WorldWideScience

Sample records for water structure breakers

  1. Laboratory effectiveness testing of water-in-oil emulsion breakers

    International Nuclear Information System (INIS)

    Fingas, M.F.; Fieldhouse, B.; Bier, I.; Conrod, D.; Tennyson, E.

    1995-01-01

    The physics and chemistry of water-in-oil emulsions dominate the development of effectiveness tests. Emulsions are variable in stability--this variability is largely dependent on oil type and degree of weathering. These factors complicate the development of a test. Emulsions which have low stability will apparently break easily with chemical emulsion breakers. Broken emulsions will form a foam-like material, called rag, which retains water which is not part of the stable emulsions. Analytical methods used to determine the final stability of the broken or unbroken emulsion were evaluated. Measurements of water content and viscosity measurements show correlation to emulsion stability. Viscosity provides a more reliable measure of emulsion stability but water content measurements are more convenient and are largely used in this study. Twelve tests were developed in the past. Two testing methods have been developed to a usable stage. These tests are described and data using them provided. The effects of mixing time, agent amount, settling time and mixing energy on effectiveness results are presented

  2. Influence of deep cryogenic treatment on structure and wear resistance of materials of hydraulic breaker chisels

    Science.gov (United States)

    Bolobov, V. I.; BinhLe, Thanh

    2018-03-01

    It is shown that shallow cryogenic treatment at -75°C (SCT) of the materials of hydraulic breaker chisels - P20, 1080 and D2 steels leads to a decrease (44 ÷ 82%) in the amount of retained austenite and an increase (26 ÷ 99%) in the amount of carbides in the structure of hardened steel, which is accompanied by an increase in its hardness (1.4 ÷ 2.1%) and abrasive wear resistance (10 ÷ 31%) with a simultaneous decrease in impact toughness (19 ÷ 24%). Deep cryogenic treatment at -196°C (DCT) and subsequent low-temperature tempering of D2 steel leads to a significant increase in its wear resistance (98%) and impact toughness (32%).

  3. AUTOMATED ANALYSIS OF BREAKERS

    Directory of Open Access Journals (Sweden)

    E. M. Farhadzade

    2014-01-01

    Full Text Available Breakers relate to Electric Power Systems’ equipment, the reliability of which influence, to a great extend, on reliability of Power Plants. In particular, the breakers determine structural reliability of switchgear circuit of Power Stations and network substations. Failure in short-circuit switching off by breaker with further failure of reservation unit or system of long-distance protection lead quite often to system emergency.The problem of breakers’ reliability improvement and the reduction of maintenance expenses is becoming ever more urgent in conditions of systematic increasing of maintenance cost and repair expenses of oil circuit and air-break circuit breakers. The main direction of this problem solution is the improvement of diagnostic control methods and organization of on-condition maintenance. But this demands to use a great amount of statistic information about nameplate data of breakers and their operating conditions, about their failures, testing and repairing, advanced developments (software of computer technologies and specific automated information system (AIS.The new AIS with AISV logo was developed at the department: “Reliability of power equipment” of AzRDSI of Energy. The main features of AISV are:· to provide the security and data base accuracy;· to carry out systematic control of breakers conformity with operating conditions;· to make the estimation of individual  reliability’s value and characteristics of its changing for given combination of characteristics variety;· to provide personnel, who is responsible for technical maintenance of breakers, not only with information but also with methodological support, including recommendations for the given problem solving  and advanced methods for its realization.

  4. Rectifier cabinet static breaker

    International Nuclear Information System (INIS)

    Costantino, R.A. Jr; Gliebe, R.J.

    1992-01-01

    A rectifier cabinet static breaker replaces a blocking diode pair with an SCR and the installation of a power transistor in parallel with the latch contactor to commutate the SCR to the off state. The SCR serves as a static breaker with fast turnoff capability providing an alternative way of achieving reactor scram in addition to performing the function of the replaced blocking diodes. The control circuitry for the rectifier cabinet static breaker includes on-line test capability and an LED indicator light to denote successful test completion. Current limit circuitry provides high-speed protection in the event of overload. 7 figs

  5. Rectifier cabinet static breaker

    Science.gov (United States)

    Costantino, Jr, Roger A.; Gliebe, Ronald J.

    1992-09-01

    A rectifier cabinet static breaker replaces a blocking diode pair with an SCR and the installation of a power transistor in parallel with the latch contactor to commutate the SCR to the off state. The SCR serves as a static breaker with fast turnoff capability providing an alternative way of achieving reactor scram in addition to performing the function of the replaced blocking diodes. The control circuitry for the rectifier cabinet static breaker includes on-line test capability and an LED indicator light to denote successful test completion. Current limit circuitry provides high-speed protection in the event of overload.

  6. Circuit breaker and bus

    International Nuclear Information System (INIS)

    Vogel, H.F.

    1978-01-01

    Two close-open operations are required each pulse cycle at approximately 3 MA with the breaker in series with the burn supply, both forming a leg in parallel with the E-coil and the homopolar. To conduct the 3-MA current, approximately 30 breaker units are connected in parallel. Each unit is equipped with a counterpulse capacitor bank, and the bus for the 30 units is provided with a common saturable reactor core made of strip steel wound around the bus. Oil breakers of a special design are chosen because of their high arc resistance facilitating the current transfer to the homopolar machine and for obtaining precision timing in opening and closing of the contacts. The precision timing is achieved by a shock wave method with the oil serving as hydraulic medium. Each of the parallel breaker units possesses two sets of contacts, a stationary and a transient one. A 1-mΩ resistor in series with the transient contacts of each breaker unit is to improve the current sharing. The bus consists of room temperature copper, stranded and transposed to help provide current equalization under transient conditions

  7. Statins: antimicrobial resistance breakers or makers?

    Directory of Open Access Journals (Sweden)

    Humphrey H.T. Ko

    2017-10-01

    Full Text Available Introduction The repurposing of non-antibiotic drugs as adjuvant antibiotics may help break antimicrobial resistance (AMR. Statins are commonly prescribed worldwide to lower cholesterol. They also possess qualities of AMR “breakers”, namely direct antibacterial activity, synergism with antibiotics, and ability to stimulate the host immune system. However, statins’ role as AMR breakers may be limited. Their current extensive use for cardiovascular protection might result in selective pressures for resistance, ironically causing statins to be AMR “makers” instead. This review examines statins’ potential as AMR breakers, probable AMR makers, and identifies knowledge gaps in a statin-bacteria-human-environment continuum. The most suitable statin for repurposing is identified, and a mechanism of antibacterial action is postulated based on structure-activity relationship analysis. Methods A literature search using keywords “statin” or “statins” combined with “minimum inhibitory concentration” (MIC was performed in six databases on 7th April 2017. After screening 793 abstracts, 16 relevant studies were identified. Unrelated studies on drug interactions; antifungal or antiviral properties of statins; and antibacterial properties of mevastatin, cerivastatin, antibiotics, or natural products were excluded. Studies involving only statins currently registered for human use were included. Results Against Gram-positive bacteria, simvastatin generally exerted the greatest antibacterial activity (lowest MIC compared to atorvastatin, rosuvastatin, and fluvastatin. Against Gram-negative bacteria, atorvastatin generally exhibited similar or slightly better activity compared to simvastatin, but both were more potent than rosuvastatin and fluvastatin. Discussion Statins may serve as AMR breakers by working synergistically with existing topical antibiotics, attenuating virulence factors, boosting human immunity, or aiding in wound healing. It

  8. Commutation circuit for an HVDC circuit breaker

    Science.gov (United States)

    Premerlani, William J.

    1981-01-01

    A commutation circuit for a high voltage DC circuit breaker incorporates a resistor capacitor combination and a charging circuit connected to the main breaker, such that a commutating capacitor is discharged in opposition to the load current to force the current in an arc after breaker opening to zero to facilitate arc interruption. In a particular embodiment, a normally open commutating circuit is connected across the contacts of a main DC circuit breaker to absorb the inductive system energy trapped by breaker opening and to limit recovery voltages to a level tolerable by the commutating circuit components.

  9. Design and computational analysis of passive siphon breaker for 49-2 swimming pool reactor

    International Nuclear Information System (INIS)

    Yue Zhiting; Song Yunpeng; Liu Xingmin; Zou Yao; Wu Yuanyuan

    2014-01-01

    Based on safety considerations, a passive siphon breaker will be added to the primary cooling system of 49-2 Swimming Pool Reactor (SPR). With the breaker location determined, the capability of siphon breakers with diameters of 1.5 cm and 2.0 cm was calculated and analyzed respectively by RELAP5/MOD3.3 code. The results show that in the condition of large break loss of coolant accident these two sizes of siphon breakers are able to break the siphon phenomena, and maintain the pool water level above the reactor core when the reactor and the pump are shutdown. In the end, to be conservative, the siphon breaker with diameter of 2.0 cm is adopted. (authors)

  10. Hydraulic actuator for an electric circuit breaker

    Science.gov (United States)

    Imam, Imdad [Colonie, NY

    1983-01-01

    This actuator comprises a fluid motor having a piston, a breaker-opening space at one side of the piston, and a breaker-closing space at its opposite side. An accumulator freely communicates with the breaker-opening space for supplying pressurized fluid thereto during a circuit breaker opening operation. The breaker-opening space and the breaker-closing space are connected by an impeded flow passage. A pilot valve opens to allow the pressurized liquid in the breaker-closing space to flow to a back chamber of a normally closed main valve to cause the main valve to be opened during a circuit breaker opening operation to release the pressurized liquid from the breaker-closing space. An impeded passage affords communication between the back chamber and a sump located on the opposite side of the main valve from the back chamber. The pilot valve and impeded passage allow rapid opening of the main valve with pressurized liquid from the breaker closing side of the piston.

  11. Retrofit breakers resolve trip failures

    International Nuclear Information System (INIS)

    Hanna, G.L.

    1995-01-01

    This articles examines how power plants can use advance planning and retrofit equipment to upgrade existing systems while avoiding unnecessary downtime. A break that fails to open challenges the safety features of a nuclear power plant. To ensure reliable operations, the utility selected a comprehensive retrofit program to replace a third of the 200 breakers originally installed at the Shearon Harris Nuclear Power Plant. Under contract, the retrofits--Siemens RLN breakers--were built and qualified for nuclear service by Wyle Laboratories through a special teaming agreement with Siemens Energy and Automation. The project offers an excellent example of how a utility can use advance planning and retrofit equipment to upgrade its existing systems while avoiding unnecessary downtime

  12. Smart Circuit Breaker Communication Infrastructure

    Directory of Open Access Journals (Sweden)

    Octavian Mihai MACHIDON

    2017-11-01

    Full Text Available The expansion of the Internet of Things has fostered the development of smart technologies in fields such as power transmission and distribution systems (as is the Smart Grid and also in regard to home automation (the Smart Home concept. This paper addresses the network communication infrastructure for a Smart Circuit Breaker system, a novel application at the edge of the two afore-mentioned systems (Smart Grid and Smart Home. Such a communication interface has high requirements from functionality, performance and security point of views, given the large amount of distributed connected elements and the real-time information transmission and system management. The paper describes the design and implementation of the data server, Web interface and the embedded networking capabilities of the smart circuit breakers, underlining the protocols and communication technologies used.

  13. What's new about generator circuit breakers

    International Nuclear Information System (INIS)

    Kolarik, P.L.

    1979-01-01

    The need for updating ANSI C37 Standards for AC high-voltage circuit breakers has become necessary because of the increased interest in power circuit breakers for generator application. These circuit breakers, which have continuous current ratings and rated short-circuit currents that are much higher than those presently covered by existing C37 Standards, take on added importance because they are being installed in critical AC power supplies at nuclear power stations

  14. Interactive effects of relay and circuit breaker aging in a safety-related system

    International Nuclear Information System (INIS)

    Toman, G.J.; Bacanskas, V.P.; Shook, T.A.; Ladlow, C.C.; Gunther, W.

    1987-01-01

    This paper provides an overview of the results of a program to evaluate the aging of circuit breakers and relays and the effects of that aging on the function of a safety system used in nuclear power plants. The program was performed under the Nuclear Plant Aging Research (NPAR) Program of the US Nuclear Regulatory Commission under subcontract to Brookhaven National Laboratory. There were two primary aspects to the program. In the first, the aging and failure modes of relays and circuit breakers were determined by evaluating the construction, design, and materials and the failure data related to nuclear power plant service. In the second, the interactions between a safety system and its relays and circuit breakers were evaluated to determine the effects of relay and circuit breaker aging on the function of the safety system. The aging of relays and circuit breakers was assessed through evaluation of failure data bases, discussions with utility personnel, and evaluation of equipment operating and maintenance manuals. The interaction study was based on an analysis of the safety injection system of a pressurized water reactor. The effects of stresses from the system were analyzed for the tendency to cause deterioration of the relays and circuit breakers in the system. Then the effect of the deterioration of relays and circuit breakers on the functional capability of the safety system was evaluated

  15. Filter cake breaker systems

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, Marcelo H.F. [Poland Quimica Ltda., Duque de Caxias, RJ (Brazil)

    2004-07-01

    Drilling fluids filter cakes are based on a combination of properly graded dispersed particles and polysaccharide polymers. High efficiency filter cakes are formed by these combination , and their formation on wellbore walls during the drilling process has, among other roles, the task of protecting the formation from instantaneous or accumulative invasion of drilling fluid filtrate, granting stability to well and production zones. Filter cake minimizes contact between drilling fluid filtrate and water, hydrocarbons and clay existent in formations. The uniform removal of the filter cake from the entire interval is a critical factor of the completion process. The main methods used to breaking filter cake are classified into two groups, external or internal, according to their removal mechanism. The aim of this work is the presentation of these mechanisms as well their efficiency. (author)

  16. Extending temporary storage capacity with emulsion breakers

    International Nuclear Information System (INIS)

    Buist, I.; Guarino, A.; DeVitis, D.; Nolan, K.; Lewis, A.; Smith, B.; Lane, J.

    2002-01-01

    The use of emulsion breakers injected into an oil spill recovery system was examined in both laboratory testing and at the OHMSETT test facility. The tests were designed to assess the injection/mixing/settling regimes needed for optimum water-removal performance from a meso-stable water-in-oil emulsion with an oil spill demulsifier. Different types of injection locations and mixing technologies were examined, including skimmer heads, cargo lines, tank inlets, as well as static in-line and mechanical technologies. During laboratory testing, water-in-oil emulsions and free water was pumped through various lengths of piping loops, an in-line mixer and 8 settling tanks. Following the injection of a demulsifier, the fluid was decanted to observe the emulsion breaking. At the OHMSETT test facility, a Desmi Terminator skimmer recovered the same emulsion from a polluted water surface. Different slick thicknesses, wave heights and recovery rates were used. A demulsifier was also injected into the recovered fluid which was allowed to separate in recovery tanks. The demulsifier efficiency was then measured. It was determined that the demulsifier significantly reduced the volume of water in the recovery tanks and the water content of the remaining emulsion. If free water content was greater than 60 per cent, then the effect of the surfactant was greatly reduced. If no free water was present, the level of turbulence was insufficient to promote emulsion breaking. More than 33 per cent free water content is needed to reduce the bulk viscosity of the fluid and to promote emulsion breaking. The degree of emulsion breaking also increased with increasing mixing energy. 10 refs., 5 tabs., 8 figs

  17. Arc modelling in SF6 circuit breakers

    International Nuclear Information System (INIS)

    Verite, J.C.; Boucher, T.; Comte, A.; Delalondre, C.; Robin-Jouan, P.; Serres, E.; Texier, V.; Barrault, M.; Chevrier, P.; Fievet, C.

    1995-06-01

    The paper presents the work done by an operator, EDF and two manufacturers to improve the physical models and numerical methods used to simulate the behavior of the plasma and cold gas around it in a breaking chamber of the HV SF6 circuit breaker, during the high-current phase. This work concerns flow phenomena, in particular incorporating compressibility and the study of turbulence, the coupling between these flow phenomena and electromagnetic phenomena, and finally, radiation - which plays an essential role in energy transfer during the high-current phase. For this latter aspect, emission but also absorption were proven to play a major role, and the two were introduced into the models. The paper presents the models developed and the results obtained with them for simulation of two circuit breaker mock-ups (a double-pressure circuit breaker mock-up and a self-expanding and rotating arc circuit breaker mock-up). (author)

  18. Film breakers prevent migration of aqueous potassium hydroxide in fuel cells

    Science.gov (United States)

    Hess, P. D.

    1970-01-01

    Electrolyte film breakers made from polytetrafluoroethylene are installed in the reactant and water vapor removal outlets of each cell and sealed by elastomers. Use of these devices in the water vapor removal cavity outlets prevents loss of KOH solution through film migration during water removal.

  19. Breaker Maintenance: Volume 3, Molded-Case circuit breakers

    International Nuclear Information System (INIS)

    Davis, E.L.; Funk, D.L.

    1991-09-01

    Modeled-case circuit breakers (MCCBs) provide power and circuit protection in nuclear plant electrical distribution systems. Thus, their proper operation is essential to the safe and reliable operation of plant electrical distribution systems. This guide for both nuclear and non-nuclear power generating facilities will help improve the maintenance and reliability of MCCBs. The authors developed this guide to establish a working-level understanding of hardware performance trends, reliability, and failure modes from which maintenance practices could be specified. The first step in preparing this guide was an in-depth review of available operating experience and failure data, which was obtained from nuclear information sources such as EPRI's Nuclear Maintenance Applications Center. In addition, they evaluated some nonnuclear reliability data. Next, they investigated current industry practices, including a review of manufacturer's recommendations and numerous industry standards. Finally, they used the collective information to develop programmatic recommendations and, where appropriate, detailed inspection and test guidance. This guide offers many recommendations applicable to MCCB maintenance, such as an engineering description of MCCBs and their operation; an overview of reliability and failure data; programmatic recommendations, including inspection and test periodicity; detailed inspection and test guidance; and corrective maintenance recommendations. Supplementary information includes an overview of industry standards, a discussion of regulatory issues, and sample data sheets. An evaluation of operating experience indicates that a maintenance program need not be overly complicated to detect the predominant failure modes associated with MCCBs. Those implementating an MCCB maintenance and testing program, however, must recognize the inherent limitations associated with field-testing of these devices. 42 refs., 17 figs., 7 tabs

  20. Monitoring power breakers using vibro acoustic techniques

    Directory of Open Access Journals (Sweden)

    Horia Balan

    2017-09-01

    Full Text Available Speaking about the commutation’s equipment, it can be said that the best solution in increasing reliability and lowering the maintenance costs is a continuous monitoring of the equipment. However, if the price/quality ratio is considered, it is obvious that, for the moment, the diagnosis can be also an acceptable solution. Nowadays the predictive maintenance for equipment’s diagnosis is currently replacing the preventive diagnosis. An efficient modality of lowering the maintenance costs is to online monitoring the power breakers, during their operation in the power systems. Consequently any connecting/disconnecting operations may be used in diagnosing a power breaker. Thus any supplementary and superfluous tests and/or maintenance maneuvers are avoided. The paper presents the operational maintenance in a power station with three high voltage active breakers, Areva type. The method of establishing the state of a breaker consists in the comparison between the signature of the acoustic signal provided by the manufacturer and the signal issued from the testing operation of the breaker’s state. The software processing procedure and the methodology of determining the faults of the monitored equipment are also developed. All the tests on the circuit breaker are made according the prescriptions of normative.

  1. 30 CFR 75.900-1 - Circuit breakers; location.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Circuit breakers; location. 75.900-1 Section 75.900-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY... Alternating Current Circuits § 75.900-1 Circuit breakers; location. Circuit breakers used to protect low-and...

  2. 30 CFR 75.800-1 - Circuit breakers; location.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Circuit breakers; location. 75.800-1 Section 75.800-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY... § 75.800-1 Circuit breakers; location. Circuit breakers protecting high-voltage circuits entering an...

  3. Hydraulically-activated operating system for an electric circuit breaker

    Science.gov (United States)

    Imam, Imdad; Barkan, Philip

    1979-01-01

    This operating system comprises a fluid motor having a piston, a breaker-opening space at one side of the piston, and a breaker-closing space at its opposite side. An accumulator freely communicates with the breaker-opening space for supplying pressurized fluid thereto during a circuit-breaker opening operation. A normally-closed valve located on the breaker-closing-side of the piston is openable to release liquid from the breaker-closing space so that pressurized liquid in the breaker-opening space can drive the piston in an opening direction. Means is provided for restoring the valve to its closed position following the circuit-breaker opening operation. An impeded passage affords communication between the accumulator and the breaker-closing space to allow pressurized liquid to flow from the accumulator to the breaker-closing space and develop a pressure therein substantially equal to accumulator pressure when the valve is restored to closed position following breaker-opening. This passage is so impeded that the flow therethrough from the accumulator into the breaker-closing space is sufficiently low during initial opening motion of the piston through a substantial portion of its opening stroke as to avoid interference with said initial opening motion of the piston.

  4. Switching phenomena in high-voltage circuit breakers

    International Nuclear Information System (INIS)

    Nakanishi, K.

    1991-01-01

    The topics covered in this book include: general problems concerning current interruption, the physical arc model, and miscellaneous types of modern switching apparatus, such as gas circuit breakers, gas-insulated switch-gear, vacuum circuit breakers and high-voltage direct-current circuit breakers

  5. 735 kV air-blast circuit breakers for Hydro Quebec

    Energy Technology Data Exchange (ETDEWEB)

    Lindstrom, I

    1966-01-01

    In 1962 the Quebec Hydro-Electric Commission started the development of aproject for utilizing water power in Manicouagan and Outardes, two rivers some 350 miles northeast of the city of Montreal on the left bank of the St. Lawrence estuary. The project involved the transmission of power at 735 kV ac from Manicouagan and Outardes to the heavy and growing load centers of Quebec and Montreal. The total amount of energy to be transmitted in the final stage is about 6,000 MW. The project involved the need of considerable quantities of apparatus for 735 kV, such as transformers, reactors, lightning arrestors, circuit-breakers, and disconnectors. Since the supply of the major part of the 735 kV circuit-breakers, altogether 14 three-pole units, was awarded to ASEA in Sweden, a short presentation of these airblast circuit-breakers is presented.

  6. The testing of generator circuit-breakers

    NARCIS (Netherlands)

    Smeets, R.P.P.; Linden, van der W.A.

    1998-01-01

    Generator circuit-breakers face much higher current and voltage stress than distribution switchgear. This has led to a special standard (ANSI C37.013). Strictly in accordance with this standard's requirements, test circuits and parameters for a 100 kA and 120 kA (25.3 kV) SF6 generator

  7. Circuit breaker operation and potential failure modes during an earthquake

    International Nuclear Information System (INIS)

    Lambert, H.E.; Budnitz, R.J.

    1987-01-01

    This study addresses the effect of a strong-motion earthquake on circuit breaker operation. It focuses on the loss of offsite power (LOSP) transient caused by a strong-motion earthquake at the Zion Nuclear Power Plant. This paper also describes the operator action necessary to prevent core melt if the above circuit breaker failure modes occur simultaneously on three 4.16 KV buses. Numerous circuit breakers important to plant safety, such as circuit breakers to diesel generators and engineered safety systems (ESS), must open and/or close during this transient while strong motion is occurring. Potential seismically-induced circuit-breaker failures modes were uncovered while the study was conducted. These failure modes include: circuit breaker fails to close; circuit breaker trips inadvertently; circuit breaker fails to reclose after trip. The causes of these failure modes include: Relay chatter causes the circuit breaker to trip; Relay chatter causes anti-pumping relays to seal-in which prevents automatic closure of circuit breakers; Load sequencer failures. The incorporation of these failure modes as well as other instrumentation and control failures into a limited scope seismic probabilistic risk assessment is also discussed in this paper

  8. Megavolt nanosecond generator with semiconductor current breaker

    CERN Document Server

    Bushlyakov, A I; Rukin, S N; Slovikovskij, B G; Timoshenkov, S P

    2002-01-01

    The heavy-current nanosecond generator with the pulse capacity up to 1.6 GW and output voltage of 0.5-1 MW is described. The generator contains four capacity storages, one induction storage and six solid body commutators: one thyristor, four magnetic commutators and a semiconductor current breaker on the SOS-diodes. The results of studies on the energy change-over efficiency through a semiconductor breaker by various external resistance loads as well as the results of the thermal and frequency tests are presented. It is established that selection of the optimal cooling system provides for the generator continuous mode of operation with the pulse sequence frequency from 300 Hz up to 850 Hz

  9. Short- circuit tests of circuit breakers

    OpenAIRE

    Chorovský, P.

    2015-01-01

    This paper deals with short-circuit tests of low voltage electrical devices. In the first part of this paper, there are described basic types of short- circuit tests and their principles. Direct and indirect (synthetic) tests with more details are described in the second part. Each test and principles are explained separately. Oscilogram is obtained from short-circuit tests of circuit breakers at laboratory. The aim of this research work is to propose a test circuit for performing indirect test.

  10. Development of large-scale thyristor dc circuit breaker

    International Nuclear Information System (INIS)

    Kobayashi, S.; Tanoue, Y.; Ikegame, H.; Matushita, T.; Sato, Y.

    1981-01-01

    A study for developing a thyristor dc circuit breaker that is applicable to the Tokamak device for engineering feasibility is presented. The design and test of a unit circuit breaker consisting of 4kV-3kA thyristors connected 2 in series and 12 in parallel are described. And based on the results a 50kV-24kA thyristor dc circuit breaker is conceptually designed

  11. Structure and Dynamics of Urea/Water Mixtures Investigated by Vibrational Spectroscopy and Molecular Dynamics Simulation

    Science.gov (United States)

    Carr, J. K.; Buchanan, L. E.; Schmidt, J. R.; Zanni, M. T.; Skinner, J. L.

    2013-01-01

    Urea/water is an archetypical “biological” mixture, and is especially well known for its relevance to protein thermodynamics, as urea acts as a protein denaturant at high concentration. This behavior has given rise to an extended debate concerning urea’s influence on water structure. Based on a variety of methods and of definitions of water structure, urea has been variously described as a structure-breaker, a structure-maker, or as remarkably neutral towards water. Because of its sensitivity to microscopic structure and dynamics, vibrational spectroscopy can help resolve these debates. We report experimental and theoretical spectroscopic results for the OD stretch of HOD/H2O/urea mixtures (linear IR, 2DIR, and pump-probe anisotropy decay) and for the CO stretch of urea-D4/D2O mixtures (linear IR only). Theoretical results are obtained using existing approaches for water, and a modification of a frequency map developed for acetamide. All absorption spectra are remarkably insensitive to urea concentration, consistent with the idea that urea only very weakly perturbs water structure. Both this work and experiments by Rezus and Bakker, however, show that water’s rotational dynamics are slowed down by urea. Analysis of the simulations casts doubt on the suggestion that urea immobilizes particular doubly hydrogen bonded water molecules. PMID:23841646

  12. The wave vane - A device to measure the breaker angle

    Digital Repository Service at National Institute of Oceanography (India)

    Chandramohan, P.; Nayak, B.U.; Anand, N.M.

    directional wave gauge at a considerable cost. For economic and practical considerations, visual measurements on the breaker height, the breaker period and the breaker angle are generally made in the LEO pro- gramme. The breaker height is recorded... of the fins. Flag masts are fixed on either end of the arms. The whole assembly thus revolves around the spindle resting on the sleeve. WORKING PRINCIPLE The flag masts, two on the revolving arms and one on the top of the spindle lie always in a straight...

  13. Water structure around trehalose

    Energy Technology Data Exchange (ETDEWEB)

    Pagnotta, S.E. [Dipartimento di Fisica ' E. Amaldi' , Universita di Roma Tre, Via della Vasca Navale 84, 00146 Roma (Italy); CNISM-CNR, Unita di Roma Tre, Via della Vasca Navale 84, 00146 Roma (Italy)], E-mail: pagnotta@fis.uniroma3.it; Ricci, M.A.; Bruni, F. [Dipartimento di Fisica ' E. Amaldi' , Universita di Roma Tre, Via della Vasca Navale 84, 00146 Roma (Italy); McLain, S. [ISIS Facility, Rutherford Appleton Laboratories, Chilton, Didcot, Oxon OX11 0QX (United Kingdom); Magazu, S. [Dipartimento di Fisica, Universita di Messina, C. da Papardo 31, 98166 Messina (Italy)

    2008-04-18

    A diluted solution of trehalose in water has been investigated by means of neutron diffraction with isotopic H/D substitution of the water hydrogens. Data have been analyzed in terms of site-site radial distribution functions, via the EPSR simulation code. This is the first time that the capabilities of this data refinement method are tested against neutron diffraction data of a complex carbohydrate molecule. A small perturbation of water hydration shell and short hydrogen bonds between trehalose oxygens and water hydrogens has been evidenced.

  14. Testing of SF6- and vacuum generator circuit breakers

    NARCIS (Netherlands)

    Smeets, R.P.P.; Paske, te L.H.

    2011-01-01

    Generator circuit breakers differ in various aspects from standard distribution breakers. One of the main differences is in the electrical stresses during fault current interruption. This situation will be discussed in the present contribution, along with the standardization status and the

  15. Double system wave energy converter for the breaker zone

    International Nuclear Information System (INIS)

    Malavasi, Stefano; Negri; Marco

    2015-01-01

    In this paper a particular type of wave energy converter, namely EDS (Energy Double System) is presented. It is a two-body point absorber composed by a heaving float and a surging paddle, mounted on the same structure and aligned along the wave propagation direction. The system is designed for working in the breaker zone, where waves close to breaking can generate a considerable surging force on the paddle. A scale EDS model has been built and tested in the wave flume of the Hydraulics Laboratory of the 'Politecnico' of Milan. The power absorbed by the system, varying its configuration, position and wave, has been measured, and interesting efficiencies have been found.

  16. The structure of liquid water

    International Nuclear Information System (INIS)

    Marin, B.

    1969-01-01

    We have tried to expose a bibliography so complete as possible on structure of liquid water. One synthesis of the different models of water structure is presently impossible, so, we have exposed the main properties of water. We have pointed out the new hypotheses on the electronic structure of water molecule and on the theory of hydrogen bond. After that, we have put together the studies of structure by spectroscopy and given the main deductions of some workers on this subject. We have also exposed the characteristics of processes: relaxation and dielectric constant, influence of temperature on structure. At last, we have considered briefly the partition and thermodynamic functions established from the various models proposed. (author) [fr

  17. Synchronous transmission circuit breaker development. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Garzon, R D

    1976-08-01

    The need for the development of a synchronous transmission breaker is discussed and the basic preliminary specifications for such a circuit breaker are established and tabulated. The initial exploratory work designed to establish the preferred designs for a synchronous pulse generator, (or current zero predictor), for an operating mechanism and for a suitable interrupter are described in detail. The experimental results obtained with vacuum interrupters and with axial blast interrupters using pure SF/sub 6/, mixtures of SF/sub 6/ and N/sub 2/, and high pressure liquid SF/sub 6/ are reported. The results are then evaluated and the performances obtained with each interrupting media are compared arriving at the end to a choice of a preferred design. This preferred design, an interrupter that uses SF/sub 6/ in the liquid state at pressures of 13.8 megapascals (2000 psi), is completely described. The results obtained in a series of experiments designed to establish limits of performance for this interrupter are also discussed.

  18. NRC Information No. 90-41: Potential failure of General Electric Magne-Blast circuit breakers and AK circuit breakers

    International Nuclear Information System (INIS)

    Rossi, C.E.

    1992-01-01

    This information notice is intended to alert addressees to potential safety concerns that may result from failures of GE vertical lift (AM) and horizontal draw-out (AMH) Magne-Blast circuit breakers utilizing ML-13 operating mechanisms to open or close them and AK circuit breakers. The particular breaker failures reported herein were caused by operating problems with prop springs, snap rings and lubricating grease. GE Nuclear Energy has informed the NRC that it is aware of these problems and that GE routinely checks and corrects them if the circuit breakers are serviced at one of the four GE nuclear service centers in the US. However, the NRC is aware that some utilities may have their circuit breakers repaired or serviced at facilities other than the four GE nuclear service centers

  19. Age-related degradation of Westinghouse 480-volt circuit breakers

    International Nuclear Information System (INIS)

    Subudhi, M.; Shier, W.; MacDougall, E.

    1990-07-01

    An aging assessment of Westinghouse DS-series low-voltage air circuit breakers was performed as part of the Nuclear Plant Aging Research (NPAR) program. The objectives of this study are to characterize age-related degradation within the breaker assembly and to identify maintenance practices to mitigate their effect. Since this study has been promulgated by the failures of the reactor trip breakers at the McGuire Nuclear Station in July 1987, results relating to the welds in the breaker pole lever welds are also discussed. The design and operation of DS-206 and DS-416 breakers were reviewed. Failure data from various national data bases were analyzed to identify the predominant failure modes, causes, and mechanisms. Additional operating experiences from one nuclear station and two industrial breaker-service companies were obtained to develop aging trends of various subcomponents. The responses of the utilities to the NRC Bulletin 88-01, which discusses the center pole lever welds, were analyzed to assess the final resolution of failures of welds in the reactor trips. Maintenance recommendations, made by the manufacturer to mitigate age-related degradation were reviewed, and recommendations for improving the monitoring of age-related degradation are discussed. As described in Volume 2 of this NUREG, the results from a test program to assess degradation in breaker parts through mechanical cycling are also included. The testing has characterized the cracking of center-pole lever welds, identified monitoring techniques to determine aging in breakers, and provided information to augment existing maintenance programs. Recommendations to improve breaker reliability using effective maintenance, testing, and inspection programs are suggested. 13 refs., 21 figs., 8 tabs

  20. Viscosities of oxalic acid and its salts in water and binary aqueous ...

    Indian Academy of Sciences (India)

    Unknown

    Viscosities; oxalic acid and its salts; water + THF mixtures; structure-breakers. 1. Introduction ... has found its application in the organic syntheses as manifested from ... water. In other words, these results indicate that oxalic acid and its salts mix ...

  1. Arc modelling in SF{sub 6} circuit breakers

    Energy Technology Data Exchange (ETDEWEB)

    Verite, J.C. [Electricite de France, Clamart (France). Derection des Etudes et Recherches; Boucher, T.; Comte, A. [Electricite de France, Moret sur Loing (France). Direction des Etudes et Recherches; Delalondre, C. [Electricite de France, Chatou (France). Direction des Etudes et Recherches; Robin-Jouan, P.; Serres, E.; Texier, V. [GEC Alsthom, Villeurbanne (France). Direction Technique Haute et Moyenne Tension; Barrault, M.; Chevrier, P.; Fievet, C. [CEA Centre d`Etudes Nucleaires de Grenoble, 38 (France). Merlin Gerin

    1995-06-01

    The paper presents the work done by an operator, EDF and two manufacturers to improve the physical models and numerical methods used to simulate the behavior of the plasma and cold gas around it in a breaking chamber of the HV SF6 circuit breaker, during the high-current phase. This work concerns flow phenomena, in particular incorporating compressibility and the study of turbulence, the coupling between these flow phenomena and electromagnetic phenomena, and finally, radiation - which plays an essential role in energy transfer during the high-current phase. For this latter aspect, emission but also absorption were proven to play a major role, and the two were introduced into the models. The paper presents the models developed and the results obtained with them for simulation of two circuit breaker mock-ups (a double-pressure circuit breaker mock-up and a self-expanding and rotating arc circuit breaker mock-up). (author) 10 refs.

  2. Vision based speed breaker detection for autonomous vehicle

    Science.gov (United States)

    C. S., Arvind; Mishra, Ritesh; Vishal, Kumar; Gundimeda, Venugopal

    2018-04-01

    In this paper, we are presenting a robust and real-time, vision-based approach to detect speed breaker in urban environments for autonomous vehicle. Our method is designed to detect the speed breaker using visual inputs obtained from a camera mounted on top of a vehicle. The method performs inverse perspective mapping to generate top view of the road and segment out region of interest based on difference of Gaussian and median filter images. Furthermore, the algorithm performs RANSAC line fitting to identify the possible speed breaker candidate region. This initial guessed region via RANSAC, is validated using support vector machine. Our algorithm can detect different categories of speed breakers on cement, asphalt and interlock roads at various conditions and have achieved a recall of 0.98.

  3. Oscillating water column structural model

    Energy Technology Data Exchange (ETDEWEB)

    Copeland, Guild [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bull, Diana L [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Jepsen, Richard Alan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gordon, Margaret Ellen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-09-01

    An oscillating water column (OWC) wave energy converter is a structure with an opening to the ocean below the free surface, i.e. a structure with a moonpool. Two structural models for a non-axisymmetric terminator design OWC, the Backward Bent Duct Buoy (BBDB) are discussed in this report. The results of this structural model design study are intended to inform experiments and modeling underway in support of the U.S. Department of Energy (DOE) initiated Reference Model Project (RMP). A detailed design developed by Re Vision Consulting used stiffeners and girders to stabilize the structure against the hydrostatic loads experienced by a BBDB device. Additional support plates were added to this structure to account for loads arising from the mooring line attachment points. A simplified structure was designed in a modular fashion. This simplified design allows easy alterations to the buoyancy chambers and uncomplicated analysis of resulting changes in buoyancy.

  4. Life testing of a low voltage air circuit breaker

    International Nuclear Information System (INIS)

    Subudhi, M.; Aggarwal, S.

    1992-01-01

    A DS-416 low voltage air circuit breaker manufactured by Westinghouse was mechanically cycled to identify age-related degradation in the various breaker subcomponents, specifically the power-operated mechanism. This accelerated aging test was performed on one breaker unit for over 36,000 cycles. Three separate pole shafts, one with a 60-degree weld, one with a 120-degree weld, and one with a 180-degree weld in the third pole lever were used to characterize cracking in the welds. In addition, during the testing three different operating mechanisms and several other parts were replaced as they became inoperable. Among the seven welds on the pole shaft, number-sign 1 and number-sign 3 were found to be critical ones whose fracture can result in misalignment of the pole levers. This can lead to problems with the operating mechanism, including the burning of coils, excessive wear in certain parts, and overstressed linkages. Furthermore, the limiting service life of a number of subcomponents of the power-operated mechanism, including the operating mechanism itself, were assessed. Based on these findings, suggestions are provided to alleviate the age-related degradation that could occur as a result of normal closing and opening of the breaker contacts during its service life. Also, cause and effect analyses of various age-related degradation in various breaker parts are discussed

  5. [Usefullness of the StoneBreaker lithotripter for percutaneous nephrolithotomy].

    Science.gov (United States)

    del Peso, Almudena Coloma; González, Inmaculada Fernández; Gálvez, Milagros Jiménez; Abad, Pablo Garrido; Fajardo, Gloria Bocardo; Fernández, Luis Miguel Herranz; Arjona, Manuel Fernández; Torres, Lorenzo Herrero; Sanz, Ignacio Pereira

    2008-01-01

    Throughout the history, many devices have been used for breaking urinary tract stones. StoneBreaker (LMA Urology, Gland, Switzerland) is a second generation of intracorporeal lithotripter, pneumatic and portable, which adds several new advantages, like effectiveness in stone fragmentation and easy handling, very useful during percutaneous lithotripsy. We report the case of a 40 year-old male patient, with a left kidney pyelic lithiasis, who was treated by percutaneous lithotripsy, under general anaesthesia, with StoneBreaker (LMA Urology, Gland, Switzerland) as lithotripter. StoneBreaker (LMA Urology, Gland, Switzerland) is a lithotripter usable with rigid and semirigid ureteroscopes, much more powerful than its predecessors. It is able to decrease the number of shocks necessary for stone fragmentation, without bigger tissue reaction. It also has a more comfortable design due to the absence of connections, and its power by replaceable carbon dioxide cartridges.

  6. Magnetic Method to Characterize the Current Densities in Breaker Arc

    International Nuclear Information System (INIS)

    Machkour, Nadia

    2005-01-01

    The purpose of this research was to use magnetic induction measurements from a low voltage breaker arc, to reconstruct the arc's current density. The measurements were made using Hall effect sensors, which were placed close to, but outside the breaking device. The arc was modelled as a rectangular current sheet, composed of a mix of threadlike current segments and with a current density varying across the propagation direction. We found the magnetic induction of the arc is a convolution product of the current density, and a function depending on the breaker geometry and arc model. Using deconvolution methods, the current density in the electric arc was determined.The method is used to study the arc behavior into the breaker device. Notably, position, arc size, and electric conductivity could all be determined, and then used to characterize the arc mode, diffuse or concentrated, and study the condition of its mode changing

  7. Inductive energy storage using high voltage vacuum circuit breakers

    International Nuclear Information System (INIS)

    McCann, R.B.; Woodson, H.H.; Mukutmoni, T.

    1976-01-01

    Controlled thermonuclear fusion experiments currently being planned require large amounts of pulsed energy. Inductive energy storage systems (IES) appear to be attractive for at least two applications in the fusion research program: high beta devices and those employing turbulent heating. The well-known roadblock to successful implementation of IES is the development of a reliable and cost-effective off-switch capable of handling high currents and withstanding high recovery voltages. The University of Texas at Austin has a program to explore the application of conventional vacuum circuit breakers designed for use in AC systems, in conjunction with appropriate counter pulse circuits, as off-switches in inductive energy storage systems. The present paper describes the IES employing vacuum circuit breakers as off-switches. Since the deionization property of these circuit breakers is of great importance to the design and the cost of the counter-pulse circuit, a synthetic test installation to test these breakers has been conceived, designed and is being installed in the Fusion Research Center, University of Texas at Austin. Some design aspects of the facility will be discussed here. Finally, the results of the study on a mathematical model developed and optimized to determine the least cost system which meets both the requirements of an off-switch for IES Systems and the ratings of circuit breakers used in power systems has been discussed. This analysis indicates that the most important factor with respect to the system cost is the derating of the circuit breakers to obtain satisfactory lifetimes

  8. Numaerical simulation of a SF6 circuit-breaker arc

    International Nuclear Information System (INIS)

    Vergne, P.J.; Gonzalez, J.J.; Gleizes, A.

    1995-01-01

    The design and the validation of high-voltage circuit breaker require more and more physical models which take into account complex phenomenae. We present here a numerical simulation of an SF 6 arc established in a simplified geometry of a circuit breaker prototype. Our study deals specially with the turbulent flow, the boundary conditions of the arc roots on the electrodes, the influence of the electromagnetic strengths and the radiative transfer. The results concern a stationary state with fixed geometry and current intensity (I=2000 A)

  9. High-voltage direct-current circuit breakers

    International Nuclear Information System (INIS)

    Yoshioka, Y.; Hirasawa, K.

    1991-01-01

    This paper reports that in 1954 the first high-voltage direct-current (HVDC) transmission system was put into operation between Gotland and the mainland of Sweden. Its system voltage and capacity were 100 kV and 20 MW, respectively. Since then many HVDC transmission systems have been planned, constructed, or commissioned in more than 30 places worldwide, and their total capacity is close to 40 GW. Most systems commissioned to date are two-terminal schemes, and HVDC breakers are not yet used in the high-potential main circuit of those systems, because the system is expected to perform well using only converter/inverter control even at a fault stage of the transmission line. However, even in a two-terminal scheme there are not a few merits in using an HVDC breaker when the system has two parallel transmission lines, that is, when it is a double-circuit system

  10. Age-related degradation of Westinghouse 480-volt circuit breakers

    International Nuclear Information System (INIS)

    Subudhi, M.; MacDougall, E.; Kochis, S.; Wilhelm, W.; Lee, B.S.

    1990-11-01

    After the McGuire event in 1987 relating to failure of the center pole weld in one of its reactor trip breakers, activities were initiated by the NRC to investigate the probable causes. A review of operating experience suggested that the burning of coils, jamming of the operating mechanism, and deterioration of the contacts dominated the breakers failures. Although failures of the pole shaft weld were not included as one of the generic problems, the NRC augmented inspection team had suspected that these welds were substandard which led them to crack prematurely. A DS-416 low voltage air circuit breaker manufactured by Westinghouse was mechanically cycled to identify age-related degradations. This accelerated aging test was conducted for over 36,000 cycles during nine months. Three separate pole shafts, one with a 60 degree weld, one with a 120 degree and one with a 180 degree were used to characterize the cracking in the pole level welds. In addition, three different operating mechanisms and several other parts were replaced as they became inoperable. The testing yielded many useful results. The burning of the closing coils was found to be the effect of binding in the linkages that are connected to this device. Among the seven welds on the pole shaft, number-sign 1 and number-sign 3 were the critical ones which cracked first to cause misalignment of the pole levers, which, in turn, had led to many problems with the operating mechanism including the burning of coils, excessive wear in certain parts, and overstressed linkages. Based on these findings, a maintenance program is suggested to alleviate the age-related degradations that occur due to mechanical cycling of this type of breaker. 3 refs., 39 figs., 7 tabs

  11. Lime helps establish crownvetch on coal-breaker refuse

    Science.gov (United States)

    Miroslaw M. Czapowskyj; Edward A. Sowa

    1976-01-01

    A study was begun in 1965 to determine the effect of lime fertilizer, and mulch on the establishment and growth of crownvetch crowns planted on anthracite coal-breaker refuse. After 7 years the lime application had by far the strongest effect. Both 2.5 and 5.0 tons per acre increased survival and ground cover manyfold, and both treatments were equally beneficial from...

  12. The Solenarc circuit-breaker of high performance level

    International Nuclear Information System (INIS)

    Lehmann, J.M.

    1983-01-01

    After recalling the breaking principle involved in MV circuit-breakers manufactured by Merlin Gerin, it is showed how Solenarc technique enables specific problems to be solved that are set by the equipment of Eurodif plant at Tricastin and that represent constraints similar to those encountered with protective equipment for power station auxiliaries (high rated currents, long duration overloads, very high short-circuit currents, current breaks without natural passage through zero, etc.) [fr

  13. Life testing of a low voltage air circuit breaker

    International Nuclear Information System (INIS)

    Subudhi, M.

    1991-01-01

    ADS-416 low voltage air circuit breaker manufacture by Westinghouse was mechanically cycled to identify age-related degradation in various breaker subcomponents, in particular, the power-operating mechanism. This accelerated aging test was performed on one breaker unit for over 36,000 cycles. Three separate pole shafts, one with a 60 degree weld, one with a 120 degree weld and one with a 180 degree weld in the third pole lever were used to characterize the cracking in these welds. In addition, during the testing, three different operating mechanisms and several other parts were replaced as they degraded to an inoperable condition. Of the seven welds on the pole shaft, two were found to be the critical ones whose fracture can result in misalignment problems of the pole levers. These failures, in turn can lead to many other problems with the operating mechanism including the burn-out of coils, excessive wear in certain parts and over-stressed linkages. Furthermore, the limiting service life of a number of subcomponents of the power-operated mechanism, including the operating mechanism itself, were assessed. 1 ref., 3 figs

  14. Low-voltage circuit breaker arcs—simulation and measurements

    International Nuclear Information System (INIS)

    Yang, Fei; Wu, Yi; Rong, Mingzhe; Sun, Hao; Ren, Zhigang; Niu, Chunping; Murphy, Anthony B

    2013-01-01

    As one of the most important electrical components, the low-voltage circuit breaker (LVCB) has been widely used for protection in all types of low-voltage distribution systems. In particular, the low-voltage dc circuit breaker has been arousing great research interest in recent years. In this type of circuit breaker, an air arc is formed in the interrupting process which is a 3D transient arc in a complex chamber geometry with splitter plates. Controlling the arc evolution and the extinction are the most significant problems. This paper reviews published research works referring to LVCB arcs. Based on the working principle, the arcing process is divided into arc commutation, arc motion and arc splitting; we focus our attention on the modelling and measurement of these phases. In addition, previous approaches in papers of the critical physical phenomenon treatment are discussed, such as radiation, metal erosion, wall ablation and turbulence in the air arc. Recommendations for air arc modelling and measurement are presented for further investigation. (topical review)

  15. NRC Information No. 87-41: Failures of certain Brown Boveri Electric circuit breakers

    International Nuclear Information System (INIS)

    Rossi, C.E.

    1992-01-01

    On April 20, 1987, Duquesne Light Company, the Beaver Valley Unit 2 licensee, notified the NRC of the failure of a BBE Type 5HK Class IE 4-KV circuit breaker. When the circuit breaker was racked onto the bus and 125-V DC control power was applied to the breaker's control circuit, the closing spring charged and the circuit breaker immediately closed and opened several times before the control power could be turned off. The licensee determined by field testing that the closing coil was not being energized. Another problem with BBE circuit breakers occurred at River Bend and was reported March 6, 1987. On February 6, 1987, with the unit at full power, the Division I diesel generator 4.16-KV output circuit breaker (Gould-Brown Boveri Type 5HK) failed to close during a weekly surveillance test. The licensee's inspection of the output circuit breaker revealed that a mounting bolt had fallen out of the closing spring charging motor, rendering the motor inoperable. Further investigation revealed several other circuit breakers that contained loose or missing charging motor mounting bolts. The licensee also stated that the River Bend circuit breaker preventive maintenance program, which the licensee believes to be in accordance with the vendor's recommendations, did not detect this problem. The licensee believes the root cause of the problem to be insufficient torquing of the charging motor mounting bolts by the vendor

  16. Assessment and modelling of switching technologies for application in HVDC-circuit breakers

    OpenAIRE

    Lund, Johan

    2011-01-01

    A key element for future DC-grids is a DC circuit breaker that in case of a short circuit fault reliably can turn off a short circuit current. AC circuit breakers are well known components that has been in use for a long time in AC-grids. The AC circuit breaker is designed to interrupt the current at its natural current zero crossings. In DC grids such does not exists, therefore AC breakers can not be directly applied in DC grids. Different concepts and technologies to solve this problem is a...

  17. A mechanical arcless dc circuit breaker for a superconducting magnet system

    International Nuclear Information System (INIS)

    Yamaguchi, S.; Sasao, H.; Matumura, Y.; Tukamoto, T.

    1993-01-01

    Next fusion research experiments plan to use many superconducting magnets. When a quench phenomenon is observed, the current should be interrupted to protect the magnet. Therefore, a dc circuit breaker is necessary. There are four technical situations to be considered for the dc circuit breaker system; (1) high rated current, (2) smaller size breaker, (3) high reliability and (4) no surge voltage during the interruption. The sizer of the breaker is limited by the arc current density of the contacts, and the low current density is better in the circuit breakers. A high rated current also needs the large contacts of the breaker. Here, we introduce a new type of dc circuit breaker system which does not generate an arc plasma between the contacts, equip the high rated current disconnecting switch and a fuse for the failure of the interruption, and use the conventional ac breaker. The switch size of the breaker is almost one hundred times smaller than that of the previous switch. (orig.)

  18. Water cooling of RF structures

    International Nuclear Information System (INIS)

    Battersby, G.; Zach, M.

    1994-06-01

    We present computer codes for heat transfer in water cooled rf cavities. RF parameters obtained by SUPERFISH or analytically are operated on by a set of codes using PLOTDATA, a command-driven program developed and distributed by TRIUMF [1]. Emphasis is on practical solutions with designer's interactive input during the computations. Results presented in summary printouts and graphs include the temperature, flow, and pressure data. (authors). 4 refs., 4 figs

  19. Piezoelectric Bolt Breakers and Bolt Fatigue Testers

    Science.gov (United States)

    Sherrit, Stewart; Badescu, Mircea; Bar-Cohen, Yoseph; Barengoltz, Jack; Heckman, Vanessa

    2008-01-01

    A proposed family of devices for inducing fatigue in bolts in order to break the bolts would incorporate piezoelectric actuators into resonant fixtures as in ultrasonic/ sonic drills/corers and similar devices described in numerous prior NASA Tech Briefs articles. These devices were originally intended primarily for use as safer, more-reliable, more-versatile alternatives to explosive bolts heretofore used to fasten spacecraft structures that must subsequently be separated from each other quickly on command during flight. On Earth, these devices could be used for accelerated fatigue testing of bolts. Fatigue theory suggests that a bolt subjected to both a constant-amplitude dynamic (that is, oscillatory) stress and a static tensile stress below the ultimate strength of the bolt material will fail faster than will a bolt subjected to only the dynamic stress. This suggestion would be applied in a device of the proposed type. The device would be designed so that the device and the bolt to be fatigue-tested or broken would be integral parts of an assembly (see figure). The static tension in the tightened bolt would apply not only the clamping force to hold the joined structures (if any) together but also the compression necessary for proper operation of the piezoelectric actuators as parts of a resonant structural assembly. The constant-amplitude dynamic stress would be applied to the bolt by driving the piezoelectric actuators with a sinusoidal voltage at the resonance frequency of longitudinal vibration of the assembly. The amplitude of the excitation would be made large enough so that the vibration would induce fatigue in the bolt within an acceptably short time. In the spacecraft applications or in similar terrestrial structural-separation applications, devices of the proposed type would offer several advantages over explosive bolts: Unlike explosive bolts, the proposed devices would be reusable, could be tested before final use, and would not be subject to

  20. Testing of 800 and 1200 kV class circuit breakers

    NARCIS (Netherlands)

    Smeets, R.P.P.; Kuivenhoven, S.; Hofstee, A.B.

    2011-01-01

    The most critical transient a circuit breaker has to endure during its operation is the transient recovery voltage (TRV), initiated by the electric power system as a natural reaction on current interruption. For circuit breakers intended to operate in ultra-high voltage systems (with rated voltage

  1. Experimental and theoretical analysis of vacuum circuit breaker prestrike effect on a transformer

    NARCIS (Netherlands)

    Popov, M.; Smeets, R.P.P.; Van der Sluis, L.; De Herdt, H.; Declerq, J.

    2009-01-01

    The work presented in this paper deals with the investigation of circuit breaker prestrike effect that occurs during energizing a distribution transformer. An experimental test setup that consists of a supply transformer, a vacuum circuit breaker (VCB), a cable and a test transformer is built, and

  2. "I just wanted to get away": An analysis of spring breakers' travel motivations

    Science.gov (United States)

    Nuno F. Ribeiro; Paul E. Durrenberger; Careen M. Yarnal; Garry E. Chick

    2010-01-01

    Scholarly research on Spring Break has grown substantially and has often associated spring breakers' motivations with a number of risky behaviors. Recent research, however, has challenged these assumptions. The purpose of this study was to examine spring breakers' motivations for going on Spring Break. Unlike the media portrayal of Spring Break as a time of...

  3. 30 CFR 75.601-1 - Short circuit protection; ratings and settings of circuit breakers.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Short circuit protection; ratings and settings... Trailing Cables § 75.601-1 Short circuit protection; ratings and settings of circuit breakers. Circuit breakers providing short circuit protection for trailing cables shall be set so as not to exceed the...

  4. A High Power Solid State Circuit Breaker for Military Hybrid Electric Vehicle Applications

    Science.gov (United States)

    2012-08-01

    the SSCB to isolate a fault, breaker opening is latched and can be reset to reclose the breaker via remote logic input. SSCB state and health...rated load current (125 A). Figure 10 shows that after the SSCB detects a fault and opens, it can also be repeatedly reclosed remotely to attempt to

  5. 735 kV circuit breakers for ehv

    Energy Technology Data Exchange (ETDEWEB)

    1966-01-01

    French manufacturers have been studying the design of high and extra high voltage circuit breakers for several years. The two techniques they used were the low volume oil and the air pressure technique. These have permitted the development of a type gear capable of solving problems all over the world as they arose following the development of electrical energy transmission at extra high voltage as well as high short circuit power. Today, the air pressure solution is used in new constructions such as the 735 kV transmission network in Canada.

  6. Breaker turbulence and sediment suspension in the surf zone

    DEFF Research Database (Denmark)

    Aagaard, Troels; Hughes, Michael G

    2010-01-01

    Field measurements of fluid velocities and suspended sediment concentrations were used to investigate the relative role of coherent vortices (related to wave breaking) in suspended sediment dynamics. The measurements were obtained from a barred (intermediate-type) beach and the instrument rig...... and incoherent higher-frequency turbulence using a threshold magnitude for the vertical velocity component. Plunging breakers displayed the largest root-mean-square (RMS) and maximum vertical velocities; the latter reaching approximately 1 m s(-1). These measurements were made at an elevation of 0.15 m above...

  7. Tests of a vacuum breaker for the FTU commutation system

    International Nuclear Information System (INIS)

    Andreani, R.; Lovisetto, L.; Cornago, F.

    1984-01-01

    A two poles vacuum breaker, equipped with saturable inductances and capacitor banks to produce an artificial current zero, appears the most suitable solution to satisfy these requirements with high reliability of operation and limited maintenance. Two series of tests have been conducted to evaluate the performance and reliability of the system and in particular the erosion of the electrodes as a function of number of operations. The test results have been very satisfactory. At least 1000 full power pulses can be envisaged before replacing the vacuum bottles. (author)

  8. The Impact Of Surface Shape Of Chip-Breaker On Machined Surface

    Science.gov (United States)

    Šajgalík, Michal; Czán, Andrej; Martinček, Juraj; Varga, Daniel; Hemžský, Pavel; Pitela, David

    2015-12-01

    Machined surface is one of the most used indicators of workpiece quality. But machined surface is influenced by several factors such as cutting parameters, cutting material, shape of cutting tool or cutting insert, micro-structure of machined material and other known as technological parameters. By improving of these parameters, we can improve machined surface. In the machining, there is important to identify the characteristics of main product of these processes - workpiece, but also the byproduct - the chip. Size and shape of chip has impact on lifetime of cutting tools and its inappropriate form can influence the machine functionality and lifetime, too. This article deals with elimination of long chip created when machining of shaft in automotive industry and with impact of shape of chip-breaker on shape of chip in various cutting conditions based on production requirements.

  9. Hydraulically-actuated operating system for an electric circuit breaker

    Science.gov (United States)

    Barkan, Philip; Imam, Imdad

    1978-01-01

    This hydraulically-actuated operating system comprises a cylinder, a piston movable therein in an opening direction to open a circuit breaker, and an accumulator for supplying pressurized liquid to a piston-actuating space within the cylinder. A normally-closed valve between the accumulator and the actuating space is openable to allow pressurized liquid from the accumulator to flow through the valve into the actuating space to drive the piston in an opening direction. A vent is located hydraulically between the actuating space and the valve for affording communication between said actuating space and a low pressure region. Flow control means is provided for restricting leakage through said vent to a rate that prevents said leakage from substantially detracting from the development of pressure within said actuatng space during the period from initial opening of the valve to the time when said piston has moved through most of its opening stroke. Following such period and while the valve is still open, said flow control means allows effective leakage through said vent. The accumulator has a limited capacity that results in the pressure within said actuating space decaying promptly to a low value as a result of effective leakage through said vent after the piston has moved through a circuit-breaker opening stroke and while the valve is in its open state. Means is provided for resetting the valve to its closed state in response to said pressure decay in the actuating space.

  10. AFM Structural Characterization of Drinking Water Biofilm ...

    Science.gov (United States)

    Due to the complexity of mixed culture drinking water biofilm, direct visual observation under in situ conditions has been challenging. In this study, atomic force microscopy (AFM) revealed the three dimensional morphology and arrangement of drinking water relevant biofilm in air and aqueous solution. Operating parameters were optimized to improve imaging of structural details for a mature biofilm in liquid. By using a soft cantilever (0.03 N/m) and slow scan rate (0.5 Hz), biofilm and individual bacterial cell’s structural topography were resolved and continuously imaged in liquid without loss of spatial resolution or sample damage. The developed methodology will allow future in situ investigations to temporally monitor mixed culture drinking water biofilm structural changes during disinfection treatments. Due to the complexity of mixed culture drinking water biofilm, direct visual observation under in situ conditions has been challenging. In this study, atomic force microscopy (AFM) revealed the three dimensional morphology and arrangement of drinking water relevant biofilm in air and aqueous solution. Operating parameters were optimized to improve imaging of structural details for a mature biofilm in liquid. By using a soft cantilever (0.03 N/m) and slow scan rate (0.5 Hz), biofilm and individual bacterial cell’s structural topography were resolved and continuously imaged in liquid without loss of spatial resolution or sample damage. The developed methodo

  11. Perspective on the structure of liquid water

    International Nuclear Information System (INIS)

    Nilsson, A.; Pettersson, L.G.M.

    2011-01-01

    Graphical abstract: Liquid water can be described in a fluctuating inhomogeneous picture with two local structural motifs that are spatially separated. At ambient temperatures most molecules favor a closer packing than tetrahedral, with strongly distorted hydrogen bonds giving higher density (yellow), which allows the quantized librational modes to be excited and contribute to the entropy, but with enthalpically favored tetrahedrally bonded water patches appearing as fluctuations (blue), i.e. a competition between entropy and enthalpy. Upon cooling water the amount of molecules participating in tetrahedral structures and the size of the tetrahedral patches increase. Highlights: ► Two components maximizing either enthalpy (tetrahedral, low-density) or entropy (non-specific H-bonding, higher density). ► Interconvert discontinuously and ratio depends on temperature. ► Density fluctuations on 1 nm length scale. ► Increasing size in supercooled region. ► Connection to Widom line and 2nd critical point. - Abstract: We present a picture that combines discussions regarding the thermodynamic anomalies in ambient and supercooled water with recent interpretations of X-ray spectroscopy and scattering data of water in the ambient regime. At ambient temperatures most molecules favor a closer packing than tetrahedral, with strongly distorted hydrogen bonds, which allows the quantized librational modes to be excited and contribute to the entropy, but with enthalpically favored tetrahedrally bonded water patches appearing as fluctuations, i.e. a competition between entropy and enthalpy. Upon cooling water the amount of molecules participating in tetrahedral structures and the size of the tetrahedral patches increase. The two local structures are connected to the liquid–liquid critical point hypothesis in supercooled water corresponding to high density liquid and low density liquid. We will discuss the interpretation of X-ray absorption spectroscopy, X-ray emission

  12. Modeling Equity for Alternative Water Rate Structures

    Science.gov (United States)

    Griffin, R.; Mjelde, J.

    2011-12-01

    The rising popularity of increasing block rates for urban water runs counter to mainstream economic recommendations, yet decision makers in rate design forums are attracted to the notion of higher prices for larger users. Among economists, it is widely appreciated that uniform rates have stronger efficiency properties than increasing block rates, especially when volumetric prices incorporate intrinsic water value. Yet, except for regions where water market purchases have forced urban authorities to include water value in water rates, economic arguments have weakly penetrated policy. In this presentation, recent evidence will be reviewed regarding long term trends in urban rate structures while observing economic principles pertaining to these choices. The main objective is to investigate the equity of increasing block rates as contrasted to uniform rates for a representative city. Using data from four Texas cities, household water demand is established as a function of marginal price, income, weather, number of residents, and property characteristics. Two alternative rate proposals are designed on the basis of recent experiences for both water and wastewater rates. After specifying a reasonable number (~200) of diverse households populating the city and parameterizing each household's characteristics, every household's consumption selections are simulated for twelve months. This procedure is repeated for both rate systems. Monthly water and wastewater bills are also computed for each household. Most importantly, while balancing the budget of the city utility we compute the effect of switching rate structures on the welfares of households of differing types. Some of the empirical findings are as follows. Under conditions of absent water scarcity, households of opposing characters such as low versus high income do not have strong preferences regarding rate structure selection. This changes as water scarcity rises and as water's opportunity costs are allowed to

  13. Appropriate administrative structures in harnessing water resources ...

    African Journals Online (AJOL)

    Appropriate administrative structures in harnessing water resources for sustainable growth in Nigeria. Lekan Oyebande. Abstract. No Abstract. Journal of Mining and Geology Vol. 42(1) 2006: 21-30. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT.

  14. High speed hydraulically-actuated operating system for an electric circuit breaker

    Science.gov (United States)

    Iman, Imdad

    1983-06-07

    This hydraulically-actuated operating system comprises a cylinder, a piston movable therein in an opening direction to open a circuit breaker, and an accumulator for supplying pressurized liquid to a breaker-opening piston-actuating space within the cylinder. A normally-closed valve between the accumulator and the actuating space is openable to allow pressurized liquid from the accumulator to flow through the valve into the actuating space to drive the piston in an opening direction. A dashpotting mechanism operating separately from the hydraulic actuating system is provided, thereby reducing flow restriction interference with breaker opening.

  15. Decreasing emissions of a secondary lead smelter by installation of a battery breaker. Emissionsminderung einer Sekundaerbleihuette durch Integration einer Akkuschrott-Aufbereitung

    Energy Technology Data Exchange (ETDEWEB)

    Lamm, K F

    1986-11-01

    Dust and lead emissions of a secondary lead smelter mainly from the area of stockyards, handling, transport, charge preparing as well as the further treatment in rotary furnaces. A 60% decrease is obtained by compact assembling of covered battery stockyard, battery breaker and charge preparation and direct connection to the existing smelter area. The breaker itself contains a wet screen trommel and a filter press for separation of paste. The heavy-media sink-float-system has been replaced by dynamic water separation, which results in cleaner qualities of all fractions. In spite of a 100% wet separation plant, a bagfilter can be used with expected clean gas dust contents below 5 mg/m{sup 3} and below 2.5 mg Pb/m{sup 3}. Over a 2 years-period, dust and lead contents have been below 1 mg/m{sup 3}. (orig.) With 5 refs., 2 flowsheets, 10 figs.

  16. Lessons Learned "Establishing an Electrically Safe Work Condition" Specifically related to Racking Electrical Breakers

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Tommy Robert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Romero, Philbert Roland [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Garcia, Samuel Anthony [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-11-09

    During low voltage electrical equipment maintenance, a bad breaker was identified. The breaker was racked out from the substation cubicle without following the hazardous energy control process identified in the Integrated Work Document (IWD). The IWD required the substation to be in an electrically safe work condition prior to racking the breaker. Per NFPA 70E requirements, electrical equipment shall be put into an electrically safe work condition before an employee performs work on or interacts with equipment in a manner that increases the likelihood of creating an arc flash. Racking in or out a breaker on an energized bus may increase the likelihood of creating an arc flash dependent on equipment conditions. A thorough risk assessment must be performed prior to performing such a task. The risk assessment determines the risk control measures to be put in place prior to performing the work. Electrical Safety Officers (ESO) can assist in performing risk assessments and incorporating risk control measures.

  17. Analysis of fluid structural instability in water

    International Nuclear Information System (INIS)

    Piccirillo, N.

    1997-02-01

    Recent flow testing of stainless steel hardware in a high pressure/high temperature water environment produced an apparent fluid-structural instability. The source of instability was investigated by studying textbook theory and by performing NASTRAN finite element analyses. The modal analyses identified the mode that was being excited, but the flutter instability analysis showed that the design is stable if minimal structural damping is present. Therefore, it was suspected that the test hardware was the root cause of the instability. Further testing confirmed this suspicion

  18. Pengembangan Media Ice Breaker Talking Pen pada Mata Pelajaran PAI Kelas X SMAN 100 Jakarta

    Directory of Open Access Journals (Sweden)

    Ati Sulastri

    2017-07-01

    Full Text Available This study aims to find out how to develop media ice breaker talking pen and media feasibility on the subjects of PAI. The research method used is Borg and Gall development model which includes requirement analysis, validation test, and test phase. The result of this development research is ice breaker talking pen media product which consists of command card and music developed through data collection, planning, product development, and validation and testing. Based on the validation results obtained the average score of the material experts of 4.75 (very good, and from the media experts of 3.78 (good, and the results of student responses about this media amounted to 4.39 or very good category. Therefore the ice breaker talking media on the eyes of learning PAI class X is declared eligible for use with very good category. Keywords: Development Model  Study, Ice Breaker Talking Pen, PAI Abstrak Penelitian ini bertujuan untuk mengetahui cara mengembangkan media ice breaker talking pen dan kelayakan media tersebut pada mata pelajaran PAI. Metode yang digunakan adalah model pengembangan Borg dan Gall yang meliputi analisis kebutuhan, tahap validasi dan tahap uji coba. Hasil penelitian pengembangan ini adalah produk media ice breaker talking pen yang terdiri dari kartu perintah dan musik yang dikembangkan melalui tahap pengumpulan data, perencanaan, pengembangan produk, serta validasi dan uji coba. Berdasarkan pada hasil validasi didapat skor rata-rata dari ahli materi sebesar 4,75 (sangat baik, dan dari ahli media sebesar 3,78 (baik. Serta hasil dari tanggapan siswa mengenai media ini sebesar 4,39 atau kategori sangat baik. Maka dari itu media ice breaker talking pen pada mata pelajaran PAI kelas X dinyatakan layak untuk digunakan dengan kategori sangat baik. Kata Kunci : Pengembangan Model Pembelajaran, Ice Breaker Talking Pen, PAI

  19. Automatic recloser circuit breaker integrated with GSM technology for power system notification

    Science.gov (United States)

    Lada, M. Y.; Khiar, M. S. A.; Ghani, S. A.; Nawawi, M. R. M.; Rahim, N. H.; Sinar, L. O. M.

    2015-05-01

    Lightning is one type of transient faults that usually cause the circuit breaker in the distribution board trip due to overload current detection. The instant tripping condition in the circuit breakers clears the fault in the system. Unfortunately most circuit breakers system is manually operated. The power line will be effectively re-energized after the clearing fault process is finished. Auto-reclose circuit is used on the transmission line to carry out the duty of supplying quality electrical power to customers. In this project, an automatic reclose circuit breaker for low voltage usage is designed. The product description is the Auto Reclose Circuit Breaker (ARCB) will trip if the current sensor detects high current which exceeds the rated current for the miniature circuit breaker (MCB) used. Then the fault condition will be cleared automatically and return the power line to normal condition. The Global System for Mobile Communication (GSM) system will send SMS to the person in charge if the tripping occurs. If the over current occurs in three times, the system will fully trip (open circuit) and at the same time will send an SMS to the person in charge. In this project a 1 A is set as the rated current and any current exceeding a 1 A will cause the system to trip or interrupted. This system also provides an additional notification for user such as the emergency light and warning system.

  20. [Crystallographic evaluation of structural changes in water].

    Science.gov (United States)

    Farashchuk, N F; Rakhmanin, Yu A; Savostikova, O N; Telenkova, O G

    2014-01-01

    The study of the structural state of tap water that has been stored for two days in the packaging materials of various type and in different conditions, was performed with the use of crystallographic method for the investigation of liquids based on a special approach for dehydration of the drop, which is a fixed thin "slice" of the examines liquid. Most organized crystallographic pattern was shown to observe in a drop of water after treatment Bioptron lamp (content of liquid-crystal associates (LCA)--6.90 ± 0.23), and stored in a silver vessel (content LCA--6.28 ± 0.17), and the least organized, almost amorphous precipitate is formed in a drop of water stored in plastic containers (content LCA--2.92 ± 0.15%). Basing on the obtained results, it can be concluded that the crystallographic method can be used for the identification of qualitative changes occurring in liquid water under the influence of various physical factors, for the identification of the rationality of the use of hereafter sophisticated quantitative techniques.

  1. Optimal planning of series resistor to control time constant of test circuit for high-voltage AC circuit-breakers

    OpenAIRE

    Yoon-Ho Kim; Jung-Hyeon Ryu; Jin-Hwan Kim; Kern-Joong Kim

    2016-01-01

    The equivalent test circuit that can deliver both short-circuit current and recovery voltage is used to verify the performance of high-voltage circuit breakers. Most of the parameters in this circuit can be obtained by using a simple calculation or a simulation program. The ratings of the circuit breaker include rated short-circuit breaking current, rated short-circuit making current, rated operating sequence of the circuit breaker and rated short-time current. Among these ratings, the short-...

  2. The ice-breaker effect: singing mediates fast social bonding.

    Science.gov (United States)

    Pearce, Eiluned; Launay, Jacques; Dunbar, Robin I M

    2015-10-01

    It has been proposed that singing evolved to facilitate social cohesion. However, it remains unclear whether bonding arises out of properties intrinsic to singing or whether any social engagement can have a similar effect. Furthermore, previous research has used one-off singing sessions without exploring the emergence of social bonding over time. In this semi-naturalistic study, we followed newly formed singing and non-singing (crafts or creative writing) adult education classes over seven months. Participants rated their closeness to their group and their affect, and were given a proxy measure of endorphin release, before and after their class, at three timepoints (months 1, 3 and 7). We show that although singers and non-singers felt equally connected by timepoint 3, singers experienced much faster bonding: singers demonstrated a significantly greater increase in closeness at timepoint 1, but the more gradual increase shown by non-singers caught up over time. This represents the first evidence for an 'ice-breaker effect' of singing in promoting fast cohesion between unfamiliar individuals, which bypasses the need for personal knowledge of group members gained through prolonged interaction. We argue that singing may have evolved to quickly bond large human groups of relative strangers, potentially through encouraging willingness to coordinate by enhancing positive affect.

  3. Proposal for Remodeling the Sedimentation System of the CONCREPAL Material Breaker at Barranca, Costa Rica

    Directory of Open Access Journals (Sweden)

    Nazareth Arguedas-Zumbado

    2016-08-01

    Full Text Available Due to a change in environmental paradigm and the production increase, this document is a proposal for remodeling the CONCREPAL’s settler located in Barranca, Costa Rica. It is presented as an eco-efficient alternative that simultaneously enables compliance with current legislation on landfill and wastewater reuse. Initially, an environmental diagnosis of the characteristics and performance of the current sedimentation tank was made. Subsequently, the design of the proposed remodeling of the treatment system, incorporating the recirculation of treated water in the breaker material production process, was developed. Finally, a life-size settler model was created in a test environment in order to start measurements tests and determine the functionality; successfully, after all tests, positive results within the range allowed by national legislation on total suspended-solids concentration (40 ± 0.01 mg/l were obtained. Thanks to the cost-benefit and environmental management analysis, a new settler system can be implemented with positive short and long term results for the company.

  4. Structure of steam water mixture spray

    International Nuclear Information System (INIS)

    Mitsuhashi, Yuki; Mizutani, Hiroya; Sanada, Toshiyuki; Saito, Takayuki

    2008-01-01

    The flow structure of steam and water mixture spray is studied both numerically and experimentally. The velocity and pressure profiles of the single phase flow are calculated using numerical methods. Using calculated flow fields, the droplet behavior is predicted by the one-way interaction model. This numerical analysis clarifies that the droplets are still accelerated after they are sprayed from the nozzle. In the experiments, the spray of the mixture is observed by using ultra high-speed video camera, and the velocity field is measured by using PIV technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, mixing process of steam and water, and atomization process of liquid film are observed through the transparent nozzle. The high-speed photography observation reveals that the flow inside the nozzle forms the annular flow and the most of the liquid film is atomized at the nozzle outlet. Finally, the optimum method of processing mixture of steam and water is proposed. (author)

  5. Reprises textuelles dans The Dew Breaker d’Edwidge Danticat Rewriting / Reprising in Edwidge Danticat’s The Dew Breaker

    Directory of Open Access Journals (Sweden)

    Corinne Duboin

    2007-01-01

    Full Text Available In her recent novel, The Dew Breaker (2004, Haitian-American writer Edwidge Danticat weaves together the lives of her bruised Haitian characters and their torturer, a former Tonton Macoute, all in exile in the US. Seven of the nine chapters were previously published as separate short stories and have been rearranged to form a novel. The reader is then led to unravel a narrative tangle made of many threads. The disparate nature of the book, its non-linear narrative, the plurality of stories and voices, the gaps in a fragmented, elliptic text all bear witness to an alternative approach to creative writing. Like a seamstress, the novelist pieces together individual stories, connecting them as the multifarious facets of a great whole. In the wake of francophone Haitian writers (namely Jacques Roumain, the author of Masters of the Dew, and Jacques Stephen Alexis who wrote General Sun, My Brother, Edwidge Danticat fictionalizes the traumatic history of a people confronted with violence and terror and engages in a complex intertextual game. Combining ethics and aesthetics, temporal and textual memory, the novelist explores facts and, rather than giving answers, raises difficult questions. Her characters, whether victims or perpetrators, all strive to free themselves from a haunting past: is it ever possible to forgive so as to heal the pain? Can one make amends for the harm that has been done to victims who seek redress?

  6. INVESTIGATION OF MECHANICAL STRESSES IN THE DRIVE SHAFT OF MV VACUUM CIRCUIT BREAKER

    Directory of Open Access Journals (Sweden)

    E. I. Baida

    2017-03-01

    Full Text Available Introduction. In the last 10-15 years a dominant position in the market of medium voltage circuit breakers, vacuum circuit breakers have taken in which as an actuator mono- or bistable actuators with permanent magnets are used. Such circuit breakers are characterized by simplicity of design, high reliability, require preventive maintenance for many years. Development, research and improvement of vacuum circuit breakers are carried out at the Department for Electrical Apparatus, National Technical University «Kharkiv Polytechnic Institute». While working on the circuit breakers, developers have to deal with two related objectives – electrical and mechanical. This paper considers the solution of one of these problems – calculation of mechanical forces in the drive shaft of the vacuum circuit breaker in static and dynamic modes. This work was preceded by the failure of the results of measurements of the prototype circuit breakers’ contacts. Measurements have shown that these values do not match the expected values (there were less than the value of 0.8 to 1 mm. The assumption about the reasons for this discrepancy needed to be detailed checked. The results of the work done are presented in this paper. Purpose. Investigation of static and dynamic mechanical stresses and strains in the drive shaft of the vacuum circuit breaker mechanism to determine its characteristics and material selection. Methods. The investigation of mechanical processes is performed by the finite element method in the COMSOL software package. Results. We obtain the static and dynamic characteristics of the circuit breaker drive shaft: deformations, reaction forces, stresses. These characteristics made it possible to determine the actual course of the contacts, select shaft material and calculate the forces acting on the bearings. Conclusions. It is shown that the contact velocity and contact pressure are different from the theoretical value due to the deformation of the

  7. Research on burnout fault of moulded case circuit breaker based on finite element simulation

    Science.gov (United States)

    Xue, Yang; Chang, Shuai; Zhang, Penghe; Xu, Yinghui; Peng, Chuning; Shi, Erwei

    2017-09-01

    In the failure event of molded case circuit breaker, overheating of the molded case near the wiring terminal has a very important proportion. The burnout fault has become an important factor restricting the development of molded case circuit breaker. This paper uses the finite element simulation software to establish the model of molded case circuit breaker by coupling multi-physics field. This model can simulate the operation and study the law of the temperature distribution. The simulation results show that the temperature near the wiring terminal, especially the incoming side of the live wire, of the molded case circuit breaker is much higher than that of the other areas. The steady-state and transient simulation results show that the temperature at the wiring terminals is abnormally increased by increasing the contact resistance of the wiring terminals. This is consistent with the frequent occurrence of burnout of the molded case in this area. Therefore, this paper holds that the burnout failure of the molded case circuit breaker is mainly caused by the abnormal increase of the contact resistance of the wiring terminal.

  8. Ohmic heating coil power supply using thyristor circuit breaker in a thermonuclear fusion device

    International Nuclear Information System (INIS)

    Tani, Keiji; Shimada, Ryuichi; Tamura, Sanae; Yabuno, Kohei; Koseki, Shoichiro.

    1982-01-01

    In a large scale Tokamak thermonuclear fusion device such as the critical plasma testing facility (JT60) presently under construction, mechanical breakers such as vacuum and air breakers are mostly used for interrupting DC heavy current which is supplied to the ohmic heating coils of inductive energy accumulation method. The practical use of the DC breakers employing thyristors has just been started because the history of thyristor development is short and thristors are still expensive, in spite of the advantages. In this paper, the circuit is investigated in which the excellent high speed controllability of thyristors is fully utilized, while the economy is taken into accout, and the experiment carried out with a unit model is described. It was found that a thyristor switch, which was constructed by connecting the high speed thyristors of peak off-state voltage rating 2,000 V and mean current rating 500 A in direct parallel, was able to interrupt 12.7 kA current in the power supply circuit of ohmic heating coils developed this time. In addition, the switch configuration was able to be greatly simplified. When the multistage raising of plasma current is required, the raise can be performed with a single thyristor breaker because it can make high speed control. Therefore, the capacity of the breaker can be doubly and drastically reduced. Also, if current unbalance might occur between thyristor switch units, it gives no problem since the time of reverse voltage after current interruption dispersed smaller as current increased. (Wakatsuki, Y.)

  9. Trend analysis of breaker events at United States nuclear power plants

    International Nuclear Information System (INIS)

    Shimada, Hiroki

    2006-01-01

    From events in overseas nuclear power plants recorded in the nuclear information detabase of Institute of Nuclear Safety System, Inc. (INSS), the number of events of electrical systems during the four years from 2002 to 2005 was extracted and the trend was analyzed. The results showed that breaker events were the largest in number in all years, and almost all them occurred in the US. The breaker events that occurred in US nuclear power plants in 2005 were analyzed by classifying them by cause of failure and effect on the plant, and by comparing the number of occurrences with that in Japan. As a result, the main cause of many of the breaker events was improper maintenance due to poor arrangement of maintenance manuals and human error, as well as aging degradation, they can be estimated to have been caused by insufficient maintenance control and inspection. The number of breaker failures per plant per year in our country was lower than that in the US by an order of magnitude, and there were no failures that led to a plant trip or power reduction. These facts suggest that our country's maintenance contents of breaker are advantage. (author)

  10. Electrical, Magnetic, Thermal Modeling and Analysis of a 5000A Solid-State Switch Module and Its Application as a DC Circuit Breaker

    OpenAIRE

    Zhou, Xigen

    2005-01-01

    This dissertation presents a systematic design and demonstration of a novel solid-state DC circuit breaker. The mechanical circuit breaker is widely used in power systems to protect industrial equipment during fault or abnormal conditions. Compared with the slow and high-maintenance mechanical circuit breaker, the solid-state circuit breaker is capable of high-speed interruption of high currents without generating an arc, hence it is maintenance-free. Both the switch and the tripping unit ...

  11. Experiment and CFD simulation of exhaust tube in highvoltage circuit breaker

    Directory of Open Access Journals (Sweden)

    Ye Xiangyang

    2018-01-01

    Full Text Available In a high-voltage circuit breaker, the exhaust tube connects the arc zone with the exhaust volume. During the arc interruption process, the exhaust tube transports the hot gas from the arc interruption zone to the exhaust volume through its distributed holes. The design of a high performance exhaust tube in the circuit breaker development aims for well controlled hot gas evacuation mass flow and pressure waves. In this paper, the exhaust tube behaviour is investigated using Computational Fluid Dynamics (CFD. To verify the CFD simulation, a basic experimental study with pressure measurements at different positions of the exhaust tube is performed. Further, the design parameters influencing the exhaust tube behaviour and circuit breaker performance are investigated and discussed.

  12. Optimizing the switching time for 400 kV SF6 circuit breakers

    Science.gov (United States)

    Ciulica, D.

    2018-01-01

    This paper presents real-time voltage and current analysis for optimizing the wave switching point of the circuit breaker SF6. Circuit Breaker plays an important role in power systems. It provides protection for equipment in embedded stations in transport networks. SF6 Circuit Breaker is very important equipment in Power Systems, which is used for up to 400 kV due to its excellent performance. The controlled switching is used to eliminate transient modes and electrodynamic and dielectric charges in the network at manual switching of capacitor, shunt reactors and power transformers. These effects reduce the reliability and lifetime of the equipment installed on the network, or may lead to erroneous protection.

  13. Research on current sharing of paralleled IGBTs in different DC breaker circuit topologies

    Directory of Open Access Journals (Sweden)

    Chen Ying

    2016-01-01

    Full Text Available IGBT modules used in series and parallel to satisfy the requirement in high-power DC circuit breakers are often prone to large-current destruction due to current unbalance between paralleled IGBTs. It is of great importance to identify the current unbalance causes and to find a method optimizing the current sharing of paralleled IGBTs. In this paper the current-sharing influencing factors are discussed and verified by simulation. Two possible circuit topologies used in DC circuit breakers are proposed and simulated to see their performance in current sharing. The results show that one of them can provide us with a simple and effective method to achieve good current balancing in the DC circuit breaker application.

  14. Shock wave focusing in water inside convergent structures

    Directory of Open Access Journals (Sweden)

    C Wang

    2016-09-01

    Full Text Available Experiments on shock focusing in water-filled convergent structures have been performed. A shock wave in water is generated by means of a projectile, launched from a gas gun, which impacts a water-filled convergent structure. Two types of structures have been tested; a bulk material and a thin shell structure. The geometric shape of the convergent structures is given by a logarithmic spiral, and this particular shape is chosen because it maximizes the amount of energy reaching the focal region. High-speed schlieren photography is used to visualize the shock dynamics during the focusing event. Results show that the fluid-structure interaction between the thin shell structure and the shock wave in the water is different from that of a bulk structure; multiple reflections of the shock wave inside the thin shell are reflected back into the water, thus creating a wave train, which is not observed for shock focusing in a bulk material.

  15. Water stale and structure analysis of Konjac irradiation copolymer

    International Nuclear Information System (INIS)

    Geng Shengrong; Xia Hezhou; Chen Xueling; Ye Lixiu; Hua Yuejin

    2011-01-01

    To study the absorption performance of Konjac-AA copolymer prepared by using irradiation, the water absorption capacity, sorbent speed and water keeping ability were determined, DSC and TEM analysis were used to investigate the water content and structure characters. The results showed that the largest water absorption speed was 16 g · -1 · min -1 at room temperature, and the largest water absorption was 400 times within 60 minutes. The water absorption was affected by granularity, temperature, ion content and ion type, especially the ion type. The water keeping ability was affected by temperature and time, which was up to 35% of absorbed water when the fully water absorbed copolymer was kept under room temperature for 15 d. The free and bounder water content which could be assimilated by the plants was 99.617%. The water stale copolymer has a three-dimensional spiral structure. (authors)

  16. Structure of water and the thermodynamics of aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Nemethy, G.

    1970-10-26

    This report represents the summary of a series of lectures held at the Istituto Superiore di Sanita, Laboratori di Fisica, from 18 September to 26 October 1970. The topics discussed were: Intermolecular forces, the individual water molecule and the hydrogen bond, the structures of the solid phases of water, experimental information on the strucuture of liquid water, theoretical models of water structure, experimental properties and theoretical models of aqueous solutions of nonpolar solutes, polar solutes, and electrolytes, the conformational stability of biological macromolecules.

  17. Polyamide membranes with nanoscale Turing structures for water purification

    Science.gov (United States)

    Tan, Zhe; Chen, Shengfu; Peng, Xinsheng; Zhang, Lin; Gao, Congjie

    2018-05-01

    The emergence of Turing structures is of fundamental importance, and designing these structures and developing their applications have practical effects in chemistry and biology. We use a facile route based on interfacial polymerization to generate Turing-type polyamide membranes for water purification. Manipulation of shapes by control of reaction conditions enabled the creation of membranes with bubble or tube structures. These membranes exhibit excellent water-salt separation performance that surpasses the upper-bound line of traditional desalination membranes. Furthermore, we show the existence of high water permeability sites in the Turing structures, where water transport through the membranes is enhanced.

  18. Formation and development of a breaker bar under regular waves. Part 2: Sediment transport and morphology

    DEFF Research Database (Denmark)

    Jacobsen, Niels Gjøl; Fredsøe, Jørgen

    2014-01-01

    In Part 2 of this work, the hydrodynamic model described in Part 1 is applied for the simulation of sediment transport and the associated morphological development of breaker bars. The sediment description is split into bed load and suspended load, and like the hydrodynamics the sediment transport...

  19. Vacuum circuit breaker postarc current modelling based on the theory of Langmuir probes

    NARCIS (Netherlands)

    Lanen, van E.P.A.; Smeets, R.; Popov, M.; Sluis, van der L.

    2007-01-01

    High-resolution measurements on the postarc current in vacuum circuit breakers (VCBs) reveal a period, immediately following current-zero, in which the voltage remains practically zero. The most widely used model for simulating the interaction between the postarc current with the electrical circuit

  20. Current-zero measurements of vacuum circuit breakers interrupting short-line faults

    NARCIS (Netherlands)

    Smeets, R.P.P.; Linden, van der W.A.

    2003-01-01

    Current zero measurements are performed during short-line fault interruption tests of vacuum circuit breakers. This switching cycle is characterized by a very steep transient recovery voltage. High-resolution measurements of near current-zero arc current and voltage were carried out. Various

  1. Effect of magnetic attachment with stress breaker on lateral stress to abutment tooth under overdenture.

    Science.gov (United States)

    Gonda, T; Ikebe, K; Ono, T; Nokubi, T

    2004-10-01

    Recently, a newly developed magnetic attachment with stress breaker was used in retentive components in overdentures. Excessive lateral stress has a more harmful effect on natural teeth than axial stress, and the magnetic attachment with stress breaker is expected to reduce lateral forces on abutment teeth and protect it teeth from excessive stress. However, the properties of this retainer have not yet been determined experimentally. This study compares the lateral forces on abutment teeth for three retainers under loading on the denture base in a model study. A mandibular simulation model is constructed to measure lateral stress. Three types of retentive devices are attached to the canine root. These devices include the conventional root coping, the conventional magnetic attachment and the new magnetic attachment with stress breaker. For each retentive device, load is generated on the occlusal table of the model overdenture, and the lateral stress on the canine root and the displacement of the overdenture measured. The magnetic attachment with stress breaker does not displace the denture and exhibits lower lateral stress in the canine root than conventional root coping and magnetic attachments.

  2. A study of plunging breaker mechanics by PIV measurements and a Navier-Stokes solver

    DEFF Research Database (Denmark)

    Emarat, Narumon; Forehand, David I. M.; Christensen, Erik Damgaard

    2000-01-01

    The mechanics of a surf-zone plunging breaker are studied from Particle Image Velocimetry (PIV) measurements and a numerical model based on the Navier-Stokes equations, using a Volume of Fluid (VOF) method. An additional numerical model using a Boundary-Integral Method (BIM) is also used in order...

  3. Transient studies in large offshore wind farms, taking into account network/circuit breaker interaction

    DEFF Research Database (Denmark)

    Glasdam, Jacob Bærholm; Bak, Claus Leth; Hjerrild, Jesper

    2011-01-01

    to ensure reliable switching operations. Transient measurement results in an OWF are compared with simulation results in PSCAD EMTDC and DigSILENT Power Factory, where a user-defined model of the vacuum circuit breaker (VCB) is included, capable of simulating multiple prestrikes during the closing operation...... the simulation results, whereas little improvement is found in DigSILENT....

  4. Numerical simulation for arc-plasma dynamics during contact opening process in electrical circuit-breakers

    International Nuclear Information System (INIS)

    Gupta, D N; Srinivas, D; Patil, G N; Kale, S S; Potnis, S B

    2010-01-01

    The high-energy, high-current thermal plasma that develops between electric contacts in a gas circuit-breaker during circuit interruption is an important phenomenon in the power transmission industry. The high temperature and pressure arc dissipates the tremendous amount of energy generated by the fault current. Simultaneously, this energy has to be transferred away from the contacts to build the dielectric strength level of the circuit-breaker. In order to interrupt the current, the arc must be weakened and finally extinguished. We model these phenomena by using a computer software code based on the solution of the unsteady Euler equations of gas dynamics. We consider the equations of fluid flows. These equations are solved numerically in complex circuit breaker geometries using a finite-volume method. The domain is initially filled with SF 6 gas. We begin our simulations from cold mode, where the fault current is not present (hence no arc). An axis-symmetric geometry of a 145 kV gas circuit-breaker is considered to study the pressure, density, and temperature profile during contact opening process.

  5. Can we describe graphene confined water structures as overlapping of approaching graphene-water interfacial structures?

    Energy Technology Data Exchange (ETDEWEB)

    Chialvo, Ariel A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Vlcek, Lukas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-03-21

    We investigate the microscopic mechanisms of the overlap of interfacial structures in confined fluids and attempt to answer the question whether the confined structures can be predicted from the original density profiles of individual solid-fluid interfaces. For that purpose we perform (globally) isobaricisothermal (locally, grand canonical) molecular dynamics simulations to extract not only the axial distribution functions of the water-sites for the uncoupled graphene-water interfaces, but also those corresponding to the confined aqueous environments over the interplate range 8 ≤ h(Å) ≤ 28 typically at ambient conditions. We have tested two (i.e., an arithmetic and a geometric) superposition approximations for the singlet density of confined water between flat graphene plates, as well as for a combination of flat and corrugated graphene plates. The outcome of this study suggests that the answer to the title’s question is a “yes”, provided that the interplate distance h is large enough to avoid fluid geometric packing frustration.

  6. Structural and functional significance of water permeation through cotransporters

    DEFF Research Database (Denmark)

    Zeuthen, Thomas; Gorraitz, Edurne; Her, Ka

    2016-01-01

    Membrane transporters, in addition to their major role as specific carriers for ions and small molecules, can also behave as water channels. However, neither the location of the water pathway in the protein nor their functional importance is known. Here, we map the pathway for water and urea...... through the intestinal sodium/glucose cotransporter SGLT1. Molecular dynamics simulations using the atomic structure of the bacterial transporter vSGLT suggest that water permeates the same path as Na+ and sugar. On a structural model of SGLT1, based on the homology structure of vSGLT, we identified...... to be due to alterations in steric hindrance to water and urea, and/or changes in protein folding caused by mismatching of side chains in the water pathway. Water permeation through SGLT1 and other transporters bears directly on the structural mechanism for the transport of polar solutes through...

  7. Metal-clad switchgear with large capacity vacuum circuit breaker in two-tier arrangement for nuclear power plants

    International Nuclear Information System (INIS)

    Yoshikawa, Isao; Watanabe, Hideo; Sugitani, Shinji

    1982-01-01

    Accompanying the increase of main machinery capacity in nuclear power stations, the short-circuit capacity for 6.9 kV in-house auxiliary machinery circuit has increased, and a 63 kA circuit breaker has become necessary. Although magnetic breakers have been used as large capacity breakers so far, vacuum breakers which are more suitable for the recent environmental conditions of power stations have become employed. Hitachi Ltd. has developed the metal-clad switchboard with vacuum breakers of 7.2 kV, 1,200 to 3,000 A, and breaking current of 63 kA in two-tier arrangement. The main features of this breaker are small size, light weight, long life, labour-saving in maintenance and inspection, simple construction, easy handling, high reliability and safety. In addition, in this paper, the construction of the breaker and switchboard, aseismic property, and test results are described. The tests include the withstand voltage test, elevated temperature test, short period current test, short-circuit test, low current breaking test, continuous on-off test, on-off surge combination test and short-circuit breaking test under the condition of vacuum failure in one phase. The aseismic property is guaranteed by analyzing the vibration characteristics and the strength using computer-aided finite element method so that the performance required is satisfied. (Wakatsuki, Y.)

  8. Water polygons in high-resolution protein crystal structures.

    Science.gov (United States)

    Lee, Jonas; Kim, Sung-Hou

    2009-07-01

    We have analyzed the interstitial water (ISW) structures in 1500 protein crystal structures deposited in the Protein Data Bank that have greater than 1.5 A resolution with less than 90% sequence similarity with each other. We observed varieties of polygonal water structures composed of three to eight water molecules. These polygons may represent the time- and space-averaged structures of "stable" water oligomers present in liquid water, and their presence as well as relative population may be relevant in understanding physical properties of liquid water at a given temperature. On an average, 13% of ISWs are localized enough to be visible by X-ray diffraction. Of those, averages of 78% are water molecules in the first water layer on the protein surface. Of the localized ISWs beyond the first layer, almost half of them form water polygons such as trigons, tetragons, as well as expected pentagons, hexagons, higher polygons, partial dodecahedrons, and disordered networks. Most of the octagons and nanogons are formed by fusion of smaller polygons. The trigons are most commonly observed. We suggest that our observation provides an experimental basis for including these water polygon structures in correlating and predicting various water properties in liquid state.

  9. Structure and stability of spiro-cyclic water clusters

    Indian Academy of Sciences (India)

    Administrator

    Abstract. The structure and stability of spiro-cyclic water clusters containing up to 32 water molecules have been ... due to its importance in various real life systems. 1–8. High level ... It is well-known from the crystal structure data- base that the ...

  10. Structural transition in alcohol–water binary mixtures: A ...

    Indian Academy of Sciences (India)

    WINTEC

    Abstract. The strengthening of the hydrogen bonding (H-bond) network as well as transition from the tetrahedral-like water network to the zigzag chain structure of alcohol upon increasing the alcohol con- centration in ethanol–water and tertiary butanol (TBA) – water mixtures have been studied by using both steady state ...

  11. Enhanced water desalination performance through hierarchically-structured ceramic membranes

    NARCIS (Netherlands)

    Liu, Tong; Lei, Libin; Gu, Jianqiang; Wang, Yao; Winnubst, Louis; Chen, Chusheng; Ye, Chunsong; Chen, Fanglin

    2017-01-01

    Developments of membrane water desalination are impeded by low water vapor flux across the membrane. We present an innovative membrane design to significantly enhance the water vapor flux. A bilayer zirconia-based membrane with a thick hierarchically-structured support and a thin functional layer is

  12. Structure-function relationships in sapwood water transport and storage.

    Science.gov (United States)

    Barbara L. Gartner; Frederick C. Meinzer

    2005-01-01

    Primary production by plants requires the loss of substantial quantities of water when the stomata are open for carbon assimilation. The delivery of that water to the leaves occurs through the xylem. The structure, condition, and quantity of the xylem control not only the transport efficiency but also the release of water from storage. For example, if there is high...

  13. Cellular Automata Models of Traffic Behavior in Presence of Speed Breaking Structures

    International Nuclear Information System (INIS)

    Ramachandran, Parthasarathy

    2009-01-01

    In this article, we study traffic flow in the presence of speed breaking structures. The speed breakers are typically used to reduce the local speed of vehicles near certain institutions such as schools and hospitals. Through a cellular automata model we study the impact of such structures on global traffic characteristics. The simulation results indicate that the presence of speed breakers could reduce the global flow under moderate global densities. However, under low and high global density traffic regime the presence of speed breakers does not have an impact on the global flow. Further the speed limit enforced by the speed breaker creates a phase distinction. For a given global density and slowdown probability, as the speed limit enforced by the speed breaker increases, the traffic moves from the reduced flow phase to maximum flow phase. This underlines the importance of proper design of these structures to avoid undesired flow restrictions. (general)

  14. Approaching the Processes in the Generator Circuit Breaker at Disconnection through Sustainability Concepts

    Directory of Open Access Journals (Sweden)

    Carmen A. Bulucea

    2013-03-01

    Full Text Available Nowadays, the electric connection circuits of power plants (based on fossil fuels as well as renewable sources entail generator circuit-breakers (GCBs at the generator terminals, since the presence of that electric equipment offers many advantages related to the sustainability of a power plant. In an alternating current (a.c. circuit the interruption of a short circuit is performed by the circuit-breaker at the natural passing through zero of the short-circuit current. During the current interruption, an electric arc is generated between the opened contacts of the circuit-breaker. This arc must be cooled and extinguished in a controlled way. Since the synchronous generator stator can flow via highly asymmetrical short-circuit currents, the phenomena which occur in the case of short-circuit currents interruption determine the main stresses of the generator circuit-breaker; the current interruption requirements of a GCB are significantly higher than for the distribution network circuit breakers. For shedding light on the proper moment when the generator circuit-breaker must operate, using the space phasor of the short-circuit currents, the time expression to the first zero passing of the short-circuit current is determined. Here, the manner is investigated in which various factors influence the delay of the zero passing of the short-circuit current. It is shown that the delay time is influenced by the synchronous machine parameters and by the load conditions which precede the short-circuit. Numerical simulations were conducted of the asymmetrical currents in the case of the sudden three-phase short circuit at the terminals of synchronous generators. Further in this study it is emphasized that although the phenomena produced in the electric arc at the terminals of the circuit-breaker are complicated and not completely explained, the concept of exergy is useful in understanding the physical phenomena. The article points out that just after the short

  15. NRC Information No. 89-86: Type HK circuit breakers missing close latch anti-shock springs

    International Nuclear Information System (INIS)

    Rossi, C.E.

    1992-01-01

    During the recent refueling outage at Fermi Unit 2, the licensee inspected both safety-related and non-safety-related Type HK circuit breakers. The close latch anti-shock springs were observed to be missing in approximately 40 safety-related Type HK circuit breakers that had been manufactured outside of the previously identified timeframes. (The identified circuit breakers were manufactured in 1974.) Thus, the timeframes previously identified by the manufacturer (prior to 1973 and from June 1975 to June 1977) may not be totally inclusive. In addition, because of changes in corporate name, mergers, etc., Type HK circuit breakers may indicate manufacture by ITE, ITE Imperial, Gould, Brown Boveri, or a combination thereof. The current name of the manufacturer is ASEA Brown Boveri. Recipients may need to be cognizant of this when determining whether they utilize potentially affected equipment

  16. Water's Interfacial Hydrogen Bonding Structure Reveals the Effective Strength of Surface-Water Interactions.

    Science.gov (United States)

    Shin, Sucheol; Willard, Adam P

    2018-06-05

    We combine all-atom molecular dynamics simulations with a mean field model of interfacial hydrogen bonding to analyze the effect of surface-water interactions on the structural and energetic properties of the liquid water interface. We show that the molecular structure of water at a weakly interacting ( i.e., hydrophobic) surface is resistant to change unless the strength of surface-water interactions are above a certain threshold. We find that below this threshold water's interfacial structure is homogeneous and insensitive to the details of the disordered surface, however, above this threshold water's interfacial structure is heterogeneous. Despite this heterogeneity, we demonstrate that the equilibrium distribution of molecular orientations can be used to quantify the energetic component of the surface-water interactions that contribute specifically to modifying the interfacial hydrogen bonding network. We identify this specific energetic component as a new measure of hydrophilicity, which we refer to as the intrinsic hydropathy.

  17. Ground water work breakdown structure dictionary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-04-01

    This report contains the activities that are necessary to assess in ground water remediation as specified in the UMTRA Project. These activities include the following: site characterization; remedial action compliance and design documentation; environment, health, and safety program; technology assessment; property access and acquisition activities; site remedial actions; long term surveillance and licensing; and technical and management support.

  18. Ground water work breakdown structure dictionary

    International Nuclear Information System (INIS)

    1995-04-01

    This report contains the activities that are necessary to assess in ground water remediation as specified in the UMTRA Project. These activities include the following: site characterization; remedial action compliance and design documentation; environment, health, and safety program; technology assessment; property access and acquisition activities; site remedial actions; long term surveillance and licensing; and technical and management support

  19. Properties of L-ascorbic acid in water and binary aqueous mixtures of D-glucose and D-fructose at different temperatures

    Science.gov (United States)

    Sharma, Ravi; Thakur, R. C.; Sani, Balwinder; Kumar, Harsh

    2017-12-01

    Using density and sound velocity partial molar volumes, partial molar adiabatic compressibilities, partial molar expansibilities and structure of L-ascorbic acid have been determined in water and aqueous mixtures of D-glucose and D-fructose at different concentrations and temperatures. Masson's equation was used to analyze the measured data. The obtained parameters have been interpreted in terms of solute-solute and solute-solvent interactions. It is found that the L-ascorbic acid acts as structure breaker in water as well in binary studied mixtures.

  20. Solubilities of boric acid in heavy water

    International Nuclear Information System (INIS)

    Nakai, Shigetsugu; Aoi, Hideki; Hayashi, Ken-ichi; Katoh, Taizo; Watanabe, Takashi.

    1988-01-01

    A gravimetric analysis using meta-boric acid (HBO 2 or DBO 2 ) as a weighing form has been developed for solubility measurement. The method gave satisfactory results in preliminary measurement of solubilities of boric acid in light water. By using this method, the solubilities of 10 B enriched D 3 BO 3 in heavy water were measured. The results are as follows; 2.67 (7deg C), 3.52 (15deg C), 5.70 (30deg C), 8.87 (50deg C) and 12.92 (70deg C) w/o, respectively. These values are about 10% lower than those in light water. Thermodynamical consideration based on the data shows that boric acid is the water structure breaker. (author)

  1. Effect of sprinkler structure on water distribution uniformity

    International Nuclear Information System (INIS)

    Xu, M; Li, H; Chen, C; Tu, Q; Liu, J P

    2012-01-01

    Structures of sprinklers play important roles in the uniformity of water distribution. The advances and achievements to improve the distribution uniformity through the innovation in the sprinkler structures at home and abroad were presented in details. Analyses showed that three types of structure can ameliorate the water distribution efficiently. First, novel nozzle structures were applied, including the application of non-circle nozzle and special spread nozzles. Second, new structures of flow channel were used. Third, assistant device was added so as to improve the uneven water distribution, such as an assistant stream interrupter, pressure or flow rate regulator and so on. Compared to domestic sprinklers, sprinklers produced abroad have novel and special structures with better hydraulic performance. Basic theoretical researches should be strengthened and new materials, new manufacturing processes and new technique should be applied. Then new kinds of sprinkler will be produced and the hydraulic performance of sprinklers will be promoted to a higher level.

  2. Test model of the fast thyristor circuit breaker, for TORE SUPRA

    International Nuclear Information System (INIS)

    Bareyt, B.; Leloup, C.; Rijnoudt, E.

    1984-01-01

    The tokamak TORE SUPRA, permits, owing to the toroidal superconducting coils and to the poloidal field system performances, long discharges (30 s and more), for a plasma current of typically 2 MA. The poloidal field system uses the magnetic energy initially stored, for the ignition and the fast rise of the plasma current, by forcing the primary current to flow through a resistor after breaking the main rectifier current by a fast thyristor circuit breaker. In order to test the technical capabilities of such a breaker system made of fast thyristors, in series and in parallel, after a single thyristor test model T1 the series arrangement was studied on a 24 thyristor test model T2 and the parallel arrangement problems, led the manufacturer CGEE Alsthom, to build a new test model T3. (author)

  3. Effect of Circuit Breaker Shunt Resistance on Chaotic Ferroresonance in Voltage Transformer

    Directory of Open Access Journals (Sweden)

    RADMANESH, H.

    2010-08-01

    Full Text Available Ferroresonance or nonlinear resonance is a complex electrical phenomenon, which may cause over voltages and over currents in the electrical power system which endangers the system reliability and continuous safe operating. This paper studies the effect of circuit breaker shunt resistance on the control of chaotic ferroresonance in a voltage transformer. It is expected that this resistance generally can cause ferroresonance dropout. For confirmation this aspect Simulation has been done on a one phase voltage transformer rated 100VA, 275kV. The magnetization characteristic of the transformer is modeled by a single-value two-term polynomial with q=7. The simulation results reveal that considering the shunt resistance on the circuit breaker, exhibits a great mitigating effect on ferroresonance over voltages. Significant effect on the onset of chaos, the range of parameter values that may lead to chaos along with ferroresonance voltages has been obtained and presented.

  4. Structural properties of water around uncharged and charged carbon nanotubes

    International Nuclear Information System (INIS)

    Dezfoli, Amir Reza Ansari; Mehrabian, Mozaffar Ali; Rafsanjani, Hassan Hashemipour

    2013-01-01

    Studying the structural properties of water molecules around the carbon nanotubes is very important in a wide variety of carbon nanotubes applications. We studied the number of hydrogen bonds, oxygen and hydrogen density distributions, and water orientation around carbon nanotubes. The water density distribution for all carbon nanotubes was observed to have the same feature. In water-carbon nanotubes interface, a high-density region of water molecules exists around carbon nanotubes. The results reveal that the water orientation around carbon nanotubes is roughly dependent on carbon nanotubes surface charge. The water molecules in close distances to carbon nanotubes were found to make an HOH plane nearly perpendicular to the water-carbon nanotubes interface for carbon nanotubes with negative surface charge. For uncharged carbon nanotubes and carbon nanotubes with positive surface charge, the HOH plane was in tangential orientation with water-carbon nanotubes interface. There was also a significant reduction in hydrogen bond of water region around carbon nanotubes as compared with hydrogen bond in bulk water. This reduction was very obvious for carbon nanotubes with positive surface charge. In addition, the calculation of dynamic properties of water molecules in water-CNT interface revealed that there is a direct relation between the number of Hbonds and self-diffusion coefficient of water molecules

  5. Modeling of soil-water-structure interaction

    DEFF Research Database (Denmark)

    Tang, Tian

    as the developed nonlinear soil displacements and stresses under monotonic and cyclic loading. With the FVM nonlinear coupled soil models as a basis, multiphysics modeling of wave-seabed-structure interaction is carried out. The computations are done in an open source code environment, OpenFOAM, where FVM models...

  6. Password Based Distribution Panel and Circuit Breaker Operation for the Safety of Lineman during Maintenance Work

    OpenAIRE

    Hudedmani, Mallikarjun G; Ummannanavar, Nitin; Mudaliar, Mani Dheeraj; Sooji, Chandana; Bogar, Mala

    2017-01-01

    Security is the prime concern in our day to day life while performing any activity. In the current scenario, accidental death of lineman is often read and evidenced. In this direction, a safety measure to safe guard the operator is found very necessary looking into the present working style. The electric lineman safety system is designed to control the control panel doors and circuit breaker by using a password for the safety. Critical electrical accidents to lineman are on the rise during el...

  7. Ballplayer or barrier breaker? Branding through the seven statues of Jackie Robinson

    OpenAIRE

    Stride, C.; Thomas, F.; Smith, M.M.

    2014-01-01

    Jackie Robinson is the baseball player most frequently depicted by a public statue within the USA, a ubiquity explained by his unique position as barrier breaker of the Major League colour bar. Utilising a detailed inspection of statue designs, locations and inscriptions, and comparisons with wider baseball statuary, Robinson's monuments reveal a distinctive set of cultural projections. These are commemorations distinguished by their age, location away from MLB ballparks, lack of action poses...

  8. Detusking fence-breaker elephants as an approach in human-elephant conflict mitigation.

    Science.gov (United States)

    Mutinda, Matthew; Chenge, Geoffrey; Gakuya, Francis; Otiende, Moses; Omondi, Patrick; Kasiki, Samuel; Soriguer, Ramón C; Alasaad, Samer

    2014-01-01

    Human-elephant conflict (HEC) is a recurring problem that appears wherever the range of elephants and humans overlap. Different methods including the use of electric fences are used worldwide to mitigate this conflict. Nonetheless, elephants learn quickly that their tusks do not conduct electricity and use them to break down fences (fence-breakers). In Lewa Wildlife Conservancy, Kenya, destructive elephants (Loxodonta africana) were monitored between 2010 and 2013. The fence-breaking rate reached four incidents (fence-breaking) per elephant per 100 days. Ten bull males and 57 females were identified as fence-breakers. The bulls were involved in 85.07% and the females in 14.93% of incidents. The Kenya Wildlife Service approved detusking (partial cutting of tusks) in four of the 10 fence-breakers as a way of preventing them from breaking down fences, thereby mitigating HEC in the Conservancy. The result of the detusking was a drastic six-fold reduction in damage to fences (range: 1.67 to 14.5 times less fence-breaking) by the four worst fence-breaker elephants, because with trimmed tusks elephants lack the tools to break down fences. Detusking could not totally eliminate fence destruction because, despite lacking their tools, elephants can still destroy fences using their heads, bodies and trunks, albeit less effectively. On the other hand, apart from inherent aesthetic considerations, the detusking of elephants may have certain negative effects on factors such as elephants' social hierarchies, breeding, mate selection and their access to essential minerals and food. Elephant detusking seems to be effective in drastically reducing fence-breaking incidents, nonetheless its negative effects on behaviour, access to food and its aesthetical consequences still need to be further studied and investigated.

  9. Detusking fence-breaker elephants as an approach in human-elephant conflict mitigation.

    Directory of Open Access Journals (Sweden)

    Matthew Mutinda

    Full Text Available Human-elephant conflict (HEC is a recurring problem that appears wherever the range of elephants and humans overlap. Different methods including the use of electric fences are used worldwide to mitigate this conflict. Nonetheless, elephants learn quickly that their tusks do not conduct electricity and use them to break down fences (fence-breakers.In Lewa Wildlife Conservancy, Kenya, destructive elephants (Loxodonta africana were monitored between 2010 and 2013. The fence-breaking rate reached four incidents (fence-breaking per elephant per 100 days. Ten bull males and 57 females were identified as fence-breakers. The bulls were involved in 85.07% and the females in 14.93% of incidents. The Kenya Wildlife Service approved detusking (partial cutting of tusks in four of the 10 fence-breakers as a way of preventing them from breaking down fences, thereby mitigating HEC in the Conservancy. The result of the detusking was a drastic six-fold reduction in damage to fences (range: 1.67 to 14.5 times less fence-breaking by the four worst fence-breaker elephants, because with trimmed tusks elephants lack the tools to break down fences. Detusking could not totally eliminate fence destruction because, despite lacking their tools, elephants can still destroy fences using their heads, bodies and trunks, albeit less effectively. On the other hand, apart from inherent aesthetic considerations, the detusking of elephants may have certain negative effects on factors such as elephants' social hierarchies, breeding, mate selection and their access to essential minerals and food.Elephant detusking seems to be effective in drastically reducing fence-breaking incidents, nonetheless its negative effects on behaviour, access to food and its aesthetical consequences still need to be further studied and investigated.

  10. Sistem Proteksi Arus Bocor Menggunakan Earth Leakage Circuit Breaker Berbasis Arduino

    OpenAIRE

    Syukriyadin, Syukriyadin

    2016-01-01

    Touching a live part of electrical equipment either intentionally or unintentionally can cause an electric shock. The touch can occur directly or indirectly and results in the flow of electric current through the human body to the ground. This electric current is known as the leakage current and can have fatal effects on the human body such as burns, cramps, faint and death. This paper aims to design a prototype protection model of the earth leakage circuit breaker device based on Arduino (EL...

  11. Structured ecosystem-scale approach to marine water quality management

    CSIR Research Space (South Africa)

    Taljaard, Susan

    2006-10-01

    Full Text Available and implement environmental management programmes. A structured ecosystem-scale approach for the design and implementation of marine water quality management programmes developed by the CSIR (South Africa) in response to recent advances in policies...

  12. Structures of water molecular nanotube induced by axial tensile strains

    Energy Technology Data Exchange (ETDEWEB)

    Li, H. [Key Laboratory of Liquid Structures and Heredity of Materials, Ministry of Education, School of Materials Science and Engineering, Shandong University (China)], E-mail: lihuilmy@hotmail.com; Zhang, X.Q. [Physics Department, Ocean University of China, Qingdao (China); Liew, K.M. [Department of Building and Constructions, City University of Hong Kong, Kowloon (Hong Kong); Liu, X.F. [Key Laboratory of Liquid Structures and Heredity of Materials, Ministry of Education, School of Materials Science and Engineering, Shandong University (China)

    2008-10-06

    Five well-ordered nano-ice structures embedded in carbon nanotubes are obtained in this study. These five nano-ice phases all exhibit single walled tubular morphologies, including the pentagon, hexagon ice nanotubes whose structures are quite different from bulk ice. Our simulation results indicate that water molecules tend to rearrange into surface ring structures to reduce the number of free OH groups. The structural behavior of these ice nanotubes inside CNTs subject to axial stress is also investigated. The ice nanotubes tend to be drawn to ice nanorings or ice nanospring during the mechanical stretching. The distribution function exhibits typical order-to-disorder transition of the water network confined in carbon nanotube during the stretching. By analysis, we suggest that it is unlikely that additional water molecules will enter the tubes because of the increased volume available if the tubes are stretched at contact with a water reservoir.

  13. Hydrogen/deuterium substitution methods: understanding water structure in solution

    International Nuclear Information System (INIS)

    Soper, A.K.

    1993-01-01

    The hydrogen/deuterium substitution method has been used for different applications, such as the short range order between water molecules in a number of different environments (aqueous solutions of organic molecules), or to study the partial structure factors of water at high pressure and temperature. The absolute accuracy that can be obtained remains uncertain, but important qualitative information can be obtained on the local organization of water in aqueous solution. Some recent results with pure water, methanol and dimethyl sulphoxide (DMSO) solutions are presented. It is shown that the short range water structure is not greatly affected by most solutes except at high concentrations and when the solute species has its own distinctive interaction with water (such as a dissolved small ion). 3 figs., 14 refs

  14. Fuzzy Diagnostic System for Oleo-Pneumatic Drive Mechanism of High-Voltage Circuit Breakers

    Directory of Open Access Journals (Sweden)

    Viorel Nicolau

    2013-01-01

    Full Text Available Many oil-based high-voltage circuit breakers are still in use in national power networks of developing countries, like those in Eastern Europe. Changing these breakers with new more reliable ones is not an easy task, due to their implementing costs. The acting device, called oleo-pneumatic mechanism (MOP, presents the highest fault rate from all components of circuit breaker. Therefore, online predictive diagnosis and early detection of the MOP fault tendencies are very important for their good functioning state. In this paper, fuzzy logic approach is used for the diagnosis of MOP-type drive mechanisms. Expert rules are generated to estimate the MOP functioning state, and a fuzzy system is proposed for predictive diagnosis. The fuzzy inputs give information about the number of starts and time of functioning per hour, in terms of short-term components, and their mean values. Several fuzzy systems were generated, using different sets of membership functions and rule bases, and their output performances are studied. Simulation results are presented based on an input data set, which contains hourly records of operating points for a time horizon of five years. The fuzzy systems work well, making an early detection of the MOP fault tendencies.

  15. A Novel Approach to Power Circuit Breaker Design for Replacement of SF6

    Directory of Open Access Journals (Sweden)

    D. J. Telfer

    2004-01-01

    Full Text Available This contribution explores the role of PTFE ablation in enhancing current interruption for various background gases in high voltage circuit breakers. An assessment of the current interruption capability has been made in terms of the arcing duration and the contact gap length at which critical arc extinction is achieved. These observations are supported by measurements of the magnitude of extinction and re-ignition voltage peaks. Most previous and other current experimental work on gas filled circuit breaker design follows conventional wisdom in investigating arcing behaviours at elevated gas pressures (usually up to 6 bar. But in this work we concentrate on the effects of using low gas pressures (less than 1 bar in the presence of a close-fitting shield of ablatant polymer material (PTFE that surrounds the electrode assembly of an experimental high power circuit breaker. We demonstrate that for several different gases, arc extinction capability compares well under these conditions with SF6, suggesting that SF6 could be replaced entirely in this novel system by more environmentally friendly gases. Moreover, the critical contact gap lengths at extinction are only slightly greater than when using SF6 at 6 bar. Weight loss measurements from the ablatant shield suggest that a chemical puffer action is the most likely mechanism for achieving the observed arc extinctions in this system.

  16. Identification of structural relaxation in the dielectric response of water

    DEFF Research Database (Denmark)

    Hansen, Jesper Schmidt; Kisliuk, Alexander; Solokov, Alexei P.

    2016-01-01

    One century ago pioneering dielectric results obtained for water and n-alcohols triggered the advent of molecular rotation diffusion theory considered by Debye to describe the primary dielectric absorption in these liquids. Comparing dielectric, viscoelastic, and light scattering results, we...... unambiguously demonstrate that the structural relaxation appears only as a high-frequency shoulder in the dielectric spectra of water. In contrast, the main dielectric peak is related to a supramolecular structure, analogous to the Debye-like peak observed in monoalcohols....

  17. Structures of water molecules in carbon nanotubes under electric fields

    International Nuclear Information System (INIS)

    Winarto,; Takaiwa, Daisuke; Yamamoto, Eiji; Yasuoka, Kenji

    2015-01-01

    Carbon nanotubes (CNTs) are promising for water transport through membranes and for use as nano-pumps. The development of CNT-based nanofluidic devices, however, requires a better understanding of the properties of water molecules in CNTs because they can be very different from those in the bulk. Using all-atom molecular dynamics simulations, we investigate the effect of axial electric fields on the structure of water molecules in CNTs having diameters ranging from (7,7) to (10,10). The water dipole moments were aligned parallel to the electric field, which increases the density of water inside the CNTs and forms ordered ice-like structures. The electric field induces the transition from liquid to ice nanotubes in a wide range of CNT diameters. Moreover, we found an increase in the lifetime of hydrogen bonds for water structures in the CNTs. Fast librational motion breaks some hydrogen bonds, but the molecular pairs do not separate and the hydrogen bonds reform. Thus, hydrogen bonds maintain the water structure in the CNTs, and the water molecules move collectively, decreasing the axial diffusion coefficient and permeation rate

  18. Structure and optical properties of water covered Cu(110) surfaces

    International Nuclear Information System (INIS)

    Baghbanpourasl, A.

    2014-01-01

    In this thesis structural and optical properties of the water covered Cu(110) surface is studied using density functional theory within independent particle approximation. Several stable adsorption structures are studied such as water clusters (monomer, dimer, trimer, tetramer and pentamer), different hexagonal monolayers, partially dissociated water monolayers and three different types of chains among them a chain that consists of pentagon rings. For a copper surface in contact with water vapor, the energetically stable H 2 O/OH adsorbed structures are compared thermodynamically using adsorption free energy (change of free energy due to adsorption). Several phase diagrams with respect to temperature and pressure are calculated. It is found that among the large number of energetically stable structures (i.e. structures with positive adsorption energy ) only limited number of them are thermodynamically stable. These thermodynamically stable structures are the class of almost energetically degenerate hexagonal overlayers, one type of partially dissociated water structure that contains Bjerrum defect in the hydrogen bond network and pentagon chain. Since hydrogen atoms are light weight their vibrational effects can be considerable. Zero point vibration decreases the adsorption energy up to 0.1 eV and free energy of adsorbed molecules arising from vibrational degree of freedom can go up to -0.2 eV per adsorbed molecule at 500 Kelvin. However zero point energy and vibrational free energy of adsorbed molecules do not alter relative stability of the adsorbed structures. To account for the long range van der Waals interactions, a semi-empirical scheme is applied. Reflectance Anisotropy Spectroscopy (RAS) is a fast and non destructive optical method that can be used to prob the surface in different conditions such as vacuum and electro-chemical environment. Elasto-optic coeficients of bulk are calculated from first principles and the change of the RA spectrum of the bare Cu

  19. NABi, a novel β-sheet breaker, inhibits Aβ aggregation and neuronal toxicity: Therapeutic implications for Alzheimer's disease.

    Science.gov (United States)

    Jang, Ja-Young; Rhim, Hyangshuk; Kang, Seongman

    2018-01-01

    Amyloid beta (Aβ) aggregates are an important therapeutic target for Alzheimer's disease (AD), a fatal neurodegenerative disease. To date, AD still remains a big challenge due to no effective treatments. Based on the property that Aβ aggregates have the cross-β-structure, a common structural feature in amyloids, we systemically designed the Aβ-aggregation inhibitor that maintains Aβ-interacting ability but removes toxic part from SOD1 (superoxide dismutase 1)-G93A. We identified NABi (Natural Aβ Binder and Aβ-aggregation inhibitor) composed of β2-3 strands, a novel breaker of Aβ aggregation, which does not self-aggregate and has no cytotoxicity at all. The NABi blocks Aβ-fibril formation in vitro and in vivo and prevents neuronal cell death, a hallmark of AD pathogenesis. Such anti-amyloidogenic properties can provide novel strategies for treating AD. Furthermore, our study provides molecular insights into the design of amyloidogenic inhibitors to cure various neurodegenerative and amyloid-associated diseases, as NABi would regulate aggregation of other toxic β-sheet proteins other than Aβ. Copyright © 2017 Elsevier B.V. All rights reserved.

  20. Water relations, thallus structure and photosynthesis in Negev Desert lichens

    Science.gov (United States)

    Palmer, R. J. Jr; Friedmann, E. I.

    1990-01-01

    The role of lichen thallus structure in water relations and photosynthesis was studied in Ramalina maciformis (Del.) Bory and Teloschistes lacunosus (Rupr.) Sav. Water-vapour adsorption and photosynthesis are dependent upon thallus integrity and are significantly lower in crushed thalli. Cultured phycobiont (Trebouxia sp.) cells are capable of photosynthesis over the same relative humidity range (> 80% RH) as are intact lichens. Thus, water-vapour adsorption by the thallus and physiological adaptation of the phycobiont contribute to the ability of these lichens to photosynthesize in an arid environment. Despite differences in their anatomical structure and water-uptake characteristics, their CO2 incorporation is similar. The two lichens use liquid water differently and they occupy different niches.

  1. SOCIO-ECONOMIC STUDY OF SUPLIT STONE BREAKER WOMEN IN SUPPORTING FAMILY LIFE: A CASE STUDY OF INFORMAL SECTOR STONE BREAKER WORKER IN THE NORTH MORAMO, INDONESIA

    Directory of Open Access Journals (Sweden)

    Kambolong M.

    2017-10-01

    Full Text Available A socio-economic study of Suplit Stone breaker women In Supporting Family life is a study of the Informal Sector Workers carried out in the form of a survey. This study aims to assess the socio-economic level of the workers, educational level, results achieved, income levels, health effects, and household's social condition. This research will specifically study and analyze income received, identify and examine the issues that arise in performing stone breaker as an occupation: deficiencies, expectations, and negative impacts. Ten urban villages/villages in Moramo North District was taken as research population. Area samples taken were five (5 urban/rural where workers are concentrated in Lalowaru Village, Puasana Village, Mata Mawatu Village, Sanggula Village, and Lamokula Village. Samples community were 5 percent of all household. Therefore total samples taken were 93 people scattered in villages. Research informants are Head of North Morano district, Stone Processing owner, and stone carrier driver. Data collection was conducted by observation, interview using a list of questions, as well as documentation of objective conditions. Data were analyzed using descriptive analysis techniques, which describe the objective conditions of the field in accordance with the purpose of research. Research result shows workers are housewives who help their husbands and families to supplement the household income to support family life. In general, socio-economic conditions of women suplit stone breaker is relatively low, their education level is generally elementary or none. The results achieved are still limited by an average of IDR 30,000, per day/worker is calculated based on the total stone yield. These women perform their work using simple tools such as hammer and gloves. The negative impact on eye health and breathing difficulty caused by inhaling stone dust every day. The problems faced by the workers is the lack of working capital to be trying to own

  2. Structural and mechanical properties of glassy water in nanoscale confinement.

    Science.gov (United States)

    Lombardo, Thomas G; Giovambattista, Nicolás; Debenedetti, Pablo G

    2009-01-01

    We investigate the structure and mechanical properties of glassy water confined between silica-based surfaces with continuously tunable hydrophobicity and hydrophilicity by computing and analyzing minimum energy, mechanically stable configurations (inherent structures). The structured silica substrate imposes long-range order on the first layer of water molecules under hydrophobic confinement at high density (p > or = 1.0 g cm(-3)). This proximal layer is also structured in hydrophilic confinement at very low density (p approximately 0.4 g cm(-3)). The ordering of water next to the hydrophobic surface greatly enhances the mechanical strength of thin films (0.8 nm). This leads to a substantial stress anisotropy; the transverse strength of the film exceeds the normal strength by 500 MPa. The large transverse strength results in a minimum in the equation of state of the energy landscape that does not correspond to a mechanical instability, but represents disruption of the ordered layer of water next to the wall. In addition, we find that the mode of mechanical failure is dependent on the type of confinement. Under large lateral strain, water confined by hydrophilic surfaces preferentially forms voids in the middle of the film and fails cohesively. In contrast, water under hydrophobic confinement tends to form voids near the walls and fails by loss of adhesion.

  3. The life test of a DC circuit breaker of tokamak device JT-60 for a nuclear fusion research

    International Nuclear Information System (INIS)

    Shimada, Ryuichi; Tani, Keiji; Kishimoto, Hiroshi; Tamura, Sanae; Yanabu, Satoru.

    1979-01-01

    In the Tokamak devices for nuclear fusion research, the construction of the current transformer circuits having plasma as the secondary circuit and the change of the primary circuit current are necessary for generating current in the plasma. This is considered to be fairly difficult in practice if conventional methods using capacitor discharge and iron core coils are employed. Considering such circumstances, it was decided for JT-60 to use an air-core current transformer coil and to employ the method of storing energy in the form of current in the coil inductance instead of a capacitor. For this reason, a DC circuit breaker is required to interrupt coil current. The authors improved an AV vacuum breaker, which had been developed as the vacuum breaker of longitudinal magnetic field type applying a magnetic field in parallel with an arc, to get the one for DC circuit for the purpose of applying it to JT-60. In this paper, the operational characteristic of the DC breaker is described, the construction and function of the life test circuit is explained, and the test results are reported. Finally, interruptions of 10,000 times at 20 kA were carried out. It is successful that the restrike of arc occurring during tens of milli-seconds after interruptions was improved to 0.05% or less for 10,000 times operations. Further, it was found that the generation of arc restrike can be reduced practically to zero with two breakers in series. (Wakatsuki, Y.)

  4. Bond-Valence Constraints on Liquid Water Structure

    International Nuclear Information System (INIS)

    Bickmore, Barry R.; Rosso, Kevin M.; Brown, I. David; Kerisit, Sebastien N.

    2009-01-01

    The recent controversy about the structure of liquid water pits a new model involving water molecules in relatively stable rings-and-chains structures against the standard model that posits water molecules in distorted tetrahedral coordination. Molecular dynamics (MD) simulations 'both classical and ab initio' almost uniformly support the standard model, but since none of them can yet reproduce all the anomalous properties of water, they leave room for doubt. We argue that it is possible to evaluate these simulations by testing them against their adherence to the bond-valence model, a well known, and quantitatively accurate, empirical summary of the behavior of atoms in the bonded networks of inorganic solids. Here we use the results of ab initio molecular dynamics simulations of ice, water, and several solvated aqueous species to show that the valence sum rule (the first axiom of the bond-valence model,) is followed in both solid and liquid bond networks. We then test MD simulations of water, employing several popular potential models, against this criterion and the experimental O-O radial distribution function. It appears that most of those tested cannot satisfy both criteria well, except TIP4P and TIP5P. If the valence sum rule really can be applied to simulated liquid structures, then it follows that the bonding behaviors of atoms in liquids are in some ways identical to those in solids. We support this interpretation by showing that the simulations produce O-H-O geometries completely consistent with the range of geometries available in solids, and the distributions of instantaneous valence sums reaching the atoms in both the ice and liquid water simulations are essentially identical. Taken together, this is powerful evidence in favor of the standard distorted tetrahedral model of liquid water structure

  5. The effect of the water tariff structures on the water consumption in Mallorcan hotels

    Science.gov (United States)

    Deyà-Tortella, Bartolomé; Garcia, Celso; Nilsson, William; Tirado, Dolores

    2016-08-01

    Tourism increases water demand, especially in coastal areas and on islands, and can also cause water shortages during the dry season and the degradation of the water supply. The aim of this study is to evaluate the impact of water price structures on hotel water consumption on the island of Mallorca (Spain). All tourist municipalities on the island use different pricing structures, such as flat or block rates, and different tariffs. This exogenous variation is used to evaluate the effect of prices on water consumption for a sample of 134 hotels. The discontinuity of the water tariff structure and the fixed rate, which depends on the number of hotel beds, generate endogeneity problems. We propose an econometric model, an instrumental variable quantile regression for within artificial blocks transformed data, to solve both problems. The coefficients corresponding to the price variables are not found to be significantly different from zero. The sign of the effect is negative, but the magnitude is negligible: a 1% increase in all prices would reduce consumption by an average of only 0.024%. This result is probably due to the small share of water costs with respect to the total hotel operational costs (around 4%). Our regression model concludes that the introduction of water-saving initiatives constitutes an effective way to reduce consumption.

  6. Water-insoluble Silk Films with Silk I Structure

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Q.; Hu, X; Wang, X; Kluge, J; Lu, S; Cebe, P; Kaplan, D

    2010-01-01

    Water-insoluble regenerated silk materials are normally produced by increasing the {beta}-sheet content (silk II). In the present study water-insoluble silk films were prepared by controlling the very slow drying of Bombyx mori silk solutions, resulting in the formation of stable films with a predominant silk I instead of silk II structure. Wide angle X-ray scattering indicated that the silk films stabilized by slow drying were mainly composed of silk I rather than silk II, while water- and methanol-annealed silk films had a higher silk II content. The silk films prepared by slow drying had a globule-like structure at the core surrounded by nano-filaments. The core region was composed of silk I and silk II, surrounded by hydrophilic nano-filaments containing random turns and {alpha}-helix secondary structures. The insoluble silk films prepared by slow drying had unique thermal, mechanical and degradative properties. Differential scanning calorimetry results revealed that silk I crystals had stable thermal properties up to 250 C, without crystallization above the T{sub g}, but degraded at lower temperatures than silk II structure. Compared with water- and methanol-annealed films the films prepared by slow drying had better mechanical ductility and were more rapidly enzymatically degraded, reflecting the differences in secondary structure achieved via differences in post processing of the cast silk films. Importantly, the silk I structure, a key intermediate secondary structure for the formation of mechanically robust natural silk fibers, was successfully generated by the present approach of very slow drying, mimicking the natural process. The results also point to a new mode of generating new types of silk biomaterials with enhanced mechanical properties and increased degradation rates, while maintaining water insolubility, along with a low {beta}-sheet content.

  7. Contact angles of wetting and water stability of soil structure

    Science.gov (United States)

    Kholodov, V. A.; Yaroslavtseva, N. V.; Yashin, M. A.; Frid, A. S.; Lazarev, V. I.; Tyugai, Z. N.; Milanovskiy, E. Yu.

    2015-06-01

    From the soddy-podzolic soils and typical chernozems of different texture and land use, dry 3-1 mm aggregates were isolated and sieved in water. As a result, water-stable aggregates and water-unstable particles composing dry 3-1 mm aggregates were obtained. These preparations were ground, and contact angles of wetting were determined by the static sessile drop method. The angles varied from 11° to 85°. In most cases, the values of the angles for the water-stable aggregates significantly exceeded those for the water-unstable components. In terms of carbon content in structural units, there was no correlation between these parameters. When analyzing the soil varieties separately, the significant positive correlation between the carbon content and contact angle of aggregates was revealed only for the loamy-clayey typical chernozem. Based on the multivariate analysis of variance, the value of contact wetting angle was shown to be determined by the structural units belonging to water-stable or water-unstable components of macroaggregates and by the land use type. In addition, along with these parameters, the texture has an indirect effect.

  8. Structure of liquid water at high pressures and temperatures

    CERN Document Server

    Eggert, J H; Loubeyre, P

    2002-01-01

    We report quantitatively accurate structure-factor and radial-distribution-function measurements of liquid water in a diamond-anvil cell (DAC) using x-ray diffraction. During the analysis of our diffraction data, we found it possible (and necessary) to also determine the density. Thus, we believe we present the first-ever diffraction-based determination of a liquid structure factor and equation of state in a DAC experiment.

  9. Effect of Magnesium Oxide Nanoparticles on Water Glass Structure

    Directory of Open Access Journals (Sweden)

    Bobrowski A.

    2012-09-01

    Full Text Available An attempt has been made to determine the effect of an addition of colloidal suspensions of the nanoparticles of magnesium oxide on the structure of water glass, which is a binder for moulding and core sands. Nanoparticles of magnesium oxide MgO in propanol and ethanol were introduced in the same mass content (5wt.% and structural changes were determined by measurement of the FT-IR absorption spectra.

  10. Freely floating structures trapping time-harmonic water waves (revisited)

    OpenAIRE

    Kuznetsov, Nikolay; Motygin, Oleg

    2014-01-01

    We study the coupled small-amplitude motion of the mechanical system consisting of infinitely deep water and a structure immersed in it. The former is bounded above by a free surface, whereas the latter is formed by an arbitrary finite number of surface-piercing bodies floating freely. The mathematical model of time-harmonic motion is a spectral problem in which the frequency of oscillations serves as the spectral parameter. It is proved that there exist axisymmetric structures consisting of ...

  11. Study and field verification of the effects of removing closing resistors from 500 kV circuit breakers

    International Nuclear Information System (INIS)

    Selin, D.A.; Agrawal, B.L.; Farmer, R.G.; Demcko, J.A.

    1992-01-01

    Closing resistors in EHV circuit breakers are frequently used to reduce switching transients on lines thus preventing flashovers during line energization. Maintenance and failures of such closing resistors can be costly and reduce transmission system reliability. For these reasons, APS conducted an investigation into the technical feasibility of operating its 500 kV without closing resistors. This paper describes study results of removing closing resistors from 500 kV breakers in a system which employs older technology silicon carbide type surge arresters. The paper also describes results of field tests of the expected flashover rates calculated in the study. These field tests involve repeatedly energizing a 258 mile 500 kV line using a breaker in which the closing resistors are disabled. Transient overvoltages captured during the tests are compared with predicted overvoltages. The study concludes that closing resistors may be removed from the subject system without unacceptable consequences

  12. A thyristor breaker of 1.5 109 V.A. for the poloidal field system of TORUS SUPRA

    International Nuclear Information System (INIS)

    Bareyt, B.; Leloup, C.; Rijnoudt, E.

    1980-09-01

    The poloidal field system of Torus Supra has an inductive storage of approximately 38 MJ, which has conducted to research the best solution for a D.C. breaker (55 kA., 27 kV). A solid-state breaker has been chosen. The working principles have been tested on a small size model. The final circuit breaker will contain a large number of thyristors in series and in parallel; the critical problem lies in the series arrangement. A test unit for full tension has been constructed. In this unit the thyristors are submitted to the maximum current as well as to the maximum voltage. The surges measured during tests are not higher than the calculated values. A synthetic circuit of the poloidal field system has been used for test under the final working conditions

  13. Experimental and theoretical analysis of vacuum circuit breaker prestrike effect on a transformer, Calgary Alberta, Canada 29-31 July 2009

    NARCIS (Netherlands)

    Popov, M.; Smeets, R.P.P.; Sluis, van der L.; Herdt, de H.; Declercq, J.

    2009-01-01

    Summary form only given. The work presented in this paper deals with the investigation of circuit breaker prestrike effect that occurs during energizing a distribution transformer. An experimental test setup that consists of a supply transformer, a vacuum circuit breaker (VCB), a cable and a test

  14. Transient Studies in Large Offshore Wind Farms, Employing Detailed Circuit Breaker Representation

    DEFF Research Database (Denmark)

    Glasdam, Jakob Bærholm; Bak, Claus Leth; Hjerrild, Jesper

    2012-01-01

    in order to ensure reliable switching operations. Transient measurement results in an OWF are compared with simulation results in PSCAD EMTDC and DigSILENT Power Factory. A user-defined model of the vacuum circuit breaker (VCB) is included in both tools, capable of simulating multiple prestrikes during...... greatly improves the simulation results, whereas little improvement is found in DigSILENT. Based on the transient study it is found that the simulated SOV can be up to 60% higher at the sending end when using the detailed VCB representation compared to the built-in switch, which emphasises the need...

  15. Optical fiber imaging for high speed plasma motion diagnostics: Applied to low voltage circuit breakers

    International Nuclear Information System (INIS)

    McBride, J. W.; Balestrero, A.; Tribulato, G.; Ghezzi, L.; Cross, K. J.

    2010-01-01

    An integrated portable measurement system is described for the study of high speed and high temperature unsteady plasma flows such as those found in the vicinity of high current switching arcs. An array of optical fibers allows the formation of low spatial resolution images, with a maximum capture rate of 1x10 6 images per second (1 MHz), with 8 bit intensity resolution. Novel software techniques are reported to allow imaging of the arc; and to measure arc trajectories. Results are presented on high current (2 kA) discharge events in a model test fixture and on the application to a commercial low voltage circuit breaker.

  16. Structure of human insulin monomer in water/acetonitrile solution

    Energy Technology Data Exchange (ETDEWEB)

    Bocian, Wojciech; Sitkowski, Jerzy; Bednarek, Elzbieta [National Medicines Institute (Poland); Tarnowska, Anna; Kawecki, Robert [Institute of Organic Chemistry Polish Academy of Sciences (Poland); Kozerski, Lech [National Medicines Institute (Poland)], E-mail: lkoz@icho.edu.pl

    2008-01-15

    Here we present evidence that in water/acetonitrile solvent detailed structural and dynamic information can be obtained for important proteins that are naturally present as oligomers under native conditions. An NMR-derived human insulin monomer structure in H{sub 2}O/CD{sub 3}CN, 65/35 vol%, pH 3.6 is presented and compared with the available X-ray structure of a monomer that forms part of a hexamer (Acta Crystallogr. 2003 Sec. D59, 474) and with NMR structures in water and organic cosolvent. Detailed analysis using PFGSE NMR, temperature-dependent NMR, dilution experiments and CSI proves that the structure is monomeric in the concentration and temperature ranges 0.1-3 mM and 10-30 deg. C, respectively. The presence of long-range interstrand NOEs, as found in the crystal structure of the monomer, provides the evidence for conservation of the tertiary structure. Starting from structures calculated by the program CYANA, two different molecular dynamics simulated annealing refinement protocols were applied, either using the program AMBER in vacuum (AMBER{sub V}C), or including a generalized Born solvent model (AMBER{sub G}B)

  17. Structure of human insulin monomer in water/acetonitrile solution

    International Nuclear Information System (INIS)

    Bocian, Wojciech; Sitkowski, Jerzy; Bednarek, Elzbieta; Tarnowska, Anna; Kawecki, Robert; Kozerski, Lech

    2008-01-01

    Here we present evidence that in water/acetonitrile solvent detailed structural and dynamic information can be obtained for important proteins that are naturally present as oligomers under native conditions. An NMR-derived human insulin monomer structure in H 2 O/CD 3 CN, 65/35 vol%, pH 3.6 is presented and compared with the available X-ray structure of a monomer that forms part of a hexamer (Acta Crystallogr. 2003 Sec. D59, 474) and with NMR structures in water and organic cosolvent. Detailed analysis using PFGSE NMR, temperature-dependent NMR, dilution experiments and CSI proves that the structure is monomeric in the concentration and temperature ranges 0.1-3 mM and 10-30 deg. C, respectively. The presence of long-range interstrand NOEs, as found in the crystal structure of the monomer, provides the evidence for conservation of the tertiary structure. Starting from structures calculated by the program CYANA, two different molecular dynamics simulated annealing refinement protocols were applied, either using the program AMBER in vacuum (AMBER V C), or including a generalized Born solvent model (AMBER G B)

  18. Skin lipid structure controls water permeability in snake molts.

    Science.gov (United States)

    Torri, Cristian; Mangoni, Alfonso; Teta, Roberta; Fattorusso, Ernesto; Alibardi, Lorenzo; Fermani, Simona; Bonacini, Irene; Gazzano, Massimo; Burghammer, Manfred; Fabbri, Daniele; Falini, Giuseppe

    2014-01-01

    The role of lipids in controlling water exchange is fundamentally a matter of molecular organization. In the present study we have observed that in snake molt the water permeability drastically varies among species living in different climates and habitats. The analysis of molts from four snake species: tiger snake, Notechis scutatus, gabon viper, Bitis gabonica, rattle snake, Crotalus atrox, and grass snake, Natrix natrix, revealed correlations between the molecular composition and the structural organization of the lipid-rich mesos layer with control in water exchange as a function of temperature. It was discovered, merging data from micro-diffraction and micro-spectroscopy with those from thermal, NMR and chromatographic analyses, that this control is generated from a sophisticated structural organization that changes size and phase distribution of crystalline domains of specific lipid molecules as a function of temperature. Thus, the results of this research on four snake species suggest that in snake skins different structured lipid layers have evolved and adapted to different climates. Moreover, these lipid structures can protect, "safety", the snakes from water lost even at temperatures higher than those of their usual habitat. Copyright © 2013 Elsevier Inc. All rights reserved.

  19. A structured ecosystem-scale approach to marine water quality ...

    African Journals Online (AJOL)

    These, in turn, created the need for holistic and integrated frameworks within which to design and implement environmental management programmes. A structured ecosystem-scale approach for the design and implementation of marine water quality management programmes developed by the CSIR (South Africa) in ...

  20. Tempered Water Lower Port Connector Structural Analysis Verification

    International Nuclear Information System (INIS)

    CREA, B.A.

    2000-01-01

    Structural analysis of the lower port connection of the Tempered Water System of the Cold Vacuum Drying Facility was performed. Subsequent detailed design changes to enhance operability resulted in the need to re-evaluate the bases of the original analysis to verify its continued validity. This evaluation is contained in Appendix A of this report. The original evaluation is contained in Appendix B

  1. Influence of ground water on soil-structure interaction

    International Nuclear Information System (INIS)

    Costantino, C.J.; Graves, H.L.

    1987-01-01

    The basic problem consists of a liner flexible structure situated at or near the surface of a soil half-space. In keeping with typical small strain seismic analyses, the soil skeleton is represented as a linear medium in which all potential nonlinearities are at most lumped together into an equivalent hysteretic damping modulus. In addition, the ground water level is located at some depth relatively close to the structure, and in a position to impact on the seismic response of the facility. In order to estimate the response of this oil-water system, the two-phased medium formulation of Biot was used to treat the response of the solids and water as two separate linear media, coupled together through soil permeability and volume effects. (orig./HP)

  2. Structure of bound water and refinement of acid metmyoglobin

    International Nuclear Information System (INIS)

    Raghaven, N.V.; Schoenborn, B.P.

    1982-06-01

    The structure of myoglobin has been determined by x-ray diffraction for the acidmet, deoxy, and the oxy forms. Neutron diffraction work, done in this laboratory, has demonstrated that hydrogen and deuterium positions can be located. In addition to the localization of H and D, neutron diffraction provides a unique method for studying the water structure because of the strong scattering ability of D 2 O. The scattering factor of deuterium is nearly twice as large as that of hydrogen, and it increases the visibility of water molecules in Fourier maps, so that in a neutron map a water molecule appears about three times as strong as in an equivalent electron-density map. (DT)

  3. Structure of the floating water bridge and water in an electric field.

    Science.gov (United States)

    Skinner, Lawrie B; Benmore, Chris J; Shyam, Badri; Weber, J K R; Parise, John B

    2012-10-09

    The floating water bridge phenomenon is a freestanding rope-shaped connection of pure liquid water, formed under the influence of a high potential difference (approximately 15 kV). Several recent spectroscopic, optical, and neutron scattering studies have suggested that the origin of the bridge is associated with the formation of anisotropic chains of water molecules in the liquid. In this work, high energy X-ray diffraction experiments have been performed on a series of floating water bridges as a function of applied voltage, bridge length, and position within the bridge. The two-dimensional X-ray scattering data showed no direction-dependence, indicating that the bulk water molecules do not exhibit any significant preferred orientation along the electric field. The only structural changes observed were those due to heating, and these effects were found to be the same as for bulk water. These X-ray scattering measurements are supported by molecular dynamics (MD) simulations which were performed under electric fields of 10(6) V/m and 10(9) V/m. Directional structure factor calculations were made from these simulations parallel and perpendicular to the E-field. The 10(6) V/m model showed no significant directional-dependence (anisotropy) in the structure factors. The 10(9) V/m model however, contained molecules aligned by the E-field, and had significant structural anisotropy.

  4. Function and operation of the Doublet III E-coil vacuum breaker system

    International Nuclear Information System (INIS)

    Callis, R.W.; Jackson, G.; DeGrassie, J.; Peterson, P.; LeVine, F.

    1979-11-01

    The ohmic heating system for the Doublet III fusion research device at General Atomic is required to provide the voltage for the initial breakdown phase (there is no preionization) along with the energy to drive the plasma current to a value of 2.5 MA or greater. This requires a peak one turn voltage of 250 volts (16 kV across coil terminals) and a magnetic flux swing of 5 volt-seconds (peak coil current of 110 kA). This voltage and flux swing is accomplished by reverse biasing the ohmic heating coil (E-coil) where, upon reaching a value of 110 ka the coil current is interrupted and commutated into a RC network producing 16 kV across the coil. The interrruption of the E-coil current is accomplished by the use of an array of vacuum circuit breakers (VCB's) and a counter plus network. A description is given of the ohmic heating circuit and the performance of the vacuum circuit breaker array and its counter pulse system

  5. Deliberation of arc plasma characteristics according to experimental results in a typical gas circuit-breaker

    International Nuclear Information System (INIS)

    Borghei, M.

    2005-01-01

    One of the industrial plasma applications is in the gas circuit breakers (GCB) and switching processes. During GCB operation and opening of its two contacts, current flows through of the inter-electrode medium (generally SF 6 or its mixture) and electric arc forms from the plasma that has been created between the contacts. The electric arc is a self-sustained discharge having low voltage drop and able to support great amplitudes of current. The technical basis of circuit breaker is: initiating arc plasma, flowing a large current, cooling it effectively to avoid re-ignition, and finally the transition from a well-conducting medium into insulating gas space in a very short time interval. In other words, for a successful interruption we need to know about power brought to the arc and that of removed. In this paper an attempt has been made to study, characterize and understand some arc behaviors such as arc conductance and its changes according to recorded current and voltage traces experimentally. From physical point of view, there are different phenomena that affect on arc behavior. According to methodology used here, we tried to understand some of arc behavior from experimental results and finally we extract some arc parameters. (author)

  6. Modelling soil-water dynamics in the rootzone of structured and water-repellent soils

    Science.gov (United States)

    Brown, Hamish; Carrick, Sam; Müller, Karin; Thomas, Steve; Sharp, Joanna; Cichota, Rogerio; Holzworth, Dean; Clothier, Brent

    2018-04-01

    In modelling the hydrology of Earth's critical zone, there are two major challenges. The first is to understand and model the processes of infiltration, runoff, redistribution and root-water uptake in structured soils that exhibit preferential flows through macropore networks. The other challenge is to parametrise and model the impact of ephemeral hydrophobicity of water-repellent soils. Here we have developed a soil-water model, which is based on physical principles, yet possesses simple functionality to enable easier parameterisation, so as to predict soil-water dynamics in structured soils displaying time-varying degrees of hydrophobicity. Our model, WEIRDO (Water Evapotranspiration Infiltration Redistribution Drainage runOff), has been developed in the APSIM Next Generation platform (Agricultural Production Systems sIMulation). The model operates on an hourly time-step. The repository for this open-source code is https://github.com/APSIMInitiative/ApsimX. We have carried out sensitivity tests to show how WEIRDO predicts infiltration, drainage, redistribution, transpiration and soil-water evaporation for three distinctly different soil textures displaying differing hydraulic properties. These three soils were drawn from the UNSODA (Unsaturated SOil hydraulic Database) soils database of the United States Department of Agriculture (USDA). We show how preferential flow process and hydrophobicity determine the spatio-temporal pattern of soil-water dynamics. Finally, we have validated WEIRDO by comparing its predictions against three years of soil-water content measurements made under an irrigated alfalfa (Medicago sativa L.) trial. The results provide validation of the model's ability to simulate soil-water dynamics in structured soils.

  7. The structure of liquid water; La structure de l'eau liquide

    Energy Technology Data Exchange (ETDEWEB)

    Marin, B [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    We have tried to expose a bibliography so complete as possible on structure of liquid water. One synthesis of the different models of water structure is presently impossible, so, we have exposed the main properties of water. We have pointed out the new hypotheses on the electronic structure of water molecule and on the theory of hydrogen bond. After that, we have put together the studies of structure by spectroscopy and given the main deductions of some workers on this subject. We have also exposed the characteristics of processes: relaxation and dielectric constant, influence of temperature on structure. At last, we have considered briefly the partition and thermodynamic functions established from the various models proposed. (author) [French] Nous nous sommes proposes d'ecrire une bibliographie aussi complete que possible sur la structure de l'eau liquide. Apres avoir rappele les differentes tentatives d'etablissement de modele de structure, et s'etre rendu compte qu'une synthese s'averait impossible, il nous est apparu souhaitable d'exposer les principales proprietes de l'eau. C'est ainsi que nous avons donne les hypotheses les plus recentes sur la structure electronique de la molecule d'eau ainsi que celles concernant la theorie de la liaison hydrogene. Puis nous avons rassemble les etudes de structure par spectroscopie et fourni les deductions auxquelles les divers auteurs sont arrives. Nous avons egalement expose les caracteristiques des processus tels que: relaxation et constante dielectrique, l'influence de la temperature sur la structure et enfin nous avons donne brievement les fonctions de partition et les grandeurs thermodynamiques etablies a partir des divers modeles proposes. (auteur)

  8. Structural Optimization of Triboelectric Nanogenerator for Harvesting Water Wave Energy.

    Science.gov (United States)

    Jiang, Tao; Zhang, Li Min; Chen, Xiangyu; Han, Chang Bao; Tang, Wei; Zhang, Chi; Xu, Liang; Wang, Zhong Lin

    2015-12-22

    Ocean waves are one of the most abundant energy sources on earth, but harvesting such energy is rather challenging due to various limitations of current technologies. Recently, networks formed by triboelectric nanogenerator (TENG) have been proposed as a promising technology for harvesting water wave energy. In this work, a basic unit for the TENG network was studied and optimized, which has a box structure composed of walls made of TENG composed of a wavy-structured Cu-Kapton-Cu film and two FEP thin films, with a metal ball enclosed inside. By combination of the theoretical calculations and experimental studies, the output performances of the TENG unit were investigated for various structural parameters, such as the size, mass, or number of the metal balls. From the viewpoint of theory, the output characteristics of TENG during its collision with the ball were numerically calculated by the finite element method and interpolation method, and there exists an optimum ball size or mass to reach maximized output power and electric energy. Moreover, the theoretical results were well verified by the experimental tests. The present work could provide guidance for structural optimization of wavy-structured TENGs for effectively harvesting water wave energy toward the dream of large-scale blue energy.

  9. Structural conceptual models of water-conducting features at Aespoe

    International Nuclear Information System (INIS)

    Bossart, P.; Mazurek, M.; Hermansson, Jan

    1998-01-01

    Within the framework of the Fracture Classification and Characterization Project (FCC), water conducting features (WCF) in the Aespoe tunnel system and on the surface of Aespoe Island are being characterized over a range of scales. The larger-scale hierarchies of WCF are mostly constituted of fault arrays, i.e. brittle structures that accommodated episodes of shear strain. The smaller-scale WCF (contained within blocks 1 m. Structural evidence indicates that the fractures within the TRUE-1 block constitute an interconnected system with a pronounced anisotropy

  10. Effects of alagebrium, an advanced glycation endproduct breaker, on exercise tolerance and cardiac function in patients with chronic heart failure

    NARCIS (Netherlands)

    Hartog, Jasper W. L.; Willemsen, Suzan; van Veldhuisen, Dirk J.; Posma, Jan L.; van Wijk, Leen M.; Hummel, Yoran M.; Hillege, Hans L.; Voors, Adriaan A.

    Aims Advanced glycation endproducts (AGEs) have been associated with the development and progression of chronic heart failure (CHF). Advanced glycation endproducts-crosslink breakers might be of benefit in HF, but only small-scale and uncontrolled data are available. Our aim was to conduct a

  11. Transient Recovery Voltages at the Main 132kV Line Bay GIS Circuit Breaker in a Windfarm

    DEFF Research Database (Denmark)

    Arana Aristi, Iván; Okholm, J.; Holbøll, Joachim

    2011-01-01

    This paper presents the results of investigations of the Transient Recovery Voltage (TRV) across the terminals of the main 132kV Line Bay GIS circuit breaker (GIS CB) for Walney 2, second phase of the Walney Offshore Wind Farm. Several simulations were performed where the influence of different...

  12. Transient Studies in Large Offshore Wind Farms, Tak-ing Into Account Network/Circuit Breaker Interaction

    DEFF Research Database (Denmark)

    Glasdam, Jakob; Bak, Claus Leth; Hjerrild, Jesper

    2011-01-01

    to ensure reliable switching operations. Transient measurement results in an OWF are compared with simulation results in PSCAD EMTDC and DigSILENT Power Factory, where a user-defined model of the vacuum circuit breaker (VCB) is included, capable of simulating multiple prestrikes during the closing operation...... the simulation results, whereas little improvement is found in DigSILENT....

  13. Induced activity in accelerator structures, air and water

    CERN Document Server

    Stevenson, Graham Roger

    2001-01-01

    A summary is given of several 'rules of thumb' which can be used to predict the formation and decay of radionuclides in the structure of accelerators together with the dose rates from the induced radioactivity. Models are also given for the activation of gases (air of the accelerator vault) and liquids (in particular cooling water), together with their transport front the activation region to the release point. (18 refs).

  14. Dropwise chains as the elements of water fog spatial structure

    International Nuclear Information System (INIS)

    Shavlov, A.V.; Sokolov, I.V.; Romanyuk, S.N.; Dzhumandzhi, V.A.

    2013-01-01

    Video images of water fog drops were acquired under standard atmospheric conditions with weak turbulence of the environment. Pair correlation functions of the drops were performed and traces of the spatial arrangement of the drops inside the fog determined. The fog structure carriers are the drop chains with a fixed interdroplet distance. The possible influence of the drop chains on the shear viscosity and fog surface tension has been analysed.

  15. Soil-structure interaction Vol.3. Influence of ground water

    Energy Technology Data Exchange (ETDEWEB)

    Costantino, C J

    1986-04-01

    This study has been performed for the Nuclear Regulatory Commission (NRC) by the Structural Analysis Division of Brookhaven National Laboratory (BNL). The study was conducted during the fiscal year 1965 on the program entitled 'Benchmarking of Structural Engineering Problems' sponsored by NRC. The program considered three separate but complementary problems, each associated with the soil-structure interaction (551) phase of the seismic response analysis of nuclear plant facilities. The reports, all entitled Soil-Structure Interaction, are presented in three separate volumes, namely: Vol. 1 Influence of Layering by AJ Philippacopoulos, Vol. 2 Influence of Lift-Off by C.A. Miller, Vol. 3 Influence of Ground Water by C.J. Costantino. The two problems presented in Volumes 2 and 3 were conducted at the City University of New York (CUNY) under subcontract to BNL. This report, Volume 3 of the report, presents a summary of the first year's effort on the subject of the influence of foundation ground water on the SSI phenomenon. A finite element computer program was developed for the two-phased formulation of the combined soil-water problem. This formulation is based on the Biot dynamic equations of motion for both the solid and fluid phases of a typical soil. Frequency dependent interaction coefficients were generated for the two-dimensional plane problem of a rigid surface footing moving against a saturated linear soil. The results indicate that interaction coefficients are significantly modified as compared to the comparable values for a dry soil, particularly for the rocking mode of response. Calculations were made to study the impact of the modified interaction coefficients on the response of a typical nuclear reactor building. The amplification factors for a stick model placed atop a dry and saturated soil were computed. It was found that pore water caused the rocking response to decrease and translational response to increase over the frequency range of interest, as

  16. Induced activity in accelerator structures, air and water

    International Nuclear Information System (INIS)

    Stevenson, G.R.

    2001-01-01

    A summary is given of several 'rules of thumb' which can be used to predict the formation and decay of radionuclides in the structure of accelerators together with the dose rates from the induced radioactivity. Models are also given for the activation of gases (air of the accelerator vault) and liquids (in particular cooling water), together with their transport from the activation region to the release point. (author)

  17. Thermomechanical finite element analysis of hot water boiler structure

    Directory of Open Access Journals (Sweden)

    Živković Dragoljub S.

    2012-01-01

    Full Text Available The paper presents an application of the Finite Elements Method for stress and strain analysis of the hot water boiler structure. The aim of the research was to investigate the influence of the boiler scale on the thermal stresses and strains of the structure of hot water boilers. Results show that maximum thermal stresses appear in the zone of the pipe carrying wall of the first reversing chamber. This indicates that the most critical part of the boiler are weld spots of the smoke pipes and pipe carrying plate, which in the case of significant scale deposits can lead to cracks in the welds and water leakage from the boiler. The nonlinear effects were taken into account by defining the bilinear isotropic hardening model for all boiler elements. Temperature dependency was defined for all relevant material properties, i. e. isotropic coefficient of thermal expansion, Young’s modulus, and isotropic thermal conductivity. The verification of the FEA model was performed by comparing the measured deformations of the hot water boiler with the simulation results. As a reference object, a Viessmann - Vitomax 200 HW boiler was used, with the installed power of 18.2 MW. CAD modeling was done within the Autodesk Inventor, and stress and strain analysis was performed in the ANSYS Software.

  18. Record breakers

    CERN Multimedia

    Antonella Del Rosso

    2012-01-01

    In the sixties, CERN’s Fellows were but a handful of about 50 young experimentalists present on site to complete their training. Today, their number has increased to a record-breaking 500. They come from many different fields and are spread across CERN’s different activity areas.   “Diversifying the Fellowship programme has been the key theme in recent years,” comments James Purvis, Head of the Recruitment, Programmes and Monitoring group in the HR Department. “In particular, the 2005 five-yearly review introduced the notion of ‘senior’ and ‘junior’ Fellowships, broadening the target audience to include those with Bachelor-level qualifications.” Diversification made CERN’s Fellowship programme attractive to a wider audience but the number of Fellows on site could not have increased so much without the support of EU-funded projects, which were instrumental in the growth of the programme. ...

  19. Structure of Mesozooplankton Communities in the Coastal Waters of Morocco

    Science.gov (United States)

    Lidvanov, V. V.; Grabko, O. G.; Kukuev, E. I.; Korolkova, T. G.

    2018-03-01

    Mero- and holoplanktonic organisms from 23 large taxa have been detected in the coastal waters of Morocco. Seven Cladocera species and 164 Copepoda species were identified. Copepod fauna mostly consisted of oceanic epipelagic widely tropical species, but the constant species group (frequency of occurrence over 50%) included neritic and neritic-oceanic widely tropical species. The neritic community that formed a biotopic association with coastal upwelling waters and the distant-neritic community associated with Canary Current waters were the two major communities detected. The former community was characterized by a high abundance and biomass (5700 ind./m3 and 260 mg/m3) and predominance of neritic species. The trophic structure was dominated by thin filter feeders, mixed-food consumers, and small grabbers; the species structure was dominated by Paracalanus indicus, Acartia clausi, and Oncaea curta; the indices of species diversity (3.07 bit/ind.) and evenness (0.63) were relatively low. The latter community was characterized by low abundance and biomass (1150 ind./m3 and 90 mg/m3); variable biotopic, trophic, and species structure; and higher Shannon indices (3.99 bit/ind.) and Pielou (0.75). Seasonal variation of the abundance of organisms was not detected in the communities. Anomalous mesozooplankton states were observed in summer 1998 and winter 1998-1999.

  20. Gas hydrate inhibition by perturbation of liquid water structure

    Science.gov (United States)

    Sa, Jeong-Hoon; Kwak, Gye-Hoon; Han, Kunwoo; Ahn, Docheon; Lee, Kun-Hong

    2015-06-01

    Natural gas hydrates are icy crystalline materials that contain hydrocarbons, which are the primary energy source for this civilization. The abundance of naturally occurring gas hydrates leads to a growing interest in exploitation. Despite their potential as energy resources and in industrial applications, there is insufficient understanding of hydrate kinetics, which hinders the utilization of these invaluable resources. Perturbation of liquid water structure by solutes has been proposed to be a key process in hydrate inhibition, but this hypothesis remains unproven. Here, we report the direct observation of the perturbation of the liquid water structure induced by amino acids using polarized Raman spectroscopy, and its influence on gas hydrate nucleation and growth kinetics. Amino acids with hydrophilic and/or electrically charged side chains disrupted the water structure and thus provided effective hydrate inhibition. The strong correlation between the extent of perturbation by amino acids and their inhibition performance constitutes convincing evidence for the perturbation inhibition mechanism. The present findings bring the practical applications of gas hydrates significantly closer, and provide a new perspective on the freezing and melting phenomena of naturally occurring gas hydrates.

  1. Influence of ground water on soil-structure interaction

    International Nuclear Information System (INIS)

    Costantino, C.J.; Lung, R.H.; Graves, H.L.

    1987-01-01

    The study of structural response to seismic inputs has been extensively studied and, particularly with the advent of the growth of digital computer capability, has lead to the development of numerical methods of analysis which are used as standard tools for the design of structures. One aspect of the soil-structure interaction (SSI) process which has not been developed to the same degree of sophistication is the impact of ground water (or pure water) on the response of the soil-structure system. There are very good reasons for his state of affairs, however, not the least of which is the difficulty of incorporating the true constitutive behavior of saturated soils into the analysis. At the large strain end of the spectrum, the engineer is concerned with the potential development of failure conditions under the structure, and is typically interested in the onset of liquefaction conditions. The current state of the art in this area is to a great extent based on empirical methods of analysis which were developed from investigations of limited failure data from specific sites around the world. Since it is known that analytic solutions are available for only the simplest of configurations, a numerical finite element solution process was developed. Again, in keeping with typical SSI analyses, in order to make the finite element approach yield resonable results, a comparable transmitting boundary formulation was included in the development. The purpose of the transmitting boundary is, of course, to allow for the treatment of extended soil/water half-space problems. For the calculations presented herein, a simple one dimensional transmitting boundary model was developed and utilized

  2. Solvation structures of lithium halides in methanol–water mixtures

    International Nuclear Information System (INIS)

    Sarkar, Atanu; Dixit, Mayank Kumar; Tembe, B.L.

    2015-01-01

    Highlights: • Potentials of mean force for Li + -halides are calculated in methanol–water mixtures. • Stable CIP for x methanol = 1.0 becomes unstable at and below x methanol = 0.75. • The Li + ion is preferentially solvated by methanol molecules. • The halide ions are preferentially solvated by water molecules. - Abstract: The potentials of mean force (PMFs) for the ion pairs, Li + −Cl − , Li + −Br − and Li + −I − have been calculated in five methanol–water compositions. The results obtained are verified by trailing the trajectories and calculating the ion pair distance residence times. Local structures around the ions are studied using the radial distribution functions, density profiles, orientational correlation functions, running coordination numbers and excess coordination numbers. The major change in PMF is observed as the methanol mole fraction (x methanol ) is changed from 1.0 to 0.75. The stable contact ion pair occurring for x methanol = 1.0 becomes unstable at and below x methanol = 0.75. The preferential solvation data show that the halide ions are always preferentially solvated by water molecules. Although the lithium ion is preferentially solvated by methanol molecules, there is significant affinity towards water molecules as well

  3. Triple oxygen isotope systematics of structurally bonded water in gypsum

    Science.gov (United States)

    Herwartz, Daniel; Surma, Jakub; Voigt, Claudia; Assonov, Sergey; Staubwasser, Michael

    2017-07-01

    The triple oxygen isotopic composition of gypsum mother water (gmw) is recorded in structurally bonded water in gypsum (gsbw). Respective fractionation factors have been determined experimentally for 18O/16O and 17O/16O. By taking previous experiments into account we suggest using 18αgsbw-gmw = 1.0037; 17αgsbw-gmw = 1.00195 and θgsbw-gmw = 0.5285 as fractionation factors in triple oxygen isotope space. Recent gypsum was sampled from a series of 10 ponds located in the Salar de Llamara in the Atacama Desert, Chile. Total dissolved solids (TDS) in these ponds show a gradual increase from 23 g/l to 182 g/l that is accompanied by an increase in pond water 18O/16O. Gsbw falls on a parallel curve to the ambient water from the saline ponds. The offset is mainly due to the equilibrium fractionation between gsbw and gmw. However, gsbw represents a time integrated signal biased towards times of strong evaporation, hence the estimated gmw comprises elevated 18O/16O compositions when compared to pond water samples taken on site. Gypsum precipitation is associated with algae mats in the ponds with lower salinity. No evidence for respective vital effects on the triple oxygen isotopic composition of gypsum hydration water is observed, nor are such effects expected. In principle, the array of δ18Ogsbw vs. 17Oexcess can be used to: (1) provide information on the degree of evaporation during gypsum formation; (2) estimate pristine meteoric water compositions; and (3) estimate local relative humidity which is the controlling parameter of the slope of the array for simple hydrological situations. In our case study, local mining activities may have decreased deep groundwater recharge, causing a recent change of the local hydrology.

  4. Water linked 3D coordination polymers: Syntheses, structures and applications

    Science.gov (United States)

    Singh, Suryabhan; Bhim, Anupam

    2016-12-01

    Three new coordination polymers (CPs) based on Cd and Pb, [Cd(OBA)(μ-H2O)(H2O)]n1, [Pb(OBA)(μ-H2O)]n2 [where OBA=4,4'-Oxybis(benzoate)] and [Pb(SDBA)(H2O)]n.1/4DMF 3 (SDBA=4,4'-Sulfonyldibenzoate), have been synthesized and characterized. The single crystal structural studies reveal that CPs 1 and 2 have three dimensional structure. A water molecule bridges two metal centres which appears to the responsible for the dimensionality increase from 2D to 3D. Compound 3 has a supramolecular 3D structure involving water molecule and hydrogen bonds. A structural transformation is observed when 3 was heated at 100 °C or kept in methanol, forming [Pb(SDBA)]n4. Compound 4 is used as supporting matrix for palladium nanoparticles, PdNPs@4. The PdNPs@4 exhibits good catalytic activity toward the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) in the presence of NaBH4 at room temperature. Luminescence studies revealed that all CPs could be an effective sensor for nitroaromatic explosives.

  5. Urban water infrastructure asset management - a structured approach in four water utilities.

    Science.gov (United States)

    Cardoso, M A; Silva, M Santos; Coelho, S T; Almeida, M C; Covas, D I C

    2012-01-01

    Water services are a strategic sector of large social and economic relevance. It is therefore essential that they are managed rationally and efficiently. Advanced water supply and wastewater infrastructure asset management (IAM) is key in achieving adequate levels of service in the future, particularly with regard to reliable and high quality drinking water supply, prevention of urban flooding, efficient use of natural resources and prevention of pollution. This paper presents a methodology for supporting the development of urban water IAM, developed during the AWARE-P project as well as an appraisal of its implementation in four water utilities. Both water supply and wastewater systems were considered. Due to the different contexts and features of the utilities, the main concerns vary from case to case; some problems essentially are related to performance, others to risk. Cost is a common deciding factor. The paper describes the procedure applied, focusing on the diversity of drivers, constraints, benefits and outcomes. It also points out the main challenges and the results obtained through the implementation of a structured procedure for supporting urban water IAM.

  6. Electric circuit breaker comprising a plurality of vacuum interrupters simultaneously operated by a common operator

    Science.gov (United States)

    Barkan, Philip; Imam, Imdad

    1980-01-01

    This circuit breaker comprises a plurality of a vacuum-type circuit interrupters, each having a movable contact rod. A common operating device for the interrupters comprises a linearly-movable operating member. The interrupters are mounted at one side of the operating member with their movable contact rods extending in a direction generally toward the operating member. Means is provided for mechanically coupling the operating member to the contact rods, and this means comprises a plurality of insulating operating rods, each connected at one end to the operating member and at its opposite end to one of the movable contact rods. The operating rods are of substantially equal length and have longitudinal axes that converge and intersect at substantially a common point.

  7. Experimental and numerical investigation of the internal kinetics of a surf-zone plunging breaker

    DEFF Research Database (Denmark)

    Emarat, Narumon; Forehand, David I.M.; Christensen, Erik Damgaard

    2012-01-01

    Over the last couple of decades both the qualitative and quantitative understanding of breaking waves in the surf zone have greatly increased. This is due to the advances in experimental and numerical techniques. However, few comparisons between these two different investigative techniques...... for surfzone breaking waves have been reported. In this study, a comparison is made between the experimental and numerical investigation of the internal kinematics of a surf-zone plunging breaker. The full-field velocity measuring technique known as Particle Image Velocimetry (PIV) is used in the experiments...... was found for all comparisons: free-surface elevations, velocity vector maps, velocity profiles and velocity-magnitude contours. However, some small discrepancies were observed. In the free-surface elevation comparisons, a slight time lag was observed in the numerical results and it is suggested...

  8. Smooth criminal: convicted rule-breakers show reduced cognitive conflict during deliberate rule violations.

    Science.gov (United States)

    Jusyte, Aiste; Pfister, Roland; Mayer, Sarah V; Schwarz, Katharina A; Wirth, Robert; Kunde, Wilfried; Schönenberg, Michael

    2017-09-01

    Classic findings on conformity and obedience document a strong and automatic drive of human agents to follow any type of rule or social norm. At the same time, most individuals tend to violate rules on occasion, and such deliberate rule violations have recently been shown to yield cognitive conflict for the rule-breaker. These findings indicate persistent difficulty to suppress the rule representation, even though rule violations were studied in a controlled experimental setting with neither gains nor possible sanctions for violators. In the current study, we validate these findings by showing that convicted criminals, i.e., individuals with a history of habitual and severe forms of rule violations, can free themselves from such cognitive conflict in a similarly controlled laboratory task. These findings support an emerging view that aims at understanding rule violations from the perspective of the violating agent rather than from the perspective of outside observer.

  9. Transient studies in large offshore wind farms, taking into account network/circuit breaker interaction

    Energy Technology Data Exchange (ETDEWEB)

    Glasdam, Jakob; Hjerrild, Jesper; Arana, Ivan [DONG Energy Power A/S, Fredericia (Denmark); Bak, Claus Leth [Aalborg Univ. (Denmark). Inst. of Energy Technology

    2011-07-01

    Switching overvoltages (SOV) are considered a possible source of experienced component failures in existing offshore wind farms (OWFs). The inclusion of sufficiently accurate and validated models of the main components in the OWF in the simulation tool is therefore an important issue in order to ensure reliable switching operations. Transient measurement results in an OWF are compared with simulation results in PSCAD EMTDC and DigSILENT Power Factory, where a user-defined model of the vacuum circuit breaker (VCB) is included, capable of simulating multiple prestrikes during the closing operation. An analysis of the switching transients that might occur in an OWF will be made on basis of the validated model and the importance of the inclusion of a sufficient accurate representation of the VCB in the simulation tool will be described. The inclusion of the VCB model in PSCAD greatly improves the simulation results, whereas little improvement is found in DigSILENT. (orig.)

  10. Swirling flow and its influence on dc arcs in a duo-flow hybrid circuit breaker

    International Nuclear Information System (INIS)

    Kweon, K Y; Lee, H S; Yan, J D; Fang, M T C; Park, K Y

    2009-01-01

    The effects of swirling flow on the behaviour of dc SF 6 arcs in a duo-flow nozzle are computationally investigated in the electric current range 3-7 kA. A swirling flow is produced by the interaction of the magnetic field of a current-carrying coil and the plasma. Results show that a strong swirling flow is generated in regions where a large radial current density exists as a result of the conducting arc column rapidly changing its radial dimension. The presence of the swirling flow reduces the axis pressure, modifies the arc shape and slightly lowers the arc voltage (2-5%) in comparison with the case without considering the swirling flow. The different natures of swirling flows in a plasma jet/arc heater and in a hybrid circuit breaker are also discussed.

  11. Coplanar capacitance sensors for detecting water intrusion in composite structures

    International Nuclear Information System (INIS)

    Nassr, Amr A; El-Dakhakhni, Wael W; Ahmed, Wael H

    2008-01-01

    Composite materials are becoming more affordable and widely used for retrofitting, rehabilitating and repairing reinforced concrete structures designed and constructed under older specifications. However, the mechanical properties and long-term durability of composite materials may degrade severely in the presence of water intrusion. This study presents a new non-destructive evaluation (NDE) technique for detecting the water intrusion in composite structures by evaluating the dielectric properties of different composite system constituent materials. The variation in the dielectric signatures was employed to design a coplanar capacitance sensor with high sensitivity to detect such defects. An analytical model was used to study the effect of the sensor geometry on the output signal and to optimize sensor design. A finite element model was developed to validate analytical results and to evaluate other sensor design-related parameters. Experimental testing of a concrete specimen wrapped with composite laminate and containing a series of pre-induced water intrusion defects was conducted in order to validate the concept of the new technique. Experimental data showed excellent agreement with the finite element model predictions and confirmed sensor performance

  12. Investigation of structural responses of breakwaters for green water based on fluid-structure interaction analysis

    Directory of Open Access Journals (Sweden)

    Chi-Seung Lee

    2012-06-01

    Full Text Available In the present study, the structural response of breakwaters installed on container carriers against green water impact loads was numerically investigated on the basis of the fluid-structure interaction analysis. A series of numerical studies is carried out to induce breakwater collapse under such conditions, whereby a widely accepted fluid-structure interaction analysis technique is adopted to realistically consider the phenomenon of green water impact loads. In addition, the structural behaviour of these breakwaters under green water impact loads is investigated simultaneously throughout the transient analysis. A verification study of the numerical results is performed using data from actual collapse incidents of breakwaters on container carriers. On the basis of the results of a series of numerical analyses, the pressure distribution of green water was accurately predicted with respect to wave mass and velocity. It is expected that the proposed analytical methodology and predicted pressure distribution could be used as a practical guideline for the design of breakwaters on container carriers.

  13. Water linked 3D coordination polymers: Syntheses, structures and applications

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Suryabhan, E-mail: sbs.bhu@gmail.com; Bhim, Anupam

    2016-12-15

    Three new coordination polymers (CPs) based on Cd and Pb, [Cd(OBA)(μ-H{sub 2}O)(H{sub 2}O)]{sub n}1, [Pb(OBA)(μ-H{sub 2}O)]{sub n}2 [where OBA=4,4’-Oxybis(benzoate)] and [Pb(SDBA)(H{sub 2}O)]{sub n}.1/4DMF 3 (SDBA=4,4’-Sulfonyldibenzoate), have been synthesized and characterized. The single crystal structural studies reveal that CPs 1 and 2 have three dimensional structure. A water molecule bridges two metal centres which appears to the responsible for the dimensionality increase from 2D to 3D. Compound 3 has a supramolecular 3D structure involving water molecule and hydrogen bonds. A structural transformation is observed when 3 was heated at 100 °C or kept in methanol, forming [Pb(SDBA)]{sub n}4. Compound 4 is used as supporting matrix for palladium nanoparticles, PdNPs@4. The PdNPs@4 exhibits good catalytic activity toward the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) in the presence of NaBH{sub 4} at room temperature. Luminescence studies revealed that all CPs could be an effective sensor for nitroaromatic explosives. - Graphical abstract: Three new CPs based on Cd and Pb, have been synthesized and characterized. A water molecule bridges two metal centres which appears to the responsible for the dimensionality increase from 2D to 3D. One of the CP is used as supporting matrix for palladium nanoparticles, PdNPs@4. The PdNPs@4 exhibits good catalytic activity toward the reduction of 4-nitrophenol. Luminescence studies shown that all CPs could be an effective sensor for nitroaromatic explosives. - Highlights: • Three new CPs based on Cd and Pb, have been synthesized and characterized. • A water molecule bridges two metal centres which appears to the responsible for the dimensionality increase from 2D to 3D. • One of the CP is used as supporting matrix for palladium nanoparticles, PdNPs@4. • Luminescence studies shown that all CPs could be an effective sensor for nitroaromatic explosives.

  14. Studies on melt-water-structure interaction during severe accidents

    International Nuclear Information System (INIS)

    Sehgal, B.R.; Dinh, T.N.; Okkonen, T.J.; Bui, V.A.; Nourgaliev, R.R.; Andersson, J.

    1996-10-01

    Results of a series of studies, on melt-water-structure interactions which occur during the progression of a core melt-down accident, are described. The emphasis is on the in-vessel interactions and the studies are both experimental and analytical. Since, the studies performed resulted in papers published in proceedings of the technical meetings, and in journals, copies of a set of selected papers are attached to provide details. A summary of the results obtained is provided for the reader who does not, or cannot, venture into the perusal of the attached papers. (au)

  15. Studies on melt-water-structure interaction during severe accidents

    Energy Technology Data Exchange (ETDEWEB)

    Sehgal, B.R.; Dinh, T.N.; Okkonen, T.J.; Bui, V.A.; Nourgaliev, R.R.; Andersson, J. [Royal Inst. of Technology, Div. of Nucl. Power Safety, Stockholm (Sweden)

    1996-10-01

    Results of a series of studies, on melt-water-structure interactions which occur during the progression of a core melt-down accident, are described. The emphasis is on the in-vessel interactions and the studies are both experimental and analytical. Since, the studies performed resulted in papers published in proceedings of the technical meetings, and in journals, copies of a set of selected papers are attached to provide details. A summary of the results obtained is provided for the reader who does not, or cannot, venture into the perusal of the attached papers. (au).

  16. A One-Dimensional Hydrodynamic and Water Quality Model for a Water Transfer Project with Multihydraulic Structures

    OpenAIRE

    Yujun Yi; Caihong Tang; Zhifeng Yang; Shanghong Zhang; Cheng Zhang

    2017-01-01

    The long Middle Route of the South to North Water Transfer Project is composed of complex hydraulic structures (aqueduct, tunnel, control gate, diversion, culvert, and diverted siphon), which generate complex flow patterns. It is vital to simulate the flow patterns through hydraulic structures, but it is a challenging work to protect water quality and maintain continuous water transfer. A one-dimensional hydrodynamic and water quality model was built to understand the flow and pollutant movem...

  17. Simulating liquid water for determining its structural and transport properties

    International Nuclear Information System (INIS)

    Arismendi-Arrieta, Daniel; Medina, Juan S.; Fanourgakis, George S.; Prosmiti, Rita; Delgado-Barrio, Gerardo

    2014-01-01

    Molecular dynamics simulations are carried out for calculating structural and transport properties of pure liquid water, such as radial distribution functions and self-diffusion and viscosity coefficients, respectively. We employed reparameterized versions of the ab initio water potential by Niesar, Clementi and Corongiu (NCC). In order to investigate the role of the electrostatic contribution, the partial charges of the NCC model are adjusted so that to reproduce the dipole moment values of the SPC/E, SPC/Fw and TIP4P/2005 water models. The single and collective transport coefficients are obtained by employing the Green–Kubo relations at various temperatures. Additionally, in order to overcome convergence difficulties arising from the long correlation times of the stress-tensor autocorrelation functions, a previously reported fitting scheme was employed. The present results indicate that there is a significant relationship between the dipole moment value of the model, and the calculated transport coefficients. We found that by adjusting the molecular dipole moment of the NCC to the value of the TIP4P/2005, the obtained values for the self-diffusion and viscosity coefficients are in better agreement with experiment, compared to the values obtained with the original NCC model. Even though the predictions of the present model exhibits an overall correct behavior, we conclude that further improvements are still required. In order to achieve that, a careful reparameterization of the repulsion–dispersion terms of the potential model is proposed. Also, the effect of the inclusion of many-body effects such as polarizability, should also be investigated. - Highlights: ► Transport properties of liquid water are important in bio-simulations. ► Self-diffusion coefficient, shear and bulk viscosities calculations from NVE molecular dynamics simulations. ► Their comparison with experimental data provides information on intermolecular forces, and serve to develop water

  18. The Structure of Sea Water and Gelatinous Water in the Deep Ocean

    Science.gov (United States)

    Peltzer, E. T.; Walz, P. M.; Wojciechowicz, M.; Brewer, P. G.

    2016-12-01

    Gelatinous life forms are common in the deep sea and are able to maintain a careful combination of body integrity and easy fluidity of motion over a wide range of T and P. They accomplish this in part by modifying the molecular structure of water. Both the transparent body of the organism (the mesoglea) and the structure of the immediate surrounding sea water were investigated by in situ laser Raman spectroscopy at depths from 300m to 2,800m. The structure of water is reasonably well known; the basic unit is a hydrogen bonded pentamer with defined stretching and bending modes. The spectrum of the bending band is separable into two components while the stretching band spectrum is composed of five components representing both intra- and inter-molecular vibrations. The effect of temperature on the various vibrational modes is complex. While the effect of pressure on the bending modes is small, but the effect of temperature and pressure on the stretching modes is significant and can be modeled as a van `t Hoff function. Our in situ experiments were conducted using MBARI's ROV Ventana and ROV Doc Ricketts. We collected cnidarians and ctenophores into a 6 L glass detritus sampler fitted with a metal grid plate. Once the animal was captured, we introduced argon gas through the lid of the sampler displacing the contained sea water and leaving a motionless sea water free specimen for spectroscopy. The laser beam was focused through the glass wall of the container and the focal point adjusted to be inside the gelatinous body. Our results very clearly show that:i) The gelatinous mass effectively excludes salts with zero sulfate ion being detected.ii) The water bending modes are absent from the gelatinous spectra.iii) The water stretching modes are highly modified from the typical 5 band liquid pentamer structure with only 3 vibrational modes observable. These results stand in marked contrast to the familiar household gelatin which is typically derived from bovine sources

  19. Structure and dynamics of interfacial water. Role of hydratation water in the globular proteins dynamics

    International Nuclear Information System (INIS)

    Zanotti, J.M.

    1997-01-01

    This memoir includes five chapters. In the first chapter, are given the elements of the neutrons scattering theory that is used in this study. the second chapter is devoted to a general presentation of the interaction between biological macro molecule and water. The third part is dedicated to the study of the structure and the dynamics of interfacial water in the neighbouring of model systems, the vycor and the amorphous carbon. The results presented in this part are compared with these one relative to water dynamics at the C-phycocyanin surface. This study makes the object of the fourth chapter. Then, in the fifth and last chapter are discussed the results relative to the role of hydratation on the parv-albumin dynamics for which have been combined the neutron quasi elastic incoherent scattering and the nuclear magnetic resonance of the carbon 13 solid in natural abundance

  20. The effect of an advanced glycation end-product crosslink breaker and exercise training on vascular function in older individuals: a randomized factorial design trial.

    NARCIS (Netherlands)

    Oudegeest-Sander, M.H.; Olde Rikkert, M.G.M.; Smits, P.; Thijssen, D.H.J.; Dijk, A.P.J. van; Levine, B.D.; Hopman, M.T.E.

    2013-01-01

    Aging leads to accumulation of irreversible advanced glycation end-products (AGEs), contributing to vascular stiffening and endothelial dysfunction. When combined with the AGE-crosslink breaker Alagebrium, exercise training reverses cardiovascular aging in experimental animals. This study is the

  1. Scaled photographs of surf over the full range of breaker sizes on the north shore of Oahu and Jaws, Maui, Hawaiian Islands (NODC Accession 0001753)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Digital surf photographs were scaled using surfers as height benchmarks to estimate the size of the breakers. Historical databases for surf height in Hawaii are...

  2. IE Information Notice No. 85-93: Westinghouse Type DS circuit breakers, potential failure of electric closing feature because of broken spring release latch lever

    International Nuclear Information System (INIS)

    Jordan, E.L.

    1992-01-01

    On April 14, 1985, the Westinghouse Nuclear Services Integration Division (NSID) issued Technical Bulletin No. NSID-TB-85-17 advising their customers of a potential malfunction in Westinghouse Type DS Class 1E circuit breakers because of broken spring release latch levers. These electrically operated type DS breakers will not close electrically when the spring release latch lever has been broken off. Twenty-five broken levers have been reported and evaluated. This evaluation shows concentrations of incidents traceable to manufacturing in the following periods of time: early 1975, April 1976, and early 1978. This circuit breaker failure, as discussed, adversely affects the safety function (closing on demand) when the circuit breaker is used in the Engineered Safety Features Systems. However, this failure mode will not affect the safety trip function when it is used in the reactor protection system

  3. Structural characterization of the exopolysaccharides from water kefir.

    Science.gov (United States)

    Fels, Lea; Jakob, Frank; Vogel, Rudi F; Wefers, Daniel

    2018-06-01

    Water kefir is a beverage which is produced by initiating fermentation of a fruit extract/sucrose solution with insoluble kefir grains. Exopolysaccharides that are formed from sucrose play a major role in the kefir grain formation, but the exopolysaccharides in the kefir beverage and the detailed structural composition of the whole kefir grains have not been studied yet. Therefore, kefir grains and the corresponding kefir beverage were analyzed for exopolysaccharides by multiple chromatographic approaches and two-dimensional NMR spectroscopy. Furthermore, different fractionation techniques were applied to obtain further information about the exopolysaccharides. The exopolysaccharide-fraction of the investigated kefir beverage was predominantly composed of O3- and O2-branched dextrans as well as lower amounts of levans. The insoluble dextrans from the kefir grains were mostly O3-branched and contained an elevated portion of 1,3-linked glucose units compared to the soluble dextrans. The structurally different exopolysaccharides in water kefir suggest the involvement of multiple bacteria. Copyright © 2018 Elsevier Ltd. All rights reserved.

  4. Influence of organobentonite structure on toluene adsorption from water solution

    Directory of Open Access Journals (Sweden)

    Nuria Vidal

    2012-12-01

    Full Text Available Due to increase water pollution by organic compound derived from hydrocarbons such as toluene, several alternative technologies for remediation of polluted water have been originated. In this work natural bentonites were modified with cetyltrimethylammonium (CTMA+ for obtaining organophilic bentonites. The obtained CTMA-bentonites would be suitable for use as adsorbents of toluene present in water. The influence of structural characteristics of CTMA-bentonites on their adsorption capacity was studied. It was shown that adsorption of toluene depended on homogeneous interlayer space associated with arrangements of CTMA+ paraffin-monolayer and bilayer models, accompanied by a high degree ordering of the carbon chain of organic cation in both arrangements. However, packing density would not have an evident influence on the retention capacity of these materials. The solids obtained were characterized by chemical analysis, X-ray diffractions and infrared spectroscopy. Toluene adsorption was measured by UV-visible spectrophotometer. Adsorption capacity was studied by determining adsorption isotherms and adsorption coefficient calculation. The adsorption isotherms were straight-line indicating a partition phenomenon of toluene between the aqueous and organic phase present in organophilic bentonites.

  5. Flow structure of steam-water mixed spray

    International Nuclear Information System (INIS)

    Sanada, Toshiyuki; Mitsuhashi, Yuki; Mizutani, Hiroya; Saito, Takayuki

    2010-01-01

    In this study, the flow structure of a steam-water mixed spray is studied both numerically and experimentally. The velocity and pressure profiles of single-phase flow are calculated using numerical methods. On the basis of the calculated flow fields, the droplet behavior is predicted by a one-way interaction model. This numerical analysis reveals that the droplets are accelerated even after they are sprayed from the nozzle. Experimentally, the mixed spray is observed using an ultra-high-speed video camera, and the velocity field is measured by using the oarticle image velocimetry (PIV) technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, the mixing process of steam and water and the atomization process of a liquid film are observed using a transparent nozzle. High-speed photography observations reveal that the flow inside the nozzle is annular flow and that most of the liquid film is atomized at the nozzle throat and nozzle outlet. Finally, the optimum mixing method for steam and water is determined.

  6. Flow structure of steam-water mixed spray

    Energy Technology Data Exchange (ETDEWEB)

    Sanada, Toshiyuki, E-mail: ttsanad@ipc.shizuoka.ac.j [Department of Mechanical Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Shizuoka (Japan); Mitsuhashi, Yuki; Mizutani, Hiroya; Saito, Takayuki [Department of Mechanical Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Shizuoka (Japan)

    2010-12-15

    In this study, the flow structure of a steam-water mixed spray is studied both numerically and experimentally. The velocity and pressure profiles of single-phase flow are calculated using numerical methods. On the basis of the calculated flow fields, the droplet behavior is predicted by a one-way interaction model. This numerical analysis reveals that the droplets are accelerated even after they are sprayed from the nozzle. Experimentally, the mixed spray is observed using an ultra-high-speed video camera, and the velocity field is measured by using the oarticle image velocimetry (PIV) technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, the mixing process of steam and water and the atomization process of a liquid film are observed using a transparent nozzle. High-speed photography observations reveal that the flow inside the nozzle is annular flow and that most of the liquid film is atomized at the nozzle throat and nozzle outlet. Finally, the optimum mixing method for steam and water is determined.

  7. Structure design of water discharge surge tank of nuclear power plant

    International Nuclear Information System (INIS)

    Wang Fang; Hou Shuqiang

    2015-01-01

    Drainage is an important function of water discharge surge tank in nuclear power plant. There is little wall and beam inside the water discharge surge tank due to the requirement of major work, which is different from the general structure. Taking water discharge surge tank of nuclear power plant for example, concerned problems are expatiated in the structure scheme of water discharge surge tank, and important structural components are analyzed. Structural analysis model is established by ANSYS finite element analysis. A comprehensive and numerical analysis is performed for different combinations of structural model, and the internal force of structure is extracted. Finally, suggestions for design of similar structure are proposed. (authors)

  8. A new generation of medium-voltage switchboards and circuit-breakers; Eine neue Generation von Mittelspannungsschaltanlagen und -leistungsschaltern

    Energy Technology Data Exchange (ETDEWEB)

    Saemann, D.; Weichert, R.; Werner, S. [Siemens AG, Erlangen (Germany). Bereich Energieuebertragung und -verteilung

    1998-04-06

    Todays market and the trend towards globalization of business both call for new products. The authors describe the new generation of medium-voltage switchgears and circuit-breakers, along with the benefit they bring for customers. (orig./RHM) [Deutsch] Der Markt und die Globalisierung des Geschaeftes fordern neue Produkte. Die Verfasser beschreiben die neue Generation von Mittelspannungsschaltanlagen und -schaltern sowie deren Nutzen fuer die Anwender. (orig./RHM)

  9. Analytical Analysis and Case Study of Transient Behavior of Inrush Current in Power Transformer for Designing of Efficient Circuit Breakers

    Science.gov (United States)

    Harmanpreet, Singh, Sukhwinder; Kumar, Ashok; Kaur, Parneet

    2010-11-01

    Stability & security are main aspects in electrical power systems. Transformer protection is major issue of concern to system operation. There are many mall-trip cases of transformer protection are caused by inrush current problems. The phenomenon of transformer inrush current has been discussed in many papers since 1958. In this paper analytical analysis of inrush current in a transformer switched on dc and ac supply has been done. This analysis will help in design aspects of circuit breakers for better performance.

  10. Breaking wave impact forces on truss support structures for offshore wind turbines

    Science.gov (United States)

    Cieślikiewicz, Witold; Gudmestad, Ove T.; Podrażka, Olga

    2014-05-01

    Due to depletion of the conventional energy sources, wind energy is becoming more popular these days. Wind energy is being produced mostly from onshore farms, but there is a clear tendency to transfer wind farms to the sea. The foundations of offshore wind turbines may be truss structures and might be located in shallow water, where are subjected to highly varying hydrodynamic loads, particularly from plunging breaking waves. There are models for impact forces prediction on monopiles. Typically the total wave force on slender pile from breaking waves is a superposition of slowly varying quasi-static force, calculated from the Morison equation and additional dynamical, short duration force due to the impact of the breaker front or breaker tongue. There is not much research done on the truss structures of wind turbines and there are still uncertainties on slamming wave forces, due to plunging breaking waves on those structures. Within the WaveSlam (Wave slamming forces on truss structures in shallow water) project the large scale tests were carried out in 2013 at the Large Wave Flume in Forschungszentrum Küste (FZK) in Hannover, Germany. The following institutions participated in this initiative: the University of Stavanger and the Norwegian University of Science and Technology (project management), University of Gdańsk, Poland, Hamburg University of Technology and the University of Rostock, Germany and Reinertsen AS, Norway. This work was supported by the EU 7th Framework Programme through the grant to the budget of the Integrating Activity HYDRALAB IV. The main aim of the experiment was to investigate the wave slamming forces on truss structures, development of new and improvement of existing methods to calculate forces from the plunging breakers. The majority of the measurements were carried out for regular waves with specified frequencies and wave heights as well as for the irregular waves based on JONSWAP spectrum. The truss structure was equipped with both

  11. Technical-economic evaluation of the utilization of closing resistor in CEMIG extra-high voltage circuit breakers

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Angelica C.O.; Pinto, Roberto del Giudice R.; Teixeira, Jose Cleber; Fonseca, Rodrigo Assuncao; F, Junior, Sebastiao V [Companhia Energetica de Minas Gerais (CEMIG), Belo Horizonte, MG (Brazil)

    1994-12-31

    This paper presents the technical and economic studies performed by CEMIG, Companhia Energetica de Minas Gerais, Brazil, concerning the use of closing resistor in its extra-high voltage (EHV) breakers. The analysis emphasizes the advantages which could be achieved with the elimination of the resistor as far as costs and reliability are concerned. This evaluation was motivated by two 500 kV breaker failures resulting from the breakdown of the closing resistor operation mechanism. These occurrences resulted in operative restriction for CEMIG EHV system. The analysis demanded a review of the capability criteria of silicon carbide (Si C) gap arresters, which are still greatly used in CEMIG EHV System, and of the procedures to be applied when carrying out the transient studies. The investigation resulted in the prompt removal of closing resistors from circuit breakers in CEMIG extra-high voltage system generating an economy of approximately U$ 840,00 and an improvement in safety and system reliability. (author) 13 refs., 4 figs., 1 tab.

  12. Current identification in vacuum circuit breakers as a least squares problem*

    Directory of Open Access Journals (Sweden)

    Ghezzi Luca

    2013-01-01

    Full Text Available In this work, a magnetostatic inverse problem is solved, in order to reconstruct the electric current distribution inside high voltage, vacuum circuit breakers from measurements of the outside magnetic field. The (rectangular final algebraic linear system is solved in the least square sense, by involving a regularized singular value decomposition of the system matrix. An approximated distribution of the electric current is thus returned, without the theoretical problem which is encountered with optical methods of matching light to temperature and finally to current density. The feasibility is justified from the computational point of view as the (industrial goal is to evaluate whether, or to what extent in terms of accuracy, a given experimental set-up (number and noise level of sensors is adequate to work as a “magnetic camera” for a given circuit breaker. Dans cet article, on résout un problème inverse magnétostatique pour déterminer la distribution du courant électrique dans le vide d’un disjoncteur à haute tension à partir des mesures du champ magnétique extérieur. Le système algébrique (rectangulaire final est résolu au sens des moindres carrés en faisant appel à une décomposition en valeurs singulières regularisée de la matrice du système. On obtient ainsi une approximation de la distribution du courant électrique sans le problème théorique propre des méthodes optiques qui est celui de relier la lumière à la température et donc à la densité du courant. La faisabilité est justifiée d’un point de vue numérique car le but (industriel est d’évaluer si, ou à quelle précision, un dispositif expérimental donné (nombre et seuil limite de bruit des senseurs peut travailler comme une “caméra magnétique” pour un certain disjoncteur.

  13. Community Structure Of Reef Fish In Eastern Luwu Water Territory

    Directory of Open Access Journals (Sweden)

    Henny Tribuana Cinnawara

    2015-01-01

    Full Text Available Abstract One bio-indicators the condition of coral reefs is a presence of reef fish. The purpose of research is to determine species composition abundance distribution and structure of reef fish communities in these waters. Data collection was conducted in April at six locations in the north and the south eastern Luwu. Mechanical Underwater Visual Cencus UVC and transect method Line intercept Transec LIT with SCUBA equipment used for research data collection. Total reef fish species collected as many as 366 species belonging to 31 families consisting of 150 species of fish target fish consumption 10 species of indicator fish indicator species 206 types of major fissh. The most dominant indicator type of fish is Chaetodon octofasciatus while the major dominant family Pomacentridae Labridae and Apogonidae. Diversity index values ranged from 2.145 to 3.408. Dominance index C is in the range of 0.056 to 0.298. The result is expected to be a reference literature as basic data for the management of reef fish especially in the waters of eastern Luwu.

  14. Impressed current cathodic protection of deep water structures

    Digital Repository Service at National Institute of Oceanography (India)

    Venkatesan, R.

    that the cathodic protection design approaches for shallow water may not be adequate for deeper water. This paper discusses on environmental factors encountered in deep water and their effect on cathodic protection behaviour of steel. Further, current CP design...

  15. Self-commutated high-voltage direct current transmission with DC circuit breakers. Backbone for the energy policy turnaround; Selbstgefuehrte Hochspannungs-Gleichstromuebertragung mit DC-Leistungsschalter. Rueckgrat fuer die Energiewende

    Energy Technology Data Exchange (ETDEWEB)

    Goerner, Raphael [ABB AG, Mannheim (Germany). Marketing und Vertrieb, Geschaeftsbereich Grid Systems

    2013-06-01

    The 'current war' between direct current and alternating current is extended by a new location. In the future, both technologies work together in order to provide a reliable power transmission in Germany and long-term in Europe. This is based on the self-guided high-voltage direct current transmission. In conjunction with direct current circuit breakers (DC circuit breaker) the power circuit breakers may help to make the transmission grids more flexible and to minimize losses.

  16. Investigation of DC hybrid circuit breaker based on high-speed switch and arc generator

    Science.gov (United States)

    Wu, Yifei; Rong, Mingzhe; Wu, Yi; Yang, Fei; Li, Mei; Zhong, Jianying; Han, Guohui; Niu, Chunping; Hu, Yang

    2015-02-01

    A new design of DC hybrid circuit breaker based on high-speed switch (HSS) and arc generator (AG), which can drastically profit from low heat loss in normal state and fast current breaking under fault state, is presented and analyzed in this paper. AG is designed according to the magnetic pinch effect of liquid metal. By utilizing the arc voltage generated across AG, the fault current is rapidly commutated from HSS into parallel connected branch. As a consequence, the arcless open of HSS is achieved. The post-arc conducting resume time (Δ tc) of AG and the commutation original voltage (Uc), two key factors in the commutation process, are investigated experimentally. Particularly, influences of the liquid metal channel diameter (Φ) of AG, fault current rate of rise (di/dt) and Uc on Δ tc are focused on. Furthermore, a suitable Uc is determined during the current commutation process, aiming at the reliable arcless open of HSS and short breaking time. Finally, the fault current breaking test is carried out for the current peak value of 11.8 kA, and the validity of the design is confirmed by the experimental results.

  17. Insulation co-ordination aspects for power stations with generator circuit-breakers

    International Nuclear Information System (INIS)

    Sanders, M.; Koeppl, G.; Kreuzer, J.

    1995-01-01

    The generator circuit-breaker (gen. c.b.) located between the generator and the step-up transformer, is now being applied world-wide. It has become a recognized electrical component of power stations which is largely due to economical advantages and increased power station availability. Technical protection considerations for power stations have always been the reason for discussion and the object of improvement. With the use of a gen. c.b., some points of view need to be considered anew. Not only the protection system in case of fault conditions will be influenced, but also the insulation co-ordination philosophy. Below the results of some calculations concerning expected overvoltages are presented. These calculations are based on a transformer rated 264/15.5kV, 220 MVA. But the results are transferable to other power plants. Some measurements carried out on a transformer of the same rating complement the calculations. The findings may contribute to an improvement in insulation co-ordination and protection of the electrical system generator--step-up transformer

  18. Simulation and Experimental Study of Arc Column Expansion After Ignition in Low-Voltage Circuit Breakers

    Institute of Scientific and Technical Information of China (English)

    MA Qiang; RONG Mingzhe; WU Yi; XU Tiejun; SUN Zhiqiang

    2008-01-01

    The dynamicprocess of arc pressure and corresponding arc column expansion, which is the main feature after arc ignition and has a significant effect on the breaking behaviour of low -voltage circuit breakers, is studied. By constructing a three dimensional mathematical model of air arc plasma and adopting the Control Volume Method, the parameters of arc plasma including temperature and pressure axe obtained. The variations of pressure field and temperature field with time are simulated. The result indicates that there are six stages for the process of arc column expansion according to the variation of pressure in arc chamber. In the first stage, the maximal pressure locates in the region close to cathode, and in the second stage the maximal pressure shifts to the region close to the anode. In the third stage, the pressure difference between the middle of arc column and the ambient gas is very large, so the arc column begins to expand apparently. In the fourth stage, the pressure wave propagates towards both ends and the maximal pressure appears at the two ends when the pressure wave reaches both sidewalls. In the fifth stage, the pressure wave is reflected and collides in the middle of the arc chamber. In the last stage, the propagation and reflection of pressure wave will repeat several times until a steady burning state is reached. In addition, the experimental results of arc column expansion, corresponding to the arc pressure variation, are presented to verify the simulation results.

  19. Curcumin, an antibiotic resistance breaker against a multiresistant clinical isolate of Mycobacterium abscessus.

    Science.gov (United States)

    Marini, Emanuela; Di Giulio, Mara; Magi, Gloria; Di Lodovico, Silvia; Cimarelli, Maria Enrica; Brenciani, Andrea; Nostro, Antonia; Cellini, Luigina; Facinelli, Bruna

    2018-03-01

    Curcumin, a phenolic compound extracted from Curcuma longa, exerts multiple pharmacological effects, including an antimicrobial action. Mycobacterium abscessus, an environmental, nontuberculous, rapidly growing mycobacterium, is an emerging human pathogen causing serious lung infections and one of the most difficult to treat, due to its multidrug resistance and biofilm-forming ability. We wanted to evaluate the antimicrobial and antivirulence activity of curcumin and its ability to synergize with antibiotics against a clinical M. abscessus strain (29904), isolated from the bronchoaspirate of a 66-year-old woman admitted to hospital for suspected tuberculosis. Curcumin [minimum inhibitory concentrations (MIC) = 128 mg/L] was synergic (fractional inhibitory concentration index ≤0.5) with amikacin, clarithromycin, ciprofloxacin, and linezolid, to which strain 29904 showed resistance/intermediate susceptibility. Curcumin at 1/8 × MIC significantly reduced motility, whereas at 4 × MIC, it completely inhibited 4- and 8-day mature biofilms. Synergistic combinations of curcumin and amikacin induced a general reduction in microbial aggregates and substantial loss in cell viability. Disruption of 4- and 8-day biofilms was the main effect detected when curcumin was the predominant compound. The present findings support previous evidence that curcumin is a potential antibiotic resistance breaker. Curcumin, either alone or combined with antibiotics, could provide a novel strategy to combat antibiotic resistance and virulence of M. abscessus. Copyright © 2017 John Wiley & Sons, Ltd.

  20. Investigation of DC hybrid circuit breaker based on high-speed switch and arc generator.

    Science.gov (United States)

    Wu, Yifei; Rong, Mingzhe; Wu, Yi; Yang, Fei; Li, Mei; Zhong, Jianying; Han, Guohui; Niu, Chunping; Hu, Yang

    2015-02-01

    A new design of DC hybrid circuit breaker based on high-speed switch (HSS) and arc generator (AG), which can drastically profit from low heat loss in normal state and fast current breaking under fault state, is presented and analyzed in this paper. AG is designed according to the magnetic pinch effect of liquid metal. By utilizing the arc voltage generated across AG, the fault current is rapidly commutated from HSS into parallel connected branch. As a consequence, the arcless open of HSS is achieved. The post-arc conducting resume time (Δ tc) of AG and the commutation original voltage (Uc), two key factors in the commutation process, are investigated experimentally. Particularly, influences of the liquid metal channel diameter (Φ) of AG, fault current rate of rise (di/dt) and Uc on Δ tc are focused on. Furthermore, a suitable Uc is determined during the current commutation process, aiming at the reliable arcless open of HSS and short breaking time. Finally, the fault current breaking test is carried out for the current peak value of 11.8 kA, and the validity of the design is confirmed by the experimental results.

  1. Investigation of the dielectric recovery in synthetic air in a high voltage circuit breaker

    International Nuclear Information System (INIS)

    Seeger, M; Naidis, G; Steffens, A; Nordborg, H; Claessens, M

    2005-01-01

    The dielectric recovery of an axially blown arc in an experimental set-up based on a conventional HV circuit breaker was investigated both experimentally and theoretically. As a quenching gas, synthetic air was used. The investigated time range was from 10 μs to 10 ms after current zero (CZ). A fast rise in the dielectric strength during the first 100 μs, followed by a plateau and further rise later was observed. The dependences on the breaking current and pressure were determined. The measured dielectric recovery during the first 100 μs after CZ could be reproduced with good accuracy by computational fluid dynamics simulations. From that it could be deduced that the temperature decay in the axis does not depend sensitively on the pressure. The dielectric recovery during the first 100 μs scales therefore mainly with the filling pressure. The plateau in the breakdown characteristic is due to a hot vapour layer from the still evaporating PTFE nozzle surface

  2. Identification Trouble Valve Destruction On Hidroulic Press Breaker Model MPV.1620 ''DAVY-ITALlA''

    International Nuclear Information System (INIS)

    Paidjo; Pinitojo; Hafid, Abdul; Musa, Tamsil; Sagino

    2000-01-01

    To 'utility instalation examination and operation test, how long capacity to appear on the severaly valve.Torned valve on hidroulic press breaker is three sample: The first directional control valve type. 4 WE 10 H 32 / CE 24 N 9 Z4. Coil: Hydronorma GZ . 63-4 -A. 476. 24VDC, 1,46 A. For two and three is boll spriral spring valve Process operation explanation a short is oil lubrication to pump from reception center tank in to directional control valve then distributed. anything to boll spiral spring valve continued to hidroulic piston for pressed the sample job / plate thickness maximum = 16 mm with to different corner model, maximum press = 160 bar.Hindrance principle is to utilize operation test, hidroulic piston movement botom-up is smothly 0 whereas botom-down went no smoothly. Operation test property to utilize repeated resutls of the aqua. Hindrance / broken the fist estimate that the hole oil works at the directional control valve to threadbore hidroulic piston, wherever preasure not maximum to manometer indicate = 0 bar, at the moment to utilize operation. The second on the boll spiral spring valve no maximum, then to utilize servise detail and to utilize operation test againt. The results from operation test to concende destruction at the boll spiral spring valve, wherever after over houling to appear boll massive place position possessed spring wire> 3 mm to twist of couse preasure to press hidroulic piston no maximum because from leaking

  3. Sistem Proteksi Arus Bocor Menggunakan Earth Leakage Circuit Breaker Berbasis Arduino

    Directory of Open Access Journals (Sweden)

    Syukriyadin Syukriyadin

    2017-02-01

    Full Text Available Touching a live part of electrical equipment either intentionally or unintentionally can cause an electric shock. The touch can occur directly or indirectly and results in the flow of electric current through the human body to the ground. This electric current is known as the leakage current and can have fatal effects on the human body such as burns, cramps, faint and death. This paper aims to design a prototype protection model of the earth leakage circuit breaker device based on Arduino (ELCBA to protect the human body from the electrical hazards. The performance of the ELCBA is investigated by detecting the earth leakage current to the grounding system (TN.  The prototype is designed and simulated by using Proteus software. Based on the response test carried out on the prototype, it can be concluded that the ELCBA can operate properly to disconnect the electric circuit if the leakage current is detected greater than or equal to 30 mA with a time delay of 15 ms and to reclose the circuit again after 5 minutes.

  4. Transient Studies in Large Offshore Wind Farms Employing Detailed Circuit Breaker Representation

    Directory of Open Access Journals (Sweden)

    Jesper Hjerrild

    2012-07-01

    Full Text Available Switching overvoltages (SOV are considered a possible source of component failures experienced in existing offshore wind farms (OWFs. The inclusion of sufficiently accurate and validated models of the main electrical components in the OWF in the simulation tool is therefore an important issue in order to ensure reliable switching operations. Transient measurement results in an OWF are compared with simulation results in PSCAD EMTDC and DigSILENT Power Factory. A user-defined model of the vacuum circuit breaker (VCB is included in both tools, capable of simulating multiple prestrikes during the closing operation. An analysis of the switching transients that might occur in OWFs will be made on the basis of the validated model, and the importance of the inclusion of a sufficiently accurate representation of the VCB in the simulation tool will be described. The inclusion of the VCB model in PSCAD greatly improves the simulation results, whereas little improvement is found in DigSILENT. Based on the transient study it is found that the simulated SOV can be up to 60% higher at the sending end when using the detailed VCB representation compared to the built-in switch, which emphasises the need for accurate representation of the VCB for energisation studies.

  5. A No-Arc DC Circuit Breaker Based on Zero-Current Interruption

    Science.gov (United States)

    Xiang, Xuewei; Chai, Jianyun; Sun, Xudong

    2017-05-01

    A dc system has no natural current zero-crossing point, so a dc arc is more difficult to extinguish than an ac arc. In order to effectively solve the problem of the dc arc, this paper proposes a dc circuit breaker (DCCB) capable of implementing a no-arc interruption. The proposed DCCB includes a main branch consisting of a mechanical switch, a diode and a current-limiting inductor, a semi-period resonance circuit consisting of a diode, an inductor and a capacitor, and a buffer branch consisting of a capacitor, a thyristor and a resistor. The mechanical switch is opened in a zero-current state, and the overvoltage caused by the counter electromotive force of the inductor does not exist. Meanwhile, the capacitor has a buffering effect on the voltage. The rising of the voltage of the mechanical switch is slower than the rising of the insulating strength of a contact gap of the mechanical switch, resulting in the contact gap not able to be broken down. Thus, the arc cannot be generated. The simulation results show that the proposed DCCB does not generate the arc in the interruption process, the rise rate of the short circuit current can be effectively limited, and the short circuit fault point can be rapidly isolated from the dc power supply.

  6. Promoting inclusive water governance and forecasting the structure of water consumption based on compositional data: A case study of Beijing.

    Science.gov (United States)

    Wei, Yigang; Wang, Zhichao; Wang, Huiwen; Yao, Tang; Li, Yan

    2018-09-01

    Water is centrally important for agricultural security, environment, people's livelihoods, and socio-economic development, particularly in the face of extreme climate changes. Due to water shortages in many cities, the conflicts between various stakeholders and sectors over water use and allocation are becoming more common and intense. Effective inclusive governance of water use is critical for relieving water use conflicts. In addition, reliable forecasting of the structure of water usage among different sectors is a basic need for effective water governance planning. Although a large number of studies have attempted to forecast water use, little is known about the forecasted structure and trends of water use in the future. This paper aims to develop a forecasting model for the structure of water usage based on compositional data. Compositional data analysis is an effective approach for investigating the internal structure of a system. A host of data transformation methods and forecasting models were adopted and compared in order to derive the best-performing model. According to mean absolute percent error for compositional data (CoMAPE), a hyperspherical-transformation-based vector autoregression model for compositional data (VAR-DRHT) is the best-performing model. The proportions of the agricultural, industrial, domestic and environmental water will be 6.11%, 5.01%, 37.48% and 51.4% by 2020. Several recommendations for water inclusive development are provided to give a better account for the optimization of the water use structure, alleviation of water shortages, and improving stake holders' wellbeing. Overall, although we focus on groundwater, this study presents a powerful framework broadly applicable to resource management. Copyright © 2018 Elsevier B.V. All rights reserved.

  7. Structural analysis of fuel rod applied to pressurized water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Danilo P.; Pinheiro, Andre Ricardo M.; Lotto, André A., E-mail: danilo.pinheiro@marinha.mil.br [Centro Tecnológico da Marinha em São Paulo (CTMSP), São Paulo, SP (Brazil)

    2017-07-01

    The design of fuel assemblies applied to Pressurized Water Reactors (PWR) has several requirements and acceptance criteria that must be attended for licensing. In the case of PWR fuel rods, an important mechanical structural requirement is to keep the radial stability when submitted to the coolant external pressure. In the framework of the Accident Tolerant Fuel (ATF) program new materials have been studied to replace zirconium based alloys as cladding, including iron-based alloys. In this sense, efforts have been made to evaluate the behavior of these materials under PWR conditions. The present work aims to evaluate the collapse cold pressure of a stainless steel thin-walled tube similar to that used as cladding material of fuel rods by means of the comparison of numeric data, and experimental results. As a result of the simulations, it was observed that the collapse pressure has a value intermediate value between those found by regulatory requirements and analytical calculations. The experiment was carried out for the validation of the computational model using test specimens of thin-walled tubes considering empty tube. The test specimens were sealed at both ends by means of welding. They were subjected to a high pressure device until the collapse of the tubes. Preliminary results obtained from experiments with the empty test specimens indicate that the computational model can be validated for stainless steel cladding, considering the difference between collapse pressure indicated in the regulatory document and the actual limit pressure concerning to radial instability of tubes with the studied characteristics. (author)

  8. Structural basis for catalysis at the membrane-water interface.

    Science.gov (United States)

    Dufrisne, Meagan Belcher; Petrou, Vasileios I; Clarke, Oliver B; Mancia, Filippo

    2017-11-01

    The membrane-water interface forms a uniquely heterogeneous and geometrically constrained environment for enzymatic catalysis. Integral membrane enzymes sample three environments - the uniformly hydrophobic interior of the membrane, the aqueous extramembrane region, and the fuzzy, amphipathic interfacial region formed by the tightly packed headgroups of the components of the lipid bilayer. Depending on the nature of the substrates and the location of the site of chemical modification, catalysis may occur in each of these environments. The availability of structural information for alpha-helical enzyme families from each of these classes, as well as several beta-barrel enzymes from the bacterial outer membrane, has allowed us to review here the different ways in which each enzyme fold has adapted to the nature of the substrates, products, and the unique environment of the membrane. Our focus here is on enzymes that process lipidic substrates. This article is part of a Special Issue entitled: Bacterial Lipids edited by Russell E. Bishop. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. IE Information Notice No. 85-64: BBC Brown Boveri low-voltage K-line circuit breakers, with deficient overcurrent trip devices models OD-4 and 5

    International Nuclear Information System (INIS)

    Jordan, E.L.

    1992-01-01

    On May 13, 1985, BBC Brown Boveri Inc. (BBC) made a 10 CFR Part 21 report to the NRC concerning a deficiency in the Models OD-4 and OD-5 overcurrent trip devices installed on K-line circuit breakers. The affected breakers were manufactured by BBC from October 1983 to March 1985 and may have incorrect short time delay band levers (links) installed in electromechanical overcurrent trip device models OD-4 and OD-5. The incorrect link could limit the travel of the short time armature and cause the short time element to be inoperative in the maximum (MAX) band. The May 13, 1985, report recommended that all K-line circuit breakers with the OD-4 and OD-5 overcurrent trip devices and any spare OD-4 and OD-5 overcurrent trip devices that were manufactured between October 1983 and March 1985, be inspected for an incorrect short time delay band link. Licensees known by BBC to have purchased K-line breakers or spare OD-4 or OD-5 overcurrent trip devices were notified of the possible defect and instructions provided for their inspection. Enclosed is a list of utilities and related facilities that were notified by BBC. However, BBC advised the NRC that there is a possibility that other utilities could be using K-line circuit breakers with the suspect OD-4 and OD-5 overcurrent trip devices. Therefore, all licensees are being notified of this possible defect

  10. Water permeability evaluation of hollow cylindrical reinforced concrete structure by means of long-term water penetration test with pressure

    International Nuclear Information System (INIS)

    Fujiwara, Ai; Miura, Norihiko; Konishi, Kazuhiro; Tsuji, Yukikazu

    2005-01-01

    In order to evaluate initial permeability of large concrete structure, hollow cylindrical reinforced concrete structure, having 6 m in outer diameter, 6 m in height, 1 m in thickness, had been tested by means of 0.25 MPa of outside water pressure. As the results, although surface cracking and partial separation of joint had been observed at the inner side, no water permeation through concrete could be happened even after 5.5 years. After this test, concrete core specimen showed less water penetration within the depth of concrete cover of reinforcement. Thus it was verified that this concrete structure had very high water-tightness, and that the initial average water permeability was estimated to be about 1.6 x 10 -12 m/s. (author)

  11. On the upper ocean turbulent dissipation rate due to microscale breakers and small whitecaps

    Science.gov (United States)

    Banner, Michael L.; Morison, Russel P.

    2018-06-01

    In ocean wave modelling, accurately computing the evolution of the wind-wave spectrum depends on the source terms and the spectral bandwidth used. The wave dissipation rate source term which spectrally quantifies wave breaking and other dissipative processes remains poorly understood, including the spectral bandwidth needed to capture the essential model physics. The observational study of Sutherland and Melville (2015a) investigated the relative dissipation rate contributions of breaking waves, from large-scale whitecaps to microbreakers. They concluded that a large fraction of wave energy was dissipated by microbreakers. However, in strong contrast with their findings, our analysis of their data and other recent data sets shows that for young seas, microbreakers and small whitecaps contribute only a small fraction of the total breaking wave dissipation rate. For older seas, we find microbreakers and small whitecaps contribute a large fraction of the breaking wave dissipation rate, but this is only a small fraction of the total dissipation rate, which is now dominated by non-breaking contributions. Hence, for all the wave age conditions observed, microbreakers make an insignificant contribution to the total wave dissipation rate in the wave boundary layer. We tested the sensitivity of the results to the SM15a whitecap analysis methodology by transforming the SM15a breaking data using our breaking crest processing methodology. This resulted in the small-scale breaking waves making an even smaller contribution to the total wave dissipation rate, and so the result is independent of the breaker processing methodology. Comparison with other near-surface total TKE dissipation rate observations also support this conclusion. These contributions to the spectral dissipation rate in ocean wave models are small and need not be explicitly resolved.

  12. A Novel Topology of Hybrid HVDC Circuit Breaker for VSC-HVDC Application

    Directory of Open Access Journals (Sweden)

    Van-Vinh Nguyen

    2017-10-01

    Full Text Available The use of high voltage direct current (HVDC circuit breakers (CBs with the capabilities of bidirectional fault interruption, reclosing, and rebreaking can improve the reliable and safe operation of HVDC grids. Although several topologies of CBs have been proposed to perform these capabilities, the limitation of these topologies is either high on-state losses or long time interruption in the case bidirectional fault current interruption. Long time interruption results in the large magnitude of the fault current in the voltage source converter based HVDC (VSC-HVDC system due to the high rate of rise of fault current. This paper proposes a new topology of hybrid CB (HCB with lower conduction loss and lower interruption time to solve the problems. The proposed topology is based on the inverse current injection method, which uses the capacitor to enforce the fault current to zero. In the case of the bidirectional fault current interruption, the capacitor does not change its polarity after identifying the direction of fault current, which can reduce the interruption time accordingly. A switching control algorithm for the proposed topology is presented in detail. Different operation modes of proposed HCB, such as normal current mode, breaking fault current mode, discharging, and reversing capacitor voltage modes after clearing the fault, are considered in the proposed algorithm. The proposed topology with the switching control algorithm is tested in a simulation-based system. Different simulation scenarios such as temporary and permanent faults are carried out to verify the performance of the proposed topology. The simulation is performed in the Matlab/Simulink environment.

  13. Investigation of the Structures and Energy Landscapes of Thiocyanate-Water Clusters

    Directory of Open Access Journals (Sweden)

    Lewis C. Smeeton

    2017-03-01

    Full Text Available The Basin Hopping search method is used to find the global minima (GM and map the energy landscapes of thiocyanate-water clusters, (SCN−(H2On with 3–50 water molecules, with empirical potentials describing the ion-water and water-water interactions. (It should be noted that beyond n = 23, the lowest energy structures were only found in 1 out of 8 searches so they are unlikely to be the true GM but are indicative low energy structures. As for pure water clusters, the low energy isomers of thiocyanate-water clusters show a preponderance of fused water cubes and pentagonal prisms, with the weakly solvated thiocyanate ion lying on the surface, replacing two water molecules along an edge of a water polyhedron and with the sulfur atom in lower coordinated sites than nitrogen. However, by comparison with Density Functional Theory (DFT calculations, the empirical potential is found to overestimate the strength of the thiocyanate-water interaction, especially O–H⋯S, with low energy DFT structures having lower coordinate N and (especially S atoms than for the empirical potential. In the case of these finite ion-water clusters, the chaotropic (“disorder-making” thiocyanate ion weakens the water cluster structure but the water molecule arrangement is not significantly changed.

  14. Feasibility analysis of a novel hybrid-type superconducting circuit breaker in multi-terminal HVDC networks

    International Nuclear Information System (INIS)

    Khan, Umer Amir; Lee, Jong-Geon; Seo, In-Jin; Amir, Faisal; Lee, Bang-Wook

    2015-01-01

    Highlights: • A novel hybrid-type superconducting circuit breaker (SDCCB) is proposed. • SDCCB has SFCL located in the main current path to limit the fault current until the final trip signal. • SFCL in SDCCB suppressed the fast rising DC fault current for a predefined time. • SFCL significantly reduced the DC current breaking stress on SDCCB components. • SDCCB isolated the HVDC faulty line in three, four, and five converter stations MTDC. - Abstract: Voltage source converter-based HVDC systems (VSC-HVDC) are a better alternative than conventional thyristor-based HVDC systems, especially for developing multi-terminal HVDC systems (MTDC). However, one of the key obstacles in developing MTDC is the absence of an adequate protection system that can quickly detect faults, locate the faulty line and trip the HVDC circuit breakers (DCCBs) to interrupt the DC fault current. In this paper, a novel hybrid-type superconducting circuit breaker (SDCCB) is proposed and feasibility analyses of its application in MTDC are presented. The SDCCB has a superconducting fault current limiter (SFCL) located in the main current path to limit fault currents until the final trip signal is received. After the trip signal the IGBT located in the main line commutates the current into a parallel line where DC current is forced to zero by the combination of IGBTs and surge arresters. Fault simulations for three-, four- and five-terminal MTDC were performed and SDCCB performance was evaluated in these MTDC. Passive current limitation by SFCL caused a significant reduction of fault current interruption stress in the SDCCB. It was observed that the DC current could change direction in MTDC after a fault and the SDCCB was modified to break the DC current in both the forward and reverse directions. The simulation results suggest that the proposed SDCCB could successfully suppress the DC fault current, cause a timely interruption, and isolate the faulty HVDC line in MTDC.

  15. Feasibility analysis of a novel hybrid-type superconducting circuit breaker in multi-terminal HVDC networks

    Energy Technology Data Exchange (ETDEWEB)

    Khan, Umer Amir [Hanyang University, Sa-3dong, Sangrok-gu, Ansan 426-791 (Korea, Republic of); National University of Sciences and Technology, PNEC Campus, Habib Rehmatullah Road, Karachi (Pakistan); Lee, Jong-Geon; Seo, In-Jin [Hanyang University, Sa-3dong, Sangrok-gu, Ansan 426-791 (Korea, Republic of); Amir, Faisal [National University of Sciences and Technology, PNEC Campus, Habib Rehmatullah Road, Karachi (Pakistan); Lee, Bang-Wook, E-mail: bangwook@hanyang.ac.kr [Hanyang University, Sa-3dong, Sangrok-gu, Ansan 426-791 (Korea, Republic of)

    2015-11-15

    Highlights: • A novel hybrid-type superconducting circuit breaker (SDCCB) is proposed. • SDCCB has SFCL located in the main current path to limit the fault current until the final trip signal. • SFCL in SDCCB suppressed the fast rising DC fault current for a predefined time. • SFCL significantly reduced the DC current breaking stress on SDCCB components. • SDCCB isolated the HVDC faulty line in three, four, and five converter stations MTDC. - Abstract: Voltage source converter-based HVDC systems (VSC-HVDC) are a better alternative than conventional thyristor-based HVDC systems, especially for developing multi-terminal HVDC systems (MTDC). However, one of the key obstacles in developing MTDC is the absence of an adequate protection system that can quickly detect faults, locate the faulty line and trip the HVDC circuit breakers (DCCBs) to interrupt the DC fault current. In this paper, a novel hybrid-type superconducting circuit breaker (SDCCB) is proposed and feasibility analyses of its application in MTDC are presented. The SDCCB has a superconducting fault current limiter (SFCL) located in the main current path to limit fault currents until the final trip signal is received. After the trip signal the IGBT located in the main line commutates the current into a parallel line where DC current is forced to zero by the combination of IGBTs and surge arresters. Fault simulations for three-, four- and five-terminal MTDC were performed and SDCCB performance was evaluated in these MTDC. Passive current limitation by SFCL caused a significant reduction of fault current interruption stress in the SDCCB. It was observed that the DC current could change direction in MTDC after a fault and the SDCCB was modified to break the DC current in both the forward and reverse directions. The simulation results suggest that the proposed SDCCB could successfully suppress the DC fault current, cause a timely interruption, and isolate the faulty HVDC line in MTDC.

  16. Dynamics and structure of water-bitumen mixtures

    DEFF Research Database (Denmark)

    Lemarchand, Claire; Greenfield, Michael L.; Hansen, Jesper Schmidt

    2016-01-01

    Systems of Cooee bitumen and water up to 4% mass are studied by molecular dynamics simulations. The cohesive energy density of the system is shown to decrease with an increasing water content. This decrease is due mainly to an increase in the interaction energy which is not high enough to counter......Systems of Cooee bitumen and water up to 4% mass are studied by molecular dynamics simulations. The cohesive energy density of the system is shown to decrease with an increasing water content. This decrease is due mainly to an increase in the interaction energy which is not high enough...... droplets being more stable at the highest temperature simulated. The droplet is mainly located close to the saturates molecules in bitumen. Finally, it is shown that the water dynamics is much slower in bitumen than in pure water because it is governed by the diffusion of the droplet and not of the single...

  17. Slow Dynamics and Structure of Supercooled Water in Confinement

    Directory of Open Access Journals (Sweden)

    Gaia Camisasca

    2017-04-01

    Full Text Available We review our simulation results on properties of supercooled confined water. We consider two situations: water confined in a hydrophilic pore that mimics an MCM-41 environment and water at interface with a protein. The behavior upon cooling of the α relaxation of water in both environments is well interpreted in terms of the Mode Coupling Theory of glassy dynamics. Moreover, we find a crossover from a fragile to a strong regime. We relate this crossover to the crossing of the Widom line emanating from the liquid-liquid critical point, and in confinement we connect this crossover also to a crossover of the two body excess entropy of water upon cooling. Hydration water exhibits a second, distinctly slower relaxation caused by its dynamical coupling with the protein. The crossover upon cooling of this long relaxation is related to the protein dynamics.

  18. Reactor water spontaneous circulation structure in reactor pressure vessel

    International Nuclear Information System (INIS)

    Takahashi, Kazumi

    1998-01-01

    The gap between the inner wall of a reactor pressure vessel of a BWR type reactor and a reactor core shroud forms a down comer in which reactor water flows downwardly. A feedwater jacket to which feedwater at low temperature is supplied is disposed at the outer circumference of the pressure vessel just below a gas/water separator. The reactor water at the outer circumferential portion just below the air/water separator is cooled by the feedwater jacket, and the feedwater after cooling is supplied to the feedwater entrance disposed below the feedwater jacket by way of a feedwater introduction line to supply the feedwater to the lower portion of the down comer. This can cool the reactor water in the down comer to increase the reactor water density in the down comer thereby forming strong downward flows and promote the recycling of the reactor water as a whole. With such procedures, the reactor water can be recycled stably only by the difference of the specific gravity of the reactor water without using an internal pump. In addition, the increase of the height of the pressure vessel can be suppressed. (I.N.)

  19. Feasibility of a continuous surface mining machine using impact breakers. First quarterly report, October 1-December 31, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Fisk, A. T.

    1980-01-01

    This is the first quarterly report on the efforts to evaluate the feasibility of excavating coal and overburden from surface mines using impact breakers. The initial stages of the project are devoted to a literature search, equipment selection, test site selection, and conceptual test system design. Hence, this report details the progress made in these areas; the next quarter will see the finalization of Phase I. Included as appendices to this report are FMA internal reports on the individual mines visited. These reports are the basis of the test site selection, and have been censored here to remove data the mine operators deemed as confidential.

  20. The Role of Infragravity Waves in Near-Bed Cross-Shore Sediment Flux in the Breaker Zone

    Directory of Open Access Journals (Sweden)

    Samantha Kularatne

    2014-08-01

    Full Text Available Results from a series of field experiments, conducted to investigate the influence of infragravity waves (from wave groups, ripple type and location relative to the breaker line on cross-shore suspended sediment flux close to the sea bed in nearshore environments, are presented. The field data were collected from Cable Beach (Broome and Mullaloo Beach in Western Australia and Chilaw in Sri Lanka. These beaches experience different incident wave, tidal and morphological conditions, with Cable Beach having a 10-m spring tidal range, whilst the other two beaches have tidal ranges <1.0 m. Measurements included simultaneous records of surface elevation, two-dimensional horizontal current velocities and suspended sediment concentrations, together with half-hourly observations of the seabed topography. Although most of the data sets were obtained just outside of the surf zone, a few results from inside of the surf zone were also included. A significant correlation between wave groups and suspended sediment concentration was found at all of the measurement sites, either with or without bed ripples. The direction and magnitude of cross-shore suspended sediment flux varied with location with respect to the breaker line; however, other parameters, such as bed ripples and velocity skewness, could have influenced this result. In Broome, where the measurement location with respect to the breaker line varied with the tidal cycle, the cross-shore sediment flux due to swell waves was shoreward inside and just outside of the surf zone and seaward farther offshore of the breaker line. Further, sediment flux due to swell waves was onshore when the seabed was flat and offshore over post-vortex ripples. Sediment flux due to swell waves was onshore when the normalised velocity skewness towards the shore was high (positive; the flux was offshore when the skewness was lower, but positive, suggesting the influence of other parameters, such as ripples and grain size. The

  1. Simulation of the Process of Arc Energy-Effect in High Voltage Auto-Expansion SF6 Circuit Breaker

    International Nuclear Information System (INIS)

    Rong Mingzhe; Yang Qian; Fan Chunduo

    2005-01-01

    A new magnetic hydro-dynamics (MHD) model of arc in H.V. auto-expansion SF 6 circuit breaker that takes into consideration nozzle ablation due to both radiation and thermal conduction is presented in this paper. The effect of PTFE (polytetrafluorethylene) vapor is considered in the mass, momentum and energy conservation equations of the constructed model. Then, the gas flow fields with and without conduction considered are simulated. By comparing the aforementioned two results, it is indicated that the arc's maximal temperature with conduction considered is 90 percent of that without considering conduction

  2. A One-Dimensional Hydrodynamic and Water Quality Model for a Water Transfer Project with Multihydraulic Structures

    Directory of Open Access Journals (Sweden)

    Yujun Yi

    2017-01-01

    Full Text Available The long Middle Route of the South to North Water Transfer Project is composed of complex hydraulic structures (aqueduct, tunnel, control gate, diversion, culvert, and diverted siphon, which generate complex flow patterns. It is vital to simulate the flow patterns through hydraulic structures, but it is a challenging work to protect water quality and maintain continuous water transfer. A one-dimensional hydrodynamic and water quality model was built to understand the flow and pollutant movement in this project. Preissmann four-point partial-node implicit scheme was used to solve the governing equations in this study. Water flow and pollutant movement were appropriately simulated and the results indicated that this water quality model was comparable to MIKE 11 and had a good performance and accuracy. Simulation accuracy and model uncertainty were analyzed. Based on the validated water quality model, six pollution scenarios (Q1 = 10 m3/s, Q2 = 30 m3/s, and Q3 = 60 m3/s for volatile phenol (VOP and contaminant mercury (Hg were simulated for the MRP. Emergent pollution accidents were forecasted and changes of water quality were analyzed according to the simulations results, which helped to guarantee continuously transferring water for a large water transfer project.

  3. TAPWAT: Definition structure and applications for modelling drinking water treatment

    NARCIS (Netherlands)

    Versteegh JFM; Gaalen FW van; Rietveld LC; Evers EG; Aldenberg TA; Cleij P; Technische Universiteit Delft; LWD

    2001-01-01

    The 'Tool for the Analysis of the Production of drinking WATer' (TAPWAT) model has been developed for describing drinking-water quality in integral studies in the context of the Environmental Policy Assessment of the RIVM. The model consists of modules that represent individual steps in a treatment

  4. Probing water structure and transport in proton exchange membranes

    NARCIS (Netherlands)

    Ling, X.

    2018-01-01

    Proton exchange membrane fuel cells (PEMFCs) have attracted tremendous attention as alternative energy sources because of their high energy density and practically zero greenhouse gas emission - water is their only direct by-product. Critical to the function of PEMFCs is fast proton and water

  5. Diagnosis technique for the detection of mechanical faults in power breakers; Tecnica de diagnostico para la deteccion de fallas mecanicas en interruptores de potencia

    Energy Technology Data Exchange (ETDEWEB)

    Linan, Roberto; Perez, Marciano; Estrada, J. Manuel [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1996-12-31

    This article reports a non-invasive diagnosis technique for the detection of mechanical faults in power breakers, supporting it with the recording and analysis of vibration signals of the equipment under test. Also, an assessment of four breakers using this technique is presented. [Espanol] En el presente articulo se reporta una tecnica de diagnostico no invasiva para detectar fallas mecanicas en interruptores de potencia, apoyandose en el registro y analisis de senales de vibracion del equipo bajo prueba. Asimismo, se presenta la evaluacion de cuatro interruptores usando esta tecnica.

  6. Diagnosis technique for the detection of mechanical faults in power breakers; Tecnica de diagnostico para la deteccion de fallas mecanicas en interruptores de potencia

    Energy Technology Data Exchange (ETDEWEB)

    Linan, Roberto; Perez, Marciano; Estrada, J Manuel [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1997-12-31

    This article reports a non-invasive diagnosis technique for the detection of mechanical faults in power breakers, supporting it with the recording and analysis of vibration signals of the equipment under test. Also, an assessment of four breakers using this technique is presented. [Espanol] En el presente articulo se reporta una tecnica de diagnostico no invasiva para detectar fallas mecanicas en interruptores de potencia, apoyandose en el registro y analisis de senales de vibracion del equipo bajo prueba. Asimismo, se presenta la evaluacion de cuatro interruptores usando esta tecnica.

  7. Power ion beam production in a magnetic-insulated diode placed in a circuit with an inductive storage with a plasmoerosion circuit breaker

    International Nuclear Information System (INIS)

    Anan'in, P.S.; Karpov, V.B.; Krasik, Ya.E.; Paul', E.A.

    1991-01-01

    Consideration is given to results of experimental studies of modes of operation of plasma current breaker and magnetic insulated diode, placed parallel in a circuit with inductive storage and microsecond generator, as well as parameters of high-power ion beam, generated in gas-filled diode. Magnetic field of mirror configuration, which enabled to locate the gas-filled diode dose to breaking region was used for decrease of electrodynamic plasma transfer. It is shown that time delay (of the order of ten and more) of power maximum in gas-filled diode with respect to power maximum in plasma breaker is observed when using passive plasma source on anode

  8. Procedure for developing biological input for the design, location, or modification of water-intake structures

    Energy Technology Data Exchange (ETDEWEB)

    Neitzel, D.A.; McKenzie, D.H.

    1981-12-01

    To minimize adverse impact on aquatic ecosystems resulting from the operation of water intake structures, design engineers must have relevant information on the behavior, physiology and ecology of local fish and shellfish. Identification of stimulus/response relationships and the environmental factors that influence them is the first step in incorporating biological information in the design, location or modification of water intake structures. A procedure is presented in this document for providing biological input to engineers who are designing, locating or modifying a water intake structure. The authors discuss sources of stimuli at water intakes, historical approaches in assessing potential/actual impact and review biological information needed for intake design.

  9. IMPROVING STRUCTURAL INTEGRITY MONITORING CAPABILITY FOR WATER MAINS: COLLABORATION EFFORTS AND OPPORTUNITIES

    Science.gov (United States)

    The structural integrity of the approximately 1,000,000 miles of U.S. water mains is important to both immediate and long-term drinking water quality and availability. As pipes wear out, leaks and main breaks increase, as well as the associated occurrences of water loss and low-...

  10. The constructional design of cooling water discharge structures on German rivers

    International Nuclear Information System (INIS)

    Geldner, P.; Zimmermann, C.

    1975-11-01

    The present compilation of structures for discharging cooling water from power stations into rivers is an attempt to make evident developments in the constructional design of such structures and to give reasons for special structure shapes. A complete collection of all structures built in Germany, however, is difficult to realize because of the large number of power stations. For conventionally heated power stations therefore only a selection was made, while nuclear power stations in operation or under construction could almost completely be taken into account. For want of sufficient quantities of water for river water cooling, projected power stations are now almost exclusively designed for closed-circuit cooling so that the required discharge structures for elutrition water from the cooling towers as well as for the emergency and secondary cooling circuits have to be designed only for small amounts of water. (orig./HP) [de

  11. Mathematical Model to Predict the Permeability of Water Transport in Concrete Structure

    OpenAIRE

    Solomon Ndubuisi Eluozo

    2013-01-01

    Mathematical model to predict the permeability of water transport in concrete has been established, the model is to monitor the rate of water transport in concrete structure. The process of this water transport is based on the constituent in the mixture of concrete. Permeability established a relation on the influence of the micropores on the constituent that made of concrete, the method of concrete placement determine the rate of permeability deposition in concrete structure, permeability es...

  12. Water-mediated ionic interactions in protein structures

    Indian Academy of Sciences (India)

    ISHWARYA( R SARANI( M KIRTI VAISHNAVI and K SEKAR. Supplementary table 1. List of complete water-mediated ionic interactions formed by different combinations of charged atoms and their corresponding occurrences. S. No. Type.

  13. Chelation: A Fundamental Mechanism of Action of AGE Inhibitors, AGE Breakers, and Other Inhibitors of Diabetes Complications

    Energy Technology Data Exchange (ETDEWEB)

    Nagai, Rhoji; Murray, David B.; Metz, Thomas O.; Baynes, John

    2012-03-01

    Advanced glycation or glycoxidation end-products (AGE) increase in tissue proteins with age, and their rate of accumulation is increased in diabetes, nephropathy and inflammatory diseases. AGE inhibitors include a range of compounds that are proposed to act by trapping carbonyl and dicarbonyl intermediates in AGE formation. However, some among the newer generation of AGE inhibitors lack reactive functional groups that would trap reaction intermediates, indicating an alternative mechanism of action. We propose that AGE inhibitors function primarily as chelators, inhibiting metal-catalyzed oxidation reactions. The AGE-inhibitory activity of angiotensin-converting enzyme inhibitors and angiotensin receptor blockers is also consistent with their chelating activity. Finally, compounds described as AGE breakers, or their hydrolysis products, also have strong chelating activity, suggesting that these compounds also act through their chelating activity. We conclude that chelation is the common, and perhaps the primary, mechanism of action of AGE inhibitors and breakers, and that chronic, mild chelation therapy should prove useful in treatment of diabetes and age-related diseases characterized by oxidative stress, inflammation and increased chemical modification of tissue proteins by advanced glycoxidation and lipoxidation end-products.

  14. Feasibility analysis of a novel hybrid-type superconducting circuit breaker in multi-terminal HVDC networks

    Science.gov (United States)

    Khan, Umer Amir; Lee, Jong-Geon; Seo, In-Jin; Amir, Faisal; Lee, Bang-Wook

    2015-11-01

    Voltage source converter-based HVDC systems (VSC-HVDC) are a better alternative than conventional thyristor-based HVDC systems, especially for developing multi-terminal HVDC systems (MTDC). However, one of the key obstacles in developing MTDC is the absence of an adequate protection system that can quickly detect faults, locate the faulty line and trip the HVDC circuit breakers (DCCBs) to interrupt the DC fault current. In this paper, a novel hybrid-type superconducting circuit breaker (SDCCB) is proposed and feasibility analyses of its application in MTDC are presented. The SDCCB has a superconducting fault current limiter (SFCL) located in the main current path to limit fault currents until the final trip signal is received. After the trip signal the IGBT located in the main line commutates the current into a parallel line where DC current is forced to zero by the combination of IGBTs and surge arresters. Fault simulations for three-, four- and five-terminal MTDC were performed and SDCCB performance was evaluated in these MTDC. Passive current limitation by SFCL caused a significant reduction of fault current interruption stress in the SDCCB. It was observed that the DC current could change direction in MTDC after a fault and the SDCCB was modified to break the DC current in both the forward and reverse directions. The simulation results suggest that the proposed SDCCB could successfully suppress the DC fault current, cause a timely interruption, and isolate the faulty HVDC line in MTDC.

  15. Exploring the effectiveness of sustainable water management structures in the Upper Pungwe river basin

    Science.gov (United States)

    Nyikadzino, B.; Chibisa, P.; Makurira, H.

    The study endeavoured to assess the effectiveness of stakeholder structures and their participation in sustainable water resources management in the Upper Pungwe river basin shared by Zimbabwe and Mozambique. The study sought to assess the level and effectiveness of stakeholder, gender and the vulnerable groups representation in sustainable water resources management as well as the whole stakeholder participation process. The study employed both qualitative and quantitative methods for data collection and analysis. Sampling data was obtained from 15 stakeholder representatives (councillors) constituting Pungwe Subcatchment Council, 30 water users ranging from small scale to large scale users and professionals in water resources management. Two different questionnaires and three structured interviews were administered during the study. Water permit database, financial reports and other source documents were also analysed. The study established that the sustainability and effectiveness of stakeholder structures and their participation in water resources management is being compromised by lack of stakeholder awareness. Water utilisation is very high in the subcatchment (99%) while women participation is still low (20%). The study therefore recommends the use of quotas for the participation of women in stakeholder structures. Stakeholder structures are encouraged to intensify stakeholder awareness on issues of river protection, efficient water use and pollution control. Further research is recommended to be carried out on the effectiveness of stakeholder structures in combating water pollution and enhancing river protection.

  16. The structure of water quality monitoring in the disaster area

    International Nuclear Information System (INIS)

    Yoshida, Nobuo

    2012-01-01

    Described are monitoring systems of water environment at usual times and after the 2011 Tohoku Earthquake and Tsunami Disaster, and measures taken by the Ministry of the Environment (ME) for radioactive substances in the water environment. At usual times, the monitoring of hazardous substance in water environment is conducted by local governments. At/after the Disaster, ME conducted the monitoring investigation concerning the environmental quality standards and toxicants like dioxins in the river, sea and groundwater from late May to late July, 2011 because undesirable effects on health and life of the residents had been feared due to possible leak of hazardous substances in public water area and underground water of victim prefectures, Aomori, Iwate, Miyagi, Fukushima and Ibaraki. As the results, no high contamination due to the Disaster was found, and a part of regions exhibited the slight chemical contamination, where continuous and additional monitoring was to be kept locally with guidance of drinking the concerned well water. ME measured radioactive iodine and cesium at 29 places of Fukushima rivers to find <65 and <30,000 Bq/kg, respectively, of 4 spots of river bed material alone (late May); then Cs 32 Bq/L in water at 1 spot and <26,000 Bq/kg in bed at all places after rain (early July). In groundwater, no radioactive nuclides above were detected in any of 111 places of Fukushima Prefecture (late June to early August). Cs was not found in sea water of 9 places of concerned prefectures, but was in the sea bottom soil, <1,380 Bq/kg (middle June). As well, local governments measured those two radioactive nuclides in water and ambient dose rate of 551 sea bathing beaches (late May to early Oct.) and found only one beach (Iwaki City, Fukushima) inappropriate for swimming play. Hereafter, ME is still to investigate the bed material of public water area and to continue to monitor the marine environment in cooperation with related authorities. (T.T.)

  17. Trends and Consumption Structures of China’s Blue and Grey Water Footprint

    Directory of Open Access Journals (Sweden)

    Huixiao Wang

    2018-04-01

    Full Text Available Water footprint has become a common method to study the water resources utilization in recent years. By using input–output analysis and dilution theory, the internal water footprint, blue water footprint and grey water footprint of China from 2002 to 2012 were estimated, and the consumption structure of water footprint and virtual water trade were analyzed. The results show: (1 From 2002 to 2012, the average annual internal water footprint was 3.83 trillion m3 in China, of which the blue water footprint was 0.25 trillion m3, and the grey water footprint was 3.58 trillion m3 (with Grade III water standard accounting; both the internal water footprint and grey water footprint experienced decreasing trends from 2002 to 2012, except for a dramatic increase in 2010; (2 Average annual virtual blue water footprint was the greatest in agriculture (39.2%, while tertiary industry (27.5% and food and tobacco processing (23.7% were the top two highest for average annual virtual grey water footprint; (3 Virtual blue water footprint in most sectors showed increasing trends due to the increase of final demand, while virtual grey water footprint in most sectors showed decreasing trends due to the decreases of total return water coefficients and conversion coefficients of virtual grey water footprint; (4 For water resources, China was self-reliant: the water used for producing the products and services to meet domestic consumption was taken domestically; meanwhile, China exported virtual water to other countries, which aggravated the water stress in China.

  18. Structural evaluation report of piping and support structure for design-changed hot-water layer system

    International Nuclear Information System (INIS)

    Ryu, Jeong Soo

    1998-05-01

    After hot-water layer system had been installed, the verification tests to reduce the radiation level at the top of reactor pool were performed many times. The major goal of this report is to assess the structural integrity on the piping and the support structures of design-changed hot-water layer system. The piping stress analysis was performed by using ADLPIPE program for the pump suction line and the pump discharge line subjected to dead weight, pressure, thermal expansion and seismic loadings. The stress analysis of the support structure was carried out using the reaction forces obtained from the piping stress analysis. The results of structural evaluation for the pipings and the support structures showed that the structural acceptance criteria were satisfied, in compliance with ASME, subsection ND for the piping and subsection NF for the support structures. Therefore based on the results of the analysis and the design, the structural integrity on the piping and the support structures of design-changed hot-water system was proved. (author). 9 refs., 9 tabs., 14 figs

  19. Structural material anomaly detection system using water chemistry data

    International Nuclear Information System (INIS)

    Asakura, Yamato; Nagase, Makoto; Uchida, Shunsuke; Ohsumi, Katsumi.

    1992-01-01

    The concept of an advanced water chemistry diagnosis system for detection of anomalies and preventive maintenance of system components is proposed and put into a concrete form. Using the analogy to a medical inspection system, analyses of water chemistry change will make it possible to detect symptoms of anomalies in system components. Then, correlations between water chemistry change and anomaly occurrence in the components of the BWR primary cooling system are analyzed theoretically. These fragmentary correlations are organized and reduced to an algorithm for the on-line diagnosis system using on-line monitoring data, pH and conductivity. By using actual plant data, the on-line diagnosis model system is verified to be applicable for early and automatic finding of the anomaly cause and for timely supply of much diagnostic information to plant operators. (author)

  20. Structural material anomaly detection system using water chemistry data, (7)

    International Nuclear Information System (INIS)

    Nagase, Makoto; Uchida, Shunsuke; Asakura, Yamato; Ohsumi, Katsumi.

    1993-01-01

    A method to detect small changes in water quality and diagnose their causes by analyzing on-line conductivity and pH data was proposed. Laboratory tests showed that effective noise reduction of measured on-line data could be got by using median filter to detect small changes of conductivity ; a relative change of 0.001 μS/cm was distinguishable. By simulating the changes of pH and conductivity in the reactor water against a small concentration change of sodium ion or sulfate ion in the feedwater, it was found that an adequate elapsed time for the diagnosis was 4 h from the start of the concentration change. A conductivity difference of 0.001 μS/cm in the reactor water made it theoretically possible to distinguish between a sodium ion concentration change of 4.6 ppt and a sulfate ion concentration change of 9.6 ppt in the feedwater. (author)

  1. Emergence of the Coherent Structure of Liquid Water

    Directory of Open Access Journals (Sweden)

    Ivan Bono

    2012-07-01

    Full Text Available We examine in some detail the interaction of water molecules with the radiative electromagnetic field and find the existence of phase transitions from the vapor phase to a condensed phase where all molecules oscillate in unison, in tune with a self-trapped electromagnetic field within extended mesoscopic space regions (Coherence Domains. The properties of such a condensed phase are examined and found to be compatible with the phenomenological properties of liquid water. In particular, the observed value of critical density is calculated with good accuracy.

  2. Biotechnologies based on simple and structured superlight water for use in biopharmaceutical and biocosmetic field

    International Nuclear Information System (INIS)

    Manzatu, I.; Olariu, L.; Rusu, M.; Zamfir, S.

    2000-01-01

    S.C. Biotehnos S.A. has developed studies to obtain structured aqueous solutions to find biotechnologies that were patented both in this country and abroad. An increasing interest concerning the action of superlight water on biological systems as well as the investigation of possibility of incorporating this type of water in pharmaceutical and cosmetic products encouraged research upon the processes of structuring the deuterium depleted water to establish non-conventional modern biotechnologies. Thus, physico-chemical parameters of interest (pH-value, conductivity, redox potential) were determined for the superlight water systems resulting from structuration process. Also, these studies have dealt with the effects of superlight water and structured aqueous solutions upon cellular breeding, studies of major importance in cell physiology

  3. Dielectric study on hierarchical water structures restricted in cement and wood materials

    International Nuclear Information System (INIS)

    Abe, Fumiya; Nishi, Akihiro; Saito, Hironobu; Asano, Megumi; Watanabe, Seiei; Kita, Rio; Shinyashiki, Naoki; Yagihara, Shin; Fukuzaki, Minoru; Sudo, Seiichi; Suzuki, Youki

    2017-01-01

    Dielectric relaxation processes for mortar observed by broadband dielectric spectroscopy were analyzed in the drying and hydration processes for an aging sample in the frequency region from 1 MHz up to 2 MHz. At least two processes for structured water in the kHz frequency region and another mHz relaxation process affected by ionic behaviors were observed. Comparison of the relaxation parameters obtained for the drying and hydration processes suggests an existence of hierarchical water structures in the exchange of water molecules, which are originally exchanged from free water observed at around 20 GHz. The water molecules reflected in the lower frequency process of the two kHz relaxation processes are more restricted and take more homogeneous structures than the higher kHz relaxation process. These structured water usually hidden in large ionic behaviors for wood samples was observed by electrodes covered by a thin Teflon film, and hierarchical water structures were also suggested for wood samples. Dielectric spectroscopy technique is an effective tool to analyze the new concept of hierarchical water structures in complex materials. (paper)

  4. A study on the water permeability of concrete structures

    International Nuclear Information System (INIS)

    Loadsman, R.V.C.; Acres, D.H.; Stokes, C.J.; Wadeson, L.

    1988-03-01

    This report forms part of the DoE's research programme on the disposal of nuclear waste. The information available on the permeability of concrete and the effects of various factors on this value are reviewed. The effect of defects on the overall permeability of concrete structures is examined and the recorded performance of a range of existing concrete structures is considered with identification of some of the factors that are significant in practice. Deficiencies in the information available on this subject are identified and recommendations for further work are made including a list of structures suitable for future monitoring. (author)

  5. Water structure near single and multi-layer nanoscopic hydrophobic ...

    Indian Academy of Sciences (India)

    Wintec

    We have performed a series of molecular dynamics simulations of water containing two nano- scopic hydrophobic ..... the simulation for l00 ps for equilibration during which ... was further run for a production phase of 100–200 ps depending on ...

  6. TAPWAT: Definition structure and applications for modelling drinking water treatment

    NARCIS (Netherlands)

    Versteegh JFM; van Gaalen FW; Rietveld LC; Evers EG; Aldenberg TA; Cleij P; LWD

    2001-01-01

    Het model TAPWAT (Tool for the Analysis of the Production of drinking WATer), is ontwikkeld om de drinkwaterkwaliteit te beschrijven voor integrale studies in het kader van het planbureau Milieu en Natuur van het RIVM. Het model bestaat uit modules die de individuele zuiveringsstappen van het

  7. Generation of shockwave and vortex structures at the outflow of a boiling water jet

    Science.gov (United States)

    Alekseev, M. V.; Lezhnin, S. I.; Pribaturin, N. A.; Sorokin, A. L.

    2014-12-01

    Results of numerical simulation for shock waves and generation of vortex structures during unsteady outflow of boiling liquid jet are presented. The features of evolution of shock waves and vortex structures formation during unsteady outflow of boiling water are compared with corresponding structures during unsteady gas outflow.

  8. Networked Water Citizen Organisations in Spain: Potential for Transformation of Existing Power Structures in Water Management

    Directory of Open Access Journals (Sweden)

    Nuria Hernández-Mora

    2015-06-01

    Full Text Available The shift from hierarchical-administrative water management toward more transparent, multi-level and participated governance approaches has brought about a shifting geography of players, scales of action, and means of influencing decisions and outcomes. In Spain, where the hydraulic paradigm has dominated since the early 1920s, participation in decisions over water has traditionally been limited to a closed water policy community, made up of economic water users, primarily irrigator associations and hydropower generators, civil engineering corps and large public works companies. The river basin planning process under the Water Framework Directive of the European Union presented a promise of transformation, giving access to non-economic water users, environmental concerns and the wider public to water-related information on planning and decision-making. This process coincided with the consolidation of the use of Information and Communication Technologies (ICTs by the water administration, with the associated potential for information and data generation and dissemination. ICTs are also increasingly used by citizen groups and other interested parties as a way to communicate, network and challenge existing paradigms and official discourses over water, in the broader context of the emergence of 'technopolitics'. This paper investigates if and in what way ICTs may be providing new avenues for participated water resources management and contributing to alter the dominating power balance. We critically analyse several examples where networking possibilities provided by ICTs have enabled the articulation of interest groups and social agents that have, with different degrees of success, questioned the existing hegemonic view over water. The critical review of these cases sheds light on the opportunities and limitations of ICTs, and their relation with traditional modes of social mobilisation in creating new means of societal involvement in water

  9. Investigating Characteristics of N2, CO2 and CF3I in Contrast to High Current Arcs in Circuit Breakers to Choose a Suitable Substitute for SF6

    Directory of Open Access Journals (Sweden)

    V. Abbasi

    2017-09-01

    Full Text Available Specific and sensitive operation of circuit breakers makes an individual position for them in power networks. Circuit breakers are at the central gravity of variations and execution operations. Therefore, an optimum operation is the main reason to investigate about new gases to be used in MV and HV circuit breakers instead of SF6. The arc process has enormous complexity because of hydrodynamic and electromagnetic combination equations, and that is the exact reason why most of the previous simulations were processed in two-dimension analysis. But, in this paper a three-dimension simulation with sufficient results has been fully discussed. Different evaluations on the other gases have taken under study in order to find a suitable substitute instead of SF6 gas, which can also bring an optimum operation for the breakers and can be even friendly with the environment. The simulations have been carried out based on the finite element method (FEM and magneto-hydrodynamic equations. A three-dimension model under the transient state has been chosen in the simulations to find a feasible substitute for SF6 gas. The main factors of the analysis are threefold as follows: arc temperature on the different regions, the cooling ability and arc resistance. CO2, CF3I and N2 are nominated to substitute the SF6 gas and their effects on cooling ability, nozzle evaporation, contacts erosion and arc resistance will be discussed.

  10. Leisure/Crime, Immaterial Labor, and the Performance of the Teenage Girl in Harmony Korine’s Spring Breakers and Sofia Coppola’s The Bling Ring

    NARCIS (Netherlands)

    Wilkinson, M.

    2017-01-01

    Harmony Korine’s Spring Breakers (2012) and Sofia Coppola’s The Bling Ring (2013) introduced audiences to girls exploring criminal behavior both for and as leisure. The films introduce an idea of leisure/crime: criminal acts that appear to develop as natural, fruitful extensions of leisure

  11. Thermodynamic and structural signatures of water-driven methane-methane attraction in coarse-grained mW water.

    Science.gov (United States)

    Song, Bin; Molinero, Valeria

    2013-08-07

    Hydrophobic interactions are responsible for water-driven processes such as protein folding and self-assembly of biomolecules. Microscopic theories and molecular simulations have been used to study association of a pair of methanes in water, the paradigmatic example of hydrophobic attraction, and determined that entropy is the driving force for the association of the methane pair, while the enthalpy disfavors it. An open question is to which extent coarse-grained water models can still produce correct thermodynamic and structural signatures of hydrophobic interaction. In this work, we investigate the hydrophobic interaction between a methane pair in water at temperatures from 260 to 340 K through molecular dynamics simulations with the coarse-grained monatomic water model mW. We find that the coarse-grained model correctly represents the free energy of association of the methane pair, the temperature dependence of free energy, and the positive change in entropy and enthalpy upon association. We investigate the relationship between thermodynamic signatures and structural order of water through the analysis of the spatial distribution of the density, energy, and tetrahedral order parameter Qt of water. The simulations reveal an enhancement of tetrahedral order in the region between the first and second hydration shells of the methane molecules. The increase in tetrahedral order, however, is far from what would be expected for a clathrate-like or ice-like shell around the solutes. This work shows that the mW water model reproduces the key signatures of hydrophobic interaction without long ranged electrostatics or the need to be re-parameterized for different thermodynamic states. These characteristics, and its hundred-fold increase in efficiency with respect to atomistic models, make mW a promising water model for studying water-driven hydrophobic processes in more complex systems.

  12. Patterns, structures and regulations of domestic water cycle systems in China

    Science.gov (United States)

    Chu, Junying; Wang, Hao; Wang, Jianhua; Qin, Dayong

    2010-05-01

    Domestic water cycle systems serving as one critical component of artificial water cycle at the catchment's scale, is so closely related to public healthy, human rights and social-economic development, and has gained the highest priority in strategic water resource and municipal infrastructure planning. In this paper, three basic patterns of domestic water cycle systems are identified and analyzed, including rural domestic water system (i.e. primary level), urban domestic water system (i.e. intermediate level) and metropolitan domestic water system (i.e. senior level), with different "abstract-transport-consume-discharge" mechanisms and micro-components of water consumption (such as drinking, cooking, toilet flushing, showering or cleaning). The rural domestic water system is general simple with three basic "abstract-consume-discharge" mechanisms and micro-components of basic water consumption such as drinking, cooking, washing and sanitation. The urban domestic water system has relative complex mechanisms of "abstract-supply-consume-treatment-discharge" and more micro-components of water consumption such as bath, dishwashing or car washing. The metropolitan domestic water system (i.e. senior level) has the most complex mechanisms by considering internal water reuse, external wastewater reclamation, and nutrient recycling processes. The detailed structures for different water cycle pattern are presented from the aspects of water quantity, wastewater quality and nutrients flow. With the speed up of urbanization and development of social-economy in China, those three basic patterns are interacting, transforming and upgrading. According to the past experiences and current situations, urban domestic water system (i.e. intermediate level) is the dominant pattern based on indicator of system number or system scale. The metropolitan domestic water system (i.e. senior level) is the idealized model for the future development and management. Current domestic water system

  13. How Do You Get Your Water? Structural Violence Pedagogy and Women's Access to Water

    Science.gov (United States)

    Keefer, Natalie; Bousalis, Rina

    2015-01-01

    In many parts of the less developed world it is women and girls who are expected to provide water for their family. Frequently, young girls are unable to complete school or get jobs because water scarcity means they are forced to walk miles daily to obtain this most basic need. Since the creation of the United Nations Millennium Goals, progress…

  14. Soft photo structuring of porous silicon in water

    Energy Technology Data Exchange (ETDEWEB)

    Juan, M.; Bouillard, J.S.; Plain, J.; Bachelot, R.; Adam, P.M.; Lerondel, G.; Royer, P. [ICD - Laboratoire de Nanotechnologie et d' Instrumentation Optique, CNRS FRE 2848, Universite de Technologie de Troyes, 12 rue Marie Curie, BP 2060, 10010 Troyes (France)

    2007-05-15

    We report on local photo-induced patterning of porous silicon in water. Scanning probe microscopy images of the sample surface after illumination show that the emission properties as well as the topography are modified according to the interferometric illumination pattern. Local photo-oxidation is believed to be at the origin of these modifications. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  15. Comparison of Novel Carboneous Structures to Treat Nitroaromatic Impacted Water

    Science.gov (United States)

    2015-12-01

    Perfluorinated Compounds from Groundwater using Granular Activated Carbon. University of Colorado. Li, L., Quinlivan, P. A, and Knappe, D. R. U. (2002...and Owens, G. (2009). "Kinetics and thermodynamics of sorption of nitroaromatic compounds to as-grown and oxidized multiwalled carbon nanotubes...used as adsorbents to treat water contaminated by a model nitroaromatic compound , 2,4- dinitrotoluene (DNT). The DNT adsorption capacity of pristine

  16. Structure and reactivity in amphiphile-water micelles

    International Nuclear Information System (INIS)

    Chevalier, Yves

    1985-01-01

    Following a review of the general properties of micelles, this report contains two parts: - A structural study of octylphosphate micelles. Important structural changes have been evidenced by mean of small angle neutron scattering as the electrical charge of the interface is varied. The NMR relaxation study of the conformation of the hydrocarbon chains has shown that the micellar core is disordered in contrast with the interface which is rather structured. The diffusion motions in the interface and the segmental motions of the chains are fast. - Studies on the reactivity in micelles have been carried out. A large micellar effect on the complexation of transition ions by amphiphilic ligands is evidenced. The problem of solute localization in micelles is developed with few examples. (author) [fr

  17. Impact of soda-lime borosilicate glass composition on water penetration and water structure at the first time of alteration

    International Nuclear Information System (INIS)

    Rebiscoul, D.; Bruguier, F.; Gin, S.; Magnin, V.

    2012-01-01

    In this study, the impact of soda-lime borosilicate glass composition and particularly the effect of charge compensators such Ca and Na and, of network formers such Si and Zr, on water penetration and water structure at the first time of alteration were investigated. Two non-destructive techniques were combined: the Fourier transform infrared spectroscopy in attenuated total reflection geometry to precise the predominant alteration mechanisms and assess the water structure in altered zone and the grazing incidence X-ray reflectometry to determine the thickness of the altered glass zone allowing to calculate the water diffusion coefficients through the glasses. The results of glass alteration at pH = 3 and 30 degrees C have shown that hydrolysis was the predominant mechanism after few seconds for glass having a high amount of non-binding oxygen. For the other glasses, which for the diffusion was the limiting reaction, the calculated water diffusion coefficients were comprised between 10 -21 and 10 -19 m 2 .s -1 and vary as a function of glass composition. An activation energy of 76.9 kJ.mol -1 was calculated and appears to be higher than inert gas diffusion through the glass highlighting that water molecules strongly interact with the glass matrix. (authors)

  18. Water balance and topography predict fire and forest structure patterns

    Science.gov (United States)

    Van R. Kane; James A. Lutz; C. Alina Cansler; Nicholas A. Povak; Derek J. Churchill; Douglas F. Smith; Jonathan T. Kane; Malcolm P. North

    2015-01-01

    Mountainous topography creates fine-scale environmental mosaics that vary in precipitation, temperature, insolation, and slope position. This mosaic in turn influences fuel accumulation and moisture and forest structure. We studied these the effects of varying environmental conditions across a 27,104 ha landscape within Yosemite National Park, California, USA, on the...

  19. Electronic structure effects in liquid water studied by photoelectron spectroscopy and density functional theory

    Energy Technology Data Exchange (ETDEWEB)

    Nordlund, Dennis; Odelius, Michael; Bluhm, Hendrik; Ogasawara, Hirohito; Pettersson, Lars G.M.; Nilsson, Anders

    2008-04-29

    We present valence photoelectron emission spectra of liquid water in comparison with gas-phase water, ice close to the melting point, low temperature amorphous and crystalline ice. All aggregation states have major electronic structure changes relative to the free molecule, with rehybridization and development of bonding and anti-bonding states accompanying the hydrogen bond formation. Sensitivity to the local structural order, most prominent in the shape and splitting of the occupied 3a{sub 1} orbital, is understood from the electronic structure averaging over various geometrical structures, and reflects the local nature of the orbital interaction.

  20. Structural integrity of water reactor pressure boundary components

    International Nuclear Information System (INIS)

    Loss, F.J.

    1977-01-01

    The dynamic fracture toughness was determined as a function of temperature for three-point bend specimens of A533-B, A508-2, and A302-B steels. Crack propagation rates at 288 0 C in a water reactor environment were determined for A533-B and A508-2. Radiation-induced degradation of notch toughness of reactor steels and welds was explored. The ''warm prestress'' occurring in a flawed reactor vessel following a LOCA and operation of ECCS was studied. 25 figures

  1. Seismic evaluation of a cooling water reservoir facility including fluid-structure and soil-structure interaction effects

    International Nuclear Information System (INIS)

    Kabir, A.F.; Maryak, M.E.

    1991-01-01

    Seismic analyses and structural evaluations were performed for a cooling water reservoir of a nuclear reactor facility. The horizontal input seismic motion was the NRC Reg. guide 1.60 spectrum shape anchored at 0.20g zero period acceleration. Vertical input was taken as two-thirds of the horizontal input. Soil structure interaction and hydrodynamic effects were addressed in the seismic analyses. Uncertainties in the soil properties were accounted for by considering three soil profiles. Two 2-dimensional SSI models and a 3-dimensional static model. Representing different areas of the reservoir structures were developed and analyzed to obtain seismic forces and moments, and accelerations at various locations. The results included in this paper indicated that both hydrodynamic and soil-structure interaction effects are significant contributors to the seismic responses of the water-retaining walls of the reservoir

  2. Lower Colorado River GRP Dams and Water Retention Structures, Arizona, 2012, Arizona Department of Environmental Quality

    Data.gov (United States)

    U.S. Environmental Protection Agency — Location of dams and water retention structures as compiled from multiple sources by the Arizona Department of Environmental Quality (ADEQ). The data are "sensitive"...

  3. Seasonal and diurnal variability of thermal structure in the coastal waters off Visakhapatnam

    Digital Repository Service at National Institute of Oceanography (India)

    Rao, B.P.; RameshBabu, V.; Chandramohan, P.

    relaxing event helps in the development of a strong layered thermal structure while convective mixing due to winter inversions during November to February causes weak thermal gradients in the water column...

  4. Structure from Dynamics: Vibrational Dynamics of Interfacial Water as a Probe of Aqueous Heterogeneity

    Science.gov (United States)

    2018-01-01

    The structural heterogeneity of water at various interfaces can be revealed by time-resolved sum-frequency generation spectroscopy. The vibrational dynamics of the O–H stretch vibration of interfacial water can reflect structural variations. Specifically, the vibrational lifetime is typically found to increase with increasing frequency of the O–H stretch vibration, which can report on the hydrogen-bonding heterogeneity of water. We compare and contrast vibrational dynamics of water in contact with various surfaces, including vapor, biomolecules, and solid interfaces. The results reveal that variations in the vibrational lifetime with vibrational frequency are very typical, and can frequently be accounted for by the bulk-like heterogeneous response of interfacial water. Specific interfaces exist, however, for which the behavior is less straightforward. These insights into the heterogeneity of interfacial water thus obtained contribute to a better understanding of complex phenomena taking place at aqueous interfaces, such as photocatalytic reactions and protein folding. PMID:29490138

  5. Light Water Reactor Sustainability Program Advanced Seismic Soil Structure Modeling

    Energy Technology Data Exchange (ETDEWEB)

    Bolisetti, Chandrakanth [Idaho National Lab. (INL), Idaho Falls, ID (United States); Coleman, Justin Leigh [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-06-01

    Risk calculations should focus on providing best estimate results, and associated insights, for evaluation and decision-making. Specifically, seismic probabilistic risk assessments (SPRAs) are intended to provide best estimates of the various combinations of structural and equipment failures that can lead to a seismic induced core damage event. However, in some instances the current SPRA approach has large uncertainties, and potentially masks other important events (for instance, it was not the seismic motions that caused the Fukushima core melt events, but the tsunami ingress into the facility). SPRA’s are performed by convolving the seismic hazard (this is the estimate of all likely damaging earthquakes at the site of interest) with the seismic fragility (the conditional probability of failure of a structure, system, or component given the occurrence of earthquake ground motion). In this calculation, there are three main pieces to seismic risk quantification, 1) seismic hazard and nuclear power plants (NPPs) response to the hazard, 2) fragility or capacity of structures, systems and components (SSC), and 3) systems analysis. Two areas where NLSSI effects may be important in SPRA calculations are, 1) when calculating in-structure response at the area of interest, and 2) calculation of seismic fragilities (current fragility calculations assume a lognormal distribution for probability of failure of components). Some important effects when using NLSSI in the SPRA calculation process include, 1) gapping and sliding, 2) inclined seismic waves coupled with gapping and sliding of foundations atop soil, 3) inclined seismic waves coupled with gapping and sliding of deeply embedded structures, 4) soil dilatancy, 5) soil liquefaction, 6) surface waves, 7) buoyancy, 8) concrete cracking and 9) seismic isolation The focus of the research task presented here-in is on implementation of NLSSI into the SPRA calculation process when calculating in-structure response at the area

  6. Method of repairing incore structure and water sealing chamber

    Energy Technology Data Exchange (ETDEWEB)

    Kikuchi, Toshikazu; Sato, Sukenobu (Hitachi Nuclear Engineering Co. Ltd., Ibaraki (Japan)); Wada, Noriaki; Kurosawa, Koichi; Tsujimura, Hiroshi; Enomoto, Kunio.

    1993-11-26

    An incore-chamber main body comprises a guide tube, an insertion guide, an extensible arm, a device fixing mechanism, a gas supply pipe, a guide driving mechanism and an in-core chamber control device. The in-core chamber main body is installed and secured to an upper flange surface of a shroud. Reactor water is raised to a level below a flange of a reactor pressure vessel while supplying a dry gas from a gas supply pipe to make the inside of the shroud as a gas atmosphere. Subsequently, each of the devices is attached to the top end of the extensible arm, and the guide driving mechanism is operated by the in-core chamber control device to an aimed position for preventive maintenance or repair to conduct positioning and fixing by utilizing the guide tube and the insertion guide. This enables to conduct preventive maintenance or repair in a state where reactor water is present to the outside of the in-core reactor chamber while maintaining the in-core equipment in the gas atmosphere, thereby enabling to reduce operator's exposure dose. (I.N.).

  7. Method of repairing incore structure and water sealing chamber

    International Nuclear Information System (INIS)

    Kikuchi, Toshikazu; Sato, Sukenobu; Wada, Noriaki; Kurosawa, Koichi; Tsujimura, Hiroshi; Enomoto, Kunio.

    1993-01-01

    An incore-chamber main body comprises a guide tube, an insertion guide, an extensible arm, a device fixing mechanism, a gas supply pipe, a guide driving mechanism and an in-core chamber control device. The in-core chamber main body is installed and secured to an upper flange surface of a shroud. Reactor water is raised to a level below a flange of a reactor pressure vessel while supplying a dry gas from a gas supply pipe to make the inside of the shroud as a gas atmosphere. Subsequently, each of the devices is attached to the top end of the extensible arm, and the guide driving mechanism is operated by the in-core chamber control device to an aimed position for preventive maintenance or repair to conduct positioning and fixing by utilizing the guide tube and the insertion guide. This enables to conduct preventive maintenance or repair in a state where reactor water is present to the outside of the in-core reactor chamber while maintaining the in-core equipment in the gas atmosphere, thereby enabling to reduce operator's exposure dose. (I.N.)

  8. The Relationship Between Dynamics and Structure in the Far Infrared Absorption Spectrum of Liquid Water

    Energy Technology Data Exchange (ETDEWEB)

    Woods, K.

    2005-01-14

    Using an intense source of far-infrared radiation, the absorption spectrum of liquid water is measured at a temperature ranging from 269 to 323 K. In the infrared spectrum we observe modes that are related to the local structure of liquid water. Here we present a FIR measured spectrum that is sensitive to the low frequency (< 100cm{sup -1}) microscopic details that exist in liquid water.

  9. Utilization threshold of surface water and groundwater based on the system optimization of crop planting structure

    Directory of Open Access Journals (Sweden)

    Qiang FU,Jiahong LI,Tianxiao LI,Dong LIU,Song CUI

    2016-09-01

    Full Text Available Based on the diversity of the agricultural system, this research calculates the planting structures of rice, maize and soybean considering the optimal economic-social-ecological aspects. Then, based on the uncertainty and randomness of the water resources system, the interval two-stage stochastic programming method, which introduces the uncertainty of the interval number, is used to calculate the groundwater exploitation and the use efficiency of surface water. The method considers the minimum cost of water as the objective of the uncertainty model for surface water and groundwater joint scheduling optimization for different planting structures. Finally, by calculating harmonious entropy, the optimal exploitation utilization interval of surface water and groundwater is determined for optimal cultivation in the Sanjiang Plain. The optimal matching of the planting structure under the economic system is suitable when the mining ratio of the surface is in 44.13%—45.45% and the exploitation utilization of groundwater is in 54.82%—66.86%, the optimal planting structure under the social system is suitable when surface water mining ratio is in 47.84%—48.04% and the groundwater exploitation threshold is in 67.07%—72.00%. This article optimizes the economic-social-ecological-water system, which is important for the development of a water- and food-conserving society and providing a more accurate management environment.

  10. Structure and thermal analysis of the water cooling mask at NSRL front end

    International Nuclear Information System (INIS)

    Zhao Feiyun; Xu Chaoyin; Wang Qiuping; Wang Naxiu

    2003-01-01

    A water cooling mask is an important part of the front end, usually used for absorbing high power density synchrotron radiation to protect the apparatus from being destroyed by heat load. This paper presents the structure of the water cooling mask and the thermal analysis results of the mask block at NSRL using Program ANSYS5.5

  11. Structural investigation of water-soluble polysaccharides extracted from the fruit bodies of Coprinus comatus

    NARCIS (Netherlands)

    Li, Bo; Dobruchowska, Justyna M.; Gerwig, Gerrit J.; Dijkhuizen, Lubbert; Kamerling, Johannis P.

    2013-01-01

    Water-soluble polysaccharide material, extracted from the stipes of the fruit bodies of Coprinus comatus by hot water, was fractionated by sequential weak anion-exchange and size-exclusion chromatography. The relevant fractions were subjected to structural analysis, including (D/L)

  12. Structural transition in a lipid-water liquid system

    International Nuclear Information System (INIS)

    Bulavin, L.A.; Solovjov, D.V.; Solovjov, D.V.; Gorshkova, Yu.Je.; Zhigunov, O.M.; Ivan'kov, O.I.; Ivan'kov, O.I.; Gordelij, V.I.; Gordelij, V.I.; Gordelij, V.I.; Gordelij, V.I.; Kuklin, O.I.; Kuklin, O.I.

    2012-01-01

    Small-angle X-ray scattering technique has been used to study multilayer lipid membranes of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) and the 3:1-mixture DPPC/1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC) in excess water. The temperature dependences of the repetition period for lipid bilayers in the temperature range 20-55 o C are obtained. A comparative analysis of the scattering curves obtained for multilayer membranes showed that, below a temperature of 40 o C , there emerges an additional ordering with a repetition period of 66 A in the lipid mixture, which we associate with the lipid phase separation. A disappearance of the so-called ripple (wave-like) phase of DPPC lipid in the mixture is also observed.

  13. Structural and dynamical properties of water confined between two hydrophilic surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Di Napoli, Solange, E-mail: dinapoli@tandar.cnea.gov.a [Depto. de Fisica - CAC, Comision Nacional de Energia Atomica, Av. Gral Paz 1499, (1650) San Martin, Buenos Aires (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (Argentina); Gamba, Zulema, E-mail: gamba@tandar.cnea.gov.a [Depto. de Fisica - CAC, Comision Nacional de Energia Atomica, Av. Gral Paz 1499, (1650) San Martin, Buenos Aires (Argentina)

    2009-10-01

    The properties of water in the vicinity of surfaces and under confinement have been extensively studied because of the relevance of a quantitative understanding of many processes that not only take place in biological systems, like cells, membranes and microemulsions, but also in many others such as confined water in rocks, ionic channels and interestellar matter. In this work we perform molecular dynamic calculations of the nanoscopic structure of TIP5P model water confined between two hydrophilic surfaces. We calculate the diffusion coefficients and the atomic density profile of water molecules and polar ions in the system as a function of the number of water molecules per amphiphilic (n{sub W}). We also study the dependence of the water layer thickness and the profiles of water dipole orientation with this parameter.

  14. Structural and dynamical properties of water confined between two hydrophilic surfaces

    International Nuclear Information System (INIS)

    Di Napoli, Solange; Gamba, Zulema

    2009-01-01

    The properties of water in the vicinity of surfaces and under confinement have been extensively studied because of the relevance of a quantitative understanding of many processes that not only take place in biological systems, like cells, membranes and microemulsions, but also in many others such as confined water in rocks, ionic channels and interestellar matter. In this work we perform molecular dynamic calculations of the nanoscopic structure of TIP5P model water confined between two hydrophilic surfaces. We calculate the diffusion coefficients and the atomic density profile of water molecules and polar ions in the system as a function of the number of water molecules per amphiphilic (n W ). We also study the dependence of the water layer thickness and the profiles of water dipole orientation with this parameter.

  15. Novel Structures for the Excess Electron State of the Water Hexamer and the Interaction Forces Governing the Structures

    International Nuclear Information System (INIS)

    Lee, S.; Kim, J.; Lee, S.J.; Kim, K.S.

    1997-01-01

    The geometrical and electronic structures of partially hydrated electron systems, in particular, the water hexamer, which have been controversial for decades, have been clarified by an exhaustive search for possible low-lying energy structures. Several competing interaction forces governing the conformation have been examined for the first time. The low-lying energy structures are hybrid (or partially internal and partially surface) excess electron states. Our prediction is evidenced from excellent agreements with available experimental data. The vertical electron-detachment energies are mainly determined by the number of dangling H atoms (H d ) . copyright 1997 The American Physical Society

  16. Structures of nanoparticles prepared from oil-in-water emulsions.

    Science.gov (United States)

    Sjöström, B; Kaplun, A; Talmon, Y; Cabane, B

    1995-01-01

    Hydrophobic substances were dissolved in an organic solvent and emulsified with an aqueous solution at very high shear. Droplets of very small sizes (50-100 nm) were obtained by using surfactants which were combinations of lecithins and bile salts. After emulsification, the organic solvent was removed by evaporation, yielding stable dispersions of solid particles. The sizes, shapes, and structures of the particles were examined through quasi-elastic light scattering, small-angle neutron scattering and cryotransmission electron microscopy. Cholesterol acetate particles stabilized by lecithin and bile salts were found to be platelets of 10-20 nm thickness and 80 nm diameter. Cholesteryl acetate particles stabilized with POE-(20)-sorbitan monolaurate were dense spherical globules of diameter 100 nm. Particles with a composition similar to the endogenously occurring, lipoprotein, LDL, were large spherical globules studded with small vesicles. The subsequent evolution of the cholesteryl acetate dispersion upon aging was examined. There was no transfer of cholesteryl acetate between particles nor to large crystals. However, some aggregation of the particles was observed when the volume fraction of the particles in the aqueous dispersion exceeded 0.05. Thus, the structure of the nanoparticles obtained through deswelling of emulsion droplets changes according to the nature of the emulsifiers and to the composition of the hydrophobic substances which they contain.

  17. Accurate Energies and Structures for Large Water Clusters Using the X3LYP Hybrid Density Functional

    OpenAIRE

    Su, Julius T.; Xu, Xin; Goddard, William A., III

    2004-01-01

    We predict structures and energies of water clusters containing up to 19 waters with X3LYP, an extended hybrid density functional designed to describe noncovalently bound systems as accurately as covalent systems. Our work establishes X3LYP as the most practical ab initio method today for calculating accurate water cluster structures and energies. We compare X3LYP/aug-cc-pVTZ energies to the most accurate theoretical values available (n = 2−6, 8), MP2 with basis set superposition error (BSSE)...

  18. Integrating Water, Actors, and Structure to Study Socio-Hydro-Ecological Systems

    Science.gov (United States)

    Hale, R. L.; Armstrong, A.; Baker, M. A.; Bedingfield, S.; Betts, D.; Buahin, C. A.; Buchert, M.; Crowl, T.; Dupont, R.; Endter-Wada, J.; Flint, C.; Grant, J.; Hinners, S.; Horns, D.; Horsburgh, J. S.; Jackson-Smith, D.; Jones, A. S.; Licon, C.; Null, S. E.; Odame, A.; Pataki, D. E.; Rosenberg, D. E.; Runburg, M.; Stoker, P.; Strong, C.

    2014-12-01

    Urbanization, climate uncertainty, and ecosystem change represent major challenges for managing water resources. Water systems and the forces acting upon them are complex, and there is a need to understand and generically represent the most important system components and linkages. We developed a framework to facilitate understanding of water systems including potential vulnerabilities and opportunities for sustainability. Our goal was to produce an interdisciplinary framework for water resources research to address water issues across scales (e.g., city to region) and domains (e.g., water supply and quality, urban and transitioning landscapes). An interdisciplinary project (iUTAH - innovative Urban Transitions and Aridregion Hydro-sustainability) with a large (N=~100), diverse team having expertise spanning the hydrologic, biological, ecological, engineering, social, planning, and policy sciences motivated the development of this framework. The framework was developed through review of the literature, meetings with individual researchers, and workshops with participants. The Structure-Water-Actor Framework (SWAF) includes three main components: water (quality and quantity), structure (natural, built, and social), and actors (individual and organizational). Key linkages include: 1) ecological and hydrological processes, 2) ecosystem and geomorphic change, 3) planning, design, and policy, 4) perceptions, information, and experience, 5) resource access, and 6) operational water use and management. Our expansive view of structure includes natural, built, and social components, allowing us to examine a broad set of tools and levers for water managers and decision-makers to affect system sustainability and understand system outcomes. We validate the SWAF and illustrate its flexibility to generate insights for three research and management problems: green stormwater infrastructure in an arid environment, regional water supply and demand, and urban river restoration

  19. Fluid-structure interaction with pipe-wall viscoelasticity during water hammer

    NARCIS (Netherlands)

    Keramat, A.; Tijsseling, A.S.; Hou, Q.; Ahmadi, A.

    2011-01-01

    Fluid-structure interaction (FSI) due to water hammer in a pipeline which has viscoelastic wall behaviour is studied. Appropriate governing equations are derived and numerically solved. In the numerical implementation of the hydraulic and structural equations, viscoelasticity is incorporated using

  20. Fluid-structure interaction with pipe-wall viscoelasticity during water hammer

    NARCIS (Netherlands)

    Keramat, A.; Tijsseling, A.S.; Hou, Q.; Ahmadi, A.

    2012-01-01

    Fluid–structure interaction (FSI) due to water hammer in a pipeline which has viscoelastic wall behaviour is studied. Appropriate governing equations are derived and numerically solved. In the numerical implementation of the hydraulic and structural equations, viscoelasticity is incorporated using

  1. Spectral structure of mesoscale winds over the water

    DEFF Research Database (Denmark)

    Larsén, Xiaoli Guo; Vincent, Claire Louise; Larsen, Søren Ejling

    2013-01-01

    to describe the spectral slope transition as well as the limit for application of the Taylor hypothesis. The stability parameter calculated from point measurements, the bulk Richardson number, is found insufficient to represent the various atmospheric structures that have their own spectral behaviours under...... spectra show universal characteristics, in agreement with the findings in literature, including the energy amplitude and the −5/3 spectral slope in the mesoscale range transitioning to a slope of −3 for synoptic and planetary scales. The integral time-scale of the local weather is found to be useful...... different stability conditions, such as open cells and gravity waves. For stationary conditions, the mesoscale turbulence is found to bear some characteristics of two-dimensional isotropy, including (1) very minor vertical variation of spectra; (2) similar spectral behaviour for the along- and across...

  2. [Mass maritime casualty incidents in German waters: structures and resources].

    Science.gov (United States)

    Castan, J; Paschen, H-R; Wirtz, S; Dörges, V; Wenderoth, S; Peters, J; Blunk, Y; Bielstein, A; Kerner, T

    2012-07-01

    The Central Command for Maritime Emergencies was founded in Germany in 2003 triggered by the fire on board of the cargo ship "Pallas" in 1998. Its mission is to coordinate and direct measures at or above state level in maritime emergency situations in the North Sea and the Baltic Sea. A special task in this case is to provide firefighting and medical care. To face these challenges at sea emergency doctors and firemen have been specially trained. This form of organization provides a concept to counter mass casualty incidents and peril situations at sea. Since the foundation of the Central Command for Maritime Emergencies there have been 5 operations for firefighting units and 4 for medical response teams. Assignments and structure of the Central Command for Maritime Emergencies are unique in Europe.

  3. Mechanics of structures and maintenance of pressurized water reactors

    International Nuclear Information System (INIS)

    Hutin, J.P.

    1992-01-01

    Electricite de France nowadays has in operation 34 units of 900 MW and 17 units of 1300 MW of PWR. Since the first unit was run, this means that more than 350 reactor-years have been performed, to which should be added the experience already gained on fossil fuel or natural uranium plants. This enabled EDF to build its own philosophy and a strategy for maintenance that are best suited for the specific requirements of the hardware with which the actual nuclear boilers are made-up. This philosophy and strategy rest upon an analysis which calls widely for the mechanics of structures, to such an extent that major decisions concerning maintenance depend on the ability that one has for resolving problems within the scope of that discipline

  4. Structure of electron tracks in water. 2. Distribution of primary ionizations and excitations in water radiolysis

    International Nuclear Information System (INIS)

    Pimblott, S.M.; Mozumder, A.

    1991-01-01

    A procedure for the calculation of entity-specific ionization and excitation probabilities for water radiolysis at low linear energy transfer (LET) has been developed. The technique pays due attention to the effects of the ionization threshold and the energy dependence of the ionization efficiency. The numbers of primary ionizations and excitations are not directly proportional to the spur energy. At a given spur energy, ionization follows a binomial distribution subject to an energetically possible maximum. The excitation distribution for a spur of given energy and with a given number of ionizations is given by a geometric series. The occurrence probabilities depend upon the cross sections of ionization, excitation, and other inferior processes. Following the low-LET radiolysis of liquid water the most probable spurs contain one ionization, two ionizations, or one ionization and one excitation, while in water vapor they contain either one ionization or one excitation. In liquid water the most probable outcomes for spurs corresponding to the most probable energy loss (22 eV) and to the mean energy loss (38 eV) are one ionization and one excitation, and two ionizations and one excitation, respectively. In the vapor, the most probable energy loss is 14 eV which results in one ionization or one excitation and the mean energy loss is 34 eV for which the spur of maximum probability contains one ionization and two excitations. The total calculated primary yields for low-LET radiolysis are in approximate agreement with experiment in both phases

  5. Centralized Drinking Water Treatment Operations Shape Bacterial and Fungal Community Structure.

    Science.gov (United States)

    Ma, Xiao; Vikram, Amit; Casson, Leonard; Bibby, Kyle

    2017-07-05

    Drinking water microbial communities impact opportunistic pathogen colonization and corrosion of water distribution systems, and centralized drinking water treatment represents a potential control for microbial community structure in finished drinking water. In this article, we examine bacterial and fungal abundance and diversity, as well as the microbial community taxonomic structure following each unit operation in a conventional surface water treatment plant. Treatment operations drove the microbial composition more strongly than sampling time. Both bacterial and fungal abundance and diversity decreased following sedimentation and filtration; however, only bacterial abundance and diversity was significantly impacted by free chlorine disinfection. Similarly, each treatment step was found to shift bacterial and fungal community beta-diversity, with the exception of disinfection on the fungal community structure. We observed the enrichment of bacterial and fungal taxa commonly found in drinking water distribution systems through the treatment process, for example, Sphingomonas following filtration and Leptospirillium and Penicillium following disinfection. Study results suggest that centralized drinking water treatment processes shape the final drinking water microbial community via selection of community members and that the bacterial community is primarily driven by disinfection while the eukaryotic community is primarily controlled by physical treatment processes.

  6. Effect of Water-Cement Ratio on Pore Structure and Strength of Foam Concrete

    Directory of Open Access Journals (Sweden)

    Zhongwei Liu

    2016-01-01

    Full Text Available Foam concrete with different dry densities (400, 500, 600, 700, and 800 kg/m3 was prepared from ordinary Portland cement (P.O.42.5R and vegetable protein foaming agent by adjusting the water-cement ratio through the physical foaming method. The performance of the cement paste adopted, as well as the structure and distribution of air pores, was characterized by a rheometer, scanning electron microscope, vacuum water saturation instrument, and image analysis software. Effects of the water-cement ratio on the relative viscosity of the cement paste, as well as pore structure and strength of the hardened foam concrete, were discussed. Results showed that water-cement ratio can influence the size, distribution, and connectivity of pores in foam concrete. The compressive strength of the foam concrete showed an inverted V-shaped variation law with the increase in water-cement ratio.

  7. Structure and dynamics in liquid water from x-ray absorption spectroscopy

    International Nuclear Information System (INIS)

    Wernet, Philippe

    2009-01-01

    Oxygen K-edge x-ray absorption spectra of water are discussed. The spectra of gas-phase water, liquid water and ice illustrate the sensitivity of oxygen K-edge x-ray absorption spectroscopy to hydrogen bonding in water. Transmission mode spectra of amorphous and crystalline ice are compared to x-ray Raman spectra of ice. The good agreement consolidates the experimental spectrum of crystalline ice and represents an incentive for theoretical calculations of the oxygen K-edge absorption spectrum of crystalline ice. Time-resolved infrared-pump and x-ray absorption probe results are finally discussed in the light of this structural interpretation.

  8. Probing membrane protein structure using water polarization transfer solid-state NMR.

    Science.gov (United States)

    Williams, Jonathan K; Hong, Mei

    2014-10-01

    Water plays an essential role in the structure and function of proteins, lipid membranes and other biological macromolecules. Solid-state NMR heteronuclear-detected (1)H polarization transfer from water to biomolecules is a versatile approach for studying water-protein, water-membrane, and water-carbohydrate interactions in biology. We review radiofrequency pulse sequences for measuring water polarization transfer to biomolecules, the mechanisms of polarization transfer, and the application of this method to various biological systems. Three polarization transfer mechanisms, chemical exchange, spin diffusion and NOE, manifest themselves at different temperatures, magic-angle-spinning frequencies, and pulse irradiations. Chemical exchange is ubiquitous in all systems examined so far, and spin diffusion plays the key role in polarization transfer within the macromolecule. Tightly bound water molecules with long residence times are rare in proteins at ambient temperature. The water polarization-transfer technique has been used to study the hydration of microcrystalline proteins, lipid membranes, and plant cell wall polysaccharides, and to derive atomic-resolution details of the kinetics and mechanism of ion conduction in channels and pumps. Using this approach, we have measured the water polarization transfer to the transmembrane domain of the influenza M2 protein to obtain information on the structure of this tetrameric proton channel. At short mixing times, the polarization transfer rates are site-specific and depend on the pH, labile protons, sidechain conformation, as well as the radial position of the residues in this four-helix bundle. Despite the multiple dependences, the initial transfer rates reflect the periodic nature of the residue positions from the water-filled pore, thus this technique provides a way of gleaning secondary structure information, helix tilt angle, and the oligomeric structure of membrane proteins. Copyright © 2014 Elsevier Inc. All

  9. Characterisation of fluid-structure interaction for water impact of composite panels

    Directory of Open Access Journals (Sweden)

    M Battley

    2016-09-01

    Full Text Available Hydrodynamic loads can be very significant for high performance marine vessels. Water impact of panels, known as "slamming", typically generates high magnitude short duration pressure pulses that move across the structure. In the case of compliant panels there can be significant coupling between the pressures and the structural responses. While there has been significant development of numerical methods to simulate this type of fluid-structure interaction there is only very limited experimental data available for validation of the simulation approaches. This paper describes an experimental study of sandwich composite panels subjected to water slamming impacts. The results demonstrate that compliant panels subjected to water slamming impacts experience different pressures than rigid panels, and have different structural responses than predicted by traditional uniform pressure based analysis approaches. The study also characterizes the significant effects that the dimensions of pressure transducers and data acquisition sampling rates have on the measured pressures.

  10. Uncommon structure making/breaking behaviour of cholinium taurate in water

    International Nuclear Information System (INIS)

    Gadžurić, Slobodan; Tot, Aleksandar; Armaković, Stevan; Armaković, Sanja; Panić, Jovana; Jović, Branislav; Vraneš, Milan

    2017-01-01

    Highlights: • Structuring of water in cholinium taurate ionic liquids was studied. • Nature of interactions were discussed. • Structure breaking properties were observed below and structure making properties above 300 K. • Molecular dynamics confirmed conclusions derived from experiments. - Abstract: Synthesis, volumetric and transport properties of the new third generation ionic liquid cholinium taurate, [Chol][Tau], are reported. Density, viscosity and electrical conductivity measurements of diluted aqueous solution of [Chol][Tau] were performed, while from the theoretical aspects density functional theory (DFT) calculations and molecular dynamics (MD) simulations have been applied in order to understand the nature of interactions and water structuring in the studied system. DFT approach was used to understand geometry and non-covalent interactions between [Chol] + and [Tau] − ions, while radial distribution functions (RDFs) obtained after MD simulations were applied in order to determine the parts of the ionic liquid that are most responsible for the interaction with water.

  11. Comparison of water degradation of YBaCuO superconducting films made from different structures

    International Nuclear Information System (INIS)

    Chang, C.; Tsai, J.A.

    1988-01-01

    Immersion of YBaCuO superconducting films in water has shown a large difference in degradation between structures with and without silver. For the structures containing silver layers and depositing at a high temperature, superconducting films with zero resistance at 87 K remain superconductive at 77 K after 5 h immersion in water, with an increase in room-temperature film resistance by a factor of 4; the contact resistance remains low after 60 h of immersion, allowing the measurement at low temperatures. For the structures containing no silver and depositing at room temperature, the contact resistance rapidly increases with immersion times, making the measurement at 77 K difficult after 5 min of immersion. Changes in the sharpness of the superconductive transition, and structures of the films due to the water immersion are also compared

  12. New potentional of high-speed water jet technology for renovating concrete structures

    Science.gov (United States)

    Bodnárová, L.; Sitek, L.; Hela, R.; Foldyna, J.

    2011-06-01

    The paper discusses the background and results of research focused on the action of a high-speed water jet on concrete with different qualities. The sufficient and careful removal of degraded concrete layers is very important for the renovation of concrete structures. High-speed water jet technology is one of the most common methods used for removing degraded concrete layers. Different types of high-speed water jets were tested in the experimental part. The classical technology of a single continuous water jet generated with one nozzle was tested as well as the technology of revolving water jets generated by multiple nozzles (used mainly for the renovation of larger areas). A continuous flat water jet and pulsating flat water jet were tested the first time, because the connection of a water jet with the acoustic generator of a pulsating jet offers new possibilities for the use of a water jet (see [1] and [2]). A water jet with such a modification is capable of efficient action and can even be used for cutting solid concrete with a relatively low consumption of energy. A flat pulsating water jet which can be newly used for renovation seems to be a promising technology.

  13. Validating spatial structure in canopy water content using geostatistics

    Science.gov (United States)

    Sanderson, E. W.; Zhang, M. H.; Ustin, S. L.; Rejmankova, E.; Haxo, R. S.

    1995-01-01

    Heterogeneity in ecological phenomena are scale dependent and affect the hierarchical structure of image data. AVIRIS pixels average reflectance produced by complex absorption and scattering interactions between biogeochemical composition, canopy architecture, view and illumination angles, species distributions, and plant cover as well as other factors. These scales affect validation of pixel reflectance, typically performed by relating pixel spectra to ground measurements acquired at scales of 1m(exp 2) or less (e.g., field spectra, foilage and soil samples, etc.). As image analysis becomes more sophisticated, such as those for detection of canopy chemistry, better validation becomes a critical problem. This paper presents a methodology for bridging between point measurements and pixels using geostatistics. Geostatistics have been extensively used in geological or hydrogeolocial studies but have received little application in ecological studies. The key criteria for kriging estimation is that the phenomena varies in space and that an underlying controlling process produces spatial correlation between the measured data points. Ecological variation meets this requirement because communities vary along environmental gradients like soil moisture, nutrient availability, or topography.

  14. Structural analysis and modeling of water reactor fuel rod behavior

    International Nuclear Information System (INIS)

    Roshan Zamir, M.

    2000-01-01

    An important aspect of the design and analysis of nuclear reactor is the ability to predict the behavior of fuel elements in the adverse environment of a reactor system under normal and emergency operating conditions. To achieve these objectives and in order to provide a suitable computer code based on fundamental material properties for design and study of the thermal-mechanical behavior of water reactor fuel rods during their irradiation life and also to demonstrate the fuel rod design and modeling for students, The KIANA-1 computer program has been developed by the writer at Amir-Kabir university of technology with support of Atomic Energy Organization of Iran. KIANA-1 is an integral one-dimensional computer program for the thermal and mechanical analysis in order to predict fuel rods performance and also parameter study of Zircaloy-clad UO 2 fuel rod during steady state conditions. The code has been designed for the following main objectives: To give a solution for the steady state heat conduction equation for fuel as a heat source and clad by using finite difference, control volume and semi-analytical methods in order to predict the temperature profile in the fuel and cladding. To predict the inner gas pressures due to the filling gases and released gaseous fission products. To predict the fission gas production and release by using a simple diffusion model based on the Booth models and an empirical model. To calculate the fuel-clad gap conductance for cracked fuel with partial contact zones to a closed gap with strong contact. To predict the distribution of stress in three principal directions in the fuel and sheet by assuming one-dimensional plane strain and asymmetric idealization. To calculate the strain distribution in three principal directions and the corresponding deformation in the fuel and cladding. For this purpose the permanent strain such as creep or plasticity as well as the thermoelastic deformation and also the swelling, densification, cracking

  15. Flow and coherent structures around circular cylinders in shallow water

    Science.gov (United States)

    Zeng, Jie; Constantinescu, George

    2017-06-01

    Eddy-resolving numerical simulations are conducted to investigate the dynamics of the large-scale coherent structures around a circular cylinder in an open channel under very shallow flow conditions where the bed friction significantly affects the wake structure. Results are reported for three test cases, for which the ratio between the cylinder diameter, D, and the channel depth, H, is D/H = 10, 25, and 50, respectively. Simulation results show that a horseshoe vortex system forms in all test cases and the dynamics of the necklace vortices is similar to that during the breakaway sub-regime observed for cases when a laminar horseshoe vortex forms around the base of the cylinder. Given the shallow conditions and turbulence in the incoming channel flow, the necklace vortices occupy a large fraction of the flow depth (they penetrate until the free surface in the shallower cases with D/H = 25 and 50). The oscillations of the necklace vortices become less regular with increasing polar angle magnitude and can induce strong amplification of the bed shear stress beneath their cores. Strong interactions are observed between the legs of the necklace vortices and the eddies shed in the separated shear layers in the cases with D/H = 25 and 50. In these two cases, a vortex-street type wake is formed and strong three-dimensional effects are observed in the near-wake flow. A secondary instability in the form of arrays of co-rotating parallel horizontal vortices develops. Once the roller vortices get away from the cylinder, the horizontal vortices in the array orient themselves along the streamwise direction. This instability is not present for moderately shallow conditions (e.g., D/H ≈ 1) nor for very shallow cases when the wake changes to an unsteady bubble type (e.g., D/H = 50). For cases when this secondary instability is present, the horizontal vortices extend vertically over a large fraction of the flow depth and play an important role in the vertical mixing of fluid

  16. Spatial organization and drivers of the virtual water trade: a community-structure analysis

    International Nuclear Information System (INIS)

    D’Odorico, Paolo; Carr, Joel; Laio, Francesco; Ridolfi, Luca

    2012-01-01

    The trade of agricultural commodities can be associated with a virtual transfer of the local freshwater resources used for the production of these goods. Thus, trade of food products virtually transfers large amounts of water from areas of food production to far consumption regions, a process termed the ‘globalization of water’. We consider the (time-varying) community structure of the virtual water network for the years 1986–2008. The communities are groups of countries with dense internal connections, while the connections are sparser among different communities. Between 1986 and 2008, the ratio between virtual water flows within communities and the total global trade of virtual water has continuously increased, indicating the existence of well defined clusters of virtual water transfers. In some cases (e.g. Central and North America and Europe in recent years) the virtual water communities correspond to geographically coherent regions, suggesting the occurrence of an ongoing process of regionalization of water resources. However, most communities also include countries located on different ‘sides’ of the world. As such, geographic proximity only partly explains the community structure of virtual water trade. Similarly, the global distribution of people and wealth, whose effect on the virtual water trade is expressed through simple ‘gravity models’, is unable to explain the strength of virtual water communities observed in the past few decades. A gravity model based on the availability of and demand for virtual water in different countries has higher explanatory power, but the drivers of the virtual water fluxes are yet to be adequately identified. (letter)

  17. [Biological testing of water with different structural states in rats and frogs].

    Science.gov (United States)

    Farashchuk, N F; Mikhaylova, R I; Telenkova, O G

    2014-01-01

    The effect of water samples with different structural states on some physiological indices of white laboratory rats, 5 groups of 10 animals (5 females and 5 males) and frogs has been studied. The investigation was performed for 1 month. For the determination of the content of liquid crystal associates (LCA) in water samples there was used the dilatometric method, the performance of experimental animals was studied by the swimming test (up to total fatigue). The performed experiment on growing rats with the use of water with varying degrees of structuredness showed that according to the weight gain there were optimal water "Lekor" and tap water, treated with Bioptron (the content of the structured fraction is 5.06 +/- 0.09% and 6.9 +/- 0.23%, respectively). On physical performance the best indices were in animals consumed water treated with the Bioptron lamp. In performance of experiments on frogs it was found that cardiac function in animals under experimental conditions over time weakens spontaneously: heart rate and cardiac output decline. Therefore, the effect of different water samples on the cardiac function was assessed on the intensity of its decrease for 15 minutes. In the experimental study of the effect of water with different content of LCA on heart rate and cardiac output of the frog it was found that the optimum level of structuredness of water is within the range of 5.06 +/- 0.09% (in water "Lekor") - 6.9 +/- 0.23% (tap water treated with Bioptron). All the other water samples, the content of nanocrystals in which was below or above this range, has a pronounced inhibitory effect on the heart performance of the frog.

  18. The geomorphic legacy of water and erosion control structures in a semiarid rangeland watershed

    Science.gov (United States)

    Nichols, Mary H.; Magirl, Christopher S.; Sayre, N.F.; Shaw, Jeremy R.

    2018-01-01

    Control over water supply and distribution is critical for agriculture in drylands where manipulating surface runoff often serves the dual purpose of erosion control. However, little is known of the geomorphic impacts and legacy effects of rangeland water manipulation infrastructure, especially if not maintained. This study investigated the geomorphic impacts of structures such as earthen berms, water control gates, and stock tanks, in a semiarid rangeland in the southwestern USA that is responding to both regional channel incision that was initiated over a century ago, and a more recent land use change that involved cattle removal and abandonment of structures. The functional condition of remnant structures was inventoried, mapped, and assessed using aerial imagery and lidar data. Headcut initiation, scour, and channel incision associated with compromised lateral channel berms, concrete water control structures, floodplain water spreader berms, and stock tanks were identified as threats to floodplains and associated habitat. Almost half of 27 identified lateral channel berms (48%) have been breached and 15% have experienced lateral scour; 18% of 218 shorter water spreader berms have been breached and 17% have experienced lateral scour. A relatively small number of 117 stock tanks (6%) are identified as structurally compromised based on analysis of aerial imagery, although many currently do not provide consistent water supplies. In some cases, the onset of localized disturbance is recent enough that opportunities for mitigation can be identified to alter the potentially damaging erosion trajectories that are ultimately driven by regional geomorphic instability. Understanding the effects of prior land use and remnant structures on channel and floodplain morphologic condition is critical because both current land management and future land use options are constrained by inherited land use legacy effects.

  19. Structure and Conceptual Design of a Water-Hammering-Type Honsang for Restoration

    Directory of Open Access Journals (Sweden)

    Yong Sam Lee

    2012-06-01

    Full Text Available We analyzed the manufacturing procedure, specifications, repair history, and details of celestial movements of the water-hammering type Honsang (celestial globe. Results from our study on the remaining Honsangs in China and Japan and on the reconstruction models in Korea were applied to our conceptual design of the water-hammering type Honsang. A Honui (armillary sphere and Honsang using the water-hammering method were manufactured in Joseon in 1435 (the 17th year of King Sejong. Jang Yeong-Sil developed the Honsang system based on the water-operation method of Shui yün i hsiang t’ai in China. Water-operation means driving water wheels using a water flow. The most important factor in this type of operation is the precision of the water clock and the control of the water wheel movement. The water-hammering type Honsang in Joseon probably adopted the Cheonhyeong (天衡; oriental escapement device system of Shui yün i hsiang t’ai in China and the overflow mechanism of Jagyeongnu (striking clepsydra in Joseon, etc. In addition to the Cheonryun system, more gear instruments were needed to stage the rotation of the Honsang globe and the sun’s movement. In this study, the water-hammering mechanism is analyzed in the structure of a water clock, a water wheel, the Cheonhyeong system, and the Giryun system, as an organically working operation mechanism. We expect that this study will serve as an essential basis for studies on Heumgyeonggaknu, the water-operating astronomical clock, and other astronomical clocks in the middle and latter parts of the Joseon dynasty.

  20. Effect of glycine, DL-alanine and DL-2-aminobutyric acid on the temperature of maximum density of water

    International Nuclear Information System (INIS)

    Romero, Carmen M.; Torres, Andres Felipe

    2015-01-01

    Highlights: • Effect of α-amino acids on the temperature of maximum density of water is presented. • The addition of α-amino acids decreases the temperature of maximum density of water. • Despretz constants suggest that the amino acids behave as water structure breakers. • Despretz constants decrease as the number of CH 2 groups of the amino acid increase. • Solute disrupting effect becomes smaller as its hydrophobic character increases. - Abstract: The effect of glycine, DL-alanine and DL-2-aminobutyric acid on the temperature of maximum density of water was determined from density measurements using a magnetic float densimeter. Densities of aqueous solutions were measured within the temperature range from T = (275.65 to 278.65) K at intervals of T = 0.50 K over the concentration range between (0.0300 and 0.1000) mol · kg −1 . A linear relationship between density and concentration was obtained for all the systems in the temperature range considered. The temperature of maximum density was determined from the experimental results. The effect of the three amino acids is to decrease the temperature of maximum density of water and the decrease is proportional to molality according to Despretz equation. The effect of the amino acids on the temperature of maximum density decreases as the number of methylene groups of the alkyl chain becomes larger. The results are discussed in terms of (solute + water) interactions and the effect of amino acids on water structure

  1. Molecular Structure and Dynamics in Thin Water Films at the Silica and Graphite Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Argyris, Dr. Dimitrios [University of Oklahoma; Tummala, Dr. Naga Rajesh [University of Oklahoma; StrioloDr., A [Vanderbilt University; Cole, David R [ORNL

    2008-01-01

    The structure and dynamic properties of interfacial water at the graphite and silica solid surfaces were investigated using molecular dynamics simulations. The effect of surface properties on the characteristics of interfacial water was quantified by computing density profiles, radial distribution functions, surface density distributions, orientation order parameters, and residence and reorientation correlation functions. In brief, our results show that the surface roughness, chemical heterogeneity, and surface heterogeneous charge distribution affect the structural and dynamic properties of the interfacial water molecules, as well as their rate of exchange with bulk water. Most importantly, our results indicate the formation of two distinct water layers at the SiO2 surface covered by a large density of hydroxyl groups. Further analysis of the data suggests a highly confined first layer where the water molecules assume preferential hydrogen-down orientation and a second layer whose behavior and characteristics are highly dependent on those of the first layer through a well-organized hydrogen bond network. The results suggest that water-water interactions, in particular hydrogen bonds, may be largely responsible for macroscopic interfacial properties such as adsorption and contact angle.

  2. Estimations of radiation characteristics of spent fuel in reactors of nuclear submarines and the ice-breaker Lenin dumped near Novaya Zemlya

    International Nuclear Information System (INIS)

    Rubtsov, P.M.; Ruzhanskij, P.A.

    1996-01-01

    Calculations of radionuclide composition and radiation characteristics of actinides and fission products for the reactor spent nuclear fuel of the nuclear submarines and the ice-breaker Lenin dumped near Novaya Zemlya are calculated on the basis of the actual data on the regimes of operation of the above reactors. It is determined that the maximum total activity in 1995 in all reactor sections of the nuclear submarines is concentrated in the fuel (M = 261.9 kg, W = 2.75 GW x day) of the left reactor of the nuclear submarine APL-285 and constitutes 51.9 Ci for actinides and 1.68 x 10 4 Ci for fission products. The corresponding values for the dumped fuel (M = 856 kg, W = 14.2 GW x day) of the ice-breaker Lenin are equal to 3.9 x 10 3 and 5.22 x 10 4 Ci

  3. Hydroxide diffuses slower than hydronium in water because its solvated structure inhibits correlated proton transfer

    Science.gov (United States)

    Chen, Mohan; Zheng, Lixin; Santra, Biswajit; Ko, Hsin-Yu; DiStasio, Robert A., Jr.; Klein, Michael L.; Car, Roberto; Wu, Xifan

    2018-03-01

    Proton transfer via hydronium and hydroxide ions in water is ubiquitous. It underlies acid-base chemistry, certain enzyme reactions, and even infection by the flu. Despite two centuries of investigation, the mechanism underlying why hydroxide diffuses slower than hydronium in water is still not well understood. Herein, we employ state-of-the-art density-functional-theory-based molecular dynamics—with corrections for non-local van der Waals interactions, and self-interaction in the electronic ground state—to model water and hydrated water ions. At this level of theory, we show that structural diffusion of hydronium preserves the previously recognized concerted behaviour. However, by contrast, proton transfer via hydroxide is less temporally correlated, due to a stabilized hypercoordination solvation structure that discourages proton transfer. Specifically, the latter exhibits non-planar geometry, which agrees with neutron-scattering results. Asymmetry in the temporal correlation of proton transfer leads to hydroxide diffusing slower than hydronium.

  4. Irreversible Change of the Pore Structure of ZIF-8 in Carbon Dioxide Capture with Water Coexistence

    DEFF Research Database (Denmark)

    Liu, Huang; Guo, Ping; Regueira Muñiz, Teresa

    2016-01-01

    The performance of zeolitic imidazolate framework 8 (ZIF-8) for CO2 capture under three different conditions (wetted ZIF-8, ZIF-8/water slurry, and ZIF-8/water-glycol slurry) was systemically investigated. This investigation included the study of the pore structure stability of ZIF-8 by using X......-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, and Raman detection technologies. Our results show that the CO2 adsorption ability of ZIF-8 could be substantially increased under the existence of liquid water. However, the structure characterization of the recovered ZIF-8...... showed an irreversible change of its framework, which occurs during the CO2 capture process. It was found that there is an irreversible chemical reaction among ZIF-8, water, and CO2, which creates both zinc carbonate (or zinc carbonate hydroxides) and single 2-methylimidazole crystals, and therefore...

  5. Structure and Dynamics of Water on Aqueous Barium Ion and the {001} Barite Surface

    International Nuclear Information System (INIS)

    Stack, Andrew G.; Rustad, James R.

    2007-01-01

    The structure of water and its dynamics affect a number of fundamental properties of an interface. Yet, these properties are often inaccessible experimentally and computational studies including solvent are comparatively few. Here, we estimate the structure and kinetics of water exchange of aqueous barium ions and barium ions within the {001} barite surface using molecular dynamics and the reactive flux method. For the aqueous ion, the Ba-O distance to water in the first hydration shell was found to be 280 pm with a coordination number of 8.3, and the best estimate of the exchange rate constant is 4.8 x 10 9 s -1 , closely matching experimental estimates. For the barite surface, the first shell water distance was 282 pm, with a coordination number of 0.9 and the best estimate of the rate constant for exchange is 1.7 x 10 10 s -1 , 3.5 times faster than that of the aqueous ion.

  6. Experimental Observation of Bulk Liquid Water Structure in ``No Man's Land''

    Science.gov (United States)

    Sellberg, Jonas; McQueen, Trevor; Huang, Congcong; Loh, Duane; Laksmono, Hartawan; Sierra, Raymond; Hampton, Christina; Starodub, Dmitri; Deponte, Daniel; Martin, Andrew; Barty, Anton; Wikfeldt, Thor; Schlesinger, Daniel; Pettersson, Lars; Beye, Martin; Nordlund, Dennis; Weiss, Thomas; Feldkamp, Jan; Caronna, Chiara; Seibert, Marvin; Messerschmidt, Marc; Williams, Garth; Boutet, Sebastien; Bogan, Michael; Nilsson, Anders

    2013-03-01

    Experiments on pure bulk water below about 235 K have so far been difficult: water crystallization occurs very rapidly below the homogeneous nucleation temperature of 232 K and above 160 K, leading to a ``no man's land'' devoid of experimental results regarding the structure. Here, we demonstrate a new, general experimental approach to study the structure of liquid states at supercooled conditions below their limit of homogeneous nucleation. We use femtosecond x-ray pulses generated by the LCLS x-ray laser to probe evaporatively cooled droplets of supercooled bulk water and find experimental evidence for the existence of metastable bulk liquid water down to temperatures of 223 K in the previously largely unexplored ``no man's land''. We acknoweledge NSF (CHE-0809324), Office of Basic Energy Sciences, and the Swedish Research Council for financial support.

  7. Structure/property relationships in polymer membranes for water purification and energy applications

    Science.gov (United States)

    Geise, Geoffrey

    Providing sustainable supplies of purified water and energy is a critical global challenge for the future, and polymer membranes will play a key role in addressing these clear and pressing global needs for water and energy. Polymer membrane-based processes dominate the desalination market, and polymer membranes are crucial components in several rapidly developing power generation and storage applications that rely on membranes to control rates of water and/or ion transport. Much remains unknown about the influence of polymer structure on intrinsic water and ion transport properties, and these relationships must be developed to design next generation polymer membrane materials. For desalination applications, polymers with simultaneously high water permeability and low salt permeability are desirable in order to prepare selective membranes that can efficiently desalinate water, and a tradeoff relationship between water/salt selectivity and water permeability suggests that attempts to prepare such materials should rely on approaches that do more than simply vary polymer free volume. One strategy is to functionalize hydrocarbon polymers with fixed charge groups that can ionize upon exposure to water, and the presence of charged groups in the polymer influences transport properties. Additionally, in many emerging energy applications, charged polymers are exposed to ions that are very different from sodium and chloride. Specific ion effects have been observed in charged polymers, and these effects must be understood to prepare charged polymers that will enable emerging energy technologies. This presentation discusses research aimed at further understanding fundamental structure/property relationships that govern water and ion transport in charged polymer films considered for desalination and electric potential field-driven applications that can help address global needs for clean water and energy.

  8. El aprendizaje bajo incertidumbre aplicado al mantenimiento de interruptores de potencia; Machine learning applied to the maintenance in high voltage breaker

    Directory of Open Access Journals (Sweden)

    Israel Gondres Torné

    2014-06-01

    Full Text Available La gestión del mantenimiento en las subestaciones eléctricas, así como en los interruptores de potencia ha evolucionado en el transcurso de los años de acuerdo a los equipos de medición de parámetros eléctricos y a las filosofías de mantenimiento mundial. El presente trabajo trata dichos avances desde una visión diferente, se utiliza la inteligencia artificial, específicamente el aprendizaje bajo incertidumbre para la toma de decisiones en la planificación del mantenimiento a los interruptores de potencia de una subestación. Se determina el índice de deterioro, los coeficientes de importancia del deterioro de cada tipo y del elemento del interruptor con la ayuda de los expertos. Posteriormente se obtienen los índices de membresías con los procesos correspondientes para la fusificación y defusificación; finalmente se realiza la evaluación de las reglas y defusificación para el tiempo de mantenimiento, implementando dicho método en diferentes interruptores de potencia. The maintenance management in electrical substations over the years has evolved according to the measurement equipment and the electrical parameters of global maintenance philosophies, and in particular the high voltage breakers have not been left behind. This paper is such advances from a different vision, artificial intelligence, specifically machine learning for decision-making in planning maintenance high voltage breaker sused in a substation. It determines the rate of deterioration, the coefficients of importance of each type of the deterioration and the high voltage breaker element with the help of experts. Subsequently are obtained the membership rates with the corresponding processes for fuzzification and defuzzification; finally the rule evaluation and defuzzification for the time maintenance is performed, the method is appliance in different high voltage breakers.

  9. Molecular Descriptors Family on Structure Activity Relationships 6. Octanol-Water Partition Coefficient of Polychlorinated Biphenyls

    Directory of Open Access Journals (Sweden)

    Lorentz JÄNTSCHI

    2006-01-01

    Full Text Available Octanol-water partition coefficient of two hundred and six polychlorinated biphenyls was model by the use of an original method based on complex information obtained from compounds structure. The regression analysis shows that best results are obtained in four-varied model (r2 = 0.9168. The prediction ability of the model was studied through leave-one-out analysis (r2cv(loo = 0.9093 and in training and test sets analysis. Modeling the octanol-water partition coefficient of polychlorinated biphenyls by integration of complex structural information provide a stable and performing four-varied model, allowing us to make remarks about relationship between structure of polychlorinated biphenyls and associated octanol-water partition coefficients.

  10. Diffusion under water-saturated conditions in PFA/OPC-based structural concrete

    International Nuclear Information System (INIS)

    Harris, A.W.; Nickerson, A.K.

    1990-05-01

    A substantial proportion of the volume of the UK radioactive waste repository is likely to be composed of materials based on hydraulic cements. This includes the structural components, which are likely to be manufactured from concrete. The mass transport characteristics of dissolved species for a typical structural concrete, based on a mixture of pulverised fuel ash and ordinary Portland cement, have been measured in a water-saturated condition. Both the water permeability and the diffusion parameters (for caesium, strontium and iodide ion and tritiated water diffusion) are low compared to values obtained for other structural concretes. The intrinsic diffusion coefficients for iodide and caesium ions are in the range 2-5x10 -14 m 2 s -1 . There is no evidence of significant sorption of any of the diffusants studied. (author)

  11. Numerical study of turbulence-influence mechanism on arc characteristics in an air direct current circuit breaker

    Science.gov (United States)

    Wu, Mingliang; Yang, Fei; Rong, Mingzhe; Wu, Yi; Qi, Yang; Cui, Yufei; Liu, Zirui; Guo, Anxiang

    2016-04-01

    This paper focuses on the numerical investigation of arc characteristics in an air direct current circuit breaker (air DCCB). Using magneto-hydrodynamics (MHD) theory, 3D laminar model and turbulence model are constructed and calculated. The standard k-epsilon model is utilized to consider the turbulence effect in the arc chamber of the DCCB. Several important phenomena are found: the arc column in the turbulence-model case is more extensive, moves much more slowly than the counterpart in the laminar-model case, and shows stagnation at the entrance of the chamber, unlike in the laminar-model case. Moreover, the arc voltage in the turbulence-model case is much lower than in the laminar-model case. However, the results in the turbulence-model case show a much better agreement with the results of the breaking experiments under DC condition than in the laminar-model case, which is contradictory to the previous conclusions from the arc researches of both the low-voltage circuit breaker and the sulfur hexafluoride (SF6) nozzle. First, in the previous air-arc research of the low-voltage circuit breaker, it is assumed that the air plasma inside the chamber is in the state of laminar, and the laminar-model application gives quite satisfactory results compared with the experiments, while in this paper, the laminar-model application works badly. Second, the turbulence-model application in the arc research of the SF6-nozzle performs much better and gives higher arc voltage than the laminar-model application does, whereas in this paper, the turbulence-model application predicts lower arc voltage than the laminar-model application does. Based on the analysis of simulation results in detail, the mechanism of the above phenomena is revealed. The transport coefficients are strongly changed by turbulence, which will enhance the arc diffusion and make the arc volume much larger. Consequently, the arc appearance and the distribution of Lorentz force in the turbulence-model case

  12. Numerical study of turbulence-influence mechanism on arc characteristics in an air direct current circuit breaker

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Mingliang; Yang, Fei, E-mail: yfei2007@mail.xjtu.edu.cn; Rong, Mingzhe; Wu, Yi; Qi, Yang; Cui, Yufei [State Key Lab of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi' an Jiaotong University, Xi' an Shaanxi 710049 (China); Liu, Zirui [State Grid Shaanxi Electric Power Company, Xi' an, Shaanxi (China); Guo, Anxiang [Electric Power Research Institute of State Grid Shaanxi Electric Power Company, Xi' an, Shaanxi (China)

    2016-04-15

    This paper focuses on the numerical investigation of arc characteristics in an air direct current circuit breaker (air DCCB). Using magneto-hydrodynamics (MHD) theory, 3D laminar model and turbulence model are constructed and calculated. The standard k-epsilon model is utilized to consider the turbulence effect in the arc chamber of the DCCB. Several important phenomena are found: the arc column in the turbulence-model case is more extensive, moves much more slowly than the counterpart in the laminar-model case, and shows stagnation at the entrance of the chamber, unlike in the laminar-model case. Moreover, the arc voltage in the turbulence-model case is much lower than in the laminar-model case. However, the results in the turbulence-model case show a much better agreement with the results of the breaking experiments under DC condition than in the laminar-model case, which is contradictory to the previous conclusions from the arc researches of both the low-voltage circuit breaker and the sulfur hexafluoride (SF6) nozzle. First, in the previous air-arc research of the low-voltage circuit breaker, it is assumed that the air plasma inside the chamber is in the state of laminar, and the laminar-model application gives quite satisfactory results compared with the experiments, while in this paper, the laminar-model application works badly. Second, the turbulence-model application in the arc research of the SF6-nozzle performs much better and gives higher arc voltage than the laminar-model application does, whereas in this paper, the turbulence-model application predicts lower arc voltage than the laminar-model application does. Based on the analysis of simulation results in detail, the mechanism of the above phenomena is revealed. The transport coefficients are strongly changed by turbulence, which will enhance the arc diffusion and make the arc volume much larger. Consequently, the arc appearance and the distribution of Lorentz force in the turbulence-model case

  13. Model-based leakage localization in drinking water distribution networks using structured residuals

    OpenAIRE

    Puig Cayuela, Vicenç; Rosich, Albert

    2013-01-01

    In this paper, a new model based approach to leakage localization in drinking water networks is proposed based on generating a set of structured residuals. The residual evaluation is based on a numerical method based on an enhanced Newton-Raphson algorithm. The proposed method is suitable for water network systems because the non-linearities of the model make impossible to derive analytical residuals. Furthermore, the computed residuals are designed so that leaks are decoupled, which impro...

  14. Branched ZnO wire structures for water collection inspired by cacti.

    Science.gov (United States)

    Heng, Xin; Xiang, Mingming; Lu, Zhihui; Luo, Cheng

    2014-06-11

    In this work, motivated by an approach used in a cactus to collect fog, we have developed an artificial water-collection structure. This structure includes a large ZnO wire and an array of small ZnO wires that are branched on the large wire. All these wires have conical shapes, whose diameters gradually increase from the tip to the root of a wire. Accordingly, a water drop that is condensed on the tip of each wire is driven to the root by a capillary force induced by this diameter gradient. The lengths of stem and branched wires in the synthesized structures are in the orders of 1 mm and 100 μm, respectively. These dimensions are, respectively, comparable to and larger than their counterparts in the case of a cactus. Two groups of tests were conducted at relative humidity of 100% to compare the amounts of water collected by artificial and cactus structures within specific time durations of 2 and 35 s, respectively. The amount of water collected by either type of structures was in the order of 0.01 μL. However, on average, what has been collected by the artificial structures was 1.4-5.0 times more than that harvested by the cactus ones. We further examined the mechanism that a cactus used to absorb a collected water drop into its stem. On the basis of the gained understanding, we developed a setup to successfully collect about 6 μL of water within 30 min.

  15. Structure and Dynamics in Formamide-(H2O)3: A Water Pentamer Analogue.

    Science.gov (United States)

    Blanco, Susana; Pinacho, Pablo; López, Juan Carlos

    2017-12-21

    Water self-association dominates the formation of microsolvated molecular clusters which may give rise to complex structures resembling those of pure water clusters. We present a rotational study of the complex formamide-(H 2 O) 3 formed in a supersonic jet and several monosubstituted isotopologues. Formamide and water molecules form a four-body sequential cycle through N-H···O, O-H···O, and O-H···O═C hydrogen bonds, resulting in a chiral structure with a nonplanar skeleton that can be overlapped to that of water pentamer. The analysis of the 14 N-nucleus quadrupole coupling effects shows the depletion of the electron density of the N atom lone pair with respect to the bare formamide that affects the amide group C-N and C═O distances. The study of the observed tunneling doublets shows that formamide-(H 2 O) 3 follows a path to invert its structure driven by the flipping of water subunits and passing through successive nonplanar configurations, a motion reminiscent of the pseudorotation of water pentamer.

  16. Polymer Structure and Water States in Salt-Containing Polyampholyte Hydrogels

    Science.gov (United States)

    Li, Xinda; Elliott, Janet A. W.; Lee, Byeongdu; Chung, Hyun-Joong

    The phase behavior of water in hydrogels has broad impact on various applications, such as lubrication, adhesion, and electrical conductivity, as well as the hydrogel's low temperature properties. The status of the water molecules is correlated to the structure of the polymer chains in the hydrogel. In this study, the structure and water status of a model charge-balanced polyampholyte poly(4-vinylbenzenesulfonate-co-[3-(methacryloylamino) propyl] trimethylammonium chloride), were investigated by using differential scanning calorimetry (DSC) and small-angle x-ray scattering (SAXS). A globular network structure suggested by SAXS results dictated the depression of the freezing point of water in the hydrogel, as supported by the DSC results. The polyampholyte chains undergo an irreversible collapse during dialysis in deionized water. Such collapsed hydrogels are not able to prevent freezing of water molecules. The results of both synthesis condition and post-synthesis treatments for polyampholyte hydrogels provide us insights to design optimal polyampholyte hydrogels for low temperature applications.

  17. Numerical simulation and structural optimization of the inclined oil/water separator.

    Directory of Open Access Journals (Sweden)

    Liqiong Chen

    Full Text Available Improving the separation efficiency of the inclined oil/water separator, a new type of gravity separation equipment, is of great importance. In order to obtain a comprehensive understanding of the internal flow field of the separation process of oil and water within this separator, a numerical simulation based on Euler multiphase flow analysis and the realizable k-ε two equation turbulence model was executed using Fluent software. The optimal value ranges of the separator's various structural parameters used in the numerical simulation were selected through orthogonal array experiments. A field experiment on the separator was conducted with optimized structural parameters in order to validate the reliability of the numerical simulation results. The research results indicated that the horizontal position of the dispenser, the hole number, and the diameter had significant effects on the oil/water separation efficiency, and that the longitudinal position of the dispenser and the position of the weir plate had insignificant effects on the oil/water separation efficiency. The optimal structural parameters obtained through the orthogonal array experiments resulted in an oil/water separation efficiency of up to 95%, which was 4.996% greater than that realized by the original structural parameters.

  18. The Structure and Transport of Water and Hydrated Ions Within Hydrophobic, Nanoscale Channels

    International Nuclear Information System (INIS)

    Holt, J.K.; Herberg, J.L.; Wu, Y.; Schwegler, E.; Mehta, A.

    2009-01-01

    The purpose of this project includes an experimental and modeling investigation into water and hydrated ion structure and transport at nanomaterials interfaces. This is a topic relevant to understanding the function of many biological systems such as aquaporins that efficiently shuttle water and ion channels that permit selective transport of specific ions across cell membranes. Carbon nanotubes (CNT) are model nanoscale, hydrophobic channels that can be functionalized, making them artificial analogs for these biological channels. This project investigates the microscopic properties of water such as water density distributions and dynamics within CNTs using Nuclear Magnetic Resonance (NMR) and the structure of hydrated ions at CNT interfaces via X-ray Absorption Spectroscopy (XAS). Another component of this work is molecular simulation, which can predict experimental measurables such as the proton relaxation times, chemical shifts, and can compute the electronic structure of CNTs. Some of the fundamental questions this work is addressing are: (1) what is the length scale below which nanoscale effects such as molecular ordering become important, (2) is there a relationship between molecular ordering and transport?, and (3) how do ions interact with CNT interfaces? These are questions of interest to the scientific community, but they also impact the future generation of sensors, filters, and other devices that operate on the nanometer length scale. To enable some of the proposed applications of CNTs as ion filtration media and electrolytic supercapacitors, a detailed knowledge of water and ion structure at CNT interfaces is critical.

  19. NRC Information Notice No. 93-22: Tripping of Klockner-Moeller molded-case circuit breakers due to support lever failure

    International Nuclear Information System (INIS)

    Grimes, B.K.

    1993-01-01

    On July 1, 1992, Virginia Electric and Power Company (VEPCO), licensee for North Anna Power Station (North Anna), Units 1 and 2, reported to the NRC that over a three-month period in 1992, three K-M model NZM6-63, 480-Vac MCCBs had tripped without appreciable load or fault condition or other electrical or mechanical transient. The three failed MCCBs were located in the cable vault and tunnel area of North Anna-2 and supplied power to motor operated valves in the charging and safety injection systems. The switch handles were found in the trip-free position and the breakers could not be relatched and reclosed. Examination of the internals of one of the three failed breakers revealed that its support lever (also described by VEPCO as a ''spring arm''), located in the rear compartment of the case, had fractured. This caused the breaker to trip and to become incapable of being reclosed. The NRC has determined that the support levers only in K-M model NZM6, NZM6b, and NZMH6 MCCBs, rated for 100 amperes and below and manufactured from 1972 on, have been made of the same type of plastic used in the support levers of the MCCBs that failed at North Anna-2

  20. Stomatal structure and physiology do not explain differences in water use among montane eucalypts.

    Science.gov (United States)

    Gharun, Mana; Turnbull, Tarryn L; Pfautsch, Sebastian; Adams, Mark A

    2015-04-01

    Understanding the regulation of water use at the whole-tree scale is critical to advancing the utility of physiological ecology, for example in its role in predictive hydrology of forested catchments. For three eucalypt species that dominate high-elevation catchments in south-eastern Australia, we examined if whole-tree water use could be related to three widely discussed regulators of water use: stomatal anatomy, sensitivity of stomata [i.e. stomatal conductance (g(s))] to environmental influences, and sapwood area. While daily tree water use varied sixfold among species, sap velocity and sapwood area varied in parallel. Combined, stomatal structure and physiology could not explain differences in species-specific water use. Species which exhibited the fastest (Eucalyptus delegatensis) and slowest (Eucalyptus pauciflora) rates of water use both exhibited greater capacity for physiological control of g(s) [indicated by sensitivity to vapour pressure deficit (VPD)] and a reduced capacity to limit g(s) anatomically [indicated by greater potential g(s) (g(max))]. Conversely, g(s) was insensitive to VPD and g(max) was lowest for Eucalyptus radiata, the species showing intermediate rates of water use. Improved knowledge of stomatal anatomy will help us to understand the capacity of species to regulate leaf-level water loss, but seems likely to remain of limited use for explaining rates of whole-tree water use in montane eucalypts at the catchment scale.

  1. Structural Models of Water and Ice Regarding the Energy of Hydrogen Bonding

    OpenAIRE

    Ignat Ignatov; Oleg Mosin

    2015-01-01

    In this review it is reported about the research on the structure of water and ice and intermolecular water cyclic associates (clusters) with general formula (Н2О)n and their charged ionic clusters [(Н2О)n]+ and [(Н2О)n]- by means of computer modelling and spectroscopy methods as 1Н-NMR, IR-spectroscopy, DNES, EXAFS-spectroscopy, X-Ray and neurons diffraction. The computer calculation of polyhedral nanoclusters (Н2О)n, where n = 3–20 are carried out. Based on this data the main structural mat...

  2. Method to study water hammer with fluid-structure interaction in spatial pipe

    International Nuclear Information System (INIS)

    Xi Zhide; Ma Jianzhong; Sun Lei

    2013-01-01

    The theory of coupling 4-function models and its solution approach are first introduced in this paper, and the method of CFD to calculate fluid-structure interaction is also introduced. Finally, the model in related reference is applied with this method to simulate the process of water hammer. By CFD calculation for the classical water hammer, the numerical scheme and grid are selected, and the results of CFD are compared with reference. The results show that the method in this paper can be used in more complex pipe system to simulate the water hammer effect. (authors)

  3. Water-mediated variability in the structure of relaxed-state haemoglobin

    International Nuclear Information System (INIS)

    Kaushal, Prem Singh; Sankaranarayanan, R.; Vijayan, M.

    2008-01-01

    Partial dehydration of high-salt horse methaemoglobin crystals tends to shift the structure from the R state to the R2 state, in agreement with previous observations that movements in the molecule resulting from changes in water content mimic those involved in protein action. The crystal structure of high-salt horse methaemoglobin has been determined at environmental relative humidities (r.h.) of 88, 79, 75 and 66%. The molecule is in the R state in the native and the r.h. 88% crystals. At r.h. 79%, the water content of the crystal is reduced and the molecule appears to move towards the R2 state. The crystals undergo a water-mediated transformation involving a doubling of one of the unit-cell parameters and an increase in water content when the environmental humidity is further reduced to r.h. 75%. The water content is now similar to that in the native crystals and the molecules are in the R state. The crystal structure at r.h. 66% is similar, but not identical, to that at r.h. 75%, but the solvent content is substantially reduced and the molecules have a quaternary structure that is in between those corresponding to the R and R2 states. Thus, variation in hydration leads to variation in the quaternary structure. Furthermore, partial dehydration appears to shift the structure from the R state to the R2 state. This observation is in agreement with the earlier conclusion that the changes in protein structure that accompany partial dehydration are similar to those that occur during protein action

  4. The changes of macroscopic features and microscopic structures of water under influence of magnetic field

    International Nuclear Information System (INIS)

    Pang Xiaofeng; Deng Bo

    2008-01-01

    Influences of magnetic field on microscopic structures and macroscopic properties of water are studied by the spectrum techniques of infrared, Raman, visible, ultraviolet lights and X-ray. From these investigations, we know that the magnetic fields change the distribution of molecules and electrons, cause displacements and polarization of molecules and atoms, result in changes of dipole-moment transition and vibrational states of molecules and variation of transition probability of electrons, but does not alter the constitution of molecules and atoms. These are helpful in seeking the mechanism of magnetization of water. Meanwhile, we also measure the changed rules of the surface tension force, soaking effect or angle of contact, viscosity, rheology features, refraction index, dielectric constant and electric conductivity of magnetized water relative to that of pure water. The results show that the magnetic fields increase the soaking degree and hydrophobicity of water to materials, depress its surface-tension force, diminish the viscosity of war, enhance the feature of plastic flowing of water, and increase the refraction index, dielectric constant and electric conductivity of water after magnetization. These changes are caused by the above changes of microscopic structures under the action of magnetic field. Therefore, our studies are significant in science and has practical value of applications

  5. Prediction of the effects of size and morphology on the structure of water around hematite nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Spagnoli, D.; Gilbert, B.; Waychunas, G.A.; Banfield, J. F.

    2009-05-15

    Compared with macroscopic surfaces, the structure of water around nanoparticles is difficult to probe directly. We used molecular dynamics simulations to investigate the effects of particle size and morphology on the time-averaged structure and the dynamics of water molecules around two sizes of hematite ({alpha}-Fe{sub 2}O{sub 3}) nanoparticles. Interrogation of the simulations via atomic density maps, radial distribution functions and bound water residence times provide insight into the relationships between particle size and morphology and the behavior of interfacial water. Both 1.6 and 2.7 nm particles are predicted to cause the formation of ordered water regions close to the nanoparticle surface, but the extent of localization and ordering, the connectivity between regions of bound water, and the rates of molecular exchange between inner and outer regions are all affected by particle size and morphology. These findings are anticipated to be relevant to understanding the rates of interfacial processes involving water exchange and the transport of aqueous ions to surface sites.

  6. Structure of ionic liquid-water mixtures at interfaces: x-ray and neutron reflectometry studies

    International Nuclear Information System (INIS)

    Lauw, Yansen; Rodopoulos, Theo; Horne, Mike; Follink, Bart; Hamilton, Bill; Knott, Robert; Nelson, Andy

    2009-01-01

    Full text: Fundamental studies on the effect of water in ionic liquids are necessary since the overall performance of ionic liquids in many industrial applications is often hampered by the presence of water.[1] Based on this understanding, the surface and interfacial structures of 1-butyl-1methylpyrrolidinium trifluoromethylsulfonylimide [C4mpyr][NTf2] ionic liquid-water mixtures were probed using x-ray and neutron reflectometry techniques. At the gas-liquid surface, a thick cation+water layer was detected next to the phase boundary, followed by an increasing presence of anion towards the bulk. The overall thickness of the surface exhibits non-monotonic trends with an increasing water content, which explains similar phenomenological trends in surface tension reported in the literature.[2] At an electrified interface, the interfacial structure of pure ionic liquids probed by neutron reflectometry shows similar trends to those predicted by a mean-field model.[3] However, the presence of water within the electrical double-layer is less obvious, although it is widely known that water reduces electrochemical window of ionic liquids. To shed light on this issue, further studies are currently in progress.

  7. Molecular Structure and Dynamics of Water on Pristine and Strained Phosphorene: Wetting and Diffusion at Nanoscale.

    Science.gov (United States)

    Zhang, Wei; Ye, Chao; Hong, Linbi; Yang, Zaixing; Zhou, Ruhong

    2016-12-06

    Phosphorene, a newly fabricated two-dimensional (2D) nanomaterial, has emerged as a promising material for biomedical applications with great potential. Nonetheless, understanding the wetting and diffusive properties of bio-fluids on phosphorene which are of fundamental importance to these applications remains elusive. In this work, using molecular dynamics (MD) simulations, we investigated the structural and dynamic properties of water on both pristine and strained phosphorene. Our simulations indicate that the diffusion of water molecules on the phosphorene surface is anisotropic, with strain-enhanced diffusion clearly present, which arises from strain-induced smoothing of the energy landscape. The contact angle of water droplet on phosphorene exhibits a non-monotonic variation with the transverse strain. The structure of water on transverse stretched phosphorene is demonstrated to be different from that on longitudinal stretched phosphorene. Moreover, the contact angle of water on strained phosphorene is proportional to the quotient of the longitudinal and transverse diffusion coefficients of the interfacial water. These findings thereby offer helpful insights into the mechanism of the wetting and transport of water at nanoscale, and provide a better foundation for future biomedical applications of phosphorene.

  8. Hydrate phase equilibrium and structure for (methane + ethane + tetrahydrofuran + water) system

    International Nuclear Information System (INIS)

    Sun Changyu; Chen Guangjin; Zhang Lingwei

    2010-01-01

    The separation of methane and ethane through forming hydrate is a possible choice in natural gas, oil processing, or ethylene producing. The hydrate formation conditions of five groups of (methane + ethane) binary gas mixtures in the presence of 0.06 mole fraction tetrahydrofuran (THF) in water were obtained at temperatures ranging from (277.7 to 288.2) K. In most cases, the presence of THF in water can lower the hydrate formation pressure of (methane + ethane) remarkably. However, when the composition of ethane is as high as 0.832, it is more difficult to form hydrate than without THF system. Phase equilibrium model for hydrates containing THF was developed based on a two-step hydrate formation mechanism. The structure of hydrates formed from (methane + ethane + THF + water) system was also determined by Raman spectroscopy. When THF concentration in initial aqueous solution was only 0.06 mole fraction, the coexistence of structure I hydrate dominated by ethane and structure II hydrate dominated by THF in the hydrate sample was clearly demonstrated by Raman spectroscopic data. On the contrary, only structure II hydrate existed in the hydrate sample formed from (methane + ethane + THF + water) system when THF concentration in initial aqueous solution was increased to 0.10 mole fraction. It indicated that higher THF concentration inhibited the formation of structure I hydrate dominated by ethane and therefore lowered the trapping of ethane in hydrate. It implies a very promising method to increase the separation efficiency of methane and ethane.

  9. Structural analysis on mutation residues and interfacial water molecules for human TIM disease understanding

    Science.gov (United States)

    2013-01-01

    Background Human triosephosphate isomerase (HsTIM) deficiency is a genetic disease caused often by the pathogenic mutation E104D. This mutation, located at the side of an abnormally large cluster of water in the inter-subunit interface, reduces the thermostability of the enzyme. Why and how these water molecules are directly related to the excessive thermolability of the mutant have not been investigated in structural biology. Results This work compares the structure of the E104D mutant with its wild type counterparts. It is found that the water topology in the dimer interface of HsTIM is atypical, having a "wet-core-dry-rim" distribution with 16 water molecules tightly packed in a small deep region surrounded by 22 residues including GLU104. These water molecules are co-conserved with their surrounding residues in non-archaeal TIMs (dimers) but not conserved across archaeal TIMs (tetramers), indicating their importance in preserving the overall quaternary structure. As the structural permutation induced by the mutation is not significant, we hypothesize that the excessive thermolability of the E104D mutant is attributed to the easy propagation of atoms' flexibility from the surface into the core via the large cluster of water. It is indeed found that the B factor increment in the wet region is higher than other regions, and, more importantly, the B factor increment in the wet region is maintained in the deeply buried core. Molecular dynamics simulations revealed that for the mutant structure at normal temperature, a clear increase of the root-mean-square deviation is observed for the wet region contacting with the large cluster of interfacial water. Such increase is not observed for other interfacial regions or the whole protein. This clearly suggests that, in the E104D mutant, the large water cluster is responsible for the subunit interface flexibility and overall thermolability, and it ultimately leads to the deficiency of this enzyme. Conclusions Our study

  10. Shock modon: a new type of coherent structure in rotating shallow water.

    Science.gov (United States)

    Lahaye, Noé; Zeitlin, Vladimir

    2012-01-27

    We show that a new type of coherent structure, a shock modon, exists in a rotating shallow water model at large Rossby numbers. It is a combination of an asymmetric vortex dipole with a stationary hydraulic jump. The structure is long living, despite the energy dissipation by the hydraulic jump, and moving along a circular path. Collisions of shock modons can be elastic, or lead to formation of shock tripoles.

  11. Impact of curved shaped energy dissipaters downstream of head structures on both water energy dissipation and irrigation water quality

    Directory of Open Access Journals (Sweden)

    Ashour Mohamed A.

    2015-03-01

    Full Text Available Using energy dissipaters on the soled aprons downstream of head structures is the main technique for accelerating hydraulic jump formation and dissipating a great amount of the residual harmful kinetic energy occurring downstream of head structures. In this paper, an experimental study was conducted to investigate some untested shapes of curved dissipaters with different angles of curvature and arrangements from two points of view. The first is to examine its efficiency in dissipating the kinetic water energy. The second is to examine the most effective shape and arrangement obtained from the aforementioned step in enriching the flow with dissolved oxygen for enhancement of the irrigation water quality. The study was held in the irrigation and hydraulic laboratory of the Civil Department, Faculty of Engineering, Assiut University, using a movable bed tilting channel 20 m long, 30 cm wide, and 50 cm high, using 21 types of curved dissipaters with different arrangements. A total of 660 runs were carried out. Results were analysed, tabulated and graphically presented, and new formulas were introduced to estimate the energy dissipation ratio, as well as the DO concentrations. Results in general showed that the dissipater performance is more tangible in dissipating the residual energy when the curvature is in the opposite direction to that of the flow. Also, the energy loss ratio increases with an increase in curvature angle (θ, until it reaches (θ = 120°, then it decreases again. The study also showed that using three rows of dissipaters give nearly the same effect as using four rows, concerning both the relative energy dissipation and dissolved oxygen content. So, it is recommended to use three rows of the curved dissipater with the angle of curvature (θ = 120° in the opposite direction to that of the flow to obtain the maximum percentage of water energy dissipation downstream of head structures, and maximum dissolved oxygen content too

  12. Water

    Science.gov (United States)

    ... www.girlshealth.gov/ Home Nutrition Nutrition basics Water Water Did you know that water makes up more ... to drink more water Other drinks How much water do you need? top Water is very important, ...

  13. Social and Structural Patterns of Drought-Related Water Conservation and Rebound

    Science.gov (United States)

    Gonzales, Patricia; Ajami, Newsha

    2017-12-01

    Water use practices and conservation are the result of complex sociotechnical interactions of political, economic, hydroclimatic, and social factors. While the drivers of water demand have been extensively studied, they have traditionally been applied to models that assume stationary relationships between these various factors, and usually do not account for potential societal changes in response to increased scarcity awareness. For example, following a period of sustained low demand such as during a drought, communities often increase water use during a hydrologically wet period, a phenomenon known as "rebounding" water use. Previous experiences show the extent of this rebound is not a straightforward function of policy and efficiency improvements, but may also reflect short-term or long-lasting change in community behavior, which are not easily captured by models that assume stationarity. In this work, we develop a system dynamics model to represent water demand as a function of both structural and social factors. We apply this model to the analysis of three diverse water utilities in the San Francisco Bay Area between 1980 and 2017, identifying drought response trends and drivers over time. Our model is consistent with empirical patterns and historical context of water use in California, and provides important insights on the rebound phenomenon that can be extended to other locations. This comparative assessment indicates that policies, public outreach, and better data availability have played a key role in raising public awareness of water scarcity, especially with the raise of the internet era in recent years.

  14. Ice crystallization in ultrafine water-salt aerosols: nucleation, ice-solution equilibrium, and internal structure.

    Science.gov (United States)

    Hudait, Arpa; Molinero, Valeria

    2014-06-04

    Atmospheric aerosols have a strong influence on Earth's climate. Elucidating the physical state and internal structure of atmospheric aqueous aerosols is essential to predict their gas and water uptake, and the locus and rate of atmospherically important heterogeneous reactions. Ultrafine aerosols with sizes between 3 and 15 nm have been detected in large numbers in the troposphere and tropopause. Nanoscopic aerosols arising from bubble bursting of natural and artificial seawater have been identified in laboratory and field experiments. The internal structure and phase state of these aerosols, however, cannot yet be determined in experiments. Here we use molecular simulations to investigate the phase behavior and internal structure of liquid, vitrified, and crystallized water-salt ultrafine aerosols with radii from 2.5 to 9.5 nm and with up to 10% moles of ions. We find that both ice crystallization and vitrification of the nanodroplets lead to demixing of pure water from the solutions. Vitrification of aqueous nanodroplets yields nanodomains of pure low-density amorphous ice in coexistence with vitrified solute rich aqueous glass. The melting temperature of ice in the aerosols decreases monotonically with an increase of solute fraction and decrease of radius. The simulations reveal that nucleation of ice occurs homogeneously at the subsurface of the water-salt nanoparticles. Subsequent ice growth yields phase-segregated, internally mixed, aerosols with two phases in equilibrium: a concentrated water-salt amorphous mixture and a spherical cap-like ice nanophase. The surface of the crystallized aerosols is heterogeneous, with ice and solution exposed to the vapor. Free energy calculations indicate that as the concentration of salt in the particles, the advance of the crystallization, or the size of the particles increase, the stability of the spherical cap structure increases with respect to the alternative structure in which a core of ice is fully surrounded by

  15. Characterization of a Novel Water Pocket Inside the Human Cx26 Hemichannel Structure

    Science.gov (United States)

    Araya-Secchi, Raul; Perez-Acle, Tomas; Kang, Seung-gu; Huynh, Tien; Bernardin, Alejandro; Escalona, Yerko; Garate, Jose-Antonio; Martínez, Agustin D.; García, Isaac E.; Sáez, Juan C.; Zhou, Ruhong

    2014-01-01

    Connexins (Cxs) are a family of vertebrate proteins constituents of gap junction channels (GJCs) that connect the cytoplasm of adjacent cells by the end-to-end docking of two Cx hemichannels. The intercellular transfer through GJCs occurs by passive diffusion allowing the exchange of water, ions, and small molecules. Despite the broad interest to understand, at the molecular level, the functional state of Cx-based channels, there are still many unanswered questions regarding structure-function relationships, perm-selectivity, and gating mechanisms. In particular, the ordering, structure, and dynamics of water inside Cx GJCs and hemichannels remains largely unexplored. In this work, we describe the identification and characterization of a believed novel water pocket—termed the IC pocket—located in-between the four transmembrane helices of each human Cx26 (hCx26) monomer at the intracellular (IC) side. Using molecular dynamics (MD) simulations to characterize hCx26 internal water structure and dynamics, six IC pockets were identified per hemichannel. A detailed characterization of the dynamics and ordering of water including conformational variability of residues forming the IC pockets, together with multiple sequence alignments, allowed us to propose a functional role for this cavity. An in vitro assessment of tracer uptake suggests that the IC pocket residue Arg-143 plays an essential role on the modulation of the hCx26 hemichannel permeability. PMID:25099799

  16. Structural integrity investigation for RPV with various cooling water levels under pressurized melting pool

    Directory of Open Access Journals (Sweden)

    J. Mao

    2018-03-01

    Full Text Available The strategy denoted as in-vessel retention (IVR is widely used in severe accident (SA management by most advanced nuclear power plants. The essence of IVR mitigation is to provide long-term external water cooling in maintaining the reactor pressure vessel (RPV integrity. Actually, the traditional IVR concept assumed that RPV was fully submerged into the water flooding, and the melting pool was depressurized during the SA. The above assumptions weren't seriously challenged until the occurrence of Fukushima accident on 2011, suggesting the structural behavior had not been appropriately assessed. Therefore, the paper tries to address the structure-related issue on determining whether RPV safety can be maintained or not with the effect of various water levels and internal pressures created from core meltdown accident. In achieving it, the RPV structural behaviors are numerically investigated in terms of several field parameters, such as temperature, deformation, stress, plastic strain, creep strain, and total damage. Due to the presence of high temperature melt on the inside and water cooling on the outside, the RPV failure is governed by the failure mechanisms of creep, thermal-plasticity and plasticity. The creep and plastic damages are interacted with each other, which further accelerate the failure process. Through detailed investigation, it is found that the internal pressure as well as water levels plays an important role in determining the RPV failure time, mode and site.

  17. The influence of Critical Zone structure on runoff paths, seasonal water storage, and ecosystem composition

    Science.gov (United States)

    Hahm, W. J.; Dietrich, W. E.; Rempe, D.; Dralle, D.; Dawson, T. E.; Lovill, S.; Bryk, A.

    2017-12-01

    Understanding how subsurface water storage mediates water availability to ecosystems is crucial for elucidating linkages between water, energy, and carbon cycles from local to global scales. Earth's Critical Zone (the CZ, which extends from the top of the vegetation canopy downward to fresh bedrock) includes fractured and weathered rock layers that store and release water, thereby contributing to ecosystem water supplies, and yet are not typically represented in land-atmosphere models. To investigate CZ structural controls on water storage dynamics, we intensively studied field sites in a Mediterranean climate where winter rains arrive months before peak solar energy availability, resulting in strong summertime ecosystem reliance on stored subsurface water. Intra-hillslope and catchment-wide observations of CZ water storage capacity across a lithologic boundary in the Franciscan Formation of the Northern California Coast Ranges reveal large differences in the thickness of the CZ and water storage capacity that result in a stark contrast in plant community composition and stream behavior. Where the CZ is thick, rock moisture storage supports forest transpiration and slow groundwater release sustains baseflow and salmon populations. Where the CZ is thin, limited water storage is used by an oak savanna ecosystem, and streams run dry in summer due to negligible hillslope drainage. At both sites, wet season precipitation replenishes the dynamic storage deficit generated during the summer dry season, with excess winter rains exiting the watersheds via storm runoff as perched groundwater fracture flow at the thick-CZ site and saturation overland flow at the thin-CZ site. Annual replenishment of subsurface water storage even in severe drought years may lead to ecosystem resilience to climatic perturbations: during the 2011-2015 drought there was not widespread forest die-off in the study area.

  18. 76 FR 43230 - National Pollutant Discharge Elimination System-Cooling Water Intake Structures at Existing...

    Science.gov (United States)

    2011-07-20

    ... ENVIRONMENTAL PROTECTION AGENCY 40 CFR Parts 122 and 125 [EPA-HQ-OW-2008-0667, FRL-9441-8] RIN 2040-AE95 National Pollutant Discharge Elimination System--Cooling Water Intake Structures at Existing Facilities and Phase I Facilities AGENCY: Environmental Protection Agency (EPA). ACTION: Proposed rule...

  19. Sonneratiaceae (concluded). Sonneratiaceae and other mangrove-swamp families, anatomical structure and water relations

    NARCIS (Netherlands)

    Reinders-Gouwentak, C.A.

    1948-01-01

    The question whether tidal and non-tidal members of a family have a separate wood anatomical structure would be examined best in such genera as embrace both types. The sequel to this examination, whether any such differences are connected with peculiarities in the water relations of the plants,

  20. Atomic-scale structures of interfaces between phyllosilicate edges and water

    NARCIS (Netherlands)

    Liu, X.; Lu, X.; Meijer, E.J.; Wang, R.; Zhou, H.

    2012-01-01

    We report first-principles molecular dynamics (FPMD) studies on the structures of interfaces between phyllosilicate edges and water. Using FPMD, the substrates and solvents are simulated at the same first-principles level, and the thermal motions are sampled via molecular dynamics. Both the neutral

  1. Institutional and structural barriers for implementing on-farm water saving irrigation systems

    DEFF Research Database (Denmark)

    Pedersen, Søren Marcus; Boesen, Mads Vejlby; Ørum, Jens Erik

    2013-01-01

    institutional and structural barriers for shifting to more water efficient technologies on farms. To deal with the lack of incentives, a holistic and multidisciplinary assessment approach has been taken to cover the various parameters that may influence farmers' choice of technology. A case study analysis has...

  2. Animal Hairs as Water-stimulated Shape Memory Materials: Mechanism and Structural Networks in Molecular Assemblies

    Science.gov (United States)

    Xiao, Xueliang; Hu, Jinlian

    2016-05-01

    Animal hairs consisting of α-keratin biopolymers existing broadly in nature may be responsive to water for recovery to the innate shape from their fixed deformation, thus possess smart behavior, namely shape memory effect (SME). In this article, three typical animal hair fibers were first time investigated for their water-stimulated SME, and therefrom to identify the corresponding net-points and switches in their molecular and morphological structures. Experimentally, the SME manifested a good stability of high shape fixation ratio and reasonable recovery rate after many cycles of deformation programming under water stimulation. The effects of hydration on hair lateral size, recovery kinetics, dynamic mechanical behaviors and structural components (crystal, disulfide and hydrogen bonds) were then systematically studied. SME mechanisms were explored based on the variations of structural components in molecular assemblies of such smart fibers. A hybrid structural network model with single-switch and twin-net-points was thereafter proposed to interpret the water-stimulated shape memory mechanism of animal hairs. This original work is expected to provide inspiration for exploring other natural materials to reveal their smart functions and natural laws in animals including human as well as making more remarkable synthetic smart materials.

  3. Destabilization of the hydrogen-bond structure of water by the osmolyte trimethylamine N-oxide

    NARCIS (Netherlands)

    Rezus, Y.L.A.; Bakker, H.J.

    2009-01-01

    We use femtosecond mid-infrared pump−probe spectroscopy to investigate the effects of the osmolyte trimethylamine N-oxide (TMAO) on the structural dynamics of water. As a comparison, we also investigate the effects of other amphiphilic molecules: tetramethylurea (TMU), urea, proline, and

  4. Water hammer with fluid-structure interaction in thick-walled pipes

    NARCIS (Netherlands)

    Tijsseling, A.S.

    2007-01-01

    A one-dimensional mathematical model is presented which describes the acoustic behaviour of thick-walled liquid-filled pipes. The model is based on conventional water-hammer and beam theories. Fluid–structure interaction (FSI) is taken into account. The equations governing straight pipes are derived

  5. Structure and stability of triglyceride monolayers on water and mica surfaces

    NARCIS (Netherlands)

    Zdravkova, A.N.; van der Eerden, J.P.J.M.

    2007-01-01

    The structure and the stability of tripalmitin (PPP), tristearin (SSS), and triarachidin (AAA) monolayers at the air-water interface are investigated with the Langmuir method. The Langmuir-Blodgett (LB) layers obtained by deposition on mica were investigated with atomic force microscopy (AFM). Our

  6. The effect of water content on the magnetic and structural properties of goethite

    International Nuclear Information System (INIS)

    Betancur, J.D.; Barrero, C.A.; Greneche, J.M.; Goya, G.F.

    2004-01-01

    We have studied the effect of water content on the magnetic and structural properties of goethite. For that purpose, four samples were prepared using two different hydrothermal methods, one of them is derived on the Fe(II) precursors and the other one from Fe(III) precursors. The samples were characterized by X-ray diffraction (XRD), TGA, BET, FTIR, Moessbauer spectrometry at RT, 77 and 4.2 K and ZFC and FC curves. The results suggest that the goethites from the Fe(II) precursors are less crystalline, have higher water contents and do not show magnetic ordered structure at RT in comparison to the goethites from the Fe(III) precursors. The goethites from the last systems exhibit good crystallinity, low water content and magnetic ordering at room temperature. Our results suggest that both structural and adsorbed water contents reduce the magnetic hyperfine field at 4.2 K. A linear correlation with regression coefficient of 0.91 between the saturation hyperfine field and both the structural hydroxyl content and the surface area could be derived

  7. Designing robust alumina nanowires-on-nanopores structures: superhydrophobic surfaces with slippery or sticky water adhesion.

    Science.gov (United States)

    Peng, Shan; Tian, Dong; Miao, Xinrui; Yang, Xiaojun; Deng, Wenli

    2013-11-01

    Hierarchical alumina surfaces with different morphologies were fabricated by a simple one-step anodization method. These alumina films were fabricated by a new raw material: silica gel plate (aluminum foil with a low purity of 97.17%). The modulation of anodizing time enabled the formation of nanowires-on-nanopores hybrid nanostructures having controllable nanowires topographies through a self-assembly process. The resultant structures were demonstrated to be able to achieve superhydrophobicity without any hydrophobic coating layer. More interestingly, it is found that the as-prepared superhydrophobic alumina surfaces exhibited high contrast water adhesion. Hierarchical alumina film with nanowire bunches-on-nanopores (WBOP) morphology presents extremely slippery property which can obtain a sliding angle (SA) as low as 1°, nanowire pyramids-on-nanopores (WPOP) structure shows strongly sticky water adhesion with the adhesive ability to support 15 μL inverted water droplet at most. The obtained superhydrophobic alumina surfaces show remarkable mechanical durability even treated by crimping or pressing without impact on the water-repellent performance. Moreover, the created surfaces also show excellent resistivity to ice water, boiling water, high temperature, organic solvent and oil contamination, which could expand their usefulness and efficacy in harsh conditions. Copyright © 2013 Elsevier Inc. All rights reserved.

  8. Encapsulating fly ash and acidic process waste water in brick structure

    International Nuclear Information System (INIS)

    Koseoglu, K.; Polat, M.; Polat, H.

    2010-01-01

    Fly ash contains metals such as cadmium, iron, lead, aluminum and zinc in its structure in appreciable amounts. These metals can leach out into surface and ground waters if fly ash is not properly disposed of. A similar problem also exists for acidic process waste waters discharged by numerous industries. The purpose of this study was to utilize such wastes as additives in the production of construction quality bricks for the purpose of waste elimination. The bricks produced were subjected to flexural strength and water retention capacity tests along with heavy metal leaching experiments in order to determine the applicability of the procedure and the best possible recipes. This paper summarizes the results obtained in these tests along with the possible mechanisms involved in stabilizing the two wastes in the brick structure.

  9. Income, Economic Structure and Trade: Impacts on Recent Water Use Trends in the European Union

    Directory of Open Access Journals (Sweden)

    Rosa Duarte

    2018-01-01

    Full Text Available From the mid-1990s to the recent international economic crisis, the European Union (EU27 experienced a significant economic growth and a flat population increase. During these years, the water resources directly used by the EU countries displayed a growing but smooth trend. However, European activities intensively demanded water resources throughout the whole global supply chain. The growth rate of embodied water use was three times higher than the growth in water directly used by these economies. This was mainly due to the large upsurge of virtual water imports in the EU (e.g., about 25% of the change in water imports in the world was directly linked to the increasing imports in the EU27 countries. In this context, we analyze water use changes in the EU27 from 1995 to 2009, combining the production and consumption perspectives. To that aim, we use the environmentally extended input-output approach to obtain the volume of water embodied in domestic production and in trade flows at the sector and country levels. In the empirical analysis, we utilize multi-regional input-output data from the World Input Output Database. In addition, by means of a structural decomposition analysis we identify and quantify the factors explaining changes in these trends. We focus both on the role of domestic production and trade and estimate the associated intensity, technology and scale effects. This analysis is done for different clusters, identifying singular patterns depending on income criteria. Our results confirm the boost of demand growth in that period, the positive but negligible effect of structural change, and the decline in water intensity which, however, was not enough to compensate the effects on water associated to the economic expansion in the period. These findings also point at a gradual substitution of domestic water use for virtual water imports. More concretely, in most countries the food industry tended to reduce its backward linkages with the

  10. Protonic charge defect structures in floating water bridges observed as Zundel and Eigen solvation arrangements

    Science.gov (United States)

    Teschke, Omar; de Castro, Jose Roberto; Valente Filho, Juracyr Ferraz; Soares, David Mendez

    2017-10-01

    Protonic arrangements were detected in water bridge structures using confocal Raman microscopy, and the spectra show two formed structures. The measured Raman spectra were modified using the voltage applied to the bridge structure, which changed the proportion of these two species. Initially, for a 6.3 kV applied voltage, there was a measurable increase in the bridge current above the Ohmic contribution and the observed Raman spectrum of this new injected specie corresponded to the computed spectrum for the Zundel protonic arrangement. As the voltage further increases a contribution from the Eigen proton solvation specie is added to the measured spectrum.

  11. Microscopic dynamics of water around unfolded structures of barstar at room temperature

    Energy Technology Data Exchange (ETDEWEB)

    Pal, Somedatta; Chakraborty, Kaushik; Khatua, Prabir; Bandyopadhyay, Sanjoy, E-mail: sanjoy@chem.iitkgp.ernet.in [Molecular Modeling Laboratory, Department of Chemistry, Indian Institute of Technology, Kharagpur 721302 (India)

    2015-02-07

    The breaking of the native structure of a protein and its influences on the dynamic response of the surrounding solvent is an important issue in protein folding. In this work, we have carried out atomistic molecular dynamics simulations to unfold the protein barstar at two different temperatures (400 K and 450 K). The two unfolded forms obtained at such high temperatures are further studied at room temperature to explore the effects of nonuniform unfolding of the protein secondary structures along two different pathways on the microscopic dynamical properties of the surface water molecules. It is demonstrated that though the structural transition of the protein in general results in less restricted water motions around its segments, but there are evidences of formation of new conformational motifs upon unfolding with increasingly confined environment around them, thereby resulting in further restricted water mobility in their hydration layers. Moreover, it is noticed that the effects of nonuniform unfolding of the protein segments on the relaxation times of the protein–water (PW) and the water–water (WW) hydrogen bonds are correlated with hindered hydration water motions. However, the kinetics of breaking and reformation of such hydrogen bonds are found to be influenced differently at the interface. It is observed that while the effects of unfolding on the PW hydrogen bond kinetics seem to be minimum, but the kinetics involving the WW hydrogen bonds around the protein segments exhibit noticeably heterogeneous characteristics. We believe that this is an important observation, which can provide valuable insights on the origin of heterogeneous influence of unfolding of a protein on the microscopic properties of its hydration water.

  12. Structural Modifications of Fructans in Aloe barbadensis Miller (Aloe Vera) Grown under Water Stress.

    Science.gov (United States)

    Salinas, Carlos; Handford, Michael; Pauly, Markus; Dupree, Paul; Cardemil, Liliana

    2016-01-01

    Aloe barbadensis Miller (Aloe vera) has a Crassulaceae acid metabolism which grants the plant great tolerance to water restrictions. Carbohydrates such as acemannans and fructans are among the molecules responsible for tolerating water deficit in other plant species. Nevertheless, fructans, which are prebiotic compounds, have not been described nor studied in Aloe vera, whose leaf gel is known to possess beneficial pharmaceutical, nutritional and cosmetic properties. As Aloe vera is frequently cultivated in semi-arid conditions, like those found in northern Chile, we investigated the effect of water deficit on fructan composition and structure. For this, plants were subjected to different irrigation regimes of 100%, 75%, 50% and 25% field capacity (FC). There was a significant increase in the total sugars, soluble sugars and oligo and polyfructans in plants subjected to water deficit, compared to the control condition (100% FC) in both leaf tips and bases. The amounts of fructans were also greater in the bases compared to the leaf tips in all water treatments. Fructans also increase in degree of polymerization with increasing water deficit. Glycosidic linkage analyses by GC-MS, led to the conclusion that there are structural differences between the fructans present in the leaves of control plants with respect to plants irrigated with 50% and 25% FC. Therefore, in non-stressed plants, the inulin, neo-inulin and neo-levan type of fructans predominate, while in the most stressful conditions for the plant, Aloe vera also synthesizes fructans with a more branched structure, the neofructans. To our knowledge, the synthesis and the protective role of neo-fructans under extreme water deficit has not been previously reported.

  13. Vacuum circuit breaker modelling for the assessment of transient recovery voltages: application to various network configurations

    DEFF Research Database (Denmark)

    Bak, Claus Leth; Borghetti, Alberto; Glasdam, Jakob Bærholm

    2018-01-01

    capabilities of simulating TRVs due to opening/closing manoeuvres, namely the switching of large electrical motors and the switching of cables collecting offshore wind farms (OWFs). Data from digital fault recorder (DFR) in a water-pumping plant and from a measurement campaign in an OWF using a high...

  14. Structural and energetic properties of La3+ in water/DMSO mixtures

    Science.gov (United States)

    Montagna, Maria; Spezia, Riccardo; Bodo, Enrico

    2017-11-01

    By using molecular dynamics based on a custom polarizable force field, we have studied the solvation of La3+ in an equimolar mixture of dimethylsulfoxide (DMSO) with water. An extended structural analysis has been performed to provide a complete picture of the physical properties at the basis of the interaction of La3+ with both solvents. Through our simulations we found that, very likely, the first solvation shell in the mixture is not unlike the one found in pure water or pure DMSO and contains 9 solvent molecules. We have also found that the solvation is preferentially due to DMSO molecules with the water initially present in first shell quickly leaving to the bulk. The dehydration process of the first shell has been analyzed by both plain MD simulations and a constrained dynamics approach; the free energy profiles for the extraction of water from first shell have also been computed.

  15. SFG study on potential-dependent structure of water at Pt electrode/electrolyte solution interface

    Energy Technology Data Exchange (ETDEWEB)

    Noguchi, Hidenori; Okada, Tsubasa; Uosaki, Kohei [Physical Chemistry Laboratory, Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810 (Japan)

    2008-10-01

    Structure of water at Pt/electrolyte solution interface was investigated by sum frequency generation (SFG) spectroscopy. Two broad peaks were observed in OH stretching region at ca. 3200 cm{sup -1} and ca. 3400 cm{sup -1}, which are known to be due to the symmetric OH stretching (U{sub 1}) of tetrahedrally coordinated, i.e., strongly hydrogen bonded 'ice-like' water, and the asymmetric OH stretching (U{sub 3}) of water molecules in a more random arrangement, i.e., weakly hydrogen bonded 'liquid-like' water, respectively. The SFG intensity strongly depended on electrode potential. Several possibilities are suggested for the potential dependence of the SFG intensity. (author)

  16. Structural Arrangement of Water Molecules around Highly Charged Nanoparticles: Molecular Dynamics Simulation

    International Nuclear Information System (INIS)

    Kim, Eunae; Yeom, Min Sun

    2014-01-01

    Molecular dynamics simulations were performed to understand the structural arrangement of water molecules around highly charged nanoparticles under aqueous conditions. The effect of two highly charged nanoparticles on the solvation charge asymmetry has been examined. We calculated the radial distribution functions of the components of water molecules around nanoparticles which have four charge types at two different salt concentrations. Even though the distributions of water molecules surrounding a sodium ion and a chloride ion are hardly affected by the charges of nanoparticles and the salt concentrations, those around highly charged nanoparticles are strongly influenced by the charges of nanoparticles, but hardly by the charges of nanoparticles and salt concentrations. We find that the distributions of hydrogen atoms in water molecules around one highly charged nanoparticle are dependent on the magnitude of the nanoparticle charge

  17. Structure and crystallinity of water dispersible photoactive nanoparticles for organic solar cells

    DEFF Research Database (Denmark)

    Pedersen, Emil Bøje Lind; Pedersen, M.C.; Simonsen, Søren Bredmose

    2015-01-01

    Water based inks would be a strong advantage for large scale production of organic photovoltaic devices. Formation of water dispersible nanoparticles produced by the Landfester method is a promising route to achieve such inks. We provide new insights into the key ink properties of poly(3-hexylthi......Water based inks would be a strong advantage for large scale production of organic photovoltaic devices. Formation of water dispersible nanoparticles produced by the Landfester method is a promising route to achieve such inks. We provide new insights into the key ink properties of poly(3......-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) nanoparticles such as the internal structure and crystallinity of the dispersed nanoparticles and the previously unreported drastic changes that occur when the inks are cast into a film. We observe through transmission electron...

  18. Multi-frequency complex network from time series for uncovering oil-water flow structure.

    Science.gov (United States)

    Gao, Zhong-Ke; Yang, Yu-Xuan; Fang, Peng-Cheng; Jin, Ning-De; Xia, Cheng-Yi; Hu, Li-Dan

    2015-02-04

    Uncovering complex oil-water flow structure represents a challenge in diverse scientific disciplines. This challenge stimulates us to develop a new distributed conductance sensor for measuring local flow signals at different positions and then propose a novel approach based on multi-frequency complex network to uncover the flow structures from experimental multivariate measurements. In particular, based on the Fast Fourier transform, we demonstrate how to derive multi-frequency complex network from multivariate time series. We construct complex networks at different frequencies and then detect community structures. Our results indicate that the community structures faithfully represent the structural features of oil-water flow patterns. Furthermore, we investigate the network statistic at different frequencies for each derived network and find that the frequency clustering coefficient enables to uncover the evolution of flow patterns and yield deep insights into the formation of flow structures. Current results present a first step towards a network visualization of complex flow patterns from a community structure perspective.

  19. The structure of liquid water by polarized neutron diffraction and reverse Monte Carlo modelling.

    Science.gov (United States)

    Temleitner, László; Pusztai, László; Schweika, Werner

    2007-08-22

    The coherent static structure factor of water has been investigated by polarized neutron diffraction. Polarization analysis allows us to separate the huge incoherent scattering background from hydrogen and to obtain high quality data of the coherent scattering from four different mixtures of liquid H(2)O and D(2)O. The information obtained by the variation of the scattering contrast confines the configurational space of water and is used by the reverse Monte Carlo technique to model the total structure factors. Structural characteristics have been calculated directly from the resulting sets of particle coordinates. Consistency with existing partial pair correlation functions, derived without the application of polarized neutrons, was checked by incorporating them into our reverse Monte Carlo calculations. We also performed Monte Carlo simulations of a hard sphere system, which provides an accurate estimate of the information content of the measured data. It is shown that the present combination of polarized neutron scattering and reverse Monte Carlo structural modelling is a promising approach towards a detailed understanding of the microscopic structure of water.

  20. Influence of cholesterol and ceramide VI on the structure of multilamellar lipid membranes at water exchange

    International Nuclear Information System (INIS)

    Ryabova, N. Yu.; Kiselev, M. A.; Balagurov, A. M.

    2010-01-01

    The structural changes in the multilamellar lipid membranes of dipalmitoylphosphatidylcholine (DPPC)/cholesterol and DPPC/ceramide VI binary systems during hydration and dehydration have been studied by neutron diffraction. The effect of cholesterol and ceramide on the kinetics of water exchange in DPPC membranes is characterized. Compared to pure DPPC, membranes of binary systems swell faster during hydration (with a characteristic time of ∼30 min). Both compounds, ceramide VI and cholesterol, similarly affect the hydration of DPPC membranes, increasing the repeat distance due to the bilayer growth. However, in contrast to cholesterol, ceramide significantly reduces the thickness of the membrane water layer. The introduction of cholesterol into a DPPC membrane slows down the change in the parameters of the bilayer internal structure during dehydration. In the DPPC/ceramide VI/cholesterol ternary system (with a molar cholesterol concentration of 40%), cholesterol is partially released from the lamellar membrane structure into the crystalline phase.

  1. Multistep Cylindrical Structure Analysis at Normal Incidence Based on Water-Substrate Broadband Metamaterial Absorbers

    Science.gov (United States)

    Fang, Chonghua

    2018-01-01

    A new multistep cylindrical structure based on water-substrate broadband metamaterial absorbers is designed to reduce the traditional radar cross-section (RCS) of a rod-shaped object. The proposed configuration consists of two distinct parts. One of these components is formed by a four-step cylindrical metal structure, whereas the other one is formed by a new water-substrate broadband metamaterial absorber. The designed structure can significantly reduce the radar cross section more than 10 dB from 4.58 to 18.42 GHz which is the 86.5 % bandwidth of from C-band to 20 GHz. The results of measurement show reasonably good accordance with the simulated ones, which verifies the ability and effect of the proposed design.

  2. Slowing the Starch Digestion by Structural Modification through Preparing Zein/Pectin Particle Stabilized Water-in-Water Emulsion.

    Science.gov (United States)

    Chen, Jia-Feng; Guo, Jian; Zhang, Tao; Wan, Zhi-Li; Yang, Juan; Yang, Xiao-Quan

    2018-04-25

    Slowing the digestion of starch is one of the dominant concerns in the food industry. A colloidal structural modification strategy for solving this problem was proposed in this work. Due to thermodynamic incompatibility between two biopolymers, water/water emulsion of waxy corn starch (WCS) droplets dispersed in a continuous aqueous guar gum (GG) was prepared, and zein particles (ZPs), obtained by antisolvent precipitation and pectin modification, were used as stabilizer. As the ratio of zein to pectin in the particles was 1:1, their wetting properties in the two polysaccharides were similar, which made them accumulate at the interface and cover the WCS-rich droplets. The analysis of digestibility curves indicated that a rapid (rate constant k 1 : 0.145 min -1 ) and a slow phase ( k 2 : 0.022 min -1 ) existed during WCS digestion. However, only one slow phase ( k 2 : 0.019 min -1 ) was found in the WCS/GG emulsion, suggesting that this structure was effective in slowing starch digestion.

  3. Regulation of Silk Material Structure by Temperature-Controlled Water Vapor Annealing

    Science.gov (United States)

    Hu, Xiao; Shmelev, Karen; Sun, Lin; Gil, Eun-Seok; Park, Sang-Hyug; Cebe, Peggy; Kaplan, David L.

    2011-01-01

    We present a simple and effective method to obtain refined control of the molecular structure of silk biomaterials through physical temperature-controlled water vapor annealing (TCWVA). The silk materials can be prepared with control of crystallinity, from a low content using conditions at 4°C (alpha-helix dominated silk I structure), to highest content of ~60% crystallinity at 100°C (beta-sheet dominated silk II structure). This new physical approach covers the range of structures previously reported to govern crystallization during the fabrication of silk materials, yet offers a simpler, green chemistry, approach with tight control of reproducibility. The transition kinetics, thermal, mechanical, and biodegradation properties of the silk films prepared at different temperatures were investigated and compared by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), uniaxial tensile studies, and enzymatic degradation studies. The results revealed that this new physical processing method accurately controls structure, in turn providing control of mechanical properties, thermal stability, enzyme degradation rate, and human mesenchymal stem cell interactions. The mechanistic basis for the control is through the temperature controlled regulation of water vapor, to control crystallization. Control of silk structure via TCWVA represents a significant improvement in the fabrication of silk-based biomaterials, where control of structure-property relationships is key to regulating material properties. This new approach to control crystallization also provides an entirely new green approach, avoiding common methods which use organic solvents (methanol, ethanol) or organic acids. The method described here for silk proteins would also be universal for many other structural proteins (and likely other biopolymers), where water controls chain interactions related to material properties. PMID:21425769

  4. The structure of the pelagic food web in relation to water column structure in the Skagerrak

    DEFF Research Database (Denmark)

    Kiørboe, Thomas; Kaas, H.; Kruse, B.

    1990-01-01

    by a doming of the pycnocline, with a deep mixed layer along the periphery and a very shallow pycnocline in central parts. Average phytoplankton size increased with the depth of the upper mixed layer, and the central stratified area was characterized by small flagellates while large and chain-forming diatoms...... on particle surface area rather than particle volume or chl a, and showed a distributional pattern that was nearly the inverse of the distribution of copepod activity. That is, peak bacterial growth rates occurred in central, stratified parts and lower rates were found along the margin with a deep mixed layer....... Thus a 'microbial loop' type of food web seemed to be evolving in the central, strongly stratified parts of the Skagerrak, while a shorter 'classical' type of food web appeared to dominate along the margin. The relation between food web structure and vertical mixing processes observed on oceanwide...

  5. Design Concept of Dialyzer Biomaterials: How to Find Biocompatible Polymers Based on the Biointerfacial Water Structure.

    Science.gov (United States)

    Tanaka, Masaru

    2017-01-01

    Although various types of materials have been used widely in dialyzers, most biomaterials lack the desired functional properties to interface with blood and have not been engineered for optimum performance. Therefore, there is increasing demand to develop novel materials to address such problems in the dialysis arena. Numerous parameters of polymeric biomaterials can affect biocompatibility in a controlled manner. The mechanisms responsible for the biocompatibility of polymers at the molecular level have not been clearly demonstrated, although many theoretical and experimental efforts have been made to try and understand them. Moreover, water interactions have been recognized as fundamental for the blood response to contact with polymers. We have proposed the 'intermediate water' concept and hypothesized that intermediate water, which prevents the proteins and blood cells from directly contacting the polymer surface, or nonfreezing water on the polymer surface, plays an important role in the biocompatibility of polymers. This chapter provides an overview of the recent experimental progress of biocompatible polymers measured by thermal, spectroscopic, and surface force techniques. Additionally, it highlights recent developments in the use of biocompatible polymeric biomaterials for dialyzers and provides an overview of the progress made in the design of multifunctional biomedical polymers by controlling the biointerfacial water structure through precision polymer synthesis. Key Messages: Intermediate water was found only in hydrated biopolymers (proteins, polysaccharides, and nucleic acids, DNA and RNA) and hydrated biocompatible synthetic polymers. Intermediate water could be one of the main screening factors for the design of appropriate dialyzer materials. © 2017 S. Karger AG, Basel.

  6. Structure of water in mesoporous organosilica by calorimetry and inelastic neutron scattering

    Science.gov (United States)

    Levy, Esthy; Kolesnikov, Alexander I.; Li, Jichen; Mastai, Yitzhak

    2009-01-01

    In this paper, we describe the preparation of mesoporous organosilica samples with hydrophilic or hydrophobic organic functionality inside the silica channel. We synthesized mesoporous organosilica of identical pore sizes based on two different organic surface functionality namely hydrophobic (based on octyltriethoxysilane OTES) and hydrophilic (3-aminopropyltriethoxysilane ATES) and MCM-41 was used as a reference system. The structure of water/ice in those porous silica samples have been investigated over a range temperatures by differential scanning calorimetry (DSC) and inelastic neutron scattering (INS). INS study revealed that water confined in hydrophobic mesoporous organosilica shows vibrational behavior strongly different than bulk water. It consists of two states: water with strong and weak hydrogen bonds (with ratio 1:2.65, respectively), compared to ice-Ih. The corresponding O-O distances in these water states are 2.67 and 2.87 Ǻ, which strongly differ compared to ice-Ih (2.76 Ǻ). INS spectra for water in hydrophilic mesoporous organosilica ATES show behavior similar to bulk water, but with greater degree of disorder.

  7. Bacterial Community Structure Shifted by Geosmin in Granular Activated Carbon System of Water Treatment Plants.

    Science.gov (United States)

    Pham, Ngoc Dung; Lee, Eun-Hee; Chae, Seon-Ha; Cho, Yongdeok; Shin, Hyejin; Son, Ahjeong

    2016-01-01

    We investigated the relation between the presence of geosmin in water and the bacterial community structure within the granular activated carbon (GAC) system of water treatment plants in South Korea. GAC samples were collected in May and August of 2014 at three water treatment plants (Sungnam, Koyang, and Yeoncho in Korea). Dissolved organic carbon and geosmin were analyzed before and after GAC treatment. Geosmin was found in raw water from Sungnam and Koyang water treatment plants but not in that from Yeoncho water treatment plant. Interestingly, but not surprisingly, the 16S rRNA clone library indicated that the bacterial communities from the Sungnam and Koyang GAC systems were closely related to geosmin-degrading bacteria. Based on the phylogenetic tree and multidimensional scaling plot, bacterial clones from GAC under the influence of geosmin were clustered with Variovorax paradoxus strain DB 9b and Comamonas sp. DB mg. In other words, the presence of geosmin in water might have inevitably contributed to the growth of geosmin degraders within the respective GAC system.

  8. Influence of secondary water supply systems on microbial community structure and opportunistic pathogen gene markers.

    Science.gov (United States)

    Li, Huan; Li, Shang; Tang, Wei; Yang, Yang; Zhao, Jianfu; Xia, Siqing; Zhang, Weixian; Wang, Hong

    2018-06-01

    Secondary water supply systems (SWSSs) refer to the in-building infrastructures (e.g., water storage tanks) used to supply water pressure beyond the main distribution systems. The purpose of this study was to investigate the influence of SWSSs on microbial community structure and the occurrence of opportunistic pathogens, the latter of which are an emerging public health concern. Higher numbers of bacterial 16S rRNA genes, Legionella and mycobacterial gene markers were found in public building taps served by SWSSs relative to the mains, regardless of the flushing practice (P water retention time, warm temperature and loss of disinfectant residuals promoted microbial growth and colonization of potential pathogens in SWSSs. Varied levels of microbial community shifts were found in different types of SWSSs during water transportation from the distribution main to taps, highlighting the critical role of SWSSs in shaping the drinking water microbiota. Overall, the results provided insight to factors that might aid in controlling pathogen proliferation in real-world water systems using SWSSs. Copyright © 2018 Elsevier Ltd. All rights reserved.

  9. Geostatistical investigation into the temporal evolution of spatial structure in a shallow water table

    Directory of Open Access Journals (Sweden)

    S. W. Lyon

    2006-01-01

    Full Text Available Shallow water tables near-streams often lead to saturated, overland flow generating areas in catchments in humid climates. While these saturated areas are assumed to be principal biogeochemical hot-spots and important for issues such as non-point pollution sources, the spatial and temporal behavior of shallow water tables, and associated saturated areas, is not completely understood. This study demonstrates how geostatistical methods can be used to characterize the spatial and temporal variation of the shallow water table for the near-stream region. Event-based and seasonal changes in the spatial structure of the shallow water table, which influences the spatial pattern of surface saturation and related runoff generation, can be identified and used in conjunction to characterize the hydrology of an area. This is accomplished through semivariogram analysis and indicator kriging to produce maps combining soft data (i.e., proxy information to the variable of interest representing general shallow water table patterns with hard data (i.e., actual measurements that represent variation in the spatial structure of the shallow water table per rainfall event. The area used was a hillslope in the Catskill Mountains region of New York State. The shallow water table was monitored for a 120 m×180 m near-stream region at 44 sampling locations on 15-min intervals. Outflow of the area was measured at the same time interval. These data were analyzed at a short time interval (15 min and at a long time interval (months to characterize the changes in the hydrologic behavior of the hillslope. Indicator semivariograms based on binary-transformed ground water table data (i.e., 1 if exceeding the time-variable median depth to water table and 0 if not were created for both short and long time intervals. For the short time interval, the indicator semivariograms showed a high degree of spatial structure in the shallow water table for the spring, with increased range

  10. The structural and dynamic characteristics of a water-polimer high-speed jet

    Directory of Open Access Journals (Sweden)

    Андрій Володимирович Погребняк

    2017-07-01

    Full Text Available The aim is to study the structural and dynamic characteristics of the water-polymer jet, what is of decisive importance for understanding the nature of the abnormally high cutting ability. A complex study of the structure and dynamics of a water-polymer high-speed jet has been carried out. Analysis of the photographs of jets of aqueous PEO solution indicates that adding polyethylene oxide (PEO into water results in a significant increase in the initial sections of the water-polymer jet, which characterizes the quality of its formation, and leads to compactness due to a reduction of its diameter. The obtained experimental data made it possible to propose a relationship for determining the dimensionless value of the initial sections of jets of aqueous PEO solutions of different concentration and molecular mass of PEO, taking into account the real parameters of the jet forming head. Investigation of changes in the energy capabilities of water-polymer jets, which were estimated by the force of the jet impact on the steel obstacle, made it possible to establish the features of their dynamics. The obtained experimental data explain the nature of the change in the cutting properties of the water-polymer jet as a function of the distance between the surface of the material that is being cut and the cut of the nozzle. If the distance from the nozzle to the surface of the material is less than the size of the initial sections of the water-polymer jet, an increase in the diameter of the nozzle outlet hole will lead to a reduction in the depth of the cut. If, however, the distance from the nozzle to the surface of the material approaches or exceeds the size of the main part of the water-polymer jet, then the depth of the cut will increase with increasing diameter of the nozzle at a constant pressure. The use of structural and dynamic characteristics of water-polymer jets is substantiated when establishing rational parameters of equipment for water

  11. Interactions between soil texture, water, and nutrients control patterns of biocrusts abundance and structure

    Science.gov (United States)

    Young, Kristina; Bowker, Matthew; Reed, Sasha; Howell, Armin

    2017-04-01

    Heterogeneity in the abiotic environment structures biotic communities by controlling niche space and parameters. This has been widely observed and demonstrated in vascular plant and other aboveground communities. While soil organisms are presumably also strongly influenced by the physical and chemical dimensions of the edaphic environment, there are fewer studies linking the development, structure, productivity or function of surface soil communities to specific edaphic gradients. Here, we use biological soil crusts (biocrusts) as a model system to determine mechanisms regulating community structure of soil organisms. We chose soil texture to serve as an edaphic gradient because of soil texture's influence over biocrust distribution on a landscape level. We experimentally manipulated texture in constructed soil, and simultaneously manipulated two main outcomes of texture, water and nutrient availability, to determine the mechanism underlying texture's influence on biocrust abundance and structure. We grew biocrust communities from a field-sourced inoculum on four different soil textures, sieved from the same parent soil material, manipulating watering levels and nutrient additions across soil textures in a full-factorial design over a 5-month period of time. We measured abundance and structure of biocrusts over time, and measured two metrics of function, N2 fixation rates and soil stabilization, at the conclusion of the experiment. Our results showed finer soil textures resulted in faster biocrust community development and dominance by mosses, whereas coarser textures grew more slowly and had biocrust communities dominated by cyanobacteria and lichen. Additionally, coarser textured soils contained cyanobacterial filaments significantly deeper into the soil profile than fine textured soils. N2-fixation values increased with increasing moss cover and decreased with increasing cyanobacterial cover, however, the rate of change depended on soil texture and water amount

  12. Roles of water in protein structure and function studied by molecular liquid theory.

    Science.gov (United States)

    Imai, Takashi

    2009-01-01

    The roles of water in the structure and function of proteins have not been completely elucidated. Although molecular simulation has been widely used for the investigation of protein structure and function, it is not always useful for elucidating the roles of water because the effect of water ranges from atomic to thermodynamic level. The three-dimensional reference interaction site model (3D-RISM) theory, which is a statistical-mechanical theory of molecular liquids, can yield the solvation structure at the atomic level and calculate the thermodynamic quantities from the intermolecular potentials. In the last few years, the author and coworkers have succeeded in applying the 3D-RISM theory to protein aqueous solution systems and demonstrated that the theory is useful for investigating the roles of water. This article reviews some of the recent applications and findings, which are concerned with molecular recognition by protein, protein folding, and the partial molar volume of protein which is related to the pressure effect on protein.

  13. Light Modulation and Water Splitting Enhancement Using a Composite Porous GaN Structure.

    Science.gov (United States)

    Yang, Chao; Xi, Xin; Yu, Zhiguo; Cao, Haicheng; Li, Jing; Lin, Shan; Ma, Zhanhong; Zhao, Lixia

    2018-02-14

    On the basis of the laterally porous GaN, we designed and fabricated a composite porous GaN structure with both well-ordered lateral and vertical holes. Compared to the plane GaN, the composite porous GaN structure with the combination of the vertical holes can help to reduce UV reflectance and increase the saturation photocurrent during water splitting by a factor of ∼4.5. Furthermore, we investigated the underlying mechanism for the enhancement of the water splitting performance using a finite-difference time-domain method. The results show that the well-ordered vertical holes can not only help to open the embedded pore channels to the electrolyte at both sides and reduce the migration distance of the gas bubbles during the water splitting reactions but also help to modulate the light field. Using this composite porous GaN structure, most of the incident light can be modulated and trapped into the nanoholes, and thus the electric fields localized in the lateral pores can increase dramatically as a result of the strong optical coupling. Our findings pave a new way to develop GaN photoelectrodes for highly efficient solar water splitting.

  14. Fabrication of superhydrophobic polyurethane/organoclay nano-structured composites from cyclomethicone-in-water emulsions

    International Nuclear Information System (INIS)

    Bayer, I.S.; Steele, A.; Martorana, P.J.; Loth, E.

    2010-01-01

    Nano-structured polyurethane/organoclay composite films were fabricated by dispersing moisture-curable polyurethanes and fatty amine/amino-silane surface modified montmorillonite clay (organoclay) in cyclomethicone-in-water emulsions. Cyclomethicone Pickering emulsions were made by emulsifying decamethylcyclopentasiloxane (D 5 ), dodecamethylcyclohexasiloxane (D 6 ) and aminofunctional siloxane polymers with water using montmorillonite particles as emulsion stabilizers. Polyurethane and organoclay dispersed emulsions were spray coated on aluminum surfaces. Upon thermosetting, water repellent self-cleaning coatings were obtained with measured static water contact angles exceeding 155 o and low contact angle hysteresis ( o ). Electron microscopy images of the coating surfaces revealed formation of self-similar hierarchical micro- and nano-scale surface structures. The surface morphology and the coating adhesion strength to aluminum substrates were found to be sensitive to the relative amounts of dispersed polyurethane and organoclay in the emulsions. The degree of superhydrophobicity was analyzed using static water contact angles as well as contact angle hysteresis measurements. Due to biocompatibility of cyclomethicones and polyurethane, developed coatings can be considered for specific bio-medical applications.

  15. Fabrication of superhydrophobic polyurethane/organoclay nano-structured composites from cyclomethicone-in-water emulsions

    Energy Technology Data Exchange (ETDEWEB)

    Bayer, I.S., E-mail: ibayer1@illinois.edu [Department of Aerospace Engineering, University of Illinois at Urbana-Champaign, IL 61801 (United States); Steele, A.; Martorana, P.J. [Department of Aerospace Engineering, University of Illinois at Urbana-Champaign, IL 61801 (United States); Loth, E. [Department of Aerospace Engineering, University of Illinois at Urbana-Champaign, IL 61801 (United States); Department of Mechanical and Aerospace Engineering, University of Virginia, VA 22904 (United States)

    2010-11-15

    Nano-structured polyurethane/organoclay composite films were fabricated by dispersing moisture-curable polyurethanes and fatty amine/amino-silane surface modified montmorillonite clay (organoclay) in cyclomethicone-in-water emulsions. Cyclomethicone Pickering emulsions were made by emulsifying decamethylcyclopentasiloxane (D{sub 5}), dodecamethylcyclohexasiloxane (D{sub 6}) and aminofunctional siloxane polymers with water using montmorillonite particles as emulsion stabilizers. Polyurethane and organoclay dispersed emulsions were spray coated on aluminum surfaces. Upon thermosetting, water repellent self-cleaning coatings were obtained with measured static water contact angles exceeding 155{sup o} and low contact angle hysteresis (<8{sup o}). Electron microscopy images of the coating surfaces revealed formation of self-similar hierarchical micro- and nano-scale surface structures. The surface morphology and the coating adhesion strength to aluminum substrates were found to be sensitive to the relative amounts of dispersed polyurethane and organoclay in the emulsions. The degree of superhydrophobicity was analyzed using static water contact angles as well as contact angle hysteresis measurements. Due to biocompatibility of cyclomethicones and polyurethane, developed coatings can be considered for specific bio-medical applications.

  16. Corrosion of structural materials and electrochemistry in high temperature water of nuclear power systems

    International Nuclear Information System (INIS)

    Uchida, Shunsuke

    2008-01-01

    The latest experiences with corrosion in the cooling systems of nuclear power plants are reviewed. High temperature cooling water causes corrosion of structural materials, which often leads to adverse effects in the plants, e.g., increased shutdown radiation, generation of defects in materials of major components and fuel claddings, and increased volume of radwaste sources. Corrosion behavior is greatly affected by water quality and differs according to the water quality values and the materials themselves. In order to establish reliable operation, each plant requires its own unique optimal water chemistry control based on careful consideration of its system, materials and operational history. Electrochemistry is one of the key issues that determine corrosion-related problems, but it is not the only issue. Most corrosion-related phenomena, e.g., flow accelerated corrosion (FAC), intergranular stress corrosion cracking (IGSCC), primary water stress corrosion cracking (PWSCC) and thinning of fuel cladding materials, can be understood based on an electrochemical index, e.g., the electrochemical corrosion potential (ECP), conductivities and pH. The most important electrochemical index, the ECP, can be measured at elevated temperature and applied to in situ sensors of corrosion conditions to detect anomalous conditions of structural materials at their very early stages. (orig.)

  17. Corrosion of structural materials and electrochemistry in high temperature water of nuclear power systems

    International Nuclear Information System (INIS)

    Uchida, Shunsuke

    2014-01-01

    The latest experiences with corrosion in the cooling systems of nuclear power plants are reviewed. High temperature cooling water causes corrosion of structural materials, which often leads to adverse effects in the plants, e.g., generating defects in materials of major components and fuel claddings, increasing shutdown radiation and increasing the volume of radwaste sources. Corrosion behaviors are much affected by water qualities and differ according to the values of water qualities and the materials themselves. In order to establish reliable operation, each plant requires its own unique optimal water chemistry control based on careful consideration of its system, materials and operational history. Electrochemistry is one of key issues that determine corrosion related problems but it is not the only issue. Most phenomena for corrosion related problems, e.g., flow-accelerated corrosion (FAC), intergranular stress corrosion cracking (IGSCC), primary water stress corrosion cracking (PWSCC) and thinning of fuel cladding materials, can be understood based on an electrochemical index, e.g., electrochemical corrosion potential (ECP), conductivities and pH. The most important electrochemical index, ECP, can be measured at elevated temperature and applied to in situ sensors of corrosion conditions to detect anomalous conditions of structural materials at their very early stages. In the paper, theoretical models based on electrochemistry to estimate wall thinning rate of carbon steel piping due to flow-accelerated corrosion and corrosive conditions determining IGSCC crack initiation and growth rate are introduced. (author)

  18. THE UTILIZATION STRUCTURE OF THERMAL WATER WELLS AND ITS UNEXPLOITED CAPACITIES IN HUNGARY

    Directory of Open Access Journals (Sweden)

    BALÁZS KULCSÁR

    2014-12-01

    Full Text Available In order to mitigate Hungary’s vulnerability in energy supply and accomplish the renewable energy production targets, it is essential to discover exploitable alternative opportunities for energy production and step up the utilization of the available capacities. The purpose of this publication is to map up the utilization structure of the existing Hungarian thermal water wells, describe its changes over the past 16 years, reveal the associated reasons and define the unutilized well capacities that may contribute to increasing the exploitation of geothermal heat by municipalities. The studies have been conducted in view of the Cadaster of Thermal Water Wells of Hungary compiled in 1994, the well cadasters kept by the regional water management directorates, as well as the data of the digital thermal water cadaster of 2010. The calculations performed for the evaluation of data have been based on the ratios and respective utilization areas of the existing wells. In the past 150 years, nearly 1500 thermal water wells have been drilled for use by a broad range of economic operations. The principal goals of constructing thermal water wells encompass the use of water in balneology, water and heat supply to the agriculture, hydrocarbon research and the satisfaction of municipal water demands. In 1994, 26% of the facilities was operated as baths, 21% was used by agriculture, while 13% and 12% served communal and waterworks supply, respectively. Then in 2010, 31% of thermal water wells was continued to be used for the water supply of bathing establishments, followed by 20% for agricultural use, 19% for utilization by waterworks, 11% for observation purposes and 10% for communal use. During the 16 years between 1994 and 2010, the priorities of utilization often changed, new demands emerged in addition to the former utilization goals of thermal water wells. The economic landscape and changes in consumer habits have transformed the group of consumers, which

  19. Probing ion-specific effects on aqueous acetate solutions: Ion pairing versus water structure modifications.

    Science.gov (United States)

    Petit, Tristan; Lange, Kathrin M; Conrad, Gerrit; Yamamoto, Kenji; Schwanke, Christoph; Hodeck, Kai F; Dantz, Marcus; Brandenburg, Tim; Suljoti, Edlira; Aziz, Emad F

    2014-05-01

    The effect of monovalent cations (Li(+), K(+), NH4 (+), Na(+)) on the water structure in aqueous chloride and acetate solutions was characterized by oxygen K-edge X-ray absorption spectroscopy (XAS), X-ray emission spectroscopy, and resonant inelastic X-ray scattering (RIXS) of a liquid microjet. We show ion- and counterion dependent effects on the emission spectra of the oxygen K-edge, which we attribute to modifications of the hydrogen bond network of water. For acetates, ion pairing with carboxylates was also probed selectively by XAS and RIXS. We correlate our experimental results to speciation data and to the salting-out properties of the cations.

  20. Structures, Energetics and Spectroscopic Fingerprints of Water Clusters n=2-24

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Soohaeng; Xantheas, Sotiris S.

    2017-06-08

    This chapter discusses the structures, energetics, and vibrational spectra of the first few (n$24) water clusters obtained from high-level electronic structure calculations. The results are discussed in the perspective of being used to parameterize/assess the accuracy of classical and quantum force fields for water. To this end, a general introduction with the classification of those force fields is presented. Several low-lying families of minima for the medium cluster sizes are considered. The transition from the “all surface” to the “fully coordinated” cluster structures occurring at nD17 and its spectroscopic signature is presented. The various families of minima for nD20 are discussed together with the low energy networks of the pentagonal dodecahedron (H2O)20 water cage. Finally, the low-energy networks of the tetrakaidecahedron (T-cage) (H2O)24 cluster are shown and their significance in the construction of periodic lattices of structure I (sI) of the hydrate lattices is discussed.

  1. Water footprint of crop production for different crop structures in the Hebei southern plain, North China

    Science.gov (United States)

    Chu, Yingmin; Shen, Yanjun; Yuan, Zaijian

    2017-06-01

    The North China Plain (NCP) has a serious shortage of freshwater resources, and crop production consumes approximately 75 % of the region's water. To estimate water consumption of different crops and crop structures in the NCP, the Hebei southern plain (HSP) was selected as a study area, as it is a typical region of groundwater overdraft in the NCP. In this study, the water footprint (WF) of crop production, comprised of green, blue and grey water footprints, and its annual variation were analyzed. The results demonstrated the following: (1) the WF from the production of main crops was 41.8 km3 in 2012. Winter wheat, summer maize and vegetables were the top water-consuming crops in the HSP. The water footprint intensity (WFI) of cotton was the largest, and for vegetables, it was the smallest; (2) the total WF, WFblue, WFgreen and WFgrey for 13 years (2000-2012) of crop production were 604.8, 288.5, 141.3 and 175.0 km3, respectively, with an annual downtrend from 2000 to 2012; (3) winter wheat, summer maize and vegetables consumed the most groundwater, and their blue water footprint (WFblue) accounted for 74.2 % of the total WFblue in the HSP; (4) the crop structure scenarios analysis indicated that, with approximately 20 % of arable land cultivated with winter wheat-summer maize in rotation, 38.99 % spring maize, 10 % vegetables and 10 % fruiters, a sustainable utilization of groundwater resources can be promoted, and a sufficient supply of food, including vegetables and fruits, can be ensured in the HSP.

  2. Water footprint of crop production for different crop structures in the Hebei southern plain, North China

    Directory of Open Access Journals (Sweden)

    Y. Chu

    2017-06-01

    Full Text Available The North China Plain (NCP has a serious shortage of freshwater resources, and crop production consumes approximately 75 % of the region's water. To estimate water consumption of different crops and crop structures in the NCP, the Hebei southern plain (HSP was selected as a study area, as it is a typical region of groundwater overdraft in the NCP. In this study, the water footprint (WF of crop production, comprised of green, blue and grey water footprints, and its annual variation were analyzed. The results demonstrated the following: (1 the WF from the production of main crops was 41.8 km3 in 2012. Winter wheat, summer maize and vegetables were the top water-consuming crops in the HSP. The water footprint intensity (WFI of cotton was the largest, and for vegetables, it was the smallest; (2 the total WF, WFblue, WFgreen and WFgrey for 13 years (2000–2012 of crop production were 604.8, 288.5, 141.3 and 175.0 km3, respectively, with an annual downtrend from 2000 to 2012; (3 winter wheat, summer maize and vegetables consumed the most groundwater, and their blue water footprint (WFblue accounted for 74.2 % of the total WFblue in the HSP; (4 the crop structure scenarios analysis indicated that, with approximately 20 % of arable land cultivated with winter wheat–summer maize in rotation, 38.99 % spring maize, 10 % vegetables and 10 % fruiters, a sustainable utilization of groundwater resources can be promoted, and a sufficient supply of food, including vegetables and fruits, can be ensured in the HSP.

  3. Estimation of expected short-circuit current levels in and circuit-breaker requirements for the 330 to 750 kV networks of the southern integrated power grid

    Energy Technology Data Exchange (ETDEWEB)

    Krivushkin, L.F.; Gorazeeva, T.F.

    1978-08-01

    Studies were made in order to project the operating levels in the Southern Integrated Power Grid to the year 2000. The short-circuit current levels and, the requirements which circuit breakers will have to meet are estimated. A gradual transition from 330 to 750 kV generation is foreseen, with 330 kV networks remaining only for a purely distribution service. The number of 330 kV line hookups and the number of circuit breakers at nodal points (stations and substations) will not change significantly, they will account for 40% of all circuit breakers installed in 25% of all nodal points. Short-circuit currents are expected to reach the 46 kA level in 750 kV networks and 63 kA (standing wave voltage 1.5 to 2.5 kV/microsecond) in 330 kV networks. These are the ratings of circuit breakers; of the 63 kA ones 150 will be needed by 1980--1990 and 400 by 1990--2000. It will also be eventually worthwhile to install circuit breakers with a 63 kA-750 kV rating.

  4. Structure and dynamics of the peptide strand KRFK from the thrombospondin TSP-1 in water.

    Science.gov (United States)

    Taleb Bendiab, W; Benomrane, B; Bounaceur, B; Dauchez, M; Krallafa, A M

    2018-02-14

    Theoretical investigations of a solute in liquid water at normal temperature and pressure can be performed at different levels of theory. Static quantum calculations as well as classical and ab initio molecular dynamics are used to completely explore the conformational space for large solvated molecular systems. In the classical approach, it is essential to describe all of the interactions of the solute and the solvent in detail. Water molecules are very often described as rigid bodies when the most commonly used interaction potentials, such as the SPCE and the TIP4P models, are employed. Recently, a physical model based upon a cluster of rigid water molecules with a tetrahedral architecture (AB 4 ) was proposed that describes liquid water as a mixture of both TIP4P and SPCE molecular species that occur in the proportions implied by the tetrahedral architecture (one central molecule versus four outer molecules; i.e., 20% TIP4P versus 80% SPCE molecules). In this work, theoretical spectroscopic data for a peptide strand were correlated with the structural properties of the peptide strand solvated in water, based on data calculated using different theoretical approaches and physical models. We focused on a particular peptide strand, KRFK (lysine-arginine-phenylalanine-lysine), found in the thrombospondin TSP-1, due to its interesting properties. As the activity and electronic structure of this system is strongly linked to its structure, we correlated its structure with charge-density maps obtained using different semi-empirical charge Q eq equations. The structural and thermodynamic properties obtained from classical simulations were correlated with ab initio molecular dynamics (AIMD) data. Structural changes in the peptide strand were rationalized in terms of the motions of atoms and groups of atoms. To achieve this, conformational changes were investigated using calculated infrared spectra for the peptide in the gas phase and in water solvent. The calculated AIMD

  5. Apparent molal volumes of HMT and TATD in aqueous solutions around the temperature of maximum density of water

    International Nuclear Information System (INIS)

    Clavijo Penagos, J.A.; Blanco, L.H.

    2012-01-01

    Highlights: ►V φ for HMT and TATD in aqueous solutions around the temperature of maximum density of water are reported. ► V φ is linear in m form m = 0.025 for all the aqueous solutions investigated. ► Variation of V ¯ 2 ∞ with T obeys a second grade polynomial trend. ► The solutes are classified as structure breakers according to Hepler’s criterion. - Abstract: Apparent molal volumes V φ have been determined from density measurements for several aqueous solutions of 1,3,5,7-tetraazatricyclo[3.3.1.1(3,7)]decane (HMT) and 1,3,6,8-tetraazatricyclo[4.4.1.1(3,8)]dodecane (TATD) at T = (275.15, 275.65, 276.15, 276.65, 277.15, 277.65 and 278.15) K as function of composition. The infinite dilution partial molar volumes of solutes in aqueous solution are evaluated through extrapolation. Interactions of the solutes with water are discussed in terms of the effect of the temperature on the volumetric properties and the structure of the solutes. The results are interpreted in terms of water structure-breaking or structure forming character of the solutes.

  6. The structural modification of cassava starch using a saline water pretreatment

    Directory of Open Access Journals (Sweden)

    Hanny Frans SANGIAN

    2018-04-01

    Full Text Available Abstract The cassava has been modified successfully by using the saline water, which was abundantly available on the planet. The biomass was submerged in saline waters that salt concentrations were altered at 0, 3.5 percent (seawater and 10 percent (w/w and were kept 5 days. After recovery by washing steps, the treated solids were characterized by using XRD (X-ray diffraction , FTIR (Fourier transform infra-red, and SEM (Scanning electron microscopic. The results showed that the XRD pattern of saline water pretreatment decreased significantly. The biggest decrease of X-ray intensity occurred at around 18o. Meanwhile, the fingerprint of FTIR revealed the transmittance intensity of infra-red ray of saline water treated solid inclined for all wave constant numbers, suggesting that many hydrogen bonds were disconnected. Those findings also were enhanced by SEM pictures that showed the change of surface morphology of treated biomass. It was indicative that cassava structure was modified becoming more textured after employing saline water pretreatment. This work is an innovative finding to gradually substitute commercial ionic liquids that are very expensive with saline water for biomass pretreatment.

  7. Water and the Interior Structure of Terrestrial Planets and Icy Bodies

    Science.gov (United States)

    Monteux, J.; Golabek, G. J.; Rubie, D. C.; Tobie, G.; Young, E. D.

    2018-02-01

    Water content and the internal evolution of terrestrial planets and icy bodies are closely linked. The distribution of water in planetary systems is controlled by the temperature structure in the protoplanetary disk and dynamics and migration of planetesimals and planetary embryos. This results in the formation of planetesimals and planetary embryos with a great variety of compositions, water contents and degrees of oxidation. The internal evolution and especially the formation time of planetesimals relative to the timescale of radiogenic heating by short-lived 26Al decay may govern the amount of hydrous silicates and leftover rock-ice mixtures available in the late stages of their evolution. In turn, water content may affect the early internal evolution of the planetesimals and in particular metal-silicate separation processes. Moreover, water content may contribute to an increase of oxygen fugacity and thus affect the concentrations of siderophile elements within the silicate reservoirs of Solar System objects. Finally, the water content strongly influences the differentiation rate of the icy moons, controls their internal evolution and governs the alteration processes occurring in their deep interiors.

  8. Atomistic structure of cobalt-phosphate nanoparticles for catalytic water oxidation.

    Science.gov (United States)

    Hu, Xiao Liang; Piccinin, Simone; Laio, Alessandro; Fabris, Stefano

    2012-12-21

    Solar-driven water splitting is a key photochemical reaction that underpins the feasible and sustainable production of solar fuels. An amorphous cobalt-phosphate catalyst (Co-Pi) based on earth-abundant elements has been recently reported to efficiently promote water oxidation to protons and dioxygen, a main bottleneck for the overall process. The structure of this material remains largely unknown. We here exploit ab initio and classical atomistic simulations combined with metadynamics to build a realistic and statistically meaningful model of Co-Pi nanoparticles. We demonstrate the emergence and stability of molecular-size ordered crystallites in nanoparticles initially formed by a disordered Co-O network and phosphate groups. The stable crystallites consist of bis-oxo-bridged Co centers that assemble into layered structures (edge-sharing CoO(6) octahedra) as well as in corner- and face-sharing cubane units. These layered and cubane motifs coexist in the crystallites, which always incorporate disordered phosphate groups at the edges. Our computational nanoparticles, although limited in size to ~1 nm, can contain more than one crystallite and incorporate up to 18 Co centers in the cubane/layered structures. The crystallites are structurally stable up to high temperatures. We simulate the extended X-ray absorption fine structure (EXAFS) of our nanoparticles. Those containing several complete and incomplete cubane motifs-which are believed to be essential for the catalytic activity-display a very good agreement with the experimental EXAFS spectra of Co-Pi grains. We propose that the crystallites in our nanoparticles are reliable structural models of the Co-Pi catalyst surface. They will be useful to reveal the origin of the catalytic efficiency of these novel water-oxidation catalysts.

  9. Variance in water chemistry parameters in isolated wetlands of Florida, USA, and relationships with macroinvertebrate and diatom community structure

    Science.gov (United States)

    Eighty small isolated wetlands throughout Florida were sampled in 2005 to explore within-site variability of water chemistry parameters and relate water chemistry to macroinvertebrate and diatom community structure. Three samples or measures of water were collected within each si...

  10. Moisture harvesting and water transport through specialized micro-structures on the integument of lizards.

    Science.gov (United States)

    Comanns, Philipp; Effertz, Christian; Hischen, Florian; Staudt, Konrad; Böhme, Wolfgang; Baumgartner, Werner

    2011-01-01

    Several lizard species that live in arid areas have developed special abilities to collect water with their bodies' surfaces and to ingest the so collected moisture. This is called rain- or moisture-harvesting. The water can originate from air humidity, fog, dew, rain or even from humid soil. The integument (i.e., the skin plus skin derivatives such as scales) has developed features so that the water spreads and is soaked into a capillary system in between the reptiles' scales. Within this capillary system the water is transported to the mouth where it is ingested. We have investigated three different lizard species which have developed the ability for moisture harvesting independently, viz. the Australian thorny devil (Moloch horridus), the Arabian toadhead agama (Phrynocephalus arabicus) and the Texas horned lizard (Phrynosoma cornutum). All three lizards have a honeycomb like micro ornamentation on the outer surface of the scales and a complex capillary system in between the scales. By investigation of individual scales and by producing and characterising polymer replicas of the reptiles' integuments, we found that the honeycomb like structures render the surface superhydrophilic, most likely by holding a water film physically stable. Furthermore, the condensation of air humidity is improved on this surface by about 100% in comparison to unstructured surfaces. This allows the animals to collect moisture with their entire body surface. The collected water is transported into the capillary system. For Phrynosoma cornutum we found the interesting effect that, in contrast to the other two investigated species, the water flow in the capillary system is not uniform but directed to the mouth. Taken together we found that the micro ornamentation yields a superhydrophilic surface, and the semi-tubular capillaries allow for an efficient passive - and for Phrynosoma directed - transport of water.

  11. Moisture harvesting and water transport through specialized micro-structures on the integument of lizards

    Directory of Open Access Journals (Sweden)

    Philipp Comanns

    2011-04-01

    Full Text Available Several lizard species that live in arid areas have developed special abilities to collect water with their bodies' surfaces and to ingest the so collected moisture. This is called rain- or moisture-harvesting. The water can originate from air humidity, fog, dew, rain or even from humid soil. The integument (i.e., the skin plus skin derivatives such as scales has developed features so that the water spreads and is soaked into a capillary system in between the reptiles' scales. Within this capillary system the water is transported to the mouth where it is ingested. We have investigated three different lizard species which have developed the ability for moisture harvesting independently, viz. the Australian thorny devil (Moloch horridus, the Arabian toadhead agama (Phrynocephalus arabicus and the Texas horned lizard (Phrynosoma cornutum. All three lizards have a honeycomb like micro ornamentation on the outer surface of the scales and a complex capillary system in between the scales. By investigation of individual scales and by producing and characterising polymer replicas of the reptiles' integuments, we found that the honeycomb like structures render the surface superhydrophilic, most likely by holding a water film physically stable. Furthermore, the condensation of air humidity is improved on this surface by about 100% in comparison to unstructured surfaces. This allows the animals to collect moisture with their entire body surface. The collected water is transported into the capillary system. For Phrynosoma cornutum we found the interesting effect that, in contrast to the other two investigated species, the water flow in the capillary system is not uniform but directed to the mouth. Taken together we found that the micro ornamentation yields a superhydrophilic surface, and the semi-tubular capillaries allow for an efficient passive – and for Phrynosoma directed – transport of water.

  12. Moisture harvesting and water transport through specialized micro-structures on the integument of lizards

    Science.gov (United States)

    Comanns, Philipp; Effertz, Christian; Hischen, Florian; Staudt, Konrad; Böhme, Wolfgang

    2011-01-01

    Summary Several lizard species that live in arid areas have developed special abilities to collect water with their bodies' surfaces and to ingest the so collected moisture. This is called rain- or moisture-harvesting. The water can originate from air humidity, fog, dew, rain or even from humid soil. The integument (i.e., the skin plus skin derivatives such as scales) has developed features so that the water spreads and is soaked into a capillary system in between the reptiles' scales. Within this capillary system the water is transported to the mouth where it is ingested. We have investigated three different lizard species which have developed the ability for moisture harvesting independently, viz. the Australian thorny devil (Moloch horridus), the Arabian toadhead agama (Phrynocephalus arabicus) and the Texas horned lizard (Phrynosoma cornutum). All three lizards have a honeycomb like micro ornamentation on the outer surface of the scales and a complex capillary system in between the scales. By investigation of individual scales and by producing and characterising polymer replicas of the reptiles' integuments, we found that the honeycomb like structures render the surface superhydrophilic, most likely by holding a water film physically stable. Furthermore, the condensation of air humidity is improved on this surface by about 100% in comparison to unstructured surfaces. This allows the animals to collect moisture with their entire body surface. The collected water is transported into the capillary system. For Phrynosoma cornutum we found the interesting effect that, in contrast to the other two investigated species, the water flow in the capillary system is not uniform but directed to the mouth. Taken together we found that the micro ornamentation yields a superhydrophilic surface, and the semi-tubular capillaries allow for an efficient passive – and for Phrynosoma directed – transport of water. PMID:21977432

  13. Effects of clustering structure on volumetric properties of amino acids in (DMSO + water) mixtures

    International Nuclear Information System (INIS)

    Huang Aimin; Liu Chunli; Ma Lin; Tong Zhangfa; Lin Ruisen

    2012-01-01

    Graphical abstract: Together with static light scattering measurement, volumetric properties of glycine, L-alanine and L-serine were determined and utilized to reveal the microscopic solvent structure of (DMSO + water) mixtures and its influence on the interaction between DMSO and amino acids from a clustering point of view. The results demonstrated that the interaction between amino acids and DMSO was greatly related to the clustering structure of the mixed solvent and that amino acids interacted with already established solvent clusters. Hydrophobic aggregating of DMSO lead to a decrease in the hydrophobic effect of DMSO and the hydrophobic–hydrophilic and hydrophobic–hydrophobic interaction with amino acids, which was reflected by the solvation of proteins. Highlights: ► Determine volumetric properties of three amino acids in aqueous DMSO in details. ► Static light scattering measurement for clustering structure of aqueous DMSO. ► Volumetric behaviour of amino acids depends on clustering structure of aqueous DMSO. ► Clustering structure of aqueous DMSO influences solvation of protein and cellulose. - Abstract: For a better understanding on the functions of DMSO in biological systems at a relatively lower concentration, apparent molar volumes of three typical amino acids, glycine, L-alanine and L-serine in (DMSO + water) mixtures were determined and the transfer volumes from water to the mixtures were evaluated. Together with static light scattering measurement, the results were utilised to reveal the microscopic solvent structure of (DMSO + water) mixtures and its influence on the interaction between DMSO and amino acids from a clustering point of view. The results demonstrate that the interaction between amino acids and DMSO is greatly related to the clustering structure of the mixed solvent and that amino acids interacted with already established solvent clusters. The linear dependence of transfer volume of amino acids on DMSO concentration up to 2

  14. Probing the electronic structure of liquid water with many-body perturbation theory

    Science.gov (United States)

    Pham, Tuan Anh; Zhang, Cui; Schwegler, Eric; Galli, Giulia

    2014-03-01

    We present a first-principles investigation of the electronic structure of liquid water based on many-body perturbation theory (MBPT), within the G0W0 approximation. The liquid quasiparticle band gap and the position of its valence band maximum and conduction band minimum with respect to vacuum were computed and it is shown that the use of MBPT is crucial to obtain results that are in good agreement with experiment. We found that the level of theory chosen to generate molecular dynamics trajectories may substantially affect the electronic structure of the liquid, in particular, the relative position of its band edges and redox potentials. Our results represent an essential step in establishing a predictive framework for computing the relative position of water redox potentials and the band edges of semiconductors and insulators. Work supported by DOE/BES (Grant No. DE-SC0008938). Work at LLNL was performed under Contract DE-AC52-07NA27344.

  15. Effect of biochar on soil structural characteristics: water retention and gas transport

    DEFF Research Database (Denmark)

    Sun, Zhencai; Møldrup, Per; Vendelboe, Anders Lindblad

    Biochar addition to agricultural soil has been reported to reduce climate gas emission, as well as improve soil fertility and crop productivity. Little, however, is known about biochar effects on soil structural characteristics. This study investigates if biochar-application changes soil structural...... characteristics, as indicated from water retention and gas transport measurements on intact soil samples. Soil was sampled from a field experiment on a sandy loam with four control plots (C) without biochar and four plots (B) with incorporated biochar at a rate of 20 tons per hectare (plot size, 6 x 8 m). The C......-gas diffusivity on intact 100cm3 soil samples (5 replicates in each plot). We found that biochar application significantly decreased soil bulk density, hereby creating higher porosity. At the same soil-water matric potential, all the soil-gas phase parameters (air-filled porosity, air permeability and gas...

  16. Water vapor weathering of Taurus-Littrow orange soil - A pore-structure analysis

    Science.gov (United States)

    Cadenhead, D. A.; Mikhail, R. S.

    1975-01-01

    A pore-volume analysis was performed on water vapor adsorption data previously obtained on a fresh sample of Taurus-Littrow orange soil, and the analysis was repeated on the same sample after its exposure to moist air for a period of approximately six months. The results indicate that exposure of an outgassed sample to high relative pressures of water vapor can result in the formation of substantial micropore structure, the precise amount being dependent on the sample pretreatment, particularly the outgassing temperature. Micropore formation is explained in terms of water penetration into surface defects. In contrast, long-term exposure to moist air at low relative pressures appears to reverse the process with the elimination of micropores and enlargement of mesopores possibly through surface diffusion of metastable adsorbent material. The results are considered with reference to the storage of lunar samples.

  17. Structure and dynamics of water and lipid molecules in charged anionic DMPG lipid bilayer membranes

    DEFF Research Database (Denmark)

    Rønnest, A. K.; Peters, Günther H.J.; Hansen, Flemming Yssing

    2016-01-01

    Molecular dynamics simulations have been used to investigate the influence of the valency of counter-ions on the structure of freestanding bilayer membranes of the anionic 1,2-dimyristoyl-sn-glycero-3-phosphoglycerol (DMPG) lipid at 310 K and 1 atm. At this temperature, the membrane is in the fluid...... compared to experimental results and used to determine an average diffusion constant for all water molecules in the system. On extrapolating the diffusion constants inferred experimentally to a temperature of 310 K, reasonable agreement with the simulations is obtained. However, the experiments do not have...... the sensitivity to confirm the diffusion of a small component of water bound to the lipids as found in the simulations. In addition, the orientation of the dipole moment of the water molecules has been determined as a function of their depth in the membrane. Previous indirect estimates of the electrostatic...

  18. Analysis of water hammer-structure interaction in piping system for a loss of coolant accident in primary loop of pressurized water reactor

    International Nuclear Information System (INIS)

    Zhang Xiwen; Yang Jinglong; He Feng; Wang Xuefang

    2000-01-01

    The conventional analysis of water hammer and dynamics response of structure in piping system is divided into two parts, and the interaction between them is neglected. The mechanism of fluid-structure interaction under the double-end break pipe in piping system is analyzed. Using the characteristics method, the numerical simulation of water hammer-structure interaction in piping system is completed based on 14 parameters and 14 partial differential equations of fluid-piping cell. The calculated results for a loss of coolant accident (LOCA) in primary loop of pressurized water reactor show that the waveform and values of pressure and force with time in piping system are different from that of non-interaction between water hammer and structure in piping system, and the former is less than the later

  19. Mixing of alcohol and water molecules studied by neutron probe. Structure and dynamics

    International Nuclear Information System (INIS)

    Yoshida, Koji

    2001-01-01

    Structure of water/alcohol mixing solution was studied by three methods such as an isotope-exchanged neutron scattering method, RISM (Reference Interaction Site Model) integral equation and a neutron spin echo method. The principle of methods, experiments and results were reported. The results of experiments of water/tert-butyl alcohol (TBA) solution by the isotope-exchange neutron scattering method showed TBA molecule associated with each other through end methyl group. Especially this effect was the largest at x TBA = 0.06 and decreased with increasing the concentration of TBA. However, hydrogen bonding of TBA was very rare at x TBA = 0.06. By the partial radial distribution function obtained from RISM integral equation, it indicated that the structure of pure TBA became chain structure by hydrogen bond but changed to the structure contacted directly each hydrophobic group with increasing the concentration of water. Water/2-butoxyethanol (BE) mixing solution was measured by a neutron spin echo method. The activation energy of the diffusion coefficients obtained agreed to the energy of hydrogen bonding. The temperature response of diffusion coefficients showed the inverse of the experimental results obtained by the dynamic light scattering method. The difference between two measurement methods was different time scale and space scale. Namely, the object of the neutron scattering method is nano meter and nano second, but one of light scattering method many times over. It was proved from the above results that there was the cluster consisted of the same kind of molecule in the homogeneous two components solution, but the cluster was not stable and constantly exchanged with molecule, where the production and decay of the cluster is repeated at about nano sec. (S.Y.)

  20. Data needs for the track structure of alpha particles and electrons in water

    International Nuclear Information System (INIS)

    Pagnamenta, A.

    1983-01-01

    We have made calculations of the ionization spectra for alpha particle and electron tracks in water. We have also computed the number of ions created per micrometre of track length, the energy distribution of the secondaries, and the energy expended per ion pair created. Our aim is less toward theoretical derivations than to obtain a numerically accurate description of the track structure at all energies in a form suitable for biomedical applications. 13 references

  1. Heavy water effects on the structure, functions and behavior of biological systems

    International Nuclear Information System (INIS)

    Buzgariu, Wanda; Caloianu, Maria; Moldovan, Lucia; Titescu, G.

    2003-01-01

    The H 2 O substitution for D 2 O either in environment or in the culture medium of the living systems generates changes in their main functions and composition. In this paper some of the heavy water effects in biological systems such as structural and functional changes were reviewed: normal cell architecture alterations, cell division and membrane functions disturbance, muscular contractility and the perturbations of biological oscillators such as circadian rhythm, heart rate, respiratory cycle, tidal and ultradian rhythm. (authors)

  2. Physiology and microbial community structure in soil at extreme water content

    Czech Academy of Sciences Publication Activity Database

    Uhlířová, Eva; Elhottová, Dana; Tříska, Jan; Šantrůčková, Hana

    2005-01-01

    Roč. 50, č. 2 (2005), s. 161-166 ISSN 0015-5632 R&D Projects: GA ČR(CZ) GA206/99/1410; GA ČR(CZ) GA526/99/P033 Institutional research plan: CEZ:AV0Z6066911 Keywords : microbial community structure * soils * extreme water content Subject RIV: EH - Ecology, Behaviour Impact factor: 0.918, year: 2005

  3. Design and analysis of the DII-D radiative divertor water-cooled structures

    International Nuclear Information System (INIS)

    Hollerbach, M.A.; Smith, J.P.; Baxi, C.B.; Bozek; Chin, E.; Phelps, R.D.; Redler, K.M.; Reis, E.E.

    1995-10-01

    The Radiative Divertor is a major modification to the divertor of DIII-D and is being designed and fabricated for installation in late 1996. The Radiative Divertor Program (RDP) will enhance the dissipative processes in the edge and divertor plasmas to reduce the heat flux and plasma erosion at the divertor target. This approach will have major implications for the heat removal methods used in future devices. The divertor is of slot-type configuration designed to minimize the flow of sputtered and injected impurities back to the core plasma. The new divertor will be composed of toroidally continuous, Inconel 625 water-cooled rings of sandwich construction with an internal water channel, incorporating seam welding to provide the water-to-vacuum seal as well as structural integrity. The divertor structure is designed to withstand electromagnetic loads as a result of halo currents and induced toroidal currents. It also accommodates the thermal differences experienced during the 400 degrees C bake used on DIII-D. A low Z plasma-facing surface is provided by mechanically attached graphite tiles. Water flow through the rings will inertially cool these tiles which will be subjected to 38 MW, 10 second pulses. Current schedules call for detailed design in 1996 with installation completed in March 1997. A full size prototype, one-quarter of one ring, is being built to validate manufacturing techniques, machining, roll-forming, and seam welding. The experience and knowledge gained through the fabrication of the prototype is discussed. The design of the electrically isolated (5 kV) vacuum-to-air water feedthroughs supplying the water-cooled rings is also discussed

  4. Design and analysis of the DIII-D radiative divertor water-cooled structures

    International Nuclear Information System (INIS)

    Hollerbach, M.A.; Smith, J.P.; Baxi, C.B.; Bozek, A.S.; Chin, E.; Phelps, R.D.; Redler, K.M.; Reis, E.E.

    1995-01-01

    The Radiative Divertor is a major modification to the divertor of DIII-D and is being designed and fabricated for installation in late 1996. The Radiative Divertor Program (RDP) will enhance the dissipative processes in the edge and divertor plasmas to reduce the heat flux and plasma erosion at the divertor target. This approach will have major implications for the heat removal methods used in future devices. The divertor is of slot-type configuration designed to minimize the flow of sputtered and injected impurities back to the core plasma. The new divertor will be composed of toroidally continuous, Inconel 625 water-cooled rings of sandwich construction with an internal water channel, incorporating seam welding to provide the water-to-vacuum seal as well as structural integrity. The divertor structure is designed to withstand electro-magnetic loads as a result of halo currents and induced toroidal currents. It also accommodates the thermal differences experienced during the 400 C bake used on DIII-D. A low Z plasma-facing surface is provided by mechanically attached graphite tiles. Water flow through the rings will inertially cool these tiles which will be subjected to 38 MW, 10 second pulses. Current schedules call for detailed design in 1996 with installation completed in March 1997. A full size prototype, one-quarter of one ring, is being built to validate manufacturing techniques, machining, roll-forming, and seam welding. The experience and knowledge gained through the fabrication of the prototype is discussed. The design of the electrically isolated (5 kV) vacuum-to-air water feedthroughs supplying the water-cooled rings is also discussed

  5. Molecular simulation of the water-triolein-oleic acid mixture: Local structure and thermodynamic properties

    Science.gov (United States)

    Couallier, E.; Riaublanc, A.; David Briand, E.; Rousseau, B.

    2018-05-01

    An artificial oil-in-water emulsion analogous to those found in bioresources or food matrices is simulated and studied experimentally. It is composed of one of the major natural free fatty acids (the oleic acid, OA) and the corresponding triacylglyceride (trioleic glyceride, or triolein, GTO). Because of the large time and length scales involved, the molecular simulations are done with the Martini force field, a coarse-grained model. This allowed us to study the water-OA-GTO system at different compositions with more than 20 000 molecules and up to 2 μs. Interfacial tension was measured using the pendant drop method and compared with molecular simulation results. We observe very good agreement at high OA concentrations and deviations up to 15% at low OA concentrations. The water solubility in the lipid phase is in fair agreement with experiments, between 0.03 and 0.32 mol/l, rising with the OA content. The area occupied by OA and GTO at the interface between water and the pure product fitted with experimental data (AOA = 36.6 Å2 and AGTO = 152.1 Å2). The consistency between simulation and experimental results allowed a structural analysis of the interface. A bilayer structure of the lipids at the water/oil interface is proposed, containing preferentially oleic acid but also triolein. Through all these results, the usefulness of coarse-grained simulation for the description of water-oil interfacial organization is demonstrated. This method will be used later to bring local information on the organization of target compounds, necessary in biomass fractionation processes or food additive formulations, for example.

  6. Attenuation and Velocity Structure in Spain and Morocco: Distinguishing Between Water, Temperature, and Partial Melt

    Science.gov (United States)

    Bezada, M. J.; Humphreys, E.

    2014-12-01

    Temperature, melt fraction, and water content affect seismic velocity and attenuation differently. Both are sensitive to temperature, but velocity is more sensitive to melt fraction and attenuation is thought to be more sensitive to water content. For these reasons, combining attenuation measurements with tomographic imaging of velocity structure can help untangle these fields and better resolve lithospheric structure and physical state. We map variations in attenuation beneath Spain and northern Morocco using teleseismic data generated by more than a dozen teleseismic deep-focus earthquakes recorded on a dense array of stations. For each event, we first estimate the source from the best quality recordings. We then apply an attenuation operator to the source estimate, using a range of t* values, to match the record at each station. We invert for a smooth map of t* from the ensemble of measurements. The spatial patterns in t* correlate very well with the tectonic domains in Spain and Morocco. In particular, areas in Spain that resisted deformation during the Variscan and Alpine orogenies produce very little attenuation. Comparing the attenuation map with seismic velocity structure we find that, in Morocco, some areas with strong low-velocity anomalies and recent volcanism do not cause high attenuation. These observations suggest that water content is a more likely cause for seismic attenuation in the study area than temperature, and that the non-attenuative low-velocity anomalies in Morocco are produced by partial mel.

  7. Variations in Microbial Community Structure through the Stratified Water Column in the Tyrrhenian Sea (Central Mediterranean

    Directory of Open Access Journals (Sweden)

    Francesco Smedile

    2015-08-01

    Full Text Available The central Mediterranean Sea is among the most oligotrophic habitats in the marine environment. In this study, we investigated the abundance, diversity and activity of prokaryoplankton in the water column (25–3000-m depth at Station Vector (Tyrrhenian Sea, 39°32.050′ N; 13°22.280′ E. This specific water column consists of three different water masses (Modified Atlantic Water (MAW, Levantine Intermediate Water (LIW and Tyrrhenian Deep Water (TDW, possessing a typical stratification of the Central Mediterranean basin. CARD-FISH showed that the metabolically-active fraction of bacterial populations exceeded the archaeal fraction along the whole water column, except at the deepest water masses. 16S rDNA and 16S rRNA clone libraries obtained from each type of water mass were used to analyse the prokaryoplankton community structure and to distinguish between active and “less active” microbial fractions. Our results showed that the rRNA-derived bacterial libraries seemed to be more depth specific compared to 16S rDNA-derived counterparts. Major differences were detected between the active fractions of bacterioplankton thriving in photic (25 m, MAW and aphotic layers (500–3000 m, LIW and TDW respectively, whereas no statistically-significant differences were detected within the deep, aphotic layers (500–3000 m, LIW and TDW. Archaeal communities possessed more depth-specific distribution patterns with both total and active fractions showing depth stratification. Cyanobacteria and Marine Group II MAGII of Euryarchaea dominated the MAW prokaryoplankton. A notable fraction of Geitlerinema-related cyanobacteria was detected among the metabolically-active bacterial population recovered from the mesopelagic (500 m, LIW aphotic layer, which is indicative of their mixotrophic behaviour. Heterotrophic Gammaproteobacteria and members of Marine Group 1.1a and the PSL12-related ALOHA group of Thaumarchaeota were both abundant in the aphotic layers

  8. Scheme of substations: circuit breakers topology; El esquema de S.E.: interruptor y medio y algunas variantes del mismo, a la luz de la gestion privada de instalaciones de servicio publico

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, Maximo B. [Sade Skanska S.A. (Argentina)

    2001-07-01

    This work approaches a topological scheme applicable for the entrance circuit breakers which are used in high voltage substations and also in substations from the rated voltage class of 115 Kv by many countries. It is a safe scheme due to providing a double connection for the feeder cables and more economical than the double circuit breakers option. Nevertheless, the scheme has some restrictions as follows: a) The premises of continuity are not accomplished in small substations b) It is possible to occur a responsibility conflict in relation to the main circuit breaker. In the private administration of public service facilities multiples jurisdictions can appear which require well defined limits, and the penalties due to outages can be minimized.

  9. Impact of regression methods on improved effects of soil structure on soil water retention estimates

    Science.gov (United States)

    Nguyen, Phuong Minh; De Pue, Jan; Le, Khoa Van; Cornelis, Wim

    2015-06-01

    Increasing the accuracy of pedotransfer functions (PTFs), an indirect method for predicting non-readily available soil features such as soil water retention characteristics (SWRC), is of crucial importance for large scale agro-hydrological modeling. Adding significant predictors (i.e., soil structure), and implementing more flexible regression algorithms are among the main strategies of PTFs improvement. The aim of this study was to investigate whether the improved effect of categorical soil structure information on estimating soil-water content at various matric potentials, which has been reported in literature, could be enduringly captured by regression techniques other than the usually applied linear regression. Two data mining techniques, i.e., Support Vector Machines (SVM), and k-Nearest Neighbors (kNN), which have been recently introduced as promising tools for PTF development, were utilized to test if the incorporation of soil structure will improve PTF's accuracy under a context of rather limited training data. The results show that incorporating descriptive soil structure information, i.e., massive, structured and structureless, as grouping criterion can improve the accuracy of PTFs derived by SVM approach in the range of matric potential of -6 to -33 kPa (average RMSE decreased up to 0.005 m3 m-3 after grouping, depending on matric potentials). The improvement was primarily attributed to the outperformance of SVM-PTFs calibrated on structureless soils. No improvement was obtained with kNN technique, at least not in our study in which the data set became limited in size after grouping. Since there is an impact of regression techniques on the improved effect of incorporating qualitative soil structure information, selecting a proper technique will help to maximize the combined influence of flexible regression algorithms and soil structure information on PTF accuracy.

  10. Shear-stress-induced structural arrangement of water molecules in nanoscale Couette flow with slipping at wall boundary

    International Nuclear Information System (INIS)

    Lin, Jau-Wen

    2014-01-01

    This study investigated the structuring of water molecules in a nanoscale Couette flow with the upper plate subjected to lateral forces with various magnitudes and water slipping against a metal wall. It was found that when the upper plate is subjected to a force, the water body deforms into a parallelepiped. Water molecules in the channel are then gradually arranged into lattice positions, creating a layered structure. The structural arrangement of water molecules is caused by the water molecules accommodating themselves to the increase in energy under the application of a lateral force on the moving plate. The ordering arrangement of water molecules increases the rotational degree of freedom, allowing the molecules to increase their Coulomb potential energy through polar rotation that accounts for the energy input through the upper plate. With a force continuously applied to the upper plate, the water molecules in contact with the upper plate move forward until slip between the water and upper plate occurs. The relation between the structural arrangement of water molecules, slip at the wall, and the shear force is studied. The relation between the slip and the locking/unlocking of water molecules to metal atoms is also studied

  11. Effect of hardening methods of moulding sands with water glass on structure of bonding bridges

    Directory of Open Access Journals (Sweden)

    M. Stachowicz

    2010-07-01

    Full Text Available Research on influence of hardening methods on structure of bonding bridges in moulding sands with sodium water glass is presented.Moulding sands with addition of 2.5 % of binder with molar module 2.0 were hardened with CO2 and dried in traditional way or hardenedwith microwaves. It was proved that the hardening method affects structure of bonding bridges, correlating with properties of the hardened moulding sands. It was found that strength of the moulding sands hardened with microwaves for 4 min is very close to that measured after traditional drying at 110 °C for 120 min. So, application of microwave hardening ensures significant shortening of the process time to the value comparable with CO2 hardening but guaranteeing over 10-fold increase of mechanical properties. Analysis of SEM images of hardened moulding sands permitted explaining differences in quality parameters of moulding sands by connecting them with structure of the created bonding bridges.

  12. Theoretical and experimental investigation into structural and fluid motions at low frequencies in water distribution pipes

    Science.gov (United States)

    Gao, Yan; Liu, Yuyou

    2017-06-01

    Vibrational energy is transmitted in buried fluid-filled pipes in a variety of wave types. Axisymmetric (n = 0) waves are of practical interest in the application of acoustic techniques for the detection of leaks in underground pipelines. At low frequencies n = 0 waves propagate longitudinally as fluid-dominated (s = 1) and shell-dominated (s = 2) waves. Whilst sensors such as hydrophones and accelerometers are commonly used to detect leaks in water distribution pipes, the mechanism governing the structural and fluid motions is not well documented. In this paper, the low-frequency behaviour of the pipe wall and the contained fluid is investigated. For most practical pipework systems, these two waves are strongly coupled; in this circumstance the ratios of the radial pipe wall displacements along with the internal pressures associated with these two wave types are obtained. Numerical examples show the relative insensitivity of the structural and fluid motions to the s = 2 wave for both metallic and plastic pipes buried in two typical soils. It is also demonstrated that although both acoustic and vibration sensors at the same location provide the identical phase information of the transmitted signals, pressure responses have significantly higher levels than acceleration responses, and thus hydrophones are better suited in a low signal-to-noise ratio (SNR) environment. This is supported by experimental work carried out at a leak detection facility. Additional pressure measurements involved excitation of the fluid and the pipe fitting (hydrant) on a dedicated water pipe. This work demonstrates that the s = 1 wave is mainly responsible for the structural and fluid motions at low frequencies in water distribution pipes as a result of water leakage and direct pipe excitation.

  13. Impact of water temperature and structural parameters on the hydraulic labyrinth-channel emitter performance

    Directory of Open Access Journals (Sweden)

    Ahmed I. Al-Amoud

    2014-06-01

    Full Text Available The effects of water temperature and structural parameters of a labyrinth emitter on drip irrigation hydraulic performance were investigated. The inside structural parameters of the trapezoidal labyrinth emitter include path width (W and length (L, trapezoidal unit numbers (N, height (H, and spacing (S. Laboratory experiments were conducted using five different types of labyrinth-channel emitters (three non-pressure compensating and two pressure-compensating emitters commonly used for subsurface drip irrigation systems. The water temperature effect on the hydraulic characteristics at various operating pressures was recorded and a comparison was made to identify the most effective structural parameter on emitter performance. The pressure compensating emitter flow exponent (x average was 0.014, while non-pressure compensating emitter’s values average was 0.456, indicating that the sensitivity of non-pressure compensating emitters to pressure variation is an obvious characteristic (p<0.001 of this type of emitters. The effects of water temperature on emitter flow rate were insignificant (p>0.05 at various operating pressures, where the flow rate index values for emitters were around one. The effects of water temperature on manufacturer’s coefficient of variation (CV values for all emitters were insignificant (p>0.05. The CV values of the non-pressure compensating emitters were lower than those of pressure compensating emitters. This is typical for most compensating models because they are manufactured with more elements than non-compensating emitters are. The results of regression analysis indicate that N and H are the essential factors (p<0.001 to affect the hydraulic performance.

  14. Artificial neural networks aided conceptual stage design of water harvesting structures

    Directory of Open Access Journals (Sweden)

    Vinay Chandwani

    2016-09-01

    Full Text Available The paper presents artificial neural networks (ANNs based methodology for ascertaining the structural parameters of water harvesting structures (WHS at the conceptual stage of design. The ANN is trained using exemplar patterns generated using an in-house MSExcel based design program, to draw a functional relationship between the five inputs design parameters namely, peak flood discharge, safe bearing capacity of strata, length of structure, height of structure and silt factor and four outputs namely, top width, bottom width, foundation depth and flood lift representing the structural parameters of WHS. The results of the study show that, the structural parameters of the WHS predicted using ANN model are in close agreement with the actual field parameters. The versatility of ANN to map complex or complex unknown relationships has been proven in the study. A parametric sensitivity study is also performed to assess the most significant design parameter. The study holistically presents a neural network based decision support tool that can be used to accurately estimate the major design parameters of the WHS at the conceptual stage of design in quick time, aiding the engineer-in-charge to conveniently forecast the budget requirements and minimize the labor involved during the subsequent phases of analysis and design.

  15. Completion Report on the Corps of Engineers Structural Engineering Conference Held in Portland, Oregon on 23-28 June 1985.

    Science.gov (United States)

    1986-03-01

    The domes are fabricated from extruded 6061-T6 aluminum, 6 in. deep, wide flange struts, approximately 8 ft long, forming triangular structural...Ice Breaker - snack lines laid out poorly and bar dismantled too quickly. Not a lot of nearby food choices on evening and weekends. 12. Wednesday

  16. Aqueous turbulence structure immediately adjacent to the air - water interface and interfacial gas exchange

    Science.gov (United States)

    Wang, Binbin

    Air-sea interaction and the interfacial exchange of gas across the air-water interface are of great importance in coupled atmospheric-oceanic environmental systems. Aqueous turbulence structure immediately adjacent to the air-water interface is the combined result of wind, surface waves, currents and other environmental forces and plays a key role in energy budgets, gas fluxes and hence the global climate system. However, the quantification of turbulence structure sufficiently close to the air-water interface is extremely difficult. The physical relationship between interfacial gas exchange and near surface turbulence remains insufficiently investigated. This dissertation aims to measure turbulence in situ in a complex environmental forcing system on Lake Michigan and to reveal the relationship between turbulent statistics and the CO2 flux across the air-water interface. The major objective of this dissertation is to investigate the physical control of the interfacial gas exchange and to provide a universal parameterization of gas transfer velocity from environmental factors, as well as to propose a mechanistic model for the global CO2 flux that can be applied in three dimensional climate-ocean models. Firstly, this dissertation presents an advanced measurement instrument, an in situ free floating Particle Image Velocimetry (FPIV) system, designed and developed to investigate the small scale turbulence structure immediately below the air-water interface. Description of hardware components, design of the system, measurement theory, data analysis procedure and estimation of measurement error were provided. Secondly, with the FPIV system, statistics of small scale turbulence immediately below the air-water interface were investigated under a variety of environmental conditions. One dimensional wave-number spectrum and structure function sufficiently close to the water surface were examined. The vertical profiles of turbulent dissipation rate were intensively studied

  17. Nano-structured silica coated mesoporous carbon micro-granules for potential application in water filtration

    Science.gov (United States)

    Das, Avik; Sen, D.; Mazumder, S.; Ghosh, A. K.

    2017-05-01

    A novel nano-composite spherical micro-granule has been synthesized using a facile technique of solvent evaporation induced assembly of nanoparticles for potential application in water filtration. The spherical micro-granule is comprised of nano-structured shell of hydrophilic silica encapsulating a hydrophobic mesoporous carbon at the core. Hierarchical structure of such core-shell micro-granules has been rigorously characterized using small-angle neutron and X-ray scattering techniques and complemented with scanning electron microscopy. The hydrophilic silica envelope around the carbon core helps in incorporation of such granules into the hydrophilic polymeric ultra-filtration membrane. The interstitial micro-pores present in the silica shell can serve as water transport channels and the mesoporus carbon core enhances the separation performance due its well adsorption characteristics. It has been found that the incorporation of such granules inside the ultra-filtration membrane indeed enhances the water permeability as well as the separation performance in a significant way.

  18. Role of water on formation and structural features of Maya blue

    International Nuclear Information System (INIS)

    Mondelli, C; Río, M Sánchez del; González, M A; Magazzú, A; Cavallari, C; Suárez, M; García-Romero, E; Romano, P

    2012-01-01

    The Maya blue (MB) is an artificial pigment created between 500-800 A.D. and used in murals, pottery and sculptures by Mayas and other people in Mesoamerica. MB is resistant to age, acid, weathering, biodegradation and even modern chemical solvents, but the chemical reasons behind the resistance to chemical aggressions are still under debate. Water plays a fundamental role in the interactions between indigo and clay. The dynamics of the clay's zeolitic and structural water molecules during the formation of MB, usually stabilized by moderate heating, has been monitored by means of neutron inelastic scattering. Neutron incoherent scattering in these samples is only due to the hydrogen atoms, so the signal is very sensitive to the amount of released water, providing detailed information on the dehydration process. A simultaneous analysis of the coherent elastic scattering and the incoherent scattering allows observing and quantifying how the structure of the clay is affected by dehydration. Here we show that a quite resistant pigment can be obtained at room temperature simply by dehydrating a palygorskite-indigo mixture employing only vacuum, without any thermal treatment.

  19. Distortions of the calcite and aragonite atomic structures from interstitial water

    Energy Technology Data Exchange (ETDEWEB)

    Sinha, S.; Rez, P., E-mail: Peter.Rez@asu.edu

    2015-05-01

    Amorphous calcium carbonate (ACC), as observed by diffraction or infra-red spectroscopy, is especially significant as a precursor in biomineralization. The atomic structure and mechanisms for transformation to the crystalline phases are still unknown. It is conceivable that insertion of water molecules could give rise to distortions that result in the observed diffraction patterns and infrared spectra. We use the VASP density functional theory code to relax model supercells with 24 formula units of CaCO{sub 3} where we have inserted up to 5 water molecules, corresponding to 3.75 wt%. The main effect is tilting of the carbonate planes, which can be as high as 50°. This leads to a range of Ca–O distances that are consistent with the observed changes in the IR spectra in ACC. The spread in cation–cation distances is not enough to destroy coherent diffraction from regions 70 nm across, and so does not explain amorphous diffraction profiles. - Highlights: • Low concentrations of water in the calcite or aragonite structures lead to tilting of the carbonate planes. • This is consistent with IR observations from amorphous calcium carbonate. • It does not explain amorphous diffraction patterns.

  20. Role of water on formation and structural features of Maya blue

    Science.gov (United States)

    Mondelli, C.; Sánchez del Río, M.; González, M. A.; Magazzú, A.; Cavallari, C.; Suárez, M.; García-Romero, E.; Romano, P.

    2012-02-01

    The Maya blue (MB) is an artificial pigment created between 500-800 A.D. and used in murals, pottery and sculptures by Mayas and other people in Mesoamerica. MB is resistant to age, acid, weathering, biodegradation and even modern chemical solvents, but the chemical reasons behind the resistance to chemical aggressions are still under debate. Water plays a fundamental role in the interactions between indigo and clay. The dynamics of the clay's zeolitic and structural water molecules during the formation of MB, usually stabilized by moderate heating, has been monitored by means of neutron inelastic scattering. Neutron incoherent scattering in these samples is only due to the hydrogen atoms, so the signal is very sensitive to the amount of released water, providing detailed information on the dehydration process. A simultaneous analysis of the coherent elastic scattering and the incoherent scattering allows observing and quantifying how the structure of the clay is affected by dehydration. Here we show that a quite resistant pigment can be obtained at room temperature simply by dehydrating a palygorskite-indigo mixture employing only vacuum, without any thermal treatment.

  1. Structural Investigation of Alkali Activated Clay Minerals for Application in Water Treatment Systems

    Science.gov (United States)

    Bumanis, G.; Bajare, D.; Dembovska, L.

    2015-11-01

    Alkali activation technology can be applied for a wide range of alumo-silicates to produce innovative materials with various areas of application. Most researches focuse on the application of alumo-silicate materials in building industry as cement binder replacement to produce mortar and concrete [1]. However, alkali activation technology offers high potential also in biotechnologies [2]. In the processes where certain pH level, especially alkaline environment, must be ensured, alkali activated materials can be applied. One of such fields is water treatment systems where high level pH (up to pH 10.5) ensures efficient removal of water pollutants such as manganese [3]. Previous investigations had shown that alkali activation technology can be applied to calcined clay powder and aluminium scrap recycling waste as a foam forming agent to create porous alkali activated materials. This investigation focuses on the structural investigation of calcined kaolin and illite clay alkali activation processes. Chemical and mineralogical composition of both clays were determined and structural investigation of alkali activated materials was made by using XRD, DTA, FTIR analysis; the microstructure of hardened specimens was observed by SEM. Physical properties of the obtained material were determined. Investigation indicates the essential role of chemical composition of the clay used in the alkali activation process, and potential use of the obtained material in water treatment systems.

  2. Seismic response of elevated rectangular water tanks considering soil structure interaction

    Science.gov (United States)

    Visuvasam, J.; Simon, J.; Packiaraj, J. S.; Agarwal, R.; Goyal, L.; Dhingra, V.

    2017-11-01

    The overhead staged water tanks are susceptible for high lateral forces during earthquakes. Due to which, the failure of beam-columns joints, framing elements and toppling of tanks arise. To avoid such failures, they are analyzed and designed for lateral forced induced by devastating earthquakes assuming the base of the structures are fixed and considering functional needs, response reduction, soil types and severity of ground shaking. In this paper, the flexible base was provided as spring stiffness in order to consider the effect of soil properties on the seismic behaviour of water tanks. A linear time history earthquake analysis was performed using SAP2000. Parametric studies have been carried out based on various types of soils such as soft, medium and hard. The soil stiffness values highly influence the time period and base shear of the structure. The ratios of time period of flexible to fixed base and base shear of flexible to fixed base were observed against capacities of water tank and the overall height of the system. The both responses are found to be increased as the flexibility of soil medium decreases

  3. Structure and dynamics of POPC bilayers in water solutions of room temperature ionic liquids

    International Nuclear Information System (INIS)

    Benedetto, Antonio; Bingham, Richard J.; Ballone, Pietro

    2015-01-01

    Molecular dynamics simulations in the NPT ensemble have been carried out to investigate the effect of two room temperature ionic liquids (RTILs), on stacks of phospholipid bilayers in water. We consider RTIL compounds consisting of chloride ([bmim][Cl]) and hexafluorophosphate ([bmim][PF 6 ]) salts of the 1-buthyl-3-methylimidazolium ([bmim] + ) cation, while the phospholipid bilayer is made of 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC). Our investigations focus on structural and dynamical properties of phospholipid and water molecules that could be probed by inelastic and quasi-elastic neutron scattering measurements. The results confirm the fast incorporation of [bmim] + into the lipid phase already observed in previous simulations, driven by the Coulomb attraction of the cation for the most electronegative oxygens in the POPC head group and by sizeable dispersion forces binding the neutral hydrocarbon tails of [bmim] + and of POPC. The [bmim] + absorption into the bilayer favours the penetration of water into POPC, causes a slight but systematic thinning of the bilayer, and further stabilises hydrogen bonds at the lipid/water interface that already in pure samples (no RTIL) display a lifetime much longer than in bulk water. On the other hand, the effect of RTILs on the diffusion constant of POPC (D POPC ) does not reveal a clearly identifiable trend, since D POPC increases upon addition of [bmim][Cl] and decreases in the [bmim][PF 6 ] case. Moreover, because of screening, the electrostatic signature of each bilayer is only moderately affected by the addition of RTIL ions in solution. The analysis of long wavelength fluctuations of the bilayers shows that RTIL sorption causes a general decrease of the lipid/water interfacial tension and bending rigidity, pointing to the destabilizing effect of RTILs on lipid bilayers

  4. Structure and dynamics of POPC bilayers in water solutions of room temperature ionic liquids

    Energy Technology Data Exchange (ETDEWEB)

    Benedetto, Antonio [School of Physics, University College Dublin, Dublin 4 (Ireland); Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, 5232 Villigen (Switzerland); Bingham, Richard J. [York Centre for Complex Systems Analysis, University of York, York YO10 5GE (United Kingdom); Ballone, Pietro [Center for Life Nano Science @Sapienza, Istituto Italiano di Tecnologia (IIT), 00185 Roma (Italy); Department of Physics, Università di Roma “La Sapienza,” 00185 Roma (Italy)

    2015-03-28

    Molecular dynamics simulations in the NPT ensemble have been carried out to investigate the effect of two room temperature ionic liquids (RTILs), on stacks of phospholipid bilayers in water. We consider RTIL compounds consisting of chloride ([bmim][Cl]) and hexafluorophosphate ([bmim][PF{sub 6}]) salts of the 1-buthyl-3-methylimidazolium ([bmim]{sup +}) cation, while the phospholipid bilayer is made of 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC). Our investigations focus on structural and dynamical properties of phospholipid and water molecules that could be probed by inelastic and quasi-elastic neutron scattering measurements. The results confirm the fast incorporation of [bmim]{sup +} into the lipid phase already observed in previous simulations, driven by the Coulomb attraction of the cation for the most electronegative oxygens in the POPC head group and by sizeable dispersion forces binding the neutral hydrocarbon tails of [bmim]{sup +} and of POPC. The [bmim]{sup +} absorption into the bilayer favours the penetration of water into POPC, causes a slight but systematic thinning of the bilayer, and further stabilises hydrogen bonds at the lipid/water interface that already in pure samples (no RTIL) display a lifetime much longer than in bulk water. On the other hand, the effect of RTILs on the diffusion constant of POPC (D{sub POPC}) does not reveal a clearly identifiable trend, since D{sub POPC} increases upon addition of [bmim][Cl] and decreases in the [bmim][PF{sub 6}] case. Moreover, because of screening, the electrostatic signature of each bilayer is only moderately affected by the addition of RTIL ions in solution. The analysis of long wavelength fluctuations of the bilayers shows that RTIL sorption causes a general decrease of the lipid/water interfacial tension and bending rigidity, pointing to the destabilizing effect of RTILs on lipid bilayers.

  5. Trust makers, breakers and brokers: building trust in the Australian food system.

    Science.gov (United States)

    Wilson, Annabelle; Coveney, John; Henderson, Julie; Meyer, Samantha; Calnan, Michael; Caraher, Martin; Webb, Trevor; Elliott, Anthony; Ward, Paul

    2013-03-15

    The importance of consumer trust in the food supply has previously been identified, and dimensions of consumer trust in food-who they trust and the type of trust that they exhibit-has been explored. However, there is a lack of research about the mechanisms through which consumer trust in the food supply is developed, maintained, broken and repaired. This study seeks to address this gap by exploring if, and how, consumer trust in the food supply is considered by the media, food industry and governments when responding to food scares. The aim of the research is to develop models of trust building that can be implemented following food scares. Semi-structured interviews will be undertaken with media, public relations officials and policy makers in Australia, New Zealand and the United Kingdom. Participants will be recruited through purposive sampling and will be asked to discuss a hypothetical case study outlining a food incident, and any experiences of specific food scares. Models of trust development, maintenance and repair will be developed from interview data. Comment on these models will be sought from experts in food-related organizations through a Delphi study, where participants will be asked to consider the usefulness of the models. Participants' comments will be used to revise the models until consensus is reached on the suitability and usability of the models. This study will contribute to the literature about systems-based trust, and explore trust as a social and regulatory process. The protocol and results will be of interest and use to the food industry, food regulators, consumer advocate groups, media seeking to report food-related issues and policy makers concerned with public health and consumer health and well-being. This research represents an important contribution to the translation of the theoretical conceptualizations of trust into practical use in the context of food.

  6. Heterogeneous structure and solvation dynamics of DME/water binary mixtures: A combined spectroscopic and simulation investigation

    Science.gov (United States)

    Das Mahanta, Debasish; Rana, Debkumar; Patra, Animesh; Mukherjee, Biswaroop; Mitra, Rajib Kumar

    2018-05-01

    Water is often found in (micro)-heterogeneous environments and therefore it is necessary to understand their H-bonded network structure in such altered environments. We explore the structure and dynamics of water in its binary mixture with relatively less polar small biocompatible amphiphilic molecule 1,2-Dimethoxyethane (DME) by a combined spectroscopic and molecular dynamics (MD) simulation study. Picosecond (ps) resolved fluorescence spectroscopy using coumarin 500 as the fluorophore establishes a non-monotonic behaviour of the mixture. Simulation studies also explore the various possible H-bond formations between water and DME. The relative abundance of such different water species manifests the heterogeneity in the mixture.

  7. Classification and assessment of water bodies as adaptive structural measures for flood risk management planning.

    Science.gov (United States)

    McMinn, William R; Yang, Qinli; Scholz, Miklas

    2010-09-01

    Severe rainfall events have become increasingly common in Europe. Flood defence engineering works are highly capital intensive and can be limited by land availability, leaving land and communities exposed to repeated flooding. Any adaptive drainage structure must have engineered inlets and outlets that control the water level and the rate of release. In Scotland, there are a relatively high number of drinking water reservoirs (operated by Scottish Water), which fall within this defined category and could contribute to flood management control. Reducing the rate of runoff from the upper reaches of a catchment will reduce the volume and peak flows of flood events downstream, thus allowing flood defences to be reduced in size, decreasing the corresponding capital costs. A database of retention basins with flood control potential has been developed for Scotland. The research shows that the majority of small and former drinking water reservoirs are kept full and their spillways are continuously in operation. Utilising some of the available capacity to contribute to flood control could reduce the costs of complying with the EU Flood Directive. Furthermore, the application of a previously developed classification model for Baden in Germany for the Scottish data set showed a lower diversity for basins in Scotland due to less developed infrastructure. The principle value of this approach is a clear and unambiguous categorisation, based on standard variables, which can help to promote communication and understanding between stakeholders. 2010 Elsevier Ltd. All rights reserved.

  8. Implementation of the national desalination and water purification technology roadmap : structuring and directing the development of water supply solutions.

    Energy Technology Data Exchange (ETDEWEB)

    Price, Kevin M.; Dorsey, Zachary; Miller, G. Wade; Brady, Patrick Vane; Mulligan, Conrad; Rayburn, Chris

    2006-06-01

    In the United States, economic growth increasingly requires that greater volumes of freshwater be made available for new users, yet supplies of freshwater are already allocated to existing users. Currently, water for new users is made available through re-allocation of xisting water supplies-for example, by cities purchasing agricultural water rights. Water may also be made available through conservation efforts and, in some locales, through the development of ''new'' water from non-traditional sources such as the oceans, deep aquifer rackish groundwater, and water reuse.

  9. Fundamental Understanding of Crack Growth in Structural Components of Generation IV Supercritical Light Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Iouri I. Balachov; Takao Kobayashi; Francis Tanzella; Indira Jayaweera; Palitha Jayaweera; Petri Kinnunen; Martin Bojinov; Timo Saario

    2004-11-17

    This work contributes to the design of safe and economical Generation-IV Super-Critical Water Reactors (SCWRs) by providing a basis for selecting structural materials to ensure the functionality of in-vessel components during the entire service life. During the second year of the project, we completed electrochemical characterization of the oxide film properties and investigation of crack initiation and propagation for candidate structural materials steels under supercritical conditions. We ranked candidate alloys against their susceptibility to environmentally assisted degradation based on the in situ data measure with an SRI-designed controlled distance electrochemistry (CDE) arrangement. A correlation between measurable oxide film properties and susceptibility of austenitic steels to environmentally assisted degradation was observed experimentally. One of the major practical results of the present work is the experimentally proven ability of the economical CDE technique to supply in situ data for ranking candidate structural materials for Generation-IV SCRs. A potential use of the CDE arrangement developed ar SRI for building in situ sensors monitoring water chemistry in the heat transport circuit of Generation-IV SCWRs was evaluated and proved to be feasible.

  10. A new model for the structure function of integrated water vapor in turbulence

    International Nuclear Information System (INIS)

    Bobak, Justin P.; Ruf, Christopher S.

    1999-01-01

    Turbulent fluctuation of integrated water vapor in the troposphere is one of the major noise sources in radio interferometry. Processed integrated water vapor estimates from microwave radiometers colocated with interferometers have been used to set bounds on this uncertainty. The bound has been in the form of a calculated structure function, which is a measure of temporal or spatial decorrelation of fluctuations. In this paper a new model is presented for the estimation of the structure function in the absence of radiometer measurements. Using this model, the structure function can be estimated using measurements or estimates of a limited number of meteorological parameters. These parameters include boundary layer depth, surface heat and humidity fluxes, entrainment humidity flux, average virtual potential temperature in the boundary layer, and geostrophic wind speed. These parameters can be found or estimated from radiosonde and surface eddy correlation system data. The model is based on a framework of turbulence meteorology and provides excellent agreement when compared with state-of-the-art atmospheric turbulence simulations. Results of preliminary comparisons with ground truth show some excellent agreement, as well as some problems. The performance of the new model exceeds that of one current model. (c) 1999 American Geophysical Union

  11. Structural analysis of surface film on alloy 600 formed under environment of PWR primary water

    Energy Technology Data Exchange (ETDEWEB)

    Terachi, Takumi; Totsuka, Nobuo; Yamada, Takuyo; Nakagawa, Tomokazu [Inst. of Nuclear Safety System Inc., Mihama, Fukui (Japan); Deguchi, Hiroshi [Kansai Electric Power Co., Inc., Osaka (Japan); Horiuchi, Masaki; Oshitani, Masato [Kanden Kako Co., Ltd., Osaka (Japan)

    2002-09-01

    It has been shown by one of the present authors and so forth that PWSCC of alloy 600 relates to dissolved hydrogen concentration (DH) in water and oxide film structure. However, the mechanism of PWSCC has not been clear yet. Therefore, in order to investigate relationship between them, structural analysis of the oxide film formed under the environment of PWR primary water was carried out by using X-ray diffraction, the scanning electron microscope and the transmission electron microscope. Especially, to perform accurate analysis, the synchrotron orbital radiation with SPring-8 was tried to use for thin film X-ray diffraction measurement. From the results, observed are as follows: 1. the oxide film is mainly composed of NiO, under the condition without hydrogen. 2. In the environment of DH 2.75ppm, the oxide film forms thin spinel structures. 3. On the other hand, needlelike oxides are formed at DH 1ppm. For this reason, around 1ppm of DH there would be the boundary that stable NiO and spinel oxide generate, and it agrees with the peak range of the PWSCC susceptibility on hydrogen. From this, it is suggested that the boundary of NiO/spinel oxide affects the SCC susceptibility. (author)

  12. Three-Dimensional Simulation of Plasma Deformation During Contact Opening in a Circuit Breaker, Including the Analysis of Kink Instability and Sausage Instability

    International Nuclear Information System (INIS)

    Abbasi, Vahid; Gholami, Ahmad; Niayesh, Kaveh

    2012-01-01

    A three-dimensional (3-D) transient model has been developed to investigate plasma deformation driven by a magnetic field and its influence on arc stability in a circuit breaker. The 3-D distribution of electric current density is obtained from a current continuity equation along with the generalized Ohm's law; while the magnetic field induced by the current flowing through the arc column is calculated by the magnetic vector potential equation. When gas interacts with an arc column, fundamental factors, such as Ampere's law, Ohm's law, the turbulence model, transport equations of mass, momentum and energy of plasma flow, have to be coupled for analyzing the phenomenon. The coupled interactions between arc and plasma flow are described in the framework of time-dependent magnetohydrodynamic (MHD) equations in conjunction with a K-ε turbulence model. Simulations have been focused on sausage and kink instabilities in plasma (these phenomena are related to pinch effects and electromagnetic fields). The 3-D simulation reveals the relation between plasma deformation and instability phenomena, which affect arc stability during circuit breaker operation. Plasma deformation is the consequence of coupled interactions between the electromagnetic force and plasma flow described in simulations. (plasma technology)

  13. Post-arc current simulation based on measurement in vacuum circuit breaker with a one-dimensional particle-in-cell model

    Science.gov (United States)

    Jia, Shenli; Mo, Yongpeng; Shi, Zongqian; Li, Junliang; Wang, Lijun

    2017-10-01

    The post-arc dielectric recovery process has a decisive effect on the current interruption performance in a vacuum circuit breaker. The dissipation of residual plasma at the moment of current zero under the transient recovery voltage, which is the first stage of the post-arc dielectric recovery process and forms the post-arc current, has attracted many concerns. A one-dimensional particle-in-cell model is developed to simulate the measured post-arc current in the vacuum circuit breaker in this paper. At first, the parameters of the residual plasma are estimated roughly by the waveform of the post-arc current which is taken from measurements. After that, different components of the post-arc current, which are formed by the movement of charged particles in the residual plasma, are discussed. Then, the residual plasma density is adjusted according to the proportion of electrons and ions absorbed by the post-arc anode derived from the particle-in-cell simulation. After this adjustment, the post-arc current waveform obtained from the simulation is closer to that obtained from measurements.

  14. Forest canopy water fluxes can be estimated using canopy structure metrics derived from airborne light detection and ranging (LiDAR)

    DEFF Research Database (Denmark)

    Schumacher, Johannes; Christiansen, Jesper Riis

    2015-01-01

    Forests contribute to improve water quality, affect drinking water resources, and therefore influence water supply on a regional level. The forest canopy structure affects the retention of precipitation (Pr) in the canopy and hence the amount of water transferred to the forest floor termed canopy...... impacts water resources on a large scale in regions where forests play a major role in water resource management....

  15. Atomic structure of diamond {111} surfaces etched in oxygen water vapor

    International Nuclear Information System (INIS)

    Theije, F.K. de; Reedijk, M.F.; Arsic, J.; Enckevort, W.J.P. van; Vlieg, E.

    2001-01-01

    The atomic structure of the {111} diamond face after oxygen-water-vapor etching is determined using x-ray scattering. We find that a single dangling bond diamond {111} surface model, terminated by a full monolayer of -OH fits our data best. To explain the measurements it is necessary to add an ordered water layer on top of the -OH terminated surface. The vertical contraction of the surface cell and the distance between the oxygen atoms are generally in agreement with model calculations and results on similar systems. The OH termination is likely to be present during etching as well. This model experimentally confirms the atomic-scale mechanism we proposed previously for this etching system

  16. Complex networks from experimental horizontal oil–water flows: Community structure detection versus flow pattern discrimination

    International Nuclear Information System (INIS)

    Gao, Zhong-Ke; Fang, Peng-Cheng; Ding, Mei-Shuang; Yang, Dan; Jin, Ning-De

    2015-01-01

    We propose a complex network-based method to distinguish complex patterns arising from experimental horizontal oil–water two-phase flow. We first use the adaptive optimal kernel time–frequency representation (AOK TFR) to characterize flow pattern behaviors from the energy and frequency point of view. Then, we infer two-phase flow complex networks from experimental measurements and detect the community structures associated with flow patterns. The results suggest that the community detection in two-phase flow complex network allows objectively discriminating complex horizontal oil–water flow patterns, especially for the segregated and dispersed flow patterns, a task that existing method based on AOK TFR fails to work. - Highlights: • We combine time–frequency analysis and complex network to identify flow patterns. • We explore the transitional flow behaviors in terms of betweenness centrality. • Our analysis provides a novel way for recognizing complex flow patterns. • Broader applicability of our method is demonstrated and articulated

  17. Probing ion-specific effects on aqueous acetate solutions: Ion pairing versus water structure modifications

    Directory of Open Access Journals (Sweden)

    Tristan Petit

    2014-05-01

    Full Text Available The effect of monovalent cations (Li+, K+, NH4+, Na+ on the water structure in aqueous chloride and acetate solutions was characterized by oxygen K-edge X-ray absorption spectroscopy (XAS, X-ray emission spectroscopy, and resonant inelastic X-ray scattering (RIXS of a liquid microjet. We show ion- and counterion dependent effects on the emission spectra of the oxygen K-edge, which we attribute to modifications of the hydrogen bond network of water. For acetates, ion pairing with carboxylates was also probed selectively by XAS and RIXS. We correlate our experimental results to speciation data and to the salting-out properties of the cations.

  18. Relating soil microbial activity to water content and tillage-induced differences in soil structure

    DEFF Research Database (Denmark)

    Schjønning, Per; Thomsen, Ingrid Kaag; Petersen, Søren O

    2011-01-01

    Several studies have identified optima in soil water content for aerobic microbial activity, and this has been ascribed to a balance between gas and solute diffusivity as limiting processes. We investigated the role of soil structure, as created by different tillage practices (moldboard ploughing......, MP, or shallow tillage, ST), in regulating net nitrification, applied here as an index of aerobic microbial activity. Intact soil cores were collected at 0–4 and 14–18 cm depth from a fine sandy (SAND) and a loamy (LOAM) soil. The cores were drained to one of seven matric potentials ranging from − 15...... content to a maximum and then decreased. This relationship was modelled with a second order polynomium. Model parameters did not show any tillage effect on the optimum water content, but the optimum coincided with a lower matric potential in ST (SAND: − 140 to –197 hPa; LOAM: − 37 to − 65 hPa) than in MP...

  19. 1st International Conference on Hydraulic Design in Water Resources Engineering : Channels and Channel Control Structures

    CERN Document Server

    1984-01-01

    The development of water resources has proceeded at an amazing speed around the world in the last few decades. The hydraulic engineer has played his part: in constructing much larger artificial channels than ever before, larger and more sophisticated control structures, and systems of irrigation, drainage and water supply channels in which the flow by its nature is complex and unsteady requiring computer-based techniques at both the design and operation stage. It seemed appropriate to look briefly at some of the developments in hydraulic design resulting from this situation. Hence the idea of the Conference was formed. The Proceedings of the Conference show that hydraulic engineers have been able to acquire a very substantial base of design capability from the experience of the period referred to. The most outstanding development to have occurred is in the combination of physical and mathematical modelling, which in hydraulic engineering has followed a parallel path to that in other branches of engineering sc...

  20. The structure of a lipid-water lamellar phase containing two types of lipid monolayers

    International Nuclear Information System (INIS)

    Ranck, J.L.; Luzzati, V.; Zaccai, G.

    1980-01-01

    One lamellar phase, observed in the mitochondrial lipids-water system at low temperature (ca 253 K) and at low water content (ca 15%), contains four lipid monolayers in its unit cell, two of type α and two of type β. Previous X-ray scattering studies of this phase led to an ambiguity: the phase could contain either two homogeneous bilayers, one α and one β, or two mixed bilayers, each formed by an α and a β monolayer. A solution to this problem was sought in a neutron scattering study as a function of the D 2 O/H 2 O ratio. Because of limited resolution, straightforward analysis of the neutron scattering data leads also to ambiguous results. Using a more sophisticated analysis based upon the zeroth- and second-order moments of the Patterson peaks relevant to the exchangeable components, it is shown that the weight of the evidence is in favour of a structure containing mixed bilayers. (Auth.)

  1. Coordination structure of adsorbed Zn(II) at Water-TiO2 interfaces

    Energy Technology Data Exchange (ETDEWEB)

    He, G.; Pan, G.; Zhang, M.; Waychunas, G.A.

    2011-01-15

    The local structure of aqueous metal ions on solid surfaces is central to understanding many chemical and biological processes in soil and aquatic environments. Here, the local coordination structure of hydrated Zn(II) at water-TiO{sub 2} interfaces was identified by extended X-ray absorption fine structure (EXAFS) and X-ray absorption near-edge structure (XANES) spectroscopy combined with density functional theory (DFT) calculations. A nonintegral coordination number of average {approx}4.5 O atoms around a central Zn atom was obtained by EXAFS analysis. DFT calculations indicated that this coordination structure was consistent with the mixture of 4-coordinated bidentate binuclear (BB) and 5-coordinated bidentate mononuclear (BM) metastable equilibrium adsorption (MEA) states. The BB complex has 4-coordinated Zn, while the monodentate mononuclear (MM) complex has 6-coordinated Zn, and a 5-coordinated adsorbed Zn was found in the BM adsorption mode. DFT calculated energies showed that the lower-coordinated BB and BM modes were thermodynamically more favorable than the higher-coordinated MM MEA state. The experimentally observed XANES fingerprinting provided additional direct spectral evidence of 4- and 5-coordinated Zn-O modes. The overall spectral and computational evidence indicated that Zn(II) can occur in 4-, 5-, and 6-oxygen coordinated sites in different MEA states due to steric hindrance effects, and the coexistence of different MEA states formed the multiple coordination environments.

  2. Molecular dynamics simulations of structural transformation of perfluorooctane sulfonate (PFOS) at water/rutile interfaces.

    Science.gov (United States)

    He, Guangzhi; Zhang, Meiyi; Zhou, Qin; Pan, Gang

    2015-09-01

    Concentration and salinity conditions are the dominant environmental factors affecting the behavior of perfluorinated compounds (PFCs) on the surfaces of a variety of solid matrices (suspended particles, sediments, and natural minerals). However, the mechanism has not yet been examined at molecular scales. Here, the structural transformation of perfluorooctane sulfonate (PFOS) at water/rutile interfaces induced by changes of the concentration level of PFOS and salt condition was investigated using molecular dynamics (MD) simulations. At low and intermediate concentrations all PFOS molecules directly interacted with the rutile (110) surface mainly by the sulfonate headgroups through electrostatic attraction, yielding a typical monolayer structure. As the concentration of PFOS increased, the molecules aggregated in a complex multi-layered structure, where an irregular assembling configuration was adsorbed on the monolayer structure by the van der Waals interactions between the perfluoroalkyl chains. When adding CaCl2 to the system, the multi-layered structure changed to a monolayer again, indicating that the addition of CaCl2 enhanced the critical concentration value to yield PFOS multilayer assemblies. The divalent Ca(2+) substituted for monovalent K(+) as the bridging counterion in PFOS adsorption. MD simulation may trigger wide applications in study of perfluorinated compounds (PFCs) from atomic/molecular scale. Copyright © 2015 Elsevier Ltd. All rights reserved.

  3. Smart nanogels at the air/water interface: structural studies by neutron reflectivity

    Science.gov (United States)

    Zielińska, Katarzyna; Sun, Huihui; Campbell, Richard A.; Zarbakhsh, Ali; Resmini, Marina

    2016-02-01

    The development of effective transdermal drug delivery systems based on nanosized polymers requires a better understanding of the behaviour of such nanomaterials at interfaces. N-Isopropylacrylamide-based nanogels synthesized with different percentages of N,N'-methylenebisacrylamide as cross-linker, ranging from 10 to 30%, were characterized at physiological temperature at the air/water interface, using neutron reflectivity (NR), with isotopic contrast variation, and surface tension measurements; this allowed us to resolve the adsorbed amount and the volume fraction of nanogels at the interface. A large conformational change for the nanogels results in strong deformations at the interface. As the percentage of cross-linker incorporated in the nanogels becomes higher, more rigid matrices are obtained, although less deformed, and the amount of adsorbed nanogels is increased. The data provide the first experimental evidence of structural changes of nanogels as a function of the degree of cross-linking at the air/water interface.The development of effective transdermal drug delivery systems based on nanosized polymers requires a better understanding of the behaviour of such nanomaterials at interfaces. N-Isopropylacrylamide-based nanogels synthesized with different percentages of N,N'-methylenebisacrylamide as cross-linker, ranging from 10 to 30%, were characterized at physiological temperature at the air/water interface, using neutron reflectivity (NR), with isotopic contrast variation, and surface tension measurements; this allowed us to resolve the adsorbed amount and the volume fraction of nanogels at the interface. A large conformational change for the nanogels results in strong deformations at the interface. As the percentage of cross-linker incorporated in the nanogels becomes higher, more rigid matrices are obtained, although less deformed, and the amount of adsorbed nanogels is increased. The data provide the first experimental evidence of structural changes

  4. Diversity and structure of Chironomidae communities in relation to water quality differences in the Swartkops River

    Science.gov (United States)

    Odume, O. N.; Muller, W. J.

    The Swartkops River is an important freshwater ecosystem in South Africa. But owing to its location, it suffers varying degrees of human induced impacts which include industrial and domestic effluent discharges, deforestation as well as agricultural land use which have negatively impacted on the water quality. Diversity and community composition of aquatic insects are frequently used to assess environmental water quality status. Chironomids occupy extremely varied biotopes. Their extraordinary ecological range and environmental sensitivity make them particularly useful for assessing and interpreting changes in water quality of aquatic ecosystems. The community structure of chironomid larvae was investigated at four sites in the Swartkops River and effects of different chemical and physical variables on their distribution were explored. Chironomid larvae were collected using the South African Scoring System version 5 (SASS5) protocol. A total of 26 taxa from four sampling sites in the Swartkops River were identified. Margalef’s species richness index, equitability, Shannon and Simpson diversity indices were highest at site 1 (reference site). The downstream sites contained 6-20 taxa compared to the 25 taxa at site 1. Site 1 was characterised by the subfamilies Orthocladiinae, Tanypodinae and the tribe Tanytarsini while the impacted sites were characterised by Orthocladiinae and Chironomini. Chironomus spp., Dirotendipes sp., Kiefferulus sp. and Tanypus sp. seemed to be tolerant to pollution, occurring in high abundance at sites 2, 3 and 4. In contrast, Polypedilum sp., Tanytarsus sp., Orthocladius sp., Cricotopus spp. and Ablabesmyia sp. appeared to be more sensitive taxa, being less common at the impacted sites (sites 2, 3 and 4). Five days biochemical oxygen demand, dissolved oxygen, electrical conductivity, orthophosphate-phosphorus and total inorganic nitrogen were among the important variables that determine the observed chironomid community structure

  5. New era / new solutions: The role of alternative tariff structures in water supply projects.

    Science.gov (United States)

    Pinto, F Silva; Marques, R Cunha

    2017-12-01

    Water utilities face different challenges that may force them to seek prioritized objectives. When doing so, particular projects may have to be developed, being important to understand their impact on water tariffs, and thus, on customers. Such consequences may bear an increased relevance in cases stressed with, e.g., resource scarcity, poverty, and the need for infrastructure investments. The resulting cost and revenue variability demand a comprehensive study. If the first may require a stochastic modeling (in major cost components) in order to consider its inherent uncertainty, the second needs to be modeled following context-specific objectives set by the relevant stakeholders. The solutions achieved will likely promote distinct revenue sources, as well as diversified water tariff structures. A multi-objective optimization model (i.e., a Framework for Suitable Prices) is built to deal with those diversified requirements (e.g., stochastic energy costs, affordability, cost recovery, or administrative simplicity). The model is solved through achievement scalarizing functions with several weighting coefficients for a reference point, so as to provide a significant perception of possible revenue options (and their impact) to the decision makers. The proposed method is applied to a case study, Boa Vista Island in Cabo Verde, in which the background characteristics, namely water sources availability (e.g., the adoption of desalination technologies), economic development and other contextual factors were considered. The key role of tariff structure selection is displayed, instead of assuming it a priori, giving important insights regarding project feasibility. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. A surprisingly simple correlation between the classical and quantum structural networks in liquid water

    Science.gov (United States)

    Hamm, Peter; Fanourgakis, George S.; Xantheas, Sotiris S.

    2017-08-01

    Nuclear quantum effects in liquid water have profound implications for several of its macroscopic properties related to the structure, dynamics, spectroscopy, and transport. Although several of water's macroscopic properties can be reproduced by classical descriptions of the nuclei using interaction potentials effectively parameterized for a narrow range of its phase diagram, a proper account of the nuclear quantum effects is required to ensure that the underlying molecular interactions are transferable across a wide temperature range covering different regions of that diagram. When performing an analysis of the hydrogen-bonded structural networks in liquid water resulting from the classical (class) and quantum (qm) descriptions of the nuclei with two interaction potentials that are at the two opposite ends of the range in describing quantum effects, namely the flexible, pair-wise additive q-TIP4P/F, and the flexible, polarizable TTM3-F, we found that the (class) and (qm) results can be superimposed over the temperature range T = 250-350 K using a surprisingly simple, linear scaling of the two temperatures according to T(qm) = α T(class) + ΔT, where α = 0.99 and ΔT = -6 K for q-TIP4P/F and α = 1.24 and ΔT = -64 K for TTM3-F. This simple relationship suggests that the structural networks resulting from the quantum and classical treatment of the nuclei with those two very different interaction potentials are essentially similar to each other over this extended temperature range once a model-dependent linear temperature scaling law is applied.

  7. The interplay between dynamic heterogeneities and structure of bulk liquid water: A molecular dynamics simulation study

    Energy Technology Data Exchange (ETDEWEB)

    Demontis, Pierfranco; Suffritti, Giuseppe B. [Dipartimento di Chimica e Farmacia, Università degli studi di Sassari, Sassari (Italy); Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM), Unità di ricerca di Sassari, Via Vienna, 2, I-07100 Sassari (Italy); Gulín-González, Jorge [Grupo de Matemática y Física Computacionales, Universidad de las Ciencias Informáticas (UCI), Carretera a San Antonio de los Baños, Km 21/2, La Lisa, La Habana (Cuba); Masia, Marco [Dipartimento di Chimica e Farmacia, Università degli studi di Sassari, Sassari (Italy); Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM), Unità di ricerca di Sassari, Via Vienna, 2, I-07100 Sassari (Italy); Istituto Officina dei Materiali del CNR, UOS SLACS, Via Vienna 2, 07100 Sassari (Italy); Sant, Marco [Dipartimento di Chimica e Farmacia, Università degli studi di Sassari, Sassari (Italy)

    2015-06-28

    In order to study the interplay between dynamical heterogeneities and structural properties of bulk liquid water in the temperature range 130–350 K, thus including the supercooled regime, we use the explicit trend of the distribution functions of some molecular properties, namely, the rotational relaxation constants, the atomic mean-square displacements, the relaxation of the cross correlation functions between the linear and squared displacements of H and O atoms of each molecule, the tetrahedral order parameter q and, finally, the number of nearest neighbors (NNs) and of hydrogen bonds (HBs) per molecule. Two different potentials are considered: TIP4P-Ew and a model developed in this laboratory for the study of nanoconfined water. The results are similar for the dynamical properties, but are markedly different for the structural characteristics. In particular, for temperatures higher than that of the dynamic crossover between “fragile” (at higher temperatures) and “strong” (at lower temperatures) liquid behaviors detected around 207 K, the rotational relaxation of supercooled water appears to be remarkably homogeneous. However, the structural parameters (number of NNs and of HBs, as well as q) do not show homogeneous distributions, and these distributions are different for the two water models. Another dynamic crossover between “fragile” (at lower temperatures) and “strong” (at higher temperatures) liquid behaviors, corresponding to the one found experimentally at T{sup ∗} ∼ 315 ± 5 K, was spotted at T{sup ∗} ∼ 283 K and T{sup ∗} ∼ 276 K for the TIP4P-Ew and the model developed in this laboratory, respectively. It was detected from the trend of Arrhenius plots of dynamic quantities and from the onset of a further heterogeneity in the rotational relaxation. To our best knowledge, it is the first time that this dynamical crossover is detected in computer simulations of bulk water. On the basis of the simulation results, the possible

  8. Effects of some structural materials on the reactivity and flux distributions in a pressurised water reactor

    International Nuclear Information System (INIS)

    Mondal, A.M.W.; Mannan, M.A.

    1983-01-01

    The effect of the structural materials of the guide tubes, spacer grids and the shroud on the reactivity and the flux distribution of a Pressurised Water Reactor (PWR) has been studied. Group constants of different cells of guide tubes, spacer grids, shroud and the fuel have been calculated using the cell codes LEOPARD, PANTHER and METHUSELAH. Core calculations have been performed using the diffusion code EQUIPOISE. It has been found for a PWR of 1300 MWe of Kraftwork Union design for Iron that the total change in reactivity due to the presence of guide tubes, spacer grids and the shroud is about -2.48x10 -2 . (author)

  9. On the influence of molecular structure on the conductivity of electrolyte solutions - sodium nitrate in water

    Directory of Open Access Journals (Sweden)

    H. Krienke

    2013-01-01

    Full Text Available Theoretical calculations of the conductivity of sodium nitrate in water are presented and compared with experimental measurements. The method of direct correlation force in the framework of the interionic theory is used for the calculation of transport properties in connection with the associative mean spherical approximation (AMSA. The effective interactions between ions in solutions are derived with the help of Monte Carlo and Molecular Dynamics calculations on the Born-Oppenheimer level. This work is based on earlier theoretical and experimental studies of the structure of concentrated aqueous sodium nitrate solutions.

  10. Structural elements of collapses in shallow water flows with horizontally nonuniform density

    Energy Technology Data Exchange (ETDEWEB)

    Goncharov, V. P., E-mail: v.goncharov@rambler.ru [Russian Academy of Sciences, Obukhov Institute of Atmospheric Physics (Russian Federation); Pavlov, V. I., E-mail: Vadim.Pavlov@univ-lille1.fr [Universite de Lille 1, UFR de Mathematiques Pures et Appliquees-LML UMR 8107 (France)

    2013-10-15

    The mechanisms and structural elements of instability whose evolution results in the occurrence of the collapse are studied in the scope of the rotating shallow water model with a horizontally nonuniform density. The diagram stability based on the integral collapse criterion is suggested to explain system behavior in the space of constants of motion. Analysis of the instability shows that two collapse scenarios are possible. One scenario implies anisotropic collapse during which the contact area of a collapsing drop-like fragment with the bottom contracts into a rotating segment. The other implies isotropic contraction of the area into a point.

  11. Simultaneous improvement in productivity, water use, and albedo through crop structural modification.

    Science.gov (United States)

    Drewry, Darren T; Kumar, Praveen; Long, Stephen P

    2014-06-01

    Spanning 15% of the global ice-free terrestrial surface, agricultural lands provide an immense and near-term opportunity to address climate change, food, and water security challenges. Through the computationally informed breeding of canopy structural traits away from those of modern cultivars, we show that solutions exist that increase productivity and water use efficiency, while increasing land-surface reflectivity to offset greenhouse gas warming. Plants have evolved to maximize capture of radiation in the upper leaves, thus shading competitors. While important for survival in the wild, this is suboptimal in monoculture crop fields for maximizing productivity and other biogeophysical services. Crop progenitors evolved over the last 25 million years in an atmosphere with less than half the [CO2] projected for 2050. By altering leaf photosynthetic rates, rising [CO2] and temperature may also alter the optimal canopy form. Here using soybean, the world's most important protein crop, as an example we show by applying optimization routines to a micrometeorological leaf canopy model linked to a steady-state model of photosynthesis, that significant gains in production, water use, and reflectivity are possible with no additional demand on resources. By modifying total canopy leaf area, its vertical profile and angular distribution, and shortwave radiation reflectivity, all traits available in most major crop germplasm collections, increases in productivity (7%) are possible with no change in water use or albedo. Alternatively, improvements in water use (13%) or albedo (34%) can likewise be made with no loss of productivity, under Corn Belt climate conditions. © 2014 California Institute of Technology. Government sponsorship acknowledged.

  12. Instability Mechanisms of Water-in-Oil Nanoemulsions with Phospholipids: Temporal and Morphological Structures.

    Science.gov (United States)

    Sommerling, Jan-Hendrik; de Matos, Maria B C; Hildebrandt, Ellen; Dessy, Alberto; Kok, Robbert Jan; Nirschl, Hermann; Leneweit, Gero

    2018-01-16

    Many food preparations, pharmaceuticals, and cosmetics use water-in-oil (W/O) emulsions stabilized by phospholipids. Moreover, recent technological developments try to produce liposomes or lipid coated capsules from W/O emulsions, but are faced with colloidal instabilities. To explore these instability mechanisms, emulsification by sonication was applied in three cycles, and the sample stability was studied for 3 h after each cycle. Clearly identifiable temporal structures of instability provide evidence about the emulsion morphology: an initial regime of about 10 min is shown to be governed by coalescence after which Ostwald ripening dominates. Transport via molecular diffusion in Ostwald ripening is commonly based on the mutual solubility of the two phases and is therefore prohibited in emulsions composed of immiscible phases. However, in the case of water in oil emulsified by phospholipids, these form water-loaded reverse micelles in oil, which enable Ostwald ripening despite the low solubility of water in oil, as is shown for squalene. As is proved for the phospholipid dipalmitoylphosphatidylcholine (DPPC), concentrations below the critical aggregation concentration (CAC) form monolayers at the interfaces and smaller droplet sizes. In contrast, phospholipid concentrations above the CAC create complex multilayers at the interface with larger droplet sizes. The key factors for stable W/O emulsions in classical or innovative applications are first, the minimization of the phospholipids' capacity to form reversed micelles, and second, the adaption of the initial phospholipid concentration to the water content to enable an optimized coverage of phospholipids at the interfaces for the intended drop size.

  13. Corrosion resistance of structural material AlMg-2 in water following heat treatment and cooling

    International Nuclear Information System (INIS)

    Maman Kartaman A; Djoko Kisworo; Dedi Hariyadi; Sigit

    2005-01-01

    Corrosion tests of structural material AlMg-2 in water were carried out using autoclave in order to study the effects of heat treatment on the corrosion resistance of the material. Prior to the tests, the samples were heat-treated at temperatures of 90, 200, 300 and 500 °C and cooled in air, sand and water. The corrosion tests were conducted in water at temperature of 150 °C for 250 hours. The results showed that AlMg-2 samples were corroded although the increase of mass gain was relatively small. Heat treatment from 90 to 500 °C in sand cooling media resulted in an increase of mass gain despite that at 300 °C the increase was less than those at 200 °C and 500 °C. For water cooling media in the temperature range of 90 to 200 °C, the mass gain increased from 0.1854 g/cm 2 to 2.1204 g/cm 2 although after 200 °C it decreased to 1.8207 g/cm 2 and 1.6779 g/cm 2 respectively. For air cooling media, the mass gain was relatively constant. Based on the experiment results, it can be concluded that heat treatment and cooling did not significantly influence the corrosion resistance of material AlMg-2. The passive film Al 2 O 3 on the surface was able to protect the inner surface from further corrosion. Water media with pH range from 4 – 9 did not cause damage to passive layer formed. (author)

  14. Systematic comparison of crystalline and amorphous phases: Charting the landscape of water structures and transformations

    International Nuclear Information System (INIS)

    Pietrucci, Fabio; Martoňák, Roman

    2015-01-01

    Systematically resolving different crystalline phases starting from the atomic positions, a mandatory step in algorithms for the prediction of structures or for the simulation of phase transitions, can be a non-trivial task. Extending to amorphous phases and liquids which lack the discrete symmetries, the problem becomes even more difficult, involving subtle topological differences at medium range that, however, are crucial to the physico-chemical and spectroscopic properties of the corresponding materials. Typically, system-tailored order parameters are devised, like global or local symmetry indicators, ring populations, etc. We show that a recently introduced metric provides a simple and general solution to this intricate problem. In particular, we demonstrate that a map can be traced displaying distances among water phases, including crystalline as well as amorphous states and the liquid, consistently with experimental knowledge in terms of phase diagram, structural features, and preparation routes

  15. Light water reactor fuel analysis code FEMAXI-IV(Ver.2). Detailed structure and user's manual

    International Nuclear Information System (INIS)

    Suzuki, Motoe; Saitou, Hiroaki.

    1997-11-01

    A light water reactor fuel behavior analysis code FEMAXI-IV(Ver.2) was developed as an improved version of FEMAXI-IV. Development of FEMAXI-IV has been already finished in 1992, though a detailed structure and input manual of the code have not been open to users yet. Here, the basic theories and structure, the models and numerical solutions applied to FEMAXI-IV(Ver.2), and the material properties adopted in the code are described in detail. In FEMAXI-IV(Ver.2), programming bugs in previous FEMAXI-IV were eliminated, renewal of the pellet thermal conductivity was performed, and a model of thermal-stress restraint on FP gas release was incorporated. For facilitation of effective and wide-ranging application of the code, methods of input/output of the code are also described in detail, and sample output is included. (author)

  16. Flow structure of conical distributed multiple gas jets injected into a water chamber

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Jiajun; Yu, Yonggang [Nanjing University of Science and Technology, Nanjing (China)

    2017-04-15

    Based on an underwater gun firing project, a mock bullet with several holes on the head was designed and experimented to observe the combustion gas injected into a cylindrical water chamber through this mock bullet. The combustion gas jets contain one vertical central jet and 4 to 8 slant lateral jets. A high speed camera system was used to record the expansion of gas jets in the experimental study. In numerical simulations, the Euler two-fluid model and volume of fluid method were adopted to describe the gas-liquid flow. The results show the backflow zone in lateral jet is the main factor influencing the gas-liquid turbulent mixing in downstream. On cross sections, the gas volume fraction increased with time but the growth rate decreased. With a change of nozzle structure, the gas fraction was more affected than the shock structure.

  17. Standard Test Method for Water Absorption of Core Materials for Structural Sandwich Constructions

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2001-01-01

    1.1 This test method covers the determination of the relative amount of water absorption by various types of structural core materials when immersed or in a high relative humidity environment. This test method is intended to apply to only structural core materials; honeycomb, foam, and balsa wood. 1.2 The values stated in SI units are to be regarded as the standard. The inch-pound units given may be approximate. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  18. Structural dynamics of supercooled water from quasielastic neutron scattering and molecular simulations.

    Science.gov (United States)

    Qvist, Johan; Schober, Helmut; Halle, Bertil

    2011-04-14

    One of the outstanding challenges presented by liquid water is to understand how molecules can move on a picosecond time scale despite being incorporated in a three-dimensional network of relatively strong H-bonds. This challenge is exacerbated in the supercooled state, where the dramatic slowing down of structural dynamics is reminiscent of the, equally poorly understood, generic behavior of liquids near the glass transition temperature. By probing single-molecule dynamics on a wide range of time and length scales, quasielastic neutron scattering (QENS) can potentially reveal the mechanistic details of water's structural dynamics, but because of interpretational ambiguities this potential has not been fully realized. To resolve these issues, we present here an extensive set of high-quality QENS data from water in the range 253-293 K and a corresponding set of molecular dynamics (MD) simulations to facilitate and validate the interpretation. Using a model-free approach, we analyze the QENS data in terms of two motional components. Based on the dynamical clustering observed in MD trajectories, we identify these components with two distinct types of structural dynamics: picosecond local (L) structural fluctuations within dynamical basins and slower interbasin jumps (J). The Q-dependence of the dominant QENS component, associated with J dynamics, can be quantitatively rationalized with a continuous-time random walk (CTRW) model with an apparent jump length that depends on low-order moments of the jump length and waiting time distributions. Using a simple coarse-graining algorithm to quantitatively identify dynamical basins, we map the newtonian MD trajectory on a CTRW trajectory, from which the jump length and waiting time distributions are computed. The jump length distribution is gaussian and the rms jump length increases from 1.5 to 1.9 Å as the temperature increases from 253 to 293 K. The rms basin radius increases from 0.71 to 0.75 Å over the same range. The

  19. Multi-scale experimental and numerical study of the structure and the dynamics of water confined in clay minerals

    International Nuclear Information System (INIS)

    Guillaud, Emmanuel Bertrand

    2017-01-01

    Clay are complex minerals with a multi-scale porosity and a remarkable ability to swell under humid atmosphere. These materials have many applications in catalysis, waste management, construction industry... However, the properties of confined water are still not fully understood, due in particular to the complexity of water itself. The aim of this work is, using mainly molecular simulations and vibrational spectroscopy, to understand the structure and the dynamics of water confined in clay minerals. To evaluate the accuracy of numerical models to describe water confined in clay minerals, and to understand the origin of its structural and dynamical properties, a large part of the work was devoted to the building blocks of clays: pure bulk water, water at the surface of a solid, and salt water. To this extent, the viscoelastic properties of water from the deeply supercooled regime to the boiling temperature were investigated using classical molecular dynamics. The evolution of the friction properties of water on a prototypical solid surface was also analyzed, and the accuracy of ab initio approaches and empirical salt models was studied. In a second part, those results were confronted to the properties of water confined in clay minerals at low and room temperature, studied both experimentally and numerically. Experimental work consisted mostly in extensive far- and -mid infrared absorption spectrometry measurements, whereas numerical work mainly consisted in empirical molecular dynamics simulations. Especially, the existence of confinement- or temperature-induced phase transitions of confined water was investigated. (author)

  20. Efficiency of temporary storage of geothermal waters in a lake system: Monitoring the changes of water quality and bacterial community structures.

    Science.gov (United States)

    Szirányi, Barbara; Krett, Gergely; Kosáros, Tünde; Janurik, Endre; Pekár, Ferenc; Márialigeti, Károly; Borsodi, Andrea K

    2017-12-01

    Disposal of used geothermal waters in Hungary often means temporary storage in reservoir lakes to reduce temperature and improve water quality. In this study, the physical and chemical properties and changes in the bacterial community structure of a reservoir lake system in southeast region of Hungary were monitored and compared through 2 years, respectively. The values of biological oxygen demand, concentrations of ammonium ion, total inorganic nitrogen, total phosphorous, and total phenol decreased, whereas oxygen saturation, total organic nitrogen, pH, and conductivity increased during the storage period. Bacterial community structure of water and sediment samples was compared by denaturing gradient gel electrophoresis (DGGE) following the amplification of the 16S rRNA gene. According to the DGGE patterns, greater seasonal than spatial differences of bacterial communities were revealed in both water and sediment of the lakes. Representatives of the genera Arthrospira and Anabaenopsis (cyanobacteria) were identified as permanent and dominant members of the bacterial communities.

  1. Strong cooperative effect of oppositely charged surfactant mixtures on their adsorption and packing at the air-water interface and interfacial water structure.

    Science.gov (United States)

    Nguyen, Khoi T; Nguyen, Tuan D; Nguyen, Anh V

    2014-06-24

    Remarkable adsorption enhancement and packing of dilute mixtures of water-soluble oppositely-charged surfactants, sodium dodecyl sulfate (SDS) and dodecyl amine hydrochloride (DAH), at the air-water interface were observed by using sum frequency generation spectroscopy and tensiometry. The interfacial water structure was also observed to be significantly influenced by the SDS-DAH mixtures, differently from the synergy of the single surfactants. Most strikingly, the obtained spectroscopic evidence suggests that the interfacial hydrophobic alkyl chains of the binary mixtures assemble differently from those of single surfactants. This study highlights the significance of the cooperative interaction between the headgroups of oppositely charged binary surfactant systems and subsequently provides some insightful observations about the molecular structure of the air-aqueous interfacial water molecules and, more importantly, about the packing nature of the surfactant hydrophobic chains of dilute SDS-DAH mixtures of concentration below 1% of the CMC.

  2. Wetted-region structure in horizontal unsaturated fractures: Water entry through the surrounding porous matrix

    International Nuclear Information System (INIS)

    Glass, R.J.; Norton, D.L.

    1991-01-01

    Small-scale processes that influence wetted structure within the plane of a horizontal fracture as the fracture wets or drains through the matrix are investigated. Our approach integrates both aperture-scale modeling and physical experimentation. Several types of aperture-scale models have been defined and implemented. A series of physical experimental systems that allow us to measure wetted-region structure as a function of system parameters and water pressure head in analogue fractures also have been designed. In our preliminary proof-of-concept experiment, hysteresis is clearly evident in the measured saturation/pressure relation, as is the process of air entrapment, which causes a reduction in the connected areas between blocks and the wetted region available for flow in the plane of the fracture. A percolation threshold where the system is quickly spanned, allowing fluid conduction in the fracture plane, is observed which is analogous to that found in the aperture-scale models. A fractal wetted and entrapped-region structure is suggested by both experiment and modeling. This structure implies that flow tortuosity for both flow in the fracture and for inter-block fluid transfer is a scale-dependent function of pressure head

  3. OECD - HRP Summer School on Light Water Reactor Structural Materials. August 26th - 30th, 2002

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    In cooperation with the OECD Nuclear Energy Agency (NEA), the Halden Reactor Project organised a Summer School on Light Water Reactor Structural Materials in the period August 26 - 30, 2002. The summer school was primarily intended for people who wanted to become acquainted with materials-related subjects and issues without being experts. It is especially hoped that the summer school served to transfer knowledge to the ''young generation'' in the field of nuclear. Experts from Halden Project member organisations were solicited for the following programme: (1) Overview of The Nuclear Community and Current Issues, (2) Regulatory Framework for Ensuring Structural Integrity, (3) Non-Destructive Testing for Detection of Cracks, (4) Part I - Basics of Radiation and Radiation Damage, (5) Part II - Radiation Effects on Reactor Internal Materials, (6) Water Chemistry and Radiolysis Effects in LWRs, (7) PWR and Fast Breeder Reactor Internals, (8) PWR and Fast Breeder Reactor Internals, (9) Secondary Side Corrosion Cracking of PWR Steam Generator Tubes, (10) BWR Materials and Their Interaction with the Environment, (11) Radiation Damage in Reactor Pressure Vessels.

  4. The Influence of Fluorination on Structure of the Trifluoroacetonitrile Water Complex

    Science.gov (United States)

    Lin, Wei; Wu, Anan; Lu, Xin; Obenchain, Daniel A.; Novick, Stewart E.

    2015-06-01

    Acetonitrile, CH_3CN, and trifluoroacetonitrile, CF_3CN, are symmetric tops. In a recent study of the rotational spectrum of the acetonitrile and water complex, it was observed that the structure was also an effective symmetric top, with the external hydrogen freely rotating about the O-H bond aligned towards the nitrogen of the cyanide of CH_3CN. Unlike the CH_3CN-H_2O complex, the CH_3CN-Ar and CF_3CN-Ar complexes were observed to be asymmetric tops. Having a series of symmetric and asymmetric top complexes of acetonitrile and trifluoracetonitrile for comparison, we report the rotational spectrum of the weakly bound complex between trifluoroacetonitrile and water. Rotational constants and quadrupole coupling constants will be presented, and the structure of CF_3CN-H_2O will be revealed. Lovas, F.J.; Sobhanadri, J. Microwave rotational spectral study of CH_3CN-H_2O and Ar-CH_3CN. J. Mol. Spetrosc. 2015, 307, 59-64. SPOILER ALERT: It's an asymmetric top.

  5. OECD - HRP Summer School on Light Water Reactor Structural Materials. August 26th - 30th, 2002

    International Nuclear Information System (INIS)

    2002-01-01

    In cooperation with the OECD Nuclear Energy Agency (NEA), the Halden Reactor Project organised a Summer School on Light Water Reactor Structural Materials in the period August 26 - 30, 2002. The summer school was primarily intended for people who wanted to become acquainted with materials-related subjects and issues without being experts. It is especially hoped that the summer school served to transfer knowledge to the ''young generation'' in the field of nuclear. Experts from Halden Project member organisations were solicited for the following programme: (1) Overview of The Nuclear Community and Current Issues, (2) Regulatory Framework for Ensuring Structural Integrity, (3) Non-Destructive Testing for Detection of Cracks, (4) Part I - Basics of Radiation and Radiation Damage, (5) Part II - Radiation Effects on Reactor Internal Materials, (6) Water Chemistry and Radiolysis Effects in LWRs, (7) PWR and Fast Breeder Reactor Internals, (8) PWR and Fast Breeder Reactor Internals, (9) Secondary Side Corrosion Cracking of PWR Steam Generator Tubes, (10) BWR Materials and Their Interaction with the Environment, (11) Radiation Damage in Reactor Pressure Vessels

  6. Communication: Relationship between local structure and the stability of water in hydrophobic confinement

    Science.gov (United States)

    Altabet, Y. Elia; Debenedetti, Pablo G.

    2017-12-01

    Liquid water confined between nanoscale hydrophobic objects can become metastable with respect to its vapor at nanoscale separations. While the separations are only several molecular diameters, macroscopic theories are often invoked to interpret the thermodynamics and kinetics of water under confinement. We perform detailed rate and free energy calculations via molecular simulations in order to assess the dependence of the rate of evaporation, free energy barriers, and free energy differences between confined liquid and vapor upon object separation and compare them to the relevant macroscopic theories. At small enough separations, the rate of evaporation appears to deviate significantly from the predictions of classical nucleation theory, and we attribute such deviations to changes in the structure of the confined liquid film. However, the free energy difference between the confined liquid and vapor phases agrees quantitatively with macroscopic theory, and the free energy barrier to condensation displays qualitative agreement. Overall, the present work suggests that theories attempting to capture the kinetic behavior of nanoscale systems should incorporate structural details rather than treating it as a continuum.

  7. Temperature-Correlated Changes in Phytoplankton Community Structure Are Restricted to Polar Waters.

    Science.gov (United States)

    Ward, Ben A

    2015-01-01

    Globally distributed observations of size-fractionated chlorophyll a and temperature were used to incorporate temperature dependence into an existing semi-empirical model of phytoplankton community size structure. The additional temperature-dependent term significantly increased the model's ability to both reproduce and predict observations of chlorophyll a size-fractionation at temperatures below 2°C. The most notable improvements were in the smallest (picoplankton) size-class, for which overall model fit was more than doubled, and predictive skill was increased by approximately 40%. The model was subsequently applied to generate global maps for three phytoplankton size classes, on the basis of satellite-derived estimates of surface chlorophyll a and sea surface temperature. Polar waters were associated with marked decline in the chlorophyll a biomass of the smallest cells, relative to lower latitude waters of equivalent total chlorophyll a. In the same regions a complementary increase was seen in the chlorophyll a biomass of larger size classes. These findings suggest that a warming and stratifying ocean will see a poleward expansion of the habitat range of the smallest phytoplankton, with the possible displacement of some larger groups that currently dominate. There was no evidence of a strong temperature dependence in tropical or sub-tropical regions, suggesting that future direct temperature effects on community structure at lower latitudes may be small.

  8. Distinctive Microbial Community Structure in Highly Stratified Deep-Sea Brine Water Columns

    KAUST Repository

    Bougouffa, Salim; Yang, J. K.; Lee, O. O.; Wang, Y.; Batang, Zenon B.; Al-Suwailem, Abdulaziz M.; Qian, P. Y.

    2013-01-01

    Atlantis II and Discovery are two hydrothermal and hypersaline deep-sea pools in the Red Sea rift that are characterized by strong thermohalo-stratification and temperatures steadily peaking near the bottom. We conducted comprehensive vertical profiling of the microbial populations in both pools and highlighted the influential environmental factors. Pyrosequencing of the 16S rRNA genes revealed shifts in community structures vis-à-vis depth. High diversity and low abundance were features of the deepest convective layers despite the low cell density. Surprisingly, the brine interfaces had significantly higher cell counts than the overlying deep-sea water, yet they were lowest in diversity. Vertical stratification of the bacterial populations was apparent as we moved from the Alphaproteobacteria-dominated deep sea to the Planctomycetaceae- or Deferribacteres-dominated interfaces to the Gammaproteobacteria-dominated brine layers. Archaeal marine group I was dominant in the deep-sea water and interfaces, while several euryarchaeotic groups increased in the brine. Across sites, microbial phylotypes and abundances varied substantially in the brine interface of Discovery compared with Atlantis II, despite the near-identical populations in the overlying deep-sea waters. The lowest convective layers harbored interestingly similar microbial communities, even though temperature and heavy metal concentrations were very different. Multivariate analysis indicated that temperature and salinity were the major influences shaping the communities. The harsh conditions and the low-abundance phylotypes could explain the observed correlation in the brine pools.

  9. Distinctive Microbial Community Structure in Highly Stratified Deep-Sea Brine Water Columns

    KAUST Repository

    Bougouffa, Salim

    2013-03-29

    Atlantis II and Discovery are two hydrothermal and hypersaline deep-sea pools in the Red Sea rift that are characterized by strong thermohalo-stratification and temperatures steadily peaking near the bottom. We conducted comprehensive vertical profiling of the microbial populations in both pools and highlighted the influential environmental factors. Pyrosequencing of the 16S rRNA genes revealed shifts in community structures vis-à-vis depth. High diversity and low abundance were features of the deepest convective layers despite the low cell density. Surprisingly, the brine interfaces had significantly higher cell counts than the overlying deep-sea water, yet they were lowest in diversity. Vertical stratification of the bacterial populations was apparent as we moved from the Alphaproteobacteria-dominated deep sea to the Planctomycetaceae- or Deferribacteres-dominated interfaces to the Gammaproteobacteria-dominated brine layers. Archaeal marine group I was dominant in the deep-sea water and interfaces, while several euryarchaeotic groups increased in the brine. Across sites, microbial phylotypes and abundances varied substantially in the brine interface of Discovery compared with Atlantis II, despite the near-identical populations in the overlying deep-sea waters. The lowest convective layers harbored interestingly similar microbial communities, even though temperature and heavy metal concentrations were very different. Multivariate analysis indicated that temperature and salinity were the major influences shaping the communities. The harsh conditions and the low-abundance phylotypes could explain the observed correlation in the brine pools.

  10. Thermal structure of the TTL and its relation to stratospheric-tropospheric exchange of water.

    Science.gov (United States)

    de La Torre Juárez, M.; Ao, C. O.; Schr\\O der, T. M.; Hermann, R.

    2004-12-01

    The annual cycle of the TTL fine scale thermal structure is described as captured by GPS radio occultation and the pressure levels of the ECMWF weather analysis. This annual cycle is compared to the annual cycle in water concentrations at the upper troposphere/lower stratosphere measured by HALOE. It is found that the saturation mixing ratios at the Cold Point Tropopause temperatures are consistent and sligthly below HALOE values with some temporal lag. This suggests that if dehydration mechanisms other than those associated with slow vertical asscent are working effectively, they must be counterbalanced by other hydration mechanisms. A comparison between saturation mixing ratios at the temperatures captured by GPS radio occultation and HALOE concentrations of water vapor show an annual cycle dominated by supersaturation in the boreal winter months, when the upward mass fluxes are larger, and subsaturation in the summer. The longitudinal dependence of these cycles is discussed and so is its possible implication for the seasonality of statospheric-tropospheric exchange of water.

  11. Investigation on Melt-Structure-Water Interactions (MSWI) during severe accidents

    Energy Technology Data Exchange (ETDEWEB)

    Sehgal, B.R.; Yang, Z.L.; Dinh, T.N.; Nourgaliev, R.R.; Bui, V.A.; Haraldsson, H.O.; Li, H.X.; Konovakhin, M.; Paladino, D.; Leung, W.H [Royal Inst. of Tech., Stockholm (Sweden). Div. of Nuclear Power Safety

    1999-08-01

    This report is the final report for the work performed in 1998 in the research project Melt Structure Water Interactions (MSWI), under the auspices of the APRI Project, jointly funded by SKI, HSK, USNRC and the Swedish and Finnish power companies. The present report describes results of advanced analytical and experimental studies concerning melt-water-structure interactions during the course of a hypothetical severe core meltdown accident in a light water reactor (LWR). Emphasis has been placed on phenomena and properties which govern the fragmentation and breakup of melt jets and droplets, melt spreading and coolability, and thermal and mechanical loadings of a pressure vessel during melt-vessel interaction. Many of the investigations performed in support of this project have produced papers which have been published in the proceedings of technical meetings. A short summary of the results achieved in these papers is provided in this overview. Both experimental and analytical studies were performed to improve knowledge about phenomena of melt-structure-water interactions. We believe that significant technical advances have been achieved during the course of these studies. It was found that: the solidification has a strong effect on the drop deformation and breakup. Initially appearing at the drop surface and, later, thickening inwards, the solid crust layer dampens the instability waves on the drop surface and, therefore, hinders drop deformation and breakup. The drop thermal properties also affect the thermal behavior of the drop and, therefore, have impact on its deformation behavior. The jet fragmentation process is a function of many related phenomena. The fragmentation rate depends not only on the traditional parameters, e.g. the Weber number, but also on the melt physical properties, which change as the melt cools down from the liquidus to the solidus temperature. Additionally, the crust formed on the surface of the melt jet will also reduce the propensity

  12. Investigation on Melt-Structure-Water Interactions (MSWI) during severe accidents

    International Nuclear Information System (INIS)

    Sehgal, B.R.; Yang, Z.L.; Dinh, T.N.; Nourgaliev, R.R.; Bui, V.A.; Haraldsson, H.O.; Li, H.X.; Konovakhin, M.; Paladino, D.; Leung, W.H

    1999-08-01

    This report is the final report for the work performed in 1998 in the research project Melt Structure Water Interactions (MSWI), under the auspices of the APRI Project, jointly funded by SKI, HSK, USNRC and the Swedish and Finnish power companies. The present report describes results of advanced analytical and experimental studies concerning melt-water-structure interactions during the course of a hypothetical severe core meltdown accident in a light water reactor (LWR). Emphasis has been placed on phenomena and properties which govern the fragmentation and breakup of melt jets and droplets, melt spreading and coolability, and thermal and mechanical loadings of a pressure vessel during melt-vessel interaction. Many of the investigations performed in support of this project have produced papers which have been published in the proceedings of technical meetings. A short summary of the results achieved in these papers is provided in this overview. Both experimental and analytical studies were performed to improve knowledge about phenomena of melt-structure-water interactions. We believe that significant technical advances have been achieved during the course of these studies. It was found that: the solidification has a strong effect on the drop deformation and breakup. Initially appearing at the drop surface and, later, thickening inwards, the solid crust layer dampens the instability waves on the drop surface and, therefore, hinders drop deformation and breakup. The drop thermal properties also affect the thermal behavior of the drop and, therefore, have impact on its deformation behavior. The jet fragmentation process is a function of many related phenomena. The fragmentation rate depends not only on the traditional parameters, e.g. the Weber number, but also on the melt physical properties, which change as the melt cools down from the liquidus to the solidus temperature. Additionally, the crust formed on the surface of the melt jet will also reduce the propensity

  13. Water

    Science.gov (United States)

    ... drink and water in food (like fruits and vegetables). 6. Of all the earth’s water, how much is ocean or seas? 97 percent of the earth’s water is ocean or seas. 7. How much of the world’s water is frozen? Of all the water on earth, about 2 percent is frozen. 8. How much ...

  14. The Effect of Interactive, Three Dimensional, High Speed Simulations on High School Science Students' Conceptions of the Molecular Structure of Water.

    Science.gov (United States)

    Hakerem, Gita; And Others

    The Water and Molecular Networks (WAMNet) Project uses graduate student written Reduced Instruction Set Computing (RISC) computer simulations of the molecular structure of water to assist high school students learn about the nature of water. This study examined: (1) preconceptions concerning the molecular structure of water common among high…

  15. John Hennessey, Barrier Breaker

    Science.gov (United States)

    Nelson, Stephen J.

    2018-01-01

    John Hennessey lived a remarkable, full life as a professor, as a leader in his field of management and business, and moral, ethical leadership, and as dean at Dartmouth College's Tuck School of Business and provost at the University of Vermont. He was extraordinary on many fronts, a great man who lived in tumultuous times marked by world war as a…

  16. Heavy metal accumulation imparts structural differences in fragrant Rosa species irrigated with marginal quality water.

    Science.gov (United States)

    Ahsan, Muhammad; Younis, Adnan; Jaskani, Muhammad Jafar; Tufail, Aasma; Riaz, Atif; Schwinghamer, Timothy; Tariq, Usman; Nawaz, Fahim

    2018-09-15

    Wastewater is an alternative to traditional sources of renewable irrigation water in agriculture, particularly in water-scarce regions. However, the possible risks due to heavy metals accumulation in plant tissues are often overlooked by producers. The present study aimed to identify heavy metals-induced structural modifications to roots of scented Rosa species that were irrigated with water of marginal quality. The chemical and mineral contents from the experimental irrigation canal water (control) and treated wastewater were below the limits recommended by the Pakistan Environmental Protection Agency (Pak-EPA) for medicinal plants. The experimentally untreated wastewater contained electrical conductivity (EC), chemical oxygen demand (COD), biological oxygen demand (BOD), and heavy metals (Co, Cu, Cd, Pb) that were above the recommended limits. The responses by wastewater-treated Rosa species (Rosa damascena, R. bourboniana, R. Gruss-an-Teplitz, and R. centifolia) were evaluated. The experimental data revealed that treated wastewater significantly increased the thickness of collenchyma (cortex and pith) and parenchyma tissues (vascular bundle, xylem, and phloem) of R. Gruss-an-Teplitz. Root dermal tissues (epidermis) of R. bourboniana also responded to treated wastewater. R. damascena and R. centifolia were the least affected species, under the experimental irrigation conditions. Collenchyma and dermal tissues were thicker in R. damascena and R. Gruss-an-Teplitz under untreated wastewater conditions. In parenchyma tissues, vascular bundles were thicker in R. damascena in untreated wastewater conditions, while the xylem and phloem of R. Gruss-an-Teplitz were thicker where treated wastewater was applied. In tissues other than the vascular bundle, the differences in anatomical metrics due to the experimental irrigation treatments were greater during the second year of the experiment than in the first year. The contents of metals other than chromium in the roots and

  17. Testing the performance of a Dynamic Global Ecosystem Model: Water balance, carbon balance, and vegetation structure

    Science.gov (United States)

    Kucharik, Christopher J.; Foley, Jonathan A.; Delire, Christine; Fisher, Veronica A.; Coe, Michael T.; Lenters, John D.; Young-Molling, Christine; Ramankutty, Navin; Norman, John M.; Gower, Stith T.

    2000-09-01

    While a new class of Dynamic Global Ecosystem Models (DGEMs) has emerged in the past few years as an important tool for describing global biogeochemical cycles and atmosphere-biosphere interactions, these models are still largely untested. Here we analyze the behavior of a new DGEM and compare the results to global-scale observations of water balance, carbon balance, and vegetation structure. In this study, we use version 2 of the Integrated Biosphere Simulator (IBIS), which includes several major improvements and additions to the prototype model developed by Foley et al. [1996]. IBIS is designed to be a comprehensive model of the terrestrial biosphere; the model represents a wide range of processes, including land surface physics, canopy physiology, plant phenology, vegetation dynamics and competition, and carbon and nutrient cycling. The model generates global simulations of the surface water balance (e.g., runoff), the terrestrial carbon balance (e.g., net primary production, net ecosystem exchange, soil carbon, aboveground and belowground litter, and soil CO2 fluxes), and vegetation structure (e.g., biomass, leaf area index, and vegetation composition). In order to test the performance of the model, we have assembled a wide range of continental and global-scale data, including measurements of river discharge, net primary production, vegetation structure, root biomass, soil carbon, litter carbon, and soil CO2 flux. Using these field data and model results for the contemporary biosphere (1965-1994), our evaluation shows that simulated patterns of runoff, NPP, biomass, leaf area index, soil carbon, and total soil CO2 flux agree reasonably well with measurements that have been compiled from numerous ecosystems. These results also compare favorably to other global model results.

  18. Structure stability of HKUST-1 towards water and ethanol and their effect on its CO2 capture properties.

    Science.gov (United States)

    Álvarez, J Raziel; Sánchez-González, Elí; Pérez, Eric; Schneider-Revueltas, Emilia; Martínez, Ana; Tejeda-Cruz, Adriana; Islas-Jácome, Alejandro; González-Zamora, Eduardo; Ibarra, Ilich A

    2017-07-18

    Water and ethanol stabilities of the crystal structure of the Cu-based metal-organic framework (MOF) HKUST-1 have been investigated. Vapour (water and ethanol) sorption isotherms and cyclability were measured by a dynamic strategy. The ethanol sorption capacity of HKUST-1 at 303 K remained unchanged contrasting water sorption (which decreased along with the sorption experiment time). Considering the binding energy of each sorbate with the open Cu(ii) sites, obtained by the use of diffusion coefficients, we showed the superior crystal stability of the HKUST-1 framework towards ethanol. Finally, a small quantity of ethanol (pre-adsorbed) slightly enhanced CO 2 capture without crystal structure degradation.

  19. Structural interactions between lipids, water and S1-S4 voltage-sensing domains.

    Science.gov (United States)

    Krepkiy, Dmitriy; Gawrisch, Klaus; Swartz, Kenton J

    2012-11-02

    Membrane proteins serve crucial signaling and transport functions, yet relatively little is known about their structures in membrane environments or how lipids interact with these proteins. For voltage-activated ion channels, X-ray structures suggest that the mobile voltage-sensing S4 helix would be exposed to the membrane, and functional studies reveal that lipid modification can profoundly alter channel activity. Here, we use solid-state NMR to investigate structural interactions of lipids and water with S1-S4 voltage-sensing domains and to explore whether lipids influence the structure of the protein. Our results demonstrate that S1-S4 domains exhibit extensive interactions with lipids and that these domains are heavily hydrated when embedded in a membrane. We also find evidence for preferential interactions of anionic lipids with S1-S4 domains and that these interactions have lifetimes on the timescale of ≤ 10(-3)s. Arg residues within S1-S4 domains are well hydrated and are positioned in close proximity to lipids, exhibiting local interactions with both lipid headgroups and acyl chains. Comparative studies with a positively charged lipid lacking a phosphodiester group reveal that this lipid modification has only modest effects on the structure and hydration of S1-S4 domains. Taken together, our results demonstrate that Arg residues in S1-S4 voltage-sensing domains reside in close proximity to the hydrophobic interior of the membrane yet are well hydrated, a requirement for carrying charge and driving protein motions in response to changes in membrane voltage. Published by Elsevier Ltd.

  20. Evaluating a novel tiered scarcity adjusted water budget and pricing structure using a holistic systems modelling approach.

    Science.gov (United States)

    Sahin, Oz; Bertone, Edoardo; Beal, Cara; Stewart, Rodney A

    2018-06-01

    Population growth, coupled with declining water availability and changes in climatic conditions underline the need for sustainable and responsive water management instruments. Supply augmentation and demand management are the two main strategies used by water utilities. Water demand management has long been acknowledged as a least-cost strategy to maintain water security. This can be achieved in a variety of ways, including: i) educating consumers to limit their water use; ii) imposing restrictions/penalties; iii) using smart and/or efficient technologies; and iv) pricing mechanisms. Changing water consumption behaviours through pricing or restrictions is challenging as it introduces more social and political issues into the already complex water resources management process. This paper employs a participatory systems modelling approach for: (1) evaluating various forms of a proposed tiered scarcity adjusted water budget and pricing structure, and (2) comparing scenario outcomes against the traditional restriction policy regime. System dynamics modelling was applied since it can explicitly account for the feedbacks, interdependencies, and non-linear relations that inherently characterise the water tariff (price)-demand-revenue system. A combination of empirical water use data, billing data and customer feedback on future projected water bills facilitated the assessment of the suitability and likelihood of the adoption of scarcity-driven tariff options for a medium-sized city within Queensland, Australia. Results showed that the tiered scarcity adjusted water budget and pricing structure presented was preferable to restrictions since it could maintain water security more equitably with the lowest overall long-run marginal cost. Copyright © 2018 Elsevier Ltd. All rights reserved.