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Sample records for two-dimensional structure resulting

  1. Two-Dimensional Simulation of Electrospun Nanofibrous Structures: Connection of Experimental and Simulated Results

    Directory of Open Access Journals (Sweden)

    Panu Danwanichakul

    2014-01-01

    Full Text Available Nanofibrous mats were obtained from electrospinning Nylon-6 solutions with concentrations of 30 and 35 wt% and were tested for filtration of polystyrene particles in suspension. Some experimental results were compared with the simulated ones. In the simulation, the two-dimensional structures were constructed by randomly depositing a nanofiber, which was assumed as an ellipse with an aspect ratio of 100, one by one. The nanofiber size is assumed to be polydisperse. The results showed that simulated configurations resembled real nanofibers with polydisperse diameters. Fibers from higher solution concentration were larger, resulting in larger pore size, which was confirmed with simulations. Varying the size distribution around the same average value did not make any difference to the surface coverage but it affected 2D pore areas for the systems at low fiber density. In addition, the probability for a particle to pass through the porous structure was less when the fiber density was higher and the particle diameter was larger, which was consistent with the filtration test. Lastly, water flux measurement could yield the void volume fraction as well as the volume-averaged pore diameter, which was found to be greater than the averaged 2D pore diameter from SEM micrographs by the quantity related to the fiber size.

  2. Nonlinear excitations in two-dimensional molecular structures with impurities

    DEFF Research Database (Denmark)

    Gaididei, Yuri Borisovich; Rasmussen, Kim; Christiansen, Peter Leth

    1995-01-01

    We study the nonlinear dynamics of electronic excitations interacting with acoustic phonons in two-dimensional molecular structures with impurities. We show that the problem is reduced to the nonlinear Schrodinger equation with a varying coefficient. The latter represents the influence of the imp......We study the nonlinear dynamics of electronic excitations interacting with acoustic phonons in two-dimensional molecular structures with impurities. We show that the problem is reduced to the nonlinear Schrodinger equation with a varying coefficient. The latter represents the influence...... excitations. Analytical results are in good agreement with numerical simulations of the nonlinear Schrodinger equation....

  3. Two-Dimensionally-Modulated, Magnetic Structure of Neodymium Metal

    DEFF Research Database (Denmark)

    Lebech, Bente; Bak, P.

    1979-01-01

    The incipient magnetic order of dhcp Nd is described by a two-dimensional, incommensurably modulated structure ("triple-q" structure). The ordering is accompanied by a lattice distortion that forms a similar pattern....

  4. Band structure of absorptive two-dimensional photonic crystals

    Science.gov (United States)

    van der Lem, Han; Tip, Adriaan; Moroz, Alexander

    2003-06-01

    The band structure for an absorptive two-dimensional photonic crystal made from cylinders consisting of a Drude material is calculated. Absorption causes the spectrum to become complex and form islands in the negative complex half-plane. The boundaries of these islands are not always formed by the eigenvalues calculated for Bloch vectors on the characteristic path, and we find a hole in the spectrum. For realistic parameter values, the real part of the spectrum is hardly influenced by absorption, typically less than 0.25%. The employed method uses a Korringa-Kohn-Rostoker procedure together with analytical continuation. This results in an efficient approach that allows these band-structure calculations to be done on a Pentium III personal computer.

  5. Structure and computation of two-dimensional incompressible extended MHD

    CERN Document Server

    Grasso, D; Abdelhamid, H M; Morrison, P J

    2016-01-01

    A comprehensive study of a reduced version of Lust's equations, the extended magnetohydrodynamic (XMHD) model obtained from the two-fluid theory for electrons and ions with the enforcement of quasineutrality, is given. Starting from the Hamiltonian structure of the fully three-dimensional theory, a Hamiltonian two-dimensional incompressible four-field model is derived. In this way energy conservation along with four families of Casimir invariants are naturally obtained. The construction facilitates various limits leading to the Hamiltonian forms of Hall, inertial, and ideal MHD, with their conserved energies and Casimir invariants. Basic linear theory of the four-field model is treated, and the growth rate for collisionless reconnection is obtained. Results from nonlinear simulations of collisionless tearing are presented and interpreted using, in particular normal fields, a product of the Hamiltonian theory that gives rise to simplified equations of motion.

  6. Structure and computation of two-dimensional incompressible extended MHD

    Science.gov (United States)

    Grasso, D.; Tassi, E.; Abdelhamid, H. M.; Morrison, P. J.

    2017-01-01

    A comprehensive study of the extended magnetohydrodynamic model obtained from the two-fluid theory for electrons and ions with the enforcement of quasineutrality is given. Starting from the Hamiltonian structure of the fully three-dimensional theory, a Hamiltonian two-dimensional incompressible four-field model is derived. In this way, the energy conservation along with four families of Casimir invariants is naturally obtained. The construction facilitates various limits leading to the Hamiltonian forms of Hall, inertial, and ideal MHD, with their conserved energies and Casimir invariants. Basic linear theory of the four-field model is treated, and the growth rate for collisionless reconnection is obtained. Results from nonlinear simulations of collisionless tearing are presented and interpreted using, in particular, normal fields, a product of the Hamiltonian theory that gives rise to simplified equations of motion.

  7. Structure of the lithosphere of the northeastern part of the Indian Ocean according to results of two-dimensional structural-density modeling

    Science.gov (United States)

    Bulychev, A. A.; Gilod, D. A.; Dubinin, E. P.

    2016-05-01

    From a gravitational field analysis, the lithosphere was regionalized and a structural schematic map of the eastern part of the Indian Ocean was compiled. The area adjacent to the western margin of Australia was studied. The region is characterized by a complex lithospheric structure. It includes heterogeneous blocks of varying age, framed by structures with different morphological and geophysical expression and varying genesis. To clarify the peculiarities of tectonic structures of various genetic types, structural-density modeling was performed. This made it possible to establish certain gravimetric indicators characteristic of structures of various genesis.

  8. Static Structure of Two-Dimensional Granular Chain

    Institute of Scientific and Technical Information of China (English)

    WEN Ping-Ping; LI Liang-Sheng; ZHENG Ning; SHI Qing-Fan

    2010-01-01

    @@ Static packing structures of two-dimensional granular chains are investigated experimentally.It is shown that the packing density approximates the saturation with the exponential law as the length of chain increases.The packing structures are globally disordered,while the local square crystallization is found by using the radial distribution function.This characteristic phase of chain packing is similar to a liquid crystal state,and has properties between a conventional liquid and solid crystal.

  9. Two-dimensional localized structures in harmonically forced oscillatory systems

    Science.gov (United States)

    Ma, Y.-P.; Knobloch, E.

    2016-12-01

    Two-dimensional spatially localized structures in the complex Ginzburg-Landau equation with 1:1 resonance are studied near the simultaneous presence of a steady front between two spatially homogeneous equilibria and a supercritical Turing bifurcation on one of them. The bifurcation structures of steady circular fronts and localized target patterns are computed in the Turing-stable and Turing-unstable regimes. In particular, localized target patterns grow along the solution branch via ring insertion at the core in a process reminiscent of defect-mediated snaking in one spatial dimension. Stability of axisymmetric solutions on these branches with respect to axisymmetric and nonaxisymmetric perturbations is determined, and parameter regimes with stable axisymmetric oscillons are identified. Direct numerical simulations reveal novel depinning dynamics of localized target patterns in the radial direction, and of circular and planar localized hexagonal patterns in the fully two-dimensional system.

  10. Electronic structure of boron based single and multi-layer two dimensional materials

    Science.gov (United States)

    Miyazato, Itsuki; Takahashi, Keisuke

    2017-09-01

    Two dimensional nanosheets based on boron and Group VA elements are designed and characterized using first principles calculations. B-N, B-P, B-As, B-Sb, and B-Bi are found to possess honeycomb structures where formation energies indicate exothermic reactions. Contrary to B-N, the cases of B-P, B-As, B-Sb, and B-Bi nanosheets are calculated to possess narrow band gaps. In addition, calculations reveal that the electronegativity difference between B and Group VA elements in the designed materials is a good indicator to predict the charge transfer and band gap of the two dimensional materials. Hydrogen adsorption over defect-free B-Sb and B-Bi results in exothermic reactions, while defect-free B-N, B-P, and B-As result in endothermic reactions. The layerability of the designed two dimensional materials is also investigated where the electronic structure of two-layered two dimensional materials is strongly coupled with how the two dimensional materials are layered. Thus, one can consider that the properties of two dimensional materials can be controlled by the composition of two dimensional materials and the structure of layers.

  11. The encoding complexity of two dimensional range minimum data structures

    DEFF Research Database (Denmark)

    Brodal, Gerth Stølting; Brodnik, Andrej; Davoodi, Pooya

    2013-01-01

    In the two-dimensional range minimum query problem an input matrix A of dimension m ×n, m ≤ n, has to be preprocessed into a data structure such that given a query rectangle within the matrix, the position of a minimum element within the query range can be reported. We consider the space complexity...... of the encoding variant of the problem where queries have access to the constructed data structure but can not access the input matrix A, i.e. all information must be encoded in the data structure. Previously it was known how to solve the problem with space O(mn min {m,logn}) bits (and with constant query time...

  12. Isolated structures in two-dimensional optical superlattice

    Science.gov (United States)

    Zou, Xin-Hao; Yang, Bao-Guo; Xu, Xia; Tang, Peng-Ju; Zhou, Xiao-Ji

    2017-10-01

    Overlaying commensurate optical lattices with various configurations called superlattices can lead to exotic lattice topologies and, in turn, a discovery of novel physics. In this study, by overlapping the maxima of lattices, a new isolated structure is created, while the interference of minima can generate various "sublattice" patterns. Three different kinds of primitive lattices are used to demonstrate isolated square, triangular, and hexagonal "sublattice" structures in a two-dimensional optical superlattice, the patterns of which can be manipulated dynamically by tuning the polarization, frequency, and intensity of laser beams. In addition, we propose the method of altering the relative phase to adjust the tunneling amplitudes in "sublattices". Our configurations provide unique opportunities to study particle entanglement in "lattices" formed by intersecting wells and to implement special quantum logic gates in exotic lattice geometries.

  13. Isolated Structures in Two-Dimensional Optical Superlattice

    CERN Document Server

    Zou, Xinhao; Xu, Xia; Tang, Pengju; Zhou, Xiaoji

    2016-01-01

    Overlaying commensurate optical lattices with various configurations called superlattices can lead to exotic lattice topologies and, in turn, a discovery of novel physics. In this study, by overlapping the maxima of lattices, a new isolated structure is created, while the interference of minima can generate various "sublattice" patterns. Three different kinds of primitive lattices are used to demonstrate isolated square, triangular, and hexagonal "sublattice" structures in a two-dimensional optical superlattice, the patterns of which can be manipulated dynamically by tuning the polarization, frequency, and intensity of laser beams. In addition, we propose the method of altering the relative phase to adjust the tunneling amplitudes in "sublattices." Our configurations provide unique opportunities to study particle entanglement in "lattices" formed by intersecting wells and to implement special quantum logic gates in exotic lattice geometries.

  14. Terahertz spectroscopy of two-dimensional subwavelength plasmonic structures

    Energy Technology Data Exchange (ETDEWEB)

    Azad, Abul K [Los Alamos National Laboratory; Chen, Houtong [Los Alamos National Laboratory; Taylor, Antoinette [Los Alamos National Laboratory; O' Hara, John F [Los Alamos National Laboratory; Han, Jiaguang [OSU; Lu, Xinchao [OSU; Zhang, Weili [OSU

    2009-01-01

    The fascinating properties of plasmonic structures have had significant impact on the development of next generation ultracompact photonic and optoelectronic components. We study two-dimensional plasmonic structures functioning at terahertz frequencies. Resonant terahertz response due to surface plasmons and dipole localized surface plasmons were investigated by the state-of-the-art terahertz time domain spectroscopy (THz-TDS) using both transmission and reflection configurations. Extraordinary terahertz transmission was demonstrated through the subwavelength metallic hole arrays made from good conducting metals as well as poor metals. Metallic arrays m!lde from Pb, generally a poor metal, and having optically thin thicknesses less than one-third of a skin depth also contributed in enhanced THz transmission. A direct transition of a surface plasmon resonance from a photonic crystal minimum was observed in a photo-doped semiconductor array. Electrical controls of the surface plasmon resonances by hybridization of the Schottkey diode between the metallic grating and the semiconductor substrate are investigated as a function of the applied reverse bias. In addition, we have demonstrated photo-induced creation and annihilation of surface plasmons with appropriate semiconductors at room temperature. According to the Fano model, the transmission properties are characterized by two essential contributions: resonant excitation of surface plasmons and nonresonant direct transmission. Such plasmonic structures may find fascinating applications in terahertz imaging, biomedical sensing, subwavelength terahertz spectroscopy, tunable filters, and integrated terahertz devices.

  15. Photonic Band Gap Structures with Periodically Arranged Atoms in a Two-Dimensional Photonic Crystal

    Institute of Scientific and Technical Information of China (English)

    LI Zhi-Yu; CHEN Fang; ZHOU Jian-Ying

    2005-01-01

    @@ Linear transmission, reflection and absorption spectra for a new two-dimensional photonic crystal with periodically arranged resonant atoms are examined. Numerical results show that a twin-gap structure with forbidden bands displaced from a non-doped bandgap structure can be produced as a result of atomic polarization. The absorption spectrum is also significantly altered compared to the single atom entity.

  16. Electrical Oscillations in Two-Dimensional Microtubular Structures

    Science.gov (United States)

    Cantero, María Del Rocío; Perez, Paula L.; Smoler, Mariano; Villa Etchegoyen, Cecilia; Cantiello, Horacio F.

    2016-06-01

    Microtubules (MTs) are unique components of the cytoskeleton formed by hollow cylindrical structures of αβ tubulin dimeric units. The structural wall of the MT is interspersed by nanopores formed by the lateral arrangement of its subunits. MTs are also highly charged polar polyelectrolytes, capable of amplifying electrical signals. The actual nature of these electrodynamic capabilities remains largely unknown. Herein we applied the patch clamp technique to two-dimensional MT sheets, to characterize their electrical properties. Voltage-clamped MT sheets generated cation-selective oscillatory electrical currents whose magnitude depended on both the holding potential, and ionic strength and composition. The oscillations progressed through various modes including single and double periodic regimes and more complex behaviours, being prominent a fundamental frequency at 29 Hz. In physiological K+ (140 mM), oscillations represented in average a 640% change in conductance that was also affected by the prevalent anion. Current injection induced voltage oscillations, thus showing excitability akin with action potentials. The electrical oscillations were entirely blocked by taxol, with pseudo Michaelis-Menten kinetics and a KD of ~1.29 μM. The findings suggest a functional role of the nanopores in the MT wall on the genesis of electrical oscillations that offer new insights into the nonlinear behaviour of the cytoskeleton.

  17. Two dimensional electron spin resonance: Structure and dynamics of biomolecules

    Science.gov (United States)

    Saxena, Sunil; Freed, Jack H.

    1998-03-01

    The potential of two dimensional (2D) electron spin resonance (ESR) for measuring the structural properties and slow dynamics of labeled biomolecules will be presented. Specifically, it will be shown how the recently developed method of double quantum (DQ) 2D ESR (S. Saxena and J. H. Freed, J. Chem. Phys. 107), 1317, (1997) can be used to measure large interelectron distances in bilabeled peptides. The need for DQ ESR spectroscopy, as well as the challenges and advantages of this method will be discussed. The elucidation of the slow reorientational dynamics of this peptide (S. Saxena and J. H. Freed, J. Phys. Chem. A, 101) 7998 (1997) in a glassy medium using COSY and 2D ELDOR ESR spectroscopy will be demonstrated. The contributions to the homogeneous relaxation time, T_2, from the overall and/or internal rotations of the nitroxide can be distinguished from the COSY spectrum. The growth of spectral diffusion cross-peaks^2 with mixing time in the 2D ELDOR spectra can be used to directly determine a correlation time from the experiment which can be related to the rotational correlation time.

  18. Results from laboratory tests of the two-dimensional Time-Encoded Imaging System.

    Energy Technology Data Exchange (ETDEWEB)

    Marleau, Peter; Brennan, James S.; Brubaker, Erik; Gerling, Mark D; Le Galloudec, Nathalie Joelle

    2014-09-01

    A series of laboratory experiments were undertaken to demonstrate the feasibility of two dimensional time-encoded imaging. A prototype two-dimensional time encoded imaging system was designed and constructed. Results from imaging measurements of single and multiple point sources as well as extended source distributions are presented. Time encoded imaging has proven to be a simple method for achieving high resolution two-dimensional imaging with potential to be used in future arms control and treaty verification applications.

  19. Adaptivity techniques for the computation of two-dimensional viscous flows using structured meshes

    Science.gov (United States)

    Szmelter, J.; Evans, A.; Weatherill, N. P.

    In this paper three different adaptivity techniques have been investigated on the base of structured meshes. All the techniques indicate the significance of using adaptivity for improving computational results. In particular, the technique of combining point enrichment and node movement strategies offers the best compromise. Although, the work presented here used two-dimensional structured meshes, the techniques can be readily applied to hybrid and unstructured meshes. Also, preliminary three-dimensional numerical results have been already obtained by coauthors.

  20. Two-dimensional magnetic ordering in a multilayer structure

    Indian Academy of Sciences (India)

    M K Mukhopadhyay; M K Sanyal

    2006-07-01

    The effect of confinement from one, two or from all three directions on magnetic ordering has remained an active field of research for almost 100 years. The role of dipolar interactions and anisotropy are important to obtain, the otherwise forbidden, ferromagnetic ordering at finite temperature for ions arranged in two-dimensional (2D) arrays (monolayers). We have demonstrated that conventional low-temperature magnetometry and polarized neutron scattering measurements can be performed to study short-range ferromagnetic ordering of in-plane spins in 2D systems using a multilayer stack of non-interacting monolayers of gadolinium ions formed by Langmuir–Blodgett (LB) technique. The spontaneous magnetization could not be detected in the heterogeneous magnetic phase observed here and the saturation value of the net magnetization was found to depend on the sample temperature and applied magnetic field. The net magnetization rises exponentially with lowering temperature and then reaches saturation following a ln( ) dependence. The ln( ) dependence of magnetization has been predicted from spin-wave theory of 2D in-plane spin system with ferromagnetic interaction. The experimental findings reported here could be explained by extending this theory to a temperature domain of < 1.

  1. Structure and phase transition of a two-dimensional dusty plasma

    Institute of Scientific and Technical Information of China (English)

    刘斌; 刘艳红; 陈雁萍; 杨思泽; 王龙

    2003-01-01

    The structure and phase transition of a two-dimensional (2D) dusty plasma have been investigated in detail by molecular dynamics simulation. Pair correlation function, static structure factor, mean square displacement, and bond angle correlation function have been calculated to characterize the structural properties. The variation of internal energy, shear modulus, particle trajectories and structural properties with temperature has been monitored to study the phase transition of the 2D dusty plasma system. The simulation results are in favour of a two-step continuous transition for this kind of plasma.

  2. Surface Plasmon Polaritons of Two-Dimensional Three-Order Dendritic Structures

    Institute of Scientific and Technical Information of China (English)

    王敏凤; 周鲁卫

    2011-01-01

    We study surface plasmon polaritons excited on two-dimensional three-order dendritic structures. Previous studies show that split ring resonators (SRRs) can be used to obtain magnetic resonance, thus sustairdng surface waves behaving like surface plasmon polaritons (SPPs). In this paper, we obtain detailed results on surface plasmon polaritons of several different grating structures and theoretically prove that this kind of structures can sustain SPPs. Besides, since dendritic structures can be fabricated by double template-assisted electrochemical deposition, it is worth noting that fabrication of SPP-based materials might be much easier.

  3. Two-dimensional chiral asymmetry in unidirectional magnetic anisotropy structures

    Directory of Open Access Journals (Sweden)

    P. Perna

    2016-05-01

    Full Text Available We investigate the symmetry-breaking effects of magnetic nanostructures that present unidirectional (one-fold magnetic anisotropy. Angular and field dependent transport and magnetic properties have been studied in two different exchange-biased systems, i.e. ferromagnetic (FM/ antiferromagnetic (AFM bilayer and spin-valve structures. We experimentally show the direct relationships between the magnetoresistance (MR response and the magnetization reversal pathways for any field value and direction. We demonstrate that even though the MR signals are related to different transport phenomena, namely anisotropic magnetoresistance (AMR and giant magnetoresistance (GMR, chiral asymmetries are found around the magnetization hard-axis direction, in both cases originated from the one-fold symmetry of the interfacial exchange coupling. Our results indicate that the chiral asymmetry of transport and magnetic behaviors are intrinsic of systems with an unidirectional contribution.

  4. Two dimensional structural analysis of reactor fuel element claddings due to local effects

    Energy Technology Data Exchange (ETDEWEB)

    Karimi, R; Wolf, L

    1978-04-01

    Two dimensional thermoelastic and inelastic stresses and deformation of typical LWR (PWR) and LMFBR (CRBR) claddings are evaluated by utilizing the following codes, for (1) Thermoelastic analysis (a) STRESS Code (b) SEGPIPE Code (2) Thermoinelastic analysis (a) Modified version of the GOGO code (b) One dimensional GRO-II code. The primary objective of this study is to analyze the effect of various local perturbations in the clad temperature field, namely eccentrically mounted fuel pellet, clad ovality, power tilt across the fuel and clad-coolant heat transfer variation on the cladding stress and deformation. In view of the fact that the thermoelastic analysis is always the first logical choice entering the structural field, it was decided to start the analysis with the two dimensional codes such as STRESS and SEGPIPE. Later, in order to assess the validity and compare the thermoelastic results to those obtained for actual reactor conditions, a two dimensional code, namely a modified version of the GOGO code, was used to account for inelastic effects such as irradiation and thermal creep and swelling in the evaluation. The comparison of thermoelastic and inelastic results shows that the former can be used effectively to analyze LWR fuel pin over 350 hours of lifetime under the most adverse condition and 500 hours of lifetime for an LMFBR fuel pin. Beyond that the inelastic solution must be used. The impact of the individual thermal perturbation and combinations thereof upon the structural quantity is also shown. Finally, the effect of rod displacement on the two dimensional thermal and structural quantities of the LMFBR fuel pin cladding is analyzed.

  5. Two-dimensional microwave band-gap structures of different dielectric materials

    Indian Academy of Sciences (India)

    E D V Nagesh; G Santosh Babu; V Subramanian; V Sivasubramanian; V R K Murthy

    2005-12-01

    We report the use of low dielectric constant materials to form two-dimensional microwave band-gap structures for achieving high gap-to-midgap ratio. The variable parameters chosen are the lattice spacing and the geometric structure. The selected geometries are square and triangular and the materials chosen are PTFE ( = 2.1), PVC ( = 2.38) and glass ( = 5.5). Using the plane-wave expansion method, proper lattice spacing is selected for each structure and material. The observed experimental results are analyzed with the help of the theoretical prediction.

  6. Coherent structures in two-dimensional plasma turbulence

    DEFF Research Database (Denmark)

    Huld, T.; Nielsen, A.H.; Pécseli, H.L.;

    1991-01-01

    -band turbulent fluctuations is demonstrated by a conditional sampling technique. Depending on plasma parameters, the dominant structures can appear as monopole or multipole vortices, dipole vortices in particular. The importance of large structures for the turbulent plasma diffusion is discussed. A statistical...... analysis of the randomly varying plasma flux is presented....

  7. Coherent vortical structures in two-dimensional plasma turbulence

    DEFF Research Database (Denmark)

    Pécseli, H.L.; Coutsias, E.A.; Huld, T.;

    1992-01-01

    A laboratory experiment was carried out in order to study the nonlinear saturated stage of the cross-field electrostatic Kelvin-Helmholtz instability in a strongly magnetized plasma. The presence of large vortex-like structures in a background of wide-band turbulent fluctuations was demonstrated...... simulations. The importance of the large scale structures for the turbulent plasma transport across magnetic field lines was analyzed in detail....

  8. Graphene materials having randomly distributed two-dimensional structural defects

    Energy Technology Data Exchange (ETDEWEB)

    Kung, Harold H.; Zhao, Xin; Hayner, Cary M.; Kung, Mayfair C.

    2016-05-31

    Graphene-based storage materials for high-power battery applications are provided. The storage materials are composed of vertical stacks of graphene sheets and have reduced resistance for Li ion transport. This reduced resistance is achieved by incorporating a random distribution of structural defects into the stacked graphene sheets, whereby the structural defects facilitate the diffusion of Li ions into the interior of the storage materials.

  9. Graphene materials having randomly distributed two-dimensional structural defects

    Science.gov (United States)

    Kung, Harold H; Zhao, Xin; Hayner, Cary M; Kung, Mayfair C

    2013-10-08

    Graphene-based storage materials for high-power battery applications are provided. The storage materials are composed of vertical stacks of graphene sheets and have reduced resistance for Li ion transport. This reduced resistance is achieved by incorporating a random distribution of structural defects into the stacked graphene sheets, whereby the structural defects facilitate the diffusion of Li ions into the interior of the storage materials.

  10. Two-dimensional bismuth-silver structures on Si(111)

    Science.gov (United States)

    Denisov, N. V.; Chukurov, E. N.; Luniakov, Yu. V.; Utas, O. A.; Azatyan, S. G.; Yakovlev, A. A.; Zotov, A. V.; Saranin, A. A.

    2014-05-01

    Using scanning tunneling microscopy (STM) observations, it has been found that deposition of 0.8-1.3 monolayer of Ag onto the mixed Si(111)α - √ 3 × √ 3 / β - √ 3 × √ 3-Bi surfaces followed by annealing at 150-250°C induces formation of new ordered and quasi-ordered (Bi,Ag)/Si(111) metastable structures, √ 19 × √ 19, 4 × 4, 2 √ 3 × 2 √ 3, and ‘3 √ 3 × 3√3’. Scanning tunneling spectroscopy has demonstrated that the 2√3 × 2√3 structure is semiconducting, while the √19 × √19 and 4 × 4 structures are metallic. Structural models of the √19 × √19 and 4 × 4 have been proposed based on placing a single Ag(111)1 × 1 layer with selected Ag atoms being substituted for Bi atoms onto the bulk-like Si(111)1 × 1 surface. The models have been proved with DFT calculations and comparison of simulated and experimental STM images. Calculated band structure of the Si(111)4 × 4 structure displays a spin-split metallic surface-state band with splitting of ∆k ≈ 0.002 Å- 1 and ∆E ≈ 10 meV in the vicinity of the Fermi level.

  11. Solitary wave propagation through two-dimensional treelike structures.

    Science.gov (United States)

    Falls, William J; Sen, Surajit

    2014-02-01

    It is well known that a velocity perturbation can travel through a mass spring chain with strongly nonlinear interactions as a solitary and antisolitary wave pair. In recent years, nonlinear wave propagation in 2D structures have also been explored. Here we first consider the propagation of such a velocity perturbation for cases where the system has a 2D "Y"-shaped structure. Here each of the three pieces that make up the "Y" are made of a small mass spring chain. In addition, we consider a case where multiple "Y"-shaped structures are used to generate a "tree." We explore the early time dynamical behavior associated with the propagation of a velocity perturbation initiated at the trunk and at the extremities for both cases. We are looking for the energy transmission properties from one branch to another of these "Y"-shaped structures. Our dynamical simulations suggest the following broad observations: (i) for strongly nonlinear interactions, mechanical energy propagation resembles pulse propagation with the energy propagation being dispersive in the linear case; (ii) for strong nonlinear interactions, the tree-like structure acts as an energy gate showing preference for large perturbations in the system while the behavior of the linear case shows no such preference, thereby suggesting that such structures can possibly act as switches that activate at sufficiently high energies. The study aspires to develop insights into the nature of nonlinear wave propagation through a network of linear chains.

  12. On Space Efficient Two Dimensional Range Minimum Data Structures

    DEFF Research Database (Denmark)

    Brodal, Gerth Stølting; Davoodi, Pooya; Rao, S. Srinivasa

    2012-01-01

    the space and query time of the problem. We show that every algorithm enabled to access A during the query and using a data structure of size O(N/c) bits requires Ω(c) query time, for any c where 1≤c≤N. This lower bound holds for arrays of any dimension. In particular, for the one dimensional version...... of the problem, the lower bound is tight up to a constant factor. In two dimensions, we complement the lower bound with an indexing data structure of size O(N/c) bits which can be preprocessed in O(N) time to support O(clog 2 c) query time. For c=O(1), this is the first O(1) query time algorithm using a data...... structure of optimal size O(N) bits. For the case where queries can not probe A, we give a data structure of size O(N⋅min {m,log n}) bits with O(1) query time, assuming m≤n. This leaves a gap to the space lower bound of Ω(Nlog m) bits for this version of the problem...

  13. Two-dimensional dynamics of a free molecular chain with a secondary structure

    DEFF Research Database (Denmark)

    Zolotaryuk, Alexander; Christiansen, Peter Leth; Savin, A.V.

    1996-01-01

    A simple two-dimensional (2D) model of an isolated (free) molecular chain with primary and secondary structures has been suggested and investigated both analytically and numerically. This model can be considered as the simplest generalization of the well-known Fermi-Pasta-Ulam model...... of an anharmonic chain in order to include transverse degrees of freedom of the chain molecules. Both the structures are provided by the first- and second-neighbor intermolecular bonds, respectively, resulting in a regular zig-zag (''20 helix'') chain on a plane. The set of two coupled nonlinear field equations...

  14. Cut-wire-pair structures as two-dimensional magnetic metamaterials.

    Science.gov (United States)

    Powell, David A; Shadrivov, Ilya V; Kivshar, Yuri S

    2008-09-15

    We study numerically and experimentally magnetic metamaterials based on cut-wire pairs instead of split-ring resonators. The cut-wire pair planar structure is extended in order to create a truly two-dimensional metamaterial suitable for scaling to optical frequencies. We fabricate the cut-wire metamaterial operating at microwave frequencies with lattice spacing around 10% of the free-space wavelength, and find good agreement with direct numerical simulations. Unlike the structures based on split-ring resonators, the nearest-neighbor coupling in cut-wire pairs can result in a magnetic stop-band with propagation in the transverse direction.

  15. On Space Efficient Two Dimensional Range Minimum Data Structures

    DEFF Research Database (Denmark)

    Davoodi, Pooya; Brodal, Gerth Stølting; Rao, S. Srinivasa

    2010-01-01

    , the lower bound is tight up to a constant factor. In two dimensions, we complement the lower bound with an indexing data structure of size O(N/c) bits additional space which can be preprocessed in O(N) time and achieves O(clog2 c) query time. For c = O(1), this is the first O(1) query time algorithm using...... optimal O(N) bits additional space. For the case where queries can not probe A, we give a data structure of size O(N· min {m,logn}) bits with O(1) query time, assuming m ≤ n. This leaves a gap to the lower bound of Ω(Nlogm) bits for this version of the problem....

  16. STRUCTURE OF KELLER MAPPINGS, TWO-DIMENSIONAL CASE

    Directory of Open Access Journals (Sweden)

    V. V. Starkov

    2017-06-01

    Full Text Available A Keller map is a polynomial mapping ƒ : Rⁿ → Rⁿ (or Cⁿ → Cⁿ with the Jacobian J_ƒ ≡ const ≠ 0. The Jacobian conjecture was first formulated by O. N. Keller in 1939. In the modern form it supposes injectivity of a Keller map. Earlier, in the case n = 2, the author gave a complete description of Keller maps with deg ƒ ≤ 3. This paper is devoted to the description of Keller maps for which deg ƒ ≤ 4. Significant differences between these two cases are revealed, which, in particular, indicate the irregular structure of Keller maps even in the case of n = 2.

  17. T-shaped polarization beam splitter based on two-dimensional photonic crystal waveguide structures

    Science.gov (United States)

    Li, Xinlan; Shen, Hongjun; Li, Ting; Liu, Jie; Huang, Xianjian

    2016-12-01

    A T-shaped polarization beam splitter based on two-dimensional photonic crystal is proposed, which is composed of three waveguides: one input and two output. Unpolarized beams incident from the input port will be separated into two different polarization modes and outputted individually by two different coupling structures. Simulation results can be obtained by the finite-difference time-domain (FDTD) method. In the normalized frequency range of 0.3456 extinction ratio is all 30dB for both modes. The polarization beam splitter attains the requirement we expected by analyzing simulation results.

  18. Band gap structures in two-dimensional super porous phononic crystals.

    Science.gov (United States)

    Liu, Ying; Sun, Xiu-zhan; Chen, Shao-ting

    2013-02-01

    As one kind of new linear cellular alloys (LCAs), Kagome honeycombs, which are constituted by triangular and hexagonal cells, attract great attention due to the excellent performance compared to the ordinary ones. Instead of mechanical investigation, the in-plane elastic wave dispersion in Kagome structures are analyzed in this paper aiming to the multi-functional application of the materials. Firstly, the band structures in the common two-dimensional (2D) porous phononic structures (triangular or hexagonal honeycombs) are discussed. Then, based on these results, the wave dispersion in Kagome honeycombs is given. Through the component cell porosity controlling, the effects of component cells on the whole responses of the structures are investigated. The intrinsic relation between the component cell porosity and the critical porosity of Kagome honeycombs is established. These results will provide an important guidance in the band structure design of super porous phononic crystals.

  19. Photodetectors Based on Two-Dimensional Layer-Structured Hybrid Lead Iodide Perovskite Semiconductors.

    Science.gov (United States)

    Zhou, Jiachen; Chu, Yingli; Huang, Jia

    2016-10-05

    Hybrid lead iodide perovskite semiconductors have attracted intense research interests recently because of their easy fabrication processes and high power conversion efficiencies in photovoltaic applications. Layer-structured materials have interesting properties such as quantum confinement effect and tunable band gap due to the unique two-dimensional crystalline structures. ⟨100⟩-oriented layer-structured perovskite materials are inherited from three-dimensional ABX3 perovskite materials with a generalized formula of (RNH3)2(CH3NH3)n-1MnX3n+1, and adopt the Ruddlesden-Popper type crystalline structure. Here we report the synthesis and investigation of three layer-structured perovskite materials with different layer numbers: (C4H9NH3)2PbI4 (n = 1, one-layered perovskite), (C4H9NH3)2(CH3NH3)Pb2I7 (n = 2, two-layered perovskite) and (C4H9NH3)2(CH3NH3)2Pb3I10 (n = 3, three-layered perovskite). Their photoelectronic properties were investigated in related to their molecular structures. Photodetectors based on these two-dimensional (2D) layer-structured perovskite materials showed tunable photoresponse with short response time in milliseconds. The photodetectors based on three-layered perovskite showed better performances than those of the other two devices, in terms of output current, responsivity, Ilight/Idark ratio, and response time, because of its smaller optical band gap and more condensed microstructure comparing the other two materials. These results revealed the relationship between the molecular structures, film microstructures and the photoresponse properties of 2D layer-structured hybrid perovskites, and demonstrated their potentials as flexible, functional, and tunable semiconductors in optoelectronic applications, by taking advantage of their tunable quantum well molecular structure.

  20. The mechanical and acoustic properties of two-dimensional pentamode metamaterials with different structural parameters

    Science.gov (United States)

    Cai, Xuan; Wang, Lei; Zhao, Zhigao; Zhao, Aiguo; Zhang, Xiangdong; Wu, Tao; Chen, Hong

    2016-09-01

    The effective mechanical and acoustic properties of two-dimensional pentamode metamaterials (PMs) with different structural parameters are investigated in this paper. It is found that with varying structural parameters, the effective bulk modulus and density remain constant as the same as those of water, while the figure of merit, i.e., the ratio of the bulk modulus to the shear modulus (B/G) gradually increases due to the decrease of the shear modulus. However, full wave simulations reveal that with the increase of B/G, the acoustic scattering becomes more and more intense, which indicates that the acoustic properties of pentamode metamaterials gradually deviate from those of water. These anomalous acoustic behaviors are proposed to arise from the existence of the bending modes in pentamode microstructures. Our results show that for pentamode metamaterials, the mechanical properties cannot be simply translated to their acoustic properties, and the structural parameters affect the mechanical and acoustic properties in much different ways.

  1. Identification of the dynamics of a two-dimensional grid structure using least square lattice filters

    Science.gov (United States)

    Montgomery, R. C.; Sundararajan, N.

    1984-01-01

    The basic theory of least square lattice filters and their use in identification of structural dynamics systems is summarized. Thereafter, this theory is applied to a two-dimensional grid structure made of overlapping bars. Previously, this theory has been applied to an integral beam. System identification results are presented for both simulated and experimental tests and they are compared with those predicted using finite element modelling. The lattice filtering approach works well for simulated data based on finite element modelling. However, considerable discrepancy exists between estimates obtained from experimental data and the finite element analysis. It is believed that this discrepancy is the result of inadequacies in the finite element modelling to represent the damped motion of the laboratory apparatus.

  2. Validating two-dimensional leadership models on three-dimensionally structured fish schools

    Science.gov (United States)

    Nagy, Máté; Holbrook, Robert I.; Biro, Dora; Burt de Perera, Theresa

    2017-01-01

    Identifying leader–follower interactions is crucial for understanding how a group decides where or when to move, and how this information is transferred between members. Although many animal groups have a three-dimensional structure, previous studies investigating leader–follower interactions have often ignored vertical information. This raises the question of whether commonly used two-dimensional leader–follower analyses can be used justifiably on groups that interact in three dimensions. To address this, we quantified the individual movements of banded tetra fish (Astyanax mexicanus) within shoals by computing the three-dimensional trajectories of all individuals using a stereo-camera technique. We used these data firstly to identify and compare leader–follower interactions in two and three dimensions, and secondly to analyse leadership with respect to an individual's spatial position in three dimensions. We show that for 95% of all pairwise interactions leadership identified through two-dimensional analysis matches that identified through three-dimensional analysis, and we reveal that fish attend to the same shoalmates for vertical information as they do for horizontal information. Our results therefore highlight that three-dimensional analyses are not always required to identify leader–follower relationships in species that move freely in three dimensions. We discuss our results in terms of the importance of taking species' sensory capacities into account when studying interaction networks within groups.

  3. Study on electro-optic properties of two-dimensional PLZT photonic crystal band structure

    Institute of Scientific and Technical Information of China (English)

    TONG Kai; WU Xiao-gang; WANG Mei-ting

    2011-01-01

    The band characteristics of two-dimensional (2D) lead lanthanum zirconate titanate (PLZT) photonic cystals are analyzed by finite element method. The electro-optic effect of PLZT can cause the refractive index change when it is imposed by the applied electric field, and the band structure of 2D photonic crystals based on PLZT varies accordingly. The effect of the applied electric field on the structural characteristics of the first and second band gaps in 2D PLZT photonic crystals is analyzed in detail. And the results show that for each band gap, the variations of start wavelength, cut-off wavelength and bandwidth are proportional to quadratic of the electric field.

  4. An Optical Power Divider Based on Two-dimensional Photonic Crystal Structure

    Science.gov (United States)

    Mesri, Nazanin; Alipour-Banaei, Hamed

    2017-05-01

    In this paper, an optical power divider with one input and four outputs has been proposed in a two-dimensional photonic crystal with triangular lattice and simulated using dielectric holes in an air substrate. The dividing properties of the power divider have been numerically simulated and analyzed using the plane wave expansion and finite difference time domain methods. The results show that the transmittance of this divider can be as high as 94.22 % for λ=1.55 µm; thus, the proposed structure is suitable for wavelength division multiplexing communication systems. Also, due to the small footprint of the proposed structure, this optical power divider is applicable for optical-integrated circuit design.

  5. Calculation and analysis of complex band structure in dispersive and dissipative two-dimensional photonic crystals

    CERN Document Server

    Brûlé, Yoann; Gralak, Boris

    2015-01-01

    Numerical calculation of modes in dispersive and absorptive systems is performed using the finite element method. The dispersion is tackled in the frame of an extension of Maxwell's equations where auxiliary fields are added to the electromagnetic field. This method is applied to multi-domain cavities and photonic crystals including Drude and Drude-Lorentz metals. Numerical results are compared to analytical solutions for simple cavities and to previous results of the literature for photonic crystals, showing excellent agreement. The advantages of the developed method lie on the versatility of the finite element method regarding geometries, and in sparing the use of tedious complex poles research algorithm. Hence the complex spectrum of resonances of non-hermitian operators and dissipative systems, like two-dimensional photonic crystal made of absorbing Drude metal, can be investigated in detail. The method is used to reveal unexpected features of their complex band structures.

  6. Two-dimensional NMR and structure determination of salmon calcitonin in methanol

    Energy Technology Data Exchange (ETDEWEB)

    Meadows, R.P.; Nikonowicz, E.P.; Jones, C.R.; Gorenstein, D.G. (Purdue Univ., Lafayette, IN (USA)); Bastian, J.W.

    1991-02-05

    The structure of the 32-residue peptide salmon calcitonin (sCT) in 90% MeOH-10% H{sub 2}O has been investigated by two-dimensional NMR techniques and molecular modeling. Sequential assignments for nearly all of the 32 spin systems have been obtained, and results indicate that the heptaresidue loop formed by the disulfide bond between Cys-1 and Cys-7 is followed by an {alpha}-helical segment from Val-8 through Tyr-22. A region of conformational heterogeneity is observed for residues 20-25, resulting from the slow isomerism of the cis and trans forms of Pro-23. The C-terminal segment is found to exist in an extended conformation.

  7. New hybrid lead iodides: From one-dimensional chain to two-dimensional layered perovskite structure

    Energy Technology Data Exchange (ETDEWEB)

    Xiong, Kecai; Liu, Wei [Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854 (United States); Teat, Simon J. [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); An, Litao; Wang, Hao; Emge, Thomas J. [Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854 (United States); Li, Jing, E-mail: jingli@rutgers.edu [Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854 (United States)

    2015-10-15

    Two new hybrid lead halides (H{sub 2}BDA)[PbI{sub 4}] (1) (H{sub 2}BDA=1,4-butanediammonium dication) and (HNPEIM)[PbI{sub 3}] (2) (HNPEIM=N-​phenyl-ethanimidamidine cation) have been synthesized and structurally characterized. X-ray diffraction analyses reveal that compound 1 features a two-dimensional corner-sharing perovskite layer whereas compound 2 contains one-dimensional edge-sharing double chains. The N-​phenyl-ethanimidamidine cation within compound 2 was generated in-situ under solvothermal conditions. The optical absorption spectra collected at room temperature suggest that both compounds are semiconductors having direct band gaps, with estimated values of 2.64 and 2.73 eV for 1 and 2, respectively. Results from the density functional theory (DFT) calculations are consistent with the experimental data. Density of states (DOS) analysis reveals that in both compounds 1 and 2, the energy states in the valence band maximum region are iodine 5p atomic orbitals with a small contribution from lead 6s, while in the region of conduction band minimum, the major contributions are from the inorganic (Pb 6p atomic orbitals) and organic components (C and N 2p atomic orbitals) in compound 1 and 2, respectively. - Graphical abstract: Two new hybrid lead halides built on one-dimensional edge-sharing double chains and two-dimensional corner-sharing perovskite layers are synthesized and their structural and electronic properties are analyzed. - Highlights: • Two new hybrid lead iodides are designed, synthesized, and characterized. • They are closely related to, but different from, perovskite structures. • The electronic properties of both compounds are analyzed by DFT calculations.

  8. Transport Properties of Two-Dimensional Electron Gases in Antiparallel Magnetic-Electric Barrier Structures

    Institute of Scientific and Technical Information of China (English)

    PING Yun-Xia; CHENG Ze

    2006-01-01

    We study theoretically transport properties of two-dimensional electron gases through antiparallel magnetic electric barrier structures. Two kinds of magnetic barrier configurations are employed: one is that the strength of the double δ-function in opposite directions is equal and the other is that the strength is unequal. Similarities and differences of electronic transports are presented. It is found that the transmission and the conductance depend strongly on the shape of the magnetic barrier and the height of the electric barrier. The results indicate that this system does not possess any spin filtering and spin polarization and electron gases can realize perfect resonant tunneling and wave-vector filtering properties. Moreover, the strength of the effect of the inhomogeneous magnetic field on the transport properties is discussed.

  9. Direct Measurement of the Band Structure of a Buried Two-Dimensional Electron Gas

    DEFF Research Database (Denmark)

    Miwa, Jill; Hofmann, Philip; Simmons, Michelle Y.;

    2013-01-01

    We directly measure the band structure of a buried two dimensional electron gas (2DEG) using angle resolved photoemission spectroscopy. The buried 2DEG forms 2 nm beneath the surface of p-type silicon, because of a dense delta-type layer of phosphorus n-type dopants which have been placed there. ...

  10. Two-Dimensional Structure of Disulfides and Thiols on Gold(111)

    NARCIS (Netherlands)

    Nelles, Gabriele; Schönherr, Holger; Jaschke, Manfred; Wolf, Heiko; Schaub, Matthias; Kuther, Jörg; Tremel, Wolfgang; Bamberg, Ernst; Ringsdorf, Helmut; Butt, Hans-Jürgen

    1998-01-01

    In order to find factors which determine the two-dimensional structure of self-assembled monolayers (SAMs), several classes of thiols and disulfides on gold (111) have been investigated by atomic force microscopy (AFM). SAMs were formed from a series of symmetrical and asymmetrical diethylalkanoate

  11. Model for ballistic spin-transport in ferromagnet/two-dimensional electron gas/ferromagnet structures

    NARCIS (Netherlands)

    Schapers, T; Nitta, J; Heersche, HB; Takayanagi, H

    2002-01-01

    The spin dependent conductance of a ferromagnet/two-dimensional electron gas ferromagnet structure is theoretically examined in the ballistic transport regime. It is shown that the spin signal can be improved considerably by making use of the spin filtering effect of a barrier at the ferromagnet two

  12. Signatures of beta-sheet secondary structures in linear and two-dimensional infrared spectroscopy

    NARCIS (Netherlands)

    Cheatum, CM; Tokmakoff, A; Knoester, J

    2004-01-01

    Using idealized models for parallel and antiparallel beta sheets, we calculate the linear and two-dimensional infrared spectra of the amide I vibration as a function of size and secondary structure. The model assumes transition-dipole coupling between the amide I oscillators in the sheet and account

  13. Coherent two-dimensional infrared spectroscopy: quantitative analysis of protein secondary structure in solution.

    Science.gov (United States)

    Baiz, Carlos R; Peng, Chunte Sam; Reppert, Mike E; Jones, Kevin C; Tokmakoff, Andrei

    2012-04-21

    We present a method to quantitatively determine the secondary structure composition of globular proteins using coherent two-dimensional infrared (2DIR) spectroscopy of backbone amide I vibrations (1550-1720 cm(-1)). Sixteen proteins with known crystal structures were used to construct a library of 2DIR spectra, and the fraction of residues in α-helix, β-sheet, and unassigned conformations was determined by singular value decomposition (SVD) of the measured two-dimensional spectra. The method was benchmarked by removing each individual protein from the set and comparing the composition extracted from 2DIR against the composition determined from the crystal structures. To highlight the increased structural content extracted from 2DIR spectra a similar analysis was also carried out using conventional infrared absorption of the proteins in the library.

  14. A Multi-Resolution Data Structure for Two-Dimensional Morse Functions

    Energy Technology Data Exchange (ETDEWEB)

    Bremer, P-T; Edelsbrunner, H; Hamann, B; Pascucci, V

    2003-07-30

    The efficient construction of simplified models is a central problem in the field of visualization. We combine topological and geometric methods to construct a multi-resolution data structure for functions over two-dimensional domains. Starting with the Morse-Smale complex we build a hierarchy by progressively canceling critical points in pairs. The data structure supports mesh traversal operations similar to traditional multi-resolution representations.

  15. Stability and electronic structure of two-dimensional allotropes of group-IV materials

    Science.gov (United States)

    Matusalem, Filipe; Marques, Marcelo; Teles, Lara K.; Bechstedt, Friedhelm

    2015-07-01

    We study six different two-dimensional (2D) allotropes of carbon, silicon, germanium, and tin by means of the ab initio density functional theory for the ground state and approximate methods to calculate their electronic structures, including quasiparticle effects. Four of the investigated allotropes are based on dumbbell geometries, one on a kagome lattice, and one on the graphenelike hexagonal structure for comparison. Concerning carbon, our calculations of the cohesive energies clearly show that the hexagonal structure (graphene) is most stable. However, in the case of Si and Ge, the dumbbell structures, particularly the large honeycomb dumbbell (LHD) geometries, are energetically favored compared to the s p2/s p3 -bonded hexagonal lattice (i.e., silicene and germanene). The main reason for this is the opening of a band gap in the honeycomb dumbbell arrangements. The LHD sheet crystals represent indirect semiconductors with a K →Γ gap of about 0.5 eV. In the Sn case we predict the MoS2-like symmetry to be more stable, in contrast to the stanene and LHD geometries predicted in literature. Our results for freestanding group-IV layers shine new light on recent experimental studies of group-IV overlayers on various substrates.

  16. Valence and conduction band structure of the quasi-two-dimensional semiconductor Sn S2

    Science.gov (United States)

    Racke, David A.; Neupane, Mahesh R.; Monti, Oliver L. A.

    2016-02-01

    We present the momentum-resolved photoemission spectroscopy of both the valence and the conduction band region in the quasi-two-dimensional van der Waals-layered indirect band gap semiconductor Sn S2 . Using a combination of angle-resolved ultraviolet photoemission and angle-resolved two-photon photoemission (AR-2PPE) spectroscopy, we characterize the band structure of bulk Sn S2 . Comparison with density functional theory calculations shows excellent quantitative agreement in the valence band region and reveals several localized bands that likely originate from defects such as sulfur vacancies. Evidence for a moderate density of defects is also observed by AR-2PPE in the conduction band region, leading to localized bands not present in the computational results. The energetic structure and dispersion of the conduction bands is captured well by the computational treatment, with some quantitative discrepancies remaining. Our results provide a broader understanding of the electronic structure of Sn S2 in particular and van der Waals-layered semiconductors in general.

  17. A humidity sensitive two-dimensional tunable amorphous photonic structure in the outer layer of bivalve ligament from Sunset Siliqua

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Weigang, E-mail: abczwg15@163.com [College of Materials and Chemical Engineering, Chuzhou University, Chuzhou 239000 (China); Zhang, Gangsheng [College of Material Science and Technology, Guangxi University, Nanning 530004 (China)

    2015-07-01

    A humidity sensitive two-dimensional tunable amorphous photonic structure (2D TAPS) in the outer layer of bivalve ligament from Sunset Siliqua (OLLS) was reported in this paper. The structural color and microstructure of OLLS were investigated by reflection spectra and scanning electron microscopy, respectively. The results indicate that the reflection peak wavelength of the wet OLLS blue-shifts from 454 nm to 392 nm with the increasing of air drying time from 0 to 40 min, while the reflectivity decreases gradually and vanishes at last, relevant color changes from blue to black background color. The structural color in the OLLS is produced by a two-dimensional amorphous photonic structure consisting of aligned protein fibers, in which the diameter of protein fiber and the inter-fiber spacing are 101 ± 12 nm. Water can reversibly tune the reflection peak wavelength and reflectivity of this photonic structure, and the regulation achieved through dynamically tuning the interaction between inter-fiber spacing and average refractive index. - Highlights: • A humidity sensitive two-dimensional tunable amorphous photonic structure • Water can reversibly tune the reflection peak wavelength and reflectivity of this photonic structure. • This photonic structure may yield very useful template for artificial structures.

  18. A two-dimensional mutate-and-map strategy for non-coding RNA structure

    Science.gov (United States)

    Kladwang, Wipapat; Vanlang, Christopher C.; Cordero, Pablo; Das, Rhiju

    2011-12-01

    Non-coding RNAs fold into precise base-pairing patterns to carry out critical roles in genetic regulation and protein synthesis, but determining RNA structure remains difficult. Here, we show that coupling systematic mutagenesis with high-throughput chemical mapping enables accurate base-pair inference of domains from ribosomal RNA, ribozymes and riboswitches. For a six-RNA benchmark that has challenged previous chemical/computational methods, this ‘mutate-and-map’ strategy gives secondary structures that are in agreement with crystallography (helix error rates, 2%), including a blind test on a double-glycine riboswitch. Through modelling of partially ordered states, the method enables the first test of an interdomain helix-swap hypothesis for ligand-binding cooperativity in a glycine riboswitch. Finally, the data report on tertiary contacts within non-coding RNAs, and coupling to the Rosetta/FARFAR algorithm gives nucleotide-resolution three-dimensional models (helix root-mean-squared deviation, 5.7 Å) of an adenine riboswitch. These results establish a promising two-dimensional chemical strategy for inferring the secondary and tertiary structures that underlie non-coding RNA behaviour.

  19. Analysis of bandgap characteristics of two-dimensional periodic structures by using the source-model technique.

    Science.gov (United States)

    Ludwig, Alon; Leviatan, Yehuda

    2003-08-01

    We introduce a solution based on the source-model technique for periodic structures for the problem of electromagnetic scattering by a two-dimensional photonic bandgap crystal slab illuminated by a transverse-magnetic plane wave. The proposed technique takes advantage of the periodicity of the slab by solving the problem within the unit cell of the periodic structure. The results imply the existence of a frequency bandgap and provide a valuable insight into the relationship between the dimensions of a finite periodic structure and its frequency bandgap characteristics. A comparison shows a discrepancy between the frequency bandgap obtained for a very thick slab and the bandgap obtained by solving the corresponding two-dimensionally infinite periodic structure. The final part of the paper is devoted to explaining in detail this apparent discrepancy.

  20. Band structures in two-dimensional phononic crystals with periodic Jerusalem cross slot

    Science.gov (United States)

    Li, Yinggang; Chen, Tianning; Wang, Xiaopeng; Yu, Kunpeng; Song, Ruifang

    2015-01-01

    In this paper, a novel two-dimensional phononic crystal composed of periodic Jerusalem cross slot in air matrix with a square lattice is presented. The dispersion relations and the transmission coefficient spectra are calculated by using the finite element method based on the Bloch theorem. The formation mechanisms of the band gaps are analyzed based on the acoustic mode analysis. Numerical results show that the proposed phononic crystal structure can yield large band gaps in the low-frequency range. The formation mechanism of opening the acoustic band gaps is mainly attributed to the resonance modes of the cavities inside the Jerusalem cross slot structure. Furthermore, the effects of the geometrical parameters on the band gaps are further explored numerically. Results show that the band gaps can be modulated in an extremely large frequency range by the geometry parameters such as the slot length and width. These properties of acoustic waves in the proposed phononic crystals can potentially be applied to optimize band gaps and generate low-frequency filters and waveguides.

  1. Optical gaps, mode patterns and dipole radiation in two-dimensional aperiodic photonic structures

    Science.gov (United States)

    Boriskina, Svetlana V.; Gopinath, Ashwin; Negro, Luca Dal

    2009-05-01

    Based on the rigorous generalized Mie theory solution of Maxwell's equations for dielectric cylinders we theoretically investigate the optical properties of two-dimensional deterministic structures based on the Fibonacci, Thue-Morse and Rudin-Shapiro aperiodic sequences. In particular, we investigate bandgap formation and mode localization properties in aperiodic photonic structures based on the accurate calculation of their local density of states (LDOS). In addition, we explore the potential of photonic structures based on aperiodic order for the engineering of radiative rates and emission patterns in erbium-doped silicon-rich nitride photonic structures.

  2. Structural information in two-dimensional patterns: entropy convergence and excess entropy.

    Science.gov (United States)

    Feldman, David P; Crutchfield, James P

    2003-05-01

    We develop information-theoretic measures of spatial structure and pattern in more than one dimension. As is well known, the entropy density of a two-dimensional configuration can be efficiently and accurately estimated via a converging sequence of conditional entropies. We show that the manner in which these conditional entropies converge to their asymptotic value serves as a measure of global correlation and structure for spatial systems in any dimension. We compare and contrast entropy convergence with mutual-information and structure-factor techniques for quantifying and detecting spatial structure.

  3. Two-dimensional Fourier analysis of the spongy medullary keratin of structurally coloured feather barbs

    Science.gov (United States)

    Prum, R. O.; Torres, R.; Williamson, S.; Dyck, J.

    1999-01-01

    We conducted two-dimensional (2D) discrete Fourier analyses of the spatial variation in refractive index of the spongy medullary keratin from four different colours of structurally coloured feather barbs from three species of bird: the rose-faced lovebird, Agapornis roseicollis (Psittacidae), the budgerigar, Melopsittacus undulatus (Psittacidae), and the Gouldian finch, Poephila guttata (Estrildidae). These results indicate that the spongy medullary keratin is a nanostructured tissue that functions as an array of coherent scatterers. The nanostructure of the medullary keratin is nearly uniform in all directions. The largest Fourier components of spatial variation in refractive index in the tissue are of the appropriate size to produce the observed colours by constructive interference alone. The peaks of the predicted reflectance spectra calculated from the 2D Fourier power spectra are congruent with the reflectance spectra measured by using microspectrophotometry. The alternative physical models for the production of these colours, the Rayleigh and Mie theories, hypothesize that medullary keratin is an incoherent array and that scattered waves are independent in phase. This assumption is falsified by the ring-like Fourier power spectra of these feathers, and the spacing of the scattering air vacuoles in the medullary keratin. Structural colours of avian feather barbs are produced by constructive interference of coherently scattered light waves from the optically heterogeneous matrix of keratin and air in the spongy medullary layer.

  4. Synthesis and structural characterization of two-dimensional hierarchical covellite nano-structures

    Energy Technology Data Exchange (ETDEWEB)

    Banerjee, Nirupam, E-mail: n.banerjee@utwente.nl [Materials Research Center, Indian Institute of Science, Bangalore 560012 (India); MESA Institute for Nanotechnology, University of Twente, Enschede (Netherlands); Krupanidhi, S.B., E-mail: sbk@mrc.iisc.ernet.in [Materials Research Center, Indian Institute of Science, Bangalore 560012 (India)

    2012-12-14

    We report a simple, template free and low-temperature hydrothermal reaction pathway using Cu(II) - thiourea complex (prepared in situ from copper (II) chloride and thiourea as precursors) and citric acid as complexing agent to synthesize two-dimensional hierarchical nano-structures of covellite (CuS). The product was characterized with the help of X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive analysis of X-ray spectroscopy (EDAX) and X-ray photoelectron spectroscopy (XPS). The concentration of citric acid in the hydrothermal precursor solution was seen to have a profound effect on the nanostructure of the product generated. Based on the outcoming product nano-architecture at different concentration of the ionic surfactant in the hydrothermal precursor solution a possible mechanism suited for reaction and further nucleation is also discussed. -- Highlights: Black-Right-Pointing-Pointer A novel reaction scheme is proposed for synthesizing covellite 2D nano-structures. Black-Right-Pointing-Pointer The nanostructures were thoroughly characterized, both structurally and chemically. Black-Right-Pointing-Pointer Through variation of synthetic parameters a general growth mechanism is proposed.

  5. Reconstruction of two-dimensional magnetopause structures from Cluster observations: verification of method

    Directory of Open Access Journals (Sweden)

    H. Hasegawa

    2004-04-01

    Full Text Available A recently developed technique for reconstructing approximately two-dimensional (∂/∂z≈0, time-stationary magnetic field structures in space is applied to two magnetopause traversals on the dawnside flank by the four Cluster spacecraft, when the spacecraft separation was about 2000km. The method consists of solving the Grad-Shafranov equation for magnetohydrostatic structures, using plasma and magnetic field data measured along a single spacecraft trajectory as spatial initial values. We assess the usefulness of this single-spacecraft-based technique by comparing the magnetic field maps produced from one spacecraft with the field vectors that other spacecraft actually observed. For an optimally selected invariant (z-axis, the correlation between the field components predicted from the reconstructed map and the corresponding measured components reaches more than 0.97. This result indicates that the reconstruction technique predicts conditions at the other spacecraft locations quite well.

    The optimal invariant axis is relatively close to the intermediate variance direction, computed from minimum variance analysis of the measured magnetic field, and is generally well determined with respect to rotations about the maximum variance direction but less well with respect to rotations about the minimum variance direction. In one of the events, field maps recovered individually for two of the spacecraft, which crossed the magnetopause with an interval of a few tens of seconds, show substantial differences in configuration. By comparing these field maps, time evolution of the magnetopause structures, such as the formation of magnetic islands, motion of the structures, and thickening of the magnetopause current layer, is discussed.

    Key words. Magnetospheric physics (Magnetopause, cusp, and boundary layers – Space plasma physics (Experimental and mathematical techniques, Magnetic reconnection

  6. Hydrogen Bonding and Multiphonon Structure in One- and Two-Dimensional Polymeric Magnets

    Science.gov (United States)

    Musfeldt, J. L.; Brown, S.; Cao, J.; Conner, M. M.; McConnell, A. C.; Southerland, H. I.; Manson, J. L.; Schlueter, J. A.; Phillips, M. D.; Turnbull, M. M.; Landee, C. P.

    2007-03-01

    We report a systematic investigation of the temperature dependent infrared vibrational spectra of a family of chemically related coordination polymeric magnets based upon two different bridging anions, fluoride (F^-) and bifluoride (HF2^-), in copper-pyrazine complexes including Cu(HF2)(pyz)2BF4, Cu(HF2)(pyz)2ClO4, and CuF2(H2O)(pyz)). We compare our results with several one- and two-dimensional prototype materials including Cu(NO3)2(pyz) and Cu(ClO4)(pyz) 2. Unusual low temperature hydrogen bonding, local structural transitions associated with stronger low-temperature hydrogen bonding, and striking multiphonon effects that derive from coupling of an infrared-active fundamental with strong Raman-active modes of the pyrazine building-block molecule are observed. Based on the spectroscopic evidence, these interactions are common to this family of coordination polymers and work to stabilize the low temperature magnetic state. Similar interactions are likely to be present in other molecule-based magnets.

  7. Coupling between Fano and Bragg bands in photonic band structure of two-dimensional metallic photonic structures

    CERN Document Server

    Markos, Peter

    2016-01-01

    Frequency and transmission spectrum of two-dimensional array of metallic rods is investigated numerically. Based on the recent analysis of the band structure of two-dimensional photonic crystal with dielectric rods [P. Marko\\v{s}, Phys. Rev. A 92 043814 (2015)] we identify two types of bands in the frequency spectrum: Bragg (P) bands resulting from a periodicity and Fano (F) bands which arise from Fano resonances associated with each of the cylinders within the periodic structure. It is shown that the existence of Fano band in a certain frequency range is manifested by a Fano resonance in the transmittance. In particular, we re-examine the symmetry properties of the H- polarized band structure in the frequency range where the spectrum consists of the localized modes associated with the single scatterer resonances and we explore process of formation of Fano bands by identifying individual terms in the expansion of the LCAO states. We demonstrate how the interplay between the two scattering mechanisms affects p...

  8. Synchronization of radiation in an oversized coaxial Ka-band backward wave oscillator using two-dimensional Bragg structure

    Directory of Open Access Journals (Sweden)

    N. S. Ginzburg

    2015-12-01

    Full Text Available A coaxial Ka-band backward wave oscillator with a two-dimensional Bragg structure located at the output of the interaction space has been studied. This structure has a double-period corrugation and provides azimuthal electromagnetic energy fluxes, which act on the synchronized radiation of an oversized tubular electron beam. Proof-of-principle experiments were conducted based on the Saturn thermionic accelerator (300  keV/200  A/2  μs. In accordance with simulations, narrow-band generation was obtained at a frequency of 30 GHz and a power level of 1.5–2 MW. As a result, the possibility of using a two-dimensional distributed feedback mechanism in oscillators of the Cherenkov type has been demonstrated.

  9. Two-dimensional iron oxide bi-and trilayer structures on Pd(100)

    Science.gov (United States)

    Kuhness, D.; Pomp, S.; Mankad, V.; Barcaro, G.; Sementa, L.; Fortunelli, A.; Netzer, F. P.; Surnev, S.

    2016-03-01

    The growth morphology and structure of iron oxide films, prepared by postoxidation of Fe monolayers on a Pd(100) surface, have been investigated in a multitechnique study, using scanning tunneling microscopy (STM), low energy electron diffraction (LEED), high-resolution x-ray photoelectron spectroscopy (HR-XPS) and x-ray absorption spectroscopy (XAS), both using synchrotron radiation, and comprehensive density functional theory (DFT) analysis. A two-dimensional (2-D) hexagonal O-Fe-O trilayer phase has been generated at submonolayer Fe coverages, which converges into two different 2-D hexagonal Fe-O bilayer structures at one monolayer. One phase exhibits a c(8 × 2) coincidence structure and is associated with a stoichiometric FeO(111) bilayer. The second phase displays a superstructure of triangular loops, which is understood from DFT modeling as excess O ad-atoms in the terminating oxygen layer, thus corresponding to a FeO bilayer with a formal FeO1.125 stoichiometry. Annealing the latter in ultrahigh vacuum to 770 K results in the pure c(8 × 2) wetting layer. The thermodynamic stability of the O-Fe-O trilayer and FeO bilayer phases is analyzed in the DFT framework and is found to be in good agreement with the experiment. The absence of a c(4 × 2)-Fe3O4 phase in the experimental phase diagram, which is found to be stable by DFT and is experimentally encountered for other transition metal oxide films, such as Ni-, Co-, and Mn-oxide on Pd(100), is ascribed to kinetic reasons.

  10. Wave transmission through two-dimensional structures by the hybrid FE/WFE approach

    Science.gov (United States)

    Mitrou, Giannoula; Ferguson, Neil; Renno, Jamil

    2017-02-01

    The knowledge of the wave transmission and reflection characteristics in connected two-dimensional structures provides the necessary background for many engineering prediction methodologies. Extensive efforts have previously been exerted to investigate the propagation of waves in two-dimensional periodic structures. This work focuses on the analysis of the wave propagation and the scattering properties of joined structures comprising of two or more plates. The joint is modelled using the finite element (FE) method whereas each (of the joined) plate(s) is modelled using the wave and finite element (WFE) method. This latter approach is based on post-processing a standard FE model of a small segment of the plate using periodic structure theory; the FE model of the segment can be obtained using any commercial/in-house FE package. Stating the equilibrium and continuity conditions at the interfaces and expressing the motion in the plates in terms of the waves in each plate yield the reflection and transmission matrices of the joint. These can then be used to obtain the response of the whole structure, as well as investigating the frequency and incidence dependence for the flow of power in the system.

  11. Two-dimensional computer simulation of hypervelocity impact cratering: some preliminary results for Meteor Crater, Arizona

    Energy Technology Data Exchange (ETDEWEB)

    Bryan, J.B.; Burton, D.E.; Cunningham, M.E.; Lettis, L.A. Jr.

    1978-06-01

    A computational approach used for subsurface explosion cratering was extended to hypervelocity impact cratering. Meteor (Barringer) Crater, Arizona, was selected for the first computer simulation because it is one of the most thoroughly studied craters. It is also an excellent example of a simple, bowl-shaped crater and is one of the youngest terrestrial impact craters. Initial conditions for this calculation included a meteorite impact velocity of 15 km/s, meteorite mass of 1.67 x 10/sup 8/ kg, with a corresponding kinetic energy of 1.88 x 10/sup 16/ J (4.5 megatons). A two-dimensional Eulerian finite difference code called SOIL was used for this simulation of a cylindrical iron projectile impacting at normal incidence into a limestone target. For this initial calculation, a Tillotson equation-of-state description for iron and limestone was used with no shear strength. Results obtained for this preliminary calculation of the formation of Meteor Crater are in good agreement with field measurements. A color movie based on this calculation was produced using computer-generated graphics. 19 figures, 5 tables, 63 references.

  12. Wake structure and thrust generation of a flapping foil in two-dimensional flow

    DEFF Research Database (Denmark)

    Andersen, Anders Peter; Bohr, Tomas; Schnipper, Teis

    2017-01-01

    We present a combined numerical (particle vortex method) and experimental (soap film tunnel) study of a symmetric foil undergoing prescribed oscillations in a two-dimensional free stream. We explore pure pitching and pure heaving, and contrast these two generic types of kinematics. We compare...... measurements and simulations when the foil is forced with pitching oscillations, and we find a close correspondence between flow visualisations using thickness variations in the soap film and the numerically determined vortex structures. Numerically, we determine wake maps spanned by oscillation frequency...

  13. Flexural vibration band gaps in thin plates with two-dimensional binary locally resonant structures

    Institute of Scientific and Technical Information of China (English)

    Yu Dian-Long; Wang Gang; Liu Yao-Zong; Wen Ji-Hong; Qiu Jing

    2006-01-01

    The complete flexural vibration band gaps are studied in the thin plates with two-dimensional binary locally resonant structures, i.e. the composite plate consisting of soft rubber cylindrical inclusions periodically placed in a host material. Numerical simulations show that the low-frequency gaps of flexural wave exist in the thin plates. The width of the first gap decreases monotonically as the matrix density increases. The frequency response of the finite periodic thin plates is simulated by the finite element method, which provides attenuations of over 20dB in the frequency range of the band gaps. The findings will be significant in the application of phononic crystals.

  14. Resistive MHD reconstruction of two-dimensional coherent structures in space

    Directory of Open Access Journals (Sweden)

    W.-L. Teh

    2010-11-01

    Full Text Available We present a reconstruction technique to solve the steady resistive MHD equations in two dimensions with initial inputs of field and plasma data from a single spacecraft as it passes through a coherent structure in space. At least two components of directly measured electric fields (the spacecraft spin-plane components are required for the reconstruction, to produce two-dimensional (2-D field and plasma maps of the cross section of the structure. For convenience, the resistivity tensor η is assumed diagonal in the reconstruction coordinates, which allows its values to be estimated from Ohm's law, E+v×B=η·j. In the present paper, all three components of the electric field are used. We benchmark our numerical code by use of an exact, axi-symmetric solution of the resistive MHD equations and then apply it to synthetic data from a 3-D, resistive, MHD numerical simulation of reconnection in the geomagnetic tail, in a phase of the event where time dependence and deviations from 2-D are both weak. The resistivity used in the simulation is time-independent and localized around the reconnection site in an ellipsoidal region. For the magnetic field, plasma density, and pressure, we find very good agreement between the reconstruction results and the simulation, but the electric field and plasma velocity are not predicted with the same high accuracy.

  15. Two-dimensional quantum compass model in a staggered field: some rigorous results

    Institute of Scientific and Technical Information of China (English)

    He Pei-Song; You Wen-Long; Tian Guang-Shan

    2011-01-01

    We study the properties of the two-dimensional quantum compass model in a staggered field. Using the PerronFr(o)enius theorem and the reflection positivity method, we rigorously determine the low energy spectrum of this model and its global ground state Ψ0. Furthermore, we show that Ψ0 has a directional long-range order.

  16. Investigating protein structure and folding with coherent two-dimensional infrared spectroscopy

    Science.gov (United States)

    Baiz, Carlos; Peng, Chunte; Reppert, Michael; Jones, Kevin; Tokmakoff, Andrei

    2012-02-01

    We present a new technique to quantitatively determine the secondary structure composition of proteins in solution based on ultrafast two-dimensional infrared (2DIR) spectroscopy. The percentage of residues in alpha-helix, beta-sheet, and unstructured conformations is extracted from a principal component analysis of the measured amide-I 2DIR spectra. We benchmark the method against a library of commercially-available proteins by comparing the predicted structure compositions with the x-ray crystal structures. The new technique offers sub-picosecond time resolution, and can be used to study systems that are difficult to study with conventional methods such as gels, intrinsically disordered peptides, fibers, and aggregates. We use the technique to investigate the structural changes and timescales associated with folding and denaturing of small proteins via equilibrium and transient temperature-jump 2DIR spectroscopy.

  17. Two-dimensional structure in a generic model of triangular proteins and protein trimers.

    Science.gov (United States)

    Camp, Philip J; Duncan, Peter D

    2006-04-01

    Motivated by the diversity and complexity of two-dimensional (2D) crystals formed by triangular proteins and protein trimers, we have investigated the structures and phase behavior of hard-disk trimers. In order to mimic specific binding interactions, each trimer possesses an "attractive" disk which can interact with similar disks on other trimers via an attractive square-well potential. At low density and low temperature, the fluid phase mainly consists of tetramers, pentamers, or hexamers. Hexamers provide the structural motif for a high-density, low-temperature periodic solid phase, but we also identify a metastable periodic structure based on a tetramer motif. At high density there is a transition between orientationally ordered and disordered solid phases. The connections between simulated structures and those of 2D protein crystals--as seen in electron microscopy--are briefly discussed.

  18. Two-dimensional artificial light-harvesting antennae with predesigned high-order structure and robust photosensitising activity

    Science.gov (United States)

    Feng, Xiao; Ding, Xuesong; Chen, Long; Wu, Yang; Liu, Lili; Addicoat, Matthew; Irle, Stephan; Dong, Yuping; Jiang, Donglin

    2016-09-01

    Highly ordered discrete assemblies of chlorophylls that are found in natural light-harvesting antennae are key to photosynthesis, which converts light energy to chemical energy and is the principal producer of organic matter on Earth. Porphyrins and phthalocyanines, which are analogues of chlorophylls, exhibit a strong absorbance of visible and near-infrared light, respectively. A highly ordered porphyrin-co-phthalocyanine antennae would harvest photons over the entire solar spectrum for chemical transformation. However, such a robust antennae has not yet been synthesised. Herein, we report a strategy that merges covalent bonds and noncovalent forces to produce highly ordered two-dimensional porphyrin-co-phthalocyanine antennae. This methodology enables control over the stoichiometry and order of the porphyrin and phthalocyanine units; more importantly, this approach is compatible with various metalloporphyrin and metallophthalocyanine derivatives and thus may lead to the generation of a broad structural diversity of two-dimensional artificial antennae. These ordered porphyrin-co-phthalocyanine two-dimensional antennae exhibit unique optical properties and catalytic functions that are not available with single-component or non-structured materials. These 2D artificial antennae exhibit exceptional light-harvesting capacity over the entire solar spectrum as a result of a synergistic light-absorption effect. In addition, they exhibit outstanding photosensitising activities in using both visible and near-infrared photons for producing singlet oxygen.

  19. Dynamics and Structure of Disordered Peptides from Two-Dimensional Infrared Spectroscopy

    Science.gov (United States)

    Reppert, Mike; Lessing, Joshua; Peng, Chunte; Jones, Kevin; Baiz, Carlos; Tokmakoff, Andrei

    2012-02-01

    Two-dimensional infrared (IR) spectroscopy is a powerful tool for investigating the ultra-fast dynamics and association of complex biological macromolecules such as proteins and DNA. In addition to the improved spectral discrimination afforded by a two-dimensional spectrum, the ultra-fast time-resolution inherent to the technique provides unique insight (unobtainable by standard linear IR measurements) into the time-scales of macromolecular conformational fluctuations, particularly for intrinsically disordered systems. Here we discuss the use of accurate line shape modeling of peptide amide I vibrations as an advanced method for extracting structural and dynamic information from experimental spectra. The mixed quantum-classical model makes use of standard MD trajectories and a parametrized site energy and coupling map as inputs for excitonic calculations of the delocalized amide I vibrations. We present examples of the application of this method to extract site-specific structural information (such as hydrogen bond number and turn conformation) as well as insight into conformation dynamics and time-scales from experimental data for disordered peptides.

  20. The Second Las Cruces Trench Experiment: Experimental Results and Two-Dimensional Flow Predictions

    Science.gov (United States)

    Hills, R. G.; Wierenga, P. J.; Hudson, D. B.; Kirkland, M. R.

    1991-10-01

    As part of a comprehensive field study designed to provide data to test stochastic and deterministic models of water flow and contaminant transport in the vadose zone, several trench experiments were performed in the semiarid region of southern New Mexico. The first trench experiment is discussed by Wierenga et al. (this issue). During the second trench experiment, a 1.2 m wide by 12 m long area on the north side of and parallel to a 26.4 m long by 4.8 m wide by 6m deep trench was irrigated with water containing tracers using a carefully controlled drip irrigation system. The irrigated area was heavily instrumented with tensiometers and neutron probe access tubes to monitor water movement, and with suction samplers to monitor solute transport. Water containing tritium and bromide was. applied during the first 11.5 days of the study. Thereafter, water was applied without tracers for an additional 64 days. Both water movement and tracer movement were monitored in the subsoil during infiltration and redistribution. The experimental results indicate that water and bromide moved fairly uniformly during infiltration and the bromide moved ahead of the tritium due to anion exclusion during redistribution. Comparisons between measurements and predictions made with a two-dimensional model show qualitative agreement for two of the three water content measurement planes. Model predictions of tritium and bromide transport were not as satisfactory. Measurements of both tritium and bromide show localized areas of high relative concentrations and a large downward motion of bromide relative to tritium during redistribution. While the simple deterministic model does show larger downward motions for bromide than for tritium during redistribution, it does not predict the high concentrations of solute observed during infiltration, nor can it predict the heterogeneous behavior observed for tritium during infiltration and for bromide during redistribution.

  1. Isotopological Relaxation, Coherent Structures, and Gaussian Turbulence in Two-Dimensional Magnetohydrodynamics

    CERN Document Server

    Isichenko, M B

    1994-01-01

    The long-time relaxation of ideal two dimensional magnetohydrodynamic turbulence subject to the conservation of two infinite families of constants of motion---the magnetic and the "cross" topology invariants--is examined. The analysis of the Gibbs ensemble, where all integrals of motion are respected, predicts the initial state to evolve into an equilibrium, stable coherent structure (the most probable state) and decaying Gaussian turbulence (fluctuations) with a vanishing, but always positive temperature. The non-dissipative turbulence decay is accompanied by decrease in both the amplitude and the length scale of the fluctuations, so that the fluctuation energy remains finite. The coherent structure represents a set of singular magnetic islands with plasma flow whose magnetic topology is identical to that of the initial state, while the energy and the cross topology invariants are shared between the coherent structure and the Gaussian turbulence. These conservation laws suggest the variational principle of i...

  2. Two-dimensional physical habitat modeling of effects of habitat structures on urban stream restoration

    Directory of Open Access Journals (Sweden)

    Dongkyun IM

    2011-12-01

    Full Text Available River corridors, even if highly modified or degraded, still provide important habitats for numerous biological species, and carry high aesthetic and economic values. One of the keys to urban stream restoration is recovery and maintenance of ecological flows sufficient to sustain aquatic ecosystems. In this study, the Hongje Stream in the Seoul metropolitan area of Korea was selected for evaluating a physically-based habitat with and without habitat structures. The potential value of the aquatic habitat was evaluated by a weighted usable area (WUA using River2D, a two-dimensional hydraulic model. The habitat suitability for Zacco platypus in the Hongje Stream was simulated with and without habitat structures. The computed WUA values for the boulder, spur dike, and riffle increased by about 2%, 7%, and 131%, respectively, after their construction. Also, the three habitat structures, especially the riffle, can contribute to increasing hydraulic heterogeneity and enhancing habitat diversity.

  3. Mode shape combination in a two-dimensional vibration energy harvester through mass loading structural modification

    Energy Technology Data Exchange (ETDEWEB)

    Sharpes, Nathan; Kumar, Prashant [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Abdelkefi, Abdessattar; Abdelmoula, Hichem [Department of Mechanical and Aerospace Engineering, New Mexico State University, Las Cruces, New Mexico 88003 (United States); Adler, Jan [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Institute of Dynamics and Vibration Research (IDS), Leibniz Universität, Hannover 30167 (Germany); Priya, Shashank [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Bio-Inspired Materials and Devices Laboratory (BMDL), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2016-07-18

    Mode shapes in the design of mechanical energy harvesters, as a means of performance increase, have been largely overlooked. Currently, the vast majority of energy harvester designs employ some variation of a single-degree-of-freedom cantilever, and the mode shapes of such beams are well known. This is especially true for the first bending mode, which is almost exclusively the chosen vibration mode for energy harvesting. Two-dimensional beam shapes (those which curve, meander, spiral, etc., in a plane) have recently gained research interest, as they offer freedom to modify the vibration characteristics of the harvester beam for achieving higher power density. In this study, the second bending mode shape of the “Elephant” two-dimensional beam shape is examined, and its interaction with the first bending mode is evaluated. A combinatory mode shape created by using mass loading structural modification to lower the second bending modal frequency was found to interact with the first bending mode. This is possible since the first two bending modes do not share common areas of displacement. The combined mode shape is shown to produce the most power of any of the considered mode shapes.

  4. Linear Two-Dimensional MHD of Accretion Disks: Crystalline structure and Nernst coefficient

    CERN Document Server

    Montani, Giovanni

    2009-01-01

    We analyse the two-dimensional MHD configurations characterising the steady state of the accretion disk on a highly magnetised neutron star. The model we describe has a local character and represents the extension of the crystalline structure outlined in Coppi (2005), dealing with a local model too, when a specific accretion rate is taken into account. We limit our attention to the linearised MHD formulation of the electromagnetic back-reaction characterising the equilibrium, by fixing the structure of the radial, vertical and azimuthal profiles. Since we deal with toroidal currents only, the consistency of the model is ensured by the presence of a small collisional effect, phenomenologically described by a non-zero constant Nernst coefficient (thermal power of the plasma). Such an effect provides a proper balance of the electron force equation via non zero temperature gradients, related directly to the radial and vertical velocity components. We show that the obtained profile has the typical oscillating feat...

  5. The Two-dimensional ElectromagneticScattering from Periodic Chiral Structures and Its Finite Element Approximation

    Institute of Scientific and Technical Information of China (English)

    张德悦; 马富明

    2004-01-01

    In this paper, we consider the electromagnetic scattering from periodic chiral structures. The structure is periodic in one direction and invariant in another direction. The electromagnetic fields in the chiral medium are governed by the Maxwell equations together with the Drude-Born-Fedorov equations. We simplify the problem to a two-dimensional scattering problem and we show that for all but possibly a discrete set of wave numbers, there is a unique quasi-periodic weak solution to the diffraction problem. The diffraction problem can be solved by finite element method. We also establish uniform error estimates for the finite element method and the error estimates when the truncation of the nonlocal transparent boundary operators takes place.

  6. Ordered quasi-two-dimensional structure of nanoparticles in semiflexible ring polymer brushes under compression

    Science.gov (United States)

    Hua, Yunfeng; Deng, Zhenyu; Jiang, Yangwei; Zhang, Linxi

    2017-06-01

    Molecular dynamics simulations of a coarse-grained bead-spring model of ring polymer brushes under compression are presented. Flexible polymer brushes are always disordered during compression, whereas semiflexible polymer brushes tend to be ordered under sufficiently strong compression. Further, the polymer monomer density of the semiflexible polymer brush is very high near the brush surface, inducing a peak value of the free energy near the surface. Therefore, when nanoparticles are compressed in semiflexible ring polymer brushes, they tend to exhibit a closely packed single-layer structure between the brush surface and the impenetrable wall, and a quasi-two-dimensional ordered structure near the brush surface is formed under strong compression. These findings provide a new approach to designing responsive applications.

  7. Two-dimensional silica: Structural, mechanical properties, and strain-induced band gap tuning

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Enlai; Xie, Bo [Applied Mechanics Laboratory, Department of Engineering Mechanics, and Center for Nano and Micro Mechanics, Tsinghua University, Beijing 100084 (China); Xu, Zhiping, E-mail: xuzp@tsinghua.edu.cn [Applied Mechanics Laboratory, Department of Engineering Mechanics, and Center for Nano and Micro Mechanics, Tsinghua University, Beijing 100084 (China); State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)

    2016-01-07

    Two-dimensional silica is of rising interests not only for its practical applications as insulating layers in nanoelectronics, but also as a model material to understand crystals and glasses. In this study, we examine structural and electronic properties of hexagonal and haeckelite phases of silica bilayers by performing first-principles calculations. We find that the corner-sharing SiO{sub 4} tetrahedrons in these two phases are locally similar. The robustness and resilience of these tetrahedrons under mechanical perturbation allow effective strain engineering of the electronic structures with band gaps covering a very wide range, from of that for insulators, to wide-, and even narrow-gap semiconductors. These findings suggest that the flexible 2D silica holds great promises in developing nanoelectronic devices with strain-tunable performance, and lay the ground for the understanding of crystalline and vitreous phases in 2D, where bilayer silica provides an ideal test-bed.

  8. Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions

    Science.gov (United States)

    Kajiro, Hiroshi; Kondo, Atsushi; Kaneko, Katsumi; Kanoh, Hirofumi

    2010-01-01

    Coordination polymers (CPs) or metal-organic frameworks (MOFs) have attracted considerable attention because of the tunable diversity of structures and functions. A 4,4′-bipyridine molecule, which is a simple, linear, exobidentate, and rigid ligand molecule, can construct two-dimensional (2D) square grid type CPs. Only the 2D-CPs with appropriate metal cations and counter anions exhibit flexibility and adsorb gas with a gate mechanism and these 2D-CPs are called elastic layer-structured metal-organic frameworks (ELMs). Such a unique property can make it possible to overcome the dilemma of strong adsorption and easy desorption, which is one of the ideal properties for practical adsorbents. PMID:21152303

  9. Structures and Dynamics of a Two-Dimensional Confined Dusty Plasma System

    Institute of Scientific and Technical Information of China (English)

    HUANG Feng; LIU Yan-Hong; WANG Long

    2005-01-01

    The influence of the confining potential strength and temperature on the structures and dynamics of a two-dimensional (2D) dusty plasma system is investigated through molecular dynamic (MD) simulation. The circular symmetric confining potential leads to the nonuniform packing of particles, that is, an inner core with a hexagon lattice surrounded by a few outer circular shells. Under the appropriate confining potential and temperature, the particle trajectories on middle shells form a series of concentric and nested hexagons due to tangential movements of particles.Mean square displacement, self-diffusion constant, pair correlation function, and the nearest bond are used to characterize the structural and dynamical properties of the system. With the increase of the confining potential, the radial and tangential movements of particles have different behaviors. With the increase of temperature, the radial and tangential motions strengthen, particle trajectories gradually become disordered, and the system gradually changes from a crystal or liquid state to a gas state.

  10. Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions

    Directory of Open Access Journals (Sweden)

    Hiroshi Kajiro

    2010-09-01

    Full Text Available Coordination polymers (CPs or metal-organic frameworks (MOFs have attracted considerable attention because of the tunable diversity of structures and functions. A 4,4'-bipyridine molecule, which is a simple, linear, exobidentate, and rigid ligand molecule, can construct two-dimensional (2D square grid type CPs. Only the 2D-CPs with appropriate metal cations and counter anions exhibit flexibility and adsorb gas with a gate mechanism and these 2D-CPs are called elastic layer-structured metal-organic frameworks (ELMs. Such a unique property can make it possible to overcome the dilemma of strong adsorption and easy desorption, which is one of the ideal properties for practical adsorbents.

  11. A humidity sensitive two-dimensional tunable amorphous photonic structure in the bivalve ligament of Meretrix linnaeus.

    Science.gov (United States)

    Zhang, Weigang; Zhang, Gangsheng

    2015-12-01

    A humidity sensitive two-dimensional tunable amorphous photonic structure (2D TAPS) in the bivalve ligament of Meretrix linnaeus (LML) was reported in this paper. The structural color and microstructure of LML were investigated by reflection spectra and scanning electron microscopy, respectively. The results indicate that the LML has complex structural colors from blue to orange in the wet state from ventral to dorsal, which are derived from the aragonite fiber diameter increases continuously from ventral to dorsal of the ligament. The reflection peak wavelength of the wet LML can blue-shift from 522 nm to 480 nm with the air drying time increased from 0 to 60 min, while the reflectivity decreases gradually and only a weak reflection peak at last, relevant color changes from green to light blue. The structural color in the LML is produced by a two-dimensional amorphous photonic structure consists of aligned aragonite fibers and proteins, in which the diameters of the aragonite fiber and the inter-fiber spacing are 104±11 nm and 126±16 nm, respectively. Water can reversibly tune the reflection peak wavelength and reflectivity of this photonic structure, and the regulation achieved through dynamically tune the degree of order and lattice constant of the ligament in the different wet states.

  12. Structural analysis of a dipole system in two-dimensional channels.

    Science.gov (United States)

    Haghgooie, Ramin; Doyle, Patrick S

    2004-12-01

    A system of magnetic dipoles in two-dimensional (2D) channels was studied using Brownian dynamics simulations. The dipoles interact with a purely repulsive r(-3) potential and are confined by two hard walls in one of the dimensions. Solid crystals were annealed in the 2D channels and the structural properties of the crystals were investigated. The long-ranged nature of the purely repulsive dipoles combined with the presence of hard walls led to structural deviations from the unbounded (infinite) 2D dipolar crystal. The structures in the channels were characterized by a high density of particles along the walls. The particles along the wall became increasingly localized as the channel width was increased. The spacing of the walls was important in determining the properties of the structures formed in the channel. Small changes in the width of the channel induced significant structural changes in the crystal. These structural changes were manifested in the density profiles, defect concentrations, and local bond-orientation order of the system. Oscillations in the structural properties were observed as the channel width was increased, indicating the existence of magic-number channel widths for this system. As the channel width was increased the properties of the confined system approached those of the unbounded system surprisingly slowly.

  13. Resolving molecular vibronic structure using high-sensitivity two-dimensional electronic spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Bizimana, Laurie A.; Brazard, Johanna; Carbery, William P.; Gellen, Tobias; Turner, Daniel B., E-mail: dturner@nyu.edu [Department of Chemistry, New York University, 100 Washington Square East, New York, New York 10003 (United States)

    2015-10-28

    Coherent multidimensional optical spectroscopy is an emerging technique for resolving structure and ultrafast dynamics of molecules, proteins, semiconductors, and other materials. A current challenge is the quality of kinetics that are examined as a function of waiting time. Inspired by noise-suppression methods of transient absorption, here we incorporate shot-by-shot acquisitions and balanced detection into coherent multidimensional optical spectroscopy. We demonstrate that implementing noise-suppression methods in two-dimensional electronic spectroscopy not only improves the quality of features in individual spectra but also increases the sensitivity to ultrafast time-dependent changes in the spectral features. Measurements on cresyl violet perchlorate are consistent with the vibronic pattern predicted by theoretical models of a highly displaced harmonic oscillator. The noise-suppression methods should benefit research into coherent electronic dynamics, and they can be adapted to multidimensional spectroscopies across the infrared and ultraviolet frequency ranges.

  14. Synthesis and structure of two-dimensional transition-metal dichalcogenides

    KAUST Repository

    Shi, Yumeng

    2015-07-13

    Two-dimensional (2D) transition-metal dichalcogenides (TMDCs) exhibit unique electrical, optical, thermal, and mechanical properties, which enable them to be used as building blocks in compact and lightweight integrated electronic systems. The controllable and reliable synthesis of atomically thin TMDCs is essential for their practical application. Recent progress in large-area synthesis of monolayer TMDCs paves the way for practical production of various 2D TMDC layers. The intrinsic optical and electrical properties of monolayer TMDCs can be defined by stoichiometry during synthesis. By manipulating the lattice structure or layer stacking manner, it is possible to create atomically thin van der Waals materials with unique and unexplored physical properties. In this article, we review recent developments in the synthesis of TMDC monolayers, alloys, and heterostructures, which shine light on the design of novel TMDCs with desired functional properties.

  15. Two-dimensional modeling of electrochemical and transport phenomena in the porous structures of a PEMFC

    Energy Technology Data Exchange (ETDEWEB)

    Sahraoui, Melik [Institut Preparatoire aux Etudes d' Ingenieurs de Tunis (IPEIT) (Tunisia); Kharrat, Chafik; Halouani, Kamel [UR: Micro-Electro-Thermal Systems (METS-ENIS), Industrial Energy Systems Group, Institut Preparatoire aux Etudes d' Ingenieurs de Sfax (IPEIS), University of Sfax, B.P: 1172, 3018 Sfax (Tunisia)

    2009-04-15

    A two-dimensional CFD model of PEM fuel cell is developed by taking into account the electrochemical, mass and heat transfer phenomena occurring in all of its regions simultaneously. The catalyst layers and membrane are each considered as distinct regions with finite thickness and calculated properties such as permeability, local protonic conductivity, and local dissolved water diffusion. This finite thickness model enables to model accurately the protonic current in these regions with higher accuracy than using an infinitesimal interface. In addition, this model takes into account the effect of osmotic drag in the membrane and catalyst layers. General boundary conditions are implemented in a way taking into consideration any given species concentration at the fuel cell inlet, such as water vapor which is a very important parameter in determining the efficiency of fuel cells. Other operating parameters such as temperature, pressure and porosity of the porous structure are also investigated to characterize their effect on the fuel cell efficiency. (author)

  16. Structure of the novel steroidal antibiotic squalamine determined by two-dimensional NMR spectroscopy.

    Science.gov (United States)

    Wehrli, S L; Moore, K S; Roder, H; Durell, S; Zasloff, M

    1993-08-01

    Squalamine is a novel aminosterol recently isolated from the dogfish shark, Squalus acanthias. This water-soluble steroid exhibits potent antibacterial activity against both gram-negative and gram-positive bacteria. In addition, squalamine is fungicidal and induces osmotic lysis of protozoa. We report here the structural determination of squalamine, 3 beta-N-1-[N(3-[4-aminobutyl])-1,3 diaminopropane]-7 alpha,24 zeta-dihydroxy-5 alpha-cholestane 24-sulfate, which was deduced from the analysis of fast atom bombardment spectra and a series of two-dimensional nuclear magnetic resonance (NMR) spectra. Squalamine is a cationic steroid characterized by a condensation of an anionic bile salt intermediate with the polyamine, spermidine. This molecule is a potential host-defense agent in the shark, and provides insight into a new class of vertebrate antimicrobial molecules.

  17. Two-dimensional crystallization and preliminary electron crystallographic result of partially purified Fo from porcine mitochondria

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    After removal of cytoplasmic sector F1 from submitochondrial particles of FoF1-ATP synthase complex with guanidine hydrochloride, the transmembrane sector Fo was specifically extracted from the stripped membranes in the presence of detergent CHAPS and partially purified.Two-dimensional crystals were produced by the reconstitution of the partially purified Fo into asolectin and microdialysis. The obtained crystals are able to diffract to 2 nm. The projection map of the negatively stained crystal shows that the crystal has p4212 symmetry, lattice constant, a = b = 14.4nm. A unit cell contains four Fo molecules.

  18. A humidity sensitive two-dimensional tunable amorphous photonic structure in the outer layer of bivalve ligament from Sunset Siliqua.

    Science.gov (United States)

    Zhang, Weigang; Zhang, Gangsheng

    2015-01-01

    A humidity sensitive two-dimensional tunable amorphous photonic structure (2D TAPS) in the outer layer of bivalve ligament from Sunset Siliqua (OLLS) was reported in this paper. The structural color and microstructure of OLLS were investigated by reflection spectra and scanning electron microscopy, respectively. The results indicate that the reflection peak wavelength of the wet OLLS blue-shifts from 454 nm to 392 nm with the increasing of air drying time from 0 to 40 min, while the reflectivity decreases gradually and vanishes at last, relevant color changes from blue to black background color. The structural color in the OLLS is produced by a two-dimensional amorphous photonic structure consisting of aligned protein fibers, in which the diameter of protein fiber and the inter-fiber spacing are 101 ± 12 nm. Water can reversibly tune the reflection peak wavelength and reflectivity of this photonic structure, and the regulation achieved through dynamically tuning the interaction between inter-fiber spacing and average refractive index.

  19. Analytical and Numerical Calculations of Two-Dimensional Dielectric Photonic Band Gap Structures and Cavities for Laser Acceleration

    CERN Document Server

    Samokhvalova, Ksenia R; Liang Qian, Bao

    2005-01-01

    Dielectric photonic band gap (PBG) structures have many promising applications in laser acceleration. For these applications, accurate determination of fundamental and high order band gaps is critical. We present the results of our recent work on analytical calculations of two-dimensional (2D) PBG structures in rectangular geometry. We compare the analytical results with computer simulation results from the MIT Photonic Band Gap Structure Simulator (PBGSS) code, and discuss the convergence of the computer simulation results to the analytical results. Using the accurate analytical results, we design a mode-selective 2D dielectric cylindrical PBG cavity with the first global band gap in the frequency range of 8.8812 THz to 9.2654 THz. In this frequency range, the TM01-like mode is shown to be well confined.

  20. The spin structure of the proton at low $x$ and low $Q^2$ in two-dimensional bins from COMPASS

    CERN Document Server

    Nunes, A.S.

    2016-01-01

    The longitudinal double spin asymmetries $A_1^p$ and the spin dependent structure function of the proton $g_1^p$ were extracted from COMPASS data in the region of low Bjorken scaling variable $x$ and low photon virtuality $Q^2$. The data were taken in 2007 and 2011 from scattering of polarised muons off polarised protons, resulting in a sample that is 150 times larger than the one from the previous experiment SMC that pioneered studies in this kinematic region. For the first time, $A_1^p$ and $g_1^p$ were evaluated in this region in two-dimensional bins of kinematic variables: $(x,Q^2)$, $(\

  1. Structure analysis of aromatic medicines containing nitrogen using near-infrared spectroscopy and generalized two-dimensional correlation spectroscopy

    Science.gov (United States)

    Liu, Hao; Gao, Hongbin; Qu, Lingbo; Huang, Yanping; Xiang, Bingren

    2008-12-01

    Four aromatic medicines (acetaminophen; niacinamide; p-aminophenol; nicotinic acid) containing nitrogen were investigated by FT-NIR (Fourier transform near-infrared) spectroscopy and generalized two-dimensional (2D) correlation spectroscopy. The FT-NIR spectra were measured over a temperature range of 30-130 °C. By combining near-infrared spectroscopy, generalized 2D correlation spectroscopy and references, the molecular structures (especially the hydrogen bond related with nitrogen) were analyzed and the NIR band assignments were performed. The results will be helpful to the understanding of aromatic medicines containing nitrogen and the utility of these substances.

  2. Negative refraction and imaging of acoustic waves in a two-dimensional square chiral lattice structure

    Science.gov (United States)

    Zhao, Sheng-Dong; Wang, Yue-Sheng

    2016-05-01

    The negative refraction behavior and imaging effect for acoustic waves in a kind of two-dimensional square chiral lattice structure are studied in this paper. The unit cell of the proposed structure consists of four zigzag arms connected through a thin circular ring at the central part. The relation of the symmetry of the unit cell and the negative refraction phenomenon is investigated. Using the finite element method, we calculate the band structures and the equi-frequency surfaces of the system, and confirm the frequency range where the negative refraction is present. Due to the rotational symmetry of the unit cell, a phase difference is induced to the waves propagating from a point source through the structure to the other side. The phase difference is related to the width of the structure and the frequency of the source, so we can get a tunable deviated imaging. This kind of phenomenon is also demonstrated by the numerical simulation of two Gaussian beams that are symmetrical about the interface normal with the same incident angle, and the different negative refractive indexes are presented. Based on this special performance, a double-functional mirror-symmetrical slab is proposed for realizing acoustic focusing and beam separation.

  3. Disparate Strain Dependent Thermal Conductivity of Two-dimensional Penta-Structures.

    Science.gov (United States)

    Liu, Huake; Qin, Guangzhao; Lin, Yuan; Hu, Ming

    2016-06-08

    Two-dimensional (2D) carbon allotrope called penta-graphene was recently proposed from first-principles calculations and various similar penta-structures emerged. Despite significant effort having been dedicated to electronic structures and mechanical properties, little research has been focused on thermal transport in penta-structures. Motivated by this, we performed a comparative study of thermal transport properties of three representative pentagonal structures, namely penta-graphene, penta-SiC2, and penta-SiN2, by solving the phonon Boltzmann transport equation with interatomic force constants extracted from first-principles calculations. Unexpectedly, the thermal conductivity of the three penta-structures exhibits diverse strain dependence, despite their very similar geometry structures. While the thermal conductivity of penta-graphene exhibits standard monotonic reduction by stretching, penta-SiC2 possesses an unusual nonmonotonic up-and-down behavior. More interestingly, the thermal conductivity of penta-SiN2 has 1 order of magnitude enhancement due to the strain induced buckled to planar structure transition. The mechanism governing the diverse strain dependence is identified as the competition between the change of phonon group velocity and phonon lifetime of acoustic phonon modes with combined effect from the unique structure transition for penta-SiN2. The disparate thermal transport behavior is further correlated to the fundamentally different bonding nature in the atomic structures with solid evidence from the distribution of deformation charge density and more in-depth molecular orbital analysis. The reported giant and robust tunability of thermal conductivity may inspire intensive research on other derivatives of penta-structures as potential materials for emerging nanoelectronic devices. The fundamental physics understood from this study also solidifies the strategy to engineer thermal transport properties of broad 2D materials by simple mechanical

  4. Two-dimensional colloidal crystal assisted formation of conductive porous gold films with flexible structural controllability.

    Science.gov (United States)

    Lu, Zhicheng; Liu, Chen; Han, Heyou

    2015-01-01

    Two-dimensional (2D) colloidal crystals of polystyrene (PS) particles were used as a structure-controlling template to fabricate conductive Au films with an ordered array of nanoholes. The fabrication mainly involved the functionalization of the supporting substrate with polyelectrolyte (PE) functional layers, self-assembly of Au nanoparticles, and electroless deposition of gold. The self-assembly of Au nanoparticles and electroless deposition of gold were macroscopically monitored using ultraviolet-visible (UV-vis) spectroscopy based on the changes in both the extinction spectra of Au nanoparticles and the optical responses of ordered arrays of PS particles. By scanning electron microscopy (SEM) characterization, it was found that Au nanoparticles were assembled into a film structure with orderly dispersed nanoholes and the deposition of gold was confined to the preformed Au nanoparticle films. During the formation of Au films, PE layer structure, Au nanoparticle size and heating treatment applied to the PS template could influence the structures of conductive porous Au films such as the hole diameter, film thickness, and hole diameter/wall thickness ratio (D/W). In addition, this paper also described electrochemical cyclic voltammetry (CV) employed to demonstrate the porosity of the ultimate Au films.

  5. Structural semiconductor-to-semimetal phase transition in two-dimensional materials induced by electrostatic gating.

    Science.gov (United States)

    Li, Yao; Duerloo, Karel-Alexander N; Wauson, Kerry; Reed, Evan J

    2016-01-01

    Dynamic control of conductivity and optical properties via atomic structure changes is of technological importance in information storage. Energy consumption considerations provide a driving force towards employing thin materials in devices. Monolayer transition metal dichalcogenides are nearly atomically thin materials that can exist in multiple crystal structures, each with distinct electrical properties. By developing new density functional-based methods, we discover that electrostatic gating device configurations have the potential to drive structural semiconductor-to-semimetal phase transitions in some monolayer transition metal dichalcogenides. Here we show that the semiconductor-to-semimetal phase transition in monolayer MoTe2 can be driven by a gate voltage of several volts with appropriate choice of dielectric. We find that the transition gate voltage can be reduced arbitrarily by alloying, for example, for Mo(x)W(1-x)Te2 monolayers. Our findings identify a new physical mechanism, not existing in bulk materials, to dynamically control structural phase transitions in two-dimensional materials, enabling potential applications in phase-change electronic devices.

  6. A novel approach for structure analysis of two-dimensional membrane protein crystals using x-ray powder diffraction data

    CERN Document Server

    Dilanian, Ruben A; Varghese, Jose N; Wilkins, Steve W; Oka, Toshihiko; Yagi, Naoto; Quiney, Harry M; Nugent, Keith A

    2010-01-01

    The application of powder diffraction methods in two-dimensional crystallography is regarded as intractable because of the uncertainties associated with overlapping reflections. Here, we report an approach that resolves these ambiguities and provides reliable low-resolution phase information directly from powder diffraction data. We apply our method to the recovery of the structure of the bacteriorhodopsin (bR) molecule to a resolution of 7 angstroms using only powder diffraction data obtained from two-dimensional purple membrane (PM) crystals.

  7. Laboratory setup and results of experiments on two-dimensional multiphase flow in porous media

    Energy Technology Data Exchange (ETDEWEB)

    McBride, J.F. (ed.) (Pacific Northwest Lab., Richland, WA (USA)); Graham, D.N. (ed.); Schiegg, H.O. (SIMULTEC Ltd., Meilen/Zurich (Switzerland))

    1990-10-01

    In the event of an accidental release into earth's subsurface of an immiscible organic liquid, such as a petroleum hydrocarbon or chlorinated organic solvent, the spatial and temporal distribution of the organic liquid is of great interest when considering efforts to prevent groundwater contamination or restore contaminated groundwater. An accurate prediction of immiscible organic liquid migration requires the incorporation of relevant physical principles in models of multiphase flow in porous media; these physical principles must be determined from physical experiments. This report presents a series of such experiments performed during the 1970s at the Swiss Federal Institute of Technology (ETH) in Zurich, Switzerland. The experiments were designed to study the transient, two-dimensional displacement of three immiscible fluids in a porous medium. This experimental study appears to be the most detailed published to date. The data obtained from these experiments are suitable for the validation and test calibration of multiphase flow codes. 73 refs., 140 figs.

  8. The band gap variation of a two dimensional binary locally resonant structure in thermal environment

    Science.gov (United States)

    Li, Zhen; Wang, Xian; Li, Yue-ming

    2017-01-01

    In this study, the numerical investigation of thermal effect on band gap dynamical characteristic for a two-dimensional binary structure composed of aluminum plate periodically filled with nitrile rubber cylinder is presented. Initially, the band gap of the binary structure variation trend with increasing temperature is studied by taking the softening effect of thermal stress into account. A breakthrough is made which found the band gap being narrower and shifting to lower frequency in thermal environment. The complete band gap which in higher frequency is more sensitive to temperature that it disappears with temperature increasing. Then some new transformed models are created by changing the height of nitrile rubber cylinder from 1mm to 7mm. Simulations show that transformed model can produce a wider band gap (either flexure or complete band gap). A proper forbidden gap of elastic wave can be utilized in thermal environment although both flexure and complete band gaps become narrower with temperature. Besides that, there is a zero-frequency flat band appearing in the first flexure band, and it becomes broader with temperature increasing. The band gap width decreases trend in thermal environment, as well as the wider band gap induced by the transformed model with higher nitrile rubber cylinder is useful for the design and application of phononic crystal structures in thermal environment.

  9. The band gap variation of a two dimensional binary locally resonant structure in thermal environment

    Directory of Open Access Journals (Sweden)

    Zhen Li

    2017-01-01

    Full Text Available In this study, the numerical investigation of thermal effect on band gap dynamical characteristic for a two-dimensional binary structure composed of aluminum plate periodically filled with nitrile rubber cylinder is presented. Initially, the band gap of the binary structure variation trend with increasing temperature is studied by taking the softening effect of thermal stress into account. A breakthrough is made which found the band gap being narrower and shifting to lower frequency in thermal environment. The complete band gap which in higher frequency is more sensitive to temperature that it disappears with temperature increasing. Then some new transformed models are created by changing the height of nitrile rubber cylinder from 1mm to 7mm. Simulations show that transformed model can produce a wider band gap (either flexure or complete band gap. A proper forbidden gap of elastic wave can be utilized in thermal environment although both flexure and complete band gaps become narrower with temperature. Besides that, there is a zero-frequency flat band appearing in the first flexure band, and it becomes broader with temperature increasing. The band gap width decreases trend in thermal environment, as well as the wider band gap induced by the transformed model with higher nitrile rubber cylinder is useful for the design and application of phononic crystal structures in thermal environment.

  10. A new structure of two-dimensional allotropes of group V elements

    Science.gov (United States)

    Li, Ping; Luo, Weidong

    2016-05-01

    The elemental two-dimensional (2D) materials such as graphene, silicene, germanene, and black phosphorus have attracted considerable attention due to their fascinating physical properties. Structurally they possess the honeycomb or distorted honeycomb lattices, which are composed of six-atom rings. Here we find a new structure of 2D allotropes of group V elements composed of eight-atom rings, which we name as the octagonal tiling (OT) structure. First-principles calculations indicate that these allotropes are dynamically stable and are also thermally stable at temperatures up to 600 K. These allotropes are semiconductors with band gaps ranging from 0.3 to 2.0 eV, thus they are potentially useful in near- and mid-infrared optoelectronic devices. OT-Bi is also a 2D topological insulator (TI) with a band gap of 0.33 eV, which is the largest among the reported elemental 2D TIs, and this gap can be increased further by applying compressive strains.

  11. Effect of solvent evaporation temperature on the structure of two-dimensional melamine networks on Au(111)

    Science.gov (United States)

    Okada, Arifumi; Nakata, Yohei; Minou, Kosuke; Yoshimura, Masamichi; Kadono, Kohei

    2016-12-01

    By scanning tunneling microscopy (STM), we investigated two-dimensional (2D) structures of melamine formed on Au(111) surfaces by solvent evaporation. By increasing the evaporation temperature, the well-known ordered honeycomb 2D molecular phase, in which all molecules are linked by hydrogen bonding, changes to four coexisting phases, i.e., a 2D network consisting of linear segments, 1D molecular rows, and hexagonal and distorted hexagonal structures. The first two phases are sometimes observed in ultrahigh vacuum (UHV) on metallic substrates other than Au. The last two phases have lattice parameters close to those of the well-known honeycomb structure. The structural change observed in this study is attributed to local temperature and concentration distributions of the solution and substrate surface during solvent evaporation. From the results, we found that the molecular nanostructures can be tailored by the solvent evaporation method with small changes in temperature.

  12. Axis and velocity determination for quasi two-dimensional plasma/field structures from Faraday's law: A second look

    Science.gov (United States)

    Sonnerup, Bengt U. Ö.; Denton, Richard E.; Hasegawa, Hiroshi; Swisdak, M.

    2013-05-01

    We re-examine the basic premises of a single-spacecraft data analysis method, developed by Sonnerup and Hasegawa (2005), for determining the axis orientation and proper frame velocity of quasi two-dimensional, quasi-steady structures of magnetic field and plasma. The method, which is based on Faraday's law, makes use of magnetic and electric field data measured by a single spacecraft traversing the structure, although in many circumstances the convection electric field, - v × B, can serve as a proxy for E. It has been used with success for flux ropes observed at the magnetopause but has usually failed to provide acceptable results when applied to real space data from reconnection events as well as to virtual data from numerical MHD simulations of such events. In the present paper, the reasons for these shortcomings are identified, analyzed, and discussed in detail. Certain basic properties of the method are presented in the form of five theorems, the last of which makes use of singular value decomposition to treat the special case where the magnetic variance matrix is non-invertible. These theorems are illustrated using data from analytical models of flux ropes and also from MHD simulations as well as a 2-D kinetic simulation of reconnection. The results make clear that the method requires the presence of a significant, non-removable electric field distribution in the plane transverse to the invariant direction and that it is sensitive to deviations from strict two-dimensionality and strict time stationarity.

  13. Spatially structured oscillations in a two-dimensional excitatory neuronal network with synaptic depression

    KAUST Repository

    Kilpatrick, Zachary P.

    2009-10-29

    We study the spatiotemporal dynamics of a two-dimensional excitatory neuronal network with synaptic depression. Coupling between populations of neurons is taken to be nonlocal, while depression is taken to be local and presynaptic. We show that the network supports a wide range of spatially structured oscillations, which are suggestive of phenomena seen in cortical slice experiments and in vivo. The particular form of the oscillations depends on initial conditions and the level of background noise. Given an initial, spatially localized stimulus, activity evolves to a spatially localized oscillating core that periodically emits target waves. Low levels of noise can spontaneously generate several pockets of oscillatory activity that interact via their target patterns. Periodic activity in space can also organize into spiral waves, provided that there is some source of rotational symmetry breaking due to external stimuli or noise. In the high gain limit, no oscillatory behavior exists, but a transient stimulus can lead to a single, outward propagating target wave. © Springer Science + Business Media, LLC 2009.

  14. Interfacial engineering of two-dimensional nano-structured materials by atomic layer deposition

    Science.gov (United States)

    Zhuiykov, Serge; Kawaguchi, Toshikazu; Hai, Zhenyin; Karbalaei Akbari, Mohammad; Heynderickx, Philippe M.

    2017-01-01

    Atomic Layer Deposition (ALD) is an enabling technology which provides coating and material features with significant advantages compared to other existing techniques for depositing precise nanometer-thin two-dimensional (2D) nanostructures. It is a cyclic process which relies on sequential self-terminating reactions between gas phase precursor molecules and a solid surface. ALD is especially advantageous when the film quality or thickness is critical, offering ultra-high aspect ratios. ALD provides digital thickness control to the atomic level by depositing film one atomic layer at a time, as well as pinhole-free films even over a very large and complex areas. Digital control extends to sandwiches, hetero-structures, nano-laminates, metal oxides, graded index layers and doping, and it is perfect for conformal coating and challenging 2D electrodes for various functional devices. The technique's capabilities are presented on the example of ALD-developed ultra-thin 2D tungsten oxide (WO3) over the large area of standard 4" Si substrates. The discussed advantages of ALD enable and endorse the employment of this technique for the development of hetero-nanostructure 2D semiconductors with unique properties.

  15. Experimental Observation of Exact Coherent Structures in a Weakly Turbulent Quasi-Two-Dimensional Flow

    Science.gov (United States)

    Suri, Balachandra; Tithof, Jeffrey; Pallantla, Ravi Kumar; Grigoriev, Roman; Schatz, Michael

    2015-11-01

    The dynamical systems approach to fluid turbulence relies on understanding the role of unstable, non-chaotic solutions - such as equilibria, traveling waves, and periodic orbits - of the Navier-Stokes equations. These solutions, called Exact Coherent Structures, exist in the same parameter regime as turbulence, but being unstable, are observed in experiments only as short transients. In this talk, we present experimental evidence for the existence and dynamical relevance of unstable equilibria in a weakly turbulent quasi-two-dimensional (Q2D) Kolmogorov flow. In the experiment, this Q2D flow is generated in an electromagnetically driven shallow layer of electrolyte. The numerical simulations, however, use a strictly 2D model which incorporates the effects of the finite thickness of the fluid layer in the experiment. During its evolution, there are instances when the dynamics of a weakly turbulent flow slow down, rather dramatically. Using experimental flow fields from such instances, and by means of a Newton-Solver, we numerically compute several unstable equilibria. Additionally, using numerical simulations, we show that the dynamics of a turbulent flow in the neighbourhood of an equilibrium are accurately described by the unstable manifold of the equilibrium. This work is supported in part by the National Science Foundation under grants CBET-0900018, and CMMI-1234436.

  16. Hamiltonian structure for two-dimensional extended Green-Naghdi equations

    Science.gov (United States)

    Matsuno, Yoshimasa

    2016-06-01

    The two-dimensional Green-Naghdi (GN) shallow-water model for surface gravity waves is extended to incorporate the arbitrary higher-order dispersive effects. This can be achieved by developing a novel asymptotic analysis applied to the basic nonlinear water wave problem. The linear dispersion relation for the extended GN system is then explored in detail. In particular, we use its characteristics to discuss the well-posedness of the linearized problem. As illustrative examples of approximate model equations, we derive a higher-order model that is accurate to the fourth power of the dispersion parameter in the case of a flat bottom topography, and address the related issues such as the linear dispersion relation, conservation laws and the pressure distribution at the fluid bottom on the basis of this model. The original Green-Naghdi (GN) model is then briefly described in the case of an uneven bottom topography. Subsequently, the extended GN system presented here is shown to have the same Hamiltonian structure as that of the original GN system. Last, we demonstrate that Zakharov's Hamiltonian formulation of surface gravity waves is equivalent to that of the extended GN system by rewriting the former system in terms of the momentum density instead of the velocity potential at the free surface.

  17. Coherent Structures in Turbulent Flow over Two-Dimensional River Dunes

    CERN Document Server

    Omidyeganeh, Mohammad

    2011-01-01

    We performed large-eddy simulations of the flow over a typical two-dimensional dune geometry at laboratory scale (the Reynolds number based on the average channel height and mean velocity is 18,900) using the Lagrangian dynamic eddy-viscosity subgrid-scale model. The flow separates at the dune crest and reattaches downstream on the bed (at x=5.7h). A favorable pressure gradient accelerates the flow over the stoss-side (the upward-sloping region for x > 8h) and an unfavorable gradient for x < 8h decelerates the flow over the lee-side of the dune. Due to the separation of the flow, a shear layer is generated after the crest that expands in the wake region towards the next dune. The outer-layer turbulence structures are visualized through isosurfaces of pressure fluctuations colored by distance to the surface. Spanwise vortices are generated in the shear layer separating from the crest due to the Kelvin-Helmholtz instability. They are convected downstream and either interact with the wall or rise to the surfa...

  18. White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites.

    Science.gov (United States)

    Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C; Wasielewski, Michael R; Kanatzidis, Mercouri G

    2017-03-29

    Hybrid inorganic-organic perovskites are developing rapidly as high performance semiconductors. Recently, two-dimensional (2D) perovskites were found to have white-light, broadband emission in the visible range that was attributed mainly to the role of self-trapped excitons (STEs). Here, we describe three new 2D lead bromide perovskites incorporating a series of bifunctional ammonium dications as templates which also emit white light: (1) α-(DMEN)PbBr4 (DMEN = 2-(dimethylamino)ethylamine), which adopts a unique corrugated layered structure in space group Pbca with unit cell a = 18.901(4) Å, b = 11.782(2) Å, and c = 23.680(5) Å; (2) (DMAPA)PbBr4 (DMAPA = 3-(dimethylamino)-1-propylamine), which crystallizes in P21/c with a = 10.717(2) Å, b = 11.735(2) Å, c = 12.127(2) Å, and β = 111.53(3)°; and (3) (DMABA)PbBr4 (DMABA = 4-dimethylaminobutylamine), which adopts Aba2 with a = 41.685(8) Å, b = 23.962(5) Å, and c = 12.000(2) Å. Photoluminescence (PL) studies show a correlation between the distortion of the "PbBr6" octahedron in the 2D layer and the broadening of PL emission, with the most distorted structure having the broadest emission (183 nm full width at half-maximum) and longest lifetime (τavg = 1.39 ns). The most distorted member α-(DMEN)PbBr4 exhibits white-light emission with a color rendering index (CRI) of 73 which is similar to a fluorescent light source and correlated color temperature (CCT) of 7863 K, producing "cold" white light.

  19. Simultaneous two-color, two-dimensional angular optical scattering patterns from airborne particulates: Scattering results and exploratory analysis

    Science.gov (United States)

    Holler, Stephen; Fuerstenau, Stephen D.; Skelsey, Charles R.

    2016-07-01

    Light scattering from non-spherical particles and aggregates exhibits complex structure that is revealed only when observed in two angular dimensions (θ, ϕ). However, due to variations in shape, packing, and orientation of such aerosols, the structure of two-dimensional angular optical scattering (TAOS) patterns varies among particles. The spectral dependence of scattering contributes further to the observed complexity, but offers another facet to consider. By leveraging multispectral TAOS data from flowing aerosols, we have identified novel morphological descriptors that may be employed in multivariate statistical algorithms for "unknown" particle classification.

  20. Structuring Au nanoparticles on two-dimensional MoS2 nanosheets for electrochemical glucose biosensors.

    Science.gov (United States)

    Parlak, Onur; İncel, Anıl; Uzun, Lokman; Turner, Anthony P F; Tiwari, Ashutosh

    2017-03-15

    Two-dimensional (2D) bioelectronics is an emerging field of research which fuses the advantages of 2D nanomaterials with those of nanobiotechnology. Due to the various physical and chemical properties present in layered counterparts of 2D materials, including high charge density, large surface area, remarkable electron mobility, ready electron transport, sizeable band gaps and ease of hybridisation, they are set to become a versatile tool to fabricate sensitive and selective novel biodevices, which might offer an unique advantages to tackle key energy, medical and environmental issues. Current 2D bioelectronics research is focused on the design of simple-to-use and cheaper biodevices, while improving their selectivity, sensitivity and stability. However, current designs generally suffer from a lack of efficiency, relatively low sensitivity, slow electron transfer kinetics, high background charging current and low current density arising from poor mass transport. Here, we report a nanoparticle-structured MoS2 nanosheet as an ideal semiconductor interface, which is able to form a homogenous layer on the electrode surface for the assembly of gold nanoparticles. This not only enhances electrocatalytic reactions, but also provides excellent electrochemical properties such as high faradic-to-capacitive current ratios, high current density and electron mobility, and faster mass transport, due to the dominance of radial diffusion. The MoS2/Au NPs/GOx bioelectrode exhibits a linear response to glucose from 0.25 to 13.2mM, with a detection limit of 0.042µM (S/N=3) and sensitivity of 13.80µA/µM/cm(2).

  1. Tuning the electronic structures and magnetism of two-dimensional porous C2N via transition metal embedding.

    Science.gov (United States)

    Du, Juan; Xia, Congxin; Xiong, Wenqi; Zhao, Xu; Wang, Tianxing; Jia, Yu

    2016-08-10

    Based on first-principles calculations, the electronic structures and magnetism are investigated in 3d transition metal (TM)-embedded porous two-dimensional (2D) C2N monolayers. Numerical results indicate that except Mn and Co atoms, other TM atoms can be embedded stably in the 2D C2N monolayer. Moreover, the magnetic moments of the TM-embedded C2N monolayer depend highly on the atomic number of the TM atoms. The Sc, Ti, V, Cr, Mn, Fe, Co and Ni atom-embedded C2N monolayers possess a ferromagnetic ground state, while embedding Cu can induce paramagnetic characteristics in the 2D C2N monolayer. Meanwhile, the Zn-embedded C2N monolayer exhibits a nonmagnetic ground state. These results indicate that the magnetism of 2D C2N monolayers can be tuned via embedding TM atoms.

  2. Dipeptide Structural Analysis Using Two-Dimensional NMR for the Undergraduate Advanced Laboratory

    Science.gov (United States)

    Gonzalez, Elizabeth; Dolino, Drew; Schwartzenburg, Danielle; Steiger, Michelle A.

    2015-01-01

    A laboratory experiment was developed to introduce students in either an organic chemistry or biochemistry lab course to two-dimensional nuclear magnetic resonance (2D NMR) spectroscopy using simple biomolecules. The goal of this experiment is for students to understand and interpret the information provided by a 2D NMR spectrum. Students are…

  3. Dipeptide Structural Analysis Using Two-Dimensional NMR for the Undergraduate Advanced Laboratory

    Science.gov (United States)

    Gonzalez, Elizabeth; Dolino, Drew; Schwartzenburg, Danielle; Steiger, Michelle A.

    2015-01-01

    A laboratory experiment was developed to introduce students in either an organic chemistry or biochemistry lab course to two-dimensional nuclear magnetic resonance (2D NMR) spectroscopy using simple biomolecules. The goal of this experiment is for students to understand and interpret the information provided by a 2D NMR spectrum. Students are…

  4. Free energy and structure of dislocation cores in two-dimensional crystals

    NARCIS (Netherlands)

    Bladon, P.B.; Frenkel, D.

    2004-01-01

    The nature of the melting transition in two dimensions is critically dependent on the core energy of dislocations. In this paper, we report calculations of the core free energy and the core size of dislocations in two-dimensional solids of systems interacting via square well, hard disk, and r-12

  5. Geometrical approach in physical understanding of the Goos-Haenchen shift in one- and two-dimensional periodic structures.

    Science.gov (United States)

    Miri, Mehdi; Naqavi, Ali; Khavasi, Amin; Mehrany, Khashayar; Khorasani, Sina; Rashidian, Bizhan

    2008-12-15

    The Goos-Haenchen shift of a totally reflected beam at the planar interface of two dielectric media, as if the incident beam is reflected from beneath the interface between the incident and transmitted media, has been geometrically associated with the penetration of the incident photons in the less-dense forbidden transmission region. This geometrical approach is here generalized to analytically calculate the Goos-Haenchen shift in one- and two-dimensional periodic structures. Several numerical examples are presented, and the obtained results are successfully tested against the well-known Artman's formula. The proposed approach is shown to be a fast, simple, and efficient method that can provide good physical insight to the nature of the phenomenon.

  6. Generalized two-dimensional correlation near-infrared spectroscopy and principal component analysis of the structures of methanol and ethanol

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Liquid state methanol and ethanol under different temperatures have been investigated by FT-NIR(Fourier transform nearinfrared) spectroscopy,generalized two-dimensional(2D) correlation spectroscopy,and PCA(principal component analysis) . First,the FT-NIR spectra were measured over a temperature range of 30-64(or 30-71) °C,and then the 2D correlation spectra were computed.Combining near-infrared spectroscopy,generalized 2D correlation spectroscopy,and references,we analyzed the molecular structures(especially the hydrogen bond) of methanol and ethanol,and performed the NIR band assignments. The PCA method was employed to verify the results of the 2D analysis.This study will be helpful to the understanding of these reagents.

  7. Assessment of the micro-structure and depletion potentials in two-dimensional binary mixtures of additive hard-disks

    Science.gov (United States)

    Perera-Burgos, Jorge Adrián; Méndez-Alcaraz, José Miguel; Pérez-Ángel, Gabriel; Castañeda-Priego, Ramón

    2016-09-01

    Depletion forces are a particular class of effective interactions that have been mainly investigated in binary mixtures of hard-spheres in bulk. Although there are a few contributions that point toward the effects of confinement on the depletion potential, little is known about such entropic potentials in two-dimensional colloidal systems. From theoretical point of view, the problem resides in the fact that there is no general formulation of depletion forces in arbitrary dimensions and, typically, any approach that works well in three dimensions has to be reformulated for lower dimensionality. However, we have proposed a theoretical framework, based on the formalism of contraction of the description within the integral equations theory of simple liquids, to account for effective interactions in colloidal liquids, whose main feature is that it does not need to be readapted to the problem under consideration. We have also shown that such an approach allows one to determine the depletion pair potential in three-dimensional colloidal mixtures even near to the demixing transition, provided the bridge functions are sufficiently accurate to correctly describe the spatial correlation between colloids [E. López-Sánchez et al., J. Chem. Phys. 139, 104908 (2013)]. We here report an extensive analysis of the structure and the entropic potentials in binary mixtures of additive hard-disks. In particular, we show that the same functional form of the modified-Verlet closure relation used in three dimensions can be straightforwardly employed to obtain an accurate solution for two-dimensional colloidal mixtures in a wide range of packing fractions, molar fractions, and size asymmetries. Our theoretical results are explicitly compared with the ones obtained by means of event-driven molecular dynamics simulations and recent experimental results. Furthermore, to assess the accuracy of our predictions, the depletion potentials are used in an effective one-component model to reproduce

  8. Phase quality map based on local multi-unwrapped results for two-dimensional phase unwrapping.

    Science.gov (United States)

    Zhong, Heping; Tang, Jinsong; Zhang, Sen

    2015-02-01

    The efficiency of a phase unwrapping algorithm and the reliability of the corresponding unwrapped result are two key problems in reconstructing the digital elevation model of a scene from its interferometric synthetic aperture radar (InSAR) or interferometric synthetic aperture sonar (InSAS) data. In this paper, a new phase quality map is designed and implemented in a graphic processing unit (GPU) environment, which greatly accelerates the unwrapping process of the quality-guided algorithm and enhances the correctness of the unwrapped result. In a local wrapped phase window, the center point is selected as the reference point, and then two unwrapped results are computed by integrating in two different simple ways. After the two local unwrapped results are computed, the total difference of the two unwrapped results is regarded as the phase quality value of the center point. In order to accelerate the computing process of the new proposed quality map, we have implemented it in a GPU environment. The wrapped phase data are first uploaded to the memory of a device, and then the kernel function is called in the device to compute the phase quality in parallel by blocks of threads. Unwrapping tests performed on the simulated and real InSAS data confirm the accuracy and efficiency of the proposed method.

  9. Efficient Two-Dimensional Direction Finding via Auxiliary-Variable Manifold Separation Technique for Arbitrary Array Structure

    Directory of Open Access Journals (Sweden)

    Guang Hua

    2015-01-01

    Full Text Available A polynomial rooting direction of arrival (DOA algorithm for multiple plane waves incident on an arbitrary array structure that combines the multipolynomial resultants and matrix computations is proposed in this paper. Firstly, a new auxiliary-variable manifold separation technique (AV-MST is used to model the steering vector of arbitrary array structure as the product of a sampling matrix (dependent only on the array structure and two Vandermonde-structured wavefield coefficient vectors (dependent on the wavefield. Then the propagator operator is calculated and used to form a system of bivariate polynomial equations. Finally, the automatically paired azimuth and elevation estimates are derived by polynomial rooting. The presented algorithm employs the concept of auxiliary-variable manifold separation technique which requires no sector by sector array interpolation and thus does not suffer from any mapping errors. In addition, the new algorithm does not need any eigenvalue decomposition of the covariance matrix and exhausted search over the two-dimensional parameter space. Moreover, the algorithm gives automatically paired estimates, thus avoiding the complex pairing procedure. Therefore, the proposed algorithm shows low computational complexity and high robustness performance. Simulation results are shown to validate the effectiveness of the proposed method.

  10. The Two-Dimensional One Component Plasma in a Doubly Periodic Background: Exact Results.

    Science.gov (United States)

    1988-01-24

    Background: Exact Results by Francoise Cornu*, Bernard Jancovici*, and Lesser Blum** *Laboratoire de Physique Theorique et Hautes Energies, Universite Paris...87/69 November 1987 1 Laboratolre de Physique Thdorlque et Hautes Energies, Unlversltd Parls-Sud, Bit. 21 1, 91405 Orsay, France (This Laboratory Is...Micanique Quantique (Hermann, Paris, 1977). 9. B. Jancovici, J. Stat. Phys. 2& 43 (1982). 10. S.L. Carnie and D.Y.C. Chan, Chem. Phys. Lett. 77 :437 (1981

  11. Corner wetting in the two-dimensional Ising model: Monte Carlo results

    Science.gov (United States)

    Albano, E. V.; DeVirgiliis, A.; Müller, M.; Binder, K.

    2003-01-01

    Square L × L (L = 24-128) Ising lattices with nearest neighbour ferromagnetic exchange are considered using free boundary conditions at which boundary magnetic fields ± h are applied, i.e., at the two boundary rows ending at the lower left corner a field +h acts, while at the two boundary rows ending at the upper right corner a field -h acts. For temperatures T less than the critical temperature Tc of the bulk, this boundary condition leads to the formation of two domains with opposite orientations of the magnetization direction, separated by an interface which for T larger than the filling transition temperature Tf (h) runs from the upper left corner to the lower right corner, while for T interface is localized either close to the lower left corner or close to the upper right corner. Numerous theoretical predictions for the critical behaviour of this 'corner wetting' or 'wedge filling' transition are tested by Monte Carlo simulations. In particular, it is shown that for T = Tf (h) the magnetization profile m(z) in the z-direction normal to the interface is simply linear and the interfacial width scales as w propto L, while for T > Tf (h) it scales as w proptosurd L. The distribution P (ell) of the interface position ell (measured along the z-direction from the corners) decays exponentially for T Tf (h). Furthermore, the Monte Carlo data are compatible with langleellrangle propto (Tf (h) - T)-1 and a finite size scaling of the total magnetization according to M(L, T) = tilde M {(1 - T/Tf (h))nubot L} with nubot = 1. Unlike the findings for critical wetting in the thin film geometry of the Ising model, the Monte Carlo results for corner wetting are in very good agreement with the theoretical predictions.

  12. Corner wetting in the two-dimensional Ising model: Monte Carlo results

    Energy Technology Data Exchange (ETDEWEB)

    Albano, E V [INIFTA, Universidad Nacional de La Plata, CC 16 Suc. 4, 1900 La Plata (Argentina); Virgiliis, A De [INIFTA, Universidad Nacional de La Plata, CC 16 Suc. 4, 1900 La Plata (Argentina); Mueller, M [Institut fuer Physik, Johannes Gutenberg Universitaet, Staudinger Weg 7, D-55099 Mainz (Germany); Binder, K [Institut fuer Physik, Johannes Gutenberg Universitaet, Staudinger Weg 7, D-55099 Mainz (Germany)

    2003-01-29

    Square LxL (L=24-128) Ising lattices with nearest neighbour ferromagnetic exchange are considered using free boundary conditions at which boundary magnetic fields are applied, i.e., at the two boundary rows ending at the lower left corner a field +h acts, while at the two boundary rows ending at the upper right corner a field -h acts. For temperatures T less than the critical temperature T{sub c} of the bulk, this boundary condition leads to the formation of two domains with opposite orientations of the magnetization direction, separated by an interface which for T larger than the filling transition temperature T{sub f} (h) runs from the upper left corner to the lower right corner, while for TT{sub f} (h) it scales as w {proportional_to}{radical} L. The distribution P (l) of the interface position l (measured along the z-direction from the corners) decays exponentially for TT{sub f} (h). Furthermore, the Monte Carlo data are compatible with (l) {proportional_to} (T{sub f} (h) - T){sup -1} and a finite size scaling of the total magnetization according to M(L, T) M-tilde ((1 - T/T{sub f} (h)){sup {nu}}{sub perp} L) with {nu}{sub perp} = 1. Unlike the findings for critical wetting in the thin film geometry of the Ising model, the Monte Carlo results for corner wetting are in very good agreement with the theoretical predictions.

  13. Identification of the dynamics of a two-dimensional grid structure using least square lattice filters. [for large space structures

    Science.gov (United States)

    Montgomery, R. C.; Sundararajan, N.

    1984-01-01

    It is doubtful whether the dynamics of large space structures (LSS) can be predicted well enough for control system design applications. Hence, dynamic modeling from on-orbit measurements followed by a modification of the control system is of interest, taking into account the utilization of adaptive control concepts. The present paper is concerned with the model determination phase of the adaptive control problem. Using spectral decoupling to determine mode shapes, mode frequency and damping data can be obtained with the aid of an equation error parameter identification method. This method employs a second-order auto-regressive moving average (ARMA) model to represent the natural mode amplitudes. The discussed procedure involves an extension of the application of the least square lattice filter in system identification to a nonintegral, two-dimensional grid structure made of overlapping bars.

  14. A compact chaotic laser device with a two-dimensional external cavity structure

    Energy Technology Data Exchange (ETDEWEB)

    Sunada, Satoshi, E-mail: sunada@se.kanazawa-u.ac.jp; Adachi, Masaaki [Faculty of Mechanical Engineering, Institute of Science and Engineering, Kanazawa University, Kakuma-machi, Kanazawa, Ishikawa 920-1192 (Japan); Fukushima, Takehiro [Department of Information and Communication Engineering, Okayama Prefectural University, 111 Kuboki, Soja, Okayama 719-1197 (Japan); Shinohara, Susumu; Arai, Kenichi [NTT Communication Science Laboratories, NTT Corporation, 2-4 Hikaridai, Seika-cho, Soraku-gun, Kyoto 619-0237 (Japan); Harayama, Takahisa [NTT Communication Science Laboratories, NTT Corporation, 2-4 Hikaridai, Seika-cho, Soraku-gun, Kyoto 619-0237 (Japan); Department of Mechanical Engineering, Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585 (Japan)

    2014-06-16

    We propose a compact chaotic laser device, which consists of a semiconductor laser and a two-dimensional (2D) external cavity for delayed optical feedback. The overall size of the device is within 230 μm × 1 mm. A long time delay sufficient for chaos generation can be achieved with the small area by the multiple reflections at the 2D cavity boundary, and the feedback strength is controlled by the injection current to the external cavity. We experimentally demonstrate that a variety of output properties, including chaotic output, can be selectively generated by controlling the injection current to the external cavity.

  15. On the algebraic structure of rotationally invariant two-dimensional Hamiltonians on the noncommutative phase space

    Science.gov (United States)

    Falomir, H.; Pisani, P. A. G.; Vega, F.; Cárcamo, D.; Méndez, F.; Loewe, M.

    2016-02-01

    We study two-dimensional Hamiltonians in phase space with noncommutativity both in coordinates and momenta. We consider the generator of rotations on the noncommutative plane and the Lie algebra generated by Hermitian rotationally invariant quadratic forms of noncommutative dynamical variables. We show that two quantum phases are possible, characterized by the Lie algebras {sl}(2,{{R}}) or su(2) according to the relation between the noncommutativity parameters, with the rotation generator related with the Casimir operator. From this algebraic perspective, we analyze the spectrum of some simple models with nonrelativistic rotationally invariant Hamiltonians in this noncommutative phase space, such as the isotropic harmonic oscillator, the Landau problem and the cylindrical well potential.

  16. On the algebraic structure of rotationally invariant two-dimensional Hamiltonians on the noncommutative phase space

    CERN Document Server

    Falomir, H; Vega, F; Cárcamo, D; Méndez, F; Loewe, M

    2015-01-01

    We study two-dimensional Hamiltonians in phase space with noncommutativity both in coordinates and momenta. We consider the generator of rotations on the noncommutative plane and the Lie algebra generated by Hermitian rotationally invariant quadratic forms of noncommutative dynamical variables. We show that two quantum phases are possible, characterized by the Lie algebras $sl(2,\\mathbb{R})$ or $su(2)$ according to the relation between the noncommutativity parameters. From this perspective, we analyze the spectrum of some simple models with nonrelativistic rotationally invariant Hamiltonians in this noncommutative phase space, as the isotropic harmonic oscillator, the Landau problem and the cylindrical well potential.

  17. Magnetic and Structural Studies on Two-Dimensional Antiferromagnets (MCl)LaNb2O7 (M = Mn, Co, Cr)

    Science.gov (United States)

    Kitada, Atsushi; Tsujimoto, Yoshihiro; Nishi, Masakazu; Matsuo, Akira; Kindo, Koichi; Ueda, Yutaka; Ajiro, Yoshitami; Kageyama, Hiroshi

    2016-03-01

    We report magnetic and structural studies on the two-dimensional antiferromagnets (MCl)LaNb2O7 (M = Mn, Cr, Co), prepared by topochemical reactions of a layered perovskite RbLaNb2O7. Electron diffraction of these oxyhalides revealed a superstructure with a √{2}a × √{2}a cell for M = Mn and Co, and a 2a × 2a cell for M = Cr, indicating that the MCl networks are distorted from an ideal square lattice. Neutron diffraction experiments showed that M = Mn and Co exhibit a (π 0 π ) antiferromagnetic order as observed for the S = 1/2 counterparts. (CoCl)LaNb2O7 with a strong spin anisotropy shows an antiferro to weak-ferromagnetic transition at low field, followed by novel two-step metamagnetic transitions likely associated with a 1/2 plateau for 27-54 T. Possible spin structures under magnetic field are discussed in terms of an Ising-type model. By contrast, (CrCl)LaNb2O7 exhibits a (π π π ) order, which is the first observation among related oxyhalides, and a spin-flop transition at 12 T due to a weak spin anisotropy. These results suggest that a slight difference in the MCl structure and spin anisotropy provides a crucial influence on the magnetic properties.

  18. Optical generation of a spatially variant two-dimensional lattice structure by using a phase only spatial light modulator

    CERN Document Server

    Kumar, Manish

    2016-01-01

    We propose a simple and straightforward method to generate a spatially variant lattice structures by optical interference lithography method. Using this method, it is possible to independently vary the orientation and period of the two-dimensional lattice. The method consists of two steps which are: numerical synthesis of corresponding phase mask by employing a two-dimensional integrated gradient calculations and experimental implementation of synthesized phase mask by making use of a phase only spatial light modulator in an optical 4f Fourier filtering setup. As a working example, we provide the experimental fabrication of a spatially variant square lattice structure which has the possibility to guide a Gaussian beam through a 90{\\deg} bend by photonic crystal self-collimation phenomena. The method is digitally reconfigurable, is completely scalable and could be extended to other kind of lattices as well.

  19. Optical generation of a spatially variant two-dimensional lattice structure by using a phase only spatial light modulator

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Manish, E-mail: manishk@physics.iitd.ac.in; Joseph, Joby, E-mail: joby@physics.iitd.ac.in [Photonics Research Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India)

    2014-08-04

    We propose a simple and straightforward method to generate spatially variant lattice structures by optical interference lithography method. Using this method, it is possible to independently vary the orientation and period of the two-dimensional lattice. The method consists of two steps which are: numerical synthesis of corresponding phase mask by employing a two-dimensional integrated gradient calculations and experimental implementation of synthesized phase mask by making use of a phase only spatial light modulator in an optical 4f Fourier filtering setup. As a working example, we provide the experimental fabrication of a spatially variant square lattice structure which has the possibility to guide a Gaussian beam through a 90° bend by photonic crystal self-collimation phenomena. The method is digitally reconfigurable, is completely scalable, and could be extended to other kind of lattices as well.

  20. Solutions of the Two-Dimensional Hubbard Model: Benchmarks and Results from a Wide Range of Numerical Algorithms

    Science.gov (United States)

    LeBlanc, J. P. F.; Antipov, Andrey E.; Becca, Federico; Bulik, Ireneusz W.; Chan, Garnet Kin-Lic; Chung, Chia-Min; Deng, Youjin; Ferrero, Michel; Henderson, Thomas M.; Jiménez-Hoyos, Carlos A.; Kozik, E.; Liu, Xuan-Wen; Millis, Andrew J.; Prokof'ev, N. V.; Qin, Mingpu; Scuseria, Gustavo E.; Shi, Hao; Svistunov, B. V.; Tocchio, Luca F.; Tupitsyn, I. S.; White, Steven R.; Zhang, Shiwei; Zheng, Bo-Xiao; Zhu, Zhenyue; Gull, Emanuel; Simons Collaboration on the Many-Electron Problem

    2015-10-01

    Numerical results for ground-state and excited-state properties (energies, double occupancies, and Matsubara-axis self-energies) of the single-orbital Hubbard model on a two-dimensional square lattice are presented, in order to provide an assessment of our ability to compute accurate results in the thermodynamic limit. Many methods are employed, including auxiliary-field quantum Monte Carlo, bare and bold-line diagrammatic Monte Carlo, method of dual fermions, density matrix embedding theory, density matrix renormalization group, dynamical cluster approximation, diffusion Monte Carlo within a fixed-node approximation, unrestricted coupled cluster theory, and multireference projected Hartree-Fock methods. Comparison of results obtained by different methods allows for the identification of uncertainties and systematic errors. The importance of extrapolation to converged thermodynamic-limit values is emphasized. Cases where agreement between different methods is obtained establish benchmark results that may be useful in the validation of new approaches and the improvement of existing methods.

  1. Solutions of the Two Dimensional Hubbard Model: Benchmarks and Results from a Wide Range of Numerical Algorithms

    Science.gov (United States)

    Leblanc, James

    In this talk we present numerical results for ground state and excited state properties (energies, double occupancies, and Matsubara-axis self energies) of the single-orbital Hubbard model on a two-dimensional square lattice. In order to provide an assessment of our ability to compute accurate results in the thermodynamic limit we employ numerous methods including auxiliary field quantum Monte Carlo, bare and bold-line diagrammatic Monte Carlo, method of dual fermions, density matrix embedding theory, density matrix renormalization group, dynamical cluster approximation, diffusion Monte Carlo within a fixed node approximation, unrestricted coupled cluster theory, and multireference projected Hartree-Fock. We illustrate cases where agreement between different methods is obtained in order to establish benchmark results that should be useful in the validation of future results.

  2. A molecular dynamics study on the structural and electronic properties of two-dimensional icosahedral B12 cluster based structures

    Science.gov (United States)

    Kah, Cherno Baba; Yu, M.; Jayanthi, C. S.; Wu, S. Y.

    2014-03-01

    Our previous study on one-dimensional icosahedral B12 cluster (α-B12) based chain [Bulletin of APS Annual Meeting, p265 (2013)] and ring structures has prompted us to study the two-dimensional (2D) α-B12 based structures. Recently, we have carried out a systematic molecular dynamics study on the structural stabilities and electronic properties of the 2D α-B12 based structures using the SCED-LCAO method [PRB 74, 15540 (2006)]. We have considered several types of symmetry for these 2D structures such as δ3, δ4, δ6 (flat triangular), and α' types. We have found that the optimized structures are energetically in the order of δ6 < α' < δ3 < δ4 which is different from the energy order of α'< δ6 < δ4 < δ3 found in the 2D boron monolayer sheets [ACS Nano 6, 7443 (2012)]. A detailed discussion of this study will be presented. The first author acknowledges the McSweeny Fellowship for supporting his research in this work.

  3. Selective cleavage of periodic mesoscale structures: two-dimensional replication of binary colloidal crystals into dimpled gold nanoplates.

    Science.gov (United States)

    Kuroda, Yoshiyuki; Sakamoto, Yasuhiro; Kuroda, Kazuyuki

    2012-05-23

    Specific crystallographic planes of binary colloidal crystals consisting of silica nanoparticles are two-dimensionally replicated on the surface of gold nanoplates. The selectivity of the surface patterns is explained by the geometrical characteristics of the binary colloidal crystals as templates. The binary colloidal crystals with the AlB(2)- and NaZn(13)-type structures are fabricated from aqueous dispersions of stoichiometrically mixed silica nanoparticles with different sizes. The stoichiometry is precisely controlled on the basis of a seed growth of silica nanoparticles. Dimpled gold nanoplates are formed by the two-dimensional growth of gold between partially cleaved surfaces of templates. The selectivity of the surface patterns is explained using the AlB(2)-type binary colloidal crystal as a template. The surface pattern is determined by the preferential cleavage of the plane with the lowest density of particle-particle connections. The tendency to form well-defined cleavage in binary colloidal crystals is crucial to formation of dimpled gold nanoplates, which is explained using the NaZn(13)-type binary colloidal crystal as a template. Its complex structure does not show well-defined cleavage, and only distorted nanoplates are obtained. Therefore, the mechanism of the two-dimensional replication of binary colloidal crystals is reasonably explained on the basis of their periodic mesoscale structures and crystal-like properties.

  4. Photonic Band Gaps in Two-Dimensional Crystals with Fractal Structure

    Institute of Scientific and Technical Information of China (English)

    刘征; 徐建军; 林志方

    2003-01-01

    We simulate the changes of the photonic band structure of the crystal in two dimensions with a quasi-fractal structure when it is fined to a fractal. The result shows that when the dielectric distribution is fined, the photonic band structure will be compressed on the whole and the ground photonic band gap (PBG) closed while the next PBGs shrunk, in conjunction with their position declining in the frequency spectrum. Furthermore, the PBGs in the high zone are much more sensitive than those in low zones.

  5. Structural Transformations in Two-Dimensional Transition-Metal Dichalcogenide MoS2 under an Electron Beam

    DEFF Research Database (Denmark)

    Kretschmer, Silvan; Komsa, Hannu-Pekka; Bøggild, Peter

    2017-01-01

    The polymorphism of two-dimensional (w2D) transition-metal dichalcogenides (TMDs) and different electronic properties of the polymorphs make TMDs particularly promising materials in the context of applications in electronics. Recently, local transformations from the semiconducting trigonal prisma...... development and optimization of electron-beam-mediated engineering of the atomic structure and electronic properties of 2D TMDs with subnanometer resolution.......The polymorphism of two-dimensional (w2D) transition-metal dichalcogenides (TMDs) and different electronic properties of the polymorphs make TMDs particularly promising materials in the context of applications in electronics. Recently, local transformations from the semiconducting trigonal...... prismatic H phase to the metallic octahedral T phase in 2D MoS2 have been induced by electron irradiation [Nat. Nanotech. 2014, 9, 391], but the mechanism of the transformations remains elusive. Using density functional theory calculations, we study the energetics of the stable and metastable phases of 2D...

  6. Semi-phenomenological analysis of neutron scattering results for quasi-two dimensional quantum anti-ferromagnet

    Science.gov (United States)

    Sarkar, Subhajit; Chaudhury, Ranjan; Paul, Samir K.

    2017-01-01

    The available results from the inelastic neutron scattering experiment performed on the quasi-two dimensional spin 1/2 anti-ferromagnetic material La2CuO4 have been analysed theoretically. The formalism of ours is based on a semi-classical like treatment involving a model of an ideal gas of mobile vortices and anti-vortices built on the background of the Néel state, using the bipartite classical spin configuration corresponding to an XY-anisotropic Heisenberg anti-ferromagnet on a square lattice. The results for the integrated intensities for our spin 1/2 model corresponding to different temperatures, show occurrence of vigorous unphysical oscillations, when convoluted with a realistic spectral window function. These results indicate failure of the conventional semi-classical theoretical model of ideal vortex/anti-vortex gas arising in the Berezinskii-Kosterlitz-Thouless theory for the low spin magnetic systems. A full fledged quantum mechanical formalism and calculations seem crucial for the understanding of topological excitations in such low spin systems. Furthermore, a severe disagreement is found to occur at finite values of energy transfer between the integrated intensities obtained theoretically from the conventional formalism and those obtained experimentally. This further suggests strongly that the full quantum treatment should also incorporate the interaction between the fragile-magnons and the topological excitations. This is quite plausible in view of the recent work establishing such a process in XXZ quantum ferromagnet on 2D lattice. The high spin XXZ quasi-two dimensional antiferromagnet like MnPS3 however follows the conventional theory quite well.

  7. Unusual onset of p-element magnetization in a two dimensional structure

    Science.gov (United States)

    Matar, Samir F.

    2016-10-01

    Based on density functional theory electronic and magnetic structure characterizations an unusual onset of spin polarization of p states is demonstrated leading to a stable ferromagnetic order within a carbon layered honeycomb-like compound. Specifically structural relaxation of formerly studied C2N in 3D network and devised here in 2D layered AlB2-type derived structure shows that the resulting ordered compound maintains the hexagonal crystal symmetry with an exceptionally large c/a ratio leading to strong localization of N states along c and letting magnetization develop within N-pz orbitals with 1.1 μB per formula unit. Anisotropic antibonding interactions between C and N layers allow interpreting the results. The compound is energetically characterized in ferromagnetic ground state versus less stable anti-ferromagnetic order.

  8. Observation of mesoscopic crystalline structures in a two-dimensional Rydberg gas

    CERN Document Server

    Schauß, Peter; Endres, Manuel; Fukuhara, Takeshi; Hild, Sebastian; Omran, Ahmed; Pohl, Thomas; Gross, Christian; Kuhr, Stefan; Bloch, Immanuel

    2012-01-01

    The ability to control and tune interactions in ultracold atomic gases has paved the way towards the realization of new phases of matter. Whereas experiments have so far achieved a high degree of control over short-ranged interactions, the realization of long-range interactions would open up a whole new realm of many-body physics and has become a central focus of research. Rydberg atoms are very well-suited to achieve this goal, as the van der Waals forces between them are many orders of magnitude larger than for ground state atoms. Consequently, the mere laser excitation of ultracold gases can cause strongly correlated many-body states to emerge directly when atoms are transferred to Rydberg states. A key example are quantum crystals, composed of coherent superpositions of different spatially ordered configurations of collective excitations. Here we report on the direct measurement of strong correlations in a laser excited two-dimensional atomic Mott insulator using high-resolution, in-situ Rydberg atom imag...

  9. Quantifying Resonant Structure in NGC 6946 from Two-dimensional Kinematics

    CERN Document Server

    Fathi, Kambiz; Falcón-Barroso, Jesús; Beckman, John E; Hernandez, Olivier; Daigle, Olivier; Carignan, Claude; de Zeeuw, Tim

    2007-01-01

    We study the two-dimensional kinematics of the H-alpha-emitting gas in the nearby barred Scd galaxy, NGC 6946, in order to determine the pattern speed of the primary m=2 perturbation mode. The pattern speed is a crucial parameter for constraining the internal dynamics, estimating the impact velocities of the gravitational perturbation at the resonance radii, and to set up an evolutionary scenario for NGC 6946. Our data allows us to derive the best fitting kinematic position angle and the geometry of the underlying gaseous disk, which we use to derive the pattern speed using the Tremaine-Weinberg method. We find a main pattern speed Omega_p=22 km/s/kpc, but our data clearly reveal the presence of an additional pattern speed Omega_p=47 km/s/kpc in a zone within 1.25 kpc of the nucleus. Using the epicyclic approximation, we deduce the location of the resonance radii and confirm that inside the outer Inner Lindblad Resonance radius of the main oval, a primary bar has formed rotating at more than twice the outer p...

  10. Quantifying Resonant Structure in NGC 6946 from Two-dimensional Kinematics

    Science.gov (United States)

    Fathi, Kambiz; Toonen, Silvia; Falcón-Barroso, Jesús; Beckman, John E.; Hernandez, Olivier; Daigle, Olivier; Carignan, Claude; de Zeeuw, Tim

    2007-10-01

    We study the two-dimensional kinematics of the Hα-emitting gas in the nearby barred Scd galaxy NGC 6946, in order to determine the pattern speed of the primary m=2 perturbation mode. The pattern speed is a crucial parameter for constraining the internal dynamics, estimating the impact velocities of the gravitational perturbation at the resonance radii, and setting up an evolutionary scenario for NGC 6946. Our data allow us to derive the best-fitting kinematic position angle and the geometry of the underlying gaseous disk, which we use to derive the pattern speed using the Tremaine-Weinberg method. We find a main pattern speed ΩPp=22+4-1 km s-1 kpc-1, but our data clearly reveal the presence of an additional pattern speed ΩSp=47+3-2 km s-1 kpc-1 in a zone within 1.25 kpc of the nucleus. Using the epicyclic approximation, we deduce the location of the resonance radii and confirm that inside the outer inner Lindblad resonance radius of the main oval, a primary bar has formed rotating at more than twice the outer pattern speed. We further confirm that a nuclear bar has formed inside the inner Lindblad resonance radius of the primary bar, coinciding with the inner inner Lindblad resonance radius of the large-scale m=2 mode oval.

  11. The octamer motif in immunoglobulin genes: extraction of structural constraints from two-dimensional NMR studies.

    Science.gov (United States)

    Weisz, K; Shafer, R H; Egan, W; James, T L

    1992-08-25

    Phase-sensitive two-dimensional nuclear Overhauser enhancement (2D NOE) and double-quantum-filtered correlated (2QF-COSY) spectra were recorded at 500 MHz for the DNA duplex d(CATTTGCATC).d(GATGCAAATG), which contains the octamer element of immunoglobulin genes. Exchangeable and nonexchangeable proton resonances including those of the H5' and H5" protons were assigned. Overall, the decamer duplex adopts a B-type DNA conformation. Scalar coupling constants for the sugar protons were determined by quantitative simulations of 2QF-COSY cross-peaks. These couplings are consistent with a two-state dynamic equilibrium between a minor N- and a major S-type conformer for all residues. The pseudorotation phase angle P of the major conformer is in the range 117-135 degrees for nonterminal pyrimidine nucleotides and 153-162 degrees for nonterminal purine nucleotides. Except for the terminal residues, the minor conformer comprises less than 25% of the population. Distance constraints obtained by a complete relaxation matrix analysis of the 2D NOE intensities with the MARDIGRAS algorithm confirm the dependence of the sugar pucker on pyrimidine and purine bases. Averaging by fast local motions has at most small effects on the NOE-derived interproton distances.

  12. Impact of Radii Ratios on a Two-Dimensional Cloaking Structure and Corresponding Analysis for Practical Design at Optical Wavelengths

    Directory of Open Access Journals (Sweden)

    Nadia Anam

    2017-01-01

    Full Text Available This work is an extension to the evaluation and analysis of a two-dimensional cylindrical cloak in the Terahertz or visible range spectrum using Finite Difference Time-Domain (FDTD method. It was concluded that it is possible to expand the frequency range of a cylindrical cloaking model by careful scaling of the inner and outer radius of the simulation geometry with respect to cell size and/or number of time steps in the simulation grid while maintaining appropriate stability conditions. Analysis in this study is based on a change in the radii ratio, that is, outer radius to inner radius, of the cloaking structure for an array of wavelengths in the visible spectrum. Corresponding outputs show inconsistency in the cloaking pattern with respect to frequency. The inconsistency is further increased as the radii ratio is decreased. The results also help to establish a linear relationship between the transmission coefficient and the real component of refractive index with respect to different radii ratios which may simplify the selection of the material for practical design purposes. Additional performance analysis is carried out such that the dimensions of the cloak are held constant at an average value and the frequency varied to determine how a cloaked object may be perceived by the human eye which considers different wavelengths to be superimposed on each other simultaneously.

  13. Investigation of polarization-selective InGaAs sensor with elliptical two-dimensional holes array structure

    Science.gov (United States)

    Wang, Wenbo; Fu, Dong; Hu, Xiaobin; Xu, Yun; Song, Guofeng; Wei, Xin

    2016-10-01

    Polarimetric imaging in infrared wavelengths have attracted more and more attention for broad applications in meteorological observations, medicine, remote sensing and many other fields. Metal metamaterial structures are used in nanophotonics in order to localize and enhance the incident electromagnetic field. Here we develop an elliptical gold Two-Dimensional Holes Array (2DHA) in which photons can be manipulated by surface plasmon resonance, and the ellipse introduce the asymmetry to realize a polarization selective function. Strong polarization dependence is observed in the simulated transmission spectra. To further understand the coupling mechanism between gold holes array and InP, the different parameters of the 2DHA are analyzed. It is shown that the polarization axis is perpendicular to the major axis of the ellipse, and the degree of polarization is determined by the aspect ratio of the ellipse. Furthermore, the resonance frequency of the 2DHA shows a linear dependence on the array period, the bandwidth of transmission spectra closely related to duty cycle of the ellipse in each period. This result will establish a basis for the development of innovative polarization selective infrared sensor.

  14. Aluminum-based one- and two-dimensional micro fin array structures: high-throughput fabrication and heat transfer testing

    Science.gov (United States)

    Primeaux, Philip A.; Zhang, Bin; Zhang, Xiaoman; Miller, Jacob; Meng, W. J.; KC, Pratik; Moore, Arden L.

    2017-02-01

    Microscale fin array structures were replicated onto surfaces of aluminum 1100 and aluminum 6061 alloy (Al1100/Al6061) sheet metals through room-temperature instrumented roll molding. Aluminum-based micro fin arrays were replicated at room temperature, and the fabrication process is one with high throughput and low cost. One-dimensional (1D) micro fin arrays were made through one-pass rolling, while two-dimensional (2D) micro fin arrays were made by sequential 90° cross rolling with the same roller sleeve. For roll molding of 1D micro fins, fin heights greater than 600 µm were achieved and were shown to be proportional to the normal load force per feature width. At a given normal load force, the fin height was further shown to scale inversely with the hardness of the sheet metal. For sequential 90° cross rolling, morphologies of roll molded 2D micro fin arrays were examined, which provided clues to understand how plastic deformation occurred under cross rolling conditions. A series of pool boiling experiments on low profile Al micro fin array structures were performed within Novec 7100, a widely used commercial dielectric coolant. Results for both horizontal and vertical surface orientations show that roll molded Al micro fin arrays can increase heat flux at fixed surface temperature as compared to un-patterned Al sheet. The present results further suggest that many factors beyond just increased surface area can influence heat transfer performance, including surface finish and the important multiphase transport mechanisms in and around the fin geometry. These factors must also be considered when designing and optimizing micro fin array structures for heat transfer applications.

  15. Reconstruction of two-dimensional molecular structure with laser-induced electron diffraction from laser-aligned polyatomic molecules

    Science.gov (United States)

    Yu, Chao; Wei, Hui; Wang, Xu; Le, Anh-Thu; Lu, Ruifeng; Lin, C. D.

    2015-01-01

    Imaging the transient process of molecules has been a basic way to investigate photochemical reactions and dynamics. Based on laser-induced electron diffraction and partial one-dimensional molecular alignment, here we provide two effective methods for reconstructing two-dimensional structure of polyatomic molecules. We demonstrate that electron diffraction images in both scattering angles and broadband energy can be utilized to retrieve complementary structure information, including positions of light atoms. With picometre spatial resolution and the inherent femtosecond temporal resolution of lasers, laser-induced electron diffraction method offers significant opportunities for probing atomic motion in a large molecule in a typical pump-probe measurement. PMID:26503116

  16. A Pseudospectral Time-Domain Algorithm for Calculating the Band Structure of a Two-Dimensional Photonic Crystal

    Institute of Scientific and Technical Information of China (English)

    何江平; 沈林放; 张全; 何赛灵

    2002-01-01

    A pseudospectral time-domain (PSTD) method is developed for calculating the band structure of a two-dimensional photonic crystal. Maxwell's equations are rewritten in terms of period fields by using the Bloch theorem. Instead of spatial finite differences, the fast Fourier transform is used to calculate the spatial derivatives. To reach a similar accuracy, fewer sample points are required in the present PSTD method as compared to the conventional finite-difference time-domain methods. Our numerical simulation shows that the present PSTD method is an efficient and accurate method for calculating the band structure of a photonic crystal.

  17. Two-dimensional simulations of temperature and current-density distribution in electromigrated structures

    Science.gov (United States)

    Kießig, Birgit; Schäfer, Roland; von Löhneysen, Hilbert

    2014-01-01

    We report on the application of a feedback-controlled electromigration technique for the formation of nanometre-sized gaps in mesoscopic gold wires and rings. The effect of current density and temperature, linked via Joule heating, on the resulting gap size is investigated. Our experiments include in situ measurements of the evolution of the electrical resistance and of the structure of the device during electromigration. Experimentally, a good thermal coupling to the substrate turned out to be crucial to reach electrode spacings below 10 nm and to avoid overall melting of the nanostructures. This finding is supported by numerical calculations of the current-density and temperature profiles for structure layouts subjected to electromigration. The numerical method can be used for optimizing the layout so as to predetermine the location where electromigration leads to the formation of a gap.

  18. A study of frequency band structure in two-dimensional homogeneous anisotropic phononic K3-metamaterials

    Science.gov (United States)

    Gorshkov, V. N.; Navadeh, N.; Fallah, A. S.

    2017-09-01

    Phononic metamaterials are synthesised materials in which locally resonant units are arranged in a particular geometry of a substratum lattice and connected in a predefined topology. This study investigates dispersion surfaces in two-dimensional anisotropic acoustic metamaterials involving mass-in-mass units connected by massless springs in K3 topology. The reasons behind the particular choice of this topology are explained. Two sets of solutions for the eigenvalue problem | {\\boldsymbol{D}}({ω }2,{\\boldsymbol{k}})| =0 are obtained and the existence of absolutely different mechanisms of gap formation between acoustic and optical surface frequencies is shown as a bright display of quantum effects like strong coupling, energy splitting, and level crossings in classical mechanical systems. It has been concluded that a single dimensionless parameter i.e. relative mass controls the order of formation of gaps between different frequency surfaces. If the internal mass of the locally resonant mass-in-mass unit, m, increases relative to its external mass, M, then the coupling between the internal and external vibrations in the whole system rises sharply, and a threshold {μ }* is reached so that for m/M> {μ }* the optical vibrations break the continuous spectrum of ‘acoustic phonons’ creating the gap between them for any value of other system parameters. The methods to control gap parameters and polarisation properties of the optical vibrations created over these gaps were investigated. Dependencies of morphology and width of gaps for several anisotropic cases have been expounded and the physical meaning of singularity at the point of tangential contact between two adjacent frequency surfaces has been provided. Repulsion between different frequency band curves, as planar projections of surfaces, has been explained. The limiting case of isotropy has been discussed and it has been shown that, in the isotropic case, the lower gap always forms, irrespective of the value

  19. Photonic band structures of two-dimensional photonic crystals with deformed lattices

    Institute of Scientific and Technical Information of China (English)

    Cai Xiang-Hua; Zheng Wan-Hua; Ma Xiao-Tao; Ren Gang; Xia Jian-Bai

    2005-01-01

    Using the plane-wave expansion method, we have calculated and analysed the changes of photonic band structures arising from two kinds of deformed lattices, including the stretching and shrinking of lattices. The square lattice with square air holes and the triangular lattice with circular air holes are both studied. Calculated results show that the change of lattice size in some special ranges can enlarge the band gap, which depends strongly on the filling factor of air holes in photonic crystals; and besides, the asymmetric band edges will appear with the broken symmetry of lattices.

  20. Analysis of two-dimensional photonic band gap structure with a rhombus lattice

    Institute of Scientific and Technical Information of China (English)

    Limei Qi; Ziqiang Yang; Xi Gao; Zheng Liang

    2008-01-01

    @@ The relative band gap for a rhombus lattice photonic crystal is studied by plane wave expansion method and high frequency structure simulator (HFSS) simulation. General wave vectors in the first Briliouin zone are derived. The relative band gap as a function of air-filling factor and background material is investigated, respectively, and the nature of photonic band gap for different lattice angles is analyzed by the distribution of electric energy. These results would provide theoretical instruction for designing optical integrated devices using photonic crystal with a rhombus lattice.

  1. Atomic structure and electronic properties of the two-dimensional (Au ,Al )/Si (111 )2 ×2 compound

    Science.gov (United States)

    Gruznev, D. V.; Bondarenko, L. V.; Matetskiy, A. V.; Tupchaya, A. Y.; Chukurov, E. N.; Hsing, C. R.; Wei, C. M.; Eremeev, S. V.; Zotov, A. V.; Saranin, A. A.

    2015-12-01

    A combination of scanning tunneling microscopy, angle-resolved photoelectron spectroscopy, ab initio random structure searching, and density functional theory electronic structure calculations was applied to elucidate the atomic arrangement and electron band structure of the (Au ,Al )/Si (111 )2 ×2 two-dimensional compound formed upon Al deposition onto the mixed 5 ×2 /√{3 }×√{3 } Au/Si(111) surface. It was found that the most stable 2 ×2 -(Au, Al) compound incorporates four Au atoms, three Al atoms, and two Si atoms per 2 ×2 unit cell. Its atomic arrangement can be visualized as an array of meandering Au atomic chains with two-thirds of the Al atoms incorporated into the chains and one-third of the Al atoms interconnecting the chains. The compound is metallic and its electronic properties can be controlled by appropriate Al dosing since energetic location of the bands varies by ˜0.5 eV during increasing of Al contents. The 2 ×2 -(Au, Al) structure appears to be lacking the C3 v symmetry typical for the hexagonal lattices. The consequence of the peculiar atomic structure of the two-dimensional alloy is spin splitting of the metallic states, which should lead to anisotropy of the current-induced in-plane spin polarization.

  2. Solutions of the Two-Dimensional Hubbard Model: Benchmarks and Results from a Wide Range of Numerical Algorithms

    Directory of Open Access Journals (Sweden)

    2015-12-01

    Full Text Available Numerical results for ground-state and excited-state properties (energies, double occupancies, and Matsubara-axis self-energies of the single-orbital Hubbard model on a two-dimensional square lattice are presented, in order to provide an assessment of our ability to compute accurate results in the thermodynamic limit. Many methods are employed, including auxiliary-field quantum Monte Carlo, bare and bold-line diagrammatic Monte Carlo, method of dual fermions, density matrix embedding theory, density matrix renormalization group, dynamical cluster approximation, diffusion Monte Carlo within a fixed-node approximation, unrestricted coupled cluster theory, and multireference projected Hartree-Fock methods. Comparison of results obtained by different methods allows for the identification of uncertainties and systematic errors. The importance of extrapolation to converged thermodynamic-limit values is emphasized. Cases where agreement between different methods is obtained establish benchmark results that may be useful in the validation of new approaches and the improvement of existing methods.

  3. Structural soil crust development from raindrop impacts using two-dimensional discrete element method

    Science.gov (United States)

    Yeom, Seungcheol; Sjoblom, Kurt

    2016-12-01

    The mechanical nature of crust formation as a result of raindrop impacts was simulated within a discrete element modeling environment. Simulations were conducted in two-dimensions (2D) using both linear and non-linear elastic contact models. The 2D approach was found to minimize the computational effort required and maximize the number of particles in the soil profile. For the non-linear model, the effect of the coefficient of restitution (COR) for soil-rain and soil-soil was investigated. Finally, the comparison between the linear and nonlinear elastic contact model was presented. The simulation indicated that the COR for rain-soil had negligible effect on the crust development but the computational time was exponentially increased with increasing coefficient value. In contrast, the COR for soil-soil had a dominant influence on the crust development. To validate the numerical results, a micro computerized tomography (microCT) technique was applied to characterize the changes in pore structure to a USCS SP soil after exposure under a rainfall simulator. Additionally, the effect of cyclic wetting and drying (without rainfall) on the changes in porosity was investigated. The experimental results showed that the rainfall simulator sufficiently densified the soil but the effect of cyclic wetting and drying was negligible. The numerical simulations showed similar changes in porosity along the depth of the soil profile as compared with the experimental results thus validating the DEM technique to simulate crust development.

  4. Fabrication of two-dimensional visible wavelength nanoscale plasmonic structures using hydrogen silsesquioxane based resist

    Science.gov (United States)

    Smith, Kyle Z.; Gadde, Akshitha; Kadiyala, Anand; Dawson, Jeremy M.

    2016-03-01

    In recent years, the global market for biosensors has continued to increase in combination with their expanding use in areas such as biodefense/detection, home diagnostics, biometric identification, etc. A constant necessity for inexpensive, portable bio-sensing methods, while still remaining simple to understand and operate, is the motivation behind novel concepts and designs. Labeled visible spectrum bio-sensing systems provide instant feedback that is both simple and easy to work with, but are limited by the light intensity thresholds required by the imaging systems. In comparison, label-free bio-sensing systems and other detection modalities like electrochemical, frequency resonance, thermal change, etc., can require additional technical processing steps to convey the final result, increasing the system's complexity and possibly the time required for analysis. Further decrease in the detection limit can be achieved through the addition of plasmonic structures into labeled bio-sensing systems. Nano-structures that operate in the visible spectrum have feature sizes typically in the order of the operating wavelength, calling for high aspect ratio nanoscale fabrication capabilities. In order to achieve these dimensions, electron beam lithography (EBL) is used due to its accurate feature production. Hydrogen silsesquioxane (HSQ) based electron beam resist is chosen for one of its benefits, which is after exposure to oxygen plasma, the patterned resist cures into silicon dioxide (SiO2). These cured features in conjunction with nanoscale gold particles help in producing a high electric field through dipole generation. In this work, a detailed process flow of the fabrication of square lattice of plasmonic structures comprising of gold coated silicon dioxide pillars designed to operate at 560 nm wavelength and produce an intensity increase of roughly 100 percent will be presented.

  5. Synthesis of two-dimensional TlxBi1−x compounds and Archimedean encoding of their atomic structure

    Science.gov (United States)

    Gruznev, Dimitry V.; Bondarenko, Leonid V.; Matetskiy, Andrey V.; Mihalyuk, Alexey N.; Tupchaya, Alexandra Y.; Utas, Oleg A.; Eremeev, Sergey V.; Hsing, Cheng-Rong; Chou, Jyh-Pin; Wei, Ching-Ming; Zotov, Andrey V.; Saranin, Alexander A.

    2016-01-01

    Crystalline atomic layers on solid surfaces are composed of a single building block, unit cell, that is copied and stacked together to form the entire two-dimensional crystal structure. However, it appears that this is not an unique possibility. We report here on synthesis and characterization of the one-atomic-layer-thick TlxBi1−x compounds which display quite a different arrangement. It represents a quasi-periodic tiling structures that are built by a set of tiling elements as building blocks. Though the layer is lacking strict periodicity, it shows up as an ideally-packed tiling of basic elements without any skips or halting. The two-dimensional TlxBi1−x compounds were formed by depositing Bi onto the Tl-covered Si(111) surface where Bi atoms substitute appropriate amount of Tl atoms. Atomic structure of each tiling element as well as arrangement of TlxBi1−x compounds were established in a detail. Electronic properties and spin texture of the selected compounds having periodic structures were characterized. The shown example demonstrates possibility for the formation of the exotic low-dimensional materials via unusual growth mechanisms. PMID:26781340

  6. Synthesis of two-dimensional TlxBi1-x compounds and Archimedean encoding of their atomic structure

    Science.gov (United States)

    Gruznev, Dimitry V.; Bondarenko, Leonid V.; Matetskiy, Andrey V.; Mihalyuk, Alexey N.; Tupchaya, Alexandra Y.; Utas, Oleg A.; Eremeev, Sergey V.; Hsing, Cheng-Rong; Chou, Jyh-Pin; Wei, Ching-Ming; Zotov, Andrey V.; Saranin, Alexander A.

    2016-01-01

    Crystalline atomic layers on solid surfaces are composed of a single building block, unit cell, that is copied and stacked together to form the entire two-dimensional crystal structure. However, it appears that this is not an unique possibility. We report here on synthesis and characterization of the one-atomic-layer-thick TlxBi1-x compounds which display quite a different arrangement. It represents a quasi-periodic tiling structures that are built by a set of tiling elements as building blocks. Though the layer is lacking strict periodicity, it shows up as an ideally-packed tiling of basic elements without any skips or halting. The two-dimensional TlxBi1-x compounds were formed by depositing Bi onto the Tl-covered Si(111) surface where Bi atoms substitute appropriate amount of Tl atoms. Atomic structure of each tiling element as well as arrangement of TlxBi1-x compounds were established in a detail. Electronic properties and spin texture of the selected compounds having periodic structures were characterized. The shown example demonstrates possibility for the formation of the exotic low-dimensional materials via unusual growth mechanisms.

  7. Synthesis of two-dimensional Tl(x)Bi(1-x) compounds and Archimedean encoding of their atomic structure.

    Science.gov (United States)

    Gruznev, Dimitry V; Bondarenko, Leonid V; Matetskiy, Andrey V; Mihalyuk, Alexey N; Tupchaya, Alexandra Y; Utas, Oleg A; Eremeev, Sergey V; Hsing, Cheng-Rong; Chou, Jyh-Pin; Wei, Ching-Ming; Zotov, Andrey V; Saranin, Alexander A

    2016-01-19

    Crystalline atomic layers on solid surfaces are composed of a single building block, unit cell, that is copied and stacked together to form the entire two-dimensional crystal structure. However, it appears that this is not an unique possibility. We report here on synthesis and characterization of the one-atomic-layer-thick Tl(x)Bi(1-x) compounds which display quite a different arrangement. It represents a quasi-periodic tiling structures that are built by a set of tiling elements as building blocks. Though the layer is lacking strict periodicity, it shows up as an ideally-packed tiling of basic elements without any skips or halting. The two-dimensional Tl(x)Bi(1-x) compounds were formed by depositing Bi onto the Tl-covered Si(111) surface where Bi atoms substitute appropriate amount of Tl atoms. Atomic structure of each tiling element as well as arrangement of Tl(x)Bi(1-x) compounds were established in a detail. Electronic properties and spin texture of the selected compounds having periodic structures were characterized. The shown example demonstrates possibility for the formation of the exotic low-dimensional materials via unusual growth mechanisms.

  8. Two-dimensional imaging detectors for structural biology with X-ray lasers.

    Science.gov (United States)

    Denes, Peter

    2014-07-17

    Our ability to harness the advances in microelectronics over the past decade(s) for X-ray detection has resulted in significant improvements in the state of the art. Biology with X-ray free-electron lasers present daunting detector challenges: all of the photons arrive at the same time, and individual high peak power pulses must be read out shot-by-shot. Direct X-ray detection in silicon pixel detectors--monolithic or hybrid--are the standard for XFELs today. For structural biology, improvements are needed for today's 10-100 Hz XFELs, and further improvements are required for tomorrow's 10+ kHz XFELs. This article will discuss detector challenges, why they arise and ways to overcome them, along with the current state of the art. © 2014 The Author(s) Published by the Royal Society. All rights reserved.

  9. The topology of large-scale structure. V - Two-dimensional topology of sky maps

    Science.gov (United States)

    Gott, J. R., III; Mao, Shude; Park, Changbom; Lahav, Ofer

    1992-01-01

    A 2D algorithm is applied to observed sky maps and numerical simulations. It is found that when topology is studied on smoothing scales larger than the correlation length, the topology is approximately in agreement with the random phase formula for the 2D genus-threshold density relation, G2(nu) varies as nu(e) exp-nu-squared/2. Some samples show small 'meatball shifts' similar to those seen in corresponding 3D observational samples and similar to those produced by biasing in cold dark matter simulations. The observational results are thus consistent with the standard model in which the structure in the universe today has grown from small fluctuations caused by random quantum noise in the early universe.

  10. Design of a Photonic-Crystal Channel-Drop Filter Based on the Two-Dimensional Triangular-Lattice Hole Structure

    Institute of Scientific and Technical Information of China (English)

    Kyu; Hwan; Hwang; G.; Hugh; Song; Chanmook; Lim; Soan; Kim; Kyung-Won; Chun; Mahn; Yong; Park

    2003-01-01

    A channel-drop filter has been designed based on the two-dimensional triangular-lattice hole photonic-crystal structure, which consists of two line defects and two point defects, by a two-dimensional finite-difference time-domain simulation.

  11. Light propagation in two-dimensional photonic crystals based on uniaxial polar materials: results on polaritonic spectrum

    Science.gov (United States)

    Gómez-Urrea, H. A.; Duque, C. A.; Pérez-Quintana, I. V.; Mora-Ramos, M. E.

    2017-03-01

    The dispersion relations of two-dimensional photonic crystals made of uniaxial polaritonic cylinders arranged in triangular lattice are calculated. The particular case of the transverse magnetic polarization is taken into account. Three different uniaxial materials showing transverse phonon-polariton excitations are considered: aluminum nitride, gallium nitride, and indium nitride. The study is carried out by means of the finite-difference time-domain technique for the solution of Maxwell equations, together with the method of the auxiliary differential equation. It is shown that changing the filling fraction can result in the modification of both the photonic and polaritonic bandgaps in the optical dispersion relations. Wider gaps appear for smaller filling fraction values, whereas a larger number of photonic bandgaps will occur within the frequency range considered when a larger filling fraction is used. The effect of including the distinct wurtzite III-V nitride semiconductors as core materials in the cylinders embedded in the air on the photonic properties is discussed as well, highlighting the effect of the dielectric anisotropy on the properties of the polaritonic part of the photonic spectrum.

  12. Design, fabrication, and characterization of lightweight and broadband microwave absorbing structure reinforced by two dimensional composite lattice

    Science.gov (United States)

    Chen, Mingji; Pei, Yongmao; Fang, Daining

    2012-07-01

    Microwave absorbing structures (MASs) reinforced by two dimensional (2D) composite lattice elements have been designed and fabricated. The density of these MASs is lower than 0.5 g/cm3. Experimental measurements show that the sandwich structure with glass fiber reinforced composite (GFRC) lattice core can serve as a broadband MAS with its reflectivity below -10 dB over the frequency range of 4-18 GHz. The low permittivity GFRC is indicated to be the proper material for both the structural element of the core and the transparent face sheet. Calculations by the periodic moment method (PMM) demonstrate that the 2D Kagome lattice performs better for microwave absorbing than the square one at relatively low frequencies. The volume fraction and cell size of the structural element are also revealed to be key factors for microwave absorbing performance.

  13. One- and Two-Dimensional Maximum Softening Indicators for Reinforced Concrete Structures under Seismic Excitation

    DEFF Research Database (Denmark)

    Nielsen, Søren R. K.; Köyüoglu, H. U.; Cakmak, A. S.

    The maximum softening concept is based on the variation of the vibrational periods of a structure during a seismic event. Maximum softening damage indicators, which measure the maximum relative stiffness reduction caused by stiffness and strength deterioration of the actual structure, are calcula......The maximum softening concept is based on the variation of the vibrational periods of a structure during a seismic event. Maximum softening damage indicators, which measure the maximum relative stiffness reduction caused by stiffness and strength deterioration of the actual structure...

  14. Structure of growing microtubule ends: two-dimensional sheets close into tubes at variable rates.

    Science.gov (United States)

    Chrétien, D; Fuller, S D; Karsenti, E

    1995-06-01

    Observation of microtubule growth at different rates by cryo-electron microscopy reveals that the ends range from blunt to long, gently curved sheets. The mean sheet length increases with the growth rate while the width of the distributions increases with the extent of assembly. The combination of a concentration dependent growth rate of the tubulin sheet with a variable closure rate of the microtubule cylinder, results in a model in which stochastic fluctuations in sheet length and tubulin conformation confine GTP-tubulins to microtubule ends. We propose that the variability of microtubule growth rate observed by video microscopy (Gildersleeve, R. F., A. R. Cross, K. E. Cullen, A. P. Fagen, and R. C. Williams. 1992. J. Biol. Chem. 267: 7995-8006, and this study) is due to the variation in the rate of cylinder closure. The curvature of the sheets at the end of growing microtubules and the small oligomeric structures observed at the end of disassembling microtubules, indicate that tubulin molecules undergo conformational changes both during assembly and disassembly.

  15. Phononic band gaps and vibrations in one- and two-dimensional mass-spring structures

    DEFF Research Database (Denmark)

    Jensen, Jakob Søndergaard

    2003-01-01

    The vibrational response of finite periodic lattice structures subjected to periodic loading is investigated. Special attention is devoted to the response in frequency ranges with gaps in the band structure for the corresponding infinite periodic lattice. The effects of boundaries, viscous dampin...

  16. Quantum ratchet effects induced by terahertz radiation in GaN-based two-dimensional structures

    NARCIS (Netherlands)

    Weber, W.; Golub, L. E.; Danilov, S. N.; Karch, J.; Reitmaier, C.; Wittmann, B.; Bel' kov, V. V.; Ivchenko, E. L.; Kvon, Z. D.; Vinh, N. Q.; van der Meer, A. F. G.; Murdin, B.; Ganichev, S. D.

    2008-01-01

    Photogalvanic effects are observed and investigated in wurtzite (0001)-oriented GaN/AlGaN low-dimensional structures excited by terahertz radiation. The structures are shown to represent linear quantum ratchets. Experimental and theoretical analysis exhibits that the observed photocurrents are relat

  17. Quantum ratchet effects induced by terahertz radiation in GaN-based two-dimensional structures

    Science.gov (United States)

    Weber, W.; Golub, L. E.; Danilov, S. N.; Karch, J.; Reitmaier, C.; Wittmann, B.; Bel'Kov, V. V.; Ivchenko, E. L.; Kvon, Z. D.; Vinh, N. Q.; van der Meer, A. F. G.; Murdin, B.; Ganichev, S. D.

    2008-06-01

    Photogalvanic effects are observed and investigated in wurtzite (0001)-oriented GaN/AlGaN low-dimensional structures excited by terahertz radiation. The structures are shown to represent linear quantum ratchets. Experimental and theoretical analysis exhibits that the observed photocurrents are related to the lack of an inversion center in the GaN-based heterojunctions.

  18. Phononic band gaps and vibrations in one- and two-dimensional mass-spring structures

    DEFF Research Database (Denmark)

    Jensen, Jakob Søndergaard

    2003-01-01

    The vibrational response of finite periodic lattice structures subjected to periodic loading is investigated. Special attention is devoted to the response in frequency ranges with gaps in the band structure for the corresponding infinite periodic lattice. The effects of boundaries, viscous dampin...

  19. Phononic band gaps and vibrations in one- and two-dimensional mass-spring structures

    Science.gov (United States)

    Jensen, J. S.

    2003-10-01

    The vibrational response of finite periodic lattice structures subjected to periodic loading is investigated. Special attention is devoted to the response in frequency ranges with gaps in the band structure for the corresponding infinite periodic lattice. The effects of boundaries, viscous damping, and imperfections are studied by analyzing two examples; a 1-D filter and a 2-D wave guide. In 1-D the structural response in the band gap is shown to be insensitive to damping and small imperfections. In 2-D the similar effect of damping is noted for one type of periodic structure, whereas for another type the band gap effect is nearly eliminated by damping. In both 1-D and 2-D it is demonstrated how the free structural boundaries affect the response in the band gap due to local resonances. Finally, 2-D wave guides are considered by replacing the periodic structure with a homogeneous structure in a straight and a 90° bent path, and it is shown how the vibrational response is confined to the paths in the band gap frequency ranges.

  20. When is high-dimensional scattering chaos essentially two dimensional? Measuring the product structure of singularities.

    Science.gov (United States)

    Drótos, G; Jung, C; Tél, T

    2012-11-01

    We demonstrate how the area of the enveloping surface of the scattering singularities in a three-degrees-of-freedom (3-dof) system depends on a perturbation parameter controlling the distance from a reducible case. This dependence is monotonic and approximately linear. Therefore it serves as a measure for this distance, which can be extracted from an investigation of the fractal structure. These features are a consequence of the dynamics being governed by normally hyperbolic invariant manifolds. We conclude that typical n-dof chaotic scattering exhibits either structures developing out of a stack of chaotic structures of 2-dof type or hardly any chaotic effects.

  1. Electrostatic Structures in Space Plasmas: Stability of Two-dimensional Magnetic Bernstein-Greene-Kruskal Modes

    CERN Document Server

    Ng, C S; Yasin, E

    2011-01-01

    Electrostatic structures have been observed in many regions of space plasmas, including the solar wind, the magnetosphere, the auroral acceleration region, and in association with shocks, turbulence, and magnetic reconnection. Due to potentially large amplitude of electric fields within these structures, their effects on particle heating, scattering, or acceleration can be important. One possible theoretical description of some of these structures is the concept of Bernstein-Greene-Kruskal (BGK) modes, which are exact nonlinear solutions of the Vlasov-Poisson system of equations in collisionless kinetic theory. BGK modes have been studied extensively for many decades, predominately in one dimension (1D), although there have been observations showing that some of these structures have clear 3D features. While there have been approximate solutions of higher dimensional BGK modes, an exact 3D BGK mode solution in a finite magnetic field has not been found yet. Recently we have constructed exact solutions of 2D B...

  2. Study on two-dimensional equilibrium structure of magnetized complex plasmas based on a Langevin dynamics simulation

    Science.gov (United States)

    Kong, Wei; Yang, Fang; Liu, Songfen; Shi, Feng

    2016-10-01

    A Langevin dynamics simulation method is used to study the two-dimensional (2D) equilibrium structure of complex plasmas while considering an external magnetic field. The traditional Yukawa potential and a modified Yukawa potential according to Shukla et al. [Phys. Lett. A 291, 413 (2001); Shukla and Mendonca, Phys. Scr. T113 82 (2004)] and Salimullah et al. [Phys. Plasmas 10, 3047 (2003)] respectively, are employed to account for the interaction of the charged dust particles. It is found that the collisions between neutral gas and charged dust particles have minor effects on the 2D equilibrium structure of the system. Based on the modified Yukawa potential, studies on the 2D equilibrium structure show that the traditional Yukawa potential is still suitable for describing the magnetized complex plasmas, even if the shielding distance of charged dust particles is affected by the strong external magnetic field.

  3. Extracting structural information from the polarization dependence of one- and two-dimensional sum frequency generation spectra.

    Science.gov (United States)

    Laaser, Jennifer E; Zanni, Martin T

    2013-07-25

    We present ways in which pulse sequences and polarizations can be used to extract structural information from one- and two-dimensional vibrational sum frequency generation (2D SFG) spectra. We derive analytic expressions for the polarization dependence of systems containing coupled vibrational modes, and we present simulated spectra to identify the features of different molecular geometries. We discuss several useful polarization combinations for suppressing strong diagonal peaks and emphasizing weaker cross-peaks. We investigate unique capabilities of 2D SFG spectra for obtaining structural information about SFG-inactive modes and for identifying coupled achiral chromophores. This work builds on techniques that have been developed for extracting structural information from 2D IR spectra. This paper discusses how to utilize these concepts in 2D SFG experiments to probe multioscillator systems at interfaces. The sample code for calculating polarization dependence of 1D and 2D SFG spectra is provided in the Supporting Information .

  4. Detailed study of the TE band structure of two dimensional metallic photonic crystals with square symmetry

    Energy Technology Data Exchange (ETDEWEB)

    Sedghi, Aliasghar [Islamic Azad University, Shabestar (Iran, Islamic Republic of); Valiaghaie, Soma [Islamic Azad University, Sanandaj (Iran, Islamic Republic of); Soufiani, Ahad Rounaghi [Islamic Azad University, Sufian (Iran, Islamic Republic of)

    2014-10-15

    By virtue of the efficiency of the Dirichlet-to-Neumann map method, we have calculated, for H-polarization (TE mode), the band structure of 2D photonic crystals with a square lattice composed of metallic rods embedded in an air background. The rod in the unit cell is chosen to be circular in shape. Here, from a practical point of view, in order to obtain maximum band gaps, we have studied the band structure as a function of the size of the rods. We have also studied the flat bands appearing in the band structures and have shown that for frequencies around the surface plasmon frequency, the modes are highly localized at the interface between the metallic rods and the air background.

  5. Detailed Study of the TE band structure of two dimensional metallic photonic crystals with square symmetry

    Science.gov (United States)

    Sedghi, Aliasghar; Valiaghaie, Soma; Soufiani, Ahad Rounaghi

    2014-10-01

    By virtue of the efficiency of the Dirichlet-to-Neumann map method, we have calculated, for H-polarization (TE mode), the band structure of 2D photonic crystals with a square lattice composed of metallic rods embedded in an air background. The rod in the unit cell is chosen to be circular in shape. Here, from a practical point of view, in order to obtain maximum band gaps, we have studied the band structure as a function of the size of the rods. We have also studied the flat bands appearing in the band structures and have shown that for frequencies around the surface plasmon frequency, the modes are highly localized at the interface between the metallic rods and the air background.

  6. Structured mirror array for two-dimensional collimation of a chromium beam in atom lithography

    Institute of Scientific and Technical Information of China (English)

    Zhang Wan-Jing; Ma Yan; Li Tong-Bao; Zhang Ping-Ping; Deng Xiao; Chen Sheng; Xiao Sheng-Wei

    2013-01-01

    Direct-write atom lithography,one of the potential nanofabrication techniques,is restricted by some difficulties in producing optical masks for the deposition of complex structures.In order to make further progress,a structured mirror array is developed to transversely collimate the chromium atomic beam in two dimensions.The best collimation is obtained when the laser red detunes by natural line-width of transition 7S3 → 7P40 of the chromium atom.The collimation ratio is 0.45 vertically (in x axis),and it is 0.55 horizontally (in y axis).The theoretical model is also simulated,and success of our structured mirror array is achieved.

  7. Modeling and process design for laser interference lithography used in fabricating two-dimensional periodic structures

    NARCIS (Netherlands)

    Bostan, C.G.; Ridder, de R.M.; Dorssen, van I.; Wolferen, van H.A.G.M.; Kuipers, L.; Hulst, van N.F.

    2002-01-01

    Laser interference lithography (LIL) is a technique that can be successfully used for realization of 2D periodic structures, with excellent uniformity over large areas. However, detailed modeling is needed in order to extract the optimum design parameters. In this paper, we refer to a design procedu

  8. Simple vibration modeling of structural fuzzy with continuous boundary by including two-dimensional spatial memory

    DEFF Research Database (Denmark)

    Friis, Lars; Ohlrich, Mogens

    2008-01-01

    -dimensional continuous boundary. Additionally, a simple method for determining the so-called equivalent coupling factor is presented. The validity of this method is demonstrated by numerical simulations of the vibration response of a master plate structure with fuzzy attachments. It is revealed that the method performs...

  9. Fundamental interactions of vortical structures with boundary layers in two-dimensional flows

    DEFF Research Database (Denmark)

    Coutsias, E.A.; Lynov, Jens-Peter

    1991-01-01

    in the vorticity-stream function representation for bounded geometries. Fundamental processes connected to vorticity detachment from the boundary layers caused by the proximity of vortical structures are described. These processes include enstrophy enhancement of the main flow during bursting events, and pinning...

  10. Health Assessment of Large Two Dimensional Structures Using Limited Information: Recent Advances

    Directory of Open Access Journals (Sweden)

    Ajoy Kumar Das

    2012-01-01

    Full Text Available Some recent advances of a recently developed structural health assessment procedure proposed by the research team at the University of Arizona, commonly known as generalized iterative least-squares extended Kalman filter with unknown input (GILS-EKF-UI are presented. The procedure is a finite elements-based time-domain system-identification technique. It can assess structural health at the element level using only limited number of noise-contaminated responses. With the help of examples, it is demonstrated that the structure can be excited by multiple loadings simultaneously. The method can identify defects in various stages of degradation in single or multiple members and also relatively less severe defect. The defective element(s need not be in the substructure, but the defect detection capability increases if the defect spot is close to the substructure. Two alternatives are suggested to locate defect spot more accurately within a defective element. The paper advances several areas of GILS-EKF-UI to assess health of large structural systems.

  11. Study on the crystalline structure transition of syndiotactic polystyrene film during heat treatment by two-dimensional infrared correlation spectroscopy.

    Science.gov (United States)

    Li, Weizhen; Wu, Peiyi

    2009-08-01

    The crystal structure transition of syndiotactic polystyrene film from the helical conformation to the more stable planar zigzag conformation during a heating process was studied using Fourier transform infrared (FT-IR) spectroscopy in combination with two-dimensional (2D) correlation analysis and perturbation-correlation moving-window 2D analysis. The sequence of different conformations during the transition was investigated by analyzing two-dimensional FT-IR correlation spectra in the spectral ranges of 800-700 cm(-1) and 600-500 cm(-1). It was observed that the conformation of delta helical changes prior to gamma helical, and the gamma helical phase is faster than the alpha' planar zigzag phase. By utilizing the 2D asynchronous correlation spectra, the 744 cm(-1) band, which is usually incorporated in the broad 750 cm(-1) band, can now be uniquely attributed as the alpha' zigzag configuration for the first time. Furthermore, by employing thermal perturbation, the shorter helical segments consisting of m = 7-12 and m = 12-20 monomeric units were disturbed in a shorter time than the longer helical segments m = 20-30 during the heating process.

  12. Transition from two-dimensional photonic crystals to dielectric metasurfaces in the optical diffraction with a fine structure.

    Science.gov (United States)

    Rybin, Mikhail V; Samusev, Kirill B; Lukashenko, Stanislav Yu; Kivshar, Yuri S; Limonov, Mikhail F

    2016-08-05

    We study experimentally a fine structure of the optical Laue diffraction from two-dimensional periodic photonic lattices. The periodic photonic lattices with the C4v square symmetry, orthogonal C2v symmetry, and hexagonal C6v symmetry are composed of submicron dielectric elements fabricated by the direct laser writing technique. We observe surprisingly strong optical diffraction from a finite number of elements that provides an excellent tool to determine not only the symmetry but also exact number of particles in the finite-length structure and the sample shape. Using different samples with orthogonal C2v symmetry and varying the lattice spacing, we observe experimentally a transition between the regime of multi-order diffraction, being typical for photonic crystals to the regime where only the zero-order diffraction can be observed, being is a clear fingerprint of dielectric metasurfaces characterized by effective parameters.

  13. Transition from two-dimensional photonic crystals to dielectric metasurfaces in the optical diffraction with a fine structure

    Science.gov (United States)

    Rybin, Mikhail V.; Samusev, Kirill B.; Lukashenko, Stanislav Yu.; Kivshar, Yuri S.; Limonov, Mikhail F.

    2016-08-01

    We study experimentally a fine structure of the optical Laue diffraction from two-dimensional periodic photonic lattices. The periodic photonic lattices with the C4v square symmetry, orthogonal C2v symmetry, and hexagonal C6v symmetry are composed of submicron dielectric elements fabricated by the direct laser writing technique. We observe surprisingly strong optical diffraction from a finite number of elements that provides an excellent tool to determine not only the symmetry but also exact number of particles in the finite-length structure and the sample shape. Using different samples with orthogonal C2v symmetry and varying the lattice spacing, we observe experimentally a transition between the regime of multi-order diffraction, being typical for photonic crystals to the regime where only the zero-order diffraction can be observed, being is a clear fingerprint of dielectric metasurfaces characterized by effective parameters.

  14. Structural analysis of lime wood biodegraded by white rot fungi through infrared and two dimensional correlation spectroscopy techniques

    Science.gov (United States)

    Popescu, Carmen-Mihaela; Gradinariu, Petronela; Popescu, Maria-Cristina

    2016-11-01

    The action of the white rot fungi Phanerochaete crisosporium on the structure of lime wood (Tilia cordata) has been studied. The degree of decay was determined by weight loss, which was of 37% after 110 days. The samples were further analyzed by infrared and two dimensional correlation spectroscopy. The recorded spectra for different intervals of decay indicate variations in the intensities and width or wavenumber shifts of the bands assigned, both, for lignin and carbohydrates. An increase in the intensities of the bands from the carbonyl region due to formation of new structures, accompanied by the reduction of the methoxyl and methyl/methylene groups in lignin was evidenced. Further, the differences between reference and decayed wood spectra were examined in detail using 2DCOS spectroscopy and the second derivative analysis and the sequential order of modifications were established.

  15. On the two-dimensional metallic state in silicon-on-insulator structures

    OpenAIRE

    Brunthaler, G.; Prinz, A.; Pillwein, G.; Lindelof, P. E.; Ahopelto, J.

    2002-01-01

    It is shown that the electronic conduction in silicon-on-insulator (SOI) layers exhibits a metallic regime which is very similar to that in high-mobility Si-metal oxide semiconductor structures (MOS). The peak in the electron mobility versus density, the strong drop in resistivity and the critical concentration for the metal-insulator transition are all consistent. On the basis of our SOI data for the temperature and in-plane magnetic field dependence of the resistivity, we discuss several mo...

  16. Two-dimensional analysis of coupled heat and moisture transport in masonry structures

    Science.gov (United States)

    Krejčí, Tomáš

    2016-06-01

    Reconstruction and maintenance of historical buildings and bridges require good knowledge of temperature and moisture distribution. Sharp changes in the temperature and moisture can lead to damage. This paper describes analysis of coupled heat and moisture transfer in masonry based on two-level approach. Macro-scale level describes the whole structure while meso-scale level takes into account detailed composition of the masonry. The two-level approach is very computationally demanding and it was implemented in parallel. The two-level approach was used in analysis of temperature and moisture distribution in Charles bridge in Prague, Czech Republic.

  17. Simulations of super-structure domain walls in two dimensional assemblies of magnetic nanoparticles

    DEFF Research Database (Denmark)

    Jordanovic, Jelena; Beleggia, Marco; Schiøtz, Jakob

    2015-01-01

    taking the role of the atomic spins. The coupling is, however, different. The superspins interact only by dipolar interactions as exchange coupling between individual nanoparticles may be neglected due to interparticle spacing. We observe that it is energetically favorable to introduce domain walls...... oriented along the long dimension of nanoparticle assemblies rather than along the short dimension. This is unlike what is typically observed in continuous magnetic materials, where the exchange interaction introduces an energetic cost proportional to the area of the domain walls. Structural disorder...

  18. Solution of the two-dimensional compressible Navier-Stokes equations on embedded structured multiblock meshes

    Science.gov (United States)

    Szmelter, J.; Marchant, M. J.; Evans, A.; Weatherill, N. P.

    A cell vertex finite volume Jameson scheme is used to solve the 2D compressible, laminar, viscous fluid flow equations on locally embedded multiblock meshes. The proposed algorithm is applicable to both the Euler and Navier-Stokes equations. It is concluded that the adaptivity method is very successful in efficiently improving the accuracy of the solution. Both the mesh generator and the flow equation solver which are based on a quadtree data structure offer good flexibility in the treatment of interfaces. It is concluded that methods under consideration lead to accurate flow solutions.

  19. Experimental investigation of the structure of supersonic two-dimensional air microjets

    Science.gov (United States)

    Timofeev, Ivan; Aniskin, Vladimir; Mironov, Sergey

    2016-10-01

    We have experimentally studied the structure of supersonic underexpanded room-temperature air jets escaping from micronozzles with characteristic heights from 47 to 175 µm and widths within 2410-3900 µm in a range of Reynolds numbers of 1280-9460. The dimensions of the first shock cell are established. The supersonic core length of supersonic underexpanded air jets has been determined for the first time. A flow regime with a large supersonic core length has observed for air jets escaping from a 47µm high nozzle.

  20. Two-dimensional crystal CuS—electronic and structural properties

    Science.gov (United States)

    Soares, Antonio L., Jr.; Dos Santos, Egon C.; Morales-García, A.; Heine, Thomas; De Abreu, Heitor A.; Duarte, Hélio A.

    2017-03-01

    Covellite is a metallic layered mineral with rather strong interlayer interaction. Recently, synthesis of covellite nanosheets of 3.2 nm thickness was reported (Du et al 2012 Nat. Commun. 3 1177), which raises the question: ‘What is the thinnest possible covellite nanosheet?’ Based on density functional/plane waves calculations, we have shown that graphene-like structure CuS (1L-CuS) is unstable but can be stabilized on a support. Here, however, we demonstrate that the three layered CuS (3L-CuS) with thickness of 0.773 nm (including the atomic radius of the outer plans atoms) is predicted to be intrinsically stable, as confirmed by phonon analysis and Born-Oppenheimer molecular dynamics simulations, with 3L-CuS about 0.15 eV per CuS less stable than the bulk. Interestingly, the electronic band structure shows metallic character with four bands crossing the Fermi level. The nature of chemical bonding is confirmed by a detailed topological analysis of the electron density.

  1. Electronic structure and optical properties of the single crystal and two-dimensional structure of CdWO{sub 4} from first principles

    Energy Technology Data Exchange (ETDEWEB)

    Babamoradi, Mohsen, E-mail: babamoradi@iust.ac.ir [Department of Physics, Iran University of Science and Technology, Narmak, 16846-13114 Tehran (Iran, Islamic Republic of); Liyai, Mohammad Reza [Department of Physics, Iran University of Science and Technology, Narmak, 16846-13114 Tehran (Iran, Islamic Republic of); Azimirad, Rouhollah, E-mail: azimirad@yahoo.com [Malek-Ashtar University of Technology, Tehran (Iran, Islamic Republic of); Salehi, Hamdollah, E-mail: salehi_h@scu.ac.ir [Department of Physics, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz (Iran, Islamic Republic of)

    2017-04-15

    In this paper, we have investigated the electronic structure and optical properties of the single crystal and two-dimensional (2D) structure of cadmium tungstate (CdWO{sub 4}). This investigation includes calculation of the density of states (DOS), dielectric tensor elements and reflectivity. All the calculations have been done by full potential augmented plane waves plus local orbitals (FP-APW+lo) with Wien2k code. The calculated band gaps for the single crystal and 2D structure along [010] direction are 4.2 and 5.02 eV, respectively. The results show that in the 2D structure of CdWO{sub 4}, the electron density of the surface oxygen atoms is much more than the electron density of the inside oxygen atoms. This difference in the density has the main role in the optical properties. The results of the dielectric tensor elements and reflectivity for the single crystal are in good agreement with the experimental values. The results of the dielectric tensor elements and reflectivity for the 2D structure in comparison with the single crystal have shown that the intensity and place of the calculated peaks reduced and shifted, respectively. These results can be related to the surface oxygen atoms and thickness of the 2D structure.

  2. BASIN STRUCTURE FROM TWO-DIMENSIONAL SEISMIC REFLECTION DATA, CRAZY MOUNTAINS BASIN, MONTANA

    Energy Technology Data Exchange (ETDEWEB)

    David J. Taylor

    2003-08-01

    Some 140 miles of multichannel seismic reflection data, acquired commercially in the 1970's, were reprocessed by the U.S. Geological Survey in late 2000 and early 2001 to interpret the subsurface geology of the Crazy Mountains Basin, an asymmetric Laramide foreland basin located in south-central Montana. The seismic data indicate that the northwestern basin margin is controlled by a thrust fault that places basement rocks over a thick (22,000 feet) sequence of Paleozoic and Mesozoic sedimentary rocks to the south. From the deep basin trough, Paleozoic through Tertiary rocks slope gently upward to the south and southeast. The northern boundary of the basin, which is not imaged well by the seismic data, appears to be folded over a basement ridge rather than being truncated against a fault plane. Seismic data along the basin margin to the south indicate that several fault controlled basement highs may have been created by thin-skinned tectonics where a series of shallow thrust faults cut Precambrian, Paleozoic, and early Mesozoic rocks, whereas, in contrast, Cretaceous and Tertiary strata are folded. The data are further interpreted to indicate that this fault-bounded asymmetric basin contains several structures that possibly could trap hydrocarbons, provided source rocks, reservoirs, and seals are present. In addition, faults in the deep basin trough may have created enough fracturing to enhance porosity, thus developing ''sweet spots'' for hydrocarbons in basin-centered continuous gas accumulations.

  3. Two Dimensional LIF Measurements and Potential Structure of Ion Beam Formation in an Argon Helicon Plasma

    Science.gov (United States)

    Aguirre, Evan; Scime, Earl; Good, Timothy

    2016-10-01

    We report 2-dimensional, spatially resolved observations of ion beam formation in an expanding helicon plasma. Previous studies found that a current free double layer (CFDL) spontaneously arises at low pressure, below 1 mT. We use Laser Induced Fluorescence (LIF), a non-perturbative diagnostic to measure the ion velocity distribution functions (IVDFs) of argon ions both parallel and perpendicular to the background magnetic field. We report ion beam formation as a function of the expansion chamber magnetic field (0-108 G). The ion beam appears peaked in the center of the expansion chamber and decays over a few centimeters radially. We also report the potential structure of the plasma obtained with a planar Langmuir probe. To obtain meaningful Langmuir probe measurements, averages of tens of current-voltage are needed to reduce the effects of large electrostatic fluctuations that arise in plasmas that generate ion beams. We report the dependence of density, electron temperature, and floating potential on radial and axial position in the expansion plume. NSF Award PHYS-1360278.

  4. On the theory of elastic properties of two-dimensional hexagonal structures

    Science.gov (United States)

    Davydov, S. Yu.; Posrednik, O. V.

    2015-04-01

    The properties of graphene and graphene-like materials (GLMs) have been considered using the Harrison bond-orbital method, within which the stability of GLMs with a high bond ionicity has been analyzed. For purely covalent crystals (graphene, silicene, and germanen) and GLMs with a low bond ionicity, the anharmonic elastic properties (Grüneisen constant, pressure and temperature dependences of the bulk modulus) have been considered. Within the Keating force constant model, the second- and third-order elastic constants and the pressure dependence of the second-order elastic constants have been determined. The parameters of the previously proposed empirical potential have been determined. The results obtained are compared with the available experimental data and calculation results of other studies.

  5. Two-dimensional structure of mountain wave observed by aircraft during the PYREX experiment

    Directory of Open Access Journals (Sweden)

    J. L. Attié

    Full Text Available This study presents an experimental analysis from aircraft measurements above the Pyrenees chain during the PYREX experiment. The Pyrenees chain, roughly WE oriented, is a major barrier for northerly and southerly airflows. We present a case of southerly flow (15 October 1990 and three successive cases of northerly flows above the Pyrenees (14, 15 and 16 November 1990 documented by two aircraft. The aircraft have described a vertical cross section perpendicular to the Pyrenean ridge. This area is described via the thermodynamical and dynamical fields which have a horizontal resolution of 10 km. Three methods for computing the vertical velocity of the air are presented. The horizontal advection terms which play a role in the budget equations are also evaluated. The altitude turbulence zone of 15 October are shown via turbulent fluxes, turbulent kinetic energy (TKE, dissipation rate of TKE and inertial length-scale. A comparison of results obtained by eddy-correlation and inertial-dissipation method is presented. The experimental results show a warm and dry downdraft for the southerly flow with large values for advection terms. All the mountain wave cases are also shown to present an important dynamical perturbation just above the Pyrenees at upper altitudes.

  6. Band structure of magneto-metallo-dielectric photonic crystals with hybrid one- and two-dimensional periodicity

    Energy Technology Data Exchange (ETDEWEB)

    Reyes-Ayona, E. [Instituto de Fisica, Benemerita Universidad Autonoma de Puebla, Apartado Postal J-48, Puebla 72570 (Mexico); Instituto Nacional de Astrofisica Optica y Electronica, Apartado Postal 51, Puebla 72000 (Mexico); Halevi, P. [Instituto Nacional de Astrofisica Optica y Electronica, Apartado Postal 51, Puebla 72000 (Mexico)

    2012-06-15

    We calculate the band structure of a magneto-metallo-dielectric photonic crystal (PC) with hybrid one- and two-dimensional periodicity. Namely, the permittivity (permeability) is periodic in a plane (single direction). The metallic and magnetic properties are described, respectively, by means of the Drude model and a specific permeability model for Barium-M ferrite. Because of the dispersion of both the permeability and the permittivity, we obtain a non-standard eigenvalue problem which is possible to solve by means of a linearization technique. We found that the first band of this PC is very sensitive to the filling fraction of the magnetic component: by changing this fraction from 0.20 to 0.16 the slope - and effective index of refraction - changes from positive to negative. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  7. Layer-dependent anisotropic electronic structure of freestanding quasi-two-dimensional Mo S 2

    KAUST Repository

    Hong, Jinhua

    2016-02-29

    The anisotropy of the electronic transition is a well-known characteristic of low-dimensional transition-metal dichalcogenides, but their layer-thickness dependence has not been properly investigated experimentally until now. Yet, it not only determines the optical properties of these low-dimensional materials, but also holds the key in revealing the underlying character of the electronic states involved. Here we used both angle-resolved electron energy-loss spectroscopy and spectral analysis of angle-integrated spectra to study the evolution of the anisotropic electronic transition involving the low-energy valence electrons in the freestanding MoS2 layers with different thicknesses. We are able to demonstrate that the well-known direct gap at 1.8 eV is only excited by the in-plane polarized field while the out-of-plane polarized optical gap is 2.4 ± 0.2 eV in monolayer MoS2. This contrasts with the much smaller anisotropic response found for the indirect gap in the few-layer MoS2 systems. In addition, we determined that the joint density of states associated with the indirect gap transition in the multilayer systems and the corresponding indirect transition in the monolayer case has a characteristic three-dimensional-like character. We attribute this to the soft-edge behavior of the confining potential and it is an important factor when considering the dynamical screening of the electric field at the relevant excitation energies. Our result provides a logical explanation for the large sensitivity of the indirect transition to thickness variation compared with that for the direct transition, in terms of quantum confinement effect.

  8. Visualization of Structured Packing with Laser Induced Fluorescence Technique:Two-Dimensional Measurement of Liquid Concentration Distribution

    Institute of Scientific and Technical Information of China (English)

    刘伯潭; 申言同; 张会书; 刘春江; 唐忠利; 袁希钢

    2016-01-01

    A method of using laser induced fluorescence(LIF)technique was applied to two-dimensional meas-urement of the liquid concentration distribution in the 250Y structured packing sheet. The experimental structured packing sheet was made of perspex so that the laser could pass through it. The visualization of the distribution of the liquid concentration in the structured packing sheet was realized. The calibration of the thickness and liquid concentration was carried out firstly and the regression formulaI=kcd was acquired, in which concentrationc and the liquid film thicknessd were both considered. Then the liquid feed of uniform tracer(rhodamine)concentration entered the perspex structured packing from the top under different spraying densities. The corresponding thickness of liquid film on the packing was calculated. Finally, tracer(rhodamine)with a high concentration was injected only at one fixed point of the structured packing under different spraying densities of the liquid. With the known liquid film thickness, the concentration distribution of the tracer can be calculated inside the structured packing sheet.

  9. Structure of two-dimensional and three-dimensional turbulent boundary layers with sparsely distributed roughness elements

    Science.gov (United States)

    George, Jacob

    The present study deals with the effects of sparsely distributed three-dimensional elements on two-dimensional (2-D) and three-dimensional (3-D) turbulent boundary layers (TBL) such as those that occur on submarines, ship hulls, etc. This study was achieved in three parts: Part 1 dealt with the cylinders when placed individually in the turbulent boundary layers, thereby considering the effect of a single perturbation on the TBL; Part 2 considered the effects when the same individual elements were placed in a sparse and regular distribution, thus studying the response of the flow to a sequence of perturbations; and in Part 3, the distributions were subjected to 3-D turbulent boundary layers, thus examining the effects of streamwise and spanwise pressure gradients on the same perturbed flows as considered in Part 2. The 3-D turbulent boundary layers were generated by an idealized wing-body junction flow. Detailed 3-velocity-component Laser-Doppler Velocimetry (LDV) and other measurements were carried out to understand and describe the rough-wall flow structure. The measurements include mean velocities, turbulence quantities (Reynolds stresses and triple products), skin friction, surface pressure and oil flow visualizations in 2-D and 3-D rough-wall flows for Reynolds numbers, based on momentum thickness, greater than 7000. Very uniform circular cylindrical roughness elements of 0.38mm, 0.76mm and 1.52mm height (k) were used in square and diagonal patterns, yielding six different roughness geometries of rough-wall surface. For the 2-D rough-wall flows, the roughness Reynolds numbers, k +, based on the element height (k) and the friction velocity (Utau), range from 26 to 131. Results for the 2-D rough-wall flows reveal that the velocity-defect law is similar for both smooth and rough surfaces, and the semi-logarithmic velocity-distribution curve is shifted by an amount DeltaU/U, depending on the height of the roughness element, showing that Delta U/Utau is a function

  10. Two-dimensional deterministic photonic band gap structures based on the quasiperiodic sequences at millimeter wave frequencies

    Directory of Open Access Journals (Sweden)

    Y. Trabelsi

    2011-08-01

    Full Text Available Two-dimensional quasi-periodic band gap structures were investigated theoretically in microwave frequency range. Quasiperiodic photonic crystal based on the square range, arranged in a quasi-periodical fashion which follows Thue Morse or Fibonaci period substitutional sequences were obtained by the inflation rules emerging from the quasi-periodic sequence. The introduction of 2D quasi-periodicity distribution like Thue Morse or Fibonacci order and deterministic aperiodicity give some interesting microwave properties and offers amultitude of adjacent pseudo-band gap in different frequency range. The potential of photonic structures are explored by varying the structural parameters. The photonic band gap formation was explored as function of geometries of the structures such as pillar radius and parameters of quasi-periodical sequences. The electromagnetic field distribution can be described as a quasi-localized state varied by some defect carried by Thue Morse order. These structures provide interesting properties, which could be used to design novelmicrowave devices.

  11. Two-dimensional IR spectroscopy and segmental 13C labeling reveals the domain structure of human γD-crystallin amyloid fibrils.

    Science.gov (United States)

    Moran, Sean D; Woys, Ann Marie; Buchanan, Lauren E; Bixby, Eli; Decatur, Sean M; Zanni, Martin T

    2012-02-28

    The structural eye lens protein γD-crystallin is a major component of cataracts, but its conformation when aggregated is unknown. Using expressed protein ligation, we uniformly (13)C labeled one of the two Greek key domains so that they are individually resolved in two-dimensional (2D) IR spectra for structural and kinetic analysis. Upon acid-induced amyloid fibril formation, the 2D IR spectra reveal that the C-terminal domain forms amyloid β-sheets, whereas the N-terminal domain becomes extremely disordered but lies in close proximity to the β-sheets. Two-dimensional IR kinetics experiments show that fibril nucleation and extension occur exclusively in the C-terminal domain. These results are unexpected because the N-terminal domain is less stable in the monomer form. Isotope dilution experiments reveal that each C-terminal domain contributes two or fewer adjacent β-strands to each β-sheet. From these observations, we propose an initial structural model for γD-crystallin amyloid fibrils. Because only 1 μg of protein is required for a 2D IR spectrum, even poorly expressing proteins can be studied under many conditions using this approach. Thus, we believe that 2D IR and protein ligation will be useful for structural and kinetic studies of many protein systems for which IR spectroscopy can be straightforwardly applied, such as membrane and amyloidogenic proteins.

  12. Aerosol assisted fabrication of two dimensional ZnO island arrays and honeycomb patterns with identical lattice structures

    Directory of Open Access Journals (Sweden)

    Mitsuhiro Numata

    2010-11-01

    Full Text Available Two dimensional island arrays and honeycomb patterns consisting of ZnO nanocrystal clusters were fabricated on predefined TiO2 seed patterns prepared by vacuum free, aerosol assisted wet-chemical synthesis. The TiO2 seed patterns were prepared by applying an aerosol of a water soluble titanium complex on hexagonally close-packed polystyrene bead arrays for different lengths of time. Scanning electron microscopy revealed that a dot array grows into a honeycomb shape as increasing amounts of the precursor were deposited. ZnO nucleation on substrates with a dot array and honeycomb patterns resulted in the formation of two discrete patterns with contrasting fill fractions of the materials.

  13. Two-dimensional NMR spectroscopy links structural moieties of soil organic matter to the temperature sensitivity of its decomposition

    Science.gov (United States)

    Soucemarianadin, Laure; Erhagen, Björn; Öquist, Mats; Nilsson, Mats; Schleucher, Jürgen

    2015-04-01

    Soil organic matter (SOM) represents a huge carbon pool, specifically in boreal ecosystems. Warming-induced release of large amounts of CO2 from the soil carbon pool might become a significant exacerbating feedback to global warming, if decomposition rates of boreal soils were more sensitive to increased temperatures. Despite a large number of studies dedicated to the topic, it has proven difficult to elucidate how the organo-chemical composition of SOM influences its decomposition, or its quality as a substrate for microbial metabolism. A great part of this challenge results from our inability to achieve a detailed characterization of the complex composition of SOM on the level of molecular structural moieties. 13C nuclear magnetic resonance (NMR) spectroscopy is a common tool to characterize SOM. However, SOM is a very complex mixture and the chemical shift regions distinguished in the 13C NMR spectra often represent many different molecular fragments. For example, in the carbohydrates region, signals of all monosaccharides present in many different polymers overlap. This overlap thwarts attempts to identify molecular moieties, resulting in insufficient information to characterize SOM composition. We applied two-dimensional (2D) NMR to characterize SOM with highly increased resolution. We directly dissolved finely ground litters and forest floors'fibric and humic horizons'of both coniferous and deciduous boreal forests in dimethyl sulfoxide and analyzed the resulting solution with a 2D 1H-13C NMR experiment. In the 2D planes of these spectra, signals of CH groups can be resolved based on their 13C and 1H chemical shifts, hence the resolving power and information content of these NMR spectra is hugely increased. The 2D spectra indeed resolved overlaps observed in 1D 13C spectra, so that hundreds of distinct CH groups could be observed and many molecular fragments could be identified. For instance, in the aromatics region, signals from individual lignin units could

  14. Real-space and plane-wave hybrid method for electronic structure calculations for two-dimensional materials

    Science.gov (United States)

    Do, V. Nam; Le, H. Anh; Vu, V. Thieu

    2017-04-01

    We propose a computational approach to combining the plane-wave method and the real-space treatment to describe the periodic variation in the material plane and the decay of wave functions from the material surfaces. The proposed approach is natural for two-dimensional material systems and thus may circumvent some intrinsic limitations involving the artificial replication of material layers in traditional supercell methods. In particular, we show that the proposed method is easy to implement and, especially, computationally effective since low-cost computational algorithms, such as iterative and recursive techniques, can be used to treat matrices with block tridiagonal structure. Using this approach we show first-principles features that supplement the current knowledge of some fundamental issues in bilayer graphene systems, including the coupling between the two graphene layers, the preservation of the σ band of monolayer graphene in the electronic structure of the bilayer system, and the differences in low-energy band structure between the AA- and AB-stacked configurations.

  15. Two-dimensional magnetotelluric model of deep resistivity structure in the Bodie-Aurora district of California

    Science.gov (United States)

    Sampson, Jay A.

    2006-01-01

    Introduction: Magnetotelluric data were acquired during October 2001 by the U.S. Geological Survey (USGS) as part of a study to examine the structural nature of basins in the transition zone between the Sierra Nevada Mountains of California and the Basin and Range province of Nevada. Magnetotelluric (MT) geophysical studies assist the mapping of geologic structure and the inference of lithologic packages that are concealed beneath the Earth's surface. The Basin and Range province has a complicated geologic history, which includes extension and compression of the Earth's crust to form the basins and ranges that blanket much of Nevada. The basins and ranges in the vicinity of this study trend northeastward and are bounded by steeply dipping strike slip faults. Interestingly, deep east-west magnetic trends occur in the aeromagnetic data of this study area indicating that the northeast-trending basins and ranges represent only thin-skinned deformation at the surface with an underlying east-west structure. To investigate this issue, MT data were acquired at seven stations in eastern California, 20 km east of Mono Lake. The purpose of this report is to present a two-dimensional apparent resistivity model of the MT data acquired for this study.

  16. Dual curved photonic crystal ring resonator based channel drop filter using two-dimensional photonic crystal structure

    Energy Technology Data Exchange (ETDEWEB)

    Chhipa, Mayur Kumar, E-mail: mayurchhipa1@gmail.com [Deptt. of Electronics and Communication Engineering, Government Engineering College Ajmer Rajasthan INDIA (India); Dusad, Lalit Kumar [Rajasthan Technical University Kota, Rajasthan (India)

    2016-05-06

    In this paper channel drop filter (CDF) is designed using dual curved photonic crystal ring resonator (PCRR). The photonic band gap (PBG) is calculated by plane wave expansion (PWE) method and the photonic crystal (PhC) based on two dimensional (2D) square lattice periodic arrays of silicon (Si) rods in air structure have been investigated using finite difference time domain (FDTD) method. The number of rods in Z and X directions is 21 and 20 respectively with lattice constant 0.540 nm and rod radius r = 0.1 µm. The channel drop filter has been optimized for telecommunication wavelengths λ = 1.591 µm with refractive indices 3.533. In the designed structure further analysis is also done by changing whole rods refractive index and it has been observed that this filter may be used for filtering several other channels also. The designed structure is useful for CWDM systems. This device may serve as a key component in photonic integrated circuits. The device is ultra compact with the overall size around 123 µm{sup 2}.

  17. Syntheses and Crystal Structures of Two Two-dimensional Coordination Polymers with 2,3-Dimethylpyrazine-1,4-dioxide and Thiocyanate as Mixed Bridge Ligands

    Institute of Scientific and Technical Information of China (English)

    SHI Jing-Min; LI Wei-Nan; ZHANG Feng-Xia; ZHANG Xia; LIU Lian-Dong

    2007-01-01

    Two two-dimensional coordination polymers,[Cd(μ1,3-SCN-)2(μ1,6-L)]n 1 and [Co(μ1,3-SCN-)2(μ1,6-L)]n 2,have been synthesized with 2,3-dimethylpyrazine-1,4-dioxide (L) and thiocyanate as mixed bridging ligands,and their crystal structures were determined by X-ray crystallography.Both crystals belong to monoclinic system,space group C2/c.The other crystal parameters are as follows:for complex 1:a = 9.732(3),b = 14.658(5),c = 8.811(3) (A),β =102.935(4)°,Z = 4,V = 1225.1(7)(A)3,CsHsCdN4O2S2,Mr = 368.71,Dc.-- 1.999 g/cm3,F(000) =720 andμ = 2.117 mm-1;for complex 2:a = 9.528(7),b = 14.563(11),c = 8.415(6) (A),β =102.195(9)°,V= 1141.3(14) (A)3,Z = 4,C8H8CoN4O2S2,Mr = 315.23,Dc = 1.835 g/cm3,F(000) =636 andμ = 1.863 mm-1.The two complexes show similar two-dimensional sheet structures.Along the c axis one-dimensional chains are constructed by the coordination of Cd(Ⅱ) (or Co(Ⅱ))ions with μ1,6-L bridging ligand,and the μ1,3-SCN- bridging ligands make the chains connect to each other,resulting in the formation of a two-dimensional sheet on the ac plane.

  18. Multilocality and fusion rules on the generalized structure functions in two-dimensional and three-dimensional Navier-Stokes turbulence.

    Science.gov (United States)

    Gkioulekas, Eleftherios

    2016-09-01

    Using the fusion-rules hypothesis for three-dimensional and two-dimensional Navier-Stokes turbulence, we generalize a previous nonperturbative locality proof to multiple applications of the nonlinear interactions operator on generalized structure functions of velocity differences. We call this generalization of nonperturbative locality to multiple applications of the nonlinear interactions operator "multilocality." The resulting cross terms pose a new challenge requiring a new argument and the introduction of a new fusion rule that takes advantage of rotational symmetry. Our main result is that the fusion-rules hypothesis implies both locality and multilocality in both the IR and UV limits for the downscale energy cascade of three-dimensional Navier-Stokes turbulence and the downscale enstrophy cascade and inverse energy cascade of two-dimensional Navier-Stokes turbulence. We stress that these claims relate to nonperturbative locality of generalized structure functions on all orders and not the term-by-term perturbative locality of diagrammatic theories or closure models that involve only two-point correlation and response functions.

  19. Integral field optical spectroscopy of a representative sample of ULIRGs: II. Two-dimensional kpc-scale extinction structure

    CERN Document Server

    García-Marín, M; Arribas, S

    2009-01-01

    We investigate the two-dimensional kpc-scale structure of the extinction in a representative sample of local ULIRGs using the Halpha/Hbeta line ratio.We use optical integral field spectroscopy obtained with the INTEGRAL instrument at the William Herschel Telescope. Complementary optical and near-IR high angular resolution HST images have also been used. The extinction exhibits a very complex and patchy structure in ULIRGs on kpc scales, from basically transparent regions to others deeply embedded in dust (Av~0.0 to Av~8.0 mag). Nuclear extinction covers a broad range in Av from 0.6 to 6 mag, 69% of the nuclei having Av>2.0 mag. Extinction in the external regions is substantially lower than in the nuclei with 64% of the ULIRGs in the sample having median Av of less than 2 mag for the entire galaxy. While post-coalescence nuclei tend to cluster around Av values of 2 to 3 mag, pre-coalescence nuclei appear more homogeneously distributed over the entire 0.4 mag

  20. Two-dimensional infrared spectroscopic study on the thermally induced structural changes of glutaraldehyde-crosslinked collagen.

    Science.gov (United States)

    Tian, Zhenhua; Wu, Kun; Liu, Wentao; Shen, Lirui; Li, Guoying

    2015-04-05

    The thermal stability of collagen solution (5 mg/mL) crosslinked by glutaraldehyde (GTA) [GTA/collagen (w/w)=0.5] was measured by differential scanning calorimetry and Fourier transform infrared spectroscopy (FTIR), and the thermally induced structural changes were analyzed using two-dimensional (2D) correlation spectra. The denaturation temperature (Td) and enthalpy change (ΔH) of crosslinked collagen were respectively about 27°C and 88 J/g higher than those of native collagen, illuminating the thermal stability increased. With the increase of temperature, the red-shift of absorption bands and the decreased AIII/A1455 value obtained from FTIR spectra indicated that hydrogen bonds were weakened and the unwinding of triple helix occurred for both native and crosslinked collagens; whereas the less changes in red-shifting and AIII/A1455 values for crosslinked collagen also confirmed the increase in thermal stability. Additionally, the 2D correlation analysis provided information about the thermally induced structural changes. In the 2D synchronous spectra, the intensities of auto-peaks at 1655 and 1555 cm(-1), respectively assigned to amide I band (CO stretching vibration) and amide II band (combination of NH bending and CN stretching vibrations) in helical conformation were weaker for crosslinked collagen than those for native collagen, indicating that the helical structure of crosslinked collagen was less sensitive to temperature. Moreover, the sequence of the band intensity variations showed that the band at 1555 cm(-1) moved backwards owing to the addition of GTA, demonstrating that the response of helical structure of crosslinked collagen to the increased temperature lagged. It was speculated that the stabilization of collagen by GTA was due to the reinforcement of triple helical structure.

  1. Two-dimensional wide-band-gap II-V semiconductors with a dilated graphene-like structure

    Science.gov (United States)

    Zhang, Xue-Jing; Liu, Bang-Gui

    2016-12-01

    Since the advent of graphene, two-dimensional (2D) materials have become very attractive and there is growing interest in exploring new 2D materials beyond graphene. Here, through density-functional theory (DFT) calculations, we predict 2D wide-band-gap II-V semiconductor materials of M3X2 (M = Zn, Cd and X = N, P, As) with a dilated graphene-like honeycomb structure. In this structure the group-V X atoms form two X-atomic planes symmetrically astride the centering group-IIB M atomic plane. Our DFT calculation shows that 2D Zn3N2, Zn3P2 and Zn3As2 have direct band gaps of 2.87, 3.81 and 3.55 eV, respectively, and 2D Cd3N2, Cd3P2 and Cd3As2 exhibit indirect band gaps of 2.74, 3.51 and 3.29 eV, respectively. Each of the six 2D materials is shown to have effective carrier (either hole or electron) masses down to 0.03m 0-0.05m 0. The structural stability and feasibility of experimental realization of these 2D materials has been shown in terms of DFT phonon spectra and total energy comparison with related existing bulk materials. On the experimental side, there already are many similar two-coordinate structures of Zn and other transition metals in various organic materials. Therefore, these 2D semiconductors can enrich the family of 2D electronic materials and may have promising potential for achieving novel transistors and optoelectronic devices.

  2. Global Structure of Three Distinct Accretion Flows and Outflows around Black Holes through Two-Dimensional Radiation-Magnetohydrodynamic Simulations

    CERN Document Server

    Ohsuga, Ken

    2011-01-01

    We present the detailed global structure of black hole accretion flows and outflows through newly performed two-dimensional radiation-magnetohydrodynamic simulations. By starting from a torus threaded with weak toroidal magnetic fields and by controlling the central density of the initial torus, rho_0, we can reproduce three distinct modes of accretion flow. In model A with the highest central density, an optically and geometrically thick supercritical accretion disk is created. The radiation force greatly exceeds the gravity above the disk surface, thereby driving a strong outflow (or jet). Because of the mild beaming, the apparent (isotropic) photon luminosity is ~22L_E (where L_E is the Eddington luminosity) in the face-on view. Even higher apparent luminosity is feasible if we increase the flow density. In model B with a moderate density, radiative cooling of the accretion flow is so efficient that a standard-type, cold, and geometrically thin disk is formed at radii greater than ~7R_S (where R_S is the S...

  3. Two-dimensional MoS2 under ion irradiation: from controlled defect production to electronic structure engineering

    Science.gov (United States)

    Ghorbani-Asl, Mahdi; Kretschmer, Silvan; Spearot, Douglas E.; Krasheninnikov, Arkady V.

    2017-06-01

    Two-dimensional (2D) transition metal dichalcogenides (TMDs), like MoS2, have unique electronic and optical properties, which can further be tuned using ion bombardment and post-synthesis ion-beam mediated methods combined with exposure of the irradiated sample to precursor gases. The optimization of these techniques requires a complete understanding of the response of 2D TMDs to ion irradiation, which is affected by the reduced dimensionality of the system. By combining analytical potential molecular dynamics with first-principles calculations, we study the production of defects in free-standing MoS2 sheets under noble gas ion irradiation for a wide range of ion energies when nuclear stopping dominates, and assess the probabilities for different defects to appear. We show that depending on the incident angle, ion type and energy, sulfur atoms can be sputtered away predominantly from the top or bottom layers, creating unique opportunities for engineering mixed MoSX compounds where X are chemical elements from group V or VII. We study the electronic structure of such systems, demonstrate that they can be metals, and finally discuss how metal/semiconductor/metal junctions, which exhibit negative differential resistance, can be designed using focused ion beams combined with the exposure of the system to fluorine.

  4. Defining RNA motif-aminoglycoside interactions via two-dimensional combinatorial screening and structure-activity relationships through sequencing.

    Science.gov (United States)

    Velagapudi, Sai Pradeep; Disney, Matthew D

    2013-10-15

    RNA is an extremely important target for the development of chemical probes of function or small molecule therapeutics. Aminoglycosides are the most well studied class of small molecules to target RNA. However, the RNA motifs outside of the bacterial rRNA A-site that are likely to be bound by these compounds in biological systems is largely unknown. If such information were known, it could allow for aminoglycosides to be exploited to target other RNAs and, in addition, could provide invaluable insights into potential bystander targets of these clinically used drugs. We utilized two-dimensional combinatorial screening (2DCS), a library-versus-library screening approach, to select the motifs displayed in a 3×3 nucleotide internal loop library and in a 6-nucleotide hairpin library that bind with high affinity and selectivity to six aminoglycoside derivatives. The selected RNA motifs were then analyzed using structure-activity relationships through sequencing (StARTS), a statistical approach that defines the privileged RNA motif space that binds a small molecule. StARTS allowed for the facile annotation of the selected RNA motif-aminoglycoside interactions in terms of affinity and selectivity. The interactions selected by 2DCS generally have nanomolar affinities, which is higher affinity than the binding of aminoglycosides to a mimic of their therapeutic target, the bacterial rRNA A-site.

  5. Magnetic breakdown phenomenon in quasi-two-dimensional organic conductors: A quantum model inspired by a realistic band structure

    Science.gov (United States)

    Kim, Ju H.; Han, S. Y.; Brooks, J. S.

    1999-08-01

    We investigate the phenomenon of magnetic breakdown in quasi-two-dimensional organic conductors such as α-(ET)2KHg(SCN)4 and κ-(ET)2Cu(NCS)2 by constructing a tight-binding model based on a realistic band structure which is derived from the crystallographic data. We solve the model numerically to compute the magnetic field dependence of the magnetization and show that the present model accounts naturally for the experimentally observed magnetization oscillation frequencies that are forbidden in the semiclassical picture. The computed values of the fundamental and magnetic breakdown frequencies with no adjustable parameters are close to the experimentally measured values. For completeness, we carry out the computation for both canonical (fixed number of particles) and grand canonical (fixed chemical potential) ensembles, and show that the forbidden frequencies appear in both cases. Hence, the appearance of anomalous frequencies in the de Haas-van Alphen effect has a quantum-mechanical origin and arises from the interplay of electronic states from two partially occupied bands near the Fermi energy as a function of magnetic field. We also compute the temperature dependence of the magnetization and apply ad hoc the Lifshitz-Kosevich analysis to the amplitudes of the Fourier components at moderately high temperatures. This yields effective mass values for α-(ET)2KHg(SCN)4 in good agreement with experimental values.

  6. Development and optimization of scanning spreading resistance microscopy for measuring the two-dimensional carrier profile in solar cell structures

    Energy Technology Data Exchange (ETDEWEB)

    Eyben, Pierre; Hantschel, Thomas; Lorenz, Anne; Gestel, Dries van; John, Joachim [IMEC, Kapeldreef 75, 3001 Leuven (Belgium); Seidel, Felix [IMEC, Kapeldreef 75, 3001 Leuven (Belgium); TU Bergakademie Freiberg, Institut fuer Elektronik- und Sensormaterialien, Gustav-Zeuner-Str. 3, 09599 Freiberg (Germany); Schulze, Andreas; Vandervorst, Wilfried [IMEC, Kapeldreef 75, 3001 Leuven (Belgium); Instituut voor Kern- en Stralingsfysika, K.U. Leuven, Celestijnenlaan 200D, 3001 Leuven (Belgium); Castro, Angel Uruena de [IMEC, Kapeldreef 75, 3001 Leuven (Belgium); Department of Electrical Engineering (ESAT), Katholieke Universiteit Leuven, Oude Markt, 13, Bus 5005, 3000 Leuven (Belgium); Horzel, Joerg [SCHOTT Solar AG, Carl-Zeiss-Strasse 4, 63755 Alzenau (Germany)

    2011-03-15

    Within this work, we have explored the use of scanning spreading resistance microscopy (SSRM) on advanced solar cell structures. Three main topics, corresponding to three important needs, were targeted. First, we have analyzed the highly doped regions at the frontside of solar cells. The influence of the surface roughness, hindering the use of other techniques (e.g., secondary ion mass spectrometry, SIMS), and the phosphorus diffusion along grains for multicrystalline silicon (mc-Si) have been studied quantitatively as they may affect substantially the electrical properties of solar cells. Secondly, we have explored local backside contacts manufactured using new techniques like laser ablation followed by dopant diffusion. Having a better knowledge of the two-dimensional (2D)-dopant distribution is a subject of growing interest. Finally, we have studied electrical properties of grain-boundary and intragrain defects in polycrystalline silicon (pc-Si) layers as they may play a major role in the electrical performances of the solar cells. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  7. Hierarchical on-surface synthesis and electronic structure of carbonyl-functionalized one- and two-dimensional covalent nanoarchitectures

    Science.gov (United States)

    Steiner, Christian; Gebhardt, Julian; Ammon, Maximilian; Yang, Zechao; Heidenreich, Alexander; Hammer, Natalie; Görling, Andreas; Kivala, Milan; Maier, Sabine

    2017-03-01

    The fabrication of nanostructures in a bottom-up approach from specific molecular precursors offers the opportunity to create tailored materials for applications in nanoelectronics. However, the formation of defect-free two-dimensional (2D) covalent networks remains a challenge, which makes it difficult to unveil their electronic structure. Here we report on the hierarchical on-surface synthesis of nearly defect-free 2D covalent architectures with carbonyl-functionalized pores on Au(111), which is investigated by low-temperature scanning tunnelling microscopy in combination with density functional theory calculations. The carbonyl-bridged triphenylamine precursors form six-membered macrocycles and one-dimensional (1D) chains as intermediates in an Ullmann-type coupling reaction that are subsequently interlinked to 2D networks. The electronic band gap is narrowed when going from the monomer to 1D and 2D surface-confined π-conjugated organic polymers comprising the same building block. The significant drop of the electronic gap from the monomer to the polymer confirms an efficient conjugation along the triphenylamine units within the nanostructures.

  8. Lennard-Jones fluids in two-dimensional nano-pores. Multi-phase coexistence and fluid structure

    Science.gov (United States)

    Yatsyshin, Petr; Savva, Nikos; Kalliadasis, Serafim

    2014-03-01

    We present a number of fundamental findings on the wetting behaviour of nano-pores. A popular model for fluid confinement is a one-dimensional (1D) slit pore formed by two parallel planar walls and it exhibits capillary condensation (CC): a first-order phase transition from vapour to capillary-liquid (Kelvin shift). Capping such a pore at one end by a third orthogonal wall forms a prototypical two-dimensional (2D) pore. We show that 2D pores possess a wetting temperature such that below this temperature CC remains of first order, above it becomes a continuous phase transition manifested by a slab of capillary-liquid filling the pore from the capping wall. Continuous CC exhibits hysteresis and can be preceded by a first-order capillary prewetting transition. Additionally, liquid drops can form in the corners of the 2D pore (remnant of 2D wedge prewetting). The three fluid phases, vapour, capillary-liquid slab and corner drops, can coexist at the pore triple point. Our model is based on the statistical mechanics of fluids in the density functional formulation. The fluid-fluid and fluid-substrate interactions are dispersive. We analyze in detail the microscopic fluid structure, isotherms and full phase diagrams. Our findings also suggest novel ways to control wetting of nano-pores. We are grateful to the European Research Council via Advanced Grant No. 247031 for support.

  9. Estimates of the statistical two-dimensional spatial structure in rain over a small network of disdrometers

    Science.gov (United States)

    Jameson, A. R.; Larsen, M. L.

    2016-06-01

    Microphysical understanding of the variability in rain requires a statistical characterization of different drop sizes both in time and in all dimensions of space. Temporally, there have been several statistical characterizations of raindrop counts. However, temporal and spatial structures are neither equivalent nor readily translatable. While there are recent reports of the one-dimensional spatial correlation functions in rain, they can only be assumed to represent the two-dimensional (2D) correlation function under the assumption of spatial isotropy. To date, however, there are no actual observations of the (2D) spatial correlation function in rain over areas. Two reasons for this deficiency are the fiscal and the physical impossibilities of assembling a dense network of instruments over even hundreds of meters much less over kilometers. Consequently, all measurements over areas will necessarily be sparsely sampled. A dense network of data must then be estimated using interpolations from the available observations. In this work, a network of 19 optical disdrometers over a 100 m by 71 m area yield observations of drop spectra every minute. These are then interpolated to a 1 m resolution grid. Fourier techniques then yield estimates of the 2D spatial correlation functions. Preliminary examples using this technique found that steadier, light rain decorrelates spatially faster than does the convective rain, but in both cases the 2D spatial correlation functions are anisotropic, reflecting an asymmetry in the physical processes influencing the rain reaching the ground not accounted for in numerical microphysical models.

  10. Tellurium speciation, connectivity, and chemical order in As(x)Te(100-x) glasses: results from two-dimensional 125Te NMR spectroscopy.

    Science.gov (United States)

    Kaseman, Derrick C; Hung, Ivan; Lee, Kathleen; Kovnir, Kirill; Gan, Zhehong; Aitken, Bruce; Sen, Sabyasachi

    2015-02-05

    The short-range structure, connectivity, and chemical order in As(x)Te(100-x) (25 ≤ x ≤ 65) glasses are studied using high-resolution two-dimensional projection magic-angle-turning (pjMAT) (125)Te nuclear magnetic resonance (NMR) spectroscopy. The (125)Te pjMAT NMR results indicate that the coordination of Te atoms obeys the 8-N coordination rule over the entire composition range. However, in strong contrast with the analogous glass-forming As-S and As-Se chalcogenides, significant violation of chemical order is observed in As-Te glasses over the entire composition range in the form of homopolar As-As (Te-Te) bonds, even in severely As (Te)-deficient glasses. The speciation of the Te coordination environments can be explained with the dissociation reaction model As2Te3 → 2As + 3Te(II), characterized by a dissociation constant that is independent of glass composition. These structural characteristics can be attributed to the high metallicity of Te and the strong energetic similarity between the Te-Te, Te-As, and As-As bonds, and they are consistent with the monotonic and often nearly linear variation of physical properties observed in telluride glasses as a function of the Te content.

  11. Crystallization of a Two-Dimensional Hydrogen-Bonded Molecular Assembly: Evolution of the Local Structure Resolved by Atomic Force Microscopy.

    Science.gov (United States)

    Patera, Laerte L; Liu, Xunshan; Mosso, Nico; Decurtins, Silvio; Liu, Shi-Xia; Repp, Jascha

    2017-08-28

    Structures of the aromatic N-heterocyclic hexaazatriphenylene (HAT) molecular synthon obtained by surface-assisted self-assembly were analyzed with sub-Å resolution by means of noncontact atomic force microscopy (nc-AFM), both in the kinetically trapped amorphous state and in the thermodynamically stable crystalline phase. These results reveal how the crystallization governs the length scale of the network order for non-flexible molecular species without affecting the local bonding schemes. The capability of nc-AFM to accurately resolve structural relaxations will be highly relevant for the characterization of vitreous two-dimensional supramolecular materials. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Tunability of band structures in a two-dimensional magnetostrictive phononic crystal plate with stress and magnetic loadings

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Shunzu; Shi, Yang [Key Laboratory of Mechanics on Disaster and Environment in Western China attached to the Ministry of Education of China, Lanzhou University, Lanzhou, Gansu 730000 (China); Department of Mechanics and Engineering Sciences, College of Civil Engineering and Mechanics, Lanzhou University, Lanzhou, Gansu 730000 (China); Gao, Yuanwen, E-mail: ywgao@lzu.edu.cn [Key Laboratory of Mechanics on Disaster and Environment in Western China attached to the Ministry of Education of China, Lanzhou University, Lanzhou, Gansu 730000 (China); Department of Mechanics and Engineering Sciences, College of Civil Engineering and Mechanics, Lanzhou University, Lanzhou, Gansu 730000 (China)

    2017-03-26

    Considering the magneto-mechanical coupling of magnetostrictive material, the tunability of in-plane wave propagation in two-dimensional Terfenol-D/epoxy phononic crystal (PC) plate is investigated theoretically by the plane wave expansion method. Two Schemes, i.e. magnetic field is rotated in x–y plane and x–z plane, are studied, respectively. The effects of amplitude and direction of magnetic field, pre-stress and geometric parameters are discussed. For Scheme-I, band gap reaches the maximum at an optimal angle 45° of magnetic field. However, the optimal angle is 0° for Scheme-II, because band gap decreases monotonically until disappears with the increasing angle. For both cases, higher-order band gaps generate and become stronger as magnetic field amplitude increases, while increasing compressive pre-stress has the opposite effect. Meanwhile, filling fraction plays a key role in controlling band gaps. These results provide possibility for intelligent regulation and optimal design of PC plates. - Highlights: • The in-plane wave propagation in phononic crystal thin plate is tuned theoretically. • Magnetostrictive material is introduced in the study. • The effects of magnetic field and pre-stress are considered. • The variations of band gaps with external stimuli are discussed.

  13. Two-dimensional function photonic crystals

    CERN Document Server

    Wu, Xiang-Yao; Liu, Xiao-Jing; Liang, Yu

    2016-01-01

    In this paper, we have firstly proposed two-dimensional function photonic crystals, which the dielectric constants of medium columns are the functions of space coordinates $\\vec{r}$, it is different from the two-dimensional conventional photonic crystals constituting by the medium columns of dielectric constants are constants. We find the band gaps of two-dimensional function photonic crystals are different from the two-dimensional conventional photonic crystals, and when the functions form of dielectric constants are different, the band gaps structure should be changed, which can be designed into the appropriate band gaps structures by the two-dimensional function photonic crystals.

  14. Turbulent pair separation due to multi scale stagnation point structure and its time asymmetry in two-dimensional turbulence

    OpenAIRE

    Faber, Tristan; Vassilicos, J. C.

    2008-01-01

    The pair separation model of Goto and Vassilicos (S Goto and J C Vassilicos, 2004, New J.Phys., 6, p.65) is revisited and placed on a sound mathematical foundation. A DNS of two dimensional homogeneous isotropic turbulence with an inverse energy cascade and a k^{-5/3} power law is used to investigate properties of pair separation in two dimensional turbulence. A special focus lies on the time asymmetry observed between forward and backward separation. Application of the present model to this ...

  15. Assessing two-dimensional crystallization trials of small membrane proteins for structural biology studies by electron crystallography.

    Science.gov (United States)

    Johnson, Matthew C; Rudolph, Frederik; Dreaden, Tina M; Zhao, Gengxiang; Barry, Bridgette A; Schmidt-Krey, Ingeborg

    2010-10-29

    Electron crystallography has evolved as a method that can be used either alternatively or in combination with three-dimensional crystallization and X-ray crystallography to study structure-function questions of membrane proteins, as well as soluble proteins. Screening for two-dimensional (2D) crystals by transmission electron microscopy (EM) is the critical step in finding, optimizing, and selecting samples for high-resolution data collection by cryo-EM. Here we describe the fundamental steps in identifying both large and ordered, as well as small 2D arrays, that can potentially supply critical information for optimization of crystallization conditions. By working with different magnifications at the EM, data on a range of critical parameters is obtained. Lower magnification supplies valuable data on the morphology and membrane size. At higher magnifications, possible order and 2D crystal dimensions are determined. In this context, it is described how CCD cameras and online-Fourier Transforms are used at higher magnifications to assess proteoliposomes for order and size. While 2D crystals of membrane proteins are most commonly grown by reconstitution by dialysis, the screening technique is equally applicable for crystals produced with the help of monolayers, native 2D crystals, and ordered arrays of soluble proteins. In addition, the methods described here are applicable to the screening for 2D crystals of even smaller as well as larger membrane proteins, where smaller proteins require the same amount of care in identification as our examples and the lattice of larger proteins might be more easily identifiable at earlier stages of the screening.

  16. 基于FPGA快速二维DCT图像编码结构%FPGA Rapid Two-dimensional DCT Image Coding Structure

    Institute of Scientific and Technical Information of China (English)

    龙飞; 李良荣; 李绪诚

    2012-01-01

    本文提出了一种二维DCT快速算法的FPGA实现结构,采用行列分解算法将二维DCT分解成两个一维DCT和一个转置缓冲器组成的结构,其中一雏DCT借鉴Arai DCT算法,并采取了FPGA特有的并行的流水线技术,该结构极大减少了加法器和乘法器的数量,节省了计算时间.该结构的特点是高数据吞吐率、硬件资源消耗少,功耗低.实验结果证明了二维DCT核设计的正确性,适合图像的实时处理.%In this paper, a two-dimensional DCT fast algorithm for FPGA implementation structure. Decomposition algorithm using the line-column, 2D-DCT is broken down into the structure of two 1D-DCT and a transpose buffer, and 1D-DCT is learn from Arai DCT algorithm, and mining is indeed a unique parallel pipeline technique in FPGA. The structure greatly reduces the adder and multiplier is the number, to save calculation time. The structure is characterized by high data throughput, the hardware resource consumption, low power consumption. The experimental results show the correctness of the two-dimensional DCT core design, suitable for real-time processing of the image.

  17. On the large-scale structure and spectral dynamics of two-dimensional turbulence in a periodic channel

    NARCIS (Netherlands)

    Kramer, W.; Clercx, H.J.H.; van Heijst, G.J.F.

    2008-01-01

    This paper reports on a numerical study of forced two-dimensional turbulence in a periodic channel with flat no-slip walls. Since corners or curved domain boundaries, which are met in the standard rectangular, square, or circular geometries, are absent in this geometry, the (statistical) analysis of

  18. First-principles investigation of the effect of charged unit cell on the electronic structure of two-dimensional MoS2

    Science.gov (United States)

    Shekaari, Ashkan; Abolhassani, Mohammad Reza; Lashgari, Hamed

    2017-01-01

    Density-functional theory has been applied to investigate the effect of charged unit cell on the structural and electronic properties of two-dimensional MoS2 within PBE-GGA. The charge of the unit cell of the monolayer changes from zero to n = ± 4 e with e the absolute value of the elementary electric charge. Variations of the lattice constant, Mo-S bond length, S-Mo-S bond angle, total energy, exchange and correlation contributions, and the Fermi level versus n have been calculated quantitatively, indicating decrease in the stability of the atomic structure of the monolayer with increase in the absolute value of n. It is found that the Fermi level for two-dimensional MoS2 is a function of both the number of electrons in allowed states and the inverse of the volume of the unit cell. The electronic properties of each monolayer have been also calculated via examining the related electronic band structure and density of states. Results broadly support the view that the effect of charged unit cell (n =+ e to - 4 e) on the electronic properties of MoS2 monolayer is manifested in the form of semiconductor-to-metal transition in addition to the Fermi level shift. It is also verified that as the negative charge of the unit cell increases from n = - e to - 4 e , there is an ever-increasing trend in the total number of allowed electronic states at the Fermi level, implying a direct correlation between electrical conductivity and the value of n in a way that the more negative the charge of the unit cell, the higher the electrical conductivity of the monolayer.

  19. Acousto-optical interaction of surface acoustic and optical waves in a two-dimensional phoxonic crystal hetero-structure cavity.

    Science.gov (United States)

    Ma, Tian-Xue; Zou, Kui; Wang, Yue-Sheng; Zhang, Chuanzeng; Su, Xiao-Xing

    2014-11-17

    Phoxonic crystal is a promising material for manipulating sound and light simultaneously. In this paper, we theoretically demonstrate the propagation of acoustic and optical waves along the truncated surface of a two-dimensional square-latticed phoxonic crystal. Further, a phoxonic crystal hetero-structure cavity is proposed, which can simultaneously confine surface acoustic and optical waves. The interface motion and photoelastic effects are taken into account in the acousto-optical coupling. The results show obvious shifts in eigenfrequencies of the photonic cavity modes induced by different phononic cavity modes. The symmetry of the phononic cavity modes plays a more important role in the single-phonon exchange process than in the case of the multi-phonon exchange. Under the same deformation, the frequency shift of the photonic transverse electric mode is larger than that of the transverse magnetic mode.

  20. AlGaAs/GaAs two-dimensional electron gas structures studied by photo reflectance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Guillen Cervantes, A; Rivera Alvarez, Z; Hernandez, F; Huerta, J. [Instituto Politecnico Nacional, Mexico, D.F. (Mexico); Mendez Garcia, V. H.; Lastras Martinez, A.; Zamora, L.; Saucedo, N. [Universidad Autonoma de San Luis Potosi, San Luis Potosi (Mexico); Melendez Lira, M; Lopez, M [Instituto Politecnico Nacional, Mexico, D.F. (Mexico)

    2001-12-01

    Al{sub x} Ga{sub 1}-x As/GaAs two-dimensional electron gas (2-DEG) heterostructures were fabricated by molecular beam epitaxy in three different laboratories. The samples were characterized by room temperature Photo reflectance (PR) spectroscopy and measurements at 77 K. Internal electric fields were detected by the presence of Franz-Keldysh (FK) oscillations in the PR spectra. >From a FK analysis we obtained the GaAs band-gap energy and the built-in electric field strength in each sample. On the other hand, in the energy region corresponding to Al{sub x} Ga{sub 1}-x As a broad PR signal was registered typical of a highly doped material. Using the third derivative theory we obtained the Al{sub x} Ga{sub 1}-x As band-gap energy, and from this value the Al concentration in the samples. Results showed that the sample with highest electron mobility exhibited the lowest internal electric field strength. [Spanish] Se fabricaron heteroestructuras del tipo Al{sub x} Ga{sub 1}-x As/GaAs con un gas de electrones en dos dimensiones por medio de epitaxia de haces moleculares en tres laboratorios diferentes. Las muestras se caracterizaron por fotorreflectancia (FR) a temperatura ambiente y por mediciones del efecto mayor a 77 K. Campos electricos internos se detectaron por la presencia de oscilaciones Franz-Leldysh (FK) en los espectros de FR. Del analisis de las oscilaciones FK obtuvimos la energia de la brecha prohibida del GaAs y la intensidad del campo electrico interno en cada muestra. Por otra parte, en la region de energia correspondiente al Al{sub x} Ga{sub 1}-x As observamos una senal de FR ancha, tipica de un material altamente impurificado. Usando la teoria de la tercera derivada, obtuvimos el valor de la brecha de energia del Al{sub x}Ga{sub 1}-xAs, y de este valor la concentracion de Al en las muestras. Los resultados mostraron que la estructura con el valor de movilidad electronica mas alto tiene la intensidad de campo electrico interno mas baja.

  1. New structural information on a humic acid from two-dimensional 1H-13C correlation solid-state nuclear magnetic resonance.

    Science.gov (United States)

    Mao, J D; Xing, B; Schmidt-Rohr, K

    2001-05-15

    New information on the chemical structure of a peat humic acid has been obtained using a series of two-dimensional 1H-13C heteronuclear correlation solid-state NMR (HETCOR) experiments with different contact times and with spectral editing by dipolar dephasing and 13C transverse relaxation filtering. Carbon-bonded methyl groups (C-CH3) are found to be near both aliphatic and O-alkyl but not aromatic groups. The spectra prove that most OCH3 groups are connected directly with the aromatic rings, as is typical in lignin. As a result, about one-third of the aromatic C-O groups is not phenolic C-OH but C-OCH3. Both protonated and unprotonated anomeric O-C-O carbons are identified in the one- and two-dimensional spectra. COO groups are found predominantly in OCHn-COO environments, but some are also bonded to aromatic rings and aliphatic groups. All models of humic acids in the literature lack at least some of the features observed here. Compositional heterogeneity was studied by introducing 1H spin diffusion into the HETCOR experiment. Comparison with data for a synthetic polymer, polycarbonate, indicates that the separation between O-alkyl and aromatic groups in the humic acid is less than 1.5 nm. However, transverse 13C relaxation filtering under 1H decoupling reveals heterogeneity on a nanometer scale, with the slow-relaxing component being rich in lignin-like aromatic-C-O-CH3 moieties and poor in COO groups.

  2. Two-dimensional HRCT for monitoring postoperative results of the anterior cruciate ligament reconstruction. Zweidimensionale (2-D) CT-Arthrotomographie zur postoperativen Kontrolle einer neuen vorderen Kreuzbandplastik

    Energy Technology Data Exchange (ETDEWEB)

    Tosch, U.; Witt, H. (Freie Univ. Berlin (Germany, F.R.). Roentgendiagnostisches Zentralinstitut); Hertel, P.; Lais, E. (Freie Univ. Berlin (Germany, F.R.). Unfallchirurgische Klinik)

    1989-11-01

    Fifty-eight patients underwent intraarticular reconstruction of the anterior cruciate ligament. This was performed by using an autogenous transplant from the mid portion of the patellar ligament with a proximal and distal bone block, as described by Hertel. For comparison with the conventional X-ray examination, HRCT was performed to study the early postoperative results. In four patients (7%) dislocation of the bone block in the femoral condyle was seen. Two-dimensional reconstruction proved to be a satisfactory method for demonstration of the exact position of the autogenous transplant in both coronary and sagittal planes. (orig.).

  3. Periodic ordering of clusters and stripes in a two-dimensional lattice model. II. Results of Monte Carlo simulation.

    Science.gov (United States)

    Almarza, N G; Pȩkalski, J; Ciach, A

    2014-04-28

    The triangular lattice model with nearest-neighbor attraction and third-neighbor repulsion, introduced by Pȩkalski, Ciach, and Almarza [J. Chem. Phys. 140, 114701 (2014)] is studied by Monte Carlo simulation. Introduction of appropriate order parameters allowed us to construct a phase diagram, where different phases with patterns made of clusters, bubbles or stripes are thermodynamically stable. We observe, in particular, two distinct lamellar phases-the less ordered one with global orientational order and the more ordered one with both orientational and translational order. Our results concern spontaneous pattern formation on solid surfaces, fluid interfaces or membranes that is driven by competing interactions between adsorbing particles or molecules.

  4. A theoretical model for the evolution of two-dimensional large-scale coherent structures in a mixing layer

    Institute of Scientific and Technical Information of China (English)

    周恒; 马良

    1995-01-01

    By a proper combination of the modified weakly nonlinear theory of hydrodynamic stability and the energy method, the spatial evolution of the large-scale coherent structures in a mixing layer has been calculated. The results are satisfactory.

  5. Visualization of Excitonic Structure in the Fenna-Matthews-OlsonPhotosynthetic Complex by Polarization-Dependent Two-DimensionalElectronic Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Department of Chemistry, The University of Chicago; Department of Biology, Department of Chemistry, Washington University; Fleming, Graham; Read, Elizabeth L.; Schlau-Cohen, Gabriela S.; Engel, Gregory S.; Wen, Jianzhong; Blankenship, Robert E.; Fleming, Graham R.

    2008-05-26

    Photosynthetic light-harvesting proceeds by the collection and highly efficient transfer of energy through a network of pigment-protein complexes. Inter-chromophore electronic couplings and interactions between pigments and the surrounding protein determine energy levels of excitonic states and dictate the mechanism of energy flow. The excitonic structure (orientation of excitonic transition dipoles) of pigment-protein complexes is generally deduced indirectly from x-ray crystallography in combination with predictions of transition energies and couplings in the chromophore site basis. Here, we demonstrate that coarse-grained excitonic structural information in the form of projection angles between transition dipole moments can be obtained from polarization-dependent two-dimensional electronic spectroscopy of an isotropic sample, particularly when the nonrephasing or free polarization decay signal rather than the photon echo signal is considered. The method provides an experimental link between atomic and electronic structure and accesses dynamical information with femtosecond time resolution. In an investigation of the Fenna-Matthews-Olson complex from green sulfur bacteria, energy transfer connecting two particular exciton states in the protein is isolated as being the primary contributor to a cross peak in the nonrephasing 2D spectrum at 400 fs under a specific sequence of polarized excitation pulses. The results suggest the possibility of designing experiments using combinations of tailored polarization sequencesto separate and monitor individual relaxation pathways.

  6. Visualization of Excitonic Structure in the Fenna-Matthews-OlsonPhotosynthetic Complex by Polarization-Dependent Two-DimensionalElectronic Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Department of Chemistry, The University of Chicago; Department of Biology, Department of Chemistry, Washington University; Fleming, Graham; Read, Elizabeth L.; Schlau-Cohen, Gabriela S.; Engel, Gregory S.; Wen, Jianzhong; Blankenship, Robert E.; Fleming, Graham R.

    2008-05-26

    Photosynthetic light-harvesting proceeds by the collection and highly efficient transfer of energy through a network of pigment-protein complexes. Inter-chromophore electronic couplings and interactions between pigments and the surrounding protein determine energy levels of excitonic states and dictate the mechanism of energy flow. The excitonic structure (orientation of excitonic transition dipoles) of pigment-protein complexes is generally deduced indirectly from x-ray crystallography in combination with predictions of transition energies and couplings in the chromophore site basis. Here, we demonstrate that coarse-grained excitonic structural information in the form of projection angles between transition dipole moments can be obtained from polarization-dependent two-dimensional electronic spectroscopy of an isotropic sample, particularly when the nonrephasing or free polarization decay signal rather than the photon echo signal is considered. The method provides an experimental link between atomic and electronic structure and accesses dynamical information with femtosecond time resolution. In an investigation of the Fenna-Matthews-Olson complex from green sulfur bacteria, energy transfer connecting two particular exciton states in the protein is isolated as being the primary contributor to a cross peak in the nonrephasing 2D spectrum at 400 fs under a specific sequence of polarized excitation pulses. The results suggest the possibility of designing experiments using combinations of tailored polarization sequencesto separate and monitor individual relaxation pathways.

  7. Topological defects in two-dimensional crystals

    OpenAIRE

    Chen, Yong; Qi, Wei-Kai

    2008-01-01

    By using topological current theory, we study the inner topological structure of the topological defects in two-dimensional (2D) crystal. We find that there are two elementary point defects topological current in two-dimensional crystal, one for dislocations and the other for disclinations. The topological quantization and evolution of topological defects in two-dimensional crystals are discussed. Finally, We compare our theory with Brownian-dynamics simulations in 2D Yukawa systems.

  8. Time-domain analysis of bandgap characteristics of two-dimensional periodic structures by use of a source-model technique.

    Science.gov (United States)

    Ludwig, Alon; Leviatan, Yehuda

    2008-02-01

    We introduce a time-domain source-model technique for analysis of two-dimensional, transverse-magnetic, plane-wave scattering by a photonic crystal slab composed of a finite number of identical layers, each comprising a linear periodic array of dielectric cylinders. The proposed technique takes advantage of the periodicity of the slab by solving the problem within a unit cell of the periodic structure. A spectral analysis of the temporal behavior of the fields scattered by the slab shows a clear agreement between frequency bands where the spectral density of the transmitted energy is low and the bandgaps of the corresponding two-dimensionally infinite periodic structure. The effect of the bandwidth of the incident pulse and its center frequency on the manner it is transmitted through and reflected by the slab is studied via numerical examples.

  9. A numerical method for three-dimensional vortical structure of spiral vortex in wind turbine with two-dimensional velocity data at plural azimuthal angles

    Science.gov (United States)

    Nakayama, Katsuyuki; Mizushima, Lucas Dias; Murata, Junsuke; Maeda, Takao

    2016-06-01

    A numerical method is presented to extract three-dimensional vortical structure of a spiral vortex (wing tip vortex) in a wind turbine, from two-dimensional velocity data at several azimuthal angles. This numerical method contributes to analyze a vortex observed in experiment where three-dimensional velocity field is difficult to be measured. This analysis needs two-dimensional velocity data in parallel planes at different azimuthal angles of a rotating blade, which facilitates the experiment since the angle of the plane does not change. The vortical structure is specified in terms of the invariant flow topology derived from eigenvalues and eigenvectors of three-dimensional velocity gradient tensor and corresponding physical properties. In addition, this analysis enables to investigate not only vortical flow topology but also important vortical features such as pressure minimum and vortex stretching that are derived from the three-dimensional velocity gradient tensor.

  10. Comprehensive magnetotransport characterization of two dimensional electron gas in AlGaN/GaN high electron mobility transistor structures leading to the assessment of interface roughness

    Energy Technology Data Exchange (ETDEWEB)

    Mishra, Manna Kumari [Solid State Physics Laboratory, Lucknow Road, Timarpur, Delhi-110054 (India); Netaji Subhas Institute of Technology, Dwarka, New Delhi-110078 (India); Sharma, Rajesh K., E-mail: rksharma@sspl.drdo.in; Manchanda, Rachna; Bag, Rajesh K.; Muralidharan, Rangarajan [Solid State Physics Laboratory, Lucknow Road, Timarpur, Delhi-110054 (India); Thakur, Om Prakash [Netaji Subhas Institute of Technology, Dwarka, New Delhi-110078 (India)

    2014-09-15

    Magnetotransport in two distinct AlGaN/GaN HEMT structures grown by Molecular Beam Epitaxy (MBE) on Fe-doped templates is investigated using Shubnikov de-Haas Oscillations in the temperature range of 1.8–6 K and multicarrier fitting in the temperature range of 1.8–300 K. The temperature dependence of the two dimensional electron gas mobility is extracted from simultaneous multicarrier fitting of transverse and longitudinal resistivity as a function of magnetic field and the data is utilized to estimate contribution of interface roughness to the mobility and the corresponding transport lifetime. The quantum scattering time obtained from the analysis of Shubnikov de Haas Oscillations in transverse magnetoresistance along with the transport lifetime time were used to estimate interface roughness amplitude and lateral correlation length. The results indicate that the insertion of AlN over layer deposited prior to the growth of GaN base layer on Fe doped GaN templates for forming HEMT structures reduced the parallel conduction but resulted in an increase in interface roughness.

  11. Comprehensive magnetotransport characterization of two dimensional electron gas in AlGaN/GaN high electron mobility transistor structures leading to the assessment of interface roughness

    Directory of Open Access Journals (Sweden)

    Manna Kumari Mishra

    2014-09-01

    Full Text Available Magnetotransport in two distinct AlGaN/GaN HEMT structures grown by Molecular Beam Epitaxy (MBE on Fe-doped templates is investigated using Shubnikov de-Haas Oscillations in the temperature range of 1.8–6 K and multicarrier fitting in the temperature range of 1.8–300 K. The temperature dependence of the two dimensional electron gas mobility is extracted from simultaneous multicarrier fitting of transverse and longitudinal resistivity as a function of magnetic field and the data is utilized to estimate contribution of interface roughness to the mobility and the corresponding transport lifetime. The quantum scattering time obtained from the analysis of Shubnikov de Haas Oscillations in transverse magnetoresistance along with the transport lifetime time were used to estimate interface roughness amplitude and lateral correlation length. The results indicate that the insertion of AlN over layer deposited prior to the growth of GaN base layer on Fe doped GaN templates for forming HEMT structures reduced the parallel conduction but resulted in an increase in interface roughness.

  12. Analyzing the photonic band gaps in two-dimensional plasma photonic crystals with fractal Sierpinski gasket structure based on the Monte Carlo method

    Directory of Open Access Journals (Sweden)

    Hai-Feng Zhang

    2016-08-01

    Full Text Available In this paper, the properties of photonic band gaps (PBGs in two types of two-dimensional plasma-dielectric photonic crystals (2D PPCs under a transverse-magnetic (TM wave are theoretically investigated by a modified plane wave expansion (PWE method where Monte Carlo method is introduced. The proposed PWE method can be used to calculate the band structures of 2D PPCs which possess arbitrary-shaped filler and any lattice. The efficiency and convergence of the present method are discussed by a numerical example. The configuration of 2D PPCs is the square lattices with fractal Sierpinski gasket structure whose constituents are homogeneous and isotropic. The type-1 PPCs is filled with the dielectric cylinders in the plasma background, while its complementary structure is called type-2 PPCs, in which plasma cylinders behave as the fillers in the dielectric background. The calculated results reveal that the enough accuracy and good convergence can be obtained, if the number of random sampling points of Monte Carlo method is large enough. The band structures of two types of PPCs with different fractal orders of Sierpinski gasket structure also are theoretically computed for a comparison. It is demonstrate that the PBGs in higher frequency region are more easily produced in the type-1 PPCs rather than in the type-2 PPCs. Sierpinski gasket structure introduced in the 2D PPCs leads to a larger cutoff frequency, enhances and induces more PBGs in high frequency region. The effects of configurational parameters of two types of PPCs on the PBGs are also investigated in detail. The results show that the PBGs of the PPCs can be easily manipulated by tuning those parameters. The present type-1 PPCs are more suitable to design the tunable compacted devices.

  13. Analyzing the photonic band gaps in two-dimensional plasma photonic crystals with fractal Sierpinski gasket structure based on the Monte Carlo method

    Science.gov (United States)

    Zhang, Hai-Feng; Liu, Shao-Bin

    2016-08-01

    In this paper, the properties of photonic band gaps (PBGs) in two types of two-dimensional plasma-dielectric photonic crystals (2D PPCs) under a transverse-magnetic (TM) wave are theoretically investigated by a modified plane wave expansion (PWE) method where Monte Carlo method is introduced. The proposed PWE method can be used to calculate the band structures of 2D PPCs which possess arbitrary-shaped filler and any lattice. The efficiency and convergence of the present method are discussed by a numerical example. The configuration of 2D PPCs is the square lattices with fractal Sierpinski gasket structure whose constituents are homogeneous and isotropic. The type-1 PPCs is filled with the dielectric cylinders in the plasma background, while its complementary structure is called type-2 PPCs, in which plasma cylinders behave as the fillers in the dielectric background. The calculated results reveal that the enough accuracy and good convergence can be obtained, if the number of random sampling points of Monte Carlo method is large enough. The band structures of two types of PPCs with different fractal orders of Sierpinski gasket structure also are theoretically computed for a comparison. It is demonstrate that the PBGs in higher frequency region are more easily produced in the type-1 PPCs rather than in the type-2 PPCs. Sierpinski gasket structure introduced in the 2D PPCs leads to a larger cutoff frequency, enhances and induces more PBGs in high frequency region. The effects of configurational parameters of two types of PPCs on the PBGs are also investigated in detail. The results show that the PBGs of the PPCs can be easily manipulated by tuning those parameters. The present type-1 PPCs are more suitable to design the tunable compacted devices.

  14. Two-dimensional hydrogen-bonded polymers in the crystal structures of the ammonium salts of phenoxyacetic acid, (4-fluorophenoxyacetic acid and (4-chloro-2-methylphenoxyacetic acid

    Directory of Open Access Journals (Sweden)

    Graham Smith

    2014-12-01

    Full Text Available The structures of the ammonium salts of phenoxyacetic acid, NH4+·C8H6O3−, (I, (4-fluorophenoxyacetic acid, NH4+·C8H5FO3−, (II, and the herbicidally active (4-chloro-2-methylphenoxyacetic acid (MCPA, NH4+·C9H8ClO3−·0.5H2O, (III have been determined. All have two-dimensional layered structures based on inter-species ammonium N—H...O hydrogen-bonding associations, which give core substructures consisting primarily of conjoined cyclic motifs. The crystals of (I and (II are isomorphous with the core comprising R12(5, R12(4 and centrosymmetric R42(8 ring motifs, giving two-dimensional layers lying parallel to (100. In (III, the water molecule of solvation lies on a crystallographic twofold rotation axis and bridges two carboxyl O atoms in an R44(12 hydrogen-bonded motif, creating two R43(10 rings, which together with a conjoined centrosymmetric R42(8 ring incorporating both ammonium cations, generate two-dimensional layers lying parallel to (100. No π–π ring associations are present in any of the structures.

  15. Intercomparison of ion beam analysis software for the simulation of backscattering spectra from two-dimensional structures

    Science.gov (United States)

    Mayer, M.; Malinský, P.; Schiettekatte, F.; Zolnai, Z.

    2016-10-01

    The codes RBS-MAST, STRUCTNRA, F95-Rough and CORTEO are simulation codes for ion beam analysis spectra from two- or three-dimensional sample structures. The codes were intercompared in a code-code comparison using an idealized grating structure and by comparison to experimental data from a silicon grating on tantalum interlayer. All codes are in excellent agreement at higher incident energies and not too large energy losses. At lower incident energies, grazing angles of incidence and/or larger energy losses plural scattering effects play an increasing role. Simulation codes with plural scattering capabilities offer higher accuracy and better agreement to experimental results in this regime.

  16. Two-dimensional calculus

    CERN Document Server

    Osserman, Robert

    2011-01-01

    The basic component of several-variable calculus, two-dimensional calculus is vital to mastery of the broader field. This extensive treatment of the subject offers the advantage of a thorough integration of linear algebra and materials, which aids readers in the development of geometric intuition. An introductory chapter presents background information on vectors in the plane, plane curves, and functions of two variables. Subsequent chapters address differentiation, transformations, and integration. Each chapter concludes with problem sets, and answers to selected exercises appear at the end o

  17. Two dimensional vernier

    Science.gov (United States)

    Juday, Richard D. (Inventor)

    1992-01-01

    A two-dimensional vernier scale is disclosed utilizing a cartesian grid on one plate member with a polar grid on an overlying transparent plate member. The polar grid has multiple concentric circles at a fractional spacing of the spacing of the cartesian grid lines. By locating the center of the polar grid on a location on the cartesian grid, interpolation can be made of both the X and Y fractional relationship to the cartesian grid by noting which circles coincide with a cartesian grid line for the X and Y direction.

  18. Two-dimensionally stacked heterometallic layers hosting a discrete chair dodecameric ring of water clusters: synthesis and structural study.

    Science.gov (United States)

    Kenfack Tsobnang, Patrice; Wenger, Emmanuel; Biache, Coralie; Lambi Ngolui, John; Ponou, Siméon; Dahaoui, Slimane; Lecomte, Claude

    2014-10-01

    The stacked two-dimensional supramolecular compound catena-{Co(amp)3Cr(ox)3·6H2O} (amp = 2-picolylamine, ox = oxalate) has been synthesized from the bimolecular approach using hydrogen bonds. It is built from layers in which both Co(amp)(3+) (D) and Cr(ox)(3-) (A) ions are bonded in a repeating DADADA… pattern along the a and c axes by multiple hydrogen bonds. These layers host a well resolved R12 dodecameric discrete ring of water clusters built by six independent molecules located around the 2c centrosymmetric Wyckoff positions of the P21/n space group in which the compound crystallizes. These clusters are ranged along the [001] direction, occupy 733.5 Å(3) (22.0%) of the unit cell and have a chair conformation via 12 hydrogen bonds. The water molecules of the cluster are linked with stronger hydrogen bonds than those between the cluster and its host, which explains the single continuous step of the dehydration process of the compound.

  19. Identifying important structural features of ionic liquid stationary phases for the selective separation of nonpolar analytes by comprehensive two-dimensional gas chromatography.

    Science.gov (United States)

    Zhang, Cheng; Ingram, Isaiah C; Hantao, Leandro W; Anderson, Jared L

    2015-03-20

    A series of dicationic ionic liquid (IL)-based stationary phases were evaluated as secondary columns in comprehensive two-dimensional gas chromatography (GC×GC) for the separation of aliphatic hydrocarbons from kerosene. In order to understand the role that structural features of ILs play on the selectivity of nonpolar analytes, the solvation parameter model was used to probe the solvation properties of the IL-based stationary phases. It was observed that room temperature ILs containing long free alkyl side chain substituents and long linker chains between the two cations possess less cohesive forces and exhibited the highest resolution of aliphatic hydrocarbons. The anion component of the IL did not contribute significantly to the overall separation, as similar selectivities toward aliphatic hydrocarbons were observed when examining ILs with identical cations and different anions. In an attempt to further examine the separation capabilities of the IL-based GC stationary phases, columns of the best performing stationary phases were prepared with higher film thickness and resulted in enhanced selectivity of aliphatic hydrocarbons.

  20. Terahertz optical-Hall effect characterization of two-dimensional electron gas properties in AlGaN/GaN high electron mobility transistor structures

    Science.gov (United States)

    Schöche, S.; Shi, Junxia; Boosalis, A.; Kühne, P.; Herzinger, C. M.; Woollam, J. A.; Schaff, W. J.; Eastman, L. F.; Schubert, M.; Hofmann, T.

    2011-02-01

    The free-charge carrier mobility, sheet density, and effective mass of a two-dimensional electron gas are exemplarily determined in the spectral range from 640 GHz to 1 THz in a AlGaN/GaN heterostructure using the optical-Hall effect at room temperature. Complementary midinfrared spectroscopic ellipsometry measurements are performed for analysis of heterostructure constituents layer thickness, phonon mode, and free-charge carrier parameters. The electron effective mass is determined to be (0.22±0.04)m0. The high-frequency sheet density and carrier mobility parameters are in good agreement with results from dc electrical Hall effect measurements, indicative for frequency-independent carrier scattering mechanisms of the two-dimensional carrier distribution.

  1. Thermodynamic versus kinetic control in self-assembly of zero-, one-, quasi-two-, and two-dimensional metal-organic coordination structures.

    Science.gov (United States)

    Lin, Tao; Wu, Qi; Liu, Jun; Shi, Ziliang; Liu, Pei Nian; Lin, Nian

    2015-03-14

    Four types of metal-organic structures exhibiting specific dimensionality were studied using scanning tunneling microscopy and Monte Carlo simulations. The four structures were self-assembled out of specifically designed molecular building blocks via the same coordination motif on an Au(111) surface. We found that the four structures behaved differently in response to thermal annealing treatments: The two-dimensional structure was under thermodynamic control while the structures of lower dimension were under kinetic control. Monte Carlo simulations revealed that the self-assembly pathways of the four structures are associated with the characteristic features of their specific heat. These findings provide insights into how the dimensionality of supramolecular coordination structures affects their thermodynamic properties.

  2. A two-dimensional Riemann solver with self-similar sub-structure - Alternative formulation based on least squares projection

    Science.gov (United States)

    Balsara, Dinshaw S.; Vides, Jeaniffer; Gurski, Katharine; Nkonga, Boniface; Dumbser, Michael; Garain, Sudip; Audit, Edouard

    2016-01-01

    Just as the quality of a one-dimensional approximate Riemann solver is improved by the inclusion of internal sub-structure, the quality of a multidimensional Riemann solver is also similarly improved. Such multidimensional Riemann problems arise when multiple states come together at the vertex of a mesh. The interaction of the resulting one-dimensional Riemann problems gives rise to a strongly-interacting state. We wish to endow this strongly-interacting state with physically-motivated sub-structure. The self-similar formulation of Balsara [16] proves especially useful for this purpose. While that work is based on a Galerkin projection, in this paper we present an analogous self-similar formulation that is based on a different interpretation. In the present formulation, we interpret the shock jumps at the boundary of the strongly-interacting state quite literally. The enforcement of the shock jump conditions is done with a least squares projection (Vides, Nkonga and Audit [67]). With that interpretation, we again show that the multidimensional Riemann solver can be endowed with sub-structure. However, we find that the most efficient implementation arises when we use a flux vector splitting and a least squares projection. An alternative formulation that is based on the full characteristic matrices is also presented. The multidimensional Riemann solvers that are demonstrated here use one-dimensional HLLC Riemann solvers as building blocks. Several stringent test problems drawn from hydrodynamics and MHD are presented to show that the method works. Results from structured and unstructured meshes demonstrate the versatility of our method. The reader is also invited to watch a video introduction to multidimensional Riemann solvers on http://www.nd.edu/~dbalsara/Numerical-PDE-Course.

  3. A Vacuum Ultraviolet Absorption Array Spectrometer as a Selective Detector for Comprehensive Two-Dimensional Gas Chromatography: Concept and First Results.

    Science.gov (United States)

    Gröger, Thomas; Gruber, Beate; Harrison, Dale; Saraji-Bozorgzad, Mohammad; Mthembu, Makhosazana; Sutherland, Aimée; Zimmermann, Ralf

    2016-03-15

    Fast and selective detectors are very interesting for comprehensive two-dimensional gas chromatography (GC × GC). This is particularly true if the detector system can provide additional spectroscopic information on the compound structure and/or functionality. Other than mass spectrometry (MS), only optical spectroscopic detectors are able to provide selective spectral information. However, until present the application of optical spectroscopy technologies as universal detectors for GC × GC has been restricted mainly due to physical limitations such as insufficient acquisition speed or high detection limits. A recently developed simultaneous-detection spectrometer working in the vacuum ultraviolet (VUV) region of 125-240 nm overcomes these limitations and meets all the criteria of a universal detector for GC × GC. Peak shape and chromatographic resolution is preserved and unique spectral information, complementary to mass spectrometry data, is gained. The power of this detector is quickly recognized as it has the ability to discriminate between isomeric compounds or difficult to separate structurally related isobaric species; thus, it provides additional selectivity. A further promising feature of this detector is the data analysis concept of spectral filtering, which is accomplished by targeting special electronic transitions that allows for a fast screening of GC × GC chromatograms for designated compound classes.

  4. Evolution and structure of the plasma of current sheets forming in two-dimensional magnetic fields with a null line at low initial gas ionization and their interpretation

    Science.gov (United States)

    Ostrovskaya, G. V.; Frank, A. G.

    2012-04-01

    An analysis of the experimental data obtained by holographic interferometry in our work [1] makes it possible to explain most of the observed specific features of the structure and evolution of the plasma sheets developing in a two-dimensional magnetic field with a null line in a plasma with a low initial degree of ionization (≈10-4). The following two processes are shown to play a key role here: additional gas ionization in an electric field and the peculiarities of plasma dynamics in a current sheet expanding in time.

  5. Two-dimensional Network Crown Ether Complex. Synthesis and Crystal Structure of 18-Crown-6 Complex: [K(18-C-6) ]2[Cd-(mnt)2

    Institute of Scientific and Technical Information of China (English)

    WANG,Da-Qi(王大奇); YU,Qing-Jiang(于清江); DOU,Jian-Min(窦建民)

    2002-01-01

    The novel complex [K(18-C-6)]2[Cd(mnt)2] [18-C-6=18-crown-6, mnt= 1, 2-dicyanoethen-1, 2-dithiolate, C2S2-(CN)2- 2] was synthesized and characterized by elemental analysis,IR spectrum and X-ray diffraction analysis. The complex displays two-dimensional network structure of [ K(18-C-6)] complex segments and [Cd(mnt)2] complex segment bridged by S-K-S, S-K-N and N-K-N interactions between adjacent [K(18-C-6)] and [Cd(mnt)2] units.

  6. Complete photonic band gaps and tunable self-collimation in the two-dimensional plasma photonic crystals with a new structure

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Hai-Feng, E-mail: hanlor@163.com [Key Laboratory of Radar Imaging and Microwave Photonics (Nanjing University of Aeronautics and Astronautics), Ministry of Education, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); Nanjing Artillery Academy, Nanjing 211132 (China); Ding, Guo-Wen; Li, Hai-Ming; Liu, Shao-Bin [Key Laboratory of Radar Imaging and Microwave Photonics (Nanjing University of Aeronautics and Astronautics), Ministry of Education, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)

    2015-02-15

    In this paper, the properties of complete photonic band gaps (CPBGs) and tunable self-collimation in two-dimensional plasma photonic crystals (2D PPCs) with a new structure in square lattices, whose dielectric fillers (GaAs) are inserted into homogeneous and nomagnetized plasma background are theoretically investigated by a modified plane wave expansion (PWE) method with a novel technique. The novel PWE method can be utilized to compute the dispersion curves of 2D PPCs with arbitrary-shaped cross section in any lattices. As a comparison, CPBGs of PPCs for four different configurations are numerically calculated. The computed results show that the proposed design has the advantages of achieving the larger CPBGs compared to the other three configurations. The influences of geometric parameters of filled unit cell and plasma frequency on the properties of CPBGs are studied in detail. The calculated results demonstrate that CPBGs of the proposed 2D PPCs can be easily engineered by changing those parameters, and the larger CPBGs also can be obtained by optimization. The self-collimation in such 2D PPCs also is discussed in theory under TM wave. The theoretical simulations reveal that the self-collimation phenomena can be found in the TM bands, and both the frequency range of self-collimation and the equifrequency surface contours can be tuned by the parameters as mentioned above. It means that the frequency range and direction of electromagnetic wave can be manipulated by designing, as it propagates in the proposed PPCs without diffraction. Those results can hold promise for designing the tunable applications based on the proposed PPCs.

  7. Two-dimensional optical spectroscopy

    CERN Document Server

    Cho, Minhaeng

    2009-01-01

    Discusses the principles and applications of two-dimensional vibrational and optical spectroscopy techniques. This book provides an account of basic theory required for an understanding of two-dimensional vibrational and electronic spectroscopy.

  8. Comparison between theoretical and experimental results for energy states of two-dimensional electron gas in pseudomorphically strained InAs high-electron-mobility transistors

    Science.gov (United States)

    Nishio, Yui; Tange, Takahiro; Hirayama, Naomi; Iida, Tsutomu; Takanashi, Yoshifumi

    2014-01-01

    The energy states of a two-dimensional electron gas (2DEG) in high-electron-mobility transistors with a pseudomorphically strained InAs channel (PHEMTs) were analyzed rigorously using a recently established theory that takes into account the nonparabolicity of the conduction band of the channel layer. The sheet density of the 2DEG in InxGa1-xAs-PHEMTs and the drain I-V characteristics of those devices were calculated theoretically and compared with the density and characteristics obtained experimentally. Not only the calculated threshold voltage (VTH) but also the calculated transconductance agreed fairly well with the corresponding values obtained experimentally. When the effects of the compositions of the InxGa1-xAs subchannel layer in the composite channel and the channel layer on energy states of 2DEG were investigated in order to establish a guiding principle for a design of the channel structure in PHEMTs, it was found that VTH is determined by the effective conduction-band offset energy ΔEC between the InAlAs barrier and the channel layers.

  9. Crosslinked structurally-tuned polymeric ionic liquids as stationary phases for the analysis of hydrocarbons in kerosene and diesel fuels by comprehensive two-dimensional gas chromatography.

    Science.gov (United States)

    Zhang, Cheng; Park, Rodney A; Anderson, Jared L

    2016-04-01

    Structurally-tuned ionic liquids (ILs) have been previously applied as the second dimension column in comprehensive two-dimensional gas chromatography (GC×GC) and have demonstrated high selectivity in the separation of individual aliphatic hydrocarbons from other aliphatic hydrocarbons. However, the maximum operating temperatures of these stationary phases limit the separation of analytes with high boiling points. In order to address this issue, a series of polymeric ionic liquid (PIL)-based stationary phases were prepared in this study using imidazolium-based IL monomers via in-column free radical polymerization. The IL monomers were functionalized with long alkyl chain substituents to provide the needed selectivity for the separation of aliphatic hydrocarbons. Columns were prepared with different film thicknesses to identify the best performing stationary phase for the separation of kerosene. The bis[(trifluoromethyl)sulfonyl]imide ([NTf2](-))-based PIL stationary phase with larger film thickness (0.28μm) exhibited higher selectivity for aliphatic hydrocarbons and showed a maximum allowable operating temperature of 300°C. PIL-based stationary phases containing varied amount of IL-based crosslinker were prepared to study the effect of the crosslinker on the selectivity and thermal stability of the resulting stationary phase. The optimal resolution of aliphatic hydrocarbons was achieved when 50% (w/w) of crosslinker was incorporated into the PIL-based stationary phase. The resulting stationary phase exhibited good selectivity for different groups of aliphatic hydrocarbons even after being conditioned at 325°C. Finally, the crosslinked PIL-based stationary phase was compared with SUPELCOWAX 10 and DB-17 columns for the separation of aliphatic hydrocarbons in diesel fuel. Better resolution of aliphatic hydrocarbons was obtained when employing the crosslinked PIL-based stationary phase as the second dimension column.

  10. Formation of a protocluster: A virialized structure from gravoturbulent collapse. II. A two-dimensional analytical model for a rotating and accreting system

    Science.gov (United States)

    Lee, Yueh-Ning; Hennebelle, Patrick

    2016-06-01

    Context. Most stars are born in the gaseous protocluster environment where the gas is reprocessed after the global collapse from the diffuse molecular cloud. The knowledge of this intermediate step gives more accurate constraints on star formation characteristics. Aims: We demonstrate that a virialized globally supported structure, in which star formation happens, is formed out of a collapsing molecular cloud, and we derive a mapping from the parent cloud parameters to the protocluster to predict its properties with a view to confront analytical calculations with observations and simulations. Methods: We decomposed the virial theorem into two dimensions to account for the rotation and the flattened geometry. Equilibrium was found by balancing rotation, turbulence, and self-gravity, while turbulence was maintained through accretion driving and it dissipates in one crossing time. We estimated the angular momentum and the accretion rate of the protocluster from the parent cloud properties. Results: The two-dimensional virial model predicts the size and velocity dispersion given the mass of the protocluster and that of the parent cloud. The gaseous protoclusters lie on a sequence of equilibrium with the trend R ~ M0.5 with limited variations, depending on the evolutionary stage, parent cloud, and parameters that are not well known, such as turbulence driving efficiency by accretion and turbulence anisotropy. The model reproduces observations and simulation results successfully. Conclusions: The properties of protoclusters follow universal relations and they can be derived from that of the parent cloud. The gaseous protocluster is an important primary stage of stellar cluster formation, and should be taken into account when studying star formation. Using simple estimates to infer the peak position of the core mass function (CMF) we find a weak dependence on the cluster mass, suggesting that the physical conditions inside protoclusters may contribute to set a CMF, and by

  11. A new integral representation for quasiperiodic fields and its application to two-dimensional band structure calculations

    CERN Document Server

    Barnett, Alex H

    2010-01-01

    In this paper, we consider band-structure calculations governed by the Helmholtz or Maxwell equations in piecewise homogeneous periodic materials. Methods based on boundary integral equations are natural in this context, since they discretize the interface alone and can achieve high order accuracy in complicated geometries. In order to handle the quasi-periodic conditions which are imposed on the unit cell, the free-space Green's function is typically replaced by its quasi-periodic cousin. Unfortunately, the quasi-periodic Green's function diverges for families of parameter values that correspond to resonances of the empty unit cell. Here, we bypass this problem by means of a new integral representation that relies on the free-space Green's function alone, adding auxiliary layer potentials on the boundary of the unit cell itself. An important aspect of our method is that by carefully including a few neighboring images, the densities may be kept smooth and convergence rapid. This framework results in an integr...

  12. Band structure effects on resonant tunneling in III-V quantum wells versus two-dimensional vertical heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, Philip M., E-mail: philip.campbell@gatech.edu [School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Electronic Systems Laboratory, Georgia Tech Research Institute, Atlanta, Georgia 30332 (United States); Tarasov, Alexey; Joiner, Corey A.; Vogel, Eric M. [School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Ready, W. Jud [Electronic Systems Laboratory, Georgia Tech Research Institute, Atlanta, Georgia 30332 (United States)

    2016-01-14

    Since the invention of the Esaki diode, resonant tunneling devices have been of interest for applications including multi-valued logic and communication systems. These devices are characterized by the presence of negative differential resistance in the current-voltage characteristic, resulting from lateral momentum conservation during the tunneling process. While a large amount of research has focused on III-V material systems, such as the GaAs/AlGaAs system, for resonant tunneling devices, poor device performance and device-to-device variability have limited widespread adoption. Recently, the symmetric field-effect transistor (symFET) was proposed as a resonant tunneling device incorporating symmetric 2-D materials, such as transition metal dichalcogenides (TMDs), separated by an interlayer barrier, such as hexagonal boron-nitride. The achievable peak-to-valley ratio for TMD symFETs has been predicted to be higher than has been observed for III-V resonant tunneling devices. This work examines the effect that band structure differences between III-V devices and TMDs has on device performance. It is shown that tunneling between the quantized subbands in III-V devices increases the valley current and decreases device performance, while the interlayer barrier height has a negligible impact on performance for barrier heights greater than approximately 0.5 eV.

  13. Spatial structure of correlations around a quantum impurity at the edge of a two-dimensional topological insulator

    Science.gov (United States)

    Allerdt, Andrew; Feiguin, A. E.; Martins, G. B.

    2017-07-01

    We calculate exact zero-temperature real-space properties of a substitutional magnetic impurity coupled to the edge of a zigzag silicenelike nanoribbon. Using a Lanczos transformation [A. Allerdt et al., Phys. Rev. B 91, 085101 (2015), 10.1103/PhysRevB.91.085101] and the density-matrix renormalization-group method, we obtain a realistic description of stanene and germanene that includes the bulk and the edges as boundary one-dimensional helical metallic states. Our results for substitutional impurities indicate that the development of a Kondo state and the structure of the spin correlations between the impurity and the electron spins in the metallic edge state depend considerably on the location of the impurity. More specifically, our real-space resolution allows us to conclude that there is a sharp distinction between the impurity being located at a crest or a trough site at the zigzag edge. We also observe, as expected, that the spin correlations are anisotropic due to an emerging Dzyaloshinskii-Moriya interaction with the conduction electrons and that the edges scatter from the impurity and "snake" or circle around it. Our estimates for the Kondo temperature indicate that there is a very weak enhancement due to the presence of spin-orbit coupling.

  14. Three-dimensional structural damage localization system and method using layered two-dimensional array of capacitance sensors

    Science.gov (United States)

    Curry, Mark A (Inventor); Senibi, Simon D (Inventor); Banks, David L (Inventor)

    2010-01-01

    A system and method for detecting damage to a structure is provided. The system includes a voltage source and at least one capacitor formed as a layer within the structure and responsive to the voltage source. The system also includes at least one sensor responsive to the capacitor to sense a voltage of the capacitor. A controller responsive to the sensor determines if damage to the structure has occurred based on the variance of the voltage of the capacitor from a known reference value. A method for sensing damage to a structure involves providing a plurality of capacitors and a controller, and coupling the capacitors to at least one surface of the structure. A voltage of the capacitors is sensed using the controller, and the controller calculates a change in the voltage of the capacitors. The method can include signaling a display system if a change in the voltage occurs.

  15. Energetic, spatial, and momentum character of the electronic structure at a buried interface: The two-dimensional electron gas between two metal oxides

    Science.gov (United States)

    Nemšák, S.; Conti, G.; Gray, A. X.; Palsson, G. K.; Conlon, C.; Eiteneer, D.; Keqi, A.; Rattanachata, A.; Saw, A. Y.; Bostwick, A.; Moreschini, L.; Rotenberg, E.; Strocov, V. N.; Kobayashi, M.; Schmitt, T.; Stolte, W.; Ueda, S.; Kobayashi, K.; Gloskovskii, A.; Drube, W.; Jackson, C. A.; Moetakef, P.; Janotti, A.; Bjaalie, L.; Himmetoglu, B.; Van de Walle, C. G.; Borek, S.; Minar, J.; Braun, J.; Ebert, H.; Plucinski, L.; Kortright, J. B.; Schneider, C. M.; Balents, L.; de Groot, F. M. F.; Stemmer, S.; Fadley, C. S.

    2016-06-01

    The interfaces between two condensed phases often exhibit emergent physical properties that can lead to new physics and novel device applications and are the subject of intense study in many disciplines. We here apply experimental and theoretical techniques to the characterization of one such interesting interface system: the two-dimensional electron gas (2DEG) formed in multilayers consisting of SrTi O3 (STO) and GdTi O3 (GTO). This system has been the subject of multiple studies recently and shown to exhibit very high carrier charge densities and ferromagnetic effects, among other intriguing properties. We have studied a 2DEG-forming multilayer of the form [6unit cells (u .c .) STO /3 u .c .of GTO ] 20 using a unique array of photoemission techniques including soft and hard x-ray excitation, soft x-ray angle-resolved photoemission, core-level spectroscopy, resonant excitation, and standing-wave effects, as well as theoretical calculations of the electronic structure at several levels and of the actual photoemission process. Standing-wave measurements below and above a strong resonance have been exploited as a powerful method for studying the 2DEG depth distribution. We have thus characterized the spatial and momentum properties of this 2DEG in detail, determining via depth-distribution measurements that it is spread throughout the 6 u.c. layer of STO and measuring the momentum dispersion of its states. The experimental results are supported in several ways by theory, leading to a much more complete picture of the nature of this 2DEG and suggesting that oxygen vacancies are not the origin of it. Similar multitechnique photoemission studies of such states at buried interfaces, combined with comparable theory, will be a very fruitful future approach for exploring and modifying the fascinating world of buried-interface physics and chemistry.

  16. SINGER: A Computer Code for General Analysis of Two-Dimensional Reinforced Concrete Structures. Volume 1. Solution Process

    Science.gov (United States)

    1975-05-01

    34 Journal of the Structural Division. ASCE, Vol. 99, St. 6, June 1973, pp. 1091-1187. 2. Bogner, F. K., Malletr, R. H., Minich , M. D., and Schmit, L. A...201. 6. Bogner, F. K., Mallett, R. H., Minich , M. D., and Schmit, L. A., "Development and Evaluation of Energy Search Methods of Non- linear... Minich , -1. ü., "An linergy Search Method for Nonlinear Structural Analysis," Case Institute of Technology, EDC Report 2-64-5, January

  17. Numerical results on the short-range spin correlation functions in the ground state of the two-dimensional Hubbard model

    Science.gov (United States)

    Qin, Mingpu; Shi, Hao; Zhang, Shiwei

    2017-08-01

    Optical lattice experiments with ultracold fermion atoms and quantum gas microscopy have recently realized direct measurements of magnetic correlations at the site-resolved level. We calculate the short-range spin-correlation functions in the ground state of the two-dimensional repulsive Hubbard model with the auxiliary-field quantum Monte Carlo (AFQMC) method. The results are numerically exact at half filling where the fermion sign problem is absent. Away from half filling, we employ the constrained path AFQMC approach to eliminate the exponential computational scaling from the sign problem. The constraint employs unrestricted Hartree-Fock trial wave functions with an effective interaction strength U , which is optimized self-consistently within AFQMC. Large supercells are studied, with twist averaged boundary conditions as needed, to reach the thermodynamic limit. We find that the nearest-neighbor spin correlation always increases with the interaction strength U , contrary to the finite-temperature behavior where a maximum is reached at a finite U value. We also observe a change of sign in the next-nearest-neighbor spin correlation with increasing density, which is a consequence of the buildup of the long-range antiferromagnetic correlation. We expect the results presented in this paper to serve as a benchmark as lower temperatures are reached in ultracold atom experiments.

  18. Two-dimensional function photonic crystals

    Science.gov (United States)

    Liu, Xiao-Jing; Liang, Yu; Ma, Ji; Zhang, Si-Qi; Li, Hong; Wu, Xiang-Yao; Wu, Yi-Heng

    2017-01-01

    In this paper, we have studied two-dimensional function photonic crystals, in which the dielectric constants of medium columns are the functions of space coordinates , that can become true easily by electro-optical effect and optical kerr effect. We calculated the band gap structures of TE and TM waves, and found the TE (TM) wave band gaps of function photonic crystals are wider (narrower) than the conventional photonic crystals. For the two-dimensional function photonic crystals, when the dielectric constant functions change, the band gaps numbers, width and position should be changed, and the band gap structures of two-dimensional function photonic crystals can be adjusted flexibly, the needed band gap structures can be designed by the two-dimensional function photonic crystals, and it can be of help to design optical devices.

  19. The structures and properties of the new two-dimensional inorganic–organic hybrid materials based on the molybdate chains

    Energy Technology Data Exchange (ETDEWEB)

    Li, Na; Mu, Bao; Cao, Xinyu; Huang, Rudan, E-mail: huangrd@bit.edu.cn

    2014-09-15

    A series of inorganic organic hybrid materials based on polyoxometalates(POMs), namely, [M{sup II}(HL){sub 2}(H{sub 2}O){sub 2}][Mo{sup VI}{sub 6}O{sub 20}] [M=Co (1), Ni (2), Cu (3), Zn (4)], [Mn{sup IV}L{sub 2}(H{sub 2}O){sub 2}][Mo{sup VI}{sub 6}O{sub 20}] (5), and (HL){sub 3}PMO{sub 12}O{sub 40} (6) [L=3-(4-pyridyl)pyrazole], have been synthesized. The compounds have been characterized by elemental analysis, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1–5 are isostructural. It is worth noting that the polyanions are bridged by Mo–O–Mo to form 1D inorganic chains, which are further connected via M ions to form 2D nets. In compound 6, the ligands are used as the positive ions to balance the charge of the compound. Moreover, the magnetic properties of compound 5 have also been investigated in detail. - Graphical abstract: In complex 1, The Co ion is six coordinated by four oxygen atoms from two Mo{sub 6}O{sub 20} and two water molecules, and two N atoms from two different ligand. It is noticeable that there is an one-dimensional chain molybdate, which is combined by O–Mo–O, then the chain parallel with each other, the Mo{sub 6} anion acts as a bidentate ligand providing O7 atoms to bridge CoII ions to form a 2D inorganic layer. Finally every nets become 3D structure by hydrogen bond. - Highlights: • Novel inorganic–organic hybrid materials have been prepared. • Compounds 1–5 contain the 1D molybdate chains composed of (MoO{sub 6}) octahedra. • The 1D chains parallel with each other to form a 2D inorganic layer.

  20. Effects of electric field on structures and dynamics in a two-dimensional dust dipole particle system

    Science.gov (United States)

    Hou, X. N.; Liu, Y. H.; Huang, F.; Jiang, S. Z.; Chen, Z. Y.; Zhang, R. Y.

    2016-09-01

    Effects of radial electric field on the structures and dynamics of dust dipoles are studied by molecular dynamics simulations. The dipoles' configuration and mean distance to the system center are used to illustrate the structures of the whole system. It is shown that the dipole particles can arrange themselves into ring-like structures in the absence of external electric field, which can gradually transform to vortex, and then to radial arrangement with the increase of the strength of electric field. The trajectories, mean square displacement, and the mean speed in radial and tangential directions of dipoles are investigated to depict the effects of the radial electric filed on the collective motion of dust dipolar particles, which are closely associated with the growth of dust particle, especially for the formation of rod-like and some other complex fractal dust particles.

  1. Ultrafast Structural Fluctuations of Myoglobin-Bound Thiocyanate and Selenocyanate Ions Measured with Two-Dimensional Infrared Photon Echo Spectroscopy.

    Science.gov (United States)

    Maj, Michał; Kwak, Kyungwon; Cho, Minhaeng

    2015-11-16

    Structural dynamics within the distal cavity of myoglobin protein is investigated using 2D-IR and IR pump-probe spectroscopy of the N≡C stretch modes of heme-bound thiocyanate and selenocyanate ions. Although myoglobin-bound thiocyanate group shows a doublet in its IR absorption spectrum, no cross peaks originating from chemical exchange between the two components are observed in the time-resolved 2D IR spectra within the experimental time window. Frequency-frequency correlation functions of the two studied anionic ligands are obtained by means of a few different analysis approaches; these functions were then used to elucidate the differences in structural fluctuation around ligand, ligand-protein interactions, and the degree of structural heterogeneity within the hydrophobic pocket of these myoglobin complexes.

  2. Evaluation of left ventricular structures in normotensive and hypertensive subjects by two-dimensional echocardiography: Anthropometric correlates in hypertension

    Directory of Open Access Journals (Sweden)

    Mr. Agbo Julius Amaechi

    2008-07-01

    Full Text Available This study was conducted with the objective to establish a nomogram for some left ventricular structures and their alterations in hypertension. Correlations between left ventricular structures and anthropometric variables in hypertension were also established. A sample of 320 normotensive and 80 hypertensive subjects were studied. Echocardiograhic end diastolic diameter, posterior wall thickness and septal wall thickness were obtained. Subject height, weight, age and blood pressures were obtained. Blood pressures were measured in sitting position. The values of left ventricular mass (LVM, left ventricular mass index (LVMI and left relative wall thickness (RWT were computed. Parametric tests were conducted. Tests were two tailed with P < 0.05 indicating statistical significance. Normal values of left ventricular structures were established; LVM: 63.72g – 336.18g, LVMI: 38.16g/m – 222.64g/m, and RWT: 0.25 – 0.52. Significant differences (P < 0.05 were established in LVM, LVMI and RWT between normotensive and hypertensive subjects. Positive and significant correlations were noted between these variables and systolic blood pressure in hypertensive subjects. A simple linear regression of RWT on Body surface area gives RWT = - 0.058 BSA + 0.475 in normotensive subjects. Normal values of left ventricular structures and a linear regression model have been established which could be used in the assessment of morbidity in hypertension.

  3. Two dimensional Coupled Eulerian Lagrangian (CEL) model for banded structure prediction in friction stir welding with trigonal tool

    Science.gov (United States)

    Tongne, A.; Robe, H.; Desrayaud, C.; Jahazi, M.; Feulvarch, E.

    2016-10-01

    A finite element model has been developed by means of a coupled Eulerian-Lagrangian approach. The banded structure which is related to the periodical material deposition is predicted in two dimensions as the experimental investigation shows that, during FSW with trigonal tool, the material flow operates mainly in the welded plates plan.

  4. One and Two-dimensional Structures of a New Oxamido Copper(Ⅱ) Complex with Phthalato Bridged

    Institute of Scientific and Technical Information of China (English)

    CHEN Jing; JIANG Zong-Hui; LIAO Dai-Zheng; YAN Shi-Ping

    2005-01-01

    A new o-phthalato-bridged oxamide copper(Ⅱ) complex 1, {[Cu2(oxap)](pht)4H2O}n (oxap = N, N'-bis(2-aminopropyl)oxamide, pht = phthalate dianion), has been prepared and structurally characterized. It crystallizes in monoclinic, space group C2/c with a = 23.424(4), b = 7.9696(14), c = 15.727(3) (A), β = 129.617(2)°, C16H28Cu2N4O10, Mr = 563.50, V = 2261.6(7) (A)3, Z = 4, Dc = 1.655 g/cm3,μ(MoKα) = 1.939 mm 1, F(000) = 1160, the final R = 0.0393 and wR = 0.0928 for 1707 observed reflections with I > 2σ(Ⅰ). Single-crystal X-ray analysis reveals that 1 displays a one-dimensional zigzag chain structure, in which each Cu(oxap) moiety adopting trans-conformation is connected by μ1,6-phthalate anion bridges, and these zigzag chains are further linked by anotherμ1,6-phthalate anion bridge to form a 2D sheet structure. The polar guest water molecules reside in the inter- and intrasheets to stabilize the whole crystal structure.

  5. Binding energy of two-dimensional biexcitons

    DEFF Research Database (Denmark)

    Singh, Jai; Birkedal, Dan; Vadim, Lyssenko;

    1996-01-01

    Using a model structure for a two-dimensional (2D) biexciton confined in a quantum well, it is shown that the form of the Hamiltonian of the 2D biexciton reduces into that of an exciton. The binding energies and Bohr radii of a 2D biexciton in its various internal energy states are derived...... analytically using the fractional dimension approach. The ratio of the binding energy of a 2D biexciton to that of a 2D exciton is found to be 0.228, which agrees very well with the recent experimental value. The results of our approach are compared with those of earlier theories....

  6. Structure and magnetic properties of the two-dimensional ferrimagnet (NEt4)[[Mn(salen)]2Fe(CN)6]: investigation of magnetic anisotropy on a single crystal.

    Science.gov (United States)

    Miyasaka, Hitoshi; Ieda, Hidenori; Matsumoto, Naohide; Sugiura, Ken-ichi; Yamashita, Masahiro

    2003-06-02

    The title compound, (NEt(4))[[Mn(salen)](2)Fe(CN)(6)] (1), was synthesized via a 1:1 reaction of [Mn(salen)(H(2)O)]ClO(4) with (NEt(4))(3)[Fe(CN)(6)] in a methanol/ethanol medium (NEt(4)(+) = tetraethylammonium cation, salen(2)(-) = N,N'-ethylenebis(salicylidene)iminate). The two-dimensional layered structure of 1 was revealed by X-ray crystallographic analysis: 1 crystallizes in monoclinic space group P2(1)/c with cell dimensions of a = 12.3660(8) A, b = 15.311(1) A, c = 12.918(1) A, beta = 110.971(4) degrees, Z = 2 and is isostructural to the previously synthesized compound, (NEt(4))[[Mn(5-Clsalen)](2)Fe(CN)(6)] (5-Clsalen(2-) = N,N'-ethylenebis(5-chlorosalicylidene)iminate; Miyasaka, H.; Matsumoto, N.; Re, N.; Gallo, E.; Floriani, C. Inorg. Chem. 1997, 36, 670). The Mn ion is surrounded by an equatorial salen quadridentate ligand and two axial nitrogen atoms from the [Fe(CN)(6)](3-) unit, the four Fe[bond]CN groups of which coordinate to the Mn ions of [Mn(salen)](+) units, forming a two-dimensional network having [[bond]Mn[bond]NC[bond]Fe[bond]CN[bond

  7. Effect of the initial plasma parameters on the structure of the current sheets developing in two-dimensional magnetic fields with a null line

    Science.gov (United States)

    Ostrovskaya, G. V.; Frank, A. G.; Bogdanov, S. Yu.

    2010-07-01

    The effect of the initial plasma parameters on the structure of the plasma of the current sheets that form in two-dimensional magnetic fields with a null line is studied by holographic interferometry. The evolution of the plasma sheets that develop in an initial low-density plasma, where a gas is mainly ionized by a pulse current passing through the plasma and initiating the formation of a current sheet, has been comprehensively studied for the first time. At the early stage of evolution, the spatial structure of such a plasma sheet differs substantially from the classic current sheets forming in a dense plasma. Nevertheless, extended plasma sheets with similar parameters form eventually irrespective of the initial plasma density.

  8. Two-dimensional (2D) infrared correlation study of the structural characterization of a surface immobilized polypeptide film stimulated by pH

    Science.gov (United States)

    Chae, Boknam; Son, Seok Ho; Kwak, Young Jun; Jung, Young Mee; Lee, Seung Woo

    2016-11-01

    The pH-induced structural changes to surface immobilized poly (L-glutamic acid) (PLGA) films were examined by Fourier transform infrared (FTIR) spectroscopy and two-dimensional (2D) correlation analysis. Significant spectral changes were observed in the FTIR spectra of the surface immobilized PLGA film between pH 6 and 7. The 2D correlation spectra constructed from the pH-dependent FTIR spectra of the surface immobilized PLGA films revealed the spectral changes induced by the alternations of the protonation state of the carboxylic acid group in the PLGA side chain. When the pH was increased from 6 to 8, weak spectral changes in the secondary structure of the PLGA main chain were induced by deprotonation of the carboxylic acid side group.

  9. Cancellation exponent and multifractal structure in two-dimensional magnetohydrodynamics: direct numerical simulations and Lagrangian averaged modeling.

    Science.gov (United States)

    Graham, Jonathan Pietarila; Mininni, Pablo D; Pouquet, Annick

    2005-10-01

    We present direct numerical simulations and Lagrangian averaged (also known as alpha model) simulations of forced and free decaying magnetohydrodynamic turbulence in two dimensions. The statistics of sign cancellations of the current at small scales is studied using both the cancellation exponent and the fractal dimension of the structures. The alpha model is found to have the same scaling behavior between positive and negative contributions as the direct numerical simulations. The alpha model is also able to reproduce the time evolution of these quantities in free decaying turbulence. At large Reynolds numbers, an independence of the cancellation exponent with the Reynolds numbers is observed.

  10. Two-dimensional inorganic–organic hybrid semiconductors composed of double-layered ZnS and monoamines with aromatic and heterocyclic aliphatic rings: Syntheses, structures, and properties

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Sujing; Li, Jing, E-mail: jingli@rutgers.edu

    2015-04-15

    As an addition to the II–VI based inorganic–organic hybrid semiconductor family, five new two-dimensional (2D) double-layered structures have been synthesized employing monoamines with different aromatic or heterocyclic aliphatic rings. Zn{sub 2}S{sub 2}(bza) (1), Zn{sub 2}S{sub 2}(mbza) (2), Zn{sub 2}S{sub 2}(fbza) (3), Zn{sub 2}S{sub 2}(pca) (4), and Zn{sub 2}S{sub 2}(thfa) (5) (bza=benzylamine, mbza=4-methoxybenzylamine, fbza=4-flurobenzylamine, pca=3-picolylamine, and thfa=tetrahydrofurfurylamine) are prepared by solvothermal reactions and characterized by different analytical methods, including powder X-ray diffraction, optical diffuse reflection, thermogravimetric analysis and photoluminescence spectroscopy. The powder X-ray diffraction patterns show that all five compounds adopt 2D double-layered structures. Optical diffuse reflectance spectra of these compounds suggest that they have notably lower band gaps than those of the similar compounds composed of aliphatic alkyl amines. Their photoluminescence properties and thermal stability are also analyzed. - Graphical abstract: Five new members of two-dimensional double-layered 2D-Zn{sub 2}S{sub 2}(L) (L=Ligand) structures employing monoamines with different aromatic or heterocyclic aliphatic rings have been designed, synthesized, and characterized. - Highlights: • A new sub-family of II-VI based hybrid semiconductors are designed, synthesized, and structurally characterized using amines with aromatic or aliphatic cyclic rings. • These compounds have notably lower band gaps than those made of aliphatic alkyl amines, greatly broadening the range of band gaps of this material family. • They emit strongly with systematically tunable emission intensity and energy.

  11. Two-dimensional quantum repeaters

    Science.gov (United States)

    Wallnöfer, J.; Zwerger, M.; Muschik, C.; Sangouard, N.; Dür, W.

    2016-11-01

    The endeavor to develop quantum networks gave rise to a rapidly developing field with far-reaching applications such as secure communication and the realization of distributed computing tasks. This ultimately calls for the creation of flexible multiuser structures that allow for quantum communication between arbitrary pairs of parties in the network and facilitate also multiuser applications. To address this challenge, we propose a two-dimensional quantum repeater architecture to establish long-distance entanglement shared between multiple communication partners in the presence of channel noise and imperfect local control operations. The scheme is based on the creation of self-similar multiqubit entanglement structures at growing scale, where variants of entanglement swapping and multiparty entanglement purification are combined to create high-fidelity entangled states. We show how such networks can be implemented using trapped ions in cavities.

  12. Understanding the two-dimensional ionization structure in luminous infrared galaxies. A near-IR integral field spectroscopy perspective

    CERN Document Server

    Colina, Luis; Arribas, Santiago; Riffel, Rogerio; Riffel, Rogemar A; Rodriguez-Ardila, Alberto; Pastoriza, Miriani; Storchi-Bergmann, Thaisa; Alonso-Herrero, Almudena; Sales, Dinalva

    2015-01-01

    We investigate the 2D excitation structure of the ISM in a sample of LIRGs and Seyferts using near-IR IFS. This study extends to the near-IR the well-known optical and mid-IR emission line diagnostics used to classify activity in galaxies. Based on the spatially resolved spectroscopy of prototypes, we identify in the [FeII]1.64/Br$\\gamma$ - H_2 1-0S(1)/Br$\\gamma$ plane regions dominated by the different heating sources, i.e. AGNs, young MS massive stars, and evolved stars i.e. supernovae. The ISM in LIRGs occupy a wide region in the near-IR diagnostic plane from -0.6 to +1.5 and from -1.2 to +0.8 (in log units) for the [FeII]/Br$\\gamma$ and H_2/Br$\\gamma$ line ratios, respectively. The corresponding median(mode) ratios are +0.18(0.16) and +0.02(-0.04). Seyferts show on average larger values by factors ~2.5 and ~1.4 for the [FeII]/Br$\\gamma$ and H_2/Br$\\gamma$ ratios, respectively. New areas and relations in the near-IR diagnostic plane are defined for the compact, high surface brightness regions dominated by ...

  13. A two-dimensional zinc(II) coordination polymer based on mixed dimethyl succinate and bipyridine ligands: synthesis, structure, thermostability and luminescence properties.

    Science.gov (United States)

    Liu, Yang; Feng, Yong Lan; Fu, Wei Wei

    2016-04-01

    From the viewpoint of crystal engineering, the construction of crystalline polymeric materials requires a rational choice of organic bridging ligands for the self-assembly process. Multicarboxylate ligands are of particular interest due to their strong coordination activity towards metal ions, as well as their various coordination modes and versatile conformations. The structural chemistry of dicarboxylate-based coordination polymers of transition metals has been developed through the grafting of N-containing organic linkers into carboxylate-bridged transition metal networks. A new luminescent two-dimensional zinc(II) coordination polymer containing bridging 2,2-dimethylsuccinate and 4,4'-bipyridine ligands, namely poly[[aqua(μ2-4,4'-bipyridine-κ(2)N:N')bis(μ3-2,2-dimethylbutanedioato)-κ(4)O(1),O(1'):O(4):O(4');κ(5)O(1):O(1),O(4):O(4),O(4')-dizinc(II)] dihydrate], {[Zn2(C6H8O4)2(C10H8N2)(H2O)]·2H2O}n, has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction and elemental, IR and thermogravimetric analyses. In the structure, the 2,2-dimethylsuccinate ligands link linear tetranuclear Zn(II) subunits into one-dimensional chains along the c axis. 4,4'-Bipyridine acts as a tethering ligand expanding these one-dimensional chains into a two-dimensional layered structure. Hydrogen-bonding interactions between the water molecules (both coordinated and free) and carboxylate O atoms strengthen the packing of the layers. Furthermore, the luminescence properties of the complex were investigated. The compound exhibits a blue photoluminescence in the solid state at room temperature and may be a good candidate for potential hybrid inorganic-organic photoactive materials.

  14. Development and testing of a two-dimensional ultrasonic laboratory model system for seismic imaging of heterogeneous structures

    Science.gov (United States)

    Mo, Yike; Karaman, Hakki; Greenhalgh, Stewart

    2014-05-01

    To tackle the challenges and imaging problems of complex structures, we have recently assembled within the Wave Propagation Lab at ETH Zürich a simple 2D ultrasonic model facility in which the simulated geological structures are constructed from thin (2 mm thickness) metal and plastic sheets, cut and bonded together. The models were used, in full recognition of the similitude relations, to investigate reflections from beneath a low velocity distorting overburden. Besides uniform and irregular near surface layers, flat and dipping interfaces as well as rectangular high and low velocity block inserts were investigated. The experiments entailed the use of a piezoelectric source driven by a pulse amplifier at ultrasonic frequencies (20-300 kHz) to generate Lamb waves in the plate, which are detected by piezoelectric receivers and recorded digitally on a National Instruments recording system, under SignalExpress software control. In the lab system, a single cycle sinusoidal pulse with a negative onset (5 μs pulse width and 600 V pulse voltage) was selected as the optimized source pulse. Transducers can be placed along the thin edges of the plate in reflection mode (same edge) or transmission mode (opposite edges, or perpendicular edges). Alternatively they can be mounted on the flat planar surface of the plate to simulate a crosshole survey. Data were originally collected in all different recording geometries over a homogenous aluminium model for calibration purposes and to examine wave modes and propagation characteristics. The two dominant Lamb waves recorded are the fundamental symmetric mode (non-dispersive) and the fundamental antisymmetric (flexural) dispersive mode, which is normally absent when the source transducer is located on a model edge but dominant when it is on the flat planar surface of the plate. Only the symmetric Lamb mode can be used as a proxy for 2D propagation in an extended medium (the field situation). Experimental group and phase velocity

  15. Impulse transfer in a turbulent flow with two-dimensional structure of disturbances in a homogeneous shear region

    Energy Technology Data Exchange (ETDEWEB)

    Votsish, A.D.

    1977-07-01

    Results are given for experimental studies of the effect that a cross-sectional magnetic field has on longitudinal and cross-sectional velocity pulsations and the coefficient of their correlation in a homogeneous shear region of averaged flow velocity. An opposite sign change for turbulent friction was obtained as the magnetic field was increased. In this connection an identification was made of an impulse transfer from regions with lower speeds to regions with high speeds. 4 references, 1 figure.

  16. Structural, electronic, and magnetic properties of transition-metal atom adsorbed two-dimensional GaAs nanosheet

    Science.gov (United States)

    Luo, Jia; Xiang, Gang; Yu, Tian; Lan, Mu; Zhang, Xi

    2016-09-01

    By using first-principles calculations within the framework of density functional theory, the electronic and magnetic properties of 3d transitional metal (TM) atoms (from Sc to Zn) adsorbed monolayer GaAs nanosheets (GaAsNSs) are systematically investigated. Upon TM atom adsorption, GaAsNS, which is a nonmagnetic semiconductor, can be tuned into a magnetic semiconductor (Sc, V, and Fe adsorption), a half-metal (Mn adsorption), or a metal (Co and Cu adsorption). Our calculations show that the strong p-d hybridization between the 3d orbit of TM atoms and the 4p orbit of neighboring As atoms is responsible for the formation of chemical bonds and the origin of magnetism in the GaAsNSs with Sc, V, and Fe adsorption. However, the Mn 3d orbit with more unpaired electrons hybridizes not only with the As 4p orbit but also with the Ga 4p orbit, resulting in a stronger exchange interaction. Our results may be useful for electronic and magnetic applications of GaAsNS-based materials. Project supported by the National Natural Science Foundation of China (Grant No. 11174212).

  17. On the quasi-one dimensional structure of the cellular detonation in a two-dimensional duct

    Science.gov (United States)

    Uyeda, C. M.; Kurosaka, M.; Ferrante, A.

    2015-11-01

    We performed numerical simulations of cellular detonations in a 2D duct to establish the validity of the one-dimensional ZND model. The detonation was simulated by solving the Euler equations with a WENO-TCD numerical method using adaptive mesh refinement and a detailed chemical reaction mechanism. The results show that the properties of the ZND model of a 2H2-O2-7Ar reaction are very close to the results of the simulations initiated using three different methods for the area-averaged properties and the properties of particles tracked along their pathlines. Disagreements between the particle properties and the ZND model are greatest near the detonation front where the transverse wave and Mach stem introduce larger jumps in the flow properties than the ZND model predicts. The particle pathlines also exhibit a quasi one-dimensional motion downstream from the detonation front which is supported by the quick decay in the particles' velocity ratio of the vertical to horizontal velocity components, in the reference frame attached to the detonation front. These findings show the quasi one-dimensional nature of 2D detonations and the applicability of the ZND model.

  18. Existence of shocklets in a two-dimensional supersonic mixing layer and its influence on the flow structure

    Institute of Scientific and Technical Information of China (English)

    CAO; Wei

    2001-01-01

    gravitational lens sys-tem 2016 + 112, Astrophys. J. , 1985, 294: 66.[39]Aldcroft, T. L. , Bechtold, J. , Elvis, M. , MglI absorption in a sample of 56 steep-spectrum quasars, Astrophys. J. Sup-pl., 1994, 93: 1.[40]Verib-Getty, M. P., Veron, P., A catalogue of quasars and active nuclei, ESO Scientific Report, 1996, 17: 1.[41]Hewitt, A., Burbidge, G., A revised and updated catalog of quas-stellar objects, Astrophys, J. Suppl., 1993, 87: 451.[42]Rudy, R. J., Cohan, R. D., Ake, T. B., Ultraviolet and optical spectrophyotometry of the seyfert 1.8 galaxy Markarian 609, Astrophys. J., 1988, 332: 172.[43]Bregrmamn, T. S. , Pastoriza, M. G. , On the metal abundance of low-activity galactic nuclei, Astrophys. J. , 1989, 347:195.[44]Malkan, M. A., Oke, J. B., IUE observations of Markarian 3 and 6: reddening and nonstellar continuum, Astrophys. J. ,1983, 265: 92.[45]Oke, J. B., Goodrich, R. W., IUE and VISUAl spectrophotometry of Markarian 9, Markarian 10, and 3C 390.3, Astro-phys. J., 1981, 243: 445.[46]Crenshaw, D. M. , Peterson, B. M. , Korista, K. , Ultraviolet and optical spectra of high-ionization Seyfert galaxies with nar-row lines, AJ, 1991, 101: 1202.[47]Voit, G. M. , Shull, J. M. , Begelman, M. C. , Broad, variable absorption lines in the Seyfert Galaxy NGC 3516-probing the structure of the emission-line regions, Astrophys. J., 1987, 316: 573.[48]Reichert, G. A., Rodriguez-Pascual, P. M. , Alloin, D. et al., Steps toward determination of the size and structure of the broad-line region in active galactic, Astrophys. J., 1994, 425: 582.[49]Setti, G., Woltjer, L., Hubble Diagram for Quasars, Astrophys. J., 1973, 181: L61.[50]Baldwin, J. A. , Burke, W. L. , Gaskell, M. G. et al. , Relative quasar luminosities determined from emission line strengths, Nature, 1978, 273: 431.[51]Bressan, A., Chiosi, C., Fagotto, F., Spectrophotometric evolution of elliptical galaxies, Astrophys. J. Suppl., 1994, 94:63.[52]Scappa, R. , Urry, C. M

  19. Observation of the variations of the domain structure of a spontaneous electric field in a two-dimensional electron system under microwave irradiation

    Science.gov (United States)

    Dorozhkin, S. I.; Umansky, V.; von Klitzing, K.; Smet, J. H.

    2016-11-01

    It has been found on a sample of the GaAs/AlGaAs heterostructure with the two-dimensional electron system that different configurations of domains of a spontaneous electric field are possible within one microwave- induced state with the resistance tending to zero. Transitions between such configurations are observed at the variation of the radiation power and magnetic field. In the general case, the configuration of domains is more complicated than existing models. The fragment of the distribution of the electric field in the sample for one of the observed configurations is in agreement with the rhombic domain structure considered by I. G. Finkler and B. I. Halperin, Phys. Rev. B 79, 085315 (2009).

  20. Electronic band structure and Fermi surfaces of the quasi-two-dimensional monophosphate tungsten bronze, P4W12O44

    Science.gov (United States)

    Paul, S.; Ghosh, A.; Sato, T.; Sarma, D. D.; Takahashi, T.; Wang, E.; Greenblatt, M.; Raj, S.

    2014-02-01

    The electronic structure of quasi-two-dimensional monophosphate tungsten bronze, P4W12O44, has been investigated by high-resolution angle-resolved photoemission spectroscopy and density functional theoretical calculations. Experimental electron-like bands around \\Gamma point and Fermi surfaces have similar shapes as predicted by calculations. Fermi surface mapping at different temperatures shows a depletion of density of states at low temperature in certain flat portions of the Fermi surfaces. These flat portions of the Fermi surfaces satisfy the partial nesting condition with incommensurate nesting vectors q_1 and q_2 , which leads to the formation of charge density waves in this phosphate tungsten bronzes. The setting up of charge density wave in these bronzes can well explain the anomaly observed in its transport properties.

  1. Patterning the two dimensional electron gas at the LaAlO3/SrTiO3 interface by structured Al capping

    Science.gov (United States)

    Zhou, Y.; Wang, P.; Luan, Z. Z.; Shi, Y. J.; Jiang, S. W.; Ding, H. F.; Wu, D.

    2017-04-01

    We demonstrate an approach for patterning a quasi-two dimensional electron gas (q-2DEG) at the interface of LaAlO3 (LAO) and SrTiO3 (STO) utilizing a structured Al capping layer. The capping of Al enables the formation of q-2DEG at the interface of 1-3 unit cells (uc) of LAO on STO, which was originally insulating before capping. The properties of the q-2DEG induced by the Al capping layer are essentially the same as those of q-2DEG without Al. Therefore, we can pattern q-2DEG by simply patterning the Al film on LAO (2 or 3 uc)/STO using a one-step liftoff process. Our approach circumvents the difficulty of direct patterning of oxide materials and provides a simple and robust patterning method for future device applications based on complex oxide interfaces.

  2. Subband Structure of a Two-Dimensional Electron Gas Formed at the Polar Surface of the Strong Spin-Orbit Perovskite KTaO3

    Energy Technology Data Exchange (ETDEWEB)

    King, P.D.C.

    2012-03-01

    We demonstrate the formation of a two-dimensional electron gas (2DEG) at the (100) surface of the 5d transition-metal oxide KTaO{sub 3}. From angle-resolved photoemission, we find that quantum confinement lifts the orbital degeneracy of the bulk band structure and leads to a 2DEG composed of ladders of subband states of both light and heavy carriers. Despite the strong spin-orbit coupling, we find no experimental signatures of a Rashba spin splitting, which has important implications for the interpretation of transport measurements in both KTaO{sub 3}- and SrTiO{sub 3}-based 2DEGs. The polar nature of the KTaO{sub 3}(100) surface appears to help mediate formation of the 2DEG as compared to non-polar SrTiO{sub 3}(100).

  3. Formation of proto-cluster: a virialized structure from gravo-turbulent collapse II. A two-dimensional analytical model for rotating and accreting system

    CERN Document Server

    Lee, Yueh-Ning

    2016-01-01

    Most stars are born in the gaseous proto-cluster environment. The knowledge of this intermediate stage gives more accurate constraints on star formation characteristics. We demonstrate that a virialized globally supported structure, in which star formation happens, is formed out of a collapsing molecular cloud, and derive a mapping from the parent cloud parameters to the proto-cluster to predict its properties, with a view to confront analytical calculations with observations and simulations. The virial theorem is decomposed into two dimensions to account for the rotation and the flattened geometry. Equilibrium is found by balancing rotation, turbulence and self-gravity, while turbulence is maintained by accretion driving and dissipates in one crossing time. The angular momentum and the accretion rate of the proto-cluster are estimated from the parent cloud properties. The two-dimensional virial model predicts the size and velocity dispersion given the mass of the proto-cluster and that of the parent cloud. T...

  4. Analysis of the horizontal two-dimensional near-surface structure of a winter tornadic vortex using high-resolution in situ wind and pressure measurements

    Science.gov (United States)

    Kato, Ryohei; Kusunoki, Kenichi; Sato, Eiichi; Mashiko, Wataru; Inoue, Hanako Y.; Fujiwara, Chusei; Arai, Ken-ichiro; Nishihashi, Masahide; Saito, Sadao; Hayashi, Syugo; Suzuki, Hiroto

    2015-06-01

    The horizontal two-dimensional near-surface structure of a tornadic vortex within a winter storm was analyzed. The tornadic vortex was observed on 10 December 2012 by the high-resolution in situ observational linear array of wind and pressure sensors (LAWPS) system in conjunction with a high-resolution Doppler radar. The 0.1 s maximum wind speed and pressure deficit near the ground were recorded as 35.3 m s-1 and -3.8 hPa, respectively. The horizontal two-dimensional distributions of the tornadic vortex wind and pressure were retrieved by the LAWPS data, which provided unprecedented observational detail on the following important features of the near-surface structure of the tornadic vortex. Asymmetric convergent inflow toward the vortex center existed. Total wind speed was strong to the right and rear side of the translational direction of the vortex and weak in the forward part of the vortex possibly because of the strong convergent inflow in that region. The tangential wind speed profile of the vortex was better approximated using a modified Rankine vortex rather than the Rankine vortex both at 5 m above ground level (agl) and 100 m agl, and other vortex models (Burgers-Rott vortex and Wood-White vortex) were also compared. The cyclostrophic wind balance was violated in the core radius R0 and outside the core radius in the forward sector; however, it was held with a relatively high accuracy of approximately 14% outside the core of the vortex in the rearward sector (from 2 R0 to 5 R0) near the ground.

  5. Application of a quantitative structure retention relationship approach for the prediction of the two-dimensional gas chromatography retention times of polycyclic aromatic sulfur heterocycle compounds.

    Science.gov (United States)

    Gieleciak, Rafal; Hager, Darcy; Heshka, Nicole E

    2016-03-11

    Information on the sulfur classes present in petroleum is a key factor in determining the value of refined products and processing behavior in the refinery. A large part of the sulfur present is included in polycyclic aromatic sulfur heterocycles (PASHs), which in turn are difficult to desulfurize. Furthermore, some PASHs are potentially more mutagenic and carcinogenic than polycyclic aromatic hydrocarbons, PAHs. All of this calls for improved methods for the identification and quantification of individual sulfur species. Recent advances in analytical techniques such as comprehensive two-dimensional gas chromatography (GC×GC) have enabled the identification of many individual sulfur species. However, full identification of individual components, particularly in virgin oil fractions, is still out of reach as standards for numerous compounds are unavailable. In this work, a method for accurately predicting retention times in GC×GC using a QSRR (quantitative structure retention relationship) method was very helpful for the identification of individual sulfur compounds. Retention times for 89 saturated, aromatic, and polyaromatic sulfur-containing heterocyclic compounds were determined using two-dimensional gas chromatography. These retention data were correlated with molecular descriptors generated with CODESSA software. Two independent QSRR relationships were derived for the primary as well as the secondary retention characteristics. The predictive ability of the relationships was tested by using both independent sets of compounds and a cross-validation technique. When the corresponding chemical standards are unavailable, the equations developed for predicting retention times can be used to identify unknown chromatographic peaks by matching their retention times with those of sulfur compounds of known molecular structure.

  6. A Method to Formulate the Unit Cell for Density Functional Theory (DFT) Calculations of the Electronic Band Structure of Heterostructures of Two-dimensional Nanosheets

    Science.gov (United States)

    2015-04-01

    distribution is unlimited. i CONTENTS Page Introduction 1 Two-dimensional Material Geometry and Analogs with Close-packed Systems 1 Matching...distribution is unlimited. 1 INTRODUCTION Two-dimensional (2D) material heterostructures offer novel and compelling electronic and optical...methods have undoubtedly been created for matching lattice constants of dissimilar nanomaterials , very few are actually covered explicitly in literature

  7. Design of an LED chip structure with an integrated two-dimensional photonic crystal to enhance the light-extraction efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Won-Sik; Park, Si-Hyun [Yeungnam University, Gyeongsan (Korea, Republic of)

    2014-05-15

    We numerically simulated the light-extraction efficiency of light-emitting diodes (LEDs) with an integrated two-dimensional photonic crystal (PC) structure on the top surface in order to enhance light extraction. We considered InGaN-based LED chips with a typical emission wavelength of λ{sub o} = 460 nm and an emission wavelength inside the LED chip of λ = λ{sub 0}/n{sub GaN} , where n{sub GaN} is the refractive index of GaN. We used positive (relief) and negative (intaglio) patterns for the PC structures with square arrangements. The pattern period (Λ), width (d), and height (h) of the PC structure were varied systematically in the PC-LEDs; then the light-extraction efficiency of each PC-LED was simulated numerically using a three-dimensional finite-difference time-domain method to optimize the PC structure in terms of light extraction. The PC LED with a square pillar pattern with Λ ∼ 1.4λ, d ∼ 0.75Λ, and h ∼ 0.75Λ had the maximum light-extraction efficiency for positive patterns while the cylindrical hole pattern with Λ ∼ 1.2λ, d ∼ 0.5Λ, and h ∼ 0.5Λ had the maximum light-extraction efficiency for negative patterns.

  8. Synthesis and Structure of A Novel Quasi-Two Dimensional Organic-inorganic Hybrid Coordination Polymer:{[Cu(en)2][Ag2I4]}n

    Institute of Scientific and Technical Information of China (English)

    SUN Ling-Guo; LI Hao-Hong; CHEN Zhi-Rong; HUANG Chang-Cang; ZHAO Bin; LI Jun-Qian

    2006-01-01

    A novel coordination polymer {[Cu(en)2][Ag2I4]}n (en = ethylenediamine) was synthesized by the reaction of NaAgI2 and Cu(en)2(NO3)2·2H2O at room temperature with pH = 6.0, and the structure was characterized by X-ray single-crystal diffraction. It crystallizes in monoclinic, space group C2/m, with a=10.646(2), b = 13.304(3), c = 6.8445(14)(A), β = 118.95(3)°, C4H16N4CuAg2I4, Mr = 907.10, V = 848.3(4)(A)3, Z = 2, Dc = 3.551 g/cm3, F(000) = 806, μ(MoKα) = 10.787 mm(1, the final R1 = 0.0256 and wR2 = 0.0654 for 900 observed reflections with I > 2σ(I). According to structural analysis, the title compound consists of template cation [Cu(en)2]2+ and inorganic chain [Ag2I4]n2-. The polymeric negative chain [Ag2I4]n2- is built up from pairs of AgI4 tetrahedron by sharing one edge. Through N-H…I hydrogen-bonding interactions, the whole structure represents a quasi-two dimensional arrangement. Electrostatic attraction exists between organic cations and inorganic chains, leading to a so-called organic-inorganic hybrid structure.

  9. Crystal structure and photoluminescence of a new two-dimensional Cd(II) coordination polymer based on 3-(carboxymethoxy)-2-naphthoic acid

    Energy Technology Data Exchange (ETDEWEB)

    Kong, Zhi-Guo; Guo, Sheng-Nan; Miao, Jia-Qi; An, Miao [Jilin Normal Univ., College of Chemistry, Siping (China); Ministry of Education, Siping (China). Key Lab. of Preparation and Applications of Enviromental Friendly Materials

    2015-11-01

    A new Cd(II) coordination polymer, [Cd(CNA)]{sub n} (1) (H{sub 2}CNA = 3-(carboxymethoxy)-2-naphthoic acid), was hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. The crystals are monoclinic, space group P{sub 2}1/c with a = 16.9698(18), b = 7.8314(8), c = 8.9553(10) Aa, β = 100.657(2) {sup circle}, V = 1169.6(2) Aa{sup 3}, Z = 4, D{sub calcd.} = 2.03 g cm{sup -3}, μ(MoK{sub α}) = 1.9 mm{sup -1}, F(000) = 696 e, R = 0.0305, wR = 0.0784 for 172 refined parameters and 2285 data. Each CNA anion bridges three Cd(II) cations to give rise to a two-dimensional network structure. Topologically, if each CNA anion is regarded as a linker, and each Cd(II) atom considered as a 4-connected node, the structure is simplified as a 4-connected (4,4) network. The solid state photoluminescent properties of the compound were also studied at room temperature.

  10. On-Surface Synthesis of Two-Dimensional Covalent Organic Structures versus Halogen-Bonded Self-Assembly: Competing Formation of Organic Nanoarchitectures.

    Science.gov (United States)

    Peyrot, David; Silly, Fabien

    2016-05-24

    The competition between the on-surface synthesis of covalent nanoarchitectures and the self-assembly of star-shaped 1,3,5-Tris(4-iodophenyl)benzene molecules on Au(111) in vacuum is investigated using scanning tunneling microscopy above room temperature. The molecules form covalent polygonal nanoachitectures at the gold surface step edges and at the elbows of the gold reconstruction at low coverage. With coverage increasing two-dimensional halogen-bonded structures appear and grow on the surface terraces. Two different halogen-bonded nanoarchitectures are coexisting on the surface and hybrid covalent-halogen bonded structures are locally observed. At high coverage covalent nanoarchitectures are squeezed at the domain boundary of the halogen-bonded structures. The competitive growth between the covalent and halogen-bonded nanoarchitectures leads to formation of a two-layer film above one monolayer deposition. For this coverage, the covalent nanoarchitectures are propelled on top of the halogen-bonded first layer. These observations open up new opportunities for decoupling covalent nanoarchitectures from catalytically active and metal surfaces in vacuum.

  11. Equivalency of two-dimensional algebras

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Gildemar Carneiro dos; Pomponet Filho, Balbino Jose S. [Universidade Federal da Bahia (UFBA), BA (Brazil). Inst. de Fisica

    2011-07-01

    Full text: Let us consider a vector z = xi + yj over the field of real numbers, whose basis (i,j) satisfy a given algebra. Any property of this algebra will be reflected in any function of z, so we can state that the knowledge of the properties of an algebra leads to more general conclusions than the knowledge of the properties of a function. However structural properties of an algebra do not change when this algebra suffers a linear transformation, though the structural constants defining this algebra do change. We say that two algebras are equivalent to each other whenever they are related by a linear transformation. In this case, we have found that some relations between the structural constants are sufficient to recognize whether or not an algebra is equivalent to another. In spite that the basis transform linearly, the structural constants change like a third order tensor, but some combinations of these tensors result in a linear transformation, allowing to write the entries of the transformation matrix as function of the structural constants. Eventually, a systematic way to find the transformation matrix between these equivalent algebras is obtained. In this sense, we have performed the thorough classification of associative commutative two-dimensional algebras, and find that even non-division algebra may be helpful in solving non-linear dynamic systems. The Mandelbrot set was used to have a pictorial view of each algebra, since equivalent algebras result in the same pattern. Presently we have succeeded in classifying some non-associative two-dimensional algebras, a task more difficult than for associative one. (author)

  12. A matrix-exponential decomposition based time-domain method for calculating the defect states of scalar waves in two-dimensional periodic structures

    Science.gov (United States)

    Su, Xiao-Xing; Wang, Yue-Sheng; Zhang, Chuanzeng

    2017-05-01

    A time-domain method for calculating the defect states of scalar waves in two-dimensional (2D) periodic structures is proposed. In the time-stepping process of the proposed method, the column vector containing the spatially sampled field values is updated by multiplying it with an iteration matrix, which is written in a matrix-exponential form. The matrix-exponential is first computed by using the Suzuki's decomposition based technique of the fourth order, in which the Floquet-Bloch boundary conditions are incorporated. The obtained iteration matrix is then squared to enlarge the time-step that can be used in the time-stepping process (namely, the squaring technique), and the small nonzero elements in the iteration matrix is finally pruned to improve the sparse structure of the matrix (namely, the pruning technique). The numerical examples of the super-cell calculations for 2D defect-containing phononic crystal structures show that, the fourth order decomposition based technique for the matrix-exponential computation is much more efficient than the frequently used precise integration technique (PIT) if the PIT is of an order greater than 2. Although it is not unconditionally stable, the proposed time-domain method is particularly efficient for the super-cell calculations of the defect states in a 2D periodic structure containing a defect with a wave speed much higher than those of the background materials. For this kind of defect-containing structures, the time-stepping process can run stably for a sufficiently large number of the time-steps with a time-step much larger than the Courant-Friedrichs-Lewy (CFL) upper limit, and consequently the overall efficiency of the proposed time-domain method can be significantly higher than that of the conventional finite-difference time-domain (FDTD) method. Some physical interpretations on the properties of the band structures and the defect states of the calculated periodic structures are also presented.

  13. Two-dimensional incommensurately modulated structure of (Sr0.13Ca0. 87)2CoSi2O7 crystals.

    Science.gov (United States)

    Bagautdinov, B; Hagiya, K; Kusaka, K; Ohmasa, M; Iishi, K

    2000-10-01

    The incommensurate structure of (Sr(0.13)Ca(0.87))(2)CoSi(2)O(7) at room temperature has been determined from single-crystal X-ray diffraction data. The compound has a non-centrosymmetric tetragonal basic cell of a = 7.8743 (4) and c = 5.0417 (2) A with the space group P4;2(1)m. The refinements of the basic structure converged to R = 0.038 for 757 main reflections. The two-dimensional incommensurate structure is characterized by the wavevectors q(1) = 0.286 (3)(a* + b*) and q(2) = 0.286 (3)(-a* + b*), where a*, b* are the reciprocal lattice vectors of the basic structure. With the (3 + 2)-dimensional superspace group P(p4mg)(P4;2(1)(m)), the refinements converged to R = 0.071 for 1697 observed reflections (757 main and 940 satellite reflections). The structure is described in terms of displacement of the atoms, rotation, distortion of CoO(4) and SiO(4) tetrahedra, and the partial ordering of the Sr and Ca atoms accompanied with the modulation. Correlated evolution of these features throughout the crystal gives rise to various oxygen coordination around Ca/Sr. Comparison of the derived modulated structure to that of Ca(2)CoSi(2)O(7) clarified that the partial substitution of Ca by large alkaline-earth atoms such as Sr should decrease the distortion of the polyhedra around the cations.

  14. Generation of eye field/optic vesicle-like structures from human embryonic stem cells under two-dimensional and chemically defined conditions.

    Science.gov (United States)

    Parvini, Maryam; Parivar, Kazem; Safari, Fatemeh; Tondar, Mahdi

    2015-03-01

    Despite the enormous progress in studying retinal cell differentiation from human embryonic stem cells (hESCs), none of the reported protocols have produced a cost-effective eye field cells with the capability to further differentiate into retinal derivatives. In this study, by drawing chemicals on our four-step differentiation strategy, we demonstrated the ability of hESCs in assembling such qualifications to follow human retinogenesis in a serum- and feeder-free adherent condition. Two-dimensional (2D) populations of eye field cells arose within early forebrain progeny upon hESCs differentiation. Gene expression analysis showed that the treatment of hESCs with a combination of selected small molecules (SMs) gave rise to the higher expressions of eye field-specific genes, PAX6, RX, and SIX3. Thereafter, a subset of cells gained the transient features of advancing retinal differentiation, including optic vesicle (OV)-like structures, which expressed MITF and CHX10 in a manner imitated in vivo human retinal development. The competency of derived cells in differentiation to retinal derivatives was further investigated. The gene analysis of the cells showed more propensity for generating retinal pigment epithelial (RPE) than neural retina (NR). The generation of OV-like structures in 2D cultures can shed light on molecular events governing retinal specification. It can also facilitate the study of human retinal development.

  15. Synthesis, crystal structure, vibrational spectra, optical properties and theoretical investigation of a two-dimensional self-assembled organic-inorganic hybrid material

    Science.gov (United States)

    Dammak, Hajer; Elleuch, Slim; Feki, Habib; Abid, Younes

    2016-11-01

    Organic-inorganic hybrid material of formula (C4H3SC2H4NH3)2[PbI4] was synthesized and studied by X-ray diffraction, Infrared absorption, Raman scattering, UV-Visible absorption and photoluminescence measurements. The molecule crystallizes as an organic-inorganic two-dimensional (2D) structure built up from infinite PbI6 octahedra surrounded by organic cations. Such a structure may be regarded as quantum wells system in which the inorganic layers act as semiconductor wells and the organic cations act as insulator barriers. Room temperature IR and Raman spectra were recorded in the 520-3500 and 10-3500 cm-1 frequency range, respectively. Optical absorption measurements performed on thin films of (C4H3SC2H4NH3)2[PbI4] revealed three distinct bands at 2.4, 2.66 and 3.25 eV. We also report DFT calculations of the electric dipole moments (μ), polarizability (α), the static first hyperpolarizability (β) and HOMO-LUMO analysis of the title compound investigated by GAUSSIAN 09 package. The calculated static first Hyperpolarizability is equal to 11.46 × 10-31 esu.

  16. Crystal Structure and Magnetic Property of a Two-dimensional Manganese Compound [Mn(PhCOO)2(4,4'-bipyridine)]n

    Institute of Scientific and Technical Information of China (English)

    CHEN Hui; WANG Wen-Guo; MA Cheng-Bing; CHEN Chang-Neng; LIU Qiu-Tian; LIAO Dai-Zheng; LI Li-Cun

    2007-01-01

    A new two-dimensional polymeric manganese compound [Mn(PhCOO)2(4,4'-bipyridine)]n 1 has been prepared and structurally characterized by X-ray diffraction. The complex crystallizes in space group Pbcn with a = 18.7158(2), b = 11.6919(3), c = 9.4799(2)(A), V = 2074.42(7)(A)3, Z = 4, Mr = 453.34, Dc = 1.452 g/cm3, μ = 0.670 mm-1 and F(000) = 932. The final refinement gave R = 0.0458 and wR = 0.1439 for 1358 observed reflections with Ⅰ> 2σ(Ⅰ). The complex consists of repeating units of Mn(PhCOO)2(4,4'-bipyridine). Each Mn center is sixcoordinated by four carboxylate O atoms of four benzoate anions and two pyridyl N atoms from bipy ligands to furnish a slightly distorted octahedral geometry. The two adjacent Mn atoms are connected by a pair of μ1,3-carboxylate groups to form infinite chains, which are further interlinked by bipy to complete a 2D grid network. The magnetic property of the polymeric complex has also been investigated.

  17. High-pressure crystal structure of the non-linear optical compound BiB(3)O(6) from two-dimensional powder diffraction data.

    Science.gov (United States)

    Dinnebier, R E; Hinrichsen, B; Lennie, A; Jansen, M

    2009-02-01

    Our recently proposed method for automatic detection, calibration and evaluation of Debye-Scherrer ellipses using pattern-recognition techniques and advanced signal filtering was applied to the two-dimensional powder diffraction data of the non-ferroelectric, non-centrosymmetric non-linear optical (NLO) compound alpha-BiB(3)O(6) as a function of pressure. At ambient conditions, alpha-BiB(3)O(6) crystallizes in the space group C2 (phase I). In the pressure range between P = 6.09 and 6.86 GPa, it exhibits a first-order phase transition into a structure with the space group C1 (P1) [phase II at P = 8.34 GPa: a = 7.4781 (6), b = 3.9340 (4), c = 6.2321 (6) A, alpha = 93.73 (1), beta = 102.93 (1), gamma = 90.76 (1) degrees , and V = 178.24 (3) A(3)]. Non-linear compression behaviour over the entire pressure range is observed, which can be described by two Vinet relations in the ranges from P = 0.0 to 6.09 GPa, and from P = 6.86 to 11.6 GPa. The extrapolated bulk moduli of the high-pressure phases were determined to be K(0) = 38 (1) GPa for phase I, and K(0) = 114 (10) GPa for phase II. The crystal structures of both phases were refined against X-ray powder diffraction data measured at several pressures between 0.0 and 11.6 GPa. The structural phase transition of alpha-BiB(3)O(6) is mainly characterized by a reorientation of the [BO(3)](3-) triangles, the [BO(4)](5-) tetrahedra and the lone electron pair which is localized at Bi(3+), in order to optimize crystal packing.

  18. Interpolation by two-dimensional cubic convolution

    Science.gov (United States)

    Shi, Jiazheng; Reichenbach, Stephen E.

    2003-08-01

    This paper presents results of image interpolation with an improved method for two-dimensional cubic convolution. Convolution with a piecewise cubic is one of the most popular methods for image reconstruction, but the traditional approach uses a separable two-dimensional convolution kernel that is based on a one-dimensional derivation. The traditional, separable method is sub-optimal for the usual case of non-separable images. The improved method in this paper implements the most general non-separable, two-dimensional, piecewise-cubic interpolator with constraints for symmetry, continuity, and smoothness. The improved method of two-dimensional cubic convolution has three parameters that can be tuned to yield maximal fidelity for specific scene ensembles characterized by autocorrelation or power-spectrum. This paper illustrates examples for several scene models (a circular disk of parametric size, a square pulse with parametric rotation, and a Markov random field with parametric spatial detail) and actual images -- presenting the optimal parameters and the resulting fidelity for each model. In these examples, improved two-dimensional cubic convolution is superior to several other popular small-kernel interpolation methods.

  19. Two-Dimensional Hydrodynamic Modeling and Analysis of the Proposed Channel Modifications and Grade Control Structure on the Blue River near Byram's Ford Industrial Park, Kansas City, Missouri

    Science.gov (United States)

    Huizinga, Richard J.

    2007-01-01

    The Blue River Channel Modification project being implemented by the U.S. Army Corps of Engineers (USACE) is intended to provide flood protection within the Blue River valley in the Kansas City, Mo., metropolitan area. In the latest phase of the project, concerns have arisen about preserving the Civil War historic area of Byram's Ford and the associated Big Blue Battlefield while providing flood protection for the Byram's Ford Industrial Park. In 1996, the USACE used a physical model built at the Waterways Experiment Station (WES) in Vicksburg, Miss., to examine the feasibility of a proposed grade control structure (GCS) that would be placed downstream from the historic river crossing of Byram's Ford to provide a subtle transition of flow from the natural channel to the modified channel. The U.S. Geological Survey (USGS), in cooperation with the USACE, modified an existing two-dimensional finite element surface-water model of the river between 63d Street and Blue Parkway (the 'original model'), used the modified model to simulate the existing (as of 2006) unimproved channel and the proposed channel modifications and GCS, and analyzed the results from the simulations and those from the WES physical model. Modifications were made to the original model to create a model that represents existing (2006) conditions between the north end of Swope Park immediately upstream from 63d Street and the upstream limit of channel improvement on the Blue River (the 'model of existing conditions'). The model of existing conditions was calibrated to two measured floods. The model of existing conditions also was modified to create a model that represents conditions along the same reach of the Blue River with proposed channel modifications and the proposed GCS (the 'model of proposed conditions'). The models of existing conditions and proposed conditions were used to simulate the 30-, 50-, and 100-year recurrence floods. The discharge from the calibration flood of May 15, 1990, also

  20. High-resolution structural studies of ultra-thin magnetic, transition metal overlayers and two-dimensional transition metal oxides using synchrotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Kellar, S.A. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley National Lab., CA (United States). Advanced Light Source Div.

    1997-05-01

    This thesis report the surface-structure determination of three, ultra-thin magnetic transition-metal films, Fe/Au(100), Mn/Ni(100), and Mn/Cu(100) using Angle-Resolved Photoemission Extended Fine Structure (ARPEFS) and photoelectron holography. These structural studies are the first to use non-s initial states in the ARPEFS procedure. This thesis also reports an ARPEFS surface-structure determination of a two-dimensional transition-metal oxide, [(1 x 1)O/W(110)] x 12. The authors have analyzed the ARPFES signal from the Au 4f{sub 7/5} core level of the Au(1 ML)/Fe(15 ML)/Au(100) system. The analysis shows that the Fe grows layer by layer with one monolayer of gold, acting as a surfactant, remaining on top of the growing Fe layers. These surface gold atoms sit in the four-fold hollow site, 1.67 {+-} 0.02 A above the iron surface. The grown Fe layer is very much like the bulk, bcc iron, with an interlayer spacing of 1.43 {+-} 0.03 A. Analysis of the Mn 3p ARPEFS signals from c(2 x 2)Mn/Ni(100) and c(2 x 2)Mn/Cu(100) shows that the Mn forms highly corrugated surface alloys. The corrugation of the Mn/Ni(100) and Mn/Cu(100) systems are 0.24 {+-} 0.02 A and 0.30 {+-} 0.04 A respectively. In both cases the Mn is sticking above the plane of the surface substrate atoms. For the Mn/Ni(100) system the first layer Ni is contracted 4% from the bulk value. The Mn/Cu(100) system shows bulk spacing for the substrate Cu. Photoelectron holography shows that the Mn/Ni interface is very abrupt with very little Mn leaking into the second layer, while the Mn/Cu(100) case has a significant amount of Mn leaking into the second layer. A new, five-element electrostatic electron lens was developed for hemispherical electron-energy analyzers. This lens system can be operated at constant transverse or constants angular magnification, and has been optimized for use with the very small photon-spot sizes. Improvements to the hemispherical electron-energy analyzer are also discussed.

  1. Two-dimensional liquid chromatography

    DEFF Research Database (Denmark)

    Græsbøll, Rune

    of this thesis is on online comprehensive two-dimensional liquid chromatography (online LC×LC) with reverse phase in both dimensions (online RP×RP). Since online RP×RP has not been attempted before within this research group, a significant part of this thesis consists of knowledge and experience gained...

  2. Piezoelectricity in Two-Dimensional Materials

    KAUST Repository

    Wu, Tao

    2015-02-25

    Powering up 2D materials: Recent experimental studies confirmed the existence of piezoelectricity - the conversion of mechanical stress into electricity - in two-dimensional single-layer MoS2 nanosheets. The results represent a milestone towards embedding low-dimensional materials into future disruptive technologies. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA.

  3. Kronecker Product of Two-dimensional Arrays

    Institute of Scientific and Technical Information of China (English)

    Lei Hu

    2006-01-01

    Kronecker sequences constructed from short sequences are good sequences for spread spectrum communication systems. In this paper we study a similar problem for two-dimensional arrays, and we determine the linear complexity of the Kronecker product of two arrays. Our result shows that similar good property on linear complexity holds for Kronecker product of arrays.

  4. Two-Dimensional Simulation of Flow and Evaluation of Bridge Scour at Structure A-1700 on Interstate 155 over the Mississippi River near Caruthersville, Missouri

    Science.gov (United States)

    Huizinga, Richard J.

    2007-01-01

    The evaluation of scour at bridges throughout the State of Missouri has been ongoing since 1991, and most of these evaluations have used one-dimensional hydraulic analysis and application of conventional scour depth prediction equations. Occasionally, the complex conditions of a site dictate a more thorough assessment of the stream hydraulics beyond a one-dimensional model. This was the case for structure A-1700, the Interstate 155 bridge crossing the Mississippi River near Caruthersville, Missouri. To assess the complex hydraulics at this site, a two-dimensional hydrodynamic flow model was used to simulate flow conditions on the Mississippi River in the vicinity of the Interstate 155 structure A-1700. The model was used to simulate flow conditions for three discharges: a flood that occurred on April 4, 1975 (the calibration flood), which had a discharge of 1,658,000 cubic feet per second; the 100-year flood, which has a discharge of 1,960,000 cubic feet per second; and the project design flood, which has a discharge of 1,974,000 cubic feet per second. The project design flood was essentially equivalent to the flood that would cause impending overtopping of the mainline levees along the Mississippi River in the vicinity of structure A-1700. Discharge and river-stage readings from the flood of April 4, 1975, were used to calibrate the flow model. The model was then used to simulate the 100-year and project design floods. Hydraulic flow parameters obtained from the three flow simulations were applied to scour depth prediction equations to determine contraction, local pier, and abutment scour depths at structure A-1700. Contraction scour and local pier scour depths computed for the project design discharge generally were the greatest, whereas the depths computed for the calibration flood were the least. The maximum predicted total scour depth (contraction and local pier scour) for the calibration flood was 66.1 feet; for the 100-year flood, the maximum predicted total

  5. Two dimensional unstable scar statistics.

    Energy Technology Data Exchange (ETDEWEB)

    Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Kotulski, Joseph Daniel; Lee, Kelvin S. H. (ITT Industries/AES Los Angeles, CA)

    2006-12-01

    This report examines the localization of time harmonic high frequency modal fields in two dimensional cavities along periodic paths between opposing sides of the cavity. The cases where these orbits lead to unstable localized modes are known as scars. This paper examines the enhancements for these unstable orbits when the opposing mirrors are both convex and concave. In the latter case the construction includes the treatment of interior foci.

  6. Two-Dimensional Vernier Scale

    Science.gov (United States)

    Juday, Richard D.

    1992-01-01

    Modified vernier scale gives accurate two-dimensional coordinates from maps, drawings, or cathode-ray-tube displays. Movable circular overlay rests on fixed rectangular-grid overlay. Pitch of circles nine-tenths that of grid and, for greatest accuracy, radii of circles large compared with pitch of grid. Scale enables user to interpolate between finest divisions of regularly spaced rule simply by observing which mark on auxiliary vernier rule aligns with mark on primary rule.

  7. Synthesis, Structure and Characterization of Two-dimensional Network Copper Complex [ Cu3 (nta) 2(azpy) 2(H2O)2]· 6H2O

    Institute of Scientific and Technical Information of China (English)

    LI,Bao-Long(李宝龙); XU,Yan(徐艳); LIU,Qi(刘琦); WANG,Hua-Qin(王化勤); XU,Zheng(徐正)

    2002-01-01

    The copper(Ⅱ) complex [Cu3(nta)2(azpy)2(H2O)2] @6H2O(nta= nitrilotriacetate, azpy= 4,4'-azobispyridine) has been synthesized and characterized. The X-ray analysis reveals that there are two kinds of copper(Ⅱ) coordination environments.Cu(1) has a distorted square plane symmetry and Cu(2) has a distorted octahedral symmetry. Cu(1)is linked to Cu(2)through nta and bound to Cu(1C) by azpy, and Cu(2) islinked to Cu(2A) through azpy, which extends to two-dimensional network with large rhombus 1.2 nm× 1.7 nm.

  8. Two-Dimensional NMR Lineshape Analysis

    Science.gov (United States)

    Waudby, Christopher A.; Ramos, Andres; Cabrita, Lisa D.; Christodoulou, John

    2016-04-01

    NMR titration experiments are a rich source of structural, mechanistic, thermodynamic and kinetic information on biomolecular interactions, which can be extracted through the quantitative analysis of resonance lineshapes. However, applications of such analyses are frequently limited by peak overlap inherent to complex biomolecular systems. Moreover, systematic errors may arise due to the analysis of two-dimensional data using theoretical frameworks developed for one-dimensional experiments. Here we introduce a more accurate and convenient method for the analysis of such data, based on the direct quantum mechanical simulation and fitting of entire two-dimensional experiments, which we implement in a new software tool, TITAN (TITration ANalysis). We expect the approach, which we demonstrate for a variety of protein-protein and protein-ligand interactions, to be particularly useful in providing information on multi-step or multi-component interactions.

  9. A two-dimensional Dirac fermion microscope

    Science.gov (United States)

    Bøggild, Peter; Caridad, José M.; Stampfer, Christoph; Calogero, Gaetano; Papior, Nick Rübner; Brandbyge, Mads

    2017-06-01

    The electron microscope has been a powerful, highly versatile workhorse in the fields of material and surface science, micro and nanotechnology, biology and geology, for nearly 80 years. The advent of two-dimensional materials opens new possibilities for realizing an analogy to electron microscopy in the solid state. Here we provide a perspective view on how a two-dimensional (2D) Dirac fermion-based microscope can be realistically implemented and operated, using graphene as a vacuum chamber for ballistic electrons. We use semiclassical simulations to propose concrete architectures and design rules of 2D electron guns, deflectors, tunable lenses and various detectors. The simulations show how simple objects can be imaged with well-controlled and collimated in-plane beams consisting of relativistic charge carriers. Finally, we discuss the potential of such microscopes for investigating edges, terminations and defects, as well as interfaces, including external nanoscale structures such as adsorbed molecules, nanoparticles or quantum dots.

  10. A two-dimensional Dirac fermion microscope.

    Science.gov (United States)

    Bøggild, Peter; Caridad, José M; Stampfer, Christoph; Calogero, Gaetano; Papior, Nick Rübner; Brandbyge, Mads

    2017-06-09

    The electron microscope has been a powerful, highly versatile workhorse in the fields of material and surface science, micro and nanotechnology, biology and geology, for nearly 80 years. The advent of two-dimensional materials opens new possibilities for realizing an analogy to electron microscopy in the solid state. Here we provide a perspective view on how a two-dimensional (2D) Dirac fermion-based microscope can be realistically implemented and operated, using graphene as a vacuum chamber for ballistic electrons. We use semiclassical simulations to propose concrete architectures and design rules of 2D electron guns, deflectors, tunable lenses and various detectors. The simulations show how simple objects can be imaged with well-controlled and collimated in-plane beams consisting of relativistic charge carriers. Finally, we discuss the potential of such microscopes for investigating edges, terminations and defects, as well as interfaces, including external nanoscale structures such as adsorbed molecules, nanoparticles or quantum dots.

  11. The Chandrasekhar's Equation for Two-Dimensional Hypothetical White Dwarfs

    CERN Document Server

    De, Sanchari

    2014-01-01

    In this article we have extended the original work of Chandrasekhar on the structure of white dwarfs to the two-dimensional case. Although such two-dimensional stellar objects are hypothetical in nature, we strongly believe that the work presented in this article may be prescribed as Master of Science level class problem for the students in physics.

  12. Topological aspect of disclinations in two-dimensional crystals

    Institute of Scientific and Technical Information of China (English)

    Qi Wei-Kai; Zhu Tao; Chen Yong; Ren Ji-Rong

    2009-01-01

    By using topological current theory, this paper studies the inner topological structure of disclinations during the melting of two-dimensional systems. From two-dimensional elasticity theory, it finds that there are topological currents for topological defects in homogeneous equation. The evolution of disclinations is studied, and the branch conditions for generating, annihilating, crossing, splitting and merging of disclinations are given.

  13. Two-dimensional liquid chromatography

    DEFF Research Database (Denmark)

    Græsbøll, Rune

    Two-dimensional liquid chromatography has received increasing interest due to the rise in demand for analysis of complex chemical mixtures. Separation of complex mixtures is hard to achieve as a simple consequence of the sheer number of analytes, as these samples might contain hundreds or even...... dimensions. As a consequence of the conclusions made within this thesis, the research group has, for the time being, decided against further development of online LC×LC systems, since it was not deemed ideal for the intended application, the analysis of the polar fraction of oil. Trap-and...

  14. The separation of whale myoglobins with two-dimensional electrophoresis.

    Science.gov (United States)

    Spicer, G S

    1988-10-01

    Five myoglobins (sperm whale, Sei whale, Hubbs' beaked whale, pilot whale, and Amazon River dolphin) were examined using two-dimensional electrophoresis. Previous reports indicated that none of these proteins could be separated by using denaturing (in the presence of 8-9 M urea) isoelectric focusing. This result is confirmed in the present study. However, all the proteins could be separated by using denaturing nonequilibrium pH-gradient electrophoresis in the first dimension. Additionally, all the myoglobins have characteristic mobilities in the second dimension (sodium dodecyl sulfate), but these mobilities do not correspond to the molecular weights of the proteins. We conclude that two-dimensional electrophoresis can be more sensitive to differences in primary protein structure than previous studies indicate and that the assessment seems to be incorrect that this technique can separate only proteins that have a unit charge difference.

  15. Transport behavior of water molecules through two-dimensional nanopores

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Chongqin; Li, Hui; Meng, Sheng, E-mail: smeng@iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2014-11-14

    Water transport through a two-dimensional nanoporous membrane has attracted increasing attention in recent years thanks to great demands in water purification and desalination applications. However, few studies have been reported on the microscopic mechanisms of water transport through structured nanopores, especially at the atomistic scale. Here we investigate the microstructure of water flow through two-dimensional model graphene membrane containing a variety of nanopores of different size by using molecular dynamics simulations. Our results clearly indicate that the continuum flow transits to discrete molecular flow patterns with decreasing pore sizes. While for pores with a diameter ≥15 Å water flux exhibits a linear dependence on the pore area, a nonlinear relationship between water flux and pore area has been identified for smaller pores. We attribute this deviation from linear behavior to the presence of discrete water flow, which is strongly influenced by the water-membrane interaction and hydrogen bonding between water molecules.

  16. Transport behavior of water molecules through two-dimensional nanopores

    Science.gov (United States)

    Zhu, Chongqin; Li, Hui; Meng, Sheng

    2014-11-01

    Water transport through a two-dimensional nanoporous membrane has attracted increasing attention in recent years thanks to great demands in water purification and desalination applications. However, few studies have been reported on the microscopic mechanisms of water transport through structured nanopores, especially at the atomistic scale. Here we investigate the microstructure of water flow through two-dimensional model graphene membrane containing a variety of nanopores of different size by using molecular dynamics simulations. Our results clearly indicate that the continuum flow transits to discrete molecular flow patterns with decreasing pore sizes. While for pores with a diameter ≥15 Å water flux exhibits a linear dependence on the pore area, a nonlinear relationship between water flux and pore area has been identified for smaller pores. We attribute this deviation from linear behavior to the presence of discrete water flow, which is strongly influenced by the water-membrane interaction and hydrogen bonding between water molecules.

  17. Two-dimensional capillary origami

    Energy Technology Data Exchange (ETDEWEB)

    Brubaker, N.D., E-mail: nbrubaker@math.arizona.edu; Lega, J., E-mail: lega@math.arizona.edu

    2016-01-08

    We describe a global approach to the problem of capillary origami that captures all unfolded equilibrium configurations in the two-dimensional setting where the drop is not required to fully wet the flexible plate. We provide bifurcation diagrams showing the level of encapsulation of each equilibrium configuration as a function of the volume of liquid that it contains, as well as plots representing the energy of each equilibrium branch. These diagrams indicate at what volume level the liquid drop ceases to be attached to the endpoints of the plate, which depends on the value of the contact angle. As in the case of pinned contact points, three different parameter regimes are identified, one of which predicts instantaneous encapsulation for small initial volumes of liquid. - Highlights: • Full solution set of the two-dimensional capillary origami problem. • Fluid does not necessarily wet the entire plate. • Global energy approach provides exact differential equations satisfied by minimizers. • Bifurcation diagrams highlight three different regimes. • Conditions for spontaneous encapsulation are identified.

  18. Two-Dimensional Scheduling: A Review

    Directory of Open Access Journals (Sweden)

    Zhuolei Xiao

    2013-07-01

    Full Text Available In this study, we present a literature review, classification schemes and analysis of methodology for scheduling problems on Batch Processing machine (BP with both processing time and job size constraints which is also regarded as Two-Dimensional (TD scheduling. Special attention is given to scheduling problems with non-identical job sizes and processing times, with details of the basic algorithms and other significant results.

  19. String breaking in two-dimensional QCD

    CERN Document Server

    Hornbostel, K J

    1999-01-01

    I present results of a numerical calculation of the effects of light quark-antiquark pairs on the linear heavy-quark potential in light-cone quantized two-dimensional QCD. I extract the potential from the Q-Qbar component of the ground-state wavefunction, and observe string breaking at the heavy-light meson pair threshold. I briefly comment on the states responsible for the breaking.

  20. Two-dimensional numerical computation of the structure-dependent spectral response in a 4H-SiC metal-semiconductor-metal ultraviolet photodetector with consideration of reflection and absorption on contact electrodes

    Institute of Scientific and Technical Information of China (English)

    Chen Bin; Yang Yintang; Chai Changchun; Song Kun; Ma Zhenyang

    2011-01-01

    A two-dimensional model of a 4H-SiC metal-semiconductor-metal (MSM) ultraviolet photodetector has been established using a self-consistent numerical calculation method.The structure-dependent spectral response of a 4H-SiC MSM detector is calculated by solving Poisson's equation,the current continuity equation and the current density equation.The calculated results are verified with experimental data.With consideration of the reflection and absorption on the metal contacts,a detailed study involving various electrode heights (H),spacings (S) and widths (W) reveals conclusive results in device design.The mechanisms responsible for variations of responsivity with those parameters are analyzed.The findings show that responsivity is inversely proportional to electrode height and is enhanced with an increase of electrode spacing and width.In addition,the ultraviolet (UV)-to-visible rejection ratio is > 103.By optimizing the device structure at 10 V bias,a responsivity as high as 180.056 mA/W,a comparable quantum efficiency of 77.93% and a maximum UV-to-visible rejection ratio of 1875 are achieved with a detector size of H =50 nm,S =9 μm and W =3μm.

  1. Two-dimensional numerical computation of the structure-dependent spectral response in a 4H-SiC metal-semiconductor-metal ultraviolet photodetector with consideration of reflection and absorption on contact electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Chen Bin; Yang Yintang; Chai Changchun; Song Kun; Ma Zhenyang, E-mail: xidianchenbin@163.com [Key Laboratory of Ministry of Education for Wide Band-Gap Semiconductor Materials and Devices, School of Microelectronics, Xidian University, Xi' an 710071 (China)

    2011-08-15

    A two-dimensional model of a 4H-SiC metal-semiconductor-metal (MSM) ultraviolet photodetector has been established using a self-consistent numerical calculation method. The structure-dependent spectral response of a 4H-SiC MSM detector is calculated by solving Poisson's equation, the current continuity equation and the current density equation. The calculated results are verified with experimental data. With consideration of the reflection and absorption on the metal contacts, a detailed study involving various electrode heights (H), spacings (S) and widths (W) reveals conclusive results in device design. The mechanisms responsible for variations of responsivity with those parameters are analyzed. The findings show that responsivity is inversely proportional to electrode height and is enhanced with an increase of electrode spacing and width. In addition, the ultraviolet (UV)-to-visible rejection ratio is > 10{sup 3}. By optimizing the device structure at 10 V bias, a responsivity as high as 180.056 mA/W, a comparable quantum efficiency of 77.93% and a maximum UV-to-visible rejection ratio of 1875 are achieved with a detector size of H = 50 nm, S = 9 {mu}m and W = 3 {mu}m.

  2. Two-dimensional capillary origami

    Science.gov (United States)

    Brubaker, N. D.; Lega, J.

    2016-01-01

    We describe a global approach to the problem of capillary origami that captures all unfolded equilibrium configurations in the two-dimensional setting where the drop is not required to fully wet the flexible plate. We provide bifurcation diagrams showing the level of encapsulation of each equilibrium configuration as a function of the volume of liquid that it contains, as well as plots representing the energy of each equilibrium branch. These diagrams indicate at what volume level the liquid drop ceases to be attached to the endpoints of the plate, which depends on the value of the contact angle. As in the case of pinned contact points, three different parameter regimes are identified, one of which predicts instantaneous encapsulation for small initial volumes of liquid.

  3. Two-dimensional cubic convolution.

    Science.gov (United States)

    Reichenbach, Stephen E; Geng, Frank

    2003-01-01

    The paper develops two-dimensional (2D), nonseparable, piecewise cubic convolution (PCC) for image interpolation. Traditionally, PCC has been implemented based on a one-dimensional (1D) derivation with a separable generalization to two dimensions. However, typical scenes and imaging systems are not separable, so the traditional approach is suboptimal. We develop a closed-form derivation for a two-parameter, 2D PCC kernel with support [-2,2] x [-2,2] that is constrained for continuity, smoothness, symmetry, and flat-field response. Our analyses, using several image models, including Markov random fields, demonstrate that the 2D PCC yields small improvements in interpolation fidelity over the traditional, separable approach. The constraints on the derivation can be relaxed to provide greater flexibility and performance.

  4. Description and results of a two-dimensional lattice physics code benchmark for the Canadian Pressure Tube Supercritical Water-cooled Reactor (PT-SCWR)

    Energy Technology Data Exchange (ETDEWEB)

    Hummel, D.W.; Langton, S.E.; Ball, M.R.; Novog, D.R.; Buijs, A., E-mail: hummeld@mcmaster.ca [McMaster Univ., Hamilton, Ontario (Canada)

    2013-07-01

    Discrepancies have been observed among a number of recent reactor physics studies in support of the PT-SCWR pre-conceptual design, including differences in lattice-level predictions of infinite neutron multiplication factor, coolant void reactivity, and radial power profile. As a first step to resolving these discrepancies, a lattice-level benchmark problem was designed based on the 78-element plutonium-thorium PT-SCWR fuel design under a set of prescribed local conditions. This benchmark problem was modeled with a suite of both deterministic and Monte Carlo neutron transport codes. The results of these models are presented here as the basis of a code-to-code comparison. (author)

  5. Two-dimensional hydrodynamic core-collapse supernova simulations with spectral neutrino transport. I. Numerical method and results for a 15 M_sun star

    CERN Document Server

    Buras, R; Janka, H T; Kifonidis, K

    2005-01-01

    Supernova models with a full spectral treatment of the neutrino transport are presented, employing the Prometheus/Vertex neutrino-hydrodynamics code with a ``ray-by-ray plus'' approximation for treating two- (or three-) dimensional problems. The method is described in detail and critically assessed with respect to its capabilities, limitations, and inaccuracies in the context of supernova simulations. In this first paper of a series, 1D and 2D core-collapse calculations for a (nonrotating) 15 M_sun star are discussed, uncertainties in the treatment of the equation of state -- numerical and physical -- are tested, Newtonian results are compared with simulations using a general relativistic potential, bremsstrahlung and interactions of neutrinos of different flavors are investigated, and the standard approximation in neutrino-nucleon interactions with zero energy transfer is replaced by rates that include corrections due to nucleon recoil, thermal motions, weak magnetism, and nucleon correlations. Models with t...

  6. The crystal structure, luminescence and nitrobenzene-sensing properties of a two-dimensional Mn(II) coordination polymer based on 2,6-bis(imidazol-1-yl)pyridine.

    Science.gov (United States)

    Wang, Yin-Lin; Long, Ling-Liang; Zhang, Jin-Fang

    2015-06-01

    A two-dimensional Mn(II) coordination polymer (CP), poly[bis[μ2-2,6-bis(imidazol-1-yl)pyridine-κ(2)N(3):N(3')]bis(thiocyanato-κN)manganese] [Mn(NCS)2(C11H9N5)2]n, (I), has been obtained by the self-assembly reaction of Mn(ClO4)2·6H2O, NH4SCN and bent 2,6-bis(imidazol-1-yl)pyridine (2,6-bip). CP (I) was characterized by FT-IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal structure features a unique two-dimensional (4,4) network with one-dimensional channels. The luminescence and nitrobenzene-sensing properties were explored in a DMF suspension, revealing that CP (I) shows a strong luminescence emission and is highly sensitive for nitrobenzene detection.

  7. Size-dispersity effects in two-dimensional melting.

    Science.gov (United States)

    Watanabe, Hiroshi; Yukawa, Satoshi; Ito, Nobuyasu

    2005-01-01

    In order to investigate the effect of size dispersity on two-dimensional melting transitions, hard-disk systems with equimolar bidispersity are studied by means of particle dynamics simulations. From the nonequilibrium relaxation behaviors of bond-orientational order parameters, we find that (i) there is a critical dispersity at which the melting transition of the hexagonal solid vanishes and (ii) the quadratic structure is metastable in a certain region of the dispersity-density parameter space. These results suggest that the dispersity not only destroys order but produces new structures under certain specific conditions.

  8. Fabrication of two-dimensional micro patterns for adaptive optics by using laser interference lithography

    Science.gov (United States)

    Li, Xinghui; Cai, Yindi; Aihara, Ryo; Shimizu, Yuki; Ito, So; Gao, Wei

    2015-07-01

    This paper presents a fabrication method of two-dimensional micro patterns for adaptive optics with a micrometric or sub-micrometric period to be used for fabrication of micro lens array or two-dimensional diffraction gratings. A multibeam two-axis Lloyd's mirror interferometer is employed to carry out laser interference lithography for the fabrication of two-dimensional grating structures. In the proposed instrument, the optical setup consists of a light source providing a laser beam, a multi-beam generator, two plane mirrors to generate a two-dimensional XY interference pattern and a substrate on which the XY interference pattern is to be exposed. In this paper, pattern exposure tests are carried out by the developed optical configuration optimized by computer simulations. Some experimental results of the XY pattern fabrication will be reported.

  9. A new two-dimensional approach to quantitative prediction for collision cross-section of more than 110 singly protonated peptides by a novel moecular electronegativity-interaction vector through quantitative structure-spectrometry relationship studies

    Institute of Scientific and Technical Information of China (English)

    ZHOU Peng; MEI Hu; TIAN Feifei; WANG Jiaona; WU Shirong; LI Zhiliang

    2007-01-01

    Based on two-dimensional topological characters,a novel method called molecular electronegativityinteraction vector(MEIV)is proposed to parameterize molecular structures.Applying MEIV into quantitative structure-spectrometry relationship studies on ion mobility spectrometry collision cross-sections of 113 singly protonated peptides,three models were strictly obtained,with correlative coefficient r and leave-one-out cross-validation q of 0.983,0.979,0.981,0.979 and 0.980,0.978,respectively.Thus,the MEIV is confirmed to be potent to structural characterizations and property predictions for organic and biologic molecules.

  10. Two-dimensional hybrid layered materials: strain engineering on the band structure of MoS2/WSe2 hetero-multilayers

    Science.gov (United States)

    Gu, Kunming; Yu, Sheng; Eshun, Kwesi; Yuan, Haiwen; Ye, Huixian; Tang, Jiaoning; Ioannou, Dimitris E.; Xiao, Changshi; Wang, Hui; Li, Qiliang

    2017-09-01

    In this paper, we report a comprehensive modeling and simulation study of constructing hybrid layered materials by alternately stacking MoS2 and WSe2 monolayers. Such hybrid MoS2/WSe2 hetero-multilayers exhibited direct bandgap semiconductor characteristics with bandgap energy (E g) in a range of 0.45-0.55 eV at room temperature, very attractive for optoelectronics (wavelength range 2.5-2.75 μm) based on thicker two-dimensional (2D) materials. It was also found that the interlayer distance has a significant impact on the electronic properties of the hetero-multilayers, for example a five orders of magnitude change in the conductance was observed. Three material phases, direct bandgap semiconductor, indirect bandgap semiconductor, and metal were observed in MoS2/WSe2 hetero-multilayers, as the interlayer distance decreased from its relaxed (i.e., equilibrium) value of about 6.73 Å down to 5.50 Å, representing a vertical pressure of about 0.8 GPa for the bilayer and 1.5 GPa for the trilayer. Such new hybrid layered materials are very interesting for future nanoelectronic pressure sensor and nanophotonic applications. This study describes a new approach to explore and engineer the construction and application of tunable 2D semiconductors.

  11. Two-Dimensional Theory of Scientific Representation

    Directory of Open Access Journals (Sweden)

    A Yaghmaie

    2013-03-01

    Full Text Available Scientific representation is an interesting topic for philosophers of science, many of whom have recently explored it from different points of view. There are currently two competing approaches to the issue: cognitive and non-cognitive, and each of them claims its own merits over the other. This article tries to provide a hybrid theory of scientific representation, called Two-Dimensional Theory of Scientific Representation, which has the merits of the two accounts and is free of their shortcomings. To do this, we will argue that although scientific representation needs to use the notion of intentionality, such a notion is defined and realized in a simply structural form contrary to what cognitive approach says about intentionality. After a short introduction, the second part of the paper is devoted to introducing theories of scientific representation briefly. In the third part, the structural accounts of representation will be criticized. The next step is to introduce the two-dimensional theory which involves two key components: fixing and structural fitness. It will be argued that fitness is an objective and non-intentional relation, while fixing is intentional.

  12. Classifying Two-dimensional Hyporeductive Triple Algebras

    CERN Document Server

    Issa, A Nourou

    2010-01-01

    Two-dimensional real hyporeductive triple algebras (h.t.a.) are investigated. A classification of such algebras is presented. As a consequence, a classification of two-dimensional real Lie triple algebras (i.e. generalized Lie triple systems) and two-dimensional real Bol algebras is given.

  13. A self-consistent two-dimensional resistive fluid theory of field-aligned potential structures including charge separation and magnetic and velocity shear

    Science.gov (United States)

    Hesse, Michael; Birn, Joachim; Schindler, Karl

    1990-01-01

    A self-consistent two-fluid theory that includes the magnetic field and shear patterns is developed to model stationary electrostatic structures with field-aligned potential drops. Shear flow is also included in the theory since this seems to be a prominent feature of the structures of interest. In addition, Ohmic dissipation, a Hall term, and pressure gradients in a generalized Ohm's law, modified for cases without quasi-neutrality, are included. In the analytic theory, the electrostatic force is balanced by field-aligned pressure gradients (i.e., thermal effects in the direction of the magnetic field) and by pressure gradients and magnetic stresses in the perpendicular direction. Within this theory, simple examples of applications are presented to demonstrate the kind of solutions resulting from the model. The results show how the effects of charge separation and shear in the magnetic field and the velocity can be combined to form self-consistent structures such as are found to exist above the aurora, suggested also in association with solar flares.

  14. Weakly disordered two-dimensional Frenkel excitons

    Science.gov (United States)

    Boukahil, A.; Zettili, Nouredine

    2004-03-01

    We report the results of studies of the optical properties of weakly disordered two- dimensional Frenkel excitons in the Coherent Potential Approximation (CPA). An approximate complex Green's function for a square lattice with nearest neighbor interactions is used in the self-consistent equation to determine the coherent potential. It is shown that the Density of States is very much affected by the logarithmic singularities in the Green's function. Our CPA results are in excellent agreement with previous investigations by Schreiber and Toyozawa using the Monte Carlo simulation.

  15. An Evaluation of Recently Developed RANS-Based Turbulence Models for Flow Over a Two-Dimensional Block Subjected to Different Mesh Structures and Grid Resolutions

    Science.gov (United States)

    Kardan, Farshid; Cheng, Wai-Chi; Baverel, Olivier; Porté-Agel, Fernando

    2016-04-01

    Understanding, analyzing and predicting meteorological phenomena related to urban planning and built environment are becoming more essential than ever to architectural and urban projects. Recently, various version of RANS models have been established but more validation cases are required to confirm their capability for wind flows. In the present study, the performance of recently developed RANS models, including the RNG k-ɛ , SST BSL k-ω and SST ⪆mma-Reθ , have been evaluated for the flow past a single block (which represent the idealized architecture scale). For validation purposes, the velocity streamlines and the vertical profiles of the mean velocities and variances were compared with published LES and wind tunnel experiment results. Furthermore, other additional CFD simulations were performed to analyze the impact of regular/irregular mesh structures and grid resolutions based on selected turbulence model in order to analyze the grid independency. Three different grid resolutions (coarse, medium and fine) of Nx × Ny × Nz = 320 × 80 × 320, 160 × 40 × 160 and 80 × 20 × 80 for the computational domain and nx × nz = 26 × 32, 13 × 16 and 6 × 8, which correspond to number of grid points on the block edges, were chosen and tested. It can be concluded that among all simulated RANS models, the SST ⪆mma-Reθ model performed best and agreed fairly well to the LES simulation and experimental results. It can also be concluded that the SST ⪆mma-Reθ model provides a very satisfactory results in terms of grid dependency in the fine and medium grid resolutions in both regular and irregular structure meshes. On the other hand, despite a very good performance of the RNG k-ɛ model in the fine resolution and in the regular structure grids, a disappointing performance of this model in the coarse and medium grid resolutions indicates that the RNG k-ɛ model is highly dependent on grid structure and grid resolution. These quantitative validations are essential

  16. Electronic Transmission Properties of Two-Dimensional Quasi-Lattice

    Institute of Scientific and Technical Information of China (English)

    侯志林; 傅秀军; 刘有延

    2002-01-01

    In the framework of the tight binding model, the electronic transmission properties of two-dimensional Penrose lattices with free boundary conditions are studied using the generalized eigenfunction method (Phys. Rev. B 60(1999)13444). The electronic transmission coefficients for Penrose lattices with different sizes and widths are calculated, and the result shows strong energy dependence because of the quasiperiodic structure and quantum coherent effect. Around the Fermi level E = 0, there is an energy region with zero transmission amplitudes,which suggests that the studied systems are insulating. The spatial distributions of several typical electronic states with different transmission coefficients are plotted to display the propagation process.

  17. Two-dimensional photonic crystal surfactant detection.

    Science.gov (United States)

    Zhang, Jian-Tao; Smith, Natasha; Asher, Sanford A

    2012-08-07

    We developed a novel two-dimensional (2-D) crystalline colloidal array photonic crystal sensing material for the visual detection of amphiphilic molecules in water. A close-packed polystyrene 2-D array monolayer was embedded in a poly(N-isopropylacrylamide) (PNIPAAm)-based hydrogel film. These 2-D photonic crystals placed on a mirror show intense diffraction that enables them to be used for visual determination of analytes. Binding of surfactant molecules attaches ions to the sensor that swells the PNIPAAm-based hydrogel. The resulting increase in particle spacing red shifts the 2-D diffracted light. Incorporation of more hydrophobic monomers increases the sensitivity to surfactants.

  18. Two-dimensional discrete gap breathers in a two-dimensional discrete diatomic Klein-Gordon lattice

    Institute of Scientific and Technical Information of China (English)

    XU Quan; QIANG Tian

    2009-01-01

    We study the existence and stability of two-dimensional discrete breathers in a two-dimensional discrete diatomic Klein-Gordon lattice consisting of alternating light and heavy atoms, with nearest-neighbor harmonic coupling.Localized solutions to the corresponding nonlinear differential equations with frequencies inside the gap of the linear wave spectrum, i.e. two-dimensional gap breathers, are investigated numerically. The numerical results of the corresponding algebraic equations demonstrate the possibility of the existence of two-dimensional gap breathers with three types of symmetries, i.e., symmetric, twin-antisymmetric and single-antisymmetric. Their stability depends on the nonlinear on-site potential (soft or hard), the interaction potential (attractive or repulsive)and the center of the two-dimensional gap breather (on a light or a heavy atom).

  19. A study of two-dimensional magnetic polaron

    Institute of Scientific and Technical Information of China (English)

    LIU; Tao; ZHANG; Huaihong; FENG; Mang; WANG; Kelin

    2006-01-01

    By using the variational method and anneal simulation, we study in this paper the self-trapped magnetic polaron (STMP) in two-dimensional anti-ferromagnetic material and the bound magnetic polaron (BMP) in ferromagnetic material. Schwinger angular momentum theory is applied to changing the problem into a coupling problem of carriers and two types of Bosons. Our calculation shows that there are single-peak and multi-peak structures in the two-dimensional STMP. For the ferromagnetic material, the properties of the two-dimensional BMP are almost the same as that in one-dimensional case; but for the anti-ferromagnetic material, the two-dimensional STMP structure is much richer than the one-dimensional case.

  20. Tunable electronic structure in stained two dimensional van der Waals g-C2N/XSe2 (X = Mo, W) heterostructures

    Science.gov (United States)

    Zheng, Z. D.; Wang, X. C.; Mi, W. B.

    2017-10-01

    The electronic structure of the strained g-C2N/XSe2 (X=Mo, W) van der Waals heterostructures are investigated by first-principles calculations. The g-C2N/MoSe2 heterostructure is an indirect band gap semiconductor at a strain from 0% to 8%, where its band gap is 0.66, 0.61, 0.73, 0.60 and 0.33 eV. At K point, the spin splitting is 186, 181, 39, 13 and 9 meV, respectively. For g-C2N/WSe2 heterostructures, the band gap is 0.32, 0.37, 0.42, 0.45 and 0.36 eV, and the conduction band minimum is shifted from Г-M region to K-Г region as the strain increases from 0% to 8%. Its spin splitting monotonically decreases as a strain raises to 8%, which is 445, 424, 261, 111 and 96 meV, respectively. Moreover, at a strain less than 4%, the conduction band mainly comes from g-C2N, but it comes from XSe2 (X=Mo, W) above 6%. Our results show that the g-C2N/XSe2 heterostructures have tunable electronic structures, which makes it a potential candidate for novel electronic devices.

  1. FACE RECOGNITION USING TWO DIMENSIONAL LAPLACIAN EIGENMAP

    Institute of Scientific and Technical Information of China (English)

    Chen Jiangfeng; Yuan Baozong; Pei Bingnan

    2008-01-01

    Recently,some research efforts have shown that face images possibly reside on a nonlinear sub-manifold. Though Laplacianfaces method considered the manifold structures of the face images,it has limits to solve face recognition problem. This paper proposes a new feature extraction method,Two Dimensional Laplacian EigenMap (2DLEM),which especially considers the manifold structures of the face images,and extracts the proper features from face image matrix directly by using a linear transformation. As opposed to Laplacianfaces,2DLEM extracts features directly from 2D images without a vectorization preprocessing. To test 2DLEM and evaluate its performance,a series of ex-periments are performed on the ORL database and the Yale database. Moreover,several experiments are performed to compare the performance of three 2D methods. The experiments show that 2DLEM achieves the best performance.

  2. The two dimensional fold test in paleomagnetism using ipython notebook

    Science.gov (United States)

    Setiabudidaya, Dedi; Piper, John D. A.

    2016-01-01

    One aspect of paleomagnetic analysis prone to controversy is the result of the fold test used to evaluate the age of a magnetisation component relative to the age of a structural event. Initially, the fold test was conducted by comparing the Fisherian precision parameter (k) to results from different limbs of a fold structure before and after tilt adjustment. To accommodate synfolding magnetisation, the tilt correction can be performed in stepwise fashion to both limbs simultaneously, here called one dimensional (1D) fold test. The two dimensional (2D) fold test described in this paper is carried out by applying stepwise tilt adjustment to each limb of the fold separately. The rationale for this is that tilts observed on contrasting limbs of deformed structure may not be synchronous or even belong to the same episode of deformation. A program for the procedure is presented here which generates two dimensional values of the k-parameter visually presented in contoured form. The use of ipython notebook enables this 2D fold test to be performed interactively and yield a more precise evaluation than the primitive 1D fold test.

  3. Synthesis, property and crystal structure of a novel two-dimensional network organic-inorganic hybrid compound based on the neodymium III center and Keggin-type heteropolyanion of [α-BW 12O 40] 5-

    Science.gov (United States)

    Niu, Jingyang; Zhao, Junwei; Wang, Jingping; Ma, Pengtao

    2004-08-01

    A novel two-dimensional infinite network organic-inorganic hybrid neodymium(III)-centered compound of formula (dmaH) 2[Nd(dmf) 4(H 2O)][α-BW 12O 40]·H 2O ( 1) [dma=dimethylamine and dmf= N, N-dimethylformamide] is obtained by the conventional self-assembly reaction of neodymium oxide, N, N-dimethylformamide and borotungstic acid (α-H 5BW 12O 40·30H 2O) in the mixed solvent of acetonitrile and water, and characterized by IR, UV-visible spectra and X-ray single crystal diffraction. Structural analysis indicates that every [α-BW 12O 40] 5- polyanion interconnects with three adjacent [Nd(dmf) 4(H 2O)] 3+ subunits by means of W-O-Nd bridges, meanwhile, every [Nd(dmf) 4(H 2O)] 3+ building block is surrounded by three neighboring [α-BW 12O 40] 5- polyanions by making use of which an unprecedented two-dimensional extended network structure can be constructed. Interestingly, this structure pattern may act as useful model for the design and assembly of functional molecule-based compounds, especially in the field of molecular sieve materials.

  4. Elastic Wave Scattering by Two-Dimensional Periodical Array of Cylinders

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    We extend the multiple-scattering theory (MST) for elastic wave scattering and propagating in two-dimensional composite. The formalism for the band structure calculation is presented by taking into account the full vector character of the elastic wave. As a demonstration of application of the formalism, we calculate the band structure of elastic wave propagating in a two-dimensional periodic arrangement of cylinders. The results manifest that the MST shows great promise in complementing the plane-wave (PW) approach for the study of elastic wave.

  5. Hadamard States and Two-dimensional Gravity

    CERN Document Server

    Salehi, H

    2001-01-01

    We have used a two-dimensional analog of the Hadamard state-condition to study the local constraints on the two-point function of a linear quantum field conformally coupled to a two-dimensional gravitational background. We develop a dynamical model in which the determination of the state of the quantum field is essentially related to the determination of a conformal frame. A particular conformal frame is then introduced in which a two-dimensional gravitational equation is established.

  6. Two-Dimensional Hexagonal Transition-Metal Oxide for Spintronics.

    Science.gov (United States)

    Kan, Erjun; Li, Ming; Hu, Shuanglin; Xiao, Chuanyun; Xiang, Hongjun; Deng, Kaiming

    2013-04-04

    Two-dimensional materials have been the hot subject of studies due to their great potential in applications. However, their applications in spintronics have been blocked by the difficulty in producing ordered spin structures in 2D structures. Here we demonstrated that the ultrathin films of recently experimentally realized wurtzite MnO can automatically transform into a stable graphitic structure with ordered spin arrangement via density functional calculation, and the stability of graphitic structure can be enhanced by external strain. Moreover, the antiferromagnetic ordering of graphitic MnO single layer can be switched into half-metallic ferromagnetism by small hole-doping, and the estimated Curie temperature is higher than 300 K. Thus, our results highlight a promising way toward 2D magnetic materials.

  7. A two-dimensional polymer prepared by organic synthesis.

    Science.gov (United States)

    Kissel, Patrick; Erni, Rolf; Schweizer, W Bernd; Rossell, Marta D; King, Benjamin T; Bauer, Thomas; Götzinger, Stephan; Schlüter, A Dieter; Sakamoto, Junji

    2012-02-05

    Synthetic polymers are widely used materials, as attested by a production of more than 200 millions of tons per year, and are typically composed of linear repeat units. They may also be branched or irregularly crosslinked. Here, we introduce a two-dimensional polymer with internal periodicity composed of areal repeat units. This is an extension of Staudinger's polymerization concept (to form macromolecules by covalently linking repeat units together), but in two dimensions. A well-known example of such a two-dimensional polymer is graphene, but its thermolytic synthesis precludes molecular design on demand. Here, we have rationally synthesized an ordered, non-equilibrium two-dimensional polymer far beyond molecular dimensions. The procedure includes the crystallization of a specifically designed photoreactive monomer into a layered structure, a photo-polymerization step within the crystal and a solvent-induced delamination step that isolates individual two-dimensional polymers as free-standing, monolayered molecular sheets.

  8. RESEARCH ON TWO-DIMENSIONAL LDA FOR FACE RECOGNITION

    Institute of Scientific and Technical Information of China (English)

    Han Ke; Zhu Xiuchang

    2006-01-01

    The letter presents an improved two-dimensional linear discriminant analysis method for feature extraction. Compared with the current two-dimensional methods for feature extraction, the improved two-dimensional linear discriminant analysis method makes full use of not only the row and the column direction information of face images but also the discriminant information among different classes. The method is evaluated using the Nanjing University of Science and Technology (NUST) 603 face database and the Aleix Martinez and Robert Benavente (AR) face database. Experimental results show that the method in the letter is feasible and effective.

  9. Two-dimensional shape memory graphene oxide

    Science.gov (United States)

    Chang, Zhenyue; Deng, Junkai; Chandrakumara, Ganaka G.; Yan, Wenyi; Liu, Jefferson Zhe

    2016-06-01

    Driven by the increasing demand for micro-/nano-technologies, stimuli-responsive shape memory materials at nanoscale have recently attracted great research interests. However, by reducing the size of conventional shape memory materials down to approximately nanometre range, the shape memory effect diminishes. Here, using density functional theory calculations, we report the discovery of a shape memory effect in a two-dimensional atomically thin graphene oxide crystal with ordered epoxy groups, namely C8O. A maximum recoverable strain of 14.5% is achieved as a result of reversible phase transition between two intrinsically stable phases. Our calculations conclude co-existence of the two stable phases in a coherent crystal lattice, giving rise to the possibility of constructing multiple temporary shapes in a single material, thus, enabling highly desirable programmability. With an atomic thickness, excellent shape memory mechanical properties and electric field stimulus, the discovery of a two-dimensional shape memory graphene oxide opens a path for the development of exceptional micro-/nano-electromechanical devices.

  10. The Deconstruction of Japanese Two-dimensional Animation Industry System Based on the Theory of Dissipative Structure%基于耗散结构理论的日本“二次元”动漫产业系统

    Institute of Scientific and Technical Information of China (English)

    李彬; 熊文靓

    2015-01-01

    近年来,日本“二次元”动漫产业已成为动漫界热议的焦点。基于耗散结构理论解析日本“二次元”动漫产业系统发现其具有远离平衡态、非线性、突变性和涨落等耗散结构特点。支撑日本“二次元”动漫产业系统的体系包括政府支持、人才输送、知识产权法律、投融资渠道等。日本经验启示中国发展动漫产业应采取建立激励保健机制、创建学科交叉平台、增加信息技术投入和变“走出去”为“融进去”等措施。%In recent years, Japanese two-dimensional animation industry has become the focus of the debate in animation industry. Based on the theory of dissipative structure, the deconstruction of Japanese two-dimensional animation industry system is found to be far from equilibrium, nonlinear, mutability and lfuctuation etc. The support system of Japanese two-dimensional animation industry system mainly includes the support from the government, intellectual property act, investment and ifnancing. system. Taking examples from Japan's experience, countermeasures are ought to be taken, that establishing incentive care mechanism, creating a platform of cross-disciplines, increasing information technology investment, and "going out" to "blend in", on the current situation of the development of animation industry in China.

  11. Tailoring the Structure of Two-Dimensional Self-Assembled Nanoarchitectures Based on NiII–Salen Building Blocks

    DEFF Research Database (Denmark)

    Viciano-Chumillas, Marta; Li, Dongzhe; Smogunov, Alexander

    2014-01-01

    -butyl) is presented. Their electronic structure and self-assembly was studied. The organic ligands of the salen complexes are functionalized with peripheral carboxylic groups for driving molecular self-assembly through hydrogen bonding. In addition, other substituents, that is, tert-butyl and diamine bridges (2......, which remain unchanged. Scanning tunneling microscopy (STM) shows that the three complexes self-assemble into three different 2D nanoarchitectures at the solid–liquid interface on graphite. Two structures are porous and one is close-packed. These structures are stabilized by hydrogen bonds in one...

  12. Optimal excitation of two dimensional Holmboe instabilities

    CERN Document Server

    Constantinou, Navid C

    2010-01-01

    Highly stratified shear layers are rendered unstable even at high stratifications by Holmboe instabilities when the density stratification is concentrated in a small region of the shear layer. These instabilities may cause mixing in highly stratified environments. However these instabilities occur in tongues for a limited range of parameters. We perform Generalized Stability analysis of the two dimensional perturbation dynamics of an inviscid Boussinesq stratified shear layer and show that Holmboe instabilities at high Richardson numbers can be excited by their adjoints at amplitudes that are orders of magnitude larger than by introducing initially the unstable mode itself. We also determine the optimal growth that obtains for parameters for which there is no instability. We find that there is potential for large transient growth regardless of whether the background flow is exponentially stable or not and that the characteristic structure of the Holmboe instability asymptotically emerges for parameter values ...

  13. Probabilistic Universality in two-dimensional Dynamics

    CERN Document Server

    Lyubich, Mikhail

    2011-01-01

    In this paper we continue to explore infinitely renormalizable H\\'enon maps with small Jacobian. It was shown in [CLM] that contrary to the one-dimensional intuition, the Cantor attractor of such a map is non-rigid and the conjugacy with the one-dimensional Cantor attractor is at most 1/2-H\\"older. Another formulation of this phenomenon is that the scaling structure of the H\\'enon Cantor attractor differs from its one-dimensional counterpart. However, in this paper we prove that the weight assigned by the canonical invariant measure to these bad spots tends to zero on microscopic scales. This phenomenon is called {\\it Probabilistic Universality}. It implies, in particular, that the Hausdorff dimension of the canonical measure is universal. In this way, universality and rigidity phenomena of one-dimensional dynamics assume a probabilistic nature in the two-dimensional world.

  14. Rationally synthesized two-dimensional polymers.

    Science.gov (United States)

    Colson, John W; Dichtel, William R

    2013-06-01

    Synthetic polymers exhibit diverse and useful properties and influence most aspects of modern life. Many polymerization methods provide linear or branched macromolecules, frequently with outstanding functional-group tolerance and molecular weight control. In contrast, extending polymerization strategies to two-dimensional periodic structures is in its infancy, and successful examples have emerged only recently through molecular framework, surface science and crystal engineering approaches. In this Review, we describe successful 2D polymerization strategies, as well as seminal research that inspired their development. These methods include the synthesis of 2D covalent organic frameworks as layered crystals and thin films, surface-mediated polymerization of polyfunctional monomers, and solid-state topochemical polymerizations. Early application targets of 2D polymers include gas separation and storage, optoelectronic devices and membranes, each of which might benefit from predictable long-range molecular organization inherent to this macromolecular architecture.

  15. Two-dimensional fourier transform spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    DeFlores, Lauren; Tokmakoff, Andrei

    2016-10-25

    The present invention relates to a system and methods for acquiring two-dimensional Fourier transform (2D FT) spectra. Overlap of a collinear pulse pair and probe induce a molecular response which is collected by spectral dispersion of the signal modulated probe beam. Simultaneous collection of the molecular response, pulse timing and characteristics permit real time phasing and rapid acquisition of spectra. Full spectra are acquired as a function of pulse pair timings and numerically transformed to achieve the full frequency-frequency spectrum. This method demonstrates the ability to acquire information on molecular dynamics, couplings and structure in a simple apparatus. Multi-dimensional methods can be used for diagnostic and analytical measurements in the biological, biomedical, and chemical fields.

  16. Two-dimensional fourier transform spectrometer

    Science.gov (United States)

    DeFlores, Lauren; Tokmakoff, Andrei

    2013-09-03

    The present invention relates to a system and methods for acquiring two-dimensional Fourier transform (2D FT) spectra. Overlap of a collinear pulse pair and probe induce a molecular response which is collected by spectral dispersion of the signal modulated probe beam. Simultaneous collection of the molecular response, pulse timing and characteristics permit real time phasing and rapid acquisition of spectra. Full spectra are acquired as a function of pulse pair timings and numerically transformed to achieve the full frequency-frequency spectrum. This method demonstrates the ability to acquire information on molecular dynamics, couplings and structure in a simple apparatus. Multi-dimensional methods can be used for diagnostic and analytical measurements in the biological, biomedical, and chemical fields.

  17. Extreme paths in oriented two-dimensional percolation

    OpenAIRE

    Andjel, E. D.; Gray, L. F.

    2016-01-01

    International audience; A useful result about leftmost and rightmost paths in two dimensional bond percolation is proved. This result was introduced without proof in \\cite{G} in the context of the contact process in continuous time. As discussed here, it also holds for several related models, including the discrete time contact process and two dimensional site percolation. Among the consequences are a natural monotonicity in the probability of percolation between different sites and a somewha...

  18. Coherent optical nonlinearities and phase relaxation of quasi-three-dimensional and quasi-two-dimensional excitons in ZnSxSe1 - x/ZnSe structures

    DEFF Research Database (Denmark)

    Wagner, Hans Peter; Schätz, A.; Maier, R.

    1997-01-01

    We investigate the dephasing of heavy-hole excitons in different free-standing ZnSxSe1-x/ZnSe layer structures by spectrally resolved transient four-wave mixing. ZnSe layers of 80, 8, and 4 nm thickness with ternary barriers are studied, representing the crossover from quasi-three-dimensional to ......We investigate the dephasing of heavy-hole excitons in different free-standing ZnSxSe1-x/ZnSe layer structures by spectrally resolved transient four-wave mixing. ZnSe layers of 80, 8, and 4 nm thickness with ternary barriers are studied, representing the crossover from quasi...

  19. Synthesis, crystal structure, and proton conductivity of one-dimensional, two-dimensional, and three-dimensional zirconium phosphonates based on glyphosate and glyphosine.

    Science.gov (United States)

    Taddei, Marco; Donnadio, Anna; Costantino, Ferdinando; Vivani, Riccardo; Casciola, Mario

    2013-10-21

    The reaction of two small phosphono-amino acids based on glycine (glyphosine and glyphosate) with zirconium under mild conditions led to the attainment of three related zirconium derivatives with 1D, 2D, and 3D structures of formulas ZrF[H3(O3PCH2NHCH2COO)2] (1), Zr3H8[(O3PCH2)2NCH2COO]4·2H2O (2), and Zr[(O3PCH2)(HO3PCH2)NHCH2COOH]2·2H2O (3), respectively, whose structures were solved by X-ray powder and single-crystal diffraction data. The glyphosate derivative has 1D ribbon-type structure whereas the dimensionality of the glyphosine-derived materials (2D and 3D) can be tuned by changing the synthesis conditions. The low-dimensional compounds (1 and 2) can be directly produced in the form of nanoparticles with different size and morphology whereas the 3D compound (3) has a higher crystallinity and can be obtained as single crystals with a prismatic shape. The different structural dimensionality reflects the shape and size of the crystals and also differently affects the proton conductivity properties, measured over a wide range of temperature at 95% relative humidity. Their high thermal and chemical stability together with the small size may promote their use as fillers for polymeric electrolyte membranes for fuel cells applications.

  20. Evidence for Intramolecular Antiparallel Beta-Sheet Structure in Alpha-Synuclein Fibrils from a Combination of Two-Dimensional Infrared Spectroscopy and Atomic Force Microscopy

    NARCIS (Netherlands)

    Roeters, Steven J.; Iyer, Aditya; Pletikapic, Galja; Kogan, Vladimir; Subramaniam, Vinod; Woutersen, Sander

    2017-01-01

    The aggregation of the intrinsically disordered protein alpha-synuclein (αS) into amyloid fibrils is thought to play a central role in the pathology of Parkinson’s disease. Using a combination of techniques (AFM, UV-CD, XRD, and amide-I 1D- and 2D-IR spectroscopy) we show that the structure of αS fi

  1. Improved two-dimensional electron mobility in asymmetric barrier delta-doped GaAs/AlGaAs modulation-doped field-effect transistor structures

    Science.gov (United States)

    Das, Sudhakar; Mohapatra, Meryleen; Nayak, Rasmita K.; Panda, Ajit K.; Sahu, Trinath

    2017-03-01

    We study the enhancement of electron mobility μ in barrier delta-doped GaAs/AlGaAs quantum-well-based modulation-doped field-effect transistor (MODFET) structures. We asymmetrically vary the doping concentrations N d1 and N d2 in the barriers on the substrate and surface sides, respectively, to obtain a nonlinear enhancement of μ as a function of the well width w through multi-subband effects. We show that an increase in doping concentration increases the surface electron density N s, which in turn enhances μ. Interchanging N d1 and N d2 leads to no change in N s but rather, an enhancement of μ as a function of w for N d2 > N d1 owing to asymmetric variation of subband wave functions, thereby implying a higher channel conductivity in a surface-doped structure than in an inverted doped structure. By keeping (N d1 + N d2) unchanged, the conductivity of a single-channel MODFET, N d1 (N d2) ≠ 0 and N d2 (N d1) = 0, can be enhanced by considering a MODFET based on an asymmetrically doped (N d1 ≠ N d2 ≠ 0) quantum well structure. We show that the highest N s and μ product for these structures occurs almost before the onset of the occupation of the second subband. Our analysis of the effect of asymmetric doping profiles on channel conductivity can be utilized for the performance improvement of MODFET-like devices.

  2. Crystal Structure And Magnetic Property of the Complex of Hydrogen-bonded Two-dimensional Layer Copper(Ⅱ) Acrylate with Trimethyl Phosphate

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    @@ Copper carboxylate complexes play an important role in catalysing the enzymatic activities[1-4], and the phosphate has an especial use in DNA recognition[5]. Indeed the report about copper carboxylate complexes with phosphate ligands is rare. A chain structure supramolecule [Cu2(CH2CH-COO)4(H2O)2]n has been reported recently[6], in which a Cu2(CH2CH-COO)4(H2O)2 unit is linked by four O(water)-H...O(carboxyl) hydrogen bonds with two adjacent units(Fig.1). In this work a layer structure complex {Cu2(CH2CH-COO)4(H2O)2[OP(OCH3)3]}n was synthesized by means of hydrogen-bonded assembly approach between complex [Cu2(CH2CH-COO)4(H2O)2]n with trimethyl phosphate(TMP).

  3. Vibrational Properties of a Two-Dimensional Silica Kagome Lattice.

    Science.gov (United States)

    Björkman, Torbjörn; Skakalova, Viera; Kurasch, Simon; Kaiser, Ute; Meyer, Jannik C; Smet, Jurgen H; Krasheninnikov, Arkady V

    2016-12-27

    Kagome lattices are structures possessing fascinating magnetic and vibrational properties, but in spite of a large body of theoretical work, experimental realizations and investigations of their dynamics are scarce. Using a combination of Raman spectroscopy and density functional theory calculations, we study the vibrational properties of two-dimensional silica (2D-SiO2), which has a kagome lattice structure. We identify the signatures of crystalline and amorphous 2D-SiO2 structures in Raman spectra and show that, at finite temperatures, the stability of 2D-SiO2 lattice is strongly influenced by phonon-phonon interaction. Our results not only provide insights into the vibrational properties of 2D-SiO2 and kagome lattices in general but also suggest a quick nondestructive method to detect 2D-SiO2.

  4. Evidence for Intramolecular Antiparallel Beta-Sheet Structure in Alpha-Synuclein Fibrils from a Combination of Two-Dimensional Infrared Spectroscopy and Atomic Force Microscopy

    Science.gov (United States)

    Roeters, Steven J.; Iyer, Aditya; Pletikapić, Galja; Kogan, Vladimir; Subramaniam, Vinod; Woutersen, Sander

    2017-01-01

    The aggregation of the intrinsically disordered protein alpha-synuclein (αS) into amyloid fibrils is thought to play a central role in the pathology of Parkinson’s disease. Using a combination of techniques (AFM, UV-CD, XRD, and amide-I 1D- and 2D-IR spectroscopy) we show that the structure of αS fibrils varies as a function of ionic strength: fibrils aggregated in low ionic-strength buffers ([NaCl] ≤ 25 mM) have a significantly different structure than fibrils grown in higher ionic-strength buffers. The observations for fibrils aggregated in low-salt buffers are consistent with an extended conformation of αS molecules, forming hydrogen-bonded intermolecular β-sheets that are loosely packed in a parallel fashion. For fibrils aggregated in high-salt buffers (including those prepared in buffers with a physiological salt concentration) the measurements are consistent with αS molecules in a more tightly-packed, antiparallel intramolecular conformation, and suggest a structure characterized by two twisting stacks of approximately five hydrogen-bonded intermolecular β-sheets each. We find evidence that the high-frequency peak in the amide-I spectrum of αS fibrils involves a normal mode that differs fundamentally from the canonical high-frequency antiparallel β-sheet mode. The high sensitivity of the fibril structure to the ionic strength might form the basis of differences in αS-related pathologies.

  5. Structural determination of oligosaccharides derived from lipooligosaccharide of Neisseria gonorrhoeae F62 by chemical, enzymatic, and two-dimensional NMR methods

    Energy Technology Data Exchange (ETDEWEB)

    Yamasaki, Ryohei; Nasholds, W.; Griffiss, J.M. (Univ. of California, San Francisco (United States) Veterans Administration Medical Center, San Francisco, CA (United States)); Bacon, B.E. (Veterans Administration Medical Center, San Francisco (United States)); Schneider, H. (Walter Reed Research Inst., Washington, DC (United States))

    1991-10-29

    F62 LOS of Neisseria gonorrhoeae consists of two major LOS components; the higher and smaller molecular weight (MW) components were recognized by MAbs 1-1-M and 3F11 respectively. Base-line separation of the two major oligosaccharide (OS) components from F62 LOS was achieved by Bio-Gel P-4 chromatography after dephosphorylation of the OS mixture. The structures of the two major OSs were studied by chemical, enzymatic, and 2D NMR methods as well as methylation followed by GC/MS analysis. The OS component derived from the MAb 1-1-M defined LOS component was determined to have a V{sup 3}-({beta}-N-acetylgalactosaminyl)neolactotetraose structure at one of its nonreducing termini. The OS component derived from the MAb 3F11 defined LOS component did not have a GalNAc residue. The rest of its structure was identical to that of the OS-1, and a neolactotetraose is exposed at its nonreducing terminus.

  6. Strongly interacting two-dimensional Dirac fermions

    NARCIS (Netherlands)

    Lim, L.K.; Lazarides, A.; Hemmerich, Andreas; de Morais Smith, C.

    2009-01-01

    We show how strongly interacting two-dimensional Dirac fermions can be realized with ultracold atoms in a two-dimensional optical square lattice with an experimentally realistic, inherent gauge field, which breaks time reversal and inversion symmetries. We find remarkable phenomena in a temperature

  7. Topology optimization of two-dimensional waveguides

    DEFF Research Database (Denmark)

    Jensen, Jakob Søndergaard; Sigmund, Ole

    2003-01-01

    In this work we use the method of topology optimization to design two-dimensional waveguides with low transmission loss.......In this work we use the method of topology optimization to design two-dimensional waveguides with low transmission loss....

  8. The Two-dimensional Electromagnetic Scattering from Periodic Chiral Structures and Its Finite Element Approximation%周期手性介质中二维电磁散射问题及有限元逼近

    Institute of Scientific and Technical Information of China (English)

    张德悦; 马富明

    2004-01-01

    In this paper, we consider the electromagnetic scattering from periodic chiral structures. The structure is periodic in one direction and invariant in another direction. The electromagnetic fields in the chiral medium are governed by the Maxwell equations together with the Drude-Born-Fedorov equations. We simplify the problem to a two-dimensional scattering problem and we show that for all but possibly a discrete set of wave numbers, there is a unique quasi-periodic weak solution to the diffraction problem. The diffraction problem can be solved by finite element method. We also establish uniform error estimates for the finite element method and the error estimates when the truncation of the nonlocal transparent boundary operators takes place.

  9. Acoustic excitation of diffusion flames with coherent structure in a plane shear layer. ; Application of active combustion control to two-dimensional phase-locked arranging measurements. Soshiki kozo wo tomonau heimen sendai kakusan kaen no onkyo reiki. ; Nijigen iso heikin bunpu sokutei eno active nensho seigyo no oyo

    Energy Technology Data Exchange (ETDEWEB)

    Ishino, Y.; Kojima, T.; Oiwa, N.; Yamaguchi, S. (Nagoya Institute of Technology, Nagoya (Japan))

    1993-11-25

    The acoustic excitation of a plane diffusion flame enhances the periodicity of organized eddy controlled combustion. In this study, to clarify an effectiveness of application of active combustion control, phase characteristics of the excited eddy flames with high periodicity have been examined. A computer-aided phase-locked averaging method was employed to obtain graphical two-dimensional contour maps of the instantaneous profiles of temperature and CH emission. Both maps consisting of eight consecutive phases indicated clearly not only the periodic behavior of the organized eddy flame, but also the gas dynamic properties peculiar to those flames with coherent structure. In addition, the profiles of local contribution of the sound field to the combustion process were examined by calculating the two-dimensional distribution of the local Rayleigh index. Calculation results of the two-dimensional distribution of the local Rayleigh index indicated that the organized eddy flames have high sensitivity to sound, and play an important role in an interaction of sound and flame. 6 refs., 9 figs.

  10. Simulating three-dimensional seismograms in 2.5-dimensional structures by combining two-dimensional finite difference modelling and ray tracing

    Science.gov (United States)

    Miksat, J.; Müller, T. M.; Wenzel, F.

    2008-07-01

    Finite difference (FD) simulation of elastic wave propagation is an important tool in geophysical research. As large-scale 3-D simulations are only feasible on supercomputers or clusters, and even then the simulations are limited to long periods compared to the model size, 2-D FD simulations are widespread. Whereas in generally 3-D heterogeneous structures it is not possible to infer the correct amplitude and waveform from 2-D simulations, in 2.5-D heterogeneous structures some inferences are possible. In particular, Vidale & Helmberger developed an approach that simulates 3-D waveforms using 2-D FD experiments only. However, their method requires a special FD source implementation technique that is based on a source definition which is not any longer used in nowadays FD codes. In this paper, we derive a conversion between 2-D and 3-D Green tensors that allows us to simulate 3-D displacement seismograms using 2-D FD simulations and the actual ray path determined in the geometrical optic limit. We give the conversion for a source of a certain seismic moment that is implemented by incrementing the components of the stress tensor. Therefore, we present a hybrid modelling procedure involving 2-D FD and kinematic ray-tracing techniques. The applicability is demonstrated by numerical experiments of elastic wave propagation for models of different complexity.

  11. Hydrothermal Synthesis and Structure of a New Two- dimensional Zincophosphite:Zn2(HPO3)3(H2DACH (DACH = 1,2-diaminocyclohexane)

    Institute of Scientific and Technical Information of China (English)

    潘建新; 郑寿添; 杨国昱

    2004-01-01

    A new open-framework zincophosphite, Zn2(HPO3)3(H2DACH 1, was hydrothermally synthesized in the presence of 1,2-diaminocyclohexane (DACH) as structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, powder X-ray diffraction and thermogravimetric analysis. Crystal data for 1: Mr = 486.88, monoclinic, space group P21/c with a = 10.2287(11), b = 9.7624(11), c = 16.1686(18) A,β = 92.573(2), V = 1612.9(3) A3, Z = 4, Dc = 2.005 g/cm3, F(000) = 984, μ = 3.314 mm-1 and S = 1.152. The final R = 0.0473 and wR = 0.1121 for 2456 observed reflections with I > 2σ(I). The inorganic layer consisting of four- and eight-membered rings is constructed of alternating ZnO4 tetrahedra and HPO3 pseudo pyramids by sharing vertices. The organic template molecules reside in the interlayer region and interact with the inorganic network through H-bonds.

  12. Predicting Two-Dimensional Silicon Carbide Monolayers.

    Science.gov (United States)

    Shi, Zhiming; Zhang, Zhuhua; Kutana, Alex; Yakobson, Boris I

    2015-10-27

    Intrinsic semimetallicity of graphene and silicene largely limits their applications in functional devices. Mixing carbon and silicon atoms to form two-dimensional (2D) silicon carbide (SixC1-x) sheets is promising to overcome this issue. Using first-principles calculations combined with the cluster expansion method, we perform a comprehensive study on the thermodynamic stability and electronic properties of 2D SixC1-x monolayers with 0 ≤ x ≤ 1. Upon varying the silicon concentration, the 2D SixC1-x presents two distinct structural phases, a homogeneous phase with well dispersed Si (or C) atoms and an in-plane hybrid phase rich in SiC domains. While the in-plane hybrid structure shows uniform semiconducting properties with widely tunable band gap from 0 to 2.87 eV due to quantum confinement effect imposed by the SiC domains, the homogeneous structures can be semiconducting or remain semimetallic depending on a superlattice vector which dictates whether the sublattice symmetry is topologically broken. Moreover, we reveal a universal rule for describing the electronic properties of the homogeneous SixC1-x structures. These findings suggest that the 2D SixC1-x monolayers may present a new "family" of 2D materials, with a rich variety of properties for applications in electronics and optoelectronics.

  13. Synthesis and Crystal Structure of a Two-dimensional Silver Framework Constructed by H2idc (H2idc = Iminodiacetic Acid)

    Institute of Scientific and Technical Information of China (English)

    LIN Xiu-E; CAO Rong; WANG Yan-Qin; LI Xiao-Ju; BI Wen-Hua; YUAN Da-Qiang

    2005-01-01

    A new compound formulated [Ag2(idc)](NO3)(H2O (H2idc = iminodiacetic acid) was synthesized under mild conditions and characterized by IR spectrum and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group of P21/n with a = 5.5029(2), b = 11.1316(5), c = 15.5319 (1) (A), β = 96.038(3)°, V = 946.15(6) (A)3, Z = 4, R = 0.0619 and wR = 0.1606. Its structure is a 2D polymer, whose repeat units consist of dinuclear silver cluster coordinated by two bridging iminodiacetic acids. In the complex, the Ag(I) ions adopt three coordinate fashions, and the Ag-Ag metal-metal contacts of 2.8418 (A) are observed.

  14. Phonon hydrodynamics in two-dimensional materials.

    Science.gov (United States)

    Cepellotti, Andrea; Fugallo, Giorgia; Paulatto, Lorenzo; Lazzeri, Michele; Mauri, Francesco; Marzari, Nicola

    2015-03-06

    The conduction of heat in two dimensions displays a wealth of fascinating phenomena of key relevance to the scientific understanding and technological applications of graphene and related materials. Here, we use density-functional perturbation theory and an exact, variational solution of the Boltzmann transport equation to study fully from first-principles phonon transport and heat conductivity in graphene, boron nitride, molybdenum disulphide and the functionalized derivatives graphane and fluorographene. In all these materials, and at variance with typical three-dimensional solids, normal processes keep dominating over Umklapp scattering well-above cryogenic conditions, extending to room temperature and more. As a result, novel regimes emerge, with Poiseuille and Ziman hydrodynamics, hitherto typically confined to ultra-low temperatures, characterizing transport at ordinary conditions. Most remarkably, several of these two-dimensional materials admit wave-like heat diffusion, with second sound present at room temperature and above in graphene, boron nitride and graphane.

  15. Janus Spectra in Two-Dimensional Flows

    Science.gov (United States)

    Liu, Chien-Chia; Cerbus, Rory T.; Chakraborty, Pinaki

    2016-09-01

    In large-scale atmospheric flows, soap-film flows, and other two-dimensional flows, the exponent of the turbulent energy spectra, α , may theoretically take either of two distinct values, 3 or 5 /3 , but measurements downstream of obstacles have invariably revealed α =3 . Here we report experiments on soap-film flows where downstream of obstacles there exists a sizable interval in which α transitions from 3 to 5 /3 for the streamwise fluctuations but remains equal to 3 for the transverse fluctuations, as if two mutually independent turbulent fields of disparate dynamics were concurrently active within the flow. This species of turbulent energy spectra, which we term the Janus spectra, has never been observed or predicted theoretically. Our results may open up new vistas in the study of turbulence and geophysical flows.

  16. Efficient excitation of photoluminescence in a two-dimensional waveguide consisting of a quantum dot-polymer sandwich-type structure.

    Science.gov (United States)

    Suárez, I; Larrue, A; Rodríguez-Cantó, P J; Almuneau, G; Abargues, R; Chirvony, V S; Martínez-Pastor, J P

    2014-08-15

    In this Letter, we study a new kind of organic polymer waveguide numerically and experimentally by combining an ultrathin (10-50 nm) layer of compactly packed CdSe/ZnS core/shell colloidal quantum dots (QDs) sandwiched between two cladding poly(methyl methacrylate) (PMMA) layers. When a pumping laser beam is coupled into the waveguide edge, light is mostly confined around the QD layer, improving the efficiency of excitation. Moreover, the absence of losses in the claddings allows the propagation of the pumping laser beam along the entire waveguide length; hence, a high-intensity photoluminescence (PL) is produced. Furthermore, a novel fabrication technology is developed to pattern the PMMA into ridge structures by UV lithography in order to provide additional light confinement. The sandwich-type waveguide is analyzed in comparison to a similar one formed by a PMMA film homogeneously doped by the same QDs. A 100-fold enhancement in the waveguided PL is found for the sandwich-type case due to the higher concentration of QDs inside the waveguide.

  17. Nonequilibrium structures and slow dynamics in a two-dimensional spin system with competing long-range and short-range interactions.

    Science.gov (United States)

    Osenda, Omar; Tamarit, Francisco A; Cannas, Sergio A

    2009-08-01

    We present a lattice spin model that mimics a system of interacting particles through a short-range repulsive potential and a long-range attractive power-law decaying potential. We perform a detailed analysis of the general equilibrium phase diagram of the model at finite temperature, showing that the only possible equilibrium phases are the ferromagnetic and the antiferromagnetic ones. We then study the nonequilibrium behavior of the model after a quench to subcritical temperatures, in the antiferromagnetic region of the phase diagram region, where the pair interaction potential behaves in the same qualitative way as in a Lennard-Jones gas. We find that even in the absence of quenched disorder or geometric frustration, the competition between interactions gives rise to nonequilibrium disordered structures at low enough temperatures that strongly slow down the relaxation of the system. This nonequilibrium state presents several features characteristic of glassy systems such as subaging, nontrivial fuctuation dissipation relations, and possible logarithmic growth of free-energy barriers to coarsening.

  18. A Large Deformation Model for the Elastic Moduli of Two-dimensional Cellular Materials

    Institute of Scientific and Technical Information of China (English)

    HU Guoming; WAN Hui; ZHANG Youlin; BAO Wujun

    2006-01-01

    We developed a large deformation model for predicting the elastic moduli of two-dimensional cellular materials. This large deformation model was based on the large deflection of the inclined members of the cells of cellular materials. The deflection of the inclined member, the strain of the representative structure and the elastic moduli of two-dimensional cellular materials were expressed using incomplete elliptic integrals. The experimental results show that these elastic moduli are no longer constant at large deformation, but vary significantly with the strain. A comparison was made between this large deformation model and the small deformation model proposed by Gibson and Ashby.

  19. Spectral Radiative Properties of Two-Dimensional Rough Surfaces

    Science.gov (United States)

    Xuan, Yimin; Han, Yuge; Zhou, Yue

    2012-12-01

    Spectral radiative properties of two-dimensional rough surfaces are important for both academic research and practical applications. Besides material properties, surface structures have impact on the spectral radiative properties of rough surfaces. Based on the finite difference time domain algorithm, this paper studies the spectral energy propagation process on a two-dimensional rough surface and analyzes the effect of different factors such as the surface structure, angle, and polarization state of the incident wave on the spectral radiative properties of the two-dimensional rough surface. To quantitatively investigate the spatial distribution of energy reflected from the rough surface, the concept of the bidirectional reflectance distribution function is introduced. Correlation analysis between the reflectance and different impact factors is conducted to evaluate the influence degree. Comparison between the theoretical and experimental data is given to elucidate the accuracy of the computational code. This study is beneficial to optimizing the surface structures of optoelectronic devices such as solar cells.

  20. Optical modulators with two-dimensional layered materials

    CERN Document Server

    Sun, Zhipei; Wang, Feng

    2016-01-01

    Light modulation is an essential operation in photonics and optoelectronics. With existing and emerging technologies increasingly demanding compact, efficient, fast and broadband optical modulators, high-performance light modulation solutions are becoming indispensable. The recent realization that two-dimensional layered materials could modulate light with superior performance has prompted intense research and significant advances, paving the way for realistic applications. In this review, we cover the state-of-the-art of optical modulators based on two-dimensional layered materials including graphene, transition metal dichalcogenides and black phosphorus. We discuss recent advances employing hybrid structures, such as two-dimensional heterostructures, plasmonic structures, and silicon/fibre integrated structures. We also take a look at future perspectives and discuss the potential of yet relatively unexplored mechanisms such as magneto-optic and acousto-optic modulation.

  1. The use of comprehensive two-dimensional gas chromatography and structure-activity modeling for screening and preliminary risk assessment of organic contaminants in soil, sediment, and surface water

    Energy Technology Data Exchange (ETDEWEB)

    Moreira Bastos, Patricia; Haglund, Peter [Umeaa Univ. (Sweden). Dept. of Chemistry

    2012-08-15

    Purpose: This article aims to investigate the use and benefits of using comprehensive two-dimensional gas chromatography (GC x GC) and structure-activity relationship modeling for screening and prioritization of organic contaminants in complex matrices. The benefit of applying comprehensive screening techniques to samples with high organic contaminant content is primarily that compounds with diverse physicochemical properties can be analyzed simultaneously. Here, a heavily contaminated industrial area was surveyed for organic pollutants by analyzing soil, sediment, and surface water samples. The hazard of the pollutants were ranked using SARs. Material and methods: The water samples were liquid-liquid extracted using dichloromethane and directly analyzed by GC x GC-time-of-flight mass spectrometry (GC x GC-TofMS). Soil and sediment samples were extracted with dichloromethane in an ultrasonic bath and subjected to gel permeation chromatography to eliminate lipids and humic matter. The low molecular weight fraction was then analyzed with GC x GC-TofMS. Results and discussion: More than 10,000 components were found in each sample, of which ca. 300 individual compounds were unambiguously identified using the National Institute of Standards and Technology mass spectra library and authentic reference standards. Alkanes, polycyclic aromatic hydrocarbons, and phthalates were generally the most abundant and were found in all matrices. In contrast, chlorinated compounds such as chlorophenols, biphenyls, and chlorinated pesticides were only detected in samples from a few hotspot regions. The toxicities of the most frequently detected compounds and of the compounds detected at the highest concentrations in samples from hotspot regions were estimated by ecological structure-activity relationships. The ratio of the measured concentration to the predicted toxicity level was then calculated for each compound and used for an initial risk assessment in order to prioritize compounds

  2. 领导成熟度二维结构及其实证研究%The Two-Dimensional Structure of Leadership Maturity and Its Empirical Analysis

    Institute of Scientific and Technical Information of China (English)

    王宝荣; 刘瑜

    2013-01-01

    Research on leadership maturity can not only enrich the theories of management competency and leadership effectiveness , but also contribute to the solutions in management practice like the selection and training of outstanding leaders , the change of leadership style and the improvement of leadership efficiency .Leadership maturity can be ex-plained by six competency characteristics .Using factor analysis , we found that the leadership maturity model consisted of two dimensions:environmental adaptability and internal coordination .Applying structural equation method to analyze 257 samples , this study confirmed that almost all the primary model fit indices reached the criterion and the presumptive mod -el agreed well with the data .%开展领导成熟度的研究既能丰富管理胜任力、领导有效性理论,也有助于解决管理实践中提出的如何选拔培养优秀的领导者,如何转变领导方式,如何提高领导效能等问题。领导成熟度可通过6项管理胜任力特征表现出来,因子分析的结果表明领导成熟度存在环境适应性和内在协调性两个维度。本文利用结构方程对257个样本进行验证性分析,证实各项主要适配指标均达到标准,假设模型与数据能够很好地契合。

  3. Communication: radial distribution functions in a two-dimensional binary colloidal hard sphere system.

    Science.gov (United States)

    Thorneywork, Alice L; Roth, Roland; Aarts, Dirk G A L; Dullens, Roel P A

    2014-04-28

    Two-dimensional hard disks are a fundamentally important many-body model system in classical statistical mechanics. Despite their significance, a comprehensive experimental data set for two-dimensional single component and binary hard disks is lacking. Here, we present a direct comparison between the full set of radial distribution functions and the contact values of a two-dimensional binary colloidal hard sphere model system and those calculated using fundamental measure theory. We find excellent quantitative agreement between our experimental data and theoretical predictions for both single component and binary hard disk systems. Our results provide a unique and fully quantitative mapping between experiments and theory, which is crucial in establishing the fundamental link between structure and dynamics in simple liquids and glass forming systems.

  4. Acoustic resonances in two dimensional radial sonic crystals shells

    CERN Document Server

    Torrent, Daniel

    2010-01-01

    Radial sonic crystals (RSC) are fluidlike structures infinitely periodic along the radial direction. They have been recently introduced and are only possible thanks to the anisotropy of specially designed acoustic metamaterials [see Phys. Rev. Lett. {\\bf 103} 064301 (2009)]. We present here a comprehensive analysis of two-dimensional RSC shells, which consist of a cavity defect centered at the origin of the crystal and a finite thickness crystal shell surrounded by a fluidlike background. We develop analytic expressions demonstrating that, like for other type of crystals (photonic or phononic) with defects, these shells contain Fabry-Perot like resonances and strongly localized modes. The results are completely general and can be extended to three dimensional acoustic structures and to their photonic counterparts, the radial photonic crystals.

  5. Acoustic resonances in two-dimensional radial sonic crystal shells

    Science.gov (United States)

    Torrent, Daniel; Sánchez-Dehesa, José

    2010-07-01

    Radial sonic crystals (RSC) are fluidlike structures infinitely periodic along the radial direction that verify the Bloch theorem and are possible only if certain specially designed acoustic metamaterials with mass density anisotropy can be engineered (see Torrent and Sánchez-Dehesa 2009 Phys. Rev. Lett. 103 064301). A comprehensive analysis of two-dimensional (2D) RSC shells is reported here. A given shell is in fact a circular slab with a central cavity. These finite crystal structures contain Fabry-Perot-like resonances and modes strongly localized at the central cavity. Semi-analytical expressions are developed to obtain the quality factors of the different resonances, their symmetry features and their excitation properties. The results reported here are completely general and can be extended to equivalent 3D spherical shells and to their photonic counterparts.

  6. A hybrid wavelet-based adaptive immersed boundary finite-difference lattice Boltzmann method for two-dimensional fluid-structure interaction

    Science.gov (United States)

    Cui, Xiongwei; Yao, Xiongliang; Wang, Zhikai; Liu, Minghao

    2017-03-01

    A second generation wavelet-based adaptive finite-difference Lattice Boltzmann method (FD-LBM) is developed in this paper. In this approach, the adaptive wavelet collocation method (AWCM) is firstly, to the best of our knowledge, incorporated into the FD-LBM. According to the grid refinement criterion based on the wavelet amplitudes of density distribution functions, an adaptive sparse grid is generated by the omission and addition of collocation points. On the sparse grid, the finite differences are used to approximate the derivatives. To eliminate the special treatments in using the FD-based derivative approximation near boundaries, the immersed boundary method (IBM) is also introduced into FD-LBM. By using the adaptive technique, the adaptive code requires much less grid points as compared to the uniform-mesh code. As a consequence, the computational efficiency can be improved. To justify the proposed method, a series of test cases, including fixed boundary cases and moving boundary cases, are invested. A good agreement between the present results and the data in previous literatures is obtained, which demonstrates the accuracy and effectiveness of the present AWCM-IB-LBM.

  7. Perspective: Two-dimensional resonance Raman spectroscopy

    Science.gov (United States)

    Molesky, Brian P.; Guo, Zhenkun; Cheshire, Thomas P.; Moran, Andrew M.

    2016-11-01

    Two-dimensional resonance Raman (2DRR) spectroscopy has been developed for studies of photochemical reaction mechanisms and structural heterogeneity in complex systems. The 2DRR method can leverage electronic resonance enhancement to selectively probe chromophores embedded in complex environments (e.g., a cofactor in a protein). In addition, correlations between the two dimensions of the 2DRR spectrum reveal information that is not available in traditional Raman techniques. For example, distributions of reactant and product geometries can be correlated in systems that undergo chemical reactions on the femtosecond time scale. Structural heterogeneity in an ensemble may also be reflected in the 2D spectroscopic line shapes of both reactive and non-reactive systems. In this perspective article, these capabilities of 2DRR spectroscopy are discussed in the context of recent applications to the photodissociation reactions of triiodide and myoglobin. We also address key differences between the signal generation mechanisms for 2DRR and off-resonant 2D Raman spectroscopies. Most notably, it has been shown that these two techniques are subject to a tradeoff between sensitivity to anharmonicity and susceptibility to artifacts. Overall, recent experimental developments and applications of the 2DRR method suggest great potential for the future of the technique.

  8. 结构参数对二维Archimedes A7晶格光子晶体禁带的影响%Effects of structure parameters on the bandgap of two dimensional Archimedes A7 photonic crystals

    Institute of Scientific and Technical Information of China (English)

    杨毅彪; 王伟军; 费宏明; 梁伟; 王云才

    2012-01-01

    利用平面波展开法对空气背景中介质圆柱和方柱构造的二维Archimedes A7晶格光子晶体的禁带结构随介质折射率、填充比的变化关系进行了研究,并进一步计算了介质方柱的旋转角度对完全光子禁带宽度的影响.研究发现,介质圆柱构造的Archimedes A7晶格结构在介质柱折射率最低为n=2.40时出现完全光子禁带,当n=2.60时禁带宽度达到最大值.介质方柱构造的Archimedes A7晶格结构在介质柱折射率n=3.80时完全禁带宽度达到最大值,且随着折射率的增加禁带宽度变化很小;在介质方柱折射率恒定情况下,其最大禁带宽度与旋转角度无关,但旋转后出现完全禁带的填充比范围明显扩大.%Plane wave expansion method is introduced to simulate the band structures of two-dimensional photonic crystals made of Archimedes A7 lattice of circular and square dielectric rod in air. The bandgaps of Archimedes A7 lattice with dielectric rods is also discussed as functions of the refractive index, filling fraction and rotation angle. The results show that the complete bandgap can be obtained when the refractive index is greater than 2.40. The width of complete bandgap reaches the maximum when the dielectric refractive index of the circular rod is equal to 2.60. For the Archimedes A7 lattice of square dielectric rod, the complete bandgap reaches the maximum when the dielectric refractive index equals 3. 80. The maximum complete bandgap changes in a narrow range as the refractive index increases. When the rotation angle of the square dielectric rods changes, the maximum bandgap keeps constant for a fixed refractive index. However after the change of rotation angle, the complete bandgap appears in a large scale of the filling fraction.

  9. Two Dimensional Plasmonic Cavities on Moire Surfaces

    Science.gov (United States)

    Balci, Sinan; Kocabas, Askin; Karabiyik, Mustafa; Kocabas, Coskun; Aydinli, Atilla

    2010-03-01

    We investigate surface plasmon polariton (SPP) cavitiy modes on two dimensional Moire surfaces in the visible spectrum. Two dimensional hexagonal Moire surface can be recorded on a photoresist layer using Interference lithography (IL). Two sequential exposures at slightly different angles in IL generate one dimensional Moire surfaces. Further sequential exposure for the same sample at slightly different angles after turning the sample 60 degrees around its own axis generates two dimensional hexagonal Moire cavity. Spectroscopic reflection measurements have shown plasmonic band gaps and cavity states at all the azimuthal angles (omnidirectional cavity and band gap formation) investigated. The plasmonic band gap edge and the cavity states energies show six fold symmetry on the two dimensional Moire surface as measured in reflection measurements.

  10. Two-Dimensional Planetary Surface Lander

    Science.gov (United States)

    Hemmati, H.; Sengupta, A.; Castillo, J.; McElrath, T.; Roberts, T.; Willis, P.

    2014-06-01

    A systems engineering study was conducted to leverage a new two-dimensional (2D) lander concept with a low per unit cost to enable scientific study at multiple locations with a single entry system as the delivery vehicle.

  11. Two dimensional radiated power diagnostics on Alcator C-Moda)

    Science.gov (United States)

    Reinke, M. L.; Hutchinson, I. H.

    2008-10-01

    The radiated power diagnostics for the Alcator C-Mod tokamak have been upgraded to measure two dimensional structure of the photon emissivity profile in order to investigate poloidal asymmetries in the core radiation. Commonly utilized unbiased absolute extreme ultraviolet (AXUV) diode arrays view the plasma along five different horizontal planes. The layout of the diagnostic set is shown and the results from calibrations and recent experiments are discussed. Data showing a significant, 30%-40%, inboard/outboard emissivity asymmetry during ELM-free H-mode are presented. The ability to use AXUV diode arrays to measure absolute radiated power is explored by comparing diode and resistive bolometer-based emissivity profiles for highly radiative L-mode plasmas seeded with argon. Emissivity profiles match in the core but disagree radially outward resulting in an underprediction of Prad of nearly 50% by the diodes compared to Prad determined using resistive bolometers.

  12. Radiation effects on two-dimensional materials

    Energy Technology Data Exchange (ETDEWEB)

    Walker, R.C. II; Robinson, J.A. [Department of Materials Science, Penn State, University Park, PA (United States); Center for Two-Dimensional Layered Materials, Penn State, University Park, PA (United States); Shi, T. [Department of Mechanical and Nuclear Engineering, Penn State, University Park, PA (United States); Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, MI (United States); Silva, E.C. [GlobalFoundries, Malta, NY (United States); Jovanovic, I. [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, MI (United States)

    2016-12-15

    The effects of electromagnetic and particle irradiation on two-dimensional materials (2DMs) are discussed in this review. Radiation creates defects that impact the structure and electronic performance of materials. Determining the impact of these defects is important for developing 2DM-based devices for use in high-radiation environments, such as space or nuclear reactors. As such, most experimental studies have been focused on determining total ionizing dose damage to 2DMs and devices. Total dose experiments using X-rays, gamma rays, electrons, protons, and heavy ions are summarized in this review. We briefly discuss the possibility of investigating single event effects in 2DMs based on initial ion beam irradiation experiments and the development of 2DM-based integrated circuits. Additionally, beneficial uses of irradiation such as ion implantation to dope materials or electron-beam and helium-beam etching to shape materials have begun to be used on 2DMs and are reviewed as well. For non-ionizing radiation, such as low-energy photons, we review the literature on 2DM-based photo-detection from terahertz to UV. The majority of photo-detecting devices operate in the visible and UV range, and for this reason they are the focus of this review. However, we review the progress in developing 2DMs for detecting infrared and terahertz radiation. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  13. Photodetectors based on two dimensional materials

    Science.gov (United States)

    Zheng, Lou; Zhongzhu, Liang; Guozhen, Shen

    2016-09-01

    Two-dimensional (2D) materials with unique properties have received a great deal of attention in recent years. This family of materials has rapidly established themselves as intriguing building blocks for versatile nanoelectronic devices that offer promising potential for use in next generation optoelectronics, such as photodetectors. Furthermore, their optoelectronic performance can be adjusted by varying the number of layers. They have demonstrated excellent light absorption, enabling ultrafast and ultrasensitive detection of light in photodetectors, especially in their single-layer structure. Moreover, due to their atomic thickness, outstanding mechanical flexibility, and large breaking strength, these materials have been of great interest for use in flexible devices and strain engineering. Toward that end, several kinds of photodetectors based on 2D materials have been reported. Here, we present a review of the state-of-the-art in photodetectors based on graphene and other 2D materials, such as the graphene, transition metal dichalcogenides, and so on. Project supported by the National Natural Science Foundation of China (Nos. 61377033, 61574132, 61504136) and the State Key Laboratory of Applied Optics, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences.

  14. Dynamics of vortex interactions in two-dimensional flows

    DEFF Research Database (Denmark)

    Juul Rasmussen, J.; Nielsen, A.H.; Naulin, V.

    2002-01-01

    a critical value, a(c). Using the Weiss-field, a(c) is estimated for vortex patches. Introducing an effective radius for vortices with distributed vorticity, we find that 3.3 a(c) ...The dynamics and interaction of like-signed vortex structures in two dimensional flows are investigated by means of direct numerical solutions of the two-dimensional Navier-Stokes equations. Two vortices with distributed vorticity merge when their distance relative to their radius, d/R-0l. is below...

  15. Hamiltonian formalism of two-dimensional Vlasov kinetic equation.

    Science.gov (United States)

    Pavlov, Maxim V

    2014-12-08

    In this paper, the two-dimensional Benney system describing long wave propagation of a finite depth fluid motion and the multi-dimensional Russo-Smereka kinetic equation describing a bubbly flow are considered. The Hamiltonian approach established by J. Gibbons for the one-dimensional Vlasov kinetic equation is extended to a multi-dimensional case. A local Hamiltonian structure associated with the hydrodynamic lattice of moments derived by D. J. Benney is constructed. A relationship between this hydrodynamic lattice of moments and the two-dimensional Vlasov kinetic equation is found. In the two-dimensional case, a Hamiltonian hydrodynamic lattice for the Russo-Smereka kinetic model is constructed. Simple hydrodynamic reductions are presented.

  16. Flat Chern band in a two-dimensional organometallic framework.

    Science.gov (United States)

    Liu, Zheng; Wang, Zheng-Fei; Mei, Jia-Wei; Wu, Yong-Shi; Liu, Feng

    2013-03-01

    By combining exotic band dispersion with nontrivial band topology, an interesting type of band structure, namely, the flat Chern band, has recently been proposed to spawn high-temperature fractional quantum Hall states. Despite the proposal of several theoretical lattice models, however, it remains doubtful whether such a "romance of flatland" could exist in a real material. Here, we present a first-principles design of a two-dimensional indium-phenylene organometallic framework that realizes a nearly flat Chern band right around the Fermi level by combining lattice geometry, spin-orbit coupling, and ferromagnetism. An effective four-band model is constructed to reproduce the first-principles results. Our design, in addition, provides a general strategy to synthesize topologically nontrivial materials by virtue of organic chemistry and nanotechnology.

  17. Coherent two-dimensional spectroscopy of a Fano model

    CERN Document Server

    Poulsen, Felipe; Pullerits, Tõnu; Hansen, Thorsten

    2016-01-01

    The Fano lineshape arises from the interference of two excitation pathways to reach a continuum. Its generality has resulted in a tremendous success in explaining the lineshapes of many one-dimensional spectroscopies - absorption, emission, scattering, conductance, photofragmentation - applied to very varied systems - atoms, molecules, semiconductors and metals. Unravelling a spectroscopy into a second dimension reveals the relationship between states in addition to decongesting the spectra. Femtosecond-resolved two-dimensional electronic spectroscopy (2DES) is a four-wave mixing technique that measures the time-evolution of the populations, and coherences of excited states. It has been applied extensively to the dynamics of photosynthetic units, and more recently to materials with extended band-structures. In this letter, we solve the full time-dependent third-order response, measured in 2DES, of a Fano model and give the new system parameters that become accessible.

  18. Computationally Driven Two-Dimensional Materials Design: What Is Next?

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Jie [Materials Science; Lany, Stephan [Materials Science; Qi, Yue [Department of Chemical Engineering and Materials Science, Michigan State University, East Lansing, Michigan 48824, United States

    2017-07-17

    Two-dimensional (2D) materials offer many key advantages to innovative applications, such as spintronics and quantum information processing. Theoretical computations have accelerated 2D materials design. In this issue of ACS Nano, Kumar et al. report that ferromagnetism can be achieved in functionalized nitride MXene based on first-principles calculations. Their computational results shed light on a potentially vast group of materials for the realization of 2D magnets. In this Perspective, we briefly summarize the promising properties of 2D materials and the role theory has played in predicting these properties. In addition, we discuss challenges and opportunities to boost the power of computation for the prediction of the 'structure-property-process (synthesizability)' relationship of 2D materials.

  19. Two-dimensional assignment with merged measurements using Langrangrian relaxation

    Science.gov (United States)

    Briers, Mark; Maskell, Simon; Philpott, Mark

    2004-01-01

    Closely spaced targets can result in merged measurements, which complicate data association. Such merged measurements violate any assumption that each measurement relates to a single target. As a result, it is not possible to use the auction algorithm in its simplest form (or other two-dimensional assignment algorithms) to solve the two-dimensional target-to-measurement assignment problem. We propose an approach that uses the auction algorithm together with Lagrangian relaxation to incorporate the additional constraints resulting from the presence of merged measurements. We conclude with some simulated results displaying the concepts introduced, and discuss the application of this research within a particle filter context.

  20. Two-Dimensional Mesoscale-Ordered Conducting Polymers

    NARCIS (Netherlands)

    Liu, Shaohua; Zhang, Jian; Dong, Renhao; Gordiichuk, Pavlo; Zhang, Tao; Zhuang, Xiaodong; Mai, Yiyong; Liu, Feng; Herrmann, Andreas; Feng, Xinliang

    2016-01-01

    Despite the availability of numerous two-dimensional (2D) materials with structural ordering at the atomic or molecular level, direct construction of mesoscale-ordered superstructures within a 2D monolayer remains an enormous challenge. Here, we report the synergic manipulation of two types of assem

  1. Divorticity and dihelicity in two-dimensional hydrodynamics

    DEFF Research Database (Denmark)

    Shivamoggi, B.K.; van Heijst, G.J.F.; Juul Rasmussen, Jens

    2010-01-01

    A framework is developed based on the concepts of divorticity B (≡×ω, ω being the vorticity) and dihelicity g (≡vB) for discussing the theoretical structure underlying two-dimensional (2D) hydrodynamics. This formulation leads to the global and Lagrange invariants that could impose significant...

  2. Two-Dimensional Mesoscale-Ordered Conducting Polymers

    NARCIS (Netherlands)

    Liu, Shaohua; Zhang, Jian; Dong, Renhao; Gordiichuk, Pavlo; Zhang, Tao; Zhuang, Xiaodong; Mai, Yiyong; Liu, Feng; Herrmann, Andreas; Feng, Xinliang

    2016-01-01

    Despite the availability of numerous two-dimensional (2D) materials with structural ordering at the atomic or molecular level, direct construction of mesoscale-ordered superstructures within a 2D monolayer remains an enormous challenge. Here, we report the synergic manipulation of two types of

  3. Two Dimensional F(R) Horava-Lifshitz Gravity

    CERN Document Server

    Kluson, J

    2016-01-01

    We study two-dimensional F(R) Horava-Lifshitz gravity from the Hamiltonian point of view. We determine constraints structure with emphasis on the careful separation of the second class constraints and global first class constraints. We determine number of physical degrees of freedom and also discuss gauge fixing of the global first class constraints.

  4. A heuristic two-dimensional presentation of microsatellite-based data applied to dogs and wolves

    Directory of Open Access Journals (Sweden)

    Foerster Martin

    2007-07-01

    Full Text Available Abstract Methods based on genetic distance matrices usually lose information during the process of tree-building by converting a multi-dimensional matrix into a phylogenetic tree. We applied a heuristic method of two-dimensional presentation to achieve a better resolution of the relationship between breeds and individuals investigated. Four hundred and nine individuals from nine German dog breed populations and one free-living wolf population were analysed with a marker set of 23 microsatellites. The result of the two-dimensional presentation was partly comparable with and complemented a model-based analysis that uses genotype patterns. The assignment test and the neighbour-joining tree based on allele sharing estimate allocated 99% and 97% of the individuals according to their breed, respectively. The application of the two-dimensional presentation to distances on the basis of the proportion of shared alleles resulted in comparable and further complementary insight into inferred population structure by multilocus genotype data. We expect that the inference of population structure in domesticated species with complex breeding histories can be strongly supported by the two-dimensional presentation based on the described heuristic method.

  5. Interior design of a two-dimensional semiclassic black hole

    CERN Document Server

    Levanony, Dana; 10.1103/PhysRevD.80.084008

    2009-01-01

    We look into the inner structure of a two-dimensional dilatonic evaporating black hole. We establish and employ the homogenous approximation for the black-hole interior. The field equations admit two types of singularities, and their local asymptotic structure is investigated. One of these singularities is found to develop, as a spacelike singularity, inside the black hole. We then study the internal structure of the evaporating black hole from the horizon to the singularity.

  6. Tracking dynamics of two-dimensional continuous attractor neural networks

    Science.gov (United States)

    Fung, C. C. Alan; Wong, K. Y. Michael; Wu, Si

    2009-12-01

    We introduce an analytically solvable model of two-dimensional continuous attractor neural networks (CANNs). The synaptic input and the neuronal response form Gaussian bumps in the absence of external stimuli, and enable the network to track external stimuli by its translational displacement in the two-dimensional space. Basis functions of the two-dimensional quantum harmonic oscillator in polar coordinates are introduced to describe the distortion modes of the Gaussian bump. The perturbative method is applied to analyze its dynamics. Testing the method by considering the network behavior when the external stimulus abruptly changes its position, we obtain results of the reaction time and the amplitudes of various distortion modes, with excellent agreement with simulation results.

  7. Two-Dimensional Electronic Spectroscopy Using Incoherent Light: Theoretical Analysis

    CERN Document Server

    Turner, Daniel B; Sutor, Erika J; Hendrickson, Rebecca A; Gealy, M W; Ulness, Darin J

    2012-01-01

    Electronic energy transfer in photosynthesis occurs over a range of time scales and under a variety of intermolecular coupling conditions. Recent work has shown that electronic coupling between chromophores can lead to coherent oscillations in two-dimensional electronic spectroscopy measurements of pigment-protein complexes measured with femtosecond laser pulses. A persistent issue in the field is to reconcile the results of measurements performed using femtosecond laser pulses with physiological illumination conditions. Noisy-light spectroscopy can begin to address this question. In this work we present the theoretical analysis of incoherent two-dimensional electronic spectroscopy, I(4) 2D ES. Simulations reveal diagonal peaks, cross peaks, and coherent oscillations similar to those observed in femtosecond two-dimensional electronic spectroscopy experiments. The results also expose fundamental differences between the femtosecond-pulse and noisy-light techniques; the differences lead to new challenges and opp...

  8. Janus spectra in two-dimensional flows

    CERN Document Server

    Liu, Chien-Chia; Chakraborty, Pinaki

    2016-01-01

    In theory, large-scale atmospheric flows, soap-film flows and other two-dimensional flows may host two distinct types of turbulent energy spectra---in one, $\\alpha$, the spectral exponent of velocity fluctuations, equals $3$ and the fluctuations are dissipated at the small scales, and in the other, $\\alpha=5/3$ and the fluctuations are dissipated at the large scales---but measurements downstream of obstacles have invariably revealed $\\alpha = 3$. Here we report experiments on soap-film flows where downstream of obstacles there exists a sizable interval in which $\\alpha$ has transitioned from $3$ to $5/3$ for the streamwise fluctuations but remains equal to $3$ for the transverse fluctuations, as if two mutually independent turbulent fields of disparate dynamics were concurrently active within the flow. This species of turbulent energy spectra, which we term the Janus spectra, has never been observed or predicted theoretically. Our results may open up new vistas in the study of turbulence and geophysical flows...

  9. Two-dimensional hexagonal semiconductors beyond graphene

    Science.gov (United States)

    Nguyen, Bich Ha; Hieu Nguyen, Van

    2016-12-01

    The rapid and successful development of the research on graphene and graphene-based nanostructures has been substantially enlarged to include many other two-dimensional hexagonal semiconductors (THS): phosphorene, silicene, germanene, hexagonal boron nitride (h-BN) and transition metal dichalcogenides (TMDCs) such as MoS2, MoSe2, WS2, WSe2 as well as the van der Waals heterostructures of various THSs (including graphene). The present article is a review of recent works on THSs beyond graphene and van der Waals heterostructures composed of different pairs of all THSs. One among the priorities of new THSs compared to graphene is the presence of a non-vanishing energy bandgap which opened up the ability to fabricate a large number of electronic, optoelectronic and photonic devices on the basis of these new materials and their van der Waals heterostructures. Moreover, a significant progress in the research on TMDCs was the discovery of valley degree of freedom. The results of research on valley degree of freedom and the development of a new technology based on valley degree of freedom-valleytronics are also presented. Thus the scientific contents of the basic research and practical applications os THSs are very rich and extremely promising.

  10. Stability and electronic properties of two-dimensional indium iodide

    Science.gov (United States)

    Wang, Jizhang; Dong, Baojuan; Guo, Huaihong; Yang, Teng; Zhu, Zhen; Hu, Gan; Saito, Riichiro; Zhang, Zhidong

    2017-01-01

    Based on ab initio density functional calculations, we studied the stability and electronic properties of two-dimensional indium iodide (InI). The calculated results show that monolayer and few-layer InI can be as stable as its bulk counterpart. The stability of the monolayer structure is further supported by examining the electronic and dynamic stability. The interlayer interaction is found to be fairly weak (˜160 meV/atom) and mechanical exfoliation to obtain monolayer and few-layer structures will be applicable. A direct band gap of 1.88 eV of the bulk structure is obtained from the hybrid functional method, and is comparable to the experimental one (˜2.00 eV). The electronic structure can be tuned by layer stacking and external strain. The size of the gap is a linear function of an inverse number of layers, suggesting that we can design few-layer structures for optoelectronic applications in the visible optical range. In-plane tensile or hydrostatic compressive stress is found to be useful not only in varying the gap size to cover the whole visible optical range, but also in inducing a semiconductor-metal transition with an experimentally accessible stress. The present result strongly supports the strategy of broadening the scope of group-V semiconductors by looking for isoelectronic III-VII atomic-layered materials.

  11. rac- 11-t-Butoxy- 1,4-dihydro- 1,4-methanoanthracene:A two-dimensional framework structure built from C-H…O and C-H…π hydrogen bonds

    Institute of Scientific and Technical Information of China (English)

    Hsing Yang Tsai; Ming Hui Luo; Ming Jen Chang; Tzu Chien Fang; Kew Yu Chen

    2012-01-01

    The title compound rac-11-t-butoxy-1,4-dihydro-1,4-methanoanthracene (C19H2oO,Mr =264.35) has been synthesized and characterized by FT-IR,1H NMR,HRMS spectra and single-crystal X-ray diffraction.The crystal belongs to monoclinic,space group P21/n,with a =13.5240(10),b =8.3453(6),c =13.9604(9) (A),β =100.0190(10)°.The structure of the title compound comprises a norbornene unit with a t-butoxy group,having a naphthalene ring fused on one side.The naphthalene is essentially planar with a maximum deviation of 0.032(2) (A) for atom C(3).In the crystal,inversion-related molecules are linked by pairs of C-H...O hydrogen bonds,forming a cyclic dimer with R22 (16) graph-set motif.The C-H...π interactions are also observed,linking the molecules into a continuous two-dimensional framework structure.

  12. A new two-dimensional Cd(II) coordination polymer based on 2-(1H-imidazol-1-ylmethyl)-6-methyl-1H-benzimidazole and benzene-1,2-dicarboxylate: synthesis, crystal structure and characterization.

    Science.gov (United States)

    Yang, Huai Xia; Yang, Yan Qiu; Cheng, Di; Li, Ya Xue; Meng, Xiang Ru

    2017-10-01

    In the construction of coordination polymers, many factors can influence the formation of the final architectures, such as the nature of the metal centres, the organic ligands and the counter-anions. In the coordination polymer poly[aqua(μ-benzene-1,2-dicarboxylato-κ(4)O(1),O(1'):O(2),O(2'))[μ-2-(1H-imidazol-1-ylmethyl)-6-methyl-1H-benzimidazole-κ(2)N(2):N(3)]cadmium(II)], [Cd(C12H12N4)(C8H4O4)(H2O)]n or [Cd(immb)(1,2-bdic)(H2O)]n, each Cd(II) ion is seven-coordinated by two N atoms from two symmetry-related 2-(1H-imidazol-1-ylmethyl)-6-methyl-1H-benzimidazole (immb) ligands, by four O atoms from two symmetry-related benzene-1,2-dicarboxylate (1,2-bdic(2-)) ligands and by one water molecule, leading to a CdN2O5 distorted pentagonal bipyramidal coordination environment. The immb and 1,2-bdic(2-) ligands bridge Cd(II) ions and form a two-dimensional network structure. O-H...O and N-H...O hydrogen bonds stabilize the structure. In addition, the IR spectroscopic properties, PXRD patterns, thermogravimetric behaviour and fluorescence properties of the title polymer have been investigated.

  13. TWO-DIMENSIONAL TOPOLOGY OF COSMOLOGICAL REIONIZATION

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yougang; Xu, Yidong; Chen, Xuelei [Key Laboratory of Computational Astrophysics, National Astronomical Observatories, Chinese Academy of Sciences, Beijing, 100012 China (China); Park, Changbom [School of Physics, Korea Institute for Advanced Study, 85 Hoegiro, Dongdaemun-gu, Seoul 130-722 (Korea, Republic of); Kim, Juhan, E-mail: wangyg@bao.ac.cn, E-mail: cbp@kias.re.kr [Center for Advanced Computation, Korea Institute for Advanced Study, 85 Hoegiro, Dongdaemun-gu, Seoul 130-722 (Korea, Republic of)

    2015-11-20

    We study the two-dimensional topology of the 21-cm differential brightness temperature for two hydrodynamic radiative transfer simulations and two semi-numerical models. In each model, we calculate the two-dimensional genus curve for the early, middle, and late epochs of reionization. It is found that the genus curve depends strongly on the ionized fraction of hydrogen in each model. The genus curves are significantly different for different reionization scenarios even when the ionized faction is the same. We find that the two-dimensional topology analysis method is a useful tool to constrain the reionization models. Our method can be applied to the future observations such as those of the Square Kilometre Array.

  14. Two dimensional topology of cosmological reionization

    CERN Document Server

    Wang, Yougang; Xu, Yidong; Chen, Xuelei; Kim, Juhan

    2015-01-01

    We study the two-dimensional topology of the 21-cm differential brightness temperature for two hydrodynamic radiative transfer simulations and two semi-numerical models. In each model, we calculate the two dimensional genus curve for the early, middle and late epochs of reionization. It is found that the genus curve depends strongly on the ionized fraction of hydrogen in each model. The genus curves are significantly different for different reionization scenarios even when the ionized faction is the same. We find that the two-dimensional topology analysis method is a useful tool to constrain the reionization models. Our method can be applied to the future observations such as those of the Square Kilometer Array.

  15. Two-dimensional lattice Boltzmann model for magnetohydrodynamics.

    Science.gov (United States)

    Schaffenberger, Werner; Hanslmeier, Arnold

    2002-10-01

    We present a lattice Boltzmann model for the simulation of two-dimensional magnetohydro dynamic (MHD) flows. The model is an extension of a hydrodynamic lattice Boltzman model with 9 velocities on a square lattice resulting in a model with 17 velocities. Earlier lattice Boltzmann models for two-dimensional MHD used a bidirectional streaming rule. However, the use of such a bidirectional streaming rule is not necessary. In our model, the standard streaming rule is used, allowing smaller viscosities. To control the viscosity and the resistivity independently, a matrix collision operator is used. The model is then applied to the Hartmann flow, giving reasonable results.

  16. Quasinormal frequencies of asymptotically flat two-dimensional black holes

    CERN Document Server

    Lopez-Ortega, A

    2011-01-01

    We discuss whether the minimally coupled massless Klein-Gordon and Dirac fields have well defined quasinormal modes in single horizon, asymptotically flat two-dimensional black holes. To get the result we solve the equations of motion in the massless limit and we also calculate the effective potentials of Schrodinger type equations. Furthermore we calculate exactly the quasinormal frequencies of the Dirac field propagating in the two-dimensional uncharged Witten black hole. We compare our results on its quasinormal frequencies with other already published.

  17. Two-dimensional x-ray diffraction

    CERN Document Server

    He, Bob B

    2009-01-01

    Written by one of the pioneers of 2D X-Ray Diffraction, this useful guide covers the fundamentals, experimental methods and applications of two-dimensional x-ray diffraction, including geometry convention, x-ray source and optics, two-dimensional detectors, diffraction data interpretation, and configurations for various applications, such as phase identification, texture, stress, microstructure analysis, crystallinity, thin film analysis and combinatorial screening. Experimental examples in materials research, pharmaceuticals, and forensics are also given. This presents a key resource to resea

  18. Matching Two-dimensional Gel Electrophoresis' Spots

    DEFF Research Database (Denmark)

    Dos Anjos, António; AL-Tam, Faroq; Shahbazkia, Hamid Reza

    2012-01-01

    This paper describes an approach for matching Two-Dimensional Electrophoresis (2-DE) gels' spots, involving the use of image registration. The number of false positive matches produced by the proposed approach is small, when compared to academic and commercial state-of-the-art approaches. This ar......This paper describes an approach for matching Two-Dimensional Electrophoresis (2-DE) gels' spots, involving the use of image registration. The number of false positive matches produced by the proposed approach is small, when compared to academic and commercial state-of-the-art approaches...

  19. Mobility anisotropy of two-dimensional semiconductors

    Science.gov (United States)

    Lang, Haifeng; Zhang, Shuqing; Liu, Zhirong

    2016-12-01

    The carrier mobility of anisotropic two-dimensional semiconductors under longitudinal acoustic phonon scattering was theoretically studied using deformation potential theory. Based on the Boltzmann equation with the relaxation time approximation, an analytic formula of intrinsic anisotropic mobility was derived, showing that the influence of effective mass on mobility anisotropy is larger than those of deformation potential constant or elastic modulus. Parameters were collected for various anisotropic two-dimensional materials (black phosphorus, Hittorf's phosphorus, BC2N , MXene, TiS3, and GeCH3) to calculate their mobility anisotropy. It was revealed that the anisotropic ratio is overestimated by the previously described method.

  20. Towards two-dimensional search engines

    OpenAIRE

    Ermann, Leonardo; Chepelianskii, Alexei D.; Shepelyansky, Dima L.

    2011-01-01

    We study the statistical properties of various directed networks using ranking of their nodes based on the dominant vectors of the Google matrix known as PageRank and CheiRank. On average PageRank orders nodes proportionally to a number of ingoing links, while CheiRank orders nodes proportionally to a number of outgoing links. In this way the ranking of nodes becomes two-dimensional that paves the way for development of two-dimensional search engines of new type. Statistical properties of inf...

  1. Phenyl-ring rotational disorder in the two-dimensional hydrogen-bonded structure of the 1:1 proton-transfer salt of the diazo-dye precursor 4-(phenyldiazenyl)aniline (aniline yellow) with L-tartaric acid.

    Science.gov (United States)

    Smith, Graham; Wermuth, Urs D; Young, David J

    2010-07-01

    In the structure of the 1:1 proton-transfer compound from the reaction of L-tartaric acid with the azo-dye precursor aniline yellow [4-(phenyldiazenyl)aniline], namely 4-(phenyldiazenyl)anilinium (2R,3R)-3-carboxy-2,3-dihydroxypropanoate, C(12)H(12)N(3)(+) x C(4)H(5)O(6)(-), the asymmetric unit contains two independent 4-(phenyldiazenyl)anilinium cations and two hydrogen L-tartrate anions. The structure is unusual in that all four phenyl rings of the two cations have identical rotational disorder with equal occupancy of the conformations. The two hydrogen L-tartrate anions form independent but similar chains through head-to-tail carboxyl-carboxylate O-H...O hydrogen bonds [graph set C(7)], which are then extended into a two-dimensional hydrogen-bonded sheet structure through hydroxy O-H...O hydrogen-bonded links. The anilinium groups of the 4-(phenyldiazenyl)anilinium cations are incorporated into the sheets and also provide internal hydrogen-bonded extensions, while their aromatic tails are layered in the structure without significant association except for weak pi-pi interactions [minimum ring centroid separation = 3.844 (3) A]. The hydrogen L-tartrate residues of both anions exhibit the common short intramolecular hydroxy-carboxylate O-H...O hydrogen bonds. This work provides a solution to the unusual disorder problem inherent in the structure of this salt, as well as giving another example of the utility of the hydrogen tartrate anion in the generation of sheet substructures in molecular assembly processes.

  2. A two-dimensional spin liquid in quantum kagome ice.

    Science.gov (United States)

    Carrasquilla, Juan; Hao, Zhihao; Melko, Roger G

    2015-06-22

    Actively sought since the turn of the century, two-dimensional quantum spin liquids (QSLs) are exotic phases of matter where magnetic moments remain disordered even at zero temperature. Despite ongoing searches, QSLs remain elusive, due to a lack of concrete knowledge of the microscopic mechanisms that inhibit magnetic order in materials. Here we study a model for a broad class of frustrated magnetic rare-earth pyrochlore materials called quantum spin ices. When subject to an external magnetic field along the [111] crystallographic direction, the resulting interactions contain a mix of geometric frustration and quantum fluctuations in decoupled two-dimensional kagome planes. Using quantum Monte Carlo simulations, we identify a set of interactions sufficient to promote a groundstate with no magnetic long-range order, and a gap to excitations, consistent with a Z2 spin liquid phase. This suggests an experimental procedure to search for two-dimensional QSLs within a class of pyrochlore quantum spin ice materials.

  3. Two dimensional convolute integers for machine vision and image recognition

    Science.gov (United States)

    Edwards, Thomas R.

    1988-01-01

    Machine vision and image recognition require sophisticated image processing prior to the application of Artificial Intelligence. Two Dimensional Convolute Integer Technology is an innovative mathematical approach for addressing machine vision and image recognition. This new technology generates a family of digital operators for addressing optical images and related two dimensional data sets. The operators are regression generated, integer valued, zero phase shifting, convoluting, frequency sensitive, two dimensional low pass, high pass and band pass filters that are mathematically equivalent to surface fitted partial derivatives. These operators are applied non-recursively either as classical convolutions (replacement point values), interstitial point generators (bandwidth broadening or resolution enhancement), or as missing value calculators (compensation for dead array element values). These operators show frequency sensitive feature selection scale invariant properties. Such tasks as boundary/edge enhancement and noise or small size pixel disturbance removal can readily be accomplished. For feature selection tight band pass operators are essential. Results from test cases are given.

  4. Quantum magnetotransport in a modulated two-dimensional electron gas

    Science.gov (United States)

    Park, Tae-ik; Gumbs, Godfrey

    1997-09-01

    Quantum mechanical calculations of the magnetotransport coefficients of a modulated two-dimensional electron gas in a perpendicular magnetic field are presented using the Kubo method. The model modulation potential used is such that the effect of the steepness of the potential and its strength on the band part of the longitudinal resistivity ρxxand the Hall resistivity ρxycould be studied. In the extreme limit of a very steep potential, a two-dimensional square array of antidots is simulated. Impurity scattering is included in the self-consistent t-matrix approximation. The results show that for a strong lateral superlattice potential, ρxyis quenched in the low magnetic field regime and as the magnetic field increases there is a large negative Hall resistivity. The intensity of this negative peak is suppressed as the strength of the modulation potential is decreased. It is also shown that the height of the negative peak depends on the steepness of the potential. The longitudinal resistivity also has some interesting features. There are Aharonov-Bohm oscillations and a double peak structure which depends on both the strength of the modulation potential as well as its slope. The numerical results show that the position and intensity of the lower peak is not very sensitive to a change in the strength of the lattice potential or its steepness. However, the upper peak is greatly reduced when the lattice potential is diminished in strength. The double peak feature in ρxxand the negative peak and quenching of the Hall effect at low magnetic fields have been observed experimentally for antidots in both the quasiclassical and quantum regimes.

  5. Vortices in the Two-Dimensional Simple Exclusion Process

    Science.gov (United States)

    Bodineau, T.; Derrida, B.; Lebowitz, Joel L.

    2008-06-01

    We show that the fluctuations of the partial current in two dimensional diffusive systems are dominated by vortices leading to a different scaling from the one predicted by the hydrodynamic large deviation theory. This is supported by exact computations of the variance of partial current fluctuations for the symmetric simple exclusion process on general graphs. On a two-dimensional torus, our exact expressions are compared to the results of numerical simulations. They confirm the logarithmic dependence on the system size of the fluctuations of the partial flux. The impact of the vortices on the validity of the fluctuation relation for partial currents is also discussed in an Appendix.

  6. Two-Dimensional Toda-Heisenberg Lattice

    Directory of Open Access Journals (Sweden)

    Vadim E. Vekslerchik

    2013-06-01

    Full Text Available We consider a nonlinear model that is a combination of the anisotropic two-dimensional classical Heisenberg and Toda-like lattices. In the framework of the Hirota direct approach, we present the field equations of this model as a bilinear system, which is closely related to the Ablowitz-Ladik hierarchy, and derive its N-soliton solutions.

  7. A novel two dimensional particle velocity sensor

    NARCIS (Netherlands)

    Pjetri, Olti; Wiegerink, Remco J.; Lammerink, Theo S.; Krijnen, Gijs J.

    2013-01-01

    In this paper we present a two wire, two-dimensional particle velocity sensor. The miniature sensor of size 1.0x2.5x0.525 mm, consisting of only two crossed wires, shows excellent directional sensitivity in both directions, thus requiring no directivity calibration, and is relatively easy to fabrica

  8. Two-dimensional microstrip detector for neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Oed, A. [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    Because of their robust design, gas microstrip detectors, which were developed at ILL, can be assembled relatively quickly, provided the prefabricated components are available. At the beginning of 1996, orders were received for the construction of three two-dimensional neutron detectors. These detectors have been completed. The detectors are outlined below. (author). 2 refs.

  9. Two-dimensional magma-repository interactions

    NARCIS (Netherlands)

    Bokhove, O.

    2001-01-01

    Two-dimensional simulations of magma-repository interactions reveal that the three phases --a shock tube, shock reflection and amplification, and shock attenuation and decay phase-- in a one-dimensional flow tube model have a precursor. This newly identified phase ``zero'' consists of the impact of

  10. Two-dimensional subwavelength plasmonic lattice solitons

    CERN Document Server

    Ye, F; Hu, B; Panoiu, N C

    2010-01-01

    We present a theoretical study of plasmonic lattice solitons (PLSs) formed in two-dimensional (2D) arrays of metallic nanowires embedded into a nonlinear medium with Kerr nonlinearity. We analyze two classes of 2D PLSs families, namely, fundamental and vortical PLSs in both focusing and defocusing media. Their existence, stability, and subwavelength spatial confinement are studied in detai

  11. A two-dimensional Dirac fermion microscope

    DEFF Research Database (Denmark)

    Bøggild, Peter; Caridad, Jose; Stampfer, Christoph

    2017-01-01

    in the solid state. Here we provide a perspective view on how a two-dimensional (2D) Dirac fermion-based microscope can be realistically implemented and operated, using graphene as a vacuum chamber for ballistic electrons. We use semiclassical simulations to propose concrete architectures and design rules of 2...

  12. Optical Spectroscopy of Two Dimensional Graphene and Boron Nitride

    Science.gov (United States)

    Ju, Long

    This dissertation describes the use of optical spectroscopy in studying the physical properties of two dimensional nano materials like graphene and hexagonal boron nitride. Compared to bulk materials, atomically thin two dimensional materials have a unique character that is the strong dependence of physical properties on external control. Both electronic band structure and chemical potential can be tuned in situ by electric field-which is a powerful knob in experiment. Therefore the optical study at atomic thickness scale can greatly benefit from modern micro-fabrication technique and electric control of the material properties. As will be shown in this dissertation, such control of both gemometric and physical properties enables new possibilities of optical spectroscopic measurement as well as opto-electronic studies. Other experimental techniques like electric transport and scanning tunneling microscopy and spectroscopy are also combined with optical spectroscopy to reveal the physics that is beyond the reach of each individual technique. There are three major themes in the dissertation. The first one is focused on the study of plasmon excitation of Dirac electrons in monolayer graphene. Unlike plasmons in ordinary two dimensional electron gas, plasmons of 2D electrons as in graphene obey unusual scaling laws. We fabricate graphene micro-ribbon arrays with photolithography technique and use optical absorption spectroscopy to study its absorption spectrum. The experimental result demonstrates the extraordinarily strong light-plasmon coupling and its novel dependence on both charge doping and geometric dimensions. This work provides a first glance at the fundamental properties of graphene plasmons and forms the basis of an emerging subfield of graphene research and applications such as graphene terahertz metamaterials. The second part describes the opto-electronic response of heterostructures composed of graphene and hexagonal boron nitride. We found that there is

  13. How two-dimensional brick layer J-aggregates differ from linear ones: excitonic properties and line broadening mechanisms

    CERN Document Server

    Dijkstra, Arend G; Knoester, Jasper; Nelson, Keith A; Cao, Jianshu

    2016-01-01

    We study the excitonic coupling and homogeneous spectral line width of brick layer J-aggregate films. We begin by analysing the structural information revealed by the two-exciton states probed in two-dimensional spectra. Our first main result is that the relation between the excitonic couplings and the spectral shift in a two-dimensional structure is different (larger shift for the same nearest neighbour coupling) from that in a one-dimensional structure, which leads to an estimation of dipolar coupling in two-dimensional lattices. We next investigate the mechanisms of homogeneous broadening - population relaxation and pure dephasing - and evaluate their relative importance in linear and two-dimensional aggregates. Our second main result is that pure dephasing dominates the line width in two-dimensional systems up to a crossover temperature, which explains the linear temperature dependence of the homogeneous line width. This is directly related to the decreased density of states at the band edge when compared...

  14. Ultrafast two dimensional infrared chemical exchange spectroscopy

    Science.gov (United States)

    Fayer, Michael

    2011-03-01

    The method of ultrafast two dimensional infrared (2D IR) vibrational echo spectroscopy is described. Three ultrashort IR pulses tuned to the frequencies of the vibrational transitions of interest are directed into the sample. The interaction of these pulses with the molecular vibrational oscillators produces a polarization that gives rise to a fourth pulse, the vibrational echo. The vibrational echo pulse is combined with another pulse, the local oscillator, for heterodyne detection of the signal. For fixed time between the second and third pulses, the waiting time, the first pulse is scanned. Two Fourier transforms of the data yield a 2D IR spectrum. The waiting time is increased, and another spectrum is obtained. The change in the 2D IR spectra with increased waiting time provides information on the time evolution of the structure of the molecular system under observation. In a 2D IR chemical exchange experiment, two species A and B, are undergoing chemical exchange. A's are turning into B's, and B's are turning into A's, but the overall concentrations of the species are not changing. The kinetics of the chemical exchange on the ground electronic state under thermal equilibrium conditions can be obtained 2D IR spectroscopy. A vibration that has a different frequency for the two species is monitored. At very short time, there will be two peaks on the diagonal of the 2D IR spectrum, one for A and one for B. As the waiting time is increased, chemical exchange causes off-diagonal peaks to grow in. The time dependence of the growth of these off-diagonal peaks gives the chemical exchange rate. The method is applied to organic solute-solvent complex formation, orientational isomerization about a carbon-carbon single bond, migration of a hydrogen bond from one position on a molecule to another, protein structural substate interconversion, and water hydrogen bond switching between ions and water molecules. This work was supported by the Air Force Office of Scientific

  15. Operator splitting for two-dimensional incompressible fluid equations

    CERN Document Server

    Holden, Helge; Karper, Trygve K

    2011-01-01

    We analyze splitting algorithms for a class of two-dimensional fluid equations, which includes the incompressible Navier-Stokes equations and the surface quasi-geostrophic equation. Our main result is that the Godunov and Strang splitting methods converge with the expected rates provided the initial data are sufficiently regular.

  16. Thermodynamics of Two-Dimensional Black-Holes

    OpenAIRE

    Nappi, Chiara R.; Pasquinucci, Andrea

    1992-01-01

    We explore the thermodynamics of a general class of two dimensional dilatonic black-holes. A simple prescription is given that allows us to compute the mass, entropy and thermodynamic potentials, with results in agreement with those obtained by other methods, when available.

  17. Two-Dimensional Chirality in Three-Dimensional Chemistry.

    Science.gov (United States)

    Wintner, Claude E.

    1983-01-01

    The concept of two-dimensional chirality is used to enhance students' understanding of three-dimensional stereochemistry. This chirality is used as a key to teaching/understanding such concepts as enaniotropism, diastereotopism, pseudoasymmetry, retention/inversion of configuration, and stereochemical results of addition to double bonds. (JN)

  18. Two-dimensional effects in nonlinear Kronig-Penney models

    DEFF Research Database (Denmark)

    Gaididei, Yuri Borisovich; Christiansen, Peter Leth; Rasmussen, Kim

    1997-01-01

    An analysis of two-dimensional (2D) effects in the nonlinear Kronig-Penney model is presented. We establish an effective one-dimensional description of the 2D effects, resulting in a set of pseudodifferential equations. The stationary states of the 2D system and their stability is studied...

  19. Sound waves in two-dimensional ducts with sinusoidal walls

    Science.gov (United States)

    Nayfeh, A. H.

    1974-01-01

    The method of multiple scales is used to analyze the wave propagation in two-dimensional hard-walled ducts with sinusoidal walls. For traveling waves, resonance occurs whenever the wall wavenumber is equal to the difference of the wavenumbers of any two duct acoustic modes. The results show that neither of these resonating modes could occur without strongly generating the other.

  20. Bounds on the capacity of constrained two-dimensional codes

    DEFF Research Database (Denmark)

    Forchhammer, Søren; Justesen, Jørn

    2000-01-01

    Bounds on the capacity of constrained two-dimensional (2-D) codes are presented. The bounds of Calkin and Wilf apply to first-order symmetric constraints. The bounds are generalized in a weaker form to higher order and nonsymmetric constraints. Results are given for constraints specified by run...

  1. Fabrication of Two-Dimensional Photonic Crystals with Triangular Rods by Single-Exposure Holographic Lithography

    Institute of Scientific and Technical Information of China (English)

    PU Yi-Ying; LIANG Guan-Quan; MAO Wei-Dong; DONG Jian-Wen; WANG He-Zhou

    2007-01-01

    We demonstrate a single-exposure holographic fabrication of two-dimensional photonic crystal witn roundband gaps exist in this structure.Our experimental results show that holographic lithography can be used to fabricate photonic crystals not only with various lattice structures but also with various kinds of structures of the atoms,to obtain absolute band gaps or a particular band gap structure.Furthermore,the single-exposure holographic method not only makes the fabrication process simple and convenient but also makes the structures of the atoms more perfect.

  2. Structural and Spectral Studies on the Ni(Ⅱ) Complexes of 1,5-Diazacyclooctane (DACO) Bearing Heterocyclic Pendants: Formation of a Two-dimensional Network Via Hydrogen Bonds and π-π Stacking Interactions

    Institute of Scientific and Technical Information of China (English)

    DU,Miao(杜淼); DU,Miao; XU,Qiang(徐强); XU,Qiang; GUO,Ya-Mei (郭亚梅); GUO,Ya-Mei; WENG,Lin-Hong(翁林红); WENG,Lin-Hong; BU,Xian-He (卜显和); BU,Xian-He

    2001-01-01

    A penta-coordinated Ni(II) complex with a 1,5-diazacyclooctane (DACO) ligand functionazed by two imidazole donor pendants, [NiiL1Cl] (ClO4)'HH2O (1) (where L1 = 1,5-bis (imidazol-4-ylmethyl)-1,S-diazacyclooctane) has been synthesized and characterized by X-ray diffraction, infrared spectra, elemental analyses, conductance, thermal analyses and UV-Vis techniques. Complex 1 crystallizes in triclinic crystal system, P-1 space group with a = 0.74782(7), b = 1.15082(10), c = 1.237s1(11) nm, a=82.090(2), β=73.011(2), γ=83.462(2)°, V= 1.00603(16) nn3, Mr = 486.00, Z=2,Dc=1.604 g/cm3, final R=0.0435, and wR=0.1244. The structures of 1 and its related complexes show that in all the three mononuclear complexes, each Ni(Ⅱ) center is penta-coordinated with a near regular square pyranid (RSP) to distorted square-pyramidal (DSP) coordination environment due to the boat/chair configuration of DACO ring in these complexes, and the degree of distortion increases with the augment of the size of the heterocyclic pendants. In addition, the most striking feature of complex 1 resides in the formation of a two-dimensional network structure through hydrogen bonds and stabilized by π-π stacking. The solution behaviors of the Ni(ⅡI) complexes are also discussed in detail.

  3. A new one-dimensional Cd(II) coordination polymer with a two-dimensional layered structure incorporating 2-[(1H-imidazol-1-yl)methyl]-1H-benzimidazole and benzene-1,2-dicarboxylate ligands.

    Science.gov (United States)

    Huang, Qiu Ying; Lin, Xiao Yi; Meng, Xiang Ru

    2016-06-01

    The N-heterocyclic ligand 2-[(1H-imidazol-1-yl)methyl]-1H-benzimidazole (imb) has a rich variety of coordination modes and can lead to polymers with intriguing structures and interesting properties. In the coordination polymer catena-poly[[cadmium(II)-bis[μ-benzene-1,2-dicarboxylato-κ(4)O(1),O(1'):O(2),O(2')]-cadmium(II)-bis{μ-2-[(1H-imidazol-1-yl)methyl]-1H-benzimidazole}-κ(2)N(2):N(3);κ(2)N(3):N(2)] dimethylformamide disolvate], {[Cd(C8H4O4)(C11H10N4)]·C3H7NO}n, (I), each Cd(II) ion exhibits an irregular octahedral CdO4N2 coordination geometry and is coordinated by four O atoms from two symmetry-related benzene-1,2-dicarboxylate (1,2-bdic(2-)) ligands and two N atoms from two symmetry-related imb ligands. Two Cd(II) ions are connected by two benzene-1,2-dicarboxylate ligands to generate a binuclear [Cd2(1,2-bdic)2] unit. The binuclear units are further connected into a one-dimensional chain by pairs of bridging imb ligands. These one-dimensional chains are further connected through N-H...O hydrogen bonds and π-π interactions, leading to a two-dimensional layered structure. The dimethylformamide solvent molecules are organized in dimeric pairs via weak interactions. In addition, the title polymer exhibits good fluorescence properties in the solid state at room temperature.

  4. Experimental study of two-dimensional turbulence properties in a plane duct in an azimuthal magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Votsish, A.D.; Kolesnikov, Yu.B.

    1977-01-01

    Results are given for an experimental study of two-dimensional turbulent flow with shifts in a plane duct in an azimuthal magnetic field. The turbulent flow was shown to become practically equal to zero in a sufficiently strong field whereas the intensity of the pulsation rate has a finite value. This is explained by the fact that the magnetic field transforms the structure of turbulence into a two-dimensional structure whose maintenance merely requires an insignificant portion of medium flow energy. 4 illustrations, 8 references.

  5. Numerical Simulation and Visualization of a Flowfield by Interaction of Two Parallel Two-Dimensional Freejets

    OpenAIRE

    TESHIMA, Koji; NAKATSUJI, Hiroyuki

    1987-01-01

    Flowfields resulted from interaction of two equivalent freejets issued from two parallel two-dimensional sonic nozzles at various nozzle distances and at various values of the stagnation to ambient pressure ratio are investigated numerically and by visualization. A strong shear flow region appears between the two jets, which is observed by visualization, is simulated well by the present calculation. Agreements of the parameters representing the whole structure of the flowfield, such as the lo...

  6. Maximizing bandgaps in two-dimensional photonic crystals a variational algorithm

    CERN Document Server

    Paul, P; Paul, Prabasaj; Ndi, Francis C.

    2002-01-01

    We present an algorithm for the maximization of photonic bandgaps in two-dimensional crystals. Once the translational symmetries of the underlying structure have been imposed, our algorithm finds a global maximal (and complete, if one exists) bandgap. Additionally, we prove two remarkable results related to maximal bandgaps: the so-called `maximum contrast' rule, and about the location in the Brillouin zone of band edges.

  7. Two-dimensional gallium nitride realized via graphene encapsulation

    Science.gov (United States)

    Al Balushi, Zakaria Y.; Wang, Ke; Ghosh, Ram Krishna; Vilá, Rafael A.; Eichfeld, Sarah M.; Caldwell, Joshua D.; Qin, Xiaoye; Lin, Yu-Chuan; Desario, Paul A.; Stone, Greg; Subramanian, Shruti; Paul, Dennis F.; Wallace, Robert M.; Datta, Suman; Redwing, Joan M.; Robinson, Joshua A.

    2016-11-01

    The spectrum of two-dimensional (2D) and layered materials `beyond graphene’ offers a remarkable platform to study new phenomena in condensed matter physics. Among these materials, layered hexagonal boron nitride (hBN), with its wide bandgap energy (~5.0-6.0 eV), has clearly established that 2D nitrides are key to advancing 2D devices. A gap, however, remains between the theoretical prediction of 2D nitrides `beyond hBN’ and experimental realization of such structures. Here we demonstrate the synthesis of 2D gallium nitride (GaN) via a migration-enhanced encapsulated growth (MEEG) technique utilizing epitaxial graphene. We theoretically predict and experimentally validate that the atomic structure of 2D GaN grown via MEEG is notably different from reported theory. Moreover, we establish that graphene plays a critical role in stabilizing the direct-bandgap (nearly 5.0 eV), 2D buckled structure. Our results provide a foundation for discovery and stabilization of 2D nitrides that are difficult to prepare via traditional synthesis.

  8. Scale Adjustments to Facilitate Two-Dimensional Measurements in OCT Images.

    Directory of Open Access Journals (Sweden)

    Marina Garcia Garrido

    Full Text Available To address the problem of unequal scales for the measurement of two-dimensional structures in OCT images, and demonstrate the use of intra¬ocular objects of known dimensions in the murine eye for the equal calibration of axes.The first part of this work describes the mathematical foundation of major distortion effects introduced by X-Y scaling differences. Illustrations were generated with CorelGraph X3 software. The second part bases on image data obtained with a HRA2 Spectralis (Heidelberg Engineering in SV129 wild-type mice. Subretinally and intravitreally implanted microbeads, alginate capsules with a diameter of 154±5 μm containing GFP-marked mesenchymal stem cells (CellBeads, were used as intraocular objects for calibration.The problems encountered with two-dimensional measurements in cases of unequal scales are demonstrated and an estimation of the resulting errors is provided. Commonly, the Y axis is reliably calibrated using outside standards like histology or manufacturer data. We show here that intraocular objects like dimensionally stable spherical alginate capsules allow for a two-dimensional calibration of the acquired OCT raw images by establishing a relation between X and Y axis data. For our setup, a correction factor of about 3.3 was determined using both epiretinally and subretinally positioned beads (3.350 ± 0.104 and 3.324 ± 0.083, respectively.In this work, we highlight the distortion-related problems in OCT image analysis induced by unequal X and Y scales. As an exemplary case, we provide data for a two-dimensional in vivo OCT image calibration in mice using intraocular alginate capsules. Our results demonstrate the need for a proper two-dimensional calibration of OCT data, and we believe that equal scaling will certainly improve the efficiency of OCT image analysis.

  9. Electronics based on two-dimensional materials.

    Science.gov (United States)

    Fiori, Gianluca; Bonaccorso, Francesco; Iannaccone, Giuseppe; Palacios, Tomás; Neumaier, Daniel; Seabaugh, Alan; Banerjee, Sanjay K; Colombo, Luigi

    2014-10-01

    The compelling demand for higher performance and lower power consumption in electronic systems is the main driving force of the electronics industry's quest for devices and/or architectures based on new materials. Here, we provide a review of electronic devices based on two-dimensional materials, outlining their potential as a technological option beyond scaled complementary metal-oxide-semiconductor switches. We focus on the performance limits and advantages of these materials and associated technologies, when exploited for both digital and analog applications, focusing on the main figures of merit needed to meet industry requirements. We also discuss the use of two-dimensional materials as an enabling factor for flexible electronics and provide our perspectives on future developments.

  10. Two-dimensional ranking of Wikipedia articles

    Science.gov (United States)

    Zhirov, A. O.; Zhirov, O. V.; Shepelyansky, D. L.

    2010-10-01

    The Library of Babel, described by Jorge Luis Borges, stores an enormous amount of information. The Library exists ab aeterno. Wikipedia, a free online encyclopaedia, becomes a modern analogue of such a Library. Information retrieval and ranking of Wikipedia articles become the challenge of modern society. While PageRank highlights very well known nodes with many ingoing links, CheiRank highlights very communicative nodes with many outgoing links. In this way the ranking becomes two-dimensional. Using CheiRank and PageRank we analyze the properties of two-dimensional ranking of all Wikipedia English articles and show that it gives their reliable classification with rich and nontrivial features. Detailed studies are done for countries, universities, personalities, physicists, chess players, Dow-Jones companies and other categories.

  11. Towards two-dimensional search engines

    CERN Document Server

    Ermann, Leonardo; Shepelyansky, Dima L

    2011-01-01

    We study the statistical properties of various directed networks using ranking of their nodes based on the dominant vectors of the Google matrix known as PageRank and CheiRank. On average PageRank orders nodes proportionally to a number of ingoing links, while CheiRank orders nodes proportionally to a number of outgoing links. In this way the ranking of nodes becomes two-dimensional that paves the way for development of two-dimensional search engines of new type. Information flow properties on PageRank-CheiRank plane are analyzed for networks of British, French and Italian Universities, Wikipedia, Linux Kernel, gene regulation and other networks. Methods of spam links control are also analyzed.

  12. Toward two-dimensional search engines

    Science.gov (United States)

    Ermann, L.; Chepelianskii, A. D.; Shepelyansky, D. L.

    2012-07-01

    We study the statistical properties of various directed networks using ranking of their nodes based on the dominant vectors of the Google matrix known as PageRank and CheiRank. On average PageRank orders nodes proportionally to a number of ingoing links, while CheiRank orders nodes proportionally to a number of outgoing links. In this way, the ranking of nodes becomes two dimensional which paves the way for the development of two-dimensional search engines of a new type. Statistical properties of information flow on the PageRank-CheiRank plane are analyzed for networks of British, French and Italian universities, Wikipedia, Linux Kernel, gene regulation and other networks. A special emphasis is done for British universities networks using the large database publicly available in the UK. Methods of spam links control are also analyzed.

  13. Two dimensional fermions in four dimensional YM

    CERN Document Server

    Narayanan, R

    2009-01-01

    Dirac fermions in the fundamental representation of SU(N) live on a two dimensional torus flatly embedded in $R^4$. They interact with a four dimensional SU(N) Yang Mills vector potential preserving a global chiral symmetry at finite $N$. As the size of the torus in units of $\\frac{1}{\\Lambda_{SU(N)}}$ is varied from small to large, the chiral symmetry gets spontaneously broken in the infinite $N$ limit.

  14. Two-dimensional Kagome photonic bandgap waveguide

    DEFF Research Database (Denmark)

    Nielsen, Jens Bo; Søndergaard, Thomas; Libori, Stig E. Barkou;

    2000-01-01

    The transverse-magnetic photonic-bandgap-guidance properties are investigated for a planar two-dimensional (2-D) Kagome waveguide configuration using a full-vectorial plane-wave-expansion method. Single-moded well-localized low-index guided modes are found. The localization of the optical modes...... is investigated with respect to the width of the 2-D Kagome waveguide, and the number of modes existing for specific frequencies and waveguide widths is mapped out....

  15. Two-dimensional supramolecular electron spin arrays.

    Science.gov (United States)

    Wäckerlin, Christian; Nowakowski, Jan; Liu, Shi-Xia; Jaggi, Michael; Siewert, Dorota; Girovsky, Jan; Shchyrba, Aneliia; Hählen, Tatjana; Kleibert, Armin; Oppeneer, Peter M; Nolting, Frithjof; Decurtins, Silvio; Jung, Thomas A; Ballav, Nirmalya

    2013-05-07

    A bottom-up approach is introduced to fabricate two-dimensional self-assembled layers of molecular spin-systems containing Mn and Fe ions arranged in a chessboard lattice. We demonstrate that the Mn and Fe spin states can be reversibly operated by their selective response to coordination/decoordination of volatile ligands like ammonia (NH3). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Topological defect motifs in two-dimensional Coulomb clusters

    CERN Document Server

    Radzvilavičius, A; 10.1088/0953-8984/23/38/385301

    2012-01-01

    The most energetically favourable arrangement of low-density electrons in an infinite two-dimensional plane is the ordered triangular Wigner lattice. However, in most instances of contemporary interest one deals instead with finite clusters of strongly interacting particles localized in potential traps, for example, in complex plasmas. In the current contribution we study distribution of topological defects in two-dimensional Coulomb clusters with parabolic lateral confinement. The minima hopping algorithm based on molecular dynamics is used to efficiently locate the ground- and low-energy metastable states, and their structure is analyzed by means of the Delaunay triangulation. The size, structure and distribution of geometry-induced lattice imperfections strongly depends on the system size and the energetic state. Besides isolated disclinations and dislocations, classification of defect motifs includes defect compounds --- grain boundaries, rosette defects, vacancies and interstitial particles. Proliferatio...

  17. Two dimensional echocardiographic detection of intraatrial masses.

    Science.gov (United States)

    DePace, N L; Soulen, R L; Kotler, M N; Mintz, G S

    1981-11-01

    With two dimensional echocardiography, a left atrial mass was detected in 19 patients. Of these, 10 patients with rheumatic mitral stenosis had a left atrial thrombus. The distinctive two dimensional echocardiographic features of left atrial thrombus included a mass of irregular nonmobile laminated echos within an enlarged atrial cavity, usually with a broad base of attachment to the posterior left atrial wall. Seven patients had a left atrial myxoma. Usually, the myxoma appeared as a mottled ovoid, sharply demarcated mobile mass attached to the interatrial septum. One patient had a right atrial angiosarcoma that appeared as a nonmobile mass extending from the inferior vena caval-right atrial junction into the right atrial cavity. One patient had a left atrial leiomyosarcoma producing a highly mobile mass attached to the lateral wall of the left atrium. M mode echocardiography detected six of the seven myxomas, one thrombus and neither of the other tumors. Thus, two dimensional echocardiography appears to be the technique of choice in the detection, localization and differentiation of intraatrial masses.

  18. Two dimensional discriminant neighborhood preserving embedding in face recognition

    Science.gov (United States)

    Pang, Meng; Jiang, Jifeng; Lin, Chuang; Wang, Binghui

    2015-03-01

    One of the key issues of face recognition is to extract the features of face images. In this paper, we propose a novel method, named two-dimensional discriminant neighborhood preserving embedding (2DDNPE), for image feature extraction and face recognition. 2DDNPE benefits from four techniques, i.e., neighborhood preserving embedding (NPE), locality preserving projection (LPP), image based projection and Fisher criterion. Firstly, NPE and LPP are two popular manifold learning techniques which can optimally preserve the local geometry structures of the original samples from different angles. Secondly, image based projection enables us to directly extract the optimal projection vectors from twodimensional image matrices rather than vectors, which avoids the small sample size problem as well as reserves useful structural information embedded in the original images. Finally, the Fisher criterion applied in 2DDNPE can boost face recognition rates by minimizing the within-class distance, while maximizing the between-class distance. To evaluate the performance of 2DDNPE, several experiments are conducted on the ORL and Yale face datasets. The results corroborate that 2DDNPE outperforms the existing 1D feature extraction methods, such as NPE, LPP, LDA and PCA across all experiments with respect to recognition rate and training time. 2DDNPE also delivers consistently promising results compared with other competing 2D methods such as 2DNPP, 2DLPP, 2DLDA and 2DPCA.

  19. How two-dimensional bending can extraordinarily stiffen thin sheets

    Science.gov (United States)

    Pini, V.; Ruz, J. J.; Kosaka, P. M.; Malvar, O.; Calleja, M.; Tamayo, J.

    2016-07-01

    Curved thin sheets are ubiquitously found in nature and manmade structures from macro- to nanoscale. Within the framework of classical thin plate theory, the stiffness of thin sheets is independent of its bending state for small deflections. This assumption, however, goes against intuition. Simple experiments with a cantilever sheet made of paper show that the cantilever stiffness largely increases with small amounts of transversal curvature. We here demonstrate by using simple geometric arguments that thin sheets subject to two-dimensional bending necessarily develop internal stresses. The coupling between the internal stresses and the bending moments can increase the stiffness of the plate by several times. We develop a theory that describes the stiffness of curved thin sheets with simple equations in terms of the longitudinal and transversal curvatures. The theory predicts experimental results with a macroscopic cantilever sheet as well as numerical simulations by the finite element method. The results shed new light on plant and insect wing biomechanics and provide an easy route to engineer micro- and nanomechanical structures based on thin materials with extraordinary stiffness tunability.

  20. Chronology Protection in Two-Dimensional Dilaton Gravity

    CERN Document Server

    Mishima, T; Mishima, Takashi; Nakamichi, Akika

    1994-01-01

    The global structure of 1 + 1 dimensional compact Universe is studied in two-dimensional model of dilaton gravity. First we give a classical solution corresponding to the spacetime in which a closed time-like curve appears, and show the instability of this spacetime due to the existence of matters. We also observe quantum version of such a spacetime having closed timelike curves never reappear unless the parameters are fine-tuned.

  1. Phase Transitions in Two-Dimensional Traffic Flow Models

    CERN Document Server

    Cuesta, J A; Molera, J M; Cuesta, José A; Martinez, Froilán C; Molera, Juan M

    1993-01-01

    Abstract: We introduce two simple two-dimensional lattice models to study traffic flow in cities. We have found that a few basic elements give rise to the characteristic phase diagram of a first-order phase transition from a freely moving phase to a jammed state, with a critical point. The jammed phase presents new transitions corresponding to structural transformations of the jam. We discuss their relevance in the infinite size limit.

  2. Phase Transitions in Two-Dimensional Traffic Flow Models

    CERN Document Server

    Cuesta, José A; Molera, Juan M; Escuela, Angel Sánchez; 10.1103/PhysRevE.48.R4175

    2009-01-01

    We introduce two simple two-dimensional lattice models to study traffic flow in cities. We have found that a few basic elements give rise to the characteristic phase diagram of a first-order phase transition from a freely moving phase to a jammed state, with a critical point. The jammed phase presents new transitions corresponding to structural transformations of the jam. We discuss their relevance in the infinite size limit.

  3. SU(1,2) invariance in two-dimensional oscillator

    CERN Document Server

    Krivonos, Sergey

    2016-01-01

    Performing the Hamiltonian analysis we explicitly established the canonical equivalence of the deformed oscillator, constructed in arXiv:1607.03756[hep-th], with the ordinary one. As an immediate consequence, we proved that the SU(1,2) symmetry is the dynamical symmetry of the ordinary two-dimensional oscillator. The characteristic feature of this SU(1,2) symmetry is a non-polynomial structure of its generators written it terms of the oscillator variables.

  4. Molecular assembly on two-dimensional materials

    Science.gov (United States)

    Kumar, Avijit; Banerjee, Kaustuv; Liljeroth, Peter

    2017-02-01

    Molecular self-assembly is a well-known technique to create highly functional nanostructures on surfaces. Self-assembly on two-dimensional (2D) materials is a developing field driven by the interest in functionalization of 2D materials in order to tune their electronic properties. This has resulted in the discovery of several rich and interesting phenomena. Here, we review this progress with an emphasis on the electronic properties of the adsorbates and the substrate in well-defined systems, as unveiled by scanning tunneling microscopy. The review covers three aspects of the self-assembly. The first one focuses on non-covalent self-assembly dealing with site-selectivity due to inherent moiré pattern present on 2D materials grown on substrates. We also see that modification of intermolecular interactions and molecule–substrate interactions influences the assembly drastically and that 2D materials can also be used as a platform to carry out covalent and metal-coordinated assembly. The second part deals with the electronic properties of molecules adsorbed on 2D materials. By virtue of being inert and possessing low density of states near the Fermi level, 2D materials decouple molecules electronically from the underlying metal substrate and allow high-resolution spectroscopy and imaging of molecular orbitals. The moiré pattern on the 2D materials causes site-selective gating and charging of molecules in some cases. The last section covers the effects of self-assembled, acceptor and donor type, organic molecules on the electronic properties of graphene as revealed by spectroscopy and electrical transport measurements. Non-covalent functionalization of 2D materials has already been applied for their application as catalysts and sensors. With the current surge of activity on building van der Waals heterostructures from atomically thin crystals, molecular self-assembly has the potential to add an extra level of flexibility and functionality for applications ranging

  5. Aerodynamics of two-dimensional flapping wings in tandem configuration

    Science.gov (United States)

    Lua, K. B.; Lu, H.; Zhang, X. H.; Lim, T. T.; Yeo, K. S.

    2016-12-01

    This paper reports a fundamental investigation on the aerodynamics of two-dimensional flapping wings in tandem configuration in forward flight. Of particular interest are the effects of phase angle (φ) and center-to-center distance (L) between the front wing and the rear wing on the aerodynamic force generation at a Reynolds number of 5000. Both experimental and numerical methods were employed. A force sensor was used to measure the time-history aerodynamic forces experienced by the two wings and digital particle image velocimetry was utilized to obtain the corresponding flow structures. Both the front wing and the rear wing executed the same simple harmonic motions with φ ranging from -180° to 180° and four values of L, i.e., 1.5c, 2c, 3c, and 4c (c is the wing chord length). Results show that at fixed L = 2c, tandem wings perform better than the sum of two single wings that flap independently in terms of thrust for phase angle approximately from -90° to 90°. The maximum thrust on the rear wing occurs during in-phase flapping (φ = 0°). Correlation of transient thrust and flow structure indicates that there are generally two types of wing-wake interactions, depending on whether the rear wing crosses the shear layer shed from the front wing. Finally, increasing wing spacing has similar effect as reducing the phase angle, and an approximate mathematical model is derived to describe the relationship between these two parameters.

  6. Electromagnetic Wave Propagation in Two-Dimensional Photonic Crystals

    Energy Technology Data Exchange (ETDEWEB)

    Stavroula Foteinopoulou

    2003-12-12

    In this dissertation, they have undertaken the challenge to understand the unusual propagation properties of the photonic crystal (PC). The photonic crystal is a medium where the dielectric function is periodically modulated. These types of structures are characterized by bands and gaps. In other words, they are characterized by frequency regions where propagation is prohibited (gaps) and regions where propagation is allowed (bands). In this study they focus on two-dimensional photonic crystals, i.e., structures with periodic dielectric patterns on a plane and translational symmetry in the perpendicular direction. They start by studying a two-dimensional photonic crystal system for frequencies inside the band gap. The inclusion of a line defect introduces allowed states in the otherwise prohibited frequency spectrum. The dependence of the defect resonance state on different parameters such as size of the structure, profile of incoming source, etc., is investigated in detail. For this study, they used two popular computational methods in photonic crystal research, the Finite Difference Time Domain method (FDTD) and the Transfer Matrix Method (TMM). The results for the one-dimensional defect system are analyzed, and the two methods, FDTD and TMM, are compared. Then, they shift their attention only to periodic two-dimensional crystals, concentrate on their band properties, and study their unusual refractive behavior. Anomalous refractive phenomena in photonic crystals included cases where the beam refracts on the ''wrong'' side of the surface normal. The latter phenomenon, is known as negative refraction and was previously observed in materials where the wave vector, the electric field, and the magnetic field form a left-handed set of vectors. These materials are generally called left-handed materials (LHM) or negative index materials (NIM). They investigated the possibility that the photonic crystal behaves as a LHM, and how this behavior relates

  7. Analysis of one dimensional and two dimensional fuzzy controllers

    Institute of Scientific and Technical Information of China (English)

    Ban Xiaojun; Gao Xiaozhi; Huang Xianlin; Wu Tianbao

    2006-01-01

    The analytical structures and the corresponding mathematical properties of the one dimensional and two dimensional fuzzy controllers are first investigated in detail.The nature of these two kinds of fuzzy controllers is next probed from the perspective of control engineering. For the one dimensional fuzzy controller, it is concluded that this controller is a combination of a saturation element and a nonlinear proportional controller, and the system that employs the one dimensional fuzzy controller is the combination of an open-loop control system and a closedloop control system. For the latter case, it is concluded that it is a hybrid controller, which comprises the saturation part, zero-output part, nonlinear derivative part, nonlinear proportional part, as well as nonlinear proportional-derivative part, and the two dimensional fuzzy controller-based control system is a loop-varying system with varying number of control loops.

  8. Data analysis results of the second sea trial of ambient noise imaging with acoustic lens in 2014: Two-dimensional target images affected by direction of field of view and spatial noise distribution

    Science.gov (United States)

    Mori, Kazuyoshi; Ogasawara, Hanako; Tsuchiya, Takenobu; Endoh, Nobuyuki

    2016-07-01

    An aspherical lens with an aperture diameter of 1.0 m has been designed and fabricated to develop a prototype system for ambient noise imaging (ANI). A sea trial of silent target detection using the prototype ANI system was conducted under only natural ocean ambient noise at Uchiura Bay in November 2010. It was verified that targets are successfully detected under natural ocean ambient noise, mainly generated by snapping shrimps. Recently, we have built a second prototype ANI system using an acoustic lens with a two-dimensional (2D) receiver array with 127 elements corresponding to a field of view (FOV) spanning 15° horizontally by 9° vertically. In this study, we investigated the effects of the direction of the FOV and the spatial noise distribution on the 2D target image obtained by ANI. Here, the noise sources in front of the target are called “front light”, and those at the rear of the target are called “back light”. The second sea trial was conducted to image targets arranged in the FOV and measure the positions of noise sources at Uchiura Bay in November 10-14, 2014. For front light, the pixel values in the on-target directions were greater than those in other directions owing to the dominant target scatterings. Reversely, for back light, the pixel values in the on-target directions were lower than those in other directions owing to the dominant direct noises such as “silhouette”.

  9. Strongly correlated two-dimensional plasma explored from entropy measurements.

    Science.gov (United States)

    Kuntsevich, A Y; Tupikov, Y V; Pudalov, V M; Burmistrov, I S

    2015-06-23

    Charged plasma and Fermi liquid are two distinct states of electronic matter intrinsic to dilute two-dimensional electron systems at elevated and low temperatures, respectively. Probing their thermodynamics represents challenge because of lack of an adequate technique. Here, we report a thermodynamic method to measure the entropy per electron in gated structures. Our technique appears to be three orders of magnitude superior in sensitivity to a.c. calorimetry, allowing entropy measurements with only 10(8) electrons. This enables us to investigate the correlated plasma regime, previously inaccessible experimentally in two-dimensional electron systems in semiconductors. In experiments with clean two-dimensional electron system in silicon-based structures, we traced entropy evolution from the plasma to Fermi liquid regime by varying electron density. We reveal that the correlated plasma regime can be mapped onto the ordinary non-degenerate Fermi gas with an interaction-enhanced temperature-dependent effective mass. Our method opens up new horizons in studies of low-dimensional electron systems.

  10. Theory of two-dimensional transformations

    OpenAIRE

    Kanayama, Yutaka J.; Krahn, Gary W.

    1998-01-01

    The article of record may be found at http://dx.doi.org/10.1109/70.720359 Robotics and Automation, IEEE Transactions on This paper proposes a new "heterogeneous" two-dimensional (2D) transformation group ___ to solve motion analysis/planning problems in robotics. In this theory, we use a 3×1 matrix to represent a transformation as opposed to a 3×3 matrix in the homogeneous formulation. First, this theory is as capable as the homogeneous theory, Because of the minimal size, its implement...

  11. Two-dimensional ranking of Wikipedia articles

    CERN Document Server

    Zhirov, A O; Shepelyansky, D L

    2010-01-01

    The Library of Babel, described by Jorge Luis Borges, stores an enormous amount of information. The Library exists {\\it ab aeterno}. Wikipedia, a free online encyclopaedia, becomes a modern analogue of such a Library. Information retrieval and ranking of Wikipedia articles become the challenge of modern society. We analyze the properties of two-dimensional ranking of all Wikipedia English articles and show that it gives their reliable classification with rich and nontrivial features. Detailed studies are done for countries, universities, personalities, physicists, chess players, Dow-Jones companies and other categories.

  12. Mobility anisotropy of two-dimensional semiconductors

    CERN Document Server

    Lang, Haifeng; Liu, Zhirong

    2016-01-01

    The carrier mobility of anisotropic two-dimensional (2D) semiconductors under longitudinal acoustic (LA) phonon scattering was theoretically studied with the deformation potential theory. Based on Boltzmann equation with relaxation time approximation, an analytic formula of intrinsic anisotropic mobility was deduced, which shows that the influence of effective mass to the mobility anisotropy is larger than that of deformation potential constant and elastic modulus. Parameters were collected for various anisotropic 2D materials (black phosphorus, Hittorf's phosphorus, BC$_2$N, MXene, TiS$_3$, GeCH$_3$) to calculate their mobility anisotropy. It was revealed that the anisotropic ratio was overestimated in the past.

  13. Sums of two-dimensional spectral triples

    DEFF Research Database (Denmark)

    Christensen, Erik; Ivan, Cristina

    2007-01-01

    construct a sum of two dimensional modules which reflects some aspects of the topological dimensions of the compact metric space, but this will only give the metric back approximately. At the end we make an explicit computation of the last module for the unit interval in. The metric is recovered exactly......, the Dixmier trace induces a multiple of the Lebesgue integral but the growth of the number of eigenvalues is different from the one found for the standard differential operator on the unit interval....

  14. Dynamics of film. [two dimensional continua theory

    Science.gov (United States)

    Zak, M.

    1979-01-01

    The general theory of films as two-dimensional continua are elaborated upon. As physical realizations of such a model this paper examines: inextensible films, elastic films, and nets. The suggested dynamic equations have enabled us to find out the characteristic speeds of wave propagation of the invariants of external and internal geometry and formulate the criteria of instability of their shape. Also included herein is a detailed account of the equation describing the film motions beyond the limits of the shape stability accompanied by the formation of wrinkles. The theory is illustrated by examples.

  15. Image encryption using the two-dimensional logistic chaotic map

    Science.gov (United States)

    Wu, Yue; Yang, Gelan; Jin, Huixia; Noonan, Joseph P.

    2012-01-01

    Chaos maps and chaotic systems have been proved to be useful and effective for cryptography. In our study, the two-dimensional logistic map with complicated basin structures and attractors are first used for image encryption. The proposed method adopts the classic framework of the permutation-substitution network in cryptography and thus ensures both confusion and diffusion properties for a secure cipher. The proposed method is able to encrypt an intelligible image into a random-like one from the statistical point of view and the human visual system point of view. Extensive simulation results using test images from the USC-SIPI image database demonstrate the effectiveness and robustness of the proposed method. Security analysis results of using both the conventional and the most recent tests show that the encryption quality of the proposed method reaches or excels the current state-of-the-art methods. Similar encryption ideas can be applied to digital data in other formats (e.g., digital audio and video). We also publish the cipher MATLAB open-source-code under the web page https://sites.google.com/site/tuftsyuewu/source-code.

  16. А heuristic algorithm for two-dimensional strip packing problem

    OpenAIRE

    Dayong, Cao; Kotov, V.M.

    2011-01-01

    In this paper, we construct an improved best-fit heuristic algorithm for two-dimensional rectangular strip packing problem (2D-RSPP), and compare it with some heuristic and metaheuristic algorithms from literatures. The experimental results show that BFBCC could produce satisfied packing layouts than these methods, especially for the large problem of 50 items or more, BFBCC could get better results in shorter time.

  17. Surface Topography of Fine-grained ZrO2 Ceramic by Two-dimensional Ultrasonic Vibration Grinding

    Institute of Scientific and Technical Information of China (English)

    DING Ailing; WU Yan; LIU Yongjiang

    2011-01-01

    The surface quality of fine-grained ZrO2 engineering ceramic were researched using 270# diamond wheel both with and without work-piece two-dimension ultrasonic vibration grinding(WTDUVG).By AFM images,the surface topography and the micro structure of the two-dimensional ultrasonic vibration grinding ceramics were especially analyzed.The experimental results indicate that the surface roughness is related to grinding vibration mode and the material removal mechanism.Surface quality of WTDUVG is superior to that of conventional grinding,and it is easy for two-dimensional ultrasonic vibration grinding that material removal mechanism is ductile mode grinding.

  18. Discrete piezoelectric sensors and actuators for active control of two-dimensional spacecraft components

    Science.gov (United States)

    Bayer, Janice I.; Varadan, V. V.; Varadan, V. K.

    1991-01-01

    This paper describes research into the use of discrete piezoelectric sensors and actuators for active modal control of flexible two-dimensional structures such as might be used as components for spacecraft. A dynamic coupling term is defined between the sensor/actuator and the structure in terms of structural model shapes, location and piezoelectric behavior. The relative size of the coupling term determines sensor/actuator placement. Results are shown for a clamped square plate and for a large antenna. An experiment was performed on a thin foot-square plate clamped on all sides. Sizable vibration control was achieved for first, second/third (degenerate) and fourth modes.

  19. A two-dimensional analytical model of laminar flame in lycopodium dust particles

    Energy Technology Data Exchange (ETDEWEB)

    Rahbari, Alireza [Shahid Rajaee Teacher Training University, Tehran (Iran, Islamic Republic of); Shakibi, Ashkan [Iran University of Science and Technology, Tehran (Iran, Islamic Republic of); Bidabadi, Mehdi [Combustion Research Laboratory, Narmak, Tehran (Iran, Islamic Republic of)

    2015-09-15

    A two-dimensional analytical model is presented to determine the flame speed and temperature distribution of micro-sized lycopodium dust particles. This model is based on the assumptions that the particle burning rate in the flame front is controlled by the process of oxygen diffusion and the flame structure consists of preheat, reaction and post flame zones. In the first step, the energy conservation equations for fuel-lean condition are expressed in two dimensions, and then these differential equations are solved using the required boundary condition and matching the temperature and heat flux at the interfacial boundaries. Consequently, the obtained flame temperature and flame speed distributions in terms of different particle diameters and equivalence ratio for lean mixture are compared with the corresponding experimental data for lycopodium dust particles. Consequently, it is shown that this two-dimensional model demonstrates better agreement with the experimental results compared to the previous models.

  20. Non-classical photon correlation in a two-dimensional photonic lattice

    CERN Document Server

    Gao, Jun; Lin, Xiao-Feng; Jiao, Zhi-Qiang; Feng, Zhen; Zhou, Zheng; Gao, Zhen-Wei; Xu, Xiao-Yun; Chen, Yuan; Tang, Hao; Jin, Xian-Min

    2016-01-01

    Quantum interference and quantum correlation, as two main features of quantum optics, play an essential role in quantum information applications, such as multi-particle quantum walk and boson sampling. While many experimental demonstrations have been done in one-dimensional waveguide arrays, it remains unexplored in higher dimensions due to tight requirement of manipulating and detecting photons in large-scale. Here, we experimentally observe non-classical correlation of two identical photons in a fully coupled two-dimensional structure, i.e. photonic lattice manufactured by three-dimensional femtosecond laser writing. Photon interference consists of 36 Hong-Ou-Mandel interference and 9 bunching. The overlap between measured and simulated distribution is up to $0.890\\pm0.001$. Clear photon correlation is observed in the two-dimensional photonic lattice. Combining with controllably engineered disorder, our results open new perspectives towards large-scale implementation of quantum simulation on integrated phot...