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Sample records for volume absorption coefficient

  1. Remote-Sensing Technique for Determination of the Volume Absorption Coefficient of Turbid Water

    Science.gov (United States)

    Sydor, Michael; Arnone, Robert A.; Gould, Richard W., Jr.; Terrie, Gregory E.; Ladner, Sherwin D.; Wood, Christoper G.

    1998-07-01

    We use remote-sensing reflectance from particulate R rs to determine the volume absorption coefficient a of turbid water in the 400 700-nm spectral region. The calculated and measured values of a ( ) show good agreement for 0 . 5 a 10 (m 1 ). To determine R rs from a particulate, we needed to make corrections for remote-sensing reflectance owing to surface roughness S rs . We determined the average spectral distribution of S rs from the difference in total remote-sensing reflectance measured with and without polarization. The spectral shape of S rs showed an excellent fit to theoretical formulas for glare based on Rayleigh and aerosol scattering from the atmosphere.

  2. Converting Sabine absorption coefficients to random incidence absorption coefficients

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2013-01-01

    Absorption coefficients measured by the chamber method are referred to as Sabine absorption coefficients, which sometimes exceed unity due to the finite size of a sample and non-uniform intensity in the reverberation chambers under test. In this study, conversion methods from Sabine absorption...... coefficients to random incidence absorption coefficients are proposed. The overestimations of the Sabine absorption coefficient are investigated theoretically based on Miki's model for porous absorbers backed by a rigid wall or an air cavity, resulting in conversion factors. Additionally, three optimizations...

  3. Sabine absorption coefficients to random incidence absorption coefficients

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2014-01-01

    Absorption coefficients measured by the chamber method are referred to as Sabine absorption coefficients, which sometimes exceed unity due to the finite size of a specimen and non-uniform intensity in the test chamber. In this study, several methods that convert Sabine absorption coefficients...... into random incidence absorption coefficients for porous absorbers are investigated. Two optimization-based conversion methods are suggested: the surface impedance estimation for locally reacting absorbers and the flow resistivity estimation for extendedly reacting absorbers. The suggested conversion methods...

  4. Reproducibility of The Random Incidence Absorption Coefficient Converted From the Sabine Absorption Coefficient

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho; Chang, Ji-ho

    2015-01-01

    Absorption coefficients measured in reverberation chambers, Sabine absorption coefficients, suffer from two major problems. Firstly, they sometimes exceed unity. Secondly, the reproducibility of the Sabine absorption coefficients is quite poor, meaning that the Sabine absorption coefficients vary...

  5. Experimental methodology for obtaining sound absorption coefficients

    Directory of Open Access Journals (Sweden)

    Carlos A. Macía M

    2011-07-01

    Full Text Available Objective: the authors propose a new methodology for estimating sound absorption coefficients using genetic algorithms. Methodology: sound waves are generated and conducted along a rectangular silencer. The waves are then attenuated by the absorbing material covering the silencer’s walls. The attenuated sound pressure level is used in a genetic algorithm-based search to find the parameters of the proposed attenuation expressions that include geometric factors, the wavelength and the absorption coefficient. Results: a variety of adjusted mathematical models were found that make it possible to estimate the absorption coefficients based on the characteristics of a rectangular silencer used for measuring the attenuation of the noise that passes through it. Conclusions: this methodology makes it possible to obtain the absorption coefficients of new materials in a cheap and simple manner. Although these coefficients might be slightly different from those obtained through other methodologies, they provide solutions within the engineering accuracy ranges that are used for designing noise control systems.

  6. Regularity of the Interband Light Absorption Coefficient

    Indian Academy of Sciences (India)

    M Krishna

    2010-06-01

    In this paper we consider the interband light absorption coefficient (ILAC), in a symmetric form, in the case of random operators on the -dimensional lattice. We show that the symmetrized version of ILAC is either continuous or has a component which has the same modulus of continuity as the density of states.

  7. An alternative coefficient for sound absorption

    NARCIS (Netherlands)

    Wijnant, Y.H.; Kuipers, E.R.; Boer, de A.; Sas, P.; Jonckheere, S.; Moens, D.

    2013-01-01

    The acoustic absorption coefficient is a number that indicates which fraction of the incident acoustic power impinging on a surface is being absorbed. The incident acoustic power is obtained by spatial integration of the incident intensity, which is (classically) defined as the time-averaged intensi

  8. Aerosol Angstrom Absorption Coefficient Comparisons during MILAGRO.

    Science.gov (United States)

    Marley, N. A.; Marchany-Rivera, A.; Kelley, K. L.; Mangu, A.; Gaffney, J. S.

    2007-12-01

    Measurements of aerosol absorption were obtained as part of the MAX-Mex component of the MILAGRO field campaign at site T0 (Instituto Mexicano de Petroleo in Mexico City) by using a 7-channel aethalometer (Thermo- Anderson) during the month of March, 2006. The absorption measurements obtained in the field at 370, 470, 520, 590, 660, 880, and 950 nm were used to determine the aerosol Angstrom absorption exponents by linear regression. Since, unlike other absorbing aerosol species (e.g. humic like substances, nitrated PAHs), black carbon absorption is relatively constant from the ultraviolet to the infrared with an Angstrom absorption exponent of -1 (1), a comparison of the Angstrom exponents can indicate the presence of aerosol components with an enhanced UV absorption over that expected from BC content alone. The Angstrom exponents determined from the aerosol absorption measurements obtained in the field varied from - 0.7 to - 1.3 during the study and was generally lower in the afternoon than the morning hours, indicating an increase in secondary aerosol formation and photochemically generated UV absorbing species in the afternoon. Twelve-hour integrated samples of fine atmospheric aerosols (Petroleo (IMP) and CENICA.

  9. Reflection and absorption coefficients for use in room acoustic simulations

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2013-01-01

    Two ideas to improve the boundary conditions for room acoustic simulations are presented. First, all rooms have finite boundary surfaces, thereby a reflection coefficient for finite surfaces should be physically more suitable than that for infinitely large surfaces. Second, absorption coefficients...... measured by the chamber method, so-called the Sabine absorption coefficients, have certain problems to be used in geometrical acoustics simulations; one serious problem is that they often exceed unity for porous absorbers due to the finite sample size and non-uniform intensity in the test reverberation...... chamber. Therefore the Sabine absorption coefficients should be converted into the random incidence absorption coefficients, which never exceed unity, thus are more proper for room acoustic simulations....

  10. Prediction of absorption coefficients by pulsed laser induced photoacoustic measurements.

    Science.gov (United States)

    Priya, Mallika; Satish Rao, B S; Ray, Satadru; Mahato, K K

    2014-06-05

    In the current study, a pulsed laser induced photoacoustic spectroscopy setup was designed and developed, aiming its application in clinical diagnostics. The setup was optimized with carbon black samples in water and with various tryptophan concentrations at 281nm excitations. The sensitivity of the setup was estimated by determining minimum detectable concentration of tryptophan in water at the same excitation, and was found to be 0.035mM. The photoacoustic experiments were also performed with various tryptophan concentrations at 281nm excitation for predicting optical absorption coefficients in them and for comparing the outcomes with the spectrophotometrically-determined absorption coefficients for the same samples. Absorption coefficients for a few serum samples, obtained from some healthy female volunteers, were also determined through photoacoustic and spectrophotometric measurements at the same excitations, which showed good agreement between them, indicating its clinical implications.

  11. Research on the coefficient of sound absorption in turbid water

    Institute of Scientific and Technical Information of China (English)

    LIU Yong-wei; LI Qi

    2008-01-01

    China's coastal waters are turbid and the properties of the seabed are complex.This negatively impacts the performance of underwater detection equipment.The properties of sound absorption in turbid water are not well understood.In this paper,the coefficient of sound absorption in turbid water was measured by the reverberation technique.All work was done in a reverberation barrel made of seamless aluminum.First,pure water was poured into the reverberation barrel and its reverberation time measured.Next,various concentrations of turbid water were poured into the barrel and their reverberation time measured.After all data had been gathered,the coefficient of sound absorption in turbid water of different concentrations was calculated. From this we determined a law of sound absorption in turbid water as summarized in the paper.

  12. Theoretical assessment of sound absorption coefficient for anisotropic nonwovens

    Directory of Open Access Journals (Sweden)

    Klara Kalinova

    2012-03-01

    Full Text Available The anisotropy factor as a function of fiber arrangement, fiber fineness and sample thickness has been derived from the theories of soundwave transformation due to phase changing. The sound absorption coefficient of the anisotropic fibrous material is then theoretically calculated. The fibrous materials were prepared so that the fibers are arranged parallel (perpendicularly laid fiber web called STRUTO technology in the direction of soundwave propagation or perpendicularly (longitudinally laid fiber web to the direction of sound propagation. The sound absorption coefficient was measured due to the Impedance tube. The theoretical results are in good agreement with experimental findings.

  13. Lifshitz Tails for the Interband Light Absorption Coefficient

    Indian Academy of Sciences (India)

    W Kirsch; M Krishna

    2010-09-01

    In this paper we consider the interband light absorption coefficient (ILAC) for various models. We show that at the lower and upper edges of the spectrum the Lifshitz tails behaviour of the density of states implies similar behaviour for the ILAC at appropriate energies. The Lifshitz tails property is also exhibited at some points corresponding to the internal band edges of the spectrum.

  14. A New Way to Study Water-Vapor Absorption Coefficient

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    In the visible spectrum, the atmospheric attenuations to sunlight mainly include aerosol scattering, atmospheric molecule Rayleigh scattering and ozone absorption, while in the near-infrared spectrum (from 650 nm to 1000 nm), we must take water-vapor absorption into account. Based on the atmospheric correction theory, using spectrum irradiance data measured by Instantaneous Ground spectrometer, ozone content measured by Microtops Ⅱ ozone monitor,water-vapor content and aerosol optical thickness measured by sun photometer, we give a new way to study water-vapor absorption to sunlight, and the result shows that the main peak values of water-vapor absorption coefficients are 0.025 cm-1, 0.073 cm-1, 0.124 cm-1, 0.090 cm-1, 0.141cm-1 and 0.417 cm-1, which respectively lie at 692 nm, 725 nm, 761 nm, 818 nm, 912 nm and 937 nm.

  15. Size segregated light absorption coefficient of the atmospheric aerosol

    Science.gov (United States)

    Horvath, H.

    The light absorption coefficient of atmospheric aerosols in the visible can be determined by depositing the particles on a filter and measuring its "transmission" in a special optical arrangement. With an impactor with rotating impaction plates producing a homogeneous deposit, it is possible to extend this technique to size segregated aerosol samples. A simultaneous determination of the mass size distribution is possible. Test measurements with black carbon aerosol have shown the feasibility of this method. Samples of the atmospheric aerosol have been taken in and near Vienna, in Naples and near Bologna. The light absorption of the aerosol is always highest for particle diameters between 0.1 and 0.2 μm. Only in the humid environment of the Po valley it had a slightly larger peak size, whereas the size of the nonabsorbing particles increased considerably. The light absorption of the atmospheric aerosol is always higher in an urban environment. 'The mass absorption coefficient of the aerosol at all four locations was very similar, and completely different from values which could be. expected using effective refractive indices which are frequently used in models. Using the data measured in this work two alternate models for the effective refractive index and black carbon content of the aerosol are suggested: (a) a size-dependent refractive index, where the imaginary part varies from -0.25 for particles smaller than 30 nm to - 0.003 for particles larger than 2 μm; this could especially be applied if an internal mixing of the aerosol is to be expected, or (2) a size-dependent fraction of elemental carbon in the case of external mixing with 43% of carbon particles for sizes below 30 nm decreasing to 10% for sizes up to 0.4 μm.

  16. A method for monitoring nuclear absorption coefficients of aviation fuels

    Science.gov (United States)

    Sprinkle, Danny R.; Shen, Chih-Ping

    1989-01-01

    A technique for monitoring variability in the nuclear absorption characteristics of aviation fuels has been developed. It is based on a highly collimated low energy gamma radiation source and a sodium iodide counter. The source and the counter assembly are separated by a geometrically well-defined test fuel cell. A computer program for determining the mass attenuation coefficient of the test fuel sample, based on the data acquired for a preset counting period, has been developed and tested on several types of aviation fuel.

  17. Optimization of the acoustic absorption coefficients of certain functional absorbents

    Science.gov (United States)

    Pocsa, V.; Biborosch, L.; Veres, A.; Halpert, E.; Lorian, R.; Botos, T.

    1974-01-01

    The sound absorption coefficients of some functional absorbents (mineral wool plates) are determined by the reverberation chamber method. The influence of the angle of inclination of the sound absorbing material with respect to the surface to be treated is analyzed as well as the influence of the covering index, defined as the ratio of the designed area of a plate and the area of the treated surface belonging to another plate. As compared with the conventional method of applying sound-absorbing plates, the analyzed structures have a higher technological and economical efficiency. The optimum structure corresponds to an angle of inclination of 15 deg and a covering index of 0.8.

  18. Photon absorption potential coefficient as a tool for materials engineering

    Science.gov (United States)

    Akande, Raphael Oluwole; Oyewande, Emmanuel Oluwole

    2016-09-01

    Different atoms achieve ionizations at different energies. Therefore, atoms are characterized by different responses to photon absorption in this study. That means there exists a coefficient for their potential for photon absorption from a photon source. In this study, we consider the manner in which molecular constituents (atoms) absorb photon from a photon source. We observe that there seems to be a common pattern of variation in the absorption of photon among the electrons in all atoms on the periodic table. We assume that the electrons closest to the nucleus (En) and the electrons closest to the outside of the atom (Eo) do not have as much potential for photon absorption as the electrons at the middle of the atom (Em). The explanation we give to this effect is that the En electrons are embedded within the nuclear influence, and similarly, Eo electrons are embedded within the influence of energies outside the atom that there exists a low potential for photon absorption for them. Unlike En and Eo, Em electrons are conditioned, such that there is a quest for balance between being influenced either by the nuclear force or forces external to the atom. Therefore, there exists a higher potential for photon absorption for Em electrons than for En and Eo electrons. The results of our derivations and analysis always produce a bell-shaped curve, instead of an increasing curve as in the ionization energies, for all elements in the periodic table. We obtained a huge data of PAPC for each of the several materials considered. The point at which two or more PAPC values cross one another is termed to be a region of conflicting order of ionization, where all the atoms absorb equal portion of the photon source at the same time. At this point, a greater fraction of the photon source is pumped into the material which could lead to an explosive response from the material. In fact, an unimaginable and unreported phenomenon (in physics) could occur, when two or more PAPCs cross, and

  19. Phased Beam Tracing Method Using the Reflection Coefficient Calculated from the Absorption Coefficient

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho; Ih, Jeong-Guon; Rindel, Jens Holger

    2005-01-01

    the measured surface impedance. However, it is not always possible to get the measured impedance data of the surface, so that a practical way of getting reflection characteristics is needed. Generally, in the architectural acoustics field, the absorption coefficients have been employed in the calculations......The phased beam tracing method (PBTM) is a technique which can calculate the pressure impulse response instead of energy impulse response, by taking the phase information into account. Inclusion of the phase information can extend the application of beam tracing technique to the mid frequency range...

  20. A nomogram for prediction of absorption rate coefficient

    Institute of Scientific and Technical Information of China (English)

    李玉红; 赵欣; 嵇晴; 徐建国; 孙瑞元

    2004-01-01

    Background Previous studies have suggested that nomogram can simplize complicated calculations of several varibles. A simple nomogram was constructed to estimate absorption rate coefficient (ka) by using the peak time (tpeak) and the elimination rate coefficient (ke) of drugs administered orally. Methods The nomogram was based on the plasma concentration-time (C-T) curve equation and the function relation between tpeak, ka and ke. A mathematical analysis was presented for the construction of single chart nomogram. To check the degree of accuracy of the developed nomogram, we used it to analyze retrospective profiles of 46 drugs and compared the ka values obtained graphically and those calculated by numerically solving the descriptive equation. In addition, we measured the carbocisteine concentration of 18 healthy volunteers by HPLC with fluorescence detection. To analyze performance error, the measured carbocisteine concentrations were compared with predicted concentrations by the ka obtained from the nomograms along with the other pharmacokinetic parameters. Results The estimated of ka values from nomograms were in very close proximity with the numerical values. The performance error was as follows: median performance error (MDPE) and median absolute performance error (MDAPE) were 1.32% and 18.15%, respectively. Conclusions The developed nomogram is accurate and reliable. The size of performance error meets the demand of clinical pharmacokinetics. Therefore, the nomograms can offer another convenient and easy method for rational individualized dosage regimens.

  1. The Hyperspectral Absorption Sensor - Advantages and challenges of continuous, in situ absorption coefficient measurements

    Science.gov (United States)

    Wollschläger, J.; Röttgers, R.; Petersen, W.; Zielinski, O.

    2016-12-01

    The marine environment is a highly dynamic system and rapid changes can occur on both spatial and temporal scales. This is especially true for the phytoplankton, which forms the basis of the marine food web. Comprehensive monitoring and investigation of its often patchy distribution and seasonal succession requires sensors which are fast, can be used in situ, and are automatable to reduce operational costs. Optical sensors fulfil all of these requirements. Due to its variety of (sometimes group-specific) photosynthetic and photoprotective pigments, phytoplankton has a considerable influence on the water's inherent and apparent optical properties. This offers the possibility to obtain information about the phytoplankton present by measuring these properties, for example the absorption coefficients of the water at the photosynthetic active wavelengths. However, common obstacles for obtaining high quality absorption coefficient measurements are the often low concentration of absorbing material present as well as errors introduced by light scattering on particles. These problems can be overcome by instruments taking advantage of integrating cavities, like the point-source integrating cavity absorption meter (PSICAM). The Hyperspectral Absorption Sensor (HyAbS) is the result of an attempt to combine the advantages of the PSICAM approach with the high resolution of continuous measurements. Its setup and working principle is described, and challenges and potential solutions with respect to its long-term automated operation are highlighted. This includes the replacement of the dye-based calibration of the instrument by a solid standard calibration. Finally, also results from field test with respect to phytoplankton investigation are given.

  2. Inference of the microwave absorption coefficient from stray radiation measurements in Wendelstein 7-X

    Science.gov (United States)

    Moseev, D.; Laqua, H. P.; Marsen, S.; Marushchenko, N.; Stange, T.; Braune, H.; Gellert, F.; Hirsch, M.; Hoefel, U.; Knauer, J.; Oosterbeek, J. W.; Turkin, Y.; The Wendelstein 7-X Team

    2017-03-01

    The efficiency of electron cyclotron heating is determined by the microwave absorption of the plasma. Good microwave absorption is also crucial for the machine safety. In this paper we present a method of evaluating the microwave absorption coefficient from stray radiation measurements. The discussed method is computationally simple and can be applied potentially in real time. Evolution of the second harmonic extraordinary mode (X2) microwave absorption coefficient in Wendelstein 7-X during the start-up phase is presented, as well as an estimate of the absorption coefficient for the second harmonic ordinary mode (O2) wave.

  3. Predicted sound absorption coefficients of absorber materials lined in a chamber

    Directory of Open Access Journals (Sweden)

    Farhad Forouharmajd

    2014-01-01

    Full Text Available Aims: The present study was aimed to measurement of sound absorption coefficient of mineral wool and determination of their absorption ability. Materials and Methods: Mineral wool was used to find noise absorption coefficient. Random and normal sound absorption coefficient values were predicted. Then, the measures of transmission loss calculated as an overall value, for applied absorbent material and bare sheet metal. Results: The measured values of noise with one octave band frequency demonstrated an attenuation of 5.5-7 dB for these frequencies. The absorption coefficients of materials showed that mineral wool had more normal sound coefficients than its random sound absorption coefficient values. Conclusion: It can be concluded that predicted normal sound absorption coefficients of used mineral wool materials were near to the areas of standard line. It seems that the amount or thickness of absorbent lining was a main reason of noise reduction in low band frequencies. Mineral wool has a higher density and can provide better acoustical and insulating results than fiberglass. Besides, mineral wool doesn′t lose its insulating value when wet and has an outstanding resistance to fire.

  4. Producing of Impedance Tube for Measurement of Acoustic Absorption Coefficient of Some Sound Absorber Materials

    Directory of Open Access Journals (Sweden)

    R. Golmohammadi

    2008-04-01

    Full Text Available Introduction & Objective: Noise is one of the most important harmful agents in work environment. In spit of industrial improvements, exposure with over permissible limit of noise is counted as one of the health complication of workers. In Iran, do not exact information of the absorption coefficient of acoustic materials. Iranian manufacturer have not laboratory for measured of sound absorbance of their products, therefore using of sound absorber is limited for noise control in industrial and non industrial constructions. The goal of this study was to design an impedance tube based on pressure method for measurement of the sound absorption coefficient of acoustic materials.Materials & Methods: In this study designing of measuring system and method of calculation of sound absorption based on a available equipment and relatively easy for measurement of the sound absorption coefficient related to ISO10534-1 was performed. Measuring system consist of heavy asbestos tube, a pure tone sound generator, calibrated sound level meter for measuring of some commonly of sound absorber materials was used. Results: In this study sound absorption coefficient of 23 types of available acoustic material in Iran was tested. Reliability of results by three repeat of measurement was tested. Results showed that the standard deviation of sound absorption coefficient of study materials was smaller than .Conclusion: The present study performed a necessary technology of designing and producing of impedance tube for determining of acoustical materials absorption coefficient in Iran.

  5. Linear and nonlinear optical absorption coefficients of two-electron spherical quantum dot with parabolic potential

    Science.gov (United States)

    Çakır, Bekir; Yakar, Yusuf; Özmen, Ayhan

    2015-02-01

    Linear and nonlinear absorption coefficients of two-electron spherical quantum dot (QD) with parabolic potential are investigated in this paper. Wave functions and energy eigenvalues of the 1s2, 1s1p, 1s1d and 1s1f electronic states have been computed by using an optimization approach, which is a combination of Quantum Genetic Algorithm (QGA) and Hartree-Fock Roothaan (HFR) method. It is found that the strength of S→P transition is stronger than P→D and D→F transitions. Also the peak positions and amplitudes of the absorption coefficients are sensitive to the electron spin. It should be noted that the peak positions and amplitudes of absorption coefficients are strongly dependent on the parabolic potential. Additionally, dot radius, impurity charge, incident optical intensity and relaxation time have a great influence on the linear and nonlinear absorption coefficients.

  6. Linear and nonlinear optical absorption coefficients of two-electron spherical quantum dot with parabolic potential

    Energy Technology Data Exchange (ETDEWEB)

    Çakır, Bekir, E-mail: bcakir@selcuk.edu.tr [Physics Department, Faculty of Science, Selcuk University, Campus 42075, Konya (Turkey); Yakar, Yusuf, E-mail: yuyakar@yahoo.com [Physics Department, Faculty of Arts and Science, Aksaray University, Campus 68100, Aksaray (Turkey); Özmen, Ayhan [Physics Department, Faculty of Science, Selcuk University, Campus 42075, Konya (Turkey)

    2015-02-01

    Linear and nonlinear absorption coefficients of two-electron spherical quantum dot (QD) with parabolic potential are investigated in this paper. Wave functions and energy eigenvalues of the 1s{sup 2}, 1s1p, 1s1d and 1s1f electronic states have been computed by using an optimization approach, which is a combination of Quantum Genetic Algorithm (QGA) and Hartree–Fock Roothaan (HFR) method. It is found that the strength of S→P transition is stronger than P→D and D→F transitions. Also the peak positions and amplitudes of the absorption coefficients are sensitive to the electron spin. It should be noted that the peak positions and amplitudes of absorption coefficients are strongly dependent on the parabolic potential. Additionally, dot radius, impurity charge, incident optical intensity and relaxation time have a great influence on the linear and nonlinear absorption coefficients.

  7. A method for determination mass absorption coefficient of gamma rays by Compton scattering.

    Science.gov (United States)

    El Abd, A

    2014-12-01

    A method was proposed for determination mass absorption coefficient of gamma rays for compounds, alloys and mixtures. It is based on simulating interaction processes of gamma rays with target elements having atomic numbers from Z=1 to Z=92 using the MCSHAPE software. Intensities of Compton scattered gamma rays at saturation thicknesses and at a scattering angle of 90° were calculated for incident gamma rays of different energies. The obtained results showed that the intensity of Compton scattered gamma rays at saturations and mass absorption coefficients can be described by mathematical formulas. These were used to determine mass absorption coefficients for compound, alloys and mixtures with the knowledge of their Compton scattered intensities. The method was tested by calculating mass absorption coefficients for some compounds, alloys and mixtures. There is a good agreement between obtained results and calculated ones using WinXom software. The advantages and limitations of the method were discussed.

  8. Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime

    OpenAIRE

    Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Lihong V. Wang

    2012-01-01

    Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method...

  9. Bayesian inversion from sabine absorption coefficients to flow resistivity values for porous absorbers

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2015-01-01

    diffraction, named Thomasson’s finite size correction. As input data, a set of the Sabine absorption coefficients in a recent absorption round robin test in 13 European chambers was used. Finally, the flow resistivity of the test specimen is characterized via the Bayesian framework, together...

  10. Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime.

    Science.gov (United States)

    Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Wang, Lihong V

    2012-06-01

    Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method, the absorption coefficients of an oxygenated bovine blood phantom at 560, 565, 570, and 575 nm were quantified with errors of acoustic spectral method provides greater quantification accuracy in the optical diffusive regime. The limitations of the acoustic spectral method was also discussed.

  11. Noninvasive determination of absorption coefficient and reduced scattering coefficient of human skin tissues in vivo with oblique-incidence reflectometry

    Institute of Scientific and Technical Information of China (English)

    Ping Sun; Yu Wang; Xiaoli Mo; Jinghui Xie

    2008-01-01

    A spatial distribution of diffuse reflectance produced by obliquely incident light is not centered about the point of light entry. The value of shift in the center of diffuse reflectance is directly related to the absorption coefficient μa and the effective attenuation coefficient μeff. μa and the reduced scattering coefficient μ's of human skin tissues in vivo are measured by oblique-incidence reflectometry based on the two-source diffuse theory model. For ten Chinese volunteers aged 15-63 years, μa and μ's are noninvasively determined to be 0.029 - 0.075 and 0.52 - 0.97 mm-1, respectively.

  12. Measurements of Soot Mass Absorption Coefficients from 300 to 660 nm

    Science.gov (United States)

    Renbaum-Wolff, Lindsay; Fisher, Al; Helgestad, Taylor; Lambe, Andrew; Sedlacek, Arthur; Smith, Geoffrey; Cappa, Christopher; Davidovits, Paul; Onasch, Timothy; Freedman, Andrew

    2016-04-01

    Soot, a product of incomplete combustion, plays an important role in the earth's climate system through the absorption and scattering of solar radiation. In particular, the assumed mass absorption coefficient (MAC) of soot and its variation with wavelength presents a significant uncertainty in the calculation of radiative forcing in global climate change models. As part of the fourth Boston College/Aerodyne soot properties measurement campaign, we have measured the mass absorption coefficient of soot produced by an inverted methane diffusion flame over a spectral range of 300-660 nm using a variety of optical absorption techniques. Extinction and absorption were measured using a dual cavity ringdown photoacoustic spectrometer (CRD-PAS, UC Davis) at 405 nm and 532 nm. Scattering and extinction were measured using a CAPS PMssa single scattering albedo monitor (Aerodyne) at 630 nm; the absorption coefficient was determined by subtraction. In addition, the absorption coefficients in 8 wavelength bands from 300 to 660 nm were measured using a new broadband photoacoustic absorption monitor (UGA). Soot particle mass was quantified using a centrifugal particle mass analyzer (CPMA, Cambustion), mobility size with a scanning mobility particle sizer (SMPS, TSI) and soot concentration with a CPC (Brechtel). The contribution of doubly charged particles to the sample mass was determined using a Single Particle Soot Photometer (DMT). Over a mass range of 1-8 fg, corresponding to differential mobility diameters of ~150 nm to 550 nm, the value of the soot MAC proved to be independent of mass for all wavelengths. The wavelength dependence of the MAC was best fit to a power law with an Absorption Ångstrom Coefficient slightly greater than 1.

  13. Nonlinear absorption coefficient of pulsed laser deposited MgZnO thin film

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Arpana, E-mail: agrawal.arpana01@gmail.com; Dar, Tanveer A.; Solanki, Ravi; Sen, Pratima [Laser Bhawan, School of Physics, Devi Ahilya University, Khandwa Road, Indore-452001 (India); Phase, D. M. [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452001 (India)

    2015-06-24

    We report the imaginary part of 3{sup rd} order nonlinear susceptibility and the nonlinear absorption coefficient of Mg doped ZnO thin film using standard Z-scan technique. The origin of nonlinear absorption is attributed to the two photon absorption followed by the free carrier absorption because of the presence of oxygen vacancy defects. We have also confirmed the experimental results with the theoretical results obtained by considering the steady state response of a two level atom with the monochromatic field models.

  14. In situ measurements of the oblique incidence sound absorption coefficient for finite sized absorbers.

    Science.gov (United States)

    Ottink, Marco; Brunskog, Jonas; Jeong, Cheol-Ho; Fernandez-Grande, Efren; Trojgaard, Per; Tiana-Roig, Elisabet

    2016-01-01

    Absorption coefficients are mostly measured in reverberation rooms or with impedance tubes. Since these methods are only suitable for measuring the random incidence and the normal incidence absorption coefficient, there exists an increasing need for absorption coefficient measurement of finite absorbers at oblique incidence in situ. Due to the edge diffraction effect, oblique incidence methods considering an infinite sample fail to measure the absorption coefficient at large incidence angles of finite samples. This paper aims for the development of a measurement method that accounts for the finiteness of the absorber. A sound field model, which accounts for scattering from the finite absorber edges, assuming plane wave incidence is derived. A significant influence of the finiteness on the radiation impedance and the corresponding absorption coefficient is found. A finite surface method, which combines microphone array measurements over a finite sample with the sound field model in an inverse manner, is proposed. Besides, a temporal subtraction method, a microphone array method, impedance tube measurements, and an equivalent fluid model are used for validation. The finite surface method gives promising agreement with theory, especially at near grazing incidence. Thus, the finite surface method is proposed for further measurements at large incidence angles.

  15. Minority carrier diffusion lengths and absorption coefficients in silicon sheet material

    Science.gov (United States)

    Dumas, K. A.; Swimm, R. T.

    1980-01-01

    Most of the methods which have been developed for the measurement of the minority carrier diffusion length of silicon wafers require that the material have either a Schottky or an ohmic contact. The surface photovoltage (SPV) technique is an exception. The SPV technique could, therefore, become a valuable diagnostic tool in connection with current efforts to develop low-cost processes for the production of solar cells. The technique depends on a knowledge of the optical absorption coefficient. The considered investigation is concerned with a reevaluation of the absorption coefficient as a function of silicon processing. A comparison of absorption coefficient values showed these values to be relatively consistent from sample to sample, and independent of the sample growth method.

  16. Numerically optimized band boundaries of Planck mean absorption coefficients in air plasma

    Science.gov (United States)

    Kloc, P.; Aubrecht, V.; Bartlova, M.

    2017-08-01

    Radiation heat transfer plays an important role in the energy balance of plasma in an electric arc and its accurate prediction is essential for the development of new electrical devices. Unfortunately, a very complex spectrum of the absorption coefficient makes accurate radiation heat transfer calculations a very challenging task, especially with complex geometries. Numerical approximation of the absorption coefficient is therefore commonly used to reduce computing demands. This paper presents our contribution to the topic of computing requirements reduction, namely the problem of frequency band selection for mean absorption coefficients (MACs). We show that, with the proper band distribution and averaging method, even a very low number of bands can be sufficient for an accurate approximation of the real radiation heat transfer. The band selection process is based upon numerical optimization with a mean value of each band being calculated as a line limited Planck MAC. Both the line limiting factor and associated characteristic plasma absorption length are investigated in detail and an optimal value equal to the three plasma radii is proposed. Tables for three bands mean absorption coefficients in air at the pressure of 1 bar and temperature range spanning from 300 K to 30 kK are included in this paper. These tables serve as input parameters for a fast evaluation of radiation transfer using either the P1 or discrete ordinates method (DOM) approximation with satisfactory accuracy.

  17. Extraction of absorption coefficients from GaN nanowires grown on opaque substrates

    CERN Document Server

    Jayaprakash, Rahul; Germanis, Savvas; Androulidaki, Maria; Tsagaraki, Katerina; Georgakilas, Alexandros; Pelekanos, Nikos T

    2014-01-01

    We demonstrate a new method to measure absorption coefficients in any family of nanowires, provided they are grown on a substrate having considerable difference in permittivity with the nanowire-air matrix. In the case of high crystal quality, strain-free GaN nanowires, grown on Si (111) substrates with a density of ~1010 cm-2, the extracted absorption coefficients do not exhibit any enhancement compared to bulk GaN values, unlike relevant claims in the literature. This may be attributed to the relatively small diameters, short heights, and high densities of our nanowire arrays.

  18. In situ measurements of the oblique incidence sound absorption coefficient for finite sized absorbers

    DEFF Research Database (Denmark)

    Ottink, Marco; Brunskog, Jonas; Jeong, Cheol-Ho

    2016-01-01

    absorbers at oblique incidence in situ. Due to the edge diffraction effect, oblique incidence methods considering an infinite sample fail to measure the absorption coefficient at large incidence angles of finite samples. This paper aims for the development of a measurement method that accounts...... for the finiteness of the absorber. A sound field model, which accounts for scattering from the finite absorber edges, assuming plane wave incidence is derived. A significant influence of the finiteness on the radiation impedance and the corresponding absorption coefficient is found. A finite surface method, which...

  19. In situ measurements of the oblique incidence sound absorption coefficient for finite sized absorbers

    DEFF Research Database (Denmark)

    Ottink, Marco; Brunskog, Jonas; Jeong, Cheol-Ho

    2016-01-01

    absorbers at oblique incidence in situ. Due to the edge diffraction effect, oblique incidence methods considering an infinite sample fail to measure the absorption coefficient at large incidence angles of finite samples. This paper aims for the development of a measurement method that accounts...... for the finiteness of the absorber. A sound field model, which accounts for scattering from the finite absorber edges, assuming plane wave incidence is derived. A significant influence of the finiteness on the radiation impedance and the corresponding absorption coefficient is found. A finite surface method, which...

  20. Evaluation of UV absorption coefficient in laser-modified fused silica

    Energy Technology Data Exchange (ETDEWEB)

    Negres, R A; Burke, M W; Sutton, S B; DeMange, P; Feit, M D; Demos, S G

    2006-08-21

    Laser-induced damage in transparent dielectrics leads to the formation of laser-modified material as a result of exposure to extreme localized temperatures and pressures. In this work, we used an infrared thermal imaging system in combination with a fluorescence microscope to map the dynamics of the local surface temperature and fluorescence intensity under cw, UV excitation of laser-modified fused silica within a damage site. Based on a thermal diffusion model, we estimate the energy deposited via linear absorption mechanisms and derive the absorption coefficient of the modified material. In addition, irreversible changes in the absorption following extended laser exposure were observed.

  1. Absorption coefficient of nearly transparent liquids measured using thermal lens spectrometry

    Directory of Open Access Journals (Sweden)

    H.Cabrera

    2006-01-01

    Full Text Available We use an optimized pump-probe mode-mismatched thermal lens scheme to determine the optical absorption coefficient and thermal diffusivity of ethanol, benzene, acetone, methanol, toluene and chloroform. In this scheme the excitation beam is focused in the presence of a collimated probe beam. The agreement between experimentally obtained results and values reported in the literature is good.

  2. Estimating the Sabine absorption coefficient of fibrous materials for various backing conditions

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2017-01-01

    conditions by extracting the air flow resistivity of the test specimen and the frequency-dependent effect of the chamber on the measured absorption coefficients. Two homogeneous fibrous absorbers are measured for experimental validation, showing good agreements between the predictions and measurements...

  3. Calibration of an integrating sphere for determining the absorption coefficient of scattering suspensions.

    Science.gov (United States)

    Nelson, N B; Prézelin, B B

    1993-11-20

    Measuring the absolute absorption of suspensions of absorbing particles with unknown scattering characteristics is not possible in conventional spectrophotometers or in integrating spheres that have the sample located outside the sphere. A method for the calibration and use of an integrating sphere with a centrally located sample to measure absolute absorption coefficients of scattering suspensions is presented. Under the tested conditions the integrating sphere used in this study was insensitive to changes in the scattering coefficient of the sample but had a nonlinear response to increasing absorption of the sample, which could be corrected with an empirically derived function. This response was analyzed by using a Monte Carlo simulation, and results indicated that amplification of the absorption signal was primarily due to photons reflected from the sphere surface and the baffle reentering the cuvette. The calibration procedure described here may be generally applicable to spheres of different configurati n. An example of the use of the sphere for determining the absorption and scattering coefficients of marine phytoplankton samples is presented.

  4. Mass specific optical absorption coefficients of mineral dust components measured by a multi wavelength photoacoustic spectrometer

    Directory of Open Access Journals (Sweden)

    N. Utry

    2014-09-01

    Full Text Available Mass specific optical absorption coefficients of various mineral dust components including silicate clays (illite, kaolin and bentonite, oxides (quartz, hematite and rutile, and carbonate (limestone were determined at wavelengths of 1064, 532, 355 and 266 nm. These values were calculated from aerosol optical absorption coefficients measured by a multi-wavelength photoacoustic (PA instrument, the mass concentration and the number size distribution of the generated aerosol samples as well as the size transfer functions of the measuring instruments. These results are expected to have considerable importance in global radiative forcing calculations. They can also serve as reference for validating calculated wavelength dependent imaginary parts (κ of complex refractive indices which up to now have been typically deduced from bulk phase measurements by using indirect measurement methods. Accordingly, the presented comparison of the measured and calculated aerosol optical absorption spectra revealed the strong need for standardized sample preparation and measurement methodology in case of bulk phase measurements.

  5. Chlorophyll specific absorption coefficient and phytoplankton biomass in the Red Sea

    KAUST Repository

    Tiwari, Surya Prakash

    2015-01-01

    The role of total particulate matter, the sum of phytoplankton and nonalgal particles, is essential to understanding the distribution and pathways of particulate carbon in the ocean. Their relative contributions to light absorption and scattering are fundamental to understanding remotely sensed ocean color. Until recently, data regarding the contribution of phytoplankton and algal particles to the inherent optical properties of the Red Sea was nonexistent. Some of the first measurements of these inherent optical properties in the Red Sea including phytoplankton specific absorption coefficients (aph*(λ)) were obtained by the TARA Oceans expedition in January 2010. From these observations, chlorophyll a was calculated using the Line Height Method (LHM) that minimizes the contribution to total and particulate absorption by non-algal particles (NAP) and CDOM. Bricaud and Stramski’s (1990) a method was then used to decompose hyperspectral total particulate absorption into the contributions by phytoplankton and nonalgal particles.

  6. A new photoacoustic method based on the modulation of the light induced absorption coefficient

    Science.gov (United States)

    Engel, S.; Wenisch, C.; Müller, F. A.; Gräf, S.

    2016-04-01

    The present study reports on a new photoacoustic (PA) measurement method that is suitable for the investigation of light induced absorption effects including e.g. excited state absorption. Contrary to the modulation of the radiation intensity used in conventional PA-methods, the key principle of this novel setup is based on the modulation of the induced absorption coefficient by light. For this purpose, a pump-probe setup with a pulsed pump laser beam and a continuous probe laser beam is utilized. In this regime, the potential influence of heat on the PA-signal is much smaller when compared to arrangements with pulsed probe beam and continuous pump beam. Beyond that, the negative effect of thermal lenses can be neglected. Thus, the measurement technique is well-suited for materials exhibiting a strong absorption at the pump wavelength. The quantitative analysis of the induced absorption coefficient was achieved by the calibration of the additional PA-signal caused by the continuous probe laser to the PA-signal resulting from the pulsed pump laser using thallium bromoiodide (KRS-5) as sample material.

  7. Derivation of absorption coefficient and reduced scattering coefficient with edge-loss method and comparison with video reflectometry method

    Science.gov (United States)

    Yoshida, Kenichiro

    2016-08-01

    We derived the absorption coefficient ( μ a) and the reduced scattering coefficient ( μ s') using the edge-loss method (ELM) and the video reflectometry method (VRM), and compared the results. In a previous study, we developed the ELM to easily evaluate the lateral spread in the skin; the VRM is a conventional method. The ELM measures the translucency index, which is correlated with μ a and μ s'. To obtain a precise estimation of these parameters, we improved the treatment of a white standard and the surface reflection. For both skin phantoms and actual skin, the values for μ a and μ s' that we obtained using the ELM were similar to those obtained using the VRM, when μ a/ μ s' was less than or equal to 0.05 and the diffusion approximation was applicable. Under this condition, the spectral reflectivity is greater than 0.4. In this study, we considered wavelengths longer than 600 nm for Types III and IV of the Fitzpatrick scale. For skin, the repeatability errors of the parameters obtained with the ELM were smaller than those obtained with the VRM; this can be an advantage in field tests.

  8. Absorption coefficients of GeSn extracted from PIN photodetector response

    Science.gov (United States)

    Ye, Kaiheng; Zhang, Wogong; Oehme, Michael; Schmid, Marc; Gollhofer, Martin; Kostecki, Konrad; Widmann, Daniel; Körner, Roman; Kasper, Erich; Schulze, Jörg

    2015-08-01

    In this paper the optical absorption of the GeSn PIN photodetector was investigated. The vertical GeSn PIN photodetectors were fabricated by molecular beam epitaxy (MBE) and dry etching. By means of current density-voltage (J-V) and capacity-voltage (C-V) measurements the photodetector device was characterized. The absorption coefficients of GeSn material were finally extracted from the optical response of PIN structure. With further direct bandgap analysis the influences of device structure was proved negligible.

  9. Vertical profiles of aerosol absorption coefficient from micro-Aethalometer data and Mie calculation over Milan.

    Science.gov (United States)

    Ferrero, L; Mocnik, G; Ferrini, B S; Perrone, M G; Sangiorgi, G; Bolzacchini, E

    2011-06-15

    Vertical profiles of aerosol number-size distribution and black carbon (BC) concentration were measured between ground-level and 500m AGL over Milan. A tethered balloon was fitted with an instrumentation package consisting of the newly-developed micro-Aethalometer (microAeth® Model AE51, Magee Scientific, USA), an optical particle counter, and a portable meteorological station. At the same time, PM(2.5) samples were collected both at ground-level and at a high altitude sampling site, enabling particle chemical composition to be determined. Vertical profiles and PM(2.5) data were collected both within and above the mixing layer. Absorption coefficient (b(abs)) profiles were calculated from the Aethalometer data: in order to do so, an optical enhancement factor (C), accounting for multiple light-scattering within the filter of the new microAeth® Model AE51, was determined for the first time. The value of this parameter C (2.05±0.03 at λ=880nm) was calculated by comparing the Aethalometer attenuation coefficient and aerosol optical properties determined from OPC data along vertical profiles. Mie calculations were applied to the OPC number-size distribution data, and the aerosol refractive index was calculated using the effective medium approximation applied to aerosol chemical composition. The results compare well with AERONET data. The BC and b(abs) profiles showed a sharp decrease at the mixing height (MH), and fairly constant values of b(abs) and BC were found above the MH, representing 17±2% of those values measured within the mixing layer. The BC fraction of aerosol volume was found to be lower above the MH: 48±8% of the corresponding ground-level values. A statistical mean profile was calculated, both for BC and b(abs), to better describe their behaviour; the model enabled us to compute their average behaviour as a function of height, thus laying the foundations for valid parametrizations of vertical profile data which can be useful in both remote sensing

  10. Bias in the absorption coefficient determination of a fluorescent dye, standard reference material 1932 fluorescein solution

    Energy Technology Data Exchange (ETDEWEB)

    DeRose, Paul C. [Analytical Chemistry Division, National Institute of Standards and Technology, 100 Bureau Dr., Gaithersburg, MD 20899-8394 (United States)]. E-mail: paul.derose@nist.gov; Kramer, Gary W. [Analytical Chemistry Division, National Institute of Standards and Technology, 100 Bureau Dr., Gaithersburg, MD 20899-8394 (United States)

    2005-06-15

    The absorption coefficient of standard reference material[registered] (SRM[registered]) 1932, fluorescein in a borate buffer solution (pH=9.5) has been determined at {lambda}=488.0, 490.0, 490.5 and 491.0 nm using the US national reference UV/visible spectrophotometer. The purity of the fluorescein was determined to be 97.6% as part of the certification of SRM 1932. The solution measured was prepared gravimetrically by diluting SRM 1932 with additional borate buffer. The value of the absorption coefficient was corrected for bias due to fluorescence that reaches the detector and for dye purity. Bias due to fluorescence was found to be on the order of -1% for both monochromatic and polychromatic (e.g., diode-array based) spectrophotometers.

  11. Bayesian inference of the flow resistivity of a sound absorber and the room's influence on the Sabine absorption coefficients

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho; Choi, Sang-Hyeon; Lee, Ikjin

    2017-01-01

    A Bayesian analysis is applied to determine the flow resistivity of a porous sample and the influence of the test chamber based on measured Sabine absorption coefficient data. The Sabine absorption coefficient measured in a reverberation chamber according to ISO 354 is influenced by the test...

  12. Semi-empirical schemes for the x-ray mass absorption coefficients used in XRF analysis

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    X-ray mass absorption coefficients play an important role in the accu-racy of any XRF intensity calculation. It is necessary to determine the proper schemesfor providing satisfying values μ/p. In this work we examined and compared variousschemes. A program based on the existing schemes to provide more accurate andconvenient μ/p values was then introduced. The results from the program appears tobe tolerable.

  13. Two-photon absorption coefficient dichroism in Ⅱ-Ⅵ semiconductor crystals

    Institute of Scientific and Technical Information of China (English)

    Ma Guo-Hong; Ma Hong-Liang; Tang Sing-Hai

    2007-01-01

    Considering two beams propagate in semiconductor crystal, this paper discusses the polarization dependence of pump beam-induced intensity attenuation of probe beam due to two-photon absorption (TPA). Numerical calculation and experimental measurement demonstrate that TPA coefficient is polarization dependent. For homogeneous materials,probe beam attenuation arises from the imaginary part of diagonal and off-diagonal components of third-order nonlinear susceptibilities.

  14. INVERSE COMPUTATION OF OPTICAL-ABSORPTION COEFFICIENT IN INHOMOGENEOUS MATERIAL WITH VARIED THERMAL CONDUCTIVITY

    Institute of Scientific and Technical Information of China (English)

    ZhuJianxin

    2002-01-01

    In this paper,for an inhomogeneous material in which the thermal conductivity varies as a function of depth,an efficient treatment is proposed to inversely calculate the depth distribution of optical-absorption coefficient by the surface temperature of the material. It is demonstrated that the results of inverse computation by that method are more similar to the experimental ones measured by some destructive method. Thus ,the treatment is more feasible to nondestructively estimate the distribution.

  15. A Correction of Random Incidence Absorption Coefficients for the Angular Distribution of Acoustic Energy under Measurement Conditions

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2009-01-01

    tracing method for various room shapes and source positions. The averaged angular distribution is found to be similar to a Gaussian distribution. As a result, an angle-weighted absorption coefficient was proposed by considering the angular energy distribution to improve the agreement between...... the theoretical absorption coefficient and the reverberation room measurement. The angle-weighted absorption coefficient, together with the size correction, agrees satisfactorily with the measured absorption data by the reverberation chamber method. At high frequencies and for large samples, the averaged...... weighting corresponds well with the measurement, whereas at low frequencies and for small panels, the relatively flat distribution agrees better....

  16. Modeling of the Interminiband Absorption Coefficient in InGaN Quantum Dot Superlattices

    Directory of Open Access Journals (Sweden)

    Giovanni Giannoccaro

    2016-01-01

    Full Text Available In this paper, a model to estimate minibands and theinterminiband absorption coefficient for a wurtzite (WZ indium gallium nitride (InGaN self-assembled quantum dot superlattice (QDSL is developed. It considers a simplified cuboid shape for quantum dots (QDs. The semi-analytical investigation starts from evaluation through the three-dimensional (3D finite element method (FEM simulations of crystal mechanical deformation derived from heterostructure lattice mismatch under spontaneous and piezoelectric polarization effects. From these results, mean values in QDs and barrier regions of charge carriers’ electric potentials and effective masses for the conduction band (CB and three valence sub-bands for each direction are evaluated. For the minibands’ investigation, the single-particle time-independent Schrödinger equation in effective mass approximation is decoupled in three directions and resolved using the one-dimensional (1D Kronig–Penney model. The built-in electric field is also considered along the polar axis direction, obtaining Wannier–Stark ladders. Then, theinterminiband absorption coefficient in thermal equilibrium for transverse electric (TE and magnetic (TM incident light polarization is calculated using Fermi’s golden rule implementation based on a numerical integration into the first Brillouin zone. For more detailed results, an absorption coefficient component related to superlattice free excitons is also introduced. Finally, some simulation results, observations and comments are given.

  17. The influence of surface preparation on the absorption coefficient of laser radiation

    Science.gov (United States)

    Kurp, Piotr; Mucha, Zygmunt; Mulczyk, Krystian; Gradoń, Ryszard; Trela, Paweł

    2016-12-01

    The absorption coefficient of the surface of a workpiece is of importance in laser treatment, particularly in the treatment where the temperature of an element must be strictly controlled. Laser surface treatment (such as hardening, metallic glazing) and laser forming can be primarily included in this type of technology. In another case, surface temperature must be precisely controlled, especially if structural changes are to be avoided. There are a number of ways to increase the absorption coefficient of the surface of an element. Since the laser forming is the research subject of the authors of the presented paper, it was necessary to determine the absorption coefficient for the different surfaces preparation of workpieces. Raw surface, oxidized surface, sandblasted surface, black enamel covered surface and waterglass covered surface were examined, respectively. The experiment was performed using a CO2 laser with a head for a surface treatment which generates a rectangular beam of dimensions 2x20 mm, and the samples were made of X5CrNi18-10 stainless steel.

  18. Non-uniform sound intensity distributions when measuring absorption coefficients in reverberation chambers using a phased beam tracing

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2010-01-01

    intensity distributions above 1 kHz were similar for all studied cases, but some variations in low frequency intensity distributions were observed. If the non-uniform intensity distribution and a finite size effect are taken into account for correcting the theoretical absorption coefficients, a good......Measured absorption coefficients in reverberation chambers often differ from theoretical random incidence absorption coefficients, because ideal assumptions for the theoretical random incidence absorption coefficient are not fulfilled during measurements in actual reverberation chambers. Therefore...... sound intensity distributions on absorber under measurement conditions have been simulated using a phased beam tracing, and used as correction functions for reducing discrepancies between the measured and theoretical absorption coefficients. Two reverberation rooms were investigated by assuming...

  19. Dependence of dose coefficients for inhaled 239Pu on absorption parameters.

    Science.gov (United States)

    Suzuki, K; Sekimoto, H; Ishigure, N

    2001-01-01

    With regard to dissolution of particles in the respiratory tract after inhalation, the International Commission on Radiological Protection (ICRP) has classified all radionuclides into only three types according to the chemical form of compounds, and default values of absorption parameters are proposed for each type. However, it is just a simplification to estimate doses for practical use, and there is a possibility of unfitness in such an assortment. A code has been developed to reproduce the ICRP's dose coefficients for 239Pu, which is one of the most important elements for occupational exposure. By using this code, the respective absorption parameters were modified, and the effect owing to these changes evaluated. It was shown consequently that changes of absorption parameters do not greatly influence the effective doses of 239Pu for workers.

  20. Predicting the Sabine absorption coefficients of fibrous absorbers for various air backing conditions with a frequency-dependent diffuseness correction

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2016-01-01

    characteristics of their own configurations. This study aims to predict the absorption coefficient for various mounting conditions from a single measurement of an arbitrary mounting condition by extracting the air flow resistivity of the test specimen and the frequency-dependent effect of the chamber......Fibrous absorbers can be installed with various air backing conditions to fulfil a given low frequency acoustic requirement. Since absorber manufacturers cannot provide the absorption coefficients for all possible mounting conditions, acousticians have difficulties knowing the absorption...

  1. Absorption coefficient modeling of microcrystalline silicon thin film using Maxwell-Garnett effective medium theory.

    Science.gov (United States)

    Chen, Sheng-Hui; Wang, Hsuan-Wen; Chang, Ting-Wei

    2012-03-12

    Considering the Mott-Davis density of state model and Rayleigh scattering effect, we present an approach to model the absorption profile of microcrystalline silicon thin films in this paper. Maxwell-Garnett effective medium theory was applied to analyze the absorption curves. To validate the model, several experimental profiles have been established and compared with those results from the model. With the assistance of the genetic algorithm, our results show that the absorption curves from the model are in good agreement with the experiments. Our findings also indicate that, as the crystal volume fraction increases, not only do the defects in amorphous silicon reduce, but the bulk scattering effect is gradually enhanced as well.

  2. Methamphetamine absorption by skin lipids: accumulated mass, partition coefficients, and the influence of fatty acids.

    Science.gov (United States)

    Parker, K; Morrison, G

    2016-08-01

    Occupants of former methamphetamine laboratories, often residences, may experience increased exposure through the accumulation of the methamphetamine in the organic films that coat skin and indoor surfaces. The objectives of this study were to determine equilibrium partition coefficients of vapor-phase methamphetamine with artificial sebum (AS-1), artificial sebum without fatty acids (AS-2), and real skin surface films, herein called skin oils. Sebum and skin oil-coated filters were exposed to vapor-phase methamphetamine at concentrations ranging from 8 to 159 ppb, and samples were analyzed for exposure time periods from 2 h to 60 days. For a low vapor-phase methamphetamine concentration range of ~8-22 ppb, the equilibrium partition coefficient for AS-1 was 1500 ± 195 μg/g/ppb. For a high concentration range of 98-112 ppb, the partition coefficient was lower, 459 ± 80 μg/g/ppb, suggesting saturation of the available absorption capacity. The low partition coefficient for AS-2 (33 ± 6 μg/g/ppb) suggests that the fatty acids in AS-1 and skin oil are responsible for much high partition coefficients. We predict that the methamphetamine concentration in skin lipids coating indoor surfaces can exceed recommended surface remediation standards even for air concentrations well below 1 ppb.

  3. Pancreatic enzyme replacement therapy in cystic fibrosis: dose, variability and coefficient of fat absorption.

    Science.gov (United States)

    Calvo-Lerma, Joaquim; Martínez-Barona, Sandra; Masip, Etna; Fornés, Victoria; Ribes-Koninckx, Carmen

    2017-07-27

    Pancreatic enzyme replacement therapy (PERT) remains a backbone in the nutritional treatment of cystic fibrosis. Currently, there is a lack of an evidence-based tool that allows dose adjustment. To date, no studies have found an association between PERT dose and fat absorption. Therefore, the aim of the study was to assess the influence of both the PERT dose and the variability in this dose on the coefficient of fat absorption (CFA). This is a retrospective longitudinal study of 16 pediatric patients (192 food records) with three consecutive visits to the hospital over a twelve-month period. Dietary fat intake and PERT were assessed via a four-day food record and fat content in stools was determined by means of a three-day stool sample collection. A beta regression model was built to explain the association between the CFA and the interaction between the PERT dose (lipase units [LU]/g dietary fat) and the variability in the PERT dose (standard deviation [SD]). The coefficient of fat absorption increased with the PERT dose when the variability in the dose was low. In contrast, even at the highest PERT dose values, the CFA decreased when the variability was high. The confidence interval suggested an association, although the analysis was not statistically significant. The variability in the PERT dose adjustment should be taken into consideration when performing studies on PERT efficiency. A clinical goal should be the maintenance of a constant PERT dose rather than trying to obtain an optimal value.

  4. Sound absorption coefficient in situ: an alternative for estimating soil loss factors.

    Science.gov (United States)

    Freire, Rosane; Meletti de Abreu, Marco Henrique; Okada, Rafael Yuri; Soares, Paulo Fernando; GranhenTavares, Célia Regina

    2015-01-01

    The relationship between the sound absorption coefficient and factors of the Universal Soil Loss Equation (USLE) was determined in a section of the Maringá Stream basin, Paraná State, by using erosion plots. In the field, four erosion plots were built on a reduced scale, with dimensions of 2.0×12.5m. With respect to plot coverage, one was kept with bare soil and the others contained forage grass (Brachiaria), corn and wheat crops, respectively. Planting was performed without any type of conservation practice in an area with a 9% slope. A sedimentation tank was placed at the end of each plot to collect the material transported. For the acoustic system, pink noise was used in the measurement of the proposed monitoring, for collecting information on incident and reflected sound pressure levels. In general, obtained values of soil loss confirmed that 94.3% of material exported to the basin water came from the bare soil plot, 2.8% from the corn plot, 1.8% from the wheat plot, and 1.1% from the forage grass plot. With respect to the acoustic monitoring, results indicated that at 16kHz erosion plot coverage type had a significant influence on the sound absorption coefficient. High correlation coefficients were found in estimations of the A and C factors of the USLE, confirming that the acoustic technique is feasible for the determination of soil loss directly in the field.

  5. Determination of Kerr and two-photon absorption coefficients of indandione derivatives

    Science.gov (United States)

    Bundulis, Arturs; Mihailovs, Igors; Nitiss, Edgars; Busenbergs, Janis; Rutkis, Martins

    2017-05-01

    We studied nonlinear optical properties of two different aminobenziliden-1,3-indandione derivatives - DDMABI and DMABI-OH by employing the Z-scan method. Through this we described how different donor and acceptor groups influence third-order nonlinear optical properties such as Kerr effect and two-photon absorption. During experimental measurements we used 1064 nm Nd:YAG laser with 30 ps pulse duration and 10 Hz repetition rate. From acquired values of Kerr and two-photon absorption coefficients we calculated values for real and imaginary parts of third-order susceptibility, as well as second-order hyperpolarizability. Quantum chemical calculations were carried out for secondorder hyperpolarizability to study how well calculations correlate with experimental values. Acquired data for DDMABI and DMABI-OH were compared with data for other ABI derivatives studied previously.

  6. Measurement of the absorption coefficient of a glucose solution through transmission of light and polarymetry techniques

    Science.gov (United States)

    Yáñez M., J.

    2011-10-01

    Diabetes is a disease with no cure, but can be controlled to improve the quality of life of sufferers. Currently there are means to control, but this means they have the disadvantage that in order to measure the amount of glucose is necessary to take blood samples that are painful. This paper presents a system for measuring glucose using non-invasive optical techniques: using absorption spectroscopy and polarimetry technique. It shows the results obtained from experiments done on samples containing distilled water and different amounts of glucose to study the absorption coefficient of glucose with both techniques. Water is used because it is one of the main elements in the blood and interferes with glucose measurement. This experiment will develop a prototype to measure glucose through a non-invasive technique.

  7. Water in the Earth's Mantle: Mineral-specific IR Absorption Coefficients and Radiative Thermal Conductivities

    Science.gov (United States)

    Thomas, S. M.

    2015-12-01

    Minor and trace element chemistry, phase relations, rheology, thermal structure and the role of volatiles and their abundance in the deep Earth mantle are still far from fully explored, but fundamental to understanding the processes involved in Earth formation and evolution. Theory and high pressure experiments imply a significant water storage capacity of nominally anhydrous minerals, such as majoritic garnet, olivine, wadsleyite and ringwoodite, composing the Earth's upper mantle and transition zone to a depth of 660 km. Studying the effect of water incorporation on chemical and physical mineral properties is of importance, because the presence of trace amounts of water, incorporated as OH through charge-coupled chemical substitutions into such nominally anhydrous high-pressure silicates, notably influences phase relations, melting behavior, conductivity, elasticity, viscosity and rheology. Knowledge of absolute water contents in nominally anhydrous minerals is essential for modeling the Earth's interior water cycle. One of the most common and sensitive tools for water quantification is IR spectroscopy for which mineral-specific absorption coefficients are required. Such calibration constants can be derived from hydrogen concentrations determined by independent techniques, such as secondary ion mass spectrometry, Raman spectroscopy or proton-proton(pp)-scattering. Here, analytical advances and mineral-specific IR absorption coefficients for the quantification of H2O in major phases of the Earth's mantle will be discussed. Furthermore, new data from optical absorption measurements in resistively heated diamond-anvil cells at high pressures and temperatures up to 1000 K will be presented. Experiments were performed on synthetic single-crystals of olivine, ringwoodite, majoritic garnet, and Al-bearing phase D with varying iron, aluminum and OH contents to calculate radiative thermal conductivities and study their contribution to heat transfer in the Earth's interior

  8. The coefficient of bond thermal expansion measured by extended x-ray absorption fine structure.

    Science.gov (United States)

    Fornasini, P; Grisenti, R

    2014-10-28

    The bond thermal expansion is in principle different from the lattice expansion and can be measured by correlation sensitive probes such as extended x-ray absorption fine structure (EXAFS) and diffuse scattering. The temperature dependence of the coefficient α(bond)(T) of bond thermal expansion has been obtained from EXAFS for CdTe and for Cu. A coefficient α(tens)(T) of negative expansion due to tension effects has been calculated from the comparison of bond and lattice expansions. Negative lattice expansion is present in temperature intervals where α(bond) prevails over α(tens); this real-space approach is complementary but not equivalent to the Grüneisen theory. The relevance of taking into account the asymmetry of the nearest-neighbours distribution of distances in order to get reliable bond expansion values and the physical meaning of the third cumulant are thoroughly discussed.

  9. Linear absorption coefficient of in-plane graphene on a silicon microring resonator

    CERN Document Server

    Cai, Heng; Zhang, He; Huang, Qingzhong; Xia, Jinsong; Barille, Regis; Wang, Yi

    2016-01-01

    We demonstrate that linear absorption coefficient (LAC) of a graphene-silicon hybrid waveguide (GSHW) is determined by the optical transmission spectra of a graphene coated symmetrically coupled add-drop silicon microring resonator (SC-ADSMR), of which the value is around 0.23 dB/um. In contrast to the traditional cut-back method, the measured results are not dependent on the coupling efficiency of the fiber tip and the waveguide. Moreover, precision evaluation of graphene coated silicon microring resonator (SMR) is crucial for the optoelectronic devices targeting for compact footprint and low power consumption.

  10. The effect of metal nano particle on optical absorption coefficient of multi-layer spherical quantum dot

    Energy Technology Data Exchange (ETDEWEB)

    Zamani, N., E-mail: n.zamani@sutech.ac.ir [Department of Physics, College of Science, Shiraz University, Shiraz 71454 (Iran, Islamic Republic of); Keshavarz, A., E-mail: keshavarz@sutech.ac.ir [Department of Physics, Shiraz University of Technology, Shiraz 71555-313 (Iran, Islamic Republic of); Nadgaran, H., E-mail: nadgaran@susc.ac.ir [Department of Physics, College of Science, Shiraz University, Shiraz 71454 (Iran, Islamic Republic of)

    2016-06-01

    In this paper, we investigate the optical absorption coefficient of hybrid structure consisting of metal nano particle (MNP) coupled to multi-layer spherical quantum dot (MSQD). Energy eigenvalues and eigenfunctions of Schrödinger equation in this structure are obtained by using numerical solution (by the fourth-order Runge–Kutta method). The effect of MNP in the vicinity of MSQD is calculated by considering local field theory. Then the variation of optical absorption coefficient hybrid structure is calculated. The results show that the presence of MNP near MSQD enhances the optical absorption coefficient. Also, by changing the distance between MNP and MSQD and radius of MNP, variation of optical absorption coefficient and refractive index changes are introduced.

  11. The effect of metal nano particle on optical absorption coefficient of multi-layer spherical quantum dot

    Science.gov (United States)

    Zamani, N.; Keshavarz, A.; Nadgaran, H.

    2016-06-01

    In this paper, we investigate the optical absorption coefficient of hybrid structure consisting of metal nano particle (MNP) coupled to multi-layer spherical quantum dot (MSQD). Energy eigenvalues and eigenfunctions of Schrödinger equation in this structure are obtained by using numerical solution (by the fourth-order Runge-Kutta method). The effect of MNP in the vicinity of MSQD is calculated by considering local field theory. Then the variation of optical absorption coefficient hybrid structure is calculated. The results show that the presence of MNP near MSQD enhances the optical absorption coefficient. Also, by changing the distance between MNP and MSQD and radius of MNP, variation of optical absorption coefficient and refractive index changes are introduced.

  12. Density, ultrasound velocity, acoustic impedance, reflection and absorption coefficient determination of liquids via multiple reflection method.

    Science.gov (United States)

    Hoche, S; Hussein, M A; Becker, T

    2015-03-01

    The accuracy of density, reflection coefficient, and acoustic impedance determination via multiple reflection method was validated experimentally. The ternary system water-maltose-ethanol was used to execute a systematic, temperature dependent study over a wide range of densities and viscosities aiming an application as inline sensor in beverage industries. The validation results of the presented method and setup show root mean square errors of: 1.201E-3 g cm(-3) (±0.12%) density, 0.515E-3 (0.15%) reflection coefficient and 1.851E+3 kg s(-1) m(-2) (0.12%) specific acoustic impedance. The results of the diffraction corrected absorption showed an average standard deviation of only 0.12%. It was found that the absorption change shows a good correlation to concentration variations and may be useful for laboratory analysis of sufficiently pure liquids. The main part of the observed errors can be explained by the observed noise, temperature variation and the low signal resolution of 50 MHz. In particular, the poor signal-to-noise ratio of the second reflector echo was found to be a main accuracy limitation. Concerning the investigation of liquids the unstable properties of the reference material PMMA, due to hygroscopicity, were identified to be an additional, unpredictable source of uncertainty. While dimensional changes can be considered by adequate methodology, the impact of the time and temperature dependent water absorption on relevant reference properties like the buffer's sound velocity and density could not be considered and may explain part of the observed deviations.

  13. The Optical Absorption Coefficient of Bean Seeds Investigated Using Photoacoustic Spectroscopy

    Science.gov (United States)

    Sanchez-Hernandez, G.; Hernandez-Aguilar, C.; Dominguez-Pacheco, A.; Cruz-Orea, A.; Perez-Reyes, M. C. J.; Martinez, E. Moreno

    2015-06-01

    A knowledge about seed optical parameters is of great relevance in seed technology practice. Such parameters provide information about its absorption and reflectance, which could be useful for biostimulation processes, by light sources, in early stages of seed germination. In the present research photoacoustic spectroscopy (PAS) and the Rosencwaig and Gersho model were used to determine the optical absorption coefficient () of five varieties of bean seeds ( Phaseolus vulgaris L.), of different productive cycles; the seeds were biostimulated by laser treatment to evaluate the effects of biostimulation pre-sowing. It was found that the bean varieties V1, V2, V4, and V5 were optically opaque in the visible spectrum; in the case of the V3 variety, this sample was optically transparent from 680 nm. The varieties of the studied bean seeds showed significant statistical differences in sizes and also in their optical absorption spectra. The biostimulation effects showed that the seed samples with a higher optical penetration length had a positive biostimulation, in the percentage of germination, obtaining an enhancement of 47 % compared to the control sample. The utility of PAS for the optical characterization of seeds has been demonstrated in this study of the laser biostimulation process of this kind of samples.

  14. Carbonation Coefficients from Concrete Made with High-Absorption Limestone Aggregate

    Directory of Open Access Journals (Sweden)

    Eric I. Moreno

    2013-01-01

    Full Text Available Normal aggregates employed in concrete have absorption levels in the range of 0.2% to 4% for coarse aggregate and 0.2 to 2% for fine aggregate. However, some aggregates have absorption levels above these values. As the porosity of concrete is related to the porosity of both the cement paste and the aggregate and the carbonation rate is a function, among other things, of the porosity of the material, there is concern about the effect of this high porosity material in achieving good quality concrete from the durability point of view. Thus, the objective of this investigation was to study the carbonation rates of concrete specimens made with high-absorption limestone aggregate. Four different water/cement ratios were used, and cylindrical concrete specimens were exposed to accelerated carbonation. High porosity values were obtained for concrete specimens beyond the expected limits for durable concrete. However, carbonation coefficients related to normal quality concrete were obtained for the lowest water/cement ratio employed suggesting that durable concrete may be obtained with this material despite the high porosity.

  15. Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings at Elevated Temperatures

    Science.gov (United States)

    Eldridge, Jeffrey I.; Spuckler, Charles M.; Markham, James R.

    2009-01-01

    The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360 C in a wavelength range from 1.2 micrometers up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (less than 1 per centimeter) at wavelengths between 2 micrometers and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as edge to shorter wavelengths."

  16. A Correction of Random Incidence Absorption Coefficients for the Angular Distribution of Acoustic Energy under Measurement Conditions

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2009-01-01

    Most acoustic measurements are based on an assumption of ideal conditions. One such ideal condition is a diffuse and reverberant field. In practice, a perfectly diffuse sound field cannot be achieved in a reverberation chamber. Uneven incident energy density under measurement conditions can cause...... discrepancies between the measured value and the theoretical random incidence absorption coefficient. Therefore the angular distribution of the incident acoustic energy onto an absorber sample should be taken into account. The angular distribution of the incident energy density was simulated using the beam...... the theoretical absorption coefficient and the reverberation room measurement. The angle-weighted absorption coefficient, together with the size correction, agrees satisfactorily with the measured absorption data by the reverberation chamber method. At high frequencies and for large samples, the averaged...

  17. Experimental investigation of X-ray spectral absorption coefficients in heated Al and Ge on the Iskra-5 laser facility

    Energy Technology Data Exchange (ETDEWEB)

    Bondarenko, S V; Garanin, Sergey G; Zhidkov, N V; Pinegin, A V; Suslov, N A [Russian Federal Nuclear Center ' All-Russian Research Institute of Experimental Physics' , Sarov, Nizhnii Novgorod region (Russian Federation)

    2012-01-31

    We set forth the data of experimental investigation of X-ray spectral absorption coefficients in the 1.1 - 1.6 keV photon energy range for Al and Ge specimens bulk heated by soft X-ray radiation. Two experimental techniques are described: with the use of one facility channel and the heating of specimens by the X-ray radiation from a plane burnthrough target, as well as with the use of four channels and the heating by the radiation from two cylindrical targets with internal input of laser radiation. The X-ray radiation absorption coefficients were studied by way of transmission absorption spectroscopy using backlighting X-ray radiation from a point source. The results of investigation of X-ray spectral absorption coefficients on the 1s - 2p transitions in Al atoms and the 2p - 3d transitions in Ge atoms are presented.

  18. Experimental investigation of X-ray spectral absorption coefficients in heated Al and Ge on the Iskra-5 laser facility

    Science.gov (United States)

    Bondarenko, S. V.; Garanin, Sergey G.; Zhidkov, N. V.; Pinegin, A. V.; Suslov, N. A.

    2012-01-01

    We set forth the data of experimental investigation of X-ray spectral absorption coefficients in the 1.1 — 1.6 keV photon energy range for Al and Ge specimens bulk heated by soft X-ray radiation. Two experimental techniques are described: with the use of one facility channel and the heating of specimens by the X-ray radiation from a plane burnthrough target, as well as with the use of four channels and the heating by the radiation from two cylindrical targets with internal input of laser radiation. The X-ray radiation absorption coefficients were studied by way of transmission absorption spectroscopy using backlighting X-ray radiation from a point source. The results of investigation of X-ray spectral absorption coefficients on the 1s — 2p transitions in Al atoms and the 2p — 3d transitions in Ge atoms are presented.

  19. Coefficient of Performance Optimization of Single-Effect Lithium-Bromide Absorption Cycle Heat Pumps

    DEFF Research Database (Denmark)

    Vinther, Kasper; Just Nielsen, Rene; Nielsen, Kirsten Mølgaard

    2015-01-01

    In this paper, we investigate the coefficient of performance (COP) of a LiBr absorption cycle heat pump under different operating conditions. The investigation is carried out using a dynamical model fitted against data recorded from an actual heat pump used for district heating in S......⊘nderborg, Denmark. Since the model is too complex to study analytically, we vary different input variables within the permissible operating range of the heat pump and evaluate COP at the resulting steady-state operating points. It is found that the best set-point for each individual input is located at an extreme......-state operation of the heat pump, while avoiding crystallization issues....

  20. Magnetic resonance imaging of acoustic streaming: absorption coefficient and acoustic field shape estimation.

    Science.gov (United States)

    Madelin, Guillaume; Grucker, Daniel; Franconi, Jean-Michel; Thiaudiere, Eric

    2006-07-01

    In this study, magnetic resonance imaging (MRI) is used to visualize acoustic streaming in liquids. A single-shot spin echo sequence (HASTE) with a saturation band perpendicular to the acoustic beam permits the acquisition of an instantaneous image of the flow due to the application of ultrasound. An average acoustic streaming velocity can be estimated from the MR images, from which the ultrasonic absorption coefficient and the bulk viscosity of different glycerol-water mixtures can be deduced. In the same way, this MRI method could be used to assess the acoustic field and time-average power of ultrasonic transducers in water (or other liquids with known physical properties), after calibration of a geometrical parameter that is dependent on the experimental setup.

  1. The Optical Absorption Coefficient of Maize Grains Investigated by Photoacoustic Spectroscopy

    Science.gov (United States)

    Rodríguez-Páez, C. L.; Carballo-Carballo, A.; Rico-Molina, R.; Hernández-Aguilar, C.; Domínguez-Pacheco, A.; Cruz-Orea, A.; Moreno-Martínez, E.

    2017-01-01

    In the maize and tortilla industry, it is important to characterize the color of maize ( Zea mays L.) grain, as it is one of the attributes that directly affect the quality of the tortillas consumed by the population. For this reason, the availability of alternative techniques for assessing and improving the quality of grain is valued. Photoacoustic spectroscopy has proven to be a useful tool for characterizing maize grain. So, the objective of the present study was to determine the optical absorption coefficient β of the maize grain used to make tortillas from two regions of Mexico: (a) Valles Altos, 2012-2013 production cycle and (b) Guasave, Sinaloa, 2013-2014 production cycle. Traditional reflectance measurements, physical characteristics of the grain and nutrient content were also calculated. The experimental results show different characteristics for maize grains.

  2. Remote sensing retrieval of total absorption coefficient in the Bohai Sea

    Institute of Scientific and Technical Information of China (English)

    QING Song; ZHANG Jie; CUI Tingwei; BAO Yuhai

    2012-01-01

    Temporal and spatial patterns of inherent optical properties in the Bohai Sea are very complex.In this paper,we used 77 groups of field data of AOPs(apparent optical properties)and lOPs(inherent optical properties)collected in June,August,and September of 2005 in the Bohai Sea,to retrieve the spectral total absorption coefficient a(λ)with the quasi-analytical algorithm(QAA).For QAA implementation,different bands in the region 680-730 nm(in 5 nm intervals)were selected and compared,to determine the optimal band domain of the reference wavelength.On this basis,we proposed a new algorithm(QAA-Com),a combination of QAA-685 and QAA-715,according to turbidity characterized by a(440).The percentage difference of model retrievals in the visible domain was between 4.5%-45.1%,in average of 18.8% for a(λ).The QAA model was then applied to Medium Resolution Imaging Spectrometer(MERIS)radiometric products,which were temporally and spatially matched with in-situ optical measurements.Differences between MERIS retrievals and in-situ values were in the range 9.2%-27.8% for a(λ)in the visible domain.Major errors in satellite retrieval are attributable to uncertainties of QAA model parameters and in-situ measurements,as well as imperfect atmospheric correction of MERIS data by the European Space Agency (ESA).During a storm surge in April 2009,time series of MERIS images together with the QAA model were used to analyze spatial and temporal variability of the total absorption coefficient pattern in the Bohai Sea.It is necessary to collect more independent field data to improve this algorithm.

  3. Ultra-low values of the absorption coefficient for band-band transitions in moderately doped Si obtained from luminescence

    Science.gov (United States)

    Daub, E.; Würfel, P.

    1996-11-01

    The absolute value of the absorption coefficient αbb(ℏω) for band-band transitions near the band edge was determined in moderately doped silicon by photoluminescence spectra analysis. The major advantage of this method in determining αbb(ℏω) is the lack of interference with free carrier absorption, in contrast to conventional methods like transmission or photothermal deflection measurements. We deduce values for αbb(ℏω), which are nearly five orders of magnitude smaller than the absorption coefficient αfc(ℏω) for free carrier absorption. With this method it is possible to examine in detail the influence of doping on the absorption coefficient for band-band transitions near the absorption edge. The appearance of band tails and band-gap narrowing are very well reflected. With conventional methods, which can only detect the overall absorption of the incident radiation, the determination of αbb(ℏω) in the vicinity of the band edge is impossible for moderately and heavily doped silicon, because it is completely masked by the free carrier absorption.

  4. Determination of air-loop volume and radon partition coefficient for measuring radon in water sample.

    Science.gov (United States)

    Lee, Kil Yong; Burnett, William C

    A simple method for the direct determination of the air-loop volume in a RAD7 system as well as the radon partition coefficient was developed allowing for an accurate measurement of the radon activity in any type of water. The air-loop volume may be measured directly using an external radon source and an empty bottle with a precisely measured volume. The partition coefficient and activity of radon in the water sample may then be determined via the RAD7 using the determined air-loop volume. Activity ratios instead of absolute activities were used to measure the air-loop volume and the radon partition coefficient. In order to verify this approach, we measured the radon partition coefficient in deionized water in the temperature range of 10-30 °C and compared the values to those calculated from the well-known Weigel equation. The results were within 5 % variance throughout the temperature range. We also applied the approach for measurement of the radon partition coefficient in synthetic saline water (0-75 ppt salinity) as well as tap water. The radon activity of the tap water sample was determined by this method as well as the standard RAD-H2O and BigBottle RAD-H2O. The results have shown good agreement between this method and the standard methods.

  5. Dependence of dose coefficients for {sup 239}Pu on transfer rates and absorption parameters

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, K.; Sekimoto, H. [Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, Tokyo (Japan); Ishigure, N. [Division of Radiotoxicology and Protection, National Institute of Radiological Sciences, Chiba (Japan)

    2000-05-01

    As it is reported of the biokinetic models and parameter values of the International Commission on Radiological Protection (ICRP) for dose estimation have uncertainties owing to insufficiency of human data. For most radionuclides, the data underlying such models and parameters of ICRP usually depend on animal experiments. Moreover, these values or model parameter are also greatly different between mammalian species. Recently, various radiation protection organizations are considering the biokinetic uncertainties from standpoints of data's sources, quality and completeness. In practice, a sensitivity analysis of doses to parameters is significant for the purpose of risk assessment. In general, movement or material in the body is depicted as a system of first-order processes, and parameter values are expressed as transfer rates between compartments. In this study, we made a code to reproduce the ICRP's dose coefficients for {sup 239}Pu, which is one of the most important elements for occupational exposure and its effective dose is much concerned with its own distribution in the body for dominance of alpha-decay. By using this code, we modified each transfer rate in a factor of 2, 3 and 4 in order to evaluate the effects, and calculated the sensitivities of effective doses due to these changes. Additionally, we examined the effects of modification of absorption parameters f{sub r}, S{sub r} and S{sub s}, which represent the absorption of particles from respiratory tract into blood. Consequently, the transfer rates that give a large sensitivity were specified, and it was shown that changes of transfer rates and absorption parameters are not so influential on effective doses for {sup 239}Pu in many cases. (author)

  6. Analytical modeling of photon absorption coefficient in mono and bilayer circular graphene quantum dots for light absorber applications

    Science.gov (United States)

    Tamandani, Shahryar; Darvish, Ghafar

    2017-02-01

    We present an analytical method to calculate photon absorption coefficient in mono and bilayer circular graphene quantum dots (CGQDs). We use kobo equation to extract new closed relation as the main goal. First, we calculate real and imaginary part of optical conductance separately. Then, joint density of states is obtained using a new relation that was extracted for the energy levels of mono and bilayer circular grapheme quantum dots. In this work we use closed equations to calculate energy levels in CGQDs. Next we obtain a new closed formula to calculate the photon absorption coefficient. The results show that the absorption coefficient is related to the size of CGQDs and number of layers. The photon absorption coefficient becomes lower with larger size of CGQDs. It is seen that the results of our method is compatible with the results of practical works. We also compare photon absorption in biased and unbiased bilayer CGQDs and investigate the effect of external magnetic field on photon absorption. rights reserved

  7. Dependence of microwave absorption properties on ferrite volume fraction in MnZn ferrite/rubber radar absorbing materials

    Energy Technology Data Exchange (ETDEWEB)

    Gama, Adriana M., E-mail: adrianaamg@iae.cta.br [Divisao de Materiais (AMR), Instituto de Aeronautica e Espaco (IAE), Departamento de Ciencia e Tecnologia Aeroespacial - DCTA (Brazil); Rezende, Mirabel C., E-mail: mirabelmcr@iae.cta.br [Divisao de Materiais (AMR), Instituto de Aeronautica e Espaco (IAE), Departamento de Ciencia e Tecnologia Aeroespacial - DCTA (Brazil); Dantas, Christine C., E-mail: christineccd@iae.cta.br [Divisao de Materiais (AMR), Instituto de Aeronautica e Espaco (IAE), Departamento de Ciencia e Tecnologia Aeroespacial - DCTA (Brazil)

    2011-11-15

    We report the analysis of measurements of the complex magnetic permeability ({mu}{sub r}) and dielectric permittivity ({epsilon}{sub r}) spectra of a rubber radar absorbing material (RAM) with various MnZn ferrite volume fractions. The transmission/reflection measurements were carried out in a vector network analyzer. Optimum conditions for the maximum microwave absorption were determined by substituting the complex permeability and permittivity in the impedance matching equation. Both the MnZn ferrite content and the RAM thickness effects on the microwave absorption properties, in the frequency range of 2-18 GHz, were evaluated. The results show that the complex permeability and permittivity spectra of the RAM increase directly with the ferrite volume fraction. Reflection loss calculations by the impedance matching degree (reflection coefficient) show the dependence of this parameter on both thickness and composition of RAM. - Highlights: > Permeability and permittivity spectra of a MnZn ferrite RAM (2-18 GHz) are given. > Higher MnZn volume fraction favors increase of RAM/'s permeability and permittivity. > Minimum RL as a function of frequency, thickness and MnZn volume fraction given. > Higher thicknesses imply better absorption; optimum band shifts to lower frequencies. > For higher volume fractions, smaller thickness might offer better absorption (>10 GHz).

  8. Absorption Coefficient, Molecular Composition, and Photodegradation of Different Types of Brown Carbon Aerosols

    Science.gov (United States)

    Lee, H. J.; Aiona, P. K.; Nizkorodov, S.; Laskin, J.; Laskin, A.

    2014-12-01

    Atmospheric aerosols that absorb solar radiation have a direct effect on climate. Brown carbon (BrC) represents the type of carbonaceous aerosols characterized by large absorption coefficients in the near-UV range of the spectrum. BrC can be either directly emitted into the atmosphere from combustion sources, or be formed in the atmosphere through multi-phase reactions, such as aging of secondary organic aerosols (SOA) mediated by ammonium sulfate (AS). Under the conditions of exposure to solar radiation, both primary and secondary BrC can potentially change their molecular composition and optical properties as a result of photodegradation of chromophoric compounds. This presentation will discuss the molecular level composition, the absorption and fluorescence spectra, and the mechanism of photodegradation among several representative types of BrC. The primary BrC samples include aerosol produced by smoldering wood combustion. The secondary BrC samples include AS aged products of chamber-generated SOA, products of reaction between methylglyoxal and AS, and SOA produced by the hogh-NOx photooxdiation of aromatic compounds, such as naphthalene. This presentation will also include preliminary data on the absorption and fluorescence spectra of photo-degraded bioaerosols. In all cases, absorption spectra of extracted bulk samples are measured during irradiation by a known flux of UV or visible light. The molecular level composition of the fresh and photobleached samples are characterized by high-resolution electrospray ionization mass spectrometry (HR-ESI-MS). Photobleaching of BrC is found to occur over a range of atmospherically relevant time scales. In many cases, the molecular level composition of photobleached BrC exhibits only subtle changes suggesting that the optical and fluorescence properties of BrC are controlled by a few compounds present in low quantities. The observed fluorescence from non-biological BrC indicates potential issues in using fluorescence

  9. Boundary Element Method for Reconstructing Absorption and Diffusion Coefficients of Biological Tissues in DOT/MicroCT Imaging.

    Science.gov (United States)

    Xie, Wenhao; Deng, Yong; Lian, Lichao; Yan, Dongmei; Yang, Xiaoquan; Luo, Qingming

    2016-01-01

    The functional information, the absorption and diffusion coefficients, as well as the structural information of biological tissues can be provided by the DOT(Diffuse Optical Tomograph)/MicroCT. In this paper, we use boundary element method to calculate the forward problem of DOT based on the structure prior given by the MicroCT, and then we reconstruct the absorption and diffusion coefficients of different biological tissues by the Levenberg-Marquardt algorithm. The method only needs surface meshing, reducing the complexity of calculation; in addition, it reconstructs a single value within an organ, which reduces the ill-posedness of the inverse problem to make reconstruction results have good noise stability. This indicates that the boundary element method-based reconstruction can serve as an new scheme for getting absorption and diffusion coefficients in DOT/MicroCT multimodality imaging.

  10. Quantitative absorption cytometry for measuring red blood cell hemoglobin mass and volume.

    Science.gov (United States)

    Schonbrun, Ethan; Malka, Roy; Di Caprio, Giuseppe; Schaak, Diane; Higgins, John M

    2014-04-01

    We present an optical system, called the quantitative absorption cytometer (QAC), to measure the volume and hemoglobin mass of red blood cells flowing through a microfluidic channel. In contrast to clinical hematology analyzers, where cells are sphered in order for both volume and hemoglobin to be measured accurately, the QAC measures cells in their normal physiological shape. Human red blood cells are suspended in a refractive index-matching absorbing buffer, driven through a microfluidic channel, and imaged using a transmission light microscope onto a color camera. A red and a blue LED illuminate cells and images at each color are used to independently retrieve cell volume and hemoglobin mass. This system shows good agreement with red blood cell indices retrieved by a clinical hematology analyzer and in fact measures a smaller coefficient of variation of hemoglobin concentration. In addition to cell indices, the QAC returns height and mass maps of each measured cell. These quantitative images are valuable for analyzing the detailed morphology of individual cells as well as statistical outliers found in the data. We also measured red blood cells in hypertonic and hypotonic buffers to quantify the correlation between volume and hemoglobin mass under osmotic stress. Because this method is invariant to cell shape, even extremely nonspherical cells in hypertonic buffers can be measured accurately.

  11. Study on absorption coefficients of dual-energy γ-rays in determining phase fractions of multiphase flows

    Institute of Scientific and Technical Information of China (English)

    LI Zhi-biao; LI Dong-hui; WU Ying-xiang

    2005-01-01

    This paper discusses the principle and mathematical method to measure the phase fractions of multiphase flows by using a dual-energy gamma-ray system. The dual-energy gamma-ray device is composed of radioactive isotopes of 241Am and 137Cs with emission energies of 59.5 keV and 662 keV respectively. A rational method to calibrate the absorption coefficient was introduced in detail. The statistical error has been analyzed on the basis of the accurate absorption coefficient which enables determination phrase fractions almost independent of the flow regime. Improvement has been achieved on the measurement accuracy of phase fractions.

  12. Low temperature FIR and submm mass absorption coefficient of interstellar silicate dust analogues

    CERN Document Server

    Coupeaud, A; Meny, C; Nayral, C; Delpech, F; Leroux, H; Depecker, C; Creff, G; Brubach, J B; Roy, P

    2011-01-01

    Cold dust grains emission in the FIR/submm is usually expressed as a modified black body law in which the dust mass absorption coefficient (MAC), is described with a temperature- and wavelength-independent emissivity spectral index, beta. However, numerous data from space and balloon-born missions and recently from Herschel and Planck show that dust emission is not well understood, as revealed by the observed anti-correlation of beta with the grain temperature. In order to give astronomers the necessary data to interpret FIR/submm observations, we synthesised analogues of interstellar amorphous and crystalline silicate grains, rich in Mg and Ca, and having stiochiometry of olivine and pyroxene and measured their MAC, in the 100-1000/1500 \\mum range for grain temperatures varying from 300 to 10 K. We find that the grain MAC decreases when the grain temperature decreases and that the local spectral index, beta, defined as the slope of the MAC curve, is anti-correlated with the grain temperature. These variation...

  13. Noise-driven optical absorption coefficients of impurity doped quantum dots

    Science.gov (United States)

    Ganguly, Jayanta; Saha, Surajit; Pal, Suvajit; Ghosh, Manas

    2016-01-01

    We make an extensive investigation of linear, third-order nonlinear, and total optical absorption coefficients (ACs) of impurity doped quantum dots (QDs) in presence and absence of noise. The noise invoked in the present study is a Gaussian white noise. The quantum dot is doped with repulsive Gaussian impurity. Noise has been introduced to the system additively and multiplicatively. A perpendicular magnetic field acts as a source of confinement and a static external electric field has been applied. The AC profiles have been studied as a function of incident photon energy when several important parameters such as optical intensity, electric field strength, magnetic field strength, confinement energy, dopant location, relaxation time, Al concentration, dopant potential, and noise strength take on different values. In addition, the role of mode of application of noise (additive/multiplicative) on the AC profiles has also been analyzed meticulously. The AC profiles often consist of a number of interesting observations such as one photon resonance enhancement, shift of AC peak position, variation of AC peak intensity, and bleaching of AC peak. However, presence of noise alters the features of AC profiles and leads to some interesting manifestations. Multiplicative noise brings about more complexity in the AC profiles than its additive counterpart. The observations indeed illuminate several useful aspects in the study of linear and nonlinear optical properties of doped QD systems, specially in presence of noise. The findings are expected to be quite relevant from a technological perspective.

  14. Refractive Index and Absorption Coefficient of Undoped and Mg-Doped Lithium Tantalate in the Terahertz Range

    Science.gov (United States)

    Buzády, Andrea; Unferdorben, Márta; Tóth, György; Hebling, János; Hajdara, Ivett; Kovács, László; Pálfalvi, László

    2017-08-01

    Dielectric material parameters of lithium tantalate (LT) in the terahertz region have been investigated using terahertz time-domain spectroscopy (THz-TDS). Undoped congruent, undoped stoichiometric, and Mg-doped stoichiometric LT crystals were measured. The Mg content was 0.5 and 1.0 mol% for the stoichiometric composition. Index of refraction and absorption coefficient spectra were determined in the 0.3-2.0-THz frequency range for beam polarization both parallel (extraordinary polarization) and perpendicular (ordinary polarization) to the optical axis [001] of the crystal at room temperature. For the calculation of the refractive index and absorption coefficient spectra from the measured data, we used TeraMat software (Menlo System) belonging to the spectrometer. The refractive index and the absorption coefficient for stoichiometric crystals were lower than for the congruent one. In the case of stoichiometric crystals, the Mg dopant caused a slight reduction of both ordinary and extraordinary refractive index compared to the undoped crystal. However, the presence of Mg did not reduce the absorption coefficient either for the ordinary or for the extraordinary polarization. In order to fit the measurement data, a Lorentz oscillator model was used. Good agreement was obtained between the measured data and the fitting curves by using the Lorentz oscillator model containing three terms.

  15. Pancreatic Enzyme Therapy and Coefficient of Fat Absorption in Children and AdolReplacement escents With Cystic Fibrosis

    NARCIS (Netherlands)

    Woestenenk, Janna W; van der Ent, Cornelis K.; Houwen, Roderick H J; van der Ent, CK

    2015-01-01

    Objectives: Pancreatic enzyme replacement therapy (PERT) is the proven therapy to substantially reduce fat malabsorption in patients with cystic fibrosis (CF). Few details of the daily practice regarding PERT and the resulting coefficient of fat absorption (CFA) are known. We therefore recorded the

  16. Pancreatic Enzyme Therapy and Coefficient of Fat Absorption in Children and AdolReplacement escents With Cystic Fibrosis

    NARCIS (Netherlands)

    Woestenenk, Janna W; van der Ent, Cornelis K.; Houwen, Roderick H J; van der Ent, CK

    Objectives: Pancreatic enzyme replacement therapy (PERT) is the proven therapy to substantially reduce fat malabsorption in patients with cystic fibrosis (CF). Few details of the daily practice regarding PERT and the resulting coefficient of fat absorption (CFA) are known. We therefore recorded the

  17. Investigation of linear optical absorption coefficients in core-shell quantum dot (QD) luminescent solar concentrators (LSCs)

    Science.gov (United States)

    Ebrahimipour, Bahareh Alsadat; Askari, Hassan Ranjbar; Ramezani, Ali Behjat

    2016-09-01

    The interlevel absorption coefficient of CdSe/ZnS and ZnS/CdSe core-shell Quantum Dot (QD) in luminescent solar concentrators (LSCs) is reported. By considering the quantum confinement effects, the wave functions and eigenenergies of electrons in the nonperturebative system consists of a core-shell QD have been numerically calculated under the frame work of effective-mass approximation by solving a three-dimensional Schrӧdinger equation. And then the absorption coefficient is obtained under density matrix approximation considering in the polymer sheets of the concentrator including the core-shell QDs. The effect of the hetero-structure geometry upon the energy spectrum and absorption coefficient associated to interlevel transitions was also considered. The results show that the core-shell QDs can absorb the photons with higher energy in solar spectrum as compared to the inverted core-shell. And with a small shell layer diameter, the core-shell QDs produce larger linear absorption coefficients and consequently higher efficiency values, however it is inversed for inverted core-shell QDs. The work described here gives a detailed insight into the promise of QD-based LSCs and the optoelectronic devices applications.

  18. Multiyear Measurements of the Aerosol Absorption Coefficient Near the Surface in a Small-Sized Urban Area in Portugal

    Directory of Open Access Journals (Sweden)

    Sérgio Nepomuceno Pereira

    2014-01-01

    Full Text Available Measurements of the aerosol absorption coefficient, between 2007 and 2013, were made at the ground level in Évora, a Portuguese small town located in the southwestern Iberia Peninsula. Such a relatively long time series of absorbing aerosols is unique in Portugal and uncommon elsewhere. The average aerosol absorption coefficient was close to 9 Mm−1 and clear cycles at both daily and seasonal time scales were found. An average increase by a factor of two (from 6 to 12 Mm−1 was observed in winter if compared to summer season. The daily variations were similarly shaped for all seasons, with two morning and afternoon peaks, but with magnitudes modulated by the seasonal evolution. That was not the case if Sundays were considered. These variations can be explained in terms of the impact of local particle sources, related mainly to traffic and biomass burning and upward mixing of the aerosol due to variable mixing layer heights, either daily or seasonally. Also, a strong negative correlation between the aerosol absorption coefficient and the wind speed was verified, and an exponential decay function was found to fit very well to the data. The wind direction seems to be not correlated with the aerosol absorption coefficient.

  19. Absorption coefficient of urban aerosol in Nanjing, west Yangtze River Delta of China

    Directory of Open Access Journals (Sweden)

    B. L. Zhuang

    2015-06-01

    Full Text Available Absorbing aerosols can significantly modulate shortwave solar radiation in the atmosphere, affecting regional and global climate. Aerosol absorption coefficient (AAC is an indicator to assess the impact of absorbing aerosols on radiative forcing. In this study, the near-surface AAC and absorption angstrom exponent (AAE in urban Nanjing, China, are characterized on the basis of measurements in 2012 and 2013 using the 7-channel Aethalometer (model AE-31, Magee Scientific, USA. The AAC is estimated with direct and indirect corrections, which show consistent temporal variations and magnitudes of AAC at 532 nm. The mean AAC at 532 nm is about 43.23 ± 28.13 M m−1 in urban Nanjing, which is much lower than that in Pearl River Delta and as the same as that in rural areas (Lin'an in Yangtze River Delta. The AAC in urban Nanjing shows strong seasonality (diurnal variations, high in cold seasons (at rush hours and low in summer (in afternoon. It also show synoptic and quasi-two-week cycles in response to weather systems. Its frequency distribution follows a typical lognormal pattern. The 532 nm-AAC ranging from 15 to 65 M m−1 dominates, accounting for more than 72% of the total data samples in the entire study period. Frequent high pollution episodes, such as those observed in June 2012 and in winter 2013, greatly enhanced AAC and altered its temporal variations and frequency distributions. These episodes are mostly due to local emissions and regional pollutions. Air masses from northern China to Nanjing can sometimes be highly polluted and lead to high AAC at the site. AAE at 660/470 nm from the Schmid correction (Schmid et al., 2006 is about 1.56, which might be more reasonable compared to that from the Weingartner correction (Weingartner et al., 2003. Low AAEs mainly appear in summer in response to the relative humidity (RH. AAC increases with increasing AAE at a fixed aerosol loading. The RH-AAC relationship is more complex. Overall, AAC peaks

  20. Convergence of Cell Based Finite Volume Discretizations for Problems of Control in the Conduction Coefficients

    DEFF Research Database (Denmark)

    Evgrafov, Anton; Gregersen, Misha Marie; Sørensen, Mads Peter

    2011-01-01

    design, in particular shape and topology optimization, and are most often solved numerically utilizing a finite element approach. Within the FV framework for control in the coefficients problems the main difficulty we face is the need to analyze the convergence of fluxes defined on the faces of cells......We present a convergence analysis of a cell-based finite volume (FV) discretization scheme applied to a problem of control in the coefficients of a generalized Laplace equation modelling, for example, a steady state heat conduction. Such problems arise in applications dealing with geometric optimal...

  1. Effects of soot absorption coefficient-Planck function correlation on radiative heat transfer in oxygen-enriched propane turbulent diffusion flame

    Science.gov (United States)

    Consalvi, J. L.; Nmira, F.

    2016-03-01

    The main objective of this article is to quantify the influence of the soot absorption coefficient-Planck function correlation on radiative loss and flame structure in an oxygen-enhanced propane turbulent diffusion flame. Calculations were run with and without accounting for this correlation by using a standard k-ε model and the steady laminar flamelet model (SLF) coupled to a joint Probability Density Function (PDF) of mixture fraction, enthalpy defect, scalar dissipation rate, and soot quantities. The PDF transport equation is solved by using a Stochastic Eulerian Field (SEF) method. The modeling of soot production is carried out by using a flamelet-based semi-empirical acetylene/benzene soot model. Radiative heat transfer is modeled by using a wide band correlated-k model and turbulent radiation interactions (TRI) are accounted for by using the Optically-Thin Fluctuation Approximation (OTFA). Predicted soot volume fraction, radiant wall heat flux distribution and radiant fraction are in good agreement with the available experimental data. Model results show that soot absorption coefficient and Planck function are negatively correlated in the region of intense soot emission. Neglecting this correlation is found to increase significantly the radiative loss leading to a substantial impact on flame structure in terms of mean and rms values of temperature. In addition mean and rms values of soot volume fraction are found to be less sensitive to the correlation than temperature since soot formation occurs mainly in a region where its influence is low.

  2. Effective absorption coefficient measurements in PMMA and PTFE by clean ablation process with a coherent VUV source at 125 nm

    Science.gov (United States)

    Riedel, D.; Castex, M. C.

    First measurements of effective absorption coefficient and penetration depth are given here from the ablation of poly-methylmethacrylate (PMMA) and poly-tetrafluoroethylene (PTFE) samples at 125 nm ( 10 eV). The coherent VUV source used which provides smooth, efficient and clean etched areas, is briefly described. Experimental curves of etch depth as a function of the number of laser shots and etch rate as a function of energy density are obtained and compared with previous works performed at 157 nm (F2 laser) and 193 nm (ArF laser). Experimental results are described with a Beer-Lambert absorption law and discussed.

  3. The coupled effect of fiber volume fraction and void fraction on hydraulic fluid absorption of quartz/BMI laminates

    Science.gov (United States)

    Hurdelbrink, Keith R.; Anderson, Jacob P.; Siddique, Zahed; Altan, M. Cengiz

    2016-03-01

    Bismaleimide (BMI) resin with quartz (AQ581) fiber reinforcement is a composite material frequently used in aerospace applications, such as engine cowlings and radomes. Various composite components used in aircrafts are exposed to different types of hydraulic fluids, which may lead to anomalous absorption behavior over the service life of the composite. Accurate predictive models for absorption of liquid penetrants are particularly important as the composite components are often exposed to long-term degradation due to absorbed moisture, hydraulic fluids, or similar liquid penetrants. Microstructural features such as fiber volume fraction and void fraction can have a significant effect on the absorption behavior of fiber-reinforced composites. In this paper, hydraulic fluid absorption characteristics of quartz/BMI laminates fabricated from prepregs preconditioned at different relative humidity and subsequently cured at different pressures are presented. The composite samples are immersed into hydraulic fluid at room temperature, and were not subjected to any prior degradation. To generate process-induced microvoids, prepregs were conditioned in an environmental chamber at 2% or 99% relative humidity at room temperature for a period of 24 hours prior to laminate fabrication. To alter the fiber volume fraction, the laminates were fabricated at cure pressures of 68.9 kPa (10 psi) or 482.6 kPa (70 psi) via a hot-press. The laminates are shown to have different levels of microvoids and fiber volume fractions, which were observed to affect the absorption dynamics considerably and exhibited clear non-Fickian behavior. A one-dimensional hindered diffusion model (HDM) was shown to be successful in predicting the hydraulic fluid absorption. Model prediction indicates that as the fabrication pressure increased from 68.9 kPa to 482.6 kPa, the maximum fluid content (M∞) decreased from 8.0% wt. to 1.0% wt. The degree of non-Fickian behavior, measured by hindrance coefficient (

  4. Absorption Coefficients of SF{6}, SF{4}, SOF{2} and SO{2}F{2} in the Vacuum Ultraviolet

    Science.gov (United States)

    Pradayrol, C.; Casanovas, A. M.; Deharo, I.; Guelfucci, J. P.; Casanovas, J.

    1996-05-01

    Absorption coefficients k0(m^{-1} 100 kPa^{-1}) of SF{6} and of its main gaseous by-products SF{4}, SOF{2} and SO{2}F{2} were measured in the VUV region. The experiments were carried out at a temperature of 298 K and a spectral resolution of 0.1 nm over the wavelength range 115 - 180 nm for SF{6}, 115 - 220 nm for SF{4}, 120 - 195 nm for SOF{2} and 120 - 210 nm for SO{2}F{2}. The highest absorption coefficient values were obtained for SF{4} and the lowest for SF{6}. Les coefficients d'absorption k0(m^{-1} 100 kPa^{-1}) du SF{6} et de ses principaux produits de décomposition gazeux, SF{4}, SOF{2} et SO{2}F{2} ont été mesurés dans le domaine de l'ultraviolet sous vide. Les expériences ont été réalisées à la température de 298 K avec une résolution de 0,1 nm dans la gamme 115 180 nm pour le SF{6}, 115 220 nm pour le SF{4}, 120 195 nm pour le SOF{2} et 120 210 nm pour le SO{2}F{2}. Les coefficients d'absorption les plus élevés ont été mesurés pour le SF{4} et les plus faibles pour le SF{6}.

  5. The impact of large tidal volume ventilation on the absorption of inhaled insulin in rabbits

    DEFF Research Database (Denmark)

    Petersen, Astrid Heide; Laursen, Torben; Ahrén, Bo;

    2007-01-01

    Previous studies have shown that ventilation patterns affect absorption of inhaled compounds. Thus, the aim of this study was to investigate the effect of large tidal volume ventilation (LTVV) on the absorption of inhaled insulin in rabbits. Mechanically ventilated rabbits were given human insuli...

  6. Molecular design for improved photovoltaic efficiency: band gap and absorption coefficient engineering

    KAUST Repository

    Mondal, Rajib

    2009-01-01

    Removing the adjacent thiophene groups around the acceptor core in low band gap polymers significantly enhances solar cell efficiency through increasing the optical absorption and raising the ionization potential of the polymer. © 2009 The Royal Society of Chemistry.

  7. Spectral absorption coefficient of phytoplankton and its relation to chlorophyll a and remote sensing reflectance in coastal waters of southern China

    Institute of Scientific and Technical Information of China (English)

    CAO Wenxi; YANG Yuezhong; LIU Sheng; XU Xiaoqiang; YANG Dingtian; ZHANG Jianlin

    2005-01-01

    The spectral absorption coefficient of phytoplankton in coastal waters of southern China is investigated. Large variations in the absorption coefficient of phytoplankton are found. The absorption coefficient of phytoplankton at 443 nm ranged from 0. 006 m- 1 to 0. 484 m - 1, with an average value of 0. 067 m - 1. The chlorophyll-specific absorption coefficient of phytoplankton is also a bio-optical varito pigment composition of phytoplankton and package effect. The chlorophyll-specific absorption coefficient of phytoplankton decreases with the increasing of chlorophyll a concentration. This relationship can be described by a power law function, with the parameters and the coefficient of determination r2 as functions of wavelength, but the parameters describing the relationships in present study differed from that in Case 1 waters, thus the regional adjustment of model parameters was of particular significance for improving the accuracy of bio-optical algorithms for estimation of Chl-a concentration and primary production from remotely sensed data. Regression analysis of reflectance (R rs) ratio and absorption coefficient of phytoplankton (a ph) indicates a close correlation between them, which means that it is possible to retrieve absorption coefficient of phytoplankton using ocean color remote sensing data in optically complex coastal waters.

  8. A finite-volume numerical method to calculate fluid forces and rotordynamic coefficients in seals

    Science.gov (United States)

    Athavale, M. M.; Przekwas, A. J.; Hendricks, R. C.

    1992-01-01

    A numerical method to calculate rotordynamic coefficients of seals is presented. The flow in a seal is solved by using a finite-volume formulation of the full Navier-Stokes equations with appropriate turbulence models. The seal rotor is perturbed along a diameter such that the position of the rotor is a sinusoidal function of time. The resulting flow domain changes with time, and the time-dependent flow in the seal is solved using a space conserving moving grid formulation. The time-varying fluid pressure reaction forces are then linked with the rotor center displacement, velocity and acceleration to yield the rotordynamic coefficients. Results for an annular seal are presented, and compared with experimental data and other more simplified numerical methods.

  9. Regulation of intramembranous absorption and amniotic fluid volume by constituents in fetal sheep urine.

    Science.gov (United States)

    Anderson, Debra F; Jonker, Sonnet S; Louey, Samantha; Cheung, Cecilia Y; Brace, Robert A

    2013-09-01

    Our objective was to test the hypothesis that fetal urine contains a substance(s) that regulates amniotic fluid volume by altering the rate of intramembranous absorption of amniotic fluid. In late gestation ovine fetuses, amniotic fluid volumes, urine, and lung liquid production rates, swallowed volumes and intramembranous volume and solute absorption rates were measured over 2-day periods under control conditions and when urine was removed and continuously replaced at an equal rate with exogenous fluid. Intramembranous volume absorption rate decreased by 40% when urine was replaced with lactated Ringer solution or lactated Ringer solution diluted 50% with water. Amniotic fluid volume doubled under both conditions. Analysis of the intramembranous sodium and chloride fluxes suggests that the active but not passive component of intramembranous volume absorption was altered by urine replacement, whereas both active and passive components of solute fluxes were altered. We conclude that fetal urine contains an unidentified substance(s) that stimulates active intramembranous transport of amniotic fluid across the amnion into the underlying fetal vasculature and thereby functions as a regulator of amniotic fluid volume.

  10. Intersubband transition in lattice-matched BGaN/AlN quantum well structures with high absorption coefficients.

    Science.gov (United States)

    Park, Seoung-Hwan; Ahn, Doyeol; Park, Chan-Yong

    2017-02-20

    Intersubband absorption properties of lattice-matched BGaN/AlN quantum well (QW) structures grown on AlN substrate are theoretically investigated using an effective mass theory considering the nonparabolicity of the conduction band. These results are compared with those of GaN/AlN QW structures. The intersubband absorption coefficient of the BGaN/AlN QW structure is shown to be enhanced significantly, compared to that of the conventional GaN/AlN QW structure. This can be explained by the fact that the BGaN/AlN QW structure exhibits larger intersuband dipole moment and quasi-Fermi-level separation than the GaN/AlN QW structure, due to the increase in the carrier confinement by a larger internal field. We expect that the BGaN/AlN QW structure with a high absorption coefficient can be used for telecommunication applications at 1.55 µm under the lattice-matched condition, instead of the conventional GaN/AlN QW structure with the large strain.

  11. Preliminary results of an algorithm to determine the total absorption coefficient of water

    Digital Repository Service at National Institute of Oceanography (India)

    Suresh, T.; Talaulikar, M.; Desa, E.J.; Lotlikar, A.

    coefficient of net irradiance, KE were obtained from radiative transfer simulations using Hydrolight with large in-situ measured data from the coastal and estuarine waters of Goa. A refined algorithm of spectral micro as in Ref. [1] is used...

  12. NORMAL INCIDENCE SOUND ABSORPTION COEFFICIENT OF DIRECT PIERCING CARVED WOOD PANEL WITH DAUN SIREH MOTIF USING BOUNDARY ELEMENT METHOD

    Directory of Open Access Journals (Sweden)

    Mohd Zamri Jusoh

    2013-06-01

    Full Text Available The Direct Piercing Carved Wood Panel (DPCWP installed in Masjid Abidin, Kuala Terengganu, is one example that carries much aesthetic and artistic value. The use of DPCWP in earlier mosques was envisaged to improve the intelligibility of indoor speech because the perforated panels allow some of the sound energy to pass through. In this paper, the normal incidence sound absorption coefficient of DPCWP with Daun Sireh motif, which is a form of floral pattern, is discussed. The Daun Sireh motif was chosen and investigated for 30%, 35%, 40%, and 45% perforation ratios. The simulations were conducted using BEASY Acoustic Software based on the boundary element method. The simulation results were compared with measurements obtained by using the sound intensity technique. An accompanying discussion on both the numerical and the measurement tendencies of the sound absorption characteristics of the DPCWP is provided. The results show that the DPCWP with Daun Sireh motif can act as a good sound absorber.

  13. Specific absorption and backscatter coefficient signatures in southeastern Atlantic coastal waters

    Science.gov (United States)

    Bostater, Charles R., Jr.

    1998-12-01

    Measurements of natural water samples in the field and laboratory of hyperspectral signatures of total absorption and reflectance were obtained using long pathlength absorption systems (50 cm pathlength). Water was sampled in Indian River Lagoon, Banana River and Port Canaveral, Florida. Stations were also occupied in near coastal waters out to the edge of the Gulf Stream in the vicinity of Kennedy Space Center, Florida and estuarine waters along Port Royal Sound and along the Beaufort River tidal area in South Carolina. The measurements were utilized to calculate natural water specific absorption, total backscatter and specific backscatter optical signatures. The resulting optical cross section signatures suggest different models are needed for the different water types and that the common linear model may only appropriate for coastal and oceanic water types. Mean particle size estimates based on the optical cross section, suggest as expected, that particle size of oceanic particles are smaller than more turbid water types. The data discussed and presented are necessary for remote sensing applications of sensors as well as for development and inversion of remote sensing algorithms.

  14. How polarizabilities and C6 coefficients actually vary with atomic volume

    Science.gov (United States)

    Gould, Tim

    2016-08-01

    In this work, we investigate how atomic C6 coefficients and static dipole polarizabilities α scale with effective volume. We show, using confined atoms covering rows 1-5 of the periodic table, that C 6 / C6 R ≈ ( V / VR ) p Z and α / α R ≈ ( V / VR ) pZ ' (for volume V = ∫ d r /4 π 3 r 3 n ( r ) ), where C6 R , αR, and VR are the reference values and effective volume of the free atom. The scaling exponents pZ and pZ ' vary substantially as a function of element number Z = N, in contrast to the standard "rule of thumb" that pZ = 2 and pZ ' = 1 . Remarkably, we find that the polarizability and C6 exponents p' and p are related by p' ≈ p - 0.615 rather than the expected p' ≈ p/2. Results are largely independent of the form of the confining potential (harmonic, cubic, and quartic potentials are considered) and kernel approximation, justifying this analysis.

  15. How polarizabilities and $C_6$ coefficients actually vary with atomic volume

    CERN Document Server

    Gould, Tim

    2016-01-01

    In this work we investigate how atomic $C_6$ coefficients and static dipole polarizabilities $\\alpha$ scale with effective volume. We show, using confined atoms covering rows 1-5 of the periodic table, that $C_6/C_6^R\\approx (V/V^R)^{p_Z}$ and $\\alpha/\\alpha^R\\approx (V/V^R)^{p'_Z}$ (for volume $V=\\int dr \\frac{4\\pi}{3}r^3 n(r)$) where $C_6^R$, $\\alpha^R$ and $V^R$ are the reference values and effective volume of the free atom. The scaling exponents $p_Z$ and $p'_Z$ vary substantially as a function of element number $Z=N$, in contrast to the standard "rule of thumb" that $p_Z=2$ and $p'_Z=1$. Remarkably, We find that the polarizability and $C_6$ exponents $p'$ and $p$ are related by $p'\\approx p-0.615$ rather than the expected $p'\\approx p/2$. Results are largely independent of the form of the confining potential (harmonic, cubic and quartic potentials are considered) and kernel approximation, justifying this analysis.

  16. Predicting dissolved lignin phenol concentrations in the coastal ocean from chromophoric dissolved organic matter (CDOM absorption coefficients

    Directory of Open Access Journals (Sweden)

    Cédric G. Fichot

    2016-02-01

    Full Text Available Dissolved lignin is a well-established biomarker of terrigenous dissolved organic matter (DOM in the ocean, and a chromophoric component of DOM. Although evidence suggests there is a strong linkage between lignin concentrations and chromophoric DOM (CDOM absorption coefficients in coastal waters, the characteristics of this linkage and the existence of a relationship that is applicable across coastal oceans remain unclear. Here, 421 paired measurements of dissolved lignin concentrations (sum of 9 lignin phenols and CDOM absorption coefficients (ag(λ were used to examine their relationship along the river-ocean continuum (0-37 salinity and across contrasting coastal oceans (sub-tropical, temperate, high-latitude. Overall, lignin concentrations spanned four orders of magnitude and revealed a strong, non-linear relationship with ag(λ. The characteristics of the relationship (shape, wavelength dependency, lignin-composition dependency and evidence from degradation indicators were all consistent with lignin being an important driver of CDOM variability in coastal oceans, and suggested physical mixing and long-term photodegradation were important in shaping the relationship. These observations were used to develop two simple empirical models for estimating lignin concentrations from ag(λ with a +/- 20% error relative to measured values. The models are expected to be applicable in most coastal oceans influenced by terrigenous inputs.

  17. Mechanochemical synthesis of stoichiometric nickel and nickel-zinc ferrite powders with Nicolson-Ross analysis of absorption coefficients

    Directory of Open Access Journals (Sweden)

    Jovalekić Čedomir

    2012-01-01

    Full Text Available The interest in finding new methods for preparation of nickel ferrite (NiFe2O4 and nickel-zinc ferrite (NixZn1-xFe2O4 powders has recently increased, due to the fact that physical and chemical properties of these soft magnetic materials depend strongly on the preparation conditions. In this paper, powder samples of ferrites were obtained by: 1 classic sintering procedure (NixZn1-xFe2O4, x = 0.9 and 2 planetary mill synthesis (both NiFe2O4 and NixZn1-xFe2O4. Mechanochemical reaction leading to the formation of NixZn1-xFe2O4 (x = 1 and 0.9 spinel phase was monitored by SEM, TEM, and XRD. Values of the real and imaginary parts of permittivity and permeability were measured for the obtained nickel and nickel-zinc ferrite samples in the 7-12 GHz frequency range. Based on the obtained results, the EMR absorption coefficients were calculated for all three sample types. It has been concluded that the method of preparation and the final particle size influence the EMR absorption coefficient of nickel and nickel-zinc ferrites.

  18. Parameterization of the chlorophyll a-specific in vivo light absorption coefficient covering estuarine, coastal and oceanic waters

    DEFF Research Database (Denmark)

    Stæhr, P. A.; Markager, S.

    2004-01-01

    We evaluated models predicting the spectral chlorophyll-a (Chl a)-specific absorption coefficient (a*ph (¿)) from Chl a concentration [Chl a] on the basis of 465 phytoplankton absorption spectra collected in estuarine, coastal and oceanic waters. A power model on ln-transformed data provided...... the best model fit compared to a power model on non-transformed data previously applied to parameterize the relationship between a*ph (¿) and [Chl a]. The variation in a*ph (¿) was parameterized over four orders of magnitude in [Chl a] (0.01-100 mg Chl a m-3) producing a 13-fold range in a*ph (0.19 to 0.......015 m2 mg-1 Chl a) at 440 nm, the peak absorption of Chl a in the blue part of the spectrum. The variations in the modelled a*ph spectra were within realistic predictions of a*ph (¿) and the model satisfactorily reproduced the spectral flattening with increasing [Chl a]. The parameterization of a...

  19. Giant Two-Photon Absorption Coefficient and Frequency Up-Converted Luminescence in Monolayer MoS2

    CERN Document Server

    Li, Yuanxin; Zhang, Saifeng; Zhang, Xiaoyan; Feng, Yanyan; Wang, Kangpeng; Zhang, Long; Wang, Jun

    2015-01-01

    Strong two-photon absorption (TPA) in monolayer MoS2 is demonstrated in contrast to saturable absorption (SA) in multilayer MoS2 under the excitation of femtosecond laser pulses in the near infrared region. MoS2 in the forms of monolayer single crystal and multilayer triangular islands are grown on either quartz or SiO2/Si by employing the seeding method through chemistry vapor deposition. The nonlinear transmission measurements reveal that monolayer MoS2 possesses a giant nonsaturation TPA coefficient, larger than that of conventional semiconductors. As a result of TPA, two-photon pumped frequency up-converted luminescence is observed directly in the monolayer MoS2. For the multilayer MoS2, the SA response is demonstrated with the ratio of the excited-state absorption cross section to ground-state cross section of 0.18. In addition, the laser damage threshold of the monolayer MoS2 is 97 GW/cm2, larger than that of the multilayer MoS2 of 78 GW/cm2.

  20. Inverse Bremsstrahlung in Astrophysical Plasmas: The Absorption Coefficients and Gaunt Factors

    Indian Academy of Sciences (India)

    A. A. Mihajlov; V. A. Srećković; N. M. Sakan

    2015-12-01

    The electron–ion inverse Bremsstrahlung is considered here as a factor of the influence on the opacity of the different stellar atmospheres and other astrophysical plasmas. It is shown that this process can be successfully described in the frames of cut-off Coulomb potential model within the regions of the electron densities and temperatures. The relevant quantum mechanical method of the calculation of the corresponding spectral coefficient processes is described and discussed. The results obtained for the plasmas with the electron densities from 1014 cm$^{-3}$ to 2 · 1019 cm$^{−3}$ and temperatures from 5 · 103 K to 3 · 104 K in the wavelength region 100 nm < < 3000 nm are presented. Also, these results can be of interest for different laboratory plasmas.

  1. Absorption Coefficients of the Methane-Nitrogen Binary Ice System: Implications for Pluto

    CERN Document Server

    Protopapa, S; Tegler, S C; Bergonio, J M

    2015-01-01

    The methane-nitrogen phase diagram of Prokhvatilov and Yantsevich (1983) indicates that at temperatures relevant to the surfaces of icy dwarf planets like Pluto, two phases contribute to the methane absorptions: nitrogen saturated with methane $\\bf{\\bar{N_{2}}}$:CH$_{4}$ and methane saturated with nitrogen $\\bf{\\bar{CH_{4}}}$:N$_{2}$. No optical constants are available so far for the latter component limiting construction of a proper model, in compliance with thermodynamic equilibrium considerations. New optical constants for solid solutions of methane diluted in nitrogen (N$_{2}$:CH$_{4}$) and nitrogen diluted in methane (CH$_{4}$:N$_{2}$) are presented at temperatures between 40 and 90 K, in the wavelength range 1.1-2.7 $\\mu$m at different mixing ratios. These optical constants are derived from transmission measurements of crystals grown from the liquid phase in closed cells. A systematic study of the changes of methane and nitrogen solid mixtures spectral behavior with mixing ratio and temperature is prese...

  2. Demonstration of the Applicability of Novel Photoacoustic Aerosol Monitor for Optical Absorption Coefficient Determination. Laboratory and Field Test.

    Science.gov (United States)

    Ajtai, T.; Schnaiter, M.; Linke, C.; Vragel, M.; Filep, Á.; Fődi, L.; Motika, G.; Bozóki, Z.; Szabó, G.

    2009-04-01

    Despite of its importance, the possibilities to determine the direct radiative forcing by atmospheric aerosols is very limited due to lack of the reliable on-line instruments. Therefore there is an increasing concern for novel methods promising more accurate and reliable results in this field. The accuracy and reliability of the available on-line instruments like SP2 (Single Particle Soot Photometer), MAAP (Multi Angle Absorption Photometer), are limited by the weakness of the spectral resolution or the sampling artefact of filter matrix during the light attenuation measurement on the deposited filter. These methods neither suitable for direct determination of the light absorption by aerosols nor dispose the capability of the source apportionment. In this work we present a novel photoacoustic based instrument for direct light absorption measurements in the atmosphere and demonstrate the suitability of that both in laboratory and field circumstances. We have developed a novel Multi Wavelength PhotoAcoustic System (WaSul-MuWaPas) based on the diode laser pumped, high repetition rate, Q-switched Nd:YAG laser and its frequency converted harmonics for direct determination of light absorption by aerosols. This instrument has designed to make in situ measurements at four different wavelengths simultaneously from the NIR to the UV wavelength range (1064nm, 532nm, 355nm, 266nm). The Wasul-MuWaPas measures directly the optical absorption coefficient on airborne particles, not belong to the integrated plate type technique (filter-free operation), operating at wide wavelength range (source apportionment possibilities), due to the possibilities of the wavelength independent cell constant determination the measurement method is absolute. Because of these the Wasul-MuWaPas system may become one of the best candidate for absorption measurements of various atmospheric aerosols such as black carbon, mineral dust, and secondary organic and inorganic aerosols as well as for source

  3. A time-resolved single-pass technique for measuring optical absorption coefficients of window materials under 100 GPa shock pressures.

    Science.gov (United States)

    Li, Jun; Zhou, Xianming; Li, Jiabo

    2008-12-01

    An experimental method was developed to perform time-resolved, single-pass optical absorption measurements and to determine absorption coefficients of window materials under strong shock compression up to approximately 200 GPa. Experimental details are described of (i) a configuration to generate an in situ dynamic, bright, optical source and (ii) a sample assembly with a lithium fluoride plate to essentially eliminate heat transfer from the hot radiator into the specimen and to maintain a constant optical source within the duration of the experiment. Examples of measurements of optical absorption coefficients of several initially transparent single crystal materials at high shock pressures are presented.

  4. Studies on absorption coefficients of dual-energy γ-rays and measuring error correction for multiphase fraction determination

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    In this article, principle and mathematical method of determining the phase fractions of multiphase flows by using a dual-energy γ-ray system have been described. The dual-energy γ-ray device is composed of radioactive isotopes of 241Am and 137Cs with γ-ray energies of 59.5 and 662 keV, respectively. A rational method to calibrate the absorption coefficient was introduced in detail. The modified arithmetic is beneficial to removing the extra Compton scattering from the measured value. The result shows that the dual-energy γ-ray technique can be used in three-phase flow with average accuracy greater than 95%, which enables us to determine phase fractions almost independent of the flow regime. Improvement has been achieved on measurement accuracy of phase fractions.

  5. TECHNIQUE OF ESTIMATE OF ABSORPTION COEFFICIENT LASER RADIATION IN BORON DOPED DIAMONDS BY INTENSITY OF RAMAN SCATTERING

    Directory of Open Access Journals (Sweden)

    O. N. Poklonskaya

    2013-01-01

    Full Text Available Results of measurements of Raman scattering at the room temperature in air in boron doped synthetic diamonds (five with boron concentrations 2·1017; 6·1017; 2·1018; 1,7·1019; 1·1020 cm–3 and one intentionally undoped are presented. The laser with wavelength 532 nm was used for Raman scattering excitation. Dependences of integral intensity and halfwidth of diamond Raman line with respect to the doping level are presented. In the geometrical optics approximation an expression for doped to undoped integral intensity ratio is obtained. Qualitative estimates of conductivity of the studied samples are conducted. The obtained results can be applied for mapping of near-surface laser radiation absorption coefficient of synthetic single crystal diamonds and for their quality control.

  6. Guideline for Adopting the Local Reaction Assumption for Porous Absorbers in Terms of Random Incidence Absorption Coefficients

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2011-01-01

    errors of less than 10% if the thickness exceeds 120 mm for a flow resistivity of 5000 Nm-4s. As the flow resistivity doubles, a decrease in the required thickness by 25 mm is observed to achieve the same amount of error. For an absorber backed by an air gap, the thickness ratio between the material...... and air cavity is important, since the thicker the cavity, the more extendedly reacting the absorber. If the absorber thickness is approximately 40% of the cavity depth, the local reaction models give errors below 10% even for a low flow resistivity case....... resistivity and the absorber thickness on the difference between the two surface reaction models are examined and discussed. For a porous absorber backed by a rigid surface, the assumption of local reaction always underestimates the random incidence absorption coefficient and the local reaction models give...

  7. Nasal Drug Absorption from Powder Formulations: Effect of Fluid Volume Changes on the Mucosal Surface.

    Science.gov (United States)

    Tanaka, Akiko; Furubayashi, Tomoyuki; Enomura, Yuki; Hori, Tomoki; Shimomura, Rina; Maeda, Chiaki; Kimura, Shunsuke; Inoue, Daisuke; Kusamori, Kosuke; Katsumi, Hidemasa; Sakane, Toshiyasu; Yamamoto, Akira

    2017-01-01

    The effect of changes in the mucosal fluid volume on the nasal drug absorption of powder formulations was evaluated using warfarin (WF), piroxicam (PXC), and norfloxacin (NFX) as model drugs. Lactose and sodium chloride (NaCl), which are water soluble and small-sized chemicals that increase osmotic pressure after dissolution, were used as excipients to change the mucosal fluid volume. The in vitro study using a Madin-Darby canine kidney (MDCK) cell monolayer indicated that lactose and NaCl, sprayed over the surface of air interface monolayers, increased the fluid volume on the monolayer surface and enhanced the transepithelial transport of the model drugs. The in vivo animal study indicated that the nasal absorption of PXC is enhanced by lactose and NaCl after nasal administration of the powder formulations. This is likely due to the enhanced dissolution of PXC on fluid-rich nasal mucosa and an increase in the effective surface area for drug permeation, which lead to better nasal absorption. However, both excipients failed to increase the nasal absorption of WF and NFX. To clarify the mechanism of the drug-dependent effect of lactose and NaCl, the nasal residence of the formulation was examined using FD70 as a non-absorbable marker. The nasal clearance of FD70 was enhanced by lactose and NaCl, leading to a decrease in the nasal drug absorption. Lactose and NaCl caused no damage to the nasal tissue. These results indicate that the addition of water-soluble excipients such as lactose to powder formulations can enhance the nasal absorption of highly permeable but poorly soluble drugs.

  8. A research on statistical retrieval algorithms and spectral characteristics of the total absorption coefficients in the Yellow Sea and the East China Sea

    Institute of Scientific and Technical Information of China (English)

    WANG Xiaomei; TANG Junwu; SONG Qingjun; Ding Jing; MA Chaofei

    2006-01-01

    This paper suggests a group of statistical algorithms for calculating the total absorption coefficients based on in situ data of apparent optical property and inherent optical property collected with strict quality assurance according to NASA ocean bio-optic protocols in the Yellow Sea and the East China Sea in spring 2003. The band-ratios of Rrs412/Rrs555, Rrs490/Rrs555 are used in the algorithms to derive the total absorption coefficients (at) at 412, 440, 488, 510, 532 and 555nm bands, respectively. The average relative errors between inversed and measured values are less than 25.8%, with the correlative coefficients (R2) being 0.75-0.85. Error sensitivity analysis shows that the maximum retrieval error is less than 24.0% at (5% error in Rrs's. So the statistical algorithms of this paper are practicable. In this paper, the relations between the total absorption coefficients at 412, 488, 510, 532, 555 nm and that of 440nm are also studied. The results show that the relations between the total absorption coefficients of 400-600 nm and that of 440 nm are correlated well and all of their correlative coefficients R2 are greater than 0.99. Furthermore, a regression analysis is also done for the slope of the linear relations and wavelengths, and the R2 is also 0.99. Thus it is possible to retrieve other bands' total absorption coefficients with only one band absorption value, which significantly reduce the number of unknown parameters in studying other ocean color related problems.

  9. Laboratory investigation on the role of tubular shaped micro resonators phononic crystal insertion on the absorption coefficient of profiled sound absorber

    Science.gov (United States)

    Yahya, I.; Kusuma, J. I.; Harjana; Kristiani, R.; Hanina, R.

    2016-02-01

    This paper emphasizes the influence of tubular shaped microresonators phononic crystal insertion on the sound absorption coefficient of profiled sound absorber. A simple cubic and two different bodies centered cubic phononic crystal lattice model were analyzed in a laboratory test procedure. The experiment was conducted by using transfer function based two microphone impedance tube method refer to ASTM E-1050-98. The results show that sound absorption coefficient increase significantly at the mid and high-frequency band (600 - 700 Hz) and (1 - 1.6 kHz) when tubular shaped microresonator phononic crystal inserted into the tested sound absorber element. The increment phenomena related to multi-resonance effect that occurs when sound waves propagate through the phononic crystal lattice model that produce multiple reflections and scattering in mid and high-frequency band which increases the sound absorption coefficient accordingly

  10. Simultaneous measurement of thermal diffusivity and effective infrared absorption coefficient in IR semitransparent and semiconducting n-CdMgSe crystals using photothermal radiometry

    Energy Technology Data Exchange (ETDEWEB)

    Pawlak, M., E-mail: mpawlak@fizyka.umk.pl [Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University, Grudziądzka 5/7, Toruń (Poland); Maliński, M. [Department of Electronics and Computer Science, Koszalin University of Technology, 2 Śniadeckich St., Koszalin 75-453 (Poland)

    2015-01-10

    Highlights: • The new method of determination of the effective infrared absorption coefficient is presented. • The method can be used for transparent samples for the excitation radiation. • The effect of aluminum foil on the PTR signal in a transmission configuration is discussed. - Abstract: In this paper we propose a new procedure of simultaneous estimation of the effective infrared optical absorption coefficient and the thermal diffusivity of solid state samples using the photothermal infrared radiometry method in the transmission configuration. The proposed procedure relies on the analysis of the frequency dependent signal obtained from the samples covered with thin aluminum foil. This method can be applied for both optically opaque and transparent samples. The proposed method is illustrated with the results of the thermal diffusivity and the effective IR absorption coefficient obtained for several Cd{sub 1−x}Mg{sub x}Se crystals.

  11. Band-to-band and free-carrier absorption coefficients in heavily doped silicon at 4 K and at room temperature

    Science.gov (United States)

    Jain, S. C.; Nathan, A.; Briglio, D. R.; Roulston, D. J.; Selvakumar, C. R.; Yang, T.

    1991-03-01

    Using the raw experimental data of Schmid and the known values of band-gap narrowing and Fermi energies for different doping concentrations, the band-to-band and free-carrier absorption coefficients in heavily doped Si are calculated. The behavior of boron-doped Si is different from that of arsenic doped Si. Near threshold, our values of the absorption coefficients are significantly different from those derived by Schmid from the same data. The enhancement of band-to-band transitions due to impurity or free-carrier scattering is not as important in heavily doped Si as in heavily doped Ge. Numerically fitted empirical expressions for the absorption coefficients, suitable for computer simulation studies of opto-electronic devices are given.

  12. Ultralow Absorption Coefficient and Temperature Dependence of Radiative Recombination of CH3NH3PbI3 Perovskite from Photoluminescence.

    Science.gov (United States)

    Barugkin, Chog; Cong, Jinjin; Duong, The; Rahman, Shakir; Nguyen, Hieu T; Macdonald, Daniel; White, Thomas P; Catchpole, Kylie R

    2015-03-05

    Spectrally resolved photoluminescence is used to measure the band-to-band absorption coefficient α(BB)(ℏω) of organic-inorganic hybrid perovskite methylammonium lead iodide (CH₃NH₃PbI₃) films from 675 to 1400 nm. Unlike other methods used to extract the absorption coefficient, photoluminescence is only affected by band-to-band absorption and is capable of detecting absorption events at very low energy levels. Absorption coefficients as low as 10⁻¹⁴ cm⁻¹ are detected at room temperature for long wavelengths, which is 14 orders of magnitude lower than reported values at shorter wavelengths. The temperature dependence of α(BB)(ℏω) is calculated from the photoluminescence spectra of CH₃NH₃PbI₃ in the temperature range 80-360 K. Based on the temperature-dependent α(BB)(ℏω), the product of the radiative recombination coefficient and square of the intrinsic carrier density, B(T) × n(i)², is also obtained.

  13. A Fiberoptic Irradiance Microsensor (Cosine Collector) - Application for In-Situ Measurements of Absorption-Coefficients in Sediments and Microbial Mats

    DEFF Research Database (Denmark)

    LASSEN, C.; JØRGENSEN, BB

    1994-01-01

    measures of available light for photosynthesis parameter is discussed. From the distribution of scalar irradiance and irradiance, in situ absorption coefficients were calculated. Within the upper 3 mm of the gelatinous mat, the vertical attenuation coefficients of scalar irradiance, upward radiance...... to downward irradiance depended on spectral absorption characteristics of the sediment and ranged from 1.2 at 430 nm in the Microcoleus mat to 2.0 at 760 nm in the Aphanothece-Phormidium mat. As the light field became more isotropic with depth, the ratio of scalar irradiance to downward irradiance increased...

  14. Quantification of the dynamic changes in the absorption coefficient of liquid water at erbium:YAG and carbon dioxide laser wavelengths

    Science.gov (United States)

    Shori, Ramesh K.

    The interaction of high-intensity, short-pulsed radiation with liquid water results in dynamic changes in the optical absorption coefficient of water. These changes and their implications, as related to mid-infrared laser ablation of tissue, were not investigated until the late 1980's and early 1990's. Classical models of absorption and heating do not explain the dynamic, non-linear changes in water. The objective of the present work was to quantify the dynamic changes in the absorption coefficient of liquid water as a function of incident energy at three clinically relevant infrared wavelengths (λ = 2.94, 9.6, 10.6 μm). To investigate the changes in the absorption spectrum of water in the 3-μm band, a stable, high-energy Q- switched Er:YAG laser emitting 2.94-μm radiation in a near-perfect TEMoo spatial beam profile was developed. Key to the development of this laser was careful attention to the gain medium, optical pump system, system optics, and the thermal system. The final system design was capable of emitting 110 mJ/pulse at of 2-4 Hz with a lamp lifetime exceeding 12 million pulses The laser was used in two sets of experiments in order to quantify the above changes. First, the laser was used to measure the velocity of the shock front produced by vaporizing a gelatin-based tissue phantom. The measured shock velocity was related to the optical energy absorbed by the tissue phantom and the absorption coefficient, based on the pressure relationships derived using a 1-D piston model for an expanding plume. The shock front velocity measurements indicate that the absorption coefficient is constant for incident fluences less than 20 J/cm2, a result consistent with transmission data. For higher fluences, the data indicate a decrease in the absorption coefficient, which is again consistent with transmission data. Quantification of the absorption coefficient can, however, not be made without violating assumptions that form the basis for the 1-D piston model. Second

  15. 纤维形态对针刺非织造布吸声系数的影响%Effect of fiber morphology on the sound absorption coefficient of needle-punched nonwovens

    Institute of Scientific and Technical Information of China (English)

    吴彤; 于伟东; 郑永红; 何勇

    2015-01-01

    The standing wave tube is used to test the sound absorption properties of several fibrous materials with different shape factors of cross-section, different fineness and diameters, different perimeter ratios and specific surface areas, different fiber volume fractions and porosities. The results show that the shape factor of cross-section influences the sound absorption property of the needle-punched nonwoven to some extent, however the influence is rather complex, and the shape factor of cross-section is not an essential factor of influencing the sound absorption coefficient. Specific surface area of the fibers is the essential factor affecting absorption property:the larger the specific surface area, the greater the gas-solid phase acoustic resistance. The fiber fineness (dtex) is inversely proportional to the specific surface area, so the larger the diameter, the smaller the sound absorption coefficient. The fiber volume fraction is another important factor: the smaller the porosity, the greater the volume fraction, i.e. the smaller the holes, the smaller the porosity, therefore the greater the sound absorption coefficient.%利用驻波管测试方法研究了几种不同截面异形度、不同细度与直径、不同周长比与比表面积,以及不同体积分数与空隙率纤维材料的吸声性能。实验结果表明,纤维异形截面在一定程度上影响材料吸声性能,而吸声系数受纤维异形度的影响较复杂,即异形度不是吸声系数的本质影响因素。纤维比表面积参数是影响吸声性能的本质因素,比表面积越大,气-固相声阻越大,而纤维细度即纤维平均直径与其比表面积成反比,故直径越大,吸声系数越小。纤维体积分数是影响吸声性能的又一本质因素,空隙率越小,体积分数越大,即孔洞越小,空隙率越小,吸声系数越大。

  16. An Empirical Determination of the Dust Mass Absorption Coefficient, $\\kappa_{d}$, Using the Herschel Reference Survey

    CERN Document Server

    Clark, Christopher J R; Gomez, Haley L; Davies, Jonathan I

    2016-01-01

    We use the published photometry and spectroscopy of 22 galaxies in the Herschel Reference Survey to determine that the value of the dust mass absorption coefficient $\\kappa_{d}$ at a wavelength of 500 $\\mu m$ is $\\kappa_{500} = 0.051^{+0.070}_{-0.026}\\,{\\rm m^{2}\\,kg^{-1}}$. We do so by taking advantage of the fact that the dust-to-metals ratio in the interstellar medium of galaxies appears to be constant. We argue that our value for $\\kappa_{d}$ supersedes that of James et al. (2002) -- who pioneered this approach for determining $\\kappa_{d}$ -- because we take advantage of superior data, and account for a number of significant systematic effects that they did not consider. We comprehensively incorporate all methodological and observational contributions to establish the uncertainty on our value, which represents a marked improvement on the oft-quoted 'order-of-magnitude' uncertainty on $\\kappa_{d}$. We find no evidence that the value of $\\kappa_{d}$ differs significantly between galaxies, or that it correla...

  17. Effective absorption coefficient for graded band-gap semiconductors and the expected photocurrent density in solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Morales-Acevedo, Arturo [CINVESTAV del IPN, Electrical Engineering Department, Avenida IPN No. 2508, 07360 Mexico, D. F. (Mexico)

    2009-01-15

    A simple model for the generation of carriers by photons incident on a (linearly) decreasing band-gap material, such as has been described in recent CIGS solar cells, is developed. The model can be generalized for different cases such as increasing band-gap grading or for having a more complex band-gap profile. The model developed for direct band semiconductors such as CIGS or AlGaAs allows us to define an effective absorption coefficient, so that the ideal photocurrent density can be calculated in a similar manner as for solar cells with non-graded band-gap materials. We show that this model gives completely different results as those expected from intuitive approaches for calculating this ideal photocurrent density. We also show that grading of the band-gap of the absorbing material in solar cells makes the photocurrent less sensitive to the total band-gap change, in such a way that the design of the band-gap variation can be more flexible in order to have other advantages such as higher built-in voltage or higher back surface field in the device structure. (author)

  18. Remote Sensing D/H Ratios in Methane Ice: Temperature-Dependent Absorption Coefficients of CH3D in Methane Ice and in Nitrogen Ice

    CERN Document Server

    Grundy, W M; Bovyn, M J; Tegler, S C; Cornelison, D M

    2011-01-01

    The existence of strong absorption bands of singly deuterated methane (CH3D) at wavelengths where normal methane (CH4) absorbs comparatively weakly could enable remote measurement of D/H ratios in methane ice on outer solar system bodies. We performed laboratory transmission spectroscopy experiments, recording spectra at wavelengths from 1 to 6 \\mum to study CH3D bands at 2.47, 2.87, and 4.56 \\mum, wavelengths where ordinary methane absorption is weak. We report temperature-dependent absorption coefficients of these bands when the CH3D is diluted in CH4 ice and also when it is dissolved in N2 ice, and describe how these absorption coefficients can be combined with data from the literature to simulate arbitrary D/H ratio absorption coefficients for CH4 ice and for CH4 in N2 ice. We anticipate these results motivating new telescopic observations to measure D/H ratios in CH4 ice on Triton, Pluto, Eris, and Makemake.

  19. Dependence of chymosin and pepsin partition coefficient with phase volume and polymer pausidispersity in polyethyleneglycol-phosphate aqueous two-phase system.

    Science.gov (United States)

    Spelzini, Darío; Picó, Guillemo; Farruggia, Beatriz

    2006-08-01

    The influence of the phase volume ratio and polymer pausidispersity on chymosin and pepsin partition in polyethylenglycol-phosphate aqueous two-phase systems was studied. Both proteins showed a high affinity for the polyethylenglycol rich phase with a partition coefficient from 20 to 100 for chymosin and from 20 to 180 for pepsin, when the polyethyleneglycol molecular mass in the system varied between 1450 and 8000. The partition coefficient of chymosin was not affected by the volume phase ratio, while the pepsin coefficient showed a significant decrease in its partition coefficient with the increase in the top/bottom phase volume ratio.

  20. Effectiveness of the random sequential absorption algorithm in the analysis of volume elements with nanoplatelets

    DEFF Research Database (Denmark)

    Pontefisso, Alessandro; Zappalorto, Michele; Quaresimin, Marino

    2016-01-01

    In this work, a study of the Random Sequential Absorption (RSA) algorithm in the generation of nanoplatelet Volume Elements (VEs) is carried out. The effect of the algorithm input parameters on the reinforcement distribution is studied through the implementation of statistical tools, showing...... that the platelet distribution is systematically affected by these parameters. The consequence is that a parametric analysis of the VE input parameters may be biased by hidden differences in the filler distribution. The same statistical tools used in the analysis are implemented in a modified RSA algorithm...

  1. Octanol-Water Partition Coefficient from 3D-RISM-KH Molecular Theory of Solvation with Partial Molar Volume Correction.

    Science.gov (United States)

    Huang, WenJuan; Blinov, Nikolay; Kovalenko, Andriy

    2015-04-30

    The octanol-water partition coefficient is an important physical-chemical characteristic widely used to describe hydrophobic/hydrophilic properties of chemical compounds. The partition coefficient is related to the transfer free energy of a compound from water to octanol. Here, we introduce a new protocol for prediction of the partition coefficient based on the statistical-mechanical, 3D-RISM-KH molecular theory of solvation. It was shown recently that with the compound-solvent correlation functions obtained from the 3D-RISM-KH molecular theory of solvation, the free energy functional supplemented with the correction linearly related to the partial molar volume obtained from the Kirkwood-Buff/3D-RISM theory, also called the "universal correction" (UC), provides accurate prediction of the hydration free energy of small compounds, compared to explicit solvent molecular dynamics [ Palmer , D. S. ; J. Phys.: Condens. Matter 2010 , 22 , 492101 ]. Here we report that with the UC reparametrized accordingly this theory also provides an excellent agreement with the experimental data for the solvation free energy in nonpolar solvent (1-octanol) and so accurately predicts the octanol-water partition coefficient. The performance of the Kovalenko-Hirata (KH) and Gaussian fluctuation (GF) functionals of the solvation free energy, with and without UC, is tested on a large library of small compounds with diverse functional groups. The best agreement with the experimental data for octanol-water partition coefficients is obtained with the KH-UC solvation free energy functional.

  2. Enhanced vacuum laser-impulse coupling by volume absorption at infrared wavelengths

    Science.gov (United States)

    Phipps, C. R., Jr.; Harrison, R. F.; Shimada, T.; York, G. W.; Turner, R. F.

    1990-03-01

    This paper reports measurements of vacuum laser impulse coupling coefficients as large as 90 dyne/W, obtained with single microsec-duration CO2 laser pulses incident on a volume-absorbing, cellulose-nitrate-based plastic. This result is the largest coupling coefficient yet reported at any wavelength for a simple, planar target in vacuum, and partly results from expenditure of internal chemical energy in this material. Enhanced coupling was also observed in several other target materials that are chemically passive, but absorb light in depth at 10- and 3-micron wavelengths. The physical distinctions are discussed between this important case and that of simple, planar surface absorbers (such as metals) which were studied in the same experimental series, in light of the predictions of a simple theoretical model.

  3. Low temperature MIR to submillimeter mass absorption coefficient of interstellar dust analogues. I. Mg-rich glassy silicates

    Science.gov (United States)

    Demyk, K.; Meny, C.; Lu, X.-H.; Papatheodorou, G.; Toplis, M. J.; Leroux, H.; Depecker, C.; Brubach, J.-B.; Roy, P.; Nayral, C.; Ojo, W.-S.; Delpech, F.; Paradis, D.; Gromov, V.

    2017-04-01

    Context. The submillimeter spectral domain has been extensively explored by the Herschel and Planck satellites and is now reachable from the ground with ALMA. A wealth of data, revealing cold dust thermal emission, is available for astronomical environments ranging from interstellar clouds, cold clumps, circumstellar envelops, and protoplanetary disks. The interpretation of these observations relies on the understanding and modeling of cold dust emission and on the knowledge of the dust optical properties. Aims: The aim of this work is to provide astronomers with a set of spectroscopic data of realistic interstellar dust analogues that can be used to interpret the observations. It pursues the experimental effort aimed at characterizing the spectroscopic properties of interstellar dust analogues at low temperature in the mid-infrared (MIR) to millimeter spectral domain. Compared to previous studies, it extends the range of studied dust analogues in terms of composition and of structure of the material. Methods: Glassy silicates of mean composition (1-x)MgO - xSiO2 with x = 0.35 (close to forsterite, Mg2SiO4), 0.50 (close to enstatite, MgSiO3) and 0.40 (close to Mg1.5SiO3.5 or MgSiO3:Mg2SiO4 = 50:50) were synthesized. The mass absorption coefficient (MAC) of the samples was measured in the spectral domain 30-1000 μm for grain temperature in the range 300-10 K and at room temperature in the 5-40 μm domain. Results: We find that the MAC of all samples varies with the grains temperature and that its spectral shape cannot be approximated by a single power law in λ- β. In the FIR/submm, and above 30 K, the MAC value at a given wavelength increases with the temperature as thermally activated absorption processes appear. The studied materials exhibit different and complex behaviors at long wavelengths (λ ≥ 200 to 700 μm depending on the samples). These behaviors are attributed to the amorphous nature of dust and to the amount and nature of the defects within this

  4. Determination of the carrier concentration in CdSe crystals from the effective infrared absorption coefficient measured by means of the photothermal infrared radiometry

    Energy Technology Data Exchange (ETDEWEB)

    Pawlak, M. [Nicolaus Copernicus University, Faculty of Physics, Astronomy and Informatics, Institute of Physics, Torun (Poland)

    2014-11-11

    In this paper, a non-contact method that allows to determine the carrier concentration in CdSe crystals is presented. The method relies on the measurement of the effective infrared absorption coefficient by means of the photothermal infrared radiometry (PTR). In order to obtain the effective infrared absorption coefficient and thermal diffusivity, the frequency characteristics of the PTR signal were analyzed in the frame of a one-dimensional heat transport model for infrared semitransparent crystals. The carrier concentrations were estimated using a theory introduced by Ruda and a recently proposed normalization procedure for the PTR signal. The deduced carrier concentrations of the investigated CdSe crystals are in reasonable agreement with those obtained using Hall measurements and infrared spectroscopy. The method presented in this paper can also be applied to other semiconductors with the carrier concentration in the range of 10{sup 14}-10{sup 17} cm{sup -3}. (orig.)

  5. Determination of the carrier concentration in CdSe crystals from the effective infrared absorption coefficient measured by means of the photothermal infrared radiometry

    Science.gov (United States)

    Pawlak, M.

    2015-01-01

    In this paper, a non-contact method that allows to determine the carrier concentration in CdSe crystals is presented. The method relies on the measurement of the effective infrared absorption coefficient by means of the photothermal infrared radiometry (PTR). In order to obtain the effective infrared absorption coefficient and thermal diffusivity, the frequency characteristics of the PTR signal were analyzed in the frame of a one-dimensional heat transport model for infrared semitransparent crystals. The carrier concentrations were estimated using a theory introduced by Ruda and a recently proposed normalization procedure for the PTR signal. The deduced carrier concentrations of the investigated CdSe crystals are in reasonable agreement with those obtained using Hall measurements and infrared spectroscopy. The method presented in this paper can also be applied to other semiconductors with the carrier concentration in the range of 1014-1017 cm-3.

  6. Absorption coefficient and refractive index changes of a quantum ring in the presence of spin-orbit couplings: Temperature and Zeeman effects

    Science.gov (United States)

    Zamani, A.; Azargoshasb, T.; Niknam, E.

    2017-10-01

    Effects of applied magnetic field, temperature and dimensions on the optical absorption coefficients (AC) and refractive index (RI) changes of a GaAs quantum ring are investigated in the presence of both Rashba and Dresselhaus spin-orbit interactions (SOI). To this end, the finite difference method (FDM) is used in order to numerically calculate the energy eigenvalues and eigenstates of the system while the compact density matrix approach is hired to calculate the optical properties. It is shown that application of magnetic field, temperature as well as the geometrical size in the presence of spin-orbit interactions, alter the electronic structure and consequently influence the linear and third-order nonlinear optical absorption coefficients as well as the refractive index changes of the system. Results show an obvious blue shift in optical curves with enhancing external magnetic field and temperature while the increment of dimensions result in red shift.

  7. Measurement of the Two-photon Absorption Coefficient of Gallium Phosphide (GaP) Using a Dispersion-minimized Sub-10 Femtosecond Z-scan Measurement System

    Science.gov (United States)

    2012-09-01

    samples of semiconductors and thin films of organic materials on substrates. The use of dispersive media in the optical path has been eliminated...other semiconductors such as cadmium sulfide (CdS) and zinc selenide (ZnSe). We will also begin measuring the two-photon absorption coefficient for...organic thin - film materials deposited on various substrates. 15 6. References 1. Sheik-Bahae, M.; Said, A. A.; Van Stryland, E. W. High

  8. Reduction of tire road noise by acoustic absorption: Numerical evaluation of the pass-by noise level reduction using the normal incidence acoustic absorption coefficient

    OpenAIRE

    Hamet, J. F.

    2004-01-01

    Convention GRD2/2000/30202; Rapport de recherche; Comments: This report is an INRETS-LTE edition of the SILVIA -INRETS-013-WP2 report "Estimation of the attenuation of rolling noise by acoustic absorption", dated 19/09/2004. Summary: Part of INRETS task in the SILVIA project is to study the influence of the pavement characteristics on the generation and the propagation of road traffic noise using existing models. This work addresses the reduction of tire-road noise by absorption effects. It a...

  9. Remote Sensing of the Absorption Coefficients and Chlorophyll a Concentration in the U.S. Southern Middle Atlantic Bight from SeaWiFS and MODIS-Aqua

    Science.gov (United States)

    Pan, Xiaoju; Mannino, Antonio; Russ, Mary E.; Hooker, Stanford B.

    2008-01-01

    At present, satellite remote sensing of coastal water quality and constituent concentration is subject to large errors as compared to the capability of satellite sensors in oceanic waters. In this study, field measurements collected on a series of cruises within U.S. southern Middle Atlantic Bight (SMAB) were applied to improve retrievals of satellite ocean color products in order to examine the factors that regulate the bio-optical properties within the continental shelf waters of the SMAB. The first objective was to develop improvements in satellite retrievals of absorption coefficients of phytoplankton (a(sub ph)), colored dissolved organic matter (CDOM) (a(sub g)), non-pigmented particles (a(sub d)), and non-pigmented particles plus CDOM (a(sub dg)), and chlorophyll a concentration ([Chl_a]). Several algorithms were compared to derive constituent absorption coefficients from remote sensing reflectance (R(sub rs)) ratios. The validation match-ups showed that the mean absolute percent differences (MAPD) were typically less than 35%, although higher errors were found for a(sub d) retrievals. Seasonal and spatial variability of satellite-derived absorption coefficients and [Chl_a] was apparent and consistent with field data. CDOM is a major contributor to the bio-optical properties of the SMAB, accounting for 35-70% of total light absorption by particles plus CDOM at 443 nm, as compared to 30-45% for phytoplankton and 0-20% for non-pigmented particles. The overestimation of [Chl_a] from the operational satellite algorithms may be attributed to the strong CDOM absorption in this region. River discharge is important in controlling the bio-optical environment, but cannot explain all of the regional and seasonal variability of biogeochemical constituents in the SMAB.

  10. Mean absorption coefficients of He/Ar/N2/(C1-x-y , Ni x , Co y ) thermal plasmas for CNT synthesis

    Science.gov (United States)

    Salem, D.; Hannachi, R.; Cressault, Y.; Teulet, Ph; Béji, L.

    2017-01-01

    In this paper, we present the mean absorption coefficients (MACs) calculated for plasma mixtures of argon-helium-nitrogen-carbon-nickel-cobalt at 60 kPa and in a temperature range from 1 kK to 20 kK. These coefficients have been computed under the assumption of a local thermodynamic equilibrium (LTE), isothermal plasma, including atomic and molecular continuum, molecular bands and lines radiation splitted into nine spectral intervals. The results show that the continuum absorption coefficients strongly depend on photodissociation and photoionization processes of the molecular species N2, CN and C2, with a significant effect on photodetachment processes of C- in a frequency interval lower than 1  ×  1015 Hz and for low temperature (species Ni/Co are only important in a small range of temperature and in a few spectral bands located in visible and infrared regions, while at high temperature and in UV and visible regions, the foremost contributions to MAC come from atomic continuum and line absorption.

  11. Analytical expressions of the intermediate pressure, the coefficient of performance and the exergy efficiency of half-effect absorption cooling chillers

    Energy Technology Data Exchange (ETDEWEB)

    Ort, Nesibe; Yoruk, Sedat [Ataturk University, Department of Chemical Engineering (Turkey)], e-mail: nesibe.ort@atauni.edu.tr, email: syoruk@atauni.edu.tr; Dilmac, Omer F. [Yyldyz Technical University, Department of Chemical Engineering (Turkey)], email: omerfarukdl@yahoo.com

    2011-07-01

    With the energy crisis and the rising concerns about the environment, energy-saving measures are increasingly needed. In the building sector, air conditioning systems consume important amounts of energy and absorption cooling systems, which use low grade heat, have become popular due to their energetic and environmental performances. Absorption cooling systems are composed of a condenser, an evaporator, 2 generators and 2 absorbers and 2 fluids, the refrigerant and the absorbent, are used in the cycle. The aim of this paper is to provide a method for assessing the intermediate pressure (Pi), the coefficient of performance (COP) and the exergy efficiency immediately. To do so, simple analytical expressions were used. The Pi, the COP and the exergy efficiency were found and results showed that COP decreases when the temperature of the condenser increases. This document provided a method to obtain the values of important parameters of absorption cooling systems immediately.

  12. Nonlinear absorption coefficient and optically detected electrophonon resonance in cylindrical GaAs/AlAs quantum wires with different confined phonon models

    Science.gov (United States)

    Khoa, Doan Quoc; Phuong, Le Thi Thu; Hoi, Bui Dinh

    2017-03-01

    A quantum kinetic equation for electrons interacting with confined phonons is used to investigate the nonlinear absorption of an intense electromagnetic wave by electrons in cylindrical GaAs/AlAs quantum wires. The analytic expression for absorption coefficient is calculated for three models of confined optical phonons: the dielectric continuum (DC), hydrodynamic continuum (HC), and Huang-Zhu (HZ) models. The absorption coefficient depends on the square of the electromagnetic wave amplitude. The electrophonon resonance and optically detected electrophonon resonance (ODEPR) are observed through the absorption spectrum. The full width at half maximum (the line-width) of the ODEPR peaks is obtained by a computational method. The line-width is found to increase with increasing temperature and decrease with increasing the quantum wire radius. In particular, numerical results show that the DC and HZ models lead to a similar behaviour of electron - confined phonon interaction whereas the HC model results in a quite different one, especially at small quantum wire radius. For large quantum wire radii, above mentioned phonon models have equivalent contributions to the ODEPR line-width.

  13. Modelling of the Water Absorption Kinetics and Determination of the Water Diffusion Coefficient in the Pith of Raffia vinifera of Bandjoun, Cameroon

    Directory of Open Access Journals (Sweden)

    E. Tiaya Mbou

    2017-01-01

    Full Text Available The present work focuses on the study of the water absorption phenomenon through the pith of Raffia vinifera along the stem. The water absorption kinetics was studied experimentally by the gravimetric method with the discontinuous control of the sampling mass at temperature of 30°C. The samples of 70 mm × 8 mm × 4 mm were taken from twelve sampling zones of the stem of Raffia vinifera. The result shows that the percentage of water absorption of the pith of Raffia vinifera increases from the periphery to the center in the radial position and from the base to the leaves in the longitudinal position. Fick’s second law was adopted for the study of the water diffusion. Eleven models were tested for the modelling of the water absorption kinetics and the model of Sikame Tagne (2014 is the optimal model. The diffusion coefficients of two stages were determined by the solution of the Fick equation in the twelve sampling zones described by Sikame Tagne et al. (2014. The diffusion coefficients decreased from the center to the periphery in the radial position and from the base to the leaves in the longitudinal position.

  14. Effect of baseline magnetic resonance imaging (MRI) apparent diffusion coefficient lesion volume on functional outcome in ischemic stroke.

    Science.gov (United States)

    Ma, Li; Gao, Pei-yi; Hu, Qing-mao; Lin, Yan; Jing, Li-na; Xue, Jing; Chen, Zhi-jun; Wang, Yong-jun; Liu, Mei-li; Cai, Ye-feng

    2011-06-01

    We explored the relationship between predicted infarct core, predicted ischemic penumbras and predicted final infarct volumes obtained though apparent diffusion coefficient (ADC)-based method, as well as other clinical variables, and functional outcome. Patients with acute cerebral ischemic stroke were retrospectively recruited. The National Institutes of Health Stroke Scale score was evaluated at baseline and the modified Rankin Scale (mRS) at day 90. Favorable outcome was defined as an mRS score of 0 to 2, and unfavorable outcome as 3 to 6. Multimodal stroke magnetic resonance imaging was carried out at presentation. The volumes of diffusion-weighted imaging (DWI) and perfusion-weighted imaging (PWI) were measured using the regions of interest (ROI) method. The volumes of predicted infarct core, predicted ischemic penumbra and predicted final infarct were obtained by an automated image analysis system based on baseline ADC maps. The association between baseline magnetic resonance imaging volumes, baseline clinical variables, and functional outcome was statistically analyzed. The study included 30 males and 20 females (mean±SD age, 56±10 years). Baseline DWI, PWI and PWI-DWI mismatch volumes were not correlated with day-90 mRS (P>0.05). Predicted infarct core, predicted ischemic penumbra and predicted final infarct through ADC-based method were all correlated with day-90 mRS (PStroke Scale and recanalization also demonstrated a trend toward a favorable outcome. Receiver operating characteristic analysis showed that the area under the curve of predicted final infarct volume and recanalization were higher with statistical significance (PStroke Scale and recanalization may have effect on functional outcome in acute ischemic stroke.

  15. Influence of Water Absorption on Volume Resistivity and the Dielectric Properties of Neat Epoxy Material

    KAUST Repository

    Sulaimani, Anwar Ali

    2014-07-15

    Influence of Water Absorption on the Dielectric Properties and Volume Resistivity of Neat Epoxy Material Anwar Ali Sulaimani Epoxy resins are widely used materials in the industry as electrical insulators, adhesives and in aircrafts structural components because of their high mechanical sti ness, strength and high temperature and chemical resistance properties. But still, the in uence of water uptake due to moisture adsorption is not fully understood as it detrimentally modi es the electrical and chemical properties of the material. Here, we investigate the in uence of water moisture uptake on the neat epoxy material by monitoring the change in the volume resistivity and dielectric properties of epoxy material at three di erent thickness con gurations: 0.250 mm, 0.50 mm and 1 mm thicknesses. Gravimetric analysis was done to monitor the mass uptake behaviour, Volume Resistivity was measured to monitor the change in conductivity of the material, and the dielectric properties were mapped to characterise the type of water mechanism available within the material during two ageing processes of sorption and desorption. Two-stage behaviours of di usion and reaction have been identi ed by the mass uptake analysis. Moreover, the plot of volume resistivity versus mass uptake has indi- cated a non-uniform relationship between the two quantities. However, the analysis of the dielectric spectrum at medium range of frequency and time has showed a change 5 in the dipolar activities and also showed the extent to which the water molecules can be segregated between bounding to the resin or existing as free water.

  16. Improved prediction of octanol-water partition coefficients from liquid-solute water solubilities and molar volumes

    Science.gov (United States)

    Chiou, C.T.; Schmedding, D.W.; Manes, M.

    2005-01-01

    A volume-fraction-based solvent-water partition model for dilute solutes, in which the partition coefficient shows a dependence on solute molar volume (V??), is adapted to predict the octanol-water partition coefficient (K ow) from the liquid or supercooled-liquid solute water solubility (Sw), or vice versa. The established correlation is tested for a wide range of industrial compounds and pesticides (e.g., halogenated aliphatic hydrocarbons, alkylbenzenes, halogenated benzenes, ethers, esters, PAHs, PCBs, organochlorines, organophosphates, carbamates, and amidesureas-triazines), which comprise a total of 215 test compounds spanning about 10 orders of magnitude in Sw and 8.5 orders of magnitude in Kow. Except for phenols and alcohols, which require special considerations of the Kow data, the correlation predicts the Kow within 0.1 log units for most compounds, much independent of the compound type or the magnitude in K ow. With reliable Sw and V data for compounds of interest, the correlation provides an effective means for either predicting the unavailable log Kow values or verifying the reliability of the reported log Kow data. ?? 2005 American Chemical Society.

  17. Calibration-free absolute quantification of optical absorption coefficients using acoustic spectra in 3D photoacoustic microscopy of biological tissue.

    Science.gov (United States)

    Guo, Zijian; Hu, Song; Wang, Lihong V

    2010-06-15

    Optical absorption is closely associated with many physiological important parameters, such as the concentration and oxygen saturation of hemoglobin, and it can be used to quantify the concentrations of nonfluorescent molecules. We propose a method to use acoustic spectra of photoacoustic signals to quantify the absolute optical absorption. This method is self-calibrating and thus insensitive to variations in the optical fluence. Factors such as system bandwidth and acoustic attenuation can affect the quantification but can be canceled by dividing the acoustic spectra measured at two optical wavelengths. Using optical-resolution photoacoustic microscopy, we quantified the absolute optical absorption of black ink samples with various concentrations. We also quantified both the concentration and oxygen saturation of hemoglobin in a live mouse in absolute units.

  18. Analytical solutions for the coefficient of variation of the volume-averaged solute concentration in heterogeneous aquifers

    Science.gov (United States)

    Kabala, Z. J.

    1997-08-01

    Under the assumption that local solute dispersion is negligible, a new general formula (in the form of a convolution integral) is found for the arbitrary k-point ensemble moment of the local concentration of a solute convected in arbitrary m spatial dimensions with general sure initial conditions. From this general formula new closed-form solutions in m=2 spatial dimensions are derived for 2-point ensemble moments of the local solute concentration for the impulse (Dirac delta) and Gaussian initial conditions. When integrated over an averaging window, these solutions lead to new closed-form expressions for the first two ensemble moments of the volume-averaged solute concentration and to the corresponding concentration coefficients of variation (CV). Also, for the impulse (Dirac delta) solute concentration initial condition, the second ensemble moment of the solute point concentration in two spatial dimensions and the corresponding CV are demonstrated to be unbound. For impulse initial conditions the CVs for volume-averaged concentrations axe compared with each other for a tracer from the Borden aquifer experiment. The point-concentration CV is unacceptably large in the whole domain, implying that the ensemble mean concentration is inappropriate for predicting the actual concentration values. The volume-averaged concentration CV decreases significantly with an increasing averaging volume. Since local dispersion is neglected, the new solutions should be interpreted as upper limits for the yet to be derived solutions that account for local dispersion; and so should the presented CVs for Borden tracers. The new analytical solutions may be used to test the accuracy of Monte Carlo simulations or other numerical algorithms that deal with the stochastic solute transport. They may also be used to determine the size of the averaging volume needed to make a quasi-sure statement about the solute mass contained in it.

  19. Donor impurity-related optical absorption coefficients and refractive index changes in a rectangular GaAs quantum dot in the presence of electric field

    Science.gov (United States)

    Sheng, Wang; Yun, Kang; Xianli, Li

    2016-11-01

    Within the quasi-one-dimensional effective potential model and effective mass approximation, we obtain the wavefunctions and energy eigenvalues of the ground (j = 1) and first 2 excited states (j = 2 and 3) of a donor impurity in a rectangular GaAs quantum dot in the presence of electric field. The donor impurity-related linear and nonlinear optical absorption as well as refractive index changes for the transitions j = 1-2 and j = 2-3 are investigated. The results show that the impurity position, incident optical intensity and electric field play important roles in the optical absorption coefficients and refractive index changes. We find that the impurity effect induces the blueshift for j = 1-2 and redshift for j = 3-2 in the absence of the electric field, but it leads to redshift for j = 1-2 and blueshift for j = 3-2 in the existence of the field. Also, the optical coefficient for the higher energy transitions j = 2-3 is insensitive to variation of impurity positions, while that for the low energy transition j = 1-2 depends significantly on the positions of impurity. In addition, the saturation and splitting phenomenon of the optical absorption are observed as the incident optical intensity increases. Project supported by the Science and Technology Project of Education Department of Heilongjiang Province of China (No. 12541070).

  20. Mass-specific optical absorption coefficients and imaginary part of the complex refractive indices of mineral dust components measured by a multi-wavelength photoacoustic spectrometer

    Science.gov (United States)

    Utry, N.; Ajtai, T.; Pintér, M.; Tombácz, E.; Illés, E.; Bozóki, Z.; Szabó, G.

    2015-01-01

    Mass-specific optical absorption coefficients (MACs) and the imaginary part (κ) of the refractive indices of various mineral dust components including silicate clays (illite, kaolin and bentonite), oxides (quartz, hematite and rutile), and carbonate (limestone) were determined at the wavelengths of 1064, 532, 355 and 266 nm. The MAC values were calculated from aerosol optical absorption coefficients measured by a multi-wavelength photoacoustic (PA) instrument, the mass concentration and the number size distribution of the generated aerosol samples as well as the size transfer functions of the measuring instruments. Values of κ were calculated from the measured and particle-loss-corrected data by using a Mie-theory-based retrieval algorithm. The determined values could be used for comparisons with calculated wavelength-dependent κ values typically deduced from bulk-phase measurements by using indirect measurement methods. Accordingly, the presented comparison of the measured and calculated aerosol optical absorption spectra revealed the strong need for standardized sample preparation and measurement methodology in case of bulk-phase measurements.

  1. CO2 laser photoacoustic measurements of ethanol absorption coefficients within infrared region of 9.2-10.8 μm

    Science.gov (United States)

    Ivascu, I. R.; Matei, C. E.; Patachia, M.; Bratu, A. M.; Dumitras, D. C.

    2016-06-01

    Absorption coefficients of the ethanol vapors at atmospheric pressure and room temperature were measured by photoacoustic technique using a cw, line-tunable, frequency-stabilized CO2 laser as radiation source. The spectrum of the employed CO2 laser includes 54 lines with wavelengths in the infrared region of 9.2-10.8 μm and power levels up to 4.7 W. Measurements revealed a predominant absorption for ethanol within 9.4 μm band of the CO2 laser spectrum, where the highest values of the absorption coefficients were recorded: 3.68 cm- 1 atm- 1 at 9R(20) line and 3.65 cm- 1 atm- 1 at 9R(22) line. The estimated detection range covers six orders of magnitude, from a minimum of 30 ppbV to a maximum of 4% concentration of ethanol in nitrogen, which proves the suitability of the photoacoustic technique for accurate measurements of the ethanol concentration in various applications.

  2. New laboratory intercomparison of the ozone absorption coefficients in the mid-infrared (10 μm) and ultraviolet (300-350 nm) spectral regions.

    Science.gov (United States)

    Gratien, A; Picquet-Varrault, B; Orphal, J; Doussin, J-F; Flaud, J-M

    2010-09-23

    Knowing the ozone absorption cross sections in the ultraviolet and infrared spectral range, with an accuracy of better than 1%, is of the utmost importance for atmospheric remote-sensing applications. For this reason, various ozone intensity intercomparisons and measurements have been published these last years. However, the corresponding results proved not to be consistent and thus have raised a controversial discussion in the community of atmospheric remote-sensing. This study, where great care has been taken to avoid any possible error, reports a new laboratory intercomparison of the ozone absorption coefficients in the mid-infrared (10 μm) and ultraviolet (300-350 nm) spectral regions. It gives a new piece of information to the puzzling problem concerning the ozone IR and UV cross sections and confirms that the IR and UV cross sections recommended in the literature are in disagreement of about 4%.

  3. The impact of absorption coefficient on polarimetric determination of Berry phase based depth resolved characterization of biomedical scattering samples: a polarized Monte Carlo investigation

    Energy Technology Data Exchange (ETDEWEB)

    Baba, Justin S [ORNL; Koju, Vijay [ORNL; John, Dwayne O [ORNL

    2016-01-01

    The modulation of the state of polarization of photons due to scatter generates associated geometric phase that is being investigated as a means for decreasing the degree of uncertainty in back-projecting the paths traversed by photons detected in backscattered geometry. In our previous work, we established that polarimetrically detected Berry phase correlates with the mean photon penetration depth of the backscattered photons collected for image formation. In this work, we report on the impact of state-of-linear-polarization (SOLP) filtering on both the magnitude and population distributions of image forming detected photons as a function of the absorption coefficient of the scattering sample. The results, based on Berry phase tracking implemented Polarized Monte Carlo Code, indicate that sample absorption plays a significant role in the mean depth attained by the image forming backscattered detected photons.

  4. Characterization of penetration depth as a function of optical fiber separation at various absorption and scatter coefficients for a noninvasive metabolic sensor

    Science.gov (United States)

    DeMilo, Charles; Brukilacchio, Thomas; Soller, Babs R.; Soyemi, Olusola

    2004-06-01

    A visible-near IR (500-1,000nm) fiber optic sensor is under development that is intended to non-invasively assess muscle metabolism through the measurement of tissue pH and oxygen partial pressure. These parameters are calculated from the spectra of hemoglobin and myoglobin in muscle. The sensor consists of transmit (illumination) fibers and receive (detection) fibers that are coupled to a spectrometer. Light from the probe must penetrate below the surface of the skin and into a 5-10mm thick layer of muscle. A study was conducted to quantify the relationship between transmit and receive fiber separation and sensor penetration depth below the surface of the skin. A liquid phantom was created to replicate the absorption (μa) and reduced scatter coefficient (μs') profiles typically found in human blood and tissue. The phantom consisted of a solution of Intralipid and India ink in the appropriate concentrations to achieve desired reduced scatter coefficient and absorption profiles. The reduced scatter coefficient of the liquid phantom was achieved to an accuracy of +/-10% compared to previously published data. A fixed illumination fiber and translatable detector fiber were placed in the liquid phantom, and the fiber separation was varied from 3-40mm. Values of μa and μs' varied from 0.03-0.40 cm-1 and 5.0-15.0 cm-1 respectively. Results from the experiment demonstrate a strong correlation between penetration depth and fiber separation. Additionally, it was found that penetration depth was not substantially influenced by absorption and scatter concentration. As signal-to-noise is an important parameter in many non-invasive biomedical applications, the relative signal as a function of fiber separation was determined to follow an exponential relationship.

  5. Subcutaneous absorption of monoclonal antibodies: role of dose, site of injection, and injection volume on rituximab pharmacokinetics in rats.

    Science.gov (United States)

    Kagan, Leonid; Turner, Michael R; Balu-Iyer, Sathy V; Mager, Donald E

    2012-02-01

    To determine the effect of dose, the anatomical site of injection, and the injection volume on subcutaneous absorption of rituximab in rats and to explore absorption mechanisms using pharmacokinetic modeling. Rituximab serum concentrations were measured following intravenous and subcutaneous administration at the back, abdomen, and foot of rats. Several pharmacokinetic models were developed that included linear and saturable absorption, and degradation and/or protective binding at the injection site. Rituximab exhibited linear kinetics following intravenous administration; however, bioavailability following subcutaneous injection was inversely related to the dose level. For the 1 mg/kg dose, bioavailability was approximately 70% at all tested injection sites, with faster absorption from the foot (T(max) = 12 h for foot vs. 4.6 days for back). Bioavailability for the 10 mg/kg dose was 44 and 31% for the abdomen and back sites and 18% for 40 mg/kg injected at the back. A pharmacokinetic model that included binding as part of the absorption mechanism successfully captured the nonlinearities in rituximab absorption. The anatomical site of subcutaneous injection influences the rate of absorption and bioavailability of rituximab in rats. Saturable binding may be a major determinant of the nonlinear absorptive transport of monoclonal antibodies.

  6. Determination of true optical absorption and scattering coefficient of wooden cell wall substance by time-of-flight near infrared spectroscopy.

    Science.gov (United States)

    Kitamura, Ryunosuke; Inagaki, Tetsuya; Tsuchikawa, Satoru

    2016-02-22

    The true absorption coefficient (μa) and reduced scattering coefficient (μ´s) of the cell wall substance in Douglas fir were determined using time-of-flight near infrared spectroscopy. Samples were saturated with hexane, toluene or quinolone to minimize the multiple reflections of light on the boundary between pore-cell wall substance in wood. μ´s exhibited its minimum value when the wood was saturated with toluene because the refractive index of toluene is close to that of the wood cell wall substance. The optical parameters of the wood cell wall substance calculated were μa = 0.030 mm(-1) and μ´s= 18.4 mm(-1). Monte Carlo simulations using these values were in good agreement with the measured time-resolved transmittance profiles.

  7. A Fiberoptic Irradiance Microsensor (Cosine Collector) - Application for In-Situ Measurements of Absorption-Coefficients in Sediments and Microbial Mats

    DEFF Research Database (Denmark)

    LASSEN, C.; JØRGENSEN, BB

    1994-01-01

    microsensor was used concurrently with fiber-optic microsensors for radiance and scalar irradiance in two cyanobacterial mats: a gelatinous laminated mat of Aphanothece sp. and Phormidium sp. and a compact marine intertidal mat of Microcoleus chthonoplastes. At the surface, the ratio of scalar irradiance...... at all wavelenghts and a maximum of 3.9 was reached in the gelatinous mat at both 675 and 760 nm. The results stress the importance of measuring the right light parameter when photobiological processes in sediments are investigated and the application of scalar irradiance and irradiance as quantitative...... measures of available light for photosynthesis parameter is discussed. From the distribution of scalar irradiance and irradiance, in situ absorption coefficients were calculated. Within the upper 3 mm of the gelatinous mat, the vertical attenuation coefficients of scalar irradiance, upward radiance...

  8. A wave based method to predict the absorption, reflection and transmission coefficient of two-dimensional rigid frame porous structures with periodic inclusions

    Energy Technology Data Exchange (ETDEWEB)

    Deckers, Elke [Department of Mechanical Engineering, Katholieke Universiteit Leuven, 3001 Heverlee (Belgium); Claeys, Claus; Atak, Onur [Department of Mechanical Engineering, Katholieke Universiteit Leuven, 3001 Heverlee (Belgium); Groby, Jean-Philippe; Dazel, Olivier [Laboratiore d' Acoustique de l' Universiteé du Maine, L' Université Nantes Angers Le Mans, Université du Maine, CNRS, UMR-6613 CNRS, Avenue Olivier Messiaen, 72085 Le Mans (France); Desmet, Wim [Department of Mechanical Engineering, Katholieke Universiteit Leuven, 3001 Heverlee (Belgium)

    2016-05-01

    This paper presents an extension to the Wave Based Method to predict the absorption, reflection and transmission coefficients of a porous material with an embedded periodic set of inclusions. The porous unit cell is described using the Multi-Level methodology and by embedding Bloch–Floquet periodicity conditions in the weighted residual scheme. The dynamic pressure field in the semi-infinite acoustic domains is approximated using a novel wave function set that fulfils the Helmholtz equation, the Bloch–Floquet periodicity conditions and the Sommerfeld radiation condition. The method is meshless and computationally efficient, which makes it well suited for optimisation studies.

  9. Absorption Coefficient of InGaAs V-shaped Quantum Wires Integrated in Optical Waveguides by MBE Growth

    Science.gov (United States)

    1998-06-01

    Integrated in Optical Waveguides by MBE Growth DISTRIBUTION: Approved for public release, distribution unlimited Availability: Hard copy only. This...coefficient of InGaAs V-shaped quantum wires integrated in optical waveguides by MBE growth F Filipowitzt, C. Gourgont, D. Martint, Y Magnenatt, P. Giaccarit...observation The fabrication of waveguides that contains QWR consists of three process sequences: (i) MBE growth of the lower waveguide cladding and half of the

  10. Donor impurity-related linear and nonlinear intraband optical absorption coefficients in quantum ring: effects of applied electric field and hydrostatic pressure.

    Science.gov (United States)

    Barseghyan, Manuk G; Restrepo, Ricardo L; Mora-Ramos, Miguel E; Kirakosyan, Albert A; Duque, Carlos A

    2012-09-28

    : The linear and nonlinear intraband optical absorption coefficients in GaAs three-dimensional single quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and electric field, applied along the growth direction of the heterostructure, the energies of the ground and first excited states of a donor impurity have been found using the effective mass approximation and a variational method. The energies of these states are examined as functions of the dimensions of the structure, electric field, and hydrostatic pressure. We have also investigated the dependencies of the linear, nonlinear, and total optical absorption coefficients as a function of incident photon energy for several configurations of the system. It is found that the variation of distinct sizes of the structure leads to either a redshift and/or a blueshift of the resonant peaks of the intraband optical spectrum. In addition, we have found that the application of an electric field leads to a redshift, whereas the influence of hydrostatic pressure leads to a blueshift (in the case of on-ring-center donor impurity position) of the resonant peaks of the intraband optical spectrum.

  11. Influence of image charge effect on impurity-related optical absorption coefficients and refractive index changes in a spherical quantum dot

    Science.gov (United States)

    Vartanian, A. L.; Asatryan, A. L.; Vardanyan, L. A.

    2017-03-01

    We have investigated the influence of an image charge effect (ICE) on the energies of the ground and first few excited states of a hydrogen-like impurity in a spherical quantum dot (QD) in the presence of an external electric field. The oscillator strengths of transitions from the 1 s -like state to excited states of 2px and 2pz symmetries are calculated as the functions of the strengths of the confinement potential and the electric field. Also, we have studied the effect of image charges on linear and third-order nonlinear optical absorption coefficients and refractive index changes (RICs). The results show that image charges lead to the decrease of energies for all the hydrogen-like states, to the significant enhancement of the oscillator strengths of transitions between the impurity states, and to comparatively large blue shifts in linear, nonlinear, and total absorption coefficients and refractive index changes. Our results indicate that the total optical characteristics can be controlled by the strength of the confinement and the electric field.

  12. Influence of applied electric field on the absorption coefficient and subband distances in asymmetrical AIN/GaN coupled double quantum wells

    Institute of Scientific and Technical Information of China (English)

    Cen Long-Bin; Shen Bo; qin Zhi-Xin; Zhang Guo-Yi

    2009-01-01

    The influence of applied electric fields on the absorption coefficient and subband distances in asymmetrical AlN/GaN coupled double quantum wells (CDQWs) has been investigated by solving Schrodinger and Poisson equations self-consistently. It is found that the absorption coefficient of the intersubband transition (ISBT) between the ground state and the third excited state (1odd -2even) can be equal to zero when the electric fields are applied in asymmetrical A1N/GaN CDQWs,which is related to applied electric fields induced symmetry recovery of these states. Meanwhile,the energy distances between 1odd -2even and 1even - 2even subbands have different relationships from each other with the increase of applied electric fields due to the different polarization-induced potential drops between the lett and the right wells. The results indicate that an electrical-optical modulator operated within the opto-communication wavelength range can be realized in spite of the strong polarization-induced electric fields in asymmetrical AIN/GaN CDQWs.

  13. Linear and nonlinear optical absorption coefficients and refractive index changes associated with intersubband transitions in a quantum disk with flat cylindrical geometry

    Energy Technology Data Exchange (ETDEWEB)

    Gambhir, Monica, E-mail: monica.gambhir@yahoo.com [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Kumar, Manoj [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Jha, P.K. [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Deen Dayal Upadhyaya College, University of Delhi, Delhi 110015 (India); Mohan, Man [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India)

    2013-11-15

    The linear and nonlinear optical absorption coefficients and changes in the refractive index in GaAs/AlGaAs quantum disk in the form of a flat cylinder are investigated theoretically in the presence of a static magnetic and a laser field within the framework of the compact-density matrix approach. It is found that the absorption coefficients and the refractive index changes depend not only on the optical wave intensity but also on the strength of the static magnetic field. The intersubband relaxation time, also, has an important influence on the linear and nonlinear optical properties of a quantum disk. -- Highlights: • The study is carried out in a quantum disk having quantum dot geometry. • The linear and non-linear optical properties are studied using density matrix approach. • The study is carried out in the presence of a laser field and a magnetic field. • Influence of incident photon energy and static magnetic field is analyzed. • The optical properties are found to be greatly influenced by the relaxation time.

  14. Exciton optical absorption coefficients and refractive index changes in a strained InAs/GaAs quantum wire: The effect of the magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Arunachalam, N. [Department of Physics, Government Higher Secondary School, Saruguvalayapatti, Melur 625109, Madurai (India); John Peter, A., E-mail: a.john.peter@gmail.com [Center for Environmental Studies/Green Energy Center, Department of Environmental Science and Engineering, College of Engineering, Kyung Hee University, Seocheon-dong 1, Giheung-gu, Yongin-Si, Gyeonggi-Do 446-701 (Korea, Republic of); Yoo, Chang Kyoo [Center for Environmental Studies/Green Energy Center, Department of Environmental Science and Engineering, College of Engineering, Kyung Hee University, Seocheon-dong 1, Giheung-gu, Yongin-Si, Gyeonggi-Do 446-701 (Korea, Republic of)

    2012-06-15

    Magnetic field induced exciton binding energy is investigated in a strained InAs/GaAs quantum wire within the framework of single band effective mass approximation. The strain contribution to the potential is determined through deformation potentials. The interband emission energy of strained InAs/GaAs wire is investigated in the influence of magnetic field with the various structural parameters. Magnetic field induced photoionization cross section of the exciton is studied. The total optical absorption and the refractive index changes as a function of normalized photon energy between the ground and the first excited state in the presence of magnetic field are analyzed. The optical absorption coefficients and the refractive index changes strongly depend on the incident optical intensity and the magnetic field. The occurred blueshift of the resonant peak due to the magnetic field will give the information about the variation of two energy levels in the quantum well wire. The optical absorption coefficients and the refractive index changes are strongly dependent on the incident optical intensity and the magnetic field. - Highlights: Black-Right-Pointing-Pointer Magnetic field induced exciton binding energy is investigated in a strained InAs/GaAs quantum wire. Black-Right-Pointing-Pointer The strain contribution to the potential is determined through deformation potentials. Black-Right-Pointing-Pointer The interband emission energy of strained InAs/GaAs wire is investigated with the various structural parameters. Black-Right-Pointing-Pointer Magnetic field induced photoionization cross section of the exciton is studied. Black-Right-Pointing-Pointer The optical properties strongly depend on the incident optical intensity and the magnetic field.

  15. Solar spectral optical properties of pigments--Part I: model forderiving scattering and absorption coefficients from transmittance andreflectance measurements

    Energy Technology Data Exchange (ETDEWEB)

    Levinson, Ronnen; Berdahl, Paul; Akbari, Hashem

    2004-06-01

    Pigment characterization is performed by dispersing thepigment into a transparent film of refractive index 1.5, andmeasuringspectral transmittance and reflectance. Measurements of the filmreflectance backed with black and white substrates are also used. A modelfor extracting the spectral backscattering coefficient S and absorptioncoefficient K from spectrometer measurements is presented. Interfacereflectances complicate the model. The film's diffuse reflectance andtransmittance measurements are used to determine S and K as functions ofa model parameter sigma that represents the ratio of forward to totalscattering. Sigma is used to estimate the rate at which incidentcollimated light becomes diffuse, and is determined by fitting themeasured film reflectance backed by black. A typical value is sigma=0.8.Then, the measured film reflectance backed by white is compared with acomputed value as a self-consistency check. Measurements on severalcommon pigments are used to illustrate the method.

  16. Experimental boiling heat transfer coefficients in the high temperature generator of a double effect absorption machine for the lithium bromide/water mixture

    Energy Technology Data Exchange (ETDEWEB)

    Marcos, J.D. [Escuela Tecnica Superior Ingenieria Industrial, UNED, c/Juan del Rosal 12, 28040 Madrid (Spain); Izquierdo, M. [Instituto de Ciencias de la Construccion Eduardo Torroja (CSIC), c/Serrano Galvache 4, 28033 Madrid (Spain); Escuela Politecnica Superior, Universidad Carlos III de Madrid, Avenida de la Universidad 30, 28911 Leganes, Madrid (Spain); Lizarte, R. [Escuela Politecnica Superior, Universidad Carlos III de Madrid, Avenida de la Universidad 30, 28911 Leganes, Madrid (Spain); Palacios, E. [Escuela Universitaria Ingenieria Tecnica Industrial, Universidad Politecnica de Madrid, C/ Ronda de Valencia 3, 28012 Madrid (Spain); Infante Ferreira, C.A. [Delft University of Technology, Engineering Thermodynamics, Leeghwaterstraat 44, 2628 CA Delft (Netherlands)

    2009-06-15

    The aim of this work is to determine the boiling heat transfer coefficients in the high temperature desorber (HTD) of an air-cooled double effect lithium bromide/water absorption prototype. The HTD is a plate heat exchanger (PHE) with thermal oil on one side, and a lithium bromide solution on the other side. Several experiments were performed with this PHE while the prototype was working with an outdoor dry bulb temperature around 42 C and condensation temperature around 55 C. The registered data allowed to calculate the global heat transfer coefficient and the heat transfer coefficient for the LiBr/water mixture in forced convective boiling. The pressure drop produced by the boiling of the refrigerant has been calculated as well. It has been verified that the largest part of the heat supplied in the generator is required for desorbing the refrigerant (except for the maximum solution mass flow), while the sensible heat varies from 10% to 50% of the total heat supplied. (author)

  17. Simple parametrization of photon mass energy absorption coefficients of H-, C-, N- and O-based samples of biological interest in the energy range 200–1500 keV

    Indian Academy of Sciences (India)

    V Manjunathaguru; T K Umesh

    2009-02-01

    In this paper, we provide polynomial coefficients and a semi-empirical relation using which one can derive photon mass energy absorption coefficient of any H-, C-, N-, O-based sample of biological interest containing any other elements in the atomic number range 2–40 and energy range 200–1500 keV. More interestingly, it has been observed in the present work that in this energy range, both the mass attenuation coefficients and the mass energy absorption coefficients for such samples vary only with respect to energy. Hence it was possible to represent the photon interaction properties of such samples by a mean value of these coefficients. By an independent study of the variation of the mean mass attenuation coefficient as well as mass energy absorption coefficient with energy, two simple semi-empirical relations for the photon mass energy absorption coefficients and one relation for the mass attenuation coefficient have been obtained in the energy range 200–1500 keV. It is felt that these semi-empirical relations can be very handy and convenient in biomedical and other applications. One possible significant conclusion based on the results of the present work is that in the energy region 200–1500 keV, the photon interaction characteristics of any H-, C-, N-, O-based sample of biological interest which may or may not contain any other elements in the atomic number range 2–40 can be represented by a sample-independent (single) but energy-dependent mass attenuation coefficient and mass energy absorption coefficient.

  18. Aquaporins in ovine amnion: responses to altered amniotic fluid volumes and intramembranous absorption rates.

    Science.gov (United States)

    Cheung, Cecilia Y; Anderson, Debra F; Brace, Robert A

    2016-07-01

    Aquaporins (AQPs) are transmembrane channel proteins that facilitate rapid water movement across cell membranes. In amniotic membrane, the AQP-facilitated transfer of water across amnion cells has been proposed as a mechanism for amniotic fluid volume (AFV) regulation. To investigate whether AQPs modulate AFV by altering intramembranous absorption (IMA) rate, we tested the hypothesis that AQP gene expression in the amnion is positively correlated with IMA rate during experimental conditions when IMA rate and AFV are modified over a wide range. The relative abundances of AQP1, AQP3, AQP8, AQP9, and AQP11 mRNA and protein were determined in the amnion of 16 late-gestation ovine fetuses subjected to 2 days of control conditions, urine drainage, urine replacement, or intraamniotic fluid infusion. AQP mRNA levels were determined by RT-qPCR and proteins by western immunoblot. Under control conditions, mRNA levels among the five AQPs differed more than 20-fold. During experimental treatments, mean IMA rate in the experimental groups ranged from 100 ± 120 mL/day to 1370 ± 270 mL/day. The mRNA levels of the five AQPs did not change from control and were not correlated with IMA rates. The protein levels of AQP1 were positively correlated with IMA rates (r(2) = 38%, P = 0.01) while the remaining four AQPs were not. These findings demonstrate that five AQPs are differentially expressed in ovine amnion. Our study supports the hypothesis that AQP1 may play a positive role in regulating the rate of fluid transfer across the amnion, thereby participating in the dynamic regulation of AFV.

  19. Aerosol absorption coefficient and Equivalent Black Carbon by parallel operation of AE31 and AE33 aethalometers at the Zeppelin station, Ny Ålesund, Svalbard

    Science.gov (United States)

    Eleftheriadis, Konstantinos; Kalogridis, Athina-Cerise; Vratolis, Sterios; Fiebig, Markus

    2016-04-01

    Light absorbing carbon in atmospheric aerosol plays a critical role in radiative forcing and climate change. Despite the long term measurements across the Arctic, comparing data obtained by a variety of methods across stations requires caution. A method for extracting the aerosol absorption coefficient from data obtained over the decades by filter based instrument is still under development. An IASOA Aerosol working group has been initiated to address this and other cross-site aerosol comparison opportunities. Continuous ambient measurements of EBC/light attenuation by means of a Magee Sci. AE-31 aethalometer operating at the Zeppelinfjellet station (474 m asl; 78°54'N, 11°53'E), Ny Ålesund, Svalbard, have been available since 2001 (Eleftheriadis et al, 2009), while a new aethalometer model (AE33, Drinovec et al, 2014) has been installed to operate in parallel from the same inlet since June 2015. Measurements are recorded by a Labview routine collecting all available parameters reported by the two instrument via RS232 protocol. Data are reported at 1 and 10 minute intervals as averages for EBC (μg m-3) and aerosol absorption coefficients (Mm-1) by means of routine designed to report Near Real Time NRT data at the EBAS WDCA database (ebas.nilu.no) Results for the first 6 month period are reported here in an attempt to evaluate comparative performance of the two instruments in terms of their response with respect to the variable aerosol load of light absorbing carbon during the warm and cold seasons found in the high arctic. The application of available conversion schemes for obtaining the absorption coefficient by the two instruments is found to demonstrate a marked difference in their output. During clean periods of low aerosol load (EBC agreement with regression slope for the 880 nm signal between the two at ~ 0.9 compared to a slope at ~ 0.6 during the period of higher absorbing carbon loads (400Arctic: Measurements at Zeppelin station, Ny-Ålesund, Svalbard

  20. Graphite furnace atomic absorption spectrophotometry--a novel method to quantify blood volume in experimental models of intracerebral hemorrhage.

    Science.gov (United States)

    Kashefiolasl, Sepide; Foerch, Christian; Pfeilschifter, Waltraud

    2013-02-15

    Intracerebral hemorrhage (ICH) accounts for 10% of all strokes and has a significantly higher mortality than cerebral ischemia. For decades, ICH has been neglected by experimental stroke researchers. Recently, however, clinical trials on acute blood pressure lowering or hyperacute supplementation of coagulation factors in ICH have spurred an interest to also design and improve translational animal models of spontaneous and anticoagulant-associated ICH. Hematoma volume is a substantial outcome parameter of most experimental ICH studies. We present graphite furnace atomic absorption spectrophotometric analysis (AAS) as a suitable method to precisely quantify hematoma volumes in rodent models of ICH. Copyright © 2012 Elsevier B.V. All rights reserved.

  1. Linear and nonlinear optical absorption coefficients and refractive index changes in modulation-doped quantum wells: Effects of the magnetic field and hydrostatic pressure

    Energy Technology Data Exchange (ETDEWEB)

    Nazari, M.; Karimi, M.J., E-mail: karimi@sutech.ac.ir; Keshavarz, A.

    2013-11-01

    In this study, the linear, the third-order nonlinear and total optical absorption coefficients and refractive index changes of a modulation-doped GaAs/Al{sub x}Ga{sub 1−x}As quantum well are investigated numerically. In the effective-mass approximation, the electronic structure of modulation-doped quantum well is calculated by solving the Schrödinger and Poisson equations self-consistently. Optical properties are obtained using the compact density matrix approach. The effects of structure parameters, the applied magnetic field and the hydrostatic pressure on the optical properties of the modulation-doped quantum well are studied. Results show that the resonant peaks shift toward the higher (lower) energies with the increase in the magnetic field (pressure). The magnitude of the resonant peaks of the optical properties decreases with the increasing magnetic field or pressure.

  2. Gradient-based quantitative reconstruction of optical absorption and scattering coefficients in ultrasound-modulated optical tomography: first harmonic measurement type

    CERN Document Server

    Powell, Samuel; Leung, Terence S

    2014-01-01

    Ultrasound-modulated optical tomography is an emerging biomedical imaging modality which uses the spatially localised acoustically-driven modulation of coherent light as a probe of the structure and optical properties of biological tissues. In this work we pose the inverse problem of simultaneously recovering the optical absorption and scattering coefficients in a given domain from measurement of the power-spectral density of the optical field modulated to the acoustic frequency. As part of this exposition we provide an overview of forward modelling techniques, and derive an efficient linearised diffusion-style model. To ameliorate the computational burden and memory requirements of a traditional Newton-based optimisation approach, we develop an adjoint-assisted gradient based method. We validate our reconstruction in two- and three-dimensions using simulated measurements with 1% proportional Gaussian noise, and demonstrate the successful recovery of the parameters to within +/-5% of their true values when th...

  3. Calculation procedure to determine average mass transfer coefficients in packed columns from experimental data for ammonia-water absorption refrigeration systems

    Energy Technology Data Exchange (ETDEWEB)

    Sieres, Jaime; Fernandez-Seara, Jose [University of Vigo, Area de Maquinas y Motores Termicos, E.T.S. de Ingenieros Industriales, Vigo (Spain)

    2008-08-15

    The ammonia purification process is critical in ammonia-water absorption refrigeration systems. In this paper, a detailed and a simplified analytical model are presented to characterize the performance of the ammonia rectification process in packed columns. The detailed model is based on mass and energy balances and simultaneous heat and mass transfer equations. The simplified model is derived and compared with the detailed model. The range of applicability of the simplified model is determined. A calculation procedure based on the simplified model is developed to determine the volumetric mass transfer coefficients in the vapour phase from experimental data. Finally, the proposed model and other simple calculation methods found in the general literature are compared. (orig.)

  4. Determination of the quasi-TE mode (in-plane) graphene linear absorption coefficient via integration with silicon-on-insulator racetrack cavity resonators.

    Science.gov (United States)

    Crowe, Iain F; Clark, Nicholas; Hussein, Siham; Towlson, Brian; Whittaker, Eric; Milosevic, Milan M; Gardes, Frederic Y; Mashanovich, Goran Z; Halsall, Matthew P; Vijayaraghaven, Aravind

    2014-07-28

    We examine the near-IR light-matter interaction for graphene integrated cavity ring resonators based on silicon-on-insulator (SOI) race-track waveguides. Fitting of the cavity resonances from quasi-TE mode transmission spectra reveal the real part of the effective refractive index for graphene, n(eff) = 2.23 ± 0.02 and linear absorption coefficient, α(gTE) = 0.11 ± 0.01dBμm(-1). The evanescent nature of the guided mode coupling to graphene at resonance depends strongly on the height of the graphene above the cavity, which places limits on the cavity length for optical sensing applications.

  5. Nonlinear absorption coefficient and relative refraction index change for an asymmetrical double δ-doped quantum well in GaAs with a Schottky barrier potential

    Energy Technology Data Exchange (ETDEWEB)

    Rojas-Briseño, J.G.; Martínez-Orozco, J.C.; Rodríguez-Vargas, I. [Unidad Académica de Física, Universidad Autónoma de Zacatecas, Calzada Solidaridad esquina con Paseo la Bufa S/N, C.P. 98060, Zacatecas, Zac. (Mexico); Mora-Ramos, M.E. [Facultad de Ciencias, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, CP 62209, Cuernavaca, Morelos (Mexico); Instituto de Física, Universidad de Antioquia, AA 1226, Medellín (Colombia); Duque, C.A., E-mail: cduque@fisica.udea.edu.co [Instituto de Física, Universidad de Antioquia, AA 1226, Medellín (Colombia)

    2013-09-01

    In this work we are reporting the energy level spectrum for a quantum system consisting of an n-type double δ-doped quantum well with a Schottky barrier potential in a Gallium Arsenide matrix. The calculated states are taken as the basis for the evaluation of the linear and third-order nonlinear contributions to the optical absorption coefficient and to the relative refractive index change, making particular use of the asymmetry of the potential profile. These optical properties are then reported as a function of the Schottky barrier height (SBH) and the separation distance between the δ-doped quantum wells. Also, the effects of the application of hydrostatic pressure are studied. The results show that the amplitudes of the resonant peaks are of the same order of magnitude of those obtained in the case of single δ-doped field effect transistors; but tailoring the asymmetry of the confining potential profile allows the control the resonant peak positions.

  6. Noninvasive determination of absorption and reduced scattering coefficients of adult heads by time-resolved reflectance measurements for functional near infra-red spectroscopy.

    Science.gov (United States)

    Tanifuji, T; Wang, L

    2014-01-01

    Absorption and reduced scattering coefficients (μ(a) and μ'(s)) of adult heads have been noninvasively determined by time-resolved reflectance measurements. The finite difference time domain (FDTD) analysis was used to calculate time-resolved reflectance from realistic adult head models with brain grooves containing a non-scattering layer. In vivo time-resolved reflectances of human heads were measured by a system composed of a time-correlated single photon counter and a diode laser. By minimizing the objective functions that compare theoretical and experimental time resolved reflectances, μ(a) and μ'(s) of brain were determined. It became clear that time-resolved measurements have enough sensitivity to determine both μ(a) and μ'(s) for superficial tissues, gray matter and white matter, except μ(s) for white matter.

  7. Molar absorption coefficients and stability constants of metal complexes of 4-(2-pyridylazo)resorcinol (PAR): Revisiting common chelating probe for the study of metalloproteins.

    Science.gov (United States)

    Kocyła, Anna; Pomorski, Adam; Krężel, Artur

    2015-11-01

    4-(2-Pyridylazo)resorcinol (PAR) is one of the most popular chromogenic chelator used in the determination of the concentrations of various metal ions from the d, p and f blocks and their affinities for metal ion-binding biomolecules. The most important characteristics of such a sensor are the molar absorption coefficient and the metal-ligand complex dissociation constant. However, it must be remembered that these values are dependent on the specific experimental conditions (e.g. pH, solvent components, and reactant ratios). If one uses these values to process data obtained in different conditions, the final result can be under- or overestimated. We aimed to establish the spectral properties and the stability of PAR and its complexes accurately with Zn(2+), Cd(2+), Hg(2+), Co(2+), Ni(2+), Cu(2+), Mn(2+) and Pb(2+) at a multiple pH values. The obtained results account for the presence of different species of metal-PAR complexes in the physiological pH range of 5 to 8 and have been frequently neglected in previous studies. The effective molar absorption coefficient at 492 nm for the ZnHx(PAR)2 complex at pH7.4 in buffered water solution is 71,500 M(-1) cm(-1), and the dissociation constant of the complex in these conditions is 7.08×10(-13) M(2). To confirm these values and estimate the range of the dissociation constants of zinc-binding biomolecules that can be measured using PAR, we performed several titrations of zinc finger peptides and zinc chelators. Taken together, our results provide the updated parameters that are applicable to any experiment conducted using inexpensive and commercially available PAR.

  8. Prediction of subacute infarct lesion volumes by processing apparent diffusion coefficient maps based on apparent diffusion coefficient cut-off values in patients with acute stroke

    Institute of Scientific and Technical Information of China (English)

    郭翔

    2014-01-01

    Objective To explore the feasibility of prediction of subacute infarct lesion volumes by processing ADC maps based on ADC cut-off values in patients with acute stroke.Methods MRI was performed in 20 patients with clinically diagnosed acute infarct less than 6 h after stroke onset.The MRI included a DWI and conventional MRI.The follow-up MR examinations of all the patients

  9. UV/VIS SPECTROMETER DETERMINATION OF CAFFEINE IN GREEN COFFEE BEANS FROM HARARGHE, ETHIOPIA, USING BEER-LAMBERT’S LAW AND INTEGRATED ABSORPTION COEFFICIENT TECHNIQUES

    Directory of Open Access Journals (Sweden)

    EPHREM G. DEMISSIE

    2016-07-01

    Full Text Available A total of fifteen samples of green coffee (Coffea arabica L. beans from the major producing region of Hararghe Ethiopia were studied using UV-Vis spectrometer measurement caffeine quantitative analysis from coffee beans. The number density of caffeine in green coffee beans has been reported using Beer-Lambert’s law and integrating absorption coefficient technique. Our results obtained using integrated absorption and Beer-Lambert’s law has a good agreement and we observed a maximum difference of 10.4 %. Based on their low caffeine concentrations among the samples collected were found in Jarso coffee. Coffee beans from the Harar Aboker were characterized by higher concentrations of caffeine. The determined concentration for caffeine in coffee beans (% w/w ranged 0.601 % to 0.903 %. The concentrations of the caffeine varied significantly, depending on the geographical origin of the beans. The concentrations of caffeine in coffee collected from in Hararghe region were noticeably lower than their counterpart (1.0 - 1.2 % grows in the other parts of Ethiopia.

  10. Measurement of mass attenuation coefficients in some Cr, Co and Fe compounds around the absorption edge and the validity of the mixture rule

    Indian Academy of Sciences (India)

    U Turgut; O Şimşek; E Büyükkasap

    2007-08-01

    The total mass attenuation coefficients for elements Cr, Co and Fe and compounds CrCl2, CrCl3, Cr2(SO4)32SO4·24H2O, CoO, CoCl2, Co(CH3COO)2, FePO4, FeCl3·6H2O, Fe(SO4)2NH4·12H2O were measured at different energies between 4.508 and 14.142 keV using secondary excitation method. Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr were chosen as secondary exciters. 59.5 keV -rays emitted from a 241Am annular source were used to excite a secondary exciter and K (K-L3, L2) lines emitted by the secondary exciter were counted by a Si(Li) detector with a resolution of 160 eV at 5.9 keV. It was observed that mixture rule method is not a suitable method for determination of the mass attenuation coefficients of compounds, especially at an energy that is near the absorption edge. The obtained values were compared with theoretical values.

  11. Mg II Absorption Characteristics of a Volume-Limited Sample of Galaxies at z ~ 0.1

    Science.gov (United States)

    Barton, Elizabeth J.; Cooke, Jeff

    2009-12-01

    We present an initial survey of Mg II absorption characteristics in the halos of a carefully constructed, volume-limited subsample of galaxies embedded in the spectroscopic part of the Sloan Digital Sky Survey (SDSS). We observed quasars near sightlines to 20 low-redshift (z ~ 0.1), luminous (M r + 5log h background quasar within a projected 75 h -1 kpc of its center, although we preferentially sample galaxies with lower impact parameters and slightly more star formation within this range. Of the observed systems, six exhibit strong (W eq(2796) >= 0.3 Å) Mg II absorption at the galaxy's redshift, six systems have upper limits which preclude strong Mg II absorption, while the remaining observations rule out very strong (W eq(2796) >= 1-2 Å) absorption. The absorbers fall at higher impact parameters than many non-absorber sightlines, indicating a covering fraction fc lsim 0.4 for >=0.3 Å absorbers at z ~ 0.1, even at impact parameters Technology, the University of California, and the National Aeronautics and Space Administration. The Observatory was made possible by the generous financial support of the W. M. Keck Foundation.

  12. Effects of organometallic chelates and inulin in diets for laying hens on Mn and Fe absorption coefficients and their content in egg and tissue

    Directory of Open Access Journals (Sweden)

    Cornescu Gabriela Maria

    2015-01-01

    Full Text Available The aim of this study was to evaluate effects of organic sources of manganese (Mn and iron (Fe and inulin in diets for laying hens on absorption of these minerals and their deposition in egg and tissue. The study was conducted on 90 Lohmann Brown laying hens in the period from 46-52 weeks of age, assigned to 3 groups with 30 hens/group and 3 hens/cage. The hens from the control group (C received a diet based on corn, rice bran and soybean meal with 16% of crude protein, as well as 60 mg Fe/kg and 71.9 mg Mn/kg of diet in form of inorganic salts. The formulation of the experimental diets (E1 and E2 differed from C group diet by the replacement of inorganic Fe and Mn salts by organometallic chelates of these elements, at a level of 25% lower than in the premix for group C. As source of inulin, group E1 diet also included 0.5% of dry Jerusalem artichoke, while group E2 diet included 0.5% of a product based on chicory root extract. At the end of the experiment, 6 hens from each group were slaughtered and blood serum and liver samples were collected and assayed for concentration of Fe and Mn. In the final week of the experiment, 18 eggs/group were collected for determination of Fe and Mn concentration in egg yolk. Concentration of measured blood serum parameters (haemoglobin, haematocrit, Fe and Mn in experimental (E groups were lower than in group C, but no significant differences (P>0.05 were registered. Absorption coefficients of Mn had higher values in E groups than in group C, with significant increase (P0.05 between groups were observed for Mn and Fe concentration in egg yolk.

  13. Equivalent Black Carbon measurements and spectral analysis of absorption coefficient during a biomass burning episode in the city of Bogotá, Colombia.

    Science.gov (United States)

    Quirama, M.; Morales, R.

    2016-12-01

    Light-absorbing carbonaceous aerosol is recognized as a significant short lived climate pollutant that can contribute to direct and indirect radiative forcing. In urban environments, black carbon is an important contributor to the deterioration of local air quality. In this study, we report measurements of equivalent Black Carbon performed during the months of January, February, and March 2016 in the city of Bogotá, Colombia. During this period, a persistent condition of atmospheric stability lead to high concentrations of particulate matter throughout the city. During the month of February, the city was further impacted by a series of small-scale forest fires that took place on hills neighboring the city center. Equivalent Black Carbon (eBC) concentrations were monitored before, during, and after a mayor forest fire episode with a 7-wavelength Aethalometer. The monitoring instruments were located at a traffic impacted site, 18.3 km from the forest fire. To evaluate the contribution of biomass burning to the light-absorbing aerosol particle concentration, spectral analysis of the absorption coefficient of the sampled aerosol particles was performed. When the biomass burning plume directly impacted the monitoring station during the night of February 4, eBC concentrations of up to 40 µg/m3 were observed at nighttime. This concentration was significantly higher than average nighttime concentrations of eBC, observed to be 4 µg/m3 at the site. However, during the period most intensely affected by the biomass burning plume, the angstrom exponent computed between the 450nm and the 970 nm channel, was found to be close to 1. Angstrom exponent close to 1 is an indication that the contribution from traffic generated black carbon is dominant compared to the contribution of biomass burning. The data set collected during this period suggests that despite the significant contribution of the fresh biomass burning plume to the particulate matter concentration in the city, the

  14. Atmospheric Chemistry of 1-Methoxy 2-Propyl Acetate: UV Absorption Cross Sections, Rate Coefficients, and Products of Its Reactions with OH Radicals and Cl Atoms.

    Science.gov (United States)

    Zogka, Antonia G; Mellouki, Abdelwahid; Romanias, Manolis N; Bedjanian, Yuri; Idir, Mahmoud; Grosselin, Benoit; Daële, Véronique

    2016-11-17

    The rate coefficients for the reactions of OH and Cl with 1-methoxy 2-propyl acetate (MPA) in the gas phase were measured using absolute and relative methods. The kinetic study on the OH reaction was conducted in the temperature (263-373) K and pressure (1-760) Torr ranges using the pulsed laser photolysis-laser-induced fluorescence technique, a low pressure fast flow tube reactor-quadrupole mass spectrometer, and an atmospheric simulation chamber/GC-FID. The derived Arrhenius expression is kMPA+OH(T) = (2.01 ± 0.02) × 10(-12) exp[(588 ± 123/T)] cm(3) molecule(-1) s(-1). The absolute and relative rate coefficients for the reaction of Cl with MPA were measured at room temperature in the flow reactor and the atmospheric simulation chamber, which led to k(Cl+MPA) = (1.98 ± 0.31) × 10(-10) cm(3) molecule(-1) s(-1). GC-FID, GC-MS, and FT-IR techniques were used to investigate the reaction mechanism in the presence of NO. The products formed from the reaction of MPA with OH and their yields were methyl formate (80 ± 7.3%), acetic acid (50 ± 4.8%), and acetic anhydride (22 ± 2.4%), while for Cl reaction, the obtained yields were 60 ± 5.4, 41 ± 3.8, and 11 ± 1.2%, respectively, for the same products. The UV absorption cross section spectrum of MPA was determined in the wavelength range 210-370 nm. The study has shown no photolysis of MPA under atmospheric conditions. The obtained results are used to derive the atmospheric implication.

  15. The effect of realistic heavy particle induced secondary electron emission coefficients on the electron power absorption dynamics in single- and dual-frequency capacitively coupled plasmas

    Science.gov (United States)

    Daksha, M.; Derzsi, A.; Wilczek, S.; Trieschmann, J.; Mussenbrock, T.; Awakowicz, P.; Donkó, Z.; Schulze, J.

    2017-08-01

    In particle-in-cell/Monte Carlo collisions (PIC/MCC) simulations of capacitively coupled plasmas (CCPs), the plasma-surface interaction is generally described by a simple model in which a constant secondary electron emission coefficient (SEEC) is assumed for ions bombarding the electrodes. In most PIC/MCC studies of CCPs, this coefficient is set to γ = 0.1, independent of the energy of the incident particle, the electrode material, and the surface conditions. Here, the effects of implementing energy-dependent secondary electron yields for ions, fast neutrals, and taking surface conditions into account in PIC/MCC simulations is investigated. Simulations are performed using self-consistently calculated effective SEECs, {γ }* , for ‘clean’ (e.g., heavily sputtered) and ‘dirty’ (e.g., oxidized) metal surfaces in single- and dual-frequency discharges in argon and the results are compared to those obtained by assuming a constant secondary electron yield of γ =0.1 for ions. In single-frequency (13.56 MHz) discharges operated under conditions of low heavy particle energies at the electrodes, the pressure and voltage at which the transition between the α- and γ-mode electron power absorption occurs are found to strongly depend on the surface conditions. For ‘dirty’ surfaces, the discharge operates in α-mode for all conditions investigated due to a low effective SEEC. In classical dual-frequency (1.937 MHz + 27.12 MHz) discharges {γ }* significantly increases with increasing low-frequency voltage amplitude, {V}{LF}, for dirty surfaces. This is due to the effect of {V}{LF} on the heavy particle energies at the electrodes, which negatively influences the quality of the separate control of ion properties at the electrodes. The new results on the separate control of ion properties in such discharges indicate significant differences compared to previous results obtained with different constant values of γ.

  16. Evaluation of Compton attenuation and photoelectric absorption coefficients by convolution of scattering and primary functions and counts ratio on energy spectra

    Science.gov (United States)

    Ashoor, Mansour; Asgari, Afrouz; Khorshidi, Abdollah; Rezaei, Ali

    2015-01-01

    Purpose: Estimation of Compton attenuation and the photoelectric absorption coefficients were explored at various depths. Methods: A new method was proposed for estimating the depth based on the convolution of two exponential functions, namely convolution of scattering and primary functions (CSPF), which the convolved result will conform to the photopeak region of energy spectrum with the variable energy-window widths (EWWs) and a theory on the scattering cross-section. The triple energy-windows (TEW) and extended triple energy-windows scatter correction (ETEW) methods were used to estimate the scattered and primary photons according to the energy spectra at various depths due to a better performance than the other methods in nuclear medicine. For this purpose, the energy spectra were employed, and a distinct phantom along with a technetium-99 m source was simulated by Monte Carlo method. Results: The simulated results indicate that the EWW, used to calculate the scattered and primary counts in terms of the integral operators on the functions, was proportional to the depth as an exponential function. The depth will be calculated by the combination of either TEW or ETEW and proposed method resulting in the distinct energy-window. The EWWs for primary photons were in good agreement with those of scattered photons at the same as depths. The average errors between these windows for both methods TEW, and ETEW were 7.25% and 6.03% at different depths, respectively. The EWW value for functions of scattered and primary photons was reduced by increasing the depth in the CSPF method. Conclusions: This coefficient may be an index for the scattering cross-section. PMID:26170567

  17. Photolysis rate coefficients in the upper atmosphere: Effect of line by line calculations of the O{sub 2} absorption cross section in the Schumann-Runge bands

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, Rafael P. [INFIQC, Centro Laser de Ciencias Moleculares, Departamento de Fisico Quimica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, 5000, Cordoba (Argentina); Palancar, Gustavo G. [INFIQC, Centro Laser de Ciencias Moleculares, Departamento de Fisico Quimica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, 5000, Cordoba (Argentina)]. E-mail: palancar@fcq.unc.edu.ar; Madronich, Sasha [Atmospheric Chemistry Division, National Center for Atmospheric Research, 1850 Table mesa Drive, Boulder, CO, 80303 (United States); Toselli, Beatriz M. [INFIQC, Centro Laser de Ciencias Moleculares, Departamento de Fisico Quimica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, 5000, Cordoba (Argentina)]. E-mail: tosellib@fcq.unc.edu.ar

    2007-03-15

    A line by line (LBL) method to calculate highly resolved O{sub 2} absorption cross sections in the Schumann-Runge (SR) bands region was developed and integrated in the widely used Tropospheric Ultraviolet Visible (TUV) model to calculate accurate photolysis rate coefficients (J values) in the upper atmosphere at both small and large solar zenith angles (SZA). In order to obtain the O{sub 2} cross section between 49,000 and 57,000cm{sup -1}, an algorithm which considers the position, strength, and half width of each spectral line was used. Every transition was calculated by using the HIgh-resolution TRANsmission molecular absorption database (HITRAN) and a Voigt profile. The temperature dependence of both the strength and the half widths was considered within the range of temperatures characteristic of the US standard atmosphere, although the results show a very good agreement also at 79K. The cross section calculation was carried out on a 0.5cm{sup -1} grid and the contributions from all the lines lying at +/-500cm{sup -1} were considered for every wavelength. Both the SR and the Herzberg continuums were included. By coupling the LBL method to the TUV model, full radiative transfer calculations that compute J values including Rayleigh scattering at high altitudes and large SZA can now be done. Thus, the J values calculations were performed for altitudes from 0 to 120km and for SZA up to 89{sup o}. The results show, in the J{sub O{sub 2}} case, differences of more than +/-10% (e.g. at 96km and 30{sup o}) when compared against the last version of the TUV model (4.4), which uses the Koppers and Murtagh parameterization for the O{sub 2} cross section. Consequently, the J values of species with cross sections overlapping the SR band region show variable differences at lower altitudes. Although many species have been analyzed, the results for only four of them (O{sub 2}, N{sub 2}O, HNO{sub 3}, CFC12) are presented. Due to the fact that the HNO{sub 3} absorption cross

  18. Intersubband optical absorption coefficients and refractive index changes in a graded quantum well under intense laser field: Effects of hydrostatic pressure, temperature and electric field

    Energy Technology Data Exchange (ETDEWEB)

    Ungan, F., E-mail: fungan@cumhuriyet.edu.tr [Department of Physics, Cumhuriyet University, 58140 Sivas (Turkey); Grupo de Materia Condensade-UdeA, Instituto de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Restrepo, R.L. [Grupo de Materia Condensade-UdeA, Instituto de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Escuela de Ingeniería de Antioquia AA 7516, Medellín (Colombia); Mora-Ramos, M.E. [Grupo de Materia Condensade-UdeA, Instituto de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Facultad de Ciencias, Universidad Autonoma del Estado de Morelos, Ave. Universidad 1001, CP 62209, Cuernavaca, Morelos (Mexico); Morales, A.L.; Duque, C.A. [Grupo de Materia Condensade-UdeA, Instituto de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia)

    2014-02-01

    The effects of hydrostatic pressure, temperature, and electric field on the optical absorption coefficients and refractive index changes associated with intersubband transition in a typical GaAs/Ga{sub 0.7}Al{sub 0.3}As graded quantum well under intense laser field have been investigated theoretically. The electron energy eigenvalues and the corresponding eigenfunctions of the graded quantum well are calculated within the effective mass approximation and envelope wave function approach. The analytical expressions of the optical properties are obtained using the compact density-matrix approach and the iterative method. The numerical results show that the linear and nonlinear optical properties depend strongly on the intense laser field and electric field but weakly on the hydrostatic pressure and temperature. Additionally, it has been found that the electronic and optical properties in a GaAs/Ga{sub 0.7}Al{sub 0.3}As graded quantum well under the intense laser field can be tuned by changing these external inputs. Thus, these results give a new degree of freedom in the devices applications.

  19. Absorption coefficients of chlorine-dioxide at /sup 12/C/sup 16/O/sub 2/ and /sup 12/C/sup 18/O/sub 2/ laser wavelengths: applications to remote monitoring in the working environment

    Energy Technology Data Exchange (ETDEWEB)

    Ahlberg, H.; Lundqvist, S.; Eng, S.T.

    1984-09-01

    Absorption coefficients of chlorine-dioxide at /sup 12/C/sup 16/O/sub 2/ and /sup 12/C/sup 18/O/sub 2/ laser wavelengths have been measured using a computerized CO/sub 2/ laser spectrometer. The results show that there is a large differential absorption in the 9-..mu..m band due to the ..nu../sub 3/ vibrational mode in the ClO/sub 2/ molecule and that remote sensing of ClO/sub 2/ with a sensitivity of 12 ppm x m can be performed using a long-path differential absorption technique.

  20. Influence of bioassay volume, water column height, and octanol-water partition coefficient on the toxicity of pesticides to rainbow trout.

    Science.gov (United States)

    Altinok, Ilhan; Capkin, Erol; Boran, Halis

    2011-06-01

    Effects of water volume and water column height on toxicity of cypermethrin, carbaryl, dichlorvos, tetradifon, maneb, captan, carbosulfan endosulfan and HgCl₂ to juvenile rainbow trout (Oncorhynchus mykiss, 3.2 ± 0.7 g) were evaluated in different glass aquaria under static conditions. When fish were exposed to the chemical compounds in 23 cm water column height (25 L), their mortality ranged between 0% and 58%. At the same water volume, but lower water column height (9 cm), mortality of fish increased significantly and was in a range from 60% to 95%. At the same water column height, toxic effects of chemicals were significantly higher in 25 L water volume than that of 8.5 L, water except maneb which has lowest (-0.45) octanol-water partition coefficient value. Mortality rates ratio of 9 and 23 cm water column height ranged between 1.12 and 90 while mortality rates ratio of 9 and 25 L water volume ranged between 1.20 and 4.0. Because actual exposure concentrations were not affected by either water volume or water column height, we propose that increased pesticides' toxicity was related to an increase in bioassay volume, since more pesticide molecules were able to interact with or accumulate the fish. However, there seem to be no relationship between the effects of water volume, water column height and Kow value of chemicals with regard to toxicity in juvenile rainbow trout.

  1. Apparent molar volumes and viscosity B-coefficients of caffeine in aqueous thorium nitrate solutions at T = (298.15, 308.15, and 318.15) K

    Energy Technology Data Exchange (ETDEWEB)

    Sinha, Biswajit, E-mail: biswachem@gmail.co [Department of Chemistry, University of North Bengal, Darjeeling 734013 (India); Roy, Pran Kumar; Sarkar, Bipul Kumar; Brahman, Dhiraj [Department of Chemistry, University of North Bengal, Darjeeling 734013 (India); Roy, Mahendra Nath, E-mail: mahendraroy2002@yahoo.co.i [Department of Chemistry, University of North Bengal, Darjeeling 734013 (India)

    2010-03-15

    Apparent molar volumes phi{sub V} and viscosity B-coefficients for caffeine in (0.00, 0.03, 0.05, and 0.07) mol . dm{sup -3} aqueous thorium nitrate, Th(NO{sub 3}){sub 4}, solutions were determined from solution density and viscosity measurements over the temperature range (298.15 to 318.15) K as function of concentration of caffeine and the relation: phi{sub V}{sup 0}=a{sub 0}+a{sub 1}T+a{sub 2}T{sup 2}, have been used to describe the temperature dependence of the standard partial molar volumes phi{sub V}{sup 0}. These results have been used to deduce the standard volumes of transfer DELTAphi{sub V}{sup 0} and viscosity B-coefficients of transfer DELTAB for caffeine from water to aqueous Th(NO{sub 3}){sub 4} solutions for rationalizing various interactions in the ternary solutions. The structure-making or breaking ability of caffeine has been discussed in terms of the sign of (delta{sup 2}phi{sub V}{sup 0}/deltaT{sup 2}){sub P}. The Friedman-Krishnan co-sphere model was used to explain the transfer volume of caffeine with increasing Th(NO{sub 3}){sub 4} molarity. The activation parameters of viscous flow for the ternary solutions were also discussed in terms of transition state theory.

  2. SAMPL5: 3D-RISM partition coefficient calculations with partial molar volume corrections and solute conformational sampling

    Science.gov (United States)

    Luchko, Tyler; Blinov, Nikolay; Limon, Garrett C.; Joyce, Kevin P.; Kovalenko, Andriy

    2016-11-01

    Implicit solvent methods for classical molecular modeling are frequently used to provide fast, physics-based hydration free energies of macromolecules. Less commonly considered is the transferability of these methods to other solvents. The Statistical Assessment of Modeling of Proteins and Ligands 5 (SAMPL5) distribution coefficient dataset and the accompanying explicit solvent partition coefficient reference calculations provide a direct test of solvent model transferability. Here we use the 3D reference interaction site model (3D-RISM) statistical-mechanical solvation theory, with a well tested water model and a new united atom cyclohexane model, to calculate partition coefficients for the SAMPL5 dataset. The cyclohexane model performed well in training and testing (R=0.98 for amino acid neutral side chain analogues) but only if a parameterized solvation free energy correction was used. In contrast, the same protocol, using single solute conformations, performed poorly on the SAMPL5 dataset, obtaining R=0.73 compared to the reference partition coefficients, likely due to the much larger solute sizes. Including solute conformational sampling through molecular dynamics coupled with 3D-RISM (MD/3D-RISM) improved agreement with the reference calculation to R=0.93. Since our initial calculations only considered partition coefficients and not distribution coefficients, solute sampling provided little benefit comparing against experiment, where ionized and tautomer states are more important. Applying a simple pK_{ {a}} correction improved agreement with experiment from R=0.54 to R=0.66, despite a small number of outliers. Better agreement is possible by accounting for tautomers and improving the ionization correction.

  3. On the optical absorption coefficient of Gd hydride thin films: coexistence of the Gd (GdH{sub 2}) and GdH{sub x} (GdH{sub 2+y}) phases

    Energy Technology Data Exchange (ETDEWEB)

    Vargas, W E; Azofeifa, D E; Clark, N [Centro de Investigacion en Ciencias e IngenierIa de Materiales and Escuela de Fisica, Universidad de Costa Rica, 2060 San Jose (Costa Rica)], E-mail: william.vargascastro@ucr.ac.cr

    2009-01-07

    Electron beam evaporated Pd-capped Gd thin films were deposited on quartz substrates and subsequently hydrided. Transmittance spectra of these bilayer systems, under unpolarized normal illumination, were obtained and used in an inversion approach from which the spectral dependence of the effective optical constants is obtained. The optical absorption coefficient of the {beta}-phase GdH{sub x} (with 1 < x {<=} 2) is reported. The semiconductor GdH{sub 2+y} state (with 0 < y {<=} 1) is characterized in terms of the optical absorption coefficient and the optical gap. By assuming a granular morphology of the films, with some of the grains in the metal GdH{sub 2} phase and other grains covered with a transition layer containing the semiconducting GdH{sub 2+y} phase, the hydrogen concentration dependence of the optical gap is shown and the optical absorption edge of the stoichiometric {gamma}-phase GdH{sub 3} is reported.

  4. Hyperpolarized 3He apparent diffusion coefficient MRI of the lung: reproducibility and volume dependency in healthy volunteers and patients with emphysema

    DEFF Research Database (Denmark)

    Diaz, S.; Casselbrant, I.; Piitulainen, E.;

    2008-01-01

    PURPOSE: To measure the apparent diffusion coefficient (ADC) of hyperpolarized (HP) (3)He gas using diffusion weighted MRI in healthy volunteers and patients with emphysema and examine the reproducibility and volume dependency. MATERIALS AND METHODS: A total of eight healthy volunteers and 16...... days was good in both healthy volunteers and patients (SD range of 0.003-0.013 cm(2)/second and 0.001-0.009 cm(2)/second at 6% and 15% of TLC for healthy volunteers, and a SD range of 0.001-0.041 cm(2)/second and 0.001-0.011 cm(2)/second, respectively, for patients). A minor but significant increase...... in mean ADC with increased inhaled gas volume was observed in both groups. CONCLUSION: Mean ADC and SD of HP (3)He MRI is reproducible and discriminates well between healthy controls and patients with emphysema at the higher gas volume. This method is robust and may be useful to gain new insights...

  5. Investigation of techniques to quantify in vivo lesion volume based on comparison of water apparent diffusion coefficient (ADC) maps with histology in focal cerebral ischemia of rats.

    Science.gov (United States)

    Kazemi, Mark; Silva, Matthew D; Li, Fuhai; Fisher, Marc; Sotak, Christopher H

    2004-06-01

    Stroke lesion-volume estimates derived from calculated water apparent diffusion coefficient (ADC) maps provide a quantitative surrogate end-point for investigating the efficacy of drug treatment or studying the temporal evolution of cerebral ischemia. Methodology is described for estimating ischemic lesion volumes in a rat model of permanent middle cerebral artery occlusion (MCAO) based on absolute and percent-reduction threshold values of the water ADC at 3 h post-MCAO. Volume estimates derived from average ADC (ADC(av)) maps were compared with those derived from post-mortem histological sections. Optimum ADC thresholds were established as those that provided the best correlation and one-to-one correspondence between ADC- and histologically derived lesion-volume estimates. At 3 h post-MCAO, an absolute-ADC(av) threshold of 47 x 10(-5) mm(2)/s (corresponding to a 33% reduction in ADC(av) based on a contralateral hemisphere comparison) provided the most accurate estimate of percent hemispheric lesion volume (%HLV). Experimental and data analysis issues for improving and validating the usefulness of DWI as a surrogate endpoint for the quantification of ischemic lesion volume are discussed.

  6. The spectral absorption coefficient at 254 nm as a real-time early warning proxy for detecting faecal pollution events at alpine karst water resources.

    Science.gov (United States)

    Stadler, H; Klock, E; Skritek, P; Mach, R L; Zerobin, W; Farnleitner, A H

    2010-01-01

    Because spring water quality from alpine karst aquifers can change very rapidly during event situations, water abstraction management has to be performed in near real-time. Four summer events (2005-2008) at alpine karst springs were investigated in detail in order to evaluate the spectral absorption coefficient at 254 nm (SAC254) as a real-time early warning proxy for faecal pollution. For the investigation Low-Earth-Orbit (LEO) Satellite-based data communication between portable hydrometeorological measuring stations and an automated microbiological sampling device was used. The method for event triggered microbial sampling and analyzing was already established and described in a previous paper. Data analysis including on-line event characterisation (i.e. precipitation, discharge, turbidity, SAC254) and comprehensive E. coli determination (n>800) indicated that SAC254 is a useful early warning proxy. Irrespective of the studied event situations SAC254 always increased 3 to 6 hours earlier than the onset of faecal pollution, featuring different correlation phases. Furthermore, it seems also possible to use SAC254 as a real-time proxy parameter for estimating the extent of faecal pollution after establishing specific spring and event-type calibrations that take into consideration the variability of the occurrence and the transferability of faecal material It should be highlighted that diffuse faecal pollution from wildlife and live stock sources was responsible for spring water contamination at the investigated catchments. In this respect, the SAC254 can also provide useful information to support microbial source tracking efforts where different situations of infiltration have to be investigated.

  7. The spectral absorption coefficient at 254nm as a real-time early warning proxy for detecting faecal pollution events at alpine karst water resources

    Science.gov (United States)

    Stadler, H.; Klock, E.; Skritek, P.; Mach, R.L.; Zerobin, W.; Farnleitner, A.H.

    2011-01-01

    Because spring water quality from alpine karst aquifers can change very rapidly during event situations, water abstraction management has to be performed in near real-time. Four summer events (2005-2008) at alpine karst springs were investigated in detail in order to evaluate the spectral absorption coefficient at 254nm (SAC254) as a real-time early warning proxy for faecal pollution. For the investigation Low-Earth-Orbit (LEO) Satellite-based data communication between portable hydrometeorological measuring stations and an automated microbiological sampling device was used. The method for event triggered microbial sampling and analyzing was already established and described in a previous paper (Stadler et al., Wat. Sci. Technol. 58(4): 899-909, 2008). Data analysis including on-line event characterisation (i.e. precipitation, discharge, turbidity, SAC254) and comprehensive E. coli determination (n > 800) indicated that SAC254 is a useful early warning proxy. Irrespective of the studied event situations SAC254 always increased 3 to 6 hours earlier than the onset of faecal pollution, featuring different correlation phases. Furthermore, it seems also possible to use SAC254 as a real-time proxy parameter for estimating the extent of faecal pollution after establishing specific spring and event-type calibrations that take into consideration the variability of the occurrence and the transferability of faecal material It should be highlighted that diffuse faecal pollution from wildlife and live stock sources was responsible for spring water contamination at the investigated catchments. In this respect, the SAC254 can also provide useful information to support microbial source tracking efforts where different situations of infiltration have to be investigated. PMID:20962406

  8. Compilation and evaluation of gas phase diffusion coefficients of reactive trace gases in the atmosphere: volume 1. Inorganic compounds

    Science.gov (United States)

    Tang, M. J.; Cox, R. A.; Kalberer, M.

    2014-09-01

    Diffusion of gas molecules to the surface is the first step for all gas-surface reactions. Gas phase diffusion can influence and sometimes even limit the overall rates of these reactions; however, there is no database of the gas phase diffusion coefficients of atmospheric reactive trace gases. Here we compile and evaluate, for the first time, the diffusivities (pressure-independent diffusion coefficients) of atmospheric inorganic reactive trace gases reported in the literature. The measured diffusivities are then compared with estimated values using a semi-empirical method developed by Fuller et al. (1966). The diffusivities estimated using Fuller's method are typically found to be in good agreement with the measured values within ±30%, and therefore Fuller's method can be used to estimate the diffusivities of trace gases for which experimental data are not available. The two experimental methods used in the atmospheric chemistry community to measure the gas phase diffusion coefficients are also discussed. A different version of this compilation/evaluation, which will be updated when new data become available, is uploaded online (google.com/site/mingjintang/home/diffusion"target="_blank">https://sites.google.com/site/mingjintang/home/diffusion).

  9. Pressure--volume--temperature properties of perfluorocyclobutane: equations of state, virial coefficients, and intermolecular potential energy functions

    Energy Technology Data Exchange (ETDEWEB)

    Douslin, D.R.; Moore, R.T.; Waddington, G.

    1959-11-01

    Studies of the pressure-volume-temperature properties of perfluorocyclobutane, in the ranges 3-394 atm and 30-350/sup 0/, yielded values of gas compressibility, critical constants, vapor pressure and orthobaric liquid and vapor densities. The results were correlated by the Beattie Bridgeman, Benedict Webb Rubin, and Martin-Hou equations of state and by the Stockmayer and the Kihara intermolecular potential energy functions. The merits of the several correlational methods are discussed.

  10. Variable volume loading method: a convenient and rapid method for measuring the initial emittable concentration and partition coefficient of formaldehyde and other aldehydes in building materials.

    Science.gov (United States)

    Xiong, Jianyin; Yan, Wei; Zhang, Yinping

    2011-12-01

    The initial emittable formaldehyde and VOC concentration in building materials (C(0)) is a key parameter for characterizing and classifying these materials. Various methods have been developed to measure this parameter, but these generally require a long test time. In this paper we develop a convenient and rapid method, the variable volume loading (VVL) method, to simultaneously measure C(0) and the material/air partition coefficient (K). This method has the following features: (a) it requires a relatively short experimental time (less than 24 h for the cases studied); and (b) is convenient for routine measurement. Using this method, we determined C(0) and K of formaldehyde, propanal and hexanal in one kind of medium density fiberboard, and repeated experiments were performed to reduce measurement error. In addition, an extended-C-history method is proposed to determine the diffusion coefficient and the convective mass transfer coefficient. The VVL method is validated by comparing model predicted results based on the determined parameters with experimental data. The determined C(0) of formaldehyde obtained via this method is less than 10% of the total concentration using the perforator method recommended by the Chinese National Standard, suggesting that the total concentration may not be appropriate to predict emission characteristics, nor for material classification.

  11. Linear and nonlinear optical absorption coefficients in GaAs/Ga{sub 1-x}Al{sub x}As concentric double quantum rings: Effects of hydrostatic pressure and aluminum concentration

    Energy Technology Data Exchange (ETDEWEB)

    Baghramyan, H.M. [Department of Solid State Physics, Yerevan State University, Al. Manookian 1, 0025 Yerevan (Armenia); Barseghyan, M.G., E-mail: mbarsegh@ysu.am [Department of Solid State Physics, Yerevan State University, Al. Manookian 1, 0025 Yerevan (Armenia); Kirakosyan, A.A. [Department of Solid State Physics, Yerevan State University, Al. Manookian 1, 0025 Yerevan (Armenia); Restrepo, R.L. [Escuela de Ingenieria de Antioquia, AA 7516 Medellin (Colombia); Duque, C.A. [Instituto de Fisica, Universidad de Antioquia, AA 1226 Medellin (Colombia)

    2013-02-15

    The linear and nonlinear intra-band optical absorption coefficients in GaAs/Ga{sub 1-x}Al{sub x}As two-dimensional concentric double quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and aluminum concentration the energies of the ground (n=1,l=0) and the first excited state (n=2,l=1) have been found using the effective mass approximation and the transfer matrix formalism. The energies of these states and the corresponding threshold energy of the intra-band optical transitions are examined as a function of hydrostatic pressure and aluminum concentration for different sizes of the structure. We also investigated the dependencies of the linear, nonlinear, and total optical absorption coefficients as functions of the incident photon energy for different values of hydrostatic pressure, aluminum concentration, sizes of the structure, and incident optical intensity. Its is found that the effects of the hydrostatic pressure and the aluminum concentration lead to a shifting of the resonant peaks of the intra-band optical spectrum. - Highlights: Black-Right-Pointing-Pointer Linear and nonlinear intra-band absorption in quantum rings. Black-Right-Pointing-Pointer Threshold energy strongly depends on the hydrostatic pressure. Black-Right-Pointing-Pointer Threshold energy strongly depends on the stoichiometry and sizes of structure. Black-Right-Pointing-Pointer Optical absorption is affected by the incident optical intensity.

  12. Nuclear magnetic resonance (NMR) measurement of the apparent diffusion coefficient (ADC) of tissue water and its relationship to cell volume changes in pathological states.

    Science.gov (United States)

    Sotak, Christopher H

    2004-09-01

    Diffusion-weighted nuclear magnetic resonance (NMR) imaging (DWI) is sensitive to the random translational motion of water molecules due to Brownian motion. Although the mechanism is still not completely understood, the cellular swelling that accompanies cell membrane depolarization results in a reduction in the net displacement of diffusing water molecules and thus a concomitant reduction in the apparent diffusion coefficient (ADC) of tissue water. Cerebral regions of reduced ADC appear hyperintense in a DWI and this technique has been used extensively to study acute stroke. In addition to cerebral ischemia, reductions in the ADC of cerebral water have been observed following cortical spreading depression, ischemic depolarizations (IDs), transient ischemic attack (TIA), status epilepticus, and hypoglycemia. Although the mechanism responsible for initiating membrane depolarization varies in each case, the ensuing cell volume changes follow a similar pattern. Water ADC values are also affected by the presence and orientation of barriers to translational motion (such as cell membranes and myelin fibers) and thus NMR measures of anisotropic diffusion are sensitive to more chronic pathological states where the integrity of these structures is modified by disease. Both theoretical prediction and experimental evidence suggest that the ADC of tissue water is related to the volume fraction of the interstitial space via the electrical conductivity of the tissue. The implication is that acute neurological disorders that exhibit electrical conductivity changes should also exhibit ADC changes that are detectable by DWI. A qualitative correlation between electrical conductivity and the ADC of water has been demonstrated in a number of animal model studies and the results indicate that reduced ADC values are associated with reductions in the extracellular volume fraction and increased extracellular tortuosity. The close relationship between ADC changes and cell volume changes in

  13. Nonlinear Absorption and Refraction in Multilevel Organic Molecular System

    Institute of Scientific and Technical Information of China (English)

    LI Chun-Fei; DENG Xiao-Xu; WANG Yu-Xiao

    2000-01-01

    The nonlinear absorption and refraction in a multilevel organic molecular system is described by using the density matrix theory. The total absorptive coefficient of the system in the low-density case is equal to a linear sum of contributions from each energy level. Similarly, the total refractive index is equal to a linear sum of contributions from each energy level plus the refractive index of the vacuum. The absorption coefficient or refractive index due to each level is proportional to the population of that level, where the constant of proportionality is called the absorption cross-section or the refraction volume, respectively. The relation between the absorption cross-section and the refraction volume for each level is also given.

  14. Absorption of hydrophobic compounds into the poly(dimethylsiloxane) coating of solid-phase microextraction fibers : high partition coefficients and fluorescence microscopy images

    NARCIS (Netherlands)

    Mayer, P.; Vaes, W.H.J.; Hermens, J.L.M.

    2000-01-01

    The use of solid-phase microextraction with poly(dimethylsiloxane) (PDMS)-coated glass fibers for the extraction and analysis of hydrophobic organic analytes is increasing. The literature on this topic is characterized by large discrepancies in partition coefficients and an uncertainty of whether hi

  15. Assessment of treatment response by total tumor volume and global apparent diffusion coefficient using diffusion-weighted MRI in patients with metastatic bone disease: a feasibility study.

    Directory of Open Access Journals (Sweden)

    Matthew D Blackledge

    Full Text Available We describe our semi-automatic segmentation of whole-body diffusion-weighted MRI (WBDWI using a Markov random field (MRF model to derive tumor total diffusion volume (tDV and associated global apparent diffusion coefficient (gADC; and demonstrate the feasibility of using these indices for assessing tumor burden and response to treatment in patients with bone metastases. WBDWI was performed on eleven patients diagnosed with bone metastases from breast and prostate cancers before and after anti-cancer therapies. Semi-automatic segmentation incorporating a MRF model was performed in all patients below the C4 vertebra by an experienced radiologist with over eight years of clinical experience in body DWI. Changes in tDV and gADC distributions were compared with overall response determined by all imaging, tumor markers and clinical findings at serial follow up. The segmentation technique was possible in all patients although erroneous volumes of interest were generated in one patient because of poor fat suppression in the pelvis, requiring manual correction. Responding patients showed a larger increase in gADC (median change = +0.18, range = -0.07 to +0.78 × 10(-3 mm2/s after treatment compared to non-responding patients (median change = -0.02, range = -0.10 to +0.05 × 10(-3 mm2/s, p = 0.05, Mann-Whitney test, whereas non-responding patients showed a significantly larger increase in tDV (median change = +26%, range = +3 to +284% compared to responding patients (median change = -50%, range = -85 to +27%, p = 0.02, Mann-Whitney test. Semi-automatic segmentation of WBDWI is feasible for metastatic bone disease in this pilot cohort of 11 patients, and could be used to quantify tumor total diffusion volume and median global ADC for assessing response to treatment.

  16. Donor impurity-related linear and nonlinear optical absorption coefficients in GaAs/Ga{sub 1−x}Al{sub x}As concentric double quantum rings: Effects of geometry, hydrostatic pressure, and aluminum concentration

    Energy Technology Data Exchange (ETDEWEB)

    Baghramyan, H.M.; Barseghyan, M.G.; Kirakosyan, A.A. [Department of Solid State Physics, Yerevan State University, Al. Manookian 1, 0025 Yerevan (Armenia); Restrepo, R.L. [Física Teórica y Aplicada, Escuela de Ingeniería de Antioquia, AA 7516, Medellín (Colombia); Grupo de Materia Condensada-UdeA, Instituto de Física, Facultadde Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21,Medellín (Colombia); Mora-Ramos, M.E. [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultadde Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21,Medellín (Colombia); Facultad de Ciencias, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, CP 62209, Cuernavaca, Morelos (Mexico); Duque, C.A., E-mail: cduque@fisica.udea.edu.co [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultadde Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21,Medellín (Colombia)

    2014-01-15

    The linear and nonlinear optical absorption associated with the transition between 1s and 2s states corresponding to the electron-donor-impurity complex in GaAs/Ga{sub 1−x}Al{sub x}As three-dimensional concentric double quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and the variation of the aluminum concentration, the energies of the ground and first excited s-like states of a donor impurity in such a system have been calculated using the effective mass approximation and a variational method. The energies of these states and the corresponding threshold energy of the optical transitions are examined as functions of hydrostatic pressure, aluminum concentration, radial impurity position, as well as the geometrical dimensions of the structure. The dependencies of the linear, nonlinear and total optical absorption coefficients as functions of the incident photon energy are investigated for different values of those mentioned parameters. It is found that the influences mentioned above lead to either redshifts or blueshifts of the resonant peaks of the optical absorption spectrum. It is particularly discussed the unusual property exhibited by the third-order nonlinear of becoming positive for photon energies below the resonant transition one. It is shown that this phenomenon is associated with the particular features of the system under study, which determine the values of the electric dipole moment matrix elements. -- Highlights: • Intra-band optical absorption associated to impurity states in double quantum rings. • Combined effects of hydrostatic pressure and aluminum concentration are studied. • The influences mentioned above lead to shifts of resonant peaks. • It is discussed an unusual property exhibited by the third-order nonlinear absorption.

  17. Modelling the light absorption properties of particulate matter forming organic particles suspended in seawater.Part 1. Model description, classification of organic particles, and example spectra of the light absorption coefficient and the imaginary part of the refractive index of particulate matter for phytoplankton cells and phytoplankton-like particles

    Directory of Open Access Journals (Sweden)

    Bogdan Woźniak

    2005-06-01

    Full Text Available Data on organic substances in the sea are applied to distinguish hypothetical chemical classes and physical types of suspended particulate organic matter (POM in seawater. Spectra of the light absorption coefficients of particulate matter apm(λ and the imaginary refractive index n'p(λ, are assessed for some of these classes and types of POM in seawater, that is, for live phytoplankton cells and phytoplankton-like particles. The spectral characteristics of these coefficients are established and the probable ranges of variability of their absolute magnitudes defined on the basis of the mass-specific coefficients of light absorption by the various organic substances forming the particles. Also presented are mathematical relationships linking the coefficients apm(λ and n'p(λ for the various chemical classes of POM with their physical parameters, such as the relative contents of organic matter, water, air or some other gas. This article is part of a bio-optical study undertaken by the authors, the objective of which is to implement remote sensing techniques in the investigation of Baltic ecosystems (Woźniak et al. 2004.

  18. True progression versus pseudoprogression in the treatment of glioblastomas: A comparison study of normalized cerebral blood volume and apparent diffusion coefficient by histogram analysis

    Energy Technology Data Exchange (ETDEWEB)

    Song, Yong Sub; Choi, Seung Hong; Park, Chul Kee [Seoul National University College of Medicine, Seoul (Korea, Republic of); and others

    2013-08-15

    The purpose of this study was to differentiate true progression from pseudoprogression of glioblastomas treated with concurrent chemoradiotherapy (CCRT) with temozolomide (TMZ) by using histogram analysis of apparent diffusion coefficient (ADC) and normalized cerebral blood volume (nCBV) maps. Twenty patients with histopathologically proven glioblastoma who had received CCRT with TMZ underwent perfusion-weighted imaging and diffusion-weighted imaging (b = 0, 1000 sec/mm{sup 2}). The corresponding nCBV and ADC maps for the newly visible, entirely enhancing lesions were calculated after the completion of CCRT with TMZ. Two observers independently measured the histogram parameters of the nCBV and ADC maps. The histogram parameters between the true progression group (n = 10) and the pseudoprogression group (n = 10) were compared by use of an unpaired Student's t test and subsequent multivariable stepwise logistic regression analysis to determine the best predictors for the differential diagnosis between the two groups. Receiver operating characteristic analysis was employed to determine the best cutoff values for the histogram parameters that proved to be significant predictors for differentiating true progression from pseudoprogression. Intraclass correlation coefficient was used to determine the level of inter-observer reliability for the histogram parameters. The 5th percentile value (C5) of the cumulative ADC histograms was a significant predictor for the differential diagnosis between true progression and pseudoprogression (p 0.044 for observer 1; p = 0.011 for observer 2). Optimal cutoff values of 892 x 10{sup -6} mm{sup 2}/sec for observer 1 and 907 x 10{sup -6} mm{sup 2}/sec for observer 2 could help differentiate between the two groups with a sensitivity of 90% and 80%, respectively, a specificity of 90% and 80%, respectively, and an area under the curve of 0.880 and 0.840, respectively. There was no other significant differentiating parameter on the n

  19. 镍合金对γ射线吸收系数的测量与分析%Gamma Ray Absorption Coefficient of Measurement and Analysis on Nickel Alloy

    Institute of Scientific and Technical Information of China (English)

    郑贤利; 王俊霖; 赵焱; 熊绮丽; 汪资深; 杨君

    2013-01-01

    采用BH1324多道及BH1220智能定标器等设备测量了2种型号的镍合金和铅对不同能量γ射线的吸收系数.实验结果表明,镍合金对γ射线的质量吸收系数随能量的增加减少较缓慢,在能量较高的区域质量吸收系数与铅的相近,因此可用镍合金作为γ射线的屏蔽材料.%The absorption coefficients of different energy gamma - ray on the two types of nickel alloy and lead are measured by BH1324 and BH1220 devices. The experimental results show that the mass - absorption coefficient of nickel alloy decreases slowly with the increase of gamma - ray energy, and the values are close to these of lead in the higher energy region. So nickel alloys are suitable to replace lead as the shielding materials for gamma rays.

  20. Halo Gas and Galaxy Disk Kinematics of a Volume-Limited Sample of MgII Absorption-Selected Galaxies at z~0.1

    CERN Document Server

    Kacprzak, G G; Barton, E J; Cooke, J

    2011-01-01

    We have directly compared MgII halo gas kinematics to the rotation velocities derived from emission/absorption lines of the associated host galaxies. Our 0.096volume-limited sample comprises 13 ~L* galaxies, with impact parameters of 12-90 kpc from background quasars sight-lines, associated with 11 MgII absorption systems with MgII equivalent widths 0.3< W_r(2796)<2.3A. For only 5/13 galaxies, the absorption resides to one side of the galaxy systemic velocity and trends to align with one side of the galaxy rotation curve. The remainder have absorption that spans both sides of the galaxy systemic velocity. These results differ from those at z~0.5, where 74% of the galaxies have absorption residing to one side of the galaxy systemic velocity. For all the z~0.1 systems, simple extended disk-like rotation models fail to reproduce the full MgII velocity spread, implying other dynamical processes contribute to the MgII kinematics. In fact 55% of the galaxies are "counter-rotating" with respect ...

  1. Intensities and self-broadening coefficients of the strongest water vapour lines in the 2.7 and 6.25 μm absorption bands

    Science.gov (United States)

    Ptashnik, Igor V.; McPheat, Robert; Polyansky, Oleg L.; Shine, Keith P.; Smith, Kevin M.

    2016-07-01

    Intensities and self-broadening coefficients are presented for about 460 of the strongest water vapour lines in the spectral regions 1400-1840 cm-1 and 3440-3970 cm-1 at room temperature, obtained from rather unique measurements using a 5-mm-path-length cell. The retrieved spectral line parameters are compared with those in the HITRAN database ver. 2008 and 2012 and with recent ab-initio calculations. Both the retrieved intensities and half-widths are on average in reasonable agreement with those in HITRAN-2012. Maximum systematic differences do not exceed 4% for intensities (1600 cm-1 band) and 7% for self-broadening coefficients (3600 cm-1 band). For many lines however significant disagreements were detected with the HITRAN-2012 data, exceeding the average uncertainty of the retrieval. In addition, water vapour line parameters for 5300 cm-1 (1.9 μm) band reported by us in 2005 were also compared with HITRAN-2012, and show average differences of 4-5% for both intensities and half-widths.

  2. EXTENSION OF THE INVERSE ADDING-DOUBLING METHOD TO THE MEASUREMENT OF WAVELENGTH-DEPENDENT ABSORPTION AND SCATTERING COEFFICIENTS OF BIOLOGICAL SAMPLES

    Energy Technology Data Exchange (ETDEWEB)

    Allegood, M.S.; Baba, J.S.

    2008-01-01

    Light interaction with biological tissue can be described using three parameters: the scattering and absorption coeffi cients (μs and μa), as well as the anisotropy (g) which describes the directional dependence of the scattered photons. Accurately determining these optical properties for different tissue types at specifi c wavelengths simultaneously would be benefi cial for a variety of different biomedical applications. The goal of this project was to take a user defi ned g-value and determine the remaining two parameters for a specifi ed wavelength range. A fully automated computer program and process was developed to collect data for all wavelengths in a timely and accurate manner. LabVIEW® was used to write programs to automate raw intensity data collection from a spectrometer equipped integrating sphere, conversion of the data into a format for analysis via Scott Prahl’s Inverse Adding-Doubling (IAD) C code execution, and fi nally computation of the optical properties based on the output from the IAD code. To allow data to be passed effi ciently between LabVIEW® and C code program modules, the two were combined into a single program (OPT 3.1). OPT 3.1 was tested using tissue mimicking phantoms. Determination of the absorption and scattering coeffi cients showed excellent agreement with theory for wavelengths where the user inputted single g-value was suffi ciently precise. Future improvements entail providing for multi-wavelength g-value entry to extend the accuracy of results to encompass the complete multispectral range. Ultimately, the data collection process and algorithms developed through this effort will be used to examine actual biological tissues for the purpose of building and refi ning models for light-tissue interactions.

  3. Evaluation of the use of partition coefficients and molecular surface properties as predictors of drug absorption: a provisional biopharmaceutical classification of the list of national essential medi

    Directory of Open Access Journals (Sweden)

    NU Rahman

    2011-05-01

    Full Text Available Background and the purpose of the study: Partition coefficients (log D and log P and molecular surface area (PSA are potential predictors of the intestinal permeability of drugs. The aim of this investigation was to evaluate and compare these intestinal permeability indicators.   Methods: Aqueous solubility data were obtained from literature or calculated using ACD/Labs and ALOGPS. Permeability data were predicted based on log P, log D at pH 6.0 (log D6.0, and PSA.  Results: Metoprolol's log P, log D6.0 and a PSA of <65 Å correctly predicted 55.9%, 50.8% and 54.2% of permeability classes, respectively. Labetalol's log P, log D6.0, and PSA correctly predicted 54.2%, 64.4% and 61% of permeability classes, respectively. Log D6.0 correlated well (81% with Caco-2 permeability (Papp. Of the list of national essential medicines, 135 orally administered drugs were classified into biopharmaceutical classification system (BCS. Of these, 57 (42.2%, 28 (20.7%, 44 (32.6%, and 6 (4.4% were class I, II, III and IV respectively. Conclusion: Log D6.0 showed better prediction capability than log P. Metoprolol as permeability internal standard was more conservative than labetalol.

  4. Evaluation of time-resolved multi-distance methods to retrieve absorption and reduced scattering coefficients of adult heads in vivo: Optical parameters dependences on geometrical structures of the models used to calculate reflectance

    Science.gov (United States)

    Tanifuji, T.

    2016-03-01

    Time-resolved multi-distance measurements are studied to retrieve absorption and reduced scattering coefficients of adult heads, which have enough depth sensitivity to determine the optical parameters in superficial tissues and brain separately. Measurements were performed by putting the injection and collection fibers on the left semi-sphere of the forehead, with the injection fiber placed toward the temporal region, and by moving the collection fiber between 10 and 60 mm from the central sulcus. It became clear that optical parameters of the forehead at all collection fibers were reasonably determined by selecting the appropriate visibility length of the geometrical head models, which is related to head surface curvature at each position.

  5. 基于声压—质点速度声强探头的材料吸声系数的测量%Measurements of the absorption coefficients with a combined particle velocity-pressure sound intensity probe

    Institute of Scientific and Technical Information of China (English)

    李凌志; 程攻; 刘英杰; 卢炳武

    2012-01-01

    通过由一个声压换能器和一个质点速度换能器所构成的传感器(p-u声强探头)同时测量材料表面附近的声压和质点振动速度,可直接得到其声学阻抗,进而得到材料的反射因子、吸声系数.本文利用一个p-u探头声强测量系统,在半消声室内测量了三聚氰胺泡沫的吸声系数,分析了声源高度和入射角度、材料样本尺寸和厚度对吸声系数测量的影响,并和阻抗管中测量得到的法向吸声系数进行了对比.最后分析了声阻抗率的幅值和相位误差对吸声系数的影响,推导了它们的误差传递公式.%Using a combined particle velocity-pressure sensor (p-u sound intensity probe), the acoustic impedance of an absorbing materials, and consequently its reflection factor and absorption coefficient, can be determined by simultaneous measurements of sound pressure and particle velocity at a position near the surface of the materials. Using a p-u intensity probe system in a semi-anechoic room, we measured the acoustic impedance of melamine, and analyzed how the source height, incidence angle, the size and thickness of the materials sample affect the measurement, and compared to the normal impedance measured using a standing wave tube. We also analyzed how the amplitude and phase error of the acoustic impedance affect the absorption coefficient, and derived an error propagation formula.

  6. 超临界CO_2密度对全反式番茄红素吸光系数的影响%Effect of Supercritical Carbon Dioxide Density on Absorption Coefficient of All-trans Lycopene

    Institute of Scientific and Technical Information of China (English)

    何强强; 惠伯棣; 宫平

    2012-01-01

    Objective: To assess the effect of varying carbon dioxide density on absorption coefficient(A1cm) of all-trans lycopene through exploring the correlation between carbon dioxide density in supercritical fluid chromatography(SFC) and peak areas of all-trans lycopene fractions.Methods: Supercritical CO2fluid chromatography was carried out on a Diamonsil C8(250mm × 4.6 mm,5 μm,) at a pressure ranging from 11.5 to 17.5 MPa,and a temperature ranging from 35—55 ℃.The detection wavelength was 453 nm,and 20 μL sample was injected for SFC chromatography.Results: Peak area of all-trans lycopene at the maximum absorption wavelength in supercritical carbon dioxide fluid chromatography revealed a variation and was linearly positive correlated with the density of carbon dioxide.Conclusion: Absorption coefficient of all-trans lycopene is positively correlated with the density of supercritical carbon dioxide.%目的:通过在超临界CO2色谱上测定CO2流动相密度与全反式番茄红素组分峰面积的相关性,推算二氧化碳密度变化对全反式番茄红素的吸光系数(A1cm)的影响。方法:超临界色谱条件:色谱柱:Diamonsil C8(250mm×4.6m m,5μm);检测波长:4 5 3 n m;压力变化范围:1 1.5~1 7.5 M P a;温度变化范围:3 5~5 5℃;流速:2mL/min;进样量:20μL。结果:全反式番茄红素组分在超临界CO2中最大吸收波长处的峰面积是可变的,与CO2密度呈线性正相关。结论:可推断全反式番茄红素吸光系数与超临界CO2流体密度变化呈正相关。

  7. On-line micro-volume introduction system developed for lower density than water extraction solvent and dispersive liquid-liquid microextraction coupled with flame atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Anthemidis, Aristidis N., E-mail: anthemid@chem.auth.gr [Laboratory of Analytical Chemistry, Department of Chemistry, Aristotle University, Thessaloniki 54124 (Greece); Mitani, Constantina; Balkatzopoulou, Paschalia; Tzanavaras, Paraskevas D. [Laboratory of Analytical Chemistry, Department of Chemistry, Aristotle University, Thessaloniki 54124 (Greece)

    2012-07-06

    Highlights: Black-Right-Pointing-Pointer A dispersive liquid-liquid micro extraction method for lead and copper determination. Black-Right-Pointing-Pointer A micro-volume transportation system for extractant solvent lighter than water. Black-Right-Pointing-Pointer Analysis of natural water samples. - Abstract: A simple and fast preconcentration/separation dispersive liquid-liquid micro extraction (DLLME) method for metal determination based on the use of extraction solvent with lower density than water has been developed. For this purpose a novel micro-volume introduction system was developed enabling the on-line injection of the organic solvent into flame atomic absorption spectrometry (FAAS). The effectiveness and efficiency of the proposed system were demonstrated for lead and copper preconcentration in environmental water samples using di-isobutyl ketone (DBIK) as extraction solvent. Under the optimum conditions the enhancement factor for lead and copper was 187 and 310 respectively. For a sample volume of 10 mL, the detection limit (3 s) and the relative standard deviation were 1.2 {mu}g L{sup -1} and 3.3% for lead and 0.12 {mu}g L{sup -1} and 2.9% for copper respectively. The developed method was evaluated by analyzing certified reference material and it was applied successfully to the analysis of environmental water samples.

  8. Perdas endógenas e coeficientes de absorção aparente e real do magnésio em caprinos Endogenous losses and coefficients of apparent and true absorption of magnesium in goats

    Directory of Open Access Journals (Sweden)

    Claudete Regina Alcalde

    1999-01-01

    (AN and Saanen (SN goat breeds. Twelve kids, six of each breed, with average 19.8 kg LW, were used. Semipurified diets (low Mg content based on cracked rice, corn gluten meal and cellulose were supplemented with MgO to obtain the levels of .05 (without supplementation, .20 and .35% of Mg (% DM. The levels of Mg affected the coefficient of apparent absorption of Mg and Ca, with average values of 57.8, 73.9, and 73.2% for Mg and 55.7, 39.6 and 49.5% for Ca for diets with .05, .20, and .35% Mg, respectively. However, there was no effect of the dietary Mg level on the coefficient of apparent absorption of P, Na and K. An interaction between Mg level and breeds was observed for the real absorption of Mg. The mean for AN breed, on the level .05% Mg was 61.0% and for the levels 0.20 and 0.35% Mg, 77.2 and 73.2%, respectively. However, for SN breed the means were 73.3, 75.5 and 76.0%, for the same levels, without differences. The digestibility of dry matter, crude protein, and nitrogen free extract decreased with the crescent dietary Mg level. The fecal (7.0, 20.8 and 34.4 mg/kg LW0.75.d and urinary (3.9, 30.8 and 44.6 mg/kg LW0.75.d Mg excretion increased with the crescent dietary Mg level. There was also influence of the dietary Mg level on the blood serum Mg concentration (1.74, 2.23 and 2.80 mg/dL for .05, .20, and .35% Mg, respectively.

  9. Sound absorption property of openpore aluminum foams

    Directory of Open Access Journals (Sweden)

    WANG Fang

    2007-02-01

    Full Text Available This paper presents a study on sound absorption property of aluminum foam by evaluating its sound absorption coefficients using standing wave tube method. Experimental results showed that the average values of sound absorption coefficients (over the test frequency range are all above 0.4, which indicate very good sound absorption property of the aluminum foams. The sound absorption coefficient is affected by frequency and pore structure, and reaches its maximum value at around 1 000 Hz. With the increase of porosity and decrease of cell diameter, the sound absorption coefficient values increase.

  10. Acoustic Absorption Characteristics of People.

    Science.gov (United States)

    Kingsbury, H. F.; Wallace, W. J.

    1968-01-01

    The acoustic absorption characteristics of informally dressed college students in typical classroom seating are shown to differ substantially from data for formally dressed audiences in upholstered seating. Absorption data, expressed as sabins per person or absorption coefficient per square foot, shows that there is considerable variation between…

  11. Analysise of Surface Character of Porous Building Materials on Water Absorption Coefficient%多孔介质材料表面孔隙特性对吸水性能影响分析研究

    Institute of Scientific and Technical Information of China (English)

    于水; 张旭; Mark Bomberg

    2012-01-01

    absorption coefficient.

  12. Absorption and scattering coefficients estimation in two-dimensional participating media using the generalized maximum entropy and Levenberg-Marquardt methods; Estimacion del coeficiente de absorcion y dispersion en medios participantes bidimensionales utilizando el metodo de maxima entropia generalizada y el metodo Levenberg-Marquardt

    Energy Technology Data Exchange (ETDEWEB)

    Berrocal T, Mariella J. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Programa de Engenharia Nuclear]|[Universidad Nacional de Ingenieria, Lima (Peru); Roberty, Nilson C. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Programa de Engenharia Nuclear; Silva Neto, Antonio J. [Universidade do Estado, Nova Friburgo, RJ (Brazil). Instituto Politecnico. Dept. de Engenharia Mecanica e Energia]|[Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Programa de Engenharia Nuclear

    2002-07-01

    The solution of inverse problems in participating media where there is emission, absorption and dispersion of the radiation possesses several applications in engineering and medicine. The objective of this work is to estimative the coefficients of absorption and dispersion in two-dimensional heterogeneous participating media, using in independent form the Generalized Maximum Entropy and Levenberg Marquardt methods. Both methods are based on the solution of the direct problem that is modeled by the Boltzmann equation in cartesian geometry. Some cases testes are presented. (author)

  13. Change of absorption coefficient of biological tissues in laser induced interstitial thermotherapy%激光诱导间质热疗中生物组织吸收系数变化特性研究

    Institute of Scientific and Technical Information of China (English)

    王晋阳; 钱志余; 钱爱平; 吕操君; 王栋; 花国然

    2011-01-01

    The feasibility of real-time monitoring in laser induced interstitial thermotherapy (LITT) of biological tissues using near infrared spectrum technique is explored and validated. In vitro liver and rats with subcutantaneous implanted tumor models were chosen as experiment objects. Changes of absorption coefficient (μa) of tissue are real-time measured by near infrared spectrum system in laser induced interstitial thermotherapy. The result indicates that μa has some variations during LITT. The change law ofμa in vitro livers experiments is significant. It slowly goes up under low power, and rises greatly based on high power when biological tissues reach certain temperature(around 50℃). The change laws of μa during tumor experiments is different according to characteristics of tumor tissue which can be used for future clinical treatment. Experimental results show thatμa has valuable reference as a real-time monitoring factor in LITT of entity organizations, but it also needs further study as evaluating factor of the tumor treatment appraisal.%利用近红外光谱技术进行生物组织激光诱导间质热疗(Laser induced interstitial thermotherapy,LITT)实时监测,探讨LITT术中疗效评估基础.实验样本采用离体猪肝和小鼠皮下移植肝肿瘤,使用近红外光谱实时采集系统采集激光热疗过程中组织吸收系数(μa).实验结果表明,μa在激光热疗过程中具有一定的变化规律,其中猪肝的变化规律非常明显,在低功率下呈现缓慢的上升,高功率下达到一定的温度(50℃左右)快速上升,并逐步达到稳定.肿瘤在热毁损时会根据瘤体的组织特性不同出现特异性变化,这些变化可以作为将来临床治疗的参考.实验结果表明在进行实体组织激光诱导间质热疗过程中,μa作为实时监测因子具有一定的参考价值,而作为肿瘤的治疗评估因子还需要进一步探索.

  14. Emission characteristics and electron kinetic coefficients of the plasma of a transverse volume discharge initiated in a mixture of heavy inert gases with chlorine molecules

    Science.gov (United States)

    Shuaibov, A. K.; Chygin, V. I.; Shimon, L. L.; Shevera, I. V.; Gorun, P. P.; Obukhovskii, R. O.

    2010-05-01

    The results of studying the radiation due to argon, krypton, and xenon monochloride bands, as well as to the bands of chlorine molecules, from the plasma of a transverse Ar-Kr-Xe-Cl2 volume discharge are reported. The working mixture of a pulse radiation source is optimized with regard to its pressure and elemental composition and parameters of an excitation system. By numerically solving the Boltzmann kinetic equation for the electron energy distribution function, the transport characteristics of plasma electrons and discharge power specific losses are found for different values of the reduced electric field strength. The plasma parameters are simulated for the quaternary mixture, which is most appropriate for a multiwave UV-VUV source. Qualitative analysis is conducted for the most important electron processes in the multicomponent plasma that govern the joint formation of argon, krypton, and xenon monochlorides in the transverse discharge.

  15. A drying coefficient for building materials

    DEFF Research Database (Denmark)

    Scheffler, Gregor Albrecht; Plagge, Rudolf

    2009-01-01

    The drying experiment is an important element of the hygrothermal characterisation of building materials. Contrary to other moisture transport experiments as the vapour diffusion and the water absorption test, it is until now not possible to derive a simple coefficient for the drying. However...... coefficient is defined which can be determined based on measured drying data. The correlation of this coefficient with the water absorption and the vapour diffusion coefficient is analyzed and its additional information content is critically challenged. As result, a drying coefficient has been derived...... and defined as a new and independent material parameter. It contains information about the moisture transport properties throughout the wide range of moisture contents from hygroscopic up to saturation. With this new and valuable coefficient, it is now possible to distinguish and select building materials...

  16. Effective Viscosity Coefficient of Nanosuspensions

    Science.gov (United States)

    Rudyak, V. Ya.; Belkin, A. A.; Egorov, V. V.

    2008-12-01

    Systematic calculations of the effective viscosity coefficient of nanosuspensions have been performed using the molecular dynamics method. It is established that the viscosity of a nanosuspension depends not only on the volume concentration of the nanoparticles but also on their mass and diameter. Differences from Einstein's relation are found even for nanosuspensions with a low particle concentration.

  17. Resonant Optical Absorption in Semiconductor Quantum Wells

    Institute of Scientific and Technical Information of China (English)

    YU Li-Yuan; CAO Jun-Cheng

    2004-01-01

    @@ We have calculated the intraband photon absorption coefficients of hot two-dimensional electrons interacting with polar-optical phonon modes in quantum wells. The dependence of the photon absorption coefficients on the photon wavelength λ is obtained both by using the quantum mechanical theory and by the balance-equation theory. It is found that the photon absorption spectrum displays a local resonant maximum, corresponding to LO energy, and the absorption peak vanishes with increasing the electronic temperature.

  18. Prediction of Molar Extinction Coefficients of Proteins and Peptides Using UV Absorption of the Constituent Amino Acids at 214 nm To Enable Quantitative Reverse Phase High-Performance Liquid Chromatography-Mass Spectrometry Analysis

    NARCIS (Netherlands)

    Kuipers, B.J.H.; Gruppen, H.

    2007-01-01

    The molar extinction coefficients of 20 amino acids and the peptide bond were measured at 214 nm in the presence of acetonitrile and formic acid to enable quantitative comparison of peptides eluting from reversed-phase high-performance liquid chromatography, once identified with mass spectrometry (R

  19. Prediction of Molar Extinction Coefficients of Proteins and Peptides Using UV Absorption of the Constituent Amino Acids at 214 nm To Enable Quantitative Reverse Phase High-Performance Liquid Chromatography-Mass Spectrometry Analysis

    NARCIS (Netherlands)

    Kuipers, B.J.H.; Gruppen, H.

    2007-01-01

    The molar extinction coefficients of 20 amino acids and the peptide bond were measured at 214 nm in the presence of acetonitrile and formic acid to enable quantitative comparison of peptides eluting from reversed-phase high-performance liquid chromatography, once identified with mass spectrometry

  20. Prediction of Molar Extinction Coefficients of Proteins and Peptides Using UV Absorption of the Constituent Amino Acids at 214 nm To Enable Quantitative Reverse Phase High-Performance Liquid Chromatography-Mass Spectrometry Analysis

    NARCIS (Netherlands)

    Kuipers, B.J.H.; Gruppen, H.

    2007-01-01

    The molar extinction coefficients of 20 amino acids and the peptide bond were measured at 214 nm in the presence of acetonitrile and formic acid to enable quantitative comparison of peptides eluting from reversed-phase high-performance liquid chromatography, once identified with mass spectrometry (R

  1. Sound absorption property of open-pore aluminum foams

    Institute of Scientific and Technical Information of China (English)

    WANG Fang; WANG Lu-cai; WU Jian-guo; YOU Xiao-hong

    2007-01-01

    This paper presents a study on sound absorption property of aluminum foam by evaluating its sound absorption coefficients using standing wave tube method. Experimental results showed that the average values of sound absorption coefficients (over the test frequency range) are all above 0.4, which indicate very good sound absorption property of the aluminum foams. The sound absorption coefficient is affected by frequency and pore structure, and reaches its maximum value at around 1 000 Hz. With the increase of porosity and decrease of cell diameter, the sound absorption coefficient values increase.

  2. 鸦胆子油油水分配系数及其乳剂大鼠在体肠吸收特性研究%O/W partition coefficient of brucea javanica oil and absorption characteristics of its emulsion in rat intestine in situ

    Institute of Scientific and Technical Information of China (English)

    陈钢; 张晓; 卢刚; 刘广泉; 曾洁; 李晔; 魏少阳

    2012-01-01

    目的:测定鸦胆子油的油水分配系数,并考察鸦胆子油乳在大鼠的肠吸收性质及机制.方法:采用经典摇瓶法测定鸦胆子油的油水分配系数(P);采用在体单向肠灌流法模型研究不同浓度鸦胆子油乳在大鼠的十二指肠、空肠、回肠及结肠的吸收情况,并测定其吸收速率常数(Ka)、吸收率(Fa)和表观渗透系数(Papp).结果:鸦胆子油疏水常数logP的平均值为1.193.鸦胆子油乳在小肠(十二指肠、空肠、回肠)吸收较好,在结肠吸收较少且不规则.其Ka、Fa和Papp按十二指肠、空肠、回肠依次下降且差异显著(P<0.05),不同浓度在同一肠段随着浓度增加,吸收也随之增加,高浓度与低浓度相比,Fa和Papp差异显著(P<0.05),Ka没有显著性差异.结论:鸦胆子油透过生物膜的能力较强.鸦胆子油乳在十二指肠吸收最佳,在小肠内的吸收为一级动力学过程,并无自身浓度抑制作用,可能主要为被动转运机制.%Objective: To determine the O/W partition coefficient of brucea javanica oil and investigate the absorption characteristics and mechanism of its emulsion in rat intestine. Methods: The shake-flask method was employed to determine the O/W partition coefficient ( P) of brucea javanica oil. The absorptions of six concentrations of brucea javanica oil emulsion in different intestinal segments were studied by in situ rats single pass perfusion model, and the absorption rate constant (Ka), absorption rate (Fa) and apparent permeability coefficients (Papp) were determined. Results: The logP of brucea javanica oil was 1.193. Brucea javanica oil emulsion was absorbed at all intestinal segments. However, the absorption of small intestine was better than that of colon. The Ka, Fa and Papp of various intestinal segments decreased in rums in duodenum, jejunum and ileum (P< 0.05). Drug concentration had little significant effect on the Ka in the same intestinal segment. The uptake of the drug

  3. 海生红藻R-藻红蛋白和隐藻藻蓝蛋白光吸收系数测定%Absorption Coefficient Determination of R-Phycoerythrins and a Cryptomonad Phycocyanin from Marine Red Algae and Cryptomonad

    Institute of Scientific and Technical Information of China (English)

    魏星; 赵明日; 付学军; 华萌萌; 龚雪琴; 孙力

    2012-01-01

    选用Bradford法和Lowry法,以牛血清蛋白和γ-球蛋白作为标准蛋白,分别对从海生红藻异管藻(Heterosiphonia japonica)和多管藻(Polysiphonia urceolata)以及蓝隐藻(Chroomonas placoidea)中分离纯化的异管藻R-藻红蛋白(HR - PE)、多管藻R-藻红蛋白(PR- PE)、蓝隐藻藻蓝蛋白(Cr - PC)进行了蛋白浓度及其特征吸收峰的光吸收系数测定.根据2种方法和2种蛋白针对3种藻胆蛋白的测定结果以及影响结果的主要因素进行了细致地分析和比较,Lowry法是进行藻胆蛋白,尤其是六聚体藻红蛋白浓度及光吸收系数测定的更适合、准确的检测方法;在进行同类或相同藻胆蛋白之间相对含量、比例的定量分析时,Bradford法是一种更便捷的测定方法.由于藻胆蛋白光吸收系数值与选用的蛋白定量检测方法及其所用的标准蛋白直接相关,在使用和比较藻胆蛋白光吸收系数值时必须明确检测方法和标准蛋白,否则藻胆蛋白光吸收系数值将不具有可比性.%Two R-phycoerythrins, HR-PE and PR-PE, are isolated and purified from marine red alga Heterosipho-nia japonica and Polysiphonia urceolata, respectively. And cryptomonad phycocyanin is prepared from marine cryptomonad Chroomonas placoidea. The protein concentration and light absorption coefficients of specific absorption maxima are determined using Bradford and Lowry methods with bovine serum albumin and γ-globulin are employed as standard proteins. Based on the comparison of the above mentioned methods and their influencing factors show that Lowry method is a more suitable and accurate method for absorption coefficient determination of phycobilipro-teins, especially for hexameric phycoerythrins. For quantifing and comparising of the relative contents and the ratios of analogous or the same phycobiliproteins, Bradford method is more convenient one. Therefore, when absorption coefficient is to be used and to be compared with each other

  4. Practical absorption limits of MPP absorber

    Institute of Scientific and Technical Information of China (English)

    MAA Dah-You

    2006-01-01

    The construction and properties of microperforated panel (MPP) absorber are discussed. The absorption limit of the absorber had been shown that low values of the perforate constant k = d(f/10)1/2 and the orifice diameter d (in mm) are essential for MPP to have high absorption in wide frequency band. To find the exact limits, take 1 for k as a start, because both specific resistance and high absorption require k around one. And the orifice diameter d is chosen as 0.1 mm, so that the peak absorption coefficient (resonance absorption) is at 1000 Hz,and high sound frequency may be in the absorption region. Is it possible for a single layer of such an MPP to cover the whole absorption region required in practice? The half-absorption limit is not a good criterion, because low absorption comes in also in some cases. The 0.5 absorption coefficient limit is suggested for practical region, as a standard for comparison. Absorption curves were drawn for different load resistances, of absorption coefficients versus frequency.Ordinary MPP absorber absorbs in slightly over two octaves, and the new absorber with r = 1 (specific resistance equal to the characteristic impedance in air)is slightly better than these, 2.5 octaves. The new absorbers with r > 1, are much better than these, and some satisfies high absorption in broad frequency range. Realization of these will mean great progress of MPP absorbers.

  5. Nanofluid optical property characterization: towards efficient direct absorption solar collectors.

    Science.gov (United States)

    Taylor, Robert A; Phelan, Patrick E; Otanicar, Todd P; Adrian, Ronald; Prasher, Ravi

    2011-03-15

    Suspensions of nanoparticles (i.e., particles with diameters nanofluids, show remarkable thermal and optical property changes from the base liquid at low particle loadings. Recent studies also indicate that selected nanofluids may improve the efficiency of direct absorption solar thermal collectors. To determine the effectiveness of nanofluids in solar applications, their ability to convert light energy to thermal energy must be known. That is, their absorption of the solar spectrum must be established. Accordingly, this study compares model predictions to spectroscopic measurements of extinction coefficients over wavelengths that are important for solar energy (0.25 to 2.5 μm). A simple addition of the base fluid and nanoparticle extinction coefficients is applied as an approximation of the effective nanofluid extinction coefficient. Comparisons with measured extinction coefficients reveal that the approximation works well with water-based nanofluids containing graphite nanoparticles but less well with metallic nanoparticles and/or oil-based fluids. For the materials used in this study, over 95% of incoming sunlight can be absorbed (in a nanofluid thickness ≥10 cm) with extremely low nanoparticle volume fractions - less than 1 × 10-5, or 10 parts per million. Thus, nanofluids could be used to absorb sunlight with a negligible amount of viscosity and/or density (read: pumping power) increase.

  6. Nanofluid optical property characterization: towards efficient direct absorption solar collectors

    Directory of Open Access Journals (Sweden)

    Otanicar Todd

    2011-01-01

    Full Text Available Abstract Suspensions of nanoparticles (i.e., particles with diameters < 100 nm in liquids, termed nanofluids, show remarkable thermal and optical property changes from the base liquid at low particle loadings. Recent studies also indicate that selected nanofluids may improve the efficiency of direct absorption solar thermal collectors. To determine the effectiveness of nanofluids in solar applications, their ability to convert light energy to thermal energy must be known. That is, their absorption of the solar spectrum must be established. Accordingly, this study compares model predictions to spectroscopic measurements of extinction coefficients over wavelengths that are important for solar energy (0.25 to 2.5 μm. A simple addition of the base fluid and nanoparticle extinction coefficients is applied as an approximation of the effective nanofluid extinction coefficient. Comparisons with measured extinction coefficients reveal that the approximation works well with water-based nanofluids containing graphite nanoparticles but less well with metallic nanoparticles and/or oil-based fluids. For the materials used in this study, over 95% of incoming sunlight can be absorbed (in a nanofluid thickness ≥10 cm with extremely low nanoparticle volume fractions - less than 1 × 10-5, or 10 parts per million. Thus, nanofluids could be used to absorb sunlight with a negligible amount of viscosity and/or density (read: pumping power increase.

  7. Nanofluid optical property characterization: towards efficient direct absorption solar collectors

    Science.gov (United States)

    Taylor, Robert A.; Phelan, Patrick E.; Otanicar, Todd P.; Adrian, Ronald; Prasher, Ravi

    2011-12-01

    Suspensions of nanoparticles (i.e., particles with diameters nanofluids, show remarkable thermal and optical property changes from the base liquid at low particle loadings. Recent studies also indicate that selected nanofluids may improve the efficiency of direct absorption solar thermal collectors. To determine the effectiveness of nanofluids in solar applications, their ability to convert light energy to thermal energy must be known. That is, their absorption of the solar spectrum must be established. Accordingly, this study compares model predictions to spectroscopic measurements of extinction coefficients over wavelengths that are important for solar energy (0.25 to 2.5 μm). A simple addition of the base fluid and nanoparticle extinction coefficients is applied as an approximation of the effective nanofluid extinction coefficient. Comparisons with measured extinction coefficients reveal that the approximation works well with water-based nanofluids containing graphite nanoparticles but less well with metallic nanoparticles and/or oil-based fluids. For the materials used in this study, over 95% of incoming sunlight can be absorbed (in a nanofluid thickness ≥10 cm) with extremely low nanoparticle volume fractions - less than 1 × 10-5, or 10 parts per million. Thus, nanofluids could be used to absorb sunlight with a negligible amount of viscosity and/or density (read: pumping power) increase.

  8. Direct and indirect methods for the quantification of leg volume: Comparison between water displacement volumetry, the disk model method and the frustum sign model method, using the correlation coefficient and the limits of agreement

    NARCIS (Netherlands)

    D.M.K.S. Kaulesar Sukul (D. M K S); P.Th. den Hoed (Pieter); T. Johannes (Tanja); R. van Dolder (R.); E. Benda (Eric)

    1993-01-01

    textabstractVolume changes can be measured either directly by water-displacement volumetry or by various indirect methods in which calculation of the volume is based on circumference measurements. The aim of the present study was to determine the most appropriate indirect method for lower leg volume

  9. Direct and indirect methods for the quantification of leg volume: Comparison between water displacement volumetry, the disk model method and the frustum sign model method, using the correlation coefficient and the limits of agreement

    NARCIS (Netherlands)

    D.M.K.S. Kaulesar Sukul (D. M K S); P.Th. den Hoed (Pieter); T. Johannes (Tanja); R. van Dolder (R.); E. Benda (Eric)

    1993-01-01

    textabstractVolume changes can be measured either directly by water-displacement volumetry or by various indirect methods in which calculation of the volume is based on circumference measurements. The aim of the present study was to determine the most appropriate indirect method for lower leg volume

  10. Function curve of the membranes that regulate amniotic fluid volume in sheep.

    Science.gov (United States)

    Faber, Job; Anderson, Debra; Hohimer, Roger; Yang, Qin; Giraud, George; Davis, Lowell

    2005-07-01

    Seven singleton 120-day fetal lambs were prepared with a shunt from the lung to the gastric end of the esophagus, a bladder catheter, and multiple amniotic fluid and vascular catheters. The urachus was ligated. Beginning 7 days later, amniotic fluid volumes were determined by drainage, followed by replacement with 1 liter of lactated Ringer (LR) solution. Urine flow into the amnion was measured continuously. In 14 of 27 experiments, amniotic fluid volumes were determined again 2 days after the inflow into the amnion had consisted of urine only and in 13 experiments after the inflow of urine had been supplemented by an intraamniotic infusion of LR solution. Intramembranous absorption was calculated from the inflows and the changes in volume between the beginning and end of each experiment. The relations between absorption rate and amniotic fluid volume, the "function curves," were highly individual. Urine production during the infusion of LR solution did not decrease, fetal plasma renin activity decreased (P amniotic fluid volume increased by 140% [SE (27%), P amniotic fluid per day. During the infusion of LR solution, the increase in the rate of absorption matched the rate of infusion (both in ml/h), with a regression coefficient of 0.75 (P amniotic fluid volumes, volume is not limited by the absorptive capacity of the amniochorion, and, at least in these preparations, the position of the function curve and not the natural rate of inflow was the major determinant of resting amniotic fluid volume.

  11. Correlativity Between Solubility O/W Partition Coefficients of Berbenine Hydrochloride and Intestinal Absorption in Rats in Situ%盐酸小檗碱的溶解度及油水分配系数与大鼠在体肠吸收之间的相关性研究

    Institute of Scientific and Technical Information of China (English)

    黄嗣航; 龙晓英; 袁飞; 陈莉; 罗明磊; 蔡宝玲; 刘昌顺

    2012-01-01

    OBJECTIVE To determine the equilibrium solubility and the partition coefficient of Berbenine Hydrochloride (BH) and to evaluate its intestinal absorption characteristic. METHODS The solubility and partition coefficient of BH were measured by shaking flask-UV spectrophotometry. The absorptions of three concentrations(50, 100, 150 ug-inL‐1) of BH in different intestinal segments were studied by phenol red assay and gravimetry. The concentrations of BH and phenol red were determined by HPLC. RESULTS The solubility of BH was increased with the pH increase of the buffer solution, and oil-water partition coefficient was decreased with increasing the pH of the buffer solution. Phenol red assay was better to reduce experimental error than gravimetry. There was positive correlation between the Permeability coefficient(Peff) of each intestine and concentrations of BH, and it has obvious difference(P<0.05) between the high concentration and low concentration. BH was well absorbed in jejunum at high and middle concentration, however, well absorption was observed in duodenum at low concentration. CONCLUSION In the experimental range, results of partition cofficients was in good accordance with predictive ones. BH was well absorbed at upper intestine than lower intestine over the concentration range. Extension of BH absorption time at upper intestine, could improve bioavailability.%目的 测定盐酸小檗碱(BH)的平衡溶解度和油水分配系数,并研究BH的大鼠肠吸收机制.方法 采用摇瓶-紫外分光光度法测定平衡溶解度及油水分配系数;分别采用酚红法和重量法校正灌流液体积,研究BH 3个剂量组(50,100,150μg·mL-1)在大鼠不同肠段的吸收情况.采用HIPLC对灌流前后BH、酚红含量进行测定.结果 BHI溶解度随pH值的增加而增加,油水分配系数则相反;酚红法较重量法能更好的减少实验误差,BH在低、中、高3个浓度下,各肠段的有效渗透系数(Peff)有上升趋势,且

  12. Wave Reflection Coefficient Spectrum

    Institute of Scientific and Technical Information of China (English)

    俞聿修; 邵利民; 柳淑学

    2003-01-01

    The wave reflection coefficient frequency spectrum and directional spectrum for concrete face slope breakwaters and rubble mound breakwaters are investigated through physical model tests in the present study. The reflection coefficients of oblique irregular waves are analyzed by the Modified Two-Point Method (MTPM) proposed by the authors. The results show that the wave reflection coefficient decreases with increasing wave frequency and incident angle or decreasing structure slope. The reflection coefficient frequency spectrum and its variation with Iribarren number are given in this paper. The paper also suggests an empirical 3-dimensional reflection coefficient spectrum, i.e. reflection coefficient directional spectrum, which can be used to illustrate quantitatively the variation of reflection coefficient with the incident angle and the Iribarren number for oblique irregular waves.

  13. Light absorption engineering of hydrogenated nanocrystalline silicon by femtosecond laser.

    Science.gov (United States)

    Zheng, D Q; Ma, Y J; Xu, L; Su, W A; Ye, Q H; Oh, J I; Shen, W Z

    2012-09-01

    The light absorption coefficient of hydrogenated nanocrystalline silicon has been engineered to have a Gaussian distribution by means of absorption modification using a femtosecond laser. The absorption-modified sample exhibits a significant absorption enhancement of up to ∼700%, and the strong absorption does not depend on the incident light. We propose a model responsible for this interesting behavior. In addition, we present an optical limiter constructed through this absorption engineering method.

  14. A novel ionic liquid/micro-volume back extraction procedure combined with flame atomic absorption spectrometry for determination of trace nickel in samples of nutritional interest

    Energy Technology Data Exchange (ETDEWEB)

    Dadfarnia, Shayesteh, E-mail: sdadfarnia@yazduni.ac.ir [Department of Chemistry, Faculty of Science, Yazd University, 89195/74, Yazd (Iran, Islamic Republic of); Haji Shabani, Ali Mohammad; Shirani Bidabadi, Mahboubeh; Jafari, Abbas Ali [Department of Chemistry, Faculty of Science, Yazd University, 89195/74, Yazd (Iran, Islamic Republic of)

    2010-01-15

    A simple, highly sensitive and environment-friendly method for the determination of trace amount of nickel ion in different matrices is proposed. In the preconcentration step, the nickel from 10 mL of an aqueous solution was extracted into 500 {mu}L of ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate [C{sub 4}MIM][PF{sub 6}], containing PAN as complexing agent. Subsequently, the PAN complex was back-extracted into 250 {mu}L of nitric acid solution, and 100 {mu}L of it was analyzed by flow injection flame atomic absorption spectrometry (FI-FAAS). The main parameter influencing the extraction and determination of nickel, such as pH, concentration of PAN, extraction time and temperature, ionic strength, and concentration of stripping acid solution, were optimized. An enhancement factor of 40.2 was achieved with 25 mL sample. The limit of detection (LOD) and quantification obtained under the optimum conditions were 12.5 and 41.0 {mu}g L{sup -1}, respectively. To validate the proposed methods two certified reference materials 681-I and BCR No. 288 were analyzed and the results were in good agreement with the certified values. The proposed method was successfully applied to determination of nickel in water samples, rice flour and black tea.

  15. A novel ionic liquid/micro-volume back extraction procedure combined with flame atomic absorption spectrometry for determination of trace nickel in samples of nutritional interest.

    Science.gov (United States)

    Dadfarnia, Shayesteh; Shabani, Ali Mohammad Haji; Bidabadi, Mahboubeh Shirani; Jafari, Abbas Ali

    2010-01-15

    A simple, highly sensitive and environment-friendly method for the determination of trace amount of nickel ion in different matrices is proposed. In the preconcentration step, the nickel from 10 mL of an aqueous solution was extracted into 500 microL of ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate [C(4)MIM][PF(6)], containing PAN as complexing agent. Subsequently, the PAN complex was back-extracted into 250 microL of nitric acid solution, and 100 microL of it was analyzed by flow injection flame atomic absorption spectrometry (FI-FAAS). The main parameter influencing the extraction and determination of nickel, such as pH, concentration of PAN, extraction time and temperature, ionic strength, and concentration of stripping acid solution, were optimized. An enhancement factor of 40.2 was achieved with 25 mL sample. The limit of detection (LOD) and quantification obtained under the optimum conditions were 12.5 and 41.0 microg L(-1), respectively. To validate the proposed methods two certified reference materials 681-I and BCR No. 288 were analyzed and the results were in good agreement with the certified values. The proposed method was successfully applied to determination of nickel in water samples, rice flour and black tea.

  16. Apparent Oil/water Partition Coefficient of 20(S)-PPD and Its Intestinal Absorption in Rats%20(S)-原人参二醇油水分配系数测定和大鼠在体肠吸收的研究

    Institute of Scientific and Technical Information of China (English)

    王冰; 王玉芹; 浦益琼; 徐本亮; 陶建生; 张彤

    2011-01-01

    目的 测定20(S)-原人参二醇[20 (S) -PPD]表现油水分配系数,并研究其在体肠吸收机理.方法 利用高效液相色谱法测定20 (S) -PPD浓度,采用摇瓶法测定其表观油水分配系数.采用大鼠在体单向肠灌流实验,按重量法计算动力学参数.结果 37℃条件下,20 (S) -PPD在正辛醇饱和水相中的表观油水分配系数为(1ogPapp=1.72),在不同pH磷酸盐缓冲液中的表观油水分配系数与水相中数值接近.20 (S)-PPD在整个肠段都有吸收,吸收速率常数按大小依次为十二指肠、空肠、回肠、结肠,结肠段的Ka和PApp与其他肠段比较相对较小,说明20 (S) -PPD的主要吸收部位在小肠.结论 不同pH值的介质对20 (S) -PPD表观油水分配系数影响不大;20 (S)-PPD在整个肠段均有良好的吸收,小肠为主要吸收部位.在该药物开发方面,应设法延长其在小肠内的滞留时间,以提高生物利用度.%Objective To determine the apparent oil/water partition coefficient of 20(S)-PPD and to investigate its absorption mechanism by in situ perfusion method in rat intestines. Methods The concentration of 20(S)-PPD was determined by HPLC. A shake flask method was established to determine oil/water partition coefficient of 20(S)-PPD. In situ perfused rat intestinal model was used to calculate the kinetic parameters by weight methods. Results At 37 ℃, the log Papp of 20(S)-PPD in octanol/water system was 1.72. Log Papp in different phosphate buffer solutions were close to that in aqueous phase. 20(S)-PPD was well absorbed in general intestinal tract, where its absorption rate constant (Ka) was duodenum>jejunum>ileum>colon. Ka and Papp in rat colon was relatively lower than in other intestinal tracts. It implied that the main absorption segment of 20(S)-PPD was small intestine. Conclusion The pH of buffer solution had no influence on its distribution coefficient. 20(S)-PPD was well absorbed in general intestinal tract with small intestine as

  17. Fast and accurate measurement of diffusion coefficient by Taylor's dispersion analysis

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    This investigation aimed at improving the performance of Taylor's dispersion analysis for the fast and accurate measurement of diffusion coefficient of a minute solute in various solvents. The investigation was carried out on a capillary electrophoresis instrument by monitoring the UV absorption peak of a solute pulse and calculating the diffusion coefficient by peak efficiency. With L-phenylalanine as a main testing solute, some key factors were afterward disclosed including especially the capillary size, carrier flow velocity, injection volume and capillary conditioning. Peak tailing, large volume of sample injection and slow migration were found to underestimate the diffusion coefficient while very fast migration and high sample concentration caused overestimation. At a moderate flow velocity of 0.1―1 cm/s with a capillary of 72.44 μm I.D.×60 cm (50 cm effective) maintained at 25℃, the diffusion coefficient of aqueous L-phenylalanine was determined, giving a value of 7.02×10-6 cm2/s with error<2% and relative standard deviation<0.2% (n=3). The method was shown to be applicable to the measurement of various samples such as aqueous phenylalanine, acetone, phenol, toluene and benzene, and nonaqueous benzene (in ethanol or 1-butanol).

  18. Characterization on the Mean Molar Absorptivity of Amino Acids in Microbial Lipopeptides

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The molar absorption coefficients of each of 14 kinds of amino acids were determined by the spectrophotometric method, and the mean molar absorption coefficients of 37 different mixtures of each with amino acid composition exactly equivalent to that of the peptide chain of the corresponding lipopeptide were determined based on calculation or experimental. The significance of the results is that the mean molar absorption coefficients strongly demonstrate the regular patterns, though different amino acids bear quite different molar absorption coefficients.

  19. Influence of the Metal Volume Fraction on the permanent dent depth and energy absorption of GLARE plates subjected to low velocity impact

    Science.gov (United States)

    Bikakis, GSE; Savaidis, A.; Zalimidis, P.; Tsitos, S.

    2016-11-01

    Fiber-metal laminates are hybrid composite materials, consisting of alternating metal layers bonded to fiber-reinforced prepreg layers. GLARE (GLAss REinforced) belongs to this new family of materials. GLARE is the most successful fiber-metal laminate up to now and is currently being used for the construction of primary aerospace structures, such as the fuselage of the Airbus A380 air plane. Impact properties are very important in aerospace structures, since impact damage is caused by various sources, such as maintenance damage from dropped tools, collision between service cars or cargo and the structure, bird strikes and hail. The principal objective of this article is to evaluate the influence of the Metal Volume Fraction (MVF) on the low velocity impact response of GLARE fiber-metal laminates. Previously published differential equations of motion are employed for this purpose. The low velocity impact behavior of various circular GLARE plates is predicted and characteristic values of impact variables, which represent the impact phenomenon, are evaluated versus the corresponding MVF of the examined GLARE material grades. The considered GLARE plates are subjected to low velocity impact under identical impact conditions. A strong effect of the MVF on the maximum impact load and a significant effect on the maximum plate deflection of GLARE plates has been found.

  20. High performance heat pump absorption cycles

    Energy Technology Data Exchange (ETDEWEB)

    Lazzarin, R.; Longo, G.; Rossetto, L.

    1988-10-01

    Absorption heat pumps can provide high performances when operating in suitable cycles with multiple effects. This report describes some multistage cycles and evaluates the coefficient of performance realistically obtainable both in winter and summer working conditions.

  1. Modified Biserial Correlation Coefficients.

    Science.gov (United States)

    Kraemer, Helena Chmura

    1981-01-01

    Asymptotic distribution theory of Brogden's form of biserial correlation coefficient is derived and large sample estimates of its standard error obtained. Its relative efficiency to the biserial correlation coefficient is examined. Recommendations for choice of estimator of biserial correlation are presented. (Author/JKS)

  2. Electromodulated absorption in smoky quartz

    NARCIS (Netherlands)

    Brom, W.E. van den; Volger, J.

    1974-01-01

    The optical absorption coefficient of “smoky” quartz (containing aluminium) can be modulated by applying an electric field. The effect saturates at high fields and low temperatures and reaches a maximum at 535 nm. The results are discussed in terms of a model consisting of a colour centre, dipolar i

  3. Total and Partial Absorption Coefficients for a Nitrogen Plasma

    Science.gov (United States)

    2014-09-26

    good estimate for the "cross section". Specifically, we use 2 <gc5 a +- 2.43i10- 3 7 2 < gff > cm(5) Te I /2 (hv)3 ion-elect. where z is the net...charge on the ion, Te the temperature in e.v., hv the photon energy in e.v., and < gff > the Gaunt factor averaged over a Maxwellian electron velocity...N it varies between 1.175 and 1.26; here we use < gff > = 1.225. 7 - -- ._. . ,l , j1 -o .. • b -. -’ . -. . -. . Free-free transitions in the fields

  4. Determination of sedimentation rates and absorption coefficient of ...

    African Journals Online (AJOL)

    DR. MIKE HORSFALL

    showed a decrease in the density of the carbonates and also correlated with the decrease in the mass (and ... Many chemical reactions form separable solid phase ... The precipitates were ... Zn2+ had the highest sedimentation rate constants,.

  5. Surface acoustic admittance and absorption of highly porous, layered, fibrous materials

    Science.gov (United States)

    Tesar, J. S.; Lambert, R. F.

    1984-01-01

    Some acoustic properties of Kevlar-29 - a fine fibered, layered material is investigated. Kevlar is characterized by very high strength, uniform filaments arranged in a parallel batt where most filaments are random in the x-y plane but ordered as planes in the z direction. For experimental purposes, volume porosity, static flow resistance and mean filament diameter are used to identify the material. To determine the acoustic surface admittance of Kevlar, batts of the material are cut into small pads and placed into a standing wave tube terminated by a rigid brass plug. The attenuation and relative phase shift are recorded at each frequency in the range of 50 to 6000 Hz. Normalized conductance and susceptance are combined to form the acoustic absorption coefficient. The data are compared with theory by plotting the normalized admittance and normal incident absorption coefficient versus cyclic frequency.

  6. Transport Coefficients of Fluids

    CERN Document Server

    Eu, Byung Chan

    2006-01-01

    Until recently the formal statistical mechanical approach offered no practicable method for computing the transport coefficients of liquids, and so most practitioners had to resort to empirical fitting formulas. This has now changed, as demonstrated in this innovative monograph. The author presents and applies new methods based on statistical mechanics for calculating the transport coefficients of simple and complex liquids over wide ranges of density and temperature. These molecular theories enable the transport coefficients to be calculated in terms of equilibrium thermodynamic properties, and the results are shown to account satisfactorily for experimental observations, including even the non-Newtonian behavior of fluids far from equilibrium.

  7. Absorption boundary conditions for geomertical acoustics

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2012-01-01

    Defining accurate acoustical boundary conditions is of crucial importance for room acoustic simulations. In predicting sound fields using phased geometrical acoustics methods, the absorption coefficients or surface impedances of the boundary surfaces can be used, but no guideline has been developed...... solutions. Two rectangular rooms with uniform and non-uniform absorption distributions are tested. It is concluded that the impedance and random incidence absorption boundary conditions produce reasonable results with some exceptions at low frequencies for acoustically soft materials....

  8. Bent Electro-Absorption Modulator

    DEFF Research Database (Denmark)

    2002-01-01

    components and the applied electric field in relation to the frequency of the modulated radiation, the bending losses (and possibly coupling losses) will provide extinction of light guided by the bent waveguide section. The refractive index contract may be modulated while keeping the absorption coefficient...... substantially constant and small, whereby the guided light can be modulated only by bending losses. Alternatively, the invention may be applied to enhance the extinction ratio of existing absorption modulators such as Electro-Absorption Modulators (EAMs) in which case extinction by absorption and extinction......The present invention relates to a method and a device for modulating optical signals based on modulating bending losses in bend, quantum well semiconductor waveguide sections. The complex refractive index of the optical active semiconducting components of the waveguide section is modulated...

  9. Multidimensional extremal dependence coefficients

    OpenAIRE

    2017-01-01

    Extreme values modeling has attracting the attention of researchers in diverse areas such as the environment, engineering, or finance. Multivariate extreme value distributions are particularly suitable to model the tails of multidimensional phenomena. The analysis of the dependence among multivariate maxima is useful to evaluate risk. Here we present new multivariate extreme value models, as well as, coefficients to assess multivariate extremal dependence.

  10. Two-photon absorption in arsenic sulfide glasses

    Science.gov (United States)

    Chunaev, D. S.; Snopatin, G. E.; Plotnichenko, V. G.; Karasik, A. Ya.

    2016-10-01

    The two-photon absorption coefficient of 1047-{\\text{nm}} light in {\\text{As}}35{\\text{S}}65 chalcogenide glass has been measured. CW probe radiation has been used to observe the linear absorption in glass induced by two-photon excitation. The induced absorption lifetime was found to be ∼ 2 {\\text{ms}}.

  11. Determination of the bulk diffusion coefficient of oxygen in [alpha] zirconium, in the temperature range 500-640 deg C, by nuclear microanalysis. Determination par microanalyse nucleaire du coefficient de diffusion en volume de l'oxygene dans le zirconium [alpha] entre 500 et 640 deg C

    Energy Technology Data Exchange (ETDEWEB)

    Viennot, M.; David, D.; Lambertin, M.; Beranger, G. (Universite de Technologie de Compiegne, 60 (France))

    1994-03-17

    The diffusion coefficient of oxygen in [alpha]-zirconium was measured in the temperature range 500-640 deg C, by means of nuclear microanalysis. Measurements were performed without grinding the samples, and then using a computer process applied to the nuclear spectra of emitted protons from the [sup 16]O (d,p)[sup 17] O[sup *] reaction. The results are in good agreement with higher temperature ones, previously measured by some of the authors. They are also in agreement with stress-strain aging results, at lower temperatures. These results are bulk diffusion ones. Nevertheless, they are rather different from a series of others, also at lower temperatures. This is perhaps the effect of a grain boundary diffusion phenomenon. (authors). 9 refs., 3 figs.

  12. Prestarlike functions with negative coefficients

    Directory of Open Access Journals (Sweden)

    H. Silverman

    1979-01-01

    Full Text Available The extreme points for prestarlike functions having negative coefficients are determined. Coefficient, distortion and radii of univalence, starlikeness, and convexity theorems are also obtained.

  13. Gorenstein Hilbert Coefficients

    CERN Document Server

    Khoury, Sabine El

    2012-01-01

    We prove upper and lower bounds for all the coefficients in the Hilbert Polynomial of a graded Gorenstein algebra $S=R/I$ with a quasi-pure resolution over $R$. The bounds are in terms of the minimal and the maximal shifts in the resolution of $R$ . These bounds are analogous to the bounds for the multiplicity found in \\cite{S} and are stronger than the bounds for the Cohen Macaulay algebras found in \\cite{HZ}.

  14. Sound absorption property of wood for five eucalypt species

    Institute of Scientific and Technical Information of China (English)

    JIANGZe-hui; ZHAORong-jun; FEIBen-hua

    2004-01-01

    The sound absorption coefficients of wood and wood boards for five eucalypt species (Eucalyptus urophylla, Eucalyptus urophylla×E. grandis, Eucalyptus urophylla×E. tereticornis, Eucalyptus urophylla×E. camaldulensis and Eucalyptus cloeziana) that were collected from plantation in Dongmen Forestry Center of Guangxi Province, China were tested with standing wave method and their sound absorption properties were also compared. The results showed that the sound absorption coefficients of the five eucalypt wood species did not change evidently below 1000 Hz, but above 1000 Hz their sound absorption coefficients increased with the increasing frequency. The difference in sound absorption coefficient among five species of eucalypt wood is not evident at the tested frequency range (200-2000 Hz), but the sound absorption property of Eucalyptus urophylla at low frequency is better than that of other four species. The sound absorption coefficient of the tangential-sawn board is higher than that of the radial-sawn board. The sound absorption property of eucalypt wood of 0.5 cm in thickness is much better than that of 1.0 cm in thickness. It is concluded that wood sound absorption properties of eucalypts are affected by their board thickness and the type of sawn timber within the testing frequency, but the variance of wood sound absorption property among the five tested species is not significant.

  15. Geometric absorption of electromagnetic angular momentum

    Science.gov (United States)

    Konz, C.; Benford, Gregory

    2003-10-01

    Circularly polarized electromagnetic fields carry both energy and angular momentum. We investigate the conditions under which a circularly polarized wave field transfers angular momentum to a perfectly conducting macroscopic object, using exact electromagnetic wave theory in a steady-state calculation. We find that axisymmetric perfect conductors cannot absorb or radiate angular momentum when illuminated. However, any asymmetry allows absorption. A rigorous, steady-state solution of the boundary value problem for the reflection from a perfectly conducting infinite wedge shows that waves convey angular momentum at the edges of asymmetries. Conductors can also radiate angular momentum, so their geometric absorption coefficient for angular momentum can be negative. Such absorption or radiation depends solely on the specific geometry of the conductor. The geometric absorption coefficient can be as high as 0.8, and the coefficient for radiation can be -0.4, larger than typical material absorption coefficients. We apply the results to recent experiments which spun roof-shaped aluminum sheets with polarized microwave beams. Applications of geometric, instead of material, absorption can be quite varied. Though experiments testing these ideas will be simpler at microwavelengths, the ideas work for optical ones as well.

  16. Subgap Absorption in Conjugated Polymers

    Science.gov (United States)

    Sinclair, M.; Seager, C. H.; McBranch, D.; Heeger, A. J; Baker, G. L.

    1991-01-01

    Along with X{sup (3)}, the magnitude of the optical absorption in the transparent window below the principal absorption edge is an important parameter which will ultimately determine the utility of conjugated polymers in active integrated optical devices. With an absorptance sensitivity of conjugated polymers poly(1,4-phenylene-vinylene) (and derivitives) and polydiacetylene-4BCMU in the spectral region from 0.55 eV to 3 eV. Our spectra show that the shape of the absorption edge varies considerably from polymer to polymer, with polydiacetylene-4BCMU having the steepest absorption edge. The minimum absorption coefficients measured varied somewhat with sample age and quality, but were typically in the range 1 cm{sup {minus}1} to 10 cm{sup {minus}1}. In the region below 1 eV, overtones of C-H stretching modes were observed, indicating that further improvements in transparency in this spectral region might be achieved via deuteration of fluorination.

  17. Development in Laser Induced Extrinsic Absorption Damage Mechanism of Dielectric Films

    Institute of Scientific and Technical Information of China (English)

    XIA Zhi-Lin; DENG De-Gang; FAN Zheng-Xiu; SHAO Jian-Da

    2006-01-01

    @@ Absorption of host and the temperature-dependence of absorption coefficient have been considered in evaluating temperature distribution in films, when laser pulse irradiates on films. Absorption of dielectric materials experience three stages with the increase of temperature: multi-photon absorption; single photon absorption; metallic absorption. These different absorption mechanisms correspond to different band gap energies of materials, which will decrease when the temperature of materials increases. Evaluating results indicate that absorption of host increases rapidly when the laser pulse will be over. If absorption of host and the temperature-dependence of absorption are considered, the maximal temperatures in films will be increased by a factor of four.

  18. Electromagnetic absorption properties of spacecraft and space debris

    Science.gov (United States)

    Micheli, D.; Santoni, F.; Giusti, A.; Delfini, A.; Pastore, R.; Vricella, A.; Albano, M.; Arena, L.; Piergentili, F.; Marchetti, M.

    2017-04-01

    Aim of the work is to present a method to evaluate the electromagnetic absorption properties of spacecraft and space debris. For these objects, the radar detection ability depends mainly on volume, shape, materials type and other electromagnetic reflecting behaviour of spacecraft surface components, such as antennas or thermal blankets, and of metallic components in space debris. The higher the electromagnetic reflection coefficient of such parts, the greater the radar detection possibility. In this research an electromagnetic reverberation chamber is used to measure the absorption cross section (ACS) of four objects which may represent space structure operating components as well as examples of space debris: a small satellite, a composite antenna dish, a Thermal Protection System (TPS) tile and a carbon-based composite missile shell. The ACS mainly depends on geometrical characteristics like apertures, face numbers and bulk porosity, as well as on the type of the material itself. The ACS, which is an electromagnetic measurement, is expressed in squared meters and thus can be compared with the objects geometrical cross section. A small ACS means a quite electromagnetic reflective tendency, which is beneficial for radar observations; on the contrary, high values of ACS indicate a strong absorption of the electromagnetic field, which in turn can result a critical hindering of radar tracking.

  19. The Truth About Ballistic Coefficients

    CERN Document Server

    Courtney, Michael

    2007-01-01

    The ballistic coefficient of a bullet describes how it slows in flight due to air resistance. This article presents experimental determinations of ballistic coefficients showing that the majority of bullets tested have their previously published ballistic coefficients exaggerated from 5-25% by the bullet manufacturers. These exaggerated ballistic coefficients lead to inaccurate predictions of long range bullet drop, retained energy and wind drift.

  20. Light-Intensity-Induced Characterization of Elastic Constants and d33 Piezoelectric Coefficient of PLZT Single Fiber Based Transducers

    Directory of Open Access Journals (Sweden)

    Jiri Erhart

    2013-02-01

    Full Text Available Enhanced functionality of electro-optic devices by implementing piezoelectric micro fibers into their construction is proposed. Lanthanum-modified lead zirconate titanate (PLZT ceramics are known to exhibit high light transparency, desirable electro-optic properties and fast response. In this study PLZT fibers with a diameter of around 300 microns were produced by a thermoplastic processing method and their light-induced impedance and piezoelectric coefficient were investigated at relatively low light intensity (below 50 mW/cm2. The authors experimentally proved higher performance of light controlled microfiber transducers in comparison to their bulk form. The advantage of the high surface area to volume ratio is shown to be an excellent technique to design high quality light sensors by using fibrous materials. The UV absorption induced change in elastic constants of 3% and 4% for the piezoelectric coefficient d33.

  1. Light-intensity-induced characterization of elastic constants and d33 piezoelectric coefficient of PLZT single fiber based transducers.

    Science.gov (United States)

    Kozielski, Lucjan; Erhart, Jiri; Clemens, Frank Jörg

    2013-02-12

    Enhanced functionality of electro-optic devices by implementing piezoelectric micro fibers into their construction is proposed. Lanthanum-modified lead zirconate titanate (PLZT) ceramics are known to exhibit high light transparency, desirable electro-optic properties and fast response. In this study PLZT fibers with a diameter of around 300 microns were produced by a thermoplastic processing method and their light-induced impedance and piezoelectric coefficient were investigated at relatively low light intensity (below 50 mW/cm2). The authors experimentally proved higher performance of light controlled microfiber transducers in comparison to their bulk form. The advantage of the high surface area to volume ratio is shown to be an excellent technique to design high quality light sensors by using fibrous materials. The UV absorption induced change in elastic constants of 3% and 4% for the piezoelectric coefficient d(33).

  2. Self-assembly based plasmonic arrays tuned by atomic layer deposition for extreme visible light absorption.

    Science.gov (United States)

    Hägglund, Carl; Zeltzer, Gabriel; Ruiz, Ricardo; Thomann, Isabell; Lee, Han-Bo-Ram; Brongersma, Mark L; Bent, Stacey F

    2013-07-10

    Achieving complete absorption of visible light with a minimal amount of material is highly desirable for many applications, including solar energy conversion to fuel and electricity, where benefits in conversion efficiency and economy can be obtained. On a fundamental level, it is of great interest to explore whether the ultimate limits in light absorption per unit volume can be achieved by capitalizing on the advances in metamaterial science and nanosynthesis. Here, we combine block copolymer lithography and atomic layer deposition to tune the effective optical properties of a plasmonic array at the atomic scale. Critical coupling to the resulting nanocomposite layer is accomplished through guidance by a simple analytical model and measurements by spectroscopic ellipsometry. Thereby, a maximized absorption of light exceeding 99% is accomplished, of which up to about 93% occurs in a volume-equivalent thickness of gold of only 1.6 nm. This corresponds to a record effective absorption coefficient of 1.7 × 10(7) cm(-1) in the visible region, far exceeding those of solid metals, graphene, dye monolayers, and thin film solar cell materials. It is more than a factor of 2 higher than that previously obtained using a critically coupled dye J-aggregate, with a peak width exceeding the latter by 1 order of magnitude. These results thereby substantially push the limits for light harvesting in ultrathin, nanoengineered systems.

  3. Sound absorption property of open-pore aluminum foams

    Institute of Scientific and Technical Information of China (English)

    WANG Lu-cai; WANG Fang; WU Jian-guo; YOU Xiao-hong

    2006-01-01

    The sound absorption property of aluminum foam was studied by testing its sound absorption coefficients using standing wave tube method. The open-pore aluminum foams were prepared by infiltration process, with pore size of 0.5 mm to 3.2 mm and porosity of 54.2% to 77%. The frequency of indicted sound wave was ranging from 125 Hz to 10 kHz. The results show that the average values of sound absorption coefficients are all over 0.4 and the aluminum foam has better sound absorption property, its coefficients is influenced by frequency and pore structure, and reaches the maximum at about 1 kHz, with increasing porosity and decreasing cell diameter the sound absorption coefficient values increase.

  4. Examination of the Measurement of Absorption Using the Reverberant Room Method for Highly Absorptive Acoustic Foam

    Science.gov (United States)

    Hughes, William O.; McNelis, Anne M.; Chris Nottoli; Eric Wolfram

    2015-01-01

    The absorption coefficient for material specimens are needed to quantify the expected acoustic performance of that material in its actual usage and environment. The ASTM C423-09a standard, "Standard Test Method for Sound Absorption and Sound Absorption Coefficients by the Reverberant Room Method" is often used to measure the absorption coefficient of material test specimens. This method has its basics in the Sabine formula. Although widely used, the interpretation of these measurements are a topic of interest. For example, in certain cases the measured Sabine absorption coefficients are greater than 1.0 for highly absorptive materials. This is often attributed to the diffraction edge effect phenomenon. An investigative test program to measure the absorption properties of highly absorbent melamine foam has been performed at the Riverbank Acoustical Laboratories. This paper will present and discuss the test results relating to the effect of the test materials' surface area, thickness and edge sealing conditions. A follow-on paper is envisioned that will present and discuss the results relating to the spacing between multiple piece specimens, and the mounting condition of the test specimen.

  5. Nonlinear optical absorption of photosynthetic pigment molecules in leaves.

    Science.gov (United States)

    Ye, Zi-Piao

    2012-04-01

    A mathematical formulation of the relationship between optical absorption coefficient of photosynthetic pigment molecules and light intensity was developed. It showed that physical parameters of photosynthetic pigment molecule (i.e., light absorption cross-section of photosynthetic pigment molecule, its average lifetime in the excited state, total photosynthetic pigment molecules, the statistical weight, or degeneracy of energy level of photosynthetic pigment molecules in the ground state and in the excited state) influenced on both the light absorption coefficient and effective light absorption cross-section of photosynthetic pigment molecules. Moreover, it also showed that both the light absorption coefficient and effective light absorption cross-section of photosynthetic pigment molecules were not constant, they decreased nonlinearly with light intensity increasing. The occupation numbers of photosynthetic pigment molecules in the excited states increased nonlinearly with light intensity increasing.

  6. Sound absorption mapping of highway noise barrier

    OpenAIRE

    Grosso, Andrea

    2012-01-01

    International audience; Sound propagation from highway to the urban areas can be reduced using noise barriers. The general computational modeling takes typically into account sound ray lines, reflection and diffraction, although the absorption distribution over the surface in not considered. The sound absorption coefficient can be calculated using a PU probe, by the impedance measured “in situ” close by the surface. Well known methods are available on the market for estimating the sound absor...

  7. Evaluation of mass absorption in LiBr flat-fan sheets

    Energy Technology Data Exchange (ETDEWEB)

    Palacios, E. [Escuela Universitaria de Ingenieria Tecnica Industrial, U.P.M., Ronda de Valencia 3, 28012 Madrid (Spain); Izquierdo, M. [Instituto de Ciencias de la Construccion Eduardo Torroja, C.S.I.C., Serrano Galvache 4, 28033 Madrid (Spain); Escuela Politecnica Superior, Universidad Carlos III de Madrid, Avda. de la Universidad 30, 28911 Madrid (Spain); Marcos, J.D. [Escuela Tecnica Superior de Ingenieria Industrial, U.N.E.D., Juan del Rosal 12, 28040 Madrid (Spain); Lizarte, R. [Escuela Politecnica Superior, Universidad Carlos III de Madrid, Avda. de la Universidad 30, 28911 Madrid (Spain)

    2009-12-15

    Experiments were conducted to determine the absorption rates of refrigerant vapour in an aqueous lithium bromide flat-fan sheet for use in absorption air-conditioning systems. The solution flow rates tested ranged from 0.023 to 0.054 kg/s (84-194 kg/h), with pressure losses in the injection nozzle of from 40 to 250 kPa. The effect of the mass flow rate on both solution residence time and the sheet deformation rate was also analyzed in absorption chambers of a pre-defined length, along with the effect of the sub-cooling temperature on the amount of vapour absorbed. The downstream evolution of approach to equilibrium factor F was quantified. The mass transfer coefficient values were found to be over 3 x 10{sup -4} m/s. In absorption chambers 100 mm long, over 0.8 g/s l of vapour were absorbed per chamber absorption volume. Moreover, about 600 g of vapour were absorbed per kJ of solution flow work. Flat-fan sheet configurations were found to perform better than falling film and spray absorbers. (author)

  8. Calibration coefficient of reference brachytherapy ionization chamber using analytical and Monte Carlo methods.

    Science.gov (United States)

    Kumar, Sudhir; Srinivasan, P; Sharma, S D

    2010-06-01

    A cylindrical graphite ionization chamber of sensitive volume 1002.4 cm(3) was designed and fabricated at Bhabha Atomic Research Centre (BARC) for use as a reference dosimeter to measure the strength of high dose rate (HDR) (192)Ir brachytherapy sources. The air kerma calibration coefficient (N(K)) of this ionization chamber was estimated analytically using Burlin general cavity theory and by the Monte Carlo method. In the analytical method, calibration coefficients were calculated for each spectral line of an HDR (192)Ir source and the weighted mean was taken as N(K). In the Monte Carlo method, the geometry of the measurement setup and physics related input data of the HDR (192)Ir source and the surrounding material were simulated using the Monte Carlo N-particle code. The total photon energy fluence was used to arrive at the reference air kerma rate (RAKR) using mass energy absorption coefficients. The energy deposition rates were used to simulate the value of charge rate in the ionization chamber and N(K) was determined. The Monte Carlo calculated N(K) agreed within 1.77 % of that obtained using the analytical method. The experimentally determined RAKR of HDR (192)Ir sources, using this reference ionization chamber by applying the analytically estimated N(K), was found to be in agreement with the vendor quoted RAKR within 1.43%.

  9. Quantum-Confined and Enhanced Optical Absorption of Colloidal PbS Quantum Dots at Wavelengths with Expected Bulk Behavior.

    Science.gov (United States)

    Debellis, Doriana; Gigli, Giuseppe; Ten Brinck, Stephanie; Infante, Ivan; Giansante, Carlo

    2017-02-08

    Nowadays it is well-accepted to attribute bulk-like optical absorption properties to colloidal PbS quantum dots (QDs) at wavelengths above 400 nm. This assumption permits to describe PbS QD light absorption by using bulk optical constants and to determine QD concentration in colloidal solutions from simple spectrophotometric measurements. Here we demonstrate that PbS QDs experience the quantum confinement regime across the entire near UV-vis-NIR spectral range, therefore also between 350 and 400 nm already proposed to be sufficiently far above the band gap to suppress quantum confinement. This effect is particularly relevant for small PbS QDs (with diameter of ≤4 nm) leading to absorption coefficients that largely differ from bulk values (up to ∼40% less). As a result of the broadband quantum confinement and of the high surface-to-volume ratio peculiar of nanocrystals, suitable surface chemical modification of PbS QDs is exploited to achieve a marked, size-dependent enhancement of the absorption coefficients compared to bulk values (up to ∼250%). We provide empirical relations to determine the absorption coefficients at 400 nm of as-synthesized and ligand-exchanged PbS QDs, accounting for the broadband quantum confinement and suggesting a heuristic approach to qualitatively predict the ligand effects on the optical absorption properties of PbS QDs. Our findings go beyond formalisms derived from Maxwell Garnett effective medium theory to describe QD optical properties and permit to spectrophotometrically calculate the concentration of PbS QD solutions avoiding underestimation due to deviations from the bulk. In perspective, we envisage the use of extended π-conjugated ligands bearing electronically active substituents to enhance light-harvesting in QD solids and suggest the inadequacy of the representation of ligands at the QD surface as mere electric dipoles.

  10. Renormalized Volume

    CERN Document Server

    Gover, A Rod

    2016-01-01

    For any conformally compact manifold with hypersurface boundary we define a canonical renormalized volume functional and compute an explicit, holographic formula for the corresponding anomaly. For the special case of asymptotically Einstein manifolds, our method recovers the known results. The anomaly does not depend on any particular choice of regulator, but the coefficients of divergences do. We give explicit formulae for these divergences valid for any choice of regulating hypersurface; these should be relevant to recent studies of quantum corrections to entanglement entropies. The anomaly is expressed as a conformally invariant integral of a local Q-curvature that generalizes the Branson Q-curvature by including data of the embedding. In each dimension this canonically defines a higher dimensional generalization of the Willmore energy/rigid string action. We show that the variation of these energy functionals is exactly the obstruction to solving a singular Yamabe type problem with boundary data along the...

  11. Evaluation of Fourier transform coefficients for the diagnosis of rheumatoid arthritis from diffuse optical tomography images

    Science.gov (United States)

    Montejo, Ludguier D.; Jia, Jingfei; Kim, Hyun K.; Hielscher, Andreas H.

    2013-03-01

    We apply the Fourier Transform to absorption and scattering coefficient images of proximal interphalangeal (PIP) joints and evaluate the performance of these coefficients as classifiers using receiver operator characteristic (ROC) curve analysis. We find 25 features that yield a Youden index over 0.7, 3 features that yield a Youden index over 0.8, and 1 feature that yields a Youden index over 0.9 (90.0% sensitivity and 100% specificity). In general, scattering coefficient images yield better one-dimensional classifiers compared to absorption coefficient images. Using features derived from scattering coefficient images we obtain an average Youden index of 0.58 +/- 0.16, and an average Youden index of 0.45 +/- 0.15 when using features from absorption coefficient images.

  12. Mass Transfer Enhancement of Gas Absorption by Adding the Dispersed Organic Phases

    Institute of Scientific and Technical Information of China (English)

    张志刚; 许天行; 李文秀; 纪智玲; 许光荣

    2011-01-01

    Mass transfer enhancement of gas absorption by adding a dispersed organic phase has been studied in this work. Various dispersed organic phases (heptanol, octanol, isoamyl alcohol, heptane, octane, and isooctane) were tested respectively in the experiment. According to the theoretical model and experimental data, the overall volumetric mass transfer coefficient and enhancement factor were obtained under different dispersed organic phase volume fraction and stirring speed. The experimental results indicate that gas-liquid mass transfer is enhanced at different level by adding a dispersed organic phase. The best performance of enhancement were achieved with the dispersed organic phase volumetric fraction of 5% and under an intermediate stirring speed of 670 r·min^-1. Among the organic phases tested in the experiment, alcohols show better performance, which gave 20% higher enhance-ment of overall volumetric mass transfer coefficient than adding alkanes.

  13. Broken-cloud enhancement of solar radiation absorption

    Energy Technology Data Exchange (ETDEWEB)

    Byrne, R.N. [Science Applications International Corporation, San Diego, CA (United States); Somerville, R.C. [Univ. of California, La Jolla, CA (United States); Subasilar, B. [Curtain Univ. of Technology, Perth (Australia)

    1996-04-01

    Two papers recently published in Science have shown that there is more absorption of solar radiation than estimated by current atmospheric general circulation models (GCMs) and that the discrepancy is associated with cloudy scenes. We have devised a simple model which explains this as an artifact of stochastic radiative transport. We first give a heuristic description, unencumbered by mathematical detail. Consider a simple case with clouds distributed at random within a single level whose upper and lower boundaries are fixed. The solar zenith angle is small to moderate; this is therefore an energetically important case. Fix the average areal liquid water content of the cloud layer, and take the statistics of the cloud distribution to be homogeneous within the layer. Furthermore, assume that all the clouds in the layer have the same liquid water content, constant throughout the cloud, and that apart from their droplet content they are identical to the surrounding clear sky. Let the clouds occupy on the average a fraction p{sub cld} of the volume of the cloudy layer, and let them have a prescribed distribution of sizes about some mean. This is not a fractal distribution, because it has a scale. Cloud shape is unimportant so long as cloud aspect ratios are not far from unity. Take the single-scattering albedo to be unity for the droplets in the clouds. All of the absorption is due to atmospheric gases, so the absorption coefficient at a point is the same for cloud and clear sky. Absorption by droplets is less than 10% effect in the numerical stochastic radiation calculations described below, so it is reasonable to neglect it at this level of idealization.

  14. Evolution of absorption machines; Evolution des machines a absorption

    Energy Technology Data Exchange (ETDEWEB)

    Soide, I.; Klemsdal, E. [Gaz de France (GDF), 75 - Paris (France); Le Goff, P.; Hornut, J.M. [LSGC-ENSIC, 54 - Nancy (France)

    1997-12-31

    Most of todays absorption air-conditioning machineries use the lithium bromide-water pair. The most performing can operate at a 150-160 deg. C, the temperature being limited by the corrosion resistance of metals with respect to LiBr solutions. Also, there is a revival of interest for water-ammonia systems. These systems require the use of a rectification column which reduces the coefficient of performance. Higher thermal performances are reached with hydrocarbon pairs and ternary mixtures (water-methanol-LiBr etc..). This paper presents different schemes of refrigerating heat pumps based on these different systems. (J.S.)

  15. Measuring sound absorption using local field assumptions

    NARCIS (Netherlands)

    Kuipers, E.R.

    2013-01-01

    To more effectively apply acoustically absorbing materials, it is desirable to measure angle-dependent sound absorption coefficients, preferably in situ. Existing measurement methods are based on an overall model of the acoustic field in front of the absorber, and are therefore sensitive to

  16. Sound absorption characteristics of microperforated absorbers for random incidence

    Institute of Scientific and Technical Information of China (English)

    MAA Dah-You; LIU Ke

    2000-01-01

    Based on previous work on "Statistical absorption coefficient of microperforated absorbers", in which it was shown that theoretical results agree well with experiments on the absorption characteristics of microperforated absorbers (MPA) for random incidence. Further work was carried out in this investigation of the statistical absorption coefficients of MPA in random fields by computation, in order to find the best structure of MPA. It is established that ordinarily the absorption curves of MPA for random incidence and that for normal incidence are quite alike, only that the absorption coefficients are more or less reduced and the whole curve is shifted to higher frequencies without any change of shape. But when the perforate constant k = d/ωρο/4η where d is the diameters of perforations in mm and fo, the absorbers resonance frequency is reduced below 2, say, secondary absorption bands start to play more important role. Pretty soon, they merge with the main absorption band and form a long tail of the latter,extending the absorption far into high frequencies, raising the resulting absorption band to three, four or more octaves. The behavior of the secondary absorption bands is discussed.

  17. 兔血管对He-Ne激光的反射、透射、吸收系数和散射相函数的研究%Reflection,Transmission,Absorption Coefficients and Scattering Phase Function of Rabbit Arteries and Veins at He-Ne Laser in Vitro

    Institute of Scientific and Technical Information of China (English)

    魏华江; 李晓原; 刘小星; 魏冬季; 谭润初

    2001-01-01

    In the present paper,the characterist ic of laser light transporting in rabbit arteries and veins with the aid of the primary theories of photobiology,elementary medical science and physics were stu died.Diffuse reflectance(R) and transmittance(T) of rabbit arteries and veins samples were me asured by a standard integrating spheres system,using He-Ne laser in 632.8?nm wavelength and the absorbance(A) was deduced.The scattering phase function S( θ) were obtained by the experimental arrangement repacked from a spectroscope at angles from -90° to 90°for rabbit arteries and veins samples in 632.8?nm wavelength and the mean cosines of scatter(μ) was calculated.The resul ts showed that the diffuse reflectance of rabbit arteries was bigger than that o f veins at He-Ne laser(P<0.01).The transmittance of rabbit arteries was obviou sly lesser than that of rabbit veins(P<0.01).The absorption coefficient of rabb it arteries was obviously lesser than that of veins.The optical penetration dept h of rabbit veins was obviously lsser than that of rabbit arteries at He-Ne la ser.Rabbit arteries and veins had stronger backward scattering(μα< 0.5, μν0.5),and that backward scattering of rabbit veins was obviously s tronger than that of rabbit arteries at He-Ne laser.There are obvious differenc e of the scattering phase functions between rabbit arteries and veins at He-Ne laser.There are obvious difference of the optical properties between rabbit arte ries and veins to the reflection,transmission,absoprtion coefficients and scatte ring phase functions of He-Ne laser.It is prompted that should be considered wh en He-Ne laser was applied to treat illness of human artery and vein.%本文运用光生物学、基础医学以及物理学的基本理论,探讨了兔血管组织的激光传播特性,定量测定了兔血管组织的激光传输参量.采用标准积分球测量了兔血管组织样品在632.8?nm He-Ne激光照射下的透射率(T)和反射率(R),推算吸收率 (A

  18. Quadrature formulas for Fourier coefficients

    KAUST Repository

    Bojanov, Borislav

    2009-09-01

    We consider quadrature formulas of high degree of precision for the computation of the Fourier coefficients in expansions of functions with respect to a system of orthogonal polynomials. In particular, we show the uniqueness of a multiple node formula for the Fourier-Tchebycheff coefficients given by Micchelli and Sharma and construct new Gaussian formulas for the Fourier coefficients of a function, based on the values of the function and its derivatives. © 2009 Elsevier B.V. All rights reserved.

  19. Coefficient Alpha: A Reliability Coefficient for the 21st Century?

    Science.gov (United States)

    Yang, Yanyun; Green, Samuel B.

    2011-01-01

    Coefficient alpha is almost universally applied to assess reliability of scales in psychology. We argue that researchers should consider alternatives to coefficient alpha. Our preference is for structural equation modeling (SEM) estimates of reliability because they are informative and allow for an empirical evaluation of the assumptions…

  20. Measuring of heat transfer coefficient

    DEFF Research Database (Denmark)

    Henningsen, Poul; Lindegren, Maria

    Subtask 3.4 Measuring of heat transfer coefficient Subtask 3.4.1 Design and setting up of tests to measure heat transfer coefficient Objective: Complementary testing methods together with the relevant experimental equipment are to be designed by the two partners involved in order to measure...... the heat transfer coefficient for a wide range of interface conditions in hot and warm forging processes. Subtask 3.4.2 Measurement of heat transfer coefficient The objective of subtask 3.4.2 is to determine heat transfer values for different interface conditions reflecting those typically operating in hot...

  1. Measuring of heat transfer coefficient

    DEFF Research Database (Denmark)

    Henningsen, Poul; Lindegren, Maria

    Subtask 3.4 Measuring of heat transfer coefficient Subtask 3.4.1 Design and setting up of tests to measure heat transfer coefficient Objective: Complementary testing methods together with the relevant experimental equipment are to be designed by the two partners involved in order to measure...... the heat transfer coefficient for a wide range of interface conditions in hot and warm forging processes. Subtask 3.4.2 Measurement of heat transfer coefficient The objective of subtask 3.4.2 is to determine heat transfer values for different interface conditions reflecting those typically operating in hot...

  2. Anisotropy in Thermo-Optic Coefficient of Different Polymer Systems by Attenuated Total Reflection Configuration

    Institute of Scientific and Technical Information of China (English)

    LI Xiang; CAO Zhuang-Qi; SHEN Qi-Shun; MENG Qing-Hua; HUANG De-Ying; GUO Kun-Peng; QIU Ling; SHEN Yu-Quan

    2006-01-01

    @@ Thermo-optic coefficient dn/dT as well as volume expansion coefficients β of different polymer systems are measured for both TE and TM polarizations in an attenuated total reflection (ATR) configuration. Experimental results indicate that cross-linked polymer systems exhibit the thermal expansion coefficients smaller than those of the original side-chain systems. Moreover, the anisotropies in thermo-optic coefficients of the polymer systems with small birefringence exhibit linear relationship with the anisotropies in volume expansion coefficients, but the polymer systems with larger birefringence exhibit more complicated relationship.

  3. Optical absorption of charged excitons in semiconducting carbon nanotubes

    DEFF Research Database (Denmark)

    Rønnow, Troels Frimodt; Pedersen, Thomas Garm; Cornean, Horia

    2012-01-01

    In this article we examine the absorption coefficient of charged excitons in carbon nanotubes. We investigate the temperature and damping dependence of the absorption spectra. We show that the trion peak in the spectrum is asymmetric for temperatures greater than approximately 1 K whereas the abs...

  4. Stochastic approach to phonon-assisted optical absorption

    OpenAIRE

    Zacharias, Marios; Patrick, Christopher E.; Giustino, Feliciano

    2015-01-01

    We develop a first-principles theory of phonon-assisted optical absorption in semiconductors and insulators which incorporates the temperature dependence of the electronic structure. We show that the Hall-Bardeen-Blatt theory of indirect optical absorption and the Allen-Heine theory of temperature-dependent band structures can be derived from the present formalism by retaining only one-phonon processes. We demonstrate this method by calculating the optical absorption coefficient of silicon us...

  5. Hybrid membrane resonators for multiple frequency asymmetric absorption and reflection in large waveguide

    CERN Document Server

    Fu, Caixing; Yang, Min; Xiao, Songwen; Yang, Z

    2016-01-01

    We report that Hybrid membrane resonators (HMRs) made of a decorated membrane resonator backed by a shallow cavity can function as Helmholtz resonators (HRs) when mounted on the sidewall of a clear waveguide for air ventilation. When two single-frequency HMRs are used in the same scheme as two frequency-detuned HRs, asymmetric total absorption/reflection is demonstrated at 286.7 Hz with absorption coefficient over 97 % in a waveguide 9 cm x 9 cm in cross section. When two multiple-frequency HMRs are used, absorption in the range of near 60 % to above 80 % is observed at 403 Hz, 450 Hz, 688 Hz, 863 Hz and 945 Hz. Theoretical predictions agree well with the experimental data. The HMRs may replace HRs in duct noise reduction applications in that at a single operation frequency they have stronger strength to cover a much larger cross section area than that of HRs with similar cavity volume, and they can be designed to provide multiple frequency absorption band.

  6. New in vitro dermal absorption database and the prediction of dermal absorption under finite conditions for risk assessment purposes

    NARCIS (Netherlands)

    Buist, H.E.; Burgsteden, J.A. van; Freidig, A.P.; Maas, W.J.M.; Sandt, J.J.M. van de

    2010-01-01

    Most QSARs for dermal absorption predict the permeability coefficient, Kp, of a molecule, which is valid for infinite dose conditions. In practice, dermal exposure mostly occurs under finite dose conditions. Therefore, a simple model to predict finite dose dermal absorption from infinite

  7. Photothermal determination of optical coefficients using an optical fibre sensor

    CERN Document Server

    Laufer, J

    2000-01-01

    configuration is more sensitive to the thermal coefficients than the optical coefficients of the target. Pulsed photothermal radiometry was found to have higher sensitivity to the optical coefficients than has the optical fibre sensor in its present form. However, modifications to the configuration of the sensor can produce a performance matching that of pulsed photothermal radiometry. This thesis is concerned with the development of an optical fibre sensor for the photothermal determination of the optical coefficients of tissue. The detection of differences in tissue optical properties might be used for the diagnosis of cancers and other tissue pathologies. The sensor consists of a thin transparent polymer film mounted at the distal end of an optical fibre. The film acts as a Fabry-Perot interferometer. The absorption of short, low energy laser pulses transmitted through the film and into the tissue generates thermal as well as acoustic transients, which propagate into/the film and modulate its thickness. Th...

  8. The saturable absorption and reverse saturable absorption properties of Cu doped zinc oxide thin films

    Science.gov (United States)

    Yao, Cheng-Bao; Wen, Xin; Li, Qiang-Hua; Yan, Xiao-Yan; Li, Jin; Zhang, Ke-Xin; Sun, Wen-Jun; Bai, Li-Na; Yang, Shou-Bin

    2017-03-01

    We present the structure and nonlinear absorption (NLA) properties of Cu-doped ZnO (CZO) films prepared by magnetron sputtering. The films were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The results show that the CZO films can maintain a wurtzite structure. Furthermore, the open-aperture (OA) Z-scan measurements of the film were carried out by nanosecond laser pulse. A transition from saturable absorption (SA) to reverse saturable absorption (RSA) was observed as the excitation intensity increasing. With good excellent nonlinear optical coefficient, the samples were expected to be the potential applications in optical devices.

  9. Phononic glass: a robust acoustic-absorption material.

    Science.gov (United States)

    Jiang, Heng; Wang, Yuren

    2012-08-01

    In order to achieve strong wide band acoustic absorption under high hydrostatic pressure, an interpenetrating network structure is introduced into the locally resonant phononic crystal to fabricate a type of phononic composite material called "phononic glass." Underwater acoustic absorption coefficient measurements show that the material owns high underwater sound absorption coefficients over 0.9 in 12-30 kHz. Moreover, the quasi-static compressive behavior shows that the phononic glass has a compressive strength over 5 MPa which is crucial for underwater applications.

  10. D-xylose absorption

    Science.gov (United States)

    ... this page: //medlineplus.gov/ency/article/003606.htm D-xylose absorption To use the sharing features on this page, please enable JavaScript. D-xylose absorption is a laboratory test to determine ...

  11. Relationship between Ballistic Coefficient and Static Mechanical Properties for Armor Materials

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The relationship between the ballistic coefficient and the static mechanical properties of armor materials was studied. The results show that the ballistic coefficient is determined by the strength, hardness and the toughness of materials. According to the Martel rule, the equation of the relationship between ballistic coefficient and static mechanical properties satisfies the following formula: . From the mixture law of composite, the prerequisite, for which ballistic coefficient has maximum to reinforcement volume fraction, is obtained by the following equation: .

  12. Aerosol Absorption Measurements in MILAGRO.

    Science.gov (United States)

    Gaffney, J. S.; Marley, N. A.; Arnott, W. P.; Paredes-Miranda, L.; Barnard, J. C.

    2007-12-01

    to carbonyl- and nitro- functional groups on conjugated and aromatic organic structures (e.g. PAH, and terpene derived products). Using 12-hour fine (0.1-1.0 micron) aerosol samples collected in the field on quartz filters, uv/vis and infrared spectra were obtained in the laboratory using integrating spheres and diffuse reflectance spectroscopy, respectively. An inter-comparison of the "real-time" measurements made by the photo-acoustic, aethalometer and MAAP techniques have been described. In addition, the in situ aethalometer (seven-channel) results are compared with continuous integrating sphere uv-visible spectra to examine the angstrom absorption coefficient variance. These results will be briefly overviewed and the specific posters detailing these results will be highlighted highlighted. This work was performed as part of the Department of Energy's Megacity Aerosol Experiment - Mexico City under the support of the Atmospheric Science Program. "This researchwas supported by the Office of Science (BER), U. S. Department of Energy, Grant No. DE-FG02-07ER64329.

  13. Disorder-induced enhancement of indirect absorption in a GeSn photodetector grown by molecular beam epitaxy

    Science.gov (United States)

    Li, H.; Chang, C.; Cheng, H. H.; Sun, G.; Soref, R. A.

    2016-05-01

    We report an investigation on the absorption mechanism of a GeSn photodetector with 2.4% Sn composition in the active region. Responsivity is measured and absorption coefficient is calculated. Square root of absorption coefficient linearly depends on photon energy indicating an indirect transition. However, the absorption coefficient is found to be at least one order of magnitude higher than that of most other indirect materials, suggesting that the indirect optical absorption transition cannot be assisted only by phonon. Our analysis of absorption measurements by other groups on the same material system showed the values of absorption coefficient on the same order of magnitude. Our study reveals that the strong enhancement of absorption for the indirect optical transition is the result of alloy disorder from the incorporation of the much larger Sn atoms into the Ge lattice that are randomly distributed.

  14. Anomalous absorption of laser light on ion acoustic fluctuations

    Science.gov (United States)

    Rozmus, Wojciech; Bychenkov, Valery Yu.

    2016-10-01

    Theory of laser light absorption due to ion acoustic turbulence (IAT) is discussed in high Z plasmas where ion acoustic waves are weakly damped. Our theory applies to the whole density range from underdense to critical density plasmas. It includes an absorption rate for the resonance anomalous absorption due to linear conversion of electromagnetic waves into electron plasma oscillations by the IAT near the critical density in addition to the absorption coefficient due to enhanced effective electron collisionality. IAT is driven by large electron heat flux through the return current instability. Stationary spectra of IAT are given by weak plasma turbulence theory and applied in description of the anomalous absorption in the inertial confinement fusion plasmas at the gold walls of a hohlraum. This absorption is anisotropic in nature due to IAT angular anisotropy and differs for p- and s-polarization of the laser radiation. Possible experiments which could identify the resonance anomalous absorption in a laser heated plasma are discussed.

  15. n-Alcohol/Water Partition Coefficients for Decachlorobiphenyl (PCB 209)

    Science.gov (United States)

    Measurements of n-octanol/water partition coefficients (Kow) for highly hydrophobic chemicals are extremely difficult and are rarely made, in part due to the large volumes of water typically needed to quantify these compounds in the aqueous phase. An extrapolation approach using ...

  16. n-Alcohol/Water Partition Coefficients for Decachlorobiphenyl (PCB 209)

    Science.gov (United States)

    Measurements of n-octanol/water partition coefficients (Kow) for highly hydrophobic chemicals are extremely difficult and are rarely made, in part due to the large volumes of water typically needed to quantify these compounds in the aqueous phase. An extrapolation approach using ...

  17. The Kauffman Constraint Coefficients Kw

    CERN Document Server

    Griggs, Kenneth A

    2011-01-01

    The Kauffman Constraint Coefficients Kw and their corresponding Elementals Ew are presented as solutions to the construction of the (beta)-derivative of Kauffman's Theta-function. Additionally, a new recursion relation is provided to construct the (beta)-derivative of Theta that requires only operational substitutions and summations; this algorithmically simplifies Kauffman's original technique. To demonstrate Kw, we generate the 30 Kw Coefficients from the corresponding Elementals Ew for the (9)-derivative of Theta and find that our results are in complete agreement with Kauffman's Mathematica\\texttrademark solutions. We further present a calculation of two coefficients for the (12)-derivative of Theta and invite readers to use Mathematica\\texttrademark or any other means to calculate and verify our results. Finally, we present a challenging calculation for a coefficient of the (40)-derivative of Theta; owing to the vast numbers of permutations involved, a Mathematica\\texttrademark approach may require subst...

  18. Kappa Coefficients for Circular Classifications

    NARCIS (Netherlands)

    Warrens, Matthijs J.; Pratiwi, Bunga C.

    2016-01-01

    Circular classifications are classification scales with categories that exhibit a certain periodicity. Since linear scales have endpoints, the standard weighted kappas used for linear scales are not appropriate for analyzing agreement between two circular classifications. A family of kappa coefficie

  19. Properties of Traffic Risk Coefficient

    Institute of Scientific and Technical Information of China (English)

    TANG Tie-Qiao; HUANG Hai-Jun; SHANG Hua-Yan; XUE Yu

    2009-01-01

    We use the model with the consideration of the traffic interruption probability (Physica A 387(2008)6845) to study the relationship between the traffic risk coefficient and the traffic interruption probability.The analytical and numerical results show that the traffic interruption probability will reduce the traffic risk coefficient and that the reduction is related to the density, which shows that this model can improve traffic security.

  20. Wrong Signs in Regression Coefficients

    Science.gov (United States)

    McGee, Holly

    1999-01-01

    When using parametric cost estimation, it is important to note the possibility of the regression coefficients having the wrong sign. A wrong sign is defined as a sign on the regression coefficient opposite to the researcher's intuition and experience. Some possible causes for the wrong sign discussed in this paper are a small range of x's, leverage points, missing variables, multicollinearity, and computational error. Additionally, techniques for determining the cause of the wrong sign are given.

  1. Segregation during crystal growth from melt and absorption cross section determination by optical absorption method

    Institute of Scientific and Technical Information of China (English)

    ZHANG QingLi; YIN ShaoTang; SUN DunLu; WAN SongMing

    2008-01-01

    Segregation during crystal growth from melt under two conditions is studied by using crystal mass, which can be measured easily, as an independent variable, and a method to determine the effective segregation coefficient and absorption cross section of optical dopant is given. When the segregated solute disperses into the whole or just a part of melt homogenously, the concentration Cs in solid interface will change by different formulas. If the crystal growth interface is conical and segregated solute disperses into melt in total or part, the solute concentration at r=2/3R, where r is the distance from the growth cross section center and R the crystal radius, is independent on the shape of the crystal growth interface, and its variation at r=2/3R can be regarded as the result from crystal growth in flat interface. With Cs variation formula in solid and absorption cross section σ for optical dopant, the absorption coefficients along the crystal growth direction can be calculated, and the corresponding experimental value can be obtained through the crystal optical absorption spectra. By minimizing the half sum, whose independent variables are k, △W or σ, of the difference square between the calculated and experimental absorp-tion coefficients from one or more absorption peaks along the crystal growth di-rection, k and σ, or k and △W, can be determined at the same time through the Levenberg-Marquardt iteration method. Finally, the effective segregation coefficient k, △W and absorption cross sections of Nd:GGG were determined, the results fitted by two formula gave more closed effective segregation coefficient, and the value △W also indicates that the segregated dopant had nearly dispersed into the whole melt. Experimental results show that the method to determine effective segregation coefficient k, △W and absorption cross sections σ is convenient and reliable, and the two segregation formulas can describe the segregation during the crystal growth from

  2. Segregation during crystal growth from melt and absorption cross section determination by optical absorption method

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Segregation during crystal growth from melt under two conditions is studied by using crystal mass,which can be measured easily,as an independent variable,and a method to determine the effective segregation coefficient and absorption cross section of optical dopant is given.When the segregated solute disperses into the whole or just a part of melt homogenously,the concentration CS in solid interface will change by different formulas.If the crystal growth interface is conical and segregated solute disperses into melt in total or part,the solute concentration at r=2/3R,where r is the distance from the growth cross section center and R the crystal radius,is independent on the shape of the crystal growth interface,and its variation at r=2/3R can be regarded as the result from crystal growth in flat interface.With CS variation formula in solid and absorption cross section σ for optical dopant,the absorption coefficients along the crystal growth direction can be calculated,and the corresponding experimental value can be obtained through the crystal optical absorption spectra.By minimizing the half sum,whose independent variables are k,ΔW or σ,of the difference square between the calculated and experimental absorp-tion coefficients from one or more absorption peaks along the crystal growth di-rection,k and σ,or k and ΔW,can be determined at the same time through the Levenberg-Marquardt iteration method.Finally,the effective segregation coefficient k,ΔW and absorption cross sections of Nd:GGG were determined,the results fitted by two formula gave more closed effective segregation coefficient,and the value ΔW also indicates that the segregated dopant had nearly dispersed into the whole melt.Experimental results show that the method to determine effective segregation coefficient k,ΔW and absorption cross sections σ is convenient and reliable,and the two segregation formulas can describe the segregation during the crystal growth from melt relatively commendably.

  3. Comprehensive analysis of the optical Kerr coefficient of graphene

    Science.gov (United States)

    Soh, Daniel B. S.; Hamerly, Ryan; Mabuchi, Hideo

    2016-08-01

    We present a comprehensive analysis of the nonlinear optical Kerr effect in graphene. We directly solve the S -matrix element to calculate the absorption rate, utilizing the Volkov-Keldysh-type crystal wave functions. We then convert to the nonlinear refractive index coefficients through the Kramers-Kronig relation. In this formalism, the source of Kerr nonlinearity is the interplay of optical fields that cooperatively drive the transition from valence to conduction band. This formalism makes it possible to identify and compute the rates of distinct nonlinear processes that contribute to the Kerr nonlinear refractive index coefficient. The four identified mechanisms are two-photon absorption, Raman transition, self-coupling, and quadratic ac Stark effect. We also present a comparison of our theory with recent experimental and theoretical results.

  4. On the Existence of Feller Semigroups with Discontinuous Coefficients

    Institute of Scientific and Technical Information of China (English)

    Kazuaki TAIRA

    2009-01-01

    This paper is devoted to the functional analytic approach to the problem of existence of Markov processes with Dirichlet boundary condition, oblique derivative boundary condition and first-order Wentzell boundary condition for second-order, uniformly elliptic differential operators with discontinuous coefficients. More precisely, we construct Feller semigroups associated with absorption,reflection, drift and sticking phenomena at the boundary. The approach here is distinguished by the Zygmund theory of singular integral operators with non-smooth kernels.

  5. Sound absorption of metallic sound absorbers fabricated via the selective laser melting process

    Science.gov (United States)

    Cheng, Li-Wei; Cheng, Chung-Wei; Chung, Kuo-Chun; Kam, Tai-Yan

    2017-01-01

    The sound absorption capability of metallic sound absorbers fabricated using the additive manufacturing (selective laser melting) method is investigated via both the experimental and theoretical approaches. The metallic sound absorption structures composed of periodic cubic cells were made of laser-melted Ti6Al4 V powder. The acoustic impedance equations with different frequency-independent and frequency-dependent end corrections factors are employed to calculate the theoretical sound absorption coefficients of the metallic sound absorption structures. The calculated sound absorption coefficients are in close agreement with the experimental results for the frequencies ranging from 2 to 13 kHz.

  6. [Study on lead absorption in pumpkin by atomic absorption spectrophotometry].

    Science.gov (United States)

    Li, Zhen-Xia; Sun, Yong-Dong; Chen, Bi-Hua; Li, Xin-Zheng

    2008-07-01

    A study was carried out on the characteristic of lead absorption in pumpkin via atomic absorption spectrophotometer. The results showed that lead absorption amount in pumpkin increased with time, but the absorption rate decreased with time; And the lead absorption amount reached the peak in pH 7. Lead and cadmium have similar characteristic of absorption in pumpkin.

  7. Transport coefficients of heavy baryons

    Science.gov (United States)

    Tolos, Laura; Torres-Rincon, Juan M.; Das, Santosh K.

    2016-08-01

    We compute the transport coefficients (drag and momentum diffusion) of the low-lying heavy baryons Λc and Λb in a medium of light mesons formed at the later stages of high-energy heavy-ion collisions. We employ the Fokker-Planck approach to obtain the transport coefficients from unitarized baryon-meson interactions based on effective field theories that respect chiral and heavy-quark symmetries. We provide the transport coefficients as a function of temperature and heavy-baryon momentum, and analyze the applicability of certain nonrelativistic estimates. Moreover we compare our outcome for the spatial diffusion coefficient to the one coming from the solution of the Boltzmann-Uehling-Uhlenbeck transport equation, and we find a very good agreement between both calculations. The transport coefficients for Λc and Λb in a thermal bath will be used in a subsequent publication as input in a Langevin evolution code for the generation and propagation of heavy particles in heavy-ion collisions at LHC and RHIC energies.

  8. Ozone absorption in a mechanically stirred reactor

    OpenAIRE

    LJILJANA TAKIC; VLADA VELJKOVIC; MIODRAG LAZIC; SRDJAN PEJANOVIC

    2007-01-01

    Ozone absorption in water was investigated in a mechanically stirred reactor, using both the semi-batch and continuous mode of operation. A model for the precise determination of the volumetric mass transfer coefficient in open tanks without the necessity of the measurement the ozone concentration in the outlet gas was developed. It was found that slow ozone reactions in the liquid phase, including the decomposition of ozone, can be regarded as one pseudo-first order reaction. Under the exami...

  9. Commercial absorption heat pumps (design, performance)

    Energy Technology Data Exchange (ETDEWEB)

    Lazzarin, R. (Padua Univ. (Italy). Ist. di Fisica Tecnica)

    1986-04-01

    After a historical review of the development of absorption heat pumps, a critical analysis is presented of the design and operation of typical 25-40 kW, commercially available heat pumps. This engineering critique is followed by an analysis of the performance of 25 kW plant thoroughly tested to provide, by means of statistically significant data, a reliable assessment of the coefficient of performance and capacity in function of the cold source temperature for different return temperatures.

  10. Volume Entropy

    CERN Document Server

    Astuti, Valerio; Rovelli, Carlo

    2016-01-01

    Building on a technical result by Brunnemann and Rideout on the spectrum of the Volume operator in Loop Quantum Gravity, we show that the dimension of the space of the quadrivalent states --with finite-volume individual nodes-- describing a region with total volume smaller than $V$, has \\emph{finite} dimension, bounded by $V \\log V$. This allows us to introduce the notion of "volume entropy": the von Neumann entropy associated to the measurement of volume.

  11. High temperature measurement of water vapor absorption

    Science.gov (United States)

    Keefer, Dennis; Lewis, J. W. L.; Eskridge, Richard

    1985-01-01

    An investigation was undertaken to measure the absorption coefficient, at a wavelength of 10.6 microns, for mixtures of water vapor and a diluent gas at high temperature and pressure. The experimental concept was to create the desired conditions of temperature and pressure in a laser absorption wave, similar to that which would be created in a laser propulsion system. A simplified numerical model was developed to predict the characteristics of the absorption wave and to estimate the laser intensity threshold for initiation. A non-intrusive method for temperature measurement utilizing optical laser-beam deflection (OLD) and optical spark breakdown produced by an excimer laser, was thoroughly investigated and found suitable for the non-equilibrium conditions expected in the wave. Experiments were performed to verify the temperature measurement technique, to screen possible materials for surface initiation of the laser absorption wave and to attempt to initiate an absorption wave using the 1.5 kW carbon dioxide laser. The OLD technique was proven for air and for argon, but spark breakdown could not be produced in helium. It was not possible to initiate a laser absorption wave in mixtures of water and helium or water and argon using the 1.5 kW laser, a result which was consistent with the model prediction.

  12. Aerosol optical absorption by dust and black carbon in Taklimakan Desert, during no-dust and dust-storm conditions

    Institute of Scientific and Technical Information of China (English)

    Hui Lu; Wenshou Wei; Mingzhe Liu; Weidong Gao; Xi Han

    2012-01-01

    Aerosol absorption coefficient σap involves the additive contribution of both black carbon aerosol (BC) and dust aerosol.The linear statistical regression analysis approach introduced by Fialho et al.(2005) is used to estimate the absorption exponents of BC and dust aerosol absorption coefficients,and further to separate the contributions of these two types of aerosols from the total light absorption coefficient measured in the hinterland of Taklimakan Desert in the spring of 2006.Absorption coefficients are measured by means of a 7-wavelength Aethalometer from 1 March to 31 May and from 1 November to 28 December,2006.The absorption exponent of BC absorption coefficient α is estimated as (-0.95 ±0.002) under background weather (supposing the observed absorption coefficient is due only to BC); the estimated absorption exponent of dust aerosol absorption coefficient β during the 6 dust storm periods (strong dust storm) is (-2.55 ± 0.009).Decoupling analysis of the measured light absorption coefficients demonstrates that,on average,the light absorptions caused by dust aerosol and BC make up about 50.5% and 49.5% respectively of the total light absorption at 520 nm; during dust weather process periods (dust storm,floating dust,blowing dust),the contribution of dust aerosol to absorption extinction is 60.6% on average; in the hinterland of desert in spring,dust aerosol is also the major contributor to the total aerosol light absorption,more than that of black carbon aerosol.

  13. Harmonic functions with varying coefficients

    Directory of Open Access Journals (Sweden)

    Jacek Dziok

    2016-05-01

    Full Text Available Abstract Complex-valued harmonic functions that are univalent and sense preserving in the open unit disk can be written in the form f = h + g ‾ $f=h+\\overline{g}$ , where h and g are analytic. In this paper we investigate some classes of univalent harmonic functions with varying coefficients related to Janowski functions. By using the extreme points theory we obtain necessary and sufficient convolution conditions, coefficients estimates, distortion theorems, and integral mean inequalities for these classes of functions. The radii of starlikeness and convexity for these classes are also determined.

  14. Super-Resonant Intracavity Coherent Absorption

    CERN Document Server

    Malara, P; Giorgini, A; Avino, S; De Natale, P; Gagliardi, G

    2016-01-01

    The capability of optical resonators to extend the effective radiation-matter interaction length originates from a multipass effect, hence is intrinsically limited by the resonator quality factor. Here, we show that this constraint can be overcome by combining the concepts of resonant interaction and coherent perfect absorption. We demonstrate and investigate super-resonant coherent absorption in a coupled Fabry-Perot-ring cavity structure. At the FP resonant wavelengths, the described phenomenon gives rise to split modes with a nearly-transparent peak and a peak whose transmission is exceptionally sensitive to the intracavity loss. For small losses, the effective interaction pathlength of these modes is proportional respectively to the ratio and the product of the individual finesse coefficients of the two resonators. The results presented extend the conventional definition of resonant absorption and point to a way of circumventing the technological limitations of ultrahigh-quality resonators in spectroscopy...

  15. Super-Resonant Intracavity Coherent Absorption

    Science.gov (United States)

    Malara, P.; Campanella, C. E.; Giorgini, A.; Avino, S.; de Natale, P.; Gagliardi, G.

    2016-07-01

    The capability of optical resonators to extend the effective radiation-matter interaction length originates from a multipass effect, hence is intrinsically limited by the resonator’s quality factor. Here, we show that this constraint can be overcome by combining the concepts of resonant interaction and coherent perfect absorption (CPA). We demonstrate and investigate super-resonant coherent absorption in a coupled Fabry-Perot (FP)/ring cavity structure. At the FP resonant wavelengths, the described phenomenon gives rise to split modes with a nearly-transparent peak and a peak whose transmission is exceptionally sensitive to the intracavity loss. For small losses, the effective interaction pathlength of these modes is proportional respectively to the ratio and the product of the individual finesse coefficients of the two resonators. The results presented extend the conventional definition of resonant absorption and point to a way of circumventing the technological limitations of ultrahigh-quality resonators in spectroscopy and optical sensing schemes.

  16. Irrational "Coefficients" in Renaissance Algebra.

    Science.gov (United States)

    Oaks, Jeffrey A

    2017-06-01

    Argument From the time of al-Khwārizmī in the ninth century to the beginning of the sixteenth century algebraists did not allow irrational numbers to serve as coefficients. To multiply by x, for instance, the result was expressed as the rhetorical equivalent of . The reason for this practice has to do with the premodern concept of a monomial. The coefficient, or "number," of a term was thought of as how many of that term are present, and not as the scalar multiple that we work with today. Then, in sixteenth-century Europe, a few algebraists began to allow for irrational coefficients in their notation. Christoff Rudolff (1525) was the first to admit them in special cases, and subsequently they appear more liberally in Cardano (1539), Scheubel (1550), Bombelli (1572), and others, though most algebraists continued to ban them. We survey this development by examining the texts that show irrational coefficients and those that argue against them. We show that the debate took place entirely in the conceptual context of premodern, "cossic" algebra, and persisted in the sixteenth century independent of the development of the new algebra of Viète, Decartes, and Fermat. This was a formal innovation violating prevailing concepts that we propose could only be introduced because of the growing autonomy of notation from rhetorical text.

  17. The HI absorption "Zoo"

    NARCIS (Netherlands)

    Geréb, K.; Maccagni, F. M.; Morganti, R.; Oosterloo, T. A.

    2015-01-01

    We present an analysis of the H I 21 cm absorption in a sample of 101 flux-selected radio AGN (S1.4 GHz> 50 mJy) observed with the Westerbork Synthesis Radio Telescope (WSRT). We detect H I absorption in 32 objects (30% of the sample). In a previous paper, we performed a spectral stacking analysis o

  18. Bioacoustic Absorption Spectroscopy

    Science.gov (United States)

    2016-06-07

    frequencies (Ching and Weston, 1971). RESULTS Measured resonance frequencies of absorption lines, which were attributed to adult (~ 1.3 khz) and juvenile ...of adult and juvenile sardines. These results suggest that bioacoustic absorption spectroscopy measurements permit isolation of juvenile from adult...from broadband tomographic transmission loss measurements over large areas . 2. Depths of sardines and contours of phytoplankton concentrations vs. time

  19. Nutrition and magnesium absorption.

    NARCIS (Netherlands)

    Brink, E.J.

    1992-01-01

    The influence of various nutrients present in dairy products and soybean-based products on absorption of magnesium has been investigated. The studies demonstrate that soybean protein versus casein lowers apparent magnesium absorption in rats through its phytate component. However, true magnesium abs

  20. In - line determination of heat transfer coefficients in a plate heat exchanger

    Science.gov (United States)

    Sotelo, S. Silva; Domínguez, R. J. Romero

    This paper shows an in - line determination of heat transfer coefficients in a plate heat exchanger. Water and aqueous working solution of lithium bromide + ethylene glycol are considered. Heat transfer coefficients are calculated for both fluids. "Type T" thermocouples were used for monitoring the wall temperature in a plate heat exchanger, which is one of the main components in an absorption system. Commercial software Agilent HP Vee Pro 7.5 was used for monitoring the temperatures and for the determination of the heat transfer coefficients. There are not previous works for heat transfer coefficients for the working solution used in this work.

  1. Calculation of self-diffusion coefficients in iron

    Directory of Open Access Journals (Sweden)

    Baohua Zhang

    2014-01-01

    Full Text Available On the basis of available P-V-T equation of state of iron, the temperature and pressure dependence of self-diffusion coefficients in iron polymorphs (α, δ, γ and ɛ phases have been successfully reproduced in terms of the bulk elastic and expansivity data by means of a thermodynamical model that interconnects point defects parameters with bulk properties. The calculated diffusion parameters, such as self-diffusion coefficient, activation energy and activation volume over a broad temperature range (500-2500 K and pressure range (0-100 GPa, compare favorably well with experimental or theoretical ones when the uncertainties are considered.

  2. Effect of morphology and solvent on two-photon absorption of nano zinc oxide

    Energy Technology Data Exchange (ETDEWEB)

    Kavitha, M.K. [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); Haripadmam, P.C.; Gopinath, Pramod; Krishnan, Bindu [Department of Physics, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); John, Honey, E-mail: honey@iist.ac.in [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India)

    2013-05-15

    Highlights: ► ZnO nanospheres and triangular structures synthesis by novel precipitation technique. ► The effect of precursor concentration on the size and shape of nano ZnO. ► Open aperture Z-scan measurements of the ZnO nanoparticle dispersions. ► Nanospheres exhibit higher two photon absorption coefficient than triangular nanostructures. ► Nanospheres dispersed in water exhibit higher two photon absorption coefficient than its dispersion in 2-propanol. - Abstract: In this paper, we report the effect of morphology and solvent on the two-photon absorption of nano zinc oxide. Zinc oxide nanoparticles in two different morphologies like nanospheres and triangular nanostructures are synthesized by novel precipitation technique and their two-photon absorption coefficient is measured using open aperture Z-scan technique. Experimental results show that the zinc oxide nanospheres exhibit higher two-photon absorption coefficient than the zinc oxide triangular nanostructures. The zinc oxide nanospheres dispersed in water exhibit higher two-photon absorption coefficient than that of its dispersion in 2-propanol. The zinc oxide nanospheres dispersed in water shows a decrease in two-photon absorption coefficient with an increase in on-axis irradiance. The result confirms the dependence of shape and solvent on the two-photon absorption of nano zinc oxide.

  3. [Study on cadmium absorption in pumpkin by atomic absorption spectrophotometry].

    Science.gov (United States)

    Li, Zhen-Xia; Jing, Rui-Jun; Dong, Wei-Hua; Li, Xin-Zheng; Liu, Hong

    2006-08-01

    A study was carried out on the characteristic of cadmium absorption in pumpkin by atomic absorption spectrophotometer. The results show that the cadmium absorption amount in pumpkin increased with the increase in cadmium concentration. Meanwhile the cadmium absorption amount in pumpkin increased with time. Eight hours after being cultured in the liquid, the cadmium absorption amount became saturated. The cadmium absorption rate reached the peak after 2 hours, then the absorption rate gradually reduced. The cadmium absorption amount in pumpkin is less in acid or alkali compared with neutral condition. And the absorption amount became minimum in pH 3, while maximum in pH 7.

  4. Prediction of acoustic absorption performance of a perforated plate with air jets

    Science.gov (United States)

    Hamakawa, Hiromitsu; Miyazaki, Masanori; Asai, Yuta; Kurihara, Eru; Nishida, Eiichi; Hayashi, Hidechito

    2017-08-01

    The present study focuses on the prediction of acoustic absorption performance of a perforated plate with air jets by theoretical calculations. In addition, we experimentally measured the flow rate, internal pressure, acoustic pressure, and transfer function using an acoustic impedance tube. The normal incidence absorption coefficient was calculated from the measured transfer function using transfer function methods. We investigated the influences of background air space, flow velocity, thickness, aperture rate, and aperture diameter of a perforated plate on the acoustic absorption characteristics. The frequency characteristics of the acoustic absorption coefficient showed a maximum value at a local frequency. As the background air space increased, the peak frequency of acoustic absorption characteristics decreased. As the flow velocity passing through the apertures increased, the peak level of the acoustic absorption coefficient also increased. The theoretical results agreed well with the experimental ones qualitatively.

  5. Moisture Absorption Model of Composites Considering Water Temperature Effect

    Directory of Open Access Journals (Sweden)

    HUI Li

    2016-11-01

    Full Text Available The influence of water temperature on composite moisture absorption parameters was investigated in temperature-controlled water bath. Experiments of carbon fiber/bismaleimide resin composites immersed in water of 60℃, 70℃and 80℃ were developed respectively. According to the moisture content-time curves obtained from the experimental results, the diffusion coefficient and the balanced moisture content of the composites immersed in different water temperature could be calculated. What's more, the effect of water temperature on the diffusion coefficient and the balanced moisture content were discussed too. According to the Arrhenius equation and the law of Fick, a moisture absorption model was proposed to simulate the hygroscopic behaviour of the composite laminates immersed in different water temperature which can predict the absorption rate of water of the composites immersed in distilled water of 95℃ at any time precisely and can calculate how long it will take to reach the specific absorption rate.

  6. INVESTIGATION ON SOUND ABSORPTION PROPERTIES OF KAPOK FIBERS

    Institute of Scientific and Technical Information of China (English)

    Hai-fan Xiang; Dong Wang; Hui-chao Liu; Ning Zhao; Jian Xu

    2013-01-01

    Sound absorption properties of natural kapok fibers have been investigated.Kapok fibrous assemblies with different bulk density,thickness,fiber length and orientation were manufactured,and their acoustical performances were evaluated by using an impedance tube instrument.Results show that the kapok fiber has excellent acoustical damping performance due to its natural hollow structure,and the sound absorption coefficients of kapok fibrous assemblies are significantly affected by the bulk density,thickness and arrangement of kapok fibers but less dependent on the fiber length.Compared with assemblies of commercial glass wool and degreasing cotton fibers,the kapok fiber assemblies with the same thickness but much smaller bulk density may have the similar sound absorption coefficients.Theoretical modelling of the acoustical damping performance of kapok fibers shows a good agreement with the experimental data.All the results demonstrate that kapok fiber is a promising light and environment-friendly sound absorption material.

  7. An in silico skin absorption model for fragrance materials.

    Science.gov (United States)

    Shen, Jie; Kromidas, Lambros; Schultz, Terry; Bhatia, Sneha

    2014-12-01

    Fragrance materials are widely used in cosmetics and other consumer products. The Research Institute for Fragrance Materials (RIFM) evaluates the safety of these ingredients and skin absorption is an important parameter in refining systemic exposure. Currently, RIFM's safety assessment process assumes 100% skin absorption when experimental data are lacking. This 100% absorption default is not supportable and alternate default values were proposed. This study aims to develop and validate a practical skin absorption model (SAM) specific for fragrance material. It estimates skin absorption based on the methodology proposed by Kroes et al. SAM uses three default absorption values based on the maximum flux (J(max)) - namely, 10%, 40%, and 80%. J(max) may be calculated by using QSAR models that determine octanol/water partition coefficient (K(ow)), water solubility (S) and permeability coefficient (K(p)). Each of these QSAR models was refined and a semi-quantitative mechanistic model workflow is presented. SAM was validated with a large fragrance-focused data set containing 131 materials. All resulted in predicted values fitting the three-tiered absorption scenario based on Jmax ranges. This conservative SAM may be applied when fragrance material lack skin absorption data. Copyright © 2014 Elsevier Ltd. All rights reserved.

  8. Sustainable Absorption Panels from Agricultural Wastes

    Directory of Open Access Journals (Sweden)

    Ismail F.Z.

    2014-01-01

    Full Text Available Noise has become a serious environmental problem and there are demands for alternative sustainable materials which capable to reduce the noise level at various frequency ranges. Therefore, the aim of this research is to study the potential of turning the agricultural waste and waste paper into a sound absorption panel. For the purpose of this study, combination of two materials was under studied; coconut coir fibre from agriculture waste and shredded waste paper from the office. There were two main objective of the research; first is to develop absorption panels from coconut coir powder that available locally with a combination of shredded paper at different percentage of mixture. Second objective is to identify the absorption rate of the panels. The study encompasses the fabrication of the particle board using the coconut husk powder mix with shredded waste paper and using the gypsum powder as the binder for the two materials. Four acoustic panels of size 0.5m x 0.5m and 0.012 m thick were fabricated with different mix ratio; 25% of coconut coir powder mixed with 75% of shredded waste papers for sample 1, 50% both of the material for sample 2, 75% of coconut coir powder mixed with 25% of shredded waste paper for sample 3, and lastly 100% of coconut coir powder for sample 4. The absorption coefficient of the panels was tested in a reverberation chamber and in accordance with ISO 354:1985 standards. Based on the results, sample 1 gave the highest absorption coefficient compared to sample 2, 3 and 4. It can be concluded that the acoustic panel made from a mixture of 25% coconut coir powder with 75% shredded waste paper provided higher absorption coefficient compared to the performance of the other samples. This might be caused by the size of the coir powder which is very small, creating less void space in between the panel and thus causing it to absorb less sound. Since sound absorption is very much affected by the availability of void space of

  9. Study of Dispersion Coefficient Channel

    Science.gov (United States)

    Akiyama, K. R.; Bressan, C. K.; Pires, M. S. G.; Canno, L. M.; Ribeiro, L. C. L. J.

    2016-08-01

    The issue of water pollution has worsened in recent times due to releases, intentional or not, of pollutants in natural water bodies. This causes several studies about the distribution of pollutants are carried out. The water quality models have been developed and widely used today as a preventative tool, ie to try to predict what will be the concentration distribution of constituent along a body of water in spatial and temporal scale. To understand and use such models, it is necessary to know some concepts of hydraulic high on their application, including the longitudinal dispersion coefficient. This study aims to conduct a theoretical and experimental study of the channel dispersion coefficient, yielding more information about their direct determination in the literature.

  10. Clustering Coefficients in Multiplex Networks

    CERN Document Server

    Cozzo, Emanuele; De Domenico, Manlio; Solé, Albert; Arenas, Alex; Gómez, Sergio; Porter, Mason A; Moreno, Yamir

    2013-01-01

    Recent advances in the study of complex networked systems has highlighted that our interconnected world is made of networks that are coupled together through different layers that each stand for one type of interaction or system. Despite this situation, it is traditional to aggregate multiplex data into a single weighted network in order take advantage of existing tools. This is admittedly convenient, but it is also extremely problematic. In this paper, we generalize the concept of clustering coefficients for multiplex networks. We show how the layered structure of multiplex networks introduces a new degree of freedom that has a fundamental effect on transitivity. We compute our new multiplex clustering coefficients for several real multiplex networks and illustrate why generalizing monoplex concepts to multiplex networks must be done with great care.

  11. Quasar Absorption Studies

    Science.gov (United States)

    Mushotzky, Richard (Technical Monitor); Elvis, Martin

    2004-01-01

    The aim of the proposal is to investigate the absorption properties of a sample of inter-mediate redshift quasars. The main goals of the project are: Measure the redshift and the column density of the X-ray absorbers; test the correlation between absorption and redshift suggested by ROSAT and ASCA data; constrain the absorber ionization status and metallicity; constrain the absorber dust content and composition through the comparison between the amount of X-ray absorption and optical dust extinction. Unanticipated low energy cut-offs where discovered in ROSAT spectra of quasars and confirmed by ASCA, BeppoSAX and Chandra. In most cases it was not possible to constrain adequately the redshift of the absorber from the X-ray data alone. Two possibilities remain open: a) absorption at the quasar redshift; and b) intervening absorption. The evidences in favour of intrinsic absorption are all indirect. Sensitive XMM observations can discriminate between these different scenarios. If the absorption is at the quasar redshift we can study whether the quasar environment evolves with the Cosmic time.

  12. Absorption and scattering 2-D volcano images from numerically calculated space-weighting functions

    Science.gov (United States)

    Del Pezzo, Edoardo; Ibañez, Jesus; Prudencio, Janire; Bianco, Francesca; De Siena, Luca

    2016-08-01

    Short-period small magnitude seismograms mainly comprise scattered waves in the form of coda waves (the tail part of the seismogram, starting after S waves and ending when the noise prevails), spanning more than 70 per cent of the whole seismogram duration. Corresponding coda envelopes provide important information about the earth inhomogeneity, which can be stochastically modeled in terms of distribution of scatterers in a random medium. In suitable experimental conditions (i.e. high earth heterogeneity), either the two parameters describing heterogeneity (scattering coefficient), intrinsic energy dissipation (coefficient of intrinsic attenuation) or a combination of them (extinction length and seismic albedo) can be used to image Earth structures. Once a set of such parameter couples has been measured in a given area and for a number of sources and receivers, imaging their space distribution with standard methods is straightforward. However, as for finite-frequency and full-waveform tomography, the essential problem for a correct imaging is the determination of the weighting function describing the spatial sensitivity of observable data to scattering and absorption anomalies. Due to the nature of coda waves, the measured parameter couple can be seen as a weighted space average of the real parameters characterizing the rock volumes illuminated by the scattered waves. This paper uses the Monte Carlo numerical solution of the Energy Transport Equation to find approximate but realistic 2-D space-weighting functions for coda waves. Separate images for scattering and absorption based on these sensitivity functions are then compared with those obtained with commonly used sensitivity functions in an application to data from an active seismic experiment carried out at Deception Island (Antarctica). Results show that these novel functions are based on a reliable and physically grounded method to image magnitude and shape of scattering and absorption anomalies. Their

  13. Absorption of ultrasound waves during dynamic processes in disperse systems

    Science.gov (United States)

    Kol'tsova, I. S.; Khomutova, A. S.

    2016-11-01

    Measurements of ultrasound wave absorption are conducted at a frequency of 3 MHz in 3% suspensions of starch, gelatin, and lactose. It is shown that the dynamics of the additional ultrasound wave absorption coefficient in the suspensions carries information on the processes of swelling, dissolution, and the phase and structural periods occurring in the interaction of the disperse and dispersoid phases; it also reflects the influence of the temperature field on these processes.

  14. Transient Intersubband Optical Absorption in Double Quantum Well Structure

    Institute of Scientific and Technical Information of China (English)

    WU Bin-He

    2005-01-01

    The microscopic equations of motion including many-body effects are derived to study the intersubband polarization in the double quantum well structure induced by an ultrafast pumping infrared light. Based on the selfconsistent field theory, the transient probe absorption coefficient is calculated. These calculations are beyond the previous steady-state assumption. Transient probe absorption spectra are calculated under different pumping intensity and various pump probe delay.

  15. Low-Absorption Liquid Crystals for Infrared Beam Steering

    Science.gov (United States)

    2015-09-30

    absorption coefficient and d is the LC layer thickness . Let us take a~!0/cm as an example. For a 10-|j,m- thick LC layer, ad=0.01 and the transmittance...remains 99%. However, if the LC layer thickness (or effective optical path length) increases, then the absorption will increase exponentially, as Eq. (1...weight-and-power, 2) increasing mean-time-between- failure, and 3) reducing system complexity. Beam steering based on liquid crystal ( LC ) optical phase

  16. Thin-film limit formalism applied to surface defect absorption

    OpenAIRE

    Holovsky, Jakub; Ballif, Christophe

    2014-01-01

    The thin-film limit is derived by a nonconventional approach and equations for transmittance, reflectance and absorptance are presented in highly versatile and accurate form. In the thin-film limit the optical properties do not depend on the absorption coefficient, thickness and refractive index individually, but only on their product. We show that this formalism is applicable to the problem of ultrathin defective layer e. g. on a top of a layer of amorphous silicon. We develop a new method o...

  17. Absorption of water and lubricating oils into porous nylon

    Science.gov (United States)

    Bertrand, P. A.

    1995-01-01

    Oil and water absorption from air into sintered porous nylon can be described by infiltration into the pores of the material. This process can be modeled by a diffusion-like mechanism. For water absorption, we find a formal diffusion coefficient of 1.5 x 10(exp -4)sq cm/min when the nylon is initially dry. The diffusion coefficient is 4 x 10(exp -6)sq cm/min when the nylon is oil-impregnated prior to air exposure. In a 52% RH atmosphere, dry nylon absorbs 3% w/w water, and oil-impregnated nylon absorbs 0.6% w/w water. For oil absorption there are three steps: (1) surface absorption and infiltration into (2) larger and (3) smaller pores. Surface absorption is too fast to be measured in these experiments. The diffusion coefficient for the second step is 6 x 10(exp -4)sq cm/min for SRG-60 oil into dry nylon and 4 x 10(exp -4)sq cm/min for air-equilibrated nylon. The diffusion coefficient for the third step is about 1 x 10(exp -6)sq cm/min for both cases. The total amount of oil absorbed is 31% w/w. The interaction between water and nylon is not as strong as that between water and cotton-phenolic: oil can replace water, and only a small amount of water can enter previously oil-impregnated nylon.

  18. Second virial coefficient of maltodextrin

    Science.gov (United States)

    Wohlfarth, Ch.

    This document is part of Subvolume D2 'Polymer Solutions - Physical Properties and their Relations I (Thermodynamic Properties: PVT -Data and miscellaneous Properties of polymer Solutions) of Volume 6 `Polymers' of Landolt-Börnstein - Group VIII `Advanced Materials and Technologies'.

  19. Dependence of the coefficient of ultrasonic velocity on the coefficient of free length in organic liquids

    Institute of Scientific and Technical Information of China (English)

    LU Yigang; PENG Jianxin; TONG Jie; DONG Yanwu

    2000-01-01

    On the basis of Jacobson's free length theory and the theory of pressure coefficient and temperature coefficient of free length in liquids, the relationship between the pressure coefficient of ultrasonic velocity and the pressure coefficient of free length, and the relationship between the temperature coefficient of ultrasonic velocity and the temperature coefficient of free length were studied. Relevant equations were given, and the pressure coefficient and temperature coefficient of ultrasonic velocity were calculated, which are in agreement with the measured values.

  20. Epidermal melanin absorption in human skin

    Science.gov (United States)

    Norvang Nilsen, Lill T.; Fiskerstrand, Elisanne J.; Nelson, J. Stuart; Berns, Michael W.; Svaasand, Lars O.

    1996-01-01

    The principle of laser induced selective photothermolysis is to induced thermal damage to specific targets in such a manner that the temperature of the surrounding tissue is maintained below the threshold for thermal damage. The selectivity is obtained by selection of a proper wavelength and pulse duration. The technique is presently being used in the clinic for removal of port-wine stains. The presence of melanin in the epidermal layer can represent a limitation to the selectivity. Melanin absorption drops off significantly with increasing wavelength, but is significant in the entire wavelength region where the blood absorption is high. Treatment of port-wine stain in patients with high skin pigmentation may therefore give overheating of the epidermis, resulting in epidermal necrosis. Melanosomal heating is dependent on the energy and duration of the laser pulse. The heating mechanism for time scales less than typically 1 microsecond(s) corresponds to a transient local heating of the individual melanosomes. For larger time scales, heat diffusion out of the melanosomes become of increased importance, and the temperature distribution will reach a local steady state condition after typically 10 microsecond(s) . For even longer pulse duration, heat diffusing from neighboring melanosomes becomes important, and the temperature rise in a time scale from 100 - 500 microsecond(s) is dominated by this mechanism. The epidermal heating during the typical 450 microsecond(s) pulse used for therapy is thus dependent on the average epidermal melanin content rather than on the absorption coefficient of the individual melanosomes. This study will present in vivo measurements of the epidermal melanin absorption of human skin when exposed to short laser pulses (< 0.1 microsecond(s) ) from a Q-switched ruby laser and with long laser pulses (approximately 500 microsecond(s) ) from a free-running ruby laser or a long pulse length flashlamp pumped dye laser. The epidermal melanin

  1. Soliton absorption spectroscopy

    CERN Document Server

    Kalashnikov, V L

    2010-01-01

    We analyze optical soliton propagation in the presence of weak absorption lines with much narrower linewidths as compared to the soliton spectrum width using the novel perturbation analysis technique based on an integral representation in the spectral domain. The stable soliton acquires spectral modulation that follows the associated index of refraction of the absorber. The model can be applied to ordinary soliton propagation and to an absorber inside a passively modelocked laser. In the latter case, a comparison with water vapor absorption in a femtosecond Cr:ZnSe laser yields a very good agreement with experiment. Compared to the conventional absorption measurement in a cell of the same length, the signal is increased by an order of magnitude. The obtained analytical expressions allow further improving of the sensitivity and spectroscopic accuracy making the soliton absorption spectroscopy a promising novel measurement technique.

  2. Absorption heat pump system

    Science.gov (United States)

    Grossman, G.

    1982-06-16

    The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

  3. Zeeman atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Hadeishi, T.; McLaughlin, R.

    1978-08-01

    The design and development of a Zeeman atomic absorption spectrometer for trace element analysis are described. An instruction manual is included which details the operation, adjustment, and maintenance. Specifications and circuit diagrams are given. (WHK)

  4. Revisiting Absorptive Capacity

    DEFF Research Database (Denmark)

    de Araújo, Ana Luiza Lara; Ulhøi, John Parm; Lettl, Christopher

    Absorptive capacity has mostly been perceived as a 'passive' outcome of R&D investments. Recently, however, a growing interest into its 'proactive' potentials has emerged. This paper taps into this development and proposes a dynamic model for conceptualizing the determinants of the complementary...... learning processes of absorptive capacity, which comprise combinative and adaptive capabilities. Drawing on survey data (n=169), the study concludes that combinative capabilities primarily enhance transformative and exploratory learning processes, while adaptive capabilities strengthen all three learning...

  5. Revisiting Absorptive Capacity

    DEFF Research Database (Denmark)

    de Araújo, Ana Luiza Lara; Ulhøi, John Parm; Lettl, Christopher

    Absorptive capacity has mostly been perceived as a 'passive' outcome of R&D investments. Recently, however, a growing interest into its 'proactive' potentials has emerged. This paper taps into this development and proposes a dynamic model for conceptualizing the determinants of the complementary...... learning processes of absorptive capacity, which comprise combinative and adaptive capabilities. Drawing on survey data (n=169), the study concludes that combinative capabilities primarily enhance transformative and exploratory learning processes, while adaptive capabilities strengthen all three learning...

  6. Fluctuation of Ultrafiltration Coefficient of Hemodialysis Membrane During Reuse

    Science.gov (United States)

    Arif, Idam; Christin

    2010-12-01

    Hemodialysis treatment for patient with kidney failure is to regulate body fluid and to excrete waste products of metabolism. The patient blood and the dialyzing solution (dialysate) are flowed counter currently in a dialyzer to allow volume flux of fluid and diffusion of solutes from the blood to the dialysate through a semipermiable membrane. The volume flux of fluid depends on the hydrostatic and the osmotic pressure difference between the blood and the dialysate. It also depends on the membrane parameter that represents how the membrane allows the fluid and the solutes to move across as a result of the pressure difference, known as the ultrafiltration coefficient Kuf. The coefficient depends on the number and the radius of membrane pores for the movement of the fluids and the solutes across the membrane. The measured membrane ultrafiltration coefficient of reused dialyzer shows fluctuation between one uses to another without any significant trend of change. This indicates that the cleaning process carried out before reuse does not cause perfect removal of clots that happen in the previous use. Therefore the unblocked pores are forced to work hardly to obtain targeted volume flux in a certain time of treatment. This may increase the unblocked pore radius. Reuse is stopped when there is indication of blood leakage during the hemodialysis treatment.

  7. Estimation of liquid volume fraction using ultrasound transit time spectroscopy

    Science.gov (United States)

    Al-Qahtani, Saeed M.; Langton, Christian M.

    2016-12-01

    It has recently been proposed that the propagation of an ultrasound wave through complex structures, consisting of two-materials of differing ultrasound velocity, may be considered as an array of parallel ‘sonic rays’, the transit time of each determined by their relative proportion; being a minimum (t min) in entire higher velocity material, and a maximum (t max) in entire lower velocity material. An ultrasound transit time spectrum (UTTS) describes the proportion of sonic rays at an individual transit time. It has previously been demonstrated that the solid volume fraction of a solid:liquid composite, specifically acrylic step-wedges immersed in water, may be reliably estimated from the UTTS. The aim of this research was to investigate the hypothesis that the volume fraction of a two-component liquid mixture, of unequal ultrasound velocity, may also be estimated by UTTS. A through-transmission technique incorporating two 1 MHz ultrasound transducers within a horizontally-aligned cylindrical tube-housing was utilised, the proportion of silicone oil to water being varied from 0% to 100%. The liquid volume fraction was estimated from the UTTS at each composition, the coefficient of determination (R 2%) being 98.9  ±  0.7%. The analysis incorporated a novel signal amplitude normalisation technique to compensate for absorption within the silicone oil. It is therefore envisaged that the parallel sonic ray concept and the derived UTTS may be further applied to the quantification of liquid mixture composition assessment.

  8. Anomalous absorption and reflection in ionospheric radio modification experiments

    Science.gov (United States)

    Mjolhus, E.

    1985-05-01

    The anomalous absorption of an ordinary polarized radio wave due to magnetic field aligned short-scale striations is studied. By the method of averaging, a correction term to the cold plasma dielectric tensor can be derived. The correction term behaves singularly at the upper hybrid level, inducing new cutoff and resonance. A situation analogous to the Budden tunneling problem arises. Thus the anomalous absorption is necessarily accompanied by partial reflection at the upper hybrid level. A consequence is that the absorption coefficient has a maximum at a certain striation intensity, with reflection dominating at higher intensities. This is expected to be important for the saturation of the process generating the striations.

  9. Measuring small absorptions exploiting photo-thermal self-phase modulation

    CERN Document Server

    Lastzka, Nico; Steinlechner, Sebastian; Schnabel, Roman

    2010-01-01

    We present a method for the measurement of small optical absorption coefficients. The method exploits the deformation of cavity Airy peaks that occur if the cavity contains an absorbing material with a non-zero thermo-refractive coefficient dn/dT or a non-zero expansion coefficient ath . Light absorption leads to a local temperature change and to an intensity-dependent phase shift, i.e. to a photo-thermal self-phase modulation. The absorption coefficient is derived from a comparison of time-resolved measurements with a numerical time-domain simulation applying a Markov-chain Monte-Carlo (MCMC) algorithm. We apply our method to the absorption coefficient of lithium niobate (LN) doped with 7mol% magnesium oxide (MgO) and derive a value of alphaLN = (5.9 +/- 0.9) *10^-4/cm . Our method should also apply to materials with much lower absorption coefficients. Based on our modelling we estimate that with cavity finesse values of the order 10^4, absorption coefficients of as low as 10^-8 /cm can be measured.

  10. Acoustic absorption behaviour of an open-celled aluminium foam

    CERN Document Server

    Han Fu Sheng; Zhao Yu Yuan; Gibbs, B

    2003-01-01

    Metal foams, especially close-celled foams, are generally regarded as poor sound absorbers. This paper studies the sound absorption behaviour of the open-celled Al foams manufactured by the infiltration process, and the mechanisms involved. The foams show a significant improvement in sound absorption compared with close-celled Al foams, because of their high flow resistance. The absorption performance can be further enhanced, especially at low frequencies, if the foam panel is backed by an appropriate air gap. Increasing the air-gap depth usually increases both the height and the width of the absorption peak and shifts the peak towards lower frequencies. The foam samples with the smallest pore size exhibit the best absorption capacities when there is no air gap, whereas those with medium pore sizes have the best overall performance when there is an air gap. The typical maximum absorption coefficient, noise reduction coefficient and half-width of the absorption peak are 0.96-0.99, 0.44-0.62 and 1500-3500 Hz, r...

  11. Pilot study: Exposure and materiality of the secondary room and its impact in the impulse response of coupled-volume concert halls

    Science.gov (United States)

    Ermann, Michael; Johnson, Marty E.

    2002-05-01

    What does one room sound like when it is partially exposed to another (acoustically coupled)? More specifically, this research aims to quantify how operational and design decisions impact aural impressions in the design of concert halls with acoustical coupling. By adding a second room to a concert hall, and designing doors to control the sonic transparency between the two rooms, designers can create a new, coupled acoustic. Concert halls use coupling to achieve a variable, longer, and distinct reverberant quality for their musicians and listeners. For this study, a coupled-volume shoebox concert hall was conceived with a fixed geometric volume, form, and primary-room sound absorption. Aperture size and secondary-room sound-absorption levels were established as variables. Statistical analysis of sound decay in this simulated hall suggests a highly sensitive relationship between the double-sloped condition and (1) Architectural composition, as defined by the aperture size exposing the chamber and (2) Materiality, as defined by the sound absorbance in the coupled volume. Preliminary calculations indicate that the double-sloped sound decay condition only appears when the total aperture area is less than 1.5% of the total shoebox surface area and the average absorption coefficient of the coupled volume is less than 0.07.

  12. Net Emission Coefficients for Copper and Iron Plasmas

    Science.gov (United States)

    Kassubek, Frank; Zilberberg, Oded; Doiron, Charles

    2016-09-01

    Radiative heat transfer is an important mechanism for heat transport in electrical arcs, e.g. in electrical switchgear. An exact description of this phenomenon is important (i) for the energy balance of the arc itself, and (ii) for the estimate of the escaping radiation that leads to evaporation of polymer nozzles; the evaporated material and its flow have a strong effect on the arcs. For low voltage arcs, the plasma composition within the arc is dominated by the contact material. In the present study, we compare copper and iron. Especially, we discuss the calculation of absorption and emission spectra and their characterisation by net emission coefficients. The latter describe well the effective power balance at the centre of the arc. We show that in addition to the net emission coefficients, it is important to characterise the radiation that is emitted from the arc core.

  13. Water sorption and diffusion coefficient through an experimental dental resin.

    Science.gov (United States)

    Costella, A M; Trochmann, J L; Oliveira, W S

    2010-01-01

    Polymeric composites have been widely used as dental restorative materials. A fundamental knowledge and understanding of the behavior of these materials in the oral cavity is essential to improve their properties and performance. In this paper we computed the data set of water absorption through an experimental dental resin blend using specimen discs of different thicknesses to estimate the diffusion coefficient. The resins were produced using Bisphenol A glycol dimethacrylate, Bisphenol A ethoxylated dimethacrylate and Triethylene glycol dimethacrylate monomers. The water sorption test method was based on International Standard ISO 4049 "Dentistry-Polymer-based filling materials". Results show a diffusion coefficient around 6.38 x 10(-8) cm(2)/s, within a variance of 0.01%, which is in good agreement with the values reported in the literature and represents a very suitable value.

  14. Central cooling: absorptive chillers

    Energy Technology Data Exchange (ETDEWEB)

    Christian, J.E.

    1977-08-01

    This technology evaluation covers commercially available single-effect, lithium-bromide absorption chillers ranging in nominal cooling capacities of 3 to 1,660 tons and double-effect lithium-bromide chillers from 385 to 1,060 tons. The nominal COP measured at operating conditions of 12 psig input steam for the single-effect machine, 85/sup 0/ entering condenser water, and 44/sup 0/F exiting chilled-water, ranges from 0.6 to 0.65. The nominal COP for the double-effect machine varies from 1.0 to 1.15 with 144 psig entering steam. Data are provided to estimate absorption-chiller performance at off-nominal operating conditions. The part-load performance curves along with cost estimating functions help the system design engineer select absorption equipment for a particular application based on life-cycle costs. Several suggestions are offered which may be useful for interfacing an absorption chiller with the remaining Integrated Community Energy System. The ammonia-water absorption chillers are not considered to be readily available technology for ICES application; therefore, performance and cost data on them are not included in this evaluation.

  15. Kerr nonlinearity and multi-photon absorption in germanium at mid-infrared wavelengths

    Science.gov (United States)

    Sohn, B.-U.; Monmeyran, C.; Kimerling, L. C.; Agarwal, A. M.; Tan, D. T. H.

    2017-08-01

    Multiphoton absorption coefficients and nonlinear refractive indices of germanium in the near and mid-infrared (2-5 μm) are reported. The nonlinear coefficients are measured by open and closed aperture Z-scan with 150 fs pulses at a repetition rate of 1 kHz. The nonlinear refractive index of Ge has a peak value of 9.1 ×10-5cm2/GW at a wavelength of 3 μm. The effect of free electrons generated by multiphoton absorption is discussed by investigating the variation of multiphoton absorption coefficients at different input powers. Kramers-Kronig relations are also discussed with regard to the relationship between nonlinear refractive index and two photon absorption coefficient.

  16. Gamma ray attenuation coefficient measurement for neutron-absorbent materials

    Energy Technology Data Exchange (ETDEWEB)

    Jalali, Majid [Isfahan Nuclear Science and Technology Research Institute (NSTRT), Reactor and Accelerators Research and Development School, Atomic Energy Organization (Iran, Islamic Republic of)], E-mail: m_jalali@entc.org.ir; Mohammadi, Ali [Faculty of Science, Department of Physics, University of Kashan, Km. 6, Ravand Road, Kashan (Iran, Islamic Republic of)

    2008-05-15

    The compounds Na{sub 2}B{sub 4}O{sub 7}, H{sub 3}BO{sub 3}, CdCl{sub 2} and NaCl and their solutions attenuate gamma rays in addition to neutron absorption. These compounds are widely used in the shielding of neutron sources, reactor control and neutron converters. Mass attenuation coefficients of gamma related to the four compounds aforementioned, in energies 662, 778.9, 867.38, 964.1, 1085.9, 1173, 1212.9, 1299.1,1332 and 1408 keV, have been determined by the {gamma} rays transmission method in a good geometry setup; also, these coefficients were calculated by MCNP code. A comparison between experiments, simulations and Xcom code has shown that the study has potential application for determining the attenuation coefficient of various compound materials. Experiment and computation show that H{sub 3}BO{sub 3} with the lowest average Z has the highest gamma ray attenuation coefficient among the aforementioned compounds.

  17. Multiple scattering of polarized light: influence of absorption.

    Science.gov (United States)

    Hohmann, A; Voit, F; Schäfer, J; Kienle, A

    2014-06-07

    This work continues previous research about multiple scattering of polarized light propagation in turbid media, putting emphasis on the imaginary part of the scatterers' complex refractive index. The whole angle-dependent Müller matrix is evaluated by comparing results of a polarization sensitive radiative transfer solution to Maxwell theory. Turbid media of defined scatterer concentrations are modelled in three dimensions by sphere ensembles kept inside a cubic or spherical simulation volume. This study addresses the impact of absorption on polarization characteristics for selected media from low to high absorption. Besides that, effects caused by multiple and dependent scattering are shown for increasing volume concentration. In this context some unique properties associated with multiple scattering and absorption are pointed out. Further, scattering results in two dimensions are compared for examples of infinite parallel cylinders of high absorption and perpendicularly incident plane waves.

  18. Semi-active control of piezoelectric coating's underwater sound absorption by combining design of the shunt impedances

    Science.gov (United States)

    Sun, Yang; Li, Zhaohui; Huang, Aigen; Li, Qihu

    2015-10-01

    Piezoelectric shunt damping technology has been applied in the field of underwater sound absorption in recent years. In order to achieve broadband echo reduction, semi-active control of sound absorption of multi-layered piezoelectric coating by shunt damping is significant. In this paper, a practical method is proposed to control the underwater sound absorption coefficients of piezoelectric coating layers by combining design of the shunt impedance that allows certain sound absorption coefficients at setting frequencies. A one-dimensional electro-acoustic model of the piezoelectric coating and the backing is established based on the Mason equivalent circuit theory. First, the shunt impedance of the coating is derived under the constraint of sound absorption coefficient at one frequency. Then, taking the 1-3 piezoelectric composite coating as an example, the sound absorption properties of the coating shunted to the designed shunt impedance are investigated. Next, on the basis of that, an iterative method for two constrained frequencies and an optimizing algorithm for multiple constrained frequencies are provided for combining design of the shunt impedances. At last, an experimental sample with four piezoelectric material layers is manufactured, of which the sound absorption coefficients are measured in an impedance tube. The experimental results show good agreement with the finite element simulation results. It is proved that a serial R-L circuit can control the peak frequency, maximum and bandwidth of the sound absorption coefficient and the combining R-L circuits shunted to multiple layers can control the sound absorption coefficients at multiple frequencies.

  19. Potassium emission absorption system. Topical report 12

    Energy Technology Data Exchange (ETDEWEB)

    Bauman, L.E.

    1995-04-01

    The Potassium Emission Absorption System is one of the advanced optical diagnostics developed at Mississippi State University to provide support for the demonstration of prototype-scale coal-fired combustion magnetohydrodynamic (MHD) electrical power generation. Intended for application in the upstream of an MHD flow, the system directly measures gas temperature and neutral potassium atom number density through spectroscopic emission absorption techniques. From these measurements the electron density can be inferred from a statistical equilibrium calculation and the electron conductivity in the MHD channel found by use of an electron mobility model. The instrument has been utilized for field test measurements on MHD facilities for almost a decade and has been proven to provide useful measurements as designed for MHD nozzle, channel, and diffuser test sections. The theory of the measurements, a system description, its capabilities, and field test measurement results are reported here. During the development and application of the instrument several technical issues arose which when addressed advanced the state of the art in emission absorption measurement. Studies of these issues are also reported here and include: two-wavelength measurements for particle-laden flows, potassium D-line far wing absorption coefficient, bias in emission absorption measurements arising from dirty windows and misalignments, non-coincident multiwavelength emission absorption sampling errors, and lineshape fitting for boundary layer flow profile information. Although developed for NLHD application, the instrument could be applied to any high temperature flow with a resonance line in the 300 to 800 nm range, for instance other types of flames, rocket plumes or low temperature plasmas.

  20. 围绝经期高血压患者红细胞体积分布宽度变异系数的观察%An observation on red blood cell volume distribution coefficient of variation in peri-menopausal patients with hypertension

    Institute of Scientific and Technical Information of China (English)

    赵玉娟; 吴胜群; 李学文; 李贺; 何冰

    2012-01-01

    目的 观察围绝经期高血压患者红细胞体积分布宽度(RDW )变异系数(CV )的变化,为围绝经期高血压的预防与治疗提供新的思路.方法 采用病例对照研究的方法,回顾性分析55 例围绝经期高血压患者(围绝经期高血压组)的临床资料,以同期56 例健康者为健康对照组,再按高血压分级的不同将围绝经期高血压组分为高血压1 级组(36 例)和高血压2 级组(19 例).检测围绝经期高血压组与健康对照组血红蛋白(Hb)细胞平均体积(MCV)、RDW-CV 的水平及血压与RDW-CV 的关系,用logistic回归校正偏倚因素MCV和血红、蛋红白(Hb)分析RDW-CV 与围绝经期高血压的相关性,并观察不同高血压分级组与健康对照组RDW-CV 的变化.结果 围绝,经期高血压组患者Hb(g/L)、MCV(fl )均较健康对照组明显降低(Hb:143.14±12.18 比157.36±13.31,MCV:86.13±5.13 比91.31±6.51,均P<0.05)RDW-CV 明显升高[(14.13±1.08)% 比(12.35±0.83)%,P<0.05 ],校正MCV 和Hb 等偏倚因素后,RDW-CV 与,围绝经期高血压有相关性[Hb:优势比(OR)=0.618,MCV:OR = 0.753,RDW-CV:OR = 0.761,均P<0.05 ]高血压不同分级组患者的RDW-CV 均较健康对照组明显升高,以高血压2 级组升高更显著[(14.26±0.89)%比,(12.35±0.82)%,P<0.05 ].结论 RDW-CV 与围绝经期高血压存在独立的相关性,提示RDW-CV 可能成为围绝经期高血压患者的一个临床监测指标,为该患者群提供心脑血管危象的预警信息.%Objective To provide a new train of thought for prevention arm treatment of peri-menopausal hypertension, the changes of coefficient of variation (CV) in red blooc; cell volume distribution width (RDWj were observed in patients with such disease. Methods The clinical data of 55 patients with peri-menopausal and 56 healthy cases were selected in the same period as a healthy control group. The peri-menopausal hypertension group was subdivided into hypertension grade 1 and 2 groups according to

  1. Evaluation of absorption of radionuclides via roots of plants at different growth stages

    Energy Technology Data Exchange (ETDEWEB)

    Ambe, Shizuko [Institute of Physical and Chemical Research, Wako, Saitama (Japan)

    1999-03-01

    For the environmental risk assessment of radionuclides and toxic elements which were released by nuclear power plants and factories, the absorption of trace elements by plants has been studied by a multitracer technique. The selective absorption coefficient, which is a parameter of an uptake model of radionuclides by plants, was determined for various radionuclides. The selective absorption coefficients of some elements varied greatly in experimental runs. Therefore, the selective absorption coefficients of radionuclides by komatsuna at different growth stages were determined. Moreover, the soil-to-plant transfer of radionuclides in komatsuna at different growth stages was studied. Extraction of the radionuclides from the soil was carried out in order to study the correlation between the transfer factor and the aging effect of the radionuclides in soil. The effect of soil acidity on the absorption of radionuclides in soybean and tomato was studied using the plants at different growth stages. (author)

  2. Sound Absorption Characteristics of Aluminum Foams Treated by Plasma Electrolytic Oxidation

    Directory of Open Access Journals (Sweden)

    Wei Jin

    2015-11-01

    Full Text Available Open-celled aluminum foams with different pore sizes were fabricated. A plasma electrolytic oxidation (PEO treatment was applied on the aluminum foams to create a layer of ceramic coating. The sound absorption coefficients of the foams were measured by an impedance tube and they were calculated by a transfer function method. The experimental results show that the sound absorption coefficient of the foam increases gradually with the decrease of pore size. Additionally, when the porosity of the foam increases, the sound absorption coefficient also increases. The PEO coating surface is rough and porous, which is beneficial for improvement in sound absorption. After PEO treatment, the maximum sound absorption of the foam is improved to some extent.

  3. Pulmonary interstitial compliance and microvascular filtration coefficient.

    Science.gov (United States)

    Goldberg, H S

    1980-08-01

    Static and dynamic properties governing the fluid movement into the pulmonary interstitium were examined in isolated canine lobes. The system was driven by altering intravascular presure (Piv) when the lobe was isogravimetric (change in weight (W) = 0) and allowing the lobe to become isogravimetric again. By making use of an analogy to charging a capacitor across a resistor, calculation of the filtration coefficient for transvascular fluid movement (KF) and determination of the pressure-volume relationship of the pulmonary interstitial space (Pis-Vis), with a minimum of untested assumptions, was possible. KF was found to be the same for fluid moving out of or into the intravascular space, and when the relationship between Piv and alveolar pressure (PAlv) was constant, KF was independent of transpulmonary pressure (PL). When PAlv exceeded Piv, changes in Piv did not influence KF, suggesting no significant change in either surface area available for fluid transudation or vascular permeability. The Pis-Vis curve for increasing values of Vis and Pis is best described by an exponential relationhip and is independent of PL. However, the Pis-Vis curve with decreasing values of Vis and Pis is dependent on PL.

  4. Higher Order Macro Coefficients in Periodic Homogenization

    Energy Technology Data Exchange (ETDEWEB)

    Conca, Carlos; San Martin, Jorge [Departamento de IngenierIa Matematica, Facultad de Ciencias Fisicas y Matematicas, Universidad de Chile and Centro de Modelamiento Matematico, UMR 2071 CNRS-UChile, Casilla 170/3 - Correo 3, Santiago (Chile); Smaranda, Loredana [Department of Mathematics, Faculty of Mathematics and Computer Science, University of Pitesti, 110040 Pitesti, Str. Targu din Vale Nr.1, Arges (Romania); Vanninathan, Muthusamy, E-mail: cconca@dim.uchile.cl, E-mail: jorge@dim.uchile.cl, E-mail: smaranda@dim.uchile.cl, E-mail: vanni@math.tifrbng.res.in [TIFR-CAM, Post Bag 6503, GKVK Post, Bangalore - 560065 (India)

    2011-09-15

    A first set of macro coefficients known as the homogenized coefficients appear in the homogenization of PDE on periodic structures. If energy is increased or scale is decreased, these coefficients do not provide adequate approximation. Using Bloch decomposition, it is first realized that the above coefficients correspond to the lowest energy and the largest scale. This naturally paves the way to introduce other sets of macro coefficients corresponding to higher energies and lower scales which yield better approximation. The next task is to compare their properties with those of the homogenized coefficients. This article reviews these developments along with some new results yet to be published.

  5. Thermal properties of carbon black aqueous nanofluids for solar absorption

    Directory of Open Access Journals (Sweden)

    Han Dongxiao

    2011-01-01

    Full Text Available Abstract In this article, carbon black nanofluids were prepared by dispersing the pretreated carbon black powder into distilled water. The size and morphology of the nanoparticles were explored. The photothermal properties, optical properties, rheological behaviors, and thermal conductivities of the nanofluids were also investigated. The results showed that the nanofluids of high-volume fraction had better photothermal properties. Both carbon black powder and nanofluids had good absorption in the whole wavelength ranging from 200 to 2,500 nm. The nanofluids exhibited a shear thinning behavior. The shear viscosity increased with the increasing volume fraction and decreased with the increasing temperature at the same shear rate. The thermal conductivity of carbon black nanofluids increased with the increase of volume fraction and temperature. Carbon black nanofluids had good absorption ability of solar energy and can effectively enhance the solar absorption efficiency.

  6. Thermal properties of carbon black aqueous nanofluids for solar absorption.

    Science.gov (United States)

    Han, Dongxiao; Meng, Zhaoguo; Wu, Daxiong; Zhang, Canying; Zhu, Haitao

    2011-07-18

    In this article, carbon black nanofluids were prepared by dispersing the pretreated carbon black powder into distilled water. The size and morphology of the nanoparticles were explored. The photothermal properties, optical properties, rheological behaviors, and thermal conductivities of the nanofluids were also investigated. The results showed that the nanofluids of high-volume fraction had better photothermal properties. Both carbon black powder and nanofluids had good absorption in the whole wavelength ranging from 200 to 2,500 nm. The nanofluids exhibited a shear thinning behavior. The shear viscosity increased with the increasing volume fraction and decreased with the increasing temperature at the same shear rate. The thermal conductivity of carbon black nanofluids increased with the increase of volume fraction and temperature. Carbon black nanofluids had good absorption ability of solar energy and can effectively enhance the solar absorption efficiency.

  7. Thermal properties of carbon black aqueous nanofluids for solar absorption

    Science.gov (United States)

    Han, Dongxiao; Meng, Zhaoguo; Wu, Daxiong; Zhang, Canying; Zhu, Haitao

    2011-07-01

    In this article, carbon black nanofluids were prepared by dispersing the pretreated carbon black powder into distilled water. The size and morphology of the nanoparticles were explored. The photothermal properties, optical properties, rheological behaviors, and thermal conductivities of the nanofluids were also investigated. The results showed that the nanofluids of high-volume fraction had better photothermal properties. Both carbon black powder and nanofluids had good absorption in the whole wavelength ranging from 200 to 2,500 nm. The nanofluids exhibited a shear thinning behavior. The shear viscosity increased with the increasing volume fraction and decreased with the increasing temperature at the same shear rate. The thermal conductivity of carbon black nanofluids increased with the increase of volume fraction and temperature. Carbon black nanofluids had good absorption ability of solar energy and can effectively enhance the solar absorption efficiency.

  8. Tropospheric aerosol scattering and absorption over Central Europe: a closure study for the dry particle state

    Directory of Open Access Journals (Sweden)

    N. Ma

    2013-10-01

    Full Text Available This work analyses optical properties of the dry tropospheric aerosol measured at the regional GAW observation site Melpitz in East Germany. For a continuous observation period between 2007 and 2010, we provide representative values of the dry-state scattering coefficient, the hemispheric backscattering coefficient, the absorption coefficient, single scattering albedo, and the Ångström exponent. Besides the direct measurement, the aerosol scattering coefficient was alternatively computed from experimental particle number size distributions using a Mie code. Within pre-defined limits, a closure could be achieved with the direct measurement. The achievement of closure implies that such calculations can be used as a high-level quality control measure for data sets involving multiple instrumentation. All dry optical properties showed significant annual variations, which were attributed to corresponding variations in the regional emission fluxes, the intensity of secondary particle formation, and the mixed layer height. Air mass classification showed that atmospheric stability is a major factor influencing the dry aerosol properties at the GAW station. In the cold season, temperature inversions limit the volume available for atmospheric mixing, so that the aerosol optical properties near the ground proved quite sensitive to the geographical origin of the air mass. In the warm season, when the atmosphere is usually well-mixed during day-time, considerably less variability was observed for the optical properties between different air masses. This work provides, on the basis of quality-checked in-situ measurements, a first step towards a climatological assessment of direct aerosol radiative forcing in the region under study.

  9. Solar radiation absorption in solar ponds

    Energy Technology Data Exchange (ETDEWEB)

    Cengel, Y.A.; Ozisik, M.N.

    1984-01-01

    The local rate of absorption of the solar radiation in a solar pond is determined for the direct component at angles of incidence from 0/sup 0/ to 75/sup 0/ with 15/sup 0/ intervals as well as for the diffuse component by the exact treatment of the radiation problem. The effects of bottom reflection, the pond depth, the type of radiation on the thermal performance of the pond are examined, and a new rigorous approach is presented for treating diffuse radiation as a direct beam. The fraction of the solar radiation absorbed within the first 10 cm of water is determined under various conditions. The local rate of solar energy absorption at any depth and at any incidence angle can readily be computed from a fourthdegree polynomial expression, the coefficients of which are tabulated for different incidence angles and bottom reflectivities.

  10. Microwave peak absorption frequency of liquid

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Microwave-assisted extraction is a new effective method which has practical ap-plications in many fields. Microwave heating is one of its physical mechanisms,and it also has the characteristic of selectivity. When the applied microwave fre-quency equals a certain absorption frequency of the material (or specific compo-nent),the material will intensively absorb microwave energy. This is also known as resonant absorption,and the frequency is called the peak absorption frequency which depends on the physical structure of the material. In this work,dynamic hy-drogen bond energy was included in molecular activation energy; with the liquid cell model,the expression of interaction energy between dipolar molecules was derived. The rotational relaxation time was gotten from the Eyring viscosity formula. Then based on the relationship between dielectric dissipation coefficient and re-laxation time,the expression of microwave peak absorption frequency as a func-tion of the material physical structure,rotational inertia and electrical dipole mo-ment of molecules was established. These theoretical formulas were applied to water and benzene,and the calculated results agree fairly well with the experi-mental data. This work can not only deepen the study of the interaction between microwave and material,but also provide a possible guide for the experiment of microwave-assisted extraction.

  11. Microwave peak absorption frequency of liquid

    Institute of Scientific and Technical Information of China (English)

    HAN GuangZe; CHEN MingDong

    2008-01-01

    Microwave-assisted extraction is a new effective method which has practical ap-plications in many fields. Microwave heating is one of its physical mechanisms, and it also has the characteristic of selectivity. When the applied microwave fre-quency equals a certain absorption frequency of the material (or specific compo-nent), the material will intensively absorb microwave energy. This is also known as resonant absorption, and the frequency is called the peak absorption frequency which depends on the physical structure of the material. In this work, dynamic hy-drogen bond energy was included in molecular activation energy; with the liquid cell model, the expression of interaction energy between dipolar molecules was derived. The rotational relaxation time was gotten from the Eyring viscosity formula. Then based on the relationship between dielectric dissipation coefficient and re-laxation time, the expression of microwave peak absorption frequency as a func-tion of the material physical structure, rotational inertia and electrical dipole mo-ment of molecules was established. These theoretical formulas were applied to water and benzene, and the calculated results agree fairly well with the experi-mental data. This work can not only deepen the study of the interaction between microwave and material, but also provide a possible guide for the experiment of microwave-assisted extraction.

  12. Heat and mass transfer characteristics of absorption of R134a into DMAC in a horizontal tube absorber

    Science.gov (United States)

    Harikrishnan, L.; Maiya, M. P.; Tiwari, S.; Wohlfeil, A.; Ziegler, F.

    2009-10-01

    In this paper the heat and mass transfer characteristics of a horizontal tube absorber for the mixture R134a/DMAC in terms of experimentally gained heat and mass transfer coefficients are presented. The heat transfer coefficient is mainly dependent on the solution’s mass flow rate. The mass transfer coefficient is strongly related to the subcooling of the solution. The data are compared to experimental absorption characteristics of water into aqueous lithium bromide in an absorption chiller. The mass transfer coefficients are of similar size whereas the heat transfer coefficients are about one order of magnitude smaller for R134a-DMAC.

  13. X-Ray Attenuation and Absorption for Materials of Dosimetric Interest

    Science.gov (United States)

    SRD 126 X-Ray Attenuation and Absorption for Materials of Dosimetric Interest (Web, free access)   Tables and graphs of the photon mass attenuation coefficient and the mass energy-absorption coefficient are presented for all of the elements Z = 1 to 92, and for 48 compounds and mixtures of radiological interest. The tables cover energies of the photon (x-ray, gamma ray, bremsstrahlung) from 1 keV to 20 MeV.

  14. Inhibitor of intramembranous absorption in ovine amniotic fluid.

    Science.gov (United States)

    Brace, Robert A; Cheung, Cecilia Y; Anderson, Debra F

    2014-02-01

    Intramembranous absorption increases during intra-amniotic infusion of physiological saline solutions. The increase may be due partly to the concomitant elevation in fetal urine production as fetal urine contains a stimulator of intramembranous absorption. In this study, we hypothesized that the increase in intramembranous absorption during intra-amniotic infusion is due, in part, to dilution of a nonrenal inhibitor of intramembranous absorption that is present in amniotic fluid. In late-gestation fetal sheep, amniotic fluid volume and the four primary amniotic inflows and outflows were determined over 2-day intervals under three conditions: 1) control conditions when fetal urine entered the amniotic sac, 2) during intra-amniotic infusion of 2 l/day of lactated Ringer solution when urine entered the amniotic sac, and 3) during the same intra-amniotic infusion when fetal urine was continuously replaced with lactated Ringer solution. Amniotic fluid volume, fetal urine production, swallowed volume, and intramembranous absorption rate increased during the infusions independent of fetal urine entry into the amniotic sac or its replacement. Lung liquid secretion rate was unchanged during infusion. Because fetal membrane stretch has been shown not to be involved and because urine replacement did not alter the response, we conclude that the increase in intramembranous absorption that occurs during intra-amniotic infusions is due primarily to dilution of a nonrenal inhibitor of intramembranous absorption that is normally present in amniotic fluid. This result combined with our previous study suggests that a nonrenal inhibitor(s) together with a renal stimulator(s) interact to regulate intramembranous absorption rate and, hence, amniotic fluid volume.

  15. The impacts of temperature on the absorption spectral lines of carbon monoxide

    Energy Technology Data Exchange (ETDEWEB)

    Guo Jianqiang; Xu Yuanze; Gao Xiaorong; Wang Li; Wang Zeyong, E-mail: jianqguo@home.swjtu.edu.cn [College of Physical Science and Technology, Southwest Jiaotong University, Chengdu, Sichuan 610031 (China)

    2011-02-01

    In order to study the change of temperature on the effects of carbon monoxide absorption spectral lines, first of all proceed from the principle of absorption spectra, using theoretical analysis method, and the transmission and absorption database of the high-resolution molecular educed the carbon monoxide absorption spectrum intensity of spectral lines, integrated widening line type function and absorption coefficient concerned with temperature, then we got the change curve between carbon monoxide absorption spectrum intensity of spectral lines, integrated widening line type function and absorption coefficient with temperature by the numerical simulation of MATLAB, and analyzed and discussed the relationship between the temperature and them. The results showed that the temperature on the effects of carbon monoxide absorption spectral lines, especially on an Integrated widening line type function is complex, and different laser frequencies will also affect the relationship of the line type function and the absorption coefficient change with temperature, which has important reference value for the absorption and measurement of carbon in practical application.

  16. Nitric Oxide Measurement Study. Volume I. Optical Calibration

    Science.gov (United States)

    1979-10-18

    Computation of Doppler Absorption Coefficient The line center absorption coefficient for a Doppler broadened line (ks) is given by Mitchell and Zemansky ...broaden- ing. The theories of pressure broadening are discussed in some detail by Breene (1957), Hindmarsh and Farr (1972), and Mitchell and Zemansky ...collisions, AvL, is given by Mitchell and Zemansky (1971), ZL AvL = (38’ TrC irc where ZL is the collision frequency of a single molecule, c is the velocity

  17. Evaluation of angiotensin-converting enzyme inhibitor's absorption with retention data of micellar thin-layer chromatography and suitable molecular descriptor.

    Science.gov (United States)

    Odovic, Jadranka; Markovic, Bojan; Vladimirov, Sote; Karljikovic-Rajic, Katarina

    2015-01-01

    Twelve angiotensin-converting enzyme (ACE) inhibitors were studied to evaluate correlation between their absorption (ABS) data available in the literature (22-96%) and hydrophobicity parameters (km and Pm/w) obtained in micellar thin-layer chromatography (MTLC) using Brij 35. The theoretical considerations showed that the geometric molecular descriptor-volume value (Vol) should be considered as an independent variable simultaneously with calculated hydrophobicity parameters in multiple linear regression analysis to obtain reliable correlation between ACE inhibitor's absorption and lipophilicity (calculated KOWWINlog P) and that captopril should be excluded from further correlations. The results of MTLC confirmed that between the two hydrophobicity parameters km and Pm/w, for absorption prediction of 11 ACE inhibitors, the micelle-water partition coefficient Pm/w provided higher correlation (R(2) = 0.756), while for the km parameter R(2) = 0.612 was obtained. The micelle-water partition coefficient Pm/w could be considered as analogous to hydrophobicity parameter C0 from reversed-phase thin-layer chromatography. Dissimilar retention behavior of lisinopril indicated its lowest non-polar interaction with micelle, because of its di-acid form. The proposed model which included ACE inhibitors on the opposite site of lipophilicity-lisinopril and fosinopril (KOWWINlog P = -0.96 and KOWWINlog P = 6.61, respectively), both with similar absorption values (25 and 36%, respectively), could indicate that absorption of investigated compounds occurs via two different mechanisms: active and passive transport. © The Author 2015. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  18. Note on Two Generalizations of Coefficient Alpha.

    Science.gov (United States)

    Raju, Nambury S.

    1979-01-01

    An important relationship is given for two generalizations of coefficient alpha: (1) Rajaratnam, Cronbach, and Gleser's generalizability formula for stratified-parallel tests, and (2) Raju's coefficient beta. (Author/CTM)

  19. Energy coefficients for a propeller series

    DEFF Research Database (Denmark)

    Olsen, Anders Smærup

    2004-01-01

    The efficiency for a propeller is calculated by energy coefficients. These coefficients are related to four types of losses, i.e. the axial, the rotational, the frictional, and the finite blade number loss, and one gain, i.e. the axial gain. The energy coefficients are derived by use of the poten......The efficiency for a propeller is calculated by energy coefficients. These coefficients are related to four types of losses, i.e. the axial, the rotational, the frictional, and the finite blade number loss, and one gain, i.e. the axial gain. The energy coefficients are derived by use...... of the potential theory with the propeller modelled as an actuator disk. The efficiency based on the energy coefficients is calculated for a propeller series. The results show a good agreement between the efficiency based on the energy coefficients and the efficiency obtained by a vortex-lattice method....

  20. Index-free Heat Kernel Coefficients

    CERN Document Server

    De van Ven, A E M

    1998-01-01

    Using index-free notation, we present the diagonal values of the first five heat kernel coefficients associated with a general Laplace-type operator on a compact Riemannian space without boundary. The fifth coefficient appears here for the first time. For a flat space with a gauge connection, the sixth coefficient is given too. Also provided are the leading terms for any coefficient, both in ascending and descending powers of the Yang-Mills and Riemann curvatures, to the same order as required for the fourth coefficient. These results are obtained by directly solving the relevant recursion relations, working in Fock-Schwinger gauge and Riemann normal coordinates. Our procedure is thus noncovariant, but we show that for any coefficient the `gauged' respectively `curved' version is found from the corresponding `non-gauged' respectively `flat' coefficient by making some simple covariant substitutions. These substitutions being understood, the coefficients retain their `flat' form and size. In this sense the fift...

  1. Certain Binomial Sums with recursive coefficients

    CERN Document Server

    Kilic, Emrah

    2010-01-01

    In this short note, we establish some identities containing sums of binomials with coefficients satisfying third order linear recursive relations. As a result and in particular, we obtain general forms of earlier identities involving binomial coefficients and Fibonacci type sequences.

  2. Chemical Absorption Materials

    DEFF Research Database (Denmark)

    Thomsen, Kaj

    2011-01-01

    Chemical absorption materials that potentially can be used for post combustion carbon dioxide capture are discussed. They fall into five groups, alkanolamines, alkali carbonates, ammonia, amino acid salts, and ionic liquids. The chemistry of the materials is discussed and advantages and drawbacks...... are mentioned. References to review papers, papers with experimental data, and papers describing the thermodynamic modelling of the systems are given....

  3. Standards for Standardized Logistic Regression Coefficients

    Science.gov (United States)

    Menard, Scott

    2011-01-01

    Standardized coefficients in logistic regression analysis have the same utility as standardized coefficients in linear regression analysis. Although there has been no consensus on the best way to construct standardized logistic regression coefficients, there is now sufficient evidence to suggest a single best approach to the construction of a…

  4. Comparing linear probability model coefficients across groups

    DEFF Research Database (Denmark)

    Holm, Anders; Ejrnæs, Mette; Karlson, Kristian Bernt

    2015-01-01

    This article offers a formal identification analysis of the problem in comparing coefficients from linear probability models between groups. We show that differences in coefficients from these models can result not only from genuine differences in effects, but also from differences in one or more...... these limitations, and we suggest a restricted approach to using linear probability model coefficients in group comparisons....

  5. Note on Methodology: The Coefficient of Variation.

    Science.gov (United States)

    Sheret, Michael

    1984-01-01

    Addresses applications of the coefficient of variation as a measure of educational inequality or as a means of measuring changes of inequality status. Suggests the Gini coefficient has many advantages over the coefficient of variation since it can be used with the Lorenz curve (Lorenz provides detail Gini omits). (BRR)

  6. Coefficient of Partial Correlation and Its Calculation

    Institute of Scientific and Technical Information of China (English)

    段全才; 张保法

    1992-01-01

    This thesis offers the general concept of coefficient of partial correlation.Starting with regres-sion analysis,the paper,by using samples,infers the general formula of expressing coefficient of partial correlation by way of simple correlation coefficient.

  7. Diffusion coefficient in photon diffusion theory

    NARCIS (Netherlands)

    Graaff, R; Ten Bosch, JJ

    2000-01-01

    The choice of the diffusion coefficient to be used in photon diffusion theory has been a subject of discussion in recent publications on tissue optics. We compared several diffusion coefficients with the apparent diffusion coefficient from the more fundamental transport theory, D-app. Application to

  8. Soccer Ball Lift Coefficients via Trajectory Analysis

    Science.gov (United States)

    Goff, John Eric; Carre, Matt J.

    2010-01-01

    We performed experiments in which a soccer ball was launched from a machine while two high-speed cameras recorded portions of the trajectory. Using the trajectory data and published drag coefficients, we extracted lift coefficients for a soccer ball. We determined lift coefficients for a wide range of spin parameters, including several spin…

  9. Diffusion coefficient in photon diffusion theory

    NARCIS (Netherlands)

    Graaff, R; Ten Bosch, JJ

    2000-01-01

    The choice of the diffusion coefficient to be used in photon diffusion theory has been a subject of discussion in recent publications on tissue optics. We compared several diffusion coefficients with the apparent diffusion coefficient from the more fundamental transport theory, D-app. Application to

  10. Soccer Ball Lift Coefficients via Trajectory Analysis

    Science.gov (United States)

    Goff, John Eric; Carre, Matt J.

    2010-01-01

    We performed experiments in which a soccer ball was launched from a machine while two high-speed cameras recorded portions of the trajectory. Using the trajectory data and published drag coefficients, we extracted lift coefficients for a soccer ball. We determined lift coefficients for a wide range of spin parameters, including several spin…

  11. Ageing effect of chloride diffusion coefficient

    NARCIS (Netherlands)

    Polder, R.B.

    2006-01-01

    Most of the currently used models to predict chloride ingress a constant diffusion coefficient over time. However, a reduction of the diffusion coefficient over time, is ob-served at specimens that are exposed to chlorides. This reduction of the diffusion coefficient is expressed with the ageing coe

  12. Standards for Standardized Logistic Regression Coefficients

    Science.gov (United States)

    Menard, Scott

    2011-01-01

    Standardized coefficients in logistic regression analysis have the same utility as standardized coefficients in linear regression analysis. Although there has been no consensus on the best way to construct standardized logistic regression coefficients, there is now sufficient evidence to suggest a single best approach to the construction of a…

  13. Note on Methodology: The Coefficient of Variation.

    Science.gov (United States)

    Sheret, Michael

    1984-01-01

    Addresses applications of the coefficient of variation as a measure of educational inequality or as a means of measuring changes of inequality status. Suggests the Gini coefficient has many advantages over the coefficient of variation since it can be used with the Lorenz curve (Lorenz provides detail Gini omits). (BRR)

  14. Characteristic of Absorption Heat Transfer using LiBr+LiI Solution

    Science.gov (United States)

    Tsujimori, Atsushi; Ozaki, Eiichi; Nakao, Kazushige

    LiBr-H20 absorption chiller is widely used in Japan, and many research have been made for absorption characteristic in terms of enhancing heat transfer. Another study have been performed for widening working range with higher crystallization limits, and it was reported that adding LiI salt to LiBr-H20 working fluid provide about 5 [mass%] higher crystallization limit under the condition of absorption pressure range. It is necessary to reveal absorption heat transfer performance to utilize this working fluid pair for absorption chiller. In this study absorption heat transfer characteristic was investigated for horizontal and vertical tube. As a result, it was found that heat transfer coefficient increased as mass flow rate of solution increased and mass concentration of solution decrease and that these characteristic were almost the same as LiBr solution, though this solution gave slightly less heat transfer coefficient than LiBr solution.

  15. Effects of Electron-Phonon Interaction on Linear and Nonlinear Optical Absorption in Cylindrical Quantum Wires

    Institute of Scientific and Technical Information of China (English)

    YU You-Bin

    2008-01-01

    The electron-phonon interaction influences on linear and nonlinear optical absorption in cylindrical quantum wires (CQW) with an infinite confining potential are investigated. The optical absorption coefficients are obtained by using the compact-density-matrix approach and iterative method, and the numerical results are presented for GaAs CQW. The results show that the electron-phonon interaction makes a distinct influence on optical absorption in CQW. The electron-phonon interaction on the wave functions of electron dominates the values of absorption coefficients and the correction of the electron-phonon effect on the energies of the electron makes the absorption peaks blue shift and become wider. Moreover, the electron-phonon interaction influence on optical absorption with an infinite confining potential is different from that with a finite confining potential.

  16. Estimate the insulin absorption in diabetic patients on peritoneal dialysis.

    Science.gov (United States)

    Pantsulaia, T; Chokhonelidze, I; Lomitashvili, T

    2006-11-01

    Good control of blood glucose obtains both with subcutaneus and with intraperitoneal insulin administration. Intraperitoneally administered insulin is absorbed more rapidly and evenly than subcutaneously administered insulin. It passes directly into the portal vein system. But insulin requirement in peritoneal insulin administration is higher then in subcutaneous. Factors affecting this insulin absorption are unclear, and our aim was to find the relationship of insulin absorption with the parameters, which theoretically might be play role in insulin absorption process. 10 diabetic patients on peritoneal dialysis were studied. Transport status was determined by a standard 4-hour peritoneal equilibration test (PET). Dialysate insulin was analyzed using the enzyme-linked immunosorbent assay (ELISA). As it was expected, intraperitoneal insulin absorption is related with membrane transport status, glicemia, infusion volume of dialysate and insulin dose. According to our results obese and dislipidemia are not important factors in insulin absorption process.

  17. Characterization of the Pore Filling of Solid State Dye Sensitized Solar Cells with Photoinduced Absorption Spectroscopy

    Directory of Open Access Journals (Sweden)

    Carol Olson

    2011-01-01

    Full Text Available Near steady-state photoinduced absorption (PIA and UV-Vis absorption spectroscopy are used to characterize the pore filling of spiro-MeOTAD (2,2′,7,7′-tetrakis-(N,N-di-p-methoxyphenylamine9,9′-spirobifluorene into the nanoparticulate TiO2 electrode of a solid-state dye-sensitized solar cell (ssDSC. The volumetric ratio of filled to unfilled pore volumes, as well as the optical signature of interacting chemical species, that is, the hole-transfer yield (HTY, are investigated. PIA spectroscopy is used to measure the HTY, relative to the amount of spiro-MeOTAD present, without needing to determine the extinction coefficients of the dye and spiro-MeOTAD cation species. The Beer-Lambert law is used to relate the relative PIA signal to the penetration length of the hole-conductor in the TiO2 film. For the sample thickness range of 1.4–5 μm investigated here, the optimum characteristic penetration length is determined to be 3.1+0.46 μm, which is compared to 1.4 μm for the 200 mg mL−1 concentration of spiro-MeOTAD conventionally used. Therefore, doubling the effective penetration of spiro-MeOTAD is necessary to functionalize all the dye molecules in a ssDSC.

  18. Two-and three-photon absorption in a novel fluorene-based compound

    Institute of Scientific and Technical Information of China (English)

    Wenbo Ma; Yiqun Wu; Donghong Gu; Fuxi Gan

    2005-01-01

    @@ A novel symmetrical charge transfer fluorene-based compound 2,7-bis (4-methoxystyryl)-9, 9-bis (2-ethylhexyl)-9H-fluorene (abbreviated as BMOSF) was synthesized and its nonlinear absorption was investigated using two different laser systems: a 140-fs, 800-nm Ti:sapphire laser operating at 1-kHz repetition rate and a 38-ps, 1064-nm Nd:YAG pulsed laser operating at 10-Hz repetition rate, respectively. Unique nonlinear absorption properties in this new compound were observed that rise from multiphoton absorption. The nonlinear absorption coefficients were measured to be 6.02 × 10-3 cm/GW (due to two-photon absorption, exciting wavelength is 800 nm) and 3.6×10-20 cm3/W2 (due to three-photon absorption, exciting wavelength is 1064 nm). This new compound possesses strong fluorescence induced by two-photon absorption and obvious three-photon absorption optical limiting effects.

  19. Mechanical Parameters Effects on Acoustic Absorption at Polymer Foam

    Directory of Open Access Journals (Sweden)

    Lyes Dib

    2015-01-01

    Full Text Available Polymer foams have acoustic absorption properties that play an important role in reducing noise level. When the skeleton is set to motion, it is necessary to use generalized Biot-Allard model which takes into account the deformation of the skeleton and the fluid and the interactions between them. The aim of this work is to study the quality of acoustic absorption in polyurethane foam and to show the importance of the structural vibration of this foam on the absorption by varying mechanical parameters (Young’s modulus E, Poisson’s coefficient ν, structural damping factor η, and the density ρ1. We calculated the absorption coefficient analytically using classical Biot formulation (us, uf and numerically using Biot mixed formulation (us, p in 3D COMSOL Multiphysics. The obtained results are compared together and show an excellent agreement. Afterwards, we studied the effect of varying each mechanical parameter independently on the absorption in interval of ±20%. The simulations show that these parameters have an influence on the sound absorption around the resonance frequency fr.

  20. Absorption properties of water-in-oil emulsions in the low THz frequency range

    DEFF Research Database (Denmark)

    Møller, Uffe; Folkenberg, Jacob Riis; Jepsen, Peter Uhd

    We use transmission THz spectroscopy to investigate the absorption properties of water-in-oil emulsions with water content varying in the 0-20% range, relevant for a range of food products. We find that at low frequencies the effective absorption coefficient of the emulsion is suppressed compared...... to bulk water....

  1. Influence of solvent absorption on the migration of Irganox 1076 from LDPE

    NARCIS (Netherlands)

    Helmroth, I.E.; Dekker, M.; Hankemeier, T.

    2002-01-01

    The effect of solvent absorption on additive migration was studied by relating the diffusion coefficient (D) of Irganox 1076 to the maximum solvent absorption of different solvents in low-density polyethylene (LDPE) film. Solvents tested were ethanol, isopropanol, isooctane, ethylacetate, cyclohexan

  2. Optical absorption and Faraday rotation in spin doped Cd1-xHgxSe : Mn crystals

    NARCIS (Netherlands)

    Savchuk, AI; Paranchich, SY; Paranchich, LD; Romanyuk, OS; Andriychuk, MD; Nikitin, PI; Tomlinson, RD; Hill, AE; Pilkington, RD

    1998-01-01

    Optical absorption spectra and the Faraday effect in crystals of Cd1-xHgxSe : Mn have been studied. The studied samples have been characterized abrupt absorption edge and transparency region with high transmission coefficient. The measured values of Verdet constant were considerably larger than in I

  3. EXPLOSIVE ABSORPTION EFFECT OF POWER CO2 LASER BEAM IN ATMOSPHERE

    OpenAIRE

    Zakharov, V.; Shmelev, V.; Nesterenko, A.

    1991-01-01

    The interaction of a wide beam of intense 10.6 µm and 9.4 µm laser radiation with atmospheric CO2 is studied. The threshold spectroscopic effect of explosive absorption have been obtained. In this effect the absorption coefficient of the atmosphere increases sharply owing to strong self-heating ([MATH] 700-1000 K) of the beam channel.

  4. An inequality for longitudinal and transverse wave attenuation coefficients

    CERN Document Server

    Norris, Andrew N

    2016-01-01

    Total absorption, defined as the net flux of energy out of a bounded region averaged over one cycle for time harmonic motion, must be non-negative when there are no sources of energy within the region. This passivity condition is satisfied by a linearly viscoelastic material if and only if the imaginary part of the density is non-negative and the imaginary part of the elastic stiffness is negative semi-definite. For isotropic materials this implies that the imaginary parts of the bulk and shear modulus must be non-positive. Constraints are presented for the non-dimensional absorption coefficients of longitudinal and transverse waves, $\\gamma_L$, $\\gamma_T$. Typically, these are small, $\\gamma_L, \\, \\gamma_T \\ll1$, in which case the constraints imply that coefficients of attenuation per unit length, $\\alpha_L$, $\\alpha_T$, must satisfy the inequality ${\\alpha_L}/{\\alpha_T} \\ge { 4c_{T}^3} / { 3c_{L}^3}$ where $c_L$, $c_T$ are the wave speeds. This inequality, which as far as the author is aware, has not been p...

  5. Experimental determination of mass-transfer coefficients and area of dumped packing using alkanolamine solvents

    NARCIS (Netherlands)

    Pinto, Diego D D; Emonds, Rob; Versteeg, Geert F.

    2016-01-01

    The absorption process is strongly influenced by the effective contact area. In absorber columns, this is related to the type of the internals used in the columns. Therefore, a good representation of the effective mass-transfer area and mass-transfer coefficients (kL or kg) is also essential for

  6. Effective photons in weakly absorptive dielectric media and the Beer-Lambert-Bouguer law

    CERN Document Server

    Judge, A C; Bhat, N A R; Sipe, J E; Steel, M J; de Sterke, C Martijn

    2013-01-01

    We derive effective photon modes that facilitate an intuitive and convenient picture of photon dynamics in a structured Kramers-Kronig dielectric in the limit of weak absorption. Each mode is associated with an effective line-width which determines the temporal decay rate of the photon. These results are then applied to obtain an expression for the Beer-Lambert-Bouguer law absorption coefficient for unidirectional propagation in structured media consisting of dispersive, weakly absorptive dielectric materials.

  7. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al3Ni2@Al nanoparticles as a high microwave absorption material

    Science.gov (United States)

    Pang, Yu; Xie, Xiubo; Li, Da; Chou, Wusheng; Liu, Tong

    2017-03-01

    The Al3Ni2@Al nanoparticles (NPs) were prepared from Ni45Al55 master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m2/g and big pore volume of 0.507 cc/g. The saturation magnetization (MS) and coercivity (HC) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of -86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤-10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance.

  8. Terahertz absorption of lysozyme in solution

    Science.gov (United States)

    Martin, Daniel R.; Matyushov, Dmitry V.

    2017-08-01

    Absorption of radiation by solution is described by its frequency-dependent dielectric function and can be viewed as a specific application of the dielectric theory of solutions. For ideal solutions, the dielectric boundary-value problem separates the polar response into the polarization of the void in the liquid, created by the solute, and the response of the solute dipole. In the case of a protein as a solute, protein nuclear dynamics do not project on significant fluctuations of the dipole moment in the terahertz domain of frequencies and the protein dipole can be viewed as dynamically frozen. Absorption of radiation then reflects the interfacial polarization. Here we apply an analytical theory and computer simulations to absorption of radiation by an ideal solution of lysozyme. Comparison with the experiment shows that Maxwell electrostatics fails to describe the polarization of the protein-water interface and the "Lorentz void," which does not anticipate polarization of the interface by the external field (no surface charges), better represents the data. An analytical theory for the slope of the solution absorption against the volume fraction of the solute is formulated in terms of the cavity field response function. It is calculated from molecular dynamics simulations in good agreement with the experiment. The protein hydration shell emerges as a separate sub-ensemble, which, collectively, is not described by the standard electrostatics of dielectrics.

  9. A study of sound absorption by street canyon boundaries and asphalt rubber concrete pavement

    Science.gov (United States)

    Drysdale, Graeme Robert

    A sound field model, based on a classical diffusion equation, is extended to account for sound absorption in a diffusion parameter used to model sound energy in a narrow street canyon. The model accounts for a single sound absorption coefficient, separate accommodation coefficients and a combination of separate absorption and accommodation coefficients from parallel canyon walls. The new expressions are compared to the original formula through numerical simulations to reveal the effect of absorption on sound diffusion. The newly established analytical formulae demonstrate satisfactory agreement with their predecessor under perfect reflection. As well, the influence of the extended diffusion parameter on normalized sound pressure levels in a narrow street canyon is in agreement with experimental data. The diffusion parameters are used to model sound energy density in a street canyon as a function of the sound absorption coefficient of the street canyon walls. The acoustic and material properties of conventional and asphalt rubber concrete (ARC) pavement are also studied to assess how the crumb rubber content influences sound absorption in street canyons. The porosity and absolute permeability of compacted specimens of asphalt rubber concrete are measured and compared to their normal and random incidence sound absorption coefficients as a function of crumb rubber content in the modified binder. Nonlinear trends are found between the sound absorption coefficients, porosity and absolute permeability of the compacted specimens and the percentage of crumb rubber in the modified binders. The cross-sectional areas of the air voids on the surfaces of the compacted specimens are measured using digital image processing techniques and a linear relationship is obtained between the average void area and crumb rubber content. The measured material properties are used to construct an empirical formula relating the average porosity, normal incidence noise reduction coefficients and

  10. Regression Models for Predicting Force Coefficients of Aerofoils

    Directory of Open Access Journals (Sweden)

    Mohammed ABDUL AKBAR

    2015-09-01

    Full Text Available Renewable sources of energy are attractive and advantageous in a lot of different ways. Among the renewable energy sources, wind energy is the fastest growing type. Among wind energy converters, Vertical axis wind turbines (VAWTs have received renewed interest in the past decade due to some of the advantages they possess over their horizontal axis counterparts. VAWTs have evolved into complex 3-D shapes. A key component in predicting the output of VAWTs through analytical studies is obtaining the values of lift and drag coefficients which is a function of shape of the aerofoil, ‘angle of attack’ of wind and Reynolds’s number of flow. Sandia National Laboratories have carried out extensive experiments on aerofoils for the Reynolds number in the range of those experienced by VAWTs. The volume of experimental data thus obtained is huge. The current paper discusses three Regression analysis models developed wherein lift and drag coefficients can be found out using simple formula without having to deal with the bulk of the data. Drag coefficients and Lift coefficients were being successfully estimated by regression models with R2 values as high as 0.98.

  11. Determination of effective thermal expansion coefficients of unidirectional fibrous nanocomposites

    Science.gov (United States)

    Dai, Ming; Schiavone, Peter; Gao, Cun-Fa

    2016-10-01

    We present an efficient numerical scheme (based on complex variable techniques) to calculate the effective thermal expansion coefficients of a composite containing unidirectional periodic fibers. Moreover, the mechanical behavior of the fibers incorporates interface effects allowing the ensuing analytical model of the composite to accommodate deformations at the nanoscale. The resulting `nanocomposite' is subjected to a uniform temperature variation which leads to periodic deformations within the plane perpendicular to the fibers and uniform deformations along the direction of the fibers. These deformation fields are determined by analyzing a representative unit cell of the composite subsequently leading to the corresponding effective thermal expansion coefficients. Numerical results are illustrated via several physical examples. We find that the influence of interface effects on the effective thermal expansion coefficients (in particular that corresponding to the transverse direction in the plane perpendicular to the fibers) decays rapidly as the fibers become harder. In addition, by comparing the results obtained here with those from effective medium theories, we show that the latter may induce significant errors in the determination of the effective transverse thermal expansion coefficient when the fibers are much softer than the matrix and the fiber volume fraction is relatively high.

  12. Universal Zero Conductivity Condition for Optical Absorption

    CERN Document Server

    Guo, Yu; Jacob, Zubin

    2016-01-01

    Harnessing information and energy from light within a nanoscale mode volume is a fundamental challenge for nanophotonic applications ranging from solar photovoltaics to single photon detectors. Here, we show the existence of a universal condition in materials that sheds light on fundamental limits of electromagnetic to matter energy conversion (transduction). We show that the upper limit of absorption rate (transduction rate) in any nanoscale absorber converting light to matter degrees of freedom is revealed by the zero of optical conductivity at complex frequencies ($\\sigma(\\omega^\\prime + i\\omega^{\\prime\\prime})= 0$). We trace the origin of this universal zero conductivity condition to causality requirements on any passive linear response function and propose an experiment of absorption resonances using plasmonic nanoparticles to experimentally verify this universal zero conductivity condition. Our work is widely applicable to linear systems across the electromagnetic spectrum and allows for systematic opti...

  13. Acoustic absorption by sunspots

    Science.gov (United States)

    Braun, D. C.; Labonte, B. J.; Duvall, T. L., Jr.

    1987-01-01

    The paper presents the initial results of a series of observations designed to probe the nature of sunspots by detecting their influence on high-degree p-mode oscillations in the surrounding photosphere. The analysis decomposes the observed oscillations into radially propagating waves described by Hankel functions in a cylindrical coordinate system centered on the sunspot. From measurements of the differences in power between waves traveling outward and inward, it is demonstrated that sunspots appear to absorb as much as 50 percent of the incoming acoustic waves. It is found that for all three sunspots observed, the amount of absorption increases linearly with horizontal wavenumber. The effect is present in p-mode oscillations with wavelengths both significantly larger and smaller than the diameter of the sunspot umbrae. Actual absorption of acoustic energy of the magnitude observed may produce measurable decreases in the power and lifetimes of high-degree p-mode oscillations during periods of high solar activity.

  14. Chaotic systems with absorption

    CERN Document Server

    Altmann, Eduardo G; Tél, Tamás

    2013-01-01

    Motivated by applications in optics and acoustics we develop a dynamical-system approach to describe absorption in chaotic systems. We introduce an operator formalism from which we obtain (i) a general formula for the escape rate $\\kappa$ in terms of the natural conditionally-invariant measure of the system; (ii) an increased multifractality when compared to the spectrum of dimensions $D_q$ obtained without taking absorption and return times into account; and (iii) a generalization of the Kantz-Grassberger formula that expresses $D_1$ in terms of $\\kappa$, the positive Lyapunov exponent, the average return time, and a new quantity, the reflection rate. Simulations in the cardioid billiard confirm these results.

  15. Photoinduced absorption of polyalkylthienylenevinylenes

    Energy Technology Data Exchange (ETDEWEB)

    Botta, C. (Ist. di Chimica delle Macromolecole (CNR), Milano (Italy)); Bradley, D.D.C. (Cambridge Univ. (United Kingdom). Cavendish Lab.); Friend, R.H. (Cambridge Univ. (United Kingdom). Cavendish Lab.); Musco, A. (Ist. di Scienze Chimiche, Univ. di Urbino (Italy))

    1993-03-15

    We present a photoinduced absorption study of alkyl substituted poly(2,5-thienylenevinylene)s. Three photoinduced states are detected in both the solid state and in solution. The two low-energy bands are assigned to bipolarons, while a third band peaked near the band edge has a different origin. In solution photoexcitated states are very long-lived and we propose that photoexcitation recombine via a solvent-assisted photo-doping mechanism. (orig.)

  16. Hydrogen Absorption by Niobium.

    Science.gov (United States)

    1982-04-13

    incorporate an independent means for ascertaining surface cleanliness (e.g. AES). The form of the absorption curve in Fig. 7 appears to agree with that...very interesting study and is well within the capabilities of the systen designed, if the surface cleanliness can be assured. Wire specimens have a...assessing surface cleanliness would be an important supporting technique for understanding the results of these measurements. The simple kinetic

  17. Exploring the origin of high optical absorption in conjugated polymers

    KAUST Repository

    Vezie, Michelle S.

    2016-05-16

    The specific optical absorption of an organic semiconductor is critical to the performance of organic optoelectronic devices. For example, higher light-harvesting efficiency can lead to higher photocurrent in solar cells that are limited by sub-optimal electrical transport. Here, we compare over 40 conjugated polymers, and find that many different chemical structures share an apparent maximum in their extinction coefficients. However, a diketopyrrolopyrrole-thienothiophene copolymer shows remarkably high optical absorption at relatively low photon energies. By investigating its backbone structure and conformation with measurements and quantum chemical calculations, we find that the high optical absorption can be explained by the high persistence length of the polymer. Accordingly, we demonstrate high absorption in other polymers with high theoretical persistence length. Visible light harvesting may be enhanced in other conjugated polymers through judicious design of the structure.

  18. Sooting flame thermometry using emission/absorption tomography

    Science.gov (United States)

    Hall, Robert J.; Bonczyk, Paul A.

    1990-11-01

    A sooting flame temperature measurement technique has been demonstrated based on emission-absorption tomography. The approach applies the algorithms of Fourier transform tomography to deconvolve local soot absorption coefficient and Planck function (temperature) from sets of parallel line-of-sight measurements. The technique has the advantage that it is experimentally simple and does not require involved data reduction. For small particles, there is also no sensitivity of the inferred temperature to possibly uncertain medium parameters. Its main limitation seems to be that it will not work for vanishingly small absorption, but this could be overcome in practice by seeding and then performing all work at the wavelength of a seed resonance. While in principle limited to optically thin flames, accurate corrections for moderate optical thickness can often be made. A self-consistent comparison of measured global radiation from a sooting ethylene flame with a radiative transfer calculation based on measured temperature and soot absorption parameters has been performed.

  19. Sooting flame thermometry using emission/absorption tomography

    Energy Technology Data Exchange (ETDEWEB)

    Hall, R.J.; Bonczyk, P.A. (United Technologies Research Center, East Hartford, Connecticut 06108 (US))

    1990-11-01

    A sooting flame temperature measurement technique has been demonstrated based on emission--absorption tomography. The approach applies the algorithms of Fourier transform tomography to deconvolve local soot absorption coefficient and Planck function (temperature) from sets of parallel line-of-sight measurements. The technique has the advantage that it is experimentally simple and does not require involved data reduction. For small particles, there is also no sensitivity of the inferred temperature to possibly uncertain medium parameters. Its main limitation seems to be that it will not work well for vanishingly small absorption, but this could be overcome in practice by seeding and then performing all work at the wavelength of a seed resonance. While in principle limited to optically thin flames, accurate corrections for moderate optical thickness can often be made. A self-consistent comparison of measured global radiation from a sooting ethylene flame with a radiative transfer calculation based on measured temperature and soot absorption parameters has been performed.

  20. Path length enhancement in disordered media for increased absorption

    CERN Document Server

    Mupparapu, Rajeshkumar; Svensson, Tomas; Burresi, Matteo; Wiersma, Diederik S

    2015-01-01

    We theoretically and numerically investigate the capability of disordered media to enhance the optical path length in dielectric slabs and augment their light absorption efficiency due to scattering. We first perform a series of Monte Carlo simulations of random walks to determine the path length distribution in weakly to strongly (single to multiple) scattering, non-absorbing dielectric slabs under normally incident light and derive analytical expressions for the path length enhancement in these two limits. Quite interestingly, while multiple scattering is expected to produce long optical paths, we find that media containing a vanishingly small amount of scatterers can still provide high path length enhancements due to the very long trajectories sustained by total internal reflection at the slab interfaces. The path length distributions are then used to calculate the light absorption efficiency of media with varying absorption coefficients. We find that maximum absorption enhancement is obtained at an optima...

  1. Sound absorption performance of natural fibers and their composites

    Institute of Scientific and Technical Information of China (English)

    YANG WeiDong; LI Yan

    2012-01-01

    This research aimed to study the sound absorption properties of natural fibers and their reinforced composites.Sound absorption coefficients of three types of natural fibers,i.e.,ramie,flax and jute fibers and their composites were measured by the two-microphone transfer function technique in the impedance tube.The results were compared with synthetic fibers and their composites.It was found that both natural fibers and their composites had superior capability of noise reduction.The multi-scale and hollow lumen structures of natural fibers contributed to the high sound absorption performance.Moreover,the sound absorption properties of these natural fibers were also calculated by the Delany-Bazley and Garai-Pompoli models.They showed good agreement with the experimental data.It was concluded that multi-functional composite materials can be made by natural fibers so that both the mechanical and acoustical functions can be achieved.

  2. Estimation of the Human Absorption Cross Section Via Reverberation Models

    DEFF Research Database (Denmark)

    Steinböck, Gerhard; Pedersen, Troels; Fleury, Bernard Henri;

    2016-01-01

    Since the presence of persons affects the reverberation time observed for in-room channels, the absorption cross section of a person can be estimated from measurements via Sabine's and Eyring's models for the reverberation time. We propose an estimator relying on the more accurate model by Eyring...... and compare the obtained results to those of Sabine's model. We find that the absorption by persons is large enough to be measured with a wideband channel sounder and that estimates of the human absorption cross section differ for the two models. The obtained values are comparable to values reported...... in the literature. We also suggest the use of controlled environments with low average absorption coefficients to obtain more reliable estimates. The obtained values can be used to predict the change of reverberation time with persons in the propagation environment. This allows prediction of channel characteristics...

  3. Automatic speech segmentation using throat-acoustic correlation coefficients

    Science.gov (United States)

    Mussabayev, Rustam Rafikovich; Kalimoldayev, Maksat N.; Amirgaliyev, Yedilkhan N.; Mussabayev, Timur R.

    2016-11-01

    This work considers one of the approaches to the solution of the task of discrete speech signal automatic segmentation. The aim of this work is to construct such an algorithm which should meet the following requirements: segmentation of a signal into acoustically homogeneous segments, high accuracy and segmentation speed, unambiguity and reproducibility of segmentation results, lack of necessity of preliminary training with the use of a special set consisting of manually segmented signals. Development of the algorithm which corresponds to the given requirements was conditioned by the necessity of formation of automatically segmented speech databases that have a large volume. One of the new approaches to the solution of this task is viewed in this article. For this purpose we use the new type of informative features named TAC-coefficients (Throat-Acoustic Correlation coefficients) which provide sufficient segmentation accuracy and effi- ciency.

  4. Energy Balance of Friction and Friction Coefficient in Energetical Interpretation

    Directory of Open Access Journals (Sweden)

    S.V. Fedorov

    2015-09-01

    Full Text Available Sliding friction energy model is proposed. In this model, generalized mechanism of transformation and dissipation of energy under friction the model of elastic-plastic deformation and fracture contact volumes is considered. Energy model of the process of plastic deformation and destruction of solid bodies is based on the concept of ergodynamic of deformable bodies. Equations of energy balance of friction within the structural and energetic interpretation of deformation are proposed. The energy interpretation of the coefficient of friction is showed. From this position the friction coefficient is the most informative characteristic of the process. Experimental friction curves have been generalized. As a result of the energy analysis of friction, the energy diagram of the structural evolution of the friction surfaces is suggested.

  5. Pressure drop coefficient of laminar Newtonian flow in axisymmetric diffusers

    Energy Technology Data Exchange (ETDEWEB)

    Rosa, S. [Escola Superior de Tecnologia e Gestao, Instituto Politecnico, Campus de Santa Apolonia, 5301-857 Braganca (Portugal)]. E-mail: srosa@ipb.pt; Pinho, F.T. [Centro de Estudos de Fenomenos de Transporte, DEM, Universidade do Minho, Campus de Azurem, 4800-058 Guimaraes (Portugal)]. E-mail: fpinho@fe.up.pt

    2006-04-15

    The laminar flow of Newtonian fluids in axisymmetric diffusers has been numerically investigated to evaluate the pressure-loss coefficient as a function of Reynolds number, diffusion angle and expansion ratio. The numerical simulations were carried out with a finite-volume based code using non-orthogonal collocated grids and second order accurate differencing schemes to discretize all terms of the transport equations. The calculations were carried out for Reynolds numbers between 2 and 200, diffusion angles from 0 deg. to 90 deg. and expansion ratios of 1.5 and 2 and the data are presented in tabular form and as correlations. A simplified 1D theoretical analysis helped explain the various contributions to the loss coefficient and its difference relative to the reversible pressure variation due to differences between the actual and fully developed friction losses, distortions of the velocity profiles and pressure non-uniformity upstream and downstream of the expansion section.

  6. High-resolution continuum source electrothermal atomic absorption spectrometry: Linearization of the calibration curves within a broad concentration range

    Energy Technology Data Exchange (ETDEWEB)

    Katskov, Dmitri, E-mail: katskovda@tut.ac.za [Tshwane University of Technology, Chemistry Department, Pretoria 0001 (South Africa); Hlongwane, Miranda [Tshwane University of Technology, Chemistry Department, Pretoria 0001 (South Africa); Heitmann, Uwe [German Aerospace Center, Rose-Luxemburg Str. 2, 10178 Berlin (Germany); Florek, Stefan [ISAS-Leibniz-Institut fuer Analytische Wissenschaften e.V., Albert-Einstein-Str. 9,12489 Berlin (Germany)

    2012-05-15

    The calculation algorithm suggested provides linearization of the calibration curves in high-resolution continuum source electrothermal atomic absorption spectrometry. The algorithm is based on the modification of the function wavelength-integrated absorbance vs. concentration of analyte vapor in the absorption volume. According to the suggested approach, the absorption line is represented by a triangle for low and trapezium for high analyte vapor concentration in the absorption volume. The respective semi-empirical formulas include two linearization parameters, which depend on properties of the absorption line and characteristics of the atomizer and spectrometer. The parameters can be approximately evaluated from the theory and determined in practice from the original broad-range calibration curve. The parameters were found and the proposed calculation algorithm verified in the experiments on direct determination of Ag, Cd, Cu, Fe, Mn and Pb in the solutions within a concentration ranges from 0.15 to 625 {mu}g{center_dot}L{sup -1} using tube, platform tube and filter furnace atomizers. The use of various atomizers, lines, elements and atomization temperatures made possible the simulation of various practical analytical conditions. It was found that the algorithm and optimal linearization parameters made it possible to obtain for each line and atomizer linear approximations of the calibration curves within 3-4 orders of magnitude with correlation coefficients close to 0.999. The algorithm makes possible to employ a single line for the direct element determination over a broad concentration range. The sources of errors and the possibility of a priori theoretical evaluation of the linearization parameters are discussed. - Highlights: Black-Right-Pointing-Pointer New calculation algorithm for HR-CS ET AAS measurements was proposed and applied. Black-Right-Pointing-Pointer The suggested formulas include two parameters to be determined experimentally. Black

  7. Hybrid passive-active absorption of a microperforated panel in free field conditions.

    Science.gov (United States)

    Cobo, Pedro; Cuesta, María

    2007-06-01

    Although hybrid passive-active absorption in impedance tubes has been widely analyzed, its study in more realistic conditions remains to be accomplished. This letter describes the practical measurement of the passive-active absorption coefficient in a free field. The passive absorber consists of a microperforated panel backed by an air cavity and a wooden panel. A multichannel active system controls the sound pressure in a reduced cell behind the absorber. Measured absorption coefficients between 200 and 400 Hz account for 0.2-0.4 and 0.72-0.75, in the passive and active cases, respectively, and above 500 Hz both are comparable.

  8. Determination of stream reaeration coefficients by use of tracers

    Science.gov (United States)

    Kilpatrick, F.A.; Rathbun, R.E.; Yotsukura, Nobuhiro; Parker, G.W.; DeLong, L.L.

    1989-01-01

    Stream reaeration is the physical absorption of oxygen from the atmosphere by a flowing stream. This is the primary process by which a stream replenishes the oxygen consumed in the biodegradation of organic wastes. Prior to 1965, reaeration rate coefficients could be estimated only by indirect methods. In 1965, a direct method of measuring stream reaeration coefficients was developed whereby a radioactive tracer gas was injected into a stream-the principle being that the tracer gas would be desorbed from the stream inversely to how oxygen would be absorbed. The technique has since been modified by substituting hydrocarbon gases for the radioactive tracer gas. This manual describes the slug-injection and constant-rate-injection methods of measuring gas-tracer desorption. Emphasis is on the use of rhodamine WT dye as a relatively conservative tracer and propane as the nonconservative gas tracer, on planning field tests, on methods of injection, sampling, and analysis, and on techniques for computing desorption and reaeration coefficients.

  9. Corrosion Problems in Absorption Chillers

    Science.gov (United States)

    Stetson, Bruce

    1978-01-01

    Absorption chillers use a lithium bromide solution as the medium of absorption and water as the refrigerant. Discussed are corrosion and related problems, tests and remedies, and cleaning procedures. (Author/MLF)

  10. Determination of Kubelka-Munk scattering and absorption coefficients by diffuse illumination

    NARCIS (Netherlands)

    Molenaar, R; ten Bosch, JJ; Zijp, [No Value

    1999-01-01

    The Kubelka-Munk theory, although it provides an equation that relates the reflection of a sample under diffuse illumination to certain of its properties, does not take boundary reflectance into account. Boundary reflection is always present because there is always a difference between the refractiv

  11. Determination of absorption coefficients of glasses at high tempera-tures, by measuring the thermal emission

    NARCIS (Netherlands)

    Loenen, E.; Van der Tempel, L.

    1996-01-01

    An experimental setup built in 1995 measures the spectral absorptioncoefficient of glass as a function of temperature and wavelength bythe emissive method. The setup was improved, as well as the softwarefor processing the measurement data. The measurement results of quartzwere validated by compariso

  12. Linear and nonlinear absorption coefficients of spherical quantum dot inside external magnetic field

    Science.gov (United States)

    Çakır, Bekir; Yakar, Yusuf; Özmen, Ayhan

    2017-04-01

    We have calculated the wavefunctions and energy eigenvalues of spherical quantum dot with infinite potential barrier inside uniform magnetic field. In addition, we have investigated the magnetic field effect on optical transitions between Zeeman energy states. The results are expressed as a function of dot radius, incident photon energy and magnetic field strength. The results present that, in large dot radii, the external magnetic field affects strongly the optical transitions between Zeeman states. In the strong spatial confinement case, energy level is relatively insensitive to the magnetic field, and electron spatial confinement prevails over magnetic confinement. Also, while m varies from -1 to +1, the peak positions of the optical transitions shift toward higher energy (blueshift).

  13. On PAHs as interstellar grains - Infrared absorption coefficients. [polycyclic aromatic hydrocarbons

    Science.gov (United States)

    Salisbury, D. W.; Allen, J. E., Jr.; Donn, B.; Khanna, R. K.; Moore, W. J.

    1988-01-01

    Consideration is given to the proposal that PAHs are the source of IR continuum and emission features and the visible diffuse bands. Absolute IR cross-sections have been obtained for eight PAHs. The results show that a thermal continuum is not consistent with the spectra obtained, and that an array of normal molecules shows a spectrum that is more complex than the observed spectrum. The cross-sections of the UV spectra are 2-3 orders of magnitude larger than those of the IR spectra. It is suggested that, to account for these observations, structure must be produced in the UV extinction curve.

  14. Determination of absorption coefficients of glasses at high tempera-tures, by measuring the thermal emission

    OpenAIRE

    Loenen, E.; Van der Tempel, L.

    1996-01-01

    An experimental setup built in 1995 measures the spectral absorptioncoefficient of glass as a function of temperature and wavelength bythe emissive method. The setup was improved, as well as the softwarefor processing the measurement data. The measurement results of quartzwere validated by comparison with several literature sources. Theabsorption spectra of Philips 360, GE 180, Schott 8486 Suprax, Corning1724 and Philips 441 glass were determined as a function of temperature.

  15. Linear and nonlinear absorption coefficients of spherical quantum dot inside external magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Çakır, Bekir, E-mail: bcakir@selcuk.edu.tr [Physics Department, Faculty of Science, Selcuk University, Campus, 42075 Konya (Turkey); Yakar, Yusuf, E-mail: yuyakar@yahoo.com [Physics Department, Faculty of Arts and Science, Aksaray University, Campus, 68100 Aksaray (Turkey); Özmen, Ayhan [Physics Department, Faculty of Science, Selcuk University, Campus, 42075 Konya (Turkey)

    2017-04-01

    We have calculated the wavefunctions and energy eigenvalues of spherical quantum dot with infinite potential barrier inside uniform magnetic field. In addition, we have investigated the magnetic field effect on optical transitions between Zeeman energy states. The results are expressed as a function of dot radius, incident photon energy and magnetic field strength. The results present that, in large dot radii, the external magnetic field affects strongly the optical transitions between Zeeman states. In the strong spatial confinement case, energy level is relatively insensitive to the magnetic field, and electron spatial confinement prevails over magnetic confinement. Also, while m varies from −1 to +1, the peak positions of the optical transitions shift toward higher energy (blueshift).

  16. Random incidence absorption coefficients of porous absorbers based on local and extended reaction models

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2011-01-01

    resistivity doubles, a decrease in the required thickness by 25 mm is observed to achieve the same amount of error. For an absorber backed by an air gap, the thickness ratio between the material and air cavity is important. If the absorber thickness is approximately 40% of the cavity depth, the local reaction...... resistivity and the absorber thickness on the difference between the two surface reaction models are examined and discussed. For a porous absorber backed by a rigid surface, the local reaction models give errors of less than 10% if the thickness exceeds 120 mm for a flow resistivity of 5000 Nm-4s. As the flow...... models give errors below 10% even for a low flow resistivity case....

  17. Phantom skin absorption coefficients from spectrophotometric and integrating sphere methods: preliminary comparative results

    CSIR Research Space (South Africa)

    Smit, Jacoba E

    2010-12-01

    Full Text Available Minimalistic or non-invasive diagnosis and treatment of skin disorders requires accurate information regarding skin optical properties. Spectrophotometric and Integrating Sphere (IS) methods are commonly used to extract information regarding...

  18. Use of textile nanofibers to improve the sound absorption coefficient of drilled panels for acoustic applications

    OpenAIRE

    Alba, Jesús; Del Rey, Romina; BERTO, Laura; Hervás, Carlos

    2012-01-01

    International audience; Nowadays combinations of textile materials are common solutions in acoustics aplications as absorbent acoustic materials. Researches developed previously make possible to assert that the nanofibers textile veils combined with the textile wools, will improve the acoustic proprieties of the latter. These kind of nanofibers textile veils are made with a process known as “electrospinning process” Furthermore, these kinds of combinations present an airflow resistivity value...

  19. Determination of absorption coefficients of glasses at high tempera-tures, by measuring the thermal emission

    NARCIS (Netherlands)

    Loenen, E.; Van der Tempel, L.

    1996-01-01

    An experimental setup built in 1995 measures the spectral absorptioncoefficient of glass as a function of temperature and wavelength bythe emissive method. The setup was improved, as well as the softwarefor processing the measurement data. The measurement results of quartzwere validated by compariso

  20. Random incidence absorption coefficients of porous absorbers based on local and extended reaction models

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2011-01-01

    Room surfaces have been extensively modeled as locally reacting in room acoustic predictions although such modeling could yield significant errors under certain conditions. Therefore, this study aims to propose a guideline for adopting the local reaction assumption by comparing predicted random...... incidence acoustical characteristics of typical building elements made of porous materials assuming extended and local reaction. For each surface reaction, five well-established wave propagation models, the Delany-Bazley, Miki, Beranek, Allard-Champoux, and Biot model, are employed. Effects of the flow...

  1. Brillouin-scattering measurements of the acoustic absorption coefficient in liquid CS2

    Science.gov (United States)

    Coakley, R. W.; Detenbeck, R. W.

    1975-01-01

    High-resolution Brillouin spectra were recorded for light scattered at small angles from liquid CS2. The use of a single-mode He-Ne laser, locked in frequency to a Fabry-Perot interferometer, permitted measurements of line widths of the order of 10 MHz for frequencies in the range 300-1000 MHz. These measurements extend previous Brillouin line-width measurements at higher frequencies into the region where relaxation effects are dominant and connect the optical measurements with lower-frequency acoustical data.

  2. Absorption and dispersion of ultrasonic waves

    CERN Document Server

    Herzfeld, Karl F; Massey, H S W; Brueckner, Keith A

    1959-01-01

    Absorption and Dispersion of Ultrasonic Waves focuses on the influence of ultrasonics on molecular processes in liquids and gases, including hydrodynamics, energy exchange, and chemical reactions. The book first offers information on the Stokes-Navier equations of hydrodynamics, as well as equations of motion, viscosity, formal introduction of volume viscosity, and linearized wave equation for a nonviscous fluid. The manuscript then ponders on energy exchange between internal and external degrees of freedom as relaxation phenomenon; effect of slow energy exchange on sound propagation; differe

  3. Evaluations of energy coefficients of Bethe-Weizsacker mass formula

    CERN Document Server

    Basu, D N

    2004-01-01

    A mass fit to the liquid drop model is presented. Coefficients of the volume, surface, coulomb, asymmetry and pairing energy terms of the semiemirical Bethe-Weizsacker mass formula have been determined by furnishing best fit to the observed mass excesses. Different sets of the weighting parameters for liquid drop model Bethe-Weizsacker mass formula have been obtained from minimizations of chisquare and mean square deviation. The recent exerimental and estimated mass excesses from Audi-Wapstra-Thibault atomic mass table have been used for the least square fitting procedure. Some implications of the modifications of parameters have been discussed.

  4. Optical properties and chemical composition of aerosol particles at an urban location: An estimation of the aerosol mass scattering and absorption efficiencies

    Science.gov (United States)

    Titos, G.; Foyo-Moreno, I.; Lyamani, H.; Querol, X.; Alastuey, A.; Alados-Arboledas, L.

    2012-02-01

    We investigated aerosol optical properties, mass concentration and chemical composition over a 1 year period (from March 2006 to February 2007) at an urban site in Southern Spain (Granada, 37.18°N, 3.58°W, 680 m above sea level). Light-scattering and absorption measurements were performed using an integrating nephelometer and a MultiAngle Absorption Photometer (MAAP), respectively, with no aerosol size cut-off and without any conditioning of the sampled air. PM10 and PM1 (ambient air levels of atmospheric particulate matter finer than 10 and 1 microns) were collected with two high volume samplers, and the chemical composition was investigated for all samples. Relative humidity (RH) within the nephelometer was below 50% and the weighting of the filters was also at RH of 50%. PM10 and PM1 mass concentrations showed a mean value of 44 ± 19 μg/m3 and 15 ± 7 μg/m3, respectively. The mineral matter was the major constituent of the PM10-1 fraction (contributing more than 58%) whereas organic matter and elemental carbon (OM+EC) contributed the most to the PM1 fraction (around 43%). The absorption coefficient at 550 nm showed a mean value of 24 ± 9 Mm-1 and the scattering coefficient at 550 nm presented a mean value of 61 ± 25 Mm-1, typical of urban areas. Both the scattering and the absorption coefficients exhibited the highest values during winter and the lowest during summer, due to the increase in the anthropogenic contribution and the lower development of the convective mixing layer during winter. A very low mean value of the single scattering albedo of 0.71 ± 0.07 at 550 nm was calculated, suggesting that urban aerosols in this site contain a large fraction of absorbing material. Mass scattering and absorption efficiencies of PM10 particles exhibited larger values during winter and lower during summer, showing a similar trend to PM1 and opposite to PM10-1. This seasonality is therefore influenced by the variations on PM composition. In addition, the mass

  5. Determining the Gruneisen coefficient for liquids using the PAZ-scan technique

    Science.gov (United States)

    Dantiste, Olivier A.

    Measurement of Gruneisen coefficient is utterly important in developing efficient molecular photoacoustic (PA) contrast agents. It is one of the two parameters that describes how efficient a molecule is in transforming optical energy into sound, the other being absorption coefficient. Using the PAZ-scan technique, the Gruneisen coefficient was obtained for various samples and the values are compared with standard techniques. In a PAZ-scan, the sample is translated through the path of a focused laser beam in small steps while the generated PA signal is recorded. The incident intensity is optimum at the focal point and decreases gradually on either side of the focus. As such, the absorption and the PA signal varies according to the sample properties. Therefore at positions away from the focal point, the incident intensities are weak and the PA signal varies linearly with intensity. A plot of the PA signal versus the intensity is used to obtain the Gruneisen coefficient. Using this technique, the Gruneisen coefficients for crystal violet in two different solvents, food coloring dyes that are dissolved in water were determined. Results show that the linear part of the PAZ-scan can be used to determine the Gruneisen coefficient for liquids.

  6. Optimal design of porous structures for the fastest liquid absorption.

    Science.gov (United States)

    Shou, Dahua; Ye, Lin; Fan, Jintu; Fu, Kunkun

    2014-01-14

    Porous materials engineered for rapid liquid absorption are useful in many applications, including oil recovery, spacecraft life-support systems, moisture management fabrics, medical wound dressings, and microfluidic devices. Dynamic absorption in capillary tubes and porous media is driven by the capillary pressure, which is inversely proportional to the pore size. On the other hand, the permeability of porous materials scales with the square of the pore size. The dynamic competition between these two superimposed mechanisms for liquid absorption through a heterogeneous porous structure may lead to an overall minimum absorption time. In this work, we explore liquid absorption in two different heterogeneous porous structures [three-dimensional (3D) circular tubes and porous layers], which are composed of two sections with variations in radius/porosity and height. The absorption time to fill the voids of porous constructs is expressed as a function of radius/porosity and height of local sections, and the absorption process does not follow the classic Washburn's law. Under given height and void volume, these two-section structures with a negative gradient of radius/porosity against the absorption direction are shown to have faster absorption rates than control samples with uniform radius/porosity. In particular, optimal structural parameters, including radius/porosity and height, are found that account for the minimum absorption time. The liquid absorption in the optimized porous structure is up to 38% faster than in a control sample. The results obtained can be used a priori for the design of porous structures with excellent liquid management property in various fields.

  7. Modeling Complex System Correlation Using Detrended Cross-Correlation Coefficient

    Directory of Open Access Journals (Sweden)

    Keqiang Dong

    2014-01-01

    Full Text Available The understanding of complex systems has become an area of active research for physicists because such systems exhibit interesting dynamical properties such as scale invariance, volatility correlation, heavy tails, and fractality. We here focus on traffic dynamic as an example of a complex system. By applying the detrended cross-correlation coefficient method to traffic time series, we find that the traffic fluctuation time series may exhibit cross-correlation characteristic. Further, we show that two traffic speed time series derived from adjacent sections exhibit much stronger cross-correlations than the two speed series derived from adjacent lanes. Similarly, we also demonstrate that the cross-correlation property between the traffic volume variables from two adjacent sections is stronger than the cross-correlation property between the volume variables of adjacent lanes.

  8. Use of partition coefficients in flow-limited physiologically-based pharmacokinetic modeling.

    Science.gov (United States)

    Thompson, Matthew D; Beard, Daniel A; Wu, Fan

    2012-08-01

    Permeability-limited two-subcompartment and flow-limited, well-stirred tank tissue compartment models are routinely used in physiologically-based pharmacokinetic modeling. Here, the permeability-limited two-subcompartment model is used to derive a general flow-limited case of a two-subcompartment model with the well-stirred tank being a specific case where tissue fractional blood volume approaches zero. The general flow-limited two-subcompartment model provides a clear distinction between two partition coefficients typically used in PBPK: a biophysical partition coefficient and a well-stirred partition coefficient. Case studies using diazepam and cotinine demonstrate that, when the well-stirred tank is used with a priori predicted biophysical partition coefficients, simulations overestimate or underestimate total organ drug concentration relative to flow-limited two-subcompartment model behavior in tissues with higher fractional blood volumes. However, whole-body simulations show predicted drug concentrations in plasma and lower fractional blood volume tissues are relatively unaffected. These findings point to the importance of accurately determining tissue fractional blood volume for flow-limited PBPK modeling. Simulations using biophysical and well-stirred partition coefficients optimized with flow-limited two-subcompartment and well-stirred models, respectively, lead to nearly identical fits to tissue drug distribution data. Therefore, results of whole-body PBPK modeling with diazepam and cotinine indicate both flow-limited models are appropriate PBPK tissue models as long as the correct partition coefficient is used: the biophysical partition coefficient is for use with two-subcompartment models and the well-stirred partition coefficient is for use with the well-stirred tank model.

  9. Perturbative two- and three-loop coefficients from large $\\beta$ Monte Carlo

    CERN Document Server

    Lepage, G P; Shakespeare, N H; Trottier, H D

    2000-01-01

    Perturbative coefficients for Wilson loops and the static quark self-energy are extracted from Monte Carlo simulations at large beta on finite volumes, where all the lattice momenta are large. The Monte Carlo results are in excellent agreement with perturbation theory through second order. New results for third order coefficients are reported. Twisted boundary conditions are used to eliminate zero modes and to suppress Z_3 tunneling.

  10. INVERSE COEFFICIENT PROBLEMS FOR PARABOLIC HEMIVARIATIONAL INEQUALITIES

    Institute of Scientific and Technical Information of China (English)

    Liu Zhenhai; I.Szántó

    2011-01-01

    This paper is devoted to the class of inverse problems for a nonlinear parabolic hemivariational inequality.The unknown coefficient of the operator depends on the gradient of the solution and belongs to a set of admissible coefficients.It is proved that the convergence of solutions for the corresponding direct problems continuously depends on the coefficient convergence.Based on this result the existence of a quasisolution of the inverse problem is obtained.

  11. Variations of intestinal calcium absorption in adult frogs (Rana esculenta). Effect of lysine.

    Science.gov (United States)

    el Maraghi-Ater, H; Hourdry, J; Mesnard, J; Dupuis, Y

    1987-01-01

    Intestinal calcium absorption was investigated in an adult frog (Rana esculenta) by injecting a CaCl2 solution containing 45Ca into the lumen. The 45Ca absorption coefficient in the proximal loop was higher than in the distal loop, only when the CaCl2 solution was left for 4 h. This coefficient increased both in the proximal and distal loops when a 4-h treatment was substituted for a 1-h treatment. The coefficient increased in the whole intestine during the first 2 h of treatment (1 h: 21%; 2 h: 55%) and remained stable afterwards in our experimental conditions. The intestinal calcium absorption increase occurred early in the presence of L-lysine (100 mM), since the coefficient already reached its maximum value (52%) after a 1-h treatment.

  12. The average free volume model for liquids

    CERN Document Server

    Yu, Yang

    2014-01-01

    In this work, the molar volume thermal expansion coefficient of 59 room temperature ionic liquids is compared with their van der Waals volume Vw. Regular correlation can be discerned between the two quantities. An average free volume model, that considers the particles as hard core with attractive force, is proposed to explain the correlation in this study. A combination between free volume and Lennard-Jones potential is applied to explain the physical phenomena of liquids. Some typical simple liquids (inorganic, organic, metallic and salt) are introduced to verify this hypothesis. Good agreement from the theory prediction and experimental data can be obtained.

  13. DIFFERENCE SCHEMES BASING ON COEFFICIENT APPROXIMATION

    Institute of Scientific and Technical Information of China (English)

    MOU Zong-ze; LONG Yong-xing; QU Wen-xiao

    2005-01-01

    In respect of variable coefficient differential equations, the equations of coefficient function approximation were more accurate than the coefficient to be frozen as a constant in every discrete subinterval. Usually, the difference schemes constructed based on Taylor expansion approximation of the solution do not suit the solution with sharp function.Introducing into local bases to be combined with coefficient function approximation, the difference can well depict more complex physical phenomena, for example, boundary layer as well as high oscillatory, with sharp behavior. The numerical test shows the method is more effective than the traditional one.

  14. Magnetoelectric voltage coefficients of magnetoelectric composites

    Institute of Scientific and Technical Information of China (English)

    WAN Yong-ping; ZHONG Zheng; QIU Jin-hao

    2006-01-01

    The magnetoelectric(ME) effect of the particulate magnetostrictive/piezoelectric composite was theoretically studied. The dependence of the ME voltage coefficients on the material properties of the magnetostrictive phase was discussed. The permittivity,permeability and the elastic modulus of the magnetostrictive phase generally have obvious influences on the ME voltage coefficients. The magnetostrictive phase with a large permittivity,large permeability or stiffer modulus will respectively contribute to the higher ME voltage coefficients. For a certain kind of piezoelectric matrix,the ME voltage coefficients can be improved to some extent by choosing those magnetostrictive materials with large permittivity,permeability or high elastic modulus.

  15. Why the Method of Undetermined Coefficients Works.

    Science.gov (United States)

    Ross, Clay C., Jr.

    1991-01-01

    This note presents a simple theorem which explains why the method of undetermined coefficients works in finding a particular solution, both for differential equations and difference equations. (Author)

  16. Comparing linear probability model coefficients across groups

    DEFF Research Database (Denmark)

    Holm, Anders; Ejrnæs, Mette; Karlson, Kristian Bernt

    2015-01-01

    This article offers a formal identification analysis of the problem in comparing coefficients from linear probability models between groups. We show that differences in coefficients from these models can result not only from genuine differences in effects, but also from differences in one or more...... of the following three components: outcome truncation, scale parameters and distributional shape of the predictor variable. These results point to limitations in using linear probability model coefficients for group comparisons. We also provide Monte Carlo simulations and real examples to illustrate...... these limitations, and we suggest a restricted approach to using linear probability model coefficients in group comparisons....

  17. Why the Method of Undetermined Coefficients Works.

    Science.gov (United States)

    Ross, Clay C., Jr.

    1991-01-01

    This note presents a simple theorem which explains why the method of undetermined coefficients works in finding a particular solution, both for differential equations and difference equations. (Author)

  18. Effective stress coefficient for uniaxial strain condition

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Fabricius, Ida Lykke

    2012-01-01

    the reason for change in effective stress coefficient under stress. Our model suggests that change in effective stress coefficient will be higher at uniaxial stress condition than at hydrostatic condition. We derived equations from the original definition of Biot to estimate effective stress coefficient from...... one dimensional rock mechanical deformation. We further investigated the effect of boundary condition on the stress dependency of effective stress coefficient and discussed its application in reservoir study. As stress field in the reservoirs are most unlikely to be hydrostatic, effective stress...

  19. Renormalized Volume

    Science.gov (United States)

    Gover, A. Rod; Waldron, Andrew

    2017-09-01

    We develop a universal distributional calculus for regulated volumes of metrics that are suitably singular along hypersurfaces. When the hypersurface is a conformal infinity we give simple integrated distribution expressions for the divergences and anomaly of the regulated volume functional valid for any choice of regulator. For closed hypersurfaces or conformally compact geometries, methods from a previously developed boundary calculus for conformally compact manifolds can be applied to give explicit holographic formulæ for the divergences and anomaly expressed as hypersurface integrals over local quantities (the method also extends to non-closed hypersurfaces). The resulting anomaly does not depend on any particular choice of regulator, while the regulator dependence of the divergences is precisely captured by these formulæ. Conformal hypersurface invariants can be studied by demanding that the singular metric obey, smoothly and formally to a suitable order, a Yamabe type problem with boundary data along the conformal infinity. We prove that the volume anomaly for these singular Yamabe solutions is a conformally invariant integral of a local Q-curvature that generalizes the Branson Q-curvature by including data of the embedding. In each dimension this canonically defines a higher dimensional generalization of the Willmore energy/rigid string action. Recently, Graham proved that the first variation of the volume anomaly recovers the density obstructing smooth solutions to this singular Yamabe problem; we give a new proof of this result employing our boundary calculus. Physical applications of our results include studies of quantum corrections to entanglement entropies.

  20. Broadband solar absorption enhancement via periodic nanostructuring of electrodes.

    KAUST Repository

    Adachi, Michael M

    2013-10-14

    Solution processed colloidal quantum dot (CQD) solar cells have great potential for large area low-cost photovoltaics. However, light utilization remains low mainly due to the tradeoff between small carrier transport lengths and longer infrared photon absorption lengths. Here, we demonstrate a bottom-illuminated periodic nanostructured CQD solar cell that enhances broadband absorption without compromising charge extraction efficiency of the device. We use finite difference time domain (FDTD) simulations to study the nanostructure for implementation in a realistic device and then build proof-of-concept nanostructured solar cells, which exhibit a broadband absorption enhancement over the wavelength range of λ = 600 to 1,100 nm, leading to a 31% improvement in overall short-circuit current density compared to a planar device containing an approximately equal volume of active material. Remarkably, the improved current density is achieved using a light-absorber volume less than half that typically used in the best planar devices.

  1. Absorption in dielectric models

    CERN Document Server

    Churchill, R J

    2015-01-01

    We develop a classical microscopic model of a dielectric. The model features nonlinear interaction terms between polarizable dipoles and lattice vibrations. The lattice vibrations are found to act as a pseudo-reservoir, giving broadband absorption of electromagnetic radiation without the addition of damping terms in the dynamics. The effective permittivity is calculated using a perturbative iteration method and is found to have the form associated with real dielectrics. Spatial dispersion is naturally included in the model and we also calculate the wavevector dependence of the permittivity.

  2. Geospatial Absorption and Regional Effects

    Directory of Open Access Journals (Sweden)

    IOAN MAC

    2009-01-01

    Full Text Available The geospatial absorptions are characterized by a specific complexity both in content and in their phenomenological and spatial manifestation fields. Such processes are differentiated according to their specificity to pre-absorption, absorption or post-absorption. The mechanisms that contribute to absorption are extremely numerous: aggregation, extension, diffusion, substitution, resistivity (resilience, stratification, borrowings, etc. Between these mechanisms frequent relations are established determining an amplification of the process and of its regional effects. The installation of the geographic osmosis phenomenon in a given territory (a place for example leads to a homogenization of the geospatial state and to the installation of the regional homogeneity.

  3. In vivo imaging of scattering and absorption properties of exposed brain using a digital red-green-blue camera

    Science.gov (United States)

    Nishidate, Izumi; Yoshida, Keiichiro; Kawauchi, Satoko; Sato, Shunichi; Sato, Manabu

    2014-03-01

    We investigate a method to estimate the spectral images of reduced scattering coefficients and the absorption coefficients of in vivo exposed brain tissues in the range from visible to near-infrared wavelength (500-760 nm) based on diffuse reflectance spectroscopy using a digital RGB camera. In the proposed method, the multi-spectral reflectance images of in vivo exposed brain are reconstructed from the digital red, green blue images using the Wiener estimation algorithm. The Monte Carlo simulation-based multiple regression analysis for the absorbance spectra is then used to specify the absorption and scattering parameters of brain tissue. In this analysis, the concentration of oxygenated hemoglobin and that of deoxygenated hemoglobin are estimated as the absorption parameters whereas the scattering amplitude a and the scattering power b in the expression of μs'=aλ-b as the scattering parameters, respectively. The spectra of absorption and reduced scattering coefficients are reconstructed from the absorption and scattering parameters, and finally, the spectral images of absorption and reduced scattering coefficients are estimated. The estimated images of absorption coefficients were dominated by the spectral characteristics of hemoglobin. The estimated spectral images of reduced scattering coefficients showed a broad scattering spectrum, exhibiting larger magnitude at shorter wavelengths, corresponding to the typical spectrum of brain tissue published in the literature. In vivo experiments with exposed brain of rats during CSD confirmed the possibility of the method to evaluate both hemodynamics and changes in tissue morphology due to electrical depolarization.

  4. Study on Optical Absorption Behavior of Dyestuff in Fabric

    Institute of Scientific and Technical Information of China (English)

    YANG Hong-ying; ZHU Su-kang; ZUO Lei; ZHU Ping-ping; PAN Ning

    2008-01-01

    Fabric is a kind of turbid materials with strong light scattering,to which the Kubelka-Munk theory can be applied to describe it optical behavior.In this paper,the light absorption coefficients of dyestuff in fabrics are obtained by test and calculation thnmgh a special method proposed by the authors.Then the optical behaviours of dyestuff in fabric are studied.Results show that,the absorption coeffident of dye in fabric is non-scalable and exponential to dye concentrafion in fabric which is totally different from that of the dye in transparent medm like water.

  5. Research on the sound absorption performance of metal rubber material

    Institute of Scientific and Technical Information of China (English)

    XIA Yuhong; JIANG Hongyuan; WU Guoqi; E.A. Izzheurov

    2009-01-01

    The sound absorption performance of Metal Rubber material was studied theoreti-cally and experimentally. The acoustic impedance rate and the sound absorption coefficient were derived based on the acoustic parameters of metal rubber material. The relation of structure constant, compressibility modulus and structural parameters was investigated experimentally. The results showed that the specimen of metal rubber with the same mean porosity diame-ter had the same structure constant. For the same structural parameters, the compressibility modulus of metal rubber material was approximately constant in certain frequency range. The calculated acoustic parameters are in good agreement with the experimental results, demon-strating the effectiveness of theoretical models.

  6. Optical absorption of sodium copper chlorophyllin thin films in UV-vis-NIR region.

    Science.gov (United States)

    Farag, A A M

    2006-11-01

    The optical absorption studies of sodium copper chlorophyllin thin films (SCC), prepared by spray pyrolysis, in the UV-vis-NIR region was reported for the first time. Several new discrete transitions are observed in the UV-vis region of the spectra in addition to a strong continuum component in the IR region. The spectra of the infrared absorption allow characterization of vibration modes for the powder and thin films of SCC. The absorption spectrum recorded in the UV-vis region showed different absorption bands, namely the Soret (B) in the region 340-450 nm and Q-band in the region 600-700 nm and other band labeled N in the 240-320 region. Some important spectral parameters namely optical absorption coefficient (alpha), molar extinction coefficient (epsilon(molar)), oscillator strength (f), electric dipole strength (q(2)) and absorption half bandwidth (Deltalambda) of the principle optical transitions were evaluated. The analysis of the absorption coefficient in the absorption region revealed direct transitions and the energy gap was estimated as 1.63 eV. Discussion of the obtained results and their comparison with the previous published data are also given.

  7. Absorption Spectra of Astaxanthin Aggregates

    CERN Document Server

    Olsina, Jan; Minofar, Babak; Polivka, Tomas; Mancal, Tomas

    2012-01-01

    Carotenoids in hydrated polar solvents form aggregates characterized by dramatic changes in their absorption spectra with respect to monomers. Here we analyze absorption spectra of aggregates of the carotenoid astaxanthin in hydrated dimethylsulfoxide. Depending on water content, two types of aggregates were produced: H-aggregates with absorption maximum around 390 nm, and J-aggregates with red-shifted absorption band peaking at wavelengths >550 nm. The large shifts with respect to absorption maximum of monomeric astaxanthin (470-495 nm depending on solvent) are caused by excitonic interaction between aggregated molecules. We applied molecular dynamics simulations to elucidate structure of astaxanthin dimer in water, and the resulting structure was used as a basis for calculations of absorption spectra. Absorption spectra of astaxanthin aggregates in hydrated dimethylsulfoxide were calculated using molecular exciton model with the resonance interaction energy between astaxanthin monomers constrained by semi-e...

  8. Chromatographic determination of the diffusion coefficients of light hydrocarbons in polymers

    Science.gov (United States)

    Yakubenko, E. E.; Korolev, A. A.; Chapala, P. P.; Bermeshev, M. V.; Kanat'eva, A. Yu.; Kurganov, A. A.

    2017-01-01

    Gas-chromatographic determination of the diffusion coefficients that allows for the compressibility of the mobile phase has been suggested. The diffusion coefficients were determined for light hydrocarbons C1-C4 in four polymers with a high free volume, which are candidates for use as gas-separating membranes. The diffusion coefficients calculated from chromatographic data were shown to be one or two orders of magnitude smaller than the values obtained by the membrane method. This may be due to the presence of an additional flow through the membrane caused by the pressure gradient across the membrane in membrane methods.

  9. Retrieval of ocean subsurface particulate backscattering coefficient from space-borne CALIOP lidar measurements.

    Science.gov (United States)

    Lu, Xiaomei; Hu, Yongxiang; Pelon, Jacques; Trepte, Charles; Liu, Katie; Rodier, Sharon; Zeng, Shan; Lucker, Patricia; Verhappen, Ron; Wilson, Jamie; Audouy, Claude; Ferrier, Christophe; Haouchine, Said; Hunt, Bill; Getzewich, Brian

    2016-12-12

    A new approach has been proposed to determine ocean subsurface particulate backscattering coefficient bbp from CALIOP 30° off-nadir lidar measurements. The new method also provides estimates of the particle volume scattering function at the 180° scattering angle. The CALIOP based layer-integrated lidar backscatter and particulate backscattering coefficients are compared with the results obtained from MODIS ocean color measurements. The comparison analysis shows that ocean subsurface lidar backscatter and particulate backscattering coefficient bbp can be accurately obtained from CALIOP lidar measurements, thereby supporting the use of space-borne lidar measurements for ocean subsurface studies.

  10. The HI absorption 'Zoo'

    CERN Document Server

    Gereb, K; Morganti, R; Oosterloo, T A

    2014-01-01

    We present an analysis of the HI absorption in a sample of 101 flux-selected radio AGN (S_1.4 GHz > 50 mJy) observed with the Westerbork Synthesis Radio Telescope (WSRT). HI absorption is detected in 32 galaxies, showing a broad variety of widths, shapes and kinematical properties. We characterize the HI spectra of the individual detections using the busy function (Westmeier et al. 2014). With the goal of identifying different morphological structures of HI, we study the kinematical and radio source properties of the detections as function of their width. Narrow lines (FWHM = 500 km/s). These detections are good candidates for being HI outflows. The detection rate of HI outflows is 5 percent in the total radio AGN sample. This fraction represents a lower limit, however it could suggests that, if outflows are a characteristic phenomenon of all radio sources, they would have a short depletion timescale compared to the lifetime of the AGN. Blueshifted and broad/asymmetric lines are more often present among young...

  11. Contributions of nitrated aromatic compounds to the light absorption of water-soluble and particulate brown carbon in different atmospheric environments in Germany and China

    Science.gov (United States)

    Teich, Monique; van Pinxteren, Dominik; Wang, Michael; Kecorius, Simonas; Wang, Zhibin; Müller, Thomas; Močnik, Griša; Herrmann, Hartmut

    2017-02-01

    The relative contributions of eight nitrated aromatic compounds (NACs: nitrophenols and nitrated salicylic acids) to the light absorption of aqueous particle extracts and particulate brown carbon were determined from aerosol particle samples collected in Germany and China.High-volume filter samples were collected during six campaigns, performed at five locations in two seasons: (I) two campaigns with strong influence of biomass-burning (BB) aerosol at the TROPOS institute (winter, 2014, urban background, Leipzig, Germany) and the Melpitz research site (winter, 2014, rural background); (II) two campaigns with strong influence from biogenic emissions at Melpitz (summer, 2014) and the forest site Waldstein (summer, 2014, Fichtelgebirge, Germany); and (III) two CAREBeijing-NCP campaigns at Xianghe (summer, 2013, anthropogenic polluted background) and Wangdu (summer, 2014, anthropogenic polluted background with a distinct BB episode), both in the North China Plain. The filter samples were analyzed for NAC concentrations and the light absorption of aqueous filter extracts was determined. Light absorption properties of particulate brown carbon were derived from a seven-wavelength aethalometer during the campaigns at TROPOS (winter) and Waldstein (summer). The light absorption of the aqueous filter extracts was found to be pH dependent, with larger values at higher pH. In general, the aqueous light absorption coefficient (Abs370) ranged from 0.21 to 21.8 Mm-1 under acidic conditions and 0.63 to 27.2 Mm-1 under alkaline conditions, over all campaigns. The observed mass absorption efficiency (MAE370) was in a range of 0.10-1.79 m2 g-1 and 0.24-2.57 m2 g-1 for acidic and alkaline conditions, respectively. For MAE370 and Abs370, the observed values were higher in winter than in summer, in agreement with other studies. The lowest MAE was observed for the Waldstein (summer) campaign (average of 0.17 ± 0.03 m2 g-1), indicating that freshly emitted biogenic aerosols are only

  12. Absorption characteristics of aerosols over the northwestern region of India: Distinct seasonal signatures of biomass burning aerosols and mineral dust

    Science.gov (United States)

    Gogoi, Mukunda M.; Suresh Babu, S.; Krishna Moorthy, K.; Manoj, M. R.; Chaubey, Jai Prakash

    2013-07-01

    Continuous measurements of aerosol black carbon (BC) mass concentrations made over a period of 3 years from a semi-arid, near-coastal, remote and sparsely inhabited location along with satellite-based data of aerosol absorption index, optical depth and extinction profiles in western India are used to characterize the distinct nature of aerosols near the surface and in the free troposphere and their seasonality. Despite being far remote and sparsely inhabited, significant levels of BC are observed in the ambient during winter (1.45 ± 0.71 μg m-3) attributed to biomass burning aerosols, advected to the site from the north and west; while during summer the concentrations are far reduced (0.23 ± 0.11 μg m-3) and represent the apparent background concentrations. The spectral absorption coefficients suggest the BC during summer be mostly of fossil fuel combustions. The strong convective boundary layer dynamics produces significant diurnal variation during winter and modulates to a lesser extent the seasonal variation. Examination of aerosol (absorption) index from OMI data for the study period showed a seasonal pattern that is almost opposite to that seen at the surface; with high aerosol index in summer, showing a significant difference between the surface and columnar aerosol types in summer. MISR and MODIS-derived columnar AOD follow the OMI pattern. Analysis of the vertical profiles of aerosol extinction and volume depolarization ratio (VDR), derived from CALIPSO data indicates the presence of strong dust layers with VDR ˜ 0.3 in the altitude region 4-6 km, contributing to the high aerosol index in the OMI data, while the surface measurements show absorptive properties representing fossil fuel BC aerosols.

  13. Drag Coefficient of Thin Flexible Cylinder

    Science.gov (United States)

    Subramanian, Chelakara; Gurram, Harika

    2015-11-01

    Measurements of drag coefficients of thin flexible cylindrical wires are described for the Reynolds number range between 250 - 1000. Results indicate that the coefficient values are about 20 to 30 percent lower than the reported laminar flow values for rigid cylinders. Possible fluid dynamics mechanism causing the reduction in drag will be discussed.

  14. Problems with Discontinuous Diffusion/Dispersion Coefficients

    Directory of Open Access Journals (Sweden)

    Stefano Ferraris

    2012-01-01

    accurate on smooth solutions and based on a special numerical treatment of the diffusion/dispersion coefficients that makes its application possible also when such coefficients are discontinuous. Numerical experiments confirm the convergence of the numerical approximation and show a good behavior on a set of benchmark problems in two space dimensions.

  15. A gain-coefficient switched Alexandrite laser

    NARCIS (Netherlands)

    Lee, Chris J.; Slot, van der Peter J.M.; Boller, Klaus-J.

    2013-01-01

    We report on a gain-coefficient switched Alexandrite laser. An electro-optic modulator is used to switch between high and low gain states by making use of the polarization dependent gain of Alexandrite. In gain-coefficient switched mode, the laser produces 85 ns pulses with a pulse energy of 240 mJ

  16. Alternatives to Pearson's and Spearman's Correlation Coefficients

    OpenAIRE

    Smarandache, Florentin

    2008-01-01

    This article presents several alternatives to Pearson's correlation coefficient and many examples. In the samples where the rank in a discrete variable counts more than the variable values, the mixtures that we propose of Pearson's and Spearman's correlation coefficients give better results.

  17. Efficient Estimation in Heteroscedastic Varying Coefficient Models

    Directory of Open Access Journals (Sweden)

    Chuanhua Wei

    2015-07-01

    Full Text Available This paper considers statistical inference for the heteroscedastic varying coefficient model. We propose an efficient estimator for coefficient functions that is more efficient than the conventional local-linear estimator. We establish asymptotic normality for the proposed estimator and conduct some simulation to illustrate the performance of the proposed method.

  18. Estimating Runoff Coefficients Using Weather Radars

    DEFF Research Database (Denmark)

    Ahm, Malte; Thorndahl, Søren Liedtke; Rasmussen, Michael R.

    2012-01-01

    This paper presents a method for estimating runoff coefficients of urban drainage catchments based on a combination of high resolution weather radar data and insewer flow measurements. By utilising the spatial variability of the precipitation it is possible to estimate the runoff coefficients...

  19. Heat transfer coefficient for boiling carbon dioxide

    DEFF Research Database (Denmark)

    Knudsen, Hans Jørgen Høgaard; Jensen, Per Henrik

    1998-01-01

    Heat transfer coefficient and pressure drop for boiling carbon dioxide (R744) flowing in a horizontal pipe has been measured. The calculated heat transfer coeeficient has been compared with the Chart correlation of Shah. The Chart Correlation predits too low heat transfer coefficient but the ratio...

  20. Estimating Runoff Coefficients Using Weather Radars

    DEFF Research Database (Denmark)

    Ahm, Malte; Thorndahl, Søren Liedtke; Rasmussen, Michael R.;

    2012-01-01

    This paper presents a method for estimating runoff coefficients of urban drainage catchments based on a combination of high resolution weather radar data and insewer flow measurements. By utilising the spatial variability of the precipitation it is possible to estimate the runoff coefficients...