br(•)/Br(-)) = 1.22 V vs SCE in acetone, which is about 460 mV less positive than the accepted value in H2O. The results demonstrate that Br(-) oxidation by molecular excited states can be rapid and useful for solar energy conversion.

Gasification under EPACT2005. US Emerging Energy and Environmental Strategies

International Nuclear Information System (INIS)

Rosenberg, W.G.

2005-11-01

To celebrate its 50th anniversary, ECN gathered a group of 30 high-level energy experts to discuss climate change mitigation strategies and their implications for energy technology development. This summary reports the main findings of the international scientific symposium. It also gives an account of the principal lessons learned, and formulates recommendations for energy innovation policy-making in the European Union. In this presentation attention is paid to gasification under the USA Energy Policy Act of 2005 (EPACT2005)

DOE Solar Energy Technologies Program FY 2005 Annual Report

Energy Technology Data Exchange (ETDEWEB)

Sutula, Raymond A. [DOE Solar Energy Technologies Program, Washington, D.C. (United States)

2006-03-01

The DOE Solar Energy Technologies Program FY 2005 Annual Report chronicles the R&D results of the program for fiscal year 2005. In particular, the report describes R&D performed by the Program’s national laboratories and university and industry partners.

White paper on atomic energy in 2005

International Nuclear Information System (INIS)

2006-03-01

Since the publication of its last White Paper on Atomic Energy in 2004, the Atomic Energy Commission of Japan (AEC) summarized trends covering all aspects of nuclear energy over the period up to December 2005. This paper is comprised of a main document and supplementary materials. In the first chapter of the main document, the first section summarized the changes on research, development and utilization of nuclear energy in 50 years from establishment of the Atomic Energy Basic Law. The second section summarized that nuclear energy utilization (energy utilization and radiation utilization) for contributing to the welfare of humanity and the improvement of the standard of living of the people, and the appropriate direction in the future and the recognitions to become its background of nuclear policies that indicated in 'Framework for Nuclear Energy Policy' (AEC decided at October 2005), concerning fundamental activities, R and D activities and international activities that essential for the realization of nuclear energy utilization. The second chapter summarized recent trends of national and private activities on research, development and utilization of nuclear energy, covering the topics 'Nuclear Energy Policy in Japan', 'Strengthening Fundamental Activities on Research, Development and Utilization of Nuclear Energy', 'Steady Promotion of Nuclear Energy Utilization', Promotion of Nuclear Energy Research and Development', Promotion of International Activity', 'Various Evaluation on Research, Development and Utilization of Nuclear Energy'. The supplementary materials include lists of AEC decisions, nuclear energy budgets, year-by-year data tables, and other such similar materials. (J.P.N.)

Energy policy act 2005 of the USA

International Nuclear Information System (INIS)

Marzi, Graziella

2006-01-01

The Energy Policy Act 2005 has ended a long energy policy debate in the United States. The new energy legislation aims to assure a stable energy supply and will impact on the structure of the electric sector and the supply of fuels. The paper assesses that while the implications on the electric sector are going to be substantial, those concerning the supply of fuels are expected to bring no significant changes in the present mix of fuels [it

Energy final consumption projection - 1985/2005 - basic scenery - Minas Gerais State

International Nuclear Information System (INIS)

1989-03-01

A projection of the final energy consumption study for the Minas Gerais State until 2005 year is presented. The conclusion of this projection shows a increasing of 108,8% for the total energy. The industries will be response for 62,0% and the transport sector will use 20,7% of the total energy in 2005. (L.J.C.)

Analytical potential energy function for the Br + H{sub 2} system

Energy Technology Data Exchange (ETDEWEB)

Kurosaki, Yuzuru [Japan Atomic Energy Research Inst., Kizu, Kyoto (Japan). Kansai Research Establishment

2001-10-01

Analytical functions with a many-body expansion for the ground and first-excited-state potential energy surfaces for the Br+H{sub 2} system are newly presented in this work. These functions describe the abstraction and exchange reactions qualitatively well, although it has been found that the function for the ground-state potential surface is still quantitatively unsatisfactory. (author)

The dynamics of the Hg + Br2 reaction: elucidation of the reaction mechanism for the Br exchange reaction.

Science.gov (United States)

Jambrina, P G; Menéndez, M; Aoiz, F J

2017-06-28

In spite of its importance in the Hg atmospheric chemistry, the dynamics of the Hg + Br 2 → HgBr + Br reaction is poorly understood. In this article, we have carried out a comprehensive study of the reaction mechanism of this reaction by means of quasiclassical trajectories (QCTs) on an existing ab initio potential energy surface (PES). The reaction has a non trivial dynamics, as a consequence of its large endothermicity, the presence of a deep potential well, and the competition between the Br exchange and the collision induced dissociation processes. Our calculations demonstrate that insertion is only relevant at energies just above the reaction threshold and that, at energies above 2.3 eV, HgBr formation typically takes place via a sort of frustrated dissociation. In order to compare directly with the results obtained in extensive cross molecular beam experiments for the homologous reaction with I 2 , angular distributions in the laboratory frame for Hg + Br 2 have been simulated under similar experimental conditions. The lack of agreement at the highest energies considered suggests that either the two reactions have substantially different mechanisms or that calculations on a single PES cannot account for the dynamics at those energies.

Absorbed dose in AgBr in direct film for photon energies (<150 keV): relation to optical density. Theoretical calculation and experimental evaluation

International Nuclear Information System (INIS)

Helmrot, E.; Alm Carlsson, G.

1996-01-01

Calculations of absorbed dose in the silver bromide were compared with measurements of optical densities in Ultra-speed and Ektaspeed films for a broad range (25-145 kV) of X-ray energy. The calculated absorbed dose values were appropriately averaged over the complete photon energy spectrum, which was determined experimentally using a Compton spectrometer. For the whole range of tube potentials used, the measured optical densities of the films were found to be proportional to the mean absorbed dose in the AgBr grains calculated according to GREENING's theory. They were also found to be proportional to the collision kerma in silver bromide (K c,AgBr ) indicating proportionality between K c,AgBr and the mean absorbed dose in silver bromide. While GREENING's theory shows that the quotient of the mean absorbed dose in silver bromide and K c,AgBr varies with photon energy, this is not apparent when averaged over the broad (diagnostic) X-ray energy spectra used here. Alternatively, proportionality between K c,AgBr and the mean absorbed dose in silver bromide can be interpreted as resulting from a combination of the SPIERS-CHARLTON theory, valid at low photon energies ( c,AgBr (at the position of the film) independent of photon energy. The importance of taking the complete X-ray energy spectrum into full account in deriving K c,AgBr is clearly demonstrated, showing that the concept of effective energy must be used with care. (orig./HP)

World nuclear generating capacity and uranium requirements to 2005

International Nuclear Information System (INIS)

Anon.

1991-01-01

The outlook for the world nuclear power industry through 2005 is more positive than some may believe. Installed nuclear electric generating capacity is forecast to grow at an average rate of 2.4 percent per year, and reach 448 gigawatts electric (GWe) by 2005. Consequently, annual world uranium requirements also will grow, reaching over 200 million pounds equivalent U 3 O 8 by 2005. This article presents data and summarizes installed nuclear generating capacity and charts its increase as a function of time through the year 2005. This data is also charted by reactor type as well as reactor status: under construction, planned, or estimated future construction. In a similar fashion, the data is also charted by country and continent. Historical and projected data is also given for capacity factor

Dye adsorbates BrPDI, BrGly, and BrAsp on anatase TiO2(001) for dye-sensitized solar cell applications

Science.gov (United States)

Çakır, D.; Gülseren, O.; Mete, E.; Ellialtıoǧlu, Ş.

2009-07-01

Using the first-principles plane-wave pseudopotential method within density functional theory, we systematically investigated the interaction of perylenediimide (PDI)-based dye compounds (BrPDI, BrGly, and BrAsp) with both unreconstructed (UR) and reconstructed (RC) anatase TiO2(001) surfaces. All dye molecules form strong chemical bonds with surface in the most favorable adsorption structures. In UR-BrGly, RC-BrGly, and RC-BrAsp cases, we have observed that highest occupied molecular orbital and lowest unoccupied molecular orbital levels of molecules appear within band gap and conduction-band region, respectively. Moreover, we have obtained a gap narrowing upon adsorption of BrPDI on the RC surface. Because of the reduction in effective band gap of surface-dye system and possibly achieving the visible-light activity, these results are valuable for photovoltaic and photocatalytic applications. We have also considered the effects of hydration of surface to the binding of BrPDI. It has been found that the binding energy drops significantly for the completely hydrated surfaces.

Projected Benefits of Federal Energy Efficiency and Renewable Energy Programs. FY 2005 - FY 2050

Energy Technology Data Exchange (ETDEWEB)

None, None

2004-05-01

This report describes a benefits analysis undertaken by EERE to better understand the extent to which the technologies and market improvements funded by its FY 2005 budget request will make energy more affordable, cleaner, and more reliable. It summarizes the results of the analysis, which focused on economic, environmental, and security benefits related to energy. The report identifies specific measures or indicators of estimated benefits for FY 2005.

Photodissociation of C{sub 3}H{sub 5}Br and C{sub 4}H{sub 7}Br at 234 nm

Energy Technology Data Exchange (ETDEWEB)

Kim, Hyun Kook; Paul, Dababrata; Hong, Ki Ryong; Cho, Ha Na; Kim, Tae Kyu [Pusan National University, Busan (Korea, Republic of); Lee, Kyoung Seok [Korea Research Institute of Standards and Science, Daejeon (Korea, Republic of)

2012-01-15

The photodissociation dynamics of cyclopropyl bromide (C-3H{sub 5}Br) and cyclobutyl bromide (C{sub 4}H{sub 7}Br) at 234 nm was investigated. A two-dimensional photofragment ion-imaging technique coupled with a [2+1] resonance enhanced multiphoton ionization scheme was utilized to obtain speed and angular distributions of the nascent Br({sup 2}P{sub 3/2}) and Br*({sup 2}P{sub 1/2}) atoms. The recoil anisotropies for the Br and Br* channels were measured to be βBr = 0.92 ± 0.03 and βBr* = 1.52 ± 0.04 for C{sub 3}H{sub 5}Br and βBr = 1.10 ± 0.03 and βBr* = 1.49 ± 0.05 for C{sub 4}H{sub 7}Br. The relative quantum yield for Br was found to be ΦBr = 0.13 ± 0.03 and for C{sub 3}H{sub 5}Br and C{sub 4}H{sub 7}Br, respectively. The soft radical limit of the impulsive model adequately modeled the related energy partitioning. The nonadiabatic transition probability from the 3A' and 4A' potential energy surfaces was estimated and discussed.

The millennium development goals and household energy requirements in Nigeria.

Science.gov (United States)

Ibitoye, Francis I

2013-01-01

Access to clean and affordable energy is critical for the realization of the United Nations' Millennium Development Goals, or MDGs. In many developing countries, a large proportion of household energy requirements is met by use of non-commercial fuels such as wood, animal dung, crop residues, etc., and the associated health and environmental hazards of these are well documented. In this work, a scenario analysis of energy requirements in Nigeria's households is carried out to compare estimates between 2005 and 2020 under a reference scenario, with estimates under the assumption that Nigeria will meet the millennium goals. Requirements for energy under the MDG scenario are measured by the impacts on energy use, of a reduction by half, in 2015, (a) the number of household without access to electricity for basic services, (b) the number of households without access to modern energy carriers for cooking, and (c) the number of families living in one-room households in Nigeria's overcrowded urban slums. For these to be achieved, household electricity consumption would increase by about 41% over the study period, while the use of modern fuels would more than double. This migration to the use of modern fuels for cooking results in a reduction in the overall fuelwood consumption, from 5 GJ/capita in 2005, to 2.9 GJ/capita in 2015.

Potential energy landscape of TIP4P/2005 water

Science.gov (United States)

Handle, Philip H.; Sciortino, Francesco

2018-04-01

We report a numerical study of the statistical properties of the potential energy landscape of TIP4P/2005, one of the most accurate rigid water models. We show that, in the region where equilibrated configurations can be generated, a Gaussian landscape description is able to properly describe the model properties. We also find that the volume dependence of the landscape properties is consistent with the existence of a locus of density maxima in the phase diagram. The landscape-based equation of state accurately reproduces the TIP4P/2005 pressure-vs-volume curves, providing a sound extrapolation of the free-energy at low T. A positive-pressure liquid-liquid critical point is predicted by the resulting free-energy.

Surfactant-promoted reactions of Cl2 and Br2 with Br- in glycerol.

Science.gov (United States)

Faust, Jennifer A; Dempsey, Logan P; Nathanson, Gilbert M

2013-10-17

Gas-liquid scattering experiments are used to explore reactions of gaseous Cl2 and Br2 with a 0.03 M solution of the surfactant tetrahexylammonium bromide (THABr) dissolved in glycerol. At thermal collision energies, 79 ± 2% of incident Cl2 molecules react with Br(-) to form Cl2Br(-) in the interfacial region. This reaction probability is three times greater than the reactivity of Cl2 with 3 M NaBr-glycerol, even though the interfacial Br(-) concentrations are similar in each solution. We attribute the high 79% uptake to the presence of surface THA(+) ions that stabilize the Cl2Br(-) intermediate as it is formed in the charged, hydrophobic pocket created by the hexyl chains. Cl2Br(-) generates the single exchange product BrCl in a 1% yield close to the surface, while the remaining 99% desorbs as the double exchange product Br2 over >0.1 s after diffusing deeply into the bulk. When NaCl is added to the surfactant solution in a 20:1 Cl(-)/Br(-) ratio, the Cl2 reaction probability drops from 79% to 46 ± 1%, indicating that Cl(-) in the interfacial region only partially blocks reaction with Br(-). In parallel, we observe that gaseous Br2 molecules dissolve in 0.03 M THABr for 10(4) times longer than in 3 M NaBr. We attribute this change to formation of stabilizing interfacial and bulk-phase THA(+)Br3(-) ion pairs, in analogy with the capture of Cl2 and formation of THA(+)Cl2Br(-) pairs. The THA(+) ion appears to be a powerful interfacial catalyst for promoting reaction of Cl2 and Br2 with Br(-) and for ferrying the resultant ions into solution.

Computations on the primary photoreaction of Br2 with CO2: stepwise vs concerted addition of Br atoms.

Science.gov (United States)

Xu, Kewei; Korter, Timothy M; Braiman, Mark S

2015-04-09

It was proposed previously that Br2-sensitized photolysis of liquid CO2 proceeds through a metastable primary photoproduct, CO2Br2. Possible mechanisms for such a photoreaction are explored here computationally. First, it is shown that the CO2Br radical is not stable in any geometry. This rules out a free-radical mechanism, for example, photochemical splitting of Br2 followed by stepwise addition of Br atoms to CO2-which in turn accounts for the lack of previously observed Br2+CO2 photochemistry in gas phases. A possible alternative mechanism in liquid phase is formation of a weakly bound CO2:Br2 complex, followed by concerted photoaddition of Br2. This hypothesis is suggested by the previously published spectroscopic detection of a binary CO2:Br2 complex in the supersonically cooled gas phase. We compute a global binding-energy minimum of -6.2 kJ mol(-1) for such complexes, in a linear geometry. Two additional local minima were computed for perpendicular (C2v) and nearly parallel asymmetric planar geometries, both with binding energies near -5.4 kJ mol(-1). In these two latter geometries, C-Br and O-Br bond distances are simultaneously in the range of 3.5-3.8 Å, that is, perhaps suitable for a concerted photoaddition under the temperature and pressure conditions where Br2 + CO2 photochemistry has been observed.

A comparative ab initio study of Br2*- and Br2 water clusters.

Science.gov (United States)

Pathak, A K; Mukherjee, T; Maity, D K

2006-01-14

The work presents ab initio results on structure and electronic properties of Br2*-.nH2O(n=1-10) and Br2.nH2O(n=1-8) hydrated clusters to study the effects of an excess electron on the microhydration of the halide dimer. A nonlocal density functional, namely, Becke's half-and-half hybrid exchange-correlation functional is found to perform well on the present systems with a split valence 6-31++G(d,p) basis function. Geometry optimizations for all the clusters are carried out with several initial guess structures and without imposing any symmetry restriction. Br2*-.nH2O clusters prefer to have symmetrical double hydrogen-bonding structures. Results on Br2.nH2O(n>or=2) cluster show that the O atom of one H2O is oriented towards one Br atom and the H atom of another H2O is directed to other Br atom making Br2 to exist as Br+-Br- entity in the cluster. The binding and solvation energies are calculated for the Br2*-.nH2O and Br2.nH2O clusters. Calculations of the vibrational frequencies show that the formation of Br2*- and Br2 water clusters induces significant shifts from the normal modes of isolated water. Excited-state calculations are carried out on Br2*-.nH2O clusters following configuration interaction with single electron excitation procedure and UV-VIS absorption profiles are simulated. There is an excellent agreement between the present theoretical UV-VIS spectra of Br2*-.10H2O cluster and the reported transient optical spectra for Br2*- in aqueous solution.

Hydro-Quebec 2005 annual report : people with energy

International Nuclear Information System (INIS)

2006-01-01

Hydro-Quebec generates, transmits and distributes electricity mainly produced by renewable energy sources. Its sole shareholder is the Quebec government. This annual report reviewed the operations of Hydro-Quebec, and provided data on energy sales, production and details of the utility's environmental programs. Information on Hydro-Quebec subsidiaries in 2005 was presented in the following separate sections: Hydro-Quebec Production; Hydro-Quebec TransEnergie; Hydro-Quebec Distribution; Hydro-Quebec Equipement; and the Societe d'energie de la Baie James. In 2005, Hydro-Quebec Distribution signed contracts for an initial block of 990 MW of wind power and issued a tender call for an additional 2000 MW of wind power. A generator balancing service was created and authorized by the Regie de l'energie. Hydro-Quebec customers have achieved energy savings of nearly 450 GWh in 2005. The commissioning of Toulnustouc generating station was achieved 5 months ahead of schedule. The 526 MW facility will generate 2.7 TWh annually. Work at the Chute-Allard and Rapide-des-Coeurs sites has continued, as well as construction at Mercier and Peribonka and Eastmain-1. Income from continuing operations came to $2.25 billion, a $124 million increase that was attributed to a rise in domestic sales and net short-term exports. The income was offset by higher pension expenses, depreciation and amortization, as well as by cost of supply on external markets and financial expenses. All other operating expenses were lower than in 2004. Capital spending for the transmission system reached its highest level since 1997, with $793 million invested, including $336 million to meet growth. Data on the company's financial performance, executive changes and reorganization were provided. Financial statements included a review and analysis of financial transactions, an auditor's report, as well as customary notes to the consolidated financial statement including balance sheets, assets, liabilities and

Scientific Report 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-04-15

The annual scientific report gives a summary overview of the research and development activities at the Belgian Nuclear Research Centre SCK-CEN in 2005. The report discusses progress and main achievements in the following areas: reactor safety, radioactive waste and clean-up, radiation protection, the BR2 reactor, nuclear research and society, managing nuclear knowledge and fusion research.

Scientific Report 2005

International Nuclear Information System (INIS)

2006-04-01

The annual scientific report gives a summary overview of the research and development activities at the Belgian Nuclear Research Centre SCK-CEN in 2005. The report discusses progress and main achievements in the following areas: reactor safety, radioactive waste and clean-up, radiation protection, the BR2 reactor, nuclear research and society, managing nuclear knowledge and fusion research

From constraint to sufficiency. The decoupling of energy and carbon from human needs, 1975-2005

Energy Technology Data Exchange (ETDEWEB)

Steinberger, Julia K. [Institute of Social Ecology, University of Klagenfurt, Vienna (Austria); Roberts, J. Timmons [Center for Environmental Studies, Brown University, Providence, RI (United States)

2010-12-15

We investigate the relationship between human needs, energy consumption and carbon emissions for several indicators of human development: life expectancy, literacy, income and the Human Development Index. We find that high human development can be achieved at moderate energy and carbon levels; increasing energy and carbon past this level does not necessarily contribute to higher living standards. By conducting a novel longitudinal analysis from 1975 to 2005, we observe a previously undetected decoupling of the per capita energy and carbon required for human needs. If resources were equally distributed, current energy and carbon levels would be more than sufficient to satisfy global human needs at high levels of human development. By projecting current trends to 2030, we demonstrate that the global energy consumption and carbon emissions required to satisfy human needs will decrease with time, despite growth in population. (author)

The 2005 energy situation in France; Bilan energetique de l'annee 2005 en France

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-04-15

After a year 2004 of economic revival, 2005 shows a crisis of the energy prices and a slow economic activity. The year is characterized by again a petroleum consumption decrease, a poor hydro electric power which generates an increase of the fossil fuels consumption and finally a little increase of the primary energy consumption and CO{sub 2} emissions. It provides more details on the economic and energy context, on the energy consumption and production and on the carbon dioxide emissions from the energy. (A.L.B.)

Estimated United States Transportation Energy Use 2005

Energy Technology Data Exchange (ETDEWEB)

Smith, C A; Simon, A J; Belles, R D

2011-11-09

A flow chart depicting energy flow in the transportation sector of the United States economy in 2005 has been constructed from publicly available data and estimates of national energy use patterns. Approximately 31,000 trillion British Thermal Units (trBTUs) of energy were used throughout the United States in transportation activities. Vehicles used in these activities include automobiles, motorcycles, trucks, buses, airplanes, rail, and ships. The transportation sector is powered primarily by petroleum-derived fuels (gasoline, diesel and jet fuel). Biomass-derived fuels, electricity and natural gas-derived fuels are also used. The flow patterns represent a comprehensive systems view of energy used within the transportation sector.

2000-2006 National Wood Energy Programme. 2000-2005 Activities Report

International Nuclear Information System (INIS)

2006-01-01

2005 was marked by key decisions which were taken with the aim of developing the biomass sector as a substitute for fossil fuels. Indeed, to achieve the ambitious objectives for renewable sources of energy set out by the July 2005 Energy Policy Orientation Programme (POPE), we must make great use of biomass, particularly to increase by 50% the share of renewable thermal energy between now and 2010 and to enable biofuels to represent 7% of all fuels used at the same date. To a lesser extent, and in conjunction with heat production, the share of biomass in renewable electricity production also needs to rise. Both the resource and key supply players are there and are ready to get organised in order to rise to these challenges. There is an abundant supply of agricultural and forest by-products. More than sixty companies organise and deliver heating wood. More than 300 government and professional promotion, regulatory, PR, finance, equipment construction and operation, research and engineering organizations are involved in this market. The strategic and economic context is highly favourable in the light of laws, directives and international agreements aiming to combat greenhouse gas emissions, but also due to the structural pressure on the price of fossil fuels. Wood energy, as a renewable energy source, has an important role to play in this context of growth. Furthermore, the wood energy sector should be developed using an exemplary sustainable development approach, which means that all the economic, social and environmental effects are taken into account. In order to comprehensively assess the sector's environmental impact, a full chapter of this report presents the work and programmes set up by ADEME to reduce pollutant emissions produced by biomass combustion, particularly from private households. Moreover, consultation and dialogue between those involved must be widened in order to enable all wood users to benefit from 'best forest use' which will be a key

Enova results report 2005; Enova resultatrapport 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-07-01

In 2005 Enova entered into agreements with 186 projects that together provided an energy result of 2 TWh. The result is almost evenly divided between projects providing higher energy production and projects that reduce energy use. The energy production consists of 585 GWh in new wind power and 409 GWh in new heat energy in 2005. Overall for the period 2001 to 2005, Enova contracted for energy results of well over 6.6 TWh. Enova is doing well in relation to the objectives set for its activities.

Sharing our energies. Corporate social responsibility report 2005; Notre energie en partage. Rapport societal et environnemental 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-05-15

Total is a multinational energy company, the fourth largest publicly-traded integrated oil and gas company in the world. Total worldwide operations are conducted through three business segments: Upstream includes oil and gas Exploration and Production, Gas and Power and other energy sources. Downstream covers Trading and Shipping,Refining and the Marketing of TOTAL and Elf brand petroleum products, automotive and other fuels, and specialties such as LPG, aviation fuel and lubricants, through both the retail network and other outlets worldwide. Chemicals comprises various activities including Base chemicals (Petrochemicals and Fertilizers) and Specialties for industry and the consumer market. This corporate social responsibility report presents the Group activity for the year 2005 in the following domains: the business principles, the environment safety and health, the social responsibility and the local development, the future of energy (fossil fuels, renewable energies and towards energy vectors). (A.L.B.)

Photoresponse of CsPbBr3 and Cs4PbBr6 Perovskite Single Crystals.

Science.gov (United States)

Cha, Ji-Hyun; Han, Jae Hoon; Yin, Wenping; Park, Cheolwoo; Park, Yongmin; Ahn, Tae Kyu; Cho, Jeong Ho; Jung, Duk-Young

2017-02-02

High-quality and millimeter-sized perovskite single crystals of CsPbBr 3 and Cs 4 PbBr 6 were prepared in organic solvents and studied for correlation between photocurrent generation and photoluminescence (PL) emission. The CsPbBr 3 crystals, which have a 3D perovskite structure, showed a highly sensitive photoresponse and poor PL signal. In contrast, Cs 4 PbBr 6 crystals, which have a 0D perovskite structure, exhibited more than 1 order of magnitude higher PL intensity than CsPbBr 3 , which generated an ultralow photoresponse under illumination. Their contrasting optoelectrical characteristics were attributed to different exciton binding energies, induced by coordination geometry of the [PbBr 6 ] 4- octahedron sublattices. This work correlated the local structures of lead in the primitive perovskite and its derivatives to PL spectra as well as photoconductivity.

Technical Training: ELEC-2005: Electronics in High Energy Physics

CERN Multimedia

Monique Duval

2005-01-01

CERN Technical Training 2005: Learning for the LHC! ELEC-2005: Electronics in High Energy Physics - Spring Term ELEC-2005 is a new course series on modern electronics, given by CERN physicists and engineers within the framework of the 2005 Technical Training Programme, in an extended format of the successful ELEC-2002 course series. This comprehensive course series is designed for people who are not electronics specialists, for example physicists, engineers and technicians working at or visiting the laboratory, who use or will use electronics in their present or future activities, in particular in the context of the LHC accelerator and experiments. ELEC-2005 is composed of four Terms: the Winter Term, Introduction to electronics in HEP, already took place; the next three Terms will run throughout the year: Spring Term: Integrated circuits and VLSI technology for physics (March, 6 lectures) - now open for registration Summer Term: System electronics for physics: Issues (May, 7 lectures) Autumn Term: Ele...

Exploring Polaronic, Excitonic Structures and Luminescence in Cs4PbBr6/CsPbBr3.

Science.gov (United States)

Kang, Byungkyun; Biswas, Koushik

2018-02-15

Among the important family of halide perovskites, one particular case of all-inorganic, 0-D Cs 4 PbBr 6 and 3-D CsPbBr 3 -based nanostructures and thin films is witnessing intense activity due to ultrafast luminescence with high quantum yield. To understand their emissive behavior, we use hybrid density functional calculations to first compare the ground-state electronic structure of the two prospective compounds. The dispersive band edges of CsPbBr 3 do not support self-trapped carriers, which agrees with reports of weak exciton binding energy and high photocurrent. The larger gap 0-D material Cs 4 PbBr 6 , however, reveals polaronic and excitonic features. We show that those lattice-coupled carriers are likely responsible for observed ultraviolet emission around ∼375 nm, reported in bulk Cs 4 PbBr 6 and Cs 4 PbBr 6 /CsPbBr 3 composites. Ionization potential calculations and estimates of type-I band alignment support the notion of quantum confinement leading to fast, green emission from CsPbBr 3 nanostructures embedded in Cs 4 PbBr 6 .

Improved production of Br atoms near zero speed by photodissociating laser aligned Br2 molecules.

Science.gov (United States)

Deng, L Z; Yin, J P

2014-10-28

We theoretically investigated the improvement on the production rate of the decelerated bromine (Br) atoms near zero speed by photodissociating laser aligned Br2 precursors. Adiabatic alignment of Br2 precursors exposed to long laser pulses with duration on the order of nanoseconds was investigated by solving the time-dependent Schrödinger equation. The dynamical fragmentation of adiabatically aligned Br2 precursors was simulated and velocity distribution of the Br atoms produced was analyzed. Our study shows that the larger the degree of the precursor alignment, ⟨cos(2) θ⟩, the higher the production rate of the decelerated Br atoms near zero speed. For Br2 molecules with an initial rotational temperature of ~1 K, a ⟨cos(2) θ⟩ value of ~0.88 can result in an improvement factor of over ~20 on the production rate of the decelerated Br atoms near zero speed, requiring a laser intensity of only ~1 × 10(12) W/cm(2) for alignment.

Eole 2005; Eole 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-10-01

The Eole 2005 programme is a french development programme of wind power plants joined up to the power distribution system. It has been launched in february 1996 by the ministry of Industry. The aim is to install in France a power of 250 to 500 Mw in wind power from now until 2005. Electricite de France is implied in other kind of renewable energies: hydroelectric power, biomass, solar energy, and geothermal energy. (N.C.)

Molecular elimination of Br2 in photodissociation of CH2BrC(O)Br at 248 nm using cavity ring-down absorption spectroscopy.

Science.gov (United States)

Fan, He; Tsai, Po-Yu; Lin, King-Chuen; Lin, Cheng-Wei; Yan, Chi-Yu; Yang, Shu-Wei; Chang, A H H

2012-12-07

The primary elimination channel of bromine molecule in one-photon dissociation of CH(2)BrC(O)Br at 248 nm is investigated using cavity ring-down absorption spectroscopy. By means of spectral simulation, the ratio of nascent vibrational population in v = 0, 1, and 2 levels is evaluated to be 1:(0.5 ± 0.1):(0.2 ± 0.1), corresponding to a Boltzmann vibrational temperature of 581 ± 45 K. The quantum yield of the ground state Br(2) elimination reaction is determined to be 0.24 ± 0.08. With the aid of ab initio potential energy calculations, the obtained Br(2) fragments are anticipated to dissociate on the electronic ground state, yielding vibrationally hot Br(2) products. The temperature-dependence measurements support the proposed pathway via internal conversion. For comparison, the Br(2) yields are obtained analogously from CH(3)CHBrC(O)Br and (CH(3))(2)CBrC(O)Br to be 0.03 and 0.06, respectively. The trend of Br(2) yields among the three compounds is consistent with the branching ratio evaluation by Rice-Ramsperger-Kassel-Marcus method. However, the latter result for each molecule is smaller by an order of magnitude than the yield findings. A non-statistical pathway so-called roaming process might be an alternative to the Br(2) production, and its contribution might account for the underestimate of the branching ratio calculations.

Energy in Sweden. Facts and figures 2005

International Nuclear Information System (INIS)

2005-12-01

Energy in Sweden. Facts and Figures 2005 contains the tabular data for most of the diagrams in the main publication. These data consist primarily of the results of the Agency's processing of basic data from Statistics Sweden. Facts and Figures is available at www.stem.se in pdf- and excel file formats. With effect from the 2001 edition, statistics are of preliminary character for the two preceding years (2003 and 2004). Breakdowns into certain types of fuels vary somewhat depending on whether preliminary or final data has been used. Further information about the statistics can be found in Energy in Sweden, chapter 8 Energy Facts

2005 Status Report Savings Estimates for the ENERGY STAR(R)Voluntary Labeling Program

Energy Technology Data Exchange (ETDEWEB)

Webber, Carrie A.; Brown, Richard E.; Sanchez, Marla

2006-03-07

ENERGY STAR(R) is a voluntary labeling program designed toidentify and promote energy-efficient products, buildings and practices.Operated jointly by the Environmental Protection Agency (EPA) and theU.S. Department of Energy (DOE), Energy Star labels exist for more thanforty products, spanning office equipment, residential heating andcooling equipment, commercial and residential lighting, home electronics,and major appliances. This report presents savings estimates for a subsetof ENERGY STAR labeled products. We present estimates of the energy,dollar and carbon savings achieved by the program in the year 2004, whatwe expect in 2005, and provide savings forecasts for two marketpenetration scenarios for the periods 2005 to 2010 and 2005 to 2020. Thetarget market penetration forecast represents our best estimate of futureENERGY STAR savings. It is based on realistic market penetration goalsfor each of the products. We also provide a forecast under the assumptionof 100 percent market penetration; that is, we assume that all purchasersbuy ENERGY STAR-compliant products instead of standard efficiencyproducts throughout the analysis period.

Comparative study of α and β-ThBr4: structure and luminescence. Spectroscopy of U4+ in α-ThBr4

International Nuclear Information System (INIS)

Simoni, E.

1988-05-01

UV absorption of β-ThBr 4 : presents a plain absorption front and for the same temperature the threshold energy has the same value than the threshold energy of excitation function and photocurrent peak. Emission intensity and lifetime decrease when temperature increases from 300 K to 400K (extinction temperature). Results are interpreted either by molecular orbital levels of the ThBr 8 4- cluster or either by conduction and valence bands of the matrix above. Absorption and emission spectra of U 4+ in α-ThBr 4 (where U 4+ has a S 4 symmetry) between 300 K and 4.2 K allow indexation of 30 levels. Spectroscopic parameters are calculated in D 2d and S 4 symmetry. Comparison of these parameters with those of U 4+ in β-ThBr 4 and β-ThCl 4 shows that crystal field force is practically the same in the three matrices but the structure transformation from β to α has more influence on B q k than ligand change from Br - to Cl - . Owing to very low phonon energy, fluorescence spectra of U 4+ is easy to observe in α-ThBr 4 as it is in β-ThBr 4 and ThCl 4 [fr

Feasibility study of a highly sensitive LaBr{sub 3} PET scanner based on the DOI-dependent extended-energy window

Energy Technology Data Exchange (ETDEWEB)

Yoshida, Eiji [Naitonal Institute of Radiological Sciences, Chiba (Japan)], E-mail: rush@nirs.go.jp; Kitamura, Keishi [Shimadzu Corporation, Kyoto (Japan); Nishikido, Fumihiko; Shibuya, Kengo [Naitonal Institute of Radiological Sciences, Chiba (Japan); Hasegawa, Tomoyuki [Kitasato University, Kanagawa (Japan); Yamaya, Taiga; Inadama, Naoko; Murayama, Hideo [Naitonal Institute of Radiological Sciences, Chiba (Japan)

2009-06-01

Conventionally, positron emission tomograph (PET) scanners use scintillators which have a high effective atomic number. Recently, novel scintillators like LaBr{sub 3} have been developed which have excellent timing and energy resolutions. LaBr{sub 3} has a high performance for PET scanner use, but its effective atomic number is lower than that of lutetium oxyorthosilicate (LSO). As an alternative, we have developed a scatter reduction method using depth-of-interaction (DOI) information and energy information to increase the sensitivity. The sensitivity of the PET scanner with LaBr{sub 3} can be improved using the DOI-dependent extended-energy window (DEEW) method. In this work, our method is applied to the whole-body LSO/LaBr{sub 3} PET scanner using the GATE simulation toolkit. Simulation results show the number of true coincidences can be increased while minimizing the scatter and random coincidences by using the DEEW method. Noise equivalent count rate (NECR) can be improved by 20-70% for the whole-body DOI-PET scanner. Sensitivity of the PET scanner with a scintillator of low-effective atomic number can be improved by the DEEW method.

CRM1-mediated nuclear export is required for 26 S proteasome-dependent degradation of the TRIP-Br2 proto-oncoprotein.

Science.gov (United States)

Cheong, Jit Kong; Gunaratnam, Lakshman; Hsu, Stephen I-Hong

2008-04-25

Overexpression of the proto-oncogene TRIP-Br2 (SERTAD2) has been shown to induce E2F activity and promote tumorigenesis, whereas ablation of TRIP-Br2 arrests cell proliferation. Timely degradation of many cell cycle regulators is fundamental to the maintenance of proper cell cycle progression. Here we report novel mechanism(s) that govern the tight regulation of TRIP-Br2 levels during cell cycle progression. TRIP-Br2 was observed to be a short-lived protein in which the expression level peaks at the G(1)/S boundary. TRIP-Br2 accumulated in cells treated with 26 S proteasome inhibitors. Co-immunoprecipitation studies revealed that TRIP-Br2 forms ubiquitin conjugates. In silico analysis identified a putative leucine-rich nuclear export signal (NES) motif that overlaps with the PHD-Bromo interaction domain in the acidic C-terminal transactivation domain (TAD) of TRIP-Br2. This NES motif is highly conserved in widely divergent species and in all TRIP-Br family members. TRIP-Br2 was shown to be stabilized in G(2)/M phase cells through nuclear entrapment, either by deletion of the acidic C-terminal TAD, which includes the NES motif, or by leptomycin B-mediated inhibition of the CRM1-dependent nuclear export machinery. Mutation of leucine residue 238 of this NES motif abolished the interaction between CRM1 and TRIP-Br2, as well as the nuclear export of TRIP-Br2 and its subsequent 26 S proteasome-dependent degradation. These data suggest that CRM1-mediated nuclear export may be required for the proper execution of ubiquitin-proteasome-dependent degradation of TRIP-Br2.

Quantum dynamics of Ne-Br2 vibrational predissociation: the role of continuum resonances as doorway states.

Science.gov (United States)

García-Vela, A; Janda, K C

2006-01-21

Wave-packet simulations of the Ne-Br2(B,upsilon') vibrational predissociation dynamics in the range upsilon' = 16-29 are reported. The aim is to interpret recent time-dependent pump-probe experiments [Cabrera et al., J. Chem. Phys. 123, 054311 (2005)]. Good agreement is found between the calculated and the experimental lifetimes corresponding to decay of the Ne-Br2(B,upsilon') initial state and to appearance of Br2(B,upsilonBr2(B,upsilonBr2(B,upsilonBr2 distances greater than 15 angstroms. In the light of the results, a structure of the spectrum of continuum resonances is suggested and discussed.

The thermal analysis of BR-100: A barge/rail nuclear spent fuel transportation container

International Nuclear Information System (INIS)

Copsey, A.B.

1992-01-01

B ampersand W Fuel Company is designing a spent-fuel container called BR-100 that can be used for either barge or rail transport. This paper presents the thermal design and analysis. Both normal operation and hypothetical accident thermal transient conditions are evaluated. The BR-100 cask has a concrete layer than contains free water. During a hypothetical accident, the free water vaporizes and flows from the cask, removing a significant amount of thermal transient energy. The BR-100 transportation package meets the thermal requirements of 10CFR71. It additionally offers substantial margins to established material temperature limits

Proceedings of the 6. 2005 energy meetings

International Nuclear Information System (INIS)

2005-02-01

The energy meetings is the biggest annual event for French local communities in the energy domain. The public is mainly composed of officials, representatives from local communities, institutions, private organisations and associations. The aim of the meetings is to debate and exchange on the actions to be implemented at the regional scale by Territorial authorities in order to meet the climate and energy challenges of the century. Consuming less and better, improving buildings energy efficiency, purchasing energy, clean vehicles and energy services, setting an example to provide credible support to the territorial action, financing actions using market mechanisms (energy saving certificates), producing locally to limit the use of exogenous resources have been the main topics approached during these meetings. This 2005 edition is organised around 2 plenary sessions and 12 workshops. These proceedings brings together the available material: a detailed programme, a synthesis of the meetings, and the presentations (slides) given during the workshops with their abstracts

Performance evaluation of LaBr3: Ce scintillator

International Nuclear Information System (INIS)

Xie Ming; Lin Li; Liu Shihao; Xiao Peng; Xie Qingguo

2012-01-01

The cerium doped lanthanum bromide crystal (LaBr 3 : Ce) is a new kind of scintillator with many advantages such as good energy resolution, high light output, short decay time, good proportionality response. These properties make the LaBr 3 : Ce attractive substantial interest to use in the radiation detection. The energy resolution were investigated with Φ25 × 25 mm LaBr 3 : Ce coupled to a Hamamatsu R8900 photomultiplier tube. Energy resolution of 3.6% (FWHM) have been achieved for 511 keV photons ( 18 F source) at room temperature. Decay time constant of 20 ns have been acquired with a Hamamatsu fast-time-response R9800 photomultiplier tube. The results approve the excellent characterizations of LaBr 3 : Ce and imply its enormous potentiality in the radiation detectors of gamma-ray spectroscopy and PET. (authors)

Hybridization of Single Nanocrystals of Cs4PbBr6 and CsPbBr3.

Science.gov (United States)

Weerd, Chris de; Lin, Junhao; Gomez, Leyre; Fujiwara, Yasufumi; Suenaga, Kazutomo; Gregorkiewicz, Tom

2017-09-07

Nanocrystals of all-inorganic cesium lead halide perovskites (CsPbX 3 , X = Cl, Br, I) feature high absorption and efficient narrow-band emission which renders them promising for future generation of photovoltaic and optoelectronic devices. Colloidal ensembles of these nanocrystals can be conveniently prepared by chemical synthesis. However, in the case of CsPbBr 3 , its synthesis can also yield nanocrystals of Cs 4 PbBr 6 and the properties of the two are easily confused. Here, we investigate in detail the optical characteristics of simultaneously synthesized green-emitting CsPbBr 3 and insulating Cs 4 PbBr 6 nanocrystals. We demonstrate that, in this case, the two materials inevitably hybridize, forming nanoparticles with a spherical shape. The actual amount of these Cs 4 PbBr 6 nanocrystals and nanohybrids increases for synthesis at lower temperatures, i.e., the condition typically used for the development of perovskite CsPbBr 3 nanocrystals with smaller sizes. We use state-of-the-art electron energy loss spectroscopy to characterize nanoparticles at the single object level. This method allows distinguishing between optical characteristics of a pure Cs 4 PbBr 6 and CsPbBr 3 nanocrystal and their nanohybrid. In this way, we resolve some of the recent misconceptions concerning possible visible absorption and emission of Cs 4 PbBr 6 . Our method provides detailed structural characterization, and combined with modeling, we conclusively identify the nanospheres as CsPbBr 3 /Cs 4 PbBr 6 hybrids. We show that the two phases are independent of each other's presence and merge symbiotically. Herein, the optical characteristics of the parent materials are preserved, allowing for an increased absorption in the UV due to Cs 4 PbBr 6 , accompanied by the distinctive efficient green emission resulting from CsPbBr 3 .

Annual report 2005 General Direction of the Energy and raw materials; Rapport annuel 2005 Direction Generale de L'Energie et des Matieres Premieres

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-07-01

This 2005 annual report of the DGEMP (General Direction of the Energy and the raw Materials), takes stock on the energy bill and accounting of the France. The first part presents the electric power, natural gas and raw materials market in France. The second part is devoted to the diversification of the energy resources with a special attention to the renewable energies and the nuclear energy. The third part discusses the energy and raw materials prices and the last part presents the international cooperation in the energy domain. (A.L.B.)

Technical Training: ELEC-2005 - Electronics in High Energy Physics: Summer Term (May 2005)

CERN Multimedia

Davide Vitè

2005-01-01

ELEC-2005 is a new course series on modern electronics, given by CERN physicists and engineers within the framework of the 2005 Technical Training Programme. It is designed for people who are not electronics specialists, for example physicists, engineers and technicians working at or visiting the laboratory, who use or will use electronics in their present or future activities, in particular in the context of the LHC accelerator and experiments. The next ELEC-2005 Summer Term, System electronics for physics: Issues, is now open for online registration, and will start on May 10th. Lectures will take place on Tuesdays and Thursdays, from 10h00 to 12h30. The course will be in English, with questions and answers also possible in French. Separate registration to each Term is required: attendance costs will be of 10.- CHF per lecture (Summer Term: 70.- CHF). If you are interested in attending, please discuss with your supervisor and/or your DTO, and apply electronically via EDH. Participation to all sessions in a...

Formation of positive cluster ions Li(n) Br (n = 2-7) and ionization energies studied by thermal ionization mass spectrometry.

Science.gov (United States)

Veličković, S R; Đustebek, J B; Veljković, F M; Veljković, M V

2012-05-01

Clusters of the type Li(n)X (X = halides) can be considered as potential building blocks of cluster-assembly materials. In this work, Li(n)Br (n = 2-7) clusters were obtained by a thermal ionization source of modified design and selected by a magnetic sector mass spectrometer. Positive ions of the Li(n)Br (n = 4-7) cluster were detected for the first time. The order of ion intensities was Li(2)Br(+) > Li(4)Br(+) > Li(5)Br(+) > Li(6)Br(+) > Li(3)Br(+). The ionization energies (IEs) were measured and found to be 3.95 ± 0.20 eV for Li(2)Br, 3.92 ± 0.20 eV for Li(3)Br, 3.93 ± 0.20 eV for Li(4)Br, 4.08 ± 0.20 eV for Li(5)Br, 4.14 ± 0.20 eV for Li(6)Br and 4.19 ± 0.20 eV for Li(7)Br. All of these clusters have a much lower ionization potential than that of the lithium atom, so they belong to the superalkali class. The IEs of Li(n)Br (n = 2-4) are slightly lower than those in the corresponding small Li(n) or Li(n)H clusters, whereas the IEs of Li(n)Br are very similar to those of Li(n) or Li(n)H for n = 5 and 6. The thermal ionization source of modified design is an important means for simultaneously obtaining and measuring the IEs of Li(n)Br (n = 2-7) clusters (because their ions are hermodynamically stable with respect to the loss of lithium atoms in the gas phase) and increasingly contributes toward the development of clusters for practical applications. Copyright © 2012 John Wiley & Sons, Ltd.

High Defect Tolerance in Lead Halide Perovskite CsPbBr3.

Science.gov (United States)

Kang, Jun; Wang, Lin-Wang

2017-01-19

The formation energies and charge-transition levels of intrinsic point defects in lead halide perovskite CsPbBr 3 are studied from first-principles calculations. It is shown that the formation energy of dominant defect under Br-rich growth condition is much lower than that under moderate or Br-poor conditions. Thus avoiding the Br-rich condition can help to reduce the defect concentration. Interestingly, CsPbBr 3 is found to be highly defect-tolerant in terms of its electronic structure. Most of the intrinsic defects induce shallow transition levels. Only a few defects with high formation energies can create deep transition levels. Therefore, CsPbBr 3 can maintain its good electronic quality despite the presence of defects. Such defect tolerance feature can be attributed to the lacking of bonding-antibonding interaction between the conduction bands and valence bands.

Cost-optimal levels of minimum energy performance requirements in the Danish Building Regulations

Energy Technology Data Exchange (ETDEWEB)

Aggerholm, S.

2013-09-15

The purpose of the report is to analyse the cost optimality of the energy requirements in the Danish Building Regulations 2010, BR10 to new building and to existing buildings undergoing major renovation. The energy requirements in the Danish Building Regulations have by tradition always been based on the cost and benefits related to the private economical or financial perspective. Macro economical calculations have in the past only been made in addition. The cost optimum used in this report is thus based on the financial perspective. Due to the high energy taxes in Denmark there is a significant difference between the consumer price and the macro economical for energy. Energy taxes are also paid by commercial consumers when the energy is used for building operation e.g. heating, lighting, ventilation etc. In relation to the new housing examples the present minimum energy requirements in BR 10 all shows gaps that are negative with a deviation of up till 16 % from the point of cost optimality. With the planned tightening of the requirements to new houses in 2015 and in 2020, the energy requirements can be expected to be tighter than the cost optimal point, if the costs for the needed improvements don't decrease correspondingly. In relation to the new office building there is a gap of 31 % to the point of cost optimality in relation to the 2010 requirement. In relation to the 2015 and 2020 requirements there are negative gaps to the point of cost optimality based on today's prices. If the gaps for all the new buildings are weighted to an average based on mix of building types and heat supply for new buildings in Denmark there is a gap of 3 % in average for the new building. The excessive tightness with today's prices is 34 % in relation to the 2015 requirement and 49 % in relation to the 2020 requirement. The component requirement to elements in the building envelope and to installations in existing buildings adds up to significant energy efficiency

CaBr2 hydrolysis for HBr production using a direct sparging contactor

International Nuclear Information System (INIS)

Doctor, R.D.; Yang, J.; Panchal, Ch.B.; Lottes, St.A.; Lyczkowski, R.W.

2010-01-01

We investigated a novel, continuous hybrid cycle for hydrogen production employing both heat and electricity. Calcium bromide (CaBr 2 ) hydrolysis, which is endothermic, generates hydrogen bromide (HBr), and this is electrolysed to produce hydrogen. CaBr 2 hydrolysis at 1050 K is endothermic with a 181.5 KJ/mol heat of reaction and the free energy change is positive at 99.6 kJ/mol. What makes this hydrolysis reaction attractive is both its rate and the fact that well over half the thermodynamic requirements for water-splitting free energy of ΔG T = 285.8 KJ/mol are supplied at this stage using heat rather than electricity. These experiments provide support for a second order hydrolysis reaction in CaBr 2 forming a complex involving CaBr 2 and CaO and the system appears to be: 3CaBr 2 + H 2 O → (CaBr 2 ) 2 .CaO + 2HBr. This reaction is highly endothermic and the complex also includes some water of hydration. COMSOL TM multi-physics modelling of sparging steam into a calcium bromide melt guided the design of an experiment using a mullite tube (ID 70 mm) capable of holding 0.3-0.5 kg (1.5-2.5 10 -3 kmol) CaBr 2 forming a melt with a maximum 0.08 m depth. Half of the experiments employed packings. Sparging steam at a steam rate of 0.02-0.04 mol/mol of CaBr 2 per minute into this molten bath promptly yielded HBr in a stable operation that converted up to 19 mol% of the calcium bromide. The kinetic constant derived from the experimental data was kinetic constant was 2.17 10 -12 kmol s -1 m -2 MPa -1 for the hydrolysis reaction. (authors)

Structure and luminescence of α and β ThBr4: optical properties of U4+ in α ThBr4

International Nuclear Information System (INIS)

Simoni, E.

1988-05-01

The aim of this work is to understand the comparative structural and intrinsic luminescence properties of the pure matrices α and β - ThBr 4 , and to study the electronic structure by optical spectroscopy of the U 4+ ion in the α-ThBr 4 matrix. 1)Under U.V. excitation, βThBr 4 is intensively fluorescent in the blue-purple and α-ThBr 4 is fluorescent in the red. The main results concerning β-ThBr 4 are the following: -the optical absorption in the U.V. is under the form of a sudden absorption front and for a same temperature, its threshold energy has the same value as the threshold energy of the excitation function and of the photocurrent peak; -the intensity and the life time of the emission decrease when the temperature increases from 300 K until 400 K ( extinction temperature). All the obtained results have been explained either with the molecular orbitals levels of the ThBr 8 4- cluster or with the valence and conduction bands of the pure matrix. 2)The absorption and emission spectra of U 4+ in α-ThBr 4 (in which U 4+ has a point symmetry S 4 ) obtained between 300 K and 4.2 K have allowed to index 30 levels. The calculation of the spectroscopic parameters F k , ξ and B k q has been carried out in symmetry D 2d and S 4 . The comparison of these parameters with those calculated for U 4+ in β-ThBr 4 and β-ThCl 4 show that the global force of the crystalline field is practically the same in the three matrices, but that the structure transformation β→α occurs more on the values of these B k q than on the change of the ligands Br - →Cl - . On the other hand, it has been possible with the α-ThBr 4 matrix, or the β-ThBr 4 and the β-ThCl 4 , to observe the fluorescence spectra of the U 4+ ion (particularly weak phonons energies). (O.M.)

Projected Benefits of Federal Energy Efficiency and Renewable Energy Programs: FY 2005 Budget Request

Energy Technology Data Exchange (ETDEWEB)

National Renewable Energy Laboratory

2004-05-01

The Office of Energy Efficiency and Renewable Energy (EERE) of the U.S. Department of Energy (DOE) leads the Federal Government's efforts to provide reliable, affordable, and environmentally sound energy for America, through its 11 research, development, demonstration, and deployment (RDD&D) programs. EERE invests in high-risk, high-value research and development (R&D) that, conducted in partnership with the private sector and other government agencies, accelerates the development and facilitates the deployment of advanced clean energy technologies and practices. This document summarizes the results of the benefits analysis of EERE's programs, as described in the FY 2005 Budget Request. EERE has adopted a benefits framework developed by the National Research Council (NRC) to represent the various types of benefits resulting from the energy efficiency technology improvements and renewable energy technology development prompted by EERE programs. EERE's benefits analysis focuses on three main categories of energy-linked benefits-economic, environmental, and security. These metrics are not a complete representation of the benefits or market roles of efficiency and renewable technologies, but provide an indication of the range of benefits provided. EERE has taken steps to more fully represent the NRC framework, including two key improvements to the FY 2005 analysis-adding an electricity security metric and extending the analysis through the year 2050.

Energy resolution measurements of LaBr3:Ce scintillating crystals with an ultra-high quantum efficiency photomultiplier tube

International Nuclear Information System (INIS)

Pani, R.; Cinti, M.N.; Scafe, R.; Pellegrini, R.; Vittorini, F.; Bennati, P.; Ridolfi, S.; Lo Meo, S.; Mattioli, M.; Baldazzi, G.; Pisacane, F.; Navarria, F.; Moschini, G.; Boccaccio, P.; Orsolini Cencelli, V.; Sacco, D.

2009-01-01

The performance of the new prototype of high quantum efficiency PMT (43% at 380 nm), Hamamatsu R7600U-200, was studied coupled to a LaBr 3 :Ce crystal with the size of o12.5 mmx12.5 mm. The energy resolution results were compared with ones from two PMTs, Hamamatsu R7600U and R6231MOD, with 22% and 30% quantum efficiency (QE), respectively. Moreover, the photodetectors were equipped with tapered and un-tapered voltage dividers to study the non-linearity effects on pulse height distribution, due to very high peak currents induced in the PMT by the fast and intense light pulse of LaBr 3 :Ce. The results show an energy resolution improvement with UBA PMT of about 20%, in the energy range of 80-662 keV, with respect to the BA one.

The European Activation File, EAF-2005

International Nuclear Information System (INIS)

Forrest, R.A.

2005-01-01

The current version of the European Activation File is EAF-2003. This contains various libraries of nuclear data required for activation calculations. An important component is the neutron-induced cross-section library. Plans to expose fusion components to high neutron fluxes include the IFMIF materials testing facility. This accelerator-based device will produce neutrons with a high-energy tail up to about 55 MeV. In order to carry out activation calculations on materials exposed to such neutrons it is necessary to extend the energy range of the cross-section library. Work on extending the energy range to 60 MeV is nearing completion. A test version (EAF-2004) was produced at the end of 2003 showing the feasibility of the chosen approach. This library required calculated data to extend the existing data from 20-60 MeV and to enlarge it with new classes of reactions with high thresholds. A summary of the new library EAF-2005, which is under development and is planned for distribution at the beginning of 2005, is given. The other files in EAF-2005 are briefly described; these cover cross-section uncertainty information and decay data. Both these have been extended beyond the current version to allow activation calculations at energies up to 60 MeV

Caspian energy phase II: Beyond 2005

International Nuclear Information System (INIS)

Shaffer, Brenda

2010-01-01

This article examines the major factors that will shape the second phase of Caspian oil and natural gas export. The article compares the prospects of the post-2005 period with the Caspian energy developments in the first decade and a half after independence. This article claims: One, political considerations will continue to play an important role in the decisions on export routes for and participants in Caspian energy production and export projects. However, those political considerations will produce different policies in phase two of Caspian energy production than they did in the first phase. Second, the relative influence and interest in the Caspian region of various global and regional powers have changed significantly from Caspian energy phase one to phase two. Third, the producers in the region are not as anxious for foreign investment as they were earlier. The major resources that will be developed in Caspian phase two are: new production of Azerbaijan's natural gas, extension to new markets and expansion of capacity of existing gas export routes; new production projects for Turkmenistan's natural gas and new pipelines; and additional Kazakhstani oil production and natural gas increased production and initiation of export.

Validation of a novel protocol for calculating estimated energy requirements and average daily physical activity ratio for the US population: 2005-2006.

Science.gov (United States)

Archer, Edward; Hand, Gregory A; Hébert, James R; Lau, Erica Y; Wang, Xuewen; Shook, Robin P; Fayad, Raja; Lavie, Carl J; Blair, Steven N

2013-12-01

To validate the PAR protocol, a novel method for calculating population-level estimated energy requirements (EERs) and average physical activity ratio (APAR), in a nationally representative sample of US adults. Estimates of EER and APAR values were calculated via a factorial equation from a nationally representative sample of 2597 adults aged 20 and 74 years (US National Health and Nutrition Examination Survey; data collected between January 1, 2005, and December 31, 2006). Validation of the PAR protocol-derived EER (EER(PAR)) values was performed via comparison with values from the Institute of Medicine EER equations (EER(IOM)). The correlation between EER(PAR) and EER(IOM) was high (0.98; Pmen to 148 kcal/d (5.7% higher) in obese women. The 2005-2006 EERs for the US population were 2940 kcal/d for men and 2275 kcal/d for women and ranged from 3230 kcal/d in obese (BMI ≥30) men to 2026 kcal/d in normal weight (BMI women. There were significant inverse relationships between APAR and both obesity and age. For men and women, the APAR values were 1.53 and 1.52, respectively. Obese men and women had lower APAR values than normal weight individuals (P¼.023 and P¼.015, respectively) [corrected], and younger individuals had higher APAR values than older individuals (Pphysical activity and health. Copyright © 2013 Mayo Foundation for Medical Education and Research. Published by Elsevier Inc. All rights reserved.

Theoretical study and rate constant calculation for the reactions of SH (SD) with Cl2, Br2, and BrCl.

Science.gov (United States)

Wang, Li; Liu, Jing-Yao; Li, Ze-Sheng; Sun, Chia-Chung

2005-01-30

The mechanisms of the SH (SD) radicals with Cl2 (R1), Br2 (R2), and BrCl (R3) are investigated theoretically, and the rate constants are calculated using a dual-level direct dynamics method. The optimized geometries and frequencies of the stationary points are calculated at the MP2/6-311G(d,p) and MPW1K/6-311G(d,p) levels. Higher-level energies are obtained at the approximate QCISD(T)/6-311++G(3df, 2pd) level using the MP2 geometries as well as by the multicoefficient correlation method based on QCISD (MC-QCISD) using the MPW1K geometries. Complexes with energies less than those of the reactants or products are located at the entrance or the exit channels of these reactions, which indicate that the reactions may proceed via an indirect mechanism. The enthalpies of formation for the species XSH/XSD (X = Cl and Br) are evaluated using hydrogenation working reactions method. By canonical variational transition-state theory (CVT), the rate constants of SH and SD radicals with Cl2, Br2, and BrCl are calculated over a wide temperature range of 200-2000 K at the a-QCISD(T)/6-311++G(3df, 2pd)//MP2/6-311G(d, p) level. Good agreement between the calculated and experimental rate constants is obtained in the measured temperature range. Our calculations show that for SH (SD) + BrCl reaction bromine abstraction (R3a or R3a') leading to the formation of BrSH (BrSD) + Cl in a barrierless process dominants the reaction with the branching ratios for channels 3a and 3a' of 99% at 298 K, which is quite different from the experimental result of k3a'/k3' = 54 +/- 10%. Negative activation energies are found at the higher level for the SH + Br2 and SH + BrCl (Br-abstraction) reactions; as a result, the rate constants show a slightly negative temperature dependence, which is consistent with the determination in the literature. The kinetic isotope effects for the three reactions are "inverse". The values of kH/kD are 0.88, 0.91, and 0.69 at room temperature, respectively, and they increase

Annual Energy Review 2005

Energy Technology Data Exchange (ETDEWEB)

Seiferlein, Katherine E. [USDOE Energy Information Administration (EIA), Washington, DC (United States)

2006-07-01

The Annual Energy Review (AER) is the Energy Information Administration's (EIA) primary report of annual historical energy statistics. For many series, data begin with the year 1949. Included are data on total energy production, consumption, and trade; overviews of petroleum, natural gas, coal, electricity, nuclear energy, renewable energy, international energy, as well as financial and environment indicators; and data unit conversion tables. Publication of this report is required under Public Law 95–91 (Department of Energy Organization Act), Section 205(c), and is in keeping with responsibilities given to the EIA under Section 205(a)(2), which states: “The Administrator shall be responsible for carrying out a central, comprehensive, and unified energy data and information program which will collect, evaluate, assemble, analyze, and disseminate data and information....” The AER is intended for use by Members of Congress, Federal and State agencies, energy analysts, and the general public. EIA welcomes suggestions from readers regarding data series in the AER and in other EIA publications.

Swiss electricity statistics 2005; Schweizerische Elektrizitaetsstatistik 2005/Statistique suisse de l'electricite 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-07-01

This comprehensive report made by the Swiss Federal Office of Energy (SFOE) presents the statistics for 2005 on electricity production and usage in Switzerland for the year 2005. First of all, an overview of Switzerland's electricity supply in 2005 is presented. Details are noted of the proportions generated by different sources including nuclear, hydro-power, storage schemes and thermal power stations as well as energy transfer with neighbouring countries. A second chapter takes a look at the balance of imports and exports with illustrative flow diagrams along with tables for total figures from 1950 through to 2005. For the summer and winter periods, figures from 1995 to 2005 are presented. The third chapter examines the production of electricity in the various types of power stations and the developments over the years 1950 to 2005, whereby, for example, statistics on regional generation and power station type are looked at. The fourth chapter looks at electricity consumption in various sectors from 1983 to 2005 and compares the figures with international data. The fifth chapter looks at generation, consumption and loading on particular days and chapter six considers energy exchange with Switzerland's neighbours. Chapter seven takes a look at possibilities for extending generation facilities in the period up to 2012.

Operation of the BR2 Reactor

International Nuclear Information System (INIS)

Gubel, P.

2006-01-01

The BR2 is still SCK-CEN's most important nuclear facility. After an extensive refurbishment of 22 months to compensate for the ageing of the installations, to enhance the reliability of operation and to comply with modern safety standards, it was restarted in April 1997. The facility is mainly used for the irradiation and testing of fuels and materials and for commercial productions - including radioisotopes for the medical and industrial uses, and NTD-Silicon. The article describes the main achievements and activities in 2005

Electricity production from wind energy: world situation and the French program EOLE 2005; Production d'electricite par energie eolienne: situation dans le monde et programme francais EOLE 2005

Energy Technology Data Exchange (ETDEWEB)

Electricite de France [ed.] [Electricite de France (EDF), 75 - Paris (France)

2000-06-07

The wind electricity world market shows at present an important development stage characterized by an annual increase rate of 20% to 30%. The total installed power in the world reached the value 7,200 MW in November 1997 and, according to forecasts, it could increase fivefold up to 2005. For France's high wind potential sites, namely the DOM-TOM and in Corsica, where the electricity production is more expensive than in inland France, this energy production mode approaches the threshold of competitiveness with other production means. The program EOLE 2005 (targeting 250 to 500 MW from wind turbines to be installed in France until 2005), launched in 1996 by EDF in collaboration with ADEME, on request of public authorities, is thought to implement this demand. The sections of the report are titled as following: - An energy used by man from long time ago; - Momentous developments of the wind power technology since eighties; - From wind turbines of some hundreds kW to 3 MW, based on robust technologies and newly devised methods; - Wind energy becomes equally interesting from economic viewpoint but for which applications?; - This option presents some drawbacks; - Which is the wind potential economically acceptable if the mentioned constraints are taken into account?; - The wind generators will be installed on sea near seashores; - An outstanding change in this field in France since 1996: the programme EOLE 2005; - 35 selected projects of 125,3 MW total power; - Future. The electricity production from wind energy seems promising particularly for the countries that have not resorted to either nuclear energy or hydropower options and which possess important wind resources.

Lattice potential energy and standard molar enthalpy in the formation of 1-dodecylamine hydrobromide(1-C12H25NH3·Br)(s)

Institute of Scientific and Technical Information of China (English)

Liu Yu-Pu; Di You-Ying; Dan Wen-Yan; He Dong-Hua; Kong Yu-Xia; Yang Wei-Wei

2011-01-01

This paper reports that 1-dodecylamine hydrobromide (1-C12H25NH3·Br)(s) has been synthesized using the liquid phase reaction method. The lattice potential energy of the compound 1-C12H25NH3·Br and the ionic volume and radius of the 1-C12H25NH3+ cation are obtained from the crystallographic data and other auxiliary ther-modynamic data. The constant-volume energy of combustion of 1-C12H25NH3·Br(s) is measured to be △cUm°(1-C12H25NH3·Br, s) =-(7369.03±3.28) kJ·mol-1 by means of an RBC-Ⅱ precision rotating-bomb combustion calorimeter at T=(298.15±0.001) K. The standard molar enthalpy of combustion of the compound is derived to be △cHm°(1-C12H25NH3·Br, s)=-(7384.52±3.28) kJ·mol-1 from the constant-volume energy of combustion. The standard molar enthalpy of formation of the compound is calculated to be △fHm°(1-C12H25NH3·Br, s)=-(1317.86±3.67) kJ·mol-1 from the standard molar enthalpy of combustion of the title compound and other auxiliary thermodynamic quantities through a thermochemical cycle.

Tunable CsPbBr3/Cs4PbBr6 phase transformation and their optical spectroscopic properties.

Science.gov (United States)

Chen, Xiao; Chen, Daqin; Li, Junni; Fang, Gaoliang; Sheng, Hongchao; Zhong, Jiasong

2018-04-24

As a novel type of promising materials, metal halide perovskites are a rising star in the field of optoelectronics. On this basis, a new frontier of zero-dimensional perovskite-related Cs4PbBr6 with bright green emission and high stability has attracted an enormous amount of attention, even though its photoluminescence still requires to clarification. Herein, the controllable phase transformation between three-dimensional CsPbBr3 and zero-dimensional Cs4PbBr6 is easily achieved in a facile ligand-assisted supersaturated recrystallization synthesis procedure via tuning the amount of surfactants, and their unique optical properties are investigated and compared in detail. Both Cs4PbBr6 and CsPbBr3 produce remarkably intense green luminescence with quantum yields up to 45% and 80%, respectively; however, significantly different emitting behaviors are observed. The fluorescence lifetime of Cs4PbBr6 is much longer than that of CsPbBr3, and photo-blinking is easily detected in the Cs4PbBr6 product, proving that the zero-dimensional Cs4PbBr6 is indeed a highly luminescent perovskite-related material. Additionally, for the first time, tunable emissions over the visible-light spectral region are demonstrated to be achievable via halogen composition modulations in the Cs4PbX6 (X = Cl, Br, I) samples. Our study brings a simple method for the phase control of CsPbBr3/Cs4PbBr6 and demonstrates the intrinsic luminescence nature of the zero-dimensional perovskite-related Cs4PbX6 products.

Sharing our energies. Corporate social responsibility report 2005

International Nuclear Information System (INIS)

2006-05-01

Total is a multinational energy company, the fourth largest publicly-traded integrated oil and gas company in the world. Total worldwide operations are conducted through three business segments: Upstream includes oil and gas Exploration and Production, Gas and Power and other energy sources. Downstream covers Trading and Shipping,Refining and the Marketing of TOTAL and Elf brand petroleum products, automotive and other fuels, and specialties such as LPG, aviation fuel and lubricants, through both the retail network and other outlets worldwide. Chemicals comprises various activities including Base chemicals (Petrochemicals and Fertilizers) and Specialties for industry and the consumer market. This corporate social responsibility report presents the Group activity for the year 2005 in the following domains: the business principles, the environment safety and health, the social responsibility and the local development, the future of energy (fossil fuels, renewable energies and towards energy vectors). (A.L.B.)

Bromine-rich Zinc Bromides: Zn6Br12(18-crown-6)2×(Br2)5, Zn4Br8(18-crown-6)2×(Br2)3, and Zn6Br12(18-crown-6)2×(Br2)2.

Science.gov (United States)

Hausmann, David; Feldmann, Claus

2016-06-20

The bromine-rich zinc bromides Zn6Br12(18-crown-6)2×(Br2)5 (1), Zn4Br8(18-crown-6)2×(Br2)3 (2), and Zn6Br12(18-crown-6)2×(Br2)2 (3) are prepared by reaction of ZnBr2, 18-crown-6, and elemental bromine in the ionic liquid [MeBu3N][N(Tf)2] (N(Tf)2 = bis(trifluoromethylsulfonyl)amide). Zn6Br12(18-crown-6)2×(Br2)5 (1) is formed instantaneously by the reaction. Even at room temperature, compound 1 releases bromine, which was confirmed by thermogravimetry (TG) and mass spectrometry (MS). The release of Br2 can also be directly followed by the color and density of the title compounds. With controlled conditions (2 weeks, 25 °C, absence of excess Br2) Zn6Br12(18-crown-6)2×(Br2)5 (1) slowly releases bromine with conconcurrent generation of Zn4Br8(18-crown-6)2×(Br2)3 (2) (in ionic liquid) and Zn6Br12(18-crown-6)2×(Br2)2 (3) (in inert oil). All bromine-rich zinc bromides contain voluminous uncharged (e.g., Zn3Br6(18-crown-6), Zn2Br4(18-crown-6)) or ionic (e.g., [Zn2Br3(18-crown-6)](+), [(Zn2Br6)×(Br2)2](2-)) building units with dibromine molecules between the Zn oligomers and partially interconnecting the Zn-containing building units. Due to the structural similarity, the bromine release is possible via crystal-to-crystal transformation with retention of the crystal shape.

Annual report 2005 General Direction of the Energy and raw materials

International Nuclear Information System (INIS)

2005-01-01

This 2005 annual report of the DGEMP (General Direction of the Energy and the raw Materials), takes stock on the energy bill and accounting of the France. The first part presents the electric power, natural gas and raw materials market in France. The second part is devoted to the diversification of the energy resources with a special attention to the renewable energies and the nuclear energy. The third part discusses the energy and raw materials prices and the last part presents the international cooperation in the energy domain. (A.L.B.)

Development of source-less efficiency calibration procedure for CeBr3 based gamma spectrometry system

International Nuclear Information System (INIS)

Verma, Amit K.; Narayani, K.; Pant, Amar D.; Bhosale, Nitin; Anilkumar, S.; Palani Selvam, T.

2018-01-01

Scintillation spectrometers are widely used in detection and spectrometry of gamma photons. Sodium Iodide (NaI(Tl)) is the most commonly used scintillation detector for gamma ray spectrometry. However for portable application that require higher efficiency and better resolution Cerium Bromide (CeBr 3 ) crystals are more suitable than NaI(Tl) crystals. CeBr 3 detectors have high light output (∼ 68,000 photons/MeV), good proportionality, fast response and better energy resolution (<4% for 662 keV of 137 Cs), which makes it very promising detector for gamma ray spectrometry. In the present work, experimental and Monte Carlo based efficiencies for CeBr 3 detector for 137 Cs and 60 Co were evaluated

Photodissociation of dibromoethanes at 248 nm: an ignored channel of Br2 elimination.

Science.gov (United States)

Lee, Hsin-Lung; Lee, Ping-Chen; Tsai, Po-Yu; Lin, King-Chuen; Kuo, H H; Chen, P H; Chang, A H H

2009-05-14

Br(2) molecular elimination is probed in the photodissociation of 1,1- and 1,2-C(2)H(4)Br(2) isomeric forms at 248 nm by using cavity ring-down absorption spectroscopy. Their photodissociation processes differ markedly from each other. The quantum yield of the Br(2) fragment in 1,2-dibromoethane is 0.36+/-0.18, in contrast to a value of 0.05+/-0.03 in 1,1-dibromoethane. The vibrational population ratios of Br(2)(v=1)/Br(2)(v=0) are 0.8+/-0.1 and 0.5+/-0.2 for 1,2- and 1,1-dibromoethanes, respectively. The Br(2) yield densities are found to increase by a factor of 35% and 190% for 1,2- and 1,1-dibromoethanes within the same temperature increment. In the ab initio potential energy calculations, the transition state (TS) along the adiabatic ground state surface may correlate to the Br(2) products. The TS energy for 1,2-dibromoethane is well below the excitation energy at 483 kJ/mol, whereas that for 1,1-dibromoethane is slightly above. Such a small TS energy barrier impedes the photodissociation of the ground state 1,1-dibromoethane such that the production yield of Br(2) may become relatively low, but rise rapidly with the temperature. The TS structure shows a larger bond distance of Br-Br in 1,2-dibromoethane than that in 1,1-dibromoethane. That explains why the former isomer may result in hotter vibrational population of the Br(2) fragments.

Energy year 2005 - how is the energy balance in Rogaland and what are the implications?

International Nuclear Information System (INIS)

2006-01-01

The topic of the lunch meeting is the current and future energy balance in the county of Rogaland, Norway. The question of how to meet the future's increased energy demand is treated. An assessment of the energy situation in the years 2005-2015 is made. Regional projects are presented in the forms of coal fired power station, gasworks and wind power projects. The presented projects are Haugaland Kraft's coal-fired power station, Naturkraft's gas fired power plant and Norsk Vind Energi's wind turbine plants (ml)

Meeting the International Health Regulations (2005) surveillance core capacity requirements at the subnational level in Europe

DEFF Research Database (Denmark)

Ziemann, Alexandra; Rosenkötter, Nicole; Riesgo, Luis Garcia-Castrillo

2015-01-01

BACKGROUND: The revised World Health Organization's International Health Regulations (2005) request a timely and all-hazard approach towards surveillance, especially at the subnational level. We discuss three questions of syndromic surveillance application in the European context for assessing...... public health emergencies of international concern: (i) can syndromic surveillance support countries, especially the subnational level, to meet the International Health Regulations (2005) core surveillance capacity requirements, (ii) are European syndromic surveillance systems comparable to enable cross...... effect of different types of public health emergencies in a timely manner as required by the International Health Regulations (2005)....

Dissociative multiple photoionization of SiBr4 and GeBr4 in the VUV and X-ray regions: a comparative study of inner-shell processes involving Si(2p, 2s), Ge(3d, 3p, 3s), and Br(3d, 3p, 3s)

International Nuclear Information System (INIS)

Boo, Bong Hyun; Saito, Norio

2003-01-01

Dissociative multiple photoionization of MBr 4 (M=Si, Ge) in the Si(2p, 2s), Ge(3d, 3s, 3p), and Br(3d, 3p, 3s) inner-shell regions has been studied by using time-of-flight (TOF) mass spectrometry coupled to synchrotron radiation in the ranges of 50∼944 eV for SiBr 4 and 50∼467 eV for GeBr 4 . Total photoion and photoion-photoion coincidence (PIPICO) yields have been measured as functions of the photon energy. Here, giant shape resonances have been observed beyond the thresholds of the 3d shells owing to the Br(3d 10 )→Br(3d 9 -f) excitation, showing the similar patterns for both of the systems. The ranges and the intensities of the shape resonances are found to be tremendously broad and enhanced, respectively, by the tetrahedral arrangement of the bromine ligands. In addition to the giant resonances, we have observed discrete features corresponding to the Br(3d), Si(2p), and Si(2s) in SiBr 4 and to the Br(3d), Ge(3p), and Ge(3s) in GeBr 4 . The dissociation processes of multiply charged parent ions have also been evaluated from the variations of photoelectron-photoion coincidence (PEPICO) and PIPICO yields with the photon energy. Over the entire energies examined, most efficient PIPICO channels involve Br + -Br + , Br + -MBr + , and M + -Br + (M=Si, Ge), the formation of which indicates that the total destruction of the molecules is a dominant process in the dissociative photoionization of the molecules

Elimination mechanisms of Br2+ and Br+ in photodissociation of 1,1- and 1,2-dibromoethylenes using velocity imaging technique

International Nuclear Information System (INIS)

Hua Linqiang; Zhang Bing; Lee, Wei-Bin; Chao, Meng-Hsuan; Lin, King-Chuen

2011-01-01

Elimination pathways of the Br 2 + and Br + ionic fragments in photodissociation of 1,2- and 1,1-dibromoethylenes (C 2 H 2 Br 2 ) at 233 nm are investigated using time-of-flight mass spectrometer equipped with velocity ion imaging. The Br 2 + fragments are verified not to stem from ionization of neutral Br 2 , that is a dissociation channel of dibromoethylenes reported previously. Instead, they are produced from dissociative ionization of dibromoethylene isomers. That is, C 2 H 2 Br 2 is first ionized by absorbing two photons, followed by the dissociation scheme, C 2 H 2 Br 2 + + hv→Br 2 + + C 2 H 2 . 1,2-C 2 H 2 Br 2 gives rise to a bright Br 2 + image with anisotropy parameter of -0.5 ± 0.1; the fragment may recoil at an angle of ∼66 deg. with respect to the C = C bond axis. However, this channel is relatively slow in 1,1-C 2 H 2 Br 2 such that a weak Br 2 + image is acquired with anisotropy parameter equal to zero, indicative of an isotropic recoil fragment distribution. It is more complicated to understand the formation mechanisms of Br + . Three routes are proposed for dissociation of 1,2-C 2 H 2 Br 2 , including (a) ionization of Br that is eliminated from C 2 H 2 Br 2 by absorbing one photon, (b) dissociation from C 2 H 2 Br 2 + by absorbing two more photons, and (c) dissociation of Br 2 + . Each pathway requires four photons to release one Br + , in contrast to the Br 2 + formation that involves a three-photon process. As for 1,1-C 2 H 2 Br 2 , the first two pathways are the same, but the third one is too weak to be detected.

European Energy Law Seminar 2005. Report of NeVER

International Nuclear Information System (INIS)

Oosterom, A.R.; Boumans, L.

2005-01-01

An overview is given of the lectures and presentations at the title seminar, which was held in Noordwijk aan Zee, Netherlands, 30-31 May 2005. The seminar was organized by the Dutch Association for Energy Law (NeVER), the Scandinavian Institute for Maritime Law of the University of Oslo, and the Groningen University. The subjects presented concerned recent developments with regard to the internal (European) energy market, LNG, developments in the North Sea area, supply security and quality in a competitive market, reorganization of the European market for natural gas in the light of the liberalization process and privatization of the energy sector [nl

Br2 elimination in 248-nm photolysis of CF2Br2 probed by using cavity ring-down absorption spectroscopy.

Science.gov (United States)

Hsu, Ching-Yi; Huang, Hong-Yi; Lin, King-Chuen

2005-10-01

By using cavity ring-down absorption spectroscopy technique, we have observed the channel of Br2 molecular elimination following photodissociation of CF2Br2 at 248 nm. A tunable laser beam, which is crossed perpendicular to the photolyzing laser beam in a ring-down cell, is used to probe the Br2 fragment in the B 3Piou+-X1Sigmag+ transition. The vibrational population is obtained in a nascent state, despite ring-down time as long as 500-1000 ns. The population ratio of Br2(v=1)/Br2(v=0) is determined to be 0.4+/-0.2, slightly larger than the value of 0.22 evaluated by Boltzmann distribution at room temperature. The quantum yield of the Br2 elimination reaction is also measured to be 0.04+/-0.01. This work provides direct evidence to support molecular elimination occurring in the CF2Br2 photodissociation and proposes a plausible pathway with the aid of ab initio potential-energy calculations. CF2Br2 is excited probably to the 1B1 and 3B2 states at 248 nm. As the C-Br bond is elongated upon excitation, the coupling of the 1A'(1B1) state to the high vibrational levels of the ground state X 1A'(1A1) may be enhanced to facilitate the process of internal conversion. After transition, the highly vibrationally excited CF2Br2 feasibly surpasses a transition barrier prior to decomposition. According to the ab initio calculations, the transition state structure tends to correlate with the intermediate state CF2Br+Br(CF2Br...Br) and the products CF2+Br2. A sequential photodissociation pathway is thus favored. That is, a single C-Br bond breaks, and then the free-Br atom moves to form a Br-Br bond, followed by the Br2 elimination. The formed Br-Br bond distance in the transition state tends to approach equilibrium such that the Br2 fragment may be populated in cold vibrational distribution. Observation of a small vibrational population ratio of Br2(v=1)Br2(v=0) agrees with the proposed mechanism.

2005 primary energy consumption in Germany

International Nuclear Information System (INIS)

Anon.

2006-01-01

According to preliminar calculations by the Arbeitsgemeinschaft Energiebilanzen (Working Party on Energy Balances, AGEB), the consumption of an aggregate 486 million TCE of primary energy resources in Germany last year was 1.3% below the level of the year before. Energy consumption was influenced by both the high level of prices and the development of the economy. Hardly any influence was attributable to the level of temperatures, which was largely unchanged compared to the figure of the year before. Oil consumption in 2005 in Germany dropped by nearly 2% to 174.8 million TCE. On the whole, oil with its 36% share in the energy balance remained by far the most important energy resource in Germany. Natural gas consumption of 110.4 million TCE was at the level of the year before. Its share in the primary energy balance rose slightly to 22.7%. Hard coal, because of lower use in power plants and the decline in iron making, showed a 4.6% drop in consumption to 62.8 million TCE. In this way, hard coal contributed 13% to total energy consumption. Lignite consumption dropped by 3.2% to 54.4 million TCE as a result of lower deliveries to power plants. Its 11.2% share in the total consumption of primary energy continued to make lignite the most important domestic energy resource. More than 90% of the lignite produced is used for electricity generation. The contribution to primary energy consumption of nuclear power dropped by more than 2% to 60.7 million TCE. Hydroelectric plants and wind power plants increased their contribution by 3.6%. The contribution to primary energy consumption made by all renewable energy resources rose to 4.6%. AGEB evaluates statistics of all areas of the power economy on the basis of standard criteria in order to combine these data in a comprehensive picture. Since 1994, the energy balances for Germany have been compiled by DIW on behalf of AGEB. (orig.)

Two-color visible/vacuum ultraviolet photoelectron imaging dynamics of Br2.

Science.gov (United States)

Plenge, Jürgen; Nicolas, Christophe; Caster, Allison G; Ahmed, Musahid; Leone, Stephen R

2006-10-07

An experimental two-color photoionization dynamics study of laser-excited Br2 molecules is presented, combining pulsed visible laser excitation and tunable vacuum ultraviolet (VUV) synchrotron radiation with photoelectron imaging. The X 1Sigmag + -B 3Pi0+u transition in Br2 is excited at 527 nm corresponding predominantly to excitation of the v' = 28 vibrational level in the B 3Pi0+u state. Tunable VUV undulator radiation in the energy range of 8.40-10.15 eV is subsequently used to ionize the excited molecules to the X 2Pi32,12 state of the ion, and the ionic ground state is probed by photoelectron imaging. Similar experiments are performed using single-photon synchrotron ionization in the photon energy range of 10.75-12.50 eV without any laser excitation. Photoelectron kinetic energy distributions are extracted from the photoelectron images. In the case of two-color photoionization using resonant excitation of the intermediate B 3Pi0+u state, a broad distribution of photoelectron kinetic energies is observed, and in some cases even a bimodal distribution, which depends on the VUV photon energy. In contrast, for single-photon ionization, a single nearly Gaussian-shaped distribution is observed, which shifts to higher energy with photon energy. Simulated spectra based on Franck-Condon factors for the transitions Br2(X 1Sigmag+, v" = 0)-Br2 +(X 2Pi12,32, v+) and Br2(B 3Pi0+u, v' = 28)-Br2 +(X 2Pi12,32, v+) are generated. Comparison of these calculated spectra with the measured images suggests that the differences in the kinetic energy distributions for the two ionization processes reflect the different extensions of the vibrational wave functions in the v" = 0 electronic ground state (X 1Sigmag+) versus the electronically and vibrationally excited state (B 3Pi0+u, v' = 28).

A significant shift in favor of nuclear energy since 2005

International Nuclear Information System (INIS)

Anon.

2008-01-01

A new opinion poll shows a general trend in Europe in favor of nuclear energy: 44% of the people interrogated are for nuclear energy while only 37% were for in 2005. About 40% of the people against nuclear energy would change their mind if a safe and definitive solution for the management of radioactive waste was found. The survey also shows that more people are aware of the assets of nuclear energy in terms of energy independence and greenhouse gas emission. The countries where the support is the strongest are the Czech Republic (64%), Lithuania (64%), Sweden (62%) and Finland (61%). In France, the biggest nuclear energy producer in Europe, the rate of favorable opinion for nuclear energy remains constant at 52%. (A.C.)

Ultrafast interfacial energy transfer and interlayer excitons in the monolayer WS2/CsPbBr3 quantum dot heterostructure.

Science.gov (United States)

Li, Han; Zheng, Xin; Liu, Yu; Zhang, Zhepeng; Jiang, Tian

2018-01-25

The idea of fabricating artificial solids with band structures tailored to particular applications has long fascinated condensed matter physicists. Heterostructure (HS) construction is viewed as an effective and appealing approach to engineer novel electronic properties in two dimensional (2D) materials. Different from common 2D/2D heterojunctions where energy transfer is rarely observed, CsPbBr 3 quantum dots (0D-QDs) interfaced with 2D materials have become attractive HSs for exploring the physics of charge transfer and energy transfer, due to their superior optical properties. In this paper, a new 0D/2D HS is proposed and experimentally studied, making it possible to investigate both light utilization and energy transfer. Specifically, this HS is constructed between monolayer WS 2 and CsPbBr 3 QDs, and exhibits a hybrid band alignment. The dynamics of energy transfer within the investigated 0D/2D HS is characterized by femtosecond transient absorption spectrum (TAS) measurements. The TAS results reveal that ultrafast energy transfer caused by optical excitation is observed from CsPbBr 3 QDs to the WS 2 layer, which can increase the exciton fluence within the WS 2 layer up to 69% when compared with pristine ML WS 2 under the same excitation fluence. Moreover, the formation and dynamics of interlayer excitons have also been investigated and confirmed in the HS, with a calculated recombination time of 36.6 ps. Finally, the overall phenomenological dynamical scenario for the 0D/2D HS is established within the 100 ps time region after excitation. The techniques introduced in this work can also be applied to versatile optoelectronic devices based on low dimensional materials.

Contributions of BrCl, Br2, BrOCl, Br2O, and HOBr to regiospecific bromination rates of anisole and bromoanisoles in aqueous solution.

Science.gov (United States)

Sivey, John D; Bickley, Mark A; Victor, Daniel A

2015-04-21

When bromide-containing waters are chlorinated, conventional wisdom typically assumes HOBr is the only active brominating agent. Several additional and often-overlooked brominating agents (including BrCl, Br2, BrOCl, Br2O) can form in chlorinated waters, albeit at generally lower concentrations than HOBr. The extent to which these additional brominating agents influence bromination rates of disinfection byproduct precursors is, however, poorly understood. Herein, the influence of BrCl, Br2, BrOCl, Br2O, and HOBr toward rates of sequential bromination of anisole was quantified. Conditions affecting bromine speciation (e.g., pH, concentrations of chloride, bromide, and chlorine) were varied, and regiospecific second-order rate constants were calculated for reactions of each brominating agent with anisole, 2-bromoanisole, and 4-bromoanisole. The regioselectivity of anisole bromination changed with pH, consistent with the participation of more than one brominating agent. Under conditions representative of chlorinated drinking water, contributions to bromination rates decreased as BrCl > BrOCl > HOBr > Br2O (Br2 negligible). The second-order rate constant determined for net bromination of anisole by HOBr is up to 3000-times less than reported in previous studies (which assumed HOBr was the only active brominating agent). Accordingly, models that assume HOBr is the only kinetically relevant brominating agent in solutions of free bromine may be insufficient for reactions involving modestly nucleophilic organic compounds.

An interatomic potential model for molecular dynamics simulation of silicon etching by Br+-containing plasmas

International Nuclear Information System (INIS)

Ohta, H.; Iwakawa, A.; Eriguchi, K.; Ono, K.

2008-01-01

An interatomic potential model for Si-Br systems has been developed for performing classical molecular dynamics (MD) simulations. This model enables us to simulate atomic-scale reaction dynamics during Si etching processes by Br + -containing plasmas such as HBr and Br 2 plasmas, which are frequently utilized in state-of-the-art techniques for the fabrication of semiconductor devices. Our potential form is based on the well-known Stillinger-Weber potential function, and the model parameters were systematically determined from a database of potential energies obtained from ab initio quantum-chemical calculations using GAUSSIAN03. For parameter fitting, we propose an improved linear scheme that does not require any complicated nonlinear fitting as that in previous studies [H. Ohta and S. Hamaguchi, J. Chem. Phys. 115, 6679 (2001)]. In this paper, we present the potential derivation and simulation results of bombardment of a Si(100) surface using a monoenergetic Br + beam

Theoretical investigation of potential energy surface and bound states for the van der Waals complex Ar–BrCl dimer

Energy Technology Data Exchange (ETDEWEB)

Zheng, Rui [School of Mathematics and Information Science, North China University of Water Resources and Electric Power, Zhengzhou (China); Key Laboratory of Magnetic Resonance in Biological Systems, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Centre for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan (China); Li, Song, E-mail: lsong@yangtzeu.edu.cn [School of Physics and Optoelectronic Engineering, Yangtze University, Jingzhou (China); Chen, Shan-Jun; Chen, Yan [School of Physics and Optoelectronic Engineering, Yangtze University, Jingzhou (China); Zheng, Li-Min [Key Laboratory of Magnetic Resonance in Biological Systems, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Centre for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan (China)

2015-09-08

Highlights: • A two-dimensional potential for Ar–BrCl is constructed at the CCSD(T) level. • The PES is characterized by three minima and two saddle points between them. • Bound state calculations were carried out for the complex. - Abstract: The intermolecular potential energy surface (PES) of the ground electronic state for the Ar–BrCl dimer is constructed at the CCSD(T) level with the aug-cc-pVQZ basis set and mid-bond functions. The PES is characterized by three minima and two saddle points. The global minimum corresponding to a collinear Ar–BrCl configuration, which has been observed experimentally, is located at R = 4.10 Å and θ = 2.5° with a well depth of −285.207 cm{sup −1}. A nearly T-shaped structure and an anti-linear Ar–ClBr geometry is also predicted. The bound state calculations are preformed to study intermolecular vibrational modes, rotational levels and average structures for the complex. Our transition frequencies, spectroscopic constants and average structures for all isotopomers of the collinear isomer agree well with experimental data. We have also provided pure rotational transitional frequencies for both nearly T-shaped and anti-linear isomers. These results are significant for further experimental investigations of the Ar–BrCl dimer.

Temperature dependent absorption spectra of Br(-), Br2(•-), and Br3(-) in aqueous solutions.

Science.gov (United States)

Lin, Mingzhang; Archirel, Pierre; Van-Oanh, Nguyen Thi; Muroya, Yusa; Fu, Haiying; Yan, Yu; Nagaishi, Ryuji; Kumagai, Yuta; Katsumura, Yosuke; Mostafavi, Mehran

2011-05-05

The absorption spectra of Br(2)(•-) and Br(3)(-) in aqueous solutions are investigated by pulse radiolysis techniques from room temperature to 380 and 350 °C, respectively. Br(2)(•-) can be observed even in supercritical conditions, showing that this species could be used as a probe in pulse radiolysis at high temperature and even under supercritical conditions. The weak temperature effect on the absorption spectra of Br(2)(•-) and Br(3)(-) is because, in these two systems, the transition occurs between two valence states; for example, for Br(2)(-) we have (2)Σ(u) → (2)Σ(g) transition. These valence transitions involve no diffuse final state. However, the absorption band of Br(-) undergoes an important red shift to longer wavelengths. We performed classical dynamics of hydrated Br(-) system at 20 and 300 °C under pressure of 25 MPa. The radial distribution functions (rdf's) show that the strong temperature increase (from 20 to 300 °C) does not change the radius of the solvent first shell. On the other hand, it shifts dramatically (by 1 Å) the second maximum of the Br-O rdf and introduces much disorder. This shows that the first water shell is strongly bound to the anion whatever the temperature. The first two water shells form a cavity of a roughly spherical shape around the anion. By TDDFT method, we calculated the absorption spectra of hydrated Br(-) at two temperatures and we compared the results with the experimental data.

Evidence for concerted ring opening and C-Br bond breaking in UV-excited bromocyclopropane.

Science.gov (United States)

Pandit, Shubhrangshu; Preston, Thomas J; King, Simon J; Vallance, Claire; Orr-Ewing, Andrew J

2016-06-28

Photodissociation of gaseous bromocyclopropane via its A-band continuum has been studied at excitation wavelengths ranging from 230 nm to 267 nm. Velocity-map images of ground-state bromine atoms (Br), spin-orbit excited bromine atoms (Br(∗)), and C3H5 hydrocarbon radicals reveal the kinetic energies of these various photofragments. Both Br and Br(∗) atoms are predominantly generated via repulsive excited electronic states in a prompt photodissociation process in which the hydrocarbon co-fragment is a cyclopropyl radical. However, the images obtained at the mass of the hydrocarbon radical fragment identify a channel with total kinetic energy greater than that deduced from the Br and Br(∗) images, and with a kinetic energy distribution that exceeds the energetic limit for Br + cyclopropyl radical products. The velocity-map images of these C3H5 fragments have lower angular anisotropies than measured for Br and Br(∗), indicating molecular restructuring during dissociation. The high kinetic energy C3H5 signals are assigned to allyl radicals generated by a minor photochemical pathway which involves concerted C-Br bond dissociation and cyclopropyl ring-opening following single ultraviolet (UV)-photon absorption. Slow photofragments also contribute to the velocity map images obtained at the C3H5 radical mass, but the corresponding slow Br atoms are not observed. These features in the images are attributed to C3H5 (+) from the photodissociation of the C3H5Br(+) molecular cation following two-photon ionization of the parent compound. This assignment is confirmed by 118-nm vacuum ultraviolet ionization studies that prepare the molecular cation in its ground electronic state prior to UV photodissociation.

Trends in energy 2005. Utility value chain optimisation

International Nuclear Information System (INIS)

Fens, T.; IJsbrandy, C.; Van Druten, A.; De Rooij, S.; Van de Rhee, R.; Rookmaaker, J.; Spaans, P.; Pulles, L.

2005-01-01

Trends in Energy 2005 has been written around a number of events that were observed in research that was carried out in 2004: the full market opening mid 2004, the likely unbundling of distribution networks in some form, security of supply issues, fuel mix in the generation portfolio and the associated investment strategies, the rise of intelligent metering, certificates of origin for electricity, the most likely movement towards the suppliers model ('leveranciersmodel') and finally emissions management emerging from Kyoto that is coming into force. These events have been interpreted from the perspective of the units in the energy value chain: production, trade, transmission, distribution, metering and sales, the latter is the mostly the direct contact for the end customer

Energy calibration for LaBr3(Ce) scintillator detector in the region of 1-10 MeV

International Nuclear Information System (INIS)

Zhang Jianhua; Zhu Chengsheng; Zeng Jun; Ding Ge; Xiang Qingpei; Liu Zhao; Yang Chaowen

2013-01-01

Background: LaBr 3 (Ce) detector has played an important role in detecting explosive, contraband and landmine because of its high y detection efficiency and good energy resolution etc. Purpose: To calibrate detector in wide energy region. Methods: The gamma spectra of NH 4 Cl and C 3 H 6 N 6 induced by 252 Cf neutron source were measured. Results: Comparing their gamma spectra, characteristic gamma lines can be located and the energy calibration curve was obtained. Conclusions: Radio nuclides can be identified by the calibration curve fitted with quadratic or cubic polynomial. (authors)

Irradiation techniques at BR2 reactor

International Nuclear Information System (INIS)

Hebel, W.

1978-01-01

Since 1963 the material testing reactor BR2 at Mol is operated for the realisation of numerous research programs and experiments on the behavior of materials under nuclear radiation and in particular under intensive neutron exposure. During this period special irradiation techniques and experimental devices were developed according to the desiderata of the different experiments and to the irradiation possibilities offered at BR2. The design and the operating characteristics of quite a number of those irradiation rigs of proven reliability may be used or can be made available for new irradiation experiments. A brief description is given of some typical irradiation devices designed and constructed by CEN/SCK, Technology and Energy Dpt. They are compiled according to their main use for the different research and development programs realized at BR2. Their eventual application however for different objectives could be possible. A final chapter summarizes the principal irradiation conditions offered by BR2 reactor. (author)

Evidence for concerted ring opening and C–Br bond breaking in UV-excited bromocyclopropane

Energy Technology Data Exchange (ETDEWEB)

Pandit, Shubhrangshu; Preston, Thomas J.; Orr-Ewing, Andrew J., E-mail: a.orr-ewing@bristol.ac.uk [School of Chemistry, University of Bristol, Cantock’s Close, Bristol BS8 1TS (United Kingdom); King, Simon J.; Vallance, Claire [Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA (United Kingdom)

2016-06-28

Photodissociation of gaseous bromocyclopropane via its A-band continuum has been studied at excitation wavelengths ranging from 230 nm to 267 nm. Velocity-map images of ground-state bromine atoms (Br), spin-orbit excited bromine atoms (Br{sup ∗}), and C{sub 3}H{sub 5} hydrocarbon radicals reveal the kinetic energies of these various photofragments. Both Br and Br{sup ∗} atoms are predominantly generated via repulsive excited electronic states in a prompt photodissociation process in which the hydrocarbon co-fragment is a cyclopropyl radical. However, the images obtained at the mass of the hydrocarbon radical fragment identify a channel with total kinetic energy greater than that deduced from the Br and Br{sup ∗} images, and with a kinetic energy distribution that exceeds the energetic limit for Br + cyclopropyl radical products. The velocity-map images of these C{sub 3}H{sub 5} fragments have lower angular anisotropies than measured for Br and Br{sup ∗}, indicating molecular restructuring during dissociation. The high kinetic energy C{sub 3}H{sub 5} signals are assigned to allyl radicals generated by a minor photochemical pathway which involves concerted C–Br bond dissociation and cyclopropyl ring-opening following single ultraviolet (UV)-photon absorption. Slow photofragments also contribute to the velocity map images obtained at the C{sub 3}H{sub 5} radical mass, but the corresponding slow Br atoms are not observed. These features in the images are attributed to C{sub 3}H{sub 5}{sup +} from the photodissociation of the C{sub 3}H{sub 5}Br{sup +} molecular cation following two-photon ionization of the parent compound. This assignment is confirmed by 118-nm vacuum ultraviolet ionization studies that prepare the molecular cation in its ground electronic state prior to UV photodissociation.

Chemical effects of the radioactive decay 7677Kr→7677Br reactions of recoil bromine in the gas phase

International Nuclear Information System (INIS)

Jong, D. de.

1982-01-01

This thesis describes the chemical reactions of 76 Br and 77 Br recoil species, formed by radioactive decay of 76 Kr and 77 Kr, with various gaseous compounds. Due to differences in decay energy and decay mode the resulting 76 Br and 77 Br isotopes obtain different kinetic energies and carry different charges; 76 Kr decays completely via electron capture and the resulting 76 Br is formed with a multiple positive charge and a kinetic energy of 7.2 eV at the most. 77 Kr decays for only 16% via electron capture, resulting in 77 Brsup(n+) ions with a maximal kinetic energy of 56.9 eV. 84% of the 77 Kr decays via #betta# + particle emission, which leads to 77 Br species, that are mainly negative or uncharged and that possess a maximal kinetic energy of 36.4 eV. The aim of this study was to explore whether these initial differences in charge and kinetic energy are reflected in the products, formed after chemical reactions of 76 Br and 77 Br. (Auth.)

KEK (High Energy Accelerator Research Organization) annual report, 2005

International Nuclear Information System (INIS)

2006-01-01

This report summarizes research activities of KEK (High Energy Accelerator Research Organization) in the fiscal year 2005. Two years have passed since the KEK was reorganized as an inter-university research institute corporation, and KEK continue to facilitate a wide range of research programs based on high-energy accelerators for users from universities. KEK consists of two research institutes, the Institute of Particle and Nuclear Studies (IPNS) and the Institute of Materials Science (IMSS); and two laboratories, the Accelerator Laboratory and the Applied Research Laboratory. KEK has been operating four major accelerator facilities in Tsukuba: the 12 GeV Proton Synchrotron (PS), the KEK B-factory (KEKB), the Photon Factory (PF), and the Electron/Positron Injector Linac. We are now engaged in the construction of the Japan Proton Accelerator Research Complex (J-PARC) in Tokai in cooperation with the Japan Atomic Energy Agency (JAEA). The J-PARC Center was established in February 2006 to take full responsibility for the operation of J-PARC. With the progress of construction, the PS ceased operation at the end of March 2006 after a history of 26 years. The task of KEK is to play a key role in the fields of elementary particle, nuclei, materials and life science as one of leading research facilities of the world. The fiscal year 2005 activities of both KEK employees and visiting researchers yielded excellent outcomes in these research fields. (J.P.N.)

LaBr3:Ce crystal: The latest advance for scintillation cameras

International Nuclear Information System (INIS)

Pani, R.; Pellegrini, R.; Cinti, M.N.; Bennati, P.; Betti, M.; Vittorini, F.; Mattioli, M.; Trotta, G.; Orsolini Cencelli, V.; Scafe, R.; Montani, L.; Navarria, F.; Bollini, D.; Baldazzi, G.; Moschini, G.; Rossi, P.; De Notaristefani, F.

2007-01-01

Recent availability of LaBr 3 :Ce crystal is attracting researchers for the development of new advanced SPECT e PET systems. The crystal shows excellent energy resolution values good radiation absorption properties and speed. At present, LaBr 3 :Ce crystal is available with continuous shape covering 5x5 cm 2 area with a thickness up to 1 in. With the aim of analysing the imaging performances of LaBr 3 :Ce for Single Photon Emission Tomography (SPET), we tested three continuous crystals with the same detection area of 5x5 cm 2 and various thicknesses ranging between 4 and 10 mm. Three small scintillation cameras were assembled by coupling LaBr3:Ce crystal to Hamamatsu H8500 Flat panel PMT. The results show very good imaging performances for single photon emission application with superior energy and spatial resolution up 7.5% and 0.9 mm, respectively, and a detection efficiency up to 95% at 140 keV photon energy

248 nm photolysis of CH2Br2 by using cavity ring-down absorption spectroscopy: Br2 molecular elimination at room temperature.

Science.gov (United States)

Wei, Pei-Ying; Chang, Yuan-Ping; Lee, Wei-Bin; Hu, Zhengfa; Huang, Hong-Yi; Lin, King-Chuen; Chen, K T; Chang, A H H

2006-10-07

Following photodissociation of CH2Br2 at 248 nm, Br2 molecular elimination is detected by using a tunable laser beam, as crossed perpendicular to the photolyzing laser beam in a ring-down cell, probing the Br2 fragment in the B 3Piou+ -X 1Sigmag+ transition. The nascent vibrational population is obtained, yielding a population ratio of Br2(v = 1)Br2(v = 0) to be 0.7 +/- 0.2. The quantum yield for the Br2 elimination reaction is determined to be 0.2 +/- 0.1. Nevertheless, when CH2Br2 is prepared in a supersonic molecular beam under cold temperature, photofragmentation gives no Br2 detectable in a time-of-flight mass spectrometer. With the aid of ab initio potential energy calculations, a plausible pathway is proposed. Upon excitation to the 1B1 or 3B1 state, C-Br bond elongation may change the molecular symmetry of Cs and enhance the resultant 1 1,3A'-X 1A' (or 1 1,3B1-X 1A1 as C2v is used) coupling to facilitate the process of internal conversion, followed by asynchronous concerted photodissociation. Temperature dependence measurements lend support to the proposed pathway.

End-user GHG emissions from energy. Reallocation of emissions from energy industries to end users 2005-2009

Energy Technology Data Exchange (ETDEWEB)

Fernandez, R. (European Environment Agency (EEA), Copenhagen (Denmark)); Watterson, J. (AEA Technology plc - EEA' s European Topic Centre on Air Pollution and Climate Change Mitigation (ETC/ACM) (United Kingdom))

2011-12-15

The objective of this report is to help improve the understanding of past greenhouse gas (GHG) emission trends in the energy sector from the demand or end-user side. To do this, the report develops a methodology to redistributes emissions from energy industries to the final users (by sector) of that energy. This reallocation is done on the basis of Eurostat's energy balances and GHG inventories for the energy sector as reported to the United Nations Framework Convention on Climate Change (UNFCCC), for the period 2005-2009. (Author)

End-user GHG emissions from energy. Reallocation of emissions from energy industries to end users 2005-2010

Energy Technology Data Exchange (ETDEWEB)

Fernandez, R. [European Environment Agency (EEA), Copenhagen (Denmark); Watterson, J. [AEA Technology plc - EEA' s European Topic Centre on Air Pollution and Climate Change Mitigation (ETC/ACM) (United Kingdom)

2012-12-15

The objective of this report is to help improve the understanding of past GHG emission trends in the energy sector from the demand or end-user side. To do this, the report develops a methodology to redistributes emissions from energy industries to the final users (by sector) of that energy. This reallocation is done on the basis of Eurostat's energy balances and GHG inventories for the energy sector as reported to the United Nations Framework Convention on Climate Change (UNFCCC), for the period 2005-2010. (Author)

Non-enzymatic antioxidant accumulations in BR-deficient and BR-insensitive barley mutants under control and drought conditions.

Science.gov (United States)

Gruszka, Damian; Janeczko, Anna; Dziurka, Michal; Pociecha, Ewa; Fodor, Jozsef

2017-12-07

Drought is one of the most adverse stresses that affect plant growth and yield. Disturbances in metabolic activity resulting from drought cause overproduction of reactive oxygen species. It is postulated that brassinosteroids (BRs) regulate plant tolerance to the stress conditions, but the underlying mechanisms remain largely unknown. An involvement of endogenous BRs in regulation of the antioxidant homeostasis is not fully clarified either. Therefore, the aim of this study was to elucidate the role of endogenous BRs in regulation of non-enzymatic antioxidants in barley (Hordeum vulgare) under control and drought conditions. The plant material included the 'Bowman' cultivar and a group of semi-dwarf near-isogenic lines (NILs), representing mutants deficient in BR biosynthesis or signaling. In general, accumulations of 11 compounds representing various types of non-enzymatic antioxidants were analyzed under both conditions. The analyses of accumulations of reduced and oxidized forms of ascorbate indicated that the BR mutants contain significantly higher contents of dehydroascorbic acid under drought conditions when compared with the 'Bowman' cultivar. The analysis of glutathione accumulation indicated that under the control conditions the BR-insensitive NILs contained significantly lower concentrations of this antioxidant when compared with the rest of genotypes. Therefore, we postulate that BR sensitivity is required for normal accumulation of glutathione. A complete accumulation profile of various tocopherols indicated that functional BR biosynthesis and signaling are required for their normal accumulation under both conditions. Results of this study provided an insight into the role of endogenous BRs in regulation of the non-enzymatic antioxidant homeostasis. © 2017 Scandinavian Plant Physiology Society.

Studies on the phase diagram of LiBr-SrBr2 system

International Nuclear Information System (INIS)

Mahendran, K.H.; Sujatha, K.; Sridharan, R.; Gnanasekaran, T.

2003-01-01

Binary LiBr-SrBr 2 system was investigated using differential scanning calorimetry (DSC) and the equilibrium phases at different compositions were identified using X-ray diffraction (XRD). This system has a compound LiSr 2 Br 5 , and exhibits a eutectic reaction between this compound and LiBr at 434 deg. C and the eutectic has a composition of 35 mol% SrBr 2 . The compound LiSr 2 Br 5 undergoes peritectic decomposition at 484 deg. C. From the DSC and XRD results, phase diagram of the LiBr-SrBr 2 system is constructed

Nuclear Energy, Long Term Requirements

International Nuclear Information System (INIS)

Knapp, V.

2006-01-01

There are serious warnings about depletion of oil and gas and even more serious warnings about dangers of climate change caused by emission of carbon dioxide. Should developed countries be called to replace CO2 emitting energy sources as soon as possible, and the time available may not be longer then few decades, can nuclear energy answer the call and what are the requirements? Assuming optimistic contribution of renewable energy sources, can nuclear energy expand to several times present level in order to replace large part of fossil fuels use? Paper considers intermediate and long-term requirements. Future of nuclear power depends on satisfactory answers on several questions. First group of questions are those important for near and intermediate future. They deal with economics and safety of nuclear power stations in the first place. On the same time scale a generally accepted concept for radioactive waste disposal is also required. All these issues are in the focus of present research and development. Safer and more economical reactors are targets of international efforts in Generation IV and INPRO projects, but aiming further ahead these innovative projects are also addressing issues such as waste reduction and proliferation resistance. However, even assuming successful technical development of these projects, and there is no reason to doubt it, long term and large-scale nuclear power use is thereby not yet secured. If nuclear power is to play an essential role in the long-term future energy production and in reduction of CO2 emission, than several additional questions must be replied. These questions will deal with long-term nuclear fuel sufficiency, with necessary contribution of nuclear power in sectors of transport and industrial processes and with nuclear proliferation safety. This last issue is more political then technical, thus sometimes neglected by nuclear engineers, yet it will have essential role for the long-term prospects of nuclear power. The

Energy sector from 1990 to 2005 - analysis and consequences

International Nuclear Information System (INIS)

Granic, G.

2005-01-01

The paper analyzes the energy sector in the period from 1990 to 2005. What is shown here through an analysis of political, economic, energy, technological and institutional processes, and based on actual developments and non-developments, the consequences on energy situation to be evolved in the next 15 years, are analyzed. A crucial characteristic of this period is the fact that consumption growth is more distant from the trends in the developed countries and is increasingly approaching ones occurring in developing and undeveloped countries. The other such characteristic is lack of technological progress, which could generate desirable structural changes in energy production and demand. Taking in consideration what has been accomplished so far and what has not been accomplished, we cannot expect in the coming period the changes that could significantly modify the relations in the structure of energy production and demand. Keeping the balance between production and demand will be increasingly difficult, as well as keeping the influence on energy prices which will be growing. In this, it is more than ever indispensable that the state takes up its role.(author)

Fragmentation of pure and hydrated clusters of 5Br-uracil by low energy carbon ions: observation of hydrated fragments

Czech Academy of Sciences Publication Activity Database

Castrovilli, M. C.; Markush, P.; Bolognesi, P.; Rousseau, P.; Maclot, S.; Cartoni, A.; Delaunay, R.; Domaracka, A.; Kočišek, Jaroslav; Huber, B. A.; Avaldi, L.

2017-01-01

Roč. 19, č. 30 (2017), s. 19807-19814 ISSN 1463-9076 Institutional support: RVO:61388955 Keywords : fragmentation * nano-hydrated 5BrU clusters * low energy carbon ions Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 4.123, year: 2016

Energy and architecture. [Denmark]; Energi + arkitektur

Energy Technology Data Exchange (ETDEWEB)

Lehrskov, H. [Ingenioerhoejskolen i Aarhus, Aarhus (Denmark); Oehlenschlaeger, R. [AplusB, Aarhus (Denmark); Kappel, K. [Solar City Copenhagen, Copenhagen (Denmark); Kleis, B. [Arkitekturformidling.dk, Vanloese (Denmark); Klint, J. [Kuben Management, Aarhus (Denmark); Vejsig Pedersen, P. [Cenergia, Herlev (Denmark)

2011-07-01

The book presents the best examples of Danish energy-oriented architecture with a focus on architectural and energy measures in the integrated design process, resulting in architectural quality. The book consists of two parts and consists first of an introduction to the challenges and tools within low-energy buildings, and then a catalog of a wide range of building projects in the categories of housing, business, education, institutions and sports. The book contains examples of new buildings that as a minimum meet the requirements of the building codes LE1, BR08. The book also contains suggestions for renovation projects that meet LE2 BR08, as the energy optimization of the existing building stock is an imminent task with great constructional and aesthetic challenges. The selected projects are designed and built in the period 2009 to 2011 and include both everyday architecture, created under highly competitive economic environment, as more exclusive development projects. The objectives of the projects are often higher than required by the building code, and in many projects measurements were made to find out what works. These examples show that the stricter energy requirements can serve as inspiration for a holistic architecture and contribute to a paradigm shift in the cooperation process between the project parties. But it is also clear that it requires a focused commitment of all players in the construction industry - clients, consultants, contractors and building product manufacturers - to reduce energy consumption significantly. (LN)

Structure and bonding of transition metal-boryl compounds. Theoretical study of [(PH3)2(CO)ClOs-BR2] and [(PH3)2(CO)2ClOs-BR2] (BR2 = BH2, BF2, B(OH)2, B(OCH=CHO), Bcat).

Science.gov (United States)

Giju, K T; Bickelhaupt, F M; Frenking, G

2000-10-16

Quantum chemical DFT calculations using the B3LYP functionals have been carried out for the electronically unsaturated 16 VE five-coordinate osmium boryl-complexes [(PH3)2(CO)ClOs-BR2] and the 18 VE six-coordinate complexes [(PH3)2(CO)2ClOs-BR2] with BR2 = BH2, BF2, B(OH)2, B(OHC=CHO), and Bcat (cat = catecholate O2C6H4). The bonding situation of the Os-BR2 bond was analyzed with the help of the NBO partitioning scheme. The Os-B bond dissociation energies of the 16 VE complexes are very high, and they do not change very much for the different boryl ligands. The 18 VE complexes have only slightly lower bond energies than the 16 VE species. The Os-B bond in both classes of compounds is provided by a covalent sigma-bond which is polarized toward osmium and by strong charge attraction. Os-->B pi-donation is not important for the Os-B binding interactions, except for the Os-BH2 complexes. The stability of the boryl complexes [Os]-BR2 comes mainly from BB pi-donation. The intraligand charge distribution of the BR2 group changes little when the Os-B bond is formed, except for BH2. The CO ligand in [(PH3)2(CO)2ClOs-BR2] which is trans to BR2 has a relatively weak bond to the osmium atom.

CeBr3 as a room-temperature, high-resolution gamma-ray detector

International Nuclear Information System (INIS)

Guss, Paul; Reed, Michael; Yuan Ding; Reed, Alexis; Mukhopadhyay, Sanjoy

2009-01-01

Cerium bromide (CeBr 3 ) has become a material of interest in the race for high-resolution gamma-ray spectroscopy at room temperature. This investigation quantified the potential of CeBr 3 as a room-temperature, high-resolution gamma-ray detector. The performance of CeBr 3 crystals was compared to other scintillation crystals of similar dimensions and detection environments. Comparison of self-activity of CeBr 3 to cerium-doped lanthanum tribromide (LaBr 3 :Ce) was performed. Energy resolution and relative intrinsic efficiency were measured and are presented.

76 FR 5248 - Insurer Reporting Requirements; Annual Insurer Report on Motor Vehicle Theft for the 2005...

Science.gov (United States)

2011-01-28

...] Insurer Reporting Requirements; Annual Insurer Report on Motor Vehicle Theft for the 2005 Reporting Year... on motor vehicle theft for the 2005 reporting year. Section 33112(h) of Title 49 of the U.S. Code... report provides information on theft and recovery of vehicles; rating rules and plans used by motor...

Development and thermochemical characterizations of vermiculite/SrBr_2 composite sorbents for low-temperature heat storage

International Nuclear Information System (INIS)

Zhang, Y.N.; Wang, R.Z.; Zhao, Y.J.; Li, T.X.; Riffat, S.B.; Wajid, N.M.

2016-01-01

Novel EVM/SrBr_2 composite sorbents with different salt contents were developed for low-temperature thermal energy storage (TES). Simulative sorption experiment was conducted to obtain the sorption kinetics diagram and identify threshold salt content that composite sorbents can hold without solution leakage. Distribution of salt embedded in EVM was observed by extreme-resolution scanning electron microscopy (ER-SEM). Thermochemical characterizations including desorption performance and desorption heat were fully investigated by analyzing simultaneous thermal analyzer (STA) results. Results reveal that sorption process of composite sorbents is divided into three parts: water adsorption of EVM, water adsorption of SrBr_2 crystal and liquid-gas absorption of SrBr_2 solution. Since SrBr_2 solution can be hold in macrospores of EVM, water uptake and energy storage density are greatly increased. It appears that the composite sorbent of EVMSrBr_240 is a promising material for thermal energy storage, with water uptake of 0.53 g/g, mass energy storage density of 0.46 kWh/kg and volume energy storage density of 105.36 kWh/m"3. - Highlights: • Vermiculite/SrBr_2 composite sorbents were developed for thermal energy storage. • Water uptake of composite sorbents is divided into three phases. • Energy storage density of each sorption phase is evaluated via calculations. • EVMSrBr_240 is chosen as optimal sorbent without solution leakage.

Single crystal growth and surface chemical stability of KPb2Br5

Science.gov (United States)

Atuchin, V. V.; Isaenko, L. I.; Kesler, V. G.; Tarasova, A. Yu.

2011-03-01

Single crystal of KPb2Br5 has been grown using the Bridgman technique. Initially the synthesis of stoichiometric KPb2Br5 compound was performed from high purity bromide salts. Electronic structure of KPb2Br5 has been determined with X-ray photoelectron spectroscopy for powdered sample fabricated by grinding in air. Drastic chemical interaction of KPb2Br5 with atmosphere has not been detected. Chemical bonding in potassium- and lead-containing bromides is considered using binding energy differences ΔK=(BE K 2p3/2-BE Br 3d) and ΔPb=(BE Pb 4f7/2-BE Br 3d), respectively, as representative parameters.

Production of 77 Br for medical application

International Nuclear Information System (INIS)

Bastos, M.A.V.

1982-01-01

Bromine-77 is produced with the variable energy cyclotron (CV-28) at the Instituto de Engenharia Nuclear, via the 75 As. (α, 2 n) 77 Br reaction, by bombarding arsenic trioxide with 28 MeV alpha-particles. The thick target yield is 0.3 mCi/μAh. The target is dissolved in concentrated N H 4 OH and 77 Br, separated from arsenic, by an anionic exchange resin, is obtained carrier-free with a separation yield greater than 90%. All the process is remotely controlled using electric and pneumatic systems, manipulators and tongs. The quality control is made by atomic absorption and gamma-ray spectroscopy. The present production rate of Br-77 is 2.3 mCi per irradiation. (author)

Pulse radiolysis of LiBr-KBr melts. Optical transient absorption spectra

International Nuclear Information System (INIS)

Sawamura, S.; Gebicki, J.L.; Mayer, J.; Kroh, J.

1990-01-01

Absorption spectra of the irradiated melts of LiBr and LiBr-KBr mixtures were investigated in the temperature range 673-873 K by nanosecond pulse radiolysis. The visible band ascribed to e s - shows the apparent shift towards longer wavelengths with increasing temperature and increasing content of KBr in the mixture. The UV transient absorption was attributed to superimposed Br 2 - and Br 3 - bands. The relation between the transition energy of visible band and the inverse mean ion distance is given for alkali bromide and chloride systems. (author)

Annual report 2005[International Atomic Energy Agency]; Informe anual 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-07-01

The Annual Report reviews the results of the Agency's programme according to the three 'pillars' of technology, safety and verification. The main part of the report, starting on page 13, generally follows the programme structure as it applied in 2005. The introductory chapter, 'The Year in Review', seeks to provide a thematic analysis, based on the three pillars, of the Agency's activities within the overall context of notable developments during the year. Information on specific issues can be found in the latest editions of the Agency's Nuclear Safety Review, Nuclear Technology Review and Technical Cooperation Report. For the convenience of readers, these documents are available on the CD-ROM attached to the inside back cover of this report. Additional information covering various aspects of the Agency's programme is also provided on the attached CD-ROM, and is also available on the Agency?s iaea.org web site (http://www.iaea.org/Worldatom/Documents/Anrep/Anrep2005/). All sums of money are expressed in United States dollars. The designations employed and the presentation of material in this document do not imply the expression of any opinion whatsoever on the part of the Secretariat concerning the legal status of any country or territory or of its authorities, or concerning the delimitation of its frontiers. The topics covered in the chapter related to Technology are: Nuclear Power; Nuclear Fuel Cycle and Materials Technologies; Capacity Building and Nuclear Knowledge Maintenance for Sustainable Energy Development; Nuclear Science; Food and Agriculture; Human Health; Water Resources; Protection of the Marine and Terrestrial Environment; Physical and Chemical Applications. Topics related to Safety and Security discussed in this report are: Safety of Nuclear Installations; Radiation and Transport Safety; Management of Radioactive Waste; Nuclear Security. Topics related to Verification are Safeguards and Verification in Iraq Pursuant to UNSC Resolutions. A separate

MORE. Management of Requirements in NPP modernisation projects - Project report 2005

International Nuclear Information System (INIS)

Thunem, A.P.J.; Fredriksen, R.; Thunem, H.P.J.; Ventae, O.; Valkonen, J.; Holmberg, J.E.

2006-04-01

The overall objective of the project MORE is to improve the means for managing the large amounts of evolving requirements in Nordic NPP modernisation projects. In accordance to this objective, the activity will facilitate the industrial utilisation of the research results from the project TACO. On the basis of experiences in the Nordic countries, the overall aim of the TACO project has been to identify the best practices and most important criteria for ensuring effective communication in relation to requirements elicitation and analysis, understandability of requirements to all parties, and traceability of requirements. The project resulted in the development of a traceability model for handling requirements from their origins and through their final shapes. Particular emphasis for the MORE project in 2005 was put on utilising a prototype of a tool (TRACE) intended to support an adopted approach to dependable requirements engineering, suitable for modelling and handling large amounts of requirements related to all stages of the systems development process and not only those traditionally including requirements at high-level stages. (au)

MORE. Management of Requirements in NPP modernisation projects - Project report 2005

Energy Technology Data Exchange (ETDEWEB)

Thunem, A.P.J.; Fredriksen, R.; Thunem, H.P.J. [IFE (Norway); Ventae, O.; Valkonen, J.; Holmberg, J.E. [VTT Technical Research Centre of Finland (Finland)

2006-04-15

The overall objective of the project MORE is to improve the means for managing the large amounts of evolving requirements in Nordic NPP modernisation projects. In accordance to this objective, the activity will facilitate the industrial utilisation of the research results from the project TACO. On the basis of experiences in the Nordic countries, the overall aim of the TACO project has been to identify the best practices and most important criteria for ensuring effective communication in relation to requirements elicitation and analysis, understandability of requirements to all parties, and traceability of requirements. The project resulted in the development of a traceability model for handling requirements from their origins and through their final shapes. Particular emphasis for the MORE project in 2005 was put on utilising a prototype of a tool (TRACE) intended to support an adopted approach to dependable requirements engineering, suitable for modelling and handling large amounts of requirements related to all stages of the systems development process and not only those traditionally including requirements at high-level stages. (au)

Energy- and temperature dependences of secondary electron emission of CsI- and CsBr layers doped with Cd

International Nuclear Information System (INIS)

Galij, P.V.; Tsal', N.A.

1983-01-01

The energy and temperature dependences of the secondary electron emission coefficient (SEEC) of CsI-Cd-, CsBr-Cd-, CsI-CsBr layers have been studied. The effect of bivalent cadmium impurity on the SEEC value is investigated. It is shown that implantation of small amounts of Cd 2+ impurity into the lattice of the initial monocrystals might increase the SEEC values of the layers. Temperature dependences (TD) of SEEC are measured and the possibility of comparing experimental results with the Dekker formula is analyzed. A conclusion is drawn that the Dekker model well describes the TD of SEEC of doped layers at temperatures T < or approximately 100 deg C. At elevated temperatures., along with secondary electron scattering on phonons, one should take into account their scattering on vacancies

Reference Projections Energy and Emissions 2005-2020

International Nuclear Information System (INIS)

Van Dril, A.W.N.; Elzenga, H.E.

2005-10-01

The Reference Projection 2005-2020 covers the future development of Dutch energy use, greenhouse gas emissions and air pollution up to 2020. The Reference projection is based on assumptions regarding economic, structural, technological and policy developments. Two scenarios have been used. The Strong Europe (SE) scenario is characterized by moderate economic growth and strong public responsibility. The Global Economy (GE) scenario assumes high economic growth and has a strong orientation towards private responsibility. Energy consumption continues to grow in both scenarios and energy intensity is declining in the GE-scenario. Gradual rise of temperature is now included in the estimates for space heating and air conditioning. Energy prices for end users will rise, due to increased imports of natural gas and rising costs of electricity generation. The share of renewables in electricity consumption increases considerably due to subsidies for wind at sea and biomass, up to the target of 9% in 2010. Emissions of non-CO2 greenhouse gases are reduced and stabilise after 2010. The Dutch Kyoto target is probably met in both scenarios, assuming considerable emission reduction ef-forts abroad. Acidifying emissions of NOx and SO2 stabilise after reductions, but at levels that exceed their national emission ceiling (NEC). Emissions of volatile organic compounds are projected to fall with approximately 25% between 2002 and 2010 below their NEC. Emissions of ammonia are projected to meet their NEC. The emission of particulate matter (PM10) will stabilise at present levels

Investigation of selenium compounds as targets for {sup 76,77}Br production using protons of energies up to 34 MeV

Energy Technology Data Exchange (ETDEWEB)

Hassan, H. Ebrahim [Atomic Energy Authority, Cairo (Egypt). Nuclear Research Centre; Forschungszentrum Juelich (Germany). Inst. fuer Neurowissenschaften und Medizin, INM-5: Nuklearchemie; El-Azony, Khaled M. [Atomic Energy Authority, Cairo (Egypt). Hot Labs. Centre; Azzam, Ahmed [Atomic Energy Authority, Cairo (Egypt). Nuclear Research Centre; Qaim, Syed M. [Forschungszentrum Juelich (Germany). Inst. fuer Neurowissenschaften und Medizin, INM-5: Nuklearchemie

2017-07-01

Selenium compounds of Zn, Sn and Cu were prepared using a conventional sintering method and the phase composition of each compound was investigated using X-ray diffraction. The compounds prepared were tested under variable irradiation and separation conditions for {sup 76,77}Br production. The activity of {sup 77}Br was measured as a function of proton beam current within the range 2-15 μA and the thermal stability of the irradiated compound was investigated. The results showed that the compounds ZnSe and Cu{sub 2}Se are thermally more stable in comparison to the SnSe. The effects of several factors, such as temperature, gas flow rate and separation time, were studied to obtain the maximum separation yield of radiobromine by the dry distillation method. The data showed that the compound Cu{sub 2}Se is the most suitable target for proton irradiation to produce {sup 76,77}Br at energies up to 20 MeV. A simplified method was used to prepare also CuSe, which was tested in irradiations with intermediate energy protons of beam currents up to 10 μA. The data of a typical production run using 17 MeV protons and the Cu{sub 2}Se target are reported.

BRIEF COMMUNICATIONS: Optically pumped ultraviolet BR2 laser

Science.gov (United States)

Kamrukov, A. S.; Kozlov, N. P.; Protasov, Yu S.; Ushmarov, E. Yu

1989-12-01

A report is given of lasing achieved for the first time in optically pumped molecular bromine (D' 3Π2g→A' 3π2u, λL approx 292 nm). It was pumped by thermal vacuum ultraviolet radiation emitted by plasmadynamic discharges of magnetoplasma compressors, formed directly in the laser active medium. An output energy of ~ 1.1 J was obtained per laser pulse of ~ 5-μs duration from a Br2:Ar approx 1:450 active mixture at a pressure of ~ 4 atm. A comparison was made of the experimental output parameters of optically pumped Br2, I2, and XeF (B-X) lasers when their geometries and excitation energies were identical.

Flg22-Triggered Immunity Negatively Regulates Key BR Biosynthetic Genes.

Science.gov (United States)

Jiménez-Góngora, Tamara; Kim, Seong-Ki; Lozano-Durán, Rosa; Zipfel, Cyril

2015-01-01

In plants, activation of growth and activation of immunity are opposing processes that define a trade-off. In the past few years, the growth-promoting hormones brassinosteroids (BR) have emerged as negative regulators of pathogen-associated molecular pattern (PAMP)-triggered immunity (PTI), promoting growth at the expense of defense. The crosstalk between BR and PTI signaling was described as negative and unidirectional, since activation of PTI does not affect several analyzed steps in the BR signaling pathway. In this work, we describe that activation of PTI by the bacterial PAMP flg22 results in the reduced expression of BR biosynthetic genes. This effect does not require BR perception or signaling, and occurs within 15 min of flg22 treatment. Since the described PTI-induced repression of gene expression may result in a reduction in BR biosynthesis, the crosstalk between PTI and BR could actually be negative and bidirectional, a possibility that should be taken into account when considering the interaction between these two pathways.

Swiss electricity statistics 2005

International Nuclear Information System (INIS)

2006-01-01

This comprehensive report made by the Swiss Federal Office of Energy (SFOE) presents the statistics for 2005 on electricity production and usage in Switzerland for the year 2005. First of all, an overview of Switzerland's electricity supply in 2005 is presented. Details are noted of the proportions generated by different sources including nuclear, hydro-power, storage schemes and thermal power stations as well as energy transfer with neighbouring countries. A second chapter takes a look at the balance of imports and exports with illustrative flow diagrams along with tables for total figures from 1950 through to 2005. For the summer and winter periods, figures from 1995 to 2005 are presented. The third chapter examines the production of electricity in the various types of power stations and the developments over the years 1950 to 2005, whereby, for example, statistics on regional generation and power station type are looked at. The fourth chapter looks at electricity consumption in various sectors from 1983 to 2005 and compares the figures with international data. The fifth chapter looks at generation, consumption and loading on particular days and chapter six considers energy exchange with Switzerland's neighbours. Chapter seven takes a look at possibilities for extending generation facilities in the period up to 2012

PSI Scientific Report 2005. Volume 3: Energy and Environment

Energy Technology Data Exchange (ETDEWEB)

Schlaepfer-Miller, J; Gerber, B [eds.

2006-04-15

The overarching goal of energy research at PSI is to provide scientific nd technical solutions for the development of cost-effective, reliable, socially acceptable and environmentally sustainable energy. his research is done within two departments: General Energy and nuclear Energy and Safety, their research highlights from 2005 are documented in the following chapter. Major accomplishments of the past year include: a pioneer solar power-plant; improvements in catalysts and processes for the production of methane from wood; development of characterization tools to improve combustion processes; fuel cells, and batteries under operating conditions; carbon dioxide in forests; and a new dating method for glacial ice. Progress was made in determining the suitability of opalinus clay to store radioactive waste and how iodine exposure could be reduced under normal operation and in the event of a severe accident at a nuclear power-plant. Systems analysis research also included a report on the external environmental costs of electricity and whether the Swiss population are willing to pay for renewable energy. This report only highlights a selection of the work done at PSI in the past year; information about many other ongoing projects can be accessed through our website, (www.psi.ch). (author)

PSI Scientific Report 2005. Volume 3: Energy and Environment

International Nuclear Information System (INIS)

Schlaepfer-Miller, J.; Gerber, B.

2006-04-01

The overarching goal of energy research at PSI is to provide scientific nd technical solutions for the development of cost-effective, reliable, socially acceptable and environmentally sustainable energy. his research is done within two departments: General Energy and nuclear Energy and Safety, their research highlights from 2005 are documented in the following chapter. Major accomplishments of the past year include: a pioneer solar power-plant; improvements in catalysts and processes for the production of methane from wood; development of characterization tools to improve combustion processes; fuel cells, and batteries under operating conditions; carbon dioxide in forests; and a new dating method for glacial ice. Progress was made in determining the suitability of opalinus clay to store radioactive waste and how iodine exposure could be reduced under normal operation and in the event of a severe accident at a nuclear power-plant. Systems analysis research also included a report on the external environmental costs of electricity and whether the Swiss population are willing to pay for renewable energy. This report only highlights a selection of the work done at PSI in the past year; information about many other ongoing projects can be accessed through our website, (www.psi.ch). (author)

Die Interhalogenkationen [Br2F5]+ und [Br3F8].

Science.gov (United States)

Ivlev, Sergei; Karttunen, Antti; Buchner, Magnus; Conrad, Matthias; Kraus, Florian

2018-05-02

Wir berichten über die Synthese und Charakterisierung der bislang einzigen Polyhalogenkationen, in denen verbrückende Fluoratome vorliegen. Das [Br2F5]+-Kation enthält eine symmetrische [F2Br-µ-F-BrF2]-Brücke, das [Br3F8]+-Kation enthält unsymmetrische µ-F-Brücken. Die Fluoronium-Ionen wurden in Form ihrer [SbF6]--Salze erhalten und Raman-, und 19F-NMR-spektroskopisch, sowie durch Röntgenbeugung am Einkristall untersucht. Quantenchemische Rechnungen, sowohl für die isolierten Kationen in der Gasphase, als auch für die Festkörper selbst, wurden durchgeführt. Populationsanalysen zeigen, dass die µ-F-Atome die am stärksten negativ partialgeladenen Atome der Kationen sind. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

CERN Technical Training 2005 - ELEC-2005: Electronics in High Energy Physics

CERN Multimedia

Monique Duval

2004-01-01

Learning for the LHC!ELEC-2005 is a new course series on modern electronics, given by CERN physicists and engineers within the framework of the 2005 Technical Training Programme, in an extended format of the successful ELEC-2002 course series. This comprehensive course series is designed for people who are not electronics specialists, for example physicists, engineers and technicians working at or visiting the laboratory, who use or will use electronics in their present or future activities, in particular in the context of the LHC accelerator and experiments.ELEC-2005 is composed of four Terms that will run throughout the year:Winter Term: Introduction to electronics in HEP (January-February, 6 lectures) Spring Term: Integrated circuits and VLSI technology for physics (March, 6 lectures) Summer Term: System electronics for physics: Issues (May, 7 lectures) Winter Term: Electronics applications in HEP experiments (November-December, 10 lectures) Lectures within each Term will take place on Tuesdays and Thursd...

Cage-Like Porous Carbon with Superhigh Activity and Br2 -Complex-Entrapping Capability for Bromine-Based Flow Batteries.

Science.gov (United States)

Wang, Chenhui; Lai, Qinzhi; Xu, Pengcheng; Zheng, Daoyuan; Li, Xianfeng; Zhang, Huamin

2017-06-01

Bromine-based flow batteries receive wide attention in large-scale energy storage because of their attractive features, such as high energy density and low cost. However, the Br 2 diffusion and relatively low activity of Br 2 /Br - hinder their further application. Herein, a cage-like porous carbon (CPC) with specific pore structure combining superhigh activity and Br 2 -complex-entrapping capability is designed and fabricated. According to the results of density functional theory (DFT) calculation, the pore size of the CPC (1.1 nm) is well designed between the size of Br - (4.83 Å), MEP + (9.25 Å), and Br 2 complex (MEPBr 3 12.40 Å), wherein Br - is oxidized to Br 2 , which forms a Br 2 complex with the complexing agent immediately and is then entrapped in the cage via pore size exclusion. In addition, the active sites produced during the carbon dioxide activation process dramatically accelerate the reaction rate of Br 2 /Br - . In this way, combining a high Br 2 -entrapping-capability and high specific surface areas, the CPC shows very impressive performance. The zinc bromine flow battery assembled with the prepared CPC shows a Coulombic efficiency of 98% and an energy efficiency of 81% at the current density of 80 mA cm -2 , which are among the highest values ever reported. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

CH3 NH3 PbBr3 Perovskite Nanocrystals as Efficient Light-Harvesting Antenna for Fluorescence Resonance Energy Transfer.

Science.gov (United States)

Muthu, Chinnadurai; Vijayan, Anuja; Nair, Vijayakumar C

2017-05-04

Hybrid perovskites have created enormous research interest as a low-cost material for high-performance photovoltaic devices, light-emitting diodes, photodetectors, memory devices and sensors. Perovskite materials in nanocrystal form that display intense luminescence due to the quantum confinement effect were found to be particularly suitable for most of these applications. However, the potential use of perovskite nanocrystals as a light-harvesting antenna for possible applications in artificial photosynthesis systems is not yet explored. In the present work, we study the light-harvesting antenna properties of luminescent methylammonium lead bromide (CH 3 NH 3 PbBr 3 )-based perovskite nanocrystals using fluorescent dyes (rhodamine B, rhodamine 101, and nile red) as energy acceptors. Our studies revealed that CH 3 NH 3 PbBr 3 nanocrystals are an excellent light-harvesting antenna, and efficient fluorescence resonance energy transfer occurs from the nanocrystals to fluorescent dyes. Further, the energy transfer efficiency is found to be highly dependent on the number of anchoring groups and binding ability of the dyes to the surface of the nanocrystals. These observations may have significant implications for perovskite-based light-harvesting devices and their possible use in artificial photosynthesis systems. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Tuning growth cycles of Brassica crops via natural antisense transcripts of BrFLC.

Science.gov (United States)

Li, Xiaorong; Zhang, Shaofeng; Bai, Jinjuan; He, Yuke

2016-03-01

Several oilseed and vegetable crops of Brassica are biennials that require a prolonged winter cold for flowering, a process called vernalization. FLOWERING LOCUS C (FLC) is a central repressor of flowering. Here, we report that the overexpression of natural antisense transcripts (NATs) of Brassica rapa FLC (BrFLC) greatly shortens plant growth cycles. In rapid-, medium- and slow-cycling crop types, there are four copies of the BrFLC genes, which show extensive variation in sequences and expression levels. In Bre, a biennial crop type that requires vernalization, five NATs derived from the BrFLC2 locus are rapidly induced under cold conditions, while all four BrFLC genes are gradually down-regulated. The transgenic Bre lines overexpressing a long NAT of BrFLC2 do not require vernalization, resulting in a gradient of shortened growth cycles. Among them, a subset of lines both flower and set seeds as early as Yellow sarson, an annual crop type in which all four BrFLC genes have non-sense mutations and are nonfunctional in flowering repression. Our results demonstrate that the growth cycles of biennial crops of Brassica can be altered by changing the expression levels of BrFLC2 NATs. Thus, BrFLC2 NATs and their transgenic lines are useful for the genetic manipulation of crop growth cycles. © 2015 Society for Experimental Biology, Association of Applied Biologists and John Wiley & Sons Ltd.

Intrinsic Lead Ion Emissions in Zero-Dimensional Cs4PbBr6 Nanocrystals

KAUST Repository

Yin, Jun

2017-11-07

We investigate the intrinsic lead ion (Pb2+) emissions in zero-dimensional (0D) perovskite nanocrystals (NCs) using a combination of experimental and theoretical approaches. The temperature-dependent photoluminescence experiments for both “nonemissive” (highly suppressed green emission) and emissive (bright green emission) Cs4PbBr6 NCs show a splitting of emission spectra into high- and low-energy transitions in the ultraviolet (UV) spectral range. In the nonemissive case, we attribute the high-energy UV emission at approximately 350 nm to the allowed optical transition of 3P1 to 1S0 in Pb2+ ions and the low-energy UV emission at approximately 400 nm to the charge-transfer state involved in the 0D NC host lattice (D-state). In the emissive Cs4PbBr6 NCs, in addition to the broad UV emission, we demonstrate that energy transfer occurs from Pb2+ ions to green luminescent centers. The optical phonon modes in Cs4PbBr6 NCs can be assigned to both Pb–Br stretching and rocking motions from density functional theory calculations. Our results address the origin of the dual broadband Pb2+ ion emissions observed in Cs4PbBr6 NCs and provide insights into the mechanism of ionic exciton–optical phonon interactions in these 0D perovskites.

Imaging the Dynamics of CH2BrI Photodissociation in the Near Ultraviolet Region.

Science.gov (United States)

Pan, Changen; Zhang, Yi; Lee, Joseph D; Kidwell, Nathanael M

2018-04-19

The photodissociation dynamics of jet-cooled CH 2 BrI were investigated in the near-ultraviolet (UV) region from 280-310 nm using velocity map imaging. We report the translational and internal energy distributions of the CH 2 Br radical and ground state I ( 2 P 3/2 ) or spin-orbit excited I ( 2 P 1/2 ) fragments determined by velocity map imaging of the ionized iodine fragments following 2 + 1 resonance-enhanced multiphoton ionization of the nascent neutral iodine products. The velocity distributions indicate that most of the available energy is partitioned into the internal energy of the CH 2 Br radical with only modest translational excitation imparted to the cofragments, which is consistent with a simple impulsive model. Furthermore, from extrapolation of the velocity distribution results, the first determination of the C-I bond dissociation energy of CH 2 BrI is presented in this work to be D 0 = 16 790 ± 590 cm -1 . The ion images appear anisotropic, indicative of a prompt dissociation, and the derived anisotropy parameters are consistently positive. Additionally, the angular distributions report on the electronic excited state dynamics, which validate recent works characterizing the electronic states responsible for the first absorption band of CH 2 BrI. In the current work, photolysis of CH 2 BrI on the red edge of the absorption spectrum reveals an additional channel producing I ( 2 P 3/2 ) fragments.

Slovak Republic - energy policy review 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-07-01

Slovakia has implemented impressive energy reforms over the recent past, a unique performance in Central and Eastern Europe. The 2000 energy policy prioritised market reforms and sectoral policies, notably on energy security and environment, in order to comply with EU requirements, which were largely met at the time of the country's EU accession in 2004. Also, Slovakia established new regulations, notably cost reflective pricing enforced by an independent energy regulator, thereby attracting significant foreign direct investment. Notably, this rapid transition has occurred without disruption in this key energy transit country. New challenges ahead include strengthening energy security by diversification, opening energy markets and integrating them into the EU, strongly increasing energy efficiency to offset the high economic burden of energy prices and to help better controlling pollution and CO{sub 2} emissions in line with EU and international obligations. This review analyses the Slovak energy sector and policies, and provides recommendations for the government. It is a comprehensive assessment of what constitutes a remarkable case study of effective energy reforms in an economy in transition, which has applied for IEA membership. 39 refs., 32 tabs., 4 apps.

Rate constant for the reaction SO + BrO yields SO2 + Br

Science.gov (United States)

Brunning, J.; Stief, L.

1986-01-01

The rate of the radical-radical reaction SO + BrO yields SO2 + Br has been determined at 298 K in a discharge flow system near 1 torr pressure with detection of SO and BrO via collision-free sampling mass spectrometry. The rate constant was determined using two different methods: measuring the decay of SO radicals in the presence of an excess of BrO and measuring the decay of BrO radicals in excess SO. The results from the two methods are in reasonable agreement and the simple mean of the two values gives the recommended rate constant at 298 K, k = (5.7 + or - 2.0) x 10 to the -11th cu cm/s. This represents the first determination of this rate constant and it is consistent with a previously derived lower limit based on SO2 formation. Comparison is made with other radical-radical reactions involving SO or BrO. The reaction SO + BrO yields SO2 + Br is of interest for models of the upper atmosphere of the earth and provides a potential coupling between atmospheric sulfur and bromine chemistry.

Annual Site Environmental Report: 2005

Energy Technology Data Exchange (ETDEWEB)

sabba, d

2007-02-03

This report provides information about environmental programs during 2005 at the Stanford Linear Accelerator Center (SLAC). Seasonal activities that span calendar years are also included. Production of an annual site environmental report (ASER) is a requirement established by the United States Department of Energy (DOE) for all management and operating (M&O) contractors throughout the DOE complex. SLAC is a federally-funded research and development center with Stanford University as the M&O contractor. SLAC effectively applied environmental management in meeting the site's integrated safety and environmental management system (ISEMS) goals. For normal daily activities, all SLAC managers and supervisors are responsible for ensuring that proper procedures are followed so that: (1) Worker safety and health are protected; (2) The environment is protected; and (3) Compliance is ensured. Throughout 2005, SLAC focused on these activities through the SLAC management systems (described in Chapter 3). These systems were also the way SLAC approached implementing ''greening of the government'' initiatives such as Executive Order 13148. The management systems at SLAC are effective, supporting compliance with all relevant statutory and regulatory requirements. There were no reportable releases to the environment from SLAC operations during 2005. In addition, many improvements were continued during 2005, in waste minimization, recycling, stormwater drain system, groundwater restoration, and implementing a chemical management system (CMS) to better manage chemical use. Program-specific details are discussed.

Origin of the Substitution Mechanism for the Binding of Organic Ligands on the Surface of CsPbBr3 Perovskite Nanocubes.

Science.gov (United States)

Ravi, Vikash Kumar; Santra, Pralay K; Joshi, Niharika; Chugh, Jeetender; Singh, Sachin Kumar; Rensmo, Håkan; Ghosh, Prasenjit; Nag, Angshuman

2017-10-19

Optoelectronic properties of CsPbBr 3 perovskite nanocubes (NCs) depend strongly on the interaction of the organic passivating molecules with the inorganic crystal. To understand this interaction, we employed a combination of synchrotron-based X-ray photoelectron spectroscopy (XPS), nuclear magnetic resonance (NMR) spectroscopy, and first-principles density functional theory (DFT)-based calculations. Variable energy XPS elucidated the internal structure of the inorganic part in a layer-by-layer fashion, whereas NMR characterized the organic ligands. Our experimental results confirm that oleylammonium ions act as capping ligands by substituting Cs + ions from the surface of CsPbBr 3 NCs. DFT calculations shows that the substitution mechanism does not require much energy for surface reconstruction and, in contrast, stabilizes the nanocrystal by the formation of three hydrogen bonds between the -NH 3 + moiety of oleylammonium and surrounding Br - on the surface of NCs. This substitution mechanism and its origin are in stark contrast to the usual adsorption of organic ligands on the surface of typical NCs.

Collision energy-resolved study of the emission cross-section and the Penning ionization cross-section in the reaction of BrCN with He*(2 3S)

Science.gov (United States)

Kanda, Kazuhiro; Yamakita, Yoshihiro; Ohno, Koichi

2001-12-01

The dissociative excitation of BrCN producing CN(B 2Σ +) fragment by the collision of He *(2 3S) was investigated by the collision energy-resolved electron and emission spectroscopy using time-of-flight method with a high-intensity He * beam. The Penning electrons ejected from BrCN and the subsequent CN ( B2Σ +- X2Σ +) emission were measured as a function of collision energy in the range of 90-180 meV. The formation of CN ( B2Σ +) is concluded to proceed dominantly via the promotion of an electron from Π-character orbital, by comparison between the collision energy dependence of the partial Penning ionization cross-sections and the CN ( B2Σ +- X2Σ +) emission cross-section.

Light-emitting diodes based on two-dimensional PA2(CsPbBr3)n-1PbBr4 layered perovskites%基于PA2(CsPbBr3)n-1PbBr4二维层状钙钛矿的电致发光二极管

Institute of Scientific and Technical Information of China (English)

孟妍; 牛连斌; 许龙; 林春燕; 熊自阳; 熊祖洪; 陈平

2018-01-01

remains a major concern.To circumvent this problem,all-inorganic halide perovskites exhibiting higher thermal and chemical stability,such as cesium lead bromide (CsPbBr3),have been used as alternative emitters in PeLED.Despite the advantages described above,both the brightness and the EQE of CsPbBr3-based PeLED remain limited.One important reason for low efficiency of CsPbBr3-based PeLED is the facile dissociation of excitons in 3D perovskites due to their small exciton binding energy.One promising way to enhance the exciton binding energy is reducing the grain size of perovskites.Herein,we report a solution process to form highly uniform and ultra-fiat perovskite films with nanometre-sized grains that allow us to demonstrate efficient PeLED.By mixing long-chain ammonium halides of CH3CH2CH2NH3Br (PABr) with the 3D CsPbBr3 perovskite precursor solution,the growth of 3D perovskite grains are dramatically impeded and the PA2(CsPbBr3)n-1PbBr4 quantum dots with grain size of ～100 nm were achieved.This is because the long-chain ammonium ions cannot fill the comer of PbBr4 octahedral layers and therefore impedes the 3D perovskite formation.Moreover,the nanometre-sized grains feature reduced dimensionality,starting a transition from 3D to 2D layered (so-called Ruddlesden-Popper phase) perovskite structures.The SEM image show the morphology of PA2(CsPbBr3)n-1PbBr4 layer was dense and uniform,which is very important to suppress the leaking current in the PeLED.We found that PA2(CsPbBr3)n-1PbBr4 film mainly consists of two different 2D structures,namely PA2PbBr4 (n=l) and PA2(CsPbBr3)PbBr4 (n=2),according to the analysis of XRD pattern.Compared to the single UVs absorption peak of CsPbBr3 at ～520 nm,PA2(CsPbBr3)n-1PbBr4 film show multiple absorption peaks,indicating several extonic states are formed upon light excitation.Although several extonic states exist,photoluminescence (PL) with only one peak of 506 nm was observed in PA2(CsPbBr3)n-1PbBr4 film.We suspect that the energy

The calculation of some gamma shielding parameters for semiconductor CsPbBr3

Science.gov (United States)

Oto, Berna; Gulebaglan, Sinem Erden; Kanberoglu, Gulsah Saydan

2017-02-01

Recently, researchers produced perovskites structures used in optoelectronic devices as substrates, sensors. CsPbBr3 crystal is found in the cubic perovskite structure and its space group is Pm-3m. CsPbBr3 is a developing material for detection of X- and γ-ray radiations and the knowledge of the attenuation parameters of CsPbBr3 crystal is important. In this study, some photon shielding parameters such as mass attenuation coefficient (μρ), effective atomic number (Zeff) and electron density (Nel) have been investigated for CsPbBr3 compound. The theoretical values of μρ have been calculated in the energy range from 1 keV to 100 GeV using WinXCom computer code and these values have been used in order to calculate the values of Zeff and Nel in the same energy range.

Angular correlation for gamma-gamma transitions in 81Br and 83Br nuclei

International Nuclear Information System (INIS)

Matheus, R.

1984-01-01

The directional angular correlation of coincident gamma transitions in 81 Br and 83 Br have been measured following the β - decay of 81 Se(T sub(1/2) = 18.6 min) and 83 Se(T sub(1/2) = 22.6 min) respectively, using Ge(Li) - high purity Ge and Ge(Li)-NaI(Tl) spectrometers. The radioactive sources were prepared by irradiating with neutrons in the IEA-R1 reactor, metallic selenium (natural) to produce 81 Se and samples of metallic selenium enriched (to approx. 90% in 82 Se) to produce 83 Se. Measurements have been carried out for the gamma cascades 260-276 KeV, 290-276 KeV and 552-276 KeV in 81 Br and the gamma cascades 225(510)-356 KeV, 510-356 KeV, 572-(510)-356 KeV, 718-(225)-(510)-356 KeV, 1064-356 KeV, 718-225 KeV, 718-(225)-510 KeV, 836-718 KeV, 718-(225)-866 KeV, 883-718 KeV and 1895-799 KeV in 83 Br. The multipole mixing ratios, σ(E2/M1), were determined for 3 gamma transitions in 81 Br and 11 gamma transitions in 83 Br. In the case of 81 Br present results confirmed some of the earlier results. The spin and parity assignment were made to the majority of levels in 81 Br and 83 Br involved in the present study, some of them confirming the earlier results. A comparison of some of the nuclear properties of the 79 Br, 81 Br and 83 Br is made based on the available experimental data. The experimental results are also discussed qualitatively in terms of some nuclear models applicable for the description of the properties of odd-A bromine isotopes. (Author) [pt

Commercial and institutional consumption of energy survey : summary report 2005

Energy Technology Data Exchange (ETDEWEB)

Fecteau, V.; Hulan, I.; McNabb, D. [Natural Resources Canada, Ottawa, ON (Canada). Office of Energy Efficiency

2007-06-15

A survey was conducted on the energy consumption of Canada's commercial and institutional sectors. The primary purpose was to improve the understanding of various aspects of energy consumption in these sector and to enable Natural Resources Canada to develop programs to support institutions that seek to achieve greater energy efficiency and reduce their greenhouse gas emissions. Energy intensity data was presented by energy source and region amongst the following commercial and institutional sectors: retail trade including food and non-food; education including colleges and universities; health care including non-hospital health care and hospitals; and, accommodation and food services. Data obtained on each establishment's energy consumption and floor area were used to calculate their energy intensity ratio. In 2005, the commercial and institutional establishments consumed 1.04 billion gigajoules, nearly double the annual consumption of all private households in Ontario. The total energy intensity was 1.54 GJ per square metre. The lowest energy rating was found in social assistance establishments, while the highest energy rating was in food services and drinking places, followed by hospitals. Quebec and the Atlantic provinces had the lowest energy intensity levels, while the Prairie provinces had the highest energy intensity rate. The survey included data on the age of establishments; the energy sources used for space heating cooling and water heating; establishment spending on energy consumption; and, the use of auxiliary equipment. refs., tabs., figs.

Optical properties of Pb-based aggregated phases in CsBr crystal

Energy Technology Data Exchange (ETDEWEB)

Voloshinovskii, A. [Ivan Franko National University of Lviv, 8 Kyryla i Mefodiya Str., 79005 Lviv (Ukraine); Myagkota, S. [Ivan Franko National University of Lviv, 8 Kyryla i Mefodiya Str., 79005 Lviv (Ukraine); Garapyn, I. [Ivan Franko National University of Lviv, 8 Kyryla i Mefodiya Str., 79005 Lviv (Ukraine); Stryganyuk, G. [Ivan Franko National University of Lviv, 8 Kyryla i Mefodiya Str., 79005 Lviv (Ukraine); Rodnyi, P. [St. Petersburg State Polytechnical University, 29 Polyteknicheskaya Str., 195251 St. Petersburg (Russian Federation); Eijk, C.W.E. van [Interfaculty Reactor Institute, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands)]. E-mail: vaneijk@iri.tudelft.nl

2005-01-01

The emission and excitation spectra as well as luminescence decay kinetics of a CsBr:Pb (1.0mol%) crystal have been measured under pulsed synchrotron radiation excitation. The heat-treated ({approx}200 deg. C) crystal shows evidence of single lead centres and aggregated phases such as CsPbBr3 nanocrystals. The latter have been identified from comparison of the spectral-kinetic characteristics of the CsPbBr3 aggregated phases and single crystals. The process of energy transfer from the host to the aggregates is considered.

Optical properties of Pb-based aggregated phases in CsBr crystal

International Nuclear Information System (INIS)

Voloshinovskii, A.; Myagkota, S.; Garapyn, I.; Stryganyuk, G.; Rodnyi, P.; Eijk, C.W.E. van

2005-01-01

The emission and excitation spectra as well as luminescence decay kinetics of a CsBr:Pb (1.0mol%) crystal have been measured under pulsed synchrotron radiation excitation. The heat-treated (∼200 deg. C) crystal shows evidence of single lead centres and aggregated phases such as CsPbBr3 nanocrystals. The latter have been identified from comparison of the spectral-kinetic characteristics of the CsPbBr3 aggregated phases and single crystals. The process of energy transfer from the host to the aggregates is considered

$^{80}$Br $^{80}$Br-a new electron-gamma PAC probe

CERN Document Server

Correia, J G; Araújo, J P; Marques, J G; Soares, J C; Melo, A A

2001-01-01

Conversion electron-gamma PAC measurements of the 49-37 keV cascade in /sup 80/Br through the intermediate 2/sup -/ state with T/sub 1/2 /=7.4 ns were performed with a system of two magnetic lens spectrometers and two BaF/sub 2/ scintillation detectors. The parent /sup 80m/Br activity with a halflife of 4.4 hrs was implanted into Ni, Zn and graphite at the ISOLDE separator at CERN. The observed interaction frequency in the nickel matrix is in good agreement with the known value of the hyperfine field for Br in Ni and the magnetic moment of the 2/sup -/ state. From the measured quadrupole interaction in Zn and graphite the electric field gradients at Br were obtained. (7 refs).

Preparation of 80Br or 82Br-biomolecules via excitation labelling methods

International Nuclear Information System (INIS)

Wong, S.; Ache, H.J.

1975-01-01

The direct decay-induced 82 Br (or 80 Br) labelling by exposing the solid substrate molecules, such as deoxyuridine, L-tyrosine, guanosine, deoxycytidine, phenylalanine, and acetic acid, to gaseous CF 3 82 /sup m/Br (or CF 3 80 /sup m/Br) was studied. The radiochemical yields of the brominated products are relatively small and range from 1 percent in the case of bromo deoxyuridine to 11 percent for bromoacetic acid. The modification of this technique by adding Cl 2 gas to the reaction mixture improves the yields in several cases drastically (up to 80 percent for bromo-guanosine and bromo-L-tyrosine). Similar improvement can be achieved by exposing crystalline KBrO 3 for some time to CF 3 82 /sup m/Br (or CF 3 80 /sup m/Br) and dissolving subsequently the KBrO 3 in an acidic solution of the substrate. (auth)

Nonadiabatic effects in C-Br bond scission in the photodissociation of bromoacetyl chloride

International Nuclear Information System (INIS)

Valero, Rosendo; Truhlar, Donald G.

2006-01-01

Bromoacetyl chloride photodissociation has been interpreted as a paradigmatic example of a process in which nonadiabatic effects play a major role. In molecular beam experiments by Butler and co-workers [J. Chem. Phys. 95, 3848 (1991); J. Chem. Phys. 97, 355 (1992)], BrCH 2 C(O)Cl was prepared in its ground electronic state (S 0 ) and excited with a laser at 248 nm to its first excited singlet state (S 1 ). The two main ensuing photoreactions are the ruptures of the C-Cl bond and of the C-Br bond. A nonadiabatic model was proposed in which the C-Br scission is strongly suppressed due to nonadiabatic recrossing at the barrier formed by the avoided crossing between the S 1 and S 2 states. Recent reduced-dimensional dynamical studies lend support to this model. However, another interpretation that has been given for the experimental results is that the reduced probability of C-Br scission is a consequence of incomplete intramolecular energy redistribution. To provide further insight into this problem, we have studied the energetically lowest six singlet electronic states of bromoacetyl chloride by using an ab initio multiconfigurational perturbative electronic structure method. Stationary points (minima and saddle points) and minimum energy paths have been characterized on the S 0 and S 1 potential energy surfaces. The fourfold way diabatization method has been applied to transform five adiabatic excited electronic states to a diabatic representation. The diabatic potential energy matrix of the first five excited singlet states has been constructed along several cuts of the potential energy hypersurfaces. The thermochemistry of the photodissociation reactions and a comparison with experimental translational energy distributions strongly suggest that nonadiabatic effects dominate the C-Br scission, but that the reaction proceeds along the energetically allowed diabatic pathway to excited-state products instead of being nonadiabatically suppressed. This conclusion is

Study on effects of gamma-ray irradiation on TlBr semiconductor detectors

International Nuclear Information System (INIS)

Matsumura, Motohiro; Watanabe, Kenichi; Yamazaki, Atsushi; Uritani, Akira; Kimura, Norihisa; Nagano, Nobumichi; Hitomi, Keitaro

2016-01-01

Radiation hardness of thallium bromide (TlBr) semiconductor detectors to 60 Co gamma-ray irradiation was evaluated. The energy spectra and μτ products of electrons were measured to evaluate the irradiation effects. No significant degradation of spectroscopic performance of the TlBr detector for 137 Cs gamma-rays was observed up to 45 kGy irradiation. Although the μτ products of electrons in the TlBr detector slightly decreased, position of the photo-peak was stable without significant degradation after the gamma-ray irradiation. We confirmed that the TlBr semiconductor detector has a high tolerance for gamma-ray irradiation at least up to 45 kGy. (author)

ELEC-2005 - Electronics in High Energy Physics: Autumn Term (November-December 2005)

CERN Multimedia

Davide Vitè

2005-01-01

ELEC-2005 is a new course series on modern electronics, given by CERN physicists and engineers within the framework of the 2005 Technical Training Programme, in an extended format of the ELEC-2002 course series. This new, comprehensive course series is designed for people who are not electronics specialists, for example physicists, engineers and technicians working at or visiting the laboratory, who use or will use electronics in their present or future activities, in particular in the context of the LHC accelerator and experiments. ELEC-2005 is composed of four Terms. The Winter (Introduction to electronics in HEP), Spring (Integrated circuits and VLSI technology for physics), and Summer (System electronics for physics: Issues) Terms already took place. The Autumn Term - Electronics applications in HEP experiments (November-December, 10 lectures) is still open for registration, and has started on November 8th with the following programme: Tuesday 8.11 - Tracking (Geoff Hall). Thursday 10.11 - Calorimetr...

Maintaining and assessing extended 9 test methods in accordance with ISO/IEC 17025: 2005 for Isotopes Hydrology Laboratory

International Nuclear Information System (INIS)

Nguyen Thi Hong Thinh; Ha Lan Anh; Vo Thi Anh; Tran Khanh Minh; Vu Hoai

2016-01-01

The ISO/IEC 17025:2005 ''General requirements for the competence of testing and calibration laboratories'' is basis for the accreditation body of the country in general and VILAS in particular recognizing the competence of laboratories. With the desire to prove that we have sufficient technique and management capacity , and the ability to provide the legally recognized and technically valuable test results, the Isotope Hydrology Laboratory have developed and maintain a quality management system in accordance with ISO/IEC 17025:2005. In 2013, Isotope Hydrology Laboratory received a certificate of accreditation issued by Bureau of Accreditation which recognized the laboratory in accordance with ISO/IEC 17025:2005 with VILAS 670 accredited code. Scope of recognition is analyzed 14 parameters: F"-, Cl"-, NO_2"-, NO_3"-, Br"-, PO_4"3"-, SO_4"2"-, Li"+, Na"+, NH_4"+, K"+, Mg"2"+, Ca"2"+ and "3H in water by ion chromatography and liquid scintillator counting method. The laboratory has successfully implemented the task of maintaining quality management systems conform to ISO/IEC 17025: 2005 and expanded the scope of accreditation by 9 parameters in water: pH, EC, TSS, TDS, DO, BOD5, pH, Fe and Mn in 2015. (author)

Electronic structure of the CsPbBr3/polytriarylamine (PTAA) system

Science.gov (United States)

Endres, James; Kulbak, Michael; Zhao, Lianfeng; Rand, Barry P.; Cahen, David; Hodes, Gary; Kahn, Antoine

2017-01-01

The inorganic lead halide perovskite CsPbBr3 promises similar solar cell efficiency to its hybrid organic-inorganic counterpart CH3NH3PbBr3 but shows greater stability. Here, we exploit this stability for the study of band alignment between perovskites and carrier selective interlayers. Using ultraviolet, X-ray, and inverse photoemission spectroscopies, we measure the ionization energy and electron affinities of CsPbBr3 and the hole transport polymer polytriarylamine (PTAA). We find that undoped PTAA introduces a barrier to hole extraction of 0.2-0.5 eV, due to band bending in the PTAA and/or a dipole at the interface. p-doping the PTAA eliminates this barrier, raising PTAA's highest occupied molecular orbital to 0.2 eV above the CsPbBr3 valence band maximum and improving hole transport. However, IPES reveals the presence of states below the PTAA lowest unoccupied molecular level. If present at the CsPbBr3/PTAA interface, these states may limit the polymer's efficacy at blocking electrons in solar cells with wide band gap materials like CsPbBr3 and CH3NH3PbBr3.

Transient photoelectron spectroscopy of the dissociative Br2(1Piu) state.

Science.gov (United States)

Strasser, Daniel; Goulay, Fabien; Leone, Stephen R

2007-11-14

Photodissociation of bromine on the Br2(1Piu) state is probed with ultrafast extreme ultraviolet (53.7 nm) single-photon ionization. Time-resolved photoelectron spectra show simultaneously the depletion of ground state bromine molecules as well as the rise of Br(2P3/2) products due to 402.5 nm photolysis. A partial photoionization cross-section ratio of atomic versus molecular bromine is obtained. Transient photoelectron spectra of a dissociative wave packet on the excited state are presented in the limit of low-power-density, single-photon excitation to the dissociative state. Transient binding energy shifts of "atomic-like" photoelectron peaks are observed and interpreted as photoionization of nearly separated Br atom pairs on the Br2(1Piu) state to repulsive dissociative ionization states.

Energetic Diagrams and Structural Properties of Monohaloacetylenes HC≡CX (X = F, Cl, Br).

Science.gov (United States)

Khiri, D; Hochlaf, M; Chambaud, G

2016-08-04

Highly correlated electronic wave functions within the Multi Reference Configuration Interaction (MRCI) approach are used to study the stability and the formation processes of the monohaloacetylenes HCCX and monohalovinylidenes C2HX (X = F, Cl, Br) in their electronic ground state. These tetra-atomics can be formed through the reaction of triatomic fragments C2F, C2Cl, and C2Br with a hydrogen atom or of C2H with halogen atoms via barrierless reactions, whereas the reactions between the diatomics [C2 + HX] need to overcome barriers of 1.70, 0.89, and 0.58 eV for X = F, Cl, and Br. It is found that the linear HCCX isomers, in singlet symmetry, are more stable than the singlet C2HX iso-forms by 1.995, 2.083, and 1.958 eV for X = F, Cl, and Br. The very small isomerization barriers from iso to linear forms are calculated 0.067, 0.044, and 0.100 eV for F, Cl, and Br systems. The dissociation energies of the HCCX systems (without ZPE corrections), resulting from the breaking of the CX bond, are calculated to be 5.647, 4.691, and 4.129 eV for X = F, Cl, Br, respectively. At the equilibrium geometry of the X(1)Σ(+) state of HCCX, the vertical excitation energies in singlet and triplet symmetries are all larger than the respective dissociation energies. Stable excited states are found only as (3)A', (3)A″, and (1)A″ monohalovinylidene structures.

Reference outlook for energy and emissions 2005-2020

International Nuclear Information System (INIS)

Van Dril, A.W.N.; Elzenga, H.E.

2005-05-01

The Reference Projection 2005-2020 covers the future development of Dutch energy use, greenhouse gas emissions and air pollution up to 2020. The Reference projection is based on assumptions regarding economic, structural, technological and policy developments. Two scenarios have been used. The Strong Europe (SE) scenario is characterized by moderate economic growth and strong public responsibility. The Global Economy (GE) scenario assumes high economic growth and has a strong orientation towards private responsibility. Energy consumption continues to grow in both scenarios and energy intensity is declining in the GE-scenario. Gradual rise of temperature is now included in the estimates for space heating and air conditioning. Energy prices for end users will rise, due to increased imports of natural gas and rising costs of electricity generation. The share of renewables in electricity consumption increases considerably due to subsidies for wind at sea and biomass, up to the target of 9% in 2010. Emissions of non-CO2 greenhouse gases are reduced and stabilise after 2010. The Dutch Kyoto target is probably met in both scenarios, assuming considerable emission reduction efforts abroad. Acidifying emissions of NOx and SO2 stabilise after reductions, but at levels that exceed their national emission ceiling (NEC). Emissions of volatile organic compounds are projected to fall with approximately 25% between 2002 and 2010 below their NEC. Emissions of ammonia are projected to meet their NEC. The emission of fine particles (PM10) will stabilise at present levels [nl

RESONANCE CARS IN BR2 MOLECULES AND BR-ATOMS

NARCIS (Netherlands)

Aben, I.; Levelt, P.; Ubachs, W.M.G.; Hogervorst, W.

1991-01-01

Resonance-enhanced CARS processes were studied in molecular bromine. On the basis of the known spectroscopic constants of the two electronic states involved, the features in the spectra could be identified. CARS signals from Br-atoms produced from dissociation of Br2 were obtained by tuning (omega-1

Land surface temperature representativeness in a heterogeneous area through a distributed energy-water balance model and remote sensing data

Directory of Open Access Journals (Sweden)

C. Corbari

2010-10-01

Full Text Available Land surface temperature is the link between soil-vegetation-atmosphere fluxes and soil water content through the energy water balance. This paper analyses the representativeness of land surface temperature (LST for a distributed hydrological water balance model (FEST-EWB using LST from AHS (airborne hyperspectral scanner, with a spatial resolution between 2–4 m, LST from MODIS, with a spatial resolution of 1000 m, and thermal infrared radiometric ground measurements that are compared with the representative equilibrium temperature that closes the energy balance equation in the distributed hydrological model. <br>> Diurnal and nocturnal images are analyzed due to the non stable behaviour of the thermodynamic temperature and to the non linear effects induced by spatial heterogeneity. <br>> Spatial autocorrelation and scale of fluctuation of land surface temperature from FEST-EWB and AHS are analysed at different aggregation areas to better understand the scale of representativeness of land surface temperature in a hydrological process. <br>> The study site is the agricultural area of Barrax (Spain that is a heterogeneous area with a patchwork of irrigated and non irrigated vegetated fields and bare soil. The used data set was collected during a field campaign from 10 to 15 July 2005 in the framework of the SEN2FLEX project.

Identification of the transition arrays 3d74s-3d74p in Br X and 3d64s-3d64p in Br XI

International Nuclear Information System (INIS)

Zeng, X.T.; Jupen, C.; Bengtsson, P.; Engstroem, L.; Westerlind, M.; Martinson, I.

1991-01-01

We report a beam-foil study of multiply ionized bromine in the region 400-1300A, performed with 6 and 8 MeV Br ions from a tandem accelerator. At these energies transitions belonging to Fe-like Br X and Mn-like Br XI are expected to be prominent. We have identified 31 lines as 3d 7 4s-3d 7 4p transitions in Br X, from which 16 levels of the previously unknown 3d 7 4s configuration could be established. We have also added 6 new 3d 7 4p levels to the 99 previously known. For Br XI we have classified 9 lines as 3d 6 4s-3d 6 4p combinations. The line identifications have been corroborated by isoelectronic comparisons and theoretical calculations using the superposition-of-configurations technique. (orig.)

Greenhouse gases emissions inventory in 2005 by the Mexican energy sector; Inventario de emisiones en 2005 de gases de efecto invernadero por el sector energetico mexicano

Energy Technology Data Exchange (ETDEWEB)

Flores Velazquez, R.; Munoz Lerdo Carranza, R.; Villalba Valle, D. [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: rfv@iie.org.mx; rml@iie.org.mx; danviva17@yahoo.com.mx

2010-01-15

In the present work, it is estimated the greenhouse gases (GHG, GEI in this paper) emissions in 2005 by the consumption and/or transformation of energy in Mexico. This document is not official, and it is used as reference the fuel consumption reported in the Balance National de Energia 2005 published by the Secretaria de Energia. In this way, it is standardized the emission source that will be used in the near future to estimated the official 2005 GHG Emissions Inventory. In order to solve the absence of own emission factors in Mexico, it is used the default global emission factors proposed by the Intergovernmental Panel for Climate Change. The Sectorial Method was used to estimate the GHG emissions taking in account the fuel consumption in each subsector considered in the energy sector. It was found that the transport and energy industries sector had the most GHG emissions, and that Mexico as a non-industrialized country had lower per capita emissions that developed countries. [Spanish] En este trabajo se calcularon las emisiones de Gases de Efecto de inventario (GEI's) del 2005 por la seccion de consumo y/o transformacion de energia en Mexico. El documento obtenido no es oficial, y como referencia, se utiliza el consumo de combustible que refiere el Balance Nacional de Energia 2005, publicado por la Secretaria de Energia. Con esto, se estandarizan las fuentes de emision que en algun momento usara el Inventario Nacional de Emisiones de GEI's 2005. Para resolver la falta de factores de emision propios de Mexico, se recurre a los factores globales de emision propuestos como valores por omision por el Panel Intergubernamental de Cambio Climatico. Para la estimacion de las emisiones de GEI's se utilizo el Metodo Sectorial tomando en consideracion el consumo de combustible de cada uno de los subsectores en que se encuentra dividido el sector energetico. Se encontro que los sectores transporte y de la industria de la transformacion de energia son los que

Our energies have a future. A future without CO{sub 2}. Areva in 2005; Nos energies ont de l'avenir. Un avenir sans CO{sub 2}. Areva en 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-07-01

This document is the sustainable development and 2005 annual report altogether of Areva group. It presents first the challenges of energy for economical development, the climate change threat and the sustainability of nuclear power in particular with respect to radioactive wastes management and power blackouts. Then follows a presentation of Areva's 10 commitments for sustainable development (governance and continuous improvement, financial performance, innovation, customer satisfaction, commitment to employees, risk management and prevention, environmental protection, dialogue and consensus building, community involvement). The annual report presents: the 2005 highlights, Areva around the world, key data, corporate governance, organisation of the group, share information and shareholder relations, business review (front end division, reactors and services division, back end division, transmission and distribution division), financial report and glossary. (J.S.)

USDA Section 9006 Program: Status and Energy Benefits of Grant Awards in FY 2003-2005

Energy Technology Data Exchange (ETDEWEB)

Walters, T.; Savage, S.; Brown, J.

2006-08-01

At the request of the U. S. Department of Agriculture (USDA) Rural Development, the National Renewable Energy Laboratory reviewed projects awarded in the Section 9006 Program: Renewable Energy Systems and Energy Efficiency Improvements Program. This report quantifies federal and private investment, outlines project status based on recent field updates, and calculates the effects on energy and emissions of energy efficiency and renewable energy projects awarded grants in FY 2003, FY 2004, and FY 2005. An overview of the program challenges and modifications in the first three years of operation is also included.

Determinants of energy sector performance in Iraq, 2003 to 2005

International Nuclear Information System (INIS)

Tiedemann, K.H.

2007-01-01

Iraq's energy sector was rehabilitated from 2003 to 2005. The focus of rehabilitation was on restoring Iraq's electricity and oil infrastructure to pre-war production levels; delivering electricity and refined fuels for domestic consumption; and delivering electricity and oil security. This paper provided an analysis of the impact of Coalition efforts and insurgent activities on energy sector performance using time-series models. The paper presented a simple three-equation model consisting of an insurgent attack equation, an investment equation, and production function. The paper also discussed the phases of the insurgency in Iraq, with particular reference to the beginning of the insurgency; initial bombing campaign; escalation of the insurgency; and intra-Iraqi conflict. Key energy sector indicators and regression results were also presented for oil production; diesel production; gasoline production; oil exports; and production and consumption of electricity. It was concluded that expenditures by the United States on oil infrastructure appear to have been relatively efficiently spent. 16 refs., 9 tabs

Minerals and energy: major development projects - April 2005 listing

Energy Technology Data Exchange (ETDEWEB)

Ian Haine (and others) [Australian Bureau of Agricultural and Resource Economics (ABARE), Canberra, ACT (Australia)

2005-06-01

The article describes trends in project development and investment in the minerals and energy sector in Australia. It lists competed projects and committed projects. Black coal projects completed during November 2004 to April 2005 were: Dendrobium underground and Mandalong longwall mining expansion projects in New South Wales and development of Curragh North and Eaglefield opencut mine in Queensland. One of the more significant newly listed projects is Macarthur Coal's Queensland Coke Project near Rockhampton. Capital cost and values of projects are included. The full listing of 229 projects is available electronically from ABARE. The list is released around May and November each year. 10 figs., 4 tabs.

Energy balance of the EPFL buildings at Ecublens for the year 2005; Bilan des energies du site de l'EPFL a Ecublens. Annee 2005

Energy Technology Data Exchange (ETDEWEB)

Vuille, F.

2006-07-01

An overview of the energy consumption of the Swiss Federal Institute of Technology, Lausanne, Switzerland for the year 2005 is given, together with a detailed description of the heating and cooling system of the buildings. Heating is mainly accomplished by two heat pumps using low-temperature heat from water pumped from the near lake of Geneva. Each heat pump has a thermal power of 4.5 MW delivering heat at 50 {sup o}C. Electric power for the heat pumps is generated on site by two cogeneration units comprising gas turbines fueled by 'green' fuel oil (low in sulfur and nitrogen). Each turbine delivers 3 MW electric and 5 MW thermal power (heating water at 65 {sup o}C). During the last years, 68% of the heating energy delivered to the heat distribution system was renewable energy from the lake, 20% was electric energy for powering the heat pumps, 4% was electrical energy used by the water pumps, and 8% was heat from fuel oil. This results in an overall coefficient of performance COP of the heat pumps of 3.7. Neglecting the power used for pumping lake water the average COP would be 4.5.

Development and validation of the Affect in Play Scale-brief rating version (APS-BR).

Science.gov (United States)

Cordiano, Tori J Sacha; Russ, Sandra W; Short, Elizabeth J

2008-01-01

The Affect in Play Scale (APS; Russ, 1987, 2004) is one of few reliable, standardized measures of pretend play, yet the fact that it requires videotaping and extensive training to score compromises its clinical utility. In this study, we developed and validated a brief rating version (APS-BR) that does not require videotaping. Construct validity was established by comparing scores from the original APS and the APS-BR using an existing data set of videotaped play (n = 46). We examined associations between scores on the APS-BR and theoretically relevant measures of divergent thinking and emotional memories. Scores on the APS-BR related strongly to those on the APS, and the pattern of correlations for each scale and relevant criterion measures was similar in strength and direction, supporting the APS-BR as an alternate form of the APS. In addition, we completed a pilot study to examine the efficacy of using the APS-BR in its intended in vivo format (n = 28). Results from both studies suggest that the APS-BR is a promising brief measure of children's pretend play that can be substituted for the APS in clinical and research settings.

Reactor BR2

Energy Technology Data Exchange (ETDEWEB)

Gubel, P

2000-07-01

The BR2 reactor is still SCK-CEN's most important nuclear facility. After an extensive refurbishment to compensate for the ageing of the installation, the reactor was restarted in April 1997. Various aspects concerning the operation of the BR2 Reactor, the utilisation of the CALLISTO loop and the irradiation programme, the BR2 R and D programme and the production of isotopes and of NTD-silicon are discussed. Progress and achievements in 1999 are reported.

Reactor BR2

International Nuclear Information System (INIS)

Gubel, P.

2000-01-01

The BR2 reactor is still SCK-CEN's most important nuclear facility. After an extensive refurbishment to compensate for the ageing of the installation, the reactor was restarted in April 1997. Various aspects concerning the operation of the BR2 Reactor, the utilisation of the CALLISTO loop and the irradiation programme, the BR2 R and D programme and the production of isotopes and of NTD-silicon are discussed. Progress and achievements in 1999 are reported

What is the best bonding model of the (σ-H-BR) species bound to a transition metal? Bonding analysis in complexes [(H)2Cl(PMe3)2M(σ-H-BR)] (M = Fe, Ru, Os).

Science.gov (United States)

Pandey, Krishna K

2012-03-21

Density Functional Theory calculations have been performed for the σ-hydroboryl complexes of iron, ruthenium and osmium [(H)(2)Cl(PMe(3))(2)M(σ-H-BR)] (M = Fe, Ru, Os; R = OMe, NMe(2), Ph) at the BP86/TZ2P/ZORA level of theory in order to understand the interactions between metal and HBR ligands. The calculated geometries of the complexes [(H)(2)Cl(PMe(3))(2)Ru(HBNMe(2))], [(H)(2)Cl(PMe(3))(2)Os(HBR)] (R = OMe, NMe(2)) are in excellent agreement with structurally characterized complexes [(H)(2)Cl(P(i)Pr(3))(2)Os(σ-H-BNMe(2))], [(H)(2)Cl(P(i)Pr(3))(2)Os{σ-H-BOCH(2)CH(2)OB(O(2)CH(2)CH(2))}] and [(H)(2)Cl(P(i)Pr(3))(2)Os(σ-H-BNMe(2))]. The longer calculated M-B bond distance in complex [(H)(2)Cl(PMe(3))(2)M(σ-H-BNMe(2))] are due to greater B-N π bonding and as a result, a weaker M-B π-back-bonding. The B-H2 bond distances reveal that (i) iron complexes contain bis(σ-borane) ligand, (ii) ruthenium complexes contain (σ-H-BR) ligands with a stretched B-H2 bond, and (iii) osmium complexes contain hydride (H2) and (σ-H-BR) ligands. The H-BR ligands in osmium complexes are a better trans-directing ligand than the Cl ligand. Values of interaction energy, electrostatic interaction, orbital interaction, and bond dissociation energy for interactions between ionic fragments are very large and may not be consistent with M-(σ-H-BR) bonding. The EDA as well as NBO and AIM analysis suggest that the best bonding model for the M-σ-H-BR interactions in the complexes [(H)(2)Cl(PMe(3))(2)M(σ-H-BR)] is the interaction between neutral fragments [(H)(2)Cl(PMe(3))(2)M] and [σ-H-BR]. This becomes evident from the calculated values for the orbital interactions. The electron configuration of the fragments which is shown for C in Fig. 1 experiences the smallest change upon the M-σ-H-BR bond formation. Since model C also requires the least amount of electronic excitation and geometry changes of all models given by the ΔE(prep) values, it is clearly the most appropriate choice of

Interfacial Energy-Level Alignment for High-Performance All-Inorganic Perovskite CsPbBr3 Quantum Dot-Based Inverted Light-Emitting Diodes.

Science.gov (United States)

Subramanian, Alagesan; Pan, Zhenghui; Zhang, Zhenbo; Ahmad, Imtiaz; Chen, Jing; Liu, Meinan; Cheng, Shuang; Xu, Yijun; Wu, Jun; Lei, Wei; Khan, Qasim; Zhang, Yuegang

2018-04-18

All-inorganic perovskite light-emitting diode (PeLED) has a high stability in ambient atmosphere, but it is a big challenge to achieve high performance of the device. Basically, device design, control of energy-level alignment, and reducing the energy barrier between adjacent layers in the architecture of PeLED are important factors to achieve high efficiency. In this study, we report a CsPbBr 3 -based PeLED with an inverted architecture using lithium-doped TiO 2 nanoparticles as the electron transport layer (ETL). The optimal lithium doping balances the charge carrier injection between the hole transport layer and ETL, leading to superior device performance. The device exhibits a current efficiency of 3 cd A -1 , a luminance efficiency of 2210 cd m -2 , and a low turn-on voltage of 2.3 V. The turn-on voltage is one of the lowest values among reported CsPbBr 3 -based PeLEDs. A 7-fold increase in device efficiencies has been obtained for lithium-doped TiO 2 compared to that for undoped TiO 2 -based devices.

The TbBr3–LiBr binary system: Experimental thermodynamic investigation and assessment of phase diagram

International Nuclear Information System (INIS)

Rycerz, L.; Gong, W.; Gaune-Escard, M.

2013-01-01

Highlights: ► DSC measurements for the (LiBr + TbBr 3 ) system. ► congruently Li3TbBr 6 and incongruently melting Li5TbBr 8 compounds. ► Thermodynamic description of the liquid phase in the (LiBr + TbBr 3 ) system. ► Assessment with a two-sublattice ionic solution model. - Abstract: DSC was used to study the phase equilibrium in the TbBr 3 –LiBr binary system. The results obtained provided a basis for constructing the phase diagram of this system. It exhibits two compounds: Li 5 TbBr 8 , which decomposes in the solid state at 611 K, and Li 3 TbBr 6 , which melts congruently at 785 K with the related enthalpy 59.1 kJ·mol −1 . The binary LiBr–TbBr 3 system was then optimized using the available experimental information on phase diagram and thermodynamic properties. A two-sub-lattice ionic solution model (Li + ) P :(Br − , TbBr 6 −3 , TbBr 3 ) Q was adopted to describe the liquid phase. The present assessment of the binary LiBr–TbBr 3 system was in good agreement with the corresponding experimental data and confirmed their consistency.

Fine structure of excitons and electron-hole exchange energy in polymorphic CsPbBr3 single nanocrystals.

Science.gov (United States)

Ramade, Julien; Andriambariarijaona, Léon Marcel; Steinmetz, Violette; Goubet, Nicolas; Legrand, Laurent; Barisien, Thierry; Bernardot, Frédérick; Testelin, Christophe; Lhuillier, Emmanuel; Bramati, Alberto; Chamarro, Maria

2018-04-05

All inorganic CsPbX3 (X = Cl, Br, I) nanocrystals (NCs) belong to the novel class of confined metal-halide perovskites which are currently arousing enthusiasm and stimulating huge activity across several fields of optoelectronics due to outstanding properties. A deep knowledge of the band-edge excitonic properties of these materials is thus crucial to further optimize their performances. Here, high-resolution photoluminescence (PL) spectroscopy of single bromide-based NCs reveals the exciton fine structure in the form of sharp peaks that are linearly polarized and grouped in doublets or triplets, which directly mirror the adopted crystalline structure, tetragonal (D4h symmetry) or orthorhombic (D2h symmetry). Intelligible equations are found that show how the fundamental parameters (spin-orbit coupling, ΔSO, crystal field term, T, and electron-hole exchange energy, J) rule the energy spacings in doublets and triplets. From experimental data, fine estimations of each parameter are obtained. The analysis of the absorption spectra of an ensemble of NCs with a "quasi-bulk" behavior leads to ΔSO = 1.20 ± 0.06 eV and T = -0.34 ± 0.05 eV in CsPbBr3. The study of individual luminescence responses of NCs having sizes comparable to the exciton Bohr diameter, 7 nm, allows us to estimate the value of J to be around ≈3 meV in both tetragonal and orthorhombic phases. This value is already enhanced by confinement.

$^{80m}$Br/$^{80}$Br a new electron-$\\gamma$ - PAC Probe

CERN Document Server

Correia, J G; Araújo, J P; Marques, J G; Soares, J C; Melo, A A

2001-01-01

Conversion electron-$\\gamma$ PAC measurements of the 49 keV - 37 keV cascade in $^{80}$Br through the intermediate 2$^{-}$ state with T$_{1/2}$=7.4 ns were performed with a system of two magnetic lens spectrometers and two BaF$_{2}$ scintillation detectors. The parent $^{80m}$Br activity with half-life of 4.4 hrs was implanted into Ni, Zn and graphite at the ISOLDE separator at CERN. The observed interaction frequency in the nickel matrix is in good agreement with the known value of the hyperfine field for Br in Ni and the magnetic moment of the 2$^{-}$ state. From the measured quadrupole interaction in Zn and graphite the electric field gradients at Br were obtained.

Elimination of nonspecific radioactivity from [76Br]bromide in PET study with [76Br]bromodeoxyuridine

International Nuclear Information System (INIS)

Li Lu; Bergstroem, Mats; Fasth, Karl-Johan; Wu Feng; Eriksson, Barbro; Laangstroem, Bengt

1999-01-01

[ 76 Br]Bromodeoxyuridine ([ 76 Br]BrdU) might allow a determination of proliferation in vivo using positron emission tomography (PET), but only with consideration of organ nonspecific radioactivity constituted by [ 76 Br]bromide. A first study assessed the potential of diuretics to eliminate [ 76 Br]bromide. [ 76 Br]Bromide was injected in the vein of rats and different diuretic combinations were given. Urine was collected and radioactivity measured. Torasemide plus sodium chloride gave better 76 Br elimination than the other diuretics. In a second experiment, rats were given [ 76 Br]BrdU. After the radioactivity injection, the rats of the treatment group were given torasemide plus NaCl. At 44 h after the radioactivity injection, the radioactivity concentration and the fraction incorporated into DNA were measured in different organs. Using diuretics, the elimination of [ 76 Br]bromide was increased. The radioactivity decreased 30-50% in most of the organs but the highest radioactivity uptake was found in the organs with more active DNA synthesis. This method may facilitate the use of [ 76 Br]BrdU as a tracer for DNA synthesis using PET

Investigation of LaBr3:Ce probe for gamma-ray spectroscopy and dosimetry

Science.gov (United States)

Maghraby, Ahmed M.; Alzimami, K. S.; Alkhorayef, M. A.; Alsafi, K. G.; Ma, A.; Alfuraih, A. A.; Alghamdi, A. A.; Spyrou, N. M.

2014-02-01

The main thrust of this work is the investigation of performance of relatively new commercial LaBr3:Ce probe (Inspector 1000™ with LaBr3:Ce crystal) for gamma-ray spectroscopy and dosimetry measurements in comparison to LaCl3:Ce and NaI:Tl scintillators. The crystals were irradiated by a wide range of energies (57Co, 22Na, 18F, 137Cs and 60Co). The study involved recording of detected spectra and measurement of energy resolution, photopeak efficiency, internal radioactivity measurements as well as dose rate. The Monte Carlo package, Geant4 Application for Tomographic Emission (GATE) was used to validate the experiments. Overall results showed very good agreement between the measurements and the simulations. The LaBr3:Ce crystal has excellent energy resolution, energy resolutions of (3.37±0.05)% and (2.98±0.07)% for a 137Cs 662 keV and a 60Co 1332 keV gamma-ray point sources respectively, were recorded. The disadvantage of the lanthanum halide scintillators is their internal radioactivity. Inspector 1000™ with LaBr3:Ce scintillator has shown an accurate and quick dose measurements at Positron Emission Tomography (PET) Units which allows accurate assessment of the radiation dose received by staff members compared to the use of electronic personal dosimeters (EPD).

Single crystal growth, electronic structure and optical properties of Cs2HgBr4

Science.gov (United States)

Lavrentyev, A. A.; Gabrelian, B. V.; Vu, V. T.; Shkumat, P. N.; Parasyuk, O. V.; Fedorchuk, A. O.; Khyzhun, O. Y.

2015-10-01

We report on successful synthesis of high-quality single crystal of cesium mercury tetrabromide, Cs2HgBr4, by using the vertical Bridgman-Stockbarger method as well as on studies of its electronic structure. For the Cs2HgBr4 crystal, we have recorded X-ray photoelectron spectra for both pristine and Ar+ ion-bombarded surfaces. Our data indicate that the Cs2HgBr4 single crystal surface is rather sensitive with respect to Ar+ ion-bombardment. In particular, such a treatment of the Cs2HgBr4 single crystal surface alters its elemental stoichiometry. To explore peculiarities of the energy distribution of total and partial densities of states within the valence band and the conduction band of Cs2HgBr4, we have made band-structure calculations based on density functional theory (DFT) employing the augmented plane wave+local orbitals (APW+lo) method as incorporated in the WIEN2k package. The APW+lo calculations allow for concluding that the Br 4p states make the major contributions in the upper portion of the valence band, while its lower portion is dominated by contributors of the Hg 5d and Cs 5p states. Further, the main contributors to the bottom of the conduction band of Cs2HgBr4 are the unoccupied Br p and Hg s states. In addition, main optical characteristics of Cs2HgBr4 such as dispersion of the absorption coefficient, real and imaginary parts of dielectric function, electron energy-loss spectrum, refractive index, extinction coefficient and optical reflectivity have been explored from the first-principles band-structure calculations.

Transcription regulator TRIP-Br2 mediates ER stress-induced brown adipocytes dysfunction.

Science.gov (United States)

Qiang, Guifen; Whang Kong, Hyerim; Gil, Victoria; Liew, Chong Wee

2017-01-09

In contrast to white adipose tissue, brown adipose tissue (BAT) is known to play critical roles for both basal and inducible energy expenditure. Obesity is associated with reduction of BAT function; however, it is not well understood how obesity promotes BAT dysfunction, especially at the molecular level. Here we show that the transcription regulator TRIP-Br2 mediates ER stress-induced inhibition of lipolysis and thermogenesis in BAT. Using in vitro, ex vivo, and in vivo approaches, we demonstrate that obesity-induced inflammation upregulates brown adipocytes TRIP-Br2 expression via the ER stress pathway and amelioration of ER stress in mice completely abolishes high fat diet-induced upregulation of TRIP-Br2 in BAT. We find that increased TRIP-Br2 significantly inhibits brown adipocytes thermogenesis. Finally, we show that ablation of TRIP-Br2 ameliorates ER stress-induced inhibition on lipolysis, fatty acid oxidation, oxidative metabolism, and thermogenesis in brown adipocytes. Taken together, our current study demonstrates a role for TRIP-Br2 in ER stress-induced BAT dysfunction, and inhibiting TRIP-Br2 could be a potential approach for counteracting obesity-induced BAT dysfunction.

Pure Cs4PbBr6: Highly Luminescent Zero-Dimensional Perovskite Solids

KAUST Repository

Saidaminov, Makhsud I.

2016-09-26

So-called zero-dimensional perovskites, such as Cs4PbBr6, promise outstanding emissive properties. However, Cs4PbBr6 is mostly prepared by melting of precursors that usually leads to a coformation of undesired phases. Here, we report a simple low-temperature solution-processed synthesis of pure Cs4PbBr6 with remarkable emission properties. We found that pure Cs4PbBr6 in solid form exhibits a 45% photoluminescence quantum yield (PLQY), in contrast to its three-dimensional counterpart, CsPbBr3, which exhibits more than 2 orders of magnitude lower PLQY. Such a PLQY of Cs4PbBr6 is significantly higher than that of other solid forms of lower-dimensional metal halide perovskite derivatives and perovskite nanocrystals. We attribute this dramatic increase in PL to the high exciton binding energy, which we estimate to be ∼353 meV, likely induced by the unique Bergerhoff–Schmitz–Dumont-type crystal structure of Cs4PbBr6, in which metal-halide-comprised octahedra are spatially confined. Our findings bring this class of perovskite derivatives to the forefront of color-converting and light-emitting applications.

The production and recovery of 77Br at Los Alamos for nuclear medicine studies

International Nuclear Information System (INIS)

Grant, P.M.; Whipple, R.E.; Barnes, J.W.; Bentley, G.E.; Wanek, P.M.; O'Brien, H.A. Jr.

1981-01-01

A procedure for the synthesis and isolation of 77 Br for nuclear medicine research has been developed at LASL. Metallic Mo targets are irradiated at LAMPF with medium-energy protons at high beam current. Following dissolution, volatilization, precipitation, and ion exchange techniques, 77 Br is recovered with a (91 +- 7)% chemical yield and is completely free of all other radioactive species with the exception of small levels of 76 Br and 82 Br. Ci-quantity production capabilities have been demonstrated, and the product is proving successful for the labelling of diverse radiopharmaceuticals. Future improvements in the process are also discussed. (author)

All-Ambient Processed Binary CsPbBr3-CsPb2Br5 Perovskites with Synergistic Enhancement for High-Efficiency Cs-Pb-Br-Based Solar Cells.

Science.gov (United States)

Zhang, Xisheng; Jin, Zhiwen; Zhang, Jingru; Bai, Dongliang; Bian, Hui; Wang, Kang; Sun, Jie; Wang, Qian; Liu, Shengzhong Frank

2018-02-28

All-inorganic CsPbBr 3 perovskite solar cells display outstanding stability toward moisture, light soaking, and thermal stressing, demonstrating great potential in tandem solar cells and toward commercialization. Unfortunately, it is still challenging to prepare high-performance CsPbBr 3 films at moderate temperatures. Herein, a uniform, compact CsPbBr 3 film was fabricated using its quantum dot (QD)-based ink precursor. The film was then treated using thiocyanate ethyl acetate (EA) solution in all-ambient conditions to produce a superior CsPbBr 3 -CsPb 2 Br 5 composite film with a larger grain size and minimal defects. The achievement was attributed to the surface dissolution and recrystallization of the existing SCN - and EA. More specifically, the SCN - ions were first absorbed on the Pb atoms, leading to the dissolution and stripping of Cs + and Br - ions from the CsPbBr 3 QDs. On the other hand, the EA solution enhances the diffusion dynamics of surface atoms and the surfactant species. It is found that a small amount of CsPb 2 Br 5 in the composite film gives the best surface passivation, while the Br-rich surface decreases Br vacancies (V Br ) for a prolonged carrier lifetime. As a result, the fabricated device gives a higher solar cell efficiency of 6.81% with an outstanding long-term stability.

New measurement of BR(D→ρμν)BR(D→Kμν) branching ratio

Science.gov (United States)

FOCUS Collaboration; Link, J. M.; Yager, P. M.; Anjos, J. C.; Bediaga, I.; Castromonte, C.; Machado, A. A.; Magnin, J.; Massafferri, A.; de Miranda, J. M.; Pepe, I. M.; Polycarpo, E.; Dos Reis, A. C.; Carrillo, S.; Casimiro, E.; Cuautle, E.; Sánchez-Hernández, A.; Uribe, C.; Vá, F.; Agostino, L.; Cinquini, L.; Cumalat, J. P.; O'Reilly, B.; Segoni, I.; Stenson, K.; Butler, J. N.; Cheung, H. W. K.; Chiodini, G.; Gaines, I.; Garbincius, P. H.; Garren, L. A.; Gottschalk, E.; Kasper, P. H.; Kreymer, A. E.; Kutschke, R.; Wang, M.; Benussi, L.; Bertani, M.; Bianco, S.; Fabbri, F. L.; Pacetti, S.; Zallo, A.; Reyes, M.; Cawlfield, C.; Kim, D. Y.; Rahimi, A.; Wiss, J.; Gardner, R.; Kryemadhi, A.; Chung, Y. S.; Kang, J. S.; Ko, B. R.; Kwak, J. W.; Lee, K. B.; Cho, K.; Park, H.; Alimonti, G.; Barberis, S.; Boschini, M.; Cerutti, A.; D'Angelo, P.; Dicorato, M.; Dini, P.; Edera, L.; Erba, S.; Inzani, P.; Leveraro, F.; Malvezzi, S.; Menasce, D.; Mezzadri, M.; Moroni, L.; Pedrini, D.; Pontoglio, C.; Prelz, F.; Rovere, M.; Sala, S.; Davenport, T. F.; Arena, V.; Boca, G.; Bonomi, G.; Gianini, G.; Liguori, G.; Lopes Pegna, D.; Merlo, M. M.; Pantea, D.; Ratti, S. P.; Riccardi, C.; Vitulo, P.; Gö, C.; Otalora, J.; Hernandez, H.; Lopez, A. M.; Mendez, H.; Paris, A.; Quinones, J.; Ramirez, J. E.; Zhang, Y.; Wilson, J. R.; Handler, T.; Mitchell, R.; Engh, D.; Hosack, M.; Johns, W. E.; Luiggi, E.; Moore, J. E.; Nehring, M.; Sheldon, P. D.; Vaandering, E. W.; Webster, M.; Sheaff, M.

2006-06-01

Using data collected by the FOCUS experiment at Fermilab, we present a new measurement of the charm semileptonic branching ratio BR(D→ρμν)BR(D→Kμν). From a sample of 320±44 and 11372±161D→ρμν and D→Kπμν events respectively, we find BR(D→ρμν)BR(D→Kμν)=0.041±0.006 (stat)±0.004 (syst).

2005 Tour de Sol: The Sustainable Energy and Transportation Festival and Competition

Energy Technology Data Exchange (ETDEWEB)

Nancy Hazard

2005-05-07

This report gives a summary of the 2005Tour de Sol: The Sustainable Energy and Transportation Festival and Competition. It lists our objectives, what we did, and an analysis of how we met our objectives. An 80-page report with a list of verified print, radio and TV media coverage, and copies of selected news clips and web media coverage is available at the NESEA office for review.

Technical Training: ELEC-2005 - Electronics in High Energy Physics: Summer Term (May 2005)

CERN Multimedia

Davide Vitè

2005-01-01

ELEC-2005 is a new course series on modern electronics, given by CERN physicists and engineers within the framework of the 2005 Technical Training Programme, in an extended format of the successful ELEC-2002 course series.This comprehensive course series is designed for people who are not electronics specialists, for example physicists, engineers and technicians working at or visiting the laboratory, who use or will use electronics in their present or future activities, in particular in the context of the LHC accelerator and experiments. ELEC-2005 is composed of four Terms. The last two Terms will run with the following schedule: Summer Term: System electronics for physics: Issues (May, 7 lectures) - now open for registration Autumn Term: Electronics applications in HEP experiments (November-December, 10 lectures) Lectures within each Term will take place on Tuesdays and Thursdays, from 10h00 to 12h30. The course will be in English, with questions and answers also possible in French. Separate registrati...

Technical Training: ELEC-2005 - Electronics in High Energy Physics: Summer Term (May 2005)

CERN Multimedia

Monique Duval

2005-01-01

ELEC-2005 is a new course series on modern electronics, given by CERN physicists and engineers within the framework of the 2005 Technical Training Programme, in an extended format of the successful ELEC-2002 course series. This comprehensive course series is designed for people who are not electronics specialists, for example physicists, engineers and technicians working at or visiting the laboratory, who use or will use electronics in their present or future activities, in particular in the context of the LHC accelerator and experiments. ELEC-2005 is composed of four Terms. The Winter (Introduction to electronics in HEP) and Spring (Integrated circuits and VLSI technology for physics) Terms already took place; the next two Terms will run with the following schedule: Summer Term: System electronics for physics: Issues (May, 7 lectures) - now open for registration Autumn Term: Electronics applications in HEP experiments (November-December, 10 lectures) Lectures within each Term will take place on Tuesday...

Physical adsorption and charge transfer of molecular Br2 on graphene.

Science.gov (United States)

Chen, Zheyuan; Darancet, Pierre; Wang, Lei; Crowther, Andrew C; Gao, Yuanda; Dean, Cory R; Taniguchi, Takashi; Watanabe, Kenji; Hone, James; Marianetti, Chris A; Brus, Louis E

2014-03-25

We present a detailed study of gaseous Br2 adsorption and charge transfer on graphene, combining in situ Raman spectroscopy and density functional theory (DFT). When graphene is encapsulated by hexagonal boron nitride (h-BN) layers on both sides, in a h-BN/graphene/h-BN sandwich structure, it is protected from doping by strongly oxidizing Br2. Graphene supported on only one side by h-BN shows strong hole doping by adsorbed Br2. Using Raman spectroscopy, we determine the graphene charge density as a function of pressure. DFT calculations reveal the variation in charge transfer per adsorbed molecule as a function of coverage. The molecular adsorption isotherm (coverage versus pressure) is obtained by combining Raman spectra with DFT calculations. The Fowler-Guggenheim isotherm fits better than the Langmuir isotherm. The fitting yields the adsorption equilibrium constant (∼0.31 Torr(-1)) and repulsive lateral interaction (∼20 meV) between adsorbed Br2 molecules. The Br2 molecule binding energy is ∼0.35 eV. We estimate that at monolayer coverage each Br2 molecule accepts 0.09 e- from single-layer graphene. If graphene is supported on SiO2 instead of h-BN, a threshold pressure is observed for diffusion of Br2 along the (somewhat rough) SiO2/graphene interface. At high pressure, graphene supported on SiO2 is doped by adsorbed Br2 on both sides.

Speeding Up Slow Deaths: <br>Medical Sovereignty circa 2005

Directory of Open Access Journals (Sweden)

Lisa Diedrich

2011-10-01

Full Text Available In this essay, I take up the question of the time of medicine in relation to two events in the U.S. from 2005—the Terri Schiavo case and Hurricane Katrina and its aftermath. I consider both cases as “mediatized medical events,” that is, as events in which the practices of medicine received considerable media attention at a particular historical moment; or, we might say, as events that brought a convergence between media and medical practices. I juxtapose these two events because, placed side by side, they help make visible two stories of catastrophe, as well as the many difficulties of telling stories of catastrophe. Bringing together these seemingly divergent events allows me to draw connections that I hope will expand our bioethical imaginary beyond the reductive approaches that tend to dominate the practice of bioethics today. I also juxtapose them to signal a bioethical tension at the heart of the neoliberal state’s response to catastrophe in general, what Foucault might have diagnosed as the difference between making live and letting die. In these two events, we glimpsed—if only fleetingly—the state’s operation of making live and letting die, and medicine’s central role in that operation, as well as the re-assertion of medical sovereignty in crisis events.

Our energies have a future. A future without CO2. Areva in 2005

International Nuclear Information System (INIS)

2005-01-01

This document is the sustainable development and 2005 annual report altogether of Areva group. It presents first the challenges of energy for economical development, the climate change threat and the sustainability of nuclear power in particular with respect to radioactive wastes management and power blackouts. Then follows a presentation of Areva's 10 commitments for sustainable development (governance and continuous improvement, financial performance, innovation, customer satisfaction, commitment to employees, risk management and prevention, environmental protection, dialogue and consensus building, community involvement). The annual report presents: the 2005 highlights, Areva around the world, key data, corporate governance, organisation of the group, share information and shareholder relations, business review (front end division, reactors and services division, back end division, transmission and distribution division), financial report and glossary. (J.S.)

Household energy requirement and value patterns

International Nuclear Information System (INIS)

Vringer, Kees; Aalbers, Theo; Blok, Kornelis

2007-01-01

For an effective consumer energy policy, it is important to know why some households require more energy than others. The aim of the study described here was to examine whether there is a relationship between the total household energy requirement, on one hand, and value patterns, the motivation to save energy or the problem perception of climate change, on the other. To examine these relationships, we held a consumer survey among 2304 respondent households. We did not find significant differences in the energy requirement of groups of households with different value patterns, taking into account the differences in the socio-economic situation of households. Only for the 'motivation to save energy' we did find that the least motivated group requires 10 GJ more energy than the average and most motivated groups; this is about 4% of the total household energy requirement. This means that a self-regulating energy policy, solely based on the fact that a strategy of internalising environmental responsibility will not be effective in saving energy. There are indications that a social dilemma is one of the reasons why people's consumption patterns do not conform to their value patterns, problem perception or motivation to save energy

ELEC-2005: Electronics in High Energy Physics

CERN Multimedia

Monique Duval

2004-01-01

ELEC-2005 is a new course series on modern electronics, given by CERN physicists and engineers in the format of the successful ELEC-2002 course series, and within the framework of the 2005 Technical Training Programme. This comprehensive course series is designed for people who are not electronics specialists, for example physicists, engineers and technicians working at or visiting the laboratory, who use or will use electronics in their present or future activities, in particular in the context of the LHC accelerator and experiments. ELEC-2005 will composed of four Terms throughout the year: Winter Term: Introduction to electronics in HEP (January-February, 6 lectures) Spring Term: Integrated circuits and VLSI technology for physics (March, 6 lectures) Summer Term: System electronics for physics: Issues (May, 7 lectures) Winter Term: Electronics applications in HEP experiments (November-December, 10 lectures) Lectures within each Term will take place on Tuesdays and Thursdays, from 10:00 to 12:30. The...

Yrityksen brändin uudistaminen

OpenAIRE

Saarimaa, Petri

2015-01-01

Brändin rakentaminen on tänä päivänä tärkeä osa yrityksen näkyvyyden ja kilpailukyvyn edistämisessä. Huolellisesti rakennetulla brändillä ja hyvällä markkinoinnilla yritys voi erottua kilpailijoistaan positiivisesti. Tie menestyvään brändiin on kuitenkin pitkä prosessi. Toimeksiantajana opinnäytetyössä toimi rakennusyritys Rakennus Vuoriot Oy. Opinnäytetyön tavoitteena oli toteuttaa yritykselle brändin uudistaminen luomalla kokonaan uusi perusta ja rakennusosat olemassa olevalle brändille...

Our energies have a future. A future without CO{sub 2}. Areva in 2005; Nos energies ont de l'avenir. Un avenir sans CO{sub 2}. Areva en 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-07-01

This document is the sustainable development and 2005 annual report altogether of Areva group. It presents first the challenges of energy for economical development, the climate change threat and the sustainability of nuclear power in particular with respect to radioactive wastes management and power blackouts. Then follows a presentation of Areva's 10 commitments for sustainable development (governance and continuous improvement, financial performance, innovation, customer satisfaction, commitment to employees, risk management and prevention, environmental protection, dialogue and consensus building, community involvement). The annual report presents: the 2005 highlights, Areva around the world, key data, corporate governance, organisation of the group, share information and shareholder relations, business review (front end division, reactors and services division, back end division, transmission and distribution division), financial report and glossary. (J.S.)

EASY-2005.1, European Neutron Activation System

International Nuclear Information System (INIS)

Forrest, R.A.; Sublet, Jean-Christophe

2008-01-01

1 - Description of program or function: The EASY-2005 (European Activation System) consists of a wide range of codes, data and documentation all aimed at satisfying the objective of calculating the response of materials irradiated in a neutron flux. The main difference from the previous version is the upper energy limit which has increased from 20 to 60 MeV. It is designed to investigate both fusion devices and accelerator based materials test facilities that will act as intense sources of high energy neutrons causing significant activation of the surrounding materials. The very general nature of the calculational method and the data libraries means that it is applicable (with some reservations) to all situations (e.g. fission reactors or neutron sources) where materials are exposed to neutrons below 60 MeV. EASY can be divided into two parts: data and code development tools and user tools and data. The former are required to develop the latter, but EASY users only need to be able to use the inventory code FISPACT and be aware of the contents of the EAF library (the data source). The complete EASY package contains the FISPACT-2005 inventory code, the EAF-2005 library, and the EASY User Interface. The activation package EASY-2005 [1] is the result of significant development to extend the upper energy range from 20 to 60 MeV so that it is capable of being used for IFMIF calculations. The EAF-2005 library contains 62,637 reactions, almost five times more than in EAF-2003 (12,617). Such a large increase means that some mistakes may exist in the new file that need to be corrected. Because of these shortcomings and for other reasons explained below, a maintenance release, EAF-2005.1 has been produced. A deuteron-induced cross section library was also included for the first time, and can be used with EASY to enable calculations of the activation due to deuterons [2]. This library is included in the EASY-2005.1 maintenance release as is a new version of the FISPACT code

Integrating Renewable Energy Requirements Into Building Energy Codes

Energy Technology Data Exchange (ETDEWEB)

Kaufmann, John R.; Hand, James R.; Halverson, Mark A.

2011-07-01

This report evaluates how and when to best integrate renewable energy requirements into building energy codes. The basic goals were to: (1) provide a rough guide of where we’re going and how to get there; (2) identify key issues that need to be considered, including a discussion of various options with pros and cons, to help inform code deliberations; and (3) to help foster alignment among energy code-development organizations. The authors researched current approaches nationally and internationally, conducted a survey of key stakeholders to solicit input on various approaches, and evaluated the key issues related to integration of renewable energy requirements and various options to address those issues. The report concludes with recommendations and a plan to engage stakeholders. This report does not evaluate whether the use of renewable energy should be required on buildings; that question involves a political decision that is beyond the scope of this report.

Establishing the Isotope Hydrology Laboratory in accordance with ISO/IEC 17025:2005 standard

International Nuclear Information System (INIS)

Nguyen Thi Hong Thinh; Ha Lan Anh; Vo Thi Anh; Dinh Thi Bich Lieu; Vo Thi Tuong Hanh

2013-01-01

The ISO/IEC 17025:2005 General requirements for the competence calibration laboratories is basis for the accreditation body of the country in general and VILAS in particular recognizing the competence of laboratories. With the desire to prove that we have sufficient technical , management capacity , and the ability to provide the legally recognized and technically valuable test results, the Isotope Hydrology Laboratory have developed a quality management system in accordance with ISO / IEC 17025:2005, in which the laboratory quality manual has been developed. It describes the laboratory management system , scope of activities related to quality assurance of 13 major ions and tritium content measurement services in water samples. Under quality management system, there are management and technical procedures, analysis procedures, work instructions, technical documentation, file and form system. These documents define the roles, responsibilities, powers, detailed instructions for applying and maintaining effective quality management system. Isotope Hydrology Laboratory received a certificate of accreditation issued by Bureau of Accreditation which recognized the laboratory in accordance with ISO 17025:2005 with VILAS 670 accreditation code. Scope of recognition is analyzed 14 parameters: F - , Cl - , NO 2 - , NO 3 - , Br - , PO 4 3- , SO 4 2- , Li + , Na + , NH 4 + , K + , Mg 2+ , Ca 2+ and 3 H in water by ion chromatography and liquid scintillator counting method. (author)

EDF - Electricite de France, 2005 annual Results

International Nuclear Information System (INIS)

2006-01-01

The EDF Group is an integrated energy supplier operating in a wide range of electricity-related businesses: generation, transmission, distribution, sale and trading of energy. It is the main operator in the French electricity market and one of the leading electricity groups in Europe. The EDF Group has built a business model balanced between deregulated and regulated operations in France and an international presence. This document is EDF Group's annual Results for 2005. It is made of several reports: the 2005 Annual Results presentation, the consolidated financial statements at 31 December 2005, the 2005 Half-year results presentation, and the Consolidated financial statements at 30 June 2005

Chanel-brändin nuorentaminen Suomessa

OpenAIRE

Auvinen, Elina

2017-01-01

Tämän opinnäytetyön tavoitteena oli kartoittaa Chanel-kosmetiikkabrändin imagoa ja asiakaskuntaa Suomessa sekä luoda saatujen tulosten pohjalta kehitysehdotuksia Chanel-brändin markkinointiin Suomessa brändin nuorentamisen näkökulmasta. Työn toimeksiantaja oli Chanel-brändin jakelija Oy Transmeri Ab. Teoriataustassa käsiteltiin laajasti erilaisia brändin nuorentamiseen liittyviä aihepiirejä; bränditeoriaa, brändien uudistamista, luksusbrändien erityispiirteitä sekä niiden asiakkaita, digitaal...

Revised and extended analysis of Br IV

International Nuclear Information System (INIS)

Riyaz, A.; Rahimullah, K.; Tauheed, A.

2014-01-01

The spectrum of three-times ionized bromine Br IV has been studied in the 319–2350 Å wavelength region. The spectrum was recorded on a 3-m normal incidence vacuum spectrograph at the St. Francis Xavier University, Antigonish (Canada) and 6.65-m grazing incidence spectrograph at the Zeeman laboratory (Amsterdam). The light sources used were a triggered spark and sliding spark, respectively. The ground configuration of Br IV 3d 10 4s 2 4p 2 , the excited configurations 3d 10 4s4p 3 +3d 10 4s 2 4p (4d+5d+6d+5s+6s+7s) in the odd parity system and 3d 10 4s 2 4p (5p+4f+5f)+3d 10 4s4p 2 (4d+5s)+3d 10 4p 4 in the even parity system have been studied. Relativistic Hartree–Fock (HFR) and least squares fitted (LSF) parametric calculations were used to interpret the observed spectrum. 120 Levels of Br IV have now been established, 58 being new. Among 424 spectral lines, 277 are newly classified. The levels 4s4p 35 S 2 , 4s 2 4p4d 3 F 4 and 4p5p ( 3 P 0,1 , 3 D 1,2 , 3 S 1 ) are revised. We estimate the accuracy of our measured wavelength for sharp and unblended lines to be ±0.005 Å. The ionization limit is determined as 385,390±100 cm −1 (47.782±0.012 eV). -- Highlights: • The spectrum of Br was recorded on a 3-m spectrograph with triggered spark source. • Atomic transitions for Br IV were identified to established new energy levels. • CI calculations with relativistic corrections were made for theoretical predictions. • Weighted oscillator strength (gf) and transition probabilities (gA) were calculated. • Ionization potential of Br IV was determined experimentally

Nevada Test Site Environmental Report 2005

International Nuclear Information System (INIS)

Cathy A. Wills

2006-01-01

The Nevada Test Site Environmental Report 2005 (NTSER) was prepared to meet the information needs of the public and the requirements and guidelines of the U.S. Department of Energy (DOE) for annual site environmental reports. Its purpose is to (1) report compliance status with environmental standards and requirements, (2) present results of environmental monitoring of radiological and nonradiological effluents, (3) report estimated radiological doses to the public from releases of radioactive material, (4) summarize environmental incidents of noncompliance and actions taken in response to them, (5) describe the NTS Environmental Management System and characterize its performance, and (6) highlight significant environmental programs and efforts

Nevada Test Site Environmental Report 2005

Energy Technology Data Exchange (ETDEWEB)

Cathy A. Wills

2006-10-01

The Nevada Test Site Environmental Report 2005 (NTSER) was prepared to meet the information needs of the public and the requirements and guidelines of the U.S. Department of Energy (DOE) for annual site environmental reports. Its purpose is to (1) report compliance status with environmental standards and requirements, (2) present results of environmental monitoring of radiological and nonradiological effluents, (3) report estimated radiological doses to the public from releases of radioactive material, (4) summarize environmental incidents of noncompliance and actions taken in response to them, (5) describe the NTS Environmental Management System and characterize its performance, and (6) highlight significant environmental programs and efforts.

High rate read-out of LaBr(Ce) scintillator with a fast digitizer

International Nuclear Information System (INIS)

Stevanato, L.; Cester, D.; Nebbia, G.; Viesti, G.; Neri, F.; Petrucci, S.; Selmi, S.; Tintori, C

2012-01-01

The energy resolution of a LaBr(Ce) detector has been studied as a function of the count rate up to 340 kHz by using a 12 bit 250 MS/s V1720 digitizer. The time resolution achieved by processing off line the digitized signals has been also determined. It appears that the energy resolution obtained with the digitizer is better than that achievable using standard NIM electronics. The time resolution yielded by the digitizer with a software CFTD is about δt=0.8 ns (FWHM), slightly worse with respect to δt=0.65 ns (FWHM) obtained from standard NIM. However, this time resolution lies well within the requirements for applications in Non-Destructive Analysis of large objects with tagged neutron beams.

Refurbishment programme for the BR2-reactor

Energy Technology Data Exchange (ETDEWEB)

Koonen, E [Centre d' Etude de l' Energie Nucleaire, Studiecentrum voor Kernenergie, BR2 Department, Boeretang, Mol (Belgium)

1992-07-01

BR2 is a high flux engineering test reactor, which differs from comparable material testing reactors by its specific core array (fig. 1). It is a heterogeneous, thermal, tank-in-pool type reactor, moderated by beryllium and light water, which serves also as coolant. The fuel elements consist of cylindrical assemblies loaded in channels materialized by hexagonal beryllium prisms. The central 200 mm channel is vertical, while all others are inclined and form a hyperbolical arrangement around the central one. This feature combines a very compact core with the requirement of sufficient space for individual access to all channels through penetrations in the top cover of the aluminium pressure vessel. Each channel may hold a fuel element, a control rod, an experiment, an irradiation device or a beryllium plug. The refurbishment Program According to the present programme of C.E.N./S.C.K., BR2 will be in operation until 1996. At that time, the beryllium matrix will reach its foreseen end-of-life. In order to continue operation beyond this point, a thorough refurbishment of the reactor is foreseen, in addition to the unavoidable replacement of the matrix, to ensure quality of the installation and compliance with modern standards. Some fundamental options have been taken as a starting point: BR2 will continue to be used as a classical MTR, i.e. fuel and material irradiations and safety experiments with some additional service-activities. The present configuration is optimized for that use and there is no specific experimental requirement to change the basic concepts and performance characteristics. From the customers viewpoint, it is desirable to go ahead with the well-known features of BR2, to maintain a high degree of availability and reliability and to minimize the duration of the long shutdown. It is also important to limit the amount of nuclear liabilities. So the objective of the refurbishment programme is the life extension of BR2 for about 15 years, corresponding to

Refurbishment programme for the BR2-reactor

International Nuclear Information System (INIS)

Koonen, E.

1992-01-01

BR2 is a high flux engineering test reactor, which differs from comparable material testing reactors by its specific core array (fig. 1). It is a heterogeneous, thermal, tank-in-pool type reactor, moderated by beryllium and light water, which serves also as coolant. The fuel elements consist of cylindrical assemblies loaded in channels materialized by hexagonal beryllium prisms. The central 200 mm channel is vertical, while all others are inclined and form a hyperbolical arrangement around the central one. This feature combines a very compact core with the requirement of sufficient space for individual access to all channels through penetrations in the top cover of the aluminium pressure vessel. Each channel may hold a fuel element, a control rod, an experiment, an irradiation device or a beryllium plug. The refurbishment Program According to the present programme of C.E.N./S.C.K., BR2 will be in operation until 1996. At that time, the beryllium matrix will reach its foreseen end-of-life. In order to continue operation beyond this point, a thorough refurbishment of the reactor is foreseen, in addition to the unavoidable replacement of the matrix, to ensure quality of the installation and compliance with modern standards. Some fundamental options have been taken as a starting point: BR2 will continue to be used as a classical MTR, i.e. fuel and material irradiations and safety experiments with some additional service-activities. The present configuration is optimized for that use and there is no specific experimental requirement to change the basic concepts and performance characteristics. From the customers viewpoint, it is desirable to go ahead with the well-known features of BR2, to maintain a high degree of availability and reliability and to minimize the duration of the long shutdown. It is also important to limit the amount of nuclear liabilities. So the objective of the refurbishment programme is the life extension of BR2 for about 15 years, corresponding to

BR2 Reactor: Irradiation of fuels

International Nuclear Information System (INIS)

Verwimp, A.

2005-01-01

Safe, reliable and economical operation of reactor fuels, both UO 2 and MOX types, requires in-pile testing and qualification up to high target burn-up levels. In-pile testing of advanced fuels for improved performance is also mandatory. The objectives of research performed at SCK-CEN are to perform Neutron irradiation of LWR (Light Water Reactor) fuels in the BR2 reactor under relevant operating and monitoring conditions, as specified by the experimenter's requirements and to improve the on-line measurements on the fuel rods themselves

Aagesta-BR3 Decommissioning Cost. Comparison and Benchmarking Analysis

Energy Technology Data Exchange (ETDEWEB)

Varley, Geoff [NAC International, Henley on Thames (United Kingdom)

2002-11-01

arising from the decontamination activity. A factor of 15 different in ion exchange resin volume is puzzling and no explanation has been found, other than that the volumes were 'estimated' rather than calculated in accordance with a clearly defined method statement. The work analysed for comparisons included preparation work before the actual dismantling of the primary pipes and the auxiliary circuits plus the actual cutting of the primary pipes into small pieces of 0.8 m long to fit in the chemical reactor of the BR3 decontamination process. The estimated grand total resources required was 4,734 hours, for a unit requirement of 740 hours/MT. This is very close to the Westinghouse Test reactor benchmark figure for this activity. The total resource requirements for primary pipework dismantling were dominated by the preparatory activities rather than the cutting activity itself. (abstract truncated)

In situ Spectroscopy of Solid-State Chemical Reaction in PbBr2-Deposited CsBr Crystals

Science.gov (United States)

Kondo, Shin-ichi; Matsunaga, Toshihiro; Saito, Tadaaki; Asada, Hiroshi

2003-09-01

It is possible to measure the fundamental optical absorption spectra of CsPbBr3 and Cs4PbBr6, whose stability is predicted by the study of phase diagram in the binary system CsBr-PbBr2, by means of in situ optical absorption and reflection spectroscopy of thermally induced solid-state chemical reaction in PbBr2-deposited CsBr crystals. On heavy annealing of the crystals, the Pb2+ ions are uniformly dispersed in the crystal matrix. The present experiment provides a novel method for measuring intrinsic optical absorption of ternary metal halides and also for in situ monitoring of doping metal halide crystal with impurities (metal ions or halogen ions).

SAVANNAH RIVER SITE ENVIRONMENTAL REPORT FOR 2005

Energy Technology Data Exchange (ETDEWEB)

Mamatey, A

2006-07-18

The ''Savannah River Site Environmental Report for 2005'' (WSRC-TR-2006-00007) is prepared for the U.S. Department of Energy (DOE) according to requirements of DOE Order 231.1A, ''Environment, Safety and Health Reporting'', and DOE Order 5400.5, ''Radiation Protection of the Public and Environment''. The report's purpose is to: present summary environmental data that characterize site environmental management performance; confirm compliance with environmental standards and requirements; highlight significant programs and efforts; and assess the impact of SRS operations on the public and the environment.

Continuum and discrete pulsed cavity ring down laser absorption spectra of Br2 vapor.

Science.gov (United States)

Sharma, Ramesh C; Huang, Hong-Yi; Chuang, Wang-Ting; Lin, King-Chuen

2005-07-01

The absorption cross-sections at room temperature are reported for the first time, of Br2 vapor in overlapping bound-free and bound-bound transition of A(3)pi1u Br2. We obtained discrete absorption cross-section in the rotational structure, the continuum absorption cross-sections, and were also able to measure the absorption cross-section in separate contribution of A(3)pi1u Br2. The absorption cross-sections are increasing with increasing excitation energy in the wavelength region 510-535 nm.

Contribution and influence of proceedings papers to citation impact in seven conference and journal-driven sub-fields of energy research 2005-11

DEFF Research Database (Denmark)

Ingwersen, Peter; Larsen, Birger; Garcia-Zorita, J. Carlos

2013-01-01

and Wave Energy, Geo-thermal, Bio-fuel and Bio-mass energy sub-fields. The analyses cover research and review articles as well as conference proceeding papers excluding meeting abstracts published 2005-09 and cited 2005-11 through Web of Science. Central findings are: The distribution across document types......This paper analyses the following seven sub-fields of Sustainable Energy Research with respect to the influence of conference paper dominance on citation patterns across citing and cited document types, overall sub-field and document type impacts and citedness: Wind Power, Renewable Energy, Solar...

Electronic parameters and top surface chemical stability of RbPb{sub 2}Br{sub 5}

Energy Technology Data Exchange (ETDEWEB)

Atuchin, V.V., E-mail: atuchin@thermo.isp.nsc.ru [Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk 90, 630090 (Russian Federation); Isaenko, L.I. [Laboratory of Crystal Growth, Institute of Geology and Mineralogy, SB RAS, Novosibirsk 90, 630090 (Russian Federation); Kesler, V.G. [Laboratory of Physical Principles for Integrated Microelectronics, Institute of Semiconductor Physics, SB RAS, Novosibirsk 90, 630090 (Russian Federation); Pokrovsky, L.D. [Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk 90, 630090 (Russian Federation); Tarasova, A.Yu. [Laboratory of Crystal Growth, Institute of Geology and Mineralogy, SB RAS, Novosibirsk 90, 630090 (Russian Federation)

2012-01-16

Highlights: Black-Right-Pointing-Pointer Bridgman growth of RbPb{sub 2}Br{sub 5} crystal. Black-Right-Pointing-Pointer Electronic structure measurements with XPS. Black-Right-Pointing-Pointer Optical crystalline surface fabrication. - Abstract: The RbPb{sub 2}Br{sub 5} crystal has been grown by Bridgman method. The electronic structure of RbPb{sub 2}Br{sub 5} has been measured with XPS for a powder sample. High chemical stability of RbPb{sub 2}Br{sub 5} surface is verified by weak intensity of O 1s core level recorded by XPS and structural RHEED measurements. Chemical bonding effects have been observed by the comparative analysis of element core levels and crystal structure of RbPb{sub 2}Br{sub 5} and several rubidium- and lead-containing bromides using binding energy difference parameters {Delta}{sub Rb} = (BE Rb 3d - BE Br 3d) and {Delta}{sub Pb} = (BE Pb 4f{sub 7/2} - BE Br 3d).

Energy Requirements in Critically Ill Patients

Science.gov (United States)

2018-01-01

During the management of critical illness, optimal nutritional support is an important key for achieving positive clinical outcomes. Compared to healthy people, critically ill patients have higher energy expenditure, thereby their energy requirements and risk of malnutrition being increased. Assessing individual nutritional requirement is essential for a successful nutritional support, including the adequate energy supply. Methods to assess energy requirements include indirect calorimetry (IC) which is considered as a reference method, and the predictive equations which are commonly used due to the difficulty of using IC in certain conditions. In this study, a literature review was conducted on the energy metabolic changes in critically ill patients, and the implications for the estimation of energy requirements in this population. In addition, the issue of optimal caloric goal during nutrition support is discussed, as well as the accuracy of selected resting energy expenditure predictive equations, commonly used in critically ill patients.

Energy Requirements in Critically Ill Patients.

Science.gov (United States)

Ndahimana, Didace; Kim, Eun-Kyung

2018-04-01

During the management of critical illness, optimal nutritional support is an important key for achieving positive clinical outcomes. Compared to healthy people, critically ill patients have higher energy expenditure, thereby their energy requirements and risk of malnutrition being increased. Assessing individual nutritional requirement is essential for a successful nutritional support, including the adequate energy supply. Methods to assess energy requirements include indirect calorimetry (IC) which is considered as a reference method, and the predictive equations which are commonly used due to the difficulty of using IC in certain conditions. In this study, a literature review was conducted on the energy metabolic changes in critically ill patients, and the implications for the estimation of energy requirements in this population. In addition, the issue of optimal caloric goal during nutrition support is discussed, as well as the accuracy of selected resting energy expenditure predictive equations, commonly used in critically ill patients.

Multiple Gamma-Ray Detection Capability of a CeBr3 Detector for Gamma Spectroscopy

Directory of Open Access Journals (Sweden)

A. A. Naqvi

2017-01-01

Full Text Available The newly developed cerium tribromide (CeBr3 detector has reduced intrinsic gamma-ray activity with gamma energy restricted to 1400–2200 keV energy range. This narrower region of background gamma rays allows the CeBr3 detector to detect more than one gamma ray to analyze the gamma-ray spectrum. Use of multiple gamma-ray intensities in elemental analysis instead of a single one improves the accuracy of the estimated results. Multigamma-ray detection capability of a cylindrical 75 mm × 75 mm (diameter × height CeBr3 detector has been tested by analyzing the chlorine concentration in water samples using eight chlorine prompt gamma rays over 517 to 8578 keV energies utilizing a D-D portable neutron generator-based PGNAA setup and measuring the corresponding minimum detection limit (MDC of chlorine. The measured MDC of chlorine for gamma rays with 517–8578 keV energies varies from 0.07 ± 0.02 wt% to 0.80 ± 0.24. The best value of MDC was measured to be 0.07 ± 0.02 wt% for 788 keV gamma rays. The experimental results are in good agreement with Monte Carlo calculations. The study has shown excellent detection capabilities of the CeBr3 detector for eight prompt gamma rays over 517–8578 keV energy range without significant background interference.

Estimating BrAC from transdermal alcohol concentration data using the BrAC estimator software program.

Science.gov (United States)

Luczak, Susan E; Rosen, I Gary

2014-08-01

Transdermal alcohol sensor (TAS) devices have the potential to allow researchers and clinicians to unobtrusively collect naturalistic drinking data for weeks at a time, but the transdermal alcohol concentration (TAC) data these devices produce do not consistently correspond with breath alcohol concentration (BrAC) data. We present and test the BrAC Estimator software, a program designed to produce individualized estimates of BrAC from TAC data by fitting mathematical models to a specific person wearing a specific TAS device. Two TAS devices were worn simultaneously by 1 participant for 18 days. The trial began with a laboratory alcohol session to calibrate the model and was followed by a field trial with 10 drinking episodes. Model parameter estimates and fit indices were compared across drinking episodes to examine the calibration phase of the software. Software-generated estimates of peak BrAC, time of peak BrAC, and area under the BrAC curve were compared with breath analyzer data to examine the estimation phase of the software. In this single-subject design with breath analyzer peak BrAC scores ranging from 0.013 to 0.057, the software created consistent models for the 2 TAS devices, despite differences in raw TAC data, and was able to compensate for the attenuation of peak BrAC and latency of the time of peak BrAC that are typically observed in TAC data. This software program represents an important initial step for making it possible for non mathematician researchers and clinicians to obtain estimates of BrAC from TAC data in naturalistic drinking environments. Future research with more participants and greater variation in alcohol consumption levels and patterns, as well as examination of gain scheduling calibration procedures and nonlinear models of diffusion, will help to determine how precise these software models can become. Copyright © 2014 by the Research Society on Alcoholism.

XeBr exciplex laser

International Nuclear Information System (INIS)

Searles, S.K.

1976-01-01

Laser emission from the recently discovered XeBr exciplex laser was investigated as a function of the partial pressures of Xe and Br 2 . An optical loss process appears to limit high-pressure operation

Elimination of nonspecific radioactivity from [{sup 76}Br]bromide in PET study with [{sup 76}Br]bromodeoxyuridine

Energy Technology Data Exchange (ETDEWEB)

Li Lu; Bergstroem, Mats E-mail: Mats.Bergstroem@pet.uu.se; Fasth, Karl-Johan; Wu Feng; Eriksson, Barbro; Laangstroem, Bengt

1999-10-01

[{sup 76}Br]Bromodeoxyuridine ([{sup 76}Br]BrdU) might allow a determination of proliferation in vivo using positron emission tomography (PET), but only with consideration of organ nonspecific radioactivity constituted by [{sup 76}Br]bromide. A first study assessed the potential of diuretics to eliminate [{sup 76}Br]bromide. [{sup 76}Br]Bromide was injected in the vein of rats and different diuretic combinations were given. Urine was collected and radioactivity measured. Torasemide plus sodium chloride gave better {sup 76}Br elimination than the other diuretics. In a second experiment, rats were given [{sup 76}Br]BrdU. After the radioactivity injection, the rats of the treatment group were given torasemide plus NaCl. At 44 h after the radioactivity injection, the radioactivity concentration and the fraction incorporated into DNA were measured in different organs. Using diuretics, the elimination of [{sup 76}Br]bromide was increased. The radioactivity decreased 30-50% in most of the organs but the highest radioactivity uptake was found in the organs with more active DNA synthesis. This method may facilitate the use of [{sup 76}Br]BrdU as a tracer for DNA synthesis using PET.

Aagesta-BR3 Decommissioning Cost. Comparison and Benchmarking Analysis

International Nuclear Information System (INIS)

Varley, Geoff

2002-11-01

decontamination activity. A factor of 15 different in ion exchange resin volume is puzzling and no explanation has been found, other than that the volumes were 'estimated' rather than calculated in accordance with a clearly defined method statement. The work analysed for comparisons included preparation work before the actual dismantling of the primary pipes and the auxiliary circuits plus the actual cutting of the primary pipes into small pieces of 0.8 m long to fit in the chemical reactor of the BR3 decontamination process. The estimated grand total resources required was 4,734 hours, for a unit requirement of 740 hours/MT. This is very close to the Westinghouse Test reactor benchmark figure for this activity. The total resource requirements for primary pipework dismantling were dominated by the preparatory activities rather than the cutting activity itself. A comparison with the Aagesta cost estimate would be possible only if a more detailed breakdown of projected manhour information could be provided for Aagesta. The basis for the preparatory work and actual removal of the Aagesta RPV is unclear and may not have been particularly rigorous. Comparison with BR3 benchmarking data suggests that the Aagesta estimate for the RPV could be significantly low. However, actual experience of steam generator (SG) removal at Aagesta provides evidence of very efficient execution of similar work, which might contradict the BR3 experience. The available data does not support reaching a detailed conclusion. A clear possibility is that the nature of the two jobs (SG and RPV) is radically different, either due to size, radiological conditions, physical access etc., or a combination of all factors, with RPV work being more demanding. If this is correct, the Aagesta SG experience may not be particularly relevant, whilst the BR3 experience would indicate the need for further scrutiny of the Aagesta RPV estimate

Partial structures in molten AgBr

Energy Technology Data Exchange (ETDEWEB)

Ueno, Hiroki [Department of Condensed Matter Chemistry and Physics, Faculty of Sciences, Kyushu University, 4-2-1 Ropponmatsu, Chuo-ku, Fukuoka 810-8560 (Japan)], E-mail: ueno@gemini.rc.kyushu-u.ac.jp; Tahara, Shuta [Faculty of Pharmacy, Niigata University of Pharmacy and Applied Life Science, Higashijima, Akiha-ku, Niigata 956-8603 (Japan); Kawakita, Yukinobu [Department of Physics, Faculty of Sciences, Kyushu University, 4-2-1 Ropponmatsu, Chuo-ku, Fukuoka 810-8560 (Japan); Kohara, Shinji [Research and Utilization Division, Japan Synchrotron Radiation Research Institute (JASRI, SPring-8), 1-1-1 Koto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Takeda, Shin' ichi [Department of Physics, Faculty of Sciences, Kyushu University, 4-2-1 Ropponmatsu, Chuo-ku, Fukuoka 810-8560 (Japan)

2009-02-21

The structure of molten AgBr has been studied by means of neutron and X-ray diffractions with the aid of structural modeling. It is confirmed that the Ag-Ag correlation has a small but well-defined first peak in the partial pair distribution function whose tail penetrates into the Ag-Br nearest neighbor distribution. This feature on the Ag-Ag correlation is intermediate between that of molten AgCl (non-superionic melt) and that of molten AgI (superionic melt). The analysis of Br-Ag-Br bond angle reveals that molten AgBr preserves a rocksalt type local ordering in the solid phase, suggesting that molten AgBr is clarified as non-superionic melt like molten AgCl.

Investigations on the system Te/O/Br

International Nuclear Information System (INIS)

Oppermann, H.; Kunze, G.; Wolf, E.; Titov, V.A.; Kokovin, G.A.

1978-01-01

The melting point diagram of the system TeBr 4 -TeO 2 was obtained by total pressure measurements and DTA measurements. A congruent melting composition Te 6 O 11 Br 2 exists, the melting point is 570 0 C. The enthalpy of formation and the standard entropy of the species TeOBr 2 ,g was derived from measurements of the total pressure over Te 6 O 11 Br 2 /TeBr 4 and from the transport behaviour of the TeO 2 with Br 2 . From the decomposition-pressure measurements over Te 6 O 11 Br 2 /TeO 2 follow the partial pressures. The enthalpy of formation ΔH 0 (Te 6 O 11 Br 2 ,f,298) -453.5 kcal/Mol was obtained from the enthalpy of solution. The transport-behaviour of TeO 2 with HBr, TeBr 4 and Br 2 and that of Te 6 O 11 Br 2 is clear with the thermodynamic data of TeOBr 2 . (author)

Changes in consumption of food away from home and intakes of energy and other nutrients among US working-age adults, 2005-2014.

Science.gov (United States)

Todd, Jessica E

2017-12-01

To document changes in consumption of food away from home (FAFH) and intakes of selected nutrients by working-age adults between 2005-06 and 2013-14, covering the most recent recessionary period and recovery. Means were compared across survey rounds relative to 2005-06. Multivariate regression was used to account for changes in demographic characteristics over time. National Health and Nutrition Examination Survey (NHANES), 2005-2014. Working-age adults born in 1951-80 (n 12 129) and adolescents and young adults born in 1981-90 (n 5197) who reported day 1 dietary intake data. Approximately 34 % of energy consumed by working-age adults came from FAFH (14 % from fast foods) in 2005-06. Levels of FAFH consumption were lowest in 2009-10, at 28 and 11 % of energy from FAFH and fast foods, respectively. Percentage of energy from fast foods was 1·9 percentage points higher in 2013-14. Percentage of energy from saturated fat and total mg of cholesterol consumed were lower in 2009-14, while intake of fibre was higher in 2011-14. At-home foods had less saturated fat and more fibre in 2009-14. The greater the percentage of energy from FAFH in the day, the greater the intakes of fat and cholesterol. Percentage of energy from FAFH was highest among those born in 1981-90 and lowest among those born in 1951-60. FAFH is a significant source of energy, fat and cholesterol among working-age adults. Menu labelling may lower FAFH's energy content and make it easier for consumers to choose more healthful items.

Polymeric anionic networks using dibromine as a crosslinker; the preparation and crystal structure of [(C4H9)4N]2[Pt2Br10].(Br2)7 and [(C4H9)4N]2[PtBr4Cl2].(Br2)6.

Science.gov (United States)

Berkei, Michael; Bickley, Jamie F; Heaton, Brian T; Steiner, Alexander

2002-09-21

The reaction of M[PtX3(CO)] (M+ = [(C4H9)4N]+, X = Br, Cl) with an excess of Br2 gives the new platinum(IV) salts, [(C4H9)4N]2[Pt2Br10].(Br2)7, 1, and [(C4H9)4N]2[PtBr4Cl2].(Br2)6, 2, which, in the solid state, contain strong Br Br interactions resulting in the formation of polymeric networks; they could provide useful solid storage reservoirs for elemental bromine.

First Principle Quantum Description of the Energetics Associated with LaBr3, LaCl3, and Ce Doped Scintillators

International Nuclear Information System (INIS)

Michael E. McIlwain; Da Gao; Nick Thompson

2007-01-01

Considerable interest is given to the excellent scintillation properties of cerium doped lanthanum chloride (LaCl3) and lanthanum bromide (LaBr3). The scintillation efficiencies are much greater than other materials, even those containing cerium. This high efficiency is attributed to the high mobility of electrons and holes, unique placement of the cerium 5d states within the band gap, and energy of the band gap. To better understand the scintillation process and better define the nature of the Self Trapped Exciton (STE) within these unique scintillation materials, density functional theory (DFT), and Ab-initio (HF-MP2) calculations are reported. DFT calculations have yielded a qualitative description of the orbital composition and energy distribution of the band structure in the crystalline material. MP2 and single configuration interaction calculations have provided quantitative values for the band gap and provided energies for the possible range of excited states created following hole and electron creation. Based on this theoretical treatment, one possible description of the STE is the combination of Vk center (Br2-1) and LaBr+1 species that recombine to form a distorted geometry LaBr3* (triplet state). Depending on the distance between the LaBr and Br2, the STE emission band can be reproduced

2005 DAtF winter meeting - pleading in favor of a sensible energy mix

International Nuclear Information System (INIS)

2005-01-01

The year's Winter Meeting of Deutsches Atomforum, which was held under the general heading of 'Pleading in Favor of a Sensible Energy Mix', dealt with the large variety of aspects and perspectives of this important key topic, also with respect to the sustainability factors, environment, economy, and social aspects. Twelve contributions, or statements, by representatives from politics, industry, society, and research covered different aspects of a 'sensible energy mix'. A round of politicians debated the subject controversially. The meeting, which was attended by more than 250 participants, thus opened 2005 with an interesting presentation of present and future topics of the power supply debate. (orig.)

Institutional Plan FY 2001-2005

Energy Technology Data Exchange (ETDEWEB)

Chartock, Michael; Hansen, Todd, editors

2000-07-01

The FY 2001-2005 Institutional Plan provides an overview of the Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab, the Laboratory) mission, strategic plan, initiatives, and the resources required to fulfill its role in support of national needs in fundamental science and technology, energy resources, and environmental quality. To advance the Department of Energy's ongoing efforts to define the Integrated Laboratory System, the Berkeley Lab Institutional Plan reflects the strategic elements of our planning efforts. The Institutional Plan is a management report that supports the Department of Energy's mission and programs and is an element of the Department of Energy's strategic management planning activities, developed through an annual planning process. The Plan supports the Government Performance and Results Act of 1993 and complements the performance-based contract between the Department of Energy and the Regents of the University of California. It identifies technical and administrative directions in the context of the national energy policy and research needs and the Department of Energy's program planning initiatives. Preparation of the Plan is coordinated by the Office of Planning and Communications from information contributed by Berkeley Lab's scientific and support divisions.

Gamma-ray spectroscopy in the decay of (83)Se to levels of (83)Br.

Science.gov (United States)

Krane, K S

2015-03-01

High-resolution γ ray spectroscopy experiments have been done to study the emissions from the radioactive decay of 22-min (83g)Se produced from neutron capture using samples of enriched (82)Se. Energy and intensity values have been obtained to roughly an order of magnitude greater precision than in previous studies. Based on energy sums, 2 new levels are proposed in the daughter (83)Br and one previously proposed level is shown to be doubtful. Some 25 new transitions appear to decay with the (83)Se halflife, about half of which can be accommodated among the previous or newly proposed levels. Several previous γ ray placements are shown to be inconsistent with the new determinations of the (83)Br energy levels, but cannot be accommodated anywhere else among the known levels. As a result of the missing γ ray placements, some of the β branchings in the decay to levels of (83)Br appear to be negative. Gamma rays from the 2.4-h decay of the daughter (83)Br to levels of (83)Kr have also been observed, along with decays of (81g)(,m)Se present as a small impurity in the enriched samples and also as a strong component in irradiated samples of natural Se. Copyright © 2014 Elsevier Ltd. All rights reserved.

Extended analysis of fifth spectrum of bromine: Br V

International Nuclear Information System (INIS)

Riyaz, A.; Tauheed, A.; Rahimullah, K.

2014-01-01

The fifth spectrum of bromine (Br V) has been studied in the 200–2400 Å wavelength region. The spectrum was photographed on a 3-m normal incidence vacuum spectrograph at the St. Francis Xavier University, Antigonish (Canada) and 6.65-m grazing incidence spectrograph at the Zeeman laboratory (Amsterdam). The light sources used were a triggered spark and sliding spark. The ground configuration of Br V is 4s 2 4p. The excited configurations 4s4p 2 +4s 2 (4d+5d+5s+6s+7s+5g+6g)+4s4p(5p+4f)+4p 2 4d in the even parity system and the 4p 3 +4s 2 (5p+6p+7p+4f)+4s4p4d+4s4p5s configurations in the odd parity system have been studied. Relativistic Hartree–Fock (HFR) and least squares fitted (LSF) parametric calculations have been used to interpret the observed spectrum. 99 levels of Br V have now been established, 43 being new. Among 394 classified spectral lines, 181 are newly classified. The level 4s 2 7s 2 S 1/2 is revised. We estimate the accuracy of our measured wavelengths for sharp and unblended lines to be±0.005 Å. The ionization limit is determined as 479,657±200 cm −1 (59.470±0.025 eV). - Highlights: • The spectrum of Br was recorded on a 3-m spectrograph with triggered spark source. • Atomic transitions for Br V were identified to established new energy levels. • CI calculations with relativistic corrections were made for theoretical predictions. • Weighted oscillator strength (gf) and transition probabilities (gA) were calculated. • Ionization potential of Br V was determined experimentally

Novel Bi/BiOBr/AgBr composite microspheres: Ion exchange synthesis and photocatalytic performance

Science.gov (United States)

Lyu, Jianchang; Li, Zhenlu; Ge, Ming

2018-06-01

Novel Bi/BiOBr/AgBr composite microspheres were prepared by a rational in situ ion exchange reaction between Bi/BiOBr microspheres and AgNO3. The characteristic of the as-obtained ternary microspheres was tested by X-ray diffraction (XRD), energy dispersive X-ray spectrometer (EDS), scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (UV-vis DRS) and photoluminescence (PL). Under visible light irradiation, Bi/BiOBr/AgBr microspheres exhibited an excellent photocatalytic efficiency for rhodamine B (RhB) degradation, which was about 1.4 and 4.9 times as high as that of Bi/BiOBr and BiOBr/AgBr, demonstrating that the highest separation efficiency of charge carriers in the heterostructured Bi/BiOBr/AgBr. The photocatalytic activity of Bi/BiOBr/AgBr microspheres just exhibited a slight decrease after three consecutive cycles. The photocatalytic mechanism investigation confirmed that the superoxide radicals (O2•-) were the dominant reactive oxygen species for RhB degradation in Bi/BiOBr/AgBr suspension.

Uranium 2005 Resources, Production and Demand

CERN Document Server

Organisation for Economic Cooperation and Development. Paris. Nuclear Energy Agency

2006-01-01

Published every other year, Uranium Resources, Production, and Demand, or the "Red Book" as it is commonly known, is jointly prepared by the OECD Nuclear Energy Agency and the International Atomic Energy Agency. It is the recognised world reference on uranium and is based on official information received from 43 countries. This 21st edition presents the results of a thorough review of world uranium supplies and demand as of 1st January 2005 and provides a statistical profile of the world uranium industry in the areas of exploration, resource estimates, production and reactor-related requirements. It provides substantial new information from all major uranium production centres in Africa, Australia, Central Asia, Eastern Europe and North America. Projections of nuclear generating capacity and reactor-related uranium requirements through 2025 are provided as well as a discussion of long-term uranium supply and demand issues. This edition focuses on recent price and production increases that could signal major c...

Scientific evaluation at the French Atomic Energy Commission (CEA). 2005-2006 annual report

International Nuclear Information System (INIS)

2006-01-01

This report aims at presenting the scientific evaluation activities carried out at the CEA during the years 2005-2006. The evaluation system is described in detail. It comprises two aspects: the evaluation of the scientific policy implemented by the scientific Council and by the visiting committee of the CEA, and the evaluation of the laboratories, performed by a pool of 36 scientific councils. The evaluation by external and independent parties is the key point of this system. This document makes a status of the evaluations performed in 2005 and 2006. It presents a synthesis of the conclusions of the evaluation authorities. The actions implemented by the CEA to take into consideration the recommendations are also reported with the improvements noticed. The two topics examined by the scientific Committee and by the visiting committee were dealing with the energy domain, which is a strategic issue for the CEA. The examination of the researches on future nuclear reactors and on new energy technologies have shown the major role played by the CEA in the recent advances in these domains. About 95% of the laboratories activity was examined during the 2002-2005 period. The richness of the remarks and recommendations made by the scientific councils should allow the CEA to improve the quality and relevance of its research works. The start-up of the 2006-2009 evaluation cycle has been the occasion to modify the evaluation of some research domains in order to take into account the evolution of programs. The evaluation system of the CEA is highly consistent with the AERES principles. Its implementation, adapted to each type of activity (fundamental research, applied research, technological developments) allows the CEA to follow up a permanent improvement approach. (J.S.)

Energy requirement of some energy resources

International Nuclear Information System (INIS)

Chapman, P.F.; Hemming, D.F.

1976-01-01

The energy requirements for the sources of energy under examination are expressed as the fraction of total energy consumed in the production of a unit of gross output. Clearly there are vast differences between the energy requirements of these sources of fuels. Using energy analysis it is possible to indicate points of futility where no net energy is produced (i.e. Xsub(f) = 1). For North Sea oil fields using current technology, this appears to occur at a field size of 100,000-200,000 tons of recoverable reserves of oil. For oil shales exploited using above-ground retorting, the outer limit is at a grade of about 5 gal/ton. For uranium ores used to fuel a burner reactor, the cut-off grade was found to be of the order of 20 ppm. However, it should be remembered that at Xsub(f) = 1, there is no net output and the price of the fuel would be infinite. Because of payments to labour and capital, the upper limit of economic viability may well occur at values of Xsub(f) from 0.1 to 0.2. Thus uranium ores of a grade of 100 ppm U 3 O 8 or less may not be ecomically viable using current burner reactors and this in turn implies an upper bound for the total thermal reactor capacity. For oil shales exploited using above-ground retorting and room-and-pillar mining 15-20 gal/ton shale may represent the upper limit of economic viability, depending on the efficiency that can be achieved in a commercial-scale retort

Postsynthesis Transformation of Insulating Cs4PbBr6 Nanocrystals into Bright Perovskite CsPbBr3 through Physical and Chemical Extraction of CsBr.

Science.gov (United States)

Palazon, Francisco; Urso, Carmine; De Trizio, Luca; Akkerman, Quinten; Marras, Sergio; Locardi, Federico; Nelli, Ilaria; Ferretti, Maurizio; Prato, Mirko; Manna, Liberato

2017-10-13

Perovskite-related Cs 4 PbBr 6 nanocrystals present a "zero-dimensional" crystalline structure where adjacent [PbBr 6 ] 4- octahedra do not share any corners. We show in this work that these nanocrystals can be converted into "three-dimensional" CsPbBr 3 perovskites by extraction of CsBr. This conversion drastically changes the optoelectronic properties of the nanocrystals that become highly photoluminescent. The extraction of CsBr can be achieved either by thermal annealing (physical approach) or by chemical reaction with Prussian Blue (chemical approach). The former approach can be simply carried out on a dried film without addition of any chemicals but does not yield a full transformation. Instead, reaction with Prussian Blue in solution achieves a full transformation into the perovskite phase. This transformation was also verified on the iodide counterpart (Cs 4 PbI 6 ).

Chalcogen- and halogen-bonds involving SX2 (X = F, Cl, and Br) with formaldehyde.

Science.gov (United States)

Mo, Lixin; Zeng, Yanli; Li, Xiaoyan; Zhang, Xueying; Meng, Lingpeng

2016-07-01

The capacity of SX2 (X = F, Cl, and Br) to engage in different kinds of noncovalent bonds was investigated by ab initio calculations. SCl2 (SBr2) has two σ-holes upon extension of Cl (Br)-S bonds, and two σ-holes upon extension of S-Cl (Br) bonds. SF2 contains only two σ-holes upon extension of the F-S bond. Consequently, SCl2 and SBr2 form chalcogen and halogen bonds with the electron donor H2CO while SF2 forms only a chalcogen bond, i.e., no F···O halogen bond was found in the SF2:H2CO complex. The S···O chalcogen bond between SF2 and H2CO is the strongest, while the strongest halogen bond is Br···O between SBr2 and H2CO. The nature of these two types of noncovalent interaction was probed by a variety of methods, including molecular electrostatic potentials, QTAIM, energy decomposition, and electron density shift maps. Termolecular complexes X2S···H2CO···SX'2 (X = F, Cl, Br, and X' = Cl, Br) were constructed to study the interplay between chalcogen bonds and halogen bonds. All these complexes contained S···O and Cl (Br)···O bonds, with longer intermolecular distances, smaller values of electron density, and more positive three-body interaction energies, indicating negative cooperativity between the chalcogen bond and the halogen bond. In addition, for all complexes studied, interactions involving chalcogen bonds were more favorable than those involving halogen bonds. Graphical Abstract Molecular electrostatic potential and contour map of the Laplacian of the electron density in Cl2S···H2CO···SCl2 complex.

Dicty_cDB: FC-BR23 [Dicty_cDB

Lifescience Database Archive (English)

Full Text Available FC (Link to library) FC-BR23 (Link to dictyBase) - - - Contig-U15008-1 FC-BR23Z (Li...nk to Original site) - - FC-BR23Z 641 - - - - Show FC-BR23 Library FC (Link to library) Clone ID FC-BR23 (Li.../dictycdb.biol.tsukuba.ac.jp/CSM/FC/FC-BR/FC-BR23Q.Seq.d/ Representative seq. ID FC-BR2...3Z (Link to Original site) Representative DNA sequence >FC-BR23 (FC-BR23Q) /CSM/FC/FC-BR/FC-BR23Q.Seq....9 0.0 SLA211 (SLA211Q) /CSM/SL/SLA2-A/SLA211Q.Seq.d/ 1029 0.0 FC-BR23 (FC-BR23Q) /CSM/FC/FC-BR/FC-BR2

Balloon-borne stratospheric BrO measurements: comparison with Envisat/SCIAMACHY BrO limb profiles

Directory of Open Access Journals (Sweden)

M. Dorf

2006-01-01

Full Text Available For the first time, results of four stratospheric BrO profiling instruments, are presented and compared with reference to the SLIMCAT 3-dimensional chemical transport model (3-D CTM. Model calculations are used to infer a BrO profile validation set, measured by 3 different balloon sensors, for the new Envisat/SCIAMACHY (ENVIronment SATellite/SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY satellite instrument. The balloon observations include (a balloon-borne in situ resonance fluorescence detection of BrO (Triple, (b balloon-borne solar occultation DOAS measurements (Differential Optical Absorption Spectroscopy of BrO in the UV, and (c BrO profiling from the solar occultation SAOZ (Systeme d'Analyse par Observation Zenithale balloon instrument. Since stratospheric BrO is subject to considerable diurnal variation and none of the measurements are performed close enough in time and space for a direct comparison, all balloon observations are considered with reference to outputs from the 3-D CTM. The referencing is performed by forward and backward air mass trajectory calculations to match the balloon with the satellite observations. The diurnal variation of BrO is considered by 1-D photochemical model calculation along the trajectories. The 1-D photochemical model is initialised with output data of the 3-D model with additional constraints on the vertical transport, the total amount and photochemistry of stratospheric bromine as given by the various balloon observations. Total [Bry]=(20.1±2.5 pptv obtained from DOAS BrO observations at mid-latitudes in 2003, serves as an upper limit of the comparison. Most of the balloon observations agree with the photochemical model predictions within their given error estimates. First retrieval exercises of BrO limb profiling from the SCIAMACHY satellite instrument on average agree to around 20% with the photochemically-corrected balloon observations of the remote sensing instruments (SAOZ

A Theoretical Study of the Oxidation of Hg0 to HgBr2 in the Troposphere

DEFF Research Database (Denmark)

Goodsite, M. E.; Plane, J. M C; Skov, H.

2004-01-01

The oxidation of elemental mercury (Hg0) to the divalent gaseous mercury dibromide (HgBr2) has been proposed to account for the removal of Hg0 during depletion events in the springtime Arctic. The mechanism of this process is explored in this paper by theoretical calculations of the relevant rate...... coefficients. Rice-Ramsberger-Kassel-Marcus (RRKM) theory, together with ab initio quantum calculations where required, are used to estimate the following: recombination rate coefficients of Hg with Br, I, and O; the thermal dissociation rate coefficient of HgBr; and the recombination rate coefficients of Hg......Br with Br, I, OH, and O2. A mechanism based on the initial recombination of Hg with Br, followed by the addition of a second radical (Br, I, or OH) in competition with thermal dissociation of HgBr, is able to account for the observed rate of Hg 0 removal, both in Arctic depletion events and at lower...

Energikravene i BR15

DEFF Research Database (Denmark)

Kragh, Jesper; Aggerholm, Søren

2015-01-01

Bygningsreglement 2015 – BR15 – gælder fra 1. januar 2016 med en overgangsfase frem til 1. juli 2016. Det bygger videre på BR10 og de tidligere udmeldte krav til nybyggeriet frem mod 2020. I denne kvikguide får du hurtigt overblik over, hvordan du sikrer, at de bygninger, du er med til at opføre...... eller renovere, lever op til BR15’s energikrav. Disse krav findes primært i reglementets kapitel 7 om energiforbrug og i kapitel 8 om installationer samt i kapitel 6 om indeklima....

CISBAT 2005 proceedings. Renewables in a changing climate - Innovation in building envelopes and environmental systems; CISBAT 2005 proceedings. Energies renouvelables et climat - Enveloppes et systemes environnementaux innovatifs

Energy Technology Data Exchange (ETDEWEB)

Scartezzini, J L [ed.

2005-07-01

These proceedings include the contributions presented at the 2005 CISBAT conference, held in Lausanne, Switzerland. Hosted by the Swiss Federal Institute of Technology (EPFL) in Lausanne and jointly organised by the Solar Energy and Buildings Physics Laboratory at the EPFL, Cambridge University and the Massachusetts Institute of Technology (MIT), this international conference looked at 'Innovation in building envelopes and environmental systems'. Along with three keynote presentations on climate change, the use of renewables in the European Union and Swiss policies on solar energy, these 632-page conference proceedings include the conference's 106 presentations grouped in 10 sections. These cover the following topics: Design and renovation of building envelopes (33 contributions); solar collectors (16 contributions); active and passive cooling (9 contributions); indoor environment quality and health (10 contributions); optimisation of daylighting and electric lighting (5 contributions); advanced building control systems (2 contributions); environmental impacts of construction (4 contributions); networks and decentralised energy production (1 contribution); sustainable urban development (12 contributions) and software and new information technologies (14 contributions). Organised each second year, the two-day CISBAT international conference 2005 attracted more than 200 participants from all over the world.

CISBAT 2005 proceedings. Renewables in a changing climate - Innovation in building envelopes and environmental systems; CISBAT 2005 proceedings. Energies renouvelables et climat - Enveloppes et systemes environnementaux innovatifs

Energy Technology Data Exchange (ETDEWEB)

Scartezzini, J. L. (ed.)

2005-07-01

These proceedings include the contributions presented at the 2005 CISBAT conference, held in Lausanne, Switzerland. Hosted by the Swiss Federal Institute of Technology (EPFL) in Lausanne and jointly organised by the Solar Energy and Buildings Physics Laboratory at the EPFL, Cambridge University and the Massachusetts Institute of Technology (MIT), this international conference looked at 'Innovation in building envelopes and environmental systems'. Along with three keynote presentations on climate change, the use of renewables in the European Union and Swiss policies on solar energy, these 632-page conference proceedings include the conference's 106 presentations grouped in 10 sections. These cover the following topics: Design and renovation of building envelopes (33 contributions); solar collectors (16 contributions); active and passive cooling (9 contributions); indoor environment quality and health (10 contributions); optimisation of daylighting and electric lighting (5 contributions); advanced building control systems (2 contributions); environmental impacts of construction (4 contributions); networks and decentralised energy production (1 contribution); sustainable urban development (12 contributions) and software and new information technologies (14 contributions). Organised each second year, the two-day CISBAT international conference 2005 attracted more than 200 participants from all over the world.

Solvation dynamics through Raman spectroscopy: hydration of Br2 and Br3(-), and solvation of Br2 in liquid bromine.

Science.gov (United States)

Branigan, Edward T; Halberstadt, N; Apkarian, V A

2011-05-07

Raman spectroscopy of bromine in the liquid phase and in water illustrates uncommon principles and yields insights regarding hydration. In liquid Br(2), resonant excitation over the B((3)Π(0u)(+)) ← X((1)Σ(g)(+)) valence transition at 532 nm produces a weak resonant Raman (RR) progression accompanied by a five-fold stronger non-resonant (NR) scattering. The latter is assigned to pre-resonance with the C-state, which in turn must be strongly mixed with inter-molecular charge transfer states. Despite the electronic resonance, RR of Br(2) in water is quenched. At 532 nm, the homogeneously broadened fundamental is observed, as in the NR case at 785 nm. The implications of the quenching of RR scattering are analyzed in a simple, semi-quantitative model, to conclude that the inertial evolution of the Raman packet in aqueous Br(2) occurs along multiple equivalent water-Br(2) coordinates. In distinct contrast with hydrophilic hydration in small clusters and hydrophobic hydration in clathrates, it is concluded that the hydration shell of bromine in water consists of dynamically equivalent fluxional water molecules. At 405 nm, the RR progression of Br(3)(-) is observed, accompanied by difference transitions between the breathing of the hydration shell and the symmetric stretch of the ion. The RR scattering process in this case can be regarded as the coherent photo-induced electron transfer to the solvent and its radiative back-transfer.

Quantitative analysis and efficiency study of PSD methods for a LaBr{sub 3}:Ce detector

Energy Technology Data Exchange (ETDEWEB)

Zeng, Ming; Cang, Jirong [Key Laboratory of Particle & Radiation Imaging(Tsinghua University), Ministry of Education (China); Department of Engineering Physics, Tsinghua University, Beijing 100084 (China); Zeng, Zhi, E-mail: zengzhi@tsinghua.edu.cn [Key Laboratory of Particle & Radiation Imaging(Tsinghua University), Ministry of Education (China); Department of Engineering Physics, Tsinghua University, Beijing 100084 (China); Yue, Xiaoguang; Cheng, Jianping; Liu, Yinong; Ma, Hao; Li, Junli [Key Laboratory of Particle & Radiation Imaging(Tsinghua University), Ministry of Education (China); Department of Engineering Physics, Tsinghua University, Beijing 100084 (China)

2016-03-21

The LaBr{sub 3}:Ce scintillator has been widely studied for nuclear spectroscopy because of its optimal energy resolution (<3%@ 662 keV) and time resolution (~300 ps). Despite these promising properties, the intrinsic radiation background of LaBr{sub 3}:Ce is a critical issue, and pulse shape discrimination (PSD) has been shown to be an efficient potential method to suppress the alpha background from the {sup 227}Ac. In this paper, the charge comparison method (CCM) for alpha and gamma discrimination in LaBr{sub 3}:Ce is quantitatively analysed and compared with two other typical PSD methods using digital pulse processing. The algorithm parameters and discrimination efficiency are calculated for each method. Moreover, for the CCM, the correlation between the CCM feature value distribution and the total charge (energy) is studied, and a fitting equation for the correlation is inferred and experimentally verified. Using the equations, an energy-dependent threshold can be chosen to optimize the discrimination efficiency. Additionally, the experimental results show a potential application in low-activity high-energy γ measurement by suppressing the alpha background.

Scientific evaluation at the French Atomic Energy Commission (CEA). 2005-2006 annual report; L'evaluation scientifique au CEA. Rapport annuel 2005-2006

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-07-01

This report aims at presenting the scientific evaluation activities carried out at the CEA during the years 2005-2006. The evaluation system is described in detail. It comprises two aspects: the evaluation of the scientific policy implemented by the scientific Council and by the visiting committee of the CEA, and the evaluation of the laboratories, performed by a pool of 36 scientific councils. The evaluation by external and independent parties is the key point of this system. This document makes a status of the evaluations performed in 2005 and 2006. It presents a synthesis of the conclusions of the evaluation authorities. The actions implemented by the CEA to take into consideration the recommendations are also reported with the improvements noticed. The two topics examined by the scientific Committee and by the visiting committee were dealing with the energy domain, which is a strategic issue for the CEA. The examination of the researches on future nuclear reactors and on new energy technologies have shown the major role played by the CEA in the recent advances in these domains. About 95% of the laboratories activity was examined during the 2002-2005 period. The richness of the remarks and recommendations made by the scientific councils should allow the CEA to improve the quality and relevance of its research works. The start-up of the 2006-2009 evaluation cycle has been the occasion to modify the evaluation of some research domains in order to take into account the evolution of programs. The evaluation system of the CEA is highly consistent with the AERES principles. Its implementation, adapted to each type of activity (fundamental research, applied research, technological developments) allows the CEA to follow up a permanent improvement approach. (J.S.)

Measurement of the ratio of branching ratios BR(B+ → J/ψK+)/BR(B0 → J/φK0) and BR(B+ → J/ψK+)/BR(B+ → J/ψK*+)

International Nuclear Information System (INIS)

Atavales, J. B. G.

1995-01-01

A preliminary measurement of the ratio of branching ratios BR(B + → J/ψK + )/BR(B 0 → J/ψK 0 ) and BR(B + → J/ψK + )/BR(B + → J/ψK *+ ) is made by fully reconstructing each mode, where J/ψ → μ + μ - , K *+ → K 0 s π + and K 0 s → π + π - . The data were taken with the CDF detector during the 1993 run. The total integrated luminosity is ∼ 20pb -1 resulting in a sample of about 170 J/ψK ± , 50 J/ψK 0 S and 25 J/ψK *± candidate events. The results will be reported

Measurement of cross sections producing short-lived nuclei by 14 MeV neutron. Br, Te, Dy, Ho, Yb

Energy Technology Data Exchange (ETDEWEB)

Sakane, H.; Matsumoto, T.; Yamamoto, H.; Kawade, K. [Nagoya Univ. (Japan); Iida, T.; Takahashi, A.

1997-03-01

Nine neutron activation cross sections producing the nuclei with half-lives between 2 min and 57 min have been measured at energy range between 13.4 and 14.9 MeV for Br, Te, Dy, Ho, Yb. The cross sections of {sup 81}Br(n,p){sup 81m}Se, {sup 128}Te(n,p){sup 128m}Sb, {sup 128}Te(n,{alpha}){sup 125m}Sn, {sup 164}Dy(n,p){sup 164}Tb, {sup 165}Ho(n,{alpha}){sup 162}Tb, {sup 176}Yb(n,p){sup 176}Tm were newly obtained at the six energy points between 13.4-14.9 MeV, although the previous results have been obtained at one energy point. {sup 79}Br(n,2n){sup 78}Br, {sup 164}Dy(n,p){sup 164}Tb are compared with evaluated data of JENDL-3.2. The evaluations for these reactions agree reasonably well with experimental results. The cross sections of (n,p) reaction are compared with systematics by Kasugai et. al. The systematics agrees with experimental results. (author)

Annual Site Environmental Report Calendar Year 2005

International Nuclear Information System (INIS)

Dan Kayser

2005-01-01

This report summarizes the environmental status of Ames Laboratory for calendar year 2005. It includes descriptions of the Laboratory site, its mission, the status of its compliance with applicable environmental regulations, its planning and activities to maintain compliance, and a comprehensive review of its environmental protection, surveillance and monitoring activities. Ames Laboratory is located on the campus of Iowa State University (ISU) and occupies 11 buildings owned by the Department of Energy (DOE). See the Laboratory's Web page at www.external.ameslab.gov for locations and Laboratory overview. The Laboratory also leases space in ISU owned buildings. In 2005, the Laboratory accumulated and disposed of waste under U.S. Environmental Protection Agency (EPA) issued generator numbers. All waste is handled accordingly to all applicable EPA, State, Local and DOE Orders. The most recent RCRA inspection was conducted by EPA Region VII in January 1999. The Laboratory received a notice of violation (NOV) which included five citations. There have been no inspections since then. The citations were minor and were corrected by the Laboratory within the time allocated by the EPA. See correspondence in Appendix D. The Laboratory was in compliance with all applicable federal, state, local and DOE regulations and orders in 2005. There were no radiological air emissions or exposures to the general public due to Laboratory activities in 2005. See U.S. Department of Energy Air Emissions Annual Report in Appendix B. Pollution awareness, waste minimization and recycling programs were implemented in 1990 and updated in 2003. Included in these efforts were battery and CRT recycling, waste white paper and green computer paper-recycling. Ames Laboratory also recycles/reuses salvageable metal, used oil, styrofoam peanuts, batteries, CRTs, fluorescent lamps and telephone books. Ames Laboratory reported to DOE-CH, through the Laboratory's Self Assessment Report, on its Affirmative

Dual-Phase CsPbBr3 -CsPb2 Br5 Perovskite Thin Films via Vapor Deposition for High-Performance Rigid and Flexible Photodetectors.

Science.gov (United States)

Tong, Guoqing; Li, Huan; Li, Danting; Zhu, Zhifeng; Xu, Enze; Li, Guopeng; Yu, Linwei; Xu, Jun; Jiang, Yang

2018-02-01

Inorganic perovskites with special semiconducting properties and structures have attracted great attention and are regarded as next generation candidates for optoelectronic devices. Herein, using a physical vapor deposition process with a controlled excess of PbBr 2 , dual-phase all-inorganic perovskite composite CsPbBr 3 -CsPb 2 Br 5 thin films are prepared as light-harvesting layers and incorporated in a photodetector (PD). The PD has a high responsivity and detectivity of 0.375 A W -1 and 10 11 Jones, respectively, and a fast response time (from 10% to 90% of the maximum photocurrent) of ≈280 µs/640 µs. The device also shows an excellent stability in air for more than 65 d without encapsulation. Tetragonal CsPb 2 Br 5 provides satisfactory passivation to reduce the recombination of the charge carriers, and with its lower free energy, it enhances the stability of the inorganic perovskite devices. Remarkably, the same inorganic perovskite photodetector is also highly flexible and exhibits an exceptional bending performance (>1000 cycles). These results highlight the great potential of dual-phase inorganic perovskite films in the development of optoelectronic devices, especially for flexible device applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Reactivity of BrCl, Br₂, BrOCl, Br₂O, and HOBr toward dimethenamid in solutions of bromide + aqueous free chlorine.

Science.gov (United States)

Sivey, John D; Arey, J Samuel; Tentscher, Peter R; Roberts, A Lynn

2013-02-05

HOBr, formed via oxidation of bromide by free available chlorine (FAC), is frequently assumed to be the sole species responsible for generating brominated disinfection byproducts (DBPs). Our studies reveal that BrCl, Br(2), BrOCl, and Br(2)O can also serve as brominating agents of the herbicide dimethenamid in solutions of bromide to which FAC was added. Conditions affecting bromine speciation (pH, total free bromine concentration ([HOBr](T)), [Cl(-)], and [FAC](o)) were systematically varied, and rates of dimethenamid bromination were measured. Reaction orders in [HOBr](T) ranged from 1.09 (±0.17) to 1.67 (±0.16), reaching a maximum near the pK(a) of HOBr. This complex dependence on [HOBr](T) implicates Br(2)O as an active brominating agent. That bromination rates increased with increasing [Cl(-)], [FAC](o) (at constant [HOBr](T)), and excess bromide (where [Br(-)](o)>[FAC](o)) implicate BrCl, BrOCl, and Br(2), respectively, as brominating agents. As equilibrium constants for the formation of Br(2)O and BrOCl (aq) have not been previously reported, we have calculated these values (and their gas-phase analogues) using benchmark-quality quantum chemical methods [CCSD(T) up to CCSDTQ calculations plus solvation effects]. The results allow us to compute bromine speciation and hence second-order rate constants. Intrinsic brominating reactivity increased in the order: HOBr ≪ Br(2)O Br(2) < BrCl. Our results indicate that species other than HOBr can influence bromination rates under conditions typical of drinking water and wastewater chlorination.

Product state resolved excitation spectroscopy of He-, Ne-, and Ar-Br2 linear isomers: experiment and theory.

Science.gov (United States)

Pio, Jordan M; van der Veer, Wytze E; Bieler, Craig R; Janda, Kenneth C

2008-04-07

Valence excitation spectra for the linear isomers of He-, Ne-, and Ar-Br2 are reported and compared to a two-dimensional simulation using the currently available potential energy surfaces. Excitation spectra from the ground electronic state to the region of the inner turning point of the Rg-Br2 (B,nu') stretching coordinate are recorded while probing the asymptotic Br2 (B,nu') state. Each spectrum is a broad continuum extending over hundreds of wavenumbers, becoming broader and more blueshifted as the rare gas atom is changed from He to Ne to Ar. In the case of Ne-Br2, the threshold for producing the asymptotic product state reveals the X-state linear isomer bond energy to be 71+/-3 cm(-1). The qualitative agreement between experiment and theory shows that the spectra can be correctly regarded as revealing the one-atom solvent shifts and also provides new insight into the one-atom cage effect on the halogen vibrational relaxation. The measured spectra provide data to test future ab initio potential energy surfaces in the interaction of rare gas atoms with the halogen valence excited state.

Characterization of malaria mortality in Valle del Cauca, 2005-2006 Caracterización de la mortalidad por malaria en el Valle del Cauca, 2005-2006

Directory of Open Access Journals (Sweden)

Gloria Castro

2009-12-01

Full Text Available Introduction. Valle del Cauca is one of the states in Colombia that reports a high number of deaths due to malaria. Understanding the basis of malarial deaths is useful for assessing the efficacy of the health system and to identify areas where improvements are necessary to decrease malaria mortality.<br />Objective. Potential determinants of mortality in malaria cases are characterized in a demographic study centered in Valle del Cauca.<br />Materials and methods. A descriptive analysis was directed to 25 cases of malaria death occurring in Valle del Cauca during 2005 and 2006.<br />Results. The mean age was 31.3 years (range, 2 to 71 yr, 11 were women (1 pregnant, 11 were from the malaria-endemic port of Buenaventura, and 5 from other Pacific coastal states. After entering the health system facility, the standard malaria diagnostic, the thick smear, was not ordered for 7 cases at any time during the treatment period. In cases where a thick smear was taken at first contact, 11 had a positive and 5 had a negative initial report. Cerebral malaria (7/18 cases and renal failure (6/18 cases were the most frequent complications. During hospitalization, 13/18 cases developed other complications, mainly acute lung edema (8/18 cases and shock (5/18 cases.<br />Conclusions. Failures in primary health care of patients with malaria were recognized. This information has been used to implement actions aimed at improving initial care of malaria subjects in the health services of Valle del Cauca. The study recommends that other states in Colombia increase their efforts to decrease malaria mortality.Introducción. El Valle del Cauca es uno de los departamentos que mayor número de muertes por paludismo reporta en Colombia. El análisis de estas muertes permite una aproximación diagnóstica al funcionamiento del sistema de salud y contribuye a generar propuestas tendientes a disminuir la mortalidad por esta enfermedad.<br />Objetivo. Caracterizar demogr

The BR eigenvalue algorithm

Energy Technology Data Exchange (ETDEWEB)

Geist, G.A. [Oak Ridge National Lab., TN (United States). Computer Science and Mathematics Div.; Howell, G.W. [Florida Inst. of Tech., Melbourne, FL (United States). Dept. of Applied Mathematics; Watkins, D.S. [Washington State Univ., Pullman, WA (United States). Dept. of Pure and Applied Mathematics

1997-11-01

The BR algorithm, a new method for calculating the eigenvalues of an upper Hessenberg matrix, is introduced. It is a bulge-chasing algorithm like the QR algorithm, but, unlike the QR algorithm, it is well adapted to computing the eigenvalues of the narrowband, nearly tridiagonal matrices generated by the look-ahead Lanczos process. This paper describes the BR algorithm and gives numerical evidence that it works well in conjunction with the Lanczos process. On the biggest problems run so far, the BR algorithm beats the QR algorithm by a factor of 30--60 in computing time and a factor of over 100 in matrix storage space.

Energy requirements for racing endurance sled dogs*

OpenAIRE

Loftus, John P.; Yazwinski, Molly; Milizio, Justin G.; Wakshlag, Joseph J.

2014-01-01

Endurance sled dogs have unique dietary energy requirements. At present, there is disparity in the literature regarding energy expenditure and thus energy requirements of these dogs. We sought to further elucidate energy requirements for endurance sled dogs under field conditions. Three sled dog teams completing the 2011 Yukon Quest volunteered to provide diet history. Nutritional content was evaluated and a mock meal was analysed for each team. Race data were obtained from www.yukonquest.com...

2D-2D stacking of graphene-like g-C{sub 3}N{sub 4}/Ultrathin Bi{sub 4}O{sub 5}Br{sub 2} with matched energy band structure towards antibiotic removal

Energy Technology Data Exchange (ETDEWEB)

Ji, Mengxia; Di, Jun; Ge, Yuping; Xia, Jiexiang, E-mail: xjx@ujs.edu.cn; Li, Huaming, E-mail: lhm@ujs.edu.cn

2017-08-15

Highlights: • 2D-2D graphene-like g-C{sub 3}N{sub 4}/ultrathin Bi{sub 4}O{sub 5}Br{sub 2} materials have been prepared. • With matched energy band structure, the effective charge separation can be achieved. • The holes and O{sub 2}{sup −} are determined to be the main active species. - Abstract: A novel visible-light-driven 2D-2D graphene-like g-C{sub 3}N{sub 4}/ultrathin Bi{sub 4}O{sub 5}Br{sub 2} photocatalyst was prepared via a facile solvothermal method in the presence of reactable ionic liquid 1-hexadecyl-3-methylimidazolium bromide ([C{sub 16}mim]Br) for the first time. FT-IR, XPS and TEM analysis results demonstrated the successful introduction of the 2D graphene-like g-C{sub 3}N{sub 4} material to the Bi{sub 4}O{sub 5}Br{sub 2} system. DRS and BET analysis results indicated the existence of the g-C{sub 3}N{sub 4} could lead to the broaden absorption edge and larger surface area of the ultrathin Bi{sub 4}O{sub 5}Br{sub 2} nanosheets. The electrochemical analysis implied a fast transfer of the interfacial electrons and low recombination rate of photogenerated charge carriers in g-C{sub 3}N{sub 4}/Bi{sub 4}O{sub 5}Br{sub 2}, which could be assigned to the sufficient and tight contact between ultrathin Bi{sub 4}O{sub 5}Br{sub 2} and graphene-like g-C{sub 3}N{sub 4}. The quinolone antibiotic ciprofloxacin (CIP) was chosen as the target pollutant to evaluate the photocatalytic performance of the as-prepared samples under visible light irradiation. 1 wt% g-C{sub 3}N{sub 4}/Bi{sub 4}O{sub 5}Br{sub 2} composite exhibited the highest photocatalytic degradation performance among all of the as-prepared photocatalysts. The enhancement of photocatalytic activity was attributed to the maximum contact between graphene-like g-C{sub 3}N{sub 4} and ultrathin Bi{sub 4}O{sub 5}Br{sub 2} material with matched energy band structure, which enable the efficient charge seperation. A possible photocatalytic mechanism also was proposed.

Proceedings of the 1st International Operational Modal Analysis Conference, April 26-27, 2005, Copenhagen, Denmark

DEFF Research Database (Denmark)

These proceedings contain approximately 100 papers presented at the 1st International Operational Modal Conference, Copenhagen, Denmark, April 26 - 27, 2005. The conference is jointly organised by Structural Vibration Systems (SVS), Aalborg, Brüel & Kjær Sound and Vibration Measurement A/S and th......These proceedings contain approximately 100 papers presented at the 1st International Operational Modal Conference, Copenhagen, Denmark, April 26 - 27, 2005. The conference is jointly organised by Structural Vibration Systems (SVS), Aalborg, Brüel & Kjær Sound and Vibration Measurement A....../S and the Department of Building Technology and Structural Engineering at Aalborg University. It is the first conference ever to focus solely on experimental modal analysis for cases where only the responses are measured. It was decided to hold the conference to generate interest in operational modal analysis (also...... effort and higher versatility. However, because the mathematical background was initially weak, computer power was insufficient and the equipment not sensitive enough for this kind of testing, the technology has only become popular during the last 3 - 4 years. For this reason, the first conference...

Renewable energy in focus: In5Se5Br, a solid material with promising thermoelectric properties for industrial applications

International Nuclear Information System (INIS)

Xhaxhiu, Kledi; Kvarnström, Carita; Damlin, Pia; Bente, Klaus

2014-01-01

Highlights: • In 5 Se 5 Br contains indium simultaneously in three different oxidation states. • Bulk sample of In 5 Se 5 Br shows n-type conductivity. • The Seebeck voltage increases linearly with the temperature difference increase. • In bulk In 5 Se 5 Br the resistivity oscillates between 2.6 MΩ and 23 MΩ. • DTA and HT-powder XRD data show incongruent melting of the compound. - Abstract: We obtained via solid state synthesis needle-shaped crystals of In 5 Se 5 Br crystallizing in the space group Pmn2 1 and containing indium simultaneously in three different oxidation states: In + , formal In 2+ and In 3+ . Bulk sample of In 5 Se 5 Br shows n-type conductivity and linear increase of Seebeck voltage with the temperature difference increase. Seebeck voltage of approx. 720 mV is recorded at a temperature difference of 80 K, corresponding to a Seebeck coefficient −8900 μV/K. A voltage increase up to 250 mV is recorded within 10 min upon application of a 27 K temperature difference between the contacts. On-off switching of the heating source unveils repeatable results. Linear I–U behavior with a resistivity of 2.32 × 10 11 Ω is observable for individual needles of In 5 Se 5 Br. In bulk In 5 Se 5 Br the resistivity oscillates between 2.6 MΩ and 23 MΩ. DTA and HT-powder XRD data show incongruent melting to InBr, InSe and In 2 Se 3 at 805 K. The ternary compound expands 1.02% along [0 1 0] showing a coefficient of thermal expansion α b = 2.3(4) × 10 −5 K −1 . Lower expansions of 0.6% and 0.16% along a and c axes corresponding to mean coefficients of thermal expansion of α a ¯ = 1.3(1) × 10 −5 K −1 , α c ¯ = 4.4(5) × 10 −6 K −1 are observed. Thin layer growing of In 5 Se 5 Br on glass substrate with targeted doping/substitutions can improve the sample conductivity, increase the Seebeck coefficient and lower the thermal conductivity making In 5 Se 5 Br a good alternative material for industrial thermoelectric applications

Fusion Energy Sciences Network Requirements

Energy Technology Data Exchange (ETDEWEB)

Dart, Eli [ESNet, Berkeley, CA (United States); Tierney, Brian [ESNet, Berkeley, CA (United States)

2012-09-26

The Energy Sciences Network (ESnet) is the primary provider of network connectivity for the U.S. Department of Energy Office of Science, the single largest supporter of basic research in the physical sciences in the United States. In support of the Office of Science programs, ESnet regularly updates and refreshes its understanding of the networking requirements of the instruments, facilities, scientists, and science programs that it serves. This focus has helped ESnet to be a highly successful enabler of scientific discovery for over 25 years. In December 2011, ESnet and the Office of Fusion Energy Sciences (FES), of the DOE Office of Science (SC), organized a workshop to characterize the networking requirements of the programs funded by FES. The requirements identified at the workshop are summarized in the Findings section, and are described in more detail in the body of the report.

Dicty_cDB: FC-BR21 [Dicty_cDB

Lifescience Database Archive (English)

Full Text Available FC (Link to library) FC-BR21 (Link to dictyBase) - - - Contig-U15384-1 | Contig-U16443-1 FC-BR2...1P (Link to Original site) FC-BR21F 551 FC-BR21Z 122 FC-BR21P 673 - - Show FC-BR21 Library FC (L...ink to library) Clone ID FC-BR21 (Link to dictyBase) Atlas ID - NBRP ID - dictyBase ID - Link to Contig Cont...ig-U15384-1 | Contig-U16443-1 Original site URL http://dictycdb.biol.tsukuba.ac.jp/CSM/FC/FC-BR/FC-BR2...1Q.Seq.d/ Representative seq. ID FC-BR21P (Link to Original site) Representative DNA sequence >FC-BR21 (FC-BR2

Technical Training: ELEC-2005

CERN Multimedia

Davide Vitè

2005-01-01

ELEC-2005 - Electronics in High Energy Physics: Autumn Term (November-December 2005) ELEC-2005 is a new course series on modern electronics, given by CERN physicists and engineers within the framework of the 2005 Technical Training Programme, in an extended format of the ELEC-2002 course series. This new, comprehensive course series is designed for people who are not electronics specialists, for example physicists, engineers and technicians working at or visiting the laboratory, who use or will use electronics in their present or future activities, in particular in the context of the LHC accelerator and experiments. ELEC-2005 is composed of four Terms. The Winter (Introduction to electronics in HEP), Spring (Integrated circuits and VLSI technology for physics), and Summer (System electronics for physics: Issues) Terms already took place. The Autumn Term: Electronics applications in HEP experiments (November-December, 10 lectures) is now open for online registration, and will start on November 8th with the...

Designing Sustainable Energy for All : Sustainable Product-Service System Design Applied to Distributed Renewable Energy

NARCIS (Netherlands)

Vezzoli, C; Ceschin, F; Osanjo, L; M'Rithaa, MK; Moalosi, R; Nakazibwe, V.; Diehl, J.C.

2018-01-01

This open access book addresses the issue of diffusing sustainable energy access in low- and middle-income contexts.<br/>/>Access to energy is one of the greatest challenges for many people living in low-<br/>income and developing contexts, as around 1.4 billion people lack access to electricity.

Material test reactor fuel research at the BR2 reactor

Energy Technology Data Exchange (ETDEWEB)

Dyck, Steven Van; Koonen, Edgar; Berghe, Sven van den [Institute for Nuclear Materials Science, SCK-CEN, Boeretang, Mol (Belgium)

2012-03-15

The construction of new, high performance material test reactor or the conversion of such reactors' core from high enriched uranium (HEU) to low enriched uranium (LEU) based fuel requires several fuel qualification steps. For the conversion of high performance reactors, high density dispersion or monolithic fuel types are being developed. The Uranium-Molybdenum fuel system has been selected as reference system for the qualification of LEU fuels. For reactors with lower performance characteristics, or as medium enriched fuel for high performance reactors, uranium silicide dispersion fuel is applied. However, on the longer term, the U-Mo based fuel types may offer a more efficient fuel alternative and-or an easier back-end solution with respect to the silicide based fuels. At the BR2 reactor of the Belgian nuclear research center, SCK-CEN in Mol, several types of fuel testing opportunities are present to contribute to such qualification process. A generic validation test for a selected fuel system is the irradiation of flat plates with representative dimensions for a fuel element. By flexible positioning and core loading, bounding irradiation conditions for fuel elements can be performed in a standard device in the BR2. For fuel element designs with curved plates, the element fabrication method compatibility of the fuel type can be addressed by incorporating a set of prototype fuel plates in a mixed driver fuel element of the BR2 reactor. These generic types of tests are performed directly in the primary coolant flow conditions of the BR2 reactor. The experiment control and interpretation is supported by detailed neutronic and thermal-hydraulic modeling of the experiments. Finally, the BR2 reactor offers the flexibility for irradiation of full size prototype fuel elements, as 200mm diameter irradiation channels are available. These channels allow the accommodation of various types of prototype fuel elements, eventually using a dedicated cooling loop to provide the

Observation of Enhanced Hole Extraction in Br Concentration Gradient Perovskite Materials.

Science.gov (United States)

Kim, Min-Cheol; Kim, Byeong Jo; Son, Dae-Yong; Park, Nam-Gyu; Jung, Hyun Suk; Choi, Mansoo

2016-09-14

Enhancing hole extraction inside the perovskite layer is the key factor for boosting photovoltaic performance. Realization of halide concentration gradient perovskite materials has been expected to exhibit rapid hole extraction due to the precise bandgap tuning. Moreover, a formation of Br-rich region on the tri-iodide perovskite layer is expected to enhance moisture stability without a loss of current density. However, conventional synthetic techniques of perovskite materials such as the solution process have not achieved the realization of halide concentration gradient perovskite materials. In this report, we demonstrate the fabrication of Br concentration gradient mixed halide perovskite materials using a novel and facile halide conversion method based on vaporized hydrobromic acid. Accelerated hole extraction and enhanced lifetime due to Br gradient was verified by observing photoluminescence properties. Through the combination of secondary ion mass spectroscopy and transmission electron microscopy with energy-dispersive X-ray spectroscopy analysis, the diffusion behavior of Br ions in perovskite materials was investigated. The Br-gradient was found to be eventually converted into a homogeneous mixed halide layer after undergoing an intermixing process. Br-substituted perovskite solar cells exhibited a power conversion efficiency of 18.94% due to an increase in open circuit voltage from 1.08 to 1.11 V and an advance in fill-factor from 0.71 to 0.74. Long-term stability was also dramatically enhanced after the conversion process, i.e., the power conversion efficiency of the post-treated device has remained over 97% of the initial value under high humid conditions (40-90%) without any encapsulation for 4 weeks.

Oxidation mechanisms of CF2Br2 and CH2Br2 induced by air nonthermal plasma.

Science.gov (United States)

Schiorlin, Milko; Marotta, Ester; Dal Molin, Marta; Paradisi, Cristina

2013-01-02

Oxidation mechanisms in air nonthermal plasma (NTP) at room temperature and atmospheric pressure were investigated in a corona reactor energized by +dc, -dc, or +pulsed high voltage.. The two bromomethanes CF(2)Br(2) and CH(2)Br(2) were chosen as model organic pollutants because of their very different reactivities with OH radicals. Thus, they served as useful mechanistic probes: they respond differently to the presence of humidity in the air and give different products. By FT-IR analysis of the postdischarge gas the following products were detected and quantified: CO(2) and CO in the case of CH(2)Br(2), CO(2) and F(2)C ═ O in the case of CF(2)Br(2). F(2)C ═ O is a long-lived oxidation intermediate due to its low reactivity with atmospheric radicals. It is however removed from the NTP processed gas by passage through a water scrubber resulting in hydrolysis to CO(2) and HF. Other noncarbon containing products of the discharge were also monitored by FT-IR analysis, including HNO(3) and N(2)O. Ozone, an important product of air NTP, was never detected in experiments with CF(2)Br(2) and CH(2)Br(2) because of the highly efficient ozone depleting cycles catalyzed by BrOx species formed from the bromomethanes. It is concluded that, regardless of the type of corona applied, CF(2)Br(2) reacts in air NTP via a common intermediate, the CF(2)Br radical. The possible reactions leading to this radical are discussed, including, for -dc activation, charge exchange with O(2)(-), a species detected by APCI mass spectrometry.

Projections of energy requirements and their implications

International Nuclear Information System (INIS)

Hogroian, P.

1978-01-01

The subject is covered in sections, entitled as shown. Numerical data are indicated in parenthesis. The record of nuclear power forecasting (estimates of the growth of world nuclear power, penetration of the electric power market by nuclear power); brief review of energy forecasting techniques and problems; some views of future world energy demand (estimates of world primary energy requirements); possible allocations of energy resources to needs (allocation of resources (oil, oil from tar sands, shale, natural gas, coal, coal to gasification, hydroelectricity, renewable resources, nuclear) to the world's primary energy needs in the year 2000); observations on the adequacy of energy resources; implications for nuclear energy (postulated growth of world nuclear power, annual fuel cycle requirements of the world, annual uranium requirements of the world). (U.K.)

Odd-even staggering in the πg9/2νg9/2 band in 72Br

International Nuclear Information System (INIS)

Fotiades, N.; Cizewski, J.A.; Lister, C.J.; Davids, C.N.; Janssens, R.V.; Seweryniak, D.; Carpenter, M.P.; Khoo, T.L.; Lauritsen, T.; Nisius, D.; Reiter, P.; Uusitalo, J.; Wiedenhover, I.; Macchiavelli, A.O.; MacLeod, R.W.

1999-01-01

High-spin positive-parity states in 72 Br have been studied using the 16 O+ 58 Ni reaction. The πg 9/2 νg 9/2 decoupled band in 72 Br has been observed up to ∼10 MeV excitation energy and the expected odd-even staggering has been delineated. A larger signature splitting is observed for this band in 72 Br than in the same collective structures in the heavier 74,76,78 Br. No signature inversion at low spin is observed for this band in 72 Br, in contrast to the heavier isotopes, 74,76,78 Br, in which signature inversion is observed below ∼10ℎ. The observations are in general agreement with theoretical models in this mass region which predict no signature inversion for nuclei with less than 39 protons and neutrons. copyright 1999 The American Physical Society

Annual report 2005

International Nuclear Information System (INIS)

2005-01-01

This annual report of the Group Gaz de France presents the activities for the year 2005 in four main chapters: the group profile, the governance and the challenges; the energy and services display and the infrastructures; the capital opening and some key data; the group collaborators, the energy conservation, the research programs and the future of the gas and the electricity. (A.L.B.)

Energy Policies of IEA Countries: Slovak Republic 2005 Review

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-07-01

Slovakia has implemented impressive energy reforms over the recent past, a unique performance in Central and Eastern Europe. The 2000 energy policy prioritised market reforms and sectoral policies, notably on energy security and environment, in order to comply with EU requirements, which were largely met at the time of the country’s EU accession in 2004. Also, Slovakia established new regulations, notably cost reflective pricing enforced by an independent energy regulator, thereby attracting significant foreign direct investment. Notably, this rapid transition has occurred without disruption in this key energy transit country. New challenges ahead include strengthening energy security by diversification, opening energy markets and integrating them into the EU, strongly increasing energy efficiency to offset the high economic burden of energy prices and to help better controlling pollution and CO2 emissions in line with EU and international obligations. This review analyses the Slovak energy sector and policies, and provides recommendations for the government. It is a comprehensive assessment of what constitutes a remarkable case study of effective energy reforms in an economy in transition, which has applied for IEA membership.

Enhancing Hybrid Perovskite Detectability in the Deep Ultraviolet Region with Down-Conversion Dual-Phase (CsPbBr3-Cs4PbBr6) Films.

Science.gov (United States)

Tong, Guoqing; Li, Huan; Zhu, Zhifeng; Zhang, Yan; Yu, Linwei; Xu, Jun; Jiang, Yang

2018-04-05

Hybrid perovskite photodetectors (PDs) exhibit outstanding performance in the ultraviolet-visible (UV-vis) spectrum but have poor detectability in the deep ultraviolet (DUV) region (200-350 nm). In this work, a novel inorganic-hybrid architecture that incorporates a dual-phase (CsPbBr 3 -Cs 4 PbBr 6 ) inorganic perovskite material as a down-conversion window layer and a hybrid perovskite as a light capture layer was prepared to achieve faster, highly sensitive photodetection in the DUV spectrum. A dual-phase inorganic perovskite film coated on the back surface of the photodetector enables strong light absorption and tunes the incident energy into emission bands that are optimized for the perovskite photodetector. The presence of Cs 4 PbBr 6 enhances the capture and down-conversion of the incident DUV light. Due to the down-conversion and transport of the DUV photons, a self-driven perovskite photodetector with this composite structure exhibits a fast response time of 7.8/33.6 μs and a high responsivity of 49.4 mA W -1 at 254 nm without extra power supply.

Spent fuel strategy for the BR2 reactor

International Nuclear Information System (INIS)

Gubel, P.; Collard, G.

1998-01-01

The Belgian MTR reactor is fuelled with HEU UAl x elements and the fuel cycle was normally closed by reprocessing consecutively in Belgium (Eurochemic), France (Marcoule) and finally in the U.S.A. (Idaho Falls and Savannah River). When the acceptance of spent fuel by the U.S. was terminated, the facility was left with a huge backlog of used elements stored under water. After a few years, urgent and mandatory actions were required to maintain the BR2 facility operating. Later the accent was put on the evaluation of an optimum long term solution for the BR2 spent fuel during the projected 15 years life extension after the refurbishment executed between 1995 and 1997. The paper gives an overview of these successive actions taken during the last years as well as the handled various criteria for comparing and evaluating the available long-term alternatives. After commitment to reprocessing in existing facilities operated for aluminum fuels the focus of the BR2 fuel cycle strategy is now moving to the procurement of the necessary HEU fuel for securing the long-term operation of the facility. (author)

Hybridization of Single Nanocrystals of Cs4PbBr6 and CsPbBr3

OpenAIRE

Weerd, Chris de; Lin, Junhao; Gomez, Leyre; Fujiwara, Yasufumi; Suenaga, Kazutomo; Gregorkiewicz, Tom

2017-01-01

Nanocrystals of all-inorganic cesium lead halide perovskites (CsPbX3, X = Cl, Br, I) feature high absorption and efficient narrow-band emission which renders them promising for future generation of photovoltaic and optoelectronic devices. Colloidal ensembles of these nanocrystals can be conveniently prepared by chemical synthesis. However, in the case of CsPbBr3, its synthesis can also yield nanocrystals of Cs4PbBr6 and the properties of the two are easily confused. Here, we investigate in de...

CNEN, IAEA and ISO normative requirements for measurement management

International Nuclear Information System (INIS)

Kibrit, Eduardo

2009-01-01

International standard ISO 10012:2003 establishes requirements for measurement management systems, including requirements for measurement processes and measuring equipment. ISO 9001:2008 presents requirements for quality management systems, including requirements for the control of monitoring and measuring equipment. ISO 17025:2005 presents general requirements for the competence of testing and calibration laboratories. In the nuclear field the requirements for measurement management are established by standards published by the International Atomic Energy Agency (IAEA), and in Brazil, by the National Nuclear Energy Commission (CNEN). The present paper presents and discusses the normative requirements for measurement management, considering requirements established by National Nuclear Energy Commission (CNEN), International Atomic Energy Agency (IAEA), and International Organisation for Standardisation (ISO). (author)

The decommissioning of the BR3 steam generator

International Nuclear Information System (INIS)

Denissen, L.

2006-01-01

A steam generator is a crucial component in a PWR (Pressurized Water Reactor). It is the crossing between the primary, contaminated, circuit and the secondary water-steam circuit. The heat from the primary reactor coolant loop is transferred to the secondary side in thousands of small tubes. Due to several problems in the material of those tubes, like SCC (Stress Corrosion Cracking), insufficient control in water chemistry, which can be the cause of tube leakage, more and more steam generators are replaced today. Only in Belgium, already 17 of them are replaced. The old 300 ton heavy SGs are stored at the 2 nuclear power plants of Doel and Tihange . While it was foreseen in the BR3 strategy to dismantle the steam generator (only 30 ton), we took the opportunity to search for a complete package in the decommissioning of a steam generator. The complete management consists of a decontamination of the primary side followed by the complete dismantling. The first step, the decontamination with MEDOC (water box + tube bundle) has already been achieved in 2002. It has led to an important DF (Decontamination Factor) between 100 and 1000 and an important dose rate reduction. This hard chemical decontamination process has been described earlier in the scientific report 2002 (The BR3 steam generator decontamination with the MEDOC process - M. Ponnet). The second step, the complete dismantling of the SG has been executed in 2005. With the BR3 SG, the main goal was to dismantle it in a safe way and to free release a maximum of material. We've used two cutting tools to perform the job: A HPWJC (High Pressure Water Jet Cutting) tool in combination with a hydraulic robot and a water cooled diamond cable. The last technique was done in close collaboration with the external company Husqvarna. It was important to have an idea of the performance, the efficiency of the cable and the quantity and the type of secondary waste

Energy transport corridors: the potential role of Federal lands in states identified by the Energy Policy Act of 2005, section 368(b).

Energy Technology Data Exchange (ETDEWEB)

Krummel, J.; Hlohowskyj, I.; Kuiper, J.; Kolpa, R.; Moore, R.; May, J.; VanKuiken, J.C.; Kavicky, J.A.; McLamore, M.R.; Shamsuddin, S. (Decision and Information Sciences); ( EVS)

2011-09-01

On August 8, 2005, the President signed the Energy Policy Act of 2005 (EPAct) into law. In Subtitle F of EPAct, Congress set forth various provisions that would change the way certain federal agencies (Agencies) coordinate to authorize the use of land for a variety of energy-related purposes. As part of Subtitle F of EPAct, Section 368 addresses the issue of energy transportation corridors on federal land for oil, gas, and hydrogen pipelines, as well as electricity transmission and distribution facilities. Because of the critical importance of improving the nation's electrical transmission grid, Congress recognized that electricity transmission issues should receive added attention when the Agencies address corridor location and analysis issues. In Section 368, Congress specifically directed the Agencies to consider the need for upgraded and new facilities to deliver electricity: In carrying out [Section 368], the Secretaries shall take into account the need for upgraded and new electricity transmission and distribution facilities to (1) improve reliability; (2) relieve congestion; and (3) enhance capability of the national grid to deliver electricity. Section 368 does not require the Agencies to consider or approve specific projects, applications for rights-of-way (ROWs), or other permits within designated energy corridors. Importantly, Section 368 does not direct, license, or otherwise permit any on-the-ground activity of any sort. If an applicant is interested in obtaining an authorization to develop a project within any corridor designated under Section 368, the applicant would have to apply for a ROW authorization and applicable permits. The Agencies would consider each application by applying appropriate project-specific reviews under requirements of laws and related regulations, including, but not limited to, the National Environmental Policy Act (NEPA), the Clean Water Act, the Clean Air Act, Section 7 of the Endangered Species Act (ESA), and Section

LiBr absorption systems integrated with high–efficiency IGSG plant

DEFF Research Database (Denmark)

Rokni, Masoud; Bellomare, Filippo

2015-01-01

vapor compression inverse cycles; waste heat from other systems can in fact be used as an efficient input instead of electrical energy. The opportunity to integrate Li-Br absorption systems with a high-efficiency energy plant was studied; rejected heat from a Municipal Solid Waste Gasification Plant......Over the last few years, the energy demand for cooling systems is increasing; different solutions in fact have been proposed in order to minimize the energetic and environmental impact of this trend. In this direction, absorption cooling systems are recognized as a valid alternative to traditional...

Cd4As2Br3

Directory of Open Access Journals (Sweden)

Mohammed Kars

2014-03-01

Full Text Available Single crystals of Cd4As2Br3 (tetracadmium biarsenide tribromide were grown by a chemical transport reaction. The structure is isotypic with the members of the cadmium and mercury pnictidohalides family with general formula M4A2X3 (M = Cd, Hg; A = P, As, Sb; X = Cl, Br, I and contains two independent As atoms on special positions with site symmetry -3 and two independent Cd atoms, of which one is on a special position with site symmetry -3. The Cd4As2Br3 structure consists of AsCd4 tetrahedra sharing vertices with isolated As2Cd6 octahedra that contain As–As dumbbells in the centre of the octahedron. The Br atoms are located in the voids of this three-dimensional arrangement and bridge the different polyhedra through Cd...Br contacts.

Is the 'Bromine Explosion' generated from the reaction BrO HO2 alone?

Science.gov (United States)

Behnke, Wolfgang; Zetzsch, Cornelius

2010-05-01

[toluene] ~ 100). Formation of aldehydes (R-CHO) interferes with the chain reaction (1) - (3) markedly, since kBr[O3] ≈kBr[R-CHO]. The chain reaction is limited by availability of ozone (degradation of HCs by atomic Cl stops completely with vanishing ozone), of HO2 (HCs are required to form HO2) and of aerosol. The central question is: will sufficient HO2 be formed from degradation of HCs to explain the magnitude of the formed Br2 and BrCl in our experiments? We found that the formation of HO2 should be by a factor of 2-4 larger to explain the formation of Br2 and BrCl. Which other sources for the formation of HOBr besides reaction (2a) are then available? The rate of CH3O2with BrO is 25% of that with HO2 (Enami, S.; Yamanaka, T.; Nakayama, T.; Hashimoto, S.; Kawasaki, M.; Shallcross, D.E.; Nakano, Y.; Ishiwata, T., J. Phys. Chem. A, 11, 3342 - 3348, 2007), suggesting that other RO2 radicals must contribute. In our model calculations we use this rate constant for all RO2 radicals to obtain reasonable agreement between the produced HOBr and the formed BrCl and Br2 necessary for our experimental degradation results. So reaction scheme (1) - (3) should be completed by: BrO + RO2 => HOBr + products (2b) The German Science Foundation (DFG) supported this research in unit 783 (HALOPROC).

Ablation of TRIP-Br2, a regulator of fat lipolysis, thermogenesis and oxidative metabolism, prevents diet-induced obesity and insulin resistance.

Science.gov (United States)

Liew, Chong Wee; Boucher, Jeremie; Cheong, Jit Kong; Vernochet, Cecile; Koh, Ho-Jin; Mallol, Cristina; Townsend, Kristy; Langin, Dominique; Kawamori, Dan; Hu, Jiang; Tseng, Yu-Hua; Hellerstein, Marc K; Farmer, Stephen R; Goodyear, Laurie; Doria, Alessandro; Blüher, Matthias; Hsu, Stephen I-Hong; Kulkarni, Rohit N

2013-02-01

Obesity develops as a result of altered energy homeostasis favoring fat storage. Here we describe a new transcription co-regulator for adiposity and energy metabolism, SERTA domain containing 2 (TRIP-Br2, also called SERTAD2). TRIP-Br2-null mice are resistant to obesity and obesity-related insulin resistance. Adipocytes of these knockout mice showed greater stimulated lipolysis secondary to enhanced expression of hormone sensitive lipase (HSL) and β3-adrenergic (Adrb3) receptors. The knockout mice also have higher energy expenditure because of increased adipocyte thermogenesis and oxidative metabolism caused by upregulating key enzymes in their respective processes. Our data show that a cell-cycle transcriptional co-regulator, TRIP-Br2, modulates fat storage through simultaneous regulation of lipolysis, thermogenesis and oxidative metabolism. These data, together with the observation that TRIP-Br2 expression is selectively elevated in visceral fat in obese humans, suggests that this transcriptional co-regulator is a new therapeutic target for counteracting the development of obesity, insulin resistance and hyperlipidemia.

Influence of proceedings papers on citation impact in seven sub-fields of sustainable energy research 2005–2011

DEFF Research Database (Denmark)

Ingwersen, Peter; Larsen, Birger; Garcia-Zorita, J. Carlos

2014-01-01

and Wave Energy, Geo-thermal, Bio-fuel and Bio-mass energy ub-fields. The analyses cover peer reviewed research and review articles as well as two kinds of proceeding papers from conferences published 2005–2009 in (a) book series or volumes and (b) special journal issues excluding meeting abstracts cited......This paper analyses the following seven sub-fields of Sustainable Energy Research with respect to the influence of proceedings papers on citation patterns across citing and cited document types, overall sub-field and document type impacts and citedness: the Wind Power, Renewable Energy, Solar...

BR2 reactor neutron beams

International Nuclear Information System (INIS)

Neve de Mevergnies, M.

1977-01-01

The use of reactor neutron beams is becoming increasingly more widespread for the study of some properties of condensed matter. It is mainly due to the unique properties of the ''thermal'' neutrons as regards wavelength, energy, magnetic moment and overall favorable ratio of scattering to absorption cross-sections. Besides these fundamental reasons, the impetus for using neutrons is also due to the existence of powerful research reactors (such as BR2) built mainly for nuclear engineering programs, but where a number of intense neutron beams are available at marginal cost. A brief introduction to the production of suitable neutron beams from a reactor is given. (author)

Synthesis and single crystal growth of perovskite semiconductor CsPbBr3

Science.gov (United States)

Zhang, Mingzhi; Zheng, Zhiping; Fu, Qiuyun; Chen, Zheng; He, Jianle; Zhang, Sen; Chen, Cheng; Luo, Wei

2018-02-01

As a typical representative of all-inorganic lead halide perovskites, cesium lead bromine (CsPbBr3) has attracted significant attention in recent years. The direct band gap semiconductor CsPbBr3 has a wide band gap of 2.25 eV and high average atomic number (Cs: 55, Pb: 82 and Br: 35), which meet most of the requirements for detection of X- and γ-ray radiation, such as high attenuation, high resistivity, and significant photoconductivity response. However, the growth of large volume CsPbBr3 single crystals remains a challenge. In this paper, the synthesis of CsPbBr3 polycrystalline powders by a chemical co-precipitation method was investigated and the optimum synthesis conditions were obtained. A large CsPbBr3 single crystal of 8 mm diameter and 60 mm length was obtained by a creative electronic dynamic gradient (EDG) method. X-ray diffraction (XRD) patterns and X-ray rocking curve showed that the CsPbBr3 crystal preferentially oriented in the (1 1 0) direction and had a low dislocation density and small residual stress in the crystal. The IR and UV-Vis transmittance and temperature-dependent photoluminescence (PL) spectra showed the crystal had a good basic optical performance. The almost linear current-voltage (I-V) curves implied good ohmic contact between the electrodes and crystal surfaces. The resistivity of the crystal was calculated 109-1010 Ω cm. The above results showed that the quality of the obtained crystal had met the demand of optoelectronic applications.

Pulp & paper markets cope with high energy prices and growth in Asia : markets for paper, paperboard and woodpulp, 2005-2006

Science.gov (United States)

Peter J. Ince

2006-01-01

\\tPulp and paper markets in the UNECE region were influenced by higher energy prices and demand growth in Asia in 2005 and 2006. Important developments in Europe included the launching of the EU Emissions Trading Scheme, which was followed by substantial increases in electrical energy prices. High global energy prices pushed up costs of production and prices for pulp...

Br2(X) microsolvation in helium clusters: effect of the interaction on the quantum solvent density distribution.

Science.gov (United States)

Di Paola, Cono; Gianturco, Franco A; López-Durán, David; de Lara-Castells, Maria Pilar; Delgado-Barrio, Gerardo; Villarreal, Pablo; Jellinek, Julius

2005-07-11

The Born-Oppenheimer potential energy surface for the Br2(X) molecule interacting with a varying number of 4He bosons is constructed following two different schemes which employ either a full ab initio evaluation of the Br2-He interaction forces or an estimate of the latter through an empirical model. Both descriptions are employed by carrying out diffusion Monte Carlo (DMC) calculations of the ground-state energies and quantum wavefunctions for Br2-(He)n clusters with n up to 24. The results clearly indicate, for both interactions, the occurrence of the full solvation of the molecular dopant within the quantum bosonic "solvent" but also show differences between the two models in terms of the expected density distributions of the surrounding particles within the shorter-range region that makes up the clusters with smaller n values. Our calculations also show that such differences become insignificant for the larger 4He clusters surrounding the Br2 molecule, where density profiles and bulk behaviour are chiefly driven by the solvent structure, once n values reach the region of 15-20 adatoms.

Simulation of the compressor-assisted triple-effect H{sub 2}O/LiBr absorption cooling cycles

Energy Technology Data Exchange (ETDEWEB)

Kim, Jin Soo; Ziegler, F. [Bavarian Center for Applied Energy Research, Garching (Germany); Lee, Huen [Korea Advanced Inst. of Science and Technology, Taejon (Korea). Dept. of Chemical Engineering

2002-03-01

The construction of a triple-effect absorption cooling machine using the lithium bromide-based working fluid is strongly limited by the corrosion problem caused by the high generator temperature. In this study four compressor-assisted H{sub 2}O/LiBr cooling cycles were suggested to solve the problem by lowering the generator temperature of the basic theoretical triple-effect cycle. Each cycle includes one compressor at a different state point to elevate the pressure of the refrigerant vapor up to a useful condensation temperature. Cycle simulations were carried out to investigate both a basic triple-effect cycle and four compressor-assisted cycles. All types of compressor-assisted cycles were found to be operable with a significantly lowered generator temperature. The temperature decrements increase with elevated compression ratios. This means that, if a part of energy input is changed from heat to mechanical energy, the machine can be operated in a favorable region of generator temperature not to cause corrosion problems. In order to obtain 40 K of generator temperature decrement (from 475.95 K) for all cycles, 3-5% of cooling capacity equivalent mechanical energies were required for operating the compressor. A great advantage of the investigated triple-effect cycles is that the conventionally used H{sub 2}O/LiBr solution can be used as a working fluid without the danger of corrosion or without integrating multiple solution circuits.(author)

Brændeovnes bidrag til luftforurening

DEFF Research Database (Denmark)

Pedersen, Jens Christian

2010-01-01

Brændeovnenes bidrag til luftforurening er blevet kortlagt med en hidtil uset detaljeringsgrad. Det er forskere fra Danmarks Miljøundersøgelser (DMU) på Aarhus Universitet som står bag kortlægningen. En omfattende målekampagne i Slagslunde viser at brændeovnene bidrager væsentligt til partikelfor......Brændeovnenes bidrag til luftforurening er blevet kortlagt med en hidtil uset detaljeringsgrad. Det er forskere fra Danmarks Miljøundersøgelser (DMU) på Aarhus Universitet som står bag kortlægningen. En omfattende målekampagne i Slagslunde viser at brændeovnene bidrager væsentligt til...

Emission characteristics of Xe-RbBr plasma

Science.gov (United States)

Heneral, A. A.; Avtaeva, S. V.

2017-12-01

The luminescence spectra of the longitudinal pulsed-periodic discharge in Xe-RbBr gas-vapour mixtures at low pressures are experimentally studied. Conditions for obtaining strong UV radiation of XeBr* exiplex molecules in the spectral range of 200-425 nm are found. The greatest output of the XeBr* UV radiation is provided at temperature of the gas-discharge tube walls of ~1000 K. The maximum UV emission power of the whole plasma volume is 4.8 W. Formation of XeBr* exciplex molecules in the pulsed-periodic discharge in Xe-RbBr gas-vapour mixtures at low pressures is discussed.

Free-tropospheric BrO investigations based on GOME

Science.gov (United States)

Post, P.; van Roozendael, M.; Backman, L.; Damski, J.; Thölix, L.; Fayt, C.; Taalas, P.

2003-04-01

Bromine compounds contribute significantly to the stratospheric ozone depletion. However measurements of most bromine compounds are sparse or non-existent, and experimental studies essentially rely on BrO observations. The differences between balloon and ground based measurements of stratospheric BrO columns and satellite total column measurements are too large to be explained by measurement uncertainties. Therefore, it has been assumed that there is a concentration of BrO in the free troposphere of about 1-3 ppt. In a previous work, we have calculated the tropospheric BrO abundance as the difference between total BrO and stratospheric BrO columns. The total vertical column densities of BrO are extracted from GOME measurements using IASB-BIRA algorithms. The stratospheric amount has been calculated using chemical transport models (CTM). Results from SLIMCAT and FinROSE simulations are used for this purpose. SLIMCAT is a widely used 3D CTM that has been tested against balloon measurements. FinROSE is a 3D CTM developed at FMI. We have tried several different tropospheric BrO profiles. Our results show that a profile with high BrO concentrations in the boundary layer usually gives unrealistically high tropospheric column values over areas of low albedo (like oceans). This suggests that the tropospheric BrO would be predominantly distributed in the free troposphere. In this work, attempts are made to identify the signature of a free tropospheric BrO content when comparing cloudy and non-cloudy scenes. The possible impact of orography on measured BrO columns is also investigated.

Measurement of the relative branching ratio BR(Ξc+-- >p+K- π+)/BR(Ξc+-->Ξ- π+π+)

Science.gov (United States)

FOCUS Collaboration; Link, J. M.; Reyes, M.; Yager, P. M.; Anjos, J. C.; Bediaga, I.; Göbel, C.; Magnin, J.; Massafferri, A.; de Miranda, J. M.; Pepe, I. M.; dos Reis, A. C.; Sima~o, F. R. A.; Carrillo, S.; Casimiro, E.; Sánchez-Hernández, A.; Uribe, C.; Vázquez, F.; Cinquini, L.; Cumalat, J. P.; O'Reilly, B.; Ramirez, J. E.; Vaandering, E. W.; Butler, J. N.; Cheung, H. W. K.; Gaines, I.; Garbincius, P. H.; Garren, L. A.; Gottschalk, E.; Kasper, P. H.; Kreymer, A. E.; Kutschke, R.; Bianco, S.; Fabbri, F. L.; Sarwar, S.; Zallo, A.; Cawlfield, C.; Kim, D. Y.; Rahimi, A.; Wiss, J.; Gardner, R.; Chung, Y. S.; Kang, J. S.; Ko, B. R.; Kwak, J. W.; Lee, K. B.; Park, H.; Alimonti, G.; Boschini, M.; Caccianiga, B.; D'Angelo, P.; DiCorato, M.; Dini, P.; Giammarchi, M.; Inzani, P.; Leveraro, F.; Malvezzi, S.; Menasce, D.; Mezzadri, M.; Milazzo, L.; Moroni, L.; Pedrini, D.; Pontoglio, C.; Prelz, F.; Rovere, M.; Sala, A.; Sala, S.; Davenport, T. F., III; Agostino, L.; Arena, V.; Boca, G.; Bonomi, G.; Gianini, G.; Liguori, G.; Merlo, M. M.; Pantea, D.; Ratti, S. P.; Riccardi, C.; Segoni, I.; Viola, L.; Vitulo, P.; Hernandez, H.; Lopez, A. M.; Mendez, H.; Mendez, L.; Mirles, A.; Montiel, E.; Olaya, D.; Paris, A.; Quinones, J.; Rivera, C.; Xiong, W.; Zhang, Y.; Wilson, J. R.; Cho, K.; Handler, T.; Engh, D.; Hosack, M.; Johns, W. E.; Nehring, M.; Sheldon, P. D.; Stenson, K.; Webster, M.; Sheaff, M.

2001-07-01

We report the observation of the Cabibbo suppressed decay Ξc+-->pK-π+ using data collected with the FOCUS spectrometer during the 1996-1997 Fermilab fixed target run. We find a Ξc+ signal peak of /202+/-35 events. We have measured the relative branching ratios BR(Ξ+c-->pK- π+)/BR(Ξ+c-->Ξ- π+π+)=0.234+/-0.047+/-0.022 and BR(Ξ+c-- >pK¯*(892)0)/BR(Ξ+c-->pK-π+)=0.54+/-0.09+/-0.05.

Nuclear Safety and Radiation Protection in France in 2005; La surete nucleaire et la radioprotection en France en 2005. Dossier de presse

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-04-15

In 2005, the Asn pursued its significant investment in radiation protection and reaffirms its ambition to become as efficient in radiation protection as it is in nuclear safety as of 2009. 2005 was a year of great progress for the Asn as it consolidated its organisation and working methods, in accordance with the 2005-2007 strategic plan it set for itself. The Asn continued progress in the field of radiation protection has given rise to various new regulations to improve the legislative and regulatory framework in this area. The Asn plans to step up its efforts to ensure better monitoring of patient exposure to ionizing radiation and to provide better management of radon-related risks, particularly in housing. Fully aware that its newfound power in this area requires outside evaluation, the Asn has asked the International Atomic Energy Agency (IAEA) to organize an I.R.R.S. (Integrated Regulatory Review Service) assignment consisting of a peer-conducted audit. The IAEA has confirmed that this audit will take place in November 2006. (N.C.)

In situ quantification of Br and Cl in minerals and fluid inclusions by LA-ICP-MS: a powerful tool to identify fluid sources

Science.gov (United States)

Hammerli, Johannes; Rusk, Brian; Spandler, Carl; Emsbo, Poul; Oliver, Nicholas H.S.

2013-01-01

Bromine and chlorine are important halogens for fluid source identification in the Earth's crust, but until recently we lacked routine analytical techniques to determine the concentration of these elements in situ on a micrometer scale in minerals and fluid inclusions. In this study, we evaluate the potential of in situ Cl and Br measurements by LA-ICP-MS through analysis of a range of scapolite grains with known Cl and Br concentrations. We assess the effects of varying spot sizes, variable plasma energy and resolve the contribution of polyatomic interferences on Br measurements. Using well-characterised natural scapolite standards, we show that LA-ICP-MS analysis allows measurement of Br and Cl concentrations in scapolite, and fluid inclusions as small as 16 μm in diameter and potentially in sodalite and a variety of other minerals, such as apatite, biotite, and amphibole. As a demonstration of the accuracy and potential of Cl and Br analyses by LA-ICP-MS, we analysed natural fluid inclusions hosted in sphalerite and compared them to crush and leach ion chromatography Cl/Br analyses. Limit of detection for Br is ~8 μg g−1, whereas relatively high Cl concentrations (> 500 μg g−1) are required for quantification by LA-ICP-MS. In general, our LA-ICP-MS fluid inclusion results agree well with ion chromatography (IC) data. Additionally, combined cathodoluminescence and LA-ICP-MS analyses on natural scapolites within a well-studied regional metamorphic suite in South Australia demonstrate that Cl and Br can be quantified with a ~25 μm resolution in natural minerals. This technique can be applied to resolve a range of hydrothermal geology problems, including determining the origins of ore forming brines and ore deposition processes, mapping metamorphic and hydrothermal fluid provinces and pathways, and constraining the effects of fluid–rock reactions and fluid mixing.

Study of resolution and linearity in LaBr3: Ce scintillator through digital-pulse processing

International Nuclear Information System (INIS)

Abhinav Kumar; Mishra, Gaurav; Ramachandran, K.

2014-01-01

Advent of digital pulse processing has led to a paradigm shift in pulse processing techniques by replacing analog electronics processing chain with equivalent algorithms acting on pulse profiles digitized at high sampling rates. In this paper, we have carried out offline digital pulse processing of Cerium-doped Lanthanum bromide scintillator (LaBr 3 : Ce) detector pulses, acquired using CAEN V1742 VME digitizer module. Algorithms have been written to approximate the functioning of peak sensing analog-to-digital convertor (ADC) and charge-to-digital convertor (QDC). Energy dependence of resolution and energy linearity of LaBr 3 : Ce scintillator detector has been studied by utilizing aforesaid algorithms

Experimental studies and nuclear model calculations on proton-induced reactions on $^{nat}$Se, $^{76}$Se and $^{77}$Se with particular reference to the production of the medically interesting radionuclides $^{76}$Br and $^{77}$Br

CERN Document Server

Hassan, H E; Coenen, H H; Morsy, M; Qaim, S M; Shubin, Yu; 10.1016/j.apradiso.2004.02.001

2004-01-01

Excitation functions of the reactions /sup nat/Se(p, x)/sup 75,76,77,82/Br, /sup 76/Se(p, xn)/sup 75,76/Br, /sup 76/Se(p, x)/sup 75/Se and /sup 77/Se(p, xn)/sup 76,77/Br were measured from their respective thresholds up to 40 MeV, with particular emphasis on data for the production of the medically important radionuclides /sup 76 /Br and /sup 77/Br. The conventional stacked-foil technique was used. The samples were prepared by a sedimentation process. Irradiations were performed using the compact cyclotron CV 28 and the injector of COSY, both at the Research Centre Julich. In order to validate the data, nuclear model calculations were performed using the code ALICE- IPPE which is based on the preequilibrium-evaporation model. Good agreement was found between the experimental and theoretical data, except in the high-energy region where the calculated data were somewhat higher. All the measured excitation curves were compared with the data available in the literature. From the experimental data the theoretical ...

On the path to fusion energy. Teller lecture 2005

International Nuclear Information System (INIS)

Tabak, M.

2007-01-01

There is a need to develop alternate energy sources in the coming century because fossil fuels will become depleted and their use may lead to global climate change. Inertial fusion can become such an energy source, but significant progress must be made before its promise is realized. The high-density approach to inertial fusion suggested by Nuckolls et al. leads reaction chambers compatible with civilian power production. Methods to achieve the good control of hydrodynamic stability and implosion symmetry required to achieve these high fuel densities will be discussed. Fast Ignition, a technique that achieves fusion ignition by igniting fusion fuel after it is assembled, will be described along with its gain curves. Fusion costs of energy for conventional hotspot ignition will be compared with those of Fast Ignition and their capital costs compared with advanced fission plants. Finally, techniques that may improve possible Fast Ignition gains by an order of magnitude and reduce driver scales by an order of magnitude below conventional ignition requirements are described. (author)

World enrichment requirements to 2005

International Nuclear Information System (INIS)

Anon.

1991-01-01

The primary enrichment suppliers-Eurodif, Techsnabexport, Urenco, and the US DOE - are positioning themselves to take advantage of the post - 1995 market. Overall, unfilled requirements represent about 40 percent of world requirements in the year 2000. The USA will be the primary market, as US utilities' unfilled enrichment requirements account for over 60 percent of the world's total unfilled requirements. The enrichment market is moving toward more global competition, as each supplier tries to maintain its current regional market base and then to capture additional market share in other regions

Luminescent characteristic of the CsBr phosphor activated with Eu{sup 2+} and Mn{sup 2+} ions

Energy Technology Data Exchange (ETDEWEB)

Téllez-Flores, E., E-mail: bluedays8i@hotmail.com [Programa de Posgrado en Ciencias (Física), Departamento de Investigación en Física, Universidad de Sonora, Rosales y Blvd. Transversal S/N, 83000 Hermosillo, Son., México (Mexico); Aceves, R., E-mail: raceves@cifus.uson.mx [Centro de Investigación en Física, Universidad de Sonora, Apartado Postal 5-88, 83190 Hermosillo, Son., México (Mexico); Pérez-Salas, R., E-mail: rperez@cifus.uson.mx [Centro de Investigación en Física, Universidad de Sonora, Apartado Postal 5-88, 83190 Hermosillo, Son., México (Mexico); Camarillo, I., E-mail: as99@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, Col. Vicentina, Delegación Iztapalapa, C.P. 09340 México D.F. (Mexico); Caldiño, U., E-mail: cald@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, Col. Vicentina, Delegación Iztapalapa, C.P. 09340 México D.F. (Mexico)

2013-12-15

Spectra of excitation and emission were measured at RT and 15 K in crystals quenched (Q) of CsBr:Eu{sup 2+}, CsBr:Mn{sup 2+} and CsBr:Eu{sup 2+},Mn{sup 2+}. Emission bands at 444, 480, 520 and 570 nm with different relative intensities are generated in the samples after UV excitation. The blue band at 444 nm was ascribed with unknown clusters or aggregated centers (AC) of dipoles type Eu{sup 2+}–V{sub C}{sup −} and insulated dipole centers (IDC) like Eu{sup 2+}–O{sup 2−}. The bands at 480, 520 and 570 nm were assigned to Cs{sub 4}EuBr{sub 6} nanocrystals; AC containing MnBr{sub 4}{sup 2−} units in tetrahedral symmetry and another yet unidentified AC defect, respectively. In crystals of CsBr:Eu{sup 2+},Mn{sup 2+} the excitation and emission spectra taken at 15 K show no clear evidence of an energy transfer mechanism. Instead, the results suggest that the emission is produced by direct excitation of the ions of Eu{sup 2+} and Mn{sup 2+}. Accordingly, single- or double-doped CsBr crystals may contain the same type of defects, either AC and/or IDC. -- Highlights: • The PL consists of several overlapping bands in the entire visible region. • The emission bands were ascribed to dipoles, aggregated and nanocrystals of different nature. • No clear evidence of energy transfer, meaning Eu and Mn pairs are not formed. • The material shows potential characteristics for its use as LED to white emission.

Key figures. Year 2005; Chiffres cles. Annee 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-07-01

This document summarizes in a series of tables the key data of the petroleum industry and of the other energies for the year 2005. Data of the two previous years are given for comparison: 1 - petroleum, France: exploration, reserves, production, transports (tankers, pipelines, crude and refined products), storage capacities, status of resources and uses, foreign trade (imports, prices, exports), refining (capacities, facilities), evolution of supplies, automotive fuels consumption; 2 - energies, France: production, consumption and trade data for coal, natural gas, electricity; total production and consumption of primary energy; consumption per sector of use; 3 - petroleum, world: crude production and reserves per geographical area, OPEC production, imports/exports and refining/consumption per geographical area, international quotation for crudes and refined products; 4 - energies, world: reserves, production and consumption data for coal, natural gas and electricity; uranium production and resources; total primary energy production and consumption per energy source and geographical area. (J.S.)

One-pot solvothermal synthesis of highly efficient, daylight active and recyclable Ag/AgBr coupled photocatalysts with synergistic dual photoexcitation

International Nuclear Information System (INIS)

Zhang, Caihong; Ai, Lunhong; Li, Lili; Jiang, Jing

2014-01-01

Highlights: • Ag/AgBr photocatalysts were controllably synthesized by solvothermal process. • Ag/AgBr composites showed excellent daylight driven photocatalytic activity. • The remarkable activity is attributed to the synergistic dual photoexcitation. -- Abstract: Efficient light harvesting has been considered to be critical for manipulating the photocatalytic behavior of photocatalysts, because it directly determines the generation of reactive redox charge carriers involved in photoreaction process. In this study, we present a successful example on efficient conversion of solar energy by Ag/AgBr coupled photocatalysts that hold unique synergistic dual photoexcitation. A series of Ag/AgBr coupled photocatalysts were controllably synthesized by an easily manipulated mild solvothermal process. The physicochemical properties of the as-prepared Ag/AgBr coupled photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray energy dispersive spectroscopy (EDS) and UV–vis diffuse reflectance spectroscopy (DRS). The results showed the solvothermal reaction time played key role for control of crystalline structure, morphology, composition, and visible light absorption ability of the resulting photocatalysts. The as-prepared Ag/AgBr coupled photocatalysts exhibited remarkable photocatalytic performance and good reusability for decomposing organic dyes in aqueous solution under the irradiation of commercial 20 W cool daylight fluorescent lamp, owing to the synergistic dual photoexcitation cooperating between plasmonic Ag nanoparticles and narrow-band-gap AgBr

Exciton-phonon coupling in a CsPbBr3 single nanocrystal

Science.gov (United States)

Ramade, Julien; Andriambariarijaona, Léon Marcel; Steinmetz, Violette; Goubet, Nicolas; Legrand, Laurent; Barisien, Thierry; Bernardot, Frédérick; Testelin, Christophe; Lhuillier, Emmanuel; Bramati, Alberto; Chamarro, Maria

2018-02-01

We have performed micro-photoluminescence measurements on a single CsPbBr3 nanocrystal (NC) with a size comparable to the Bohr diameter (7 nm). When the NC has an orthorhombic crystal symmetry, we observe an exciton fine structure composed of three peaks linearly polarized. We took advantage of the polarization properties of micro-photoluminescence to monitor in situ both the energy and linewidth of individual peaks when increasing temperature. We reveal that two regimes exist, at low and high temperature, which are dominated by acoustic or longitudinal optical phonon (Fröhlich term) couplings, respectively. The acoustic contribution does not change when the energy of the excitonic transition varies in the range of 2.46-2.62 eV, i.e., with NC sizes corresponding to this range. We find that line broadening is mainly ruled by the Fröhlich term, which is consistent with the polar nature of CsPbBr3.

The genus Actiniceps Berk. & Br

NARCIS (Netherlands)

Boedijn, K.B.

1959-01-01

The genus Actiniceps Berk. & Br. is shown to be a Basidiomycete. Wiesnerina Höhn. and Dimorphocystis Corner are regarded synonymous. The type species A. thwaitesii Berk. & Br. is redescribed with D. capitatus Corner as synonym. The following new combinations are proposed: A. horrida (Höhn.) Boedijn,

Brûlure chez l’épileptique: brûlure pas comme les autres

Science.gov (United States)

Boukind, S.; Elatiqi, O.K.; Dlimi, M.; Elamrani, D.; Benchamkha, Y.; Ettalbi, S.

2015-01-01

Summary L’association brûlure et épilepsie est une constatation fréquente au Maroc. Ces brûlures, souvent itératives, touchent le plus souvent des femmes jeunes de milieu rural. L’accident survient habituellement au domicile, le plus souvent dans la cuisine à la suite d’une chute sur un moyen de cuisson posé au sol. Elles peuvent être inaugurales de la maladie mais surviennent plus souvent chez des patients connus mais au traitement mal suivi. Les conséquences de ces brûlures, toujours profondes, sont souvent dramatiques en termes de séquelles, chez des patients ayant déjà une insertion sociale rendue difficile par l’épilepsie. La prise en charge doit être multidisciplinaire et concerner à la fois la brûlures et l’épilepsie. Des mesures de prévention simples, visant à équilibrer l’épilepsie et éviter au patient de se trouver seul à proximité d’une source de chaleur, doivent être mises en place. PMID:27252613

Ablation of TRIP-Br2, a novel regulator of fat lipolysis, thermogenesis and oxidative metabolism, prevents diet-induced obesity and insulin resistance

Science.gov (United States)

Liew, Chong Wee; Boucher, Jeremie; Cheong, Jit Kong; Vernochet, Cecile; Koh, Ho-Jin; Mallol, Cristina; Townsend, Kristy; Langin, Dominique; Kawamori, Dan; Hu, Jiang; Tseng, Yu-Hua; Hellerstein, Marc K; Farmer, Stephen R; Goodyear, Laurie; Doria, Alessandro; Blüher, Matthias; Hsu, Stephen I-Hong; Kulkarni, Rohit N

2012-01-01

SUMMARY Obesity develops due to altered energy homeostasis favoring fat storage. Here we describe a novel transcription co-regulator for adiposity and energy metabolism, TRIP-Br2 (also called SERTAD2). TRIP-Br2 null mice are resistant to obesity and obesity-related insulin resistance. Adipocytes of the knockout (KO) mice exhibited greater stimulated lipolysis secondary to enhanced expression of hormone sensitive lipase (HSL) and β3-adrenergic (Adrb3) receptors. The KOs also exhibit higher energy expenditure due to increased adipocyte thermogenesis and oxidative metabolism by up-regulating key enzymes in respective processes. Our data show for the first time that a cell cycle transcriptional co-regulator, TRIP-Br2, modulates fat storage through simultaneous regulation of lipolysis, thermogenesis and oxidative metabolism. These data together with the observation that TRIP-BR2 expression is selectively elevated in visceral fat in obese humans suggests that this transcriptional co-regulator is a novel therapeutic target for counteracting the development of obesity, insulin resistance and hyperlipidemia. PMID:23291629

Technical Training: ELEC-2005 - Electronics in High Energy Physics

CERN Multimedia

Monique Duval

2005-01-01

Learning for the LHC! ELEC-2005 is a new course series on modern electronics, given by CERN physicists and engineers within the framework of the 2005 Technical Training Programme, in an extended format of the successful ELEC-2002 course series. This comprehensive course series is designed for people who are not electronics specialists, for example physicists, engineers and technicians working at or visiting the laboratory, who use or will use electronics in their present or future activities, in particular in the context of the LHC accelerator and experiments. ELEC-2005 is composed of four Terms that will run throughout the year: Winter Term: Introduction to electronics in HEP (January-February, 6 lectures) Spring Term: Integrated circuits and VLSI technology for physics (March, 6 lectures) Summer Term: System electronics for physics: Issues (May, 7 lectures) Autumn Term: Electronics applications in HEP experiments (November-December, 10 lectures) Lectures within each Term will take place on Tuesdays an...

CH3Br adsorption on MgO/Mo ultrathin films: A DFT study

Science.gov (United States)

Cipriano, Luis A.; Tosoni, Sergio; Pacchioni, Gianfranco

2018-06-01

The adsorption of methyl bromide on MgO ultrathin films supported on Mo(100) was studied by means of density functional theory calculations, in comparison to the MgO(100) and Mo(100) surfaces. The adsorption energy and geometry were shown to depend on the thickness of the supported oxide film. MgO films as thick as 2ML (or more) display adsorptive properties similar to MgO(100), i.e. the adsorption of CH3Br is mostly due to dispersion and the molecule lies in a tilted geometry almost parallel to the surface. The CH3Br HOMO-LUMO gap is almost unaltered with respect to the gas phase. On metallic Mo(100) surfaces the bonding is completely different with the CH3Br molecule strongly bound and the C-Br bond axis almost vertical with respect to the metal surface. The MgO monolayer supported on Mo exhibits somehow intermediate properties: the tilt angle is larger and the bonding is stronger than on MgO(100), due to the effect of the supporting metal. In this case, a small reduction of the HOMO-LUMO gap of the adsorbed molecule is reported. The results help to rationalize the observed behavior in photodissociation of CH3Br supported on different substrates.

Reactions of N2O5 with Salty and Surfactant-Coated Glycerol: Interfacial Conversion of Br- to Br2 Mediated by Alkylammonium Cations.

Science.gov (United States)

Shaloski, Michael A; Gord, Joseph R; Staudt, Sean; Quinn, Sarah L; Bertram, Timothy H; Nathanson, Gilbert M

2017-05-18

Gas-liquid scattering and product-yield experiments are used to investigate reactions of N 2 O 5 with glycerol containing Br - and surfactant ions. N 2 O 5 oxidizes Br - to Br 2 for every solution tested: 2.7 M NaBr, 0.03 M tetrahexylammonium bromide (THABr), 0.03 M THABr + 0.5 M NaBr, 0.03 M THABr + 0.5 M NaCl, 0.03 M THABr + 0.01 M sodium dodecyl sulfate (SDS), and 0.01 M cetyltrimethylammonium bromide (CTABr). N 2 O 5 also reacts with glycerol itself to produce mono- and dinitroglycerin. Surface tension measurements indicate that 0.03 M THABr and 2.7 M NaBr have similar interfacial Br - concentrations, though their bulk Br - concentrations differ by 90-fold. We find that twice as much Br 2 is produced in the presence of THA + , implying that the conversion of Br - to Br 2 is initiated at the interface, perhaps mediated by the charged, hydrophobic pocket within the surface THA + cation. The addition of 0.5 M NaBr, 0.5 M NaCl, or 0.01 M SDS to 0.03 M THABr lowers the Br 2 production rate by 23%, 63%, and 67% of the THABr value, respectively. When CTA + is substituted for THA + , Br 2 production drops to 12% of the THABr value. The generation of Br 2 under such different conditions implies that trace amounts of surface-active alkylammonium ions can catalyze interfacial N 2 O 5 reactions, even when salts and other surfactants are present.

Nuclear Safety and Radiation Protection in France in 2005

International Nuclear Information System (INIS)

2006-04-01

In 2005, the Asn pursued its significant investment in radiation protection and reaffirms its ambition to become as efficient in radiation protection as it is in nuclear safety as of 2009. 2005 was a year of great progress for the Asn as it consolidated its organisation and working methods, in accordance with the 2005-2007 strategic plan it set for itself. The Asn continued progress in the field of radiation protection has given rise to various new regulations to improve the legislative and regulatory framework in this area. The Asn plans to step up its efforts to ensure better monitoring of patient exposure to ionizing radiation and to provide better management of radon-related risks, particularly in housing. Fully aware that its newfound power in this area requires outside evaluation, the Asn has asked the International Atomic Energy Agency (IAEA) to organize an I.R.R.S. (Integrated Regulatory Review Service) assignment consisting of a peer-conducted audit. The IAEA has confirmed that this audit will take place in November 2006. (N.C.)

Võrdlev brändiuuring : NKB, Tallinn 2007 ja NPNK, Tallinn ja Tartu 2005 : noor kunst / Andreas Trossek

Index Scriptorium Estoniae

Trossek, Andreas, 1980-

2007-01-01

Noorte kunstnike biennaal (NKB) "Tagajärjed ja ettepanekud" Tallinnas Rüütelkonna hoones, kuraatorid Rael Artel ja Anneli Porri, korraldaja Kaasaegse Kunsti Eesti Keskus. Noortepanga reklaam (NPNK) Tallinnas ja Tartus 2005. aastal

Intrinsic Lead Ion Emissions in Zero-Dimensional Cs4PbBr6 Nanocrystals

KAUST Repository

Yin, Jun; Zhang, Yuhai; Bruno, Annalisa; Soci, Cesare; Bakr, Osman; Bredas, Jean-Luc; Mohammed, Omar F.

2017-01-01

-energy UV emission at approximately 350 nm to the allowed optical transition of 3P1 to 1S0 in Pb2+ ions and the low-energy UV emission at approximately 400 nm to the charge-transfer state involved in the 0D NC host lattice (D-state). In the emissive Cs4PbBr6

High Br- Content CsPb(Cl yBr1- y)3 Perovskite Nanocrystals with Strong Mn2+ Emission through Diverse Cation/Anion Exchange Engineering.

Science.gov (United States)

Li, Fei; Xia, Zhiguo; Pan, Caofeng; Gong, Yue; Gu, Lin; Liu, Quanlin; Zhang, Jin Z

2018-04-11

The unification of tunable band edge (BE) emission and strong Mn 2+ doping luminescence in all-inorganic cesium lead halide perovskite nanocrystals (NCs) CsPbX 3 (X = Cl and Br) is of fundamental importance in fine tuning their optical properties. Herein, we demonstrate that benefiting from the differentiation of the cation/anion exchange rate, ZnBr 2 and preformed CsPb 1- x Cl 3 : xMn 2+ NCs can be used to obtain high Br - content Cs(Pb 1- x- z Zn z )(Cl y Br 1- y ) 3 : xMn 2+ perovskite NCs with strong Mn 2+ emission, and the Mn 2+ substitution ratio can reach about 22%. More specifically, the fast anion exchange could be realized by the soluble halide precursors, leading to anion exchange within a few seconds as observed from the strong BE emission evolution, whereas the cation exchange instead generally required at least a few hours; moreover, their exchange mechanism and dynamics process have been evaluated. The Mn 2+ emission intensity could be further varied by controlling the replacement of Mn 2+ by Zn 2+ with prolonged ion exchange reaction time. White light emission of the doped perovskite NCs via this cation/anion synergistic exchange strategy has been realized, which was also successfully demonstrated in a prototype white light-emitting diode (LED) device based on a commercially available 365 nm LED chip.

The strategic plan of the nuclear energy Agency 2005-2009

International Nuclear Information System (INIS)

2005-01-01

The NEA mission is to assist its member countries in maintaining and further developing, through international co-operation, the scientific, technological and legal bases required for a safe, environmentally friendly and economical use of nuclear energy for peaceful purposes; as well as to provide authoritative assessments and to forge common understandings on key issues as input to government decisions on nuclear energy policy and to broader OECD policy analyses in areas such as energy and sustainable development. (author)

2005 annual report

International Nuclear Information System (INIS)

2006-01-01

This report is the 2005 evaluation of the CEA (french Atomic Energy Center) activities in the three following main domains: 1- defense and security, with the simulation programs, the nuclear missiles, the nuclear propulsion, the Rhone valley installations drainage, the fight against the terrorism; 2- the energy, with the industrial park optimization, the long life wastes management, the energy of the future and the fourth generation systems, the dismantling and the cleaning, the european nuclear research, the new technologies of the energy; 3- the technologies for the information and the health with the nano technologies. It provides also a scientifical evaluation and the program management. (A.L.B.)

Photodissociation of 1,2-dibromoethylene at 248 nm: Br2 molecular elimination probed by cavity ring-down absorption spectroscopy.

Science.gov (United States)

Chang, Yuan-Pin; Lee, Ping-Chen; Lin, King-Chuen; Huang, C H; Sun, B J; Chang, A H H

2008-06-02

The Br2 elimination channel is probed for 1,2-C2H2Br2 in the B(3)Pi(+)ou-X(1)Sigma(+)g transition upon irradiation at 248 nm by using cavity ring-down absorption spectroscopy (CRDS). The nascent vibrational population ratio of Br2(v=1)/Br2(v=0) is obtained to be 0.7+/-0.2, thus indicating that the Br2 fragment is produced in hot vibrational states. The obtained Br2 products are anticipated to result primarily from photodissociation of the ground-state cis isomer via four-center elimination or from cis/trans isomers via three-center elimination, each mechanism involving a transition state that has a Br-Br distance much larger than that of ground state Br2. According to ab initio potential energy calculations, the pathways that lead to Br2 elimination may proceed either through the electronic ground state by internal conversion or through the triplet state by intersystem crossing. Temperature-dependence measurements are examined, thereby supporting the pathway that involves internal conversion--which was excluded previously by using product translational spectroscopy (PTS). The quantum yield for the Br2 elimination reaction is determined to be 0.120.1, being substantially contributed by the ground-state Br2 product. The discrepancy of this value from that (of 0.2) obtained by PTS may rise from the lack of measurements in probing the triplet-state Br2 product.

Annual Report 2005

Energy Technology Data Exchange (ETDEWEB)

Swiboda, G [Institute of Atomic Energy, Otwock-Swierk (Poland)

2006-07-01

The Annual Report of the Institute of Atomic Energy describes the results of the research activities carried out in 2005. The document consist of seven parts: General Information; Operation and safety of MARIA reactor; Radiological protection and dosimetry; Nuclear Technology in Energy Generation; Solid State Physics; Nuclear techniques in Health and Environment Protection management of Hazards and in last section the list of published in 2004 papers, conferences, seminars, workshops, research projects and educational activities are presented.

Annual Report 2005

International Nuclear Information System (INIS)

Swiboda, G.

2006-01-01

The Annual Report of the Institute of Atomic Energy describes the results of the research activities carried out in 2005. The document consist of seven parts: General Information; Operation and safety of MARIA reactor; Radiological protection and dosimetry; Nuclear Technology in Energy Generation; Solid State Physics; Nuclear techniques in Health and Environment Protection management of Hazards and in last section the list of published in 2004 papers, conferences, seminars, workshops, research projects and educational activities are presented

Annual report and balance 2005; Memoria y balance 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-07-01

A summary of the research, development, services and production activities of the National Atomic Energy Commission (CNEA) of Argentina is given as well as details of management resources together with the evolution of the budget. The activities of the CNEA related companies during 2005 are also outlined. A special mention is made of the activities of the three CNEA educational and training institutes.

Preparation and characterization of (R,S)-[76Br]BrQNB: an analogue of QNB for PET

International Nuclear Information System (INIS)

Strijckmans, V.; Loc'h, C.; Ottaviani, M.; Maziere, B.; Lee, K.S.; Zeeberg, B.R.

1997-01-01

(R,S)-[ 76 Br]BrQNB was prepared for imaging mAChR by PET . (R,S)QNB was labelled with bromine-76 by electrophilic substitution of the tributylstannyl precursor using peracetic acid as oxidizing agent. The exchange between bromine-76 and the leaving group occurred in 20 min at room temperature. A chemically and radiochemically pure product was obtained with a final radiolabelling yield of 30%. Preliminary evaluation of pharmacological properties was performed in rats. In brain, biodistribution and autoradiography studies showed that the preferential localization of (R,S)-[ 76 Br]BrQNB was m-AChR rich structures. 6 h p.i. the radioactivity uptake in the posterior cortex was 1% ID/g and the striatum to cerebellum radioactivity ratio was 13.5. Metabolite study revealed that the radiotracer remains unchanged in brain for at least 3 h. (Author)

Z-(-,-)-[76Br]BrQNP: a high affinity PET radiotracer for central and cardiac muscarinic receptors

International Nuclear Information System (INIS)

Strijckmans, V.; Coulon, C.; Loc'h, C.; Maziere, B.; Luo, H.; McPherson, D.W.; Knapp, F.F.

1996-01-01

Racemic E-1-azabicyclo[2.2.2]oct-3-yl α-(1-bromo-1-1-propen-3-yl)-α -hydroxy-α-phenylacetate (BrQNP) was prepared and evaluated in vivo as a potential candidate for imaging muscarinic acetylcholinergic receptors by Positron Emission Tomography. Initial in vivo blocking studies utilizing Z-(-,-)-[ 125 I]IQNP as a radiolabelled muscarinic probe demonstrated that a preinjection of cold E-BrQNP effectively blocks the uptake of the radiolabelled probe in the brain and heart, by 71% and 86% respectively. Z-(-,-)-[ 76 Br]BrQNP was prepared by electrophilic substitution from a tributylstannyl precursor. Peracetic acid and chloramine T was evaluated as oxidizing agents. After purification by SPE and RP-HPLC, radiolabelling yields of 85% and 95% were obtained with peracetic acid and chloramine T, respectively. The final radiochemical yield was 70% for both oxidizing agents. (author)

Ab Initio Calculations on Halogen Bond Between N-Br and Electron-donating Groups

Institute of Scientific and Technical Information of China (English)

WANG Yan-hua; CHEN Xue-song; ZOU Jian-wei; YU Qing-sen

2007-01-01

Ab initio calculations of complexes formed between N-bromosuccinimide and a series of electron-donating groups were performed at the level of MP2/Lanl2DZ* to gain a deeper insight into the nature of the N-Br halogen stronger halogen-bonding complex than the C-Br. A comparison of neutral hydrogen bond complex series reveals that the electron-donating capacities of the atoms decrease in the order, N＞O＞S; O(sp3)＞O(sp2), which is adequate for the C-Br halogen bonding. Interaction energies, in conjunction with the geometrical parameters show that the affinitive capacity of trihalide anions X-3 with N-bromosuccinimide are markedly lower than that of the corresponding X- with N-bromosuccinimide, even lower than those of neutral molecules with N-bromosuccinimide. AIM analyses further confirmed the above results.

The states of 73Se populated by the beta decay of 73Br

International Nuclear Information System (INIS)

Heiguchi, K.; Mitarai, S.; Min, B.J.; Kuroyanagi, T.

1987-01-01

Decay of mass-separated samples of the nuclide 73 Br have been investigated by means of an on-line isotope separator in the Tandem Accelerator Laboratory of Kyushu University. Twenty eight γ-rays were assigned to the decay of 73 Br. The half-life was measured to be 3.4±0.2 min. The decay scheme of 73 Br was constructed on the basis of γ-ray energies, intensities of γ-rays and conversion electrons, and relations of γγ-, βγ- and γ(ce)-coincidences. Spins and parities of the ten levels of 73 Se were assigned or limited according to log ft values, conversion coefficients and branching ratios of the transitions. Systematical trends in the level schemes of N=39 isotones 69 Zn, 71 Ge, 73 Se, 75 Kr and 77 Sr are discussed. (orig.)

Outlook for electricity markets 2005-2006 : an energy market assessment

International Nuclear Information System (INIS)

2005-06-01

The National Energy Board monitors the supply of electricity as well as its demand in both domestic and export markets. This document was produced in response to a survey with power generation, transmission and distribution companies, marketers, end-users, environmental groups and government agencies who demonstrated the need for more short-and medium-term energy market assessments to supplement the Board's longer term energy analysis. It on the short-term (2005-2006) issues that can have a long-term effect on the electricity sector. The document presents an analysis of Canadian electricity markets with particular focus on the main drivers affecting current trends in generation, demand, prices, infrastructure additions, and inter-regional and international trade. Current restructuring activities in Canada's electricity industry were also described along with the close relationship between the electricity sectors in Canada and the United States which stems from the integrated nature of the North American power grid. A regional market assessment and a summary was provided for each of Canada's provinces and territories with reference to market structure and current market developments. It was revealed that Canada's electricity markets have developed along provincial or regional boundaries. Utilities have tried to provide adequate and reliable electricity supply, environmental sustainability and acceptable electricity prices. It was concluded that supply is adequate in all regions in the short-term, but tight supply conditions could emerge as early as 2007. Alternative and renewable resource and demand management are becoming more important in addressing air quality issues and supply adequacy. Since uncertainty may delay investment and development of new infrastructure, utilities may be forced to increase electricity prices. It was suggested that interprovincial energy transfers should be further explored. Five recommendations were presented to address the key

Pluri-energy analysis of livestock systems--a comparison of dairy systems in different territories.

Science.gov (United States)

Vigne, Mathieu; Vayssières, Jonathan; Lecomte, Philippe; Peyraud, Jean-Louis

2013-09-15

This paper introduces a generic assessment method called pluri-energy analysis. It aims to assess the types of energy used in agricultural systems and their conversion efficiencies. Four types of energy are considered: fossil energy, gross energy contained in the biomass, energy from human and animal labor and solar energy. The method was applied to compare smallholder low-input dairy-production systems, which are common in developing countries, to the high-input systems encountered in OECD countries. The pluri-energy method is useful for analyzing the functioning of agricultural systems by highlighting their modes of energy management. Since most dairy systems in South Mali (SM) are low-input systems, they are primarily based on solar and labor energy types and do not require substantial fossil-energy inputs to produce milk. Farms in Poitou-Charentes (PC) and Bretagne (BR) show intermediate values of fossil-energy use for milk production, similar to that found in the literature for typical European systems. However, fossil-energy use for milk production is higher on PC than BR farms because of a higher proportion of maize silage in the forage area; grazing pastures are more common on BR farms. Farms on Reunion Island (RI) require a relatively large amount of fossil energy to produce milk, mainly because the island context limits the amount of arable land. Consequently, milk production is based on large imports of concentrated feed with a high fossil-energy cost. The method also enables assessment of fossil-energy-use efficiency in order to increase the performance of biological processes in agricultural systems. Comparing the low-input systems represented by SM to the high-input systems represented by RI, PC and BR, an increase in solar-energy conversion, and thus land productivity, was observed due to intensification via increased fossil-energy use. Conversely, though fossil-energy use at the herd level increased milk productivity, its effect on gross-energy

New results for the formation of a muoniated radical in the Mu + Br2 system: a van der Waals complex or evidence for vibrational bonding in Br-Mu-Br?

Science.gov (United States)

Fleming, Donald G; Cottrell, Stephen P; McKenzie, Iain; Macrae, Roderick M

2012-08-21

New evidence is presented for the observation of a muoniated radical in the Mu + Br(2) system, from μSR longitudinal field (LF) repolarisation studies in the gas phase, at Br(2) concentrations of 0.1 bar in a Br(2)/N(2) mixture at 300 K and at 10 bar total pressure. The LF repolarisation curve, up to a field of 4.5 kG, reveals two paramagnetic components, one for the Mu atom, formed promptly during the slowing-down process of the positive muon, with a known Mu hyperfine coupling constant (hfcc) of 4463 MHz, and one for a muoniated radical formed by fast Mu addition. From model fits to the Br(2)/N(2) data, the radical component is found to have an unusually high muon hfcc, assessed to be ∼3300 MHz with an overall error due to systematics expected to exceed 10%. This high muon hfcc is taken as evidence for the observation of either the Br-Mu-Br radical, and hence of vibrational bonding in this H[combining low line]-L[combining low line]-H[combining low line] system, or of a MuBr(2) van der Waals complex formed in the entrance channel. Preliminary ab initio electronic structure calculations suggest the latter is more likely but fully rigorous calculations of the effect of dynamics on the hfcc for either system have yet to be carried out.

Synthesis, purification, and characterization of perovskite semiconductor CsPbBr3 as a new candidate for y-ray detector(Conference Presentation)

Science.gov (United States)

Chung, Duck Young; Kanatzidis, Mercouri G.; Meng, Fang; Malliakas, Christos D.

2016-09-01

CsPbBr3 has direct band gap (orange color, 2.25 eV), high density (4.85 g/cm3), attenuation coefficient comparable to CZT, and high resistivity 10^9 ohm•cm. These fundamental physical properties of CsPbBr3well meet the requirements for gamma-ray detector materials. CsPbBr3 exhibits the carrier mobility-lifetime product in the order of 10^-4 cm2/V promising enough to be further developed for practical applications. The major challenge in the process to further enhance the detection performance is the carrier traps present at a deep level of the energy gap which should be minimized. We report the synthesis, purification, crystal growth and physical characterization of the CsPbBr3 crystals obtained by new processes we developed for highly pure materials with reduced carrier traps. The starting binary materials were prepared by reaction of Cs2CO3/HBr and Pb(ac)2/HBr in aqueous solution. Purification of materials was performed by sublimation, bromination with HBr gas, and filtration of molten materials. Large single crystals were grown by the vertical Bridgman and EelectroDynamic Gradient method and cut to the dimensions appropriate for assessment of the material for gamma-ray detector applications. All characterization including optical characteristics, charge transport properties, photoconductivity, and gamma-ray spectroscopy from the new single crystals of CsPbBr3 will be presented. In addition, the charge carrier traps profile has been studied for this compound by Deep-Level Transient Spectroscopy (DLTS), Thermally Stimulated Luminescence (TSL), and Photoluminescence (PL) and will be presented.

Commission for Energy regulation (CRE) - Activity report June 2005; Commission de regulation de l'energie (CRE) - Rapport d'activite juin 2005

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-07-01

CRE is the French commission for energy regulation. CRE's remit is to assist in ensuring the proper operation of the electricity and natural gas markets for the benefit of the end-user. In particular, CRE ensures that the conditions of access to electricity and natural gas transmission and distribution systems do not hinder the development of competition. It monitors, for the electricity and natural gas sectors, all transactions made between suppliers, traders and producers, all transactions made on the organised markets and cross-border trading. It ensures that suppliers, traders and producers propose offers that are consistent with their financial and technical constraints. It monitors the implementation of and compliance with regulations giving consumers the right to choose their supplier in a competitive market, and allowing new suppliers to enter the market. This document is the 2005 activity report of CRE. Content: A - The opening of the markets in France and in Europe: The opening of the markets one year after 1 July 2004 (An especially important step, Electricity and gas: a common framework with structural differences, The coexistence of market prices and regulated tariffs); The European texts of 26 June 2003 (Texts to give new impetus, Texts to harmonize the role and powers of national regulators, Texts to guarantee the independence of system operators, Texts to ensure transparent and non-discriminatory access to networks, Texts providing for strengthening of interconnections); The outlook for 2007, a fully open market (1 July 2007: a date set by the directives, Priority given to informing and protecting consumers); B - Regulation of the natural gas market: The gas market in the European context (Europe's dependency on imports is increasing, Gas prices increased considerably across the whole of Europe in 2004, The European gas scene continues to be dominated by a small number of players, Gas infrastructures need to be developed in Europe, The new European

Influence of Polyethylene Glycol (PEG in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study

Directory of Open Access Journals (Sweden)

Nur Khalidah Zainuddin

2017-04-01

Full Text Available The present work was carried with new type and promising polymer electrolytes system by development of carboxylmethylcellulose (CMC doped NH4Br and plasticized with polyethylene glycol (PEG. The sample was successfullyprepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity andthermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedancespectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable forthe conductance and assist to enhancing the ionic conductivity of the CMC-NH4Br-PEG electrolyte system. The addition of PEG to the CMC-based electrolyte can enhance towards the cation mobility which is turn increases ionic conductivity. The conductivity-temperature of plasticized BdPEs system was found obeys the Arrhenius relation where the ionic conductivity increases with temperature and activation energy for the ions hopping of the highest conducting PEs system only required small value to migrate. The electrical studies show a non-Debye behaviour of BdPEs based on the analyzed data using complex permittivity, ε* and complex electrical modulus, M* of the sample at different temperature.

Genomic identification and characterization of the elite strains Bradyrhizobium yuanmingense BR 3267 and Bradyrhizobium pachyrhizi BR 3262 recommended for cowpea inoculation in Brazil.

Science.gov (United States)

Leite, Jakson; Passos, Samuel Ribeiro; Simões-Araújo, Jean Luiz; Rumjanek, Norma Gouvêa; Xavier, Gustavo Ribeiro; Zilli, Jerri Édson

2017-03-31

The leguminous inoculation with nodule-inducing bacteria that perform biological nitrogen fixation is a good example of an "eco-friendly agricultural practice". Bradyrhizobium strains BR 3267 and BR 3262 are recommended for cowpea (Vigna unguiculata) inoculation in Brazil and showed remarkable responses; nevertheless neither strain was characterized at species level, which is our goal in the present work using a polyphasic approach. The strains presented the typical phenotype of Bradyrhizobium with a slow growth and a white colony on yeast extract-mannitol medium. Strain BR 3267 was more versatile in its use of carbon sources compared to BR 3262. The fatty acid composition of BR 3267 was similar to the type strain of Bradyrhizobium yuanmingense; while BR 3262 was similar to Bradyrhizobium elkanii and Bradyrhizobium pachyrhizi. Phylogenetic analyses based on 16S rRNA and three housekeeping genes placed both strains within the genus Bradyrhizobium: strain BR 3267 was closest to B. yuanmingense and BR 3262 to B. pachyrhizi. Genome average nucleotide identity and DNA-DNA reassociation confirmed the genomic identification of B. yuanmingense BR 3267 and B. pachyrhizi BR 3262. The nodC and nifH gene analyses showed that strains BR 3267 and BR 3262 hold divergent symbiotic genes. In summary, the results indicate that cowpea can establish effective symbiosis with divergent bradyrhizobia isolated from Brazilian soils. Published by Elsevier Editora Ltda.

BR2 reactor: medical and industrial applications

International Nuclear Information System (INIS)

Ponsard, B.

2005-01-01

The radioisotopes are produced for various applications in the nuclear medicine (diagnostic, therapy, palliation of metastatic bone pain), industry (radiography of welds, ...), agriculture (radiotracers, ...) and basic research. Due to the availability of high neutron fluxes (thermal neutron flux up to 10 15 n/cm 2 .s), the BR2 reactor is considered as a major facility through its contribution for a continuous supply of products such 99 Mo ( 99 mTc), 131 I, 133 Xe, 192 Ir, 186 Re, 153 Sm, 90 Y, 32 P, 188 W ( 188 Re), 203 Hg, 82 Br, 41 Ar, 125 I, 177 Lu, 89 Sr, 60 Co, 169 Yb, 147 Nd, and others. Neutron Transmutation Doped (NTD) silicon is produced for the semiconductor industry in the SIDONIE (Silicon Doping by Neutron Irradiation Experiment) facility, which is designed to continuously rotate and traverse the silicon through the neutron flux. These combined movements produce exceptional dopant homogeneity in batches of silicon measuring 4 and 5-inches in diameter by up to 750 mm in length. The main objectives of work performed were to provide a reliable and qualitative supply of radioisotopes and NTD-silicon to the customers in accordance with a quality system that has been certified to the requirements of the EN ISO 9001: 2000. This new Quality System Certificate has been obtained in November 2003 for the Production of radioisotopes for medical and industrial applications and the Production of Neutron Transmutation Doped (NTD) Silicon in the BR2 reactor

Stig Brøgger's Artists' Books

DEFF Research Database (Denmark)

Ørum, Tania; Hvis Kromann, Thomas

Introduction and presentation of the many artist's books made by the Danish artist Stig Brøgger......Introduction and presentation of the many artist's books made by the Danish artist Stig Brøgger...

UV-Induced Anisotropy In CdBr2-CdBr2: Cu Nanostructures

Directory of Open Access Journals (Sweden)

El-Naggar A. M.

2015-09-01

Full Text Available We have found an occurrence of anisotropy in the nanostructure CdBr2-CdBr2: Cu nanocrystalline films. The film thickness was varied from 4 nm up to 80 nm. The films were prepared by successive deposition of the novel layers onto the basic nanocrystals. The detection of anisotropy was performed by occurrence of anisotropy in the polarized light at 633 nm He-Ne laser wavelength. The occurrence of anisotropy was substantially dependent on the film thickness and the photoinduced power density. Possible mechanisms of the observed phenomena are discussed.

Development and supply of the world energy requirement

International Nuclear Information System (INIS)

Schulz, E.

1981-01-01

Recently published research reveals that the world energy requirement can and must grow more slowly than previously anticipated. In order to supply developing nations with the energy necessary for the expansion of their economies, energy saving and oil substitution assume greater significance in the industrialised countries such as the Federal Republic. Future fulfillment of the world energy requirement will be characterised by escalating costs for supply, especially for the current main energy carrier oil, on the one hand and by increased use of coal and nuclear energy as well unconventional fossils such as regenerative energies on the other. Nuclear energy and thus the electricity economy must play a key function in the future energy supply of industrial nations such as Federal Germany. Nuclear energy enables, both directly and indirectly, the substitution of oil in the heat market, supplies the process heat required for coal production and, due to the ease of storage or uranium, provides a hedge against fluctuations on the world energy market. (orig.) [de

Finding the Missing Stratospheric Br(sub y): A Global Modeling Study of CHBr3 and CH2Br2

Science.gov (United States)

Liang, Q.; Stolarski, R. S.; Kawa, S. R.; Nielsen, J. E.; Douglass, A. R.; Rodriguez, J. M.; Blake, D. R.; Atlas, E. L.; Ott, L. E.

2010-01-01

Recent in situ and satellite measurements suggest a contribution of 5 pptv to stratospheric inorganic bromine from short-lived bromocarbons. We conduct a modeling study of the two most important short-lived bromocarbons, bromoform (CHBr3) and dibromomethane (CH2Br2), with the Goddard Earth Observing System Chemistry Climate Model (GEOS CCM) to account for this missing stratospheric bromine. We derive a "top-down" emission estimate of CHBr3 and CH2Br2 using airborne measurements in the Pacific and North American troposphere and lower stratosphere obtained during previous NASA aircraft campaigns. Our emission estimate suggests that to reproduce the observed concentrations in the free troposphere, a global oceanic emission of 425 Gg Br yr(exp -1) for CHBr3 and 57 Gg Br yr(exp -l) for CH2Br2 is needed, with 60% of emissions from open ocean and 40% from coastal regions. Although our simple emission scheme assumes no seasonal variations, the model reproduces the observed seasonal variations of the short-lived bromocarbons with high concentrations in winter and low concentrations in summer. This indicates that the seasonality of short-lived bromocarbons is largely due to seasonality in their chemical loss and transport. The inclusion of CHBr3 and CH2Br2 contributes 5 pptv bromine throughout the stratosphere. Both the source gases and inorganic bromine produced from source gas degradation (BrSLS) in the troposphere are transported into the stratosphere, and are equally important. Inorganic bromine accounts for half (2.5 pptv) of the bromine from the inclusion of CHBr3 and CHzBr2 near the tropical tropopause and its contribution rapidly increases to 100% as altitude increases. More than 85% of the wet scavenging of Br(sub y)(sup VSLS) occurs in large-scale precipitation below 500 hPa. Our sensitivity study with wet scavenging in convective updrafts switched off suggests that Br(sub y)(sup SLS) in the stratosphere is not sensitive to convection. Convective scavenging only

Nuclear and high-energy physics laboratory - LPNHE. Activity report 2004-2005

International Nuclear Information System (INIS)

Debu, Pascal; Bassler, Ursula; Boratav, Murat; Lacour, Didier; Lebbolo, Herve; Cossin, Isabelle; Mathy, Jean-Yves

2006-01-01

The LPNHE is a joint research unit (UMR 7585) of the National Institute of Nuclear Physics and Particle Physics (IN2P3), Institute of the National Centre for Scientific Research (CNRS), UPMC and Paris Diderot Paris 7. It hosts several research teams and technical services (computers, electronics, mechanical), and two support services (administration, logistics). The laboratory is engaged in several major experimental programs pursued in the framework of international collaborations with very large research facilities around the world, centers of particle accelerators and observatories. The research programs cover current issues in particle physics, astro-particle and cosmology. This report presents the activities of the laboratory during the years 2004-2005: 1 - Forewords; 2 - Scientific activities: Physics with accelerators (LHC, Tevatron, CP Violation, future linear electron collider, Neutrino beams); Physics without accelerators (Cosmology and supernovae, high-energy gamma astronomy, extreme energy cosmic radiation, theoretical physics, physics-biology interface); 3 - Technical and administrative activities (electronics, computers, mechanics departments, Administration, health and safety, radiation protection); 4 - Laboratory life (Teaching, training, internships and PhDs); 5 - Internal activities (seminars, meetings..); 6 - External activities (Public information, relations with the industry, valorisation..); 7 - List of publications; 8 - Appendixes: organigram, staff

A statistical analysis of the energy policy act of 2005, its changes to the daylight saving program, and impact on residential energy consumption

Science.gov (United States)

Murray, Patrick L.

Government programs designed to decrease resource consumption, improve productivity and capitalize on extended daylight hours in the summer have been developed and implemented throughout the world for nearly three hundred years. In 2005, The United States government adopted an extended daylight savings program that increases the number of weeks where the country observes Daylight Saving Time (DST) from 31 to 35 weeks. The program took effect in March 2007. Arguments in support of DST programs highlight the portion of electricity consumption attributed to residential lighting in the evening hours. Adjusting clocks forward by one hour in summer months is believed to reduce electricity consumption due to lighting and therefore significantly reduce residential energy consumption during the period of DST. This paper evaluates the efficacy of the changes to DST resulting from the Energy Policy Act of 2005. The study focuses on changes to household electricity consumption during the extended four weeks of DST. Arizona, one of two states that continue to opt out of DST serves as the study's control for a comparison with neighboring states, Colorado, Nebraska, Nevada, New Mexico, Oklahoma, Texas and Utah. Results from the regression analysis of a Difference in Difference model indicate that contrary to evaluations by Congress and the Department of Energy, the four week period of Extended Daylight Saving Time does not produce a significant decrease in per capita electricity consumption in Southwestern states.

Quantum state-to-state dynamics for the quenching process of Br(2P1/2) + H2(v(i) = 0, 1, j(i) = 0).

Science.gov (United States)

Xie, Changjian; Jiang, Bin; Xie, Daiqian; Sun, Zhigang

2012-03-21

Quantum state-to-state dynamics for the quenching process Br((2)P(1/2)) + H(2)(v(i) = 0, 1, j(i) = 0) → Br((2)P(3/2)) + H(2)(v(f), j(f)) has been studied based on two-state model on the recent coupled potential energy surfaces. It was found that the quenching probabilities have some oscillatory structures due to the interference of reflected flux in the Br((2)P(1/2)) + H(2) and Br((2)P(3/2)) + H(2) channels by repulsive potential in the near-resonant electronic-to-vibrational energy transfer process. The final vibrational state resolved integral cross sections were found to be dominated by the quenching process Br((2)P(1/2)) + H(2)(v) → Br((2)P(3/2)) + H(2)(v+1) and the nonadiabatic reaction probabilities for Br((2)P(1/2)) + H(2)(v = 0, 1, j(i) = 0) are quite small, which are consistent with previous theoretical and experimental results. Our calculated total quenching rate constant for Br((2)P(1/2)) + H(2)(v(i) = 0, j(i) = 0) at room temperature is in good agreement with the available experimental data. © 2012 American Institute of Physics

The 18 basic requirement of quality assurance for American design NPP

International Nuclear Information System (INIS)

Baliza, Ana Rosa

2013-01-01

On April 17th, 1969, the Atomic Energy Commission (AEC) published in the U.S. Federal Register (FR), Volume 34, Number 73, a proposed amendment to 10CFR50 to insert Appendix B - 'Quality assurance criteria for Nuclear Power Plant'. This Appendix was officially approved on June 27th, 1970 and published in the FR, volume 35, number 125. Appendix B is the Quality Assurance document for U.S. nuclear facilities. This document establishes eighteen basic requirements (BR) to design, construction, manufacture and operation of structures, systems and components (SSC) related to safety. The 18 BR describe 'what' shall be done, but not 'how' to do. In order to standardize the actions of nuclear facilities during 10 CFR 50 App B implementation, the industry has developed some documents, the main ones are: ASME NQA-1 (Quality Assurance Requirements for Nuclear Facility Applications) and the series ANSI N 45.2 (Quality Assurance Program Requirements for Nuclear Facilities). Both documents are approved by the NRC (Nuclear Regulatory Commission). The NRC is the licensing body of U.S. nuclear facilities. In Brazil, the licensing body is CNEN (Comissao Nacional de Energia Nuclear). This paper describes the 18 BR for American Designed Nuclear Power Plant (NPP), applicable to Angra-1 NPP. (author)

Nuclear Magnetic Resonance Reveals Disordered Level-Crossing Physics in the Bose-Glass Regime of the Br-Doped Ni(Cl_{1-x}Br_{x})_{2}-4SC(NH_{2})_{2} Compound at a High Magnetic Field.

Science.gov (United States)

Orlova, Anna; Blinder, Rémi; Kermarrec, Edwin; Dupont, Maxime; Laflorencie, Nicolas; Capponi, Sylvain; Mayaffre, Hadrien; Berthier, Claude; Paduan-Filho, Armando; Horvatić, Mladen

2017-02-10

By measuring the nuclear magnetic resonance (NMR) T_{1}^{-1} relaxation rate in the Br (bond) doped DTN compound, Ni(Cl_{1-x}Br_{x})_{2}-4SC(NH_{2})_{2}(DTNX), we show that the low-energy spin dynamics of its high magnetic field "Bose-glass" regime is dominated by a strong peak of spin fluctuations found at the nearly doping-independent position H^{*}≅13.6  T. From its temperature and field dependence, we conclude that this corresponds to a level crossing of the energy levels related to the doping-induced impurity states. Observation of the local NMR signal from the spin adjacent to the doped Br allowed us to fully characterize this impurity state. We have thus quantified a microscopic theoretical model that paves the way to better understanding of the Bose-glass physics in DTNX, as revealed in the related theoretical study [M. Dupont, S. Capponi, and N. Laflorencie, Phys. Rev. Lett. 118, 067204 (2017).PRLTAO0031-900710.1103/PhysRevLett.118.067204].

Pure zero-dimensional Cs4PbBr6 single crystal rhombohedral microdisks with high luminescence and stability.

Science.gov (United States)

Zhang, Haihua; Liao, Qing; Wu, Yishi; Chen, Jianwei; Gao, Qinggang; Fu, Hongbing

2017-11-08

Zero-dimensional (0D) perovskite Cs 4 PbBr 6 has been speculated to be an efficient solid-state emitter, exhibiting strong luminescense on achieving quantum confinement. Although several groups have reported strong green luminescence from Cs 4 PbBr 6 powders and nanocrystals, doubts that the origin of luminescence comes from Cs 4 PbBr 6 itself or CsPbBr 3 impurities have been a point of controversy in recent investigations. Herein, we developed a facile one-step solution self-assembly method to synthesize pure zero-dimensional rhombohedral Cs 4 PbBr 6 micro-disks (MDs) with a high PLQY of 52% ± 5% and photoluminescence full-width at half maximum (FWHM) of 16.8 nm. The obtained rhombohedral MDs were high quality single-crystalline as demonstrated by XRD and SAED patterns. We demonstrated that Cs 4 PbBr 6 MDs and CsPbBr 3 MDs were phase-separated from each other and the strong green emission comes from Cs 4 PbBr 6 . Power and temperature dependence spectra evidenced that the observed strong green luminescence of pure Cs 4 PbBr 6 MDs originated from direct exciton recombination in the isolated octahedra with a large binding energy of 303.9 meV. Significantly, isolated PbBr 6 4- octahedra separated by a Cs + ion insert in the crystal lattice is beneficial to maintaining the structural stability, depicting superior thermal and anion exchange stability. Our study provides an efficient approach to obtain high quality single-crystalline Cs 4 PbBr 6 MDs with highly efficient luminescence and stability for further optoelectronic applications.

Maintenance Energy Requirements of Double-Muscled Belgian Blue Beef Cows

Directory of Open Access Journals (Sweden)

Leo O. Fiems

2015-02-01

Full Text Available Sixty non-pregnant, non-lactating double-muscled Belgian Blue (DMBB cows were used to estimate the energy required to maintain body weight (BW. They were fed one of three energy levels for 112 or 140 days, corresponding to approximately 100%, 80% or 70% of their total energy requirements. The relationship between daily energy intake and BW and daily BW change was developed using regression analysis. Maintenance energy requirements were estimated from the regression equation by setting BW gain to zero. Metabolizable and net energy for maintenance amounted to 0.569 ± 0.001 and 0.332 ± 0.001 MJ per kg BW0.75/d, respectively. Maintenance energy requirements were not dependent on energy level (p > 0.10. Parity affected maintenance energy requirements (p < 0.001, although the small numerical differences between parities may hardly be nutritionally relevant. Maintenance energy requirements of DMBB beef cows were close to the mean energy requirements of other beef genotypes reported in the literature.

Maintenance Energy Requirements of Double-Muscled Belgian Blue Beef Cows.

Science.gov (United States)

Fiems, Leo O; De Boever, Johan L; Vanacker, José M; De Campeneere, Sam

2015-02-13

Sixty non-pregnant, non-lactating double-muscled Belgian Blue (DMBB) cows were used to estimate the energy required to maintain body weight (BW). They were fed one of three energy levels for 112 or 140 days, corresponding to approximately 100%, 80% or 70% of their total energy requirements. The relationship between daily energy intake and BW and daily BW change was developed using regression analysis. Maintenance energy requirements were estimated from the regression equation by setting BW gain to zero. Metabolizable and net energy for maintenance amounted to 0.569 ± 0.001 and 0.332 ± 0.001 MJ per kg BW(0.75)/d, respectively. Maintenance energy requirements were not dependent on energy level (p > 0.10). Parity affected maintenance energy requirements (p < 0.001), although the small numerical differences between parities may hardly be nutritionally relevant. Maintenance energy requirements of DMBB beef cows were close to the mean energy requirements of other beef genotypes reported in the literature.

The sensitivity of LaBr{sub 3}:Ce scintillation detectors to low energy neutrons: Measurement and Monte Carlo simulation

Energy Technology Data Exchange (ETDEWEB)

Tain, J.L., E-mail: tain@ific.uv.es [Instituto de Física Corpuscular, CSIC–Universidad de Valencia, Apdo. Correos 22085, E-46071 Valencia (Spain); Agramunt, J.; Algora, A. [Instituto de Física Corpuscular, CSIC–Universidad de Valencia, Apdo. Correos 22085, E-46071 Valencia (Spain); Aprahamian, A. [University of Notre Dame, Department of Physics, IN 46556, Notre Dame (United States); Cano-Ott, D. [Centro de Investigaciones Energéticas Medioambientales y Tecnológicas, E-28040 Madrid (Spain); Fraile, L.M. [Universidad Complutense, Grupo de Fisica Nuclear, CEI Moncloa, E-28040 Madrid (Spain); Guerrero, C. [CERN, Geneva (Switzerland); Jordan, M.D. [Instituto de Física Corpuscular, CSIC–Universidad de Valencia, Apdo. Correos 22085, E-46071 Valencia (Spain); Mach, H. [University of Notre Dame, Department of Physics, IN 46556, Notre Dame (United States); Universidad Complutense, Grupo de Fisica Nuclear, CEI Moncloa, E-28040 Madrid (Spain); Martinez, T.; Mendoza, E. [Centro de Investigaciones Energéticas Medioambientales y Tecnológicas, E-28040 Madrid (Spain); Mosconi, M.; Nolte, R. [Physikalisch-Technische Bundesanstalt, D-38116 Braunschweig (Germany)

2015-02-21

The neutron sensitivity of a cylindrical ⊘1.5 in.×1.5 in. LaBr{sub 3}:Ce scintillation detector was measured using quasi-monoenergetic neutron beams in the energy range from 40 keV to 2.5 MeV. In this energy range the detector is sensitive to γ-rays generated in neutron inelastic and capture processes. The experimental energy response was compared with Monte Carlo simulations performed with the Geant4 simulation toolkit using the so-called High Precision Neutron Models. These models rely on relevant information stored in evaluated nuclear data libraries. The performance of the Geant4 Neutron Data Library as well as several standard nuclear data libraries was investigated. In the latter case this was made possible by the use of a conversion tool that allowed the direct use of the data from other libraries in Geant4. Overall it was found that there was good agreement with experiment for some of the neutron data bases like ENDF/B-VII.0 or JENDL-3.3 but not with the others such as ENDF/B-VI.8 or JEFF-3.1.

Scientific and Technological Report 2005; Informe Cientifico Tecnologico 2005

Energy Technology Data Exchange (ETDEWEB)

Prado Cuba, Antonio; Robles Nique, Anita; Rodriguez R, Juan; Solis Veliz, Jose [eds.

2006-07-15

This annual scientific and technological report provides an overview of research and development activities at Peruvian Institute of Nuclear Energy (IPEN) during the period from 1 january to 31 december, 2005. This report includes 38 papers divided in 7 subject matters, such as: physics and chemistry, materials science, nuclear engineering, industrial and environmental applications, medical and biological applications, radiation protection and nuclear safety, and management aspects.

Imbedded Nanocrystals of CsPbBr3 in Cs4 PbBr6 : Kinetics, Enhanced Oscillator Strength, and Application in Light-Emitting Diodes.

Science.gov (United States)

Xu, Junwei; Huang, Wenxiao; Li, Peiyun; Onken, Drew R; Dun, Chaochao; Guo, Yang; Ucer, Kamil B; Lu, Chang; Wang, Hongzhi; Geyer, Scott M; Williams, Richard T; Carroll, David L

2017-11-01

Solution-grown films of CsPbBr 3 nanocrystals imbedded in Cs 4 PbBr 6 are incorporated as the recombination layer in light-emitting diode (LED) structures. The kinetics at high carrier density of pure (extended) CsPbBr 3 and the nanoinclusion composite are measured and analyzed, indicating second-order kinetics in extended and mainly first-order kinetics in the confined CsPbBr 3 , respectively. Analysis of absorption strength of this all-perovskite, all-inorganic imbedded nanocrystal composite relative to pure CsPbBr 3 indicates enhanced oscillator strength consistent with earlier published attribution of the sub-nanosecond exciton radiative lifetime in nanoprecipitates of CsPbBr 3 in melt-grown CsBr host crystals and CsPbBr 3 evaporated films. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Comparabilidade entre o resultado em BR GAAP e U.S. GAAP: evidências das companhias brasileiras listadas nas bolsas norte-americanas Comparability between BR GAAP and U.S. GAAP results: evidence from Brazilian companies listed on North American stock exchanges

Directory of Open Access Journals (Sweden)

Sirlei Lemes

2009-08-01

Full Text Available Esta pesquisa avalia a materialidade das diferenças de reconciliação dos lucros divulgados por empresas brasileiras. Dada a inexistência de demonstrações contábeis conforme as IFRS publicadas por empresas brasileiras, a amostra foi composta de empresas que divulgam o resultado, segundo os Br GAAP e os U.S. GAAP, nos Form 20-F arquivados na SEC. Por meio de uma pesquisa exploratória, em função dos seus objetivos, e documental, em consequência da coleta de dados, aplicou-se o Índice de Comparabilidade de Gray (GRAY, 1980 às diferenças evidenciadas por 30 companhias brasileiras nos anos de 2000 a 2005. Os resultados indicam um número representativo de empresas com resultados materialmente não comparáveis, sendo três para uma margem de materialidade de 5%, seis a 10% e, para 15%, somente 21 das 30 empresas apresentaram lucros comparáveis. Analisando as reconciliações de 10 empresas do ano de 2005, o ajuste referente à combinação de empresas foi o que afetou o maior número de empresas e quanto à reavaliação de ativos, caracteristicamente apontada como uma prática que demanda frequentes ajustes aos U.S. GAAP, não foi observada a reconciliação para a maioria das empresas. Sugerem-se estudos adicionais para identificar diferenças específicas para um maior número de empresas e anos.This research assesses the materiality of the reconciliation differences in profits reported by Brazilian companies. Given the non-existence of IFRS compatible accounting statements for Brazilian companies, the sample was composed of enterprises that publish the result according to Br GAAP and U.S. GAAP on the 20-F Form filed at the Securities and Exchange Commission (SEC. By means of an exploratory - in function of its objectives - and documentary research - due to the data collection method - Gray's Index of Comparability (Gray, 1980 was applied to the differences evidenced for 30 Brazilian companies between 2000 and 2005. The results

Germylenes: structures, electron affinities, and singlet-triplet gaps of the conventional XGeCY(3) (X = H, F, Cl, Br, and I; Y = F and Cl) species and the unexpected cyclic XGeCY(3) (Y = Br and I) systems.

Science.gov (United States)

Bundhun, Ashwini; Abdallah, Hassan H; Ramasami, Ponnadurai; Schaefer, Henry F

2010-12-23

A systematic investigation of the X-Ge-CY(3) (X = H, F, Cl, Br, and I; Y = F, Cl, Br, and I) species is carried out using density functional theory. The basis sets used for all atoms (except iodine) in this work are of double-ζ plus polarization quality with additional s- and p-type diffuse functions, and denoted DZP++. Vibrational frequency analyses are performed to evaluate zero-point energy corrections and to determine the nature of the stationary points located. Predicted are four different forms of neutral-anion separations: adiabatic electron affinity (EA(ad)), zero-point vibrational energy corrected EA(ad(ZPVE)), vertical electron affinity (EA(vert)), and vertical detachment energy (VDE). The electronegativity (χ) reactivity descriptor for the halogens (X = F, Cl, Br, and I) is used as a tool to assess the interrelated properties of these germylenes. The topological position of the halogen atom bound to the divalent germanium center is well correlated with the trend in the electron affinities and singlet-triplet gaps. For the expected XGeCY(3) structures (X = H, F, Cl, Br, and I; Y = F and Cl), the predicted trend in the electron affinities is well correlated with simpler germylene derivatives (J. Phys. Chem. A 2009, 113, 8080). The predicted EA(ad(ZPVE)) values with the BHLYP functional range from 1.66 eV (FGeCCl(3)) to 2.20 eV (IGeCF(3)), while the singlet-triplet splittings range from 1.28 eV (HGeCF(3)) to 2.22 eV (FGeCCl(3)). The XGeCY(3) (Y = Br and I) species are most often characterized by three-membered cyclic systems involving the divalent germanium atom, the carbon atom, and a halogen atom.

Photoproduction of I2, Br2, and Cl2 on n-semiconducting powder

Science.gov (United States)

Reichman, B.; Byvik, C. E.

1981-01-01

The photosynthetic production of Br2 and Cl2 and the photocatalytic production of I2 from aqueous solutions of the respective halide ions in the presence of platinized semiconducting n-TiO2 powder are reported. Reactions were produced in 2-3 M oxygen-saturated aqueous solutions of KI, KBr or NaCl containing Pt-TiO2 powder which were irradiated by a high-pressure mercury lamp at a power of 400 mW/sq cm. Halogens are found to be produced in greater quantities when platinized TiO2 powders are used rather than pure TiO2, and rates of halogen production are observed to increase from Cl2 to Br2 to I2. The presence of the synthetic reactions producing Br2 and Cl2 with a net influx of energy indicates that an effective separation of the photoproduced electron-hole pair occurs in the semiconductor. Quantum efficiencies of the reaction, which increase with decreasing solution pH, are found to be as high as 30%, implying a solar-to-chemical energy conversion efficiency between 0.03% and 3% for the case of chlorine production. It is concluded that the photoproduction of halogens may be of practical value if product halogens are efficiently removed from the reaction cell.

Maintenance Energy Requirements of Double-Muscled Belgian Blue Beef Cows

Science.gov (United States)

Fiems, Leo O.; De Boever, Johan L.; Vanacker, José M.; De Campeneere, Sam

2015-01-01

Simple Summary Double-muscled Belgian Blue animals are extremely lean, characterized by a deviant muscle fiber type with more fast-glycolytic fibers, compared to non-double-muscled animals. This fiber type may result in lower maintenance energy requirements. On the other hand, lean meat animals mostly have a higher rate of protein turnover, which requires more energy for maintenance. Therefore, maintenance requirements of Belgian Blue cows were investigated based on a zero body weight gain. This technique showed that maintenance energy requirements of double-muscled Belgian Blue beef cows were close to the mean requirements of cows of other beef genotypes. Abstract Sixty non-pregnant, non-lactating double-muscled Belgian Blue (DMBB) cows were used to estimate the energy required to maintain body weight (BW). They were fed one of three energy levels for 112 or 140 days, corresponding to approximately 100%, 80% or 70% of their total energy requirements. The relationship between daily energy intake and BW and daily BW change was developed using regression analysis. Maintenance energy requirements were estimated from the regression equation by setting BW gain to zero. Metabolizable and net energy for maintenance amounted to 0.569 ± 0.001 and 0.332 ± 0.001 MJ per kg BW0.75/d, respectively. Maintenance energy requirements were not dependent on energy level (p > 0.10). Parity affected maintenance energy requirements (p < 0.001), although the small numerical differences between parities may hardly be nutritionally relevant. Maintenance energy requirements of DMBB beef cows were close to the mean energy requirements of other beef genotypes reported in the literature. PMID:26479139

Projecting India's energy requirements for policy formulation

International Nuclear Information System (INIS)

Parikh, Kirit S.; Karandikar, Vivek; Rana, Ashish; Dani, Prasanna

2009-01-01

Energy policy has to have a long-term perspective. To formulate it one needs to know the contours of energy requirements and options. Different approaches have been followed in literature, each with their own problems. A top down econometric approach provides little guidance on policies, while a bottom up approval requires too much knowledge and too many assumptions. Using top-down econometric approach for aggregate overall benchmarking and a detailed activity analysis model, Integrated Energy System Model, for a few large sectors, provides a unique combination for easing the difficulties of policy formulation. The model is described in this paper. Eleven alternate scenarios are built, designed to map out extreme points of feasible options. Results show that even after employing all domestic energy resource to their full potential, there will be a continued rise of fossil fuel use, continued importance of coal, and continued rise of import dependence. Energy efficiency emerges as a major option with a potential to reduce energy requirement by as much as 17%. Scenario results point towards pushing for development of alternative sources. (author)

BrO measurements over the Eastern North-Atlantic

Directory of Open Access Journals (Sweden)

U. Platt

2009-12-01

Full Text Available The aim of the work presented here was to detect BrO in the marine boundary layer over the Eastern North-Atlantic by Multi AXis-Differential Optical Absorption Spectroscopy (MAX-DOAS of scattered sunlight. With this technique, information about the concentration and the vertical profile of trace gases in the atmosphere can be gained. BrO can be formed in the marine atmosphere by degradation of biogenic organohalogens or by oxidation of bromide in sea salt aerosol. BrO influences the chemistry in marine air in many ways, e.g. since it catalytically destroys ozone, changes the NO₂/NO-ratio as well as the OH/HO₂-ratio and oxidises DMS. However, the abundance and the significance of BrO in the marine atmosphere is not yet fully understood. <br>> We report on data collected during a ship cruise, which took place along the West African Coast in February 2007, within the framework of the Surface Ocean PRocesses in the ANthropocene project (SOPRAN. Tropospheric BrO could be detected during this cruise at peak mixing ratios of (10.2±3.7 ppt at an assumed layer height of 1 km on 18 February 2007. Furthermore, it was found that the mean BrO concentrations increased when cruising close to the African Coast suggesting that at least part of the BrO might have originated from there.

End-of-year-closure 2005/2006

CERN Multimedia

HR Department

2005-01-01

As announced in Weekly Bulletin Nº 2/2005, the Laboratory will be closed from Thursday 22 December 2005 to Wednesday 4 January 2006 inclusive. This period consists of 14 days: 4 days' official holiday, i.e. 24, 25 and 31 December 2005 and 1st January 2006; 6 days' special paid leave in accordance with Article R II 4.34 of the Staff Regulations, i.e.  26, 27, 28, 29, 30 December 2005 and 4 January 2006; 4 days, 22 and 23 December 2005 to compensate for 24 and 25 December 2005 and 2 and 3 January 2006 to compensate for 31 December 2005 and 1st January 2006 (Article R II 4.33 of the Staff Regulations); The first working day in the New Year will be Thursday, 5 January 2006. Further information is available from Department Secretariats, specifically concerning the conditions applicable to members of the personnel who are required to work during this period. Human Resources Department Tel. 73903

End-of-year-closure 2005/2006

CERN Multimedia

2005-01-01

As announced in Weekly Bulletin No. 2/2005, the Laboratory will be closed from Thursday 22 December 2005 to Wednesday 4 January 2006 inclusive. This period consists of 14 days: 4 days' official holiday, i.e. 24, 25 and 31 December 2005 and 1st January 2006; 6 days' special paid leave in accordance with Article R II 4.34 of the Staff Regulations, i.e.  26, 27, 28, 29, 30 December 2005 and 4 January 2006; 4 days, 22 and 23 December 2005 to compensate for 24 and 25 December 2005 and 2 and 3 January 2006 to compensate for 31 December 2005 and 1st January 2006 (Article R II 4.33 of the Staff Regulations); The first working day in the New Year will be Thursday, 5 January 2006. Further information is available from Department Secretariats, specifically concerning the conditions applicable to members of the personnel who are required to work during this period. Human Resources Department Tel. 73903

Rashba split surface states in BiTeBr

International Nuclear Information System (INIS)

Eremeev, S V; Rusinov, I P; Nechaev, I A; Chulkov, E V

2013-01-01

Within density functional theory, we study the bulk band structure and surface states of BiTeBr. We consider both ordered and disordered phases, which differ in atomic order in the Te–Br sublattice. On the basis of relativistic ab initio calculations, we show that the ordered BiTeBr is energetically preferable as compared with the disordered one. We demonstrate that both Te- and Br-terminated surfaces of the ordered BiTeBr hold surface states with a giant spin–orbit splitting. The Te-terminated surface-state spin splitting has Rashba-type behavior with the coupling parameter α R ∼ 2 eVÅ. (paper)

Reduced γ–γ time walk to below 50 ps using the multiplexed-start and multiplexed-stop fast-timing technique with LaBr_3(Ce) detectors

International Nuclear Information System (INIS)

Régis, J.-M.; Saed-Samii, N.; Rudigier, M.; Ansari, S.; Dannhoff, M.; Esmaylzadeh, A.; Fransen, C.; Gerst, R.-B.; Jolie, J.; Karayonchev, V.; Müller-Gatermann, C.; Stegemann, S.

2016-01-01

The electronic γ–γ fast-timing technique using arrays consisting of many LaBr_3(Ce) detectors is a powerful method to determine lifetimes of nuclear excited states with a lower limit of about 5 ps. This method requires the determination of the energy-dependent time walk of the zero time which is represented by the centroid of a prompt γ–γ time distribution. The full-energy peak versus full-energy peak prompt response difference which represents the linearly combined mean γ–γ time walk of a fast-timing array consisting of 8 LaBr_3(Ce) detectors was measured using a standard "1"5"2Eu γ-ray source for the energy region of 40–1408 keV. The data were acquired using a “multiplexed-start and multiplexed-stop” analogue electronics circuitry and analysed by employing the generalized centroid difference method. Concerning the cylindrical 1.5 in.×1.5 in. LaBr_3(Ce) crystals which are coupled to the Hamamatsu R9779 photomultiplier tubes, the best fast-timing array time resolution of 202(3) ps is obtained for the two prompt γ lines of "6"0Co by using the leading-edge timing principle. When using the zero-crossover timing principle the time resolution is degraded by up to 30%, dependent on the energy and the shaping delay time of the constant fraction discriminator model Ortec 935. The smallest γ–γ time walk to below 50 ps is obtained by using a shaping delay time of about 17 ns and an optimum “time-walk adjustment” needed for detector output pulses with amplitudes smaller than 400 mV.

Brominated methanes as photoresponsive molecular storage of elemental Br2.

Science.gov (United States)

Kawakami, Kazumitsu; Tsuda, Akihiko

2012-10-01

The photochemical generation of elemental Br(2) from brominated methanes is reported. Br(2) was generated by the vaporization of carbon oxides and HBr through oxidative photodecomposition of brominated methanes under a 20 W low-pressure mercury lamp, wherein the amount and situations of Br(2) generation were photochemically controllable. Liquid CH(2)Br(2) can be used not only as an organic solvent but also for the photoresponsive molecular storage of Br(2), which is of great technical benefit in a variety of organic syntheses and in materials science. By taking advantage of the in situ generation of Br(2) from the organic solvent itself, many organobromine compounds were synthesized in high practical yields with or without the addition of a catalyst. Herein, Br(2) that was generated by the photodecomposition of CH(2)Br(2) retained its reactivity in solution to undergo essentially the same reactions as those that were carried out with solutions of Br(2) dissolved in CH(2)Br(2) that were prepared without photoirradiation. Furthermore, HBr, which was generated during the course of the photodecomposition of CH(2)Br(2), was also available for the substitution of the OH group for the Br group and for the preparation of the HBr salts of amines. Furthermore, the photochemical generation of Br(2) from CH(2)Br(2) was available for the area-selective photochemical bleaching of natural colored plants, such as red rose petals, wherein Br(2) that was generated photochemically from CH(2)Br(2) was painted onto the petal to cause radical oxidations of the chromophoric anthocyanin molecules. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Zn2(TeO3Br2

Directory of Open Access Journals (Sweden)

Mats Johnsson

2008-05-01

Full Text Available Single crystals of dizinc tellurium dibromide trioxide, Zn2(TeO3Br2, were synthesized via a transport reaction in sealed evacuated silica tubes. The compound has a layered crystal structure in which the building units are [ZnO4Br] distorted square pyramids, [ZnO2Br2] distorted tetrahedra, and [TeO3E] tetrahedra (E being the 5s2 lone pair of Te4+ joined through sharing of edges and corners to form layers of no net charge. Bromine atoms and tellurium lone pairs protrude from the surfaces of each layer towards adjacent layers. This new compound Zn2(TeO3Br2 is isostructural with the synthetic compounds Zn2(TeO3Cl2, CuZn(TeO32, Co2(TeO3Br2 and the mineral sophiite, Zn2(SeO3Cl2.

On the electrodeposition of /sup 80m/Br, /sup 80/Br and /sup 82/Br species from (eta, gamma) activated dibromoethane - N,N-dimethyl aniline mixture

International Nuclear Information System (INIS)

Zaman, M.R.

1997-01-01

Thermal neutron activation have been carried out in dibromomethane (DBM)-n,n-dimethyl aniline (N,N-DMA) system and the /sup 80m/Br, /sup 82/Br species have been electrodeposited on Ag/AgBr electrodes under a constant electric field of 175 volts cm/sup -1/. With the addition of N,N-DMA, anodic deposition has been severely decreased for all the radiobromines and cathode plate shows zero activities. Results are critically discussed by explaining the chemical reactivity of the amine. Electrode deposition pattern and the chemical stabilization mode of the nucleogenic bromine species in this system are deduced to some extents. (author)

Solution-Grown CsPbBr3 /Cs4 PbBr6 Perovskite Nanocomposites: Toward Temperature-Insensitive Optical Gain.

Science.gov (United States)

Wang, Yue; Yu, Dejian; Wang, Zeng; Li, Xiaoming; Chen, Xiaoxuan; Nalla, Venkatram; Zeng, Haibo; Sun, Handong

2017-09-01

With regards to developing miniaturized coherent light sources, the temperature-insensitivity in gain spectrum and threshold is highly desirable. Quantum dots (QDs) are predicted to possess a temperature-insensitive threshold by virtue of the separated electronic states; however, it is never observed in colloidal QDs due to the poor thermal stability. Besides, for the classical II-VI QDs, the gain profile generally redshifts with increasing temperature, plaguing the device chromaticity. Herein, this paper addresses the above two issues simultaneously by embedding ligands-free CsPbBr 3 nanocrystals in a wider band gap Cs 4 PbBr 6 matrix by solution-phase synthesis. The unique electronic structures of CsPbBr 3 nanocrystals enable temperature-insensitive gain spectrum while the lack of ligands and protection from Cs 4 PbBr 6 matrix ensure the thermal stability and high temperature operation. Specifically, a color drift-free stimulated emission irrespective of temperature change (20-150 °C) upon two-photon pumping is presented and the characteristic temperature is determined to be as high as ≈260 K. The superior gain properties of the CsPbBr 3 /Cs 4 PbBr 6 perovskite nanocomposites are directly validated by a vertical cavity surface emitting laser operating at temperature as high as 100 °C. The results shed light on manipulating optical gain from the advantageous CsPbBr 3 nanocrystals and represent a significant step toward the temperature-insensitive frequency-upconverted lasers. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Preparation of radioactive labelled compounds Pt.1. 82Br labelled organic bromine compounds

International Nuclear Information System (INIS)

Otto, R.

1988-05-01

A simple method allowing the preparation of 82 Br labelled organic bromine compounds from olefins with chemical and radiochemical yields between 75 and 95% and the specific activities required, is described [fr

Performance of LiAlloy/Ag(2)CrO(4) Couples in Molten CsBr-LiBr-KBr Eutectic

International Nuclear Information System (INIS)

GUIDOTTI, RONALD A.; REINHARDT, FREDERICK W.

1999-01-01

The performance of Li-alloy/CsBr-LiBr-KBr/Ag(sub 2)CrO(sub 4) systems was studied over a temperature range of 250 C to 300 C, for possible use as a power source for geothermal borehole applications. Single cells were discharged at current densities of 15.8 and 32.6 mA/cm(sup 2) using Li-Si and Li-Al anodes. When tested in 5-cell batteries, the Li-Si/CsBr-LiBr-KBr/Ag(sub 2)CrO(sub 4) system exhibited thermal runaway. Thermal analytical tests showed that the Ag(sub 2)CrO(sub 4) cathode reacted exothermically with the electrolyte on activation. Consequently, this system would not be practical for the envisioned geothermal borehole applications

Energy requirements for growth in the Yorkshire terrier.

Science.gov (United States)

Alexander, Janet E; Colyer, Alison; Morris, Penelope J

2017-01-01

The 2006 National Research Council (NRC) equation calculating puppy energy requirements does not account for reported breed differences in growth pattern. Energy requirements of toy breed puppies are unknown and it is unclear whether feeding guidelines should differ between breeds. Energy requirements of Yorkshire terrier (YT) puppies were observed over their first year of life and compared with those predicted by the NRC and those previously observed in large (Labrador retriever) and medium (miniature Schnauzer; MS) breed puppies. Twenty-two puppies (from eight litters) were offered complete and balanced diets to maintain ideal body condition score (BCS). Energy intake, body weight and BCS were recorded from 10 to 52 weeks of age. Every 12 weeks, health was monitored by veterinary examination, routine haematology and plasma biochemistry. Puppies remained clinically healthy with normal skeletal development throughout. After analysis by linear mixed models it was observed that the NRC equation overestimates YT energy requirements between 10 and 20 weeks of age by up to 324·3 (95 % CI 390·4, 258·2) kJ/kg 0·75 . Energy intake was lower ( P  < 0·05) in YT than Labradors until 29 weeks by up to 376·6 (95 % CI 477·4, 275·3) kJ/kg 0·75 and lower than MS between 16 and 25 weeks by up to 216·3 (95 % CI 313·0, 119·7) kJ/kg 0·75 ( P  < 0·05). Data indicate differences in toy, medium and large breed energy requirements for growth. The NRC equation for puppy energy requirements overestimated the requirements of this YT population, suggesting the need for breed-specific feeding guides for growth to avoid overfeeding.

Energy requirements, protein-energy metabolism and balance, and carbohydrates in preterm infants.

Science.gov (United States)

Hay, William W; Brown, Laura D; Denne, Scott C

2014-01-01

Energy is necessary for all vital functions of the body at molecular, cellular, organ, and systemic levels. Preterm infants have minimum energy requirements for basal metabolism and growth, but also have requirements for unique physiology and metabolism that influence energy expenditure. These include body size, postnatal age, physical activity, dietary intake, environmental temperatures, energy losses in the stool and urine, and clinical conditions and diseases, as well as changes in body composition. Both energy and protein are necessary to produce normal rates of growth. Carbohydrates (primarily glucose) are principle sources of energy for the brain and heart until lipid oxidation develops over several days to weeks after birth. A higher protein/energy ratio is necessary in most preterm infants to approximate normal intrauterine growth rates. Lean tissue is predominantly produced during early gestation, which continues through to term. During later gestation, fat accretion in adipose tissue adds increasingly large caloric requirements to the lean tissue growth. Once protein intake is sufficient to promote net lean body accretion, additional energy primarily produces more body fat, which increases almost linearly at energy intakes >80-90 kcal/kg/day in normal, healthy preterm infants. Rapid gains in adiposity have the potential to produce later life obesity, an increasingly recognized risk of excessive energy intake. In addition to fundamental requirements for glucose, protein, and fat, a variety of non-glucose carbohydrates found in human milk may have important roles in promoting growth and development, as well as production of a gut microbiome that could protect against necrotizing enterocolitis. © 2014 S. Karger AG, Basel.