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Sample records for yuko riyo ni

  1. Utilization of coal fired power plant by-products. Utilization of coal ash; Sekitan karyoku ni okeru fukusanbutsu no yuko riyo gijutsu. Sekitanbai no yuko riyo

    Energy Technology Data Exchange (ETDEWEB)

    Kishimoto, K. [The Federation of Electric Power Companies, Tokyo (Japan); Watanabe, M. [Electric Power Development Co. Ltd., Tokyo (Japan)

    1997-11-05

    The paper introduced the present situation and future task of the tackling with effective use of coal ash discharged from coal thermal power plants. Making the use of the characteristics, coal ash is mostly used in the fields of cement/concrete, civil engineering/construction, and agriculture/forestry/fisheries. In the case of using fly ash to concrete, the effects are the heightening of long-term strength, increase in workability, decrease in hydration heat, control of alkali aggregate reaction, etc. In the civil engineering/construction field, coal ash is allowed to be used for road bed material and mixed civil engineering material as road materials, for revetment back-filling material, soft ground surface layer treatment, soft ground/soil improvement materials, FGC deep layer mixing treatment process, SPC (sand compaction pile) material, etc. as earth work materials. Besides, it is used for light coarse aggregate, light sand, etc., as construction materials, for material substituting ceramics products, etc. as building materials, and for agricultural material, potassium silicate fertilizer and ocean structure in the agriculture/forestry/fisheries field. 4 refs., 2 tabs.

  2. Pressure on Yukos growing

    International Nuclear Information System (INIS)

    Slovak, K.

    2006-01-01

    The fate of the Russian oil concern Yukos seems to be sealed. The former rising star of the Russian energy firmament seems to be dying under the pressure of local state administration. Tax arrears, the fact that the owner Mikhail Khodorkovsky was jailed and the company placed under forced administration reflects the conflict between business and political interests in Russia. And the conflict also has an impact on Slovakia. In the portfolio of Yukos Finance, the Dutch subsidiary of Yukos, are assets that are very attractive for Russian oil concerns. One of them is the Slovak operator of the Druzba pipeline, Transpetrol. Yukos Finance owns 49% of the company's shares. Last year, the company signed a contract with the Russian oil company Russneft on the sale of the stake for 103 mil. USD. According to a contract signed in 2002 that stipulated the conditions under which the Slovak state sold the Transpetrol shares to Yukos for the next 5 years such a step has to be approved by the Ministry of Economy. The Dutch company can also sell the shares without such an approval but then it has to pay a penalty fine. In such a case Slovakia would get 50% of the original amount, i.e. 37 mil. USD. (author)

  3. Fiscal 1997 survey report on the project on energy conservation by effectively using building energy in Indonesia; 1997 nendo chosa hokokusho (Indonesia ni okeru biru energy yuko riyo ni yoru sho energy ka project chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    As an energy conservation method for a model building, the following eight methods were selected and trially calculated of the effects. 1) adoption of high efficient illumination apparatus, 2) introduction of an illuminance control system, 3) cooling water secondary pump with invertor, 4) ventilation control for parking lots, 5) heightening of the established temperature, 6) improvement of the 24-hour run chiller, 7) elevator with invertor, and 8) introduction of the photovoltaic power generation. As a result, it was found out that energy was totally reduced by about 3,837.4 MWh/yr or 25.6%. If viewed from the amount of reduction in greenhouse gas, the amount of CO2 emitted from office buildings, approximately 0.22 million t-C/yr, decreases to approximately 0.16 million t-C/yr. Further, approximately 0.93 million t-C/yr, the amount of CO2 emitted from commercial use facilities such as office buildings, department stores and hotels is reduced to about 0.69 million t-C/yr, thanks to the effect of the project on energy saving buildings, which made a CO2 reduction by approximately 0.24 million t-C/yr possible. Validity of the project on energy conservation in Indonesia was confirmed. 2 refs., 55 figs., 38 tabs.

  4. FY 2000 project on the research cooperation for the environmental response type water resource effective utilization system; 2000 nendo kenkyu kyoryoku jigyo. Kankyo taiogata mizu shigen yuko riyo system ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of prevention of water pollution, stable water supply in the Philippines, etc., developmental study was made of a waste water treatment/water recycling system, and the FY 2000 results were summed up. In the operational study of Pilot Plant 1, for the waste water in the papermaking process of used paper recycling plant, development was studied of a waste water treatment/water recycling system. There occurred problems on minuteness, outflow, etc. of anaerobic granules, but those were caused by malfunction of SS removal equipment at plant side. The problems were solved by increasing flocculation/precipitation facilities. As to Pilot Plant 2 of which the R and D are planned to be started in April 2001, the food processing plant was surveyed for study, and SYSCORE was selected. Relating to the waste water treatment test of Pilot Plant 2, researchers of the Industrial Technology Development Institute (ITDI) of the Philippines conducted it under the guidance of the experimental data analysis. Besides, the paper carried out the training for technology spread/acceptance, technology spread seminar, support study in Japan, etc. (NEDO)

  5. FY 2000 Report on survey results. Curtailment of the carbon dioxide emission by effective use of woody biomass system waste; 2000 nendo mokushitsu biomass kei haikibutsu no yuko riyo ni yoru nisanka tanso haishutsu no sakugen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    It is estimated that the woody biomass resources in Japan total 42.70 million t/y on a dry basis (indigenous production: 20.00 million t/y), which corresponds to 18.00 million t/y as oil. This project studies effective utilization of low-quality biomass resources now discarded, e.g., thinning materials and demolition woods, by reference to biomass utilization pursued in European and North American countries. The study activities cover the 3 areas of woody biomass wastes, current status of biomass utilization technologies in the overseas countries, and feasibility of introduction of the utilization technologies, after investigating necessity of abatement of the green-effect gases, current status of energy demands and policies, and woody biomass. Utilization of biomass resources for low-temperature heat purposes, which is the central issue in Japan, is not well established both technologically and politically. Moreover, the biomass resources are not exposed to price competition. Based on these premises, a total of 6 scenarios are proposed to promote utilization of biomass resources, including power/heat co-generation at a wood processing center, and dual firing at existing coal-fired boilers. (NEDO)

  6. Fiscal 1999 technical survey report. Model project implementation feasibility study in Malaysia on effective utilization of waste heat from paper sludge incineration; 1999 nendo Malaysia ni okeru seishi sludge nensho hainetsu yuko riyo model jigyo jisshi kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Efforts are under way to popularize practical energy conservation technologies through verification on real machines in target countries. Possibilities were studied that Malaysian paper making plants would adopt technologies of collecting heat from high-temperature exhaust gas from paper sludge incineration and of effectively utilizing the thus-collected heat. The Malaysian paper making industry produced 800-thousand tons or more in 1998, covering 72% of the total national demand. Heat recovery facilities may be installed in 15 plants. On-site surveys were made into their actual states, and then Genting Sanyen Industrial Paper Sdn. Bhd. was selected as the plant for the model project, and detailed model project feasibility studies were conducted. The studies covered the amount of wastes from paper making, their properties, treatment process, amounts of utilities to be used during system operation, land on which to build the facilities, and a plan for collecting invested funds. As the result, it was concluded in view of the magnitude of the expected fruit that the model project be implemented at this plant. (NEDO)

  7. 1998 research cooperation project. Research cooperation on environment-compatible type water resource effective-utilization system; 1998 nendo kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For the purpose of securing water stably and preventing water pollution in the Philippines, R and D were carried out on a wastewater treatment and water reclamation and reuse system which is easy to operate and maintain and low in cost through the research cooperation between the Philippine Industrial Technology Development Institute and Japan. According to the survey result of statistical data concerning water pollution load structure by industrial wastewater classified by the industry in the Philippines, enumerated are the food manufacturing industry, paper pulp manufacturing industry, and the textile dyeing industry as those greatly affecting water pollution in BOD exhaust and wastewater, etc. Consequently, with Ram Food Product Co. of vegetable processing and Solid Mill Co., of textile dyeing as plants to be studied, a wastewater treatment test was performed in a laboratory scale. From the result of the test, the pilot plant was basically designed to have 'anaerobic + aerobic treatment + tertiary treatment' for the treatment process, with an one-tank type UASB method used as the anaerobic treatment, with a sand filtration + activated charcoal treatment as the tertiary treatment, and with the cost effectiveness for water reuse set to be examined. (NEDO)

  8. Report on survey of international cooperation possibility on chemical CO2 fixation and utilization technology in FY 1997; 1997 nendo chosa hokokusho (kagakuteki CO2 koteika yuko riyo gijutsu ni kakawaru kokusai kyoryoku kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This survey focused on the end of the more promising companion and promoting the international cooperation on chemical CO2 fixation and utilization technology. As a result, the way of the carrying-forward of the international cooperation with more than one companion could be arranged beforehand. It led to getting an arrangement about a secrecy agreement respectively with Lurgi company and ABB company in Europe, and to providing a catalyst sample developed by RITE to implement an examination by the other party and to show related technical information. In addition, it concluded a cooperation agreement about a total system of the chemical CO2 fixation and utilization technology and methanol synthesis with ZSW. In Australia, negotiation about international cooperation with CSIRO which is a federal research organization and CRC (Cooperative Research Centre) for renewable energy has been started. The ideal circumstances are being ready for the chemical CO2 fixation project for which the international cooperation with the country where the natural energy is rich like Australia is essential when coming to practical use. To do alternating current with further high density in the following year it is desired to build a concrete study cooperation system. 1 fig., 4 tabs.

  9. Research cooperation project for fiscal 1999. Research cooperation on environment-compatible type water resource effective utilization system; 1999 nendo kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Efforts are made under this project to develop a wastewater treatment/regeneration system, easy to operate and maintain and low in cost, jointly with a Philippine research institute. Technologies are transferred to this institute concerning research and development, system designing, operation, maintenance, and management. The goal is to disseminate such technologies in the Philippines. As for fiscal 1999 endeavors, emphases are placed on the items described below. The Container Corporation which regenerates waste paper and the RAM Food Corporation which manufactures canned foods and pickles are selected as the sites for pilot plant research. Wastewater discharged by the two corporations is subjected to laboratory-scale wastewater treatment (combination of aerobic/anaerobic treatment and activated carbon adsorption), by which a pilot plant wastewater treatment process is determined and designing conditions are defined. As for activated carbon for advanced wastewater treatment, a fine grain sample, which is the lowest in price among activated coconut shell charcoals produced in the Philippines, is acquired, and tested for performance. A wastewater treatment pilot plant is complete at the Container Corporation, and has started operation. (NEDO)

  10. FY 1999 report on the feasibility study on dissemination of the technologies for effective utilization of blast furnace top pressure in China; 1999 nendo Chugoku ni okeru koro rochoatsu yuko riyo gijutsu no fukyu kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the FY 1999 results of the feasibility study on the blast furnace top pressure recovery turbine (TRT) technology in China. Government of China is promoting the steel industry policies to weed out outdated, inefficient production systems while preparing the priority guidance list to promote introduction of advanced technologies, for which the government is implementing or planning the preferential measures, including exemption from the import taxes and VAT, and subsidization of interest on investment. This feasibility study predicts the commercial based investment in the case where the dry dust collector and TRT that are the principal components of a dry type TRT system are manufactured in China and its acquisition ratio is increased on the condition that a suitable number of the systems are installed and on the premise that a dissemination model project is implemented. The results indicate that the system can be introduced at a cost a little less than 60% of the predicted investment in the dissemination model project. The cost-effect ratio varies with power price, which widely varies by region in China, and the dissemination feasibility is studied over a wide range of power price. The system has high dissemination potential, because almost all of the Chinese steel makers will have a sufficient cost-effect ratio which satisfies their investment standards, if they are granted the preferential measures from the government. (NEDO)

  11. Study on the best utilization of solar energy. Experimental study of hydrogen generation by water electrolysis using solar battery; Taiyo energy no yuko riyo ni kansuru kenkyu. Taiyo denchi riyosui denki bunkai suiso hassei field test

    Energy Technology Data Exchange (ETDEWEB)

    Kawashima, Y; Murai, K; Nakai, T [Himeji Institute of Technology, Hyogo (Japan)

    1997-11-25

    Shortcomings of solar energy are that it is subject to weather and is not available in the nighttime. The weak points may be effectively made up for when solar energy collected on a fine day is stored in the form of hydrogen energy for recovery as required. In this report, power generated by solar cells is used for the electrolysis of water for the generation of hydrogen. The amounts of the thus-generated hydrogen and hydrogen energy are determined and, on the basis of the measured amount of insolation, the solar energy availability rate (hydrogen conversion performance) is calculated. The amount of hydrogen generated in fiscal 1996 is also calculated for every month. The hydrogen generation level is quite low in the TiO2 wet type solar cell, approximately 0.2% at most. The current efficiency is fairly high in hydrogen generation using electrolysis, which is approximately 96-97%. The efficiency is higher when several units of electrolyte are connected in series until the solar cell optimum voltage is attained. A linear relationship is found between the daily summation of insolation and the amount of hydrogen generated. 1 ref., 7 figs., 2 tabs.

  12. Fiscal 1999 technical survey report. Model project implementation feasibility study in India on effective utilization of blast furnace gas pressure energy; 1999 nendo Indo ni okeru koro gas atsuryoku energy yuko riyo model jigyo jisshi kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    From the viewpoint of energy utilization stated above, blast furnace top pressure recovery turbine (TRT) unit installability was studied at Bhilai Steel Works of Steel Authority of India, Ltd., Bokaro Steel Works of Steel Authority of India, Ltd., and Visakhapatnum Steel Works of Rashtriya Ispat Nigem. The energy consumption rate at an Indian steelmaking plant is 8Gcal/t-steel, which is larger than 5-6Gcal/t-steel of Japan and therefore needs improvement. Out of the blast furnaces in India, 26 are larger than 1,000m{sup 3}, and two of them are provided with a TRT device of now-defunct Soviet Union manufacture. The blast furnaces were examined for pressure at the top, amount of gas at the top, amount of dust, and safeness in operation. The No. 2 blast furnace of the Borkaro plant was selected for the project, and studies were made for a wet type TRT device. Improvements to be achieved by TRT device installation were calculated to be a TRT output of 5,900kW, power output of 49,100MWh/year, saved crude oil amount of 12,990toe/year, and CO2 reduction of 40,200 tons-CO2/year. (NEDO)

  13. Study on electrical monitoring of fill-up improvement. Utilization of resistivity data for soil compaction management; Hiteiko mitsudo kanri ni kansuru kisoteki kenkyu. Moritsuchi seko kanri eno hiteiko yuko riyo

    Energy Technology Data Exchange (ETDEWEB)

    Ueno, N; Hiramatsu, W [Dai Nippon Construction, Gifu (Japan); Sugano, T [Kyoto University, Kyoto (Japan). Faculty of Engineering

    1996-10-01

    At present, measurement of wet density and water content by radio isotope (RI method) is used for filling management. It is supposed for filling in road construction that putting-out thickness of banking material reaches nearly 1m in the future rapid construction, however, use of RI method is difficult because of inserting and installing of a radiation source rod, large measuring apparatus, and the legal regulation on radioactivity intensity. Application of resistivity measurement was thus considered. Since resistivity has the same parameter as compaction curve, and monotonously decreases with an increase in water content by volume, it is applicable as construction management index. The management reference of resistivity (Rm) is set by plotting of a compaction curve and corresponding resistivity curve, determination of the reference resistivity (Ro) corresponding to a maximum dry density and optimum water content ratio, and setting of the allowance to Ro according to soil or application. It was clarified that Rm is applicable as set for every filling material. 1 ref., 10 figs., 2 tabs.

  14. Report for fiscal 1998. Joint research of environment-friendly system for effectively utilizing water resources; 1998 nendo hokokusho. Kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The research is conducted in cooperation with Industrial Technology Development Institute of the Philippines, and aims to solve water related problems such as unstable water supply and water quality pollution though developing a waste water treatment and recycling system which is easy to operate and maintain, low in cost, and usable in the Philippines. Fiscal 1998 is the second year of the project. Statistics are studied about the load that each industrial branch imposes on water for its pollution, and it is found that food manufacturers, paper pulp mills, and fiber dyeing plants are heavily responsible for water pollution. A method consisting of single-tower UASB anaerobic treatment and activated sludge treatment is applied as a water treatment process to Ram Food Products Corporation, and its optimization is studied. A removal rate 60% is achieved after a 12-hour treatment period at a COD (chemical oxygen demand) rate of 8g/liter/day. A method consisting of coagulating sedimentation and activated sludge treatment is applied to the waste water from a Solid Mill Corporation dyeing plant, when it is found that the water after ultimate treatment is almost colorless and that COD is 76mg/liter and BOD (biological oxygen demand) 13mg/liter, and these suggest that the waste water is recyclable. Since it is low in COD removing rate, the application of anaerobic treatment to high-concentration water after washing is not appropriate. (NEDO)

  15. Research cooperation report for fiscal 1997 on the environment-friendly system for effectively utilizing water resources; 1997 nendo kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku itaku gyomu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This effort exerted in cooperation with the Philippines aims to solve problems related to water resources such as stable supply and pollution of water through developing a waste water treatment/water reuse system which is easy to operate and maintain, and low in price. The ultimate goal includes (1) the construction of a waste water treatment/water reuse system comprising an anaerobic reaction tank and activated charcoal absorption tower, easy to operate and maintain, and low in price, (2) the employment of goods procurable in the Philippines, the goods including carriers for use in the anaerobic reaction tank, microbes for use in both aerobic and anaerobic reaction tanks, and activated charcoal for use in waste water reutilization, and (3) the establishment of optimum operating conditions for the waste water treatment/water reuse system by use of a pilot plant and the transfer of operating and managing techniques to the Filipino counterpart. In this fiscal year, investigations are conducted to disclose the actualities of waste water treatment and water consumption by primary industries in the vicinity of Laguna de Bay, and the waste water to be the object of study and the place of pilot plant installation have been selected. Also conducted are investigations into the carrier, microbe, activated charcoal, etc., for use in the anaerobic reaction tank. (NEDO)

  16. Fiscal 1999 technical survey report. Model project implementation feasibility study in China on effective utilization of cement waste heat; 1999 nendo Chugoku ni okeru cement hainetsu yuko riyo model jigyo jisshi kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Although China ranks first in the world in the manufacture of cement, yet the energy consumption rate is high and there remains room for improvement. Effective utilization of energy at cement making plants will not only profit the industry but also contribute to the stabilization of energy supply for China. The model project on power generation using cement waste heat implemented at Ningguo Cement Plant was concluded successfully. For the purpose of enabling China to domestically manufacture the equipment, the installation of such equipment at Zhujiang Cement Plant and Liuzhou Cement Plant in Guangxi Zhuangzu Zizhiqu was assumed, and their locations and plant operating conditions were studied. In addition, surveys were conducted of manufacturers of important components of the power generation equipment such as boilers, steam turbines, generators, and breaker boards. Two manufacturers were visited for each of the components, and they were checked for records of manufacturing similar equipment, quality assurance and process management capabilities, and for ability to satisfy required specifications. Among the visited manufacturers were Nanjing Turbine and Electric Machinery Co., Jinan Power Equipment Factory, and Hangzhou Boiler Works. Based on the results of the surveys, it was concluded that the model project may be implemented. (NEDO)

  17. Survey report for fiscal 1999 on internationalization of technologies for effective use of energy resources. Survey by exploration of international cooperative researches on energy-saving through advanced use of steel slag; 1999 nendo energy shigen yuko riyo gijutsu kenkyu kokusaika chosa hokokusho. Tekko slag no kodo riyo ni yoru sho energy gijutsu ni kansuru kokusai kyodo kenkyu no tansaku chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    As for the collection of sensible heat, 1/3 of blast-furnace slag is treated to the purpose at the Teesside Technology Centre, Britain, but none is collected in the latter half of tapping in case there is so much slag that cooling cannot be done in time. In the case of a large blast furnace, some measures have to be contrived because molten iron comes out of the furnace intermittently. In Germany, the heat collection rate is as low as 3%, with no effort made at heat collection. In North America, desire to develop such a technology is not strong. A visit was made to the Institute of Ocean Sciences, Canada, in relation to the concept of using steel slag as a eutrophic source for marine photo-plankton. A large-scale long-term test is under way for examining the relationship between global warming and ocean current circulation. There are possibilities that Japan will enter into the project for a joint study, for example, of heavy metal elution from slag though the test fails to name slag as the direct object of study. Not only for Canada but also for any other country who faces the sea, it may be a meaningful national policy to inject some active ingredients into the sea for an increase in living marine resources. Greece is engaged in the ocean dumping of nickel slag on an experimental basis but, in view of the purpose of the experiment, Japan will not be a participant in the project. (NEDO)

  18. System approach on solar hydrogen generation and the gas utilization; Taiyo energy ni yoru suiso no seisei oyobi sono riyo system ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, I; Hirooka, N; Deguchi, Y; Narita, D [Meiji University, Tokyo (Japan)

    1997-11-25

    An apparatus is developed to establish a system which allows utilization of hydrogen safely and easily, and its applicability to a hydrogen system for domestic purposes is tested. The system converts solar energy by the photovoltaic cell unit into power, which is used to generate hydrogen by electrolysis of water at the hydrogen generator, stores hydrogen in a metal hydride , and sends stored hydrogen to the burner and fuel cell units. It is found that a hydrogen occluding alloy of LaNi4.8Al0.2 stores hydrogen to approximately 80% when cooled to 20 to 25degC, and releases it to 10% when heated to 40degC. The fuel cell uses a solid polymer as the electrolyte. The hydrogen gas burner is a catalytic combustion burner with a Pt catalyst carried by expanded Ni-Al alloy. The optimum distance between the burner and object to be heated is 22mm. High safety and fabrication simplicity are confirmed for use for domestic purposes. The system characteristics will be further investigated. 4 refs., 8 figs.

  19. Effective utilization technology of carbon dioxide. CO sub 2 no yuko riyo gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Ibusuki, T. (National Research Inst. for pollution and Resources, Tsukuba (Japan))

    1991-03-12

    As carbon dioxide-related environmental measures, method was explained to chemically convert and utilize carbon dioxide. Synthesis is possible of methanol, carbon monoxide, different carbohydrates, etc. by catalytic hydrogenation of carbon dioxide, using hydrogen produced by the electrolysis of water. Task consists of heightening in both convertibility and selectivity, and abundant supply of low cost hydrogen. Methane, alcohol, etc. can be synthesized by electrochemical reducion of carbon dioxide. Because of effectively inserting multiple electron, discssion is being made of catalyst, intergrated with electrode, and electron transmitter. The photoelectrochemical reduction of carbon dioxide can be also made by utilizing photoelectric current, generated upon photoradiation on the semiconductive electrode. However, task consists of heightening in both efficiency and selectivity. Photochemical reduction of carbon dioxide, actually made by green plant, consists of oxidationlike decomposition of water and reduction of carbon dioxide. Both those reactions are skillfully separated by intermediation of very quick electron transmission system. Reduction is being studied with semiconductor, metallic colloid, enzyme, metallic complex and other various catalysts. 10 refs., 3 figs., 4 tabs.

  20. Research and development of technologies for CO{sub 2} fixation and effective utilization thereof, etc., in fiscal 1998. Report on research and development of technologies for the effective use of CO{sub 2} by virtue of contact hydrogenation (CO{sub 2} separation and recovery system of the next-generation type); 1998 nendo nisanka tanso koteika yuko riyo gijutsu nado kenkyu kaihatsu jigyo. Sesshoku suisoka hanno riyo nisanka tanso yuko riyo gijutsu kenkyu kaihatsu jigyo kenkyu kaihatsu jigyo (jisedaigata shoene CO{sub 2} bunri kaishu system ni kansuru chosa kenkyu hokokusho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Researches were conducted for the goal of proposing a totally new process enhanced in efficiency and energy saving, and capable of CO2 separation. In fiscal 1997, hydrocarbon materials were reformed by oxygen separated within a system allowing fuel cells to generate power efficiently, when all the emitted CO2 was separated and recovered within the system. Furthermore, cold heat was utilized for the acquisition of liquefied CO2 gas products. A part of oxygen separated at the fuel cell cathode was recycled into the combustion section external to the tubular reaction reformer, and CO2 was separated by mere cooling from the combustion products for the simultaneous production of by-products such as high-purity nitrogen gas and liquefied CO2 for a great improvement in economy. In fiscal 1998, the system was improved. Proposed then was a new system in which an oxygen partial oxidation type reformer assumed the nuclear role, separating all the oxygen at the cathode, reusing part thereof for oxygen enrichment, and feeding the rest thereof into the reformer. The design realized the recycling of the whole of the products of the two cell electrodes into the reformer for the maximum reuse of the products of the hydrogen/oxygen separation function. (NEDO)

  1. Survey report for fiscal 1998. Survey of the current state and tasks of research and development of technologies for effectively utilizing CO{sub 2} fixation by higher vegetation; 1998 nendo chosa hokokusho. Koto shokubutsu ni okeru nisanka tanso koteika yuko riyo gijutsu no kenkyu kaihatsu no genjo to kadai ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Investigations and studies are conducted seeking for a CO2 fixation method improved by utilizing the photosynthesizing function of higher vegetation. Details of higher vegetation genes are being disclosed thanks to the rapid progress of studies making use of molecular biological techniques, and the application of the genetic mechanism to scientific and technological fields is becoming increasingly feasible. In particular, the role of the CO2 fixation enzyme RuBisCO has been elucidated almost completely. It has been learned that, in terms of photosynthesizing capability, the C{sub 4} plants (corn etc.) are 2-3 times higher than the C{sub 3} plants (rice, wheat, etc.), and 5-10 times higher than the CAM plants (cactuses etc.). Studies are also under way about the rice genome so that a photosynthesizing capability so high as that of the C{sub 4} plants may be endowed the rice plant. The metabolism and control of useful substances produced in the CO2 fixation process etc. in the higher vegetation are being investigated, and it is now expected that some day such useful substances will be produced and utilized efficiently. Researches are under way into the relationship between the green leaf that is the organ that performs photosynthesis and the organ (sink) that stores and utilizes starch and sugar is in progress, and now a new field is going to open where vegetables will be fully utilized. (NEDO)

  2. Report on investigations in fiscal 2000. International infrastructure improving project for rationalization of energy use (Fundamental survey on effective utilization of unutilized biomass energy in ASEAN countries); 2000 nendo kokusai energy shiyo gorika kiban seibi jigyo chosa hokokusho. ASEAN shokoku ni okeru miriyo baiomasu energy no yuko riyo ni kansuru kisochosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With an objective to utilize 'biomass' being the unutilized and reproducible energy source, which exists affluently in the ASEAN countries, investigations and discussions have been carried out on electric power generation using palm shells as fuel in Malaysia. This paper reports the achievement in fiscal 2000. The biomass energy plant project was discussed with the followings as the conditions: an output of 1 MW, use of biomass in the form of wastes discharged from oil palm mills, the system of direct combustion process with boiler/steam turbine generation process, and power transmission to public grids. As a result of the discussions, the following conclusions were obtained: reduction of greenhouse effect gas exhaust will amount to 81,540 t-CO2/year, reduction will be realized on white smoke pollution caused by wastes incineration being criticized from various sectors and such harmful gas exhaust as SOx and NOx discharged from fossil fuel power generation, the uncertainty of electric power supply currently depending on DG power generation will be mitigated resulting in acquisition of economic effects, and electric power supply to 1,000 households will be possible, contributing to enhancement of living standard due to electrification. (NEDO)

  3. FY 1999 investigational survey on the project on the potential survey of the effective energy utilization model project in the Asian region; 1999 nendo Asia chiiki ni okeru kokateki energy yuko riyo model jigyo no jisshi kanosei ni kansuru chosa jigyo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    A survey was made on the technology applicable to the energy effective utilization model project in the Asian region. In the survey, the technology was listed up which could be the base for the model project in which the use in the commercial/residential field and the use of natural energy were considered. Further, countries for survey were limited to developing countries in the Asian region. Technologies for survey were as follows: various cogeneration systems, fuel cell cogeneration systems, heat storage type heat utilization, heat storage type air conditioning using night power, night power use dynamic ice maker and heat storage tank utilization, low temperature exhaust heat use adsorption type refrigeration, low temperature waste heat recovery absorption type heat pump, low head hydroelectric power generation, energy conservation in buildings, rationalization of energy utilization by energy management, heat supply using solar energy/wind power energy, biomass energy utilization, high efficiency/multiple effect heat utilization, high performance membrane separator utilization, high temperature/high humidity drying, airless dryer, etc. (NEDO)

  4. Catalytic technology in the energy/environment field. Utilization of catalyst in coal pyrolysis and gasification processes; Energy kankyo bun`ya ni okeru shokubai gijutsu. Sekitan no netsubunkai oyobi gas ka ni okeru shokubai no riyo

    Energy Technology Data Exchange (ETDEWEB)

    Otsuka, Y. [Tohoku University, Institute for Chemical Reaction Science (Japan)

    1998-05-20

    This review article focuses on the utilization of several catalysts during coal pyrolysis and gasification. In situ or off line catalytic upgrading of volatile matters during pyrolysis of low rank coals is carried out in pressurized H2 with different reactors to produce BTX (benzene, toluene and xylene). When NiSO4 and Ni(OH)2 are used in the hydropyrolysis of Australian brown coal using an entrained bed reactor with two separated reaction zones, BTX yield reaches 18-23%. MS-13X zeolite and USY zeolite mixed with Al2O3 are effective for producing BTX with powder-particle fluidized bed and two-stage reactors, respectively. Catalytic gasification is described from a standpoint of direct production of SNG(CH4) from coal and steam. When K2CO3 and Ni are compared for this purpose, Ni catalyst is more suitable at low temperatures of 500-600degC, where CH4 formation is thermodynamically favorable. Fe and Ca catalysts can successfully be prepared from inexpensive raw materials and are rather active for steam gasification at {>=}700degC. The use of upgrading and gasification catalysts is discussed in terms of preparation, performance, life and recovery. 27 refs., 6 figs., 2 tabs.

  5. Achievement report in fiscal 1999 on commissioned research project. 'Model project for facilities to effectively utilize wastes from industrial complexes in Thailand' Project for 1999 Volume 3; 1999 nendo seika hokokusho. Tai ni okeru kogyo danchi sangyo haikibutsu yuko riyo setsubi moderu jigyo - 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With an objective to reuse industrial wastes and effectively utilize them as a petroleum replacing energy resource, and attempt to reduce consumption of fossil fuel in Thailand where increase in discharge of industrial wastes is estimated, a model project for facilities to effectively utilize wastes from industrial complexes has been carried out. This paper reports the achievements in fiscal 1999. Specifically, the project calls for incineration in fluidized bed incinerators of industrial wastes discharged from factories in industrial complexes possessed by the Industrial Estate Authority of Thailand (IEAT), recovery of waste heat from waste heat recovering boilers to generate process steam, which is supplied to the factories in the complexes. The current fiscal year, which is the first current year of the project, has put into order the operations shared by Japan and Thailand, compiled the various procedures and schedules into the form of appendices to the agreement, and executed signing of the agreement. Thereafter, the Japanese side has carried out decision on the specifications of the facilities, the basic designs, the detailed designs of facilities to be arranged by Japan, and the fabrication of some of the devices according to the descriptions of the agreement appendices. The volume 3 summarizes the inspection reports other than those included in the Volume 2. (NEDO)

  6. FY 2000 Study report. Feasibility study on model project for effective utilization of sensible heat of off gas from hot stoves at blast furnaces in India; 2000 nendo Indo ni okeru koro netsufuro hai gas kennetsu yuko riyo model jigyo jisshi kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The feasibility study was conducted on a model project in India for the energy saving effect and reduction of the greenhouse gas emissions by introducing blast furnace hot stove waste heat recovery systems in steelworks. The blast furnaces studied are Blast Furnace G at Jamshedpur Steelworks of TISCO, the largest private steel maker in India, and No.7 Blast Furnace at Bhilai Steelworks of state-operated Steel Authority of India Ltd. (SAIL). The study results indicate that the annual energy-saving effects of 8,255 and 8,190 tons as heavy oil, and annual CO2 emission reduction of 25,543 and 25,342 tons are expected in the TISCO and SAIL blast furnaces, respectively, in the case of increasing blast temperature and reducing blast furnace fuel coke (increased iron production possible). The model project is applicable to both blast furnaces. There are a total of 46 blast furnaces in India in which the heat recovery systems can be introduced. The nation-wide annual energy saving and CO2 abatement would reach 126,202 tons as heavy oil and 390,501 tons, when all of these blast furnaces could be provided with the heat recovery systems. (NEDO)

  7. FY 2000 report on the survey of policies on cooperation in new energy/energy conservation for developing countries by developed countries/international organizations. Survey of collection/analysis of information on effective energy utilization, etc.; 2000 nendo senshinkoku kokusai kikan no tai tojokoku shin energy sho energy kyoryoku seisaku ni kakawaru chosa hokokusho. Energy yuko riyo nado joho shushu bunseki chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Looking for measures for cooperation in effective energy conservation for developing countries, the paper arranged characteristics of the policies, systems and organizations in relation to energy conservation/new energy policies in developed countries and international organizations excluding Japan. Concretely, survey was made of the following 5 fields: 1) new energy cooperation (project) for developing countries by developed countries and international organizations excluding Japan; 2) outline of activities by aid giving organizations; 3) energy conservation policies of developing countries and cooperation of developed countries and international organizations; 4) policies of new energy introduction in developed countries; 5) study to reinforce cooperation for helping developing countries by Japan and developed countries/international organizations excluding Japan. In 1), survey is composed of case study of the main project and study of the outline of activities by aid giving organizations. The activities by the following aid giving organizations were surveyed: the World Bank group, International Finance Corporation (IFC), United Nations Development Program (UNDP), the European Committee and the Asian Development Bank (ADB). (NEDO)

  8. FY 2000 report on the basic survey to promote Joint Implementation, etc. Survey of the effective use of wastes at palm oil refineries; 2000 nendo kyodo jisshi nado suishin kiso chosa hokokusho. Palm oil seisei kojo ni okeru haikibutsu yuko riyo chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    As to empty fruit bunches (EFB) which are wasted at the Lahad Datu plant of Felda Vegetable Oil Products Co. in Malaysia, a project was studied for energy substitution and greenhouse effect gas reduction by fluidized bed cogeneration facilities using this as fuel. In the project, studied was the introduction of on-site cogenerator of 7,800kW in generating-end output, and that of IPP cogenerator of 16,000kW as reference. As a result of the study, the energy substitution amount in toe in 20 years was approximately 376 k tons in case of on-site power generation/fluidized bed boiler and approximately 695 k tons in case of IPP and fluidized bed boiler. The amount of greenhouse effect gas emission in toe in 20 years was approximately 5,757 k tons and 11,654 k tons, respectively. Concerning the profitability, the internal earning rate was 3.32-8.47% in case of on-site power generation/fluidized bed boiler and 9.13-14.65% in case of IPP/fluidized bed boiler. It indicated the materialization of the project. (NEDO)

  9. FY 1999 report on the results of the contract project 'The model project for facilities for effective utilization of industrial waste at the industrial complex in Thailand.' Separate Volume 4 - FY 1999 project; 1999 nendo seika hokokusho. Tai ni okeru kogyo danchi sangyo haikibutsu yuko riyo setsubi moderu jigyo - 4

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of reducing the consumption of fossil fuel by recycling industrial waste for effective use as petroleum substituting energy in Thailand where the amount of industrial waste is expected to increase, a model project on facilities for effective use of industrial waste at the industrial complex was carried out, and the FY 1999 results were reported. Concretely, the industrial waste generated from each plant at the industrial complex owned by IEAT is to be incinerated in fluidized bed incinerator, and the process steam is to be generated by recovering waste heat by waste heat recovery boiler and to be supplied to plants within the complex. In this fiscal year, the first year of the project, the attachment to the agreement was prepared in terms of the allotment of the project work between Japan and Thailand, various kinds of gist, schedules, etc. and signed. After that, the following were conducted at the Japan side according to the attachment to the agreement: determination of the basic specifications for facilities, basic design, detailed design, manufacture of a part of the equipment, etc. Separate Volume 4 included the results of the inspection of the tank, pump, blower, etc. (NEDO)

  10. Achievement report in fiscal 1999 on commissioned research project. 'Model project for facilities to effectively utilize wastes from industrial complexes in Thailand' Project for 1999 Volume 1; 1999 nendo seika hokokusho. Tai ni okeru kogyo danchi sangyo haikibutsu yuko riyo setsubi moderu jigyo - 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With an objective to reuse industrial wastes and effectively utilize them as a petroleum replacing energy resource, and attempt to reduce consumption of fossil fuel in Thailand where increase in discharge of industrial wastes is estimated, a model project for facilities to effectively utilize wastes from industrial complexes has been carried out. This paper reports the achievements in fiscal 1999. Specifically, the project calls for incineration in fluidized bed incinerators of industrial wastes discharged from factories in industrial complexes possessed by the Industrial Estate Authority of Thailand (IEAT), recovery of waste heat from waste heat recovering boilers to generate process steam, which is supplied to the factories in the complexes. The current fiscal year, which is the first current year of the project, has put into order the operations shared by Japan and Thailand, compiled the various procedures and schedules into the form of appendices to the agreement, and executed signing of the agreement. Thereafter, the Japanese side has carried out decision on the specifications of the facilities, the basic designs, the detailed designs of facilities to be arranged by Japan, and the fabrication of some of the devices according to the descriptions of the agreement appendices. The volume 1 summarizes the agreement appendices, and the specifications of the main devices. (NEDO)

  11. FY 1999 report on the results of the contract project 'The model project for facilities for effective utilization of industrial waste at the industrial complex in Thailand.' Separate Volume 5 - FY 1999 project; 1999 nendo seika hokokusho. Tai ni okeru kogyo danchi sangyo haikibutsu yuko riyo setsubi moderu jigyo - 5

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of reducing the consumption of fossil fuel by recycling industrial waste for effective use as petroleum substituting energy in Thailand where the amount of industrial waste is expected to increase, a model project on facilities for effective use of industrial waste at the industrial complex was carried out, and the FY 1999 results were reported. Concretely, the industrial waste generated from each plant at the industrial complex owned by IEAT is to be incinerated in fluidized bed incinerator, and the process steam is to be generated by recovering waste heat by waste heat recovery boiler and to be supplied to plants within the complex. In this fiscal year, the first year of the project, the attachment to the agreement was prepared in terms of the allotment of the project work between Japan and Thailand, various kinds of gist, schedules, etc. and signed. After that, the following were conducted at the Japan side according to the attachment to the agreement: determination of the basic specifications for facilities, basic design, detailed design, manufacture of a part of the equipment, etc. Separate Volume 5 included the drawing of the basic design, drawing of building/design, drawing of manufacturing equipment, etc. (NEDO)

  12. FY 2000 report on the survey of new energy policies by developing countries. Survey of collection/analysis of information on effective energy utilization, etc.; 2000 nendo tojokoku no shin energy seisaku ni kakawaru chosa hokokusho. Energy yuko riyo nado joho shushu bunseki chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of effectively introducing technologies for new energy/energy conservation in developing countries, the paper arranged the policies, systems and organizations in relation to new energy in developing countries. Survey was made of the following two fields: 1) new energy in developing countries; 2) situation of new energy introduction in developing countries (India, Indonesia, Thailand, Malaysia, the Philippines and China). In 2), about India, for example, survey was made on the following: outline of the new energy policy, regulation for new energy promotion and law specifying concrete measures, departments in charge/promotion organizations for new energy, system and setup for new energy promotion, numerical target of new energy introduction, support from developed countries including the E.U. and the U.S. and the effects, support from international organizations including the World Bank and UNDP and the effects, the country's main industries related to new energy, the government's policy for the domestic production, outline of the use of India's biomass project, etc. (NEDO)

  13. FY 1999 survey report on the survey on the role and course of the development of technology such as CO2 recovery, fixation and effective use in the industrial policy; 1999 nendo CO{sub 2} kaishu koteika yuko riyo nado gijutsu kaihatsu no sangyo seisakujo no ichizuke oyobi hokosei ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This paper aims at arranging and assessing the role of themes of the technology development such as CO2 recovery, fixation and effective use in the industrial policy and the results of the development. It also aims at analyzing factors to hinder technology development in comparison with the developmental trend of technology and the role in the industrial policy in foreign countries and at considering the future role in the industrial policy and the course to be taken. Judging from the number of projects and a variety of fields of technology, it could be said that the development of the related technology in Japan is at a top level the same as that in the U.S. In the present conditions, however, most of the technologies are at the stage of the basic research. In many of the research fields except a part like EOR, it is difficult to promote the research only by economical principles, and the government as core needs to promote it. As viewed from an international point, the development/commercialization of technology such as CO2 recovery, fixation and effective use are extremely important from an aspect of not only the heightening of competitiveness in the domestic industry, but Japan's international contribution in the 21st century. (NEDO)

  14. FY 1999 report on the plan to implement the model project for effective utilization of blast furnace gas pressure energy and the potential survey of the spread in India; 1999 nendo Indo ni okeru koro gas atsuryoku energy yuko riyo model jigyo jisshi keikaku oyobi fukyu kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    As to the implementation of 'the model project for effective utilization of blast furnace gas pressure energy' and the possibility of spreading the said technology, survey/study were conducted, and the results were reported. The enterprise implementing the model project, Steel Authority of India Limited (SAIL), has been investing a total of 300 billion yen in modernizing facility/equipment after the liberalization in 1992, which is a cause of a large amount of deficit. About SAIL' cash flow, it is expected that SAIL will go into the black after tax in and after 2002. Local financial institutions are careful in investing in the iron/steel industry, but they have no problems in their own financing ability. In the evaluation of economical efficiency on the commercial basis, it is difficult to implement this model if using power prices, customs duties and borrowing rates in India as conditions. However, when preferential measures such as the exemption from taxation and help to borrowing rates are taken for energy conservation facility/equipment and the cost reduction is realized by technical cooperation, etc., it will be possible to recover the investment in 5 years. As to the possibility of spreading this model, the blast furnace with a capacity of 1000{sup 3} or more is targeted, and the number of the targeted blast furnace is 23. (NEDO)

  15. Research report for fiscal 1998. Research of feasibility of energy supply/demand structure overseas improvement (research of feasibility of more effective energy use for Russian energy consuming industries); 1998 nendo kaigai energy jukyu kozo kodoka jisshi kanosei chosa. Roshia no energy tashohi sangyo ni okeru energy yuko riyo nado jigyo jisshi kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A report is made outlining the economic situation and industrial policies in Russia and the actual state of energy consuming industries (thermoelectric power generation, oil refining, and iron making) in that country. In Russia, energy efficiency is much lower than in advanced countries in the West, and the improvement of energy efficiency is a serious task to solve in the Russian fuel energy department. Cited to explain the poor efficiency are facilities growing antiquated, delay in the introduction of new technologies and instruments, insufficient maintenance, and the weak consciousness of energy saving. Although the electric power circle and energy related departments are conscious of the need of endeavors for improving energy efficiency, yet it is too difficult for corporations themselves to invest heavily in facilities. When Japan implements a model project for saving energy in Russia, it will be greatly contributing to the improvement of energy supply/demand in Russia, to the stabilization of social and economic states in that country, and to the prevention of global warming. (NEDO)

  16. FY 1999 report on the results of the contract project 'The model project for facilities for effective utilization of industrial waste at the industrial complex in Thailand.' Separate Volume 4 - FY 1999 project; 1999 nendo seika hokokusho. Tai ni okeru kogyo danchi sangyo haikibutsu yuko riyo setsubi moderu jigyo - 4

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of reducing the consumption of fossil fuel by recycling industrial waste for effective use as petroleum substituting energy in Thailand where the amount of industrial waste is expected to increase, a model project on facilities for effective use of industrial waste at the industrial complex was carried out, and the FY 1999 results were reported. Concretely, the industrial waste generated from each plant at the industrial complex owned by IEAT is to be incinerated in fluidized bed incinerator, and the process steam is to be generated by recovering waste heat by waste heat recovery boiler and to be supplied to plants within the complex. In this fiscal year, the first year of the project, the attachment to the agreement was prepared in terms of the allotment of the project work between Japan and Thailand, various kinds of gist, schedules, etc. and signed. After that, the following were conducted at the Japan side according to the attachment to the agreement: determination of the basic specifications for facilities, basic design, detailed design, manufacture of a part of the equipment, etc. Separate Volume 4 included the results of the inspection of the tank, pump, blower, etc. (NEDO)

  17. Achievement report in fiscal 1999 on commissioned research project. 'Model project for facilities to effectively utilize wastes from industrial complexes in Thailand' Project for 1999 Volume 2; 1999 nendo seika hokokusho. Tai ni okeru kogyo danchi sangyo haikibutsu yuko riyo setsubi moderu jigyo - 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With an objective to reuse industrial wastes and effectively utilize them as a petroleum replacing energy resource, and attempt to reduce consumption of fossil fuel in Thailand where increase in discharge of industrial wastes is estimated, a model project for facilities to effectively utilize wastes from industrial complexes has been carried out. This paper reports the achievements in fiscal 1999. Specifically, the project calls for incineration in fluidized bed incinerators of industrial wastes discharged from factories in industrial complexes possessed by the Industrial Estate Authority of Thailand (IEAT), recovery of waste heat from waste heat recovering boilers to generate process steam, which is supplied to the factories in the complexes. The current fiscal year, which is the first current year of the project, has put into order the operations shared by Japan and Thailand, compiled the various procedures and schedules into the form of appendices to the agreement, and executed signing of the agreement. Thereafter, the Japanese side has carried out decision on the specifications of the facilities, the basic designs, the detailed designs of facilities to be arranged by Japan, and the fabrication of some of the devices according to the descriptions of the agreement appendices. The volume 2 summarizes the inspection reports in the referential materials. (NEDO)

  18. FY 1999 report on the results of the contract project 'The model project for facilities for effective utilization of industrial waste at the industrial complex in Thailand.' Separate Volume 6 - FY 1999 project; 1999 nendo seika hokokusho. Tai ni okeru kogyo danchi sangyo haikibutsu yuko riyo setsubi moderu jigyo - 6

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of reducing the consumption of fossil fuel by recycling industrial waste for effective use as petroleum substituting energy in Thailand where the amount of industrial waste is expected to increase, a model project on facilities for effective use of industrial waste at the industrial complex was carried out, and the FY 1999 results were reported. Concretely, the industrial waste generated from each plant at the industrial complex owned by IEAT is to be incinerated in fluidized bed incinerator, and the process steam is to be generated by recovering waste heat by waste heat recovery boiler and to be supplied to plants within the complex. In this fiscal year, the first year of the project, the attachment to the agreement was prepared in terms of the allotment of the project work between Japan and Thailand, various kinds of gist, schedules, etc. and signed. After that, the following were conducted at the Japan side according to the attachment to the agreement: determination of the basic specifications for facilities, basic design, detailed design, manufacture of a part of the equipment, etc. Separate Volume 6 included drawings of assembling of the equipment such as crane, crusher and valve. (NEDO)

  19. FY 1999 report on the results of the contract project 'The model project for facilities for effective utilization of industrial waste at the industrial complex in Thailand.' Separate Volume 6 - FY 1999 project; 1999 nendo seika hokokusho. Tai ni okeru kogyo danchi sangyo haikibutsu yuko riyo setsubi moderu jigyo - 6

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of reducing the consumption of fossil fuel by recycling industrial waste for effective use as petroleum substituting energy in Thailand where the amount of industrial waste is expected to increase, a model project on facilities for effective use of industrial waste at the industrial complex was carried out, and the FY 1999 results were reported. Concretely, the industrial waste generated from each plant at the industrial complex owned by IEAT is to be incinerated in fluidized bed incinerator, and the process steam is to be generated by recovering waste heat by waste heat recovery boiler and to be supplied to plants within the complex. In this fiscal year, the first year of the project, the attachment to the agreement was prepared in terms of the allotment of the project work between Japan and Thailand, various kinds of gist, schedules, etc. and signed. After that, the following were conducted at the Japan side according to the attachment to the agreement: determination of the basic specifications for facilities, basic design, detailed design, manufacture of a part of the equipment, etc. Separate Volume 6 included drawings of assembling of the equipment such as crane, crusher and valve. (NEDO)

  20. Vat leaching of gold ores and utilization of the tailings; Kinkoseki no vat leaching to koshi no yuko riyo

    Energy Technology Data Exchange (ETDEWEB)

    Hosooka, T. [Nippon Clay Mining Co. Ltd., Tokyo (Japan); Miyagawa, H. [Mitsui Mining and Smelting Co. Ltd., Tokyo (Japan)

    1996-01-25

    Mitsui Kushikino Mine previously processed two gold ores from Kushikino and Iwato ore deposits by the all slime cyanidation method, where the ores were ground to fine size smaller than 75 {mu}m and leached with sodium, cyanide. A large amount of slimes were produced as waste and discarded in tailings ponds. To save the costs of grinding and waste treatment it is desirable to process coarse sized ores. The Iwato ore is gold and silver bearing silicified porous rock. As most gold and silver in the Iwato ore are concentrated in the pores, leaching of coarse sized ore is expected to be possible. Laboratory tests and pilot plant tests of vat leaching for the Iwato ore were carried out using 0.15-8.0 mm feed. These results showed that the gold dissolution rate was similar to that by the all slime cyanidation and the decrease in gold recovery was a few %. The properties of these tailings can be used in fine aggregate of concrete. Based on the results vat leaching of the Iwato ore was adopted in the plant. The tailings are sold and used as fine aggregate. Utilization of slime tailings from the other ores was also developed and they are used as flux in copper smelters. Now, there is no tailings pond at Mitsui Kushikino Mine. 9 refs., 10 figs., 5 tabs.

  1. Practical use technology of coal ash (Poz-O-Tec); Sekitanbai no yuko riyo gijutsu (POZ-O-TEC)

    Energy Technology Data Exchange (ETDEWEB)

    Konno, K [Center for Coal Utilization, Japan, Tokyo (Japan); Saito, Y [Mitsui Mining Co. Ltd., Tokyo (Japan); Nagaya, Y [Mitsui Construction Co. Ltd., Tokyo (Japan)

    1996-09-01

    In order to utilize more effectively coal ash whose generation amount is increasing year after year, studies have been made on a technology to manufacture and utilize a high-strength substance solidified under normal temperature by utilizing hydration reaction of pozzolan system (Poz-O-Tec). The study works have been done as a subsidy operation of the Agency of Natural Resources and Energy, and were completed in fiscal 1995. Poz-O-Tec is a wet powder made of coal ash and stack gas desulfurization sludge (gypsum) added and mixed with lime and an adequate amount of water, which solidifies by hydration as pozzolan does. The same method as used for ordinary sands may be used as the basic application method. Because this is the material whose strength increases after construction, thickness of construction may be reduced smaller than in constructions using soils and sands. Test constructions of about sixty cases have been carried out to date, typically represented in use as a road bed material, banking, and a base material for water-barrier gutters. High-strength solid material which is stable under normal temperature may be obtained by adjusting calcium content. As a result of its effectiveness in practical use having been verified, a certificate of technological judgment has been issued for the material by the Civil Engineering Research Center. 3 refs., 11 figs., 2 tabs.

  2. FY 2000 report on the results of the development of the program system CO2 fixation/effective utilization technology. Development of the technology to assess global warming gas recovery/emission control by restoring/preserving the tropical mangrove coastal ecosystem; 2000 nendo program hoshiki nisanka tanso koteika yuko riyo gijutsu kaihatsu seika hokokusho. Mangrove nado nettai engan seitaikei no shufuku hozen ni yoru chikyu ondanka gas kaishu hoshutsu yokusei hyoka gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of developing the technology to assess the CO2 storage amount using the tropical mangrove coastal ecosystem, survey was conducted in the mangrove tree area in Ishigaki island, Japan and in Trat province, Thailand, and a draft of the assessment method was worked out. As to the assessment of the CO2 existence amount by analysis of satellite pictures, the regression equation between the mangrove existence amount and Landsat satellite data was determined to study a method for assessment of the CO2 storage amount in the whole area for survey. Further, using the relational equation between NDVI and LAI, vegetation indices reflecting vegetation conditions, methods to estimate the CO2 absorption amount by photosynthesis of mangrove tree community, the CO2 emission amount by respiration and the net production amount. Concerning the technology to assess the terrestrial area photosynthesis CO2 absorption amount, methods were studied for direct measurement of the amount of photosynthesis/respiration of the leaf area of mangrove tree community and the respiration amount by area such as trunk, branch and root and for assessment of CO2 absorption amount. Besides, studies were made on a variety of items such as the CO2 absorption/emission amount by underwater photosynthesis/respiration and decomposition of organic substances, the seawater exchange amount, and the rate of decomposition of organic substances. (NEDO)

  3. FY 2000 report on the basic survey to promote Joint Implementation, etc. Feasibility study of the effective utilization of by-product high-sulfur concentration petroleum coke at Fujian Petrochemical Co. Ltd., Fujian Province, China; 2000 nendo kyodo jisshi nado suishin kiso chosa hokokusho. Chugoku sekiyu kako shudan koji fukusei ren'yu kako yugen koji Fujian koio nodo sekiyu cokes no yuko riyo ni kansuru F/S chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of conserving energy and reducing greenhouse effect gas emission, an investigational study was conducted for the project on the effective utilization of high-sulfur petroleum coke at Fujian Petrochemical Co., Fujian Province, China. In the project, IGCC (integrated gasification combined cycle) power generation facilities are introduced to the refinery of Fujian Petrochemical Co. By gasifying the residues produced from the refinery as raw material, the gas clean the same as natural gas is produced and is used as power generation use fuel. As a result of the study, the energy conservation amount was 94,300 toe/y, and was 1,414,500 toe in cumulative amount during 15 years. Further, the amount of greenhouse effect gas reduction was 291,600 t-CO2/y, and was 4,374,000 t-CO2 in cumulative amount during 15 years. The construction cost of the project is approximately 29.7 billion yen. The annual profit to be obtained from the project is approximately 8.66 billion yen, which is indicated by difference between before and after the implementation of the project. The calculated years required for return of investment were 3.4. (NEDO)

  4. Fiscal 1993 international research cooperation project. Feasibility study of finding out the seeds of international joint research (technology for environmental preservation using biotechnology, technology for effective use of unused hydrocarbon resource, technology for development of environmental harmony type catalyst); 1995 nendo kokusai kyoryoku jigyo. Kokusai kyodo kenkyu seeds hakkutsu no tame no FS chosa (biotechnology ni yoru kankyo taisaku gijutsu, miriyo tanka suiso shigen no yuko riyo gijutsu, kankyo chowagata shokubai kaihatsu gijutsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    This project is aimed at internationally cooperating in the R and D of industrial technology and improving industrial technology of Japan. For it, the following three technologies were investigated: 1) environmental preservation technology using biotechnology, 2) technology for effective use of unused hydrocarbon resource, 3) technology for development of environmental harmony type catalyst. In 1), a survey was conducted of applicability of biological surfactant to prevention measures of pollution by heavy distillate. It showed that part of the biological surfactants is reaching a stage of its being industrially produced by gene recombination bacteria, but as a whole, biosynthetic genes have hardly been elucidated. In 2), a survey of high-grade treatment technology of petroleum coke was made. It pointed out that it is necessary to develop a technology which makes the most of features of petroleum coke and allows defects. In 3), scientists and engineers of Japan and Europe searched for themes on which they can jointly study in the fields of NOx removal catalyst, up-grading of fuel, and development of catalyst combustion of fuel. 287 refs., 136 figs., 128 tabs.

  5. Fiscal 1993 international research cooperation project. Feasibility study of finding out the seeds of international joint research (technology for environmental preservation using biotechnology, technology for effective use unused hydrocarbon resource, technology of solid electrolyte fuel cells for high-efficient electric vehicles); 1993 nendo kokusai kenkyu kyoryoku jigyo. Kokusai kyodo kenkyu seeds hakkutsu no tame no FS chosa (biotechnology ni yoru kankyo taisaku gijutsu, miriyo tanka suiso shigen no yuko riyo gijutsu, kokoritsu denki jidosha no kotai denkaishitsu nenryo denchi gijutsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This project is aimed at internationally cooperating in the R and D of industrial technology and improving industrial technology of Japan. For it, the following three technologies were investigated: 1) environmental preservation technology using biotechnology, 2) technology for effective use of unused hydrocarbon resource, 3) solid electrolyte fuel cell (SOFC) technology for high-efficient electric vehicles. In 1), bio-remediation is a choice as the result of trially using technologies for remediation of the environment polluted by pollutant, but it is not a technically completed one, but one which will be improved by trial and error. By the application of gene engineering, the use of gene recombination enables wide spread of decomposition genes. In 2), technical subjects were studied such as superheavy distillate, oil shale, coalhead methane and methane hydrate. In 3), designed were cylinder type and planar type SOFC of 850degC operation and 10kW output. Accumulation and weight of a total SOFC system are 81 liters and 100 kg in cylinder type and 136 liters and 200 kg in planar type. The vehicle can be equipped with the SOFC. 171 refs., 72 figs., 54 tabs.

  6. Cement manufacture and sludge; Semento seizo to gesui odei. Semento kojo deno antei shori {center{underscore}dot} yuko riyo gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Hirota, Yoji; Yamazaki, Masayasu; Hashimoto, Koichi [Mitsubishi Materials Corp., Tokyo (Japan)

    1998-11-10

    There was the percussion of the sludge processing from the Kitakyushu City in 1995. Within various waste treatment technology cultivated to it, the technology (direct combustion system) of cement raw material by the direct injection of sludge dehydrated cake to cement baking furnace was adopted. It became dealing with in cement baking furnace of the Kurosaki factory in our company. Through the processing by the present, it is not completely finding even in cement quality of the product, environmental side and on the problem. It was confirmed to be the processing technology of sewage dewatered sludge in which this technology was safely stabilized. In addition, the superiority in much global environmental protection has also been confirmed. (NEDO)

  7. Bioreactors for fixation and effective utilization of carbon dioxide gas. Tansan gas no koteiter dot yuko riyo no tame no bio reactor

    Energy Technology Data Exchange (ETDEWEB)

    Miyamoto, K. (Osaka University, Osaka (Japan). Faculty of Pharmaceutical Science); Benemann, J. (California University, CA (USA))

    1991-06-01

    As for a preventive countermeasure against the global warming, experiments and studies have been conducted on the bioreactors to fix carbon dioxide gas recovered from the concentric and large scale generating sources such as thermal power plamts in a form of carbohydrate by means of the culture of microbial algae. By using the Vertical Tube Reactors (VTR) culturing apparatus, a variety of microbial algae were cultivated and experiments were performed on the relationship of biomass productivity and absorption rate of carbon dioxide gas indoors and outdoors. Consequently, it was found that when the flow rate of carbon dioxide gas is adjusted to make the biomass productivity of filament type Nostoc maximum,the inlet and outlet concentrations of carbon dioxide gas were 0.7% and 0.05% respectively with the absorption rate of more than 90%. From the standpoint of fixation and effective utilization of carbon dioxide gas, the above rate of removal is one of the important parameters and it will be necessary in future to compare the rates of removal of carbon dioxide gas among various types of bioreactors as a function of operating condition. 9 refs., 6 figs., 2 tabs.

  8. Experimental study on the effective utilization of combusted scallop cultivation waste. Hotate yoshoku haikibutsu no yuko riyo no tame no shokyaku shori joken no jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Hase, Y [The Tohoku Electric Power Co. Inc., Sendai (Japan)

    1993-06-15

    Discussions are given on treatment methods that can utilize scallop cultivation wastes effectively. Tests to incinerate and convert the main scallop shell content, calcium carbonate, into calcium oxide (CaO) discovered optimal incinerating conditions of a temperature at 750[degree]C and a duration for 30 minutes, and 700[degree]C and one hour. CaO content in burnt shells was so high that they could be used as a raw material for quick lime. In the incineration and conversion tests on wastes from shell processing factories, the result of X-ray diffraction in chemically combined conditions of inorganics before and after the incineration revealed that the main component Ca existed as CaCO3, which may be converted into CaO when incinerated. The result also showed that the second component, Mg, existed as MgO after the incineration. From the above results, incinerating the wastes from shell processing factories at 750[degree]C would be capable of incinerating organic components completely and reducing their weights. Because the inorganic residues have high CaO content, they could be utilized effectively as a quick lime raw material. Although shells to be incinerated have low salt content because of having been boiled, salt content in scallop processing factory wastes will require discussions on possibilities of its corroding an incineration furnace. 3 figs., 7 tabs.

  9. Survey report for fiscal 1999 on internationalization of technologies for effective use of energy resources. Survey of international trend of technology management (Survey of necessity of creating a strategic research organization for researches on technology, management, innovation, etc., for international competitiveness enhancement); 1999 nendo energy shigen yuko riyo gijutsu kenkyu kokusaika chosa kokusai gijutsu keiei doko chosa hokokusho. Kokusai kyoryoku kyoka wo mokuteki to suru 'gijutsu' 'keiei' 'innovation' nado no senryakuteki kenkyu kiko sosetsu no hitsuyosei ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Innovation plays an important role for Japan to flexibly utilize its achievements for the purpose of properly responding to new business environments and to secure competitiveness in the market. Japan lacks experts equipped with knowledge and ability as regards technology development and management which are necessary for the planning and creation of technologies, and is also short of institutes for raising experts. In America, technology management won an important position in the 1980s in the effort at industrial renovation, and the industry, government, and academia in a body endeavored to elevate the level steadily, continuously, and deliberately, to eventually provide a source of great propulsion and international competitiveness toward today's economic success. Investigations were conducted, and a proposition is made for the establishment of an international technology management research center. Such a center will study technology management and innovation through international exchange based mainly on the industrial circle and through the organic coordination of the industry, government, and academia for widely observing changes in international society for economic frontier cultivation. A practical training and intelligent network will be organized on the global scale, which will serve as an information transmitter. A skeleton of the plan is shown. (NEDO)

  10. Causality analysis of alpha activities by multidimensional directed coherence; Tajigen yuko coherence ni yoru {alpha}ritsudo no ingasei kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Sakata, O.; Shimada, N.; Shiina, T. [University of Tsukuba, Tsukuba (Japan); Saito, Y.; Imanishi, N.

    1998-07-01

    Alpha activities as a basic component of EEG (electroencephalogram) are mainly observed with eye-closed and reported state, and indicates rhythmic and diffused pattern on the scalp. Therefore analysis of the relation among many sequences of alpha activities measured at different positions on the scalp is expected to be useful not only for diagnosing psychiatric but also for investigating mechanism of brain information processing by means of causality analysis that is, macroscopic estimation of flow pattern within brain. Although coherence analysis has been proposed as a method for estimating the direction and magnitude of information flow between two sequences, superposition of results for each pair of sequences can not represent true relation among the whole sequences. In this paper, we proposed the multidimensional directed coherence analysis by modifying two-channel formula in order to apply it to the analysis of multi-channel sequence of alpha activities. Results of simulation revealed that multidimensional directed coherence can indicate more quantitatively the relation among the multi-channel sequences compared with conventional two-channel formula. Moreover, the proposed method was applied to the analysis of EEG data of normal volunteer and patient. Results show the method can provide a useful diagnostic information by assessment of the signal flow pattern within brain. 16 refs., 10 figs.

  11. HLA antigens in five Amerindian groups (Yuko, Bari, Tunebo, Guane and Paez) of Colombia: results of 'Expedición Humana'.

    Science.gov (United States)

    Bernal, J E; Duran, C; Briceno, I; Ortega, J; Papiha, S S

    1995-01-01

    The serological HLA types (A, B, C and D loci) were studied in five different Indian groups in Colombia. The range of polymorphism was not very restricted in these groups, but there was significant genetic heterogeneity among the five populations in all the HLA loci. The gene frequency data, when converted into a kinship matrix and a two-dimensional eigen vector plot, showed a closer affinity between Bari and Yuko Indians, while Guane, Tunebo and Paez Indians were not only genetically different from the former but also well-differentiated from each other. It seems therefore from this study that geographical proximity may play a greater role than linguistic similarities in the genetic affinities of Colombian Amerindians.

  12. Report of a project for the technical development of the environmental preservation and resource effective utilization system in fiscal 1995; 1995 nendo kankyo hozen shigen yuko riyo system gijutsu kaihatsu jigyo hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The paper outlined the present situation of industrial waste all over Japan and the present situation of industrial waste of large urban areas where it is most difficult to secure places for the final disposal, and conducted an analysis on the present and future amount of final disposal waste. According to the literature from the Ministry of Health and Welfare, `research report on the discharge/treatment situation of the industrial waste` and `research results of administrative organizations for industrial waste,` the situation of final disposal from the past to the present was outlined and analyzed to study the future trend. Out of the administrative divisions of Japan, four divisions, which are all typically called large urban areas, were selected, and the situation of industrial waste in large urban areas was outlined and analyzed according to the questionnaire survey and the literature on industrial waste obtained from each administrative division. The survey by the Ministry of Health and Welfare indicated that the volume of the industrial waste discharged from the whole country amounted to approximately 400 million tons in fiscal 1992. However, helped by the improving recycling of waste construction materials, the amount of final disposal around 2000 is presumed to be less by 20% or so than that in 1992. 58 refs., 5 tabs.

  13. FY 1999 report on the results of 'the model project for effective utilization of the waste heat discharged from the combustion of paper-manufacturing sludge'; 1999 nendo seika hokoku. Seishi surajji nensho hainetsu yuko riyo moderu jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of reducing the consumption of fossil fuel and reducing emissions of global warming gases in Malaysia, a model project for thermally effective use of the sludge discharged from paper-manufacturing plant was carried out. Concretely, the paper-manufacturing sludge discharged from paper-manufacturing plant is to be dewatered and improved of its lower heating value. Then, the sludge is to be burned in fluidized bed incinerator, and the steam is to be generated by recovering heat using waste heat recovering boiler. The steam obtained is to be used as process steam of the plant. In this fiscal year, the first year of the project, the attachment to the agreement was prepared in terms of the allotment of the project work between Japan and Malaysia, various kinds of gist, schedules, etc. and signed. After that, the determination of the basic specifications for facilities was made according to the attachment to the agreement. Now, the basic design of the whole plant is being made. The design of the process flow sheet, design of the layout plan for plant equipment, etc. were finished. The goods to be purchased are now being estimated and assessed. Moreover, as to the civil engineering/construction design, drawings of the basic design are now being made. (NEDO)

  14. Fiscal 1994 entrusted task report. Surveys of advanced natural gas development and efficient utilization (Survey of coal hydrogasification technology development); 1994 nendo tennen gas kodo kaihatsu yuko riyo chosa tou itaku gyomu hokokusho. Sekitan suiten gaska gijutsu kaihatsu chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    For the establishment of a practical process for substitute natural gas (SNG) production, technological and economical assessments were made, and tasks to discharge for the development were discussed. In this fiscal year, the results of surveys conducted in the past five-year period were compiled, and studies were made to prepare for a smooth transition to the element research stage. Findings obtained are described below. SNG producing technologies need to be developed, with the demand for SNG increasing sharply, to further stabilize the base for SNG supply; coal which is abundantly available should be used as the material for SNG; and coal hydrogasification, among various methods for producing SNG from coal, is the most suitable in view of efficiency and cost performance. It was also found after a prolonged study for the improvement of efficiency and cost performance that probabilities were high that the yield of BTX (benzene, toluene, xylene) would increase and cost performance would improve. Besides, a basic plan and an element technology research plan were prepared for the development of the ARCH (advanced rapid coal hydrogasification) process. (NEDO)

  15. Systematic arrangement of global environment measure technology. 3. Current status of methane generation and its effective utilization; Chikyu kankyo taisaku gijutsu no taikeiteki seiri. 2. Methane no hassei jokyo to sono yuko riyo no genjo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The status of the methane generation due to landfill with waste has been analyzed to investigate the actual circumstances of effective utilization of methane in the world and its possibility. The artificial generation of methane is 375 Tg per year among the total methane generation in the world, 535 Tg per year. The methane generation from the landfill with waste is 40 Tg per year, which becomes a rather large contribution. The methane generation from the landfill with waste in Japan is estimated to be from 130 to 520 Gg per year, which is a rather low value as a share in the world. This is caused by the sub-aerobic property of landfill in Japan, and the methane generation can be suppressed. Accordingly, there are no systems using recovered methane as energy source in Japan. In the USA, profitability of energy recovery can be established in 600 to 700 landfills among about 6,000 landfills. The methane recovery is practically conducted at more than 120 landfills. The recovered methane is used as a power generation fuel. 45 refs., 43 figs., 27 tabs.

  16. FY 1999 report on the results of the model project for facilities for effective utilization of paper-manufacturing sludge, etc.; 1999 nendo seika hokoku. Seishi surajji tou yuko riyo setubi moderu jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of contributing to the reduction in the energy consumption in the paper/pulp industry which is an industry of much energy consumption in Indonesia and to the stable energy supply in Japan, a model project for facilities for effective utilization of paper sludge, etc. was carried out, and the FY 1999 results were reported. Concretely, the paper sludge and solid waste discharged from the paper-manufacturing process are to be incinerated in self-combustion in fluidized bed incinerator. Further, the remaining heat is to be recovered as steam from the combustion exhaust gas for the effective utilization within plant. This verifies the reduction in energy consumption and reduction in emission of greenhouse effect gas. Activities for spread of the said facilities are to be made in Indonesia. The site for this project is FSW located in Bekasi, West Jawa. This is a private paper company which manufactures cardboard use paper of 0.5 million t/y using used paper as raw material. In this fiscal year, instructors were sent to FSW for installation/construction work according to the basic agreement and the attachment to the agreement. (NEDO)

  17. Report on investigations in fiscal 2000 on the basic investigation on promotion of joint implementation. Effective utilization of associated gas as CNG; 2000 nendo kyodo jisshi nado kiso chosa hokokusho. Zuihan gas no CNG to shite no yuko riyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The Back Ho oilfield is the largest oilfield in Vietnam and at the same time is producing the largest amount of natural gas (associated gas) in Vietnam. Although the majority of the associated gas has been used in the power generation plant, a large amount of surplus gas is not effectively used because of shortage of fund and technologies. Accordingly, a feasibility study has been executed for a project to compress 20% of the associated gas into CNG, and use it effectively as automobile and factory fuel. As a result of the site survey, it was found that, although Vietnam consumes less amount of energy and emits less amount of CO2, the nation has a strong interest and a large amount of knowledge about global warming and CDM because the country is subjected to large effect of warming. Furthermore, it has been reconfirmed that introducing CNG into this territory is highly effective. Discussions have been made on places of installing the facilities, effective surplus gas utilization systems, facility specifications, utilities, and number of workers. Calculations were made on approximate cost of the facilities and the running cost. As a result of the surveys and discussions, it was determined that technological support from Japan and the Yen loan for environment with low interest rate are necessary. (NEDO)

  18. Improvement of effective utilization technology of wood-based resources and development of their new application fields. Mokushitsukei shigen no yuko riyo gijutsu no kojo to shin prime yoto kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kamiya, F.; Haishi, T.; Sueyoshi, S.; Sotozaki, M.; Kato, A.; Hayashi, Y.; Ito, Y.; Hirabayashi, Y.; Togawa, E.; Obino, T. (Forestry and Forest Products Research Institute, Ibaraki (Japan))

    1991-09-01

    On advanced work and use techniques for wood, the aseismic property of plywood-nailed bearing walls was analyzed by seismic response experiments on an excitor resulting in the sufficient aseismic property beyond usual design specification, and the load deformation model was proposed based on experimental results. The evaluation method of heat insulation for wood houses was also developed, and the simple estimation method of room temperature change and the index for evaluating heat insulation for every structure were proposed. On advanced modification and use techniques for constituents of wooden resources, the chemical structure of saponin in woods was studied together with the relation between the chemical structure and biological activity of unknown saponins synthesized from triterpene. The pervaporation property of organic composite films composed of chitinous substances and cellulose derivatives from natural polymers was also studied to develop pervaporation films effective in separating water from ethyl alcohol. 11 figs., 3 tabs.

  19. Fiscal 2000 report of investigation. Research on effective use of technology for biomass waste and diffusion scenario of the technology; 2000 nendo biomass kei haikibutsu no yuko riyo gijutsu to sono fukyu scenario no chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Examination and proposal were made on the effective uses of technologies for biomass wastes and on the diffusion scenarios, with trial calculations done to find the maximum reducible amounts in terms of carbon dioxide. In the examination of the systems, it was focused on five technologies, namely, direct combustion of straw and rice straw/CHP/heat utilization, synthesis of gasified methanol from demolition wood, biogas/CHP from livestock feces and urine, conversion to ethanol through saccharification of used paper, and conversion to biodiesel from vegetable waste oil; the examination also covered each feature, core function, use situation inside and outside Japan, technological system for each energy conversion, etc. Further, solutions were examined and proposed concerning diffusion barriers in each scenario. Consequently, the maximum amount of CO2 reduction effect was found respectively 217 thousand t-C in the straw and rice straw, 500 thousand t-C in the demolition wood, 9.53 million t-C in the livestock feces/urine, 820 thousand t-C in the used paper, and 30 thousand t-C in the vegetable waste oil. (NEDO)

  20. Report on a survey in fiscal 1999. Survey on technologies to effectively utilize biologically originated organic wastes, and the scenarios for proliferation thereof; 1999 nendo seibutsu kigen yukihaikibutsu no yuko riyo gijutsu to sono fukyu scenario no chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    With the biologically originated organic wastes (biomass) left unattended in Japan without being given effective measures as the object, effects are presented on contribution to reducing greenhouse effect gas emission and reducing environmental load, and considerations were given on scenarios to proliferate the utilization technologies. These actions were carried out upon identifying the trends inside and outside the country of developing methods and technologies to utilize them effectively as energy sources. Because of the present shortage in support from the policy aspects for regenerative energies themselves, the back-up from energy policy aspect is an urgent necessity by establishing such a law as the 'natural energy utilization promotion law' whose legislation is proposed by citizens. Appropriate useful technologies would have to be introduced into appropriate applications under such legislative support. For the time being, the 'wastes electric power generation' and 'bio-gasification power generation' systems that have been established already will be utilized. Furthermore, methanol and hydrogen will be synthesized from biomass to be used as fuel for fuel cells. Utilization of the cascade type system is advocated that uses substances sequentially from better ones to utilize woody biomass without waste. (NEDO)

  1. Fiscal 1999 basic study for promotion of joint implementation. Effective utilization of associated gas at Kokdumalak Field of the Republic of Uzbekistan; 1999 nendo Uzbekistan koku Kokdumalak zuihan gas yuko riyo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    A feasibility study is conducted for an Uzbekistani plan for effectively utilizing associated gas at its Kokdumalak Gas Field. The effort will lead to a clean development mechanism in the future. The associated gas and off-gas now being totally burnt in a flare stack will serve as raw materials for the recovery of LPG (liquid petroleum gas), NGL (natural gas liquid), etc. The amount of total investment is US$82,003,000, with US$69,739,000 borrowed and US$12,264,000 self-financed. Thanks to the products to be recovered, there will be an energy substitution rate of 168,418 tons per year in terms of oil. There will be a huge reduction of greenhouse gas emissions of 4.52-million tons per year in terms of CO2, tantamount to the discharge of a 1000MW-class power plant. Although the project will be low in profitability, with the FIRR (financial internal rate of return) on investment before tax being as low as 10.56%, yet it is desired that, in view of the expected reduction in greenhouse gas, effective utilization of associated gas, and in view of its impact on the future development of the Republic of Uzbekistan and its society, the project will be implemented as soon as possible. It is expected that the country will enjoy various tax revenues to be created, foreign exchange by importing LPG, and earnings through emission right trading involving greenhouse gas. (NEDO)

  2. Report of base consolidation promotion survey of overseas coal import in FY 1993. Feasibility survey of effective utilization of coal ash; 1993 nendo kaigaitan yunyu kiban seibi sokushin chosa. Sekitanbai yuko riyo jigyo no feasibility chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This report describes the effective utilization of coal ash discharged from general industry (general industry ash) as improving material of construction waste soil and deodorant for poultry industry. Coal ash is characterized by the pozzolan and self-hardening properties which are not shown in soil and sand. Coal ash having a large amount of free CaO in its composition has stronger such properties. Coal ash generated from fluidized bed combustor which is a kind of combustor of coal contains a large amount of free CaO, especially, resulting in the stronger such properties. On the other hand, coal ash has water and oil absorbing property due to its porous structure. To utilize these properties, the improving material of soft construction waste soil and deodorant for poultry industry have been selected. As a result of laboratory and field tests for the former, it was found that sufficient supporting force can be obtained. Since the protection of powder splash is required at the site, a humidification system has been developed, which can protect the splash by the humidification of 5%. The price between 500 and 1,000 yen/ton is suitable for the improving material of construction waste soil. The maximum price of the deodorant for poultry industry is 10 yen/kg. 14 refs., 40 figs., 49 tabs.

  3. FY 2000 report on the results of the model project on facilities for the effective utilization of industrial waste from industrial complex. Separate Volume 3; 2000 nendo Kogyo danchi sangyo haikibutsu yuko riyo setsubi model jigyo. Dai 3 Bunsatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-03-01

    For the purpose of promoting the effective utilization of industrial waste as petroleum substitution energy resource and reducing the consumption of fossil fuels in Thailand, a model project on facilities for the effective utilization of industrial waste from industrial complex was worked on, and the FY 2000 results were reported. In Separate Volume 3, drawings of the following were included: furnace, free board spray nozzle, dispersion air nozzle, secondary burner, sand make-up conveyor, sand discharge gate, boiler, silencer for boiler safety valve, steam header, steam accumulator, gas cooling tower, refuse drainage storage tank, small sized drainage pump, pressure tank, flue gas duct, air damper, incombustible conveyor 2, sand circulation system bag filter, weighing bridge, fan starter panel, control panel, control panel, local switch box, distributed control system, field instrument, flue gas analyzer. (NEDO)

  4. FY 1999 report on the model project on the effective utilization of waste-base biomass fuels. Basic survey for the feasibility; 1999 nendo haikibutsukei biomass nenryo yuko riyo model jigyo jisshi kanosei kiso chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Survey on the waste biomass was conducted for Thailand, Malaysia, Indonesia, Vietnam, Laos, Nepal, Butan, Myanmar and Cambodia to study feasibility of the project for the concrete utilization of biomass resources. In Thailand, it is expected to construct large-scale model plants for biomass resources such as rice hulls, bagasse, wood waste and oil palm. In Malaysia, expected are the cogeneration at 5MW class palm oil plant, large-scale power plant using wood waste, plant using the biomass from waste palm oil, etc. In Indonesia, there is a great potentiality, but it is necessary to handle it carefully in consideration of the unstable situation of the society. In Vietnam, the detailed survey of feasibility is needed on the project for efficiency heightening at state-run plants, the assumed national plants (recommended by the government), etc. In Laos, small-scale power generation using the forestry waste such as sawdust is expected. (NEDO)

  5. Test results of cultivation of vegetables with fish breeding water; Yogyosui riyo ni yoru yasai saibai shiken kekka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nishida, S. [Hokuriku Electric Power Co. Inc., Toyama (Japan)

    1997-10-28

    Entrails of fish, fowls and domestic animals are mostly incinerated at large expenses, although partly used as foods. This study is to test `possibility of vegetable cultivation with fish breeding water,` where the entrail wastes are used as baits for fish breeding, and fish excretions are used as the fertilizer for vegetable cultivation to purify water for fish breeding. The cultivation bed consists of two sections, one for fish breeding/vegetable cultivation and the other for vegetable cultivation by the normal method. Vegetable grow notably less in the former than in the latter, 54.6 to 79.5 versus 100. Spinach contains slightly higher contents of vitamins A and C by 6 and 13%, when cultivated in the former than in the latter. Quantities of total nitrogen, phosphorus and potassium as the fertilizer components in the former are 49, 49 and 1.7% of those in the latter. It is predicted, judging from growth of the vegetables, that the former gives a harvest comparable with that by the latter, when given a 6 to 13 days longer cultivation period. 3 figs., 2 tabs.

  6. Test results on vegetable cultivation using fish breeding water; Yogyosui riyo ni yoru yasai saibai shikenkekka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nishida, S. [Hokuriku Electric Power Co. Inc., Toyama (Japan)

    1997-10-30

    Although a part of the entrails of fishes, birds and livestock is used for food, most of them are treated by costly combustion because of their bad odor and looking, and International Environment and Welfare Laboratory, Toyama prefecture in Japan is studying their profitable treatment. As a part of such study, possibility of hydroponic cultivation of vegetable was tested using fish breeding water including excretions of fishes and residual feeds after use of waste as feed, and the growth condition, safety and effectiveness of cultured vegetable were verified. Three-hundred and fifty viviparous Oryzias were released into a breeding water area with no controlled pH and EC (electric conductivity). For comparison a culture solution area of 6.0 in pH and 1.2ms/cm in EC was prepared. The result on cultivation of 6 kinds of vegetable in culture beds supported by circulation of these water showed that hydroponic cultivation of vegetable using fish breeding water is possible, and average growth of 68% is obtained although difference in growth for every vegetable is found. 8 figs., 5 tabs.

  7. Development for environmentally friendly and highly efficient energy utilization system in fiscal 1998. Pt. 3. Research on highly efficient and effective energy utilization technology (Research on design technology for optimal system); 1998 nendo kankyo chowagata kokoritsu energy riyo system kaihatsu. 3. Kokoritsu energy yuko riyo gijutsu no kenkyu (saiteki system sekkei gijutsu no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-05-01

    This paper summarizes achievements during fiscal 1998 on researching part of the energy transportation and storage technologies, energy supply and utilization technologies, environmental load reducing technologies, and optimal system design in the 'research on highly efficient and effective energy utilization technology'. With regard to energy transportation and storage technologies, researches and developments were performed on a vacuum adiabatic transportation piping system, surfactants used for high-density heat transportation and high-density latent heat transportation technologies. In the field of energy supply and utilization technologies, researches and developments were carried out on a heat supply system using high-performance heat pumps capable of using multiple kinds of fuels, and a compression and absorption type hybrid heat utilization system. For the environmental load reducing technologies, research and development were performed on a power saving heat pump system utilizing natural coolant. In researching the optimal system design technologies, overall adjustment was made on the element technologies, whereas technological discussions and site surveys were executed by the committees at the same time. The latest achievements accomplished to date was published in a book. (NEDO)

  8. FY 1999 Technical research and development for environmentally friendly and highly efficient energy utilization system. Technical research and development for highly efficient and effective energy utilization (Technical research and development for optimum system designs - Part 3); 1999 nendo kankyo chowagata kokoritsu energy riyo system kaihatsu seika hokokusho. 3. Kokoritsu energy yuko riyo gijutsu no kenkyu (saiteki system sekkei gijutsu no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-05-01

    Research and development program is conducted for the elementary techniques as part of the eco-energy urban project of New Sunshine Project. Described herein are the FY 1999 results for the (techniques for transportation and storage of energy (continued), energy supply and utilization, reducing environmental loads, and designing the optimum systems). The R and D on heat transfer system through the vacuum heat insulation pipes involves fabrication, on a trial basis, the vacuum insulation covers for the vacuum insulation tubes, joints, flanges and valves for the 80A pipes, and the heat loss evaluation test for each item. The R and D on the energy supply and utilization techniques involves the heat transfer systems for a variety of fuels by the highly functional heat pump, and compression/absorption hybrid type heat-utilization system. The hybrid type heat-utilization system simulation results suggest possibility of achieving exergy efficiency of 56% as the development target by use of the new medium. The R and D on the environmental load reduction involves the power-saving type heat pump systems which use a natural coolant. (NEDO)

  9. Achievement report for fiscal 1998 on development of environmentally friendly high-efficiency energy utilization system. 2. Research of technology of effectively utilizing high-efficiency energy / research of optimum system designing technology; 1998 nendo kankyo chowagata kokoritsu energy riyo system kaihatsu. 2. Kokoritsu energy yuko riyo gijutsu no kenkyu, saiteki system sekkei gijutsu no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-05-01

    This 2nd volume deals with the transportation and storage of energy in the above-named research. In search of technologies for transporting exhausted heat from the industrial area to the urban section for consumers to utilize the heat for driving their air-conditioners and hot water supply systems, the decomposition and composition reactions of methanol are utilized for a long-range transportation system. The subjects taken up in this connection include the research and development of a methanol energy system, non-equilibrium high-efficiency methanol decomposition technology, multifunctional catalysts, and highly active/selective catalysts capable of promoting reversible endoergic/exoergic reactions. Research and development is also conducted of a high-efficiency heat pump technology using hydrogen-absorbing alloys, and such a pump will realize an air-conditioning system not dependent on chlorofluorocarbon. In the research and development of a long-range heat transportation system using hydrogen-absorbing alloys, a study is made of technologies of heat/hydrogen recovery, transportation, and utilization. (NEDO)

  10. FY 1999 Technical research and development for environmentally friendly and highly efficient energy utilization system. Technical research and development for highly efficient and effective energy utilization (Technical research and development for optimum system designs - Part 2); 1999 nendo kankyo chowagata kokoritsu energy riyo system kaihatsu seika hokokusho. 2. Kokoritsu energy yuko riyo gijutsu no kenkyu (saiteki system sekkei gijutsu no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-05-01

    Research and development program is conducted for the elementary techniques as part of the eco-energy urban project of New Sunshine Project. Described herein are the FY 1999 results for the (techniques for transportation and storage of energy). The R and D on methanol energy systems involves the R and D on decomposition and synthesis catalyst of methanol and methyl formate for the waste heat sources of relatively low temperature. The R and D on high-efficiency techniques using hydrogen-occluding alloys involves development of heat exchangers of low sensible heat ratio, fabrication of double-effect type MH heat pump cycle devices, and demonstration tests for the system operation. It is found that the heat output of the hydrogen-occluding alloy for high temperature use is 0.18kW/kg at 90 degrees C, and that the alloy can be massively produced. A thermal utilization efficiency COP of 0.68 is obtained for the double-effect type MH heat pump cycles. The R and D on the heat-hydrogen recovery, transportation and utilization techniques involves designs and fabrication on a trial basis of a sensible heat recovery unit. (NEDO)

  11. FY 1999 R and D project on the global environmental industry technology. Report on the results of the R and D on the catalytic hydrogenation use CO2 fixation/effective utilization technology; 1999 nendo sesshoku suisoka hanno riyo nisanka tanso seika hokokusho. Koteika yuko riyo gijutsu kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of reducing CO2 emitting together with the consumption of fossil fuels, study was conducted on the use of CO2 by converting it to chemical substances such as methanol, etc., and the FY 1999 results were outlined. In the development of the CO2 separation membrane technology, data were obtained on effects of scaling-up by module with a membrane area of 4.9m{sup 2} and on design conditions. Further, in the experiment using mock exhaust gas, it was confirmed that the performance had been kept up for 3,000 hours or more. In the development of catalytic hydrogenation technology, the basic data for enlargement were accumulated. Moreover, the activity stabilized about 18,000 hours was confirmed, and the catalytic life was estimated at more than 3 years. In the development of large quantity hydrogen production/supply technology, assembly/operation of 7,500cm{sup 2} x 6 electrolytic cells were conducted, and it was confirmed that the hydrogen production capacity per cell was 3Nm{sup 3}/h. The final target for enlargement was achieved. In the study of the total system, the conceptual design was made for 'high concentration CO2 containing natural gas use CO2 recovery utilization system,' and 'biomass resource use methanol synthesis system.' (NEDO)

  12. FY 1999 Technical research and development for environmentally friendly and highly efficient energy utilization system. Technical research and development for highly efficient and effective energy utilization (Technical research and development for optimum system designs - Part 1); 1999 nendo kankyo chowagata kokoritsu energy riyo system kaihatsu seika hokokusho. 1 Kokoritsu energy yuko riyo gijutsu no kenkyu (saiteki system sekkei gijutsu no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-05-01

    Research and development program is conducted for the elementary techniques as part of the eco-energy urban project of New Sunshine Project. Described herein are the FY 1999 results for the 'techniques for recovery and conversion of unutilized energy'. The R and D on waste heat recovery and conversion for chemical plants designs an internal structure of the 'wetted wall column for shell side as the stripping section' for increasing quantity of heat exchanged inside, and stably operates the bench plant for 100 hours or more. The R and D on thermoelectric power generating systems using low calorie exhaust gases involves development of materials, production of fine particle materials and sinters, and evaluation of their functions, among others. The program for application of the techniques to commercial plants confirms applicability of a 3kg thermoelectric power generating system to automobile coating process. The R and D on systems for thermoelectric recovery of low-temperature waste heat finds cracks on the ceramic plate for the power generating system WATT100, disassembled for repair. (NEDO)

  13. FY 2000 report on the results of the development of the environmentally friendly type high efficiency energy utilization system. Part 2. Study of the effective utilization technology of high efficiency energy (Study of the optimum system design technology); 2000 nendo kankyo chowagata kokoritsu energy riyo system kaihatsu seika hokokusho. 2. Kokoritsu energy yuko riyo gijutsu no kenkyu (saiteki system sekkei gijutsu no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-05-01

    The paper conducted the development of the environmentally friendly type high efficiency energy utilization system and the R and D of the high efficiency energy effective utilization technology, and the FY 2000 results were summed up. As to the energy transportation/storage technology, the R and D were made on the following: methanol/energy system, non-equilibrium high efficiency methanol decomposition reaction technology, development of multiple functions of catalyst, high efficiency heat pump technology using hydrogen storage alloys, heat-hydrogen recovery/transportation/utilization technology, vacuum insulated heat transport piping system, surfactant used for high density heat transport, high density latent heat transportation technology, etc. Concerning the energy supply/utilization technology, the R and D were made of the heat supply system using high efficient heat pump corresponding to multiple fuels. Relating to the environmental load reduction technology, the energy conserved heat pump system using natural coolant. As to the optimum system design technology, the comprehensive preparation of element technology, etc. (NEDO)

  14. FY 1999 report on the results of the R and D of the global environmental industry technology. R and D of the CO2 fixation/effective use technology using bacteria/algae; 1999 nendo saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of developing the technology to fix CO2 and recycle it as resource in higher efficiency than that in photosynthesis in the nature world, study of bacteria, etc. was made in terms of the search, breeding, and artificial realization of the growth environment, etc. The FY 1999 results were summed up. As to high efficiency photosynthetic bacteria/microalgae, conditions for sampling/breeding/optimum culture of bacteria were established and made database. From conditions for the optimum CO2 fixation by photosynthetic bacteria, oxygen injury prevention culture method, continuous culture experiment, etc., it was found out that the carbyne cycle was a main route of the carbon fixation also in photosynthetic bacteria. As to the cell fusion, established were the technology of electric fusion of interspecific fusion strains and the technology of evaluation of growth characteristics. Also studied was a method to transfect genes into Chlorella sp. which fixes CO2. Concerning the light collecting reactor of 200L scale, a high concentration culture experiment was carried out using Chlorella sp. UK001 as the strain tested, and the engineering data on the behavior in culture tank, multiplication speed, etc. were collected. (NEDO)

  15. Industrial technology research and development project for global environment in fiscal 1998. Report on achievements in research and development of technologies for fixation and effective utilization of carbon dioxide by utilizing bacteria and algae; 1998 nendo saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Microorganisms are cultivated industrially in a great quantity to fix CO2 at efficiency higher than that of photosynthesis in natural world to develop technologies to re-utilize them as resources. This paper describes achievements in fiscal 1998. Existing strain samples of photosynthesized bacteria and micro-algae were screened to continue discussions on optimal culture conditions, and evaluation on properties. Genes that provide Chlorella with antibiotic resistance were introduced to have performed evaluation on function manifestation, and acquired enzymatic genes of unsaturated {omega} 3. Using green algae as the object, reduction in the processing time has resulted in acquiring a large number of fused cell colonies. Discussions were given on conditions to breed photosynthesized bacteria and fix CO2. Structural analyses were performed on CA protein as an enzyme related to take CO2 into living organisms, and on genes. Developments were carried out on a photosynthesizing bio-reactor and useful substance producing technologies on a continual basis. A 200-liter scale light collection type bio-reactor improved the fixing capacity by 30% in Chlorellas by changing the culture medium. The direct light receiving panel type bio-reactor can utilize even scattered light, with its fixing capacity per installation area exceeding the target. Fundamental data were acquired with Chlorellas on utilizing feeds, fertilizers and building materials. (NEDO)

  16. FY 2000 report on the results of the development of the environmentally friendly type high efficiency energy utilization system. Part 1. Study of the effective utilization technology of high efficiency energy (Study of the optimum system design technology); 2000 nendo kankyo chowagata kokoritsu energy riyo system kaihatsu seika hokokusho. 1. Kokoritsu energy yuko riyo gijutsu no kenkyu (saiteki system sekkei gijutsu no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-05-01

    The paper conducted the development of element technology and comprehensive adjustment which are related to the development of the environmentally friendly type high efficiency energy utilization system and the study of the high efficiency energy utilization technology, and the results of FY 2000, the final fiscal year, were summed up. As to the R and D of the exhaust heat reforming/recovery system, the internal heat exchange type distillation tower was developed which has a good energy conservation effect and enables the heat supply outside. Concerning the R and D of the cogeneration system using low calorie exhaust gas, the following were conducted for further improvement of the performance of electrothermic elements: evaluation of the thermoelectric performance using bulk elements, development of new elements and evaluation of the energy balance at the time of combustion, etc. Relating to the R and D of the low temperature exhaust heat utilization cogeneration system, conducted were the development of thermoelectric materials and the fabrication/evaluation study of module. Moreover, WATT20A equipped with the original power generation module developed in this study was fabricated, and the data on the operation at the temperature of 150 degrees C were obtained by WATT-20HT. (NEDO)

  17. Development for environmentally friendly and highly efficient energy utilization system in fiscal 1998. Pt. 1. Research on highly efficient and effective energy utilization technology (Research on design technology for optimal system); 1998 nendo kankyo chowagata kokoritsu energy riyo system kaihatsu. 1. Kokoritsu energy yuko riyo gijutsu no kenkyu (saiteki system sekkei gijutsu no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-05-01

    This paper summarizes achievements of the researches during fiscal 1998 on researching a highly efficient and effective energy utilization technology. With regard to technologies to recover and convert unutilized energies, a process simulator was developed, basic internal structure was discussed by experiments and simulation, and substance migrating and heat exchanging characteristics were identified by using partial testing devices. These researches and developments were performed for the waste heat reforming and recovering systems used in chemical plants. In developing a thermoelectric generation system using low calorie exhaust gases, thermoelectric power generating materials were developed, a powder manufacturing technology was developed, a thermoelectric conversion element bulking technology was developed, a thermoelectric power generation system using porous structures was simulated, development and concept design were carried out on system element technologies. In the research and development of the thermoelectric generation system using low calorie exhaust gases, advanced materials and modules were manufactured, the modules were evaluated, and power generation systems were researched. In addition, researches were performed on energy transportation, supply and utilization technologies, and on environmental load reducing technologies. (NEDO)

  18. Industrial science and technology research and development business for fiscal 1998. Research and development achievement report on glycoconjugate production and utilization technologies (Development of technologies of glycoconjugate-aided CO{sub 2} fixation and utilization); 1998 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo. Fukugo toshitsu seisan riyo gijutsu no kenkyu kaihatsu seika hokokusho (fukugo toshitsu oyo nisanka tanso koteika yuko riyo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Enzymatic and chemical methods were combined and methods were developed for synthesizing mucin type sugar chains and glycopeptides. The influence of sugar chain positions and structures on glycoconjugate stereo structures and physiological activities was analyzed, and glycopeptide structural activities and glycoconjugate remodelling were studied. To create an industrial advantage in a glycoprotein production system by use of zooblasts, sugar chain structure control through sugar transfase occurrence control was studied. For the production of man-adaptive sugar chains using yeast, new yeast variations were subjected to molecular breeding, and tested for the resultant improvement on productivity. Sugar chain marking and refining techniques and various responding mechanisms on the solid surface were elucidated, which enabled structure analyses using sugar chain recognition molecules such as lectins and antibodies. A database on interactions between sugar chains and sugar chain recognition molecules was constructed using the said findings. An analyzing program was also formulated tentatively. This paper also covers general surveys and studies on technologies of producing and utilizing glycoconjugates. (NEDO)

  19. FY 1999 R and D project on the global environmental industry technology. Report on the results of the R and D on the catalytic hydrogenation use CO2 fixation/effective utilization technology; 1999 nendo sesshoku suisoka hanno riyo nisanka tanso seika hokokusho. Koteika yuko riyo gijutsu kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of reducing CO2 emitting together with the consumption of fossil fuels, study was conducted on the use of CO2 by converting it to chemical substances such as methanol, etc., and the FY 1999 results were outlined. In the development of the CO2 separation membrane technology, data were obtained on effects of scaling-up by module with a membrane area of 4.9m{sup 2} and on design conditions. Further, in the experiment using mock exhaust gas, it was confirmed that the performance had been kept up for 3,000 hours or more. In the development of catalytic hydrogenation technology, the basic data for enlargement were accumulated. Moreover, the activity stabilized about 18,000 hours was confirmed, and the catalytic life was estimated at more than 3 years. In the development of large quantity hydrogen production/supply technology, assembly/operation of 7,500cm{sup 2} x 6 electrolytic cells were conducted, and it was confirmed that the hydrogen production capacity per cell was 3Nm{sup 3}/h. The final target for enlargement was achieved. In the study of the total system, the conceptual design was made for 'high concentration CO2 containing natural gas use CO2 recovery utilization system,' and 'biomass resource use methanol synthesis system.' (NEDO)

  20. Fiscal 1996 report on the results of the R and D under a consignment from NEDO of the technology to fix and effectively use carbon dioxide using bacteria and microalgae (for public); 1996 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku (saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kenkyu kaihatsu seika hokokusho (kokaiyo))

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the purpose of contributing to the solution to the global environmental problem, a technology is developed in which by searching for/breeding/developing bacteria, etc. which conduct photosynthesis highly effectively, CO2 is fixed and recycled. The fiscal 1996 R and D is outlined as the utilization of bacteria, microalgae, etc. Obtained were microalgae exceeding the conventional strains in CO2 fixation ability, and bacteria/microalgae excellent in production of polysaccharides, hydrocarbon, lipid, biological active substances, etc. The fundamental study was continued of CO2 integrated enzyme function/reaction system as molecular biological breeding. In the cell fusion, a set-up of conditions for green algae was started. For the confirmation of performance of high dense/quantity culture technology using solar light, further improvement of performance and systematization, 200L scale testing equipment was manufactured. It is a collective reactor and enabled study of ventilation/agitation and control of light strength. A reactor analysis model was constructed. Also including the conversion into useful substances, energy/material balance was systematically studied. Collection of technical literature and information exchanges were made in Japan and overseas. 276 refs., 475 figs., 156 tabs.

  1. Study on utilization of shallow sea area by building an alga field. Discussions on its utilization for cultivating Ulvales; Sojo zosei ni yoru senkaiiki riyo no kenkyu. Anaaosa no baiyo to sono riyo ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Tsuno, M.; Maebayashi, M. [Hokkaido Electric Power Co. Inc., Sapporo (Japan)

    1997-03-25

    Discussions were given on mass cultivation in a water tank using sea water of an alga Ulvales used as feed for sea urchins and abalone. A fertilizer composed of ammonium sulfate and superphosphate of lime was used, and a water temperature was set as the environmental condition. Two kinds of Ulvales produced in different areas were used. One of the two kinds had full growth periodical and weight increasing rate low, but the other Ulvales had high weight increasing rate and no blights in alga bodies, and was found suitable for mass production. The result of a test on stocks of the latter species may be described as follows: multiple regression formulas for harvest, water temperature and illumination intensity were introduced for each cultivating condition for four cases regarding accommodation density and harvest frequency; and if a cultivating condition by which the harvest is maximized is adopted, a one cubic meter water tank placed on a place with good sunlight may be expected of producing as much harvest as 2181 grams at water temperature of 15{degree}C and 4899 grams at 25{degree}C. The cultivation requires the following precautions: aeration is required; sea water should be introduced into the tank; a mixed fertilizer with ratio of ammonium sulfate at 100 to superphosphate of lime at 15 may be used; water temperatures suitable for mass cultivation are 13 to 15{degree}C or higher; and light must be irradiated evenly. 14 refs., 9 figs., 5 tabs.

  2. Transition of wind power utilization technology in the 20th century; 20 seiki ni okeru furyoku riyo gijutsu no hensen

    Energy Technology Data Exchange (ETDEWEB)

    Ushiyama, I. [Ashikaga Inst. of Tech., Tochigi (Japan)

    2000-04-01

    Windmills are one of the oldest prime movers and have been used for more than 700 years in Europe. The transition from low speed windmills for grain grinding and water pumping to high speed wind turbines for electric power generation had occurred at the end of 19{sup th} century. This paper, at first, reviews the windmill technologies and the researchers before 20th century. Then describes the back ground of how the wind power generator has existed and how the four pioneers developed their wind power generator. The historical developments of windmills to wind turbines in this century are studied focusing mainly on Danish activities. Then, the effort of the development of large wind turbine such as Smith-Putnum's first MW machine in U.S.A. and other mammoth machine concept are introduced. The new concept machines such as Savonius and Darrieus wind turbines in 1920s to 1930s are also explained. Finally, the novel technologies of wind turbine covering larger machines, variable speed generators, special wing sections for wind turbines, theoretical analysis method of wind turbine performance, offshore wind turbines, and wind turbine control technologies are stated. (author)

  3. Manufacture of lightweight aggregates utilizing coal fly ash. Sekitan bai riyo ni yoru jinko keiryo kotsuzai seizo

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, K [Kyushu Electric Power Co. Inc., Fukuoka (Japan)

    1990-11-20

    Processing of a large amount of coal ash is a serious problem in considering the locational conditions of coal firing power generation plants. 46% of the coal ash was effectively used in 1985, and the remaining 54% was disposed at landfills on land and sea. Positive promotion of the effective use of coal ash is the necessity. A production method for an artificial lightweight aggregate utilizing coal ash was established by a joint research. The history of the research and development of this artificial lightweight aggregate (brand name: FA-lIGHT), outline of the manufacturing facilities, physical properties and result of use are introduced. The lightweight aggregates are used not only for the construction of multistoried buildings but also used as most suitable aggregates for making lightweight large scale panels and concrete secondary products such as lightweight blocks. FA-LIGHT is most suitable for use in the production of concrete lightweight aggregates, and can be used for hydroponic agriculture and for the improvement of drainage of land. Spread of its use is expected. 5 figs., 5 tabs.

  4. Development of materials of `bekko work` using horn; Gyukaku riyo ni yoru bekko daitai zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Mori, S.; Nagata, S. [Technology Center of Nagasaki, Nagasaki (Japan); Sakoguchi, A. [Kumamoto Institute of Technology, Kumamoto (Japan)

    1996-11-10

    The technical art `Bekko` is one of the traditional technologies in Japan, and the materials of `Bekko` are shells of hawksbills. However, the industry of `Bekko Work` has been facing a crisis recently, because the import of turtleshell is restricted. We have therefore tried to develop new materials as substitutes for the turtleshell by utilization of horn. The noteworthy aspects in this study are as follows: (a) It has been clearly established that the horn could be reformed with amber color similar to that of turtleshell by chemical treatment using hydrogen peroxide (H2O2). (b) It is also of interest that we produced new materials like `Bekko` by mixing horn powder and turtleshell powder at the appropriate ratio and molding them in the temperature range of 110-120{degree}C. 1 ref., 6 figs., 3 tabs.

  5. Research trend survey on the stable isotope utilization technology; Antei doitai no riyo gijutsu ni kansuru kenkyu doko chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report reviews the activities and the trends in the area of the stable isotope use attracting attention recently. In the medicine and clinical treatment sector, the remarkable trends are the extension of {sup 13}C use. The breath test and the magnetic resonance spectroscopy (MRS) diagnosis have been developed as inspection methods. It is noted that investigation has been initiated on the magnetic resonance imaging (MRI) using {sup 3}He and {sup 129}Xe for the lung imaging. In the organic chemistry and biochemistry sector, the stable isotopes are used for analyzing the structures of complicated natural compounds and materials relating to life science and for analyzing the chemical reaction mechanism of organic compounds. In the nuclear energy sector, {sup 10}B and {sup 7}Li have been used as neutron absorption materials and pH neutralizing reagent, respectively. In the analysis and measurement sector, the process of isotopic dilution is used for the environmental analysis of trace elements including harmful substances. Among various separation methods of isotopes, well studied uranium enrichment processes and deuterium separation processes are described. Separation of {sup 15}N by ion exchange resin method and plasma ion cyclotron resonance (ICR) isotope separation have been studied, recently. 133 refs., 53 figs., 7 tabs.

  6. `Power storage system` dealing with leveling of electric power use; Denryoku riyo no heijunka ni kotaeru `denryoku chozo system`

    Energy Technology Data Exchange (ETDEWEB)

    Igarashi, M. [Meidensha Corp., Tokyo (Japan)

    1996-06-28

    An overview is given on the development situation of a Zn-Br battery as a power storage system. The system is aimed at storing excess power at night and supplying the on-load demand during daytime. The power storage technology requires a large output and capacity of MWh level, long term stability and durability, and cost as low as pumped storage power generation. Four kinds of batteries have been examined to cope with the conditions, in which development of Zn-Br batteries along with Na-S batteries is in progress towards practicability. As a power conversion method for this system, GTO has been employed for a large capacity unit and IGBT for a medium/small capacity unit. The reliability of the Zn-Br batteries against leakage was improved by laminating each cell by hot plate welding. The service life was improved by using a material with a high bromine resistance in place of the conventional electrode constituent material. Although the battery efficiency was influenced by each resistance of electrode, film and electrolytic solution, distance between electrodes, temperature, etc., these correlations were clarified so as to establish the simulation technology. At present, the system realizes 50kW and 40kWh/m{sup 3}. 1 ref., 8 figs.

  7. Investigation on development of advanced materials by solvothermal technique; Sorubo thermal hanno riyo senshin zairyo kaihatsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Solvothermal reaction is reaction under high temperature and high pressure, which is expected to fabricate new functional materials. In this study, the materials are classified into two fields, i.e., inorganic materials, metals and their composites and organic materials and their composites. The current status of R and D of production and processing technology in each field is surveyed and the prospect of it is discussed. For the inorganic materials, metals and their composites, it is explained that very fine metal oxide particles, complex oxides, single crystals, whiskers, compounds with layer structure, metastable compounds, ion conductors and catalysts with high ability could be produced only by controlling the solvothermal reactions in atomic order. For the organic materials and their composites, surveyed results of the solvothermal technique using non-aqueous solutions are mainly provided. The necessity of a national project for researches on the solvothermal reactions is proposed from the viewpoint of resource, environment and energy. 777 refs., 38 figs., 26 tabs.

  8. FY 1999 report on the results of the project on the industrial science technology R and D. R and D of complex carbonhydrate production/utilization technology (Development of CO2 fixation/effective utilization technology by applying complex carbonhydrate); 1999 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo. Fukugo toushitsu seisan riyo gijutsu no kenkyu kaihatsu (Fukugo toushitsu oyo nisankatanso koteika yuko riyo gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of making an industrial use of complex carbonhydrate performing an important function in substance recognition, etc., which cannot be realized by only nucleic acid, protein and lipid, the R and D of the basic technology related to the production/utilization were conducted, and the FY 1999 results were reported. In the study of synthesis/utilization/remodeling technology of complex carbonhydrate using the chemical synthesis method, the R and D were made not only on the synthesis of sugar chain but for the synthesis method of the peptide added with sugar chain, that is, glycopeptide. Further, as to the reaction with the aim of the application, there was hope for large-quantity synthesis of milk oligosaccharide by the oxygen method. In the study of the design technology of complex carbonhydrate molecules, the systematical analysis using the model glycopeptide was conducted of effects of the sugar chain addition part and sugar chain structure on the 3D structure and physiological activity. Concerning the synthesis/utilization/remodeling technology of complex carbonhydrate using the biological method, study was made of the animal cell utilization, microorganism utilization, technology of structural analysis of complex carbonhydrate, etc. (NEDO)

  9. Report on a survey in fiscal 1999. Supplementary survey on research and development of carbon dioxide fixation and effective utilization technologies utilizing bacteria and algae (the survey on feasibility of bio-technologies to create economic effects, such as the biological CO2 fixation technology); 1999 nendo saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kenkyu kaihatsu futai chosa. Keizaiteki koka wo soshutsusuru seibutsuteki CO{sub 2} koteigijutsu nado no biotechnology no kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Bio-technologies including the biological CO2 fixation technology, or the green bio-technologies (GBT) are the technologies indispensable in realizing the change to a resource circulating and environment harmonizing society that accompanies economical growth, or in other words, the 'sustainable development'. In quantifying the feasibility of these technologies, the GBTs that contribute to creating Japan's international competitive power and employment were specified, and an approach to establish the realization target in 2010 was adopted, upon identifying the general condition of the related markets inside and outside the country. The GBT is the technology that makes the best use of Japan's independent strength created by combining the enzyme engineering and fermentation engineering with the 'genome science' (HEART). The targets are to substitute four million kiloliters of petroleum with a resource circulation type energy generated by the bio-technology; apply the bio-technology to about 30% of products and processes produced or used in Japan's chemical industries; and aim at creating markets by using environmental measurement and analysis, treatment of hard-to-decompose substances, and supports on tree planting as the three pillars. A simulation on return on investment in GBT business suggests the effect of promoting PFI. (NEDO)

  10. Report on the results of research and development under a consignment from NEDO of glycoconjugate production utilizing technologies. Development of technologies to fix and effectively utilize carbon dioxide by applying glycoconjugates; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Fukugo toshitsu seisan riyo gijutsu no kenkyu kaihatsu (fukugo toshitsu oyo nisanka tanso koteika yuko riyo gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper reports research results in fiscal 1997 for the `research and development of glycoconjugate production utilizing technologies`. In synthesizing, utilizing and remodeling technologies for glycoconjugates by means of chemical synthesis, studies were performed on developing methods to synthesize Gal {beta}1-3Gal NA(c {alpha})1-0-Serine in preparative scale, synthesizing high mannose type sugars of natural type without protection groups, and linking GlcNA or GalNAc onto partial peptide of fibroblast growth factor (FGF). In synthesizing, utilizing and remodeling technologies for glycoconjugates by using biological methods, studies were carried out, with regard to glycoconjugate synthesizing, utilizing and remodeling technologies utilizing animal cells, on identifying sugar structures of IFN-{gamma} produced from CHO cell line, and isolating CHO cell lines introduced with genes of sugar transferred enzyme GnTIV and/or GnTV. Furthermore, studies were conducted on glycoconjugate synthesizing, utilizing and remodeling technologies utilizing microorganisms, and glycoconjugate structure analyzing technologies. In addition, overall investigation was made on glycoconjugate production utilizing technologies. 113 refs., 76 figs., 18 tabs.

  11. Report on a survey in fiscal 1999. Supplementary survey on research and development of carbon dioxide fixation and effective utilization technologies utilizing bacteria and algae (the survey on feasibility of bio-technologies to create economic effects, such as the biological CO2 fixation technology); 1999 nendo saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kenkyu kaihatsu futai chosa. Keizaiteki koka wo soshutsusuru seibutsuteki CO{sub 2} koteigijutsu nado no biotechnology no kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Bio-technologies including the biological CO2 fixation technology, or the green bio-technologies (GBT) are the technologies indispensable in realizing the change to a resource circulating and environment harmonizing society that accompanies economical growth, or in other words, the 'sustainable development'. In quantifying the feasibility of these technologies, the GBTs that contribute to creating Japan's international competitive power and employment were specified, and an approach to establish the realization target in 2010 was adopted, upon identifying the general condition of the related markets inside and outside the country. The GBT is the technology that makes the best use of Japan's independent strength created by combining the enzyme engineering and fermentation engineering with the 'genome science' (HEART). The targets are to substitute four million kiloliters of petroleum with a resource circulation type energy generated by the bio-technology; apply the bio-technology to about 30% of products and processes produced or used in Japan's chemical industries; and aim at creating markets by using environmental measurement and analysis, treatment of hard-to-decompose substances, and supports on tree planting as the three pillars. A simulation on return on investment in GBT business suggests the effect of promoting PFI. (NEDO)

  12. Fiscal 1998 R and D project on global environmental industrial technology. Research result report on DNA analysis and information processing technology for photosynthesis microorganisms (Development of CO{sub 2} fixation and effective use technology by using bacteria and algae); 1998 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo. Kogosei biseibutsu nado DNA kaiseki joho shori gijutsu no kenkyu (saikin sorui nado riyo nisanka tanso koteika yuko riyo gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This report summarizes the fiscal 1998 research result on DNA analysis and information processing technology for photosynthesis microorganisms. On the study on DNA analysis technology by triple-strand formation method, as the comparison study result of a READ method, stable triple- strand formation method and hairpin method, a READ method showed the highest triple-strand formation efficiency for target DNA. On the study on accurate separation technology of specific genes, establishment of protocols was promoted for solid-phase probe technology, subtract technology and leveling technology. On the study on DNA microarray analysis technology by high-efficiency hybridization method, the analysis technology of genes by hybridization method using DNA chips is under investigation. In addition, the high- efficiency analysis technology of specific DNA segments by using an affinity sensor, and the high-accuracy cloning technology for DNA with altered primary structure were also studied. (NEDO)

  13. Investigation on the chemically fixing technique of carbon dioxide utilizing solar energy; Taiyo energy riyo ni yoru nisanka tanso no kagakuteki koteika gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    1993-03-01

    This report describes the results of effective fixing technique of CO2 by utilizing solar energy. First of all, the investigation was directed to the technique for synthesizing ethylene, hydrocarbons and alcohol by electrochemical reduction of CO2. The power required for this process is supplied by photovoltaic power generation. Development of excellent electrode catalyst is needed because the reduction of CO2 requires a high overvoltage. It is desirable to enhance the selectivity of the reaction for specific material and improve the transport process in the electrolytic cell. Next, designing of material and reaction of photocatalysts using semiconductor electrode and semiconductor particulate was examined. A semiconductor electrode made of FeS2 is inexpensive and has a high ability of collecting solar light. In the category of photocatalysis system, a photocatalytic system in which semiconductor particles are embedded in vesicle and a photpocatalyst based on potassium niobate are noteworthy. As biosystem, the method of reducing CO2 by calcareous algae which simultaneously advances fixing and calcification of CO2 by photosynthesis is noteworthy. 129 refs., 45 figs., 20 tabs.

  14. Some future projects in space activities. Centering around utilization of moon and satellite; Uchu kaihatsu no mirai koso ni tsuite. Tsuki/wakusei no riyo wo chushin ni

    Energy Technology Data Exchange (ETDEWEB)

    Saito, T [Obayashi Corp., Osaka (Japan); Kobayashi, H [Taisei Corp., Tokyo (Japan); Takagi, K [Shimizu Corp., Tokyo (Japan)

    1994-09-05

    Imagining a space in the middle of the 21st century, a space station installed with the artificial gravity generation facility is constructed, and a space factory utilizing a gravity free environment is also constructed. The construction materials for the space structures of this kind are prepared from the resources of the Luna. A solar power generation satellite being arranged with the solar cells manufactured from a silicon of the Luna is allocated on a geostationary orbit, and a power generated is supplied to the earth by the microwave. In such a time, a regular liner to the Luna and a ferry boat to the Mars will have come to fly, and furthermore an oxygen used for the propellant to them as well will be supplied from the Luna. In order to realize such a conception, there are various problems to be overcome such as a transportation problem first of all, a long life problem in the Luna and Mars bases and so forth. Furthermore a consideration to the environmental conservation of the Luna and Mars is also required. The nature of the Luna without a crustal alteration, meteorological phenomena, and organisms has no force to restore an environmental destruction. As for a space development in the future, it is desired that it should not damage a nature of the space and should be a field to chase a possibility of the human beings for a long time. 30 refs., 14 figs., 1 tab.

  15. Survey on a possibility of geothermal utilization in Tomakomai City; 1980 nendo Tomakomaishi ni okeru chinetsu riyo kanosei ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-11-01

    This paper describes a possibility of geothermal utilization in Tomakomai City. The Tomakomai area has an extremely great amount of hot water existing in deep layers, leading to a consideration that it is very highly possible to develop the hot water. As seen from the underground structure and ground temperature gradient in the Tomakomai sedimentary basin, the development depth would be considerably great, being assumed to be about 2,000 meters. The acquisition amount per well is estimated 100 m{sup 3}/hour or more at 65 degrees C. Rise in petroleum price in the future is an unavoidable fate, hence geothermal water utilization has a fully bright future. The water has relatively low temperature, and is effective for use in room heating, hot water supply, and agricultural and livestock industries. It is worth considering utilization as a local energy system. It has also large secondary effects. According to the latest trial calculation, the unit price for hot water for room heating and hot water supply would be 10 to 20 yen per 1,000 kilo-calories. If the same amount of hot water should be supplied from a boiler, fossil fuel of 20,470 kl/year would be required. If converted by using a kerosene price of 75 yen per liter, the cost would be 1.3 billion 35 million yen, comparatively higher than the geothermal water utilization. (NEDO)

  16. Stability analyses of urban water supply systems with wastewater reuse; Toshi haisui no junkan riyo ni yoru mizu kyokyu anteika ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, H.; Zhang, S. [Meijo Univ., Nagoya (Japan); Okada, N. [Kyoto Univ., Kyoto (Japan). Disaster Prevention Research Inst.

    1995-10-20

    Wastewater reuse can be considered as a type of water resource development which is expected to improve the aquatic environment, as well as the stability and reliability of municipal water supply systems. To this extent, wastewater reuse has been taken into account in the planning of water supply systems in several Japanese cities. However, to date the effect of wastewater reuse on water supply system stabilization has not been discussed quantitatively, and the relation between waster water reuse rate and water supply system stability has not been analyzed. In this study, a stochastic model has been presented to evaluate the stability of water supply systems with optimal wastewater reuse rate. Some theoretical analyses and numerical studies were performed, and all of the results have shown that the model is reliable for not only basic studies on water supply system stability, but also for practical use as well. 5 refs., 5 figs., 3 tabs.

  17. Fiscal 1996 report on the results of the R and D of technology of high-level treatment/effective use of domestic/industrial wastes, etc. (for public); 1996 nendo Shin Energy Sangyo gijutsu Sogo Kaihatsu Kiko itaku seikatsu sangyo haikibutsu shori yuko riyo gijutsu kenkyu kaihatsu seika hokokusho (kokaiyo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the purpose of reducing environmental loads of waste and effectively using resource by waste recycling, a study was conducted of high-level treatment/effective use technology for domestic/industrial wastes, etc. The paper reported the results of fiscal 1996. In the EcoCement producing technology using the synthetic urban type waste, EcoCement with stable quality was obtained using sewage sludge and industrial waste as raw materials. In the specified freon decomposition disposal technology, an experiment was carried out on durability, etc. of the processing unit. In the high speed/reduced smell biological garbage disposal technology, technology of fermenting disposal, etc. were established, and at the same time technology of making garbage compost was developed. In the technology to manufacture environment friendly type plastic containers, etc., a degradation behavior was grasped of degradable plastics in the compost. In the spread type waste plastic/thermal recycle technology, studied were a system to collect waste and a system to make waste solid fuel. Technology to recycle coolant freon was studied. 14 refs., 261 figs., 137 tabs.

  18. Commissioned operation report for fiscal 1992 on commissioning of surveying high-level development and effective utilization of natural gas, and development of coal hydrogasification technology; 1992 nendo tennen gas kodo kaihatsu yuko riyo chosa tou itaku gyomu hokokusho. Sekitan suiten gaska gijutsu kaihatsu chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    With an objective of establishing a practically usable process to manufacture substitution natural gas, discussions have been given on the technical, economical, and developmental problems therein. This paper summarizes the achievements in fiscal 1992. With respect to the possibility of applying the coal SNG to power generation fuel, a power generation system composed of coal SNG, pipeline transportation and natural gas was recognized of having the significance of technological development because of its capability of raising the power plant utilization rate and possibility of being superior in the economic aspect. In the study on enhancement of aqueous solution yield, performance of the ARCH-2 reactor was discussed by the simulation forecast using a mathematical model, whereas the benzene yield was found possible to be raised up to 15% in the carbon conversion rate. As the target of the hydrogasification process to be developed by Japan, based on the study results of the current fiscal year, three points consisted of SNG yield maximization, cooling gas efficiency maximization, and BTV yield maximization were indicated, and it was proposed that a process having flexibility in the product yield should be developed. (NEDO)

  19. Commissioned operation report for fiscal 1991 on commissioning of surveying high-level development and effective utilization of natural gas, and development of coal hydrogasification technology; 1991 nendo tennen gas kodo kaihatsu yuko riyo chosa tou itaku gyomu hokokusho. Sekitan suiten gaska gijutsu kaihatsu chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-03-01

    With an objective of establishing a practically usable process to manufacture substitution natural gas, discussions have been given on the technical, economical, and developmental problems therein. This paper summarizes the achievements in fiscal 1991. The summary of surveys in the current fiscal year is as follows: the coal hydrogasification process is positioned as having high necessity in the gas industry because of its high thermal efficiency and low gas cost; in order to evaluate the reaction heat in the hydrogasification reaction, a mathematical model having flexibility was structured, whereas a large number of findings has been derived, including performance of the reactor and the optimum operating conditions; in addition to having made clear the conditions for an entrained bed hydrogasification reactor, comparisons and discussions were given on the internally circulating reactor and one-through reactor; studies were performed on thermal efficiency and gas cost in the optimized process configuration o the ARCH-1 process base; and a proposal was made on the test for a new reactor having the two-step reaction zone that could be expected of increased yield in aqueous solution, and could contribute to reducing the gas cost. (NEDO)

  20. Fiscal 1999 achievement report on the venture business assisting type regional consortium - Minor business creation base type. Development of environmental protection oriented technology for effectively utilizing waste paper; 1999 nendo chiiki consortium kenkyu kaihatsu jigyo seika hokokusho. Kankyo hozengata no koshi no yuko riyo gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The effort aims to use low grade waste paper out of various grades of waste paper, whose recovery does not make good progress, as a raw material for the development of value-added, commercially competitive products and to contribute to the enhancement of waste paper recovery. A dry pulverization method less polluting the environment and not requiring a drying process is established, and types of waste paper and optimum conditions for their pulverization are made clear. A molding system using a steam injection method capable of atmospheric pressure control is established, and this enables the molding of pulverized waste paper not only into flat boards but also into corrugated boards. It is found that water contained in the waste paper alone produces a result similar to that expected from steam injection. A partitioning board is produced from waste paper, and it is found to be near the conventional product in terms of noise absorption. Old newspaper and corrugated cardboard are pulverized and an air filter is developed, which is similar to the conventional product in terms of operating efficiency and life. Waste paper is carbonized, and then charcoal with more pores than the conventional charcoal is produced. The porous charcoal is found to be usable in vegetable beds. (NEDO)

  1. FY 1999 report on the results of 'the model project for effective utilization of the waste heat discharged from the combustion of paper-manufacturing sludge'; 1999 nendo seika hokoku. Seishi surajji nensho hainetsu yuko riyo moderu jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of reducing the consumption of fossil fuel and reducing emissions of global warming gases in Malaysia, a model project for thermally effective use of the sludge discharged from paper-manufacturing plant was carried out. Concretely, the paper-manufacturing sludge discharged from paper-manufacturing plant is to be dewatered and improved of its lower heating value. Then, the sludge is to be burned in fluidized bed incinerator, and the steam is to be generated by recovering heat using waste heat recovering boiler. The steam obtained is to be used as process steam of the plant. In this fiscal year, the first year of the project, the attachment to the agreement was prepared in terms of the allotment of the project work between Japan and Malaysia, various kinds of gist, schedules, etc. and signed. After that, the determination of the basic specifications for facilities was made according to the attachment to the agreement. Now, the basic design of the whole plant is being made. The design of the process flow sheet, design of the layout plan for plant equipment, etc. were finished. The goods to be purchased are now being estimated and assessed. Moreover, as to the civil engineering/construction design, drawings of the basic design are now being made. (NEDO)

  2. FY 2000 report on the results of the R and D of the technology for rationalization of energy utilization and for CO2 fixation using recycled paper; 2000 nendo energy shiyo gorika koshi nado yuko riyo nisanka tanso koteika gijutsu kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In this R and D, the recycled paper, etc. composed mainly of cellulose are degraded (saccharified) up to saccharides in a biological method. The saccharides and CO2 obtained are converted into useful substances such as organic acid using the bacterium function. The aim of the R and D is to develop this conversion (bioconversion) technology and to establish the technology to make an effective use of the recycled paper, etc. as useful chemical raw materials/substances and energy. In FY 2000, study was made mostly of the saccharification and bioconversion. As to the saccharification, conducted were the collection of the bacteria for cellulose degrading enzyme production which have been found so far and the evaluation of degradation of the recycled paper. And, as to the bioconversion, conducted were the survey and isolation of enzyme proteins and genes which are concerned in it in the process toward the formation to organic acid from saccharides and CO2, and the analysis of part of them. In this report, introductory remarks were described in Chapter 1. In Chapter 2, the results were summarized of the study on saccharification of the recycled paper. In Chapter 3, the results were outlined of the study on the bioconversion technology. This technology development was aimed at establishing new high efficiency bio-processes. (NEDO)

  3. Fiscal 1994 report on results of R and D on innovative technology for producing advanced biomaterial. Technology of fixation and utilization of carbon dioxide using peptides; 1994 nendo senshin bio zairyo no sosei kako gijutsu no kenkyu kaihatsu seika hokokusho. Pepuchido oyo nisanka tanso koteika yuko riyo gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    R and D of a material was conducted that has a function of fixation of carbon dioxide for example, by synthesizing non-natural amino acids required for the manifestation of the function, incorporating the amino acids into new bio-functional peptides to be synthesized, and fixing the peptides on a substrate. Activities were carried out in three areas, which were (1) innovative technologies for producing functional molecules: R and D concerning structural and functional design of peptides, conformational control technique, preparation of peptides with photoelectric conversion function, peptide synthesis using enzyme, and method of incorporating non-natural amino acids into peptides, (2) R and D on materialization technologies of functional molecules: formation of film onto a substrate, pattern forming technique, substrate modification technique, peptide binding reagent or linker, and development of technologies for creation of biomaterials having molecular recognition function and their stabilization. and (3) comprehensive investigation and adjustment (operation of information exchange conference and adjustment of the progress). In (2), an examination was made on the effect of polymerization on functions, for example, by fixing molecular recognition peptides in monomers and polymers on a catalyst support. (NEDO)

  4. Fiscal 1993 report on results of R and D on innovative technology for producing advanced biomaterial. Peptide applied carbon dioxide fixation/effective utilization technology (First volume); 1993 nendo senshin bio zairyo no sosei kako gijutsu no kenkyu kaihatsu seika hokokusho. 1. Peptide oyo nisanka tanso koteika yuko riyo gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Technology is being developed for preparing functional materials by synthesizing new functional peptides in which non-natural amino acid needed for the functional manifestation is introduced, and by modifying the surface of a base plate such as silica glass by using such peptides. Activities were conducted in the three areas of (1) creation of functional molecules, (2) materialization technology, and (3) comprehensive investigation and research; the activities were carried out independently and parallelly in the first two areas. In (1), design technique for the structures and functions of peptides was developed, as were conformational control technique, synthesis of peptides having optical/electronic functions, peptide synthesis by an enzyme method, and R and D on introduction of non-natural amino acid into peptides; in (2), element technologies were developed such as substrate forming technique (pattern forming and thin film forming technology), substrate modification technique, development of reagent for binding peptide onto a substrate, and R and D on creation of biomaterials having molecular recognition function and its stabilization technique. In (3), progress control in promoting themes and a meeting for exchanging information were conducted, while survey on related element technologies was systematically and comprehensively carried out. (NEDO)

  5. Fiscal 1993 report on results of R and D on innovative technology for producing advanced biomaterial. Peptide applied carbon dioxide fixation/effective utilization technology (Second volume: comprehensive investigation and research); 1993 nendo senshin bio zairyo no sosei kako gijutsu no kenkyu kaihatsu seika hokokusho (sogo chosa kenkyu). 2. Peptide oyo nisanka tanso koteika yuko riyo gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Technology was developed for preparing functional materials by synthesizing new functional peptides in which non-natural amino acid needed for the functional manifestation was introduced, and by fixing the peptides to the surface of a base plate such as silica glass or modifying the surface with them. As the related technological investigation, the following six areas were surveyed. (1) Structural design of peptides, (2) synthesis of peptides by chemical and enzyme methods, (3) synthesis of non-natural amino acid and its introduction into peptides, (4) structural analysis of peptides, (5) physiological activity of peptides, and (6) materialization and functional manifestation of peptides. With the exception of the area (5) consisting of one advanced research case, other areas were constituted of analysis, general remarks and research cases. The area (6) was constituted of materialization technique 1 and 2, film function and peptide, catalytic action 1 and 2, and one research case; the materialization technique was defined as a technique for modifying the surface of a synthetic resin, metallic or silica glass substrate with functional peptides; and an explanation was given to the present state of the fixation, pattern formation and integration technologies. (NEDO)

  6. Report of FY 1997 on the international cooperation project. Survey of globalization of the effective energy resource utilization technology (development of high-accuracy acceleration measurement system); 1997 nendo kokusai kenkyu kyoryoku jigyo. Energy shigen yuko riyo gijutsu kenkyu kokusaika chosa (koseido kasokudo keisoku system no kaihatsu chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This report describes effectiveness of a system for measuring the acceleration and force in high accuracy by combining a laser interference meter and a vibration stand. A possibility of pressure sensitive paper to the impact force measurement in the collision examination is also described. The results obtained in FY 1997 are as follows. For the investigation of calibration system of acceleration and force sensor, one-dimensional interferometer system has been developed, which is standardized in ISO5347 accelerometer calibration. Thus, an interference fringe processing software has been made. Moreover, construction of a three-dimensional interferometer system has been started. For the characterization evaluation of pressure sensitive papers, it was succeeded in obtaining an elasticity wave pulse maximum about 1 msec by adopting the flight body made of resin. As a result, evaluation of the force sensor in the frequency area has become possible. To calculate the displacement of a body structural material in the collision experiment, an acceleration sensor has been made for trial purposes. For the international research cooperation, the working plan of a joint research with US Texas Christian University has been concluded. 11 refs., 73 figs., 23 tabs.

  7. Fiscal 2000 project of inviting proposals for international joint research - invitation for international proposal (Power generation No.4). Achievement report on effective utilization of waste heat energy; 2000 nendo kokusai kyodo kenkyu teian kobo jigyo - kokusai teian kobo (hatsuden No.4). Hainetsu energy no yuko riyo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Endeavors are exerted to develop a medium temperature thermoelectric module technology, which is one of energy/environment related technologies, in cooperation with Russia. The ultimate goal of this technology is to develop a hybrid power generation system which utilizes waste heat. Activities are conducted in three fields involving (1) the basic concept and design of thermoelectric power generation systems, (2) development of thermoelectric power generation systems, and (3) others, including the goal and self-evaluation. Summarized in field (2) are the overall activity plan, development of medium temperature thermoelectric power generation modules, development of cascade type hybrid modules, development of thermoelectric power generation systems, results of thermoelectric power generation system evaluation tests, and technical problems. Carried out for the development of thermoelectric power generation systems are the development of a medium temperature p-type thermoelectric power generation material Mn-Si, development of a method for synthesizing the Mn-Si material, and the development of a medium temperature n-type thermoelectric power generation material Co-Sb. Various methods are studied relative to the fabrication of electrodes, and the thermal spraying method is employed for a success in the development of a medium temperature thermoelectric power generation module of Mn-Si(p)/Co-Sb(n) for the first time in the world. (NEDO)

  8. Ni hombres ni mujeres providenciales

    OpenAIRE

    Montaño Virreira, Sonia

    2000-01-01

    Debo advertir a la y el lector de este texto que lo que a continuación se presenta no es, ni de lejos, una propuesta realista, si por ella entendemos la traducción, enclave mujer, de las actuales tendencias de liderazgo político vigentes en la región. Por el contrario, intento argumentaren favor de un liderazgo que supere el caudillismo como estilo y se aproxime al máximo hacia el respeto de las formas, entendiendo que sin ellas no es posible construir la democracia. Para hacerlo reviso rápid...

  9. Feasibility survey of the environmentally-friendly coal utilization system. Feasibility survey of the environmentally-friendly coal utilization system in the Philippines; Kankyo chowagata sekitan riyo system kanosei chosa. Philippines ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    With relation to the coal of the Philippines, where the expansion of the use of coal as a substitute for petroleum/plant fuel is aimed at, the paper grasped the situation of coal production/development, the trend of coal import and domestic distribution, the coal utilization trend, and environmental problems, and analyzed the situation of coal utilization/spread by industry including the commercial/residential use. The purpose of the survey is to draw up a master plan for the introduction of the environmentally-friendly coal utilization system. As to the use of environmentally-friendly coal technology which should be adopted to the coal mining industry and commercial/residential sector, cited are the introduction of coal preparation technology and power transmission technology, and the development/spread of briquette as a firewood substituting fuel. In the electric power sector, the problem is the treatment of ash after combustion and the effective use. Relating to the treatment of flue gas, there is no installation at all of desulfurization facilities and denitrification facilities. In the cement industry sector, they wish to return fuel from heavy oil to coal. For it, it is necessary to study dust preventive measures. In the other sectors, coal hasn`t been used very much. An increase in coal demand is not expected also in the future, and big problems concerning coal haven`t occurred. 42 figs., 64 tabs.

  10. Study on utilization of shallow sea areas by developing the alga field. Test for utilization of coal ash on alga reef (interim report); Sojo zosei ni yoru asakaiiki riyo no kenkyu. Sekitanbai kokabutsu no sosho riyo shiken (chukan hokoku)

    Energy Technology Data Exchange (ETDEWEB)

    Tsuno, M.; Oikawa, M. [Hokkaido Electric Power Co. Inc., Sapporo (Japan); Matsubara, T. [Hokkaido Area Management and Support Foundation, Sapporo (Japan)

    1996-03-25

    A development was intended of an alga reef block that is suitable for adherence of algae and difficult of shore-burning by utilizing coal ash. Concretes with different coal ash displacement rates were used to install alga reef blocks embedded with natural rocks, steel plates, and the used desulfurizing agents on three areas (the Usubetsu area, the Tamagawa offing, and Chatsu Bay) including shore-burned sea areas along the coast of Tomari Village. Investigations were made on the states of adherence of useful algae as a result of difference in materials and locations of installation. The best adherence of edible kelp was observed at the Usubetsu area, followed by the Tamagawa offing and Chatsu Bay in that order. Growth conditions of the kelp by locations were conceived of the correlation with how extensively the natural kelp colonies are formed around each location, and how many nutrient salts are present and sea urchins are grown. No remarkable difference was observed in the adherence of algae due to the difference in the coal ash displacement rates. Porous blocks, however, showed less adherence amount. Kelp adherence condition was found good in the order of concrete, natural rocks, and the used desulfurizing agents. No kelps have adhered on the steel plates. 10 refs., 13 figs., 3 tabs.

  11. Fiscal 1997 survey report. Feasibility study of the environmentally friendly type coal utilization system (survey of the coal utilization in Pakistan); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Pakistan ni okeru sekitan riyo gaikyo chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper made a literature survey, hearing survey, site survey/study on the coal in Pakistan such as the coal utilization system and the environmental situation, etc., and aimed at pre-examination for the survey of the introduction of the environmentally friendly type coal utilization system to be planned in Pakistan in the future. The examination, data collection and preparation were conducted in terms of the following items: the structure of coal consumption in energy supply, structure of coal consumption, mainly of domestic brown coal consumption, the situation of coal utilization by industry and by region, environmental problems caused by coal utilization such as air pollution, the trend of policies of environmental regulation, etc. The literature on the following was obtained and surveyed: the situation of economy/energy in Pakistan, coal utilization technology by industrial field, and environmental protection technology. The hearing survey was made to institutions concerned, corporation groups and men of learning and experience. Site surveys were conducted for the typically selected coal utilization equipment and existing environmental protection equipment. 66 figs., 56 tabs.

  12. Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Survey by region/industry in India; Kankyo chowagata sekitan riyo system kanosei chosa. Indo ni okeru sekitan riyo gaikyo chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    A survey was made in India which is a coal producing/consuming country following China in Asia and where coal is used for about 60% of the primary commercial energy. The survey was conducted on coal production/distribution/utilization and environmental issues, aiming at studying feasibility of introducing the environmentally friendly coal utilization system into every industry including the residential/commercial one, and at implementing a comprehensive master plan including Japan`s international cooperation. Total power source facilities in fiscal 1995 are 83.3 million kW, 64% of which are coal thermal power facilities and generated 260 TWh, 69% of the total output energy. Main commercial energy sources are coal, oil and natural gas, and oil is self-sufficient. The survey this time did not examine very well the actual state of the environmental pollution problem caused by the coal utilization. Indian coal is high in ash content but low in sulfur content, and therefore, SOx polluting air has not been a very important problem so far, but soot/smoke is almost the problem. Further, ash treatment after combustion at boilers, etc. is expected to be a big problem in the future. 49 figs., 88 tabs.

  13. Feasibility survey of the environmentally-friendly coal utilization system. Feasibility survey of the environmentally-friendly coal utilization system in Indonesia; Kankyo chowagata sekitan riyo system kanosei chosa. Indonesia ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    With relation to the coal of Indonesia, where the expansion of the use of coal as a substitute for petroleum/plant fuel is aimed at, the paper grasped the situation of coal production/distribution/utilization and environmental problems, and analyzed the situation of the coal utilization/spread by industry including the commercial/residential use. The purpose of the survey is to work out a comprehensive master plan including Japan`s international cooperation for introducing the environmentally-friendly coal utilization system to Indonesia. Coal utilization systems, the introduction of which Indonesia should study in future, were picked up, according to the surveys in fiscal 1993 and 1994. In commercial/residential and small-scale industry sectors, needed is improvement of carbonization technology for production of coal carbonization briquette. Moreover, the introduction of bio-briquette should be studied in the future. In the power generation sector, studies should be made on the introduction of technology for SOx/NOx reduction and technology for coal ash treatment including the effective use of coal ash. For the introduction of coal boilers, the combustion mixed with bagasse, which is abundant in amount, is also necessary. In the coal production sector, coal preparation technology is studied, and a method to select the optimum process was proposed through the simulation. 76 figs., 43 tabs.

  14. Research and development of system to utilize photovoltaic energy. Survey on system and peripheral technologies for utilization of photovoltaic power; Taiyoko hatsuden riyo system no kenkyu kaihatsu. Riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the survey results on systems and peripheral technologies for use of PV power in fiscal 1994. On the case study of PV communities, as housing zone PV community, Seibu Kitanodai housing estate mainly composed of detached houses, and the Suwa area of Tama New Town of apartment houses were selected to study PV power generation on a roof, wall and window. The result clarified that generated energy of a detached house reaches 3-4 times as much as consumed one, that of an apartment house is nearly equal to consumed one, and power generation of nearly 380MW is possible based on expected housing supply until 2000. As urban core zone PV community, the survey result on Ebisu Garden Place clarified that the expected PV power supply rate is 10% or more, 20% and 30% or more for hotel and office buildings, high-rise apartment building more than 30 stories, and medium-rise one of 10 and several stories, respectively. In Sakura industrial estate, the maximum generated power was nearly equal to consumed power in a weekday, and as inverse power flow in a holiday was considered, the annual PV power supply rate was extremely high.

  15. Aspiration toward geothermal energy utilization in regional development plan. Part 6. ; Hydrothermal fluid utilization business in Matsuo-mura of Iwate prefecture. Chiiki keikaku ni okeru 'chinetsu riyo' eno hofu. 6. ; Iwateken Matsuomura no chinetsu nessui riyo jigyo

    Energy Technology Data Exchange (ETDEWEB)

    Otobe, Y; Furutate, E

    1992-10-31

    Twenty six years have passed since the first geothermal power station was constructed in Matsuo-mura of Iwate Prefecture, Japan. This paper describes the history, the present situation and the future conception of the geothermal energy utilization in this village. This village includes Hachimantai of a vantage ground in the center and has the gross area of 233.8km[sup 2], the annual average temperature of 8.3 centigrade and the continuous snow cover period of about 100 days. The hot water leading facility was cooperatively constructed by Japan Metals and Chemicals, Hachimantai Hot Spring Development and Matsuo-mura. The total working expense is 539.3 million yen. Hot water sources are the condensate from the condenser of geothermal power plant and hot spring. This mixed hot water of 4.3 t/min is led to respective facilities. The hot water supplying channel has the length of 12.8km from the power station through the Hachimantai hot spring resort, Kamiyogi to Takaishino. Respective total areas of greenhouses using hydrothermal fluid in both districts are 1,075ha and the inlet temperature of hot water is 60 centigrade and kinds of crop are 5 like green pepper and others. Takaishino agricultural park has selected flower and ornamental plant culture such as poppy anemone, stock and statice which are suitable for this district of low temperature and insufficient sunshine. The planted area is 10,700m[sup 2]. 2 refs., 9 figs., 4 tabs.

  16. Conditioning of data for cyclic variation of IMEP under lean burn operation in a spark-ignition engine; Hibana tenka kikan no kihaku nensho untenji ni okeru zushi heikin yuko atsuryoku no hendo

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, K.; Urata, Y.; Yoshida, K.; Ono, t. [Honda Motor Co. Ltd., Tokyo (Japan)

    1997-07-25

    In this study, we investigated the relationship of indicated mean effective pressure (IMEP) for a spark ignition engine under lean combustion with the cyclic variation of mass fraction burned by measuring the energy release from the spark plug, intensity of the light emission from the flame and the cylinder pressure at the same time. In order to minimized an error in the initial and late combustion sages of the mass fraction burned to be obtained by cylinder pressure, spark plug energy and intensity of light emission were measured. As a result, it was found that there are three main causes of cyclic variation of IMEP. These consist of the burning speed during the initial stage of combustion, variation in the total mass fraction burned, and variation of the late burning during the late expansion stroke. Thus, we determined that there is a favorable interrelationship between the IMEPs and the corrected mass fraction burned. 13 refs., 9 figs., 1 tab.

  17. Development of hydroponic system using agricultural waste. 2. Utilization of ozone for sterilization of nutrient solution; Suiko saibai ni okeru haikibutsu riyo gijutsu no kaihatsu. 2. Ozone ni yoru baiyoeki sakkin ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Terazoe, H; Yoshihara, T; Nakaya, K [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1995-08-01

    Discussions were given on a sterilizing effect of ozone on Fusarium bacteria in hydroponic culture, and its effect on components in the culture solution. In an experiment, dry air with O3 concentration of 3.5 ppm was sent into aqueous solution inoculated with Fusarium bacteria at a flow rate of 5 liters per minute. The Fusarium bacteria was sterilized nearly completely in about five minutes. No change was observed in pH, EC and dissolved oxygen concentration of the O3-treated culture solution. However, iron and manganese among the soluble components have been oxidized by O3 and precipitated, hence these components must be added after the O3 treatment. In spinach culture performed on a culture medium inoculated with Fusarium bacteria, ozone water containing dissolved O3 at 0.8 ppm was flown into a urethane foam medium and vegetable roots. This treatment has resulted in reduction of the number of strains occurred with a wilt symptom below that in the section flown with distilled water. The spinach has grown normally without showing an effect of the ozone water. 15 refs., 10 figs., 3 tabs.

  18. FY1998 research report on the basic research on geothermal district heating in Kamchatka, Russia; 1998 nendo Roshia Renpo Kamchatka shu ni okeru chinetsu riyo ni yoru chiiki danbo ni kansuru kiso chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-05-01

    Petropavlovsk-Kamchatky (P-K) city in Kamchatka, Russia is operating hot-water district heating using heavy oil boilers and waste hot water of thermal power plants as heat sources. Feasibility study was made on district heating using natural geothermal hot water and/or geothermal heat pump systems as heat sources of hot water supply for reduction of greenhouse effect gas emission. Among 3 areas including geothermal hot water, use of hot water in K area was impossible because of lower temperature and less spring water. Use of hot water in P and UP areas was impossible as primary hot water because of temperature drop to 64 degrees C during hot water supply toward P-K city. The building heating operation test was carried out using the geothermal heat pump system installed in a newly drilled heat exchange well of 100m deep. As a result, sufficient heat recovery was achieved for heating. If all of 49 boiler houses for heating are replaced with such geothermal heat pump systems, CO{sub 2} reduction was estimated to be 520,000t/y. (NEDO)

  19. Wind energy technology : from the past to the future; 20 seiki ni okeru furyoku riyo gijutsu no henkan. Furyoku hatsuden : kako kara mirai e

    Energy Technology Data Exchange (ETDEWEB)

    Ushiyama, I. [Ashikaga Institute of Technology, Tochigi (Japan)

    2000-01-20

    Windmills are one of the oldest prime movers and have been used for more than 700 years in Europe. The transition from low speed windmills for grain grinding and water pumping to high speed wind turbines for electric power generation had occurred at first, reviews the windmill technologies and the researchers before 20{sup th} century. Then describes the back ground of how the wind power generator has existed and how the four pioneers developed their wind power generator. The historical developments of windmills to wind turbines in this century are studied focusing mainly on Danish activities. Then, the effort of the development of large wind turbine such as Smith-Putnum's first MW machine in U.S.A. and other mammoth machine concept are introduced. The new concept machines such as Savonius and Darrieus wind turbines in 1920s to 1930s are also explained. Finally, the novel technologies of wind turbine covering larger machines, variable speed generators, special wing sections for wind turbines, theoretical analysis method of wind turbine performance, offshore wind turbines, and wind turbine control technologies are stated. (author)

  20. Research report for fiscal 1998. Study of utilization of biomass including foods in energy industry; 1998 nendo shokubutsu nado no biomass no energy riyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Rice being produced as food is taken up out of various types of biomass, and a feasibility study from the viewpoints of technology and economy is conducted as to its use in the energy industry. The production of ethanol from rice, though it has no past record worth discussion, is similar to the production of ethanol from other biomass resources in terms of technology and economy. The problem is that the production cost of rice is far higher than those of other materials. It is expected, however, that there will a large-scale production cost reduction and an increase in the yield when novel cultivation techniques are introduced in the future. It is also expected that alcohol from rice will be sufficiently competitive with alcohol from molasses or the like when the exploitation of cellulose-family by-products such as husks becomes feasible. The study on this occasion deals solely with the effective use of farmland and the surplus rice. A confrontation between rice as a biomass resource and rice as a food has to be avoided as much as possible in the long term because it may cause a price rise and compromise the security of food supply. That is, in discussing this matter, it is mandatory to draw a very definite line between rice as a food and rice as an alcohol production material. (NEDO)

  1. Forward prediction of tunnel face by use of equi-traveltime planes; Tosojimen no riyo ni yoru tunnel kiriha zenpo tansa

    Energy Technology Data Exchange (ETDEWEB)

    Ashida, Y [Kyoto University, Kyoto (Japan). Faculty of Engineering; Hirano, T [Nishimatsu Construction Co. Ltd., Tokyo (Japan)

    1996-05-01

    The result is reported herein of a depth transform algorithm application utilizing equi-traveltime planes in reflection seismic exploration for the purpose of knowing the structure configuration in front of the tunnel face in a tunnel excavation process. A vibration producing hole was provided 0.5m above the ground surface while a vibration receiving hole was provided at 1.5m above the ground surface, and the excavated lengths were 1.5m and 0.5m, respectively. There were 24 recording channels, from which inline offset records were taken. The on-site records were subjected to 100-1000Hz band pass filtering. The elastic wave propagation rate in the rock used for depth conversion was set at 400m/s in consideration of the distance and direct wave travel time from the vibration source to the vibration receiving point. As the result of study, weak layers were found in the neighborhood of 230-240m, 260-270m, and 280-290m. This method requires less core memory for calculation and completes calculation in a shorter period of time, which enables a conclusion that it will be effective in grasping the 3-dimensional structure in front of the tunnel face in the working scene. 4 refs., 7 figs.

  2. Studies on the utilization of inedible parts produced at processing the marine products. Part 1; Suisan haikibutsu no kodo riyo ni kansuru kenkyu. 1

    Energy Technology Data Exchange (ETDEWEB)

    Kitamura, S.; Nomura, A.; Quinones, H. [Industrial Technology Center of Kochi Prefecture, Kochi (Japan)

    1995-09-01

    For the purpose of effectively using marine products in Kochi pref., analyses were made of the components of the following marine products: the head and inside of frigate mackerel disposed of at the time of producing dried frigate mackerel (an annual catch of the frigate mackerel is about 12000-15000 tons, almost half of which is used for processing for dried bonito), the head and other part of lobster disposed of at lobster restaurants (including the shell of lobster), the skin of lazard fish disposed of in boiled fish paste producing plants. The analysis was conducted in terms of the composition of coarse fatty and fatty acid, free amino acid, ATP related compounds, etc. As a result, the following were found out: in the fat of the head and inside of frigate mackerel, DHA (docosahexaenoic acid) and EPA (eicosapentaenoic acid) were included by 20-30% and 10%, respectively, and the fat is promising as supply source of high-grade unsaturated fatty acid; in the head and other part of lobster, chitin chitosan is included in addition to free amino acid such as glycine and alanine; in the skin of lazard fish, ATP related compounds such as inosinic acid are included, and the skin is useful for a raw material of the seasoning. 15 refs., 4 figs., 6 tabs.

  3. Evaluation report on research and development of 'seawater purification and byproduct utilization'; 'Kaisui Tansuika to fukusanbutsu riyo' no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1978-03-01

    Research, development, and evaluation were made on seawater purification for the purpose of supplying inexpensive city water stably in the future. In the research of the high flow rate long-tube type multi-stage flash process, basic characteristics were identified by studying fluidity, heat transfer, deaeration, and decarburization by using a test plant with a capacity of 3,000 m{sup 3}/d. A number of findings were derived in carrying out demonstration studies by using a test module with a capacity of 100,000 m{sup 3}/d. Research on heat transfer pipe materials covered a wide area including copper alloys, titanium and aluminum alloys, and ferrous materials, where a prospect was obtained on materials which may be practically usable in the future as transfer pipes in large seawater purifying equipment. Research on a concrete evaporator body proved that it is more economical than steel evaporators, and has sufficient corrosion resistance even against high-temperature brine. Other activities included researches on effects of contaminated seawater, brine diffusion, byproduct utilization, and total systems. Social and economic evaluations were also performed. (NEDO)

  4. Studies on substitutional protein sources for fish meal in the diet of Japanese flounder; Hirame shiryo ni okeru miriyo shigen no riyo

    Energy Technology Data Exchange (ETDEWEB)

    Kikuchi, K; Furuta, T; Sakaguchi, I [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1996-08-01

    Effectiveness of livestock industry wastes and vegetable protein added to fish meal in fish farming is tested by feeding the Japanese flounder. In the experiment, a part or the whole of the fish meal protein is replaced by the meat meal (MM), meat and bone meal (MBM), corngluten meal (CGM), or dried silkworm pupa meal (SPM), and fries of the Japanese flounder are fed on the new diets for eight weeks. On a diet containing 60% or less of MM, no change is detected in the fish in terms of increase in weight, protein efficiency ratio, and blood components, indicating that 60% at the highest of fish meal may be replaced by MM. In the case of MBM, it can occupy approximately 20%. As for CGM, the proper substitution rate is approximately 40%. Essential amino acids that the new diets may lack are added for an approximately 10% improvement on the result. The SPM substitution works up to 40%, when, however, the blood components are degraded. The proper substitution rate is therefore placed at approximately 20%. 38 refs., 2 figs., 17 tabs.

  5. Report on evaluation of research and development of resources recycling/reutilization systems. Phase 2; Shigen saisei riyo gijutsu system no kenkyu kaihatsu (dainiki) ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1983-08-01

    Described herein are the final evaluation results obtained by the 7-year R and D project, beginning in the FY 1976, established by the national project system for developing the techniques for treating urban solid wastes. This project has developed a semi-wet type selective crushing/sorting unit for sorting the wastes, and established the elementary techniques for recycling the wastes into various products, e.g., compost, pulp, combustible gases, aggregates, methane gas, or fuel oil. Two types of total treating systems, in which these elementary techniques are integrated, have been developed; one is to recover materials and the other energy. They can comprehensively, efficiently treat the wastes, adapting themselves to various situations. Pyrolysis which discharges reduced quantities of flue gases is adopted. Waste water is treated, mainly by biological treatment which is supported by the conventional methods, e.g., coagulation and adsorption. The cost estimation results indicate that the total system developed by this project can compare favorably with the conventional incineration system under general conditions, at a capacity of 300 t/d or more, when taking into consideration the secondary effects brought by the recycling/reutilization. This system is commercially feasible, when it meets with local characteristics, e.g., garbage collecting systems, market values of recycled resources, treatment/disposal conditions, and natural and social environments. This project has sufficiently achieved the original objectives. (NEDO)

  6. Evaluation report on research and development of 'the comprehensive water recycling and utilization systems'; 'Mizu sogo saisei riyo system' no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-08-01

    This research and development project is aimed at treatment of sewage, industrial waste water and the like at lower cost for reutilization, while efficiently producing methane or the like by the systems annexed to the water treatment systems with high-concentration bio-reactor systems incorporating separation membranes. The waste water types studied to be treated by these systems include sewage discharged in large quantities and waste water containing oil/fat and protein (low-concentration waste water), and starch-, alcohol and paper/pulp-containing waste water, and excrements (medium-concentration waste water). The project has found the optimum systems, by adequately configuring the separation membrane modules, and combining dissolution of suspended solid with methane fermentation reactors for selective treatment of organic substances; improved efficiencies of removing organic substances and producing methane by fermentation, and realized reduction in quantities of discharged sludge; and thereby established the bases for the new waste water treatment techniques. The reactor systems developed for water treatment are those based on biological removal of nitrogen. They greatly reduce treatment time to produce treated water of high quality. For treatment of sludge, the techniques have been developed to convert sludge into oil. These results are well applicable to various areas, e.g., sewage treatment, and food and pulp industries. (NEDO)

  7. Development of melting system using oxy-coal combustion; Sekitan chokusetsu riyo kinzoku yoyu system gijutsu (NSR) (pilot setsubi unten jokyo ni tsuite)

    Energy Technology Data Exchange (ETDEWEB)

    Sugiyama, T [Center for Coal Utilization, Japan, Tokyo (Japan); Suwa, T; Kobayashi, N; Iino, K; Yamamoto, Y; Igarashi, H [Nippon Sanso K.K., Tokyo (Japan)

    1996-09-01

    This metal melting system is a process to efficiently melt and regenerate scraps of aluminum, copper and iron by utilizing high-temperature energy obtained from pulverized coal-oxygen combustion. The process is intended to utilize coal in place of petroleum for reduced fuel cost. Joint studies have been carried out as a subsidy operation of the Agency of Natural Resources and Energy with a schedule of six years starting fiscal 1992. Development tests are being performed using a 5-ton/ch pilot plant facility since fiscal 1995 after having gone through experiments using a 1-ton/ch bench scale furnace. This paper reports the results obtained to date. Using the pilot plant facility, fiscal 1995 has achieved the initial target values, such as thermal efficiency of 55% or higher, and yield of 96% or higher for non-ferrous metals and 94% or higher for iron. The melting behavior in the furnace has improved the thermal efficiency as a whole by retaining the conditions in the preheating step for an extended period of time. The thermal efficiency has been improved better than with the bench furnace as a result of upscaling effect. 9 figs., 3 tabs.

  8. Report on a feasibility survey of the cold accumulated heat use energy system in Hokkaido; Hokkaido ni okeru reichikunetsu riyo energy system no kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A survey was conducted of various systems which use in summer cold heat from the snow stored in winter. A model of the cold accumulated heat system of the type which has a high possibility of the introduction was built to study a possibility of the realization. Types of the model system were selected assuming the utilization of cold heat energy of snow in Sapporo, a typical large city in the cold heavy-snow area. Studies were made on each model of urban type commercial facilities, urban type offices, suburban type shopping center, and suburban type hospitals. For each model, more than one systems were studied according to types and forms of the storage tank, and heat recovery methods. As a result, it was found that cold heat energy of snow can be utilized almost effectively by making an appropriate study of the energy balance like the possible supply of cold heat exceeded the demand in two models of an urban type office building and an suburban type hospital. Further, operating expenses of typical models were roughly calculated. 51 figs., 20 figs.

  9. Research and development of system to utilize photovoltaic energy. Survey on the specific purpose modules; Taiyoko hatsuden riyo system no kenkyu kaihatsu. Taiyoto module ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the survey results on the specific purpose modules for photovoltaic power generation in fiscal 1994. (1) On the feasibility survey on new application fields, it was clarified that photovoltaic power generation is applicable to extensive areas such as farmland, road, railway and public facility as latent demand sites. (2) On the optimum modules for various specific purposes, the structure, production method, cost estimation and issues of various modules were studied for desert, wasteland, coast, ocean, river, embankment, railway, road, mobile facility and arcade. (3) On the survey on new materials and material development, various conventional materials and materials promising for required performance were surveyed for every application. (4) On the survey on technology trends, the survey members participated in the first international photovoltaic energy conversion conference and the photovoltaic power generation workshop, while the members held the 1st-5th specific purpose module subcommittees. 1 tab.

  10. Study on the detached house plan using of a maximum natural energy. Part 1; Shizen energy fukugo riyo no keikaku ni kansuru kenkyu. 1

    Energy Technology Data Exchange (ETDEWEB)

    Wada, I; Mino, M; Miyata, T; Okawa, M [Nihon University, Tokyo (Japan)

    1996-10-27

    The geographical position or environment is set on the assumption that the natural energy of a detached house is used in a hybrid state. Moreover, the energy consumption of the house and the natural energy supply obtained from the geographical position were compared and investigated. As a result, the energy consumption is 10,617 kWh, and the energy supply is 8,236 kWh. About 78% of the whole consumption can be theoretically made from natural energy. The energy supply is calculated on the low side during prediction. Therefore, an increase in the energy supply is expected by installing a solar collector based on solar energy, expanding the solar panel area, and increasing the number of wind mills. However, this energy is partially lost via an inverter while it is supplied to the general domestic equipment. At the six main points in Tokyo and its districts, the adaptability of natural energy used based on the regional characteristics is investigated presently and the installation of a system is examined. 13 refs., 2 figs., 6 tabs.

  11. Performance analysis on utilization of sky radiation cooling energy for space cooling. Part 2; Hosha reikyaku riyo reibo system ni kansuru kenkyu. 2

    Energy Technology Data Exchange (ETDEWEB)

    Marushima, S; Saito, T [Tohoku University, Sendai (Japan)

    1996-10-27

    Studies have been made about a heat accumulation tank type cooling system making use of radiation cooling that is a kind of natural energy. The daily operating cycle of the cooling system is described below. A heat pump air conditioner performs cooling during the daytime and the exhaust heat is stored in a latent heat accumulation tank; the heat is then used for the bath and tapwater in the evening; at night radiation cooling is utilized to remove the heat remnant in the tank for the solidification of the phase change material (PCM); the solidified PCM serves as the cold heat source for the heat pump air conditioner to perform cooling. The new system decelerates urban area warming because it emits the cooler-generated waste heat not into the atmosphere but into space taking advantage of radiation cooling. Again, the cooler-generated waste heat may be utilized for energy saving and power levelling. For the examination of nighttime radiation cooling characteristics, CaCl2-5H2O and Na2HPO4-12H2O were tested as the PCM. Water was used as the heating medium. In the case of a PCM high in latent heat capacity, some work has to be done for insuring sufficient heat exchange for it by, for instance, rendering the flow rate low. The coefficient of performance of the system discussed here is three times higher than that of the air-cooled type heat pump system. 8 refs., 5 figs., 4 tabs.

  12. Evaluation of the performance in the solar assisted heat pump system; Taiyonetsu riyo heat pump system no seino hyoka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Saito, Y [Osaka Institute of Technology, Osaka (Japan)

    1996-10-27

    Performance of a solar heating system with a hydrothermal source heat pump was evaluated and compared with that of a direct solar heating system. The sun-dependency rates ({Sigma}D and {Sigma}H)of the direct system and heat pump (HP)-provided system were expressed as a function of the rate ({alpha}) of the auxiliary heat against the collected heat and as a function of the performance coefficient and {alpha}, respectively. When the sun-dependency rates are compared, it is found that the HP-provided system is the more advantageous when {Sigma}H/{Sigma}D>1. The relationship between the {alpha}`s of the two systems was clarified and computation was performed to compare the sun-dependency rates on condition that the two are equal in the heat collecting area. Although the sun-dependence rate cannot be elevated to 100% in the HP-provided system, it achieves a sun-dependency rate higher than that of the direct system even when the heat collecting area is small. In cases where the building is economically limited, for instance, with respect to the area for solar collector installation, it is advantageous to employ the HP-provided system. 5 figs., 1 tab.

  13. Decay of 57Ni

    International Nuclear Information System (INIS)

    Santos Scardino, A.M. dos.

    1987-01-01

    The decay of 57 Ni to 57 Co was studied by gamma ray spectroscopy using both singles and coincidence spectra. The sources were obtained with the 58 Ni (Y,n) 57 Ni reaction. Natural metallic nickel was irradiated in the bremsstrahluhng beam of the linear accelerator of the Instituto de Fisica da Universidade de Sao Paulo with 30 MeV electrons. The singles espectra were taken with 104 cc HPGe detector and the coincidences espectra with 27 and 53cc Ge(Li) and 104 cc. HPGe detectors. The energies of transitions that follow the 57 Ni decay were measured using 56 Co as standard (which was obtained by (Y,np) reaction in 58 Ni) and taking into account the cascade cross-over relations. (author) [pt

  14. Bridging exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi-Montes, Natalia, E-mail: nataliarin@gmail.com [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain); Gorria, Pedro [Departamento de Física & IUTA, EPI, Universidad de Oviedo, E-33203 Gijón (Spain); Martínez-Blanco, David [Servicios Científico-Técnicos, Universidad de Oviedo, E-33006 Oviedo (Spain); Fuertes, Antonio B. [Instituto Nacional del Carbón, CSIC, E-33080 Oviedo (Spain); Fernández Barquín, Luis [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, E-39005 Santander (Spain); Puente-Orench, Inés [Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza and Institut Laue-Langevin, BP 156, F-38042 Grenoble Cedex 9 (France); Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain)

    2016-02-15

    Among all bi-magnetic core(transition metal)@shell(transition metal oxide) nanoparticles (NPs), Ni@NiO ones show an onset temperature for the exchange bias (EB) effect far below the Néel temperature of bulk antiferromagnetic NiO. In this framework, the role played by the magnetism of NiO at the nanoscale is investigated by comparing the microstructure and magnetic properties of NiO and Ni@NiO NPs. With the aim of bridging the two systems, the diameter of the NiO NPs (~4 nm) is chosen to be comparable to the shell thickness of Ni@NiO ones (~2 nm). The EB effect in Ni@NiO NPs is attributed to the exchange coupling between the core and the shell, with an interfacial exchange energy of ΔE~0.06 erg cm{sup −2}, thus comparable to previous reports on Ni/NiO interfaces both in thin film and NP morphologies. In contrast, the EB detected in NiO NPs is explained in a picture where uncompensated spins located on a magnetically disordered surface shell are exchange coupled to the antiferromagnetic core. In all the studied NPs, the variation of the EB field as a function of temperature is described according to a negative exponential law with a similar decay constant, yielding a vanishing EB effect around T~40–50 K. In addition, the onset temperature for the EB effect in both NiO and Ni@NiO NPs seems to follow a universal dependence with the NiO crystallite size. - Highlights: • Comparison of the exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles. • Universal temperature dependence of the exchange bias effect. • Suggested similar physical origin of the effect in both systems. • Size and crystallinity of the NiO shell hold the key for exchange bias properties.

  15. OpenNI cookbook

    CERN Document Server

    Falahati, Soroush

    2013-01-01

    This is a Cookbook with plenty of practical recipes enriched with explained code and relevant screenshots to ease your learning curve. If you are a beginner or a professional in NIUI and want to write serious applications or games, then this book is for you. Even OpenNI 1 and OpenNI 1.x programmers who want to move to new versions of OpenNI can use this book as a starting point. This book uses C++ as the primary language but there are some examples in C# and Java too, so you need to have about a basic working knowledge of C or C++ for most cases.

  16. FY 2000 report on the results of development of technology for commercializing high-efficiency fuel cell systems. Development of technology for commercializing high-efficiency fuel cell systems (Development of technology for effective utilization of power produced by polymer electrolyte fuel cell systems); 2000 nendo kokoritsu nenryo denchi system jitsuyoka gijutsu kaihatsu seika hokokusho. Kotai kobunshigata nenryo denchi no shutsuryoku yuko riyo gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This project is aimed at development of technologies for effective utilization of power produced by polymer electrolyte fuel cell (PEFC) systems and waste heat, to spread cogeneration systems incorporating PEFC systems for residential purposes. Described herein are the FY 2000 results. The program for high-efficiency peripherals for residential PFEC systems attempts use of GaN-FET as the semiconductor device of wide band gap and high breakdown voltage to realize conversion efficiency over 90% by improving inverter efficiency. Two types of the prototype heat recovery systems are developed for the PEFC, one incorporating a latent heat cooling system and the other a water cooling system, to improve heat recovery efficiency and increase heat recovery temperature. The program for technology to fit PEFC output to energy demand develops hot water supply systems provided with a hot water storage function for stable supply of hot water irrespective of the heat recovery conditions, and also with a back-up function with burners. The program also develops the PEFC system of fine load following characteristics, for which pure hydrogen is used as the fuel to allow the system to instantaneously follow fluctuating loads. The program for high-efficiency partial load operation technology studies a 1kW-class residential PEFC cogeneration system incorporating a power storage device for high-efficiency operation at partial loads, where the former operates in a high output mode while the latter absorbs fluctuating loads. (NEDO)

  17. FY 2000 report on the results of the project for measures for rationalization of the international energy utilization - the model project for the heightening of efficiency of the international energy consumption. 1/2. Model project for facilities for effective utilization of by-producing exhaust gases from chemical plant, etc.; 2000 nendo kokusai energy shohi koritsuka tou moderu jigyo seika hokokusho. Kagaku kojo fukusei haigasu tou yuko riyo setsubi moderu jigyo (1/2)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of contributing to the reduction in the energy consumption in China and the stable energy supply in Japan by heightening efficiency of the energy utilization in the petrochemical industry which is an industry of much energy consumption in China, a model project for facilities for effective utilization of by-producing gases from chemical plant, etc. was carried out, and the FY 2000 results were reported. Concretely, the combustion incinerator and combustion exhaust gas recovery facilities for waste water and gas were to be installed at acrylonitrile plant of petrochemical plant in China to recover the combustion exhaust gas as process gas used in plant for effective utilization. The plant at installation site has been run since 1995, having a production capacity of 50,000-60,000 tons. In this fiscal year, the detailed design and supply of electric instrumentation equipment and manufacture of boiler facilities were carried out according to the basic design made in the previous fiscal year. Further, the equipment manufactured in the previous year and this fiscal year were transported and inspected. The paper also reviewed drawings of the design of the facilities for part of which China takes responsibility. (NEDO)

  18. FY 2000 report on the results of the project for measures for rationalization of the international energy utilization - the model project for the heightening of efficiency of the international energy consumption. 2/2. Model project for facilities for effective utilization of by-producing exhaust gases from chemical plant, etc.; 2000 nendo kokusai energy shohi koritsuka tou moderu jigyo seika hokokusho. Kagaku kojo fukusei haigasu tou yuko riyo setsubi moderu jigyo (2/2)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of contributing to the reduction in the energy consumption in China and the stable energy supply in Japan by heightening efficiency of the energy utilization in the petrochemical industry which is an industry of much energy consumption in China, a model project for facilities for effective utilization of by-producing gases from chemical plant, etc. was carried out, and the FY 2000 results were reported. Concretely, the combustion incinerator and combustion exhaust gas recovery facilities for waste water and gas were to be installed at acrylonitrile plant of petrochemical plant in China to recover the combustion exhaust gas as process gas used in plant for effective utilization. In this fiscal year, the detailed design and supply of electric instrumentation equipment and manufacture of boiler facilities were carried out according to the basic design made in the previous fiscal year. Further, the equipment manufactured in the previous year and this fiscal year were transported and inspected. The paper also reviewed drawings of the design of the facilities for part of which China takes responsibility. The separate volume (2/2) included drawings of valve, fire detector, orifice, thermocouple, motor control equipment, etc. (NEDO)

  19. Achievement report of projects in fiscal 2000 for measures on technologies to fix and utilize effectively carbon dioxide. Development of program system technologies to fix and utilize effectively carbon dioxide - researches on key technologies (Developing technology to fix carbon dioxide electrochemically); 2000 nendo program hoshiki nisanka tanso koteika yuko riyo gijutsu kaihatsu (kiban gijutsu kenkyu) seika hokokusho (kokaiyo). Nisanka tanso no denki kagakuteki koteika gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With an objective to prevent global warming, research and development has been made on a carbon dioxide fixation technology using electrochemical means. This paper summarizes the achievements in fiscal 2000. In the research of a technology to return carbon dioxide to hydrocarbon such as methane electrochemically utilizing the high concentration carbon dioxide-methanol system, basic studies were performed on electrolytic reduction of CO2 using a methanol solvent system, and experimental studies were executed on high-speed reduction of carbon dioxide using gas diffusion electrodes. In the basic property experiment on diamond electrodes, high carbon dioxide reduction activity was obtained by having copper carried in the diamond electrode. In the CO2 electrolytic reduction experiment on three-phase interface using a copper net electrode, CO, ethylene, and methane were produced, while the electrode has retained the activity for an extended period of time, and the CO2 conversion rate reached about 66%. In structuring an electrochemical carbon dioxide fixation system, specifications for the CO2 electrolytic reduction equipment were determined, design, manufacturing, and electrode materials were selected, supporting electrolytes were discussed, and the entire system flow and liquid resistance were discussed. (NEDO)

  20. Fiscal 1996 international research cooperation project. Feasibility study of finding out the seeds of international joint research (technology for effective use of saturated hydrocarbon, technology for reducing excess of aromatic hydrocarbon, high-grade treatment technology of petroleum coke); 1996 nendo kokusai kenkyu kyoryoku jigyo. Kokusai kyodo kenkyu seeds hakkutsu no tame no FS chosa (howa tanka suiso no yuko riyo gijutsu, hokozoku tanka suiso no yojo taisaku gijutsu, sekiyu cokes no kodo shori gijutsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This project is aimed at internationally cooperating in the R and D of industrial technology and improving industrial technology of Japan. For it, the following three technologies were investigated: (1) technology for effective use of saturated hydrocarbon, (2) technology for reducing excess of aromatic hydrocarbon, (3) high-grade treatment technology of petroleum coke. In (1), surveys were conducted of technologies of effective use of natural gas and effective use of C4 saturated hydrocarbon. Surveyed were a method for producing synthesis gas from natural gas, a technology to liquefy natural gas into fuel following the synthesis gas production process, a technology to liquefy natural gas into fuel without the synthesis gas production process, and the trend of effective use of C4 saturated hydrocarbon. In (2), surveys were made of process to reduce production of aromatic hydrocarbon as much as possible, process to effectively separate aromatic hydrocarbon, and process to convert excess aromatic hydrocarbon into polymer, etc. In (3), surveys were conducted on petroleum coke and pitch in terms of production methods, the supply/demand situation, property characteristics, usability to new fields, etc. 170 refs., 114 figs., 65 tabs.

  1. Fiscal 1997 R and D project on industrial science and technology under a consignment from NEDO. R and D of the synthesis and processing of advanced biomaterials (fixation and effective utilization of carbon dioxide using peptides); 1997 nendo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Senshin bio zairyo no sosei kako gijutsu no kenkyu kaihatsu (peptide oyo nisanka tanso koteika yuko riyo gijutsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In fiscal 1997, study was made on formation of peptides with a biogenic function and molecular recognition function, and peptide materials. The existing automatic design technique of peptides including non-natural amino acids was applied to design of complementary peptides of proteins with known structures to optimize a development technique of ligand. Practical function of peptides as advanced receptor ligand was verified by applying the existing conformation control technique to stable holding of peptide active conformation. Creation of bio-materials, and development of preparation technology of bio-substrates and materializing technology of functional molecular materials were carried out. To construct an electron transfer system by self- organized body of peptides formed on a substrate, a peptide molecular device was prepared and verified using linkers. To use peptides as photoelectron functional molecule, metallized peptide with main helix structure was prepared. The possibility of molecular materials with a fixation function of CO2 was examined. A high-sensitivity bio-sensor was also mentioned. 75 refs., 130 figs., 25 tabs.

  2. Gd-Ni-Si system

    International Nuclear Information System (INIS)

    Bodak, O.I.; Shvets, A.F.

    1983-01-01

    By X-ray phase analysis method isothermal cross section of phase diagram of the Gd-Ni-Si system at 870 K is studied. The existence of nine previously known compounds (GdNisub(6.72)Sisub(6.28), GdNi 10 Si 2 , GdNi 5 Si 3 , GdNi 4 Si, GdNi 2 Si 2 , GdNiSi 3 , GdNiSi 2 , Gd 3 Ni 6 Si 2 and GdNiSi) is confirmed and three new compounds (GdNisub(0.2)Sisub(1.8), Gdsub(2)Nisub(1-0.8)Sisub(1-1.2), Gd 5 NiSi 4 ) are found. On the base of Gd 2 Si 3 compound up to 0.15 at. Ni fractions, an interstitial solid solution is formed up to 0.25 at Ni fractions dissolution continues of substitution type. The Gd-Ni-Si system is similar to the Y-Ni-Si system

  3. Internal carbonitriding behavior of Ni-V, Ni-Cr, and Ni-3Nb alloys

    International Nuclear Information System (INIS)

    Allen, A.T.; Douglass, D.L.

    1999-01-01

    Ni-2V, Ni-5V, Ni-12V, Ni-10Cr, Ni-20Cr, and Ni-3Nb alloys were carbonitrided in C 3 H 6 and NH 3 gas mixtures (bal H 2 ) over the range 700--1,000 C. Carbonitridation of Ni-12V and Ni-20Cr in C 3 H 6 /NH 3 /H 2 (1.5/1.5/97 v/o) and (1.5/10/88.5 v/o) produced duplex subscales consisting of near-surface nitrides with underlying carbides. Growth of each zone obeyed the parabolic rate law under most conditions. The presence of carbon generally did not effect the depth of the nitride zones compared to nitriding the alloys in NH 3 /H 2 (10/90 v/o). However, at 700 C, the nitride zones were deeper in the carbonitrided Ni-V alloys and Ni-20Cr. The presence of nitrogen generally increased the depth of the carbide zones in Ni-12V and Ni-20Cr compared to carburizing these alloys in C 3 H 6 /H 2 (1.5/98.5 v/o). VN, CrN, and NbN formed in Ni-V, Ni-Cr, and Ni-Nb alloys, respectively, whereas the underlying carbide layers contained V 4 C 3 in Ni-12V, Cr 3 C 2 above a zone of Cr 7 C 3 in Ni-20Cr, and NbC in Ni-3Nb. The solubilities and diffusivities of nitrogen and carbon in nickel were determined. Nitrogen and carbon each exhibited retrograde solubility with temperature in pure Ni in both carbonitriding environments. Nitrogen diffusion in nickel was generally lower in each carbonitriding mixture compared to nitrogen diffusion in a nitriding environment, except at 700 C when nitrogen diffusion was higher. Carbon diffusion in nickel was generally higher in the carbonitriding environments compared to carbon diffusion in a carburizing environment

  4. Fiscal 1975 Sunshine Project research report. General research on hydrogen energy subsystems and their peripheral technologies (Research on chemical use); 1975 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Kagaku riyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-04-15

    The whole amount of hydrogen consumption for chemical industries all over the world is estimated to be 249.7 billion Nm{sup 3} in 1974, while 367.2 billion Nm{sup 3} in 1980 roughly under a bold assumption, based on 3 current big consumption fields of ammonia production, methanol production and petroleum refining, and some promising fields in the future such as reduced iron and synthetic protein. Consumption ratios for every field are probably 54.9% in ammonia production, 30% in petroleum refining, 9.5% in methanol production and 5.6% in others in 1974, and nearly similar in 1980. However, although there are various troubles, if a large amount of methanol is used as fuel in the future, and its production plan is promoted to satisfy the demand of methanol fuel, hydrogen consumption for methanol production will increase drastically. In the future, if the production process of hydrogen as secondary fuel is established, such hydrogen also will be used for various chemical industries naturally. Research was thus made on use of oxygen as byproduct inevitably. (NEDO)

  5. Achievement report on research and development in the Sunshine Project in fiscal 1976. Comprehensive discussion on hydrogen utilizing subsystems and research on peripheral technologies (Research for chemical utilization); 1976 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Kagaku riyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-04-15

    Surveys and studies were performed on chemical utilization of hydrogen regarding its status of development and utilization inside and outside the country, as well as its future prospect. This paper describes chemical utilization of hydrogen in ammonia, methanol, petroleum refining and other industries as the existing fields. It also describes chemical utilization of oxygen in iron and steel, chemical and other industries. It describes methanol as a pollution-free auxiliary fuel for electric power plants as a new type of hydrogen application. Acetic acid made by using the Monsanto method which carbonylate methanol is drawing attention in terms of economy, and is in the phase of discussing commercialization. Synthesizing ethylene glycol from carbon monoxide and hydrogen may be conceived economically. Methanol for synthesized protein depends on the possibility of future development. In the iron and steel industry, electric furnace steel makers are planning production of reduced iron, where the direct reduction process using hydrogen is considered as a complementary process, including countermeasures for scrap iron. This paper estimates hydrogen amount as a raw material for ammonia to remove NOx by using the ammonia reduction process. It also describes possibility of other types of utilization. (NEDO)

  6. FY 1974 report on the results of the Sunshine Project. Comprehensive study of hydrogen use subsystem and study on the periphery technology (Study on the chemical utilization); 1974 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Kagaku riyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-07-01

    This paper reports on the present situation of the chemical use of hydrogen and oxygen, and the short-term, medium-term, and long-term forecast. The main usage of hydrogen is ammonia synthesis, petroleum refining, and methanol synthesis. In the usage of these three, there are factors of structural changes now and in future, and it is extremely difficult to predict the amount in a short term up to around 1980. In a medium term prediction, from the result of predicting the demand of ammonia, methanol and hydrodesulfurization, the total 1985 hydrogen demand is estimated at approximately 60 billion Nm{sup 3}, and approximately 67 billion Nm{sup 3} as the gross hydrogen demand. Further, judging from that synthetic protein, fuel use methanol, and reduced iron are estimated to reach a certain production size in and after 1985, new demand for hydrogen is expected to be approximately 100 billion Nm{sup 3} mostly including fuel use methanol. In a long term prediction, it is extremely hard to predict the demand because of various factors existing in Japan and abroad. As predicted in a medium term, the amount of chemical use of hydrogen is expected to increase more and more, even if calculating it only in the field of ammonia synthesis, petroleum refining, and methanol synthesis. (NEDO)

  7. Nipah Virus (NiV)

    Science.gov (United States)

    ... Form Controls Cancel Submit Search the CDC Nipah Virus (NiV) Note: Javascript is disabled or is not ... gov . Recommend on Facebook Tweet Share Compartir Nipah virus (NiV) is a member of the family Paramyxoviridae , ...

  8. Generalized report on the research cooperation promoting project. Research cooperation related to the mine waste water treatment technology utilizing biotechnology; Kenkyu kyoryoku suishin jigyo sokatsu hokokusho. Bio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This paper is a generalized report in relation with the mine waste water treatment technology utilizing biotechnology, from among the promotion projects for research cooperation with China. Ferric iron (Fe{sup 3+}), which precipitates at low pH, is produced by utilizing bacteria which derives energy from oxidizing ferrous iron (Fe{sup 2+}) in the waste water, and the iron is precipitated and removed by using low-cost calcium carbonate as a neutralizing agent. Joint researches and developments have been carried out on selection of optimal kinds of bacteria, cultivation of bacteria oxidizing iron at high efficiency, optimal removal system of heavy metals in mine waste water, and recovery of useful resources. Japanese engineers were sent to sites in China, Chinese researchers were received in Japan, and pilot plants were operated and studied. For the purpose of proliferating and enlightening the result of the project, a seminar was held in Beijing in February 1998. In order for the achievements derived up to fiscal 1998 to be used in diverse fields, fiscal 1999 will carry out follow-ups, including assistance, for the voluntary researches performed by China. The follow-ups will also include confirmation on the state of testing the iron oxidizing bacteria technology, technical guidance, and analyses and discussions on the data. (NEDO)

  9. FY 1994 report on the cooperative research on the biological use mine wastewater treatment technology; 1994 nendo bio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    In this project, a pilot plant for mine wastewater treatment facilities using Thiobacillus ferrooxidans was installed at the Wushan mine in China to study the operation using the bacteria habitable in this mine. The project aims at establishing the mine wastewater treatment technology using the method of Thiobacillus ferrooxidans in China. The field survey and study in Japan were carried out. In the field survey, the technical guidance was given for incubation method, neutralization experiment method and analysis method of Thiobacillus ferrooxidans. In the study in Japan, one kind of bacteria to be used was selected in the 'selection test for the optimum kind of bacteria,' and a study was made which was titled 'Study of mine wastewater treatment using the method of Thiobacillus ferrooxidans which is suitable for the mine site.' In 'Study of the optimum removal of heavy metal in mine wastewater,' a table test of sulfide precipitation method was conducted on copper removal/recovery to make formation conditions of copper sulfide clear. The conditions obtained were reflected in 'Study of mine wastewater treatment by the method of Thiobacillus ferrooxidans which is suitable for the mine site,' and various conditions for bacteria oxidation process were studied. The paper surveyed characteristics of heavy metal and temperature of Chinese strains. Further, the basic data were acquired which contribute to the production of inorganic flocculants. (NEDO)

  10. Report on the research cooperation promoting project in fiscal 1998. Research cooperation related to the mine waste water treatment technology utilizing biomass; 1998 nendo kenkyu kyoryoku suishin jigyo hokokusho. Bio riyo ni yoru kohaisui shori gijutsu ni kansuru kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This paper describes the achievement in relation with the mine waste water treatment technology utilizing biomass, from among the promotion projects for research cooperation with China. Waste water is converted into ferric iron (Fe{sup 3+}), which precipitates at low pH, by utilizing iron oxidizing bacteria which use ferrous iron (Fe{sup 2+}) in the waste water as the energy source, and is precipitated and removed by using low-cost calcium carbonate as a neutralizing agent. Fiscal 1998 has performed eight site surveys with 47 persons in total. The main survey items are the study and guidance of pilot plant operation and the survey on measures to prevent occurrence of contamination by heavy metals in Wushan Mine. Additional site surveys were made at Dexing Mine and Yinshan Lead/Zinc Mine. Continued from fiscal 1997, consumables required for the pilot plant were purchased, and items of the bench-scale testing equipment used by Japan for domestic researches (an oxidation and neutralization testing equipment and a copper recovering and testing equipment) were transported to China. The operation research data of the pilot plant were put in order and analyzed. This paper summarizes the concept design of the shaft waste water treatment facilities for the north mine in Wushan Mine, and the surveys on measures for heavy metal contamination sources. (NEDO)

  11. Report on evaluation of research and development of direct steel-making using high-temperature reducing gas. Phase 1. Draft; Koon kangen gas riyo ni yoru chokusetsu seitetsu no kenkyu kaihatsu (daiikki) ni kansuru hyoka hokokusho (an)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-01-01

    Described herein is development of direct steel-making using high-temperature reducing gas. A light hydrocarbon fraction (boiling point: 230 degrees C or lower), produced by steam cracking of vacuum residua, is reformed into a reducing gas in the presence of steam, using heat to be supplied by a nuclear plant which produces high-temperature gases for various purposes. This reducing gas is then supplied to a plant for producing reduced iron. This project has established basic techniques for designing, constructing and operating a direct steel-making pilot plant, to be connected to a 50 MWt high-temperature gas test furnace. The closed iron-making system and greatly reduced SOx emissions to several fractions of the current level are some of the expected effects. The environmental impacts of the high-temperature gas furnace will be on a level with those associated with a light-water reactor. Cracking and gasification of vacuum residua, which has found limited purposes so far, should expand its applicable areas and reduce dependence on fossil resources, leading to diversification of energy sources. The overall thermal efficiency of the high-temperature gas furnace is expected to increase to at least 60%, because its high-temperature gases of around 1,000 degrees C can be used for heating processes, and the waste heat can be further used for generation of steam for power production. (NEDO)

  12. Research cooperation project in fiscal 1999. Research cooperation on a technology to treat well waste water by utilizing biomass (follow-up); 1999 nendo bio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku (follow up)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The research cooperation project on a technology to treat well waste water by utilizing biomass has used as the object the well waste water from the north mine in the Wu Shan mine in Jiangxi Province. The research included surveys on properties of the well waste water from the subject mine by means of the site survey, discussions on treatment conditions based on studies in Japan, and discussions on factors for designing a full size facility as a result of pilot plant operation research. The Japanese side has transported to Beijing the bench-scale testing equipment used for the studies in Japan (an oxidation and neutralization testing equipment and a copper recovery testing equipment). In the present follow-up project, supports were provided to the research and development activities performed voluntarily by the Chinese side by using the above bench-scale testing equipment through guiding the tests at the site and supplying consumables. Certain bacteria have capability to oxidize ferrous ions in the mine well waste water into ferric ions. Utilizing these bacteria results in sedimentation of iron oxides in lower pH zones than in the conventional method, making removal of heavy metals from the well waste water possible. As a result, such effects may be expected as reduction in chemical cost, and reduction of quantity of the produced sediments. (NEDO)

  13. Report on a survey in fiscal 1999. Survey on industrial utilization of microorganism reaction mechanisms under anaerobic condition; 1999 nendo kenki jokenka ni okeru biseibutsu hanno kiko no kogyoteki riyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Industrial utilization of reaction mechanisms of microorganisms under anaerobic condition permits structuring energy saving type production processes. The present survey has investigated features of new microorganisms under anaerobic condition and the status of researches thereon inside and outside the country, and discussed their future applications. Chapter 1 compares anaerobic microorganisms and functions of microorganism under anaerobic condition with those aerobic to describe their general features, and describes the purpose of this survey and the summary of the investigations. Chapter 2 surveys the current status of technologies to utilize microorganisms under anaerobic condition. Chapter 3 outlines metabolic characteristics of the anaerobic microorganisms, and extracts functions effective for material production by different anaerobic microorganisms to describe their applicability. Chapter 4 evaluates the system classification for the anaerobic microorganisms utilizing the basic arrangement of 16S rRNA genes, and extracts technical problems therein. Chapter 5 proposes structuring a total methane fermentation system including a raw material collecting process, and enhancing alcohol productivity of Zymomonas bacteria. (NEDO)

  14. Report on research cooperation for bio-aided treatment of waste water from pits, conducted in FY1997; 1997 nendo bio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This research cooperation promotion project was implemented to develop techniques for preventing water pollution by waste water from pits in mines in China and thereby contributing to environmental preservation by studying to select optimum bacteria, culture the bacteria for high-efficient oxidation of iron, efficiently remove heavy metals from waste water, develop waste water treatment techniques with the aid of the iron-oxidizing bacteria, suitable for the mines in China, and develop techniques for recovering useful resources. The bio-aided waste water treatment process is a suitable method for treating waste water discharged from mining pits, in which ferrous iron present in waste water is oxidized with the aid of iron-oxidizing bacteria growing with ferrous ion as the energy source into ferric iron, which is precipitated at a low pH and removed in the presence of inexpensive calcium carbonate as the neutralizer. The pilot plant has been operating smoothly in a mode to treat waste water discharged from mining pits in Wushan Mine, almost satisfying the targets of treated water properties, i.e., pH: 0.5 or less, Cu: less than 0.5, Zn: less than 2.0, Pb: less than 1.0, Cd: less than 0.1, As: less than 0.5, Mn: less than 2.0, and SS: less than 70, all in mg/L except for pH. (NEDO)

  15. FY1998 report on a survey related to joint utilization of welfare device development data using an international network; 1998 nendo kokusai network ni yoru fukushi kiki kaihatsu data no kyodo riyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A survey was made in relation with joint utilization of welfare device development data using an international network. Developing welfare devices requires data from ergonomic and medical systems, while the cope of the objects is wide, and the kinds are various. For proliferation of welfare devices, system compatibility evaluation including that on using environment is important, including living environments that are different by countries. The present survey has identified how data for aged, handicapped and help-needing persons are accumulated and utilized in research organizations in America and Europe for both of the ergonomic and medical areas. The survey also investigated major academic societies in overseas countries, and collected database and academic network information that support the advanced research and development. At the same time, investigations were also made on organizations and corporations who are moving forward the efficient data utilization. Welfare device and service information providing systems in Japan were investigated to compare them with the trends in other countries. Conceptions and methods were compiled to utilize data internationally and jointly. Database models for device development were considered, and a proposal was made on structuring a research and development supporting database, and the operation method thereof. (NEDO)

  16. Study of an optimization of regeneration for an absorbent used in the solar desiccant cooling system; Taiyonetsu riyo desiccant reibo ni mochiirareru kyushuzai saisei tokusei no saitekika ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Saito, Y [Osaka Institute of Technology, Osaka (Japan)

    1997-11-25

    A desiccant cooling system uses concentrated aqueous solution of an absorbent to reduce humidity, hence the resultant absorbent solution becomes dilute. Regeneration of the dilute solution uses solar heat, where the regeneration characteristics are affected by solution temperature, vapor pressure, water content, air-liquid flow rate, and other factors. Therefore, mutual relationship among these different factors were investigated, and an optimum operating condition was discussed. The regeneration characteristics of the absorbent is strongly affected by temperature of triethylene glycol (TEG). This is because vapor pressure, Ps, in the TEG aqueous solution increases as the TEG temperature rises. This means that preheating the solution is effective in regenerating the absorbent. As the regeneration progresses, the water content, Ww, decreases, and the regeneration rate decreases. This is because of reduction in the Ps in association with decrease in the Ww of the TEG. This suggests that it is important in the absorbent regeneration to reduce flow rate of the TEG aqueous solution as low as possible. Raised air temperature reduces difference in vapor partial pressure between the TEG and the air, resulting in reduced regeneration rate. 5 refs., 9 figs.

  17. Annual cycle solar energy utilization with seasonal storage. Part 8. Study on periodic steady state of the annual cycle energy system at a practical operation; Kisetsukan chikunetsu ni yoru nenkan cycle taiyo energy riyo system ni kansuru kenkyu. 8

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, H; Okumiya, M [Nagoya University, Nagoya (Japan)

    1997-11-25

    A study was made of the periodic steady state of the annual cycle solar energy system with seasonal heat storage at a practical operation. Cold heat in winter and warm heat in summer are stored in the seasonal storage tank, and these are each used in shift until when demand for cold/warm heat appears. Moreover, gap in quantity of cold/warm heat going in/out of the heat storage tank during a year is filled by natural energy such as solar energy, so that the system can be operated in annual cycles. Studies were conducted of the periodic unsteady term and the problem on lowering of performance during the term such as the periodic unsteady term of water temperature inside the seasonal heat storage tank and temperature of the soil around the storage tank, and the level of lowering of performance during the term, necessity of additional operation/control at the start of operation and aged deterioration of the system. Within the assumption, even if starting operation in any time of the year, the system could show the performance almost expected from the first operation year with no additional system operation and control required only at the start of operation. It is thought that the heat source selection control of heat pump largely contributes to this. 4 refs., 5 figs., 3 tabs.

  18. Achievement report on research and development (1st phase) of direct iron making by use of high-temperature; Koon kangen gas riyo ni yoru chokusetsu seitetsu no kenkyu kaihatsu (daiikki) ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-02-01

    Efforts are put into the study of direct iron making for use in a closed system where heat energy from a multi-purpose high-temperature gas furnace expected to be developed in the near future will be utilized for iron making. The researches, carried out for the establishment of technologies necessary for designing, building, and operating a pilot plant dimensionally suitable for connection to a 50MWt multi-purpose high-temperature gas furnace, cover the plant total system, a high-temperature heat exchanger, ultrahigh-temperature alloys, high-temperature insulating materials, a reduced gas generating unit, and a reduced iron making unit. When the effort is evaluated as a whole, it is found that the newly developed system is effective in preventing pollution, emitting but 0.1Nm{sup 3} of SOx per 1 ton of crude iron against the 0.4-0.9Nm{sup 3} emitted by a blast furnace/converter iron making mill. It is also found effective in reducing fossil fuel dependence and in enhancing energy source diversification. When it comes to energy conversion efficiency, furthermore, it is shown that the new system achieves a rate of 60% or more while only approximately 30% is attained by light water reactor power generation and approximately 40% by a high-temperature gas furnace. (NEDO)

  19. Borehole geophysics for delineating the geological structure in the Sakonishi prospect, the Hida area, Japan; Hida chiiki Sako nishi chiku ni okeru boring ko riyo butsuri tansa ni yoru chishitsu kozo kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Katayama, H.; Hishida, H.; Yoshioka, K. [Metal Mining Agency of Japan, Tokyo (Japan)

    1997-05-27

    In order to discuss effectiveness of physical exploration in the Sakonishi prospect in the Hida area, physical exploration was carried out by utilizing bored wells. This area contains the Kamioka mine, one of the major base metal mines in Japan, where electrical exploration has been attempted several times in the past. No effective results have been obtained, however, because specific resistance contrast between mine beds and base rocks is too small, and the topography is too steep making site workability inferior. As part of the investigations on geological structures over wide areas, electrical logging (specific resistance and natural potential) was performed in fiscal 1995 and 1996 by utilizing the boreholes. Induced polarization logging was also conducted on the same boreholes. A traverse line on the ground with a length of 600 m and boreholes were used to execute specific resistance tomography. Clear extraction was possible on a fault structure which is thought related with limestone distribution and mine bed creation. However, it was not possible to identify upward continuity of zinc ores expected in the exploration. Because of not large a specific resistance contrast between zinc ores and base rocks, it is difficult to find mine bed locations only from the information on the specific resistance. 5 refs., 5 figs., 1 tab.

  20. Ni República parlamentaria ni presidencialista

    OpenAIRE

    Álvarez Tardío, Manuel

    2004-01-01

    Revista de Estudios Políticos (Nueva Época), Núm. 123. Enero-Marzo 2004 Este trabajo está dedicado al estudio de un aspecto básico del sistema político de la II República española (1931-1936): el modelo de presidencia de la República y de relaciones de la misma con el parlamento y el gobierno. Aquí se sostiene que la Segunda República, de acuerdo con su Constitución, no fue un régimen parlamentario ni presidencial. Combinó de forma extraña y ambigua elementos de ambos modelos. Probablement...

  1. Microstructural development in NiAl/Ni-Si-B/Ni transient liquid phase bonds

    International Nuclear Information System (INIS)

    Gale, W.F.; Orel, S.V.

    1996-01-01

    A transmission electron microscopy (TEM) based investigation of microstructural development during transient liquid phase bonding of near-stoichiometric NiAl to commercial purity nickel is presented in this article. The work described employed Ni-4.5 wt pct Si-3.2 wt pct B (BNi-3) melt-spun interlayers. The precipitation of both Ni-Al based phases and borides within the joint and adjacent substrate regions is discussed. The article considers martensite formation (within the NiAl substrate) and the precipitation of L1 2 type phases (both within the joint and at the interface with the NiAl substrate). The relative roles of the two substrate materials (NiAl and Ni) in the isothermal resolidification process are identified. The preferential formation of Ni 3 B boride phases in the Ni substrate near the original location of the Ni substrate-joint interface is discussed and contrasted with the absence of similar events in the NiAl substrate

  2. Ni landsbyer i Danmark

    DEFF Research Database (Denmark)

    Larsen, Jacob Norvig

    Denne rapport beskriver en evaluering af statsstøttede forsøg med at styrke og udvikle mindre lokalsamfund. Forsøgene er gennemført i ni kommuner. Da der i disse år er stor opmærksomhed om de små byers og samfunds udviklingsmuligheder, har erfaringerne fra forsøgsprojekterne bred interesse. Forsø...

  3. Reduction mechanism of Ni2+ into Ni nanoparticles prepared from ...

    Indian Academy of Sciences (India)

    journal of. March 2009 physics pp. 577–586. Reduction mechanism of Ni2+ into Ni ..... and at high field, no domain wall is available and hence, the system becomes a .... [23] J Ding, T Tsuzuki, P G McCormick and R Street, J. Phys. D: Appl.

  4. Reactive Ni/Ti nanolaminates

    International Nuclear Information System (INIS)

    Adams, D. P.; Bai, M. M.; Rodriguez, M. A.; McDonald, J. P.; Jones, E. Jr.; Brewer, L.; Moore, J. J.

    2009-01-01

    Nickel/titanium nanolaminates fabricated by sputter deposition exhibited rapid, high-temperature synthesis. When heated locally, self-sustained reactions were produced in freestanding Ni/Ti multilayer foils characterized by average propagation speeds between ∼0.1 and 1.4 m/s. The speed of a propagating reaction front was affected by total foil thickness and bilayer thickness (layer periodicity). In contrast to previous work with compacted Ni-Ti powders, no preheating of Ni/Ti foils was required to maintain self-propagating reactions. High-temperature synthesis was also stimulated by rapid global heating demonstrating low ignition temperatures (T ig )∼300-400 deg. C for nanolaminates. Ignition temperature was influenced by bilayer thickness with more coarse laminate designs exhibiting increased T ig . Foils reacted in a vacuum apparatus developed either as single-phase B2 cubic NiTi (austenite) or as a mixed-phase structure that was composed of monoclinic B19 ' NiTi (martensite), hexagonal NiTi 2 , and B2 NiTi. Single-phase, cubic B2 NiTi generally formed when the initial bilayer thickness was made small.

  5. Electroplated Ni on the PN Junction Semiconductor

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm{sup 2}. The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased.

  6. Electroplated Ni on the PN Junction Semiconductor

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae

    2015-01-01

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm 2 . The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased

  7. FY 2000 Feasibility study on the environmentally-friendly coal utilization systems as part of the international project for coal utilization measures. Feasibility study on supporting introduction of the environmentally-friendly coal utilization systems in Vietnam (Model project for introduction of advanced coal preparation systems); 2000 nendo kokusai sekitan riyo taisaku jigyo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa jigyo Vietnam ni okeru kankyo chowagata sekitan riyo system donyu shien jigyo (kodo sentan system donyu model jigyo kanosei chosa jigyo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-06-01

    The feasibility study was conducted on a model project in Vietnam, aimed at solving the environmental pollution problems resulting from use of coal by demonstrating and disseminating the Japan's environmental technologies in the Southeast Asian countries. The feasibility study was conducted for the Cua Ong Coal Preparation Enterprise, which has the largest coal preparation capacity in Vietnam and port facilities. It is treating raw coal from 10 coal mines for classification and preparation, and shipping coal of various types that meet the standards for domestic use and export. The survey results point out that unrecovered coal remains in waste water discharged from the coal preparation plants to pollute the sea area, and that quantity of the refuse increases because of the unrecovered coal it contains. The environmental technologies needed to introduce include modification to variable wave pattern type jigging separator, refuse height measuring instrument and automatic controller, circulating heavy medium gravimeter, highly functional settling pond, and flocculent facilities. (NEDO)

  8. Synthesis and electrochemical behavior of nanostructured cauliflower-shape Co-Ni/Co-Ni oxides composites

    International Nuclear Information System (INIS)

    Gupta, Vinay; Kawaguchi, Toshikazu; Miura, Norio

    2009-01-01

    Nanostructured Co-Ni/Co-Ni oxides were electrochemically deposited onto stainless steel electrode by electrochemical method and characterized for their structural and supercapacitive properties. The SEM images indicated that the obtained Co-Ni/Co-Ni oxides had cauliflower-type nanostructure. The X-ray diffraction pattern showed the formation of Co 3 O 4 , NiO, Co and Ni. The EDX elemental mapping images indicated that Ni, Co and O are distributed uniformly. The deposited Co-Ni/Co-Ni oxides showed good supercapacitive characteristics with a specific capacitance of 331 F/g at 1 mA/cm 2 current density in 1 M KOH electrolyte. A mechanism of the formation of cauliflower-shape Co-Ni/Co-Ni oxides was proposed. A variety of promising applications in the fields such as energy storage devices and sensors can be envisioned from Co-Ni/Co-Ni oxides

  9. Radiochemical method for 63Ni

    International Nuclear Information System (INIS)

    Holm, E.; Nilsson, U.; Hallstadius, L.

    1985-01-01

    A radianalytical method for the determination of 63 Ni content in environmental samples of activated corrosion products is described. After chemical separation and electrodepositing of 63 Ni on silver briquets, the chemical yield is determined by X-ray fluorescence analysis. For the detection of low-energy beta activity, an open gas flow GM-counter with an anticoincidence guard counter is put to use

  10. Electronic structure of Ni/sub 3/Al and Ni/sub 3/Ga alloys

    CERN Document Server

    Pong, W F; Chang, Y K; Tsai, M H; Hsieh, H H; Pieh, J Y; Tseng, P K; Lee, J F; Hsu, L S

    1999-01-01

    This work investigates the charge transfer and Al(Ga) p-Ni d hybridization effects in the intermetallic Ni/sub 3/Al(Ni/sub 3/Ga) alloy using the NiL/sub 3.2/- and K-edge and Al(Ga)K X-ray absorption near edge structure (XANES) measurements. We find that the intensity of white-line features at the NiL/sub 3.2/-edge in the Ni/sub 3/Al(Ni /sub 3/Ga) alloy decreased in comparison with that of pure Ni, which can be attributed to the enhancement of Ni3d states filling and the depletion of the density of Ni 3d unoccupied states in the Ni/sub 3 /Al(Ni/sub 3/Ga) alloy. Two clear features are also observed in the Ni/sub 3/Al(Ni/sub 3/Ga) XANES spectrum at the Al(Ga) K-edge, which can be assigned to the Al(Ga) unoccupied 3p (4p) states and their hybridized states with the Ni 3d/4sp states above the Fermi level in Ni/sub 3/Al(Ni/sub 3/Ga). The threshold at Al K-edge XANES for Ni/sub 3/Al clearly shifts towards higher photon energies relative to that of pure Al, indicating that Al loses charges upon forming Ni/sub 3 /Al. ...

  11. Nitriding behavior of Ni and Ni-based binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Fonovic, Matej

    2015-01-15

    Gaseous nitriding is a prominent thermochemical surface treatment process which can improve various properties of metallic materials such as mechanical, tribological and/or corrosion properties. This process is predominantly performed by applying NH{sub 3}+H{sub 2} containing gas atmospheres serving as the nitrogen donating medium at temperatures between 673 K and 873 K (400 C and 600 C). NH{sub 3} decomposes at the surface of the metallic specimen and nitrogen diffuses into the surface adjacent region of the specimen whereas hydrogen remains in the gas atmosphere. One of the most important parameters characterizing a gaseous nitriding process is the so-called nitriding potential (r{sub N}) which determines the chemical potential of nitrogen provided by the gas phase. The nitriding potential is defined as r{sub N} = p{sub NH{sub 3}}/p{sub H{sub 2}{sup 3/2}} where p{sub NH{sub 3}} and p{sub H{sub 2}} are the partial pressures of the NH{sub 3} and H{sub 2} in the nitriding atmosphere. In contrast with nitriding of α-Fe where the nitriding potential is usually in the range between 0.01 and 1 atm{sup -1/2}, nitriding of Ni and Ni-based alloys requires employing nitriding potentials higher than 100 atm{sup -1/2} and even up to ∞ (nitriding in pure NH{sub 3} atmosphere). This behavior is compatible with decreased thermodynamic stability of the 3d-metal nitrides with increasing atomic number. Depending on the nitriding conditions (temperature, nitriding potential and treatment time), different phases are formed at the surface of the Ni-based alloys. By applying very high nitriding potential, formation of hexagonal Ni{sub 3}N at the surface of the specimen (known as external nitriding) leads to the development of a compound layer, which may improve tribological properties. Underneath the Ni{sub 3}N compound layer, two possibilities exist: (i) alloying element precipitation within the nitrided zone (known as internal nitriding) and/or (ii) development of metastable and

  12. Report on the results of the FY 1998 hydrogen utilization international clean energy system technology (WE-NET). Subtask 7. Survey/study on hydrogen utilization technology; 1998 nendo suiso riyo kokusai clean energy system (WE-NET). 7. Suiso riyo gijutsu ni kansuru chosa kento

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The paper described the results of survey/study of the FY 1998 WE-NET project. In Subtask 7, survey/study have been made on the main hydrogen utilization technologies except the hydrogen combustion gas turbine since FY 1993. Based on the survey results having been obtained, study was made on conditions for introducing promising technology, future prospects, etc. in FY 1998. As to the power generation, the basic combustion test and test on hydrogen injection equipment as element test, and test on ignition equipment were carried out using rapid compression/expansion equipment. A scenario for introducing hydrogen vehicle was made, and at the same time environmental LCA was conducted by which environmental influences can be assessed. The survey of the market of pure hydrogen polymer electrolyte fuel cells were made in terms of the electric utility use, industrial use, residential/commercial use, and movement/vehicle use. Study was conducted on the combined process of oxygen production equipment and He Brayton cycle in the subzero fractionation/low-temperature VSA method. Various methods including performance, price, etc. were surveyed/studied, making it a precondition that hydrogen supply stations are installed in stand-alone distribution near places of consumption. (NEDO)

  13. Fiscal 1997 survey report. Feasibility study of the environmentally friendly type coal utilization system (feasibility study of the environmentally friendly type coal utilization system in India); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Indo ni okeru kankyo chowagata sekitan riyo system kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The survey was conducted of the present situation of coal utilization and the present coal situation such as the environmental state of India which is a coal producing/consuming country next to China in Asia. The paper studied a feasibility of the introduction of the environmental friendly type coal utilization system` to be planned in India. The items for survey are the present situation of economy and energy and the future trend, environmental problems on coal utilization, the present status of the coal distribution system and study subjects, the present status of coal utilization by field and study subjects, a possibility of briquette use, a possibility of coal fluidization, electric power development plans and coal combustion technology in each industry, etc. The subjects are the obligation of coal preparation to coal thermal power plants 1000 km away from coal mines starting 2001, measures taken for effective ash use, measures taken for superannuated gas furnaces, etc. Based on the results of these site surveys and reports of the investigation under consignment from CMPDI, the paper studied/analyzed possibilities of introducing the coal utilization system having actual introduction results in Japan to India, and made an investigational report. 39 refs., 12 figs., 56 tabs.

  14. Fiscal 1975 Sunshine Project research report. General research on hydrogen energy subsystems and their peripheral technologies (General research on hydrogen energy subsystems); 1975 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Suiso riyo subsystem no sogoteki kento

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-03-01

    This report is composed of the part 1 'General research on hydrogen energy subsystems' and the part 2 'Outline of researches on every use pattern of hydrogen'. The part 1 outlines the fiscal 1975 activity and result, the latest research situation, the latest domestic and overseas R and D situations, some extracted problems, and the future research issues. The part 2 summarizes the research results of every committee with the following themes: (1) Hydrogen combustion technology (combustion characteristics and technology of hydrogen-methane mixture, home and industrial combustors, study on hydrogen energy system), (2) Fuel cell, (3) Automobile engine (merits and demerits of automobile hydrogen engine, problems and their possible solutions on hydrogen engine, urgent research issues), (4) Aircraft engine (prospect for hydrogen use in air transport in Japan, study on various systems around airports in hydrogen use, technical study on aircraft using hydrogen fuel), (5) Gas turbine, and (6) Chemical use of hydrogen. (NEDO)

  15. Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Feasibility study of the environmentally friendly type coal utilization system in Malaysia and Vietnam; Kankyo chowagata sekitan riyo system kanosei chosa. Malaysia Vietnam ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This survey arranged the status of coal utilization technology and the status of coal production, supply, etc. in Malaysia and Vietnam, examined/studied coal utilization systems in both countries, and finally assessed feasibility of introducing the environmentally friendly type coal utilization system. As a country of primary energy source which is abundant in crude oil, natural gas, hydroelectric power, coal, etc., Malaysia now depends on crude oil and natural gas for 80% of its energy, and places emphasis on exploration of natural gas and oil refining. In electric power and cement industries where coal is consumed, effectiveness and environmental issues in association with coal utilization are future subjects. In Vietnam, the north is abundant in hydroelectric power and anthracite, and the south in oil and gas resource, but the north and central districts are in a state of undevelopment. Coal is used for coal thermal power generation, cement industry, and residential/commercial fuel. In the future, effective coal utilization and environmental issues will be subjects. 16 refs., 38 figs., 75 tabs.

  16. Fiscal 2000 operation report. Fiscal 2000 model project for promoting advanced utilization of coal (Survey on data control system for advanced utilization of coal in Japan); 2000 nendo sekitan kodo riyo shuishin moderu jigyo gyomu hokokusho. Nihon no sekitan kodo riyo ni kakawaru data kanri system chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With the purpose of contributing to the drafting of, for example, measures for securing coal resources for Japan and strategies for developing coal utilization technologies from the standpoint of the world climate of the coal supply/demand in the future, database was built concerning coal information such as coal-related supply/demand trend, technological development and utilization status in Japan and foreign countries, with the results of fiscal 2000 reported. In the preparation of related applications, a jump function in the case of pages unregistered with related subjects was added to the coal information retrieval system completed last year, as were a subdividing function of retrieval conditions and a link function to pages of a technical term dictionary. In the arrangement of the database classified by the fields, programs were prepared on 14 tables primarily in relation to supply and demand, with the collection, processing and registration of the data performed. In addition, in order to deal with the clarification of the patent licensing of GIF related technologies, there was developed a graph display program using a general-purpose language, Java. (NEDO)

  17. Feasibility study of environmentally friendly type coal utilization systems. Feasibility study of environmentally friendly type coal utilization systems in sectors except the coal industry in China; Kankyo chowagata sekitan riyo system kanosei chosa. Chugoku no sekitan kogyo igai no bumon ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    For the purpose of working out a comprehensive master plan for application of the coal utilization system, the paper surveyed and studied the coal utilization system in terms of environmental measures and efficiency improvement in the utilization of coal. As a result of the discussion with NEDO and the National Planning Committee of China, Liaoning Province (the whole China) and Shenyang City were selected as a model area and a model city for the survey and study. As energy conservation measures taken in the former, desirable are intensifying/capacity-increase of boilers, kilns, etc. and adoption of new-type/high-efficient equipment. Also expected are reinforcement of combustion control and improvement of efficiency by using coal preparation, industrial use coal briquette, etc. Measures taken in the latter are the same as those taken in the whole China. As SOx reduction measures for Liaoning Province, desirable is installation of dry-type desulfurization equipment and simple desulfurization equipment. As dust prevention measures for it, desirable is installation of electrostatic precipitators or high-functional bag filters. SOx reduction measures for Shenyang City are the same as those taken in the whole China. SOx can be reduced by using coal-prepared low-sulfur coal and industrial use coal briquette added with desulfurizing agent. 88 figs., 163 tabs.

  18. FY1995 research report on the survey of cryogenic energy utilization systems for environmentally friendly energy community project. Case studies of LNG cryogenic energy cascade-wise utilization; 1995 nendo kankyo chowagata energycommunity jigyo ni kakawaru reinetsu riyo system kento chosa hokokusho. LNG reinetsu no cascade teki riyo case study

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Japan's import of LNG (liquefied natural gas) has increased in these 15 years from 13-million tons to 43-million tons at a high rate of 2-million tons a year. At present LNG is used only in power generation and town gas business, and its cryogenic feature which may be useful in various fields is not being utilized. In this survey, factors impeding the wider application of the cryogenic energy are investigated, methods for using the energy more widely and mechanisms required therefor are studied, and discussion is made about the feasibility of the utilization of the energy in a cascade-wise form under the environmentally friendly energy community project. Researches are conducted and the results are evaluated in a study carried out on the comprehensive utilization of LNG cryogenic energy. These researches involve the actualities and trends of LNG cryogenic energy utilization in Japan; current status and prospect of the involvement of LNG bases with their neighboring industries and communities; technological measures for cryogenic energy utilization; technological measures related to low-temperature media and cold heat transportation systems; technological measures for the cascade-wise multidirectional utilization of cryogenic energy; and case studies on assumed local models. (NEDO)

  19. Achievement report on research and development in the Sunshine Project in fiscal 1976. Comprehensive discussion on hydrogen utilizing subsystems and research on peripheral technologies (Comprehensive discussion on hydrogen utilizing subsystems); 1976 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Suiso riyo subsystem no sogoteki kento

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-03-01

    This paper describes comprehensive discussion on hydrogen utilizing subsystems. Hydrogen combustion is characterized by how low the ignition energy is, and how fast the flame propagates. In addition, flame stability is high also in diffusion combustion. However, the diffusion combustion produces a great amount of NOx, the amount varying depending on the degree of air pre-mixture. Since it causes reverse ignition very easily in the pre-mixture degree corresponding to low NOx zone, development of a burner with drastically new mechanism is demanded. In hydrogen fuel cells, the ratio of hydrogen fuel cost accounting for in the power generation cost is very high. As an automobile fuel, very much leaner combustion is possible than in conventional internal combustion engines, and ignition energy is small. However, such abnormal combustion as reverse ignition and early ignition may occur, and their prevention is an important assignment. Issues in aircraft engines are verification of safety, and cost of liquefied hydrogen. Steam turbines have reached their limit already, but gas turbines are expected of exciting efficiency improvement. This paper describes prospects on chemical utilization of hydrogen in the existing fields and new fields. (NEDO)

  20. Fiscal 1995 survey report on the feasibility study of the environmentally friendly type coal utilization system. Feasibility study of the environmentally friendly type coal utilization system in Thailand; Kankyo chowagata sekitan riyo system kanosei chosa. Tai ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-01

    The paper surveyed the present situation and future trend of economy, energy supply/demand, coal production/distribution/utilization and the environmental effects in Thailand. The survey on the coal utilization and its environmental effects was partially requested of the environmental research institute in Thailand. The amount of coal utilization in Thailand rapidly increased to nearly four times as large as that ten years ago mainly in terms of domestic lignite under the government`s policy on expansion of the domestic energy use. However, most of this domestic lignite is low-grade coal with low calories and high sulfur content, and the use of it was rapidly increased mostly in power generation sector without no adequate environmental measures taken. This caused an environmental problem on air pollution due to sulfur oxides at Mae Moh power plant in the north several years ago, and the damages to the regional residents, etc. were given much publicity by journalism and developed the social problem. Accordingly, Thai people are now critical of the coal resource exploration and the coal use expansion. Under the circumstances, the Ministry of Industry and the energy related ministries/offices are obliged to review their development/promotion plans. 84 figs., 99 tabs.

  1. Fiscal 1997 feasibility survey of an environment friendly type coal utilization system. Feasibility survey of the environment friendly type coal utilization system in Malaysia and Vietnam (case of Vietnam); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Malaysia oyobi Vietnam ni okeru kankyo chowagata sekitan riyo system kanosei chosa (Vietnam ban))

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper grasped the state of coal utilization by coal consumption field, the state of coal physical flow in Vietnam, etc., surveyed/studied a possibility of introducing the environment friendly type coal utilization system, and assessed the possibility. As to energy resources, the north is abundant in hydroelectric and coal (mainly anthracite) resources, and the south in oil and natural gas resources. Coal production in fiscal 1997 is planned to be 10 million tons. Coal preparation technique presently available is only grain size sieving. Accordingly, it is necessary to study for heightening efficiency of facilities and modernizing facilities in accordance with the introduction of the environment friendly type coal utilization technology. During the study, it is possible to propose improvement on coal processing technology (coal preparation technology). Assessment and study are made especially of the coal selection system, fine coal recovery system and waste water treatment system. For the plan on new coal-fired power plants (300MWtimes4), there is left much necessity of proposing studying models considered of the anthracite combustion technology and environmental improvement and of assessing/studying them. 60 figs., 117 tabs.

  2. FY1995 research report on the survey of cryogenic energy utilization systems for environmentally friendly energy community project. Case studies of LNG cryogenic energy cascade-wise utilization; 1995 nendo kankyo chowagata energycommunity jigyo ni kakawaru reinetsu riyo system kento chosa hokokusho. LNG reinetsu no cascade teki riyo case study

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Japan's import of LNG (liquefied natural gas) has increased in these 15 years from 13-million tons to 43-million tons at a high rate of 2-million tons a year. At present LNG is used only in power generation and town gas business, and its cryogenic feature which may be useful in various fields is not being utilized. In this survey, factors impeding the wider application of the cryogenic energy are investigated, methods for using the energy more widely and mechanisms required therefor are studied, and discussion is made about the feasibility of the utilization of the energy in a cascade-wise form under the environmentally friendly energy community project. Researches are conducted and the results are evaluated in a study carried out on the comprehensive utilization of LNG cryogenic energy. These researches involve the actualities and trends of LNG cryogenic energy utilization in Japan; current status and prospect of the involvement of LNG bases with their neighboring industries and communities; technological measures for cryogenic energy utilization; technological measures related to low-temperature media and cold heat transportation systems; technological measures for the cascade-wise multidirectional utilization of cryogenic energy; and case studies on assumed local models. (NEDO)

  3. FY 2000 report on the results of the research and development project for utilization of information of high-molecular-weight structures in a living body. Survey on the technological trends of utilizing the reactions with metals in a living body; 2000 nendo seitai kobunshi kozo joho riyo gijutsu kaihatsu chosa hokokusho. 'Seitai kinzoku hanno riyo gijutsu' ni kansuru gijutsu doko chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the FY 2000 results of the survey on the technological trends of utilizing the reactions with metals in a living body, noting the bio-processes effectively coping with the environmental problems. The effects of heavy metals on microorganisms have been investigated on the molecular biology level, but are not fully elucidated. Recently, the microorganisms capable of converting inorganic metal ions in water into the insoluble compounds have been known, leading to possibility of bioremediation to solve pollution by heavy metals, which have detrimental effects on human health. Heavy metals must be recovered, because they are not extinct by decomposition. The plant aided purification has been attracting attention to cope with heavy metals accumulated in soil. Application of bacteria-aided leaching, which is adopted as one ore smelting process, to the technologies for utilizing metals in a living body has been expected, because diversified activities of inanimate matters in extreme environments have been known. Recently, bio-machining of metals aided by Thiobacillus ferrooxidans, one species of independent nutrient bacteria capable of eating metals, has been developed to a potentially viable stage. (NEDO)

  4. Investigations in fiscal 2000 on feasibility of environment friendly coal utilization system. Feasibility survey on environment friendly coal utilization system in India; 2000 nendo kankyo chowagata sekitan riyo system kanosei chosa hokokusho. Indo ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Taking the area of the clean coal technology (CCT) effective for energy conservation and environment preservation as the object, a feasibility survey has been performed on executing a model project in India. About 70% of the total power generation capacity in India depends upon coals existing in abundance inside the country. Since the local coals are high in ash, low in sulfur, and low in calorie, the environmental problem related to thermal power plants is the disposition of fly ash. The Central Electricity Authority of India expects solving this problem by CCT introduction. It also expects increase in combustion efficiency by using ultra-critical boilers. The Indian cement industry often uses in-house electric power generation facilities because of high electric power cost, wherein the produced coal ash is used as a cement raw material. The matter of the strongest interest is the introduction of a high-efficiency combustion system that depends on low-grade coals. Among the CCTs, strong interest was shown in the fluidized bed cement kiln and the circulating fluidized bed boiler. The iron and steel industry has expectations toward effective coal washing technologies and coke manufacturing technologies. (NEDO)

  5. Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Feasibility study of the environmentally friendly type coal utilization system in the Philippines; Kankyo chowagata sekitan riyo system kanosei chosa. Philippines ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Grasping the present situation of coal utilization technology in the Philippines, the paper proposed a feasibility study of introduction of the environmentally friendly type coal utilization system which seems to be needed in the future. (1) Introduction of the environmentally friendly type coal utilization system in the electric power generation sector: there are only four full-scale running coal thermal power plants in the Philippines. In the future, several coal thermal plants are planned to be constructed by 2005, but for the new installation, it is desirable to adopt fluidized bed boilers with wide application to coal kinds. In case of 0.3-1.0 million MW class plants, it is planned to adopt high grade import coals, and it will be natural to fire pulverized coal. For the processing of flue gas, it is a must to install desulfurization facilities and smoke/soot removal devices. (2) Utilization/development of domestic low grade coals: at the mine-mouth generating plant, it is necessary to investigate the economically minable amount of coal, confirm productivity, survey coal quality, etc., and select boiler. As to coal briquetting technology, it is necessary to examine coal quality for tests and make a thorough study of what technology is most suitable. 50 figs., 78 tabs.

  6. Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Feasibility study of the environmentally friendly type coal utilization system in Thailand; Kankyo chowagata sekitan riyo system kanosei chosa. Tai ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The paper investigated and studied the present situation and future trend of coal utilization and distribution in Thailand, and the present situation of environmental effects and the measures taken for environmental protection. Around 2010, coal will probably be produced only at EGAT`s Mae Moh (MM) coal mine. Demand for overseas coal is expected to be 40-50 million tons in 2011, and preparation of the coal center becomes a subject. For general industry use coal, pretreatment such as coal preparation, coal blending and briquetting is needed, considering coal quality, usage, transport distance and environmental effects. Brown coal of MM coal mine is a lignite with high sulfur, high ash content and low heating value. Wide spread of its use can be expected if upgrading is possible such as desulfurization, deashing, increasing heating value. In the electric power generation field, the absorber was installed at the existing boiler of the mine-mouth generating plant to conduct a verification test on high grade desulfurization of ultra-high sulfur lignite. In the industry field, the circulating fluidized bed boiler was adopted. In the residential/commercial field, introduction of briquette was proposed. 80 refs., 84 tabs.

  7. Present status of and subjects on the industrial utilization of polymer separation membranes. Japan`s first largest sea water desalination plant by RO; Kobunshi bunrimaku no sangyo riyo no genjo to kadai. Zosui bun`ya ni okeru maku riyo

    Energy Technology Data Exchange (ETDEWEB)

    Furuichi, M. [Kurita Water Industries Ltd., Tokyo (Japan)

    1998-07-05

    The utilization in Japan and abroad is discussed of desalination methods using evaporation, reverse osmosis (RO) membranes, and electrodialysis membranes, out of various desalination techniques for seawater and others containing more salt. A new seawater desalination plant built in Okinawa, Japan, is outlined, and the future trend of Japan`s efforts for desalination is predicted. The said plant in Okinawa is the largest ever built in this country, and occupies 4th or 5th place in terms of capacity among similar facilities across the world. It was completed in April, 1997, and produces pure water at a rate of 40,000m{sup 3}/day. This plant, operating on RO, comprises eight RO membrane units each capable of 5131{sup 3}/day. The membranes are of the spiral type, consisting of Toray`s crosslinked aramid-base composite membranes and Nitto Denko`s membranes composed totally of crosslinked aromatic polyamide. The greatest of the pending tasks is to reduce the desalination cost. As for the operating cost of the desalination facility at the current stage, it costs 120-130 yen/m{sup 3} on the 40,000m{sup 3}/day scale, and the power cost occupies approximately 60% of the total operating cost. It is concluded that the consumption of electric power and chemicals per pure water produced have to be reduced. 8 refs., 5 figs., 5 tabs.

  8. Research report of FY 1997 on the environmentally acceptable coal utilization system feasibility survey. Environmentally acceptable coal utilization system feasibility survey in Malaysia and Vietnam (Malaysia); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Malaysia oyobi Vietnam ni okeru kankyo chowagata sekitan riyo system kanosei chosa (Malaysia ban))

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In this survey, the coal utilization status in individual consumption sectors and coal distribution status in Malaysia are summarized as basic data for the introduction of environmentally acceptable coal utilization systems. In this fiscal year, the status of existing coal utilization technology and environmental issues in Malaysia are summarized as basic data for the introduction of above-mentioned systems on the basis of data and information collected by basic research and site survey in FY 1996. Malaysia is one of the rich countries producing the primary resources with crude petroleum, natural gas, hydro-power, and coal. The coal demand will be realized after saturating LNG development since 2000. The major coal consumption industries are power generation sector and cement industry sector. As expected increase in the future coal consumption, efficiency of coal utilization and environmental issues are problems in the future. Based on the FS results of this survey, the survey will be continued for planning and conducting the model project required from Malaysia. 8 figs., 34 tabs.

  9. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    International Nuclear Information System (INIS)

    Holec, D.; Bojda, O.; Dlouhy, A.

    2008-01-01

    Non-uniform distributions of Ni 4 Ti 3 precipitate crystallographic variants are investigated in a Ni-rich NiTi shape memory alloy after aging, assisted by external stress. A finite-element method model is presented that considers the elastic anisotropy of the B2 parent phase and also mutual misorientations of grains in a polycrystalline sample. On loading by the external stress, the stress is redistributed in the microstructure and the precipitation of some Ni 4 Ti 3 crystallographic variants becomes distinctly favorable in grain boundary regions since these variant configurations minimize the elastic interaction energy. The volume fraction of the affected grain boundary regions is calculated and the numerical results are compared with the data obtained by differential scanning calorimetry and transmission electron microscopy

  10. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    Czech Academy of Sciences Publication Activity Database

    Holec, David; Bojda, Ondřej; Dlouhý, Antonín

    2008-01-01

    Roč. 481, Sp. Iss. (2008), s. 462-465 ISSN 0921-5093. [ESOMAT 2006. Bochum, 10.09.2006-15.09.2006] R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitates * Multi-step martensitic transformations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.806, year: 2008

  11. Electronic structure of Ni-- and Ni2--ethylene cluster complexes

    International Nuclear Information System (INIS)

    Basch, H.; Newton, M.D.; Moskowitz, J.W.

    1978-01-01

    The electronic structure of metal cluster--ethylene complexes has been investigated by carrying out ab initio bonding pair-correlated, self-consistent field, and configuration interaction (CI) calculations on the NiC 2 H 4 and Ni 2 C 2 H 4 species. The π-NiC 2 H 4 and π-Ni 2 C 2 H 4 cluster complexes are found to be bound, the former only with CI, while disigma-Ni 2 C 2 H 4 has only a repulsive Ni 2 --C 2 H 4 ground state potential curve. The bonding in the π-type cluster complexes can be described as follows: The metal atom configuration is 3d 9 4s 1 with the 4s hybridized (by the metal 4p) away from the ethylene molecule, thereby allowing the π orbital to form a dative sigma bond with the metal atom. The bonding interaction is promoted by the presence of a second nickel atom behind the first one, leading to a 4s orbital electron deficiency of the bonded nickel atom and thus making this nickel atom a better electron acceptor. Back donation from the occupied metal 3d into the ethylene π* molecular orbital also takes place to some extent, and thus both features of the classical Dewar--Chatt--Duncanson model are observed. The π-Ni 2 C 2 H 4 species is analyzed in terms of the addition of a bare nickel atom to a π-NiC 2 H 4 cluster complex, with concomitant stabilization of the orbitals of the bonded nickel atom. A study of the excited electronic states of π-NiC 2 H 4 shows that low-lying 4s→π* and 3d→π* (M→L) charge transfer transitions are predicted. The former is not observed experimentally, probably due to the diffuse nature of the 4s orbital. The relationship between small cluster--ethylene complex systems and ethylene chemisorption on a nickel metal surface is discussed

  12. Radioactive 63Ni in biological research

    International Nuclear Information System (INIS)

    Kasprzak, K.S.; Sunderman, F.W. Jr.

    1979-01-01

    Applications of 63 Ni in biological research are reviewed, with emphasis upon recent investigations of nickel metabolism and toxicology in experimental animals. The radiochemistry of 63 Ni is summarized, including consideration of the preparation of certain 63 Ni compounds (e.g. 63 Ni(CO) 4 and 63 Ni 3 S 2 ) that are of current interest in toxicology, teratology and cancer research. Practical guidance is given regarding the detection and determination of 63 Ni in biological materials by autoradiography and liquid scintillation spectrometry. (author)

  13. Superstructure of NiAs

    International Nuclear Information System (INIS)

    Nozue, Tatsuhiro; Kobayashi, Hisao; Kamimura, Takashi; Yamaguchi, Yasuo

    2001-01-01

    The structural transition in NiAs was studied by neutron diffraction on the single crystalline sample. The crystal structure of NiAs has been reported to be bottom-centered orthorhombic with Cmc2 1 symmetry (niccolite-type). The measurement of temperature dependence of the powder X-ray diffraction revealed that NiAs undergoes a structural transition to the NiAs-type at T t =335 K. In present neutron diffraction experiment at room temperature, we observed the reflections indexed on the basis of the orthorhombic unit cell. The intensities of these reflections are qualitatively explained in terms of the niccolite-type structure with taking account of three domain structures, except for the weak reflections indexed as (001), (003) and (012). Then, the intensities of (001), (002) and (004) reflections were measured in temperature range of 20 to 420 K. The temperature dependences of (002) and (004) reflections qualitatively agree with those of the calculated intensities using the atomic positions of niccolite-type structure. However, the temperature dependence of (001) reflection shows the anomaly around T t , which suggests the symmetry of crystal structure of NiAs is not the Cmc2 1 symmetry. (author)

  14. Thermal stability and electrical characteristics of NiSi films with electroplated Ni(W) alloy

    International Nuclear Information System (INIS)

    Xin Yuhang; Hu Anmin; Li Ming; Mao Dali

    2011-01-01

    In this study, an electroplating method to deposited Ni, crystalline NiW(c-NiW), amorphous NiW (a-NiW) films on P-type Si(1 0 0) were used to form Ni-silicide (NiSi) films. After annealed at various temperatures, sheet resistance of Ni/Cu, c-NiW/Cu and a-NiW/Cu was measured to observe the performance of those diffusion barrier layers. With W added in the barrier layer, the barrier performance was improved. The results of XRD and resistance measurement of the stacked Si/Ni(W)/Cu films reveal that Cu atom could diffuse through Ni barrier layer at 450 deg. C, could diffuse through c-NiW at 550 deg. C, but could hardly diffuse through a-NiW barrier layer. c-NiW layer has a better barrier performance than Ni layer, meanwhile the resistance is lower than a-NiW layer.

  15. Giant magnetoimpedance effect in sputtered single layered NiFe film and meander NiFe/Cu/NiFe film

    International Nuclear Information System (INIS)

    Chen, L.; Zhou, Y.; Lei, C.; Zhou, Z.M.; Ding, W.

    2010-01-01

    Giant magnetoimpedance (GMI) effect on NiFe thin film is very promising due to its application in developing the magnetic field sensors with highly sensitivity and low cost. In this paper, the single layered NiFe thin film and NiFe/Cu/NiFe thin film with a meander structure are prepared by the MEMS technology. The influences of sputtering parameters, film structure and conductor layer width on GMI effect in NiFe single layer and meander NiFe/Cu/NiFe film are investigated. Maximum of the GMI ratio in single layer and sandwich film is 5% and 64%, respectively. The results obtained are useful for developing the high-performance magnetic sensors based on NiFe thin film.

  16. High Ni in Archean tholeiites

    Science.gov (United States)

    Arndt, Nicholas T.

    1991-03-01

    Archean tholeiites generally have higher Ni, Co. Cr and Fe than most younger tholeiites with similar MgO contents. These characteristics cannot be attributed to high T or P batch melting in the Archean mantle, because, although such melts are enriched in siderophile elements, they have higher MgO than normal tholeiites. As primary melts fractionate to lower MgO, they lose Ni, Co and Cr. Nor can the differences between Archean and younger tholeiites be attributed to secular variation in mantle compositions because Archean komatiites have Ni, Co, Cr contents similar to modern (Gorgona) komatiites. It is suggested that the high siderophile element content of Archean tholeiites results from mixing of either komatiitic with basaltic magmas, as might occur in an ascending, melting mantle plume or column, or of komatiite and more evolved rocks, as may take place when komatiite encounters and assimilates crustal rocks.

  17. Relation between shape of Ni-particles and Ni migration in Ni-YSZ electrodes – a hypothesis

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Hauch, Anne; Sun, Xiufu

    2016-01-01

    This is an attempt to explain a phenomenon of total depletion of Ni next to the electrolyte in Ni-YSZ cermet electrodes in solid oxide electrolysis cells during electrolysis at high current density/overpotential. Intuitively, we would think that Ni would always migrate down the steam partial...

  18. Ni-NiO core-shell inverse opal electrodes for supercapacitors.

    Science.gov (United States)

    Kim, Jae-Hun; Kang, Soon Hyung; Zhu, Kai; Kim, Jin Young; Neale, Nathan R; Frank, Arthur J

    2011-05-14

    A general template-assisted electrochemical approach was used to synthesize three-dimensional ordered Ni core-NiO shell inverse opals (IOs) as electrodes for supercapacitors. The Ni-NiO IO electrodes displayed pseudo-capacitor behavior, good rate capability and cycling performance. © The Royal Society of Chemistry 2011

  19. CONFIGURATION-INTERACTION IN NI METAL AND NI-ALLOYS AND HIGH-ENERGY SPECTROSCOPY

    NARCIS (Netherlands)

    TANAKA, A; JO, T; SAWATZKY, GA

    We discuss the electronic state of Ni atoms in Ni metal and of Ni impurity in Cu and Au metals from the viewpoint of 3d configuration interaction (CI) using the Anderson impurity model including atomic multiplets. On the basis of the discussion, we give an interpretation for the Ni 2p-core X-ray

  20. Iodine capture by Hofmann-type clathrate Ni(II)(pz)[Ni(II)(CN)_4

    International Nuclear Information System (INIS)

    Massasso, Giovanni; Long, Jerome; Haines, Julien; Devautour-Vinot, Sabine; Maurin, Guillaume; Larionova, Joulia; Guerin, Christian; Guari, Yannick; Grandjean, Agnes; Onida, Barbara; Donnadieu, Bruno

    2014-01-01

    The thermally stable Hofmann-type clathrate framework Ni(II)(pz)[Ni(II)(CN)_4] (pz = pyrazine) was investigated for the efficient and reversible sorption of iodine (I_2) in the gaseous phase and in solution with a maximum adsorption capacity of 1 mol of I_2 per 1 mol of Ni(II)pz)[Ni(II)(CN)_4] in solution. (authors)

  1. Density functional theory study of the interfacial properties of Ni/Ni3Si eutectic alloy

    International Nuclear Information System (INIS)

    Zhao, Yuhong; Wen, Zhiqin; Hou, Hua; Guo, Wei; Han, Peide

    2014-01-01

    In order to clarify the heterogeneous nucleation potential of α-Ni grains on Ni 3 Si particles in Ni-Ni 3 Si eutectic alloy, the work of adhesion (W ad ), fracture toughness (G), interfacial energy (γ i ), and electronic structure of the index (0 0 1), (1 1 0) and (1 1 1) Ni/Ni 3 Si interfaces with two different cohesive manners are investigated using first-principles method based on density functional theory. Results indicate that the center site stacking sequence (OM) is preferable to continue the natural stacking sequence of bulk Ni and Ni 3 Si. Since OM stacking interfaces have larger W ad , G and γ i than that of the top site stacking (OT) interfaces. The Ni/Ni 3 Si (1 1 0) interface with OM stacking has the best mechanical properties. Therefore, the formation of this interface can improve the stability, ductility and fracture toughness of Ni-Ni 3 Si eutectic alloy. The calculated interfacial energy of Ni/Ni 3 Si (0 0 1), (1 1 0) and (1 1 1) interfaces with OM stacking proves the excellent nucleation potency of Ni 3 Si particles for α-Ni phase from thermodynamic considerations. Besides, the electronic structure and chemical bonding of (1 1 0) interface with OM stacking are also discussed.

  2. Density of Liquid Ni-Cr Alloy

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The density of liquid Ni-Cr alloy was measured by a modified sessile drop method. The density of liquid Ni-Cr alloywas found to decrease with increasing temperature and Cr concentration in the alloy. The molar volume of liquidNi-Cr alloy increases with increasing the Cr concentration in the alloy. The molar volume of Ni-Cr alloy determinedin the present work shows a positive deviation from the linear molar volume.

  3. Laser alloyed Al-Ni-Fe coatings

    CSIR Research Space (South Africa)

    Pityana, SL

    2008-10-01

    Full Text Available The aim of this work was to produce crack-free thin surface layers consisting of binary (Al-Ni, Al-Fe) and ternary (Al-Ni-Fe) intermetallic phases by means of a high power laser beam. The laser surface alloying was carried out by melting Fe and Ni...

  4. Fiscal 1997 report on the cooperative research on the preservation and sustainable utilization of biological diversification; Seibutsu tayosei hozen to jizokuteki riyo nado ni kansuru kenkyu kyoryoku (1997 nendo hokokusho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Cooperative researches were conducted between Japan and Thailand, Indonesia and Malaysia for the purpose of the technology development to make developing countries themselves preserve bioresources existing in tropical forests and use those sustainably. The research subjects for Thailand are a strategical study on eating of the primates, improvement of a microorganism culture collection system, preservation of biological diversification using an artificial ecosystem, bioresource utilization, etc. The subjects for Indonesia are a study of a microorganism culture collection system, study of plant preservation technology, study of microorganism utilization technology, study of plant utilization technology, promotion of the founding of the Indonesia tropical bioresource information center, etc. The subjects for Malaysia are biological diversification database and gene bank, assessment/monitoring of the ocean ecosystem, assessment and inventory of the ecosystem using hi-tech technology, search/separation of bioactive substances originated from microorganism/plant, etc. 26 refs., 24 figs., 81 tabs.

  5. FY 1998 annual report on the survey on development, introduction and promotion of urban type multipurpose geothermal utilization techniques; 1998 nendo toshigata tamokuteki chinetsu riyo gijutsu no kaihatsu, donyu, sokushin ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Introduction of geothermal heat pump systems, which depend on temperature differential, is investigated for urban areas, which have large energy demands. Results of the surveys on the current situations of geothermal heat pump (GHP) systems indicate that they have already numbered 300,000 units in USA and totaled more than 50,000 units in Switzerland and Northern European countries, and that they are increasing at an annual rate of higher than 10%. The results also indicate that introduction of these systems are well feasible in Japan, which generally has better topographical conditions than American and European countries, and the GHP system with vertical ground heat exchanger is investigated for its topographical and environmental considerations. These systems could annually abate approximately 52 million tons of CO2 (4.3% decrease), if disseminated to all households. They are also expected to help control the heat island phenomenon, and reduce peak power consumption. The technological problems to be solved before these systems are massively disseminated including development of small scale drilling rigs and preparation of drilling manuals. System standardization and introduction of subsidy systems are also needed to massively disseminate these systems. (NEDO)

  6. Fiscal 1999 report on basic research for promotion of joint implementation programs. Research on collection and utilization of coal mine methane gas in Russia (Kuznetsk coal field); Russia (Kuznetsk tanden) ni okeru tanko methane gas kaishu riyo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The above-mentioned effort is to comply with the COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change) joint implementation clause. At this coal field, mining facilities are growing superannuated and obsolescent in the prolonged business depression, causing frequent occurrence of disasters such as gas explosions. The coal mine gas collection rate at the Kuznetsk coal field is as low as 17%, with concern for safety discouraging sufficient collection. Even the small amount of the collected gas is, in the absence of gas utilizing facilities, totally discharged into the air. For the mitigation of global warming, for mining safety, and for the establishment of a foundation for business, it is desired that coal mine methane gas collection/utilization facilities and related technologies be introduced into the coal field. Gas purging from the pits is incomplete, which is attributed to the lack of equipment capable of excavating proper-diameter bores longer than 100m for longwall mining. Ventilation also needs improvement. The research is under way on the premise that highly reliable intermediate range (300m) boring equipment and gas management technologies will be available. Collection of gas of a 30-35% concentration level at a collection rate of 40% is the target. (NEDO)

  7. Comprehensive research concerning the development of effective utilizing techniques of biological resources (large scale research out of the framework). Seibutsu shigen no koritsuteki riyo gijutsu no kaihatsu ni kansuru sogo kenkyu (ogata betsuwaku kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-25

    This paper is a research report in which the cultivated production of forest resources, the development to useful substances and the systematization to take the root in a region were studied. The distribution maps of biological resources on respective woodland systems: that is, the nationwide distribution maps of the amount of resources in Japan as to the broadleaf trees in private forests and national forests, the available amount and kinds of tree were prepared. As for the establishment of cultivation technique of the super-short deforestation forest, that is, pursue of wooden growth to the maximum limit, the superior clone 26 system was selected from the willow group through the research of wooden cultivation and the clone which showed the maximum yield reached 24t/ha every year. As for the material preparation technique due to microbial enzymes, that is, the creation and breeding of fungi which have the high lignin decomposition power, a stock of fungi which has the high lignin decomposition power and the decomposition selectivity was created by the cell fusion and the UV (ultraviolet ray) radiation treatment. As for the use of effective components in wooden resources, many useful characteristics could be detected by applying the boiling, bursting and ozone treatment. As for the mushroom cultivation through the application of unused tree kinds, a new kind of mushroom for food service was selected to clarify the possibility of fruit body formation. The development of a new material from conifers is promising. 1 tab.

  8. FY 2000 research cooperation project on the research cooperation for the preservation, sustainable utilization, etc. of the biological diversification. Follow-up; 2000 nendo kenkyu kyoryoku jigyo. Seibutsu tayosei hozen to zizokuteki riyo to ni kansuru kenkyu kyoryoku (Follow up)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of contributing to developing countries' preserving biological resources in the tropical region, etc. and making the sustainable utilization of biological resources using biotechnology, etc. possible, research cooperation for strengthening the base of international research cooperation was given, and the FY 2000 results were outlined. In this fiscal year, visits were paid to research institutes in Indonesia, Thailand and Malaysia for survey of the present situation. In Indonesia, conducted were the study of information system and culture collection, study of plant utilization technology, study of utilization technology of bacteria, etc., and improvement in personnel, facilities and maintenance management power of research cooperation institutes was confirmed. In Thailand and Malaysia, conducted were the study of information system and culture collection, study of rule making of the access profit distribution to genetic resource, and management of the biological resource sampled and study of the route to the industrial utilization. Taking advantage of this project, the contract for the genetic resource search for commercial purpose was agreed between a Japanese company and a Malaysian institute. (NEDO)

  9. FY 1999 research cooperation project - the research cooperation on the protection of biodiversity and sustainable use, etc. Follow-up; 1999 nendo seibutsu tayosei hozen to jizokuteki riyo nado ni kansuru kenkyu kyoryoku. Follow up

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The follow-up for the research cooperation for Indonesia, Malaysia and Thailand was conducted to make it possible that developing countries themselves protect biological resources in the tropical area, etc. and make the sustainable use of biological resources using bio-technology. In Indonesia, the follow-up was to be made for proceeding with the joint study for 'The study on the plant utilization technology - search for useful plant ingredients' reported by Professor Koshimizu, Kinki University. In Malaysia, considering that equipment is enough installed there and research leaders are very excellent, it is considered that the country is suitable for the partner of future joint research on microorganisms with Japan. Moreover, the merit in joint study is the cooperation in study of information system and culture collection. In Thailand, Japan told them that the study theme has to be made smaller toward the culture collection rich in content and the search for useful plants/bacteria. (NEDO)

  10. FY 2000 report on the survey of the technology trend of a future of the plant use bioindustry; 2000 nendo shokubutsu riyo bio sangyo no shoraisei ni kansuru gijutsu doko chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of studying a future of the industrial application of plant use biotechnology, survey was conducted of the trend of the present international technology, etc. As to the system of the joint research/development program in Europe, there are Framework Program (FP) by European Commission and cooperative programs (EUREKA) supported by European Commission. The total budget of Framework Program 5 (FP5) project is 14.96 billion euro, and 82 of the total 1,799 projects are related to the plant biotechnology. The largest plant biotechnology research organization is the U.S. Department of Agriculture (USDA), and the budget of plant biotechnology is 300 million dollars. BTI, private nonprofit research organization, has been producing the results of the study of plant genes and study related to the agriculture biotechnology. In Japan, the Ministry of Economy, Trade and Industry is carrying out the plant factory project by Green Biology Program, targeting the industrial utilization. The Ministry of Agriculture, Forestry and Fisheries of Japan started the 21st Century Green Frontier Research toward the post-genome. (NEDO)

  11. Effects on annual cost of solar/air-heat utilization system of carbon tax and interest rate for a residential house; Jutakuyo taiyo/taikinetsu riyo system no nenkan keihi ni oyobosu tansozei kinri no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Q; Kenmoku, Y; Sakakibara, T [Toyohashi University of Technology, Aichi (Japan); Nakagawa, S [Maizuru National College of Technology, Kyoto (Japan); Kawamoto, T [Shizuoka University, Shizuoka (Japan). Faculty of Engineering

    1996-10-27

    In recent years, a system has been proposed that utilizes river heat, air-heat, exhaust heat from a cooler, etc., in addition to natural energy for the heat pump. With the introduction of such system, the amount of energy used and that of CO2 exhaust will be greatly reduced, but annual expenses will be increased as it stands. In order to improve the cost efficiency of the system, a proposal has been made for the introduction of an economic policy such as the carbon tax and a low interest financing system. With these matters in the background, the subject study predicts the production of solar cells in the future and, on the basis of this production, determines the price, conversion efficiency and equipment energy of solar cells in the future. Using these values and taking into consideration the introduction of the carbon tax and the low interest financing system, the optimum area was determined for solar cells and heat concentrators in a future residential solar/air-heat energy system. The carbon tax, being imposed on all CO2 discharges, had a large effect. Moreover, as the tax increased, annual expenses decreased for the solar/air-heat system. 3 refs., 6 figs.

  12. Survey on utilization of database for research and development of global environmental industry technology; Chikyu kankyo sangyo gijutsu kenkyu kaihatsu no tame no database nado no riyo ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    1993-03-01

    To optimize networks and database systems for promotion of the industry technology development contributing to the solution of the global environmental problem, studies are made on reusable information resource and its utilization methods. As reusable information resource, there are external database and network system for researchers` information exchange and for computer use. The external database includes commercial database and academic database. As commercial database, 6 agents and 13 service systems are selected. As academic database, there are NACSIS-IR and the database which is connected with INTERNET in the U.S. These are used in connection with the UNIX academic research network called INTERNET. For connection with INTERNET, a commercial UNIX network service called IIJ which starts service in April 1993 can be used. However, personal computer communication network is used for the time being. 6 figs., 4 tabs.

  13. Worldwide clean energy system technology using hydrogen (WE-NET). subtask 9. Investigation of innovative and leading technologies; Suiso riyo kokusai clean energy system gijutsu (WE-NET). subtask 9. Kakushinteki sendoteki gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The WE-NET Project is a long-term project designed to ensure that an energy network technology using hydrogen becomes a reality not later than 2020. So the project cannot remain effective unless constant efforts are made to foresee future trends of technology and optimize it as the making of entire system for the project. In this project, new technologies which are not up for development are also investigated. Their feasibility should be studied, if necessary. From the foregoing point of view, new technologies are studied, collected and evaluated. Thus, useful suggestions and proposals may be made as to the course for the project to follow, as well as its research and development. Proposals highly evaluated up to FY 1995 are the hydrogen-oxygen internal-combustion Stirling`s engine, hydrogen production by solid oxide electrolysis, magnetic refrigeration technology for liquefaction of hydrogen, solar thermal hydrogen production with iron sponge technology, and hydrogen producing technology with photocatalyst. Conceptual investigation themes in FY 1996 are the hydrogen internal-combustion Stirling engine, solar thermal hydrogen production, phototransformation process, and high-temperature steam electrolysis. 9 figs., 54 tabs.

  14. Fiscal 1999 survey report. Survey on use of reproducible energy in Oceania and on feasibility of future introduction; Oseania ni okeru saisei kano energy riyo jokyo to kongo no kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Survey was conducted on the actual state and the potentiality of reusable energy (RE) in the South Pacific nations. The countries to be surveyed were Australia, New Zealand, Papua New Guinea, the Fiji, the Republic of the Marshall Islands, and the Republic of Nauru. The subject RE are photovoltaic power (PV), solar heat, wind force, biomass, hydraulic power and geotherm. The survey items were as follows; RE policy and promotion programs, technical level of makers, RE supply areas and population for independent/linking type electric power systems, population of non-electrification areas, meteorological data, foreign investment policy, feasibility for introduction if RE not yet introduced, and potential of promotion if RE already introduced. Propositions are as follows. Australia and New Zealand, having a comparatively large population and a stable government, are the two most important markets for RE technologies. The South Pacific nations have a markedly small population, providing a limited market for RE systems. Papua New Guinea, being a country possessing natural gas resources, has a chance of developing photovoltaic and fossil energy hybrid systems. The Fiji shows possibility for hydraulic, wind force and biomass power generation. (NEDO)

  15. Development of a material for preventing fluidization of asphalt laid on a road by using coal-ash. Sekitan hai riyo ni yoru asufaruto hoso ryudoka boshizai no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, T. (Tohoku Electric Power Co. Inc., Sendai (Japan). Electric Power Engineering Lab.); Yamada, Y. (Taiseirotec Corp., Tokyo (Japan)); Chiba, Y. (Ministry of Construction, Tokyo (Japan))

    1993-05-30

    Currently, although prevention of fluidization of asphalt using modified asphalt mixed with resin and rubber has been taken, application of such a fluidization prevention means is limited, due to the reasons of high cost and difficult quality control, particularly mainly to places in the vicinity of intersections where the traffic is heavy, on bridges and in tunnels where construction is difficult. In addition, although low penetration asphalt is used, in this case, there are problems of deterioration of wear resistance and of cracks caused by temperature stress at low temperatures. The writers have conducted a study of imparting asphalt a fluidization resistance by adsorbing light oil in asphalt on a coal-ash fluidization preventing agent (FB) mixed in advance in an asphalt mixture. This article reports a study about the influence of mixing ratio and grain size of coal-ash upon the anti-fluidization property and durability of asphalt when coal-ash discharged from coal thermal power plants is mixed into asphalt, and a confirmation of the effectiveness of the mixing of coal-ash by actual road tests. 6 refs., 22 figs., 11 tabs.

  16. Fiscal 1995 survey report on the environmentally friendly type coal utilization system introduction support project. Verification project on the circulating fluidized bed boiler; Kankyo chowagata sekitan riyo system donyu shien jigyo. Junkan ryudosho boiler ni kakawaru jissho jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-01

    In relation to the circulating fluidized bed boiler which reduces the amount of sulfur oxides emitted in coal utilization, a verification project was carried out on installation of the equipment and spread activity in China and the Philippines contributing to the control of environmental pollutant associated with coal utilization and the effective use of energy. At the Fanshan area, installed was a 10t/h internal circulating fluidized bed boiler. At the performance test, coal includes around 7% of impurities such as stone, and the impurities should be excluded continuously at the time of actual run. Therefore, the boiler efficiency had to be changed from 89.5% to 85.8%. Further, power generation facilities have not yet been finished, and the overall operation of boiler turbine has not been executed. At the Zibo area, a 30t/h external circulating fluidized bed boiler was installed. The boiler efficiency reached 86.1%, over the targeted value. At the Batangas area in the Philippines, a 10t/h internal circulating fluidized bed boiler was installed. The boiler efficiency reached 85.8%, over the designed value. About the coal produced in the Philippines, slagging was feared, but the combustion state was favorable. 82 figs., 21 tabs.

  17. Utilization of two-way multicore cables and comparison of various electrode configurations in electrical prospecting; Denki tansa ni okeru sohokogata tashin cable no riyo to kakushu dekyoku haichi no hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Takakura, S [Geological Survey of Japan, Tsukuba (Japan); Matsushima, J [The University of Tokyo, Tokyo (Japan). Faculty of Engineering

    1996-10-01

    For more precise electrical prospecting, the new multicore cable was developed to allow high-density measurement by conventional equipment. Since conventional multicore cables are inferior in cost, length and weight, the new cable is composed of an n-conductor cable, two n-conductor male connectors and n lead wires. For connection of the multi-conductor cable and lead wires, cable sheath is peeled at n points at specific intervals. Sheath of the k-th conductor is peeled at k-th point from the terminal, and restored for insulation after connection of the conductor and lead wire. The male connectors are attached to the both ends of the multi-conductor cable. Since this two-way type cable can be used at every end, the measuring equipment can measure at one divisional point after another of a long measuring line while shifting the equipment from one point to another. All measurements are perfected only with two short cables. Resistivities were successfully measured along the long measuring line of 480m long with 97 electrodes arranged at intervals of 5m. Various electrode configurations were also compared. 1 ref., 4 figs., 2 tabs.

  18. Fiscal 1998 research cooperation project. Research cooperation on diversity preservation and sustainable use for living organisms; 1998 nendo seibutsu tayosei hozen to jizokuteki riyo nado ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This report describes the titled research cooperation. Joint R and D with Thailand, Indonesia and Malaysia was made on collection and preservation of bio-resources such as tropical rain forest, and sustainable use of them by developing countries themselves. The project includes the simple identification and preservation technology of biospecies such as microorganism, assessment and monitoring technology of ecosystem, search of useful functions of biospecies, and construction of a bio-resource information network. This project promotes conversion of excessive hunting into resource conservation in agriculture, forestry and fisheries industries, and establishment of the basis of new product development in chemical and pharmaceutical industries. This project also contributes to preparation of the basic scheme of developed countries including Japan to countries holding bio-resources in addition to industrial basis preparation of every country. Until 1997, basis establishment has been made such as training of researchers, preparation of equipment and technical guidance, and in the final 1998, various results such as extraction of promising samples from microorganisms were obtained. (NEDO)

  19. Simulation study on reduction of peak power demand and energy consumption in residential houses with solar thermal and PV systems; Taiyo energy riyo jutaku no fuka heijunka oyobi energy sakugen koka no simulation ni yoru kento

    Energy Technology Data Exchange (ETDEWEB)

    Endo, T. [Yokohama City Office, Yokohama (Japan); Udagawa, M. [Kogakuin Univ., Tokyo (Japan). Faculty of Engineering

    1995-11-20

    In this study, taking the all factors involved in the energy consumption in residential houses as subjects, the effectiveness of the solar PV system and solar thermal utilizing system in residential houses has been studied by simulating a model residential house considering the improvement of the residual environment in the future. Therefore, a model residual house is assumed, 18 kinds of combinations of construction style, cooling and heating type and solar energy utilizing form are assumed and year round simulation is carried out. The conclusions obtained by the simulation are as follows. The energy consumption in residential houses may decrease greatly by using a solar hot water supplying system. If combined with a solar PV system, the energy consumption in one year is about 8.7 to 9.7 MWh. The combined use of a solar thermal utilizing system and a PV system is more effective to reduce the second-time energy in comparison with the PV system only. 36% of the space heating energy consumption may be decreased by using the solar space heating system, but the decrease effect of the energy consumption of the solar space heating system is smaller than the solar hot water supplying system. 12 refs., 26 figs., 3 tabs.

  20. Research report for fiscal 1998 on the basic research on the promotion of joint implementation and so forth. Coalbed methane collection and utilization project in China; 1998 nendo Chugoku ni okeru tanko methane gas kaishu riyo project chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    China is surveyed for promotion of joint implementation, which is one of the flexibility measures in the Kyoto Protocol, the Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change. The project aims to collect methane for global warming suppression and to use it as town gas and for power generation as well. The survey covers the 2 coalfields of Yangquan and Panjiang. The Yangquan coalfield is the largest anthracite yielding base in China, with 6 mines in operation. Power generation centering on a 100MW plant is discussed, and generation fired by a mixture of debris out of the coal preparation facility and gas is compared with another fired by town gas, on the assumption that 130-million m{sup 3} is available under the current circumstances. In the case of the Panjiang coalfield, which is expected to develop into a large coal base in the southern part of China, power generation centering on a 50MW plant fired by a mixture of debris and gas is discussed, on the assumption that 63-million m{sup 3} is collectable from the existing 5 mines. Use of town gas is also studied. When Japan's coalbed methane collection technology is applied, the gas drainage rate will be elevated to 40-35% or higher. It is desired that the use of gas drainage will be further diffused for the prevention of disasters of coal mine gas explosion. It is hoped that the use of environmentally friendly energies will be enhanced. (NEDO)

  1. Reduction of energy essential to human life by 70%. Environment-friendly residence `ED-1` utilizing the sunlight effectively; Seikatsu ni hitsuyona energy no 70% sakugen. Taiyoko riyo no kankyo kyosei jutaku ED-1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-09-01

    This paper presents the environment-friendly residence `ED-1` utilizing the sunlight effectively. ED-1 of 97m{sup 2} in first floor area and 81m{sup 2} in second one has, on its roof, the photovoltaic power generation system, the solar hot water collector which supplies hot water by circulating heated antifreezing solution into a hot storage tank, and the solar hot wind collector which largely contributes to energy saving together with a hot room named an S unit on the first floor. The small S unit faced toward the south adjacent to a dining room is made of timber and thermal insulation glass. The S unit stores heat in a floor by taking the sunlight into a room in winter, while enhances a heating effect by discharging stored heat in nighttime. In some cases, duct circulation of heated wind is possible. Solar radiation of 90% can be removed by outside glass fiber screen of the S unit together with double glazing coated by special metal film. Roof material is superior in heat insulation, air tightness and energy saving, while floor material in sound insulation and heat storage. The target for reducing energy essential to human life by 70% was thus nearly achieved. 1 fig.

  2. Report on achievements in fiscal 1984 on research and development commissioned from Sunshine Project. Studies on hydrogen manufacturing utilizing solar beam; 1984 nendo taiyoko riyo ni yoru suiso seizo no kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1985-03-01

    Research and development has been performed on a technology to manufacture hydrogen effectively from water utilizing solar beam and using an organics oxidizing and reducing system as the intermediary, and its achievements in fiscal 1984 was reported. With regard to the process in hydrogen generation stage as the first step, water dissolvable rhodium complex was synthesized to improve the process having been developed in the previous fiscal year. Its photo-hydrogen generation capability was discussed. In the rhodium complex of ligand having sulfonic acid group for water solution, a system using only water as a solvent was discovered to show the photo-hydrogen generation capability equivalent to or greater than the system of organic solvent and water using non-water dissolvable rhodium complex. In the stage of reduction of oxidized type organics by water as the second step, discussions were given on photo-electrochemical behavior of iron oxide sintered electrodes. Photo-hydrogen generation was investigated by retaining the electrode potential to a potential generated by beam irradiation onto the iron oxide sintered electrodes, and using a system of water dissolvable rhodium complex and rhuthenium complex. As a result, a possibility of recycling the materials was discovered. (NEDO)

  3. Fiscal 1998 research report on information structuring technology for advanced use of NEDO research reports; 1998 nendo NEDO seika hokokusho nado no kodo riyo ni hitsuyona joho kozoka gijutsu no chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Research was made on electronic NEDO research reports corresponding to the recent extending trend of Internet. The logical structure and electronic format of NEDO research reports as document were first studied considering document disclosure and reuse of technical information. HTML as electronic format for Internet is unfortunately insufficient to describe the logical structure of NEDO research reports because of HTML's restricted description. Thus, XML which is being watched because of its possible definition of original tags was studied in place of HTML. As a result, because at present preparation of standards on XML and a compatibility for implementation of standards are insufficient, it was concluded that construction of the electronic document system for NEDO research reports is still too early. However, since adoption of XML as document format is important from the viewpoint of a property succession on Internet, preparation of the XML format file of NEDO research reports is essential. (NEDO)

  4. Research program for environmentally-friendly coal utilization system. Follow-up project for simplified desulfurizers (Weifang Chemical Industry Works); Kankyo chowagata sekitan riyo system donyu shien jigyo. Kan`i datsuryu setsubi ni kakawaru follow up jigyo (Weifang kakosho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    To suppress the emission of environmental pollutants from coal utilization in China and to contribute to stable security of Japan`s energy, demonstration of clean coal technology and consolidation of diffusion base to be introduced into China have been promoted. Demonstration program for diffusing simplified desulfurizers has been promoted. For accelerating the achievement, experts of desulfurizers were delegated to Weifang Chemical Industry Works, to support the program. Exhaust gas is introduced from boiler via water spray dust remover, suction fan and centralized stack into absorption tower of the simplified wet-type desulfurizer. In the ascending process, the exhaust gas contacts with absorbent, to remove SO2 and dust. The absorbent is blasted up through the spray nozzle. The absorbent is oxidized by the air into sulfate ion in the liquid chamber at the lower part of tower, and neutralized by hydrated lime to form gypsum. Through the continuous operation for two years, understandings were remarkably increased. However, good treatment of the tax system is required for further diffusion. Though there are no problems for ordinary start and stop, emergency operation is insufficient. There are some problems in the maintenance due to the delay of finding failures. 16 figs., 1 tab.

  5. FY 1999 research cooperation project - the research cooperation on the protection of biodiversity and sustainable use, etc. Follow-up; 1999 nendo seibutsu tayosei hozen to jizokuteki riyo nado ni kansuru kenkyu kyoryoku. Follow up

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The follow-up for the research cooperation for Indonesia, Malaysia and Thailand was conducted to make it possible that developing countries themselves protect biological resources in the tropical area, etc. and make the sustainable use of biological resources using bio-technology. In Indonesia, the follow-up was to be made for proceeding with the joint study for 'The study on the plant utilization technology - search for useful plant ingredients' reported by Professor Koshimizu, Kinki University. In Malaysia, considering that equipment is enough installed there and research leaders are very excellent, it is considered that the country is suitable for the partner of future joint research on microorganisms with Japan. Moreover, the merit in joint study is the cooperation in study of information system and culture collection. In Thailand, Japan told them that the study theme has to be made smaller toward the culture collection rich in content and the search for useful plants/bacteria. (NEDO)

  6. Fiscal 2000 survey report on project for promoting international cooperation. Survey on coal utilization in APEC region (Coal note); 2000 nendo kokusai kyoryoku suishin jigyo chosa hokokusho. APEC iki nai ni okeru sekitan riyo jokyo tou chosa (Koru note)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With the purpose of contributing to the infrastructure for promoting clean coal technology (CCT), there were compiled as the 'coal note' various kinds of coal-related information in China, Indonesia, Philippine, Thailand and Vietnam among APEC countries. Concerning China, for example, economic growth and energy supply/demand in the category of the energy outline were described in detail; as were the guiding principle. individual guidance plan, and specific energy policy of the 10th five year plan, in the category of the energy policy; coal deposits, geological summary, coal quality in each coal forming period, and the status quo of development, in the category of the coal mines and development; coal supply/demand, production, consumption, and export, in the category of the present status of the coal industry; producers, sales, quality of product coal, distribution, and price, in the category of the domestic supply; present state of environmental problems relating to coal, and environmental measures intended for coal, in the category of the coal-related environmental issues; and development, production, coal cleaning, quality control, safety control, and utilization (combustion, liquefaction and gasification), in the category of coal utilization technology, respectively. (NEDO)

  7. Fiscal 1998 research report. Study on the feasibility of microorganism biotechnology for effective use of environmental pollutants. Pt. 2; 1998 nendochosa hokokusho. Kankyo osen busshitsu no shigenka no tame no biseibutsu bio technology riyo kanosei ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Study was made on the feasibility of microorganism biotechnology for effective use of environmental pollutants and unused resources. Microorganisms and microorganism enzymes for decomposing lignocellulose were viewed, and uses of hydrolysis products were summarized. Production of microorganisms applicable to fodder, composting, and production of energy sources (methane, hydrogen, ethanol) were studied. Use of vegetable fiber residues such as beer lees as fungus cultivation medium and conversion to valuable substances were also studied. Microorganisms treatment (MT) of wastes in fats and oils industry was summarized. Effective use of MT of protein waste from marine products was studied. MT of manures with the greatest impact on environment as livestock waste was summarized. The necessity of separate collection of domestic wastes, and composting and methane fermentation of kitchen garbage were reported. The feasibility of MT of plastic wastes, and decomposition of halogenated methane with high toxicity were also studied. (NEDO)

  8. Hybrid utilization of solar energy. Part 2. Performance analyses of heating system with air hybrid collector; Taiyo energy no hybrid riyo ni kansuru kenkyu. 2. Kuki shunetsu hybrid collector wo mochiita danbo system no seino hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Yoshinaga, M; Okumiya, M [Nagoya University, Nagoya (Japan)

    1996-10-27

    For the effective utilization of solar energy at houses, a heating system using an air hybrid collector (capable of simultaneously performing heat collection and photovoltaic power generation). As the specimen house, a wooden house of a total floor area of 120m{sup 2} was simulated. Collected air is fanned into a crushed stone heat accumulator (capable of storing one day`s collection) or into a living room. The output of solar cell arrays is put into a heat pump (capable of handling a maximum hourly load of 36,327kJ/h) via an inverter so as to drive the fan (corresponding to average insolation on the heat collecting plate of 10.7MJ/hm{sup 2} and heat collecting efficiency of 40%), and shortage in power if any is supplied from the system interconnection. A hybrid collector, as compared with the conventional air collector, is lower in thermal efficiency but the merit that it exhibits with respect to power generation is far greater than what is needed to counterbalance the demerit. When the hybrid system is in heating operation, there is an ideal heat cycle of collection, accumulation, and radiation when the load is light, but the balance between accumulation and radiation is disturbed when the load is heavy. 4 refs., 8 figs., 3 tabs.

  9. Solid electrolyte membranes and the system to produce hydrogen from thermally decomposed water by solar energy; Taiyo energy riyo ni yoru mizu no chokusetsu netsubunkai kara no suiso seizoyo

    Energy Technology Data Exchange (ETDEWEB)

    Nigara, K; Watanabe, K; Kawamura, K; Kawada, T; Mizusaki, J; Ishigame, M [Tohoku University, Sendai (Japan). Research Institute for Scientific Measurements

    1996-10-27

    For conversion of solar heat to transportable energy, hydrogen production by direct thermal decomposition of water using concentrated high-temperature solar heat was studied. Water vapor is injected into the tubular target with high melting point and high oxygen permeability at high temperature while heating the target by concentrated solar heat over 2000K. Oxygen in decomposed gas is discharged through an oxygen permeable membrane to extract hydrogen. Solid electrolyte is used as one of the target materials. Oxygen gas in the high-oxygen partial pressure site changes into oxygen ion by accepting two electrons at the target surface, and returns to neutral oxygen gas in the low-oxygen partial pressure site by discharging two electrons at the surface after permeation through oxygen vacancy. In the case of n-type solid electrolyte, to obtain constant permeation of a large amount of oxygen, flow of a large amount of electrons is indispensable in the opposite direction to oxygen ion. Among [(ZrO2)(1-x)(CeO2)x](0.9)(CaO)(0.1), materials of 0.4-0.5 in x seems to be useful as the target material. 7 refs., 7 figs.

  10. Practical use of dry desulfurization equipment using coal ash and effective use of used desulfurizer. Sekitanbai riyo kanshiki datsuryu sochi no jitsuyoka to shiyozumi datsuryuzai no yukoriyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, T.; Ueno, T. (The Hokkaido Electric Power CO. Inc., Hokkaido (Japan))

    1992-01-30

    Practical use of dry desulfurization equipment using coal ash installed in Atsuma power plant no.1 is explained. Outline of dry desulferization process is consisted of basic principles and structure of the process which includes desulfurizer production equipment and absorption equipment. When compared with conventional wet process, equipments for waste water and for reheating of exhaust gas are not necessary, and operation maintenance has been more convenient with the simplification of the system and absorber has graded up the elimination function. Advantages of simplification of treatment of used desulfurizer, and absorption of sulfurdioxide by desulfurizer together with characteristics of desulfurizer production are given. As far as practical macineries are concerned, outline of instrument facilities, construction technology and results of experimental operation are reported. Effective Use of desulfurizer using deodorant and hedro treatment has been verified from ammonium absorption experiment and practical investigation results. However use of hedro material has required, conformity of surface caking technology, under water caking technology, under water covering technology and effect on under water living environment. 13 figs., 4 tabs.

  11. Nanostructure analysis of friction welded Pd-Ni-P/Pd-Cu-Ni-P metallic glass interface

    International Nuclear Information System (INIS)

    Ohkubo, T.; Shoji, S.; Kawamura, Y.; Hono, K.

    2005-01-01

    Friction welded Pd 40 Ni 40 P 20 /Pd 40 Cu 30 Ni 10 P 20 metallic glass interface has been characterized by energy filtering transmission electron microscopy. The interface is fully amorphous with a gradual compositional change of Cu and Ni in the range of 30 nm. By annealing above T g , the interdiffusion of Cu and Ni progressed in the supercooled liquid region, and the crystallization occurred from the Pd 40 Ni 40 P 20 glass

  12. Study of dipole interaction in micron-width NiFe/Cu/NiFe/NiO wire using exchange anisotropy

    International Nuclear Information System (INIS)

    Kimura, Takashi; Itagaki, Yoshio; Wakaya, Fujio; Gamo, Kenji

    2001-01-01

    The dipole interaction between a NiFe layer pinned by a NiO and a free NiFe layer in a micron-wide NiFe/Cu/NiFe/NiO wire was studied by changing the direction of the exchange bias from the NiO layer. The effect of the dipole interaction when the exchange bias was perpendicular to the wire axis was larger than that when the exchange bias was parallel to the wire axis, and was consistently explained by the stray field caused by the magnetic charges of the pinned layer. It was demonstrated that this method, using exchange anisotropy, is useful for investigating the dipole interaction between ferromagnetic materials separated by a nonmagnetic material in small-scale magnetic multilayers. [copyright] 2001 American Institute of Physics

  13. Effects of Ni particle morphology on cell performance of Na/NiCl2 battery

    Science.gov (United States)

    Kim, Mangi; Ahn, Cheol-Woo; Hahn, Byung-Dong; Jung, Keeyoung; Park, Yoon-Cheol; Cho, Nam-ung; Lee, Heesoo; Choi, Joon-Hwan

    2017-11-01

    Electrochemical reaction of Ni particle, one of active cathode materials in the Na/NiCl2 battery, occurs on the particle surface. The NiCl2 layer formed on the Ni particle surface during charging can disconnect the electron conduction path through Ni particles because the NiCl2 layer has very low conductivity. The morphology and size of Ni particles, therefore, need to be controlled to obtain high charge capacity and excellent cyclic retention. Effects of the Ni particle size on the cell performance were investigated using spherical Ni particles with diameters of 0.5 μm, 6 μm, and 50 μm. The charge capacities of the cells with spherical Ni particles increased when the Ni particle size becomes smaller because of their higher surface area but their charge capacities were significantly decreased with increasing cyclic tests owing to the disconnection of electron conduction path. The inferior cyclic retention of charge capacity was improved using reticular Ni particles which maintained the reliable connection for the electron conduction in the Na/NiCl2 battery. The charge capacity of the cell with the reticular Ni particles was higher than the cell with the small-sized spherical Ni particles approximately by 26% at 30th cycle.

  14. Fiscal 1997 report on the results of the international research cooperation project for a feasibility survey for finding out seeds of the international joint research. Effective use technology of saturated hydrocarbon (technology against the surplus aromatic hydrocarbon/technology of high grade treatment of petroleum coke); 1997 nendo kokusai kenkyu kyoryoku jigyo (kokusai kyodo kenkyu seeds hakkutsu no tame no FS chosa). Howa tanka suiso no yuko riyo gijutsu / hokozoku tanka suiso no yojo taisaku gijutsu / sekiyu cokes no kodo shori gijutsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    For the purpose of the effective international research cooperation, the paper surveyed in fiscal 1997 the effective use technology of saturated hydrocarbon, technology against the surplus aromatic hydrocarbon and technology of high grade treatment of petroleum coke. In the survey of the effective use technology of saturated hydrocarbon, trends of FT synthesis technology and DME synthesis technology were studied as trends of technology to produce synthetic gas, and a project was proposed for technical development of using natural gas as liquid fuel in Japan. In the survey of technology against the surplus aromatic hydrocarbon, studied were the benzene law regulation and the supply/demand trend of aromatic hydrocarbon, process to reduce production of aromatic hydrocarbon as much as possible, process to reduce aromatics of the produced petroleum products, and process to effectively use aromatic hydrocarbon as chemical raw material. In the survey of high grade treatment of petroleum coke, studied were a possibility of using HS petroleum coke in the DIOS method, iron bath gasification, and copper bath gasification technology. 108 refs., 146 figs., 103 tabs.

  15. One dimensional motion of interstitial clusters and void growth in Ni and Ni alloys

    Science.gov (United States)

    Yoshiie, T.; Ishizaki, T.; Xu, Q.; Satoh, Y.; Kiritani, M.

    2002-12-01

    One dimensional (1-D) motion of interstitial clusters is important for the microstructural evolution in metals. In this paper, the effect of 2 at.% alloying with elements Si (volume size factor to Ni: -5.81%), Cu (7.18%), Ge (14.76%) and Sn (74.08%) in Ni on 1-D motion of interstitial clusters and void growth was studied. In neutron irradiated pure Ni, Ni-Cu and Ni-Ge, well developed dislocation networks and voids in the matrix, and no defects near grain boundaries were observed at 573 K to a dose of 0.4 dpa by transmission electron microscopy. No voids were formed and only interstitial type dislocation loops were observed near grain boundaries in Ni-Si and Ni-Sn. The reaction kinetics analysis which included the point defect flow into planar sink revealed the existence of 1-D motion of interstitial clusters in Ni, Ni-Cu and Ni-Ge, and lack of such motion in Ni-Si and Ni-Sn. In Ni-Sn and Ni-Si, the alloying elements will trap interstitial clusters and thereby reduce the cluster mobility, which lead to the reduction in void growth.

  16. First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    International Nuclear Information System (INIS)

    Yun-Jiang, Wang; Chong-Yu, Wang

    2009-01-01

    A model system consisting of Ni[001](100)/Ni 3 Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni 3 Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni 3 Al multilayer can be well predicted by the Voigt–Reuss–Hill rule of mixtures. (classical areas of phenomenology)

  17. Flowsheet for 63Ni production

    International Nuclear Information System (INIS)

    Williams, D.F.; Knauer, J.B.; O'Kelley, G.D.; Wiggins, J.T.; Porter, C.E.

    1992-01-01

    The production of large quantities of high specific activity 63 Ni (>10Ci/g) requires both a highly enriched 62 Ni target and a long irradiation period at high neutron flux. Trace impurities in the nickel and associated target materials are also activated and account for a significant fraction of the discharged activity and essentially all of the gamma activity. While most of these undesirable activation products (mainly transition metals) can be easily removed as chloride complexes during anion exchange, chromium, present as 51 Cr, and manganese, present as 54 Mn, are exceptions and require solvent extraction of the in-cell product to achieve the desired purity. In addition to summarizing the current development and production experience, optimized flowsheets are discussed

  18. Microstructural investigations of Ni and Ni2Al3 coatings exposed in biomass power plants

    DEFF Research Database (Denmark)

    Wu, D. L.; Dahl, K. V.; Christiansen, T. L.

    2018-01-01

    The present work investigates the corrosion resistance of Ni and Ni2Al3 coated austenitic stainless steel (TP347H) tubes, which were exposed in a biomass-fired boiler with an outlet steam temperature of 540 °C for 6757 h. The Ni2Al3 coating was produced by electroplating Ni followed by low...... temperature pack cementation. After exposure, microstructural investigations were performed by light optical and electron microscopy (SEM-EDS). Electroplated Ni coatings were not protective in straw firing power plants and exhibited similar corrosion morphology as uncoated tubes. For Ni2Al3 coatings...

  19. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Gagorowska, B; Dus-Sitek, M [Institute of Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Czestochowa (Poland)

    2007-08-15

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d{sub Cu} = 2 nm) and the thickness of Ni layer - variable (1 nm {<=} d{sub Ni} {<=} 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent.

  20. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    International Nuclear Information System (INIS)

    Gagorowska, B; Dus-Sitek, M

    2007-01-01

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d Cu = 2 nm) and the thickness of Ni layer - variable (1 nm ≤ d Ni ≤ 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent

  1. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition; Etude exclusive des collisions centrales Ni+Ni et Ni+Au: coexistence de phase et decomposition spinodale

    Energy Technology Data Exchange (ETDEWEB)

    Guiot, B

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  2. niños preescolares

    Directory of Open Access Journals (Sweden)

    Claudia Rosario Portilla Ramírez

    2007-01-01

    Full Text Available Este estudio explora la relación entre la escritura y la comprensión de la referencia a través de una tarea de sinonimia en niños entre 5 y 6 años de edad, de origen latinoamericano, escolarizados en Barcelona (España. Las variables relacionadas con la tarea de sinonimia fueron (a la comprensión de la entidad lingüística nombre y (b el nivel de conceptualización de la escritura de los niños y la presencia de etiquetas escritas durante la tarea. Para la tarea de sinonimia se utilizaron pares de sinónimos dialectales del español (de Latinoamérica y de la Península Ibérica. Los resultados mostraron una diferenciación en el razonamiento de los niños, la cual dependía de la comparación entre lenguaje oral y lenguaje escrito en el desarrollo de la tarea, evidenciando una mayor aceptación de la sinonimia en la modalidad de lenguaje oral que en la modalidad de lenguaje escrito.

  3. Reinvestigation of 56Ni decay

    International Nuclear Information System (INIS)

    Sur, B.; Norman, E.B.; Lesko, K.T.; Browne, E.; Larimer, R.

    1990-01-01

    In a series of experiments, we have reinvestigated the decay of the doubly magic nucleus 56 Ni, which is believed to be copiously produced in supernovae. We have confirmed its previously known decay scheme and half-life, and have searched for several rare decay modes. We establish an upper limit of 5.8x10 -7 for the branching ratio of the second forbidden unique β + decay to the 158-keV level in 56 Co, leading to a lower limit of 2.9x10 4 yr for the half-life of fully ionized 56 Ni nuclei in cosmic rays. We also establish an upper limit of 5.0x10 -3 for the branching ratio of the isospin forbidden Fermi electron capture transition to the 1451-keV level in 56 Co, which in turn leads to an upper limit of 124 keV for the isospin mixing Coulomb matrix element of the 56 Ni ground state

  4. On the nature of Ni···Ni interaction in a model dimeric Ni complex.

    Science.gov (United States)

    Kamiński, Radosław; Herbaczyńska, Beata; Srebro, Monika; Pietrzykowski, Antoni; Michalak, Artur; Jerzykiewicz, Lucjan B; Woźniak, Krzysztof

    2011-06-07

    A new dinuclear complex (NiC(5)H(4)SiMe(2)CHCH(2))(2) (2) was prepared by reacting nickelocene derivative [(C(5)H(4)SiMe(2)CH=CH(2))(2)Ni] (1) with methyllithium (MeLi). Good quality crystals were subjected to a high-resolution X-ray measurement. Subsequent multipole refinement yielded accurate description of electron density distribution. Detailed inspection of experimental electron density in Ni···Ni contact revealed that the nickel atoms are bonded and significant deformation of the metal valence shell is related to different populations of the d-orbitals. The existence of the Ni···Ni bond path explains the lack of unpaired electrons in the complex due to a possible exchange channel.

  5. Achievement report for fiscal 1976 on Sunshine Program. Comprehensive examination of hydrogen-utilizing subsystems and research on peripheral technologies (Survey and research on hydrogen production by quinon method); 1976 nendo suiso riyo subsystem no sototeki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Kinonho ni yoru suiso seizoho ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-03-01

    The quantum yield and conversion efficiency are measured during photosensitized water decomposition at an n-type TiO{sub 2} semiconductor electrode built from a rutile type single crystal, and the role of the TiO{sub 2} electrode is clearly defined. A method is tested of acquiring a photoactive TiO{sub 2} semiconductor as an oxide coating and an oxide coating electrode is fabricated, and its characteristics are determined and then compared with the above-said measurements. A WO{sub 3} semiconductor is manufactured, and its characteristics are compared with the above-said measurements. The mechanism of photosensitized decomposition at a semiconductor electrode is examined, and guidelines are established to follow for improvement on efficiency in semiconductor electrode-aided hydrogen production. Dark and light reactions are caused to occur by adding methyl viologen, potassium ferrocyanide, and potassium ferricyanide, and the photochemical reaction characteristics are clearly defined. Oxygen is generated by use of chloroplast. Use of an acrylamide membrane and an osmotic membrane enables a continuous 48-hour test. A solar beam is concentrated on a TiO{sub 2} electrode for a reaction of Q+H{sub 2}O{yields}QH{sub 2}+1/2O{sub 2}{up_arrow} to occur. A reaction of QH{sub 2}{yields}Q+H{sub 2}{up_arrow} is caused to occur as an electrode reaction. A current of 3.7mA and a voltage of 2.4mV are recorded on a fine day at the beginning of October, and 0.4mA and 0.2mV on a cloudy day. (NEDO)

  6. FY 1974 report on the results of the Sunshine Project. Comprehensive study of hydrogen use subsystem and study on the periphery technology (Investigational study on the hydrogen production method by the quinone method); 1974 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Kinonho ni yoru suiso seizoho ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-05-01

    This is aimed at making an investigational study on the hydrogen production from water by means of quinone compounds. The paper studied a preparation method in case of using n-TiO2 photosemiconductor and p-GaAs and Gap photosemiconductor to photoelectrode as catalysts of this reaction. The reaction from p-benzoquinone to p-hydroquinone by reaction with H2O were studied in terms of photochemical reaction, and light reaction/dark reaction of photosemiconductor electrode. As a result, it was found out that this reaction easily advances by the photochemical reaction by solar light, and also that it advances by the counter electrode Pt electrode reaction in the water electrolysis of n-TiO2 photosemiconductor electrode. The H2 production reaction from p-hydrogquinone was studied in terms of the photochemical reaction, photosemiconductor electrode reaction, and effects of the catalysis of electron transport of metal salts, methylviologen, etc. As a result, in the n-TiO2 photosemiconductor electrode reaction, H2 formation was not as great as it can be confirmed. However, it was found that p-hydroquinone can produce H2 under the existence of methylviologen or Fe salts. (NEDO)

  7. Synthesis of Ni core NiO shell nanostructure and magnetic investigation for shell thickness determination

    International Nuclear Information System (INIS)

    Arabi, H.; Bruck, E.; Tichelaar, F.D.

    2007-01-01

    Full text: Nickel oxide has received a considerable amount of attention in recent years for its catalytic, electronic and magnetic properties. Ni nanoparticles with an average size of 8 nm were prepared by dc - arc discharge in argon atmosphere. A current of 130 A and 300 milli bar pressure of argon have been applied. The produced Ni nanoparticles were annealed for oxidizing in air at 350 for six hours to produce antiferromagnetic NiO particles. The structure of Ni and NiO nanoparticles and size estimation of them studied by means of X-ray diffraction. The size and morphology of the particles were also characterized by high resolution transmission microscopy (TEM). The Ni core NiO shell structure, resulting from the oxidation process, were studied by magnetic properties measurements. A quantum design squid magnetometer, model MPMS5S was used for measuring saturation magnetization of both nanoparticles of Ni with and without NiO layer. By knowing the density of Ni and NiO, we were able to deduce the thickness of the Ni core and NiO outer layer. They are around 3 and 5 nanometers respectively. (authors)

  8. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition

    International Nuclear Information System (INIS)

    Guiot, B.

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  9. Atomistic calculations of hydrogen interactions with Ni3Al grain boundaries and Ni/Ni3Al interfaces

    International Nuclear Information System (INIS)

    Baskes, M.I.; Angelo, J.E.; Moody, N.R.

    1995-01-01

    Embedded Atom Method (EAM) potentials have been developed for the Ni/Al/H system. The potentials have been fit to numerous properties of this system. For example, these potentials represent the structural and elastic properties of bulk Ni, Al, Ni 3 Al, and NiAl quite well. In addition the potentials describe the solution and migration behavior of hydrogen in both nickel and aluminum. A number of calculations using these potentials have been performed. It is found that hydrogen strongly prefers sites in Ni 3 Al that are surrounded by 6 Ni atoms. Calculations of the trapping of hydrogen to a number of grain boundaries in Ni 3 Al have been performed as a function of hydrogen chemical potential at room temperature. The failure of these bicrystals under tensile stress has been examined and will be compared to the failure of pure Ni 3 Al boundaries. Boundaries containing a preponderance of nickel are severely weakened by hydrogen. In order to investigate the potential embrittlement of γ/γ' alloys, trapping of hydrogen to a spherical Ni 3 Al precipate in nickel as a function of chemical potential at room temperature has been calculated. It appears that the boundary is not a strong trap for hydrogen, hence embrittlement in these alloys is not primarily due to interactions of hydrogen with the γ/γ interface

  10. Structural features in Ni-Al alloys

    International Nuclear Information System (INIS)

    Abylkalykova, R.B.; Kveglis, L.I.; Rakhimova, U.A.; Nasokhova, Sh.B.; Tazhibaeva, G.B.

    2007-01-01

    Purpose of the work is study of structural transformations under diverse memory effect in Ni-Al alloys. Examination were conducted in following composition samples: Ni -75 at.% and Al - 25 at.%. The work is devoted to clarification reasons both formation atom-ordered structures in inter-grain boundaries of bulk samples under temperature action and static load. Revealed inter-grain inter-boundary layers in Ni-Al alloy both bulk and surface state have complicated structure

  11. Compositional and structural characterisation of Ni-phyllosilicates in hydrous silicate type Ni-laterite deposits

    OpenAIRE

    Villanova de Benavent, Cristina

    2015-01-01

    Ni-bearing Mg-phyllosilicates (commonly known as garnierites) are significant ore minerals in many Ni-laterite deposits worldwide. However, the characterisation of these mineral phases is complex, as well as their classification and nomenclature, due to their fine-grained nature, low crystallinity and frequent occurrence as mixtures. The aim of this study is to shed some light to the nature of the Ni-bearing Mg-phyllosilicates occurring at the Falcondo Ni-laterite. In this deposit, these ...

  12. Thermal capture cross section for 58Ni (n,γ)59 Ni reaction

    International Nuclear Information System (INIS)

    Carbonari, A.W.; Pecequilo, B.R.S.

    1989-01-01

    The 58 Ni total thermal capture cross section was determined by suming the partial cross sections calculated for the primary transitions of the reaction 58 Ni (n,γ) 59 Ni. The primary transitions energies and intensities were determined from the 58 Ni thermal neutrons prompt gamma capture gamma rays spectrum in the 3.7 to 9.3 MeV region. The obtained value for the total cross section was 4.52 + 0.10b. (author) [pt

  13. Formation enthalpy of NiBe and Ni5Be21

    International Nuclear Information System (INIS)

    Ivanov, M.I.; Karpova, T.F.; Dalago, N.Yu.

    1981-01-01

    The method of dissolution calorimetry is used to determine standard enthalpies of NiBe and Ni 5 Be 21 formation, which are 84.8+-2.2 and (-669+-37)kJ/mol. The enthalpy values of NiBe and Ni 5 Be 21 at 331 K are shown to coincide (within the limits of errors of these values) with the values at the standard temperature of 298.15 K [ru

  14. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua; Wu, Xiaozhi; Wang, Rui; Liu, Qing; Gan, Liyong

    2014-01-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  15. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua

    2014-12-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  16. Creep and shrinkage of Mo(Ni)

    International Nuclear Information System (INIS)

    Kaysser, W.A.; Hofmann-Amtenbrink, M.; Petzow, G.

    1984-01-01

    To avoid some of the errors inherent in a quantitative interpretation of shrinkage of powder compacts as Mo-Ni, other experiments were looked for, where the influence of Ni on the material transport properties of Mo could be measured semi-quantitatively during heating up to temperature and subsequent isothermal annealing. The bending of thin Mo foils under small loads was found to be an experimental arrangement, where variations in stress, in Ni-concentration and in intrinsic material properties could be realized. The results of these creep experiments will be compared in a qualitative sense with sintering experiments in Mo-Ni done under similar conditions as the creep experiments

  17. Structure-activity relations for Ni-containing zeolites during NO reduction. II. Role of the chemical state of Ni

    NARCIS (Netherlands)

    Mosqueda Jimenez, B.I.; Jentys, A.; Seshan, Kulathuiyer; Lercher, J.A.

    2003-01-01

    The influence of the metal in Ni-containing zeolites used as catalysts for the reduction of NO with propane and propene was studied. In the fresh catalysts, Ni is located in ion exchange positions for Ni/MOR, Ni/ZSM-5, and Ni/MCM-22. The formation of carbonaceous deposits, the removal of Al from

  18. Ni-P/Zn-Ni compositionally modulated multilayer coatings - Part 2: Corrosion and protection mechanisms

    Science.gov (United States)

    Bahadormanesh, Behrouz; Ghorbani, Mohammad

    2018-06-01

    The Ni-P/Zn-Ni compositionally modulated multilayer coatings CMMCs were electrodeposited from a single bath by switching the deposition current density. The corrosion resistance of the deposits was studied and compared with that of monolayers of Ni-P and Zn-Ni alloys via Tafel polarization, EIS and salt spray tests. Characterization of corrosion products by means of EDS and XRD revealed more details from the corrosion mechanism of the monolayers and multilayers. The corrosion current density of Ni-P/Zn-Ni CMMCs were around one tenth of Zn-Ni monolayer. The CMMC with incomplete layers performed lower polarization resistance and higher corrosion current density compared to the CMMC with complete layers. The electrical circuit that was proposed for modeling the corrosion process based on the EIS spectrum, proved that layering reduces the porosity and consequently improves the barrier properties. Although, layering of Zn-Ni layers with Ni-P deposits increased the time to red rust in salt spray test, the time for white rust formation decreased. The corrosion mechanism of both Zn-Ni and Ni-P (containing small amount of Zn) was preferential dissolution of Zn and the corrosion products were comprised of mainly Zn hydroxychloride and Zn hydroxycarbonate. Also, Ni and P did not take part in the corrosion products. Based on the electrochemical character of the layers and the morphology of the corroded surface, the corrosion mechanism of multilayers was discussed.

  19. Joining of Ni-TiC FGM and Ni-Al Intermetallics by Centrifugal Combustion Synthesis

    International Nuclear Information System (INIS)

    Ohmi, Tatsuya; Matsuura, Kiyotaka; Iguchi, Manabu; Mizuma, Kiminori

    2008-01-01

    A centrifugal combustion synthesis (CCS) process has been investigated to join a Ni-Al intermetallic compound and a Ni-TiC cermet. The cermet, a tubular graphite mold, and a green compact of reactants consisting of Al, Ni and NiO were set in a centrifugal caster. When the combustion synthesis reaction was induced in the centrifugal force field, a synthesized molten Ni-Al alloy flowed into the graphite mold and joined to the cermet. The soundness of the joint interface depended on the volume percentage of TiC phase in the cermet. A lot of defects were formed near the interface between the Ni-TiC cermet and the cast Ni-Al alloy when the volume percentage of TiC was 50% or higher. For this kind of cermet system, using a functionally graded cermet such as Ni-10 vol.%TiC/Ni-25 vol.%TiC/Ni-50 vol.%TiC overcame this difficulty. The four-point bending strength of the joined specimen consisting of the three-layered FGM cermet and cast Ni-29 mol%Al alloy was 1010 MPa which is close to the result for a Ni-29 mol%Al alloy specimen

  20. Dynamic recovery in nanocrystalline Ni

    International Nuclear Information System (INIS)

    Sun, Z.; Van Petegem, S.; Cervellino, A.; Durst, K.; Blum, W.; Van Swygenhoven, H.

    2015-01-01

    The constant flow stress reached during uniaxial deformation of electrodeposited nanocrystalline Ni reflects a quasi-stationary balance between dislocation slip and grain boundary (GB) accommodation mechanisms. Stress reduction tests allow to suppress dislocation slip and bring recovery mechanisms into the foreground. When combined with in situ X-ray diffraction it can be shown that grain boundary recovery mechanisms play an important role in producing plastic strain while hardening the microstructure. This result has a significant consequence for the parameters of thermally activated glide of dislocations, such as athermal stress and activation volume, which are traditionally derived from stress/strain rate change tests

  1. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    International Nuclear Information System (INIS)

    Chopra, Nitin; Claypoole, Leslie; Bachas, Leonidas G.

    2010-01-01

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  2. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, Nitin [University of Alabama, Department of Metallurgical and Materials Engineering, Center for Materials for Information Technology (MINT) (United States); Claypoole, Leslie [Fairmont State University (United States); Bachas, Leonidas G., E-mail: bachas@uky.ed [University of Kentucky, Department of Chemistry (United States)

    2010-10-15

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  3. Continuum mechanics simulations of NiO/Ni-YSZ composites during reduction and re-oxidation

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Frandsen, Henrik Lund; Kaiser, Andreas

    2010-01-01

    for the dimensional change arises from the volumetric change related to the phase change NiO ↔ Ni. The measurable change in bulk length is given by the ceramic YSZ backbone as a response to the stress created by the chemical strain. The different subprocesses described in the model for YSZ were elastic and anelastic...... expansion, diffusional creep, grain boundary sliding (GBS) and microcracking due to excessive stress. In the Ni/NiO phase, nonelastic strains in terms of diffusional and power law creep were implemented, and additionally for NiO deformation due to microcracking and/or pseudoplasticity. Semi...

  4. Niños y niñas como cuidadores familiares

    OpenAIRE

    María Rosa Estupiñán Aponte

    2015-01-01

    En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las ...

  5. .';.:NI~

    African Journals Online (AJOL)

    al wat ons werd was. Na middagete op 29 Junie, is ek per kar suid om die grand te gaan besigtig en om te sien hoe my stellings, van die vyandelike oogpunt, daaruit .... van Gatt se optrede moes die. Nieu-Seelanders, in 'n briljante nagaanval, met gevelde bajonette, 'n weg baan deur die vyand am daardie nag te ontvlug.

  6. Water dissociation on Ni(100) and Ni(111): Effect of surface temperature on reactivity

    International Nuclear Information System (INIS)

    Seenivasan, H.; Tiwari, Ashwani K.

    2013-01-01

    Water adsorption and dissociation on Ni(100) and Ni(111) surfaces are studied using density functional theory calculations. Water adsorbs on top site on both the surfaces, while H and OH adsorb on four fold hollow and three fold hollow (fcc) sites on Ni(100) and Ni(111), respectively. Transition states (TS) on both surfaces are identified using climbing image-nudged elastic band method. It is found that the barrier to dissociation on Ni(100) surface is slightly lower than that on Ni(111) surface. Dissociation on both the surfaces is exothermic, while the exothermicity on Ni(100) is large. To study the effect of lattice motion on the energy barrier, TS calculations are performed for various values of Q (lattice atom coordinate along the surface normal) and the change in the barrier height and position is determined. Calculations show that the energy barrier to reaction decreases with increasing Q and increases with decreasing Q on both the surfaces. Dissociation probability values at different surface temperatures are computed using semi-classical approximation. Results show that the influence of surface temperature on dissociation probability on the Ni(100) is significantly larger compared to that of Ni(111). Moreover, on Ni(100), a dramatic shift in energy barrier to lower incident energy values is observed with increasing surface temperature, while the shift is smaller in the case of Ni(111)

  7. Creatividad en niños superdotados

    OpenAIRE

    González Román, María del Pilar

    1992-01-01

    Se ha realizado un estudio sobre la creatividad en los niños superdotados. Analizándose los diferentes modelos de creatividad y superdotacion avalados por un estudio empírico, en el cual se han valorado las diferencial que existen entre los niños superdotados y contraste a nivel verbal y grafico-espacial.

  8. Preparation of one-step NiO/Ni-CGO composites using factorial design

    International Nuclear Information System (INIS)

    Araujo, A.J.M. de; Sousa, A R.O. de; Camposa, L.F.A.; Macedo, D.A.; Loureiro, F. J.A.; Fagg, D.P.

    2016-01-01

    This work deals with the synthesis, processing and characterization of NiO/Ni- CGO composite materials as potential solid oxide fuel cell (SOFC) anodes. The particulate materials were obtained by a one-step synthesis method and characterized by thermal analysis (prior to calcination) and X-ray diffraction (calcined powder). The ceramic processing of samples containing from 30 to 70 wt.% NiO was carried out by factorial design. Besides the NiO content controlled during the chemical synthesis, the impacts of the pore-former content (citric acid, used in proportions of 0, 7.5 and 15 wt.%) and the sintering temperature (1300, 1350 and 1400 °C) were also investigated. The open porosity of NiO-CGO composites and reduced Ni-CGO cermets was modeled as a function of factors (NiO content, citric acid content and sintering temperature) and interaction of factors. (author)

  9. Nanoscale structural heterogeneity in Ni-rich half-Heusler TiNiSn

    International Nuclear Information System (INIS)

    Douglas, Jason E.; Pollock, Tresa M.; Chater, Philip A.; Brown, Craig M.; Seshadri, Ram

    2014-01-01

    The structural implications of excess Ni in the TiNiSn half-Heusler compound are examined through a combination of synchrotron x-ray and neutron scattering studies, in conjunction with first principles density functional theory calculations on supercells. Despite the phase diagram suggesting that TiNiSn is a line compound with no solid solution, for small x in TiNi 1+x Sn there is indeed an appearance—from careful analysis of the scattering—of some solubility, with the excess Ni occupying the interstitial tetrahedral site in the half-Heusler structure. The analysis performed here would point to the excess Ni not being statistically distributed, but rather occurring as coherent nanoclusters. First principles calculations of energetics, carried out using supercells, support a scenario of Ni interstitials clustering, rather than a statistical distribution.

  10. Microstructural evolution of Ni40Zr60 alloy during early stage of mechanical alloying of intermetallic compounds NiZr2 and Ni11Zr9

    International Nuclear Information System (INIS)

    Lee Peeyew; Koch, C.C.

    1994-01-01

    The microstructural change of Ni 40 Zr 60 alloy during mechanical alloying of mixtures of the intermetallic compounds NiZr 2 and Ni 11 Zr 9 has been studied by transmission electron microscopy. A specific ''cauliflower'' phase was formed during early stage of mechanical alloying process. It is suggested that the solid state reaction between intermetallic compounds NiZr 2 and Ni 11 Zr 9 is not the only origin for the formation of the ''cauliflower'' phase. ((orig.))

  11. Mazeikiu refinery to stay in Yukos' control / Steven Paulikas

    Index Scriptorium Estoniae

    Paulikas, Steven

    2004-01-01

    Vene peaprokuratuur andis välja rahvusvahelise vahistamisorderi Mazheikiu Nafta juhatuse esimehe ja Jukose aktsionäri Mihhail Brudno suhtes. Leedu valitsus kaalub võimalikke samme, sealhulgas Mazheikiu Nafta aktsiate tagasiostmist

  12. Microstructure and tribological properties of NiMo/Mo2Ni3Si intermetallic 'in-situ' composites

    International Nuclear Information System (INIS)

    Gui Yongliang; Song Chunyan; Yang Li; Qin Xiaoling

    2011-01-01

    Research highlights: → Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites was fabricated successfully with Mo-Ni-Si powder blends as the starting materials. Microstructure of the NiMo/Mo 2 Ni 3 Si composites consists of Mo 2 Ni 3 Si primary dendrites, binary intermetallic phase NiMo and small amount of Ni/NiMo eutectics structure. The NiMo/Mo 2 Ni 3 Si composites exhibited high hardness and outstanding tribological properties under room-temperature dry-sliding wear test conditions which were attributed to the covalent-dominant strong atomic bonds and excellent combination of strength and ductility and toughness. - Abstract: Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites with a microstructure of ternary metal silicide Mo 2 Ni 3 Si primary dendritic, the long strip-like NiMo intermetallic phase, and a small amount of Ni/NiMo eutectics structure were designed and fabricated using molybdenum, nickel and silicon elemental powders. Friction and wear properties of NiMo/Mo 2 Ni 3 Si composites were evaluated under different contact load at room-temperature dry-sliding wear test conditions. Microstructure, worn surface morphologies and subsurface microstructure were characterized by OM, XRD, SEM and EDS. Results indicate that NiMo/Mo 2 Ni 3 Si composites have low fiction coefficient, excellent wear resistance and sluggish wear-load dependence. The dominant wear mechanisms of NiMo/Mo 2 Ni 3 Si composites are soft abrasion and slightly superficial oxidative wear.

  13. Nonenzymatic Glucose Sensor Based on In Situ Reduction of Ni/NiO-Graphene Nanocomposite

    Directory of Open Access Journals (Sweden)

    Xiaohui Zhang

    2016-10-01

    Full Text Available Ni/NiO nanoflower modified reduced graphene oxide (rGO nanocomposite (Ni/NiO-rGO was introduced to screen printed electrode (SPE for the construction of a nonenzymatic electrochemical glucose biosensor. The Ni/NiO-rGO nanocomposite was synthesized by an in situ reduction process. Graphene oxide (GO hybrid Nafion sheets first chemical adsorbed Ni ions and assembled on the SPE. Subsequently, GO and Ni ions were reduced by hydrazine hydrate. The electrochemical properties of such a Ni/NiO-rGO modified SPE were carefully investigated. It showed a high activity for electrocatalytic oxidation of glucose in alkaline medium. The proposed nonenzymatic sensor can be utilized for quantification of glucose with a wide linear range from 29.9 μM to 6.44 mM (R = 0.9937 with a low detection limit of 1.8 μM (S/N = 3 and a high sensitivity of 1997 μA/mM∙cm−2. It also exhibited good reproducibility as well as high selectivity.

  14. Enthalpy of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys

    International Nuclear Information System (INIS)

    Witusiewicz, V.T.; Sommer, F.

    2000-01-01

    Since the Al-Cu-Ni-Zr system is a basis for the production of bulk amorphous materials by rapid solidification techniques from the liquid state, it is of great scientific interest to determine the partial and the integral thermodynamic functions of liquid and undercooled liquid alloys. Such data, as was pointed out previously, are important in order to understand their extremely good glass-forming ability in multicomponent metallic systems as well as for processing improvements. In order to measure the thermodynamic properties of the Al-Cu-Ni-Zr quaternary, it is necessary to have reliable thermochemical data for its constituent canaries and ternaries first. In a series of articles, the authors have reported in detail the thermodynamic properties of liquid Al-Cu, Al-Ni, Cu-Ni, Cu-Zr, Al-Zr, Al-Cu-Ni, and Al-Cu-Zr alloys. This article deals with the direct calorimetric measurements of the partial and the integral enthalpies of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys and the heat capacity of liquid Ni 26 Zr 74 . In a subsequent article, the authors will present similar data for the liquid ternary Al-Ni-Zr and for the liquid quaternary Al-Cu-Ni-Zr alloys

  15. The Ni-YSZ interface

    DEFF Research Database (Denmark)

    Jensen, Karin Vels

    The anode/electrolyte interface in solid oxide fuel cells (SOFC) is known to cause electrical losses. Geometrically simple Ni/yttria-stabilised zirconia (YSZ) interfaces were examined to gain information on the structural and chemical changes occurring during experiments at 1000°C in an atmosphere...... of 97% H2/3% H2O. Electrochemical impedance spectroscopy at open circuit voltage (OCV) and at anodic and cathodic polarisations (100 mV) was performed. A correlation of the electrical data with the structure development and the chemical composition was attempted. Nickel wires with different impurity...... between polarised and non-polarised samples. With pure nickel wires, however, the microstructures depended on the polarisation/non-polarisation conditions. At non-polarised conditions a hill and valley type structure was found. Anodic polarisation produced an up to 1 μm thick interface layer consisting...

  16. Study of the central collisions in the reactions Ni + Al and Ni + Ni at 28 A.MeV; Etude des collisions centrales dans les reactions Ni + Al et Ni + Ni a 28 A.MeV

    Energy Technology Data Exchange (ETDEWEB)

    Lebreton, L.

    1995-12-01

    The work is in characterisation of mechanisms in the energy range of onset of multifragmentation (excitation energy of composed nucleus around 4 - 5 AMeV). This work focused on an experiment performed at the SARA facility, in Grenoble, using the AMPHORA multi detection array. I have been particularly interested in central collisions in the Ni + Al and Ni + Ni systems. The possibility to detect complete events for Ni + Al, and quasi-complete events for the Ni + Ni case, is the reason of this choice. Furthermore Ni + Ni presents the interest of a symmetrical system, for which the excitation energy per nucleon is maximum. The study of these reactions has been focused on the quasi-complete events (events for which at least 80 % of the total charge has been detected). Heavy ions produced in peripheral collisions are very likely emitted along the beam line or stopped in the plastic detectors, energy thresholds are too high for the quasi-target products detection, consequently by requiring complete or quasi-complete measurement of the total charge, we are able to detect mostly central events. The knowledge of informations like charge, energy or detection angles allows to isolate the source(s) and to reconstruct the size and the excitation energy of the source(s). Comparisons with simulations like sequential emission (GEMINI code), very deep inelastic collision or instantaneous emission (Berliner code) allows to characterise the first stage of the collision (binary collisions or central collisions) and the type of deexcitation of the source(s). Some calculations was also performed with the statistical model code MODGAN. Indeed azimuthal correlations seem to be a good tool in getting more information about involved reaction mechanisms. Comparisons with MODGAN provide information about angular momentum of the source and time delay between emissions of the two particles (separation between sequential or instantaneous process). (author). 69 refs.

  17. Electrochemical preparation and characteristics of Ni-Co-LaNi{sub 5} composite coatings as electrode materials for hydrogen evolution

    Energy Technology Data Exchange (ETDEWEB)

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-02-15

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi{sub 5} composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi{sub 5} particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi{sub 5} coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol{sup -1} for the Ni-Co-LaNi{sub 5}, Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi{sub 5} proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi{sub 5} is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface.

  18. Electrochemical preparation and characteristics of Ni-Co-LaNi5 composite coatings as electrode materials for hydrogen evolution

    International Nuclear Information System (INIS)

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-01-01

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi 5 composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi 5 particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi 5 coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol -1 for the Ni-Co-LaNi 5 , Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi 5 proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi 5 is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface

  19. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong; Anjum, Dalaver H.; Zhou, Lu; Laveille, Paco; Basset, Jean-Marie

    2015-01-01

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles

  20. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong

    2015-06-25

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

  1. Growth of single-crystal W whiskers during humid H2/N2 reduction of Ni, Fe-Ni, and Co-Ni doped tungsten oxide

    International Nuclear Information System (INIS)

    Wang Shiliang; He Yuehui; Zou Jou; Wang Yong; Huang Han

    2009-01-01

    Numbers of W whiskers were obtained by reducing Ni, Ni-Fe, and Ni-Co doped tungsten oxide in a mixed atmosphere of humid H 2 and N 2 . The phases and morphologies of the reduction products were characterized by XRD and SEM. Intensive TEM and EDS analyses showed that the obtained whiskers were W single crystals which typical have alloyed particles (Ni-W, Fe-Ni, or Co-Ni-W) at the growth tips. The formed W whiskers were presumed to be induced by the alloyed particles. Our experimental results revealed that, during the reduction process of tungsten oxide, the pre-reduced Ni, Fe-Ni, or Co-Ni particles not only served as nucleation aids for the initial growth of W phase from W oxide but also played the roles of catalysts during the reductive decomposition of gaseous WO 2 (OH) 2 .

  2. Exchange bias variations of the seed and top NiFe layers in NiFe/FeMn/NiFe trilayer as a function of seed layer thickness

    International Nuclear Information System (INIS)

    Sankaranarayanan, V.K.; Yoon, S.M.; Kim, C.G.; Kim, C.O.

    2005-01-01

    Development of exchange bias at the seed and top NiFe layers in the NiFe (t nm)/FeMn(10 nm)/NiFe(5 nm) trilayer structure is investigated as a function of seed layer thickness, in the range of 2-20 nm. The seed NiFe layer shows maximum exchange bias at 4 nm seed layer thickness. The bias shows inverse thickness dependence with increasing thickness. The top NiFe layer on the other hand shows only half the bias of the seed layer which is retained even after the sharp fall in seed layer bias. The much smaller bias for the top NiFe layer is related to the difference in crystalline texture and spin orientations at the top FeMn/NiFe interface, in comparison to the bottom NiFe/FeMn interface which grows on a saturated NiFe layer with (1 1 1) orientation

  3. An Ultrastable and High-Performance Flexible Fiber-Shaped Ni-Zn Battery based on a Ni-NiO Heterostructured Nanosheet Cathode.

    Science.gov (United States)

    Zeng, Yinxiang; Meng, Yue; Lai, Zhengzhe; Zhang, Xiyue; Yu, Minghao; Fang, Pingping; Wu, Mingmei; Tong, Yexiang; Lu, Xihong

    2017-11-01

    Currently, the main bottleneck for the widespread application of Ni-Zn batteries is their poor cycling stability as a result of the irreversibility of the Ni-based cathode and dendrite formation of the Zn anode during the charging-discharging processes. Herein, a highly rechargeable, flexible, fiber-shaped Ni-Zn battery with impressive electrochemical performance is rationally demonstrated by employing Ni-NiO heterostructured nanosheets as the cathode. Benefiting from the improved conductivity and enhanced electroactivity of the Ni-NiO heterojunction nanosheet cathode, the as-fabricated fiber-shaped Ni-NiO//Zn battery displays high capacity and admirable rate capability. More importantly, this Ni-NiO//Zn battery shows unprecedented cyclic durability both in aqueous (96.6% capacity retention after 10 000 cycles) and polymer (almost no capacity attenuation after 10 000 cycles at 22.2 A g -1 ) electrolytes. Moreover, a peak energy density of 6.6 µWh cm -2 , together with a remarkable power density of 20.2 mW cm -2 , is achieved by the flexible quasi-solid-state fiber-shaped Ni-NiO//Zn battery, outperforming most reported fiber-shaped energy-storage devices. Such a novel concept of a fiber-shaped Ni-Zn battery with impressive stability will greatly enrich the flexible energy-storage technologies for future portable/wearable electronic applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Synthesis of a novel Au nanoparticles decorated Ni-MOF/Ni/NiO nanocomposite and electrocatalytic performance for the detection of glucose in human serum.

    Science.gov (United States)

    Chen, Jingyuan; Xu, Qin; Shu, Yun; Hu, Xiaoya

    2018-07-01

    A nonenzymatic glucose electrochemical sensor was constructed based on Au nanoparticles (AuNPs) decorated Ni metal-organic-framework (MOF)/Ni/NiO nanocomposite. Ni-MOF/Ni/NiO nanocomposite was synthesized by one-step calcination of Ni-MOF. Then AuNPs were loaded onto the Ni-based nanocomposites' surface through electrostatic adsorption. Through characterization by transmission electron microscopy (TEM), high resolution TEM (HRTEM) and energy disperse spectroscopy (EDS) mapping, it is found that the AuNPs were well distributed on the surface of Ni-based nanocomposite. Cyclic voltammetric (CV) study showed the electrocatalytic activity of Au-Ni nanocomposite was highly improved after loading AuNPs onto it. Amperometric study demonstrated that the Au-Ni nanocomposites modified glassy carbon electrode (GCE) exhibited a high sensitivity of 2133.5 mA M -1 cm -2 and a wide linear range (0.4-900 μM) toward the oxidation of glucose with a detection limit as low as 0.1 μM. Moreover, the reproducibility, selectivity and stability of the sensor all exhibited outstanding performance. We applied the as-fabricated high performance sensor to measure the glucose levels in human serum and obtained satisfactory results. It is believed that AuNPs decorated Ni MOF/Ni/NiO nanocomposite provides a new platform for developing highly performance electrochemical sensors in practical applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  5. Ni antagelser om Situationel Dialektisk Videnskabsteori

    DEFF Research Database (Denmark)

    Dakwar, Julia Rytter; Lorentzen, Anne-Christine Rosfeldt; Smedegaard, Flemming

    2017-01-01

    I artiklen præsenteres et præliminært bud på en Situationel Dialektisk Videnskabsteori (SDV) i form af ni antagelser. Situationel, fordi antagelserne ikke er statiske, men alle overvejelser og valg under de enkelte antagelser er afhængige af situationen. Dialektisk, fordi alle ni antagelser...... opererer med dialektiske modsætninger, og alle videnskabsteoretiske valg ses som valg på kontinua. De ni antagelser, som bliver præsenteret og diskuteret i artiklen, er: Antagelse 1: Teori og praksis fordrer hinanden Antagelse 2: Del og helhed hænger sammen Antagelse 3: Forbundne sagsforhold påvirker...

  6. New developments in Ni/Ti multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, I; Hoghoj, P [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    It is now 20 years since super-mirrors were first used as a neutron optical element. Since then the field of multilayer neutron-optics has matured with multilayers finding their way to application in many neutron scattering instruments. However, there is still room for progress in terms of multilayer quality, performance and application. Along with work on multilayers for neutron polarisation Ni/Ti super-mirrors have been optimised. The state-of-the-art Ni/Ti super-mirror performance and the results obtained in two neutron-optics applications of Ni/Ti multilayers are presented. (author).

  7. Site occupancy of Fe in ternary Ni 75-x

    Indian Academy of Sciences (India)

    The results of a detailed structural and magnetic study clearly indicate that regardless of the thermal history of the samples, Fe has a strong preference for the Ni sites in Ni-poor (non-stoichiometric) Ni75Al25 alloys. Fe substitution has a profound effect on the nature of magnetism in Ni75Al25.

  8. Reduction of a Ni/Spinel Catalyst for Methane Reforming

    DEFF Research Database (Denmark)

    Kehres, Jan; Andreasen, Jens Wenzel; Fløystad, Jostein Bø

    2015-01-01

    microscopy (HRTEM) was performed on the fresh catalyst sample. The Ni particles in the fresh catalyst sample were observed to exhibit a Ni/NiO core/shell structure. A decrease of the Ni lattice parameter is observed during the reduction in a temperature interval from 413 – 453 K, which can be related...

  9. Influence of Ni Solute segregation on the intrinsic growth stresses in Cu(Ni) thin films

    International Nuclear Information System (INIS)

    Kaub, T.M.; Felfer, P.; Cairney, J.M.; Thompson, G.B.

    2016-01-01

    Using intrinsic solute segregation in alloys, the compressive stress in a series of Cu(Ni) thin films has been studied. The highest compressive stress was noted in the 5 at.% Ni alloy, with increasing Ni concentration resulting in a subsequent reduction of stress. Atom probe tomography quantified Ni's Gibbsian interfacial excess in the grain boundaries and confirmed that once grain boundary saturation is achieved, the compressive stress was reduced. This letter provides experimental support in elucidating how interfacial segregation of excess adatoms contributes to the post-coalescence compressive stress generation mechanism in thin films. - Graphical abstract: Cu(Ni) film stress relationship with Ni additions. Atom probe characterization confirms solute enrichment in the boundaries, which was linked to stress response.

  10. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    International Nuclear Information System (INIS)

    Zhou, M. H.; Wang, Y. G.; Bi, K.; Fan, H. P.; Zhao, Z. S.

    2015-01-01

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α E,31 = 2.8 V ⋅ cm −1 ⋅ Oe −1 is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors

  11. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, M. H.; Wang, Y. G.; Bi, K., E-mail: bike@bupt.edu.cn [State Key Laboratory of Information Photonics and Optical Communications and School of Science, Beijing University of Posts and Telecommunications, Beijing 100876 (China); Fan, H. P. [School of Mechanical and Electrical Engineering, Qingdao Technological University Qindao College, Qingdao 266106 (China); Zhao, Z. S. [Shandong Engineering Consulting Institute, Jinan 250013 (China)

    2015-04-15

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α{sub E,31} = 2.8 V ⋅ cm{sup −1} ⋅ Oe{sup −1} is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors.

  12. Fe-solubility of Ni7S6 and Ni9S8: Thermodynamic analysis

    International Nuclear Information System (INIS)

    Waldner, P.

    2011-01-01

    Experimental data on phase equilibria have been used for thermodynamic analysis of the iron solubility of the nickel sulfides Ni 7 S 6 and Ni 9 S 8 . For both compounds, a two-sublattice approach within the framework of the compound energy formalism has been applied to perform Gibbs free energy modelling at 0.1 MPa total pressure consistently embedded in recent thermodynamic assessment studies of other iron-nickel-sulfides. The predicted maxima of iron solubility around 3 at% of Ni 7 S 6 and 5.5 at% of Ni 9 S 8 are confirmed by experimental data. The calculations of complex ternary phase relations with Fe-bearing Ni 7 S 6 and Ni 9 S 8 gain further improvement. The first internally consistent description of all thermodynamically stable phases known in the literature for the iron-nickel-sulfur system is completed.

  13. Phase stability and magnetism in NiPt and NiPd alloys

    International Nuclear Information System (INIS)

    Paudyal, Durga; Mookerjee, Abhijit

    2004-01-01

    We show that the differences in stability of 3d-5d NiPt and 3d-4d NiPd alloys arise mainly due to relativistic corrections. The magnetic properties of disordered NiPd and NiPt alloys also differ due to these corrections, which lead to increase in the separation between the s-d bands of 5d elements in these alloys. For the magnetic case we also analyse the results in terms of splitting of majority and minority spin d band centres of the 3d elements. We further examine the effect of relativistic corrections to the pair energies and order-disorder transition temperatures in these alloys. The magnetic moments and Curie temperatures have also been studied along with the short range ordering/segregation effects in NiPt/NiPd alloys

  14. Precipitation of Ni4Ti3-variants in a polycrystalline Ni-rich NiTi shape memory alloy

    Czech Academy of Sciences Publication Activity Database

    Bojda, Ondřej; Eggeler, G.; Dlouhý, Antonín

    2005-01-01

    Roč. 53, č. 1 (2005), s. 99-104 ISSN 1359-6462 R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitation * Transmission electron microscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.228, year: 2005

  15. Ni-Ni ion pair excitation transfer in D sub(3h) symmetry

    International Nuclear Information System (INIS)

    Terrile, M.C.

    1990-01-01

    The mechanisms contributing to excitation transfer are examined for Ni-Ni ion pairs in order to explain the delocalized character of electronic excitations observed in CsNiF sub(3). Using both first-and second-order perturbation theory and from symmetry arguments, the kind of interactions giving matrix elements between states connecting different sites for the position of the excitation are discussed. (author)

  16. Electronic structure of graphene on Ni surfaces with different orientation

    International Nuclear Information System (INIS)

    Pudikov, D.A.; Zhizhin, E.V.; Rybkin, A.G.; Rybkina, A.A.; Zhukov, Y.M.; Vilkov, O. Yu.; Shikin, A.M.

    2016-01-01

    An experimental study of the graphene, synthesized by propylene cracking on Ni surfaces with different orientation: (100) and (111), using angle-resolved photoemission, has been performed. It has been shown that graphene on Ni(111) had a perfect lateral structure due to consistency of their lattices, whereas graphene/Ni(100) consisted of a lot of domains. For both systems electronic structure was quite similar and demonstrated a strong bonding of graphene to the underlying Ni surface. After Au intercalation the electronic structure of graphene in both systems was shifted to the Fermi level and became linear in the vicinity of the K point of the Brillouin zone. - Highlights: • Graphene on Ni(111) is well-ordered, whereas on Ni(100) – multi-domain. • Graphene on Ni(111) and Ni(100) is strongly bonded with substrate. • Intercalation of Au atoms restores the linearity in dispersion and makes graphene quasi-free on both Ni(100) and Ni(111).

  17. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    Kabir, L.; Mandal, A.R. [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India); Mandal, S.K., E-mail: sk_mandal@hotmail.co [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India)

    2010-04-15

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni{sup 2+} clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni{sup 2+} clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  18. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Science.gov (United States)

    Kabir, L.; Mandal, A. R.; Mandal, S. K.

    2010-04-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  19. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    International Nuclear Information System (INIS)

    Kabir, L.; Mandal, A.R.; Mandal, S.K.

    2010-01-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  20. Modeling and simulation of NiO dissolution and Ni deposition in molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Suk Woo; Choi, Hyung-Joon; Lim, Tae Hoon [Korea Institute of Science & Technology, Seoul (Korea, Republic of)] [and others

    1996-12-31

    Dissolution of NiO cathode into the electrolyte matrix is an important phenomena limiting the lifetime of molten carbonate fuel cell (MCFC). The dissolved nickel diffuses into the matrix and is reduced by dissolved hydrogen leading to the formation of metallic nickel films in the pores of the matrix. The growth of Ni films in the electrolyte matrix during the continuous cell operation results eventually in shorting between cathode and anode. Various mathematical and empirical models have been developed to describe the NiO dissolution and Ni deposition processes, and these models have some success in estimating the lifetime of MCFC by correlating the amount of Ni deposited in the matrix with shorting time. Since the exact mechanism of Ni deposition was not well understood, deposition reaction was assumed to be very fast in most of the models and the Ni deposition region was limited around a point in the matrix. In fact, formation of Ni films takes place in a rather broad region in the matrix, the location and thickness of the film depending on operating conditions as well as matrix properties. In this study, we assumed simple reaction kinetics for Ni deposition and developed a mathematical model to get the distribution of nickel in the matrix.

  1. Layering and temperature-dependent magnetization and anisotropy of naturally produced Ni/NiO multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Pappas, S. D.; Trachylis, D.; Velgakis, M. J. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Kapaklis, V.; Joensson, P. E.; Papaioannou, E. Th. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process Engineering Research Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Poulopoulos, P. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Materials Science Department, University of Patras, 26504 Patras (Greece); Fumagalli, P. [Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Politis, C. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Materials Science and Engineering, University of Texas at Arlington, Arlington, Texas 76019 (United States)

    2012-09-01

    Ni/NiO multilayers were grown by magnetron sputtering at room temperature, with the aid of the natural oxidation procedure. That is, at the end of the deposition of each single Ni layer, air is let to flow into the vacuum chamber through a leak valve. Then, a very thin NiO layer ({approx}1.2 nm) is formed. Simulated x-ray reflectivity patterns reveal that layering is excellent for individual Ni-layer thickness larger than 2.5 nm, which is attributed to the intercalation of amorphous NiO between the polycrystalline Ni layers. The magnetization of the films, measured at temperatures 5-300 K, has almost bulk-like value, whereas the films exhibit a trend to perpendicular magnetic anisotropy (PMA) with an unusual significant positive interface anisotropy contribution, which presents a weak temperature dependence. The power-law behavior of the multilayers indicates a non-negligible contribution of higher order anisotropies in the uniaxial anisotropy. Bloch-law fittings for the temperature dependence of the magnetization in the spin-wave regime show that the magnetization in the multilayers decreases faster as a function of temperature than the one of bulk Ni. Finally, when the individual Ni-layer thickness decreases below 2 nm, the multilayer stacking vanishes, resulting in a dramatic decrease of the interface magnetic anisotropy and consequently in a decrease of the perpendicular magnetic anisotropy.

  2. XRD studies on solid state amorphisation in electroless Ni/P and Ni/B deposits

    International Nuclear Information System (INIS)

    Sampath Kumar, P.; Kesavan Nair, P.

    1996-01-01

    The decomposition of electroless Ni-P and Ni-B deposits on annealing at various temperature is studied using x-ray diffraction techniques employing profile deconvolution and line profile analysis. It appears that solid state amorphisation takes place in the Ni-B deposits in a narrow temperature range just prior to the onset of crystallization of amorphous phase. In the case of Ni-P deposits no evidence for solid state amorphisation could be obtained. Thermodynamic and kinetic considerations also support such a conclusion

  3. Ni adsorption and Ni-Al LDH precipitation in a sandy aquifer: An experimental and mechanistic modeling study

    NARCIS (Netherlands)

    Regelink, I.C.; Temminghoff, E.J.M.

    2011-01-01

    Mining activities and industries have created nickel (Ni) contaminations in many parts of the world. The objective of this study is to increase our understanding of Ni adsorption and Nickel-Aluminium Layered Double Hydroxide (Ni-Al LDH) precipitation to reduce Ni mobility in a sandy soil aquifer. At

  4. Core/shell AgNi/PtAgNi nanoparticles as methanol-tolerant oxygen reduction electrocatalysts

    International Nuclear Information System (INIS)

    Wu, Dengfeng; Cheng, Daojian

    2015-01-01

    A core/shell AgNi/PtAgNi nanoparticle (NP) was synthesized via a new seed-mediated growth method in organic solvent medium. The as-synthesized AgNi/PtAgNiNP exhibits an AgNi core coated with PtAgNi shell, which was confirmed by transmission electron microscopy (TEM), ultraviolet–visible absorption spectroscopy and X-ray Photoelectron Spectroscopy (XPS). The AgNi/PtAgNiNPs/C catalyst possesses higher oxygen reduction reaction (ORR) activity and better durability compared with the commercial Pt/C catalyst. It is found that the ORR polarization curve of the AgNi/PtAgNiNPs/C catalyst shows an onset potential of 0.91 V vs. RHE, which is superior to the commercial Pt/C (0.88 V vs. RHE). In addition, the AgNi/PtAgNiNPs/C catalyst shows much better durability than the commercial Pt/C catalyst. More interestingly, the AgNi/PtAgNiNPs/C catalyst displays much higher methanol tolerance than the commercial Pt/C catalyst in 0.1 M KOH solution in the presence of 0.5 M methanol. Our results show that core/shell AgNi/PtAgNiNPs possess selective activity for ORR even in the presence of methanol, showing potential application as methanol-tolerant cathode catalysts in direct methanol fuel cells.

  5. Grain boundaries in Ni3Al. 2

    International Nuclear Information System (INIS)

    Kung, H.; Sass, S.L.

    1992-01-01

    This paper discusses the dislocation structure of small angle tilt and twist boundaries in ordered Ni 3 Al, with and without boron, investigated using transmission electron microscopy. Dislocation with Burgers vectors that correspond to anti-phase boundary (APB)-coupled superpartials were found in small angle twist boundaries in both boron-free and boron-doped Ni 3 Al, and a small angle tilt boundary in boron-doped Ni 3 Al. The boundary structures are in agreement with theoretical models proposed by Marcinkowski and co-workers. The APB energy determined from the dissociation of the grain boundary dislocations was lower than values reported for isolated APBs in Ni 3 Al. For small angle twist boundaries the presence of boron reduced the APB energy at the interface until it approached zero. This is consistent with the structure of these boundaries containing small regions of increased compositional disorder in the first atomic plane next to the interface

  6. Ni-ZrB2 electrocomposites

    International Nuclear Information System (INIS)

    Pushpavanam, M.; Natarajan, S.R.

    1992-01-01

    New generation materials require high temperature oxidation resistance besides many other tribological properties. Ni-ZrB 2 composites and their properties are dealt with in this paper. (author). 7 refs., 3 figs., 4 tabs

  7. Not in Traffic Surveillance (NiTS)

    Data.gov (United States)

    Department of Transportation — The Not-in-Traffic Surveillance (NiTS) system is a virtual data collection system designed to provide counts and details regarding fatalities and injuries that occur...

  8. Niños y Violencia

    OpenAIRE

    International Child Development Centre

    1997-01-01

    Este Innocenti Digest explora la violencia de los niños y hacia los niños, usando el marco de la Convención de los Derechos del Niño de las Naciones Unidas. Se centra en la violencia interpersonal, tanto intrafamiliar como extrafamiliar. Se incluye el abuso sexual y la explotación ya que a pesar de no implicar obligatoriamente violencia o coerción, la mayor parte de la evidencia demuestra su efectos dañinos tanto físicos como psicológicos. También se discute la implicación de los niños en los...

  9. Collision strengths for transitions in Ni XIX

    Indian Academy of Sciences (India)

    4l configurations of Ni XIX, for which flexible atomic code. (FAC) has been ... atomic data (namely energy levels, radiative rates, collision strengths, excitation rates, etc.) ... Zhang and Sampson, who adopted the Coulomb–Born-exchange.

  10. Root morphology of Ni-treated plants

    International Nuclear Information System (INIS)

    Leskova, A.; Fargasova, A.; Giehl, R. F. H.; Wiren, N. von

    2015-01-01

    Plant roots are very important organs in terms of nutrient and water acquisition but they also serve as anchorages for the aboveground parts of the plants. The roots display extraordinary plasticity towards stress conditions as a result of integration of environmental cues into the developmental processes of the roots. Our aim was to investigate the root morphology of Arabidopsis thaliana plants exposed to a particular stress condition, excess Ni supply. We aimed to find out which cellular processes - cell division, elongation and differentiation are affected by Ni, thereby explaining the seen root phenotype. Our results reveal that a distinct sensitivity exists between roots of different order and interference with various cellular processes is responsible for the effects of Ni on roots. We also show that Ni-treated roots have several auxin-related phenotypes. (authors)

  11. Density and Structure Analysis of Molten Ni-W Alloys

    Institute of Scientific and Technical Information of China (English)

    Feng XIAO; Liang FANG

    2004-01-01

    Density of molten Ni and Ni-W alloys was measured in the temperature range of 1773~1873 K with a sessile drop method.The density of molten Ni and Ni-W alloys trends to decrease with increasing temperature. The density and molar volume of the alloys trend to increase with increasing W concentration in the alloys. The calculation result shows an ideal mixing of Ni-W alloys.

  12. Fe-Cr-Ni system alloys

    International Nuclear Information System (INIS)

    Levin, F.L.

    1986-01-01

    Phase diagram of Fe-Cr-Ni system, which is the basic one for production of corrosion resistant alloys, is considered. Data on corrosion resistance of such alloys are correlated depending on a number of factors: quality and composition of modifying elements, corrosion medium, temperature, alloy structure, mechanical and thermal treatment. Grades of Fe-Ni-Cr alloys are presented, and fields of their application are pointed out

  13. Synthesis of Ni3Ta, Ni2Ta and NiTa by high-energy ball milling and subsequent heat treatment

    International Nuclear Information System (INIS)

    Benites, H.S.N.; Silva, B.P da; Ramos, A.S.; Silva, A.A.A.P.; Coelho, G.C.; Lima, B.B. de

    2014-01-01

    The tantalum has relevance for the development of multicomponent Ni-based superalloys which are hardened by solid solution and precipitation mechanisms. Master alloys are normally used in the production step in order to produce refractory metals and alloys. The present work reports on the synthesis of Ni_3Ta, Ni_2Ta and NiTa by high-energy ball milling and subsequent heat treatment. The elemental Ni-25Ta, Ni-33Ta and Ni-50Ta (at.-%) powder mixtures were ball milled under Ar atmosphere using stainless steel balls and vials, 300 rpm and a ball-to-powder weight ratio of 10:1. Following, the as-milled samples were uniaxially compacted and heat-treated at 1100 deg C for 4h under Ar atmosphere. The characterization of as-milled and heat-treated samples was conducted by means of X-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry. A large amount of Ni_3Ta, Ni_2Ta and NiTa was formed in the mechanically alloyed heat-treated Ni-25Ta, Ni-33Ta and Ni-50Ta alloys. (author)

  14. Structural Investigation of Fe-Ni-S and Fe-Ni-Si Melts by High-temperature Fluorescence XAFS Measurements

    International Nuclear Information System (INIS)

    Manghnani, Murli H.; Balogh, John; Hong Xinguo; Newville, Matthew; Amulele, G.

    2007-01-01

    Iron-nickel (Fe-Ni) alloy is regarded as the most abundant constituent of Earth's core, with an amount of 5.5 wt% Ni in the core based on geochemical and cosmochemical models. The structural role of nickel in liquid Fe-Ni alloys with light elements such as S or Si is poorly understood, largely because of the experimental difficulties of high-temperature melts. Recently, we have succeeded in acquiring Ni K-edge fluorescence x-ray absorption fine structure (XAFS) spectra of Fe-Ni-S and Fe-Ni-Si melts and alloys. Different structural environment of Ni atoms in Fe-Ni-S and Fe-Ni-Si melts is observed, supporting the effect of light elements in Fe-Ni melts

  15. The complex transfer reaction (14C, 15O) on Ni, Zn and Ge targets: existence and mass of 69Ni

    International Nuclear Information System (INIS)

    Dessagne, P.; Bernas, M.; Langevin, M.; Pougheon, F.; Roussel, P.; Morrison, G.C.

    1984-01-01

    The ( 14 C, 15 O) complex transfer reaction has been studied at 72 MeV incident energy on 58 Ni, 60 Ni, 62 Ni, 64 Ni, 68 Zn, 70 Zn and 74 Ge, 76 Ge targets. Spectra and differential cross sections have been measured in a 5 0 angular range centred around a laboratory angle of 6 0 . The nucleus 69 Ni has been observed and its mass determined for the first time

  16. Electroless Ni-P/Ni-B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance

    International Nuclear Information System (INIS)

    Narayanan, T.S.N. Sankara; Krishnaveni, K.; Seshadri, S.K.

    2003-01-01

    The present work deals with the formation of Ni-P/Ni-B duplex coatings by electroless plating process and evaluation of their hardness, wear resistance and corrosion resistance. The Ni-P/Ni-B duplex coatings were prepared using dual baths (acidic hypophosphite- and alkaline borohydride-reduced electroless nickel baths) with both Ni-P and Ni-B as inner layers and with varying single layer thickness. Scanning electron microscopy (SEM) was used to assess the duplex interface. The microhardness, wear resistance and corrosion resistance of electroless nickel duplex coatings were compared with electroless Ni-P and Ni-B coatings of similar thickness. The study reveals that the Ni-P and Ni-B coatings are amorphous in their as-plated condition and upon heat-treatment at 450 deg. C for 1 h, both Ni-P and Ni-B coatings crystallize and produce nickel, nickel phosphide and nickel borides in the respective coatings. All the three phases are formed when Ni-P/Ni-B and Ni-B/Ni-P duplex coatings are heat-treated at 450 deg. C for 1 h. The duplex coatings are uniform and the compatibility between the layers is good. The microhardness, wear resistance and corrosion resistance of the duplex coating is higher than Ni-P and Ni-B coatings of similar thickness. Among the two types of duplex coatings studied, hardness and wear resistance is higher for coatings having Ni-B coating as the outer layer whereas better corrosion resistance is offered by coatings having Ni-P coating as the outer layer

  17. Heavy metal environmental impact. Nickel (Ni); Impatto ambientale da metalli pesanti. Il Nichel (Ni)

    Energy Technology Data Exchange (ETDEWEB)

    Bressa, G. [Padua Univ. Padua (Italy). Dipt. di Farmacologia, Lab. di Tossicologia

    2001-02-01

    Nickel (Ni) is a heavy metal in over 3.000 different alloys used to produce kitchen utensils, batteries, coins, etc.. Human extractive and industrial activities are therefore a cause for environmental dispersion of this metal into the biosphere. This shows how in urban areas car traffic and house-heating are the main sources of nickel pollution. Nickel is relatively non-toxic, such as iron, cobalt, copper and zinc; nevertheless prolonged inhalation of dust containing such compounds as Ni O or NiCl{sub 2} concurs in the outbreak of respiratory pathologies. The carcinogenic effect of such compounds as Ni S, Ni O and Ni(CO){sub 4} has been confirmed by experiments on laboratory animals. Ni potentially toxic concentrations, and as a consequence of potential environmental impact, are to be mainly found in populated areas where the main sources are represented by industries and landfills. [Italian] Il nichel (Ni) e' un metallo presente in oltre 3.000 differenti leghe che vengono utilizzate per la produzione di utensili da cucina, batterie, monete, ecc.. Le attivita' estrattive ed industriali dell'uomo sono quindi causa di una dispersione del metallo nella biosfera. Sono stati riscontrati elevati tassi di Ni nell'atmosfera di aree urbane. Cio' sta a dimostrare che nelle aree urbane il traffico automobilistico e il riscaldamento domestico sono le fonti principali di inquinamento da tale metallo. Il nichel e' relativamente atossico, analogamente a ferro, cobalto, rame e zinco, tuttavia l'inalazione protratta di polveri contenenti composti come il NiO o il NiCl{sub 2} contribuisce al manifestarsi di patologie dell'apparato respiratorio. E' stato confermato sperimentalmente su animali da laboratorio l'effetto cancerogeno di alcuni composti quali NiS, NiO e Ni(CO){sub 4}. Concentrazioni potenzialmente tossiche di Ni, e quindi di probabile impatto ambientale, sono maggiormente da ricercare nelle zone antropizzate dove le fonti

  18. Ultrathin NiO/NiFe2O4 Nanoplates Decorated Graphene Nanosheets with Enhanced Lithium Storage Properties

    International Nuclear Information System (INIS)

    Du, Dejian; Yue, Wenbo; Fan, Xialu; Tang, Kun; Yang, Xiaojing

    2016-01-01

    Highlights: • Ultrathin NiO/NiFe 2 O 4 nanoplates derived from NiFe layered double hydroxides are fabricated on the graphene. • NiO/NiFe 2 O 4 nanoplates on the graphene show superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates. • The effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are studied. • Graphene-encapsulated NiO/NiFe 2 O 4 is prepared and shows slightly decreased performance compared to graphene-based composite. - Abstract: As anode materials for lithium-ion batteries, bicomponent metal oxide composites show high reversible capacities; but the morphology and particle size of the composites are hardly controllable, which may reduce their electrochemical properties. In this work, ultrathin NiO/NiFe 2 O 4 nanoplates with a diameter of 5 ∼ 7 nm and a thickness of ∼2 nm are controllably fabricated on the graphene derived from NiFe layered double hydroxides (NiFe-LDHs), and exhibit superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates without graphene. The nanosized NiO and NiFe 2 O 4 plates are separated from each other and the graphene substrate can prevent the aggregation of NiO/NiFe 2 O 4 as well as enhance the electronic conductivity of the composite, which is beneficial to improving the electrochemical performance. Moreover, the effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are also studied in order to achieve optimal performance. Ultrathin NiO/NiFe 2 O 4 nanoplates are further encapsulated by graphene nanosheets and show slightly decreased performance compared to those supported by graphene nanosheets. The different electrochemical behaviors of graphene-containing composites may be attributed to the different interactions between graphene nanosheets and NiO/NiFe 2 O 4 nanoplates.

  19. Investigation into the MgF2-NiF2, CaF2-NiF2, SrF2-NiF2 systems

    International Nuclear Information System (INIS)

    Ikrami, D.D.; Petrov, S.V.; Fedorov, P.P.; Ol'khovaya, L.A.; Luginina, A.A.; AN SSSR, Moscow. Inst. Fizicheskikh Problem; AN SSSR, Moscow. Inst. Kristallografii)

    1984-01-01

    Using the methods of differential thermal and X-ray phase analyses the systems MgF 2 -NiF 2 , CaF 2 -NiF 2 , SrF 2 -NiF 2 have been studied. In the system SrF 2 -NiF 2 the only orthorhombic compounds SrNiF 4 (a=14.43; b=3.93; c=5.66 (+-0.01 A)) is formed. SrNiF 4 density constitutes: dsub(X-ray)=4.60+-0.01 g/cm 3 , dsub(exp.)=4.60+-0.03 g/cm 3 . Refraction indices are as follows SrNiF 4 :Ng=1.500; Nsub(m)=1.497; Nsub(p)=1.479. SrNiF 4 magnetic ordering temperature Tsub(N) approximately 100 K

  20. Microstructure and mechanical properties of sputter deposited Ni/Ni{sub 3}Al multilayer films at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Chao [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Feng, Kai, E-mail: fengkai@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Li, Zhuguo, E-mail: lizg@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Lu, Fenggui; Huang, Jian; Wu, Yixiong [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China)

    2016-08-15

    Highlights: • Ni/Ni{sub 3}Al multilayers are prepared by magnetron sputtering. • Both grain size and phase constitution of annealed Ni/Ni{sub 3}Al multilayers are dependent on individual layer thickness. • The hardness of annealed Ni/Ni{sub 3}Al multilayers varies with individual layer thickness and annealing temperature. • 40 nm Ni/Ni{sub 3}Al multilayer exhibits excellent hardness at elevated temperature. - Abstract: Nano-structured Ni/Ni{sub 3}Al multilayer was prepared by magnetron sputtering, with individual layer thicknesses h varying from 10 to 160 nm. The microstructure and hardness of Ni/Ni{sub 3}Al multilayer were investigated by X-ray diffraction, transmission electron microscopy and nanoindentation. The results show that the hardness increases with decreasing h for as-deposited and 500 °C annealed multilayers. When annealed at 700 °C, the hardness approach a peak value at h = 40 nm with followed by softening at smaller h. The influence of individual layer thickness, grain size as well as formation of ordered Ni{sub 3}Al on strengthening mechanisms of Ni/Ni{sub 3}Al multilayers at elevated temperature are discussed.

  1. Enhanced Electrocatalytic Activity for Water Splitting on NiO/Ni/Carbon Fiber Paper

    Directory of Open Access Journals (Sweden)

    Ruoyu Zhang

    2016-12-01

    Full Text Available Large-scale growth of low-cost, efficient, and durable non-noble metal-based electrocatalysts for water splitting is crucial for future renewable energy systems. Atomic layer deposition (ALD provides a promising route for depositing uniform thin coatings of electrocatalysts, which are useful in many technologies, including the splitting of water. In this communication, we report the growth of a NiO/Ni catalyst directly on carbon fiber paper by atomic layer deposition and report subsequent reduction and oxidation annealing treatments. The 10–20 nm NiO/Ni nanoparticle catalysts can reach a current density of 10 mA·cm−2 at an overpotential of 189 mV for hydrogen evolution reactions and 257 mV for oxygen evolution reactions with high stability. We further successfully achieved a water splitting current density of 10 mA·cm−2 at 1.78 V using a typical NiO/Ni coated carbon fiber paper two-electrode setup. The results suggest that nanoparticulate NiO/Ni is an active, stable, and noble-metal-free electrocatalyst, which facilitates a method for future water splitting applications.

  2. Ni(salen): a system that forms many solvates with interacting Ni atoms

    NARCIS (Netherlands)

    Siegler, M.A.M.; Lutz, M.

    2009-01-01

    Recrystallization of [N,N’-Ethylene-bis(salicylideneiminato)]-nickel(II) [Ni(salen)] has been carried out from a large selection of solvents. Crystals can be either solvent free or solvates. This study is based on X-ray crystal structure determinations, which include the redetermination of Ni(salen)

  3. Thermal stability of electrodeposited Ni and Ni-Co layers; an EBSD-study

    DEFF Research Database (Denmark)

    Rasmussen, Anette Alsted; Gholinia, A.; Trimby, P.W.

    2004-01-01

    The influence of heat treatment on the microstructure and the microtexture of electrodeposited Ni and Ni-Co layers was investigated with Electron Backscatter Diffraction (EBSD) with high resolution. Samples were annealed for 1 hour at 523 K and 673 K, the temperature region wherein...

  4. The role of Ni in sulfided carbon-supported Ni-Mo hydrodesulfurization catalysts

    NARCIS (Netherlands)

    Bouwens, S.M.A.M.; Barthe-Zahir, N.; Beer, de V.H.J.; Prins, R.

    1991-01-01

    The thiophene hydrodesulfurization activities of Ni and Ni---Mo sulfide catalysts supported on activated carbon were measured at atmospheric pressure and the catalyst structures were studied by means of X-ray photoelectron spectroscopy, dynamic oxygen chemisorption, and chemical sulfur analysis. The

  5. Mechanical properties of NiO/Ni-YSZ composites depending on temperature, porosity and redox cycling

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Kaiser, Andreas; Mogensen, Mogens Bjerg

    2009-01-01

    The Impulse Excitation Technique (IET) was used to determine the elastic modulus and specific damping of different Ni/NiO-YSZ composites suitable for use in solid oxide fuel cells (SOFC). The porosity of the as-sintered samples varied from 9 to 38% and that of the reduced ones from 31 to 52%. For...

  6. Climate Prediction Center - El Niño/La Niña Home

    Science.gov (United States)

    Weather Service NWS logo - Click to go to the NWS home page Climate Prediction Center Site Map News Information CPC Web Team HOME > El Niño/La Niña Forecasts Current U.S. Climate Outlook SST Forecasts Temperature and Anomalies NOAA/ National Weather Service National Centers for Environmental Prediction Climate

  7. Synthesis and magnetic properties of multilayer Ni/Cu and NiFe/Cu ...

    Indian Academy of Sciences (India)

    The diameter of wires can be easily varied by pore size of alumina, ranging ... saturated HgCl2 solution to remove the remaining Al, and then dipped in 5 wt% ... for NiFe alloy it is 1.3 V, that is higher than for Ni/Cu nanowires to diminish Cu.

  8. Effect of solute atoms on swelling in Ni alloys and pure Ni under He + ion irradiation

    Science.gov (United States)

    Wakai, E.; Ezawa, T.; Imamura, J.; Takenaka, T.; Tanabe, T.; Oshima, R.

    2002-12-01

    The effects of solute atoms on microstructural evolutions have been investigated using Ni alloys under 25 keV He + irradiation at 500 °C. The specimens used were pure Ni, Ni-Si, Ni-Co, Ni-Cu, Ni-Mn and Ni-Pd alloys with different volume size factors. The high number densities of dislocation loops about 1.5×10 22 m -3 were formed in the specimens irradiated to 1×10 19 ions/m 2, and they were approximately equivalent, except for Ni-Si. The mean size of loops tended to increase with the volume size factor of solute atoms. In a dose of 4×10 20 ions/m 2, the swelling was changed from 0.2% to 4.5%, depending on the volume size factors. The number densities of bubbles tended to increase with the absolute values of the volume size factor, and the swelling increased with the volume size factors. This suggests that the mobility of helium and vacancy atoms may be influenced by the interaction of solute atoms with them.

  9. Bonding Strength of Ni/Ni3Al Interface with Different Lattice Misfit

    Institute of Scientific and Technical Information of China (English)

    Ping PENG; Caixing ZHENG; Shaochang HAN; Zhaohui JIN; Rui YANG; Zhuangqi HU

    2003-01-01

    The interfacial binding covalent bond density (CBD) and the local environmental total bond order (LTBO) of the Ni/Ni3Alinterface with different lattice misfits (δ) were calculated by using first-principles discrete variation Xα method. It was foundthat

  10. Electrochemical Behaviour of Ni and Ni-PVC Electrodes for the Electroxidation of Ethanol

    International Nuclear Information System (INIS)

    Mohd Syafiq Hamdan; Norazzizi Nordin; Siti Fathrita Mohd Amir; Riyanto; Mohamed Rozali Othman

    2011-01-01

    In this study, two nickel based electrodes were prepared; nickel foil and nickel-polyvinylchloride (Ni-PVC), in order to study their electrochemical behavior using cyclic voltammetry, CV and chronocoulometry, CC. Ni electrode was prepared from Ni metal foil while Ni-PVC electrode was prepared by mixing a weighed portion of Ni powder and PVC in THF solvent, swirled until the suspension was homogeneous and drying the suspension in an oven at 50 degree Celsius for 3 h. The dry sample was then placed in a 1 cm diameter stainless steel mould and pressed at 10 ton/ cm 2 . From CV data, Ni-PVC electrode showed a better electrochemical behavior compared to Ni metal foil electrode. The use of Ni-PVC electrode at higher concentration of supporting electrolyte (1.0 M KOH) was better than at lower concentration of the same supporting electrolyte in electroxidation of ethanol. In addition to acetic acid, the oxidation of ethanol also produced ethyl acetate and acetaldehyde. (author)

  11. Room-temperature ferromagnetism in Dy films doped with Ni

    Energy Technology Data Exchange (ETDEWEB)

    Edelman, I. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation)], E-mail: ise@iph.krasn.ru; Ovchinnikov, S. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Siberian Federal University, Av. Svobodnyi 71, Krasnoyarsk 660074 (Russian Federation); Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Kesler, V. [Institute of Semiconductor Physics, Siberian Division, Russian Academy of Sciences, Av. Akademika Lavrent' eva 13, Novosibirsk 630090 (Russian Federation)

    2008-09-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy{sub (1-x)}Ni{sub x}-Ni and Dy{sub (1-x)}(NiFe){sub x}-NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy{sub (1-x)}Ni{sub x} owing to hybridization with narrow peaks near the Fermi level character for Ni.

  12. Room-temperature ferromagnetism in Dy films doped with Ni

    International Nuclear Information System (INIS)

    Edelman, I.; Ovchinnikov, S.; Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G.; Kesler, V.

    2008-01-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy (1-x) Ni x -Ni and Dy (1-x) (NiFe) x -NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy (1-x) Ni x owing to hybridization with narrow peaks near the Fermi level character for Ni

  13. Elementary martensitic transformation processes in Ni-rich NiTi single crystals with Ni4Ti3 precipitates

    International Nuclear Information System (INIS)

    Michutta, J.; Somsen, Ch.; Yawny, A.; Dlouhy, A.; Eggeler, G.

    2006-01-01

    The present study shows that multiple-step martensitic transformations can be observed in aged Ni-rich NiTi single crystals. Ageing of solution-annealed and water-quenched Ni-rich NiTi single crystals results in a homogeneous precipitation of coherent Ni 4 Ti 3 particles. When the interparticle spacing reaches a critical value (order of magnitude: 200 nm), three distinct transformation processes are observed on cooling from the high-temperature phase using differential scanning calorimetry and in situ transmission electron microscopy. The transformation sequence begins with the formation of R-phase starting from all precipitate/matrix interfaces (first step). The transformation continues with the formation of B19' and its subsequent growth along all precipitate/matrix interfaces (second step). Finally, the matrix in between the precipitates transforms to B19' (third step). Elementary transformation mechanisms which account for two- and three-step transformations in a system with small-scale microstructural heterogeneities were identified

  14. Probing the semi-magicity of $^{68}$Ni via the $^{3}$H($^{66}$Ni,$^{68}$Ni)p two-neutron transfer reaction in inverse kinematics

    CERN Multimedia

    Reiter, P; Blazhev, A A; Kruecken, R; Franchoo, S; Mertzimekis, T; Darby, I G; Van de walle, J; Raabe, R; Elseviers, J; Gernhaeuser, R A; Sorlin, O H; Georgiev, G P; Bree, N C F; Habs, D; Chapman, R; Gaudefroy, L; Diriken, J V J; Jenkins, D G; Kroell, T; Axiotis, M; Huyse, M L; Patronis, N

    We propose to perform the two-neutron transfer reaction $^{3}$H($^{66}$Ni, $^{68}$Ni)$p$ using the ISOLDE radioactive ion beam at 2.7 $A$ MeV and the MINIBALL + T-REX setup to characterize the 0$^{+}$ and 2$^{+}$ states in $^{68}$Ni.

  15. Mechanical alloying of the FeNi-Ag system

    International Nuclear Information System (INIS)

    Gonzalez, G.; Ibarra, D.; Ochoa, J.; Villalba, R.; Sagarzazu, A.

    2007-01-01

    The Fe-Ni-Ag system is of particular interest for its potential applications as soft magnetic granular material with small magnetic grains embedded in a non-magnetic metal matrix. Under equilibrium conditions: Fe-Ag and Ni-Ag are immiscible and Fe-Ni shows complete solubility. These materials are particularly important for magnetoresistivity properties. The properties of these alloys are closely related to their microstructure; therefore, a detailed study of the transformations occurring during milling was undertaken using pre-alloyed Fe x Ni 100-x (x = 30, 50 and 70) further milled with different Ag content to give the following alloys compositions (Fe x -Ni 100-x ) 100-y Ag y (y = 5, 20, 60). Consolidation of the mechanically alloyed powders by sintering at 950 o C was performed. Morphological and structural characterization of the sintered powders was carried out by scanning and transmission electron microscopy and X-ray diffraction. Fe 30 Ni 70 and Fe 50 Ni 50 formed ordered FeNi 3 compound. Fe 70 Ni 30 showed the formation of a mixture of γ-(Fe,Ni) and α-Fe(Ni) solid solutions. The mixture of these systems with Ag showed the metal solid solutions surrounded by Ag islands of Fe x Ni y -Ag, There was also evidence of Ag diffusing into the γ-(Fe,Ni). High Ag content (60%) shows formation of islands of FeNi surrounded by Ag. Sintering is always improved with the Ag content

  16. Effect of amount of glycine as fuel in obtaining nanocomposite Ni/NiO

    International Nuclear Information System (INIS)

    Simoes, A.N.; Simoes, V.N.; Neiva, L.S.; Quirino, M.R.; Vieira, D.A.; Gama, L.

    2010-01-01

    This paper proposes to investigate the effect of the amount of glycine in obtaining nanocomposite Ni/NiO synthesized by combustion reaction technique. The amount of glycine used was calculated on the stoichiometric composition of 50% and 100%. Characterizations by X-ray diffraction (XRD), N2 adsorption by the BET method and scanning electron microscopy (SEM) were performed with powder of Ni/NiO result. The analysis of X-ray diffraction showed the presence of crystalline NiO phase in the presence of nickel as a secondary phase, whose amount increased with the amount of glycine. Increasing the concentration of glycine also caused an increase in surface area, which ranged from 1.1 to 1.4 m 2 /g. The micrographs revealed the formation of soft agglomerates with porous appearance and easy dispersions. It can be concluded that the synthesis is effective to obtain nanosized powders. (author)

  17. Neutron enrichment at midrapidity in 58Ni + 58Ni at 52 MeV/u

    International Nuclear Information System (INIS)

    Theriault, D.; Vallee, A.; Gingras, L.; Larochelle, Y.; Roy, R.; April, A.; Beaulieu, L.; Grenier, F.; Lemieux, F.; Moisan, J.; Samri, M.; Saint-Pierre, C.; Turbide, S.; Yennello, S.J.; Martin, E.; Winchester, E.

    2003-01-01

    By combining data from a charged particle 58 Ni + 58 Ni experiment at 52 MeV/u with an 36 Ar + 58 Ni experiment at 50 MeV/u for which free neutrons have been detected, an increase in the neutron to proton ratio of the whole nuclear material at midrapidity has been experimentally observed in the reaction 58 Ni + 58 Ni at 52 MeV/u. The neutron to proton ratio is measured above the initial neutron to proton ratio of the system. Neutron to proton ratio of the quasi-projectile emission is analysed for the same reactions and is seen to decrease below the ratio of the initial system. (authors)

  18. Improvement of thermoelectric properties for half-Heusler TiNiSn by interstitial Ni defects

    International Nuclear Information System (INIS)

    Hazama, Hirofumi; Matsubara, Masato; Asahi, Ryoji; Takeuchi, Tsunehiro

    2011-01-01

    We have synthesized off-stoichiometric Ti-Ni-Sn half-Heusler thermoelectrics in order to investigate the relation between randomly distributed defects and thermoelectric properties. A small change in the composition of Ti-Ni-Sn causes a remarkable change in the thermal conductivity. An excess content of Ni realizes a low thermal conductivity of 2.93 W/mK at room temperature while keeping a high power factor. The low thermal conductivity originates in the defects generated by an excess content of Ni. To investigate the detailed defect structure, we have performed first-principles calculations and compared with x ray photoemission spectroscopy measurement. Based on these analyses, we conclude that the excess Ni atoms randomly occupy the vacant sites in the half-Heusler structure, which play as phonon scattering centers, resulting in significant improvement of the figure of merit without any substitutions of expensive heavy elements, such as Zr and Hf.

  19. FY 2000 report on the results of the research and development project for utilization of information of high-molecular-weight structures in a living body. Survey on the technological trends of utilizing the reactions with metals in a living body; 2000 nendo seitai kobunshi kozo joho riyo gijutsu kaihatsu chosa hokokusho. 'Seitai kinzoku hanno riyo gijutsu' ni kansuru gijutsu doko chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the FY 2000 results of the survey on the technological trends of utilizing the reactions with metals in a living body, noting the bio-processes effectively coping with the environmental problems. The effects of heavy metals on microorganisms have been investigated on the molecular biology level, but are not fully elucidated. Recently, the microorganisms capable of converting inorganic metal ions in water into the insoluble compounds have been known, leading to possibility of bioremediation to solve pollution by heavy metals, which have detrimental effects on human health. Heavy metals must be recovered, because they are not extinct by decomposition. The plant aided purification has been attracting attention to cope with heavy metals accumulated in soil. Application of bacteria-aided leaching, which is adopted as one ore smelting process, to the technologies for utilizing metals in a living body has been expected, because diversified activities of inanimate matters in extreme environments have been known. Recently, bio-machining of metals aided by Thiobacillus ferrooxidans, one species of independent nutrient bacteria capable of eating metals, has been developed to a potentially viable stage. (NEDO)

  20. Magnetoresistance of nanogranular Ni/NiO controlled by exchange anisotropy

    International Nuclear Information System (INIS)

    Del Bianco, L.; Spizzo, F.; Tamisari, M.; Allia, P.

    2013-01-01

    A link between exchange anisotropy and magnetoresistance has been found to occur in a Ni/NiO sample consisting of Ni nanocrystallites (mean size ∼13 nm, Ni content ∼33 vol%) dispersed in a NiO matrix. This material shows metallic-type electric conduction and isotropic spin-dependent magnetoresistance as well as exchange bias effect. The latter is the outcome of an exchange anisotropy arising from the contact interaction between the Ni phase and the NiO matrix. Combined analysis of magnetization M(H) and magnetoresistance MR(H) loops measured in the 5–250 K temperature range after zero-field-cooling (ZFC) and after field-cooling (FC) from 300 K reveals that the magnetoresistance is influenced by exchange anisotropy, which is triggered by the FC process and can be modified in strength by varying the temperature. Compared to the ZFC case, the exchange anisotropy produces a horizontal shift of the FC MR(H) loop along with a reduction of the MR response associated to the reorientation of the Ni moments. A strict connection between magnetoresistance and remanent magnetization of FC loops on one side and the exchange field on the other, ruled by exchange anisotropy, is indicated. - Highlights: • Nanogranular Ni/NiO with giant magnetoresistance (MR) and exchange bias effect. • Exchange anisotropy produces a shift of the field-cooled MR(H) loop and reduces MR. • MR, remanence of field-cooled loops and exchange field are three correlated quantities. • It is possible to control MR of nanogranular systems through the exchange anisotropy

  1. Ferromagnetic resonance study of sputtered NiFe/V/NiFe heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Alayo, W., E-mail: willian.rodriguez@ufpel.edu.br [Departamento de Física – IFM, Universidade Federal de Pelotas, 96010-900 Rio Grande do Sul (Brazil); Pelegrini, F. [Instituto de Física, Universidade Federal de Goiás, Goiânia, 74001-970 (Brazil); Baggio-Saitovitch, E. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro, RJ, 22290-180 (Brazil)

    2015-03-01

    The Ni{sub 81}Fe{sub 19}/V/Ni{sub 81}Fe{sub 19} heterostructures has been produced by magnetron sputtering and analyzed by ferromagnetic resonance. Two systems were investigated: the non symmetrical NiFe(50 Å)/V(t)/NiFe(30 Å) trilayers and the symmetrical NiFe(80 Å)/V(t)/NiFe(80 Å) trilayers, with variable ultrathin V thickness t. Ferromagnetic exchange coupling was evidenced for t below 10 Å by the excitation of the optic mode, in the case of the non symmetrical samples, and by the observation of a single resonance mode for the symmetrical trilayers. For larger V thickness, all samples exhibited two modes, which were attributed to the resonance of the individual NiFe layers with different effective magnetizations. The analysis with the equilibrium and resonance conditions provided the exchange coupling constants and effective magnetizations. - Highlights: • We present a study of symmetrical and non symmetrical NiFe/V/NiFe trilayers deposited on Si single crystals by ferromagnetic resonance (FMR) at room temperature. • For the non symmetrical trilayers, the FMR spectra show the optic and acoustic modes for samples with very thin V layer thicknesses, evidencing ferromagnetic exchange coupling, whereas, for larger V thickness, the spectra exhibited two well resolved modes associated to each independent NiFe layer. For the symmetrical trilayers, strong ferromagnetic exchange coupling is evidenced by the observation of a single resonance mode. • The analysis with the equilibrium condition and dispersion relation provides the exchange coupling constants and effective magnetizations.

  2. Hydrogen absorption kinetics and structural properties of Mg85Ni10Ca5 and Mg90Ni10

    International Nuclear Information System (INIS)

    Aoki, Masakazu; Saito, Katsushi; Towata, Shin-ichi

    2005-01-01

    Mg 85 Ni 10 Ca 5 and Mg 90 Ni 10 were prepared by melting mixtures of the elements in mild steel crucibles and pouring them into copper molds. Hydrogen absorption kinetics and structural properties of the alloys were characterized by the volumetric method using a Sievert's apparatus, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The crystallite size of Mg in Mg 85 Ni 10 Ca 5 , which is evaluated by XRD peak broadening, is about 50% smaller than that in Mg 90 Ni 10 . In addition, the nanometer-scale structure composed of Mg, Mg 2 Ni, Mg 2 Ca was observed in Mg 85 Ni 10 Ca 5 . Mg 85 Ni 10 Ca 5 shows better hydrogen absorption kinetics than Mg 90 Ni 10 in the temperature range of room temperature to 573 K. The better absorption kinetics of Mg 85 Ni 10 Ca 5 is mainly attributed to the nanometer-scale structure

  3. Sputtering Yields of Si and Ni from the Ni1-xSix System Studied by Rutherford Backscattering Spectrometry

    Science.gov (United States)

    Kim, Su Chol; Yamaguchi, Satoru; Kataoka, Yoshihide; Iwami, Motohiro; Hiraki, Akio; Satou, Mamoru; Fujimoto, Fuminori

    1982-01-01

    Sputtering yields of Si and Ni from thin layer films of Ni-Si compounds (Ni1-xSix), including the pure materials (Ni and Si), caused by 5 keV Ar+ ion bombardment were investigated using backscattering spectrometry. The sputtering yield for Si from Ni1-xSix increased with increasing Si concentration. However, there is an abrupt decrease in the yield for Si concentrations above NiSi2 to pure Si. This is in clear contrast to the sputtering yield of Ni from Ni1-xSix which increased with increasing Ni concentration monotonously. These results are discussed on the basis of both the difference in the atomic density and the electronic state of the alloy.

  4. Phase Equilibria of the Sn-Ni-Si Ternary System and Interfacial Reactions in Sn-(Cu)/Ni-Si Couples

    Science.gov (United States)

    Fang, Gu; Chen, Chih-chi

    2015-07-01

    Interfacial reactions in Sn/Ni-4.5 wt.%Si and Sn-Cu/Ni-4.5 wt.%Si couples at 250°C, and Sn-Ni-Si ternary phase equilibria at 250°C were investigated in this study. Ni-Si alloys, which are nonmagnetic, can be regarded as a diffusion barrier layer material in flip chip packaging. Solder/Ni-4.5 wt.%Si interfacial reactions are crucial to the reliability of soldered joints. Phase equilibria information is essential for development of solder/Ni-Si materials. No ternary compound is present in the Sn-Ni-Si ternary system at 250°C. Extended solubility of Si in the phases Ni3Sn2 and Ni3Sn is 3.8 and 6.1 at.%, respectively. As more Si dissolves in these phases their lattice constants decrease. No noticeable ternary solubility is observed for the other intermetallics. Interfacial reactions in solder/Ni-4.5 wt.%Si are similar to those for solder/Ni. Si does not alter the reaction phases. No Si solubility in the reaction phases was detected, although rates of growth of the reaction phases were reduced. Because the alloy Ni-4.5 wt.%Si reacts more slowly with solders than pure Ni, the Ni-4.5 wt.%Si alloy could be a potential new diffusion barrier layer material for flip chip packaging.

  5. Ni/boride interfaces and environmental embrittlement in Ni-based superalloys: A first-principles study

    International Nuclear Information System (INIS)

    Sanyal, Suchismita; Waghmare, Umesh V.; Hanlon, Timothy; Hall, Ernest L.

    2011-01-01

    Highlights: ► Fracture strengths of Ni/boride interfaces through first-principles calculations. ► Fracture strengths of Ni/boride interfaces are higher than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► Ni/boride interfaces have higher resistance to O-embrittlement than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► CrMo-borides are more effective than Cr-borides in resisting O-embrittlement. ► Electronegativity differences between alloying elements correlate with fracture strengths. - Abstract: Motivated by the vital role played by boride precipitates in Ni-based superalloys in improving mechanical properties such as creep rupture strength, fatigue crack growth rates and improved resistance towards environmental embrittlement , we estimate fracture strength of Ni/boride interfaces through determination of their work of separation using first-principles simulations. We find that the fracture strength of Ni/boride interfaces is higher than that of other commonly occurring interfaces in Ni-alloys, such as Ni Σ-5 grain boundaries and coherent Ni/Ni 3 Al interfaces, and is less susceptible to oxygen-induced embrittlement. Our calculations show how the presence of Mo in Ni/M 5 B 3 (M = Cr, Mo) interfaces leads to additional reduction in oxygen-induced embrittlement. Through Electron-Localization-Function based analyses, we identify the electronic origins of effects of alloying elements on fracture strengths of these interfaces and observe that chemical interactions stemming from electronegativity differences between different atomic species are responsible for the trends in calculated strengths. Our findings should be useful towards designing Ni-based alloys with higher interfacial strengths and reduced oxygen-induced embrittlement.

  6. Nickel distribution and isotopic fractionation in a Brazilian lateritic regolith: Coupling Ni isotopes and Ni K-edge XANES

    Science.gov (United States)

    Ratié, G.; Garnier, J.; Calmels, D.; Vantelon, D.; Guimarães, E.; Monvoisin, G.; Nouet, J.; Ponzevera, E.; Quantin, C.

    2018-06-01

    Ultramafic (UM) rocks are known to be nickel (Ni) rich and to weather quickly, which makes them a good candidate to look at the Ni isotope systematics during weathering processes at the Earth's surface. The present study aims at identifying the Ni solid speciation and discussing the weathering processes that produce Ni isotope fractionation in two deep laterite profiles under tropical conditions (Barro Alto, Goiás State, Brazil). While phyllosilicates and to a lower extent goethite are the main Ni-bearing phases in the saprolitic part of the profile, iron (Fe) oxides dominate the Ni budget in the lateritic unit. Nickel isotopic composition (δ60Ni values) has been measured in each unit of the regolith, i.e., rock, saprock, saprolite and laterite (n = 52). δ60Ni varies widely within the two laterite profiles, from -0.10 ± 0.05‰ to 1.43 ± 0.05‰, showing that significant Ni isotope fractionation occurs during the weathering of UM rocks. Overall, our results show that during weathering, the solid phase is depleted in heavy Ni isotopes due to the preferential sorption and incorporation of light Ni isotopes into Fe oxides; the same mechanisms likely apply to the incorporation of Ni into phyllosilicates (type 2:1). However, an isotopically heavy Ni pool is observed in the solid phase at the bottom of the saprolitic unit. This feature can be explained by two hypotheses that are not mutually exclusive: (i) a depletion in light Ni isotopes during the first stage of weathering due to the preferential dissolution of light Ni-containing minerals, and (ii) the sorption or incorporation of isotopically heavy Ni carried by percolating waters (groundwater samples have δ60Ni of 2.20 and 2.27‰), that were enriched in heavy Ni isotopes due to successive weathering processes in the overlying soil and laterite units.

  7. Fiscal 1975 Sunshine Project research report. General research on hydrogen energy subsystems and their peripheral technologies (Research on hydrogen gas turbine); 1975 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Suiso gas turbine ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-03-31

    This research aims at establishment of the meaning of using hydrogen as gas turbine fuel in the hydrogen energy system and various conditions for hydrogen gas turbines, and approaches to the feasibility study and R and D of hydrogen gas turbines in the future. In fiscal 1975, researches were made on (1) feasibility study on hydrogen-oxygen gas turbine, (2) establishment of various conditions for technical, social and economic realization of hydrogen gas turbines in the total energy system, and (3) study on technical troubles to be solved for realization of hydrogen gas turbines. For the above researches, study was made on hydrogen combustion based on the hydrogen combustion test result of gas mixture including hydrogen, and on the feasibility of aphodid cycle. In addition, study on the applicability of hydrogen-oxygen gas turbines, comparative study on hydrogen-oxygen gas turbine, MHD power generation and fuel cell, and the future prospect of hydrogen gas turbines for ships were made to place this hydrogen gas turbine. (NEDO)

  8. Indirect boundary element method on recursive matrix operation to compute waves in irregularly stratified media with infinitely extended interfaces. Perturbation by a point source; Kansetsu kyokai yosoho ni yoru fukisoku seiso kozochu no hadoba no keisanho. Tenshingen ni taisuru reference solution no riyo

    Energy Technology Data Exchange (ETDEWEB)

    Yokoi, T [Akita University, Akita (Japan). Mining College

    1996-05-01

    As a method of computation of wave fields in irregularly stratified media by use of the indirect boundary element method, an induction formula was proposed in a previous report, utilizing the reference solution representing the wave field in corresponding horizontally stratified media. This algorithm applies to other types of vibration source. In computation of a wave field with the focus in presence on the ground or in the ground, the algorithm is incorporated into the computation as a vector including the reference solution as a variable. There exists no need to modify the algorithm. Once the reference solution is obtained, the wave field in the irregularly stratified media is automatically constructed by the proposed algorithm. The wave field to be the reference solution to a point source in the horizontally stratified media, is determined when the solution is obtained of the frequency/wavenumber domain by use of the reflection/transmission matrix of Kennet (1983) and converted into the solution of the spatial domain by use of the discrete wavenumber representation of Bouchon and Aki (1977). 8 refs., 2 figs.

  9. Achievement report on research and development in the Sunshine Project in fiscal 1976. Comprehensive discussion on hydrogen utilizing subsystems and research on peripheral technologies (Research related to hydrogen gas turbines); 1976 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu. Suiso gas turbine ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-03-01

    This paper describes development of hydrogen gas turbines from among the comprehensive discussions on hydrogen utilizing subsystems. Hydrogen and oxygen gas turbine cycle has varying optimal conditions of plant efficiency depending on fuel patterns. The regenerative cycle may have the turbine inlet temperature at about 1,000 degrees C. The inlet pressure would be ten and odds atmospheric pressure. It is better to keep the inlet temperature higher in order to obtain high specific power. Reduction of power generation cost in using this plant requires that construction cost be decreased, and the specific power be increased if the plant efficiency (in other words, running cost) is assumed constant. Further development is required on technologies to use higher temperatures and pressures. For that purpose, discussions should be given on material development, structural design, and inspection. Hydrogen gas turbines, which present low pollution depending on combustion methods, have great significance for such social problem as environmental contamination. In terms of economy, since hydrogen gas turbines depend on efficiency and fuel unit cost, the evaluation thereon may vary depending on how well the regenerative gas turbines have been established, in addition to future change in hydrogen price and the technologies to use higher temperatures and pressures. (NEDO)

  10. FY 1974 report on the results of the Sunshine Project. Comprehensive study of hydrogen use subsystem and study on the periphery technology (Study on the hydrogen engine for airplane use); 1974 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Kokukiyo suiso engine ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-05-01

    This study is aimed at using hydrogen as fuel for airplane engine in the study on the use of hydrogen energy to be made as one of the new energy developments. In the investigational study plan, technical/economical possibilities of the airplane engine using hydrogen as fuel and the airplane carrying the engine are grasped to make the details of the R and D clear by the end of FY 1976. By the end of FY 1974, the actual state in the world of the airplane engine using hydrogen as fuel and the airplane carrying the engine was grasped to make the problems clear. The detailed R and D are as follows. (1) Survey of the actual state of and the problems of the hydrogen engine in Japan and abroad (to be conducted in FY 1974). (2) Consideration of the conceptual design of the potential hydrogen engine, and possibility of the commercialization and prediction of the time of the commercialization (to be conducted in FY 1975). (3) Survey of type, performance, etc. of the airplane carrying hydrogen engine, and the actual economical value and demand (to be conducted in FY 1976). This paper described the results of the survey on hydrogen general and hydrogen use airplane. (NEDO)

  11. Achievement report for fiscal 1999. Joint verification research on use for power generation of Omani superhigh-viscosity crude oil remaining unexploited; 1999 nendo Oman koku ni okeru miriyo chokonensei gen'yu no denryoku riyo ni kansuru kyodo jissho kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    A Mukhaizna oil field remains to be exploited in Oman, with an estimated reserve of 2.4-billion barrels of very heavy oil with an API (American Petroleum Institute) specific gravity of 15.3. The viscosity of the oil is so high as to be over 100-thousand cP (at 15 degrees C). The extremely high viscosity causes its exploitable rate to be so low as 3%, and makes shipment by pipeline quite difficult. In this survey, a method using water emulsion is proposed for viscosity reduction, which aims to reduce the Mukhaizna crude oil viscosity to 200mm2/s or less. In an experiment using the water emulsion method, oil is mixed with water at a rate of 72 to 28 in a shearing mixer for the production of a water emulsion of crude oil. It is found that a certain degree of stability is acquired using a surface active agent available on the market. Using this emulsion method, the crude oil is converted into a power generator fuel with a heating value of 6,775kcal/kg. The crude oil-turned product is a fine fuel superior to Orimulsion which is a fuel of the same type in terms of viscosity, amount of ash, and vanadium concentration. (NEDO)

  12. Achievement report for fiscal 1999. Joint verification research on use for power generation of Omani superhigh-viscosity crude oil remaining unexploited; 1999 nendo Oman koku ni okeru miriyo chokonensei gen'yu no denryoku riyo ni kansuru kyodo jissho kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    A Mukhaizna oil field remains to be exploited in Oman, with an estimated reserve of 2.4-billion barrels of very heavy oil with an API (American Petroleum Institute) specific gravity of 15.3. The viscosity of the oil is so high as to be over 100-thousand cP (at 15 degrees C). The extremely high viscosity causes its exploitable rate to be so low as 3%, and makes shipment by pipeline quite difficult. In this survey, a method using water emulsion is proposed for viscosity reduction, which aims to reduce the Mukhaizna crude oil viscosity to 200mm2/s or less. In an experiment using the water emulsion method, oil is mixed with water at a rate of 72 to 28 in a shearing mixer for the production of a water emulsion of crude oil. It is found that a certain degree of stability is acquired using a surface active agent available on the market. Using this emulsion method, the crude oil is converted into a power generator fuel with a heating value of 6,775kcal/kg. The crude oil-turned product is a fine fuel superior to Orimulsion which is a fuel of the same type in terms of viscosity, amount of ash, and vanadium concentration. (NEDO)

  13. FY 1997 report on the study on cryogenic aggregate target PLD process by multi-laser excitation for using gaseous materials; 1997 nendo chosa hokokusho (kitai genryo riyo no tame no taju laser reiki ni yoru gokuteion gyoshutai target PLD process ni kansuru kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper reports the result in fiscal 1995 of the study on PLD (pulse laser deposition) thin film formation process having been made since 1993. In fiscal 1995, the effect of irradiation of excimer laser and YGA(SHG) on ablation of aggregates of N2, CH4, Ar, Kr and Xe, and the effect of time-delayed irradiation of YGA(SHG) and KrF excimer laser on ablation of N2 aggregate were studied aiming at exciting ablation by cryogenic aggregate alone. Experimental results by a newly developed multi-laser excitation experiment equipment are as follows. Ablation was not caused by KrF excimer laser irradiation, while caused by YGA(SHG) irradiation. Ablation was caused by 1mm thick N2 or CH4 aggregate alone. Kr target was the most promising among rare gas solid targets expected as seed of ablation occurrence. Multi-irradiation showed a different ablation behavior as compared with single YGA(SHG) irradiation, and in some cases, multi-irradiation not increased scattering of particles. Time-delayed multi- irradiation (YGA(SHG) excitation after excimer excitation) was effective. 23 figs., 4 tabs.

  14. Study on fabrication methods of composite structures (1st. report); Joule effect curing of CFRP composite structures and its application to bonding and repair. Fukugo zai kozo no seikei kako ho ni kansuru kenkyu (Dai 1po); CFRP kozo no Joule koka wo riyo shita cure ho to setsugoter dot hoshu e no oyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Moriya, K. (The National Defense Academy, Kanagawa (Japan))

    1990-07-05

    A method for curing CFRP composite structures by using Joule effect is presented. Due to the presence of fiber to fiber contact, CFRP composites and their prepregs exhibit electrical conductivity in the direction transverse to fibers as well as in the fiber direction, and they can be considered as electrically homogeneous on a gross scale. Therefore, passing an electric current through a CFRP prepreg, it is self-heated due to the Joule effect. Feedback current control maintains the prepreg temperature at a desired level and makes the prepreg be cured by a specified cure cycle. Experimental verifiactions have been carried out to demonstrate the feasibility of the present technique. The applications to the bonding of CFRP components and to the patch repairs of effective CFRP structure are also described. 12 refs., 12 figs.

  15. Feasibility study of international cooperation in the research/development of a solar energy utilization system by the innovative solar thermochemical process; Kakushinteki solar netsukagaku process ni yoru taiyo energy riyo system no kaihatsu kenkyu ni kakawaru kokusai kyoryoku kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    At COP3 in 1997, an agreement was made to the innovative technical development/promotion by international cooperation, and the promotion of transfer of environmental technology to developing countries. Under the agreement, a feasibility study of international cooperation was made, and especially a study was conducted of the utilization/development of solar energy by the innovative solar thermochemical process. The main reason for global warming is emissions of a large amount of CO2 caused by the direct combustion of fossil fuels. Therefore, a CO2 recycle system taken up in the study enables a more substantial decline in CO2 emission (kg/kWh) per unit generation than the conventional thermal power system by composing solar methanol or solar dimethyl ether using fossil fuels including coal, water, CO2, etc. as raw materials and using solar energy as heat source, and by using this as fuel (solar fuel). CO2 can be reduced by 13% to 14% by substituting solar methanol or solar dimethyl ether produced from petroleum/methane equivalent-mol mixed raw materials for the equivalent mol coal and natural gas of the thermal power plant (CO2 recovery is not necessary). 34 refs., 47 figs., 34 tabs.

  16. FY 1974 report on the results of the Sunshine Project. Comprehensive study of hydrogen use subsystem and study on the periphery technology (Study on automobile engine); 1974 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Jidosha engine ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-05-10

    The paper made an investigational study of the data of a wide range which seems to be related to the use of hydrogen as automobile use fuel. The advantage is that the exhaust can almost be non-pollutant. The engine performance can be on the same level as that of the present gasoline engine or can be improved. The reasons are that the compression rate is heightened and that automobile can be driven at lean mixture rate. As to weak points, the volume and weight increase when it is loaded on vehicle. The cost of hydrogen is higher than that of petroleum. The problems to be quickly solved are as follows. Improvement of the combustion method: a wide range of development not only the electric ignition method, but the diesel method, and the basic study for it. It is necessary to establish the basis for a method to connect the storage method and engine. It is also necessary to comprehensively review rules related to safety. For the future, the conversion to artificial fuel is indispensable, and hydrogen has the most characteristics as energy medium. The problem is much larger sizes of fuel tank and pump, but there will be a possibility of producing a new technology together with the hydrogen production technology. The fundamental research should be promoted without any hesitation. (translated by NEDO)

  17. Fiscal 1975 Sunshine Project research report. General research on hydrogen energy subsystems and their peripheral technologies (Research on peripheral technologies around hydrogen); 1975 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Suiso no shuhen gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-03-01

    This report summarizes the fiscal 1975 research result on peripheral and seed technologies for hydrogen energy systems. Chapter 1 'Evaluation method for thermochemical techniques' reports critical study on qualitative evaluation method, estimation method for thermal efficiencies, and trial cost calculation example. Chapter 2 'Current state and problems of water electrolysis and hybrid technique composed of electrolysis and thermochemical technique' reports general survey on current water electrolysis and new technologies under development to clarify possible electrolytic voltage drop, from the practical viewpoint. Chapter 3 'Use of a high- temperature gas cooling reactor for hydrogen production' reports survey on the current and future reactors, and characteristics of such nuclear reactors, from the viewpoint that study on thermochemical technique is dependent on use of a high-temperature gas cooling reactor. Chapter 4 'Hydrogen transport and storage technology using organic compounds including oxygen' reports that acetone-isopropanol system is better for hydrogen storage. Chapter 5 'Water electrolysis using photo-semiconducting electrode' reports the additional survey. (NEDO)

  18. Fiscal 1975 Sunshine Project research report. General research on hydrogen energy subsystems and their peripheral technologies (Research on automobile engine); 1975 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Jidosha engine ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-05-10

    This report summarizes the fiscal 1975 research results, and proposes the policy toward the future as follows. (1) Computational prediction on the future trend of hydrogen energy is active in the U.S.A. (2) For application of hydrogen derived from coal to transport, chemical synthesis of methane, methanol and gasoline from such hydrogen is in proposal because of difficult transport of LH{sub 2} or MH{sub 2}. (3) Complete run of Musashi Institute of Technology's LH{sub 2} passenger car in a long-distance rally, and trial run of Billings' MH{sub 2} minibus as challenge to practical use indicated new data, features and problems for hydrogen vehicles through experiences. (4) Conversion from a conventional soft-oriented attitude to a hard-oriented one is thus necessary. (5) Preparation of LH{sub 2} production facility is also necessary. (6) Stabilization of atomic hydrogen, expected various hydrides, and an H{sub 2}-O{sub 2}-water engine as new ideas are stimulating many researchers. (7) Study on gasoline cracking methods such as JPL is active. (8) Doubled cost of gasoline will probably promote practical use of hydrogen vehicles. (NEDO)

  19. FY 1974 report on the results of the Sunshine Project. Comprehensive study of hydrogen use subsystem and study on the periphery technology (Study on the periphery technology of hydrogen); 1974 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Suiso no shuhen gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-05-01

    This is aimed at making an investigational study on the periphery technology and sprouting technology of the hydrogen energy system. In Volume 1, 'Technology of hydrogen production,' as to the hydrogen production, the paper summed up the expected technical subjects on the electrolysis method and thermochemical method. The paper further included the survey of the direct pyrolysis method and the hydrogen production method using solar energy. Concerning the latter, in Volume 2, the light electrode reaction was theoretically developed, and samples of various hybrid methods were concretely studied. In relation to subjects on hydrogen and materials, in Volume 3, the results were described of the investigation into the hydrogen behavior in metal which is the most basic field of the subjects. About the storage method which is important as periphery technology, the study was made of the methods which can be expected but liquefied hydrogen and metal hydride which are now under research and development. In the last volume, as a part of the work to review the hydrogen energy system from a wider viewpoint, the basic study was additionally made in comparison with the system using coal. (NEDO)

  20. Achievement report on research and development in the Sunshine Project in fiscal 1976. Comprehensive discussion on hydrogen utilizing subsystems and research on peripheral technologies (Research for aircraft engines); 1976 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Koku engine ni kansuru kenkyu (furoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-05-01

    This paper introduces two out of six theses related to hydrogen fueled aircraft engines presented at the First World Hydrogen Energy Conference held in Miami in March 1976. One thesis mentions several initial prospects related to terrestrial requirements on hydrogen fueled transport aircraft. Liquefied hydrogen is attractive for large long-distance transport aircraft. Its high energy content can reduce the take-off full load weight by more than 30%, enhancing the economic effect of the aircraft. Saving fossil fuels will require national policy decisions in the near future, where introduction of liquefied hydrogen is more advantageous for long-distance aircraft. However, its introduction into wide-body transport aircraft being the major consumer requires transportation companies and airport authorities to carry out joint development with transport aircraft makers and liquefied hydrogen suppliers. The second thesis describes special natures of fuel subsystems for liquefied hydrogen fueled aircraft. Requirements to major fuel system elements and operation characteristics require evaluation as a comprehensive system, rather than as individual component criteria. In addition, hardware, experience and fuel systems as they are now in space development may not necessarily serve for the purpose. (NEDO)

  1. Achievement report on research and development in the Sunshine Project in fiscal 1976. Comprehensive discussion on hydrogen utilizing subsystems and research on peripheral technologies (Research for aircraft engines); 1976 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Koku engine ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-05-01

    With an objective to utilize hydrogen fuel in aircraft engines, a conceptual design survey was carried out on medium size transport aircraft. Large size long-distance aircraft and SST loaded with a great amount of fuel have the jet fuel (JP) increase take-off weight, affecting largely the selection of wing area and engine thrust. If the hydrogen fuel can be liquefied, large reduction can be achieved and the economic effect can be increased. However, for short-distance transport aircraft, the fuel weight ratio is small, where no large advantage is anticipated even if hydrogen is liquefied. Nevertheless, considering oil depletion in the future, a conceptual design was performed on the YX2688 short-medium distance aircraft being discussed of development. Even the short-medium distance aircraft that can be developed and commercialized as civilian use aircraft has a number of common points with large aircraft development, such as hydrogen fuel using technologies and safety. Although the advantage of using liquefied hydrogen as fuel may of course be smaller in the short-medium distance aircraft than in larger aircraft, the trend of using hydrogen fuel is historical necessity, whose development plans should be moved forward. (NEDO)

  2. FY 1999 report on the potential survey of the environmental friendly type coal utilization system. Survey on the spread/promotion of circulating fluidized bed boilers in China; 1999 nendo chosa hokoksho. Kankyo chowagata sekitan riyo system kanosei chosa. Chugoku ni okeru junkan yukaboira no fukyu sokushin ni kakawaru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of contributing to the spread/promotion of Japanese-make circulating fluidized bed boilers with desulfurization function, survey was conducted of the state of utilization of circulating fluidized bed boilers, the needs, etc. in China. In the survey, field survey was made at two boiler manufacturers and four companies using boilers in Beijing city, Fujian province, Hubei province, etc. to grasp the state of utilization and study conditions for the spread/promotion of circulating fluidized bed boilers. The Chinese government is making efforts for the spread of circulating fluidized bed boilers. The number of the domestically existing circulating fluidized bed boilers is estimated at approximately 800, but almost none of them conducts furnace desulfurization. Further, the operating rate of boiler is not always high. The reasons are as follows: desulfurization costs high without connecting to the production; environmental regulation is still mild in China; reliability and maintenance technique are still at low levels. It is urgently desirable to spread highly reliable circulating fluidized bed boilers with desulfurization function, and accordingly, it is necessary to reduce the cost of Japanese-make boilers. (NEDO)

  3. Project to support promotion of forming an environmentally friendly energy community. Survey report on 'a survey on introduction of an RDF electric power generation system utilizing general wastes in the Noto area'; Kankyo chowagata energy community keisei sokushin hojo jigyo. 'Noto chiiki ni okeru ippan haikibutsu riyo RDF hatsuden no donyu ni kansuru chosa' chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A business feasibility survey was performed on introduction of an RDF electric power generation system utilizing general wastes in the Noto area. Wastes quantity was estimated by accounting for large-sized wastes to be generated newly as a result of enforcement of the container package recycling law, and transfer of non-combustible wastes to incineration. The quantity was estimated to be 84,000 tons annually. Quantities of RDF and heat were calculated from this estimation to be 103 tons per day and 400 lkcal/kg respectively. According to the result of discussing the RDF transportation systems, time-based freight was found advantageous for short distance, and distance freight system for long distance in terms of cost. Discussions for RDF power systems were carried out on an RDF circulation fluid bed furnace plus ash melting furnace, a fluid bed gasification melting furnace, and shaft furnace type gasification melting furnace. In a comprehensive view, it is difficult to distinguish them in terms of merit and demerit. Molten slag was assumed to be re-utilized, but cost for the re-utilization should be considered. According to the result of discussing the business feasibility, it was found difficult to make it profitable by operating the RDF power generation business alone, and wastes incineration charge should be collected. (NEDO)

  4. Achievement report on research and development in the Sunshine Project in fiscal 1976. Comprehensive discussion on a hydrogen utilizing subsystem and research on peripheral technologies (Research on peripheral technologies for hydrogen); 1976 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Suiso no shuhen gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-03-01

    This paper describes research on peripheral technologies for hydrogen. For the cost of manufacturing hydrogen from different primary energies, coal gasification could be the lowest at the present time. In the nuclear power field, the thermo-chemical method and the water electrolysing method may be assumed, but they depend greatly on future technological development. Particularly the water electrolysing method is dependent on electric power cost. In the hybrid method, hydrogen is obtained from electrolysing reaction with water of sulfur dioxide derived by paralyzing sulfuric acid (oxygen is also generated). The method requires two forms of energies, heat and electric power, whereas combination with a very high temperature reactor (VHTR) is being discussed as a heat source. This method may not be said greatly more advantageous than the direct water electrolysis, but may have future possibility. Hydrogen manufacturing utilizing living organisms is an interesting matter in terms of science and engineering, with a large number of research achievements beginning to appear. Expectation is drawn on the mechanism based on co-work of photosynthesis and a hydrogen generation system, alga and bacterium strain search, separation, cultivation, and applied research and development. Research is also under way to obtain hydrogen by converting photo-energy by using an electrochemical photo-cell utilizing semiconductor electrode to electrolyse water (color sensitizing) (NEDO)

  5. Fiscal 1975 Sunshine Project research report. General research on hydrogen energy subsystems and their peripheral technologies (Research on automobile engine); 1975 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Jidosha engine ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-05-10

    This report summarizes the fiscal 1975 research results, and proposes the policy toward the future as follows. (1) Computational prediction on the future trend of hydrogen energy is active in the U.S.A. (2) For application of hydrogen derived from coal to transport, chemical synthesis of methane, methanol and gasoline from such hydrogen is in proposal because of difficult transport of LH{sub 2} or MH{sub 2}. (3) Complete run of Musashi Institute of Technology's LH{sub 2} passenger car in a long-distance rally, and trial run of Billings' MH{sub 2} minibus as challenge to practical use indicated new data, features and problems for hydrogen vehicles through experiences. (4) Conversion from a conventional soft-oriented attitude to a hard-oriented one is thus necessary. (5) Preparation of LH{sub 2} production facility is also necessary. (6) Stabilization of atomic hydrogen, expected various hydrides, and an H{sub 2}-O{sub 2}-water engine as new ideas are stimulating many researchers. (7) Study on gasoline cracking methods such as JPL is active. (8) Doubled cost of gasoline will probably promote practical use of hydrogen vehicles. (NEDO)

  6. FY 1997 report on the survey on the current residential waste treatment and integrated utilization of waste including heat supply in Shanghai city; 1997 nendo chosa hokokusho (Shanghai shi ni okeru seikatsu gomi shori no genjo narabini kyonetsunado wo fukumu sogo riyo ni kansuru chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Survey was made on residential waste treatment in Shanghai city. Shanghai city with nearly 13 million registered residents produces on average 10,000-11,000 tons/day residential solid wastes. Such wastes are basically disposed by land filling. A landfill site has a current disposal capacity of 7,500 tons/day, and is scheduled to be expanded up to 9,000 tons/day. Problems of waste disposal in Shanghai city are as follows: transportation of wastes collected in the city by trucks, transportation through transit stations to the landfill site by ships, and high disposal cost. Shanghai Environmental Sanitation Bureau is pursuing researches on recycling of wastes, reduction of wastes and harmless treatment in place of conventional land filling. As the survey result, adoption of complete separate collection of wastes is basically important, and application of the latest technologies such as combustion treatment for every waste, heat use, gasification fusion furnace, and RDF (refuse derived fuel) for coal-firing boilers should be considered. 86 figs., 18 tabs.

  7. Fiscal 1997 survey report. Investigational study on the cascade utilization of thermal energy (cold heat and hot heat) (feasibility study by the off-line system); 1997 nendo chosa hokokusho. Netsu energy (reinetsu to onnetsu) no cascade riyo ni kansuru chosa kenkyu (off-line hoshiki ni yoru feasibility study)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper studied a system to effectively use unused and low-grade thermal energy (cold heat and hot heat) in the Tokyo-Yokohama seaside area. For transportation of thermal energy, the batch transportation, that is, off-line system was discussed which uses insulated tank loaded barges and railroad freight trains. Thermal energy supply sources are 1) 0.3 million kW class thermal power plant, and 2) LNG storage base of 3 million ton/year class. Thermal energy users are Tokyo (Haneda) Airport D.H.C. (District Heating/Cooling Co.), MM 21 D.H.C. and Shin-Kawasaki D.H.C. The cold heat energy supplied to these three is about 1.5 million Mcal/daytimes300 days/year, and the hot heat energy supplied is about 1.33 million Mcal/daytimes150 days/year. Cold heat is obtained from seawater after the LNG vaporization, and hot heat from heat extracted from thermal turbine. Subcooled ice was selected for cold heat medium, and PCM-120A for hot heat medium. For batch transportation, an STL heat storage system is used which transports plastic capsules sealed with heat medium. Oil saving of 62,000 tons/year and CO2 reduction of about 53,000 tons/year can be expected. 85 figs., 98 tabs.

  8. Fiscal 1995 survey of the base arrangement promotion for foreign coal import. Investigation on the policy of coal demand stabilization using low grade coal; 1995 nendo kaigaitan yunyu kiban sokushin chosa. Teihin`itan riyo ni yoru sekitan jukyu anteika hosaku ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The paper investigated the trend of and the needs for low grade coal utilization and the seeds of low grade coal utilization technology and studied usability of low grade coal in the future. Importance of low grade coal utilization was described in consideration of features of the Asia/Pacific area in the world coal market, and the trend of production/utilization of low grade coal was examined mostly in countries holding main low grade coals in the Asia/Pacific area. The trend of the technical development contributing to the low grade coal utilization was studied to make it contribute to the extraction of technologies which are regarded as effective in the Asia/Pacific area. A study was made of applicability of the low grade coal utilization technology corresponding to the needs for low grade coal utilization, and at the same time, a study was made of the effect on the coal supply/demand in the Asia/Pacific area in case the low grade coal utilization is promoted helped by the study. Focusing on technical cooperation relating to clean coal technology, a study was conducted of the trend of international cooperation in Japan and various overseas countries and the trend of new cooperation in private sectors, and a discussion was made on how Japan should act toward promotion of low grade coal utilization. 12 figs., 91 tabs.

  9. Achievement report on research and development in the Sunshine Project in fiscal 1976. Comprehensive discussion on hydrogen utilizing subsystems and researches on peripheral technologies (Research related to automotive engines); 1976 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Jidosha engine ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-03-01

    This paper discusses hydrogen fueled automotive engines. Because hydrogen has a very wide ignition mixture ratio limit for spark ignition engines, very lean combustion is possible without a need of throttling, and thermal efficiency in partial load is high. Thermal efficiency while a car is being driven is reportedly higher by 30% to 50%. Values for CO and CH in exhaust gas are negligible, while NOx is at about the same degree as in gasoline engines, which can be made extremely low during lean burn operation. The spontaneous ignition temperature is higher by about 200 degrees C than that of light oil, which presents difficulty in use for diesel engines. Because of small ignition energy and high combustion velocity, excessively early ignition and reverse ignition can occur easily. Hydrogen would be promising if new manufacturing systems are developed and production cost is reduced, and on the other hand, if petroleum price rises sharply. Hydrogen is also expected as a measure to prevent pollution, including that from soot, odor and CO2. The largest difficulty is in the transportation method, and the only possible method at the present is transportation in liquefied hydrogen form. However, practical application will have such problems as tanks, feeding devices, and cost. Development is desired on light-weight metallic hydrides. Technologies for safety and engine performance must also be developed. (NEDO)

  10. Fiscal 1975 Sunshine Project research report. General research on hydrogen energy subsystems and their peripheral technologies (Research on hydrogen engine for aircraft); 1975 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Kokukiyo suiso engine ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-05-01

    This report summarizes the research results on (1) the prospect of an aviation system based on hydrogen energy, (2) the total system of aircraft based on hydrogen energy, and (3) the performance, structure and specifications of airplanes and engines using synthetic fuel such as hydrogen. In (1), study was made on air transport energy, and prediction was made on the demand of liquid hydrogen assuming conversion of petroleum fuel into hydrogen fuel in the future. In (2), the supply system of liquid hydrogen is essential in conversion of current aircraft fuel into liquid hydrogen. Such supply system over the world is also necessary in conversion into liquid hydrogen for both domestic and international airlines. In (3), in order to discuss the feasibility of liquid hydrogen fuel aircraft, the merit of such aircraft as compared with current aircraft using JP fuel, and whether designing a new airframe or modifying existing airframes, study was made conceptually on the size and capacity of airframe by statistical treatment and analysis of previous conceptual designs. (NEDO)

  11. Annual cycle solar energy utilization with seasonal storage. Part 7. Examination on design and control of the system partially recovering exhaust heat of heat pump; Kisetsukan chikunetsu ni yoru nenkan cycle taiyo energy riyo system ni kansuru kenkyu. 7. Bubuntekina hainetsu kaishu wo koryoshita baai no sekkei seigyoho no kento

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, H; Okumiya, M [Nagoya University, Nagoya (Japan)

    1996-10-27

    The capacity and performance of the existing system that recovers the overall heating and cooling exhaust heat completely into a seasonal storage tank and the system that discharges the exhaust heat slightly to the outside and recovers it partially were compared and investigated. The system uses a central single-duct discharge system as an air-conditioning system. A heat pump and a flat-plate solar collector installed on the roof of a building are used as the heat source. The seasonal storage tank in the ground just under the building is a cylindrical water tank of 5 m deep with the concrete used as body. The upper surface of a storage tank is heat-insulated by a stylo-platform of 200 mm, and the lower side surface by a stylo-platform of 100 mm. Calculation when the difference in temperature used in a seasonal storage tank is set to 35{degree}C and 25{degree}C was performed for the system that has two control methods. The overall exhaust heat recovery system is almost the same in energy performance as the partial exhaust heat recovery system. The partial exhaust heat recovery system is more advantageous on the economic side. 4 refs., 6 figs., 3 tabs.

  12. FY 2000 report on the basic survey to promote the joint implementation. Potential survey of the greenhouse effect gas reduction by high-efficient utilization of the oil residue in Bataan Refinery in the Philippines; 2000 nendo kyodo jisshi nado suishin kiso chosa hokokusho. Philippines koku Bataan seiyusho ni okeru sekiyu zansa kokoritsu riyo ni yoru onshitsu koka gas sakugen kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of reducing the CO2 emitted from electricity/vapor supply facilities of Bataan Refinery in the Philippines, study was conducted of optimum energy supply facilities considering the effective use of the oil residue and future reinforcement of the refinery. Concerning the high-pressure/high-temperature condensing extraction boiler/turbine cogeneration, gas turbine cogeneration and low speed diesel engine cogeneration, comparative study was carried out in terms of thermal efficiency, reliability/preservation, environmental acceptability, effectiveness of measures for the future excessive oil residue, etc. As a result, the study was concluded as follows: the electric power consumption will markedly increase in the future; however, in the light of the situation of the refinery where the vapor demand will not increase, it is the most suitable to use low speed diesel engine cogeneration facilities as on-site power generation facilities which can burn the excessively increasing oil residue as direct fuel. The CO2 reduction effect estimated from the project on the present scale was 132,880 t-CO2/y, and the energy conservation effect estimated was 50,861 toe/y. (NEDO)

  13. FY 1974 report on the results of the Sunshine Project. Comprehensive study of hydrogen use subsystem and study on the periphery technology (Study on the periphery technology of hydrogen); 1974 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Suiso no shuhen gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-05-01

    This is aimed at making an investigational study on the periphery technology and sprouting technology of the hydrogen energy system. In Volume 1, 'Technology of hydrogen production,' as to the hydrogen production, the paper summed up the expected technical subjects on the electrolysis method and thermochemical method. The paper further included the survey of the direct pyrolysis method and the hydrogen production method using solar energy. Concerning the latter, in Volume 2, the light electrode reaction was theoretically developed, and samples of various hybrid methods were concretely studied. In relation to subjects on hydrogen and materials, in Volume 3, the results were described of the investigation into the hydrogen behavior in metal which is the most basic field of the subjects. About the storage method which is important as periphery technology, the study was made of the methods which can be expected but liquefied hydrogen and metal hydride which are now under research and development. In the last volume, as a part of the work to review the hydrogen energy system from a wider viewpoint, the basic study was additionally made in comparison with the system using coal. (NEDO)

  14. Fiscal 1999 hydrogen utilization international clean energy system technology (WE-NET). Phase 2 R and D (Task 3) - survey/study concerning international cooperation (Survey/study concerning standardization of hydrogen energy technology); 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu. Task 3. Kokusai kyoryoku ni kansuru kenkyu (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    With the aim of R and D of hydrogen energy technologies and the promotion of their practical use and proliferation, conducted were research on standardization of hydrogen energy technologies and research/study on draft international standards proposed by ISO/TC197. In the research on the standardization, legislation, rules and guidelines for Japan were compiled based on reference to the materials in the 'sourcebook for hydrogen applications' which was prepared in the U.S./Canada. The Japanese laws and regulations applicable to hydrogen are the high pressure gas safety law, fire service law, industrial safety and health law, building standard law, law on prevention of disasters in petroleum industrial complexes and other petroleum facilities, road vehicles act, road traffic law, harbor regulation law, etc., with related legislation compiled under headings classified as pressure containers, gas facilities, consumption, transportation, explosion proofing of electrical equipment, list of laws, and related documents. In reference to ISO/TC197, the 8th plenary meeting and WGs were held during April 6-8, 1999, in the U.S., where the progress status report, study contents, future schedule for newly proposed items, etc., of each WG were reviewed and discussed. (NEDO)

  15. Fiscal 1999 hydrogen utilization international clean energy system technology (WE-NET). Phase 2 R and D (Task 3) - survey/study concerning international cooperation (Survey/study concerning standardization of hydrogen energy technology); 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu. Task 3. Kokusai kyoryoku ni kansuru kenkyu (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    With the aim of R and D of hydrogen energy technologies and the promotion of their practical use and proliferation, conducted were research on standardization of hydrogen energy technologies and research/study on draft international standards proposed by ISO/TC197. In the research on the standardization, legislation, rules and guidelines for Japan were compiled based on reference to the materials in the 'sourcebook for hydrogen applications' which was prepared in the U.S./Canada. The Japanese laws and regulations applicable to hydrogen are the high pressure gas safety law, fire service law, industrial safety and health law, building standard law, law on prevention of disasters in petroleum industrial complexes and other petroleum facilities, road vehicles act, road traffic law, harbor regulation law, etc., with related legislation compiled under headings classified as pressure containers, gas facilities, consumption, transportation, explosion proofing of electrical equipment, list of laws, and related documents. In reference to ISO/TC197, the 8th plenary meeting and WGs were held during April 6-8, 1999, in the U.S., where the progress status report, study contents, future schedule for newly proposed items, etc., of each WG were reviewed and discussed. (NEDO)

  16. The acceleration intermediate phase (NiS and Ni3S2) evolution by nanocrystallization in Li/NiS2 thermal batteries with high specific capacity

    Science.gov (United States)

    Jin, Chuanyu; Zhou, Lingping; Fu, Licai; Zhu, Jiajun; Li, Deyi; Yang, Wulin

    2017-06-01

    The intermediate phase of NiS2 is thought to be a bottleneck currently to improve the overall performance of Li/NiS2 thermal batteries because of its low conductivity and close formation enthalpy between NiS2 and the intermediate phase (NiS, Ni3S2, etc). For improving the discharge performances of Li/NiS2 thermal batteries, the nano NiS2 with an average size of 85 ± 5 nm is designated as a cathode material. The electrochemical measurements show that the specific capacity of nano NiS2 cathode is higher than micro NiS2. The nano NiS2 cathode exhibits excellent electrochemical performances with high specific capacities of 794 and 654 mAh g-1 at current density of 0.1 and 0.5 A cm-2 under a cut-off voltage of 0.5 V, respectively. These results show that the rapid intermediate phase evolution from the nanocrystallization can obviously enhance use efficiency of NiS2 and improve discharge performances of thermal batteries.

  17. Room temperature isotherms for Mo and Ni

    International Nuclear Information System (INIS)

    Masse, J.L.

    1986-11-01

    Isotherms at room temperature for Mo and Ni are proposed. They are of three types: BIRCH, KEANE and BORN-MIE. The adjustable constants appearing in these isotherms have been determined from experimental quantities at zero pressure. An evaluation of the limit of (δB T /δP) T as P #-> # ∞, where B T is the isothermal bulk modulus, has been also used. These three isotherms obtained for Mo and Ni are compared with isotherms derived from shock-wave data according to the PRIETO's model. There is a good agreement between these and these derived from shock-wave data. The three isotherms proposed for Mo and Ni can be considered as valid until pressures of several B To , where B To is the bulk modulus B T at P = o [fr

  18. Advances in developing TiNi nanoparticles

    International Nuclear Information System (INIS)

    Castro, A. Torres; Cuellar, E. Lopez; Mendez, U. Ortiz; Yacaman, M. Jose

    2006-01-01

    The elaboration of nanoparticles has become a field of great interest for many scientists. Nanoparticles possess different properties than those ones shown in bulk materials. Shape memory alloys have the exceptional ability to recuperate its original shape by simple heating after being 'plastically' deformed. When this process is originated, important changes in properties, as mechanical and electrical, are developed in bulk material. If there is possible to obtain nanoparticles with shape memory effects, these nanoparticles could be used in the elaboration of nanofluids with the ability to change their electrical and thermal conductivity with temperature changes, i.e., smart nanofluids. In this work, some recent results and discussion of TiNi nanoparticles obtained by ion beam milling directly from a TiNi wire with shape memory are presented. The nanoparticles obtained by this process are about 2 nm of diameter with a composition of Ti-41.0 at.% Ni. Synthesized nanoparticles elaborated by this method have an ordered structure

  19. Cutting NiTi with Femtosecond Laser

    Directory of Open Access Journals (Sweden)

    L. Quintino

    2013-01-01

    Full Text Available Superelastic shape memory alloys are difficult to machine by thermal processes due to the facility for Ti oxidation and by mechanical processes due to their superelastic behavior. In this study, femtosecond lasers were tested to analyze the potential for machining NiTi since femtosecond lasers allow nonthermal processing of materials by ablation. The effect of processing parameters on machining depth was studied, and material removal rates were computed. Surfaces produced were analyzed under SEM which shows a resolidified thin layer with minimal heat affected zones. However, for high cutting speeds, that is, for short interaction times, this layer was not observed. A depletion of Ni was seen which may be beneficial in biomedical applications since Ni is known to produce human tissue reactions in biophysical environments.

  20. La niña proletaria

    Directory of Open Access Journals (Sweden)

    Cartabia, Sabrina A.

    2011-12-01

    Full Text Available El presente trabajo se propone trazar un paralelo entre el cuento de Osvaldo Lamborghini “El niño proletario”, el cual, según la autora del ensayo, introduce al lector en la lucha de clases y el sometimiento de los/as proletarios/as, que sufren las mujeres, en particular a través de la violencia sexual. De esa forma la autora se pregunta si el poder que ciertas clases detentan sobre otras no influye también sobre el sometimiento de la mujer. El ensayo analiza además cómo la violencia sexual es una herramienta que constituye la base de la desigualdad, el sometimiento y la degradación de la mujer, al igual que constituye una herramienta de opresión de otros grupos vulnerables como los niños y niñas.

  1. Effects of phase transformation and interdiffusion on the exchange bias of NiFe/NiMn

    International Nuclear Information System (INIS)

    Lai, Chih-Huang; Lien, W. C.; Chen, F. R.; Kai, J. J.; Mao, S.

    2001-01-01

    The correlation between the exchange field of NiFe/NiMn and the phase transformation of NiMn was investigated. Transmission electron microscopy (TEM) dark-field images, contributed by the order phase of NiMn, were used to identify the location and volume fraction of the order phase. TEM selected area diffraction patterns showed the (110) superlattice diffraction rings of NiMn, verifying the existence of the order phase in the annealed samples. The order volume fraction can be calculated by the dark field image contributed by the (110) diffraction. The exchange field increased almost linearly with increasing order volume fraction. Energy dispersive x-ray spectroscopy attached to TEM indicated that Mn diffused into NiFe for annealing at 280 degreeC, leading to a larger coercivity and small coercivity squareness. Part of the NiMn still maintains the paramagnetic phase even after annealing at 280 degreeC. [copyright] 2001 American Institute of Physics

  2. Ni3Si2 nanowires grown in situ on Ni foam for high-performance supercapacitors

    Science.gov (United States)

    Jiang, Yizhe; Li, Zhihui; Li, Beibei; Zhang, Jinying; Niu, Chunming

    2016-07-01

    Ni3Si2 nanowires and nanoawls have grown in situ on the surface of Ni foams by a controlled low pressure chemical vapor deposition process. Structural characterization shows that the individual Ni3Si2 nanowire is single crystal covered with a thin layer (1-2 nm) of SiO2 with a diameter of ∼20-30 nm and length of ten's micrometers. Individual nanoawl with a circular cone shape is polycrystalline. Both Ni3Si2 nanowire and nanoawl samples are evaluated as potential electrode materials for supercapacitors. The nanowire electrode delivers a very high specific capacitance and excellent rate capability. A specific capacitance of 760 F g-1 is measured at current density of 0.5 A g-1, which decreases to 518 F g-1 when the current density increases to 10 A g-1. The capacitance is dominated by pseudocapacitance with a mechanism similar to that of NiO or Ni(OH)2 widely studied in the literature. An asymmetric supercapacitor fabricated by pairing Ni3Si2 nanowire electrode with an activated carbon electrode exhibits energy densities of 17.5 Wh kg-1 and 8.8 Wh kg-1 at power densites of 301 W kg-1 and 3000 W kg-1.

  3. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    Energy Technology Data Exchange (ETDEWEB)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace, E-mail: jglin@ntu.edu.tw

    2017-02-15

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  4. Radiation damage buildup and dislocation evolution in Ni and equiatomic multicomponent Ni-based alloys

    Energy Technology Data Exchange (ETDEWEB)

    Levo, E. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Granberg, F., E-mail: fredric.granberg@helsinki.fi [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Fridlund, C.; Nordlund, K. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Djurabekova, F. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Helsinki Institute of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland)

    2017-07-15

    Single-phase multicomponent alloys of equal atomic concentrations (“equiatomic”) have proven to exhibit promising mechanical and corrosion resistance properties, that are sought after in materials intended for use in hazardous environments like next-generation nuclear reactors. In this article, we investigate the damage production and dislocation mobility by simulating irradiation of elemental Ni and the alloys NiCo, NiCoCr, NiCoFe and NiFe, to assess the effect of elemental composition. We compare the defect production and the evolution of dislocation networks in the simulation cells of two different sizes, for all five studied materials. We find that the trends in defect evolution are in good agreement between the different cell sizes. The damage is generally reduced with increased alloy complexity, and the dislocation evolution is specific to each material, depending on its complexity. We show that increasing complexity of the alloys does not always lead to decreased susceptibility to damage accumulation under irradiation. We show that, for instance, the NiCo alloy behaves very similarly to Ni, while presence of Fe or Cr in the alloy even as a third component reduces the saturated level of damage substantially. Moreover, we linked the defect evolution with the dislocation transformations in the alloys. Sudden drops in defect number and large defect fluctuations from the continuous irradiation can be explained from the dislocation activity.

  5. Corrosion Resistance Of Electroless Ni-P/Cu/Ni-P Multilayer Coatings

    Directory of Open Access Journals (Sweden)

    Zhao G.L.

    2015-06-01

    Full Text Available Ni-P/Cu/Ni-P multilayer coatings were prepared by deposition of Cu layer between two Ni–P layers. The Cu layer was deposited by metal displacement reaction between Cu2+ and Fe atoms. Corrosion behavior of single-layer Ni-P coatings, double-layer Ni-P/Cu coatings, and three-layer Ni-P/Cu/Ni-P coatings were investigated by electrochemical tests in 3.5% NaCl solution. The three-layer coatings exhibited more positive Ecorr and decreased Icorr compared with conventional single-layer Ni-P coatings, which indicated an improved corrosion resistance. The polarization curves of the three-layer coatings were characterized by two passive regions. The improved corrosion resistance was not only attributed to the function of the blocked pores of Cu. The Cu interlayer also acted as a sacrificial layer instead of a barrier in the coatings, which altered the corrosion mechanism and further improved the corrosion resistance of the coatings.

  6. PRECIPITATION HARDENING IN B2-ORDERED NiAl BY Ni2AlTiCOMPOUND

    Institute of Scientific and Technical Information of China (English)

    W.H. Tian; K. Ohishi; M. Nemoto

    2001-01-01

    Microstructural variations and correlated hardness changes in B2-ordered NiAl containing fine precipitation of Ni2AlTi have been investigated by means of transmission electron microscopy (TEM) and hardness tests. The amount of age hardening is not large as compared to the large microstructural variations during aging. TEM observations have revealed that the L21-type Ni2AlTi precipitates keep a lattice coherency with the NiAl matrix at the beginning of aging. By longer periods of aging Ni2AlTi precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. The temperature dependence of the yield strength of precipitate-containing B2-ordered NiAl was investigated by compression tests over the temperature range of 873-1273K. The fine precipitation of Ni2AlTi was found to enhance greatly the yield strength and the high-temperature strength is comparison with that of superalloy Mar-M200.``

  7. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae

    2016-01-01

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery

  8. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery.

  9. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    International Nuclear Information System (INIS)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace

    2017-01-01

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  10. Tipos especiales de niños

    Directory of Open Access Journals (Sweden)

    Mercedes Rodrigo Bellido

    1946-09-01

    Full Text Available En las tres últimas lecciones han sido expuestas algunas consideraciones referentes a niños y adolescentes desde el nacimiento hasta el dintel de la juventud. En todas ellas hemos procurado poner de relieve la necesidad de individualizar el conocimiento de cada niño para obtener mejores resultados en su adaptación a su futura vida de adultos, En todas ellas  nos hemos referido al llamado niño normal. Nos corresponde en la lección de hoy ocuparnos can la superficialidad característica de estas charlas tipo-muestrario, de otras categorías de niños muy dignos de interés.. quienes unas por exceso, otros por defecto, otros por dificultades de adaptación por diferentes causas, se desvían de la línea media de la normalidad. Consideramos que no está fuera del lugar, aquí, el tema de los niños excepcionales y por el contrario que es necesario intensificar el estudio de los trastornos de la vida mental y emocional de los niños en la preparación de los estudiantes de Medicina. Y no es nuestra solo esta opinión; no hace mucho tiempo en la Medical School de Ia Universidad de Minnessota hemos sabido que se ha hecho un intento de considerar y evaluar factores emocionales ambientales sobre las mismas bases que los descubrimientos fisiológicos.

  11. Ni Foam-Ni3 S2 @Ni(OH)2 -Graphene Sandwich Structure Electrode Materials: Facile Synthesis and High Supercapacitor Performance.

    Science.gov (United States)

    Wang, Xiaobing; Hu, Jiangjiang; Su, Yichang; Hao, Jin; Liu, Fanggang; Han, Shuang; An, Jian; Lian, Jianshe

    2017-03-23

    A novel Ni foam-Ni 3 S 2 @Ni(OH) 2 -graphene sandwich-structured electrode (NF-NN-G) with high areal mass loading (8.33 mg cm -2 ) has been developed by sulfidation and hydrolysis reactions. The conductivity of Ni 3 S 2 and Ni(OH) 2 were both improved. The upper layer of Ni(OH) 2 , covered with a thin graphene film, is formed in situ from the surface of the lower layer of Ni 3 S 2 , whereas the Ni 3 S 2 grown on Ni foam substrate mainly acts as a rough support bridging the Ni(OH) 2 and Ni foam. The graphene stabilized the Ni(OH) 2 and the electrochemical properties were effectively enhanced. The as-synthesized NF-NN-G-5mg electrode shows a high specific capacitance (2258 F g -1 at 1 A g -1 or 18.81 F cm -2 at 8.33 mA cm -2 ) and an outstanding rate property (1010 F g -1 at 20 Ag -1 or 8.413 F cm -2 at 166.6 mA cm -2 ). This result is around double the capacitance achieved in previous research on Ni 3 S 2 @Ni(OH) 2 /3DGN composites (3DGN=three-dimensional graphene network). In addition, the as-fabricated NF-NN-G-5mg composite electrode has an excellent cycle life with no capacitance loss after 3000 cycles, indicating a potential application as an efficient electrode. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Salud mental del niño

    OpenAIRE

    Ospina de González, Bernarda

    1987-01-01

    Es ya reconocida por todos las importancia de los primeros años de vida en la estructutración de la personalidad y, por consiguiente, en la salud mental del niño. En este artículo se hace una síntesis de los diferentes aspectos del desarrollo de la personalidad infanltil que seben ser conocidos por el personal de salud para estar en condiciones de brindar una atención integral a la madre y al niño. Con igual propósito se señalan algunos patrones de tipo psicosocial que influyen en la estabili...

  13. Magnetic anisotropy of Ni/Cr multilayers

    International Nuclear Information System (INIS)

    Kang, S.; Xia, H.

    1997-01-01

    The magnetic anisotropy of Ni/Cr multilayers has been investigated by using vibrating sample magnetometer (VSM) and ferromagnetic resonance techniques (FMR). The FMR spectra are obtained as a function of the orientation of the applied magnetic field from in-plane to out-of-plane. The results are fitted theoretically to determine the magnetic anisotropy. From VSM and FMR, a positive value for Ni/Cr interface anisotropy is obtained, which favours a perpendicular easy axis. The possible mechanism for the perpendicular anisotropy has been discussed and it may be attributed to the magnetostriction, caused by intrinsic stress due to lattice mismatch. (orig.). With 005 figs., 001 tabs

  14. Ionizing Radiation Effects in Ni Nanotubes

    Science.gov (United States)

    Shlimas, D.; Kozlovsky, A.; Shumskaya, A.; Kaniukov, E.; Ibragimova, M.; Zdorovets, M.; Kadyrzhanov, K.

    2017-01-01

    Polycrystalline nickel nanotubes with diameter of 380 nm and wall thickness 95 nm were synthesized by electrochemical method using PET track-etched membranes with thickness of 12 μm. A comprehensive study of the structural, morphological and electrical characteristics of Ni nanotubes irradiated with C+13 ions with energy 1.75 MeV/nucleon and fluence ranging from 109 to 5 × 1011 cm-2 was carried out. The ability of modification of structural parameters such as lattice parameter and the average size of crystallites and conductivity of Ni nanotubes by irradiation was shown.

  15. Optimization of process parameters for synthesis of silica–Ni ...

    Indian Academy of Sciences (India)

    Optimization of process parameters for synthesis of silica–Ni nanocomposite by design of experiment ... Sol–gel; Ni; design of experiments; nanocomposites. ... Kolkata 700 032, India; Rustech Products Pvt. Ltd., Kolkata 700 045, India ...

  16. Ni hollow spheres as catalysts for methanol and ethanol electrooxidation

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Changwei [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Hu, Yonghong; Rong, Jianhua; Liu, Yingliang [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); Jiang, San Ping [School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore)

    2007-08-15

    In this paper, we successfully synthesized Ni hollow spheres consisting of needle-like nickel particles by using silica spheres as template with gold nanoparticles seeding method. The Ni hollow spheres are applied to methanol and ethanol electrooxidation in alkaline media. The results show that the Ni hollow spheres give a very high activity for alcohol electrooxidation at a very low nickel loading of 0.10 mg cm{sup -2}. The current on Ni hollow spheres is much higher than that on Ni particles. The onset potential and peak potential on Ni hollow spheres are more negative than that on Ni particles for methanol and ethanol electrooxidation. The Ni hollow spheres may be of great potential in alcohol sensor and direct alcohol fuel cells. (author)

  17. Separation and preparation of "6"2Ni isotope

    International Nuclear Information System (INIS)

    Ren Xiuyan; Mi Yajing; Zeng Ziqiang; Li Gongliang; Tu Rui

    2014-01-01

    Micro nuclear battery is the perfect power of space craft equipment. "6"3Ni is the core operation material of the "6"3Ni battery. It can produce radioisotope "6"3Ni while high abundance "6"2Ni is irradiated in the reactor. In order to meet the requirements of the abundance and the purity, research of the separation for "6"2Ni isotope was developed. The magnetic field and beam transmission status were simulated. The improvement designs of the ion source and the collector pocket were carried out. The process flow of high abundance "6"2Ni using electromagnetic separation method was established. The experiment of "6"2Ni isotope was developed by using electromagnetism isotope separator. The results show that the enrichment of "6"2Ni isotope is more than 90%. (authors)

  18. X-ray fluorescence analysis of Fe - Ni - Mo systems

    International Nuclear Information System (INIS)

    Belyaev, E.E.; Ershov, A.V.; Mashin, A.I.; Mashin, N.I.; Rudnevskij, N.K.

    1998-01-01

    Procedures for the X-ray fluorescence determination of the composition and thickness of Fe - Ni - Mo thin films and the concentration of elements in thick films of the Fe - Ni - Mo alloy are developed [ru

  19. Structure characterization of Ni/NiO and Ti/TiO2 interfaces

    International Nuclear Information System (INIS)

    Lamine, Brahim

    1983-01-01

    This research thesis reports the structure characterization of Ni-NiO and Ti-TiO 2 interfaces through an in-situ investigation of thin blade oxidation, of oxide germination and growth, and through a determination of mutual metal/oxide orientation relationships. Thin films of TiO 2 have also been characterized and the study of the influence of vacuum annealing on TiO 2 layer structure and morphology has been attempted. The examination of metal-oxide interface reveals a duplex structure of NiO and TiO 2 layers, and a preferential grain boundary oxidation of the underlying metal [fr

  20. Structure of Ni-rich Ni--Cr--B--Si coating alloys

    International Nuclear Information System (INIS)

    Knotek, O.; Lugscheider, E.; Reimann, H.

    1975-01-01

    The structures of quaternary, nickel-rich Ni--Cr--B--Si alloys were analyzed at a constant boron content of 10 at. percent and a temperature of 850 0 C. The composition range for silicide formation was determined. In these quaternary alloys, known binary nickel silicides, nickel and chromium borides, and the ternary silico-boride Ni 6 Si 2 B were confirmed. A new composition for the W 5 Si 3 -type phase in the Ni--B--Si system was proposed. (U.S.)

  1. The study of quasi-projectiles produced in Ni+Ni and Ni+Au collisions: excitation energy and spin

    International Nuclear Information System (INIS)

    Buta, A.

    2003-02-01

    During the collision between the projectile and the target nuclei in the intermediate energy regime (E < 100 MeV/nucleon) two excited nuclei are mainly observed in the exit channel, the quasi projectile (QP) and the quasi target. They disintegrate by particle emission. However, this binary picture is perturbed by the emission of particles and light fragments with velocities intermediate between the projectile velocity and the target one, all along the interaction (midrapidity component). This work aim to determine the excitation energy and the intrinsic angular momentum (or spin) of quasi-projectiles produced in the Ni+Ni and Ni+Au collisions at 52 and 90 MeV/nucleon. The excitation energy is deduced from the kinematical characteristics of particles emitted by the quasi-projectile. They have to be separated from midrapidity particles. Three different scenarios have been used for this purpose. The spin of the quasi-projectile has been extracted from the experimental data by mean of proton and alpha particles multiplicities emitted by the QP in the Ni+Au at 52 MeV/nucleon reaction. The results have been compared to the predictions of a theoretical model based on nucleon transfers. Their evolution is qualitatively reproduced as a function of the violence of the collision. (author)

  2. Low temperature gaseous nitriding of Ni based superalloys

    DEFF Research Database (Denmark)

    Eliasen, K. M.; Christiansen, Thomas Lundin; Somers, Marcel A. J.

    2010-01-01

    In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr......In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr...

  3. Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window

    KAUST Repository

    Liu, E. K.; Zhang, H. G.; Xu, G. Z.; Zhang, X. M.; Ma, R. S.; Wang, W. H.; Chen, J. L.; Zhang, H. W.; Wu, G. H.; Feng, L.; Zhang, Xixiang

    2013-01-01

    An effective scheme of isostructural alloying was applied to establish a Curie-temperature window in isostructural MnNiGe-CoNiGe system. With the simultaneous accomplishment of decreasing structural-transition temperature and converting

  4. The large magnetoelectric effect in Ni-lead zirconium titanate-Ni trilayers derived by electroless deposition

    International Nuclear Information System (INIS)

    Bi, K; Wang, Y G; Wu, W; Pan, D A

    2010-01-01

    Magnetoelectric (ME) Ni-lead zirconium titanate-Ni trilayers with neither electrodes nor bonding layers have been derived by electroless deposition. The structure and magnetic properties of the electroless deposited Ni layers with different pH values are characterized by x-ray diffraction and vibrating sample magnetometer. The influence of the bias magnetic field and the magnetic field frequency (f) on ME coupling is discussed. It is seen that α E,31 depends strongly on H dc and f. The value of the ME coefficient increases as the thickness of the Ni layer and the pH of the bath increase. A maximum of the ME voltage coefficient α E,31 = 5.77 V cm -1 Oe -1 at resonance frequency with a deposited Ni layer thickness t Ni = 302 μm is obtained. The large ME coefficient makes these Ni-PZT-Ni trilayers suitable for applications in sensors, actuators and transducers. (fast track communication)

  5. Development of the dentistry alloy Ni-Cr-Nb; Desenvolvimento de ligas odontologicas Ni-Cr-Nb

    Energy Technology Data Exchange (ETDEWEB)

    Souza, M.A.; Ramos, A.S.; Hashimoto, T.M., E-mail: mari_sou@hotmail.co [UNESP/FEG, Guaratingueta, SP (Brazil). Fac. de Engenharia. Dept. de Materiais e Tecnologia

    2010-07-01

    This work reports on the structural characterization of Ni-Cr-Mo and Ni-Cr-Nb alloys produced by arc melting. Samples were characterized by means of optical microscopy, X-ray diffraction, scanning electron microscopy, and EDS analysis. Results indicated that the arc melting process was efficient to produce homogeneous structures in Ni-Cr-Mo and Ni-Cr-Nb alloys. The nickel dissolved large amounts of Cr, Mo and Nb, which was detected by EDS analysis and X-ray diffraction. The alloy containing molybdenum indicated the presence of structure based on Ni{sub SS}, while that the alloys containing niobium presented primary grains of Ni{sub SS} and precipitates formed by the simultaneous transformation of the Ni and Ni{sub 3}Nb phases. (author)

  6. Microstructure and electrochemical characterization of laser melt-deposited Ti2Ni3Si/NiTi intermetallic alloys

    International Nuclear Information System (INIS)

    Dong Lixin; Wang Huaming

    2008-01-01

    Corrosion and wear resistant Ti 2 Ni 3 Si/NiTi intermetallic alloys with Ti 2 Ni 3 Si as the reinforcing phase and the ductile NiTi as the toughening phase were designed and fabricated by the laser melt-deposition manufacturing process. Electrochemical behavior of the alloys was investigated using potentiodynamic polarization testing and electrochemical impedance spectroscopy in an NaOH solution. The results showed that the alloys have outstanding corrosion resistance due to the formation of a protective passive surface film of Ni(OH) 2 as well as the high chemical stability and strong inter-atomic bonds inherent to Ti 2 Ni 3 Si and NiTi intermetallics. The Ti 2 Ni 3 Si content has a significant influence on the microstructure of the alloys but only a slight effect on electrochemical corrosion properties

  7. Homotopic mapping solution of an oscillator for the El Niño/La Niña-southern oscillation

    International Nuclear Information System (INIS)

    Xian-Chun, Zhou; Yi-Hua, Lin; Wan-Tao, Lin; Jia-Qi, Mo

    2009-01-01

    This paper considers a class of oscillator for the El Niño/La Niña-southern oscillation (ENSO) model. By using the homotopic mapping method, it obtains approximations of the solution for the ENSO model. (general)

  8. Electrochemical reduction of NiO in a composite electrode

    DEFF Research Database (Denmark)

    Hu, Qiang; Jacobsen, Torben; Hansen, Karin Vels

    2013-01-01

    a lower overpotential. Microstructures of NiO with different reduction degrees are shown. Electrochemical impedance spectroscopy is carried out during the reduction process. Electrochemical reduction of NiO may need an induction period. When NiO is reduced at a constant voltage the current initially...

  9. Morphological and compositional engineering of Ni/carbon ...

    Indian Academy of Sciences (India)

    Ni/multi-walled carbon nanotubes (MWCNTs) composite films were deposited on the glassy carbon electrode (GCE) by a Ni plating bath containing homogeneously dispersed MWCNTs using polyvinylpyrrolidone (PVP) as dispersion additive. Incorporation of MWCNTs into Ni matrix was greatly enhanced by the application ...

  10. CLASSICAL AREAS OF PHENOMENOLOGY: First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    Science.gov (United States)

    Wang, Yun-Jiang; Wang, Chong-Yu

    2009-10-01

    A model system consisting of Ni[001](100)/Ni3Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni3Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni3Al multilayer can be well predicted by the Voigt-Reuss-Hill rule of mixtures.

  11. Low-field spin dynamics of Cr7Ni and Cr7Ni-Cu -Cr 7Ni molecular rings as detected by μ SR

    Science.gov (United States)

    Sanna, S.; Arosio, P.; Bordonali, L.; Adelnia, F.; Mariani, M.; Garlatti, E.; Baines, C.; Amato, A.; Sabareesh, K. P. V.; Timco, G.; Winpenny, R. E. P.; Blundell, S. J.; Lascialfari, A.

    2017-11-01

    Muon spin rotation measurements were used to investigate the spin dynamics of heterometallic Cr7Ni and Cr7Ni -Cu-Cr7Ni molecular clusters. In Cr7Ni the magnetic ions are arranged in a quasiplanar ring and interact via an antiferromagnetic exchange coupling constant J , while Cr7Ni -Cu-Cr7Ni is composed of two Cr7Ni linked by a bridging moiety containing one Cu ion, that induces an inter-ring ferromagnetic interaction J'≪J . The longitudinal muon relaxation rate λ collected at low magnetic fields μ0H BPP)-like heuristic fitting model that takes into account of a distribution of electronic spin characteristic times for T >5 K, while the shoulder presented by Cr7Ni can be reproduced by a BPP function that incorporates a single electronic characteristic time theoretically predicted to dominate for T <5 K. The flattening of λ (T ) in Cr7Ni -Cu-Cr7Ni occurring at very low temperature can be tentatively attributed to field-dependent quantum effects and/or to an inelastic term in the spectral density of the electronic spin fluctuations.

  12. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al nanoparticles as a high microwave absorption material

    International Nuclear Information System (INIS)

    Pang, Yu; Xie, Xiubo; Li, Da; Chou, Wusheng; Liu, Tong

    2017-01-01

    The Al_3Ni_2@Al nanoparticles (NPs) were prepared from Ni_4_5Al_5_5 master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m"2/g and big pore volume of 0.507 cc/g. The saturation magnetization (M_S) and coercivity (H_C) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m"2/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  13. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al nanoparticles as a high microwave absorption material

    Energy Technology Data Exchange (ETDEWEB)

    Pang, Yu; Xie, Xiubo; Li, Da [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China); Chou, Wusheng [School of Mechanical Engineering and Automation, Beihang University, Beijing 100191 (China); Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China)

    2017-03-15

    The Al{sub 3}Ni{sub 2}@Al nanoparticles (NPs) were prepared from Ni{sub 45}Al{sub 55} master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m{sup 2}/g and big pore volume of 0.507 cc/g. The saturation magnetization (M{sub S}) and coercivity (H{sub C}) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m{sup 2}/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  14. Tracer diffusion of 60Co and 63Ni in amorphous NiZr alloy

    International Nuclear Information System (INIS)

    Hoshino, K.; Averback, R.S.; Hahn, H.; Rothman, S.J.

    1987-01-01

    Tracer diffusion of 60 Co and 63 Ni in equiatomic amorphous NiZr alloy in the temperature range between 486 and 641 0 K can be described by: D/sub Co/sup */ = 3.7 x 10 -7 exp[-(135 +- 14) kJ mole -1 /RT] m 2 /sec and D/sub Ni//sup */ = 1.7 x 10 -7 exp[-(140 +- 9) kJ mole -1 /RT] m 2 /sec. The values of D/sub Ni//sup */ are in reasonable agreement with those measured by the Rutherford backscattering technique. The measured diffusivities were independent of time, indicating that no relaxation took place during diffusion. 27 refs., 2 tabs

  15. Precipitation-induced of partial annealing of Ni-rich NiTi shape memory alloy

    Science.gov (United States)

    Nashrudin, Muhammad Naqib; Mahmud, Abdus Samad; Mohamad, Hishamiakim

    2018-05-01

    NiTi shape memory alloy behavior is very sensitive to alloy composition and heat treatment processes. Thermomechanical behavior of near-equiatomic alloy is normally enhanced by partial anneal of a cold-worked specimen. The shape memory behavior of Ni-rich alloy can be enhanced by ageing precipitation. This work studied the effect of simultaneous partial annealing and ageing precipitation of a Ni-rich cold drawn Ti-50.9at%Ni wire towards martensite phase transformation behavior. Ageing treatment of a non-cold worked specimen was also done for comparison. It was found that the increase of heat treatment temperature caused the forward transformation stress to decrease for the cold worked and non-cold worked specimens. Strain recovery on the reverse transformation of the cold worked wire improved compared to the non-cold worked wire as the temperature increased.

  16. Corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys

    International Nuclear Information System (INIS)

    Sriraman, K.R.; Ganesh Sundara Raman, S.; Seshadri, S.K.

    2007-01-01

    The present work deals with evaluation of corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys. Corrosion behaviour of the coatings deposited on steel substrates was studied using polarization and electrochemical impedance spectroscopy techniques in 3.5% NaCl solution while their passivation behaviour was studied in 1N sulphuric acid solution. The corrosion resistance of Ni-W alloys increased with tungsten content up to 7.54 at.% and then decreased. In case of Ni-Fe-W alloys it increased with tungsten content up to 9.20 at.% and then decreased. The ternary alloy coatings exhibited poor corrosion resistance compared to binary alloy coatings due to preferential dissolution of iron from the matrix. Regardless of composition all the alloys exhibited passivation behaviour over a wide range of potentials due to the formation of tungsten rich film on the surface

  17. Evolution of collectivity in the 78Ni region: Coulomb excitation of 74Ni at intermediate energies.

    Directory of Open Access Journals (Sweden)

    Marchi T.

    2014-03-01

    Full Text Available The study of the collective properties of nuclear excitations far from stability provides information about the shell structure at extreme conditions. Spectroscopic observables such as the energy or the transition probabilities of the lowest states, in nuclei with large neutron excess, allow to probe the density and isospin dependence of the effective interaction. Indeed, it was recently shown that tensor and three-body forces play an important role in breaking and creating magic numbers. Emblematic is the case of the evolution of the Ni isotopic chain where several features showed up moving from the most neutron rich stable isotope (64Ni towards the 78Ni nucleus where the large neutron excess coincides with a double shell closure. In this framework, we have recently performed an experiment with the goal to extract the B(E2; 0+ → 2+ value for the 74Ni nucleus in an intermediate-energy Coulomb excitation experiment: preliminary results are discussed.

  18. Rate of hydrogen motion in Ni-substituted LaNi5Hx from NMR

    International Nuclear Information System (INIS)

    Mendenhall, Michael P.; Bowman, Robert C.; Ivancic, Timothy M.; Conradi, Mark S.

    2007-01-01

    Partial substitution of Sn, Ge, or Si for Ni in LaNi 5 H x greatly enhances the stability under repeated hydrogen-cycling. Proton NMR relaxation measurements are reported here to determine the rates of H hopping in the substituted metals LaNi 4.6 M 0.4 H x with M = Sn, Ge, and Si, for comparison to bare LaNi 5 H x . The relaxation times T 2 * (FID), T 2 (Hahn echo), T 2 -CPMG, T 1 , and T 1ρ were determined from 130 to 375 K. The three substituents result in only small increases in the average rate of motion at a given temperature but with a broader distribution of rates over the many inequivalent H sites and hopping paths. Evidently, the average energy barriers along the paths for H motion are only little affected by these substituents. Changes of H content x produce only minor changes in the relaxation times

  19. Moessbauer effect measurements on the intermetallic compounds Ni3Al and Ni3Ge

    International Nuclear Information System (INIS)

    Drijver, J.W.; Woude, F. van der

    1975-01-01

    Moessbauer parameters obtained from room temperature emission and absorption spectra of Ni 3 Al and Ni 3 Ga processed by a computer assuming a singlet and a doublet are given. The doublet is due to iron or cobalt atoms at the nickel site. Quadrupole splitting at 57 Fe nuclei in Ni 3 Ga is larger than in Ni 3 Al, viz. 0.52 and 0.37 mm/sec, respectively. Isomer shift at the Al/Ga position is very close to -0.02 mm/sec found in metallic nickel. Also given are the hyperfine magnetic fields at 4.2 K. Considering the preference of 57 Co and 57 Fe atoms in the lattice, the field intensities at the nickel and aluminium sites are found to be 227 +- 1 and 238 +- 1 kOe, respectively. (Z.S.)

  20. Low energy structure of even-even Ni isotopes close to 78Ni

    International Nuclear Information System (INIS)

    Rykaczewski, Krzysztof Piotr; Mazzocchi, C.; Grzywacz, Robert Kazimierz; Batchelder, J.C.; Bingham, Carrol R.; Fong, D.; Hamilton, J.H.; Hwang, J.K.; Karny, M.; Krolas, W.; Liddick, S.N.; Lisetskiy, A. F.; Morton, N.H.; Mantica, P.F.; Mueller, W.F.; Steiner, M.; Stolz, A.; Winger, J.A.

    2005-01-01

    The structure of magic neutron-rich nickel isotopes produced in the fragmentation of a 140 A MeV 86 Kr beam was investigated. For the first time four gamma transitions were assigned to the decay of the I π =8 + , T 1/2 = 590 +180 -110 isomer, thus establishing the 0 + -2 + -4 + -6 + -8 + ground-state band in 76 Ni. The previously unknown 2 + and 4 + levels belonging to the ground-state band in 74 Ni were identified in the β decay of 74 Co (T 1/2 =30(3) ms). The decay properties of 72 Co → 72 Ni were verified and confirmed on the basis of γ-γ coincidence data. The relevance of the measured level properties for the magicity of 78 Ni is analyzed with the help of advanced shell-model predictions

  1. The process of Ni-63 production and measurement of beta radiation of irradiated Ni-63

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Uhma, Young Rang; Kim, Jong Bum; Choi, Sang Mu; Son, Kwang Jae; Hong, Jin Tae; Park, Jong Han

    2016-01-01

    It has the following characteristics: long service lifetime, high energy density, easy small-scale fabrication, and minimum maintenance. For this reasons, betavoltaic batteries are widely used in many low-power applications such as medical applications and power sources for micro electro-mechanical system (MEMS) because they can operate effectively at extreme environments. Proper selection of radioisotope is a critical factor in the design of a betavoltaic battery. The important factors affecting the performance of a betavoltaic battery are specific activity, half-life, and toxicity. In this study, a target for irradiation was produced using 99% Ni-62 metal power concentrate. Ni-62 target of 1 g was irradiated in MARIA reactor operated in Poland for 470 hours, and estimated production of Ni- 63 was calculated. Irradiated Ni-63 pellets were dissolved in HCl solution, and its beta radiation was measured by Liquid Scintillation Counter (LSC).

  2. Synthetic Ni3S2/Ni hybrid architectures as potential contrast agents in MRI

    International Nuclear Information System (INIS)

    Ma, J; Chen, K

    2016-01-01

    Traditional magnetic resonance imaging (MRI) contrast agents mainly include superparamagnetic (SPM) iron oxide nanoparticle as T 2 contrast agent for liver and paramagnetic Gd (III)-chelate as T 1 contrast agent for all organs. In this work, weak ferromagnetic kale-like and SPM cabbage-like Ni 3 S 2 @Ni hybrid architectures were synthesized and evaluated as potential T 1 MRI contrast agents. Their relatively small r 2 /r 1 ratios of 2.59 and 2.38, and high r 1 values of 11.27 and 4.89 mmol −1 L s −1 (for the kale-like and cabbage-like Ni 3 S 2 @Ni, respectively) will shed some light on the development of new-type MRI contrast agents. (paper)

  3. Hierarchical NiCo2 O4 nanosheets grown on Ni nanofoam as high-performance electrodes for supercapacitors.

    Science.gov (United States)

    Gao, Guoxin; Wu, Hao Bin; Ding, Shujiang; Liu, Li-Min; Lou, Xiong Wen David

    2015-02-18

    A high-performance electrode for supercapacitors is designed and synthesized by growing electroactive NiCo2 O4 nanosheets on conductive Ni nanofoam. Because of the structural advantages, the as-prepared Ni@NiCo2 O4 hybrid nanostructure exhibits significantly improved electrochemical performance with high capacitance, excellent rate capability, and good cycling stability. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Ni(II) complexes of dithiophosphonic acids

    Indian Academy of Sciences (India)

    aDepartment of Chemistry, Science and Research Branch, Islamic Azad ... The compounds were characterized by 1H, 13C and 31P NMR, IR spectroscopy and elemental analysis. The ... design and synthesize Ni(II) complexes with new ..... Yield: 86%. ..... 28 65. 18. Greenwood D 1989 Antimicrobial chemotherapy (New.

  5. Ni MINERALIZATION AND PGE CHARACTERIZATION IN THE ...

    African Journals Online (AJOL)

    Mgina

    fractionation, (2) the IPGEs are often associated with chromites as alloys or sulfides in ... Key words: Tanzania, Kabanga, Luhuma, PGE, Ni-Cu sulfides .... massive sulfide based on size of ore zone ... to ≤ 0.1 wt% and Fe2O3T = 80- ≈ 87 wt%.

  6. Modelling of rechargeable NiMH batteries

    NARCIS (Netherlands)

    Ledovskikh, A.; Verbitskiy, E.; Ayeb, A.; Notten, P.H.L.

    2003-01-01

    A new mathematical model has been developed for rechargeable NiMH batteries, which is based on the occurring physical–chemical processes inside. This model enables one to simultaneously simulate the battery voltage, internal gas pressures (both PO2 and PH2) and temperature during battery operation.

  7. Characterisation of a Zn / Ni Plating Bath

    Science.gov (United States)

    2009-09-03

    accelerated corrosion in the first stages which is then slowed down by its own product of corrosion, Zn(OH)212. Zinc hydroxide dehydrates in time to form ZnO ... Electrochemistry , 1991, 21, 642 [5] – Alfantasi, A.M., A study on the synthesis, characterization ans properties of pulse-plated ultrafine- grained Zn-Ni alloy

  8. Evidence for an isomer in 76Ni

    International Nuclear Information System (INIS)

    Sawicka, M.; Pfuetzner, M.; Grzywacz, R.; Daugas, J.M.; Belier, G.; Sauvestre, J.E.; Matea, I.; Lewitowicz, M.; Georgiev, G.; Grawe, H.; Mayet, P.; Becker, F.; Bingham, C.; Borcea, R.; Hammache, F.; Ibrahim, F.; Bouchez, E.; Buta, A.; Dragulescu, E.; Giovinazzo, J.; Meot, V.; Negoita, F.; De Oliveira Santos, F.; Perru, O.; Roig, O.; Rykaczewski, K.P.; Saint-Laurent, M.G.; Sorlin, O.; Stanoiu, M.; Stefan, I.; Stodel, C.; Theisen, C.; Verney, D.

    2004-01-01

    In the experiment performed at the LISE2000 spectrometer at GANIL neutron-rich nickel isotopes were studied by microsecond isomer spectroscopy. Evidence for an isomer in 76 Ni is found, consistently with the shell model prediction of an 8 + state of ν(g 9/2 ) 2 structure. (orig.)

  9. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    Energy Technology Data Exchange (ETDEWEB)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju [KAERI, Daejeon (Korea, Republic of)

    2012-10-15

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  10. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    International Nuclear Information System (INIS)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju

    2012-01-01

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  11. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    International Nuclear Information System (INIS)

    Liu, Tong; Pang, Yu; Xie, Xiubo; Qi, Wen; Wu, Ying; Kobayashi, Satoru; Zheng, Jie; Li, Xingguo

    2016-01-01

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m"2/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m"2/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  12. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Pang, Yu; Xie, Xiubo [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Qi, Wen; Wu, Ying [China Iron & Steel Research Institute Group, Advanced Technology & Materials Co., Ltd, No.76 Xueyuannanlu, Haidian District, Beijing, 100081 (China); Kobayashi, Satoru [Faculty of Engineering, Iwate University, Ueda, Morioka, 020-8551 (Japan); Zheng, Jie; Li, Xingguo [Beijing National Laboratory for Molecular Sciences (BNLMS), The State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 (China)

    2016-05-15

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m{sup 2}/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m{sup 2}/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  13. Geometric structures of thin film: Pt on Pd(110) and NiO on Ni(100)

    Energy Technology Data Exchange (ETDEWEB)

    Warren, Oden L. [Iowa State Univ., Ames, IA (United States)

    1993-07-01

    This thesis is divided into 3 papers: dynamical low-energy electron- diffraction investigation of lateral displacements in topmost layer of Pd(110); determination of (1x1) and (1x2) structures of Pt thin films on Pd(110) by dynamical low-energy electron-diffraction analysis; and structural determination of a NiO(111) film on Ni(100) by dynamical low-energy electron-diffraction analysis.

  14. Fabrication and tensile properties of rapidly solidified Cu-10wt. %Ni alloy. [Cu-10Ni

    Energy Technology Data Exchange (ETDEWEB)

    Baril, D; Angers, R; Baril, J [Dept. of Mining and Metallurgy, Laval Univ., Ste-Foy, Quebec (Canada)

    1992-10-15

    Cu-10wt.%Ni ribbons were produced by melt spinning and cut into small particles with a blade cutter mill. The powders were then hot consolidated to full density by hot pressing followed by hot extrusion. Tensile properties of the resulting pieces were measured. Cu-10wt.%Ni cast ingots were also hot extruded and mechanically tested to compare with the rapidly solidified alloy and to evaluate the possible benefits brought by the rapid solidification process.

  15. 59Ni and 63Ni separation from boric acid concentrates produced at NPP

    International Nuclear Information System (INIS)

    Fisera, O.

    2010-01-01

    Procedure for direct separation of radionickel from boric acid concentrate was developed. Quantitative separation from 100 mL of real concentrate on the column filled with 3 mL of PAN-DMG composite material was achieved. PAN-DMG material (dimethylglyoxime in porous beads of polyacrylonitrile) was compared with Ni Resin and DMG-PAN material exhibited higher sorption capacity for nickel than Ni Resin. (author)

  16. Valence electronic structure of Ni in Ni Si alloys from relative K X-ray intensity studies

    Science.gov (United States)

    Kalayci, Y.; Aydinuraz, A.; Tugluoglu, B.; Mutlu, R. H.

    2007-02-01

    The Kβ-to-Kα X-ray intensity ratio of Ni in Ni 3Si, Ni 2Si and NiSi has been determined by energy dispersive X-ray fluorescence technique. It is found that the intensity ratio of Ni decreases from pure Ni to Ni 2Si and then increases from Ni 2Si to NiSi, in good agreement with the electronic structure calculations cited in the literature. We have also performed band structure calculations for pure Ni in various atomic configurations by means of linear muffin-tin orbital method and used this data with the normalized theoretical intensity ratios cited in the literature to estimate the 3d-occupation numbers of Ni in Ni-Si alloys. It is emphasized that investigation of alloying effect in terms of X-ray intensity ratios should be carried out for the stoichiometric alloys in order to make reliable and quantitative comparisons between theory and experiment in transition metal alloys.

  17. La Niña, El Niño, and Atlantic Hurricane Damages in the United States

    Science.gov (United States)

    data discussed below), this definition results in 22 El Niño years, 29 neutral years, and 22 La Niña accounting for the most significant societal changes. To normalize past impacts data to 1997 values, losses , 169 and 186. Trenberth, K. E., 1997: The definition of El Niño. Bull. Amer. Meteor. Soc., 78, 2771

  18. Observations of defect structure evolution in proton and Ni ion irradiated Ni-Cr binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Briggs, Samuel A., E-mail: sabriggs2@wisc.edu [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Barr, Christopher M. [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Pakarinen, Janne [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); SKC-CEN Belgian Nuclear Research Centre, Boeretang 200, B-2400 Mol (Belgium); Mamivand, Mahmood [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Hattar, Khalid [Sandia National Laboratories, PO Box 5800, Albuquerque, NM 87185 (United States); Morgan, Dane D. [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Taheri, Mitra [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Sridharan, Kumar [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States)

    2016-10-15

    Two binary Ni-Cr model alloys with 5 wt% Cr and 18 wt% Cr were irradiated using 2 MeV protons at 400 and 500 °C and 20 MeV Ni{sup 4+} ions at 500 °C to investigate microstructural evolution as a function of composition, irradiation temperature, and irradiating ion species. Transmission electron microscopy (TEM) was applied to study irradiation-induced void and faulted Frank loops microstructures. Irradiations at 500 °C were shown to generate decreased densities of larger defects, likely due to increased barriers to defect nucleation as compared to 400 °C irradiations. Heavy ion irradiation resulted in a larger density of smaller voids when compared to proton irradiations, indicating in-cascade clustering of point defects. Cluster dynamics simulations were in good agreement with the experimental findings, suggesting that increases in Cr content lead to an increase in interstitial binding energy, leading to higher densities of smaller dislocation loops in the Ni-18Cr alloy as compared to the Ni-5Cr alloy. - Highlights: • Binary Ni-Cr alloys were irradiated with protons or Ni ions at 400 and 500 °C. • Higher irradiation temperatures yield increased size, decreased density of defects. • Hypothesize that varying Cr content affects interstitial binding energy. • Fitting CD models for loop nucleation to data supports this hypothesis.

  19. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    Energy Technology Data Exchange (ETDEWEB)

    Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: a_layadi@yahoo.fr; Ben Youssef, J. [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Roussigne, Y. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France)

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K {sub 1} and K {sub 2}, have been included; for the Ni/Cu series, K {sub 1} was found to decrease from 1.0x10{sup 6} to 0.18x10{sup 6} erg/cm{sup 3} as t increases from 31 to 165 nm, while K {sub 2} increased from 0.24x10{sup 6} to 0.8x10{sup 6} erg/cm{sup 3}. Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t{>=}165 nm in Ni/glass and t{>=}90 nm in Ni/Cu.

  20. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    International Nuclear Information System (INIS)

    Cherif, S.-M.; Layadi, A.; Ben Youssef, J.; Nacereddine, C.; Roussigne, Y.

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K 1 and K 2 , have been included; for the Ni/Cu series, K 1 was found to decrease from 1.0x10 6 to 0.18x10 6 erg/cm 3 as t increases from 31 to 165 nm, while K 2 increased from 0.24x10 6 to 0.8x10 6 erg/cm 3 . Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t≥165 nm in Ni/glass and t≥90 nm in Ni/Cu

  1. Effect of Ni4Ti3 precipitation on martensitic transformation in Ti-Ni

    International Nuclear Information System (INIS)

    Zhou, N.; Shen, C.; Wagner, M.F.-X.; Eggeler, G.; Mills, M.J.; Wang, Y.

    2010-01-01

    Precipitation of Ni 4 Ti 3 plays a critical role in determining the martensitic transformation path and temperature in Ni-Ti shape memory alloys. In this study, the equilibrium shape of a coherent Ni 4 Ti 3 precipitate and the concentration and stress fields around it are determined quantitatively using the phase field method. Most recent experimental data on lattice parameters, elastic constants, precipitate-matrix orientation relationship and thermodynamic database are used as model inputs. The effects of the concentration and stress fields on subsequent martensitic transformations are analyzed through interaction energy between a nucleating martensitic particle and the existing microstructure. Results indicate that R-phase formation prior to B19' phase could be attributed to both direct elastic interaction and stress-induced spatial variation in concentration near Ni 4 Ti 3 precipitates. The preferred nucleation sites for the R-phase are close to the broad side of the lenticular-shaped Ni 4 Ti 3 precipitates, where tension normal to the habit plane is highest, and Ni concentration is lowest.

  2. Fabrication of metallic alloy powder (Ni{sub 3}Fe) from Fe–77Ni scrap

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Inseok [ES Materials Research Center, Research Institute of Industrial Science and Technology, Incheon 406-840 (Korea, Republic of); Shin, Shun-Myung [Extractive Metallurgy Department, Korea Institute of Geoscience and Mineral Resources, Deajeon 305-350 (Korea, Republic of); Ha, Sang-An [Department of Environmental Engineering, Silla University, Busan 46958 (Korea, Republic of); Wang, Jei-Pil, E-mail: jpwang@pknu.ac.kr [Department of Metallurgical Engineering, Pukyong National University, Busan 608-739 (Korea, Republic of)

    2016-06-15

    The oxidation behavior of Fe–77Ni alloy scrap was investigated at an oxygen partial pressure of 0.2 atm and temperatures ranging from 400 °C to 900 °C. The corresponding oxidation rate increased with increasing temperature and obeyed the parabolic rate law, as evidenced by its linear proportionality to the temperature. In addition, surface morphologies, cross-sectional views, compositions, structural properties were examined by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Diffusion through either the spinel structure or the NiO layer, which were both present in the alloy during oxidation at elevated temperatures, was deemed the rate-limiting step of the reaction. The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap was obtained using ball-milling and sieving processes. In fact, 15 h of milling yielded a recovery ratio of 97%. Using hydrogen gas, the oxide powder was successfully reduced to an alloy powder of Ni{sub 3}Fe and reduction rates of ∼97% were achieved after 3 h at 1000 °C. - Highlights: • The oxidation behavior of Fe–77Ni alloy scrap was investigated. • The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap. • Using hydrogen gas, the oxide powder was successfully reclaimed. • Reduction rates of ∼97% were achieved after 3 h at 1000 °C.

  3. Positron annihilation studies in CeNiIn and LaNiIn

    International Nuclear Information System (INIS)

    Ray, R.; Giri, S.; Sen, M.; Nambissan, P.M.G.; Ghoshray, K.; Ghoshray, A.; Sen, P.

    1997-01-01

    Doppler broadened positron annihilation spectral lineshape (DBPAS) and positron lifetime measurements in the temperature range 18-280 K have been performed in CeNiIn and LaNiIn systems. The nature of the temperature variations of the lifetime in both systems is almost similar in the whole temperature range studied, whereas the nature of the temperature variation of the S parameter in CeNiIn is similar to that in LaNiIn except in the temperature region 18-40 K. For the former system there is a dip around 20 K in the S parameter versus temperature curve. The lifetime versus T curve in both systems could be explained by the thermal expansion of the lattice. The S parameter versus T curve in LaNiIn could also be attributed to the thermal expansion of the lattice, whereas in CeNiIn the above mentioned dip seems an extra feature of the thermal expansion of the lattice. To understand this low temperature behaviour other results on the same system have been discussed. (orig.)

  4. Interfacial reaction of Ni{sub 3}Sn{sub 4} intermetallic compound in Ni/SnAg solder/Ni system under thermomigration

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yi-Shan; Yang, Chia-Jung; Ouyang, Fan-Yi, E-mail: fyouyang@ess.nthu.edu.tw

    2016-07-25

    The growth of Ni{sub 3}Sn{sub 4} intermetallic compound (IMC) between liquid–solid interface in micro-scale Ni/SnAg/Ni system was investigated under a temperature gradient of 160 °C/cm at 260 °C on a hot plate. In contrast to a symmetrical growth of Ni{sub 3}Sn{sub 4} on both interfaces under isothermally annealed at 260 °C, the interfacial Ni{sub 3}Sn{sub 4} IMC exhibited asymmetric growth under a temperature gradient; the growth of Ni{sub 3}Sn{sub 4} at cold interface was faster than that at hot side because of temperature gradient induced mass migration of Ni atoms from the hot end toward the cold end. It was found that two-stage growth behavior of Ni{sub 3}Sn{sub 4} IMC under a temperature gradient. A growth model was established and growth kinetic analysis suggested that the chemical potential gradient controlled the growth of Ni{sub 3}Sn{sub 4} at stage I (0–120 min) whereas the dynamic equilibrium between chemical potential gradient and temperature gradient forces was attained at the hot end at stage II (120–210 min). When dynamic equilibrium was achieved at 260 °C, the critical length-temperature gradient product at the hot end was experimentally estimated to be 489.18 μm × °C/cm and the moving velocity of Ni{sub 3}Sn{sub 4} interface due to Ni consumption was calculated to be 0.134 μm/h. The molar heat of transport (Q*) of Ni atoms in molten SnAg solder was calculated to be +0.76 kJ/mol. - Highlights: • Interfacial reaction in Ni/SnAg solder/Ni system under thermal gradient. • Growth rate of Ni{sub 3}Sn{sub 4} at cold end is faster than that at hot end. • Critical length-temperature gradient product at hot end is 489.2 μm°C/cm at 260 °C. • Velocity of Ni{sub 3}Sn{sub 4} moving interface is 0.134 μm/h during dynamic equilibrium. • Molar heat of transport (Q*) of Ni in molten SnAg was +0.76 kJ/mol.

  5. Evaluation of the Antitumor Activity by Ni Nanoparticles with Verbascoside

    Directory of Open Access Journals (Sweden)

    Mingyue Chen

    2013-01-01

    Full Text Available Verbascoside (VB has attracted a great deal of attention due to ITS pharmacological properties. In our study, we synthesized a multifunctional verbascoside coated Ni nanoparticles (VB-Ni. Transmission electron microscopy (TEM and high performance liquid chromatography (HPLC display the characteristics of VB-Ni nanoparticles. Compared with VB, VB-Ni has been proven to induce apoptosis and resist the growth of doxorubicin-resistant K562 cells in vitro and in vivo. Thus, VB-Ni nanoparticles can be thought of as an ideal mode of cancer treatment.

  6. A Study on Production of Carbon Nanotubes by CH4 Decomposition over LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Carbon nanotubes (CNTs) of narrow size distribution can be abundantly produced in the catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4.The CNTs obtained were characterized by means of transmission electron microscopy (TEM).Thermal oxidation of CNTs in air was monitored thermogravimetrically (TG). The resultsrevealed that a lower La/Ni ratio of the catalysts would lead to a wider diameter distribution and a higher degree of graphitic nature.

  7. Thin NiTi Films Deposited on Graphene Substrates

    Science.gov (United States)

    Hahn, S.; Schulze, A.; Böhme, M.; Hahn, T.; Wagner, M. F.-X.

    2017-03-01

    We present experimental results on the deposition of Nickel Titanium (NiTi) films on graphene substrates using a PVD magnetron sputter process. Characterization of the 2-4 micron thick NiTi films by electron microscopy, electron backscatter diffraction, and transmission electron microscopy shows that grain size and orientation of the thin NiTi films strongly depend on the type of combination of graphene and copper layers below. Our experimental findings are supported by density functional theory calculations: a theoretical estimation of the binding energies of different NiTi-graphene interfaces is in line with the experimentally determined microstructural features of the functional NiTi top layer.

  8. Properties of mechanically alloyed Mg-Ni-Ti ternary hydrogen storage alloys for Ni-MH batteries

    Science.gov (United States)

    Ruggeri, Stéphane; Roué, Lionel; Huot, Jacques; Schulz, Robert; Aymard, Luc; Tarascon, Jean-Marie

    MgNiTi x, Mg 1- xTi xNi and MgNi 1- xTi x (with x varying from 0 to 0.5) alloys have been prepared by high energy ball milling and tested as hydrogen storage electrodes. The initial discharge capacities of the Mg-Ni-Ti ternary alloys are inferior to the MgNi electrode capacity. However, an exception is observed with MgNi 0.95Ti 0.05, which has an initial discharge capacity of 575 mAh/g compared to 522 mAh/g for the MgNi electrode. The Mg-Ni-Ti ternary alloys show improved cycle life compared to Mg-Ni binary alloys with the same Mg/Ni atomic ratio. The best cycle life is observed with Mg 0.5Ti 0.5Ni electrode which retains 75% of initial capacity after 10 cycles in comparison to 39% for MgNi electrodes, in addition to improved high-rate dischargeability (HRD). According to the XPS analysis, the cycle life improvement of the Mg 0.5Ti 0.5Ni electrode can be related to the formation of TiO 2 which limits Mg(OH) 2 formation. The anodic polarization curve of Mg 0.5Ti 0.5Ni electrode shows that the current related to the active/passive transition is much less important and that the passive region is more extended than for the MgNi electrode but the corrosion of the electrode is still significant. This suggests that the cycle life improvement would be also associated with a decrease of the particle pulverization upon cycling.

  9. Densities of molten Ni-(Cr, Co, W) superalloys

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; YANG Ren-hui; FANG Liang; LIU Lan-xiao; ZHAO Hong-kai

    2008-01-01

    In order to obtain more accurate density for molten Ni-(Cr, Co, W) binary alloy, the densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys were measured with a sessile drop method. It is found that the measured densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys decrease with increasing temperature in the experimental temperature range. The density of alloys increases with increasing W and Co concentrations while it decreases with increasing Cr concentration in the alloy at 1 773-1 873 K. The molar volume of Ni-based alloys increases with increasing W concentration while it decreases with increasing Co concentration. The effect of Cr concentration on the molar volume of the alloy is little in the studied concentration range. The accommodation among atomic species was analyzed. The deviation of molar volume from ideal mixing shows an ideal mixing of Ni-(Cr, Co, W) binary alloys.

  10. Spectroscopic investigation of Ni speciation in hardened cement paste.

    Science.gov (United States)

    Vespa, M; Dähn, R; Grolimund, D; Wieland, E; Scheidegger, A M

    2006-04-01

    Cement-based materials play an important role in multi-barrier concepts developed worldwide for the safe disposal of hazardous and radioactive wastes. Cement is used to condition and stabilize the waste materials and to construct the engineered barrier systems (container, backfill, and liner materials) of repositories for radioactive waste. In this study, Ni uptake by hardened cement paste has been investigated with the aim of improving our understanding of the immobilization process of heavy metals in cement on the molecular level. X-ray absorption spectroscopy (XAS) coupled with diffuse reflectance spectroscopy (DRS) techniques were used to determine the local environment of Ni in cement systems. The Ni-doped samples were prepared at two different water/cement ratios (0.4, 1.3) and different hydration times (1 hour to 1 year) using a sulfate-resisting Portland cement. The metal loadings and the metal salts added to the system were varied (50 up to 5000 mg/kg; NO3(-), SO4(2-), Cl-). The XAS study showed that for all investigated systems Ni(ll) is predominantly immobilized in a layered double hydroxide (LDH) phase, which was corroborated by DRS measurements. Only a minor extent of Ni(ll) precipitates as Ni-hydroxides (alpha-Ni(OH)2 and beta-Ni(OH)2). This finding suggests that Ni-Al LDH, rather than Ni-hydroxides, is the solubility-limiting phase in the Ni-doped cement system.

  11. Design and fabrication of Ni nanowires having periodically hollow nanostructures.

    Science.gov (United States)

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-10-07

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag 'barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 ± 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni(2+) for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.

  12. Ductility of Ni3Al doped with substitutional elements

    International Nuclear Information System (INIS)

    Hanada, S.; Chiba, A.; Guo, H.Z.; Watanabe, S.

    1993-01-01

    This paper reports on ductility of B-free Ni 3 Al alloys. Recrystallized Ni 3 Al binary alloys with Ni-rich compositions show appreciable ductility when an environmental effect is eliminated, while the alloys with stoichiometric and Al-rich compositions remain brittle. The ductility in the Ni-rich Ni 3 Al alloys is associated with low ordering energy. The additions of ternary elements, which are classified as γ formers, ductilize ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Pd, Pt, Cu and Co), whereas the additions of γ' formers embrittle ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Ta, Mo, Nb, Zr, Hf, V, Ti and Si). The additions of small amounts (less than 1 at%) of γ' formers such as Zr and Hf also ductilize as-cast ternary Ni 3 Al alloys. Ductility of Ni 3 Al alloys doped with substitutional elements is discussed in terms of ordering energy and microstructure

  13. CO2 activation on bimetallic CuNi nanoparticles

    Directory of Open Access Journals (Sweden)

    Natalie Austin

    2016-10-01

    Full Text Available Density functional theory calculations have been performed to investigate the structural, electronic, and CO2 adsorption properties of 55-atom bimetallic CuNi nanoparticles (NPs in core-shell and decorated architectures, as well as of their monometallic counterparts. Our results revealed that with respect to the monometallic Cu55 and Ni55 parents, the formation of decorated Cu12Ni43 and core-shell Cu42Ni13 are energetically favorable. We found that CO2 chemisorbs on monometallic Ni55, core-shell Cu13Ni42, and decorated Cu12Ni43 and Cu43Ni12, whereas, it physisorbs on monometallic Cu55 and core-shell Cu42Ni13. The presence of surface Ni on the NPs is key in strongly adsorbing and activating the CO2 molecule (linear to bent transition and elongation of C˭O bonds. This activation occurs through a charge transfer from the NPs to the CO2 molecule, where the local metal d-orbital density localization on surface Ni plays a pivotal role. This work identifies insightful structure-property relationships for CO2 activation and highlights the importance of keeping a balance between NP stability and CO2 adsorption behavior in designing catalytic bimetallic NPs that activate CO2.

  14. NiCo2S4 nanosheet-decorated 3D, porous Ni film@Ni wire electrode materials for all solid-state asymmetric supercapacitor applications.

    Science.gov (United States)

    Saravanakumar, Balasubramaniam; Jayaseelan, Santhana Sivabalan; Seo, Min-Kang; Kim, Hak-Yong; Kim, Byoung-Suhk

    2017-12-07

    Wire type supercapacitors with high energy and power densities have generated considerable interest in wearable applications. Herein, we report a novel NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode for high performance supercapacitor application. In this work, a facile method is introduced to fabricate a 3D, porous Ni film deposited on a Ni wire as a flexible electrode, followed by decoration with NiCo 2 S 4 as an electroactive material. The fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode displays a superior performance with an areal and volumetric capacitance of 1.228 F cm -2 and 199.74 F cm -3 , respectively, at a current density of 0.2 mA cm -1 with a maximum volumetric energy and power density (E V : 6.935 mW h cm -3 ; P V : 1.019 W cm -3 ). Finally, the solid state asymmetric wire type supercapacitor is fabricated using the fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire as a positive electrode and N-doped reduced graphene oxide (N-rGO) as a negative electrode and this exhibits good areal and volumetric capacitances of C A : 0.12 F cm -2 and C V : 19.57 F cm -2 with a higher rate capability (92%). This asymmetric wire type supercapacitor demonstrates a low leakage current and self-discharge with a maximum volumetric energy (E V : 5.33 mW h cm -3 ) and power (P V : 855.69 mW cm -3 ) density.

  15. Surface morphology and electronic structure of Ni/Ag(100)

    International Nuclear Information System (INIS)

    Hite, D. A.; Kizilkaya, O.; Sprunger, P. T.; Howard, M. M.; Ventrice, C. A. Jr.; Geisler, H.; Zehner, D. M.

    2000-01-01

    The growth morphology and electronic structure of Ni on Ag(100) has been studied with scanning tunneling microscopy (STM) and synchrotron based angle resolved photoemission spectroscopy. At deposition temperatures at or below 300 K, STM reveals Ni cluster growth on the surface along with some subsurface growth. Upon annealing to 420 K, virtually all Ni segregates into the subsurface region forming embedded nanoclusters. The electronic structure of Ni d bands in the unannealed surface shows dispersion only perpendicular to the surface whereas the annealed surface has Ni d bands that exhibit a three-dimensional-like structure. This is a result of the increased Ni d-Ag sp hybridization bonding and increased coordination of the embedded Ni nanoclusters. (c) 2000 American Vacuum Society

  16. Measurement and analyses of molten Ni-Co alloy density

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; K. MUKAI; FANG Liang; FU Ya; YANG Ren-hui

    2006-01-01

    With the advent of powerful mathematical modeling techniques for material phenomena, there is renewed interest in reliable data for the density of the Ni-based superalloys. Up to now, there has been few report on the density of molten Ni-Co alloy.In order to obtain more accurate density data for molten Ni-Co alloy, the density of molten Ni-Co alloy was measured with a modified sessile drop method, and the accommodation of different atoms in molten Ni-Co alloy was analyzed. The density of alloy is found to decrease with increasing temperature and Co concentration in the alloy. The molar volume of molten Ni-Co alloy increases with increasing Co concentration. The molar volume of Ni-Co alloy determined shows a positive deviation from the linear molar volume, and the deviation of molar volume from ideal mixing increases with increasing Co concentration over the experimental concentration range.

  17. In situ NiTi/Nb(Ti) composite

    International Nuclear Information System (INIS)

    Jiang, Daqiang; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

    2013-01-01

    Graphical abstract: - Highlights: • In situ NiTi/Nb(Ti) composites were fabricated. • The transformation temperature was affected by the mixing Ti:Ni atomic ratios. • The NiTi component became micron-scale lamella after forging and rolling. • The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength

  18. Ni3d-Gd4f correlation effects on the magnetic behaviour of GdNi

    Energy Technology Data Exchange (ETDEWEB)

    Paulose, P L [Tata Inst. of Fundamental Research, Bombay (India); Patil, Sujata [Tata Inst. of Fundamental Research, Bombay (India); Mallik, R [Tata Inst. of Fundamental Research, Bombay (India); Sampathkumaran, E V [Tata Inst. of Fundamental Research, Bombay (India); Nagarajan, V [Tata Inst. of Fundamental Research, Bombay (India)

    1996-07-01

    The results of magnetization and heat-capacity measurements on the alloys, Gd{sub 1-x}Y{sub x}Ni (x=0.0, 0.25, 0.5, 0.75 and 0.9) are reported. The data suggest that there is a Gd induced magnetic moment on Ni, which may in turn enhance Gd-Gd exchange interaction strength in GdNi. The induced moment (on Ni) apparently exhibits itinerant ferromagnetism in the magnetically ordered state of GdNi. (orig.).

  19. Effects of Bond Coating on NiCrBSi-Mo Composite Functional Coating Properties in Plasma Spraying NiCrBSi-Mo/Ni Coating

    OpenAIRE

    DU Ji-yu; LI Fang-yi; LU Hai-yang; SHANG Jian-tong; LI Zhen

    2017-01-01

    Nickel-based bond coating and composite functional coating were sprayed on leaf blade steel material FV520B successively by using air plasma spraying system. NiCrBSi-Mo powder deposition rate, coating porosity, bonding strength and surface hardness were tested. The results indicate that, for the NiCrBSi-Mo/Ni coating, bond coating with 180-220μm thickness can improve NiCrBSi-Mo powder deposition rate while the surface coating with lower porosity, higher bonding strength and high hardness is p...

  20. Thermodynamic characterization of Ni3TeO6, Ni2Te3O8 and NiTe2O5

    Science.gov (United States)

    Dawar, Rimpi; Babu, R.; Ananthasivan, K.; Anthonysamy, S.

    2017-09-01

    Measurement of vapour pressure of TeO2(g) over the biphasic mixture Ni3TeO6 (s) + NiO(s) in the temperature range 1143-1272 K was carried out using transpiration-thermogravimetric technique (TTG). Gibbs energy of formation of Ni3TeO6 was obtained from the temperature dependence of vapour pressure of TeO2 (g) generated by the incongruent vapourisation reaction, Ni3TeO6 (s) → NiO(s) + TeO2 (g) + 1/2 O2 in the temperature range 1143-1272 K. An isoperibol type drop calorimeter was used to measure the enthalpy increments of Ni3TeO6, Ni2Te3O8 and NiTe2O5. Thermodynamic functions viz., heat capacity, entropy and Gibbs energy functions of these compounds were derived from the experimentally measured enthalpy increment values. Third-law analysis was carried out to ascertain absence of temperature dependent systematic errors in the measurement of vapour pressure of TeO2 (g). A value of -1265.1 ± 1.5 kJ mol-1 was obtained for Δ Hf,298K o (Ni3TeO6) using third-law analysis.

  1. Structural and magnetic properties of Ni-Zn and Ni-Zn-Co ferrites

    Energy Technology Data Exchange (ETDEWEB)

    Knyazev, A.V., E-mail: knyazevav@gmail.com [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Zakharchuk, I.; Lähderanta, E. [Lappeenranta University of Technology, P.O. Box 20, FI-53851 Lappeenranta (Finland); Baidakov, K.V.; Knyazeva, S.S. [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Ladenkov, I.V. [Joint-stock Company “Research and Production Company “Salut”, Nizhni Novgorod (Russian Federation)

    2017-08-01

    Highlights: • Ni-Zn and Ni-Zn-Co ferrite powders were prepared by the solid-state reaction at 1073 K. • The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. • The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. • The temperature dependences of magnetization exhibit large spin frustration and spin-glass-like behavior. - Abstract: Ni-Zn and Ni-Zn-Co ferrite powders with nominal compositions Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} were prepared by the solid-state reaction synthesis with periodic regrinding during the calcination at 1073 K. The structure of Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} was refined assuming space group F d-3m. Scanning electron microscopy revealed the average sizes of the crystalline ferrite particles are 130–630 nm for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 140–350 nm for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. The Curie temperature tends to increase upon Zn substitution by Co, as well. The temperature dependences of magnetization measured using zero-field cooled and field cooled protocols exhibit large spin frustration and spin-glass-like behavior.

  2. Anti-corrosive and anti-microbial properties of nanocrystalline Ni-Ag coatings

    Energy Technology Data Exchange (ETDEWEB)

    Raghupathy, Y.; Natarajan, K.A.; Srivastava, Chandan, E-mail: csrivastava@materials.iisc.ernet.in

    2016-04-15

    Graphical abstract: - Highlights: • Electrodeposition yielded phase-segregated, nanocrystalline Ni-Ag coatings. • Ni-Ag alloys exhibited smaller Ni crystals compared to pure Ni. • Ultra fine Ni grains of size 12–14 nm favoured Ni-Ag solid solution. • Nanocrystalline Ag resisted bio-fouling by Sulphate Reducing bacteria. • Ni-Ag outperformed pure Ni in corrosion and bio-corrosion tests. - Abstract: Anti-corrosive and anti-bacterial properties of electrodeposited nanocrystalline Ni-Ag coatings are illustrated. Pure Ni, Ni-7 at.% Ag, & Ni-14 at.% Ag coatings were electrodeposited on Cu substrate. Coating consisted of Ni-rich and Ag-rich solid solution phases. With increase in the Ag content, the corrosion resistance of the Ni-Ag coating initially increased and then decreased. The initial increase was due to the Ni-Ag solid solution. The subsequent decrease was due to the increased galvanic coupling between the Ag-rich and Ni-rich phases. For all Ag contents, the corrosion resistance of the Ni-Ag coating was higher than the pure Ni coating. Exposure to Sulphate Reducing Bacteria (SRB) revealed that the extent of bio-fouling decreased with increase in the Ag content. After 2 month exposure to SRB, the Ni-Ag coatings demonstrated less loss in corrosion resistance (58% for Ni-7 at.% Ag and 20% for Ni-14 at.% Ag) when compared pure Ni coating (115%).

  3. Niños y niñas como cuidadores familiares

    Directory of Open Access Journals (Sweden)

    María Rosa Estupiñán Aponte

    2015-01-01

    Full Text Available En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las destrezas necesarias. Desde una perspectiva de género, el artículo busca evidenciar esta situación mediante la revisión de los abordajes que sobre el tema se han hecho en países de Europa y Norteamérica, así como el análisis de información obtenida a partir de las Encuestas de Hogares y Uso del Tiempo (EUT en algunos países de Latinoamérica. Se establece la forma como las problemáticas sociales inciden en las dinámicas, tipo de tareas y responsabilidades que deben asumir niños y niñas en los hogares, mostrando delgados límites entre la colaboración al interior de las familias, la transmisión cultural de roles y funciones y las actividades que podrían incidir negativamente en su crecimiento y el ejercicio de sus derechos.

  4. Estilos de vida saludables de niños, niñas y adolescentes

    Directory of Open Access Journals (Sweden)

    Lilia Campo-Ternera

    2017-01-01

    Full Text Available Objetivo: Describir los estilos de vida saludables de niños, niñas y adolescentes de Barranquilla. Materiales y métodos: Estudio descriptivo de corte transversal en 991 niños, niñas y ado - lescentes. Se evaluó la actividad física mediante los cuestionarios de Actividad Física para Adolescentes y para niños escolares; se aplicó una encuesta que midió los conocimientos y prácticas de los escolares sobre salud bucal, lavado de manos, consumo de frutas y verduras y cuidado postural; la Lista de Chequeo “Mi Vida en la Escuela”, la cual evalúa los índices de “bullying” y agresión; y la inteligencia emocional a través dela escala TMMS -24. Resultados: El 65,4 % se categoriza como inactivos físicamente. Solo el 14,7% de los estudiantes reconoce que el peso máximo del bolso es el 10 % de su peso corporal; el 34,1 % cambia el cepillo de dientes cada 3 meses, como lo recomiendan los expertos, y 48,4 % se cepilla los dientes entre 2 y 3 veces al día. El 16,6 % no se lava las manos antes y después de ir al baño y 9,4 % no lo hace antes y después de las comidas; el 17,5 % no tiene un buen consumo de verduras y frutas; y se encontró un Índice de “bullying” en el 55,6 % de los participantes. Conclusión: Los anteriores resultados obligan a plantear intervenciones que incrementen las prácticas saludables en niños, niñas y adolescentes.

  5. Electrochemical properties of the ball-milled LaMg10NiMn alloy with Ni powders

    International Nuclear Information System (INIS)

    Wang Yi; Wang Xin; Gao Xueping; Shen Panwen

    2008-01-01

    The electrochemical characteristics of the ball-milled LaMg 10 NiMn alloys with Ni powders were investigated. It was found that the ball-milled LaMg 10 NiMn + 150 wt.% Ni composite exhibited higher first discharge capacity and better cycle performance. By means of the analysis of electrochemical impedance spectra (EIS), it was shown that the existence of manganese in LaMg 10 NiMn alloy increased the electrocatalytic activity due to its catalytic effect, and destabilized metal hydrides, and so reduced the hydrogen diffusion resistance. These contributed to the higher discharge capacity of the ball-milled LaMg 10 NiMn-Ni composite. According to the analytical results of X-ray diffraction (XRD), EIS and steady-state polarization (SSP) experiments, the inhibition of metal corrosion is not the main reason for the better cycle performance. The main reason is that the electrochemical reaction resistance of the ball-milled LaMg 10 NiMn-Ni composite is always lower than that of the ball-milled LaMg 10 Ni 2 -Ni composite because the former one contains manganese, which is a catalyst for the electrode reaction

  6. High-frequency permeability of electroplated CoNiFe and CoNiFe-C alloys

    International Nuclear Information System (INIS)

    Rhen, Fernando M.F.; McCloskey, Paul; O'Donnell, Terence; Roy, Saibal

    2008-01-01

    We have investigated CoNiFe and CoNiFe-C electrodeposited by pulse reverse plating (PRP) and direct current (DC) techniques. CoNiFe(PRP) films with composition Co 59.4 Fe 27.7 Ni 12.8 show coercivity of 95 A m -1 (1.2 Oe) and magnetization saturation flux (μ 0 M s ) of 1.8 T. Resistivity of CoNiFe (PRP) is about 24 μΩ cm and permeability remains almost constant μ r ' ∼475 up to 30 MHz with a quality factor (Q) larger than 10. Additionally, the permeability spectra analysis shows that CoNiFe exhibits a classical eddy current loss at zero bias field and ferromagnetic resonance (FMR) when biased with 0.05 T. Furthermore, a crossover between eddy current and FMR loss is observed for CoNiFe-PRP when baised with 0.05 T. DC and PRP plated CoNiFe-C, which have resistivity and permeability of 85, 38 μΩ cm, μ r '=165 and 35 with Q>10 up to 320 MHz, respectively, showed only ferromagnetic resonance losses. The ferromagnetic resonance peaks in CoNiFe and CoNiFe-C are broad and resembles a Gaussian distribution of FMR frequencies. The incorporation of C to CoNiFe reduces eddy current loss, but also reduces the FMR frequency

  7. Corrosive sliding wear behavior of laser clad Mo2Ni3Si/NiSi intermetallic coating

    International Nuclear Information System (INIS)

    Lu, X.D.; Wang, H.M.

    2005-01-01

    Many ternary metal silicides such as W 2 Ni 3 Si, Ti 2 Ni 3 Si and Mo 2 Ni 3 Si with the topologically closed-packed (TCP) hP12 MgZn 2 type Laves phase crystal structure are expected to have outstanding wear and corrosion resistance due to their inherent high hardness and sluggish temperature dependence and strong atomic bonds. In this paper, Mo 2 Ni 3 Si/NiSi intermetallic coating was fabricated on substrate of an austenitic stainless steel AISI321 by laser cladding using Ni-Mo-Si elemental alloy powders. Microstructure of the coating was characterized by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive X-ray analysis (EDS). Wear resistance of the coating is evaluated under corrosive sliding wear test condition. Influence of corrosion solutions on the wear resistance of the coating was studied and the wear mechanism was discussed based on observations of worn surface morphology. Results showed that the laser clad Mo 2 Ni 3 Si/NiSi composite coating have a fine microstructure of Mo 2 Ni 3 Si primary dendrites and the interdendritic Mo 2 Ni 3 Si/NiSi eutectics. The coating has excellent corrosive wear resistance compared with austenitic stainless steel AISI321 under acid, alkaline and saline corrosive environments

  8. Magnetic properties of two new compounds: Pr2Ni3Si5 and Ho2Ni3Si5

    International Nuclear Information System (INIS)

    Mazumdar, C.; Padalia, B.D.; Godart, C.

    1994-01-01

    Formation of two more new materials, Pr 2 Ni 3 Si 5 and Ho 2 Ni 3 Si 5 , of the series, R 2 Ni 3 Si 5 (R = rare earth and Y) and their magnetic properties are reported here. These materials crystallize in the orthorhombic U 2 Co 3 Si 5 -type structure (space group Ibam). Magnetic susceptibility measurement in the temperature range 5 K--300 K show that the compound Pr 2 Ni 3 Si 5 order antiferromagnetically at T N ∼ 8.5 K and Ho 2 Ni 3 Si 5 at ∼ 6 K. Considering T N (Gd 2 Ni 3 Si 5 ) ∼ 15 K, T N (Pr 2 Ni 3 Si 5 ) ∼ 8.5 K is rather high. The magnetic susceptibility of both of the materials, in the paramagnetic state, follows a Curie-Weiss law with effective moment close to that of the corresponding free trivalent rare earth ion

  9. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

    Directory of Open Access Journals (Sweden)

    Vladimir Linkov

    2013-07-01

    Full Text Available Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C, were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM, X-ray diffraction (XRD and X-ray photoelectron spectroscopy (XPS, and methanol oxidation activity compared using CV and chronoamperometry (CA. While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells.

  10. Hard X-ray MCD in GdNi/sub 5/ and TbNi/sub 5/ single crystals

    CERN Document Server

    Galera, R M

    1999-01-01

    XMCD experiments have been performed at the R L/sub 2,3/ and Ni K- edges on magnetically saturated single crystals of GdNi/sub 5/ and Tb Ni/sub 5/ ferromagnetic compounds. The spectra present huge and well structured dichroic $9 signals at both the R L/sub 2,3/ and the Ni K- edges. Structures from the quadrupolar (2p to 4f) transitions are clearly observed at the R L/sub 2,3/-edges. Though Ni is not magnetic, large intensities, up to 0.4, are measured at the $9 Ni K- edge. The Ni K-edge XMCD shows a three-peak structure which intensities dependent on the rare earth. (7 refs).

  11. Electrochemically induced transformation of NiS nanoparticles into Ni(OH)2 in KOH aqueous solution toward electrochemical capacitors

    International Nuclear Information System (INIS)

    Hou Linrui; Yuan Changzhou; Li Diankai; Yang Long; Shen Laifa; Zhang Fang; Zhang Xiaogang

    2011-01-01

    Highlights: → NiS is synthesized by means of the H 2 O/CS 2 interface under hydrothermal treatment. → NiS itself owns poor electrochemical capacitance in 2 M KOH solution. → NiS is electrochemically induced and transformed into electroactive Ni(OH) 2 . → Ni(OH) 2 is responsible for good energy storage of the NiS in the KOH solution. → The new formed Ni(OH) 2 delivers large energy density at high rates. - Abstract: Nickel sulfide nanoparticles (NPs) are first synthesized by virtue of a unique H 2 O/CS 2 interface under mild hydrothermal treatment. Electrochemical data reveals that the as-synthesized NiS NPs themselves own poor supercapacitive behavior at initial cyclic voltammetry (CV) cycles in 2 M KOH solution, while a specific capacitance of 893 F g -1 can be surprisingly obtained at a current density of 5 A g -1 just after continuous 320 CV cycles. X-ray diffraction and Fourier transform infrared techniques demonstrate that what is really responsible for the good electrochemical capacitance in the KOH aqueous solution is the new electrochemically formed Ni(OH) 2 phase, rather than NiS NPs themselves. The Ni(OH) 2 is slowly formed during the continuous CV cycling process, in which the electrochemically induced phase transformation from NiS to Ni(OH) 2 phase takes place. Furthermore, the new Ni(OH) 2 phase demonstrates the great ability of delivering large specific capacitance at high rates.

  12. Fe-Ni-bearing serpentines from the saprolite horizon of Caribbean Ni-laterite deposits: new insights from thermodynamic calculations

    Science.gov (United States)

    Villanova-de-Benavent, Cristina; Domènech, Cristina; Tauler, Esperança; Galí, Salvador; Tassara, Santiago; Proenza, Joaquín A.

    2017-10-01

    Fe-Ni-bearing serpentine from the saprolite horizon is the main Ni ores in hydrous silicate-type Ni laterites and formed by chemical weathering of partially serpentinized ultramafic rocks under tropical conditions. During lateritization, Mg, Si, and Ni are leached from the surface and transported downwards. Fe2+ is oxidized to Fe3+ and fixed as insoluble Fe-oxyhydroxides (mostly goethite) that incorporate Ni. This Ni is later leached from goethite and incorporated in secondary serpentine and garnierite. As a result, a serpentine-dominated saprolite horizon forms over the ultramafic protolith, overlapped by a Fe-oxyhydroxide-dominated limonite horizon. The serpentine from the protolith (serpentine I) is of hydrothermal origin and yields similar Ni (0.10-0.62 wt.% NiO) and lower Fe (mostly 1.37-5.81 wt.% FeO) concentrations than the primary olivine. In contrast, Fe-Ni-bearing serpentine from the saprolite (serpentine II) shows significantly higher and variable Fe and Ni contents, typically ranging from 2.23 to 15.59 wt.% Fe2O3 and from 1.30 to 7.67 wt.% NiO, suggesting that serpentine get enriched in Fe and Ni under supergene conditions. This study presents detailed mineralogical, textural, and chemical data on this serpentine II, as well as new insights by thermodynamic calculations assuming ideal solution between Fe-, Ni- and Mg-pure serpentines. The aim is to assess if at atmospheric pressure and temperature Fe-Ni-bearing serpentine can be formed by precipitation. Results indicate that the formation of serpentine II under atmospheric pressure and temperature is thermodynamically supported, and pH, Eh, and the equilibrium constant of the reaction are the parameters that affect the results more significantly.

  13. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Santella, M.L.; Alexander, D.J. [Oak Ridge National Laboratory, TN (United States)] [and others

    1995-05-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for (1)high-strength castable composition for turbochargers, furnace furniture, and hot-die applications; (2) castability (fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) hot fabricability of cast ingots. All of the issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes work completed to address some of these issues during the fourth quarter of FY 1994.

  14. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Viswanathan, S.; Santella, M.L. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, wire, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for: (1) high-strength castable composition for many applications that have been identified; (2) castability (mold type, fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) workability of cast or powder metallurgy product to sheet, bar, and wire. The four issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes the work completed to address some of these issues during FY 1996.

  15. Internal chlorination of Ni-Cr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Berztiss, D.; Hennesen, K.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1998-12-31

    In contrast to internal oxidation, sulfidation and carburization, very little information is available regarding internal chlorination, especially diffusion of chlorine in metallic alloys. This paper describes results of experiments on Ni-Cr alloys (<10 wt% Cr) exposed in an atmosphere containing radioactive HCl. The diffusion of chlorine in the alloy can be determined by measurement of residual {beta}-activity from the sample surface. Successively thin layers (0.5-10 {mu}m) of the alloy were removed by lapping and the surface activity was measured to obtain a depth profile. Both single and polycrystalline materials were tested. Through this work it should be determined if there is in fact solubility and diffusion of chlorine in Ni-based alloys as some authors have proposed or if the ingress of chlorine is mainly a grain boundary phenomenon. (orig.)

  16. Resonant Ni and Fe KLL Auger spectra photoexcited from NiFe alloys

    International Nuclear Information System (INIS)

    Koever, L.; Cserny, I.; Berenyi, Z.; Egri, S.; Novak, M.

    2005-01-01

    Complete text of publication follows. KLL Auger spectra of 3d transition metal atoms in solid environment, measured using high energy resolution, give an insight into the details of the local electronic structure surrounding the particular atoms emitting the signal Auger electrons. Fine tuning the energy of the exciting monochromatic photons across the K-absorption edge, features characteristic to resonant phenomena can be identified in the spectra. The shapes of the resonantly photoexcited KLL Auger spectra induced from 3d transition metals and alloys are well interpreted by the single step model of the Auger process, based on the resonant scattering theory. The peak shapes are strongly influenced by the 4p partial density of unoccupied electronic states around the excited atom. High energy resolution studies of KLL Auger spectra of 3d transition metals using laboratory X-ray sources, however, request very demanding experiments and yield spectra of limited statistical quality making the evaluation of the fine details in the spectra difficult. The Tunable High Energy XPS (THE- XPS) instrument at BW2 offers optimum photon x and energy resolution for spectroscopy of deep core Auger transitions. For the present measurements high purity polycrystalline Ni and Fe sheets as well as NiFe alloy samples of different compositions (Ni 80 Fe 20 , Ni 50 Fe 50 , Ni 20 Fe 80 ) were used. The surfaces of the samples were cleaned by in-situ argon ion sputtering. The measurements of the Ni and Fe KL 23 L 23 Auger spectra of the metal and alloy samples were performed with the THE-XPS instrument using high electron energy resolution (0.2 eV). In Fig.1, the measured Fe KL 23 L 23 spectrum, photoexcited at the Fe K absorption edge from Fe metal, is compared with the respective spectrum excited from a Ni 50 Fe 50 alloy. A significant broadening of the 1 D 2 peak and an enhancement of the spectral intensity at the low energy loss part of this peak observed in the alloy sample, while the

  17. Phase transitions in alloys of the Ni-Mo system

    International Nuclear Information System (INIS)

    Ustinovshikov, Y.; Shabanova, I.

    2011-01-01

    Graphical abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys was studied by methods of TEM and XPS. It is shown that at high temperatures the tendency toward phase separation takes place in the alloys and crystalline bcc Mo particles precipitate in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the dissolution of Mo particles and precipitation of the particles of Ni 3 Mo, Ni 2 Mo or Ni 4 Mo chemical compounds. Highlights: → 'Chemical' phase transition 'ordering-phase separation' is first discovered in alloys of the Ni-Mo system. → It is first shown that the phase separation in the alloys studied begins at temperatures above the liquidus one. → The formation of Ni 3 Mo from A1 has gone through the intervening stage of the Ni 4 Mo and Ni 2 Mo coexistence. - Abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys heat treated at different temperatures was studied by the method of transmission electron microscopy. X-ray photoelectron spectroscopy was used to detect the sign of the chemical interaction between Ni and Mo atoms at different temperatures. It is shown that at high temperatures the tendency toward phase separation takes place. The system of additional reflections at positions {1 1/2 0} on the electron diffraction patterns testifies that the precipitation of crystalline bcc Mo particles begins in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the precipitation of the particles of the chemical compounds. A body-centered tetragonal phase Ni 4 Mo (D1 a ) is formed in the Ni-20 at.% Mo alloy. In the Ni-25 at.% Mo alloy, the formation of the Ni 3 Mo (D0 22 ) chemical compound from the A1 solid solution has gone through the intervening stage of the Ni 4 Mo (D1 a ) and Ni 2 Mo (Pt 2 Mo) formation.

  18. Combining Ru, Ni and Ni(OH){sub 2} active sites for improving catalytic performance in benzene hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Lihua, E-mail: lihuazhu@stu.xmu.edu.cn [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Sun, Hanlei; Zheng, Jinbao [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Yu, Changlin, E-mail: yuchanglinjx@163.com [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Zhang, Nuowei [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Shu, Qing [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Chen, Bing H., E-mail: chenbh@xmu.edu.cn [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)

    2017-05-01

    In this study, the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were successfully prepared by the simple methods of hydrazine-reduction and galvanic replacement, where 0.04/0.96 and T represented the Ru/Ni atomic ratio and reducing temperature of the catalyst in N{sub 2}+10%H{sub 2}, respectively. The nanostructures of the Ru{sub 0.04}Ni{sub 0.96} nanoparticles in the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were controlled by modulating their annealing temperature in N{sub 2}+10%H{sub 2} and characterized by an array of techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy energy dispersive X-ray spectroscopy (STEM-EDS) mapping and high-sensitivity low-energy ion scattering (HS-LEIS). The Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, which was composed of Ru clusters or single atoms supported on Ni/Ni(OH){sub 2} nanoparticles, exhibited much better catalytic performance for benzene hydrogenation than the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts reduced at above 30 °C, such as Ru{sub 0.04}Ni{sub 0.96}/C(160) with the nanostructure of partial Ru{sub 0.04}Ni{sub 0.9} alloy and Ru{sub 0.04}Ni{sub 0.96}/C(280) with the nanostructure of complete Ru{sub 0.04}Ni{sub 0.9} alloy. The reason was that the synergistic effect of multiple active sites – Ru, Ni and Ni(OH){sub 2} sites was present in the Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, where hydrogen was preferentially activated at Ru sites, benzene was probably activated at Ni(OH){sub 2} surface and Ni acted as a “bridge” for transferring activated H{sup ∗} species to activated benzene by hydrogen spillover effect, hydrogenating and forming product – cyclohexane. This study also provided a typical example to illustrate that the synergy effect of multiple active sites can largely improve the catalytic hydrogenation performance. - Highlights: • The Ru

  19. Imaging magnetic domains in Ni nanostructures

    International Nuclear Information System (INIS)

    Asenjo, A.; Jaafar, M.; Gonzalez, E.M.; Martin, J.I.; Vazquez, M.; Vicent, J.L.

    2007-01-01

    The study of nanomagnets is the subject of increasing scientific effort. The size, the thickness and the geometric shape of the elements determine the magnetic properties and then the domain configuration. In this work, we fabricated by electron-beam lithography the three different arrays of Ni nanostructures keeping the size, the thickness and also the distance constant between the elements but varying the geometry: square, triangular and circular. The domain structure of the nanomagnets is studied by magnetic force microscopy

  20. Determination of 59Ni in radioactive waste

    International Nuclear Information System (INIS)

    Fisera, O.; Sebesta, F.

    2010-01-01

    Composite material PAN-DMG, containing chelating agent dimethylglyoxime (DMG) immobilized in porous matrix of binding polymer polyacrylonitrile (PAN), was used for nickel separation and concentration. Method for preparation of 59 Ni source for low energy photon spectrometry was developed using homogeneous precipitation of nickel with DMG. The proposed method was tested with two types of real radioactive waste (boric acid concentrate from nuclear power plant (NPP) evaporator and spent ion exchanger from NPP). (author)

  1. Structural, electrical and magnetic properties of evaporated Ni/Cu and Ni/glass thin films

    Energy Technology Data Exchange (ETDEWEB)

    Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: A_Layadi@yahoo.fr; Guittoum, A. [Centre de Recherche Nucleaire d' Alger (CRNA), Alger 16000 (Algeria); Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Chauveau, T. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Billet, D. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Youssef, J. Ben [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Bourzami, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Bourahli, M.-H. [Departement d' O. M. P., Universite Ferhat Abbas, Setif 19000 (Algeria)

    2007-01-25

    The structural, electrical and magnetic properties of Ni thin films evaporated onto glass and polycrystalline Cu substrates have been investigated. The Ni thickness ranges from 31 to 165 nm. X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM) have been used to study the structure and morphology of these systems. The Ni/Cu and Ni/glass thin films are found to be polycrystalline with a (1 1 1) texture. There is an overall increase of the grain size with increasing thickness. A negative strain was noted indicating that all the samples are under a compressive stress. Diffusion at the grain boundaries seems to be a major contribution to the electrical resistivity in this thickness range. Study of the hysteresis curves, obtained by vibrating sample magnetometer (VSM), indicates that all samples are characterized by an in-plane magnetization easy axis. Higher in-plane coercive fields seem to be associated with higher grain size, indicating that coercivity may be due to nucleation of reverse domains rather than pinning of domain walls. The saturation field and the squareness have been studied as a function of the Ni thickness.

  2. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-10-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  3. HDO of Methyl Palmitate over Silica-Supported Ni Phosphides: Insight into Ni/P Effect

    Directory of Open Access Journals (Sweden)

    Irina V. Deliy

    2017-10-01

    Full Text Available Two sets of silica-supported nickel phosphide catalysts with a nickel content of about 2.5 and 10 wt % and Ni/P molar ratio 2/1, 1/1 and 1/2 in each set, were prepared by way of a temperature-programmed reduction method using (Ni(CH3COO2 and ((NH42HPO4 as a precursor. The NixPy/SiO2 catalysts were characterized using chemical analysis N2 physisorption, XRD, TEM, 31P MAS NMR. Methyl palmitate hydrodeoxygenation (HDO was performed in a trickle-bed reactor at 3 MPa and 290 °C with LHSV ranging from 0.3 to 16 h−1. The Ni/P ratio was found to affect the nickel phosphide phase composition, POx groups content and catalytic properties in methyl palmitate HDO with the TOF increased along with a decline of Ni/P ratio and a growth of POx groups’ content. Taking into account the possible routes of methyl palmitate conversion (metal-catalyzed hydrogenolysis or acid-catalyzed hydrolysis, we proposed that the enhancement of acid POx groups’ content with the Ni/P ratio decrease provides an enhancement of the rate of methyl palmitate conversion through the acceleration of acid-catalyzed hydrolysis.

  4. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-01-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  5. Tungsten inert gas (TIG) welding of Ni-rich NiTi plates: functional behavior

    Science.gov (United States)

    Oliveira, J. P.; Barbosa, D.; Braz Fernandes, F. M.; Miranda, R. M.

    2016-03-01

    It is often reported that, to successfully join NiTi shape memory alloys, fusion-based processes with reduced thermal affected regions (as in laser welding) are required. This paper describes an experimental study performed on the tungsten inert gas (TIG) welding of 1.5 mm thick plates of Ni-rich NiTi. The functional behavior of the joints was assessed. The superelasticity was analyzed by cycling tests at maximum imposed strains of 4, 8 and 12% and for a total of 600 cycles, without rupture. The superelastic plateau was observed, in the stress-strain curves, 30 MPa below that of the base material. Shape-memory effect was evidenced by bending tests with full recovery of the initial shape of the welded joints. In parallel, uniaxial tensile tests of the joints showed a tensile strength of 700 MPa and an elongation to rupture of 20%. The elongation is the highest reported for fusion-welding of NiTi, including laser welding. These results can be of great interest for the wide-spread inclusion of NiTi in complex shaped components requiring welding, since TIG is not an expensive process and is simple to operate and implement in industrial environments.

  6. High resolution TEM study of Ni4Ti3 precipitates in austenitic Ni51Ti49

    International Nuclear Information System (INIS)

    Tirry, Wim; Schryvers, Dominique

    2003-01-01

    Binary NiTi with a composition of 51 at.% Ni was heat treated to form lens-shaped Ni 4 Ti 3 precipitates that are coherent or semi-coherent with the B2 matrix. High resolution transmission electron microscopy (HRTEM) was used to study the internal structure of the precipitates, precipitate-precipitate and matrix-precipitate interfaces and the deformation of the B2 matrix near a precipitate. Observations were made in the B2 and B2 zones and compared with computer simulated high resolution images. The B2 observations made it possible to study the [0 0 1] H zone orientation of Ni 4 Ti 3 (direction defined according to the hexagonal unit cell of Ni 4 Ti 3 ) which corresponds to the normal of the central plane of the discs. In these images the superperiodicity of the 4:3 ordering is clearly visible confirming the known atomic structure. Close to the precipitate the B2 matrix is deformed, as determined by measuring the interplanar spacing from the HRTEM images. The observed deformations are compared with theoretical models for the stress field

  7. Breakdown of antiferromagnet order in polycrystalline NiFe/NiO bilayers probed with acoustic emission

    Science.gov (United States)

    Lebyodkin, M. A.; Lebedkina, T. A.; Shashkov, I. V.; Gornakov, V. S.

    2017-07-01

    Magnetization reversal of polycrystalline NiFe/NiO bilayers was investigated using magneto-optical indicator film imaging and acoustic emission techniques. Sporadic acoustic signals were detected in a constant magnetic field after the magnetization reversal. It is suggested that they are related to elastic waves excited by sharp shocks in the NiO layer with strong magnetostriction. Their probability depends on the history and number of repetitions of the field cycling, thus testifying the thermal-activation nature of the long-time relaxation of an antiferromagnetic order. These results provide evidence of spontaneous thermally activated switching of the antiferromagnetic order in NiO grains during magnetization reversal in ferromagnet/antiferromagnet (FM/AFM) heterostructures. The respective deformation modes are discussed in terms of the thermal fluctuation aftereffect in the Fulcomer and Charap model which predicts that irreversible breakdown of the original spin orientation can take place in some antiferromagnetic grains with disordered anisotropy axes during magnetization reversal of exchange-coupled FM/AFM structures. The spin reorientation in the saturated state may induce abrupt distortion of isolated metastable grains because of the NiO magnetostriction, leading to excitation of shock waves and formation of plate (or Lamb) waves.

  8. Electric Monopole Transition Strengths in 62Ni

    Directory of Open Access Journals (Sweden)

    Evitts L. J.

    2016-01-01

    Full Text Available Excited states in 62Ni were populated with a (p, p’ reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0, were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77−34+23 × 10−3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0 value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0 values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0 value for the 22+ to 21+ transition.

  9. Electric Monopole Transition Strengths in 62Ni

    Science.gov (United States)

    Evitts, L. J.; Garnsworthy, A. B.; Kibédi, T.; Moukaddam, M.; Alshahrani, B.; Eriksen, T. K.; Holt, J. D.; Hota, S. S.; Lane, G. J.; Lee, B. Q.; McCormick, B. P.; Palalani, N.; Reed, M. W.; Stroberg, S. R.; Stuchbery, A. E.

    2016-09-01

    Excited states in 62Ni were populated with a (p, p') reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0), were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77-34+23 × 10-3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0) value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0) values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0) value for the 22+ to 21+ transition.

  10. Length-dependent corrosion behavior, Ni2+ release, cytocompatibility, and antibacterial ability of Ni-Ti-O nanopores anodically grown on biomedical NiTi alloy.

    Science.gov (United States)

    Hang, Ruiqiang; Liu, Yanlian; Bai, Long; Zhang, Xiangyu; Huang, Xiaobo; Jia, Husheng; Tang, Bin

    2018-08-01

    In the present work, nickel-titanium-oxygen nanopores with different length (0.55-114 μm) were anodically grown on nearly equiatomic nickel-titanium (NiTi) alloy. Length-dependent corrosion behavior, nickel ion (Ni 2+ ) release, cytocompatibility, and antibacterial ability were investigated by electrochemical, analytical chemistry, and biological methods. The results show constructing nanoporous structure on the NiTi alloy improve its corrosion resistance. However, the anodized samples release more Ni 2+ than that of the bare NiTi alloy, suggesting chemical dissolution of the nanopores rather than electrochemical corrosion governs the Ni 2+ release. In addition, the Ni 2+ release amount increases with nanopore length. The anodized samples show good cytocompatibility when the nanopore length is covers the one (1-11 μm) that the nanopores showing favorable antibacterial ability. Consequently, the nanopores with length in the range of 1-11 μm are promising as coatings of biomedical NiTi alloy for anti-infection, drug delivery, and other desirable applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  11. Effects of P/Ni ratio and Ni content on performance of γ-Al_2O_3-supported nickel phosphides for deoxygenation of methyl laurate to hydrocarbons

    International Nuclear Information System (INIS)

    Zhang, Zhena; Tang, Mingxiao; Chen, Jixiang

    2016-01-01

    Graphical abstract: - Highlights: • The formation of AlPO_4 was unfavorable for that of nickel phosphides. • The phase compositions of nickel phosphide depended on the amount of reduced P. • Catalytic activity was determined by surface Ni site density and catalyst acidity. • HDO pathway was promoted by increasing P/Ni ratio and Ni content. • Nickel phosphide gave much higher carbon yield and lower H_2 consumption than Ni. - Abstract: γ-Al_2O_3-supported nickel phosphides (mNi-Pn) were prepared by the TPR method and tested for the deoxygenation of methyl laurate to hydrocarbons. The effects of the P/Ni ratio (n = 1.0–2.5) and Ni content (m = 5–15 wt.%) in the precursors on their structure and performance were investigated. Ni/γ-Al_2O_3 was also studied for comparison. It was found that the formation of AlPO_4 in the precursor inhibited the reduction of phosphate and so the formation of nickel phosphides. With increasing the P/Ni ratio and Ni content, the Ni, Ni_3P, Ni_1_2P_5 and Ni_2P phases orderly formed, accompanying with the increases of their particle size and the amount of weak acid sites (mainly due to P-OH group), while the CO uptake and the amount of medium strong acid sites (mainly related to Ni sites) reached maximum on 10%Ni-P1.5. In the deoxygenation reaction, compared with Ni/γ-Al_2O_3, the mNi-Pn catalysts showed much lower activities for decarbonylation, C−C hydrogenolysis and methanation due to the ligand and ensemble effects of P. The conversion and the selectivity to n-C11 and n-C12 hydrocarbons achieved maximum on 10%Ni-P 2.0 for the 10%Ni-Pn catalysts and on 8%Ni-P2.0 for the mNi-P2.0 catalysts, while the turnover frequency (TOF) of methyl laurate mainly increased with the P/Ni ratio and Ni content. We propose that TOF was influenced by the nickel phosphide phases, the catalyst acidity and the particle size as well as the synergetic effect between the Ni site and acid site. Again, the hydrodeoxygenation pathway of methyl

  12. Level structure of 60Ni from the 58Ni(α,2p#betta#) reaction

    International Nuclear Information System (INIS)

    Chan, T.U.; Morand, C.; Azgui, F.

    1982-03-01

    The 60 Ni nucleus has been studied via the 58 Ni (α, 2p#betta#) reaction at Esub(α)=32 MeV using in-beam #betta# spectroscopy techniques. High-spin states up to 10 MeV excitation have been established. Among the 5 branches depopulating the Yrast Jsup(π)=7 - state, has been found an E3 transition down to the 4 + state. Comparison with direct reaction results leads to assign very probably the [#betta#fsub(5/2),#betta#gsub(9/2)] 7 - configuration to the Jsup(π)=7 - Yrast state at 5349 keV. Other high-spin states might be accounted for by the breaking of the 56 Ni core

  13. Atomistic simulation of the pinning of edge dislocations in Ni by Ni3Al precipitates

    International Nuclear Information System (INIS)

    Kohler, Christopher; Kizler, Peter; Schmauder, Siegfried

    2005-01-01

    Classical molecular dynamics simulations of the interaction of edge dislocations in Ni with chains of spherical Ni 3 Al precipitates are performed using EAM potentials. The order hardening is investigated at temperature T=0 -bar K by determining the critical resolved shear stresses (CRSSs) for a superdislocation that is dissociated into four partial dislocations. The CRSS is computed as a function of the radius and the distance of the precipitates. It is found that for precipitates with a diameter smaller than the dissociation width of perfect edge dislocation in Ni, the CRSS of the trailing dislocation of the superdislocation is a fraction of about 0.4 of the CRSS of the leading dislocation

  14. Sorption properties of new composite materials suitable for radioanalytical determination of 59-Ni and 63-Ni

    International Nuclear Information System (INIS)

    Fisera, O.; Sebesta, F.

    2006-01-01

    New composite materials for separation and radioanalytical determination of radionickel ( 59, 63 Ni) were prepared and their sorption properties were examined. Chelating agents dimethylglyoxime (DMG) and diphenylglyoxime (DFG) as active components were immobilized in porous matrix of binding polymer polyacrylonitrile (PAN). Sorption properties of these materials were compared with commercial Ni Resin (Eichrom Technologies, USA). Weight distribution ratios, sorption kinetics and operating capacities were investigated during experiments performed. The highest weight distribution ratios were found for the material DFG-PAN. The sorbent DMG-PAN has the highest operating capacity. The fastest kinetics of nickel sorption was determined for the commercial Ni Resin. Elution of nickel with nitric acid solution allows subsequent and direct determination of radionickel by liquid scintillation counting. (author)

  15. Effect of amorphous Mg50Ni50 on hydriding and dehydriding behavior of Mg2Ni alloy

    International Nuclear Information System (INIS)

    Guzman, D.; Ordonez, S.; Fernandez, J.F.; Sanchez, C.; Serafini, D.; Rojas, P.A.; Aguilar, C.; Tapia, P.

    2011-01-01

    Composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 was prepared by mechanical milling starting with nanocrystalline Mg 2 Ni and amorphous Mg 50 Ni 50 powders, by using a SPEX 8000 D mill. The morphological and microstructural characterization of the powders was performed via scanning electron microscopy and X-ray diffraction. The hydriding characterization of the composite was performed via a solid gas reaction method in a Sievert's-type apparatus at 363 K under an initial hydrogen pressure of 2 MPa. The dehydriding behavior was studied by differential thermogravimetry. On the basis of the results, it is possible to conclude that amorphous Mg 50 Ni 50 improved the hydriding and dehydriding kinetics of Mg 2 Ni alloy upon cycling. A tentative rationalization of experimental observations is proposed. - Research Highlights: → First study of the hydriding behavior of composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 . → Microstructural characterization of composite material using XRD and SEM was obtained. → An improved effect of Mg 50 Ni 50 on the Mg 2 Ni hydriding behavior was verified. → The apparent activation energy for the hydrogen desorption of composite was obtained.

  16. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting.

    Science.gov (United States)

    Wang, Dewen; Li, Qun; Han, Ce; Xing, Zhicai; Yang, Xiurong

    2018-01-24

    The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS 2 nanosheet array on carbon cloth (NiO@Ni/WS 2 /CC) composite. This composite serves as a unique three-dimensional (3D) synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS 2 , but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS 2 . This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO 2 , as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm -2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS 2 . Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  17. Impact of Interstitial Ni on the Thermoelectric Properties of the Half-Heusler TiNiSn

    Directory of Open Access Journals (Sweden)

    Sonia A. Barczak

    2018-03-01

    Full Text Available TiNiSn is an intensively studied half-Heusler alloy that shows great potential for waste heat recovery. Here, we report on the structures and thermoelectric properties of a series of metal-rich TiNi1+ySn compositions prepared via solid-state reactions and hot pressing. A general relation between the amount of interstitial Ni and lattice parameter is determined from neutron powder diffraction. High-resolution synchrotron X-ray powder diffraction reveals the occurrence of strain broadening upon hot pressing, which is attributed to the metastable arrangement of interstitial Ni. Hall measurements confirm that interstitial Ni causes weak n-type doping and a reduction in carrier mobility, which limits the power factor to 2.5–3 mW m−1 K−2 for these samples. The thermal conductivity was modelled within the Callaway approximation and is quantitively linked to the amount of interstitial Ni, resulting in a predicted value of 12.7 W m−1 K−1 at 323 K for stoichiometric TiNiSn. Interstitial Ni leads to a reduction of the thermal band gap and moves the peak ZT = 0.4 to lower temperatures, thus offering the possibility to engineer a broad ZT plateau. This work adds further insight into the impact of small amounts of interstitial Ni on the thermal and electrical transport of TiNiSn.

  18. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    D’Addato, S., E-mail: sergio.daddato@unimore.it [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Spadaro, M.C. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Luches, P. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Grillo, V. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); CNR-IMEM, Parco Area delle Scienze 37/A, 43100 Parma (Italy); Frabboni, S.; Valeri, S. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Ferretti, A.M.; Capetti, E.; Ponti, A. [CNR-ISTM, Laboratorio di Nanotecnologie, via G. Fantoli 16/15, 20138 Milano (Italy)

    2014-07-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  19. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting

    Directory of Open Access Journals (Sweden)

    Dewen Wang

    2017-12-01

    Full Text Available The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER and oxygen evolution reaction (OER is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS2 nanosheet array on carbon cloth (NiO@Ni/WS2/CC composite. This composite serves as a unique three-dimensional (3D synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS2, but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS2. This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO2, as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm–2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS2. Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  20. Enhanced optical and electrical properties of Ni inserted ITO/Ni/AZO tri-layer structure for photoelectric applications

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, M. Melvin David; Kim, Hyunki [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of); Park, Yun Chang [Measurement and Analysis Division, National Nanofab Center (NNFC), Daejeon 305-806 (Korea, Republic of); Kim, Joondong, E-mail: joonkim@incheon.ac.kr [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of)

    2015-05-15

    Highlights: • Ni-embedding transparent conductor effectively reduces the resistivity. • Ni insertion improves the carrier mobility and collection efficiencies. • ITO/Ni/AZO is effective to improve photo-responses compared to ITO/AZO. - Abstract: A thin Ni layer of 5 nm thickness was deposited in between indium-tin-oxide (ITO) and aluminum-doped-zinc oxide (AZO) layers of 50 nm thickness each. The Ni inserting tri-layer structure (ITO/Ni/AZO) showed lower resistivity of 5.51 × 10{sup −4} Ωcm which is nearly 20 times lesser than 97.9 × 10{sup −4} Ωcm of bilayer structure (ITO/AZO). A thin Ni layer in between ITO and AZO enhanced the carrier concentration, mobility and photoresponse behaviors so that figure of merit (FOM) value of ITO/Ni/AZO device was greater than that of ITO/AZO device. ITO/Ni/AZO structure showed improved quantum efficiencies over a broad range of wavelengths (∼350–950 nm) compared to that of ITO/AZO bilayer structure, resulting in enhanced photoresponses. These results show that the optical, electrical and photoresponse properties of ITO/AZO structure could be enhanced by inserting Ni layer of 5 nm thickness in between ITO and AZO layers.