Metallic Na formation in NaCl crystals with irradiation of electron or vacuum ultraviolet photon

Energy Technology Data Exchange (ETDEWEB)

Owaki, Shigehiro [Osaka Prefecture Univ., Sakai, Osaka (Japan). Coll. of Integrated Arts and Sciences; Koyama, Shigeko; Takahashi, Masao; Kamada, Masao; Suzuki, Ryouichi

1997-03-01

Metallic Na was formed in NaCl single crystals with irradiation of a variety of radiation sources and analyzed the physical states with several methods. In the case of irradiation of 21 MeV electron pulses to the crystal blocks, the optical absorption and lifetime measurement of positron annihilation indicated appearance of Na clusters inside. Radiation effects of electron beam of 30 keV to the crystals in vacuum showed the appearance of not only metallic Na but atomic one during irradiation with Auger electron spectroscopy. Intense photon fluxes in vacuum ultraviolet region of synchrotron radiation were used as another source and an analyzing method of ultraviolet photoelectron spectroscopy. The results showed the metallic Na layered so thick that bulk plasmon can exist. (author)

Vacuum-ultraviolet circular dichroism of amino acids as revealed by synchrotron radiation spectrophotometer

International Nuclear Information System (INIS)

Matsuo, Koichi; Matsushima, Yosuke; Fukuyama, Takayuki; Gekko, Kunihiko; Senba, Shinya

2002-01-01

We succeeded in constructing a vacuum-ultraviolet circular dichroism (VUVCD) spectrophotometer with a small-scale synchrotron radiation source (0.7 GeV) at Hiroshima Synchrotron Radiation Center (HiSOR). This VUVCD system revealed for the first time the CD spectra of amino acids in aqueous media in the 310-140 nm region under high vacuum. These data, which cannot be observed by any types of existing CD spectrophotometers, now open a new field in the structural analysis of biomaterials on a basis of the higher energy transition of chromophores. (author)

Large area, surface discharge pumped, vacuum ultraviolet light source

Science.gov (United States)

Sze, R.C.; Quigley, G.P.

1996-12-17

Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source is disclosed. A contamination-free VUV light source having a 225 cm{sup 2} emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm{sup 2} at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing. 3 figs.

Space-resolved vacuum ultra-violet spectroscopy on T.F.R. Tokamak plasmas

International Nuclear Information System (INIS)

1978-01-01

Results are reported of space-resolved vacuum-ultraviolet spectroscopy (between 100 A and 2000A) on T.F.R. Tokamak plasmas and examples are given of profiles for both heavy and light impurity ions. The experimental method and the associated uncertainties and problems are stressed. The great importance of numerical calculations in the interpretation of the impurity profiles is pointed out. (author)

Vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters

International Nuclear Information System (INIS)

Ahmed, Musahid; Ahmed, Musahid; Wilson, Kevin R.; Belau, Leonid; Kostko, Oleg

2008-01-01

In this work we report on the vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuum ultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH + (n=1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH)n(H2O)H + (n=2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH +, (CH 3OH)2 +, (CH3OH)nH + (n=1-9), and (CH 3OH)n(H2O)H + (n=2-9 ) as a function of photon energy. With an increase in the water content in the molecular beam, there is an enhancement of photoionization intensity for methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations

Design and fabrication of a vacuum ultraviolet monochromator using Seya-Namioka mount

International Nuclear Information System (INIS)

Krishnamurty, G.; Sarma, Y.A.; Meenakshi Raja Rao, P.; Bhattacharya, S.S.

1983-01-01

The design and fabrication of a one meter vacuum ultraviolet monochromator in the Seya-Namioka mounting is described. The monochromator consists of a concave replica grating (1200 grooves/mm) blazed at 1500 A. The grating rotates about a vertical axis through the center of grating by means of sine drive mechanism. An EMI 6256 photomultiplier coupled with a VUV scintillator, sodium salicylate, is used to detect the radiation. (author)

Examination of Laser Microprobe Vacuum Ultraviolet Ionization Mass Spectrometry with Application to Mapping Mars Returned Samples

Science.gov (United States)

Burton, A. S.; Berger, E. L.; Locke, D. R.; Lewis, E. K.; Moore, J. F.

2018-04-01

Laser microprobe of surfaces utilizing a two laser setup whereby the desorption laser threshold is lowered below ionization, and the resulting neutral plume is examined using 157nm Vacuum Ultraviolet laser light for mass spec surface mapping.

Vacuum-ultraviolet circular dichroism spectrophotometer using synchrotron radiation

International Nuclear Information System (INIS)

Matsu, K.; Yonehara, R.; Gekko, K.

2004-01-01

Full text: Circular dichroism (CD) spectroscopy is powerful for analyzing the structure of optically active materials such as biopolymers. However, no commercial CD spectrophotometer is capable of measuring the CD in the vacuum ultraviolet (VUV) region below 190 nm because of technical difficulties involved in the light source, optical device, and sample cell. CD measurements extended to the VUV region can provide more detailed and new information on the structure of biopolymers based on the higher energy transition of chromophores such as hydroxyl and acetal groups. We have constructed a VUVCD spectrophotometer to measure the CD spectra of biomaterials in aqueous solutions in the 310-140 nm wavelength region under a high vacuum, using a small-scale SR source (0.7 GeV) at Hiroshima Synchrotron Radiation Center (HiSOR). All optical devices of the spectrophotometer were set up under a high vacuum (10 -6 Torr), to avoid the absorption of light by air and water vapor. The SR light is separated into two orthogonal linearly polarized light beams by a linear polarizer and then modulated to circularly polarized light at 50 kHz by a photo-elastic modulator (PEM). In order to control PEM accurately and to stabilize the lock-in amplifier under a high vacuum, we used the optical servo-control system. Also, an assembled-type MgF 2 cell with a temperature-control unit was constructed using a Peltier thermoelectric element. Its path length can be adjusted by various Tefron spacers in the range from 1.3 to 50 μm and its temperature can be controlled within an accuracy of ± 1 deg C in the range from -30 to 70 deg C. The performance of the spectrophotometer and MgF 2 cell constructed was tested by monitoring the CD spectra of ammonium d-camphor-10-sulfonate (ACS), D- and L-isomers of amino acids. These obtained results demonstrate that the optical system and the sample cell constructed normally operate under a high vacuum to provide useful information on the structure analysis of

Pseudo-absolute quantitative analysis using gas chromatography – Vacuum ultraviolet spectroscopy – A tutorial

Energy Technology Data Exchange (ETDEWEB)

Bai, Ling [Department of Chemistry & Biochemistry, The University of Texas at Arlington, Arlington, TX (United States); Smuts, Jonathan; Walsh, Phillip [VUV Analytics, Inc., Cedar Park, TX (United States); Qiu, Changling [Department of Chemistry & Biochemistry, The University of Texas at Arlington, Arlington, TX (United States); McNair, Harold M. [Department of Chemistry, Virginia Tech, Blacksburg, VA (United States); Schug, Kevin A., E-mail: kschug@uta.edu [Department of Chemistry & Biochemistry, The University of Texas at Arlington, Arlington, TX (United States)

2017-02-08

The vacuum ultraviolet detector (VUV) is a new non-destructive mass sensitive detector for gas chromatography that continuously and rapidly collects full wavelength range absorption between 120 and 240 nm. In addition to conventional methods of quantification (internal and external standard), gas chromatography - vacuum ultraviolet spectroscopy has the potential for pseudo-absolute quantification of analytes based on pre-recorded cross sections (well-defined absorptivity across the 120–240 nm wavelength range recorded by the detector) without the need for traditional calibration. The pseudo-absolute method was used in this research to experimentally evaluate the sources of sample loss and gain associated with sample introduction into a typical gas chromatograph. Standard samples of benzene and natural gas were used to assess precision and accuracy for the analysis of liquid and gaseous samples, respectively, based on the amount of analyte loaded on-column. Results indicate that injection volume, split ratio, and sampling times for splitless analysis can all contribute to inaccurate, yet precise sample introduction. For instance, an autosampler can very reproducibly inject a designated volume, but there are significant systematic errors (here, a consistently larger volume than that designated) in the actual volume introduced. The pseudo-absolute quantification capability of the vacuum ultraviolet detector provides a new means for carrying out system performance checks and potentially for solving challenging quantitative analytical problems. For practical purposes, an internal standardized approach to normalize systematic errors can be used to perform quantitative analysis with the pseudo-absolute method. - Highlights: • Gas chromatography diagnostics and quantification using VUV detector. • Absorption cross-sections for molecules enable pseudo-absolute quantitation. • Injection diagnostics reveal systematic errors in hardware settings. • Internal

Pseudo-absolute quantitative analysis using gas chromatography – Vacuum ultraviolet spectroscopy – A tutorial

International Nuclear Information System (INIS)

Bai, Ling; Smuts, Jonathan; Walsh, Phillip; Qiu, Changling; McNair, Harold M.; Schug, Kevin A.

2017-01-01

The vacuum ultraviolet detector (VUV) is a new non-destructive mass sensitive detector for gas chromatography that continuously and rapidly collects full wavelength range absorption between 120 and 240 nm. In addition to conventional methods of quantification (internal and external standard), gas chromatography - vacuum ultraviolet spectroscopy has the potential for pseudo-absolute quantification of analytes based on pre-recorded cross sections (well-defined absorptivity across the 120–240 nm wavelength range recorded by the detector) without the need for traditional calibration. The pseudo-absolute method was used in this research to experimentally evaluate the sources of sample loss and gain associated with sample introduction into a typical gas chromatograph. Standard samples of benzene and natural gas were used to assess precision and accuracy for the analysis of liquid and gaseous samples, respectively, based on the amount of analyte loaded on-column. Results indicate that injection volume, split ratio, and sampling times for splitless analysis can all contribute to inaccurate, yet precise sample introduction. For instance, an autosampler can very reproducibly inject a designated volume, but there are significant systematic errors (here, a consistently larger volume than that designated) in the actual volume introduced. The pseudo-absolute quantification capability of the vacuum ultraviolet detector provides a new means for carrying out system performance checks and potentially for solving challenging quantitative analytical problems. For practical purposes, an internal standardized approach to normalize systematic errors can be used to perform quantitative analysis with the pseudo-absolute method. - Highlights: • Gas chromatography diagnostics and quantification using VUV detector. • Absorption cross-sections for molecules enable pseudo-absolute quantitation. • Injection diagnostics reveal systematic errors in hardware settings. • Internal

3m vacuum ultraviolet spectrometer with optical multichanel detector

International Nuclear Information System (INIS)

Marin, P.; Peraza, C.; Blanco, F.; Campos, J.

1993-01-01

This paper, describes the design and the performance of a normal incidence vacuum ultraviolet spectrometer, for the 300-2400 A spectral range. It is provided with a multichannel detection system. The monochromator is original design and it has been built at CIEMAT: It is equipped with a 3 m concave holographic grating with 2400 grooves/mm. The multichannel detector consists of a windowless double microchannel plate/phosphor screen image intensifier, coupled by fiber optic to a 1024 elements self-scanning linear photodiode array. The output from the arrays is digitized by a 12-bit analog to digital converter and stored in a computer for its later analysis. The necessary software to store and display data has been developed. (Author)

The Ultraviolet Surprise. Efficient Soft X-Ray High Harmonic Generation in Multiply-Ionized Plasmas

International Nuclear Information System (INIS)

Popmintchev, Dimitar; Hernandez-Garcia, Carlos; Dollar, Franklin; Mancuso, Christopher; Perez-Hernandez, Jose A.; Chen, Ming-Chang; Hankla, Amelia; Gao, Xiaohui; Shim, Bonggu; Gaeta, Alexander L.; Tarazkar, Maryam; Romanov, Dmitri A.; Levis, Robert J.; Gaffney, Jim A.; Foord, Mark; Libby, Stephen B.; Jaron-Becker, Agnieskzka; Becker, Andreas; Plaja, Luis; Muranane, Margaret M.; Kapteyn, Henry C.; Popmintchev, Tenio

2015-01-01

High-harmonic generation is a universal response of matter to strong femtosecond laser fields, coherently upconverting light to much shorter wavelengths. Optimizing the conversion of laser light into soft x-rays typically demands a trade-off between two competing factors. Reduced quantum diffusion of the radiating electron wave function results in emission from each species which is highest when a short-wavelength ultraviolet driving laser is used. But, phase matching - the constructive addition of x-ray waves from a large number of atoms - favors longer-wavelength mid-infrared lasers. We identified a regime of high-harmonic generation driven by 40-cycle ultraviolet lasers in waveguides that can generate bright beams in the soft x-ray region of the spectrum, up to photon energies of 280 electron volts. Surprisingly, the high ultraviolet refractive indices of both neutral atoms and ions enabled effective phase matching, even in a multiply ionized plasma. We observed harmonics with very narrow linewidths, while calculations show that the x-rays emerge as nearly time-bandwidt-limited pulse trains of ~100 attoseconds

3m Vacuum Ultraviolet Spectrometer with Optical Multichannel Detector

International Nuclear Information System (INIS)

Martin, P.; Peraza, C.; Blanco, F.; Campos, J.

1993-01-01

This paper describes the design and the performance of a normal incidence vacuum ultraviolet spectrometer, for the 300-2400 A spectral range. It is provided with a multichannel detection system. The monochromator is original design and it has been built at CIEMAT. It is equipped with a 3 m concave holographic grating with 2400 grooves/mm. The multichannel detector consists of a windowless double microchannel plate / phosphor screen image intensifier, coupled by fiber optic to a 1024 elements self-scanning linear photodiode array. The output from the array is digitized by a 12-bit analog to digital converter and stored in a computer, for its later analysis. The necessary software to store and display data has been developed. (Author) 18 refs

Research on reinforcement effect of vacuum preloading to treatment of the soft foundation

Science.gov (United States)

Li, bin; Li, maoji

2017-12-01

vacuum preloading method is a commonly used method to reinforce soft ground at present. Monitoring during construction stage is a dynamic monitoring, which is a standard to judge the quality of construction. This paper relies on the reclamation project of Tianjin Port Industrial Zone in North China, analyzed the monitoring purposes, monitoring method and collection data. Results had shown that vacuum preloading monitoring can make an accurate evaluation of construction quality during construction. The project practice can provide reference for similar projects.

Laser Desorption Postionization Mass Spectrometry of Antibiotic-Treated Bacterial Biofilms using Tunable Vacuum Ultraviolet Radiation

Energy Technology Data Exchange (ETDEWEB)

Gasper, Gerald L; Takahashi, Lynelle K; Zhou, Jia; Ahmed, Musahid; Moore, Jerry F; Hanley, Luke

2010-08-04

Laser desorption postionization mass spectrometry (LDPI-MS) with 8.0 ? 12.5 eV vacuum ultraviolet synchrotron radiation is used to single photon ionize antibiotics andextracellular neutrals that are laser desorbed both neat and from intact bacterial biofilms. Neat antibiotics are optimally detected using 10.5 eV LDPI-MS, but can be ionized using 8.0 eV radiation, in agreement with prior work using 7.87 eV LDPI-MS. Tunable vacuum ultraviolet radiation also postionizes laser desorbed neutrals of antibiotics and extracellular material from within intact bacterial biofilms. Different extracellular material is observed by LDPI-MS in response to rifampicin or trimethoprim antibiotic treatment. Once again, 10.5 eV LDPI-MS displays the optimum trade-off between improved sensitivity and minimum fragmentation. Higher energy photons at 12.5 eV produce significant parent ion signal, but fragment intensity and other low mass ions are also enhanced. No matrix is added to enhance desorption, which is performed at peak power densities insufficient to directly produce ions, thus allowing observation of true VUV postionization mass spectra of antibiotic treated biofilms.

Vacuum ultraviolet Ar2*laser pumped by a high-intensity laser

International Nuclear Information System (INIS)

Kubodera, Shoichi; Kaku, Masanori; Higashiguchi, Takeshi

2004-01-01

We observed a small-signal gain of Ar 2 * emission at 126 nm by use of an Ar-filled hollow fiber to guide the ultrashort-pulse high-intensity laser propagation. The small signal gain coefficient was measured to be 0.05 cm -1 at 126 nm. Kinetic analysis revealed that the electrons produced by the high-intensity laser through an optical-field ionization process initiated the Ar 2 * production process. This laser scheme could be combined with high harmonic radiation of the pump laser in the vacuum ultraviolet (VUV), leading to the production of amplified ultrashort VUV pulses. (author)

Performance of a high resolution monochromator for the vacuum ultraviolet radiation from the DORIS storage ring

International Nuclear Information System (INIS)

Saile, V.; Skibowski, M.; Steinmann, W.; Guertler, P.; Koch, E.E.; Kozevnikov, A.

1976-03-01

The unique properties of the DORIS storage ring at DESY as a synchrotron radiation source are exploited for high resolution spectroscopy in the vacuum ultraviolet. We describe a new experimental set up with a 3 meter normal incidence monochromator for wavelengths between 3,000 A to 300 A (4 [de

Vacuum ultraviolet spectropolarimeter design for precise polarization measurements.

Science.gov (United States)

Narukage, Noriyuki; Auchère, Frédéric; Ishikawa, Ryohko; Kano, Ryouhei; Tsuneta, Saku; Winebarger, Amy R; Kobayashi, Ken

2015-03-10

Precise polarization measurements in the vacuum ultraviolet (VUV) region provide a new means for inferring weak magnetic fields in the upper atmosphere of the Sun and stars. We propose a VUV spectropolarimeter design ideally suited for this purpose. This design is proposed and adopted for the NASA-JAXA chromospheric lyman-alpha spectropolarimeter (CLASP), which will record the linear polarization (Stokes Q and U) of the hydrogen Lyman-α line (121.567 nm) profile. The expected degree of polarization is on the order of 0.1%. Our spectropolarimeter has two optically symmetric channels to simultaneously measure orthogonal linear polarization states with a single concave diffraction grating that serves both as the spectral dispersion element and beam splitter. This design has a minimal number of reflective components with a high VUV throughput. Consequently, these design features allow us to minimize the polarization errors caused by possible time variation of the VUV flux during the polarization modulation and by statistical photon noise.

Spectral filter for splitting a beam with electromagnetic radiation having wavelengths in the extreme ultraviolet (EUV) or soft X-Ray (Soft X) and the infrared (IR) wavelength range

NARCIS (Netherlands)

van Goor, F.A.; Bijkerk, Frederik; van den Boogaard, Toine; van den Boogaard, A.J.R.; van der Meer, R.

2012-01-01

Spectral filter for splitting the primary radiation from a generated beam with primary electromagnetic radiation having a wavelength in the extreme ultraviolet (EUV radiation) or soft X-ray (soft X) wavelength range and parasitic radiation having a wavelength in the infrared wavelength range (IR

Simultaneous removal of NO and SO2 using vacuum ultraviolet light (VUV)/heat/peroxymonosulfate (PMS).

Science.gov (United States)

Liu, Yangxian; Wang, Yan; Wang, Qian; Pan, Jianfeng; Zhang, Jun

2018-01-01

Simultaneous removal process of SO 2 and NO from flue gas using vacuum ultraviolet light (VUV)/heat/peroxymonosulfate (PMS) in a VUV spraying reactor was proposed. The key influencing factors, active species, reaction products and mechanism of SO 2 and NO simultaneous removal were investigated. The results show that vacuum ultraviolet light (185 nm) achieves the highest NO removal efficiency and yield of and under the same test conditions. NO removal is enhanced at higher PMS concentration, light intensity and oxygen concentration, and is inhibited at higher NO concentration, SO 2 concentration and solution pH. Solution temperature has a double impact on NO removal. CO 2 concentration has no obvious effect on NO removal. and produced from VUV-activation of PMS play a leading role in NO removal. O 3 and ·O produced from VUV-activation of O 2 also play an important role in NO removal. SO 2 achieves complete removal under all experimental conditions due to its very high solubility in water and good reactivity. The highest simultaneous removal efficiency of SO 2 and NO reaches 100% and 91.3%, respectively. Copyright © 2017 Elsevier Ltd. All rights reserved.

Vacuum ultraviolet photofragmentation of octadecane: photoionization mass spectrometric and theoretical investigation.

Science.gov (United States)

Xu, Jing; Sang, Pengpeng; Zhao, Lianming; Guo, Wenyue; Qi, Fei; Xing, Wei; Yan, Zifeng

The photoionization and fragmentation of octadecane were investigated with infrared laser desorption/tunable synchrotron vacuum ultraviolet (VUV) photoionization mass spectrometry (IRLD/VUV PIMS) and theoretical calculations. Mass spectra of octadecane were measured at various photon energies. The fragment ions were gradually detected with the increase of photon energy. The main fragment ions were assigned to radical ions (C n H 2 n +1 + , n  = 4-11) and alkene ions (C n H 2 n + , n  = 5-10). The ionization energy of the precursor and appearance energy of ionic fragments were obtained by measuring the photoionization efficiency spectrum. Possible formation pathways of the fragment ions were discussed with the help of density functional theory calculations.

Effects of plasma and vacuum-ultraviolet exposure on the mechanical properties of low-k porous organosilicate glass

Science.gov (United States)

X. Guo; J.E. Jakes; S. Banna; Y. Nishi; J.L. Shohet

2014-01-01

The effects of plasma exposure and vacuum-ultraviolet (VUV) irradiation on the mechanical properties of low-k porous organosilicate glass (SiCOH) dielectric films were investigated. Nanoindentation measurements were made on SiCOH films before and after exposure to an electron-cyclotron-resonance plasma or a monochromatic synchrotron VUV beam, to determine the changes...

Vacuum ultraviolet emission from argon, krypton, and xenon in a radial-viewed theta pinch

International Nuclear Information System (INIS)

Engleman, R. Jr.; Thomson, D.B.; Monaghan, D.A.

1976-03-01

Vacuum ultraviolet line emission from argon, krypton, and xenon (5 percent in deuterium) has been observed from a plasma (approximately 50 eV and N/sub e/ approximately 10 17 /cm 3 ) produced by the Scyllar linear theta-pinch device. More than 50 emission lines in the 30- to 500-A region have been measured for each gas mixture. Some lines have been identified as due to Ar VII through XI, Kr IX and X, and Xe IX, but many lines remain unassigned

Performance of the undulator based ultraviolet and soft x-ray beamline for catalysis and surface science at National Synchrotron Radiation Laboratory

Energy Technology Data Exchange (ETDEWEB)

Du, Liangliang [University of Science and Technology of China, Department of Precision Machinery and Precision Instrumentation, Hefei, Anhui 230029 (China); University of Science and Technology of China, National Synchrotron Radiation Laboratory, Hefei, Anhui 230029 (China); Du, Xuewei, E-mail: xwdu@ustc.edu.cn [University of Science and Technology of China, National Synchrotron Radiation Laboratory, Hefei, Anhui 230029 (China); Wei, Shen [University of Science and Technology of China, National Synchrotron Radiation Laboratory, Hefei, Anhui 230029 (China); Li, Chaoyang [China Academy of Engineering Physics, Mianyang, Sichuan 621900 (China); Pan, Congyuan; Ju, Huanxin [University of Science and Technology of China, National Synchrotron Radiation Laboratory, Hefei, Anhui 230029 (China); Wang, Qiuping, E-mail: qiuping@ustc.edu.cn [University of Science and Technology of China, National Synchrotron Radiation Laboratory, Hefei, Anhui 230029 (China); Zhu, Junfa [University of Science and Technology of China, National Synchrotron Radiation Laboratory, Hefei, Anhui 230029 (China)

2016-12-01

The undulator based ultraviolet and soft x-ray beamline BL11U for catalysis and surface science at National Synchrotron Radiation Laboratory (NSRL) has been under opteration for months and the present performance is described. This beamline utilizes radiation from an in-vacuum undulator, which has 30 magnetic periods with the period length of 40 mm. A varied-line-spacing plane grating monochromator is employed tto cover the photon energy region of 20–600 eV by two gratings with nominal groove densities of 400 llmm and 1200 l/mm respectively. The energy resolution power E/ΔE is measured with a gas ionization chamber and the photon flux is measured by a photodiode. Results show that the resolution power is better than 10,000 at a photon energy of 29.2 eV. And the flux is higher than 1×10{sup 10} phs/s under 300 mA ring beam current for most of the covered photon energy.

Measurements of the intrinsic quantum efficiency and absorption length of tetraphenyl butadiene thin films in the vacuum ultraviolet regime

Science.gov (United States)

Benson, Christopher; Gann, Gabriel Orebi; Gehman, Victor

2018-04-01

A key enabling technology for many liquid noble gas (LNG) detectors is the use of the common wavelength shifting medium tetraphenyl butadiene (TPB). TPB thin films are used to shift ultraviolet scintillation light into the visible spectrum for detection and event reconstruction. Understanding the wavelength shifting efficiency and optical properties of these films are critical aspects in detector performance and modeling and hence in the ultimate physics sensitivity of such experiments. This article presents the first measurements of the room-temperature microphysical quantum efficiency for vacuum-deposited TPB thin films - a result that is independent of the optics of the TPB or substrate. Also presented are measurements of the absorption length in the vacuum ultraviolet regime, the secondary re-emission efficiency, and more precise results for the "black-box" efficiency across a broader spectrum of wavelengths than previous results. The low-wavelength sensitivity, in particular, would allow construction of LNG scintillator detectors with lighter elements (Ne, He) to target light mass WIMPs.

Sub-mm Scale Fiber Guided Deep/Vacuum Ultra-Violet Optical Source for Trapped Mercury Ion Clocks

Science.gov (United States)

Yi, Lin; Burt, Eric A.; Huang, Shouhua; Tjoelker, Robert L.

2013-01-01

We demonstrate the functionality of a mercury capillary lamp with a diameter in the sub-mm range and deep ultraviolet (DUV)/ vacuum ultraviolet (VUV) radiation delivery via an optical fiber integrated with the capillary. DUV spectrum control is observed by varying the fabrication parameters such as buffer gas type and pressure, capillary diameter, electrical resonator design, and temperature. We also show spectroscopic data of the 199Hg+ hyper-fine transition at 40.5GHz when applying the above fiber optical design. We present efforts toward micro-plasma generation in hollow-core photonic crystal fiber with related optical design and theoretical estimations. This new approach towards a more practical DUV optical interface could benefit trapped ion clock developments for future ultra-stable frequency reference and time-keeping applications.

Degradation of quinoline and isoquinoline by vacuum ultraviolet light and mechanism thereof

International Nuclear Information System (INIS)

Zhu Dazhang; Ni Yaming; Sun Dongmei; Wang Shilong; Sun Xiaoyu; Yao Side

2010-01-01

Since the wavelength is shorter than 190 nm, vacuum ultraviolet light has high energy enough to break the H-O bonds of water to produce HO·, as well as the protection is very easy, degradation of organic contaminants in water by vacuum ultraviolet light has obviously excellent feature of no reagent adding to the wastewater among advanced oxidation technologies. In this paper, it was reported that quinoline and isoquinoline were degraded in water by the irradiation of low-pressure quartz mercury light with the electric power of 200 W which mainly emitted the light of 185 nm and 254 nm. The change regulation of the concentration of substrates, chemical oxygen demand (COD) and total organic carbon (TOC) were investigated as well as the degradation processes of quinoline and isoquinoline were compared. It showed that both quinoline and isoquinoline could be degraded very fast under the given conditions. The concentration of the substrates decreased to nearly 0 in 10 minutes while the apparent first reaction rate constants were 0.41 ± 0.02 min -1 and 0.19 ± 0.01 min -1 , respectively. Meanwhile, the COD and TOC decreased to nearly 0 in 30 minutes. Quinoline has the faster degradation rate. In order to investigate mechanism thereof, pulse radiolysis and laser flash photolysis of quinoline and isoquinoline aqueous solution were performed, respectively. Pulse radiolysis indicated that the reaction rate constant of quinoline and HO· was faster than that of isoquinoline. In the meanwhile, laser flash photolysis indicated that both quinoline and isoquinoline could be ionized by the UV-C light while the photo-ionization efficiency of quinoline was higher than that of quinoline. These two reasons caused the faster degradation rate of quinoline. (authors)

Vacuum ultra-violet and electron energy loss spectroscopy of gaseous and solid organic compounds

International Nuclear Information System (INIS)

Koch, E.E.; Otto, A.

1976-01-01

The experimental arrangements used by the authors for the study of optical vacuum ultra-violet and electron energy loss spectra of organic compounds are described and some theoretical aspects of studies of higher excited states are considered. Results for alkanes, benzene, naphthalene, anthracene and some more complex hydrocarbons are reviewed. Recent results obtained by reflection and electron energy loss spectroscopy for single crystals of anthracene are included and their relevance for gas phase work as well as for the understanding of exciton effects in organic solids is described. (author)

Vacuum Ultraviolet Single-Photon Postionization of Amino Acids

Directory of Open Access Journals (Sweden)

Hsu Chen Hsu

2018-05-01

Full Text Available In this study, ultraviolet (UV laser desorption and vacuum UV single-photon (VUV SP postionization were performed to ionize and successfully analyze 20 common amino acids. The analytical merit and efficiency of the ionization was compared with those of conventional UV matrix-assisted laser desorption ionization (UV-MALDI. A VUV light source (118 nm was generated from the ninth harmonic of a Q-switched Nd:YAG laser, and the photon number was determined to be larger than 1012 for each laser pulse in the ionization region. In general, the detection sensitivity of VUV-SP-postionization was 10–100 times higher than that of conventional UV-MALDI. In particular, the ion signal from VUV-SP-postionization was considerably larger than that from UV-MALDI for analytes with low proton affinity such as glycine. However, some fragmentation of intact ions was observed in VUV-SP-postionization. Quantitative analysis performed using a glycine/histidine mixture and tryptophan/phenylalanine mixture revealed that the dynamic range of VUV-SP-postionization was one order of magnitude larger than that of UV-MALDI, indicating that VUV-SP-postionization is suitable for the quantitative analysis of amino acids.

Vacuum-ultraviolet ellipsometry spectra and structural properties of Pb(Zr,Ti)O.sub.3./sub. films

Czech Academy of Sciences Publication Activity Database

Suchaneck, G.; Chvostová, Dagmar; Kousal, J.; Železný, Vladimír; Lynnyková, Anna; Jastrabík, Lubomír; Gerlach, G.; Dejneka, Alexandr

2011-01-01

Roč. 519, č. 9 (2011), s. 2885-2888 ISSN 0040-6090 R&D Projects: GA ČR GC202/09/J017; GA AV ČR KAN301370701; GA MŠk(CZ) 1M06002; GA ČR GA202/08/1009 Institutional research plan: CEZ:AV0Z10100522 Keywords : PZT film * vacuum-ultraviolet ellipsometry * film structure * optical properties Subject RIV: BH - Optics, Masers, Lasers Impact factor: 1.890, year: 2011

Vacuum ultraviolet photoionization of carbohydrates and nucleotides

Energy Technology Data Exchange (ETDEWEB)

Shin, Joong-Won, E-mail: jshin@govst.edu [Division of Science, Governors State University, University Park, Illinois 60484-0975 (United States); Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872 (United States); Bernstein, Elliot R., E-mail: erb@lamar.colostate.edu [Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872 (United States)

2014-01-28

Carbohydrates (2-deoxyribose, ribose, and xylose) and nucleotides (adenosine-, cytidine-, guanosine-, and uridine-5{sup ′}-monophosphate) are generated in the gas phase, and ionized with vacuum ultraviolet photons (VUV, 118.2 nm). The observed time of flight mass spectra of the carbohydrate fragmentation are similar to those observed [J.-W. Shin, F. Dong, M. Grisham, J. J. Rocca, and E. R. Bernstein, Chem. Phys. Lett. 506, 161 (2011)] for 46.9 nm photon ionization, but with more intensity in higher mass fragment ions. The tendency of carbohydrate ions to fragment extensively following ionization seemingly suggests that nucleic acids might undergo radiation damage as a result of carbohydrate, rather than nucleobase fragmentation. VUV photoionization of nucleotides (monophosphate-carbohydrate-nucleobase), however, shows that the carbohydrate-nucleobase bond is the primary fragmentation site for these species. Density functional theory (DFT) calculations indicate that the removed carbohydrate electrons by the 118.2 nm photons are associated with endocyclic C–C and C–O ring centered orbitals: loss of electron density in the ring bonds of the nascent ion can thus account for the observed fragmentation patterns following carbohydrate ionization. DFT calculations also indicate that electrons removed from nucleotides under these same conditions are associated with orbitals involved with the nucleobase-saccharide linkage electron density. The calculations give a general mechanism and explanation of the experimental results.

Vacuum ultraviolet photoionization of carbohydrates and nucleotides

International Nuclear Information System (INIS)

Shin, Joong-Won; Bernstein, Elliot R.

2014-01-01

Carbohydrates (2-deoxyribose, ribose, and xylose) and nucleotides (adenosine-, cytidine-, guanosine-, and uridine-5 ′ -monophosphate) are generated in the gas phase, and ionized with vacuum ultraviolet photons (VUV, 118.2 nm). The observed time of flight mass spectra of the carbohydrate fragmentation are similar to those observed [J.-W. Shin, F. Dong, M. Grisham, J. J. Rocca, and E. R. Bernstein, Chem. Phys. Lett. 506, 161 (2011)] for 46.9 nm photon ionization, but with more intensity in higher mass fragment ions. The tendency of carbohydrate ions to fragment extensively following ionization seemingly suggests that nucleic acids might undergo radiation damage as a result of carbohydrate, rather than nucleobase fragmentation. VUV photoionization of nucleotides (monophosphate-carbohydrate-nucleobase), however, shows that the carbohydrate-nucleobase bond is the primary fragmentation site for these species. Density functional theory (DFT) calculations indicate that the removed carbohydrate electrons by the 118.2 nm photons are associated with endocyclic C–C and C–O ring centered orbitals: loss of electron density in the ring bonds of the nascent ion can thus account for the observed fragmentation patterns following carbohydrate ionization. DFT calculations also indicate that electrons removed from nucleotides under these same conditions are associated with orbitals involved with the nucleobase-saccharide linkage electron density. The calculations give a general mechanism and explanation of the experimental results

Vacuum ultraviolet beamline at the Swiss Light Source for chemical dynamics studies

International Nuclear Information System (INIS)

Johnson, Melanie; Bodi, Andras; Schulz, Lothar; Gerber, Thomas

2009-01-01

A bend-magnet vacuum ultraviolet (VUV) beamline, intended for chemical dynamics studies, was constructed and brought into operation at the Swiss Light Source (SLS) of the Paul Scherrer Institut. The beamline delivers synchrotron radiation in the 5-30 eV photon energy range with a photon flux of 10 11 photons/s at 10 eV and 10 12 photons/s at 20 eV with a resolving power of 2500. The resolving power increases to 10 4 at the cost of photon flux. An in-house designed rare gas filter is used to suppress higher harmonic radiation by a factor of >10 4 , yielding purely monochromatic light in the energy range of 5-21.6 eV. The filter is compact, easy to align, requires a total pumping power of less than 645 l/s and consumes only 3 normal l/h of filter gas. It is located at the end of the beamline, right in front of the experimental endstation. It is usually operated at a higher pressure than the endstation, which offers the additional benefit of protecting the beamline vacuum from sample contamination.

Possibility of using sources of vacuum ultraviolet irradiation to solve problems of space material science

Science.gov (United States)

Verkhoutseva, E. T.; Yaremenko, E. I.

1974-01-01

An urgent problem in space materials science is simulating the interaction of vacuum ultraviolet (VUV) of solar emission with solids in space conditions, that is, producing a light source with a distribution that approximates the distribution of solar energy. Information is presented on the distribution of the energy flux of VUV of solar radiation. Requirements that must be satisfied by the VUV source used for space materials science are formulated, and a critical evaluation is given of the possibilities of using existing sources for space materials science. From this evaluation it was established that none of the sources of VUV satisfies the specific requirements imposed on the simulator of solar radiation. A solution to the problem was found to be in the development of a new type of source based on exciting a supersonic gas jet flowing into vacuum with a sense electron beam. A description of this gas-jet source, along with its spectral and operation characteristics, is presented.

Broadband interference lithography at extreme ultraviolet and soft x-ray wavelengths.

Science.gov (United States)

Mojarad, Nassir; Fan, Daniel; Gobrecht, Jens; Ekinci, Yasin

2014-04-15

Manufacturing efficient and broadband optics is of high technological importance for various applications in all wavelength regimes. Particularly in the extreme ultraviolet and soft x-ray spectra, this becomes challenging due to the involved atomic absorption edges that rapidly change the optical constants in these ranges. Here we demonstrate a new interference lithography grating mask that can be used for nanopatterning in this spectral range. We demonstrate photolithography with cutting-edge resolution at 6.5 and 13.5 nm wavelengths, relevant to the semiconductor industry, as well as using 2.5 and 4.5 nm wavelength for patterning thick photoresists and fabricating high-aspect-ratio metal nanostructures for plasmonics and sensing applications.

Vacuum space charge effects in sub-picosecond soft X-ray photoemission on a molecular adsorbate layer.

Science.gov (United States)

Dell'Angela, M; Anniyev, T; Beye, M; Coffee, R; Föhlisch, A; Gladh, J; Kaya, S; Katayama, T; Krupin, O; Nilsson, A; Nordlund, D; Schlotter, W F; Sellberg, J A; Sorgenfrei, F; Turner, J J; Öström, H; Ogasawara, H; Wolf, M; Wurth, W

2015-03-01

Vacuum space charge induced kinetic energy shifts of O 1s and Ru 3d core levels in femtosecond soft X-ray photoemission spectra (PES) have been studied at a free electron laser (FEL) for an oxygen layer on Ru(0001). We fully reproduced the measurements by simulating the in-vacuum expansion of the photoelectrons and demonstrate the space charge contribution of the high-order harmonics in the FEL beam. Employing the same analysis for 400 nm pump-X-ray probe PES, we can disentangle the delay dependent Ru 3d energy shifts into effects induced by space charge and by lattice heating from the femtosecond pump pulse.

Permanent hydrophilic modification of polypropylene and poly(vinyl alcohol) films by vacuum ultraviolet radiation

Energy Technology Data Exchange (ETDEWEB)

Belmonte, Guilherme Kretzmann [Instituto de Química, Universidade Federal do Rio Grande do Sul (UFRGS), Avenida Bento Gonçalves 9500, 91501-970 Porto Alegre, RS (Brazil); Charles, German [Centro de Química Aplicada (CEQUIMAP), Facultad de Ciencias Químicas, Unversidad Nacional de Córdoba, Haya de la Torre y Medina Allende, Edificio de Ciencias II, Ciudad Universitaria, Córdoba 5000 (Argentina); Strumia, Miriam Cristina [Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, IPQA-Conicet, Haya de la Torre y Medina Allende, Edificio de Ciencias II, Ciudad Universitaria, Córdoba 5000 (Argentina); Weibel, Daniel Eduardo, E-mail: danielw@iq.ufrgs.br [Instituto de Química, Universidade Federal do Rio Grande do Sul (UFRGS), Avenida Bento Gonçalves 9500, 91501-970 Porto Alegre, RS (Brazil)

2016-09-30

Highlights: • Polypropylene and Poly(vinyl alcohol) were surface modified by vacuum ultraviolet (VUV) irradiation. • The hydrophilicity of the treated films was permanent and resisted aging for several months. • Grafting of styrene monomer was only observed in the VUV irradiated regions. • The obtained results showed the potential in the use of VUV treatment for surface modification and processing of polymers which lack chromophores in the UV region. - Abstract: Polypropylene (PP) and Poly(vinyl alcohol) (PVA) both synthetics polymers but one of them biodegradable, were surface modified by vacuum ultraviolet (VUV) irradiation. After VUV irradiation in an inert nitrogen atmosphere, the films were exposed to oxygen gas. The treated films were characterized by water contact angle measurements (WCA), optical profilometry, FTIR-ATR, XPS, UPS and NEXAFS techniques. PP and PVA VUV-treated films reached superhydrophilic conditions (WCAs <10°) in about 30 min of irradiation under our experimental conditions. It was observed that when the WCAs reached about 35–40° the hydrophilicity was permanent in both polymers. These results contrasted with typical plasma treatments were a rapid hydrophobic recovery with aging time is usually observed. UPS and XPS data showed the presence of new functionalities on the PP and PVA surfaces that were assigned to COO, C=O, C−O and C=C functional groups. Finally, grafting of styrene (ST) as a typical monomer was tested on PP films. It was confirmed that only in the VUV irradiated region an efficient grafting of ST or polymerized ST was found. Outside the irradiated regions no ST grafted was observed. Our results showed the potential use of VUV treatment for surface modification and processing of polymers which lack chromophores in the UV region.

Correspondence of vacuum ultraviolet aurora image with the inverted-V structure observed by Kyokko

International Nuclear Information System (INIS)

Kaneda, Eisuke; Mukai, Toshifumi; Hirao, Kunio.

1982-01-01

Since the Kyokko has been in an orbit with the inclination of 65.3 degree, various patterns of the inverted-V structure can be observed. Correspondence of vacuum ultraviolet aurora image with the inverted-V structure was studied. The energy-time diagrams were obtained. The inverted-V event occurrence map was made. The down-dusk asymmetry was recognized. The patterns of the inverted-V structure observed at present were not much different from previous ones. The observed aurora images showed not only the patterns of aurora, but also the state of aurora spreading in the polar region. Some of the observed results of energy characteristics and the aurora images are shown. (Kato, T.)

Vacuum ultraviolet-induced surface modification of cyclo-olefin polymer substrates for photochemical activation bonding

International Nuclear Information System (INIS)

Kim, Young-Jong; Taniguchi, Yoshinao; Murase, Kuniaki; Taguchi, Yoshihiro; Sugimura, Hiroyuki

2009-01-01

The surface of cyclo-olefin polymer (COP) was treated with vacuum ultraviolet (VUV) light at 172 nm wavelength to improve the wettability and adhesion properties. Through VUV treatment in air, the terminal groups of the COP surface were oxidized into oxygen functional groups, containing C-O, C=O, and COO components, making the COP surface hydrophilic. The extent of oxygenation was evaluated by XPS and FTIR-ATR spectra, and it was shown that the surface properties, hydrophilicity, and functionalization were dependent on both VUV irradiation distance and irradiation time, which have an effect on the concentration of oxygen functional groups. VUV-light treatment with a short irradiation distance was more effective in introducing oxygen functional groups.

Probing the diffusion of vacuum ultraviolet ({lambda} = 172 nm) induced oxidants by nanoparticles immobilization

Energy Technology Data Exchange (ETDEWEB)

Khatri, Om P.; Hatanaka, Takeshi; Murase, Kuniaki [Department of Materials Science and Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501 (Japan); Sugimura, Hiroyuki, E-mail: hiroyuki.sugimura@materials.mbox.media.kyoto-u.ac.jp [Department of Materials Science and Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501 (Japan)

2009-09-30

Vacuum ultraviolet (VUV, {lambda} = 172 nm) patterning of alkyl monolayer on silicon surface has been demonstrated with emphasis on the diffusion of VUV induced oxygen-derived active species, which are accountable for the pattern broadening. The VUV photons photo-dissociates the atmospheric oxygen and water molecules into the oxygen-derived active species (oxidants). These oxidants photo-oxidize the hexadecyl (HD) monolayer in VUV irradiated regions (Khatri et al., Langmuir. 24 (2008) 12077), as well as the little concentration of oxidants diffuses towards the masked areas. In this study, we performed VUV patterning at a vacuum pressure of 10 Pa to track the diffusion pathways for the oxidants with help of gold nanoparticles (AuNPs; {phi} = 10 nm) immobilization. At VUV irradiated sites AuNPs are found as uniformly distributed, but adjacent to the pattern boundary we observed quasi-linear arrays of AuNPs, which are determined by diffusion pathways of the oxidants. The diffusion of oxidants plays vital role in pattern broadening. The site selective anchoring of AuNPs demonstrates the utility of VUV photons for the construction of functional materials with microstructural architecture.

Study of higher hydrocarbon production during ethylacetylene pyrolysis using laser-generated vacuum-ultraviolet photoionization detection

Energy Technology Data Exchange (ETDEWEB)

Boyle, J.; Pfefferle, L. (Yale Univ., New Haven, CT (USA))

1990-04-19

Higher hydrocarbon formation during the pyrolysis of ethylacetylene in a microjet reactor was studied by vacuum-ultraviolet photoionization time-of-flight mass spectrometry. At the wavelength employed, this ionization technique allows for the simultaneous detection of both stable and intermediate polyatomic species with ionization potentials below 10.49 eV, including most hydrocarbons with two or more carbon atoms. Minimal fragmentation simplifies the determination of parent species and allows identification of probable reaction pathways involving hydrocarbon radicals as well as stable species. The pyrolysis of ethylacetylene was carried out in the fast-flow microjet reactor (residence times 1-2 ms) at temperatures from 300 to 1,600 K.

Validation of the uncertainty budget for soft X-ray radiant power measurement using a cryogenic radiometer

CERN Document Server

Rabus, H; Scholze, F; Thornagel, R; Ulm, G

2002-01-01

The cryogenic radiometer SYRES, a thermal detector based on the electrical substitution principle, has been used as the primary detector standard for radiant power measurement in the ultraviolet, vacuum ultraviolet and soft X-ray spectral ranges. In order to investigate the possibility of radiant energy being deposited in its absorber cavity without being transformed into heat when detecting soft X-rays, SYRES has been directly compared with the electron storage ring BESSY 1, a primary radiometric source standard of calculable spectral radiant power. To this end, the integral radiant power emitted by the storage ring,into a solid angle defined by a high-precision aperture was measured with SYRES. The experiments were conducted at two nominal energies of the circulating electrons, 800 MeV and 340 MeV, to study the influence of the different spectral distributions of the synchrotron radiation. For the original graphite-coated cavity absorber, significant discrepancies were found which could be traced back to th...

Erosion behavior of soft, amorphous deuterated carbon films by heat treatment in air and under vacuum

International Nuclear Information System (INIS)

Maruyama, K.

1999-01-01

The erosion of soft a-C:D films by heat treatment in air and under vacuum is studied by ion-beam analysis. When the films are heated in air above 500 K, the film thickness and the areal densities of C and especially D decrease, and oxygen is incorporated in the films. The initial atomic loss rates of carbon and deuterium from the films are 2.6 x 10 17 C atoms cm -2 h -1 and 4.8 x 10 17 D atoms cm -2 h -1 at 550 K. However, after D depletion the films show a resistivity against further erosion due to annealing in air. When the films are heated under vacuum erosion starts at about 600 K and all components including D decrease proportionally to the film thickness. Thermal desorption spectroscopy of the films reveals the evolution of C x D y type hydrocarbons. Infrared analysis shows that the incorporated oxygen is chemically bonded to carbon. The thermally-activated decomposition of the soft a-C:D films is compared to that of hard a-C:D films and a reaction scheme is suggested. (orig.)

Luminescent properties of Pr3+-sensitized LaPO4:Gd3+ ultraviolet-B phosphor under vacuum-ultraviolet light excitation

International Nuclear Information System (INIS)

Okamoto, Shinji; Uchino, Rika; Kobayashi, Keisuke; Yamamoto, Hajime

2009-01-01

Luminescent properties of Pr 3+ -sensitized LaPO 4 :Gd 3+ under vacuum-ultraviolet (vuv) light excitation have been investigated. The energy transfer probably occurs from the 5d levels in Pr 3+ ions to Gd 3+ ions under 172 nm light excitation. LaPO 4 :Gd 3+ ,Pr 3+ shows efficient ultraviolet-B (uv-B) emission at 312 nm, whose peak intensity reaches its maximum at Gd=35 mol % and Pr=5 mol %. (La 0.65 Gd 0.35 ) 0.95 Pr 0.05 PO 4 is about 1.6 times higher than a typical uv-B phosphor for vuv lamp, Y 0.75 Gd 0.25 Al 3 (BO 3 ) 4 , in Gd 3+ -emission intensity under 172 nm light excitation. This result implies that the Pr 3+ -sensitized LaPO 4 :Gd 3+ is a candidate of uv-B phosphors for xenon-excimer discharge vuv lamps. In order to evaluate the effect of the narrow-band uv-B emission by LaPO 4 :Gd 3+ ,Pr 3+ phosphor, irradiation test on DNA was performed. The irradiation damage of pUC 18 DNA by the narrow-band uv-B light from the LaPO 4 :Gd 3+ ,Pr 3+ phosphor is in the same magnitude as that by uv-A light from a filtered Hg lamp, even though the uv-B lamp is higher than the uv-A lamp in power density and photon energy.

Soft X-Ray Measurements of Z-Pinch-Driven Vacuum Hohlraums

International Nuclear Information System (INIS)

Baker, K.L.; Porter, J.L.; Ruggles, L.E.; Chandler, G.A.; Deeney, Chris; Varas, M.; Moats, Ann; Struve, Ken; Torres, J.; McGurn, J.; Simpson, W.W.; Fehl, D.L.; Chrien, R.E.; Matuska, W.; Idzorek, G.C.

1999-01-01

This article reports the experimental characterization of a z-pinch driven-vacuum hohlraum. The authors have measured soft x-ray fluxes of 5 x 10 12 W/cm 2 radiating from the walls of hohlraums which are 2.4--2.5 cm in diameter by 1 cm tall. The x-ray source used to drive these hohlraums was a z-pinch consisting of a 300 wire tungsten array driven by a 2 MA, 100 ns current pulse. In this hohlraum geometry, the z-pinch x-ray source can produce energies in excess of 800 kJ and powers in excess of 100 TW to drive these hohlraums. The x-rays released in these hohlraums represent greater than a factor of 25 in energy and more than a factor of three in x-ray power over previous laboratory-driven hohlraums

High-Resolution Electronics: Spontaneous Patterning of High-Resolution Electronics via Parallel Vacuum Ultraviolet (Adv. Mater. 31/2016).

Science.gov (United States)

Liu, Xuying; Kanehara, Masayuki; Liu, Chuan; Sakamoto, Kenji; Yasuda, Takeshi; Takeya, Jun; Minari, Takeo

2016-08-01

On page 6568, T. Minari and co-workers describe spontaneous patterning based on the parallel vacuum ultraviolet (PVUV) technique, enabling the homogeneous integration of complex, high-resolution electronic circuits, even on large-scale, flexible, transparent substrates. Irradiation of PVUV to the hydrophobic polymer surface precisely renders the selected surface into highly wettable regions with sharply defined boundaries, which spontaneously guides a metal nanoparticle ink into a series of circuit lines and gaps with the widths down to a resolution of 1 μm. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Vacuum ultraviolet photochemistry of tetrahydrothiophene and sulfolane

International Nuclear Information System (INIS)

Scala, A.A.; Colon, I.

1979-01-01

The vacuum uv photolysis of tetrahydrothiophene (THT) involves the breaking of the S to α-C bond. Besides ethylene, C 3 H 6 and 1,3-butadiene are also formed. Photolyses of THT, tetrahydrofuran, and pyrrolidine are similar. The vacuum uv photolysis of tetramethylene sulfone (sulfolane) was also studied; products are SO 2 , cyclobutane, 1-butene, and ethylene. No cis-2-butene was observed

Broadband transmission masks, gratings and filters for extreme ultraviolet and soft X-ray lithography

International Nuclear Information System (INIS)

Brose, S.; Danylyuk, S.; Juschkin, L.; Dittberner, C.; Bergmann, K.; Moers, J.; Panaitov, G.; Trellenkamp, St.; Loosen, P.; Grützmacher, D.

2012-01-01

Lithography and patterning on a nanometre scale with extreme ultraviolet (EUV) and soft X-ray radiation allow creation of high resolution, high density patterns independent of a substrate type. To realize the full potential of this method, especially for EUV proximity printing and interference lithography, a reliable technology for manufacturing of the transmission masks and gratings should be available. In this paper we present a development of broadband amplitude transmission masks and gratings for extreme ultraviolet and soft X-ray lithography based on free-standing niobium membranes. In comparison with a standard silicon nitride based technology the transmission masks demonstrate high contrast not only for in-band EUV (13.5 nm) radiation but also for wavelengths below Si L-absorption edge (12.4 nm). The masks and filters with free standing areas up to 1000 × 1000 μm 2 and 100 nm to 300 nm membrane thicknesses are shown. Electron beam structuring of an absorber layer with dense line and dot patterns with sub-50 nm structures is demonstrated. Diffractive and filtering properties of obtained structures are examined with EUV radiation from a gas discharge plasma source. - Highlights: ► Broadband transmission masks for EUV proximity and interference lithography. ► Technology for free standing niobium membranes with areas up to 1 mm 2 . ► High density patterns with periods of 100 nm and structure sizes below 40 nm. ► Measured diffraction efficiency at 11 nm is in agreement with the theory. ► Produced masks can be effectively used with wavelengths between 6 nm and 17 nm.

Vacuum ultraviolet photoionization cross section of the hydroxyl radical.

Science.gov (United States)

Dodson, Leah G; Savee, John D; Gozem, Samer; Shen, Linhan; Krylov, Anna I; Taatjes, Craig A; Osborn, David L; Okumura, Mitchio

2018-05-14

The absolute photoionization spectrum of the hydroxyl (OH) radical from 12.513 to 14.213 eV was measured by multiplexed photoionization mass spectrometry with time-resolved radical kinetics. Tunable vacuum ultraviolet (VUV) synchrotron radiation was generated at the Advanced Light Source. OH radicals were generated from the reaction of O( 1 D) + H 2 O in a flow reactor in He at 8 Torr. The initial O( 1 D) concentration, where the atom was formed by pulsed laser photolysis of ozone, was determined from the measured depletion of a known concentration of ozone. Concentrations of OH and O( 3 P) were obtained by fitting observed time traces with a kinetics model constructed with literature rate coefficients. The absolute cross section of OH was determined to be σ(13.436 eV) = 3.2 ± 1.0 Mb and σ(14.193 eV) = 4.7 ± 1.6 Mb relative to the known cross section for O( 3 P) at 14.193 eV. The absolute photoionization spectrum was obtained by recording a spectrum at a resolution of 8 meV (50 meV steps) and scaling to the single-energy cross sections. We computed the absolute VUV photoionization spectrum of OH and O( 3 P) using equation-of-motion coupled-cluster Dyson orbitals and a Coulomb photoelectron wave function and found good agreement with the observed absolute photoionization spectra.

Vacuum ultraviolet photoionization cross section of the hydroxyl radical

Science.gov (United States)

Dodson, Leah G.; Savee, John D.; Gozem, Samer; Shen, Linhan; Krylov, Anna I.; Taatjes, Craig A.; Osborn, David L.; Okumura, Mitchio

2018-05-01

The absolute photoionization spectrum of the hydroxyl (OH) radical from 12.513 to 14.213 eV was measured by multiplexed photoionization mass spectrometry with time-resolved radical kinetics. Tunable vacuum ultraviolet (VUV) synchrotron radiation was generated at the Advanced Light Source. OH radicals were generated from the reaction of O(1D) + H2O in a flow reactor in He at 8 Torr. The initial O(1D) concentration, where the atom was formed by pulsed laser photolysis of ozone, was determined from the measured depletion of a known concentration of ozone. Concentrations of OH and O(3P) were obtained by fitting observed time traces with a kinetics model constructed with literature rate coefficients. The absolute cross section of OH was determined to be σ(13.436 eV) = 3.2 ± 1.0 Mb and σ(14.193 eV) = 4.7 ± 1.6 Mb relative to the known cross section for O(3P) at 14.193 eV. The absolute photoionization spectrum was obtained by recording a spectrum at a resolution of 8 meV (50 meV steps) and scaling to the single-energy cross sections. We computed the absolute VUV photoionization spectrum of OH and O(3P) using equation-of-motion coupled-cluster Dyson orbitals and a Coulomb photoelectron wave function and found good agreement with the observed absolute photoionization spectra.

Spectrograms of the JT-60 plasmas in the vacuum ultraviolet region (wavelength region 15 ∼ 1360 A)

International Nuclear Information System (INIS)

Kubo, Hirotaka; Sugie, Tatsuo; Sakasai, Akira; Koide, Yoshihiko; Nishino, Nobuhiro; Akaoka, Nobuo

1988-07-01

Spectrograms in the vacuum ultraviolet region have been obtained by a 3 m grazing incidence spectrograph in order to study impurity behaviors in JT-60 plasma. The spectrograms have been investigated in the first OH experiments, High-Ti mode experiments, and the experiments that were carried out after the replacement of 40 % of the first wall of the vacuum vessel with graphite tiles. In the first OH experiments, the spectrogram which covered the wavelength region of 15 ∼ 1360 A was obtained, and spectral lines of oxygen, carbon, and titanium were identified. In High-Ti mode experiments, the spectrogram which covered the wavelength region of 17 ∼ 77 A was obtained, and spectral lines of highly ionized molybdenum were identified in addition to those of oxygen, carbon, and titanium. In the experiments after the replacement of the first wall, the spectrogram which covered the wavelength region of 15 ∼ 55 A was obtained, and it was found clearly that the metallic impurities decreased. (author)

A single-shot nonlinear autocorrelation approach for time-resolved physics in the vacuum ultraviolet spectral range

International Nuclear Information System (INIS)

Rompotis, Dimitrios

2016-02-01

In this work, a single-shot temporal metrology scheme operating in the vacuum-extreme ultraviolet spectral range has been designed and experimentally implemented. Utilizing an anti-collinear geometry, a second-order intensity autocorrelation measurement of a vacuum ultraviolet pulse can be performed by encoding temporal delay information on the beam propagation coordinate. An ion-imaging time-of-flight spectrometer, offering micrometer resolution has been set-up for this purpose. This instrument enables the detection of a magnified image of the spatial distribution of ions exclusively generated by direct two-photon absorption in the combined counter-propagating pulse focus and thus obtain the second-order intensity autocorrelation measurement on a single-shot basis. Additionally, an intense VUV light source based on high-harmonic generation has been experimentally realized. It delivers intense sub-20 fs Ti:Sa fifth-harmonic pulses utilizing a loose-focusing geometry in a long Ar gas cell. The VUV pulses centered at 161.8 nm reach pulse energies of 1.1 μJ per pulse, while the corresponding pulse duration is measured with a second-order, fringe-resolved autocorrelation scheme to be 18 ± 1 fs on average. Non-resonant, two-photon ionization of Kr and Xe and three-photon ionization of Ne verify the fifth-harmonic pulse intensity and indicate the feasibility of multi-photon VUV pump/VUV probe studies of ultrafast atomic and molecular dynamics. Finally, the extended functionally of the counter-propagating pulse metrology approach is demonstrated by a single-shot VUV pump/VUV probe experiment aiming at the investigation of ultrafast dissociation dynamics of O 2 excited in the Schumann-Runge continuum at 162 nm.

Luminescence of Ce3+ at two different sites in ?-Sr2P2O7 under vacuum ultraviolet-UV and x-ray excitation

NARCIS (Netherlands)

Hou, D.; Han, B.; Chen, W.; Liang, H.; Su, Q.; Dorenbos, P.; Huang, Y.; Gao, Z.; Tao, Y.

2010-01-01

A series of Ce3+ doped ?-Sr2?2xCexNaxP2O7 phosphor compounds has been prepared using a high-temperature solid-state reaction technique. The luminescence properties under vacuum ultraviolet-UV and x-ray excitation were studied. Luminescence spectra reveal three UV-emitting peaks at about 310, 330,

Vacuum ultraviolet photoionization mass spectrometric study of cyclohexene.

Science.gov (United States)

Chen, Jun; Cao, Maoqi; Wei, Bin; Ding, Mengmeng; Shan, Xiaobin; Liu, Fuyi; Sheng, Liusi

2016-02-01

In this work, photoionization and dissociation of cyclohexene have been studied by means of coupling a reflectron time-of-flight mass spectrometer with the tunable vacuum ultraviolet (VUV) synchrotron radiation. The adiabatic ionization energy of cyclohexene as well as the appearance energies of its fragment ions C6 H9 (+) , C6 H7 (+) , C5 H7 (+) , C5 H5 (+) , C4 H6 (+) , C4 H5 (+) , C3 H5 (+) and C3 H3 (+) were derived from the onset of the photoionization efficiency (PIE) curves. The optimized structures for the transition states and intermediates on the ground state potential energy surfaces related to photodissociation of cyclohexene were characterized at the ωB97X-D/6-31+g(d,p) level. The coupled cluster method, CCSD(T)/cc-pVTZ, was employed to calculate the corresponding energies with the zero-point energy corrections by the ωB97X-D/6-31+g(d,p) approach. Combining experimental and theoretical results, possible formation pathways of the fragment ions were proposed and discussed in detail. The retro-Cope rearrangement was found to play a crucial role in the formation of C4 H6 (+) , C4 H5 (+) and C3 H5 (+) . Intramolecular hydrogen migrations were observed as dominant processes in most of the fragmentation pathways of cyclohexene. The present research provides a clear picture of the photoionization and dissociation processes of cyclohexene in the 8- to 15.5-eV photon energy region. Copyright © 2016 John Wiley & Sons, Ltd.

Ion pair formation in the vacuum ultraviolet region of NO studied by negative ion imaging spectroscopy

International Nuclear Information System (INIS)

Hikosaka, Y.; Kaneyasu, T.; Shigemasa, E.

2007-01-01

The pair formation of positive and negative fragment ions has been studied in the vacuum ultraviolet region of NO, with negative ion imaging spectroscopy. The negative ion yield curve obtained in the photon energy region of 19-25 eV exhibits many structures which are absent from the photoabsorption spectrum in the same region. The partial yields and asymmetry parameters associated with the dissociations into individual ion pair limits have been extracted from the negative ion images observed. On the basis of these quantities, the assignments for the structures exhibited on the negative ion yield curve are given and the dynamical properties on the ion pair dissociation are discussed

Investigation of the noise effect on tomographic reconstructions for a tangentially viewing vacuum ultraviolet imaging diagnostic

International Nuclear Information System (INIS)

Ming, Tingfeng; Ohdachi, Satoshi; Suzuki, Yasuhiro

2011-01-01

Tomographic reconstruction for a tangentially viewing two-dimensional (2D) imaging system is studied. A method to calculate the geometry matrix in 2D tomography is introduced. An algorithm based on a Phillips-Tikhonov (P-T) type regularization method is investigated, and numerical tests using the P-T method are conducted with both tokamak and Heliotron configurations. The numerical tests show that the P-T method is not sensitive to the added noise levels and the emission profiles with higher mode numbers can be reconstructed with adequate resolution. The results indicate that this method is suitable for 2D tomographic reconstruction for a tangentially viewing vacuum ultraviolet telescope system. (author)

The electronic states of 1,2,4-triazoles: A study of 1H- and1-methyl-1,2,4-triazole by vacuum ultraviolet photoabsorption and ultraviolet photoelectron spectroscopy and a comparison with ab initio configuration interaction computations

DEFF Research Database (Denmark)

Palmer, Michael H.; Camp, Philip J.; Hoffmann, Søren Vrønning

2012-01-01

The first vacuum ultraviolet absorption spectrum of a 1,2,4-triazole has been obtained and analyzed in detail, with assistance from both an enhanced UV photoelectron spectroscopic study and ab initio multi-reference multi-root configuration interaction procedures. For both 1H- and 1-methyl-1,2...

The electronic states of 1,2,3-triazole studied by vacuum ultraviolet photoabsorption and ultraviolet photoelectron spectroscopy, and a comparison with ab initio configuration interaction methods

DEFF Research Database (Denmark)

Palmer, Michael H.; Hoffmann, Søren Vrønning; Jones, Nykola C.

2011-01-01

The Rydberg states in the vacuum ultraviolet photoabsorption spectrum of 1,2,3-triazole have been measured and analyzed with the aid of comparison to the UV valence photoelectron ionizations and the results of ab initio configuration interaction (CI) calculations. Calculated electronic ionization...... and excitation energies for singlet, triplet valence, and Rydberg states were obtained using multireference multiroot CI procedures with an aug-cc-pVTZ [5s3p3d1f] basis set and a set of Rydberg [4s3p3d3f] functions. Adiabatic excitation energies obtained for several electronic states using coupled...... are the excitations consistent with an f-series....

Microplasma discharge vacuum ultraviolet photoionization source for atmospheric pressure ionization mass spectrometry.

Science.gov (United States)

Symonds, Joshua M; Gann, Reuben N; Fernández, Facundo M; Orlando, Thomas M

2014-09-01

In this paper, we demonstrate the first use of an atmospheric pressure microplasma-based vacuum ultraviolet (VUV) photoionization source in atmospheric pressure mass spectrometry applications. The device is a robust, easy-to-operate microhollow cathode discharge (MHCD) that enables generation of VUV photons from Ne and Ne/H(2) gas mixtures. Photons were detected by excitation of a microchannel plate detector and by analysis of diagnostic sample ions using a mass spectrometer. Reactive ions, charged particles, and metastables produced in the discharge were blocked from entering the ionization region by means of a lithium fluoride window, and photoionization was performed in a nitrogen-purged environment. By reducing the output pressure of the MHCD, we observed heightened production of higher-energy photons, making the photoionization source more effective. The initial performance of the MHCD VUV source has been evaluated by ionizing model analytes such as acetone, azulene, benzene, dimethylaniline, and glycine, which were introduced in solid or liquid phase. These molecules represent species with both high and low proton affinities, and ionization energies ranging from 7.12 to 9.7 eV.

Gas chromatography-vacuum ultraviolet spectroscopy for analysis of fatty acid methyl esters.

Science.gov (United States)

Fan, Hui; Smuts, Jonathan; Bai, Ling; Walsh, Phillip; Armstrong, Daniel W; Schug, Kevin A

2016-03-01

A new vacuum ultraviolet (VUV) detector for gas chromatography was recently developed and applied to fatty acid methyl ester (FAME) analysis. VUV detection features full spectral acquisition in a wavelength range of 115-240nm, where virtually all chemical species absorb. VUV absorption spectra of 37 FAMEs, including saturated, monounsaturated, and polyunsaturated types were recorded. Unsaturated FAMEs show significantly different gas phase absorption profiles than saturated ones, and these classes can be easily distinguished with the VUV detector. Another advantage includes differentiating cis/trans-isomeric FAMEs (e.g. oleic acid methyl ester and linoleic acid methyl ester isomers) and the ability to use VUV data analysis software for deconvolution of co-eluting signals. As a universal detector, VUV also provides high specificity, sensitivity, and a fast data acquisition rate, making it a powerful tool for fatty acid screening when combined with gas chromatography. The fatty acid profile of several food oil samples (olive, canola, vegetable, corn, sunflower and peanut oils) were analyzed in this study to demonstrate applicability to real world samples. Copyright © 2015 Elsevier Ltd. All rights reserved.

Application of Laser Plasma Sources of Soft X-rays and Extreme Ultraviolet (EUV) in Imaging, Processing Materials and Photoionization Studies

Science.gov (United States)

Fiedorowicz, H.; Bartnik, A.; Wachulak, P. W.; Jarocki, R.; Kostecki, J.; Szczurek, M.; Ahad, I. U.; Fok, T.; Szczurek, A.; Wȩgrzyński, Ł.

In the paper we present new applications of laser plasma sources of soft X-rays and extreme ultraviolet (EUV) in various areas of plasma physics, nanotechnology and biomedical engineering. The sources are based on a gas puff target irradiated with nanosecond laser pulses from commercial Nd: YAG lasers, generating pulses with time duration from 1 to 10 ns and energies from 0.5 to 10 J at a 10 Hz repetition rate. The targets are produced with the use of a double valve system equipped with a special nozzle to form a double-stream gas puff target which allows for high conversion efficiency of laser energy into soft X-rays and EUV without degradation of the nozzle. The sources are equipped with various optical systems to collect soft X-ray and EUV radiation and form the radiation beam. New applications of these sources in imaging, including EUV tomography and soft X-ray microscopy, processing of materials and photoionization studies are presented.

Polarized vacuum ultraviolet and X-radiation

International Nuclear Information System (INIS)

Samson, J.A.R.

1978-01-01

The most intense source of polarized vacuum UV and X-radiation is synchrotron radiation, which exhibits a degree of partially polarized light between about 80-100%. However, the radiation transmitted by vacuum UV monochromators can also be highly polarized. The Seya-Namioka type of monochromator can produce partially polarized radiation between 50-80%. For certain experiments it is necessary to know the degree of polarisation of the radiation being used. Also, when synchrotron radiation and a monochromator are combined the polarization characteristic of both should be known in order to make full use of these polarization properties. The polarizing effect on monochromators (i.e. diffraction gratings) have been measured at the Seya angle and at grazing angles for various spectral orders. The author presents the first experimental evidence that the reciprocity law holds for polarization by reflection where the angle of incidence and diffraction are unequal. These results are reviewed along with the techniques for measuring the degree of polarization. (Auth.)

Ultraviolet Communication for Medical Applications

Science.gov (United States)

2015-06-01

DEI procured several UVC phosphors and tested them with vacuum UV (VUV) excitation. Available emission peaks include: 226 nm, 230 nm, 234 nm, 242...SUPPLEMENTARY NOTES Report contains color. 14. ABSTRACT Under this Phase II SBIR effort, Directed Energy Inc.’s (DEI) proprietary ultraviolet ( UV ...15. SUBJECT TERMS Non-line-of-sight (NLOS), networking, optical communication, plasma-shells, short range, ultraviolet ( UV ) light 16. SECURITY

Electronic structure, photoemission spectra, and vacuum-ultraviolet optical spectra of CsPbCl3 and CsPbBr3

Science.gov (United States)

Heidrich, K.; Schäfer, W.; Schreiber, M.; Söchtig, J.; Trendel, G.; Treusch, J.; Grandke, T.; Stolz, H. J.

1981-11-01

Optical spectra of CsPbCl3 and CsPbBr3 have been measured in the range from 2 to 10 eV and have been combined with ultraviolet-photoemission-spectroscopy (UPS)-measurements at 21.1 and 40.8 eV. A quantitative band calculation is presented, which takes into account anion-anion interaction as well as electronic states of the Cs+ ion. The prominent features of earlier band models and measurements are reestablished through our measurements and calculations, namely that the valence band consists of anionic p functions and Pb 6s functions, the lowest conduction band being Pb 6p type, and the lowest gap occuring at the R point of the Brillouin zone. Inclusion of a further (Cs 6s-type) conduction band, however, is necessary to bring the calculated joint density of states into agreement with vacuum-ultraviolet optical spectra. The calculated densities of states of the valence bands are in quantitative agreement with those deduced from our UPS measurements.

Phase space and jet definitions in soft-collinear effective theory

International Nuclear Information System (INIS)

Cheung, William Man-Yin; Luke, Michael; Zuberi, Saba

2009-01-01

We discuss consistent power counting for integrating soft and collinear degrees of freedom over arbitrary regions of phase space in the soft-collinear effective theory, and illustrate our results at one-loop with several jet algorithms: JADE, Sterman-Weinberg and k perpendicular . Consistently applying soft-collinear effective theory power counting in phase space, along with nontrivial zero-bin subtractions, prevents double counting of final states. The resulting phase space integrals over soft and collinear regions are individually ultraviolet divergent, but the phase space ultraviolet divergences cancel in the sum. Whether the soft and collinear contributions are individually infrared safe depends on the jet definition. We show that while this is true at one-loop for JADE and Sterman-Weinberg, the k perpendicular algorithm does not factorize into individually infrared safe soft and collinear pieces in dimensional regularization. We point out that this statement depends on the ultraviolet regulator, and that in a cutoff scheme the soft functions are infrared safe.

Quantification of isomerically summed hydrocarbon contributions to crude oil by carbon number, double bond equivalent, and aromaticity using gas chromatography with tunable vacuum ultraviolet ionization.

Science.gov (United States)

Nowak, Jeremy A; Weber, Robert J; Goldstein, Allen H

2018-03-12

The ability to structurally characterize and isomerically quantify crude oil hydrocarbons relevant to refined fuels such as motor oil, diesel, and gasoline represents an extreme challenge for chromatographic and mass spectrometric techniques. This work incorporates two-dimensional gas chromatography coupled to a tunable vacuum ultraviolet soft photoionization source, the Chemical Dynamics Beamline 9.0.2 of the Advanced Light Source at the Lawrence Berkeley National Laboratory, with a time-of-flight mass spectrometer (GC × GC-VUV-TOF) to directly characterize and isomerically sum the contributions of aromatic and aliphatic species to hydrocarbon classes of four crude oils. When the VUV beam is tuned to 10.5 ± 0.2 eV, both aromatic and aliphatic crude oil hydrocarbons are ionized to reveal the complete chemical abundance of C 9 -C 30 hydrocarbons. When the VUV beam is tuned to 9.0 ± 0.2 eV only aromatic hydrocarbons are ionized, allowing separation of the aliphatic and aromatic fractions of the crude oil hydrocarbon chemical classes in an efficient manner while maintaining isomeric quantification. This technique provides an effective tool to determine the isomerically summed aromatic and aliphatic hydrocarbon compositions of crude oil, providing information that goes beyond typical GC × GC separations of the most dominant hydrocarbon isomers.

Vacuum energy from noncommutative models

Science.gov (United States)

Mignemi, S.; Samsarov, A.

2018-04-01

The vacuum energy is computed for a scalar field in a noncommutative background in several models of noncommutative geometry. One may expect that the noncommutativity introduces a natural cutoff on the ultraviolet divergences of field theory. Our calculations show however that this depends on the particular model considered: in some cases the divergences are suppressed and the vacuum energy is only logarithmically divergent, in other cases they are stronger than in the commutative theory.

Optical luminescence from alkyl-passivated Si nanocrystals under vacuum ultraviolet excitation: Origin and temperature dependence of the blue and orange emissions

OpenAIRE

Chao, Y; Houlton, A; Horrocks, BR; Hunt, MRC; Poolton, NRJ; Yang, J; Šiller, L

2006-01-01

The origin and stability of luminescence are critical issues for Si nanocrystals which are intended for use as biological probes. The optical luminescence of alkyl-monolayer-passivated silicon nanocrystals was studied under excitation with vacuum ultraviolet photons (5.1–23 eV). Blue and orange emission bands were observed simultaneously, but the blue band only appeared at low temperatures (8.7 eV). At 8 K, the peak wavelengths of the emission bands were 430±2 nm (blue) and 600±2 nm (orange)....

Extreme ultraviolet (EUV) and FUV calibration facility for special sensor ultraviolet limb imager (SSULI)

Science.gov (United States)

Boyer, Craig N.; Osterman, Steven N.; Thonnard, Stefan E.; McCoy, Robert P.; Williams, J. Z.; Parker, S. E.

1994-09-01

A facility for calibrating far ultraviolet and extreme ultraviolet instruments has recently been completed at the Naval Research Laboratory. Our vacuum calibration vessel is 2-m in length, 1.67-m in diameter, and can accommodate optical test benches up to 1.2-m wide by 1.5-m in length. A kinematically positioned frame with four axis precision pointing capability of 10 microns for linear translation and .01 degrees for rotation is presently used during vacuum optical calibration of SSULI. The chamber was fabricated from 304 stainless steel and polished internally to reduce surface outgassing. A dust-free environment is maintained at the rear of the vacuum chamber by enclosing the 2-m hinged vacuum access door in an 8 ft. by 8 ft. class 100 clean room. Every effort was made to obtain an oil-free environment within the vacuum vessel. Outgassing products are continually monitored with a 1 - 200 amu residual gas analyzer. An oil-free claw and vane pump evacuates the chamber to 10-2 torr through 4 in. diameter stainless steel roughing lines. High vacuum is achieved and maintained with a magnetically levitated 480 l/s turbo pump and a 3000 l/s He4 cryopump. Either of two vacuum monochrometers, a 1-m f/10.4 or a 0.2-m f/4.5 are coaxially aligned with the optical axis of the chamber and are used to select single UV atomic resonance lines from a windowless capillary or penning discharge UV light source. A calibrated channeltron detector is coaxially mounted with the SSULI detector during calibration. All vacuum valves, the cooling system for the cryopump compressor, and the roughing pump are controlled through optical fibers which are interfaced to a computer through a VME board. Optical fibers were chosen to ensure that complete electrical isolation is maintained between the computer and the vacuum system valves-solenoids and relays.

Vacuum ultraviolet photolysis of diclofenac and the effects of its treated aqueous solutions on the proliferation and migratory responses of Tetrahymena pyriformis

International Nuclear Information System (INIS)

Arany, Eszter; Láng, Júlia; Somogyvári, Dávid; Láng, Orsolya; Alapi, Tünde; Ilisz, István

2014-01-01

The effects of dissolved O 2 , phosphate buffer and the initial concentration of diclofenac on the vacuum ultraviolet photolysis of this contaminant molecule were studied. Besides kinetic measurements, the irradiated, multicomponent samples were characterized via the proliferation and migratory responses (in sublethal concentrations) of the bioindicator eukaryotic ciliate Tetrahymena pyriformis. The results suggest that hydroxyl radicals, hydrogen atoms and hydroperoxyl radicals may all contribute to the degradation of diclofenac. The aromatic by-products of diclofenac were presumed to include a hydroxylated derivative, 1-(8-chlorocarbazolyl)acetic acid and 1-(8-hydroxycarbazolyl)acetic acid. The biological activity of photoexposed samples reflected the chemical transformation of diclofenac and was also dependent on the level of dissolved O 2 . The increase in toxicity of samples taken after different irradiation times did not exceed a factor of two. Our results suggest that the combination of vacuum ultraviolet photolysis with toxicity and chemotactic measurements can be a valuable method for the investigation of the elimination of micropollutants. - Highlights: • The radical-scavenging effect of phosphates seems to be negligible. • Only higher concentrations of HO 2 · contribute to the degradation of diclofenac. • Toxicity of VUV-treated samples decreases with increasing rate of mineralization. • Dissolved O 2 enhances the mineralization of diclofenac by affecting the radical set. • Treated samples retain the chemorepellent character of the parent compound

Vacuum ultraviolet photolysis of diclofenac and the effects of its treated aqueous solutions on the proliferation and migratory responses of Tetrahymena pyriformis

Energy Technology Data Exchange (ETDEWEB)

Arany, Eszter [Research Group of Environmental Chemistry, Institute of Chemistry, University of Szeged, H-6720 Szeged, Rerrich Béla tér 1 (Hungary); Láng, Júlia [Department of Genetics, Cell- and Immunobiology, Semmelweis University, H-1089 Budapest, Nagyvárad tér 4 (Hungary); Somogyvári, Dávid [Research Group of Environmental Chemistry, Institute of Chemistry, University of Szeged, H-6720 Szeged, Rerrich Béla tér 1 (Hungary); Láng, Orsolya [Department of Genetics, Cell- and Immunobiology, Semmelweis University, H-1089 Budapest, Nagyvárad tér 4 (Hungary); Alapi, Tünde [Research Group of Environmental Chemistry, Institute of Chemistry, University of Szeged, H-6720 Szeged, Rerrich Béla tér 1 (Hungary); Department of Inorganic and Analytical Chemistry, University of Szeged, H-6720 Szeged, Dóm tér 7 (Hungary); Ilisz, István [Department of Inorganic and Analytical Chemistry, University of Szeged, H-6720 Szeged, Dóm tér 7 (Hungary); and others

2014-01-01

The effects of dissolved O{sub 2}, phosphate buffer and the initial concentration of diclofenac on the vacuum ultraviolet photolysis of this contaminant molecule were studied. Besides kinetic measurements, the irradiated, multicomponent samples were characterized via the proliferation and migratory responses (in sublethal concentrations) of the bioindicator eukaryotic ciliate Tetrahymena pyriformis. The results suggest that hydroxyl radicals, hydrogen atoms and hydroperoxyl radicals may all contribute to the degradation of diclofenac. The aromatic by-products of diclofenac were presumed to include a hydroxylated derivative, 1-(8-chlorocarbazolyl)acetic acid and 1-(8-hydroxycarbazolyl)acetic acid. The biological activity of photoexposed samples reflected the chemical transformation of diclofenac and was also dependent on the level of dissolved O{sub 2}. The increase in toxicity of samples taken after different irradiation times did not exceed a factor of two. Our results suggest that the combination of vacuum ultraviolet photolysis with toxicity and chemotactic measurements can be a valuable method for the investigation of the elimination of micropollutants. - Highlights: • The radical-scavenging effect of phosphates seems to be negligible. • Only higher concentrations of HO{sub 2}{sup ·} contribute to the degradation of diclofenac. • Toxicity of VUV-treated samples decreases with increasing rate of mineralization. • Dissolved O{sub 2} enhances the mineralization of diclofenac by affecting the radical set. • Treated samples retain the chemorepellent character of the parent compound.

Impact of plasma jet vacuum ultraviolet radiation on reactive oxygen species generation in bio-relevant liquids

Energy Technology Data Exchange (ETDEWEB)

Jablonowski, H.; Hammer, M. U.; Reuter, S. [Center for Innovation Competence plasmatis, Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany); Leibniz Institute for Plasma Science and Technology, INP Greifswald e.V. Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany); Bussiahn, R.; Weltmann, K.-D.; Woedtke, Th. von [Leibniz Institute for Plasma Science and Technology, INP Greifswald e.V. Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany)

2015-12-15

Plasma medicine utilizes the combined interaction of plasma produced reactive components. These are reactive atoms, molecules, ions, metastable species, and radiation. Here, ultraviolet (UV, 100–400 nm) and, in particular, vacuum ultraviolet (VUV, 10–200 nm) radiation generated by an atmospheric pressure argon plasma jet were investigated regarding plasma emission, absorption in a humidified atmosphere and in solutions relevant for plasma medicine. The energy absorption was obtained for simple solutions like distilled water (dH{sub 2}O) or ultrapure water and sodium chloride (NaCl) solution as well as for more complex ones, for example, Rosewell Park Memorial Institute (RPMI 1640) cell culture media. As moderate stable reactive oxygen species, hydrogen peroxide (H{sub 2}O{sub 2}) was studied. Highly reactive oxygen radicals, namely, superoxide anion (O{sub 2}{sup •−}) and hydroxyl radicals ({sup •}OH), were investigated by the use of electron paramagnetic resonance spectroscopy. All species amounts were detected for three different treatment cases: Plasma jet generated VUV and UV radiation, plasma jet generated UV radiation without VUV part, and complete plasma jet including all reactive components additionally to VUV and UV radiation. It was found that a considerable amount of radicals are generated by the plasma generated photoemission. From the experiments, estimation on the low hazard potential of plasma generated VUV radiation is discussed.

Vacuum ultraviolet photochemistry of polymers

International Nuclear Information System (INIS)

Skurat, Vladimir

2003-01-01

The interaction of vacuum UV radiation (wavelength range from 1 to 200 nm) with polymers is interesting for fundamental and applied sciences. This interest is stimulated by various reasons: - Wide applications of polymeric materials in semiconductor technology, where they are used as photoresist materials in combination with VUV light sources (lasers, excimer lamps, synchrotron radiation and others). - Polymers are widely used as spacecraft materials in the last 20 years. On near-Earth orbits, the polymeric materials of spacecraft surfaces are destroyed by solar radiation. - VUV radiation is one of the components of gas discharge plasmas, which are used for treatment of polymer, with the aim of modifying their surface properties. The main features of interaction of VUV radiation with polymers are discussed. The spectra of intrinsic absorption of saturated polymers (polyethylene, polypropylene, polytetrafluoroethylene and others) are situated mainly in the VUV region. The photochemistry of polymers in the VUV region is very different from their photochemistry at wavelengths longer than 200 nm, where the absorption spectra belong to impurities and polymer defects. The polymer photochemistry in the VUV region is wavelength-dependent. At wavelengths longer than about 140 nm, the main role is played by transformations of primary-formed singlet excited molecules. At shorter wavelengths the role of photoionization increases progressively and the main features of VUV photolysis become similar to the picture of radiolysis, with significant contributions of charge pairs and triplet excited molecules. Very important features of VUV light absorption in polymers are high absorption coefficients. Because of this, the surface layers absorb large doses of energy. This leads to very profound transformation of material on the polymer surface. In particular for polymers which are considered destroyed by radiation (for example, perfluoropolymers), this leads to VUV-induced erosion

High-resolution vacuum-ultraviolet photoabsorption spectra of 1-butyne and 2-butyne

Energy Technology Data Exchange (ETDEWEB)

Jacovella, U. [Laboratorium für Physikalische Chemie, ETH Zürich, 8093 Zürich (Switzerland); Holland, D. M. P. [STFC, Daresbury Laboratory, Daresbury, Warrington, Cheshire WA4 4AD (United Kingdom); Boyé-Péronne, S.; Gans, B. [Institut des Sciences Moléculaires d’Orsay, UMR 8214, CNRS and Université Paris-Sud, F-91405 Orsay (France); Oliveira, N. de; Joyeux, D.; Archer, L. E. [Synchrotron Soleil, L’Orme des Merisiers, F-91192 Gif-sur-Yvette (France); Lucchese, R. R. [Department of Chemistry, Texas A& M University, College Station, Texas 77843 (United States); Xu, H.; Pratt, S. T. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)

2015-07-21

The absolute photoabsorption cross sections of 1- and 2-butyne have been recorded at high resolution by using the vacuum-ultraviolet Fourier-Transform spectrometer at the SOLEIL Synchrotron. Both spectra show more resolved structure than previously observed, especially in the case of 2-butyne. In this work, we assess the potential importance of Rydberg states with higher values of orbital angular momentum, l, than are typically observed in photoabsorption experiments from ground state molecules. We show how the character of the highest occupied molecular orbitals in 1- and 2-butyne suggests the potential importance of transitions to such high-l (l = 3 and 4) Rydberg states. Furthermore, we use theoretical calculations of the partial wave composition of the absorption cross section just above the ionization threshold and the principle of continuity of oscillator strength through an ionization threshold to support this conclusion. The new absolute photoabsorption cross sections are discussed in light of these arguments, and the results are consistent with the expectations. This type of argument should be valuable for assessing the potential importance of different Rydberg series when sufficiently accurate direct quantum chemical calculations are difficult, for example, in the n ≥ 5 manifolds of excited states of larger molecules.

Preparation of red phosphor (Y, Gd)BO3:Eu by soft chemistry methods

International Nuclear Information System (INIS)

Cui Xiangzhong; Zhuang Weidong; Yu Zhijian; Xia Tian; Huang Xiaowei; Li Hongwei

2008-01-01

The three soft chemistry methods were employed to prepare the red phosphor (Y, Gd)BO 3 :Eu, such as coprecipitation-combustion method, salt assisted combustion method and emulsion method. The main factors affecting particle size, particle distribution and luminescent properties of the product were investigated in detail, and as a result, the preparation processes were optimized. The phosphors were characterized by X-ray diffraction (XRD), scanning electronic microscope (SEM), transmission electronic microscope (TEM) and vacuum ultraviolet (VUV) spectra. Results reveal that phosphors with different morphology, small particle size and high luminescence intensity could be obtained by soft chemistry methods. The difference between the luminescence properties of phosphors in this work and commercial rare earth borate phosphor is discussed. The phosphor with grain shape and high luminescence intensity could be prepared by coprecipitation-combustion method, nanophosphor could be prepared by salt assisted combustion method, and spherical phosphor with a narrow size distribution could be obtained by using emulsion method

Ejecta Particle-Size Measurements in Vacuum and Helium Gas using Ultraviolet In-Line Fraunhofer Holography

Energy Technology Data Exchange (ETDEWEB)

Sorenson, Danny S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Pazuchanics, Peter [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Johnson, Randall P. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Malone, R. M. [National Security Technologies, LLC. (NSTec), Los Alamos, NM (United States); Kaufman, M. I. [National Security Technologies, LLC. (NSTec), Los Alamos, NM (United States); Tibbitts, A. [National Security Technologies, LLC. (NSTec), Los Alamos, NM (United States); Tunnell, T. [National Security Technologies, LLC. (NSTec), Los Alamos, NM (United States); Marks, D. [National Security Technologies, LLC. (NSTec), Los Alamos, NM (United States); Capelle, G. A. [National Security Technologies, LLC. (NSTec), Santa Barbara, CA (United States); Grover, M. [National Security Technologies, LLC. (NSTec), Santa Barbara, CA (United States); Marshall, B. [National Security Technologies, LLC. (NSTec), Santa Barbara, CA (United States); Stevens, G. D. [National Security Technologies, LLC. (NSTec), Santa Barbara, CA (United States); Turley, W. D. [National Security Technologies, LLC. (NSTec), Santa Barbara, CA (United States); LaLone, B. [National Security Technologies, LLC. (NSTec), Santa Barbara, CA (United States)

2014-06-25

An Ultraviolet (UV) in-line Fraunhofer holography diagnostic has been developed for making high-resolution spatial measurements of ejecta particles traveling at many mm/μsec. This report will discuss the development of the diagnostic including the high-powered laser system and high-resolution optical relay system. In addition, the system required to reconstruct the images from the hologram and the corresponding analysis of those images to extract particles will also be described. Finally, results from six high-explosive (HE), shock-driven Sn ejecta experiments will be presented. Particle size distributions will be shown that cover most of the ejecta velocities for experiments conducted in a vacuum, and helium gas environments. In addition, a modification has been made to the laser system that produces two laser pulses separated by 6.8 ns. This double-pulsed capability allows a superposition of two holograms to be acquired at two different times, thus allowing ejecta velocities to be measured directly. Results from this double pulsed experiment will be described.

Determination of ionization energies of small silicon clusters with vacuum?ultraviolet (VUV) radiation

Energy Technology Data Exchange (ETDEWEB)

Kostko, Oleg; Leone, Stephen R.; Duncan, Michael A.; Ahmed, Musahid

2009-09-23

In this work we report on single photon vacuum ultraviolet photoionization of small silicon clusters (n=1-7) produced via laser ablation of Si. The adiabatic ionization energies (AIE) are extracted from experimental photoionization efficiency (PIE) curves with the help of Frank?Condon simulations, used to interpret the shape and onset of the PIE curves. The obtained AIEs are (all energies are in eV): Si (8.13+-0.05), Si2 (7.92+-0.05), Si3 (8.12+-0.05), Si4 (8.2+-0.1), Si5 (7.96+-0.07), Si6 (7.8+-0.1), and Si7 (7.8+-0.1). Most of the experimental AIE values are in good agreement with ab initio electronic structure calculations. To explain observed deviations between the experimental and theoretical AIEs for Si4 and Si6, a theoretical search of different isomers of these species is performed. Electronic structure calculations aid in the interpretation of the a2PIu state of Si2+ dimer in the PIE spectrum. Time dependent density functional theory (TD-DFT) calculations are performed to reveal the energies of electronically excited states in the cations for a number of Si clusters.

Electroweak vacuum instability and renormalized Higgs field vacuum fluctuations in the inflationary universe

Energy Technology Data Exchange (ETDEWEB)

Kohri, Kazunori [Institute of Particle and Nuclear Studies, KEK, 1-1 Oho, Tsukuba 305-0801 (Japan); Matsui, Hiroki, E-mail: kohri@post.kek.jp, E-mail: matshiro@post.kek.jp [The Graduate University for Advanced Studies (SOKENDAI), 1-1 Oho, Tsukuba 305-0801 (Japan)

2017-08-01

In this work, we investigated the electroweak vacuum instability during or after inflation. In the inflationary Universe, i.e., de Sitter space, the vacuum field fluctuations < δ φ {sup 2} > enlarge in proportion to the Hubble scale H {sup 2}. Therefore, the large inflationary vacuum fluctuations of the Higgs field < δ φ {sup 2} > are potentially catastrophic to trigger the vacuum transition to the negative-energy Planck-scale vacuum state and cause an immediate collapse of the Universe. However, the vacuum field fluctuations < δ φ {sup 2} >, i.e., the vacuum expectation values have an ultraviolet divergence, and therefore a renormalization is necessary to estimate the physical effects of the vacuum transition. Thus, in this paper, we revisit the electroweak vacuum instability from the perspective of quantum field theory (QFT) in curved space-time, and discuss the dynamical behavior of the homogeneous Higgs field φ determined by the effective potential V {sub eff}( φ ) in curved space-time and the renormalized vacuum fluctuations < δ φ {sup 2} >{sub ren} via adiabatic regularization and point-splitting regularization. We simply suppose that the Higgs field only couples the gravity via the non-minimal Higgs-gravity coupling ξ(μ). In this scenario, the electroweak vacuum stability is inevitably threatened by the dynamical behavior of the homogeneous Higgs field φ, or the formations of AdS domains or bubbles unless the Hubble scale is small enough H < Λ {sub I} .

Identification and deconvolution of carbohydrates with gas chromatography-vacuum ultraviolet spectroscopy.

Science.gov (United States)

Schenk, Jamie; Nagy, Gabe; Pohl, Nicola L B; Leghissa, Allegra; Smuts, Jonathan; Schug, Kevin A

2017-09-01

Methodology for qualitative and quantitative determination of carbohydrates with gas chromatography coupled to vacuum ultraviolet detection (GC-VUV) is presented. Saccharides have been intently studied and are commonly analyzed by gas chromatography-mass spectrometry (GC-MS), but not always effectively. This can be attributed to their high degree of structural complexity: α/β anomers from their axial/equatorial hydroxyl group positioning at the C1-OH and flexible ring structures that lead to the open chain, five-membered ring furanose, and six-membered ring pyranose configurations. This complexity can result in convoluted chromatograms, ambiguous fragmentation patterns and, ultimately, analyte misidentification. In this study, mono-, di, and tri-saccharides were derivatized by two different methods-permethylation and oximation/pertrimethylsilylation-and analyzed by GC-VUV. These two derivatization methods were then compared for their efficiency, ease of use, and robustness. Permethylation proved to be a useful technique for the analysis of ketopentoses and pharmaceuticals soluble in dimethyl sulfoxide (DMSO), while the oximation/pertrimethylsilylation method prevailed as the more promising, overall, derivatization method. VUV spectra have been shown to be distinct and allow for efficient differentiation of isomeric species such as ketopentoses and reducing versus non-reducing sugars. In addition to identification, pharmaceutical samples containing several compounds were derivatized and analyzed for their sugar content with the GC-VUV technique to provide data for qualitative analysis. Copyright © 2017 Elsevier B.V. All rights reserved.

Validation of the uncertainty budget for soft X-ray radiant power measurement using a cryogenic radiometer

International Nuclear Information System (INIS)

Rabus, H.; Klein, R.; Scholze, F.; Thornagel, R.; Ulm, G.

2002-01-01

The cryogenic radiometer SYRES, a thermal detector based on the electrical substitution principle, has been used as the primary detector standard for radiant power measurement in the ultraviolet, vacuum ultraviolet and soft X-ray spectral ranges. In order to investigate the possibility of radiant energy being deposited in its absorber cavity without being transformed into heat when detecting soft X-rays, SYRES has been directly compared with the electron storage ring BESSY 1, a primary radiometric source standard of calculable spectral radiant power. To this end, the integral radiant power emitted by the storage ring,into a solid angle defined by a high-precision aperture was measured with SYRES. The experiments were conducted at two nominal energies of the circulating electrons, 800 MeV and 340 MeV, to study the influence of the different spectral distributions of the synchrotron radiation. For the original graphite-coated cavity absorber, significant discrepancies were found which could be traced back to the ablation of the graphite coating from the copper cavity body. In the case of the new gold-coated cavity absorber, the calculated and measured values of the radiant power agreed in all experiments within the combined relative uncertainties of typically 2.5 x 10 -3 (k = 1). (author)

Biological applications of ultraviolet free-electron lasers

International Nuclear Information System (INIS)

Sutherland, J.C.

1997-10-01

This review examines the possibilities for biological research using the three ultraviolet free-electron lasers that are nearing operational status in the US. The projected operating characteristics of major interest in biological research of the free-electron lasers at Brookhaven National Laboratory, the Thomas Jefferson National Accelerator Facility, and Duke University are presented. Experimental applications in the areas of far- and vacuum ultraviolet photophysics and photochemistry, structural biology, environmental photobiology, and medical research are discussed and the prospects for advances in these areas, based upon the characteristics of the new ultraviolet free-electron lasers, are evaluated

Two-color photoionization and photoelectron studies by combining infrared and vacuum ultraviolet

International Nuclear Information System (INIS)

Ng, C.Y.

2005-01-01

Recent developments of two-color infrared (IR)-vacuum ultraviolet (VUV) and VUV-IR photoionization and photoelectron detection schemes for spectroscopic studies are described. By preparing molecules in selected rovibrational states by IR excitation prior to VUV-photoionization, state-selected and state-to-state photoionization cross sections can be obtained by IR-VUV-photoionization efficiency (IR-VUV-PIE) and IR-VUV-pulsed field ionization-photoelectron (IR-VUV-PFI-PE) measurements, respectively. Rotationally resolved autoionizing Rydberg states converging to excited ionic states, which cannot be observed by single-photon VUV-PIE measurements, can be examined by the IR-VUV-PIE scheme. By monitoring the photoion and the PFI-PE intensities at a fixed VUV energy as a function of IR frequency, the respective IR photoion and IR absorption spectra of the corresponding neutral molecule can be measured. Two-color VUV-IR photo-induced Rydberg ionization (PIRI) experiment, in which high-n Rydberg states are prepared by VUV-photoexcitation followed by IR-induced autoionization, has also been demonstrated. Since the IR-VUV-PIE, IR-VUV-PFI-PE, and VUV-IR-PIRI methods do not require the existence of a bound intermediate electronic state in the UV and are generally applicable to all molecules, the development of these two-color photoionization and photoelectron schemes is expected to significantly enhance the scope of VUV spectroscopy and chemistry

Use of the vacuum ultraviolet spectral region for laser-induced breakdown spectroscopy-based Martian geology and exploration

International Nuclear Information System (INIS)

Radziemski, Leon; Cremers, David A.; Benelli, Katharine; Khoo, Cynthia; Harris, Ronny D.

2005-01-01

Several elements important to planetary geology (e.g. Br, C, Cl, P, S) and the human exploration of Mars (e.g. toxic elements such as As) have strong emission lines in the purge and vacuum ultraviolet (VUV) spectral region (100-200 nm). This spectral region has not been extensively studied for space applications using geological samples. We studied emissions from the laser-induced breakdown spectroscopy (LIBS) plasma in this region using a sample chamber filled with 7 torr (930 Pa) of CO 2 to simulate the Martian atmosphere. Pressures down to 0.02 torr were also used to evaluate the effect of the residual CO 2 on the spectra and to begin investigating the use of VUV-LIBS for airless bodies such as asteroids and the Moon. Spectra were recorded using a 0.3-m vacuum spectrometer with an intensified CCD (ICCD) camera. The effects of time delay and laser energy on LIBS detection at reduced pressure were examined. The effect of ambient CO 2 on the detection of C in soil was also evaluated. Lines useful for the spectrochemical analysis of As, Br, C, Cl, P, and S were determined and calibration curves were prepared for these elements. Although LIBS is being developed for stand-off analysis at many meters distance, the experiments reported here were aimed at in-situ (close-up) analysis

Sodium-doping as a reference to study the influence of intracluster chemistry on the fragmentation of weakly-bound clusters upon vacuum ultraviolet photoionization

OpenAIRE

Litman Jessica H; Yoder Bruce L; Schläppi Bernhard; Signorell Ruth

2012-01-01

The fragmentation of methanol water dimethyl ether and acetic acid clusters upon photoionization with a single vacuum ultraviolet (VUV) photon of 10.1 eV 13.3 eV or 17.5 eV energy is studied with mass spectrometry. The sodium doping method is used as an independent approximate measure of the original cluster size distribution providing information on the degree of fragmentation upon VUV ionization. The experimental results show strong fragmentation for (CH3)2O and CH3CO2H clusters but minor f...

Vacuum ultraviolet excited photoluminescence properties of Gd2O2CO3:Eu3+ phosphor

Institute of Scientific and Technical Information of China (English)

WANG Zhilong; WANG Yuhua; ZHANG Jiachi

2008-01-01

The Gd2O2CO3:Eu3+ with type-II structure phosphor was successfully synthesized via flux method at 400℃ and their photoluminescence properties in vacuum ultraviolet (VUV) region were examined. The broad and strong excitation bands in the range of 153-205 nm owing to the CO32- host absorption and charge transfer (CT) of Gd3+-O2- were observed for Gd2O2CO3:Eu3+. Under 172 nm excitation, Gd2O2CO3:Eu3+ exhibited strong red emission with good color purity, indicating Eu3+ ions located at low symmetry sites and the chromaticity coordination of luminescence for Gd2O2CO3:Eu3+ was (x=0.652, y=0.345). The photoluminescence quenching concentration of Eu3+ excited by 172 nm for Gd2O2CO3:Eu3+ was about 5%. Gd2O2CO3:Eu3+ would be a potential VUV-excited red phosphor applied in mercury-free fluorescent lamps.

Internal Energies of Ion-Sputtered Neutral Tryptophan and Thymine Molecules Determined by Vacuum Ultraviolet Photoionization

Energy Technology Data Exchange (ETDEWEB)

Zhou, Jia; Takahashi, Lynelle; Wilson, Kevin R.; Leone, Stephen R.; Ahmed, Musahid

2010-03-11

Vacuum ultraviolet photoionization coupled to secondary neutral mass spectrometry (VUV-SNMS) of deposited tryptophan and thymine films are performed at the Chemical Dynamics Beamline. The resulting mass spectra show that while the intensity of the VUV-SNMS signal is lower than the corresponding secondary ion mass spectroscopy (SIMS) signal, the mass spectra are significantly simplified in VUV-SNMS. A detailed examination of tryptophan and thymine neutral molecules sputtered by 25 keV Bi3 + indicates that the ion-sputtered parent molecules have ~;;2.5 eV of internal energy. While this internal energy shifts the appearance energy of the photofragment ions for both tryptophan and thymine, it does not change the characteristic photoionizaton efficiency (PIE) curves of thymine versus photon energy. Further analysis of the mass spectral signals indicate that approximately 80 neutral thymine molecules and 400 tryptophan molecules are sputtered per incident Bi3 + ion. The simplified mass spectra and significant characteristic ion contributions to the VUV-SNMS spectra indicate the potential power of the technique for organic molecule surface analysis.

A new endstation at the Swiss Light Source for ultraviolet photoelectron spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy measurements of liquid solutions

International Nuclear Information System (INIS)

Brown, Matthew A.; Redondo, Amaia Beloqui; Duyckaerts, Nicolas; Mächler, Jean-Pierre; Jordan, Inga; Wörner, Hans Jakob; Lee, Ming-Tao; Ammann, Markus; Nolting, Frithjof; Kleibert, Armin; Huthwelker, Thomas; Birrer, Mario; Honegger, Juri; Wetter, Reto; Bokhoven, Jeroen A. van

2013-01-01

A new liquid microjet endstation designed for ultraviolet (UPS) and X-ray (XPS) photoelectron, and partial electron yield X-ray absorption (XAS) spectroscopies at the Swiss Light Source is presented. The new endstation, which is based on a Scienta HiPP-2 R4000 electron spectrometer, is the first liquid microjet endstation capable of operating in vacuum and in ambient pressures up to the equilibrium vapor pressure of liquid water at room temperature. In addition, the Scienta HiPP-2 R4000 energy analyzer of this new endstation allows for XPS measurements up to 7000 eV electron kinetic energy that will enable electronic structure measurements of bulk solutions and buried interfaces from liquid microjet samples. The endstation is designed to operate at the soft X-ray SIM beamline and at the tender X-ray Phoenix beamline. The endstation can also be operated using a Scienta 5 K ultraviolet helium lamp for dedicated UPS measurements at the vapor-liquid interface using either He I or He II α lines. The design concept, first results from UPS, soft X-ray XPS, and partial electron yield XAS measurements, and an outlook to the potential of this endstation are presented

A new endstation at the Swiss Light Source for ultraviolet photoelectron spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy measurements of liquid solutions.

Science.gov (United States)

Brown, Matthew A; Redondo, Amaia Beloqui; Jordan, Inga; Duyckaerts, Nicolas; Lee, Ming-Tao; Ammann, Markus; Nolting, Frithjof; Kleibert, Armin; Huthwelker, Thomas; Müächler, Jean-Pierre; Birrer, Mario; Honegger, Juri; Wetter, Reto; Wörner, Hans Jakob; van Bokhoven, Jeroen A

2013-07-01

A new liquid microjet endstation designed for ultraviolet (UPS) and X-ray (XPS) photoelectron, and partial electron yield X-ray absorption (XAS) spectroscopies at the Swiss Light Source is presented. The new endstation, which is based on a Scienta HiPP-2 R4000 electron spectrometer, is the first liquid microjet endstation capable of operating in vacuum and in ambient pressures up to the equilibrium vapor pressure of liquid water at room temperature. In addition, the Scienta HiPP-2 R4000 energy analyzer of this new endstation allows for XPS measurements up to 7000 eV electron kinetic energy that will enable electronic structure measurements of bulk solutions and buried interfaces from liquid microjet samples. The endstation is designed to operate at the soft X-ray SIM beamline and at the tender X-ray Phoenix beamline. The endstation can also be operated using a Scienta 5 K ultraviolet helium lamp for dedicated UPS measurements at the vapor-liquid interface using either He I or He II α lines. The design concept, first results from UPS, soft X-ray XPS, and partial electron yield XAS measurements, and an outlook to the potential of this endstation are presented.

A new endstation at the Swiss Light Source for ultraviolet photoelectron spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy measurements of liquid solutions

Energy Technology Data Exchange (ETDEWEB)

Brown, Matthew A.; Redondo, Amaia Beloqui; Duyckaerts, Nicolas; Mächler, Jean-Pierre [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland); Jordan, Inga; Wörner, Hans Jakob [Laboratory of Physical Chemistry, ETH Zürich, CH-8093 Zürich (Switzerland); Lee, Ming-Tao; Ammann, Markus; Nolting, Frithjof; Kleibert, Armin; Huthwelker, Thomas; Birrer, Mario; Honegger, Juri; Wetter, Reto [Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland); Bokhoven, Jeroen A. van [Institute for Chemical and Bioengineering, ETH Zürich, CH-8093 Zürich (Switzerland); Paul Scherrer Institute, CH-5232 Villigen PSI (Switzerland)

2013-07-15

A new liquid microjet endstation designed for ultraviolet (UPS) and X-ray (XPS) photoelectron, and partial electron yield X-ray absorption (XAS) spectroscopies at the Swiss Light Source is presented. The new endstation, which is based on a Scienta HiPP-2 R4000 electron spectrometer, is the first liquid microjet endstation capable of operating in vacuum and in ambient pressures up to the equilibrium vapor pressure of liquid water at room temperature. In addition, the Scienta HiPP-2 R4000 energy analyzer of this new endstation allows for XPS measurements up to 7000 eV electron kinetic energy that will enable electronic structure measurements of bulk solutions and buried interfaces from liquid microjet samples. The endstation is designed to operate at the soft X-ray SIM beamline and at the tender X-ray Phoenix beamline. The endstation can also be operated using a Scienta 5 K ultraviolet helium lamp for dedicated UPS measurements at the vapor-liquid interface using either He I or He II α lines. The design concept, first results from UPS, soft X-ray XPS, and partial electron yield XAS measurements, and an outlook to the potential of this endstation are presented.

Characteristics of soft x-ray and extreme ultraviolet (XUV) emission from laser-produced highly charged rhodium ions

Science.gov (United States)

Barte, Ellie Floyd; Hara, Hiroyuki; Tamura, Toshiki; Gisuji, Takuya; Chen, When-Bo; Lokasani, Ragava; Hatano, Tadashi; Ejima, Takeo; Jiang, Weihua; Suzuki, Chihiro; Li, Bowen; Dunne, Padraig; O'Sullivan, Gerry; Sasaki, Akira; Higashiguchi, Takeshi; Limpouch, Jiří

2018-05-01

We have characterized the soft x-ray and extreme ultraviolet (XUV) emission of rhodium (Rh) plasmas produced using dual pulse irradiation by 150-ps or 6-ns pre-pulses, followed by a 150-ps main pulse. We have studied the emission enhancement dependence on the inter-pulse time separation and found it to be very significant for time separations less than 10 ns between the two laser pulses when using 6-ns pre-pulses. The behavior using a 150-ps pre-pulse was consistent with such plasmas displaying only weak self-absorption effects in the expanding plasma. The results demonstrate the advantage of using dual pulse irradiation to produce the brighter plasmas required for XUV applications.

Internal motion in high vacuum systems

Science.gov (United States)

Frank, J. M.

Three transfer and positioning mechanisms have been developed for the non-air exposed, multistep processing of components in vacuum chambers. The functions to be performed in all of the systems include ultraviolet/ozone cleaning, vacuum baking, deposition of thin films, and thermocompression sealing of the enclosures. Precise positioning of the components is required during the evaporation and sealing processes. The three methods of transporting and positioning the components were developed to accommodate the design criteria and goals of each individual system. The design philosophy, goals, and operation of the three mechanisms are discussed.

Generation of coherent radiation in vacuum ultra-violet by tripling frequency in continuous supersonic nitrogen free jet: quantitative investigation of resonance phenomena

International Nuclear Information System (INIS)

Faucher, Olivier

1991-01-01

This research thesis reports experimental studies performed on the generation of a coherent radiation in vacuum ultraviolet (94 nm) by tripling the frequency of an ultraviolet laser focussed within a continuous supersonic free nitrogen jet. After a recall of some general issues related to non-linear optics, the evolution of the non-linear susceptibility and conditions of phase adaptation in supersonic jet have been determined. This allowed a quantitative study of the third harmonic generation for the three following types of conversion: without resonance, with resonance with two photons, and with resonance with three photons. In the first two cases, due to the absence of saturation phenomena, measuring the harmonic signal intensity allows a diagnosis of the non-linear medium internal state to the performed. As far as the third harmonic generation with resonance with three photons is concerned, the use of supersonic free jet properties leads to a perfect understanding of saturation effects by self-absorption which are at the origin of the unusual character of the obtained spectra [fr

Gas phase radiolysis and vacuum ultraviolet photolysis of heterocyclic organic compounds. Progress report, February 1, 1974--February 1, 1975

International Nuclear Information System (INIS)

Scala, A.A.; Salomon, D.; Colon, I.; D'Angona, J.

1975-01-01

In the γ radiolysis of tetrahydrofuran there are pronounced density effects in the pressure range from 0 to 50 Torr with the most important ion-pair yields decreasing as the pressure increases. The relative product yields of the radiolysis is compared with that of xenon photolysis. Possible mechanisms to explain the results obtained are discussed. The ion-pair yields from the γ radiolysis of the heterocyclic amines, ethylenimine, azetidine, pyrrolidine, and piperidine, are determined, and the pressure effects are evaluated. Reactions mechanisms are discussed. The vacuum ultraviolet photolysis products of thietane and tetrahydrothiophene are studied and compared with the γ radiolysis products. Reaction mechanisms are discussed. The status of the construction of a photoionization mass spectrometer and the measurement of the ionization efficiencies and extinction coefficients of organic compounds is reported. (U.S.)

Effects of vacuum-ultraviolet irradiation on copper penetration into low-k dielectrics under bias-temperature stress

Energy Technology Data Exchange (ETDEWEB)

Guo, X.; Zheng, H.; Xue, P.; Shohet, J. L. [Plasma Processing and Technology Laboratory and Department of Electrical and Computer Engineering, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); King, S. W. [Logic Technology Development, Intel Corporation, Hillsboro, Oregon 97124 (United States); Nishi, Y. [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States)

2015-01-05

The effects of vacuum-ultraviolet (VUV) irradiation on copper penetration into non-porous low-k dielectrics under bias-temperature stress (BTS) were investigated. By employing x-ray photoelectron spectroscopy depth-profile measurements on both as-deposited and VUV-irradiated SiCOH/Cu stacks, it was found that under the same BTS conditions, the diffusion depth of Cu into the VUV-irradiated SiCOH is higher than that of as-deposited SiCOH. On the other hand, under the same temperature-annealing stress (TS) without electric bias, the Cu distribution profiles in the VUV-irradiated SiCOH were same with that for the as-deposited SiCOH. The experiments suggest that in as-deposited SiCOH, the diffused Cu exists primarily in the atomic state, while in VUV-irradiated SiCOH, the diffused Cu is oxidized by the hydroxyl ions (OH{sup −}) generated from VUV irradiation and exists in the ionic state. The mechanisms for metal diffusion and ion injection in VUV irradiated low-k dielectrics are discussed.

Vacuum ultra-violet damage and damage mitigation for plasma processing of highly porous organosilicate glass dielectrics

Energy Technology Data Exchange (ETDEWEB)

Marneffe, J.-F. de, E-mail: marneffe@imec.be; Lukaszewicz, M.; Porter, S. B.; Vajda, F.; Rutigliani, V.; Verdonck, P.; Baklanov, M. R. [IMEC v.z.w., 3001 Leuven (Belgium); Zhang, L.; Heyne, M.; El Otell, Z.; Krishtab, M. [IMEC v.z.w., 3001 Leuven (Belgium); Department of Chemistry, KULeuven, 3001 Leuven (Belgium); Goodyear, A.; Cooke, M. [Oxford Instruments Plasma Technology, BS49 4AP Bristol (United Kingdom)

2015-10-07

Porous organosilicate glass thin films, with k-value 2.0, were exposed to 147 nm vacuum ultra-violet (VUV) photons emitted in a Xenon capacitive coupled plasma discharge. Strong methyl bond depletion was observed, concomitant with a significant increase of the bulk dielectric constant. This indicates that, besides reactive radical diffusion, photons emitted during plasma processing do impede dielectric properties and therefore need to be tackled appropriately during patterning and integration. The detrimental effect of VUV irradiation can be partly suppressed by stuffing the low-k porous matrix with proper sacrificial polymers showing high VUV absorption together with good thermal and VUV stability. In addition, the choice of an appropriate hard-mask, showing high VUV absorption, can minimize VUV damage. Particular processing conditions allow to minimize the fluence of photons to the substrate and lead to negligible VUV damage. For patterned structures, in order to reduce VUV damage in the bulk and on feature sidewalls, the combination of both pore stuffing/material densification and absorbing hard-mask is recommended, and/or the use of low VUV-emitting plasma discharge.

Ultraviolet radiation for the sterilization of contact lenses

International Nuclear Information System (INIS)

Gritz, D.C.; Lee, T.Y.; McDonnell, P.J.; Shih, K.; Baron, N.

1990-01-01

Two sources of ultraviolet (UV) radiation with peak wavelengths in the UV-C or UV-B ranges were compared for their ability to sterilize contact lenses infected with Pseudomonas aeruginosa, Streptococcus pneumoniae, Acanthamoeba castellani, Candida albicans, and Aspergillus niger. Also examined was the effect of prolonged UV light exposure on soft and rigid gas permeable (RGP) contact lenses. The UV-C lamp (253.7 nm, 250 mW/cm2 at 1 cm) was germicidal for all organisms within 20 minutes but caused destruction of the soft lens polymers within 6 hours of cumulative exposure. UV-C caused damage to RGP lenses in less than 100 hours. The UV-B lamp (290-310 nm, 500 mW/cm2 at 1 cm) was germicidal for all organisms tested (except Aspergillus) with a 180-minute exposure and caused less severe changes in the soft lens polymers than did the UV-C lamp, although cumulative exposure of 300 hours did substantially weaken the soft lens material. RGP materials were minimally affected by exposure to 300 hours of UV-B. Ultraviolet light is an effective germicidal agent but is injurious to soft lens polymers; its possible utility in the sterilization of RGP lenses and lens cases deserves further study

Vacuum ultraviolet synchrotron measurements of excitons in NaMgF{sub 3}:Yb{sup 2+}

Energy Technology Data Exchange (ETDEWEB)

Hughes-Currie, Rosa B. [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); Ivanovskikh, Konstantin V. [ANK Service Ltd., PB 58, Novouralsk 624131, Sverdlovsk Region (Russian Federation); Ural Federal University, 19 Mira st., Ekaterinburg 620002 (Russian Federation); Reid, Michael F., E-mail: mike.reid@canterbury.ac.nz [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); MacDiarmid Institute for Advanced Materials and Nanotechnology (New Zealand); Wells, Jon-Paul R. [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); Dodd-Walls Centre for Quantum and Photonic Technologies (New Zealand); Reeves, Roger J. [Department of Physics and Astronomy, University of Canterbury, PB 4800, Christchurch 8140 (New Zealand); MacDiarmid Institute for Advanced Materials and Nanotechnology (New Zealand); Meijerink, Andries [Debye Institute, Utrecht University, P.O. Box 80 000, 3508 TA Utrecht (Netherlands)

2016-01-15

Results of a vacuum ultraviolet spectroscopic characterization of NaMgF{sub 3}:Yb{sup 2+} are presented. The material demonstrates emission features associated with self-trapped excitons and impurity-trapped excitons. The emission features noticeably overlap giving rise to a broad emission band from 17 000 to 35 000 cm{sup −1} at a sample temperature of 8 K. To identify the true profiles of the emission features we have used a deconvolution procedure. The deconvolution was possible due to the thermal quenching of self-trapped excitons at room temperature that allowed for direct observations of the impurity trapped exciton emission band. Energy transfer between host electronic excitations (excitons and e–h pairs) and Yb{sup 2+} ions leading to the formation of impurity-trapped excitons is evident from excitation spectra. - Highlights: • We present VUV emission and excitation spectra of NaMgF{sub 3}:Yb{sup 2+}. • Formation of free excitons leads to emission from intrinsic and extrinsic excitons. • We deconvolute the emission to separate the two overlapping exciton bands. • The excitation spectra show two mechanisms for forming impurity-trapped excitons.

Structure of rapidity divergences in multi-parton scattering soft factors

Science.gov (United States)

Vladimirov, Alexey

2018-04-01

We discuss the structure of rapidity divergences that are presented in the soft factors of transverse momentum dependent (TMD) factorization theorems. To provide the discussion on the most general level we consider soft factors for multi-parton scattering. We show that the rapidity divergences are result of the gluon exchanges with the distant transverse plane, and are structurally equivalent to the ultraviolet divergences. It allows to formulate and to prove the renormalization theorem for rapidity divergences. The proof is made with the help the conformal transformation which maps rapidity divergences to ultraviolet divergences. The theorem is the systematic form of the factorization of rapidity divergences, which is required for the definition of TMD parton distributions. In particular, the definition of multi parton distributions is presented. The equivalence of ultraviolet and rapidity divergences leads to the exact relation between soft and rapidity anomalous dimensions. Using this relation we derive the rapidity anomalous dimension at the three-loop order.

Two-color visible/vacuum ultraviolet photoelectron imaging dynamics of Br2.

Science.gov (United States)

Plenge, Jürgen; Nicolas, Christophe; Caster, Allison G; Ahmed, Musahid; Leone, Stephen R

2006-10-07

An experimental two-color photoionization dynamics study of laser-excited Br2 molecules is presented, combining pulsed visible laser excitation and tunable vacuum ultraviolet (VUV) synchrotron radiation with photoelectron imaging. The X 1Sigmag + -B 3Pi0+u transition in Br2 is excited at 527 nm corresponding predominantly to excitation of the v' = 28 vibrational level in the B 3Pi0+u state. Tunable VUV undulator radiation in the energy range of 8.40-10.15 eV is subsequently used to ionize the excited molecules to the X 2Pi32,12 state of the ion, and the ionic ground state is probed by photoelectron imaging. Similar experiments are performed using single-photon synchrotron ionization in the photon energy range of 10.75-12.50 eV without any laser excitation. Photoelectron kinetic energy distributions are extracted from the photoelectron images. In the case of two-color photoionization using resonant excitation of the intermediate B 3Pi0+u state, a broad distribution of photoelectron kinetic energies is observed, and in some cases even a bimodal distribution, which depends on the VUV photon energy. In contrast, for single-photon ionization, a single nearly Gaussian-shaped distribution is observed, which shifts to higher energy with photon energy. Simulated spectra based on Franck-Condon factors for the transitions Br2(X 1Sigmag+, v" = 0)-Br2 +(X 2Pi12,32, v+) and Br2(B 3Pi0+u, v' = 28)-Br2 +(X 2Pi12,32, v+) are generated. Comparison of these calculated spectra with the measured images suggests that the differences in the kinetic energy distributions for the two ionization processes reflect the different extensions of the vibrational wave functions in the v" = 0 electronic ground state (X 1Sigmag+) versus the electronically and vibrationally excited state (B 3Pi0+u, v' = 28).

Fabrication of ridge waveguide structure from photosensitive TiO2/ormosil hybrid films by using an ultraviolet soft imprint technique

International Nuclear Information System (INIS)

Zhang, Xuehua; Que, Wenxiu; Chen, Jing; Gao, Tianxi; Hu, Jiaxing; Liu, Weiguo

2013-01-01

Photosensitive TiO 2 /organically modified silane hybrid films were prepared by combining a low-temperature sol–gel process with a spin-coating technique. Optical properties and photochemical activities of the as-prepared hybrid sol–gel films under different UV irradiation time were characterized and monitored by prism coupling technique, UV–visible spectroscopy, and Fourier transform infrared spectroscopy. Surface morphology of the hybrid films was also observed by an atomic force microscopy. Advantages for fabrication of ridge waveguide structure based on the photosensitive hybrid films were demonstrated by an ultraviolet soft imprint technique. Effects of imprint force, imprint time, and UV irradiation time on high replication fidelity of the ridge waveguide structure were also investigated. An altitude replication fidelity of 99.7% can be obtained when the imprint force of 2 MPa, imprint time of 30 min and UV irradiation time of 45 min were chosen. Scanning electron microscopy and surface profiler were used to characterize the morphological and surface profile properties of the as fabricated ridge waveguide structure. Results indicate that the as-prepared photosensitive hybrid materials have great applicability for the fabrication of micro-optical elements and advantage as the imprint layer under the ultraviolet soft imprint technique. - Highlights: ► Photosensitive TiO 2 /ormosil hybrid film is prepared by a sol–gel process. ► Optical properties of the films change a little with UV exposure time. ► Photo-chemical property of the film changes a lot with UV exposure time. ► The imprint force and time, and the UV exposure time affect the imprint fidelity. ► A fidelity value of 99.7% is obtained under an optimized condition

Determination of ionization energies of CnN (n=4-12): Vacuum-ultraviolet (VUV) photoionization experiments and theoretical calculations

International Nuclear Information System (INIS)

Kostko, Oleg; Zhou, Jia; Sun, Bian Jian; Lie, Jie Shiuan; Chang, Agnes H.H.; Kaiser, Ralf I.; Ahmed, Musahid

2010-01-01

Results from single photon vacuum ultraviolet photoionization of astrophysically relevant CnN clusters, n = 4 - 12, in the photon energy range of 8.0 eV to 12.8 eV are presented. The experimental photoionization efficiency curves, combined with electronic structure calculations, provide improved ionization energies of the CnN species. A search through numerous nitrogen-terminated CnN isomers for n=4-9 indicates that the linear isomer has the lowest energy, and therefore should be the most abundant isomer in the molecular beam. Comparison with calculated results also shed light on the energetics of the linear CnN clusters, particularly in the trends of the even-carbon and the odd-carbon series. These results can help guide the search of potential astronomical observations of these neutral molecules together with their cations in highly ionized regions or regions with a high UV/VUV photon flux (ranging from the visible to VUV with flux maxima in the Lyman-a region) in the interstellar medium.

[Caesarean section with vacuum extraction of the head].

Science.gov (United States)

Dimitrov, A; Pavlova, E; Krŭsteva, K; Nikolov, A

2008-01-01

The aim of the study is to investigate the benefits and the limits in using the soft cup vacuum extractor on the fetal scalp during the caesarean section. The prospective study includes 19 cases of caesarean sections (group A), with vacuum assisted delivery using the soft cup vacuum extractor on the fetal scalp (diameter 6 cm) and 25 cases (group B) of caesarean sections with usual, manual extraction of the head assisted by fundal compression. All of the patients had undergone a planned caesarean section on term in absence of uterine activity and preserved amniotic membranes. Our results doesn't show differences in the Apgar score on the first and 5-th minute in the newborns of the two groups. The duration of the scalp traction was significantly shorter (30 +/- 4 sec) in comparison to the classical manual extraction (53 +/- 21 sec). The mean duration for applying the vacuum cup was 10 sec and 25 sec for tractions. The total blood loose and total duration of the caesarean sections were shorter than in the control group. The applied traction with the vacuum cup was sufficient for head extraction and there was no need for additional fundal compression. In conclusion we consider that the extraction of the fetal head in high position in caesarean section with vacuum extractor is an easy, non traumatic and rapid method which can put away the need of rough and prolonged fundal compression and its consequences.

An ultrahigh-vacuum apparatus for resonant diffraction experiments using soft x rays (hν=300-2000 eV)

International Nuclear Information System (INIS)

Takeuchi, T.; Chainani, A.; Takata, Y.; Tanaka, Y.; Oura, M.; Tsubota, M.; Senba, Y.; Ohashi, H.; Mochiku, T.; Hirata, K.; Shin, S.

2009-01-01

We have developed an ultrahigh-vacuum instrument for resonant diffraction experiments using polarized soft x rays in the energy range of hν=300-2000 eV at beamline BL17SU of SPring-8. The diffractometer consists of modified differentially pumped rotary feedthroughs for θ-2θ stages, a sample manipulator with motor-controlled x-y-z-, tilt (χ)-, and azimuth (φ)-axes, and a liquid helium flow-type cryostat for temperature dependent measurements between 30 and 300 K. Test results indicate that the diffractometer exhibits high reproducibility (better than 0.001 deg.) for a Bragg reflection of α-quartz 100 at a photon energy of hν=1950 eV. Typical off- and on-resonance Bragg reflections in the energy range of 530-1950 eV could be measured using the apparatus. The results show that x-ray diffraction experiments with energy-, azimuth-, and incident photon polarization-dependence can be reliably measured using soft x rays in the energy range of ∼300-2000 eV. The facility can be used for resonant diffraction experiments across the L-edge of transition metals, M-edge of lanthanides, and up to the Si K-edge of materials.

Vacuum fluctuations of the supersymmetric field in curved background

International Nuclear Information System (INIS)

Bilić, Neven; Domazet, Silvije; Guberina, Branko

2012-01-01

We study a supersymmetric model in curved background spacetime. We calculate the effective action and the vacuum expectation value of the energy momentum tensor using a covariant regularization procedure. A soft supersymmetry breaking induces a nonzero contribution to the vacuum energy density and pressure. Assuming the presence of a cosmic fluid in addition to the vacuum fluctuations of the supersymmetric field an effective equation of state is derived in a self-consistent approach at one loop order. The net effect of the vacuum fluctuations of the supersymmetric fields in the leading adiabatic order is a renormalization of the Newton and cosmological constants.

Vacuum fluctuations of the supersymmetric field in curved background

Energy Technology Data Exchange (ETDEWEB)

Bilic, Neven, E-mail: bilic@thphys.irb.hr [Rudjer Boskovic Institute, POB 180, HR-10002 Zagreb (Croatia); Domazet, Silvije, E-mail: sdomazet@irb.hr [Rudjer Boskovic Institute, POB 180, HR-10002 Zagreb (Croatia); Guberina, Branko, E-mail: guberina@thphys.irb.hr [Rudjer Boskovic Institute, POB 180, HR-10002 Zagreb (Croatia)

2012-01-16

We study a supersymmetric model in curved background spacetime. We calculate the effective action and the vacuum expectation value of the energy momentum tensor using a covariant regularization procedure. A soft supersymmetry breaking induces a nonzero contribution to the vacuum energy density and pressure. Assuming the presence of a cosmic fluid in addition to the vacuum fluctuations of the supersymmetric field an effective equation of state is derived in a self-consistent approach at one loop order. The net effect of the vacuum fluctuations of the supersymmetric fields in the leading adiabatic order is a renormalization of the Newton and cosmological constants.

Hybrid 3D Printing of Soft Electronics.

Science.gov (United States)

Valentine, Alexander D; Busbee, Travis A; Boley, John William; Raney, Jordan R; Chortos, Alex; Kotikian, Arda; Berrigan, John Daniel; Durstock, Michael F; Lewis, Jennifer A

2017-10-01

Hybrid 3D printing is a new method for producing soft electronics that combines direct ink writing of conductive and dielectric elastomeric materials with automated pick-and-place of surface mount electronic components within an integrated additive manufacturing platform. Using this approach, insulating matrix and conductive electrode inks are directly printed in specific layouts. Passive and active electrical components are then integrated to produce the desired electronic circuitry by using an empty nozzle (in vacuum-on mode) to pick up individual components, place them onto the substrate, and then deposit them (in vacuum-off mode) in the desired location. The components are then interconnected via printed conductive traces to yield soft electronic devices that may find potential application in wearable electronics, soft robotics, and biomedical devices. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Laser-assisted vacuum arc extreme ultraviolet source: a comparison of picosecond and nanosecond laser triggering

Science.gov (United States)

Beyene, Girum A.; Tobin, Isaac; Juschkin, Larissa; Hayden, Patrick; O'Sullivan, Gerry; Sokell, Emma; Zakharov, Vassily S.; Zakharov, Sergey V.; O'Reilly, Fergal

2016-06-01

Extreme ultraviolet (EUV) light generation by hybrid laser-assisted vacuum arc discharge plasmas, utilizing Sn-coated rotating-disc-electrodes, was investigated. The discharge was initiated by localized ablation of the liquid tin coating of the cathode disc by a laser pulse. The laser pulse, at 1064 nm, was generated by Nd:YAG lasers with variable energy from 1 to 100 mJ per pulse. The impact of shortening the laser pulse from 7 ns to 170 ps on the EUV generation has been investigated in detail. The use of ps pulses resulted in an increase in emission of EUV radiation. With a fixed discharge energy of ~4 J, the EUV conversion efficiency tends to plateau at ~2.4  ±  0.25% for the ps laser pulses, while for the ns pulses, it saturates at ~1.7  ±  0.3%. Under similar discharge and laser energy conditions, operating the EUV source with the ps-triggering resulted also in narrower spectral profiles of the emission in comparison to ns-triggering. The results indicate an advantage in using ps-triggering in laser-assisted discharges to produce brighter plasmas required for applications such as metrology.

Note: a novel vacuum ultraviolet light source assembly with aluminum-coated electrodes for enhancing the ionization efficiency of photoionization mass spectrometry.

Science.gov (United States)

Zhu, Zhixiang; Wang, Jian; Qiu, Keqing; Liu, Chengyuan; Qi, Fei; Pan, Yang

2014-04-01

A novel vacuum ultraviolet (VUV) light source assembly (VUVLSA) for enhancing the ionization efficiency of photoionization mass spectrometer has been described. The VUVLSA composes of a Krypton lamp and a pair of disk electrodes with circular center cavities. The two interior surfaces that face the photoionization region were aluminum-coated. VUV light can be reflected back and forth in the photoionization region between the electrodes, thus the photoionization efficiency can be greatly enhanced. The performances of two different shaped electrodes, the coated double flat electrodes (DFE), and double conical electrodes, were studied. We showed that the signal amplification of coated DFE is around 4 times higher than that of uncoated electrodes without VUV light reflection. The relationship between the pressure of ionization chamber and mass signal enhancement has also been studied.

Vacuum instability in scalar field theories

International Nuclear Information System (INIS)

McKane, A.J.

1978-09-01

Scalar field theories with an interaction of the form gphisup(N) have no stable vacuum state for some range of values of their coupling constant, g. This thesis reports calculations of vacuum instability in such theories. Using the idea that the tunnelling out of the vacuum state is described by the instanton solutions of the theory, the imaginary part of the vertex functions is calculated for the massless theory in the one-loop approximation, near the dimension dsub(c) = 2N/N-2, where the theory is just renormalisable. The calculation differs from previous treatments in that dimensional regularisation is used to control the ultra-violet divergences of the theory. In this way previous analytic calculations in conformally invariant field theories are extended to the case where the theory is almost conformally invariant, since it is now defined in dsub(c) - epsilon dimensions (epsilon > 0). (author)

Fabrication of ridge waveguide structure from photosensitive TiO{sub 2}/ormosil hybrid films by using an ultraviolet soft imprint technique

Energy Technology Data Exchange (ETDEWEB)

Zhang, Xuehua [Electronic Materials Research Laboratory, International Center for Dielectric Research, Xi' an Jiaotong University, Xi' an 710049, Shaanxi (China); Que, Wenxiu, E-mail: wxque@mail.xjtu.edu.cn [Electronic Materials Research Laboratory, International Center for Dielectric Research, Xi' an Jiaotong University, Xi' an 710049, Shaanxi (China); Chen, Jing; Gao, Tianxi; Hu, Jiaxing [Electronic Materials Research Laboratory, International Center for Dielectric Research, Xi' an Jiaotong University, Xi' an 710049, Shaanxi (China); Liu, Weiguo [Micro-optoelectronic Systems Laboratories, Xi' an Technological University, Xi' an 710032, Shaanxi (China)

2013-03-01

Photosensitive TiO{sub 2}/organically modified silane hybrid films were prepared by combining a low-temperature sol–gel process with a spin-coating technique. Optical properties and photochemical activities of the as-prepared hybrid sol–gel films under different UV irradiation time were characterized and monitored by prism coupling technique, UV–visible spectroscopy, and Fourier transform infrared spectroscopy. Surface morphology of the hybrid films was also observed by an atomic force microscopy. Advantages for fabrication of ridge waveguide structure based on the photosensitive hybrid films were demonstrated by an ultraviolet soft imprint technique. Effects of imprint force, imprint time, and UV irradiation time on high replication fidelity of the ridge waveguide structure were also investigated. An altitude replication fidelity of 99.7% can be obtained when the imprint force of 2 MPa, imprint time of 30 min and UV irradiation time of 45 min were chosen. Scanning electron microscopy and surface profiler were used to characterize the morphological and surface profile properties of the as fabricated ridge waveguide structure. Results indicate that the as-prepared photosensitive hybrid materials have great applicability for the fabrication of micro-optical elements and advantage as the imprint layer under the ultraviolet soft imprint technique. - Highlights: ► Photosensitive TiO{sub 2}/ormosil hybrid film is prepared by a sol–gel process. ► Optical properties of the films change a little with UV exposure time. ► Photo-chemical property of the film changes a lot with UV exposure time. ► The imprint force and time, and the UV exposure time affect the imprint fidelity. ► A fidelity value of 99.7% is obtained under an optimized condition.

Vacuum polarization in Coulomb field revisited

Energy Technology Data Exchange (ETDEWEB)

Zamastil, J., E-mail: zamastil@karlov.mff.cuni.cz; Šimsa, D.

2017-04-15

Simplified derivation of Wichmann–Kroll term is presented. The derivation uses two formulas for hypergeometric functions, but otherwise is elementary. It is found that Laplace transform of the vacuum charge density diverges at zero momentum transfer. This divergence has nothing to do with known ultraviolet divergence. The latter is related to the large momentum behavior of the pertinent integral, while the former to the small momentum behavior. When these divergences are removed, the energy shift caused by vacuum polarization for an ordinary hydrogen obtained here is in an exact agreement with the result obtained by Wichmann and Kroll. Also, for muonic hydrogen the result obtained here reasonably agrees with that given in literature.

A soft X-ray source based on a low divergence, high repetition rate ultraviolet laser

Science.gov (United States)

Crawford, E. A.; Hoffman, A. L.; Milroy, R. D.; Quimby, D. C.; Albrecht, G. F.

The CORK code is utilized to evaluate the applicability of low divergence ultraviolet lasers for efficient production of soft X-rays. The use of the axial hydrodynamic code wih one ozone radial expansion to estimate radial motion and laser energy is examined. The calculation of ionization levels of the plasma and radiation rates by employing the atomic physics and radiation model included in the CORK code is described. Computations using the hydrodynamic code to determine the effect of laser intensity, spot size, and wavelength on plasma electron temperature are provided. The X-ray conversion efficiencies of the lasers are analyzed. It is observed that for a 1 GW laser power the X-ray conversion efficiency is a function of spot size, only weakly dependent on pulse length for time scales exceeding 100 psec, and better conversion efficiencies are obtained at shorter wavelengths. It is concluded that these small lasers focused to 30 micron spot sizes and 10 to the 14th W/sq cm intensities are useful sources of 1-2 keV radiation.

Status of Indus-1 and Indus-2 beamlines

CERN Document Server

Nandedkar, R V

2003-01-01

Indus-1 and Indus-2 are two synchrotron radiation sources that are planned in India. Indus-1 is a 450 MeV electron storage ring for vacuum ultra-violet soft X-ray radiation. This source is operational. Two beamlines, viz. a soft X-ray/vacuum ultra-violet reflectometry beamline and an angle integrated photoelectron spectroscopy beamline are already operational. Angle resolved photoelectron spectroscopy and photophysics beamlines are going to be operational soon. The second Indian synchrotron source is the 2.5 GeV Indus-2 electron storage ring that is under construction and is expected to be ready for commissioning in the year 2003. Of the total 27 beamlines possible on this ring, about 10 beamlines are already planned and are in the design stage.

Status of Indus-1 and Indus-2 beamlines

International Nuclear Information System (INIS)

Nandedkar, R.V.; Sawhney, K.J.S.

2003-01-01

Indus-1 and Indus-2 are two synchrotron radiation sources that are planned in India. Indus-1 is a 450 MeV electron storage ring for vacuum ultra-violet soft X-ray radiation. This source is operational. Two beamlines, viz. a soft X-ray/vacuum ultra-violet reflectometry beamline and an angle integrated photoelectron spectroscopy beamline are already operational. Angle resolved photoelectron spectroscopy and photophysics beamlines are going to be operational soon. The second Indian synchrotron source is the 2.5 GeV Indus-2 electron storage ring that is under construction and is expected to be ready for commissioning in the year 2003. Of the total 27 beamlines possible on this ring, about 10 beamlines are already planned and are in the design stage

Comparison of the effect of soft-core potentials and Coulombic potentials on bremsstrahlung during laser matter interaction

Science.gov (United States)

Pandit, Rishi R.; Becker, Valerie R.; Barrington, Kasey; Thurston, Jeremy; Ramunno, Lora; Ackad, Edward

2018-04-01

An intense, short laser pulse incident on rare-gas clusters can produce nano-plasmas containing energetic electrons. As these electrons undergo scattering, from both phonons and ions, they emit bremsstrahlung radiation. Here, we compare a theory of bremsstrahlung emission appropriate for the interaction of intense lasers with matter using soft-core potentials and Coulombic potentials. A new scaling for the radiation cross-section and the radiated power via bremsstrahlung is derived for a soft-core potential (which depends on the potential depth) and compared with the Coulomb potential. Calculations using the new scaling are performed for electrons in vacuum ultraviolet, infrared and mid-infrared laser pulses. The radiation cross-section and the radiation power via bremsstrahlung are found to increase rapidly with increases in the potential depth of up to around 200 eV and then become mostly saturated for larger depths while remaining constant for the Coulomb potential. In both cases, the radiation cross-section and the radiation power of bremsstrahlung decrease with increases in the laser wavelength. The ratio of the scattering amplitude for the soft-core potential and that for the Coulombic potential decreases exponentially with an increase in momentum transfer. The bremsstrahlung emission by electrons in plasmas may provide a broadband light source for diagnostics.

Nanoscale freestanding gratings for ultraviolet blocking filters

Energy Technology Data Exchange (ETDEWEB)

van Beek, J.T.; Fleming, R.C.; Hindle, P.S.; Prentiss, J.D.; Schattenburg, M.L. [Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Ritzau, S. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

1998-11-01

Ultraviolet (UV) blocking filters are needed for atomic flux imaging in environments where high levels of ultraviolet radiation are present. Freestanding gratings are a promising candidate for UV filtering. They have a high aspect ratio ({approximately}13), narrow ({approximately}40 nm) slots, and effectively block UV radiation. The grating fabrication process makes use of several etching, electroplating, and lithographic steps and includes an optional step to plug pinholes induced by particles during processing. Gratings were successfully manufactured and tested. Measured UV transmissions of {approximately}10{sup {minus}5} and particle transmissions of {approximately}10{percent} are in agreement with theoretical predictions. {copyright} {ital 1998 American Vacuum Society.}

Spherically symmetric static spacetimes in vacuum f(T) gravity

International Nuclear Information System (INIS)

Ferraro, Rafael; Fiorini, Franco

2011-01-01

We show that Schwarzschild geometry remains as a vacuum solution for those four-dimensional f(T) gravitational theories behaving as ultraviolet deformations of general relativity. In the gentler context of three-dimensional gravity, we also find that the infrared-deformed f(T) gravities, like the ones used to describe the late cosmic speed up of the Universe, have as the circularly symmetric vacuum solution a Deser-de Sitter or a Banados, Teitelboim and Zanelli-like spacetime with an effective cosmological constant depending on the infrared scale present in the function f(T).

Effect of the coherent cancellation of the two-photon resonance on the generation of vacuum ultraviolet light by two-photon reasonantly enhanced four-wave mixing

International Nuclear Information System (INIS)

Payne, M.G.; Garrett, W.R.; Judish, J.P.; Wunderlich, R.

1988-11-01

Many of the most impressive demonstrations of the efficient generation of vacuum ultraviolet (VUV) light have made use of two- photon resonantly enhanced four-wave mixing to generate light at ω/sub VUV/ = 2ω/sub L1/ +- ω/sub L2/. The two-photon resonance state is coupled to the ground state both by two photons from the first laser, or by a photon from the second laser and one from the generated VUV beam. We show here that these two coherent pathways destructively interfere once the second laser is made sufficiently intense, thereby leading to an important limiting effect on the achievable conversion efficiency. 4 refs

Vacuum-Ultraviolet Photoionization and Mass Spectrometric Characterization of Lignin Monomers Coniferyl and Sinapyl Alcohols

Energy Technology Data Exchange (ETDEWEB)

Takahashi, Lynelle K.; Zhou, Jia; Kostko, Oleg; Golan, Amir; Leone, Stephen R.; Ahmed, Musahid

2011-02-09

The fragmentation mechanisms of monolignols under various energetic processes are studied with jet-cooled thermal desorption molecular beam (TDMB) mass spectrometry (MS), 25 keV Bi3+ secondary ion MS (SIMS), synchrotron vacuum-ultraviolet secondary neutral MS (VUV-SNMS) and theoretical methods. Experimental and calculated appearance energies of fragments observed in TDMB MS indicate that the coniferyl alcohol photoionization mass spectra contain the molecular parent and several dissociative photoionization products. Similar results obtained for sinapyl alcohol are also discussed briefly. Ionization energies of 7.60 eV ? 0.05 eV for coniferyl alcohol and<7.4 eV for both sinapyl and dihydrosinapyl alcohols are determined. The positive ion SIMS spectrum of coniferyl alcohol shares few characteristic peaks (m/z = 137 and 151) with the TDMB mass spectra, shows extensive fragmentation, and does not exhibit clear molecular parent signals. VUV-SNMS spectra, on the other hand, are dominated by the parent ion and main fragments also present in the TDMB spectra. Molecular fragmentation in VUV-SNMS spectra can be reduced by increasing the extraction delay time. Some features resembling the SIMS spectra are also observed in the desorbed neutral products. The monolignol VUV-SNMS peaks shared with the TDMB mass spectra suggest that dissociative photoionization of ion-sputtered neutral molecules predominate in the VUV-SNMS mass spectra, despite the extra internal energy imparted in the initial ion impact. The potential applications of these results to imaging mass spectrometry of bio-molecules are discussed.

Fourier-transform spectroscopy of HD in the vacuum ultraviolet at λ = 87-112 nm

Science.gov (United States)

Ivanov, T. I.; Dickenson, G. D.; Roudjane, M.; de Oliveira, N.; Joyeux, D.; Nahon, L.; Tchang-Brillet, W.-Ü. L.; Ubachs, W.

2010-03-01

Absorption spectroscopy in the vacuum ultraviolet (VUV) domain was performed on the hydrogen-deuteride molecule with a novel Fourier-transform spectrometer based upon wavefront division interferometry. This unique instrument, which is a permanent endstation of the undulator-based beamline DESIRS on the synchrotron SOLEIL facility, opens the way to Fourier-transform spectroscopy in the VUV range. The HD spectral lines in the Lyman and Werner bands were recorded in the 87-112 nm range from a quasi-static gas sample in a windowless configuration and with a Doppler-limited resolution. Line positions of some 268 transitions in the ? Lyman bands and 141 transitions in the ? Werner bands were deduced with uncertainties of 0.04 cm-1 (1σ) which correspond to Δλ/λ ∼ 4 × 10-7. This extensive laboratory database is of relevance for comparison with astronomical observations of H2 and HD spectra from highly redshifted objects, with the goal of extracting a possible variation of the proton-to-electron mass ratio (μ = m p /m e ) on a cosmological time scale. For this reason also calculations of the so-called sensitivity coefficients K i were performed in order to allow for deducing constraints on Δμ/μ. The K i coefficients, associated with the line shift that each spectral line undergoes as a result of a varying value for μ, were derived from calculations as a function of μ solving the Schrödinger equation using ab initio potentials.

Interpretation of the photoelectron, ultraviolet, and vacuum ultraviolet photoabsorption spectra of bromobenzene by ab initio configuration interaction and DFT computations

Energy Technology Data Exchange (ETDEWEB)

Palmer, Michael H., E-mail: m.h.palmer@ed.ac.uk; Ridley, Trevor, E-mail: t.ridley@ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@sns.it, E-mail: kipeters@wsu.edu [School of Chemistry, University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh EH9 3FJ, Scotland (United Kingdom); Hoffmann, Søren Vrønning, E-mail: t.ridley@ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@sns.it, E-mail: kipeters@wsu.edu; Jones, Nykola C., E-mail: t.ridley@ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@sns.it, E-mail: kipeters@wsu.edu [ISA, Department of Physics and Astronomy, Aarhus University, Ny Munkegade 120, DK-8000 Aarhus C (Denmark); Coreno, Marcello, E-mail: t.ridley@ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@sns.it, E-mail: kipeters@wsu.edu [CNR-IMIP, Montelibretti, c/o Laboratorio Elettra, Trieste (Italy); Simone, Monica de, E-mail: t.ridley@ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@sns.it, E-mail: kipeters@wsu.edu [CNR-IOM Laboratorio TASC, Trieste (Italy); Grazioli, Cesare [CNR-IOM Laboratorio TASC, Trieste (Italy); Department of Chemical and Pharmaceutical Sciences, University of Trieste, Trieste (Italy); Zhang, Teng [Department of Physics and Astronomy, University of Uppsala, Uppsala (Sweden); and others

2015-10-28

New photoelectron, ultraviolet (UV), and vacuum UV (VUV) spectra have been obtained for bromobenzene by synchrotron study with higher sensitivity and resolution than previous work. This, together with use of ab initio calculations with both configuration interaction and time dependent density functional theoretical methods, has led to major advances in interpretation. The VUV spectrum has led to identification of a considerable number of Rydberg states for the first time. The Franck-Condon (FC) analyses including both hot and cold bands lead to identification of the vibrational structure of both ionic and electronically excited states including two Rydberg states. The UV onset has been interpreted in some detail, and an interpretation based on the superposition of FC and Herzberg-Teller contributions has been performed. In a similar way, the 6 eV absorption band which is poorly resolved is analysed in terms of the presence of two ππ* states of {sup 1}A{sub 1} (higher oscillator strength) and {sup 1}B{sub 2} (lower oscillator strength) symmetries, respectively. The detailed analysis of the vibrational structure of the 2{sup 2}B{sub 1} ionic state is particularly challenging, and the best interpretation is based on equation-of-motion-coupled cluster with singles and doubles computations. A number of equilibrium structures of the ionic and singlet excited states show that the molecular structure is less subject to variation than corresponding studies for iodobenzene. The equilibrium structures of the 3b{sub 1}3s and 6b{sub 2}3s (valence shell numbering) Rydberg states have been obtained and compared with the corresponding ionic limit structures.

Exploring the structure of the quenched QCD vacuum with overlap fermions

International Nuclear Information System (INIS)

Ilgenfritz, E.M.; Koller, K.; Koma, Y.; Schierholz, G.; Deutsches Elektronen-Synchrotron; Streuer, T.; Weinberg, V.; Freie Univ. Berlin

2007-05-01

Overlap fermions have an exact chiral symmetry on the lattice and are thus an appropriate tool for investigating the chiral and topological structure of the QCD vacuum. We study various chiral and topological aspects of quenched gauge field configurations. This includes the localization and chiral properties of the eigenmodes, the local structure of the ultraviolet filtered field strength tensor, as well as the structure of topological charge fluctuations. We conclude that the vacuum has a multifractal structure. (orig.)

Soft x-ray circular dichroism of biomolecules

International Nuclear Information System (INIS)

Nakagawa, Kazumichi; Tanaka, Makoto; Agui, Akane

2005-01-01

We succeeded to observe natural circular dichroism NCD for biomolecules in soft X-ray region for the first time. Evaporated films of amino acids, phenylalanine (phe) and serine (ser) were prepared in vacuum with the thickness of about 300 nm. Measurement was carried out at the soft X-ray undulator beamline BL23SU of the Spring-8, where left- and right-circularly polarized light (LCPL and RCPL) was available from an APPLE-2 undulator. Difference spectra DA(hν) was plotted as a function of photon energy hν of soft X-ray to be the difference between absorption coefficient A L for LCPL and absorption coefficient A R for RCPL, namely, DA(hν) ≡ A L (hν) - A R (hν). Values of A L and A R were determined by means of the photoelectric drain current measurement. In the DA(hν) spectra for L-phe films, negative peak was observed at 407 eV. On the contrary, for D-phe films, positive peak was observed at 407 eV with the same magnitude but opposite sign. Moreover, no signal was observed for racemic phenylalanine (DL-phe). In the wavelength region of visible to ultraviolet, there is well-known general law in which NCD signals for D- and L-enantiomers are the same magnitude but opposite sign and racemic compound does not show NCD spectra. Characteristic features in DA(hν) spectra of the L-phe, D-phe and DL-phe were of good agreement with this well-known general law. Based on this good agreement, we concluded that peaks at 407 eV in the DA(hν) spectra are true NCD peaks. For ser films, we assigned peaks at 540 eV and 548 eV to be NCD peaks in the same manner. We hope that our first observation of NCD for biomolecules at soft X-ray region will open new science and technologies such as basic science including elucidation of fundamental mechanism of NCD and application to manipulate biomolecules using circularly polarized soft X-ray beams. (author)

Photodissociation dynamics of H2O at 111.5 nm by a vacuum ultraviolet free electron laser

Science.gov (United States)

Wang, Heilong; Yu, Yong; Chang, Yao; Su, Shu; Yu, Shengrui; Li, Qinming; Tao, Kai; Ding, Hongli; Yang, Jaiyue; Wang, Guanglei; Che, Li; He, Zhigang; Chen, Zhichao; Wang, Xingan; Zhang, Weiqing; Dai, Dongxu; Wu, Guorong; Yuan, Kaijun; Yang, Xueming

2018-03-01

Photodissociation dynamics of H2O via the F ˜ state at 111.5 nm were investigated using the high resolution H-atom Rydberg "tagging" time-of-flight (TOF) technique, in combination with the tunable vacuum ultraviolet free electron laser at the Dalian Coherent Light Source. The product translational energy distributions and angular distributions in both parallel and perpendicular directions were derived from the recorded TOF spectra. Based on these distributions, the quantum state distributions and angular anisotropy parameters of OH (X) and OH (A) products have been determined. For the OH (A) + H channel, highly rotationally excited OH (A) products have been observed. These products are ascribed to a fast direct dissociation on the B ˜ 1A1 state surface after multi-step internal conversions from the initial excited F ˜ state to the B ˜ state. While for the OH (X) + H channel, very highly rotationally excited OH (X) products with moderate vibrational excitation are revealed and attributed to the dissociation via a nonadiabatic pathway through the well-known two conical intersections between the B ˜ -state and the X ˜ -state surfaces.

Effects of vacuum ultraviolet irradiation on trapped charges and leakage currents of low-k organosilicate dielectrics

Energy Technology Data Exchange (ETDEWEB)

Zheng, H.; Guo, X.; Pei, D.; Shohet, J. L. [Plasma Processing and Technology Laboratory and Department of Electrical and Computer Engineering, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); Ryan, E. T. [GLOBALFOUNDRIES, Albany, New York 12203 (United States); Nishi, Y. [Stanford University, Stanford, California 94305 (United States)

2015-05-11

Vacuum ultraviolet (VUV) photoemission spectroscopy is utilized to investigate the distribution of trapped charges within the bandgap of low dielectric constant (low-k) organosilicate (SiCOH) materials. It was found that trapped charges are continuously distributed within the bandgap of porous SiCOH and the center of the trapped states is 1.3 eV above the valence band of the tested sample. By comparing photoemission spectroscopic results before and after VUV exposure, VUV irradiation with photon energies between 7.6 and 8.9 eV was found to deplete trapped charge while UV exposure with photon energies less than 6.0 eV induces more trapped charges in tested samples. Current-Voltage (IV) characteristics results show that the reliability of dielectrics is improved after VUV irradiation with photon energies between 7.6 and 8.9 eV, while UV exposure results in an increased level of leakage current and a decreased breakdown voltage, both of which are harmful to the reliability of the dielectric. This work shows that VUV irradiation holds the potential to substitute for UV curing in microelectronic processing to improve the reliability of low-k dielectrics by mitigating the leakage currents and trapped charges induced by UV irradiation.

FIBRILLAR CHROMOSPHERIC SPICULE-LIKE COUNTERPARTS TO AN EXTREME-ULTRAVIOLET AND SOFT X-RAY BLOWOUT CORONAL JET

International Nuclear Information System (INIS)

Sterling, Alphonse C.; Moore, Ronald L.; Harra, Louise K.

2010-01-01

We observe an erupting jet feature in a solar polar coronal hole, using data from Hinode/Solar Optical Telescope (SOT), Extreme Ultraviolet Imaging Spectrometer (EIS), and X-Ray Telescope (XRT), with supplemental data from STEREO/EUVI. From extreme-ultraviolet (EUV) and soft X-ray (SXR) images we identify the erupting feature as a blowout coronal jet: in SXRs it is a jet with a bright base, and in EUV it appears as an eruption of relatively cool (∼50,000 K) material of horizontal size scale ∼30'' originating from the base of the SXR jet. In SOT Ca II H images, the most pronounced analog is a pair of thin (∼1'') ejections at the locations of either of the two legs of the erupting EUV jet. These Ca II features eventually rise beyond 45'', leaving the SOT field of view, and have an appearance similar to standard spicules except that they are much taller. They have velocities similar to that of 'type II' spicules, ∼100 km s -1 , and they appear to have spicule-like substructures splitting off from them with horizontal velocity ∼50 km s -1 , similar to the velocities of splitting spicules measured by Sterling et al. Motions of splitting features and of other substructures suggest that the macroscopic EUV jet is spinning or unwinding as it is ejected. This and earlier work suggest that a subpopulation of Ca II type II spicules are the Ca II manifestation of portions of larger scale erupting magnetic jets. A different subpopulation of type II spicules could be blowout jets occurring on a much smaller horizontal size scale than the event we observe here.

Measurement of H and H2 populations in-situ in a low-temperature plasma by vacuum-ultraviolet laser-absorption spectroscopy

International Nuclear Information System (INIS)

Schlachter, A.S.; Young, A.T.; Stutzin, G.C.; Stearns, J.W.; Doebele, H.G.; Leung, K.N.; Kunkel, W.B.

1988-12-01

A new technique, vacuum-ultraviolet laser-absorption spectroscopy, has been developed to quantitatively determine the absolute density of H and H 2 within a plasma. The technique is particularly well suited to measurement in a plasma, where high charged particle and photon background complicate other methods of detection. The high selectivity and sensitivity of the technique allows for the measurement of the rotational-vibrational state distribution of H 2 as well as the translational temperature of the atoms and molecules. The technique has been used to study both pulsed and continuous H/sup /minus// ion-source plasma discharges. H 2 state distributions in a multicusp ''volume'' H/sup /minus// ion- source plasma show a high degree of internal excitation, with levels up to v = 5 and J = 8 being observed. The method is applicable for a very wide range of plasma conditions. Emission measurements from excited states of H are also reported. 17 refs., 9 figs

Decay constants in soft wall AdS/QCD revisited

Directory of Open Access Journals (Sweden)

Nelson R.F. Braga

2016-12-01

We show here that a modified framework of soft wall AdS/QCD involving an additional dimensionfull parameter, associated with an ultraviolet energy scale, provides decay constants decreasing with radial excitation level. In this version of the soft wall model the two point function of gauge theory operators is calculated at a finite position of the anti-de Sitter space radial coordinate.

Development of a pump-probe facility with sub-picosecond time resolution combining a high-power ultraviolet regenerative FEL amplifier and a soft X-ray SASE FEL

International Nuclear Information System (INIS)

Faatz, B.; Fateev, A.A.; Feldhaus, J.; Krzywinski, J.; Pflueger, J.; Rossbach, J.; Saldin, E.L.; Schneidmiller, E.A.; Yurkov, M.V.

2001-01-01

This paper presents the conceptual design of a high power radiation source with laser-like characteristics in the ultraviolet spectral range at the TESLA Test Facility (TTF). The concept is based on the generation of radiation in a regenerative FEL amplifier (RAFEL). The RAFEL described in this paper covers a wavelength range of 200-400 nm and provides 200 fs pulses with 2 mJ of optical energy per pulse. The linac operates at 1% duty factor and the average output radiation power exceeds 100 W. The RAFEL will be driven by the spent electron beam leaving the soft X-ray FEL, thus providing minimal interference between these two devices. The RAFEL output radiation has the same time structure as the X-ray FEL and the UV pulses are naturally synchronized with the soft X-ray pulses from the TTF FEL. Therefore, it should be possible to achieve synchronization close to the duration of the radiation pulses (200 fs) for pump-probe techniques using either an UV pulse as a pump and soft X-ray pulse as a probe, or vice versa

Vacuum Stability with Tachyonic Boundary Higgs Masses in No-Scale Supersymmetry or Gaugino Mediation

CERN Document Server

Evans, Jason L; Wells, James D

2009-01-01

No-scale supersymmetry or gaugino mediation augmented with large negative Higgs soft masses at the input scale provides a simple solution to the supersymmetric flavor problem while giving rise to a neutralino LSP. However, to obtain a neutralino LSP it is often necessary to have tachyonic input Higgs soft masses that can give rise to charge-and-color-breaking (CCB) minima and unbounded-from-below (UFB) directions in the low energy theory. We investigate the vacuum structure in these theories to determine when such problematic features are present. When the standard electroweak vacuum is only metastable, we compute its lifetime under vacuum tunneling. We find that vacuum metastability leads to severe restrictions on the parameter space for larger $\\tan\\beta \\sim 30$, while for smaller $\\tan\\beta\\sim 10$, only minor restrictions are found. Along the way, we derive an exact bounce solution for tunneling through an inverted parabolic potential.

3m Vacuum Ultraviolet Spectrometer with Optical Multichannel Detector; Espectrometro de ultravioleta de vacio de 3m provisto de sistema de deteccion optical multicanal

Energy Technology Data Exchange (ETDEWEB)

Martin, P; Peraza, C; Blanco, F; Campos, J

1993-07-01

This paper describes the design and the performance of a normal incidence vacuum ultraviolet spectrometer, for the 300-2400 A spectral range. It is provided with a multichannel detection system. The monochromator is original design and it has been built at CIEMAT. It is equipped with a 3 m concave holographic grating with 2400 grooves/mm. The multichannel detector consists of a windowless double microchannel plate / phosphor screen image intensifier, coupled by fiber optic to a 1024 elements self-scanning linear photodiode array. The output from the array is digitized by a 12-bit analog to digital converter and stored in a computer, for its later analysis. The necessary software to store and display data has been developed. (Author) 18 refs.

Contact lens disinfection by ultraviolet light

International Nuclear Information System (INIS)

Dolman, P.J.; Dobrogowski, M.J.

1989-01-01

A 253.7-nm ultraviolet light with an intensity of 1,100 microW/cm2 was tested for its germicidal activity against contact lenses and storage solutions contaminated with various corneal pathogens. The exposure time necessary to reduce a concentration of organisms from 10(6)/ml to less than 10/ml was 30 seconds for Staphylococcus aureus, 60 seconds for Pseudomonas aeruginosa, and 84 seconds for Candida albicans. The time necessary to sterilize a suspension of 10(4)/ml Acanthamoeba polyphaga was less than three minutes with this technique. Four brands of soft contact lenses were exposed to ultraviolet light for over eight hours without changing their appearance, comfort, or refraction

Measurements of Schottky barrier at the low-k SiOC:H/Cu interface using vacuum ultraviolet photoemission spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Guo, X.; Pei, D.; Zheng, H.; Shohet, J. L. [Plasma Processing and Technology Laboratory and Department of Electrical and Computer Engineering, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); King, S. W. [Logic Technology Development, Intel Corporation, Hillsboro, Oregon 97124 (United States); Lin, Y.-H.; Fung, H.-S.; Chen, C.-C. [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China); Nishi, Y. [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States)

2015-12-07

The band alignment between copper interconnects and their low-k interlayer dielectrics is critical to understanding the fundamental mechanisms involved in electrical leakage in low-k/Cu interconnects. In this work, vacuum-ultraviolet (VUV) photoemission spectroscopy is utilized to determine the potential of the Schottky barrier present at low-k a-SiOC:H/Cu interfaces. By examining the photoemission spectra before and after VUV exposure of a low-k a-SiOC:H (k = 3.3) thin film fabricated by plasma-enhanced chemical-vapor deposition on a polished Cu substrate, it was found that photons with energies of 4.9 eV or greater can deplete accumulated charge in a-SiOC:H films, while VUV photons with energies of 4.7 eV or less, did not have this effect. These critical values were identified to relate the electric potential of the interface barrier between the a-SiOC:H and the Cu layers. Using this method, the Schottky barrier at the low-k a-SiOC:H (k = 3.3)/Cu interface was determined to be 4.8 ± 0.1 eV.

Vacuum stability with tachyonic boundary Higgs masses in no-scale supersymmetry or gaugino mediation

International Nuclear Information System (INIS)

Evans, Jason L.; Wells, James D.; Morrissey, David E.

2009-01-01

No-scale supersymmetry or gaugino mediation augmented with large negative Higgs soft masses at the input scale provides a simple solution to the supersymmetric flavor problem while giving rise to a neutralino lightest superpartner particle. However, to obtain a neutralino lightest superpartner particle it is often necessary to have tachyonic input Higgs soft masses that can give rise to charge-and-color-breaking minima and unbounded-from-below directions in the low-energy theory. We investigate the vacuum structure in these theories to determine when such problematic features are present. When the standard electroweak vacuum is only metastable, we compute its lifetime under vacuum tunneling. We find that vacuum metastability leads to severe restrictions on the parameter space for larger tanβ∼30, while for smaller tanβ∼10, only minor restrictions are found. Along the way, we derive an exact bounce solution for tunneling through an inverted parabolic potential.

Electroweak radiative corrections to Higgs production via vector boson fusion using soft-collinear effective theory

International Nuclear Information System (INIS)

Fuhrer, Andreas; Manohar, Aneesh V.; Waalewijn, Wouter J.

2011-01-01

Soft-collinear effective theory (SCET) is applied to compute electroweak radiative corrections to Higgs production via gauge boson fusion, qq→qqH. There are several novel features which make this process an interesting application of SCET: The amplitude is proportional to the Higgs vacuum expectation value, and so is not a gauge singlet amplitude. Standard resummation methods require a gauge singlet operator and do not apply here. The SCET analysis requires operators with both collinear and soft external fields, with the Higgs vacuum expectation value being described by an external soft φ field. There is a scalar soft-collinear transition operator in the SCET Lagrangian which contributes to the scattering amplitude, and is derived here.

Comparison of direct and alternating current vacuum ultraviolet lamps in atmospheric pressure photoionization.

Science.gov (United States)

Vaikkinen, Anu; Haapala, Markus; Kersten, Hendrik; Benter, Thorsten; Kostiainen, Risto; Kauppila, Tiina J

2012-02-07

A direct current induced vacuum ultraviolet (dc-VUV) krypton discharge lamp and an alternating current, radio frequency (rf) induced VUV lamp that are essentially similar to lamps in commercial atmospheric pressure photoionization (APPI) ion sources were compared. The emission distributions along the diameter of the lamp exit window were measured, and they showed that the beam of the rf lamp is much wider than that of the dc lamp. Thus, the rf lamp has larger efficient ionization area, and it also emits more photons than the dc lamp. The ionization efficiencies of the lamps were compared using identical spray geometries with both lamps in microchip APPI mass spectrometry (μAPPI-MS) and desorption atmospheric pressure photoionization-mass spectrometry (DAPPI-MS). A comprehensive view on the ionization was gained by studying six different μAPPI solvent compositions, five DAPPI spray solvents, and completely solvent-free DAPPI. The observed reactant ions for each solvent composition were very similar with both lamps except for toluene, which showed a higher amount of solvent originating oxidation products with the rf lamp than with the dc lamp in μAPPI. Moreover, the same analyte ions were detected with both lamps, and thus, the ionization mechanisms with both lamps are similar. The rf lamp showed a higher ionization efficiency than the dc lamp in all experiments. The difference between the lamp ionization efficiencies was greatest when high ionization energy (IE) solvent compositions (IEs above 10 eV), i.e., hexane, methanol, and methanol/water, (1:1 v:v) were used. The higher ionization efficiency of the rf lamp is likely due to the larger area of high intensity light emission, and the resulting larger efficient ionization area and higher amount of photons emitted. These result in higher solvent reactant ion production, which in turn enables more efficient analyte ion production. © 2012 American Chemical Society

Photocatalytic pretreatment of oily wastewater from the restaurant by a vacuum ultraviolet/TiO2 system

International Nuclear Information System (INIS)

Kang Jianxiong; Lu Lu; Zhan Wei; Li Bo; Li Daosheng; Ren Yongzheng; Liu Dongqi

2011-01-01

The present study aims at investigating the performance of a vacuum ultraviolet (VUV, 185 nm) and TiO 2 oxidation system for the pretreatment of oily wastewater from restaurant. The influence of irradiation time, pH, dissolved oxygen (DO), the dosage of TiO 2 and the initial chemical oxygen demand (COD) concentration on COD removal efficiency was ascertained and optimum process conditions for stable and effective operation were determined. Under the optimum conditions of irradiation 10 min, initial COD 3981 mg/L, TiO 2 150 mg/L, pH 7.0 and flow rate of air 40 L/h, the process of VUV and TiO 2 /VUV achieved removal efficiencies of COD, BOD 5 and oil as 50 ± 3%, 37 ± 2%, 86 ± 3%, and 63 ± 3%, 43 ± 2%, 70 ± 3%, respectively. The biodegradability factor f B of the wastewater was determined as 1.56 which indicated that the VUV/TiO 2 process improved the biodegradability of the oily wastewater significantly. Results clearly indicate that VUV/TiO 2 photolysis tends to destruct parts of COD, BOD 5 , and ammonia, as well as enhances the biodegradability of the oily wastewater simultaneously. Thus, this technique could be used as a pretreatment step for conventional biological treatment of oily wastewater.

Predominance of membrane damage in yeast cells in suspension with monochromatic 163-nm vacuum ultraviolet light

International Nuclear Information System (INIS)

Ito, T.; Ito, A.

1980-01-01

Effects of monochromatic 163-nm ultraviolet light on aqueous suspensions of yeast cells were studied under N 2 and O 2 bubbling conditions. This is a continuation of previous attempts at using a bromine resonance lamp immersed in cell suspension as a means of treating cells with water radicals (163-nm photons decompose water molecules into H atoms and OH' radicals). We found that inactivation occurred only under O 2 bubbling. Genetic changes were induced, but this was attributed to the effects of far-uv components which contaminate the emission. A characteristic feature of the vacuum uv inactivation was a decrease in survival when cells were held in liquid after irradiation. The presence of p-nitrosodimethylaniline (a known OH' scavenger) during irradiation prevented the O 2 -dependent enhancement of inactivation. Cells irradiated under N 2 bubbling showed no such enhancement. Thus, the fast access of oxygen is a necessary condition for fixing initial damage. Initial damage of this type seems to be amplified during subsequent incubation, causing further killing. Cells irradiated under N 2 bubbling were not, however, free of damage, since dye permeability across the cell membrane of irradiated samples increased markedly with both N 2 and O 2 as tested by photodynamic induction of genetic changes using normally unpenetrable dye as a sensitizer. Spectrophotometric evidence for the presence of toluidine blue in the irradiated cells are also presented

Photocatalytic pretreatment of oily wastewater from the restaurant by a vacuum ultraviolet/TiO2 system.

Science.gov (United States)

Kang, Jian-xiong; Lu, Lu; Zhan, Wei; Li, Bo; Li, Dao-sheng; Ren, Yong-zheng; Liu, Dong-qi

2011-02-15

The present study aims at investigating the performance of a vacuum ultraviolet (VUV, 185 nm) and TiO(2) oxidation system for the pretreatment of oily wastewater from restaurant. The influence of irradiation time, pH, dissolved oxygen (DO), the dosage of TiO(2) and the initial chemical oxygen demand (COD) concentration on COD removal efficiency was ascertained and optimum process conditions for stable and effective operation were determined. Under the optimum conditions of irradiation 10 min, initial COD 3981 mg/L, TiO(2) 150 mg/L, pH 7.0 and flow rate of air 40 L/h, the process of VUV and TiO(2)/VUV achieved removal efficiencies of COD, BOD(5) and oil as 50±3%, 37±2%, 86±3%, and 63±3%, 43±2%, 70±3%, respectively. The biodegradability factor f(B) of the wastewater was determined as 1.56 which indicated that the VUV/TiO(2) process improved the biodegradability of the oily wastewater significantly. Results clearly indicate that VUV/TiO(2) photolysis tends to destruct parts of COD, BOD(5), and ammonia, as well as enhances the biodegradability of the oily wastewater simultaneously. Thus, this technique could be used as a pretreatment step for conventional biological treatment of oily wastewater. Copyright © 2010 Elsevier B.V. All rights reserved.

On the minimal vacuum definition for spin 1 massive fields in Robertson-Walker universes

International Nuclear Information System (INIS)

Castagnino, M.; Laciana, C.; Chimento, L.

1986-01-01

A definition of quantum vacuum is introduced for spin 1, massive, neutral fields, in spatially flat Robertson-Walker universes. For this definition all relevant observables turn out to be devoid of ultraviolet divergencies. (author)

A system for the study of molecular contamination. [experimental vacuum chambers

Science.gov (United States)

Dillow, C. F.; Allen, T. H.; Linford, R. M. F.; Richmond, R. G.

1975-01-01

An experimental vacuum chambers was designed and fabricated to provide a wide range of experimental capability. This work chamber assembly (WCA) was conceived to establish the proof-of-principle of various techniques for studying the kinetics of contaminants and their effects. It incorporates the capability for depositing both optical and contaminant films on temperature-controlled samples, and for in-situ measurements of the vacuum ultraviolet reflectance. Ellipsometer optics are mounted on the chamber for film thickness determinations, and other features include access ports for radiation sources and instrumentation.

Ultrafast soft X-ray photoelectron spectroscopy at liquid water microjets.

Science.gov (United States)

Faubel, M; Siefermann, K R; Liu, Y; Abel, B

2012-01-17

Since the pioneering work of Kai Siegbahn, electron spectroscopy for chemical analysis (ESCA) has been developed into an indispensable analytical technique for surface science. The value of this powerful method of photoelectron spectroscopy (PES, also termed photoemission spectroscopy) and Siegbahn's contributions were recognized in the 1981 Nobel Prize in Physics. The need for high vacuum, however, originally prohibited PES of volatile liquids, and only allowed for investigation of low-vapor-pressure molecules attached to a surface (or close to a surface) or liquid films of low volatility. Only with the invention of liquid beams of volatile liquids compatible with high-vacuum conditions was PES from liquid surfaces under vacuum made feasible. Because of the ubiquity of water interfaces in nature, the liquid water-vacuum interface became a most attractive research topic, particularly over the past 10 years. PES studies of these important aqueous interfaces remained significantly challenging because of the need to develop high-pressure PES methods. For decades, ESCA or PES (termed XPS, for X-ray photoelectron spectroscopy, in the case of soft X-ray photons) was restricted to conventional laboratory X-ray sources or beamlines in synchrotron facilities. This approach enabled frequency domain measurements, but with poor time resolution. Indirect access to time-resolved processes in the condensed phase was only achieved if line-widths could be analyzed or if processes could be related to a fast clock, that is, reference processes that are fast enough and are also well understood in the condensed phase. Just recently, the emergence of high harmonic light sources, providing short-wavelength radiation in ultrashort light pulses, added the dimension of time to the classical ESCA or XPS technique and opened the door to (soft) X-ray photoelectron spectroscopy with ultrahigh time resolution. The combination of high harmonic light sources (providing radiation with laserlike

Absolute atomic oxygen and nitrogen densities in radio-frequency driven atmospheric pressure cold plasmas: Synchrotron vacuum ultra-violet high-resolution Fourier-transform absorption measurements

International Nuclear Information System (INIS)

Niemi, K.; O'Connell, D.; Gans, T.; Oliveira, N. de; Joyeux, D.; Nahon, L.; Booth, J. P.

2013-01-01

Reactive atomic species play a key role in emerging cold atmospheric pressure plasma applications, in particular, in plasma medicine. Absolute densities of atomic oxygen and atomic nitrogen were measured in a radio-frequency driven non-equilibrium plasma operated at atmospheric pressure using vacuum ultra-violet (VUV) absorption spectroscopy. The experiment was conducted on the DESIRS synchrotron beamline using a unique VUV Fourier-transform spectrometer. Measurements were carried out in plasmas operated in helium with air-like N 2 /O 2 (4:1) admixtures. A maximum in the O-atom concentration of (9.1 ± 0.7)×10 20 m −3 was found at admixtures of 0.35 vol. %, while the N-atom concentration exhibits a maximum of (5.7 ± 0.4)×10 19 m −3 at 0.1 vol. %

Stellar extreme ultraviolet astronomy

International Nuclear Information System (INIS)

Cash, W.C. Jr.

1978-01-01

The design, calibration, and launch of a rocket-borne imaging telescope for extreme ultraviolet astronomy are described. The telescope, which employed diamond-turned grazing incidence optics and a ranicon detector, was launched November 19, 1976, from the White Sands Missile Range. The telescope performed well and returned data on several potential stellar sources of extreme ultraviolet radiation. Upper limits ten to twenty times more sensitive than previously available were obtained for the extreme ultraviolet flux from the white dwarf Sirius B. These limits fall a factor of seven below the flux predicted for the star and demonstrate that the temperature of Sirius B is not 32,000 K as previously measured, but is below 30,000 K. The new upper limits also rule out the photosphere of the white dwarf as the source of the recently reported soft x-rays from Sirius. Two other white dwarf stars, Feige 24 and G191-B2B, were observed. Upper limits on the flux at 300 A were interpreted as lower limits on the interstellar hydrogen column densities to these stars. The lower limits indicate interstellar hydrogen densitites of greater than .02 cm -3 . Four nearby stars (Sirius, Procyon, Capella, and Mirzam) were observed in a search for intense low temperature coronae or extended chromospheres. No extreme ultraviolet radiation from these stars was detected, and upper limits to their coronal emisson measures are derived

Actinide science with soft x-ray synchrotron radiation

International Nuclear Information System (INIS)

Shuh, D.

2002-01-01

Several workshops, some dating back more than fifteen years, recognised both the potential scientific impact and opportunities that would be made available by the capability to investigate actinide materials in the vacuum ultraviolet (VUV)/soft X-ray region of the synchrotron radiation (SR) spectrum. This spectral region revolutionized the approach to surface materials chemistry and physics nearly two decades ego. The actinide science community was unable to capitalize on these SR methodologies for the study of actinide materials until recently because of radiological safety concerns. ,The Advanced Light Source (ALS) at LBNL is a third-generation light source providing state-of-the-art performance in the VUV/soft X-ray region. Along with corresponding improvements in detector and vacuum technology, the ALS has rendered experiments with small amounts of actinide materials possible. In particular, it has been the emergence and development of micro-spectroscopic techniques that have enabled investigations of actinide materials at the ALS. The primary methods for the experimental investigation of actinide materials in the VUV/soft X-ray region are the complementary photoelectron spectroscopies, near-edge X-ray absorption fine structure (NEXAFS) and X-ray emission spectroscopy (XES) techniques. Resonant photo-emission is capable of resolving the 5f electron contributions to actinide bonding and can be used to characterise the electronic structure of actinide materials. This technique is clearly a most important methodology afforded by the tunable SR source. Core level and valence band photoelectron spectroscopies are valuable for the characterisation of the electronic properties of actinide materials, as well as for general analytical purposes. High-resolution core-level photo-emission and resonant photo-emission measurements from the a (monoclinic) and δ (FCC) allotropic phases of plutonium metal have been collected on beam line 7.0 at the ALS and the spectra show

Using the longitudinal space charge instability for generation of vacuum ultraviolet and x-ray radiation

Directory of Open Access Journals (Sweden)

E. A. Schneidmiller

2010-11-01

Full Text Available Longitudinal space charge (LSC driven microbunching instability in electron beam formation systems of x-ray free-electron lasers (FELs is a recently discovered effect hampering beam instrumentation and FEL operation. The instability was observed in different facilities in infrared and visible wavelength ranges. In this paper we propose to use such an instability for generation of vacuum ultraviolet (VUV and x-ray radiation. A typical longitudinal space charge amplifier (LSCA consists of few amplification cascades (drift space plus chicane with a short undulator behind the last cascade. If the amplifier starts up from the shot noise, the amplified density modulation has a wide band, on the order of unity. The bandwidth of the radiation within the central cone is given by an inverse number of undulator periods. A wavelength compression could be an attractive option for LSCA since the process is broadband, and a high compression stability is not required. LSCA can be used as a cheap addition to the existing or planned short-wavelength FELs. In particular, it can produce the second color for a pump-probe experiment. It is also possible to generate attosecond pulses in the VUV and x-ray regimes. Some user experiments can profit from a relatively large bandwidth of the radiation, and this is easy to obtain in the LSCA scheme. Finally, since the amplification mechanism is broadband and robust, LSCA can be an interesting alternative to the self-amplified spontaneous emission free-electron laser (SASE FEL in the case of using laser-plasma accelerators as drivers of light sources.

Clinical application of vacuum bag immobilization of the trunk in malignant tumor patients

International Nuclear Information System (INIS)

Su Jianxin; Wu Yuqi; Huang Jun; Lin Chengguang; Liu Hui; Huang Xiaoyan

2005-01-01

Objective: To evaluate the clinical application of vacuum bag immobilization of thorax and pelvis for patients with malignant tumors. Methods: Of 714 patients (fields) chosen randomly, 582(fields) were immobilized with vacuum bag, while the other 132 (fields) used only sand bags, tapes, and other simple immobilizing devices. The field movements were measured and compared before and after the setup, along with 56 patients immobilized twice with vacuum bag. Results: The variance of movement before and after the setup was 6.7% for patients with vacuum bag , while that was 26.5% for patients without the vacuum bag. It was even 32.1% for patients immobilized twice with vacuum bag. Conclusions: The variance of movement decreases significantly with vacuum bag immobilization. It should be used as frequently as possible. As the variance of movement rises obviously when vacuum bag is used twice, the semi-soft vacuum bag should be prepared afresh and checked under the simulator before the second use. (authors)

Soft X-ray focusing Telescope aboard AstroSat

DEFF Research Database (Denmark)

Singh, K. P.; Dewangan, G. C.; Chandra, S.

2017-01-01

The Soft X-ray focusing Telescope (SXT) is a moderateresolution X-ray imaging spectrometer supplementing the ultraviolet and hard X-ray payloads for broadband studies of cosmic sources with AstroSat. Well suited for observing bright X-ray sources, SXT observations of nearby active galactic nuclei...

The Normal-incidence Vacuum-ultraviolet Spectrometer for the TJ-II and First Experimental Results

Energy Technology Data Exchange (ETDEWEB)

McCarthy, K.J.; Zurro, B.; Baciero, A.

2002-07-01

A normal-incidence spectrometer, operating in the extreme-ultraviolet and ultraviolet wavelength regions, has been commissioned for the TJ-II stellarator. The instrument has been custom built by McPherson, Chelmsford, MA, and has several unique features and accessories that are described here. The instrument and CCD detector has been tested and calibrated, and its performance evaluated, using spectral lines from glow discharges and a RF excited flow lamp. Finally, the first spectra collected with the instrument of TJ-II plasmas are presented and a preliminary estimation of an oxygen ion temperature is made. (Author) 23 refs.

The Normal-incidence Vacuum-ultraviolet Spectrometer for the TJ-II and First Experimental Results

International Nuclear Information System (INIS)

McCarthy, K. J.; Zurro, B.; Baciero, A.

2002-01-01

A normal-incidence spectrometer, operating in the extreme-ultraviolet and ultraviolet wavelength regions, has been commissioned for the TJ-II stellarator. The instrument has been custom built by McPherson, Chelmsford, MA, and has several unique features and accessories that are described here. The instrument and CCD detector has been tested and calibrated, and its performance evaluated, using spectral lines from glow discharges and a RF excited flow lamp. Finally, the first spectra collected with the instrument of TJ-II plasmas are presented and a preliminary estimation of an oxygen ion temperature is made. (Author) 23 refs

Numerical and Experimental Investigations of the Effect of PVD and Vacuum Pressure on the Degree of Saturation

Directory of Open Access Journals (Sweden)

Ala Nasir Aljorany

2018-12-01

Full Text Available Soft clays are generally characterized by low shear strength, low permeability and high compressibility. An effective method to accelerate consolidation of such soils is to use vertical drains along with vacuum preloading to encourage radial flow of water. In this research numerical modeling of prefabricated vertical drains with vacuum pressure was done to investigate the effect of using vertical drains together with vacuum pressure on the degree of saturation of fully and saturated-unsaturated soft soils. Laboratory experiments were conducted by using a specially-designed large consolidometer cell where a central drain was installed and vacuum pressure was applied. All tests were conducted with a vacuum pressure of 40 kPa applied for a period of 30 days where a degree of soil consolidation of 90% was attained. At the end of the test period fifteen samples were taken from different locations distributed along the depth and radially to measure the water content. Consolidation settlements were recorded with time for all tests. The results showed that using vacuum pressure with vertical drains is a very effective method to accelerate consolidation of soils. As the thickness of unsaturated top layer increases, the settlement of soil surface decreases. The water content decreased after 30 days of application of the vacuum pressure.

Calibration of windowless photodiode for extreme ultraviolet pulse energy measurement

Czech Academy of Sciences Publication Activity Database

Koláček, Karel; Schmidt, Jiří; Štraus, Jaroslav; Frolov, Oleksandr

2015-01-01

Roč. 54, č. 35 (2015), s. 10454-10459 ISSN 1559-128X R&D Projects: GA MŠk(CZ) LG13029 Institutional support: RVO:61389021 Keywords : Photodetectors * Soft-X-ray * Extreme ultraviolet * Detection * Filters * Metrology Subject RIV: BH - Optics , Masers, Lasers Impact factor: 1.598, year: 2015

Miniature CCD X-Ray Imaging Camera Technology Final Report CRADA No. TC-773-94

Energy Technology Data Exchange (ETDEWEB)

Conder, A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Mummolo, F. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2017-10-19

The goal of the project was to develop a compact, large active area, high spatial resolution, high dynamic range, charge-coupled device (CCD) camera to replace film for digital imaging of visible light, ultraviolet radiation, and soft to penetrating X-rays. The camera head and controller needed to be capable of operation within a vacuum environment and small enough to be fielded within the small vacuum target chambers at LLNL.

Submicron, soft x-ray fluorescence imaging

International Nuclear Information System (INIS)

La Fontaine, B.; MacDowell, A.A.; Tan, Z.; White, D.L.; Taylor, G.N.; Wood, O.R. II; Bjorkholm, J.E.; Tennant, D.M.; Hulbert, S.L.

1995-01-01

Submicron fluorescence imaging of soft x-ray aerial images, using a high resolution fluorescent crystal is reported. Features as small as 0.1 μm were observed using a commercially available single-crystal phosphor, STI-F10G (Star Tech Instruments Inc. P. O. Box 2536, Danbury, CT 06813-2536), excited with 139 A light. Its quantum efficiency was estimated to be 5--10 times that of sodium salicylate and to be constant over a broad spectral range from 30 to 400 A. A comparison with a terbium-activated yttrium orthosilicate fluorescent crystal is also presented. Several applications, such as the characterization of the aerial images produced by deep ultraviolet or extreme ultraviolet lithographic exposure tools, are envisaged

Photoionization of excited states of neon-like Mg III

Indian Academy of Sciences (India)

plasma were used in vacuum ultra-violet lasing [4] and also soft X-ray laser simulation for ... et al [11], in terms of discrete R-matrix basis functions of adequate LS ... inside a sphere of radius a, containing the charge distribution of the residual ...

Scalable Sub-micron Patterning of Organic Materials Toward High Density Soft Electronics.

Science.gov (United States)

Kim, Jaekyun; Kim, Myung-Gil; Kim, Jaehyun; Jo, Sangho; Kang, Jingu; Jo, Jeong-Wan; Lee, Woobin; Hwang, Chahwan; Moon, Juhyuk; Yang, Lin; Kim, Yun-Hi; Noh, Yong-Young; Jaung, Jae Yun; Kim, Yong-Hoon; Park, Sung Kyu

2015-09-28

The success of silicon based high density integrated circuits ignited explosive expansion of microelectronics. Although the inorganic semiconductors have shown superior carrier mobilities for conventional high speed switching devices, the emergence of unconventional applications, such as flexible electronics, highly sensitive photosensors, large area sensor array, and tailored optoelectronics, brought intensive research on next generation electronic materials. The rationally designed multifunctional soft electronic materials, organic and carbon-based semiconductors, are demonstrated with low-cost solution process, exceptional mechanical stability, and on-demand optoelectronic properties. Unfortunately, the industrial implementation of the soft electronic materials has been hindered due to lack of scalable fine-patterning methods. In this report, we demonstrated facile general route for high throughput sub-micron patterning of soft materials, using spatially selective deep-ultraviolet irradiation. For organic and carbon-based materials, the highly energetic photons (e.g. deep-ultraviolet rays) enable direct photo-conversion from conducting/semiconducting to insulating state through molecular dissociation and disordering with spatial resolution down to a sub-μm-scale. The successful demonstration of organic semiconductor circuitry promise our result proliferate industrial adoption of soft materials for next generation electronics.

Classical ultraviolet photoelectron spectroscopy of polymers

International Nuclear Information System (INIS)

Salaneck, W.R.

2009-01-01

Although X-ray photoelectron spectroscopy of polymers was well established by Clark and coworkers in the 1970s, ultraviolet photoelectron spectroscopy of polymer films, was developed later. Previous to the 1970s, the first attempts to use ultraviolet light on polymer films took the form of appearance potential (valence band edge) measurements. Only some years later could the full valence band region of thin polymer films, including insulating polymers, semiconducting polymers and electrically conducting polymers. The development of what might be termed 'classical ultraviolet photoelectron spectroscopy' of polymer films may be loosely based upon a variety of issues, including adapting thin polymer film technology to ultra high vacuum studies, the widespread use of helium resonance lamps for studies of solid surfaces, the combined advent of practical and sufficient theoretical-computational methods. The advent of, and the use of, easily available synchrotron radiation for multi-photon spectroscopies, nominally in the area of the near UV, is not included in the term 'classical'. At the same time, electrically conducting polymers were discovered, leading to applications of the corresponding semiconducting polymers, which added technologically driven emphasis to this development of ultraviolet photoelectron spectroscopy for polymer materials. This paper traces a limited number of highlights in the evolution of ultraviolet photoelectron spectroscopy of polymers, from the 1970s through to 2008. Also, since this issue is dedicated to Prof. Kazuhiko Seki, who has been a friend and competitor for over two decades, the author relies on some of Prof. Seki's earlier research, unpublished, on who-did-what-first. Prof. Seki's own contributions to the field, however, are discussed in other articles in this issue.

Vacuum assisted closure in vascular surgery.

Science.gov (United States)

Beno, M; Martin, J; Sager, P

2011-01-01

Vacuum assisted closure (VAC-therapy) is a well established method in nearly all surgical disciplines. The aim is to present the efficiency of vacuum assisted closure in the treatment of acute and chronic wounds in patients admitted in the department of vascular surgery. Within the year 2008 there were 59 patients (44 men, 15 women) treated with VAC therapy in our Department of Vascular surgery (Landshut, Germany). VAC was used 22x (37.28 %) in therapy of ulcus cruris (venous, arterial, mixed genesis), 15x (25.42%) in patients with diabetic foot syndrome, 12x (20.33%) in secondary healing wounds and infected wounds, 5x (8.47%) in wounds after several injuries and soft skin tissue infections and 5x (8.47%) in wound infections connected with vascular graft infections after vascular revascularization. VAC therapy seems to be very effective in the management of patients with venous ulcers, especially after a proper surgical treatment (100%), patients with soft skin tissue infections (100%) and secondary healing wounds (100%) especially in combination with MESH-Grafting. In patients with diabetic foot syndrome (80%) and peripheral arterial occlusive disease (72.7%), an evaluation of peripheral blood perfusion and revascularization prior to VAC therapy is often necessary. Although VAC was used 5x in the therapy of infected vascular grafts, successful preservation of infected graft material was observed in only one case (infection of PTFE femoro-popliteal bypass graft). Vacuum assisted closure in vascular surgery proved to be simple and efficient method in therapy of acute and chronic wounds. The efficiency of VAC systems in therapy of infected graft material after revascularization needs further studies (Tab. 3, Ref. 10).

The absolute photoionization cross sections of helium, neon, argon and krypton in the extreme vacuum ultraviolet region of the spectrum

International Nuclear Information System (INIS)

West, J.B.; Marr, G.V.

1976-01-01

An experiment has been set up at the Daresbury Synchrotron Radiation Facility to make absolute absorption cross section measurements over a wide range of photon energies. New data are reported for helium, neon, argon and krypton over the range 340 to 40 A which are believed to be reliable to +- 5%. A critical evaluation of published cross section data has been carried out to produce best value data from the ionization thresholds throughout the vacuum ultraviolet and x-ray region. Agreement with theoretical calculations on helium is demonstrated to be within +- 2 to 3% from threshold down to the double ionization threshold at 79 eV. Comparison with recent calculations of photoionization cross sections has shown that the effect of electron correlations is significant for the heavier inert gases. Contrary to previous claims, the position of the M shell maximum in krypton is located at 184 +- 10 eV in good agreement with r.p.a.e. calculations. Oscillator strength sum rules have been examined and their moments calculated. Discrepancies developing towards the heavier inert gases suggests a decrease in polarizabilities and other atomic factors from those predicted by Hartree-Fock calculations. (author)

System performance modeling of extreme ultraviolet lithographic thermal issues

International Nuclear Information System (INIS)

Spence, P. A.; Gianoulakis, S. E.; Moen, C. D.; Kanouff, M. P.; Fisher, A.; Ray-Chaudhuri, A. K.

1999-01-01

Numerical simulation is used in the development of an extreme ultraviolet lithography Engineering Test Stand. Extensive modeling was applied to predict the impact of thermal loads on key lithographic parameters such as image placement error, focal shift, and loss of CD control. We show that thermal issues can be effectively managed to ensure that their impact on lithographic performance is maintained within design error budgets. (c) 1999 American Vacuum Society

Evaluation of Vacuum Assisted Closure Therapy for Soft Tissue Injury in Open Musculoskeletal Trauma.

Science.gov (United States)

Raj, Manish; Gill, S P S; Sheopaltan, Sunil Kumar; Singh, Pulkesh; Dinesh; Sigh, Jasveer; Rastogi, Prateek; Mishra, L N

2016-04-01

The application of controlled levels of negative or sub atmospheric pressure for a prolonged period of time on a wound had shown to accelerate removal of excess fluid and promote hyperaemia, which eventually promote wound healing. The study was conducted with the aim to evaluate the effectiveness of Vacuum Assisted Closure (VAC) therapy for soft tissue injury in open musculoskeletal trauma. Twenty cases of complex musculoskeletal wound involving different parts of body were included in this progressive randomized study. In patients, aggressive debridement was done before the application of VAC therapy. Controlled negative pressure was uniformly applied to the wound. Dressings were changed after every 4 to 5 days. The evaluation of results included healing rate of the wound, eradication of infection, complication rate, and number of secondary procedures. VAC therapy over the wound was administered for an average of 20.4 days ±6.72 days (range 14 to 42 days). There was decrease in wound size attained by VAC therapy ranged from 2.6 to 24.4cm(2), with an average reduction of 10.55 cm(2). Three wounds were infected at the start of VAC therapy. However, all patients were cleared of bacterial infection by the end of VAC therapy. VAC therapy using negative pressure promote Wound healing by increasing local capillary perfusion and increased rate of granulation tissue formation, decreases the duration of wound healing and requires fewer painful dressing change.

Improved Resolution of Hydrocarbon Structures and Constitutional Isomers in Complex Mixtures Using Gas Chromatography-Vacuum Ultraviolet-Mass Spectrometry

Energy Technology Data Exchange (ETDEWEB)

Isaacman, Gabriel [Univ. of California, Berkeley, CA (United States); Wilson, Kevin R. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chan, Arthur W. H. [Univ. of California, Berkeley, CA (United States); Worton, David R. [Univ. of California, Berkeley, CA (United States). Aerosol Dynamics Inc., Berkeley, CA (United States); Kimmel, Joel R. [Aerodyne Research, Inc., Billerica, MA (United States); Univ. of Colorado, Boulder, CO (United States). Tofwerk AG, Thun (Switzerland); Nah, Theodora [Univ. of California, Berkeley, CA (United States); Hohaus, Thorsten [Aerodyne Research, Inc., Billerica, MA (United States); Gonin, Marc [Tofwerk AG, Thun (Switzerland); Kroll, Jesse H. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Worsnop, Douglas R. [Aerodyne Research, Inc., Billerica, MA (United States); Goldstein, Allen H. [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

2012-01-30

Understanding the composition of complex hydrocarbon mixtures is important for environmental studies in a variety of fields, but many prevalent compounds cannot be confidently identified using traditional gas chromatography/mass spectrometry (GC/MS) techniques. In this study, we use vacuum-ultraviolet (VUV) ionization to elucidate the structures of a traditionally “unresolved complex mixture” by separating components by GC retention time, t_R, and mass-to-charge ratio, m/z, which are used to determine carbon number, N_C, and the number of rings and double bonds, N_DBE. Constitutional isomers are resolved on the basis of t_R, enabling the most complete quantitative analysis to date of structural isomers in an environmentally relevant hydrocarbon mixture. Unknown compounds are classified in this work by carbon number, degree of saturation, presence of rings, and degree of branching, providing structural constraints. The capabilities of this analysis are explored using diesel fuel, in which constitutional isomer distribution patterns are shown to be reproducible between carbon numbers and follow predictable rules. Nearly half of the aliphatic hydrocarbon mass is shown to be branched, suggesting branching is more important in diesel fuel than previously shown. Lastly, the classification of unknown hydrocarbons and the resolution of constitutional isomers significantly improves resolution capabilities for any complex hydrocarbon mixture.

Spectral tailoring of nanoscale EUV and soft x-ray multilayer optics

NARCIS (Netherlands)

Huang, Qiushi; Medvedev, Viacheslav; van de Kruijs, Robbert Wilhelmus Elisabeth; Yakshin, Andrey; Louis, Eric; Bijkerk, Frederik

2017-01-01

Extreme ultraviolet and soft X-ray (XUV) multilayer optics have experienced significant development over the past few years, particularly on controlling the spectral characteristics of light for advanced applications like EUV photolithography, space observation, and accelerator- or lab-based XUV

Electron temperature and density relaxations during internal disruptions in TFR Tokamak plasmas

International Nuclear Information System (INIS)

Enriques, L.; Sand, F.

1977-01-01

Several diagnostics (soft X-ray, Thompson scattering, high frequency waves, and vacuum ultraviolet spectroscopy) have been used on TFR Tokamak plasmas in order to show that the soft X-ray relaxations are mainly due to electron temperature relaxations, with only small variations of the electron density. Values of ΔTsub(eo)/Tsub(eo) up to 17% and of Δnsub(eo)/nsub(eo) of a few % or less have been measured. (author)

Electron temperature and density relaxations during internal disruptions in TFR Tokamak plasmas

International Nuclear Information System (INIS)

1976-07-01

Several diagnostics (soft X-ray, Thomson scattering, high frequency waves, and vacuum ultraviolet spectroscopy) have been used on TFR Tokamak plasmas in order to show that the soft X-ray relaxations are mainly due to electron temperature relaxations, with only small variations of the electron density. Values of ΔTsub(e0)/Tsub(e0) up to 17% and of Δnsub(e0)/nsub(e0) of a few % or less have been measured

A straightforward method for Vacuum-Ultraviolet flux measurements: The case of the hydrogen discharge lamp and implications for solid-phase actinometry

International Nuclear Information System (INIS)

Fulvio, D.; Brieva, A. C.; Jäger, C.; Cuylle, S. H.; Linnartz, H.; Henning, T.

2014-01-01

Vacuum-Ultraviolet (VUV) radiation is responsible for the photo-processing of simple and complex molecules in several terrestrial and extraterrestrial environments. In the laboratory such radiation is commonly simulated by inexpensive and easy-to-use microwave-powered hydrogen discharge lamps. However, VUV flux measurements are not trivial and the methods/devices typically used for this purpose, mainly actinometry and calibrated VUV silicon photodiodes, are not very accurate or expensive and lack of general suitability to experimental setups. Here, we present a straightforward method for measuring the VUV photon flux based on the photoelectric effect and using a gold photodetector. This method is easily applicable to most experimental setups, bypasses the major problems of the other methods, and provides reliable flux measurements. As a case study, the method is applied to a microwave-powered hydrogen discharge lamp. In addition, the comparison of these flux measurements to those obtained by O 2 actinometry experiments allow us to estimate the quantum yield (QY) values QY 122  = 0.44 ± 0.16 and QY 160  = 0.87 ± 0.30 for solid-phase O 2 actinometry.

Versatile high-repetition-rate phase-locked chopper system for fast timing experiments in the vacuum ultraviolet and x-ray spectral region

Energy Technology Data Exchange (ETDEWEB)

Plogmaker, Stefan; Johansson, Erik M. J.; Rensmo, Haakan; Feifel, Raimund; Siegbahn, Hans [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Linusson, Per [Department of Physics, Stockholm University, AlbaNova University Center, SE-106 91 Stockholm (Sweden); Eland, John H. D. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Department of Chemistry, Physical and Theoretical Chemistry Laboratory, Oxford University, South Parks Road, Oxford OX1 3QZ (United Kingdom); Baker, Neville [Department of Chemistry, Physical and Theoretical Chemistry Laboratory, Oxford University, South Parks Road, Oxford OX1 3QZ (United Kingdom)

2012-01-15

A novel light chopper system for fast timing experiments in the vacuum-ultraviolet (VUV) and x-ray spectral region has been developed. It can be phase-locked and synchronized with a synchrotron radiation storage ring, accommodating repetition rates in the range of {approx}8 to {approx}120 kHz by choosing different sets of apertures and subharmonics of the ring frequency (MHz range). Also the opening time of the system can be varied from some nanoseconds to several microseconds to meet the needs of a broad range of applications. Adjusting these parameters, the device can be used either for the generation of single light pulses or pulse packages from a microwave driven, continuous He gas discharge lamp or from storage rings which are otherwise often considered as quasi-continuous light sources. This chopper can be utilized for many different kinds of experiments enabling, for example, unambiguous time-of-flight (TOF) multi-electron coincidence studies of atoms and molecules excited by a single light pulse as well as time-resolved visible laser pump x-ray probe electron spectroscopy of condensed matter in the valence and core level region.

A straightforward method for Vacuum-Ultraviolet flux measurements: The case of the hydrogen discharge lamp and implications for solid-phase actinometry

Energy Technology Data Exchange (ETDEWEB)

Fulvio, D., E-mail: daniele.fulvio@uni-jena.de, E-mail: dfu@oact.inaf.it; Brieva, A. C.; Jäger, C. [Laboratory Astrophysics Group of the Max Planck Institute for Astronomy at the Friedrich Schiller University Jena, Institute of Solid State Physics, Helmholtzweg 3, D-07743 Jena (Germany); Cuylle, S. H.; Linnartz, H. [Raymond and Beverly Sackler Laboratory for Astrophysics, Leiden Observatory, Leiden University, P.O. box 9513, 2300 RA Leiden (Netherlands); Henning, T. [Max Planck Institute for Astronomy, Königstuhl 17, D-69117 Heidelberg (Germany)

2014-07-07

Vacuum-Ultraviolet (VUV) radiation is responsible for the photo-processing of simple and complex molecules in several terrestrial and extraterrestrial environments. In the laboratory such radiation is commonly simulated by inexpensive and easy-to-use microwave-powered hydrogen discharge lamps. However, VUV flux measurements are not trivial and the methods/devices typically used for this purpose, mainly actinometry and calibrated VUV silicon photodiodes, are not very accurate or expensive and lack of general suitability to experimental setups. Here, we present a straightforward method for measuring the VUV photon flux based on the photoelectric effect and using a gold photodetector. This method is easily applicable to most experimental setups, bypasses the major problems of the other methods, and provides reliable flux measurements. As a case study, the method is applied to a microwave-powered hydrogen discharge lamp. In addition, the comparison of these flux measurements to those obtained by O{sub 2} actinometry experiments allow us to estimate the quantum yield (QY) values QY{sub 122} = 0.44 ± 0.16 and QY{sub 160} = 0.87 ± 0.30 for solid-phase O{sub 2} actinometry.

Accelerated simulation of near-Earth-orbit polymer degradation

Science.gov (United States)

Laue, Eric

1992-01-01

There is a need to simulate the near-Earth-orbit environmental conditions, and it is useful to be able to monitor the changes in physical properties of spacecraft materials. Two different methods for simulating the vacuum-ultraviolet (VUV) and soft X-ray near-Earth-orbit flux are presented. Also, methods for monitoring the changes in optical ultraviolet transmission and mass loss are presented. The results of exposures to VUV photons and charged particles on these materials are discussed.

The confining string from the soft dilaton theorem

International Nuclear Information System (INIS)

Alvarez, Enrique; Gomez, Cesar

2000-01-01

A candidate for the confining string of gauge theories is constructed via a representation of the ultraviolet divergences of quantum field theory by a closed string dilaton insertion, computed through the soft dilaton theorem. The resulting (critical) confining string is conformally invariant, singles out naturally d=4 dimensions, and can not be used to represent theories with Landau poles

The Sandia laser plasma extreme ultraviolet and soft x-ray (XUV) light source

International Nuclear Information System (INIS)

Tooman, T.P.

1986-01-01

Laser produced plasmas have been shown to be extremely bright sources of extreme ultraviolet and soft x-ray (XUV) radiation; however, certain practical difficulties have hindered the development of this source as a routinely usable laboratory device. To explore solutions to these difficulties, Sandia has constructed an XUV laser plasma source (LASPS) with the intention of developing an instrument that can be used for experiments requiring intense XUV radiation from 50-300 eV. The driving laser for this source is a KrF excimer with a wavelength of 248 nm, divergence of 200 μrad, pulse width of 23 ns at 20 Hz and typical pulse energy of 500 mJ which allows for good energy coupling to the plasma at moderate (10/sup 12/ W cm/sup 2/) power densities. This source has been pulsed approximately 2 x 10/sup 5/ times, demonstrating good tolerance to plasma debris. The source radiates from the visible to well above 1000 eV, however, to date attention has been concentrated on the 50-300 eV region. In this paper, spectral data and plasma images for both stainless steel and gold targets are presented with the gold target yielding a 200 μm plasma and reradiating 3.9% of the pump energy into 15-73 eV band, a flux of 1.22 x 10/sup 13/ photons/pulse/eV into 2π sr. Further efforts will expand these measurements to rare earth targets and to higher spectral energies. A special high throughput wide angle XUV (50-300 eV) monochromator and associated optics is being concurrently developed to collect the plasma radiation, perform energy dispersion and focus the radiation onto the experimental area

Molecular density modulation type ultrahigh vacuum gauge

International Nuclear Information System (INIS)

Horikoshi, Gen-ichi; Komada, Kazutaka; Mizuno, Hajime

1978-01-01

When pressure is measured in ultrahigh vacuum region, with an ionization gauge one of the causes producing the measuring limit is its dark current due to so-called soft X-ray effect and ion desorption. A kind of the modulation gauge provided with a modulation electrode is described in this paper. If a plate is vibrating perpendicularly to its surface in the sufficiently low pressure gas to satisfy molecular conditions (molecular density n), the molecular density in the space in front of the plate is expected to vary with time, affected by the vibration of the plate. When the vacuum gauge is placed in this space, the modulated current is proportional to pressure P, which is not related to the current due to soft X-ray effect and ion desorption. The other cause of determining the pressure-measuring limit is noises, among which only the noise coherent with the vibration of the plate affects the measurement. To avoid the induced current by this type of noise, it is considered to use the pulse-counting technique using an electron multiplier. It is anticipated that the induced currents generated from electrical noises and mechanical vibrations can be avoided almost completely by this method. As a result, the theoretical measuring limit may be estimated at approximately 5 x 10 -13 Torr, if the mean residence time in the collision of molecules with the plate is assumed to be 1 sec, the sensitivity of the vacuum gauge S is 20 Torr -1 , electron current Ie is 2 x 10 -3 A and modulation coefficient m is 3 x 10 -3 . (Wakatsuki, Y.)

Vanishing quantum vacuum energy in eleven-dimensional supergravity on the round seven-sphere

International Nuclear Information System (INIS)

Inami, T.; Yamagishi, K.

1984-01-01

Quantum corrections to the vacuum energy are evaluated at one-loop order in eleven-dimensional supergravity on the round seven-sphere S 7 and are shown to vanish. The cancellation is also shown for all ultraviolet poles at z = 11/2, 10/2,..., corresponding to divergences of eleventh and lower powers of momentum cut-off Λ. (orig.)

Centrifugal forming and mechanical properties of silicone-based elastomers for soft robotic actuators

Science.gov (United States)

Kulkarni, Parth

This thesis describes the centrifugal forming and resulting mechanical properties of silicone-based elastomers for the manufacture of soft robotic actuators. This process is effective at removing bubbles that get entrapped within 3D-printed, enclosed molds. Conventional methods for rapid prototyping of soft robotic actuators to remove entrapped bubbles typically involve degassing under vacuum, with open-faced molds that limit the layout of formed parts to raised 2D geometries. As the functionality and complexity of soft robots increase, there is a need to mold complete 3D structures with controlled thicknesses or curvatures on multiples surfaces. In addition, characterization of the mechanical properties of common elastomers for these soft robots has lagged the development of new designs. As such, relationships between resulting material properties and processing parameters are virtually non-existent. One of the goals of this thesis is to provide guidelines and physical insights to relate the design, processing conditions, and resulting properties of soft robotic components to each other. Centrifugal forming with accelerations on the order of 100 g's is capable of forming bubble-free, true 3D components for soft robotic actuators, and resulting demonstrations in this work include an aquatic locomotor, soft gripper, and an actuator that straightens when pressurized. Finally, this work shows that the measured mechanical properties of 3D geometries fabricated within enclosed molds through centrifugal forming possess comparable mechanical properties to vacuumed materials formed from open-faced molds with raised 2D features.

Vacuum ultraviolet excited luminescence properties of sol–gel derived GdP5O14:Eu3+ powders

International Nuclear Information System (INIS)

Mbarek, Aïcha; Chadeyron, Geneviève; Boyer, Damien; Avignant, Daniel; Fourati, Mohieddine; Zambon, Daniel

2014-01-01

Sol–gel route has successfully been used to synthesize pure and Eu 3+ doped polycrystalline samples of the GdP 5 O 14 pentaphosphates. The as-prepared samples have structurally been characterized using X-ray diffraction. Optical properties in the vacuum ultraviolet (VUV) of Eu 3+ activated GdP 5 O 14 samples prepared either by sol–gel process or solid-state reaction were investigated at room temperature for comparison. In this GdP 5 O 14 host matrix the P 5 O 14 ultraphosphate groups were proved to exhibit an efficient absorption in the VUV range. The excitation spectra recorded in the VUV-UV spectral region from 120 nm to 350 nm have revealed the presence of Gd 3+ 4f–5d interconfiguration transitions, Gd 3+ –O 2− and Eu 3+ –O 2− charge transfer states(CTS)in addition to intraconfiguration transitions of Gd 3+ ions.Furthermore the Gd 3+ →Eu 3+ energy transfer process was investigated and discussed in the framework of the multiphonon relaxation process. Besides, the GdP 5 O 14 :Eu 3+ phosphor led to a strong red emission under 147/172 nm excitation, so that it can be considered as a promising red phosphor for mercury-free lamps and plasma display panels applications. -- Highlights: • Lanthanide pentaphosphates were synthesized by the sol–gel process. • A broad absorption was evidenced in the VUV range for GdP 5 O 14 :Eu 3+ . • An efficient energy transfer was proved from pentaphosphate lattice to Eu 3+ ions

Beam loss reduction by magnetic shielding using beam pipes and bellows of soft magnetic materials

Science.gov (United States)

Kamiya, J.; Ogiwara, N.; Hotchi, H.; Hayashi, N.; Kinsho, M.

2014-11-01

One of the main sources of beam loss in high power accelerators is unwanted stray magnetic fields from magnets near the beam line, which can distort the beam orbit. The most effective way to shield such magnetic fields is to perfectly surround the beam region without any gaps with a soft magnetic high permeability material. This leads to the manufacture of vacuum chambers (beam pipes and bellows) with soft magnetic materials. A Ni-Fe alloy (permalloy) was selected for the material of the pipe parts and outer bellows parts, while a ferritic stainless steel was selected for the flanges. An austenitic stainless steel, which is non-magnetic material, was used for the inner bellows for vacuum tightness. To achieve good magnetic shielding and vacuum performances, a heat treatment under high vacuum was applied during the manufacturing process of the vacuum chambers. Using this heat treatment, the ratio of the integrated magnetic flux density along the beam orbit between the inside and outside of the beam pipe and bellows became small enough to suppress beam orbit distortion. The outgassing rate of the materials with this heat treatment was reduced by one order magnitude compared to that without heat treatment. By installing the beam pipes and bellows of soft magnetic materials as part of the Japan Proton Accelerator Research Complex 3 GeV rapid cycling synchrotron beam line, the closed orbit distortion (COD) was reduced by more than 80%. In addition, a 95.5% beam survival ratio was achieved by this COD improvement.

Chiral phase transition in the soft-wall model of AdS/QCD

International Nuclear Information System (INIS)

Chelabi, Kaddour; Fang, Zhen; Huang, Mei; Li, Danning; Wu, Yue-Liang

2016-01-01

We investigate the chiral phase transition in the soft-wall model of AdS/QCD at zero chemical potential for two-flavor and three-flavor cases, respectively. We show that there is no spontaneous chiral symmetry breaking in the original soft-wall model. After detailed analysis, we find that in order to realize chiral symmetry breaking and restoration, both profiles for the scalar potential and the dilaton field are essential. The scalar potential determines the possible solution structure of the chiral condensate, except the mass term, it takes another quartic term for the two-flavor case, and for the three-flavor case, one has to take into account an extra cubic term due to the t’Hooft determinant interaction. The profile of the dilaton field reflects the gluodynamics, which is negative at a certain ultraviolet scale and approaches positive quadratic behavior at far infrared region. With this set-up, the spontaneous chiral symmetry breaking in the vacuum and its restoration at finite temperature can be realized perfectly. In the two-flavor case, it gives a second order chiral phase transition in the chiral limit, while the transition turns to be a crossover for any finite quark mass. In the case of three-flavor, the phase transition becomes a first order one in the chiral limit, while above sufficient large quark mass it turns to be a crossover again. This scenario agrees exactly with the current understanding on chiral phase transition from lattice QCD and other effective model studies.

Vacuum ultra-violet and ultra-violet scintillation light detection by means of silicon photomultipliers at cryogenic temperature

Energy Technology Data Exchange (ETDEWEB)

Falcone, A., E-mail: andrea.falcone@pv.infn.it [University of Pavia, via Bassi, 6, 27100 Pavia (Italy); INFN Sezione di Pavia, via Bassi, 6, 27100 Pavia (Italy); Bertoni, R. [INFN Sezione di Milano Bicocca, Piazza della Scienza, 3, 20126 Milano (Italy); Boffelli, F. [University of Pavia, via Bassi, 6, 27100 Pavia (Italy); INFN Sezione di Pavia, via Bassi, 6, 27100 Pavia (Italy); Bonesini, M. [INFN Sezione di Milano Bicocca, Piazza della Scienza, 3, 20126 Milano (Italy); Cervi, T. [University of Pavia, via Bassi, 6, 27100 Pavia (Italy); Menegolli, A. [University of Pavia, via Bassi, 6, 27100 Pavia (Italy); INFN Sezione di Pavia, via Bassi, 6, 27100 Pavia (Italy); Montanari, C.; Prata, M.C.; Rappoldi, A.; Raselli, G.L.; Rossella, M.; Simonetta, M. [INFN Sezione di Pavia, via Bassi, 6, 27100 Pavia (Italy); Spanu, M. [University of Pavia, via Bassi, 6, 27100 Pavia (Italy); Torti, M. [University of Pavia, via Bassi, 6, 27100 Pavia (Italy); INFN Sezione di Pavia, via Bassi, 6, 27100 Pavia (Italy); Zani, A. [INFN Sezione di Pavia, via Bassi, 6, 27100 Pavia (Italy)

2015-07-01

We tested the performance of two types of silicon photomultipliers, AdvanSiD ASD-NUV-SiPM3S-P and Hamamatsu 3×3 MM-50 UM VUV2, both at room (300 K) and at liquid nitrogen (77 K) temperature: breakdown voltage, quenching resistance, signal shape, gain and dark counts rate have been studied as function of temperature. The response of the devices to ultra-violet light is also studied. - Highlights: • We tested 2 SiPMs both at room and at cryogenic temperature. • Breakdown voltage, quenching resistance, gain and dark rate were measured. • Efficiency for VUV light detection was measured.

Dynamic Low-Vacuum Scanning Electron Microscope Freeze Drying Observation for Fresh Water Algae

International Nuclear Information System (INIS)

Mohsen, H.T.; Ghaly, W.A.; Zahran, N.F.; Helal, A.I.

2010-01-01

A new perpetration method for serving in dynamic examinations of the fresh water algae is developed in connection with the Low-Vacuum Scanning Electron Microscope (LV-SEM) freeze drying technique. Specimens are collected from fresh water of Ismailia channel then transferred directly to freeze by liquid nitrogen and dried in the chamber of the scanning electron microscope in the low vacuum mode. Scanning electron micrographs revealed that the drying method presented the microstructure of algae. Dehydration in a graded ethanol series is not necessary in the new method. Dried algae specimen is observed in SEM high vacuum mode after conductive coating at higher resolution. Low-vacuum SEM freeze drying technique is a simple, time-saving and reproducible method for scanning electron microscopy that is applicable to various aquatic microorganisms covered with soft tissues.

The vacuum interlock system for the PETRA III beamlines

Energy Technology Data Exchange (ETDEWEB)

Degenhardt, Markus; Hahn, Ulrich; Hesse, Mathias; Schulte-Schrepping, Horst [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)

2008-07-01

The storage ring PETRA at DESY in Hamburg is being reconstructed into the third generation source for synchrotron radiation, PETRA III. The up to 100 m long beamlines are large UHV-systems that guide the synchrotron radiation from the storage ring to the experiments. Each beamline will be equipped with a vacuum interlock system to ensure the safe operation of the vacuum components. In particular the task of the vacuum interlock is to prevent faulty operations that can cause a ventilation of the vacuum system or a damage of vacuum components by the high power synchrotron radiation beam. The interlock system will be implemented as a PLC that is connected to a distributed input/output layer via a field bus system. As a specialty, the PLC will be realised as a soft-PLC running on a PC with a real time windows operating system. Another specialty is the visualisation and remote control of the vacuum interlock system by means of a website. At the beamline the interlock will be operated via a touch panel that displays the visualisation website. Additionally, the interlock can be remotely operated from any location by opening the visualisation website with a browser. The interlock is protected against unauthorised operation by a login page. All relevant interlock data will be fed into the existing network-based archive system.

Vacuum ultraviolet (VUV) absorption spectra of chromatin and its components

International Nuclear Information System (INIS)

Dodonova, N.Y.; Kiseleva, M.N.; Petrov, M.Y.; Tsyganenko, N.M.; Bubyakina, V.V.; Chikhirzhina, G.I.

1984-01-01

The electron absorption spectra of thin films of chromatin and chromatin components in the ultraviolet region (140-280 nm) were investigated. The absorption coefficients μ(lambda) of chromatin, nucleosomes with and without histone H1, total histones (TH), and DNA were compared. The spectra of nucleosomes differ from the sum-spectrum of DNA plus TH. The chromatin and nucleosome spectra are not similar in the spectral region of 190-160 nm. The lack of additivity of absorption coefficients at different wavelengths may be explained by different conformational changes of DNA, TH in nucleosomes and chromatin during the process of drying aqueous solutions for the preparation of thin films. The μ(lambda) values are useful for an estimate of the DNA and TH absorption in chromatin and nucleosomes in discussing UV and VUV irradiation damages. (Auth.)

Production and analysis of some atomic emission spectra in the vacuum ultraviolet

International Nuclear Information System (INIS)

Meijer, F.G.

1979-01-01

The development of technical facilities for spectra analysis are described including the design, construction and adjustment of a grazing incidence spectrograph for the extreme ultraviolet and the improvements in light sources. The investigations of the fifth and fourth spectra of tantalum, the analysis of the sixth spectrum of tungsten, the extension of the analysis of the fourth spectrum of hafnium and a start of the analysis of the seventh spectrum of rhenium are presented. (C.F.)

Contrasting behavior of covalent and molecular carbon allotropes exposed to extreme ultraviolet and soft x-ray free-electron laser radiation

Science.gov (United States)

Toufarová, M.; Hájková, V.; Chalupský, J.; Burian, T.; Vacík, J.; Vorlíček, V.; Vyšín, L.; Gaudin, J.; Medvedev, N.; Ziaja, B.; Nagasono, M.; Yabashi, M.; Sobierajski, R.; Krzywinski, J.; Sinn, H.; Störmer, M.; Koláček, K.; Tiedtke, K.; Toleikis, S.; Juha, L.

2017-12-01

All carbon materials, e.g., amorphous carbon (a-C) coatings and C60 fullerene thin films, play an important role in short-wavelength free-electron laser (FEL) research motivated by FEL optics development and prospective nanotechnology applications. Responses of a-C and C60 layers to the extreme ultraviolet (SPring-8 Compact SASE Source in Japan) and soft x-ray (free-electron laser in Hamburg) free-electron laser radiation are investigated by Raman spectroscopy, differential interference contrast, and atomic force microscopy. A remarkable difference in the behavior of covalent (a-C) and molecular (C60) carbonaceous solids is demonstrated under these irradiation conditions. Low thresholds for ablation of a fullerene crystal (estimated to be around 0.15 eV/atom for C60 vs 0.9 eV/atom for a-C in terms of the absorbed dose) are caused by a low cohesive energy of fullerene crystals. An efficient mechanism of the removal of intact C60 molecules from the irradiated crystal due to Coulomb repulsion of fullerene-cage cation radicals formed by the ionizing radiation is revealed by a detailed modeling.

Shrinking the Synchrotron : Tabletop Extreme Ultraviolet Absorption of Transition-Metal Complexes

NARCIS (Netherlands)

Zhang, Kaili; Lin, Ming Fu; Ryland, Elizabeth S.; Verkamp, Max A.; Benke, Kristin; De Groot, Frank M F; Girolami, Gregory S.; Vura-Weis, Josh

2016-01-01

We show that the electronic structure of molecular first-row transition-metal complexes can be reliably measured using tabletop high-harmonic XANES at the metal M2,3 edge. Extreme ultraviolet photons in the 50-70 eV energy range probe 3p → 3d transitions, with the same selection rules as soft X-ray

Softness of Nuclear Matter and the Production of Strange Particles in Neutron Stars

Institute of Scientific and Technical Information of China (English)

陈伟; 文德华; 刘良钢

2003-01-01

In the various models, we study the influences of the softness of nuclear matter, the vacuum fluctuation ofnucleons and σ mesons on the production of strange particles in neutron stars. Wefind that the stiffer the nuclear matter is, the more easily the strange particles is produced in neutron stars. The vacuum fluctuation of nucleons has large effect on strange particle production while that of σ meson has little effect on it.

Improved resolution of hydrocarbon structures and constitutional isomers in complex mixtures using Gas Chromatography-Vacuum Ultraviolet-Mass Spectrometry (GC-VUV-MS)

Energy Technology Data Exchange (ETDEWEB)

Aerosol Dynamics Inc; Aerodyne Research, Inc.,; Tofwerk AG, Thun; Isaacman, Gabriel; Wilson, Kevin R.; Chan, Arthur W. H.; Worton, David R.; Kimmel, Joel R.; Nah, Theodora; Hohaus, Thorsten; Gonin, Marc; Kroll, Jesse H.; Worsnop, Doug R.; Goldstein, Allen H.

2011-09-13

Understanding the composition of complex hydrocarbon mixtures is important for environmental studies in a variety of fields, but many prevalent compounds cannot be confidently identified using traditional gas chromatography-mass spectrometry (GC-MS) techniques. This work uses vacuum-ultraviolet (VUV) ionization to elucidate the structures of a traditionally"unresolved complex mixture" by separating components by GC retention time, tR, and mass-to-charge ratio, m/Q, which are used to determine carbon number, NC, and the number of rings and double bonds, NDBE. Constitutional isomers are resolved based on tR, enabling the most complete quantitative analysis to date of structural isomers in an environmentally-relevant hydrocarbon mixture. Unknown compounds are classified in this work by carbon number, degree of saturation, presence of rings, and degree of branching, providing structural constraints. The capabilities of this analysis are explored using diesel fuel, in which constitutional isomer distribution patterns are shown to be reproducible between carbon numbers and follow predictable rules. Nearly half of the aliphatic hydrocarbon mass is shown to be branched, suggesting branching is more important in diesel fuel than previously shown. The classification of unknown hydrocarbons and the resolution of constitutional isomers significantly improves resolution capabilities for any complex hydrocarbon mixture.

Concept for a MEMS-type vacuum sensor based on electrical conductivity measurements

Directory of Open Access Journals (Sweden)

F. J. Giebel

2017-11-01

Full Text Available The concept of the micro-structured vacuum sensor presented in this article is the measurement of the electrical conductivity of thinned gases in order to develop a small, economical and quite a simple type of vacuum sensor. There are already some approaches for small vacuum sensors. Most of them are based on conservative measurement principles similar to those used in macroscopic vacuum gauges. Ionization gauges use additional sources of energy, like hot cathodes, ultraviolet radiation or high voltage for example, for ionizing gas molecules and thereby increasing the number of charge carriers for measuring low pressures. In contrast, the concept discussed here cannot be found in macroscopic sensor systems because it depends on the microscopic dimension of a gas volume defined by two electrodes. Here we present the concept and the production of a micro-structured vacuum sensor chip, followed by the electrical characterization. Reference measurements with electrodes at a distance of about 1 mm showed currents in the size of picoampere and a conductivity depending on ambient pressure. In comparison with these preliminary measurements, fundamental differences regarding pressure dependence of the conductivity are monitored in the electrical characterization of the micro-structured sensor chip. Finally the future perspectives of this sensor concept are discussed.

Airfoil sampling of a pulsed Laval beam with tunable vacuum ultraviolet synchrotron ionization quadrupole mass spectrometry: application to low-temperature kinetics and product detection.

Science.gov (United States)

Soorkia, Satchin; Liu, Chen-Lin; Savee, John D; Ferrell, Sarah J; Leone, Stephen R; Wilson, Kevin R

2011-12-01

A new pulsed Laval nozzle apparatus with vacuum ultraviolet (VUV) synchrotron photoionization quadrupole mass spectrometry is constructed to study low-temperature radical-neutral chemical reactions of importance for modeling the atmosphere of Titan and the outer planets. A design for the sampling geometry of a pulsed Laval nozzle expansion has been developed that operates successfully for the determination of rate coefficients by time-resolved mass spectrometry. The new concept employs airfoil sampling of the collimated expansion with excellent sampling throughput. Time-resolved profiles of the high Mach number gas flow obtained by photoionization signals show that perturbation of the collimated expansion by the airfoil is negligible. The reaction of C(2)H with C(2)H(2) is studied at 70 K as a proof-of-principle result for both low-temperature rate coefficient measurements and product identification based on the photoionization spectrum of the reaction product versus VUV photon energy. This approach can be used to provide new insights into reaction mechanisms occurring at kinetic rates close to the collision-determined limit.

Semi-automated high-efficiency reflectivity chamber for vacuum UV measurements

Science.gov (United States)

Wiley, James; Fleming, Brian; Renninger, Nicholas; Egan, Arika

2017-08-01

This paper presents the design and theory of operation for a semi-automated reflectivity chamber for ultraviolet optimized optics. A graphical user interface designed in LabVIEW controls the stages, interfaces with the detector system, takes semi-autonomous measurements, and monitors the system in case of error. Samples and an optical photodiode sit on an optics plate mounted to a rotation stage in the middle of the vacuum chamber. The optics plate rotates the samples and diode between an incident and reflected position to measure the absolute reflectivity of the samples at wavelengths limited by the monochromator operational bandpass of 70 nm to 550 nm. A collimating parabolic mirror on a fine steering tip-tilt motor enables beam steering for detector peak-ups. This chamber is designed to take measurements rapidly and with minimal oversight, increasing lab efficiency for high cadence and high accuracy vacuum UV reflectivity measurements.

Effective action of softly broken supersymmetric theories

International Nuclear Information System (INIS)

Groot Nibbelink, S.; Nyawelo, T.S

2006-12-01

We study the renormalization of (softly) broken supersymmetric theories at the one loop level in detail. We perform this analysis in a superspace approach in which the supersymmetry breaking interactions are parameterized using spurion insertions. We comment on the uniqueness of this parameterization. We compute the one loop renormalization of such theories by calculating superspace vacuum graphs with multiple spurion insertions. To preform this computation efficiently we develop algebraic properties of spurion operators, that naturally arise because the spurions are often surrounded by superspace projection operators. Our results are general apart from the restrictions that higher super covariant derivative terms and some finite effects due to non-commutativity of superfield dependent mass matrices are ignored. One of the soft potentials induces renormalization of the Kaehler potential. (author)

The quartz crystal microbalance in soft matter research fundamentals and modeling

CERN Document Server

Johannsmann, Diethelm

2014-01-01

This book describes the physics of the second-generation quartz crystal microbalance (QCM), a fundamental method of analysis for soft matter at interfaces.From a device for measuring film thickness in vacuum, the quartz crystal microbalance (QCM) has in the past two decades evolved into a versatile instrument for analyzing soft matter at solid/liquid and solid/gas interfaces that found applications in diverse fields including the life sciences, material science, polymer research and electrochemistry. As a consequence of this success, the QCM is now being used by scientists with a wide variety

Absolutely calibrated vacuum ultraviolet spectra in the 150-250-nm range from plasmas generated by the NIKE KrF laser

International Nuclear Information System (INIS)

Seely, J.F.; Feldman, Uri; Holland, G.E.; Weaver, J.L.; Mostovych, A.N.; Obenschain, S.P.; Schmitt, A.J.; Lehmberg, R.; Kjornarattanawanich, Benjawan; Back, C.A.

2005-01-01

High-resolution vacuum ultraviolet (VUV) spectra were recorded from plasmas generated by the NIKE KrF laser for the purpose of observing emission from the two-plasmon decay instability (TPDI) at 2/3 the NIKE wavelength (165 nm). The targets were irradiated by up to 43 overlapping beams with intensity up to ≅10 14 W/cm 2 and with beam smoothing by induced spatial incoherence (ISI). The targets consisted of planar foils of CH, BN, Al, Si, S, Ti, Pd, and Au. Titanium-doped silica aerogels in Pyrex cylinders were also irradiated. The spectra of the target elements were observed from charge states ranging from the neutral atoms to five times ionized. The spectrometer was absolutely calibrated using synchrotron radiation, and absolute VUV plasma emission intensities were determined. Emission from the TPDI at 165-nm wavelength was not observed from any of the irradiated targets. An upper bound on the possible TPDI emission was less than 4x10 -8 the incident NIKE laser energy. The NIKE laser radiation backscattered from the silica aerogel targets at 248 nm was typically 6x10 -6 the incident NIKE laser energy, and the spectral broadening corresponded to the 1-THz bandwidth of the ISI smoothing. The spectra from the moderately charged plasma ions (up to five times ionized), spectral linewidths, absolute continuum emission level, and slope of the continuum were consistent with plasma temperatures in the 100-300-eV range

Microbial survival of space vacuum and extreme ultraviolet irradiation: strain isolation and analysis during a rocket flight.

Science.gov (United States)

Saffary, Roya; Nandakumar, Renu; Spencer, Dennis; Robb, Frank T; Davila, Joseph M; Swartz, Marvin; Ofman, Leon; Thomas, Roger J; DiRuggiero, Jocelyne

2002-09-24

We have recovered new isolates from hot springs, in Yellowstone National Park and the Kamchatka Peninsula, after gamma-irradiation and exposure to high vacuum (10(-6) Pa) of the water and sediment samples. The resistance to desiccation and ionizing radiation of one of the isolates, Bacillus sp. strain PS3D, was compared to that of the mesophilic bacterium, Deinococcus radiodurans, a species well known for its extraordinary resistance to desiccation and high doses of ionizing radiation. Survival of these two microorganisms was determined in real and simulated space conditions, including exposure to extreme UV radiation (10-100 nm) during a rocket flight. We found that up to 15 days of desiccation alone had little effect on the viability of either bacterium. In contrast, exposure to space vacuum ( approximately 10(-6) Pa) decreased cell survival by two and four orders of magnitude for Bacillus sp. strain PS3D and D. radiodurans, respectively. Simultaneous exposure to space vacuum and extreme UV radiation further decreased the survival of both organisms, compared to unirradiated controls. This is the first report on the isolated effect of extreme UV at 30 nm on cell survival. Extreme UV can only be transmitted through high vacuum, therefore its penetration into the cells may only be superficial, suggesting that in contrast to near UV, membrane proteins rather than DNA were damaged by the radiation.

Electronic structure of pentacene on hafnium studied by ultraviolet photoelectron spectroscopy

International Nuclear Information System (INIS)

Kang, Seong Jun; Yi, Yeon Jin; Kim, Chung Yi; Whang, Chung Nam

2005-01-01

The electronic structure of pentacene on hafnium, which is a low work function metal, was analyzed by using ultraviolet photoelectron spectroscopy. The energy level alignment was studied by using the onset of the highest occupied molecular orbital level and the shift of the vacuum level of the pentacene layer, which was deposited on a clean hafnium surface in a stepwise manner. The measured onset of the highest occupied molecular orbital energy level was 1.52 eV from the Fermi level of hafnium. The vacuum level was shifted 0.28 eV toward higher binding energy with additional pentacene layers, which means an interfacial dipole exists at the interface between pentacene and hafnium. We confirm that a small electron injection barrier can be achieved by inserting a low work function metal in a pentacene thin-film transistor.

Probing nucleobase photoprotection with soft x-rays

Directory of Open Access Journals (Sweden)

Osipov T.

2013-03-01

Full Text Available Nucleobases absorb strongly in the ultraviolet region, leading to molecular excitation into reactive states. The molecules avoid the photoreactions by funnelling the electronic energy into less reactive states on an ultrafast timescale via non-Born-Oppenheimer dynamics. Current theory on the nucleobase thymine discusses two conflicting pathways for the photoprotective dynamics. We present our first results of our free electron laser based UV-pump soft x-ray-probe study of the photoprotection mechanism of thymine. We use the high spatial sensitivity of the Auger electrons emitted after the soft x-ray pulse induced core ionization. Our transient spetra show two timescales on the order of 200 fs and 5 ps, in agreement with previous (all UV ultrafast experiments. The timescales appear at different Auger kinetic energies which will help us to decipher the molecular dynamics.

Metastability bounds on flavour-violating trilinear soft terms in the MSSM

Energy Technology Data Exchange (ETDEWEB)

Park, Jae-hyeon

2010-11-15

The vacuum stability bounds on flavour-violating trilinear soft terms are revisited from the view-point that one should not ban a standard-model-like false vacuum as long as it is long-lived on a cosmological timescale. The vacuum transition rate is evaluated numerically by searching for the bounce configuration. Like stability, a metastability bound does not decouple even if sfermion masses grow. Apart from being more generous than stability, the new bounds are largely independent of Yukawa couplings except for the stop trilinears. With vacuum longevity imposed on otherwise arbitrary LR insertions, it is found that a super flavour factory has the potential to probe sparticle masses up to a few TeV through B and {tau} physics whereas the MEG experiment might cover a far wider range. In the stop sector, metastability is more restrictive than any existing experimental constraint such as from electroweak precision data. Also discussed are dependency on other parameters and reliability under radiative corrections. (orig.)

Metastability bounds on flavour-violating trilinear soft terms in the MSSM

International Nuclear Information System (INIS)

Park, Jae-hyeon

2010-11-01

The vacuum stability bounds on flavour-violating trilinear soft terms are revisited from the view-point that one should not ban a standard-model-like false vacuum as long as it is long-lived on a cosmological timescale. The vacuum transition rate is evaluated numerically by searching for the bounce configuration. Like stability, a metastability bound does not decouple even if sfermion masses grow. Apart from being more generous than stability, the new bounds are largely independent of Yukawa couplings except for the stop trilinears. With vacuum longevity imposed on otherwise arbitrary LR insertions, it is found that a super flavour factory has the potential to probe sparticle masses up to a few TeV through B and τ physics whereas the MEG experiment might cover a far wider range. In the stop sector, metastability is more restrictive than any existing experimental constraint such as from electroweak precision data. Also discussed are dependency on other parameters and reliability under radiative corrections. (orig.)

Vacuum-assisted closure therapy in the management of lung abscess.

Science.gov (United States)

Sziklavari, Zsolt; Ried, Michael; Hofmann, Hans-Stefan

2014-09-06

Despite significant advances in the treatment of thoracic infections, complex lung abscess remains a problem in modern thoracic surgery. We describe the novel application of vacuum-assisted closure for the treatment of a lung abscess. The technical details and preliminary results are reported. After the initial failed conservative treatment of an abscess, minimally invasive surgical intervention was performed with vacuum-assisted closure. The vacuum sponges were inserted in the abscess cavity at the most proximal point to the pleural surface. The intercostal space of the chest wall above the entering place was secured by a soft tissue retractor. The level of suction was initially set to 100 mm Hg, with a maximum suction of 125 mm Hg. The sponge was changed once on the 3rd postoperative day. The abscess cavity was rapidly cleaned and decreased in size. The mini-thoracotomy could be closed on the 9th postoperative day. Closure of the cavity was simple, without any short- or long-term treatment failure. This technique reduced the trauma associated with the procedure. The patient was discharged on the 11th postoperative day. Vacuum-assisted closure systems should be considered for widespread use as an alternative option for the treatment of complicated pulmonary abscess in elderly, debilitated, immunocompromised patients after failed conservative treatment.

Comparison of photospheric electric current and ultraviolet and x-ray emission in a solar active region

International Nuclear Information System (INIS)

Haisch, B.M.; Bruner, M.E.; Hagyard, M.J.; Bonnet, R.M.; NASA, Marshall Space Flight Center, Huntsville, AL; ESA, Paris, France)

1986-01-01

This paper presents an extensive set of coordinated observations of a solar active region, taking into account spectroheliograms obtained with the aid of the Solar Maximum Mission (SMM) Ultraviolet Spectrometer Polarimeter (UVSP) instrument, SMM soft x-ray polychromator (XRP) raster maps, and high spatial resolution ultraviolet images of the sun in Lyman-alpha and in the 1600 A continuum. These data span together the upper solar atmosphere from the temperature minimum to the corona. The data are compared to maps of the inferred photospheric electric current derived from the Marshall Space Flight Center (MSFC) vector magnetograph observations. Some empirical correlation is found between regions of inferred electric current density and the brightest features in the ultraviolet continuum and to a lesser extent those seen in Lyman-alpha within an active region. 29 references

Synthesis of CdS nanocrystals with different morphologies via an ultraviolet irradiation route

International Nuclear Information System (INIS)

Yao Suwei; Han Yuxin; Liu Weixing; Zhang Weiguo; Wang Hongzhi

2007-01-01

A simple ultraviolet photochemical reduction synthetic approach to preparing CdS nanocrystals with different morphologies is described. Sodium dodecyl sulfate (SDS) was used as soft template for the chemical synthesis of CdS nanocrystals in a mixture solution at room temperature. It was found that the magnetic force stirring and the volume proportions of C 2 H 5 OH and H 2 O had marked influences on the morphology of CdS nanocrystals (such as spherical, acicular-like, rod-like and worm-like shapes). The formation of CdS is via precipitation of Cd 2+ ions with the homogeneously released S 2- ions from decomposition of thioacetamide under ultraviolet irradiation source. X-ray diffraction (XRD), scanning electron microscopy (SEM) and the ultraviolet-visible (UV-vis) absorption spectra were employed to characterize the products. This novel method is expected to produce various semiconductor nanocrystals with potential applications in the fields of materials science and photovoltaic cells, etc

Soft x-ray streak cameras

International Nuclear Information System (INIS)

Stradling, G.L.

1988-01-01

This paper is a discussion of the development and of the current state of the art in picosecond soft x-ray streak camera technology. Accomplishments from a number of institutions are discussed. X-ray streak cameras vary from standard visible streak camera designs in the use of an x-ray transmitting window and an x-ray sensitive photocathode. The spectral sensitivity range of these instruments includes portions of the near UV and extends from the subkilovolt x- ray region to several tens of kilovolts. Attendant challenges encountered in the design and use of x-ray streak cameras include the accommodation of high-voltage and vacuum requirements, as well as manipulation of a photocathode structure which is often fragile. The x-ray transmitting window is generally too fragile to withstand atmospheric pressure, necessitating active vacuum pumping and a vacuum line of sight to the x-ray signal source. Because of the difficulty of manipulating x-ray beams with conventional optics, as is done with visible light, the size of the photocathode sensing area, access to the front of the tube, the ability to insert the streak tube into a vacuum chamber and the capability to trigger the sweep with very short internal delay times are issues uniquely relevant to x-ray streak camera use. The physics of electron imaging may place more stringent limitations on the temporal and spatial resolution obtainable with x-ray photocathodes than with the visible counterpart. Other issues which are common to the entire streak camera community also concern the x-ray streak camera users and manufacturers

Triggering photochemical processes in frozen extraterrestrial worlds by soft X-rays

International Nuclear Information System (INIS)

Pilling, Sergio; Bergantini, Alexandre; Vasconcelos, Fredson A; Rocha, Will R M

2015-01-01

We presents and experimental investigation on the effects produced by broad band soft X-rays (combined with a small fraction of vacuum ultra violet photons and possibly secondary elec-trons) on the surface of three moons of giant planets: Europa, Titan and Enceladus. Such environ-ments are constantly exposed to space ionizing agents (UV and soft X-rays photons, electrons and ions) allowing photodissociation processes, surface photochemistry and prebiotic chemistry. The processing of such spatial ices have promoted an enhancement in the chemical complexity, similar what may have happened in the early earth triggering the arising of life. (paper)

Characteristics of extreme ultraviolet emission from high-Z plasmas

International Nuclear Information System (INIS)

Ohashi, H.; Higashiguchi, T.; Suzuki, Y.; Kawasaki, M.; Suzuki, C.; Tomita, K.; Nishikino, M.; Fujioka, S.; Endo, A.; Li, B.; Otsuka, T.; Dunne, P.; O'Sullivan, G.

2016-01-01

We demonstrate the extreme ultraviolet (EUV) and soft x-ray sources in the 2 to 7 nm spectral region related to the beyond EUV (BEUV) question at 6.x nm and the water window source based on laser-produced high-Z plasmas. Resonance emission from multiply charged ions merges to produce intense unresolved transition arrays (UTAs), extending below the carbon K edge (4.37 nm). An outline of a microscope design for single-shot live cell imaging is proposed based on high-Z plasma UTA source, coupled to multilayer mirror optics. (paper)

Characteristics of extreme ultraviolet emission from high-Z plasmas

Science.gov (United States)

Ohashi, H.; Higashiguchi, T.; Suzuki, Y.; Kawasaki, M.; Suzuki, C.; Tomita, K.; Nishikino, M.; Fujioka, S.; Endo, A.; Li, B.; Otsuka, T.; Dunne, P.; O'Sullivan, G.

2016-03-01

We demonstrate the extreme ultraviolet (EUV) and soft x-ray sources in the 2 to 7 nm spectral region related to the beyond EUV (BEUV) question at 6.x nm and the water window source based on laser-produced high-Z plasmas. Resonance emission from multiply charged ions merges to produce intense unresolved transition arrays (UTAs), extending below the carbon K edge (4.37 nm). An outline of a microscope design for single-shot live cell imaging is proposed based on high-Z plasma UTA source, coupled to multilayer mirror optics.

Soft versus hard occlusal splint therapy in the management of temporomandibular disorders (TMDs)

OpenAIRE

Seifeldin, Sameh A; Elhayes, Khaled A.

2015-01-01

Aim: To compare between soft and hard occlusal splint therapy for the management of myofacial pain dysfunction (MPD) or internal derangement (ID) of the temporomandibular joint (TMJ) with reciprocal clicking. Patients and methods: This study included 50 patients (age range: 24–47 years) who had been diagnosed with MPD or ID of the TMJ in the form of reciprocal clicking. Patients were divided into two groups. They were treated for 4 months with either a vacuum-formed soft occlusal splint co...

Ultraviolet/visible and Fourier transform infrared spectroscopic investigations of organic–inorganic hybrid layers for UV protection

Energy Technology Data Exchange (ETDEWEB)

Präfke, Christiane, E-mail: christiane.praefke@iof.fraunhofer.de [Fraunhofer Institute of Applied Optics and Precision Engineering, Optical Coatings Department, Albert-Einstein-Straße 7, 07745 Jena (Germany); Institute of Applied Physics, Abbe Center of Photonics, Friedrich-Schiller-Universität Jena (Germany); Schulz, Ulrike, E-mail: ulrike.schulz@iof.fraunhofer.de [Fraunhofer Institute of Applied Optics and Precision Engineering, Optical Coatings Department, Albert-Einstein-Straße 7, 07745 Jena (Germany); Kaiser, Norbert, E-mail: norbert.kaiser@iof.fraunhofer.de [Fraunhofer Institute of Applied Optics and Precision Engineering, Optical Coatings Department, Albert-Einstein-Straße 7, 07745 Jena (Germany); Tünnermann, Andreas, E-mail: andreas.tuennermann@iof.fraunhofer.de [Fraunhofer Institute of Applied Optics and Precision Engineering, Optical Coatings Department, Albert-Einstein-Straße 7, 07745 Jena (Germany); Institute of Applied Physics, Abbe Center of Photonics, Friedrich-Schiller-Universität Jena (Germany)

2013-04-01

A study of vacuum-deposited organic–inorganic hybrid coatings for ultraviolet (UV) protection of polycarbonate is presented. For this purpose, UV-absorbing organic molecules were embedded in a silica matrix by thermal co-evaporation. Typical UV absorbers, namely a benzotriazole, a hydroxyphenyltriazine, and a cyanoacrylate, were used as organic materials. The hybrid layers were investigated by means of ultraviolet/visible (UV/VIS) and Fourier transform infrared spectroscopy (FTIR) concerning their UV/VIS absorption properties and the influence of the silica network on the organic molecules. The porosity and silica–organic interactions are discussed with reference to the infrared spectra. UV irradiation experiments were carried out to demonstrate the UV protection ability of the hybrid layers. Hybrid layers containing the hydroxyphenyltriazine compound showed the best results. - Highlights: ► Vacuum deposited organic–inorganic UV protective coatings for polycarbonate ► Thermal co-evaporation of organic UV absorbing compounds with silica ► Matrix materials and the absorber concentration influence the absorption behavior. ► The coatings on PC show improved UV stability under artificial irradiation. ► The hydroxyphenyltriazine–silica layer shows best UV protection results.

Effect of the methyl substitution on the combustion of two methylheptane isomers: Flame chemistry using vacuum-ultraviolet (VUV) photoionization mass spectrometry

KAUST Repository

Selim, Hatem

2015-04-16

Alkanes with one or more methyl substitutions are commonly found in liquid transportation fuels, so a fundamental investigation of their combustion chemistry is warranted. In the present work, stoichiometric low-pressure (20 Torr) burner-stabilized flat flames of 2-methylheptane and 3-methylheptane were investigated. Flame species were measured via time-of-flight molecular-beam mass spectrometry, with vacuum-ultraviolet (VUV) synchrotron radiation as the ionization source. Mole fractions of major end-products and intermediate species (e.g., alkanes, alkenes, alkynes, aldehydes, and dienes) were quantified axially above the burner surface. Mole fractions of several free radicals were also measured (e.g., CH3, HCO, C2H3, C3H3, and C3H5). Isomers of different species were identified within the reaction pool by an energy scan between 8 and 12 eV at a distance of 2.5 mm away from the burner surface. The role of methyl substitution location on the alkane chain was determined via comparisons of similar species trends obtained from both flames. The results revealed that the change in CH3 position imposed major differences on the combustion of both fuels. Comparison with numerical simulations was performed for kinetic model testing. The results provide a comprehensive set of data about the combustion of both flames, which can enhance the erudition of both fuels combustion chemistry and also improve their chemical kinetic reaction mechanisms. © 2015 American Chemical Society.

Vacuum ultraviolet emission spectrum measurement of a microwave-discharge hydrogen-flow lamp in several configurations: Application to photodesorption of CO ice

Energy Technology Data Exchange (ETDEWEB)

Chen, Y.-J.; Wu, C.-Y. R. [Space Sciences Center and Department of Physics and Astronomy, University of Southern California, Los Angeles, CA 90089-1341 (United States); Chuang, K.-J.; Chu, C.-C.; Yih, T.-S. [Department of Physics, National Central University, Jhongli City, Taoyuan County 32054, Taiwan (China); Muñoz Caro, G. M. [Centro de Astrobiología, INTA-CSIC, Torrejón de Ardoz, E-28850 Madrid (Spain); Nuevo, M. [NASA Ames Research Center, Moffett Field, CA 94035 (United States); Ip, W.-H., E-mail: yujung@usc.edu [Graduate Institute of Astronomy, National Central University, Jhongli City, Taoyuan County 32049, Taiwan (China)

2014-01-20

We report measurements of the vacuum ultraviolet (VUV) emission spectra of a microwave-discharge hydrogen-flow lamp (MDHL), a common tool in astrochemistry laboratories working on ice VUV photoprocessing. The MDHL provides hydrogen Ly-α (121.6 nm) and H{sub 2} molecular emission in the 110-180 nm range. We show that the spectral characteristics of the VUV light emitted in this range, in particular the relative proportion of Ly-α to molecular emission bands, strongly depend on the pressure of H{sub 2} inside the lamp, the lamp geometry (F type versus T type), the gas used (pure H{sub 2} versus H{sub 2} seeded in He), and the optical properties of the window used (MgF{sub 2} versus CaF{sub 2}). These different configurations are used to study the VUV irradiation of CO ice at 14 K. In contrast to the majority of studies dedicated to the VUV irradiation of astrophysical ice analogs, which have not taken into consideration the emission spectrum of the MDHL, our results show that the processes induced by photons in CO ice from a broad energy range are different and more complex than the sum of individual processes induced by monochromatic sources spanning the same energy range, as a result of the existence of multistate electronic transitions and discrepancy in absorption cross sections between parent molecules and products in the Ly-α and H{sub 2} molecular emission ranges.

Vacuum ultraviolet emission spectrum measurement of a microwave-discharge hydrogen-flow lamp in several configurations: Application to photodesorption of CO ice

International Nuclear Information System (INIS)

Chen, Y.-J.; Wu, C.-Y. R.; Chuang, K.-J.; Chu, C.-C.; Yih, T.-S.; Muñoz Caro, G. M.; Nuevo, M.; Ip, W.-H.

2014-01-01

We report measurements of the vacuum ultraviolet (VUV) emission spectra of a microwave-discharge hydrogen-flow lamp (MDHL), a common tool in astrochemistry laboratories working on ice VUV photoprocessing. The MDHL provides hydrogen Ly-α (121.6 nm) and H 2 molecular emission in the 110-180 nm range. We show that the spectral characteristics of the VUV light emitted in this range, in particular the relative proportion of Ly-α to molecular emission bands, strongly depend on the pressure of H 2 inside the lamp, the lamp geometry (F type versus T type), the gas used (pure H 2 versus H 2 seeded in He), and the optical properties of the window used (MgF 2 versus CaF 2 ). These different configurations are used to study the VUV irradiation of CO ice at 14 K. In contrast to the majority of studies dedicated to the VUV irradiation of astrophysical ice analogs, which have not taken into consideration the emission spectrum of the MDHL, our results show that the processes induced by photons in CO ice from a broad energy range are different and more complex than the sum of individual processes induced by monochromatic sources spanning the same energy range, as a result of the existence of multistate electronic transitions and discrepancy in absorption cross sections between parent molecules and products in the Ly-α and H 2 molecular emission ranges.

Soft CP violation in K-meson systems

International Nuclear Information System (INIS)

Montero, J.C.; Nishi, C.C.; Pleitez, V.; Ravinez, O.; Rodriguez, M.C.

2006-01-01

We consider a model with soft CP violation which accommodates the CP violation in the neutral kaons even if we assume that the Cabibbo-Kobayashi-Maskawa mixing matrix is real and the sources of CP violation are three complex vacuum expectation values and a trilinear coupling in the scalar potential. We show that for some reasonable values of the masses and other parameters the model allows us to explain all the observed CP violation processes in the K 0 -K 0 system

Bending-magnet vacuum chambers for VUV ring at LNLS

International Nuclear Information System (INIS)

Castro, A.R.B. de; Rodrigues, A.R.D.; Gomes, P.A.P.; Baptista, C.A.R.

1990-01-01

We discuss design criteria dictated by optical, thermal, electrical impedance and structural considerations. The proposed chambers will provide 3 conventional light ports. A fourth port will allow extraction of back scattered soft X-rays. Cooled absorbers will collect the unused radiation while confining the photo-stimulated desorption to a vacuum antechamber away from the electron beam path. We describe the thermal considerations relating to the cooled sapphire filters needed in the visible light ports and the cooling requirements for the copper radiation absorbers. (author)

Bending-magnet vacuum chambers for VUV ring at LNLS

International Nuclear Information System (INIS)

de Castro, A.R.B.; Rodrigues, A.R.D.; Gomes, P.A.P.; Baptista, C.A.R.P.

1990-01-01

This paper discusses design criteria dictated by optical, thermal, electrical impedance and structural considerations. The proposed chambers will provide 3 conventional light ports. A fourth port will allow extraction of back scattered soft X-rays. Cooled absorbers will collect the unused radiation while confining the photo-stimulated desorption to a vacuum antechamber away from the electron beam path. The authors describe the thermal considerations relating to the cooled sapphire filters needed in the visible light ports and the cooling requirements for the copper radiation absorbers

Evolution of Oxygen Deficiency Center on Fused Silica Surface Irradiated by Ultraviolet Laser and Posttreatment

Directory of Open Access Journals (Sweden)

Hai-Bing Lü

2014-01-01

Full Text Available Evolution of oxygen deficiency centers (ODCs on a fused silica surface irradiated using a 355 nm ultraviolet (UV laser beam in both vacuum and atmospheric conditions was quantitatively studied using photoluminescence and X-ray photoelectron spectroscopy. When the fusedsilica surface was exposed to the UV laser in vacuum, the laser damage threshold was decreased whereas the concentration of the ODCs was increased. For the fuse silica operated under the high power lasers, creation of ODCs on their surface resulted from the UV laser irradiation, and this is more severe in a high vacuum. The laser fluence and/or laser intensity have significant effects on the increase of the ODCs concentration. The ODCs can be effectively repaired using postoxygen plasma treatment and UV laser irradiation in an excessive oxygen environment. Results also demonstrated that the “gain” and “loss” of oxygen at the silica surface is a reversible and dynamic process.

A comparison of photospheric electric current and ultraviolet and X-ray emission in a solar active region

Science.gov (United States)

Haisch, B. M.; Bruner, M. E.; Hagyard, M. J.; Bonnet, R. M.

1986-01-01

This paper presents an extensive set of coordinated observations of a solar active region, taking into account spectroheliograms obtained with the aid of the Solar Maximum Mission (SMM) Ultraviolet Spectrometer Polarimeter (UVSP) instrument, SMM soft X-ray polychromator (XRP) raster maps, and high spatial resolution ultraviolet images of the sun in Lyman-alpha and in the 1600 A continuum. These data span together the upper solar atmosphere from the temperature minimum to the corona. The data are compared to maps of the inferred photospheric electric current derived from the Marshall Space Flight Center (MSFC) vector magnetograph observations. Some empirical correlation is found between regions of inferred electric current density and the brightest features in the ultraviolet continuum and to a lesser extent those seen in Lyman-alpha within an active region.

The use of vacuum ultraviolet irradiation to oxidize SO2 and NOx for simultaneous desulfurization and denitrification

International Nuclear Information System (INIS)

Ye, Junhui; Shang, Jing; Li, Qian; Xu, Weiwei; Liu, Jia; Feng, Xiang; Zhu, Tong

2014-01-01

Highlights: • ROS, ·OH, ·HO 2 , ·O, and O 3 were generated by VUV photolysis of water and oxygen. • SO 2 and NO x can react with ROS to offer 90% and 96% removal efficiency, respectively. • The flue gas factors’ influences on SO 2 and NO x removal efficiency were investigated. • Mechanisms were proposed based on the photooxidation reactions and ROS generation. • The final products H 2 SO 4 and HNO 3 can be used as industrial raw materials. - Abstract: A simple and efficient method for simultaneous desulfurization and denitrification via vacuum ultraviolet (VUV) irradiation and with no additional chemicals is presented. The simultaneous removal of 90% SO 2 and 96% NO x (NO + NO 2 ) was achieved from the simulated flue gas under the irradiation from a low-pressure mercury lamp with main wavelengths of 185 and 254 nm, respectively. The composition, flow rate, and temperature of the simulated flue gas, as well as the VUV light intensity, were evaluated as the factors impacting on the efficiency of SO 2 and NO x removal. The ·OH, ·HO 2 , ·O, and O 3 produced from the photolysis of H 2 O and O 2 were concluded as the major reactive oxygen species that oxidized SO 2 and NO x . The additional ·OH and ·HO 2 generated through the reactions of NO + ·HO 2 and SO 2 + ·OH/·HO 2 improved treatment efficiency, while the oxidation products of NO x , e.g., NO 2 , HNO 2 , HNO 3 , and HNO 4 , consumed massive reactive oxygen species (such as ·O, ·OH, and ·HO 2 ) and thereby reducing the removal efficiencies. The main reaction products were characterized as H 2 SO 4 and HNO 3 by ion chromatography, which could be used as chemical or fertilizer raw materials

BRIEF COMMUNICATIONS: Optically pumped ultraviolet BR2 laser

Science.gov (United States)

Kamrukov, A. S.; Kozlov, N. P.; Protasov, Yu S.; Ushmarov, E. Yu

1989-12-01

A report is given of lasing achieved for the first time in optically pumped molecular bromine (D' 3Π2g→A' 3π2u, λL approx 292 nm). It was pumped by thermal vacuum ultraviolet radiation emitted by plasmadynamic discharges of magnetoplasma compressors, formed directly in the laser active medium. An output energy of ~ 1.1 J was obtained per laser pulse of ~ 5-μs duration from a Br2:Ar approx 1:450 active mixture at a pressure of ~ 4 atm. A comparison was made of the experimental output parameters of optically pumped Br2, I2, and XeF (B-X) lasers when their geometries and excitation energies were identical.

Soft supersymmetry breaking in KKLT flux compactification

International Nuclear Information System (INIS)

Choi, K.; Falkowski, A.; Nilles, H.P.; Olechowski, M.

2005-01-01

We examine the structure of soft supersymmetry breaking terms in KKLT models of flux compactification with low energy supersymmetry. Moduli are stabilized by fluxes and nonperturbative dynamics while a de Sitter vacuum is obtained by adding supersymmetry breaking anti-branes. We discuss the characteristic pattern of mass scales in such a set-up as well as some features of 4D N=1 supergravity breakdown by anti-branes. Anomaly mediation is found to always give an important contribution and one can easily arrange for flavor-independent soft terms. In its most attractive realization, the modulus mediation is comparable to the anomaly mediation, yielding a quite distinctive sparticle spectrum. In addition, the axion component of the modulus/dilaton superfield dynamically cancels the relative CP phase between the contributions of anomaly and modulus mediation, thereby avoiding dangerous SUSY CP violation

Soft pair excitations and double-log divergences due to carrier interactions in graphene

Science.gov (United States)

Lewandowski, Cyprian; Levitov, L. S.

2018-03-01

Interactions between charge carriers in graphene lead to logarithmic renormalization of observables mimicking the behavior known in (3+1)-dimensional quantum electrodynamics (QED). Here we analyze soft electron-hole (e -h ) excitations generated as a result of fast charge dynamics, a direct analog of the signature QED effect—multiple soft photons produced by the QED vacuum shakeup. We show that such excitations are generated in photon absorption, when a photogenerated high-energy e -h pair cascades down in energy and gives rise to multiple soft e -h excitations. This fundamental process is manifested in a double-log divergence in the emission rate of soft pairs and a characteristic power-law divergence in their energy spectrum of the form 1/ω ln(ω/Δ ) . Strong carrier-carrier interactions make pair production a prominent pathway in the photoexcitation cascade.

Ultraviolet Extensions

Science.gov (United States)

2008-01-01

[figure removed for brevity, see original site] Side-by-Side Comparison Click on image for larger view This ultraviolet image from NASA's Galaxy Evolution Explorer shows the Southern Pinwheel galaxy, also know as Messier 83 or M83. It is located 15 million light-years away in the southern constellation Hydra. Ultraviolet light traces young populations of stars; in this image, young stars can be seen way beyond the main spiral disk of M83 up to 140,000 light-years from its center. Could life exist around one of these far-flung stars? Scientists say it's unlikely because the outlying regions of a galaxy are lacking in the metals required for planets to form. The image was taken at scheduled intervals between March 15 and May 20, 2007. It is one of the longest-exposure, or deepest, images ever taken of a nearby galaxy in ultraviolet light. Near-ultraviolet light (or longer-wavelength ultraviolet light) is colored yellow, and far-ultraviolet light is blue. What Lies Beyond the Edge of a Galaxy The side-by-side comparison shows the Southern Pinwheel galaxy, or M83, as seen in ultraviolet light (right) and at both ultraviolet and radio wavelengths (left). While the radio data highlight the galaxy's long, octopus-like arms stretching far beyond its main spiral disk (red), the ultraviolet data reveal clusters of baby stars (blue) within the extended arms. The ultraviolet image was taken by NASA's Galaxy Evolution Explorer between March 15 and May 20, 2007, at scheduled intervals. Back in 2005, the telescope first photographed M83 over a shorter period of time. That picture was the first to reveal far-flung baby stars forming up to 63,000 light-years from the edge of the main spiral disk. This came as a surprise to astronomers because a galaxy's outer territory typically lacks high densities of star-forming materials. The newest picture of M83 from the Galaxy Evolution Explorer is shown at the right, and was taken over a longer period of time. In fact, it is one of the

A fluorescence XAFS measurement instrument in the soft x-ray region toward observation under operando conditions

Energy Technology Data Exchange (ETDEWEB)

Honda, M., E-mail: honda.mitsunori@jaea.go.jp; Baba, Y.; Shimoyama, I.; Sekiguchi, T. [Quantum Beam Science Center, Japan Atomic Energy Agency (JAEA), 2-4 Shirakata-Shirane, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan)

2015-03-15

X-ray absorption fine structure (XAFS) measurements are widely used for the analysis of electronic structure. Generally, XAFS in the soft X-ray region is measured under vacuum, but chemical structures under vacuum are typically different from those under operando conditions, where chemical species exhibit their function. Here, we developed an XAFS measurement instrument, as a step toward operando fluorescent, which yields XAFS measurement using synchrotron radiation in the soft X-ray region. We applied this method to analyze the local electronic structure of the sulfur atoms in L-cysteine in different pH solutions. In water at pH 7, the hydrogen atom does not dissociate from the thiol (-SH) group in L-cysteine, which forms a structure surrounded by and interacting with water molecules. The XAFS spectrum of L-cysteine in solution was altered by changing the pH. At pH 9, the hydrogen atom dissociated and a thiolate anion was formed. Although the -SH group was oxidized to SO{sub 4}{sup 2−} when L-cysteine was adsorbed on a metal surface and dried, no oxidation was observed in solution. This may be because the water molecules were densely packed and protected the -SH group from oxidation. Our results show that this instrument aimed toward operando fluorescence XAFS measurements in the soft X-ray region is useful for structural analysis of sulfur atoms in organic molecules in air and in solution. The instrument will be applied to the structural analysis of materials containing elements that have absorption edges in soft X-ray region, such as phosphorus and alkali metals (potassium and cesium). It will be also particularly useful for the analysis of samples that are difficult to handle under vacuum and materials that have specific functions in solution.

Leybold vacuum handbook

CERN Document Server

Diels, K; Diels, Kurt

1966-01-01

Leybold Vacuum Handbook presents a collection of data sets that are essential for numerical calculation of vacuum plants and vacuum processes. The title first covers vacuum physics, which includes gas kinetics, flow phenomena, vacuum gauges, and vapor removal. Next, the selection presents data on vacuum, high vacuum process technology, and gas desorption and gettering. The text also deals with materials, vapor pressure, boiling and melting points, and gas permeability. The book will be of great interest to engineers and technicians that deals with vacuum related technologies.

Softly broken N=2 QCD

CERN Document Server

Alvarez-Gaumé, Luís; Kounnas, Costas; Marino, M; Alvarez-Gaume, Luis; Distler, Jacques; Kounnas, Costas; Marino, Marcos

1996-01-01

We analyze the possible soft breaking of N=2 supersymmetric Yang-Mills theory with and without matter flavour preserving the analyticity properties of the Seiberg-Witten solution. For small supersymmetry breaking parameter with respect to the dynamical scale of the theory we obtain an exact expression for the effective potential. We describe in detail the onset of the confinement transition and some of the patterns of chiral symmetry breaking. If we extrapolate the results to the limit where supersymmetry decouples, we obtain hints indicating that perhaps a description of the QCD vacuum will require the use of Lagrangians containing simultaneously mutually non-local degrees of freedom (monopoles and dyons).

Vacuum Technology

Energy Technology Data Exchange (ETDEWEB)

Biltoft, P J

2004-10-15

The environmental condition called vacuum is created any time the pressure of a gas is reduced compared to atmospheric pressure. On earth we typically create a vacuum by connecting a pump capable of moving gas to a relatively leak free vessel. Through operation of the gas pump the number of gas molecules per unit volume is decreased within the vessel. As soon as one creates a vacuum natural forces (in this case entropy) work to restore equilibrium pressure; the practical effect of this is that gas molecules attempt to enter the evacuated space by any means possible. It is useful to think of vacuum in terms of a gas at a pressure below atmospheric pressure. In even the best vacuum vessels ever created there are approximately 3,500,000 molecules of gas per cubic meter of volume remaining inside the vessel. The lowest pressure environment known is in interstellar space where there are approximately four molecules of gas per cubic meter. Researchers are currently developing vacuum technology components (pumps, gauges, valves, etc.) using micro electro mechanical systems (MEMS) technology. Miniature vacuum components and systems will open the possibility for significant savings in energy cost and will open the doors to advances in electronics, manufacturing and semiconductor fabrication. In conclusion, an understanding of the basic principles of vacuum technology as presented in this summary is essential for the successful execution of all projects that involve vacuum technology. Using the principles described above, a practitioner of vacuum technology can design a vacuum system that will achieve the project requirements.

Indian Vacuum Society: The Indian Vacuum Society

Science.gov (United States)

Saha, T. K.

2008-03-01

The Indian Vacuum Society (IVS) was established in 1970. It has over 800 members including many from Industry and R & D Institutions spread throughout India. The society has an active chapter at Kolkata. The society was formed with the main aim to promote, encourage and develop the growth of Vacuum Science, Techniques and Applications in India. In order to achieve this aim it has conducted a number of short term courses at graduate and technician levels on vacuum science and technology on topics ranging from low vacuum to ultrahigh vacuum So far it has conducted 39 such courses at different parts of the country and imparted training to more than 1200 persons in the field. Some of these courses were in-plant training courses conducted on the premises of the establishment and designed to take care of the special needs of the establishment. IVS also regularly conducts national and international seminars and symposia on vacuum science and technology with special emphasis on some theme related to applications of vacuum. A large number of delegates from all over India take part in the deliberations of such seminars and symposia and present their work. IVS also arranges technical visits to different industries and research institutes. The society also helped in the UNESCO sponsored post-graduate level courses in vacuum science, technology and applications conducted by Mumbai University. The society has also designed a certificate and diploma course for graduate level students studying vacuum science and technology and has submitted a syllabus to the academic council of the University of Mumbai for their approval, we hope that some colleges affiliated to the university will start this course from the coming academic year. IVS extended its support in standardizing many of the vacuum instruments and played a vital role in helping to set up a Regional Testing Centre along with BARC. As part of the development of vacuum education, the society arranges the participation of

Changes of surface electron states of InP under soft X-rays irradiation

International Nuclear Information System (INIS)

Yang Zhian; Yang Zushen; Jin Tao; Qui Rexi; Cui Mingqi; Liu Fengqin

1999-01-01

Changes of surface electronic states of InP under 1 keV X-ray irradiation is studied by X-ray photoelectron spectroscopy (XPS) and ultraviolet ray energy spectroscopy (UPS). The results show that the soft X-ray irradiation has little effect on In atoms but much on P atoms. The authors analysed the mechanism of irradiation and explained the major effect

Edge multi-energy soft x-ray diagnostic in Experimental Advanced Superconducting Tokamak

Energy Technology Data Exchange (ETDEWEB)

Li, Y. L.; Xu, G. S.; Wan, B. N.; Lan, H.; Liu, Y. L.; Wei, J.; Zhang, W.; Hu, G. H.; Wang, H. Q.; Duan, Y. M.; Zhao, J. L.; Wang, L.; Liu, S. C.; Ye, Y.; Li, J.; Lin, X.; Li, X. L. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Tritz, K. [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Zhu, Y. B. [Department of Physics and Astronomy, University of California, Irvine, California 92697-4575 (United States)

2015-12-15

A multi-energy soft x-ray (ME-SXR) diagnostic has been built for electron temperature profile in the edge plasma region in Experimental Advanced Superconducting Tokamak (EAST) after two rounds of campaigns. Originally, five preamplifiers were mounted inside the EAST vacuum vessel chamber attached to five vertically stacked compact diode arrays. A custom mechanical structure was designed to protect the detectors and electronics under constraints of the tangential field of view for plasma edge and the allocation of space. In the next experiment, the mechanical structure was redesigned with a barrel structure to absolutely isolate it from the vacuum vessel. Multiple shielding structures were mounted at the pinhole head to protect the metal foils from lithium coating. The pre-amplifiers were moved to the outside of the vacuum chamber to avoid introducing interference. Twisted copper cooling tube was embedded into the back-shell near the diode to limit the temperature of the preamplifiers and diode arrays during vacuum vessel baking when the temperature reached 150 °C. Electron temperature profiles were reconstructed from ME-SXR measurements using neural networks.

Edge multi-energy soft x-ray diagnostic in Experimental Advanced Superconducting Tokamak

International Nuclear Information System (INIS)

Li, Y. L.; Xu, G. S.; Wan, B. N.; Lan, H.; Liu, Y. L.; Wei, J.; Zhang, W.; Hu, G. H.; Wang, H. Q.; Duan, Y. M.; Zhao, J. L.; Wang, L.; Liu, S. C.; Ye, Y.; Li, J.; Lin, X.; Li, X. L.; Tritz, K.; Zhu, Y. B.

2015-01-01

A multi-energy soft x-ray (ME-SXR) diagnostic has been built for electron temperature profile in the edge plasma region in Experimental Advanced Superconducting Tokamak (EAST) after two rounds of campaigns. Originally, five preamplifiers were mounted inside the EAST vacuum vessel chamber attached to five vertically stacked compact diode arrays. A custom mechanical structure was designed to protect the detectors and electronics under constraints of the tangential field of view for plasma edge and the allocation of space. In the next experiment, the mechanical structure was redesigned with a barrel structure to absolutely isolate it from the vacuum vessel. Multiple shielding structures were mounted at the pinhole head to protect the metal foils from lithium coating. The pre-amplifiers were moved to the outside of the vacuum chamber to avoid introducing interference. Twisted copper cooling tube was embedded into the back-shell near the diode to limit the temperature of the preamplifiers and diode arrays during vacuum vessel baking when the temperature reached 150 °C. Electron temperature profiles were reconstructed from ME-SXR measurements using neural networks

Soft X-ray diffractometer for synchrotron radiation

CERN Document Server

Gau, T S; Liu, K Y; Chung, C H; Chen, C K; Lai, S C; Shu, C H; Huang, Y S; Chao, C H; Lee, Y R; Chen, C T; Chang, S L

2001-01-01

An ultra-high vacuum soft X-ray diffractometer has been constructed and commissioned at the Synchrotron Radiation Research Center (SRRC) to investigate materials structures in mesoscale. The diffractometer, housed in a UHV tank, consists of a 6-circle goniometer, together with the systems for beam-collimation, signal detection, vacuum, and control panels. The kappa-phi (cursive,open) Greek-psi goniostat is adopted for the sample orientation. Crystal samples can be rotated along a given reciprocal lattice vector by using psi scan. Two orthogonal axes, gamma (or 2 theta) and delta, are used to move the detector. The detector is a semiconductor pin diode, which can be used in UHV ambient. This 6-circle goniometer allows for sample scanning of a wide range in the momentum space. The motors used for goniometer rotation and slit selection are UHV compatible. The UHV tank is placed on an XYZ table capable of positioning the center of the goniometer onto the incident beam. Test experiments have been carried on the 1-...

Evaluation of the Efficiency of the Foxtail Millet Vacuum Cushion in Skin Cancer Radiation Treatment

Energy Technology Data Exchange (ETDEWEB)

Choi, Shin; Cheol; Lee, Kyung Jae; Jung, Sung Min; Oh, Tae Seong; Park, Jong Il; Shin, Hyun Kye [Dept. of Radiation Oncology, Ewha Womans University Mokdong Hospital, Seoul (Korea, Republic of)

2012-09-15

The sufficiency of skin dose and the reemergence of patient set-up position to the success of skin cancer radiation treatment is a very important element. But the conventional methods to increase the skin dose were used to vacuum cushion, bolus and water tank have several weak points. For this reason, we produced Foxtail Millet Vacuum Cushion and evaluated the efficiency of the Foxtail Millet Vacuum Cushion in skin cancer Radiation treatment. We measured absolute dose for 3 materials (Foxtail Millet Vacuum Cushion, bolus and solid water phantom) and compared each dose distribution. We irradiated 6 MV 100 MU photon radiation to every material of 1 cm, 2 cm, 3 cm thickness at three times. We measured absolute dose and compared dose distribution. Finally we inspected the CT simulation and radiation therapy planing using the Foxtail Millet Vacuum Cushion. Absolute dose of Foxtail Millet Vacuum Cushion was similar to absolute dose of bolus and solid water phantom's result in each thickness. it Showed only the difference of 0.1-0.2% between each material. Also the same result in dose distribution comparison. About 97% of the dose distribution was within the margin of error in the prescribed ranges (100{+-}3%), and achieved the enough skin dose (Gross Tumor Volume dose : 100{+-}5%) in radiation therapy planing. We evaluated important fact that Foxtail Millet Vacuum Cushion is no shortage of time to replace the soft tissue equivalent material and normal vacuum cushion at the low energy radiation transmittance. Foxtail Millet Vacuum Cushion can simultaneously achieve the enough skin dose in radiation therapy planing with maintaining normal vacuum cushion' function. Therefore as above We think that Foxtail Millet Vacuum Cushion is very useful in skin cancer radiation treatment.

Soft, Rotating Pneumatic Actuator.

Science.gov (United States)

Ainla, Alar; Verma, Mohit S; Yang, Dian; Whitesides, George M

2017-09-01

This article describes a soft pneumatic actuator that generates cyclical motion. The actuator consists of several (three, four, or five) chambers (arranged around the circumference of a circle surrounding a central rod) that can be actuated independently using negative pressure (or partial vacuum). Sequential actuation of the four-chamber device using reduced pressure moves the central rod cyclically in an approximately square path. We characterize the trajectory of the actuator and the force exerted by it, as we vary the material used for fabrication, the number of chambers, and the size of the actuator. We demonstrate two applications of this actuator: to deliver fluid while stirring (by replacing the central rod with a needle) and for locomotion that mimics a reptilian gait (by combining four actuators together).

OBSERVATIONS OF FIVE-MINUTE SOLAR OSCILLATIONS IN THE CORONA USING THE EXTREME ULTRAVIOLET SPECTROPHOTOMETER (ESP) ON BOARD THE SOLAR DYNAMICS OBSERVATORY EXTREME ULTRAVIOLET VARIABILITY EXPERIMENT (SDO/EVE)

International Nuclear Information System (INIS)

Didkovsky, L.; Judge, D.; Wieman, S.; Kosovichev, A. G.; Woods, T.

2011-01-01

We report on the detection of oscillations in the corona in the frequency range corresponding to five-minute acoustic modes of the Sun. The oscillations have been observed using soft X-ray measurements from the Extreme Ultraviolet Spectrophotometer (ESP) of the Extreme Ultraviolet Variability Experiment on board the Solar Dynamics Observatory. The ESP zeroth-order channel observes the Sun as a star without spatial resolution in the wavelength range of 0.1-7.0 nm (the energy range is 0.18-12.4 keV). The amplitude spectrum of the oscillations calculated from six-day time series shows a significant increase in the frequency range of 2-4 mHz. We interpret this increase as a response of the corona to solar acoustic (p) modes and attempt to identify p-mode frequencies among the strongest peaks. Due to strong variability of the amplitudes and frequencies of the five-minute oscillations in the corona, we study how the spectrum from two adjacent six-day time series combined together affects the number of peaks associated with the p-mode frequencies and their amplitudes. This study shows that five-minute oscillations of the Sun can be observed in the corona in variations of the soft X-ray emission. Further investigations of these oscillations may improve our understanding of the interaction of the oscillation modes with the solar atmosphere, and the interior-corona coupling, in general.

Chemical formation of soft metal electrodes for flexible and wearable electronics.

Science.gov (United States)

Wang, Dongrui; Zhang, Yaokang; Lu, Xi; Ma, Zhijun; Xie, Chuan; Zheng, Zijian

2018-06-18

Flexible and wearable electronics is one major technology after smartphones. It shows remarkable application potential in displays and informatics, robotics, sports, energy harvesting and storage, and medicine. As an indispensable part and the cornerstone of these devices, soft metal electrodes (SMEs) are of great significance. Compared with conventional physical processes such as vacuum thermal deposition and sputtering, chemical approaches for preparing SMEs show significant advantages in terms of scalability, low-cost, and compatibility with the soft materials and substrates used for the devices. This review article provides a detailed overview on how to chemically fabricate SMEs, including the material preparation, fabrication technologies, methods to characterize their key properties, and representative studies on different wearable applications.

Solar ultraviolet hazards

International Nuclear Information System (INIS)

Azmah Ali

1995-01-01

The paper discussed the following subjects: the sources of ultraviolet radiation, solar ultraviolet radiation definition, effects of over exposure to solar ultraviolet radiation, exposure limits and radiation protection of this radiation

Ultraviolet sterilization

International Nuclear Information System (INIS)

Schenck, G.O.

1987-01-01

Artificial ultraviolet radiation sources can supply bactericidal energy in such a high dosage that in less than a second a higher degree of disinfection is accomplished than by sun irradiation in hours. Bacteria, viruses, phages, and organic micropollutants can be degraded by photochemical wet combustion down to and below detection limits of organic carbon. There are no known ultraviolet-resistant microorganisms. There are limitations to ultraviolet treatment which can often be overcome by adequate technical measures. Unlike other water purification processes, ultraviolet irradiation only exterminates living organisms. The radiation must be able to penetrate to the objects of the kill; in a dose large enough to kill, and long enough to kill and prevent new growth. Contrary to filters, ultraviolet flow-through reactors do not restrict free flow significantly. In contrast to distillation, ultraviolet irradiation imposes no phase changes to the water. Used as a sequence in ultrapure water systems, maintenance requirements are virtually nonexistent; because of the absence of dissolved and particulate matter in purified water, mechanical cleaning of the photoreactor chambers is not essential. The process is highly economical; energy consumption is low and supervision minimal. 103 refs., 45 figs., 15 tabs

FY 2000 report on the results of the regional consortium R and D project - Regional consortium energy R and D. Development of new vacuum ultraviolet area optical materials realizing next generation short wavelength optical lithography; 2000 nendo chiiki consortium kenkyu kaihatsu jigyo - chiiki consortium energy kenkyu kaihatsu. Jisedai tanhacho hikari lithography wo jitsugensuru shinku shigaiiki kogaku zairyo no kaihatsu seika hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

As materials for next generation lithography use optical device using short wavelength light sources such as F{sub 2} and Ar{sub 2}, the development was proceeded with of fluoride monocrystal materials and 12-inch class large/high quality monocrystal production technology. Studies were made in the following five fields: 1) proposal/design of new materials and the heightening of performance: 2) establishment of the large/high quality crystal production method; 3) evaluation of optical properties and elucidation of micro-defect formation mechanism; 4) comprehensive investigational research; 5) study of the evaluation technology by vacuum ultraviolet area pulse light. In 1), for the development of the optimum materials, a lot of materials were tried to be monocrystallized, and the permeability was estimated by measuring the reflectance in the vacuum ultraviolet area. As to LiCaAlF{sub 6}, monocrystal with 1-inch diameter was made by the Bridgman method. In 2), studies were made of conditions for large crystal growth by the pull method, large crystal growth by the Bridgman method, and the structure of production equipment for crystals with larger diameter. (NEDO)

Soft-template synthesis of single-crystalline CdS dendrites.

Science.gov (United States)

Niu, Haixia; Yang, Qing; Tang, Kaibin; Xie, Yi; Zhu, Yongchun

2006-01-01

The single-crystalline CdS dendrites have been fabricated from the reaction of CdCl2 and thiourea at 180 degrees C, in which glycine was employed as a soft template. The obtained products were explored by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and selected area electronic diffraction. The optical properties of CdS dendrites have been investigated by ultraviolet and visible light (UV-vis) and photoluminescence techniques. The investigations indicated that the dendrites were grown due to the anisotropic properties enhanced by the use of Glycine in the route.

Vacuum mechatronics

Science.gov (United States)

Hackwood, Susan; Belinski, Steven E.; Beni, Gerardo

1989-01-01

The discipline of vacuum mechatronics is defined as the design and development of vacuum-compatible computer-controlled mechanisms for manipulating, sensing and testing in a vacuum environment. The importance of vacuum mechatronics is growing with an increased application of vacuum in space studies and in manufacturing for material processing, medicine, microelectronics, emission studies, lyophylisation, freeze drying and packaging. The quickly developing field of vacuum mechatronics will also be the driving force for the realization of an advanced era of totally enclosed clean manufacturing cells. High technology manufacturing has increasingly demanding requirements for precision manipulation, in situ process monitoring and contamination-free environments. To remove the contamination problems associated with human workers, the tendency in many manufacturing processes is to move towards total automation. This will become a requirement in the near future for e.g., microelectronics manufacturing. Automation in ultra-clean manufacturing environments is evolving into the concept of self-contained and fully enclosed manufacturing. A Self Contained Automated Robotic Factory (SCARF) is being developed as a flexible research facility for totally enclosed manufacturing. The construction and successful operation of a SCARF will provide a novel, flexible, self-contained, clean, vacuum manufacturing environment. SCARF also requires very high reliability and intelligent control. The trends in vacuum mechatronics and some of the key research issues are reviewed.

Effects of ultraviolet and electron radiations on graphite-reinforced polysulfone and epoxy resins

International Nuclear Information System (INIS)

Giori, C.; Yamauchi, T.

1984-01-01

Degradation mechanisms have been investigated for graphite/polysulfone and graphite/epoxy laminates exposed to ultraviolet and high-energy electron radiations in vacuum up to 960 equivalent sun hours and 10 9 rads, respectively. Based on GC and combined GC/MS analysis of volatile by-products evolved during irradiation, several free radical mechanisms of composite degradation have been identified. All the composite materials evaluated have shown high electron radiation stability and relatively low ultraviolet stability as indicated by low G values and high quantum yields for gas formation. Mechanical property measurements of irradiated samples did not reveal significant changes, with the possible exception of UV exposed polysulfone laminates. Hydrogen and methane have been identified as the main byproducts of irradiation, along with unexpectedly high levels of CO and CO 2 . Initial G values for methane relative to hydrogen formation are higher in the presence of isopropylidene linkages, which occur in bisphenol-A resins

Electronic excitation of carbonyl sulphide (COS) by high-resolution vacuum ultraviolet photoabsorption and electron-impact spectroscopy in the energy region from 4 to 11 eV

Energy Technology Data Exchange (ETDEWEB)

Limão-Vieira, P., E-mail: plimaovieira@fct.unl.pt [Laboratório de Colisões Atómicas e Moleculares, CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Department of Physics, Sophia University, Tokyo 102-8554 (Japan); Department of Physical Sciences, The Open University, Walton Hall, Milton Keynes MK7 6AA (United Kingdom); Ferreira da Silva, F.; Almeida, D. [Laboratório de Colisões Atómicas e Moleculares, CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Hoshino, M.; Tanaka, H. [Department of Physics, Sophia University, Tokyo 102-8554 (Japan); Mogi, D. [Development and Marketing Department, New Products Development Division, Kanto Denka, Kogyo Co., Ltd., Chiyoda-ku, Tokyo 101-0063 (Japan); Tanioka, T. [Shibukawa Development Research Laboratory, New Products Development Division, Kanto Denka Kogyo Co., Ltd., Shibukawa City, Gunma 377-8513 (Japan); Mason, N. J. [Department of Physical Sciences, The Open University, Walton Hall, Milton Keynes MK7 6AA (United Kingdom); Hoffmann, S. V. [ISA, Department of Physics and Astronomy, Aarhus University, Ny Munkegade 120, DK-8000 Århus C (Denmark); Hubin-Franskin, M.-J.; Delwiche, J. [Départment de Chimie, Université de Liège, Institut de Chimie-Bât. B6C, allée de la Chimie 3, B-4000 Liège 1 (Belgium)

2015-02-14

The electronic state spectroscopy of carbonyl sulphide, COS, has been investigated using high resolution vacuum ultraviolet photoabsorption spectroscopy and electron energy loss spectroscopy in the energy range of 4.0–10.8 eV. The spectrum reveals several new features not previously reported in the literature. Vibronic structure has been observed, notably in the low energy absorption dipole forbidden band assigned to the (4π←3π) ({sup 1}Δ←{sup 1}Σ{sup +}) transition, with a new weak transition assigned to ({sup 1}Σ{sup −}←{sup 1}Σ{sup +}) reported here for the first time. The absolute optical oscillator strengths are determined for ground state to {sup 1}Σ{sup +} and {sup 1}Π transitions. Based on our recent measurements of differential cross sections for the optically allowed ({sup 1}Σ{sup +} and {sup 1}Π) transitions of COS by electron impact, the optical oscillator strength f{sub 0} value and integral cross sections (ICSs) are derived by applying a generalized oscillator strength analysis. Subsequently, ICSs predicted by the scaling are confirmed down to 60 eV in the intermediate energy region. The measured absolute photoabsorption cross sections have been used to calculate the photolysis lifetime of carbonyl sulphide in the upper stratosphere (20–50 km)

Malignant transformation of guinea pig cells after exposure to ultraviolet-irradiated guinea pig cytomegalovirus

International Nuclear Information System (INIS)

Isom, H.C.; Mummaw, J.; Kreider, J.W.

1983-01-01

Guinea pig cells were malignantly transformed in vitro by ultraviolet (uv)-irradiated guinea pig cytomegalovirus (GPCMV). When guinea pig hepatocyte monolayers were infected with uv-irradiated GPCMV, three continuous epithelioid cell lines which grew in soft agarose were established. Two independently derived GPCMV-transformed liver cells and a cell line derived from a soft agarose clone of one of these lines induced invasive tumors when inoculated subcutaneously or intraperitoneally into nude mice. The tumors were sarcomas possibly derived from hepatic stroma or sinusoid. Transformed cell lines were also established after infection of guinea pig hepatocyte monolayers with human cytomegalovirus (HCMV) or simian virus 40 (SV40). These cell lines also formed colonies in soft agarose and induced sarcomas in nude mice. It is concluded that (i) GPCMV can malignantly transform guinea pig cells; (ii) cloning of GPCMV-transformed cells in soft agarose produced cells that induced tumors with a shorter latency period but with no alteration in growth rate or final tumor size; and (iii) the tumors produced by GPCMV-and HCMV-transformed guinea pig cells were more similar to each other in growth rate than to those induced by SV40-transformed guinea pig cells

Decay constants in soft wall AdS/QCD revisited

Energy Technology Data Exchange (ETDEWEB)

Braga, Nelson R.F., E-mail: braga@if.ufrj.br [Instituto de Física, Universidade Federal do Rio de Janeiro, Caixa Postal 68528, RJ 21941-972 (Brazil); Diles, Saulo, E-mail: smdiles@if.ufrj.br [Instituto de Física, Universidade Federal do Rio de Janeiro, Caixa Postal 68528, RJ 21941-972 (Brazil); Contreras, M.A. Martin, E-mail: ma.martin41@uniandes.edu.co [High Energy Group, Department of Physics, Universidad de los Andes, Carrera 1, No 18A-10, Bloque Ip, ZIP 111711, Bogotá (Colombia)

2016-12-10

Phenomenological AdS/QCD models, like hard wall and soft wall, provide hadronic mass spectra in reasonable consistency with experimental and (or) lattice results. These simple models are inspired in the AdS/CFT correspondence and assume that gauge/gravity duality holds in a scenario where conformal invariance is broken through the introduction of an energy scale. Another important property of hadrons: the decay constant, can also be obtained from these models. However, a consistent formulation of an AdS/QCD model that reproduces the observed behavior of decay constants of vector meson excited states is still lacking. In particular: for radially excited states of heavy vector mesons, the experimental data lead to decay constants that decrease with the radial excitation level. We show here that a modified framework of soft wall AdS/QCD involving an additional dimensionfull parameter, associated with an ultraviolet energy scale, provides decay constants decreasing with radial excitation level. In this version of the soft wall model the two point function of gauge theory operators is calculated at a finite position of the anti-de Sitter space radial coordinate.

Resolving the origin of the diffuse soft X-ray background

Energy Technology Data Exchange (ETDEWEB)

Smith, Randall K.; Foster, Adam R.; Edgar, Richard J.; Brickhouse, Nancy S. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge MA 02138 (United States)

2014-05-20

The ubiquitous diffuse soft (1/4 keV) X-ray background was one of the earliest discoveries of X-ray astronomy. At least some of the emission may arise from charge exchange between solar wind ions and neutral atoms in the heliosphere, but no detailed models have been fit to the available data. Here, we report on a new model for charge exchange in the solar wind, which, when combined with a diffuse hot plasma component, filling the Local Cavity provides a good fit to the only available high-resolution soft X-ray and extreme ultraviolet spectra using plausible parameters for the solar wind. The implied hot plasma component is in pressure equilibrium with the local cloud that surrounds the solar system, creating for the first time a self-consistent picture of the local interstellar medium.

The effect of the operation modes of a gas discharge low-pressure amalgam lamp on the intensity of generation of 185 nm UV vacuum radiation

Energy Technology Data Exchange (ETDEWEB)

Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru [Russian Academy of Sciences, Joint Institute of High Temperatures (Russian Federation); Drozdov, L. A., E-mail: lit@npo.lit.ru; Kostyuchenko, S. V.; Sokolov, D. V. [ZAO LIT (Russian Federation); Kudryavtsev, N. N.; Sobur, D. A., E-mail: soburda@gmail.com [Moscow Institute for Physics and Technology (Russian Federation)

2011-12-15

The effect of the discharge current, mercury vapor pressure, and the inert gas pressure on the intensity and efficiency of the 185 nm line generation are considered. The spectra of the UV radiation (vacuum ultraviolet) transmission by protective coatings from the oxides of rare earth metals and aluminum are investigated.

Vacuum-ultraviolet reflectometer

Science.gov (United States)

Allen, T. H.; Dillow, C. F.; Linford, R. M. F.

1977-01-01

Baffle, three-blade chopper, and split spherical mirror transmit alternating dual beam into integrating sphere. Alternating reference and sample beams are detected by high gain photomultiplier and modified logarithmic ratiometer. Device is useful in fusion research, high power laser work, and spectrometer or monochromator construction.

A development of laser-plasma-based soft x-ray microscope system

International Nuclear Information System (INIS)

Nam, Ki Yong; Kim, Kyong Woo; Kim, Kyu Gyeom; Kwon, Young Man; Yoon, Kwon Ha

2003-01-01

Soft x-ray nano-imaging microscopy system for biomedical application with a high resolution about 50 nm has been designed and described, and its integrated techniques also have been studied. The system is mainly composed of soft x-ray generation system, nano-scaled control system, x-ray optical device like a condenser or object mirror, a CCD camera coupled with multichannel plate (MCP) and vacuum system. In the system, soft x-ray is generated from the laser-based plasma by focusing Nd:YAG laser beam on tantalum (Ta) target. In an x-ray optical system, a wolter mirror has been considering condensing the x-ray beam on a biological specimen and zone plate was adapted as an object mirror. A Si 3 N 4 was used as specimen holder for keeping a biological sample alive in atmosphere conditions. A back-illuminated-CCD camera coupled with multichannel plate was determined to set up.

A development of laser-plasma-based soft x-ray microscope system

Energy Technology Data Exchange (ETDEWEB)

Nam, Ki Yong; Kim, Kyong Woo; Kim, Kyu Gyeom; Kwon, Young Man; Yoon, Kwon Ha [X-ray Microscopy Research Center, Wonkwang University, Iksan (Korea, Republic of)

2003-07-01

Soft x-ray nano-imaging microscopy system for biomedical application with a high resolution about 50 nm has been designed and described, and its integrated techniques also have been studied. The system is mainly composed of soft x-ray generation system, nano-scaled control system, x-ray optical device like a condenser or object mirror, a CCD camera coupled with multichannel plate (MCP) and vacuum system. In the system, soft x-ray is generated from the laser-based plasma by focusing Nd:YAG laser beam on tantalum (Ta) target. In an x-ray optical system, a wolter mirror has been considering condensing the x-ray beam on a biological specimen and zone plate was adapted as an object mirror. A Si{sub 3}N{sub 4} was used as specimen holder for keeping a biological sample alive in atmosphere conditions. A back-illuminated-CCD camera coupled with multichannel plate was determined to set up.

Analytical solutions for a single vertical drain with time-dependent vacuum combined surcharge preloading in membrane and membraneless systems

International Nuclear Information System (INIS)

Geng, X Y; Indraratna, B; Rujikiatkamjorn, C

2010-01-01

Vertical drains combined with vacuum pressure and surcharge preloading are widely used to accelerate the consolidation process of soft clay in order to decrease the pore pressure as well as to increase the effective stress. Currently there are two types of vacuum preloading systems commercially available; (a) membrane system with an airtight membrane over the drainage layer and, (b) membraneless system where a vacuum system is connected to individual drain. Their effectiveness varies from site to site depending on the type of soil treated and the characteristics of the drain-vacuum system. This study presents the analytical solutions of vertical drains with vacuum preloading for both membrane and membraneless systems. According to the field and laboratory observations, the vacuum in both of the membraneless and membrane system was assumed to be decreasing along the drain whereas in the membrane system, it was maintained at a constant level. This model was verified by using the measured settlements and excess pore pressures obtained from large-scale laboratory testing and case studies in Australia. The analytical solutions improved the accuracy of predicting the dissipation of pore water pressure and the associated settlement. The effects of the permeability of the sand blanket in a membrane system and the possible loss of vacuum were also discussed.

Bipolar soft connected, bipolar soft disconnected and bipolar soft compact spaces

Directory of Open Access Journals (Sweden)

Muhammad Shabir

2017-06-01

Full Text Available Bipolar soft topological spaces are mathematical expressions to estimate interpretation of data frameworks. Bipolar soft theory considers the core features of data granules. Bipolarity is important to distinguish between positive information which is guaranteed to be possible and negative information which is forbidden or surely false. Connectedness and compactness are the most important fundamental topological properties. These properties highlight the main features of topological spaces and distinguish one topology from another. Taking this into account, we explore the bipolar soft connectedness, bipolar soft disconnectedness and bipolar soft compactness properties for bipolar soft topological spaces. Moreover, we introduce the notion of bipolar soft disjoint sets, bipolar soft separation, and bipolar soft hereditary property and study on bipolar soft connected and disconnected spaces. By giving the detailed picture of bipolar soft connected and disconnected spaces we investigate bipolar soft compact spaces and derive some results related to this concept.

Degradation and Its Control of Ultraviolet Avalanche Photodiodes Using PEDOT:PSS/ZnSSe Organic-Inorganic Hybrid Structure

Science.gov (United States)

Abe, Tomoki; Uchida, Shigeto; Tanaka, Keita; Fujisawa, Takanobu; Kasada, Hirofumi; Ando, Koshi; Akaiwa, Kazuaki; Ichino, Kunio

2018-05-01

We investigated device degradation in PEDOT:PSS/ZnSSe organic-inorganic hybrid ultraviolet avalanche photodiodes (UV-APDs). ZnSSe/n-GaAs wafers were grown by molecular beam epitaxy, and PEDOT:PSS window layers were formed by inkjet technique. We observed rapid degradation with APD-mode stress (˜ 30 V) in the N2 (4 N) atmosphere, while we observed no marked change in forward bias current stress and photocurrent stress. In the case of a vacuum condition, we observed no detectable degradation in the dark avalanche current with APD-mode stress. Therefore, the degradation in the PEDOT:PSS/ZnSSe interface under the APD-mode stress was caused by the residual water vapor or oxygen in the N2 atmosphere and could be controlled by vacuum packaging.

Soft x-ray transmission measurements on thin films used for XMM CCD-filters

Science.gov (United States)

Stephan, K.-H.; Reppin, C.; Maier, H. J.; Frischke, D.; Fuchs, D.; Müller, P.

1997-02-01

We have been developing optical filters for ESA's X-ray astronomy project XMM (X-ray Multi Mirror Mission). Specific CCDs will be used as detectors in the focal plane on board the observatory (1). Since these detectors are sensitive from the X-ray to the near infrared spectral range, X-ray observations require optical filters, which combine a high transparency for photon energies in the soft X-ray region and a high opacity for ultraviolet and visible radiation as well. With respect to the mission goal in orbit three types of flight model filters are designed having different spectral transmittance functions. We report on one of these types, a so-called "thick" filter, which has been realized within the EQM (Electrical Qualification Model)-phase of the project. The filter features a cut-off in the extreme ultraviolet spectral range and suppresses radiation below ˜10 eV photon energy by more than 8 orders of magnitude. It has an effective aperture of 73 mm without any support structure. A 0.35 μm thick polypropylene carrier foil is coated with metallic films of Al and Sn. We describe transmission measurements in the soft X-ray photon energy range to determine the thickness of the individual layers and present the optical performance data of the filter.

New measurements on water ice photodesorption and product formation under ultraviolet irradiation

Science.gov (United States)

Cruz-Diaz, Gustavo A.; Martín-Doménech, Rafael; Moreno, Elena; Muñoz Caro, Guillermo M.; Chen, Yu-Jung

2018-03-01

The photodesorption of icy grain mantles has been claimed to be responsible for the abundance of gas-phase molecules towards cold regions. Being water a ubiquitous molecule, it is crucial to understand its role in photochemistry and its behaviour under an ultraviolet field. We report new measurements on the ultraviolet (UV) photodesorption of water ice and its H2, OH, and O2 photoproducts using a calibrated quadrupole mass spectrometer. Solid water was deposited under ultra-high-vacuum conditions and then UV-irradiated at various temperatures starting from 8 K with a microwave discharged hydrogen lamp. Deuterated water was used for confirmation of the results. We found a photodesorption yield of 1.3 × 10-3 molecules per incident photon for water and 0.7 × 10-3 molecules per incident photon for deuterated water at the lowest irradiation temperature, 8 K. The photodesorption yield per absorbed photon is given and comparison with astrophysical scenarios, where water ice photodesorption could account for the presence of gas-phase water towards cold regions in the absence of a thermal desorption process, is addressed.

Derivation of the cut-off length from the quantum quadratic enhancement of a mass in vacuum energy constant Lambda

Science.gov (United States)

Fukushima, Kimichika; Sato, Hikaru

2018-04-01

Ultraviolet self-interaction energies in field theory sometimes contain meaningful physical quantities. The self-energies in such as classical electrodynamics are usually subtracted from the rest mass. For the consistent treatment of energies as sources of curvature in the Einstein field equations, this study includes these subtracted self-energies into vacuum energy expressed by the constant Lambda (used in such as Lambda-CDM). In this study, the self-energies in electrodynamics and macroscopic classical Einstein field equations are examined, using the formalisms with the ultraviolet cut-off scheme. One of the cut-off formalisms is the field theory in terms of the step-function-type basis functions, developed by the present authors. The other is a continuum theory of a fundamental particle with the same cut-off length. Based on the effectiveness of the continuum theory with the cut-off length shown in the examination, the dominant self-energy is the quadratic term of the Higgs field at a quantum level (classical self-energies are reduced to logarithmic forms by quantum corrections). The cut-off length is then determined to reproduce today's tiny value of Lambda for vacuum energy. Additionally, a field with nonperiodic vanishing boundary conditions is treated, showing that the field has no zero-point energy.

Soft X-ray spectromicroscopy of biological and synthetic polymer systems

International Nuclear Information System (INIS)

Hitchcock, A.; Morin, C.; Araki, T.; Zhang, X.; Dynes, J.; Stover, H.; Brash, J.

2004-01-01

Full text: Scanning transmission X-ray microscopy (STXM) and X-ray photoemission electron microscopy (X-PEEM) are synchrotron based, soft X-ray spectromicroscopy techniques which provide chemical speciation at 50 nm spatial resolution based on near edge X-ray absorption spectral (NEXAFS) contrast. The instrumentation and techniques of soft X-ray spectro- microscopy will be described and illustrated with applications to wet biofilms, protein interactions with patterned polymer surfaces, and polymer microstructure optimization. STXM can be applied to samples in air, He, vacuum, or a fully hydrated environment. With many collaborators, my group is using STXM to study fundamental and applied aspects of polymer microstructure, to map metal ions and anti-microbial agents in wet biofilms, and to identify sites of selective adsorption of proteins on phase separated polymer thin films in the presence of an overlayer of protein solution. X-PEEM has greater surface sensitivity than STXM but requires a flat, conductive, and vacuum-compatible sample. Comparison of X-PEEM and STXM for the same system - fibrinogen adsorption on a PS:PMMA blend, will be used to illustrate advantages and limitations of each technique. Measurements at 5.3.2 STXM and 7.3.1 PEEM at the Advanced Light Source, funded by DoE under contract DE-AC03- 76SF00098. Research supported by NSERC (Canada), AFMnet (Advanced Food and Biomaterials Network) and the Canada Research Chair program

Device quality ZnO grown using a Filtered Cathodic Vacuum Arc

International Nuclear Information System (INIS)

Elzwawi, Salim; Kim, Hyung Suk; Heinhold, Robert; Lynam, Max; Turner, Gary; Partridge, Jim G.; McCulloch, Dougal G.

2012-01-01

In this paper we report on the structural, electrical and optical characteristics of unintentionally doped ZnO films grown on a-plane sapphire substrates using the Filtered Cathodic Vacuum Arc (FCVA) technique. The resulting films showed considerable promise for device applications with properties including high transparency, moderate intrinsic carrier concentrations (10 17 -10 19 cm -3 ), electron mobilities up to 30 cm 2 /Vs, low surface roughness (typically <2% of film thickness) and well-structured photoluminescence. Post-annealing in oxygen at temperatures up to 800 °C produced significant improvements in the properties of these films. Silver oxide Schottky diodes fabricated on FCVA ZnO showed ideality factors as low as 1.20 and good sensitivity to ultraviolet light.

MEA vacuum system

International Nuclear Information System (INIS)

Stroo, R.; Schwebke, H.; Heine, E.

1984-01-01

This report describes construction and operation of the MEA vacuum system of NIKHEF (Netherlands). First, the klystron vacuum system, beam transport system, diode pump and a triode pump are described. Next, the isolation valve and the fast valves of the vacuum system are considered. Measuring instruments, vacuum system commands and messages of failures are treated in the last chapter. (G.J.P.)

EXOSAT observations of a strong soft X-ray excess in MKN841

International Nuclear Information System (INIS)

Arnaud, K.A.; Fabian, A.C.; Shafer, R.A.; Tennant, A.F.; Ward, M.J.; Hazard, C.

1985-01-01

EXOSAT observations of the spectrum of the Seyfert 1 galaxy MKN 841 show that it is well-fitted by a power law of photon index 1.6, similar to that of other Seyferts, and a large additional soft component. The X-ray luminosity over the observed band exceeds 4x10 44 erg s -1 . A single-temperature blackbody fit to the soft X-rays and the short-wavelength ultraviolet continuum gives a luminosity of 2x10 46 erg s -1 while an accretion disc spectrum fitted to the same points gives a luminosity of 4.3x10 45 erg s -1 . The flux measured by both the EXOSAT low- and medium-energy instruments exhibits 12 per cent amplitude variability on a time-scale of one day. (author)

Optimization of northern analysis by vacuum-blotting, RNA-transfer visualization, and ultraviolet fixation

International Nuclear Information System (INIS)

Kroczek, R.A.; Siebert, E.

1990-01-01

We have optimized Northern analysis at several steps. Overnight electrophoresis was replaced by short gel runs and overnight capillary transfer by rapid vacuum-blotting adapted to Northern analysis. Short uv irradiation was used as a substitute for the usual RNA fixation by baking. Direct staining of RNA before electrophoresis made it possible to check RNA integrity and to evaluate the quality of the size separation immediately after electrophoresis. In this system, RNA transfer onto the membrane support could also be quickly assessed after the blotting step. The net result of all modifications was a doubling of the autoradiography signal compared with that obtained by modern Northern protocols. At the same time, the duration of the procedure was shortened drastically, allowing an autoradiography signal to be obtained within 24 h

Exploratory studies on a passively triggered vacuum spark

Energy Technology Data Exchange (ETDEWEB)

Rout, R.K. [High Pressure Physics Division, Bhabha Atomic Research Centre, Mumbai (India)]. E-mail: rkrout@apsara.barc.ernet.in; Auluck, S.K.H.; Kulkarni, L.V. [High Pressure Physics Division, Bhabha Atomic Research Centre, Mumbai, India (India); Nagpal, J.S. [Radiation Standards and Instrumentation Division, Bhabha Atomic Research Centre, Mumbai (India)

1999-12-07

The results of an experimental investigation on a passively triggered vacuum spark device are presented. The diagnostics include the current, x-ray and optical emission measurements. The sharp dips in the current derivative signal indicate the occurrence of pinching at an early stage of the discharge (at current {approx} 5 kA). A well-confined plasma with a central hot region was recorded using a streak camera. The pinched plasma was observed to undergo kink-type oscillations with a time period of 10-15 ns. Repeated plasma fronts were seen to move from the anode to the cathode with an average velocity of {approx}5x10{sup 6} cm s{sup -1}. Soft x-ray emission having a radiation intensity of a few hundred mR per discharge was observed. The x-ray signals obtained using photodiodes showed multiple bursts. A soft x-ray pinhole camera recorded micro-pinches of {approx}100 {mu}m. The x-ray emitting regions were confined to the inter-electrode gap. The x-ray emission characteristics were influenced by the electrolytic resistance, which was connected across the spark gap to initiate discharge. (author)

Laser-induced plasma from pure and doped water-ice at high fluence by ultraviolet and infrared radiation - art. no. 70050X

DEFF Research Database (Denmark)

Schou, Jørgen; Matei, A.; Rodrigo, Katarzyna Agnieszka

2008-01-01

Ice made of ultrapure water or water doped with 1 % polymer (polyethylene glycol, "PEG") was irradiated by laser light with fluences between 2 and 80 J/cm(2) in the ultraviolet (UV) regime at 355 nm and in the infrared (IR) regime at 1064 nm in vacuum. In the UV regime there is a threshold for pl...... of ionization breakdown at the ice surface....

Insulation vacuum and beam vacuum overpressure release

CERN Document Server

Parma, V

2009-01-01

There is evidence that the incident of 19th September caused a high pressure build-up inside the cryostat insulation vacuum which the existing overpressure devices could not contain. As a result, high longitudinal forces acting on the insulation vacuum barriers developed and broke the floor and the floor fixations of the SSS with vacuum barriers. The consequent large longitudinal displacements of the SSS damaged chains of adjacent dipole cryo-magnets. Estimates of the helium mass flow and the pressure build- up experienced in the incident are presented together with the pressure build-up for an even more hazardous event, the Maximum Credible Incident (MCI). The strategy of limiting the maximum pressure by the installation of addition pressure relieve devices is presented and discussed. Both beam vacuum lines were ruptured during the incident in sector 3-4 giving rise to both mechanical damage and pollution of the system. The sequence, causes and effects of this damage will be briefly reviewed. We will then an...

Resolving the Origin of the Diffuse Soft X-ray Background

Science.gov (United States)

Smith, Randall K.; Foster, Adam R.; Edgar, Ricard J.; Brickhouse, Nancy S.; Sanders, Wilton T.

2012-01-01

In January 1993, the Diffuse X-ray Spectrometer (DXS) measured the first high-resolution spectrum of the diffuse soft X-ray background between 44-80A. A line-dominated spectrum characteristic of a 10(exp 6)K collisionally ionized plasma' was expected but while the observed spectrum was clearly line-dominated, no model would fit. Then in 2003 the Cosmic Hot Interstellar Plasma Spectrometer (CHIPS) launched and observed the diffuse extreme-ultraviolet (EUV) spectrum between 90- 265A. Although many emission lines were again expected; only Fe IX at 171.1A was detected. The discovery of X-rays from comets led to the realization that heavy ions (Z=6-28) in the solar wind will emit soft X-rays as the ions interact via charge exchange with neutral atoms in the heliosphere and geocorona. Using a new model for solar wind charge exchange (SWCX) emission, we show that the diffuse soft X-ray background can be understood as a combination of emission from charge exchange onto the slow and fast solar wind together with a more distant and diffuse hot (10(exp 6)K) plasma.

Advanced light source vacuum policy and vacuum guidelines for beamlines and experiment endstations

International Nuclear Information System (INIS)

Hussain, Z.

1995-08-01

The purpose of this document is to: (1) Explain the ALS vacuum policy and specifications for beamlines and experiment endstations. (2) Provide guidelines related to ALS vacuum policy to assist in designing beamlines which are in accordance with ALS vacuum policy. This document supersedes LSBL-116. The Advanced Light Source is a third generation synchrotron radiation source whose beam lifetime depends on the quality of the vacuum in the storage ring and the connecting beamlines. The storage ring and most of the beamlines share a common vacuum and are operated under ultra-high-vacuum (UHV) conditions. All endstations and beamline equipment must be operated so as to avoid contamination of beamline components, and must include proper safeguards to protect the storage ring vacuum from an accidental break in the beamline or endstation vacuum systems. The primary gas load during operation is due to thermal desorption and electron/photon induced desorption of contaminants from the interior of the vacuum vessel and its components. The desorption rates are considerably higher for hydrocarbon contamination, thus considerable emphasis is placed on eliminating these sources of contaminants. All vacuum components in a beamline and endstation must meet the ALS vacuum specifications. The vacuum design of both beamlines and endstations must be approved by the ALS Beamline Review Committee (BRC) before vacuum connections to the storage ring are made. The vacuum design is first checked during the Beamline Design Review (BDR) held before construction of the beamline equipment begins. Any deviation from the ALS vacuum specifications must be approved by the BRC prior to installation of the equipment on the ALS floor. Any modification that is incorporated into a vacuum assembly without the written approval of the BRC is done at the user's risk and may lead to rejection of the whole assembly

The valence and Rydberg states of difluoromethane: A combined experimental vacuum ultraviolet spectrum absorption and theoretical study by ab initio configuration interaction and density functional computations

Science.gov (United States)

Palmer, Michael H.; Vrønning Hoffmann, Søren; Jones, Nykola C.; Coreno, Marcello; de Simone, Monica; Grazioli, Cesare

2018-06-01

The vacuum ultraviolet (VUV) spectrum for CH2F2 from a new synchrotron study has been combined with earlier data and subjected to detailed scrutiny. The onset of absorption, band I and also band IV, is resolved into broad vibrational peaks, which contrast with the continuous absorption previously claimed. A new theoretical analysis, using a combination of time dependent density functional theory (TDDFT) calculations and complete active space self-consistent field, leads to a major new interpretation. Adiabatic excitation energies (AEEs) and vertical excitation energies, evaluated by these methods, are used to interpret the spectra in unprecedented detail using theoretical vibronic analysis. This includes both Franck-Condon (FC) and Herzberg-Teller (HT) effects on cold and hot bands. These results lead to the re-assignment of several known excited states and the identification of new ones. The lowest calculated AEE sequence for singlet states is 11B1 ˜ 11A2 expected; the onset of the 15.5 eV band shows a set of vibrational peaks, but the vibration frequency does not correspond to any of the photoelectron spectral (PES) structure and is clearly valence in nature. The routine use of PES footprints to detect Rydberg states in VUV spectra is shown to be inadequate. The combined effects of FC and HT in the VUV spectral bands lead to additional vibrations when compared with the PES.

Method for the protection of extreme ultraviolet lithography optics

Science.gov (United States)

Grunow, Philip A.; Clift, Wayne M.; Klebanoff, Leonard E.

2010-06-22

A coating for the protection of optical surfaces exposed to a high energy erosive plasma. A gas that can be decomposed by the high energy plasma, such as the xenon plasma used for extreme ultraviolet lithography (EUVL), is injected into the EUVL machine. The decomposition products coat the optical surfaces with a protective coating maintained at less than about 100 .ANG. thick by periodic injections of the gas. Gases that can be used include hydrocarbon gases, particularly methane, PH.sub.3 and H.sub.2S. The use of PH.sub.3 and H.sub.2S is particularly advantageous since films of the plasma-induced decomposition products S and P cannot grow to greater than 10 .ANG. thick in a vacuum atmosphere such as found in an EUVL machine.

Measuring device for soft X-rays

International Nuclear Information System (INIS)

Dissing, E.

1978-09-01

An instrument for the measurement of the absorbed energy per unit area of diagnostic X-rays in soft human tissue was developed. The instrument is intended for dosimetry applications in the field of dental and small skeleton radiography and for mammography. The detector assembly consists of a Polyvinyltoluene scintillator 2.54 diametre x 5.08 cm CsSb semitransparent head-on vacuum phototube. Polyvinyltoluene being a pure hydrocarbon may be considered a good representative material of human soft tissue concerning the absorption of X-rays. In the photon energy range of interest, 5 - 40 keV, the mass energy absorption coefficient for muscle tissue and for PVT differ about a factor 2 due to the considerable content of Oxygen in muscle tissue. This is to some extend reflected in the photon energy response characteristic for the instrument. For human adipose, the characteristic is practically flat from 5- 40 keV. The instrument is integrating the absorbed power per unit area and the digital display shows Joules/m 2 . The range for the instrument is from 000.1 μJ/m 2 to 19.99 J/m 2 (absorbed energy in 5 cm tissue). (author)

Two-speed phacoemulsification for soft cataracts using optimized parameters and procedure step toolbar with the CENTURION Vision System and Balanced Tip.

Science.gov (United States)

Davison, James A

2015-01-01

To present a cause of posterior capsule aspiration and a technique using optimized parameters to prevent it from happening when operating soft cataracts. A prospective list of posterior capsule aspiration cases was kept over 4,062 consecutive cases operated with the Alcon CENTURION machine and Balanced Tip. Video analysis of one case of posterior capsule aspiration was accomplished. A surgical technique was developed using empirically derived machine parameters and customized setting-selection procedure step toolbar to reduce the pace of aspiration of soft nuclear quadrants in order to prevent capsule aspiration. Two cases out of 3,238 experienced posterior capsule aspiration before use of the soft quadrant technique. Video analysis showed an attractive vortex effect with capsule aspiration occurring in 1/5 of a second. A soft quadrant removal setting was empirically derived which had a slower pace and seemed more controlled with no capsule aspiration occurring in the subsequent 824 cases. The setting featured simultaneous linear control from zero to preset maximums for: aspiration flow, 20 mL/min; and vacuum, 400 mmHg, with the addition of torsional tip amplitude up to 20% after the fluidic maximums were achieved. A new setting selection procedure step toolbar was created to increase intraoperative flexibility by providing instantaneous shifting between the soft and normal settings. A technique incorporating a reduced pace for soft quadrant acquisition and aspiration can be accomplished through the use of a dedicated setting of integrated machine parameters. Toolbar placement of the procedure button next to the normal setting procedure button provides the opportunity to instantaneously alternate between the two settings. Simultaneous surgeon control over vacuum, aspiration flow, and torsional tip motion may make removal of soft nuclear quadrants more efficient and safer.

Laser Plasma Soft X-ray Microscope with Wolter Mirrors for Observation of Biological Specimens in Air

Science.gov (United States)

Hoshino, Masato; Aoki, Sadao

2006-02-01

A laser plasma soft X-ray microscope with Wolter mirrors was developed so that specimens could be set in the atmosphere. Silicon nitride membranes 100 nm thick were used as vacuum-tight windows. Using relatively large windows (0.46× 0.46 mm2), an adequate working distance for samples, which was approximately 1.2 mm, was assured. The endurance of the vacuum-tight window was measured briefly. Dry biological cells could be observed with resolution better than 100 nm. A preliminary observation of wet biological cells was carried out using a wet environmental sample holder which was composed of only two sheets of silicon nitride membrane. An X-ray micrograph of wet red blood cells from a chicken was obtained without apparent effects of radiation damage. The properties of a vacuum-tight window and a wet sample holder are discussed.

Laser plasma soft x-ray microscope with Wolter mirrors for observation of biological specimens in air

International Nuclear Information System (INIS)

Hoshino, Masato; Aoki, Sadao

2006-01-01

A laser plasma soft X-ray microscope with Wolter mirrors was developed so that specimens could be set in the atmosphere. Silicon nitride membranes 100 nm thick were used as vacuum-tight windows. Using relatively large windows (0.46 x 0.46 mm 2 ), an adequate working distance for samples, which was approximately 1.2 mm, was assured. The endrance of the vacuum-tight window was measured briefly. Dry biological cells could be observed with resolution better than 100 nm. A preliminary observation of wet biological cells was carried out using a wet environmental sample holder which was composed of only two sheets of silicon nitride membrane. An X-ray micrograph of wet red blood cells from a chicken was obtained without apparent effects of radiation damage. The properties of a vacuum-tight window and a wet sample holder are discussed. (author)

Ultra-high vacuum compatible optical chopper system for synchrotron x-ray scanning tunneling microscopy

Energy Technology Data Exchange (ETDEWEB)

Chang, Hao, E-mail: hc000211@ohio.edu [Advanced Photon Source, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439 (United States); Nanoscale and Quantum Phenomena Institute, Physics & Astronomy Department, Ohio University, Athens, Ohio 45701 (United States); Cummings, Marvin; Shirato, Nozomi; Stripe, Benjamin; Preissner, Curt; Freeland, John W. [Advanced Photon Source, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439 (United States); Rosenmann, Daniel [Center for Nanoscale Materials, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439 (United States); Kersell, Heath; Hla, Saw-Wai [Nanoscale and Quantum Phenomena Institute, Physics & Astronomy Department, Ohio University, Athens, Ohio 45701 (United States); Center for Nanoscale Materials, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439 (United States); Rose, Volker, E-mail: vrose@anl.gov [Advanced Photon Source, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439 (United States); Center for Nanoscale Materials, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439 (United States)

2016-01-28

High-speed beam choppers are a crucial part of time-resolved x-ray studies as well as a necessary component to enable elemental contrast in synchrotron x-ray scanning tunneling microscopy (SX-STM). However, many chopper systems are not capable of operation in vacuum, which restricts their application to x-ray studies with high photon energies, where air absorption does not present a significant problem. To overcome this limitation, we present a fully ultra-high vacuum (UHV) compatible chopper system capable of operating at variable chopping frequencies up to 4 kHz. The lightweight aluminum chopper disk is coated with Ti and Au films to provide the required beam attenuation for soft and hard x-rays with photon energies up to about 12 keV. The chopper is used for lock-in detection of x-ray enhanced signals in SX-STM.

[POSSIBILITIES OF VACUUM THERAPY APPLICATION IN DISORDERS OF VENOUS OUTFLOW IN ISLET GRAFTS].

Science.gov (United States)

Badyul, P O; Samoylenko, G E; Nor, N M; Slesarenko, K S

2015-07-01

The experience of "distressed" (problematic) flaps application in 33 patients with soft tissue defects over 2010-2014 years were analysed. It was proposed to use the local negative pressure for the prevention and treatment of complications associated with venous insufficiency or trombosis in using of plastics with vascularised complexes of tissues. Vacuum-therapy was conducted with the help of negative pressure apparatus "AGATE-Dnepr" (Ukraine) by attaching silver-containing polyurethane sponge on the operating zone, covering the flap with the surrounding skin netting band "Grassolind". The recommended standard of negative pressure of 75-125 mm Hg, both in impulse and in continuous mode was used. The high efficiency of vacuum-therapy for survival of grafts has been demonstrated. Thus, it might be considered as an effective element of prevention and treatment of complications associated with venous insufficiency or trombosis using of vascularised tissue complex plastics of defects.

BERKELEY: Light Source anniversary

International Nuclear Information System (INIS)

Anon.

1994-01-01

The staff of the Advanced Light Source (ALS) at the Lawrence Berkeley Laboratory has been too busy to celebrate the first anniversary of the facility's transition from a US Department of Energy construction project to operating third-generation synchrotron radiation source. Based on a 1.5-GeV, low-emittance electron storage ring that accommodates up to ten insertion-device radiation sources optimized primarily for the soft X-ray and vacuum ultra-violet regions of the spectrum, the ALS has completed

BERKELEY: Light Source anniversary

Energy Technology Data Exchange (ETDEWEB)

Anon.

1994-10-15

The staff of the Advanced Light Source (ALS) at the Lawrence Berkeley Laboratory has been too busy to celebrate the first anniversary of the facility's transition from a US Department of Energy construction project to operating third-generation synchrotron radiation source. Based on a 1.5-GeV, low-emittance electron storage ring that accommodates up to ten insertion-device radiation sources optimized primarily for the soft X-ray and vacuum ultra-violet regions of the spectrum, the ALS has completed.

Vacuum mechatronics first international workshop

Energy Technology Data Exchange (ETDEWEB)

Belinski, S.E.; Shirazi, M.; Hackwood, S.; Beni, G. (eds.) (California Univ., Santa Barbara, CA (USA))

1989-01-01

This report contains papers on the following topics: proposed epitaxial thin film growth in the ultra-vacuum of space; particle monitoring and control in vacuum processing equipment; electrostatic dust collector for use in vacuum systems; materials evaluation of an electrically noisy vacuum slip ring assembly; an overview of lubrication and associated materials for vacuum service; the usage of lubricants in a vacuum environment; guidelines and practical applications for lubrication in vacuum; recent development in leak detector and calibrator designs; the durability of ballscrews for ultrahigh vacuum; vacuum-compatible robot for self-contained manufacturing systems; the design, fabrication, and assembly of an advanced vacuum robotics system for space payload calibration; design criteria for mechanisms used in space; and concepts and requirements for semiconductor multiprocess integration in vacuum. These papers are indexed separately elsewhere.

Field-theoretic Methods in Strongly-Coupled Models of General Gauge Mediation

CERN Document Server

Fortin, Jean-Francois

2013-01-01

An often-exploited feature of the operator product expansion (OPE) is that it incorporates a splitting of ultraviolet and infrared physics. In this paper we use this feature of the OPE to perform simple, approximate computations of soft masses in gauge-mediated supersymmetry breaking. The approximation amounts to truncating the OPEs for hidden-sector current-current operator products. Our method yields visible-sector superpartner spectra in terms of vacuum expectation values of a few hidden-sector IR elementary fields. We manage to obtain reasonable approximations to soft masses, even when the hidden sector is strongly coupled. We demonstrate our techniques in several examples, including a new framework where supersymmetry-breaking arises both from a hidden sector and dynamically.

Relations Between FUV Excess and Coronal Soft X-Ray Emission Among Dwarf Stars

Science.gov (United States)

Smith, Graeme H.; Hargrave, Mason; Eckholm, Elliot

2017-11-01

The far-ultraviolet magnitudes of late-F, G and early-K dwarfs with (B - V) ⩾ 0.50 as measured by the GALEX satellite are shown to correlate with soft X-ray luminosity. This result indicates that line and continuum emission from stellar active regions make significant contributions to the flux in the GALEX FUV band for late-F, G and K dwarfs. By contrast, detection of a correlation between FUV brightness and soft X-ray luminosity among early-F dwarfs requires subtraction of the photospheric component from the FUV flux. The range in (B - V) among F and G dwarfs over which a correlation between uncorrected FUV magnitude and X-ray luminosity is detected coincides with the range in colour over which coronal and chromospheric emission correlates with stellar rotation.

Characterization of nanophotonic soft contact lenses based on poly (2-hydroxyethyl methacrylate and fullerene

Directory of Open Access Journals (Sweden)

Debeljković Aleksandra D.

2013-01-01

Full Text Available This work presents comparative research of characteristics of a basic and new nanophotonic material, the latter of which was obtained by incorporation fullerene, C60, in the base material for soft contact lenses. The basic (SL38 and nanophotonic materials (SL38-A for soft contact lenses were obtained by radical polymerization of 2-hydroxyethyl methacrylate and 2-hydroxyethyl methacrylate and fullerene, which were derived by the technology in the production lab of the company Soleko (Milan, Italy. The materials were used for production of soft contact lenses in the company Optix (Belgrade, Serbia for the purposes of this research. Fullerene was used due to its apsorption transmission characteristics in ultraviolet, visible and near infrared spectrum. For the purposes of material characterization for potential application as soft contact lenses, network parameters were calculated and SEM analysis of the materials was performed while the optical properties of the soft contact lenses were measured by a Rotlex device. The values of the diffusion exponent, n, close to 0.5 indicated Fick's kinetics corresponding to diffusion. The investigated hydrogels could be classified as nonporous hydrogels. With Rotlex device, values of optical power and map of defects were showed. The obtained values of optical power and map of defects showed that the optical power of synthesized nanophotonic soft contact lens is identical to the nominal value while this was not the case for the basic lens. Also, the quality of the nanophotonic soft contact lens is better than the basic soft contact lens. Hence, it is possible to synthesize new nanophotonic soft contact lenses of desired optical characteristics, implying possibilities for their application in this field.

Effects of vacuum ultraviolet photons, ion energy and substrate temperature on line width roughness and RMS surface roughness of patterned 193 nm photoresist

International Nuclear Information System (INIS)

Titus, M J; Graves, D B; Yamaguchi, Y; Hudson, E A

2011-01-01

We present a comparison of patterned 193 nm photoresist (PR) line width roughness (LWR) of samples processed in a well characterized argon (Ar) inductively coupled plasma (ICP) system to RMS surface roughness and bulk chemical modification of blanket 193 nm PR samples used as control samples. In the ICP system, patterned and blanket PR samples are irradiated with Ar vacuum ultraviolet photons (VUV) and Ar ions while sample temperature, photon flux, ion flux and ion energy are controlled and measured. The resulting chemical modifications to bulk 193 nm PR (blanket) and surface roughness are analysed with Fourier transform infrared spectroscopy and atomic force microscopy (AFM). LWR of patterned samples are measured with scanning electron microscopy and blanket portions of the patterned PRs are measured with AFM. We demonstrate that with no RF-bias applied to the substrate the LWR of 193 nm PR tends to smooth and correlates with the smoothing of the RMS surface roughness. However, both LWR and RMS surface roughness increases with simultaneous high-energy (≥70 eV) ion bombardment and VUV-irradiation and is a function of exposure time. Both high- and low-frequency LWR correlate well with the RMS surface roughness of the patterned and blanket 193 nm PR samples. LWR, however, does not increase with temperatures ranging from 20 to 80 deg. C, in contrast to the RMS surface roughness which increases monotonically with temperature. It is unclear why LWR remains independent of temperature over this range. However, the fact that blanket roughness and LWR on patterned samples, both scale similarly with VUV fluence and ion energy suggests a similar mechanism is responsible for both types of surface morphology modifications.

Effects of vacuum ultraviolet photons, ion energy and substrate temperature on line width roughness and RMS surface roughness of patterned 193 nm photoresist

Energy Technology Data Exchange (ETDEWEB)

Titus, M J; Graves, D B [Department of Chemical Engineering, University of California, Berkeley, CA 94720 (United States); Yamaguchi, Y; Hudson, E A, E-mail: graves@berkeley.edu [Lam Research Corporation, 4400 Cushing Parkway, Freemont, CA 94538 (United States)

2011-03-02

We present a comparison of patterned 193 nm photoresist (PR) line width roughness (LWR) of samples processed in a well characterized argon (Ar) inductively coupled plasma (ICP) system to RMS surface roughness and bulk chemical modification of blanket 193 nm PR samples used as control samples. In the ICP system, patterned and blanket PR samples are irradiated with Ar vacuum ultraviolet photons (VUV) and Ar ions while sample temperature, photon flux, ion flux and ion energy are controlled and measured. The resulting chemical modifications to bulk 193 nm PR (blanket) and surface roughness are analysed with Fourier transform infrared spectroscopy and atomic force microscopy (AFM). LWR of patterned samples are measured with scanning electron microscopy and blanket portions of the patterned PRs are measured with AFM. We demonstrate that with no RF-bias applied to the substrate the LWR of 193 nm PR tends to smooth and correlates with the smoothing of the RMS surface roughness. However, both LWR and RMS surface roughness increases with simultaneous high-energy ({>=}70 eV) ion bombardment and VUV-irradiation and is a function of exposure time. Both high- and low-frequency LWR correlate well with the RMS surface roughness of the patterned and blanket 193 nm PR samples. LWR, however, does not increase with temperatures ranging from 20 to 80 deg. C, in contrast to the RMS surface roughness which increases monotonically with temperature. It is unclear why LWR remains independent of temperature over this range. However, the fact that blanket roughness and LWR on patterned samples, both scale similarly with VUV fluence and ion energy suggests a similar mechanism is responsible for both types of surface morphology modifications.

Electroweak vacuum stability and finite quadratic radiative corrections

Energy Technology Data Exchange (ETDEWEB)

Masina, Isabella [Ferrara Univ. (Italy). Dipt. di Fisica e Scienze della Terra; INFN, Sezione di Ferrara (Italy); Southern Denmark Univ., Odense (Denmark). CP3-Origins; Southern Denmark Univ., Odense (Denmark). DIAS; Nardini, Germano [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Quiros, Mariano [Institucio Catalana de Recerca i Estudis Avancats (ICREA), Barcelona (Spain); IFAE-IAB, Barcelona (Spain)

2015-07-15

If the Standard Model (SM) is an effective theory, as currently believed, it is valid up to some energy scale Λ to which the Higgs vacuum expectation value is sensitive throughout radiative quadratic terms. The latter ones destabilize the electroweak vacuum and generate the SM hierarchy problem. For a given perturbative Ultraviolet (UV) completion, the SM cutoff can be computed in terms of fundamental parameters. If the UV mass spectrum involves several scales the cutoff is not unique and each SM sector has its own UV cutoff Λ{sub i}. We have performed this calculation assuming the Minimal Supersymmetric Standard Model (MSSM) is the SM UV completion. As a result, from the SM point of view, the quadratic corrections to the Higgs mass are equivalent to finite threshold contributions. For the measured values of the top quark and Higgs masses, and depending on the values of the different cutoffs Λ{sub i}, these contributions can cancel even at renormalization scales as low as multi-TeV, unlike the case of a single cutoff where the cancellation only occurs at Planckian energies, a result originally obtained by Veltman. From the MSSM point of view, the requirement of stability of the electroweak minimum under radiative corrections is incorporated into the matching conditions and provides an extra constraint on the Focus Point solution to the little hierarchy problem in the MSSM. These matching conditions can be employed for precise calculations of the Higgs sector in scenarios with heavy supersymmetric fields.

Magnetically induced vacuum decay

International Nuclear Information System (INIS)

Xue Shesheng

2003-01-01

We study the fermionic vacuum energy of vacua with and without application of an external magnetic field. The energetic difference of two vacua leads to the vacuum decaying and the vacuum energy being released. In the context of quantum field theories, we discuss why and how the vacuum energy can be released by spontaneous photon emission and/or paramagnetically screening the external magnetic field. In addition, we quantitatively compute the vacuum energy released, the paramagnetic screening effect, and the rate and spectrum of spontaneous photon emission. The possibilities of experimentally detecting such an effect of vacuum-energy release and that this effect accounts for the anomalous x-ray pulsar are discussed

MSSM soft terms from supergravity with gauged R-symmetry in de Sitter vacuum

Directory of Open Access Journals (Sweden)

I. Antoniadis

2016-01-01

Full Text Available We work out the phenomenology of a model of supersymmetry breaking in the presence of a tiny (tunable positive cosmological constant, proposed by the authors in arXiv:1403.1534. It utilizes a single chiral multiplet with a gauged shift symmetry that can be identified with the string dilaton (or an appropriate compactification modulus. The model is coupled to the MSSM, leading to calculable soft supersymmetry breaking masses and a distinct low energy phenomenology that allows to differentiate it from other models of supersymmetry breaking and mediation mechanisms.

MSSM soft terms from supergravity with gauged R-symmetry in de Sitter vacuum

Energy Technology Data Exchange (ETDEWEB)

Antoniadis, I. [LPTHE, UMR CNRS 7589 Sorbonne Universités, UPMC Paris 6, 75005 Paris France (France); Albert Einstein Center, Institute for Theoretical Physics Bern University, Sidlerstrasse 5, CH-3012 Bern (Switzerland); Knoops, R., E-mail: rob.knoops@cern.ch [CERN Theory Division, CH-1211 Geneva 23 (Switzerland); Section de Mathématiques, Université de Genève, CH-1211 Geneva (Switzerland); Instituut voor Theoretische Fysica, KU Leuven, Celestijnenlaan 200D, B-3001 Leuven (Belgium)

2016-01-15

We work out the phenomenology of a model of supersymmetry breaking in the presence of a tiny (tunable) positive cosmological constant, proposed by the authors in (arXiv:1403.1534). It utilizes a single chiral multiplet with a gauged shift symmetry that can be identified with the string dilaton (or an appropriate compactification modulus). The model is coupled to the MSSM, leading to calculable soft supersymmetry breaking masses and a distinct low energy phenomenology that allows to differentiate it from other models of supersymmetry breaking and mediation mechanisms.

REVIEW OF MODERN TECHNOLOGIES OF REINFORCEMENT AND STABILIZATION OF SOFT SOILS

Directory of Open Access Journals (Sweden)

Romanov Nikita Valer’evich

2018-05-01

Full Text Available Subject: description of the current situation in technologies of soil improvement, namely mechanical and hydraulic consolidation of soils and vertical reinforcement of soils for different types of soft soils. Research objectives: demonstration of modern possibilities and approaches to the design and construction of improved soils. Materials and methods: in this paper, we consider such technologies of ground improvement as dynamic compaction, hydraulic consolidation (vertical drain consolidation, Menard vacuum consolidation, vertical reinforcement of soils (CMC - controlled modulus columns. Results: the result of the study is an intuitive representation of the applicability of described technologies for various types of soft soils. Conclusions: the technologies of ground improvement considered in this article are an effective alternative to both pile foundations and soil replacement. To this day, industrial implementation of soil improvement technologies has proved its applicability, efficiency and competitiveness.

R&D ERL: Vacuum

Energy Technology Data Exchange (ETDEWEB)

Mapes, M.; Smart, L.; Weiss, D.; Steszyn, A.; Todd, R.

2010-01-01

The ERL Vacuum systems are depicted in a figure. ERL has eight vacuum volumes with various sets of requirements. A summary of vacuum related requirements is provided in a table. Five of the eight volumes comprise the electron beamline. They are the 5-cell Superconducting RF Cavity, Superconducting e-gun, injection, loop and beam dump. Two vacuum regions are the individual cryostats insulating the 5-cell Superconducting RF Cavity and the Superconducting e-gun structures. The last ERL vacuum volume not shown in the schematic is the laser transport line. The beamline vacuum regions are separated by electropneumatic gate valves. The beam dump is common with loop beamline but is considered a separate volume due to geometry and requirements. Vacuum in the 5-cell SRF cavity is maintained in the {approx}10{sup -9} torr range at room temperature by two 20 l/s ion pumps and in the e-gun SRF cavity by one 60 l/s ion pump. Vacuum in the SRF cavities operated at 2{sup o}K is reduced to low 10{sup -11} torr via cryopumping of the cavity walls. The cathode of the e-gun must be protected from poisoning, which can occur if vacuum adjacent to the e-gun in the injection line exceeds 10-11 torr range in the injection warm beamline near the e-gun exit. The vacuum requirements for beam operation in the loop and beam dump are 10-9 torr range. The beamlines are evacuated from atmospheric pressure to high vacuum level with a particulate free, oil free turbomolecular pumping cart. 25 l/s shielded ion pumps distributed throughout the beamlines maintain the vacuum requirement. Due to the more demanding vacuum requirement of the injection beamline proximate to the e-gun, a vacuum bakeout of the injection beamline is required. In addition, two 200 l/s diode ion pumps and supplemental pumping provided by titanium sublimation pumps are installed in the injection line just beyond the exit of the e-gun. Due to expected gas load a similar pumping arrangement is planned for the beam dump. The

Surface plasmon on topological insulator/dielectric interface enhanced ZnO ultraviolet photoluminescence

Directory of Open Access Journals (Sweden)

Zhi-Min Liao

2012-06-01

Full Text Available It has recently been predicted that the surface plasmons are allowed to exist on the interface between a topological insulator and vacuum. Surface plasmons can be employed to enhance the optical emission from various illuminants. Here, we study the photoluminescence properties of the ZnO/Bi2Te3 hybrid structures. Thin flakes of Bi2Te3, a typical three-dimensional topological insulator, were prepared on ZnO crystal surface by mechanical exfoliation method. The ultraviolet emission from ZnO was found to be enhanced by the Bi2Te3 thin flakes, which was attributed to the surface plasmon – photon coupling at the Bi2Te3/ZnO interface.

Online characterization of isomeric/isobaric components in the gas phase of mainstream cigarette smoke by tunable synchrotron radiation vacuum ultraviolet photoionization time-of-flight mass spectrometry and photoionization efficiency curve simulation.

Science.gov (United States)

Pan, Yang; Hu, Yonghua; Wang, Jian; Ye, Lili; Liu, Chengyuan; Zhu, Zhixiang

2013-12-17

A newly developed, qualitative and quantitative method based on tunable synchrotron radiation vacuum ultraviolet photoionization time-of-flight mass spectrometry (SR-VUV-PI-TOFMS) and photoionization efficiency (PIE) curve simulation was applied for the online analysis of isomers and isobaric compounds in the gas phase of mainstream cigarette smoke. After blocking the particulate phase components by the Cambridge filter pad, a puff of fresh gas-phase cigarette smoke was immediately introduced into a vacuum ionization chamber through a heated capillary, then was photoionized, and analyzed by a TOF mass spectrometer. The PIE curves for the mass peaks up to m/z = 106 were measured between 8.0 and 10.7 eV. Some components could be directly identified by their discriminated ionization energies (IEs) on the PIE curve. By simulating the PIE curve with the sum of scaled absolute photoionization cross sections (PICSs), complex isomeric/isobaric compounds along with their mole fractions could be obtained when the best-fitting was realized between experimental and simulated PIE curves. A series of reported toxic compounds for quantification, such as 1,3-butadiene (m/z = 54), 1,3-cyclopentadiene (m/z = 66), benzene (m/z = 78), xylene (m/z = 106), 2-propenal (m/z = 56), acetone and propanal (m/z = 58), crotonaldehyde (m/z = 70), furan and isoprene (m/z = 68), were all found to have other isomers and/or isobaric compounds with considerable abundances. Some isomers have never been reported previously in cigarette smoke, like C5H6 isomers 1-penten-3-yne, 3-penten-1-yne, and 1-penten-4-yne at m/z = 66. Isomeric/isobaric compounds characterization for the mass peaks and mole fraction calculations were discussed in detail below 10.7 eV, an energy value covering several conventional used VUV light sources.

Vacuum system for ISABELLE

International Nuclear Information System (INIS)

Hobson, J.P.

1975-01-01

An analysis is presented of the proposed vacuum system for the planned ISABELLE storage rings with respect to acceptability and practicality from the vacuum viewport. A comparison is made between the proposed vacuum system and the vacuum system at the CERN ISR, and some comments on various design and operational parameters are made

Vacuum extraction

DEFF Research Database (Denmark)

Maagaard, Mathilde; Oestergaard, Jeanett; Johansen, Marianne

2012-01-01

Objectives. To develop and validate an Objective Structured Assessment of Technical Skills (OSATS) scale for vacuum extraction. Design. Two-part study design: Primarily, development of a procedure-specific checklist for vacuum extraction. Hereafter, validation of the developed OSATS scale for vac...

Ultraviolet complete dark energy model

Science.gov (United States)

Narain, Gaurav; Li, Tianjun

2018-04-01

We consider a local phenomenological model to explain a nonlocal gravity scenario which has been proposed to address dark energy issues. This nonlocal gravity action has been seen to fit the data as well as Λ -CDM and therefore demands a more fundamental local treatment. The induced gravity model coupled with higher-derivative gravity is exploited for this proposal, as this perturbatively renormalizable model has a well-defined ultraviolet (UV) description where ghosts are evaded. We consider a generalized version of this model where we consider two coupled scalar fields and their nonminimal coupling with gravity. In this simple model, one of the scalar field acquires a vacuum expectation value (VEV), thereby inducing a mass for one of the scalar fields and generating Newton's constant. The induced mass however is seen to be always above the running energy scale thereby leading to its decoupling. The residual theory after decoupling becomes a platform for driving the accelerated expansion under certain conditions. Integrating out the residual scalar generates a nonlocal gravity action. The leading term of which is the nonlocal gravity action used to fit the data of dark energy.

Exploratory studies on a passively triggered vacuum spark

Science.gov (United States)

Rout, R. K.; Auluck, S. K. H.; Nagpal, J. S.; Kulkarni, L. V.

1999-12-01

The results of an experimental investigation on a passively triggered vacuum spark device are presented. The diagnostics include the current, x-ray and optical emission measurements. The sharp dips in the current derivative signal indicate the occurrence of pinching at an early stage of the discharge (at current icons/Journals/Common/approx" ALT="approx" ALIGN="TOP"/>5 kA). A well-confined plasma with a central hot region was recorded using a streak camera. The pinched plasma was observed to undergo kink-type oscillations with a time period of 10-15 ns. Repeated plasma fronts were seen to move from the anode to the cathode with an average velocity of icons/Journals/Common/approx" ALT="approx" ALIGN="TOP"/>5 × 106 cm s-1. Soft x-ray emission having a radiation intensity of a few hundred mR per discharge was observed. The x-ray signals obtained using photodiodes showed multiple bursts. A soft x-ray pinhole camera recorded micro-pinches of icons/Journals/Common/approx" ALT="approx" ALIGN="TOP"/>100 µm. The x-ray emitting regions were confined to the inter-electrode gap. The x-ray emission characteristics were influenced by the electrolytic resistance, which was connected across the spark gap to initiate discharge.

Characterization of X-ray optics by soft X-ray diffractometry

International Nuclear Information System (INIS)

Biltoft, P.J.

1988-01-01

The authors have constructed a soft x-ray diffractometer to characterize layered synthetic microstructures (LSMs). The source, sample stage, and counter sections of the diffractometer operate under vacuum. The design differs from most others in two respects: the preamplifier and amplifier that process pulses from the subatmospheric-pressure gas-flow proportional counter are located outside the vacuum chamber and are separated from the proportional counter by approximately 76 cm of shielded cable; in addition, the conventional gear-driven, theta-two-theta diffractometer motion is accomplished with synchronized stepper motors. Characterizations of several LSMs have yielded data on d-spacing (distance between layers of different composition), critical angle, and peak reflectivity. Future work includes incorporation of an improved laser alignment system, in vacuo sample articulation (in addition to the theta-two-theta diffractometer movements), and a higher-flux photon source with a close-coupled fluorescent target carousel. Such a capability will permit multiple-energy diffraction work in a single pumpdown cycle

Ultraviolet photoemission spectroscopy of hydrogen complex deactivation on InP:Zn(1 0 0) surfaces

International Nuclear Information System (INIS)

Williams, M.D.; Williams, S.C.; Yasharahla, S.A.; Jallow, N.

2007-01-01

Ultraviolet photoemission spectroscopy is used to study the kinetics of the H-Zn complex deactivation in Zn doped InP(1 0 0). Hydrogen injected into the material electronically passivates the local carrier concentration. Reverse-biased anneals of the InP under ultra-high vacuum show a dramatic change in the work function of the material with increasing temperature. Spectral features are also shown to be sensitive to sample temperature. To our knowledge, we show the first view of hydrogen retrapping at the surface using photoemission spectroscopy. A simple photoelectron threshold energy analysis shows the state of charge compensation of the material

Vacuum-assisted bilayer PEDOT:PSS/cellulose nanofiber composite film for self-standing, flexible, conductive electrodes.

Science.gov (United States)

Ko, Youngsang; Kim, Dabum; Kim, Ung-Jin; You, Jungmok

2017-10-01

Sustainable cellulose nanofiber (CNF)-based composites as functional conductive materials have garnered considerable attention recently for their use in soft electronic devices. In this work, self-standing, highly flexible, and conductive PEDOT:PSS-CNF composite films were developed using a simple vacuum-assisted filtration method. Two different composite films were successfully fabricated and then tested: 1) a single-layer composite composed of a mixture of PEDOT:PSS and CNF phases and 2) a bilayer composite composed of an upper PEDOT:PSS membrane layer and a CNF matrix sub-layer. The latter composite was constructed by electrostatic/hydrogen bonding interactions between PEDOT:PSS and CNFs coupled with sequential vacuum-assisted filtration. Our results demonstrated that the resultant bilayer composite film exhibited a competitive electrical conductivity (ca. 22.6Scm -1 ) compared to those of previously reported cellulose-based composites. Furthermore, decreases in the electrical properties were not observed in the composite films when they were bent up to 100 times at an angle of 180° and bent multiple times at an angle of 90°, clearly demonstrating their excellent mechanical flexibility. This study provides a straightforward method of fabricating highly flexible, lightweight, and conductive films, which have the potential to be used in high-performance soft electronic systems. Copyright © 2017 Elsevier Ltd. All rights reserved.

Response of the upper atmosphere to variations in the solar soft x-ray irradiance. Ph.D. Thesis

Science.gov (United States)

Bailey, Scott Martin

1995-01-01

Terrestrial far ultraviolet (FUV) airglow emissions have been suggested as a means for remote sensing the structure of the upper atmosphere. The energy which leads to the excitation of FUV airglow emissions is solar irradiance at extreme ultraviolet (EUV) and soft x-ray wavelengths. Solar irradiance at these wavelengths is known to be highly variable; studies of nitric oxide (NO) in the lower thermosphere have suggested a variability of more than an order of magnitude in the solar soft x-ray irradiance. To properly interpret the FUV airflow, the magnitude of the solar energy deposition must be known. Previous analyses have used the electron impact excited Lyman-Birge-Hopfield (LBH) bands of N2 to infer the flux of photoelectrons in the atmosphere and thus to infer the magnitude of the solar irradiance. This dissertation presents the first simultaneous measurements of the FUV airglow, the major atmospheric constituent densities, and the solar EUV and soft x-ray irradiances. The measurements were made on three flights of an identical sounding rocket payload at different levels of solar activity. The linear response in brightness of the LBH bands to variations in solar irradiance is demonstrated. In addition to the N2 LBH bands, atomic oxygen lines at 135.6 and 130.4 nm are also studied. Unlike the LBH bands, these emissions undergo radiative transfer effects in the atmosphere. The OI emission at 135.6 nm is found to be well modeled using a radiative transfer calculation and the known excitation processes. Unfortunately, the assumed processes leading to OI 130.4 nm excitation are found to be insufficient to reproduce the observed variability of this emission. Production of NO in the atmosphere is examined; it is shown that a lower than previously reported variability in the solar soft x-ray irradiance is required to explain the variability of NO.

Evolution of Structural and Optical Properties of ZnO Nanorods Grown on Vacuum Annealed Seed Crystallites

Directory of Open Access Journals (Sweden)

Waqar Khan

2018-01-01

Full Text Available In this study, the ambient condition for the as-coated seed layer (SL annealing at 350 °C is varied from air or nitrogen to vacuum to examine the evolution of structural and optical properties of ZnO nanorods (NRs. The NR crystals of high surface density (~240 rods/μm2 and aspect ratio (~20.3 show greatly enhanced (002 degree of orientation and crystalline quality, when grown on the SLs annealed in vacuum, compared to those annealed in air or nitrogen ambient. This is due to the vacuum-annealed SL crystals of a highly preferred orientation toward (002 and large grain sizes. X-ray photoelectron spectroscopy also reveals that the highest O/Zn atomic ratio of 0.89 is obtained in the case of vacuum-annealed SL crystals, which is due to the effective desorption of hydroxyl groups and other contaminants adsorbed on the surface formed during aqueous solution-based growth process. Near band edge emission (ultra violet range of 360–400 nm of the vacuum-annealed SLs is also enhanced by 44% and 33% as compared to those annealed in air and nitrogen ambient, respectively, in photoluminescence with significant suppression of visible light emission associated with deep level transition. Due to this improvement of SL optical crystalline quality, the NR crystals grown on the vacuum-annealed SLs produce ~3 times higher ultra violet emission intensity than the other samples. In summary, it is shown that the ZnO NRs preferentially grow along the wurtzite c-axis direction, thereby producing the high crystalline quality of nanostructures when they grow on the vacuum-annealed SLs of high crystalline quality with minimized impurities and excellent preferred orientation. The ZnO nanostructures of high crystalline quality achieved in this study can be utilized for a wide range of potential device applications such as laser diodes, light-emitting diodes, piezoelectric transducers and generators, gas sensors, and ultraviolet detectors.

Prefabricated Vertical Drain (PVD) and Deep Cement Mixing (DCM)/Stiffened DCM (SDCM) techniques for soft ground improvement

Science.gov (United States)

Bergado, D. T.; Long, P. V.; Chaiyaput, S.; Balasubramaniam, A. S.

2018-04-01

Soft ground improvement techniques have become most practical and popular methods to increase soil strength, soil stiffness and reduce soil compressibility including the soft Bangkok clay. This paper focuses on comparative performances of prefabricated vertical drain (PVD) using surcharge, vacuum and heat preloading as well as the cement-admixed clay of Deep Cement Mixing (DCM) and Stiffened DCM (SDCM) methods. The Vacuum-PVD can increase the horizontal coefficient of consolidation, Ch, resulting in faster rate of settlement at the same magnitudes of settlement compared to Conventional PVD. Several field methods of applying vacuum preloading are also compared. Moreover, the Thermal PVD and Thermal Vacuum PVD can increase further the coefficient of horizontal consolidation, Ch, with the associated reduction of kh/ks values by reducing the drainage retardation effects in the smear zone around the PVD which resulted in faster rates of consolidation and higher magnitudes of settlements. Furthermore, the equivalent smear effect due to non-uniform consolidation is also discussed in addition to the smear due to the mechanical installation of PVDs. In addition, a new kind of reinforced deep mixing method, namely Stiffened Deep Cement Mixing (SDCM) pile is introduced to improve the flexural resistance, improve the field quality control, and prevent unexpected failures of the Deep Cement Mixing (DCM) pile. The SDCM pile consists of DCM pile reinforced with the insertion of precast reinforced concrete (RC) core. The full scale test embankment on soft clay improved by SDCM and DCM piles was also analysed. Numerical simulations using the 3D PLAXIS Foundation finite element software have been done to understand the behavior of SDCM and DCM piles. The simulation results indicated that the surface settlements decreased with increasing lengths of the RC cores, and, at lesser extent, increasing sectional areas of the RC cores in the SDCM piles. In addition, the lateral movements

Infrared lessons for ultraviolet gravity: the case of massive gravity and Born-Infeld

Science.gov (United States)

Beltrán Jiménez, Jose; Heisenberg, Lavinia; Olmo, Gonzalo J.

2014-11-01

We generalize the ultraviolet sector of gravitation via a Born-Infeld action using lessons from massive gravity. The theory contains all of the elementary symmetric polynomials and is treated in the Palatini formalism. We show how the connection can be solved algebraically to be the Levi-Civita connection of an effective metric. The non-linearity of the algebraic equations yields several branches, one of which always reduces to General Relativity at low curvatures. We explore in detail a minimal version of the theory, for which we study solutions in the presence of a perfect fluid with special attention to the cosmological evolution. In vacuum we recover Ricci-flat solutions, but also an additional physical solution corresponding to an Einstein space. The existence of two physical branches remains for non-vacuum solutions and, in addition, the branch that connects to the Einstein space in vacuum is not very sensitive to the specific value of the energy density. For the branch that connects to the General Relativity limit we generically find three behaviours for the Hubble function depending on the equation of state of the fluid, namely: either there is a maximum value for the energy density that connects continuously with vacuum, or the energy density can be arbitrarily large but the Hubble function saturates and remains constant at high energy densities, or the energy density is unbounded and the Hubble function grows faster than in General Relativity. The second case is particularly interesting because it could offer an interesting inflationary epoch even in the presence of a dust component. Finally, we discuss the possibility of avoiding certain types of singularities within the minimal model.

Feasibility study into the use of silicon photo-diodes for the alignment of collimated X-rays on the SRS

CERN Document Server

Buffey, S G

1999-01-01

Dynamic alignment of beam on the crystal during data collection was studied. Development of silicon photo-diode detectors for the vacuum ultraviolet and soft X-ray spectral regions has led to the use of such devices as beam alignment tools for Protein Crystallography beamlines on the Synchrotron Radiation Source at Daresbury. Quadrant photo-diodes are used to provide signals proportional to the number of photons hitting each photo-diode, these are amplified, digitised and then summed to give the x-y position of the beam centre. (author)

Cosmic vacuum

International Nuclear Information System (INIS)

Chernin, Artur D

2001-01-01

Recent observational studies of distant supernovae have suggested the existence of cosmic vacuum whose energy density exceeds the total density of all the other energy components in the Universe. The vacuum produces the field of antigravity that causes the cosmological expansion to accelerate. It is this accelerated expansion that has been discovered in the observations. The discovery of cosmic vacuum radically changes our current understanding of the present state of the Universe. It also poses new challenges to both cosmology and fundamental physics. Why is the density of vacuum what it is? Why do the densities of the cosmic energy components differ in exact value but agree in order of magnitude? On the other hand, the discovery made at large cosmological distances of hundreds and thousands Mpc provides new insights into the dynamics of the nearby Universe, the motions of galaxies in the local volume of 10 - 20 Mpc where the cosmological expansion was originally discovered. (reviews of topical problems)

Cosmic vacuum

Energy Technology Data Exchange (ETDEWEB)

Chernin, Artur D [P.K. Shternberg State Astronomical Institute at the M.V. Lomonosov Moscow State University, Moscow (Russian Federation)

2001-11-30

Recent observational studies of distant supernovae have suggested the existence of cosmic vacuum whose energy density exceeds the total density of all the other energy components in the Universe. The vacuum produces the field of antigravity that causes the cosmological expansion to accelerate. It is this accelerated expansion that has been discovered in the observations. The discovery of cosmic vacuum radically changes our current understanding of the present state of the Universe. It also poses new challenges to both cosmology and fundamental physics. Why is the density of vacuum what it is? Why do the densities of the cosmic energy components differ in exact value but agree in order of magnitude? On the other hand, the discovery made at large cosmological distances of hundreds and thousands Mpc provides new insights into the dynamics of the nearby Universe, the motions of galaxies in the local volume of 10 - 20 Mpc where the cosmological expansion was originally discovered. (reviews of topical problems)

Vacuum level effects on gait characteristics for unilateral transtibial amputees with elevated vacuum suspension.

Science.gov (United States)

Xu, Hang; Greenland, Kasey; Bloswick, Donald; Zhao, Jie; Merryweather, Andrew

2017-03-01

The elevated vacuum suspension system has demonstrated unique health benefits for amputees, but the effect of vacuum pressure values on gait characteristics is still unclear. The purpose of this study was to investigate the effects of elevated vacuum levels on temporal parameters, kinematics and kinetics for unilateral transtibial amputees. Three-dimensional gait analysis was conducted in 9 unilateral transtibial amputees walking at a controlled speed with five vacuum levels ranging from 0 to 20inHg, and also in 9 able-bodied subjects walking at self-preferred speed. Repeated ANOVA and Dunnett's t-test were performed to determine the effect of vacuum level and limb for within subject and between groups. The effect of vacuum level significantly affected peak hip external rotation and external knee adduction moment. Maximum braking and propulsive ground reaction forces generally increased for the residual limb and decreased for the intact limb with increasing vacuum. Additionally, the intact limb experienced an increased loading due to gait asymmetry for several variables. There was no systematic vacuum level effect on gait. Higher vacuum levels, such as 15 and 20inHg, were more comfortable and provided some relief to the intact limb, but may also increase the risk of osteoarthritis of the residual limb due to the increased peak external hip and knee adduction moments. Very low vacuum should be avoided because of the negative effects on gait symmetry. A moderate vacuum level at 15inHg is suggested for unilateral transtibial amputees with elevated vacuum suspension. Copyright © 2017 Elsevier Ltd. All rights reserved.

Introduction to vacuum technology: supplementary study material developed for IVS sponsored vacuum courses

International Nuclear Information System (INIS)

Bhusan, K.G.

2008-01-01

Vacuum technology has advanced to a large extent mainly from the demands of experimental research scientists who have more than ever understood the need for clean very low pressure environments. This need only seems to increase as the lowest pressures achievable in a laboratory setup are dropping down by the decade. What is not usually said is that conventional techniques of producing ultrahigh vacuum have also undergone a metamorphosis in order to cater to the multitude of restrictions in modern day scientific research. This book aims to give that practical approach to vacuum technology. The basics are given in the first chapter with more of a definition oriented approach - which is practically useful. The second chapter deals with the production of vacuum and ultrahigh vacuum with an emphasis on the working principles of several pumps and their working pressure ranges. Measurement of low pressures, both total and partial is presented in the third chapter with a note on leak detection and mass spectrometric techniques. Chapter 4 gives an overview of the materials that are vacuum compatible and their material properties. Chapter 5 gives the necessary methods to be followed for cleaning of vacuum components especially critical if ultrahigh vacuum environment is required. The practical use of a ultrahigh vacuum environment is demonstrated in Chapter 6 for production of high quality thin films through vapour deposition

National Synchrotron Light Source: vacuum system for National Synchrotron Light Source

International Nuclear Information System (INIS)

Schuchman, J.C.; Godel, J.B.; Jordan, W.; Oversluizen, T.

1978-01-01

The National Synchrotron Light Source (NSLS), a 24 million dollar project under construction at Brookhaven National Laboratory (BNL), is a research facility dedicated to the production of synchrotron radiation. Synchrotron radiation is that radiation produced by the acceleration of charged particles at near the speed of light. This facility will provide a continuous spectrum of radiation from the vacuum ultraviolet to the hard x-ray range. The radiation will be highly intense, 100% polarized, extremely well collimated and will have a pulsed time structure. The radiation will be produced in two electron storage rings at energies of 700 MeV and 2.5 GeV, respectively. A maximum of one ampere at 2 GeV, or one-half ampere at 2.5 GeV, of electron beam will be stored

Spin-resolved photoelectron spectroscopy using femtosecond extreme ultraviolet light pulses from high-order harmonic generation

Energy Technology Data Exchange (ETDEWEB)

Plötzing, M.; Adam, R., E-mail: r.adam@fz-juelich.de; Weier, C.; Plucinski, L.; Schneider, C. M. [Forschungszentrum Jülich GmbH, Peter Grünberg Institut (PGI-6), 52425 Jülich (Germany); Eich, S.; Emmerich, S.; Rollinger, M.; Aeschlimann, M. [University of Kaiserslautern and Research Center OPTIMAS, 67663 Kaiserslautern (Germany); Mathias, S. [Georg-August-Universität Göttingen, I. Physikalisches Institut, 37077 Göttingen (Germany)

2016-04-15

The fundamental mechanism responsible for optically induced magnetization dynamics in ferromagnetic thin films has been under intense debate since almost two decades. Currently, numerous competing theoretical models are in strong need for a decisive experimental confirmation such as monitoring the triggered changes in the spin-dependent band structure on ultrashort time scales. Our approach explores the possibility of observing femtosecond band structure dynamics by giving access to extended parts of the Brillouin zone in a simultaneously time-, energy- and spin-resolved photoemission experiment. For this purpose, our setup uses a state-of-the-art, highly efficient spin detector and ultrashort, extreme ultraviolet light pulses created by laser-based high-order harmonic generation. In this paper, we present the setup and first spin-resolved spectra obtained with our experiment within an acquisition time short enough to allow pump-probe studies. Further, we characterize the influence of the excitation with femtosecond extreme ultraviolet pulses by comparing the results with data acquired using a continuous wave light source with similar photon energy. In addition, changes in the spectra induced by vacuum space-charge effects due to both the extreme ultraviolet probe- and near-infrared pump-pulses are studied by analyzing the resulting spectral distortions. The combination of energy resolution and electron count rate achieved in our setup confirms its suitability for spin-resolved studies of the band structure on ultrashort time scales.

Deciphering the structure of isomeric oligosaccharides in a complex mixture by tandem mass spectrometry: Photon activation with vacuum ultra-violet brings unique information and enables definitive structure assignment

Energy Technology Data Exchange (ETDEWEB)

Ropartz, David, E-mail: David.Ropartz@nantes.inra.fr [INRA, UR1268 Biopolymers Interactions Assemblies, F-44316 Nantes (France); Lemoine, Jérôme [Institut des Sciences Analytiques, UMR 5280, Université Lyon 1-CNRS, Université de Lyon, F-69622 Villeurbanne cedex (France); Giuliani, Alexandre [Synchrotron SOLEIL, L’Orme des Merisiers, F-91190 Gif-sur-Yvette (France); UAR 1008 CEPIA, INRA, F-44316 Nantes (France); Bittebière, Yann [INRA, UR1268 Biopolymers Interactions Assemblies, F-44316 Nantes (France); Enjalbert, Quentin [Institut des Sciences Analytiques, UMR 5280, Université Lyon 1-CNRS, Université de Lyon, F-69622 Villeurbanne cedex (France); Institut Lumière Matière, UMR5306, Université Lyon 1-CNRS, Université de Lyon, F-69622 Villeurbanne cedex (France); Antoine, Rodolphe; Dugourd, Philippe [Institut Lumière Matière, UMR5306, Université Lyon 1-CNRS, Université de Lyon, F-69622 Villeurbanne cedex (France); Ralet, Marie-Christine; Rogniaux, Hélène [INRA, UR1268 Biopolymers Interactions Assemblies, F-44316 Nantes (France)

2014-01-07

Graphical abstract: -- Highlights: •A complex mixture of methylated oligogalacturonans was fractionated by IP-RP-UHPLC. •Synchrotron-radiation in VUV range was used as an activation process for tandem MS. •VUV activation brought rich structural information compared to LE-CAD. •Resolution of more than 35 structures, including isomers, was successfully completed. -- Abstract: Carbohydrates have a wide variety of structures whose complexity and heterogeneity challenge the field of analytical chemistry. Tandem mass spectrometry, with its remarkable sensitivity and high information content, provides key advantages to addressing the structural elucidation of polysaccharides. Yet, classical fragmentation by collision-activated dissociation (CAD) in many cases fails to reach a comprehensive structural determination, especially when isomers have to be differentiated. In this work, for the first time, vacuum ultra-violet (VUV) synchrotron radiation is used as the activation process in tandem mass spectrometry of large oligosaccharides. Compared to low energy CAD (LE-CAD), photon activated dissociation brought more straightforward and valuable structural information. The outstanding feature was that complete series of informative ions were produced, with only minor neutral losses. Moreover, systematic fragmentation rules could be drawn thus facilitating the definitive assignments of fragment identities. As a result, most of the structures present in a complex mixture of oligogalacturonans could be comprehensively resolved, including many isomers differing in the position of methyl groups along the galacturonic acid backbone.

Evaluation of negative pressure vacuum-assisted system in acute and chronic wounds closure: our experience.

Science.gov (United States)

Chiummariello, S; Guarro, G; Pica, A; Alfano, C

2012-10-01

Negative-pressure therapy or vacuum-assisted closure (VAC) has been used in clinical applications since the 1940's and has increased in popularity over the past decade. This dressing technique consists of an open cell foam dressing put into the wound cavity, a vacuum pump produces a negative pressure and an adhesive drape. A controlled sub atmospheric pressure from 75 to 150 mmHg is applied. The vacuum-assisted closure has been applied by many clinicians to chronic wounds in humans; however it cannot be used as a replacement for surgical debridement. The initial treatment for every contaminated wound should be the necrosectomy. The VAC therapy has a complementary function and the range of its indications includes pressure sores, stasis ulcers, chronic wounds such as diabetic foot ulcers, post traumatic and post operative wounds, infected wounds such as necrotizing fasciitis or sternal wounds, soft-tissue injuries, bone exposed injuries, abdominal open wounds and for securing a skin graft. We describe our experience with the VAC dressing used to manage acute and chronic wounds in a series of 135 patients, with excellent results together with satisfaction of the patients.

Aligned metal absorbers and the ultraviolet background at the end of reionization

Science.gov (United States)

Doughty, Caitlin; Finlator, Kristian; Oppenheimer, Benjamin D.; Davé, Romeel; Zackrisson, Erik

2018-04-01

We use observations of spatially aligned C II, C IV, Si II, Si IV, and O I absorbers to probe the slope and intensity of the ultraviolet background (UVB) at z ˜ 6. We accomplish this by comparing observations with predictions from a cosmological hydrodynamic simulation using three trial UVBs applied in post-processing: a spectrally soft, fluctuating UVB calculated using multifrequency radiative transfer; a soft, spatially uniform UVB; and a hard, spatially uniform `quasars-only' model. When considering our paired high-ionization absorbers (C IV/Si IV), the observed statistics strongly prefer the hard, spatially uniform UVB. This echoes recent findings that cosmological simulations generically underproduce strong C IV absorbers at z > 5. A single low/high ionization pair (Si II/Si IV), by contrast, shows a preference for the HM12 UVB, whereas two more (C II/C IV and O I/C IV) show no preference for any of the three UVBs. Despite this, future observations of specific absorbers, particularly Si IV/C IV, with next-generation telescopes probing to lower column densities should yield tighter constraints on the UVB.

Development of a liquid tin microjet target for an efficient laser-produced plasma extreme ultraviolet source

Science.gov (United States)

Higashiguchi, Takeshi; Hamada, Masaya; Kubodera, Shoichi

2007-03-01

A regenerative tin liquid microjet target was developed for a high average power extreme ultraviolet (EUV) source. The diameter of the target was smaller than 160 μm and good vacuum lower than 0.5 Pa was maintained during the operation. A maximum EUV conversion efficiency of 1.8% at the Nd:yttrium-aluminum-garnet laser intensity of around 2×1011 W/cm2 with a spot diameter of 175 μm (full width at half maximum) was observed. The angular distribution of the EUV emission remained almost isotropic, whereas suprathermal ions mainly emerged toward the target normal.

Development of a liquid tin microjet target for an efficient laser-produced plasma extreme ultraviolet source

International Nuclear Information System (INIS)

Higashiguchi, Takeshi; Hamada, Masaya; Kubodera, Shoichi

2007-01-01

A regenerative tin liquid microjet target was developed for a high average power extreme ultraviolet (EUV) source. The diameter of the target was smaller than 160 μm and good vacuum lower than 0.5 Pa was maintained during the operation. A maximum EUV conversion efficiency of 1.8% at the Nd:yttrium-aluminum-garnet laser intensity of around 2x10 11 W/cm 2 with a spot diameter of 175 μm (full width at half maximum) was observed. The angular distribution of the EUV emission remained almost isotropic, whereas suprathermal ions mainly emerged toward the target normal

Development of a liquid tin microjet target for an efficient laser-produced plasma extreme ultraviolet source.

Science.gov (United States)

Higashiguchi, Takeshi; Hamada, Masaya; Kubodera, Shoichi

2007-03-01

A regenerative tin liquid microjet target was developed for a high average power extreme ultraviolet (EUV) source. The diameter of the target was smaller than 160 microm and good vacuum lower than 0.5 Pa was maintained during the operation. A maximum EUV conversion efficiency of 1.8% at the Nd:yttrium-aluminum-garnet laser intensity of around 2 x 10(11) Wcm(2) with a spot diameter of 175 microm (full width at half maximum) was observed. The angular distribution of the EUV emission remained almost isotropic, whereas suprathermal ions mainly emerged toward the target normal.

In Situ SIMS and IR Spectroscopy of Well-Defined Surfaces Prepared by Soft Landing of Mass-Selected Ions

Energy Technology Data Exchange (ETDEWEB)

Johnson, Grant E.; Gunaratne, Kalupathirannehelage Don D.; Laskin, Julia

2014-06-16

Soft landing of mass-selected ions onto surfaces is a powerful approach for the highly-controlled preparation of materials that are inaccessible using conventional synthesis techniques. Coupling soft landing with in situ characterization using secondary ion mass spectrometry (SIMS) and infrared reflection absorption spectroscopy (IRRAS) enables analysis of well-defined surfaces under clean vacuum conditions. The capabilities of three soft-landing instruments constructed in our laboratory are illustrated for the representative system of surface-bound organometallics prepared by soft landing of mass-selected ruthenium tris(bipyridine) dications, [Ru(bpy)3]2+, onto carboxylic acid terminated self-assembled monolayer surfaces on gold (COOH-SAMs). In situ time-of-flight (TOF)-SIMS provides insight into the reactivity of the soft-landed ions. In addition, the kinetics of charge reduction, neutralization and desorption occurring on the COOH-SAM both during and after ion soft landing are studied using in situ Fourier transform ion cyclotron resonance (FT-ICR)-SIMS measurements. In situ IRRAS experiments provide insight into how the structure of organic ligands surrounding metal centers is perturbed through immobilization of organometallic ions on COOH-SAM surfaces by soft landing. Collectively, the three instruments provide complementary information about the chemical composition, reactivity and structure of well-defined species supported on surfaces.

Vacuum fluctuations in an ancestor vacuum: A possible dark energy candidate

Science.gov (United States)

Aoki, Hajime; Iso, Satoshi; Lee, Da-Shin; Sekino, Yasuhiro; Yeh, Chen-Pin

2018-02-01

We consider an open universe created by bubble nucleation, and study possible effects of our "ancestor vacuum," a de Sitter space in which bubble nucleation occurred, on the present universe. We compute vacuum expectation values of the energy-momentum tensor for a minimally coupled scalar field, carefully taking into account the effect of the ancestor vacuum by the Euclidean prescription. We pay particular attention to the so-called supercurvature mode, a non-normalizable mode on a spatial slice of the open universe, which has been known to exist for sufficiently light fields. This mode decays in time most slowly, and may leave residual effects of the ancestor vacuum, potentially observable in the present universe. We point out that the vacuum energy of the quantum field can be regarded as dark energy if mass of the field is of order the present Hubble parameter or smaller. We obtain preliminary results for the dark energy equation of state w (z ) as a function of the redshift.

Two-speed phacoemulsification for soft cataracts using optimized parameters and procedure step toolbar with the CENTURION Vision System and Balanced Tip

Directory of Open Access Journals (Sweden)

Davison JA

2015-08-01

Full Text Available James A DavisonWolfe Eye Clinic, Marshalltown, IA, USA Purpose: To present a cause of posterior capsule aspiration and a technique using optimized parameters to prevent it from happening when operating soft cataracts.Patients and methods: A prospective list of posterior capsule aspiration cases was kept over 4,062 consecutive cases operated with the Alcon CENTURION machine and Balanced Tip. Video analysis of one case of posterior capsule aspiration was accomplished. A surgical technique was developed using empirically derived machine parameters and customized setting-selection procedure step toolbar to reduce the pace of aspiration of soft nuclear quadrants in order to prevent capsule aspiration.Results: Two cases out of 3,238 experienced posterior capsule aspiration before use of the soft quadrant technique. Video analysis showed an attractive vortex effect with capsule aspiration occurring in 1/5 of a second. A soft quadrant removal setting was empirically derived which had a slower pace and seemed more controlled with no capsule aspiration occurring in the subsequent 824 cases. The setting featured simultaneous linear control from zero to preset maximums for: aspiration flow, 20 mL/min; and vacuum, 400 mmHg, with the addition of torsional tip amplitude up to 20% after the fluidic maximums were achieved. A new setting selection procedure step toolbar was created to increase intraoperative flexibility by providing instantaneous shifting between the soft and normal settings.Conclusion: A technique incorporating a reduced pace for soft quadrant acquisition and aspiration can be accomplished through the use of a dedicated setting of integrated machine parameters. Toolbar placement of the procedure button next to the normal setting procedure button provides the opportunity to instantaneously alternate between the two settings. Simultaneous surgeon control over vacuum, aspiration flow, and torsional tip motion may make removal of soft nuclear

Medium-induced gluon radiation and colour decoherence beyond the soft approximation

CERN Document Server

Apolinário, Liliana; Milhano, José Guilherme; Salgado, Carlos A

2015-01-01

We derive the in-medium gluon radiation spectrum off a quark within the path integral formalism at finite energies, including all next-to-eikonal corrections in the propagators of quarks and gluons. Results are computed for finite formation times, including interference with vacuum amplitudes. Rewriting the medium averages in a convenient manner we present the spectrum in terms of dipole cross sections and a colour decoherence parameter with the same physical origin as that found in previous studies of the antenna radiation. This factorisation allows us to present a simple physical picture of the medium-induced radiation for any value of the formation time, of interest for a probabilistic implementation of the modified parton shower. Interestingly -- and unexpectedly -- we also find a modification of the contribution from the hard vertex which cannot be factorized, at finite formation time, as the vacuum Altarelli-Parisi splitting function. Known results are recovered for the particular cases of soft radiatio...

Occupational applications of ultraviolet radiation

International Nuclear Information System (INIS)

Eriksen, P.

1987-01-01

A large population of workers are exposed to ultraviolet radiation in various occupational environments which often necessitates protection. Since ultraviolet radiation may create other environmental problems an occupational hazard- and protection evaluation can be complicated. Threshold Limit Values adopted by the American Conference of Governmental Industrial Hygienists (ACGIH) on ultraviolet radiation are used in most countries as guidelines for risk assessment and control measures. This review addresses the levels of ultraviolet radiation met in occupational environments, its measurement and evaluation, and discusses different protection methods. Ultraviolet lasers are beginning to find their way into industrial processes but are still limited in number and they will not be covered here. Emphasis is on broad band incoherent radiation in high risk environments such as welding, and on the evaluation of protective eyewear, see-through curtains and plastics. Other occupational risks associated with the emission of ultraviolet radiation are discussed

High average power, highly brilliant laser-produced plasma source for soft X-ray spectroscopy.

Science.gov (United States)

Mantouvalou, Ioanna; Witte, Katharina; Grötzsch, Daniel; Neitzel, Michael; Günther, Sabrina; Baumann, Jonas; Jung, Robert; Stiel, Holger; Kanngiesser, Birgit; Sandner, Wolfgang

2015-03-01

In this work, a novel laser-produced plasma source is presented which delivers pulsed broadband soft X-radiation in the range between 100 and 1200 eV. The source was designed in view of long operating hours, high stability, and cost effectiveness. It relies on a rotating and translating metal target and achieves high stability through an on-line monitoring device using a four quadrant extreme ultraviolet diode in a pinhole camera arrangement. The source can be operated with three different laser pulse durations and various target materials and is equipped with two beamlines for simultaneous experiments. Characterization measurements are presented with special emphasis on the source position and emission stability of the source. As a first application, a near edge X-ray absorption fine structure measurement on a thin polyimide foil shows the potential of the source for soft X-ray spectroscopy.

TESIS experiment on study of solar corona in EUV spectral range (CORONAS-PHOTON project)

International Nuclear Information System (INIS)

Kuzin, S.V.; Zhitnik, I.A.; Ignat'ev, A.P.; Mitrofanov, A.V.; Pertsov, A.A.; Bugaenko, O.I.

2005-01-01

A new orbital station, namely: the CORONAS-PHOTON one (to be launched in 2006) equipped with systems to explore Sun at the intensification period of the solar activity 24-th cycle and at its peak is being designed within the framework of the CORONAS National Sun Space Exploration Program. The station equipment consists of systems to observe Sun within the spectral soft X-ray and vacuum ultraviolet bands. Paper lists and describes the TESIS experiment tools designed for the CORONAS-PHOTON Project to ensure the Sun atmospheric research within short-wave band [ru

Influence of Gap Distance on Vacuum Arc Characteristics of Cup Type AMF Electrode in Vacuum Interrupters

International Nuclear Information System (INIS)

Cheng Shaoyong; Xiu Shixin; Wang Jimei; Shen Zhengchao

2006-01-01

The greenhouse effect of SF 6 is a great concern today. The development of high voltage vacuum circuit breakers becomes more important. The vacuum circuit breaker has minimum pollution to the environment. The vacuum interrupter is the key part of a vacuum circuit breaker. The interrupting characteristics in vacuum and arc-controlling technique are the main problems to be solved for a longer gap distance in developing high voltage vacuum interrupters. To understand the vacuum arc characteristics and provide effective technique to control vacuum arc in a long gap distance, the arc mode transition of a cup-type axial magnetic field electrode is observed by a high-speed charge coupled device (CCD) video camera under different gap distances while the arc voltage and arc current are recorded. The controlling ability of the axial magnetic field on vacuum arc obviously decreases when the gap distance is longer than 40 mm. The noise components and mean value of the arc voltage significantly increase. The effective method for controlling the vacuum arc characteristics is provided by long gap distances based on the test results. The test results can be used as a reference to develop high voltage and large capacity vacuum interrupters

Vacuum-assisted delivery

Science.gov (United States)

... medlineplus.gov/ency/patientinstructions/000514.htm Vacuum-assisted delivery To use the sharing features on this page, ... through the birth canal. When is Vacuum-assisted Delivery Needed? Even after your cervix is fully dilated ( ...

R and D ERL: Vacuum

International Nuclear Information System (INIS)

Mapes, M.; Smart, L.; Weiss, D.; Steszyn, A.; Todd, R.

2010-01-01

The ERL Vacuum systems are depicted in a figure. ERL has eight vacuum volumes with various sets of requirements. A summary of vacuum related requirements is provided in a table. Five of the eight volumes comprise the electron beamline. They are the 5-cell Superconducting RF Cavity, Superconducting e-gun, injection, loop and beam dump. Two vacuum regions are the individual cryostats insulating the 5-cell Superconducting RF Cavity and the Superconducting e-gun structures. The last ERL vacuum volume not shown in the schematic is the laser transport line. The beamline vacuum regions are separated by electropneumatic gate valves. The beam dump is common with loop beamline but is considered a separate volume due to geometry and requirements. Vacuum in the 5-cell SRF cavity is maintained in the ∼10 -9 torr range at room temperature by two 20 l/s ion pumps and in the e-gun SRF cavity by one 60 l/s ion pump. Vacuum in the SRF cavities operated at 2 o K is reduced to low 10 -11 torr via cryopumping of the cavity walls. The cathode of the e-gun must be protected from poisoning, which can occur if vacuum adjacent to the e-gun in the injection line exceeds 10-11 torr range in the injection warm beamline near the e-gun exit. The vacuum requirements for beam operation in the loop and beam dump are 10-9 torr range. The beamlines are evacuated from atmospheric pressure to high vacuum level with a particulate free, oil free turbomolecular pumping cart. 25 l/s shielded ion pumps distributed throughout the beamlines maintain the vacuum requirement. Due to the more demanding vacuum requirement of the injection beamline proximate to the e-gun, a vacuum bakeout of the injection beamline is required. In addition, two 200 l/s diode ion pumps and supplemental pumping provided by titanium sublimation pumps are installed in the injection line just beyond the exit of the e-gun. Due to expected gas load a similar pumping arrangement is planned for the beam dump. The cryostat vacuum thermally

Optimizing image-based patterned defect inspection through FDTD simulations at multiple ultraviolet wavelengths

Science.gov (United States)

Barnes, Bryan M.; Zhou, Hui; Henn, Mark-Alexander; Sohn, Martin Y.; Silver, Richard M.

2017-06-01

The sizes of non-negligible defects in the patterning of a semiconductor device continue to decrease as the dimensions for these devices are reduced. These "killer defects" disrupt the performance of the device and must be adequately controlled during manufacturing, and new solutions are required to improve optics-based defect inspection. To this end, our group has reported [Barnes et al., Proc. SPIE 1014516 (2017)] our initial five-wavelength simulation study, evaluating the extensibility of defect inspection by reducing the inspection wavelength from a deep-ultraviolet wavelength to wavelengths in the vacuum ultraviolet and the extreme ultraviolet. In that study, a 47 nm wavelength yielded enhancements in the signal to noise (SNR) by a factor of five compared to longer wavelengths and in the differential intensities by as much as three orders-of-magnitude compared to 13 nm. This paper briefly reviews these recent findings and investigates the possible sources for these disparities between results at 13 nm and 47 nm wavelengths. Our in-house finite-difference time-domain code (FDTD) is tested in both two and three dimensions to determine how computational conditions contributed to the results. A modified geometry and materials stack is presented that offers a second viewpoint of defect detectability as functions of wavelength, polarization, and defect type. Reapplication of the initial SNR-based defect metric again yields no detection of a defect at λ = 13 nm, but additional image preprocessing now enables the computation of the SNR for λ = 13 nm simulated images and has led to a revised defect metric that allows comparisons at all five wavelengths.

Detailed balance condition and ultraviolet stability of scalar field in Horava-Lifshitz gravity

International Nuclear Information System (INIS)

Borzou, Ahmad; Lin, Kai; Wang, Anzhong

2011-01-01

Detailed balance and projectability conditions are two main assumptions when Horava recently formulated his theory of quantum gravity - the Horava-Lifshitz (HL) theory. While the latter represents an important ingredient, the former often believed needs to be abandoned, in order to obtain an ultraviolet stable scalar field, among other things. In this paper, because of several attractive features of this condition, we revisit it, and show that the scalar field can be stabilized, if the detailed balance condition is allowed to be softly broken. Although this is done explicitly in the non-relativistic general covariant setup of Horava-Melby-Thompson with an arbitrary coupling constant λ, generalized lately by da Silva, it is also true in other versions of the HL theory. With the detailed balance condition softly breaking, the number of independent coupling constants can be still significantly reduced. It is remarkable to note that, unlike other setups, in this da Silva generalization, there exists a master equation for the linear perturbations of the scalar field in the flat Friedmann-Robertson-Walker background

Absolute photoionization cross section of the ethyl radical in the range 8-11.5 eV: synchrotron and vacuum ultraviolet laser measurements.

Science.gov (United States)

Gans, Bérenger; Garcia, Gustavo A; Boyé-Péronne, Séverine; Loison, Jean-Christophe; Douin, Stéphane; Gaie-Levrel, François; Gauyacq, Dolores

2011-06-02

The absolute photoionization cross section of C(2)H(5) has been measured at 10.54 eV using vacuum ultraviolet (VUV) laser photoionization. The C(2)H(5) radical was produced in situ using the rapid C(2)H(6) + F → C(2)H(5) + HF reaction. Its absolute photoionization cross section has been determined in two different ways: first using the C(2)H(5) + NO(2) → C(2)H(5)O + NO reaction in a fast flow reactor, and the known absolute photoionization cross section of NO. In a second experiment, it has been measured relative to the known absolute photoionization cross section of CH(3) as a reference by using the CH(4) + F → CH(3) + HF and C(2)H(6) + F → C(2)H(5) + HF reactions successively. Both methods gave similar results, the second one being more precise and yielding the value: σ(C(2)H(5))(ion) = (5.6 ± 1.4) Mb at 10.54 eV. This value is used to calibrate on an absolute scale the photoionization curve of C(2)H(5) produced in a pyrolytic source from the C(2)H(5)NO(2) precursor, and ionized by the VUV beam of the DESIRS beamline at SOLEIL synchrotron facility. In this latter experiment, a recently developed ion imaging technique is used to discriminate the direct photoionization process from dissociative ionization contributions to the C(2)H(5)(+) signal. The imaging technique applied on the photoelectron signal also allows a slow photoelectron spectrum with a 40 meV resolution to be extracted, indicating that photoionization around the adiabatic ionization threshold involves a complex vibrational overlap between the neutral and cationic ground states, as was previously observed in the literature. Comparison with earlier photoionization studies, in particular with the photoionization yield recorded by Ruscic et al. is also discussed. © 2011 American Chemical Society

Soft Ultrathin Electronics Innervated Adaptive Fully Soft Robots.

Science.gov (United States)

Wang, Chengjun; Sim, Kyoseung; Chen, Jin; Kim, Hojin; Rao, Zhoulyu; Li, Yuhang; Chen, Weiqiu; Song, Jizhou; Verduzco, Rafael; Yu, Cunjiang

2018-03-01

Soft robots outperform the conventional hard robots on significantly enhanced safety, adaptability, and complex motions. The development of fully soft robots, especially fully from smart soft materials to mimic soft animals, is still nascent. In addition, to date, existing soft robots cannot adapt themselves to the surrounding environment, i.e., sensing and adaptive motion or response, like animals. Here, compliant ultrathin sensing and actuating electronics innervated fully soft robots that can sense the environment and perform soft bodied crawling adaptively, mimicking an inchworm, are reported. The soft robots are constructed with actuators of open-mesh shaped ultrathin deformable heaters, sensors of single-crystal Si optoelectronic photodetectors, and thermally responsive artificial muscle of carbon-black-doped liquid-crystal elastomer (LCE-CB) nanocomposite. The results demonstrate that adaptive crawling locomotion can be realized through the conjugation of sensing and actuation, where the sensors sense the environment and actuators respond correspondingly to control the locomotion autonomously through regulating the deformation of LCE-CB bimorphs and the locomotion of the robots. The strategy of innervating soft sensing and actuating electronics with artificial muscles paves the way for the development of smart autonomous soft robots. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Vacuum considerations: summary

International Nuclear Information System (INIS)

Blechschmidt, D.; Halama, H.J.

1978-01-01

A summary is given of the efforts of a vacuum systems study group of the workshop on a Heavy Ion Demonstration Experiment (HIDE) for heavy ion fusion. An inadequate knowledge of cross-sections prevents a more concrete vacuum system design. Experiments leading to trustworthy numbers for charge exchange, stripping and capture cross-sections are badly needed and should start as soon as possible. In linacs, beam loss will be almost directly proportional to the pressure inside the tanks. The tanks should, therefore, be built in such a way that they can be baked-out in situ to improve their vacuum, especially if the cross-sections turn out to be higher than anticipated. Using standard UHV techniques and existing pumps, an even lower pressure can be achieved. The vacuum system design for circular machines will be very difficult, and in some cases, beyond the present state-of-the-art

SOFT X-RAY IRRADIATION OF PURE CARBON MONOXIDE INTERSTELLAR ICE ANALOGUES

Energy Technology Data Exchange (ETDEWEB)

Ciaravella, A.; Candia, R.; Collura, A. [INAF-Osservatorio Astronomico di Palermo, P.za Parlamento 1, 90134 Palermo (Italy); Jimenez-Escobar, A.; Munoz Caro, G. M. [Centro de Astrobiologia (CSIC-INTA), Carretera de Ajalvir, km 4, Torrejon de Ardoz, 28850 Madrid (Spain); Cecchi-Pestellini, C. [INAF-Osservatorio Astronomico di Cagliari, Strada n.54, Loc. Poggio dei Pini, I-09012 Capoterra (Italy); Giarrusso, S. [INAF-Istituto di Astrofisica Spaziale e Fisica Cosmica, Via U. La Malfa 153, I-90146 Palermo (Italy); Barbera, M., E-mail: aciaravella@astropa.unipa.it [Dipartimento di Scienze Fisiche and Astronomiche, Universita di Palermo, Sezione di Astronomia, Piazza del Parlamento 1, I-90134 Palermo (Italy)

2012-02-10

There is an increasing evidence for the existence of large organic molecules in the interstellar and circumstellar medium. Very few among such species are readily formed in conventional gas-phase chemistry under typical conditions of interstellar clouds. Attention has therefore focused on interstellar ices as a potential source of these relatively complex species. Laboratory experiments show that irradiation of interstellar ice analogues by fast particles or ultraviolet radiation can induce significant chemical complexity. However, stars are sources of intense X-rays at almost every stage of their formation and evolution. Such radiation may thus provide chemical changes in regions where ultraviolet radiation is severely inhibited. After H{sub 2}O, CO is often the most abundant component of icy grain mantles in dense interstellar clouds and circumstellar disks. In this work we present irradiation of a pure carbon monoxide ice using a soft X-ray spectrum peaked at 0.3 keV. Analysis of irradiated samples shows formation of CO{sub 2}, C{sub 2}O, C{sub 3}O{sub 2}, C{sub 3}, C{sub 4}O, and CO{sub 3}/C{sub 5}. Comparison of X-rays and ultraviolet irradiation experiments, of the same energy dose, shows that X-rays are more efficient than ultraviolet radiation in producing new species. With the exception of CO{sub 2}, X-ray photolysis induces formation of a larger number of products with higher abundances, e.g., C{sub 3}O{sub 2} column density is about one order of magnitude higher in the X-ray experiment. To our knowledge this is the first report on X-ray photolysis of CO ices. The present results show that X-ray irradiation represents an efficient photo-chemical way to convert simple ices to more complex species.

Modern vacuum physics

CERN Document Server

Chambers, Austin

2005-01-01

Modern Vacuum Physics presents the principles and practices of vacuum science and technology along with a number of applications in research and industrial production. The first half of the book builds a foundation in gases and vapors under rarefied conditions, The second half presents examples of the analysis of representative systems and describes some of the exciting developments in which vacuum plays an important role. The final chapter addresses practical matters, such as materials, components, and leak detection. Throughout the book, the author''s explanations are presented in terms of first principles and basic physics, augmented by illustrative worked examples and numerous figures.

Gravitation and vacuum field

International Nuclear Information System (INIS)

Tevikyan, R.V.

1986-01-01

This paper presents equations that describe particles with spins s = 0, 1/2, 1 completely and which also describe 2s + 2 limiting fields as E → ∞. It is shown that the ordinary Hilbert-Einstein action for the gravitation field must be augmented by the action for the Bose vacuum field. This means that one must introduce in the gravitational equations a cosmological term proportional to the square of the strength of the Bose vacuum field. It is shown that the theory of gravitation describes three realities: matter, field, and vacuum field. A new form of matter--the vacuum field--is introduced into field theory

Surge-damping vacuum valve

International Nuclear Information System (INIS)

Bullock, J.C.; Kelley, B.E.

1977-01-01

A valve for damping out flow surges in a vacuum system is described. The surge-damping mechanism consists of a slotted, spring-loaded disk adjacent to the valve's vacuum port (the flow passage to the vacuum roughing pump). Under flow surge conditions, the differential pressure forces the disk into a sealing engagement with the vacuum port, thereby restricting the gas flow path to narrow slots in the disk's periphery. The increased flow damps out the flow surge. When pressure is equalized on both sides of the valve, the spring load moves the disk away from the port to restore full flow conductance through the valve

Comparison of vacuum rise time, vacuum limit accuracy, and occlusion break surge of 3 new phacoemulsification systems.

Science.gov (United States)

Han, Young Keun; Miller, Kevin M

2009-08-01

To compare vacuum rise time, vacuum limit accuracy, and occlusion break surge of 3 new phacoemulsification machines. Jules Stein Eye Institute and Department of Ophthalmology, David Geffen School of Medicine at UCLA, Los Angeles, California, USA. The vacuum rise time under normal and enhanced aspiration modes, vacuum limit accuracy, and occlusion break surge of the Infiniti Vision System, Stellaris Vision Enhancement System, and WhiteStar Signature Phacoemulsification System were tested. Vacuum rise time and limit accuracy were measured at limit settings of 400 mm Hg and 600 mm Hg. Surge area was recorded at vacuum limit settings of 200 mm Hg, 300 mm Hg, 400 mm Hg, and 500 mm Hg. The Infiniti had the fastest vacuum rise times under normal and enhanced aspiration modes. At 4 seconds, the vacuum limit accuracy was greatest with the Infiniti at the 400 mm Hg limit and the Signature at the 600 mm Hg limit. The Stellaris did not reach either vacuum target. The Infiniti performed better than the other 2 machines during testing of occlusion break surge at all vacuum limit settings above 200 mm Hg. Under controlled laboratory test conditions, the Infiniti had the fastest vacuum rise time, greatest vacuum limit accuracy at 400 mm Hg, and least occlusion break surge. These results can be explained by the lower compliance of the Infiniti system.

Vacuum type D initial data

Science.gov (United States)

García-Parrado Gómez-Lobo, Alfonso

2016-09-01

A vacuum type D initial data set is a vacuum initial data set of the Einstein field equations whose data development contains a region where the space–time is of Petrov type D. In this paper we give a systematic characterisation of a vacuum type D initial data set. By systematic we mean that the only quantities involved are those appearing in the vacuum constraints, namely the first fundamental form (Riemannian metric) and the second fundamental form. Our characterisation is a set of conditions consisting of the vacuum constraints and some additional differential equations for the first and second fundamental forms These conditions can be regarded as a system of partial differential equations on a Riemannian manifold and the solutions of the system contain all possible regular vacuum type D initial data sets. As an application we particularise our conditions for the case of vacuum data whose data development is a subset of the Kerr solution. This has applications in the formulation of the nonlinear stability problem of the Kerr black hole.

Real photon spectral weight functions, imaginary part of vacuum polarization and electromagnetic vertices

International Nuclear Information System (INIS)

Chahine, C.; College de France, 75 - Paris. Lab. de Physique Corpusculaire)

1978-02-01

The concept of a real photon spectral weight function for any cross-section involving charged particles is introduced as a simple approximation taking into account the soft part of photon emission to all orders in perturbation theory. The spectral weight function replaces the energy-momentum conservation delta function in the elastic cross-section. The spectral weight function is computed in closed form in space-time and in the peaking approximation in momentum space. The spectral weight function description is applied to the imaginary part of vacuum polarization ImPI and to electron-proton scattering. A spectral representation for ImPI is derived and its content compared with the known fourth order result, showing in particular the identity of the soft and peaking approximations in lowest order. The virtual photon radiative corrections are discussed in part, with emphasis on the threshold behavior of the vertex functions. A relativistic generalization of the electric non-relativistic vertex function is given, whose asymptotic behavior is approppriate to use in conjuction with the spectral weight function

Vacuum pumping concepts for ETF

International Nuclear Information System (INIS)

Homeyer, W.G.

1980-09-01

The Engineering Test Facility (ETF) poses unique vacuum pumping requirements due to its large size and long burn characteristics. These requirements include torus vacuum pumping initially and between burns and pumping of neutralized gas from divertor collector chambers. It was found that the requirements could be met by compound cryopumps in which molecular sieve 5A is used as the cryosorbent. The pumps, ducts, and vacuum valves required are large but fit with other ETF components and do not require major advances in vacuum pumping technology. Several additional design, analytical, and experimental studies were identified as needed to optimize designs and provide better design definition for the ETF vacuum pumping systems

An analytical solution for two-dimensional vacuum preloading combined with electro-osmosis consolidation using EKG electrodes

Science.gov (United States)

Qiu, Chenchen; Li, Yande

2017-01-01

China is a country with vast territory, but economic development and population growth have reduced the usable land resources in recent years. Therefore, reclamation by pumping and filling is carried out in eastern coastal regions of China in order to meet the needs of urbanization. However, large areas of reclaimed land need rapid drainage consolidation treatment. Based on past researches on how to improve the treatment efficiency of soft clay using vacuum preloading combined with electro-osmosis, a two-dimensional drainage plane model was proposed according to the Terzaghi and Esrig consolidation theory. However, the analytical solution using two-dimensional plane model was never involved. Current analytical solutions can’t have a thorough theoretical analysis of practical engineering and give relevant guidance. Considering the smearing effect and the rectangle arrangement pattern, an analytical solution is derived to describe the behavior of pore-water and the consolidation process by using EKG (electro-kinetic geo synthetics) materials. The functions of EKG materials include drainage, electric conduction and corrosion resistance. Comparison with test results is carried out to verify the analytical solution. It is found that the measured value is larger than the applied vacuum degree because of the stacking effect of the vacuum preloading and electro-osmosis. The trends of the mean measured value and the mean analytical value processes are comparable. Therefore, the consolidation model can accurately assess the change in pore-water pressure and the consolidation process during vacuum preloading combined with electro-osmosis. PMID:28771496

An analytical solution for two-dimensional vacuum preloading combined with electro-osmosis consolidation using EKG electrodes.

Directory of Open Access Journals (Sweden)

Yang Shen

Full Text Available China is a country with vast territory, but economic development and population growth have reduced the usable land resources in recent years. Therefore, reclamation by pumping and filling is carried out in eastern coastal regions of China in order to meet the needs of urbanization. However, large areas of reclaimed land need rapid drainage consolidation treatment. Based on past researches on how to improve the treatment efficiency of soft clay using vacuum preloading combined with electro-osmosis, a two-dimensional drainage plane model was proposed according to the Terzaghi and Esrig consolidation theory. However, the analytical solution using two-dimensional plane model was never involved. Current analytical solutions can't have a thorough theoretical analysis of practical engineering and give relevant guidance. Considering the smearing effect and the rectangle arrangement pattern, an analytical solution is derived to describe the behavior of pore-water and the consolidation process by using EKG (electro-kinetic geo synthetics materials. The functions of EKG materials include drainage, electric conduction and corrosion resistance. Comparison with test results is carried out to verify the analytical solution. It is found that the measured value is larger than the applied vacuum degree because of the stacking effect of the vacuum preloading and electro-osmosis. The trends of the mean measured value and the mean analytical value processes are comparable. Therefore, the consolidation model can accurately assess the change in pore-water pressure and the consolidation process during vacuum preloading combined with electro-osmosis.

Structure of Nonlocal quark vacuum condensate in non-perturbative QCD vacuum

International Nuclear Information System (INIS)

Xiang Qianfei; Ma Weixing; Zhou Lijuan; Jiang Weizhou

2014-01-01

Based on the Dyson-Schwinger Equations (DSEs) with the rainbow truncation, and Operator Product Expansion, the structure of nonlocal quark vacuum condensate in QCD, described by quark self-energy functions A_f and B_f given usually by the solutions of the DSEs of quark propagator, is predicted numerically. We also calculate the local quark vacuum condensate, quark-gluon mixed local vacuum condensate, and quark virtuality. The self-energy functions A_f and B_f are given by the parameterized quark propagator functions σ_v"f (p"2) and σ_s"f (p"2) of Roberts and Williams, instead of the numerical solutions of the DSEs. Our calculated results are in reasonable agreement with those of QCD sum rules, Lattice QCD calculations, and instanton model predictions, although the resulting local quark vacuum condensate for light quarks, u, d, s, are a little bit larger than those of the above theoretical predictions. We think the differences are caused by model dependence. The larger of strange quark vacuum condensate than u, d quark is due to the s quark mass which is more larger than u, d quark masses. Of course, the Roberts-Williams parameterized quark propagator is an empirical formulism, which approximately describes quark propagation. (authors)

X-ray spectra of PG quasars. II - the X-ray-ultraviolet excess of PG 1211 + 143

International Nuclear Information System (INIS)

Bechtold, J.; Czerny, B.; Elvis, M.; Fabbiano, G.; Green, R.F.; Harvard-Smithsonian Center for Astrophysics, Cambridge, MA; Kitt Peak National Observatory, Tucson, AZ)

1987-01-01

Observations of the quasar PG 1211 + 143 are presented and its continuum is modelled in terms of an accretion disk and an underlying power law. The X-ray spectrum in the Einstein imaging proportional counter band is well described by a power law with the very steep spectral index 2.2 + or - 0.4. The overall continuum spectral energy distribution can be described as a power law with alpha roughly 1.2 from the infrared to about 1 keV, with the optical, ultraviolet, and soft X-rays forming a large excess above this power law. If the soft X-ray excess is attributed to emission from a physically thin, optically thick accretion disk, then the implied accretion rate is super-Eddington, from which it is concluded that the application of this simple model is not valid. The observed broad-line ratios in PG 1211 + 143 imply broad-line cloud densities that are somewhat higher than those usually derived for quasars. 82 references

Field-theoretic methods in strongly-coupled models of general gauge mediation

International Nuclear Information System (INIS)

Fortin, Jean-François; Stergiou, Andreas

2013-01-01

An often-exploited feature of the operator product expansion (OPE) is that it incorporates a splitting of ultraviolet and infrared physics. In this paper we use this feature of the OPE to perform simple, approximate computations of soft masses in gauge-mediated supersymmetry breaking. The approximation amounts to truncating the OPEs for hidden-sector current–current operator products. Our method yields visible-sector superpartner spectra in terms of vacuum expectation values of a few hidden-sector IR elementary fields. We manage to obtain reasonable approximations to soft masses, even when the hidden sector is strongly coupled. We demonstrate our techniques in several examples, including a new framework where supersymmetry breaking arises both from a hidden sector and dynamically. Our results suggest that strongly-coupled models of supersymmetry breaking are naturally split

Fabrication and testing of an electrochemical microcell for in situ soft X-ray microspectroscopy measurements

Science.gov (United States)

Gianoncelli, A.; Kaulich, B.; Kiskinova, M.; Mele, C.; Prasciolu, M.; Sgura, I.; Bozzini, B.

2013-03-01

In this paper we report on the fabrication and testing of a novel concept of electrochemical microcell for in-situ soft X-ray microspectroscopy in transmission. The microcell, fabricated by electron-beam lithography, implements an improved electrode design, with optimal current density distribution and minimised ohmic drop, allowing the same three-electrode electrochemical control achievable with traditional cells. Moreover standard electroanalytical measurements, such as cyclic voltammetry, can be routinely performed. As far as the electrolyte is concerned, we selected a room-temperature ionic-liquid. Some of the materials belonging to this class, in addition to a broad range of outstanding electrochemical properties, feature two highlights that are crucial for in situ, soft X-ray transmission work: spinnability, enabling accurate thickness control, and stability to UHV, allowing operation of an open cell in the analysis chamber vacuum (10-6 mbar). The cell can, of course, be used also with non-vacuum stable electrolytes in the sealed version developed in previous work in our group. In this study, the microcell designed, fabricated and tested in situ by applying an anodic polarisation to a Au electrode and following the formation of a distribution of corrosion features. This specific material combination presented in this work does not limit the cell concept, that can implement any electrodic material grown by lithography, any liquid electrolyte and any spinnable solid electrolyte.

Soft Robotics Week

CERN Document Server

Rossiter, Jonathan; Iida, Fumiya; Cianchetti, Matteo; Margheri, Laura

2017-01-01

This book offers a comprehensive, timely snapshot of current research, technologies and applications of soft robotics. The different chapters, written by international experts across multiple fields of soft robotics, cover innovative systems and technologies for soft robot legged locomotion, soft robot manipulation, underwater soft robotics, biomimetic soft robotic platforms, plant-inspired soft robots, flying soft robots, soft robotics in surgery, as well as methods for their modeling and control. Based on the results of the second edition of the Soft Robotics Week, held on April 25 – 30, 2016, in Livorno, Italy, the book reports on the major research lines and novel technologies presented and discussed during the event.

From Soft Sculpture to Soft Robotics: Retracing a Physical Aesthetics of Bio-Morphic Softness

DEFF Research Database (Denmark)

Jørgensen, Jonas

2017-01-01

Soft robotics has in the past decade emerged as a growing subfield of technical robotics research, distinguishable by its bio-inspired design strategies, interest in morphological computation, and interdisciplinary combination of insights from engineering, computer science, biology and material...... science. Recently, soft robotics technology has also started to make its way into art, design, and architecture. This paper attempts to think an aesthetics of softness and the life-like through an artistic tradition deeply imbricated with an interrogation of softness and its physical substrates, namely...... the soft sculpture that started proliferating in the late 1960s. Critical descriptions of these works, interestingly, frequently emphasize their similarities with living organisms and bodies as a central tenet of their aesthetics. The paper seeks to articulate aspects of a contiguity between softness...

Shiva and Argus target diagnostics vacuum systems

International Nuclear Information System (INIS)

Glaros, S.S.; Mayo, S.E.; Campbell, D.; Holeman, D.

1978-09-01

The normal operation of LLL's Argus and Shiva laser irradiation facilities demand a main vacuum system for the target chamber and a separate local vacuum system for each of the larger appendage dianostics. This paper will describe the Argus and Shiva main vacuum systems, their respective auxiliary vacuum systems and the individual diagnostics with their respective special vacuum requirements and subsequent vacuum systems. Our latest approach to automatic computer-controlled vacuum systems will be presented

The soft notion of China's 'soft power'

OpenAIRE

Breslin, Shaun

2011-01-01

· Although debates over Chinese soft power have increased in\\ud recent years, there is no shared definition of what ‘soft power’\\ud actually means. The definition seems to change depending on\\ud what the observer wants to argue.\\ud · External analyses of soft power often include a focus on\\ud economic relations and other material (hard) sources of power\\ud and influence.\\ud · Many Chinese analyses of soft power focus on the promotion of a\\ud preferred (positive) understanding of China’s inter...

CERN Vacuum-System Activities during the Long Shutdown 1: The LHC Beam Vacuum

CERN Document Server

Baglin, V; Chiggiato, P; Jimenez, JM; Lanza, G

2014-01-01

After the Long Shutdown 1 (LS1) and the consolidation of the magnet bus bars, the CERN Large Hadron Collider (LHC) will operate with nominal beam parameters. Larger beam energy, beam intensities and luminosity are expected. Despite the very good performance of the beam vacuum system during the 2010-12 physics run (Run 1), some particular areas require attention for repair, consolidation and upgrade. Among the main activities, a large campaign aiming at the repair of the RF bridges of some vacuum modules is conducted. Moreover, consolidation of the cryogenic beam vacuum systems with burst disk for safety reasons is implemented. In addition, NEG cartridges, NEG coated inserts and new instruments for the vacuum system upgrade are installed. Besides these activities, repair, consolidation and upgrades of other beam equipment such as collimators, kickers and beam instrumentations are carried out. In this paper, the motivation and the description for such activities, together with the expected beam vacuum performa...

The AGS Booster vacuum systems

International Nuclear Information System (INIS)

Hseuh, H.C.

1989-01-01

The AGS Booster is a synchrotron for the acceleration of both protons and heavy ions. The design pressure of low 10 -11 mbar is required to minimize beam loss of the partially stripped heavy ions. To remove contaminants and to reduce outgassing, the vacuum chambers and the components located in them will be chemically cleaned, vacuum fired, baked then treated with nitric oxide. The vacuum sector will be insitu baked to a minimum of 200 degree C and pumped by the combination of sputter ion pumps and titanium sublimation pumps. This paper describes the design and the processing of this ultra high vacuum system, and the performance of some half-cell vacuum chambers. 9 refs., 7 figs

Mimicking Martian dust: An in-vacuum dust deposition system for testing the ultraviolet sensors on the Curiosity rover

International Nuclear Information System (INIS)

Sobrado, J. M.; Martín-Soler, J.; Martín-Gago, J. A.

2015-01-01

We have designed and developed an in-vacuum dust deposition system specifically conceived to simulate and study the effect of accumulation of Martian dust on the electronic instruments of scientific planetary exploration missions. We have used this device to characterize the dust effect on the UV sensor of the Rover Environmental Monitoring Station in the Mars science Laboratory mission of NASA in similar conditions to those found on Mars surface. The UV sensor includes six photodiodes for measuring the radiation in all UV wavelengths (direct incidence and reflected); it is placed on the body of Curiosity rover and it is severely affected by the dust deposited on it. Our experimental setup can help to estimate the duration of reliable reading of this instrument during operation. We have used an analogous of the Martian dust in chemical composition (magnetic species), color, and density, which has been characterized by X-ray spectroscopy. To ensure a Brownian motion of the dust during its fall and a homogeneous coverage on the instrumentation, the operating conditions of the vacuum vessel, determined by partial pressures and temperature, have to be modified to account for the different gravities of Mars with respect to Earth. We propose that our designed device and operational protocol can be of interest to test optoelectronic instrumentation affected by the opacity of dust, as can be the degradation of UV photodiodes in planetary exploration

Mimicking Martian dust: An in-vacuum dust deposition system for testing the ultraviolet sensors on the Curiosity rover

Energy Technology Data Exchange (ETDEWEB)

Sobrado, J. M., E-mail: sobradovj@inta.es; Martín-Soler, J. [Centro de Astrobiología (CAB), INTA-CSIC, Torrejón de Ardoz, 28850 Madrid (Spain); Martín-Gago, J. A. [Centro de Astrobiología (CAB), INTA-CSIC, Torrejón de Ardoz, 28850 Madrid (Spain); Instituto de Ciencias de Materiales de Madrid (ICMM–CSIC), Cantoblanco, 28049 Madrid (Spain)

2015-10-15

We have designed and developed an in-vacuum dust deposition system specifically conceived to simulate and study the effect of accumulation of Martian dust on the electronic instruments of scientific planetary exploration missions. We have used this device to characterize the dust effect on the UV sensor of the Rover Environmental Monitoring Station in the Mars science Laboratory mission of NASA in similar conditions to those found on Mars surface. The UV sensor includes six photodiodes for measuring the radiation in all UV wavelengths (direct incidence and reflected); it is placed on the body of Curiosity rover and it is severely affected by the dust deposited on it. Our experimental setup can help to estimate the duration of reliable reading of this instrument during operation. We have used an analogous of the Martian dust in chemical composition (magnetic species), color, and density, which has been characterized by X-ray spectroscopy. To ensure a Brownian motion of the dust during its fall and a homogeneous coverage on the instrumentation, the operating conditions of the vacuum vessel, determined by partial pressures and temperature, have to be modified to account for the different gravities of Mars with respect to Earth. We propose that our designed device and operational protocol can be of interest to test optoelectronic instrumentation affected by the opacity of dust, as can be the degradation of UV photodiodes in planetary exploration.

The symmetries of the vacuum

International Nuclear Information System (INIS)

Fleming, H.

1985-01-01

The vacuum equation of state required by cosmological inflation is taken seriously as a general property of the cosmological vacuum. This correctly restricts the class of theories which admit inflation. A model of such a vacuum is presented that leads naturally to the cosmological principle. (Author) [pt

Ultra-violet Spectrophotometric Determination of Caffeine in Soft and Energy Drinks Available in Yenagoa, Nigeria

OpenAIRE

Amos-Tautua; W. Bamidele Martin; E.R.E. Diepreye

2014-01-01

This study was carried out to determine the pH and levels of caffeine in eight brands of carbonated and energy drinks available in local market in Yenagoa, Nigeria. Quantitative analysis of caffeine was performed by a simple and fast standard UV spectrophotometric method, using carbon tetrachloride as the extracting solvent. Results showed that the pH of the beverages were slightly acidic ranging from 5.92-6.44. The minimum caffeine level was observed in the carbonated soft drink Coca Cola (4...

Regulating vacuum pump speed with feedback control

International Nuclear Information System (INIS)

Ludington, D.C.; Aneshansley, D.J.; Pellerin, R.; Guo, F.

1992-01-01

Considerable energy is wasted by the vacuum pump/motor on dairy farms. The output capacity (m 3 /min or cfm) of the vacuum pump always exceeds the capacity needed to milk cows and wash pipelines. Vacuum pumps run at full speed and load regardless of actual need for air. Excess air is admitted through a controller. Energy can be saved from electrical demand reduced by regulating vacuum pump speed according to air based on air usage. An adjustable speed drive (ASD) on the motor and controlled based upon air usage, can reduce the energy used by the vacuum pump. However, the ASD unit tested could not maintain vacuum levels within generally accepted guidelines when air usage changed. Adding a high vacuum reserve and a dual vacuum controller between the vacuum pump and the milking pipeline brought vacuum stability within guidelines. The ASD/dual vacuum system can reduce energy consumption and demand by at least 50 percent during milking and provide better vacuum stability than conventional systems. Tests were not run during washing cycles. Using 1990 costs and only the energy saved during milking, the simple payback on investment in new equipment for a 5 hp motor, speed controller and vacuum regulator would be about 5 years

The Source of the Quantum Vacuum

Directory of Open Access Journals (Sweden)

Daywitt W. C.

2009-01-01

Full Text Available The quantum vacuum consists of virtual particles randomly appearing and disappearing in free space. Ordinarily the wavenumber (or frequency spectrum of the zero-point fields for these virtual particles is assumed to be unbounded. The unbounded nature of the spectrum leads in turn to an infinite energy density for the quantum vacuum and an infinite renormalization mass for the free particle. This paper argues that there is a more fundamental vacuum state, the Planck vacuum, from which the quantum vacuum emerges and that the “graininess” of this more fundamental vacuum state truncates the wavenumber spectrum and leads to a finite energy density and a finite renormalization mass.

The Source of the Quantum Vacuum

Directory of Open Access Journals (Sweden)

Daywitt W. C.

2009-01-01

Full Text Available The quantum vacuum consists of virtual particles randomly appearing and disappearing in free space. Ordinarily the wavenumber (or frequency spectrum of the zero-point fields for these virtual particles is assumed to be unbounded. The unbounded nature of the spectrum leads in turn to an infinite energy density for the quantum vacuum and an infinite renormalization mass for the free particle. This paper argues that there is a more fundamental vacuum state, the Planck vacuum, from which the quantum vacuum emerges and that the "graininess" of this more fundamental vacuum state truncates the wavenumber spectrum and leads to a finite energy density and a finite renormalization mass.

Scroll vacuum pump

Energy Technology Data Exchange (ETDEWEB)

Morishita, Etsuo; Suganami, Takuya; Nishida, Mitsuhiro; Kitora, Yoshihisa; Yamamoto, Sakuei; Fujii, Kosaburo

1988-02-25

An effort is made to apply a scroll machine to development of a vacuum pump. In view of mechanical simplification and load patterns, the vacuum pump uses a rotating mechanism to produce paired vortices rotating around each center. Chip seal and atmospheric pressure are utilized for axial gap sealing while a spring and atmospheric pressure for the radial gap sealing. In both gaps, the sealing direction is stationary relative to the environment during rotation, making it much easier to achieve effective sealing as compared to oscillating pumps. Since the compression ratio is high in vacuum pumps, a zero top clearance form is adopted for the central portion of vortices and an gas release valve is installed in the rotating axis. A compact Oldham coupling with a small inertia force is installed behind the vortices to maintain the required phase relations between the vortices. These improvements result in a vacuum of 1 Pa for dry operation and 10/sup -2/ Pa for oil flooded operation of a single-stage scroll machine at 1800 rpm. (5 figs, 1 tab, 4 refs)

Combined effects of copper and ultraviolet radiation on a microscopic green alga in natural soft lake waters of varying dissolved organic carbon content

International Nuclear Information System (INIS)

West, L. Jeanine A.; Li, Karen; Greenberg, Bruce M.; Mierle, Greg; Smith, Ralph E.H.

2003-01-01

Selenastrum capricornutum was grown in two lake waters of differing dissolved organic carbon content (1.8 vs. 9.1 mg DOC l -1 ) to determine the responses of population dynamics and photosynthesis to Cu, and to assess the modifying effects of varying ultraviolet radiation (UVR) exposure. In the absence of UVR, the mean EC 50 for Cu effect on population growth rate was 2.3-2.6 μg l -1 in the low DOC water and 17.4-26.2 μg l -1 in the high DOC water. The variable chlorophyll a fluorescence ratio, F v /F m , decreased approximately in parallel with the diminished growth rates. Exposure of the higher DOC lake water to full spectrum artificial radiation caused an increase of Cu 2+ concentration, compared to samples held in darkness or in photosynthetically active radiation (PAR) only. Full spectrum exposures also resulted in a lower (although not significantly so) EC 50 for Cu effect on growth rate, consistent with response to the moderately elevated Cu 2+ concentration. Cu 2+ concentration was unaffected by radiation exposure in the low DOC water, and EC 50 s for growth were also unaffected except in the most severe UVR treatment, which was >40% inhibited even in the absence of added Cu. Using F v /F m as an end-point, there was no evidence of interactions between UVR and Cu under the relatively low PAR exposures used here. Algal growth and photosynthesis was extremely sensitive to Cu in these soft lake waters, with EC 50 s close to current water quality standards in the low DOC water

Cosmology with decaying vacuum energy

International Nuclear Information System (INIS)

Freese, K.; Adams, F.; Frieman, J.; Mottola, E.

1987-09-01

Motivated by recent attempts to solve the cosmological constant problem, we examine the observational consequences of a vacuum energy density which decays in time. For all times later than t ∼ 1 sec, the ratio of the vacuum to the total energy density of the universe must be small. Although the vacuum cannot provide the ''missing mass'' required to close the universe today, its presence earlier in the history of the universe could have important consequences. We discuss restrictions on the vacuum energy arising from primordial nucleosynthesis, the microwave and gamma ray background spectra, and galaxy formation. A small vacuum component at the era of nucleosynthesis, 0.01 5, but in some cases would severely distort the microwave spectrum. 9 refs., 3 figs

The evolution of Titan's high-altitude aerosols under ultraviolet irradiation

Science.gov (United States)

Carrasco, Nathalie; Tigrine, Sarah; Gavilan, Lisseth; Nahon, Laurent; Gudipati, Murthy S.

2018-04-01

The Cassini-Huygens space mission revealed that Titan's thick brownish haze is initiated high in the atmosphere at an altitude of about 1,000 km, before a slow transportation down to the surface. Close to the surface, at altitudes below 130 km, the Huygens probe provided information on the chemical composition of the haze. So far, we have not had insights into the possible photochemical evolution of the aerosols making up the haze during their descent. Here, we address this atmospheric aerosol aging process, simulating in the laboratory how solar vacuum ultraviolet irradiation affects the aerosol optical properties as probed by infrared spectroscopy. An important evolution was found that could explain the apparent contradiction between the nitrogen-poor infrared spectroscopic signature observed by Cassini below 600 km of altitude in Titan's atmosphere and a high nitrogen content as measured by the aerosol collector and pyrolyser of the Huygens probe at the surface of Titan.

Photodetector of ultraviolet radiation

International Nuclear Information System (INIS)

Dorogan, V.; Branzari, V.; Vieru, T.; Manole, M.; Canter, V.

2000-01-01

The invention relates to photodetectors on base of semiconductors of ultraviolet radiation and may be used in optoelectronic system for determining the intensity and the dose of ultraviolet radiation emitted by the Sun or other sources. Summary of the invention consists in the fact that in the photodetector of ultraviolet radiation the superficial potential barrier is divided into two identical elements, electrically isolated each of the other, one of them being covered with a layer of transparent material for visible and infrared radiation and absorption the ultra violet radiation. The technical result consists in mutual compensation of visible and infrared components of the radiation spectrum

Soft ideal topological space and mixed fuzzy soft ideal topological space

Directory of Open Access Journals (Sweden)

Manash Borah

2019-01-01

Full Text Available In this paper we introduce fuzzy soft ideal and mixed fuzzy soft ideal topological spaces and some properties of this space. Also we introduce fuzzy soft $I$-open set, fuzzy soft $\\alpha$-$I$-open set, fuzzy soft pre-$I$-open set, fuzzy soft semi-$I$-open set and fuzzy soft $\\beta$-$I$-open set and discuss some of their properties.

Approximated calculation of the vacuum wave function and vacuum energy of the LGT with RPA method

International Nuclear Information System (INIS)

Hui Ping

2004-01-01

The coupled cluster method is improved with the random phase approximation (RPA) to calculate vacuum wave function and vacuum energy of 2 + 1 - D SU(2) lattice gauge theory. In this calculating, the trial wave function composes of single-hollow graphs. The calculated results of vacuum wave functions show very good scaling behaviors at weak coupling region l/g 2 >1.2 from the third order to the sixth order, and the vacuum energy obtained with RPA method is lower than the vacuum energy obtained without RPA method, which means that this method is a more efficient one

Skylab ultraviolet stellar spectra - A new white dwarf, HD 149499 B

Science.gov (United States)

Parsons, S. B.; Wray, J. D.; Benedict, G. F.; Henize, K. G.; Laget, M.

1976-01-01

The letter reports the discovery of a cool star with excess brightness in the vacuum ultraviolet on an objective-prism photograph obtained during the second Skylab mission. This star, HD 149499, is of type K0 V and has a companion with an apparent magnitude of about 11.8; the relatively flat UV spectrum observed at the position of HD 149499 is characteristic of a 10th or 11th magnitude unreddened O- or early B-type star. It is shown that the excess VUV brightness is due to the companion, HD 149499B, which probably lies in the region of the H-R diagram occupied by the hot white dwarfs. Inspection of white dwarf lists indicates that this star is the sixth or seventh brightest white dwarf known. A maximum orbital motion of 0.025 arcsec/yr is estimated along with a period of just under 500 yr.

Cold Vacuum Drying (CVD) Facility Vacuum Purge System Chilled Water System Design Description. System 47-4

International Nuclear Information System (INIS)

IRWIN, J.J.

2000-01-01

This system design description (SDD) addresses the Vacuum Purge System Chilled Water (VPSCHW) system. The discussion that follows is limited to the VPSCHW system and its interfaces with associated systems. The reader's attention is directed to Drawings H-1-82162, Cold Vacuum Drying Facility Process Equipment Skid PandID Vacuum System, and H-1-82224, Cold Vacuum Drying Facility Mechanical Utilities Process Chilled Water PandID. Figure 1-1 shows the location and equipment arrangement for the VPSCHW system. The VPSCHW system provides chilled water to the Vacuum Purge System (VPS). The chilled water provides the ability to condense water from the multi-canister overpack (MCO) outlet gases during the MCO vacuum and purge cycles. By condensing water from the MCO purge gas, the VPS can assist in drying the contents of the MCO

Vacuum science, technology, and applications

CERN Document Server

Naik, Pramod K

2018-01-01

Vacuum plays an important role in science and technology. The study of interaction of charged particles, neutrals and radiation with each other and with solid surfaces requires a vacuum environment for reliable investigations. Vacuum has contributed immensely to advancements made in nuclear science, space, metallurgy, electrical/electronic technology, chemical engineering, transportation, robotics and many other fields. This book is intended to assist students, scientists, technicians and engineers to understand the basics of vacuum science and technology for application in their projects. The fundamental theories, concepts, devices, applications, and key inventions are discussed.

Vacuum leak detector and method

Science.gov (United States)

Edwards, Jr., David

1983-01-01

Apparatus and method for detecting leakage in a vacuum system involves a moisture trap chamber connected to the vacuum system and to a pressure gauge. Moisture in the trap chamber is captured by freezing or by a moisture adsorbent to reduce the residual water vapor pressure therein to a negligible amount. The pressure gauge is then read to determine whether the vacuum system is leaky. By directing a stream of carbon dioxide or helium at potentially leaky parts of the vacuum system, the apparatus can be used with supplemental means to locate leaks.

Future Directions in Ultraviolet Spectroscopy

Science.gov (United States)

Sonneborn, George (Editor); Moos, Warren; VanSteenberg, Michael

2009-01-01

The 'Future Directions in Ultraviolet Spectroscopy' conference was inspired by the accomplishments of the Far Ultraviolet Spectroscopic Explorer (FUSE) Mission. The FUSE mission was launched in June 1999 and spent over eight years exploring the far-ultraviolet universe, gathering over 64 million seconds of high-resolution spectral data on nearly 3000 astronomical targets. The goal of this conference was not only to celebrate the accomplishments of FUSE, but to look toward the future and understand the major scientific drivers for the ultraviolet capabilities of the next generation fo space observatories. Invited speakers presented discussions based on measurements made by FUSE and other ultraviolet instruments, assessed their connection with measurements made with other techniques and, where appropriate, discussed the implications of low-z measurements for high-z phenomena. In addition to the oral presentations, many participants presented poster papers. The breadth of these presentation made it clear that much good science is still in progress with FUSE data and that these result will continue to have relevance in many scientific areas.

Short wavelength optics for future free electron lasers

International Nuclear Information System (INIS)

Attwood, D.T.

1984-04-01

Although much free-electron laser work is directed toward achieving sufficient single-pass gain to be useful for research purposes, the availability of mirrors of high reflectance for the vacuum ultraviolet and soft x-ray regime would make resonant cavities a possibility. In addition, as in ordinary synchrotron radiation work, mirrors are required for the construction of realistic experiments and for beam manipulation purposes such as folding and extraction. The Working Group discussed a number of approaches to reflecting optics for free electron lasers, which are summarized here, and described in some detail. 16 references, 2 figures

SoftAR: visually manipulating haptic softness perception in spatial augmented reality.

Science.gov (United States)

Punpongsanon, Parinya; Iwai, Daisuke; Sato, Kosuke

2015-11-01

We present SoftAR, a novel spatial augmented reality (AR) technique based on a pseudo-haptics mechanism that visually manipulates the sense of softness perceived by a user pushing a soft physical object. Considering the limitations of projection-based approaches that change only the surface appearance of a physical object, we propose two projection visual effects, i.e., surface deformation effect (SDE) and body appearance effect (BAE), on the basis of the observations of humans pushing physical objects. The SDE visualizes a two-dimensional deformation of the object surface with a controlled softness parameter, and BAE changes the color of the pushing hand. Through psychophysical experiments, we confirm that the SDE can manipulate softness perception such that the participant perceives significantly greater softness than the actual softness. Furthermore, fBAE, in which BAE is applied only for the finger area, significantly enhances manipulation of the perception of softness. We create a computational model that estimates perceived softness when SDE+fBAE is applied. We construct a prototype SoftAR system in which two application frameworks are implemented. The softness adjustment allows a user to adjust the softness parameter of a physical object, and the softness transfer allows the user to replace the softness with that of another object.

Parameter restoration of a soft X radiation spectrum by the signals of X-ray vacuum diodes

International Nuclear Information System (INIS)

Branitskij, A.V.; Olejnik, G.M.

2000-01-01

The multichannel measurement complex on the basis of vacuum X-ray diodes with various filters and the methodology of signals treatment, making it possible to obtained with nanosecond time resolution the radiation capacity in several spectral intervals, ranging from 0.1 up to 4 keV, the radiation capacity within the whole spectral range and the quantum average energy, are described. The method of linear combinations and the two-parametric models, providing close capacity values, are the most acceptable algorithms. This methodology was used at the Angara-5-1 facility in experiments on the cascade liners implosion and with the Z-pinch [ru

Technical specification for vacuum systems

International Nuclear Information System (INIS)

Khaw, J.

1987-01-01

The vacuum systems at the Stanford Linear Accelerator Center (SLAC) are primarily of all-metal construction and operate at pressures from 10 -5 to 10 -11 Torr. The primary gas loads during operation result from thermal desorption and beam-induced desorption from the vacuum chamber walls. These desorption rates can be extremely high in the case of hydrocarbons and other contaminants. These specifications place a major emphasis on eliminating contamination sources. The specifications and procedures have been written to insure the cleanliness and vacuum integrity of all SLAC vacuum systems, and to assist personnel involved with SLAC vacuum systems in choosing and designing components that are compatible with existing systems and meet the quality and reliability of SLAC vacuum standards. The specification includes requirements on design, procurement, fabrication, chemical cleaning, clean room practices, welding and brazing, helium leak testing, residual gas analyzer testing, bakeout, venting, and pumpdown. Also appended are specifications regarding acceptable vendors, isopropyl alcohol, bakeable valve cleaning procedure, mechanical engineering safety inspection, notes on synchrotron radiation, and specifications of numerous individual components

Evaporation under vacuum condition

International Nuclear Information System (INIS)

Mizuta, Satoshi; Shibata, Yuki; Yuki, Kazuhisa; Hashizume, Hidetoshi; Toda, Saburo; Takase, Kazuyuki; Akimoto, Hajime

2000-01-01

In nuclear fusion reactor design, an event of water coolant ingress into its vacuum vessel is now being considered as one of the most probable accidents. In this report, the evaporation under vacuum condition is evaluated by using the evaporation model we have developed. The results show that shock-wave by the evaporation occurs whose behavior strongly depends on the initial conditions of vacuum. And in the case of lower initial pressure and temperature, the surface temp finally becomes higher than other conditions. (author)

Gauge field vacuum structure in geometrical aspect

International Nuclear Information System (INIS)

Konopleva, N.P.

2003-01-01

Vacuum conception is one of the main conceptions of quantum field theory. Its meaning in classical field theory is also very profound. In this case the vacuum conception is closely connected with ideas of the space-time geometry. The global and local geometrical space-time conceptions lead to different vacuum definitions and therefore to different ways of physical theory construction. Some aspects of the gauge field vacuum structure are analyzed. It is shown that in the gauge field theory the vacuum Einstein equation solutions describe the relativistic vacuum as common vacuum of all gauge fields and its sources. Instantons (both usual and hyperbolical) are regarded as nongravitating matter, because they have zero energy-momentum tensors and correspond to vacuum Einstein equations

Vacuum metastability with black holes

Energy Technology Data Exchange (ETDEWEB)

Burda, Philipp [Centre for Particle Theory, Durham University,South Road, Durham, DH1 3LE (United Kingdom); Gregory, Ruth [Centre for Particle Theory, Durham University,South Road, Durham, DH1 3LE (United Kingdom); Perimeter Institute, 31 Caroline Street North,Waterloo, ON, N2L 2Y5 (Canada); Moss, Ian G. annd [School of Mathematics and Statistics, Newcastle University,Newcastle Upon Tyne, NE1 7RU (United Kingdom)

2015-08-24

We consider the possibility that small black holes can act as nucleation seeds for the decay of a metastable vacuum, focussing particularly on the Higgs potential. Using a thin-wall bubble approximation for the nucleation process, which is possible when generic quantum gravity corrections are added to the Higgs potential, we show that primordial black holes can stimulate vacuum decay. We demonstrate that for suitable parameter ranges, the vacuum decay process dominates over the Hawking evaporation process. Finally, we comment on the application of these results to vacuum decay seeded by black holes produced in particle collisions.

Vacuum metastability with black holes

International Nuclear Information System (INIS)

Burda, Philipp; Gregory, Ruth; Moss, Ian G. annd

2015-01-01

We consider the possibility that small black holes can act as nucleation seeds for the decay of a metastable vacuum, focussing particularly on the Higgs potential. Using a thin-wall bubble approximation for the nucleation process, which is possible when generic quantum gravity corrections are added to the Higgs potential, we show that primordial black holes can stimulate vacuum decay. We demonstrate that for suitable parameter ranges, the vacuum decay process dominates over the Hawking evaporation process. Finally, we comment on the application of these results to vacuum decay seeded by black holes produced in particle collisions.

Spatial-Resolved Measurement and Analysis of Extreme-Ultraviolet Emission Spectra from Laser-Produced Al Plasmas

International Nuclear Information System (INIS)

Cao Shi-Quan; Su Mao-Gen; Sun Dui-Xiong; Min Qi; Dong Chen-Zhong

2016-01-01

Extreme ultraviolet emission from laser-produced Al plasma is experimentally and theoretically investigated. Spatial-evolution emission spectra are measured by using the spatio-temporally resolved laser produced plasma technique. Based on the assumptions of a normalized Boltzmann distribution among the excited states and a steady-state collisional-radiative model, we succeed in reproducing the spectra at different detection positions, which are in good agreement with experiments. The decay curves about the electron temperature and electron density, as well as the fractions of individual Al ions and average ionization stage with increasing the detection distance are obtained by comparison with the experimental measurements. These parameters are critical points for deeply understanding the expanding and cooling of laser produced plasmas in vacuum. (paper)

Vacuum exhaust duct used for thermonuclear device

International Nuclear Information System (INIS)

Tachikawa, Nobuo; Kondo, Mitsuaki; Honda, Tsutomu.

1990-01-01

The present invention concerns a vacuum exhaust duct used for a thermonuclear device. A cylindrical metal liners is lined with a gap to the inside of a vacuum exhaust duct main body. Bellows are connected to both ends of the metal liners and the end of the bellows is welded to the vacuum exhaust duct main body. Futher, a heater is mounted to the metal liner on the side of the vacuum exhaust duct main body, and the metal liner is heated by the heater to conduct baking for the vacuum exhaust duct main body. Accordingly, since there is no requirement for elevating the temperature of the vacuum exhaust duct upon conducting baking, the vacuum exhaust duct scarcely suffers substantial deformation due to heat expansion. Further, there is also no substantial deformation for the bellows disposed between the outer circumference of the vacuum vessel and a portion of a vacuum exhaust duct, so that the durability of the bellows is greatly improved. (I.S.)

Soft Neutrosophic Bi-LA-semigroup and Soft Neutrosophic N-LA-seigroup

Directory of Open Access Journals (Sweden)

Mumtaz Ali

2014-09-01

Full Text Available Soft set theory is a general mathematical tool for dealing with uncertain, fuzzy, not clearly defined objects. In this paper we introduced soft neutrosophic biLA-semigroup,soft neutosophic sub bi-LA-semigroup, soft neutrosophic N -LA-semigroup with the discuission of some of their characteristics. We also introduced a new type of soft neutrophic bi-LAsemigroup, the so called soft strong neutrosophic bi-LAsemigoup which is of pure neutrosophic character. This is also extend to soft neutrosophic strong N-LA-semigroup. We also given some of their properties of this newly born soft structure related to the strong part of neutrosophic theory.

Inhibition of seagrass photosynthesis by ultraviolet-B radiation.

Science.gov (United States)

Trocine, R P; Rice, J D; Wells, G N

1981-07-01

Effects of ultraviolet-B radiation on the photosynthesis of seagrasses (Halophila engelmanni Aschers, Halodule wrightii Aschers, and Syringodium filiforme Kütz) were examined. The intrinsic tolerance of each seagrass to ultraviolet-B, the presence and effectiveness of photorepair mechanisms to ultraviolet-B-induced photosynthetic inhibition, and the role of epiphytic growth as a shield from ultraviolet-B were investigated.Halodule was found to possess the greatest photosynthetic tolerance for ultraviolet-B. Photosynthesis in Syringodium was slightly more sensitive to ultraviolet-B while Halophila showed relatively little photosynthetic tolerance. Evidence for a photorepair mechanism was found only in Halodule. This mechanism effectively attenuated photosynthetic inhibition induced by ultraviolet-B dose rates and dosages in excess of natural conditions. Syringodium appeared to rely primarily on a thick epidermal cell layer to reduce photosynthetic damage. Halophila seemed to have no morphological or photorepair capabilities to deal with ultraviolet-B. This species appeared to rely on epiphytic and detrital shielding and the shade provided by other seagrasses to reduce ultraviolet-B irradiation to tolerable levels. The presence of epiphytes on leaf surfaces was found to reduce the extent of photosynthetic inhibition from ultraviolet-B exposure in all species.Observations obtained in this study seem to suggest the possibility of anthocyanin and/or other flavonoid synthesis as an adaptation to long term ultraviolet-B irradiation by these species. In addition, Halophila appears to obtain an increased photosynthetic tolerance to ultraviolet-B as an indirect benefit of chloroplast clumping to avoid photo-oxidation by intense levels of photosynthetically active radiation.

Divertor extreme ultraviolet (EUV) survey spectroscopy in DIII-D

Science.gov (United States)

McLean, Adam; Allen, Steve; Ellis, Ron; Jarvinen, Aaro; Soukhanovskii, Vlad; Boivin, Rejean; Gonzales, Eduardo; Holmes, Ian; Kulchar, James; Leonard, Anthony; Williams, Bob; Taussig, Doug; Thomas, Dan; Marcy, Grant

2017-10-01

An extreme ultraviolet spectrograph measuring resonant emissions of D and C in the lower divertor has been added to DIII-D to help resolve an 2X discrepancy between bolometrically measured radiated power and that predicted by boundary codes for DIII-D, JET and ASDEX-U. With 290 and 450 gr/mm gratings, the DivSPRED spectrometer, an 0.3 m flat-field McPherson model 251, measures ground state transitions for D (the Lyman series) and C (e.g., C IV, 155 nm) which account for >75% of radiated power in the divertor. Combined with Thomson scattering and imaging in the DIII-D divertor, measurements of position, temperature and fractional power emission from plasma components are made and compared to UEDGE/SOLPS-ITER. Mechanical, optical, electrical, vacuum, and shielding aspects of DivSPRED are presented. Work supported under USDOE Cooperative Agreement DE-FC02-04ER54698 and DE-AC52-07NA27344, and by the LLNL Laboratory Directed R&D Program, project #17-ERD-020.

Inhibition of seagrass photosynthesis by ultraviolet-B radiation

International Nuclear Information System (INIS)

Trocine, R.P.; Rice, J.D.; Wells, G.N.

1981-01-01

Effects of ultraviolet-B radiation on the photosynthesis of seagrasses (Halophila engelmanni Aschers, Halodule wrightii Aschers, and Syringodium filiforme (Kuetz) were examined. The intrinsic tolerance of each seagrass to ultraviolet-B, the presence and effectiveness of photorepair mechanisms to ultraviolet-B-induced photosynthetic inhibition, and the role of epiphytic growth as a shield from ultraviolet-B were investigated. Halodule was found to possess the greatest photosynthetic tolerance for ultraviolet-B. Photosynthesis in Syringodium was slightly more sensitive to ultraviolet-B while Halophila showed relatively little photosynthetic tolerance. Evidence for a photorepair mechanism was found only in Halodule. Syringodium appeared to rely primarily on a thick epidermal cell layer to reduce photosynthetic damage. Halophila seemed to have no morphological or photorepair capabilities to deal with ultraviolet-B. This species appeared to rely on epiphytic and detrital shielding and the shade provided by other seagrasses to reduce ultraviolet-B irradiation to tolerable levels. The presence of epiphytes on leaf surfaces was found to reduce the extent of photosynthetic inhibition from ultraviolet-B exposure in all species. Halophila appears to obtain an increased photosynthetic tolerance to ultraviolet-B as an indirect benefit of chloroplast clumping to avoid photo-oxidation by intense levels of photosynthetically active radiation

Harmful effects of ultraviolet radiation

International Nuclear Information System (INIS)

Anon.

1989-01-01

Tanning for cosmetic purposes by sunbathing or by using artificial tanning devices is widespread. The hazards associated with exposure to ultraviolet radiation are of concern to the medical profession. Depending on the amount and form of the radiation, as well as on the skin type of the individual exposed, ultraviolet radiation causes erythema, sunburn, photodamage (photoaging), photocarcinogenesis, damage to the eyes, alteration of the immune system of the skin, and chemical hypersensitivity. Skin cancers most commonly produced by ultraviolet radiation are basal and squamous cell carcinomas. There also is much circumstantial evidence that the increase in the incidence of cutaneous malignant melanoma during the past half century is related to increased sun exposure, but this has not been proved. Effective and cosmetically acceptable sunscreen preparations have been developed that can do much to prevent or reduce most harmful effects to ultraviolet radiation if they are applied properly and consistently. Other safety measures include (1) minimizing exposure to ultraviolet radiation, (2) being aware of reflective surfaces while in the sun, (3) wearing protective clothing, (4) avoiding use of artificial tanning devices, and (5) protecting infants and children

The ultraviolet to X-ray continua of BL Lac objects

International Nuclear Information System (INIS)

George, I.M.; Warwick, R.S.; McHardy, I.M.

1988-01-01

The results from EXOSAT observations of three X-ray bright BL Lacertae objects, Mrk 501, 1218 + 304 and Mrk 180 are presented. All three sources have soft power-law X-ray spectra with low-energy cut-offs consistent with absorption in the line-of-sight gas column density through our own galaxy. The three objects also exhibit significant spectral variability in the X-ray band on time-scales ranging from a few days to a year. In each case, X-ray flux and spectral index appear to be correlated, in the sense that the X-ray spectrum hardens as the source brightens. The intrinsic ultraviolet to X-ray spectrum of these and several other X-ray bright BL Lac objects can be modelled as a power-law continuum of energy index ∼1.0 below about 0.1 keV, above which the spectral slope steepens. (author)

Automatic electromagnetic valve for previous vacuum

International Nuclear Information System (INIS)

Granados, C. E.; Martin, F.

1959-01-01

A valve which permits the maintenance of an installation vacuum when electric current fails is described. It also lets the air in the previous vacuum bomb to prevent the oil ascending in the vacuum tubes. (Author)

Development of vacuum brazing furnace

International Nuclear Information System (INIS)

Singh, Rajvir; Yedle, Kamlesh; Jain, A.K.

2005-01-01

In joining of components where welding process is not possible brazing processes are employed. Value added components, high quality RF systems, UHV components of high energy accelerators, carbide tools etc. are produced using different types of brazing methods. Furnace brazing under vacuum atmosphere is the most popular and well accepted method for production of the above mentioned components and systems. For carrying out vacuum brazing successfully it is essential to have a vacuum brazing furnace with latest features of modern vacuum brazing technology. A vacuum brazing furnace has been developed and installed for carrying out brazing of components of copper, stainless steel and components made of dissimilar metals/materials. The above furnace has been designed to accommodate jobs of 700mm diameter x 2000mm long sizes with job weight of 500kgs up to a maximum temperature of 1250 degC at a vacuum of 5 x 10 -5 Torr. Oil diffusion pumping system with a combination of rotary and mechanical booster pump have been employed for obtaining vacuum. Molybdenum heating elements, radiation shield of molybdenum and Stainless Steel Grade 304 have been used. The above furnace is computer controlled with manual over ride facility. PLC and Pentium PC are integrated together to maneuver steps of operation and safety interlocks of the system. Closed loop water supply provides cooling to the system. The installation of the above system is in final stage of completion and it will be ready for use in next few months time. This paper presents insights of design and fabrication of a modern vacuum brazing furnace and its sub-system. (author)

Gases and vacua handbook of vacuum physics

CERN Document Server

Beck, A H

2013-01-01

Handbook of Vacuum Physics, Volume 1: Gases and Vacua provides information on the many aspects of vacuum technology, from material on the quantum theoretical aspects of the complex semi-conductors used for thermionic and photo-electric emission to data on the performance of commercially available pumps, gauges, and high-vacuum materials. The handbook satisfies the need of workers using vacuum apparatuses or works on the diverse applications of high-vacuum technology in research and industry. The book is a compilation of long articles prepared by experts in vacuum technology. Sufficient theoret

Hadron Contribution to Vacuum Polarisation

CERN Document Server

Davier, M; Malaescu, B; Zhang, Z

2016-01-01

Precision tests of the Standard Theory require theoretical predictions taking into account higher-order quantum corrections. Among these vacuum polarisation plays a predominant role. Vacuum polarisation originates from creation and annihilation of virtual particle–antiparticle states. Leptonic vacuum polarisation can be computed from quantum electrodynamics. Hadronic vacuum polarisation cannot because of the non-perturbative nature of QCD at low energy. The problem is remedied by establishing dispersion relations involving experimental data on the cross section for e+ e− annihilation into hadrons. This chapter sets the theoretical and experimental scene and reviews the progress achieved in the last decades thanks to more precise and complete data sets. Among the various applications of hadronic vacuum polarisation calculations, two are emphasised: the contribution to the anomalous magnetic moment of the muon, and the running of the fine structure constant α to the Z mass scale. They are fundamental ingre...

Effect of ultraviolet exposure on mitochondrial respiratory system

Energy Technology Data Exchange (ETDEWEB)

Noda, K [Kurume Univ., Fukuoka (Japan). School of Medicine

1975-09-01

To find the photodynamic effect of ultraviolet light on the mitochondrial respiratory chain, mitochondria were obtained from rat livers, and the suspension was exposed to an extensive ultraviolet light. The oxygen consumption was measured polarographically with a Clark oxygen electrode. The effect of ultraviolet exposure on the five states of respiratory control (Chance and Williams), the P/O ratio, and the respiratory control index in mitochondria was discussed. The ultraviolet light with a dose of 9.6 x 10/sup 6/ erg/cm/sup 2/ caused the oxidative phosphorylation in mitochondria to uncouple. The 2nd phosphorylation site of the respiratory chain was susceptible to ultraviolet exposure. The stimulation of latent ATPase activity in mitochondria following exposure was observed by increasing exposure of ultraviolet light. However, DNP-stimulated ATPase was found to be stable in activity. The uncoupling of the respiratory chain by ultraviolet exposure was not detected if the mitochondrial suspension was preincubated with bovine serum albumin before exposure. The changes in light absorption of the mitochondrial suspension were followed at 520 nm after exposure. A close correlation was found between the ultraviolet exposure and swelling in mitochondria. But, the reversing contraction was observed by adding ATP to the swelled mitochondria. The peroxide compound was formed in mitochondria irradiated with ultraviolet light. The amount of compounds formed was dependent on the radiant energy of ultraviolet light. The possible mechanisms involved in the photodynamic effect of ultraviolet light to the mitochondrial respiration system were discussed.

Helical type vacuum container

International Nuclear Information System (INIS)

Owada, Kimio.

1989-01-01

Helical type vacuum containers in the prior art lack in considerations for thermal expansion stresses to helical coils, and there is a possibility of coil ruptures. The object of the present invention is to avoid the rupture of helical coils wound around the outer surface of a vacuum container against heat expansion if any. That is, bellows or heat expansion absorbing means are disposed to a cross section of a helical type vacuum container. With such a constitution, thermal expansion of helical coils per se due to temperature elevation of the coils during electric supply can be absorbed by expansion of the bellows or absorption of the heat expansion absorbing means. Further, this can be attained by arranging shear pins in the direction perpendicular to the bellows axis so that the bellows are not distorted when the helical coils are wound around the helical type vacuum container. (I.S.)

PDX vacuum vessel stress analysis

International Nuclear Information System (INIS)

Nikodem, Z.D.

1975-01-01

A stress analysis of PDX vacuum vessel is described and the summary of results is presented. The vacuum vessel is treated as a toroidal shell of revolution subjected to an internal vacuum. The critical buckling pressure is calculated. The effects of the geometrical discontinuity at the juncture of toroidal shell head and cylindrical outside wall, and the concavity of the cylindrical wall are examined. An effect of the poloidal field coil supports and the vessel outside supports on the stress distribution in the vacuum vessel is determined. A method evaluating the influence of circular ports in the vessel wall on the stress level in the vessel is outlined

Vacuum-assisted closure downgrades reconstructive demands in high-risk patients with severe lower extremity injuries.

Science.gov (United States)

Kakagia, D; Karadimas, E; Drosos, G; Ververidis, A; Kazakos, D; Lazarides, M; Verettas, D

2009-01-01

Primary soft tissue reconstruction in complex leg injuries is mandatory in order to protect exposed tissues; however, it may be precluded by the patient's clinical status or by local wound conditions. This retrospective study aims to evaluate the use of negative pressure as an adjunct to delayed soft tissue reconstruction in patients with complex lower limb trauma. Forty-two patients with 49 complex lower limb injuries were treated with Vacuum assisted closure (VAC) 48 hours after bone fixation, vascular repair and surgical debridement. Wound swab cultures were obtained before and after every VAC application. Duration of therapy, wound flora, final reconstructive technique required, outcome and follow-up period were retrieved from medical records. Twenty-four male and eighteen female patients were recruited, with a mean age of 47 years. All were treated with VAC therapy for 15-42 days. Reconstruction was delayed due to the patients' critical condition, advanced age, medical co-morbidities, heavily exuding wounds and questionable viability of soft tissues. Patients were followed up for 90-895 days. Two wounds healed spontaneously, 6 were managed with delayed direct suture, 31 with split thickness skin grafts and 9 required local cutaneous, fasciocutaneous or muscular flaps. One patient died due to fat embolism. Wound bacterial flora progressively decreased in all but one patient. Scar formation was aesthetically acceptable by the patients while function depended on the initial injury. Negative pressure is a safe and effective adjunct to delayed soft tissue reconstruction in high-risk patients with severe lower extremity injuries, minimizing reconstructive requirements and therefore postoperative morbidity.

Quark and gluon condensate in vacuum

International Nuclear Information System (INIS)

Vajnshtejn, A.I.; Zakharov, V.I.; Shifman, M.A.

1979-01-01

The mechanism of quark confinement has been reviewed. The fact that coloured particles in a free state cannot be observed is connected with specific properties of vacuum in quantum chromodynamics. The basic hypothesis consists in the existence of vacuum fields, quark and gluon condensates, which affect the coloured objects. The vacuum transparent relative to noncharged ''white'' states serves as a source of the force acting upon the coloured particles. It has been a sucess to examine strictly the action of the vacuum fields on quarks when the distance between them is relatively small and the force of the vacuum fields on quarks is relatively small too. It is shown that the interaction with the vacuum fields manifests itself earlier than the forces connected with the gluon exchange do. It is assumed that the vacuum condensate of quarks and gluons and its relation to properties of resonances and to the bag model exist in reality. The dispersion sum rules are used for calculating masses and lepton widths of resonances

CAS CERN Accelerator School vacuum technology. Proceedings

International Nuclear Information System (INIS)

Turner, S.

1999-01-01

These proceedings present the lectures given at the twelfth specialized course organized by the CERN Accelerator School (CAS), the topic this time being 'Vacuum Technology'. Despite the importance of vacuum technology in the design and operation of particle accelerators at CERN and at the many other accelerators already installed around the world, this was the first time that CAS has organized a course devoted entirely to this topic. Perhaps this reflects the facts that vacuum has become one of the more critical aspects of future accelerators, and that many of the pioneers in the accelerator field are being replaced by new, younger personnel. The lectures start with the basic concepts of the physics and technology of vacuum followed by detailed descriptions of the many different types of gas-pumping devices and methods to measure the pressures achieved. The outgassing characteristics of the different materials used in the construction of vacuum systems and the optimisation of cleaning methods to reduce this outgassing are then explained together with the effects of the residual gases on the particle beams. Then follow chapters on leak detection, materials and vacuum system engineering. Finally, seminars are presented on designing vacuum systems, the history of vacuum devices, the LHC (large hadron collider) vacuum system, vacuum systems for electron storage rings, and quality assurance for vacuum. (orig.)

ULTRARAPID VACUUM-MICROWAVE HISTOPROCESSING

NARCIS (Netherlands)

KOK, LP; BOON, ME

A novel histoprocessing method for paraffin sections is presented in which the combination of vacuum and microwave exposure is the key element. By exploiting the decrease in boiling temperature under vacuum, the liquid molecules in the tissues have been successfully extracted and exchanged at

Mutagenesis of Trichoderma Viride by Ultraviolet and Plasma

International Nuclear Information System (INIS)

Yao Risheng; Li Manman; Deng Shengsong; Hu Huajia; Wang Huai; Li Fenghe

2012-01-01

Considering the importance of a microbial strain capable of increased cellulase production, a mutant strain UP4 of Trichoderma viride was developed by ultraviolet (UV) and plasma mutation. The mutant produced a 21.0 IU/mL FPase which was 98.1% higher than that of the parent strain Trichoderma viride ZY-1. In addition, the effect of ultraviolet and plasma mutagenesis was not merely simple superimposition of single ultraviolet mutation and single plasma mutation. Meanwhile, there appeared a capsule around some of the spores after the ultraviolet and plasma treatment, namely, the spore surface of the strain became fuzzy after ultraviolet or ultraviolet and plasma mutagenesis.

Mutagenesis of Trichoderma Viride by Ultraviolet and Plasma

Science.gov (United States)

Yao, Risheng; Li, Manman; Deng, Shengsong; Hu, Huajia; Wang, Huai; Li, Fenghe

2012-04-01

Considering the importance of a microbial strain capable of increased cellulase production, a mutant strain UP4 of Trichoderma viride was developed by ultraviolet (UV) and plasma mutation. The mutant produced a 21.0 IU/mL FPase which was 98.1% higher than that of the parent strain Trichoderma viride ZY-1. In addition, the effect of ultraviolet and plasma mutagenesis was not merely simple superimposition of single ultraviolet mutation and single plasma mutation. Meanwhile, there appeared a capsule around some of the spores after the ultraviolet and plasma treatment, namely, the spore surface of the strain became fuzzy after ultraviolet or ultraviolet and plasma mutagenesis.

Soft, embodied, situated & connected: enriching interactions with soft wearbles

NARCIS (Netherlands)

Tomico Plasencia, O.; Wilde, D.

2016-01-01

Soft wearables include clothing and textile-based accessories that incorporate smart textiles and soft electronic interfaces to enable responsive and interactive experiences. When designed well, soft wearables leverage the cultural, sociological and material qualities of textiles, fashion and dress;

Selection of vacuum seals for EBT-P

International Nuclear Information System (INIS)

Dillow, C.F.; Adlon, G.L.; Stubblefield, V.E.

1981-01-01

Elmo Bumpy Torus Proof of Principle (EBT-P) is a magnetic fusion RandD facility being constructed by McDonnell Douglas Astronautics Company - St. Louis Division of Oak Ridge National Laboratory (ORNL). EBT-P is a truly unique fusion device requiring careful consideration in selecting both the primary vacuum seals on the toroidal vessel and the secondary vacuum seals in components such as vacuum pumps and and valves. The vacuum seal environment is described and the considerations in vacuum seal selection fully discussed. Methods for protecting vacuum seals in pumps and valves from the microwave environments are also presented

Photodetector of ultra-violet radiation

International Nuclear Information System (INIS)

Dorogan, V.; Vieru, T.; Coseac, V.; Chirita, F.

1999-01-01

The invention relates to photodetectors on the semiconductors base, in particular, to photodetectors of ultra-violet radiation and can be used in the optoelectronics systems for determining the intensity and dose of ultraviolet radiation emitted by the Sun and other sources. In the structure of the photodetector of ultraviolet radiation with a superficial potential barrier formed of semiconductors A 3 B 5 with the prohibited power width Eg 1 , solid solutions thereof with the prohibited power width Eg 2 and SnO 2 or ITO, in the semiconductors A 3 B 5 at a surface distance less than the absorption length of the visible radiation it is formed an isotype heterojunction between the semiconductors A 3 B 5 and solid solutions thereof with the prohibited power width Eg 2 > Eg 1 . The technical result consists in manufacturing of a photodetector sensitive solely to the ultraviolet radiation

Soft CP violation and the global matter-antimatter symmetry of the universe

Science.gov (United States)

Senjanovic, G.; Stecker, F. W.

1980-01-01

Scenarios for baryon production are considered within the context of SU(5) and SO(10) grand unified theories where CP violation arises spontaneously. The spontaneous CP symmetry breaking then results in a matter-antimatter domain structure in the universe. Two possible, distinct types of theories of soft CP violation are defined. In the first type the CP nonconservation originates only from the breaking of SU(2) sub L X U(1) symmetry, and in the second type, even at the unification temperature scale, CP violation can emerge as a result of symmetry breaking by the vacuum expectation values of the superheavy Higgs sector scalars.

Vacuum transitions in dual models

International Nuclear Information System (INIS)

Pashnev, A.I.; Volkov, D.V.; Zheltukhin, A.A.

1976-01-01

The investigation is continued of the spontaneous vacuum transition problem in the Neview-Schwartz dual model (NSDM). It is shown that vacuum transitions allow disclosing of supplementary degeneration in the resonance state spectrum. The dual amplitudes possess an internal structure corresponding to the presence of an infinite number of quarks with increasing masses and retained charges. The Adler principle holds. Analytic continuation on the constant of induced vacuum transitions makes it possible to establish the existence of spontaneous vacuum transitions in the NSDM. The consequence of this fact is the exact SU(2) symmetry of π, rho meson trajectories and the Higgs mechanism in the model. In this case the ratios of masses of particles leading trajectories are analogous to those obtained in the current algebra. It is shown that in the NSDM there arises chiral SU(2) x SU(2) x U(1) x U(1) x ... symmetry resulting from spontaneous vacuum transitions

Film self-assembly properties of vacuum residua from crude oil and correlation to the stability of water/crude oil emulsions[Supercritical fluid extraction and fractional technology (SFEF)

Energy Technology Data Exchange (ETDEWEB)

Peng, Bo

2005-07-01

In this thesis, SFEF technology has been used to obtain a fine separation of vacuum residua. Three kinds of vacuum residua from Iranian Heavy Crude Oil, Iranian Light Crude Oil and Daqing Crude Oil have been separated respectively into three series narrow cut fractions as a function of the average molecular weight. And their molecular parameters have been characterized by Vapour Pressure Osmometry(VPO) system, Ultraviolet(UV) spectroscopy, Infrared(IR) spectroscopy as well as by elemental analysis. The various fractions of vacuum residua have been added to an oil/water model system. The oil phase used was pure heptane, pure toluene, a mixture of heptane and toluene etc. Various properties of the interfacial film have been studied such as the self-assembly properties, interfacial tension and interfacial viscosity, etc. The self-assembly procedure of interfacial film of vacuum residua fractions were focused by means of the Wilhelmy plate method (Paper 1). The self-assembly states of interfacial film of vacuum residua fraction from Iranian Heavy and Daqing crude oil have been revealed by using Langmuir-Blodgett technology respectively (Paper II and Paper III). From measurement of the interfacial shear viscosity, the mechanical strength of the interfacial film formed by the vacuum residua fraction has been described (Paper IV) and the roles of the surfactants added in the interfacial film have been confirmed (Paper V). At the same time, the oil/water interfacial tensions of vacuum residua fractions from the three kinds of crude oil have been studied and compared (Paper VI and Paper VII). Characteristic properties of emulsions stabilized by the vacuum residua, such as Zeta potential (Paper VIII) and particle size distribution (Paper IX), have also been studied. An attempt has been made to explain the variations of emulsion properties in terms of the interfacial self-assembly of vacuum residua fractions. Finally, based up the above research and using chemometric methods

Vacuum maintenance in vacuum insulation panels exemplified with a staggered beam VIP

Energy Technology Data Exchange (ETDEWEB)

Kwon, Jae-Sung; Jang, Choong Hyo; Jung, Haeyong; Song, Tae-Ho [Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology, Guseong-dong 373-1, Yuseong-gu, Daejeon (Korea, Republic of)

2010-05-15

Thermal insulation performance of a vacuum insulation panel (VIP) is highly dependent on the inner pressure of the VIP. Long-term vacuum maintenance characteristics are investigated in this study for a VIP with an example of polymer staggered beam structure as the core material. Various gas sources deteriorating the vacuum level in the VIP are investigated based on theoretical models and experiments. Gas permeation occurring through heat-sealed flanges and pinholes in the barrier envelope is the largest gas leakage source. The calculated gas permeation rate is in accordance with the experimental result. To reduce these permeations, a three-side sealing envelope and double enveloping are proposed. Outgassing from the core material and inner surface of the envelope is also critical. It is significantly reduced by a baking pre-treatment in vacuum. When the estimated total gas load exceeds the allowable limit within a few years, a getter material may be applied. Double enveloping structure with a getter is promising as it ensures a lifetime of more than 20 years. (author)

Vacuum guidelines for ISA insertions

International Nuclear Information System (INIS)

Edwards, D. Jr.

1976-01-01

Vacuum requirements place design restrictions on the ISA insertions. The vacuum tube diameter, given a distance L between pumps, is determined by the desorption of molecules from the wall under the impact of ions created by the beam, whereas the thickness of the tube must be sufficient to prevent collapse. In addition, the entire vacuum chamber must be able to be baked out at approximately 200 0 C

Particle contamination in vacuum systems

International Nuclear Information System (INIS)

Martignac, J.; Bonin, B.; Henriot, C.; Poupeau, J.P.; Koltchakian, I.; Kocic, D.; Herbeaux, Ch.; Marx, J.P.

1996-01-01

Many vacuum devices, like RF cavities, are sensitive to particle contamination. This fact has motivated a considerable effort of cleanliness from the SRF community. The present paper reports the first results of a general study trying to identify the most contaminating steps during assembly and vacuum operation of the cavity. The steps investigated here are gasket assembly, evacuation and venting of the vacuum system, and operation of sputter ion pumps. (author)

Particle contamination in vacuum systems

International Nuclear Information System (INIS)

Martignac, J.; Bonin, B.; Henriot, C.; Poupeau, J.P.; Koltchakian, I.; Kocic, D.; Herbeaux, Ch.; Marx, J.P.

1996-01-01

Many vacuum devices, like RF cavities, are sensitive to particle contamination. This fact has motivated a considerable effort of cleanliness from the SRF community. The first results of a general study trying to identify the most contaminating steps during assembly and vacuum operation of the cavity is reported. The steps investigated here are gasket assembly, evacuation and venting of the vacuum system, and operation of sputter ion pumps. (author)

Soft electronics for soft robotics

Science.gov (United States)

Kramer, Rebecca K.

2015-05-01

As advanced as modern machines are, the building blocks have changed little since the industrial revolution, leading to rigid, bulky, and complex devices. Future machines will include electromechanical systems that are soft and elastically deformable, lending them to applications such as soft robotics, wearable/implantable devices, sensory skins, and energy storage and transport systems. One key step toward the realization of soft systems is the development of stretchable electronics that remain functional even when subject to high strains. Liquid-metal traces embedded in elastic polymers present a unique opportunity to retain the function of rigid metal conductors while leveraging the deformable properties of liquid-elastomer composites. However, in order to achieve the potential benefits of liquid-metal, scalable processing and manufacturing methods must be identified.

Research on vacuum insulation for cryocables

International Nuclear Information System (INIS)

Graneau, P.

1974-01-01

Vacuum insulation, as compared with solid insulation, simplifies the construction of both resistive or superconducting cryogenic cables. The common vacuum space in the cable can furnish thermal insulation between the environment and the cryogenic coolant, provide electrical insulation between conductors, and establish thermal isolation between go- and return-coolant streams. The differences between solid and vacuum high voltage insulation are discussed, and research on the design, materials selection, and testing of vacuum insulated cryogenic cables is described

Vacuum-insulated catalytic converter

Science.gov (United States)

Benson, David K.

2001-01-01

A catalytic converter has an inner canister that contains catalyst-coated substrates and an outer canister that encloses an annular, variable vacuum insulation chamber surrounding the inner canister. An annular tank containing phase-change material for heat storage and release is positioned in the variable vacuum insulation chamber a distance spaced part from the inner canister. A reversible hydrogen getter in the variable vacuum insulation chamber, preferably on a surface of the heat storage tank, releases hydrogen into the variable vacuum insulation chamber to conduct heat when the phase-change material is hot and absorbs the hydrogen to limit heat transfer to radiation when the phase-change material is cool. A porous zeolite trap in the inner canister absorbs and retains hydrocarbons from the exhaust gases when the catalyst-coated substrates and zeolite trap are cold and releases the hydrocarbons for reaction on the catalyst-coated substrate when the zeolite trap and catalyst-coated substrate get hot.

Ultraviolet light - nature's own disinfection process

Energy Technology Data Exchange (ETDEWEB)

Munkeberg, T [Thorolf Gregersen a/s, Oslo (Norway)

1978-05-18

Ultraviolet radiation from the sun is the means by which natural pollution products, as well as much of the smaller amount of pollution products produced by man, are converted and returned to the cycle of nature. Artificial ultraviolet radiation offers an optimum method for the disinfection of drinking water and can be used in the long term without undesireable effects on man or the enviromment. There is no evidence that ultraviolet irradiation leads to radiation resistant mutations of bacteria. The geometrical arrangement of ultraviolet disinfection units is described and the capacities of typical units is mentioned as being 600-800 m/sup 3/ /hr, though there is no reason why this should not be increased.

Ultraviolet light - nature's own disinfection process

International Nuclear Information System (INIS)

Munkeberg, T.

1978-01-01

Ultraviolet radiation from the sun is the means by which natural pollution products, as well as much of the smaller amount of pollution products produced by man, are converted and returned to the cycle of nature. Artificial ultraviolet radiation offers an optimum method for the disinfection of drinking water and can be used in the long term without undesireable effects on man or the enviromment. There is no evidence that ultraviolet irradiation leads to radiation resistant mutations of bacteria. The geometrical arrangement of ultraviolet disinfection units is described and the capacities of typical units is mentioned as being 600-800 m 3 /hr, though there is no reason why this should not be increased. (JIW)

Spent nuclear fuel project cold vacuum drying facility vacuum and purge system design description

Energy Technology Data Exchange (ETDEWEB)

IRWIN, J.J.

1998-11-30

This document provides the System Design Description (SDD) for the Cold Vacuum Drying Facility (CVDF) Vacuum and Purge System (VPS) . The SDD was developed in conjunction with HNF-SD-SNF-SAR-O02, Safety Analysis Report for the Cold Vacuum Drying Facility, Phase 2, Supporting Installation of Processing Systems (Garvin 1998), The HNF-SD-SNF-DRD-002, 1998, Cold Vacuum Drying Facility Design Requirements, and the CVDF Design Summary Report. The SDD contains general descriptions of the VPS equipment, the system functions, requirements and interfaces. The SDD provides references for design and fabrication details, operation sequences and maintenance. This SDD has been developed for the SNFP Operations Organization and shall be updated, expanded, and revised in accordance with future design, construction and startup phases of the CVDF until the CVDF final ORR is approved.

Spent nuclear fuel project cold vacuum drying facility vacuum and purge system design description

International Nuclear Information System (INIS)

IRWIN, J.J.

1998-01-01

This document provides the System Design Description (SDD) for the Cold Vacuum Drying Facility (CVDF) Vacuum and Purge System (VPS) . The SDD was developed in conjunction with HNF-SD-SNF-SAR-O02, Safety Analysis Report for the Cold Vacuum Drying Facility, Phase 2, Supporting Installation of Processing Systems (Garvin 1998), The HNF-SD-SNF-DRD-002, 1998, Cold Vacuum Drying Facility Design Requirements, and the CVDF Design Summary Report. The SDD contains general descriptions of the VPS equipment, the system functions, requirements and interfaces. The SDD provides references for design and fabrication details, operation sequences and maintenance. This SDD has been developed for the SNFP Operations Organization and shall be updated, expanded, and revised in accordance with future design, construction and startup phases of the CVDF until the CVDF final ORR is approved

Color-magnetic permeability of QCD vacuum

Energy Technology Data Exchange (ETDEWEB)

Saito, T [Kyoto Prefectural Univ. of Medicine (Japan); Shigemoto, K

1980-03-01

In the very strong background gauge field the QCD true vacuum has been shown to have lower energy than the ''perturbative vacuum.'' The color-magnetic permeability of the QCD true vacuum is then calculated to be 1/2 within the quark-one-loop approximation.

Vacuum vessel for thermonuclear device

International Nuclear Information System (INIS)

Kikuchi, Mitsuru; Kurita, Gen-ichi; Onozuka, Masaki; Suzuki, Masaru.

1997-01-01

Heat of inner walls of a vacuum vessel that receive radiation heat from plasmas by way of first walls is removed by a cooling medium flowing in channels for cooling the inner walls. Nuclear heat generation of constitutional materials of the vacuum vessel caused by fast neutrons and γ rays is removed by a cooling medium flowing in cooling channels disposed in the vacuum vessel. Since the heat from plasmas and the nuclear heat generation are removed separately, the amount of the cooling medium flowing in the channels for cooling inner walls is increased for cooling a great amount of heat from plasmas while the amount of the cooling medium flowing in the channels for cooling the inside of the vacuum vessel is reduced for cooling the small amount of nuclear heat generation. Since the amount of the cooling medium can thus be optimized, the capacity of the facilities for circulating the cooling medium can be reduced. In addition, since the channels for cooling the inner walls and the channels of cooling medium formed in the vacuum vessel are disposed to the inner walls of the vacuum vessel on the side opposite to plasmas, integrity of the channels relative to leakage of the cooling medium can be ensured. (N.H.)

Vacuum vessel for thermonuclear device

Energy Technology Data Exchange (ETDEWEB)

Kikuchi, Mitsuru; Kurita, Gen-ichi [Japan Atomic Energy Research Inst., Tokyo (Japan); Onozuka, Masaki; Suzuki, Masaru

1997-07-31

Heat of inner walls of a vacuum vessel that receive radiation heat from plasmas by way of first walls is removed by a cooling medium flowing in channels for cooling the inner walls. Nuclear heat generation of constitutional materials of the vacuum vessel caused by fast neutrons and {gamma} rays is removed by a cooling medium flowing in cooling channels disposed in the vacuum vessel. Since the heat from plasmas and the nuclear heat generation are removed separately, the amount of the cooling medium flowing in the channels for cooling inner walls is increased for cooling a great amount of heat from plasmas while the amount of the cooling medium flowing in the channels for cooling the inside of the vacuum vessel is reduced for cooling the small amount of nuclear heat generation. Since the amount of the cooling medium can thus be optimized, the capacity of the facilities for circulating the cooling medium can be reduced. In addition, since the channels for cooling the inner walls and the channels of cooling medium formed in the vacuum vessel are disposed to the inner walls of the vacuum vessel on the side opposite to plasmas, integrity of the channels relative to leakage of the cooling medium can be ensured. (N.H.)

An ultra-high-vacuum multiple grating chamber and scan drive with improved grating change

International Nuclear Information System (INIS)

Hulbert, S.L.; Holly, D.J.; Middleton, F.H.; Wallace, D.J.; Wisconsin Univ., Stoughton, WI; Wisconsin Univ., Stoughton, WI

1989-01-01

We describe a new grating chamber and scan drive which has been designed, built, and tested by Physical Sciences Laboratory of the University of Wisconsin for the new high flux, high-resolution spectroscopy branch line of the TOK hybrid wiggler/undulator on the NSLS VUV ring. The chamber will contain spherical gratings to be used in the Spherical Grating Monochromator (SGM) configuration introduced by Chen and Sette. The grating chamber houses five 180 mm x 35 mm x 30 mm gratings capable of scanning a range of 12 degree (-14 degree to +8 degree with respect to the incoming beam direction) for VUV and soft X-ray diffraction. The gratings can be switched and precisely indexed while under ultra-high vacuum (UHV) at any scan angle and are mechanically isolated from the vacuum chamber to prevent inaccuracies due to chamber distortions. The gratings can separately be adjusted for height, yaw, pitch, and roll, with the latter three performed while in vacuo. The scan drive provides a resolution of 0.03 arc sec with linearity over the 12 degree range of ∼1.5 arc sec and absolute reproducibility of 1 arc sec. 5 refs., 5 figs

Generation of Bright, Spatially Coherent Soft X-Ray High Harmonics in a Hollow Waveguide Using Two-Color Synthesized Laser Pulses.

Science.gov (United States)

Jin, Cheng; Stein, Gregory J; Hong, Kyung-Han; Lin, C D

2015-07-24

We investigate the efficient generation of low-divergence high-order harmonics driven by waveform-optimized laser pulses in a gas-filled hollow waveguide. The drive waveform is obtained by synthesizing two-color laser pulses, optimized such that highest harmonic yields are emitted from each atom. Optimization of the gas pressure and waveguide configuration has enabled us to produce bright and spatially coherent harmonics extending from the extreme ultraviolet to soft x rays. Our study on the interplay among waveguide mode, atomic dispersion, and plasma effect uncovers how dynamic phase matching is accomplished and how an optimized waveform is maintained when optimal waveguide parameters (radius and length) and gas pressure are identified. Our analysis should help laboratory development in the generation of high-flux bright coherent soft x rays as tabletop light sources for applications.

Ultra high vacuum systems for accelerators

International Nuclear Information System (INIS)

Loefgren, P.

2001-01-01

Full text: In order to perform controlled, stable, and reproducible experiments, several research areas today require very low pressures. Maybe the most important example is the research that is performed in storage rings and accelerators where the lifetime and stability of particle beams depends critically on the vacuum conditions. Although the vacuum requirements ultimately depend on the kind of experiments that is performed, the studies of more and more rare and exotic species in storage rings and accelerators today pushes the demands on the vacuum conditions towards lower and lower pressures. The final pressure obtained in the vacuum system can often be the key factor for the outcome of an experiment. Pioneering work in vacuum technology has therefore often been performed at storage rings and accelerator facilities around the world. In order to reach pressures in the low UHV regime and lower (below 10 -11 mbar), several aspects have to be considered which implies choosing the proper materials, pumps and vacuum gauges. In the absence of gases inleaking from the outside, the rate of gas entering a vacuum system is determined by the release of molecules adsorbed on the surfaces and the outgassing from the bulk of the vacuum chamber walls. This means that the choice of material and, equally important, the pre treatment of the material, must be such that these rates are minimised. Today the most widely used material for vacuum applications are stainless steel. Besides its many mechanical advantages, it is resistant to corrosion and oxidation. If treated correctly the major gas source in a stainless steel chamber is hydrogen outgassing from the chamber walls. The hydrogen outgassing can be decreased by vacuum firing at 950 deg. C under vacuum. In addition to choosing the right materials the choice of vacuum pumps is important for the final pressure. Since no vacuum pump is capable of taking care of all kinds of gases found in the rest gas at pressures below 10 -11

Wireless Integrated Microelectronic Vacuum Sensor System

Science.gov (United States)

Krug, Eric; Philpot, Brian; Trott, Aaron; Lawrence, Shaun

2013-01-01

NASA Stennis Space Center's (SSC's) large rocket engine test facility requires the use of liquid propellants, including the use of cryogenic fluids like liquid hydrogen as fuel, and liquid oxygen as an oxidizer (gases which have been liquefied at very low temperatures). These fluids require special handling, storage, and transfer technology. The biggest problem associated with transferring cryogenic liquids is product loss due to heat transfer. Vacuum jacketed piping is specifically designed to maintain high thermal efficiency so that cryogenic liquids can be transferred with minimal heat transfer. A vacuum jacketed pipe is essentially two pipes in one. There is an inner carrier pipe, in which the cryogenic liquid is actually transferred, and an outer jacket pipe that supports and seals the vacuum insulation, forming the "vacuum jacket." The integrity of the vacuum jacketed transmission lines that transfer the cryogenic fluid from delivery barges to the test stand must be maintained prior to and during engine testing. To monitor the vacuum in these vacuum jacketed transmission lines, vacuum gauge readings are used. At SSC, vacuum gauge measurements are done on a manual rotation basis with two technicians, each using a handheld instrument. Manual collection of vacuum data is labor intensive and uses valuable personnel time. Additionally, there are times when personnel cannot collect the data in a timely fashion (i.e., when a leak is detected, measurements must be taken more often). Additionally, distribution of this data to all interested parties can be cumbersome. To simplify the vacuum-gauge data collection process, automate the data collection, and decrease the labor costs associated with acquiring these measurements, an automated system that monitors the existing gauges was developed by Invocon, Inc. For this project, Invocon developed a Wireless Integrated Microelectronic Vacuum Sensor System (WIMVSS) that provides the ability to gather vacuum

Baking results of KSTAR vacuum vessel

International Nuclear Information System (INIS)

Kim, S. T.; Kim, Y. J.; Kim, K. M.; Im, D. S.; Joung, N. Y.; Yang, H. L.; Kim, Y. S.; Kwon, M.

2009-01-01

The Korea Superconducting Tokamak Advanced Research (KSTAR) is an advanced superconducting tokamak designed to establish a scientific and technological basis for an attractive fusion reactor. The fusion energy in the tokamak device is released through fusion reactions of light atoms such as deuterium or helium in hot plasma state, of which temperature reaches several hundreds of millions Celsius. The high temperature plasma is created in the vacuum vessel that provides ultra high vacuum status. Accordingly, it is most important for the vacuum condition to keep clean not only inner space but also surface of the vacuum vessel to make high quality plasma. There are two methods planned to clean the wall surface of the KSTAR vacuum vessel. One is surface baking and the other is glow discharge cleaning (GDC). To bake the vacuum vessel, De-Ionized (DI) water is heated to 130 .deg. C and circulated in the passage between double walls of the vacuum vessel (VV) in order to bake the surface. The GDC operation uses hydrogen and inert gas discharges. In this paper, general configuration and brief introduction of the baking result will be reported

Baking results of KSTAR vacuum vessel

Energy Technology Data Exchange (ETDEWEB)

Kim, S. T.; Kim, Y. J.; Kim, K. M.; Im, D. S.; Joung, N. Y.; Yang, H. L.; Kim, Y. S.; Kwon, M. [National Fusion Research Institute, Daejeon (Korea, Republic of)

2009-05-15

The Korea Superconducting Tokamak Advanced Research (KSTAR) is an advanced superconducting tokamak designed to establish a scientific and technological basis for an attractive fusion reactor. The fusion energy in the tokamak device is released through fusion reactions of light atoms such as deuterium or helium in hot plasma state, of which temperature reaches several hundreds of millions Celsius. The high temperature plasma is created in the vacuum vessel that provides ultra high vacuum status. Accordingly, it is most important for the vacuum condition to keep clean not only inner space but also surface of the vacuum vessel to make high quality plasma. There are two methods planned to clean the wall surface of the KSTAR vacuum vessel. One is surface baking and the other is glow discharge cleaning (GDC). To bake the vacuum vessel, De-Ionized (DI) water is heated to 130 .deg. C and circulated in the passage between double walls of the vacuum vessel (VV) in order to bake the surface. The GDC operation uses hydrogen and inert gas discharges. In this paper, general configuration and brief introduction of the baking result will be reported.

Friction, Wear, and Evaporation Rates of Various Materials in Vacuum to 10(exp -7) mm Hg

Science.gov (United States)

Buckley, Donald H.; Swikert, Max; Johnson, Robert L.

1961-01-01

The requirements for bearings and seals to operate in the environment of space dictate a new area for lubrication research. The low ambient pressures encountered in space can be expected to influence the behavior of oil, grease, and solid-film lubricants. The property of these materials most significantly affected by low ambient pressures is the evaporation rate. Various investigators have therefore measured the evaporation rates of oils and greases in vacuum as one method of establishing their relative merit for space applications (1-3). The results of this work have given some indication as to the oils and greases with the greatest stability at reduced ambient pressures. Only limited experimental work, however, has been reported in the literature for inorganic solids and soft metals which have potential use as solid lubricant films or coatings for hard alloy substrates [e.g. Reference ( 4 )]. In general, the evaporation rates of these materials would be lower than those of oils and greases. These films might therefore be very attractive as lubricants for high vacuum service.

High-precision soft x-ray polarimeter at Diamond Light Source.

Science.gov (United States)

Wang, H; Dhesi, S S; Maccherozzi, F; Cavill, S; Shepherd, E; Yuan, F; Deshmukh, R; Scott, S; van der Laan, G; Sawhney, K J S

2011-12-01

The development and performance of a high-precision polarimeter for the polarization analysis in the soft x-ray region is presented. This versatile, high-vacuum compatible instrument is supported on a hexapod to simplify the alignment with a resolution less than 5 μrad, and can be moved with its own independent control system easily between different beamlines and synchrotron facilities. The polarimeter can also be used for the characterization of reflection and transmission properties of optical elements. A W/B(4)C multilayer phase retarder was used to characterize the polarization state up to 1200 eV. A fast and accurate alignment procedure was developed, and complete polarization analysis of the APPLE II undulator at 712 eV has been performed.

Far-ultraviolet spectral changes of titanium dioxide with gold nanoparticles by ultraviolet and visible light

Science.gov (United States)

Tanabe, Ichiro; Kurawaki, Yuji

2018-05-01

Attenuated total reflectance spectra including the far-ultraviolet (FUV, ≤ 200 nm) region of titanium dioxide (TiO2) with and without gold (Au) nanoparticles were measured. A newly developed external light-irradiation system enabled to observe spectral changes of TiO2 with Au nanoparticles upon light irradiations. Absorption in the FUV region decreased and increased by the irradiation with ultraviolet and visible light, respectively. These spectral changes may reflect photo-induced electron transfer from TiO2 to Au nanoparticles under ultraviolet light and from Au nanoparticles to TiO2 under visible light, respectively.

Abnormal sensitivity of diploid skin fibroblasts from a family with Gardner's syndrome to the lethal effects of X-irradiation, ultraviolet light and mitomycin-C

International Nuclear Information System (INIS)

Little, J.B.; Nove, J.; Weichselbaum, R.R.

1980-01-01

Skin fibroblasts isolated from two members of the same family with the cancer-prone disease Gardner's Syndrome (intestinal polyposis, colon cancer, bone and soft tissue tumors) showed enhanced sensitivity to the lethal effects of X-irradiation, ultraviolet light and mitomycin-C. These cells showed no liquid-holding type recovery following UV-irradiation of confluent cultures, but were normal in their capacity for UV-induced unscheduled DNA synthesis. UV survival was not influenced by post-irradiation incubation with caffeine. (orig.)

Vacuum system of SST-1 Tokamak

International Nuclear Information System (INIS)

Khan, Ziauddin; Pathan, Firozkhan; George, Siju; Semwal, Pratibha; Dhanani, Kalpesh; Paravastu, Yuvakiran; Thankey, Prashant; Ramesh, Gattu; Himabindu, Manthena; Pradhan, Subrata

2013-01-01

Highlights: ► Air leaks developed during ongoing SST-1 cooldown campaign were detected online using RGA. ► The presence of N 2 and O 2 gases with the ratio of their partial pressures with ∼3.81:1 confirmed the air leaks. ► Baking of SST-1 was done efficiently by flowing hot N 2 gas in C-channels welded on inner surfaces without any problem. ► In-house fabricated demountable bull nose couplers were demonstrated for high temperature and pressure applications. ► Cryopumping effect was observed when liquid helium cooled superconducting magnets reached below 63 K. -- Abstract: Vacuum chambers of Steady State Superconducting (SST-1) Tokamak comprises of the vacuum vessel and the cryostat. The plasma will be confined inside the vacuum vessel while the cryostat houses the superconducting magnet systems (TF and PF coils), LN 2 cooled thermal shields and hydraulics for these circuits. The vacuum vessel is an ultra-high (UHV) vacuum chamber while the cryostat is a high-vacuum (HV) chamber. In order to achieve UHV inside the vacuum vessel, it would be baked at 150 °C for longer duration. For this purpose, U-shaped baking channels are welded inside the vacuum vessel. The baking will be carried out by flowing hot nitrogen gas through these channels at 250 °C at 4.5 bar gauge pressure. During plasma operation, the pressure inside the vacuum vessel will be raised between 1.0 × 10 −4 mbar and 1.0 × 10 −5 mbar using piezoelectric valves and control system. An ultimate pressure of 4.78 × 10 −6 mbar is achieved inside the vacuum vessel after 100 h of pumping. The limitation is due to the development of few leaks of the order of 10 −5 mbar l/s at the critical locations of the vacuum vessel during baking which was confirmed with the presence of nitrogen gas and oxygen gas with the ratio of ∼3.81:1 indicating air leak. Similarly an ultimate vacuum of 2.24 × 10 −5 mbar is achieved inside the cryostat. Baking of the vacuum vessel up to 110 °C with ±10 �

Evacuation of the NET vacuum chamber

International Nuclear Information System (INIS)

Muller, R.A.

1987-01-01

Parametric calculations of the evacuation process were carried out for the NET-vacuum chamber involving two blanket designs. The results show that with an acceptable vacuum pumping capacity the required start vacuum conditions can be realized within reasonable time. The two blanket concepts do not differ remarkably in their evacuation behaviour. The remaining large pressure differences between the different locations of the vacuum chamber can be reduced if approximately 30% of the total gas flow is extracted from the heads of the blanket replacement ports

Evacuation of the NET vacuum chamber

International Nuclear Information System (INIS)

Mueller, R.

1986-01-01

Parametric calculations of the evacuation process were carried out for the NET-vacuum chamber involving two blanket designs. The results show that with an acceptable vacuum pumping capacity the required start vacuum conditions can be realized within reasonable time. The two blanket concepts do not differ remarkably in their evacuation behaviour. The remaining large pressure differences between the different locations of the vacuum chamber can be reduced if approximately 30% of the total gas flow is extracted from the heads of the blanket replacement ports. (author)

Soft leptogenesis

International Nuclear Information System (INIS)

D'Ambrosio, Giancarlo; Giudice, Gian F.; Raidal, Martti

2003-01-01

We study 'soft leptogenesis', a new mechanism of leptogenesis which does not require flavour mixing among the right-handed neutrinos. Supersymmetry soft-breaking terms give a small mass splitting between the CP-even and CP-odd right-handed sneutrino states of a single generation and provide a CP-violating phase sufficient to generate a lepton asymmetry. The mechanism is successful if the lepton-violating soft bilinear coupling is unconventionally (but not unnaturally) small. The values of the right-handed neutrino masses predicted by soft leptogenesis can be low enough to evade the cosmological gravitino problem

Vacuum Bellows, Vacuum Piping, Cryogenic Break, and Copper Joint Failure Rate Estimates for ITER Design Use

Energy Technology Data Exchange (ETDEWEB)

L. C. Cadwallader

2010-06-01

The ITER international project design teams are working to produce an engineering design in preparation for construction of the International Thermonuclear Experimental Reactor (ITER) tokamak. During the course of this work, questions have arisen in regard to safety barriers and equipment reliability as important facets of system design. The vacuum system designers have asked several questions about the reliability of vacuum bellows and vacuum piping. The vessel design team has asked about the reliability of electrical breaks and copper-copper joints used in cryogenic piping. Research into operating experiences of similar equipment has been performed to determine representative failure rates for these components. The following chapters give the research results and the findings for vacuum system bellows, power plant stainless steel piping (amended to represent vacuum system piping), cryogenic system electrical insulating breaks, and copper joints.

Big Bang or vacuum fluctuation

International Nuclear Information System (INIS)

Zel'dovich, Ya.B.

1980-01-01

Some general properties of vacuum fluctuations in quantum field theory are described. The connection between the ''energy dominance'' of the energy density of vacuum fluctuations in curved space-time and the presence of singularity is discussed. It is pointed out that a de-Sitter space-time (with the energy density of the vacuum fluctuations in the Einstein equations) that matches the expanding Friedman solution may describe the history of the Universe before the Big Bang. (P.L.)

Introducing a New Capability at SSRL: Resonant Soft X-ray Scattering

Science.gov (United States)

Lee, Jun-Sik; Jang, Hoyoung; Lu, Donghui; Kao, Chi-Chang

Stanford Synchrotron Radiation Lightsource (SSRL) at SLAC recently developed a setup for the resonant soft x-ray scattering (RSXS). In general, the RSXS technique uniquely probes not only structural information, but also chemical specific information. This is because this technique can explore the spatial periodicities of charge, orbital, spin, and lattice with spectroscopic aspect. Moreover, the soft x-ray range is particularly relevant for a study of soft materials as it covers the K-edge of C, N, F, and O, as well as the L-edges of transition metals and M-edges of rare-earth elements. Hence, the RSXS capability has been regarded as a very powerful technique for investigating the intrinsic properties of materials such as quantum- and energy-materials. The RSXS capability at the SSRL composes of in-vacuum 4-circle diffractometer. There are also the fully motorized sample-motion manipulations. Also, the sample can be cooled down to 25 K via the liquid helium. This capability has been installed at BL 13-3, where the photon source is from elliptically polarized undulator (EPU). Covering the photon energies is from 230 eV to 1400 eV. Furthermore, this EPU system offers more degree of freedoms for controlling x-ray polarizations (linear and circular). Using the advance of controlling x-ray polarization, we can also investigate a morphology effect of local domain/grain in materials. The detailed introduction of the RSXS end-station and several results will be touched in this poster presentation.

Ultraviolet spectrophotometry of three LINERs

Science.gov (United States)

Goodrich, R. W.; Keel, W. C.

1986-01-01

Three galaxies known to be LINERs were observed spectroscopically in the ultraviolet in an attempt to detect the presumed nonthermal continuum source thought to be the source of photoionization in the nuclei. NGC 4501 was found to be too faint for study with the IUE spectrographs, while NGC 5005 had an extended ultraviolet light profile. Comparison with the optical light profile of NGC 5005 indicates that the ultraviolet source is distributed spatially in the same manner as the optical starlight, probably indicating that the ultraviolet excess is due to a component of hot stars in the nucleus. These stars contribute detectable absorption features longward of 2500 A; together with optical data, the IUE spectra suggest a burst of star formation about 1 billion yr ago, with a lower rate continuing to produce a few OB stars. In NGC 4579, a point source contributing most of the ultraviolet excess is found that is much different than the optical light distribution. Furthermore, the ultraviolet to X-ray spectral index in NGC 4579 is 1.4, compatible with the UV to X-ray indices found for samples of Seyfert galaxies. This provides compelling evidence for the detection of the photoionizing continuum in NGC 4579 and draws the research fields of normal galaxies and active galactic nuclei closer together. The emission-line spectrum of NGC 4579 is compared with calculations from a photoionization code, CLOUDY, and several shock models. The photoionization code is found to give superior results, adding to the increasing weight of evidence that the LINER phenomenon is essentially a scaled-down version of the Seyfert phenomenon.

Bi-layered constructs of poly(glycerol-sebacate)-β-tricalcium phosphate for bone-soft tissue interface applications

Energy Technology Data Exchange (ETDEWEB)

Tevlek, Atakan [Bioengineering Division, Institute of Science and Engineering, Hacettepe University, Ankara (Turkey); Hosseinian, Pezhman; Ogutcu, Cansel [Nanotechnology and Nanomedicine Division, Institute of Science and Engineering, Hacettepe University, Ankara (Turkey); Turk, Mustafa [Biology Department, Kirikkale University, Kirikkale (Turkey); Aydin, Halil Murat, E-mail: hmaydin@hacettepe.edu.tr [Environmental Engineering Department, Bioengineering Division, Centre for Bioengineering, Hacettepe University, Ankara (Turkey)

2017-03-01

This study aims to establish a facile protocol for the preparation of a bi-layered poly(glycerol-sebacate) (PGS)/β-tricalcium phosphate (β-TCP) construct and to investigate its potential for bone-soft tissue engineering applications. The layered structure was prepared by distributing the ceramic particles within a prepolymer synthesized in a microwave reactor followed by a cross-linking of the final construct in vacuum (< 10 mbar). The vacuum stage led to the separation of cross-linked elastomer (top) and ceramic (bottom) phases. Results showed that addition of β-TCP particles to the elastomer matrix after the polymerization led to an increase in compression strength (up to 14 ± 2.3 MPa). Tensile strength (σ), Young's modulus (E), and elongation at break (%) values were calculated as 0.29 ± 0.03 MPa and 0.21 ± 0.03; 0.38 ± 0.02 and 1.95 ± 0.4; and 240 ± 50% and 24 ± 2% for PGS and PGS/β-TCP bi-layered constructs, respectively. Morphology was characterized by using Scanning Electron Microscopy (SEM) and micro-computed tomography (μ-CT). Tomography data revealed an open porosity of 35% for the construct, mostly contributed from the ceramic phase since the elastomer side has no pore. Homogeneous β-TCP distribution within the elastomeric structure was observed. Cell culture studies confirmed biocompatibility with poor elastomer-side and good bone-side cell attachment. In a further study to investigate the osteogenic properties, the construct were loaded with BMP-2 and/or TGF-β1. The PGS/β-TCP bi-layered constructs with improved mechanical and biological properties have the potential to be used in bone-soft tissue interface applications where soft tissue penetration is a problem. - Highlights: • Biodegradable bi-layered constructs with elastomer and ceramic sides were prepared. • The constructs could be a promising material in guided bone regeneration. • Elastomer side of the construct acts as a barrier to prevent soft tissue ingrowth. �

Vacuum vessel for thermonuclear device

International Nuclear Information System (INIS)

Kikuchi, Mitsuru; Nagashima, Keisuke; Suzuki, Masaru; Onozuka, Masaki.

1997-01-01

A vacuum vessel main body and structural members at the inside and the outside of the vacuum vessel main body are constituted by structural materials activated by irradiation of neutrons from plasmas such as stainless steels. Shielding members comprising tungsten or molybdenum are disposed on the surface of the vacuum vessel main body and the structural members of the inside and the outside of the main body. The shielding members have a function also as first walls or a seat member for the first walls. Armor tiles may be disposed to the shielding members. The shielding members and the armor tiles are secured to a securing seat member disposed, for example, to an inner plate of the vacuum vessel main body by bolts. Since the shielding members are disposed, it is not necessary to constitute the vacuum vessel main body and the structural members at the inside and the outside thereof by using a low activation material which is less activated, such as a titanium alloy. (I.N.)

Vacuum vessel for thermonuclear device

Energy Technology Data Exchange (ETDEWEB)

Kikuchi, Mitsuru; Nagashima, Keisuke [Japan Atomic Energy Research Inst., Tokyo (Japan); Suzuki, Masaru; Onozuka, Masaki

1997-07-11

A vacuum vessel main body and structural members at the inside and the outside of the vacuum vessel main body are constituted by structural materials activated by irradiation of neutrons from plasmas such as stainless steels. Shielding members comprising tungsten or molybdenum are disposed on the surface of the vacuum vessel main body and the structural members of the inside and the outside of the main body. The shielding members have a function also as first walls or a seat member for the first walls. Armor tiles may be disposed to the shielding members. The shielding members and the armor tiles are secured to a securing seat member disposed, for example, to an inner plate of the vacuum vessel main body by bolts. Since the shielding members are disposed, it is not necessary to constitute the vacuum vessel main body and the structural members at the inside and the outside thereof by using a low activation material which is less activated, such as a titanium alloy. (I.N.)

Ultraviolet safety assessments of insect light traps.

Science.gov (United States)

Sliney, David H; Gilbert, David W; Lyon, Terry

2016-01-01

Near-ultraviolet (UV-A: 315-400 nm), "black-light," electric lamps were invented in 1935 and ultraviolet insect light traps (ILTs) were introduced for use in agriculture around that time. Today ILTs are used indoors in several industries and in food-service as well as in outdoor settings. With recent interest in photobiological lamp safety, safety standards are being developed to test for potentially hazardous ultraviolet emissions. A variety of UV "Black-light" ILTs were measured at a range of distances to assess potential exposures. Realistic time-weighted human exposures are shown to be well below current guidelines for human exposure to ultraviolet radiation. These UV-A exposures would be far less than the typical UV-A exposure in the outdoor environment. Proposals are made for realistic ultraviolet safety standards for ILT products.

Design consideration on the synchrotron ultrahigh vacuum system

International Nuclear Information System (INIS)

Tsujikawa, H.; Chida, K.; Mizobuchi, A.; Miyahara, A.

1982-01-01

Ultrahigh vacuum production for the high-energy heavy-ion accelerator poses special problems concerning beam-gas molecule and beam-wall interactions. In this paper, summary of the TARN ultrahigh vacuum system and design criteria of the synchrotron ultrahigh vacuum system are presented. On-beam pressure of 4 x 10 -11 Torr is achieved in the TARN ultrahigh vacuum system, of which experiences through the construction and the operation are described and discussed. With emphasis on the application of newly developed technique in the fabrication of vacuum chamber and ultrahigh vacuum pump for the synchrotron ultrahigh vacuum system. (author)

Vacuum status-display and sector-conditioning programs

International Nuclear Information System (INIS)

Skelly, J.; Yen, S.

1989-01-01

Two programs have been developed for observation and control of the AGS vacuum system, which include these notable features: they incorporate a graphical user interface, and they are driven by a relational database which describes the vacuum system. The vacuum system comprises some 440 devices organized into 28 vacuum sectors. The Status Display Program invites menu selection of a sector, interrogates the relational database for relevant vacuum devices, acquires live readbacks, and posts a graphical display of their status. The Sector Conditioning Program likewise invites sector selection, produces the same status display, and also implements process control logic on the sector devices to pump the sector down from atmospheric pressure to high vacuum over a period extending for several hours. As additional devices are installed in the vacuum system, the devices are likewise added to the relational database; these programs then automatically include the new devices. 2 refs., 1 fig

Dynamical effects of QCD vacuum structure

International Nuclear Information System (INIS)

Ferreira, Erasmo

1994-01-01

The role of the QCD vacuum structure in the determination of the properties of states and processes occurring in the confinement regime of QCD is reviewed. The finite range of the vacuum correlations is discussed, and an analytical form is suggested for the correlation functions. The role of the vacuum quantum numbers in the phenomenology of high-energy scattering is reviewed. The vacuum correlation model of non-perturbative QCD is mentioned as a bridge between the fundamental theory and the description of the experiments. (author). 13 refs., 1 fig

Vacuum technology in the chemical industry

CERN Document Server

Jorisch, Wolfgang

2015-01-01

Based on the very successful German edition and a seminar held by the German Engineers` Association (VDI) on a regular basis for years now, this English edition has been thoroughly updated and revised to reflect the latest developments. It supplies in particular the special aspects of vacuum technology, applied vacuum pump types and vacuum engineering in the chemical, pharmaceutical and process industry application-segments. The text includes chapters dedicated to latest European regulations for operating in hazardous zones with vacuum systems, methods for process pressure control and regulati

Soft Robotics.

Science.gov (United States)

Whitesides, George M

2018-04-09

This description of "soft robotics" is not intended to be a conventional review, in the sense of a comprehensive technical summary of a developing field. Rather, its objective is to describe soft robotics as a new field-one that offers opportunities to chemists and materials scientists who like to make "things" and to work with macroscopic objects that move and exert force. It will give one (personal) view of what soft actuators and robots are, and how this class of soft devices fits into the more highly developed field of conventional "hard" robotics. It will also suggest how and why soft robotics is more than simply a minor technical "tweak" on hard robotics and propose a unique role for chemistry, and materials science, in this field. Soft robotics is, at its core, intellectually and technologically different from hard robotics, both because it has different objectives and uses and because it relies on the properties of materials to assume many of the roles played by sensors, actuators, and controllers in hard robotics. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Running vacuum cosmological models: linear scalar perturbations

Energy Technology Data Exchange (ETDEWEB)

Perico, E.L.D. [Instituto de Física, Universidade de São Paulo, Rua do Matão 1371, CEP 05508-090, São Paulo, SP (Brazil); Tamayo, D.A., E-mail: elduartep@usp.br, E-mail: tamayo@if.usp.br [Departamento de Astronomia, Universidade de São Paulo, Rua do Matão 1226, CEP 05508-900, São Paulo, SP (Brazil)

2017-08-01

In cosmology, phenomenologically motivated expressions for running vacuum are commonly parameterized as linear functions typically denoted by Λ( H {sup 2}) or Λ( R ). Such models assume an equation of state for the vacuum given by P-bar {sub Λ} = - ρ-bar {sub Λ}, relating its background pressure P-bar {sub Λ} with its mean energy density ρ-bar {sub Λ} ≡ Λ/8π G . This equation of state suggests that the vacuum dynamics is due to an interaction with the matter content of the universe. Most of the approaches studying the observational impact of these models only consider the interaction between the vacuum and the transient dominant matter component of the universe. We extend such models by assuming that the running vacuum is the sum of independent contributions, namely ρ-bar {sub Λ} = Σ {sub i} ρ-bar {sub Λ} {sub i} . Each Λ i vacuum component is associated and interacting with one of the i matter components in both the background and perturbation levels. We derive the evolution equations for the linear scalar vacuum and matter perturbations in those two scenarios, and identify the running vacuum imprints on the cosmic microwave background anisotropies as well as on the matter power spectrum. In the Λ( H {sup 2}) scenario the vacuum is coupled with every matter component, whereas the Λ( R ) description only leads to a coupling between vacuum and non-relativistic matter, producing different effects on the matter power spectrum.

46 CFR 154.804 - Vacuum protection.

Science.gov (United States)

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Vacuum protection. 154.804 Section 154.804 Shipping... Systems § 154.804 Vacuum protection. (a) Except as allowed under paragraph (b) of this section, each cargo tank must have a vacuum protection system meeting paragraph (a)(1) of this section and either paragraph...

Vacuum Mechatronics And Insvection For Self-Contained Manufacturing

Science.gov (United States)

Belinski, Steve E.; Shirazi, Majid; Seidel, Thomas E.; Hackwood, Susan

1990-02-01

The vacuum environment is increasingly being used in manufacturing operations, especially in the semiconductor industry. Shrinking linewidths and feature sizes dictate that cleanliness standards become continually more strict. Studies at the Center for Robotic Systems in Microelectronics (CRSM) indicate that a controlled vacuum enclosure can provide a superior clean environment. In addition, since many microelectronic fabrication steps are already carried out under vacuum, self-contained multichamber processing systems are being developed at a rapid pace. CRSM support of these systems includes the development of a research system, the Self-contained Automated Robotic Factory (SCARF), a vacuum-compatible robot, and investigations of particulate characterization in vacuum and inspection for multichamber systems. Successful development of complex and expensive multichamber systems is, to a great extent, dependent upon the discipline called vacuum mechatronics, which includes the design and development of vacuum-compatible computer-controlled mechanisms for manipulating, sensing and testing in a vacuum environment. Here the constituents of the vacuum mechatronics discipline are defined and reviewed in the context of the importance to self-contained in-vacuum manufacturing.

Vacuum system for HIMAC synchrotrons

International Nuclear Information System (INIS)

Kanazawa, M.; Sudou, M.; Sato, K.

1994-01-01

HIMAC synchrotrons are now under construction, which require vacuum chambers of large aperture and high vacuum of about 10 -9 torr. Wide thin wall vacuum chamber of 0.3 mm thickness reinforced with ribs has been developed as the chamber at dipole magnet. We have just now started to evacuate the lower ring. The obtained average value was about 5x10 -8 torr with turbo-molecular and sputter ion pumps, and 1.1x10 -9 torr after baking. (author)

Vacuum vessel for thermonuclear device

International Nuclear Information System (INIS)

Hagiwara, Koji; Imura, Yasuya.

1979-01-01

Purpose: To provide constituted method for easily performing baking of vacuum vessel, using short-circuiting segments. Constitution: At the time of baking, one turn circuit is formed by the vacuum vessel and short-circuiting segments, and current transformer converting the one turn circuit into a secondary circuit by the primary coil and iron core is formed, and the vacuum vessel is Joule heated by an induction current from the primary coil. After completion of baking, the short-circuiting segments are removed. (Kamimura, M.)

ITER diagnostic system: Vacuum interface

Energy Technology Data Exchange (ETDEWEB)

Patel, K.M., E-mail: Kaushal.Patel@iter.org [ITER Organization, Route de Vinon sur Verdon, 13115 St Paul-Lez-Durance (France); Udintsev, V.S.; Hughes, S.; Walker, C.I.; Andrew, P.; Barnsley, R.; Bertalot, L. [ITER Organization, Route de Vinon sur Verdon, 13115 St Paul-Lez-Durance (France); Drevon, J.M. [Bertin Technologies, BP 22, 13762 Aix-en Provence cedex 3 (France); Encheva, A. [ITER Organization, Route de Vinon sur Verdon, 13115 St Paul-Lez-Durance (France); Kashchuk, Y. [Institution “PROJECT CENTER ITER”, 1, Akademika Kurchatova pl., Moscow (Russian Federation); Maquet, Ph. [Bertin Technologies, BP 22, 13762 Aix-en Provence cedex 3 (France); Pearce, R.; Taylor, N.; Vayakis, G.; Walsh, M.J. [ITER Organization, Route de Vinon sur Verdon, 13115 St Paul-Lez-Durance (France)

2013-10-15

Diagnostics play an essential role for the successful operation of the ITER tokamak. They provide the means to observe control and to measure plasma during the operation of ITER tokamak. The components of the diagnostic system in the ITER tokamak will be installed in the vacuum vessel, in the cryostat, in the upper, equatorial and divertor ports, in the divertor cassettes and racks, as well as in various buildings. Diagnostic components that are placed in a high radiation environment are expected to operate for the life of ITER. There are approx. 45 diagnostic systems located on ITER. Some diagnostics incorporate direct or independently pumped extensions to maintain their necessary vacuum conditions. They require a base pressure less than 10{sup −7} Pa, irrespective of plasma operation, and a leak rate of less than 10{sup −10} Pa m{sup 3} s{sup −1}. In all the cases it is essential to maintain the ITER closed fuel cycle. These directly coupled diagnostic systems are an integral part of the ITER vacuum containment and are therefore subject to the same design requirements for tritium and active gas confinement, for all normal and accidental conditions. All the diagnostics, whether or not pumped, incorporate penetration of the vacuum boundary (i.e. window assembly, vacuum feedthrough etc.) and demountable joints. Monitored guard volumes are provided for all elements of the vacuum boundary that are judged to be vulnerable by virtue of their construction, material, load specification etc. Standard arrangements are made for their construction and for the monitoring, evacuating and leak testing of these volumes. Diagnostic systems are incorporated at more than 20 ports on ITER. This paper will describe typical and particular arrangements of pumped diagnostic and monitored guard volume. The status of the diagnostic vacuum systems, which are at the start of their detailed design, will be outlined and the specific features of the vacuum systems in ports and extensions

ITER diagnostic system: Vacuum interface

International Nuclear Information System (INIS)

Patel, K.M.; Udintsev, V.S.; Hughes, S.; Walker, C.I.; Andrew, P.; Barnsley, R.; Bertalot, L.; Drevon, J.M.; Encheva, A.; Kashchuk, Y.; Maquet, Ph.; Pearce, R.; Taylor, N.; Vayakis, G.; Walsh, M.J.

2013-01-01

Diagnostics play an essential role for the successful operation of the ITER tokamak. They provide the means to observe control and to measure plasma during the operation of ITER tokamak. The components of the diagnostic system in the ITER tokamak will be installed in the vacuum vessel, in the cryostat, in the upper, equatorial and divertor ports, in the divertor cassettes and racks, as well as in various buildings. Diagnostic components that are placed in a high radiation environment are expected to operate for the life of ITER. There are approx. 45 diagnostic systems located on ITER. Some diagnostics incorporate direct or independently pumped extensions to maintain their necessary vacuum conditions. They require a base pressure less than 10 −7 Pa, irrespective of plasma operation, and a leak rate of less than 10 −10 Pa m 3 s −1 . In all the cases it is essential to maintain the ITER closed fuel cycle. These directly coupled diagnostic systems are an integral part of the ITER vacuum containment and are therefore subject to the same design requirements for tritium and active gas confinement, for all normal and accidental conditions. All the diagnostics, whether or not pumped, incorporate penetration of the vacuum boundary (i.e. window assembly, vacuum feedthrough etc.) and demountable joints. Monitored guard volumes are provided for all elements of the vacuum boundary that are judged to be vulnerable by virtue of their construction, material, load specification etc. Standard arrangements are made for their construction and for the monitoring, evacuating and leak testing of these volumes. Diagnostic systems are incorporated at more than 20 ports on ITER. This paper will describe typical and particular arrangements of pumped diagnostic and monitored guard volume. The status of the diagnostic vacuum systems, which are at the start of their detailed design, will be outlined and the specific features of the vacuum systems in ports and extensions will be described

Long-term storage method for soft X-ray irradiated 'Hyuganatsu' pollen

International Nuclear Information System (INIS)

Yano, S.; Tanaka, M.; Ohara, N.

2008-01-01

The long-term storage conditions for 'Hyuganatsu ' pollen that had been irradiated with soft X-rays was examined. This study, was aimed at production of 'Tosa-buntan' without formation of nuclear fruit. 1. We evaluated the germination rate of pollen that had been irradiated with soft X-ray (500 or 1,000 Gy) and stored at 3 deg C, -20 deg C, and -40 deg C. The germination rate was the same as that of unirradiated pollen, even after storage for 1 year. Soft X-ray irradiation did not influence the storage attributes of pollen. 2. In unirradiated pollen and pollen that had been irradiated with soft X-ray (500 or 1,000 Gy), temperature conditions necessary for storing from 3 months to 1 year were -20 deg C or less, and pollen stored at -40 deg C had a higher germination rate after 1 year. 3. The germination rate was 1% or less in 4 months if silica gel was sealed into a gas barrier bag with 1,000 Gy-irradiated pollen at a rate of 10:1 (w/w). The ability to germinate was completely lost after 1 year in these conditions. 4. We evaluated the effect of sealing methods on 1,000 Gy-irradiated pollen stored at -20 deg C. There was no difference in germination rates among pollen stored in gas-barrier bags, vacuum-packaged pollen, and pollen stored with nitrogen in gas-barrier bags. Moreover, the germination rate of 750 Gy-irradiated pollen stored at -20 deg C decreased from 3 months onwards when pollen was stored with a free-oxygen absorber (Ageless ZP). 5. Pollen that was treated with acetone before or after soft X-ray irradiation (750 Gy) withstood long-term storage of 1 year. Long-term storage was possible if pollen was stored at -20 deg C, as is the case for rough pollen

FAINT NEAR-ULTRAVIOLET/FAR-ULTRAVIOLET STANDARDS FROM SWIFT/UVOT, GALEX, AND SDSS PHOTOMETRY

International Nuclear Information System (INIS)

Siegel, Michael H.; Hoversten, Erik A.; Roming, Peter W. A.; Brown, Peter

2010-01-01

At present, the precision of deep ultraviolet photometry is somewhat limited by the dearth of faint ultraviolet standard stars. In an effort to improve this situation, we present a uniform catalog of 11 new faint (u ∼ 17) ultraviolet standard stars. High-precision photometry of these stars has been taken from the Sloan Digital Sky Survey and Galaxy Evolution Explorer archives and combined with new data from the Swift Ultraviolet Optical Telescope to provide precise photometric measures extending from the near-infrared to the far-ultraviolet. These stars were chosen because they are known to be hot (20, 000 eff < 50, 000 K) DA white dwarfs with published Sloan spectra that should be photometrically stable. This careful selection allows us to compare the combined photometry and Sloan spectroscopy to models of pure hydrogen atmospheres to both constrain the underlying properties of the white dwarfs and test the ability of white dwarf models to predict the photometric measures. We find that the photometry provides good constraints on white dwarf temperatures, which demonstrates the ability of Swift/UVOT to investigate the properties of hot luminous stars. We further find that the models reproduce the photometric measures in all 11 passbands to within their systematic uncertainties. Within the limits of our photometry, we find the standard stars to be photometrically stable. This success indicates that the models can be used to calibrate additional filters to our standard system, permitting easier comparison of photometry from heterogeneous sources. The largest source of uncertainty in the model fitting is the uncertainty in the foreground reddening curve, a problem that is especially acute in the UV.

Application of the UV laser printing technique to soft gelatin capsules containing titanium dioxide in the shells.

Science.gov (United States)

Hosokawa, Akihiro; Kato, Yoshiteru

2012-03-01

The purpose of this study was to examine application of ultraviolet (UV) laser irradiation to printing soft gelatin capsules containing titanium dioxide (TiO(2)) in the shells and to study effect of UV laser power on the color strength of printing on the soft gelatin capsules. Size 6 Oval type soft gelatin capsules of which shells contained 0.685% TiO(2) and 0.005% ferric dioxide were used in this study. The capsules were irradiated pulsed UV laser at a wavelength 355 nm. The color strength of the printed capsules was determined by a spectrophotometer as total color difference (dE). The soft gelatin capsules which contained TiO(2) in the shells could be printed gray by the laser. Many black particles, which were associated with the printing, were formed at the colored parts of the shells. It was found that there were two inflection points in relationship between output laser energy of a pulse and dE. Below the lower point, the capsules were not printed. From the lower point to the upper point, the capsules were printed gray and total color difference of the printing increased linearly in proportion with the output laser energy. Beyond the upper point, total color difference showed saturation because of micro-bubbles formation at the laser irradiated spot. Soft gelatin capsules containing TiO(2) in the shells could be performed stable printing using the UV laser printing technique. Color strength of the printing could be controlled by regulating the laser energy between the two inflection points.

Study on soft magnetic properties of Finemet-type nanocrystalline alloys with Mo substituting for Nb

Energy Technology Data Exchange (ETDEWEB)

Jiang, Dehui; Zhou, Bingwen; Jiang, Boyu; Ya, Bin; Zhang, Xingguo [School of Materials Science and Engineering, Dalian University of Technology, Dalian (China)

2017-10-15

The thermal stability, microstructure, and soft magnetic properties as a function of annealing time were studied for Fe{sub 73.5}Si{sub 13.5}B{sub 9}Cu{sub 1}Nb{sub 3-x}Mo{sub x} (x = 0, 1, 2, 3) (atom percent, at.%,) ribbons. It was found that substituting Nb by Mo reduced the thermal stability. After 15 min short time vacuum annealing, Fe{sub 73.5}Si{sub 13.5}B{sub 9}Cu{sub 1}Nb{sub 2}Mo{sub 1} and Fe{sub 73.5}Si{sub 13.5}B{sub 9}Cu{sub 1}Nb{sub 1}Mo{sub 2} samples obtained higher permeability and similar coercivity compared to the original Finemet alloy (Fe{sub 73.5}Si{sub 13.5}B{sub 9}Cu{sub 1}Nb{sub 3}), Mo substituting Nb reduced the optimum annealing time in Finemet-type alloys, and meanwhile marginally increased the saturation magnetization. Substituting all Nb by Mo led to the earlier formation of non-soft magnetic phase, thus deteriorated the soft magnetic properties. XRD and TEM structural analysis showed that in Fe{sub 73.5}Si{sub 13.5}B{sub 9}Cu{sub 1}Nb{sub 2}Mo{sub 1} and Fe{sub 73.5}Si{sub 13.5}B{sub 9}Cu{sub 1}Nb{sub 1}Mo{sub 2} samples (annealed for 15 min), nanocrystals ∝10 nm in size were obtained, and the good soft magnetic properties of these alloys could be attributed to the small grain size. The relationship between annealing time, soft magnetic properties, and microstructure was established. Reducing annealing time and temperature to obtain best soft magnetic properties could cut down the production costs of Finemet-type alloys. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Vacuum system of SST-1 Tokamak

Energy Technology Data Exchange (ETDEWEB)

Khan, Ziauddin, E-mail: ziauddin@ipr.res.in [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar 382 428 (India); Pathan, Firozkhan; George, Siju; Semwal, Pratibha; Dhanani, Kalpesh; Paravastu, Yuvakiran; Thankey, Prashant; Ramesh, Gattu; Himabindu, Manthena; Pradhan, Subrata [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar 382 428 (India)

2013-10-15

Highlights: ► Air leaks developed during ongoing SST-1 cooldown campaign were detected online using RGA. ► The presence of N{sub 2} and O{sub 2} gases with the ratio of their partial pressures with ∼3.81:1 confirmed the air leaks. ► Baking of SST-1 was done efficiently by flowing hot N{sub 2} gas in C-channels welded on inner surfaces without any problem. ► In-house fabricated demountable bull nose couplers were demonstrated for high temperature and pressure applications. ► Cryopumping effect was observed when liquid helium cooled superconducting magnets reached below 63 K. -- Abstract: Vacuum chambers of Steady State Superconducting (SST-1) Tokamak comprises of the vacuum vessel and the cryostat. The plasma will be confined inside the vacuum vessel while the cryostat houses the superconducting magnet systems (TF and PF coils), LN{sub 2} cooled thermal shields and hydraulics for these circuits. The vacuum vessel is an ultra-high (UHV) vacuum chamber while the cryostat is a high-vacuum (HV) chamber. In order to achieve UHV inside the vacuum vessel, it would be baked at 150 °C for longer duration. For this purpose, U-shaped baking channels are welded inside the vacuum vessel. The baking will be carried out by flowing hot nitrogen gas through these channels at 250 °C at 4.5 bar gauge pressure. During plasma operation, the pressure inside the vacuum vessel will be raised between 1.0 × 10{sup −4} mbar and 1.0 × 10{sup −5} mbar using piezoelectric valves and control system. An ultimate pressure of 4.78 × 10{sup −6} mbar is achieved inside the vacuum vessel after 100 h of pumping. The limitation is due to the development of few leaks of the order of 10{sup −5} mbar l/s at the critical locations of the vacuum vessel during baking which was confirmed with the presence of nitrogen gas and oxygen gas with the ratio of ∼3.81:1 indicating air leak. Similarly an ultimate vacuum of 2.24 × 10{sup −5} mbar is achieved inside the cryostat. Baking of the

Rotary bayonets for cryogenic and vacuum service

International Nuclear Information System (INIS)

Rucinski, R.A.; Dixon, K.D.; Krasa, R.; Krempetz, K.J.; Mulholland, G.T.; Trotter, G.R.; Urbin, J.B.

1993-07-01

Rotary bayonets were designed, tested, and installed for liquid nitrogen, liquid argon, and vacuum service. This paper will present the design, testing, and service record for two sizes of vacuum jacketed cryogenic rotary bayonets and two sizes of vacuum service rotary bayonets. Materials used in construction provide electrical isolation across the bayonet joint. The joint permits 360 degrees of rotation between the male and female pipe sections while maintaining integrity of service. Assemblies using three such joints were built to allow end connection points to be translated through at least 1 meter of horizontal travel while kept in service. Vacuum jacketed sizes built in-house at Fermi National Accelerator Laboratory are 1-1/2 in. inner pipe size, 3 in. vacuum jacket, and 4 in. inner pipe size, 6 in. vacuum jacket The single wall vacuum service bayonets are in 4 in. and 6 in. pipe sizes. The bayonets have successfully been in active service for over one year

Rotary bayonets for cryogenic and vacuum service

International Nuclear Information System (INIS)

Rucinski, R.A.; Dixon, K.D.; Krasa, R.; Krempetz, K.J.; Mulholland, G.T.; Trotter, G.R.; Urbin, J.B.

1994-01-01

Rotary bayonets were designed, tested, and installed for liquid nitrogen, liquid argon, and vacuum service. This paper will present the design, testing, and service record for two sizes of vacuum jacketed cryogenic rotary bayonets and two sizes of vacuum service rotary bayonets. Materials used in construction provide electrical isolation across the bayonet joint. The joint permits 360 degrees of rotation between the male and female pipe sections while maintaining integrity of service. Assemblies using three such joints were built to allow end connection points to be translated through at least 1 meter of horizontal travel while kept in service. Vacuum jacketed sizes built in-house at Fermi National Accelerator Laboratory are 1 1/2 inches inner pipe size, 3 inches vacuum jacket, and 4 inches inner pipe size, 6 inches vacuum jacket. The single wall vacuum service bayonets are in 4 inch and 6 inch pipe sizes. The bayonets have successfully been in active service for over one year

TPX vacuum vessel transient thermal and stress conditions

International Nuclear Information System (INIS)

Feldshteyn, Y.; Dinkevich, S.; Feng, T.; Majumder, D.

1995-01-01

The TPX vacuum vessel provides the vacuum boundary for the plasma and the mechanical support for the internal components. Another function of the vacuum vessel is to contain neutron shielding water in the double wall space during normal operation. This double wall space serves as a heat reservoir for the entire vacuum vessel during bakeout. The vacuum vessel and the internal components are subjected to thermal stresses induced by a nonuniform temperature distribution within the structure during bakeout. A successful Conceptual Design Review in March 1993 has established superheated steam as the heating source of the vacuum vessel. A transient bakeout mode of the vacuum vessel and in-vessel components has been analyzed to evaluate transient period duration, proper temperature level, actual thermal stresses and performance of the steam equipment. Thermally, the vacuum vessel structure may be considered as an adiabatic system because it is perfectly insulated by the strong surrounding vacuum and multiple layers of superinsulation. Important aspects of the analysis are described herein

SPHINX: a generator based on 1 microsecond current rise time LTD stages. Status and first results for production of soft X-ray radiation

International Nuclear Information System (INIS)

Mangeant, Ch.; Roques, B.; Cadiergues, R.

2005-01-01

SPHINX is the new name of the facility developed for soft X-ray production. This facility is based on the ECF2 generator which was designed as a 1-3 MJ, 1 μs rise time, 5-10 MA current driver. We present a detailed view of the technology used for the capacitor bank, for the central vacuum part and for the Z-pinch loads [ru

Design foundation of vacuum system for electron beam machine

International Nuclear Information System (INIS)

Darsono; Suprapto; Djasiman

1999-01-01

Vacuum system is a main part of electron beam Machine because (EBM) the electron can not be produced without this vacuum. Vacuum system consists of vacuum pump, connecting pipe, valve, and vacuum gauge. The design vacuum system of EBM, basis knowledge and technology of vacuum is needed. The paper describes types of vacuum pump, calculation of pipe conductance and pumping time of vacuum system then there are used as consideration of criteria to choose vacuum pump for EBM. From the result of study, it is concluded that for EBM of 500 keV/10 mA which is going to use for wood coating and with consideration of economic and technic factor it is better to use diffusion pump. (author)

Theoretical and experimental investigation for SO3 production in SO2-rich astrophysical environments

International Nuclear Information System (INIS)

Bonfim, Víctor de Souza; Pilling, Sergio; Castilho, Roberto B; Baptista, Leonardo

2015-01-01

This work presents the results for the irradiation of pure SO 2 sample that was condensed in a preevacuated chamber, from Laboratório de Astroquímica e Astrobiologia (LASA/UNIVAP), at low temperature (12 K) and irradiated by ionizing photons which simulate Solar photons in the vacuum ultraviolet (VUV) and soft X-rays range. The infrared spectra of irradiated sample have presented the formation of SO 3 . Experimental formation cross section was determined. Theoretical investigations were performed at Second-order Moller- Plesset perturbation theory (MP2) level and indicate the most likely SO 3 formation channels vary with the reaction supporting medium. (paper)

Disinfection Effect of Film Cassettes by Ultraviolet Irradiation

International Nuclear Information System (INIS)

Kweon, Dae Cheol; Park, Peom

2001-01-01

A bacteria infection on film cassette contact surface was examined at the diagnostic radiology department. Studies have demonstrated a bactericidal effect of ultraviolet irradiation, and to assess the contamination level on film cassette contact surface as a predictor of patient prevent from nosocomial infection. The study showed that the laboratory result was identified non-pathologic and pathologic bacterial in the five different cassette size of the contact surface. Film cassettes were exposed to ultraviolet light for 1, 2 and 3 minutes. Ultraviolet light disinfection practices suitable for bacteria. The study concludes that presence of a bacterial infection will prevent a using antiseptic technique on film cassette contact surface. In conclusion, ultraviolet irradiate on film cassette over the surface more than 2 minutes. Ultraviolet dose of 1565 μW · s/cm 2 Win in 30 second relative to ultraviolet dose in time

Development of a vacuum superinsulation panel

Energy Technology Data Exchange (ETDEWEB)

Timm, H; Seefeldt, D; Nitze, C

1983-05-01

After completion of the investigations the vacuum-insulated panel is available as prototype. The aim of the investigations was to optimize and to finalize the vacuum superinsulation system with regard to a pressure-resistant, temperature-resistant thermal insulation of high efficiency. In this connection, particularly investigations with regard to vacuum-tight sealing, compression and evacuation of powder filling as well as special material investigations were performed. The application-specific utilization of the vacuum-insulated panel and the adjustment to special operational conditions can now be started. Application possibilities are at present seen in coverings or linings with high temperature and/or pressure requirements.

Ultraviolet-enhanced photodetection in a graphene/SiO2/Si capacitor structure with a vacuum channel

International Nuclear Information System (INIS)

Kim, Myungji; Kim, Hong Koo

2015-01-01

We report photodetection properties of a graphene/oxide/silicon capacitor structure with a nanoscale vacuum channel. The photogenerated two-dimensional electron gas (2DEG) inversion charges at SiO 2 /Si interface are extracted out to air and transported along the void channel at low bias voltage (<5 V). A monolayer graphene, placed on top of SiO 2 and suspended on the void channel, is utilized as a photon-transparent counter-electrode to the 2DEG layer and a collector electrode for the out-of-plane transported electrons, respectively. The photocurrent extracted through a void channel reveals high responsivity (1.0 A/W at 633 nm) as measured in a broad spectral range (325–1064 nm), especially demonstrating a UV-enhanced performance (0.43 A/W responsivity and 384% internal quantum efficiency at 325 nm). The mechanisms underlying photocarrier generation, emission, and transport in a suspended-graphene/SiO 2 /Si structure are proposed

SUPRA SOFT SEPARATION AXIOMS AND SUPRA IRRESOLUTENESS BASED ON SUPRA B-SOFT SETS

OpenAIRE

Abd El-latif, Alaa Mohamed; Hosny, Rodyna Ahmed

2016-01-01

This paper introduces supra soft b-separation axioms based on the supra b-open soft sets which are more general than supra open soft sets. We investigate the relationships between these supra soft separation axioms. Furthermore, with the help of examples it is established that the converse does not hold. We show that, a supra soft topological space (X; t;E) is supra soft b-T1-space, if xE is supra b-closed soft set in for each x 2 X. Also, we prove that xE is supra b-closed soft set for each ...

Vacuum phonon tunneling.

Science.gov (United States)

Altfeder, Igor; Voevodin, Andrey A; Roy, Ajit K

2010-10-15

Field-induced phonon tunneling, a previously unknown mechanism of interfacial thermal transport, has been revealed by ultrahigh vacuum inelastic scanning tunneling microscopy (STM). Using thermally broadened Fermi-Dirac distribution in the STM tip as in situ atomic-scale thermometer we found that thermal vibrations of the last tip atom are effectively transmitted to sample surface despite few angstroms wide vacuum gap. We show that phonon tunneling is driven by interfacial electric field and thermally vibrating image charges, and its rate is enhanced by surface electron-phonon interaction.

Vacuum and ultravacuum physics and technology

CERN Document Server

Bello, Igor

2018-01-01

Vacuum technology has enormous impact on human life in many aspects and fields, such as metallurgy, material development and production, food and electronic industry, microelectronics, device fabrication, physics, materials science, space science, engineering, chemistry, technology of low temperature, pharmaceutical industry, and biology. All decorative coatings used in jewelries and various daily products—including shiny decorative papers, the surface finish of watches, and light fixtures—are made using vacuum technological processes. Vacuum analytical techniques and vacuum technologies are pillars of the technological processes, material synthesis, deposition, and material analyses—all of which are used in the development of novel materials, increasing the value of industrial products, controlling the technological processes, and ensuring the high product quality. Based on physical models and calculated examples, the book provides a deeper look inside the vacuum physics and technology.

Comprehending the structure of a vacuum vessel and in-vessel components of fusion machines. 1. Comprehending the vacuum vessel structure

International Nuclear Information System (INIS)

Onozuka, Masanori; Nakahira, Masataka

2006-01-01

The functions, conditions and structure of vacuum vessel using tokamak fusion machines are explained. The structural standard and code of vacuum vessel, process of vacuum vessel design, and design of ITER vacuum vessel are described. Production and maintenance of ultra high vacuum, confinement of radioactive materials, support of machines in vessel and electromagnetic force, radiation shield, plasma vertical stability, one-turn electric resistance, high temperature baking heat and remove of nuclear heat, reduce of troidal ripple, structural standard, features of safety of nuclear fusion machines, subjects of structural standard of fusion vacuum vessel, design flow of vacuum vessel, establishment of radial build, selections of materials, baking and cooling method, basic structure, structure of special parts, shield structure, and of support structure, and example of design of structure, ITER, are stated. (S.Y.)

Soft lubrication

Science.gov (United States)