On multi-spectral quantitative photoacoustic tomography in diffusive regime

International Nuclear Information System (INIS)

Bal, Guillaume; Ren, Kui

2012-01-01

The objective of quantitative photoacoustic tomography (qPAT) is to reconstruct the diffusion, absorption and Grüneisen thermodynamic coefficients of heterogeneous media from knowledge of the interior absorbed radiation. It has been shown in Bal and Ren (2011 Inverse Problems 27 075003), based on diffusion theory, that with data acquired at one given wavelength, all three coefficients cannot be reconstructed uniquely. In this work, we study the multi-spectral qPAT problem and show that when multiple wavelength data are available, all coefficients can be reconstructed simultaneously under minor prior assumptions. Moreover, the reconstructions are shown to be very stable. We present some numerical simulations that support the theoretical results. (paper)

Spectral analysis and multigrid preconditioners for two-dimensional space-fractional diffusion equations

Science.gov (United States)

Moghaderi, Hamid; Dehghan, Mehdi; Donatelli, Marco; Mazza, Mariarosa

2017-12-01

Fractional diffusion equations (FDEs) are a mathematical tool used for describing some special diffusion phenomena arising in many different applications like porous media and computational finance. In this paper, we focus on a two-dimensional space-FDE problem discretized by means of a second order finite difference scheme obtained as combination of the Crank-Nicolson scheme and the so-called weighted and shifted Grünwald formula. By fully exploiting the Toeplitz-like structure of the resulting linear system, we provide a detailed spectral analysis of the coefficient matrix at each time step, both in the case of constant and variable diffusion coefficients. Such a spectral analysis has a very crucial role, since it can be used for designing fast and robust iterative solvers. In particular, we employ the obtained spectral information to define a Galerkin multigrid method based on the classical linear interpolation as grid transfer operator and damped-Jacobi as smoother, and to prove the linear convergence rate of the corresponding two-grid method. The theoretical analysis suggests that the proposed grid transfer operator is strong enough for working also with the V-cycle method and the geometric multigrid. On this basis, we introduce two computationally favourable variants of the proposed multigrid method and we use them as preconditioners for Krylov methods. Several numerical results confirm that the resulting preconditioning strategies still keep a linear convergence rate.

Spectral response of crystalline acetanilide and N -methylacetamide: Vibrational self-trapping in hydrogen-bonded crystals

Science.gov (United States)

Edler, Julian; Hamm, Peter

2004-06-01

Femtosecond pump-probe and Fourier transform infrared spectroscopy is applied to compare the spectral response of the amide I band and the NH-stretching band of acetanilide (ACN) and N -methylacetamide (NMA), as well as their deuterated derivatives. Both molecules form hydrogen-bonded molecular crystals that are regarded to be model systems for polypeptides and proteins. The amide I bands of both ACN and NMA show a temperature-dependent sideband, while the NH bands are accompanied by a sequence of equidistantly spaced satellite peaks. These spectral anomalies are interpreted as a signature of vibrational self-trapping. Two different types of states can be identified in both crystals in the pump-probe signal: a delocalized free-exciton state and a set of localized self-trapped states. The phonons that mediate self-trapping in ACN and deuterated ACN are identified by their temperature dependence, confirming our previous results. The study shows that the substructure of the NH band in NMA (amide A and amide B bands) originates, at least partly, from vibrational self-trapping and not, as often assumed, from a Fermi resonance.

Spectral nodal method for one-speed X,Y-geometry Eigenvalue diffusion problems

International Nuclear Information System (INIS)

Dominguez, Dany S.; Lorenzo, Daniel M.; Hernandez, Carlos G.; Barros, Ricardo C.; Silva, Fernando C. da

2001-01-01

Presented here is a new numerical nodal method for steady-state multidimensional neutron diffusion equation in rectangular geometry. Our method is based on a spectral analysis of the transverse-integrated nodal diffusion equations. These equations are obtained by integrating the diffusion equation in X and Y directions, and then considering flat approximations for the transverse leakage terms. These flat approximations are the only approximations that we consider in this method; as a result the numerical solutions are completely free from truncation errors in slab geometry. We show numerical results to illustrate the method's accuracy for coarse mesh calculations in a heterogeneous medium. (author)

The experimental vibrational infrared spectrum of lemon peel and simulation of spectral properties of the plant cell wall

Science.gov (United States)

Berezin, K. V.; Shagautdinova, I. T.; Chernavina, M. L.; Novoselova, A. V.; Dvoretskii, K. N.; Likhter, A. M.

2017-09-01

The experimental vibrational IR spectra of the outer part of lemon peel are recorded in the range of 3800-650 cm-1. The effect of artificial and natural dehydration of the peel on its vibrational spectrum is studied. It is shown that the colored outer layer of lemon peel does not have a noticeable effect on the vibrational spectrum. Upon 28-day storage of a lemon under natural laboratory conditions, only sequential dehydration processes are reflected in the vibrational spectrum of the peel. Within the framework of the theoretical DFT/B3LYP/6-31G(d) method, a model of a plant cell wall is developed consisting of a number of polymeric molecules of dietary fibers like cellulose, hemicellulose, pectin, lignin, some polyphenolic compounds (hesperetin glycoside-flavonoid), and a free water cluster. Using a supermolecular approach, the spectral properties of the wall of a lemon peel cell was simulated, and a detailed theoretical interpretation of the recorded vibrational spectrum is given.

APPLICATION OF THE SPECTRUM ANALYSIS WITH USING BERG METHOD TO DEVELOPED SPECIAL SOFTWARE TOOLS FOR OPTICAL VIBRATION DIAGNOSTICS SYSTEM

Directory of Open Access Journals (Sweden)

E. O. Zaitsev

2016-01-01

Full Text Available The objective of this paper is development and experimental verification special software of spectral analysis. Spectral analysis use of controlled vibrations objects. Spectral analysis of vibration based on use maximum-entropy autoregressive method of spectral analysis by the Berg algorithm. For measured signals use preliminary analysis based on regression analysis. This analysis of the signal enables to eliminate uninformative parameters such as – the noise and the trend. For preliminary analysis developed special software tools. Non-contact measurement of mechanical vibrations parameters rotating diffusely-reflecting surfaces used in circumstances where the use of contact sensors difficult or impossible for a number of reasons, including lack of access to the object, the small size of the controlled area controlled portion has a high temperature or is affected by strong electromagnetic fields. For control use offered laser measuring system. This measuring system overcomes the shortcomings interference or Doppler optical measuring systems. Such as measure the large amplitude and inharmonious vibration. On the basis of the proposed methods developed special software tools for use measuring laser system. LabVIEW using for developed special software. Experimental research of the proposed method of vibration signals processing is checked in the analysis of the diagnostic information obtained by measuring the vibration system grinding diamond wheel cold solid tungsten-containing alloy TK8. A result of work special software tools was complex spectrum obtained «purified» from non-informative parameters. Spectrum of the signal corresponding to the vibration process observed object. 

Stimulated nuclear spin echos and spectral diffusion in glasses

International Nuclear Information System (INIS)

Borges, N.M.; Engelsberg, M.

1984-01-01

Experimental results of stimulated nuclear spin echos decay in glasses are presented. The measurements were performed in B 2 O 3 glasses, at the 23Na and 11 B resonance lines. The data analysis allows the study of Spectral diffusion at an inhomogeneous nuclear magnetic (NMR) resonance line, broadened for a desordered system of nuclear spins. A model is proposed to explain the time constants, and the particular form of the decay. (A.C.A.S.) [pt

Calculating spectral direct solar irradiance, diffuse and global in Heredia, Costa Rica

International Nuclear Information System (INIS)

Wright, Jaime

2008-01-01

A spectral model under conditions of clear skies has described the flow of solar irradiation and is verified experimentally in Heredia, Costa Rica. A description of the model is presented by comparing its results with experimental measurements. The model has calculated the spectral flows of the global solar irradiation, direct and diffuse incident on a horizontal surface. Necessary input data include latitude, altitude, surface albedo as characteristics of a locality, and atmospheric characteristics: turbidity, precipitable water vapor, total ozone content and the optical thickness of a particular subject. The results show satisfactory values. (author) [es

Classification of Error-Diffused Halftone Images Based on Spectral Regression Kernel Discriminant Analysis

Directory of Open Access Journals (Sweden)

Zhigao Zeng

2016-01-01

Full Text Available This paper proposes a novel algorithm to solve the challenging problem of classifying error-diffused halftone images. We firstly design the class feature matrices, after extracting the image patches according to their statistics characteristics, to classify the error-diffused halftone images. Then, the spectral regression kernel discriminant analysis is used for feature dimension reduction. The error-diffused halftone images are finally classified using an idea similar to the nearest centroids classifier. As demonstrated by the experimental results, our method is fast and can achieve a high classification accuracy rate with an added benefit of robustness in tackling noise.

Discrimination of periodontal diseases using diffuse reflectance spectral intensity ratios

Science.gov (United States)

Chandra Sekhar, Prasanth; Betsy, Joseph; Presanthila, Janam; Subhash, Narayanan

2012-02-01

This clinical study was to demonstrate the applicability of diffuse reflectance (DR) intensity ratio R620/R575 in the quantification and discrimination of periodontitis and gingivitis from healthy gingiva. DR spectral measurements were carried out with white-light illumination from 70 healthy sites in 30 healthy volunteers, and 63 gingivitis- and 58 periodontitis-infected sites in 60 patients. Clinical parameters such as probing pocket depth, clinical attachment level, and gingival index were recorded in patient population. Diagnostic accuracies for discrimination of gingivitis and periodontitis from healthy gingiva were determined by comparison of spectral signatures with clinical parameters. Divergence of average DR spectral intensity ratio between control and test groups was studied using analysis of variance. The mean DR spectrum on normalization at 620 nm showed marked differences between healthy tissue, gingivitis, and periodontitis. Hemoglobin concentration and apparent SO2 (oxygen saturation) were also calculated for healthy, gingivitis, and periodontitis sites. DR spectral intensities at 545 and 575 nm showed a decreasing trend with progression of disease. Among the various DR intensity ratios studied, the R620/R575 ratio provided a sensitivity of 90% and specificity of 94% for discrimination of healthy tissues from gingivitis and a sensitivity of 91% and specificity of 100% for discrimination of gingivitis from periodontitis.

Vibration signature analysis of compressors in the gaseous diffusion process for uranium enrichment

International Nuclear Information System (INIS)

Harbarger, W.B.

1975-01-01

Continuous operation of several thousand axial-flow and centrifugal compressors is vital to the gaseous diffusion process for uranium enrichment. Vibration signature analysis using a minicomputer-based Fast Fourier Transform Analyzer is being applied to the evaluation and surveillance of compressor performance at the Portsmouth Gaseous Diffusion Plant. Three areas of application include: (1) new blade design and prototype compressor evaluation; (2) corrective and preventive maintenance of machinery components; and (3) evaluation of machinery health. The present system is being used to monitor signals from accelerometers mounted on the load-bearing housings of 16 on-line compressors. These signals are transmitted by hard-wire to the analyzer for daily monitoring. A program for expansion of this system to monitor more than a thousand compressors and automation of the signature comparison process is planned for all three gaseous diffusion plants operated for the United States Energy Research and Development Administration. (auth)

Absolute measurement of subnanometer scale vibration of cochlear partition of an excised guinea pig cochlea using spectral-domain phase-sensitive optical coherence tomography

Science.gov (United States)

Subhash, Hrebesh M.; Choudhury, Niloy; Jacques, Steven L.; Wang, Ruikang K.; Chen, Fangyi; Zha, Dingjun; Nuttall, Alfred L.

2012-01-01

Direct measurement of absolute vibration parameters from different locations within the mammalian organ of Corti is crucial for understanding the hearing mechanics such as how sound propagates through the cochlea and how sound stimulates the vibration of various structures of the cochlea, namely, basilar membrane (BM), recticular lamina, outer hair cells and tectorial membrane (TM). In this study we demonstrate the feasibility a modified phase-sensitive spectral domain optical coherence tomography system to provide subnanometer scale vibration information from multiple angles within the imaging beam. The system has the potential to provide depth resolved absolute vibration measurement of tissue microstructures from each of the delay-encoded vibration images with a noise floor of ~0.3nm at 200Hz.

Stochastic chaos induced by diffusion processes with identical spectral density but different probability density functions.

Science.gov (United States)

Lei, Youming; Zheng, Fan

2016-12-01

Stochastic chaos induced by diffusion processes, with identical spectral density but different probability density functions (PDFs), is investigated in selected lightly damped Hamiltonian systems. The threshold amplitude of diffusion processes for the onset of chaos is derived by using the stochastic Melnikov method together with a mean-square criterion. Two quasi-Hamiltonian systems, namely, a damped single pendulum and damped Duffing oscillator perturbed by stochastic excitations, are used as illustrative examples. Four different cases of stochastic processes are taking as the driving excitations. It is shown that in such two systems the spectral density of diffusion processes completely determines the threshold amplitude for chaos, regardless of the shape of their PDFs, Gaussian or otherwise. Furthermore, the mean top Lyapunov exponent is employed to verify analytical results. The results obtained by numerical simulations are in accordance with the analytical results. This demonstrates that the stochastic Melnikov method is effective in predicting the onset of chaos in the quasi-Hamiltonian systems.

Study of the diffuse spectral series of boron-like atomic systems

International Nuclear Information System (INIS)

Lavin, C.; Martin, I.; Vallejo, M.J.

1992-01-01

The diffuse spectral series, 2S 2 np 2 P-2s 2 nd 2 D, of the boron isoelectronic sequence has been studied through a one-particle scheme, by explicitly treating only the active electron. Oscillator strengths for various transitions (n = 2,3; n' = 3-16) have been computed with the quantum defect and relativistic quantum defect formalisms, and results comparing very satisfactory with other theoretical data have been obtained

Spectral diffusion of quasi localized excitons in single silicon nanocrystals

Energy Technology Data Exchange (ETDEWEB)

Martin, Joerg; Cichos, Frank [Centre for nanostructured Materials and Analytics, Institute of Physics, Chemnitz University of Technology, Reichenhainer Street 70, 09107 Chemnitz (Germany); Borczyskowski, Christian von, E-mail: Borczyskowski@physik.tu-chemnitz.de [Centre for nanostructured Materials and Analytics, Institute of Physics, Chemnitz University of Technology, Reichenhainer Street 70, 09107 Chemnitz (Germany)

2012-08-15

Evolution in time of photoluminescence spectra of SiO{sub x} capped single silicon nanocrystals has been investigated by means of confocal optical spectroscopy at room temperature. Large spectral jumps between subsequent spectra of up to 40 meV have been detected leading to noticeable line broadening and variation in the electron-phonon coupling. Further, a correlation between emission energy and emission intensity has been found and discussed in terms of an intrinsic Stark effect. Anti-correlated variations of the electron-phonon coupling to Si and SiO{sub 2} phonons as a function of photoluminescence energy indicate that the nearly localized excition is to some extent coupled to phonons in the shell covering the silicon nanocrystal. However, coupling is reduced upon increasing Stark effect, while at the same time coupling to phonons of the Si core increases. - Highlights: Black-Right-Pointing-Pointer Single silicon nanocrystals are detected via confocal microscopy. Black-Right-Pointing-Pointer Photoluminescence energies fluctuate strongly in time. Black-Right-Pointing-Pointer Spectral fluctuation is described in the form of spectral diffusion. Black-Right-Pointing-Pointer Dynamic processes are strongly controlled by electron-phonon coupling.

Comparison of measured and satellite-derived spectral diffuse attenuation coefficients for the Arabian Sea

Digital Repository Service at National Institute of Oceanography (India)

Suresh, T.; Talaulikar, M.; Desa, E.; Matondkar, S.G.P.; Mascarenhas, A.

The results of study comparing the spectral diffuse attenuation coefficients Kd(Lambda) measured in the Arabian Sea with those derived from the Sea-Viewing Wide Field-of-View Sensor (SeaWiFS) using three algorithms, of which two are empirical...

Intrinsic chirality and prochirality at Air/R-(+)- and S-(-)-limonene interfaces: spectral signatures with interference chiral sum-frequency generation vibrational spectroscopy.

Science.gov (United States)

Fu, Li; Zhang, Yun; Wei, Zhe-Hao; Wang, Hong-Fei

2014-09-01

We report in this work detailed measurements of the chiral and achiral sum-frequency vibrational spectra in the C-H stretching vibration region (2800-3050 cm(-1)) of the air/liquid interfaces of R-(+)-limonene and S-(-)-limonene, using the recently developed high-resolution broadband sum-frequency generation vibrational spectroscopy (HR-BB-SFG-VS). The achiral SFG spectra of R-limonene and S-limonene, as well as the RS racemic mixture (50/50 equal amount mixture), show that the corresponding molecular groups of the R and S enantiomers are with the same interfacial orientations. The interference chiral SFG spectra of the limonene enantiomers exhibit a spectral signature from the chiral response of the Cα-H stretching mode, and a spectral signature from the prochiral response of the CH(2) asymmetric stretching mode, respectively. The chiral spectral feature of the Cα-H stretching mode changes sign from R-(+)-limonene to S-(-)-limonene surfaces, and disappears for the RS racemic mixture surface. While the prochiral spectral feature of the CH(2) asymmetric stretching mode is the same for R-(+)-limonene and S-(-)-limonene surfaces, and also surprisingly remains the same for the RS racemic mixture surface. Therefore, the structures of the R-(+)-limonene and the S-(-)-limonene at the liquid interfaces are nevertheless not mirror images to each other, even though the corresponding groups have the same tilt angle from the interfacial normal, i.e., the R-(+)-limonene and the S-(-)-limonene at the surface are diastereomeric instead of enantiomeric. These results provide detailed information in understanding the structure and chirality of molecular interfaces and demonstrate the sensitivity and potential of SFG-VS as a unique spectroscopic tool for chirality characterization and chiral recognition at the molecular interface. © 2014 Wiley Periodicals, Inc.

Quantitative spectral and orientational analysis in surface sum frequency generation vibrational spectroscopy (SFG-VS)

Science.gov (United States)

Wang, Hong-Fei; Gan, Wei; Lu, Rong; Rao, Yi; Wu, Bao-Hua

Sum frequency generation vibrational spectroscopy (SFG-VS) has been proven to be a uniquely effective spectroscopic technique in the investigation of molecular structure and conformations, as well as the dynamics of molecular interfaces. However, the ability to apply SFG-VS to complex molecular interfaces has been limited by the ability to abstract quantitative information from SFG-VS experiments. In this review, we try to make assessments of the limitations, issues and techniques as well as methodologies in quantitative orientational and spectral analysis with SFG-VS. Based on these assessments, we also try to summarize recent developments in methodologies on quantitative orientational and spectral analysis in SFG-VS, and their applications to detailed analysis of SFG-VS data of various vapour/neat liquid interfaces. A rigorous formulation of the polarization null angle (PNA) method is given for accurate determination of the orientational parameter D = /, and comparison between the PNA method with the commonly used polarization intensity ratio (PIR) method is discussed. The polarization and incident angle dependencies of the SFG-VS intensity are also reviewed, in the light of how experimental arrangements can be optimized to effectively abstract crucial information from the SFG-VS experiments. The values and models of the local field factors in the molecular layers are discussed. In order to examine the validity and limitations of the bond polarizability derivative model, the general expressions for molecular hyperpolarizability tensors and their expression with the bond polarizability derivative model for C3v, C2v and C∞v molecular groups are given in the two appendixes. We show that the bond polarizability derivative model can quantitatively describe many aspects of the intensities observed in the SFG-VS spectrum of the vapour/neat liquid interfaces in different polarizations. Using the polarization analysis in SFG-VS, polarization selection rules or

High-speed vibrational imaging and spectral analysis of lipid bodies by compound Raman microscopy.

Science.gov (United States)

Slipchenko, Mikhail N; Le, Thuc T; Chen, Hongtao; Cheng, Ji-Xin

2009-05-28

Cells store excess energy in the form of cytoplasmic lipid droplets. At present, it is unclear how different types of fatty acids contribute to the formation of lipid droplets. We describe a compound Raman microscope capable of both high-speed chemical imaging and quantitative spectral analysis on the same platform. We used a picosecond laser source to perform coherent Raman scattering imaging of a biological sample and confocal Raman spectral analysis at points of interest. The potential of the compound Raman microscope was evaluated on lipid bodies of cultured cells and live animals. Our data indicate that the in vivo fat contains much more unsaturated fatty acids (FAs) than the fat formed via de novo synthesis in 3T3-L1 cells. Furthermore, in vivo analysis of subcutaneous adipocytes and glands revealed a dramatic difference not only in the unsaturation level but also in the thermodynamic state of FAs inside their lipid bodies. Additionally, the compound Raman microscope allows tracking of the cellular uptake of a specific fatty acid and its abundance in nascent cytoplasmic lipid droplets. The high-speed vibrational imaging and spectral analysis capability renders compound Raman microscopy an indispensible analytical tool for the study of lipid-droplet biology.

Final report on the key comparison CCPR-K5: Spectral diffuse reflectance

Science.gov (United States)

Nadal, Maria; Eckerle, Kenneth L.; Early, Edward A.; Ohno, Yoshi

2013-01-01

The CCPR K5 key comparison on spectral diffuse reflectance was carried out in the framework of the CIPM Mutual Recognition Arrangement, by 13 national metrology institutes (MMIs) as participants. The participants were CSIR-NML (South Africa), HUT (Finland), IFA-CSIC (Spain), KRISS (Republic of Korea), MSL (New Zealand), NIM (China), NIST (United States of America), NMIJ (Japan), NPL (United Kingdom), NRC (Canada), OMH (Hungary), PTB (Germany) and VNIIOFI (Russia Federation). NIST (USA) piloted the comparison. The aim of this comparison was to check the agreement of measurement of the spectral diffuse reflectance among participants, using the measurement geometry of d/0 or 0/d in the wavelength range of 360 nm to 820 nm at 20 nm increment. The comparison was a star type comparison with the samples provided by the pilot laboratory and with the measurement sequence: Pilot-Participant-Pilot. Spectralon and matte white ceramic tiles were used as the transfer standards. Each participant received three of each type of sample and at least one sample of each type was measured three times on three separate days, and the other two samples were measured once. The report presents the description of the measurement facilities, procedures and uncertainties of all the participants as well as the results of the comparison. Measurement results from the participants and their associated uncertainties were analyzed in accordance with the Guidelines for CCPR Key Comparison Report Preparation, using weighted mean with cut-off. For the calculation of the Key Comparison Reference Value (KCRV), as agreed by the participants, the data of both samples were used for the 460 nm to 820 nm region and only the data of the Spectralon samples were used in the spectral region of 360 nm to 440 nm. The unilateral degrees of equivalence (DoE) calculated for each participant are mostly consistent within the uncertainty (k = 2) of the DoE. This international comparison of spectral diffuse reflectance

Spectral function and quark diffusion constant in non-critical holographic QCD

Energy Technology Data Exchange (ETDEWEB)

Bu Yanyan, E-mail: yybu@itp.ac.cn [Institute of Theoretical Physics, Academia Sinica, Beijing 100190 (China); Yang Jinmin, E-mail: jmyang@itp.ac.cn [Institute of Theoretical Physics, Academia Sinica, Beijing 100190 (China)

2012-02-11

Motivated by recent studies of intersecting D-brane systems in critical string theory and phenomenological AdS/QCD models, we present a detailed analysis for the vector and scalar fluctuations in a non-critical holographic QCD model in the high temperature phase, i.e., the chiral symmetric phase. This model is described by N{sub f} pairs of D4 and D4{sup Macron} probe branes in a non-critical AdS{sub 6} black hole background. Focusing on the hydrodynamic as well as the high frequency limit, we analytically obtain spectral functions for vector and scalar modes on the flavor probe. Then we extract the light quark diffusion constant for flavor current using three different methods and find that different methods give the same results. We also compute the heavy quark diffusion constant for comparison with the light quark case.

Single-particle spectroscopy of I-III-VI semiconductor nanocrystals: spectral diffusion and suppression of blinking by two-color excitation.

Science.gov (United States)

Sharma, Dharmendar Kumar; Hirata, Shuzo; Bujak, Lukasz; Biju, Vasudevanpillai; Kameyama, Tatsuya; Kishi, Marino; Torimoto, Tsukasa; Vacha, Martin

2016-07-14

Ternary I-III-VI semiconductor nanocrystals have been explored as non-toxic alternatives to II-VI semiconductors for optoelectronic and sensing applications, but large photoluminescence spectral width and moderate brightness restrict their practical use. Here, using single-particle photoluminescence spectroscopy on nanocrystals of (AgIn)xZn2(1-x)S2 we show that the photoluminescence band is inhomogeneously broadened and that size distribution is the dominant factor in the broadening. The residual homogeneous linewidth of individual nanocrystals reaches up to 75% of the ensemble spectral width. Single nanocrystals undergo spectral diffusion which also contributes to the inhomogeneous band. Excitation with two lasers with energies above and below the bandgap reveals coexistence of two emitting donor states within one particle. Spectral diffusion in such particles is due to temporal activation and deactivation of one such state. Filling of a trap state with a lower-energy laser enables optical modulation of photoluminescence intermittency (blinking) and leads to an almost two-fold increase in brightness.

Determining the static electronic and vibrational energy correlations via two-dimensional electronic-vibrational spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Dong, Hui; Lewis, Nicholas H. C.; Oliver, Thomas A. A.; Fleming, Graham R., E-mail: grfleming@lbl.gov [Department of Chemistry, University of California, Berkeley, California 94720 (United States); Physical Biosciences Division, Lawrence Berkeley National Laboratory, Berkeley, Californial 94720 (United States); Kavli Energy NanoSciences Institute at Berkeley, Berkeley, California 94720 (United States)

2015-05-07

Changes in the electronic structure of pigments in protein environments and of polar molecules in solution inevitably induce a re-adaption of molecular nuclear structure. Both changes of electronic and vibrational energies can be probed with visible or infrared lasers, such as two-dimensional electronic spectroscopy or vibrational spectroscopy. The extent to which the two changes are correlated remains elusive. The recent demonstration of two-dimensional electronic-vibrational (2DEV) spectroscopy potentially enables a direct measurement of this correlation experimentally. However, it has hitherto been unclear how to characterize the correlation from the spectra. In this paper, we present a theoretical formalism to demonstrate the slope of the nodal line between the excited state absorption and ground state bleach peaks in the spectra as a characterization of the correlation between electronic and vibrational transition energies. We also show the dynamics of the nodal line slope is correlated to the vibrational spectral dynamics. Additionally, we demonstrate the fundamental 2DEV spectral line-shape of a monomer with newly developed response functions.

Analysis of Vibration Diagnostics Methods for Induction Motors

Directory of Open Access Journals (Sweden)

A. P. Kalinov

2012-01-01

Full Text Available The paper presents an analysis of existing vibration diagnostics methods. In order to evaluate an efficiency of method application the following criteria have been proposed: volume of input data required for establishing diagnosis, data content, software and hardware level, execution time for vibration diagnostics. According to the mentioned criteria a classification of vibration diagnostics methods for determination of their advantages and disadvantages, search for their development and improvement has been presented in paper. The paper contains a comparative estimation of methods in accordance with the proposed  criteria. According to this estimation the most efficient methods are a spectral analysis and spectral analysis of the vibration signal envelope.

Influence of vibrations and rotations of diatomic molecules on their physical properties: II. Refractive index, reactivity and diffusion coefficients

International Nuclear Information System (INIS)

Sharipov, Alexander S; Loukhovitski, Boris I; Starik, Alexander M

2016-01-01

The influence of the excitation of vibrational and rotational states of diatomic molecules (H 2 , N 2 , O 2 , NO, OH, CO, CH, HF and HCl) on refractive index, reactivity and transport coefficients was analyzed by using ab initio calculated data on the effective state-specific dipole moment and static polarizability obtained in the preceding paper of the present series. It has been revealed that, for non-polar molecules, the excitation both of vibrational and rotational degrees of freedom increases the averaged polarizability and, as a consequence, the refractive index. Meanwhile, for polar molecules, the effect of molecule excitation is more complex: it can either increase or decrease the refractive index. It was also shown that the excitation of molecules slightly influences the rate constants of barrierless chemical reactions between neutral particles; whereas, for ion–molecule reactions, this effect can be more pronounced. Analysis of the variation of diffusion coefficients, taking into account the effect of molecule excitation both on the collision diameter and on the well depth of intermolecular potential, exhibited that, for non-polar molecules, the effect associated with the change of collision diameter prevails. However, for polar molecules, the effect of the excitation of vibrational states on the well depth of intermolecular potential can compensate or even exceed the decrease of diffusion coefficient due to the averaged collision diameter rise. (paper)

Spectral and evolutionary analysis of advection-diffusion equations and the shear flow paradigm

International Nuclear Information System (INIS)

Thyagaraja, A.; Loureiro, N.; Knight, P.J.

2002-01-01

Advection-diffusion equations occur in a wide variety of fields in many contexts of active and passive transport in fluids and plasmas. The effects of sheared advective flows in the presence of irreversible processes such as diffusion and viscosity are of considerable current interest in tokamak and astrophysical contexts, where they are thought to play a key role in both transport and the dynamical structures characteristic of electromagnetic plasma turbulence. In this paper we investigate the spectral and evolutionary properties of relatively simple, linear, advection-diffusion equations. We apply analytical approaches based on standard Green's function methods to obtain insight into the nature of the spectra when the advective and diffusive effects occur separately and in combination. In particular, the physically interesting limit of small (but finite) diffusion is studied in detail. The analytical work is extended and supplemented by numerical techniques involving a direct solution of the eigenvalue problem as well as evolutionary studies of the initial value problem using a parallel code, CADENCE. The three approaches are complementary and entirely consistent with each other when appropriate comparison is made. They reveal different aspects of the properties of the advection-diffusion equation, such as the ability of sheared flows to generate a direct cascade to high wave numbers transverse to the advection and the consequent enhancement of even small amounts of diffusivity. The invariance properties of the spectra in the low diffusivity limit and the ability of highly sheared, jet-like flows to 'confine' transport to low shear regions are demonstrated. The implications of these properties in a wider context are discussed and set in perspective. (author)

Singular solution of the Feller diffusion equation via a spectral decomposition

Science.gov (United States)

Gan, Xinjun; Waxman, David

2015-01-01

Feller studied a branching process and found that the distribution for this process approximately obeys a diffusion equation [W. Feller, in Proceedings of the Second Berkeley Symposium on Mathematical Statistics and Probability (University of California Press, Berkeley and Los Angeles, 1951), pp. 227-246]. This diffusion equation and its generalizations play an important role in many scientific problems, including, physics, biology, finance, and probability theory. We work under the assumption that the fundamental solution represents a probability density and should account for all of the probability in the problem. Thus, under the circumstances where the random process can be irreversibly absorbed at the boundary, this should lead to the presence of a Dirac delta function in the fundamental solution at the boundary. However, such a feature is not present in the standard approach (Laplace transformation). Here we require that the total integrated probability is conserved. This yields a fundamental solution which, when appropriate, contains a term proportional to a Dirac delta function at the boundary. We determine the fundamental solution directly from the diffusion equation via spectral decomposition. We obtain exact expressions for the eigenfunctions, and when the fundamental solution contains a Dirac delta function at the boundary, every eigenfunction of the forward diffusion operator contains a delta function. We show how these combine to produce a weight of the delta function at the boundary which ensures the total integrated probability is conserved. The solution we present covers cases where parameters are time dependent, thereby greatly extending its applicability.

Multi-spectral and fluorescence diffuse optical tomography of breast cancer

Science.gov (United States)

Corlu, Alper

Multi-spectral and fluorescence diffuse optical tomography (DOT) techniques are explored and applied to image human breast cancer in vivo. Image reconstruction algorithms that utilize first and second order gradient information are described in detail. Breast DOT requires large computational memory and long run times. To this end, parallel computation techniques were developed appropriate to each reconstruction algorithm. A parallel plate DOT instrument developed for breast cancer imaging is described. The system relies heavily on continuous-wave (CW) transmission measurements and utilizes frequency domain (FD) measurements on the reemission side. However, traditional DOT image reconstruction methods based on CW measurements fail to separate tissue absorption and scattering uniquely. In this manuscript, multi-spectral DOT is shown to be capable of minimizing cross-talk and retrieving spectral parameters almost uniquely when the measurement wavelengths are optimized. A theoretical framework to select optimum wavelengths is provided, and tested with computer simulations. Results from phantom spectroscopy experiments and in vivo patient measurements support the notion that multi-spectral methods are superior to traditional DOT image reconstruction schemes. The same breast DOT instrument is improved and utilized to obtain the first in vivo images of human breast cancer based on fluorescence DOT (FDOT). To this end the fluorophore Indocyanine Green (ICG) is injected intravenously and fluorescence excitation and detection are accomplished in the soft-compression, parallel-plane, transmission geometry using laser sources at 786 nm and spectrally filtered CCD detection. Careful phantom and in vivo measurements are carried on to assure that the signals are due to ICG fluorescence, rather than tissue autofluorescence and excitation light leakage. An in vivo measurement protocol is designed to maximize the ICG contrast by acquiring full fluorescence tomographic scan during

Near infrared spectral imaging of explosives using a tunable laser source

Energy Technology Data Exchange (ETDEWEB)

Klunder, G L; Margalith, E; Nguyen, L K

2010-03-26

Diffuse reflectance near infrared hyperspectral imaging is an important analytical tool for a wide variety of industries, including agriculture consumer products, chemical and pharmaceutical development and production. Using this technique as a method for the standoff detection of explosive particles is presented and discussed. The detection of the particles is based on the diffuse reflectance of light from the particle in the near infrared wavelength range where CH, NH, OH vibrational overtones and combination bands are prominent. The imaging system is a NIR focal plane array camera with a tunable OPO/laser system as the illumination source. The OPO is programmed to scan over a wide spectral range in the NIR and the camera is synchronized to record the light reflected from the target for each wavelength. The spectral resolution of this system is significantly higher than that of hyperspectral systems that incorporate filters or dispersive elements. The data acquisition is very fast and the entire hyperspectral cube can be collected in seconds. A comparison of data collected with the OPO system to data obtained with a broadband light source with LCTF filters is presented.

A method of noise reduction in heterodyne interferometric vibration metrology by combining auto-correlation analysis and spectral filtering

Science.gov (United States)

Hao, Hongliang; Xiao, Wen; Chen, Zonghui; Ma, Lan; Pan, Feng

2018-01-01

Heterodyne interferometric vibration metrology is a useful technique for dynamic displacement and velocity measurement as it can provide a synchronous full-field output signal. With the advent of cost effective, high-speed real-time signal processing systems and software, processing of the complex signals encountered in interferometry has become more feasible. However, due to the coherent nature of the laser sources, the sequence of heterodyne interferogram are corrupted by a mixture of coherent speckle and incoherent additive noise, which can severely degrade the accuracy of the demodulated signal and the optical display. In this paper, a new heterodyne interferometric demodulation method by combining auto-correlation analysis and spectral filtering is described leading to an expression for the dynamic displacement and velocity of the object under test that is significantly more accurate in both the amplitude and frequency of the vibrating waveform. We present a mathematical model of the signals obtained from interferograms that contain both vibration information of the measured objects and the noise. A simulation of the signal demodulation process is presented and used to investigate the noise from the system and external factors. The experimental results show excellent agreement with measurements from a commercial Laser Doppler Velocimetry (LDV).

A Hybrid Finite Element-Fourier Spectral Method for Vibration Analysis of Structures with Elastic Boundary Conditions

Directory of Open Access Journals (Sweden)

Wan-You Li

2014-01-01

Full Text Available A novel hybrid method, which simultaneously possesses the efficiency of Fourier spectral method (FSM and the applicability of the finite element method (FEM, is presented for the vibration analysis of structures with elastic boundary conditions. The FSM, as one type of analytical approaches with excellent convergence and accuracy, is mainly limited to problems with relatively regular geometry. The purpose of the current study is to extend the FSM to problems with irregular geometry via the FEM and attempt to take full advantage of the FSM and the conventional FEM for structural vibration problems. The computational domain of general shape is divided into several subdomains firstly, some of which are represented by the FSM while the rest by the FEM. Then, fictitious springs are introduced for connecting these subdomains. Sufficient details are given to describe the development of such a hybrid method. Numerical examples of a one-dimensional Euler-Bernoulli beam and a two-dimensional rectangular plate show that the present method has good accuracy and efficiency. Further, one irregular-shaped plate which consists of one rectangular plate and one semi-circular plate also demonstrates the capability of the present method applied to irregular structures.

A variational multi-scale method with spectral approximation of the sub-scales: Application to the 1D advection-diffusion equations

KAUST Repository

Chacó n Rebollo, Tomá s; Dia, Ben Mansour

2015-01-01

This paper introduces a variational multi-scale method where the sub-grid scales are computed by spectral approximations. It is based upon an extension of the spectral theorem to non necessarily self-adjoint elliptic operators that have an associated base of eigenfunctions which are orthonormal in weighted L2 spaces. This allows to element-wise calculate the sub-grid scales by means of the associated spectral expansion. We propose a feasible VMS-spectral method by truncation of this spectral expansion to a finite number of modes. We apply this general framework to the convection-diffusion equation, by analytically computing the family of eigenfunctions. We perform a convergence and error analysis. We also present some numerical tests that show the stability of the method for an odd number of spectral modes, and an improvement of accuracy in the large resolved scales, due to the adding of the sub-grid spectral scales.

A variational multi-scale method with spectral approximation of the sub-scales: Application to the 1D advection-diffusion equations

KAUST Repository

Chacón Rebollo, Tomás

2015-03-01

This paper introduces a variational multi-scale method where the sub-grid scales are computed by spectral approximations. It is based upon an extension of the spectral theorem to non necessarily self-adjoint elliptic operators that have an associated base of eigenfunctions which are orthonormal in weighted L2 spaces. This allows to element-wise calculate the sub-grid scales by means of the associated spectral expansion. We propose a feasible VMS-spectral method by truncation of this spectral expansion to a finite number of modes. We apply this general framework to the convection-diffusion equation, by analytically computing the family of eigenfunctions. We perform a convergence and error analysis. We also present some numerical tests that show the stability of the method for an odd number of spectral modes, and an improvement of accuracy in the large resolved scales, due to the adding of the sub-grid spectral scales.

Vibrational Spectrum of HMX at CO2 Laser Wavelengths: A Combined DRIFT and LPAS Study

Directory of Open Access Journals (Sweden)

A. Puiu

2012-01-01

Full Text Available The vibrational spectrum of solid standard HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine was investigated. Two spectroscopic techniques were adopted for their different sensitivity and resolution. A preliminary survey of the absorption bands of the compound was performed in the 8000–400 cm−1 spectral range by employing the diffuse reflectance infrared Fourier transform (DRIFT technique at room temperature. The high-resolution line spectrum of HMX was obtained in the 9.2–10.8 μm spectral range by laser photoacoustic spectroscopy (LPAS method, using a line tuneable 10 W stabilised cw CO2 laser light source. By comparing the data collected with the two techniques in the common frequency range, a very good agreement was observed.

Simultaneous measurements of global vibrational spectra and dephasing times of molecular vibrational modes by broadband time-resolved coherent anti-Stokes Raman scattering spectrography

International Nuclear Information System (INIS)

Yin Jun; Yu Ling-Yao; Liu Xing; Wan Hui; Lin Zi-Yang; Niu Han-Ben

2011-01-01

In broadband coherent anti-Stokes Raman scattering (CARS) spectroscopy with supercontinuum (SC), the simultaneously detectable spectral coverage is limited by the spectral continuity and the simultaneity of various spectral components of SC in an enough bandwidth. By numerical simulations, the optimal experimental conditions for improving the SC are obtained. The broadband time-resolved CARS spectrography based on the SC with required temporal and spectral distributions is realised. The global molecular vibrational spectrum with well suppressed nonresonant background noise can be obtained in a single measurement. At the same time, the measurements of dephasing times of various molecular vibrational modes can be conveniently achieved from intensities of a sequence of time-resolved CARS signals. It will be more helpful to provide a complete picture of molecular vibrations, and to exhibit a potential to understand not only both the solvent dynamics and the solute-solvent interactions, but also the mechanisms of chemical reactions in the fields of biology, chemistry and material science. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

Damage detection on mesosurfaces using distributed sensor network and spectral diffusion maps

International Nuclear Information System (INIS)

Chinde, V; Vaidya, U; Laflamme, S; Cao, L

2016-01-01

In this work, we develop a data-driven method for the diagnosis of damage in mesoscale mechanical structures using an array of distributed sensor networks. The proposed approach relies on comparing intrinsic geometries of data sets corresponding to the undamaged and damaged states of the system. We use a spectral diffusion map approach to identify the intrinsic geometry of the data set. In particular, time series data from distributed sensors is used for the construction of diffusion maps. The low dimensional embedding of the data set corresponding to different damage levels is obtained using a singular value decomposition of the diffusion map. We construct appropriate metrics in the diffusion space to compare the different data sets corresponding to different damage cases. The developed algorithm is applied for damage diagnosis of wind turbine blades. To achieve this goal, we developed a detailed finite element-based model of CX-100 blade in ANSYS using shell elements. Typical damage, such as crack or delamination, will lead to a loss of stiffness, is modeled by altering the stiffness of the laminate layer. One of the main challenges in the development of health monitoring algorithms is the ability to use sensor data with a relatively small signal-to-noise ratio. Our developed diffusion map-based algorithm is shown to be robust to the presence of sensor noise. The proposed diffusion map-based algorithm is advantageous by enabling the comparison of data from numerous sensors of similar or different types of data through data fusion, hereby making it attractive to exploit the distributed nature of sensor arrays. This distributed nature is further exploited for the purpose of damage localization. We perform extensive numerical simulations to demonstrate that the proposed method can successfully determine the extent of damage on the wind turbine blade and also localize the damage. We also present preliminary results for the application of the developed algorithm on

Vibration insensitive interferometry

Science.gov (United States)

Millerd, James; Brock, Neal; Hayes, John; Kimbrough, Brad; North-Morris, Michael; Wyant, James C.

2017-11-01

The largest limitation of phase-shifting interferometry for optical testing is the sensitivity to the environment, both vibration and air turbulence. An interferometer using temporal phase-shifting is very sensitive to vibration because the various phase shifted frames of interferometric data are taken at different times and vibration causes the phase shifts between the data frames to be different from what is desired. Vibration effects can be reduced by taking all the phase shifted frames simultaneously and turbulence effects can be reduced by averaging many measurements. There are several techniques for simultaneously obtaining several phase-shifted interferograms and this paper will discuss two such techniques: 1) Simultaneous phase-shifting interferometry on a single detector array (PhaseCam) and 2) Micropolarizer phase-shifting array. The application of these techniques for the testing of large optical components, measurement of vibrational modes, the phasing of segmented optical components, and the measurement of deformations of large diffuse structures is described.

Spectral zone selection methodology for pebble bed reactors

International Nuclear Information System (INIS)

Mphahlele, Ramatsemela; Ougouag, Abderrafi M.; Ivanov, Kostadin N.; Gougar, Hans D.

2011-01-01

A methodology is developed for determining boundaries of spectral zones for pebble bed reactors. A spectral zone is defined as a region made up of a number of nodes whose characteristics are collectively similar and that are assigned the same few-group diffusion constants. The spectral zones are selected in such a manner that the difference (error) between the reference transport solution and the diffusion code solution takes a minimum value. This is achieved by choosing spectral zones through optimally minimizing this error. The objective function for the optimization algorithm is the total reaction rate error, which is defined as the sum of the leakage, absorption and fission reaction rates errors in each zone. The selection of these spectral zones is such that the core calculation results based on diffusion theory are within an acceptable tolerance as compared to a proper transport reference solution. Through this work, a consistent approach for identifying spectral zones that yield more accurate diffusion results is introduced.

Measurements of ground motion and magnet vibrations at the APS

International Nuclear Information System (INIS)

Shiltsev, V.

1996-01-01

This article presents results of ground motion and magnet vibrations measurements at the Advanced Photon Source. The experiments were done over a wide, frequency range (0-05-100 Hz) with the use of SM-3KV-type seismic probes from the Budker Institute of Nuclear Physics (Russia). Spectral power densities of vertical and horizontal motions of the APS hall floor and quadrupoles on regular supports were obtained. Also investigated were magnet vibrations induced by designed cooling water flow and spectral characteristics of spatial correlation of the quadrupole vibrations at different sectors of the ring. The influence of personnel activity in the hall and traffic under the ring on the slow motion of storage ring elements were observed. Amplitudes of vibrations at the APS are compared with results of seismic measurements at some other accelerators

Structural and vibrational spectral investigations of melaminium maleate monohydrate by FTIR, FT-Raman and quantum chemical calculations

Science.gov (United States)

Arjunan, V.; Kalaivani, M.; Marchewka, M. K.; Mohan, S.

2013-04-01

The structural investigations of the molecular complex of melamine with maleic acid, namely melaminium maleate monohydrate have been carried out by quantum chemical methods in addition to FTIR, FT-Raman and far-infrared spectral studies. The quantum chemical studies were performed with DFT (B3LYP) method using 6-31G**, cc-pVDZ and 6-311++G** basis sets to determine the energy, structural and thermodynamic parameters of melaminium maleate monohydrate. The hydrogen atom from maleic acid was transferred to the melamine molecule giving the singly protonated melaminium cation. The ability of ions to form spontaneous three-dimensional structure through weak Osbnd H⋯O and Nsbnd H⋯O hydrogen bonds shows notable vibrational effects.

Man-Induced Vibrations

DEFF Research Database (Denmark)

Jönsson, Jeppe; Hansen, Lars Pilegaard

1994-01-01

work has been done on the measurement of the exact load functions and related reponse analysis. A recent work using a spectral description has been performed by Per-Erik Erikson and includes a good literature survey. Bachmann and Ammann give a good overview of vibrations caused by human activity. Other...

Vibration modes of 3n-gaskets and other fractals

Energy Technology Data Exchange (ETDEWEB)

Bajorin, N; Chen, T; Dagan, A; Emmons, C; Hussein, M; Khalil, M; Mody, P; Steinhurst, B; Teplyaev, A [Department of Mathematics, University of Connecticut, Storrs CT 06269 (United States)

2008-01-11

We rigorously study eigenvalues and eigenfunctions (vibration modes) on the class of self-similar symmetric finitely ramified fractals, which include the Sierpinski gasket and other 3n-gaskets. We consider the classical Laplacian on fractals which generalizes the usual one-dimensional second derivative, is the generator of the self-similar diffusion process, and has possible applications as the quantum Hamiltonian. We develop a theoretical matrix analysis, including analysis of singularities, which allows us to compute eigenvalues, eigenfunctions and their multiplicities exactly. We support our theoretical analysis by symbolic and numerical computations. Our analysis, in particular, allows the computation of the spectral zeta function on fractals and the limiting distribution of eigenvalues (i.e., integrated density of states). We consider such examples as the level-3 Sierpinski gasket, a fractal 3-tree, and the diamond fractal.

Site Characterization in the Urban Area of Tijuana, B. C., Mexico by Means of: H/V Spectral Ratios, Spectral Analysis of Surface Waves, and Random Decrement Method

Science.gov (United States)

Tapia-Herrera, R.; Huerta-Lopez, C. I.; Martinez-Cruzado, J. A.

2009-05-01

Results of site characterization for an experimental site in the metropolitan area of Tijuana, B. C., Mexico are presented as part of the on-going research in which time series of earthquakes, ambient noise, and induced vibrations were processed with three different methods: H/V spectral ratios, Spectral Analysis of Surface Waves (SASW), and the Random Decrement Method, (RDM). Forward modeling using the wave propagation stiffness matrix method (Roësset and Kausel, 1981) was used to compute the theoretical SH/P, SV/P spectral ratios, and the experimental H/V spectral ratios were computed following the conventional concepts of Fourier analysis. The modeling/comparison between the theoretical and experimental H/V spectral ratios was carried out. For the SASW method the theoretical dispersion curves were also computed and compared with the experimental one, and finally the theoretical free vibration decay curve was compared with the experimental one obtained with the RDM. All three methods were tested with ambient noise, induced vibrations, and earthquake signals. Both experimental spectral ratios obtained with ambient noise as well as earthquake signals agree quite well with the theoretical spectral ratios, particularly at the fundamental vibration frequency of the recording site. Differences between the fundamental vibration frequencies are evident for sites located at alluvial fill (~0.6 Hz) and at sites located at conglomerate/sandstones fill (0.75 Hz). Shear wave velocities for the soft soil layers of the 4-layer discrete soil model ranges as low as 100 m/s and up to 280 m/s. The results with the SASW provided information that allows to identify low velocity layers, not seen before with the traditional seismic methods. The damping estimations obtained with the RDM are within the expected values, and the dominant frequency of the system also obtained with the RDM correlates within the range of plus-minus 20 % with the one obtained by means of the H/V spectral

Broadband Vibration Attenuation Using Hybrid Periodic Rods

Directory of Open Access Journals (Sweden)

S. Asiri

2008-12-01

Full Text Available This paper presents both theoretically and experimentally a new kind of a broadband vibration isolator. It is a table-like system formed by four parallel hybrid periodic rods connected between two plates. The rods consist of an assembly of periodic cells, each cell being composed of a short rod and piezoelectric inserts. By actively controlling the piezoelectric elements, it is shown that the periodic rods can efficiently attenuate the propagation of vibration from the upper plate to the lower one within critical frequency bands and consequently minimize the effects of transmission of undesirable vibration and sound radiation. In such a system, longitudinal waves can propagate from the vibration source in the upper plate to the lower one along the rods only within specific frequency bands called the "Pass Bands" and wave propagation is efficiently attenuated within other frequency bands called the "Stop Bands". The spectral width of these bands can be tuned according to the nature of the external excitation. The theory governing the operation of this class of vibration isolator is presented and their tunable filtering characteristics are demonstrated experimentally as functions of their design parameters. This concept can be employed in many applications to control the wave propagation and the force transmission of longitudinal vibrations both in the spectral and spatial domains in an attempt to stop/attenuate the propagation of undesirable disturbances.

Measurements of ground motion and magnets vibrations at the APS

International Nuclear Information System (INIS)

Shil'tsev, V.D.

1994-01-01

This article presents results of ground motion and magnets vibrations measurements at the Advanced Photon Source. The experiments were done over wide frequency range 0.05-100 Hz with use of SM-3KV type seismic probes from Budker Institute of Nuclear Physics (Russia). Spectral power densities of vertical and horizontal motions of the APS hall floor and quadrupoles on regular supports were obtained. There were also investigated magnets vibrations induced by designed cooling water flow and spectral characteristics of spatial correlation of the quads vibration at different sectors of the ring. Influence of personnel activity in the hall and traffic under the ring on slow motion of storage ring elements were observed. Amplitudes of vibrations at the APS are compared with results of seismic measurements at some other accelerators. 9 refs.; 10 figs.; 1 tab

Analysis of tube vibrations in D-4 steam generator

International Nuclear Information System (INIS)

Mavko, B.; Peterlin, G.; Boltezar, M.

1983-01-01

Accelerometer data for the most exposed tube in steam generator D-4 were recorded on magnetic tape. Procedures for calculations of the most characteristic parameters were prepared for spectral analyzer on SD 360. Parameters which most satisfactorily describe the vibrations are power spectral densities peak to peak acceleration volume and root mean square displacement. Computer program was written to calculate the natural frequencies of a multispaned tube. Procedures and the computer program will be used for independent analysis of tube vibrations in Krsko D-4 type steam generator. (author)

Fourier spectral methods for fractional-in-space reaction-diffusion equations

KAUST Repository

Bueno-Orovio, Alfonso

2014-04-01

© 2014, Springer Science+Business Media Dordrecht. Fractional differential equations are becoming increasingly used as a powerful modelling approach for understanding the many aspects of nonlocality and spatial heterogeneity. However, the numerical approximation of these models is demanding and imposes a number of computational constraints. In this paper, we introduce Fourier spectral methods as an attractive and easy-to-code alternative for the integration of fractional-in-space reaction-diffusion equations described by the fractional Laplacian in bounded rectangular domains of ℝ. The main advantages of the proposed schemes is that they yield a fully diagonal representation of the fractional operator, with increased accuracy and efficiency when compared to low-order counterparts, and a completely straightforward extension to two and three spatial dimensions. Our approach is illustrated by solving several problems of practical interest, including the fractional Allen–Cahn, FitzHugh–Nagumo and Gray–Scott models, together with an analysis of the properties of these systems in terms of the fractional power of the underlying Laplacian operator.

Isotope separation using vibrationally excited molecules

International Nuclear Information System (INIS)

Woodroffe, J.A.; Keck, J.C.

1977-01-01

A system for isotope separation or enrichment wherein molecules of a selected isotope type in a flow of molecules of plural isotope types are vibrationally excited and collided with a background gas to provide enhanced diffusivity for the molecules of the selected isotope type permitting their separate collection. The system typically is for the enrichment of uranium using a uranium hexafluoride gas in combination with a noble gas such as argon. The uranium hexafluoride molecules having a specific isotope of uranium are vibrationally excited by laser radiation. The vibrational energy is converted to a translation energy upon collision with a particle of the background gas and the added translation energy enhances the diffusivity of the selected hexafluoride molecules facilitating its condensation on collection surfaces provided for that purpose. This process is periodically interrupted and the cryogenic flow halted to permit evaporation of the collected molecules to provide a distinct, enriched flow

Natural vibration experimental analysis of Novovoronezhskaya NPP main building

International Nuclear Information System (INIS)

Zoubkov, D.; Isaikin, A.; Shablinsky, G.; Lopanchuk, A.; Nefedov, S.

2005-01-01

1. Natural vibration frequencies are main characteristics of buildings and structures which allow to give integral estimation of their in-service state. Even relatively small changes of these frequencies as compared to the initially registered values point to serious defects of building structures. In this paper we analyzed natural vibration frequencies and natural modes of the main building (MB) of Novovoronezhskaya NPP operating nuclear unit with WWER-440 type reactor. The MB consists of a reactor compartment (RC), a machine room (MR) and an electric device (ED) unit positioned in between. 2. Natural vibration frequencies and natural modes of the MB were determined experimentally by analyzing its microvibrations caused by operation of basic equipment (turbines, pumps, etc.). Microvibrations of the main building were measured at 12 points. At each point measurements were carried out along two or three mutually perpendicular vibration directions. Spectral analysis of vibration records has been conducted. Identification of natural vibration frequencies was carried out on the basis of the spectral peaks and plotted vibration modes (taking into account operating frequencies of the basic equipment of the power generating unit). On the basis of the measurement results three transverse modes and corresponding natural vibration frequencies of the MB, one longitudinal mode and corresponding natural vibration frequency of the MB and two natural frequencies of vertical vibrations of RC and MR floor trusses (1st and 2nd symmetric forms) were determined. Dynamic characteristics of the main building of NV NPP resulting from full scale researches are supposed to be used as one of building structure stability criteria. (authors)

Estimation of spectral kurtosis

Science.gov (United States)

Sutawanir

2017-03-01

Rolling bearings are the most important elements in rotating machinery. Bearing frequently fall out of service for various reasons: heavy loads, unsuitable lubrications, ineffective sealing. Bearing faults may cause a decrease in performance. Analysis of bearing vibration signals has attracted attention in the field of monitoring and fault diagnosis. Bearing vibration signals give rich information for early detection of bearing failures. Spectral kurtosis, SK, is a parameter in frequency domain indicating how the impulsiveness of a signal varies with frequency. Faults in rolling bearings give rise to a series of short impulse responses as the rolling elements strike faults, SK potentially useful for determining frequency bands dominated by bearing fault signals. SK can provide a measure of the distance of the analyzed bearings from a healthy one. SK provides additional information given by the power spectral density (psd). This paper aims to explore the estimation of spectral kurtosis using short time Fourier transform known as spectrogram. The estimation of SK is similar to the estimation of psd. The estimation falls in model-free estimation and plug-in estimator. Some numerical studies using simulations are discussed to support the methodology. Spectral kurtosis of some stationary signals are analytically obtained and used in simulation study. Kurtosis of time domain has been a popular tool for detecting non-normality. Spectral kurtosis is an extension of kurtosis in frequency domain. The relationship between time domain and frequency domain analysis is establish through power spectrum-autocovariance Fourier transform. Fourier transform is the main tool for estimation in frequency domain. The power spectral density is estimated through periodogram. In this paper, the short time Fourier transform of the spectral kurtosis is reviewed, a bearing fault (inner ring and outer ring) is simulated. The bearing response, power spectrum, and spectral kurtosis are plotted to

Structural and vibrational spectral investigations of melaminium maleate monohydrate by FTIR, FT-Raman and quantum chemical calculations.

Science.gov (United States)

Arjunan, V; Kalaivani, M; Marchewka, M K; Mohan, S

2013-04-15

The structural investigations of the molecular complex of melamine with maleic acid, namely melaminium maleate monohydrate have been carried out by quantum chemical methods in addition to FTIR, FT-Raman and far-infrared spectral studies. The quantum chemical studies were performed with DFT (B3LYP) method using 6-31G(**), cc-pVDZ and 6-311++G(**) basis sets to determine the energy, structural and thermodynamic parameters of melaminium maleate monohydrate. The hydrogen atom from maleic acid was transferred to the melamine molecule giving the singly protonated melaminium cation. The ability of ions to form spontaneous three-dimensional structure through weak OH···O and NH···O hydrogen bonds shows notable vibrational effects. Copyright © 2013 Elsevier B.V. All rights reserved.

Sum frequency generation for surface vibrational spectroscopy

International Nuclear Information System (INIS)

Hunt, J.H.; Guyot-Sionnest, P.; Shen, Y.R.

1987-01-01

Surface vibrational spectroscopy is one of the best means for characterizing molecular adsorbates. For this reason, many techniques have been developed in the past. However, most of them suffer from poor sensitivity, low spectral and temporal resolution, and applications limited to vacuum solid interfaces. Recently, the second harmonic generation (SHG) technique was proved repeatedly to be a simple but versatile surface probe. It is highly sensitive and surface specific; it is also capable of achieving high temporal, spatial, and spectral resolution. Being an optical technique, it can be applied to any interface accessible by light. The only serious drawback is its lack of molecular selectivity. An obvious remedy is the extension of the technique to IR-visible sum frequency generation (SFG). Surface vibrational spectroscopy with submonolayer sensitivity is then possible using SFG with the help of a tunable IR laser. The authors report here an SFG measurement of the C-H stretch vibration of monolayers of molecules at air-solid and air-liquid interfaces

Enhancement of diffusers BRDF accuracy

Science.gov (United States)

Otter, Gerard; Bazalgette Courrèges-Lacoste, Gregory; van Brug, Hedser; Schaarsberg, Jos Groote; Delwart, Steven; del Bello, Umberto

2017-11-01

This paper reports the result of an ESA study conducted at TNO to investigate properties of various diffusers. Diffusers are widely used in space instruments as part of the on-board absolute calibration. Knowledge of the behaviour of the diffuser is therefore most important. From measurements of launched instruments in-orbit it has been discovered that when a diffuser is used in the vacuum of space the BRDF can change with respect to the one in ambient conditions. This is called the air/vacuum effect and has been simulated in this study by measuring the BRDF in a laboratory in ambient as well as vacuum conditions. Another studied effect is related to the design parameters of the optical system and the scattering properties of the diffuser. The effect is called Spectral Features and is a noise like structure superimposed on the diffuser BRDF. Modern space spectrometers, which have high spectral resolution and/or a small field of view (high spatial resolution) are suffering from this effect. The choice of diffuser can be very critical with respect to the required absolute radiometric calibration of an instrument. Even if the Spectral Features are small it can influence the error budget of the retrieval algorithms for the level 2 products. in this presentation diffuser trade-off results are presented and the Spectral Features model applied to the optical configuration of the MERIS instrument is compared to in-flight measurements of MERIS.

Preparation, crystal structure, vibrational spectral and density functional studies of bis (4-nitrophenol)-2,4,6-triamino-1,3,5-triazine monohydrate

Science.gov (United States)

Kanagathara, N.; Marchewka, M. K.; Drozd, M.; Renganathan, N. G.; Gunasekaran, S.; Anbalagan, G.

2013-10-01

An organic-organic salt, bis (4-nitrophenol) 2,4,6-triamino 1,3,5-triazine monohydrate (BNPM) has been prepared by slow evaporation technique at room temperature. Single crystal X-ray diffraction analysis reveals that the compound crystallizes in triclinic system with centrosymmetric space group P-1. IR and Raman spectra of BNPM have been recorded and analyzed. The study has been extended to confocal Raman spectral analysis. Band assignments have been made for the melamine and p-nitrophenol molecules. Vibrational spectra have also been discussed on the basis of quantum chemical density functional theory calculations using Firefly (PC GAMESS) Version 7.1 G. Vibrational frequencies are calculated and scaled values are compared with the experimental one. The Mulliken charges, HOMO-LUMO orbital energies are calculated and analyzed. The chemical structure of the compound was established by 1H NMR and 13C NMR spectra.

Mathematical formulation of temperature fluctuation and control rod vibration in PARR

International Nuclear Information System (INIS)

Ansari, S.A.; Ayazuddin, S.K.

This report describes the mathematical interpretation of experimental neutron noise spectra obtained for PARR core. A one dimensional thermal-hydraulic model of PARR core was developed to calculate the magnitude of neutron noise as a result of fluctuation in the core inlet coolant temperature. The sink structure of the neutron power spectral density as well as the dependence of observed neutron spectra on coolant velocity is also explained by the thermal hydraulic model. An attempt is made to explain the phenomena of control rod vibration by a simple eigen frequency vibration model. The calculated neutron power spectral density due to vibration and temperature noise were added and compared with the experimental power spectra obtained for PARR. (orig./A.B.)

General vibration monitoring: Experimental hall

International Nuclear Information System (INIS)

Jendrzejczyk, J.A.; Wambsganss, M.W.; Smith, R.K.

1993-01-01

The reported vibration data were generated from measurements made on the experimental hall floor on December 2, 1992. At the time of the measurements, the ESRF hydrolevel was set-up in the Early Assembly Area (EAA) of the experimental hall and was being used to measure static displacement (settlement) of the floor. The vibration measurement area was on and adjacent to the EAA, in the vicinity of the ESRF hydrolevel test which was in progress. This report summarizes the objectives, instrumentation, measurement locations, observations, and conclusions, and provides selected results in the form of RMS vs. time plots, and power spectral densities from which frequency information can be derived. Measured response amplitudes were within the vibration criteria established for the APS

Fast fourier algorithms in spectral computation and analysis of vibrating machines

International Nuclear Information System (INIS)

Farooq, U.; Hafeez, T.; Khan, M.Z.; Amir, M.

2001-01-01

In this work we have discussed Fourier and its history series, relationships among various Fourier mappings, Fourier coefficients, transforms, inverse transforms, integrals, analyses, discrete and fast algorithms for data processing and analysis of vibrating systems. The evaluation of magnitude of the source signal at transmission time, related coefficient matrix, intensity, and magnitude at the receiving end (stations). Matrix computation of Fourier transform has been explained, and applications are presented. The fast Fourier transforms, new computational scheme. have been tested with an example. The work also includes digital programs for obtaining the frequency contents of time function. It has been explained that how the fast Fourier algorithms (FFT) has decreased computational work by several order of magnitudes and split the spectrum of a signal into two (even and odd modes) at every successive step. That fast quantitative processing for discrete Fourier transforms' computations as well as signal splitting and combination provides an efficient. and reliable tool for spectral analyses. Fourier series decompose the given variable into a sum of oscillatory functions each having a specific frequency. These frequencies, with their corresponding amplitude and phase angles, constitute the frequency contents of the original time functions. These fast processing achievements, signals decomposition and combination may be carried out by the principle of superposition and convolution for, even, signals of different frequencies. Considerable information about a machine or a structure can be derived from variable speed and frequency tests. (author)

High throughput assessment of cells and tissues: Bayesian classification of spectral metrics from infrared vibrational spectroscopic imaging data.

Science.gov (United States)

Bhargava, Rohit; Fernandez, Daniel C; Hewitt, Stephen M; Levin, Ira W

2006-07-01

Vibrational spectroscopy allows a visualization of tissue constituents based on intrinsic chemical composition and provides a potential route to obtaining diagnostic markers of diseases. Characterizations utilizing infrared vibrational spectroscopy, in particular, are conventionally low throughput in data acquisition, generally lacking in spatial resolution with the resulting data requiring intensive numerical computations to extract information. These factors impair the ability of infrared spectroscopic measurements to represent accurately the spatial heterogeneity in tissue, to incorporate robustly the diversity introduced by patient cohorts or preparative artifacts and to validate developed protocols in large population studies. In this manuscript, we demonstrate a combination of Fourier transform infrared (FTIR) spectroscopic imaging, tissue microarrays (TMAs) and fast numerical analysis as a paradigm for the rapid analysis, development and validation of high throughput spectroscopic characterization protocols. We provide an extended description of the data treatment algorithm and a discussion of various factors that may influence decision-making using this approach. Finally, a number of prostate tissue biopsies, arranged in an array modality, are employed to examine the efficacy of this approach in histologic recognition of epithelial cell polarization in patients displaying a variety of normal, malignant and hyperplastic conditions. An index of epithelial cell polarization, derived from a combined spectral and morphological analysis, is determined to be a potentially useful diagnostic marker.

Road simulation for four-wheel vehicle whole input power spectral density

Science.gov (United States)

Wang, Jiangbo; Qiang, Baomin

2017-05-01

As the vibration of running vehicle mainly comes from road and influence vehicle ride performance. So the road roughness power spectral density simulation has great significance to analyze automobile suspension vibration system parameters and evaluate ride comfort. Firstly, this paper based on the mathematical model of road roughness power spectral density, established the integral white noise road random method. Then in the MATLAB/Simulink environment, according to the research method of automobile suspension frame from simple two degree of freedom single-wheel vehicle model to complex multiple degrees of freedom vehicle model, this paper built the simple single incentive input simulation model. Finally the spectrum matrix was used to build whole vehicle incentive input simulation model. This simulation method based on reliable and accurate mathematical theory and can be applied to the random road simulation of any specified spectral which provides pavement incentive model and foundation to vehicle ride performance research and vibration simulation.

Enhancement of diffusers BSDF accuracy: spectral features effect

NARCIS (Netherlands)

Brug, H. van; Courrèges-Lacoste, G.B.; Otter, G.C.J.; Schaarsberg, J.G.; Delwart, S.; Del Bello, U.

2006-01-01

This paper reports the activities performed in the framework of the ESA contract 18432/04/NL/AR: Enhancement of diffusers BSDF Accuracy. This study was conducted to investigate properties of various diffusers. Diffusers are widely used in space instruments as part of the on-board absolute

Measurements of ground motion and SSC dipole vibrations

International Nuclear Information System (INIS)

Parkhomchuk, V.V.; Shiltsev, V.D.; Weaver, H.J.

1993-06-01

The results of seismic ground measurements at the Superconducting Super Collider (SSC) site and investigations of vibrational properties of superconducting dipoles for the SSC are presented. Spectral analysis of the data obtained in the large frequency band from 0.05 Hz to 2000 Hz is done. Resonant behavior and the dipole-to-ground transform ratio are investigated. The influence of measured vibrations on SSC operations is considered

Numerical solution of the unsteady diffusion-convection-reaction equation based on improved spectral Galerkin method

Science.gov (United States)

Zhong, Jiaqi; Zeng, Cheng; Yuan, Yupeng; Zhang, Yuzhe; Zhang, Ye

2018-04-01

The aim of this paper is to present an explicit numerical algorithm based on improved spectral Galerkin method for solving the unsteady diffusion-convection-reaction equation. The principal characteristics of this approach give the explicit eigenvalues and eigenvectors based on the time-space separation method and boundary condition analysis. With the help of Fourier series and Galerkin truncation, we can obtain the finite-dimensional ordinary differential equations which facilitate the system analysis and controller design. By comparing with the finite element method, the numerical solutions are demonstrated via two examples. It is shown that the proposed method is effective.

Spectral methods for study of the G-protein-coupled receptor rhodopsin: I. Vibrational and electronic spectroscopy

Science.gov (United States)

Struts, A. V.; Barmasov, A. V.; Brown, M. F.

2015-05-01

Here we review the application of modern spectral methods for the study of G-protein-coupled receptors (GPCRs) using rhodopsin as a prototype. Because X-ray analysis gives us immobile snapshots of protein conformations, it is imperative to apply spectroscopic methods for elucidating their function: vibrational (Raman, FTIR), electronic (UV-visible absorption, fluorescence) spectroscopies, and magnetic resonance (electron paramagnetic resonance, EPR), and nuclear magnetic resonance (NMR). In the first of the two companion articles, we discuss the application of optical spectroscopy for studying rhodopsin in a membrane environment. Information is obtained regarding the time-ordered sequence of events in rhodopsin activation. Isomerization of the chromophore and deprotonation of the retinal Schiff base leads to a structural change of the protein involving the motion of helices H5 and H6 in a pH-dependent process. Information is obtained that is unavailable from X-ray crystallography, which can be combined with spectroscopic studies to achieve a more complete understanding of GPCR function.

Vibrational spectroscopic study of fluticasone propionate

Science.gov (United States)

Ali, H. R. H.; Edwards, H. G. M.; Kendrick, J.; Scowen, I. J.

2009-03-01

Fluticasone propionate is a synthetic glucocorticoid with potent anti-inflammatory activity that has been used effectively in the treatment of chronic asthma. The present work reports a vibrational spectroscopic study of fluticasone propionate and gives proposed molecular assignments on the basis of ab initio calculations using BLYP density functional theory with a 6-31G* basis set and vibrational frequencies predicted within the quasi-harmonic approximation. Several spectral features and band intensities are explained. This study generated a library of information that can be employed to aid the process monitoring of fluticasone propionate.

On spectral distribution of high dimensional covariation matrices

DEFF Research Database (Denmark)

Heinrich, Claudio; Podolskij, Mark

In this paper we present the asymptotic theory for spectral distributions of high dimensional covariation matrices of Brownian diffusions. More specifically, we consider N-dimensional Itô integrals with time varying matrix-valued integrands. We observe n equidistant high frequency data points...... of the underlying Brownian diffusion and we assume that N/n -> c in (0,oo). We show that under a certain mixed spectral moment condition the spectral distribution of the empirical covariation matrix converges in distribution almost surely. Our proof relies on method of moments and applications of graph theory....

Amplitude-cyclic frequency decomposition of vibration signals for bearing fault diagnosis based on phase editing

Science.gov (United States)

Barbini, L.; Eltabach, M.; Hillis, A. J.; du Bois, J. L.

2018-03-01

In rotating machine diagnosis different spectral tools are used to analyse vibration signals. Despite the good diagnostic performance such tools are usually refined, computationally complex to implement and require oversight of an expert user. This paper introduces an intuitive and easy to implement method for vibration analysis: amplitude cyclic frequency decomposition. This method firstly separates vibration signals accordingly to their spectral amplitudes and secondly uses the squared envelope spectrum to reveal the presence of cyclostationarity in each amplitude level. The intuitive idea is that in a rotating machine different components contribute vibrations at different amplitudes, for instance defective bearings contribute a very weak signal in contrast to gears. This paper also introduces a new quantity, the decomposition squared envelope spectrum, which enables separation between the components of a rotating machine. The amplitude cyclic frequency decomposition and the decomposition squared envelope spectrum are tested on real word signals, both at stationary and varying speeds, using data from a wind turbine gearbox and an aircraft engine. In addition a benchmark comparison to the spectral correlation method is presented.

Diagnostics of hand-arm system disorders in workers who use vibrating tools.

Science.gov (United States)

Gemne, G

1997-02-01

A hand-arm vibration syndrome occurs in some workers who use hand held vibrating tools. It is recognised to consist of white fingers, diffusely distributed finger neuropathy, pain in the arm and hand, and a small excess risk of osteoarthrosis from percussion to the wrist and elbow. Carpal tunnel syndrome is mainly due to ergonomic factors other than vibration, but certain factors related to vibration may contribute to its development. A decrease in muscle power induced by vibration, and excessive hearing deficit have been postulated. The assessment of a disorder suspected of being induced by vibration includes deciding whether there is a disorder and, if so, whether the symptoms can be caused by vibration. To decide whether the symptoms can be caused by vibration epidemiological documentation and pathogenically reasonable theories must exist. A causal diagnosis finally requires and epidemiological decision whether or not the factual exposure has elicited the patient's symptoms. Epidemiological data on the quantitative association between vibration and excessive risks of white fingers and diffusely distributed neuropathy are incomplete. The symptomatic diagnosis of white fingers is still mainly based on anamnestic information. Available laboratory tests are incapable of grading the severity of individual cases. Recording the finger systolic blood pressure during cold provocation is a method of symptomatic diagnosis with reasonable levels of specificity, sensitivity, and predictive value. For diffusely distributed neuropathy these levels are lower than desired. Electrodiagnostic tests for carpal tunnel syndrome have sufficient validity. Proper exposure evaluation must be based on an appreciation of the character of the vibration as well as effective duration and intermittency. If this is not taken into account, the number of hours of exposure and intensity of vibration are likely to be non-commensurable variables, and the simple product of them is a questionable dose

Determination of space charge region width and diffusion length in Cu(In,Ga)(S,Se)2 absorber from solar cell spectral characteristic

International Nuclear Information System (INIS)

Tivanov, M.; Mazanik, A.; Drozdov, N.; Zaretskaya, E.

2010-01-01

Full text : The space-charge region width and diffusion length of minority charge carriers in the base region (Cu(In,Ga)(S,Se) 2 absorber) are the most important parameters of the solar cell. These parameters determine the efficiency of a solar cell therefore the problem of their control is essential. In this work it is present simple non-destructive method of extracting the parameters of Cu(In,Ga)(S,Se) 2 -based solar cell (space-charge region width and diffusion length of minority charge carriers in Cu(In,Ga)(S,Se) 2 absorber) from the analysis of solar cell spectral photoresponse. The method is based on one-dimensional model of a solar cell and on the change of in-depth distribution of the photogenerated carriers in the solar cell and, hence, on the change of its photoresponse with the wave-length variation. The following assumptions are accepted: the reflection of charge carriers from a back contact and the ''drawing'' field in the quasi-neutral area of the absorber layers are absent, window and buffer layers are transparent in the analyzed part of photoresponse spectrum, the injection level of minority charge carriers is low, the recombination losses at the metallurgical p-n-junction interface of the studied photosensitive structure linearly depend on the photocurrent density. For the calculation it is necessary to obtain the following set of the experimental data: the spectral density of incident radiation, the spectral dependence of photocurrent or photovoltage of the studied photosensitive structure, the spectral dependences of optical absorption coefficient and reflectance.

Note: Electrochemical etching of cylindrical nanoprobes using a vibrating electrolyte

International Nuclear Information System (INIS)

Wang, Yufeng; Zeng, Yongbin; Qu, Ningsong; Zhu, Di

2015-01-01

An electrochemical etching process using a vibrating electrolyte of potassium hydroxide to prepare tungsten cylindrical nanotips is developed. The vibrating electrolyte eases the effects of a diffusion layer and extends the etching area, which aid in the production of cylindrical nanotips. Larger amplitudes and a vibration frequency of 35 Hz are recommended for producing cylindrical nanotips. Nanotips with a tip radius of approximately 43 nm and a conical angle of arctan 0.0216 are obtained

Report of the key-comparison of spectral diffuse reflectance (EURAMET.PR-K5) (Ref. 619)

Science.gov (United States)

Andor, György; Gál, Péter

2018-01-01

This report details the final results of the EURAMET comparison on regular spectral transmittance carried out between 2006 and 2016. The aim of this comparison was to check the agreement of measurement of the spectral diffuse reflectance among participants, using the measurement geometry of d/0 or 0/d in the wavelength range of 360 nm to 780 nm at 20 nm increment. We used a star type comparison: first the participants sent their samples to the pilot, than the pilot measured all the samples of the participants and sent them back. The participants measured the samples and sent them to the pilot for control measurement. Six standards were used as reference standards in order to maintain the scale during the comparison. These were three samples of BCR-406 opal glasses (BCR 30506; BCR 30303; BCR 30704), an MC20 Russian opal glass (MC 4777) and two samples made of pressed halon (polytetrafluoroethylene) powder (halon 2007A; halon 2007C). These six samples were designated as the Comparison reference standards. The diffuse reflectance was initially measured on the OMH (BFKH) absolute reflectometer. The link to the CCPR-K5 results was BFKH, and the check on BFKH was the PTB results who also participated in the CCPR-K5 comparison. The participants were GUM, INM, LNE, METAS, BFKH, PTB, SP. Main text To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/. The final report has been peer-reviewed and approved for publication by the CCPR, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

Vibrational spectroscopic study of terbutaline hemisulphate

Science.gov (United States)

Ali, H. R. H.; Edwards, H. G. M.; Kendrick, J.; Scowen, I. J.

2009-05-01

The Raman spectrum of terbutaline hemisulphate is reported for the first time, and molecular assignments are proposed on the basis of ab initio BLYP DFT calculations with a 6-31G* basis set and vibrational frequencies predicted within the quasi-harmonic approximation; these predictions compare favourably with the observed vibrational spectra. Comparison with previously published infrared data explains several spectral features. The results from this study provide data that can be used for the preparative process monitoring of terbutaline hemisulphate, an important β 2 agonist drug in various dosage forms and its interaction with excipients and other components.

The spectral volume method as applied to transport problems

International Nuclear Information System (INIS)

McClarren, Ryan G.

2011-01-01

We present a new spatial discretization for transport problems: the spectral volume method. This method, rst developed by Wang for computational fluid dynamics, divides each computational cell into several sub-cells and enforces particle balance on each of these sub-cells. Also, these sub-cells are used to build a polynomial reconstruction in the cell. The idea of dividing cells into many cells is a generalization of the simple corner balance and other similar schemes. The spectral volume method preserves particle conservation and preserves the asymptotic diffusion limit. We present results from the method on two transport problems in slab geometry using discrete ordinates and second through sixth order spectral volume schemes. The numerical results demonstrate the accuracy and preservation of the diffusion limit of the spectral volume method. Future work will explore possible bene ts of the scheme for high-performance computing and for resolving diffusive boundary layers. (author)

Convolutional neural networks for vibrational spectroscopic data analysis.

Science.gov (United States)

Acquarelli, Jacopo; van Laarhoven, Twan; Gerretzen, Jan; Tran, Thanh N; Buydens, Lutgarde M C; Marchiori, Elena

2017-02-15

In this work we show that convolutional neural networks (CNNs) can be efficiently used to classify vibrational spectroscopic data and identify important spectral regions. CNNs are the current state-of-the-art in image classification and speech recognition and can learn interpretable representations of the data. These characteristics make CNNs a good candidate for reducing the need for preprocessing and for highlighting important spectral regions, both of which are crucial steps in the analysis of vibrational spectroscopic data. Chemometric analysis of vibrational spectroscopic data often relies on preprocessing methods involving baseline correction, scatter correction and noise removal, which are applied to the spectra prior to model building. Preprocessing is a critical step because even in simple problems using 'reasonable' preprocessing methods may decrease the performance of the final model. We develop a new CNN based method and provide an accompanying publicly available software. It is based on a simple CNN architecture with a single convolutional layer (a so-called shallow CNN). Our method outperforms standard classification algorithms used in chemometrics (e.g. PLS) in terms of accuracy when applied to non-preprocessed test data (86% average accuracy compared to the 62% achieved by PLS), and it achieves better performance even on preprocessed test data (96% average accuracy compared to the 89% achieved by PLS). For interpretability purposes, our method includes a procedure for finding important spectral regions, thereby facilitating qualitative interpretation of results. Copyright © 2016 Elsevier B.V. All rights reserved.

Localized Surface Plasmons in Vibrating Graphene Nanodisks

DEFF Research Database (Denmark)

Wang, Weihua; Li, Bo-Hong; Stassen, Erik

2016-01-01

in graphene disks have the additional benefit to be highly tunable via electrical stimulation. Mechanical vibrations create structural deformations in ways where the excitation of localized surface plasmons can be strongly modulated. We show that the spectral shift in such a scenario is determined...... by a complex interplay between the symmetry and shape of the modal vibrations and the plasmonic mode pattern. Tuning confined modes of light in graphene via acoustic excitations, paves new avenues in shaping the sensitivity of plasmonic detectors, and in the enhancement of the interaction with optical emitters...

A study of vibrational relaxation of electronically-excited molecules

International Nuclear Information System (INIS)

Datsyuk, V.V.; Izmailov, I.A.; Kochelap, V.A.

1992-09-01

The time kinetics of the vibrational relaxation of excimers is studied in the diffusional approximation. Simple formulae for functions of nonstationary vibrational distribution are found for the electronically excited molecules. Some spectral-kinetic dependencies of the excimer luminescence are explained in a new way. The possibilities of the determination of excimer parameters are discussed. The dependence of energetical characteristics of excimer lasers on these parameters is particularly emphasized. (author). 22 refs, 5 figs

Underground measurements of seismic vibrations at the SSC site

International Nuclear Information System (INIS)

Shiltsev, V.D.; Parkhomchuk, V.V.; Weaver, H.J.

1995-01-01

The results of underground measurements of seismic vibrations at the tunnel depth of the Superconducting Super Collider (SSC) site are presented. Spectral analysis of the data obtained in the frequency band from 0.05 Hz to 1500 Hz is performed. It is found that amplitudes of ambient ground motion are less than requirements for the Collider, but cultural vibrations are unacceptably large and will cause fast growth of transverse emittance of the SSC beams

Wave propagation of spectral energy content in a granular chain

Directory of Open Access Journals (Sweden)

Shrivastava Rohit Kumar

2017-01-01

Full Text Available A mechanical wave is propagation of vibration with transfer of energy and momentum. Understanding the spectral energy characteristics of a propagating wave through disordered granular media can assist in understanding the overall properties of wave propagation through inhomogeneous materials like soil. The study of these properties is aimed at modeling wave propagation for oil, mineral or gas exploration (seismic prospecting or non-destructive testing of the internal structure of solids. The focus is on the total energy content of a pulse propagating through an idealized one-dimensional discrete particle system like a mass disordered granular chain, which allows understanding the energy attenuation due to disorder since it isolates the longitudinal P-wave from shear or rotational modes. It is observed from the signal that stronger disorder leads to faster attenuation of the signal. An ordered granular chain exhibits ballistic propagation of energy whereas, a disordered granular chain exhibits more diffusive like propagation, which eventually becomes localized at long time periods. For obtaining mean-field macroscopic/continuum properties, ensemble averaging has been used, however, such an ensemble averaged spectral energy response does not resolve multiple scattering, leading to loss of information, indicating the need for a different framework for micro-macro averaging.

Stochastic models for surface diffusion of molecules

Energy Technology Data Exchange (ETDEWEB)

Shea, Patrick, E-mail: patrick.shea@dal.ca; Kreuzer, Hans Jürgen [Department of Physics and Atmospheric Science, Dalhousie University, Halifax, Nova Scotia B3H 3J5 (Canada)

2014-07-28

We derive a stochastic model for the surface diffusion of molecules, starting from the classical equations of motion for an N-atom molecule on a surface. The equation of motion becomes a generalized Langevin equation for the center of mass of the molecule, with a non-Markovian friction kernel. In the Markov approximation, a standard Langevin equation is recovered, and the effect of the molecular vibrations on the diffusion is seen to lead to an increase in the friction for center of mass motion. This effective friction has a simple form that depends on the curvature of the lowest energy diffusion path in the 3N-dimensional coordinate space. We also find that so long as the intramolecular forces are sufficiently strong, memory effects are usually not significant and the Markov approximation can be employed, resulting in a simple one-dimensional model that can account for the effect of the dynamics of the molecular vibrations on the diffusive motion.

Study of core support barrel vibration monitoring using ex-core neutron noise analysis and fuzzy logic algorithm

International Nuclear Information System (INIS)

Christian, Robby; Song, Seon Ho; Kang, Hyun Gook

2015-01-01

The application of neutron noise analysis (NNA) to the ex-core neutron detector signal for monitoring the vibration characteristics of a reactor core support barrel (CSB) was investigated. Ex-core flux data were generated by using a nonanalog Monte Carlo neutron transport method in a simulated CSB model where the implicit capture and Russian roulette technique were utilized. First and third order beam and shell modes of CSB vibration were modeled based on parallel processing simulation. A NNA module was developed to analyze the ex-core flux data based on its time variation, normalized power spectral density, normalized cross-power spectral density, coherence, and phase differences. The data were then analyzed with a fuzzy logic module to determine the vibration characteristics. The ex-core neutron signal fluctuation was directly proportional to the CSB's vibration observed at 8Hz and15Hzin the beam mode vibration, and at 8Hz in the shell mode vibration. The coherence result between flux pairs was unity at the vibration peak frequencies. A distinct pattern of phase differences was observed for each of the vibration models. The developed fuzzy logic module demonstrated successful recognition of the vibration frequencies, modes, orders, directions, and phase differences within 0.4 ms for the beam and shell mode vibrations.

Perceptual Space of Superimposed Dual-Frequency Vibrations in the Hands.

Science.gov (United States)

Hwang, Inwook; Seo, Jeongil; Choi, Seungmoon

2017-01-01

The use of distinguishable complex vibrations that have multiple spectral components can improve the transfer of information by vibrotactile interfaces. We investigated the qualitative characteristics of dual-frequency vibrations as the simplest complex vibrations compared to single-frequency vibrations. Two psychophysical experiments were conducted to elucidate the perceptual characteristics of these vibrations by measuring the perceptual distances among single-frequency and dual-frequency vibrations. The perceptual distances of dual-frequency vibrations between their two frequency components along their relative intensity ratio were measured in Experiment I. The estimated perceptual spaces for three frequency conditions showed non-linear perceptual differences between the dual-frequency and single-frequency vibrations. A perceptual space was estimated from the measured perceptual distances among ten dual-frequency compositions and five single-frequency vibrations in Experiment II. The effect of the component frequency and the frequency ratio was revealed in the perceptual space. In a percept of dual-frequency vibration, the lower frequency component showed a dominant effect. Additionally, the perceptual difference among single-frequency and dual-frequency vibrations were increased with a low relative difference between two frequencies of a dual-frequency vibration. These results are expected to provide a fundamental understanding about the perception of complex vibrations to enrich the transfer of information using vibrotactile stimuli.

Spectral analysis by correlation

International Nuclear Information System (INIS)

Fauque, J.M.; Berthier, D.; Max, J.; Bonnet, G.

1969-01-01

The spectral density of a signal, which represents its power distribution along the frequency axis, is a function which is of great importance, finding many uses in all fields concerned with the processing of the signal (process identification, vibrational analysis, etc...). Amongst all the possible methods for calculating this function, the correlation method (correlation function calculation + Fourier transformation) is the most promising, mainly because of its simplicity and of the results it yields. The study carried out here will lead to the construction of an apparatus which, coupled with a correlator, will constitute a set of equipment for spectral analysis in real time covering the frequency range 0 to 5 MHz. (author) [fr

Spectral Dependent Degradation of the Solar Diffuser on Suomi-NPP VIIRS Due to Surface Roughness-Induced Rayleigh Scattering

Directory of Open Access Journals (Sweden)

Xi Shao

2016-03-01

Full Text Available The Visible Infrared Imaging Radiometer Suite (VIIRS onboard Suomi National Polar Orbiting Partnership (SNPP uses a solar diffuser (SD as its radiometric calibrator for the reflective solar band calibration. The SD is made of Spectralon™ (one type of fluoropolymer and was chosen because of its controlled reflectance in the Visible/Near-Infrared/Shortwave-Infrared region and its near-Lambertian reflectance property. On-orbit changes in VIIRS SD reflectance as monitored by the Solar Diffuser Stability Monitor showed faster degradation of SD reflectance for 0.4 to 0.6 µm channels than the longer wavelength channels. Analysis of VIIRS SD reflectance data show that the spectral dependent degradation of SD reflectance in short wavelength can be explained with a SD Surface Roughness (length scale << wavelength based Rayleigh Scattering (SRRS model due to exposure to solar UV radiation and energetic particles. The characteristic length parameter of the SD surface roughness is derived from the long term reflectance data of the VIIRS SD and it changes at approximately the tens of nanometers level over the operational period of VIIRS. This estimated roughness length scale is consistent with the experimental result from radiation exposure of a fluoropolymer sample and validates the applicability of the Rayleigh scattering-based model. The model is also applicable to explaining the spectral dependent degradation of the SDs on other satellites. This novel approach allows us to better understand the physical processes of the SD degradation, and is complementary to previous mathematics based models.

Structural determination of some uranyl compounds by vibrational spectroscopy

International Nuclear Information System (INIS)

Rodriguez S, A.; Martinez Q, E.

1990-07-01

The vibrational spectra of different uranyl compounds has been studied and of it spectral information has been used the fundamental asymmetric vibrational frequency, to determine the length and constant bond force U=O by means of the combination of the concept of absorbed energy and the mathematical expression of Badger modified by Jones. It is intended a factor that simplifies the mathematical treatment and the results are compared with the values obtained for other methods. (Author)

Piezoelectric energy harvesting from broadband random vibrations

International Nuclear Information System (INIS)

Adhikari, S; Friswell, M I; Inman, D J

2009-01-01

Energy harvesting for the purpose of powering low power electronic sensor systems has received explosive attention in the last few years. Most works using deterministic approaches focusing on using the piezoelectric effect to harvest ambient vibration energy have concentrated on cantilever beams at resonance using harmonic excitation. Here, using a stochastic approach, we focus on using a stack configuration and harvesting broadband vibration energy, a more practically available ambient source. It is assumed that the ambient base excitation is stationary Gaussian white noise, which has a constant power-spectral density across the frequency range considered. The mean power acquired from a piezoelectric vibration-based energy harvester subjected to random base excitation is derived using the theory of random vibrations. Two cases, namely the harvesting circuit with and without an inductor, have been considered. Exact closed-form expressions involving non-dimensional parameters of the electromechanical system have been given and illustrated using numerical examples

Piezoelectric energy harvesting from broadband random vibrations

Science.gov (United States)

Adhikari, S.; Friswell, M. I.; Inman, D. J.

2009-11-01

Energy harvesting for the purpose of powering low power electronic sensor systems has received explosive attention in the last few years. Most works using deterministic approaches focusing on using the piezoelectric effect to harvest ambient vibration energy have concentrated on cantilever beams at resonance using harmonic excitation. Here, using a stochastic approach, we focus on using a stack configuration and harvesting broadband vibration energy, a more practically available ambient source. It is assumed that the ambient base excitation is stationary Gaussian white noise, which has a constant power-spectral density across the frequency range considered. The mean power acquired from a piezoelectric vibration-based energy harvester subjected to random base excitation is derived using the theory of random vibrations. Two cases, namely the harvesting circuit with and without an inductor, have been considered. Exact closed-form expressions involving non-dimensional parameters of the electromechanical system have been given and illustrated using numerical examples.

Interstitial diffusion in crystal and the Moessbauer effect

International Nuclear Information System (INIS)

Dzyublik, A.Ya.

1976-01-01

The role of different vibrational states of a crystal is taken into account in the model of interstitial uncorrelated jumps. The relation of the diffusion coefficient for an interstitial with probabilities of jumps is found. The cross section for resonant absorption of γ-quanta by a nucleus of a diffusing atom in a crystal is calculated. The existence of vibrational levels is shown to lead to less broadening and intensity of the Moessbauer line than those predicted by the simple model of jumps. The absorption line shape for atom jumping through octahedral sites in bcc lattice is investigated [ru

Chromophore-Dependent Intramolecular Exciton-Vibrational Coupling in the FMO Complex: Quantification and Importance for Exciton Dynamics.

Science.gov (United States)

Padula, Daniele; Lee, Myeong H; Claridge, Kirsten; Troisi, Alessandro

2017-11-02

In this paper, we adopt an approach suitable for monitoring the time evolution of the intramolecular contribution to the spectral density of a set of identical chromophores embedded in their respective environments. We apply the proposed method to the Fenna-Matthews-Olson (FMO) complex, with the objective to quantify the differences among site-dependent spectral densities and the impact of such differences on the exciton dynamics of the system. Our approach takes advantage of the vertical gradient approximation to reduce the computational demands of the normal modes analysis. We show that the region of the spectral density that is believed to strongly influence the exciton dynamics changes significantly in the timescale of tens of nanoseconds. We then studied the impact of the intramolecular vibrations on the exciton dynamics by considering a model of FMO in a vibronic basis and neglecting the interaction with the environment to isolate the role of the intramolecular exciton-vibration coupling. In agreement with the assumptions in the literature, we demonstrate that high frequency modes at energy much larger than the excitonic energy splitting have negligible influence on exciton dynamics despite the large exciton-vibration coupling. We also find that the impact of including the site-dependent spectral densities on exciton dynamics is not very significant, indicating that it may be acceptable to apply the same spectral density on all sites. However, care needs to be taken for the description of the exciton-vibrational coupling in the low frequency part of intramolecular modes because exciton dynamics is more susceptible to low frequency modes despite their small Huang-Rhys factors.

SNAPSHOT SPECTRAL AND COLOR IMAGING USING A REGULAR DIGITAL CAMERA WITH A MONOCHROMATIC IMAGE SENSOR

Directory of Open Access Journals (Sweden)

J. Hauser

2017-10-01

Full Text Available Spectral imaging (SI refers to the acquisition of the three-dimensional (3D spectral cube of spatial and spectral data of a source object at a limited number of wavelengths in a given wavelength range. Snapshot spectral imaging (SSI refers to the instantaneous acquisition (in a single shot of the spectral cube, a process suitable for fast changing objects. Known SSI devices exhibit large total track length (TTL, weight and production costs and relatively low optical throughput. We present a simple SSI camera based on a regular digital camera with (i an added diffusing and dispersing phase-only static optical element at the entrance pupil (diffuser and (ii tailored compressed sensing (CS methods for digital processing of the diffused and dispersed (DD image recorded on the image sensor. The diffuser is designed to mix the spectral cube data spectrally and spatially and thus to enable convergence in its reconstruction by CS-based algorithms. In addition to performing SSI, this SSI camera is capable to perform color imaging using a monochromatic or gray-scale image sensor without color filter arrays.

Precise Multi-Spectral Dermatological Imaging

DEFF Research Database (Denmark)

Gomez, David Delgado; Carstensen, Jens Michael; Ersbøll, Bjarne Kjær

2004-01-01

In this work, an integrated imaging system to obtain accurate and reproducible multi-spectral dermatological images is proposed. The system is made up of an integrating sphere, light emitting diodes and a generic monochromatic camera. The system can collect up to 10 different spectral bands....... These spectral bands vary from ultraviolet to near infrared. The welldefined and diffuse illumination of the optically closed scene aims to avoid shadows and specular reflections. Furthermore, the system has been developed to guarantee the reproducibility of the collected images. This allows for comparative...

Comparison of sEMG processing methods during whole-body vibration exercise.

Science.gov (United States)

Lienhard, Karin; Cabasson, Aline; Meste, Olivier; Colson, Serge S

2015-12-01

The objective was to investigate the influence of surface electromyography (sEMG) processing methods on the quantification of muscle activity during whole-body vibration (WBV) exercises. sEMG activity was recorded while the participants performed squats on the platform with and without WBV. The spikes observed in the sEMG spectrum at the vibration frequency and its harmonics were deleted using state-of-the-art methods, i.e. (1) a band-stop filter, (2) a band-pass filter, and (3) spectral linear interpolation. The same filtering methods were applied on the sEMG during the no-vibration trial. The linear interpolation method showed the highest intraclass correlation coefficients (no vibration: 0.999, WBV: 0.757-0.979) with the comparison measure (unfiltered sEMG during the no-vibration trial), followed by the band-stop filter (no vibration: 0.929-0.975, WBV: 0.661-0.938). While both methods introduced a systematic bias (P interpolation method and the band-stop filter was comparable. The band-pass filter was in poor agreement with the other methods (ICC: 0.207-0.697), unless the sEMG(RMS) was corrected for the bias (ICC ⩾ 0.931, %LOA ⩽ 32.3). In conclusion, spectral linear interpolation or a band-stop filter centered at the vibration frequency and its multiple harmonics should be applied to delete the artifacts in the sEMG signals during WBV. With the use of a band-stop filter it is recommended to correct the sEMG(RMS) for the bias as this procedure improved its performance. Copyright © 2015 Elsevier Ltd. All rights reserved.

Origin of Spectral Band Patterns in the Cosmic Unidentified Infrared Emission

Science.gov (United States)

Álvaro Galué, Héctor; Díaz Leines, Grisell

2017-10-01

The cosmic unidentified infrared emission (UIE) band phenomenon is generally considered as indicative of free-flying polycyclic aromatic hydrocarbon molecules in space. However, a coherent explanation of emission spectral band patterns depending on astrophysical source is yet to be resolved under this attribution. Meanwhile astronomers have restored the alternative origin as due to amorphous carbon particles, but assigning spectral patterns to specific structural elements of particles is equally challenging. Here we report a physical principle in which inclusion of nonplanar structural defects in aromatic core molecular structures (π domains) induces spectral patterns typical of the phenomenon. We show that defects in model π domains modulate the electronic-vibration coupling that activates the delocalized π -electron contribution to aromatic vibrational modes. The modulation naturally disperses C =C stretch modes in band patterns that readily resemble the UIE bands in the elusive 6 - 9 μ m range. The electron-vibration interaction mechanics governing the defect-induced band patterns underscores the importance of π delocalization in the emergence of UIE bands. We discuss the global UIE band regularity of this range as compatible with an emission from the delocalized s p2 phase, as π domains, confined in disordered carbon mixed-phase aggregates.

Geometrical nonlinear free vibration of multi-layered graphene sheets

International Nuclear Information System (INIS)

Wang Jinbao; He Xiaoqiao; Kitipornchai, S; Zhang Hongwu

2011-01-01

A nonlinear continuum model is developed for the nonlinear vibration analysis of multi-layered graphene sheets (MLGSs), in which the nonlinear van der Waals (vdW) interaction between any two layers is formulated explicitly. The nonlinear equations of motion are studied by the harmonic-balance methods. Based on the present model, the nonlinear stiffened amplitude-frequency relations of double-layered graphene sheets (DLGSs) are investigated in the spectral neighbourhood of lower frequencies. The influence of the vdW interaction on the vibration properties of DLGSs is well illustrated by plotting the resulting modes' shapes, in which in-phase and anti-phase vibrations of DLGSs are studied. In particular, the large-amplitude vibration which associates with the anti-phase resonant frequencies, separating DLGS into single-layered GSs, is a promising application that needs to be explored further. In contrast, the vibration modes that are associated with the resonant frequencies are nonidentical and give various vibration patterns, which indicates that MLGSs are highly suited to being used as high-frequency resonators.

Interferometric and nonlinear-optical spectral-imaging techniques for outer space and live cells

Science.gov (United States)

Itoh, Kazuyoshi

2015-12-01

Multidimensional signals such as the spectral images allow us to have deeper insights into the natures of objects. In this paper the spectral imaging techniques that are based on optical interferometry and nonlinear optics are presented. The interferometric imaging technique is based on the unified theory of Van Cittert-Zernike and Wiener-Khintchine theorems and allows us to retrieve a spectral image of an object in the far zone from the 3D spatial coherence function. The retrieval principle is explained using a very simple object. The promising applications to space interferometers for astronomy that are currently in progress will also be briefly touched on. An interesting extension of interferometric spectral imaging is a 3D and spectral imaging technique that records 4D information of objects where the 3D and spectral information is retrieved from the cross-spectral density function of optical field. The 3D imaging is realized via the numerical inverse propagation of the cross-spectral density. A few techniques suggested recently are introduced. The nonlinear optical technique that utilizes stimulated Raman scattering (SRS) for spectral imaging of biomedical targets is presented lastly. The strong signals of SRS permit us to get vibrational information of molecules in the live cell or tissue in real time. The vibrational information of unstained or unlabeled molecules is crucial especially for medical applications. The 3D information due to the optical nonlinearity is also the attractive feature of SRS spectral microscopy.

Energy calibration issues in nuclear resonant vibrational spectroscopy: observing small spectral shifts and making fast calibrations.

Science.gov (United States)

Wang, Hongxin; Yoda, Yoshitaka; Dong, Weibing; Huang, Songping D

2013-09-01

The conventional energy calibration for nuclear resonant vibrational spectroscopy (NRVS) is usually long. Meanwhile, taking NRVS samples out of the cryostat increases the chance of sample damage, which makes it impossible to carry out an energy calibration during one NRVS measurement. In this study, by manipulating the 14.4 keV beam through the main measurement chamber without moving out the NRVS sample, two alternative calibration procedures have been proposed and established: (i) an in situ calibration procedure, which measures the main NRVS sample at stage A and the calibration sample at stage B simultaneously, and calibrates the energies for observing extremely small spectral shifts; for example, the 0.3 meV energy shift between the 100%-(57)Fe-enriched [Fe4S4Cl4](=) and 10%-(57)Fe and 90%-(54)Fe labeled [Fe4S4Cl4](=) has been well resolved; (ii) a quick-switching energy calibration procedure, which reduces each calibration time from 3-4 h to about 30 min. Although the quick-switching calibration is not in situ, it is suitable for normal NRVS measurements.

Vibrational dynamics of aqueous hydroxide solutions probed using broadband 2DIR spectroscopy

International Nuclear Information System (INIS)

Mandal, Aritra; Tokmakoff, Andrei

2015-01-01

We employed ultrafast transient absorption and broadband 2DIR spectroscopy to study the vibrational dynamics of aqueous hydroxide solutions by exciting the O–H stretch vibrations of the strongly hydrogen-bonded hydroxide solvation shell water and probing the continuum absorption of the solvated ion between 1500 and 3800 cm −1 . We observe rapid vibrational relaxation processes on 150–250 fs time scales across the entire probed spectral region as well as slower vibrational dynamics on 1–2 ps time scales. Furthermore, the O–H stretch excitation loses its frequency memory in 180 fs, and vibrational energy exchange between bulk-like water vibrations and hydroxide-associated water vibrations occurs in ∼200 fs. The fast dynamics in this system originate in strong nonlinear coupling between intra- and intermolecular vibrations and are explained in terms of non-adiabatic vibrational relaxation. These measurements indicate that the vibrational dynamics of the aqueous hydroxide complex are faster than the time scales reported for long-range transport of protons in aqueous hydroxide solutions

Synchrotron radiation in the Far-Infrared: Adsorbate-substrate vibrations and resonant interactions

International Nuclear Information System (INIS)

Hoffmann, F.M.; Williams, G.P.; Hirschmugl, C.J.; Chabal, Y.J.

1991-01-01

Synchrotron radiation in the Far Infrared offers the potential for a broadband source of high brightness and intensity. Recent development of a Far-Infrared Beamline at the NSLS in Brookhaven provides an unique high intensity source in the FIR spectral range (800-10 cm -1 ). This talk reviews its application to surface vibrational spectroscopy of low frequency adsorbate-substrate vibrations and resonant interactions on metal surfaces

Fast and accurate implementation of Fourier spectral approximations of nonlocal diffusion operators and its applications

International Nuclear Information System (INIS)

Du, Qiang; Yang, Jiang

2017-01-01

This work is concerned with the Fourier spectral approximation of various integral differential equations associated with some linear nonlocal diffusion and peridynamic operators under periodic boundary conditions. For radially symmetric kernels, the nonlocal operators under consideration are diagonalizable in the Fourier space so that the main computational challenge is on the accurate and fast evaluation of their eigenvalues or Fourier symbols consisting of possibly singular and highly oscillatory integrals. For a large class of fractional power-like kernels, we propose a new approach based on reformulating the Fourier symbols both as coefficients of a series expansion and solutions of some simple ODE models. We then propose a hybrid algorithm that utilizes both truncated series expansions and high order Runge–Kutta ODE solvers to provide fast evaluation of Fourier symbols in both one and higher dimensional spaces. It is shown that this hybrid algorithm is robust, efficient and accurate. As applications, we combine this hybrid spectral discretization in the spatial variables and the fourth-order exponential time differencing Runge–Kutta for temporal discretization to offer high order approximations of some nonlocal gradient dynamics including nonlocal Allen–Cahn equations, nonlocal Cahn–Hilliard equations, and nonlocal phase-field crystal models. Numerical results show the accuracy and effectiveness of the fully discrete scheme and illustrate some interesting phenomena associated with the nonlocal models.

Fiber Bragg Grating vibration sensor with DFB laser diode

Science.gov (United States)

Siska, Petr; Brozovic, Martin; Cubik, Jakub; Kepak, Stanislav; Vitasek, Jan; Koudelka, Petr; Latal, Jan; Vasinek, Vladimir

2012-01-01

The Fiber Bragg Grating (FBG) sensors are nowadays used in many applications. Thanks to its quite big sensitivity to a surrounding environment, they can be used for sensing of temperature, strain, vibration or pressure. A fiber Bragg grating vibration sensor, which is interrogated by a distributed feedback laser diode (DFB) is demonstrated in this article. The system is based on the intensity modulation of the narrow spectral bandwidth of the DFB laser, when the reflection spectrum of the FBG sensor is shifted due to the strain that is applied on it in form of vibrations caused by acoustic wave pressure from loud speaker. The sensor's response in frequency domain and strain is measured; also the factor of sensor pre-strain impact on its sensitivity is discussed.

Quantum diffusion of light interstitials in metals

International Nuclear Information System (INIS)

McMullen, T.; Bergersen, B.

1978-01-01

A quantum theory of diffusion of self-trapped light interstitials in metals is presented. The theory encompasses both coherent and incoherent tunneling, but the approximation used neglects the dependence of the interstitial transfer matrix element on the vibrational state of the crystal. The coherent tunneling contribution is estimated by fitting the incoherent diffusion rate to experimental data for hydrogen and muon diffusion. It is predicted that coherent diffusion should be dominant below approximately 80 K for H in Nb and below approximately 190 K for μ + in Cu. Experimental verifications of these predictions would require high purity strain free samples and low concentrations of the diffusing species. (author)

Digital analysis of vibrations

International Nuclear Information System (INIS)

Bohnstedt, H.J.; Walter, G.

1982-01-01

Vibrational measurements, e.g. on turbomachinery, can be evaluated rapidly and economically with the aid of a combination of the following instruments: a desk-top computer, a two-channel vector filter and a FFT spectral analyzer. This equipment combination is available within the Allianz Centre for Technology and has also been used for mobile, on-site investigations during the last year. It enables calculation and display of time functions, kinetic shaft orbits, displacement diagrams. Bode plots, polar-coordinate plots, cascade diagrams and histograms. (orig.) [de

Multigrid treatment of implicit continuum diffusion

Science.gov (United States)

Francisquez, Manaure; Zhu, Ben; Rogers, Barrett

2017-10-01

Implicit treatment of diffusive terms of various differential orders common in continuum mechanics modeling, such as computational fluid dynamics, is investigated with spectral and multigrid algorithms in non-periodic 2D domains. In doubly periodic time dependent problems these terms can be efficiently and implicitly handled by spectral methods, but in non-periodic systems solved with distributed memory parallel computing and 2D domain decomposition, this efficiency is lost for large numbers of processors. We built and present here a multigrid algorithm for these types of problems which outperforms a spectral solution that employs the highly optimized FFTW library. This multigrid algorithm is not only suitable for high performance computing but may also be able to efficiently treat implicit diffusion of arbitrary order by introducing auxiliary equations of lower order. We test these solvers for fourth and sixth order diffusion with idealized harmonic test functions as well as a turbulent 2D magnetohydrodynamic simulation. It is also shown that an anisotropic operator without cross-terms can improve model accuracy and speed, and we examine the impact that the various diffusion operators have on the energy, the enstrophy, and the qualitative aspect of a simulation. This work was supported by DOE-SC-0010508. This research used resources of the National Energy Research Scientific Computing Center (NERSC).

Spectral decomposition in advection-diffusion analysis by finite element methods

International Nuclear Information System (INIS)

Nickell, R.E.; Gartling, D.K.; Strang, G.

1978-01-01

In a recent study of the convergence properties of finite element methods in nonlinear fluid mechanics, an indirect approach was taken. A two-dimensional example with a known exact solution was chosen as the vehicle for the study, and various mesh refinements were tested in an attempt to extract information on the effect of the local Reynolds number. However, more direct approaches are usually preferred. In this study one such direct approach is followed, based upon the spectral decomposition of the solution operator. Spectral decomposition is widely employed as a solution technique for linear structural dynamics problems and can be applied readily to linear, transient heat transfer analysis; in this case, the extension to nonlinear problems is of interest. It was shown previously that spectral techniques were applicable to stiff systems of rate equations, while recent studies of geometrically and materially nonlinear structural dynamics have demonstrated the increased information content of the numerical results. The use of spectral decomposition in nonlinear problems of heat and mass transfer would be expected to yield equally increased flow of information to the analyst, and this information could include a quantitative comparison of various solution strategies, meshes, and element hierarchies

Health State Monitoring of Bladed Machinery with Crack Growth Detection in BFG Power Plant Using an Active Frequency Shift Spectral Correction Method

Directory of Open Access Journals (Sweden)

Weifang Sun

2017-08-01

Full Text Available Power generation using waste-gas is an effective and green way to reduce the emission of the harmful blast furnace gas (BFG in pig-iron producing industry. Condition monitoring of mechanical structures in the BFG power plant is of vital importance to guarantee their safety and efficient operations. In this paper, we describe the detection of crack growth of bladed machinery in the BFG power plant via vibration measurement combined with an enhanced spectral correction technique. This technique enables high-precision identification of amplitude, frequency, and phase information (the harmonic information belonging to deterministic harmonic components within the vibration signals. Rather than deriving all harmonic information using neighboring spectral bins in the fast Fourier transform spectrum, this proposed active frequency shift spectral correction method makes use of some interpolated Fourier spectral bins and has a better noise-resisting capacity. We demonstrate that the identified harmonic information via the proposed method is of suppressed numerical error when the same level of noises is presented in the vibration signal, even in comparison with a Hanning-window-based correction method. With the proposed method, we investigated vibration signals collected from a centrifugal compressor. Spectral information of harmonic tones, related to the fundamental working frequency of the centrifugal compressor, is corrected. The extracted spectral information indicates the ongoing development of an impeller blade crack that occurred in the centrifugal compressor. This method proves to be a promising alternative to identify blade cracks at early stages.

Health State Monitoring of Bladed Machinery with Crack Growth Detection in BFG Power Plant Using an Active Frequency Shift Spectral Correction Method.

Science.gov (United States)

Sun, Weifang; Yao, Bin; He, Yuchao; Chen, Binqiang; Zeng, Nianyin; He, Wangpeng

2017-08-09

Power generation using waste-gas is an effective and green way to reduce the emission of the harmful blast furnace gas (BFG) in pig-iron producing industry. Condition monitoring of mechanical structures in the BFG power plant is of vital importance to guarantee their safety and efficient operations. In this paper, we describe the detection of crack growth of bladed machinery in the BFG power plant via vibration measurement combined with an enhanced spectral correction technique. This technique enables high-precision identification of amplitude, frequency, and phase information (the harmonic information) belonging to deterministic harmonic components within the vibration signals. Rather than deriving all harmonic information using neighboring spectral bins in the fast Fourier transform spectrum, this proposed active frequency shift spectral correction method makes use of some interpolated Fourier spectral bins and has a better noise-resisting capacity. We demonstrate that the identified harmonic information via the proposed method is of suppressed numerical error when the same level of noises is presented in the vibration signal, even in comparison with a Hanning-window-based correction method. With the proposed method, we investigated vibration signals collected from a centrifugal compressor. Spectral information of harmonic tones, related to the fundamental working frequency of the centrifugal compressor, is corrected. The extracted spectral information indicates the ongoing development of an impeller blade crack that occurred in the centrifugal compressor. This method proves to be a promising alternative to identify blade cracks at early stages.

An introduction to random vibrations, spectral & wavelet analysis

CERN Document Server

Newland, D E

2005-01-01

One of the first engineering books to cover wavelet analysis, this classic text describes and illustrates basic theory, with a detailed explanation of the workings of discrete wavelet transforms. Computer algorithms are explained and supported by examples and a set of problems, and an appendix lists ten computer programs for calculating and displaying wavelet transforms.Starting with an introduction to probability distributions and averages, the text examines joint probability distributions, ensemble averages, and correlation; Fourier analysis; spectral density and excitation response relation

Wave propagation of spectral energy content in a granular chain

NARCIS (Netherlands)

Shrivastava, Rohit Kumar; Luding, Stefan

2017-01-01

A mechanical wave is propagation of vibration with transfer of energy and momentum. Understanding the spectral energy characteristics of a propagating wave through disordered granular media can assist in understanding the overall properties of wave propagation through inhomogeneous materials like

Vibrational entropies in metallic alloys

Science.gov (United States)

Ozolins, Vidvuds; Asta, Mark; Wolverton, Christopher

2000-03-01

Recently, it has been recognized that vibrational entropy can have significant effects on the phase stability of metallic alloys. Using density functional linear response calculations and molecular dynamics simulations we study three representative cases: (i) phase diagram of Al-rich Al-Sc alloys, (ii) stability of precipitate phases in CuAl_2, and (iii) phonon dynamics in bcc Zr. We find large vibrational entropy effects in all cases. In the Al-Sc system, vibrations increase the solid solubility of Sc in Al by decreasing the stability of the L12 (Al_3Sc) phase. This leads to a nearly ten-fold increase in the solid solubility of Sc in Al at T=800 K. In the Cu-Al system, our calculations predict that the tetragonal Laves phase of CuAl2 has 0.35 kB/atom higher vibrational entropy than the cubic CaF_2-type phase (the latter is predicted to be the T=0 K ground state of CuAl_2). This entropy difference causes a structural transformation in CuAl2 precipitates from the fluorite to the tetragonal Laves phase around T=500 K. Finally, we analyze the highly unusual dynamics of anharmonically stabilized bcc Zr, finding large diffuse-scattering intensity streaks between the bcc Bragg peaks.

Advanced Engine Health Management Applications of the SSME Real-Time Vibration Monitoring System

Science.gov (United States)

Fiorucci, Tony R.; Lakin, David R., II; Reynolds, Tracy D.; Turner, James E. (Technical Monitor)

2000-01-01

The Real Time Vibration Monitoring System (RTVMS) is a 32-channel high speed vibration data acquisition and processing system developed at Marshall Space Flight Center (MSFC). It Delivers sample rates as high as 51,200 samples/second per channel and performs Fast Fourier Transform (FFT) processing via on-board digital signal processing (DSP) chips in a real-time format. Advanced engine health assessment is achieved by utilizing the vibration spectra to provide accurate sensor validation and enhanced engine vibration redlines. Discrete spectral signatures (such as synchronous) that are indicators of imminent failure can be assessed and utilized to mitigate catastrophic engine failures- a first in rocket engine health assessment. This paper is presented in viewgraph form.

Control method for multi-input multi-output non-Gaussian random vibration test with cross spectra consideration

Directory of Open Access Journals (Sweden)

Ronghui ZHENG

2017-12-01

Full Text Available A control method for Multi-Input Multi-Output (MIMO non-Gaussian random vibration test with cross spectra consideration is proposed in the paper. The aim of the proposed control method is to replicate the specified references composed of auto spectral densities, cross spectral densities and kurtoses on the test article in the laboratory. It is found that the cross spectral densities will bring intractable coupling problems and induce difficulty for the control of the multi-output kurtoses. Hence, a sequential phase modification method is put forward to solve the coupling problems in multi-input multi-output non-Gaussian random vibration test. To achieve the specified responses, an improved zero memory nonlinear transformation is utilized first to modify the Fourier phases of the signals with sequential phase modification method to obtain one frame reference response signals which satisfy the reference spectra and reference kurtoses. Then, an inverse system method is used in frequency domain to obtain the continuous stationary drive signals. At the same time, the matrix power control algorithm is utilized to control the spectra and kurtoses of the response signals further. At the end of the paper, a simulation example with a cantilever beam and a vibration shaker test are implemented and the results support the proposed method very well. Keywords: Cross spectra, Kurtosis control, Multi-input multi-output, Non-Gaussian, Random vibration test

Resonance tunneling electron-vibrational spectroscopy of polyoxometalates.

Science.gov (United States)

Dalidchik, F I; Kovalevskii, S A; Balashov, E M

2017-05-21

The tunneling spectra of the ordered monolayer films of decamolybdodicobaltate (DMDC) compounds deposited from aqueous solutions on HOPG were measured by scanning tunnel microscopy in air. The DMDC spectra, as well as the tunneling spectra of other polyoxometalates (POMs), exhibit well-defined negative differential resistances (NDRs). The mechanism of formation of these spectral features was established from the collection of revealed NDR dependences on the external varying parameters and found to be common to all systems exhibiting Wannier-Stark localization. A model of biresonance tunneling was developed to provide an explanation for the totality of experimental data, both the literature and original, on the tunneling POM probing. A variant of the tunneling electron-vibrational POM spectroscopy was proposed allowing the determination of the three basic energy parameters-energy gaps between the occupied and unoccupied states, frequencies of the vibrational transitions accompanying biresonance electron-tunneling processes, and electron-vibrational interaction constants on the monomolecular level.

Quantum Monte Carlo for vibrating molecules

International Nuclear Information System (INIS)

Brown, W.R.; Lawrence Berkeley National Lab., CA

1996-08-01

Quantum Monte Carlo (QMC) has successfully computed the total electronic energies of atoms and molecules. The main goal of this work is to use correlation function quantum Monte Carlo (CFQMC) to compute the vibrational state energies of molecules given a potential energy surface (PES). In CFQMC, an ensemble of random walkers simulate the diffusion and branching processes of the imaginary-time time dependent Schroedinger equation in order to evaluate the matrix elements. The program QMCVIB was written to perform multi-state VMC and CFQMC calculations and employed for several calculations of the H 2 O and C 3 vibrational states, using 7 PES's, 3 trial wavefunction forms, two methods of non-linear basis function parameter optimization, and on both serial and parallel computers. In order to construct accurate trial wavefunctions different wavefunctions forms were required for H 2 O and C 3 . In order to construct accurate trial wavefunctions for C 3 , the non-linear parameters were optimized with respect to the sum of the energies of several low-lying vibrational states. In order to stabilize the statistical error estimates for C 3 the Monte Carlo data was collected into blocks. Accurate vibrational state energies were computed using both serial and parallel QMCVIB programs. Comparison of vibrational state energies computed from the three C 3 PES's suggested that a non-linear equilibrium geometry PES is the most accurate and that discrete potential representations may be used to conveniently determine vibrational state energies

Force Limited Random Vibration Test of TESS Camera Mass Model

Science.gov (United States)

Karlicek, Alexandra; Hwang, James Ho-Jin; Rey, Justin J.

2015-01-01

The Transiting Exoplanet Survey Satellite (TESS) is a spaceborne instrument consisting of four wide field-of-view-CCD cameras dedicated to the discovery of exoplanets around the brightest stars. As part of the environmental testing campaign, force limiting was used to simulate a realistic random vibration launch environment. While the force limit vibration test method is a standard approach used at multiple institutions including Jet Propulsion Laboratory (JPL), NASA Goddard Space Flight Center (GSFC), European Space Research and Technology Center (ESTEC), and Japan Aerospace Exploration Agency (JAXA), it is still difficult to find an actual implementation process in the literature. This paper describes the step-by-step process on how the force limit method was developed and applied on the TESS camera mass model. The process description includes the design of special fixtures to mount the test article for properly installing force transducers, development of the force spectral density using the semi-empirical method, estimation of the fuzzy factor (C2) based on the mass ratio between the supporting structure and the test article, subsequent validating of the C2 factor during the vibration test, and calculation of the C.G. accelerations using the Root Mean Square (RMS) reaction force in the spectral domain and the peak reaction force in the time domain.

Demonstrating the feasibility of monitoring the molecular-level structures of moving polymer/silane interfaces during silane diffusion using SFG.

Science.gov (United States)

Chen, Chunyan; Wang, Jie; Loch, Cheryl L; Ahn, Dongchan; Chen, Zhan

2004-02-04

In this paper, the feasibility of monitoring molecular structures at a moving polymer/liquid interface by sum frequency generation (SFG) vibrational spectroscopy has been demonstrated. N-(2-Aminoethyl)-3-aminopropyltrimethoxysilane (AATM, NH2(CH2)2NH(CH2)3Si(OCH3)3) has been brought into contact with a deuterated poly(methyl methacrylate) (d-PMMA) film, and the interfacial silane structure has been monitored using SFG. Upon initial contact, the SFG spectra can be detected, but as time progresses, the spectral intensity changes and finally disappears. Additional experiments indicate that these silane molecules can diffuse into the polymer film and the detected SFG signals are actually from the moving polymer/silane interface. Our results show that the molecular order of the polymer/silane interface exists during the entire diffusion process and is lost when the silane molecules traverse through the thickness of the d-PMMA film. The loss of the SFG signal is due to the formation of a new disordered substrate/silane interface, which contributes no detectable SFG signal. The kinetics of the diffusion of the silane into the polymer have been deduced from the time-dependent SFG signals detected from the AATM molecules as they diffuse through polymer films of different thickness.

PREFACE: Vibrations at surfaces Vibrations at surfaces

Science.gov (United States)

Rahman, Talat S.

2011-12-01

Central Florida, Orlando, in March 2010. Several speakers at this meeting were invited to contribute to the special section in this issue. As is clear from the articles in this special section, the phenomenon of vibrations at surfaces continues to be a dynamic field of investigation. In fact, there is a resurgence of effort because the insights provided by surface dynamics are still fundamental to the development of an understanding of the microscopic factors that control surface structure formation, diffusion, reaction and structural stability. Examination of dynamics at surfaces thus complements and supplements the wealth of information that is obtained from real-space techniques such as scanning tunneling microscopy. Vibrational dynamics is, of course, not limited to surfaces. Surfaces are important since they provide immediate deviation from the bulk. They display how lack of symmetry can lead to new structures, new local atomic environments and new types of dynamical modes. Nanoparticles, large molecules and nanostructures of all types, in all kinds of local environments, provide further examples of regions of reduced symmetry and coordination, and hence display characteristic vibrational modes. Given the tremendous advance in the synthesis of a variety of nanostructures whose functionalization would pave the way for nanotechnology, there is even greater need to engage in experimental and theoretical techniques that help extract their vibrational dynamics. Such knowledge would enable a more complete understanding and characterization of these nanoscale systems than would otherwise be the case. The papers presented here provide excellent examples of the kind of information that is revealed by vibrations at surfaces. Vibrations at surface contents Poisoning and non-poisoning oxygen on Cu(410)L Vattuone, V Venugopal, T Kravchuk, M Smerieri, L Savio and M Rocca Modifying protein adsorption by layers of glutathione pre-adsorbed on Au(111)Anne Vallée, Vincent Humblot

Automation of vibroacoustic data bank for random vibration criteria development. [for the space shuttle and launch vehicles

Science.gov (United States)

Ferebee, R. C.

1982-01-01

A computerized data bank system was developed for utilization of large amounts of vibration and acoustic data to formulate component random vibration design and test criteria. This system consists of a computer, graphics tablet, and a dry-silver hard copier which are all desk-top type hardware and occupy minimal space. The data bank contains data from the Saturn V and Titan III flight and static test programs. The vibration and acoustic data are stored in the form of power spectral density and one-third octave band plots over the frequency range from 20 to 2000 Hz. The data was stored by digitizing each spectral plot by tracing with the graphics tablet. The digitized data was statistically analyzed and the resulting 97.5% probability levels were stored on tape along with the appropriate structural parameters. Standard extrapolation procedures were programmed for prediction of component random vibration test criteria for new launch vehicle and payload configurations. This automated vibroacoustic data bank system greatly enhances the speed and accuracy of formulating vibration test criteria. In the future, the data bank will be expanded to include all data acquired from the space shuttle flight test program.

Vibration and Noise in Magnetic Resonance Imaging of the Vocal Tract: Differences between Whole-Body and Open-Air Devices.

Science.gov (United States)

Přibil, Jiří; Přibilová, Anna; Frollo, Ivan

2018-04-05

This article compares open-air and whole-body magnetic resonance imaging (MRI) equipment working with a weak magnetic field as regards the methods of its generation, spectral properties of mechanical vibration and acoustic noise produced by gradient coils during the scanning process, and the measured noise intensity. These devices are used for non-invasive MRI reconstruction of the human vocal tract during phonation with simultaneous speech recording. In this case, the vibration and noise have negative influence on quality of speech signal. Two basic measurement experiments were performed within the paper: mapping sound pressure levels in the MRI device vicinity and picking up vibration and noise signals in the MRI scanning area. Spectral characteristics of these signals are then analyzed statistically and compared visually and numerically.

Absolute vibrational numbering from isotope shifts in fragmentary spectroscopic data

Science.gov (United States)

Pashov, A.; Kowalczyk, P.; Jastrzebski, W.

2018-05-01

We discuss application of the isotope effect to establish the absolute vibrational numbering in electronic states of diatomic molecules. This is illustrated by examples of states with potential energy curves of both regular and irregular shape, with one or two potential minima. The minimum number of spectroscopic data (either term values or spectral line positions) necessary to provide a unique numbering is considered. We show that at favourable conditions just four term energies (or spectral lines) in one isotopologue and one term energy in the other suffice.

Sub-THz spectroscopic characterization of vibrational modes in artificially designed DNA monocrystal

International Nuclear Information System (INIS)

Sizov, Igor; Rahman, Masudur; Gelmont, Boris; Norton, Michael L.; Globus, Tatiana

2013-01-01

Highlights: • Sub-THz spectroscopy is used to characterize artificially designed DNA monocrystal. • Results are obtained using a novel near field, RT, frequency domain spectrometer. • Narrow resonances of 0.1 cm −1 width in absorption spectra of crystal are observed. • Signature measured between 310 and 490 GHz is reproducible and well resolved. • Absorption pattern is explained in part by simulation results from dsDNA fragment. - Abstract: Sub-terahertz (sub-THz) vibrational spectroscopy is a new spectroscopic branch for characterizing biological macromolecules. In this work, highly resolved sub-THz resonance spectroscopy is used for characterizing engineered molecular structures, an artificially designed DNA monocrystal, built from a short DNA sequence. Using a recently developed frequency domain spectroscopic instrument operating at room temperature with high spectral and spatial resolution, we demonstrated very intense and specific spectral lines from a DNA crystal in general agreement with a computational molecular dynamics (MD) simulation of a short double stranded DNA fragment. The spectroscopic signature measured in the frequency range between 310 and 490 GHz is rich in well resolved and reproducible spectral features thus demonstrating the capability of THz resonance spectroscopy to be used for characterizing custom macromolecules and structures designed and implemented via nanotechnology for a wide variety of application domains. Analysis of MD simulation indicates that intense and narrow vibrational modes with atomic movements perpendicular (transverse) and parallel (longitudinal) to the long DNA axis coexist in dsDNA, with much higher contribution from longitudinal vibrations

An adaptive demodulation approach for bearing fault detection based on adaptive wavelet filtering and spectral subtraction

Science.gov (United States)

Zhang, Yan; Tang, Baoping; Liu, Ziran; Chen, Rengxiang

2016-02-01

Fault diagnosis of rolling element bearings is important for improving mechanical system reliability and performance. Vibration signals contain a wealth of complex information useful for state monitoring and fault diagnosis. However, any fault-related impulses in the original signal are often severely tainted by various noises and the interfering vibrations caused by other machine elements. Narrow-band amplitude demodulation has been an effective technique to detect bearing faults by identifying bearing fault characteristic frequencies. To achieve this, the key step is to remove the corrupting noise and interference, and to enhance the weak signatures of the bearing fault. In this paper, a new method based on adaptive wavelet filtering and spectral subtraction is proposed for fault diagnosis in bearings. First, to eliminate the frequency associated with interfering vibrations, the vibration signal is bandpass filtered with a Morlet wavelet filter whose parameters (i.e. center frequency and bandwidth) are selected in separate steps. An alternative and efficient method of determining the center frequency is proposed that utilizes the statistical information contained in the production functions (PFs). The bandwidth parameter is optimized using a local ‘greedy’ scheme along with Shannon wavelet entropy criterion. Then, to further reduce the residual in-band noise in the filtered signal, a spectral subtraction procedure is elaborated after wavelet filtering. Instead of resorting to a reference signal as in the majority of papers in the literature, the new method estimates the power spectral density of the in-band noise from the associated PF. The effectiveness of the proposed method is validated using simulated data, test rig data, and vibration data recorded from the transmission system of a helicopter. The experimental results and comparisons with other methods indicate that the proposed method is an effective approach to detecting the fault-related impulses

An adaptive demodulation approach for bearing fault detection based on adaptive wavelet filtering and spectral subtraction

International Nuclear Information System (INIS)

Zhang, Yan; Tang, Baoping; Chen, Rengxiang; Liu, Ziran

2016-01-01

Fault diagnosis of rolling element bearings is important for improving mechanical system reliability and performance. Vibration signals contain a wealth of complex information useful for state monitoring and fault diagnosis. However, any fault-related impulses in the original signal are often severely tainted by various noises and the interfering vibrations caused by other machine elements. Narrow-band amplitude demodulation has been an effective technique to detect bearing faults by identifying bearing fault characteristic frequencies. To achieve this, the key step is to remove the corrupting noise and interference, and to enhance the weak signatures of the bearing fault. In this paper, a new method based on adaptive wavelet filtering and spectral subtraction is proposed for fault diagnosis in bearings. First, to eliminate the frequency associated with interfering vibrations, the vibration signal is bandpass filtered with a Morlet wavelet filter whose parameters (i.e. center frequency and bandwidth) are selected in separate steps. An alternative and efficient method of determining the center frequency is proposed that utilizes the statistical information contained in the production functions (PFs). The bandwidth parameter is optimized using a local ‘greedy’ scheme along with Shannon wavelet entropy criterion. Then, to further reduce the residual in-band noise in the filtered signal, a spectral subtraction procedure is elaborated after wavelet filtering. Instead of resorting to a reference signal as in the majority of papers in the literature, the new method estimates the power spectral density of the in-band noise from the associated PF. The effectiveness of the proposed method is validated using simulated data, test rig data, and vibration data recorded from the transmission system of a helicopter. The experimental results and comparisons with other methods indicate that the proposed method is an effective approach to detecting the fault-related impulses

Spectral studies of new fullerene-tetrathiafulvalene based system

International Nuclear Information System (INIS)

Laskowska, Barbara; Lapinski, Andrzej; Graja, Andrzej; Hudhomme, Pietrick

2007-01-01

Molecular and electronic structures as well as electronic and vibrational spectra of compounds 1-3 were investigated. The spectra were recorded in the large spectral range from 400 to 50,000 cm -1 ; our interest was focused on the electronic excitations of both moieties of the dyad and the intramolecular vibrations of the dyad's components. With the help of the Gaussian 03 program, molecular geometry, electron structure and normal mode analysis for the dyad and/or reference compounds were studied. An assignment of the main vibrational bands of the dyad and its reference molecules was made taking into consideration their IR and Raman spectra as well as results of the normal mode analysis. In principle, the intramolecular vibrations typical for C 60 and tetrathiafulvalene (TTF) derivatives can be found in the spectra of the dyad; the bands' frequencies are insignificantly shifted comparing with the separated molecules but their shape is usually modified. It suggests that symmetry and molecular structure of both components of the dyad are rather kept after dyad's formation but redistribution of charges occurs

Modification of kaolinite surfaces through mechanochemical activation with quartz: A diffuse reflectance infrared fourier transform and chemometrics study.

Science.gov (United States)

Carmody, Onuma; Frost, Ray L; Kristóf, János; Kokot, Serge; Kloprogge, J Theo; Makó, Eva

2006-12-01

Studies of kaolinite surfaces are of industrial importance. One useful method for studying the changes in kaolinite surface properties is to apply chemometric analyses to the kaolinite surface infrared spectra. A comparison is made between the mechanochemical activation of Kiralyhegy kaolinites with significant amounts of natural quartz and the mechanochemical activation of Zettlitz kaolinite with added quartz. Diffuse reflectance infrared Fourier transform (DRIFT) spectra were analyzed using principal component analysis (PCA) and multi-criteria decision making (MCDM) methods, the preference ranking organization method for enrichment evaluations (PROMETHEE) and geometrical analysis for interactive assistance (GAIA). The clear discrimination of the Kiralyhegy spectral objects on the two PC scores plots (400-800 and 800-2030 cm(-1)) indicated the dominance of quartz. Importantly, no ordering of any spectral objects appeared to be related to grinding time in the PC plots of these spectral regions. Thus, neither the kaolinite nor the quartz are systematically responsive to grinding time according to the spectral criteria investigated. The third spectral region (2600-3800 cm(-1), OH vibrations), showed apparent systematic ordering of the Kiralyhegy and, to a lesser extent, Zettlitz spectral objects with grinding time. This was attributed to the effect of the natural quartz on the delamination of kaolinite and the accompanying phenomena (i.e., formation of kaolinite spheres and water). The mechanochemical activation of kaolinite and quartz, through dry grinding, results in changes to the surface structure. Different grinding times were adopted to study the rate of destruction of the kaolinite and quartz structures. This relationship (i.e., grinding time) was classified using PROMETHEE and GAIA methodology.

Laser method of acoustical emission control from vibrating surfaces

Science.gov (United States)

Motyka, Zbigniew

2013-01-01

For limitation of the noise in environment, the necessity occurs of determining and location of sources of sounds emitted from surfaces of many machines and devices, assuring in effect the possibility of suitable constructional changes implementation, targeted at decreasing of their nuisance. In the paper, the results of tests and calculations are presented for plane surface sources emitting acoustic waves. The tests were realized with the use of scanning laser vibrometer which enabled remote registration and the spectral analysis of the surfaces vibrations. The known hybrid digital method developed for determination of sound wave emission from such surfaces divided into small finite elements was slightly modified by distinguishing the phase correlations between such vibrating elements. The final method being developed may find use in wide range of applications for different forms of vibrations of plane surfaces.

Task-specific recruitment of motor units for vibration damping.

Science.gov (United States)

Wakeling, James M; Liphardt, Anna-Maria

2006-01-01

Vibrations occur within the soft tissues of the lower extremities due to the heel-strike impact during walking. Increases in muscle activity in the lower extremities result in increased damping to reduce this vibration. The myoelectric intensity spectra were compared using principal component analysis from the tibialis anterior and lateral gastrocnemius of 40 subjects walking with different shoe conditions. The soft insert condition resulted in a significant, simultaneous increase in muscle activity with a shift to higher myoelectric frequencies in the period 0-60 ms after heel-strike which is the period when the greater vibration damping occurred. These increases in myoelectric frequency match the spectral patterns which indicate increases in recruitment of faster motor units. It is concluded that fast motor units are recruited during the task of damping the soft-tissue resonance that occurs following heel-strike.

Vibrational relaxation and energy transfer of matrix isolated HCl and DCl

Energy Technology Data Exchange (ETDEWEB)

Wiesenfeld, J.M.

1977-12-01

Vibrational kinetic and spectroscopic studies have been performed on matrix-isolated HCl and DCl between 9 and 20 K. Vibrational relaxation rates for v = 2 and v = 1 were measured by a tunable infrared laser-induced, time-resolved fluorescence technique. In an Ar matrix, vibrational decay times are faster than radiative and it is found that HCl relaxes about 35 times more rapidly than CCl, in spite of the fact that HCl must transfer more energy to the lattice than DCl. This result is explained by postulating that the rate-determining step for vibrational relaxation produces a highly rotationally excited guest in a V yield R step; rotational relaxation into lattice phonons follows rapidly. HCl v = 1, but not v = 2, excitation rapidly diffuses through the sample by a resonant dipole-dipole vibrational energy transfer process. Molecular complexes, and in particular the HCl dimer, relax too rapidly for direct observation, less than or approximately 1 ..mu..s, and act as energy sinks in the energy diffusion process. The temperature dependence for all these processes is weak--less than a factor of two between 9 and 20 K. Vibrational relaxation of HCl in N/sub 2/ and O/sub 2/ matrices is unobservable, presumably due to rapid V yield V transfer to the host. A V yield R binary collision model for relaxation in solids is successful in explaining the HCl(DCl)/Ar results as well as results of other experimenters. The model considers relaxation to be the result of ''collisions'' due to molecular motion in quantized lattice normal modes--gas phase potential parameters can fit the matrix kinetic data.

Vibrational relaxation and energy transfer of matrix isolated HCl and DCl

International Nuclear Information System (INIS)

Wiesenfeld, J.M.

1977-12-01

Vibrational kinetic and spectroscopic studies have been performed on matrix-isolated HCl and DCl between 9 and 20 K. Vibrational relaxation rates for v = 2 and v = 1 were measured by a tunable infrared laser-induced, time-resolved fluorescence technique. In an Ar matrix, vibrational decay times are faster than radiative and it is found that HCl relaxes about 35 times more rapidly than CCl, in spite of the fact that HCl must transfer more energy to the lattice than DCl. This result is explained by postulating that the rate-determining step for vibrational relaxation produces a highly rotationally excited guest in a V yield R step; rotational relaxation into lattice phonons follows rapidly. HCl v = 1, but not v = 2, excitation rapidly diffuses through the sample by a resonant dipole-dipole vibrational energy transfer process. Molecular complexes, and in particular the HCl dimer, relax too rapidly for direct observation, less than or approximately 1 μs, and act as energy sinks in the energy diffusion process. The temperature dependence for all these processes is weak--less than a factor of two between 9 and 20 K. Vibrational relaxation of HCl in N 2 and O 2 matrices is unobservable, presumably due to rapid V yield V transfer to the host. A V yield R binary collision model for relaxation in solids is successful in explaining the HCl(DCl)/Ar results as well as results of other experimenters. The model considers relaxation to be the result of ''collisions'' due to molecular motion in quantized lattice normal modes--gas phase potential parameters can fit the matrix kinetic data

Vibrational spectral investigation on xanthine and its derivatives—theophylline, caffeine and theobromine

Science.gov (United States)

Gunasekaran, S.; Sankari, G.; Ponnusamy, S.

2005-01-01

A normal coordinate analysis has been carried out on four compounds having a similar ring structure with different side chain substitutions, which are xanthine, caffeine, theophylline, and theobromine. Xanthine is chemically known as 2,6-dihydroxy purine. Caffeine, theophylline and theobromine are methylated xanthines. Considering the methyl groups as point mass, the number of normal modes of vibrations can be distributed as Γ vib=27 A'+12 A″ based on C s point group symmetry associated with the structures. In the present work 15 A' and 12 A″ normal modes are considered. A new set of orthonormal symmetry co-ordinates have been constructed. Wilson's F- G matrix method has been adopted for the normal coordinate analysis. A satisfactory vibrational band assignment has been made by employing the FTIR and FT Raman spectra of the compounds. The potential energy distribution is calculated with the arrived values of the force constants and hence the agreement of the frequency assignment has been checked.

Vibrational spectral investigation on xanthine and its derivatives--theophylline, caffeine and theobromine.

Science.gov (United States)

Gunasekaran, S; Sankari, G; Ponnusamy, S

2005-01-01

A normal coordinate analysis has been carried out on four compounds having a similar ring structure with different side chain substitutions, which are xanthine, caffeine, theophylline, and theobromine. Xanthine is chemically known as 2,6-dihydroxy purine. Caffeine, theophylline and theobromine are methylated xanthines. Considering the methyl groups as point mass, the number of normal modes of vibrations can be distributed as Gamma(vib) = 27 A' + 12 A" based on C(s) point group symmetry associated with the structures. In the present work 15 A' and 12 A'' normal modes are considered. A new set of orthonormal symmetry co-ordinates have been constructed. Wilson's F-G matrix method has been adopted for the normal coordinate analysis. A satisfactory vibrational band assignment has been made by employing the FTIR and FT Raman spectra of the compounds. The potential energy distribution is calculated with the arrived values of the force constants and hence the agreement of the frequency assignment has been checked.

Anomalous diffusion of fermions in superlattices

International Nuclear Information System (INIS)

Drozdz, S.; Okolowicz, J.; Srokowski, T.; Ploszajczak, M.

1996-03-01

Diffusion of fermions in the periodic two-dimensional lattice of fermions is studied. It is shown that effects connected with antisymmetrization of the wave function increase chaoticness of motion. Various types of anomalous diffusion, characterized by a power spectral analysis are found. The nonlocality of the Pauli potential destroys cantori in the phase space. Consequently, the diffusion process is dominated by long free paths and the power spectrum is logarithmic at small frequency limit. (author)

Whole-Body Vibration in Farming: Background Document for Creating a Simplified Procedure to Determine Agricultural Tractor Vibration Comfort

Directory of Open Access Journals (Sweden)

Maurizio Cutini

2017-09-01

Full Text Available Operator exposure to high levels of whole-body vibration (WBV presents risks to health and safety and it is reported to worsen or even cause back injuries. Work activities resulting in operator exposure to whole-body vibration have a common onset in off-road work such as farming. Despite the wide variability of agricultural surface profiles, studies have shown that with changing soil profile and tractor speed, the accelerations resulting from ground input present similar spectral trends. While on the one hand such studies confirmed that tractor WBV emission levels are very dependent upon the nature of the operation performed, on the other, irrespective of the wide range of conditions characterizing agricultural operations, they led researchers to set up a possible and realistic simplification and standardization of tractor driver comfort testing activities. The studies presented herewith indicate the usefulness, and the possibility, of developing simplified procedures to determine agricultural tractor vibration comfort. The results obtained could be used effectively to compare tractors of the same category or a given tractor when equipped with different seats, suspension, tyres, etc.

Vibrational properties of complex solids

International Nuclear Information System (INIS)

Fagas, G.

1999-11-01

Following a brief outline of the statistical analysis of spectra with respect to random matrix theory predictions and of numerical methods for calculating the elastic scattering matrix, statistical studies of vibrational spectra in disordered and complex solids, as well as studies of phonon transport across imperfect structures, are presented. The analysis of spectral statistics of lattice modes in a disordered crystal, confirmed GOE Wigner-Dyson statistical correlations of the eigenmode frequencies of a block of a disordered solid. Spectral correlations in the optic phonon spectrum of a solid with a polyatomic unit cell are also analysed using the Wigner-Dyson statistical approach. Despite the fact that all force constants are real, it is demonstrated that the statistics are predominantly of the GUE type depending on the location within the Brillouin zone of a crystal and the unit cell symmetry. Analytic and numerical results for the crossover from GOE to GUE statistics are presented. A method originally developed to probe electron transport on a mesoscopic scale is used to study generic properties of elastic phonon transport at a disordered interface. The results show that phonon transmittance is a strong function of frequency and the disorder correlation length. At low frequencies the transmittance at a given frequency increases as the correlation length decreases. This is also reflected by different power-laws for phonon conductance across correlated and uncorrelated disordered interfaces which are in approximate agreement with perturbation theory of an elastic continuum. Finally we present an analysis of acoustic-phonon propagation across long, free-standing, insulating wires with rough surfaces. We find that owing to a crossover from ballistic propagation of the lowest-frequency phonon mode at ω 1 πc/W to a diffusive (or even localized) behavior upon the increase of phonon frequency, followed by reentrance into the quasiballistic regime, the heat

Vibration and Noise in Magnetic Resonance Imaging of the Vocal Tract: Differences between Whole-Body and Open-Air Devices

Directory of Open Access Journals (Sweden)

Jiří Přibil

2018-04-01

Full Text Available This article compares open-air and whole-body magnetic resonance imaging (MRI equipment working with a weak magnetic field as regards the methods of its generation, spectral properties of mechanical vibration and acoustic noise produced by gradient coils during the scanning process, and the measured noise intensity. These devices are used for non-invasive MRI reconstruction of the human vocal tract during phonation with simultaneous speech recording. In this case, the vibration and noise have negative influence on quality of speech signal. Two basic measurement experiments were performed within the paper: mapping sound pressure levels in the MRI device vicinity and picking up vibration and noise signals in the MRI scanning area. Spectral characteristics of these signals are then analyzed statistically and compared visually and numerically.

Process and system for isotope separation using the selective vibrational excitation of molecules

International Nuclear Information System (INIS)

Woodroffe, J.A.; Keck, J.C.

1976-01-01

This invention concerns the separation of isotopes by using the isotopically selective vibrational excitation and the vibration-translation reactions of the excited particles. UF 6 molecular mixed with a carrier gas, such as argon, are directed through a refrigerated chamber lighted by a laser radiation tuned to excite vibrationally the uranium hexafluoride molecules of a particular uranium isotope. The density of the carrier gas is preferably maintained above the density of the uranium hexafluoride to allow a greater collision probability of the vibrationally excited molecules with a carried molecule. In such a case, the vibrationally excited uranium hexafluoride will collide with a carrier gas molecule provoking the conversion of the excitation energy into a translation of the excited molecule, resulting in thermal energy or greater diffusibility than that of the other uranium hexafluoride molecules [fr

Comparative Study of Time-Frequency Decomposition Techniques for Fault Detection in Induction Motors Using Vibration Analysis during Startup Transient

Directory of Open Access Journals (Sweden)

Paulo Antonio Delgado-Arredondo

2015-01-01

Full Text Available Induction motors are critical components for most industries and the condition monitoring has become necessary to detect faults. There are several techniques for fault diagnosis of induction motors and analyzing the startup transient vibration signals is not as widely used as other techniques like motor current signature analysis. Vibration analysis gives a fault diagnosis focused on the location of spectral components associated with faults. Therefore, this paper presents a comparative study of different time-frequency analysis methodologies that can be used for detecting faults in induction motors analyzing vibration signals during the startup transient. The studied methodologies are the time-frequency distribution of Gabor (TFDG, the time-frequency Morlet scalogram (TFMS, multiple signal classification (MUSIC, and fast Fourier transform (FFT. The analyzed vibration signals are one broken rotor bar, two broken bars, unbalance, and bearing defects. The obtained results have shown the feasibility of detecting faults in induction motors using the time-frequency spectral analysis applied to vibration signals, and the proposed methodology is applicable when it does not have current signals and only has vibration signals. Also, the methodology has applications in motors that are not fed directly to the supply line, in such cases the analysis of current signals is not recommended due to poor current signal quality.

Employing optical code division multiple access technology in the all fiber loop vibration sensor system

Science.gov (United States)

Tseng, Shin-Pin; Yen, Chih-Ta; Syu, Rong-Shun; Cheng, Hsu-Chih

2013-12-01

This study proposes a spectral amplitude coding-optical code division multiple access (SAC-OCDMA) framework to access the vibration frequency of a test object on the all fiber loop vibration sensor (AFLVS). Each user possesses an individual SAC, and fiber Bragg grating (FBG) encoders/decoders using multiple FBG arrays were adopted, providing excellent orthogonal properties in the frequency domain. The system also mitigates multiple access interference (MAI) among users. When an optical fiber is bent to a point exceeding the critical radius, the fiber loop sensor becomes sensitive to external physical parameters (e.g., temperature, strain, and vibration). The AFLVS involves placing a fiber loop with a specific radius on a designed vibration platform.

Moessbauer effect and vacancy diffusion

International Nuclear Information System (INIS)

Gunther, L.

1976-01-01

A dynamical theory of vacancy diffusion which was motivated by the need to explain recent experimental results for the Moessbauer spectra of Fe in Cu, Fe in Au and Fe in Al is presented. Diffusion in these systems is dominated by the vacancy mechanism, which involves strong correlations between successive jumps. The theory developed by Singwi and Sjoelander for the Moessbauer spectrum of a diffusing nucleus is therefore not applicable. The inverse of the normalized Moessbauer spectrum evaluated at zero frequency is introduced as a useful means of comparing experimental with theoretical spectral widths

On the bi-dimensional variational decomposition applied to nonstationary vibration signals for rolling bearing crack detection in coal cutters

International Nuclear Information System (INIS)

Jiang, Yu; Li, Zhixiong; Zhang, Chao; Peng, Z; Hu, Chao

2016-01-01

This work aims to detect rolling bearing cracks using a variational approach. An original method that appropriately incorporates bi-dimensional variational mode decomposition (BVMD) into discriminant diffusion maps (DDM) is proposed to analyze the nonstationary vibration signals recorded from the cracked rolling bearings in coal cutters. The advantage of this variational decomposition based diffusion map (VDDM) method in comparison to the current DDM is that the intrinsic vibration mode of the crack can be filtered into a limited bandwidth in the frequency domain with an estimated central frequency, thus discarding the interference signal components in the vibration signals and significantly improving the crack detection performance. In addition, the VDDM is able to simultaneously process two-channel sensor signals to reduce information leakage. Experimental validation using rolling bearing crack vibration signals demonstrates that the VDDM separated the raw signals into four intrinsic modes, including one roller vibration mode, one roller cage vibration mode, one inner race vibration mode, and one outer race vibration mode. Hence, reliable fault features were extracted from the outer race vibration mode, and satisfactory crack identification performance was achieved. The comparison between the proposed VDDM and existing approaches indicated that the VDDM method was more efficient and reliable for crack detection in coal cutter rolling bearings. As an effective catalyst for rolling bearing crack detection, this newly proposed method is useful for practical applications. (paper)

Frontside-micromachined planar piezoresistive vibration sensor: Evaluating performance in the low frequency test range

Directory of Open Access Journals (Sweden)

Lan Zhang

2014-01-01

Full Text Available Using a surface piezoresistor diffusion method and front-side only micromachining process, a planar piezoresistive vibration sensor was successfully developed with a simple structure, lower processing cost and fewer packaging difficulties. The vibration sensor had a large sector proof mass attached to a narrow flexure. Optimization of the boron diffusion piezoresistor placed on the edge of the narrow flexure greatly improved the sensitivity. Planar vibration sensors were fabricated and measured in order to analyze the effects of the sensor dimensions on performance, including the values of flexure width and the included angle of the sector. Sensitivities of fabricated planar sensors of 0.09–0.46 mV/V/g were measured up to a test frequency of 60 Hz. The sensor functioned at low voltages (<3 V and currents (<1 mA with a high sensitivity and low drift. At low background noise levels, the sensor had performance comparable to a commercial device.

Frontside-micromachined planar piezoresistive vibration sensor: Evaluating performance in the low frequency test range

Energy Technology Data Exchange (ETDEWEB)

Zhang, Lan; Lu, Jian, E-mail: jian-lu@aist.go.jp; Takagi, Hideki; Maeda, Ryutaro [Research Center for Ubiquitous MEMS and Micro Engineering (UMEMSME), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki, 305-8564 (Japan)

2014-01-15

Using a surface piezoresistor diffusion method and front-side only micromachining process, a planar piezoresistive vibration sensor was successfully developed with a simple structure, lower processing cost and fewer packaging difficulties. The vibration sensor had a large sector proof mass attached to a narrow flexure. Optimization of the boron diffusion piezoresistor placed on the edge of the narrow flexure greatly improved the sensitivity. Planar vibration sensors were fabricated and measured in order to analyze the effects of the sensor dimensions on performance, including the values of flexure width and the included angle of the sector. Sensitivities of fabricated planar sensors of 0.09–0.46 mV/V/g were measured up to a test frequency of 60 Hz. The sensor functioned at low voltages (<3 V) and currents (<1 mA) with a high sensitivity and low drift. At low background noise levels, the sensor had performance comparable to a commercial device.

SAFARI 2000 AERONET-derived Diffuse Spectral Irradiance for Eight Core Sites

Data.gov (United States)

National Aeronautics and Space Administration — This data set contains monthly mean values of diffuse irradiance fraction [f(Ediff), or ratio of diffuse-to-total irradiance] at ground level for a 30-degree solar...

Vibrational spectra of 1-hydroxy- and 1,4-dihydroxyanthraquinones and their magnesium chelate complexes. I. Isotopic effects of OH/OD and 24Mg/26Mg substitutions

International Nuclear Information System (INIS)

Kirszenbaum, Marek

1977-01-01

The vibrational spectra of 1-hydroxy- and 1,4-dihydroxyanthraquinones, their deuterated derivatives and their 24 Mg/ 26 Mg chelate complexes are examined in the spectral region 1700-250cm -1 . The study of deuteroxyanthraquinones allow an assignment of the OH/OD group vibrations and show the multiple coupling of the delta OH vibrations with the vCC and delta CH quinonic vibrations. These results lead to a modification of some spectral assignments of magnesium chelate complexe of 1-OH-AQ. The isotopic 24 Mg/ 26 Mg substitution enables the chelate ring vibrations which depend on the motions of the magnesium atom to be observed. The vC=O and vC-O vibrations frequencies of magnesium chelate complexe [Mg(1,4-O 2 -AQ)]sub(n) show an important difference of the chelate ring electronic state in comparison of those of 1,4-(OH) 2 -AQ. The discussion of the infrared and Raman spectra in the Mg-O vibrations region lead to the conclusion that the configuration of oxygens arround the magnesium is tetrahedral [fr

Development of Surfaces Optically Suitable for Flat Solar Panels. [using a reflectometer which separately evaluates spectral and diffuse reflectivities of surfaces

Science.gov (United States)

1979-01-01

A reflectometer which can separately evaluate the spectral and diffuse reflectivities of surfaces is described. A phase locked detection system for the reflectometer is also described. A selective coating on aluminum potentially useful for flat plate solar collector applications is presented. The coating is composed of strongly bound copper oxide (divalent) and is formed by an etching process performed on an aluminum alloy with high copper content. Fabrication costs are expected to be small due to the one stop fabrication process. A number of conclusions gathered from the literature as to the required optical properties of flat plate solar collectors are discussed.

A Patch Density Recommendation based on Convergence Studies for Vehicle Panel Vibration Response resulting from Excitation by a Diffuse Acoustic Field

Science.gov (United States)

Smith, Andrew; LaVerde, Bruce; Jones, Douglas; Towner, Robert; Waldon, James; Hunt, Ron

2013-01-01

Producing fluid structural interaction estimates of panel vibration from an applied pressure field excitation are quite dependent on the spatial correlation of the pressure field. There is a danger of either over estimating a low frequency response or under predicting broad band panel response in the more modally dense bands if the pressure field spatial correlation is not accounted for adequately. It is a useful practice to simulate the spatial correlation of the applied pressure field over a 2d surface using a matrix of small patch area regions on a finite element model (FEM). Use of a fitted function for the spatial correlation between patch centers can result in an error if the choice of patch density is not fine enough to represent the more continuous spatial correlation function throughout the intended frequency range of interest. Several patch density assumptions to approximate the fitted spatial correlation function are first evaluated using both qualitative and quantitative illustrations. The actual response of a typical vehicle panel system FEM is then examined in a convergence study where the patch density assumptions are varied over the same model. The convergence study results illustrate the impacts possible from a poor choice of patch density on the analytical response estimate. The fitted correlation function used in this study represents a diffuse acoustic field (DAF) excitation of the panel to produce vibration response.

The validation of an aerospace structure through the sine vibration analysis

Directory of Open Access Journals (Sweden)

Cristina-Diana BRATU

2018-06-01

Full Text Available Sinusoidal vibrations represent an ideal case. Technically, it is quite hard to generate pure sinusoidal vibrations without containing other spectral components, called harmonics. Sinusoidal vibrations can appear on propeller, propulsion and turbofan aircraft as well as on helicopters and aerospace structures. They can occur during different phases of flight (take-off, ascent, cruise, landing, etc.. The aim of this article is to present how a structure can be validated by using the mathematical formulas or a FEM software such as PATRAN-NASTRAN (and the equations behind it. As an application, an aerospace structure such as thruster brackets will be analyzed. A sinusoidal signal of 1g was applied on the attachment points and the response was read from the center of gravity of the thrusters.

Magnetostrictive clad steel plates for high-performance vibration energy harvesting

Science.gov (United States)

Yang, Zhenjun; Nakajima, Kenya; Onodera, Ryuichi; Tayama, Tsuyoki; Chiba, Daiki; Narita, Fumio

2018-02-01

Energy harvesting technology is becoming increasingly important with the appearance of the Internet of things. In this study, a magnetostrictive clad steel plate for harvesting vibration energy was proposed. It comprises a cold-rolled FeCo alloy and cold-rolled steel joined together by thermal diffusion bonding. The performances of the magnetostrictive FeCo clad steel plate and conventional FeCo plate cantilevers were compared under bending vibration; the results indicated that the clad steel plate construct exhibits high voltage and power output compared to a single-plate construct. Finite element analysis of the cantilevers under bending provided insights into the magnetic features of a clad steel plate, which is crucial for its high performance. For comparison, the experimental results of a commercial piezoelectric bimorph cantilever were also reported. In addition, the cold-rolled FeCo and Ni alloys were joined by thermal diffusion bonding, which exhibited outstanding energy harvesting performance. The larger the plate volume, the more the energy generated. The results of this study indicated not only a promising application for the magnetostrictive FeCo clad steel plate as an efficient energy harvester, related to small vibrations, but also the notable feasibility for the formation of integrated units to support high-power trains, automobiles, and electric vehicles.

Pattern recognition based on time-frequency analysis and convolutional neural networks for vibrational events in φ-OTDR

Science.gov (United States)

Xu, Chengjin; Guan, Junjun; Bao, Ming; Lu, Jiangang; Ye, Wei

2018-01-01

Based on vibration signals detected by a phase-sensitive optical time-domain reflectometer distributed optical fiber sensing system, this paper presents an implement of time-frequency analysis and convolutional neural network (CNN), used to classify different types of vibrational events. First, spectral subtraction and the short-time Fourier transform are used to enhance time-frequency features of vibration signals and transform different types of vibration signals into spectrograms, which are input to the CNN for automatic feature extraction and classification. Finally, by replacing the soft-max layer in the CNN with a multiclass support vector machine, the performance of the classifier is enhanced. Experiments show that after using this method to process 4000 vibration signal samples generated by four different vibration events, namely, digging, walking, vehicles passing, and damaging, the recognition rates of vibration events are over 90%. The experimental results prove that this method can automatically make an effective feature selection and greatly improve the classification accuracy of vibrational events in distributed optical fiber sensing systems.

Vibration Analysis for Steam Dryer of APR1400 Steam Generator

Energy Technology Data Exchange (ETDEWEB)

Han, Sung-heum; Ko, Doyoung [KHNP CRI, Daejeon (Korea, Republic of); Cho, Minki [Doosan Heavy Industry, Changwon (Korea, Republic of)

2016-10-15

This paper is related to comprehensive vibration assessment program for APR1400 steam generator internals. According to U.S. Nuclear Regulatory Commission, Regulatory Guide 1.20 (Rev.3, March 2007), we conducted vibration analysis for a steam dryer as the second steam separator of steam generator internals. The vibration analysis was performed at the 100 % power operating condition as the normal operation condition. The random hydraulic loads were calculated by the computational fluid dynamics and the structural responses were predicted by power spectral density analysis for the probabilistic method. In order to meet the recently revised U.S. NRC RG 1.20 Rev.3, the CVAP against the potential adverse flow effects in APR1400 SG internals should be performed. This study conducted the vibration response analysis for the SG steam dryer as the second moisture separator at the 100% power condition, and evaluated the structural integrity. The predicted alternating stress intensities were evaluated to have more than 17.78 times fatigue margin compared to the endurance limit.

Technical progress report: Completion of spectral rotating shadowband radiometers and analysis of atmospheric radiation measurement spectral shortwave data

Energy Technology Data Exchange (ETDEWEB)

Michalsky, J.; Harrison, L. [State Univ. of New York, Albany, NY (United States)

1996-04-01

Our goal in the Atmospheric Radiation Measurement (ARM) Program is the improvement of radiation models used in general circulation models (GCMs), especially in the shortwave, (1) by providing improved shortwave radiometric measurements for the testing of models and (2) by developing methods for retrieving climatologically sensitive parameters that serve as input to shortwave and longwave models. At the Atmospheric Sciences Research Center (ASRC) in Albany, New York, we are acquiring downwelling direct and diffuse spectral irradiance, at six wavelengths, plus downwelling broadband longwave, and upwelling and downwelling broadband shortwave irradiances that we combine with National Weather Service surface and upper air data from the Albany airport as a test data set for ARM modelers. We have also developed algorithms to improve shortwave measurements made at the Southern Great Plains (SGP) ARM site by standard thermopile instruments and by the multifilter rotating shadowband radiometer (MFRSR) based on these Albany data sets. Much time has been spent developing techniques to retrieve column aerosol, water vapor, and ozone from the direct beam spectral measurements of the MFRSR. Additionally, we have had success in calculating shortwave surface albedo and aerosol optical depth from the ratio of direct to diffuse spectral reflectance.

Structural and vibrational spectral investigations of melaminium glutarate monohydrate by FTIR, FT-Raman and DFT methods

Science.gov (United States)

Arjunan, V.; Marchewka, M. K.; Raj, Arushma; Yang, Haifeng; Mohan, S.

2015-01-01

Melaminium glutarate monohydrate has been synthesised and FTIR and FT-Raman spectral investigations are carried out. The molecular geometry and vibrational frequencies of melaminium glutarate monohydrate in the ground state have been determined by using B3LYP method with 6-31++G**, 6-31++G and cc-pVDZ basis sets. The stability of the system, inter molecular hydrogen bonding and the electron donor-acceptor interactions of the complex have been investigated by using natural bonding orbital analysis. It reveals that the Nsbnd H⋯O and Osbnd H⋯O intermolecular interactions significantly influence crystal packing of this molecular complex. The glutarate anion forms hydrogen bonds to the melaminium cation as the proton donor of the type Nsbnd H⋯O with a distance (N⋯O) = 2.51 Å. It is also linked by other hydrogen bonds to the water molecule of the type Osbnd H⋯O with (O⋯O) = 2.82 Å and to the amino (sbnd NH2) group of melaminium cation of the type Nsbnd H⋯O with (N⋯O) = 2.82 Å as the proton acceptor. The electrostatic potential of the complex is in the range +1.892e × 10-2 to -1.892e × 10-2. The limits of total electron density of the complex is +6.679e × 10-2 to -6.679e × 10-2.

Structural and vibrational spectral investigations of melaminium glutarate monohydrate by FTIR, FT-Raman and DFT methods.

Science.gov (United States)

Arjunan, V; Marchewka, M K; Raj, Arushma; Yang, Haifeng; Mohan, S

2015-01-25

Melaminium glutarate monohydrate has been synthesised and FTIR and FT-Raman spectral investigations are carried out. The molecular geometry and vibrational frequencies of melaminium glutarate monohydrate in the ground state have been determined by using B3LYP method with 6-31++G(**), 6-31++G and cc-pVDZ basis sets. The stability of the system, inter molecular hydrogen bonding and the electron donor-acceptor interactions of the complex have been investigated by using natural bonding orbital analysis. It reveals that the N-H⋯O and O-H⋯O intermolecular interactions significantly influence crystal packing of this molecular complex. The glutarate anion forms hydrogen bonds to the melaminium cation as the proton donor of the type N-H⋯O with a distance (N⋯O)=2.51 Å. It is also linked by other hydrogen bonds to the water molecule of the type O-H⋯O with (O⋯O)=2.82 Å and to the amino (NH2) group of melaminium cation of the type N-H⋯O with (N⋯O)=2.82 Å as the proton acceptor. The electrostatic potential of the complex is in the range +1.892e×10(-2) to -1.892e×10(-2). The limits of total electron density of the complex is +6.679e×10(-2) to -6.679e×10(-2). Copyright © 2014 Elsevier B.V. All rights reserved.

Vibrational Spectroscopies and Chemometry for Nondestructive Identification and Differentiation of Painting Binders

Directory of Open Access Journals (Sweden)

Serena Carlesi

2017-01-01

Full Text Available A comprehensive dataset of vibrational spectra of different natural organic binding media is presented and discussed. The binding media were applied on a glass substrate and analyzed after three months of natural ageing. The combination of Raman and FT-NIR spectroscopies allows for an improved identification of these materials as Raman technique is more informative about the skeletal vibrations, while FT-NIR spectroscopy is more sensitive to the substituents and polar groups. The experimental results are initially discussed in the framework of current spectral assignment. Then, multivariate analysis (PCA is applied leading to differentiation among the samples. The two major principal components allow for a complete separation of the different classes of organic materials. Further differentiation within the same class is possible thanks to the secondary components. The loadings obtained from PCA are discussed on the basis of the spectral assignment leading to clear understanding of the physical basis of this differentiation process.

Semiclassical spectral quantization: Application to two and four coupled molecular degrees of freedom

International Nuclear Information System (INIS)

De Leon, N.; Heller, E.J.

1984-01-01

Semiclassical quantization of the quasiperiodic vibrational motion of molecules is usually based on Einstein--Brillouin--Keller (EBK) conditions for the quantization of the classical actions. Explicit use of the EBK conditions for molecular systems of K degrees of freedom requires K quantization conditions. Therefore, explicit use of the EBK conditions becomes increasingly difficult if not impossible for polyatomic systems of three or more degrees of freedom. In this paper we propose a semiclassical quantization method which makes explicit use of phase coherence of the de Broglie wave associated with the trajectory rather than the EBK conditions. We show that taking advantage of phase coherence reduces the K quantization conditions to a single quantum condition: regardless of the number of degrees of freedom. For reasons that will become obvious we call this method ''spectral quantization.'' Polyatomic vibrational wave functions and energy eigenvalues are generated from quasiperiodic classical trajectories. The spectral method is applied to an ABA linear triatomic molecule with two degrees of freedom and to an anharmonic model of the molecule cyanoacetylene. The usefulness of the technique is demonstrated in this latter calculation since the cyanoacetylene model will have four coupled vibrational degrees of freedom

Sum frequency generation vibrational spectroscopy (SFG-VS) for complex molecular surfaces and interfaces: Spectral lineshape measurement and analysis plus some controversial issues

Science.gov (United States)

Wang, Hong-Fei

2016-12-01

Sum-frequency generation vibrational spectroscopy (SFG-VS) was first developed in the 1980s and it has been proven a uniquely sensitive and surface/interface selective spectroscopic probe for characterization of the structure, conformation and dynamics of molecular surfaces and interfaces. In recent years, there have been many progresses in the development of methodology and instrumentation in the SFG-VS toolbox that have significantly broadened the application to complex molecular surfaces and interfaces. In this review, after presenting a unified view on the theory and methodology focusing on the SFG-VS spectral lineshape, as well as the new opportunities in SFG-VS applications with such developments, some of the controversial issues that have been puzzling the community are discussed. The aim of this review is to present to the researchers and students interested in molecular surfaces and interfacial sciences up-to-date perspectives complementary to the existing textbooks and reviews on SFG-VS.

Parallel two-phase-flow-induced vibrations in fuel pin model

International Nuclear Information System (INIS)

Hara, Fumio; Yamashita, Tadashi

1978-01-01

This paper reports the experimental results of vibrations of a fuel pin model -herein meaning the essential form of a fuel pin from the standpoint of vibration- in a parallel air-and-water two-phase flow. The essential part of the experimental apparatus consisted of a flat elastic strip made of stainless steel, both ends of which were firmly supported in a circular channel conveying the two-phase fluid. Vibrational strain of the fuel pin model, pressure fluctuation of the two-phase flow and two-phase-flow void signals were measured. Statistical measures such as power spectral density, variance and correlation function were calculated. The authors obtained (1) the relation between variance of vibrational strain and two-phase-flow velocity, (2) the relation between variance of vibrational strain and two-phase-flow pressure fluctuation, (3) frequency characteristics of variance of vibrational strain against the dominant frequency of the two-phase-flow pressure fluctuation, and (4) frequency characteristics of variance of vibrational strain against the dominant frequency of two-phase-flow void signals. The authors conclude that there exist two kinds of excitation mechanisms in vibrations of a fuel pin model inserted in a parallel air-and-water two-phase flow; namely, (1) parametric excitation, which occurs when the fundamental natural frequency of the fuel pin model is related to the dominant travelling frequency of water slugs in the two-phase flow by the ratio 1/2, 1/1, 3/2 and so on; and (2) vibrational resonance, which occurs when the fundamental frequency coincides with the dominant frequency of the two-phase-flow pressure fluctuation. (auth.)

Spectral/hp element methods for CFD

CERN Document Server

Karniadakis, George Em

1999-01-01

Traditionally spectral methods in fluid dynamics were used in direct and large eddy simulations of turbulent flow in simply connected computational domains. The methods are now being applied to more complex geometries, and the spectral/hp element method, which incorporates both multi-domain spectral methods and high-order finite element methods, has been particularly successful. This book provides a comprehensive introduction to these methods. Written by leaders in the field, the book begins with a full explanation of fundamental concepts and implementation issues. It then illustrates how these methods can be applied to advection-diffusion and to incompressible and compressible Navier-Stokes equations. Drawing on both published and unpublished material, the book is an important resource for experienced researchers and for those new to the field.

The spectral energy distribution of the scattered light from dark clouds

Science.gov (United States)

Mattila, Kalevi; Schnur, G. F. O.

1989-01-01

A dark cloud is exposed to the ambient radiation field of integrated starlight in the Galaxy. Scattering of starlight by the dust particles gives rise to a diffuse surface brightness of the dark nebula. The intensity and the spectrum of this diffuse radiation can be used to investigate, e.g., the scattering parameters of the dust, the optical thickness of the cloud, and as a probe of the ambient radiation field at the location of the cloud. An understanding of the scattering process is also a prerequisite for the isolation of broad spectral features due to fluorescence or to any other non-scattering origin of the diffuse light. Model calculations are presented for multiple scattering in a spherical cloud. These calculations show that the different spectral shapes of the observed diffuse light can be reproduced with standard dust parameters. The possibility to use the observed spectrum as a diagnostic tool for analyzing the thickness of the cloud and the dust particle is discussed.

Enhancing vibration measurements by Mössbauer effect

Science.gov (United States)

Pasquevich, G. A.; Veiga, A.; Zélis, P. Mendoza; Martínez, N.; van Raap, M. Fernández; Sánchez, F. H.

2014-01-01

The measurement of the Mössbauer effect in a system excited with a periodic perturbation can provide information about it. For that purpose, the Mössbauer absorption of a source-absorber set which hyperfine parameters are well known, is measured at a constant relative velocity (i.e. at a defined spectral energy). The resulting Mössbauer absorption periodic signal provides information of the sample ac perturbation response. This approach has been used time ago to measure small tympanic vibrations (mechanical perturbations). In this work we present an extension of the vibration experiments, by measuring them at various absorber-source relative velocities within a constant-velocity strategy. As a demonstration test, the frequency response of a piezoelectric diaphragm in the 100 Hz-5 kHz range is obtained with a custom electronic counter. The experiments are performed using a 57Co( Rh) source and a 25-m-thick stainless-steel absorber fixed to a piezoelectric diaphragm. Phase shifts and amplitude vibrations with velocities in the range from 1.5 m/s to 20 mm/s are well characterized, extending the linearity limit well beyond the earlier suggested one of 1 mm/s.

Suspension system vibration analysis with regard to variable type ability to smooth road irregularities

Science.gov (United States)

Rykov, S. P.; Rykova, O. A.; Koval, V. S.; Makhno, D. E.; Fedotov, K. V.

2018-03-01

The paper aims to analyze vibrations of the dynamic system equivalent of the suspension system with regard to tyre ability to smooth road irregularities. The research is based on static dynamics for linear systems of automated control, methods of correlation, spectral and numerical analysis. Input of new data on the smoothing effect of the pneumatic tyre reflecting changes of a contact area between the wheel and road under vibrations of the suspension makes the system non-linear which requires using numerical analysis methods. Taking into account the variable smoothing ability of the tyre when calculating suspension vibrations, one can approximate calculation and experimental results and improve the constant smoothing ability of the tyre.

Collective vibrational spectra of α- and γ-glycine studied by terahertz and Raman spectroscopy

International Nuclear Information System (INIS)

Shi Yulei; Wang Li

2005-01-01

Terahertz time-domain spectroscopy is used to investigate the absorption and dispersion of polycrystalline α- and γ-glycine in the spectral region 0.5-3.0 THz. The spectra exhibit distinct features in these two crystalline phases. The observed far-infrared responses are attributed to intermolecular vibrational modes mediated by hydrogen bonds. We also measure the Raman spectra of the polycrystalline and dissolved glycine in the frequency range 28-3900 cm -1 . The results show that all the vibrational modes below 200 cm -1 are nonlocalized but are of a collective (phonon-like) nature. Furthermore, the temperature dependence of the Raman spectra of α-glycine agrees with the anharmonicity mechanism of the vibrational potentials

Investigation of reactivity change and neutron noise due to random absorber vibrations. 2

International Nuclear Information System (INIS)

Barthel, R.

1984-01-01

Perturbations of the neutron flux due to stochastically excited vibrations of absorbers have been investigated using a one-dimensional core model with N pointlike absorbers. Taking into account the flux depressions near the absorbers, pronounced peaks in the spectral power densities of the flux fluctuations have been found at multiples of the resonance frequencies in addition to the direct imaging of the resonances of absorber vibrations. Investigation of the space dependence of the corresponding transfer functions has shown that a localization is possible by means of the double frequency effect and that the dispersion of absorber vibrations can be determined by using the triple frequency effect. The conclusions of the paper are qualitatively compared with results of noise measurements at a pressurized water reactor. (author)

Evaluation of downwelling diffuse attenuation coefficient algorithms in the Red Sea

KAUST Repository

Tiwari, Surya Prakash; Yellepeddi, Sarma B.; Jones, Burton

2016-01-01

to comprehend the diffuse attenuation coefficient and its relationship with in situ properties. Two apparent optical properties, spectral remote sensing reflectance (Rrs) and the downwelling diffuse attenuation coefficient (Kd), are calculated from vertical

Linear and non-linear infrared response of one-dimensional vibrational Holstein polarons in the anti-adiabatic limit: Optical and acoustical phonon models

Science.gov (United States)

Falvo, Cyril

2018-02-01

The theory of linear and non-linear infrared response of vibrational Holstein polarons in one-dimensional lattices is presented in order to identify the spectral signatures of self-trapping phenomena. Using a canonical transformation, the optical response is computed from the small polaron point of view which is valid in the anti-adiabatic limit. Two types of phonon baths are considered: optical phonons and acoustical phonons, and simple expressions are derived for the infrared response. It is shown that for the case of optical phonons, the linear response can directly probe the polaron density of states. The model is used to interpret the experimental spectrum of crystalline acetanilide in the C=O range. For the case of acoustical phonons, it is shown that two bound states can be observed in the two-dimensional infrared spectrum at low temperature. At high temperature, analysis of the time-dependence of the two-dimensional infrared spectrum indicates that bath mediated correlations slow down spectral diffusion. The model is used to interpret the experimental linear-spectroscopy of model α-helix and β-sheet polypeptides. This work shows that the Davydov Hamiltonian cannot explain the observations in the NH stretching range.

Linking structure and vibrational mode coupling using high-resolution infrared spectroscopy: A comparison of gauche and trans 1-chloro-2-fluoroethane

Science.gov (United States)

Miller, C. Cameron; Stone, Stephen C.; Philips, Laura A.

1995-01-01

The high-resolution infrared spectrum of 1-chloro-2-fluoroethane in a molecular beam was collected over the 2975-2994 cm-1 spectral region. The spectral region of 2975-2981 cm-1 contains a symmetric C-H stretching vibrational band of the gauche conformer containing the 35Cl isotope. The spectral region of 2985-2994 cm-1 contains three vibrational bands of the trans conformer. Two of the three bands are assigned as an antisymmetric C-H stretch of each of the two different chlorine isotopes. The third band is assigned as a symmetric C-H stretch of the 35Cl isotope. The gauche conformer of 1-chloro-2-fluoroethane showed doublet patterns similar to those previously observed in 1,2-difluoroethane. The model for 1,2-difluoroethane is further refined in the present work. These refinements suggest that the coupling dark state in 1,2-difluoroethane is composed of 1 quantum C-H bend, 1 quantum C-C stretch, and 12 quanta of torsion. For 1-chloro-2-fluoroethane the dark state could not be identified due to a small data set. The trans conformer of 1-chloro-2-fluoroethane showed no evidence of mode coupling in the three vibrational bands. Including 2-fluoroethanol in this series of molecules, the extent of vibrational mode coupling did not correlate with the density of states available for coupling. Therefore, density of states alone is insufficient to explain the observed trend. A correlation was observed between the degree of intramolecular interaction and vibrational mode coupling.

A computationally efficient software application for calculating vibration from underground railways

International Nuclear Information System (INIS)

Hussein, M F M; Hunt, H E M

2009-01-01

The PiP model is a software application with a user-friendly interface for calculating vibration from underground railways. This paper reports about the software with a focus on its latest version and the plans for future developments. The software calculates the Power Spectral Density of vibration due to a moving train on floating-slab track with track irregularity described by typical values of spectra for tracks with good, average and bad conditions. The latest version accounts for a tunnel embedded in a half space by employing a toolbox developed at K.U. Leuven which calculates Green's functions for a multi-layered half-space.

Simultaneous analysis of rotational and vibrational-rotational spectra of DF and HF to obtain irreducible molecular constants for HF

International Nuclear Information System (INIS)

Horiai, Koui; Uehara, Hiromichi

2011-01-01

Graphical abstract: Available rotational and vibrational-rotational spectral lines of DF and HF are analyzed simultaneously using a non-Born-Oppenheimer effective Hamiltonian. Research highlights: → Simultaneous analysis of DF and HF spectral data. → Application of a non-Born-Oppenheimer effective Hamiltonian. → Twenty irreducible molecular constants for HF have been determined. - Abstract: Analytic expressions of corrections for the breakdown of the Born-Oppenheimer approximation to Dunham's Y ij with optimal parameters, i.e., determinable clusters of expansion coefficients, are applied to a data analysis of the rotational and vibrational-rotational transitions of HF reported in the literature. All the available spectral lines of the two isotopologues, DF and HF, are simultaneously fitted to a single set of molecular parameters of HF within experimental errors. Fitting of a data set of 595 spectral transitions for DF and HF has generated only 20 minimal independent parameter values, i.e., 'irreducible' molecular constants of HF, that are sufficient to precisely generate 82 Y ij coefficients and 144 band constants in total: 41 Y ij and 72 band constants each for DF and HF.

Vibrational properties of the Au-(√{3 }×√{3 } )/Si(111) surface reconstruction

Science.gov (United States)

Halbig, B.; Liebhaber, M.; Bass, U.; Geurts, J.; Speiser, E.; Räthel, J.; Chandola, S.; Esser, N.; Krenz, M.; Neufeld, S.; Schmidt, W. G.; Sanna, S.

2018-01-01

The vibrational properties of the Au-induced (√{3 }×√{3 })R 30∘ reconstruction of the Si(111) surface are investigated by polarized surface Raman spectroscopy and density-functional theory. The Raman measurements are performed in situ at room temperature as well as 20 K, and they reveal the presence of vibrational eigenmodes in the spectral range from 20 to 450 cm-1. In particular, two peaks of E symmetry at 75 and 183 cm-1 dominate the spectra. No substantial difference between room- and low-temperature spectra is observed, suggesting that the system does not undergo a phase transition down to 20 K. First-principles calculations are performed based on the structural models discussed in the literature. The thermodynamically stable conjugate honeycomb-chained-trimer model (CHCT) [Surf. Sci. 275, L691 (1992), 10.1016/0039-6028(92)90785-5] leads to phonon eigenvalues compatible with the experimental observations in the investigated spectral range. On the basis of the phonon eigenfrequencies, symmetries, and Raman intensities, we assign the measured spectral features to the calculated phonon modes. The good agreement between measured and calculated modes provides a strong argument in favor of the CHCT model.

A Novel Approach for Analyzing Water Diffusion in Mineral and Vegetable Oil-Paper Insulation

Directory of Open Access Journals (Sweden)

Bin Du

2014-04-01

Full Text Available Water diffusion characteristics of mineral and vegetable oil-paper insulation systems are important for insulation condition evaluation of oil-filled transformers. In this paper, we describe a novel application method of in situ attenuated total reflection Fourier transform infrared (ATR-FTIR approach for analyzing the diffusion process of water molecules in oil-immersed insulating paper. Two-dimensional correlation was used to analyze the 3700 cm-1 to 3000 cm- 1 hydroxyl peak. The observed results indicated that water molecules form two types of hydroxyl (OH with oil-impregnated paper in the diffusion process are weak and strong hydrogen bonds, respectively. 2D infrared correlation analysis revealed that three OH stretching vibration spectra absorption peaks was existed in hygroscopic vegetable oil-immersed insulating paper. And there are four OH stretching vibration spectra absorption peaks in mineral oil-immersed insulation paper. Furthermore, mineral oil-impregnated paper and vegetable oil-impregnated paper diffusion coefficients were obtained by nonlinear fitting.

N-propyl nitrate vibrational spectrum analysis using DFT B3LYP quantum-chemical method

Science.gov (United States)

Shaikhullina, R. M.; Hrapkovsky, G. M.; Shaikhullina, M. M.

2018-05-01

Calculation of a molecular structure, conformation and related vibrational spectra of the n- propyl nitrate C3H7NO3 was carried out by means of density functional theory (DFT) by employing the Gaussian 03 package. The molecular geometries were fully optimized by using the Becker's three-parameter hybrid exchange functional combined with the Lee–Yang–Parr correlation functional (B3LYP) and using the 6-31G(d) basis set. By scanning the dihedral angles around C-O and C-C bonds, five energetically most favorable conformers of n-propyl nitrate - TG, TT, GT, GG and G´G forms were found. Vibrational spectra of the most energetically favorable conformers were calculated. The comparative analysis of calculated and experimental spectra is carried out, the spectral features of the conformational state of n-propyl nitrate and the spectral effects of formation of intramolecular hydrogen bonds are established.

Acute effects of a vibration-like stimulus during knee extension exercise.

Science.gov (United States)

Mileva, Katya N; Naleem, Asif A; Biswas, Santonu K; Marwood, Simon; Bowtell, Joanna L

2006-07-01

This study was conducted to test whether a low-frequency vibration-like stimulus (rapid variable resistance) applied during a single session of knee extension exercise would alter muscle performance. Torque, knee joint angle, EMG activity of rectus femoris (RF) and vastus lateralis (VL) muscles, and VL muscle oxygenation status (near-infrared spectroscopy) were recorded during metronome-guided knee extension exercise. Nine healthy adults completed four trials exercising at contraction intensities of 35% (L) or 70% (H) of one-repetition maximum (1RM) in control (no vibration, Vb-) or vibrated condition (superimposed 10-Hz vibration-like stimulus, Vb+). Maximum voluntary contraction and 1RM were tested pre- and postexercise. During 1RM tests, muscle dynamic strength (P=0.02) and power (P=0.05) were significantly higher during vibrated rather than nonvibrated trials, and strength was significantly higher post- than preexercise (P=0.002), except during LVb- trial. Median spectral frequency of VL and RF EMG activity was significantly higher during postexercise than preexercise 1RM test in the vibration trials but unchanged in the control trials (Pvibration superimposition tended to speed muscle deoxygenation rate (P=0.065, 36% effect size) particularly during L trials. Vibration superimposition during knee extension exercise at low contraction intensity enhanced muscle performance. This effect appears to result from adaptation of neural factors such as motor unit excitability (recruitment and firing frequency, conduction velocity of excitation) in response to sensory receptor stimulation. Muscle vibration may increase the training effects derived from light-to-moderate exercise.

Enhanced vibration diagnostics using vibration signature analysis

International Nuclear Information System (INIS)

Ahmed, S.; Shehzad, K.; Zahoor, Y.; Mahmood, A.; Bibi, A.

2001-01-01

Symptoms will appear in equipment, as well as in human beings. when 'suffering from sickness. Symptoms of abnormality in equipment are vibration, noise, deformation, temperature, pressure, electric current, crack, wearing, leakage etc. these are called modes of failure. If the mode of failure is vibration then the vibration signature analysis can be effectively used in order to diagnose the machinery problems. Much valuable information is contained within these vibration 'Spectra' or 'Signatures' but is only of use if the analyst can unlock its 'Secrets'. This paper documents a vibration problem in the motor of a centrifugal pump (Type ETA). It focuses mainly on the roll of modern vibration monitoring system in problem analysis. The problem experienced was the motor unstability and noise due to high vibration. Using enhanced vibration signature data, the problem was analyzed. which suggested that the rotor eccentricity was the cause of excessive noise and vibration in the motor. In conclusion, advanced electronic monitoring and diagnostic systems provide powerful information for machine's condition assessment and problem analysis. Appropriate interpretation and use of this information is important for accurate and effective vibration analysis. (author)

A novel vibration-based fault diagnostic algorithm for gearboxes under speed fluctuations without rotational speed measurement

Science.gov (United States)

Hong, Liu; Qu, Yongzhi; Dhupia, Jaspreet Singh; Sheng, Shuangwen; Tan, Yuegang; Zhou, Zude

2017-09-01

The localized failures of gears introduce cyclic-transient impulses in the measured gearbox vibration signals. These impulses are usually identified from the sidebands around gear-mesh harmonics through the spectral analysis of cyclo-stationary signals. However, in practice, several high-powered applications of gearboxes like wind turbines are intrinsically characterized by nonstationary processes that blur the measured vibration spectra of a gearbox and deteriorate the efficacy of spectral diagnostic methods. Although order-tracking techniques have been proposed to improve the performance of spectral diagnosis for nonstationary signals measured in such applications, the required hardware for the measurement of rotational speed of these machines is often unavailable in industrial settings. Moreover, existing tacho-less order-tracking approaches are usually limited by the high time-frequency resolution requirement, which is a prerequisite for the precise estimation of the instantaneous frequency. To address such issues, a novel fault-signature enhancement algorithm is proposed that can alleviate the spectral smearing without the need of rotational speed measurement. This proposed tacho-less diagnostic technique resamples the measured acceleration signal of the gearbox based on the optimal warping path evaluated from the fast dynamic time-warping algorithm, which aligns a filtered shaft rotational harmonic signal with respect to a reference signal assuming a constant shaft rotational speed estimated from the approximation of operational speed. The effectiveness of this method is validated using both simulated signals from a fixed-axis gear pair under nonstationary conditions and experimental measurements from a 750-kW planetary wind turbine gearbox on a dynamometer test rig. The results demonstrate that the proposed algorithm can identify fault information from typical gearbox vibration measurements carried out in a resource-constrained industrial environment.

Vibration-induced electrical noise in a cryogen-free dilution refrigerator: Characterization, mitigation, and impact on qubit coherence

Energy Technology Data Exchange (ETDEWEB)

Kalra, Rachpon; Laucht, Arne; Dehollain, Juan Pablo; Bar, Daniel; Freer, Solomon; Simmons, Stephanie; Muhonen, Juha T.; Morello, Andrea, E-mail: a.morello@unsw.edu.au [Centre for Quantum Computation and Communication Technology, School of Electrical Engineering and Telecommunications, UNSW Australia, Sydney NSW 2052 (Australia)

2016-07-15

Cryogen-free low-temperature setups are becoming more prominent in experimental science due to their convenience and reliability, and concern about the increasing scarcity of helium as a natural resource. Despite not having any moving parts at the cold end, pulse tube cryocoolers introduce vibrations that can be detrimental to the experiments. We characterize the coupling of these vibrations to the electrical signal observed on cables installed in a cryogen-free dilution refrigerator. The dominant electrical noise is in the 5–10 kHz range and its magnitude is found to be strongly temperature dependent. We test the performance of different cables designed to diagnose and tackle the noise, and find triboelectrics to be the dominant mechanism coupling the vibrations to the electrical signal. Flattening a semi-rigid cable or jacketing a flexible cable in order to restrict movement within the cable, successfully reduces the noise level by over an order of magnitude. Furthermore, we characterize the effect of the pulse tube vibrations on an electron spin qubit device in this setup. Coherence measurements are used to map out the spectrum of the noise experienced by the qubit, revealing spectral components matching the spectral signature of the pulse tube.

Fourier spectral methods for fractional-in-space reaction-diffusion equations

KAUST Repository

Bueno-Orovio, Alfonso; Kay, David; Burrage, Kevin

2014-01-01

approximation of these models is demanding and imposes a number of computational constraints. In this paper, we introduce Fourier spectral methods as an attractive and easy-to-code alternative for the integration of fractional-in-space reaction

Natural bond orbital analysis, electronic structure and vibrational spectral analysis of N-(4-hydroxyl phenyl) acetamide: A density functional theory

Science.gov (United States)

Govindasamy, P.; Gunasekaran, S.; Ramkumaar, G. R.

2014-09-01

The Fourier transform infrared (FT-IR) and FT-Raman spectra of N-(4-hydroxy phenyl) acetamide (N4HPA) of painkiller agent were recorded in the region 4000-450 cm-1 and 4000-50 cm-1 respectively. Density functional theory (DFT) has been used to calculate the optimized geometrical parameter, atomic charges, and vibrational wavenumbers and intensity of the vibrational bands. The computed vibrational wave numbers were compared with the FT-IR and FT-Raman experimental data. The computational calculations at DFT/B3LYP level with 6-31G(d,p), 6-31++G(d,p), 6-311G(d,p) and 6-311++G(d,p) basis sets. The complete vibrational assignments were performed on the basis of the potential energy distribution (PED) of the vibrational modes calculated using Vibrational energy distribution analysis (VEDA 4) program. The oscillator’s strength calculated by TD-DFT and N4HPA is approach complement with the experimental findings. The NMR chemical shifts 13C and 1H were recorded and calculated using the gauge independent atomic orbital (GIAO) method. The molecular electrostatic potential (MESP) and electron density surfaces of the molecule were constructed. The Natural charges and intermolecular contacts have been interpreted using Natural Bond orbital (NBO) analysis the HOMO-LUMO energy gap has been calculated. The thermodynamic properties like entropy, heat capacity and zero vibrational energy have been calculated.

Study on diffusion behavior of nuclide in buffer material

International Nuclear Information System (INIS)

Suzuki, Satoru

2002-05-01

Bentonite is a promising candidate of buffer material for geological disposal of high-level radioactive waste (HLW). Mass transport in bentonite is mainly controlled by diffusion process because of extremely low-permeability. Geological environments, e.g. salinity of ground water and temperature can strongly influence on migration behavior in bentonite, and therefore diffusivity and diffusion mechanism have been investigated experimentally and theoretically. In chapter 1, the author summarizes how the diffusivity in the buffer material has been treated in the safety assessment. In chapter 2, results of diffusion experiments as a function of salinity and temperature have been shown. In chapter 3, relationship between diffusivity and pore structure of bentonite has been investigated theoretically. In chapter 4, sorption structure of strontium on smectite has been studied by using molecular dynamics simulation. In chapter 5, vibrational property of pore water has been investigated. Diffusivity in bentonite has been discussed based on rock capacity factor, microstructure and interaction between diffusant and bentonite. (author)

Synthesis, XRD single crystal structure analysis, vibrational spectral analysis, molecular dynamics and molecular docking studies of 2-(3-methoxy-4-hydroxyphenyl) benzothiazole

Science.gov (United States)

Sarau Devi, A.; Aswathy, V. V.; Sheena Mary, Y.; Yohannan Panicker, C.; Armaković, Stevan; Armaković, Sanja J.; Ravindran, Reena; Van Alsenoy, C.

2017-11-01

The vibrational spectra and corresponding vibrational assignments of 2-(3-methoxy-4-hydroxyphenyl)benzothiazole is reported. Single crystal XRD data of the title compound is reported and the orientation of methoxy group is cis to nitrogen atom of the thiazole ring. The phenyl ring breathing modes of the title compound are assigned at 1042 and 731 cm-1 theoretically. The charge transfer within the molecule is studied using frontier molecular orbital analysis. The chemical reactivity descriptors are calculated theoretically. The NMR spectral data predicted theoretically are in good agreement with the experimental data. The strong negative region spread over the phenyl rings, nitrogen atom and oxygen atom of the hydroxyl group in the MEP plot is due to the immense conjugative and hyper conjugative resonance charge delocalization of π-electrons. Molecule sites prone to electrophilic attacks have been determined by analysis of ALIE surfaces, while Fukui functions provided further insight into the local reactivity properties of title molecule. Autoxidation properties have been investigated by calculation of bond dissociation energies (BDEs) of hydrogen abstraction, while BDEs of the rest of the single acyclic bonds were valuable for the further investigation of degradation properties. Calculation of radial distribution functions was performed in order to determine which atoms of the title molecule have pronounced interactions with water molecules. The title compound forms a stable complex with aryl hydrocarbon receptor and can be a lead compound for developing new anti-tumor drug. Antimicrobial properties of the title compound was screened against one bacterial culture Escherchia coli and four fungal cultures viz., Aspergillus niger, Pencillum chrysogenum, Saccharomyces cerevisiae and Rhyzopus stolonifer.

Numerical investigation on vibration and noise induced by unsteady flow in an axial-flow pump

Energy Technology Data Exchange (ETDEWEB)

Chen, Eryun; Ma, Zui Ling; Yang, Ai Ling; Nan, Guo Fang [School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai (China); Zhao, Gai Ping [School of Medical Instruments and Food Engineering, University of Shanghai for Science and Technology, Shanghai (China); Li, Guo Ping [Shanghai Marine Equipment Research Institute, Shanghai (China)

2016-12-15

Full-scale structural vibration and noise induced by flow in an axial-flow pump was simulated by a hybrid numerical method. An unsteady flow field was solved by a large eddy simulation-based computational fluid dynamics commercial code, Fluent. An experimental validation on pressure fluctuations was performed to impose an appropriate vibration exciting source. The consistency between the computed results and experimental tests were interesting. The modes of the axial-flow pump were computed by the finite element method. After that, the pump vibration and sound field were solved using a coupled vibro-acoustic model. The numerical results indicated that the the blade-passing frequency was the dominant frequency of the vibration acceleration of the pump. This result was consistent with frequency spectral characteristics of unsteady pressure fluctuation. Finally, comparisons of the vibration acceleration between the computed results and the experimental test were conducted. These comparisons validated the computed results. This study shows that using the hybrid numerical method to evaluate the flow-induced vibration and noise generated in an axial-flow pump is feasible.

Exciton–vibrational coupling in the dynamics and spectroscopy of Frenkel excitons in molecular aggregates

International Nuclear Information System (INIS)

Schröter, M.; Ivanov, S.D.; Schulze, J.; Polyutov, S.P.; Yan, Y.; Pullerits, T.; Kühn, O.

2015-01-01

The influence of exciton–vibrational coupling on the optical and transport properties of molecular aggregates is an old problem that gained renewed interest in recent years. On the experimental side, various nonlinear spectroscopic techniques gave insight into the dynamics of systems as complex as photosynthetic antennae. Striking evidence was gathered that in these protein–pigment complexes quantum coherence is operative even at room temperature conditions. Investigations were triggered to understand the role of vibrational degrees of freedom, beyond that of a heat bath characterized by thermal fluctuations. This development was paralleled by theory, where efficient methods emerged, which could provide the proper frame to perform non-Markovian and non-perturbative simulations of exciton–vibrational dynamics and spectroscopy. This review summarizes the state of affairs of the theory of exciton–vibrational interaction in molecular aggregates and photosynthetic antenna complexes. The focus is put on the discussion of basic effects of exciton–vibrational interaction from the stationary and dynamics points of view. Here, the molecular dimer plays a prominent role as it permits a systematic investigation of absorption and emission spectra by numerical diagonalization of the exciton–vibrational Hamiltonian in a truncated Hilbert space. An extension to larger aggregates, having many coupled nuclear degrees of freedom, becomes possible with the Multi-Layer Multi-Configuration Time-Dependent Hartree (ML-MCTDH) method for wave packet propagation. In fact it will be shown that this method allows one to approach the limit of almost continuous spectral densities, which is usually the realm of density matrix theory. Real system–bath situations are introduced for two models, which differ in the way strongly coupled nuclear coordinates are treated, as a part of the relevant system or the bath. A rather detailed exposition of the Hierarchy Equations Of Motion (HEOM

Vibrational frequencies and dephasing times in excited electronic states by femtosecond time-resolved four-wave mixing

Science.gov (United States)

Joo, Taiha; Albrecht, A. C.

1993-06-01

Time-resolved degenerate four-wave mixing (TRDFWM) for an electronically resonant system in a phase-matching configuration that measures population decay is reported. Because the spectral width of input light exceeds the vibrational Bohr frequency of a strong Raman active mode, the vibrational coherence produces strong oscillations in the TRDFWM signal together with the usual population decay from the excited electronic state. The data are analyzed in terms of a four-level system: ground and excited electronic states each split by a vibrational quantum of a Raman active mode. Absolute frequencies and their dephasing times of the vibrational modes at ≈590 cm -1 are obtained for the excited as well as the ground electronic state. The vibrational dephasing rate in the excited electronic state is about an order of magnitude faster than that in the ground state, the origin of which is speculated upon.

Spectral diffusion and electron-phonon coupling of the B800 BChl a molecules in LH2 complexes from three different species of purple bacteria.

Science.gov (United States)

Baier, J; Gabrielsen, M; Oellerich, S; Michel, H; van Heel, M; Cogdell, R J; Köhler, J

2009-11-04

We have investigated the spectral diffusion and the electron-phonon coupling of B800 bacteriochlorophyll a molecules in the peripheral light-harvesting complex LH2 for three different species of purple bacteria, Rhodobacter sphaeroides, Rhodospirillum molischianum, and Rhodopseudomonas acidophila. We come to the conclusion that B800 binding pockets for Rhodobacter sphaeroides and Rhodopseudomonas acidophila are rather similar with respect to the polarity of the protein environment but that the packaging of the alphabeta-polypeptides seems to be less tight in Rb. sphaeroides with respect to the other two species.

Spectral tunneling of lattice nonlocal solitons

International Nuclear Information System (INIS)

Kartashov, Yaroslav V.; Torner, Lluis; Vysloukh, Victor A.

2010-01-01

We address spectral tunneling of walking spatial solitons in photorefractive media with nonlocal diffusion component of the nonlinear response and an imprinted shallow optical lattice. In contrast to materials with local nonlinearities, where solitons traveling across the lattice close to the Bragg angle suffer large radiative losses, in photorefractive media with diffusion nonlinearity resulting in self-bending, solitons survive when their propagation angle approaches and even exceeds the Bragg angle. In the spatial frequency domain this effect can be considered as tunneling through the band of spatial frequencies centered around the Bragg frequency where the spatial group velocity dispersion is positive.

Applications of the semiclassical spectral method to nuclear, atomic, molecular, and polymeric dynamics

International Nuclear Information System (INIS)

Koszykowski, M.L.; Pfeffer, G.A.; Noid, D.W.

1987-01-01

Nonlinear dynamics plays a dominant role in a variety of important problems in chemical physics. Examples are unimolecular reactions, infrared multiphoton decomposition of molecules, the pumping process of the gamma ray laser, dissociation of vibrationally excited state-selected van der Waals's complexes, and many other chemical and atomic processes. The present article discusses recent theoretical studies on the quasi-periodic and chaotic dynamic aspects of vibrational-rotational states of atomic, nuclear, and molecular systems using the semiclassical spectral method (SSM). The authors note that the coordinates, momenta, and so on, are found using classical mechanics in the studies included in this review. They outline the semiclassical spectral method and a wide variety of applications. Although this technique was first developed ten years ago, it has proved to be tremendously successful as a tool used in dynamics problems. Applications include problems in nonlinear dynamics, molecular and atomic spectra, surface science, astronomy and stellar dynamics, nuclear physics, and polymer physics

Nitric oxide kinetics in the afterglow of a diffuse plasma filament

Science.gov (United States)

Burnette, D.; Montello, A.; Adamovich, I. V.; Lempert, W. R.

2014-08-01

A suite of laser diagnostics is used to study kinetics of vibrational energy transfer and plasma chemical reactions in a nanosecond pulse, diffuse filament electric discharge and afterglow in N2 and dry air at 100 Torr. Laser-induced fluorescence of NO and two-photon absorption laser-induced fluorescence of O and N atoms are used to measure absolute, time-resolved number densities of these species after the discharge pulse, and picosecond coherent anti-Stokes Raman spectroscopy is used to measure time-resolved rotational temperature and ground electronic state N2(v = 0-4) vibrational level populations. The plasma filament diameter, determined from plasma emission and NO planar laser-induced fluorescence images, remains nearly constant after the discharge pulse, over a few hundred microseconds, and does not exhibit expansion on microsecond time scale. Peak temperature in the discharge and the afterglow is low, T ≈ 370 K, in spite of significant vibrational nonequilibrium, with peak N2 vibrational temperature of Tv ≈ 2000 K. Significant vibrational temperature rise in the afterglow is likely caused by the downward N2-N2 vibration-vibration (V-V) energy transfer. Simple kinetic modeling of time-resolved N, O, and NO number densities in the afterglow, on the time scale longer compared to relaxation and quenching time of excited species generated in the plasma, is in good agreement with the data. In nitrogen, the N atom density after the discharge pulse is controlled by three-body recombination and radial diffusion. In air, N, NO and O concentrations are dominated by the reverse Zel'dovich reaction, N + NO → N2 + O, and ozone formation reaction, O + O2 + M → O3 + M, respectively. The effect of vibrationally excited nitrogen molecules and excited N atoms on NO formation kinetics is estimated to be negligible. The results suggest that NO formation in the nanosecond pulse discharge is dominated by reactions of excited electronic states of nitrogen, occurring on

Analysis of solid-state transformations of pharmaceutical compounds using vibrational spectroscopy

DEFF Research Database (Denmark)

Heinz, Andrea; Strachan, Clare J; Gordon, Keith C

2009-01-01

OBJECTIVES: Solid-state transformations may occur during any stage of pharmaceutical processing and upon storage of a solid dosage form. Early detection and quantification of these transformations during the manufacture of solid dosage forms is important since the physical form of an active...... pharmaceutical ingredient can significantly influence its processing behaviour, including powder flow and compressibility, and biopharmaceutical properties such as solubility, dissolution rate and bioavailability. KEY FINDINGS: Vibrational spectroscopic techniques such as infrared, near-infrared, Raman and, most...... multivariate approaches where even overlapping spectral bands can be analysed. SUMMARY: This review discusses the applications of different vibrational spectroscopic techniques to detect and monitor solid-state transformations possible for crystalline polymorphs, hydrates and amorphous forms of pharmaceutical...

Test-Anchored Vibration Response Predictions for an Acoustically Energized Curved Orthogrid Panel with Mounted Components

Science.gov (United States)

Frady, Gregory P.; Duvall, Lowery D.; Fulcher, Clay W. G.; Laverde, Bruce T.; Hunt, Ronald A.

2011-01-01

rich body of vibroacoustic test data was recently generated at Marshall Space Flight Center for component-loaded curved orthogrid panels typical of launch vehicle skin structures. The test data were used to anchor computational predictions of a variety of spatially distributed responses including acceleration, strain and component interface force. Transfer functions relating the responses to the input pressure field were generated from finite element based modal solutions and test-derived damping estimates. A diffuse acoustic field model was applied to correlate the measured input sound pressures across the energized panel. This application quantifies the ability to quickly and accurately predict a variety of responses to acoustically energized skin panels with mounted components. Favorable comparisons between the measured and predicted responses were established. The validated models were used to examine vibration response sensitivities to relevant modeling parameters such as pressure patch density, mesh density, weight of the mounted component and model form. Convergence metrics include spectral densities and cumulative root-mean squared (RMS) functions for acceleration, velocity, displacement, strain and interface force. Minimum frequencies for response convergence were established as well as recommendations for modeling techniques, particularly in the early stages of a component design when accurate structural vibration requirements are needed relatively quickly. The results were compared with long-established guidelines for modeling accuracy of component-loaded panels. A theoretical basis for the Response/Pressure Transfer Function (RPTF) approach provides insight into trends observed in the response predictions and confirmed in the test data. The software developed for the RPTF method allows easy replacement of the diffuse acoustic field with other pressure fields such as a turbulent boundary layer (TBL) model suitable for vehicle ascent. Structural responses

Diffusion in multicomponent systems: a free energy approach

International Nuclear Information System (INIS)

Emmanuel, Simon; Cortis, Andrea; Berkowitz, Brian

2004-01-01

This work examines diffusion in ternary non-ideal systems and derives coupled non-linear equations based on a non-equilibrium thermodynamic approach in which an explicit expression for the free energy is substituted into standard diffusion equations. For ideal solutions, the equations employ four mobility parameters (M aa , M ab , M ba , and M bb ), and uphill diffusion is predicted for certain initial conditions and combinations of mobilities. For the more complex case of ternary Simple Mixtures, two non-ideality parameters (χ ac and χ bc ) that are directly related to the excess free energy of mixing are introduced. The solution of the equations is carried out by means of two different numerical schemes: (1) spectral collocation and (2) finite element. An error minimization technique is coupled with the spectral collocation method and applied to diffusional profiles to extract the M and χ parameters. The model satisfactorily reproduces diffusional profiles from published data for silicate melts. Further improvements in numerical and experimental techniques are then suggested

Dissipation enhanced vibrational sensing in an olfactory molecular switch

International Nuclear Information System (INIS)

Chęcińska, Agata; Heaney, Libby; Pollock, Felix A.; Nazir, Ahsan

2015-01-01

Motivated by a proposed olfactory mechanism based on a vibrationally activated molecular switch, we study electron transport within a donor-acceptor pair that is coupled to a vibrational mode and embedded in a surrounding environment. We derive a polaron master equation with which we study the dynamics of both the electronic and vibrational degrees of freedom beyond previously employed semiclassical (Marcus-Jortner) rate analyses. We show (i) that in the absence of explicit dissipation of the vibrational mode, the semiclassical approach is generally unable to capture the dynamics predicted by our master equation due to both its assumption of one-way (exponential) electron transfer from donor to acceptor and its neglect of the spectral details of the environment; (ii) that by additionally allowing strong dissipation to act on the odorant vibrational mode, we can recover exponential electron transfer, though typically at a rate that differs from that given by the Marcus-Jortner expression; (iii) that the ability of the molecular switch to discriminate between the presence and absence of the odorant, and its sensitivity to the odorant vibrational frequency, is enhanced significantly in this strong dissipation regime, when compared to the case without mode dissipation; and (iv) that details of the environment absent from previous Marcus-Jortner analyses can also dramatically alter the sensitivity of the molecular switch, in particular, allowing its frequency resolution to be improved. Our results thus demonstrate the constructive role dissipation can play in facilitating sensitive and selective operation in molecular switch devices, as well as the inadequacy of semiclassical rate equations in analysing such behaviour over a wide range of parameters

Characterizing interstate vibrational coherent dynamics of surface adsorbed catalysts by fourth-order 3D SFG spectroscopy

Science.gov (United States)

Li, Yingmin; Wang, Jiaxi; Clark, Melissa L.; Kubiak, Clifford P.; Xiong, Wei

2016-04-01

We report the first fourth-order 3D SFG spectroscopy of a monolayer of the catalyst Re(diCN-bpy)(CO)3Cl on a gold surface. Besides measuring the vibrational coherences of single vibrational modes, the fourth-order 3D SFG spectrum also measures the dynamics of interstate coherences and vibrational coherences states between two vibrational modes. By comparing the 3D SFG to the corresponding 2D and third-order 3D IR spectroscopy of the same molecules in solution, we found that the interstate coherences exist in both liquid and surface systems, suggesting that the interstate coherence is not disrupted by surface interactions. However, by analyzing the 3D spectral lineshape, we found that the interstate coherences also experience non-negligible homogenous dephasing dynamics that originate from surface interactions. This unique ability of determining interstate vibrational coherence dynamics of the molecular monolayer can help in understanding of how energy flows within surface catalysts and other molecular monolayers.

Vibration analysis of cooling system of upgraded PARR-1: (primary pumps)

International Nuclear Information System (INIS)

Ayazuddin, S.K.; Baig, R.; Pervez, S.

1992-12-01

During the conversion and up gradation of PARR-1, major changes were made in the cooling system of the reactor with the addition of new heat exchanger assemblies and cooling tower. It was therefore, planned to perform vibration analysis on the cooling system to check proper installation and investigate any abnormality in the operation. As a first step, vibration measurements was made on the primary pumps PW-P1 and PW-P2. Power spectral density (PSD) or frequency spectrum of the signal produced from an accelerometer placed on the pump motor assembly was analysed to identify faults which are commonly found in rotating and reciprocating machinery such as unbalance, shaft misalignment and bearing instability. The root mean square (RMS) of the signal was compared with the vibration criterion chart to determine the operating condition of the pump motor assembly. The procedure used for the analysis and faults detected in the primary pump-motor system are discussed. 9 figs. (author)

Spectral Analysis and Computation of Effective Diffusivities in Space-time Periodic Incompressible Flows

Science.gov (United States)

2015-11-01

diffusive tracer fluxes, directed normal to the tracer gradient [64], are generally equivalent to antisymmetric components in the effective diffusivity...tensor D∗, while the symmetric part of D∗ represents irreversible diffusive effects [83, 87, 39] directed down the tracer gradient . The mixing of eddy...provides an operational calculus in Hilbert space which yields powerful integral representations involving the Stieltjes measures displayed in equation

Vibrational study and Natural Bond Orbital analysis of serotonin in monomer and dimer states by density functional theory

Science.gov (United States)

Borah, Mukunda Madhab; Devi, Th. Gomti

2018-06-01

The vibrational spectral analysis of Serotonin and its dimer were carried out using the Fourier Transform Infrared (FTIR) and Raman techniques. The equilibrium geometrical parameters, harmonic vibrational wavenumbers, Frontier orbitals, Mulliken atomic charges, Natural Bond orbitals, first order hyperpolarizability and some optimized energy parameters were computed by density functional theory with 6-31G(d,p) basis set. The detailed analysis of the vibrational spectra have been carried out by computing Potential Energy Distribution (PED, %) with the help of Vibrational Energy Distribution Analysis (VEDA) program. The second order delocalization energies E(2) confirms the occurrence of intramolecular Charge Transfer (ICT) within the molecule. The computed wavenumbers of Serotonin monomer and dimer were found in good agreement with the experimental Raman and IR values.

Spectral Analysis and Computation of Effective Diffusivities for Steady Random Flows

Science.gov (United States)

2016-04-28

even in the motion of sea ice floes influenced by winds and ocean currents. The long time, large scale behavior of such systems is equivalent to an...flow plays a key role in many important processes in the global climate system [55] and Earth’s ecosys- tems [14]. Advection of geophysical fluids...HOMOGENIZATION OF THE ADVECTION-DIFFUSION EQUATION The dispersion of a cloud of passive scalars with density φ diffusing with molecular dif- fusivity ε and

A new method of organizing spectral line intensity ratio fluctuations of nightglow emissions

International Nuclear Information System (INIS)

Thelin, B.

1986-02-01

In this paper a new kind of linearization effect between the atmospheric night airglow emissions is presented. The same kind of linearization effect has previously been studied with spectrochemical light sources together with a spectrometer. A linear graph was obtained for atomic spectral lines and vibrational bandspectra when the spectral line intensity ratio fluctuations were plotted versus the photon energies of these emissions. To study this effect data from a number of different photometer investigations of night airglow emissions at different times and places have been used. (author)

Experimental research on pressure fluctuation and vibration in a mixed flow pump

Energy Technology Data Exchange (ETDEWEB)

Wang, Kai; Liu, Houlin; Wang, Wenbo [National Research Center of Pumps and Pumping System Engineering and Technology, Jiangsu University, Zhenjiang (China); Zhou, Xiaohua [Gree Electric Appliance Inc. of Zhuhai, Zhuhai (China)

2016-01-15

To study the pressure fluctuation and vibration in mixed flow pumps, we chose a mixed flow pump with specific speed of 436.1 to measure. The time domains and frequency domain at each monitoring point on diffuser and outlet elbow were analyzed, as well as the vibration frequency domain characteristics at the impeller outlet and near the motor. The results show that the peak value of pressure fluctuation peak decreased gradually with the increase of flow rate. The pressure fluctuation of each monitoring point had periodicity, and the frequency domain dominated by blade passing frequency and multiple shaft frequency. The vibration frequency of each monitoring point occurred at shaft frequency and its multiple shaft frequency. The dominant frequency and the second frequency were distributed in shaft frequency and double shaft frequency.

Wavelet and Spectral Analysis of Some Selected Problems in Reactor Diagnostics

Energy Technology Data Exchange (ETDEWEB)

Sunde, Carl

2004-12-01

Both spectral and wavelet analysis were successfully used in various diagnostic problems involving non-stationary core processes in nuclear power reactors. Three different problems were treated: two-phase flow identification, detector tube impacting and core-barrel vibrations. The first two problems are of non-stationary nature, whereas the last one is not. In the first problem, neutron radiographic and visible light images of four different vertical two-phase flow regimes, bubbly, slug, chum and annular flow, were analysed and classified with a neuro-wavelet algorithm. The algorithm consists of a wavelet part, using the 2-D discrete wavelet transform and of an artificial neural network. It classifies the different flow regimes with up to 99% efficiency. Detector tubes in a Boiling Water Reactor may execute vibrations and may also impact on nearby fuel-assemblies. Signals from in-core neutron detectors in Ringhals-1 were analysed, for detection of impacting, with both a classical spectral method and wavelet-based methods. The wavelet methods include both the discrete and the continuous 1-D wavelet transform. It was found that there is agreement between the different methods as well as with visual inspections made during the outage at the plant. However, the wavelet technique has the advantage that it does not require expert judgement for the interpretation of the analysis. In the last part two analytical calculations of the neutron noise, induced by shell-mode core-barrel vibrations, were carried out. The results are in good agreement with calculations from a numerical simulator. An out-of-phase behaviour between in-core and ex-core positions was found, which is in agreement with earlier measurements from the Pressurised Water Reactor Ringhals-3. The results from these calculations are planned to be used when diagnosing the shell-mode core-barrel vibrations in an operating plant.

Wavelet and Spectral Analysis of Some Selected Problems in Reactor Diagnostics

International Nuclear Information System (INIS)

Sunde, Carl

2004-12-01

Both spectral and wavelet analysis were successfully used in various diagnostic problems involving non-stationary core processes in nuclear power reactors. Three different problems were treated: two-phase flow identification, detector tube impacting and core-barrel vibrations. The first two problems are of non-stationary nature, whereas the last one is not. In the first problem, neutron radiographic and visible light images of four different vertical two-phase flow regimes, bubbly, slug, chum and annular flow, were analysed and classified with a neuro-wavelet algorithm. The algorithm consists of a wavelet part, using the 2-D discrete wavelet transform and of an artificial neural network. It classifies the different flow regimes with up to 99% efficiency. Detector tubes in a Boiling Water Reactor may execute vibrations and may also impact on nearby fuel-assemblies. Signals from in-core neutron detectors in Ringhals-1 were analysed, for detection of impacting, with both a classical spectral method and wavelet-based methods. The wavelet methods include both the discrete and the continuous 1-D wavelet transform. It was found that there is agreement between the different methods as well as with visual inspections made during the outage at the plant. However, the wavelet technique has the advantage that it does not require expert judgement for the interpretation of the analysis. In the last part two analytical calculations of the neutron noise, induced by shell-mode core-barrel vibrations, were carried out. The results are in good agreement with calculations from a numerical simulator. An out-of-phase behaviour between in-core and ex-core positions was found, which is in agreement with earlier measurements from the Pressurised Water Reactor Ringhals-3. The results from these calculations are planned to be used when diagnosing the shell-mode core-barrel vibrations in an operating plant

High-speed Vibrational Imaging and Spectral Analysis of Lipid Bodies by Compound Raman Microscopy

OpenAIRE

Slipchenko, Mikhail N.; Le, Thuc T.; Chen, Hongtao; Cheng, Ji-Xin

2009-01-01

Cells store excess energy in the form of cytoplasmic lipid droplets. At present, it is unclear how different types of fatty acids contribute to the formation of lipid-droplets. We describe a compound Raman microscope capable of both high-speed chemical imaging and quantitative spectral analysis on the same platform. We use a picosecond laser source to perform coherent Raman scattering imaging of a biological sample and confocal Raman spectral analysis at points of interest. The potential of t...

Capturing inhomogeneous broadening of the -CN stretch vibration in a Langmuir monolayer with high-resolution spectra and ultrafast vibrational dynamics in sum-frequency generation vibrational spectroscopy (SFG-VS)

Science.gov (United States)

Velarde, Luis; Wang, Hong-fei

2013-08-01

While in principle the frequency-domain and time-domain spectroscopic measurements should generate identical information for a given molecular system, the inhomogeneous character of surface vibrations in sum-frequency generation vibrational spectroscopy (SFG-VS) studies has only been studied with time-domain SFG-VS by mapping the decay of the vibrational polarization using ultrafast lasers, this due to the lack of SFG vibrational spectra with high enough spectral resolution and accurate enough lineshape. Here, with the recently developed high-resolution broadband SFG-VS (HR-BB-SFG-VS) technique, we show that the inhomogeneous lineshape can be obtained in the frequency-domain for the anchoring CN stretch of the 4-n-octyl-4'-cyanobiphenyl (8CB) Langmuir monolayer at the air-water interface, and that an excellent agreement with the time-domain SFG free-induction-decay can be established. We found that the 8CB CN stretch spectrum consists of a single peak centered at 2234.00 ± 0.01 cm-1 with a total linewidth of 10.9 ± 0.3 cm-1 at half maximum. The Lorentzian contribution accounts only for 4.7 ± 0.4 cm-1 to this width and the Gaussian (inhomogeneous) broadening for as much as 8.1 ± 0.2 cm-1. Polarization analysis of the -CN spectra showed that the -CN group is tilted 57° ± 2° from the surface normal. The large heterogeneity in the -CN spectrum is tentatively attributed to the -CN group interactions with the interfacial water molecules penetrated/accommodated into the 8CB monolayer, a unique phenomenon for the nCB Langmuir monolayers reported previously.

Simultaneous spectral and temporal analyses of kinetic energies in nonequilibrium systems: theory and application to vibrational relaxation of O-D stretch mode of HOD in water.

Science.gov (United States)

Jeon, Jonggu; Lim, Joon Hyung; Kim, Seongheun; Kim, Heejae; Cho, Minhaeng

2015-05-28

A time series of kinetic energies (KE) from classical molecular dynamics (MD) simulation contains fundamental information on system dynamics. It can also be analyzed in the frequency domain through Fourier transformation (FT) of velocity correlation functions, providing energy content of different spectral regions. By limiting the FT time span, we have previously shown that spectral resolution of KE evolution is possible in the nonequilibrium situations [Jeon and Cho, J. Chem. Phys. 2011, 135, 214504]. In this paper, we refine the method by employing the concept of instantaneous power spectra, extending it to reflect an instantaneous time-correlation of velocities with those in the future as well as with those in the past, and present a new method to obtain the instantaneous spectral density of KE (iKESD). This approach enables the simultaneous spectral and temporal resolution of KE with unlimited time precision. We discuss the formal and novel properties of the new iKESD approaches and how to optimize computational methods and determine parameters for practical applications. The method is specifically applied to the nonequilibrium MD simulation of vibrational relaxation of the OD stretch mode in a hydrated HOD molecule by employing a hybrid quantum mechanical/molecular mechanical (QM/MM) potential. We directly compare the computational results with the OD band population relaxation time profiles extracted from the IR pump-probe measurements for 5% HOD in water. The calculated iKESD yields the OD bond relaxation time scale ∼30% larger than the experimental value, and this decay is largely frequency-independent if the classical anharmonicity is accounted for. From the integrated iKESD over intra- and intermolecular bands, the major energy transfer pathways were found to involve the HOD bending mode in the subps range, then the internal modes of the solvent until 5 ps after excitation, and eventually the solvent intermolecular modes. Also, strong hydrogen

Detection of plum pox virus infection in selection plum trees using spectral imaging

Science.gov (United States)

Angelova, Liliya; Stoev, Antoniy; Borisova, Ekaterina; Avramov, Latchezar

2016-01-01

Plum pox virus (PPV) is among the most studied viral diseases in the world in plants. It is considered to be one of the most devastating diseases of stone fruits in terms of agronomic impact and economic importance. Noninvasive, fast and reliable techniques are required for evaluation of the pathology in selection trees with economic impact. Such advanced tools for PPV detection could be optical techniques as light-induced fluorescence and diffuse reflectance spectroscopies. Specific regions in the electromagnetic spectra have been found to provide information about the physiological stress in plants, and consequently, diseased plants usually exhibit different spectral signature than non-stressed healthy plants in those specific ranges. In this study spectral reflectance and chlorophyll fluorescence were used for the identification of biotic stress caused by the pox virus on plum trees. The spectral responses of healthy and infected leaves from cultivars, which are widespread in Bulgaria were investigated. The two applied techniques revealed statistically significant differences between the spectral data of healthy plum leaves and those infected by PPV in the visible and near-infrared spectral ranges. Their application for biotic stress detection helps in monitoring diseases in plants using the different plant spectral properties in these spectral ranges. The strong relationship between the results indicates the applicability of diffuse reflectance and fluorescence techniques for conducting health condition assessments of vegetation and their importance for plant protection practices.

Analysis of two-phase flow induced vibrations in perpendiculary supported U-type piping systems

International Nuclear Information System (INIS)

Hiramatsu, Tsutomu; Komura, Yoshiaki; Ito, Atsushi.

1984-01-01

The perpose of this analysis is to predict the vibration level of a pipe conveying a two-phase flowing fluid. Experiments were carried out with a perpendiculary supported U-type piping system, conveying an air-water two-phase flow in a steady state condition. Fluctuation signals are observed by a void signal sensor, and power spectral densities and probability density functions are obtained from the void signals. Theoretical studies using FEM and an estimation of the exciting forces from the PSD of void signals, provided a good predictional estimation of vibration responses of the piping system. (author)

The effects of vibration-reducing gloves on finger vibration

Science.gov (United States)

Welcome, Daniel E.; Dong, Ren G.; Xu, Xueyan S.; Warren, Christopher; McDowell, Thomas W.

2015-01-01

Vibration-reducing (VR) gloves have been used to reduce the hand-transmitted vibration exposures from machines and powered hand tools but their effectiveness remains unclear, especially for finger protection. The objectives of this study are to determine whether VR gloves can attenuate the vibration transmitted to the fingers and to enhance the understanding of the mechanisms of how these gloves work. Seven adult male subjects participated in the experiment. The fixed factors evaluated include hand force (four levels), glove condition (gel-filled, air bladder, no gloves), and location of the finger vibration measurement. A 3-D laser vibrometer was used to measure the vibrations on the fingers with and without wearing a glove on a 3-D hand-arm vibration test system. This study finds that the effect of VR gloves on the finger vibration depends on not only the gloves but also their influence on the distribution of the finger contact stiffness and the grip effort. As a result, the gloves increase the vibration in the fingertip area but marginally reduce the vibration in the proximal area at some frequencies below 100 Hz. On average, the gloves reduce the vibration of the entire fingers by less than 3% at frequencies below 80 Hz but increase at frequencies from 80 to 400 Hz. At higher frequencies, the gel-filled glove is more effective at reducing the finger vibration than the air bladder-filled glove. The implications of these findings are discussed. Relevance to industry Prolonged, intensive exposure to hand-transmitted vibration can cause hand-arm vibration syndrome. Vibration-reducing gloves have been used as an alternative approach to reduce the vibration exposure. However, their effectiveness for reducing finger-transmitted vibrations remains unclear. This study enhanced the understanding of the glove effects on finger vibration and provided useful information on the effectiveness of typical VR gloves at reducing the vibration transmitted to the fingers. The new

On self-diffusion in silicon and germanium

International Nuclear Information System (INIS)

Bourgoin, J.C.; Lannoo, M.

1980-01-01

The experimental results concerning self-diffusion in Si and Ge are discussed. It is noted, using recent direct experimental data, that there is no temperature variation of the activation energy for self-diffusion, as it was postulated by Seeger and coworkers. A calculation is made of the sum of the formation and migration vibrational entropies for a vacancy, versus the lattice distortion which occurs around this vacancy. Using a Morse potential to obtain force constants, a lower limit is obtained for the value of this entropy at high temperature which is in correct agreement with the large (10 to 15 k) experimental value. It is concluded that the model, proposed by Seeger and coworkers, that self-diffusion occurs through extended defects (vacancies or interstitials), can be definitively ruled out. (author)

Modern diagnostic systems for loose parts, vibration and leakage monitoring

International Nuclear Information System (INIS)

Kunze, U.

1997-01-01

The modern diagnostic systems for loose parts, vibration and leakage monitoring of Siemens marked improvements in signal detection, ease of operation, and the display of information. The paper gives an overview on: Loose parts monitoring system KUeS '95 - a computer-based system. The knowledge and experience about loose parts detection incorporated into this system can be characterized as ''intelligence''. Vibration monitoring system SUeS '95 - a fully automated system for early detection of changes in the vibration patterns of the reactor coolant system components and reactor pressure vessel internals. Leak detection system FLUeS - a system that detects even small leaks in steam-carrying components and very accurately determines their location. Leaks are detected on the moisture distribution in a sample air column into which the escaping steam locally diffuses. All systems described represent the latest state of technology. Nevertheless a considerable amount of operational experience can be reported. (author). 5 refs, 10 figs

Quantum chemical studies on structural, vibrational, nonlinear optical properties and chemical reactivity of indigo carmine dye

Science.gov (United States)

El-Mansy, M. A. M.

2017-08-01

Structural and vibrational spectroscopic studies were performed on indigo carmine (IC) isomers using FT-IR spectral analysis along with DFT/B3LYP method utilizing Gaussian 09 software. GaussView 5 program has been employed to perform a detailed interpretation of vibrational spectra. Simulation of infrared spectra has led to an excellent overall agreement with the observed spectral patterns. Mulliken population analyses on atomic charges, MEP, HOMO-LUMO, NLO, first order hyperpolarizability and thermodynamic properties have been examined by (DFT/B3LYP) method with the SDD basis set level. Density of state spectra (DOS) were calculated using GaussSum 3 at the same level of theory. Molecular modeling approved that DOS Spectra are the most significant tools for differentiating between two IC isomers so far. Moreover, The IC isomers (cis-isomer) have shown an extended applicability for manufacturing both NLO and photovoltaic devices such as solar cells.

Non-invasive vibrational SFG spectroscopy reveals that bacterial adhesion can alter the conformation of grafted "brush" chains on SAM.

Science.gov (United States)

Bulard, Emilie; Guo, Ziang; Zheng, Wanquan; Dubost, Henri; Fontaine-Aupart, Marie-Pierre; Bellon-Fontaine, Marie-Noëlle; Herry, Jean-Marie; Briandet, Romain; Bourguignon, Bernard

2011-04-19

Understanding bacterial adhesion on a surface is a crucial step to design new materials with improved properties or to control biofilm formation and eradication. Sum Frequency Generation (SFG) vibrational spectroscopy has been employed to study in situ the conformational response of a self-assembled monolayer (SAM) of octadecanethiol (ODT) on a gold film to the adhesion of hydrophilic and hydrophobic ovococcoid model bacteria. The present work highlights vibrational SFG spectroscopy as a powerful and unique non-invasive biophysical technique to probe and control bacteria interaction with ordered surfaces. Indeed, the SFG vibrational spectral changes reveal different ODT SAM conformations in air and upon exposure to aqueous solution or bacterial adhesion. Furthermore, this effect depends on the bacterial cell surface properties. The SFG spectral modeling demonstrates that hydrophobic bacteria flatten the ODT SAM alkyl chain terminal part, whereas the hydrophilic ones raise this ODT SAM terminal part. Microorganism-induced alteration of grafted chains can thus affect the desired interfacial functionality, a result that should be considered for the design of new reactive materials. © 2011 American Chemical Society

Spectral response of a polycrystalline silicon solar cell

International Nuclear Information System (INIS)

Ba, B.; Kane, M.

1994-10-01

A theoretical study of the spectral response of a polycrystalline silicon n-p junction solar cell is presented. The case of a fibrously oriented grain structure, involving grain boundary recombination velocity and grain size effects is discussed. The contribution of the base region on the internal quantum efficiency Q int is computed for different grain sizes and grain boundary recombination velocities in order to examine their influence. Suggestions are also made for the determination of base diffusion length in polycrystalline silicon solar cells using the spectral response method. (author). 15 refs, 4 figs

From dispersion relations to spectral dimension - and back again

International Nuclear Information System (INIS)

Sotiriou, Thomas P.; Visser, Matt; Weinfurtner, Silke

2011-01-01

The so-called spectral dimension is a scale-dependent number associated with both geometries and field theories that has recently attracted much attention, driven largely, though not exclusively, by investigations of causal dynamical triangulations and Horava gravity as possible candidates for quantum gravity. We advocate the use of the spectral dimension as a probe for the kinematics of these (and other) systems in the region where spacetime curvature is small, and the manifold is flat to a good approximation. In particular, we show how to assign a spectral dimension (as a function of so-called diffusion time) to any arbitrarily specified dispersion relation. We also analyze the fundamental properties of spectral dimension using extensions of the usual Seeley-DeWitt and Feynman expansions and by using saddle point techniques. The spectral dimension turns out to be a useful, robust, and powerful probe, not only of geometry, but also of kinematics.

Effectiveness of a consistently formulated diffusion-synthetic acceleration differencing approach

International Nuclear Information System (INIS)

Khalil, H.

1988-01-01

A consistently formulated differencing approach is applied to the diffusion-synthetic acceleration of discrete ordinates calculations based on various spatial differencing schemes. The diffusion ''coupling'' equations derived for each scheme are contrasted to conventional coupling relations and are shown to permit derivation of either point- or box-centered diffusion difference equations. The resulting difference equations are shown to be mathematically equivalent, in slab geometry, to equations derived by applying Larsen's four-step procedure to the S/sub 2/ equations. Fourier stability analysis of the acceleration method applied to slab model problems is used to demonstrate that, for any S/sub n/ differencing scheme (a) the upper bound on the spectral radius of the method occurs in the fine-mesh limit and equals that of the spatially continuous case (0.22466), and (b) the spectral radius decreases with increasing mesh size to an asymptotic value <0.13135. This model problem performance is somewhat superior to that of Larsen's approach, for which the spectral radius is bounded by 0.25 in the wide-mesh limit. Numerical results of multidimensional, heterogeneous, scattering-dominated problems are also presented to demonstrate the rapid convergence of accelerated discrete ordinates calculations using various spatial differencing schemes

Scanning, non-contact, hybrid broadband diffuse optical spectroscopy and diffuse correlation spectroscopy system.

Science.gov (United States)

Johansson, Johannes D; Mireles, Miguel; Morales-Dalmau, Jordi; Farzam, Parisa; Martínez-Lozano, Mar; Casanovas, Oriol; Durduran, Turgut

2016-02-01

A scanning system for small animal imaging using non-contact, hybrid broadband diffuse optical spectroscopy (ncDOS) and diffuse correlation spectroscopy (ncDCS) is presented. The ncDOS uses a two-dimensional spectrophotometer retrieving broadband (610-900 nm) spectral information from up to fifty-seven source-detector distances between 2 and 5 mm. The ncDCS data is simultaneously acquired from four source-detector pairs. The sample is scanned in two dimensions while tracking variations in height. The system has been validated with liquid phantoms, demonstrated in vivo on a human fingertip during an arm cuff occlusion and on a group of mice with xenoimplanted renal cell carcinoma.

Nodal spectrum method for solving neutron diffusion equation

International Nuclear Information System (INIS)

Sanchez, D.; Garcia, C. R.; Barros, R. C. de; Milian, D.E.

1999-01-01

Presented here is a new numerical nodal method for solving static multidimensional neutron diffusion equation in rectangular geometry. Our method is based on a spectral analysis of the nodal diffusion equations. These equations are obtained by integrating the diffusion equation in X, Y directions and then considering flat approximations for the current. These flat approximations are the only approximations that are considered in this method, as a result the numerical solutions are completely free from truncation errors. We show numerical results to illustrate the methods accuracy for coarse mesh calculations

Semiclassical analysis spectral correlations in mesoscopic systems

International Nuclear Information System (INIS)

Argaman, N.; Imry, Y.; Smilansky, U.

1991-07-01

We consider the recently developed semiclassical analysis of the quantum mechanical spectral form factor, which may be expressed in terms of classically defiable properties. When applied to electrons whose classical behaviour is diffusive, the results of earlier quantum mechanical perturbative derivations, which were developed under a different set of assumptions, are reproduced. The comparison between the two derivations shows that the results depends not on their specific details, but to a large extent on the principle of quantum coherent superposition, and on the generality of the notion of diffusion. The connection with classical properties facilitates application to many physical situations. (author)

Machine Fault Detection Based on Filter Bank Similarity Features Using Acoustic and Vibration Analysis

Directory of Open Access Journals (Sweden)

Mauricio Holguín-Londoño

2016-01-01

Full Text Available Vibration and acoustic analysis actively support the nondestructive and noninvasive fault diagnostics of rotating machines at early stages. Nonetheless, the acoustic signal is less used because of its vulnerability to external interferences, hindering an efficient and robust analysis for condition monitoring (CM. This paper presents a novel methodology to characterize different failure signatures from rotating machines using either acoustic or vibration signals. Firstly, the signal is decomposed into several narrow-band spectral components applying different filter bank methods such as empirical mode decomposition, wavelet packet transform, and Fourier-based filtering. Secondly, a feature set is built using a proposed similarity measure termed cumulative spectral density index and used to estimate the mutual statistical dependence between each bandwidth-limited component and the raw signal. Finally, a classification scheme is carried out to distinguish the different types of faults. The methodology is tested in two laboratory experiments, including turbine blade degradation and rolling element bearing faults. The robustness of our approach is validated contaminating the signal with several levels of additive white Gaussian noise, obtaining high-performance outcomes that make the usage of vibration, acoustic, and vibroacoustic measurements in different applications comparable. As a result, the proposed fault detection based on filter bank similarity features is a promising methodology to implement in CM of rotating machinery, even using measurements with low signal-to-noise ratio.

Methods for measuring the spectral reflectivity of advanced materials at high temperature

International Nuclear Information System (INIS)

Salikhov, T.P.; Kan, V.V.

1993-01-01

For investigation in the domain of advanced materials as well as for new technologies there is an urgent need for knowledge of the spectral reflectivity of the materials specially at high temperatures. However the methods available are mostly intended for measuring the model materials with specular or diffuse reflection surface. This is not quite correct since advanced materials have mixed specular diffuse reflection surfaces. New methods for reflectivity measurements of materials in the visible, near and middle infrared range at high temperature, regardless of surface texture, have been developed. The advantages of the methods proposed are as flows: (a) the facility of performing the reflectivity measurements for materials with mixed specular diffuse reflectance; (b) wide spectral range 0,38-8 micro m; (c) wide temperature range 300-3000 K; (d) high accuracy and rapid measurements. The methods are based on the following principals (i) Diffuse irradiation of the sample surface and the use of Helkholtz reciprocity principle to determine the directional hemispherical reflectivity ii) Pulse polychromatic probing of the sample by additional light source. The first principle excludes the influence of the angular reflection distribution of sample surface on data obtained. The second principle gives the possibility of simultaneous measurements of the reflectivity. The second principle gives the possibility of simultaneous measurements of the reflectivity in wide spectral range. On the basis of these principles for high temperature reflectometers have been developed and discussed here. (author)

First-principles calculations of impurity diffusion coefficients in dilute Mg alloys using the 8-frequency model

International Nuclear Information System (INIS)

Ganeshan, S.; Hector, L.G.; Liu, Z.-K.

2011-01-01

Research highlights: → Implemented the eight frequency model for impurity diffusion in hexagonal metals. → Model inputs were energetics/vibrational properties from first princples. → Predicted diffusion coefficients for Al, Ca, Zn and Sn impurity diffusion in Mg. → Successful prediction of partial correlation factors and jump frequencies. → Good agreement between calculated and experimental results. - Abstract: Diffusion in dilute Mg-X alloys, where X denotes Al, Zn, Sn and Ca impurities, was investigated with first-principles density functional theory in the local density approximation. Impurity diffusion coefficients were computed as a function of temperature using the 8-frequency model which provided the relevant impurity and solvent (Mg) jump frequencies and correlation factors. Minimum energy pathways for impurity diffusion and associated saddle point structures were computed with the climbing image nudged elastic band method. Vibrational properties were obtained with the supercell (direct) method for lattice dynamics. Calculated diffusion coefficients were compared with available experimental data. For diffusion between basal planes, we find D Mg-Ca > D Mg-Zn > D Mg-Sn > D Mg-Al, where D is the diffusion coefficient. For diffusion within a basal plane, the same trend holds except that D Mg-Zn overlaps with D Mg-Al at high temperatures and D Mg-Sn at low temperatures. These trends were explored with charge density contours in selected planes of each Mg-X alloy, the variation of the activation energy for diffusion with the atomic radius of each impurity and the electronic density of states. The theoretical methodology developed herein can be applied to impurity diffusion in other hexagonal materials.

Isotope separation using vibrationally excited molecules

International Nuclear Information System (INIS)

Woodroffe, J.A.; Keck, J.C.

1979-01-01

Vibrational excitation of molecules having components of a selected isotope type is used to produce a conversion from vibrational to translational excitation of the molecules by collision with the molecules of a heavy carrier gas. The resulting difference in translaton between the molecules of the selected isotope type and all other molecules of the same compound permits their separate collection. When applied to uranium enrichment, a subsonic cryogenic flow of molecules of uranium hexafluoride in combination with an argon carrier gas is directed through a cooled chamber that is illuminated by laser radiaton tuned to vibrationally excite the uranium hexafluoride molecules of a specific uranium isotope. The excited molecules collide with carrier gas molecules, causing a conversion of the excitation energy into a translation of the excited molecule, which results in a higher thermal energy or diffusivity than that of the other uranium hexafluoride molecules. The flowing molecules including the excited molecules directly enter a set of cryogenically cooled channels. The higher thermal velocity of the excited molecules increases the probability of their striking a collector surface. The molecules which strike this surface immediately condense. After a predetermined thickness of molecules is collected on the surface, the flow of uranium hexafluoride is interrupted and the chamber heated to the point of vaporization of the collected hexafluoride, permitting its removal. (LL)

Nonlinear dynamics and control of a vibrating rectangular plate

Science.gov (United States)

Shebalin, J. V.

1983-01-01

The von Karman equations of nonlinear elasticity are solved for the case of a vibrating rectangular plate by meams of a Fourier spectral transform method. The amplification of a particular Fourier mode by nonlinear transfer of energy is demonstrated for this conservative system. The multi-mode system is reduced to a minimal (two mode) system, retaining the qualitative features of the multi-mode system. The effect of a modal control law on the dynamics of this minimal nonlinear elastic system is examined.

Benchmarks with diffusion theory and transport theory

International Nuclear Information System (INIS)

Cunha Menezes Filho, A. da; Souza, A.L. de.

1984-01-01

The multiplication factor and some spectral indices for five critical assemblies (ZPR-6-7, ZPR-3-11, GODIVA, BIG-TEN and FLATTOP) are calculated by Diffusion and Transport Theory, with group constants generated by MC 2 (for diffusion calculations) and by NJOY (for transport calculations). The discrepancies encountered in the ZPR-6-7 spectra, can be tracked to the large differences in the elastic cross section for Iron, calculated by MC 2 and NJOY. (Author) [pt

Vibration-tolerant narrow-linewidth semiconductor disk laser using novel frequency-stabilisation schemes

Science.gov (United States)

Hunter, Craig R.; Jones, Brynmor E.; Schlosser, Peter; Sørensen, Simon Toft; Strain, Michael J.; McKnight, Loyd J.

2018-02-01

This paper will present developments in narrow-linewidth semiconductor-disk-laser systems using novel frequencystabilisation schemes for reduced sensitivity to mechanical vibrations, a critical requirement for mobile applications. Narrow-linewidth single-frequency lasers are required for a range of applications including metrology and highresolution spectroscopy. Stabilisation of the laser was achieved using a monolithic fibre-optic ring resonator with free spectral range of 181 MHz and finesse of 52 to act as passive reference cavity for the laser. Such a cavity can operate over a broad wavelength range and is immune to a wide band of vibrational frequency noise due to its monolithic implementation. The frequency noise of the locked system has been measured and compared to typical Fabry-Perotlocked lasers using vibration equipment to simulate harsh environments, and analysed here. Locked linewidths of portable, narrow-linewidth laser system for harsh environments that can be flexibly designed for a range of applications.

Conformational determination of [Leu]enkephalin based on theoretical and experimental VA and VCD spectral analyses

DEFF Research Database (Denmark)

Abdali, Salim; Jalkanen, Karl J.; Cao, X.

2004-01-01

Conformational determination of [Leu]enkephalin in DMSO-d6 is carried out using VA and VCD spectral analyses. Conformational energies, vibrational frequencies and VA and VCD intensities are calculated using DFT at B3LYP/6-31G* level of theory. Comparison between the measured spectra...

A study on waviness induced vibration of ball bearings based on signal coherence theory

Science.gov (United States)

Liu, Wentao; Zhang, Yun; Feng, Zhi-Jing; Zhao, Jing-Shan; Wang, Dongfeng

2014-11-01

This paper focuses on the effects of waviness on vibration of ball bearings. An experimental analysis method is developed by adopting signal coherence theory of multiple-inputs/single-output (MISO) system. The inputs are waviness excitations of the inner and outer races, and the output is vibration response of the outer ring. Waviness excitation signals are first derived from the manufacturing deviations, and found to be strongly coherent in low frequency range. Virtual input signals are then introduced by the method of orthogonalization. In both cases of vibration acceleration and speed responses, the cumulated virtual input-output coherence function verifies that the first peak region of vibration spectrum is mainly induced by the waviness excitations. In order to distinguish the contributions of the inner and outer races, coherence functions of the virtual inputs with real inputs are calculated, and the results indicate that the outer race waviness contributes more to vibration than the inner race waviness does in the example. Further, a multi-body dynamic model is constructed and employed to frequency response analyses. It is discovered that the waviness induced spectral peak frequency is close to the natural frequency of bearing.

Ground-based spectral measurements of solar radiation, (2)

International Nuclear Information System (INIS)

Murai, Keizo; Kobayashi, Masaharu; Goto, Ryozo; Yamauchi, Toyotaro

1979-01-01

A newly designed spectro-pyranometer was used for the measurement of the global (direct + diffuse) and the diffuse sky radiation reaching the ground. By the subtraction of the diffuse component from the global radiation, we got the direct radiation component which leads to the spectral distribution of the optical thickness (extinction coefficient) of the turbid atmosphere. The measurement of the diffuse sky radiation reveals the scattering effect of aerosols and that of the global radiation allows the estimation of total attenuation caused by scattering and absorption of aerosols. The effects of the aerosols are represented by the deviation of the real atmosphere measured from the Rayleigh atmosphere. By the combination of the measured values with those obtained by theoretical calculation for the model atmosphere, we estimated the amount of absorption by the aerosols. Very strong absorption in the ultraviolet region was recognized. (author)

Thermal infrared spectral analysis of compacted fine-grained mineral mixtures: implications for spectral interpretation of lithified sedimentary materials on Mars

Science.gov (United States)

Pan, C.; Rogers, D.

2012-12-01

Characterizing the thermal infrared (TIR) spectral mixing behavior of compacted fine-grained mineral assemblages is necessary for facilitating quantitative mineralogy of sedimentary surfaces from spectral measurements. Previous researchers have demonstrated that TIR spectra from igneous and metamorphic rocks as well as coarse-grained (>63 micron) sand mixtures combine in proportion to their volume abundance. However, the spectral mixing behavior of compacted, fine-grained mineral mixtures that would be characteristic of sedimentary depositional environments has received little attention. Here we characterize the spectral properties of pressed pellet samples of pestle and centrifuged to obtain less than 10 micron size. Pure phases and mixtures of two, three and four components were made in varying proportions by volume. All of the samples were pressed into pellets at 15000PSI to minimize volume scattering. Thermal infrared spectra of pellets were measured in the Vibrational Spectroscopy Laboratory at Stony Brook University with a Thermo Fisher Nicolet 6700 Fourier transform infrared Michelson interferometer from ~225 to 2000 cm-1. Our preliminary results indicate that some pelletized samples have contributions from volume scattering, which leads to non-linear spectral combinations. It is not clear if the transparency features (which arise from multiple surface reflections of incident photons) are due to minor clinging fines on an otherwise specular pellet surface or to partially transmitted energy through optically thin grains in the compacted mixture. Inclusion of loose powder (analysis of TES and Mini-TES data of lithified sedimentary deposits.

Investigation of the vibration and EMC characteristics of miniature Stirling electric coolers for space applications

Science.gov (United States)

Kondratjev, V.; Gostilo, V.; Owens, anb A.

2017-08-01

We present the results of an investigation into the detrimental effects that electromechanical coolers can have on the spectral performance of compact, large volume HPGe spectrometers for space applications. Both mechanical vibration and electromagnetic pickup effects were considered, as well as a comparative assessment between three miniature Stirling cycle coolers—two Ricor model K508 coolers and one Thales model RM3 cooler. In spite of the limited number of coolers tested, the following conclusions can be made. There are significant differences in the vibration characteristics not only between the various types of cooler but also between coolers of the same type. It was also found that compared to the noise induced by mechanical vibrations, electromagnetic interference emanating from the embedded controllers does not significantly impact the energy resolution of detectors.

Micro-vibration response of a stochastically excited sandwich beam with a magnetorheological elastomer core and mass

International Nuclear Information System (INIS)

Ying, Z G; Ni, Y Q

2009-01-01

Magnetorheological (MR) elastomers are used to construct a smart sandwich beam for micro-vibration control. The micro-vibration response of a clamped–free sandwich beam with an MR elastomer core and a supplemental mass under stochastic support micro-motion excitation is studied. The dynamic behavior of MR elastomer as a smart viscoelastic material is described by a complex modulus which is controllable by external magnetic field. The sixth-order partial differential equation of motion of the sandwich beam is derived from the dynamic equilibrium, constitutive and geometric relations. A frequency-domain solution method for the stochastic micro-vibration response of the sandwich beam is developed by using the frequency-response function, power spectral density function and spatial eigensolution. The root-mean-square velocity response in terms of the one-third octave frequency band is calculated, and then the response reduction capacity through optimizing the complex modulus of the core is analyzed. Numerical results illustrate the influences of the MR elastomer core parameters on the root-mean-square velocity response and the high response reduction capacity of the sandwich beam. The developed analysis method is applicable to sandwich beams with arbitrary cores described by complex shear moduli under arbitrary stochastic excitations described by power spectral density functions

Structural determination of some uranyl compounds by vibrational spectroscopy; Determinacion estructural de algunos compuestos de uranilo por espectroscopia vibracional

Energy Technology Data Exchange (ETDEWEB)

Rodriguez S, A.; Martinez Q, E

1990-07-15

The vibrational spectra of different uranyl compounds has been studied and of it spectral information has been used the fundamental asymmetric vibrational frequency, to determine the length and constant bond force U=O by means of the combination of the concept of absorbed energy and the mathematical expression of Badger modified by Jones. It is intended a factor that simplifies the mathematical treatment and the results are compared with the values obtained for other methods. (Author)

Vibration measurement with nonlinear converter in the presence of noise

Science.gov (United States)

Mozuras, Almantas

2017-10-01

Conventional vibration measurement methods use the linear properties of physical converters. These methods are strongly influenced by nonlinear distortions, because ideal linear converters are not available. Practically, any converter can be considered as a linear one, when an output signal is very small. However, the influence of noise increases significantly and signal-to-noise ratio decreases at lower signals. When the output signal is increasing, the nonlinear distortions are also augmenting. If the wide spectrum vibration is measured, conventional methods face a harmonic distortion as well as intermodulation effects. Purpose of this research is to develop a measurement method of wide spectrum vibration by using a converter described by a nonlinear function of type f(x), where x =x(t) denotes the dependence of coordinate x on time t due to the vibration. Parameter x(t) describing the vibration is expressed as Fourier series. The spectral components of the converter output f(x(t)) are determined by using Fourier transform. The obtained system of nonlinear equations is solved using the least squares technique that permits to find x(t) in the presence of noise. This method allows one to carry out the absolute or relative vibration measurements. High resistance to noise is typical for the absolute vibration measurement, but it is necessary to know the Taylor expansion coefficients of the function f(x). If the Taylor expansion is not known, the relative measurement of vibration parameters is also possible, but with lower resistance to noise. This method allows one to eliminate the influence of nonlinear distortions to the measurement results, and consequently to eliminate harmonic distortion and intermodulation effects. The use of nonlinear properties of the converter for measurement gives some advantages related to an increased frequency range of the output signal (consequently increasing the number of equations) that allows one to decrease the noise influence on

Application of H/V technique on different soils using ambient vibration measurements and earthquakes

International Nuclear Information System (INIS)

Schmidt-Diaz, Victor

2016-01-01

Four techniques to identify the fundamental frequency (f0) for 26 different sites were applied. These techniques correspond to spectral ratios based on the recording of: ambient vibration using an accelerograph (denominated VAA), ambient vibration using a seismograph (VAS), total seismic records (ST) and a time window of 5 s staring at S waves arrives in the seismic records (SOS). Better results were achieved when VAA was applied during the day (at 8 am and 3 pm). When VAA at 3 pm was compared to VAS at day time, it was observed that in the 58% of the analyzed cases the shapes and amplitudes of the spectral ratios were different, which means that VAA is not an appropriated technique to identify f0 based on that the results from VAS are the correct ones. It is affirmed based on its similarity to ST and SOS techniques in a 75% of the studied cases. These last two techniques are better justified in both mathematical and physical fundaments. (author) [es

Application of a simplified calculation for full-wave microtremor H/ V spectral ratio based on the diffuse field approximation to identify underground velocity structures

Science.gov (United States)

Wu, Hao; Masaki, Kazuaki; Irikura, Kojiro; Sánchez-Sesma, Francisco José

2017-12-01

Under the diffuse field approximation, the full-wave (FW) microtremor H/ V spectral ratio ( H/ V) is modeled as the square root of the ratio of the sum of imaginary parts of the Green's function of the horizontal components to that of the vertical one. For a given layered medium, the FW H/ V can be well approximated with only surface waves (SW) H/ V of the "cap-layered" medium which consists of the given layered medium and a new larger velocity half-space (cap layer) at large depth. Because the contribution of surface waves can be simply obtained by the residue theorem, the computation of SW H/ V of cap-layered medium is faster than that of FW H/ V evaluated by discrete wavenumber method and contour integration method. The simplified computation of SW H/ V was then applied to identify the underground velocity structures at six KiK-net strong-motion stations. The inverted underground velocity structures were used to evaluate FW H/ Vs which were consistent with the SW H/ Vs of corresponding cap-layered media. The previous study on surface waves H/ Vs proposed with the distributed surface sources assumption and a fixed Rayleigh-to-Love waves amplitude ratio for horizontal motions showed a good agreement with the SW H/ Vs of our study. The consistency between observed and theoretical spectral ratios, such as the earthquake motions of H/ V spectral ratio and spectral ratio of horizontal motions between surface and bottom of borehole, indicated that the underground velocity structures identified from SW H/ V of cap-layered medium were well resolved by the new method.[Figure not available: see fulltext.

Probing electronic and vibrational properties at the electrochemical interface using SFG spectroscopy: Methanol electro-oxidation on Pt(1 1 0)

Science.gov (United States)

Vidal, F.; Busson, B.; Tadjeddine, A.

2005-02-01

We report the study of methanol electro-oxidation on Pt(1 1 0) using infrared-visible sum-frequency generation (SFG) vibrational spectroscopy. The use of this technique enables to probe the vibrational and electronic properties of the interface simultaneously in situ. We have investigated the vibrational properties of the interface in the CO ads internal stretch spectral region (1700-2150 cm -1) over a wide range of potentials. The analysis of the evolution of the C-O stretch line shape, which is related to the interference between the vibrational and electronic parts of the non-linear response, with the potential allows us to show that the onset of bulk methanol oxidation corresponds to the transition from a negatively to a positively charged surface.

DNA Methylation Changes in Valproic Acid-Treated HeLa Cells as Assessed by Image Analysis, Immunofluorescence and Vibrational Microspectroscopy.

Directory of Open Access Journals (Sweden)

Giovana M B Veronezi

Full Text Available Valproic acid (VPA, a well-known histone deacetylase inhibitor, has been reported to affect the DNA methylation status in addition to inducing histone hyperacetylation in several cell types. In HeLa cells, VPA promotes histone acetylation and chromatin remodeling. However, DNA demethylation was not checked in this cell model for standing effects longer than those provided by histone acetylation, which is a rapid and transient phenomenon. Demonstration of VPA-induced DNA demethylation in HeLa cells would contribute to understanding the effect of VPA on an aggressive tumor cell line. In the present work, DNA demethylation in VPA-treated HeLa cells was assessed by image analysis of chromatin texture, the abundance of 5-methylcytosine (5mC immunofluorescence signals and Fourier transform-infrared (FT-IR microspectroscopy centered on spectral regions related to the vibration of-CH3 groups. Image analysis indicated that increased chromatin unpacking promoted by a 4-h-treatment with 1.0 mM VPA persisted for 24 h in the absence of the drug, suggesting the occurrence of DNA demethylation that was confirmed by decreased 5mC immunofluorescence signals. FT-IR spectra of DNA samples from 1 mM or 20 mM VPA-treated cells subjected to a peak fitting analysis of the spectral window for-CH3 stretching vibrations showed decreased vibrations and energy of these groups as a function of the decreased abundance of 5mC induced by increased VPA concentrations. Only the 20 mM-VPA treatment caused an increase in the ratio of -CH3 bending vibrations evaluated at 1375 cm-1 in relation to in-plane vibrations of overall cytosines evaluated at 1492 cm-1. CH3 stretching vibrations showed to be more sensitive than-CH3 bending vibrations, as detected with FT-IR microspectroscopy, for studies aiming to associate vibrational spectroscopy and changes in DNA 5mC abundance.

Numerical Modal Analysis of Vibrations in a Three-Phase Linear Switched Reluctance Actuator

Directory of Open Access Journals (Sweden)

José Salvado

2017-01-01

Full Text Available This paper addresses the problem of vibrations produced by switched reluctance actuators, focusing on the linear configuration of this type of machines, aiming at its characterization regarding the structural vibrations. The complexity of the mechanical system and the number of parts used put serious restrictions on the effectiveness of analytical approaches. We build the 3D model of the actuator and use finite element method (FEM to find its natural frequencies. The focus is on frequencies within the range up to nearly 1.2 kHz which is considered relevant, based on preliminary simulations and experiments. Spectral analysis results of audio signals from experimental modal excitation are also shown and discussed. The obtained data support the characterization of the linear actuator regarding the excited modes, its vibration frequencies, and mode shapes, with high potential of excitation due to the regular operation regimes of the machine. The results reveal abundant modes and harmonics and the symmetry characteristics of the actuator, showing that the vibration modes can be excited for different configurations of the actuator. The identification of the most critical modes is of great significance for the actuator’s control strategies. This analysis also provides significant information to adopt solutions to reduce the vibrations at the design.

Using Directional Diffusion Coefficients for Nonlinear Diffusion Acceleration of the First Order SN Equations in Near-Void Regions

Energy Technology Data Exchange (ETDEWEB)

Schunert, Sebastian; Hammer, Hans; Lou, Jijie; Wang, Yaqi; Ortensi, Javier; Gleicher, Frederick; Baker, Benjamin; DeHart, Mark; Martineau, Richard

2016-11-01

The common definition of the diffusion coeffcient as the inverse of three times the transport cross section is not compat- ible with voids. Morel introduced a non-local tensor diffusion coeffcient that remains finite in voids[1]. It can be obtained by solving an auxiliary transport problem without scattering or fission. Larsen and Trahan successfully applied this diffusion coeffcient for enhancing the accuracy of diffusion solutions of very high temperature reactor (VHTR) problems that feature large, optically thin channels in the z-direction [2]. It is demonstrated that a significant reduction of error can be achieved in particular in the optically thin region. Along the same line of thought, non-local diffusion tensors are applied modeling the TREAT reactor confirming the findings of Larsen and Trahan [3]. Previous work of the authors have introduced a flexible Nonlinear-Diffusion Acceleration (NDA) method for the first order S N equations discretized with the discontinuous finite element method (DFEM), [4], [5], [6]. This NDA method uses a scalar diffusion coeffcient in the low-order system that is obtained as the flux weighted average of the inverse transport cross section. Hence, it su?ers from very large and potentially unbounded diffusion coeffcients in the low order problem. However, it was noted that the choice of the diffusion coeffcient does not influence consistency of the method at convergence and hence the di?usion coeffcient is essentially a free parameter. The choice of the di?usion coeffcient does, however, affect the convergence behavior of the nonlinear di?usion iterations. Within this work we use Morel’s non-local di?usion coef- ficient in the aforementioned NDA formulation in lieu of the flux weighted inverse of three times the transport cross section. The goal of this paper is to demonstrate that significant en- hancement of the spectral properties of NDA can be achieved in near void regions. For testing the spectral properties of the NDA

[Occupational standing vibration rate and vibrational diseases].

Science.gov (United States)

Karnaukh, N G; Vyshchipan, V F; Haumenko, B S

2003-12-01

Occupational standing vibration rate is proposed in evaluating a degree of impairment of an organism activity. It will allow more widely to introduce specification of quality and quantity in assessment of the development of vibrational disease. According out-patient and inpatient obtained data we have established criterial values of functional changes in accordance with accumulated occupational standing vibration rate. The nomogram was worked out for defining a risk of the development of vibrational disease in mine workers. This nomogram more objectively can help in diagnostics of the disease.

Accuracy in mineral identification: image spectral and spatial resolutions and mineral spectral properties

Directory of Open Access Journals (Sweden)

L. Pompilio

2006-06-01

Full Text Available Problems related to airborne hyperspectral image data are reviewed and the requirements for data analysis applied to mineralogical (rocks and soils interpretation are discussed. The variability of mineral spectral features, including absorption position, shape and depth is considered and interpreted as due to chemical composition, grain size effects and mineral association. It is also shown how this variability can be related to well defined geologic processes. The influence of sensor noise and diffuse atmospheric radiance in classification accuracy is also analyzed.

Diffusion coefficients of alloying elements in dilute Mg alloys: A comprehensive first-principles study

International Nuclear Information System (INIS)

Zhou, Bi-Cheng; Shang, Shun-Li; Wang, Yi; Liu, Zi-Kui

2016-01-01

First-principles calculations based on density functional theory have been used to calculate the temperature-dependent dilute tracer diffusion coefficients for 47 substitutional alloying elements in hexagonal closed packed (hcp) Mg by combining transition state theory and an 8-frequency model. The minimum energy pathways and the saddle point configurations during solute migration are calculated with the climbing image nudged elastic band method. Vibrational properties are obtained using the quasi-harmonic Debye model with inputs from first-principles calculations. An improved generalized gradient approximation of PBEsol is used in the present first-principles calculations, which is able to well describe both vacancy formation energies and vibrational properties. It is found that the solute diffusion coefficients in hcp Mg are roughly inversely proportional to the bulk modulus of the dilute alloys, which reflects the solutes' bonding to Mg. Transition metal elements with d electrons show strong interactions with Mg and have large diffusion activation energies. Correlation effects are not negligible for solutes Ca, Na, Sr, Se, Te, and Y, in which the direct solute migration barriers are much smaller than the solvent (Mg) migration barriers. Calculated diffusion coefficients are in remarkable agreement with available experimental data in the literature.

Spectral solar irradiance and some optical properties for various polluted atmospheres

International Nuclear Information System (INIS)

Jacovides, Constantinos P.; Asimakopoulos, Demosthenis N.; Steven, Michael D.

2000-01-01

Using ground-based spectroradiometric measurements taken over the Athens atmosphere during May 1995, the influence of gaseous pollutants and aerosol on the spectral radiant energy distribution was investigated. It was found that spectral measurements exhibited variations based on various polluted urban atmospheric conditions as determined via gaseous pollutants record analysis. The relative attenuations cause by gaseous pollutants and aerosol can exceed 27%, 17% and 16% in the global ultraviolet, visible and near-infrared portions of the solar spectrum respectively, as compared to 'background' values. In contrast, an enhancement of the near-infrared diffuse component by 66%, was observed, while in visible and ultraviolet bands the relative increases reached 54% and 21% respectively. Experimental total Rayleigh-corrected and spectral aerosol optical depths were retrieved, representing differences in polluted air over the Athens atmosphere. The diffuse component accounts for more than 80% of the total radiation field under high polluted atmosphere. The observed differences of solar radiation between the Athens center and at a nearby suburban site are a manifestation of contrasting air properties provided mainly by automotive traffic. (Author)

Recovering Intrinsic Fragmental Vibrations Using the Generalized Subsystem Vibrational Analysis.

Science.gov (United States)

Tao, Yunwen; Tian, Chuan; Verma, Niraj; Zou, Wenli; Wang, Chao; Cremer, Dieter; Kraka, Elfi

2018-05-08

Normal vibrational modes are generally delocalized over the molecular system, which makes it difficult to assign certain vibrations to specific fragments or functional groups. We introduce a new approach, the Generalized Subsystem Vibrational Analysis (GSVA), to extract the intrinsic fragmental vibrations of any fragment/subsystem from the whole system via the evaluation of the corresponding effective Hessian matrix. The retention of the curvature information with regard to the potential energy surface for the effective Hessian matrix endows our approach with a concrete physical basis and enables the normal vibrational modes of different molecular systems to be legitimately comparable. Furthermore, the intrinsic fragmental vibrations act as a new link between the Konkoli-Cremer local vibrational modes and the normal vibrational modes.

Mode shape and natural frequency identification for seismic analysis from background vibration

International Nuclear Information System (INIS)

Bhan, S.; Wozniak, Z.

1986-02-01

The feasibility of calculating natural frequencies and mode shapes of major equipment in a CANDU reactor from the measurements of their response to background excitation has been studied. A review of vibration data measured at various locations in CANDU plants shows that structures responded to a combination of random and harmonic background excitation. Amplitude of measured vibration is sufficient to allow meaningful data analysis. Frequency content in the 0 to 50-Hz range, which is of interest for earthquake response, is present in some of the vibration measurements studied. Spectral techniques have been developed for determining the response function of structures from measured vibration response to background excitation. The natural frequencies and mode shapes are then evaluated graphically from the frequency function plots. The methodology has been tested on a simple cantilever beam with known natural frequencies and mode shapes. The comparison between the theoretical and the computed natural frequencies and mode shapes is good for the lower modes. However, better curve-fitting techniques will be required in future, especially for higher modes. Readily available equipment necessary for the measurement of background vibration in a CANDU plant (which is commercially available) has been identified. An experimental program has been proposed to verify the methodology developed in this study. Recommendations are also made to study methods to improve the accuracy of the mode shape and natural frequency prediction

Chemical reactions of water molecules on Ru(0001) induced by selective excitation of vibrational modes

Energy Technology Data Exchange (ETDEWEB)

Mugarza, Aitor; Shimizu, Tomoko K.; Ogletree, D. Frank; Salmeron, Miquel

2009-05-07

Tunneling electrons in a scanning tunneling microscope were used to excite specific vibrational quantum states of adsorbed water and hydroxyl molecules on a Ru(0 0 0 1) surface. The excited molecules relaxed by transfer of energy to lower energy modes, resulting in diffusion, dissociation, desorption, and surface-tip transfer processes. Diffusion of H{sub 2}O molecules could be induced by excitation of the O-H stretch vibration mode at 445 meV. Isolated molecules required excitation of one single quantum while molecules bonded to a C atom required at least two quanta. Dissociation of single H{sub 2}O molecules into H and OH required electron energies of 1 eV or higher while dissociation of OH required at least 2 eV electrons. In contrast, water molecules forming part of a cluster could be dissociated with electron energies of 0.5 eV.

Transverse single-file diffusion and enhanced longitudinal diffusion near a subcritical bifurcation

Science.gov (United States)

Dessup, Tommy; Coste, Christophe; Saint Jean, Michel

2018-05-01

A quasi-one-dimensional system of repelling particles undergoes a configurational phase transition when the transverse confining potential decreases. Below a threshold, it becomes energetically favorable for the system to adopt one of two staggered raw patterns, symmetric with respect to the system axis. This transition is a subcritical pitchfork bifurcation for short range interactions. As a consequence, the homogeneous zigzag pattern is unstable in a finite zigzag amplitude range [hC 1,hC 2] . We exhibit strong qualitative effects of the subcriticality on the thermal motions of the particles. When the zigzag amplitude is close enough to the limits hC 1 and hC 2, a transverse vibrational soft mode occurs which induces a strongly subdiffusive behavior of the transverse fluctuations, similar to single-file diffusion. On the contrary, the longitudinal fluctuations are enhanced, with a diffusion coefficient which is more than doubled. Conversely, a simple measurement of the thermal fluctuations allows a precise determination of the bifurcation thresholds.

Diffusion and spectroscopy of water and lipids in fully hydrated dimyristoylphosphatidylcholine bilayer membranes

International Nuclear Information System (INIS)

Yang, J.; Martí, J.; Calero, C.

2014-01-01

Microscopic structure and dynamics of water and lipids in a fully hydrated dimyristoylphosphatidylcholine phospholipid lipid bilayer membrane in the liquid-crystalline phase have been analyzed with all-atom molecular dynamics simulations based on the recently parameterized CHARMM36 force field. The diffusive dynamics of the membrane lipids and of its hydration water, their reorientational motions as well as their corresponding spectral densities, related to the absorption of radiation, have been considered for the first time using the present force field. In addition, structural properties such as density and pressure profiles, a deuterium-order parameter, surface tension, and the extent of water penetration in the membrane have been analyzed. Molecular self-diffusion, reorientational motions, and spectral densities of atomic species reveal a variety of time scales playing a role in membrane dynamics. The mechanisms of lipid motion strongly depend on the time scale considered, from fast ballistic translation at the scale of picoseconds (effective diffusion coefficients of the order of 10 −5 cm 2 /s) to diffusive flow of a few lipids forming nanodomains at the scale of hundreds of nanoseconds (diffusion coefficients of the order of 10 −8 cm 2 /s). In the intermediate regime of sub-diffusion, collisions with nearest neighbors prevent the lipids to achieve full diffusion. Lipid reorientations along selected directions agree well with reported nuclear magnetic resonance data and indicate two different time scales, one about 1 ns and a second one in the range of 2–8 ns. We associated the two time scales of reorientational motions with angular distributions of selected vectors. Calculated spectral densities corresponding to lipid and water reveal an overall good qualitative agreement with Fourier transform infrared spectroscopy experiments. Our simulations indicate a blue-shift of the low frequency spectral bands of hydration water as a result of its interaction

Diffusion and spectroscopy of water and lipids in fully hydrated dimyristoylphosphatidylcholine bilayer membranes

Energy Technology Data Exchange (ETDEWEB)

Yang, J.; Martí, J., E-mail: jordi.marti@upc.edu [Department of Physics and Nuclear Engineering, Technical University of Catalonia-Barcelona Tech, B4-B5 Northern Campus, Jordi Girona 1-3, 08034 Barcelona, Catalonia (Spain); Calero, C. [Department of Physics and Nuclear Engineering, Technical University of Catalonia-Barcelona Tech, B4-B5 Northern Campus, Jordi Girona 1-3, 08034 Barcelona, Catalonia (Spain); Center for Polymer Studies, Department of Physics, Boston University, 590 Commonwealth Avenue, Boston, Massachusetts 02215 (United States)

2014-03-14

Microscopic structure and dynamics of water and lipids in a fully hydrated dimyristoylphosphatidylcholine phospholipid lipid bilayer membrane in the liquid-crystalline phase have been analyzed with all-atom molecular dynamics simulations based on the recently parameterized CHARMM36 force field. The diffusive dynamics of the membrane lipids and of its hydration water, their reorientational motions as well as their corresponding spectral densities, related to the absorption of radiation, have been considered for the first time using the present force field. In addition, structural properties such as density and pressure profiles, a deuterium-order parameter, surface tension, and the extent of water penetration in the membrane have been analyzed. Molecular self-diffusion, reorientational motions, and spectral densities of atomic species reveal a variety of time scales playing a role in membrane dynamics. The mechanisms of lipid motion strongly depend on the time scale considered, from fast ballistic translation at the scale of picoseconds (effective diffusion coefficients of the order of 10{sup −5} cm{sup 2}/s) to diffusive flow of a few lipids forming nanodomains at the scale of hundreds of nanoseconds (diffusion coefficients of the order of 10{sup −8} cm{sup 2}/s). In the intermediate regime of sub-diffusion, collisions with nearest neighbors prevent the lipids to achieve full diffusion. Lipid reorientations along selected directions agree well with reported nuclear magnetic resonance data and indicate two different time scales, one about 1 ns and a second one in the range of 2–8 ns. We associated the two time scales of reorientational motions with angular distributions of selected vectors. Calculated spectral densities corresponding to lipid and water reveal an overall good qualitative agreement with Fourier transform infrared spectroscopy experiments. Our simulations indicate a blue-shift of the low frequency spectral bands of hydration water as a result of

EEG dynamical correlates of focal and diffuse causes of coma.

Science.gov (United States)

Kafashan, MohammadMehdi; Ryu, Shoko; Hargis, Mitchell J; Laurido-Soto, Osvaldo; Roberts, Debra E; Thontakudi, Akshay; Eisenman, Lawrence; Kummer, Terrance T; Ching, ShiNung

2017-11-15

Rapidly determining the causes of a depressed level of consciousness (DLOC) including coma is a common clinical challenge. Quantitative analysis of the electroencephalogram (EEG) has the potential to improve DLOC assessment by providing readily deployable, temporally detailed characterization of brain activity in such patients. While used commonly for seizure detection, EEG-based assessment of DLOC etiology is less well-established. As a first step towards etiological diagnosis, we sought to distinguish focal and diffuse causes of DLOC through assessment of temporal dynamics within EEG signals. We retrospectively analyzed EEG recordings from 40 patients with DLOC with consensus focal or diffuse culprit pathology. For each recording, we performed a suite of time-series analyses, then used a statistical framework to identify which analyses (features) could be used to distinguish between focal and diffuse cases. Using cross-validation approaches, we identified several spectral and non-spectral EEG features that were significantly different between DLOC patients with focal vs. diffuse etiologies, enabling EEG-based classification with an accuracy of 76%. Our findings suggest that DLOC due to focal vs. diffuse injuries differ along several electrophysiological parameters. These results may form the basis of future classification strategies for DLOC and coma that are more etiologically-specific and therefore therapeutically-relevant.

Application of the random vibration approach in the seismic analysis of LMFBR structures - Benchmark calculations

International Nuclear Information System (INIS)

Preumont, A.; Shilab, S.; Cornaggia, L.; Reale, M.; Labbe, P.; Noe, H.

1992-01-01

This benchmark exercise is the continuation of the state-of-the-art review (EUR 11369 EN) which concluded that the random vibration approach could be an effective tool in seismic analysis of nuclear power plants, with potential advantages on time history and response spectrum techniques. As compared to the latter, the random vibration method provides an accurate treatment of multisupport excitations, non classical damping as well as the combination of high-frequency modal components. With respect to the former, the random vibration method offers direct information on statistical variability (probability distribution) and cheaper computations. The disadvantages of the random vibration method are that it is based on stationary results, and requires a power spectral density input instead of a response spectrum. A benchmark exercise to compare the three methods from the various aspects mentioned above, on one or several simple structures has been made. The following aspects have been covered with the simplest possible models: (i) statistical variability, (ii) multisupport excitation, (iii) non-classical damping. The random vibration method is therefore concluded to be a reliable method of analysis. Its use is recommended, particularly for preliminary design, owing to its computational advantage on multiple time history analysis

Far-infrared vibrational modes of DNA components studied by terahertz time-domain spectroscopy

International Nuclear Information System (INIS)

Fischer, B M; Walther, M; Jepsen, P Uhd

2002-01-01

The far-infrared dielectric function of a wide range of organic molecules is dominated by vibrations involving a substantial fraction of the atoms forming the molecule and motion associated with intermolecular hydrogen bond vibrations. Due to their collective nature such modes are highly sensitive to the intra- and intermolecular structure and thus provide a unique fingerprint of the conformational state of the molecule and effects of its environment. We demonstrate the use of terahertz time-domain spectroscopy (THz-TDS) for recording the far-infrared (0.5-4.0 THz) dielectric function of the four nucleobases and corresponding nucleosides forming the building blocks of deoxyribose nucleic acid (DNA). We observe numerous distinct spectral features with large differences between the molecules in both frequency-dependent absorption coefficient and index of refraction. Assisted by results from density-functional calculations we interpret the origin of the observed resonances as vibrations of hydrogen bonds between the molecules

Vulnerability Assessment for a Complex Structure Using Vibration Response Induced by Impact Load

International Nuclear Information System (INIS)

Park, Jeongwon; Park, Junhong; Koo, Man Hoi

2014-01-01

This work presents a vulnerability assessment procedure for a complex structure using vibration characteristics. The structural behavior of a three-dimensional framed structure subjected to impact forces was predicted using the spectral element method. The Timoshenko beam function was applied to simulate the impact wave propagations induced by a high-velocity projectile at relatively high frequencies. The interactions at the joints were analyzed for both flexural and longitudinal wave propagations. Simulations of the impact energy transfer through the entire structure were performed using the transient displacement and acceleration responses obtained from the frequency analysis. The kill probabilities of the crucial components for an operating system were calculated as a function of the predicted acceleration amplitudes according to the acceptable vibration levels. Following the proposed vulnerability assessment procedure, the vulnerable positions of a three-dimensional combat vehicle with high possibilities of damage generation of components by impact loading were identified from the estimated vibration responses

Vibrational Spectroscopic Studies of Tenofovir Using Density Functional Theory Method

Directory of Open Access Journals (Sweden)

G. R. Ramkumaar

2013-01-01

Full Text Available A systematic vibrational spectroscopic assignment and analysis of tenofovir has been carried out by using FTIR and FT-Raman spectral data. The vibrational analysis was aided by electronic structure calculations—hybrid density functional methods (B3LYP/6-311++G(d,p, B3LYP/6-31G(d,p, and B3PW91/6-31G(d,p. Molecular equilibrium geometries, electronic energies, IR intensities, and harmonic vibrational frequencies have been computed. The assignments proposed based on the experimental IR and Raman spectra have been reviewed and complete assignment of the observed spectra have been proposed. UV-visible spectrum of the compound was also recorded and the electronic properties such as HOMO and LUMO energies and were determined by time-dependent DFT (TD-DFT method. The geometrical, thermodynamical parameters, and absorption wavelengths were compared with the experimental data. The B3LYP/6-311++G(d,p-, B3LYP/6-31G(d,p-, and B3PW91/6-31G(d,p-based NMR calculation procedure was also done. It was used to assign the 13C and 1H NMR chemical shift of tenofovir.

Vibrational spectra of crystalline formic and acetic acid isotopologues by inelastic neutron scattering and numerical simulations

International Nuclear Information System (INIS)

Johnson, M.R.; Trommsdorff, H.P.

2009-01-01

Vibrational spectra of crystalline powder of four isotopologues of formic acid (HCOOH, HCOOD, DCOOH, DCOOD) and of acetic acid (CH 3 COOH, CH 3 COOD, CD 3 COOH, CD 3 COOD) were recorded at 20 K by inelastic neutron scattering. These spectra are compared with computed spectra based on harmonic force fields derived from periodic density functional theory (DFT) calculations. The assignment of all internal vibrations is obvious from the spectral changes under isotopic substitution. Discrepancies between calculation and experiment expose the over evaluation of the strength of the hydrogen bond by these standard DFT calculations

Multi-layer multi-configuration time-dependent Hartree (ML-MCTDH) approach to the correlated exciton-vibrational dynamics in the FMO complex

Energy Technology Data Exchange (ETDEWEB)

Schulze, Jan; Kühn, Oliver, E-mail: oliver.kuehn@uni-rostock.de [Institut für Physik, Universität Rostock, Albert-Einstein-Str. 23-24, 18059 Rostock (Germany); Shibl, Mohamed F., E-mail: mfshibl@qu.edu.qa; Al-Marri, Mohammed J. [Gas Processing Center, College of Engineering, Qatar University, P.O. Box 2713, Doha (Qatar)

2016-05-14

The coupled quantum dynamics of excitonic and vibrational degrees of freedom is investigated for high-dimensional models of the Fenna-Matthews-Olson complex. This includes a seven- and an eight-site model with 518 and 592 harmonic vibrational modes, respectively. The coupling between local electronic transitions and vibrations is described within the Huang-Rhys model using parameters that are obtained by discretization of an experimental spectral density. Different pathways of excitation energy flow are analyzed in terms of the reduced one-exciton density matrix, focussing on the role of vibrational and vibronic excitations. Distinct features due to both competing time scales of vibrational and exciton motion and vibronically assisted transfer are observed. The question of the effect of initial state preparation is addressed by comparing the case of an instantaneous Franck-Condon excitation at a single site with that of a laser field excitation.

Does ℏ play a role in multidimensional spectroscopy? Reduced hierarchy equations of motion approach to molecular vibrations.

Science.gov (United States)

Sakurai, Atsunori; Tanimura, Yoshitaka

2011-04-28

frequency fluctuation is small. Thus, we observed a distinct difference between the classical and quantum mechanically calculated multidimensional spectra in the slow modulation case where spectral diffusion plays a role. This fact indicates that one may not reproduce the experimentally obtained multidimensional spectrum for high-frequency vibrational modes based on classical molecular dynamics simulations if the modulation that arises from surrounding molecules is weak and slow. A practical way to overcome the difference between the classical and quantum simulations was discussed.

Vibrational spectra and natural bond orbital analysis of organic crystal L-prolinium picrate

Science.gov (United States)

Edwin, Bismi; Amalanathan, M.; Hubert Joe, I.

2012-10-01

Vibrational spectral analysis and quantum chemical computations based on density functional theory (DFT) have been performed on the organic crystal L-prolinium picrate (LPP). The equilibrium geometry, various bonding features and harmonic vibrational wavenumbers of LPP have been investigated using B3LYP method. The calculated molecular geometry has been compared with the experimental data. The detailed interpretation of the vibrational spectra has been carried out with the aid of VEDA 4 program. The various intramolecular interactions confirming the biological activity of the compound have been exposed by natural bond orbital analysis. The distribution of Mulliken atomic charges and bending of natural hybrid orbitals associated with hydrogen bonding also reflects the presence of intramolecular hydrogen bonding thereby enhancing bioactivity. The analysis of the electron density of HOMO and LUMO gives an idea of the delocalization and low value of energy gap indicates electron transport in the molecule and thereby bioactivity. Vibrational analysis reveals the presence of strong O-H⋯O and N-H⋯O interaction between L-prolinium and picrate ions providing evidence for the charge transfer interaction between the donor and acceptor groups and is responsible for its bioactivity.

Effect of shelf aging on vibration transmissibility of anti-vibration gloves

Science.gov (United States)

SHIBATA, Nobuyuki

2017-01-01

Anti-vibration gloves have been used in real workplaces to reduce vibration transmitted through hand-held power tools to the hand. Generally materials used for vibration attenuation in gloves are resilient materials composed of certain synthetic and/or composite polymers. The mechanical characteristics of the resilient materials used in anti-vibration gloves are prone to be influenced by environmental conditions such as temperature, humidity, and photo-irradiation, which cause material degradation and aging. This study focused on the influence of shelf aging on the vibration attenuation performance of air-packaged anti-vibration gloves following 2 yr of shelf aging. Effects of shelf aging on the vibration attenuation performance of anti-vibration gloves were examined according to the Japan industrial standard JIS T8114 test protocol. The findings indicate that shelf aging induces the reduction of vibration attenuation performance in air-packaged anti-vibration gloves. PMID:28978817

Vibrational response of a rectangular duct of finite length excited by a turbulent internal flow

Science.gov (United States)

David, Antoine; Hugues, Florian; Dauchez, Nicolas; Perrey-Debain, Emmanuel

2018-05-01

Gas transport ductwork in industrial plants or air conditioning networks can be subject to vibrations induced by the internal flow. Most studies in this matter have been carried out on circular ducts. This paper focuses specifically on the vibratory response of a rectangular duct of finite length excited by an internal turbulent flow. A semi-analytical model taking into account the modal response of the structure due to both aerodynamic and acoustic contributions is derived. The aerodynamic component of the excitation is applied on the basis of Corcos model where the power spectral density of the wall pressure is determined experimentally. The acoustic component is based on the propagating modes in the duct where the acoustic modal contribution are extracted via cross-spectral densities. The vibrational response is given for a 0.2 × 0.1 × 0.5 m3 duct made of 3 mm steel plates excited by 20 m/s or 30 m/s flows. Comparisons between experimental results and numerical predictions show a good agreement. The competition between acoustic and aerodynamic components is highlighted.

Multiple-Fault Detection Methodology Based on Vibration and Current Analysis Applied to Bearings in Induction Motors and Gearboxes on the Kinematic Chain

Directory of Open Access Journals (Sweden)

Juan Jose Saucedo-Dorantes

2016-01-01

Full Text Available Gearboxes and induction motors are important components in industrial applications and their monitoring condition is critical in the industrial sector so as to reduce costs and maintenance downtimes. There are several techniques associated with the fault diagnosis in rotating machinery; however, vibration and stator currents analysis are commonly used due to their proven reliability. Indeed, vibration and current analysis provide fault condition information by means of the fault-related spectral component identification. This work presents a methodology based on vibration and current analysis for the diagnosis of wear in a gearbox and the detection of bearing defect in an induction motor both linked to the same kinematic chain; besides, the location of the fault-related components for analysis is supported by the corresponding theoretical models. The theoretical models are based on calculation of characteristic gearbox and bearings fault frequencies, in order to locate the spectral components of the faults. In this work, the influence of vibrations over the system is observed by performing motor current signal analysis to detect the presence of faults. The obtained results show the feasibility of detecting multiple faults in a kinematic chain, making the proposed methodology suitable to be used in the application of industrial machinery diagnosis.

Vibrational Characterizations of Zn0.72Li0.28O/Si Thin Films Studied by Fourier Transform Raman Spectroscopy

International Nuclear Information System (INIS)

Myo Myat Thet; Win Kyaw; Yin Maung Maung; Ko Ko Kyaw Soe

2008-03-01

The Zn0.72Li0.28O/Si (x = 0.28mol%) thin layers were fabricated on p-Si(100) substrate with five different process temperature. Vibrational characterizations of those thin films were investigated by FT- Raman spectroscopy. The resulted spectral line characters have been compared with that of Zn0.72Li0.28O/Glass thin films. Some vibrational motions of starting materials and final(candidate) thin films molecules were found in two substrates of glass and Si and vibrational frequencies were assigned by using molecular spectroscopy. Most of the frequencies of starting and final materials were found to be shifted in each of the films of two different substrates.

Nitric oxide kinetics in the afterglow of a diffuse plasma filament

International Nuclear Information System (INIS)

Burnette, D; Montello, A; Adamovich, I V; Lempert, W R

2014-01-01

A suite of laser diagnostics is used to study kinetics of vibrational energy transfer and plasma chemical reactions in a nanosecond pulse, diffuse filament electric discharge and afterglow in N 2 and dry air at 100 Torr. Laser-induced fluorescence of NO and two-photon absorption laser-induced fluorescence of O and N atoms are used to measure absolute, time-resolved number densities of these species after the discharge pulse, and picosecond coherent anti-Stokes Raman spectroscopy is used to measure time-resolved rotational temperature and ground electronic state N 2 (v = 0–4) vibrational level populations. The plasma filament diameter, determined from plasma emission and NO planar laser-induced fluorescence images, remains nearly constant after the discharge pulse, over a few hundred microseconds, and does not exhibit expansion on microsecond time scale. Peak temperature in the discharge and the afterglow is low, T ≈ 370 K, in spite of significant vibrational nonequilibrium, with peak N 2 vibrational temperature of T v  ≈ 2000 K. Significant vibrational temperature rise in the afterglow is likely caused by the downward N 2 –N 2 vibration–vibration (V–V) energy transfer. Simple kinetic modeling of time-resolved N, O, and NO number densities in the afterglow, on the time scale longer compared to relaxation and quenching time of excited species generated in the plasma, is in good agreement with the data. In nitrogen, the N atom density after the discharge pulse is controlled by three-body recombination and radial diffusion. In air, N, NO and O concentrations are dominated by the reverse Zel'dovich reaction, N + NO → N 2  + O, and ozone formation reaction, O + O 2  + M → O 3  + M, respectively. The effect of vibrationally excited nitrogen molecules and excited N atoms on NO formation kinetics is estimated to be negligible. The results suggest that NO formation in the nanosecond pulse discharge is dominated by reactions of

THE CHEMISTRY OF VIBRATIONALLY EXCITED H2 IN THE INTERSTELLAR MEDIUM

International Nuclear Information System (INIS)

Agundez, M.; Roueff, E.; Goicoechea, J. R.; Cernicharo, J.; Faure, A.

2010-01-01

The internal energy available in vibrationally excited H 2 molecules can be used to overcome or diminish the activation barrier of various chemical reactions of interest for molecular astrophysics. In this paper, we investigate in detail the impact on the chemical composition of interstellar clouds of the reactions of vibrationally excited H 2 with C + , He + , O, OH, and CN, based on the available chemical kinetics data. It is found that the reaction of H 2 (v>0) and C + has a profound impact on the abundances of some molecules, especially CH + , which is a direct product and is readily formed in astronomical regions with fractional abundances of vibrationally excited H 2 , relative to the ground state H 2 , in excess of ∼10 -6 , independently of whether the gas is hot or not. The effects of these reactions on the chemical composition of the diffuse clouds ζOph and HD 34078, the dense photon-dominated region (PDR) Orion Bar, the planetary nebula NGC 7027, and the circumstellar disk around the B9 star HD 176386 are investigated through PDR models. We find that formation of CH + is especially favored in dense and highly FUV illuminated regions such as the Orion Bar and the planetary nebula NGC 7027, where column densities in excess of 10 13 cm -2 are predicted. In diffuse clouds, however, this mechanism is found to be not efficient enough to form CH + with a column density close to the values derived from astronomical observations.

An automatic measuring system for mapping of spectral and angular dependence of direct and diffuse solar radiation; Et automatisk maalesystem for kartlegging av vinkel- og spektralfordeling av direkte og diffus solstraaling

Energy Technology Data Exchange (ETDEWEB)

Grandum, Oddbjoern

1997-12-31

In optimizing solar systems, it is necessary to know the spectral and angular dependence of the radiation. The general nonlinear character of most solar energy systems accentuates this. This thesis describes a spectroradiometer that will measure both the direct component of the solar radiation and the angular dependence of the diffuse component. Radiation from a selected part of the sky is transported through a movable set of tube sections on to a stationary set of three monochromators with detectors. The beam transport system may effectively be looked upon as a single long tube aimed at a particular spot in the sky. The half value of the effective opening angle is 1.3{sup o} for diffuse radiation and 2.8{sup o} for direct radiation. The whole measurement process is controlled and operated by a PC and normally runs without manual attention. The instrument is built into a caravan. The thesis describes in detail the experimental apparatus, calibration and measurement accuracies. To map the diffuse radiation, one divides the sky into 26 sectors of equal solid angle. A complete measurement cycle is then made at a random point within each sector. These measurements are modelled by fitting to spherical harmonics, enforcing symmetry around the solar direction and the horizontal plane. The direct radiation is measured separately. Also the circumsolar sector is given special treatment. The measurements are routinely checked against global radiation measured in parallel by a standard pyranometer, and direct solar radiation by a pyrheliometer. An extensive improvement programme is being planned for the instrument, including the use of a photomultiplier tube to measure the UV part of the spectrum, a diode array for the 400-1100 nm range, and use of a Ge diode for the 1000-1900 nm range. 78 refs., 90 figs., 31 tabs.

Variant of multimodal vibration damping of electroviscoelastic structures by appropriate choice of external electric circuit parameters

Directory of Open Access Journals (Sweden)

Dmitrii A. Oshmarin

2016-09-01

Full Text Available In technical applications it takes place the problem of vibration damping in certain regions of the structure, at the location of optical sensors for instance, at any external dynamic excitations with no mass increase and no changes in spectral portrait. In order to solve these problems it is widespread the use of special damping devices: piezoelectric elements connected to external electric circuits and attached to the structure. It became possible due to piezoelectric effect, which provides transformation of part of energy of vibrations into electric one, which is dissipated in external electric circuit. So that by using appropriate electric circuits one may dissipate internal energy and therefore reduce structural vibrations in definite frequency range. As a rule, external circuit of single branch, which shunts single piezoelectric element, allows vibration damping on one certain frequency. Due to the fact, that practical applications usually include requirements of damping of several modes by one and the same technical devices, the problem of multimodal vibration damping in smart-structures is rather acute. The objective of this paper is the study of possibility of vibration damping on several modes by using single external series RL-circuit, connected to electrodes of single piezoelectric element on the basis of solution of problems on natural and forced steady-state vibrations of electroelastic systems with external electric circuits.

Simultaneous measurements of disk vibration and pressure fluctuation in turbulent flow developing in a model hard disk drive

Energy Technology Data Exchange (ETDEWEB)

Kurashima, D.; Naka, Y.; Fukagata, K. [Department of Mechanical Engineering, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan); Obi, S., E-mail: obsn@mech.keio.ac.jp [Department of Mechanical Engineering, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan)

2011-06-15

The complex flow features inside hard disk drive models are investigated in an axisymmetric and a semi-open shroud configurations. For the axisymmetric case, we have employed both experimental and computational approaches. The experiment focuses on both flow dynamics and the disk vibration, where measurements of the fluctuating pressure and velocity are undertaken at some representative points. The correlation between the disk vibration and the fluctuating pressure in the turbulent flow between disks is evident from the spectral analysis. The experimentally observed fluctuating pressure and velocity are partly due to the disk vibration and its contribution could be estimated by comparing the experiment with the results of a large eddy simulation. For the semi-open shroud case, although the characteristic peaks attributable to the large-scale vortical structure are still observed in the power spectra, the pressure fluctuation and the disk vibration are suppressed when the arm is inserted.

A high-resolution, nanomembrane-based, thermal diffusivity biosensor for living cells

KAUST Repository

Elafandy, Rami T.; Ooi, Boon S.

2017-01-01

A method for measuring thermal diffusivity/conductivity of a microscale sample includes placing a metallic disk atop the sample, and disposing a nanomembrane over the sample and over the metallic disk so that the nanomembrane, so that the metallic disk, the nanomembrane and the sample are in thermal equilibrium with one another. A laser beam is directed to fall onto the nanomembrane over the sample, while a radiation sensor is operated to detect photoluminescent radiation emitted by the nanomembrane in response to the laser beam. A spectral shift in the detected photoluminescent radiation emitted by the nanomembrane is determined, and thermal diffusivity/conductivity is calculated from the determined spectral shift of the photoluminescence.

A high-resolution, nanomembrane-based, thermal diffusivity biosensor for living cells

KAUST Repository

El Afandy, Rami Tarek

2017-07-27

A method for measuring thermal diffusivity/conductivity of a microscale sample includes placing a metallic disk atop the sample, and disposing a nanomembrane over the sample and over the metallic disk so that the nanomembrane, so that the metallic disk, the nanomembrane and the sample are in thermal equilibrium with one another. A laser beam is directed to fall onto the nanomembrane over the sample, while a radiation sensor is operated to detect photoluminescent radiation emitted by the nanomembrane in response to the laser beam. A spectral shift in the detected photoluminescent radiation emitted by the nanomembrane is determined, and thermal diffusivity/conductivity is calculated from the determined spectral shift of the photoluminescence.

Crystal structure, vibrational and DFT simulation studies of melaminium dihydrogen phosphite monohydrate

Science.gov (United States)

Arjunan, V.; Kalaivani, M.; Marchewka, M. K.; Mohan, S.

2013-08-01

The crystal structure investigations of melamine with phosphorous acid, namely melaminium dihydrogenphosphite monohydrate (C3N6H7·H2PO3·H2O) have been investigated by means of single crystal X-ray diffraction method. The title compound crystallizes in monoclinic crystal system, and the space group is P21/c with a = 10.069 Å, b = 21.592 Å, c = 12.409 Å and Z = 12. The vibrational assignments and analysis of melaminium dihydrogen phosphite monohydrate have also been performed by FTIR, FT-Raman and far-infrared spectral studies. The quantum chemical simulations were performed with DFT (B3LYP) method using 6-31G**, cc-pVTZ, and 6-311++G** basis sets to determine the energy, structural, thermodynamic parameters and vibrational frequencies of melaminium dihydrogen phosphite monohydrate. The hydrogen atom from phosphorous acid was transferred to the melamine molecule giving the singly protonated melaminium cation. The ability of ions to form spontaneous three-dimensional structure through weak Osbnd H···O and Nsbnd H···O hydrogen bonds shows notable vibrational effects.

Production of a Beam of Highly Vibrationally Excited CO Using Perturbations

Science.gov (United States)

Bartels, N.; Schäfer, T.; Hühnert, J.; Wodtke, A. M.; Field, R. W.

2012-06-01

For many experimentalists (especially those, who are not spectroscopists), molecular pertubations are a curse, as they make assignments and analysis of spectral data more difficult. Nevertheless, they can also be a boon! In this talk we will show how a molecular beam of CO in high vibrational states (v=17,18) can be prepared by an optical pumping scheme that we call PUMP-PUMP-PERTURB and DUMP (P^3D). P^3D exploits the loaning, via spin-orbit perturbations, of the large oscillator strength of the 4th positive system, A ^1 π ← X ^1 Σ ^+, to the triplet manifold. This allows some nominally spin-forbidden transitions to be exploited in multistep optical pumping schemes. The ability to {state-selectively} prepare CO in high vibrational states opens up new opportunities for molecular beam scattering experiments.

Dependence of Exciton Diffusion Length and Diffusion Coefficient on Photophysical Parameters in Bulk Heterojunction Organic Solar Cells

Science.gov (United States)

Yeboah, Douglas; Singh, Jai

2017-11-01

Recently, the dependence of exciton diffusion length (LD ) on some photophysical parameters of organic solids has been experimentally demonstrated, however no systematic theoretical analysis of this phenomenon has been carried out. We have conducted a theoretical study by using the Förster resonance energy transfer and Dexter carrier transfer mechanisms together with the Einstein-Smoluchowski diffusion equation to derive analytical models for the diffusion lengths (LD ) and diffusion coefficients (D) of singlet (S) and triplet (T) excitons in organic solids as functions of spectral overlap integral (J) , photoluminescence (PL) quantum yield (φD ) , dipole moment (μT ) and refractive index (n) of the photoactive material. The exciton diffusion lengths and diffusion coefficients in some selected organic solids were calculated, and we found that the singlet exciton diffusion length (LDS ) increases with φD and J, and decreases with n. Also, the triplet exciton diffusion length (LDT ) increases with φD and decreases with μT . These may be achieved through doping the organic solids into broad optical energy gap host materials as observed in previous experiments. The calculated exciton diffusion lengths are compared with experimental values and a reasonably good agreement is found between them. The results presented are expected to provide insight relevant to the synthesis of new organic solids for fabrication of bulk heterojunction organic solar cells characterized by better power conversion efficiency.

Directional and Spectral Irradiance in Ocean Models: Effects on Simulated Global Phytoplankton, Nutrients, and Primary Production

Science.gov (United States)

Gregg, Watson W.; Rousseaux, Cecile S.

2016-01-01

The importance of including directional and spectral light in simulations of ocean radiative transfer was investigated using a coupled biogeochemical-circulation-radiative model of the global oceans. The effort focused on phytoplankton abundances, nutrient concentrations and vertically-integrated net primary production. The importance was approached by sequentially removing directional (i.e., direct vs. diffuse) and spectral irradiance and comparing results of the above variables to a fully directionally and spectrally-resolved model. In each case the total irradiance was kept constant; it was only the pathways and spectral nature that were changed. Assuming all irradiance was diffuse had negligible effect on global ocean primary production. Global nitrate and total chlorophyll concentrations declined by about 20% each. The largest changes occurred in the tropics and sub-tropics rather than the high latitudes, where most of the irradiance is already diffuse. Disregarding spectral irradiance had effects that depended upon the choice of attenuation wavelength. The wavelength closest to the spectrally-resolved model, 500 nm, produced lower nitrate (19%) and chlorophyll (8%) and higher primary production (2%) than the spectral model. Phytoplankton relative abundances were very sensitive to the choice of non-spectral wavelength transmittance. The combined effects of neglecting both directional and spectral irradiance exacerbated the differences, despite using attenuation at 500 nm. Global nitrate decreased 33% and chlorophyll decreased 24%. Changes in phytoplankton community structure were considerable, representing a change from chlorophytes to cyanobacteria and coccolithophores. This suggested a shift in community function, from light-limitation to nutrient limitation: lower demands for nutrients from cyanobacteria and coccolithophores favored them over the more nutrient-demanding chlorophytes. Although diatoms have the highest nutrient demands in the model, their

Application of pattern recognition techniques to the detection of the Phenix reactor control rods vibrations

International Nuclear Information System (INIS)

Zwingelstein, G.; Deat, M.; Le Guillou, G.

1979-01-01

The incipient detection of control rods vibrations is very important for the safety of the operating plants. This detection can be achieved by an analysis of the peaks of the power spectrum density of the neutron noise. Pattern Recognition techniques were applied to detect the rod vibrations which occured at the fast breeder Phenix (250MWe). In the first part we give a description of the basic pattern which is used to characterize the behavior of the plant. The pattern is considered as column vector in n dimensional Euclidian space where the components are the samples of the power spectral density of the neutron noise. In the second part, a recursive learning procedure of the normal patterns which provides the mean and the variance of the estimates is described. In the third part the classification problem has been framed in terms of a partitioning procedure in n dimensional space which encloses regions corresponding to normal operations. This pattern recognition scheme was applied to the detection of rod vibrations with neutron data collected at the Phenix site before and after occurence of the vibrations. The analysis was carried out with a 42-dimensional measurement space. The learned pattern was estimated with 150 measurement vectors which correspond to the period without vibrations. The efficiency of the surveillance scheme is then demonstrated by processing separately 119 measurement vectors recorded during the rod vibration period

Estimation and analysis of spectral solar radiation over Cairo

International Nuclear Information System (INIS)

Abdel Wahab, M.M.; Omran, M.

1994-05-01

This work presents a methodology to estimate spectral diffuse and global radiation on horizontal surface. This method is validated by comparing with measured direct and global spectral radiation in four bands. The results show a good performance in cloudless conditions. The analysis of the ratio of surface values to extraterrestrial ones revealed an over-all depletion in the summer months. Also there was no evidence for any tendency for conversion of radiational components through different bands. The model presents excellent agreement with the measured values for (UV/G) ratio. (author). 7 refs, 4 figs, 3 tabs

Dependence of Moessbauer resonance intensities on vibrational lattice anisotropy in case of an axial electric field gradient

International Nuclear Information System (INIS)

Friedt, J.M.

1976-01-01

The change in the hyperfine line intensities is discussed for various Moessbauer transitions in cases involving axial vibrational lattice anisotropy and axial electric field gradient at the resonant nucleus. The change in the relative intensities of the spectral components has been calculed numerically for the different types of Moessbauer transitions. Polynomial expansions are given to describe the functional dependence of the relative intensities on the magnitude of the vibration anisotropy. They may be used to extract the relevant parameters from experimental data without requiring the numerical integrations implied in the description of the Goldanskii-Karyagin effect [fr

Vibration mixer

Energy Technology Data Exchange (ETDEWEB)

Alekhin, S.A.; Chernov, V.S.; Denisenko, V.V.; Gorodnyanskiy, I.F.; Prokopov, L.I.; Tikhonov, Yu.P.

1983-01-01

The vibration mixer is proposed which contains a housing, vibration drive with rod installed in the upper part of the mixing mechanism made in the form of a hollow shaft with blades. In order to improve intensity of mixing and dispersion of the mud, the shaft with the blades is arranged on the rod of the vibrator and is equipped with a cam coupling whose drive disc is attached to the vibration rod. The rod is made helical, while the drive disc of the cam coupling is attached to the helical surface of the rod. In addition, the vibration mixer is equipped with perforated discs installed on the ends of the rods.

Vibration and acoustic frequency spectra for industrial process modeling using selective fusion multi-condition samples and multi-source features

Science.gov (United States)

Tang, Jian; Qiao, Junfei; Wu, ZhiWei; Chai, Tianyou; Zhang, Jian; Yu, Wen

2018-01-01

Frequency spectral data of mechanical vibration and acoustic signals relate to difficult-to-measure production quality and quantity parameters of complex industrial processes. A selective ensemble (SEN) algorithm can be used to build a soft sensor model of these process parameters by fusing valued information selectively from different perspectives. However, a combination of several optimized ensemble sub-models with SEN cannot guarantee the best prediction model. In this study, we use several techniques to construct mechanical vibration and acoustic frequency spectra of a data-driven industrial process parameter model based on selective fusion multi-condition samples and multi-source features. Multi-layer SEN (MLSEN) strategy is used to simulate the domain expert cognitive process. Genetic algorithm and kernel partial least squares are used to construct the inside-layer SEN sub-model based on each mechanical vibration and acoustic frequency spectral feature subset. Branch-and-bound and adaptive weighted fusion algorithms are integrated to select and combine outputs of the inside-layer SEN sub-models. Then, the outside-layer SEN is constructed. Thus, "sub-sampling training examples"-based and "manipulating input features"-based ensemble construction methods are integrated, thereby realizing the selective information fusion process based on multi-condition history samples and multi-source input features. This novel approach is applied to a laboratory-scale ball mill grinding process. A comparison with other methods indicates that the proposed MLSEN approach effectively models mechanical vibration and acoustic signals.

Quantitative measurement of water diffusion lifetimes at a protein/DNA interface by NMR

International Nuclear Information System (INIS)

Gruschus, James M.; Ferretti, James A.

2001-01-01

Hydration site lifetimes of slowly diffusing water molecules at the protein/DNA interface of the vnd/NK-2 homeodomain DNA complex were determined using novel three-dimensional NMR techniques. The lifetimes were calculated using the ratios of ROE and NOE cross-relaxation rates between the water and the protein backbone and side chain amides. This calculation of the lifetimes is based on a model of the spectral density function of the water-protein interaction consisting of three timescales of motion: fast vibrational/rotational motion, diffusion into/out of the hydration site, and overall macromolecular tumbling. The lifetimes measured ranged from approximately 400 ps to more than 5 ns, and nearly all the slowly diffusing water molecules detected lie at the protein/DNA interface. A quantitative analysis of relayed water cross-relaxation indicated that even at very short mixing times, 5 ms for ROESY and 12 ms for NOESY, relay of magnetization can make a small but detectable contribution to the measured rates. The temperature dependences of the NOE rates were measured to help discriminate direct dipolar cross-relaxation from chemical exchange. Comparison with several X-ray structures of homeodomain/DNA complexes reveals a strong correspondence between water molecules in conserved locations and the slowly diffusing water molecules detected by NMR. A homology model based on the X-ray structures was created to visualize the conserved water molecules detected at the vnd/NK-2 homeodomain DNA interface. Two chains of water molecules are seen at the right and left sides of the major groove, adjacent to the third helix of the homeodomain. Two water-mediated hydrogen bond bridges spanning the protein/DNA interface are present in the model, one between the backbone of Phe8 and a DNA phosphate, and one between the side chain of Asn51 and a DNA phosphate. The hydrogen bond bridge between Asn51 and the DNA might be especially important since the DNA contact made by the invariant

Vibration spectra of single atomic nanocontacts

International Nuclear Information System (INIS)

Bourahla, B; Khater, A; Rafil, O; Tigrine, R

2006-01-01

This paper introduces a simple model for an atomic nanocontact, where its mechanical properties are analysed by calculating numerically the local spectral properties at the contact atom and the nearby atoms. The standard methodology for calculating phonon spectral densities is extended to enable the calculation of localized contact modes and local density of states (DOS). The model system considered for the nanocontact consists of two sets of triple parallel semi-infinite atomic chains joined by a single atom in between. The matching method is used, in the harmonic approximation, to calculate the local Green's functions for the irreducible set of sites that constitute the inhomogeneous nanocontact domain. The Green's functions yield the vibration spectra and the DOS for the atomic sites. These are numerically calculated for different cases of elastic hardening and softening of the nanocontact domain. The purpose is to investigate how the local dynamics respond to local changes in the elastic environment. The analysis of the spectra and of the DOS identifies characteristic features and demonstrates the central role of a core subset of these sites for the dynamics of the nanocontact. The system models a situation which may be appropriate for contact atomic force microscopy

Optical fiber grating vibration sensor for vibration monitoring of hydraulic pump

Science.gov (United States)

Zhang, Zhengyi; Liu, Chuntong; Li, Hongcai; He, Zhenxin; Zhao, Xiaofeng

2017-06-01

In view of the existing electrical vibration monitoring traditional hydraulic pump vibration sensor, the high false alarm rate is susceptible to electromagnetic interference and is not easy to achieve long-term reliable monitoring, based on the design of a beam of the uniform strength structure of the fiber Bragg grating (FBG) vibration sensor. In this paper, based on the analysis of the vibration theory of the equal strength beam, the principle of FBG vibration tuning based on the equal intensity beam is derived. According to the practical application of the project, the structural dimensions of the equal strength beam are determined, and the optimization design of the vibrator is carried out. The finite element analysis of the sensor is carried out by ANSYS, and the first order resonant frequency is 94.739 Hz. The vibration test of the sensor is carried out by using the vibration frequency of 35 Hz and the vibration source of 50 Hz. The time domain and frequency domain analysis results of test data show that the sensor has good dynamic response characteristics, which can realize the accurate monitoring of the vibration frequency and meet the special requirements of vibration monitoring of hydraulic pump under specific environment.

Semiconductor Laser Multi-Spectral Sensing and Imaging

Directory of Open Access Journals (Sweden)

Han Q. Le

2010-01-01

Full Text Available Multi-spectral laser imaging is a technique that can offer a combination of the laser capability of accurate spectral sensing with the desirable features of passive multispectral imaging. The technique can be used for detection, discrimination, and identification of objects by their spectral signature. This article describes and reviews the development and evaluation of semiconductor multi-spectral laser imaging systems. Although the method is certainly not specific to any laser technology, the use of semiconductor lasers is significant with respect to practicality and affordability. More relevantly, semiconductor lasers have their own characteristics; they offer excellent wavelength diversity but usually with modest power. Thus, system design and engineering issues are analyzed for approaches and trade-offs that can make the best use of semiconductor laser capabilities in multispectral imaging. A few systems were developed and the technique was tested and evaluated on a variety of natural and man-made objects. It was shown capable of high spectral resolution imaging which, unlike non-imaging point sensing, allows detecting and discriminating objects of interest even without a priori spectroscopic knowledge of the targets. Examples include material and chemical discrimination. It was also shown capable of dealing with the complexity of interpreting diffuse scattered spectral images and produced results that could otherwise be ambiguous with conventional imaging. Examples with glucose and spectral imaging of drug pills were discussed. Lastly, the technique was shown with conventional laser spectroscopy such as wavelength modulation spectroscopy to image a gas (CO. These results suggest the versatility and power of multi-spectral laser imaging, which can be practical with the use of semiconductor lasers.

Semiconductor laser multi-spectral sensing and imaging.

Science.gov (United States)

Le, Han Q; Wang, Yang

2010-01-01

Multi-spectral laser imaging is a technique that can offer a combination of the laser capability of accurate spectral sensing with the desirable features of passive multispectral imaging. The technique can be used for detection, discrimination, and identification of objects by their spectral signature. This article describes and reviews the development and evaluation of semiconductor multi-spectral laser imaging systems. Although the method is certainly not specific to any laser technology, the use of semiconductor lasers is significant with respect to practicality and affordability. More relevantly, semiconductor lasers have their own characteristics; they offer excellent wavelength diversity but usually with modest power. Thus, system design and engineering issues are analyzed for approaches and trade-offs that can make the best use of semiconductor laser capabilities in multispectral imaging. A few systems were developed and the technique was tested and evaluated on a variety of natural and man-made objects. It was shown capable of high spectral resolution imaging which, unlike non-imaging point sensing, allows detecting and discriminating objects of interest even without a priori spectroscopic knowledge of the targets. Examples include material and chemical discrimination. It was also shown capable of dealing with the complexity of interpreting diffuse scattered spectral images and produced results that could otherwise be ambiguous with conventional imaging. Examples with glucose and spectral imaging of drug pills were discussed. Lastly, the technique was shown with conventional laser spectroscopy such as wavelength modulation spectroscopy to image a gas (CO). These results suggest the versatility and power of multi-spectral laser imaging, which can be practical with the use of semiconductor lasers.

Vibrational spectroscopic studies of Isoleucine by quantum chemical calculations.

Science.gov (United States)

Moorthi, P P; Gunasekaran, S; Ramkumaar, G R

2014-04-24

In this work, we reported a combined experimental and theoretical study on molecular structure, vibrational spectra and NBO analysis of Isoleucine (2-Amino-3-methylpentanoic acid). The optimized molecular structure, vibrational frequencies, corresponding vibrational assignments, thermodynamics properties, NBO analyses, NMR chemical shifts and ultraviolet-visible spectral interpretation of Isoleucine have been studied by performing MP2 and DFT/cc-pVDZ level of theory. The FTIR, FT-Raman spectra were recorded in the region 4000-400 cm(-1) and 3500-50 cm(-1) respectively. The UV-visible absorption spectra of the compound were recorded in the range of 200-800 nm. Computational calculations at MP2 and B3LYP level with basis set of cc-pVDZ is employed in complete assignments of Isoleucine molecule on the basis of the potential energy distribution (PED) of the vibrational modes, calculated using VEDA-4 program. The calculated wavenumbers are compared with the experimental values. The difference between the observed and calculated wavenumber values of most of the fundamentals is very small. (13)C and (1)H nuclear magnetic resonance chemical shifts of the molecule were calculated using the gauge independent atomic orbital (GIAO) method and compared with experimental results. The formation of hydrogen bond was investigated in terms of the charge density by the NBO calculations. Based on the UV spectra and TD-DFT calculations, the electronic structure and the assignments of the absorption bands were carried out. Besides, molecular electrostatic potential (MEP) were investigated using theoretical calculations. Copyright © 2014 Elsevier B.V. All rights reserved.

Predicting Soil Organic Carbon at Field Scale Using a National Soil Spectral Library

DEFF Research Database (Denmark)

Peng, Yi; Knadel, Maria; Gislum, René

2013-01-01

and the spectral library, 2718 samples) and (iii) three sub-sets selected from the spectral library. In an attempt to improve prediction accuracy, sub-sets of the soil spectral library were made using three different sample selection methods: those geographically closest (84 samples), those with the same landscape......Visible and near infrared diffuse reflectance (vis-NIR) spectroscopy is a low-cost, efficient and accurate soil analysis technique and is thus becoming increasingly popular. Soil spectral libraries are commonly constructed as the basis for estimating soil texture and properties. In this study......, partial least squares regression was used to develop models to predict the soil organic carbon (SOC) content of 35 soil samples from one field using (i) the Danish soil spectral library (2688 samples), (ii) a spiked spectral library (a combination of 30 samples selected from the local area...

Advances in molecular vibrations and collision dynamics molecular clusters

CERN Document Server

Bacic, Zatko

1998-01-01

This volume focuses on molecular clusters, bound by van der Waals interactions and hydrogen bonds. Twelve chapters review a wide range of recent theoretical and experimental advances in the areas of cluster vibrations, spectroscopy, and reaction dynamics. The authors are leading experts, who have made significant contributions to these topics.The first chapter describes exciting results and new insights in the solvent effects on the short-time photo fragmentation dynamics of small molecules, obtained by combining heteroclusters with femtosecond laser excitation. The second is on theoretical work on effects of single solvent (argon) atom on the photodissociation dynamics of the solute H2O molecule. The next two chapters cover experimental and theoretical aspects of the energetics and vibrations of small clusters. Chapter 5 describes diffusion quantum Monte Carlo calculations and non additive three-body potential terms in molecular clusters. The next six chapters deal with hydrogen-bonded clusters, refle...

The spectral analysis of cyclo-non-stationary signals

Science.gov (United States)

Abboud, D.; Baudin, S.; Antoni, J.; Rémond, D.; Eltabach, M.; Sauvage, O.

2016-06-01

Condition monitoring of rotating machines in speed-varying conditions remains a challenging task and an active field of research. Specifically, the produced vibrations belong to a particular class of non-stationary signals called cyclo-non-stationary: although highly non-stationary, they contain hidden periodicities related to the shaft angle; the phenomenon of long term modulations is what makes them different from cyclostationary signals which are encountered under constant speed regimes. In this paper, it is shown that the optimal way of describing cyclo-non-stationary signals is jointly in the time and the angular domains. While the first domain describes the waveform characteristics related to the system dynamics, the second one reveals existing periodicities linked to the system kinematics. Therefore, a specific class of signals - coined angle-time cyclostationary is considered, expressing the angle-time interaction. Accordingly, the related spectral representations, the order-frequency spectral correlation and coherence functions are proposed and their efficiency is demonstrated on two industrial cases.

2D heterodyne-detected sum frequency generation study on the ultrafast vibrational dynamics of H{sub 2}O and HOD water at charged interfaces

Energy Technology Data Exchange (ETDEWEB)

Inoue, Ken-ichi; Singh, Prashant C. [Molecular Spectroscopy Laboratory, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Nihonyanagi, Satoshi; Tahara, Tahei, E-mail: tahei@riken.jp [Molecular Spectroscopy Laboratory, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Ultrafast Spectroscopy Research Team, RIKEN Center for Advanced Photonics, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Yamaguchi, Shoichi [Molecular Spectroscopy Laboratory, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Department of Applied Chemistry, Saitama University, 255 Shimo-Okubo, Saitama 338-8570 (Japan)

2015-06-07

Two-dimensional heterodyne-detected vibrational sum-frequency generation (2D HD-VSFG) spectroscopy is applied to study the ultrafast vibrational dynamics of water at positively charged aqueous interfaces, and 2D HD-VSFG spectra of cetyltrimethylammonium bromide (CTAB)/water interfaces in the whole hydrogen-bonded OH stretch region (3000 cm{sup −1} ≤ ω{sub pump} ≤ 3600 cm{sup −1}) are measured. 2D HD-VSFG spectrum of the CTAB/isotopically diluted water (HOD-D{sub 2}O) interface exhibits a diagonally elongated bleaching lobe immediately after excitation, which becomes round with a time constant of ∼0.3 ps due to spectral diffusion. In contrast, 2D HD-VSFG spectrum of the CTAB/H{sub 2}O interface at 0.0 ps clearly shows two diagonal peaks and their cross peaks in the bleaching region, corresponding to the double peaks observed at 3230 cm{sup −1} and 3420 cm{sup −1} in the steady-state HD-VSFG spectrum. Horizontal slices of the 2D spectrum show that the relative intensity of the two peaks of the bleaching at the CTAB/H{sub 2}O interface gradually change with the change of the pump frequency. We simulate the pump-frequency dependence of the bleaching feature using a model that takes account of the Fermi resonance and inhomogeneity of the OH stretch vibration, and the simulated spectra reproduce the essential features of the 2D HD-VSFG spectra of the CTAB/H{sub 2}O interface. The present study demonstrates that heterodyne detection of the time-resolved VSFG is critically important for studying the ultrafast dynamics of water interfaces and for unveiling the underlying mechanism.

The peculiarities of spectral manifestations of high-voltage electric discharge in different phase states of ion systems.

Science.gov (United States)

Gafurov, M M; Aliev, A R; Ataev, M B; Rabadanov, K Sh

2013-10-01

The effects of high-voltage pulsed discharge (HVPD activation) on vibrational spectra of ion salt systems have been studied. The peculiarities of spectral display of HVPD in ion melts and aqueous solutions of electrolytes, in ion-conducting phases of crystalline and glassy salt systems have been investigated. After HVPD a salt system is in non-equilibrium activated state. In the activated state of a salt system, the relaxation time of the vibrational excited states of molecular ions is shorter than in the equilibrium state if the vibrational relaxation rate increases with temperature in the system. For those systems for which the relaxation rate decreases at elevated temperatures, the relaxation time of the vibrational excited states of molecular ions is longer than in the equilibrium state. HVPD activation of a salt system can change the configuration of the electron shell of molecular ions. Therefore, the lifetime values of activated state of salt systems are abnormally large. Copyright © 2013 Elsevier B.V. All rights reserved.

Tool-specific performance of vibration-reducing gloves for attenuating fingers-transmitted vibration

Science.gov (United States)

Welcome, Daniel E.; Dong, Ren G.; Xu, Xueyan S.; Warren, Christopher; McDowell, Thomas W.

2016-01-01

BACKGROUND Fingers-transmitted vibration can cause vibration-induced white finger. The effectiveness of vibration-reducing (VR) gloves for reducing hand transmitted vibration to the fingers has not been sufficiently examined. OBJECTIVE The objective of this study is to examine tool-specific performance of VR gloves for reducing finger-transmitted vibrations in three orthogonal directions (3D) from powered hand tools. METHODS A transfer function method was used to estimate the tool-specific effectiveness of four typical VR gloves. The transfer functions of the VR glove fingers in three directions were either measured in this study or during a previous study using a 3D laser vibrometer. More than seventy vibration spectra of various tools or machines were used in the estimations. RESULTS When assessed based on frequency-weighted acceleration, the gloves provided little vibration reduction. In some cases, the gloves amplified the vibration by more than 10%, especially the neoprene glove. However, the neoprene glove did the best when the assessment was based on unweighted acceleration. The neoprene glove was able to reduce the vibration by 10% or more of the unweighted vibration for 27 out of the 79 tools. If the dominant vibration of a tool handle or workpiece was in the shear direction relative to the fingers, as observed in the operation of needle scalers, hammer chisels, and bucking bars, the gloves did not reduce the vibration but increased it. CONCLUSIONS This study confirmed that the effectiveness for reducing vibration varied with the gloves and the vibration reduction of each glove depended on tool, vibration direction to the fingers, and finger location. VR gloves, including certified anti-vibration gloves do not provide much vibration reduction when judged based on frequency-weighted acceleration. However, some of the VR gloves can provide more than 10% reduction of the unweighted vibration for some tools or workpieces. Tools and gloves can be matched for

Detector point of view of reactor internal vibrations under Gaussian coloured random forces - the problem of fitting neutron noise experimental data

International Nuclear Information System (INIS)

Arnal, R.S.; Martin, G.V.; Gonzalez, J.L.M.-C.

1988-01-01

This paper studies the local vibrations of reactor components driven by Gaussian coloured and white forces, when nonlinear vibrations arise. We study also the important problem of noise sources, modelization and the noise propagation through the neutron field using the discrete ordinates transport theory. Finally, we study the effect of the neutron field upon the PSD (power spectral density) of the noise source and we analyse the problem of fitting neutron noise experimental data to perform pattern recognition analysis. (author)

Dispersion-corrected first-principles calculation of terahertz vibration, and evidence for weak hydrogen bond formation

Science.gov (United States)

Takahashi, Masae; Ishikawa, Yoichi; Ito, Hiromasa

2013-03-01

A weak hydrogen bond (WHB) such as CH-O is very important for the structure, function, and dynamics in a chemical and biological system WHB stretching vibration is in a terahertz (THz) frequency region Very recently, the reasonable performance of dispersion-corrected first-principles to WHB has been proven. In this lecture, we report dispersion-corrected first-principles calculation of the vibrational absorption of some organic crystals, and low-temperature THz spectral measurement, in order to clarify WHB stretching vibration. The THz frequency calculation of a WHB crystal has extremely improved by dispersion correction. Moreover, the discrepancy in frequency between an experiment and calculation and is 10 1/cm or less. Dispersion correction is especially effective for intermolecular mode. The very sharp peak appearing at 4 K is assigned to the intermolecular translational mode that corresponds to WHB stretching vibration. It is difficult to detect and control the WHB formation in a crystal because the binding energy is very small. With the help of the latest intense development of experimental and theoretical technique and its careful use, we reveal solid-state WHB stretching vibration as evidence for the WHB formation that differs in respective WHB networks The research was supported by the Ministry of Education, Culture, Sports, Science and Technology of Japan (Grant No. 22550003).

Multidomain spectral solution of compressible viscous flows

International Nuclear Information System (INIS)

Kopriva, D.A.

1994-01-01

We develop a nonoverlapping mutidomain spectral collocation method to solve compressible viscous flows. At the interfaces, the advection terms are treated with a characteristic correction method. The diffusion terms are treated with a penalty method. Spectral accuracy is demonstrated on linear model problems in one and two space dimensions. The method is applied to a subsonic and supersonic flow over a flat plate. The results are compared to solutions of the boundary-layer equations which show that two digit accuracy in the adiabatic plate temperature is obtained with 16 points in the boundary layer for a freestream Mach number of two. A second application is to a transonic flow in a two-dimensional converging-diverging nozzle, where the computed results are compared to experimental data

THE POSSIBLE INTERSTELLAR ANION CH2CN–: SPECTROSCOPIC CONSTANTS, VIBRATIONAL FREQUENCIES, AND OTHER CONSIDERATIONS

International Nuclear Information System (INIS)

Fortenberry, Ryan C.; Lee, Timothy J.; Crawford, T. Daniel

2013-01-01

The A 1 B 1 ⇽ X-tilde 1 A' excitation into the dipole-bound state of the cyanomethyl anion (CH 2 CN – ) has been hypothesized as the carrier for one diffuse interstellar band. However, this particular molecular system has not been detected in the interstellar medium even though the related cyanomethyl radical and the isoelectronic ketenimine molecule have been found. In this study, we are employing the use of proven quartic force fields and second-order vibrational perturbation theory to compute accurate spectroscopic constants and fundamental vibrational frequencies for X-tilde 1 A' CH 2 CN – in order to assist in laboratory studies and astronomical observations.

The Possible Interstellar Anion CH2CN-: Spectroscopic Constants, Vibrational Frequencies, and Other Considerations

Science.gov (United States)

Fortenberry, Ryan C.; Crawford, T. Daniel; Lee, Timothy J.

2013-01-01

The A\\ ^1B_1 \\leftarrow \\tilde{X}\\ ^1A^{\\prime } excitation into the dipole-bound state of the cyanomethyl anion (CH2CN-) has been hypothesized as the carrier for one diffuse interstellar band. However, this particular molecular system has not been detected in the interstellar medium even though the related cyanomethyl radical and the isoelectronic ketenimine molecule have been found. In this study, we are employing the use of proven quartic force fields and second-order vibrational perturbation theory to compute accurate spectroscopic constants and fundamental vibrational frequencies for \\tilde{X}\\ ^1A^{\\prime } CH2CN- in order to assist in laboratory studies and astronomical observations.

Theory of vibration protection

CERN Document Server

Karnovsky, Igor A

2016-01-01

This text is an advancement of the theory of vibration protection of mechanical systems with lumped and distributed parameters. The book offers various concepts and methods of solving vibration protection problems, discusses the advantages and disadvantages of different methods, and the fields of their effective applications. Fundamental approaches of vibration protection, which are considered in this book, are the passive, parametric and optimal active vibration protection. The passive vibration protection is based on vibration isolation, vibration damping and dynamic absorbers. Parametric vibration protection theory is based on the Shchipanov-Luzin invariance principle. Optimal active vibration protection theory is based on the Pontryagin principle and the Krein moment method. The book also contains special topics such as suppression of vibrations at the source of their occurrence and the harmful influence of vibrations on humans. Numerous examples, which illustrate the theoretical ideas of each chapter, ar...

Vibration of machine

International Nuclear Information System (INIS)

Kwak, Mun Gyu; Na, Sung Su; Baek, Gwang Hyeon; Song, Chul Gi; Han, Sang Bo

2001-09-01

This book deals with vibration of machine which gives descriptions of free vibration using SDOF system, forced vibration using SDOF system, vibration of multi-degree of freedom system like introduction and normal form, distribution system such as introduction, free vibration of bar and practice problem, approximate solution like lumped approximations and Raleigh's quotient, engineering by intuition and experience, real problem and experimental method such as technology of signal, fourier transform analysis, frequency analysis and sensor and actuator.

Fault feature extraction of planet gear in wind turbine gearbox based on spectral kurtosis and time wavelet energy spectrum

Science.gov (United States)

Kong, Yun; Wang, Tianyang; Li, Zheng; Chu, Fulei

2017-09-01

Planetary transmission plays a vital role in wind turbine drivetrains, and its fault diagnosis has been an important and challenging issue. Owing to the complicated and coupled vibration source, time-variant vibration transfer path, and heavy background noise masking effect, the vibration signal of planet gear in wind turbine gearboxes exhibits several unique characteristics: Complex frequency components, low signal-to-noise ratio, and weak fault feature. In this sense, the periodic impulsive components induced by a localized defect are hard to extract, and the fault detection of planet gear in wind turbines remains to be a challenging research work. Aiming to extract the fault feature of planet gear effectively, we propose a novel feature extraction method based on spectral kurtosis and time wavelet energy spectrum (SK-TWES) in the paper. Firstly, the spectral kurtosis (SK) and kurtogram of raw vibration signals are computed and exploited to select the optimal filtering parameter for the subsequent band-pass filtering. Then, the band-pass filtering is applied to extrude periodic transient impulses using the optimal frequency band in which the corresponding SK value is maximal. Finally, the time wavelet energy spectrum analysis is performed on the filtered signal, selecting Morlet wavelet as the mother wavelet which possesses a high similarity to the impulsive components. The experimental signals collected from the wind turbine gearbox test rig demonstrate that the proposed method is effective at the feature extraction and fault diagnosis for the planet gear with a localized defect.

EFFET DU GETTERING SUR LA LONGUEUR DE DIFFUSION DES PLAQUETTES DE SILICIUM SEMICRISTALLIN "SOPLIN"

Directory of Open Access Journals (Sweden)

A MOUHOUB

2003-06-01

Full Text Available L’effet des diffusions du phosphore à haute température (T = 900°C sur la longueur de diffusion (Ln des plaquettes de silicium semicristallin SOPLIN (SOlidification by PLanar INterface est déterminé par la mesure de la réponse spectrale de la photopile réalisée sur le matériau traité. L’influence de ces recuits sur les paramètres photovoltaïques est enregistrée dans les caractéristiques courant - tension sous éclairement simulé et la réponse spectrale.

Mathematical analysis and numerical simulation of patterns in fractional and classical reaction-diffusion systems

International Nuclear Information System (INIS)

Owolabi, Kolade M.

2016-01-01

The aim of this paper is to examine pattern formation in the sub— and super-diffusive scenarios and compare it with that of classical or standard diffusive processes in two-component fractional reaction-diffusion systems that modeled a predator-prey dynamics. The focus of the work concentrates on the use of two separate mathematical techniques, we formulate a Fourier spectral discretization method as an efficient alternative technique to solve fractional reaction-diffusion problems in higher-dimensional space, and later advance the resulting systems of ODEs in time with the adaptive exponential time-differencing solver. Obviously, the fractional Fourier approach is able to achieve spectral convergence up to machine precision regardless of the fractional order α, owing to the fact that our approach is able to give full diagonal representation of the fractional operator. The complexity of the dynamics in this system is theoretically discussed and graphically displayed with some examples and numerical simulations in one, two and three dimensions.

A Review of Hybrid Fiber-Optic Distributed Simultaneous Vibration and Temperature Sensing Technology and Its Geophysical Applications

Directory of Open Access Journals (Sweden)

Khalid Miah

2017-11-01

Full Text Available Distributed sensing systems can transform an optical fiber cable into an array of sensors, allowing users to detect and monitor multiple physical parameters such as temperature, vibration and strain with fine spatial and temporal resolution over a long distance. Fiber-optic distributed acoustic sensing (DAS and distributed temperature sensing (DTS systems have been developed for various applications with varied spatial resolution, and spectral and sensing range. Rayleigh scattering-based phase optical time domain reflectometry (OTDR for vibration and Raman/Brillouin scattering-based OTDR for temperature and strain measurements have been developed over the past two decades. The key challenge has been to find a methodology that would enable the physical parameters to be determined at any point along the sensing fiber with high sensitivity and spatial resolution, yet within acceptable frequency range for dynamic vibration, and temperature detection. There are many applications, especially in geophysical and mining engineering where simultaneous measurements of vibration and temperature are essential. In this article, recent developments of different hybrid systems for simultaneous vibration, temperature and strain measurements are analyzed based on their operation principles and performance. Then, challenges and limitations of the systems are highlighted for geophysical applications.

A Review of Hybrid Fiber-Optic Distributed Simultaneous Vibration and Temperature Sensing Technology and Its Geophysical Applications.

Science.gov (United States)

Miah, Khalid; Potter, David K

2017-11-01

Distributed sensing systems can transform an optical fiber cable into an array of sensors, allowing users to detect and monitor multiple physical parameters such as temperature, vibration and strain with fine spatial and temporal resolution over a long distance. Fiber-optic distributed acoustic sensing (DAS) and distributed temperature sensing (DTS) systems have been developed for various applications with varied spatial resolution, and spectral and sensing range. Rayleigh scattering-based phase optical time domain reflectometry (OTDR) for vibration and Raman/Brillouin scattering-based OTDR for temperature and strain measurements have been developed over the past two decades. The key challenge has been to find a methodology that would enable the physical parameters to be determined at any point along the sensing fiber with high sensitivity and spatial resolution, yet within acceptable frequency range for dynamic vibration, and temperature detection. There are many applications, especially in geophysical and mining engineering where simultaneous measurements of vibration and temperature are essential. In this article, recent developments of different hybrid systems for simultaneous vibration, temperature and strain measurements are analyzed based on their operation principles and performance. Then, challenges and limitations of the systems are highlighted for geophysical applications.

The separation of vibrational coherence from ground- and excited-electronic states in P3HT film

KAUST Repository

Song, Yin

2015-06-07

© 2015 AIP Publishing LLC. Concurrence of the vibrational coherence and ultrafast electron transfer has been observed in polymer/fullerene blends. However, it is difficult to experimentally investigate the role that the excited-state vibrational coherence plays during the electron transfer process since vibrational coherence from the ground- and excited-electronic states is usually temporally and spectrally overlapped. Here, we performed 2-dimensional electronic spectroscopy (2D ES) measurements on poly(3-hexylthiophene) (P3HT) films. By Fourier transforming the whole 2D ES datasets (S (λ 1, T∼ 2, λ 3)) along the population time (T∼ 2) axis, we develop and propose a protocol capable of separating vibrational coherence from the ground- and excited-electronic states in 3D rephasing and nonrephasing beating maps (S (λ 1, ν∼ 2, λ 3)). We found that the vibrational coherence from pure excited electronic states appears at positive frequency (+ ν∼ 2) in the rephasing beating map and at negative frequency (- ν∼ 2) in the nonrephasing beating map. Furthermore, we also found that vibrational coherence from excited electronic state had a long dephasing time of 244 fs. The long-lived excited-state vibrational coherence indicates that coherence may be involved in the electron transfer process. Our findings not only shed light on the mechanism of ultrafast electron transfer in organic photovoltaics but also are beneficial for the study of the coherence effect on photoexcited dynamics in other systems.

The separation of vibrational coherence from ground- and excited-electronic states in P3HT film

International Nuclear Information System (INIS)

Song, Yin; Hellmann, Christoph; Stingelin, Natalie; Scholes, Gregory D.

2015-01-01

Concurrence of the vibrational coherence and ultrafast electron transfer has been observed in polymer/fullerene blends. However, it is difficult to experimentally investigate the role that the excited-state vibrational coherence plays during the electron transfer process since vibrational coherence from the ground- and excited-electronic states is usually temporally and spectrally overlapped. Here, we performed 2-dimensional electronic spectroscopy (2D ES) measurements on poly(3-hexylthiophene) (P3HT) films. By Fourier transforming the whole 2D ES datasets (S(λ 1 ,T ~ 2 ,λ 3 )) along the population time (T ~ 2 ) axis, we develop and propose a protocol capable of separating vibrational coherence from the ground- and excited-electronic states in 3D rephasing and nonrephasing beating maps (S(λ 1 ,ν ~ 2 ,λ 3 )). We found that the vibrational coherence from pure excited electronic states appears at positive frequency (+ν ~ 2 ) in the rephasing beating map and at negative frequency (−ν ~ 2 ) in the nonrephasing beating map. Furthermore, we also found that vibrational coherence from excited electronic state had a long dephasing time of 244 fs. The long-lived excited-state vibrational coherence indicates that coherence may be involved in the electron transfer process. Our findings not only shed light on the mechanism of ultrafast electron transfer in organic photovoltaics but also are beneficial for the study of the coherence effect on photoexcited dynamics in other systems

Non-moving Hadamard matrix diffusers for speckle reduction in laser pico-projectors

Science.gov (United States)

Thomas, Weston; Middlebrook, Christopher

2014-12-01

Personal electronic devices such as cell phones and tablets continue to decrease in size while the number of features and add-ons keep increasing. One particular feature of great interest is an integrated projector system. Laser pico-projectors have been considered, but the technology has not been developed enough to warrant integration. With new advancements in diode technology and MEMS devices, laser-based projection is currently being advanced for pico-projectors. A primary problem encountered when using a pico-projector is coherent interference known as speckle. Laser speckle can lead to eye irritation and headaches after prolonged viewing. Diffractive optical elements known as diffusers have been examined as a means to lower speckle contrast. This paper presents a binary diffuser known as a Hadamard matrix diffuser. Using two static in-line Hadamard diffusers eliminates the need for rotation or vibration of the diffuser for temporal averaging. Two Hadamard diffusers were fabricated and contrast values measured showing good agreement with theory and simulated values.

The ABRAVIBE toolbox for teaching vibration analysis and structural dynamics

DEFF Research Database (Denmark)

Brandt, A.

2013-01-01

, a MATLAB toolbox (the ABRAVIBE toolbox) has been developed as an accompanying toolbox for the recent book "Noise and Vibration Analysis" by the author. This free, open software, published under GNU Public License, can be used with GNU Octave, if an entirely free software platform is wanted, with a few...... functional limitations. The toolbox includes functionality for simulation of mechanical models as well as advanced analysis such as time series analysis, spectral analysis, frequency response and correlation function estimation, modal parameter extraction, and rotating machinery analysis (order tracking...

Carrier diffusion as a measure of carrier/exciton transfer rate in InAs/InGaAsP/InP hybrid quantum dot-quantum well structures emitting at telecom spectral range

Science.gov (United States)

Rudno-Rudziński, W.; Biegańska, D.; Misiewicz, J.; Lelarge, F.; Rousseau, B.; Sek, G.

2018-01-01

We investigate the diffusion of photo-generated carriers (excitons) in hybrid two dimensional-zero dimensional tunnel injection structures, based on strongly elongated InAs quantum dots (called quantum dashes, QDashes) of various heights, designed for emission at around 1.5 μm, separated by a 3.5 nm wide barrier from an 8 nm wide In0.64Ga0.36As0.78P0.22 quantum well (QW). By measuring the spectrally filtered real space images of the photoluminescence patterns with high resolution, we probe the spatial extent of the emission from QDashes. Deconvolution with the exciting light spot shape allows us to extract the carrier/exciton diffusion lengths. For the non-resonant excitation case, the diffusion length depends strongly on excitation power, pointing at carrier interactions and phonons as its main driving mechanisms. For the case of excitation resonant with absorption in the adjacent QW, the diffusion length does not depend on excitation power for low excitation levels since the generated carriers do not have sufficient excess kinetic energy. It is also found that the diffusion length depends on the quantum-mechanical coupling strength between QW and QDashes, controlled by changing the dash size. It influences the energy difference between the QDash ground state of the system and the quantum well levels, which affects the tunneling rates. When that QW-QDash level separation decreases, the probability of capturing excitons generated in the QW by QDashes increases, which is reflected by the decreased diffusion length from approx. 5 down to 3 μm.

Axial Fan Blade Vibration Assessment under Inlet Cross-Flow Conditions Using Laser Scanning Vibrometry

Directory of Open Access Journals (Sweden)

Till Heinemann

2017-08-01

Full Text Available In thermal power plants equipped with air-cooled condensers (ACCs, axial cooling fans operate under the influence of ambient flow fields. Under inlet cross-flow conditions, the resultant asymmetric flow field is known to introduce additional harmonic forces to the fan blades. This effect has previously only been studied numerically or by using blade-mounted strain gauges. For this study, laser scanning vibrometry (LSV was used to assess fan blade vibration under inlet cross-flow conditions in an adapted fan test rig inside a wind tunnel test section. Two co-rotating laser beams scanned a low-pressure axial fan, resulting in spectral, phase-resolved surface vibration patterns of the fan blades. Two distinct operating points with flow coefficients of 0.17 and 0.28 were examined, with and without inlet cross-flow influence. While almost identical fan vibration patterns were found for both reference operating points, the overall blade vibration increased by 100% at the low fan flow rate as a result of cross-flow, and by 20% at the high fan flow rate. While numerically predicted natural frequency modes could be confirmed from experimental data as minor peaks in the vibration amplitude spectrum, they were not excited significantly by cross-flow. Instead, primarily higher rotation-rate harmonics were amplified; that is, a synchronous blade-tip flapping was strongly excited at the blade-pass frequency.

Spectral theory and nonlinear functional analysis

CERN Document Server

Lopez-Gomez, Julian

2001-01-01

This Research Note addresses several pivotal problems in spectral theory and nonlinear functional analysis in connection with the analysis of the structure of the set of zeroes of a general class of nonlinear operators. It features the construction of an optimal algebraic/analytic invariant for calculating the Leray-Schauder degree, new methods for solving nonlinear equations in Banach spaces, and general properties of components of solutions sets presented with minimal use of topological tools. The author also gives several applications of the abstract theory to reaction diffusion equations and systems.The results presented cover a thirty-year period and include recent, unpublished findings of the author and his coworkers. Appealing to a broad audience, Spectral Theory and Nonlinear Functional Analysis contains many important contributions to linear algebra, linear and nonlinear functional analysis, and topology and opens the door for further advances.

Random Vibration of Space Shuttle Weather Protection Systems

Directory of Open Access Journals (Sweden)

Isaac Elishakoff

1995-01-01

Full Text Available The article deals with random vibrations of the space shuttle weather protection systems. The excitation model represents a fit to the measured experimental data. The cross-spectral density is given as a convex combination of three exponential functions. It is shown that for the type of loading considered, the Bernoulli-Euler theory cannot be used as a simplified approach, and the structure will be more properly modeled as a Timoshenko beam. Use of the simple Bernoulli-Euler theory may result in an error of about 50% in determining the mean-square value of the bending moment in the weather protection system.

A survey of the modern auto- and cross-spectral analyses for the purpose of tokamak study

International Nuclear Information System (INIS)

Iwama, N.

1984-09-01

The modern techniques of digital auto- and cross-spectral analyses are surveyed for the purpose of the CO 2 -laser scattering experiment on the microinstability and the associated anomalous diffusion in TFR tokamak. The outline of the practical procedures of spectral estimation and the underlying mathematical principles are described with emphasis on the comparison between the maximum entropy method and the conventional methods. The statistical properties of the spectral estimators are discussed and examined by experiments

Tomographic-spectral approach for dark matter detection in the cross-correlation between cosmic shear and diffuse γ-ray emission

International Nuclear Information System (INIS)

Camera, S.; Fornasa, M.; Fornengo, N.; Regis, M.

2015-01-01

We recently proposed to cross-correlate the diffuse extragalactic γ-ray background with the gravitational lensing signal of cosmic shear. This represents a novel and promising strategy to search for annihilating or decaying particle dark matter (DM) candidates. In the present work, we demonstrate the potential of a tomographic-spectral approach: measuring the cross-correlation in separate bins of redshift and energy significantly improves the sensitivity to a DM signal. Indeed, the technique proposed here takes advantage of the different scaling of the astrophysical and DM components with redshift and, simultaneously of their different energy spectra and different angular extensions. The sensitivity to a particle DM signal is extremely promising even when the DM-induced emission is quite faint. We first quantify the prospects of detecting DM by cross-correlating the Fermi Large Area Telescope (LAT) diffuse γ-ray background with the cosmic shear expected from the Dark Energy Survey. Under the hypothesis of a significant subhalo boost, such a measurement can deliver a 5σ detection of DM, if the DM particle is lighter than 300 GeV and has a thermal annihilation rate. We then forecast the capability of the European Space Agency Euclid satellite (whose launch is planned for 2020), in combination with an hypothetical future γ-ray detector with slightly improved specifications compared to current telescopes. We predict that the cross-correlation of their data will allow a measurement of the DM mass with an uncertainty of a factor of 1.5–2, even for moderate subhalo boosts, for DM masses up to few hundreds of GeV and thermal annihilation rates

Tomographic-spectral approach for dark matter detection in the cross-correlation between cosmic shear and diffuse γ-ray emission

Energy Technology Data Exchange (ETDEWEB)

Camera, S. [Jodrell Bank Centre for Astrophysics, The University of Manchester, Alan Turing Building, Oxford Road, Manchester M13 9PL (United Kingdom); Fornasa, M. [School of Physics and Astronomy, University of Nottingham, University Campus, Nottingham NG7 2RD (United Kingdom); Fornengo, N.; Regis, M., E-mail: stefano.camera@manchester.ac.uk, E-mail: fornasam@gmail.com, E-mail: fornengo@to.infn.it, E-mail: regis@to.infn.it [Dipartimento di Fisica, Università di Torino, Via P. Giuria 1, 10125 Torino (Italy)

2015-06-01

We recently proposed to cross-correlate the diffuse extragalactic γ-ray background with the gravitational lensing signal of cosmic shear. This represents a novel and promising strategy to search for annihilating or decaying particle dark matter (DM) candidates. In the present work, we demonstrate the potential of a tomographic-spectral approach: measuring the cross-correlation in separate bins of redshift and energy significantly improves the sensitivity to a DM signal. Indeed, the technique proposed here takes advantage of the different scaling of the astrophysical and DM components with redshift and, simultaneously of their different energy spectra and different angular extensions. The sensitivity to a particle DM signal is extremely promising even when the DM-induced emission is quite faint. We first quantify the prospects of detecting DM by cross-correlating the Fermi Large Area Telescope (LAT) diffuse γ-ray background with the cosmic shear expected from the Dark Energy Survey. Under the hypothesis of a significant subhalo boost, such a measurement can deliver a 5σ detection of DM, if the DM particle is lighter than 300 GeV and has a thermal annihilation rate. We then forecast the capability of the European Space Agency Euclid satellite (whose launch is planned for 2020), in combination with an hypothetical future γ-ray detector with slightly improved specifications compared to current telescopes. We predict that the cross-correlation of their data will allow a measurement of the DM mass with an uncertainty of a factor of 1.5–2, even for moderate subhalo boosts, for DM masses up to few hundreds of GeV and thermal annihilation rates.

Tomographic-spectral approach for dark matter detection in the cross-correlation between cosmic shear and diffuse γ-ray emission

Science.gov (United States)

Camera, S.; Fornasa, M.; Fornengo, N.; Regis, M.

2015-06-01

We recently proposed to cross-correlate the diffuse extragalactic γ-ray background with the gravitational lensing signal of cosmic shear. This represents a novel and promising strategy to search for annihilating or decaying particle dark matter (DM) candidates. In the present work, we demonstrate the potential of a tomographic-spectral approach: measuring the cross-correlation in separate bins of redshift and energy significantly improves the sensitivity to a DM signal. Indeed, the technique proposed here takes advantage of the different scaling of the astrophysical and DM components with redshift and, simultaneously of their different energy spectra and different angular extensions. The sensitivity to a particle DM signal is extremely promising even when the DM-induced emission is quite faint. We first quantify the prospects of detecting DM by cross-correlating the Fermi Large Area Telescope (LAT) diffuse γ-ray background with the cosmic shear expected from the Dark Energy Survey. Under the hypothesis of a significant subhalo boost, such a measurement can deliver a 5σ detection of DM, if the DM particle is lighter than 300 GeV and has a thermal annihilation rate. We then forecast the capability of the European Space Agency Euclid satellite (whose launch is planned for 2020), in combination with an hypothetical future γ-ray detector with slightly improved specifications compared to current telescopes. We predict that the cross-correlation of their data will allow a measurement of the DM mass with an uncertainty of a factor of 1.5-2, even for moderate subhalo boosts, for DM masses up to few hundreds of GeV and thermal annihilation rates.

Stochastic Spectral Analysis for Characterizing Hydraulic Diffusivity in an Alluvial Fan Aquifer with River Stimulus

Science.gov (United States)

Wang, Y. L.; Zha, Y.; Yeh, T. C. J.; Wen, J. C.

2015-12-01

Estimation of subsurface hydraulic diffusivity was carried out to understand the characteristics of Zhuoshui River alluvial fan, Taiwan. The fan, an important agricultural and industrial region with high water demand, is located at middle Taiwan with an area of 1800 km2. The prior geo-investigations suggest that the main recharge region of the fan is at an apex along the river. The distribution of soil hydraulic diffusivity was estimated by fusing naturally recurring stimulus provided by river and groundwater head. Specifically, the variance and power spectrum provided by temporal and spatial change of groundwater head in response to river stage variations are analyzed to estimate hydraulic diffusivity distribution. It is found that the hydraulic diffusivity of the fan is at the range from 0.08 to 16 m2/s. The average hydraulic diffusivity at the apex, middle, and tail of the fan along the river is about 0.4, 0.6, and 1.0 m2/s, respectively.

DFT study of conformational and vibrational characteristics of 2-(2-hydroxyphenyl)benzothiazole molecule.

Science.gov (United States)

Pandey, Urmila; Srivastava, Mayuri; Singh, R P; Yadav, R A

2014-08-14

The conformational and IR and Raman spectral studies of 2-(2-hydroxyphenyl)benzothiazole have been carried out by using the DFT method at the B3LYP/6-311++G(**) level. The detailed vibrational assignments have been done on the basis of calculated potential energy distributions. Comparative studies of molecular geometries, atomic charges and vibrational fundamentals of all the conformers have been made. There are four possible conformers for this molecule. The optimized geometrical parameters obtained by B3LYP/6-311++G(**) method showed good agreement with the experimental X-ray data. The atomic polar tensor (APT) charges, Mulliken atomic charges, natural bond orbital (NBO) analysis and HOMO-LUMO energy gap of HBT and its conformers were also computed. Copyright © 2014 Elsevier B.V. All rights reserved.

A bandwidth correction to the Allegri-Zhang solution for accelerated random vibration testing

Directory of Open Access Journals (Sweden)

Benasciutti Denis

2018-01-01

Full Text Available In 2008, Allegri and Zhang published a study [Int. J. Fatigue. 2008, 30(6:967-977] in which they provided an exact analytical solution to the inverse scaling law for accelerated vibration tests of linear systems submitted to stationary Gaussian excitations By combining finite element analysis with multiaxial spectral methods defined in the frequency-domain, their solution generalised the simple inverse power law model suggested in some standards. The solution adopted the “equivalent von Mises stress” multiaxial criterion combined with the narrow-band damage expression. This work aims to propose a bandwidth correction to the original Allegri-Zhang solution to account for the actual spectral banwidth of the local multiaxial stress. The corrected Allegri-Zhang solution is also extended to another multiaxial spectral method, namely the “Projection-by-Projection” criterion. A numerical example is finally discussed, in which the corrected solution is applied to an L-shaped beam submitted to random accelerations.

Spatial and spectral effects in subcritical system pulsed experiments

International Nuclear Information System (INIS)

Dulla, S.; Nervo, M.; Ravetto, P.; Carta, M.

2013-01-01

Accurate neutronic models are needed for the interpretation of pulsed experiments in subcritical systems. In this work, the extent of spatial and spectral effects in the pulse propagation phenomena is investigated and the analysis is applied to the GUINEVERE experiment. The multigroup cross section data is generated by the Monte Carlo SERPENT code and the neutronic evolution following the source pulse is simulated by a kinetic diffusion code. The results presented show that important spatial and spectral aspects need to be properly accounted for and that a detailed energy approach may be needed to adequately capture the physical features of the system to the pulse injection. (authors)

Spectral analysis of allogeneic hydroxyapatite powders

Science.gov (United States)

Timchenko, P. E.; Timchenko, E. V.; Pisareva, E. V.; Vlasov, M. Yu; Red'kin, N. A.; Frolov, O. O.

2017-01-01

In this paper we discuss the application of Raman spectroscopy to the in vitro analysis of the hydroxyapatite powder samples produced from different types of animal bone tissue during demineralization process at various acid concentrations and exposure durations. The derivation of the Raman spectrum of hydroxyapatite is attempted by the analysis of the pure powders of its known constituents. Were experimentally found spectral features of hydroxyapatite, based on analysis of the line amplitude at wave numbers 950-965 cm-1 ((PO4)3- (ν1) vibration) and 1065-1075 cm-1 ((CO3)2-(ν1) B-type replacement). Control of physicochemical properties of hydroxyapatite was carried out by Raman spectroscopy. Research results are compared with an infrared Fourier spectroscopy.

Spectral analysis of allogeneic hydroxyapatite powders

International Nuclear Information System (INIS)

Timchenko, P E; Timchenko, E V; Pisareva, E V; Vlasov, M Yu; Red’kin, N A; Frolov, O O

2017-01-01

In this paper we discuss the application of Raman spectroscopy to the in vitro analysis of the hydroxyapatite powder samples produced from different types of animal bone tissue during demineralization process at various acid concentrations and exposure durations. The derivation of the Raman spectrum of hydroxyapatite is attempted by the analysis of the pure powders of its known constituents. Were experimentally found spectral features of hydroxyapatite, based on analysis of the line amplitude at wave numbers 950-965 cm -1 ((PO 4 ) 3- (ν 1 ) vibration) and 1065-1075 cm -1 ((CO 3 ) 2- (ν 1 ) B-type replacement). Control of physicochemical properties of hydroxyapatite was carried out by Raman spectroscopy. Research results are compared with an infrared Fourier spectroscopy. (paper)

Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime.

Science.gov (United States)

Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Wang, Lihong V

2012-06-01

Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method, the absorption coefficients of an oxygenated bovine blood phantom at 560, 565, 570, and 575 nm were quantified with errors of <3%. We also quantified the total hemoglobin concentration and hemoglobin oxygen saturation in a live mouse. Compared with the conventional amplitude method, the acoustic spectral method provides greater quantification accuracy in the optical diffusive regime. The limitations of the acoustic spectral method was also discussed.

[Study on plasma parameters in diffuse discharge with semispherical electrod by optical emission spectrum].

Science.gov (United States)

Dong, Li-Fang; Tong, Guo-Liang; Shen, Zhong-Kai; Liu, Liang; Ji, Ya-Fei; Zhao, Huan-Huan

2012-06-01

The diffuse discharge plasma in air was observed in a dielectric barrier discharge with two semispherical water electrodes. The variations of vibration temperature, rotation temperature, and average electron energy as the function of the applied voltage were studied by emission spectroscopy. The vibration temperature and the rotation temperature were calculated through the second positive band system (C3Pi(u)-->B3Pi(g)) of N2+ and the first negative band system (B2 Sigma(u+)-->Chi2Sigma(g+)) of N(2+) respectively. The average electron energy was studied by intensity ratio of 391.4 and 337.1 nm. It was found that the rotation temperature increases with the applied voltage increasing, while the vibration temperature and the electron energy decrease.

Anti-vibration gloves?

Science.gov (United States)

Hewitt, Sue; Dong, Ren G; Welcome, Daniel E; McDowell, Thomas W

2015-03-01

For exposure to hand-transmitted vibration (HTV), personal protective equipment is sold in the form of anti-vibration (AV) gloves, but it remains unclear how much these gloves actually reduce vibration exposure or prevent the development of hand-arm vibration syndrome in the workplace. This commentary describes some of the issues that surround the classification of AV gloves, the assessment of their effectiveness and their applicability in the workplace. The available information shows that AV gloves are unreliable as devices for controlling HTV exposures. Other means of vibration control, such as using alternative production techniques, low-vibration machinery, routine preventative maintenance regimes, and controlling exposure durations are far more likely to deliver effective vibration reductions and should be implemented. Furthermore, AV gloves may introduce some adverse effects such as increasing grip force and reducing manual dexterity. Therefore, one should balance the benefits of AV gloves and their potential adverse effects if their use is considered. © Crown copyright 2014.

Influence of intermolecular amide hydrogen bonding on the geometry, atomic charges, and spectral modes of acetanilide: An ab initio study

Science.gov (United States)

Binoy, J.; Prathima, N. B.; Murali Krishna, C.; Santhosh, C.; Hubert Joe, I.; Jayakumar, V. S.

2006-08-01

Acetanilide, a compound of pharmaceutical importance possessing pain-relieving properties due to its blocking the pulse dissipating along the nerve fiber, is subjected to vibrational spectral investigation using NIR FT Raman, FT-IR, and SERS. The geometry, Mulliken charges, and vibrational spectrum of acetanilide have been computed using the Hartree-Fock theory and density functional theory employing the 6-31G (d) basis set. To investigate the influence of intermolecular amide hydrogen bonding, the geometry, charge distribution, and vibrational spectrum of the acetanilide dimer have been computed at the HF/6-31G (d) level. The computed geometries reveal that the acetanilide molecule is planar, while twisting of the secondary amide group with respect to the phenyl ring is found upon hydrogen bonding. The trans isomerism and “amido” form of the secondary amide, hyperconjugation of the C=O group with the adjacent C-C bond, and donor-acceptor interaction have been investigated using computed geometry. The carbonyl stretching band position is found to be influenced by the tendency of the phenyl ring to withdraw nitrogen lone pair, intermolecular hydrogen bonding, conjugation, and hyperconjugation. A decrease in the NH and C=O bond orders and increase in the C-N bond orders due to donor-acceptor interaction can be observed in the vibrational spectra. The SERS spectral analysis reveals that the flat orientation of the molecule on the adsorption plane is preferred.

The Astrophysical Weeds: Rotational Transitions in Excited Vibrational States

Science.gov (United States)

Alonso, José L.; Kolesniková, Lucie; Alonso, Elena R.; Mata, Santiago

2017-06-01

The number of unidentified lines in the millimeter and submillimeter wave surveys of the interstellar medium has grown rapidly. The major contributions are due to rotational transitions in excited vibrational states of a relatively few molecules that are called the astrophysical weeds. necessary data to deal with spectral lines from astrophysical weeds species can be obtained from detailed laboratory rotational measurements in the microwave and millimeter wave region. A general procedure is being used at Valladolid combining different time and/or frequency domain spectroscopic tools of varying importance for providing the precise set of spectroscopic constants that could be used to search for this species in the ISM. This is illustrated in the present contribution through its application to several significant examples. Fortman, S. M., Medvedev, I. R., Neese, C.F., & De Lucia, F.C. 2010, ApJ,725, 1682 Rotational Spectra in 29 Vibrationally Excited States of Interstellar Aminoacetonitrile, L. Kolesniková, E. R. Alonso, S. Mata, and J. L. Alonso, The Astrophysical Journal Supplement Series 2017, (in press).

Spectral negentropy based sidebands and demodulation analysis for planet bearing fault diagnosis

Science.gov (United States)

Feng, Zhipeng; Ma, Haoqun; Zuo, Ming J.

2017-12-01

Planet bearing vibration signals are highly complex due to intricate kinematics (involving both revolution and spinning) and strong multiple modulations (including not only the fault induced amplitude modulation and frequency modulation, but also additional amplitude modulations due to load zone passing, time-varying vibration transfer path, and time-varying angle between the gear pair mesh lines of action and fault impact force vector), leading to difficulty in fault feature extraction. Rolling element bearing fault diagnosis essentially relies on detection of fault induced repetitive impulses carried by resonance vibration, but they are usually contaminated by noise and therefor are hard to be detected. This further adds complexity to planet bearing diagnostics. Spectral negentropy is able to reveal the frequency distribution of repetitive transients, thus providing an approach to identify the optimal frequency band of a filter for separating repetitive impulses. In this paper, we find the informative frequency band (including the center frequency and bandwidth) of bearing fault induced repetitive impulses using the spectral negentropy based infogram. In Fourier spectrum, we identify planet bearing faults according to sideband characteristics around the center frequency. For demodulation analysis, we filter out the sensitive component based on the informative frequency band revealed by the infogram. In amplitude demodulated spectrum (squared envelope spectrum) of the sensitive component, we diagnose planet bearing faults by matching the present peaks with the theoretical fault characteristic frequencies. We further decompose the sensitive component into mono-component intrinsic mode functions (IMFs) to estimate their instantaneous frequencies, and select a sensitive IMF with an instantaneous frequency fluctuating around the center frequency for frequency demodulation analysis. In the frequency demodulated spectrum (Fourier spectrum of instantaneous frequency) of

Spectral analysis methods for vehicle interior vibro-acoustics identification

Science.gov (United States)

Hosseini Fouladi, Mohammad; Nor, Mohd. Jailani Mohd.; Ariffin, Ahmad Kamal

2009-02-01

Noise has various effects on comfort, performance and health of human. Sound are analysed by human brain based on the frequencies and amplitudes. In a dynamic system, transmission of sound and vibrations depend on frequency and direction of the input motion and characteristics of the output. It is imperative that automotive manufacturers invest a lot of effort and money to improve and enhance the vibro-acoustics performance of their products. The enhancement effort may be very difficult and time-consuming if one relies only on 'trial and error' method without prior knowledge about the sources itself. Complex noise inside a vehicle cabin originated from various sources and travel through many pathways. First stage of sound quality refinement is to find the source. It is vital for automotive engineers to identify the dominant noise sources such as engine noise, exhaust noise and noise due to vibration transmission inside of vehicle. The purpose of this paper is to find the vibro-acoustical sources of noise in a passenger vehicle compartment. The implementation of spectral analysis method is much faster than the 'trial and error' methods in which, parts should be separated to measure the transfer functions. Also by using spectral analysis method, signals can be recorded in real operational conditions which conduce to more consistent results. A multi-channel analyser is utilised to measure and record the vibro-acoustical signals. Computational algorithms are also employed to identify contribution of various sources towards the measured interior signal. These achievements can be utilised to detect, control and optimise interior noise performance of road transport vehicles.

Spectral interferometric length measurement and tomography

International Nuclear Information System (INIS)

Pinkl, W.

1998-01-01

This work presents a new method for optical length measurement using the principles of spectral interferometry. Results of thickness measurements on glass plates, the human cornea in vivo and human finger and toe nails in vivo and in vitro are discussed. It could be demonstrated that the absorption coefficient of red and green ink can be measured depth sensitive. Another chapter describes a new technique to measure a thickness profile of a sample within the illuminating beam. It could be demonstrated that a thickness profile over a distance of a few millimeters can be measured with one single measurement. At the Institute of Medical Physics of the University of Vienna a method to measure intraocular distances by the means of interferometry has been developed during the last ten years. Basing on this method (dual beam interferometry) an optical in vivo tomography experiment could be established. A thickness map of the retina of a human eye in vivo can be easily measured. The dual beam technique uses a Michelson interferometer with a moving mirror to adjust the length of the interferometer arms. The mirror is moved by a stepper motor. This movement induces vibrations, misalignment and other disadvantages. So mechanically moved parts as reasons for possible errors should be eliminated. This work shows one possible solution - using the principle of spectral interferometry. A spectral interferometry experiment is a static experiment, no moving parts are used. A spectral interferometry experiment has been used to measure the thickness of glass plates and stacks of glass plates. Using two light sources of different wavelengths spectral absorption properties of a sample can be measured depth sensitive. This could be demonstrated with stacks of glass plates and the use of red and green ink between two plates. The obtained results are compared to the results of a computer simulation. To demonstrate the ability of spectral interferometry to measure the thickness of biologic

Vibrational imaging and microspectroscopies based on coherent anti-Stokes Raman scattering microscopy

International Nuclear Information System (INIS)

Volkmer, Andreas

2005-01-01

For noninvasive characterization of chemical species or biological components within a complex heterogeneous system, their intrinsic molecular vibrational properties can be used in contrast mechanisms in optical microscopy. A series of recent advances have made coherent anti-Stokes Raman scattering (CARS) microscopy a powerful technique that allows vibrational imaging with high sensitivity, high spectral resolution and three-dimensional sectioning capability. In this review, we discuss theoretical and experimental aspects of CARS microscopy in a collinear excitation beam geometry. Particular attention is given to the underlying physical principles behind the new features of CARS signal generation under tight focusing conditions. We provide a brief overview of the instrumentation of CARS microscopy and its experimental characterization by means of imaging of model systems and live unstained cells. CARS microscopy offers the possibility of spatially resolved vibrational spectroscopy, providing chemical and physical structure information of molecular specimens on the sub-micrometre length scale. We review multiplex CARS microspectroscopy allowing fast acquisition of frequency-resolved CARS spectra, time-resolved CARS microspectroscopy recording ultrafast Raman free induction decays and CARS correlation spectroscopy probing dynamical processes with chemical selectivity. (topical review)

The approximation function of bridge deck vibration derived from the measured eigenmodes

Directory of Open Access Journals (Sweden)

Sokol Milan

2017-12-01

Full Text Available This article deals with a method of how to acquire approximate displacement vibration functions. Input values are discrete, experimentally obtained mode shapes. A new improved approximation method based on the modal vibrations of the deck is derived using the least-squares method. An alternative approach to be employed in this paper is to approximate the displacement vibration function by a sum of sine functions whose periodicity is determined by spectral analysis adapted for non-uniformly sampled data and where the parameters of scale and phase are estimated as usual by the least-squares method. Moreover, this periodic component is supplemented by a cubic regression spline (fitted on its residuals that captures individual displacements between piers. The statistical evaluation of the stiffness parameter is performed using more vertical modes obtained from experimental results. The previous method (Sokol and Flesch, 2005, which was derived for near the pier areas, has been enhanced to the whole length of the bridge. The experimental data describing the mode shapes are not appropriate for direct use. Especially the higher derivatives calculated from these data are very sensitive to data precision.

Knots and Random Walks in Vibrated Granular Chains

International Nuclear Information System (INIS)

Ben-Naim, E.; Daya, Z. A.; Vorobieff, P.; Ecke, R. E.

2001-01-01

We study experimentally statistical properties of the opening times of knots in vertically vibrated granular chains. Our measurements are in good qualitative and quantitative agreement with a theoretical model involving three random walks interacting via hard-core exclusion in one spatial dimension. In particular, the knot survival probability follows a universal scaling function which is independent of the chain length, with a corresponding diffusive characteristic time scale. Both the large-exit-time and the small-exit-time tails of the distribution are suppressed exponentially, and the corresponding decay coefficients are in excellent agreement with theoretical values

Discontinuity in Fast Dynamics at the Glass Transition of ortho-Terphenyl.

Science.gov (United States)

Hoffman, David J; Fayer, Michael D

2017-11-16

The dynamics of the molecular glass former ortho-terphenyl through the glass transition were observed with two-dimensional infrared vibrational spectroscopy measurements of spectral diffusion using the small probe molecule phenylselenocyanate. Although the slow diffusive motions were not visible on the experimental time scale, a picosecond-scale exponential relaxation was observed at temperatures from above to well below the glass transition temperature. The characteristic time scale has a smooth temperature dependence from the liquid into the glass phase, but the range of vibrational frequencies the probe samples displayed a discontinuity at the glass transition temperature. Complementary pump-probe experiments associate the observed motion with density fluctuations. The key features of the dynamics are reproduced with a simple corrugated well potential energy surface model. In addition, the temperature dependence of the homogeneous vibrational dephasing was found to have a T 2 functional form, where T is the absolute temperature.

Measurement of the diffusion length of thermal neutrons in the beryllium oxide; Mesure de la longueur de diffusion des neutrons thermiques dans l'oxyde de beryllium

Energy Technology Data Exchange (ETDEWEB)

Koechlin, J C; Martelly, J; Duggal, V P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1955-07-01

The diffusion length of thermal neutrons in the beryllium oxide has been obtained while studying the spatial distribution of the neutrons in a massive parallelepiped of this matter placed before the thermal column of the reactor core of Saclay. The mean density of the beryllium oxide (BeO) is 2,95 gr/cm{sup 3}, the mean density of the massif is 2,92 gr/cm{sup 3}. The value of the diffusion length, deducted of the done measures, is: L = 32,7 {+-} 0,5 cm (likely gap). Some remarks are formulated about the influence of the spectral distribution of the neutrons flux used. (authors) [French] La longueur de diffusion des neutrons thermiques dans l'oxyde de beryllium a ete obtenue en etudiant la repartition spatiale des neutrons dans un massif parallelepipedique de cette matiere placee devant la colonne thermique de la Pile de Saclay. La densite moyenne de l'oxyde de beryllium (BeO) est de 2,95 gr/cm{sup 3}, la densite moyenne du massif de 2,92 gr/cm{sup 3}. La valeur de la longueur de diffusion, deduite des mesures effectuees est: L 32,7 {+-} 0,5 cm (ecart probable). Des remarques sont formulees quant a l'influence de la repartition spectrale du flux de neutrons utilise. (auteurs)

Application of the three-component bidirectional reflectance distribution function model to Monte Carlo calculation of spectral effective emissivities of nonisothermal blackbody cavities.

Science.gov (United States)

Prokhorov, Alexander; Prokhorova, Nina I

2012-11-20

We applied the bidirectional reflectance distribution function (BRDF) model consisting of diffuse, quasi-specular, and glossy components to the Monte Carlo modeling of spectral effective emissivities for nonisothermal cavities. A method for extension of a monochromatic three-component (3C) BRDF model to a continuous spectral range is proposed. The initial data for this method are the BRDFs measured in the plane of incidence at a single wavelength and several incidence angles and directional-hemispherical reflectance measured at one incidence angle within a finite spectral range. We proposed the Monte Carlo algorithm for calculation of spectral effective emissivities for nonisothermal cavities whose internal surface is described by the wavelength-dependent 3C BRDF model. The results obtained for a cylindroconical nonisothermal cavity are discussed and compared with results obtained using the conventional specular-diffuse model.

Ultra-low-vibration pulse-tube cryocooler system - cooling capacity and vibration

Science.gov (United States)

Ikushima, Yuki; Li, Rui; Tomaru, Takayuki; Sato, Nobuaki; Suzuki, Toshikazu; Haruyama, Tomiyoshi; Shintomi, Takakazu; Yamamoto, Akira

2008-09-01

This report describes the development of low-vibration cooling systems with pulse-tube (PT) cryocoolers. Generally, PT cryocoolers have the advantage of lower vibrations in comparison to those of GM cryocoolers. However, cooling systems for the cryogenic laser interferometer observatory (CLIO), which is a gravitational wave detector, require an operational vibration that is sufficiently lower than that of a commercial PT cryocooler. The required specification for the vibration amplitude in cold stages is less than ±1 μm. Therefore, during the development of low-vibration cooling systems for the CLIO, we introduced advanced countermeasures for commercial PT cryocoolers. The cooling performance and the vibration amplitude were evaluated. The results revealed that 4 K and 80 K PT cooling systems with a vibration amplitude of less than ±1 μm and cooling performance of 4.5 K and 70 K at heat loads of 0.5 W and 50 W, respectively, were developed successfully.

Vibration atomic layer deposition for conformal nanoparticle coating

Energy Technology Data Exchange (ETDEWEB)

Park, Suk Won; Woo Kim, Jun; Jong Choi, Hyung; Hyung Shim, Joon, E-mail: shimm@korea.ac.kr [School of Mechanical Engineering, Korea University, Seoul 136-701 (Korea, Republic of)

2014-01-15

A vibration atomic layer deposition reactor was developed for fabricating a conformal thin-film coating on nanosize particles. In this study, atomic layer deposition of 10–15-nm-thick Al{sub 2}O{sub 3} films was conducted on a high-surface-area acetylene black powder with particle diameters of 200–250 nm. Intense vibration during the deposition resulted in the effective separation of particles, overcoming the interparticle agglomeration force and enabling effective diffusion of the precursor into the powder chunk; this phenomenon led to the formation of a conformal film coating on the nanopowder particles. It was also confirmed that the atomic layer deposition Al{sub 2}O{sub 3} films initially grew on the high-surface-area acetylene black powder particles as discrete islands, presumably because chemisorption of the precursor and water occurred only on a few sites on the high-surface-area acetylene black powder surface. Relatively sluggish growth of the films during the initial atomic layer deposition cycles was identified from composition analysis.

Self-diffusion on (100), (110), and (111) surfaces of Ni and Cu: A detailed study of prefactors and activation energies

International Nuclear Information System (INIS)

Ku'rpick, Ulrike

2001-01-01

We calculate activation barriers and prefactors for diffusion via hopping on (100), (110), and (111) surfaces of Ni and Cu. The calculations reveal that, when activation barriers decrease there is also a decrease in the prefactors such that the changes in both quantities partly compensate for each other with respect to the diffusivities. Thermodynamic functions which contribute to the prefactors are calculated from local vibrational density of states, showing that mainly entropy contributions control the prefactors. Our method allows one to trace the obtained values back to vibrational properties of the adatoms in both the minimum-energy and transition-state configurations, and enables a physical understanding of why prefactors have certain values

Prototype fiber Bragg Grattings (FBG) sensor based on intensity modulation of the laser diode low frequency vibrations measurement

Science.gov (United States)

Setiono, Andi; Ula, Rini Khamimatul; Hanto, Dwi; Widiyatmoko, Bambang; Purnamaningsih, Retno Wigajatri

2016-02-01

In general, Fiber Bragg Grating (FBG) sensor works based on observation of spectral response characteristic to detect the desired parameter. In this research, we studied intensity response characteristic of FBG to detect the dynamic strain. Experiment result show that the reflected intensity had linier relationships with dynamic strain. Based on these characteristics, we developed the FBG sensor to detect low frequency vibration. This sensor is designed by attaching the FBG on the bronze cantilever with dimensions of 85×3×0.5 mm. Measurement results showed that the sensor was able to detect vibrations in the frequency range of 7-10 Hz at temperature range of 25-45 ˚C. The measured frequency range is still within the frequency range of digging activity, therefore this vibration sensor can be applied for oil pipelines vandalisation detection system.

Ultrafast transient absorption revisited: Phase-flips, spectral fingers, and other dynamical features

Energy Technology Data Exchange (ETDEWEB)

Cina, Jeffrey A., E-mail: cina@uoregon.edu; Kovac, Philip A. [Department of Chemistry and Biochemistry, and Oregon Center for Optical, Molecular, and Quantum Science, University of Oregon, Eugene, Oregon 97403 (United States); Jumper, Chanelle C. [Department of Chemistry, University of Toronto, Toronto, Ontario M5S 3H6 (Canada); Dean, Jacob C.; Scholes, Gregory D., E-mail: gscholes@princeton.edu [Department of Chemistry, Princeton University, Princeton, New Jersey 08544 (United States)

2016-05-07

We rebuild the theory of ultrafast transient-absorption/transmission spectroscopy starting from the optical response of an individual molecule to incident femtosecond pump and probe pulses. The resulting description makes use of pulse propagators and free molecular evolution operators to arrive at compact expressions for the several contributions to a transient-absorption signal. In this alternative description, which is physically equivalent to the conventional response-function formalism, these signal contributions are conveniently expressed as quantum mechanical overlaps between nuclear wave packets that have undergone different sequences of pulse-driven optical transitions and time-evolution on different electronic potential-energy surfaces. Using this setup in application to a simple, multimode model of the light-harvesting chromophores of PC577, we develop wave-packet pictures of certain generic features of ultrafast transient-absorption signals related to the probed-frequency dependence of vibrational quantum beats. These include a Stokes-shifting node at the time-evolving peak emission frequency, antiphasing between vibrational oscillations on opposite sides (i.e., to the red or blue) of this node, and spectral fingering due to vibrational overtones and combinations. Our calculations make a vibrationally abrupt approximation for the incident pump and probe pulses, but properly account for temporal pulse overlap and signal turn-on, rather than neglecting pulse overlap or assuming delta-function excitations, as are sometimes done.

Developing a Macroscopic Mechanistic Model for Low Molecular Weight Diffusion through Polymers in the Rubbery State

DEFF Research Database (Denmark)

Martinez-Lopez, Brais; Huguet, P.; Gontard, N.

2016-01-01

Raman microspectroscopy was used to determine the Fickian diffusivity of two families of low molecular weight molecules through amorphous polystyrene in the rubbery state. Different effects of the temperature on diffusivity for each of the families suggested that molecular mobility is controlled...... by both the volume and flexibility of the diffusing substance when the movement of polymer chains can generate stress induced deformation of molecules. The diffusing molecules were represented as Newtonian spring–bead systems, which allowed us to quantify their flexibility, in function of the vibration...... frequency of their bonds by reconstructing their theoretical spectra. Results showed that the use of molecular descriptors that take into account flexibility rather than the most stable conformation of the diffusing molecules may improve the description of the diffusion behavior caused by variations...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

We present an ab initio molecular dynamics study of vibrational spectral diffusion and hydrogen bond dynamics in aqueous solution of acetone at room temperature. It is found that the frequencies of OD bonds in the acetone hydration shell have a higher stretch frequency than those in the bulk water. Also, on average, the ...

Highly vibrationally excited O2 molecules in low-pressure inductively-coupled plasmas detected by high sensitivity ultra-broad-band optical absorption spectroscopy

Science.gov (United States)

Foucher, Mickaël; Marinov, Daniil; Carbone, Emile; Chabert, Pascal; Booth, Jean-Paul

2015-08-01

Inductively-coupled plasmas in pure O2 (at pressures of 5-80 mTorr and radiofrequency power up to 500 W) were studied by optical absorption spectroscopy over the spectral range 200-450 nm, showing the presence of highly vibrationally excited O2 molecules (up to vʺ = 18) by Schumann-Runge band absorption. Analysis of the relative band intensities indicates a vibrational temperature up to 10,000 K, but these hot molecules only represent a fraction of the total O2 density. By analysing the (11-0) band at higher spectral resolution the O2 rotational temperature was also determined, and was found to increase with both pressure and power, reaching 900 K at 80 mTorr 500 W. These measurements were achieved using a new high-sensitivity ultra-broad-band absorption spectroscopy setup, based on a laser-plasma light source, achromatic optics and an aberration-corrected spectrograph. This setup allows the measurement of weak broadband absorbances due to a baseline variability lower than 2   ×   10-5 across a spectral range of 250 nm.

Investigation of active vibration drilling using acoustic emission and cutting size analysis

Directory of Open Access Journals (Sweden)

Yingjian Xiao

2018-04-01

Full Text Available This paper describes an investigation of active bit vibration on the penetration mechanisms and bit-rock interaction for drilling with a diamond impregnated coring bit. A series of drill-off tests (DOTs were conducted where the drilling rate-of-penetration (ROP was measured at a series of step-wise increasing static bit thrusts or weight-on-bits (WOBs. Two active DOTs were conducted by applying 60 Hz axial vibration at the bit-rock interface using an electromagnetic vibrating table mounted underneath the drilling samples, and a passive DOT was conducted where the bit was allowed to vibrate naturally with lower amplitude due to the compliance of the drilling sample mountings. During drilling, an acoustic emission (AE system was used to record the AE signals generated by the diamond cutter penetration and the cuttings were collected for grain size analysis. The instrumented drilling system recorded the dynamic motions of the bit-rock interface using a laser displacement sensor, a load cell, and an LVDT (linear variable differential transformer recorded the dynamic WOB and the ROP, respectively. Calibration with the drilling system showed that rotary speed was approximately the same at any given WOB, facilitating comparison of the results at the same WOB. Analysis of the experimental results shows that the ROP of the bit at any given WOB increased with higher amplitude of axial bit-rock vibration, and the drill cuttings increased in size with a higher ROP. Spectral analysis of the AEs indicated that the higher ROP and larger cutting size were correlated with a higher AE energy and a lower AE frequency. This indicated that larger fractures were being created to generate larger cutting size. Overall, these results indicate that a greater magnitude of axial bit-rock vibration produces larger fractures and generates larger cuttings which, at the same rotary speed, results in a higher ROP. Keywords: Active bit vibration, Diamond coring drilling, Drill

Spectral intensities in cubic systems. I. Progressions based upon parity vibrational modes

International Nuclear Information System (INIS)

Acevedo, R.; Vasquez, S.O.; Meruane, T.; Poblete, V.; Pozo, J.

1998-01-01

The well-resolved emission and absorption spectra of centrosymmetric coordination compounds of the transition metal ions have been used widely to provide the experimental data against which to test theoretical models of vibronic intensities. With reference to the 2 E g → 4 A 2g luminescence transition, at a perfect octahedral site in Cs 2 SiF 6 , over than one hundred vibronic lines are observed with line widths of a few wavenumber spread over some 3000 cm -1 . This paper reports a through examination of both the electronic and vibrational factors, which influences the observed vibronic intensities of the various assigned and identified lines in the spectra of the MnF 6 2- complex ion in the Cs 2 SiF 6 cubic lattice. The origin and nature of higher order vibronic interactions are analysed on the basis of a symmetrized vibronic crystal field-ligand polarization model. (Author)

Fingers' vibration transmission and grip strength preservation performance of vibration reducing gloves.

Science.gov (United States)

Hamouda, K; Rakheja, S; Dewangan, K N; Marcotte, P

2018-01-01

The vibration isolation performances of vibration reducing (VR) gloves are invariably assessed in terms of power tools' handle vibration transmission to the palm of the hand using the method described in ISO 10819 (2013), while the nature of vibration transmitted to the fingers is ignored. Moreover, the VR gloves with relatively low stiffness viscoelastic materials affect the grip strength in an adverse manner. This study is aimed at performance assessments of 12 different VR gloves on the basis of handle vibration transmission to the palm and the fingers of the gloved hand, together with reduction in the grip strength. The gloves included 3 different air bladder, 3 gel, 3 hybrid, and 2 gel-foam gloves in addition to a leather glove. Two Velcro finger adapters, each instrumented with a three-axis accelerometer, were used to measure vibration responses of the index and middle fingers near the mid-phalanges. Vibration transmitted to the palm was measured using the standardized palm adapter. The vibration transmissibility responses of the VR gloves were measured in the laboratory using the instrumented cylindrical handle, also described in the standard, mounted on a vibration exciter. A total of 12 healthy male subjects participated in the study. The instrumented handle was also used to measure grip strength of the subjects with and without the VR gloves. The results of the study showed that the VR gloves, with only a few exceptions, attenuate handle vibration transmitted to the fingers only in the 10-200 Hz and amplify middle finger vibration at frequencies exceeding 200 Hz. Many of the gloves, however, provided considerable reduction in vibration transmitted to the palm, especially at higher frequencies. These suggest that the characteristics of vibration transmitted to fingers differ considerably from those at the palm. Four of the test gloves satisfied the screening criteria of the ISO 10819 (2013) based on the palm vibration alone, even though these caused

Vibration-based fixation assessment of tibial knee implants: A combined in vitro and in silico feasibility study.

Science.gov (United States)

Leuridan, Steven; Goossens, Quentin; Vander Sloten, Tom; De Landsheer, Koen; Delport, Hendrik; Pastrav, Leonard; Denis, Kathleen; Desmet, Wim; Vander Sloten, Jos

2017-11-01

The preoperative diagnosis of loosening of cemented tibial knee implants is challenging. This feasibility study explored the basic potential of a vibration-based method as an alternative diagnostic technique to assess the fixation state of a cemented tibia implant and establish the method's sensitivity limits. A combined in vitro and in silico approach was pursued. Several loosening cases were simulated. The largest changes in the vibrational behavior were obtained in the frequency range above 1500 Hz. The vibrational behavior was described with two features; the frequency response function and the power spectral density band power. Using both features, all experimentally simulated loosening cases could clearly be distinguished from the fully cemented cases. By complementing the experimental work with an in silico study, it was shown that loosening of approximately 14% of the implant surface on the lateral and medial side was detectable with a vibration-based method. Proximal lateral and medial locations on the tibia or locations toward the edge of the implant surface measured in the longitudinal direction were the most sensitive measurement and excitation locations to assess implant fixation. These results contribute to the development of vibration-based methods as an alternative follow-up method to detect loosened tibia implants. Copyright © 2017 IPEM. Published by Elsevier Ltd. All rights reserved.

Diffusive and quantum effects of water properties in different states of matter

International Nuclear Information System (INIS)

Yeh, Kuan-Yu; Huang, Shao-Nung; Chen, Li-Jen; Lin, Shiang-Tai

2014-01-01

The enthalpy, entropy, and free energy of water are important physical quantities for understanding many interesting phenomena in biological systems. However, conventional approaches require different treatments to incorporate quantum and diffusive effects of water in different states of matter. In this work, we demonstrate the use of the two-phase thermodynamic (2PT) model as a unified approach to obtain the properties of water over the whole phase region of water from short (∼20 ps) classical molecular dynamics trajectories. The 2PT model provides an effective way to separate the diffusive modes (gas-like component) from the harmonic vibrational modes (solid-like component) in the vibrational density of states (DoS). Therefore, both diffusive and quantum effect can be properly accounted for water by applying suitable statistical mechanical weighting functions to the DoS components. We applied the 2PT model to systematically examine the enthalpy, entropy, and their temperature dependence of five commonly used rigid water models. The 2PT results are found to be consistent with those obtained from more sophisticated calculations. While the thermodynamic properties determined from different water models are largely similar, the phase boundary determined from the equality of free energy is very sensitive to the small inaccuracy in the values of enthalpy and absolute entropy. The enthalpy, entropy, and diffusivity of water are strongly interrelated, which challenge further improvement of rigid water model via parameter fitting. Our results show that the 2PT is an efficient method for studying the properties of water under various chemical and biological environments

XRD, vibrational spectra and quantum chemical studies of an anticancer drug: 6-Mercaptopurine.

Science.gov (United States)

Kumar, S Suresh; Athimoolam, S; Sridhar, B

2015-07-05

The single crystal of the hydrated anticancer drug, 6-Mercaptopurine (6-MP), has been grown by slow evaporation technique under room temperature. The structure was determined by single crystal X-ray diffraction. The vibrational spectral analysis was carried out using Laser Raman and FT-IR spectroscopy in the range of 3300-100 and 4000-400 cm(-1). The single crystal X-ray studies shows that the crystal packing is dominated by N-H⋯O and O-H⋯N classical hydrogen bonds leading to a hydrogen bonded ensemble. This classical hydrogen bonds were further connected through O-H⋯S hydrogen bond to form two primary ring R4(4)(16) and R4(4)(12) motifs. These two primary ring motifs are interlinked with each other to build a ladder like structure. These ladders are connected through N-H⋯N hydrogen bond along c-axis of the unit cell through chain C(5) motifs. Further, the strength of the hydrogen bonds is studied through vibrational spectral measurements. The shifting of bands due to the intermolecular interactions was also analyzed in the solid crystalline state. Geometrical optimizations of the drug molecule were done by Density Functional Theory (DFT) using the B3LYP function and Hartree-Fock (HF) level with 6-311++G(d,p) basis set. The optimized molecular geometry and computed vibrational spectra are compared with experimental results which show significant agreement. The natural bond orbital (NBO) analysis was carried out to interpret hyperconjugative interaction and intramolecular charge transfer (ICT). The chemical hardness, electro-negativity and chemical potential of the molecule are carried out by HOMO-LUMO plot. In which, the frontier orbitals has lower band gap value indicating the possible pharmaceutical activity of the molecule. Copyright © 2015 Elsevier B.V. All rights reserved.

Application of comparative vibrational spectroscopic and mechanistic studies in analysis of fisetin structure

Science.gov (United States)

Dimitrić Marković, Jasmina M.; Marković, Zoran S.; Milenković, Dejan; Jeremić, Svetlana

2011-12-01

This paper addresses experimental and theoretical research in fisetin (2-(3,4-dihydroxyphenyl)-3,7-dihydroxychromen-4-one) structure by means of experimental IR and Raman spectroscopies and mechanistic calculations. Density Functional Theory calculations, with M05-2X functional and the 6-311+G (2df, p) basis set implemented in the Gaussian 09 package, are performed with the aim to support molecular structure, vibrational bands' positions and their intensities. Potential energy distribution (PED) values and the description of the largest vibrational contributions to the normal modes are calculated. The most intense bands appear in the 1650-1500 cm -1 wavenumber region. This region involves a combination of the C dbnd O, C2 dbnd C3 and C-C stretching vibrational modes. Most of the bands in the 1500-1000 cm -1 range involve C-C stretching, O-C stretching and in-plane C-C-H, C-O-H, C-C-O and C-C-C bending vibrations of the rings. The region below 1000 cm -1 is characteristic to the combination of in plane C-C-C-H, H-C-C-H, C-C-C-C, C-C-O-C and out of plane O-C-C-C, C-C-O-C, C-C-C-C torsional modes. The Raman spectra of baicalein and quercetin were used for qualitative comparison with fisetin spectrum and verification of band assignments. The applied detailed vibrational spectral analysis and the assignments of the bands, proposed on the basis of fundamentals, reproduced the experimental results with high degree of accuracy.

Spectral finite element methods for solving fractional differential equations with applications in anomalous transport

Energy Technology Data Exchange (ETDEWEB)

Carella, Alfredo Raul

2012-09-15

Quantifying species transport rates is a main concern in chemical and petrochemical industries. In particular, the design and operation of many large-scale industrial chemical processes is as much dependent on diffusion as it is on reaction rates. However, the existing diffusion models sometimes fail to predict experimentally observed behaviors and their accuracy is usually insufficient for process optimization purposes. Fractional diffusion models offer multiple possibilities for generalizing Flick's law in a consistent manner in order to account for history dependence and nonlocal effects. These models have not been extensively applied to the study of real systems, mainly due to their computational cost and mathematical complexity. A least squares spectral formulation was developed for solving fractional differential equations. The proposed method was proven particularly well-suited for dealing with the numerical difficulties inherent to fractional differential operators. The practical implementation was explained in detail in order to enhance reproducibility, and directions were specified for extending it to multiple dimensions and arbitrarily shaped domains. A numerical framework based on the least-squares spectral element method was developed for studying and comparing anomalous diffusion models in pellets. This simulation tool is capable of solving arbitrary integro-differential equations and can be effortlessly adapted to various problems in any number of dimensions. Simulations of the flow around a cylindrical particle were achieved by extending the functionality of the developed framework. A test case was analyzed by coupling the boundary condition yielded by the fluid model with two families of anomalous diffusion models: hyperbolic diffusion and fractional diffusion. Qualitative guidelines for determining the suitability of diffusion models can be formulated by complementing experimental data with the results obtained from this approach.(Author)

CMB spectral distortions as solutions to the Boltzmann equations

Energy Technology Data Exchange (ETDEWEB)

Ota, Atsuhisa, E-mail: a.ota@th.phys.titech.ac.jp [Department of Physics, Tokyo Institute of Technology, Tokyo 152-8551 (Japan)

2017-01-01

We propose to re-interpret the cosmic microwave background spectral distortions as solutions to the Boltzmann equation. This approach makes it possible to solve the second order Boltzmann equation explicitly, with the spectral y distortion and the momentum independent second order temperature perturbation, while generation of μ distortion cannot be explained even at second order in this framework. We also extend our method to higher order Boltzmann equations systematically and find new type spectral distortions, assuming that the collision term is linear in the photon distribution functions, namely, in the Thomson scattering limit. As an example, we concretely construct solutions to the cubic order Boltzmann equation and show that the equations are closed with additional three parameters composed of a cubic order temperature perturbation and two cubic order spectral distortions. The linear Sunyaev-Zel'dovich effect whose momentum dependence is different from the usual y distortion is also discussed in the presence of the next leading order Kompaneets terms, and we show that higher order spectral distortions are also generated as a result of the diffusion process in a framework of higher order Boltzmann equations. The method may be applicable to a wider class of problems and has potential to give a general prescription to non-equilibrium physics.

VIBRONIC PROGRESSIONS IN SEVERAL DIFFUSE INTERSTELLAR BANDS

International Nuclear Information System (INIS)

Duley, W. W.; Kuzmin, Stanislav

2010-01-01

A number of vibronic progressions based on low-energy vibrational modes of a large molecule have been found in the diffuse interstellar band (DIB) spectrum of HD 183143. Four active vibrational modes have been identified with energies at 5.18 cm -1 , 21.41 cm -1 , 31.55 cm -1 , and 34.02 cm -1 . The mode at 34.02 cm -1 was previously recognized by Herbig. Four bands are associated with this molecule, with origins at 6862.61 A, 6843.64 A, 6203.14 A, and 5545.11 A (14589.1 cm -1 , 14608.08 cm -1 , 16116.41 cm -1 , and 18028.9 cm -1 , respectively). The progressions are harmonic and combination bands are observed involving all modes. The appearance of harmonic, rather than anharmonic, terms in these vibronic progressions is consistent with torsional motion of pendant rings, suggesting that the carrier is a 'floppy' molecule. Some constraints on the type and size of the molecule producing these bands are discussed.

Raman spectral properties of squamous cell carcinoma of oral tissues and cells

Science.gov (United States)

Su, L.; Sun, Y. F.; Chen, Y.; Chen, P.; Shen, A. G.; Wang, X. H.; Jia, J.; Zhao, Y. F.; Zhou, X. D.; Hu, J. M.

2012-01-01

Early diagnosis is the key of the improved survival rates of oral cancer. Raman spectroscopy is sensitive to the early changes of molecular composition and structure that occur in benign lesion during carcinogenesis. In this study, in situ Raman analysis provided distinct spectra that can be used to discriminate between normal and malignant tissues, as well as normal and cancer cells. The biochemical variations between different groups were analyzed by the characteristic bands by comparing the normalized mean spectra. Spectral profiles of normal, malignant conditions show pronounced differences between one another, and multiple Raman markers associated with DNA and protein vibrational modes have been identified that exhibit excellent discrimination power for cancer sample identification. Statistical analyses of the Raman data and classification using principal component analysis (PCA) are shown to be effective for the Raman spectral diagnosis of oral mucosal diseases. The results indicate that the biomolecular differences between normal and malignant conditions are more obviously at the cellular level. This technique could provide a research foundation for the Raman spectral diagnosis of oral mucosal diseases.

Spectral intensities in cubic systems. I. Progressions based upon parity vibrational modes

Energy Technology Data Exchange (ETDEWEB)

Acevedo, R.; Vasquez, S.O. [Department of Basic Chemistry, Faculty of Physical and Mathematical Sciences, University of Chile. Tupper 2069, Casilla 2777, Santiago, Chile (Chile); Meruane, T. [Department of Chemistry, Universidad Metropolitana de Ciencias de la Educacion. Av. J.P. Alessandri 774, Casilla 147, C. Santiago, Chile (Chile); Poblete, V. [Department of Nuclear Materials, Lo Aguirre, Comision Chilena de Energia Nuclear. Amunategui 95, Casilla 188-D, Santiago, Chile (Chile); Pozo, J. [Facultad de Ciencias de la Ingenieria. Universidad Diego Portales. Casilla 298-V, Santiago, Chile (Chile)

1998-12-01

The well-resolved emission and absorption spectra of centrosymmetric coordination compounds of the transition metal ions have been used widely to provide the experimental data against which to test theoretical models of vibronic intensities. With reference to the {sup 2} E{sub g} {yields} {sup 4} A{sub 2g} luminescence transition, at a perfect octahedral site in Cs{sub 2}SiF{sub 6}, over than one hundred vibronic lines are observed with line widths of a few wavenumber spread over some 3000 cm{sup -1}. This paper reports a through examination of both the electronic and vibrational factors, which influences the observed vibronic intensities of the various assigned and identified lines in the spectra of the MnF{sub 6} {sup 2-} complex ion in the Cs{sub 2}SiF{sub 6} cubic lattice. The origin and nature of higher order vibronic interactions are analysed on the basis of a symmetrized vibronic crystal field-ligand polarization model. (Author)

Calculation of the vibrational linewidth and line shape of Raman spectra using the relaxation function : I. method and application to nitrogen

NARCIS (Netherlands)

Kooi, M.E.; Smit, F.; Michels, J.P.J.; Schouten, J.A.

2000-01-01

The spectral line shape of the fundamental vibration of nitrogen is calculated from molecular dynamics simulations by determining the Fourier transform of the relaxation function. It has been applied to the fluid phase at various pressures and temperatures, and to solid d-N2. The validity of the

Multi-layer Lanczos iteration approach to calculations of vibrational energies and dipole transition intensities for polyatomic molecules

International Nuclear Information System (INIS)

Yu, Hua-Gen

2015-01-01

We report a rigorous full dimensional quantum dynamics algorithm, the multi-layer Lanczos method, for computing vibrational energies and dipole transition intensities of polyatomic molecules without any dynamics approximation. The multi-layer Lanczos method is developed by using a few advanced techniques including the guided spectral transform Lanczos method, multi-layer Lanczos iteration approach, recursive residue generation method, and dipole-wavefunction contraction. The quantum molecular Hamiltonian at the total angular momentum J = 0 is represented in a set of orthogonal polyspherical coordinates so that the large amplitude motions of vibrations are naturally described. In particular, the algorithm is general and problem-independent. An application is illustrated by calculating the infrared vibrational dipole transition spectrum of CH based on the ab initio T8 potential energy surface of Schwenke and Partridge and the low-order truncated ab initio dipole moment surfaces of Yurchenko and co-workers. A comparison with experiments is made. The algorithm is also applicable for Raman polarizability active spectra

Effects of self-similar correlations on the spectral line shape in the neutral gas

International Nuclear Information System (INIS)

Kharintsev, S.S.; Salakhov, M.Kh.

2001-01-01

The paper is devoted to the study of the influence of self-similar correlations on the Doppler and pressure broadening within the non-equilibrium Boltzmann gas. The diffuse model for the thermal motion of the radiator and the self-similar mechanism of interference of scalar perturbations for phase shifts of an atomic oscillator are developed. It is shown that taking into account self-similar correlation in a description of the spectral line shape allows one to explain, on the one hand, the additional spectral line Dicke-narrowing in the Doppler regime, and, on the other hand, the asymmetry in wings of the spectral line in a high pressure region

Laser enhanced attachment in diffuse discharges

International Nuclear Information System (INIS)

Giesselmann, M.; Pashaie, B.; Kristiansen, M.; Schaefer, G.

1987-01-01

Measurements of the effect of laser enhanced attachment on externally sustained diffuse discharges are reported. Optical control of diffuse discharges is a promising way of upgrading the performance of e-beam controlled opening switches for repetitive operation. Ideal gases should exhibit a negligible attachment cross section for low E/N values (switch closed) in the ground state and strong attaching properties upon optical excitation in an E/N range between the conducting state and self breakdown of the switch. The ratio of resistivity change in these experiments is much higher than in previous investigations. In this investigation the attachment rate of an electronegative gas component, representing approximately 1% of the gas in the discharge volume, was increased by means of vibrational excitation with a pulsed IR-laser beam. Molecules exhibiting a strongly increased attachment rate upon IR-excitation are vinyl-chloride, vinyl flouride and trifluoroethylene, which has been verified in preliminary experiments. All experiments reported were performed with vinyl chloride and trifluoroethylene

Diffuse reflectance infrared Fourier-Transform spectra of selected organic compounds

Energy Technology Data Exchange (ETDEWEB)

Harmon, S.H.; Caton, J.E.

1982-05-01

Diffuse reflectance infrared spectra of a variety of different organic compounds have been determined. Profiles of the spectra along with the location and relative intensity of the principal bands have been included for each compound studied. In addition both diffuse reflectance and transmittance infrared spectra were obtained for the same samples, and the spectral results were compared. Although some minor variations are observed between a diffuse reflectance spectrum and the corresponding transmittance spectrum, the diffuse reflectance is quite useful and may be a superior technique for the study of many samples because it possesses an inherently higher signal-to-noise response, requires less sample preparation and allows a very wide range of samples (solids, liquids of low volatility, neat sample, or sample diluted in a reflecting medium) to be studied under very similar conditions.

Pronounced low-frequency vibrational thermal transport in C60 fullerite realized through pressure-dependent molecular dynamics simulations

Science.gov (United States)

Giri, Ashutosh; Hopkins, Patrick E.

2017-12-01

Fullerene condensed-matter solids can possess thermal conductivities below their minimum glassy limit while theorized to be stiffer than diamond when crystallized under pressure. These seemingly disparate extremes in thermal and mechanical properties raise questions into the pressure dependence on the thermal conductivity of C60 fullerite crystals, and how the spectral contributions to vibrational thermal conductivity changes under applied pressure. To answer these questions, we investigate the effect of strain on the thermal conductivity of C60 fullerite crystals via pressure-dependent molecular dynamics simulations under the Green-Kubo formalism. We show that the thermal conductivity increases rapidly with compressive strain, which demonstrates a power-law relationship similar to their stress-strain relationship for the C60 crystals. Calculations of the density of states for the crystals under compressive strains reveal that the librational modes characteristic in the unstrained case are diminished due to densification of the molecular crystal. Over a large compression range (0-20 GPa), the Leibfried-Schlömann equation is shown to adequately describe the pressure dependence of thermal conductivity, suggesting that low-frequency intermolecular vibrations dictate heat flow in the C60 crystals. A spectral decomposition of the thermal conductivity supports this hypothesis.

Kinetic energy dependence of carrier diffusion in a GaAs epilayer studied by wavelength selective PL imaging

Energy Technology Data Exchange (ETDEWEB)

Zhang, S. [University of North Carolina at Charlotte, Charlotte, NC 28223 (United States); Providence High School, Charlotte, NC 28270 (United States); Su, L.Q.; Kon, J. [University of North Carolina at Charlotte, Charlotte, NC 28223 (United States); Gfroerer, T. [Davidson College, Davidson, NC 28035 (United States); Wanlass, M.W. [National Renewable Energy Laboratory, Golden, CO 80401 (United States); Zhang, Y., E-mail: yong.zhang@uncc.edu [University of North Carolina at Charlotte, Charlotte, NC 28223 (United States)

2017-05-15

Photoluminescence (PL) imaging has been shown to be an efficient technique for investigating carrier diffusion in semiconductors. In the past, the measurement was typically carried out by measuring at one wavelength (e.g., at the band gap) or simply the whole emission band. At room temperature in a semiconductor like GaAs, the band-to-band PL emission may occur in a spectral range over 200 meV, vastly exceeding the average thermal energy of about 26 meV. To investigate the potential dependence of the carrier diffusion on the carrier kinetic energy, we performed wavelength selective PL imaging on a GaAs double hetero-structure in a spectral range from about 70 meV above to 50 meV below the bandgap, extracting the carrier diffusion lengths at different PL wavelengths by fitting the imaging data to a theoretical model. The results clearly show that the locally generated carriers of different kinetic energies mostly diffuse together, maintaining the same thermal distribution throughout the diffusion process. Potential effects related to carrier density, self-absorption, lateral wave-guiding, and local heating are also discussed.

A fractal derivative model for the characterization of anomalous diffusion in magnetic resonance imaging

Science.gov (United States)

Liang, Yingjie; Ye, Allen Q.; Chen, Wen; Gatto, Rodolfo G.; Colon-Perez, Luis; Mareci, Thomas H.; Magin, Richard L.

2016-10-01

Non-Gaussian (anomalous) diffusion is wide spread in biological tissues where its effects modulate chemical reactions and membrane transport. When viewed using magnetic resonance imaging (MRI), anomalous diffusion is characterized by a persistent or 'long tail' behavior in the decay of the diffusion signal. Recent MRI studies have used the fractional derivative to describe diffusion dynamics in normal and post-mortem tissue by connecting the order of the derivative with changes in tissue composition, structure and complexity. In this study we consider an alternative approach by introducing fractal time and space derivatives into Fick's second law of diffusion. This provides a more natural way to link sub-voxel tissue composition with the observed MRI diffusion signal decay following the application of a diffusion-sensitive pulse sequence. Unlike previous studies using fractional order derivatives, here the fractal derivative order is directly connected to the Hausdorff fractal dimension of the diffusion trajectory. The result is a simpler, computationally faster, and more direct way to incorporate tissue complexity and microstructure into the diffusional dynamics. Furthermore, the results are readily expressed in terms of spectral entropy, which provides a quantitative measure of the overall complexity of the heterogeneous and multi-scale structure of biological tissues. As an example, we apply this new model for the characterization of diffusion in fixed samples of the mouse brain. These results are compared with those obtained using the mono-exponential, the stretched exponential, the fractional derivative, and the diffusion kurtosis models. Overall, we find that the order of the fractal time derivative, the diffusion coefficient, and the spectral entropy are potential biomarkers to differentiate between the microstructure of white and gray matter. In addition, we note that the fractal derivative model has practical advantages over the existing models from the

Using frequency response functions to manage image degradation from equipment vibration in the Daniel K. Inouye Solar Telescope

Science.gov (United States)

McBride, William R.; McBride, Daniel R.

2016-08-01

The Daniel K Inouye Solar Telescope (DKIST) will be the largest solar telescope in the world, providing a significant increase in the resolution of solar data available to the scientific community. Vibration mitigation is critical in long focal-length telescopes such as the Inouye Solar Telescope, especially when adaptive optics are employed to correct for atmospheric seeing. For this reason, a vibration error budget has been implemented. Initially, the FRFs for the various mounting points of ancillary equipment were estimated using the finite element analysis (FEA) of the telescope structures. FEA analysis is well documented and understood; the focus of this paper is on the methods involved in estimating a set of experimental (measured) transfer functions of the as-built telescope structure for the purpose of vibration management. Techniques to measure low-frequency single-input-single-output (SISO) frequency response functions (FRF) between vibration source locations and image motion on the focal plane are described. The measurement equipment includes an instrumented inertial-mass shaker capable of operation down to 4 Hz along with seismic accelerometers. The measurement of vibration at frequencies below 10 Hz with good signal-to-noise ratio (SNR) requires several noise reduction techniques including high-performance windows, noise-averaging, tracking filters, and spectral estimation. These signal-processing techniques are described in detail.

Vibration analysis and vibration damage assessment in nuclear and process equipment

International Nuclear Information System (INIS)

Pettigrew, M.J.; Taylor, C.E.; Fisher, N.J.; Yetisir, M.; Smith, B.A.W.

1997-01-01

Component failures due to excessive flow-induced vibration are still affecting the performance and reliability of process and nuclear components. The purpose of this paper is to discuss flow-induced vibration analysis and vibration damage prediction. Vibration excitation mechanisms are described with particular emphasis on fluid elastic instability. The dynamic characteristics of process and power equipment are explained. The statistical nature of some parameters, in particular support conditions, is discussed. The prediction of fretting-wear damage is approached from several points-of-view. An energy approach to formulate fretting-wear damage is proposed. (author)

Vibration of hydraulic machinery

CERN Document Server

Wu, Yulin; Liu, Shuhong; Dou, Hua-Shu; Qian, Zhongdong

2013-01-01

Vibration of Hydraulic Machinery deals with the vibration problem which has significant influence on the safety and reliable operation of hydraulic machinery. It provides new achievements and the latest developments in these areas, even in the basic areas of this subject. The present book covers the fundamentals of mechanical vibration and rotordynamics as well as their main numerical models and analysis methods for the vibration prediction. The mechanical and hydraulic excitations to the vibration are analyzed, and the pressure fluctuations induced by the unsteady turbulent flow is predicted in order to obtain the unsteady loads. This book also discusses the loads, constraint conditions and the elastic and damping characters of the mechanical system, the structure dynamic analysis, the rotor dynamic analysis and the system instability of hydraulic machines, including the illustration of monitoring system for the instability and the vibration in hydraulic units. All the problems are necessary for vibration pr...

Vibrations and Eigenvalues

Indian Academy of Sciences (India)

We make music by causing strings, membranes, or air columns to vibrate. Engineers design safe structures by control- ling vibrations. I will describe to you a very simple vibrating system and the mathematics needed to analyse it. The ideas were born in the work of Joseph-Louis Lagrange (1736–1813), and I begin by quot-.

Spectroscopie du Furanne et du Thiophene Par Diffusion Inelastique D'electrons

Science.gov (United States)

Lotfi, Said

Nous avons etudie les molecules de furanne ( rm C_4H_4O) et de thiophene (rm C_4H_4O) au moyen de la spectroscopie de diffusion inelastique d'electrons. Pour (rm C_4H_4O), les spectres realises dans differentes conditions d'energie d'impact et d'angle de diffusion contiennent des singularites ou des families de pics correspondant a: (1) des vibrations de l'etat fondamental dans le domaine 0-0.5 eV, (2) des etats triplets ^3 B_1 et ^3 A_1 qui dominent la region 3-5.5 eV, (3) des etats de valences, entre 5 et 10 eV, dont certains son accompagnes de progressions vibrationnelles, soit ~ A _1B_2, ~ B ^1A_1 et ~ C ^1A_1, (4) toujours entre 5 et 10 eV, deux series de Ryhdberg (rm 1a_2to nda_2 et rm 1a_2to npb_2) qui convergent vers la premiere limite d'ionisation de la molecule, avec une progression vibrationnelle associee au mdoe nu_4 pour la seconde, et une troisieme serie (rm 2b_1to nsa_1 ) convergent vers la seconde limite d'ionisation accompagnee de la progression de mode nu _1. Pour rm C_4H_4S, nos spectres presentent les memes etats de vibration et les memes etats triplets que pour rm C_4H _4O. Nous avons releve egalement, dans la region de 5 a 10 eV, des etats de valence ~ A ^1A_1 (ou ~ A ^1B_2), ~ B ^1A_1 (ou ~ B ^1B _2) et ~ C ^1A_1 (ou ~ C ^1B_2). Pour la premiere fois, par la spectroscopie de diffusion inelastique d'electrons, de nombreux pics ont ete identifies et attribues, dans le cadre de ce travail. Il s'agit, notamment, des etats de vibration de l'etat electronique fondamental de ces molecules et egalement de certains etats de Rydberg dans le cas du furanne.

Spectral Analysis of Non-ideal MRI Modes: The Effect of Hall Diffusion

Energy Technology Data Exchange (ETDEWEB)

Mohandas, Gopakumar; Pessah, Martin E., E-mail: gopakumar@nbi.ku.dk, E-mail: mpessah@nbi.ku.dk [Niels Bohr International Academy, Niels Bohr Institute, Blegdamsvej 17, DK-2100, Copenhagen Ø (Denmark)

2017-03-20

The effect of magnetic field diffusion on the stability of accretion disks is a problem that has attracted considerable interest of late. In particular, the Hall effect has the potential to bring about remarkable changes in the dynamical behavior of disks that are without parallel. In this paper, we conduct a systematic examination of the linear eigenmodes in a weakly magnetized differentially rotating gas with a special focus on Hall diffusion. We first develop a geometrical representation of the eigenmodes and provide a detailed quantitative description of the polarization properties of the oscillatory modes under the combined influence of the Coriolis and Hall effects. We also analyze the effects of magnetic diffusion on the structure of the unstable modes and derive analytical expressions for the kinetic and magnetic stresses and energy densities associated with the non-ideal magnetorotational instability (MRI). Our analysis explicitly demonstrates that, if the dissipative effects are relatively weak, the kinetic stresses and energies make up the dominant contribution to the total stress and energy density when the equilibrium angular momentum and magnetic field vectors are anti-parallel. This is in sharp contrast to what is observed in the case of the ideal or dissipative MRI. We conduct shearing box simulations and find very good agreement with the results derived from linear theory. Because the modes under consideration are also exact solutions of the nonlinear equations, the unconventional nature of the kinetic and magnetic stresses may have significant implications for the nonlinear evolution in some regions of protoplanetary disks.

Handbook Of Noise And Vibration

International Nuclear Information System (INIS)

1995-12-01

This book is about noise and vibration. The first chapter has explanations of noise such as basic of sound, influence of noise, assessment of noise, measurement of prevention of noise and technology, case of noise measurement and soundproof. The second chapter describes vibration with outline, theory of vibration, interpretation of vibration, measurement for reduction of vibration, case of design of protection against vibration. It deals with related regulation and method of measurement.

Optimised Spectral Kurtosis for bearing diagnostics under electromagnetic interference

Science.gov (United States)

Smith, Wade A.; Fan, Zhiqi; Peng, Zhongxiao; Li, Huaizhong; Randall, Robert B.

2016-06-01

The selection of the optimal demodulation frequency band is a significant step in bearing fault diagnosis because it determines whether the fault information can be extracted from the demodulated signal via envelope analysis. Two well-known methods for selecting the demodulation band are the Fast Kurtogram, based on the kurtosis of the filtered time signal, and the Protrugram, which uses the kurtosis of the envelope (amplitude) spectrum. Although these two methods have been successfully applied in many cases, the authors have observed that they may fail in specific environments, such as in the presence of electromagnetic interference (EMI) or other impulsive masking signals. In this paper, a simple spectral kurtosis-based approach is proposed for selecting the best demodulation band to extract bearing fault-related impulsive content from vibration signals contaminated with strong EMI. The method is applied to vibration signals obtained from a planetary gearbox test rig with planet bearings seeded with inner and outer race faults. Results from the Fast Kurtogram and Protrugram methods are also included for comparison. The proposed approach is found to exhibit superior diagnostic performance in the presence of intense EMI. Another contribution of the paper is to introduce and explain the issue of EMI to the condition monitoring community. The paper outlines the characteristics of EMI arising from widely-used variable frequency drives, and these characteristics are used to simulate an EMI-contaminated vibration signal to further test the performance of the proposed approach. Although EMI has been acknowledged as a serious problem in many industrial cases, there have been very few studies showing its adverse effects on machine diagnostics. It is important for analysts to be able to identify EMI in measured vibration signals, lest it interfere with the analysis undertaken.

Vibration mode and vibration shape under excitation of a three phase model transformer core

Science.gov (United States)

Okabe, Seiji; Ishigaki, Yusuke; Omura, Takeshi

2018-04-01

Structural vibration characteristics and vibration shapes under three-phase excitation of a archetype transformer core were investigated to consider their influences on transformer noise. Acoustic noise and vibration behavior were measured in a three-limb model transformer core. Experimental modal analysis by impact test was performed. The vibration shapes were measured by a laser scanning vibrometer at different exciting frequencies. Vibration amplitude of the core in out-of-plane direction were relatively larger than those in other two in-plane directions. It was consistent with the result that the frequency response function of the core in out-of-plane direction was larger by about 20 dB or more than those in in-plane directions. There were many vibration modes having bending deformation of limbs in out-of-plane direction. The vibration shapes of the core when excited at 50 Hz and 60 Hz were almost the same because the fundamental frequencies of the vibration were not close to the resonance frequencies. When excitation frequency was 69 Hz which was half of one of the resonance frequencies, the vibration shape changed to the one similar to the resonance vibration mode. Existence of many vibration modes in out-of-plane direction of the core was presumed to be a reason why frequency characteristics of magnetostriction and transformer noise do not coincide.

Diffuse Reflectance Spectroscopy of Human Skin Using a Commercial Fiber Optic Spectrometer

International Nuclear Information System (INIS)

Atencio, J. A. Delgado; Rodriguez, M. Cunill; Montiel, S. Vazquez y; Castro, Jorge; Rodriguez, A. Cornejo; Gutierrez, J. L.; Martinez, F.; Gutierrez, B.; Orozco, E.

2008-01-01

Diffuse reflectance spectroscopy is a reliable and easy to implement technique in human tissue characterization. In this work we evaluate the performance of the commercial USB4000 miniature fiber optic spectrometer in the in-vivo measurement of the diffuse reflectance spectra of different healthy skin sites and lesions in a population of 54 volunteers. Results show, that this spectrometer reproduces well the typical signatures of skin spectra over the 400-1000 nm region. Remarkable spectral differences exist between lesions and normal surrounding skin. A diffusion-based model was used to simulate reflectance spectra collected by the optical probe of the system

Vibration Analysis of Beam and Block Precast Slab System due to Human Vibrations

Science.gov (United States)

Chik, T. N. T.; Kamil, M. R. H.; Yusoff, N. A.

2018-04-01

Beam and block precast slabs system are very efficient which generally give maximum structural performance where their voids based on the design of the unit soffit block allow a significant reduction of the whole slab self-weight. Initially for some combinations of components or the joint connection of the structural slab, this structural system may be susceptible to excessive vibrations that could effects the performance and also serviceability. Dynamic forces are excited from people walking and jumping which produced vibrations to the slab system in the buildings. Few studies concluded that human induced vibration on precast slabs system may be harmful to structural performance and mitigate the human comfort level. This study will investigate the vibration analysis of beam and block precast slab by using finite element method at the school building. Human activities which are excited from jumping and walking will induce the vibrations signal to the building. Laser Doppler Vibrometer (LDV) was used to measure the dynamic responses of slab towards the vibration sources. Five different points were assigned specifically where each of location will determine the behaviour of the entire slabs. The finite element analyses were developed in ABAQUS software and the data was further processed in MATLAB ModalV to assess the vibration criteria. The results indicated that the beam and block precast systems adequate enough to the vibration serviceability and human comfort criteria. The overall vibration level obtained was fell under VC-E curve which it is generally under the maximum permissible level of vibrations. The vibration level on the slab is acceptable within the limit that have been used by Gordon.

Application of comparative vibrational spectroscopic and mechanistic studies in analysis of fisetin structure.

Science.gov (United States)

Dimitrić Marković, Jasmina M; Marković, Zoran S; Milenković, Dejan; Jeremić, Svetlana

2011-12-01

This paper addresses experimental and theoretical research in fisetin (2-(3,4-dihydroxyphenyl)-3,7-dihydroxychromen-4-one) structure by means of experimental IR and Raman spectroscopies and mechanistic calculations. Density Functional Theory calculations, with M05-2X functional and the 6-311+G (2df, p) basis set implemented in the Gaussian 09 package, are performed with the aim to support molecular structure, vibrational bands' positions and their intensities. Potential energy distribution (PED) values and the description of the largest vibrational contributions to the normal modes are calculated. The most intense bands appear in the 1650-1500 cm(-1) wavenumber region. This region involves a combination of the CO, C2C3 and C-C stretching vibrational modes. Most of the bands in the 1500-1000 cm(-1) range involve C-C stretching, O-C stretching and in-plane C-C-H, C-O-H, C-C-O and C-C-C bending vibrations of the rings. The region below 1000 cm(-1) is characteristic to the combination of in plane C-C-C-H, H-C-C-H, C-C-C-C, C-C-O-C and out of plane O-C-C-C, C-C-O-C, C-C-C-C torsional modes. The Raman spectra of baicalein and quercetin were used for qualitative comparison with fisetin spectrum and verification of band assignments. The applied detailed vibrational spectral analysis and the assignments of the bands, proposed on the basis of fundamentals, reproduced the experimental results with high degree of accuracy. Copyright © 2011 Elsevier B.V. All rights reserved.

Transport through a vibrating quantum dot: Polaronic effects

International Nuclear Information System (INIS)

Koch, T; Alvermann, A; Fehske, H; Loos, J; Bishop, A R

2010-01-01

We present a Green's function based treatment of the effects of electron-phonon coupling on transport through a molecular quantum dot in the quantum limit. Thereby we combine an incomplete variational Lang-Firsov approach with a perturbative calculation of the electron-phonon self energy in the framework of generalised Matsubara Green functions and a Landauer-type transport description. Calculating the ground-state energy, the dot single-particle spectral function and the linear conductance at finite carrier density, we study the low-temperature transport properties of the vibrating quantum dot sandwiched between metallic leads in the whole electron-phonon coupling strength regime. We discuss corrections to the concept of an anti-adiabatic dot polaron and show how a deformable quantum dot can act as a molecular switch.

Ship Vibrations

DEFF Research Database (Denmark)

Sørensen, Herman

1997-01-01

Methods for calculating natural frequencies for ship hulls and for plates and panels.Evaluation of the risk for inconvenient vibrations on board......Methods for calculating natural frequencies for ship hulls and for plates and panels.Evaluation of the risk for inconvenient vibrations on board...

Over-the-road shock and vibration testing of the radioisotope thermoelectric generator transportation system

International Nuclear Information System (INIS)

Becker, D.L.

1997-01-01

Radioisotope Thermoelectric Generators (RTG) convert heat generated by radioactive decay into electricity through the use of thermocouples. The RTGs have a long operating life, are reasonably lightweight, and require little or no maintenance, which make them particularly attractive for use in spacecraft. However, because RTGs contain significant quantities of radioactive materials, normally plutonium-238 and its decay products, they must be transported in packages built in accordance with Title 10, Code of Federal Regulations, Part 71 (10 CFR 71). To meet these regulations, a RTG Transportation System (RTGTS) that fully complies with 10 CFR 71 has been developed, which protects RTGs from adverse environmental conditions during normal conditions of transport (e.g., shock, vibration, and heat). To ensure the protection of RTGs from shock and vibration loadings during transport, extensive over-the-road testing was conducted on the RTG'S to obtain real-time recordings of accelerations of the air-ride suspension system trailer floor, packaging, and support structure. This paper provides an overview of the RTG'S, a discussion of the shock and vibration testing, and a comparison of the test results to the specified shock response spectra and power spectral density acceleration criteria

Application of optimal interation strategies to diffusion theory calculations

International Nuclear Information System (INIS)

Jones, R.B.

1978-01-01

The geometric interpretation of optimal (minimum computational time) iteration strategies is applied to one- and two-group, two-dimensional diffusion-theory calculations. The method is a ''spectral/time balance'' technique which weighs the convergence enhancement of the inner iteration procedure with that of the outer iteration loop and the time required to reconstruct the source. The diffusion-theory option of the discrete-ordinates transport code DOT3.5 was altered to incorporate the theoretical inner/outer decision logic. For the two-dimensional configuration considered, the optimal strategies reduced the total number of iterations performed for a given error criterion

On the dependence of the OH* Meinel emission altitude on vibrational level: SCIAMACHY observations and model simulations

Directory of Open Access Journals (Sweden)

J. P. Burrows

2012-09-01

Full Text Available Measurements of the OH Meinel emissions in the terrestrial nightglow are one of the standard ground-based techniques to retrieve upper mesospheric temperatures. It is often assumed that the emission peak altitudes are not strongly dependent on the vibrational level, although this assumption is not based on convincing experimental evidence. In this study we use Envisat/SCIAMACHY (Scanning Imaging Absorption spectroMeter for Atmospheric CHartographY observations in the near-IR spectral range to retrieve vertical volume emission rate profiles of the OH(3-1, OH(6-2 and OH(8-3 Meinel bands in order to investigate whether systematic differences in emission peak altitudes can be observed between the different OH Meinel bands. The results indicate that the emission peak altitudes are different for the different vibrational levels, with bands originating from higher vibrational levels having higher emission peak altitudes. It is shown that this finding is consistent with the majority of the previously published results. The SCIAMACHY observations yield differences in emission peak altitudes of up to about 4 km between the OH(3-1 and the OH(8-3 band. The observations are complemented by model simulations of the fractional population of the different vibrational levels and of the vibrational level dependence of the emission peak altitude. The model simulations reproduce the observed vibrational level dependence of the emission peak altitude well – both qualitatively and quantitatively – if quenching by atomic oxygen as well as multi-quantum collisional relaxation by O2 is considered. If a linear relationship between emission peak altitude and vibrational level is assumed, then a peak altitude difference of roughly 0.5 km per vibrational level is inferred from both the SCIAMACHY observations and the model simulations.

Bifurcation from stable holes to replicating holes in vibrated dense suspensions.

Science.gov (United States)

Ebata, H; Sano, M

2013-11-01

In vertically vibrated starch suspensions, we observe bifurcations from stable holes to replicating holes. Above a certain acceleration, finite-amplitude deformations of the vibrated surface continue to grow until void penetrates fluid layers, and a hole forms. We studied experimentally and theoretically the parameter dependence of the holes and their stabilities. In suspensions of small dispersed particles, the circular shapes of the holes are stable. However, we find that larger particles or lower surface tension of water destabilize the circular shapes; this indicates the importance of capillary forces acting on the dispersed particles. Around the critical acceleration for bifurcation, holes show intermittent large deformations as a precursor to hole replication. We applied a phenomenological model for deformable domains, which is used in reaction-diffusion systems. The model can explain the basic dynamics of the holes, such as intermittent behavior, probability distribution functions of deformation, and time intervals of replication. Results from the phenomenological model match the linear growth rate below criticality that was estimated from experimental data.

Flow-induced vibration characteristics of the BWR/5-201 jet pump

International Nuclear Information System (INIS)

LaCroix, L.V.

1982-09-01

A General Electric boiling water reactor BWR/5-201 jet pump was tested for flow-induced vibration (FIV) characteristics in the Large Steam Water Test Facility at Moss Landing, CA, during the period June-July 1978. High level periodic FIV were observed at reactor operating conditions (1027 psia, 532 0 F and prototypical flow rates) for the specific single jet pump assembly tested. High level FIV of similar amplitude and character have been shown capable of damaging jet pump components and associated support hardware if allowed to continue unchecked. High level FIV were effectively suppressed in two special cases tested: (1) lateral load (>500 lb) at the mixer to diffuser slip joint; and (2) a labyrinth seal (5 small, circumferential grooves) on the mixer at the slip joint. Stability criteria for the particular jet pump tested were developed from test data. A cause-effect relationship between the dynamic pressure within the slip joint and the jet pump vibration was established

A spectral analysis of the domain decomposed Monte Carlo method for linear systems

Energy Technology Data Exchange (ETDEWEB)

Slattery, S. R.; Wilson, P. P. H. [Engineering Physics Department, University of Wisconsin - Madison, 1500 Engineering Dr., Madison, WI 53706 (United States); Evans, T. M. [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37830 (United States)

2013-07-01

The domain decomposed behavior of the adjoint Neumann-Ulam Monte Carlo method for solving linear systems is analyzed using the spectral properties of the linear operator. Relationships for the average length of the adjoint random walks, a measure of convergence speed and serial performance, are made with respect to the eigenvalues of the linear operator. In addition, relationships for the effective optical thickness of a domain in the decomposition are presented based on the spectral analysis and diffusion theory. Using the effective optical thickness, the Wigner rational approximation and the mean chord approximation are applied to estimate the leakage fraction of stochastic histories from a domain in the decomposition as a measure of parallel performance and potential communication costs. The one-speed, two-dimensional neutron diffusion equation is used as a model problem to test the models for symmetric operators. In general, the derived approximations show good agreement with measured computational results. (authors)

A spectral analysis of the domain decomposed Monte Carlo method for linear systems

International Nuclear Information System (INIS)

Slattery, S. R.; Wilson, P. P. H.; Evans, T. M.

2013-01-01

The domain decomposed behavior of the adjoint Neumann-Ulam Monte Carlo method for solving linear systems is analyzed using the spectral properties of the linear operator. Relationships for the average length of the adjoint random walks, a measure of convergence speed and serial performance, are made with respect to the eigenvalues of the linear operator. In addition, relationships for the effective optical thickness of a domain in the decomposition are presented based on the spectral analysis and diffusion theory. Using the effective optical thickness, the Wigner rational approximation and the mean chord approximation are applied to estimate the leakage fraction of stochastic histories from a domain in the decomposition as a measure of parallel performance and potential communication costs. The one-speed, two-dimensional neutron diffusion equation is used as a model problem to test the models for symmetric operators. In general, the derived approximations show good agreement with measured computational results. (authors)

Spectral gamuts and spectral gamut mapping

Science.gov (United States)

Rosen, Mitchell R.; Derhak, Maxim W.

2006-01-01

All imaging devices have two gamuts: the stimulus gamut and the response gamut. The response gamut of a print engine is typically described in CIE colorimetry units, a system derived to quantify human color response. More fundamental than colorimetric gamuts are spectral gamuts, based on radiance, reflectance or transmittance units. Spectral gamuts depend on the physics of light or on how materials interact with light and do not involve the human's photoreceptor integration or brain processing. Methods for visualizing a spectral gamut raise challenges as do considerations of how to utilize such a data-set for producing superior color reproductions. Recent work has described a transformation of spectra reduced to 6-dimensions called LabPQR. LabPQR was designed as a hybrid space with three explicit colorimetric axes and three additional spectral reconstruction axes. In this paper spectral gamuts are discussed making use of LabPQR. Also, spectral gamut mapping is considered in light of the colorimetric-spectral duality of the LabPQR space.

Evaluation of vibration and vibration fatigue life for small bore pipe in nuclear power plants

International Nuclear Information System (INIS)

Wang Zhaoxi; Xue Fei; Gong Mingxiang; Ti Wenxin; Lin Lei; Liu Peng

2011-01-01

The assessment method of the steady state vibration and vibration fatigue life of the small bore pipe in the supporting system of the nuclear power plants is proposed according to the ASME-OM3 and EDF evaluation methods. The GGR supporting pipe system vibration is evaluated with this method. The evaluation process includes the filtration of inborn sensitivity, visual inspection, vibration tests, allowable vibration effective velocity calculation and vibration stress calculation. With the allowable vibration effective velocity calculated and the vibration velocity calculated according to the acceleration data tested, the filtrations are performed. The vibration stress at the welding coat is calculated with the spectrum method and compared with the allowable value. The response of the stress is calculated with the transient dynamic method, with which the fatigue life is evaluated with the Miners linear accumulation model. The vibration stress calculated with the spectrum method exceeds the allowable value, while the fatigue life calculated from the transient dynamic method is larger than the designed life with a big safety margin. (authors)

Proposal to use vibration analysis steering components and car body to monitor, for example, the state of unbalance wheel

Science.gov (United States)

Janczur, R.

2016-09-01

The results of road tests of car VW Passat equipped with tires of size 195/65 R15, on the influence of the unbalancing front wheel on vibration of the parts of steering system, steering wheel and the body of the vehicle have been presented in this paper. Unbalances wheels made using weights of different masses, placed close to the outer edge of the steel rim and checked on the machine Hunter GSP 9700 for balancing wheels. The recorded waveforms vibration steering components and car body, at different constant driving speeds, subjected to spectral analysis to determine the possibility of isolating vibration caused by unbalanced wheel in various states and coming from good quality asphalt road surface. The results were discussed in terms of the possibility of identifying the state of unbalancing wheels and possible changes in radial stiffness of the tire vibration transmitted through the system driving wheel on the steering wheel. Vibration analysis steering components and car body, also in the longitudinal direction, including information from the CAN bus of the state of motion of the car, can be used to monitor the development of the state of unbalance wheel, tire damage or errors shape of brake discs or brake drums, causing pulsations braking forces.

Conformational, structural, vibrational and quantum chemical analysis on 4-aminobenzohydrazide and 4-hydroxybenzohydrazide--a comparative study.

Science.gov (United States)

Arjunan, V; Jayaprakash, A; Carthigayan, K; Periandy, S; Mohan, S

2013-05-01

Experimental and theoretical quantum chemical studies were carried out on 4-hydroxybenzohydrazide (4HBH) and 4-aminobenzohydrazide (4ABH) using FTIR and FT-Raman spectral data. The structural characteristics and vibrational spectroscopic analysis were carried performed by quantum chemical methods with the hybrid exchange-correlation functional B3LYP using 6-31G(**), 6-311++G(**) and aug-cc-pVDZ basis sets. The most stable conformer of the title compounds have been determined from the analysis of potential energy surface. The stable molecular geometries, electronic and thermodynamic parameters, IR intensities, harmonic vibrational frequencies, depolarisation ratio and Raman intensities have been computed. Molecular electrostatic potential and frontier molecular orbitals were constructed to understand the electronic properties. The potential energy distributions (PEDs) were calculated to explain the mixing of fundamental modes. The theoretical geometrical parameters and the fundamental frequencies were compared with the experimental. The interactions of hydroxy and amino group substitutions on the characteristic vibrations of the ring and hydrazide group have been analysed. Copyright © 2013 Elsevier B.V. All rights reserved.

Diffuse X-ray scattering and far infrared absorption of barium and lead β" aluminas

DEFF Research Database (Denmark)

Hayes, W.; Kjær, Kristian; Pratt, F. L.

1985-01-01

The authors have carried out high-momentum-resolution studies in diffuse X-ray scattering of barium and lead B" aluminas in the temperature range 20-700 degrees C. They have also measured the vibrational spectra of these compounds between 2K and 300K in the energy range 10-100 cm-1. The results...

Off-axis Modal Active Vibration Control Of Rotational Vibrations

NARCIS (Netherlands)

Babakhani, B.; de Vries, Theodorus J.A.; van Amerongen, J.

Collocated active vibration control is an effective and robustly stable way of adding damping to the performance limiting vibrations of a plant. Besides the physical parameters of the Active Damping Unit (ADU) containing the collocated actuator and sensor, its location with respect to the

Visible and near-infrared spectral signatures for adulteration assessment of extra virgin olive oil

Science.gov (United States)

Mignani, A. G.; Ciaccheri, L.; Ottevaere, H.; Thienpont, H.; Conte, L.; Marega, M.; Cichelli, A.; Attilio, C.; Cimato, A.

2010-04-01

Because of its high price, the extra virgin olive oil is frequently target for adulteration with lower quality oils. This paper presents an innovative optical technique capable of quantifying the adulteration of extra virgin olive oil caused by lowergrade olive oils. It relies on spectral fingerprinting the test liquid by means of diffuse-light absorption spectroscopy carried out by optical fiber technology in the wide 400-1700 nm spectral range. Then, a smart multivariate processing of spectroscopic data is applied for immediate prediction of adulterant concentration.

Vibration in car repair work.

Science.gov (United States)

Hansson, J E; Eklund, L; Kihlberg, S; Ostergren, C E

1987-03-01

The main objective of the study was to find efficient hand tools which caused only minor vibration loading. Vibration measurements were carried out under standardised working conditions. The time during which car body repairers in seven companies were exposed to vibration was determined. Chisel hammers, impact wrenches, sanders and saws were the types of tools which generated the highest vibration accelerations. The average daily exposure at the different garages ranged from 22 to 70 min. The risk of vibration injury is currently rated as high. The difference between the highest and lowest levels of vibration was considerable in most tool categories. Therefore the choice of tool has a major impact on the magnitude of vibration exposure. The importance of choosing the right tools and working methods is discussed and a counselling service on vibration is proposed.

Application of fluorescent and vibration spectroscopy for septic serum human albumin structure deformation during pathology

Science.gov (United States)

Zyubin, A.; Konstantinova, E.; Slezhkin, V.; Matveeva, K.; Samusev, I.; Bryukhanov, V.

2017-12-01

In this paper we perform results of conformational analysis of septic human serum albumin (HSA) carried out by Raman spectroscopy (RS), infrared (IR) spectroscopy and fluorescent spectroscopy. The main vibrational groups were identified and analyzed for septic HSA and its health control. Comparison between Raman and IR results were done. Fluorescent spectral changes of Trp-214 group were analyzed. Application of Raman, IR spectroscopy, fluorescent spectroscopy for conformational changes study of HSA during pathology were shown.

Rotating shadowband radiometer development and analysis of spectral shortwave data

Energy Technology Data Exchange (ETDEWEB)

Michalsky, J.; Harrison, L.; Min, Q. [State Univ. of New York, Albany, NY (United States)] [and others

1996-04-01

Our goals in the Atmospheric Radiation Measurement (ARM) Program are improved measurements of spectral shortwave radiation and improved techniques for the retrieval of climatologically sensitive parameters. The multifilter rotating shadowband radiometer (MFRSR) that was developed during the first years of the ARM program has become a workhorse at the Southern Great Plains (SGP) Cloud and Radiation Testbed (CART) site, and it is widely deployed in other climate programs. We have spent most of our effort this year developing techniques to retrieve column aerosol, water vapor, and ozone from direct beam spectral measurements of the MFRSR. Additionally, we have had some success in calculating shortwave surface diffuse spectral irradiance. Using the surface albedo and the global irradiance, we have calculated cloud optical depths. From cloud optical depth and liquid water measured with the microwave radiometer, we have calculated effective liquid cloud particle radii. The rest of the text will provide some detail regarding each of these efforts.

Super-multiplex vibrational imaging

Science.gov (United States)

Wei, Lu; Chen, Zhixing; Shi, Lixue; Long, Rong; Anzalone, Andrew V.; Zhang, Luyuan; Hu, Fanghao; Yuste, Rafael; Cornish, Virginia W.; Min, Wei

2017-04-01

The ability to visualize directly a large number of distinct molecular species inside cells is increasingly essential for understanding complex systems and processes. Even though existing methods have successfully been used to explore structure-function relationships in nervous systems, to profile RNA in situ, to reveal the heterogeneity of tumour microenvironments and to study dynamic macromolecular assembly, it remains challenging to image many species with high selectivity and sensitivity under biological conditions. For instance, fluorescence microscopy faces a ‘colour barrier’, owing to the intrinsically broad (about 1,500 inverse centimetres) and featureless nature of fluorescence spectra that limits the number of resolvable colours to two to five (or seven to nine if using complicated instrumentation and analysis). Spontaneous Raman microscopy probes vibrational transitions with much narrower resonances (peak width of about 10 inverse centimetres) and so does not suffer from this problem, but weak signals make many bio-imaging applications impossible. Although surface-enhanced Raman scattering offers high sensitivity and multiplicity, it cannot be readily used to image specific molecular targets quantitatively inside live cells. Here we use stimulated Raman scattering under electronic pre-resonance conditions to image target molecules inside living cells with very high vibrational selectivity and sensitivity (down to 250 nanomolar with a time constant of 1 millisecond). We create a palette of triple-bond-conjugated near-infrared dyes that each displays a single peak in the cell-silent Raman spectral window; when combined with available fluorescent probes, this palette provides 24 resolvable colours, with the potential for further expansion. Proof-of-principle experiments on neuronal co-cultures and brain tissues reveal cell-type-dependent heterogeneities in DNA and protein metabolism under physiological and pathological conditions, underscoring the

Electronic and vibrational hopping transport in boron carbides

International Nuclear Information System (INIS)

Emin, D.

1991-01-01

General concepts of hopping-type transport and localization are reviewed. Disorder, electronic correlations and atomic displacements, effects ignored in electronic band structure calculations, foster localization of electronic charge carriers. Examples are given that illustrate the efficacy of these effects in producing localization. This introduction is followed by a brief discussion of the relation between hopping-type transport and localization. The fundamentals of the formation, localization, and hopping transport of small polarons and/or bipolarons is then described. Electronic transport in boron carbides is presented as an example of the adiabatic hopping of small bipolarons. Finally, the notion of vibrational hopping is introduced. The high-temperature thermal diffusion in boron carbides is presented as a potential application of this idea

CR-Calculus and adaptive array theory applied to MIMO random vibration control tests

Science.gov (United States)

Musella, U.; Manzato, S.; Peeters, B.; Guillaume, P.

2016-09-01

Performing Multiple-Input Multiple-Output (MIMO) tests to reproduce the vibration environment in a user-defined number of control points of a unit under test is necessary in applications where a realistic environment replication has to be achieved. MIMO tests require vibration control strategies to calculate the required drive signal vector that gives an acceptable replication of the target. This target is a (complex) vector with magnitude and phase information at the control points for MIMO Sine Control tests while in MIMO Random Control tests, in the most general case, the target is a complete spectral density matrix. The idea behind this work is to tailor a MIMO random vibration control approach that can be generalized to other MIMO tests, e.g. MIMO Sine and MIMO Time Waveform Replication. In this work the approach is to use gradient-based procedures over the complex space, applying the so called CR-Calculus and the adaptive array theory. With this approach it is possible to better control the process performances allowing the step-by-step Jacobian Matrix update. The theoretical bases behind the work are followed by an application of the developed method to a two-exciter two-axis system and by performance comparisons with standard methods.

Bandshapes in vibrational spectroscopy

International Nuclear Information System (INIS)

Dijkman, F.G.

1978-01-01

A detailed account is given of the development of modern bandshape theories since 1965. An investigation into the relative contributions of statistical irreversible relaxation processes is described, for a series of molecules in which gradually the length of one molecular axis is increased. An investigation into the theoretical and experimental investigation of the broadening brought about by the effect of fluctuating intermolecular potentials on the vibrational frequency is also described. The effect of an intermolecular perturbative potential on anharmonic and Morse oscillators is discussed and the results are presented of a computation on the broadening of the vibrational band of some diatomic molecules in a rigid lattice type solvent. The broadening of the OH-stretching vibration in a number of aliphatic alcohols, the vibrational bandshapes of the acetylenic C-H stretching vibration and of the symmetric methyl stretching vibration are investigated. (Auth./ C.F.)

Contamination and UV ageing of diffuser targets used in satellite inflight and ground reference test site calibrations

Science.gov (United States)

Vaskuri, Anna; Greenwell, Claire; Hessey, Isabel; Tompkins, Jordan; Woolliams, Emma

2018-02-01

Diffuser reflectance targets are key components in in-orbit calibrations and for verifying ground reference test sites. In this work, Spectralon, Diffusil, and Heraeus diffusers were exposed to exhaust gases and ultraviolet (UV) radiation in the ambient air conditions and their degradations were monitored by measuring changes in spectral reflectances. Spectralon is a state-of-the-art diffuser made of polytetrafluoroethylene, and Diffusil and Heraeus diffusers are made of fused silica with gas bubbles inside. Based on the contamination tests, Spectralon degrades faster than fused silica diffusers. For the samples exposed to contamination for 20 minutes, the 250 nm - 400 nm total diffuse spectral reflectance of Spectralon degraded 3-5 times more when exposed to petrol-like emission and 16-23 times more when exposed to diesel-like emission, compared with Diffusil. When the reflectance changes of Spectralon were compared with those of Heraeus, Spectralon degraded 3-4 times more when exposed to petrol-like emission for 20 minutes and 5-7 times more when exposed to diesel-like emission for 7.5 minutes. When the samples contaminated were exposed to UV radiation in the ambient air, their reflectance gradually restored back to the original level. In conclusion, fused silica diffusers are more resistant to hydrocarbon contaminants present in ground reference test sites, and thus more stable under UV radiation in the air.

Qualitative and quantitative approach towards the molecular understanding of structural, vibrational and optical features of urea ninhydrin monohydrate

Energy Technology Data Exchange (ETDEWEB)

Sasikala, V. [Department of Physics, Bishop Moore College, Mavelikara, Alappuzha, Kerala 690110 (India); Sajan, D., E-mail: drsajanbmc@gmail.com [Department of Physics, Bishop Moore College, Mavelikara, Alappuzha, Kerala 690110 (India); Chaitanya, K. [Department of Chemistry, Nanjing University of Science and Technology, Xialingwei 200, Nanjing (China); Sundius, Tom [Department of Physics, University of Helsinki (Finland); Devi, T. Uma [Department of Physics, Government Arts College for Women (Autonomous), Pudukottai (India)

2017-04-15

In this study, single crystals of urea ninhydrin monohydrate (UNMH) have been grown by slow evaporation method. The grown crystals were characterized by FT-IR, FT-Raman and UV-Vis-NIR spectroscopies. The Kurtz and Perry powder method was employed to confirm the near-zero SHG efficiency of the as-grown centrosymmetric UNMH crystal. The third order nonlinearity of the crystal has been studied by the open aperture Z-scan method. The nonlinear absorption coefficient is calculated and the potentiality of UNMH in optical limiting applications is identified. The molecular geometry and the origin of optical non-linearity at the molecular level have been investigated by the density functional theory. The normal coordinate analysis was carried out to assign the molecular vibrational modes. Vibrational spectral studies confirms the presence of weak O-H⋯O and moderate O-H⋯O type hydrogen bonds in the molecule as well as O-H⋯O, N-H⋯O and blue-shifted C-H⋯O type H-bonds in the crystal. The intramolecular charge transfer interactions and the electronic absorption mechanisms have been discussed. The static and the dynamic values of hyperpolarizabilities for UNMH were estimated theoretically by DFT methods. - Highlights: • Molecular geometric and NBO interaction features of UNMH were analyzed. • Vibrational spectral features and types of H-bonding in isolated gaseous phase molecule were discussed. • Electronic absorption maxima of different phases of UNMH were found out. • The non-linear absorption behaviour of UNMH is investigated using z-scan. • First- and second- order hyperpolarizability values were estimated theoretically.

Scaling analyses of the spectral dimension in 3-dimensional causal dynamical triangulations

Science.gov (United States)

Cooperman, Joshua H.

2018-05-01

The spectral dimension measures the dimensionality of a space as witnessed by a diffusing random walker. Within the causal dynamical triangulations approach to the quantization of gravity (Ambjørn et al 2000 Phys. Rev. Lett. 85 347, 2001 Nucl. Phys. B 610 347, 1998 Nucl. Phys. B 536 407), the spectral dimension exhibits novel scale-dependent dynamics: reducing towards a value near 2 on sufficiently small scales, matching closely the topological dimension on intermediate scales, and decaying in the presence of positive curvature on sufficiently large scales (Ambjørn et al 2005 Phys. Rev. Lett. 95 171301, Ambjørn et al 2005 Phys. Rev. D 72 064014, Benedetti and Henson 2009 Phys. Rev. D 80 124036, Cooperman 2014 Phys. Rev. D 90 124053, Cooperman et al 2017 Class. Quantum Grav. 34 115008, Coumbe and Jurkiewicz 2015 J. High Energy Phys. JHEP03(2015)151, Kommu 2012 Class. Quantum Grav. 29 105003). I report the first comprehensive scaling analysis of the small-to-intermediate scale spectral dimension for the test case of the causal dynamical triangulations of 3-dimensional Einstein gravity. I find that the spectral dimension scales trivially with the diffusion constant. I find that the spectral dimension is completely finite in the infinite volume limit, and I argue that its maximal value is exactly consistent with the topological dimension of 3 in this limit. I find that the spectral dimension reduces further towards a value near 2 as this case’s bare coupling approaches its phase transition, and I present evidence against the conjecture that the bare coupling simply sets the overall scale of the quantum geometry (Ambjørn et al 2001 Phys. Rev. D 64 044011). On the basis of these findings, I advance a tentative physical explanation for the dynamical reduction of the spectral dimension observed within causal dynamical triangulations: branched polymeric quantum geometry on sufficiently small scales. My analyses should facilitate attempts to employ the spectral

Putting atomic diffusion theory of magnetic ApBp stars to the test: evaluation of the predictions of time-dependent diffusion models

Science.gov (United States)

Kochukhov, O.; Ryabchikova, T. A.

2018-02-01

A series of recent theoretical atomic diffusion studies has address the challenging problem of predicting inhomogeneous vertical and horizontal chemical element distributions in the atmospheres of magnetic ApBp stars. Here we critically assess the most sophisticated of such diffusion models - based on a time-dependent treatment of the atomic diffusion in a magnetized stellar atmosphere - by direct comparison with observations as well by testing the widely used surface mapping tools with the spectral line profiles predicted by this theory. We show that the mean abundances of Fe and Cr are grossly underestimated by the time-dependent theoretical diffusion model, with discrepancies reaching a factor of 1000 for Cr. We also demonstrate that Doppler imaging inversion codes, based either on modelling of individual metal lines or line-averaged profiles simulated according to theoretical three-dimensional abundance distribution, are able to reconstruct correct horizontal chemical spot maps despite ignoring the vertical abundance variation. These numerical experiments justify a direct comparison of the empirical two-dimensional Doppler maps with theoretical diffusion calculations. This comparison is generally unfavourable for the current diffusion theory, as very few chemical elements are observed to form overabundance rings in the horizontal field regions as predicted by the theory and there are numerous examples of element accumulations in the vicinity of radial field zones, which cannot be explained by diffusion calculations.

Germanium diffusion with vapor-phase GeAs and oxygen co-incorporation in GaAs

Science.gov (United States)

Wang, Wei-Fu; Cheng, Kai-Yuan; Hsieh, Kuang-Chien

2018-01-01

Vapor-phase germanium diffusion has been demonstrated in Zn-doped and semi-insulating GaAs in sealed ampoules with GeAs powders and excess arsenic. Secondary-ion-mass spectroscopy (SIMS) profiles indicate the presence of unintentional co-incorporation of oxygen in high densities (>1017/cm3) along with diffused germanium donors whose concentration (>>1018/cm3) determined by electro-chemical capacitance-voltage (ECV) profiler shows significant compensation near the surface. The source of oxygen mainly originates from the GeAs powder which contains Ge-O surface oxides. Variable-temperature photoluminescence (PL) shows that in GeAs-diffused samples, a broad peak ranging from 0.86-1.38 eV with the peak position around 1.1 eV predominates at low temperatures while the near band-edge luminescence quenches. The broad band is attributed to the GeGa-VGa self-activated (SA) centers possibly associated with nearby oxygen-related defect complex, and its luminescence persists up to 400 K. The configurational-coordinate modeling finds that the SA defect complex has a thermal activation energy of 150-180 meV and a vibrational energy 26.8 meV. The presence of oxygen does not much affect the SA emission intensity but may have influenced the peak position, vibration frequency and activation energy as compared to other common donor-VGa defects in GaAs.

Germanium diffusion with vapor-phase GeAs and oxygen co-incorporation in GaAs

Directory of Open Access Journals (Sweden)

Wei-Fu Wang

2018-01-01

Full Text Available Vapor-phase germanium diffusion has been demonstrated in Zn-doped and semi-insulating GaAs in sealed ampoules with GeAs powders and excess arsenic. Secondary-ion-mass spectroscopy (SIMS profiles indicate the presence of unintentional co-incorporation of oxygen in high densities (>1017/cm3 along with diffused germanium donors whose concentration (>>1018/cm3 determined by electro-chemical capacitance-voltage (ECV profiler shows significant compensation near the surface. The source of oxygen mainly originates from the GeAs powder which contains Ge-O surface oxides. Variable-temperature photoluminescence (PL shows that in GeAs-diffused samples, a broad peak ranging from 0.86-1.38 eV with the peak position around 1.1 eV predominates at low temperatures while the near band-edge luminescence quenches. The broad band is attributed to the GeGa-VGa self-activated (SA centers possibly associated with nearby oxygen-related defect complex, and its luminescence persists up to 400 K. The configurational-coordinate modeling finds that the SA defect complex has a thermal activation energy of 150-180 meV and a vibrational energy 26.8 meV. The presence of oxygen does not much affect the SA emission intensity but may have influenced the peak position, vibration frequency and activation energy as compared to other common donor-VGa defects in GaAs.

Social waves in giant honeybees (Apis dorsata) elicit nest vibrations.

Science.gov (United States)

Kastberger, Gerald; Weihmann, Frank; Hoetzl, Thomas

2013-07-01

Giant honeybees (Apis dorsata) nest in the open and have developed a wide array of strategies for colony defence, including the Mexican wave-like shimmering behaviour. In this collective response, the colony members perform upward flipping of their abdomens in coordinated cascades across the nest surface. The time-space properties of these emergent waves are response patterns which have become of adaptive significance for repelling enemies in the visual domain. We report for the first time that the mechanical impulse patterns provoked by these social waves and measured by laser Doppler vibrometry generate vibrations at the central comb of the nest at the basic (='natural') frequency of 2.156 ± 0.042 Hz which is more than double the average repetition rate of the driving shimmering waves. Analysis of the Fourier spectra of the comb vibrations under quiescence and arousal conditions provoked by mass flight activity and shimmering waves gives rise to the proposal of two possible models for the compound physical system of the bee nest: According to the elastic oscillatory plate model, the comb vibrations deliver supra-threshold cues preferentially to those colony members positioned close to the comb. The mechanical pendulum model predicts that the comb vibrations are sensed by the members of the bee curtain in general, enabling mechanoreceptive signalling across the nest, also through the comb itself. The findings show that weak and stochastic forces, such as general quiescence or diffuse mass flight activity, cause a harmonic frequency spectrum of the comb, driving the comb as an elastic plate. However, shimmering waves provide sufficiently strong forces to move the nest as a mechanical pendulum. This vibratory behaviour may support the colony-intrinsic information hypothesis herein that the mechanical vibrations of the comb provoked by shimmering do have the potential to facilitate immediate communication of the momentary defensive state of the honeybee nest to

Social waves in giant honeybees ( Apis dorsata) elicit nest vibrations

Science.gov (United States)

Kastberger, Gerald; Weihmann, Frank; Hoetzl, Thomas

2013-07-01

Giant honeybees ( Apis dorsata) nest in the open and have developed a wide array of strategies for colony defence, including the Mexican wave-like shimmering behaviour. In this collective response, the colony members perform upward flipping of their abdomens in coordinated cascades across the nest surface. The time-space properties of these emergent waves are response patterns which have become of adaptive significance for repelling enemies in the visual domain. We report for the first time that the mechanical impulse patterns provoked by these social waves and measured by laser Doppler vibrometry generate vibrations at the central comb of the nest at the basic (=`natural') frequency of 2.156 ± 0.042 Hz which is more than double the average repetition rate of the driving shimmering waves. Analysis of the Fourier spectra of the comb vibrations under quiescence and arousal conditions provoked by mass flight activity and shimmering waves gives rise to the proposal of two possible models for the compound physical system of the bee nest: According to the elastic oscillatory plate model, the comb vibrations deliver supra-threshold cues preferentially to those colony members positioned close to the comb. The mechanical pendulum model predicts that the comb vibrations are sensed by the members of the bee curtain in general, enabling mechanoreceptive signalling across the nest, also through the comb itself. The findings show that weak and stochastic forces, such as general quiescence or diffuse mass flight activity, cause a harmonic frequency spectrum of the comb, driving the comb as an elastic plate. However, shimmering waves provide sufficiently strong forces to move the nest as a mechanical pendulum. This vibratory behaviour may support the colony-intrinsic information hypothesis herein that the mechanical vibrations of the comb provoked by shimmering do have the potential to facilitate immediate communication of the momentary defensive state of the honeybee nest to the

Nonlinear Response of Vibrational Conveyers with Nonideal Vibration Exciter: Superharmonic and Subharmonic Resonance

Directory of Open Access Journals (Sweden)

H. Bayıroğlu

2012-01-01

Full Text Available Vibrational conveyers with a centrifugal vibration exciter transmit their load based on the jumping method. Common unbalanced-mass driver oscillates the trough. The motion is strictly related to the vibrational parameters. The transition over resonance of a vibratory system, excited by rotating unbalances, is important in terms of the maximum vibrational amplitude produced and the power demand on the drive for the crossover. The mechanical system is driven by the DC motor. In this study, the working ranges of oscillating shaking conveyers with nonideal vibration exciter have been analyzed analytically for superharmonic and subharmonic resonances by the method of multiple scales and numerically. The analytical results obtained in this study agree well with the numerical results.

Electrostatic ion cyclotron waves and ion energy diffusion in a mirror machine

International Nuclear Information System (INIS)

Turner, W.C.

1977-01-01

Measurements of ion cyclotron fluctuations and ion energy diffusion in the neutral beam injected 2XIIB mirror machine are presented. A narrow band single mode spectrum is always observed. When the plasma is de-stabilized by turning off axially injected streaming plasma, the wave amplitude increases and a simultaneous increase in ion-energy diffusion is observed. The spectral properties of the wave do not change. The data are in accord with a wave particle saturation of the drift cyclotron loss cone (DCLC) mode

Measurement and analysis of vibrational behavior of an SNR-fuel element in sodium flow

International Nuclear Information System (INIS)

Hess, B.F.H.; Ruppert, E.; Schmidt, H.; Vinzens, K.

1975-01-01

Within the framework of SNR-300 fuel element development programme a complete full size fuel element dummy has been tested thoroughly for nearly 3000 hours at 650 deg C system temperature in the AKB sodium loop at Interatom, Bensberg. It is known that the coolant flow through a subassembly can induce flutter or vibrations of structural parts such as single pins, the wrapper and the total pin bundle all of which have been of interest during this test. To detect these vibrations of different structural parts simultaneously with a minimum of instrumentation only 3 weldable high temperature strain gauges were employed. These strain gauges were especially prepared and bent in such a way as to form a bridge between the inner wrapper and a fuel pin top and spot-welded to both the wrapper and the fuel pin. Although this arrangement seems to be a rather unusual one, the simultaneous-measurement of bundle, wrapper and pin vibrations was possible and periodic flow fluctuations were also detected. The presented results are only relative due to calibration difficulties with these deformed strain gauges which were first used during this test. It is, however, believed that this arrangement, in connection with the proposed anlytical approach, leads to a simple and technical representation of the vibrational behavior of core elements during sodium tests. Detailed information needed for check and calibration of computer codes are however displayed by the respective power spectral density functions

Vocal Fold Vibration Following Surgical Intervention in Three Vocal Pathologies: A Preliminary Study.

Science.gov (United States)

Chen, Wenli; Woo, Peak; Murry, Thomas

2017-09-01

High-speed videoendoscopy captures the cycle-to-cycle vibratory motion of each individual vocal fold in normal and severely disordered phonation. Therefore, it provides a direct method to examine the specific vibratory changes following vocal fold surgery. The purpose of this study was to examine the vocal fold vibratory pattern changes in the surgically treated pathologic vocal fold and the contralateral vocal fold in three vocal pathologies: vocal polyp (n = 3), paresis or paralysis (n = 3), and scar (n = 3). Digital kymography was used to extract high-speed kymographic vocal fold images at the mid-membranous region of the vocal fold. Spectral analysis was subsequently applied to the digital kymography to quantify the cycle-to-cycle movements of each vocal fold, expressed as a spectrum. Surgical modification resulted in significantly improved spectral power of the treated pathologic vocal fold. Furthermore, the contralateral vocal fold also presented with improved spectral power irrespective of vocal pathology. In comparison with normal vocal fold spectrum, postsurgical vocal fold vibrations continued to demonstrate decreased vibratory amplitude in both vocal folds. Copyright © 2017 The Voice Foundation. Published by Elsevier Inc. All rights reserved.

THE POSSIBLE INTERSTELLAR ANION CH{sub 2}CN{sup -}: SPECTROSCOPIC CONSTANTS, VIBRATIONAL FREQUENCIES, AND OTHER CONSIDERATIONS

Energy Technology Data Exchange (ETDEWEB)

Fortenberry, Ryan C.; Lee, Timothy J. [NASA Ames Research Center, Moffett Field, CA 94035-1000 (United States); Crawford, T. Daniel, E-mail: Ryan.C.Fortenberry@nasa.gov, E-mail: Timothy.J.Lee@nasa.gov [Department of Chemistry, Virginia Tech, Blacksburg, VA 24061 (United States)

2013-01-10

The A {sup 1}B{sub 1} Leftwards-Open-Headed-Arrow X-tilde{sup 1}A' excitation into the dipole-bound state of the cyanomethyl anion (CH{sub 2}CN{sup -}) has been hypothesized as the carrier for one diffuse interstellar band. However, this particular molecular system has not been detected in the interstellar medium even though the related cyanomethyl radical and the isoelectronic ketenimine molecule have been found. In this study, we are employing the use of proven quartic force fields and second-order vibrational perturbation theory to compute accurate spectroscopic constants and fundamental vibrational frequencies for X-tilde{sup 1} A' CH{sub 2}CN{sup -} in order to assist in laboratory studies and astronomical observations.

Description and availability of the SMARTS spectral model for photovoltaic applications

Science.gov (United States)

Myers, Daryl R.; Gueymard, Christian A.

2004-11-01

Limited spectral response range of photocoltaic (PV) devices requires device performance be characterized with respect to widely varying terrestrial solar spectra. The FORTRAN code "Simple Model for Atmospheric Transmission of Sunshine" (SMARTS) was developed for various clear-sky solar renewable energy applications. The model is partly based on parameterizations of transmittance functions in the MODTRAN/LOWTRAN band model family of radiative transfer codes. SMARTS computes spectra with a resolution of 0.5 nanometers (nm) below 400 nm, 1.0 nm from 400 nm to 1700 nm, and 5 nm from 1700 nm to 4000 nm. Fewer than 20 input parameters are required to compute spectral irradiance distributions including spectral direct beam, total, and diffuse hemispherical radiation, and up to 30 other spectral parameters. A spreadsheet-based graphical user interface can be used to simplify the construction of input files for the model. The model is the basis for new terrestrial reference spectra developed by the American Society for Testing and Materials (ASTM) for photovoltaic and materials degradation applications. We describe the model accuracy, functionality, and the availability of source and executable code. Applications to PV rating and efficiency and the combined effects of spectral selectivity and varying atmospheric conditions are briefly discussed.

Electronic and vibrational spectroscopy and vibrationally mediated photodissociation of V+(OCO).

Science.gov (United States)

Citir, Murat; Altinay, Gokhan; Metz, Ricardo B

2006-04-20

Electronic spectra of gas-phase V+(OCO) are measured in the near-infrared from 6050 to 7420 cm(-1) and in the visible from 15,500 to 16,560 cm(-1), using photofragment spectroscopy. The near-IR band is complex, with a 107 cm(-1) progression in the metal-ligand stretch. The visible band shows clearly resolved vibrational progressions in the metal-ligand stretch and rock, and in the OCO bend, as observed by Brucat and co-workers. A vibrational hot band gives the metal-ligand stretch frequency in the ground electronic state nu3'' = 210 cm(-1). The OCO antisymmetric stretch frequency in the ground electronic state (nu1'') is measured by using vibrationally mediated photodissociation. An IR laser vibrationally excites ions to nu1'' = 1. Vibrationally excited ions selectively dissociate following absorption of a second, visible photon at the nu1' = 1 CO2, due to interaction with the metal. Larger blue shifts observed for complexes with fewer ligands agree with trends seen for larger V+(OCO)n clusters.

Optical decoherence and persistent spectral hole burning in Er3+:LiNbO3

International Nuclear Information System (INIS)

Thiel, C.W.; Macfarlane, R.M.; Boettger, T.; Sun, Y.; Cone, R.L.; Babbitt, W.R.

2010-01-01

Developing new resonant optical materials for spatial-spectral holography and quantum information applications requires detailed knowledge of the decoherence and population relaxation dynamics for the quantum states involved in the optical transitions, motivating the need for fundamental material studies. We report recent progress in studying these properties in erbium-doped lithium niobate at liquid helium temperatures. The influence of temperature, applied magnetic fields, measurement timescale, and dopant concentration were probed using photon echo spectroscopy and time-resolved spectral hole burning on the 1532 nm transition of Er 3+ :LiNbO 3 . Effects of spectral diffusion due to interactions between Er 3+ ions and between the Er 3+ ion and 7 Li and 93 Nb nuclear spins in the host lattice were observed. In addition, long-lived persistent spectral storage of seconds to minutes was observed due to non-equilibrium population redistribution among superhyperfine states.

Toward accurate prediction of potential energy surfaces and the spectral density of hydrogen bonded systems

International Nuclear Information System (INIS)

Rekik, Najeh

2014-01-01

Despite the considerable progress made in quantum theory and computational methods, detailed descriptions of the potential energy surfaces of hydrogen-bonded systems have not yet been achieved. In addition, the hydrogen bond (H-bond) itself is still so poorly understood at the fundamental level that it remains unclear exactly what geometry constitutes a “real” H-bond. Therefore, in order to investigate features essential for hydrogen bonded complexes, a simple, efficient, and general method for calculating matrix elements of vibrational operators capable of describing the stretching modes and the H-bond bridges of hydrogen-bonded systems is proposed. The derived matrix elements are simple and computationally easy to evaluate, which makes the method suitable for vibrational studies of multiple-well potentials. The method is illustrated by obtaining potential energy surfaces for a number of two-dimensional systems with repulsive potentials chosen to be in Gaussian form for the stretching mode and of the Morse-type for the H-bond bridge dynamics. The forms of potential energy surfaces of weak and strong hydrogen bonds are analyzed by varying the asymmetry of the Gaussian potential. Moreover, the choice and applicability of the selected potential for the stretching mode and comparison with other potentials used in the area of hydrogen bond research are discussed. The approach for the determination of spectral density has been constructed in the framework of the linear response theory for which spectral density is obtained by Fourier transform of the autocorrelation function of the dipole moment operator of the fast mode. The approach involves anharmonic coupling between the high frequency stretching vibration (double well potential) and low-frequency donor-acceptor stretching mode (Morse potential) as well as the electrical anharmonicity of the dipole moment operator of the fast mode. A direct relaxation mechanism is incorporated through a time decaying exponential

Potassium-cobalt sulphate crystal growth assisted by low frequency vibrations

Science.gov (United States)

Sadovsky, A.; Ermochenkov, I.; Dubovenko, E.; Sukhanova, E.; Bebyakin, M.; Dubov, V.; Avetissov, I.

2018-02-01

Single crystals of K2Co(SO4)2·6H2O were grown from solution using the temperature reduction method enhanced by the axial low frequency vibration control technique (AVC-technique). Physical modeling of heat-mass transfer in solution under the AVC action was performed. The growth rate of the AVC grown crystal was found to be twice that of the crystal grown under natural convection conditions. Analysis of spectral characteristics (absorption and Raman spectra) as well as structural properties (dislocation density and microhardness) of the grown crystals showed the significant superiority of the AVC technique for the growth of K2Co(SO4)2·6H2O crystals.

Portable vibration exciter

Science.gov (United States)

Beecher, L. C.; Williams, F. T.

1970-01-01

Gas-driven vibration exciter produces a sinusoidal excitation function controllable in frequency and in amplitude. It allows direct vibration testing of components under normal loads, removing the possibility of component damage due to high static pressure.

Separation of Electric Fields Into Potential and Inductive Parts, and Implications for Radial Diffusion

Science.gov (United States)

Chan, A. A.; Ilie, R.; Elkington, S. R.; Albert, J.; Huie, W.

2017-12-01

It has been traditional to separate radiation belt radial-diffusion coefficients into two contributions: an "electrostatic" diffusion coefficient, which is assumed to be due to a potential (non-inductive) electric field, and an "electromagnetic" diffusion coefficient , which is assumed to be due to the combined effect of an inductive electric field and the corresponding time-dependent magnetic field. One difficulty in implementing this separation when using magnetospheric fields obtained from measurements, or from MHD simulations, is that only the total electric field is given; the separation of the electric field into potential and inductive parts is not readily available. In this work we separate the electric field using a numerical method based on the Helmholtz decomposition of the total motional electric field calculated by the BATS-R-US MHD code. The inner boundary for the electric potential is based on the Ridley Ionospheric Model solution and we assume floating boundary conditions in the solar wind. Using different idealized solar wind drivers, including a solar wind density that is oscillating at a single frequency or with a broad spectrum of frequencies, we calculate potential and inductive electric fields, electric and magnetic power spectral densities, and corresponding radial diffusion coefficients. Simulations driven by idealized solar wind conditions show a clear separation of the potential and inductive contributions to the power spectral densities and diffusion coefficients. Simulations with more realistic solar wind drivers are underway to better assess the use of electrostatic and electromagnetic diffusion coefficients in understanding ULF wave-particle interactions in Earth's radiation belts.

Evidence of non-LTE Effects in Mesospheric Water Vapor from Spectrally-Resolved Emissions Observed by CIRRIS-1A

Science.gov (United States)

Zhou, D. K.; Mlynczak, M. G.; Lopez-Puertas, M.; Zaragoza, G.

1999-01-01

Evidence of non-LTE effects in mesospheric water vapor as determined by infrared spectral emission measurements taken from the space shuttle is reported. A cryogenic Michelson interferometer in the CIRRIS-1A shuttle payload yielded high quality, atmospheric infrared spectra. These measurements demonstrate the enhanced daytime emissions of H2O (020-010) which are the result of non-LTE processes and in agreement with non-LTE models. The radiance ratios of H2O (010 to 000) and (020 to 010) Q(1) transitions during daytime are compared with non-LTE model calculations to assess the vibration-to-vibration exchange rate between H2O and O2 in the mesosphere. An exchange rate of 1.2 x 10(exp -12)cc/s is derived.

Vibrational circulardichroism and IR spectral analysis as a test of theoretical conformational modeling for a cyclic hexapeptide

Czech Academy of Sciences Publication Activity Database

Bouř, Petr; Kim, J.; Kapitán, Josef; Hammer, R. P.; Huang, R.; Wu, L.; Keiderling, T. A.

2008-01-01

Roč. 20, č. 10 (2008), s. 1104-1119 ISSN 0899-0042 R&D Projects: GA ČR GA203/06/0420; GA ČR GA202/07/0732; GA AV ČR IAA400550702 Grant - others:NSF(US) CHE-0316014; NSF(US) CHE-0718543 Institutional research plan: CEZ:AV0Z40550506 Keywords : vibrational circular dichroism * peptide * conformation * ab initio Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.212, year: 2008

High-Temperature Vibration Damper

Science.gov (United States)

Clarke, Alan; Litwin, Joel; Krauss, Harold

1987-01-01

Device for damping vibrations functions at temperatures up to 400 degrees F. Dampens vibrational torque loads as high as 1,000 lb-in. but compact enough to be part of helicopter rotor hub. Rotary damper absorbs energy from vibrating rod, dissipating it in turbulent motion of viscous hydraulic fluid forced by moving vanes through small orifices.

Spectral analysis of an algebraic collapsing acceleration for the characteristics method

International Nuclear Information System (INIS)

Le Tellier, R.; Hebert, A.

2005-01-01

A spectral analysis of a diffusion synthetic acceleration called Algebraic Collapsing Acceleration (ACA) was carried out in the context of the characteristics method to solve the neutron transport equation. Two analysis were performed in order to assess the ACA performances. Both a standard Fourier analysis in a periodic and infinite slab-geometry and a direct spectral analysis for a finite slab-geometry were investigated. In order to evaluate its performance, ACA was compared with two competing techniques used to accelerate the convergence of the characteristics method, the Self-Collision Re-balancing technique and the Asymptotic Synthetic Acceleration. In the restricted framework of 1-dimensional slab-geometries, we conclude that ACA offers a good compromise between the reduction of the spectral radius of the iterative matrix and the resources to construct, store and solve the corrective system. A comparison on a monoenergetic 2-dimensional benchmark was performed and tends to confirm these conclusions. (authors)

Si-H bond dynamics in hydrogenated amorphous silicon

Science.gov (United States)

Scharff, R. Jason; McGrane, Shawn D.

2007-08-01

The ultrafast structural dynamics of the Si-H bond in the rigid solvent environment of an amorphous silicon thin film is investigated using two-dimensional infrared four-wave mixing techniques. The two-dimensional infrared (2DIR) vibrational correlation spectrum resolves the homogeneous line shapes ( 4ps waiting times. The Si-H stretching mode anharmonic shift is determined to be 84cm-1 and decreases slightly with vibrational frequency. The 1→2 linewidth increases with vibrational frequency. Frequency dependent vibrational population times measured by transient grating spectroscopy are also reported. The narrow homogeneous line shape, large inhomogeneous broadening, and lack of spectral diffusion reported here present the ideal backdrop for using a 2DIR probe following electronic pumping to measure the transient structural dynamics implicated in the Staebler-Wronski degradation [Appl. Phys. Lett. 31, 292 (1977)] in a-Si:H based solar cells.

[Study on crystal growth and vibrational spectra of Yb(x) : KY(1-x) (WO4)2].

Science.gov (United States)

Liu, Jing-He; Zhang, Ying; Zhang, Li-Jie; Zeng, Fan-Ming; Wang, Cheng-Wei; Zhang, Xue-Jian

2008-02-01

Yb(x) : KY(1-x)W (x = 0.05)and KYbW crystals were grown by TSSG method. Both of the structure and spectral properties were compared. The condition for the crystal growth is: the rotation rate 10-15 r x min(-1), the pulling speed 1-2 d(-1), the growing period 10-15 d, cooling growing speed 0.05-0.1 degrees C x h(-1), and the cooling speed 20 degrees C x h(-1). X-ray powder diffraction analysis was performed for the crystal powder. They belong to beta-KYW structure with low thermal phase. The cell parameters of the two crystals were calculated, and they are respectively a1 = 1.063 nm, b1 = 1.034 nm, c1 = 0.755 nm, beta1 = 130.75 degrees, Z1 = 4 and a2 = 1.061 nm, b2 = 1.029 nm, c2 = 0.749 nm, beta2 = 130.65 degrees and Z2 = 4. The infrared spectrum and Raman spectrum of crystal were measured. The sample of Yb(x) : KY(1-x) W (x = 0.05) had stronger infrared absorption peaks at 925, 891, 840, 777 and 749 cm(-1), which were caused by stretching vibration. The sample of KYW had stronger infrared absorption peaks at 484 and 437 cm(-1) caused by bending vibration. The vibration modes were analysed and vibrational frequencies of vibratory activity was assigned. The two crystals had strong Raman activity. The vibration of WOOW and WOW exists from 200 to 1000 cm(-1).

Recovery of material parameters of soft hyperelastic tissue by an inverse spectral technique

KAUST Repository

Gou, Kun

2012-07-01

An inverse spectral method is developed for recovering a spatially inhomogeneous shear modulus for soft tissue. The study is motivated by a novel use of the intravascular ultrasound technique to image arteries. The arterial wall is idealized as a nonlinear isotropic cylindrical hyperelastic body. A boundary value problem is formulated for the response of the arterial wall within a specific class of quasistatic deformations reflective of the response due to imposed blood pressure. Subsequently, a boundary value problem is developed via an asymptotic construction modeling intravascular ultrasound interrogation which generates small amplitude, high frequency time harmonic vibrations superimposed on the static finite deformation. This leads to a system of second order ordinary Sturm-Liouville boundary value problems that are then employed to reconstruct the shear modulus through a nonlinear inverse spectral technique. Numerical examples are demonstrated to show the viability of the method. © 2012 Elsevier Ltd. All rights reserved.

A new method of organizing spectral line intensity ratio fluctuations of auroral emissions

International Nuclear Information System (INIS)

Thelin, B.

1986-02-01

In this paper a new kind of linearization effect between the atmospheric auroral emissions is presented. The same kind of linearization effect has previously been found in nightglow emissions from photometer measurements and in the spectrochemical field from studies of optical light sources. Linear graphs have been obtained for atomic spectral lines and vibrational bandspectra when the spectral line ratio fluctuations were plotted versus the photon energies of these emissions. This new effect has been studied with a spectrophotometer in auroral emissions, where linear graphs have been obtained on different auroral occasions. By doing such studies of auroral light it is possible to see the importance of the inelastic scattering cross section between electrons - atoms and electrons - molecules. In this way it has shown to be possible to determine the mean energy of the interacting thermal electrons that are active in the different auroral phases. (author)

Multiplex CARS imaging with spectral notch shaped laser pulses delivered by optical fibers.

Science.gov (United States)

Oh, Seung Ryeol; Park, Joo Hyun; Kim, Kyung-Soo; Lee, Jae Yong; Kim, Soohyun

2017-12-11

We present an experimental demonstration of single-pulse coherent anti-Stokes Raman spectroscopy (CARS) using a spectrally shaped broadband laser that is delivered by an optical fiber to a sample at its distal end. The optical fiber consists of a fiber Bragg grating component to serve as a narrowband notch filter and a combined large-mode-area fiber to transmit such shaped ultrashort laser pulses without spectral distortion in a long distance. Experimentally, our implementation showed a capability to measure CARS spectra of various samples with molecular vibrations in the fingerprint region. Furthermore, CARS imaging of poly(methyl methacrylate) bead samples was carried out successfully under epi-CARS geometry in which backward-scattered CARS signals were collected into a multimode optical fiber. A compatibility of single-pulse CARS scheme with fiber optics, verified in this study, implies a potential for future realization of compact all-fiber CARS spectroscopic imaging systems.

Wavelet-based spectral finite element dynamic analysis for an axially moving Timoshenko beam

Science.gov (United States)

Mokhtari, Ali; Mirdamadi, Hamid Reza; Ghayour, Mostafa

2017-08-01

In this article, wavelet-based spectral finite element (WSFE) model is formulated for time domain and wave domain dynamic analysis of an axially moving Timoshenko beam subjected to axial pretension. The formulation is similar to conventional FFT-based spectral finite element (SFE) model except that Daubechies wavelet basis functions are used for temporal discretization of the governing partial differential equations into a set of ordinary differential equations. The localized nature of Daubechies wavelet basis functions helps to rule out problems of SFE model due to periodicity assumption, especially during inverse Fourier transformation and back to time domain. The high accuracy of WSFE model is then evaluated by comparing its results with those of conventional finite element and SFE results. The effects of moving beam speed and axial tensile force on vibration and wave characteristics, and static and dynamic stabilities of moving beam are investigated.

Ground test for vibration control demonstrator

Science.gov (United States)

Meyer, C.; Prodigue, J.; Broux, G.; Cantinaud, O.; Poussot-Vassal, C.

2016-09-01

In the objective of maximizing comfort in Falcon jets, Dassault Aviation is developing an innovative vibration control technology. Vibrations of the structure are measured at several locations and sent to a dedicated high performance vibration control computer. Control laws are implemented in this computer to analyse the vibrations in real time, and then elaborate orders sent to the existing control surfaces to counteract vibrations. After detailing the technology principles, this paper focuses on the vibration control ground demonstration that was performed by Dassault Aviation in May 2015 on Falcon 7X business jet. The goal of this test was to attenuate vibrations resulting from fixed forced excitation delivered by shakers. The ground test demonstrated the capability to implement an efficient closed-loop vibration control with a significant vibration level reduction and validated the vibration control law design methodology. This successful ground test was a prerequisite before the flight test demonstration that is now being prepared. This study has been partly supported by the JTI CleanSky SFWA-ITD.

High-order multi-implicit spectral deferred correction methods for problems of reactive flow

International Nuclear Information System (INIS)

Bourlioux, Anne; Layton, Anita T.; Minion, Michael L.

2003-01-01

Models for reacting flow are typically based on advection-diffusion-reaction (A-D-R) partial differential equations. Many practical cases correspond to situations where the relevant time scales associated with each of the three sub-processes can be widely different, leading to disparate time-step requirements for robust and accurate time-integration. In particular, interesting regimes in combustion correspond to systems in which diffusion and reaction are much faster processes than advection. The numerical strategy introduced in this paper is a general procedure to account for this time-scale disparity. The proposed methods are high-order multi-implicit generalizations of spectral deferred correction methods (MISDC methods), constructed for the temporal integration of A-D-R equations. Spectral deferred correction methods compute a high-order approximation to the solution of a differential equation by using a simple, low-order numerical method to solve a series of correction equations, each of which increases the order of accuracy of the approximation. The key feature of MISDC methods is their flexibility in handling several sub-processes implicitly but independently, while avoiding the splitting errors present in traditional operator-splitting methods and also allowing for different time steps for each process. The stability, accuracy, and efficiency of MISDC methods are first analyzed using a linear model problem and the results are compared to semi-implicit spectral deferred correction methods. Furthermore, numerical tests on simplified reacting flows demonstrate the expected convergence rates for MISDC methods of orders three, four, and five. The gain in efficiency by independently controlling the sub-process time steps is illustrated for nonlinear problems, where reaction and diffusion are much stiffer than advection. Although the paper focuses on this specific time-scales ordering, the generalization to any ordering combination is straightforward

Identification of mechanical vibrations in a PWR reactor using neutron noise signal analysis of the standard instrumentation; Identifikacija mehanichkih varijacija analizom signala shuma standardne neutronske instrumentacije PWR reaktora

Energy Technology Data Exchange (ETDEWEB)

Kostic, Lj [Institut za Nuklearne Nauke Boris Kidric, Belgrade (Yugoslavia); Runkel, J [Institut fuer Kerntechnik und Zerstoerungsfreie Pruefverfahren, Hannover (Germany)

1988-07-01

The neutron noise signals in a PWR power plant were analysed in terms of auto- and cross-power spectral densities, phases and coherences. Core barrel motion, fuel element vibrations and reactivity noise effect due to pressure variations have been monitored and analysed. (author)

Mechanical vibration and shock analysis, sinusoidal vibration

CERN Document Server

Lalanne, Christian

2014-01-01

Everything engineers need to know about mechanical vibration and shock...in one authoritative reference work! This fully updated and revised 3rd edition addresses the entire field of mechanical vibration and shock as one of the most important types of load and stress applied to structures, machines and components in the real world. Examples include everything from the regular and predictable loads applied to turbines, motors or helicopters by the spinning of their constituent parts to the ability of buildings to withstand damage from wind loads or explosions, and the need for cars to m

A method for distinguishing between propagons, diffusions, and locons

Energy Technology Data Exchange (ETDEWEB)

Seyf, Hamid Reza; Henry, Asegun [George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Heat Lab, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States)

2016-07-14

The majority of intuition on phonon transport has been derived from studies of homogenous crystalline solids, where the atomic composition and structure are periodic. For this specific class of materials, the solutions to the equations of motions for the atoms (in the harmonic limit) result in plane wave modulated velocity fields for the normal modes of vibration. However, it has been known for several decades that whenever a system lacks periodicity, either compositional or structural, the normal modes of vibration can still be determined (in the harmonic limit), but the solutions take on different characteristics and many modes may not be plane wave modulated. Previous work has classified the types of vibrations into three primary categories, namely, propagons, diffusions, and locons. One can use the participation ratio to distinguish locons, from propagons and diffusons, which measures the extent to which a mode is localized. However, distinguishing between propagons and diffusons has remained a challenge, since both are spatially delocalized. Here, we present a new method that quantifies the extent to which a mode's character corresponds to a propagating mode, e.g., exhibits plane wave modulation. This then allows for clear and quantitative distinctions between propagons and diffusons. By resolving this issue quantitatively, one can now automate the classification of modes for any arbitrary material or structure, subject to a single constraint that the atoms must vibrate stably around their respective equilibrium sites. Several example test cases are studied including crystalline silicon and germanium, crystalline silicon with different defect concentrations, as well as amorphous silicon, germanium, and silica.

NMR studies of hydrogen diffusion in hydrogen uranyl phosphate tetrahydrate (HUP)

International Nuclear Information System (INIS)

Metcalfe, K.

1988-01-01

1 H NMR spin-lattice relaxation times, T 1 (Zeeman) and T 1p (rotating frame) and spin-spin relaxation times, T 2 , and 31 P NMR solid-echoes are reported for phase I and II of hydrogen uranyl phosphate tetrahydrate (HUP) at temperatures in the range 200-323 K. The spectral density functions extracted from the measured relaxation times for phases I and II are consistent with a 2D diffusion mechanism for hydrogen motion. 31 P second moments determined from the solid-echoes show that all the hydrogens diffuse rapidly in phase I, and that the hydrogen-bond site nearest to the phosphate oxygen is not occupied in phase II. The mechanism for diffusion in phase II is discussed. 30 refs.; 6 figs.; 2 tabs

Model Predictive Vibration Control Efficient Constrained MPC Vibration Control for Lightly Damped Mechanical Structures

CERN Document Server

Takács, Gergely

2012-01-01

Real-time model predictive controller (MPC) implementation in active vibration control (AVC) is often rendered difficult by fast sampling speeds and extensive actuator-deformation asymmetry. If the control of lightly damped mechanical structures is assumed, the region of attraction containing the set of allowable initial conditions requires a large prediction horizon, making the already computationally demanding on-line process even more complex. Model Predictive Vibration Control provides insight into the predictive control of lightly damped vibrating structures by exploring computationally efficient algorithms which are capable of low frequency vibration control with guaranteed stability and constraint feasibility. In addition to a theoretical primer on active vibration damping and model predictive control, Model Predictive Vibration Control provides a guide through the necessary steps in understanding the founding ideas of predictive control applied in AVC such as: ·         the implementation of ...

Understanding the radio spectral indices of galaxy cluster relics by superdiffusive shock acceleration

Science.gov (United States)

Zimbardo, Gaetano; Perri, Silvia

2018-06-01

Galaxy cluster merger shocks are the likely source of relativistic electrons, but many observations do not fit into the standard acceleration models. In particular, there is a long-standing discrepancy between the radio derived Mach numbers M_radio and the Mach numbers derived from X-ray measurements, M_X. Here, we show how superdiffusive electron transport and superdiffusive shock acceleration (SSA) can help to solve this problem. We present a heuristic derivation of the superlinear time growth of the mean square displacement of particles, ⟨Δx2⟩∝tβ, and of the particle energy spectral index in the framework of SSA. The resulting expression for the radio spectral index α is then used to determine the superdiffusive exponent β from the observed values of α and of the compression ratio for a number of radio relics. Therefore, the fact that M_radio>M_X can be explained by SSA without the need to make assumptions on the energy spectrum of the seed electrons to be re-accelerated. We also consider the acceleration times obtained in the diffusive case, based both on the Bohm diffusion coefficient and on the quasilinear diffusion coefficient. While in the latter case the acceleration time is consistent with the estimated electron energy loss time, the former case it is much shorter.

The influence of flywheel micro vibration on space camera and vibration suppression

Science.gov (United States)

Li, Lin; Tan, Luyang; Kong, Lin; Wang, Dong; Yang, Hongbo

2018-02-01

Studied the impact of flywheel micro vibration on a high resolution optical satellite that space-borne integrated. By testing the flywheel micro vibration with six-component test bench, the flywheel disturbance data is acquired. The finite element model of the satellite was established and the unit force/torque were applied at the flywheel mounting position to obtain the micro vibration data of the camera. Integrated analysis of the data of the two parts showed that the influence of flywheel micro vibration on the camera is mainly concentrated around 60-80 Hz and 170-230 Hz, the largest angular displacement of the secondary mirror along the optical axis direction is 0.04″ and the maximum angular displacement vertical to optical axis is 0.032″. After the design and installation of vibration isolator, the maximum angular displacement of the secondary mirror is 0.011″, the decay rate of root mean square value of the angular displacement is more than 50% and the maximum is 96.78%. The whole satellite was suspended to simulate the boundary condition on orbit; the imaging experiment results show that the image motion caused by the flywheel micro vibrationis less than 0.1 pixel after installing the vibration isolator.

Leak Detection and Location of Water Pipes Using Vibration Sensors and Modified ML Prefilter.

Science.gov (United States)

Choi, Jihoon; Shin, Joonho; Song, Choonggeun; Han, Suyong; Park, Doo Il

2017-09-13

This paper proposes a new leak detection and location method based on vibration sensors and generalised cross-correlation techniques. Considering the estimation errors of the power spectral densities (PSDs) and the cross-spectral density (CSD), the proposed method employs a modified maximum-likelihood (ML) prefilter with a regularisation factor. We derive a theoretical variance of the time difference estimation error through summation in the discrete-frequency domain, and find the optimal regularisation factor that minimises the theoretical variance in practical water pipe channels. The proposed method is compared with conventional correlation-based techniques via numerical simulations using a water pipe channel model, and it is shown through field measurement that the proposed modified ML prefilter outperforms conventional prefilters for the generalised cross-correlation. In addition, we provide a formula to calculate the leak location using the time difference estimate when different types of pipes are connected.

Leak Detection and Location of Water Pipes Using Vibration Sensors and Modified ML Prefilter

Directory of Open Access Journals (Sweden)

Jihoon Choi

2017-09-01

Full Text Available This paper proposes a new leak detection and location method based on vibration sensors and generalised cross-correlation techniques. Considering the estimation errors of the power spectral densities (PSDs and the cross-spectral density (CSD, the proposed method employs a modified maximum-likelihood (ML prefilter with a regularisation factor. We derive a theoretical variance of the time difference estimation error through summation in the discrete-frequency domain, and find the optimal regularisation factor that minimises the theoretical variance in practical water pipe channels. The proposed method is compared with conventional correlation-based techniques via numerical simulations using a water pipe channel model, and it is shown through field measurement that the proposed modified ML prefilter outperforms conventional prefilters for the generalised cross-correlation. In addition, we provide a formula to calculate the leak location using the time difference estimate when different types of pipes are connected.

Spectral and entropic characterizations of Wigner functions: applications to model vibrational systems.

Science.gov (United States)

Luzanov, A V

2008-09-07

The Wigner function for the pure quantum states is used as an integral kernel of the non-Hermitian operator K, to which the standard singular value decomposition (SVD) is applied. It provides a set of the squared singular values treated as probabilities of the individual phase-space processes, the latter being described by eigenfunctions of KK(+) (for coordinate variables) and K(+)K (for momentum variables). Such a SVD representation is employed to obviate the well-known difficulties in the definition of the phase-space entropy measures in terms of the Wigner function that usually allows negative values. In particular, the new measures of nonclassicality are constructed in the form that automatically satisfies additivity for systems composed of noninteracting parts. Furthermore, the emphasis is given on the geometrical interpretation of the full entropy measure as the effective phase-space volume in the Wigner picture of quantum mechanics. The approach is exemplified by considering some generic vibrational systems. Specifically, for eigenstates of the harmonic oscillator and a superposition of coherent states, the singular value spectrum is evaluated analytically. Numerical computations are given for the nonlinear problems (the Morse and double well oscillators, and the Henon-Heiles system). We also discuss the difficulties in implementation of a similar technique for electronic problems.

Spectral and angle dependent emission of solar fluorescence collectors

Energy Technology Data Exchange (ETDEWEB)

Straeter, Hendrik; Knabe, Sebastian; Bauer, Gottfried H. [Institute of Physics, Carl von Ossietzky University Oldenburg, D-26111 Oldenburg (Germany)

2011-07-01

Fluorescence collectors (FCs) provide the option for concentration and simultaneous spectral selection of solar photons of direct or diffuse light. The energetic and commercial benefit of these systems depend on the yield of the conversion of solar photons into luminescence photons and on the efficiency of their respective conductance to the edges of the FC where they are coupled into appropriate solar cells. For the characterization of the performance of FCs and the identification of losses, we have performed angle and spectrally resolved measurements of fluorescence photons from FC with two different types of optical designs, a PMMA substrate with homogeneous depth dependent dye concentration and a novel type of FC, which consist of a transparent substrate with a thin overlayer containing the absorbing and emitting dye. We have recorded the edge fluorescence when illuminating the entire FC surface laterally homogeneously, as well as for slit-like excitation on the front surface with variation of the distance of the illuminated slit from the edge. We compare the experimental fluorescence results with a 2-dimensional ray-tracing approach and verify the spectral and angle dependent edge emission. Moreover we illuminate the FC with long wavelength photons which are not absorbed and conclude, again from angle dependent and spectrally resolved edge emission, on scattering losses at surfaces and in the bulk.

Isotopic and chemical dilution effects on the vibrational relaxation rate of some totally symmetric motions of liquid acetonitrile

International Nuclear Information System (INIS)

Marri, E.; Morresi, A.; Paliani, G.; Cataliotti, R.S.; Giorgini, M.G.

1999-01-01

The vibrational dephasing of the ν 1 (C-H, C-D stretching) and ν 3 (C-H, C-D bending) symmetric motions of liquid acetonitrile in its light and fully deuterated forms has been studied in the frame of the vibrational time correlation functions obtained as Fourier transforms of the isotropic Raman spectral distributions and interpreted within the Kubo theory. In addition, the experimental isotropic profiles have been analysed within the bandshape approach formulated by analytical Fourier transformation of the Kubo vibrational time correlation functions in order to derive the relaxation parameters in the frequency domain. The effects of the isotopic (CH 3 CN/CD 3 CN and vice versa) and chemical (CCl 4 ) dilution on the bandshapes and on the vibrational relaxation parameters have been studied. It was observed that the decay rate of ν 1 mode is insensitive to the isotopic dilution but varies appreciably with chemical (CCl 4 ) dilution. The vibrational dephasing of ν 3 mode is qualitatively, but not quantitatively, affected in the same way by chemical dilution and shows a slower modulation regime than that exhibited by the stretching mode. Unlikely from the latter, the ν 3 mode results are slightly affected by the isotopic dilution. Phase relaxation mechanisms of these two motions of acetonitrile in the liquid state are proposed on the basis of these data, and a comparison is made with the results earlier published. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

Vibrations of rotating machinery

CERN Document Server

Matsushita, Osami; Kanki, Hiroshi; Kobayashi, Masao; Keogh, Patrick

2017-01-01

This book opens with an explanation of the vibrations of a single degree-of-freedom (dof) system for all beginners. Subsequently, vibration analysis of multi-dof systems is explained by modal analysis. Mode synthesis modeling is then introduced for system reduction, which aids understanding in a simplified manner of how complicated rotors behave. Rotor balancing techniques are offered for rigid and flexible rotors through several examples. Consideration of gyroscopic influences on the rotordynamics is then provided and vibration evaluation of a rotor-bearing system is emphasized in terms of forward and backward whirl rotor motions through eigenvalue (natural frequency and damping ratio) analysis. In addition to these rotordynamics concerning rotating shaft vibration measured in a stationary reference frame, blade vibrations are analyzed with Coriolis forces expressed in a rotating reference frame. Other phenomena that may be assessed in stationary and rotating reference frames include stability characteristic...

The off-center effect on the diffusion coefficient of Cu+ and Li+ in the KCl lattice

International Nuclear Information System (INIS)

Despa, F.

1994-07-01

It is well known that the diffusion coefficients of the Cu + cation in the NaCl and KCl lattices exceeds by three or four orders of magnitude the corresponding self-diffusion coefficients in the intrinsic temperature regions. This fast diffusion of the Cu + has been explained in many papers as an interstitial diffusion although the optical spectra do not confirm the existence of interstitial Cu + . In this paper we propose a new mechanism for fast diffusion. The model assumes that the equilibrium positions of the cationic impurities are noncentral and that the diffusion proceeds by hopping across the potential barrier along the nonlinear paths with the highest probability. The main result shows that the off-center position enhances considerably the diffusion. Theoretical diffusion coefficients have been obtained by modelling the potential barrier. Changes of the configuration entropy and the vibration spectra due to the presence of the noncentral impurity have been included in the model. We proceeded in the Li + cation case as in the case of Cu + cation. We emphasize the good agreement of the model with the experimental data and we show that if the impurity is placed close to the central site the due diffusion coefficient is close to that for the cationic self-diffusion. (author). 37 refs, 6 figs, 3 tabs