Costanza, E. F.; Costanza, G.
2016-10-01
Continuum partial differential equations are obtained from a set of discrete stochastic evolution equations of both non-Markovian and Markovian processes and applied to the diffusion within the context of the lattice gas model. A procedure allowing to construct one-dimensional lattices that are topologically equivalent to two-dimensional lattices is described in detail in the case of a rectangular lattice. This example shows the general features that possess the procedure and extensions are also suggested in order to provide a wider insight in the present approach.
Lattice gas dynamics: application to driven vortices in two dimensional superconductors.
Gotcheva, Violeta; Wang, Albert T J; Teitel, S
2004-06-18
A continuous time Monte Carlo lattice gas dynamics is developed to model driven steady states of vortices in two dimensional superconducting networks. Dramatic differences are found when compared to a simpler Metropolis dynamics. Subtle finite size effects are found at low temperature, with a moving smectic that becomes unstable to an anisotropic liquid on sufficiently large length scales.
Costanza, E. F.; Costanza, G.
2016-12-01
Continuum partial differential equations are obtained from a set of discrete stochastic evolution equations of both non-Markovian and Markovian processes and applied to the diffusion within the context of the lattice gas model. A procedure allowing to construct one-dimensional lattices that are topologically equivalent to two-dimensional lattices is described in detail in the case of a triangular lattice. This example shows the general features that possess the procedure and extensions are also suggested in order to provide a wider insight in the present approach.
Costanza, E. F.; Costanza, G.
2017-02-01
Continuum partial differential equations are obtained from a set of discrete stochastic evolution equations of both non-Markovian and Markovian processes and applied to the diffusion within the context of the lattice gas model. A procedure allowing to construct one-dimensional lattices that are topologically equivalent to two-dimensional lattices is described in detail in the case of a hexagonal lattice which has the particular feature that need four types of dynamical variables. This example shows additional features to the general procedure and some extensions are also suggested in order to provide a wider insight in the present approach.
Energy Technology Data Exchange (ETDEWEB)
Budantsev, M. V., E-mail: budants@isp.nsc.ru; Lavrov, R. A.; Pogosov, A. G.; Zhdanov, E. Yu.; Pokhabov, D. A. [Russian Academy of Sciences, Rzhanov Institute of Semiconductor Physics, Siberian Branch (Russian Federation)
2011-02-15
Extraordinary piecewise parabolic behavior of the magnetoresistance has been experimentally detected in the two-dimensional electron gas with a dense triangular lattice of antidots, where commensurability magnetoresistance oscillations are suppressed. The magnetic field range of 0-0.6 T can be divided into three wide regions, in each of which the magnetoresistance is described by parabolic dependences with high accuracy (comparable to the experimental accuracy) and the transition regions between adjacent regions are much narrower than the regions themselves. In the region corresponding to the weakest magnetic fields, the parabolic behavior becomes almost linear. The observed behavior is reproducible as the electron gas density changes, which results in a change in the resistance by more than an order of magnitude. Possible physical mechanisms responsible for the observed behavior, including so-called 'memory effects,' are discussed.
Institute of Scientific and Technical Information of China (English)
罗孟波; 陈庆虎; 许祝安; 焦正宽
2001-01-01
The second-order phase transition in the two-dimensional (2D) classical Coulomb gas of half-integer charges on a square lattice is investigated by using Monte Carlo simulations. Based on the finite-size scaling analysis,we estimate the second-order phase transition temperature Tc and the static critical exponents β and v with a new numerical analysis method. More precise critical temperature Tc = 0.1311(2) and critical exponents β/ν = 0.1152(12) and ν = 0.857(15) are obtained. The estimated value of ν indicates that the charge lattice melting transition is different from the pure 2D Ising transition.
Fluctuations in an ordered c (2×2) two-dimensional lattice-gas system with repulsive interactions
Argyrakis, P.; Chumak, A. A.; Maragakis, M.
2005-06-01
Fluctuations of the particle density in an ordered c(2×2) two-dimensional lattice-gas system are studied both analytically and by means of Monte Carlo simulations. The ordering is caused by a strong interparticle repulsive interaction resulting in the second order phase transition. The lattice of adsorption sites is divided into two sublattices (almost filled and almost empty sublattices) each of which contains a small number of structural “defects,” i.e., vacancies and excess particles. The relaxation of the correlation function of fluctuations turns out to be governed by two different functions. This peculiarity is to be contrasted with the traditional fluctuation theory which predicts the existence of a single damping constant, determined by the collective diffusion coefficient. A specific thesis of the proposed approach is that transport phenomena in ordered systems may be described in terms of both displacements and generation-recombination of structural defects. Accordingly, the correlation function of fluctuations depends on diffusion coefficients of two defect species as well as on the generation-recombination frequency. Our theory reduces to the usual one when fluctuations occur under local equilibrium conditions, i.e., for a sufficiently large size of probe areas and not too great values of interaction parameter. The analytical results agree well with those obtained in the Monte Carlo framework.
Two-Dimensional Toda-Heisenberg Lattice
Directory of Open Access Journals (Sweden)
Vadim E. Vekslerchik
2013-06-01
Full Text Available We consider a nonlinear model that is a combination of the anisotropic two-dimensional classical Heisenberg and Toda-like lattices. In the framework of the Hirota direct approach, we present the field equations of this model as a bilinear system, which is closely related to the Ablowitz-Ladik hierarchy, and derive its N-soliton solutions.
Two-dimensional subwavelength plasmonic lattice solitons
Ye, F; Hu, B; Panoiu, N C
2010-01-01
We present a theoretical study of plasmonic lattice solitons (PLSs) formed in two-dimensional (2D) arrays of metallic nanowires embedded into a nonlinear medium with Kerr nonlinearity. We analyze two classes of 2D PLSs families, namely, fundamental and vortical PLSs in both focusing and defocusing media. Their existence, stability, and subwavelength spatial confinement are studied in detai
Two Dimensional Lattice Boltzmann Method for Cavity Flow Simulation
Directory of Open Access Journals (Sweden)
Panjit MUSIK
2004-01-01
Full Text Available This paper presents a simulation of incompressible viscous flow within a two-dimensional square cavity. The objective is to develop a method originated from Lattice Gas (cellular Automata (LGA, which utilises discrete lattice as well as discrete time and can be parallelised easily. Lattice Boltzmann Method (LBM, known as discrete Lattice kinetics which provide an alternative for solving the Navier–Stokes equations and are generally used for fluid simulation, is chosen for the study. A specific two-dimensional nine-velocity square Lattice model (D2Q9 Model is used in the simulation with the velocity at the top of the cavity kept fixed. LBM is an efficient method for reproducing the dynamics of cavity flow and the results which are comparable to those of previous work.
Spatiotemporal surface solitons in two-dimensional photonic lattices.
Mihalache, Dumitru; Mazilu, Dumitru; Lederer, Falk; Kivshar, Yuri S
2007-11-01
We analyze spatiotemporal light localization in truncated two-dimensional photonic lattices and demonstrate the existence of two-dimensional surface light bullets localized in the lattice corners or the edges. We study the families of the spatiotemporal surface solitons and their properties such as bistability and compare them with the modes located deep inside the photonic lattice.
Spatiotemporal dissipative solitons in two-dimensional photonic lattices.
Mihalache, Dumitru; Mazilu, Dumitru; Lederer, Falk; Kivshar, Yuri S
2008-11-01
We analyze spatiotemporal dissipative solitons in two-dimensional photonic lattices in the presence of gain and loss. In the framework of the continuous-discrete cubic-quintic Ginzburg-Landau model, we demonstrate the existence of novel classes of two-dimensional spatiotemporal dissipative lattice solitons, which also include surface solitons located in the corners or at the edges of the truncated two-dimensional photonic lattice. We find the domains of existence and stability of such spatiotemporal dissipative solitons in the relevant parameter space, for both on-site and intersite lattice solitons. We show that the on-site solitons are stable in the whole domain of their existence, whereas most of the intersite solitons are unstable. We describe the scenarios of the instability-induced dynamics of dissipative solitons in two-dimensional lattices.
Two dimensional axisymmetric smooth lattice Ricci flow
Brewin, Leo
2015-01-01
A lattice based method will be presented for numerical investigations of Ricci flow. The method will be applied to the particular case of 2-dimensional axially symmetric initial data on manifolds with S^2 topology. Results will be presented that show that the method works well and agrees with results obtained using contemporary finite difference methods.
Two-dimensional lattice Boltzmann model for magnetohydrodynamics.
Schaffenberger, Werner; Hanslmeier, Arnold
2002-10-01
We present a lattice Boltzmann model for the simulation of two-dimensional magnetohydro dynamic (MHD) flows. The model is an extension of a hydrodynamic lattice Boltzman model with 9 velocities on a square lattice resulting in a model with 17 velocities. Earlier lattice Boltzmann models for two-dimensional MHD used a bidirectional streaming rule. However, the use of such a bidirectional streaming rule is not necessary. In our model, the standard streaming rule is used, allowing smaller viscosities. To control the viscosity and the resistivity independently, a matrix collision operator is used. The model is then applied to the Hartmann flow, giving reasonable results.
Pseudo-two-dimensional random dimer lattices
Energy Technology Data Exchange (ETDEWEB)
Naether, U., E-mail: naether@unizar.es [Instituto de Ciencia de Materiales de Aragón and Departamento de Física de la Materia Condensada, CSIC – Universidad de Zaragoza, 50009 Zaragoza (Spain); Mejía-Cortés, C.; Vicencio, R.A. [Departamento de Física and MSI – Nucleus for Advanced Optics, Center for Optics and Photonics (CEFOP), Facultad de Ciencias, Universidad de Chile, Santiago (Chile)
2015-06-05
We study the long-time wave transport in correlated and uncorrelated disordered 2D arrays. When a separation of dimensions is applied to the model, we find that the previously predicted 1D random dimer phenomenology also appears in so-called pseudo-2D arrays. Therefore, a threshold behavior is observed in terms of the effective size for eigenmodes, as well as in long-time dynamics. A minimum system size is required to observe this threshold, which is very important when considering a possible experimental realization. For the long-time evolution, we find that for correlated lattices a super-diffusive long-range transport is observed. For completely uncorrelated disorder 2D transport becomes sub-diffusive within the localization length and for random binary pseudo-2D arrays localization is observed.
Institute of Scientific and Technical Information of China (English)
XU Quan; TIAN Qiang
2007-01-01
Two-dimensional compact-like discrete breathers in discrete two-dimensional monatomic square lattices are investigated by discussing a generafized discrete two-dimensional monatomic model.It is proven that the twodimensional compact-like discrete breathers exist not only in two-dimensional soft Ф4 potentials but also in hard two-dimensional Ф4 potentials and pure two-dimensional K4 lattices.The measurements of the two-dimensional compact-like discrete breather cores in soft and hard two-dimensional Ф4 potential are determined by coupling parameter K4,while those in pure two-dimensional K4 lattices have no coupling with parameter K4.The stabilities of the two-dimensional compact-like discrete breathers correlate closely to the coupling parameter K4 and the boundary condition of lattices.
Logarithmic divergent thermal conductivity in two-dimensional nonlinear lattices.
Wang, Lei; Hu, Bambi; Li, Baowen
2012-10-01
Heat conduction in three two-dimensional (2D) momentum-conserving nonlinear lattices are numerically calculated via both nonequilibrium heat-bath and equilibrium Green-Kubo algorithms. It is expected by mainstream theories that heat conduction in such 2D lattices is divergent and the thermal conductivity κ increases with lattice length N logarithmically. Our simulations for the purely quartic lattice firmly confirm it. However, very robust finite-size effects are observed in the calculations for the other two lattices, which well explain some existing studies and imply the extreme difficulties in observing their true asymptotic behaviors with affordable computation resources.
Dielectric-barrier discharges in two-dimensional lattice potentials
Sinclair, Josiah
2011-01-01
We use a pin-grid electrode to introduce a corrugated electrical potential into a planar dielectric-barrier discharge (DBD) system, so that the amplitude of the applied electric field has the profile of a two-dimensional square lattice. The lattice potential provides a template for the spatial distribution of plasma filaments in the system and has pronounced effects on the patterns that can form. The positions at which filaments become localized within the lattice unit cell vary with the width of the discharge gap. The patterns that appear when filaments either overfill or under-fill the lattice are reminiscent of those observed in other physical systems involving 2d lattices. We suggest that the connection between lattice-driven DBDs and other areas of physics may benefit from the further development of models that treat plasma filaments as interacting particles.
Institute of Scientific and Technical Information of China (English)
XU Quan; TIAN Qiang
2009-01-01
We restrict our attention to the discrete two-dimensional monatomic β-FPU lattice. We look for twodimensional breather lattice solutions and two-dimensional compact-like discrete breathers by using trying method and analyze their stability by using Aubry's linearly stable theory. We obtain the conditions of existence and stability of two-dimensional breather lattice solutions and two-dimensional compact-like discrete breathers in the discrete twodimensional monatomic β-FPU lattice.
Stress Wave Propagation in Two-dimensional Buckyball Lattice
Xu, Jun; Zheng, Bowen
2016-11-01
Orderly arrayed granular crystals exhibit extraordinary capability to tune stress wave propagation. Granular system of higher dimension renders many more stress wave patterns, showing its great potential for physical and engineering applications. At nanoscale, one-dimensionally arranged buckyball (C60) system has shown the ability to support solitary wave. In this paper, stress wave behaviors of two-dimensional buckyball (C60) lattice are investigated based on square close packing and hexagonal close packing. We show that the square close packed system supports highly directional Nesterenko solitary waves along initially excited chains and hexagonal close packed system tends to distribute the impulse and dissipates impact exponentially. Results of numerical calculations based on a two-dimensional nonlinear spring model are in a good agreement with the results of molecular dynamics simulations. This work enhances the understanding of wave properties and allows manipulations of nanoscale lattice and novel design of shock mitigation and nanoscale energy harvesting devices.
Topological states in two-dimensional hexagon lattice bilayers
Zhang, Ming-Ming; Xu, Lei; Zhang, Jun
2016-10-01
We investigate the topological states of the two-dimensional hexagon lattice bilayer. The system exhibits a quantum valley Hall (QVH) state when the interlayer interaction t⊥ is smaller than the nearest neighbor hopping energy t, and then translates to a trivial band insulator state when t⊥ / t > 1. Interestingly, the system is found to be a single-edge QVH state with t⊥ / t = 1. The topological phase transition also can be presented via changing bias voltage and sublattice potential in the system. The QVH states have different edge modes carrying valley current but no net charge current. The bias voltage and external electric field can be tuned easily in experiments, so the present results will provide potential application in valleytronics based on the two-dimensional hexagon lattice.
Vibrational Properties of a Two-Dimensional Silica Kagome Lattice.
Björkman, Torbjörn; Skakalova, Viera; Kurasch, Simon; Kaiser, Ute; Meyer, Jannik C; Smet, Jurgen H; Krasheninnikov, Arkady V
2016-12-27
Kagome lattices are structures possessing fascinating magnetic and vibrational properties, but in spite of a large body of theoretical work, experimental realizations and investigations of their dynamics are scarce. Using a combination of Raman spectroscopy and density functional theory calculations, we study the vibrational properties of two-dimensional silica (2D-SiO2), which has a kagome lattice structure. We identify the signatures of crystalline and amorphous 2D-SiO2 structures in Raman spectra and show that, at finite temperatures, the stability of 2D-SiO2 lattice is strongly influenced by phonon-phonon interaction. Our results not only provide insights into the vibrational properties of 2D-SiO2 and kagome lattices in general but also suggest a quick nondestructive method to detect 2D-SiO2.
Electronic Transmission Properties of Two-Dimensional Quasi-Lattice
Institute of Scientific and Technical Information of China (English)
侯志林; 傅秀军; 刘有延
2002-01-01
In the framework of the tight binding model, the electronic transmission properties of two-dimensional Penrose lattices with free boundary conditions are studied using the generalized eigenfunction method (Phys. Rev. B 60(1999)13444). The electronic transmission coefficients for Penrose lattices with different sizes and widths are calculated, and the result shows strong energy dependence because of the quasiperiodic structure and quantum coherent effect. Around the Fermi level E = 0, there is an energy region with zero transmission amplitudes,which suggests that the studied systems are insulating. The spatial distributions of several typical electronic states with different transmission coefficients are plotted to display the propagation process.
Quantum computing via defect states in two-dimensional antidot lattices.
Flindt, Christian; Mortensen, Niels Asger; Jauho, Antti-Pekka
2005-12-01
We propose a new structure suitable for quantum computing in a solid-state environment: designed defect states in antidot lattices superimposed on a two-dimensional electron gas at a semiconductor heterostructure. State manipulation can be obtained with gate control. Model calculations indicate that it is feasible to fabricate structures whose energy level structure is robust against thermal dephasing.
Two-dimensional chiral topological superconductivity in Shiba lattices
Li, Jian; Neupert, Titus; Wang, Zhijun; MacDonald, A. H.; Yazdani, A.; Bernevig, B. Andrei
2016-07-01
The chiral p-wave superconductor is the archetypal example of a state of matter that supports non-Abelian anyons, a highly desired type of exotic quasiparticle. With this, it is foundational for the distant goal of building a topological quantum computer. While some candidate materials for bulk chiral superconductors exist, they are subject of an ongoing debate about their actual paring state. Here we propose an alternative route to chiral superconductivity, consisting of the surface of an ordinary superconductor decorated with a two-dimensional lattice of magnetic impurities. We furthermore identify a promising experimental platform to realize this proposal.
The characters of nonlinear vibration in the two-dimensional discrete monoatomic lattice
Institute of Scientific and Technical Information of China (English)
XU Quan; TIAN Qiang
2005-01-01
The two-dimensional discrete monoatomic lattice is analyzed. Taking nearest-neighbor interaction into account, the characters of the nonlinear vibration in two-dimensional discrete monoatomic lattice are described by the two-dimensional cubic nonlinear Schrodinger equation. Considering the quartic nonlinear potential, the two-dimensional discrete-soliton trains and the solutions perturbed by the neck mode are presented.
Many body localization in two dimensional square and triangular lattices
Gonzalez-Garcia, L; Paredes, R
2016-01-01
Ultracold interacting Bose atoms placed in disordered two dimensional optical lattices with square and triangular symmetries are found to be localized above a certain disorder strength amplitude. From a Gross-Pitaevskii mean analysis we determine the localization length as a function of the disorder strength and investigate the energy spectrum in terms of the disorder magnitude. We found that the localization length is observed to decrease faster in triangular geometries than in square ones. In the presence of a harmonic confinement localization is observed at the center of the trap. The analysis of the energy spectrum reveals that discrete energy levels acquire a finite width that is always smaller than the distance among energy levels.
Compact triplexer in two-dimensional hexagonal lattice photonic crystals
Institute of Scientific and Technical Information of China (English)
Hongliang Ren; Jianping Ma; Hao Wen; Yali Qin; Zhefu Wu; Weisheng Hu; Chun Jiang; Yaohui Jin
2011-01-01
We design a contpact triplexer based on two-dimensional (2D) hexagonal lattice photonic crystals (PCs). A folded directional coupler (FDC) is introduced in the triplexer beside the point-defect micro-cavities and line-defect waveguides. Because of the reflection feedback of the FDC, high channel drop efficiency can be realized and a compact size with the order of micrometers can be maintained. The proposed device is analyzed using the plane wave expansion method, and its transmission characteristics are calculated using the finites-difference time-domain method. The footprint of the triplexer is about 12× 9 μm, and its extinction ratios are less than -20 dB for 1310 nm, approximately -20 dB for 1490 nm, and under -4O dB for 1550 nm, making it a potentially essential device ii future fiber-to-the-home networks.%@@ We design a compact triplexer based on two-dimensional (2D) hexagonal lattice photonic crystals (PCs).A folded directional coupler (FDC) is introduced in the triplexer beside the point-defect micro-cavities and line-defect waveguides.Because of the reflection feedback of the FDC, high channel drop efficiency can be realized and a compact size with the order of micrometers can be maintained.The proposed device is analyzed using the plane wave expansion method, and its transmission characteristics are calculated using the finite-difference time-domain method.The footprint of the triplexer is about 12×9 μm, and its extinction ratios are less than -20 dB for 1310 nm, approximately -20 dB for 1490 nm, and under -40 dB for 1550 nm, making it a potentially essential device in future fiber-to-the-home networks.
Two-dimensional discrete gap breathers in a two-dimensional discrete diatomic Klein-Gordon lattice
Institute of Scientific and Technical Information of China (English)
XU Quan; QIANG Tian
2009-01-01
We study the existence and stability of two-dimensional discrete breathers in a two-dimensional discrete diatomic Klein-Gordon lattice consisting of alternating light and heavy atoms, with nearest-neighbor harmonic coupling.Localized solutions to the corresponding nonlinear differential equations with frequencies inside the gap of the linear wave spectrum, i.e. two-dimensional gap breathers, are investigated numerically. The numerical results of the corresponding algebraic equations demonstrate the possibility of the existence of two-dimensional gap breathers with three types of symmetries, i.e., symmetric, twin-antisymmetric and single-antisymmetric. Their stability depends on the nonlinear on-site potential (soft or hard), the interaction potential (attractive or repulsive)and the center of the two-dimensional gap breather (on a light or a heavy atom).
Configurational entropy of a set of dipoles placed on a two-dimensional lattice
Dammig Quiña, P. L.; Irurzun, I. M.; Mola, E. E.
2017-01-01
In the present work we calculate the configurational entropy of an arbitrary number of dipoles placed on a square lattice. We use a quasi-two-dimensional (Q2D) space to capture the main features determining the occupation statistics of this system. We show that our result is in agreement with both, lattice-gas predictions at low coverages and the exact value derived in the close-packed limit as well. Therefore our equation provides a substantial improvement to the most recent calculations based on semiempirical models and Monte Carlo simulations.
Institute of Scientific and Technical Information of China (English)
Xu Quan; Tian Qiang
2009-01-01
This paper discusses the two-dimensional discrete monatomic Fermi-Pasta-Ulam lattice, by using the method of multiple-scale and the quasi-discreteness approach. By taking into account the interaction between the atoms in the lattice and their nearest neighbours, it obtains some classes of two-dimensional local models as follows: two-dimensional bright and dark discrete soliton trains, two-dimensional bright and dark line discrete breathers, and two-dimensional bright and dark discrete breather.
Larkin-Ovchinnikov phases in two-dimensional square lattices
Baarsma, J. E.; Törmä, P.
2016-10-01
We consider a two-component gas of fermions in optical lattices in the presence of a population imbalance within a mean-field theory. We study phase transitions from a normal gas of unpaired fermions to a superfluid phase of Bose-condensed Cooper pairs. The possibility of Cooper pairs with a nonzero centre-of-mass momentum is included, which corresponds to a so-called Fulde-Ferrel-Larkin-Ovchinnikov (FFLO) state. We find that for population-imbalanced systems such states can form the ground state. The FF and LO state are compared and it is shown that actually the LO state is energetically more favourable. We complete the mean-field phase diagram for the LO phase and show that it is qualitatively in excellent agreement with recent diagrammatic Monte Carlo calculations. Subsequently, we calculate the atomic density modulations in the LO phase.
Quantum magnetotransport in a modulated two-dimensional electron gas
Park, Tae-ik; Gumbs, Godfrey
1997-09-01
Quantum mechanical calculations of the magnetotransport coefficients of a modulated two-dimensional electron gas in a perpendicular magnetic field are presented using the Kubo method. The model modulation potential used is such that the effect of the steepness of the potential and its strength on the band part of the longitudinal resistivity ρxxand the Hall resistivity ρxycould be studied. In the extreme limit of a very steep potential, a two-dimensional square array of antidots is simulated. Impurity scattering is included in the self-consistent t-matrix approximation. The results show that for a strong lateral superlattice potential, ρxyis quenched in the low magnetic field regime and as the magnetic field increases there is a large negative Hall resistivity. The intensity of this negative peak is suppressed as the strength of the modulation potential is decreased. It is also shown that the height of the negative peak depends on the steepness of the potential. The longitudinal resistivity also has some interesting features. There are Aharonov-Bohm oscillations and a double peak structure which depends on both the strength of the modulation potential as well as its slope. The numerical results show that the position and intensity of the lower peak is not very sensitive to a change in the strength of the lattice potential or its steepness. However, the upper peak is greatly reduced when the lattice potential is diminished in strength. The double peak feature in ρxxand the negative peak and quenching of the Hall effect at low magnetic fields have been observed experimentally for antidots in both the quasiclassical and quantum regimes.
Decoherence in a Landau Quantized Two Dimensional Electron Gas
Directory of Open Access Journals (Sweden)
McGill Stephen A.
2013-03-01
Full Text Available We have studied the dynamics of a high mobility two-dimensional electron gas as a function of temperature. The presence of satellite reflections in the sample and magnet can be modeled in the time-domain.
Critical phenomena in the majority voter model on two-dimensional regular lattices.
Acuña-Lara, Ana L; Sastre, Francisco; Vargas-Arriola, José Raúl
2014-05-01
In this work we studied the critical behavior of the critical point as a function of the number of nearest neighbors on two-dimensional regular lattices. We performed numerical simulations on triangular, hexagonal, and bilayer square lattices. Using standard finite-size scaling theory we found that all cases fall in the two-dimensional Ising model universality class, but that the critical point value for the bilayer lattice does not follow the regular tendency that the Ising model shows.
Forensic potential of comprehensive two-dimensional gas chromatography
Sampat, A.; Lopatka, M.; Sjerps, M.; Vivo-Truyols, G.; Schoenmakers, P.; van Asten, A.
2016-01-01
In this study, the application of comprehensive two-dimensional (2D) gas chromatography (GC × GC) in forensic science is reviewed. The peer-reviewed publications on the forensic use of GC × GC and 2D gas chromatography with mass spectrometric detection (GC × GC-MS) have been studied in detail, not o
Forensic potential of comprehensive two-dimensional gas chromatography
Sampat, A.; Lopatka, M.; Sjerps, M.; Vivo-Truyols, G.; Schoenmakers, P.; van Asten, A.
2016-01-01
In this study, the application of comprehensive two-dimensional (2D) gas chromatography (GC × GC) in forensic science is reviewed. The peer-reviewed publications on the forensic use of GC × GC and 2D gas chromatography with mass spectrometric detection (GC × GC-MS) have been studied in detail, not o
Two-Dimensional Lattice Gravity as a Spin System
Beirl, W; Riedler, J
1994-01-01
Quantum gravity is studied in the path integral formulation applying the Regge calculus. Restricting the quadratic link lengths of the originally triangular lattice the path integral can be transformed to the partition function of a spin system with higher couplings on a Kagome lattice. Various measures acting as external field are considered. Extensions to matter fields and higher dimensions are discussed.
Thermal diode from two-dimensional asymmetrical Ising lattices.
Wang, Lei; Li, Baowen
2011-06-01
Two-dimensional asymmetrical Ising models consisting of two weakly coupled dissimilar segments, coupled to heat baths with different temperatures at the two ends, are studied by Monte Carlo simulations. The heat rectifying effect, namely asymmetric heat conduction, is clearly observed. The underlying mechanisms are the different temperature dependencies of thermal conductivity κ at two dissimilar segments and the match (mismatch) of flipping frequencies of the interface spins.
Spin dynamics in a two-dimensional quantum gas
DEFF Research Database (Denmark)
Pedersen, Poul Lindholm; Gajdacz, Miroslav; Deuretzbacher, Frank
2014-01-01
We have investigated spin dynamics in a two-dimensional quantum gas. Through spin-changing collisions, two clouds with opposite spin orientations are spontaneously created in a Bose-Einstein condensate. After ballistic expansion, both clouds acquire ring-shaped density distributions with superimp......We have investigated spin dynamics in a two-dimensional quantum gas. Through spin-changing collisions, two clouds with opposite spin orientations are spontaneously created in a Bose-Einstein condensate. After ballistic expansion, both clouds acquire ring-shaped density distributions...
Optical properties of two-dimensional magnetoelectric point scattering lattices
DEFF Research Database (Denmark)
Hansen, Per Lunnemann; Sersic, Ivana; Koenderink, A. Femius
2013-01-01
of split ring resonators and provide a quantitative comparison of measured and calculated transmission spectra at normal incidence as a function of lattice density, showing excellent agreement. We further show angle-dependent transmission calculations for circularly polarized light and compare...
Zero sound in a two-dimensional dipolar Fermi gas
Lu, Z.K.; Matveenko, S.I.; Shlyapnikov, G.V.
2013-01-01
We study zero sound in a weakly interacting two-dimensional (2D) gas of single-component fermionic dipoles (polar molecules or atoms with a large magnetic moment) tilted with respect to the plane of their translational motion. It is shown that the propagation of zero sound is provided by both mean-f
Quantum holographic encoding in a two-dimensional electron gas
Energy Technology Data Exchange (ETDEWEB)
Moon, Christopher
2010-05-26
The advent of bottom-up atomic manipulation heralded a new horizon for attainable information density, as it allowed a bit of information to be represented by a single atom. The discrete spacing between atoms in condensed matter has thus set a rigid limit on the maximum possible information density. While modern technologies are still far from this scale, all theoretical downscaling of devices terminates at this spatial limit. Here, however, we break this barrier with electronic quantum encoding scaled to subatomic densities. We use atomic manipulation to first construct open nanostructures - 'molecular holograms' - which in turn concentrate information into a medium free of lattice constraints: the quantum states of a two-dimensional degenerate Fermi gas of electrons. The information embedded in the holograms is transcoded at even smaller length scales into an atomically uniform area of a copper surface, where it is densely projected into both two spatial degrees of freedom and a third holographic dimension mapped to energy. In analogy to optical volume holography, this requires precise amplitude and phase engineering of electron wavefunctions to assemble pages of information volumetrically. This data is read out by mapping the energy-resolved electron density of states with a scanning tunnelling microscope. As the projection and readout are both extremely near-field, and because we use native quantum states rather than an external beam, we are not limited by lensing or collimation and can create electronically projected objects with features as small as {approx}0.3 nm. These techniques reach unprecedented densities exceeding 20 bits/nm{sup 2} and place tens of bits into a single fermionic state.
Two-dimensional Chern semimetals on the Lieb lattice
Palumbo, Giandomenico; Meichanetzidis, Konstantinos
2015-12-01
In this work we propose a simple model that supports Chern semimetals. These gapless topological phases share several properties with the Chern insulators like a well-defined Chern number associated with each band, topologically protected edge states and topological phase transitions that occur when the bands touch each, with linear dispersion around the contact points. The tight-binding model, defined on the Lieb lattice with intra-unit-cell and suitable nearest-neighbor hopping terms between three different species of spinless fermions, supports a single Dirac-like point. The dispersion relation around this point is fully relativistic and the 3 ×3 matrices in the corresponding effective Hamiltonian satisfy the Duffin-Kemmer-Petiau algebra. We show the robustness of the topologically protected edge states by employing the entanglement spectrum. Moreover, we prove that the Chern number of the lowest band is robust with respect to weak disorder. For its simplicity, our model can be naturally implemented in real physical systems like cold atoms in optical lattices.
Two-dimensional lattice gauge theories with superconducting quantum circuits
Energy Technology Data Exchange (ETDEWEB)
Marcos, D., E-mail: david.marcos@me.com [Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, A-6020 Innsbruck (Austria); Widmer, P. [Albert Einstein Center, Institute for Theoretical Physics, Bern University, CH-3012, Bern (Switzerland); Rico, E. [IPCMS (UMR 7504) and ISIS (UMR 7006), University of Strasbourg and CNRS, 67000 Strasbourg (France); Hafezi, M. [Joint Quantum Institute, NIST/University of Maryland, College Park 20742 (United States); Department of Electrical Engineering and Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, MD 20742 (United States); Rabl, P. [Institute of Atomic and Subatomic Physics, TU Wien, Stadionallee 2, 1020 Wien (Austria); Wiese, U.-J. [Albert Einstein Center, Institute for Theoretical Physics, Bern University, CH-3012, Bern (Switzerland); Zoller, P. [Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, A-6020 Innsbruck (Austria); Institute for Theoretical Physics, University of Innsbruck, A-6020 Innsbruck (Austria)
2014-12-15
A quantum simulator of U(1) lattice gauge theories can be implemented with superconducting circuits. This allows the investigation of confined and deconfined phases in quantum link models, and of valence bond solid and spin liquid phases in quantum dimer models. Fractionalized confining strings and the real-time dynamics of quantum phase transitions are accessible as well. Here we show how state-of-the-art superconducting technology allows us to simulate these phenomena in relatively small circuit lattices. By exploiting the strong non-linear couplings between quantized excitations emerging when superconducting qubits are coupled, we show how to engineer gauge invariant Hamiltonians, including ring-exchange and four-body Ising interactions. We demonstrate that, despite decoherence and disorder effects, minimal circuit instances allow us to investigate properties such as the dynamics of electric flux strings, signaling confinement in gauge invariant field theories. The experimental realization of these models in larger superconducting circuits could address open questions beyond current computational capability.
Negative Dispersion of Lattice Waves in a Two-Dimensional Yukawa System
Institute of Scientific and Technical Information of China (English)
刘艳红; 刘斌; 杨思泽; 王龙
2002-01-01
Collective motion modes existing in a two-dimensional Yukawa system are investigated by molecular dynamics simulation. The dispersion relations of transverse and longitudinal lattice waves obtained for hexagonal lattice are in agreement with the theoretical results. The negative dispersion of the parallel longitudinal wave is demonstrated by the simulation, and is explained by a physical model.
Two-dimensional ion trap lattice on a microchip for quantum simulation
Sterling, R C; Weidt, S; Lake, K; Srinivasan, P; Webster, S C; Kraft, M; Hensinger, W K
2013-01-01
Using a controllable quantum system it is possible to simulate other highly complex quantum systems efficiently overcoming an in-principle limitation of classical computing. Trapped ions constitute such a highly controllable quantum system. So far, no dedicated architectures for the simulation of two-dimensional spin lattices using trapped ions in radio-frequency ion traps have been produced, limiting the possibility of carrying out such quantum simulations on a large scale. We report the operation of a two-dimensional ion trap lattice integrated in a microchip capable of implementing quantum simulations of two-dimensional spin lattices. Our device provides a scalable microfabricated architecture for trapping such ion lattices with coupling strengths between neighbouring ions sufficient to provide a powerful platform for the implementation of quantum simulations. In order to realize this device we developed a specialist fabrication process that allows for the application of very large voltages. We fabricated ...
Quantum search on the two-dimensional lattice using the staggered model with Hamiltonians
Portugal, R.; Fernandes, T. D.
2017-04-01
Quantum search on the two-dimensional lattice with one marked vertex and cyclic boundary conditions is an important problem in the context of quantum algorithms with an interesting unfolding. It avails to test the ability of quantum walk models to provide efficient algorithms from the theoretical side and means to implement quantum walks in laboratories from the practical side. In this paper, we rigorously prove that the recent-proposed staggered quantum walk model provides an efficient quantum search on the two-dimensional lattice, if the reflection operators associated with the graph tessellations are used as Hamiltonians, which is an important theoretical result for validating the staggered model with Hamiltonians. Numerical results show that on the two-dimensional lattice staggered models without Hamiltonians are not as efficient as the one described in this paper and are, in fact, as slow as classical random-walk-based algorithms.
Bloch oscillations and Zener tunneling in two-dimensional photonic lattices.
Trompeter, Henrike; Krolikowski, Wieslaw; Neshev, Dragomir N; Desyatnikov, Anton S; Sukhorukov, Andrey A; Kivshar, Yuri S; Pertsch, Thomas; Peschel, Ulf; Lederer, Falk
2006-02-10
We report on the first experimental observation of photonic Bloch oscillations and Zener tunneling in two-dimensional periodic systems. We study the propagation of an optical beam in a square lattice superimposed on a refractive index ramp. We observe oscillations of the beam inside the first Brilloin zone and tunneling of light from the first to the higher-order bands of the lattice band gap spectrum.
Tensor renormalization group approach to two-dimensional classical lattice models.
Levin, Michael; Nave, Cody P
2007-09-21
We describe a simple real space renormalization group technique for two-dimensional classical lattice models. The approach is similar in spirit to block spin methods, but at the same time it is fundamentally based on the theory of quantum entanglement. In this sense, the technique can be thought of as a classical analogue of the density matrix renormalization group method. We demonstrate the method - which we call the tensor renormalization group method - by computing the magnetization of the triangular lattice Ising model.
Topological phase transitions driven by next-nearest-neighbor hopping in two-dimensional lattices
Beugeling, W.; Everts, J.C.; de Morais Smith, C.
2012-01-01
For two-dimensional lattices in a tight-binding description, the intrinsic spin-orbit coupling, acting as a complex next-nearest-neighbor hopping, opens gaps that exhibit the quantum spin Hall effect. In this paper, we study the effect of a real next-nearest-neighbor hopping term on the band structu
Dipolar fermions in a two-dimensional lattice at non-zero temperature
DEFF Research Database (Denmark)
Larsen, Anne-Louise G.; Bruun, Georg
2012-01-01
We examine density-ordered and superfluid phases of fermionic dipoles in a two-dimensional square lattice at nonzero temperature. The critical temperature of the density-ordered phases is determined and is shown to be proportional to the coupling strength for strong coupling. We calculate...
Lattice Methods for Pricing American Strangles with Two-Dimensional Stochastic Volatility Models
Directory of Open Access Journals (Sweden)
Xuemei Gao
2014-01-01
Full Text Available The aim of this paper is to extend the lattice method proposed by Ritchken and Trevor (1999 for pricing American options with one-dimensional stochastic volatility models to the two-dimensional cases with strangle payoff. This proposed method is compared with the least square Monte-Carlo method via numerical examples.
Hofstadter butterfly evolution in the space of two-dimensional Bravais lattices
Yılmaz, F.; Oktel, M. Ö.
2017-06-01
The self-similar energy spectrum of a particle in a periodic potential under a magnetic field, known as the Hofstadter butterfly, is determined by the lattice geometry as well as the external field. Recent realizations of artificial gauge fields and adjustable optical lattices in cold-atom experiments necessitate the consideration of these self-similar spectra for the most general two-dimensional lattice. In a previous work [F. Yılmaz et al., Phys. Rev. A 91, 063628 (2015), 10.1103/PhysRevA.91.063628], we investigated the evolution of the spectrum for an experimentally realized lattice which was tuned by changing the unit-cell structure but keeping the square Bravais lattice fixed. We now consider all possible Bravais lattices in two dimensions and investigate the structure of the Hofstadter butterfly as the lattice is deformed between lattices with different point-symmetry groups. We model the optical lattice with a sinusoidal real-space potential and obtain the tight-binding model for any lattice geometry by calculating the Wannier functions. We introduce the magnetic field via Peierls substitution and numerically calculate the energy spectrum. The transition between the two most symmetric lattices, i.e., the triangular and the square lattices, displays the importance of bipartite symmetry featuring deformation as well as closing of some of the major energy gaps. The transitions from the square to rectangular lattice and from the triangular to centered rectangular lattices are analyzed in terms of coupling of one-dimensional chains. We calculate the Chern numbers of the major gaps and Chern number transfer between bands during the transitions. We use gap Chern numbers to identify distinct topological regions in the space of Bravais lattices.
Extension of the approximate two-dimensional electron gas formulation
Pierret, R. F.
1985-07-01
The functional two-dimensional electron gas (2DEG) formalism employed in the analysis of modulation-doped field-effect transistors is extended to properly account for the bulk charge and to more accurately model sub- and near-threshold behavior. The implemented changes basically transform the functional formulation from an above-threshold formalism for lightly doped structures to one of additional utility which automatically approaches expected limits under widely divergent conditions. Sample computations of the surface carrier concentration, relevant energy level positionings, and the semiconductor depletion width as a function of surface potential and doping are also presented and examined. These computations exhibit the general utility of the extended theory and provide an indirect evaluation of the standard two-level 2DEG theory.
Polarons and molecules in a two-dimensional Fermi gas
DEFF Research Database (Denmark)
Zöllner, Sascha; Bruun, Georg Morten; Pethick, C. J.
2011-01-01
We study an impurity atom in a two-dimensional Fermi gas using variational wave functions for (i) an impurity dressed by particle-hole excitations (polaron) and (ii) a dimer consisting of the impurity and a majority atom. In contrast to three dimensions, where similar calculations predict a sharp...... transition to a dimer state with increasing interspecies attraction, we show that the polaron Ansatz always gives a lower energy. However, the exact solution for a heavy impurity reveals that both a two-body bound state and distortions of the Fermi sea are crucial. This reflects the importance of particle......-hole pairs in lower dimensions and makes simple variational calculations unreliable. We show that the energy of an impurity gives important information about its dressing cloud, for which both Ansätze give inaccurate results....
Diffusion in the two-dimensional nonoverlapping Lorentz gas
James, Corinne P.; Evans, Glenn T.
1987-10-01
The self-diffusion coefficient, velocity autocorrelation function, and distribution of collision times for a two-dimensional nonoverlapping Lorentz gas were calculated using molecular dynamics simulation. The systems studied covered a range of densities, from a packing fraction (πNr2/L2) of 0.01 to 0.8. Self-diffusion coefficients were found to agree to all densities with kinetic theory predictions [A. Weijland and J. M. J. van Leeuwen, Physica 38, 35 (1968)] if the radial distribution function (rdf) was taken into account. The density dependence of the decay of the velocity autocorrelation function was qualitatively different from that predicted by kinetic theory. The distribution of collision times was nearly exponential for all but the highest density studied.
Two-dimensional Talbot self-imaging via Electromagnetically induced lattice
Wen, Feng; Wang, Wei; Ahmed, Irfan; Wang, Hongxing; Zhang, Yiqi; Zhang, Yanpeng; Mahesar, Abdul Rasheed; Xiao, Min
2017-02-01
We propose a lensless optical method for imaging two-dimensional ultra-cold atoms (or molecules) in which the image can be non-locally observed by coincidence recording of entangled photon pairs. In particular, we focus on the transverse and longitudinal resolutions of images under various scanning methods. In addition, the role of the induced nonmaterial lattice on the image contrast is investigated. Our work shows a non-destructive and lensless way to image ultra-cold atoms or molecules that can be further used for two-dimensional atomic super-resolution optical testing and sub-wavelength lithography.
Tuning of band gaps for a two-dimensional piezoelectric phononic crystal with a rectangular lattice
Institute of Scientific and Technical Information of China (English)
Yize Wang; Fengming Li; Yuesheng Wang; Kikuo Kishimoto; Wenhu Huang
2009-01-01
In this paper, the elastic wave propagation in a two-dimensional piezoelectric phononic crystal is studied by considering the mechanic-electric coupling. The gener-alized eigenvalue equation is obtained by the relation of the mechanic and electric fields as well as the Bloch-Floquet the-orem. The band structures of both the in-plane and anti-plane modes are calculated for a rectangular lattice by the plane-wave expansion method. The effects of the lattice constant ratio and the piezoelectricity with different filling fractions are analyzed. The results show that the largest gap width is not always obtained for a square lattice. In some situations, a rectangular lattice may generate larger gaps. The band gap characteristics are influenced obviously by the piezoelectric-ity with the larger lattice constant ratios and the filling frac-tions.
Institute of Scientific and Technical Information of China (English)
Xu Quan; Tian Qiang
2013-01-01
Using numerical method,we investigate whether periodic,quasiperiodic,and chaotic breathers are supported by the two-dimensional discrete Fermi-Pasta-Ulam (FPU) lattice with linear dispersion term.The spatial profile and time evolution of the two-dimensional discrete β-FPU lattice are segregated by the method of separation of variables,and the numerical simulations suggest that the discrete breathers (DBs) are supported by the system.By introducing a periodic interaction into the linear interaction between the atoms,we achieve the coupling of two incommensurate frequencies for a single DB,and the numerical simulations suggest that the quasiperiodic and chaotic breathers are supported by the system,too.
Non-classical photon correlation in a two-dimensional photonic lattice
Gao, Jun; Lin, Xiao-Feng; Jiao, Zhi-Qiang; Feng, Zhen; Zhou, Zheng; Gao, Zhen-Wei; Xu, Xiao-Yun; Chen, Yuan; Tang, Hao; Jin, Xian-Min
2016-01-01
Quantum interference and quantum correlation, as two main features of quantum optics, play an essential role in quantum information applications, such as multi-particle quantum walk and boson sampling. While many experimental demonstrations have been done in one-dimensional waveguide arrays, it remains unexplored in higher dimensions due to tight requirement of manipulating and detecting photons in large-scale. Here, we experimentally observe non-classical correlation of two identical photons in a fully coupled two-dimensional structure, i.e. photonic lattice manufactured by three-dimensional femtosecond laser writing. Photon interference consists of 36 Hong-Ou-Mandel interference and 9 bunching. The overlap between measured and simulated distribution is up to $0.890\\pm0.001$. Clear photon correlation is observed in the two-dimensional photonic lattice. Combining with controllably engineered disorder, our results open new perspectives towards large-scale implementation of quantum simulation on integrated phot...
Tunable band topology reflected by fractional quantum Hall States in two-dimensional lattices.
Wang, Dong; Liu, Zhao; Cao, Junpeng; Fan, Heng
2013-11-01
Two-dimensional lattice models subjected to an external effective magnetic field can form nontrivial band topologies characterized by nonzero integer band Chern numbers. In this Letter, we investigate such a lattice model originating from the Hofstadter model and demonstrate that the band topology transitions can be realized by simply introducing tunable longer-range hopping. The rich phase diagram of band Chern numbers is obtained for the simple rational flux density and a classification of phases is presented. In the presence of interactions, the existence of fractional quantum Hall states in both |C| = 1 and |C| > 1 bands is confirmed, which can reflect the band topologies in different phases. In contrast, when our model reduces to a one-dimensional lattice, the ground states are crucially different from fractional quantum Hall states. Our results may provide insights into the study of new fractional quantum Hall states and experimental realizations of various topological phases in optical lattices.
Two-Dimensional Photonic Band-Gap Defect Modes with Deformed Lattice
Institute of Scientific and Technical Information of China (English)
CAI Xiang-Hua; ZHENG Wan-Hua; MA Xiao-Tao; REN Gang; XIA Jian-Bai
2005-01-01
@@ A numerical study of the defect modes in two-dimensional photonic crystals with deformed triangular lattice is presented by using the supercell method and the finite-difference time-domain method We find the stretch or shrink of the lattice can bring the change not only on the frequencies of the defect modes but also on their magnetic field distributions. We obtain the separation of the doubly degenerate dipole modes with the change of the lattice and find that both the stretch and the shrink of the lattice can make the dipole modes separate large enough to realize the single-mode emission. These results may be advantageous to the manufacture of photonic crystal lasers and provide a new way to realize the single-mode operation in photonic crystal lasers.
The mean field study of phase transitions in two dimensional Kagome lattice under local anisotropy
Directory of Open Access Journals (Sweden)
S. Mortezapour
2007-06-01
Full Text Available In this work we investigated the critical properties of the anti-ferromagnetic XY model on a two dimensional Kagome lattice under single-ion easy-axes anisotropy. Employing the mean field theory, we found that this model shows a second order phase transition from disordered to all-in all-out state for any value of anisotropy.
Institute of Scientific and Technical Information of China (English)
HOU Jing-Min
2009-01-01
We investigate the energy spectrum of ultracold atoms on the two-dimensional Kagome optical lattice under an effective magnetic field,which can be realized with laser beams.We derive the generalized Harper's equations from the Schr(o)dinger equation.The energy spectrum with a fractal band structure is obtained by numerically solving the generalized Harper's equations.We analyze the properties of the Hofstadter's butterfly spectrum and discuss its observability.
Quantum Monte Carlo simulation of a two-dimensional Majorana lattice model
Hayata, Tomoya; Yamamoto, Arata
2017-07-01
We study interacting Majorana fermions in two dimensions as a low-energy effective model of a vortex lattice in two-dimensional time-reversal-invariant topological superconductors. For that purpose, we implement ab initio quantum Monte Carlo simulation to the Majorana fermion system in which the path-integral measure is given by a semipositive Pfaffian. We discuss spontaneous breaking of time-reversal symmetry at finite temperatures.
Closed-form evaluation of two-dimensional static lattice sums
Yakubovich, S.; Drygas, P.; Mityushev, V.
2016-11-01
Closed-form formulae for the conditionally convergent two-dimensional (2D) static lattice sums S2 (for conductivity) and T2 (for elasticity) are deduced in terms of the complete elliptic integrals of the first and second kind. The obtained formulae yield asymptotic analytical formulae for the effective tensors of 2D composites with circular inclusions up to the third order in concentration. Exact relations between S2 and T2 for different lattices are established. In particular, the value S2=π for the square and hexagonal arrays is discussed and T2=π/2 for the hexagonal is deduced.
Evans, J. W.; Nord, R. S.
1985-02-01
An analytic treatment of competitive, irreversible (immobile) random one-, two-, three-, . . . point adsorption (or monomer, dimer, trimer, . . . filling) on infinite, uniform two-dimensional lattices is provided by applying previously developed truncation schemes to the hierarchial form of the appropriate master equations. The behavior of these processes for two competing species is displayed by plotting families of ``filling trajectories'' in the partial-coverage plane for various ratios of adsorption rates. The time or coverage dependence of various subconfiguration probabilities can also be analyzed. For processes where no one-point (monomer) adsorption occurs, the lattice cannot fill completely; accurate estimates of the total (and partial) saturation coverages can be obtained.
Fundamental and vortex solitons in a two-dimensional optical lattice
Yang, J; Yang, Jianke; Musslimani, Ziad
2003-01-01
Fundamental and vortex solitons in a two-dimensional optically induced waveguide array are reported. In the strong localization regime, the fundamental soliton is largely confined to one lattice site, while the vortex state comprises of four fundamental modes superimposed in a square configuration with a phase structure that is topologically equivalent to the conventional vortex. However, in the weak localization regime, both the fundamental and vortex solitons spread over many lattice sites. We further show that fundamental and vortex solitons are stable against small perturbations in the strong localization regime.
Chremmos, Ioannis; Giamalaki, Melpomeni; Yannopapas, Vassilios; Paspalakis, Emmanuel
2014-01-01
We present a formulation for deriving effective medium properties of infinitely periodic two-dimensional metamaterial lattice structures beyond the static and quasi-static limits. We utilize the multipole expansions, where the polarization currents associated with the supported Bloch modes are expressed via the electric dipole, magnetic dipole, and electric quadrupole moments per unit length. We then propose a method to calculate the Bloch modes based on the lattice geometry and individual unit element structure. The results revert to well-known formulas in the quasistatic limit and are useful for the homogenization of nanorod-type metamaterials which are frequently used in optical applications.
Heteroepitaxial growth modes with dislocations in a two-dimensional elastic lattice model
Katsuno, Hiroyasu; Uwaha, Makio; Saito, Yukio
2008-11-01
We study equilibrium shapes of adsorbate crystals by allowing a possibility of dislocations on an elastic substrate in a two-dimensional lattice model. The ground state energy is calculated numerically with the use of an elastic lattice Green's function. From the equilibrium shapes determined for various coverages, we infer the growth mode. As the misfit parameter increases, the growth mode changes from the Frank-van der Merwe (FM) to the Stranski-Krastanov (SK), further to the FM with dislocations for a parameter range of ordinary semiconductor materials. Conceivable growth modes such as the SK with dislocations appear in a parameter range between the SK and the FM with dislocations.
Boundaries determine the formation energies of lattice defects in two-dimensional buckled materials
Jain, Sandeep K.; Juričić, Vladimir; Barkema, Gerard T.
2016-07-01
Lattice defects are inevitably present in two-dimensional materials, with direct implications on their physical and chemical properties. We show that the formation energy of a lattice defect in buckled two-dimensional crystals is not uniquely defined as it takes different values for different boundary conditions even in the thermodynamic limit, as opposed to their perfectly planar counterparts. Also, the approach to the thermodynamic limit follows a different scaling: inversely proportional to the logarithm of the system size for buckled materials, rather than the usual power-law approach. In graphene samples of ˜1000 atoms, different boundary conditions can cause differences exceeding 10 eV. Besides presenting numerical evidence in simulations, we show that the universal features in this behavior can be understood with simple bead-spring models. Fundamentally, our findings imply that it is necessary to specify the boundary conditions for the energy of the lattice defects in the buckled two-dimensional crystals to be uniquely defined, and this may explain the lack of agreement in the reported values of formation energies in graphene. We argue that boundary conditions may also have an impact on other physical observables such as the melting temperature.
Li, Shuai; Qiu, Wen-Xuan; Gao, Jin-Hua
2016-07-07
Recently, a new kind of artificial two dimensional (2D) electron lattice on the nanoscale, i.e. molecular graphene, has drawn a lot of interest, where the metal surface electrons are transformed into a honeycomb lattice via absorbing a molecular lattice on the metal surface [Gomes et al., Nature, 2012, 438, 306; Wang et al., Phys. Rev. Lett., 2014, 113, 196803]. In this work, we theoretically demonstrate that this technique can be readily used to build other complex 2D electron lattices on a metal surface, which are of high interest in the field of condensed matter physics. The main challenge to build a complex 2D electron lattice is that this is a quantum antidot system, where the absorbed molecule normally exerts a repulsive potential on the surface electrons. Thus, there is no straightforward corresponding relation between the molecular lattice pattern and the desired 2D lattice of surface electrons. Here, we give an interesting example about the Kagome lattice, which has exotic correlated electronic states. We design a special molecular pattern and show that this molecular lattice can transform the surface electrons into a Kagome-like lattice. The numerical simulation is conducted using a Cu(111) surface and CO molecules. We first estimate the effective parameters of the Cu/CO system by fitting experimental data of the molecular graphene. Then, we calculate the corresponding energy bands and LDOS of the surface electrons in the presence of the proposed molecular lattice. Finally, we interpret the numerical results by the tight binding model of the Kagome lattice. We hope that our work can stimulate further theoretical and experimental interest in this novel artificial 2D electron lattice system.
Tie, B.; Tian, B. Y.; Aubry, D.
2013-12-01
The elastic wave propagation phenomena in two-dimensional periodic beam lattices are studied by using the Bloch wave transform. The numerical modeling is applied to the hexagonal and the rectangular beam lattices, in which, both the in-plane (with respect to the lattice plane) and out-of-plane waves are considered. The dispersion relations are obtained by calculating the Bloch eigenfrequencies and eigenmodes. The frequency bandgaps are observed and the influence of the elastic and geometric properties of the primitive cell on the bandgaps is studied. By analyzing the phase and the group velocities of the Bloch wave modes, the anisotropic behaviors and the dispersive characteristics of the hexagonal beam lattice with respect to the wave propagation are highlighted in high frequency domains. One important result presented herein is the comparison between the first Bloch wave modes to the membrane and bending/transverse shear wave modes of the classical equivalent homogenized orthotropic plate model of the hexagonal beam lattice. It is shown that, in low frequency ranges, the homogenized plate model can correctly represent both the in-plane and out-of-plane dynamic behaviors of the beam lattice, its frequency validity domain can be precisely evaluated thanks to the Bloch modal analysis. As another important and original result, we have highlighted the existence of the retropropagating Bloch wave modes with a negative group velocity, and of the corresponding "retro-propagating" frequency bands.
Quantum State Transfer in a Two-dimensional Regular Spin Lattice of Triangular Shape
Miki, Hiroshi; Vinet, Luc; Zhedanov, Alexei
2012-01-01
Quantum state transfer in a triangular domain of a two-dimensional, equally-spaced, spin lat- tice with non-homogeneous nearest-neighbor couplings is analyzed. An exact solution of the one- excitation dynamics is provided in terms of 2-variable Krawtchouk orthogonal polynomials that have been recently defined. The probability amplitude for an excitation to transit from one site to another is given. For some values of the parameters, perfect transfer is shown to take place from the apex of the lattice to the boundary hypotenuse.
Peng-Jen Chen; Horng-Tay Jeng
2016-01-01
A new semiconducting phase of two-dimensional phosphorous in the Kagome lattice is proposed from first-principles calculations. The band gaps of the monolayer (ML) and bulk Kagome phosphorous (Kagome-P) are 2.00 and 1.11 eV, respectively. The magnitude of the band gap is tunable by applying the in-plane strain and/or changing the number of stacking layers. High optical absorption coefficients at the visible light region are predicted for multilayer Kagome-P, indicating potential applications ...
Hamiltonian dynamics of the two-dimensional lattice {phi}{sup 4} model
Energy Technology Data Exchange (ETDEWEB)
Caiani, Lando [Scuola Internazionale Superiore di Studi Avanzati (SISSA/ISAS), Trieste (Italy); Casetti, Lapo [Istituto Nazionale di Fisica della Materia (INFM), Unita di Ricerca del Politecnico di Torino, Dipartimento di Fisica, Politecnico di Torino, Turin (Italy); Pettini, Marco [Osservatorio Astrofisico di Arcetri, Florence (Italy)
1998-04-17
The Hamiltonian dynamics of the classical {phi}{sup 4} model on a two-dimensional square lattice is investigated by means of numerical simulations. The macroscopic observables are computed as time averages. The results clearly reveal the presence of the continuous phase transition at a finite energy density and are consistent both qualitatively and quantitatively with the predictions of equilibrium statistical mechanics. The Hamiltonian microscopic dynamics also exhibits critical slowing down close to the transition. Moreover, the relationship between chaos and the phase transition is considered, and interpreted in the light of a geometrization of dynamics. (author)
Restoration of supersymmetry in two-dimensional SYM with sixteen supercharges on the lattice
Giguère, Eric
2015-01-01
We perform lattice simulations of two-dimensional supersymmetric Yang-Mills theory with sixteen supercharges with a lattice action which has two exact supercharges (Sugino lattice action). According to the gauge/gravity duality, the theory at finite temperature is expected to be well described by the corresponding black 1-branes, at low temperature in the large N limit. We aim to confirm the duality conjecture by comparing the lattice results with the theoretical predictions obtained in the gravity side. In this article, at the beginning of this study, we examine the supersymmetric Ward-Takahashi identity to test whether the lattice action reproduces the correct continuum theory. Numerical results of the SUSY WTI strongly suggest us that any cut-off effects, which break supersymmetry, disappear in the continuum limit. In addition, we study the issue of degenerate vacua and find that the admissiblilty condition or any other constraints of the link fields which guarantee the unique vacuum are not always needed.
Restoration of supersymmetry in two-dimensional SYM with sixteen supercharges on the lattice
Energy Technology Data Exchange (ETDEWEB)
Giguère, Eric [Department of Physics, University of Hokkaido,Sapporo, Hokkaido 060-0810 (Japan); Kadoh, Daisuke [KEK Theory Center, High Energy Accelerator Research Organization (KEK),Tsukuba, Ibaraki 305-0801 (Japan)
2015-05-18
We perform lattice simulations of two-dimensional supersymmetric Yang-Mills theory with sixteen supercharges with a lattice action which has two exact supercharges (Sugino lattice action). According to the gauge/gravity duality, the theory at finite temperature is expected to be well described by the corresponding black 1-branes, at low temperature in the large N limit. We aim to confirm the duality conjecture by comparing the lattice results with the theoretical predictions obtained in the gravity side. In this article, at the beginning of this study, we examine the supersymmetric Ward-Takahashi identity to test whether the lattice action reproduces the correct continuum theory. Numerical results of the SUSY WTI strongly suggest us that any cut-off effects, which break supersymmetry, disappear in the continuum limit. In addition, we study the issue of degenerate vacua and find that the admissiblilty condition or any other constraints of the link fields which guarantee the unique vacuum are not always needed.
Hydration of an apolar solute in a two-dimensional waterlike lattice fluid.
Buzano, C; De Stefanis, E; Pretti, M
2005-05-01
In a previous work, we investigated a two-dimensional lattice-fluid model, displaying some waterlike thermodynamic anomalies. The model, defined on a triangular lattice, is now extended to aqueous solutions with apolar species. Water molecules are of the "Mercedes Benz" type, i.e., they possess a D3 (equilateral triangle) symmetry, with three equivalent bonding arms. Bond formation depends both on orientation and local density. The insertion of inert molecules displays typical signatures of hydrophobic hydration: large positive transfer free energy, large negative transfer entropy (at low temperature), strong temperature dependence of the transfer enthalpy and entropy, i.e., large (positive) transfer heat capacity. Model properties are derived by a generalized first order approximation on a triangle cluster.
Entanglement entropy for a Maxwell field: Numerical calculation on a two dimensional lattice
Casini, Horacio
2014-01-01
We study entanglement entropy (EE) for a Maxwell field in 2+1 dimensions. We do numerical calculations in two dimensional lattices. This gives a concrete example of the general results of our recent work on entropy for lattice gauge fields using an algebraic approach. To evaluate the entropies we extend the standard calculation methods for the entropy of Gaussian states in canonical commutation algebras to the more general case of algebras with center and arbitrary numerical commutators. We find that while the entropy depends on the details of the algebra choice, mutual information has a well defined continuum limit. We study several universal terms for the entropy of the Maxwell field and compare with the case of a massless scalar field. We find some interesting new phenomena: An "evanescent" logarithmically divergent term in the entropy with topological coefficient which does not have any correspondence with ultraviolet entanglement in the universal quantities, and a non standard way in which strong subaddi...
Competitive irreversible random one-, two-, three-,. point adsorption on two-dimensional lattices
Energy Technology Data Exchange (ETDEWEB)
Evans, J.W.; Nord, R.S.
1985-02-15
An analytic treatment of competitive, irreversible (immobile) random one-, two-, three-, . . . point adsorption (or monomer, dimer, trimer, . . . filling) on infinite, uniform two-dimensional lattices is provided by applying previously developed truncation schemes to the hierarchial form of the appropriate master equations. The behavior of these processes for two competing species is displayed by plotting families of ''filling trajectories'' in the partial-coverage plane for various ratios of adsorption rates. The time or coverage dependence of various subconfiguration probabilities can also be analyzed. For processes where no one-point (monomer) adsorption occurs, the lattice cannot fill completely; accurate estimates of the total (and partial) saturation coverages can be obtained.
Spin superconductivity in the frustrated two-dimensional antiferromagnet in the square lattice
Lima, L. S.
2017-02-01
We use the SU(2) Schwinger boson formalism to study the spin transport in the two-dimensional S = 1 / 2 frustrated Heisenberg antiferromagnet in a square lattice, considering the second-neighbors interactions in the diagonal. We have obtained a spin superfluid behavior for the spin transport to this system similar to obtained recently to the triangular lattice. We consider an antiferromagnetic inter-chain coupling on the diagonal, J2 > 0 , and the nearest-neighbor coupling antiferromagnetic J1 > 0 . We also have in the critical temperature T0, where the correlation length ξ → 0 , that the system suffers a transition from an ordered ground state to a disordered ground state.
Vector meson masses in two-dimensional SU(NC) lattice gauge theory with massive quarks
Institute of Scientific and Technical Information of China (English)
JIANG Jun-Qin
2008-01-01
Using an improved lattice Hamiltonian with massive Wilson quarks a variational method is applied to study the dependence of the vector meson mass Mv on the quark mass m and the Wilson parameter r in in the scaling window 1 ≤ 1/g2 ≤ 2, Mv/g is approximately linear in m, but Mv/g obviously does not depend on r (this differs from the quark condensate). Particularly for m → 0 our numerical results agree very well with Bhattacharya's analytical strong coupling result in the continuum, and the value of ((e)Mv/(e)m) |mm=0 in two-dimensional SU(NC) lattice gauge theory is very close to that in Schwinger model.
Two-dimensional-lattice spin models with long-range antiferromagnetic interactions
Romano, S.
1991-10-01
We consider a classical system, consisting of m-component unit vectors (m=2,3), associated with a two-dimensional lattice \\{uk||k∈openZ2\\} and interacting via translationally and rotationally invariant antiferromagnetic pair potentials of the long-range form W=Wjk=ɛ||xj-xk||-puj.uk, p>2, where ɛ is a positive quantity, setting energy and temperature scales (i.e., T*=kBT/ɛ), and xk are the coordinates of the lattice sites. A spin-wave approach predicts orientational disorder (in the thermodynamic limit) at all finite temperatures and for all p>2 this agrees with available rigorous results for p>=4, whereas no such theorems are known in the literature when 22.
Michel, K. H.; ćakır, D.; Sevik, C.; Peeters, F. M.
2017-03-01
The elastic constant C11 and piezoelectric stress constant e1 ,11 of two-dimensional (2D) dielectric materials comprising h-BN, 2 H -MoS2 , and other transition-metal dichalcogenides and dioxides are calculated using lattice dynamical theory. The results are compared with corresponding quantities obtained with ab initio calculations. We identify the difference between clamped-ion and relaxed-ion contributions with the dependence on inner strains which are due to the relative displacements of the ions in the unit cell. Lattice dynamics allows us to express the inner-strain contributions in terms of microscopic quantities such as effective ionic charges and optoacoustical couplings, which allows us to clarify differences in the piezoelectric behavior between h-BN and MoS2. Trends in the different microscopic quantities as functions of atomic composition are discussed.
Conical wave propagation and diffraction in two-dimensional hexagonally packed granular lattices.
Chong, C; Kevrekidis, P G; Ablowitz, M J; Ma, Yi-Ping
2016-01-01
Linear and nonlinear mechanisms for conical wave propagation in two-dimensional lattices are explored in the realm of phononic crystals. As a prototypical example, a statically compressed granular lattice of spherical particles arranged in a hexagonal packing configuration is analyzed. Upon identifying the dispersion relation of the underlying linear problem, the resulting diffraction properties are considered. Analysis both via a heuristic argument for the linear propagation of a wave packet and via asymptotic analysis leading to the derivation of a Dirac system suggests the occurrence of conical diffraction. This analysis is valid for strong precompression, i.e., near the linear regime. For weak precompression, conical wave propagation is still possible, but the resulting expanding circular wave front is of a nonoscillatory nature, resulting from the complex interplay among the discreteness, nonlinearity, and geometry of the packing. The transition between these two types of propagation is explored.
Montgomery, R. C.; Sundararajan, N.
1984-01-01
The basic theory of least square lattice filters and their use in identification of structural dynamics systems is summarized. Thereafter, this theory is applied to a two-dimensional grid structure made of overlapping bars. Previously, this theory has been applied to an integral beam. System identification results are presented for both simulated and experimental tests and they are compared with those predicted using finite element modelling. The lattice filtering approach works well for simulated data based on finite element modelling. However, considerable discrepancy exists between estimates obtained from experimental data and the finite element analysis. It is believed that this discrepancy is the result of inadequacies in the finite element modelling to represent the damped motion of the laboratory apparatus.
Chen, Yi-Chung; Yossifon, Gilad; Yang, Ya-Tang
2016-11-01
Photothermal convection has been a major obstacle for stable particle trapping in plasmonic optical tweezer at high optical power. Here, we demonstrate a strategy to suppress the plasmonic photothermal convection by using vanishingly small thermal expansion coefficient of water at low temperature. A simple square nanoplasmonic array is illuminated with a loosely Gaussian beam to produce a two dimensional optical lattice for trapping of micro particles. We observe stable particle trapping due to near-field optical gradient forces at elevated optical power at low temperature. In contrast, for the same optical power at room temperature, the particles are convected away from the center of the optical lattice without their accumulation. This technique will greatly increase usable optical power and enhance the trapping capability of plasmonic optical tweezer.
An improvement of the lattice theory of dislocation for a two-dimensional triangular crystal
Institute of Scientific and Technical Information of China (English)
Wang Shao-Feng
2005-01-01
The structure of dislocation in a two-dimensional triangular crystal has been studied theoretically on the basis of atomic interaction and lattice statics. The theory presented in this paper is an improvement to that published previously.Within a reasonable interaction approximation, a new dislocation equation is obtained, which remedies a fault existing in the lattice theory of dislocation. A better simplification of non-diagonal terms of the kernel is given. The solution of the new dislocation equation asymptotically becomes the same as that obtained in the elastic theory, and agrees with experimental data. It is found that the solution is formally identical with that proposed phenomenologically by Foreman et al, where the parameter can be chosen freely, but cannot uniquely determined from theory. Indeed, if the parameter in the expression of the solution is selected suitably, the expression can be well applied to describe the fine structure of the dislocation.
Dual geometric worm algorithm for two-dimensional discrete classical lattice models
Hitchcock, Peter; Sørensen, Erik S.; Alet, Fabien
2004-07-01
We present a dual geometrical worm algorithm for two-dimensional Ising models. The existence of such dual algorithms was first pointed out by Prokof’ev and Svistunov [N. Prokof’ev and B. Svistunov, Phys. Rev. Lett. 87, 160601 (2001)]. The algorithm is defined on the dual lattice and is formulated in terms of bond variables and can therefore be generalized to other two-dimensional models that can be formulated in terms of bond variables. We also discuss two related algorithms formulated on the direct lattice, applicable in any dimension. These latter algorithms turn out to be less efficient but of considerable intrinsic interest. We show how such algorithms quite generally can be “directed” by minimizing the probability for the worms to erase themselves. Explicit proofs of detailed balance are given for all the algorithms. In terms of computational efficiency the dual geometrical worm algorithm is comparable to well known cluster algorithms such as the Swendsen-Wang and Wolff algorithms, however, it is quite different in structure and allows for a very simple and efficient implementation. The dual algorithm also allows for a very elegant way of calculating the domain wall free energy.
Long-range ferrimagnetic order in a two-dimensional supramolecular Kondo lattice
Girovsky, Jan; Nowakowski, Jan; Ali, Md. Ehesan; Baljozovic, Milos; Rossmann, Harald R.; Nijs, Thomas; Aeby, Elise A.; Nowakowska, Sylwia; Siewert, Dorota; Srivastava, Gitika; Wäckerlin, Christian; Dreiser, Jan; Decurtins, Silvio; Liu, Shi-Xia; Oppeneer, Peter M.; Jung, Thomas A.; Ballav, Nirmalya
2017-05-01
Realization of long-range magnetic order in surface-supported two-dimensional systems has been challenging, mainly due to the competition between fundamental magnetic interactions as the short-range Kondo effect and spin-stabilizing magnetic exchange interactions. Spin-bearing molecules on conducting substrates represent a rich platform to investigate the interplay of these fundamental magnetic interactions. Here we demonstrate the direct observation of long-range ferrimagnetic order emerging in a two-dimensional supramolecular Kondo lattice. The lattice consists of paramagnetic hexadeca-fluorinated iron phthalocyanine (FeFPc) and manganese phthalocyanine (MnPc) molecules co-assembled into a checkerboard pattern on single-crystalline Au(111) substrates. Remarkably, the remanent magnetic moments are oriented in the out-of-plane direction with significant contribution from orbital moments. First-principles calculations reveal that the FeFPc-MnPc antiferromagnetic nearest-neighbour coupling is mediated by the Ruderman-Kittel-Kasuya-Yosida exchange interaction via the Au substrate electronic states. Our findings suggest the use of molecular frameworks to engineer novel low-dimensional magnetically ordered materials and their application in molecular quantum devices.
Long-range ferrimagnetic order in a two-dimensional supramolecular Kondo lattice.
Girovsky, Jan; Nowakowski, Jan; Ali, Md Ehesan; Baljozovic, Milos; Rossmann, Harald R; Nijs, Thomas; Aeby, Elise A; Nowakowska, Sylwia; Siewert, Dorota; Srivastava, Gitika; Wäckerlin, Christian; Dreiser, Jan; Decurtins, Silvio; Liu, Shi-Xia; Oppeneer, Peter M; Jung, Thomas A; Ballav, Nirmalya
2017-05-22
Realization of long-range magnetic order in surface-supported two-dimensional systems has been challenging, mainly due to the competition between fundamental magnetic interactions as the short-range Kondo effect and spin-stabilizing magnetic exchange interactions. Spin-bearing molecules on conducting substrates represent a rich platform to investigate the interplay of these fundamental magnetic interactions. Here we demonstrate the direct observation of long-range ferrimagnetic order emerging in a two-dimensional supramolecular Kondo lattice. The lattice consists of paramagnetic hexadeca-fluorinated iron phthalocyanine (FeFPc) and manganese phthalocyanine (MnPc) molecules co-assembled into a checkerboard pattern on single-crystalline Au(111) substrates. Remarkably, the remanent magnetic moments are oriented in the out-of-plane direction with significant contribution from orbital moments. First-principles calculations reveal that the FeFPc-MnPc antiferromagnetic nearest-neighbour coupling is mediated by the Ruderman-Kittel-Kasuya-Yosida exchange interaction via the Au substrate electronic states. Our findings suggest the use of molecular frameworks to engineer novel low-dimensional magnetically ordered materials and their application in molecular quantum devices.
Chern, Li Ern; Hwang, Kyusung; Mizoguchi, Tomonari; Huh, Yejin; Kim, Yong Baek
2017-07-01
The Kagome-lattice-based material, volborthite, Cu3V2O7(OH) 2.2 H2O , has been considered as a promising platform for discovery of unusual quantum ground states due to the frustrated nature of spin interaction. We explore possible quantum spin liquid and magnetically ordered phases in a two-dimensional nonsymmorphic lattice, which is described by the plane group p 2 g g , consistent with the spatial anisotropy of the spin model derived from density functional theory (DFT) for volborthite. Using the projective symmetry group (PSG) analysis and Schwinger boson mean field theory, we classify possible spin liquid phases with bosonic spinons and investigate magnetically ordered phases connected to such states. It is shown, in general, that only translationally invariant mean field spin liquid ansatzes are allowed in two-dimensional nonsymmorphic lattices. We study the mean field phase diagram of the DFT-derived spin model and find that possible quantum spin liquid phases are connected to two types of magnetically ordered phases, a coplanar incommensurate (q ,0 ) spiral order as the ground state and a closely competing coplanar commensurate (π ,π ) spin density wave order. In addition, periodicity enhancement of the two-spinon continuum, a consequence of symmetry fractionalization, is found in the spin liquid state connected to the (π ,π ) spin density wave order. We discuss relevance of these results to recent and future experiments on volborthite.
Dipolar matter-wave solitons in two-dimensional anisotropic discrete lattices
Chen, Huaiyu; Liu, Yan; Zhang, Qiang; Shi, Yuhan; Pang, Wei; Li, Yongyao
2016-05-01
We numerically demonstrate two-dimensional (2D) matter-wave solitons in the disk-shaped dipolar Bose-Einstein condensates (BECs) trapped in strongly anisotropic optical lattices (OLs) in a disk's plane. The considered OLs are square lattices which can be formed by interfering two pairs of plane waves with different intensities. The hopping rates of the condensates between two adjacent lattices in the orthogonal directions are different, which gives rise to a linearly anisotropic system. We find that when the polarized orientation of the dipoles is parallel to disk's plane with the same direction, the combined effects of the linearly anisotropy and the nonlocal nonlinear anisotropy strongly influence the formations, as well as the dynamics of the lattice solitons. Particularly, the isotropy-pattern solitons (IPSs) are found when these combined effects reach a balance. Motion, collision, and rotation of the IPSs are also studied in detail by means of systematic simulations. We further find that these IPSs can move freely in the 2D anisotropic discrete system, hence giving rise to an anisotropic effective mass. Four types of collisions between the IPSs are identified. By rotating an external magnetic field up to a critical angular velocity, the IPSs can still remain localized and play as a breather. Finally, the influences from the combined effects between the linear and the nonlocal nonlinear anisotropy with consideration of the contact and/or local nonlinearity are discussed too.
Bandgaps and directional properties of two-dimensional square beam-like zigzag lattices
Energy Technology Data Exchange (ETDEWEB)
Wang, Yan-Feng; Wang, Yue-Sheng, E-mail: yswang@bjtu.edu.cn [Institute of Engineering Mechanics, Beijing Jiaotong University, Beijing 100044 (China); Zhang, Chuanzeng [Department of Civil Engineering, University of Siegen, Siegen 57068 (Germany)
2014-12-15
In this paper we propose four kinds of two-dimensional square beam-like zigzag lattice structures and study their bandgaps and directional propagation of elastic waves. The band structures are calculated by using the finite element method. Both the in-plane and out-of-plane waves are investigated simultaneously via the three-dimensional Euler beam elements. The mechanism of the bandgap generation is analyzed by studying the vibration modes at the bandgap edges. The effects of the geometry parameters of the xy- and z-zigzag lattices on the bandgaps are investigated and discussed. Multiple complete bandgaps are found owing to the separation of the degeneracy by introducing bending arms. The bandgaps are sensitive to the geometry parameters of the periodic systems. The deformed displacement fields of the harmonic responses of a finite lattice structure subjected to harmonic loads at different positions are illustrated to show the directional wave propagation. An extension of the proposed concept to the hexagonal lattices is also presented. The research work in this paper is relevant to the practical design of cellular structures with enhanced vibro-acoustics performance.
Schäpers, Th.; Guzenko, V.A.; Müller, R.P.; Golubov, A.A.; Brinkman, A.; Crecelius, G.; Kaluza, A.; Lüth, H.
2003-01-01
We study the suppression of the critical current in a multi-terminal superconductor/two-dimensional electron gas/superconductor Josephson junction by means of hot carrier injection. As a superconductor Nb is used, while the two-dimensional electron gas is located in a strained InGaAs/InP heterostruc
Magnetic properties of two dimensional silicon carbide triangular nanoflakes-based kagome lattices
Energy Technology Data Exchange (ETDEWEB)
Li Xiaowei [Peking University, Center for Applied Physics and Technology, College of Engineering (China); Zhou Jian [Peking University, Department of Materials Science and Engineering (China); Wang Qian, E-mail: qianwang2@pku.edu.cn [Peking University, Center for Applied Physics and Technology, College of Engineering (China); Jena, Puru [Virginia Commonwealth University, Department of Physics (United States)
2012-08-15
Two-dimensional (2D) magnetic kagome lattices are constructed using silicon carbide triangular nanoflakes (SiC-TNFs). Two types of structures with alternating Si and C atoms are studied: the first one is constructed using the C-edged SiC-TNFs as the building blocks and C atoms as the linkers of kagome sites (TNF{sub N}-C-TNF{sub N}) while the second one is composed of the Si-edged SiC-TNFs with Si atoms as linkers (TNF{sub N}-Si-TNF{sub N}). Using density functional theory-based calculations, we show that the fully relaxed TNF{sub N}-C-TNF{sub N} retains the morphology of regular kagome lattice and is ferromagnetism. On the other hand, the TNF{sub N}-Si-TNF{sub N} structure is deformed and antiferromagnetic. However, the ground state of TNF{sub N}-Si-TNF{sub N} structure can be transformed from the antiferromagnetic to ferromagnetic state by applying tensile strain. Monte Carlo simulations indicate that the SiC-TNFs-based kagome lattices can be ferromagnetic at room temperature.
Realization and Characterization of a Curved Two-dimensional Electron Gas
Shaji, Nakul; Deneke, Christoph
2005-03-01
Using the built-in strain from lattice mismatch between Al0.33Ga0.67As and In0.2Ga0.8As as a bending force, a strip of two-dimensional electron gas (2DEG) in an AlxGa1-xAs/GaAs/AlxGa1-xAs heterostructure is curved into a tube when released from the substrate by wet etching. A variety of mesoscopic quantum devices can be defined in such curved 2DEG structures. This technology opens the door for investigating geometry-dependent electron transport under non-uniform magnetic fields. We have defined Hall bar patterns from a sheet of 2DEG using both optical and electron-beam lithography. The sample characterization under an external magnetic field will be discussed.
Two-dimensional gas of massless Dirac fermions in graphene.
Novoselov, K S; Geim, A K; Morozov, S V; Jiang, D; Katsnelson, M I; Grigorieva, I V; Dubonos, S V; Firsov, A A
2005-11-10
Quantum electrodynamics (resulting from the merger of quantum mechanics and relativity theory) has provided a clear understanding of phenomena ranging from particle physics to cosmology and from astrophysics to quantum chemistry. The ideas underlying quantum electrodynamics also influence the theory of condensed matter, but quantum relativistic effects are usually minute in the known experimental systems that can be described accurately by the non-relativistic Schrödinger equation. Here we report an experimental study of a condensed-matter system (graphene, a single atomic layer of carbon) in which electron transport is essentially governed by Dirac's (relativistic) equation. The charge carriers in graphene mimic relativistic particles with zero rest mass and have an effective 'speed of light' c* approximately 10(6) m s(-1). Our study reveals a variety of unusual phenomena that are characteristic of two-dimensional Dirac fermions. In particular we have observed the following: first, graphene's conductivity never falls below a minimum value corresponding to the quantum unit of conductance, even when concentrations of charge carriers tend to zero; second, the integer quantum Hall effect in graphene is anomalous in that it occurs at half-integer filling factors; and third, the cyclotron mass m(c) of massless carriers in graphene is described by E = m(c)c*2. This two-dimensional system is not only interesting in itself but also allows access to the subtle and rich physics of quantum electrodynamics in a bench-top experiment.
Dai, Jian; Song, Xing-Chang
2001-07-01
One of the key ingredients of Connes's noncommutative geometry is a generalized Dirac operator which induces a metric (Connes's distance) on the pure state space. We generalize such a Dirac operator devised by Dimakis et al, whose Connes distance recovers the linear distance on an one-dimensional lattice, to the two-dimensional case. This Dirac operator has the local eigenvalue property and induces a Euclidean distance on this two-dimensional lattice, which is referred to as `natural'. This kind of Dirac operator can be easily generalized into any higher-dimensional lattices.
Diaz-Valencia, B. F.; Calero, J. M.
2017-02-01
In this work, we use the plane wave expansion method to calculate photonic band structures in two-dimensional photonic crystals which consist of high-temperature superconducting hollow rods arranged in a triangular lattice. The variation of the photonic band structure with respect to both, the inner radius and the system temperature, is studied, taking into account temperatures below the critical temperature of the superconductor in the low frequencies regime and assuming E polarization of the incident light. Permittivity contrast and nontrivial geometry of the hollow rods lead to the appearance of new band gaps as compared with the case of solid cylinders. Such band gaps can be modulated by means of the inner radius and system temperature.
Two-dimensional novel optical lattices with multi-well traps for cold atoms or molecules
Institute of Scientific and Technical Information of China (English)
Junfa Lu; Xianming Ji; Jianping Yin
2006-01-01
We propose some new schemes to constitute two-dimensional (2D) array of multi-well optical dipole traps for cold atoms (or molecules) by using an optical system consisting of a binary π-phase grating and a 2D array of rectangle microlens. We calculate the intensity distribution of each optical well in 2D array of multi-well traps and its geometric parameters and so on. The proposed 2D array of multi-well traps can be used to form novel 2D optical lattices with cold atoms (or molecules), and form various novel optical crystals with cold atoms (or molecules), or to perform quantum computing and quantum information processing on an atom chip, even to realize an array of all-optical multi-well atomic (or molecular) BoseEinstein condensates (BECs) on an all-optical integrated atom (or molecule) chip.
Batrouni, George
2011-03-01
I will discuss pairing in fermionic systems in one- and two-dimensional optical lattices with population imbalance. This will be done in the context of the attractive fermionic Hubbard model using the Stochastic Green Function algorithm in d=1 while for d=2 we use Determinant Quantum Monte Carlo. This is the first exact QMC study examining the effects of finite temperature which is very important in experiments on ultra-cold atoms. Our results show that, in the ground state, the dominant pairing mechanism is at nonzero center of mass momentum, i.e. FFLO. I will then discuss the effect of finite temperature in the uniform and confined systems and present finite temperature phase diagrams. The numerical results will be compared with experiments. With M. J. Wolak (CQT, National University of Singapore) and V. G. Rousseau (Department of Physics and Astronomy, Louisiana State University).
Duality and Fisher zeros in the two-dimensional Potts model on a square lattice.
Astorino, Marco; Canfora, Fabrizio
2010-05-01
A phenomenological approach to the ferromagnetic two-dimensional (2D) Potts model on square lattice is proposed. Our goal is to present a simple functional form that obeys the known properties possessed by the free energy of the q-state Potts model. The duality symmetry of the 2D Potts model together with the known results on its critical exponent α allows us to fix consistently the details of the proposed expression for the free energy. The agreement of the analytic ansatz with numerical data in the q=3 case is very good at high and low temperatures as well as at the critical point. It is shown that the q>4 cases naturally fit into the same scheme and that one should also expect a good agreement with numerical data. The limiting q=4 case is shortly discussed.
Nonlinear localized modes in dipolar Bose–Einstein condensates in two-dimensional optical lattices
Energy Technology Data Exchange (ETDEWEB)
Rojas-Rojas, Santiago, E-mail: srojas@cefop.cl [Center for Optics and Photonics and MSI-Nucleus on Advanced Optics, Universidad de Concepción, Casilla 160-C, Concepción (Chile); Departamento de Física, Universidad de Concepción, Casilla 160-C, Concepción (Chile); Naether, Uta [Instituto de Ciencia de Materiales de Aragón and Departamento de Física de la Materia Condensada, CSIC-Universidad de Zaragoza, 50009 Zaragoza (Spain); Delgado, Aldo [Center for Optics and Photonics and MSI-Nucleus on Advanced Optics, Universidad de Concepción, Casilla 160-C, Concepción (Chile); Departamento de Física, Universidad de Concepción, Casilla 160-C, Concepción (Chile); Vicencio, Rodrigo A. [Center for Optics and Photonics and MSI-Nucleus on Advanced Optics, Universidad de Concepción, Casilla 160-C, Concepción (Chile); Departamento de Física, Facultad de Ciencias, Universidad de Chile, Santiago (Chile)
2016-09-16
Highlights: • We study discrete two-dimensional breathers in dipolar Bose–Einstein Condensates. • Important differences in the properties of three fundamental modes are found. • Norm threshold for existence of 2D breathers varies with dipolar interaction. • The Effective Potential Method is implemented for stability analysis. • Uncommon mobility of 2D discrete solitons is observed. - Abstract: We analyze the existence and properties of discrete localized excitations in a Bose–Einstein condensate loaded into a periodic two-dimensional optical lattice, when a dipolar interaction between atoms is present. The dependence of the Number of Atoms (Norm) on the energy of solutions is studied, along with their stability. Two important features of the system are shown, namely, the absence of the Norm threshold required for localized solutions to exist in finite 2D systems, and the existence of regions in the parameter space where two fundamental solutions are simultaneously unstable. This feature enables mobility of localized solutions, which is an uncommon feature in 2D discrete nonlinear systems. With attractive dipolar interaction, a non-trivial behavior of the Norm dependence is obtained, which is well described by an analytical model.
Creating tuneable microwave media from a two-dimensional lattice of re-entrant posts
Goryachev, Maxim; Tobar, Michael E.
2015-11-01
The potential capabilities of resonators based on two dimensional arrays of re-entrant posts is demonstrated. Such posts may be regarded as magnetically coupled lumped element microwave harmonic oscillators, arranged in a 2D lattices structure, which is enclosed in a 3D cavity. By arranging these elements in certain 2D patterns, we demonstrate how to achieve certain requirements with respect to field localisation and device spectra. Special attention is paid to symmetries of the lattices, mechanical tuning, design of areas of high localisation of magnetic energy; this in turn creates unique discrete mode spectra. We demonstrate analogies between systems designed on the proposed platform and well known physical phenomena such as polarisation, frustration, and Whispering Gallery Modes. The mechanical tunability of the cavity with multiple posts is analysed, and its consequences to optomechanical applications is calculated. One particular application to quantum memory is demonstrated with a cavity design consisting of separate resonators analogous to discrete Fabry-Pérot resonators. Finally, we propose a generalised approach to a microwave system design based on the concept of Programmable Cavity Arrays.
Ground State and Collective Modes of Magnetic Dipoles Fixed on Two-Dimensional Lattice Sites
Feldmann, John; Kalman, Gabor; Hartmann, Peter; Rosenberg, Marlene
2006-10-01
In complex (dusty) plasmas the grains may be endowed with intrinsic dipole moments. We present here our results of theoretical calculations accompanied by and Molecular Dynamics simulation findings on the ground state configuration and on the collective modes mode spectrum of a system of magnetic dipoles, interacting via the magnetic dipole pair-dipole potential, fixed on two-dimensional (2D) lattice sites. In particular, we We study a family of lattices that can be characterized by two parameters: (parallelogram)---the aspect ratio, c/a, and the rhombic angle, phi. The The new collective modes of in the system associated with the dipole-dipole interaction are the angular oscillations (or wobbling) of the direction of the dipoles about their equilibrium configurations. We identify in-plane and out-of-plane modes and display their dispersions. Orders of magnitudes of the parameters of the system relevant to possible future experiments will be discussed. JD Feldmann, G J Kalman and M Rosenberg, J. Phys. A: Math. Gen. 39 (2006) 4549-4553
Creating tuneable microwave media from a two-dimensional lattice of re-entrant posts
Energy Technology Data Exchange (ETDEWEB)
Goryachev, Maxim; Tobar, Michael E. [ARC Centre of Excellence for Engineered Quantum Systems, University of Western Australia, 35 Stirling Highway, Crawley, Western Australia 6009 (Australia)
2015-11-28
The potential capabilities of resonators based on two dimensional arrays of re-entrant posts is demonstrated. Such posts may be regarded as magnetically coupled lumped element microwave harmonic oscillators, arranged in a 2D lattices structure, which is enclosed in a 3D cavity. By arranging these elements in certain 2D patterns, we demonstrate how to achieve certain requirements with respect to field localisation and device spectra. Special attention is paid to symmetries of the lattices, mechanical tuning, design of areas of high localisation of magnetic energy; this in turn creates unique discrete mode spectra. We demonstrate analogies between systems designed on the proposed platform and well known physical phenomena such as polarisation, frustration, and Whispering Gallery Modes. The mechanical tunability of the cavity with multiple posts is analysed, and its consequences to optomechanical applications is calculated. One particular application to quantum memory is demonstrated with a cavity design consisting of separate resonators analogous to discrete Fabry–Pérot resonators. Finally, we propose a generalised approach to a microwave system design based on the concept of Programmable Cavity Arrays.
Robustness and breakup of the spiral wave in a two-dimensional lattice network of neurons
Institute of Scientific and Technical Information of China (English)
无
2010-01-01
The robustness and breakup of spiral wave in a two-dimensional lattice networks of neurons are investigated. The effect of small- world type connection is often simplified with local regular connection and the long-range connection with certain probability. The network effect on the development of spiral wave can be better described by local regular connection and changeable long-range connection probability than fixed long-range connection probability because the long-range probability could be changeable in realistic biological system. The effect from the changeable probability for long-range connection is simplified by multiplicative noise. At first, a stable rotating spiral wave is developed by using appropriate initial values, parameters and no-flux boundary conditions, and then the effect of networks is investigated. Extensive numerical studies show that spiral wave keeps its alive and robust when the intensity of multiplicative noise is below a certain threshold, otherwise, the breakup of spiral wave occurs. A statistical factor of synchronization in two-dimensional array is defined to study the phase transition of spiral wave by checking the membrane potentials of all neurons corresponding to the critical parameters(the intensity of noise or forcing current)in the curve for factor of synchronization. The Hindmarsh-Rose model is investigated, the Hodgkin-Huxley neuron model in the presence of the channel noise is also studied to check the model independence of our conclusions. And it is found that breakup of spiral wave is easier to be induced by the multiplicative noise in presence of channel noise.
Institute of Scientific and Technical Information of China (English)
XU Quan; TIAN Qiang; LUO Jun
2009-01-01
@@ We study a two-dimensional lattice of anharmonic oscillators with only quartic nearest-neighbor interactions, in which discrete breathers can be explicitly constructed by an exact separation of their time and space dependence. DBs can stably exist in the two-dimensional Klein-Gordon lattice with hard on-site potential. When a parametric driving term is introduced in the factor multiplying the harmonic part of the on-site potential of the system, we can obtain the stable quasiperiodic discrete breathers and chaotic discrete breathers by changing the amplitude of the driver.
Theory of a Nearly Two-Dimensional Dipolar Bose Gas
2016-05-11
optical data storage, and quantum computing. Today , BECs can be made with a variety of atomic species, including Chromium (Cr) [8] and the rare-earth...out many of these experiments. However, the experi- ments involved atoms that possess negligible dipole moments (like the alkali atoms ). Today , there...gases of bosonic atoms at ultracold, but finite temperatures. Under these circumstances, the gas can undergo a phase transition to a purely quantum
Dipolar quantum electrodynamics of the two-dimensional electron gas
Todorov, Yanko
2015-03-01
Similarly to a previous work on the homogeneous electron gas [Y. Todorov, Phys. Rev. B 89, 075115 (2014), 10.1103/PhysRevB.89.075115], we apply the Power-Zienau-Wooley (PZW) formulation of the quantum electrodynamics to the case of an electron gas quantum confined by one-dimensional potential. We provide a microscopic description of all collective plasmon modes of the gas, oscillating both along and perpendicular to the direction of quantum confinement. Furthermore, we study the interaction of the collective modes with a photonic structure, planar metallic waveguide, by using the full expansion of the electromagnetic field into normal modes. We show how the boundary conditions for the electromagnetic field influence both the transverse light-matter coupling and the longitudinal particle-particle interactions. The PZW descriptions appear thus as a convenient tool to study semiconductor quantum optics in geometries where quantum-confined particles interact with strongly confined electromagnetic fields in microresonators, such as the ones used to achieve the ultrastrong light-matter coupling regime.
Kumar, Manish
2016-01-01
We propose a simple and straightforward method to generate a spatially variant lattice structures by optical interference lithography method. Using this method, it is possible to independently vary the orientation and period of the two-dimensional lattice. The method consists of two steps which are: numerical synthesis of corresponding phase mask by employing a two-dimensional integrated gradient calculations and experimental implementation of synthesized phase mask by making use of a phase only spatial light modulator in an optical 4f Fourier filtering setup. As a working example, we provide the experimental fabrication of a spatially variant square lattice structure which has the possibility to guide a Gaussian beam through a 90{\\deg} bend by photonic crystal self-collimation phenomena. The method is digitally reconfigurable, is completely scalable and could be extended to other kind of lattices as well.
Energy Technology Data Exchange (ETDEWEB)
Kumar, Manish, E-mail: manishk@physics.iitd.ac.in; Joseph, Joby, E-mail: joby@physics.iitd.ac.in [Photonics Research Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India)
2014-08-04
We propose a simple and straightforward method to generate spatially variant lattice structures by optical interference lithography method. Using this method, it is possible to independently vary the orientation and period of the two-dimensional lattice. The method consists of two steps which are: numerical synthesis of corresponding phase mask by employing a two-dimensional integrated gradient calculations and experimental implementation of synthesized phase mask by making use of a phase only spatial light modulator in an optical 4f Fourier filtering setup. As a working example, we provide the experimental fabrication of a spatially variant square lattice structure which has the possibility to guide a Gaussian beam through a 90° bend by photonic crystal self-collimation phenomena. The method is digitally reconfigurable, is completely scalable, and could be extended to other kind of lattices as well.
Zhao, Sheng-Dong; Wang, Yue-Sheng
2016-05-01
The negative refraction behavior and imaging effect for acoustic waves in a kind of two-dimensional square chiral lattice structure are studied in this paper. The unit cell of the proposed structure consists of four zigzag arms connected through a thin circular ring at the central part. The relation of the symmetry of the unit cell and the negative refraction phenomenon is investigated. Using the finite element method, we calculate the band structures and the equi-frequency surfaces of the system, and confirm the frequency range where the negative refraction is present. Due to the rotational symmetry of the unit cell, a phase difference is induced to the waves propagating from a point source through the structure to the other side. The phase difference is related to the width of the structure and the frequency of the source, so we can get a tunable deviated imaging. This kind of phenomenon is also demonstrated by the numerical simulation of two Gaussian beams that are symmetrical about the interface normal with the same incident angle, and the different negative refractive indexes are presented. Based on this special performance, a double-functional mirror-symmetrical slab is proposed for realizing acoustic focusing and beam separation.
The sequence d(CGGCGGCCGC) self-assembles into a two dimensional rhombic DNA lattice
Energy Technology Data Exchange (ETDEWEB)
Venkadesh, S.; Mandal, P.K. [CAS in Crystallography and Biophysics, University of Madras, Chennai 600 025 (India); Gautham, N., E-mail: n_gautham@hotmail.com [CAS in Crystallography and Biophysics, University of Madras, Chennai 600 025 (India)
2011-04-15
Highlights: {yields} This is the first crystal structure of a four-way junction with sticky ends. {yields} Four junction structures bind to each other and form a rhombic cavity. {yields} Each rhombus binds to others to form 'infinite' 2D tiles. {yields} This is an example of bottom-up fabrication of a DNA nano-lattice. -- Abstract: We report here the crystal structure of the partially self-complementary decameric sequence d(CGGCGGCCGC), which self assembles to form a four-way junction with sticky ends. Each junction binds to four others through Watson-Crick base pairing at the sticky ends to form a rhombic structure. The rhombuses bind to each other and form two dimensional tiles. The tiles stack to form the crystal. The crystal diffracted in the space group P1 to a resolution of 2.5 A. The junction has the anti-parallel stacked-X conformation like other junction structures, though the formation of the rhombic net noticeably alters the details of the junction geometry.
Chen, Peng-Jen; Jeng, Horng-Tay
2016-03-16
A new semiconducting phase of two-dimensional phosphorous in the Kagome lattice is proposed from first-principles calculations. The band gaps of the monolayer (ML) and bulk Kagome phosphorous (Kagome-P) are 2.00 and 1.11 eV, respectively. The magnitude of the band gap is tunable by applying the in-plane strain and/or changing the number of stacking layers. High optical absorption coefficients at the visible light region are predicted for multilayer Kagome-P, indicating potential applications for solar cell devices. The nearly dispersionless top valence band of the ML Kagome-P with high density of states at the Fermi level leads to superconductivity with Tc of ~9 K under the optimal hole doping concentration. We also propose that the Kagome-P can be fabricated through the manipulation of the substrate-induced strain during the process of the sample growth. Our work demonstrates the high applicability of the Kagome-P in the fields of electronics, photovoltaics, and superconductivity.
Non-equilibrium relaxation in a two-dimensional stochastic lattice Lotka-Volterra model
Chen, Sheng; Täuber, Uwe C.
We employ Monte Carlo simulations to study a stochastic Lotka-Volterra model on a two-dimensional square lattice with periodic boundary conditions. There are stable states when the predators and prey coexist. If the local prey carrying capacity is finite, there emerges an extinction threshold for the predator population at a critical value of the predation rate. We investigate the non-equilibrium relaxation of the predator density in the vicinity of this critical point. The expected power law dependence between the relaxation time and predation rate is observed (critical slowing down). The numerically determined associated critical exponents are in accord with the directed percolation universality class. Following a sudden predation rate change to its critical value, one observes critical aging for the predator density autocorrelation function with a universal scaling exponent. This aging scaling signature of the absorbing state phase transition emerges at significantly earlier times than stationary critical power laws, and could thus serve as an advanced indicator of the population's proximity to its extinction threshold. This research is supported by the U. S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Science and Engineering under Award DE-FG02-09ER46613.
Screening phase transitions in two-dimensional Coulomb gas
Energy Technology Data Exchange (ETDEWEB)
Gallavotti, G.; Nicolo, F.
1984-07-01
Infrared properties of a Coulomb gas in two dimensions and with fixed ultraviolet cutoff are studied. The existence of infinitely many thresholds Tu = 1/Ke 1/8 pi (1-1/zu)sup-1 in the interval of temperatures 1/Ke1/8 pi, 1/4 pi, where K is the Boltzmann constant and e = /e/ is the charge of the positive particle, is proved. Such thresholds are conjectured to reflect a sequence of transitions from a pure multipole phase (the Koesterlitz-Thouless region) to the plasma phase via an infinite number of intermediate phases. Mathematically the free energy becomes more and more differentiable as a function of the activity lambda, near lambda = 0, as the temperature decreases.
Ferroelectric control of two dimensional electron gas in oxide heterointerface
Thanh, Tra Vu; Chen, Jhih-Wei; Yeh, Chao-Hui; Chen, Yi-Chun; Wu, Chung-Lin; Lin, Jiunn Yuan; Chu, Ying-Hao
2012-02-01
Oxide heterointerfaces are emerging as one of the most exciting materials systems in condensed-matter science. One remarkable example is the LaAlO3 /SrTiO3 (LAO/STO) interface, a model system in which a highly mobile electron gas forms between two band insulators. Our study to manipulate the conductivity at this interface by using ferroeletricity of Pb(Zr,Ti)O3. Our transport data strongly suggests that down polarization direction depletes the conducting interface of LAO/STO. After switching the polarization direction (up), it becomes accumulation. In addition, our experiments show there is obvious the band structure changed by cross-sectional scanning tunneling microscopy and combining with X-ray photoelectron spectroscopy (XPS) measurements. The transport properties are measured to build up the connection between macroscopic properties and local electronic structures that have been applied to study this structure. Controlling the conductivity of this oxide interface suggests that this technique may not only extend more generally to other oxide systems but also open much potential to ferroelectric field effect transistors.
Boschker, Jos E.; Momand, Jamo; Bragaglia, Valeria; Wang, Ruining; Perumal, Karthick; Giussani, Alessandro; Kooi, Bart J.; Riechert, Henning; Calarco, Raffaella
2014-01-01
Sb2Te3 films are used for studying the epitaxial registry between two-dimensionally bonded (2D) materials and three-dimensional bonded (3D) substrates. In contrast to the growth of 3D materials, it is found that the formation of coincidence lattices between Sb2Te3 and Si(111) depends on the geometry
Fabrication of deep-profile Al-doped ZnO one- and two-dimensional lattices as plasmonic elements
DEFF Research Database (Denmark)
Jensen, Flemming; Shkondin, Evgeniy; Takayama, Osamu
2016-01-01
In this work, we report on fabrication of deep-profile one- and two-dimensional lattices made from Al-doped ZnO (AZO). AZO is considered as an alternative plasmonic material having the real part of the permittivity negative in the near infrared range. The exact position of the plasma frequency...
Photonic band structures of two-dimensional photonic crystals with deformed lattices
Institute of Scientific and Technical Information of China (English)
Cai Xiang-Hua; Zheng Wan-Hua; Ma Xiao-Tao; Ren Gang; Xia Jian-Bai
2005-01-01
Using the plane-wave expansion method, we have calculated and analysed the changes of photonic band structures arising from two kinds of deformed lattices, including the stretching and shrinking of lattices. The square lattice with square air holes and the triangular lattice with circular air holes are both studied. Calculated results show that the change of lattice size in some special ranges can enlarge the band gap, which depends strongly on the filling factor of air holes in photonic crystals; and besides, the asymmetric band edges will appear with the broken symmetry of lattices.
Directory of Open Access Journals (Sweden)
O. Ye. Hentosh
2016-01-01
Full Text Available The possibility of applying the method of reducing upon finite-dimensional invariant subspaces, generated by the eigenvalues of the associated spectral problem, to some two-dimensional generalization of the relativistic Toda lattice with the triple matrix Lax type linearization is investigated. The Hamiltonian property and Lax-Liouville integrability of the vector fields, given by this system, on the invariant subspace related with the Bargmann type reduction are found out.
Institute of Scientific and Technical Information of China (English)
无
2010-01-01
Absolute band gaps of a two-dimensional triangular-lattice photonic crystal are calculated with the finite-difference time-domain method in this paper.Through calculating the photonic band structures of the triangular-lattice photonic crystal consisting of Ge rods immersed in air with different shapes,it is found that a large absolute band gap of 0.098 (2c/a) can be obtained for the structures with hollow triangular Ge rods immersed in air,corresponding to 19.8% of the middle frequency.The influence of the different factors on the width of the absolute band gaps is also discussed.
Direct Measurement of the Band Structure of a Buried Two-Dimensional Electron Gas
DEFF Research Database (Denmark)
Miwa, Jill; Hofmann, Philip; Simmons, Michelle Y.;
2013-01-01
We directly measure the band structure of a buried two dimensional electron gas (2DEG) using angle resolved photoemission spectroscopy. The buried 2DEG forms 2 nm beneath the surface of p-type silicon, because of a dense delta-type layer of phosphorus n-type dopants which have been placed there. ...
Schapers, T; Nitta, J; Heersche, HB; Takayanagi, H
2002-01-01
The spin dependent conductance of a ferromagnet/two-dimensional electron gas ferromagnet structure is theoretically examined in the ballistic transport regime. It is shown that the spin signal can be improved considerably by making use of the spin filtering effect of a barrier at the ferromagnet two
Tunable secondary dimension selectivity in comprehensive two-dimensional gas chromatography
J. Mommers; G. Pluimakers; J. Knooren; T. Dutriez; S. van der Wal
2013-01-01
In this paper two tunable two-dimensional gas chromatography setups are compared and described in which the secondary dimension consists of two different capillary columns coupled in series. In the first setup the selectivity of the second dimension can be tuned by adjusting the effective column len
Collective modes of a quasi-two-dimensional Bose condensate in large gas parameter regime
Indian Academy of Sciences (India)
S R Mishra; S P Ram; Arup Banerjee
2007-06-01
We have theoretically studied the collective modes of a quasi-two-dimensional (Q2D) Bose condensate in the large gas parameter regime by using a formalism which treats the interaction energy beyond the mean-field approximation. The results show that incorporation of this higher order term leads to significant modifications in the mode frequencies.
Korytar, P.; Haglund, P.; Boer, de J.; Brinkman, U.A.Th.
2006-01-01
We explain the principles of comprehensive two-dimensional gas chromatography (GC × GC), and discuss key instrumental aspects - with emphasis on column combinations and mass spectrometric detection. As the main item of interest, we review the potential of GC × GC for the analysis of organohalogenate
Spin and charge transport in a gated two dimensional electron gas
Lerescu, Alexandru Ionut
2007-01-01
The work presented in this thesis is centered around the idea of how one can inject, transport and detect the electron's spin in a two dimensional electron gas (a semiconductor heterostructure). Metal based spintronic devices have been established to be the easy way to implement spintronic concepts
Model of two-dimensional electron gas formation at ferroelectric interfaces
Energy Technology Data Exchange (ETDEWEB)
Aguado-Puente, P.; Bristowe, N. C.; Yin, B.; Shirasawa, R.; Ghosez, Philippe; Littlewood, P. B.; Artacho, Emilio
2015-07-01
The formation of a two-dimensional electron gas at oxide interfaces as a consequence of polar discontinuities has generated an enormous amount of activity due to the variety of interesting effects it gives rise to. Here, we study under what circumstances similar processes can also take place underneath ferroelectric thin films. We use a simple Landau model to demonstrate that in the absence of extrinsic screening mechanisms, a monodomain phase can be stabilized in ferroelectric films by means of an electronic reconstruction. Unlike in the LaAlO3/SrTiO3 heterostructure, the emergence with thickness of the free charge at the interface is discontinuous. This prediction is confirmed by performing first-principles simulations of free-standing slabs of PbTiO3. The model is also used to predict the response of the system to an applied electric field, demonstrating that the two-dimensional electron gas can be switched on and off discontinuously and in a nonvolatile fashion. Furthermore, the reversal of the polarization can be used to switch between a two-dimensional electron gas and a two-dimensional hole gas, which should, in principle, have very different transport properties. We discuss the possible formation of polarization domains and how such configuration competes with the spontaneous accumulation of free charge at the interfaces.
Korytar, P.; Haglund, P.; Boer, de J.; Brinkman, U.A.Th.
2006-01-01
We explain the principles of comprehensive two-dimensional gas chromatography (GC × GC), and discuss key instrumental aspects - with emphasis on column combinations and mass spectrometric detection. As the main item of interest, we review the potential of GC × GC for the analysis of organohalogenate
Coherent electron focusing with quantum point contacts in a two-dimensional electron gas
Houten, H. van; Beenakker, C.W.J.; Williamson, J.G.; Broekaart, M.E.I.; Loosdrecht, P.H.M. van; Wees, B.J. van; Mooij, J.E.; Foxon, C.T.; Harris, J.J.
1989-01-01
Transverse electron focusing in a two-dimensional electron gas is investigated experimentally and theoretically for the first time. A split Schottky gate on top of a GaAs-AlxGa1–xAs heterostructure defines two point contacts of variable width, which are used as injector and collector of ballistic el
Quantitative analysis of target components by comprehensive two-dimensional gas chromatography
Mispelaar, V.G. van; Tas, A.C.; Smilde, A.K.; Schoenmakers, P.J.; Asten, A.C. van
2003-01-01
Quantitative analysis using comprehensive two-dimensional (2D) gas chromatography (GC) is still rarely reported. This is largely due to a lack of suitable software. The objective of the present study is to generate quantitative results from a large GC x GC data set, consisting of 32 chromatograms. I
A Robust Thermal Modulator for Comprehensive Two-Dimensional Gas Chromatography
Geus, de H.J.; Boer, de J.
1999-01-01
In comprehensive two dimensional gas chromatography (GCxGC), two capillary columns are connected in series through an interface known as a 'thermal modulator'. This device transforms effluent from the first capillary column into a series of sharp injection-like chemical pulses suitable for high-spee
Spin-polarized transport in a two-dimensional electron gas with interdigital-ferromagnetic contacts
DEFF Research Database (Denmark)
Hu, C.-M.; Nitta, Junsaku; Jensen, Ane
2001-01-01
Ferromagnetic contacts on a high-mobility, two-dimensional electron gas (2DEG) in a narrow gap semiconductor with strong spin-orbit interaction are used to investigate spin-polarized electron transport. We demonstrate the use of magnetized contacts to preferentially inject and detect specific spin...
Thermodynamics of Two-Dimensional Electron Gas in a Magnetic Field
Directory of Open Access Journals (Sweden)
V. I. Nizhankovskii
2011-01-01
Full Text Available Change of the chemical potential of electrons in a GaAs-AlGa1−As heterojunction was measured in magnetic fields up to 6.5 T at several temperatures from 2.17 to 12.3 K. A thermodynamic equation of state of two-dimensional electron gas well describes the experimental results.
Universal relations for the two-dimensional spin-1/2 Fermi gas with contact interactions
DEFF Research Database (Denmark)
Valiente, Manuel; Zinner, Nikolaj Thomas; Mølmer, Klaus
2011-01-01
We present universal relations for a two-dimensional Fermi gas with pairwise contact interactions. The derivation of these relations is made possible by obtaining the explicit form of a generalized function—selector—in the momentum representation. The selector implements the short-distance bounda...
Pixel-based analysis of comprehensive two-dimensional gas chromatograms (color plots) of petroleum
DEFF Research Database (Denmark)
Furbo, Søren; Hansen, Asger B.; Skov, Thomas;
2014-01-01
We demonstrate how to process comprehensive two-dimensional gas chromatograms (GC × GC chromatograms) to remove nonsample information (artifacts), including background and retention time shifts. We also demonstrate how this, combined with further reduction of the influence of irrelevant informati...
Dispersion of guided modes in two-dimensional split ring lattices
Lunnemann, Per
2014-01-01
We present a semi-analytical point-dipole method that uses Ewald lattice summation to find the dispersion relation of guided plasmonic and bianisotropic modes in metasurfaces composed of 2D periodic lattices of arbitrarily strongly scattering magneto-electric dipole scatterers. This method takes into account all retarded electrodynamic interactions as well as radiation damping selfconsistently. As illustration we analyze the dispersion of plasmon nanorod lattices, and of 2D split ring resonator lattices. Plasmon nanorod lattices support transverse and longitudinal in-plane electric modes. Scatterers that have an in-plane electric and out-of-plane magnetic polarizability, but without intrinsic magnetoelectric coupling, result in two bands that are mixtures of the bands of electric-only and magnetic-only lattices. Thereby bianisotropy through mutual coupling, in absence of building-block bianisotropy, is evident. Once strong bi-anisotropy is included in each building block, the Bloch modes become even more stro...
Peto, Myron; Sen, Taner Z.; Jernigan, Robert L.; Kloczkowski, Andrzej
2007-07-01
We enumerated all compact conformations within simple geometries on the two-dimensional (2D) triangular and three-dimensional (3D) face centered cubic (fcc) lattice. These compact conformations correspond mathematically to Hamiltonian paths and Hamiltonian circuits and are frequently used as simple models of proteins. The shapes that were studied for the 2D triangular lattice included m ×n parallelograms, regular equilateral triangles, and various hexagons. On the 3D fcc lattice we generated conformations for a limited class of skewed parallelepipeds. Symmetries of the shape were exploited to reduce the number of conformations. We compared surface to volume ratios against protein length for compact conformations on the 3D cubic lattice and for a selected set of real proteins. We also show preliminary work in extending the transfer matrix method, previously developed by us for the 2D square and the 3D cubic lattices, to the 2D triangular lattice. The transfer matrix method offers a superior way of generating all conformations within a given geometry on a lattice by completely avoiding attrition and reducing this highly complicated geometrical problem to a simple algebraic problem of matrix multiplication.
Peto, Myron; Sen, Taner Z; Jernigan, Robert L; Kloczkowski, Andrzej
2007-07-28
We enumerated all compact conformations within simple geometries on the two-dimensional (2D) triangular and three-dimensional (3D) face centered cubic (fcc) lattice. These compact conformations correspond mathematically to Hamiltonian paths and Hamiltonian circuits and are frequently used as simple models of proteins. The shapes that were studied for the 2D triangular lattice included mxn parallelograms, regular equilateral triangles, and various hexagons. On the 3D fcc lattice we generated conformations for a limited class of skewed parallelepipeds. Symmetries of the shape were exploited to reduce the number of conformations. We compared surface to volume ratios against protein length for compact conformations on the 3D cubic lattice and for a selected set of real proteins. We also show preliminary work in extending the transfer matrix method, previously developed by us for the 2D square and the 3D cubic lattices, to the 2D triangular lattice. The transfer matrix method offers a superior way of generating all conformations within a given geometry on a lattice by completely avoiding attrition and reducing this highly complicated geometrical problem to a simple algebraic problem of matrix multiplication.
Cluster algorithm for two-dimensional U(1) lattice gauge theory
Sinclair, R.
1992-03-01
We use gauge fixing to rewrite the two-dimensional U(1) pure gauge model with Wilson action and periodic boundary conditions as a nonfrustrated XY model on a closed chain. The Wolff single-cluster algorithm is then applied, eliminating critical slowing down of topological modes and Polyakov loops.
From spin flip excitations to the spin susceptibility enhancement of a two-dimensional electron gas.
Perez, F; Aku-leh, C; Richards, D; Jusserand, B; Smith, L C; Wolverson, D; Karczewski, G
2007-07-13
The g-factor enhancement of the spin-polarized two-dimensional electron gas was measured directly over a wide range of spin polarizations, using spin flip resonant Raman scattering spectroscopy on two-dimensional electron gases embedded in Cd(1-x)Mn(x)Te semimagnetic quantum wells. At zero Raman transferred momentum, the single-particle spin flip excitation, energy Z*, coexists in the Raman spectrum with the spin flip wave of energy Z, the bare giant Zeeman splitting. We compare the measured g-factor enhancement with recent spin-susceptibility enhancement theories and deduce the spin-polarization dependence of the mass renormalization.
Universal relations for the two-dimensional spin-1/2 Fermi gas with contact interactions
Energy Technology Data Exchange (ETDEWEB)
Valiente, Manuel; Zinner, Nikolaj T.; Moelmer, Klaus [Lundbeck Foundation Theoretical Center for Quantum System Research, Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C (Denmark)
2011-12-15
We present universal relations for a two-dimensional Fermi gas with pairwise contact interactions. The derivation of these relations is made possible by obtaining the explicit form of a generalized function--selector--in the momentum representation. The selector implements the short-distance boundary condition between two fermions in a straightforward manner and leads to simple derivations of the universal relations, in the spirit of Tan's original method for the three-dimensional gas.
Nonlinear two-dimensional terahertz photon echo and rotational spectroscopy in the gas phase
Lu, Jian; Hwang, Harold Y; Ofori-Okai, Benjamin K; Fleischer, Sharly; Nelson, Keith A
2016-01-01
Ultrafast two-dimensional spectroscopy utilizes correlated multiple light-matter interactions for retrieving dynamic features that may otherwise be hidden under the linear spectrum. Its extension to the terahertz regime of the electromagnetic spectrum, where a rich variety of material degrees of freedom reside, remains an experimental challenge. Here we report ultrafast two-dimensional terahertz spectroscopy of gas-phase molecular rotors at room temperature. Using time-delayed terahertz pulse pairs, we observe photon echoes and other nonlinear signals resulting from molecular dipole orientation induced by three terahertz field-dipole interactions. The nonlinear time-domain orientation signals are mapped into the frequency domain in two-dimensional rotational spectra which reveal J-state-resolved nonlinear rotational dynamics. The approach enables direct observation of correlated rotational transitions and may reveal rotational coupling and relaxation pathways in the ground electronic and vibrational state.
Chen, Mingji; Pei, Yongmao; Fang, Daining
2012-07-01
Microwave absorbing structures (MASs) reinforced by two dimensional (2D) composite lattice elements have been designed and fabricated. The density of these MASs is lower than 0.5 g/cm3. Experimental measurements show that the sandwich structure with glass fiber reinforced composite (GFRC) lattice core can serve as a broadband MAS with its reflectivity below -10 dB over the frequency range of 4-18 GHz. The low permittivity GFRC is indicated to be the proper material for both the structural element of the core and the transparent face sheet. Calculations by the periodic moment method (PMM) demonstrate that the 2D Kagome lattice performs better for microwave absorbing than the square one at relatively low frequencies. The volume fraction and cell size of the structural element are also revealed to be key factors for microwave absorbing performance.
Analysis of two-dimensional photonic band gap structure with a rhombus lattice
Institute of Scientific and Technical Information of China (English)
Limei Qi; Ziqiang Yang; Xi Gao; Zheng Liang
2008-01-01
@@ The relative band gap for a rhombus lattice photonic crystal is studied by plane wave expansion method and high frequency structure simulator (HFSS) simulation. General wave vectors in the first Briliouin zone are derived. The relative band gap as a function of air-filling factor and background material is investigated, respectively, and the nature of photonic band gap for different lattice angles is analyzed by the distribution of electric energy. These results would provide theoretical instruction for designing optical integrated devices using photonic crystal with a rhombus lattice.
Directory of Open Access Journals (Sweden)
U. Löw
2009-01-01
Full Text Available The magnetic properties of the two-dimensional S=1/2 (quantum antiferromagnetic Heisenberg model on a honeycomb lattice with and without interlayer coupling are studied by means of a continuous Euclidean time Quantum Monte-Carlo algorithm. The internal energy, the magnetic susceptibility and the staggered magnetization are determined in the full temperature range. For the two-dimensional system the ground-state energy/bond is found to be E0hc=-0.36303(13, and the zero temperature staggered magnetization mst=0.2681(8. For coupled planes of honeycomb systems a phase transition from an ordered phase to a disordered phase is found at T/J=0.695(10.
Two-Dimensional Anharmonic Crystal Lattices: Solitons, Solectrons, and Electric Conduction
Velarde, Manuel G.; Ebeling, Werner; Chetverikov, Alexander P.
2011-01-01
Reported here are salient features of soliton-mediated electron transport in anharmonic crystal lattices.After recalling how an electron-soliton bound state (solectron) can be formed we comment on consequences like electron surfing on a sound wave and balistic transport, possible percolation in 2d lattices, and a novel form of electron pairing with strongly correlated electrons both in real space and momentum space.
Percolation in spatial evolutionary prisoner's dilemma game on two-dimensional lattices
Choi, Woosik; Yook, Soon-Hyung; Kim, Yup
2015-11-01
We study the spatial evolutionary prisoner's dilemma game with updates of imitation max on triangular, hexagonal, and square lattices. We use the weak prisoner's dilemma game with a single parameter b . Due to the competition between the temptation value b and the coordination number z of the base lattice, a greater variety of percolation properties is expected to occur on the lattice with the larger z . From the numerical analysis, we find six different regimes on the triangular lattice (z =6 ). Regardless of the initial densities of cooperators and defectors, cooperators always percolate in the steady state in two regimes for small b . In these two regimes, defectors do not percolate. In two regimes for the intermediate value of b , both cooperators and defectors undergo percolation transitions. The defector always percolates in two regimes for large b . On the hexagonal lattice (z =3 ), there exist two distinctive regimes. For small b , both the cooperators and the defectors undergo percolation transitions while only defectors always percolate for large b . On the square lattice (z =4 ), there exist three regimes. Combining with the finite-size scaling analyses, we show that all the observed percolation transitions belong to the universality class of the random percolation. We also show how the detailed growth mechanism of cooperator and defector clusters decides each regime.
Energy Technology Data Exchange (ETDEWEB)
Mandal, R.; Barman, S.; Saha, S.; Barman, A., E-mail: abarman@bose.res.in [Department of Condensed Matter Physics and Material Sciences, S. N. Bose National Centre for Basic Sciences, Block JD, Sector III, Salt Lake, Kolkata 700 098 (India); Otani, Y. [CEMS-RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan)
2015-08-07
Ferromagnetic antidot lattices are important systems for magnetic data storage and magnonic devices, and understanding their magnetization dynamics by varying their structural parameters is an important problems in magnetism. Here, we investigate the variation in spin wave spectrum in two-dimensional nanoscale Ni{sub 80}Fe{sub 20} antidot lattices with lattice symmetry. By varying the bias magnetic field values in a broadband ferromagnetic resonance spectrometer, we observed a stark variation in the spin wave spectrum with the variation of lattice symmetry. The simulated mode profiles showed further difference in the spatial nature of the modes between different lattices. While for square and rectangular lattices extended modes are observed in addition to standing spin wave modes, all modes in the hexagonal, honeycomb, and octagonal lattices are either localized or standing waves. In addition, the honeycomb and octagonal lattices showed two different types of modes confined within the honeycomb (octagonal) units and between two such consecutive units. Simulated internal magnetic fields confirm the origin of such a wide variation in the frequency and spatial nature of the spin wave modes. The tunability of spin waves with the variation of lattice symmetry is important for the design of future magnetic data storage and magnonic devices.
Directory of Open Access Journals (Sweden)
F Bakhshi Garmi
2016-02-01
Full Text Available In this paper we studied the focusing effect of electromagnetic wave in the two-dimensional graded photonic crystal consisting of Silicon rods in the air background with gradually varying lattice constant. The results showed that graded photonic crystal can focus wide beams on a narrow area at frequencies near the lower edge of the band gap, where equal frequency contours are not concave. For calculation of photonic band structure and equal frequency contours, we have used plane wave expansion method and revised plane wave expansion method, respectively. The calculation of the electric and magnetic fields was performed by finite difference time domain method.
Fission-gas release at extended burnups: effect of two-dimensional heat transfer
Energy Technology Data Exchange (ETDEWEB)
Tayal, M. [Atomic Energy of Canada Limited, Mississauga, Ontario (Canada); Yu, S.D. [Ryerson Polytechnic Univ., Toronto, Ontario (Canada); Lau, J.H.K
2000-09-01
To better simulate the performance of high-burnup CANDU fuel, a two-dimensional model for heat transfer between the pellet and the sheath has been added to the computer code ELESTRES. The model covers four relative orientations of the pellet and the sheath and their impacts on heat transfer and fission-gas release. The predictions of the code were compared to a database of 27 experimental irradiations involving extended burnups and normal burnups. The calculated values of fission gas release matched the measurements to an average of 94%. Thus, the two-dimensional heat transfer model increases the versatility of the ELESTRES code to better simulate fuels at normal as well as at extended burnups. (author)
Li, Yanyan
2006-07-01
In recent years, comprehensive two-dimensional gas chromatography (GC x GC) have been used widely, and the applications of this technique to many fields have already been reported. In the standard method of oil analysis, the concentrations of aromatics and naphthalene hydrocarbons in light petroleum products must be detected by more than two methods. Mono-aromatics, di-aromatics etc. in light petroleum products were detected only by comprehensive two-dimensional gas chromatography. After the proper selection of column system and optimization of chromatographic conditions, the method can achieve the group separations of paraffins, olefins, naphthenes, aromatics with 1 to 2 rings and some target components in light petroleum products with good reproducibility and good precision. The recoveries of standard compounds were 89.5% - 106.1%, and the relative standard deviations of repeatedly detecting the components were all lower than 5.8%. It took only 30 min to finish a determination.
Bloch waves in an arbitrary two-dimensional lattice of subwavelength Dirichlet scatterers
Schnitzer, Ory
2016-01-01
We study waves governed by the planar Helmholtz equation, propagating in an infinite lattice of subwavelength Dirichlet scatterers, the periodicity being comparable to the wavelength. Applying the method of matched asymptotic expansions, the scatterers are effectively replaced by asymptotic point constraints. The resulting coarse-grained Bloch-wave dispersion problem is solved by a generalised Fourier series, whose singular asymptotics in the vicinities of scatterers yield the dispersion relation governing modes that are strongly perturbed from plane-wave solutions existing in the absence of the scatterers; there are also empty-lattice waves that are only weakly perturbed. Characterising the latter is useful in interpreting and potentially designing the dispersion diagrams of such lattices. The method presented, that simplifies and expands on Krynkin & McIver [Waves Random Complex, 19 347 2009], could be applied in the future to study more sophisticated designs entailing resonant subwavelength elements di...
Auxetic two-dimensional lattice with Poisson's Ratio arbitrarily close to -1
Cabras, L
2014-01-01
In this paper we propose a new lattice structure having macroscopic Poisson's ratio arbitrarily close to the stability limit -1. We tested experimentally the effective Poisson's ratio of the micro-structured medium; the uniaxial test has been performed on a thermoplastic lattice produced with a 3d printing technology. A theoretical analysis of the effective properties has been performed and the expression of the macroscopic constitutive properties is given in full analytical form as a function of the constitutive properties of the elements of the lattice and on the geometry of the microstructure. The analysis has been performed on three micro-geometry leading to an isotropic behaviour for the cases of three-fold and six-fold symmetry and to a cubic behaviour for the case of four-fold symmetry.
Magnetoresistance of a two-dimensional electron gas in a random magnetic field
DEFF Research Database (Denmark)
Smith, Anders; Taboryski, Rafael Jozef; Hansen, Luise Theil
1994-01-01
We report magnetoresistance measurements on a two-dimensional electron gas made from a high-mobility GaAs/AlxGa1-xAs heterostructure, where the externally applied magnetic field was expelled from regions of the semiconductor by means of superconducting lead grains randomly distributed on the surf...... on the surface of the sample. A theoretical explanation in excellent agreement with the experiment is given within the framework of the semiclassical Boltzmann equation. © 1994 The American Physical Society...
A New Class of Resonances at the Edge of the Two Dimensional Electron Gas
Zhitenev, N. B.; Brodsky, M; Ashoori, R. C.; Melloch, M. R.
1996-01-01
We measure the frequency dependent capacitance of a gate covering the edge and part of a two-dimensional electron gas in the quantum Hall regime. In applying a positive gate bias, we create a metallic puddle under the gate surrounded by an insulating region. Charging of the puddle occurs via electron tunneling from a metallic edge channel. Analysis of the data allows direct extraction of this tunneling conductance. Novel conductance resonances appear as a function of gate bias. Samples with g...
Interaction of a Surface Acoustic Wave with a Two-dimensional Electron Gas
Institute of Scientific and Technical Information of China (English)
YANG Shi-Jie; ZHAO Hu; YU Yue
2005-01-01
When a surface acoustic wave (SAW) propagates on the surface of a GaAs semiconductor, coupling between electrons in the two-dimensional electron gas beneath the interface and the elastic host crystal through piezoelectric interaction will attenuate the SAW. The coupling coefficient is calculated for the SAW propagating along an arbitrary direction. It is found that the coupling strength is strongly dependent on the propagating direction. When the SAW propagates along the [011] direction, the coupling becomes quite weak.
Interaction-induced huge magnetoresistance in a high mobility two-dimensional electron gas
Energy Technology Data Exchange (ETDEWEB)
Bockhorn, L.; Haug, R. J. [Institut für Festkörperphysik, Leibniz Universität Hannover, D-30167 Hannover (Germany); Gornyi, I. V. [Institut für Nanotechnologie, Karlsruher Institut of Technology, D-76021 Karlsruhe (Germany); Schuh, D. [Institut für Experimentelle und Angewandte Physik, Universität Regensburg, D-93053 Regensburg (Germany); Wegscheider, W. [ETH Zürich (Switzerland)
2013-12-04
A strong negative magnetoresistance is observed in a high-mobility two-dimensional electron gas in a GaAs/Al{sub 0.3}Ga{sub 0.7}As quantum well. We discuss that the negative magnetoresistance consists of a small peak induced by a combination of two types of disorder and a huge magnetoresistance explained by the interaction correction to the conductivity for mixed disorder.
Average site perimeter of directed animals on the two-dimensional lattices
Bacher, Axel
2009-01-01
We introduce new combinatorial (bijective) methods that enable us to compute the average value of three parameters of directed animals of a given area, including the site perimeter. Our results cover directed animals of any one-line source on the square lattice and its bounded variants, and we give counterparts for most of them in the triangular lattices. We thus prove conjectures by Conway and Le Borgne. The techniques used are based on Viennot's correspondence between directed animals and heaps of pieces (or elements of a partially commutative monoid).
Zhou Yun Song; Wang Fu He
2003-01-01
We investigate the properties of guide modes localized at the interfaces of photonic crystal (PC) heterostructures which are composed of two semi-infinite two-dimensional PCs consisting of non-circular air cylinders with different rotating angles embedded in a homogeneous host dielectric. Photonic band gap structures are calculated with the use of the plane-wave expansion method in combination with a supercell technique. We consider various configurations, for instance, rectangular (square) lattice-rectangular (square) air cylinders, and different rotating angles of the cylinders in the lattices on either side of the interface of a heterostructure. We find that the absolute gap width and the number of guide modes strongly depend on geometric and physical parameters of the heterostructures. It is anticipated that the guide modes in such heterostructures can be engineered by adjusting parameters.
Giberti, Claudio; Vernia, Cecilia
1994-12-01
We consider diffusively coupled logistic maps in one- and two-dimensional lattices. We investigate periodic behaviors as the coupling parameter varies, i.e., existence and bifurcations of some periodic orbits with the largest domain of attraction. Similarity and differences between the two lattices are shown. For small coupling the periodic behavior appears to be characterized by a number of periodic orbits structured in such a way to give rise to distinct, reverse period-doubling sequences. For intermediate values of the coupling a prominent role in the dynamics is played by the presence of normally attracting manifolds that contain periodic orbits. The dynamics on these manifolds is very weakly hyperbolic, which implies long transients. A detailed investigation allows the understanding of the mechanism of their formation. A complex bifurcation is found which causes an attracting manifold to become unstable.
Institute of Scientific and Technical Information of China (English)
Xu Quan; Tian Qiang
2009-01-01
We study a two-dimensional (2D) diatomic lattice of anharmonic oscillators with only quartic nearest-neighbor interactions, in which discrete breathers (DBs) can be explicitly constructed by an exact separation of their time and space dependence. DBs can stably exist in the 2D discrete diatomic Klein-Gordon lattice with hard and soft on-site potentials. When a parametric driving term is introduced in the factor multiplying the harmonic part of the on-site potential of the system, we can obtain the stable quasiperiodic discrete breathers (QDBs) and chaotic discrete breathers (CDBs) by changing the amplitude of the driver. But the DBs and QDBs with symmetric and anti-symmetric profiles that are centered at a heavy atom are more stable than at a light atom, because the frequencies of the DBs and QDBs centered at a heavy atom are lower than those centered at a light atom.
Noise Threshold for a Fault-Tolerant Two-Dimensional Lattice Architecture
Svore, K M; Terhal, B M; Svore, Krysta M.; Vincenzo, David P. Di; Terhal, Barbara M.
2006-01-01
We consider a model of quantum computation in which the set of operations is limited to nearest-neighbor interactions on a 2D lattice. We model movement of qubits with noisy SWAP operations. For this architecture we design a fault-tolerant coding scheme using the concatenated [[7,1,3
Wang, Pengfei; Gaitanaros, Stavros; Lee, Seungwoo; Bathe, Mark; Shih, William M; Ke, Yonggang
2016-06-22
Scaffolded DNA origami has proven to be a versatile method for generating functional nanostructures with prescribed sub-100 nm shapes. Programming DNA-origami tiles to form large-scale 2D lattices that span hundreds of nanometers to the micrometer scale could provide an enabling platform for diverse applications ranging from metamaterials to surface-based biophysical assays. Toward this end, here we design a family of hexagonal DNA-origami tiles using computer-aided design and demonstrate successful self-assembly of micrometer-scale 2D honeycomb lattices and tubes by controlling their geometric and mechanical properties including their interconnecting strands. Our results offer insight into programmed self-assembly of low-defect supra-molecular DNA-origami 2D lattices and tubes. In addition, we demonstrate that these DNA-origami hexagon tiles and honeycomb lattices are versatile platforms for assembling optical metamaterials via programmable spatial arrangement of gold nanoparticles (AuNPs) into cluster and superlattice geometries.
Institute of Scientific and Technical Information of China (English)
Kyu; Hwan; Hwang; G.; Hugh; Song; Chanmook; Lim; Soan; Kim; Kyung-Won; Chun; Mahn; Yong; Park
2003-01-01
A channel-drop filter has been designed based on the two-dimensional triangular-lattice hole photonic-crystal structure, which consists of two line defects and two point defects, by a two-dimensional finite-difference time-domain simulation.
Two-dimensional lattice solitons in polariton condensates with spin-orbit coupling
Kartashov, Yaroslav V
2016-01-01
We study two-dimensional fundamental and vortex solitons in polariton condensates with spin-orbit coupling and Zeeman splitting evolving in square arrays of microcavity pillars. Due to repulsive excitonic nonlinearity such states are encountered in finite gaps in the spectrum of the periodic array. Spin-orbit coupling between two polarization components stemming from TE-TM energy splitting of the cavity photons acting together with Zeeman splitting lifts the degeneracy between vortex solitons with opposite topological charges and makes their density profiles different for a fixed energy. This results in formation of four distinct families of vortex solitons with topological charges m=+-1, all of which can be stable. At the same time, only two stable families of fundamental gap solitons characterized by domination of different polarization components are encountered.
Phase diagram of the two-dimensional O(3) model from dual lattice simulations
Bruckmann, Falk; Kloiber, Thomas; Sulejmanpasic, Tin
2016-01-01
We have simulated the asymptotically free two-dimensional O(3) model at nonzero chemical potential using the model's dual representation. We first demonstrate how the latter solves the sign (complex action) problem. The system displays a crossover at nonzero temperature, while at zero temperature it undergoes a quantum phase transition when mu reaches the particle mass (generated dynamically similar to QCD). The density follows a square root behavior universal for repulsive bosons in one spatial dimension. We have also measured the spin stiffness, known to be sensitive to the spatial correlation length, using different scaling trajectories to zero temperature and infinite size. It points to a dynamical critical exponent z=2. Comparisons to thermodynamic Bethe ansaetze are shown as well.
Photonic Weyl point in a two-dimensional resonator lattice with a synthetic frequency dimension
Lin, Qian; Xiao, Meng; Yuan, Luqi; Fan, Shanhui
2016-12-01
Weyl points, as a signature of 3D topological states, have been extensively studied in condensed matter systems. Recently, the physics of Weyl points has also been explored in electromagnetic structures such as photonic crystals and metamaterials. These structures typically have complex three-dimensional geometries, which limits the potential for exploring Weyl point physics in on-chip integrated systems. Here we show that Weyl point physics emerges in a system of two-dimensional arrays of resonators undergoing dynamic modulation of refractive index. In addition, the phase of modulation can be controlled to explore Weyl points under different symmetries. Furthermore, unlike static structures, in this system the non-trivial topology of the Weyl point manifests in terms of surface state arcs in the synthetic space that exhibit one-way frequency conversion. Our system therefore provides a versatile platform to explore and exploit Weyl point physics on chip.
Xu, Cenke
Several examples of quantum spin systems and pseudo spin systems have been studied, and unconventional states of matters and phase transitions have been realized in all these systems under consideration. In the p +/- ip superconductor Josephson lattice and the p--band cold atomic system trapped in optical lattices, novel phases which behave similarly to 1+1 dimensional systems are realized, despite the fact that the real physical systems are in two or three dimensional spaces. For instance, by employing a spin-wave analysis together with a new duality transformation, we establish the existence and stability of a novel gapless "critical phase", which we refer to as a "bond algebraic liquid". This novel critical phase is analogous to the 1+1 dimensional algebraic boson liquid phase. The reason for the novel physics is that there is a quasilocal gauge symmetry in the effective low energy Hamiltonian. In a spin-1 system on the kagome lattice, and a hard-core boson system on the honeycomb lattice, the low energy physics is controlled by two components of compact U(1) gauge symmetries that emerge at low energy. Making use of the confinement nature of the 2+1 dimensional compact gauge theories and the powerful duality between gauge theories and height field theories, the crystalline phase diagrams are studied for both systems, and the transitions to other phases are also considered. These phase diagrams might be accessible in strongly correlated materials, or atomic systems in optical lattices. A novel quantum ground state of matter is realized in a bosonic model on three dimensional fcc lattice with emergent low energy excitations. The novel phase obtained is a stable gapless boson liquid phase, with algebraic boson density correlations. The stability of this phase is protected against the instanton effect and superfluidity by self-duality and large gauge symmetries on both sides of the duality. The gapless collective excitations of this phase closely resemble the
Vyas, Vivek M.; Panigrahi, Prasanta. K.; Banerji, J.
2013-01-01
A system of two dimensional photon gas has recently been realized experimentally. It is pointed out that this setup can be used to observe a universal breathing mode of photon gas. It is shown that a modification in the experimental setup would open up a possibility of observing the Berezinskii-Kosterlitz-Thouless (BKT) phase transition in such a system. It is shown that the universal jump in the superfluid density of light in the output channel can be used as an unambiguous signature for the...
Vyas, Vivek M; Banerji, J
2013-01-01
A system of two dimensional photon gas has recently been realized experimentally. It is pointed out that this setup can be used to observe a universal breathing mode of photon gas. It is shown that a modification in the experimental setup would open up a possibility of observing the Berezinskii-Kosterlitz-Thouless (BKT) phase transition in such a system. It is shown that the universal jump in the superfluid density of light in the output channel can be used as an unambiguous signature for the experimental verification of the BKT transition.
Directory of Open Access Journals (Sweden)
Marcio Pozzobon Pedroso
2009-01-01
Full Text Available This paper presents the fundamental principles, instrumentation and selected applications of comprehensive two-dimensional gas chromatography (GC × GC. In this technique, introduced in 1991, two capillary columns are coupled and proper modulating interfaces continuously collect the eluate from the first column, transferring it to the second column. The result is a geometric increment in the chromatographic resolution, ensuring separation of extremely complex mixtures in time periods shorter or comparable to those of analysis using conventional gas chromatography and with better detectabilities and sensitivities.
Anisotropic ordering in a two-temperature lattice gas
DEFF Research Database (Denmark)
Szolnoki, Attila; Szabó, György; Mouritsen, Ole G.
1997-01-01
We consider a two-dimensional lattice gas model with repulsive nearest- and next-nearest-neighbor interactions that evolves in time according to anisotropic Kawasaki dynamics. The hopping of particles along the principal directions is governed by two heat baths at different temperatures T-x and T...
Fabrication of deep-profile Al-doped ZnO one- and two-dimensional lattices as plasmonic elements
Jensen, Flemming; Shkondin, Evgeniy; Takayama, Osamu; Larsen, Pernille V.; Mar, Mikkel D.; Malureanu, Radu; Lavrinenko, Andrei V.
2016-09-01
In this work, we report on fabrication of deep-profile one- and two-dimensional lattices made from Al-doped ZnO (AZO). AZO is considered as an alternative plasmonic material having the real part of the permittivity negative in the near infrared range. The exact position of the plasma frequency of AZO is doping concentration dependent, allowing for tuning possibilities. In addition, the thickness of the AZO film also affects its material properties. Physical vapor deposition techniques typically applied for AZO coating do not enable deep profiling of a plasmonic structure. Using the atomic layer deposition technique, a highly conformal deposition method, allows us to fabricate high-aspect ratio structures such as one-dimensional lattices with a period of 400 nm and size of the lamina of 200 nm in width and 3 μm in depth. Thus, our structures have an aspect ratio of 1:15 and are homogeneous on areas of 2×2 cm2 and more. We also produce two-dimensional arrays of circular nanopillars with similar dimensions. Instead of nanopillars hollow tubes with a wall thickness on demand from 20 nm up to a complete fill can be fabricated.
Filippi, Jean-Jacques; Belhassen, Emilie; Baldovini, Nicolas; Brevard, Hugues; Meierhenrich, Uwe J
2013-05-03
Vetiver essential oils (VEO) are important raw ingredients used in perfume industry, entering the formula of numerous modern fragrances. Vetiver oils are considered to be among the most complex essential oils, resulting most of the time in highly coeluted chromatograms whatever the analytical technique. In this context, conventional gas chromatography has failed to provide a routine tool for the accurate qualitative and quantitative analysis of their constituents. Applying comprehensive two-dimensional gas chromatography techniques (GC×GC-FID/MS) afforded the mean to separate efficiently vetiver oil constituents in order to identify them in a more reliable way. Moreover, this is the first time that a complete true quantitation of each constituent is carried out on such complex oils by means of internal calibration. Finally, we have studied the influence of the injection mode on the determined chemical composition, and showed that several alcohols underwent dehydration under defined chromatographic conditions (splitless mode) usually recommended for quantitation purposes. Copyright © 2013 Elsevier B.V. All rights reserved.
General model for a entanglement-enhanced composed quantum game on a two-dimensional lattice
Miszczak, Jarosław Adam; Sładkowski, Jan
2013-01-01
We introduce a method of analyzing entanglement enhanced quantum games on regular lattices of agents. Our method is valid for setups with periodic and non-periodic boundary conditions. To demonstrate our approach we study two different types games, namely the prisoner's dilemma game and a cooperative Parrondo's game. In both cases we obtain results showing, that entanglement is a crucial resource necessary for the agents to achieve positive capital gain.
Three-dimensional vortex solitons in quasi-two-dimensional lattices.
Leblond, Hervé; Malomed, Boris A; Mihalache, Dumitru
2007-08-01
We consider the three-dimensional (3D) Gross-Pitaevskii or nonlinear Schrödinger equation with a quasi-2D square-lattice potential (which corresponds to the optical lattice trapping a self-attractive Bose-Einstein condensate, or, in some approximation, to a photonic-crystal fiber, in terms of nonlinear optics). Stable 3D solitons, with embedded vorticity S=1 and 2, are found by means of the variational approximation and in a numerical form. They are built, basically, as sets of four fundamental solitons forming a rhombus, with phase shifts piS2 between adjacent sites, and an empty site in the middle. The results demonstrate two species of stable 3D solitons, which were not studied before, viz., localized vortices ("spinning light bullets," in terms of optics) with S>1 , and vortex solitons (with any S not equal 0 ) supported by a lattice in the 3D space. Typical scenarios of instability development (collapse or decay) of unstable localized vortices are identified too.
Observation of a pairing pseudogap in a two-dimensional Fermi gas.
Feld, Michael; Fröhlich, Bernd; Vogt, Enrico; Koschorreck, Marco; Köhl, Michael
2011-11-30
Pairing of fermions is ubiquitous in nature, underlying many phenomena. Examples include superconductivity, superfluidity of (3)He, the anomalous rotation of neutron stars, and the crossover between Bose-Einstein condensation of dimers and the BCS (Bardeen, Cooper and Schrieffer) regime in strongly interacting Fermi gases. When confined to two dimensions, interacting many-body systems show even more subtle effects, many of which are not understood at a fundamental level. Most striking is the (as yet unexplained) phenomenon of high-temperature superconductivity in copper oxides, which is intimately related to the two-dimensional geometry of the crystal structure. In particular, it is not understood how the many-body pairing is established at high temperature, and whether it precedes superconductivity. Here we report the observation of a many-body pairing gap above the superfluid transition temperature in a harmonically trapped, two-dimensional atomic Fermi gas in the regime of strong coupling. Our measurements of the spectral function of the gas are performed using momentum-resolved photoemission spectroscopy, analogous to angle-resolved photoemission spectroscopy in the solid state. Our observations mark a significant step in the emulation of layered two-dimensional strongly correlated superconductors using ultracold atomic gases.
Dispersion of guided modes in two-dimensional split ring lattices
DEFF Research Database (Denmark)
Hansen, Per Lunnemann; Koenderink, A. Femius
2014-01-01
-plane electric modes. Scatterers that have an in-plane electric and out-of-plane magnetic polarizability, but without intrinsic magnetoelectric coupling, result in two bands that are mixtures of the bands of electric-only and magnetic-only lattices. Thereby, bianisotropy through mutual coupling, in absence...... of building-block bianisotropy, is evident. Once strong bianisotropy is included in each building block, the Bloch modes become even more strongly magnetoelectric. Our results are important to understand spatial dispersion and bianisotropy of metasurface and metamaterial designs....
Analysis of optomechanical coupling in two-dimensional square lattice phoxonic crystal slab cavities
El-Jallal, Said; Oudich, Mourad; Pennec, Yan; Djafari-Rouhani, Bahram; Laude, Vincent; Beugnot, Jean-Charles; Martínez, Alejandro; Escalante, José María; Makhoute, Abdelkader
2013-11-01
We theoretically investigate phonon-photon interaction in cavities created in a phoxonic crystal slab constituted by a two-dimensional (2D) square array of holes in a silicon membrane. The structure without defects provides 2D band gaps for both electromagnetic and elastic waves. We consider two types of cavities, namely, an L3 cavity (a row of three holes is removed) and a cross-shape cavity, which both possess highly confined phononic and photonic localized modes suitable for enhancing their interaction. In our theoretical study, we take into account two mechanisms that contribute to optomechanical interaction, namely, the photoelastic and the interface motion effects. We show that, depending on the considered pair of photonic and phononic modes, the two mechanisms can have similar or very different magnitudes, and their contributions can be either in or out of phase. We find out that only acoustic modes with a specific symmetry are allowed to couple with photonic cavity modes. The coupling strength is quantified by two different methods. In the first method, we compute a direct estimation of coupling rates by overlap integrals, while in the second one, we analyze the temporal modulation of the resonant photonic frequency by the phonon-induced acoustic vibrational motion during one acoustic period. Interestingly, we obtain high optomechanical interaction, with the coupling rate reaching more than 2.4 MHz for some specific phonon-photon pairs.
Yang, Bo; Li, Xiao-Teng; Chen, Wei; Liu, Jian; Chen, Xiao-Song
2016-10-01
Self-questioning mechanism which is similar to single spin-flip of Ising model in statistical physics is introduced into spatial evolutionary game model. We propose a game model with altruistic to spiteful preferences via weighted sums of own and opponent's payoffs. This game model can be transformed into Ising model with an external field. Both interaction between spins and the external field are determined by the elements of payoff matrix and the preference parameter. In the case of perfect rationality at zero social temperature, this game model has three different phases which are entirely cooperative phase, entirely non-cooperative phase and mixed phase. In the investigations of the game model with Monte Carlo simulation, two paths of payoff and preference parameters are taken. In one path, the system undergoes a discontinuous transition from cooperative phase to non-cooperative phase with the change of preference parameter. In another path, two continuous transitions appear one after another when system changes from cooperative phase to non-cooperative phase with the prefenrence parameter. The critical exponents v, β, and γ of two continuous phase transitions are estimated by the finite-size scaling analysis. Both continuous phase transitions have the same critical exponents and they belong to the same universality class as the two-dimensional Ising model. Supported by the National Natural Science Foundation of China under Grant Nos. 11121403 and 11504384
First-order phase transitions in repulsive rigid k-mers on two-dimensional lattices
Pasinetti, P. M.; Romá, F.; Ramirez-Pastor, A. J.
2012-02-01
In a previous paper [F. Romá, A. J. Ramirez-Pastor, and J. L. Riccardo, Phys. Rev. B 72, 035444 (2005)], the critical behavior of repulsive rigid rods of length k (k-mers) on a square lattice at half coverage has been studied by using Monte Carlo (MC) simulations. The obtained results indicated that (1) the phase transition occurring in the system is a second-order phase transition for all adsorbate sizes k; and (2) the universality class of the transition changes from 2D Ising-type for monomers (k = 1) to an unknown universality class for k ≥ 2. In the present work, we revisit our previous results together with further numerical evidences, resulting from new extensive MC simulations based on an efficient exchange algorithm and using high-performance computational capabilities. In contrast to our previous conclusions (1) and (2), the new numerical calculations clearly support the occurrence of a first-order phase transition for k ≥ 2. In addition, a similar scenario was found for k-mers adsorbed on the triangular lattice at coverage k/(2k+1).
Kinetic Theory of a Confined Quasi-Two-Dimensional Gas of Hard Spheres
Directory of Open Access Journals (Sweden)
J. Javier Brey
2017-02-01
Full Text Available The dynamics of a system of hard spheres enclosed between two parallel plates separated a distance smaller than two particle diameters is described at the level of kinetic theory. The interest focuses on the behavior of the quasi-two-dimensional fluid seen when looking at the system from above or below. In the first part, a collisional model for the effective two-dimensional dynamics is analyzed. Although it is able to describe quite well the homogeneous evolution observed in the experiments, it is shown that it fails to predict the existence of non-equilibrium phase transitions, and in particular, the bimodal regime exhibited by the real system. A critical revision analysis of the model is presented , and as a starting point to get a more accurate description, the Boltzmann equation for the quasi-two-dimensional gas has been derived. In the elastic case, the solutions of the equation verify an H-theorem implying a monotonic tendency to a non-uniform steady state. As an example of application of the kinetic equation, here the evolution equations for the vertical and horizontal temperatures of the system are derived in the homogeneous approximation, and the results compared with molecular dynamics simulation results.
Two-dimensional lattice Boltzmann model for compressible flows with high Mach number
Gan, Yanbiao; Xu, Aiguo; Zhang, Guangcai; Yu, Xijun; Li, Yingjun
2008-03-01
In this paper we present an improved lattice Boltzmann model for compressible Navier-Stokes system with high Mach number. The model is composed of three components: (i) the discrete-velocity-model by M. Watari and M. Tsutahara [Phys. Rev. E 67 (2003) 036306], (ii) a modified Lax-Wendroff finite difference scheme where reasonable dissipation and dispersion are naturally included, (iii) artificial viscosity. The improved model is convenient to compromise the high accuracy and stability. The included dispersion term can effectively reduce the numerical oscillation at discontinuity. The added artificial viscosity helps the scheme to satisfy the von Neumann stability condition. Shock tubes and shock reflections are used to validate the new scheme. In our numerical tests the Mach numbers are successfully increased up to 20 or higher. The flexibility of the new model makes it suitable for tracking shock waves with high accuracy and for investigating nonlinear nonequilibrium complex systems.
From Discreteness to Continuity: Dislocation Equation for Two-Dimensional Triangular Lattice
Institute of Scientific and Technical Information of China (English)
WANG Shao-Feng
2007-01-01
@@ A systematic method from the discreteness to the continuity is presented for the dislocation equation of the triangular lattice. A modification of the Peierls equation has been derived strictly. The modified equation includes the higher order corrections of the discrete effect which are important for the core structure of dislocation. It is observed that the modified equation possesses a universal form which is model-independent except the factors.The factors, which depend on the detail of the model, are related to the derivatives of the kernel at its zero point in the wave-vector space. The results open a way to deal with the complicated models because what one needs to do is to investigate the behaviour near the zero point of the kernel in the wave-vector space instead of calculating the kernel completely.
Spectroscopy of Dipolar Fermions in Layered Two-Dimensional and Three-Dimensional Lattices
2011-09-06
term. We approximate Vαβ(j,ρ) by Vαβ(j,ρ) ≈ γαβU(j,ρ) (8) and Vsf by Vsf(j,ρ) ≈ ηU(j,ρ), (9) with U(j,ρ) = δ0j 1 ρ3 + A + (1 − δ0j ) 1 − 3( ( jdl )2 ρ2... jdl )2 ) [ρ2 + ( jdl )2]3/2 , (10) where γαβ = dααdββ/(4π 0), η = | ∫ dzw∗1(z)w2(z)|2d212/(4π 0), and dl is the lattice spacing, where A ∼ 3, with...3( ( jdl )2 ρ2+( jdl )2 ) [ρ2 + ( jdl )2]3/2 ] = 2π3/2 √ m β n (γ12 − γ11 + η) (thermal), (28) 033608-5 HAZZARD, GORSHKOV, AND REY PHYSICAL REVIEW A 84
Magnetoelectronic transport of the two-dimensional electron gas in CdSe single quantum wells
Indian Academy of Sciences (India)
P K Ghosh; A Ghosal; D Chattopadhyay
2009-02-01
Hall mobility and magnetoresistance coefficient for the two-dimensional (2D) electron transport parallel to the heterojunction interfaces in a single quantum well of CdSe are calculated with a numerical iterative technique in the framework of Fermi–Dirac statistics. Lattice scatterings due to polar-mode longitudinal optic (LO) phonons, and acoustic phonons via deformation potential and piezoelectric couplings, are considered together with background and remote ionized impurity interactions. The parallel mode of piezoelectric scattering is found to contribute more than the perpendicular mode. We observe that the Hall mobility decreases with increasing temperature but increases with increasing channel width. The magnetoresistance coefficient is found to decrease with increasing temperature and increase with increasing magnetic field in the classical region.
Ma, Yandong; Kou, Liangzhi; Li, Xiao; Dai, Ying; Heine, Thomas
2016-01-01
So far, several transition metal dichalcogenide (TMDC)-based two-dimensional (2D) topological insulators (TIs) have been discovered, all of them based on a tetragonal lattice. However, in 2D crystals, the hexagonal rather than the tetragonal symmetry is the most common motif. Here, based on first principles calculations, we propose a class of stable 2D TMDCs of composition MX2(M =Mo ,W ;X =S ,Se ,Te ) with a hexagonal lattice. They are all in the same stability range as other 2D TMDC allotropes that have been demonstrated experimentally, and they are identified to be practical 2D TIs with large band gaps ranging from 41 to 198 meV, making them suitable for applications at room temperature. Besides, in contrast to tetragonal 2D TMDCs, their hexagonal lattice will greatly facilitate the integration of theses novel TI state van der Waals crystals with other hexagonal or honeycomb materials and thus provide a route for 2D material-based devices for wider nanoelectronic and spintronic applications. The nontrivial band gaps of both WS e2 and WT e2 2D crystals are 198 meV, which are larger than that in any previously reported TMDC-based TIs. These large band gaps entirely stem from the strong spin orbit coupling strength within the d orbitals of Mo/W atoms near the Fermi level. Our findings broaden the scientific and technological impact of both 2D TIs and TMDCs.
Metal Oxide Gas Sensor Drift Compensation Using a Two-Dimensional Classifier Ensemble
Directory of Open Access Journals (Sweden)
Hang Liu
2015-04-01
Full Text Available Sensor drift is the most challenging problem in gas sensing at present. We propose a novel two-dimensional classifier ensemble strategy to solve the gas discrimination problem, regardless of the gas concentration, with high accuracy over extended periods of time. This strategy is appropriate for multi-class classifiers that consist of combinations of pairwise classifiers, such as support vector machines. We compare the performance of the strategy with those of competing methods in an experiment based on a public dataset that was compiled over a period of three years. The experimental results demonstrate that the two-dimensional ensemble outperforms the other methods considered. Furthermore, we propose a pre-aging process inspired by that applied to the sensors to improve the stability of the classifier ensemble. The experimental results demonstrate that the weight of each multi-class classifier model in the ensemble remains fairly static before and after the addition of new classifier models to the ensemble, when a pre-aging procedure is applied.
Shevyrin, A. A.; Pogosov, A. G.; Bakarov, A. K.; Shklyaev, A. A.
2016-07-01
The electrical response of a two-dimensional electron gas to vibrations of a nanomechanical cantilever containing it is studied. Vibrations of perpendicularly oriented cantilevers are experimentally shown to oppositely change the conductivity near their bases. This indicates the piezoelectric nature of electromechanical coupling. A physical model is developed, which quantitatively explains the experiment. It shows that the main origin of the conductivity change is a rapid change in the mechanical stress on the boundary between suspended and nonsuspended areas, rather than the stress itself.
Shevyrin, A. A.; Pogosov, A. G.; Bakarov, A. K.; Shklyaev, A. A.
2017-06-01
A physical model describing the piezoelectric-effect-mediated influence of bending of a thin suspended cantilever with a two-dimensional electron gas on the conductivity is proposed. The model shows that the conductivity change is almost entirely caused by the rapid change in mechanical stress near the boundary of suspended and non-suspended areas, rather than by the stress itself. An experiment confirming that the electromechanical coupling is associated with the piezoelectric effect is performed. The experimentally measured conductance sensitivity to the cantilever’s vibrations agree with the developed physical model.
Ultra-low-temperature cooling of two-dimensional electron gas
Xia, J. S.; Adams, E. D.; Shvarts, V.; Pan, W.; Stormer, H. L.; Tsui, D. C.
2000-05-01
A new design has been used for cooling GaAs/Al xGa 1- xAs sample to ultra-low-temperatures. The sample, with electrical contacts directly soldered to the sintered silver powder heat exchangers, was immersed in liquid 3He, which was cooled by a PrNI 5 nuclear refrigerator. The data analysis shows that the two-dimensional electron gas (2DEG) was cooled to 4.0 mK at the refrigerator base temperature Tb of 2.0 mK. The design with heat exchanger cooling is applicable to any ultra-low-temperature transport measurements of 2DEG system.
Spin injection into a two-dimensional electron gas using inter-digital-ferromagnetic contacts
DEFF Research Database (Denmark)
Hu, C.M.; Nitta, J.; Jensen, Ane;
2002-01-01
We present a model that describes the spin injection across a single interface with two electrodes. The spin-injection rate across a typical hybrid junction made of ferromagnet (FM) and a two-dimensional electron gas (2DEG) is found at the percentage level. We perforin spin-injection-detection ex......-injection-detection experiment on devices with two ferromagnetic contacts on a 2DEG confined in an InAs quantum well. A spin-injection rate of 4.5% is estimated from the measured magnetoresistance....
Quantum spin-glass transition in the two-dimensional electron gas
Indian Academy of Sciences (India)
Subir Sachdev
2002-02-01
We discuss the possibility of spin-glass order in the vicinity of the unexpected metallic state of the two-dimensional electron gas in zero applied magnetic ﬁeld. An average ferromagnetic moment may also be present, and the spin-glass order then resides in the plane orthogonal to the ferromagnetic moment. We argue that a quantum transition involving the destruction of the spin-glass order in an applied in-plane magnetic ﬁeld offers a natural explanation of some features of recent magnetoconductance measurements. We present a quantum ﬁeld theory for such a transition and compute its mean ﬁeld properties.
Energy Technology Data Exchange (ETDEWEB)
Lo, C. C.; Lang, V.; George, R. E.; Morton, J. J. L.; Tyryshkin, A. M.; Lyon, A.; Bokor, J.; Schenkel, T.
2011-04-20
We have measured the electrically detected magnetic resonance of donor-doped silicon field-effect transistors in resonant X- (9.7 GHz) and W-band (94 GHz) microwave cavities. The two-dimensional electron gas (2DEG) resonance signal increases by two orders of magnitude from X- to W-band, while the donor resonance signals are enhanced by over one order of magnitude. Bolometric effects and spin-dependent scattering are inconsistent with the observations. We propose that polarization transfer from the donor to the 2DEG is the main mechanism giving rise to the spin resonance signals.
Photon-assisted spin transport in a two-dimensional electron gas
Fistul, M. V.; Efetov, K. B.
2007-01-01
We study spin-dependent transport in a two-dimensional electron gas subject to an external step-like potential $V(x)$ and irradiated by an electromagnetic field (EF). In the absence of EF the electronic spectrum splits into spin sub-bands originating from the "Rashba" spin-orbit coupling. We show that the resonant interaction of propagating electrons with the component EF parallel to the barrier induces a \\textit{% non-equilibrium dynamic gap} $(2\\Delta_{R})$ between the spin sub-bands. Exist...
Thermodynamic magnetization of two-dimensional electron gas measured over wide range of densities
Reznikov, M.; Kuntsevich, A. Yu.; Teneh, N.; Pudalov, V. M.
2011-01-01
We report measurements of dm/dn in Si MOSFET, where m is the magnetization of the two-dimensional electron gas and n is its density. We extended the density range of measurements from well in the metallic to deep in the insulating region. The paper discusses in detail the conditions under which this extension is justified, as well as the corrections one should make to extract dm/dn properly. At low temperatures, dm/dn was found to be strongly nonlinear already in weak magnetic fields, on a sc...
Andreev, Pavel A
2016-01-01
Hydrodynamics analysis of waves in two-dimensional degenerate electron gas with the account of separate spin evolution is presented. The transverse electric field is included along with the longitudinal electric field. The Coulomb exchange interaction is included in the analysis. In contrast with the three-dimensional plasma-like mediums the contribution of the transverse electric field is small. We show the decrease of frequency of both the extraordinary (Langmuir) wave and the spin-electron acoustic wave due to the exchange interaction. Moreover, spin-electron acoustic wave has negative dispersion at the relatively large spin-polarization. Corresponding dispersion dependencies are presented and analyzed.
Institute of Scientific and Technical Information of China (English)
WANG Ru-Zhi; YAN Xiao-Hong
2000-01-01
By developing a transfer-matrix method, the resonant peaks splitting of ballistic conductance are investigated into the two-dimensional electron gas system with both electric and magnetic modulations of nanoscale periods. It is found that there exists the n-fold resonant peak splitting for ballistic conductance through n perpendicular magnetic barriers to n electric barriers. With a combination of m magnetic barriers and n electric barriers by increasing the amplitude of electric field, the folds of the splitting would shift from m － 1 to n － 1.
The two-dimensional alternative binary L-J system: liquid-gas phase diagram
Institute of Scientific and Technical Information of China (English)
张陟; 陈立溁
2003-01-01
A two-dimensional (2D) binary system without considering the Lennard-Jones (L-J) potential has been studied by using the Collins model. In this paper, we introduce the L-J potential into the 2D binary system and consider the existence of the holes that are called the "molecular fraction". The liquid-gas phase diagram of the 2D alternative binary L-J system is obtained. The results are quite analogous to the behaviour of 3D substances.
Diffusivity and weak clustering in a quasi-two-dimensional granular gas.
Perera-Burgos, J A; Pérez-Ángel, G; Nahmad-Molinari, Y
2010-11-01
We present results from a detailed simulation of a quasi-two-dimensional dissipative granular gas, kept in a noncondensed steady state via vertical shaking over a rough substrate. This gas shows a weak power-law decay in the tails of its pair distribution functions, indicating clustering. This clustering depends monotonically on the dissipation coefficient and disappears when the sphere-sphere collisions are conservative. Clustering is also sensitive to the packing fraction. This gas also displays the standard nonequilibrium characteristics of similar systems, including non-Maxwellian velocity distributions. The diffusion coefficients are calculated over all the conditions of the simulations, and it is found that diluted gases are more diffusive for smaller restitution coefficients.
Response Functions for the Two-Dimensional Ultracold Fermi Gas: Dynamical BCS Theory and Beyond
Vitali, Ettore; Shi, Hao; Qin, Mingpu; Zhang, Shiwei
2017-08-01
Response functions are central objects in physics. They provide crucial information about the behavior of physical systems, and they can be directly compared with scattering experiments involving particles such as neutrons or photons. Calculations of such functions starting from the many-body Hamiltonian of a physical system are challenging and extremely valuable. In this paper, we focus on the two-dimensional (2D) ultracold Fermi atomic gas which has been realized experimentally. We present an application of the dynamical BCS theory to obtain response functions for different regimes of interaction strengths in the 2D gas with zero-range attractive interaction. We also discuss auxiliary-field quantum Monte Carlo (AFQMC) methods for the calculation of imaginary time correlations in these dilute Fermi gas systems. Illustrative results are given and comparisons are made between AFQMC and dynamical BCS theory results to assess the accuracy of the latter.
Shear viscosity and spin-diffusion coefficient of a two-dimensional Fermi gas
DEFF Research Database (Denmark)
Bruun, Georg
2012-01-01
Using kinetic theory, we calculate the shear viscosity and the spin-diffusion coefficient as well as the associated relaxation times for a two-component Fermi gas in two dimensions, as a function of temperature, coupling strength, polarization, and mass ratio of the two components. It is demonstr......Using kinetic theory, we calculate the shear viscosity and the spin-diffusion coefficient as well as the associated relaxation times for a two-component Fermi gas in two dimensions, as a function of temperature, coupling strength, polarization, and mass ratio of the two components....... It is demonstrated that the minimum value of the viscosity decreases with the mass ratio, since Fermi blocking becomes less efficient. We furthermore analyze recent experimental results for the quadrupole mode of a two-dimensional gas in terms of viscous damping, obtaining a qualitative agreement using no fitting...
Device for two-dimensional gas-phase separation and characterization of ion mixtures
Tang, Keqi; Shvartsburg, Alexandre A.; Smith, Richard D.
2006-12-12
The present invention relates to a device for separation and characterization of gas-phase ions. The device incorporates an ion source, a field asymmetric waveform ion mobility spectrometry (FAIMS) analyzer, an ion mobility spectrometry (IMS) drift tube, and an ion detector. In one aspect of the invention, FAIMS operating voltages are electrically floated on top of the IMS drift voltage. In the other aspect, the FAIMS/IMS interface is implemented employing an electrodynamic ion funnel, including in particular an hourglass ion funnel. The present invention improves the efficiency (peak capacity) and sensitivity of gas-phase separations; the online FAIMS/IMS coupling creates a fundamentally novel two-dimensional gas-phase separation technology with high peak capacity, specificity, and exceptional throughput.
Energy Technology Data Exchange (ETDEWEB)
Dai Jian [Theory Group, Department of Physics, Peking University, Beijing (China)]. E-mail: jdai@mail.phy.pku.edu.cn; Song Xingchang [Theory Group, Department of Physics, Peking University, Beijing (China)]. E-mail: songxc@ibm320h.phy.pku.edu.cn
2001-07-13
One of the key ingredients of Connes's noncommutative geometry is a generalized Dirac operator which induces a metric (Connes's distance) on the pure state space. We generalize such a Dirac operator devised by Dimakis et al, whose Connes distance recovers the linear distance on an one-dimensional lattice, to the two-dimensional case. This Dirac operator has the local eigenvalue property and induces a Euclidean distance on this two-dimensional lattice, which is referred to as 'natural'. This kind of Dirac operator can be easily generalized into any higher-dimensional lattices. (author)
Finite-Difference Lattice Boltzmann Scheme for High-Speed Compressible Flow: Two-Dimensional Case
Gan, Yan-Biao; Xu, Ai-Guo; Zhang, Guang-Cai; Zhang, Ping; Zhang, Lei; Li, Ying-Jun
2008-07-01
Lattice Boltzmann (LB) modeling of high-speed compressible flows has long been attempted by various authors. One common weakness of most of previous models is the instability problem when the Mach number of the flow is large. In this paper we present a finite-difference LB model, which works for flows with flexible ratios of specific heats and a wide range of Mach number, from 0 to 30 or higher. Besides the discrete-velocity-model by Watari [Physica A 382 (2007) 502], a modified Lax Wendroff finite difference scheme and an artificial viscosity are introduced. The combination of the finite-difference scheme and the adding of artificial viscosity must find a balance of numerical stability versus accuracy. The proposed model is validated by recovering results of some well-known benchmark tests: shock tubes and shock reflections. The new model may be used to track shock waves and/or to study the non-equilibrium procedure in the transition between the regular and Mach reflections of shock waves, etc.
Oh, Joosung; Le, Manh Duc; Jeong, Jaehong; Lee, Jung-hyun; Woo, Hyungje; Song, Wan-Young; Perring, T. G.; Buyers, W. J. L.; Cheong, S.-W.; Park, Je-Geun
2013-12-01
The breakdown of magnons, the quasiparticles of magnetic systems, has rarely been seen. By using an inelastic neutron scattering technique, we report the observation of spontaneous magnon decay in multiferroic LuMnO3, a simple two dimensional Heisenberg triangular lattice antiferromagnet, with large spin S=2. The origin of this rare phenomenon lies in the nonvanishing cubic interaction between magnons in the spin Hamiltonian arising from the noncollinear 120° spin structure. We observed all three key features of the nonlinear effects as theoretically predicted: a rotonlike minimum, a flat mode, and a linewidth broadening, in our inelastic neutron scattering measurements of single crystal LuMnO3. Our results show that quasiparticles in a system hitherto thought of as “classical” can indeed break down.
Oh, Joosung; Le, Manh Duc; Jeong, Jaehong; Lee, Jung-hyun; Woo, Hyungje; Song, Wan-Young; Perring, T G; Buyers, W J L; Cheong, S-W; Park, Je-Geun
2013-12-20
The breakdown of magnons, the quasiparticles of magnetic systems, has rarely been seen. By using an inelastic neutron scattering technique, we report the observation of spontaneous magnon decay in multiferroic LuMnO3, a simple two dimensional Heisenberg triangular lattice antiferromagnet, with large spin S=2. The origin of this rare phenomenon lies in the nonvanishing cubic interaction between magnons in the spin Hamiltonian arising from the noncollinear 120° spin structure. We observed all three key features of the nonlinear effects as theoretically predicted: a rotonlike minimum, a flat mode, and a linewidth broadening, in our inelastic neutron scattering measurements of single crystal LuMnO3. Our results show that quasiparticles in a system hitherto thought of as "classical" can indeed break down.
Ochiai, Tetsuyuki
2016-01-01
We show the presence of Floquet-Weyl and Floquet-topological-insulator phases in a stacked two-dimensional ring-network lattice. The Weyl points in the three-dimensional Brillouin zone and Fermi-arc surface states are clearly demonstrated in the quasienergy spectrum of the system in the Weyl phase. In addition, chiral surface states coexist in this phase. The Floquet-topological-insulator phase is characterized by the winding number of two in the reflection matrices of the semi-infinite system and resulting two gapless surface states in the quasienergy g ap of the bulk. The phase diagram of the system is derived in the two-parameter space of hopping S-matrices among the rings. We also discuss a possible optical realization of the system together with the introduction of synthetic gauge fields.
Energy Technology Data Exchange (ETDEWEB)
Xi, Kui-Tian, E-mail: kuitianxi@gmail.com; Li, Jinbin, E-mail: jinbin@nuaa.edu.cn; Shi, Da-Ning, E-mail: shi@nuaa.edu.cn
2014-03-01
We consider a weakly interacting two-component Bose–Einstein condensate (BEC) in a two-dimensional (2D) quasi-periodic bichromatic optical lattice (BOL). The problem is studied by means of split-step Crank–Nicolson method. The effects of weak intra- and inter-component interactions on localization of a two-component BEC are investigated. It is shown that in the quasi-2D regime, due to the enhanced disorder, there is no symmetry breaking like that in the one-dimensional (1D) case under a sine-typed potential, while configurations of density profiles are also quite different from that in the 1D case. By modulating interactions, the interplay of disorder and weak repulsive or attractive interactions is studied in detail. The cases with sine- and cosine-typed potentials acting on components 1 and 2 respectively are also discussed.
Montgomery, R. C.; Sundararajan, N.
1984-01-01
It is doubtful whether the dynamics of large space structures (LSS) can be predicted well enough for control system design applications. Hence, dynamic modeling from on-orbit measurements followed by a modification of the control system is of interest, taking into account the utilization of adaptive control concepts. The present paper is concerned with the model determination phase of the adaptive control problem. Using spectral decoupling to determine mode shapes, mode frequency and damping data can be obtained with the aid of an equation error parameter identification method. This method employs a second-order auto-regressive moving average (ARMA) model to represent the natural mode amplitudes. The discussed procedure involves an extension of the application of the least square lattice filter in system identification to a nonintegral, two-dimensional grid structure made of overlapping bars.
Ochiai, Tetsuyuki
2016-10-01
We show the presence of Floquet-Weyl and Floquet-topological-insulator phases in a stacked two-dimensional ring-network lattice. The Weyl points in the three-dimensional Brillouin zone and Fermi-arc surface states are clearly demonstrated in the quasienergy spectrum of the system in the Floquet-Weyl phase. In addition, chiral surface states coexist in this phase. The Floquet-topological-insulator phase is characterized by the winding number of two in the reflection matrices of the semi-infinite system and resulting two gapless surface states in the quasienergy gap of the bulk. The phase diagram of the system is derived in the two-parameter space of hopping S-matrices among the rings. We also discuss a possible optical realization of the system together with the introduction of synthetic gauge fields.
Institute of Scientific and Technical Information of China (English)
LI Hua-Bing; JIN Li; QIU Bing
2008-01-01
To study two-dimensional red blood cells deforming in a shear flow with the membrane nonuniform on the rigidity and mass, the membrane is discretized into equilength segments. The fluid inside and outside the red blood cell is simulated by the D2Q9 lattice Boltzmann model and the hydrodynamic forces exerted on the membrane from the inner and outer of the red blood cell are calculated by a stress-integration method. Through the global deviation from the curvature of uniform-membrane, we find that when the membrane is nonuniform on the rigidity, the deviation first decreases with the time increases and implies that the terminal profile of the red blood cell is static. To a red blood cell with the mass nonuniform on the membrane, the deviation becomes more large, and the mass distribution affects the profile of the two sides of the flattened red blood cell in a shear flow.
A novel two-dimensional MgB6 crystal: metal-layer stabilized boron kagome lattice.
Xie, Sheng-Yi; Li, Xian-Bin; Tian, Wei Quan; Chen, Nian-Ke; Wang, Yeliang; Zhang, Shengbai; Sun, Hong-Bo
2015-01-14
Based on first-principles calculations, we designed for the first time a boron-kagome-based two-dimensional MgB6 crystal, in which two boron kagome layers sandwich a triangular magnesium layer. The two-dimensional lattice is metallic with several bands across the Fermi level, and among them a Dirac point appears at the K point of the first Brillouin zone. This metal-stabilized boron kagome system displays electron-phonon coupling, with a superconductivity critical transition temperature of 4.7 K, and thus it is another possible superconducting Mg-B compound besides MgB2. Furthermore, the proposed 2D MgB6 can also be used for hydrogen storage after decoration with Ca. Up to five H2 molecules can be attracted by one Ca with an average binding energy of 0.225 eV. The unique properties of 2D MgB6 will spur broad interest in nanoscience and technology.
Phase correlations and quasicondensate in a two-dimensional ultracold Fermi gas
Energy Technology Data Exchange (ETDEWEB)
Tempere, J., E-mail: jacques.tempere@uantwerpen.be [Theory of Quantum and Complex Systems, Universiteit Antwerpen, Universiteitsplein 1, B-2610 Antwerpen (Belgium); Lyman Laboratory of Physics, Harvard University, Cambridge, MA 02138 (United States); Klimin, S.N. [Theory of Quantum and Complex Systems, Universiteit Antwerpen, Universiteitsplein 1, B-2610 Antwerpen (Belgium)
2015-02-15
The interplay between dimensionality, coherence and interaction in superfluid Fermi gases is analyzed by the phase correlation function of the field of fermionic pairs. We calculate this phase correlation function for a two-dimensional superfluid Fermi gas with s-wave interactions within the Gaussian pair fluctuation formalism. The spatial behavior of the correlation function is shown to exhibit a rapid (exponential) decay at short distances and a characteristic algebraic decay at large distances, with an exponent matching that expected from the Berezinskii–Kosterlitz–Thouless theory of 2D Bose superfluids. We conclude that the Gaussian pair fluctuation approximation is able to capture the physics of quasi-long-range order in two-dimensional Fermi gases. - Highlights: • The phase correlation functions for an ultracold Fermi gas in 2D are calculated. • The decay of the correlation functions is algebraic at long distances. • The Gaussian pair fluctuation approach is shown to capture the quasicondensate physics in 2D Fermi gases.
Bubble dynamics in a two-dimensional gas-solid fluidized bed
Institute of Scientific and Technical Information of China (English)
无
2007-01-01
Related referential studies on gas-solid two-phase flows were briefly reviewed. Bubble ascending in a two-dimensional (2D) gas-solid fluidized bed was studied both experimentally and numerically. A modified continuum model expressed in the conservation form was used in numerical simulation. Solid-phase pressure was modeled via local sound speed; gas-phase turbulence was described by the K-ε two-equation model. The modified implicit multiphase formulation (IMF) scheme was used to solve the model equations in 2D Cartesian/cylindrical coordinates. The bubble ascending velocity and particle motion in the 2D fluidized bed were measured using the photochromic dye activation (PDA) technique, which was based on UV light activation of particles impregnated with the dye. Effects of bed height and superficial gas velocity on bubble formation and ascent were investigated numerically. The numerically obtained bubble ascending velocities were compared with experimental measurements. Gas bubble in jetting gas-solids fluidized bed was also simulated numerically.
Properties of two-dimensional electron gas containing self-organized quantum antidots
Vasilyev, Yu.; Suchalkin, S.; Zundel, M.; Heisenberg, D.; Eberl, K.; von Klitzing, K.
1999-11-01
A nonuniform two-dimensional electron gas in a heterojunction with inserted self-organized electrically inactive dots (acting as antidots) has been fabricated by molecular-beam epitaxy of AlGaAs/AlInAs/GaAs layer sequences. Transport measurements give the ratio of the transport mobility to the quantum mobility less than four, which suggests that the dominant scattering at low magnetic fields is the short-range scattering from the lateral potential of the antidots. Far-infrared cyclotron resonance (CR) spectra show an absorption mode as narrow as 0.5 cm-1 at high magnetic fields associated with the high-mobility electron gas formed between the antidot islands and confined in the lateral directions. The confinement energy of 14 cm-1 is derived from the CR spectra.
Zeng, Jianhua
2013-01-01
It is commonly known that stable bright solitons in periodic potentials, which represent gratings in photonics/plasmonics, or optical lattices in quantum gases, exist either in the spectral semi-infinite gap (SIG) or in finite bandgaps. Using numerical methods, we demonstrate that, under the action of the cubic self-focusing nonlinearity, defects in the form of "holes" in two-dimensional (2D) lattices support continuous families of 2D solitons \\textit{embedded} into the first two Bloch bands of the respective linear spectrum, where solitons normally do not exist. The two families of the \\textit{embedded defect solitons} (EDSs) are found to be continuously linked by the branch of \\textit{gap defect solitons} (GDSs) populating the first finite bandgap. Further, the EDS branch traversing the first band links the GDS family with the branch of regular defect-supported solitons populating the SIG. Thus, we construct a continuous chain of regular, embedded, and gap-mode solitons ("superfamily") threading the entire ...
Two-dimensional O(3) model at nonzero density: From dual lattice simulations to repulsive bosons
Bruckmann, Falk; Gattringer, Christof; Kloiber, Thomas; Sulejmanpasic, Tin
2016-12-01
We discuss the thermodynamics of the O(3) nonlinear sigma model in 1 +1 dimensions at nonzero chemical potential (equivalent to a magnetic field). In its conventional field theory representation the model suffers from a sign problem. By dualizing the model, we are able to fully access the nonzero density regime of an asymptotically free theory with dynamical mass gap at arbitrary chemical potential values. We find a quantum phase transition at zero temperature where as a function of the chemical potential the density assumes a nonzero value. Measuring the spin stiffness we present evidence for a corresponding dynamical critical exponent z close to 2. The low energy O(3) model is conjectured to be described by a massive boson triplet with repulsive interactions. We confirm the universal square-root behavior expected for such a system at low density (and temperature) and compare our data to the results of Bethe Ansatz solutions of the relativistic and nonrelativistic one-dimensional Bose gas. We also comment on a potential Berezinskii-Kosterlitz-Thouless transition at nonzero density.
Directory of Open Access Journals (Sweden)
K.-P. Heue
2008-11-01
Full Text Available In many investigations of tropospheric chemistry information about the two dimensional distribution of trace gases on a small scale (e.g. tens to hundreds of metres is highly desirable. An airborne instrument based on imaging Differential Optical Absorption Spectroscopy has been built to map the two dimensional distribution of a series of relevant trace gases including NO_{2}, HCHO, C_{2}H_{2}O_{2}, H_{2}O, O_{4}, SO_{2}, and BrO on a scale of 100 m.
Here we report on the first tests of the novel aircraft instrument over the industrialised South African Highveld, where large variations in NO_{2} column densities in the immediate vicinity of several sources e.g. power plants or steel works, were measured. The observed patterns in the trace gas distribution are interpreted with respect to flux estimates, and it is seen that the fine resolution of the measurements allows separate sources in close proximity to one another to be distinguished.
D'Archivio, Angelo Antonio; Incani, Angela; Ruggieri, Fabrizio
2011-01-01
In this paper, we use a quantitative structure-retention relationship (QSRR) method to predict the retention times of polychlorinated biphenyls (PCBs) in comprehensive two-dimensional gas chromatography (GC×GC). We analyse the GC×GC retention data taken from the literature by comparing predictive capability of different regression methods. The various models are generated using 70 out of 209 PCB congeners in the calibration stage, while their predictive performance is evaluated on the remaining 139 compounds. The two-dimensional chromatogram is initially estimated by separately modelling retention times of PCBs in the first and in the second column ((1) t (R) and (2) t (R), respectively). In particular, multilinear regression (MLR) combined with genetic algorithm (GA) variable selection is performed to extract two small subsets of predictors for (1) t (R) and (2) t (R) from a large set of theoretical molecular descriptors provided by the popular software Dragon, which after removal of highly correlated or almost constant variables consists of 237 structure-related quantities. Based on GA-MLR analysis, a four-dimensional and a five-dimensional relationship modelling (1) t (R) and (2) t (R), respectively, are identified. Single-response partial least square (PLS-1) regression is alternatively applied to independently model (1) t (R) and (2) t (R) without the need for preliminary GA variable selection. Further, we explore the possibility of predicting the two-dimensional chromatogram of PCBs in a single calibration procedure by using a two-response PLS (PLS-2) model or a feed-forward artificial neural network (ANN) with two output neurons. In the first case, regression is carried out on the full set of 237 descriptors, while the variables previously selected by GA-MLR are initially considered as ANN inputs and subjected to a sensitivity analysis to remove the redundant ones. Results show PLS-1 regression exhibits a noticeably better descriptive and predictive
A two-dimensional position sensitive gas chamber with scanned charge transfer readout
Gómez, F.; Iglesias, A.; Lobato, R.; Mosquera, J.; Pardo, J.; Pena, J.; Pazos, A.; Pombar, M.; Rodríguez, A.
2003-10-01
We have constructed and tested a two-dimensional position sensitive parallel-plate gas ionization chamber with scanned charge transfer readout. The scan readout method described here is based on the development of a new position-dependent charge transfer technique. It has been implemented by using gate strips perpendicularly oriented to the collector strips. This solution reduces considerably the number of electronic readout channels needed to cover large detector areas. The use of a 25 μm thick kapton etched circuit allows high charge transfer efficiency with a low gating voltage, consequently needing a very simple commutating circuit. The present prototype covers 8×8 cm2 with a pixel size of 1.27×1.27 mm2. Depending on the intended use and beam characteristics a smaller effective pixel is feasible and larger active areas are possible. This detector can be used for X-ray or other continuous beam intensity profile monitoring.
Hydrodynamics for a model of a confined quasi-two-dimensional granular gas.
Brey, J Javier; Buzón, V; Maynar, P; García de Soria, M I
2015-05-01
The hydrodynamic equations for a model of a confined quasi-two-dimensional gas of smooth inelastic hard spheres are derived from the Boltzmann equation for the model, using a generalization of the Chapman-Enskog method. The heat and momentum fluxes are calculated to Navier-Stokes order, and the associated transport coefficients are explicitly determined as functions of the coefficient of normal restitution and the velocity parameter involved in the definition of the model. Also an Euler transport term contributing to the energy transport equation is considered. This term arises from the gradient expansion of the rate of change of the temperature due to the inelasticity of collisions, and it vanishes for elastic systems. The hydrodynamic equations are particularized for the relevant case of a system in the homogeneous steady state. The relationship with previous works is analyzed.
Modulation techniques and applications in comprehensive two-dimensional gas chromatography (GC x GC)
Energy Technology Data Exchange (ETDEWEB)
Pursch, Matthias [Dow Deutschland GmbH and Co. OHG, Analytical Sciences, 77836 Rheinmuenster (Germany); Sun, Kefu; Winniford, Bill; Weber, Andy [Dow Chemical Company, Analytical Sciences, Freeport, TX 77541 (United States); Cortes, Hernan; McCabe, Terry [Dow Chemical Company, Analytical Sciences, Midland MI 48667 (United States); Luong, Jim [Dow Canada, Analytical Sciences, Fort Saskatchewan (Canada)
2002-07-01
More than a decade after Phillips' first published work this article reviews recent developments in comprehensive two-dimensional gas chromatography (GC x GC). Special attention is devoted to the further development and diversity of modulation devices. These include heated sweepers, cryofocused modulators, and a variety of diaphragm valve-switching strategies. It is demonstrated that all modulation approaches can be very well suited to GC x GC, depending on the particular application. Diaphragm-valve modulation is very powerful for volatile organic compounds. Slotted heater and cryofocused modulation are preferred for samples that contain non-volatile components. Applications ranging from petroleum to environmental and biological samples are illustrated. Extension of the technique to GC x GC-mass spectrometry (MS) is also discussed and trends for future research activity are pointed out. (orig.)
Gas-kinetic numerical schemes for one- and two-dimensional inner flows
Institute of Scientific and Technical Information of China (English)
Zhi-hui LI; Lin BI; Zhi-gong TANG
2009-01-01
Several kinds of explicit and implicit finite-difference schemes directly solving the discretized velocity distribution functions are designed with precision of different orders by analyzing the inner characteristics of the gas-kinetic numerical algorithm for Boltzmann model equation.The peculiar flow phenomena and mechanism from various flow regimes are revealed in the numerical simulations of the unsteady Sod shock-tube problems and the two-dimensional channel flows with different Knudsen numbers.The numerical remainder-effects of the difference schemes are investigated and analyzed based on the computed results.The ways of improving the computational efficiency of the gaskinetic numerical method and the computing principles of difference discretization are discussed.
Automated multivariate analysis of comprehensive two-dimensional gas chromatograms of petroleum
DEFF Research Database (Denmark)
Skov, Søren Furbo
Petroleum is an economically and industrially important resource. Crude oil must be refined before use to ensure suitable properties of the product. Among the processes used in this refining is distillation and desulfurization. In order to optimize these processes, it is essential to understand...... them. Comprehensive two-dimensional gas chromatography (GCGC) is a method for analyzing the volatile parts of a sample. It can separate hundreds or thousands of compounds based on their boiling point, polarity and polarizability. This makes it ideally suited for petroleum analysis. The number...... impossible to find it. For a special class of models, multi-way models, unique solutions often exist, meaning that the underlying phenomena can be found. I have tested this class of models on GCGC data from petroleum and conclude that more work is needed before they can be automated. I demonstrate how...
Cavity quantum electrodynamics with many-body states of a two-dimensional electron gas.
Smolka, Stephan; Wuester, Wolf; Haupt, Florian; Faelt, Stefan; Wegscheider, Werner; Imamoglu, Ataç
2014-10-17
Light-matter interaction has played a central role in understanding as well as engineering new states of matter. Reversible coupling of excitons and photons enabled groundbreaking results in condensation and superfluidity of nonequilibrium quasiparticles with a photonic component. We investigated such cavity-polaritons in the presence of a high-mobility two-dimensional electron gas, exhibiting strongly correlated phases. When the cavity was on resonance with the Fermi level, we observed previously unknown many-body physics associated with a dynamical hole-scattering potential. In finite magnetic fields, polaritons show distinct signatures of integer and fractional quantum Hall ground states. Our results lay the groundwork for probing nonequilibrium dynamics of quantum Hall states and exploiting the electron density dependence of polariton splitting so as to obtain ultrastrong optical nonlinearities.
Fermi liquid-to-Bose condensate crossover in a two-dimensional ultracold gas experiment
Barmashova, T. V.; Mart'yanov, K. A.; Makhalov, V. B.; Turlapov, A. V.
2016-02-01
By controling interparticle interactions, it is possible to transform a fermionic system into a bosonic system and vice versa, while preserving quantum degeneracy. Evidence of such a transformation may be found by monitoring the pressure and interference. The Fermi pressure is an indication of the fermion?ic character of a system, while the interference implies a nonzero order parameter and Bose condensation. Lowering from three to two spatial dimensions introduces new physics and makes the system more difficult to describe due to the increased fluctuations and the reduced applicability of mean field methods. An experiment with a two-dimensional ultracold atomic gas shows a crossover between the Bose and Fermi limits, as evident from the value of pressure and from the interference pattern, and provides data to test models of 2D Fermi and Bose systems, including the most-difficult-to-model strongly coupled systems.
Terahertz Radiation Heterodyne Detector Using Two-Dimensional Electron Gas in a GaN Heterostructure
Karasik, Boris S.; Gill, John J.; Mehdi, Imran; Crawford, Timothy J.; Sergeev, Andrei V.; Mitin, Vladimir V.
2012-01-01
High-resolution submillimeter/terahertz spectroscopy is important for studying atmospheric and interstellar molecular gaseous species. It typically uses heterodyne receivers where an unknown (weak) signal is mixed with a strong signal from the local oscillator (LO) operating at a slightly different frequency. The non-linear mixer devices for this frequency range are unique and are not off-the-shelf commercial products. Three types of THz mixers are commonly used: Schottky diode, superconducting hot-electron bolometer (HEB), and superconductor-insulation-superconductor (SIS) junction. A HEB mixer based on the two-dimensional electron gas (2DEG) formed at the interface of two slightly dissimilar semiconductors was developed. This mixer can operate at temperatures between 100 and 300 K, and thus can be used with just passive radiative cooling available even on small spacecraft.
Hidden long-range order in a two-dimensional spin-orbit coupled Bose gas
Su, Shih-Wei; Gou, Shih-Chuan; Liao, Renyuan; Fialko, Oleksandr; Brand, Joachim
2016-01-01
A two-dimensional spin-orbit coupled Bose gas is shown to simultaneously possess quasi and true long-range orders in the total and relative phases, respectively. The total phase undergoes a conventional Berenzinskii- Kosterlitz-Thouless transition, where an quasi long-range order is expected. Additionally, the relative phase undergoes an Ising-type transition building up true long-range order, which is induced by the anisotropic spin- orbit coupling. Based on the Bogoliubov approach, expressions for the total- and relative-phase fluctuations are derived analytically for the low temperature regime. Numerical simulations of the stochastic projected Gross- Pitaevskii equation give a good agreement with the analytical predictions.
Energy Technology Data Exchange (ETDEWEB)
Masaoka, Sei; Nakamura, Tatsuya; Yamagishi, Hideshi; Soyama, Kazuhiko [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment
2002-02-01
A micro-strip gas chamber (MSGC) has been developing as a two-dimensional position sensitive neutron detector for neutron scattering experiments using high-intensity pulsed-neutron source in a high-intensity proton accelerator facility. MSGC is required for the high count rate, high detective efficiency, high positional resolution, stabilization and covering large area. Our purpose in this paper is to verify the proper of Gadolinium as MSGC converter. First, the basic property of Gadolinium converter was examined by simple experiments using a zero-dimensional neutron detector on the purpose of deriving the detective efficiency. Second, the optimization of the arrangement of a capillary plate in MSGC has been done by simulation on the MSGC using Gadolinium converter. As a result of that, it has been proved that Gadolinium can be theoretically used as a converter of MSGC. (author)
Liu, Rongqiang; Zhao, Haojiang; Zhang, Yingying; Guo, Honghwei; Deng, Zongquan
2015-12-01
The plane wave expansion (PWE) method is used to calculate the band gaps of two-dimensional (2D) phononic crystals (PCs) with a hybrid square-like (HSL) lattice. Band structures of both XY-mode and Z-mode are calculated. Numerical results show that the band gaps between any two bands could be maximized by altering the radius ratio of the inclusions at different positions. By comparing with square lattice and bathroom lattice, the HSL lattice is more efficient in creating larger gaps.
Energy Technology Data Exchange (ETDEWEB)
Mahato, Bipul Kumar; Rana, Bivas; Kumar, Dheeraj; Barman, Saswati; Barman, Anjan, E-mail: abarman@bose.res.in [Thematic Unit of Excellence on Nanodevice Technology, Department of Condensed Matter Physics and Material Sciences, S. N. Bose National Centre for Basic Sciences, Block JD, Sector III, Salt Lake, Kolkata 700098 (India); Sugimoto, Satoshi [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Otani, YoshiChika [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); CEMS-RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan)
2014-07-07
We demonstrate tunable spin wave spectrum in two-dimensional Ni{sub 80}Fe{sub 20} nanodot lattices by varying dot shape. A single collective mode in elliptical dot lattices transforms into three distinct modes for the half-elliptical, rectangular, and diamond dot lattices, albeit with different peak frequencies and intensities. A drastic change is observed for the triangular dots, where eight modes covering a broad band are observed. Using micromagnetic simulations, we characterized the modes as different localized, extended, and quantized modes, whose frequencies and spatial profiles are determined by a combination of internal field profiles within the nanodots and the stray magnetic field within the lattice.
Thermalization of a two-dimensional photon gas in a polymeric host matrix
Schmitt, Julian; Damm, Tobias; Vewinger, Frank; Weitz, Martin; Klaers, Jan
2012-07-01
We investigate thermodynamic properties of a two-dimensional photon gas confined by a dye-filled optical microcavity. A thermally equilibrated state of the photon gas is achieved by radiative coupling to a heat bath that is realized with dye molecules embedded in a polymer at room temperature. The chemical potential of the gas is freely adjustable. The optical microcavity consisting of two curved mirrors induces both a non-vanishing effective photon mass and a harmonic trapping potential for the photons. While previous experiments of our group have used liquid dye solutions, the measurements described here are based on dye molecules incorporated into a polymer host matrix. The solid state material allows a simplified operation of the experimental scheme. We furthermore describe studies of fluorescence properties of dye-doped polymers, and verify the applicability of Kennard-Stepanov theory in this system. In the future, dye-based solid state systems hold promise for the realization of single-mode light sources in thermal equilibrium based on Bose-Einstein condensation of photons, as well as for solar energy concentrators.
Halliday, I; Xu, X; Burgin, K
2017-02-01
An extended Benzi-Dellar lattice Boltzmann equation scheme [R. Benzi, S. Succi, and M. Vergassola, Europhys. Lett. 13, 727 (1990)EULEEJ0295-507510.1209/0295-5075/13/8/010; R. Benzi, S. Succi, and M. Vergassola, Phys. Rep. 222, 145 (1992)PRPLCM0370-157310.1016/0370-1573(92)90090-M; P. J. Dellar, Phys. Rev. E 65, 036309 (2002)1063-651X10.1103/PhysRevE.65.036309] is developed and applied to the problem of confirming, at low Re and drop fluid concentration, c, the variation of effective shear viscosity, η_{eff}=η_{1}[1+f(η_{1},η_{2})c], with respect to c for a sheared, two-dimensional, initially crystalline emulsion [here η_{1} (η_{2}) is the fluid (drop fluid) shear viscosity]. Data obtained with our enhanced multicomponent lattice Boltzmann method, using average shear stress and hydrodynamic dissipation, agree well once appropriate corrections to Landau's volume average shear stress [L. Landau and E. M. Lifshitz, Fluid Mechanics, 6th ed. (Pergamon, London, 1966)] are applied. Simulation results also confirm the expected form for f(η_{i},η_{2}), and they provide a reasonable estimate of its parameters. Most significantly, perhaps, the generality of our data supports the validity of Taylor's disputed simplification [G. I. Taylor, Proc. R. Soc. London, Ser. A 138, 133 (1932)1364-502110.1098/rspa.1932.0175] to reduce the effect of one hydrodynamic boundary condition (on the continuity of the normal contraction of stress) to an assumption that interfacial tension is sufficiently strong to maintain a spherical drop shape.
Halliday, I.; Xu, X.; Burgin, K.
2017-02-01
An extended Benzi-Dellar lattice Boltzmann equation scheme [R. Benzi, S. Succi, and M. Vergassola, Europhys. Lett. 13, 727 (1990), 10.1209/0295-5075/13/8/010; R. Benzi, S. Succi, and M. Vergassola, Phys. Rep. 222, 145 (1992), 10.1016/0370-1573(92)90090-M; P. J. Dellar, Phys. Rev. E 65, 036309 (2002), 10.1103/PhysRevE.65.036309] is developed and applied to the problem of confirming, at low Re and drop fluid concentration, c , the variation of effective shear viscosity, ηeff=η1[1 +f (η1,η2) c ] , with respect to c for a sheared, two-dimensional, initially crystalline emulsion [here η1 (η2) is the fluid (drop fluid) shear viscosity]. Data obtained with our enhanced multicomponent lattice Boltzmann method, using average shear stress and hydrodynamic dissipation, agree well once appropriate corrections to Landau's volume average shear stress [L. Landau and E. M. Lifshitz, Fluid Mechanics, 6th ed. (Pergamon, London, 1966)] are applied. Simulation results also confirm the expected form for f (ηi,η2) , and they provide a reasonable estimate of its parameters. Most significantly, perhaps, the generality of our data supports the validity of Taylor's disputed simplification [G. I. Taylor, Proc. R. Soc. London, Ser. A 138, 133 (1932), 10.1098/rspa.1932.0175] to reduce the effect of one hydrodynamic boundary condition (on the continuity of the normal contraction of stress) to an assumption that interfacial tension is sufficiently strong to maintain a spherical drop shape.
Ochiai, Tetsuyuki
2017-02-01
We study the effects of a synthetic gauge field and pseudospin-orbit interaction in a stacked two-dimensional ring-network model. The model was introduced to simulate light propagation in the corresponding ring-resonator lattice, and is thus completely bosonic. Without these two items, the model exhibits Floquet-Weyl and Floquet-topological-insulator phases with topologically gapless and gapped band structures, respectively. The synthetic magnetic field implemented in the model results in a three-dimensional Hofstadter-butterfly-type spectrum in a photonic platform. The resulting gaps are characterized by the winding number of relevant S-matrices together with the Chern number of the bulk bands. The pseudospin-orbit interaction is defined as the mixing term between two pseudospin degrees of freedom in the rings, namely, the clockwise and counter-clockwise modes. It destroys the Floquet-topological-insulator phases, while the Floquet-Weyl phase with multiple Weyl points can be preserved by breaking the space-inversion symmetry. Implementing both the synthetic gauge field and pseudospin-orbit interaction requires a certain nonreciprocity.
Energy Technology Data Exchange (ETDEWEB)
Babaev, A. B., E-mail: b-albert78@mail.ru; Magomedov, M. A.; Murtazaev, A. K. [Russian Academy of Sciences, Amirkhanov Institute of Physics, Dagestan Scientific Center (Russian Federation); Kassan-Ogly, F. A.; Proshkin, A. I. [Russian Academy of Sciences, Institute of Metal Physics, Ural Branch (Russian Federation)
2016-02-15
Phase transitions (PTs) and frustrations in two-dimensional structures described by a three-vertex antiferromagnetic Potts model on a triangular lattice are investigated by the Monte Carlo method with regard to nearest and next-nearest neighbors with interaction constants J{sub 1} and J{sub 2}, respectively. PTs in these models are analyzed for the ratio r = J{sub 2}/J{sub 1} of next-nearest to nearest exchange interaction constants in the interval |r| = 0–1.0. On the basis of the analysis of the low-temperature entropy, the density of states function of the system, and the fourth-order Binder cumulants, it is shown that a Potts model with interaction constants J{sub 1} < 0 and J{sub 2} < 0 exhibits a first-order PT in the range of 0 ⩽ r < 0.2, whereas, in the interval 0.2 ⩽ r ⩽ 1.0, frustrations arise in the system. At the same time, for J{sub 1} > 0 and J{sub 2} < 0, frustrations arise in the range 0.5 < |r| < 1.0, while, in the interval 0 ⩽ |r| ⩽ 1/3, the model exhibits a second-order PT.
Bouncing, rolling, energy flows, and cluster formation in a two-dimensional vibrated granular gas
Pérez-Ángel, Gabriel; Nahmad-Molinari, Yuri
2011-10-01
We study the formation of crystalline clusters for a two-dimensional (2D) sinusoidally vibrated granular gas, with maximum vertical acceleration smaller than gravity, using fully 3D simulations. It is found that this phenomenon arises from the spontaneous segregation of the granulate into two dynamical modes: one of grains that bounce in synchrony with the motion of the sustaining plate (“bouncers”) and another of grains that cease to bounce and simply rolls on the plate, without ever loosing contact with it (“rollers”). These two dynamical categories are quite robust with respect to perturbations. The populations for bouncers and rollers depend on the preparation of the granulate and can be made to take arbitrary values in all the range of accelerations where both dynamical modes are present. It is found that the dynamical mode with the largest population coalesces in clusters under the influence of the other mode, whose grains act as a higher pressure gas that compresses the clusters. In this way it is possible to produce clusters of rollers or clusters of bouncers. A gas made of grains from only one dynamical class shows only weak density fluctuations. When the occupation fractions for both modes are similar, one observes segregation and clusters of both types. The clustering of the gas is monitored using both the average coordination number and the local hexatic order parameter ψ6. Energy flows in the plane are monitored, and it is shown that roller-bouncer collisions increase horizontal kinetic energy, while all other types of collisions reduce this energy. We find that friction with the substrate is the main sink of horizontal energy for these granular gases.
Bordajandi, Luisa R; Ramos, Lourdes; González, María José
2006-09-01
Comprehensive two-dimensional gas chromatography with micro electron-capture detection (GC x GC-microECD) has been evaluated for the enantioseparation of five chiral toxaphenes typically found in real-life samples (Parlar 26, 32, 40, 44 and 50). From the two enantioselective beta-cyclodextrin-based columns evaluated as first dimension column, BGB-176SE and BGB-172, the latter provided the best results and was further combined with three non-enantioselective columns in the second dimension: HT-8, BPX-50 and Supelcowax-10. The combination BGB-172 x BPX-50 was finally selected because it provided a complete separation among all enantiomers. A satisfactory repeatability and reproducibility of the retention times in both the first and the second dimension were observed for all target compounds (RSDs below 0.8%, n = 4). Linear responses in the tested range of 10-200 pg/microl and limits of detection in the range of 2-6 pg/microl were obtained. The repeatability and reproducibility at a concentration of 100 pg/microl, evaluated as the RSDs calculated for the enantiomeric fraction (EF), was better than 11% (n = 4) in all instances. The feasibility of the method developed for real-life analyses was illustrated by the determination of the enantiomeric ratios and concentration levels of the test compounds in four commercial fish oil samples. These results were compared to those obtained by heart-cut multidimensional gas chromatography using the same enantioselective column.
Thermalization of a two-dimensional photonic gas in a `white wall' photon box
Klaers, Jan; Vewinger, Frank; Weitz, Martin
2010-07-01
Bose-Einstein condensation, the macroscopic accumulation of bosonic particles in the energetic ground state below a critical temperature, has been demonstrated in several physical systems. The perhaps best known example of a bosonic gas, blackbody radiation, however exhibits no Bose-Einstein condensation at low temperatures. Instead of collectively occupying the lowest energy mode, the photons disappear in the cavity walls when the temperature is lowered-corresponding to a vanishing chemical potential. Here we report on evidence for a thermalized two-dimensional photon gas with a freely adjustable chemical potential. Our experiment is based on a dye-filled optical microresonator, acting as a `white wall' box for photons. Thermalization is achieved in a photon-number-conserving way by photon scattering off the dye molecules, and the cavity mirrors provide both an effective photon mass and a confining potential-key prerequisites for the Bose-Einstein condensation of photons. As a striking example of the unusual system properties, we demonstrate a yet unobserved light concentration effect into the centre of the confining potential, an effect with prospects for increasing the efficiency of diffuse solar light collection.
Observation of Spin Coulomb Drag in a Two-Dimensional Electron Gas
Energy Technology Data Exchange (ETDEWEB)
Weber, C.P.
2011-08-19
An electron propagating through a solid carries spin angular momentum in addition to its mass and charge. Of late there has been considerable interest in developing electronic devices based on the transport of spin, which offer potential advantages in dissipation, size, and speed over charge-based devices. However, these advantages bring with them additional complexity. Because each electron carries a single, fixed value (-e) of charge, the electrical current carried by a gas of electrons is simply proportional to its total momentum. A fundamental consequence is that the charge current is not affected by interactions that conserve total momentum, notably collisions among the electrons themselves. In contrast, the electron's spin along a given spatial direction can take on two values, {+-} {h_bar}/2 (conventionally {up_arrow}, {down_arrow}), so that the spin current and momentum need not be proportional. Although the transport of spin polarization is not protected by momentum conservation, it has been widely assumed that, like the charge current, spin current is unaffected by electron-electron (e-e) interactions. Here we demonstrate experimentally not only that this assumption is invalid, but that over a broad range of temperature and electron density, the flow of spin polarization in a two-dimensional gas of electrons is controlled by the rate of e-e collisions.
Institute of Scientific and Technical Information of China (English)
FENG Jing-jie; LI Ran; YANG Hui-xia; LI Jia
2013-01-01
Elevated levels of the Total Dissolved Gas (TDG) may be reached downstream of dams,leading to increased incidences of gas bubble diseases in fish.The supersaturated TDG dissipates and transports more slowly in reservoirs than in natural rivers because of the greater depth and the lower turbulence,which endangers the fish more seriously.With consideration of the topographical characteristics of a deep reservoir,a laterally averaged two-dimensional unsteady TDG model for deep reservoir is proposed.The dissipation process of the TDG inside the waterbody and the mass transfer through the free surface are separately modeled with different functions in the model.Hydrodynamics equations are solved coupling with those of water temperature and density.The TDG concentration is calculated based on the density current field.A good agreement is found in the simulation of the Dachaoshan Reservoir between the simulation results and the field data of the hydrodynamics parameters and the TDG distribution in the vertical direction and their unsteady evolution with time.The hydrodynamics parameters,the temperature and the TDG concentration are analyzed based on the simulation results.This study demonstrates that the model can be used to predict the evolutions of hydrodynamics parameters,the temperature and the TDG distribution in a deep reservoir with unsteady inflow and outflow.The results can be used in the study of the mitigation measures of the supersaturated TDG.
Density of states in a two-dimensional electron gas: Impurity bands and band tails
Gold, A.; Serre, J.; Ghazali, A.
1988-03-01
We calculate the density of states of a two-dimensional electron gas in the presence of charged impurities within Klauder's best multiple-scattering approach. The silicon metal-oxide-semiconductor (MOS) system with impurities at the interface is studied in detail. The finite extension of the electron wave function into the bulk is included as well as various dependences of the density of states on the electron, the depletion, and the impurity densities. The transition from an impurity band at low impurity concentration to a band tail at high impurity concentration is found to take place at a certain impurity concentration. If the screening parameter of the electron gas is decreased, the impurity band shifts to lower energy. For low impurity density we find excited impurity bands. Our theory at least qualitatively explains conductivity and infrared-absorption experiments on impurity bands in sodium-doped MOS systems and deep band tails in the gap observed for high doping levels in these systems.
Yang, Kesong; Nazir, Safdar; Behtash, Maziar; Cheng, Jianli
2016-10-01
The two-dimensional electron gas (2DEG) formed at the interface between two insulating oxides such as LaAlO3 and SrTiO3 (STO) is of fundamental and practical interest because of its novel interfacial conductivity and its promising applications in next-generation nanoelectronic devices. Here we show that a group of combinatorial descriptors that characterize the polar character, lattice mismatch, band gap, and the band alignment between the perovskite-oxide-based band insulators and the STO substrate, can be introduced to realize a high-throughput (HT) design of SrTiO3-based 2DEG systems from perovskite oxide quantum database. Equipped with these combinatorial descriptors, we have carried out a HT screening of all the polar perovskite compounds, uncovering 42 compounds of potential interests. Of these, Al-, Ga-, Sc-, and Ta-based compounds can form a 2DEG with STO, while In-based compounds exhibit a strain-induced strong polarization when deposited on STO substrate. In particular, the Ta-based compounds can form 2DEG with potentially high electron mobility at (TaO2)+/(SrO)0 interface. Our approach, by defining materials descriptors solely based on the bulk materials properties, and by relying on the perovskite-oriented quantum materials repository, opens new avenues for the discovery of perovskite-oxide-based functional interface materials in a HT fashion.
Zhongxin, Zheng; Jiandong, Sun; Yu, Zhou; Zhipeng, Zhang; Hua, Qin
2015-10-01
The broadband terahertz (THz) emission from drifting two-dimensional electron gas (2DEG) in an AlGaN/GaN heterostructure at 6 K is reported. The devices are designed as THz plasmon emitters according to the Smith-Purcell effect and the ‘shallow water’ plasma instability mechanism in 2DEG. Plasmon excitation is excluded since no signature of electron-density dependent plasmon mode is observed. Instead, the observed THz emission is found to come from the heated lattice and/or the hot electrons. Simulated emission spectra of hot electrons taking into account the THz absorption in air and Fabry-Pérot interference agree well with the experiment. It is confirmed that a blackbody-like THz emission will inevitably be encountered in similar devices driven by a strong in-plane electric field. A conclusion is drawn that a more elaborate device design is required to achieve efficient plasmon excitation and THz emission. Project supported by the National Basic Research Program of China (No. G2009CB929303), the National Natural Science Foundation of China (No. 61271157), the China Postdoctoral Science Foundation (No. 2014M551678), and the Jiangsu Planned Projects for Postdoctoral Research Funds (No. 1301054B).
D. Peroni; R.J. Vonk; W. van Egmond; H.-G. Janssen
2012-01-01
When the typical column combinations are used, comprehensive two-dimensional gas chromatography (GC × GC) suffers from the impossibility to operate both dimensions at their optimum carrier gas velocities at the same time. This as a result of the flow mismatch caused by the different dimensions of th
2008-01-01
The exact partition function of the two-dimensional nearest neighbour Ising model pertaining to square lattices is derived for N sites in the case of a non-vanishing magnetic field.When the magnetic field is zero,the partition functions estimated from the present analysis are identical with those arising from Onsager's exact solution.
de Sousa, N; García-Martín, A; Froufe-Pérez, L S; Marqués, M I
2014-01-01
The effect of spatial correlations on the Purcell effect in a bidimensional dispersion of resonant nanoparticles is analyzed. We perform extensive calculations of the fluorescence decay rate of a point emitter embedded in a system of nanoparticles statistically distributed according to a sim- ple 2D lattice-gas model near the critical point. For short range correlations (high temperature thermalization) the Purcell factors present a non-Gaussian long-tailed statistics which evolves to- wards a bimodal distribution as approaching the critical point where the spatial correlation length diverges. Our results suggest long range correlations as a possible origin of the large fluctuations of experimental decay rates in disordered metal films.
Chetverikov, A. P.; Ebeling, W.; Velarde, M. G.
2016-09-01
We present computational evidence of the possibility of fast, supersonic or subsonic, nearly loss-free ballistic-like transport of electrons bound to lattice solitons (a form of electron surfing on acoustic waves) along crystallographic axes in two-dimensional anharmonic crystal lattices. First we study the structural changes a soliton creates in the lattice and the time lapse of recovery of the lattice. Then we study the behavior of one electron in the polarization field of one and two solitons with crossing pathways with suitably monitored delay. We show how an electron surfing on a lattice soliton may switch to surf on the second soliton and hence changing accordingly the direction of its path. Finally we discuss the possibility to control the way an excess electron proceeds from a source at a border of the lattice to a selected drain at another border by following appropriate straight pathways on crystallographic axes.
Pressure Tuning of First Dimension Columns in Comprehensive Two-Dimensional Gas Chromatography.
Sharif, Khan M; Kulsing, Chadin; Marriott, Philip J
2016-09-20
The experimental approach and mechanism of pressure tuning (PT) are introduced for the first stage of a comprehensive two-dimensional gas chromatography (GC × GC) separation. The PT-GC × GC system incorporates a first dimension ((1)D) coupled column ensemble comprising a pair of (1)D columns ((1)D1 and (1)D2) connected via a microfluidic splitter device, allowing variable decompression of carrier gas across each (1)D column, and a conventional (2)D narrow bore column. By variation of junction pressure between the (1)D1 and (1)D2 columns, tunable total (1)D retentions of analytes are readily derived. Separations of a standard mixture comprising a number of different chemical classes (including alkanes, monoaromatics, alcohols, aldehydes, ketones, and esters) and Australian tea tree oil (TTO) were studied as practical examples of the PT-GC × GC system application. This illustrated the change of analyte retention time with experimental conditions depending on void time and retention on the different columns. In addition to void time change, variation of carrier gas relative decompression in the (1)D ensemble leads to tunable contribution of the (1)D1/(1)D2 columns that changes apparent polarity and selectivity of the ensemble. The resulting changes in (1)D elution order further altered elution temperature and thus retention of each analyte on the (2)D column in temperature-programmed GC × GC. 2D orthogonality measurements were then conducted to evaluate overall separation performance under application of different (1)D junction pressure. As a result, distribution and selectivity of particular target compounds, monoterpenes, sesquiterpenes, and oxygenated terpenes in 2D space, and thus orthogonality, could be adequately tuned. This indicates the potential of PT-GC × GC to be applicable for practical sample separation and provides a general approach to tune selectivity of target compounds.
Doppler Velocimetry of Current Driven Spin Helices in a Two-Dimensional Electron Gas
Yang, Luyi
Spins in semiconductors provide a pathway towards the development of spin-based electronics. The appeal of spin logic devices lies in the fact that the spin current is even under time reversal symmetry, yielding non-dissipative coupling to the electric field. To exploit the energy-saving potential of spin current it is essential to be able to control it. While recent demonstrations of electrical-gate control in spin-transistor configurations show great promise, operation at room temperature remains elusive. Further progress requires a deeper understanding of the propagation of spin polarization, particularly in the high mobility semiconductors used for devices. This thesis presents the demonstration and application of a powerful new optical technique, Doppler spin velocimetry, for probing the motion of spin polarization at the level of 1 nm on a picosecond time scale. We discuss experiments in which this technique is used to measure the motion of spin helices in high mobility n-GaAs quantum wells as a function of temperature, in-plane electric field, and photoinduced spin polarization amplitude. We find that the spin helix velocity changes sign as a function of wave vector and is zero at the wave vector that yields the largest spin lifetime. This observation is quite striking, but can be explained by the random walk model that we have developed. We discover that coherent spin precession within a propagating spin density wave is lost at temperatures near 150 K. This finding is critical to understanding why room temperature operation of devices based on electrical gate control of spin current has so far remained elusive. We report that, at all temperatures, electron spin polarization co-propagates with the high-mobility electron sea, even when this requires an unusual form of separation of spin density from photoinjected electron density. Furthermore, although the spin packet co-propagates with the two-dimensional electron gas, spin diffusion is strongly suppressed
de Forges de Parny, L.; Rousseau, V. G.
2017-01-01
We study the ground state and the thermal phase diagram of a two-species Bose-Hubbard model, with U(1 ) ×Z2 symmetry, describing atoms and molecules on a two-dimensional optical lattice interacting via a Feshbach resonance. Using quantum Monte Carlo simulations and mean-field theory, we show that the conversion between the two species, coherently coupling the atomic and molecular states, has a crucial impact on the Mott-superfluid transition and stabilizes an insulating phase with a gap controlled by the conversion term—the Feshbach insulator—instead of a standard Mott-insulating phase. Depending on the detuning between atoms and molecules, this model exhibits three phases: the Feshbach insulator, a molecular condensate coexisting with noncondensed atoms, and a mixed atomic-molecular condensate. Employing finite-size scaling analysis, we observe three-dimensional (3D) X Y (3D Ising) transition when U(1 ) (Z2) symmetry is broken, whereas the transition is first order when both U(1 ) and Z2 symmetries are spontaneously broken. The finite-temperature phase diagram is also discussed. The thermal disappearance of the molecular superfluid leads to a Berezinskii-Kosterlitz-Thouless transition with unusual universal jump in the superfluid density. The loss of the quasi-long-range coherence of the mixed atomic and molecular superfluid is more subtle since only atoms exhibit conventional Berezinskii-Kosterlitz-Thouless criticality. We also observe a signal compatible with a classical first-order transition between the mixed superfluid and the normal Bose liquid at low temperature.
Strongly anomalous non-thermal fixed point in a quenched two-dimensional Bose gas
Karl, Markus
2016-01-01
Universal scaling behavior in the relaxation dynamics of an isolated two-dimensional Bose gas is studied by means of semi-classical stochastic simulations of the Gross-Pitaevskii model. The system is quenched far out of equilibrium by imprinting vortex defects into an otherwise phase-coherent condensate. A strongly anomalous non-thermal fixed point is identified, associated with a slowed decay of the defects in the case that the dissipative coupling to the thermal background noise is suppressed. At this fixed point, a large anomalous exponent $\\eta \\simeq -3$ and, related to this, a large dynamical exponent $z \\simeq 5$ are identified. The corresponding power-law decay is found to be consistent with three-vortex-collision induced loss. The article discusses these aspects of non-thermal fixed points in the context of phase-ordering kinetics and coarsening dynamics, thus relating phenomenological and analytical approaches to classifying far-from-equilibrium scaling dynamics with each other. In particular, a clo...
Strongly anomalous non-thermal fixed point in a quenched two-dimensional Bose gas
Karl, Markus; Gasenzer, Thomas
2017-09-01
Universal scaling behavior in the relaxation dynamics of an isolated two-dimensional Bose gas is studied by means of semi-classical stochastic simulations of the Gross–Pitaevskii model. The system is quenched far out of equilibrium by imprinting vortex defects into an otherwise phase-coherent condensate. A strongly anomalous non-thermal fixed point is identified, associated with a slowed decay of the defects in the case that the dissipative coupling to the thermal background noise is suppressed. At this fixed point, a large anomalous exponent η ≃ -3 and, related to this, a large dynamical exponent z≃ 5 are identified. The corresponding power-law decay is found to be consistent with three-vortex-collision induced loss. The article discusses these aspects of non-thermal fixed points in the context of phase-ordering kinetics and coarsening dynamics, thus relating phenomenological and analytical approaches to classifying far-from-equilibrium scaling dynamics with each other. In particular, a close connection between the anomalous scaling exponent η, introduced in a quantum-field theoretic approach, and conservation-law induced scaling in classical phase-ordering kinetics is revealed. Moreover, the relation to superfluid turbulence as well as to driven stationary systems is discussed.
A two-dimensional position sensitive gas chamber with scanned charge transfer readout
Energy Technology Data Exchange (ETDEWEB)
Gomez, F. E-mail: faustgr@usc.es; Iglesias, A.; Lobato, R.; Mosquera, J.; Pardo, J.; Pena, J.; Pazos, A.; Pombar, M.; Rodriguez, A
2003-10-21
We have constructed and tested a two-dimensional position sensitive parallel-plate gas ionization chamber with scanned charge transfer readout. The scan readout method described here is based on the development of a new position-dependent charge transfer technique. It has been implemented by using gate strips perpendicularly oriented to the collector strips. This solution reduces considerably the number of electronic readout channels needed to cover large detector areas. The use of a 25 {mu}m thick kapton etched circuit allows high charge transfer efficiency with a low gating voltage, consequently needing a very simple commutating circuit. The present prototype covers 8x8 cm{sup 2} with a pixel size of 1.27x1.27 mm{sup 2}. Depending on the intended use and beam characteristics a smaller effective pixel is feasible and larger active areas are possible. This detector can be used for X-ray or other continuous beam intensity profile monitoring.
Forensic profiling of sassafras oils based on comprehensive two-dimensional gas chromatography.
Schäffer, M; Gröger, T; Pütz, M; Zimmermann, R
2013-06-10
Safrole, the main compound in the essential oil of several plants of the Laurel family (Lauraceae), and its secondary product piperonylmethylketone are the predominantly used precursors for the illicit synthesis of 3,4-methylenedioxymethamphetamine (MDMA) which is, in turn, the most common active ingredient in Ecstasy tablets. Analytical methods with adequate capacity to identify links and origin of precursors, such as safrole, provide valuable information for drug-related police intelligence. Authentic sassafras oil samples from police seizures were subjected to comparative analysis based on their chemical profiles obtained by comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC × GC-TOFMS). The enhanced separation power and increased sensitivity of GC × GC allowed for the detection of minor compounds present in the essential oils which were of particular interest in case of very pure samples whose impurity profiles were not very pronounced. Discrimination of such samples was still possible even in the absence of characteristic main compounds.
Collin, William R; Nuñovero, Nicolas; Paul, Dibyadeep; Kurabayashi, Katsuo; Zellers, Edward T
2016-04-29
Comprehensive two-dimensional gas chromatography (GC×GC) with a temperature-programmed microfabricated thermal modulator (μTM) is demonstrated. The 0.78 cm(2), 2-stage μTM chip with integrated heaters and a PDMS coated microchannel was placed in thermal contact with a solid-state thermoelectric cooler and mounted on top of a bench scale GC. It was fluidically coupled through heated interconnects to an upstream first-dimension ((1)D) PDMS-coated capillary column and a downstream uncoated capillary or second-dimension ((2)D) PEG-coated capillary. A mixture of n-alkanes C6-C10 was separated isothermally and the full-width-at-half-maximum (fwhm) values of the modulated peaks were assessed as a function of the computer-controlled minimum and maximum stage temperatures of μTM, Tmin and Tmax, respectively. With Tmin and Tmax fixed at -25 and 100°C, respectively, modulated peaks of C6 and C7 had fwhm valuesthermal modulator. Replacing the PDMS phase in the μTM with a trigonal-tricationic room temperature ionic liquid eliminated the bleed observed with the PDMS, but also reduced the capacity for several test compounds. Regardless, the demonstrated capability to independently temperature program this low resource μTM enhances its versatility and its promise for use in bench-scale GC×GC systems.
Superfluidity and relaxation dynamics of a laser-stirred two-dimensional Bose gas
Singh, Vijay Pal; Weitenberg, Christof; Dalibard, Jean; Mathey, Ludwig
2017-04-01
We investigate the superfluid behavior of a two-dimensional (2D) Bose gas of 87Rb atoms using classical field dynamics. In the experiment by R. Desbuquois et al. [Nat. Phys. 8, 645 (2012), 10.1038/nphys2378], a 2D quasicondensate in a trap is stirred with a blue-detuned laser beam along a circular path around the trap center. Here, we study this experiment from a theoretical perspective. The heating induced by stirring increases rapidly above a velocity vc, which we define as the critical velocity. We identify the superfluid, the crossover, and the thermal regime by a finite, a sharply decreasing, and a vanishing critical velocity, respectively. We demonstrate that the onset of heating occurs due to the creation of vortex-antivortex pairs. A direct comparison of our numerical results to the experimental ones shows a good agreement, if a systematic shift of the critical phase-space density is included. We relate this shift to the absence of thermal equilibrium between the condensate and the thermal wings, which were used in the experiment to extract the temperature. We expand on this observation by studying the full relaxation dynamics between the condensate and the thermal cloud.
Ghosh, Abhijit; Seeley, Stacy K; Nartker, Steven R; Seeley, John V
2014-09-19
A comprehensive two-dimensional gas chromatography (GC×GC) method for separating siloxanes from hydrocarbons has been developed using a systematic process. First, the retention indices of a set of siloxanes and a set of hydrocarbons were determined on 6 different stationary phases. The retention indices were then used to model GC×GC separation on 15 different stationary phase pairs. The SPB-Octyl×DB-1 pair was predicted to provide the best separation of the siloxanes from the hydrocarbons. The efficacy of this stationary phase pair was experimentally tested by performing a GC×GC analysis of gasoline spiked with siloxanes and by analyzing biogas obtained from a local wastewater treatment facility. The model predictions agreed well with the experimental results. The SPB-Octyl×DB-1 stationary phase pair constrained the hydrocarbons to a narrow range of secondary retention times and fully isolated the siloxanes from the hydrocarbon band. The resulting GC×GC method allows siloxanes to be resolved from complex mixtures of hydrocarbons without requiring the use of a selective detector.
Electrical transport of an AlGaN/GaN two-dimensional electron gas
Energy Technology Data Exchange (ETDEWEB)
Saxler, A.; Debray, P.; Perrin, R. [and others
2000-07-01
An Al{sub x}Ga{sub 1{minus}x}N/GaN two-dimensional electron gas structure with x = 0.13 deposited by molecular beam epitaxy on a GaN layer grown by organometallic vapor phase epitaxy on a sapphire substrate was characterized. Hall effect measurements gave a sheet electron concentration of 5.1x10{sup 12} cm{sup {minus}2} and a mobility of 1.9 x 10{sup 4} cm{sup 2}/Vs at 10 K. Mobility spectrum analysis showed single-carrier transport and negligible parallel conduction at low temperatures. The sheet carrier concentrations determined from Shubnikov-de Haas magnetoresistance oscillations were in good agreement with the Hall data. The electron effective mass was determined to be 0.21 {+-} 0.006 m{sub 0} based on the temperature dependence of the amplitude of Shubnikov-de Haas oscillations. The quantum lifetime was about one-fifth of the transport lifetime of 2.3 x 10{sup {minus}12} s.
Potgieter, H; Bekker, R; Beigley, J; Rohwer, E
2017-08-04
Heavy petroleum fractions are produced during crude and synthetic crude oil refining processes and they need to be upgraded to useable products to increase their market value. Usually these fractions are upgraded to fuel products by hydrocracking, hydroisomerization and hydrogenation processes. These fractions are also upgraded to other high value commercial products like lubricant oils and waxes by distillation, hydrogenation, and oxidation and/or blending. Oxidation of hydrogenated heavy paraffinic fractions produces high value products that contain a variety of oxygenates and the characterization of these heavy oxygenates is very important for the control of oxidation processes. Traditionally titrimetric procedures are used to monitor oxygenate formation, however, these titrimetric procedures are tedious and lack selectivity toward specific oxygenate classes in complex matrices. Comprehensive two-dimensional gas chromatography (GC×GC) is a way of increasing peak capacity for the comprehensive analysis of complex samples. Other groups have used HT-GC×GC to extend the carbon number range attainable by GC×GC and have optimised HT-GC×GC parameters for the separation of aromatics, nitrogen-containing compounds as well as sulphur-containing compounds in heavy petroleum fractions. HT-GC×GC column combinations for the separation of oxygenates in oxidised heavy paraffinic fractions are optimised in this study. The advantages of the HT-GC×GC method in the monitoring of the oxidation reactions of heavy paraffinic fraction samples are illustrated. Copyright © 2017 Elsevier B.V. All rights reserved.
Wang, Mengen; Zhong, Jianqiang; Boscoboinik, Jorge Anibal; Lu, Deyu
Zeolites are important industrial catalysts with porous three-dimensional structures. The catalytically active sites are located inside the pores, thus rendering them inaccessible for surface science measurements. We synthesized a two-dimensional (2D) zeolite model system, consisting of an (alumino)silicate bilayer weakly bound to a Ru (0001) surface. The 2D zeolite is suitable for surface science studies; it allows a detailed characterization of the atomic structure of the active site and interrogation of the model system during the catalytic reaction. As an initial step, we use Ar adsorption to obtain a better understanding of the atomic structure of the 2D zeolite. In addition, atomic level studies of rare gas adsorption and separation by zeolite are important for its potential application in nuclear waste sequestration. Experimental studies found that Ar atoms can be trapped inside the 2D-zeolite, raising an interesting question on whether Ar atoms are trapped inside the hexagonal prism nano-cages or at the interface between the (alumino)silicate bilayer and Ru(0001), or both. DFT calculations using van der Waals density functionals were carried out to determine the preferred Ar adsorption sites and the corresponding adsorption energies. This research used resources of the Center for Functional Nanomaterials, which is a U.S. DOE Office of Science Facility, at Brookhaven National Laboratory under Contract No. DE-SC0012704.
Kupska, Magdalena; Chmiel, Tomasz; Jędrkiewicz, Renata; Wardencki, Waldemar; Namieśnik, Jacek
2014-01-01
Terpenes are the main group of secondary metabolites, which play essential role in human. The establishment of the terpenes profile of berries of different blue honeysuckle cultivars was achieved by headspace solid-phase microextraction coupled with comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry (HS-SPME/GC×GC-TOFMS). The berries were found to contain 44 terpenes identified by GC×GC-TOFMS. From these, 10 were previously reported in blueberries. According to their chemical structure, the compounds were organised in different groups: monoterpene hydrocarbons and monoterpene oxygen-containing compounds (oxides, alcohols, aldehydes, and ketones). Positive identification of some of the compounds was performed using authentic standards, while tentative identification of the compounds was based on deconvoluted mass spectra and comparison of linear retention indices (LRI) with literature values. The major components of volatile fraction were monoterpenes, such as eucalyptol, linalool and p-cymene. Furthermore, quantitative analysis showed that eucalyptol was the most abundant bioactive terpene in analysed berries (12.4-418.2 μg/L).
Küppersbusch, C.S.
2015-01-01
In the first part of the thesis I derive a full quantitative formula which describes the amplitude and frequency of magnetic oscillations in two-dimensional Dirac systems. The investigations are on the basis of graphene, but they generally also hold for other two-dimensional Dirac systems. Starting
Venetsanos, A G; Bartzis, J G; Würtz, J; Papailiou, D D
2003-04-25
A two-dimensional shallow layer model has been developed to predict dense gas dispersion, under realistic conditions, including complex features such as two-phase releases, obstacles and inclined ground. The model attempts to predict the time and space evolution of the cloud formed after a release of a two-phase pollutant into the atmosphere. The air-pollutant mixture is assumed ideal. The cloud evolution is described mathematically through the Cartesian, two-dimensional, shallow layer conservation equations for mixture mass, mixture momentum in two horizontal directions, total pollutant mass fraction (vapor and liquid) and mixture internal energy. Liquid mass fraction is obtained assuming phase equilibrium. Account is taken in the conservation equations for liquid slip and eventual liquid rainout through the ground. Entrainment of ambient air is modeled via an entrainment velocity model, which takes into account the effects of ground friction, ground heat transfer and relative motion between cloud and surrounding atmosphere. The model additionally accounts for thin obstacles effects in three ways. First a stepwise description of the obstacle is generated, following the grid cell faces, taking into account the corresponding area blockage. Then obstacle drag on the passing cloud is modeled by adding flow resistance terms in the momentum equations. Finally the effect of extra vorticity generation and entrainment enhancement behind obstacles is modeled by adding locally into the entrainment formula without obstacles, a characteristic velocity scale defined from the obstacle pressure drop and the local cloud height.The present model predictions have been compared against theoretical results for constant volume and constant flux gravity currents. It was found that deviations of the predicted cloud footprint area change with time from the theoretical were acceptably small, if one models the frictional forces between cloud and ambient air, neglecting the Richardson
Rathbun, Wayne
2007-01-01
A method is described for automating the regulation of cold jet flow of a comprehensive two-dimensional gas chromatograph (GCxGC) configured with flame ionization detection. This new capability enables the routine automated separation, identification, and quantitation of hydrocarbon types in petroleum fractions extending into the vacuum gas oil (VGO) range (IBP-540 degrees C). Chromatographic data acquisition software is programmed to precisely change the rate of flow from the cold jet of a nitrogen cooled loop modulator of a GCxGC instrument during sample analysis. This provides for the proper modulation of sample compounds across a wider boiling range. The boiling point distribution of the GCxGC separation is shown to be consistent with high temperature simulated distillation results indicating recovery of higher boiling semi-volatile VGO sample components. GCxGC configured with time-of-flight mass spectrometry is used to determine the molecular identity of individual sample components and boundaries of different molecular types.
Pfeiffer, F.; Meyer-Koenig, W.
1949-01-01
By means of characteristics theory, formulas for the numerical treatment of stationary compressible supersonic flows for the two-dimensional and rotationally symmetrical cases have been obtained from their differential equations.
A Lattice-Gas Model of Microemulsions
Boghosian, B M; Emerton, A N; Boghosian, Bruce M.; Coveney, Peter V.; Emerton, Andrew N.
1995-01-01
We develop a lattice gas model for the nonequilibrium dynamics of microemulsions. Our model is based on the immiscible lattice gas of Rothman and Keller, which we reformulate using a microscopic, particulate description so as to permit generalisation to more complicated interactions, and on the prescription of Chan and Liang for introducing such interparticle interactions into lattice gas dynamics. We present the results of simulations to demonstrate that our model exhibits the correct phenomenology, and we contrast it with both equilibrium lattice models of microemulsions, and to other lattice gas models.
Institute of Scientific and Technical Information of China (English)
ZHANG Yan; SHI Jun-Jie
2008-01-01
A two-dimensional photonic crystal model with a periodic square dielectric background is proposed.The photonic band modulation effects due to the two-dimensional periodic background are investigated jn detail.It is found that periodic modulation of the dielectric background greatly alters photonic band structures,especially for the Epolarization modes.The number,width and position of the photonic band gaps sensitively depend on the dielectric constants of the two-dimensional periodic background.Complete band gaps are found,and the dependence of the widths of these gaps on the structural and material parameters of the two alternating rods/holes is studied.
Amino acid analysis by using comprehensive two-dimensional gas chromatography.
Mayadunne, Renuka; Nguyen, Thuy-Tien; Marriott, Philip J
2005-06-01
The separation characteristics of alkylchloroformate-derivatised amino acids (AAs) by using comprehensive two-dimensional gas chromatography (GCxGC) is reported. The use of a low-polarity/polar column set did not provide as good a separation performance as that achieved with a polar/non-polar column set, where the latter appeared to provide less correlation over the separation space. The degree of component correlation in each column set was estimated by using the correlation coefficient (r(2); for (1)t(R) and (2)t(R) data) with the low-polarity/polar and polar/low-polarity sets returning correlation coefficients of 0.86, and 0.00 respectively, under the respective conditions employed for the experiments. The 1.5-m non-polar (2)D column (0.1-mm ID; 0.1-mum film thickness) gave peak halfwidths of the order of 50-80 ms. Linearity of detection was good, over a three order of magnitude concentration range, with typical lower detection limit of ca. 0.01 mg L(-1), compared with 0.5 mg L(-1) for normal GC operation with splitless injection. The method was demonstrated for analysis of AAs in a range of food and beverage products, including wine, beer and honey. The major AA in these samples was proline. The Heineken beer sample had a relatively more complex and more abundant AA content compared with the other beer sample. The wine and honey samples also gave a range of AA compounds. Repetition of the sample preparation/analysis procedure for the honey sample gave acceptable reproducibility for individual AAs.
Caldeira, M; Perestrelo, R; Barros, A S; Bilelo, M J; Morête, A; Câmara, J S; Rocha, S M
2012-09-07
Allergic asthma represents an important public health issue, most common in the paediatric population, characterized by airway inflammation that may lead to changes in volatiles secreted via the lungs. Thus, exhaled breath has potential to be a matrix with relevant metabolomic information to characterize this disease. Progress in biochemistry, health sciences and related areas depends on instrumental advances, and a high throughput and sensitive equipment such as comprehensive two-dimensional gas chromatography-time of flight mass spectrometry (GC×GC-ToFMS) was considered. GC×GC-ToFMS application in the analysis of the exhaled breath of 32 children with allergic asthma, from which 10 had also allergic rhinitis, and 27 control children allowed the identification of several hundreds of compounds belonging to different chemical families. Multivariate analysis, using Partial Least Squares-Discriminant Analysis in tandem with Monte Carlo Cross Validation was performed to assess the predictive power and to help the interpretation of recovered compounds possibly linked to oxidative stress, inflammation processes or other cellular processes that may characterize asthma. The results suggest that the model is robust, considering the high classification rate, sensitivity, and specificity. A pattern of six compounds belonging to the alkanes characterized the asthmatic population: nonane, 2,2,4,6,6-pentamethylheptane, decane, 3,6-dimethyldecane, dodecane, and tetradecane. To explore future clinical applications, and considering the future role of molecular-based methodologies, a compound set was established to rapid access of information from exhaled breath, reducing the time of data processing, and thus, becoming more expedite method for the clinical purposes.
Silva, Aline C A; Ebrahimi-Najafadabi, Heshmatollah; McGinitie, Teague M; Casilli, Alessandro; Pereira, Henrique M G; Aquino Neto, Francisco R; Harynuk, James J
2015-05-01
This work evaluates the application of a thermodynamic model to comprehensive two-dimensional gas chromatography (GC × GC) coupled with time-of-flight mass spectrometry for anabolic agent investigation. Doping control deals with hundreds of drugs that are prohibited in sports. Drug discovery in biological matrices is a challenging task that requires powerful tools when one is faced with the rapidly changing designer drug landscape. In this work, a thermodynamic model developed for the prediction of both primary and secondary retention times in GC × GC has been applied to trimethylsilylated hydroxyl (O-TMS)- and methoxime-trimethylsilylated carbonyl (MO-TMS)-derivatized endogenous steroids. This model was previously demonstrated on a pneumatically modulated GC × GC system, and is applied for the first time to a thermally modulated GC × GC system. Preliminary one-dimensional experiments allowed the calculation of thermodynamic parameters (ΔH, ΔS, and ΔC p ) which were successfully applied for the prediction of the analytes' interactions with the stationary phases of both the first-dimension column and the second-dimension column. The model was able to predict both first-dimension and second-dimension retention times with high accuracy compared with the GC × GC experimental measurements. Maximum differences of -8.22 s in the first dimension and 0.4 s in the second dimension were encountered for the O-TMS derivatives of 11β-hydroxyandrosterone and 11-ketoetiocholanolone, respectively. For the MO-TMS derivatives, the largest discrepancies were from testosterone (9.65 ) for the first-dimension retention times and 11-keto-etiocholanolone (0.4 s) for the second-dimension retention times.
den Hartog, Sander; Wees, B.J. van; Nazarov, Yu.V.; Klapwijk, T.M.; Borghs, G.
1998-01-01
We first present the bias-voltage dependence of the superconducting phase-dependent reduction in the differential resistance of a disordered T-shaped two-dimensional electron gas (2DEG) coupled to two superconductors. This reduction exhibits a reentrant behavior, since it first increases upon loweri
Korytar, P.; Stee, van L.L.P.; Leonards, P.E.G.; Boer, de J.; Brinkman, U.A.Th.
2003-01-01
Comprehensive two-dimensional gas chromatography (GCxGC) coupled with micro electron-capture and time-of-flight mass spectrometric (TOF-MS) detection has been used to analyse technical toxaphene. An HP-1xHT-8 column combination yielded highly structured chromatograms and revealed a complex mixture o
Houten, H. van; Beenakker, C.W.J.; Loosdrecht, P.H.M. van; Thornton, T.J.; Ahmed, H.; Pepper, M.; Foxon, C.T.; Harris, J.J.
1988-01-01
A novel negative magnetoresistance effect is found in four-terminal measurements of the voltage drop across a short constriction of variable width in a high-mobility two-dimensional electron gas. The effect is interpreted as the suppression by a magnetic field of the geometrical constriction resista
Mispelaar, V.G. van; Smilde, A.K.; Noord, O.E. de; Blomberg, J.; Schoenmakers, P.J.
2005-01-01
Comprehensive two-dimensional gas chromatography (GC × GC) has proven to be an extremely powerful separation technique for the analysis of complex volatile mixtures. This separation power can be used to discriminate between highly similar samples. In this article we will describe the use of GC × GC
Integration of complementary circuits and two-dimensional electron gas in a Si/SiGe heterostructure
Lu, T. M.; Lee, C.-H.; Tsui, D. C.; Liu, C. W.
2010-06-01
We have realized complementary devices on an undoped Si/SiGe substrate where both two-dimensional electrons and holes can be induced capacitively. The design of the heterostructure and the fabrication process are reported. Magnetotransport measurements show that the induced two-dimensional electron gas exhibits the quantum Hall effect characteristics. A p-channel field-effect transistor is characterized and the operation of an inverter is demonstrated. The proof-of-principle experiment shows the feasibility of integrating complementary logic circuits with quantum devices.
2007-01-01
An explicit expression for the partition function of two-dimensional nearest neighbour Ising models in the presence of a magnetic field is derived by a systematic enumeration of all the spin configurations pertaining to a square lattice of sixteen sites. The critical temperature is shown to be in excellent agreement with the reported values while the corresponding dimensionless magnetic field is obtained as 0.004.
A two-dimensional model for gas mixing in the upper dilute zone of a circulating fluidized bed
Energy Technology Data Exchange (ETDEWEB)
Kruse, M.; Schoenfelder, H.; Werther, J. [Technical University of Hamburg-Harburg, Hamburg (Germany)
1995-10-01
A two-dimensional two-phase flow model for gas/solid flow and gas mixing in the upper zone of a circulating fluidized bed is described. Continuous functions are used to describe variations of local flow parameters horizontally and vertically. Numerical values of dispersion parameters and interfacial mass transfer coefficients are derived from the results of tracer gas mixing experiments. There is good agreement between calculated and measured tracer gas profiles in the upper dilute zone of the circulating fluidized bed. The model is applicable to calculation of chemical reactions in CFB risers. 37 refs., 26 figs., 3 tabs.
Doppler Velocimetry of Current Driven Spin Helices in a Two-Dimensional Electron Gas
Energy Technology Data Exchange (ETDEWEB)
Yang, Luyi [Univ. of California, Berkeley, CA (United States)
2013-05-17
Spins in semiconductors provide a pathway towards the development of spin-based electronics. The appeal of spin logic devices lies in the fact that the spin current is even under time reversal symmetry, yielding non-dissipative coupling to the electric field. To exploit the energy-saving potential of spin current it is essential to be able to control it. While recent demonstrations of electrical-gate control in spin-transistor configurations show great promise, operation at room temperature remains elusive. Further progress requires a deeper understanding of the propagation of spin polarization, particularly in the high mobility semiconductors used for devices. This dissertation presents the demonstration and application of a powerful new optical technique, Doppler spin velocimetry, for probing the motion of spin polarization at the level of 1 nm on a picosecond time scale. We discuss experiments in which this technique is used to measure the motion of spin helices in high mobility n-GaAs quantum wells as a function of temperature, in-plane electric field, and photoinduced spin polarization amplitude. We find that the spin helix velocity changes sign as a function of wave vector and is zero at the wave vector that yields the largest spin lifetime. This observation is quite striking, but can be explained by the random walk model that we have developed. We discover that coherent spin precession within a propagating spin density wave is lost at temperatures near 150 K. This finding is critical to understanding why room temperature operation of devices based on electrical gate control of spin current has so far remained elusive. We report that, at all temperatures, electron spin polarization co-propagates with the high-mobility electron sea, even when this requires an unusual form of separation of spin density from photoinjected electron density. Furthermore, although the spin packet co-propagates with the two-dimensional electron gas, spin diffusion is strongly
Three-body recombination in a quasi-two-dimensional quantum gas
Huang, Bo; Zenesini, Alessandro; Grimm, Rudolf
2016-05-01
Quantum three-body recombination in three-dimensional systems is influenced by a series of weakly bound trimers known as Efimov states, which are induced by short-range interactions and exhibit a discrete scaling symmetry. On the other hand, two-dimensional systems with contact interactions are characterized by continuous scale invariance and support no Efimov physics. This raises questions about the behaviour of three-body recombination in the transition from three to two dimensions. We use ultracold caesium atoms trapped in anisotropic potentials formed by a pair of counter-propagating laser beams to experimentally investigate three-body recombination in quasi-two-dimensional systems with tunable confinement and tunable interactions. In our recent experiments, we observed a smooth transition of the three-body recombination rate coefficient from a three-dimensional to a deeply quasi-two-dimensional system. A comparison between the results obtained near two Feshbach resonances indicates a universal behaviour of three-body recombination in the quasi-two-dimensional regime. Austrian Science Fund FWF within project P23106.
Boursier, Laure; Souchon, Vincent; Dartiguelongue, Cyril; Ponthus, Jérémie; Courtiade, Marion; Thiébaut, Didier
2013-03-08
The development of efficient conversion processes requires extended knowledge on vacuum gas oils (VGOs). Among these processes, hydrocracking is certainly one of the best suited to meet the increasing demand on high quality diesel fuels. Most of refractory and inhibiting compounds towards hydrocracking and especially nitrogen containing compounds are contained in a fraction of the VGO called the resin fraction, which corresponds to the most polar fraction of a VGO obtained by liquid chromatography (LC) fractionation on a silica column. However, the lack of resolution observed through existing analytical methods does not allow a detailed characterization of these fractions. A recent study showed that comprehensive high temperature two-dimensional gas chromatography (HT-GC×GC) methods could be optimized in order to elute heavy compounds. This method was implemented for the analysis of VGO resin fractions and complete elution was reached. Firstly, the method was validated through repeatability, accuracy, linearity and response factors calculations. Four VGO resin fractions were analyzed and their HT-GC×GC simulated distillation curves were compared to their GC simulated distillation (GC-SimDist) curves. This comparison showed that the method allows complete elution of most of the analyzed VGO resin fractions. However, a detailed characterization of these fractions is not yet obtained due to the very large number of heteroatomic and aromatic species that a flame ionization detector can detect. Current work aims at increasing the selectivity of GC×GC by using heteroatom selective detectors in order to improve the characterization of such products.
Terahertz magneto-optical spectroscopy of a two-dimensional hole gas
Energy Technology Data Exchange (ETDEWEB)
Kamaraju, N., E-mail: nkamaraju@lanl.gov; Taylor, A. J.; Prasankumar, R. P., E-mail: rpprasan@lanl.gov [Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Pan, W.; Reno, J. [Sandia National Laboratories, Albuquerque, New Mexico 87123 (United States); Ekenberg, U. [Semiconsultants, Brunnsgrnd 12, SE-18773 Täby (Sweden); Gvozdić, D. M. [School of Electrical Engineering, University of Belgrade, Belgrade 11120 (Serbia); Boubanga-Tombet, S. [Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Research Institute of Electrical Communication, Tohoku University, 2-1-1 Katahira, Aoba-Ku, Sendai (Japan); Upadhya, P. C. [Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Laboratory for Electro-Optics Systems, Indian Space Research Organization, Bangalore 560058 (India)
2015-01-19
Two-dimensional hole gases (2DHGs) have attracted recent attention for their unique quantum physics and potential applications in areas including spintronics and quantum computing. However, their properties remain relatively unexplored, motivating the use of different techniques to study them. We used terahertz magneto-optical spectroscopy to investigate the cyclotron resonance frequency in a high mobility 2DHG, revealing a nonlinear dependence on the applied magnetic field. This is shown to be due to the complex non-parabolic valence band structure of the 2DHG, as verified by multiband Landau level calculations. We also find that impurity scattering dominates cyclotron resonance decay in the 2DHG, in contrast with the dominance of superradiant damping in two-dimensional electron gases. Our results shed light on the properties of 2DHGs, motivating further studies of these unique 2D nanosystems.
Collective modes of a two-dimensional spin-1/2 Fermi gas in a harmonic trap
DEFF Research Database (Denmark)
Baur, Stefan; Vogt, Enrico; Köhl, Michael
2013-01-01
We derive analytical expressions for the frequency and damping of the lowest collective modes of a two-dimensional Fermi gas using kinetic theory. For strong coupling, we furthermore show that pairing correlations overcompensate the effects of Pauli blocking on the collision rate for a large rang...... the experimental bounds results in a damping of the breathing mode which is comparable to what is observed, even for a scale-invariant system....
Gertsiuk, M.M.; Kovalchuk, T.; Kapral, K.; Lysychenko, G.V.
2014-01-01
The method of two-dimensional gas chromatography cou pled with mass-spectrometry detection was used for determination of pyrolysis liquid — a mixture of pyrolysis products of waste tires. 6500 organic compounds have been identified: the saturated, unsaturated, aromatic hydrocarbons, the derivatives of thiophene, cyclic aminocompounds. By its composition pyrolytic liquid is close to the diesel fuel and can be used as the alternative fuel.
Directory of Open Access Journals (Sweden)
Gertsiuk, M.M.
2014-03-01
Full Text Available The method of two-dimensional gas chromatography cou pled with mass-spectrometry detection was used for determination of pyrolysis liquid — a mixture of pyrolysis products of waste tires. 6500 organic compounds have been identified: the saturated, unsaturated, aromatic hydrocarbons, the derivatives of thiophene, cyclic aminocompounds. By its composition pyrolytic liquid is close to the diesel fuel and can be used as the alternative fuel.
Singh, Vijeta; Pulikkotil, J. J.
2017-02-01
The origin of quasi-two dimensional electron gas at the interface of polar-nonpolar oxide hetero-structure, such as LaAlO3/SrTiO3, is debated over electronic reconstruction and defects/disorder models. Common to these models is the partial valence transformation of substrate Ti ions from its equilibrium 4 + state to an itinerant 3 + state. Given that the Hf ions have a lower ionization potential than Ti due to the 4 f orbital screening, one would expect a hetero-interface conductivity in the polar-nonpolar LaAlO3/SrHfO3 system as well. However, our first principles calculations show the converse. Unlike the Ti3+ -Ti4+ valence transition which occur at a nominal energy cost, the barrier energy associated with its isoelectronic Hf3+ -Hf4+ counterpart is very high, hence suppressing the formation of quasi-two dimensional electron gas at LaAlO3/SrHfO3 hetero-interface. These calculations, therefore, emphasize on the propensity of mixed valence at the interface as a necessary condition for an oxide hetero-structure to exihibit quasi two-dimensional electron gas.
Naether, Uta; Johansson, Magnus
2010-01-01
We address the problem of directional mobility of discrete solitons in two-dimensional rectangular lattices, in the framework of a discrete nonlinear Schr\\"odinger model with saturable on-site nonlinearity. A numerical constrained Newton-Raphson method is used to calculate two-dimensional Peierls-Nabarro energy surfaces, which describe a pseudopotential landscape for the slow mobility of coherent localized excitations, corresponding to continuous phase-space trajectories passing close to stationary modes. Investigating the two-parameter space of the model through independent variations of the nonlinearity constant and the power, we show how parameter regimes and directions of good mobility are connected to existence of smooth surfaces connecting the stationary states. In particular, directions where solutions can move with minimum radiation can be predicted from flatter parts of the surfaces. For such mobile solutions, slight perturbations in the transverse direction yield additional transverse oscillations w...
Exact two-body solutions and quantum defect theory of two-dimensional dipolar quantum gas
Jie, Jianwen; Qi, Ran
2016-10-01
In this paper, we provide the two-body exact solutions of the two-dimensional (2D) Schrödinger equation with isotropic +/- 1/{r}3 interactions. An analytic quantum defect theory is constructed based on these solutions and it is applied to investigate the scattering properties as well as two-body bound states of an ultracold polar molecules confined in a quasi-2D geometry. Interestingly, we find that for the attractive case, the scattering resonance happens simultaneously in all partial waves, which has not been observed in other systems. The effect of this feature on the scattering phase shift across such resonances is also illustrated.
Matsumoto, M.; Hanai, R.; Inotani, D.; Ohashi, Y.
2017-06-01
We investigate strong-coupling properties of a two-dimensional ultracold Fermi gas in the normal phase. In the three-dimensional case, it has been shown that the so-called pseudogap phenomena can be well described by a (non-self-consistent) T-matrix approximation (TMA). In the two-dimensional case, while this strong-coupling theory can explain the pseudogap phenomenon in the strong-coupling regime, it unphysically gives large pseudogap size in the crossover region, as well as in the weak-coupling regime. We show that this difficulty can be overcome when one improves TMA to include higher-order pairing fluctuations within the framework of a self-consistent T-matrix approximation (SCTMA). The essence of this improvement is also explained. Since the observation of the BKT transition has recently been reported in a two-dimensional ^6{Li} Fermi gas, our results would be useful for the study of strong-coupling physics associated with this quasi-long-range order.
Matoz-Fernandez, D. A.; Linares, D. H.; Ramirez-Pastor, A. J.
2007-01-01
Monte Carlo simulations and finite-size scaling analysis have been carried out to study the critical behavior and universality for the isotropic-nematic phase transition in a system of long straight rigid rods of length $k$ ($k$-mers) on two-dimensional lattices. The nematic phase, characterized by a big domain of parallel $k$-mers, is separated from the isotropic state by a continuous transition occurring at a finite density. The determination of the critical exponents, along with the behavi...
Lima, L. S.
2017-02-01
We have used the Dirac's massless quasi-particles together with the Kubo's formula to study the spin transport by electrons in the graphene monolayer. We have calculated the electric conductivity and verified the behavior of the AC and DC currents of this system, that is a relativistic electron plasma. Our results show that the AC conductivity tends to infinity in the limit ω → 0 , similar to the behavior obtained for the spin transport in the two-dimensional frustrated antiferromagnet in the honeycomb lattice. We have made a diagrammatic expansion for the Green's function and we have not gotten significative change in the results.
Huard; Cox; Saminadayar; Arnoult; Tatarenko
2000-01-01
The dependence of the optical absorption spectrum of a semiconductor quantum well on two-dimensional electron concentration n(e) is studied using CdTe samples. The trion peak (X-) seen at low n(e) evolves smoothly into the Fermi edge singularity at high n(e). The exciton peak (X) moves off to high energy, weakens, and disappears. The X,X- splitting is linear in n(e) and closely equal to the Fermi energy plus the trion binding energy. For Cd0.998Mn0.002Te quantum wells in a magnetic field, the X,X- splitting reflects unequal Fermi energies for M = +/-1/2 electrons. The data are explained by Hawrylak's theory of the many-body optical response including spin effects.
Strongly anisotropic spin-orbit splitting in a two-dimensional electron gas
DEFF Research Database (Denmark)
Michiardi, Matteo; Bianchi, Marco; Dendzik, Maciej
2015-01-01
Near-surface two-dimensional electron gases on the topological insulator Bi$_2$Te$_2$Se are induced by electron doping and studied by angle-resolved photoemission spectroscopy. A pronounced spin-orbit splitting is observed for these states. The $k$-dependent splitting is strongly anisotropic...... Rashba Hamiltonian. However, a $\\mathbf{k} \\cdot \\mathbf{p}$ model that includes the possibility of band structure anisotropy as well as both isotropic and anisotropic third order Rashba splitting can explain the results. The isotropic third order contribution to the Rashba Hamiltonian is found...... to be negative, reducing the energy splitting at high $k$. The interplay of band structure, higher order Rashba effect and tuneable doping offers the opportunity to engineer not only the size of the spin-orbit splitting but also its direction....
Guo, Kun; Zhou, Jian; Liu, Zelong
2012-02-01
An analytical method for separating and identifying the aromatic hydrocarbons in heavy gas oil using comprehensive two-dimensional gas chromatography (GC x GC) coupled to time-of-flight mass spectrometry (TOF MS) was established. The two-dimensional distribution by ring number of the aromatic hydrocarbons was obtained. Besides phenanthrene and methyl-phenanthrene, many other polycyclic aromatic hydrocarbons (PAHs) such as pyrene and benzo [a] anthracene were identified by using the retention times, standard mass spectra or literature reports. The method was successfully applied to the hydrotreating process of heavy gas oil and the hydrotreated products of phenanthrene, pyrene were identified. This method provided technical support for the characterization of aromatic hydrocarbons in heavy gas oil and the investigation of hydrogenation mechanism of polycyclic aromatic hydrocarbons. Compared with the conventional method, gas chromatography coupled to mass spectrometry (GC-MS), the GC x GC-TOF MS method illustrated the obvious advantages for heavy gas oil analysis.
Luo, Xuebing; Zhou, Kezhao; Zhang, Zhidong
2016-11-01
We use the path-integral formalism to investigate the vortex properties of a quasi-two dimensional (2D) Fermi superfluid system trapped in an optical lattice potential. Within the framework of mean-field theory, the cooper pair density, the atom number density, and the vortex core size are calculated from weakly interacting BCS regime to strongly coupled while weakly interacting BEC regime. Numerical results show that the atoms gradually penetrate into the vortex core as the system evolves from BEC to BCS regime. Meanwhile, the presence of the optical lattice allows us to analyze the vortex properties in the crossover from three-dimensional (3D) to 2D case. Furthermore, using a simple re-normalization procedure, we find that the two-body bound state exists only when the interaction is stronger than a critical one denoted by G c which is obtained as a function of the lattice potential’s parameter. Finally, we investigate the vortex core size and find that it grows with increasing interaction strength. In particular, by analyzing the behavior of the vortex core size in both BCS and BEC regimes, we find that the vortex core size behaves quite differently for positive and negative chemical potentials. Project supported by the National Natural Science Foundation of China (Grant Nos. 51331006, 51590883, and 11204321) and the Project of Chinese Academy of Sciences (Grant No. KJZD-EW-M05-3).
Yamada, Masahiko G.; Soejima, Tomohiro; Tsuji, Naoto; Hirai, Daisuke; Dincǎ, Mircea; Aoki, Hideo
2016-08-01
We design from first principles a type of two-dimensional metal-organic framework (MOF) using phenalenyl-based ligands to exhibit a half-filled flat band of the kagome lattice, which is one of a family of lattices that show Lieb-Mielke-Tasaki's flat-band ferromagnetism. Among various MOFs, we find that trans-Au-THTAP (THTAP=trihydroxytriaminophenalenyl) has such an ideal band structure, where the Fermi energy is adjusted right at the flat band due to unpaired electrons of radical phenalenyl. The spin-orbit coupling opens a band gap giving a nonzero Chern number to the nearly flat band, as confirmed by the presence of the edge states in first-principles calculations and by fitting to the tight-binding model. This is a novel and realistic example of a system in which a nearly flat band is both ferromagnetic and topologically nontrivial.
Ochiai, Tetsuyuki
2016-01-01
Synthetic gauge field and pseudospin-orbit interaction are implemented in the stacked two-dimensional ring network model proposed by the present author. The model was introduced to simulate light propagation in the corresponding ring-resonator network, and is thus completely bosonic. Without these two items, the system exhibits Floquet-Weyl and Floquet-topological-insulator phases with topologically gapless and gapped band structures, respectively. The synthetic magnetic field implemented in the model results in a three-dimensional Hofstadter-butterfly-type spectrum in a photonic platform. The resulting gaps are characterization by the winding number of relevant S-matrices together with the Chern number of the bulk bands. The pseudospin-orbit interaction is defined as the mixing term between two pseudospin degrees of freedom in the rings, namely, the clockwise and counter-clockwise modes in the rings. It destroys the Floquet-topological-insulator phases, while the Floquet-Weyl phase with multiple Weyl points ...
Directory of Open Access Journals (Sweden)
Mitsuhiro Numata
2010-11-01
Full Text Available Two dimensional island arrays and honeycomb patterns consisting of ZnO nanocrystal clusters were fabricated on predefined TiO2 seed patterns prepared by vacuum free, aerosol assisted wet-chemical synthesis. The TiO2 seed patterns were prepared by applying an aerosol of a water soluble titanium complex on hexagonally close-packed polystyrene bead arrays for different lengths of time. Scanning electron microscopy revealed that a dot array grows into a honeycomb shape as increasing amounts of the precursor were deposited. ZnO nucleation on substrates with a dot array and honeycomb patterns resulted in the formation of two discrete patterns with contrasting fill fractions of the materials.
A new model for two-dimensional numerical simulation of pseudo-2D gas-solids fluidized beds
Energy Technology Data Exchange (ETDEWEB)
Li, Tingwen; Zhang, Yongmin
2013-10-11
Pseudo-two dimensional (pseudo-2D) fluidized beds, for which the thickness of the system is much smaller than the other two dimensions, is widely used to perform fundamental studies on bubble behavior, solids mixing, or clustering phenomenon in different gas-solids fluidization systems. The abundant data from such experimental systems are very useful for numerical model development and validation. However, it has been reported that two-dimensional (2D) computational fluid dynamic (CFD) simulations of pseudo-2D gas-solids fluidized beds usually predict poor quantitative agreement with the experimental data, especially for the solids velocity field. In this paper, a new model is proposed to improve the 2D numerical simulations of pseudo-2D gas-solids fluidized beds by properly accounting for the frictional effect of the front and back walls. Two previously reported pseudo-2D experimental systems were simulated with this model. Compared to the traditional 2D simulations, significant improvements in the numerical predictions have been observed and the predicted results are in better agreement with the available experimental data.
Optical probing of the metal-to-insulator transition in a two-dimensional high-mobility electron gas
Energy Technology Data Exchange (ETDEWEB)
Dionigi, F; Rossella, F; Bellani, V [Dipartimento di Fisica ' A Volta' and CNISM, Universita degli Studi di Pavia, 27100 Pavia (Italy); Amado, M [GISC and Departamento de Fisica de Materiales, Universidad Complutense, 28040 Madrid (Spain); Diez, E [Laboratorio de Bajas Temperaturas, Universidad de Salamanca, 37008 Salamanca (Spain); Kowalik, K [Laboratoire National des Champs Magnetiques Intenses, CNRS, 38042 Grenoble (France); Biasiol, G [Istituto Officina dei Materiali CNR, Laboratorio TASC, 34149 Trieste (Italy); Sorba, L, E-mail: vittorio.bellani@unipv.it [NEST, Istituto Nanoscienze-CNR and Scuola Normale Superiore, 56126 Pisa (Italy)
2011-06-15
We study the quantum Hall liquid and the metal-insulator transition in a high-mobility two-dimensional electron gas, by means of photoluminescence and magnetotransport measurements. In the integer and fractional regime at {nu}>1/3, by analyzing the emission energy dispersion we probe the magneto-Coulomb screening and the hidden symmetry of the electron liquid. In the fractional regime above {nu}=1/3, the system undergoes metal-to-insulator transition, and in the insulating phase the dispersion becomes linear with evidence of an increased renormalized mass.
Proskuryakov, Y. Y.; Savchenko, A. K.; Safonov, S. S.; Pepper, M; Simmons, M.Y.; Ritchie, D. A.
2001-01-01
On a high mobility two-dimensional hole gas (2DHG) in a GaAs/GaAlAs heterostructure we study the interaction correction to the Drude conductivity in the ballistic regime, $k_BT\\tau /\\hbar $ $>1$. It is shown that the 'metallic' behaviour of the resistivity ($d\\rho /dT>0$) of the low-density 2DHG is caused by hole-hole interaction effect in this regime. We find that the temperature dependence of the conductivity and the parallel-field magnetoresistance are in agreement with this description, a...
Directory of Open Access Journals (Sweden)
A. J. Ramirez-Pastor
2009-09-01
Full Text Available Using Monte Carlo simulations and finite-size scaling analysis, the critical behavior of attractive rigid rods of length $k$ ($k$-mers on square lattices at intermediate density has been studied. A nematic phase, characterized by a big domain of parallel $k$-mers, was found. This ordered phase is separated from the isotropic state by a continuous transition occurring at a intermediate density $heta_c$, which increases linearly with the magnitude of the lateral interactions.
Energy Technology Data Exchange (ETDEWEB)
Zhang, Hai-Feng, E-mail: hanlor@163.com, E-mail: lsb@nuaa.edu.cn [Key Laboratory of Radar Imaging and Microwave Photonics (Nanjing Univ. Aeronaut. Astronaut.), Ministry of Education, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); Nanjing Artillery Academy, Nanjing 211132 (China); Liu, Shao-Bin, E-mail: hanlor@163.com, E-mail: lsb@nuaa.edu.cn; Jiang, Yu-Chi [Key Laboratory of Radar Imaging and Microwave Photonics (Nanjing Univ. Aeronaut. Astronaut.), Ministry of Education, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)
2014-09-15
In this paper, the tunable all-angle negative refraction and photonic band gaps (PBGs) in two types of two-dimensional (2D) plasma photonic crystals (PPCs) composed of homogeneous plasma and dielectric (GaAs) with square-like Archimedean lattices (ladybug and bathroom lattices) for TM wave are theoretically investigated based on a modified plane wave expansion method. The type-1 structure is dielectric rods immersed in the plasma background, and the complementary structure is named as type-2 PPCs. Theoretical simulations demonstrate that the both types of PPCs with square-like Archimedean lattices have some advantages in obtaining the higher cut-off frequency, the larger PBGs, more number of PBGs, and the relative bandwidths compared to the conventional square lattices as the filling factor or radius of inserted rods is same. The influences of plasma frequency and radius of inserted rod on the properties of PBGs for both types of PPCs also are discussed in detail. The calculated results show that PBGs can be manipulated by the parameters as mentioned above. The possibilities of all-angle negative refraction in such two types of PPCs at low bands also are discussed. Our calculations reveal that the all-angle negative phenomena can be observed in the first two TM bands, and the frequency range of all-angle negative refraction can be tuned by changing plasma frequency. Those properties can be used to design the optical switching and sensor.
Zhang, Hai-Feng; Liu, Shao-Bin; Jiang, Yu-Chi
2014-09-01
In this paper, the tunable all-angle negative refraction and photonic band gaps (PBGs) in two types of two-dimensional (2D) plasma photonic crystals (PPCs) composed of homogeneous plasma and dielectric (GaAs) with square-like Archimedean lattices (ladybug and bathroom lattices) for TM wave are theoretically investigated based on a modified plane wave expansion method. The type-1 structure is dielectric rods immersed in the plasma background, and the complementary structure is named as type-2 PPCs. Theoretical simulations demonstrate that the both types of PPCs with square-like Archimedean lattices have some advantages in obtaining the higher cut-off frequency, the larger PBGs, more number of PBGs, and the relative bandwidths compared to the conventional square lattices as the filling factor or radius of inserted rods is same. The influences of plasma frequency and radius of inserted rod on the properties of PBGs for both types of PPCs also are discussed in detail. The calculated results show that PBGs can be manipulated by the parameters as mentioned above. The possibilities of all-angle negative refraction in such two types of PPCs at low bands also are discussed. Our calculations reveal that the all-angle negative phenomena can be observed in the first two TM bands, and the frequency range of all-angle negative refraction can be tuned by changing plasma frequency. Those properties can be used to design the optical switching and sensor.
Halliday, I; Lishchuk, S V; Spencer, T J; Pontrelli, G; Evans, P C
2016-08-01
We present a method for applying a class of velocity-dependent forces within a multicomponent lattice Boltzmann equation simulation that is designed to recover continuum regime incompressible hydrodynamics. This method is applied to the problem, in two dimensions, of constraining to uniformity the tangential velocity of a vesicle membrane implemented within a recent multicomponent lattice Boltzmann simulation method, which avoids the use of Lagrangian boundary tracers. The constraint of uniform tangential velocity is carried by an additional contribution to an immersed boundary force, which we derive here from physical arguments. The result of this enhanced immersed boundary force is to apply a physically appropriate boundary condition at the interface between separated lattice fluids, defined as that region over which the phase-field varies most rapidly. Data from this enhanced vesicle boundary method are in agreement with other data obtained using related methods [e.g., T. Krüger, S. Frijters, F. Günther, B. Kaoui, and J. Harting, Eur. Phys. J. 222, 177 (2013)10.1140/epjst/e2013-01834-y] and underscore the importance of a correct vesicle membrane condition.
Mohammadipour, Omid Reza; Niazmand, Hamid; Succi, Sauro
2017-03-01
In this paper, an alternative approach to implement initial and boundary conditions in the lattice Boltzmann method is presented. The main idea is to approximate the nonequilibrium component of distribution functions as a third-order power series in the lattice velocities and formulate a procedure to determine boundary node distributions by using fluid variables, consistent with such an expansion. The velocity shift associated with the body force effects is included in this scheme, along with an approximation to determine the mass density in complex geometries. Different strategies based on the present scheme are developed to implement velocity and pressure conditions for arbitrarily shaped boundaries, using the D2Q9, D3Q15, D3Q19 and D3Q27 lattices, in two and three space dimensions, respectively. The proposed treatment is tested against several well-established problems, showing second-order spatial accuracy and often improved behavior as compared to various existing methods, with no appreciable computational overhead.
Levin, A. D.; Gusev, G. M.; Raichev, O. E.; Momtaz, Z. S.; Bakarov, A. K.
2016-07-01
To study the influence of microwave irradiation on two-dimensional electrons, we apply a method based on capacitance measurements in GaAs quantum well samples where the gate covers a central part of the layer. We find that the capacitance oscillations at high magnetic fields, caused by the oscillations of thermodynamic density of states, are not essentially modified by microwaves. However, in the region of fields below 1 T, we observe another set of oscillations, with the period and the phase identical to those of microwave-induced resistance oscillations. The phenomenon of microwave-induced capacitance oscillations is explained in terms of violation of the Einstein relation between conductivity and the diffusion coefficient in the presence of microwaves, which leads to a dependence of the capacitor charging on the anomalous conductivity. We also observe microwave-induced oscillations in the capacitive response to periodic variations of external heating. These oscillations appear due to the thermoelectric effect and are in antiphase with microwave-induced resistance oscillations because of the Corbino-like geometry of our experimental setup.
Observation of mesoscopic crystalline structures in a two-dimensional Rydberg gas
Schauß, Peter; Endres, Manuel; Fukuhara, Takeshi; Hild, Sebastian; Omran, Ahmed; Pohl, Thomas; Gross, Christian; Kuhr, Stefan; Bloch, Immanuel
2012-01-01
The ability to control and tune interactions in ultracold atomic gases has paved the way towards the realization of new phases of matter. Whereas experiments have so far achieved a high degree of control over short-ranged interactions, the realization of long-range interactions would open up a whole new realm of many-body physics and has become a central focus of research. Rydberg atoms are very well-suited to achieve this goal, as the van der Waals forces between them are many orders of magnitude larger than for ground state atoms. Consequently, the mere laser excitation of ultracold gases can cause strongly correlated many-body states to emerge directly when atoms are transferred to Rydberg states. A key example are quantum crystals, composed of coherent superpositions of different spatially ordered configurations of collective excitations. Here we report on the direct measurement of strong correlations in a laser excited two-dimensional atomic Mott insulator using high-resolution, in-situ Rydberg atom imag...
Two-Dimensional Riemann Solver for Euler Equations of Gas Dynamics
Brio, M.; Zakharian, A. R.; Webb, G. M.
2001-02-01
We construct a Riemann solver based on two-dimensional linear wave contributions to the numerical flux that generalizes the one-dimensional method due to Roe (1981, J. Comput. Phys.43, 157). The solver is based on a multistate Riemann problem and is suitable for arbitrary triangular grids or any other finite volume tessellations of the plane. We present numerical examples illustrating the performance of the method using both first- and second-order-accurate numerical solutions. The numerical flux contributions are due to one-dimensional waves and multidimensional waves originating from the corners of the computational cell. Under appropriate CFL restrictions, the contributions of one-dimensional waves dominate the flux, which explains good performance of dimensionally split solvers in practice. The multidimensional flux corrections increase the accuracy and stability, allowing a larger time step. The improvements are more pronounced on a coarse mesh and for large CFL numbers. For the second-order method, the improvements can be comparable to the improvements resulting from a less diffusive limiter.
Coupled two-dimensional edge plasma and neutral gas modeling of tokamak scrape-off-layers
Energy Technology Data Exchange (ETDEWEB)
Maingi, R. [North Carolina State Univ., Raleigh, NC (United States)
1992-08-01
The objective of this study is to devise a detailed description of the tokamak scrape-off-layer (SOL), which includes the best available models of both the plasma and neutral species and the strong coupling between the two in many SOL regimes. A good estimate of both particle flux and heat flux profiles at the limiter/divertor target plates is desired. Peak heat flux is one of the limiting factors in determining the survival probability of plasma-facing-components at high power levels. Plate particle flux affects the neutral flux to the pump, which determines the particle exhaust rate. A technique which couples a two-dimensional (2-D) plasma and a 2-D neutral transport code has been developed (coupled code technique), but this procedure requires large amounts of computer time. Relevant physics has been added to an existing two-neutral-species model which takes the SOL plasma/neutral coupling into account in a simple manner (molecular physics model), and this model is compared with the coupled code technique mentioned above. The molecular physics model is benchmarked against experimental data from a divertor tokamak (DIII-D), and a similar model (single-species model) is benchmarked against data from a pump-limiter tokamak (Tore Supra). The models are then used to examine two key issues: free-streaming-limits (ion energy conduction and momentum flux) and the effects of the non-orthogonal geometry of magnetic flux surfaces and target plates on edge plasma parameter profiles.
The effect of surface roughness on rarefied gas flows by lattice Boltzmann method
Institute of Scientific and Technical Information of China (English)
Liu Chao-Feng; Ni Yu-Shan
2008-01-01
This paper studies the roughness effect combining with effects of rarefaction and compressibility by a lattice Boltzmann model for rarefied gas flows at high Knudsen numbers. By discussing the effect of the tangential momentum accommodation coefficient on the rough boundary condition, the lattice Boltzmann simulations of nitrogen and helium flows are performed in a two-dimensional microchannel with rough boundaries. The surface roughness effects in the microchannel on the velocity field, the mass flow rate and the friction coefficient are studied and analysed. Numerical results for the two gases in micro scale show different characteristics from macroscopic flows and demonstrate the feasibility of the lattice Boltzmann model in rarefied gas dynamics.
Welch, Kyle J; Hastings-Hauss, Isaac; Parthasarathy, Raghuveer; Corwin, Eric I
2014-04-01
We have constructed a macroscopic driven system of chaotic Faraday waves whose statistical mechanics, we find, are surprisingly simple, mimicking those of a thermal gas. We use real-time tracking of a single floating probe, energy equipartition, and the Stokes-Einstein relation to define and measure a pseudotemperature and diffusion constant and then self-consistently determine a coefficient of viscous friction for a test particle in this pseudothermal gas. Because of its simplicity, this system can serve as a model for direct experimental investigation of nonequilibrium statistical mechanics, much as the ideal gas epitomizes equilibrium statistical mechanics.
A two-dimensional Fermi gas in the BEC-BCS crossover
Energy Technology Data Exchange (ETDEWEB)
Ries, Martin Gerhard
2016-01-21
This thesis reports on the preparation of a 2D Fermi gas in the BEC-BCS crossover and the observation of the BKT transition into a quasi long-range ordered superfluid phase. The pair momentum distribution of the gas is probed by means of a matter-wave focusing technique which relies on time-of-flight evolution in a weak harmonic potential. This distribution holds the coherence properties of the gas. The quasi long-range ordered phase manifests itself as a sharp low-momentum peak. The temperature where it forms is identified as the transition temperature. By tuning the temperature and the interaction strength, the phase diagram of the 2D Fermi gas in the BEC-BCS crossover is mapped out. The phase coherence is investigated in a self-interference experiment. Furthermore, algebraic decay of correlations is observed in the trap average of the first order correlation function, which is obtained from the Fourier transform of the pair momentum distribution. This is in qualitative agreement with predictions of homogeneous theory for the superfluid phase in a 2D gas. The presented results provide a foundation for future experimental and theoretical studies of strongly correlated 2D Fermi gases. They might thus help to elucidate complex systems such as the electron gas in high-T{sub c} superconductors.
Almarza, N G; Pȩkalski, J; Ciach, A
2014-04-28
The triangular lattice model with nearest-neighbor attraction and third-neighbor repulsion, introduced by Pȩkalski, Ciach, and Almarza [J. Chem. Phys. 140, 114701 (2014)] is studied by Monte Carlo simulation. Introduction of appropriate order parameters allowed us to construct a phase diagram, where different phases with patterns made of clusters, bubbles or stripes are thermodynamically stable. We observe, in particular, two distinct lamellar phases-the less ordered one with global orientational order and the more ordered one with both orientational and translational order. Our results concern spontaneous pattern formation on solid surfaces, fluid interfaces or membranes that is driven by competing interactions between adsorbing particles or molecules.
Two Dimensional Incommensurate Spin Excitations and Lattice Fluctuations in La2 - x Bax CuO4
Wagman, J. J.; Carlo, J. P.; van Gastel, G.; Zhao, Y.; Kallin, A. B.; Mazurek, E.; Dabkowska, H. A.; Savicii, A.; Granroth, G. E.; Yamani, Z.; Tun, Z.; Gaulin, B. D.
2013-03-01
'Hour-glass' shaped dispersions of antiferromagnetic (AF) spin fluctuations are a robust feature common to many high temperature superconductors. In 214 cuprates, these phenomena are well known to display a strong dependence on the concentration of holes that are introduced into the copper oxide planes by doping. The incommensurability (IC) of the two dimensional magnetic order in this system is sensitive to hole concentration. Here, we present a series of neutron scattering measurements on single crystals of La2 - x Bax CuO4 (LBCO), with 0 . 035 <= x <= 0 . 095 , a doping range that spans the transition from diagonal to parallel IC ordering wavevectors, and from non-superconducting to superconducting ground states. Our measurements map out the evolution of the spin excitations for energies below ~ 50 meV, and focus on an enhancement in the scattered intensity centered in the 17-20 meV at the AF IC positions. This regime corresponds to the approximate crossing of very dispersive spin excitations and weakly dispersive low lying optic phonons in LBCO. NSERC, Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy
Directory of Open Access Journals (Sweden)
Ryan C. Blase
2015-03-01
Full Text Available In this paper, we describe a simple method for sampling, pre-concentrating, and separating volatile and semi-volatile components from two different cave atmospheres. Sampling is performed by capturing a volume of cave atmosphere in a Tedlar bag or Suma canister for sample storage and transport back to the laboratory. Loading a portion of the sample on a multi-bed sorption trap allows for sample pre-concentration prior to separation and detection of components on a comprehensive two-dimensional gas chromatograph (GC×GC. Comparison of two Texas caves reveals the power of comprehensive two-dimensional gas chromatography (GC×GC for volatile separation and detection, and to our knowledge marks the first use of GC×GC for the analysis of cave atmospheres. Analysis of the results revealed 138 and 146 chromatographic signals over an S/N threshold of 500 and direct comparison of the two samples revealed 50 identical chromatographic signals. This study is a first step toward demonstrating the ability of GC×GC to separate the complex volatiles and semi-volatiles in the cave atmosphere as a fingerprinting tool.
Biedermann, Maurus; Grob, Koni
2015-01-02
Many foods are contaminated by hydrocarbons of mineral oil or synthetic origin. High performance liquid chromatography on-line coupled with gas chromatography and flame ionization detection (HPLC-GC-FID) is a powerful tool for the quantitative determination, but it would often be desirable to obtain more information about the type of hydrocarbons in order to identify the source of the contamination and specify pertinent legislation. Comprehensive two-dimensional gas chromatography (GC×GC) is shown to produce plots distinguishing mineral oil saturated hydrocarbons (MOSH) from polymer oligomeric saturated hydrocarbons (POSH) and characterizing the degree of raffination of a mineral oil. The first dimension separation occurred on a phenyl methyl polysiloxane, the second on a dimethyl polysiloxane. Mass spectrometry (MS) was used for identification, FID for quantitative determination. This shows the substantial advances in chromatography to characterize complex hydrocarbon mixtures even as contaminants in food.
Zhou, Zhenyu; Zhao, Erhai; Liu, W Vincent
2015-03-13
Mott insulators with both spin and orbital degeneracy are pertinent to a large number of transition metal oxides. The intertwined spin and orbital fluctuations can lead to rather exotic phases such as quantum spin-orbital liquids. Here, we consider two-component (spin 1/2) fermionic atoms with strong repulsive interactions on the p band of the optical square lattice. We derive the spin-orbital exchange for quarter filling of the p band when the density fluctuations are suppressed, and show that it frustrates the development of long-range spin order. Exact diagonalization indicates a spin-disordered ground state with ferro-orbital order. The system dynamically decouples into individual Heisenberg spin chains, each realizing a Luttinger liquid accessible at higher temperatures compared to atoms confined to the s band.
Quantum anomaly, universal relations, and breathing mode of a two-dimensional Fermi gas.
Hofmann, Johannes
2012-05-01
In this Letter, we show that the classical SO(2,1) symmetry of a harmonically trapped Fermi gas in two dimensions is broken by quantum effects. The anomalous correction to the symmetry algebra is given by a two-body operator that is well known as the contact. Taking into account this modification, we are able to derive the virial theorem for the system and a universal relation for the pressure of a homogeneous gas. The existence of an undamped breathing mode is associated with the classical symmetry. We provide an estimate for the anomalous frequency shift of this oscillation at zero temperature and compare the result with a recent experiment by [E. Vogt et al., Phys. Rev. Lett. 108, 070404 (2012)]. Discrepancies are attributed to finite temperature effects.
2015-08-16
SUPPLEMENTARY NOTES 14. ABSTRACT The recent discovery of a two-dimensional electron gas (2DEG) at the interface between insulating perovskite ...3/10/2015 Abstract The recent discovery of a two-dimensional electron gas (2DEG) at the interface between insulating perovskite oxides SrTiO3...associated charge distributions in semiconductor materials, and therefore regarded as the only tool that can completely visualize the spatial
Two Dimensional Spin-Polarized Electron Gas at the Oxide Interfaces
Nanda, B. R. K.; Satpathy, S.
2008-01-01
The formation of a novel spin-polarized 2D electron gas at the LaMnO$_3$ monolayer embedded in SrMnO$_3$ is predicted from the first-principles density-functional calculations. The La (d) electrons become confined in the direction normal to the interface in the potential well of the La layer, serving as a positively-charged layer of electron donors. These electrons mediate a ferromagnetic alignment of the Mn t$_{2g}$ spins near the interface via the Anderson-Hasegawa double exchange and becom...
An accurate predictor-corrector HOC solver for the two dimensional Riemann problem of gas dynamics
Gogoi, Bidyut B.
2016-10-01
The work in the present manuscript is concerned with the simulation of twodimensional (2D) Riemann problem of gas dynamics. We extend our recently developed higher order compact (HOC) method from one-dimensional (1D) to 2D solver and simulate the problem on a square geometry with different initial conditions. The method is fourth order accurate in space and second order accurate in time. We then compare our results with the available benchmark results. The comparison shows an excellent agreement of our results with the existing ones in the literature. Being a finite difference solver, it is quite straight-forward and simple.
Quenching Plasma Waves in Two Dimensional Electron Gas by a Femtosecond Laser Pulse
Shur, Michael; Rudin, Sergey; Greg Rupper Collaboration; Andrey Muraviev Collaboration
Plasmonic detectors of terahertz (THz) radiation using the plasma wave excitation in 2D electron gas are capable of detecting ultra short THz pulses. To study the plasma wave propagation and decay, we used femtosecond laser pulses to quench the plasma waves excited by a short THz pulse. The femtosecond laser pulse generates a large concentration of the electron-hole pairs effectively shorting the 2D electron gas channel and dramatically increasing the channel conductance. Immediately after the application of the femtosecond laser pulse, the equivalent circuit of the device reduces to the source and drain contact resistances connected by a short. The total response charge is equal to the integral of the current induced by the THz pulse from the moment of the THz pulse application to the moment of the femtosecond laser pulse application. This current is determined by the plasma wave rectification. Registering the charge as a function of the time delay between the THz and laser pulses allowed us to follow the plasmonic wave decay. We observed the decaying oscillations in a sample with a partially gated channel. The decay depends on the gate bias and reflects the interplay between the gated and ungated plasmons in the device channel. Army Research Office.
Energy Technology Data Exchange (ETDEWEB)
Soria-Hoyo, C; Castellanos, A [Departamento de Electronica y Electromagnetismo, Facultad de Fisica, Universidad de Sevilla, Avda. Reina Mercedes s/n, 41012 Sevilla (Spain); Pontiga, F [Departamento de Fisica Aplicada II, EUAT, Universidad de Sevilla, Avda. Reina Mercedes s/n, 41012 Sevilla (Spain)], E-mail: cshoyo@us.es
2008-10-21
Two different numerical techniques have been applied to the numerical integration of equations modelling gas discharges: a finite-difference flux corrected transport (FD-FCT) technique and a particle-in-cell (PIC) technique. The PIC technique here implemented has been specifically designed for the simulation of 2D electrical discharges using cylindrical coordinates. The development and propagation of a streamer between two parallel electrodes has been used as a convenient test to compare the performance of both techniques. In particular, the phase velocity of the cathode directed streamer has been used to check the internal consistency of the numerical simulations. The results obtained from the two techniques are in reasonable agreement with each other, and both techniques have proved their ability to follow the high gradients of charge density and electric field present in this type of problems. Moreover, the streamer velocities predicted by the simulation are in accordance with the typical experimental values.
A high density two-dimensional electron gas in an oxide heterostructure on Si (001
Directory of Open Access Journals (Sweden)
E. N. Jin
2014-11-01
Full Text Available We present the growth and characterization of layered heterostructures comprised of LaTiO3 and SrTiO3 epitaxially grown on Si (001. Magnetotransport measurements show that the sheet carrier densities of the heterostructures scale with the number of LaTiO3/SrTiO3 interfaces, consistent with the presence of an interfacial 2-dimensional electron gas (2DEG at each interface. Sheet carrier densities of 8.9 × 1014 cm−2 per interface are observed. Integration of such high density oxide 2DEGs on silicon provides a bridge between the exceptional properties and functionalities of oxide 2DEGs and microelectronic technologies.
Mostafa, Ahmed; Górecki, Tadeusz
2016-05-17
A new liquid nitrogen-based single-stage cryogenic modulator was developed and characterized. In addition, a dedicated liquid nitrogen delivery system was developed. A well-defined restriction placed inside a deactivated fused silica capillary was used to increase the cooling surface area and provide very efficient trapping. At the same time, it enabled modulation of the carrier gas flow owing to changes in gas viscosity with temperature. Gas flow is almost unimpeded at the trapping temperature but reduced to nearly zero at the desorption temperature, which prevents analyte breakthrough. Peak widths for n-alkanes of 30-40 ms at half height were obtained. Most importantly, even the solvent peak could be modulated, which is not feasible with any commercially available thermal modulator. Evaluation of the newly developed system in two-dimensional gas chromatography (GC × GC) separations of some real samples such as regular gasoline and diesel fuel showed that the analytical performance of this single-stage modulator is fully competitive to those of the more complicated dual-stage modulators.
Hantao, Leandro Wang; Toledo, Bruna Regina; Ribeiro, Fabiana Alves de Lima; Pizetta, Marilia; Pierozzi, Caroline Geraldi; Furtado, Edson Luiz; Augusto, Fabio
2013-11-15
In this paper it is reported the use of the chromatographic profiles from volatile fractions of plant clones - in this case, hybrids of Eucalyptus grandis×Eucalyptus urophylla - to determine specimens susceptible to rust disease. The analytes were isolated by headspace solid phase microextraction (HS-SPME) and analyzed by comprehensive two-dimensional gas chromatography combined to fast quadrupole mass spectrometry (GC×GC-qMS). Parallel Factor Analysis (PARAFAC) was employed for estimate the correlation between the chromatographic profiles and resistance against Eucalyptus rust, after preliminary variable selection performed by Fisher ratio analysis. The proposed method allowed the differentiation between susceptible and non-susceptible clones and determination of three resistance biomarkers. This approach can be a valuable alternative for the otherwise time-consuming and labor-intensive methods commonly used.
Zeng, Shengwei; Lü, Weiming; Huang, Zhen; Liu, Zhiqi; Han, Kun; Gopinadhan, Kalon; Li, Changjian; Guo, Rui; Zhou, Wenxiong; Ma, Haijiao Harsan; Jian, Linke; Venkatesan, Thirumalai; Ariando
2016-04-26
Electric field effect in electronic double layer transistor (EDLT) configuration with ionic liquids as the dielectric materials is a powerful means of exploring various properties in different materials. Here, we demonstrate the modulation of electrical transport properties and extremely high mobility of two-dimensional electron gas at LaAlO3/SrTiO3 (LAO/STO) interface through ionic liquid-assisted electric field effect. With a change of the gate voltages, the depletion of charge carrier and the resultant enhancement of electron mobility up to 19 380 cm(2)/(V s) are realized, leading to quantum oscillations of the conductivity at the LAO/STO interface. The present results suggest that high-mobility oxide interfaces, which exhibit quantum phenomena, could be obtained by ionic liquid-assisted field effect.
Effect of In Composition on Two-Dimensional Electron Gas in Wurtzite AlGaN/InGaN Heterostructures
Institute of Scientific and Technical Information of China (English)
KIM Bong-Hwan; PARK Seoung-Hwan; LEE Jung-Hee; MOON Yong-Tae
2010-01-01
@@ The effect of In composition on two-dimensional electron gas in wurtzite AIGaN/InGaN heterostructures is theoretically investigated.The sheet carrier density is shown to increase nearly linearly with In mole fraction x,due to the increase in the polarization charge at the AlGaN/InGaN interface.The electron sheet density is enhanced with the doping in the AlGaN layer.The sheet carrier density is as high as 3.7 × 1013 cm-2 at the donor density of 10 x 1018 cm-3 for the HEMT structure with x = 0.3.The contribution of additional donor density on the electron sheet density is nearly independent of the In mole fraction.
Proskuryakov, Y Y; Savchenko, A K; Safonov, S S; Pepper, M; Simmons, M Y; Ritchie, D A
2002-08-12
On a high-mobility two-dimensional hole gas (2DHG) in a GaAs/GaAlAs heterostructure we study the interaction correction to the Drude conductivity in the ballistic regime, k(B)Ttau/ variant Planck's over 2pi >1. It is shown that the "metallic" behavior of the resistivity (drho/dT>0) of the low-density 2DHG is caused by the hole-hole interaction effect in this regime. We find that the temperature dependence of the conductivity and the parallel-field magnetoresistance are in agreement with this description, and determine the Fermi-liquid interaction constant Fsigma0 which controls the sign of drho/dT.
Development of an ultra-fast data-acquisition system for a two-dimensional microstrip gas chamber.
Ochi, A; Tanimori, T; Nishi, Y; Aoki, S; Nishi, Y
1998-05-01
A high-performance data-acquisition system has been developed in order to obtain time-resolved sequential images from a two-dimensional microstrip gas chamber (MSGC). This was achieved using fully digital processing with a synchronized pipeline method. Complex logical circuits for processing large numbers of signals are mounted on a small number of complex programmable logic devices. The system is operated with a 10 MHz synchronous clock, and has the capability of handling more than 3 x 10(6) counts s(-1) for asynchronous events. The system was examined using a 5 x 5 cm MSGC and the recently developed 10 x 10 cm MSGC (1024 outputs); the anticipated performances were achieved.
Bound states of a negative test charge due to many-body effects in the two-dimensional electron gas
Ghazali, A.; Gold, A.
1995-12-01
Bound states of a negative test electron in the low-density regime of the two-dimensional electron gas are obtained when many-body effects (exchange and correlation) are incorporated in the screening function via the local-field correction. Using the Green's-function method and a variational method we determine the energies and the wave functions of the ground state and the excited states as functions of the electron density. For high electron density no bound state is found. Below a critical density the number and the energy of bound states increase with decreasing electron density. The ground state is described by the wave function ψ2s~r exp(-r/α).
Shock wave structure in a lattice gas
Broadwell, James E.; Han, Donghee
2007-05-01
The motion and structure of shock and expansion waves in a simple particle system, a lattice gas and cellular automaton, are determined in an exact computation. Shock wave solutions, also exact, of a continuum description, a model Boltzmann equation, are compared with the lattice results. The comparison demonstrates that, as proved by Caprino et al. ["A derivation of the Broadwell equation," Commun. Math. Phys. 135, 443 (1991)] only when the lattice processes are stochastic is the model Boltzmann description accurate. In the strongest shock wave, the velocity distribution function is the bimodal function proposed by Mott-Smith.
Zhu, Shuai; Gao, Lirong; Zheng, Minghui; Liu, Huimin; Zhang, Bing; Liu, Lidan; Wang, Yiwen
2014-01-01
Toxaphene, which is a broad spectrum chlorinated pesticide, is a complex mixture of several hundred congeners, mainly polychlorinated bornanes. Quantifying toxaphene in environmental samples is difficult because of its complexity, and because each congener has a different response factor. Toxaphene chromatograms acquired using one-dimensional gas chromatography (1DGC) show that this technique cannot be used to separate all of the toxaphene congeners. We developed and validated a sensitive and quantitative method for determining three indicator toxaphene congeners in soil using an isotope dilution/comprehensive two-dimensional gas chromatography-tandem mass spectrometry (GC × GC-MS). The samples were extracted using accelerated solvent extraction, and then the extracts were purified using silica gel columns. (13)C₁₀-labeled Parlar 26 and 50 were used as internal standards and (13)C₁₀-labeled Parlar 62 was used as an injection standard. The sample extraction and purification treatments and the GC × GC-MS parameters were optimized. Subsequently the samples were determined by GC × GC-MS. The limits of detection for Parlar 26, 50, and 62 were 0.6 pg/g, 0.4 pg/g, and 1.0 pg/g (S/N=3), respectively, and the calibration curves had good linear correlations between 50 and 1000 μg/L (r(2)>0.99). Comprehensive two-dimensional GC gave substantial improvements over one-dimensional GC in the toxaphene analysis. We analyzed soil samples containing trace quantities of toxaphene to demonstrate that the developed method could be used to analyze toxaphene in environmental samples.
Interplay between Rashba spin-orbit coupling and adiabatic rotation in a two-dimensional Fermi gas
Doko, E.; Subaşı, A. L.; Iskin, M.
2017-01-01
We explore the trap profiles of a two-dimensional atomic Fermi gas in the presence of a Rashba spin-orbit coupling and under an adiabatic rotation. We first consider a noninteracting gas and show that the competition between the effects of Rashba coupling on the local density of single-particle states and the Coriolis effects caused by rotation gives rise to a characteristic ring-shaped density profile that survives at experimentally accessible temperatures. Furthermore, Rashba splitting of the Landau levels gives the density profiles a ziggurat shape in the rapid-rotation limit. We then consider an interacting gas under the BCS mean-field approximation for local pairing, and study the pair-breaking mechanism that is induced by the Coriolis effects on superfluidity, where we calculate the critical rotation frequencies both for the onset of pair breaking and for the complete destruction of superfluidity in the system. In particular, by comparing the results of a fully-quantum-mechanical Bogoliubov-de Gennes approach with those of a semiclassical local-density approximation, we construct extensive phase diagrams for a wide range of parameter regimes in the trap where the aforementioned competition may, e.g., favor an outer normal edge that is completely phase separated from the central superfluid core by vacuum.
Simple stochastic lattice gas automaton model for formation of river networks
Yan, Guangwu; Zhang, Jianying; Wang, Huimin; Guo, Li
2008-12-01
A stochastic lattice gas automata model for formation of river networks is proposed. The model is based on two-dimensional lattice gas automata with three fundamental principles at each node. The water source is regarded as a fixed point where a drop of water drips every time step. This system can be treated as a memory network: the probability of water moving along a direction relies on the history of the channel segment along which water drops have moved. Last, we find that the width of the river channel and the number of channels with this width meet a scaling law when the system reaches a critical status.
Dynamic structure factor in single- and two-species thermal GBL lattice gas
Dubbeldam, D.; Hoekstra, A. G.; Sloot, P. M. A.
2000-07-01
The two-dimensional 19-bits GBL lattice gas model conserves energy in a non-trivial way, allowing temperature, temperature gradients, and heat conduction. We describe the thermodynamics of the model, its equilibrium properties, and confirm the change of sound speed with energy density at fixed density with simulation results. The sound speed, the sound damping, and the thermal diffusivity are extracted from the dynamic structure factor and shown for various energy densities at fixed density. We have extended the 19 bits GBL model with multiple-species (miscible fluid model) and have measured the dynamic structure factor for this two-component thermal lattice gas model.
Tessarolo, Nathalia S; dos Santos, Luciana R M; Silva, Raphael S F; Azevedo, Débora A
2013-03-01
The liquid product obtained via the biomass flash pyrolysis is commonly called bio-oil or pyrolysis oil. Bio-oils can be used as sources for chemicals or as fuels, primarily in mixtures or emulsions with fossil fuels. A detailed chemical characterization of bio-oil is necessary to determine its potential uses. Such characterization demands a powerful analytical technique such as comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×GC-TOFMS). Limited chemical information can be obtained from conventional gas chromatography coupled mass spectrometry (GC-MS) because of the large number of compounds and coelutions. Thus, GC×GC-TOFMS was used for the individual identification of bio-oil components from two samples prepared via the flash pyrolysis of empty palm fruit bunch and pine wood chips. To the best of our knowledge, few papers have reported comprehensive two-dimensional gas chromatography (GC×GC) for bio-oil analysis. Many classes of compounds such as phenols, benzenediols, cyclopentenones, furanones, indanones and alkylpyridines were identified. Several coelutions present in the GC-MS were resolved using GC×GC-TOFMS. Many peaks were detected for the samples by GC-MS (~166 and 129), but 631 and 857 were detected by GC×GC-TOFMS, respectively. The GC×GC-TOFMS analyses indicated that the major classes of components (analytes>0.5% relative area) in the two bio-oil samples are ketones, cyclopentenones, furanones, furans, phenols, benzenediols, methoxy- and dimethoxy-phenols and sugars. In addition, esters, aldehydes and pyridines were found for sample obtained from empty palm fruit bunch, while alcohols and cyclopentanediones were found in sample prepared from pine wood chips indicating different composition profiles due to the biomass sources. The elucidation of the composition of empty fruit bunch and pine wood chips bio-oils indicates that these oils are suitable for the production of value-added chemicals. The
Energy Technology Data Exchange (ETDEWEB)
Elton, A.B.H.
1990-09-24
A numerical theory for the massively parallel lattice gas and lattice Boltzmann methods for computing solutions to nonlinear advective-diffusive systems is introduced. The convergence theory is based on consistency and stability arguments that are supported by the discrete Chapman-Enskog expansion (for consistency) and conditions of monotonicity (in establishing stability). The theory is applied to four lattice methods: Two of the methods are for some two-dimensional nonlinear diffusion equations. One of the methods is for the one-dimensional lattice method for the one-dimensional viscous Burgers equation. And one of the methods is for a two-dimensional nonlinear advection-diffusion equation. Convergence is formally proven in the L{sub 1}-norm for the first three methods, revealing that they are second-order, conservative, conditionally monotone finite difference methods. Computational results which support the theory for lattice methods are presented. In addition, a domain decomposition strategy using mesh refinement techniques is presented for lattice gas and lattice Boltzmann methods. The strategy allows concentration of computational resources on regions of high activity. Computational evidence is reported for the strategy applied to the lattice gas method for the one-dimensional viscous Burgers equation. 72 refs., 19 figs., 28 tabs.
Liu, Jing; Seo, Jung Hwan; Li, Yubo; Chen, Di; Kurabayashi, Katsuo; Fan, Xudong
2013-03-07
We developed a novel smart multi-channel two-dimensional (2-D) micro-gas chromatography (μGC) architecture that shows promise to significantly improve 2-D μGC performance. In the smart μGC design, a non-destructive on-column gas detector and a flow routing system are installed between the first dimensional separation column and multiple second dimensional separation columns. The effluent from the first dimensional column is monitored in real-time and decision is then made to route the effluent to one of the second dimensional columns for further separation. As compared to the conventional 2-D μGC, the greatest benefit of the smart multi-channel 2-D μGC architecture is the enhanced separation capability of the second dimensional column and hence the overall 2-D GC performance. All the second dimensional columns are independent of each other, and their coating, length, flow rate and temperature can be customized for best separation results. In particular, there is no more constraint on the upper limit of the second dimensional column length and separation time in our architecture. Such flexibility is critical when long second dimensional separation is needed for optimal gas analysis. In addition, the smart μGC is advantageous in terms of elimination of the power intensive thermal modulator, higher peak amplitude enhancement, simplified 2-D chromatogram re-construction and potential scalability to higher dimensional separation. In this paper, we first constructed a complete smart 1 × 2 channel 2-D μGC system, along with an algorithm for automated control/operation of the system. We then characterized and optimized this μGC system, and finally employed it in two important applications that highlight its uniqueness and advantages, i.e., analysis of 31 workplace hazardous volatile organic compounds, and rapid detection and identification of target gas analytes from interference background.
Nan, He; Zhang, Cheng; O'Brien, Richard A; Benchea, Adela; Davis, James H; Anderson, Jared L
2017-01-20
Lipidic ionic liquids (ILs) possessing long alkyl chains as well as low melting points have the potential to provide unique selectivity as well as wide operating ranges when used as stationary phases in gas chromatography. In this study, a total of eleven lipidic ILs containing various structural features (i.e., double bonds, linear thioether chains, and cyclopropanyl groups) were examined as stationary phases in comprehensive two dimensional gas chromatography (GC×GC) for the separation of nonpolar analytes in kerosene. N-alkyl-N'-methyl-imidazolium-based ILs containing different alkyl side chains were used as model structures to investigate the effects of alkyl moieties with different structural features on the selectivities and operating temperature ranges of the IL-based stationary phases. Compared to a homologous series of ILs containing saturated side chains, lipidic ILs exhibit improved selectivity toward the aliphatic hydrocarbons in kerosene. The palmitoleyl IL provided the highest selectivity compared to all other lipidic ILs as well as the commercial SUPELCOWAX 10 column. The linoleyl IL containing two double bonds within the alkyl side chain showed the lowest chromatographic selectivity. The lipidic IL possessing a cyclopropanyl group within the alkyl moiety exhibited the highest thermal stability. The Abraham solvation parameter model was used to evaluate the solvation properties of the lipidic ILs. This study provides the first comprehensive examination into the relation between lipidic IL structure and the resulting solvation characteristics. Furthermore, these results establish a basis for applying lipidic ILs as stationary phases for solute specific separations in GC×GC.
Energy Technology Data Exchange (ETDEWEB)
Reddy, Christopher; Nelson, Robert
2013-03-27
The development of comprehensive two-dimensional gas chromatography (GC x GC) has expanded the analytical window for studying complex mixtures like oil. Compared to traditional gas chromatography, this technology separates and resolves at least an order of magnitude more compounds, has a much larger signal to noise ratio, and sorts compounds based on their chemical class; hence, providing highly refined inventories of petroleum hydrocarbons in geochemical samples that was previously unattainable. In addition to the increased resolution afforded by GC x GC, the resulting chromatograms have been used to estimate the liquid vapor pressures, aqueous solubilities, octanol-water partition coefficients, and vaporization enthalpies of petroleum hydrocarbons. With these relationships, powerful and incisive analyses of phase-transfer processes affecting petroleum hydrocarbon mixtures in the environment are available. For example, GC x GC retention data has been used to quantitatively deconvolve the effects of phase transfer processes such as water washing and evaporation. In short, the positive attributes of GC x GC-analysis have led to a methodology that has revolutionized the analysis of petroleum hydrocarbons. Overall, this research has opened numerous fields of study on the biogeochemical "genetics" (referred to as petroleomics) of petroleum samples in both subsurface and surface environments. Furthermore, these new findings have already been applied to the behavior of oil at other seeps as well, for petroleum exploration and oil spill studies.
Blomberg, Jan; Riemersma, Toby; van Zuijlen, Manfred; Chaabani, Hassan
2004-09-24
Within the petrochemical industry, there has been a growing interest in methods capable of providing detailed information on the distribution of sulphur-containing compounds in various product streams, going down to the level of separating and quantifying individual sulphur species. Since no single capillary gas chromatographic column is able to perform this separation, a refuge to multi-dimensional separation techniques has to be taken. In this respect, comprehensive two-dimensional gas chromatography (GC x GC) coupled with sulphur chemiluminescence detection (SCD) has shown to be highly promising. It has been suggested, however, that the detector volume of an SCD restricts its potential to keep up with the fast second-dimension separations of contemporary GC x GC. In this paper, we will demonstrate that the lack of speed of the SCD does not originate from its physical dimensions, but is largely determined by the speed of the electronics used. Additionally, some typical examples will be presented to illustrate the potential of GC x GC coupled with fast SCD.
Two-dimensional time-dependent modelling of fume formation in a pulsed gas metal arc welding process
Boselli, M.; Colombo, V.; Ghedini, E.; Gherardi, M.; Sanibondi, P.
2013-06-01
Fume formation in a pulsed gas metal arc welding (GMAW) process is investigated by coupling a time-dependent axi-symmetric two-dimensional model, which takes into account both droplet detachment and production of metal vapour, with a model for fume formation and transport based on the method of moments for the solution of the aerosol general dynamic equation. We report simulative results of a pulsed process (peak current = 350 A, background current 30 A, period = 9 ms) for a 1 mm diameter iron wire, with Ar shielding gas. Results showed that metal vapour production occurs mainly at the wire tip, whereas fume formation is concentrated in the fringes of the arc in the spatial region close to the workpiece, where metal vapours are transported by convection. The proposed modelling approach allows time-dependent tracking of fumes also in plasma processes where temperature-time variations occur faster than nanoparticle transport from the nucleation region to the surrounding atmosphere, as is the case for most pulsed GMAW processes.
Wulf, Volker; Wienand, Nils; Wirtz, Michaela; Kling, Hans-Willi; Gäb, Siegmar; Schmitz, Oliver J
2010-01-29
Multidimensional gas-chromatographic analyses of olesochemically based nonionic, anionic and several cationic surfactants in industrial cleaners are demonstrated. Comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry allows the simultaneous determination of fatty alcohols, fatty alcohol sulphates and alkyl polyglucosides. In addition, the determination of fatty alcohol ethoxylates up to C(10)EO(8) (highest degree of ethoxylation) and C(18)EO(5) (longest C-chain at an ethoxylation degree of five) and the analysis of fatty alcohol alkoxylates that contain ethoxy (EO) and propoxy (PO) groups could be realized. Because of decomposition in the injector and a weak EI-fragmentation, cationic surfactants such as alkyl benzyl dimethyl ammonium chloride could also be identified by their characteristic fragments. Thermogravimetric analyses confirmed that the temperature in a normal GC injector is not high enough to cause thermal decomposition of esterquats. However, we could demonstrate that a modified silylation procedure forms decomposition products of esterquats in the GC injector which are detectable by GCxGC-(TOF)MS and allows the identification of such GC-atypical analytes.
Multisite Interactions in Lattice-Gas Models
Einstein, T. L.; Sathiyanarayanan, R.
For detailed applications of lattice-gas models to surface systems, multisite interactions often play at least as significant a role as interactions between pairs of adatoms that are separated by a few lattice spacings. We recall that trio (3-adatom, non-pairwise) interactions do not inevitably create phase boundary asymmetries about half coverage. We discuss a sophisticated application to an experimental system and describe refinements in extracting lattice-gas energies from calculations of total energies of several different ordered overlayers. We describe how lateral relaxations complicate matters when there is direct interaction between the adatoms, an issue that is important when examining the angular dependence of step line tensions. We discuss the connector model as an alternative viewpoint and close with a brief account of recent work on organic molecule overlayers.
Wang, Jian; Wei, Xiaowei; Wangyang, Peihua
2015-12-01
Zn-doped NiO two-dimensional grainy films on glass substrates are shown to be an ammonia-sensing material with excellent comprehensive performance, which could real-time detect and monitor ammonia (NH3) in the surrounding environment. The morphology and structure analysis indicated that the as-fabricated semiconductor films were composed of particles with diameters ranging from 80 to 160 nm, and each particle was composed of small crystalline grain with a narrow size about 20 nm, which was the face-centered cubic single crystal structure. X-ray diffraction peaks shifted toward lower angle, and the size of the lattice increased compared with undoped NiO, which demonstrated that zinc ions have been successfully doped into the NiO host structure. Simultaneously, we systematically investigated the gas-sensing properties of the Zn-doped NiO sensors for NH3 detection at room temperature. The sensor based on doped NiO sensing films gave four to nine times faster response and four to six times faster recovery speeds than those of sensor with undoped NiO films, which is important for the NiO sensor practical applications. Moreover, we found that the doped NiO sensors owned outstanding selectivity toward ammonia.
Hoomans, B.P.B.; Kuipers, J.A.M.; Briels, Willem J.; van Swaaij, Willibrordus Petrus Maria
1996-01-01
A discrete particle model of a gas-fluidised bed has been developed and in this the two-dimensional motion of the individual, spherical particles was directly calculated from the forces acting on them, accounting for the interaction between the particles and the interstitial gas phase. Our collision
Self-similarity of phase-space networks of frustrated spin models and lattice gas models
Peng, Yi; Wang, Feng; Han, Yilong
2013-03-01
We studied the self-similar properties of the phase-spaces of two frustrated spin models and two lattice gas models. The frustrated spin models included (1) the anti-ferromagnetic Ising model on a two-dimensional triangular lattice (1a) at the ground states and (1b) above the ground states and (2) the six-vertex model. The two lattice gas models were (3) the one-dimensional lattice gas model and (4) the two-dimensional lattice gas model. The phase spaces were mapped to networks so that the fractal analysis of complex networks could be applied, i.e. the box-covering method and the cluster-growth method. These phase spaces, in turn, establish new classes of networks with unique self-similar properties. Models 1a, 2, and 3 with long-range power-law correlations in real space exhibit fractal phase spaces, while models 1b and 4 with short-range exponential correlations in real space exhibit nonfractal phase spaces. This behavior agrees with one of untested assumptions in Tsallis nonextensive statistics. Hong Kong GRC grants 601208 and 601911
Diffusive description of lattice gas models
DEFF Research Database (Denmark)
Fiig, T.; Jensen, H.J.
1993-01-01
in time. We have numerically investigated the power spectrum of the density fluctuations, the lifetime distribution, and the spatial correlation function. We discuss the appropriate Langevin-like diffusion equation which can reproduce our numerical findings. Our conclusion is that the deterministic...... lattice gases are described by a diffusion equation without any bulk noise. The open lattice gas exhibits a crossover behavior as the probability for introducing particles at the edge of the system becomes small. The power spectrum changes from a 1/f to a 1/f2 spectrum. The diffusive description, proven...
Hantao, Leandro Wang; Aleme, Helga Gabriela; Passador, Martha Maria; Furtado, Edson Luiz; Ribeiro, Fabiana Alves de Lima; Poppi, Ronei Jesus; Augusto, Fabio
2013-03-01
In this paper is reported the use of the chromatographic profiles of volatiles to determine disease markers in plants - in this case, leaves of Eucalyptus globulus contaminated by the necrotroph fungus Teratosphaeria nubilosa. The volatile fraction was isolated by headspace solid phase microextraction (HS-SPME) and analyzed by comprehensive two-dimensional gas chromatography-fast quadrupole mass spectrometry (GC×GC-qMS). For the correlation between the metabolic profile described by the chromatograms and the presence of the infection, unfolded-partial least squares discriminant analysis (U-PLS-DA) with orthogonal signal correction (OSC) were employed. The proposed method was checked to be independent of factors such as the age of the harvested plants. The manipulation of the mathematical model obtained also resulted in graphic representations similar to real chromatograms, which allowed the tentative identification of more than 40 compounds potentially useful as disease biomarkers for this plant/pathogen pair. The proposed methodology can be considered as highly reliable, since the diagnosis is based on the whole chromatographic profile rather than in the detection of a single analyte.
Biedermann, Maurus; Barp, Laura; Kornauth, Christoph; Würger, Tanja; Rudas, Margaretha; Reiner, Angelika; Concin, Nicole; Grob, Koni
2015-02-15
Mineral oil hydrocarbons are by far the largest contaminant in the human body. Their composition differs from that in the mineral oils humans are exposed to, and varies also between different tissues of the same individual. Using the presently best technique for characterizing the composition of mineral oil hydrocarbons, comprehensive two-dimensional gas chromatography (GC×GC), the hydrocarbons in human tissues were compared to those of various mineral oils. This provided information about the strongly accumulated species and might give hints on the flow path through the human body. The selectivity of accumulation is probably also of interest for the risk assessment of synthetic hydrocarbons (polyolefins). GC×GC grouped the MOSH into classes of n-alkanes, paraffins with a low degree of branching, multibranched paraffins and naphthenes (alkylated cyclic hydrocarbons) with 1-4 rings. Metabolic elimination was observed for constituents of all these classes, but was selective within each class. The MOSH in the subcutaneous abdominal fat tissues and the mesenteric lymph nodes (MLN) had almost the same composition and included the distinct signals observed in mineral oil, though in reduced amounts relative to the cloud of unresolved hydrocarbons. The MOSH in the liver and the spleen were different from those in the MLN and fat tissue, but again with largely identical composition for a given individual. Virtually all constituents forming distinct signals were eliminated, leaving an unresolved residue of highly isomerized hydrocarbons.
The low-temperature mobility of two-dimensional electron gas in AlGaN/GaN heterostructures
Institute of Scientific and Technical Information of China (English)
Zhang Jin-Feng; Mao Wei; Zhang Jin-Cheng; Hao Yue
2008-01-01
To reveal the internal physics of the low-temperature mobility of two-dimensional electron gas (2DEG) in AlGaN/GaN heterostructures, we present a theoretical study of the strong dependence of 2DEG mobility on Al content and thickness of AlGaN barrier layer. The theoretical results are compared with one of the highest measured of 2DEG mobility reported for AlGaN/GaN heterostructures. The 2DEG mobility is modelled as a combined effect of the scattering mechanisms including acoustic deformation-potential, piezoelectric, ionized background donor, surface donor, dislocation, alloy disorder and interface roughness scattering. The analyses of the individual scattering processes show that the dominant scattering mechanisms are the alloy disorder scattering and the interface roughness scattering at low temperatures. The variation of 2DEG mobility with the barrier layer parameters results mainly from the change of 2DEG density and distribution. It is suggested that in AlGaN/GaN samples with a high Al content or a thick AlGaN layer, the interface roughness scattering may restrict the 2DEG mobility significantly, for the AlGan/GaN interface roughness increases due to the stress accumulation in AlGaN layer.
The mobility of two-dimensional electron gas in AlGaN/GaN heterostructures with varied Al content
Institute of Scientific and Technical Information of China (English)
ZHANG JinFeng; HAO Yue; ZHANG JinCheng; NI JinYu
2008-01-01
The mobility of the two-dimensional electron gas (2DEG) in AlGaN/GaN hetero-structures changes significantly with AI content in the AlGaN barrier layer, while few mechanism analyses focus on it. Theoretical calculation and analysis of the 2DEG mobility in AlGaN/GaN heterostructures with varied Al content are carried out based on the recently reported experimental data. The 2DEG mobility is modeled analytically as the total effects of the scattering mechanisms including acoustic deformation-potential, piezoelectric, polar optic phonon, alloy disorder, interface roughness, dislocation and remote modulation doping scattering. We show that the increase of the 2DEG density, caused by the ascension of the Al content in the barrier layer, is a dominant factor that leads to the changes of the individual scat-tering processes. The change of the 2DEG mobility with Al content are mainly de-termined by the interface roughness scattering and the alloy disorder scattering at 77 K, and the polar optic phonon scattering and the interface roughness scattering at the room temperature. The calculated function of the interface roughness pa-rameters on the Al content shows that the stress caused AlGaN/GaN interface degradation at higher Al content is an important factor in the limitation of the in-terface roughness scattering on the 2DEG mobility in AlGaN/GaN heterostructures with high Al content.
Rees, Christiaan A; Shen, Aimee; Hill, Jane E
2016-12-15
Clostridium difficile is a bacterial pathogen capable of causing life-threatening infections of the gastrointestinal tract characterized by severe diarrhea. Exposure to certain classes of antibiotics, advanced age, and prolonged hospitalizations are known risk factors for infection by this organism. Anecdotally, healthcare providers have reported that they can smell C. difficile infections in their patients, and several studies have suggested that there may indeed be an olfactory signal associated with C. difficile-associated diarrhea. In this study, we sought to characterize the volatile molecules produced by an epidemic strain of C. difficile (R20291) using headspace solid-phase microextraction (HS-SPME) followed by two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS). We report on a set of 77 volatile compounds, of which 59 have not previously been associated with C. difficile growth in vitro. Amongst these reported compounds, we detect both straight-chain and branched-chain carboxylic acids, as well as p-cresol, which have been the primary foci of C. difficile volatile metabolomic studies to-date. We additionally report on novel sulfur-containing and carbonyl-containing molecules that have not previously been reported for C. difficile. With the identification of these novel C. difficile-associated volatile compounds, we demonstrate the superior resolution and sensitivity of GC×GC-TOFMS relative to traditional GC-MS. Copyright © 2016 Elsevier B.V. All rights reserved.
Directory of Open Access Journals (Sweden)
H. J. Harsan Ma
2015-08-01
Full Text Available The two-dimensional electron gas (2DEG formed at the perovskite oxides heterostructures is of great interest because of its potential applications in oxides electronics and nanoscale multifunctional devices. A canonical example is the 2DEG at the interface between a polar oxide LaAlO3 (LAO and non-polar SrTiO3 (STO. Here, the LAO polar oxide can be regarded as the modulating or doping layer and is expected to define the electronic properties of 2DEG at the LAO/STO interface. However, to practically implement the 2DEG in electronics and device design, desired properties such as tunable 2D carrier density are necessary. Here, we report the tuning of conductivity threshold, carrier density and electronic properties of 2DEG in LAO/STO heterostructures by insertion of a La0.5Sr0.5TiO3 (LSTO layer of varying thicknesses, and thus modulating the amount of polarization of the oxide over layers. Our experimental result shows an enhancement of carrier density up to a value of about five times higher than that observed at the LAO/STO interface. A complete thickness dependent metal-insulator phase diagram is obtained by varying the thickness of LAO and LSTO providing an estimate for the critical thickness needed for the metallic phase. The observations are discussed in terms of electronic reconstruction induced by polar oxides.
Two-Dimensional Electron Gas at SrTiO3-Based Oxide Heterostructures via Atomic Layer Deposition
Directory of Open Access Journals (Sweden)
Sang Woon Lee
2016-01-01
Full Text Available Two-dimensional electron gas (2DEG at an oxide interface has been attracting considerable attention for physics research and nanoelectronic applications. Early studies reported the formation of 2DEG at semiconductor interfaces (e.g., AlGaAs/GaAs heterostructures with interesting electrical properties such as high electron mobility. Besides 2DEG formation at semiconductor junctions, 2DEG was realized at the interface of an oxide heterostructure such as the LaAlO3/SrTiO3 (LAO/STO heterojunction. The origin of 2DEG was attributed to the well-known “polar catastrophe” mechanism in oxide heterostructures, which consist of an epitaxial LAO layer on a single crystalline STO substrate among proposed mechanisms. Recently, it was reported that the creation of 2DEG was achieved using the atomic layer deposition (ALD technique, which opens new functionality of ALD in emerging nanoelectronics. This review is focused on the origin of 2DEG at oxide heterostructures using the ALD process. In particular, it addresses the origin of 2DEG at oxide interfaces based on an alternative mechanism (i.e., oxygen vacancies.
Institute of Scientific and Technical Information of China (English)
Sun Li-Feng; Dong Li-Min; Wu Zhi-Fang; Fang Chao
2013-01-01
we studied and compared the transport properties of charge carriers in bilayer graphene,monolayer graphene,and the conventional semiconductors (the two-dimensional electron gas (2DEG)).It is elucidated that the normal incidence transmission in the bilayer graphene is identical to that in the 2DEG but totally different from that in the monolayer graphene.However,resonant peaks appear in the non-normal incidence transmission profile for a high barrier in the bilayer graphene,which do not occur in the 2DEG.Furthermore,there are tunneling and forbidden regions in the transmission spectrum for each material,and the division of the two regions has been given in the work.The tunneling region covers a wide range of the incident energy for the two graphene systems,but only exists under specific conditions for the 2DEG.The counterparts of the transmission in the conductance profile are also given for the three materials,which may be used as high-performance devices based on the bilayer graphene.
Tran, Tin C.; Marriott, Philip J.
Comprehensive two-dimensional gas chromatography in tandem with flame ionization detection (GC×GC-FID) was used for the qualitative fingerprint characterisation of four different types of powdered incense headspace (H/S), and incense smoke. Volatile organic compounds (VOCs) in the incense powder and smoke were extracted by using solid phase microextraction (SPME) with a polydimethylsiloxane/divinylbenzene (PDMS/DVB) 65 μm fiber. Low-polarity/polar, and polar/non-polar phase combinations were tested to contrast the GC×GC separation of components in these two column sets. A total of 324 compounds were tentatively identified, with more than 100 compounds in incense powders and more than 200 compounds in the incense smoke, by using GC coupled to quadrupole mass spectrometric detection. Identification required at least 90% match with the NIST library; otherwise they were considered as unidentified. The smoke stream comprised compounds originating from the incense powder, and combustion products such as PAH, N-heterocyclics, and furans. However, GC×GC was able to separate many more volatile compounds (possibly hundreds more) present in the complex smoke samples, many of which cannot be separated by conventional 1D-GC; this is a direct consequence of the high-resolution power of GC×GC. GC×GC fingerprint comparison of powder H/S with smoke allows facile subtraction of the former from the latter to assist identification of compounds generated from burning incense.
Irie, Hiroshi; Todt, Clemens; Kumada, Norio; Harada, Yuichi; Sugiyama, Hiroki; Akazaki, Tatsushi; Muraki, Koji
2016-10-01
We study coherent transport and bound state formation of Bogoliubov quasiparticles in a high-mobility I n0.75G a0.25As two-dimensional electron gas (2DEG) coupled to a superconducting Nb electrode by means of a quantum point contact (QPC) as a tunable single-mode probe. Below the superconducting critical temperature of Nb, the QPC shows a single-channel conductance greater than the conductance quantum 2 e2/h at zero bias, which indicates the presence of Andreev-reflected quasiparticles, time-reversed states of the injected electron, returning back through the QPC. The marked sensitivity of the conductance enhancement to voltage bias and perpendicular magnetic field suggests a mechanism analogous to reflectionless tunneling—a hallmark of phase-coherent transport, with the boundary of the 2DEG cavity playing the role of scatterers. When the QPC transmission is reduced to the tunneling regime, the differential conductance vs bias voltage probes the single-particle density of states in the proximity area. Measured conductance spectra show a double peak within the superconducting gap of Nb, demonstrating the formation of Andreev bound states in the 2DEG. Both of these results, obtained in the open and closed geometries, underpin the coherent nature of quasiparticles, i.e., phase-coherent Andreev reflection at the InGaAs/Nb interface and coherent propagation in the ballistic 2DEG.
Kawarada, Hiroshi; Yamada, Tetsuya; Xu, Dechen; Tsuboi, Hidetoshi; Kitabayashi, Yuya; Matsumura, Daisuke; Shibata, Masanobu; Kudo, Takuya; Inaba, Masafumi; Hiraiwa, Atsushi
2017-02-01
Complementary power field effect transistors (FETs) based on wide bandgap materials not only provide high-voltage switching capability with the reduction of on-resistance and switching losses, but also enable a smart inverter system by the dramatic simplification of external circuits. However, p-channel power FETs with equivalent performance to those of n-channel FETs are not obtained in any wide bandgap material other than diamond. Here we show that a breakdown voltage of more than 1600 V has been obtained in a diamond metal-oxide-semiconductor (MOS) FET with a p-channel based on a two-dimensional hole gas (2DHG). Atomic layer deposited (ALD) Al2O3 induces the 2DHG ubiquitously on a hydrogen-terminated (C-H) diamond surface and also acts as both gate insulator and passivation layer. The high voltage performance is equivalent to that of state-of-the-art SiC planar n-channel FETs and AlGaN/GaN FETs. The drain current density in the on-state is also comparable to that of these two FETs with similar device size and VB.
Korytár, P; van Stee, L L P; Leonards, P E G; de Boer, J; Brinkman, U A Th
2003-04-25
Comprehensive two-dimensional gas chromatography (GC x GC) coupled with micro electron-capture and time-of-flight mass spectrometric (TOF-MS) detection has been used to analyse technical toxaphene. An HP-1 x HT-8 column combination yielded highly structured chromatograms and revealed a complex mixture of over 1000 compounds what is significantly higher number than in any study before. The analysis of a mixture of 23 individual congeners and TOF-MS evaluation of technical toxaphene showed that the chromatogram is structured according to the number of chlorine substituents in a molecule. The nature of the compounds (bornane and camphene) does not appear to have any influence. The sum of the peak areas of all congeners in each group was calculated using laboratory-written software; based on these results, the composition of technical toxaphene as a function of the number of chlorine substituents was provisionally calculated and was found that hepta- and octachlorinated compounds represents 75% of the total toxaphene area.
Screened test-charge - test-charge interaction in the two-dimensional electron gas: bound states
Gold, A.; Ghazali, A.
1997-08-01
We study the test-charge - test-charge interaction when screening effects of a two-dimensional electron gas are taken into account. The Schrödinger equation is solved in the momentum space by diagonalizing the corresponding matrix and the results are compared with variational calculations. For two positive (or negative) test-charges bound states are obtained for low electron densities when many-body effects are incorporated in the screening function. For a density larger than a critical density, 0953-8984/9/32/011/img5 (0953-8984/9/32/011/img6 is the Wigner - Seitz parameter), no bound states are found. Below the critical density, 0953-8984/9/32/011/img7, the number of bound states and their energy increase with decreasing density and the ground-state binding energy saturates near 0953-8984/9/32/011/img8. Finite-width effects for quantum wells are also discussed. We present new results for bound states between a positive and a negative test charge and we discuss effects of exchange and correlation on the binding energies.
Silva, Raquel V S; Tessarolo, Nathalia S; Pereira, Vinícius B; Ximenes, Vitor L; Mendes, Fábio L; de Almeida, Marlon B B; Azevedo, Débora A
2017-03-01
The elucidation of bio-oil composition is important to evaluate the processes of biomass conversion and its upgrading, and to suggest the proper use for each sample. Comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry (GC×GC-TOFMS) is a widely applied analytical approach for bio-oil investigation due to the higher separation and resolution capacity from this technique. This work addresses the issue of analytical performance to assess the comprehensive characterization of real bio-oil samples via GC×GC-TOFMS. The approach was applied to the individual quantification of compounds of real thermal (PWT), catalytic process (CPO), and hydrodeoxygenation process (HDO) bio-oils. Quantification was performed with reliability using the analytical curves of oxygenated and hydrocarbon standards as well as the deuterated internal standards. The limit of quantification was set at 1ngµL(-1) for major standards, except for hexanoic acid, which was set at 5ngµL(-1). The GC×GC-TOFMS method provided good precision (bio-oil samples. Sugars, furans, and alcohols appear as the major constituents of the PWT, CPO, and HDO samples, respectively. In order to obtain bio-oils with better quality, the catalytic pyrolysis process may be a better option than hydrogenation due to the effective reduction of oxygenated compound concentrations and the lower cost of the process, when hydrogen is not required to promote deoxygenation in the catalytic pyrolysis process.
Kawarada, Hiroshi; Yamada, Tetsuya; Xu, Dechen; Tsuboi, Hidetoshi; Kitabayashi, Yuya; Matsumura, Daisuke; Shibata, Masanobu; Kudo, Takuya; Inaba, Masafumi; Hiraiwa, Atsushi
2017-01-01
Complementary power field effect transistors (FETs) based on wide bandgap materials not only provide high-voltage switching capability with the reduction of on-resistance and switching losses, but also enable a smart inverter system by the dramatic simplification of external circuits. However, p-channel power FETs with equivalent performance to those of n-channel FETs are not obtained in any wide bandgap material other than diamond. Here we show that a breakdown voltage of more than 1600 V has been obtained in a diamond metal-oxide-semiconductor (MOS) FET with a p-channel based on a two-dimensional hole gas (2DHG). Atomic layer deposited (ALD) Al2O3 induces the 2DHG ubiquitously on a hydrogen-terminated (C-H) diamond surface and also acts as both gate insulator and passivation layer. The high voltage performance is equivalent to that of state-of-the-art SiC planar n-channel FETs and AlGaN/GaN FETs. The drain current density in the on-state is also comparable to that of these two FETs with similar device size and VB. PMID:28218234
Dutriez, Thomas; Courtiade, Marion; Thiébaut, Didier; Dulot, Hugues; Bertoncini, Fabrice; Vial, Jérôme; Hennion, Marie-Claire
2009-04-03
In a tense energetic context, the characterization of heavy petroleum fractions becomes essential. Conventional comprehensive two-dimensional gas chromatography (2D-GC or GCxGC) is widely used for middle distillates analysis, but only a few applications are devoted to these heavier fractions. In this paper, it is shown how the optimization of GCxGC separation allowed the determination of suitable high-temperature (HT) conditions, adjusting column properties and operating conditions. 2D separations were evaluated using 2D separation criteria and a new concept of 2D asymmetry (As(2D)). New HT conditions allowed the extension of GCxGC range of applications to heavier hydrocarbons, up to nC(60). A first application of high-temperature two-dimensional gas chromatography (HT-2D-GC) to a full vacuum gas oil (VGO) feed stock is described. Comparisons with other standardized methods illustrate the high potential of HT-2D-GC for heavy fractions analysis.
Lattice gas hydrodynamics: Theory and simulations
Energy Technology Data Exchange (ETDEWEB)
Hasslacher, B.
1993-01-01
The first successful application of a microscopic analogy to create a skeleton cellular automaton and analyze it with statistical mechanical tools, was the work of Frisch, Hasslacher and Pomeau on the Navier-Stokes equation in two and three dimensions. This has become a very large research area with lattice gas models and methods being used for both fundamental investigations into the foundations of statistical mechanics and a large number of diverse applications. This present research was devoted to enlarging the fundamental scope of lattice gas models and proved quite successful. Since the beginning of this proposal, cellular automata have been constructed for statistical mechanical models, fluids, diffusion and shock systems in fundamental investigations. In applied areas, there are now excellent lattice gas models for complex flows through porous media, chemical reaction and combustion dynamics, multiphase flow systems, and fluid mixtures with natural boundaries. With extended cellular fluid models, one can do problems with arbitrary pairwise potentials. Recently, these have been applied to such problems as non-newtonian or polymeric liquids and a mixture of immiscible fluids passing through fractal or spongelike media in two and three dimensions. This proposal has contributed to and enlarged the scope of this work.
Directory of Open Access Journals (Sweden)
Michael Phillips
Full Text Available BACKGROUND: Comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GCxGC-TOF MS has been proposed as a powerful new tool for multidimensional analysis of complex chemical mixtures. We investigated GCxGC-TOF MS as a new method for identifying volatile organic compounds (VOCs in normal human breath. METHODS: Samples of alveolar breath VOCs and ambient room air VOC were collected with a breath collection apparatus (BCA onto separate sorbent traps from 34 normal healthy volunteers (mean age = 40 yr, SD = 17 yr, male/female = 19/15. VOCs were separated on two serial capillary columns separated by a cryogenic modulator, and detected with TOF MS. The first and second dimension columns were non-polar and polar respectively. RESULTS: BCA collection combined with GC×GC-TOF MS analysis identified approximately 2000 different VOCs in samples of human breath, many of which have not been previously reported. The 50 VOCs with the highest alveolar gradients (abundance in breath minus abundance in ambient room air mostly comprised benzene derivatives, acetone, methylated derivatives of alkanes, and isoprene. CONCLUSIONS: Collection and analysis of breath VOCs with the BCA-GC×GC-TOF MS system extended the size of the detectable human volatile metabolome, the volatome, by an order of magnitude compared to previous reports employing one-dimensional GC-MS. The size of the human volatome has been under-estimated in the past due to coelution of VOCs in one-dimensional GC analytical systems.
Lee, Ching-Ping; Komiyama, Susumu; Chen, Jeng-Chung
2015-03-01
High mobility two-dimensional electron gas (2DEG) formed in the interface of a GaAs/AlGaAs hetero-structure in high magnetic field (B) exhibits interring nonlinear response either under microwave radiation or to a dc electric field (E). It is general believed that this kind nonlinear behavior is closely related to the occurrence of negative-differential conductance (NDC) in the presence of strong B and E. We observe a new type NDC state driven by a direct current above a threshold value (Ith) applied to a 2DEG as a function of B at relatively high temperatures (T). A current instability is observed in 2DEG system at high B ~6-8 T and at high T ~ 20- 30 K while the applied current is over Ith. The longitudinal voltage Vxx shows sub-linear behavior with the increase of I. As the current exceed Ith, Vxx suddenly drops a ΔVxx and becomes irregular associated with the appearance of hysteresis with sweeping I. We find that Ith increases with the increase of B and of T; meanwhile, ΔVxx is larger at higher B but lower T. Data analysis suggest that the onset of voltage fluctuation can be described by a NDC model proposed by Kurosawa et al. in 1976. The general behaviors of T and B dependence of current instability are analog to those recently reported at lower both T and B. This consistence suggests the same genuine mechanism of NDC phenomena observed in 2DEG system.
de Godoy, Luiz Antonio Fonseca; Hantao, Leandro Wang; Pedroso, Marcio Pozzobon; Poppi, Ronei Jesus; Augusto, Fabio
2011-08-05
The use of multivariate curve resolution (MCR) to build multivariate quantitative models using data obtained from comprehensive two-dimensional gas chromatography with flame ionization detection (GC×GC-FID) is presented and evaluated. The MCR algorithm presents some important features, such as second order advantage and the recovery of the instrumental response for each pure component after optimization by an alternating least squares (ALS) procedure. A model to quantify the essential oil of rosemary was built using a calibration set containing only known concentrations of the essential oil and cereal alcohol as solvent. A calibration curve correlating the concentration of the essential oil of rosemary and the instrumental response obtained from the MCR-ALS algorithm was obtained, and this calibration model was applied to predict the concentration of the oil in complex samples (mixtures of the essential oil, pineapple essence and commercial perfume). The values of the root mean square error of prediction (RMSEP) and of the root mean square error of the percentage deviation (RMSPD) obtained were 0.4% (v/v) and 7.2%, respectively. Additionally, a second model was built and used to evaluate the accuracy of the method. A model to quantify the essential oil of lemon grass was built and its concentration was predicted in the validation set and real perfume samples. The RMSEP and RMSPD obtained were 0.5% (v/v) and 6.9%, respectively, and the concentration of the essential oil of lemon grass in perfume agreed to the value informed by the manufacturer. The result indicates that the MCR algorithm is adequate to resolve the target chromatogram from the complex sample and to build multivariate models of GC×GC-FID data. Copyright © 2011 Elsevier B.V. All rights reserved.
Yang, Kesong
As a rapidly growing area of materials science, high-throughput (HT) computational materials design is playing a crucial role in accelerating the discovery and development of novel functional materials. In this presentation, I will first introduce the strategy of HT computational materials design, and take the HT discovery of topological insulators (TIs) as a practical example to show the usage of such an approach. Topological insulators are one of the most studied classes of novel materials because of their great potential for applications ranging from spintronics to quantum computers. Here I will show that, by defining a reliable and accessible descriptor, which represents the topological robustness or feasibility of the candidate, and by searching the quantum materials repository aflowlib.org, we have automatically discovered 28 TIs (some of them already known) in five different symmetry families. Next, I will talk about our recent research work on the HT computational design of the perovskite-based two-dimensional electron gas (2DEG) systems. The 2DEG formed on the perovskite oxide heterostructure (HS) has potential applications in next-generation nanoelectronic devices. In order to achieve practical implementation of the 2DEG in the device design, desired physical properties such as high charge carrier density and mobility are necessary. Here I show that, using the same strategy with the HT discovery of TIs, by introducing a series of combinatorial descriptors, we have successfully identified a series of candidate 2DEG systems based on the perovskite oxides. This work provides another exemplar of applying HT computational design approach for the discovery of advanced functional materials.
Wang, Min; Marriott, Philip J; Chan, Wing-Hong; Lee, Albert W M; Huie, Carmen W
2006-04-21
The separation of ephedrine-type alkaloids and their enantiomers in raw herbs and commercial herbal products was investigated by carrying out enantioselective separation in the first-dimension column (containing beta-cyclodextrin as the chiral selector) of a comprehensive two-dimensional gas chromatography (GC x GC) system, whereas a polar polyethylene glycol capillary column was used for separation in the second dimension. Naturally occurring ephedrine-type alkaloids and their synthetic analogues (enantiomeric counterparts) were adequately resolved from each other, as well as from potential interference species in the sample matrix using GC x GC, whereas single column GC analysis was unable to separate all the alkaloids of interest. Detection limits in the order of 0.1-1.3 microg/mL and linearity of calibration with R(2)>or=0.999 over approximately the range of 0.5-100 microg/mL for the quantitative determination of various ephedrine-type alkaloids were obtained. The commercial herbal products tested contained mostly (-)-ephedrine, (+)-pseudoephedrine, (-)-N-methylephedrine and (-)-norephedrine, with concentrations in the range of 40-2100, 0-1,300, 15-300 and 0-30 microg/g of the product, respectively, and repeatability of analysis was generally in the range of 1-5%. The present GCxGC method is effective and useful for the determination of the dosage levels of the principle ephedrine-type alkaloids in commercial health supplements and complex raw herb formulations, as well the differentiation of ephedrine-containing products that were derived from natural plant or synthetic sources, e.g., simply by visualizing the presence or absence of the enantiomeric pairs of (+/-) ephedrine and (+/-)-N-methylephedrine in the GC x GC chromatograms.
Wardlaw, G. D.; Reddy, C. M.; Nelson, R. K.; Valentine, D. L.
2008-12-01
In 2003 the National Research Council reported more than 380 million gallons of oil is emitted into the ocean each year from natural seepage and as a result of anthropogenic activities. Many of the hydrocarbons making up this oil are persistent and toxic to marine life. Petroleum emitted into biologically sensitive areas can lead to environmental stress and ecosystem collapse. As a result many studies and a substantial amount of resources have been devoted to creating efficient and effective remediation tools and developing a better understanding of natural hydrocarbon weathering processes occurring in marine environments. The goal of this study is to elucidate patterns and extent of aerobic hydrocarbon degradation in marine sediments. In order to assess the specific molecular transformations occurring in petroleum emitted into oxic marine environments, we prepared microcosm experiments using sediments and seawater collected from the natural oil seeps offshore Coal Oil Point, California. Petroleum recovered from Platform Holly in the Santa Barbara Channel, was added to a sediment-seawater mixture and the microcosm bottles were allowed to incubate under aerobic conditions for slightly more than 100 days. Comprehensive, two-dimensional gas chromatography was employed in this study to quantify changes in the concentrations of individual hydrocarbon compounds because of the increased resolution and resolving power provided with this robust analytical method. We show significant hydrocarbon mass loss due to aerobic biodegradation for hundreds of tracked compounds in the microcosm bottles. The results shown here provide quantitative evidence for broad-scale metabolic specificity during aerobic hydrocarbon degradation in surface and shallow subsurface marine sediments.
Energy Technology Data Exchange (ETDEWEB)
Hanu, A.R., E-mail: hanua@mcmaster.ca [Department of Medical Physics and Applied Radiation Sciences, McMaster University, Hamilton, Ontario, Canada L8S 4K1 (Canada); NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Prestwich, W.V.; Byun, S.H. [Department of Medical Physics and Applied Radiation Sciences, McMaster University, Hamilton, Ontario, Canada L8S 4K1 (Canada)
2015-04-21
We present a data acquisition (DAQ) system for two-dimensional position sensitive micropattern gas detectors using the delay-line method for readout. The DAQ system consists of a field programmable gate array (FPGA) as the main data processor and our time-to-digital (TDC) mezzanine card for making time measurements. We developed the TDC mezzanine card around the Acam TDC-GPX ASIC and it features four independent stop channels referenced to a common start, a typical timing resolution of ~81 ps, and a 17-bit measurement range, and is compliant with the VITA 57.1 standard. For our DAQ system, we have chosen the Xilinx SP601 development kit which features a single Spartan 6 FPGA, 128 MB of DDR2 memory, and a serial USB interface for communication. Output images consist of 1024×1024 square pixels, where each pixel has a 32-bit depth and corresponds to a time difference of 162 ps relative to its neighbours. When configured for a 250 ns acquisition window, the DAQ can resolve periodic event rates up to 1.8×10{sup 6} Hz without any loses and will report a maximum event rate of 6.11×10{sup 5} Hz for events whose arrival times follow Poisson statistics. The integral and differential non-linearities have also been measured and are better than 0.1% and 1.5%, respectively. Unlike commercial units, our DAQ system implements the delay-line image reconstruction algorithm entirely in hardware and is particularly attractive for its modularity, low cost, ease of integration, excellent linearity, and high throughput rate.
Griepink, F.C.; Drijfhout, F.P.; Beek, van T.A.; Visser, H.J.; Groot, de C.P.G.M.
2000-01-01
The amounts and ratios of the four constituents of the sex pheromone gland of the moth Symmetrischema tangolias were measured during a 24-hr dark–light cycle. A new approach was followed that involved the direct introduction of sex pheromone glands into the liner of a two-dimensional gas chromatogra
Weldegergis, B.T.; Villiers, de A.; McNeish, C.; Seethapathy, S.; Mostafa, A.; Górecki, T.; Crouch, A.M.
2011-01-01
As part of the ongoing research into the chemical composition of the uniquely South African wine cultivar Pinotage, the volatile composition of nine young wines of this cultivar was investigated using comprehensive two-dimensional gas chromatography (GC × GC) in combination with time-of-flight mass
Weldegergis, B.T.; Villiers, de A.; McNeish, C.; Seethapathy, S.; Mostafa, A.; Górecki, T.; Crouch, A.M.
2011-01-01
As part of the ongoing research into the chemical composition of the uniquely South African wine cultivar Pinotage, the volatile composition of nine young wines of this cultivar was investigated using comprehensive two-dimensional gas chromatography (GC × GC) in combination with time-of-flight mass
Institute of Scientific and Technical Information of China (English)
Zhai Zhi-Yuan; Li Yu-Qi; Pan Xiao-Yin
2012-01-01
We investigate the effects due to anisotropy and magnetic field interaction for a quasi-two-dimensional Boltzmann gas in an elliptical parabolic quantum dot.The specific heat is studied with varying temperature,anisotropy,and magnetic field strength.The cases without and with the inclusion of the spin Zeeman interaction are considered.
Bera, A. K.; Yusuf, S. M.; Kumar, Amit; Ritter, C.
2017-03-01
The crystal structure, magnetic ground state, and the temperature-dependent microscopic spin-spin correlations of the frustrated honeycomb lattice antiferromagnet N a2C o2Te O6 have been investigated by powder neutron diffraction. A long-range antiferromagnetic (AFM) ordering has been found below TN˜24.8 K . The magnetic ground state, determined to be zigzag antiferromagnetic and characterized by a propagation vector k =(1 /2 0 0 ) , occurs due to the competing exchange interactions up to third-nearest neighbors within the honeycomb lattice. The exceptional existence of a limited magnetic correlation length along the c axis (perpendicular to the honeycomb layers in the a b planes) has been found even at 1.8 K, well below the TN˜24.8 K . The observed limited correlation along the c axis is explained by the disorder distribution of the Na ions within the intermediate layers between honeycomb planes. The reduced ordered moments mCo (1 )=2.77 (3 ) μB/C o2 + and mCo (2 )=2.45 (2 ) μB/C o2 + at 1.8 K reflect the persistence of spin fluctuations in the ordered state. Above TN˜24.8 K , the presence of short-range magnetic correlations, manifested by broad diffuse magnetic peaks in the diffraction patterns, has been found. Reverse Monte Carlo analysis of the experimental diffuse magnetic scattering data reveals that the spin correlations are mainly confined within the two-dimensional honeycomb layers (a b plane) with a correlation length of ˜12 Å at 25 K. The nature of the spin arrangements is found to be similar in both the short-range and long-range ordered magnetic states. This implies that the short-range correlation grows with decreasing temperature and leads to the zigzag AFM ordering at T ≤TN . The present study provides a comprehensive picture of the magnetic correlations over the temperature range above and below the TN and their relation to the crystal structure. The role of intermediate soft Na layers on the magnetic coupling between honeycomb planes is
AlGaAs/GaAs two-dimensional electron gas structures studied by photo reflectance spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Guillen Cervantes, A; Rivera Alvarez, Z; Hernandez, F; Huerta, J. [Instituto Politecnico Nacional, Mexico, D.F. (Mexico); Mendez Garcia, V. H.; Lastras Martinez, A.; Zamora, L.; Saucedo, N. [Universidad Autonoma de San Luis Potosi, San Luis Potosi (Mexico); Melendez Lira, M; Lopez, M [Instituto Politecnico Nacional, Mexico, D.F. (Mexico)
2001-12-01
Al{sub x} Ga{sub 1}-x As/GaAs two-dimensional electron gas (2-DEG) heterostructures were fabricated by molecular beam epitaxy in three different laboratories. The samples were characterized by room temperature Photo reflectance (PR) spectroscopy and measurements at 77 K. Internal electric fields were detected by the presence of Franz-Keldysh (FK) oscillations in the PR spectra. >From a FK analysis we obtained the GaAs band-gap energy and the built-in electric field strength in each sample. On the other hand, in the energy region corresponding to Al{sub x} Ga{sub 1}-x As a broad PR signal was registered typical of a highly doped material. Using the third derivative theory we obtained the Al{sub x} Ga{sub 1}-x As band-gap energy, and from this value the Al concentration in the samples. Results showed that the sample with highest electron mobility exhibited the lowest internal electric field strength. [Spanish] Se fabricaron heteroestructuras del tipo Al{sub x} Ga{sub 1}-x As/GaAs con un gas de electrones en dos dimensiones por medio de epitaxia de haces moleculares en tres laboratorios diferentes. Las muestras se caracterizaron por fotorreflectancia (FR) a temperatura ambiente y por mediciones del efecto mayor a 77 K. Campos electricos internos se detectaron por la presencia de oscilaciones Franz-Leldysh (FK) en los espectros de FR. Del analisis de las oscilaciones FK obtuvimos la energia de la brecha prohibida del GaAs y la intensidad del campo electrico interno en cada muestra. Por otra parte, en la region de energia correspondiente al Al{sub x} Ga{sub 1}-x As observamos una senal de FR ancha, tipica de un material altamente impurificado. Usando la teoria de la tercera derivada, obtuvimos el valor de la brecha de energia del Al{sub x}Ga{sub 1}-xAs, y de este valor la concentracion de Al en las muestras. Los resultados mostraron que la estructura con el valor de movilidad electronica mas alto tiene la intensidad de campo electrico interno mas baja.
Institute of Scientific and Technical Information of China (English)
无
2010-01-01
The electrical properties of two-dimensional electron gas (2DEG) in AlGaN/GaN heterostructures using high temperature (HT) AlN interlayers (ITs) grown on c-plane sapphire substrate by metal organic chemical vapor deposition (MOCVD) have been investigated.It is found that the electrical properties (electron mobility and sheet carrier density) are improved compared with those in the conventional AlGaN/GaN heterostructures without HT AlN ITs,and the improved 2DEG properties result in the reduction of the sheet resistance.The results from high resolution X-ray diffraction (HRXRD) and Raman spectroscopy measurements show that HT AlN ITs increase the in-plane compressive strain in the upper GaN layer,which enhances the piezoelectric polarization in it and consequently causes increasing of 2DEG density at the AlGaN/GaN interface.Meanwhile,the compressive strain induced by HT AlN ITs leads to a less tensile strain in AlGaN barrier layer and causes positive and negative effects on the sheet carrier density of 2DEG,which counteract each other.The HT AlN ITs reduce the lattice mismatch between the GaN and AlGaN layers and smooth the interface between them,thus increasing the electric mobility of 2DEG by weakening the alloy-related interface roughness and scattering.In addition,the surface morphology of AlGaN/GaN heterostructures is improved by the insertion of HT AlN ITs.The reason for the improved properties is discussed in this paper.
The high density phase of the k-NN hard core lattice gas model
Nath, Trisha; Rajesh, R.
2016-07-01
The k-NN hard core lattice gas model on a square lattice, in which the first k next nearest neighbor sites of a particle are excluded from being occupied by another particle, is the lattice version of the hard disc model in two dimensional continuum. It has been conjectured that the lattice model, like its continuum counterpart, will show multiple entropy-driven transitions with increasing density if the high density phase has columnar or striped order. Here, we determine the nature of the phase at full packing for k up to 820 302 . We show that there are only eighteen values of k, all less than k = 4134, that show columnar order, while the others show solid-like sublattice order.
Energy Technology Data Exchange (ETDEWEB)
Liu, Xiangping; Li, Dengkun; Li, Jiequan [Nanjing Centre for Disease Control and Prevention, Zizhulin Street, Gulou 210003, Nanjing (China); Rose, Gavin [Department of Environment and Primary Industries, Macleod Centre, Ernest Jones Drive, Macleod, Vic 3085 (Australia); Marriott, Philip J., E-mail: philip.marriott@monash.edu [Australian Centre for Research on Separation Science, School of Chemistry, Monash University, Wellington Road, Clayton 3800 (Australia)
2013-12-15
Highlights: • GC × GC-FPD(P-mode) was applied to detection of 37 phosphorus (P)-containing compounds. • The method improves resolution of P-compounds that coelute in the first dimension. • P-compounds are analyzed with excellent sensitivity supported by cryogenic modulation. • The FPD(P-mode) selectivity allows analysis in high hydrocarbon (H/C) matrix. • Soil samples and spiked chemical weapon compounds in H/C matrix are readily screened. -- Abstract: Thirty-seven phosphorus (P)-containing compounds comprising organophosphorus pesticides and organophosphate esters were analyzed by using comprehensive two-dimensional gas chromatography with flame photometric detection in P mode (GC × GC-FPD(P)), with a non-polar/moderately polar column set. A suitable modulation temperature and period was chosen based on experimental observation. A number of co-eluting peak pairs on the {sup 1}D column were well separated in 2D space. Excellent FPD(P) detection selectivity, responding to compounds containing the P atom, produces clear 2D GC × GC plots with little interference from complex hydrocarbon matrices. Limits of detection (LOD) were within the range of 0.0021–0.048 μmol L{sup −1}, and linear calibration correlation coefficients (R{sup 2}) for all 37 P-compounds were at least 0.998. The P-compounds were spiked in 2% diesel and good reproducibility for their response areas and retention times was obtained. Spiked recoveries were 88%–157% for 5 μg L{sup −1} and 80%–138% for 10 μg L{sup −1} spiked levels. Both {sup 1}t{sub R} and {sup 2}t{sub R} shifts were noted when the content of diesel was in excess of 5% in the matrix. Soil samples were analyzed by using the developed method; some P-compounds were positively detected. In general, this study shows that GC × GC-FPD(P) is an accurate, sensitive and simple method for P-compound analysis in complicated environmental samples.
Vendeuvre, Colombe; Bertoncini, Fabrice; Espinat, Didier; Thiébaut, Didier; Hennion, Marie-Claire
2005-10-07
A multidimensional method providing the composition of a heavy naphtha in paraffins, isoparaffins, olefins, naphthenes, and aromatics (PIONA) in the C8-C14 range is presented. The analytical set-up consists in a silver modified silica olefin trap on-line coupled to comprehensive two-dimensional gas chromatography (GC x GC). In this configuration, hydrocarbons are separated, in gaseous state, in two fractions, saturate and unsaturate, each fraction being subsequently analysed by GC or by GC x GC. The resolution between saturates and olefins was found to be improved compared to a single GC x GC run. The characterisation of the olefin trap highlights the benefits and the limits related to the use of that stationary phase as a double bond selective fractionation medium.
Lattice-Gas Automata for the Problem Of Kinetic Theory of Gas During Free Expansion
Khotimah, Siti Nurul; Arif, Idam; Liong, The Houw
The lattice-gas method has been applied to solve the problem of kinetic theory of gas in the Gay-Lussac-Joule experiment. Numerical experiments for a two-dimensional gas were carried out to determine the number of molecules in one vessel (Nr), the ratio between the mean square values of the components of molecule velocity (/line{vx2}//line{v_y^2}), and the change in internal energy (ΔU) as a function of time during free expansion. These experiments were repeated for different sizes of an aperture in the partition between the two vessels. After puncturing the partition, the curve for the particle number in one vessel shows a damped oscillation for about half of the total number. The oscillations do not vanish after a sampling over different initial configurations. The system is in nonequilibrium due to the pressure equilibration, and here the flow is actually compressible. The equilibration time (in time steps) decreases with decreased size of aperture in the partition. For very small apertures (equal or less than 9{√{3}}/{2} lattice units), the number of molecules in one vessel changes with time in a smooth way until it reaches half of the total number; their curves obey the analytical solution for quasi-static processes. The calculations on /line{vx2}//line{v_y^2} and ΔU also support the results that the equilibration time decreases with decreased size of aperture in the partition.
Gruber, Beate; Groeger, Thomas; Harrison, Dale; Zimmermann, Ralf
2016-09-16
Vacuum ultraviolet (VUV) absorption spectroscopy was recently introduced as a new detection system for one, as well as comprehensive two-dimensional gas chromatography (GC×GC) and successfully applied to the analysis of various analytes in several matrices. In this study, its suitability for the analysis of breath metabolites was investigated and the impact of a finite volume of the absorption cell and makeup gas pressure was evaluated for volatile analytes in terms of sensitivity and chromatographic resolution. A commercial available VUV absorption spectrometer was coupled to GC×GC and applied to the analysis of highly polar volatile organic compounds (VOCs). Breath gas samples were acquired by needle trap micro extraction (NTME) during a glucose challenge and analysed by the applied technique. Regarding qualitative and quantitative information, the VGA-100 is compatible with common GC×GC detection systems like FID and even TOFMS. Average peak widths of 300ms and LODs in the lower ng range were achieved using GC×GC-VUV. Especially small oxygenated breath metabolites show intense and characteristic absorption patterns in the VUV region. Challenge responsive VOCs could be identified and monitored during a glucose challenge. The new VUV detection technology might especially be of benefit for applications in clinical research.
Zhang, Wanfeng; Zhu, Shukui; Pang, Liling; Gao, Xuanbo; Zhu, Gang-Tian; Li, Donghao
2016-12-23
Based on a homemade device, gas purge microsyringe extraction (GP-MSE) of crude oil samples was developed for the first time. As a simple, fast, low-cost, sensitive and solvent-saving technique, GP-MSE provides some outstanding advantages over the widely used sample preparation methods for crude oils such as column chromatography (ASTM D2549). Several parameters affecting extraction efficiency were optimized, including extraction temperature, extraction time, extraction solvent, condensing temperature and purge gas flow rate. With the optimized GP-MSE conditions, several real crude oil samples were extracted, and trace diamondoids were determined using comprehensive two dimensional gas chromatography-time-of-flight mass spectrometry (GC×GC-TOFMS). In total, more than 100 diamondoids were detected and 27 marker compounds were identified and quantified accurately. The limits of detection (LODs, S/N=3) were less than 0.08μg/L for all diamondoids. The relative standard deviation (RSD) was below 8%, ranging from 1.1 to 7.6%. The linearity of the developed method was in the range of 0.5-100.0μg/L with correlation coefficients (R(2)) more than 0.996. The recoveries obtained at spiking 50μg/L were between 81 and 108% for diamondoids in crude oil samples. The developed method can also be extended to the analysis of other components in crude oils and other complex matrices.
Energy Technology Data Exchange (ETDEWEB)
Vostokov, N. V., E-mail: vostokov@ipm.sci-nnov.ru; Shashkin, V. I. [Institute for Physics of Microstructures of the Russian Academy of Sciences, 603950 Nizhny Novgorod, Russia and N. I. Lobachevsky State University of Nizhny Novgorod, 603950 Nizhny Novgorod (Russian Federation)
2015-11-28
We consider the problem of non-resonant detection of terahertz signals in a short gate length field-effect transistor having a two-dimensional electron channel with zero external bias between the source and the drain. The channel resistance, gate-channel capacitance, and quadratic nonlinearity parameter of the transistor during detection as a function of the gate bias voltage are studied. Characteristics of detection of the transistor connected in an antenna with real impedance are analyzed. The consideration is based on both a simple one-dimensional model of the transistor and allowance for the two-dimensional distribution of the electric field in the transistor structure. The results given by the different models are discussed.
Tseng, M. Z.; Jiang, W. N.; Hu, E. L.
1994-09-01
A direct integration of YBa2Cu3O(7 - x) and a two dimensional electron gas Hall probe was made possible through the use of a MgO buffer layer. We demonstrate the use of this structure for the measurements of the magnetization hysteresis of a superconducting YBa2Cu3O(7 - x) thin film, and we make an estimate of the sensitivity and resolution that can be achieved with this probe structure. The close proximity of the YBa2Cu3O(7 - x) to the two dimensional electron gas (approximately 1700 A) allows sensitive measurements of interactions between the two; more importantly, closer superconductor-semiconductor spacing can be achieved without severe compromise of the component material quality.
Energy Technology Data Exchange (ETDEWEB)
Tran, T.C.; Harynuk, J.; Marriott, P. [RMIT University, Melbourne (Australia). Dept. of Applied Chemistry; Logan, G.A.; Grosjean, E. [Geoscience Australia, Canberra (Australia); Ryan, D. [Charles Sturt University, Wagga Wagga (Australia). School of Science and Technology
2006-09-15
An inverted phase (polar to non-polar) column set has been compared with a non-polar to polar column set for the GC x GC separation of petroleum hydrocarbons. This column configuration is shown to provide greatly enhanced resolution for less polar compounds and makes greater use of the two dimensional separation space. It improves resolution of a greater number of components within one analysis and offers new possibilities for crude oil fingerprinting. (Author)
Tong, Ting; Zhang, Wanfeng; Li, Donghao; Zhao, Jinhua; Chang, Zhenyang; Gao, Xuanbo; Dai, Wei; He, Sheng; Zhu, Shukui
2014-10-01
A novel sample pretreatment method, gas purge micro-syringe extraction (GP- MSE), coupled to comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry (GC x GC/TOFMS) has been developed for the characterization of volatile and semi-volatile compounds in crude oils. In the sample pretreatment process, the analytes were carried to the microsyringe barrel by inert gas, and at the same time, trapped by an organic solvent. The whole process of extraction takes less than 10 min, and only 20 μL of organic solvent was needed. Using two custom standard solutions containing alkanes and polycyclic aromatic hydrocarbons (PAHs), the influences of the extraction conditions were investigated. The optimized conditions were as follows: 5 mg crude oil, 20 μL hexane (extraction solvent), extraction for 3 min at 300 °C, condensation temperature set at -2 °C, gas flow rate set at 2 mL/min. Under the optimized conditions, a real crude oil sample was extracted and then analyzed in detail. It showed that the proposed method was very effective in simultaneously analyzing the normal and branched alkanes, cycloalkanes, aromatic hydrocarbons, and biomarkers of crude oil such as steranes and terpanes. The recoveries obtained ranged from 82.0% to 107.3% and the detection limits ranged from 34 to 93 μg/L. The correlation coefficients (R2) were more than 0.99. The relative standard deviations (RSDs, n = 5) for all the analytes were below 10%. The results indicate that the proposed method is suitable for the characterization of volatile and semi-volatile compounds in crude oils with easy operation, high sensitivity and efficiency.
Zhou, Zhilei; Liu, Shuangping; Kong, Xiangwei; Ji, Zhongwei; Han, Xiao; Wu, Jianfeng; Mao, Jian
2017-03-03
In this work, a method to characterize the aroma compounds of Zhenjiang aromatic vinegar (ZAV) was developed using comprehensive two dimensional gas chromatography (GC×GC) coupled with time-of-flight mass spectrometry (TOFMS) and gas chromatography olfactometry (GC-O). The column combination was optimized and good separation was achieved. Structured chromatograms of furans and pyrazines were obtained and discussed. A total of 360 compounds were tentatively identified based on mass spectrum match factors, structured chromatogram and linear retention indices comparison. The most abundant class in number was ketones. A large number of esters, furans and derivatives, aldehydes and alcohols were also detected. The odor-active components were identified by comparison of the reported odor of the identified compounds with the odor of corresponding GC-O region. The odorants of methanethiol, 2-methyl-propanal, 2-methyl-butanal/3-methyl-butanal, octanal, 1-octen-3-one, dimethyl trisulfide, trimethyl-pyrazine, acetic acid, 3-(methylthio)-propanal, furfural, benzeneacetaldehyde, 3-methyl-butanoic acid/2-methyl-butanoic acid and phenethyl acetate were suspected to be the most potent. About half of them were identified as significant aroma constituents in ZAV for the first time. Their contribution to specific sensory attribute of ZAJ was also studied. The results indicated that the presented method is suitable for characterization of ZAV aroma constituents. This study also enriches our knowledge on the components and aroma of ZAV.
Avila, Bárbara M F; Pereira, Ricardo; Gomes, Alexandre O; Azevedo, Débora A
2011-05-27
Comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC×GC-TOFMS) was used for the characterization of aromatic compounds present in extra heavy gas oil (EHGO) from Brazil. Individual identification of EHGO compounds was successfully achieved in addition to group-type separation on the chromatographic plane. Many aromatic hydrocarbons, especially polycyclic aromatic hydrocarbons and sulfur compounds, were detected and identified, such as chrysenes, phenanthrenes, perylenes, benzonaphthothiophenes and alkylbenzonaphthothiophenes. In addition, triaromatic steroids, methyl-triaromatic steroids, tetrahydrochrysenes and tetraromatic pentacyclic compounds were present in the EHGO aromatic fractions. Considering the roof-tile effect observed for many of these compound classes and the high number of individual compounds identified, GC×GC-TOFMS is an excellent technique to characterize the molecular composition of the aromatic fraction from EHGO samples. Moreover, data processing allowed the quantification of aromatic compounds, in class and individually, using external standards. EHGO data were obtained in μgg(-1), e.g., benzo[a]pyrene were in the range 351 to 1164μgg(-1). Thus, GC×GC-TOFMS was successfully applied in EHGO quantitative analysis.
Franchina, Flavio Antonio; Machado, Maria Elisabete; Tranchida, Peter Quinto; Zini, Cláudia Alcaraz; Caramão, Elina Bastos; Mondello, Luigi
2015-03-27
The present research is focused on the development of a flow-modulated comprehensive two-dimensional gas chromatography-triple quadrupole mass spectrometry (FM GC × GC-MS/MS) method for the determination of classes of aromatic organic sulphur compounds (benzothiophenes, dibenzothiophenes, and benzonaphthothiophene) in heavy gas oil (HGO). The MS/MS instrument was used to provide both full-scan and multiple-reaction-monitoring (MRM) data. Linear retention index (LRI) ranges were used to define the MRM windows for each chemical class. Calibration solutions (internal standard: 1-fluoronaphthalene) were prepared by using an HGO sample, depleted of S compounds. Calibration information was also derived for the thiophene class (along with MRM and LRI data), even though such constituents were not present in the HGO. Linearity was satisfactory over the analyzed concentration range (1-100 mg/L); intra-day precision for the lowest calibration point was always below 17%. Accuracy was also satisfactory, with a maximum percentage error of 3.5% (absolute value) found among the S classes subjected to (semi-)quantification. The highest limit of quantification was calculated to be 299 μg/L (for the C1-benzothiophene class), while the lowest was 21 μg/L (for the C4-benzothiophene class).
McGregor, Laura A; Gauchotte-Lindsay, Caroline; Daéid, Niamh Nic; Thomas, Russell; Daly, Paddy; Kalin, Robert M
2011-07-22
Ultra resolution chemical fingerprinting of dense non-aqueous phase liquids (DNAPLs) from former manufactured gas plants (FMGPs) was investigated using comprehensive two-dimensional gas chromatography coupled with time of flight mass spectrometry (GC×GC TOFMS). Reversed phase GC×GC (i.e. a polar primary column coupled to a non-polar secondary column) was found to significantly improve the separation of polycyclic aromatic hydrocarbons (PAHs) and their alkylated homologues. Sample extraction and cleanup was performed simultaneously using accelerated solvent extraction (ASE), with recovery rates between 76% and 97%, allowing fast, efficient extraction with minimal solvent consumption. Principal component analysis (PCA) of the GC×GC data was performed in an attempt to differentiate between twelve DNAPLs based on their chemical composition. Correlations were discovered between DNAPL composition and historic manufacturing processes used at different FMGP sites. Traditional chemical fingerprinting methods generally follow a tiered approach with sample analysis on several different instruments. We propose ultra resolution chemical fingerprinting as a fast, accurate and precise method of obtaining more chemical information than traditional tiered approaches while using only a single analytical technique.
DEFF Research Database (Denmark)
Nielsen, Morten; Miao, Ling; Ipsen, John Hjorth;
1996-01-01
In this work we concentrate on phase equilibria in two-dimensional condensed systems of particles where both translational and internal degrees of freedom are present and coupled through microscopic interactions, with a focus on the manner of the macroscopic coupling between the two types...
Strongly interacting two-dimensional Dirac fermions
Lim, L.K.; Lazarides, A.; Hemmerich, Andreas; de Morais Smith, C.
2009-01-01
We show how strongly interacting two-dimensional Dirac fermions can be realized with ultracold atoms in a two-dimensional optical square lattice with an experimentally realistic, inherent gauge field, which breaks time reversal and inversion symmetries. We find remarkable phenomena in a temperature
Schöche, S.; Shi, Junxia; Boosalis, A.; Kühne, P.; Herzinger, C. M.; Woollam, J. A.; Schaff, W. J.; Eastman, L. F.; Schubert, M.; Hofmann, T.
2011-02-01
The free-charge carrier mobility, sheet density, and effective mass of a two-dimensional electron gas are exemplarily determined in the spectral range from 640 GHz to 1 THz in a AlGaN/GaN heterostructure using the optical-Hall effect at room temperature. Complementary midinfrared spectroscopic ellipsometry measurements are performed for analysis of heterostructure constituents layer thickness, phonon mode, and free-charge carrier parameters. The electron effective mass is determined to be (0.22±0.04)m0. The high-frequency sheet density and carrier mobility parameters are in good agreement with results from dc electrical Hall effect measurements, indicative for frequency-independent carrier scattering mechanisms of the two-dimensional carrier distribution.
Desbuquois, Rémi; Yefsah, Tarik; Chomaz, Lauriane; Weitenberg, Christof; Corman, Laura; Nascimbène, Sylvain; Dalibard, Jean
2014-07-11
We present a general "fit-free" method for measuring the equation of state (EoS) of a scale-invariant gas. This method, which is inspired from the procedure introduced by Ku et al. [Science 335, 563 (2012)] for the unitary three-dimensional Fermi gas, provides a general formalism which can be readily applied to any quantum gas in a known trapping potential, in the frame of the local density approximation. We implement this method on a weakly interacting two-dimensional Bose gas across the Berezinskii-Kosterlitz-Thouless transition and determine its EoS with unprecedented accuracy in the critical region. Our measurements provide an important experimental benchmark for classical-field approaches which are believed to accurately describe quantum systems in the weakly interacting but nonperturbative regime.
Density-functional theory of a lattice-gas model with vapour, liquid, and solid phases
Prestipino, S.; Giaquinta, P. V.
2003-01-01
We use the classical version of the density-functional theory in the weighted-density approximation to build up the entire phase diagram and the interface structure of a two-dimensional lattice-gas model which is known, from previous studies, to possess three stable phases -- solid, liquid, and vapour. Following the common practice, the attractive part of the potential is treated in a mean-field-like fashion, although with different prescriptions for the solid and the fluid phases. It turns o...
A high-mobility two-dimensional electron gas at the spinel/perovskite interface of γ-Al2O3/SrTiO3
DEFF Research Database (Denmark)
Chen, Yunzhong; Bovet, N.; Trier, Felix
2013-01-01
The discovery of two-dimensional electron gases at the heterointerface between two insulating perovskite-type oxides, such as LaAlO3 and SrTiO3, provides opportunities for a new generation of all-oxide electronic devices. Key challenges remain for achieving interfacial electron mobilities much be...... confined within a layer of 0.9 nm in proximity to the interface. Our findings pave the way for studies of mesoscopic physics with complex oxides and design of high-mobility all-oxide electronic devices.......The discovery of two-dimensional electron gases at the heterointerface between two insulating perovskite-type oxides, such as LaAlO3 and SrTiO3, provides opportunities for a new generation of all-oxide electronic devices. Key challenges remain for achieving interfacial electron mobilities much...... beyond the current value of approximately 1,000 cm2V-1 s-1 (at low temperatures). Here we create a new type of two-dimensional electron gas at the heterointerface between SrTiO3 and a spinel g-Al2O3 epitaxial film with compatible oxygen ions sublattices. Electron mobilities more than one order...
Kapp, Thomas; Vetter, Walter
2009-11-20
High-speed counter-current chromatography (HSCCC), a separation technique based solely on the partitioning of solutes between two immiscible liquid phases, was applied for the fractionation of technical toxaphene, an organochlorine pesticide which consists of a complex mixture of structurally closely related compounds. A solvent system (n-hexane/methanol/water 34:24:1, v/v/v) was developed which allowed to separate compounds of technical toxaphene (CTTs) with excellent retention of the stationary phase (S(f) = 88%). Subsequent analysis of all HSCCC fractions by gas chromatography coupled to electron-capture negative ion mass spectrometry (GC/ECNI-MS) provided a wealth of information regarding separation characteristics of HSCCC and the composition of technical toxaphene. The visualization of the large amount of data obtained from the offline two-dimensional HSCCC-GC/ECNI-MS experiment was facilitated by the creation of a two-dimensional (2D) contour plot. The contour plot not only provided an excellent overview of the HSCCC separation progress, it also illustrated the differences in selectivity between HSCCC and GC. The results of this proof-of-concept study showed that the 2D chromatographic approach involving HSCCC facilitated the separation of CTTs that coelute in unidimensional GC. Furthermore, the creation of 2D contour plots may provide a useful means of enhancing data visualization for other offline two-dimensional separations.
Ostrovskaya, G. V.; Frank, A. G.
2012-04-01
An analysis of the experimental data obtained by holographic interferometry in our work [1] makes it possible to explain most of the observed specific features of the structure and evolution of the plasma sheets developing in a two-dimensional magnetic field with a null line in a plasma with a low initial degree of ionization (≈10-4). The following two processes are shown to play a key role here: additional gas ionization in an electric field and the peculiarities of plasma dynamics in a current sheet expanding in time.
Schreiber, K. A.; Samkharadze, N.; Gardner, G. C.; Biswas, Rudro R.; Manfra, M. J.; Csáthy, G. A.
2017-07-01
Under hydrostatic pressure, the ground state of a two-dimensional electron gas at ν =5 /2 changes from a fractional quantum Hall state to the stripe phase. By measuring the energy gap of the fractional quantum Hall state and of the onset temperature of the stripe phase, we mapped out a phase diagram of these competing phases in the pressure-temperature plane. Our data highlight the dichotomy of two descriptions of the half-filled Landau level near the quantum critical point: one based on electrons and another on composite fermions.
Biswas, Tutul; Ghosh, Tarun Kanti
2013-01-23
We study the interaction between electron and acoustic phonons in a Rashba spin-orbit coupled two-dimensional electron gas using Boltzmann transport theory. Both the deformation potential and piezoelectric scattering mechanisms are considered in the Bloch-Grüneisen (BG) regime as well as in the equipartition (EP) regime. The effect of the Rashba spin-orbit interaction on the temperature dependence of the resistivity in the BG and EP regimes is discussed. We find that the effective exponent of the temperature dependence of the resistivity in the BG regime decreases due to spin-orbit coupling.
Krupčík, Ján; Gorovenko, Roman; Špánik, Ivan; Sandra, Pat; Armstrong, Daniel W
2015-10-01
The analysis of Bulgarian and Turkish Rosa damascena Miller essential oils was performed by flow-modulated comprehensive two-dimensional gas chromatography using simultaneous detection of the second column effluent by flame ionization and quadrupole mass spectrometric detection. Enantioselective separations were obtained by running the samples on 2,3-di-O-ethyl-6-O-tert-butyldimethylsilyl-β-cyclodextrin column as the first column and on polyethylene glycol as the second column. The determination of enantiomeric or diastereomeric excess of some terpenoic solutes is a possible route for quality or authenticity control as well as for the elucidation of the country of origin.
Suppression of the two-dimensional electron gas in LaGaO3/SrTiO3 by cation intermixing
Nazir, S.
2013-12-03
Cation intermixing at the n-type polar LaGaO 3 /SrTiO 3 (001) interface is investigated by first principles calculations. Ti"Ga, Sr"La, and SrTi"LaGa intermixing are studied in comparison to each other, with a focus on the interface stability. We demonstrate in which cases intermixing is energetically favorable as compared to a clean interface. A depopulation of the Ti 3d xy orbitals under cation intermixing is found, reflecting a complete suppression of the two-dimensional electron gas present at the clean interface.
Giant spin splitting of the two-dimensional electron gas at the surface of SrTiO3
Santander-Syro, A. F.; Fortuna, F.; Bareille, C.; Rödel, T. C.; Landolt, G.; Plumb, N. C.; Dil, J. H.; Radović, M.
2014-12-01
Two-dimensional electron gases (2DEGs) forming at the interfaces of transition metal oxides exhibit a range of properties, including tunable insulator-superconductor-metal transitions, large magnetoresistance, coexisting ferromagnetism and superconductivity, and a spin splitting of a few meV (refs , ). Strontium titanate (SrTiO3), the cornerstone of such oxide-based electronics, is a transparent, non-magnetic, wide-bandgap insulator in the bulk, and has recently been found to host a surface 2DEG (refs , , , ). The most strongly confined carriers within this 2DEG comprise two subbands, separated by an energy gap of 90 meV and forming concentric circular Fermi surfaces. Using spin- and angle-resolved photoemission spectroscopy (SARPES), we show that the electron spins in these subbands have opposite chiralities. Although the Rashba effect might be expected to give rise to such spin textures, the giant splitting of almost 100 meV at the Fermi level is far larger than anticipated. Moreover, in contrast to a simple Rashba system, the spin-polarized subbands are non-degenerate at the Brillouin zone centre. This degeneracy can be lifted by time-reversal symmetry breaking, implying the possible existence of magnetic order. These results show that confined electronic states at oxide surfaces can be endowed with novel, non-trivial properties that are both theoretically challenging to anticipate and promising for technological applications.
Su, Ying; Wang, C.; Avishai, Y.; Meir, Yigal; Wang, X. R.
2016-09-01
The one-parameter scaling theory of localization predicts that all states in a disordered two-dimensional system with broken time reversal symmetry are localized even in the presence of strong spin-orbit coupling. While at constant strong magnetic fields this paradigm fails (recall the quantum Hall effect), it is believed to hold at weak magnetic fields. Here we explore the nature of quantum states at weak magnetic field and strongly fluctuating spin-orbit coupling, employing highly accurate numerical procedure based on level spacing distribution and transfer matrix technique combined with one parameter finite-size scaling hypothesis. Remarkably, the metallic phase, (known to exist at zero magnetic field), persists also at finite (albeit weak) magnetic fields, and eventually crosses over into a critical phase, which has already been confirmed at high magnetic fields. A schematic phase diagram drawn in the energy-magnetic field plane elucidates the occurrence of localized, metallic and critical phases. In addition, it is shown that nearest-level statistics is determined solely by the symmetry parameter β and follows the Wigner surmise irrespective of whether states are metallic or critical.
Conductivity of the two-dimensional electron gas at LaAlO3/SrTiO3 interface
Kirichenko, E. V.; Stephanovich, V. A.; Dugaev, V. K.
2017-02-01
We propose an analytical theory of metallic conductivity in the two-dimensional (2D) LaAlO3/SrTiO3 (LAO/STO) interface. For that we consider the electron-phonon interaction at the interface. The electronic part is taken from our previous work [Phys. Chem. Chem. Phys. 18, 2104 (2016), 10.1039/C5CP06627A], considering the conditions for the interfacial charge carrier (electron or hole) to become itinerant. The second ingredient deals with the atomic oscillations localized near the interface and decaying rapidly at its both sides, which can be regarded as 2D acoustic phonons. The dispersion of such phonons depends on the characteristics of phonon spectra of LAO and STO. Calculating the corresponding scattering rate by Fermi's golden rule, we show that the resulting resistivity (i.e., inverse conductivity) has typical metallic character, growing linearly with temperature and tending to zero (without defects forming so-called residual resistivity) at T →0 . The results of our calculations are in agreement with available experimental data.
Critical-like behavior in a lattice gas model
Wieloch, A; Lukasik, J; Pawlowski, P; Pietrzak, T; Trautmann, W
2010-01-01
ALADIN multifragmentation data show features characteristic of a critical behavior, which are very well reproduced by a bond percolation model. This suggests, in the context of the lattice gas model, that fragments are formed at nearly normal nuclear densities and temperatures corresponding to the Kertesz line. Calculations performed with a lattice gas model have shown that similarly good reproduction of the data can also be achieved at lower densities, particularly in the liquid-gas coexistence region.
Wong, Yong Foo; Uekane, Thais M; Rezende, Claudia M; Bizzo, Humberto R; Marriott, Philip J
2016-12-16
Improved separation of both sesquiterpenes and diterpenic acids in Copaifera multijuga Hayne oleoresin, is demonstrated by using comprehensive two-dimensional gas chromatography (GC×GC) coupled to accurate mass time-of-flight mass spectrometry (accTOFMS). GC×GC separation employs polar phases (including ionic liquid phases) as the first dimension ((1)D) column, combined with a lower polarity (2)D phase. Elution temperatures (Te) of diterpenic acids (in methyl ester form, DAME) increased as the (1)D McReynolds' polarity value of the column phase decreased. Since Te of sesquiterpene hydrocarbons decreased with increased polarity, the very polar SLB-IL111 (1)D phase leads to excessive peak broadening in the (2)D apolar phase due to increased second dimension retention ((2)tR). The combination of SLB-IL59 with a nonpolar column phase was selected, providing reasonable separation and low Te for sesquiterpenes and DAME, compared to other tested column sets, without excessive (2)tR. Identities of DAME were aided by both soft (30eV) electron ionisation (EI) accurate mass TOFMS analysis and supersonic molecular beam ionisation (cold EI) TOFMS, both which providing less fragmentation and increased relative abundance of molecular ions. The inter-relation between EI energies, emission current, signal-to-noise and mass error for the accurate mass measurement of DAME are reported. These approaches can be used as a basis for conducting of GC×GC with soft EI accurate mass measurement of terpenes, particularly for unknown phytochemicals.
Toraman, Hilal E; Dijkmans, Thomas; Djokic, Marko R; Van Geem, Kevin M; Marin, Guy B
2014-09-12
The detailed compositional characterization of plastic waste pyrolysis oil was performed with comprehensive two-dimensional GC (GC×GC) coupled to four different detectors: a flame ionization detector (FID), a sulfur chemiluminescence detector (SCD), a nitrogen chemiluminescence detector (NCD) and a time of flight mass spectrometer (TOF-MS). The performances of different column combinations were assessed in normal i.e. apolar/mid-polar and reversed configurations for the GC×GC-NCD and GC×GC-SCD analyses. The information obtained from the four detectors and the use of internal standards, i.e. 3-chlorothiophene for the FID and the SCD and 2-chloropyridine for the NCD analysis, enabled the identification and quantification of the pyrolysis oil in terms of both group type and carbon number: hydrocarbon groups (n-paraffins, iso-paraffins, olefins and naphthenes, monoaromatics, naphthenoaromatics, diaromatics, naphthenodiaromatics, triaromatics, naphthenotriaromatics and tetra-aromatics), nitrogen (nitriles, pyridines, quinolines, indole, caprolactam, etc.), sulfur (thiols/sulfides, thiophenes/disulfides, benzothiophenes, dibenzothiophenes, etc.) and oxygen containing compounds (ketones, phenols, aldehydes, ethers, etc.). Quantification of trace impurities is illustrated for indole and caprolactam. The analyzed pyrolysis oil included a significant amount of nitrogen containing compounds (6.4wt%) and to a lesser extent sulfur containing compounds (0.6wt%). These nitrogen and sulfur containing compounds described approximately 80% of the total peak volume for respectively the NCD and SCD analysis. TOF-MS indicated the presence of the oxygen containing compounds. However only a part of the oxygen containing compounds (2.5wt%) was identified because of their low concentrations and possible overlap with the complex hydrocarbon matrix as no selective detector or preparative separation for oxygen compounds was used.
Kinetics of diffuesion-controlled oxygen ordering in a lattic-gas model of YBa2Cu3O7-δ
DEFF Research Database (Denmark)
Andersen, Jørgen Vitting; Bohr, Henrik; Mouritsen, Ole G.
1990-01-01
Nonequilibrium properties of oxygen ordering in high-Tc superconductors of the Y-Ba-Cu-O type are studied via computer simulation of an anisotropic two-dimensional lattice-gas model in which the ordering processes are controlled by diffusion across the sample edges. With a view to designing optimal...
Energy Technology Data Exchange (ETDEWEB)
Rubin, P., E-mail: rubin@fi.tartu.ee; Sherman, A.
2014-11-07
The spin-1 Heisenberg model on a triangular lattice with the ferromagnetic nearest-neighbor and antiferromagnetic third-nearest-neighbor exchange interactions, J{sub 1}=−(1−p)J and J{sub 2}=pJ, J>0(0≤p≤1), is studied with the use of the SPINPACK code. This model is applicable for the description of the magnetic properties of NiGa{sub 2}S{sub 4}. The ground, low-lying excited state energies and spin-spin correlation functions have been found for lattices with N=16 and N=20 sites with the periodic boundary conditions. These results are in qualitative agreement with earlier authors' results obtained with Mori's projection operator technique. - Highlights: • The S=1J{sub 1}–J{sub 3} Heisenberg model on a triangular lattice is studied. • The ferromagnetic nearest and AF 3rd-nearest-neighbor couplings are considered. • The exact diagonalization study of finite lattices was done. • The SPINPACK code using Lanczos' method is used for calculations. • The obtained results are in agreement with those obtained by Mori's approach.
Prazen, B J; Johnson, K J; Weber, A; Synovec, R E
2001-12-01
Quantitative analysis of naphtha samples is demonstrated using comprehensive two-dimensional gas chromatography (GC x GC) and chemometrics. This work is aimed at providing a GC system for the quantitative and qualitative analysis of complex process streams for process monitoring and control. The high-speed GC x GC analysis of naphtha is accomplished through short GC columns, high carrier gas velocities, and partial chromatographic peak resolution followed by multivariate quantitative analysis. Six min GC x GC separations are analyzed with trilinear partial least squares (tri-PLS) to predict the aromatic and naphthene (cycloalkanes) content of naphtha samples. The 6-min GC x GC separation time is over 16 times faster than a single-GC-column standard method in which a single-column separation resolves the aromatic and naphthene compounds in naphtha and predicts the aromatic and naphthene percent concentrations through addition of the resolved signals. Acceptable quantitative precision is provided by GC x GC/tri-PLS.
Reddy, Christopher M; Nelson, Robert K; Sylva, Sean P; Xu, Li; Peacock, Emily A; Raghuraman, Bhavani; Mullins, Oliver C
2007-04-27
Comprehensive two-dimensional gas chromatography with flame ionization detection (GC x GC-FID) was used to measure alkene-based drilling fluids in crude oils. Compared to one-dimensional gas chromatography, GC x GC-FID is more robust for detecting alkenes due to the increased resolution afforded by second dimension separations. Using GC x GC-FID to analyze four oil samples from one reservoir contaminated with the same drilling fluid, C(15), C(16), C(17), C(18) and C(20) alkenes were identified. The drilling fluid that contaminated these samples also differed from another commercially obtained fluid, which only contained C(16) and C(18) alkenes. These results should motivate the petroleum industry to consider GC x GC-FID for measuring drilling fluids.
Zoccali, Mariosimone; Schug, Kevin A; Walsh, Phillip; Smuts, Jonathan; Mondello, Luigi
2017-05-12
The present paper is focused on the use of a vacuum ultraviolet absorption spectrometer (VUV) for gas chromatography (GC), within the context of flow modulated comprehensive two-dimensional gas chromatography (FM GC×GC). The features of the VUV detector were evaluated through the analysis of petrochemical and fatty acids samples. Besides responding in a predictable fashion via Beer's law principles, the detector provides additional spectroscopic information for qualitative analysis. Virtually all chemical species absorb and have unique gas phase absorption features in the 120-240nm wavelength range monitored. The VUV detector can acquire up to 90 full range absorption spectra per second, allowing its coupling with comprehensive two-dimensional gas chromatography. This recent form of detection can address specific limitations related to mass spectrometry (e.g., identification of isobaric and isomeric species with very similar mass spectra or labile chemical compounds), and it is also able to deconvolute co-eluting peaks. Moreover, it is possible to exploit a pseudo-absolute quantitation of analytes based on pre-recorded absorption cross-sections for target analytes, without the need for traditional calibration. Using this and the other features of the detector, particular attention was devoted to the suitability of the FM GC×GC-VUV system toward qualitative and quantitative analysis of bio-diesel fuel and different kinds of fatty acids. Satisfactory results were obtained in terms of tailing factor (1.1), asymmetry factor (1.1), and similarity (average value 97%), for the FAMEs mixtures analysis. Copyright © 2017 Elsevier B.V. All rights reserved.
Ba8CoNb6O24 : A spin-1/2 triangular-lattice Heisenberg antiferromagnet in the two-dimensional limit
Rawl, R.; Ge, L.; Agrawal, H.; Kamiya, Y.; Dela Cruz, C. R.; Butch, N. P.; Sun, X. F.; Lee, M.; Choi, E. S.; Oitmaa, J.; Batista, C. D.; Mourigal, M.; Zhou, H. D.; Ma, J.
2017-02-01
The perovskite Ba8CoNb6O24 comprises equilateral effective spin-1/2 Co2 + triangular layers separated by six nonmagnetic layers. Susceptibility, specific heat, and neutron scattering measurements combined with high-temperature series expansions and spin-wave calculations confirm that Ba8CoNb6O24 is basically a two-dimensional magnet with no detectable spin anisotropy and no long-range magnetic ordering down to 0.06 K. In other words, Ba8CoNb6O24 is very close to be a realization of the paradigmatic spin-1/2 triangular Heisenberg model, which is not expected to exhibit symmetry breaking at finite temperatures according to the Mermin and Wagner theorem.
Energy Technology Data Exchange (ETDEWEB)
Hummel, D.W.; Langton, S.E.; Ball, M.R.; Novog, D.R.; Buijs, A., E-mail: hummeld@mcmaster.ca [McMaster Univ., Hamilton, Ontario (Canada)
2013-07-01
Discrepancies have been observed among a number of recent reactor physics studies in support of the PT-SCWR pre-conceptual design, including differences in lattice-level predictions of infinite neutron multiplication factor, coolant void reactivity, and radial power profile. As a first step to resolving these discrepancies, a lattice-level benchmark problem was designed based on the 78-element plutonium-thorium PT-SCWR fuel design under a set of prescribed local conditions. This benchmark problem was modeled with a suite of both deterministic and Monte Carlo neutron transport codes. The results of these models are presented here as the basis of a code-to-code comparison. (author)
Galvez, Richard; Joseph, Anosh; Mehta, Dhagash
2012-01-01
Recently there has been some controversy in the literature concerning the existence of a fermion sign problem in the $\\mathcal{N}=(2,2)$ supersymmetric Yang--Mills (SYM) theories on the lattice. In this work, we address this issue by conducting Monte Carlo simulations not only for $\\mathcal{N}=(2,2)$ but also for $\\mathcal{N}=(8,8)$ SYM in two dimensions for the U(N) theories with N=2, using the new ideas derived from topological twisting followed by geometric discretization. Our results from simulations provide the evidence that these theories do {\\it not} suffer from a sign problem as the continuum limit is approached. These results thus boost confidence that these new lattice formulations can be used successfully to explore the nonperturbative aspects of the four-dimensional $\\mathcal{N}=4$ SYM theory.
Retta, Moges; Ho, Quang Tri; Yin, Xinyou; Verboven, Pieter; Berghuijs, Herman N C; Struik, Paul C; Nicolaï, Bart M
2016-05-01
CO2 exchange in leaves of maize (Zea mays L.) was examined using a microscale model of combined gas diffusion and C4 photosynthesis kinetics at the leaf tissue level. Based on a generalized scheme of photosynthesis in NADP-malic enzyme type C4 plants, the model accounted for CO2 diffusion in a leaf tissue, CO2 hydration and assimilation in mesophyll cells, CO2 release from decarboxylation of C4 acids, CO2 fixation in bundle sheath cells and CO2 retro-diffusion from bundle sheath cells. The transport equations were solved over a realistic 2-D geometry of the Kranz anatomy obtained from light microscopy images. The predicted responses of photosynthesis rate to changes in ambient CO2 and irradiance compared well with those obtained from gas exchange measurements. A sensitivity analysis showed that the CO2 permeability of the mesophyll-bundle sheath and airspace-mesophyll interfaces strongly affected the rate of photosynthesis and bundle sheath conductance. Carbonic anhydrase influenced the rate of photosynthesis, especially at low intercellular CO2 levels. In addition, the suberin layer at the exposed surface of the bundle sheath cells was found beneficial in reducing the retro-diffusion. The model may serve as a tool to investigate CO2 diffusion further in relation to the Kranz anatomy in C4 plants.
Tailoring the Two Dimensional Electron Gas at Polar ABO3/SrTiO3 Interfaces for Oxide Electronics
Li, Changjian; Liu, Zhiqi; Lü, Weiming; Wang, Xiao Renshaw; Annadi, Anil; Huang, Zhen; Zeng, Shengwei; Ariando; Venkatesan, T.
2015-08-01
The 2D electron gas at the polar/non-polar oxide interface has become an important platform for several novel oxide electronic devices. In this paper, the transport properties of a wide range of polar perovskite oxide ABO3/SrTiO3 (STO) interfaces, where ABO3 includes LaAlO3, PrAlO3, NdAlO3, NdGaO3 and LaGaO3 in both crystalline and amorphous forms, were investigated. A robust 4 unit cell (uc) critical thickness for metal insulator transition was observed for crystalline polar layer/STO interface while the critical thickness for amorphous ones was strongly dependent on the B site atom and its oxygen affinity. For the crystalline interfaces, a sharp transition to the metallic state (i.e. polarization catastrophe induced 2D electron gas only) occurs at a growth temperature of 515 °C which corresponds to a critical relative crystallinity of ~70 ± 10% of the LaAlO3 overlayer. This temperature is generally lower than the metal silicide formation temperature and thus offers a route to integrate oxide heterojunction based devices on silicon.
Kinetic view of chirped optical lattice gas heating
Graul, J. S.; Gimelshein, S. F.; Lilly, T. C.
2014-12-01
With a focus on optical lattice gas heating, direct simulation Monte Carlo was used to investigate the interaction between molecular nitrogen, argon and methane, initially at 300 K and 0.8 atm, with pulsed, chirped optical lattices. Created from two 700 mJ, 532 nm, flattop laser pulses, the optical lattice parameters simulated are based on published optical lattice-based experiments, to ensure that pulse energies and durations do not exceed published optical breakdown (ionization) thresholds. Resultant translational gas temperatures, as well as induced bulk velocities, were used quantify energy and momentum deposition. To maximize available gas temperature changes achieved using the technique, laser pulses were linearly chirped to produce lattice velocities able to more effectively facilitate energy deposition throughout the pulse duration. From the initial conditions, the maximum, end pulse axial translational temperature obtained in nitrogen was approximately 755 K, at a lattice velocity of 400 m/s linearly chirped at 25 Gm/s2 over the 40 ns pulse duration. To date, this stands as the single largest, numerically-predicted temperature change from optical lattice gas heating under the numerical integration of real world energy and laser-based limitations.
Energy Technology Data Exchange (ETDEWEB)
Mandal, Ruma; Laha, Pinaki; Das, Kaustuv; Saha, Susmita; Barman, Saswati; Raychaudhuri, A. K.; Barman, Anjan, E-mail: abarman@bose.res.in [Thematic Unit of Excellence on Nanodevice Technology, Department of Condensed Matter Physics and Material Sciences, S. N. Bose National Centre for Basic Sciences, Block JD, Sector III, Salt Lake, Kolkata 700 098 (India)
2013-12-23
We show that the optically induced spin wave spectra of nanoscale Ni{sub 80}Fe{sub 20} (permalloy) antidot lattices can be tuned by changing the antidot shape. The spin wave spectra also show an anisotropy with the variation of the in-plane bias field orientation. Analyses show this is due to various quantized and extended modes, whose nature changes with the antidot shape and bias field orientation as a result of the variation of the internal magnetic field profile. The observed variation and anisotropy in the spin waves with the internal and external parameters are important for their applications in magnonic devices.
Fernandes, Daniella R; Pereira, Vinícius B; Stelzer, Karen T; Gomes, Alexandre O; Neto, Francisco R Aquino; Azevedo, Débora A
2015-11-01
Comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC×GC-TOFMS) was successfully applied to eight real Brazilian Fischer-Tropsch (FT) product samples for the quantitative analysis of O-containing compounds. It not only allowed identifying and quantifying simultaneously a large number of O-containing compounds but also resolved many co-eluting components, such as carboxylic acids, which co-elute in one-dimensional gas chromatography. The homologous series of alcohols and carboxylic acids as trimethylsilyl derivatives were detected and identified at trace levels. The absolute quantification of each compound was accomplished with reliability using analytical curves. Linear alcohols (from C5 to C19), branched alcohols (C6-C13) and carboxylic acids (C4 to C12) were obtained in the range of 1.58 mg g(-1) to 14.75 mg g(-1), 0.51 mg g(-1) to 1.12 mg g(-1) and 0.21 mg g(-1) to 1.63 mg g(-1) of FT product samples, respectively. GC×GC-TOFMS provided a linear range (from 0.3 ng µL(-1) to 10 ng µL(-1)), good precision (gas-to-liquid technologies from natural gas and guide the choice of an FT conversion process that generates clean products with higher added value.
Mondello, Luigi; Casillia, Alessandro; Tranchida, Peter Quinto; Dugo, Giovanni; Dugo, Paola
2005-03-04
Single column gas chromatography (GC) in combination with a flame ionization detector (FID) and/or a mass spectrometer is routinely employed in the determination of perfume profiles. The latter are to be considered medium to highly complex matrices and, as such, can only be partially separated even on long capillaries. Inevitably, several monodimensional peaks are the result of two or more overlapping components, often hindering reliable identification and quantitation. The present investigation is based on the use of a comprehensive GC (GC x GC) method, in vacuum outlet conditions, for the near to complete resolution of a complex perfume sample. A rapid scanning quadrupole mass spectrometry (qMS) system, employed for the assignment of GC x GC peaks, supplied high quality mass spectra. The validity of the three-dimensional (3D) GC x GC-qMS application was measured and compared to that of GC-qMS analysis on the same matrix. Peak identification, in all applications, was achieved through MS spectra library matching and the interactive use of linear retention indices (LRI).
Motevalli, Benyamin; Taherifar, Neda; Liu, Zhe
We report a cooperative reformable channel system in a coordination porous polymer, named as ZIF-L. Three types of local flexible ligands coexist in the crystal structure of this polymer, resulting in ultra-flexibility. The reformable channel is able to regulate permeation of a nonspherical guest molecule, such as N2 or CO2, based on its longer molecular dimension, which is in a striking contrast to conventional molecular sieves that regulate the shorter cross-sectional dimension of the guest molecules. Our density functional theory (DFT) calculations reveal that the guest molecule induces dynamic motion of the flexible ligands, leading to the channel reformation, and then the guest molecule reorientates itself to fit in the reformed channel. Such a unique ``induced fit-in'' mechanism causes the gas molecule to pass through 6 membered-ring windows in the c- crystal direction of ZIF-L with its longer axis parallel to the window plane. Our experimental permeance of N2 through the ZIF-L membranes is about three times greater than that of CO2, supporting the DFT simulation predictions.
Nolvachai, Yada; Kulsing, Chadin; Marriott, Philip J
2016-02-16
The selection of the best column sets is one of the most tedious processes in comprehensive two-dimensional gas chromatography (GC × GC) where a multitude of choices of column sets could be employed for an individual sample analysis. We demonstrate analyte/stationary phase dependent selection approaches based on the linear solvation energy relationship (LSER), which is a reliable concept for the study of interaction mechanisms and retention prediction with a large database pool of columns and compounds. Good correlations between our predicted results, with experimental results reported in the literature, were obtained. The developed approaches were applied to the simulation of 157 920 individual experiments in GC × GC, focusing on the application of 30 nonionic liquid and 111 ionic liquid (IL) stationary phases for separation of some example sets of model compounds present in practical samples. The best column sets for each sample separation could then be extracted according to maximizing orthogonality, which estimates the quality of separation.
Yudin, Dmitry; Shelykh, Ivan A.
2016-10-01
A nonperturbative interaction of an electronic system with a laser field can substantially modify its physical properties. In particular, in two-dimensional (2D) materials with a lack of inversion symmetry, the achievement of a regime of strong light-matter coupling allows direct optical tuning of the strength of the Rashba spin-orbit interaction (SOI). Capitalizing on these results, we build a theory of the dynamical conductivity of a 2D electron gas with both Rashba and Dresselhaus SOIs coupled to an off-resonant high-frequency electromagnetic wave. We argue that strong light-matter coupling modifies qualitatively the dispersion of the electrons and can be used as a powerful tool to probe and manipulate the coupling strengths and adjust the frequency range where optical conductivity is essentially nonzero.
Adam, Frédérick; Vendeuvre, Colombe; Bertoncini, Fabrice; Thiébaut, Didier; Espinat, Didier; Hennion, Marie-Claire
2008-01-18
A new column association using comprehensive two-dimensional gas chromatography for the detailed molecular analysis of hydrocarbon mixtures is reported in this paper. In order to compare the impact of two different secondary columns, a novel column combination relying on a GC x 2GC system was used. This system is based on a non-polar first column (PONA) combined with both a permethylated beta-cyclodextrin (beta-Dex 120) stationary phase and a polysilphenylensiloxane (BPX 50) in the second dimension. Compared to BPX 50 stationary phase, the implementation of beta-cyclodextrin columns as the second dimension was found to improve the resolution between paraffins and naphthenes in the naphtha range but not in the middle distillate range. Attempts to improve the results and to understand the interaction mechanism remained unsuccessful. Therefore, the benefits of the beta-Dex 120-column are only demonstrated on heavy naphtha cut for the quantitation of hydrocarbons.
Takahashi, Kei; Kabashima, Fumie; Tsuchiya, Fumihiko
2016-03-01
Japanese sake is a traditional alcoholic beverage composed of a wide variety of metabolites, which give it many types of tastes and flavors. Previously, we have reported that medium-chain fatty acids contribute to a fatty odor in sake (Takahashi, K., et al., J. Agric. Food Chem., 62, 8478-8485, 2014). In this study, we have reanalyzed the data obtained using two-dimensional gas chromatography coupled with time-of-flight mass spectrometry. The relationship between the chemical components in sake and specific organoleptic properties such as off-flavor and quality has been explored. This led to the identification of the type of chemical compounds present and an assessment of the numerous candidate compounds that correlate with such organoleptic properties in sake. This research provides important fundamental knowledge for the sake-brewing industry. Copyright © 2015 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.
Energy Technology Data Exchange (ETDEWEB)
Lu, Mao-Wang; Huang, Xin-Hong; Zhang, Gui-Lin; Chen, Sai-Yan [College of Science, Guilin University of Technology, Guilin 541004 (China)
2012-11-15
We present a theoretical study on the spin-dependent Goos-Haenchen (GH) effect in a two-dimensional electron gas modulated by ferromagnetic and Schottky metal (SM) stripes. The GH shifts for spin electron beams across this device are calculated with the help of the stationary phase method. It is shown that the GH shift of spin-up beam is significantly different from that of spin-down beam, i.e., this device shows up a considerable spin polarization effect in GH shifts of electron beams. It also is shown that both magnitude and sign of spin polarization of GH shifts are closely related to the stripe width, the magnetic strength and the gated voltage under SM stripe. These interesting properties not only provide an effective method of spin injection for spintronics application, but also give rise to a tunable spin beam splitter. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Mao, Debin; Lookman, Richard; Van De Weghe, Hendrik; Van Look, Dirk; Vanermen, Guido; De Brucker, Nicole; Diels, Ludo
2009-02-27
Enhanced bioremediation of petroleum hydrocarbons in two biopiles was quantified by high-performance liquid chromatography (HPLC) followed by comprehensive two-dimensional gas chromatography (GCXGC). The attenuation of 34 defined hydrocarbon classes was calculated by HPLC-GCXGC analysis of representative biopile samples at start-up and after 18 weeks of biopile operation. In general, a-cyclic alkanes were most efficiently removed from the biopiles, followed by monoaromatic hydrocarbons. Cycloalkanes and polycyclic aromatic hydrocarbons (PAHs) were more resistant to degradation. A-cyclic biomarkers farnesane, trimethyl-C13, norpristane, pristane and phytane dropped to only about 10% of their initial concentrations. On the other hand, C29-C31 hopane concentrations remained almost unaltered after 18 weeks of biopile operation, confirming their resistance to biodegradation. They are thus reliable indicators to estimate attenuation potential of petroleum hydrocarbons in biopile processed soils.
Energy Technology Data Exchange (ETDEWEB)
Mohammadkhani, R., E-mail: rmkhani@znu.ac.ir; Hassanloo, Gh.
2014-11-01
We have studied the tunneling conductance of a clean two dimensional electron gas/p- wave superconductor junction with Rashba spin–orbit coupling (RSOC) which is present in the normal layer and at the interface. Using the extended Blonder–Tinkham–Klapwijk formalism we have found that the subgap conductance peaks are shifted to a nonzero bias by RSOC at the interface which are the same as Ref. [1]. It is shown that for low insulating barrier and in the absence of the interface RSOC, the tunneling conductance decreases within energy gap with increasing of the RSOC in the normal layer while for high insulating barrier it enhances by increase of the RSOC. We have also shown that the RSOC inside the normal cannot affect the location of the subgap conductance peaks shifted by the interface RSOC.
Barnes, Brian B; Snow, Nicholas H
2012-02-24
Salvinorin A, a psychoactive hallucinogen, and related compounds, were analyzed in plants, water, and urine using liquid-liquid extraction (LLE), solid-phase microextraction (SPME) and comprehensive two-dimensional gas chromatography-time of flight mass spectrometry (GC×GC-ToFMS). A semi-qualitative study of the extraction of Salvinorin A and analogs from Salvia divinorum plants by LLE showed ppb levels of Salvinorin A and several analogs in the leaves and stems of S. divinorum plants, much lower than expected. Quantitative analysis of Salvinorin A spiked into water and urine showed much better figures of merit for SPME than LLE, with limit of detection of about 5 ng/mL, linear range from 8 to 500 ng/mL and precision about ±10% for the SPME-based analyses using external standard quantitation. GC×GC-ToFMS was especially effective in separating the peaks of interest from matrix and chromatographic interferences.
Energy Technology Data Exchange (ETDEWEB)
Pogosov, A.G.; Budantsev, M.V.; Lavrov, R.A.; Mansurov, V.G.; Nikitin, A.Yu.; Preobrazhenskii, V.V.; Zhuravlev, K.S. [Institute of Semiconductor Physics, 13 Lavrentiev Avenue, 630090 Novosibirsk (Russian Federation)
2006-07-15
Transport properties of the two-dimensional electron gas in AlGaN/GaN heterostructures grown by ammonia molecular-beam epitaxy are experimentally investigated. Conventional Hall and Shubnikov-de Haas measurements as well as investigations of quantum transport phenomena are reported. It is found that negative magnetoresistance (NMR) caused by weak localization demonstrates an unusual behavior at low temperature (1.8 K). The observed NMR cannot be described by the ordinary theory of quantum corrections to conductivity based on a single phase breaking time {tau}{sub {phi}}. The anomalous NMR behavior can be explained by the presence of two occupied quantum subbands, characterized by their own phase breaking times {tau} {sub {phi}} {sub 1} and {tau} {sub {phi}} {sub 2}. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Donor-Like Surface Traps on Two-Dimensional Electron Gas and Current Collapse of AlGaN/GaN HEMTs
Yu, Chen-hui; Luo, Qing-zhou; Luo, Xiang-dong; Liu, Pei-sheng
2013-01-01
The effect of donor-like surface traps on two-dimensional electron gas (2DEG) and drain current collapse of AlGaN/GaN high electron mobility transistors (HEMTs) has been investigated in detail. The depletion of 2DEG by the donor-like surface states is shown. The drain current collapse is found to be more sensitive to the addition of positive surface charges. Surface trap states with higher energy levels result in weaker current collapse and faster collapse process. By adopting an optimized backside doping scheme, the electron density of 2DEG has been improved greatly and the current collapse has been greatly eliminated. These results give reference to the improvement in device performance of AlGaN/GaN HEMTs. PMID:24348195
Two-dimensional electron gas generated by La-doping at SrTiO3(001 surface: A first-principles study
Directory of Open Access Journals (Sweden)
Yun Li
2013-06-01
Full Text Available We carried out first-principles calculations to study the electronic properties of SrO-terminated and TiO2-terminated SrTiO3(001 surfaces with La-doping at the surface. We find that an intrinsic lower-lying state at the SrO-terminated surface can accommodate a two-dimensional electron gas (2DEG. By introducing La-doping at the SrO-terminated surface the energy position of the surface state and the 2DEG density can be tuned by changing the doping concentration. The higher the La-doping concentration, the lower the lower-lying state and the higher the 2DEG density. This 2DEG has a small effective mass and hopefully shows a high mobility.
Patterning the two dimensional electron gas at the LaAlO3/SrTiO3 interface by structured Al capping
Zhou, Y.; Wang, P.; Luan, Z. Z.; Shi, Y. J.; Jiang, S. W.; Ding, H. F.; Wu, D.
2017-04-01
We demonstrate an approach for patterning a quasi-two dimensional electron gas (q-2DEG) at the interface of LaAlO3 (LAO) and SrTiO3 (STO) utilizing a structured Al capping layer. The capping of Al enables the formation of q-2DEG at the interface of 1-3 unit cells (uc) of LAO on STO, which was originally insulating before capping. The properties of the q-2DEG induced by the Al capping layer are essentially the same as those of q-2DEG without Al. Therefore, we can pattern q-2DEG by simply patterning the Al film on LAO (2 or 3 uc)/STO using a one-step liftoff process. Our approach circumvents the difficulty of direct patterning of oxide materials and provides a simple and robust patterning method for future device applications based on complex oxide interfaces.
Xu, Peng; Ayino, Yilikal; Cheng, Christopher; Pribiag, Vlad S.; Comes, Ryan B.; Sushko, Peter V.; Chambers, Scott A.; Jalan, Bharat
2016-09-01
Through systematic control of the Nd concentration, we show that the carrier density of the two-dimensional electron gas (2DEG) in SrTiO3/NdTiO3/SrTiO3(001 ) can be modulated over a wide range. We also demonstrate that the NdTiO3 in heterojunctions without a SrTiO3 cap is degraded by oxygen absorption from air, resulting in the immobilization of donor electrons that could otherwise contribute to the 2DEG. This system is, thus, an ideal model to understand and control the insulator-to-metal transition in a 2DEG based on both environmental conditions and film-growth processing parameters.
Institute of Scientific and Technical Information of China (English)
HAN Xiu-Xun; WU Jie-Jun; LI Jie-Min; CONG Guang-Wei; LIU Xiang-Lin; ZHU Qin-Sheng; WANG Zhan-Guo
2005-01-01
@@ Low-temperature photoluminescence measurement is performed on an undoped Alx Ga1-xN/GaN heterostructure. Temperature-dependent Hall mobility confirms the formation of two-dimensional electron gas (2DEG) near the heterointerface. A weak photoluminescence (PL) peak with the energy of ～79meV lower than the free exciton (FE) emission of bulk GaN is related to the radiative recombination between electrons confined in the triangular well and the holes near the flat-band region of GaN. Its identification is supported by the solution of coupled one-dimensional Poisson and Schrodinger equations. When the temperature increases, the red shift of the 2DEG related emission peak is slower than that of the FE peak. The enhanced screening effect coming from the increasing 2DEG concentration and the varying electron distribution at two lowest subbands as a function of temperature account for such behaviour.
Energy Technology Data Exchange (ETDEWEB)
King, P.D.C.
2012-03-01
We demonstrate the formation of a two-dimensional electron gas (2DEG) at the (100) surface of the 5d transition-metal oxide KTaO{sub 3}. From angle-resolved photoemission, we find that quantum confinement lifts the orbital degeneracy of the bulk band structure and leads to a 2DEG composed of ladders of subband states of both light and heavy carriers. Despite the strong spin-orbit coupling, we find no experimental signatures of a Rashba spin splitting, which has important implications for the interpretation of transport measurements in both KTaO{sub 3}- and SrTiO{sub 3}-based 2DEGs. The polar nature of the KTaO{sub 3}(100) surface appears to help mediate formation of the 2DEG as compared to non-polar SrTiO{sub 3}(100).
Tanuma, S; Kudoh, T; Shibata, K; Tanuma, Syuniti; Yokoyama, Takaaki; Kudoh, Takahiro; Shibata, Kazunari
2001-01-01
We examine the magnetic reconnection triggered by a supernova (or a point explosion) in interstellar medium, by performing two-dimensional resistive magnetohydrodynamic (MHD) numerical simulations with high spatial resolution. We found that the magnetic reconnection starts long after a supernova shock (fast-mode MHD shock) passes a current sheet. The current sheet evolves as follows: (i) Tearing-mode instability is excited by the supernova shock, and the current sheet becomes thin in its nonlinear stage. (ii) The current-sheet thinning is saturated when the current-sheet thickness becomes comparable to that of Sweet-Parker current sheet. After that, Sweet-Parker type reconnection starts, and the current-sheet length increases. (iii) ``Secondary tearing-mode instability'' occurs in the thin Sweet-Parker current sheet. (iv) As a result, further current-sheet thinning occurs and anomalous resistivity sets in, because gas density decreases in the current sheet. Petschek type reconnection starts and heats interste...
Mogollon, Noroska Gabriela Salazar; Ribeiro, Fabiana Alves de Lima; Lopez, Monica Mamian; Hantao, Leandro Wang; Poppi, Ronei Jesus; Augusto, Fabio
2013-09-24
In this paper, a method to determine the composition of blends of biodiesel with mineral diesel (BXX) by multivariate curve resolution with Alternating Least Squares (MRC-ALS) combined to comprehensive two-dimensional gas chromatography with Flame Ionization Detection (GC×GC-FID) is presented. Chromatographic profiles of BXX blends produced with biodiesels from different sources were used as input data. An initial evaluation carried out after multiway principal component analysis (MPCA) was used to reveal regions of the chromatograms were the signal was likely to be dependent on the concentration of biodiesel, regardless its vegetable source. After this preliminary step MCR-ALS modeling was carried out only using relevant parts of the chromatograms. The resulting procedure was able to predict accurately the concentration of biodiesel in the BXX samples regardless of its origin.
Tran, Tin C.; Marriott, Philip J.
This study reports comprehensive two-dimensional gas chromatography hyphenated to time-of-flight mass spectrometry detection (GC × GC/TOFMS) for characterisation and identification of components generated by four different types of powdered incense headspace (H/S) and incense smoke. GC × GC/TOFMS allowed simultaneous separation and identification of compounds emitted into the atmosphere as a result of combustion of incense powder. The smoke stream comprised compounds originating from the incense powder, and combustion products such as saturated and unsaturated hydrocarbons, essential oil type compounds, nitromusks, fatty acid methyl esters (FAMEs), polycyclic aromatic hydrocarbons (PAHs, which possibly include oxygenated and nitrated PAH), N-heterocyclics, pyrans and furans, which were detected and tentatively identified by GC × GC/TOFMS. GC × GC-electron capture detector/nitrogen phosphorous detector (ECD/NPD) potentially offers the prospect of providing selective chemical compositional information of incense powder and smoke, such as nitrogen-containing (N-containing) and halogenated compounds. Results of GC×GC-ECD/NPD showed that both incense powder and smoke generated emission of N-containing and halogenated compounds. A significant number of halogenated and N-containing compounds were emitted during the incomplete combustion of incense. However, one further objective of this paper is to demonstrate the capacity of comprehensive two-dimensional gas chromatography coupled to specific and/or selective detectors such as those used in this study (GC × GC-ECD/NPD) for the detection of particular classes of compounds such as N-containing and halogenated compounds at trace level concentrations in complex smoke samples.
Gieleciak, Rafal; Hager, Darcy; Heshka, Nicole E
2016-03-11
Information on the sulfur classes present in petroleum is a key factor in determining the value of refined products and processing behavior in the refinery. A large part of the sulfur present is included in polycyclic aromatic sulfur heterocycles (PASHs), which in turn are difficult to desulfurize. Furthermore, some PASHs are potentially more mutagenic and carcinogenic than polycyclic aromatic hydrocarbons, PAHs. All of this calls for improved methods for the identification and quantification of individual sulfur species. Recent advances in analytical techniques such as comprehensive two-dimensional gas chromatography (GC×GC) have enabled the identification of many individual sulfur species. However, full identification of individual components, particularly in virgin oil fractions, is still out of reach as standards for numerous compounds are unavailable. In this work, a method for accurately predicting retention times in GC×GC using a QSRR (quantitative structure retention relationship) method was very helpful for the identification of individual sulfur compounds. Retention times for 89 saturated, aromatic, and polyaromatic sulfur-containing heterocyclic compounds were determined using two-dimensional gas chromatography. These retention data were correlated with molecular descriptors generated with CODESSA software. Two independent QSRR relationships were derived for the primary as well as the secondary retention characteristics. The predictive ability of the relationships was tested by using both independent sets of compounds and a cross-validation technique. When the corresponding chemical standards are unavailable, the equations developed for predicting retention times can be used to identify unknown chromatographic peaks by matching their retention times with those of sulfur compounds of known molecular structure.
Institute of Scientific and Technical Information of China (English)
Chai Zhen-Hua; Shi Bao-Chang; Zheng Lin
2006-01-01
By coupling the non-equilibrium extrapolation scheme for boundary condition with the multi-relaxation-time lattice Boltzmann method, this paper finds that the stability of the multi-relaxation-time model can be improved greatly, especially on simulating high Reynolds number (Re) flow. As a discovery, the super-stability analysed by Lallemand and Luo is verified and the complex structure of the cavity flow is also exhibited in our numerical simulation when Re is high enough. To the best knowledge of the authors, the maximum of Re which has been investigated by direct numerical simulation is only around 50 000 in the literature; however, this paper can readily extend the maximum to 1000 000 with the above combination.
Zhuravlev, Vladimir; Duan, Wenye; Maniv, Tsofar
2017-01-01
A self-consistent Bogoliubov-de Gennes theory of the vortex lattice state in a 2D strong type-II superconductor at high magnetic fields reveals a novel quantum mixed state around the semiclassical Hc 2, characterized by a well-defined Landau-Bloch band structure in the quasiparticle spectrum and suppressed order-parameter amplitude, which sharply crossover into the well-known semiclassical (Helfand-Werthamer) results upon decreasing magnetic field. Application to the 2D superconducting state observed recently on the surface of the topological insulator Sb2Te3 accounts well for the experimental data, revealing a strong type-II superconductor, with unusually low carrier density and very small cyclotron mass, which can be realized only in the strong coupling superconductor limit.
Energy Technology Data Exchange (ETDEWEB)
Pires, A.S.T. [Departamento de Fisica, Universidade Federal de Minas Gerais, Belo Horizonte, MG, CP 702, 30123-970 (Brazil); Lapa, R.S., E-mail: rodrigophc@gmail.com [Departamento de Fisica, Universidade Federal de Minas Gerais, Belo Horizonte, MG, CP 702, 30123-970 (Brazil)
2013-08-15
We study the disordered phase of the J{sub 1}–J{sub 2} frustrated Heisenberg antiferromagnet with spin S=1 on a square lattice using a SU(3) Schwinger boson representation. In the approximation of Bose condensation and in a mean-field treatment of the four-operator terms, we calculate the gap as a function of J{sub 1}/J{sub 2}, and the quadrupole static structure factor at zero temperature. Our results indicate the existence of a nematic state in the paramagnetic phase. - Highlights: ► The disordered phase is studied. ► The energy gap in the paramagnetic phase is calculated. ► The static spin structure factor is calculated. ► The static quadrupole structure factor is calculated. ► The ground state energy is calculated.
Thornhill, J. W.; Giuliani, J. L.; Chong, Y. K.; Velikovich, A. L.; Dasgupta, A.; Apruzese, J. P.; Jones, B.; Ampleford, D. J.; Coverdale, C. A.; Jennings, C. A.; Waisman, E. M.; Lamppa, D. C.; McKenney, J. L.; Cuneo, M. E.; Krishnan, M.; Coleman, P. L.; Madden, R. E.; Elliott, K. W.
2012-09-01
Argon Z-pinch experiments are to be performed on the refurbished Z machine (which we will refer to as ZR here in order to distinguish between pre-refurbishment Z) at Sandia National Laboratories with a new 8 cm diameter double-annulus gas puff nozzle constructed by Alameda Applied Sciences Corporation (AASC). The gas exits the nozzle from an outer and inner annulus and a central jet. The amount of gas present in each region can be varied. Here a two-dimensional radiation MHD (2DRMHD) model, MACH2-TCRE, with tabular collisional radiative equilibrium atomic kinetics is used to theoretically investigate stability and K-shell emission properties of several measured (interferometry) initial gas distributions emanating from this new nozzle. Of particular interest is to facilitate that the distributions employed in future experiments have stability and K-shell emission properties that are at least as good as the Titan nozzle generated distribution that was successfully fielded in earlier experiments on the Z machine before it underwent refurbishment. The model incorporates a self-consistent calculation for non-local thermodynamic equilibrium kinetics and ray-trace based radiation transport. This level of detail is necessary in order to model opacity effects, non-local radiation effects, and the high temperature state of K-shell emitting Z-pinch loads. Comparisons of radiation properties and stability of measured AASC gas profiles are made with that of the distribution used in the pre-refurbished Z experiments. Based on these comparisons, an optimal K-shell emission producing initial gas distribution is determined from among the AASC nozzle measured distributions and predictions are made for K-shell yields attainable from future ZR experiments.
Vanhille, Christian
2017-01-17
This work deals with a theoretical analysis about the possibility of using linear and nonlinear acoustic properties to modify ultrasound by adding gas bubbles of determined sizes in a liquid. We use a two-dimensional numerical model to evaluate the effect that one and several monodisperse bubble populations confined in restricted areas of a liquid have on ultrasound by calculating their nonlinear interaction. The filtering of an input ultrasonic pulse performed by a net of bubbly-liquid cells is analyzed. The generation of a low-frequency component from a single cell impinged by a two-frequency harmonic wave is also studied. These effects rely on the particular dispersive character of attenuation and nonlinearity of such bubbly fluids, which can be extremely high near bubble resonance. They allow us to observe how gas bubbles can change acoustic signals. Variations of the bubbly medium parameters induce alterations of the effects undergone by ultrasound. Results suggest that acoustic signals can be manipulated by bubbles. This capacity to achieve the modification and control of sound with oscillating gas bubbles introduces the concept of bubbly-liquid-based acoustic metamaterials (BLAMMs).
Cui, Xiongwei; Yao, Xiongliang; Wang, Zhikai; Liu, Minghao
2017-03-01
A second generation wavelet-based adaptive finite-difference Lattice Boltzmann method (FD-LBM) is developed in this paper. In this approach, the adaptive wavelet collocation method (AWCM) is firstly, to the best of our knowledge, incorporated into the FD-LBM. According to the grid refinement criterion based on the wavelet amplitudes of density distribution functions, an adaptive sparse grid is generated by the omission and addition of collocation points. On the sparse grid, the finite differences are used to approximate the derivatives. To eliminate the special treatments in using the FD-based derivative approximation near boundaries, the immersed boundary method (IBM) is also introduced into FD-LBM. By using the adaptive technique, the adaptive code requires much less grid points as compared to the uniform-mesh code. As a consequence, the computational efficiency can be improved. To justify the proposed method, a series of test cases, including fixed boundary cases and moving boundary cases, are invested. A good agreement between the present results and the data in previous literatures is obtained, which demonstrates the accuracy and effectiveness of the present AWCM-IB-LBM.
Institute of Scientific and Technical Information of China (English)
李未; 陈小玲
2011-01-01
利用二维三角晶格介质柱光子晶体TE偏振的禁带与介质柱半径的变化关系,分析了二维光子晶体的带隙分布及斜边耦合特性.结果表明,光子禁带的大小受到构成光子晶体的介电材料的空间排列分布以及介质柱半径大小的影响;束缚在光子晶体中的光波可以在波导和谐振腔中进行传输,达到选择输出光波的目的.%The paper study the relation between two dimensional triangular lattice photonic crystal band gap for TE polarizationand dielectric cylinder radius, and study distribution of two dimensional photonic crystal defect state. Results show, the photonic crystal band gaps were distributed by dielectric material space distribution and medium size of the radius; Tied in the photon crystals of light waves can transmission in waveguides and resonator cavity to select the output of light waves.
Rosenstein, Baruch; Shapiro, B. Ya.; Shapiro, I.; Li, Dingping
2016-07-01
Pairing in one-atomic-layer-thick two-dimensional electron gas (2DEG) by a single flat band of high-energy longitudinal optical phonons is considered. The polar dielectric SrTiO3 (STO) exhibits such an energetic phonon mode and the 2DEG is created both when one unit cell FeSe layer is grown on its (100 ) surface and on the interface with another dielectric like LaAlO3 (LAO). We obtain a quantitative description of both systems solving the gap equation for Tc for arbitrary Fermi energy ɛF, electron-phonon coupling λ , and the phonon frequency Ω , and direct (random-phase approximation) electron-electron repulsion strength α . The focus is on the intermediate region between the adiabatic, ɛF>>Ω , and the nonadiabatic, ɛF<<Ω , regimes. The high-temperature superconductivity in single-unit-cell FeSe/STO is possible due to a combination of three factors: high-longitudinal-optical phonon frequency, large electron-phonon coupling λ ˜0.5 , and huge dielectric constant of the substrate suppression the Coulomb repulsion. It is shown that very low density electron gas in the interfaces is still capable of generating superconductivity of the order of 0.1 K in LAO/STO.
Adam, Frédérick; Bertoncini, Fabrice; Coupard, Vincent; Charon, Nadège; Thiébaut, Didier; Espinat, Didier; Hennion, Marie-Claire
2008-04-04
In the current energetic context (increasing consumption of vehicle fuels, greenhouse gas emission etc.) government policies lead to mandatory introduction in fossil fuels of fuels resulting from renewable sources of energy such as biomass. Blending of fatty acid alkyl esters from vegetable oils (also known as biodiesel) with conventional diesel fuel is one of the solutions technologically available; B5 blends (up to 5%w/w esters in fossil fuel) are marketed over Europe. Therefore, for quality control as well as for forensic reasons, it is of major importance to monitor the biodiesel origin (i.e. the fatty acid ester distribution) and its content when it is blend with petroleum diesel. This paper reports a comprehensive two-dimensional gas chromatography (GC x GC) method that was developed for the individual quantitation of fatty acid esters in middle distillates matrices. Several first and the second dimension columns have been investigated and their performances to achieve (i) a group type separation of hydrocarbons and (ii) individual identification and quantitation of fatty acid ester blend with diesel are reported and discussed. Finally, comparison of quantitative GC x GC results with reference methods demonstrates the benefits of GC x GC approach which enables fast and reliable individual quantitation of fatty acid esters in one single run. Results show that under developed chromatographic conditions, quantitative group type analysis of hydrocarbons is also possible, meaning that simultaneous quantification of hydrocarbons and fatty acid esters can be achieved in one single run.
Vildosola, Verónica; Güller, Francisco; Llois, Ana María
2013-05-17
In this Letter, we find by means of first-principles calculations a new physical mechanism to generate a two-dimensional electron gas, namely, the breaking of charge ordering at the surface of a charge-ordered semiconductor due to the incomplete oxygen environment of the surface ions. The emergence of the 2D gas is independent of the presence of oxygen vacancies or polar discontinuities; this is a self-doping effect. This mechanism might apply to many charge-ordered systems, in particular, we study the case of BaBiO(3)(001). Our calculations show that the outer layer of the Bi-terminated simulated surface turns more cubiclike and metallic while the inner layers remain in the insulating monoclinic state that the system present in the bulk form. On the other hand, the metallization does not occur for the Ba termination, a fact that makes this system appealing for nanostructuring. Finally, in view of the bulk properties of this material under doping, this particular finding sets another possible route for future exploration: the potential scenario of 2D superconductivity at the BaBiO(3) surface.
Gauchotte-Lindsay, C; Richards, P; McGregor, L A; Thomas, R; Kalin, R M
2012-08-31
A dense non-aqueous phase liquid sample formed by release of coal tar into the environment was derivatised by trimethylsilylation using the reagent N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA) and extracted in hexane using accelerated solvent extraction. This procedure enables comprehensive extraction of an extensive suite of organic compounds from tar, which has not previously been described. Comprehensive two dimensional gas chromatography coupled to time of flight mass spectrometry (GC×GC-TOFMS) was used for the analysis of the sample for concurrent evaluation of -OH functional group-containing compounds along with aliphatics, polycyclic aromatic hydrocarbons and other typical tar compounds normally determined via classic gas chromatography. Using statistically designed experiments, a range of conditions were tested for complete recovery of four different surrogates. The robustness and repeatability of the optimised derivatisation/extraction method was demonstrated. Finally, more than a hundred and fifty derivatised compounds were identified using mass spectra elucidation and GC×GC logical order of elution. Copyright © 2012 Elsevier B.V. All rights reserved.
Complex Saddles in Two-dimensional Gauge Theory
Buividovich, P V; Valgushev, S N
2015-01-01
We study numerically the saddle point structure of two-dimensional (2D) lattice gauge theory, represented by the Gross-Witten-Wadia unitary matrix model. The saddle points are in general complex-valued, even though the original integration variables and action are real. We confirm the trans-series/instanton gas structure in the weak-coupling phase, and identify a new complex-saddle interpretation of non-perturbative effects in the strong-coupling phase. In both phases, eigenvalue tunneling refers to eigenvalues moving off the real interval, into the complex plane, and the weak-to-strong coupling phase transition is driven by saddle condensation.
Gröger, Thomas; Gruber, Beate; Harrison, Dale; Saraji-Bozorgzad, Mohammad; Mthembu, Makhosazana; Sutherland, Aimée; Zimmermann, Ralf
2016-03-15
Fast and selective detectors are very interesting for comprehensive two-dimensional gas chromatography (GC × GC). This is particularly true if the detector system can provide additional spectroscopic information on the compound structure and/or functionality. Other than mass spectrometry (MS), only optical spectroscopic detectors are able to provide selective spectral information. However, until present the application of optical spectroscopy technologies as universal detectors for GC × GC has been restricted mainly due to physical limitations such as insufficient acquisition speed or high detection limits. A recently developed simultaneous-detection spectrometer working in the vacuum ultraviolet (VUV) region of 125-240 nm overcomes these limitations and meets all the criteria of a universal detector for GC × GC. Peak shape and chromatographic resolution is preserved and unique spectral information, complementary to mass spectrometry data, is gained. The power of this detector is quickly recognized as it has the ability to discriminate between isomeric compounds or difficult to separate structurally related isobaric species; thus, it provides additional selectivity. A further promising feature of this detector is the data analysis concept of spectral filtering, which is accomplished by targeting special electronic transitions that allows for a fast screening of GC × GC chromatograms for designated compound classes.
Michailof, Chrysoula; Sfetsas, Themistoklis; Stefanidis, Stylianos; Kalogiannis, Konstantinos; Theodoridis, Georgios; Lappas, Angelos
2014-11-21
Thermal and catalytic pyrolysis are efficient processes for the transformation of biomass to bio-oil, a liquid energy carrier and a general source of chemicals. The elucidation of the bio-oil's composition is essential for a rational design of both its production and utilization process. However, the complex composition of bio-oils hinders their complete qualitative and quantitative analysis, and conventional chromatographic techniques lack the necessary separation power. Two-dimensional gas chromatography with time-of-flight mass spectrometry (GC×GC-ToFMS) is considered a suitable technique for bio-oil analysis due to its increased separation and resolution capacity. This work presents the tentative qualitative and quantitative analysis of bio-oils resulting from the thermal and catalytic pyrolysis of standard xylan, cellulose, lignin and their mixture by GC×GC-ToFMS. Emphasis is placed on the development of the quantitative method using phenol-d6 as internal standard. During the method development, a standard solution of 39 compounds was used for the determination of the respective Relative Response Factors (RRF) employing statistical methods, ANOVA and WLSLR, for verification of the data. The developed method was applied to the above mentioned bio-oils and their detailed analysis is presented. The different compounds produced and their diverse concentration allows for an elucidation of the pyrolysis mechanism and highlight the effect of the catalyst.
Nizio, Katie D; Harynuk, James J
2012-08-24
Alkyl phosphate based gellants used as viscosity builders for fracturing fluids used in the process of hydraulic fracturing have been implicated in numerous refinery-fouling incidents in North America. In response, industry developed an inductively coupled plasma optical emission spectroscopy (ICP-OES) based method for the analysis of total volatile phosphorus in distillate fractions of crude oil; however, this method is plagued by poor precision and a high limit of detection (0.5±1μg phosphorus mL(-1)). Furthermore this method cannot provide speciation information, which is critical for developing an understanding of the challenge of alkyl phosphates at a molecular level. An approach using comprehensive two-dimensional gas chromatography with nitrogen phosphorus detection (GC×GC-NPD) and post-column Deans switching is presented. This method provides qualitative and quantitative profiles of alkyl phosphates in industrial petroleum samples with increased precision and at levels comparable to or below those achievable by ICP-OES. A recovery study in a fracturing fluid sample and a profiling study of alkyl phosphates in four recovered fracturing fluid/crude oil mixtures (flowback) are also presented.
In-plane anisotropy in two-dimensional electron gas at LaAlO3/SrTiO3(110) interface
Sheng-Chun, Shen; Yan-Peng, Hong; Cheng-Jian, Li; Hong-Xia, Xue; Xin-Xin, Wang; Jia-Cai, Nie
2016-07-01
A systematic study of the two-dimensional electron gas at LaAlO3/SrTiO3(110) interface reveals an anisotropy along two specific directions, [001] and . The anisotropy becomes distinct for the interface prepared under high oxygen pressure with low carrier density. Angular dependence of magnetoresistance shows that the electron confinement is stronger along the direction. Gate-tunable magnetoresistance reveals a clear in-plane anisotropy of the spin-orbit coupling, and the spin relaxation mechanism along both directions belongs to D’yakonov-Perel’ (DP) scenario. Moreover, in-plane anisotropic superconductivity is observed for the sample with high carrier density, the superconducting transition temperature is lower but the upper critical field is higher along the direction. This in-plane anisotropy could be ascribed to the anisotropic band structure along the two crystallographic directions. Project supported by the Ministry of Science and Technology of China (Grant Nos. 2013CB921701, 2013CBA01603, and 2014CB920903), the National Natural Science Foundation of China (Grant Nos. 10974019, 51172029, 91121012, 11422430, 11374035, 11474022, and 11474024), the Program for New Century Excellent Talents in the University of the Ministry of Education of China (Grant No. NCET-13-0054), and the Beijing Higher Education Young Elite Teacher Project, China (Grant No. YETP0238).
Egert, Björn; Weinert, Christoph H; Kulling, Sabine E
2015-07-31
Comprehensive two-dimensional gas chromatography mass spectrometry (GC×GC-MS) is a well-established key technology in analytical chemistry and increasingly used in the field of untargeted metabolomics. However, automated processing of large GC×GC-MS data sets is still a major bottleneck in untargeted, large-scale metabolomics. For this reason we introduce a novel peaklet-based alignment strategy. The algorithm is capable of an untargeted deterministic alignment exploiting a density based clustering procedure within a time constrained similarity matrix. Exploiting minimal (1)D and (2)D retention time shifts between peak modulations, the alignment is done without the need for peak merging which also eliminates the need for linear or nonlinear retention time correction procedures. The approach is validated in detail using data of urine samples from a large human metabolomics study. The data was acquired by a Shimadzu GCMS-QP2010 Ultra GC×GC-qMS system and consists of 512 runs, including 312 study samples and 178 quality control sample injections, measured within a time period of 22 days. The final result table consisted of 313 analytes, each of these being detectable in at least 75% of the study samples. In summary, we present an automated, reliable and fully transparent workflow for the analysis of large GC×GC-qMS metabolomics data sets.
Zhang, Cheng; Ingram, Isaiah C; Hantao, Leandro W; Anderson, Jared L
2015-03-20
A series of dicationic ionic liquid (IL)-based stationary phases were evaluated as secondary columns in comprehensive two-dimensional gas chromatography (GC×GC) for the separation of aliphatic hydrocarbons from kerosene. In order to understand the role that structural features of ILs play on the selectivity of nonpolar analytes, the solvation parameter model was used to probe the solvation properties of the IL-based stationary phases. It was observed that room temperature ILs containing long free alkyl side chain substituents and long linker chains between the two cations possess less cohesive forces and exhibited the highest resolution of aliphatic hydrocarbons. The anion component of the IL did not contribute significantly to the overall separation, as similar selectivities toward aliphatic hydrocarbons were observed when examining ILs with identical cations and different anions. In an attempt to further examine the separation capabilities of the IL-based GC stationary phases, columns of the best performing stationary phases were prepared with higher film thickness and resulted in enhanced selectivity of aliphatic hydrocarbons.
Nahar, Limon Khatun; Andrews, Rebecca; Paterson, Sue
2015-09-01
A highly sensitive and fully validated method was developed for the quantification of buprenorphine in postmortem blood. After a two-step protein precipitation process using acetonitrile, buprenorphine was purified using mixed-mode (C8/cation exchange) solid-phase extraction cartridges. Endogenous water-soluble compounds and lipids were removed from the cartridges before the samples were eluted, concentrated and derivatized using N-methyl-N-trimethylsilyltrifluoroacetamide. The samples were analyzed using two-dimensional gas chromatography-mass spectrometry (2D GC-MS) in selective ion-monitoring mode. A low polarity Rxi(®)-5MS (30 m × 0.25 mm I.D. × 0.25 µm) was used as the primary column and the secondary column was a mid-polarity Rxi(®) -17Sil MS (15 m × 0.32 mm I.D. × 0.25 µm). The assay was linear from 1.0 to 50.0 ng/mL (r(2) > 0.99; n = 6). Intraday (n = 6) and interday (n = 9) imprecisions (percentage relative standard deviation, % RSD) were selective with no interference from endogenous compounds or from 62 commonly encountered drugs. To prove method applicability to forensic postmortem cases, 14 authentic postmortem blood samples were analyzed.
Cajka, Tomás; Hajslová, Jana; Cochran, Jack; Holadová, Katerina; Klimánková, Eva
2007-03-01
Head-space solid phase microextration (SPME), followed by comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry (GCxGC-TOFMS), has been implemented for the analysis of honey volatiles, with emphasis on the optimal selection of SPME fibre and the first- and second-dimension GC capillaries. From seven SPME fibres investigated, a divinylbenzene/Carboxen/polydimethylsiloxane (DVB/CAR/PDMS) 50/30 microm fibre provided the best sorption capacity and the broadest range of volatiles extracted from the headspace of a mixed honey sample. A combination of DB-5ms x SUPELCOWAX 10 columns enabled the best resolution of sample components compared to the other two tested column configurations. Employing this powerful analytical strategy led to the identification of 164 volatile compounds present in a honey mixture during a 19-min GC run. Combination of this simple and inexpensive SPME-based sampling/concentration technique with the advanced separation/identification approach represented by GCxGC-TOFMS allows a rapid and comprehensive examination of the honey volatiles profile. In this way, the laboratory sample throughput can be increased significantly and, at the same time, the risk of erroneous identification, which cannot be avoided in one-dimensional GC separation, is minimised.
Muscalu, Alina M; Morse, Dave; Reiner, Eric J; Górecki, Tadeusz
2017-03-01
The analysis of persistent organic pollutants in environmental samples is a challenge due to the very large number of compounds with varying chemical and physical properties. Chlorinated paraffins (CPs) are complex mixtures of chlorinated n-alkanes with varying chain lengths (C10 to C30) and degree of chlorination (30 to 70% by weight). Their physical-chemical properties make these compounds persistent in the environment and able to bioaccumulate in living organisms. Comprehensive two-dimensional gas chromatography (GC × GC) coupled with micro-electron capture detection (μECD) was used to separate and quantify short-chain chlorinated paraffins (SCCP) in sediment samples. Distinct ordered bands were observed in the GC × GC chromatograms pointing to group separation. Using the Classification function of the ChromaTOF software, summary tables were generated to determine total area counts to set up multilevel-calibration curves for different technical mixes. Fortified sediment samples were analyzed by GC × GC-μECD with minimal extraction and cleanup. Recoveries ranged from 120 to 130%. To further validate the proposed method for the analysis of SCCPs, the laboratory participated in interlaboratory studies for the analysis of standards and sediment samples. The results showed recoveries between 75 and 95% and z-score values <2, demonstrating that the method is suitable for the analysis of SCCPs in soil/sediment samples. Graphical abstract Quantification of SCCPs by 2D-GC-μECD.
Antle, Patrick M; Zeigler, Christian D; Livitz, Dimitri G; Robbat, Albert
2014-10-17
Local conditions influence how pollutants will weather in subsurface environments and sediment, and many of the processes that comprise environmental weathering are dependent upon these substances' physical and chemical properties. For example, the effects of dissolution, evaporation, and organic phase partitioning can be related to the aqueous solubility (SW), vapor pressure (VP), and octanol-water partition coefficient (KOW), respectively. This study outlines a novel approach for estimating these physical properties from comprehensive two-dimensional gas chromatography-mass spectrometry (GC×GC/MS) retention index-based polyparameter linear free energy relationships (LFERs). Key to robust correlation between GC measurements and physical properties is the accurate and precise generation of retention indices. Our model, which employs isovolatility curves to calculate retention indices, provides improved retention measurement accuracy for families of homologous compounds and leads to better estimates of their physical properties. Results indicate that the physical property estimates produced from this approach have the same error on a logarithmic-linear scale as previous researchers' log-log estimates, yielding a markedly improved model. The model was embedded into a new software program, allowing for automated determination of these properties from a single GC×GC analysis with minimal model training and parameter input. This process produces component maps that can be used to discern the mechanism and progression of how a particular site weathers due to dissolution, organic phase partitioning, and evaporation into the surrounding environment.
Energy Technology Data Exchange (ETDEWEB)
Kwack, H.S.; Cho, Y.H. [Department of Physics and Institute for Basic Science Research, Chungbuk National University, Cheongju 361-763 (Korea); Kim, G.H. [School of Information and Communication Engineering, Sungkyunkwan University, Suwon 440-746 (Korea); Park, M.R.; Youn, D.H.; Bae, S.B.; Lee, K.S. [Basic Research Laboratory, Electronics and Telecommunications Research Institute, Daejeon 305-350 (Korea); Lee, J.H.; Lee, J.H. [Department of Electric and Electronic Engineering, Kyungpook National University, Taegu 702-701 (Korea)
2006-06-15
The structural and optical properties of undoped AlGaN/GaN single heterojunctions (HJs) were studied by means of high-resolution x-ray diffraction, photoluminescence (PL), cathodoluminescence (CL), and time-resolved PL spectroscopy. An additional two-dimensional electron gas (2DEG)-related PL and CL emission appeared at about 40 meV below the GaN band-edge emission energy and persisted up to about 100 K, while this peak disappeared when the top AlGaN layer was removed by reactive ion etching. Depth-resolved CL spectra reveal the presence of a 2DEG at the heterointerface. The additional PL and CL emission below the GaN band-edge emission is attributed to the recombination between photogenerated holes and electrons confined at 2DEG states in the triangular-shaped interface potential. For the 2DEG emission, we observed an about 50-ps delayed rise time than the GaN and AlGaN emissions by using time-resolved PL, indicating effective carrier transfer from the GaN flatband and AlGaN regions to the heterointerface. From the results, we explained the optical properties and carrier recombination dynamics of 2DEG, GaN, and AlGaN emissions in undoped AlGaN/GaN single HJs. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Kwack, H. S.; Cho, Y. H.; Kim, G. H.; Park, M. R.; Youn, D. H.; Bae, S. B.; Lee, K.-S.; Lee, J. H.; Lee, J. H.
2006-06-01
The strucutral and optical properties of undoped AlGaN/GaN single heterojunctions (HJs) were studied by means of high-resolution x-ray diffraction, photoluminescence (PL), cathodoluminescence (CL), and time-resolved PL spectroscopy. An additional two-dimensional electron gas (2DEG)-related PL and CL emission appeared at about 40 meV below the GaN band-edge emission energy and persisted up to about 100 K, while this peak disappeared when the top AlGaN layer was removed by reactive ion etching. Depth-resolved CL spectra reveal the presence of a 2DEG at the heterointerface. The additional PL and CL emission below the GaN band-edge emission is attributed to the recombination between photogenerated holes and electrons confined at 2DEG states in the triangular-shaped interface potential. For the 2DEG emission, we observed an about 50-ps delayed rise time than the GaN and AlGaN emissions by using time-resolved PL, indicating effective carrier transfer from the GaN flatband and AlGaN regions to the heterointerface. From the results, we explained the optical properties and carrier recombination dynamics of 2DEG, GaN, and AlGaN emissions in undoped AlGaN/GaN single HJs.
Energy Technology Data Exchange (ETDEWEB)
Zhu, Rui, E-mail: rzhu@scut.edu.cn; Dai, Jiao-Hua [Department of Physics, South China University of Technology, Guangzhou 510641 (China); Guo, Yong [Department of Physics and State Key Laboratory of Low-Dimensional Quantum Physics, Tsinghua University, Beijing 100084 (China); Collaborative Innovation Center of Quantum Matter, Beijing (China)
2015-04-28
Interference between different quantum paths can generate Fano resonance. One of the examples is transport through a quasibound state driven by a time-dependent scattering potential. Previously it is found that Fano resonance occurs as a result of energy matching in one-dimensional systems. In this work, we demonstrate that when transverse motion is present, Fano resonance occurs precisely at the wavevector matching situation. Using the Floquet scattering theory, we considered the transport properties of a nonadiabatic time-dependent well both in a two-dimensional electron gas and monolayer graphene structure. Dispersion of the quasibound state of a static quantum well is obtained with transverse motion present. We found that Fano resonance occurs when the wavevector in the transport direction of one of the Floquet sidebands is exactly identical to that of the quasibound state in the well at equilibrium and follows the dispersion pattern of the latter. To observe the Fano resonance phenomenon in the transmission spectrum, we also considered the pumped shot noise properties when time and spatial symmetry secures vanishing current in the considered configuration. Prominent Fano resonance is found in the differential pumped shot noise with respect to the reservoir Fermi energy.
Nishio, Yui; Tange, Takahiro; Hirayama, Naomi; Iida, Tsutomu; Takanashi, Yoshifumi
2014-01-01
The energy states of a two-dimensional electron gas (2DEG) in high-electron-mobility transistors with a pseudomorphically strained InAs channel (PHEMTs) were analyzed rigorously using a recently established theory that takes into account the nonparabolicity of the conduction band of the channel layer. The sheet density of the 2DEG in InxGa1-xAs-PHEMTs and the drain I-V characteristics of those devices were calculated theoretically and compared with the density and characteristics obtained experimentally. Not only the calculated threshold voltage (VTH) but also the calculated transconductance agreed fairly well with the corresponding values obtained experimentally. When the effects of the compositions of the InxGa1-xAs subchannel layer in the composite channel and the channel layer on energy states of 2DEG were investigated in order to establish a guiding principle for a design of the channel structure in PHEMTs, it was found that VTH is determined by the effective conduction-band offset energy ΔEC between the InAlAs barrier and the channel layers.
Zoccali, Mariosimone; Tranchida, Peter Quinto; Mondello, Luigi
2015-02-03
The present contribution is focused on the on-line combination of high performance liquid chromatography (HPLC), cryogenically modulated comprehensive two-dimensional gas chromatography (GC × GC), and triple quadrupole mass spectrometry (QqQ MS), generating a very powerful unified separation-science tool. The instrument can be used in seven different combinations ranging from one-dimensional HPLC with a photodiode array detector to on-line LC × GC × GC/QqQ MS. The main focus of the present research is directed to the LC-GC × GC/QqQ MS configuration, with its analytical potential shown in a proof-of-principle study involving a very complex sample, namely, coal tar. Specifically, a normal-phase LC process enabled the separation of three classes of coal tar compounds: (1) nonaromatic hydrocarbons; (2) unsaturated compounds (with and without S); (3) oxygenated constituents. The HPLC fractions were transferred to the GC × GC instrument via a syringe-based interface mounted on an autosampler. Each fraction was subjected to a specific programmed temperature vaporizer GC × GC/QqQ MS untargeted or targeted analysis. For example, the coal tar S-containing compounds were pinpointed through multiple-reaction-monitoring analysis, while full-scan information was attained for the oxygenated constituents.
Energy Technology Data Exchange (ETDEWEB)
Mishra, Manna Kumari [Solid State Physics Laboratory, Lucknow Road, Timarpur, Delhi-110054 (India); Netaji Subhas Institute of Technology, Dwarka, New Delhi-110078 (India); Sharma, Rajesh K., E-mail: rksharma@sspl.drdo.in; Manchanda, Rachna; Bag, Rajesh K.; Muralidharan, Rangarajan [Solid State Physics Laboratory, Lucknow Road, Timarpur, Delhi-110054 (India); Thakur, Om Prakash [Netaji Subhas Institute of Technology, Dwarka, New Delhi-110078 (India)
2014-09-15
Magnetotransport in two distinct AlGaN/GaN HEMT structures grown by Molecular Beam Epitaxy (MBE) on Fe-doped templates is investigated using Shubnikov de-Haas Oscillations in the temperature range of 1.8–6 K and multicarrier fitting in the temperature range of 1.8–300 K. The temperature dependence of the two dimensional electron gas mobility is extracted from simultaneous multicarrier fitting of transverse and longitudinal resistivity as a function of magnetic field and the data is utilized to estimate contribution of interface roughness to the mobility and the corresponding transport lifetime. The quantum scattering time obtained from the analysis of Shubnikov de Haas Oscillations in transverse magnetoresistance along with the transport lifetime time were used to estimate interface roughness amplitude and lateral correlation length. The results indicate that the insertion of AlN over layer deposited prior to the growth of GaN base layer on Fe doped GaN templates for forming HEMT structures reduced the parallel conduction but resulted in an increase in interface roughness.
Directory of Open Access Journals (Sweden)
Manna Kumari Mishra
2014-09-01
Full Text Available Magnetotransport in two distinct AlGaN/GaN HEMT structures grown by Molecular Beam Epitaxy (MBE on Fe-doped templates is investigated using Shubnikov de-Haas Oscillations in the temperature range of 1.8–6 K and multicarrier fitting in the temperature range of 1.8–300 K. The temperature dependence of the two dimensional electron gas mobility is extracted from simultaneous multicarrier fitting of transverse and longitudinal resistivity as a function of magnetic field and the data is utilized to estimate contribution of interface roughness to the mobility and the corresponding transport lifetime. The quantum scattering time obtained from the analysis of Shubnikov de Haas Oscillations in transverse magnetoresistance along with the transport lifetime time were used to estimate interface roughness amplitude and lateral correlation length. The results indicate that the insertion of AlN over layer deposited prior to the growth of GaN base layer on Fe doped GaN templates for forming HEMT structures reduced the parallel conduction but resulted in an increase in interface roughness.
Wu, Qingyun; Shen, Lei; Yang, Ming; Zhou, Jun; Chen, Jingsheng; Feng, Yuan Ping
2016-10-01
Using first-principles calculations, we investigate the tunneling electroresistance (TER) of ferroelectric tunnel junctions [Pt /BaTiO3(BTO)/SrTiO3(STO )/Pt ]. It is found that the TER of Pt/BTO/STO/Pt junctions can be greatly increased with increasing thickness of STO layers. The underlying physics of this giant TER is the switchable two-dimensional electron gas (2DEG) at a nonpolar BTO/STO interface induced by the ferroelectric polarization. Our calculations show that when the ferroelectric polarization is pointing from BTO to STO, a 2DEG forms at the interface and acts as bridge for electrons to tunnel through the junctions. Nevertheless, there is no 2DEG at the interface under the opposite direction of the ferroelectric polarization, which results in a large tunnel resistance. More importantly, this ferroelectrically switchable 2DEG leads to a low resistance area product for Pt/BTO/STO/Pt junctions, which offers good compatibility with other components in an integrated circuit and is highly desired for industrial applications.
Institute of Scientific and Technical Information of China (English)
Petr Lacina; Ludmila Mravcová; Milada Vávrová
2013-01-01
Pharmaceutical residues have become tightly controlled environmental contaminants in recent years,due to their increasing concentration in environmental components.This is mainly caused by their high level of production and everyday consumption.Therefore there is a need to apply new and sufficiently sensitive analytical methods,which can detect the presence of these contaminants even in very low concentrations.This study is focused on the application of a reliable analytical method for the analysis of 10 selected drug residues,mainly from the group of non-steroidal anti-iaffammatory drugs (salicylic acid,acetylsalicylic acid,clofibric acid,ibuprofen,acetaminophen,caffeine,naproxen,mefenamic acid,ketoprofen,and dicofenac),in wastewaters and surface waters.This analytical method is based on solid phase extraction,derivatization by N-methyl-N-(trimethylsilyl)trifluoroacetamide (MSTFA) and finally analysis by comprehensive two-dimensional gas chromatography with Time-of-Flight mass spectrometric detection (GCxGC-TOF MS).Detection limits ranged from 0.18 to 5 ng/L depending on the compound and selected matrix.The method was successfully applied for detection of the presence of selected pharmaceuticals in the Svratka River and in wastewater from the wastewater treatment plant in Brno-Modrice,Czech Republic.The concentration of pharmaceuticals varied from one to several hundreds of ng/L in surface water and from one to several tens of μg/L in wastewater.
Ntlhokwe, Gaalebalwe; Tredoux, Andreas G J; Górecki, Tadeusz; Edwards, Matthew; Vestner, Jochen; Muller, Magdalena; Erasmus, Lené; Joubert, Elizabeth; Christel Cronje, J; de Villiers, André
2017-07-01
The applicability of comprehensive two-dimensional gas chromatography (GC×GC) using a single-stage thermal modulator was explored for the analysis of honeybush tea (Cyclopia spp.) volatile compounds. Headspace solid phase micro-extraction (HS-SPME) was used in combination with GC×GC separation on a non-polar × polar column set with flame ionisation (FID) detection for the analysis of fermented Cyclopia maculata, Cyclopia subternata and Cyclopia genistoides tea infusions of a single harvest season. Method optimisation entailed evaluation of the effects of several experimental parameters on the performance of the modulator, the choice of columns in both dimensions, as well as the HS-SPME extraction fibre. Eighty-four volatile compounds were identified by co-injection of reference standards. Principal component analysis (PCA) showed clear differentiation between the species based on their volatile profiles. Due to the highly reproducible separations obtained using the single-stage thermal modulator, multivariate data analysis was simplified. The results demonstrate both the complexity of honeybush volatile profiles and the potential of GC×GC separation in combination with suitable data analysis techniques for the investigation of the relationship between sensory properties and volatile composition of these products. The developed method therefore offers a fast and inexpensive methodology for the profiling of honeybush tea volatiles. Graphical abstract Surface plot obtained for the GC×GC-FID analysis of honeybush tea volatiles.
Study of phase separation using liquid-gas model of lattice-gas cellular automata
Energy Technology Data Exchange (ETDEWEB)
Ebihara, Kenichi; Watanabe, Tadashi; Kaburaki, Hideo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment
1997-07-01
This report describes the study of phase separation by the liquid gas model of lattice gas cellular automata. The lattice gas cellular automaton is one model for simulating fluid phenomena which was proposed by Frisch, Hasslacher and Pomeau in 1986. In 1990, Appert and Zaleski added a new long-range interaction to lattice gas cellular automata to construct a model, the liquid-gas model, which could simulate phase separation using lattice-gas cellular automata. Gerits et al formulated the liquid-gas model mathematically using the theory of statistical dynamics in 1993 and explained the mechanism of phase separation in the liquid-gas model using the equation of state. At first this report explains the FHP model of lattice gas cellular automata and derives fluid dynamics equations such as the equation of continuity and the Navier-Stokes equation. Then the equation of state for the liquid-gas model which was derived by Gerits et al is modified by adding the interactions which were proposed by Appert but not considered by Gerits et al. The modified equation of state is verified by the computer simulation using the liquid gas model. The relation between phase separation and the equation of state is discussed. (author)
Gauchotte-Lindsay, Caroline; McGregor, Laura; Richards, Phil; Kerr, Stephanie; Glenn, Aliyssa; Thomas, Russell; Kalin, Robert
2013-04-01
Comprehensive two-dimensional gas chromatography (GCxGC) is a recently developed analytical technique in which two capillary columns with different stationary phases are placed in series enabling planar resolution of the analytes. The resolution power of GCxGC is one order of magnitude higher than that of one dimension gas chromatography. Because of its high resolution capacity, the use of GCxGC for complex environmental samples such as crude oils, petroleum derivatives and polychlorinated biphenyls mixtures has rapidly grown in recent years. We developed a one-step method for the forensic analysis of coal tar dense non-aqueous phase liquids (DNAPLs) from former manufactured gas plant (FMGP) sites. Coal tar is the by-product of the gasification of coal for heating and lighting and it is composed of thousands of organic and inorganic compounds. Before the boom of natural gases and oils, most towns and cities had one or several manufactured gas plants that have, in many cases, left a devastating environmental print due to coal tar contamination. The fate of coal tar DNAPLs, which can persist in the environment for more than a hundred years, is therefore of crucial interest. The presented analytical method consists of a unique clean-up/ extraction stage by pressurized liquid extraction and a single analysis of its organic chemical composition using GCxGC coupled with time of flight mass spectrometry (TOFMS). The chemical fingerprinting is further improved by derivatisation by N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA) of the tar compounds containing -OH functions such as alcohols and carboxylic acids. We present here how, using the logical order of elution in GCxGC-TOFMS system, 1) the identification of never before observed -OH containing compounds is possible and 2) the isomeric selectivity of an oxidation reaction on a DNAPL sample can be revealed. Using samples collected at various FMGP sites, we demonstrate how this GCxGC method enables the simultaneous
Osserman, Robert
2011-01-01
The basic component of several-variable calculus, two-dimensional calculus is vital to mastery of the broader field. This extensive treatment of the subject offers the advantage of a thorough integration of linear algebra and materials, which aids readers in the development of geometric intuition. An introductory chapter presents background information on vectors in the plane, plane curves, and functions of two variables. Subsequent chapters address differentiation, transformations, and integration. Each chapter concludes with problem sets, and answers to selected exercises appear at the end o
Juday, Richard D. (Inventor)
1992-01-01
A two-dimensional vernier scale is disclosed utilizing a cartesian grid on one plate member with a polar grid on an overlying transparent plate member. The polar grid has multiple concentric circles at a fractional spacing of the spacing of the cartesian grid lines. By locating the center of the polar grid on a location on the cartesian grid, interpolation can be made of both the X and Y fractional relationship to the cartesian grid by noting which circles coincide with a cartesian grid line for the X and Y direction.
Damage spreading in a driven lattice gas model
Rubio Puzzo, M. Leticia; Saracco, Gustavo P.; Albano, Ezequiel V.
2013-06-01
We studied damage spreading in a Driven Lattice Gas (DLG) model as a function of the temperature T, the magnitude of the external driving field E, and the lattice size. The DLG model undergoes an order-disorder second-order phase transition at the critical temperature Tc(E), such that the ordered phase is characterized by high-density strips running along the direction of the applied field; while in the disordered phase one has a lattice-gas-like behavior. It is found that the damage always spreads for all the investigated temperatures and reaches a saturation value D that depends only on T. D increases for TTc(E=∞) and is free of finite-size effects. This behavior can be explained as due to the existence of interfaces between the high-density strips and the lattice-gas-like phase whose roughness depends on T. Also, we investigated damage spreading for a range of finite fields as a function of T, finding a behavior similar to that of the case with E=∞.
Fick's Law in a Random Lattice Lorentz Gas
Lefevere, Raphaël
2015-06-01
We provide a proof that the stationary macroscopic current of particles in a random lattice Lorentz gas satisfies Fick's law when connected to particles reservoirs. We consider a box on a d + 1-dimensional lattice and when , we show that under a diffusive rescaling of space and time, the probability of finding a current different from its stationary value is exponentially small in time. Its stationary value is given by the conductivity times the difference of chemical potentials of the reservoirs. The proof is based on the fact that in a high dimension, random walks have a small probability of making loops or intersecting each other when starting sufficiently far apart.
Zhang, Cheng; Park, Rodney A; Anderson, Jared L
2016-04-01
Structurally-tuned ionic liquids (ILs) have been previously applied as the second dimension column in comprehensive two-dimensional gas chromatography (GC×GC) and have demonstrated high selectivity in the separation of individual aliphatic hydrocarbons from other aliphatic hydrocarbons. However, the maximum operating temperatures of these stationary phases limit the separation of analytes with high boiling points. In order to address this issue, a series of polymeric ionic liquid (PIL)-based stationary phases were prepared in this study using imidazolium-based IL monomers via in-column free radical polymerization. The IL monomers were functionalized with long alkyl chain substituents to provide the needed selectivity for the separation of aliphatic hydrocarbons. Columns were prepared with different film thicknesses to identify the best performing stationary phase for the separation of kerosene. The bis[(trifluoromethyl)sulfonyl]imide ([NTf2](-))-based PIL stationary phase with larger film thickness (0.28μm) exhibited higher selectivity for aliphatic hydrocarbons and showed a maximum allowable operating temperature of 300°C. PIL-based stationary phases containing varied amount of IL-based crosslinker were prepared to study the effect of the crosslinker on the selectivity and thermal stability of the resulting stationary phase. The optimal resolution of aliphatic hydrocarbons was achieved when 50% (w/w) of crosslinker was incorporated into the PIL-based stationary phase. The resulting stationary phase exhibited good selectivity for different groups of aliphatic hydrocarbons even after being conditioned at 325°C. Finally, the crosslinked PIL-based stationary phase was compared with SUPELCOWAX 10 and DB-17 columns for the separation of aliphatic hydrocarbons in diesel fuel. Better resolution of aliphatic hydrocarbons was obtained when employing the crosslinked PIL-based stationary phase as the second dimension column.
Energy Technology Data Exchange (ETDEWEB)
Hoggard, Jamin C.; Wahl, Jon H.; Synovec, Robert E.; Mong, Gary M.; Fraga, Carlos G.
2010-01-15
In this work we present the feasibility of using analytical chemical and chemometric methodologies to reveal and exploit the organic impurity profiles from commercial dimethyl methylphosphonate (DMMP) samples to illustrate the type of forensic information that may be obtained from chemical-attack evidence. Using DMMP as a model compound for a toxicant that may be used in a chemical attack, we used comprehensive two-dimensional gas chromatography mass spectrometric detection (GC × GC-TOFMS) to detect and identify trace organic impurities in six samples of commercially acquired DMMP. The GC x GC-TOFMS data were analyzed to produce impurity profiles for all six DMMP samples using 29 analyte impurities. The use of PARAFAC for the mathematical resolution of overlap GC x GC peaks ensured clean spectra for the identification of many of the detected analytes by spectral library matching. The use of statistical pairwise comparison revealed that there were trace impurities that were quantitatively similar and different among five of the six DMMP samples. Two of the DMMP samples were revealed to have identical impurity profiles by this approach. The use of nonnegative matrix factorization proved that there were five distinct DMMP sample types as illustrated by the clustering of the multiple DMMP analyses into 5 distinct clusters in the scores plots. The two indistinguishable DMMP samples were confirmed by their chemical supplier to be from the same bulk source. Sample information from the other chemical suppliers supported that the other five DMMP samples were likely from different bulk sources. These results demonstrate that the matching of synthesized products from the same source is possible using impurity profiling. In addition, the identified impurities common to all six DMMP samples provide strong evidence that basic route information can be obtained from impurity profiles. In addition, impurities that may be unique to the sole bulk manufacturer of DMMP were found in
Freye, Chris E; Fitz, Brian D; Billingsley, Matthew C; Synovec, Robert E
2016-06-01
The chemical composition and several physical properties of RP-1 fuels were studied using comprehensive two-dimensional (2D) gas chromatography (GC×GC) coupled with flame ionization detection (FID). A "reversed column" GC×GC configuration was implemented with a RTX-wax column on the first dimension ((1)D), and a RTX-1 as the second dimension ((2)D). Modulation was achieved using a high temperature diaphragm valve mounted directly in the oven. Using leave-one-out cross-validation (LOOCV), the summed GC×GC-FID signal of three compound-class selective 2D regions (alkanes, cycloalkanes, and aromatics) was regressed against previously measured ASTM derived values for these compound classes, yielding root mean square errors of cross validation (RMSECV) of 0.855, 0.734, and 0.530mass%, respectively. For comparison, using partial least squares (PLS) analysis with LOOCV, the GC×GC-FID signal of the entire 2D separations was regressed against the same ASTM values, yielding a linear trend for the three compound classes (alkanes, cycloalkanes, and aromatics), yielding RMSECV values of 1.52, 2.76, and 0.945 mass%, respectively. Additionally, a more detailed PLS analysis was undertaken of the compounds classes (n-alkanes, iso-alkanes, mono-, di-, and tri-cycloalkanes, and aromatics), and of physical properties previously determined by ASTM methods (such as net heat of combustion, hydrogen content, density, kinematic viscosity, sustained boiling temperature and vapor rise temperature). Results from these PLS studies using the relatively simple to use and inexpensive GC×GC-FID instrumental platform are compared to previously reported results using the GC×GC-TOFMS instrumental platform.
Energy Technology Data Exchange (ETDEWEB)
Umana-Membreno, G.A.; Dell, J.M.; Parish, G.; Nener, B.D.; Faraone, L. [School of Electrical, Electronic and Computer Engineering, The University ofWestern Australia, Crawley WA 6009 (Australia); Ventury, R.; Mishra, U.K. [Dept. of Electrical and Computer Engineering, University of California, Santa Barbara, CA 93106 (United States)
2005-05-01
The effect of {sup 60}Co gamma-irradiation on Al{sub 0.33}Ga{sub 0.67}N/GaN high-electron-mobility transistors (HEMTs) has been investigated using DC and geometrical magnetoresistance measurements. The devices studied were of similar epitaxial structure, yet differed in the doping levels of the Al{sub 0.33}Ga{sub 0.67}N barrier layer: (A) nominally undoped and (B) Si-doped with SiN{sub x} passivation. Exposure to cumulative gamma-ray doses up to 20 Mrad(Si) is shown to induce significant changes in drain-current level, threshold voltage and gate leakage current level. Analysis of magnetoresistance characteristics measured at 80 K indicated that irradiation induced an increase in two-dimensional electron-gas (2DEG) density, which leads to negative threshold voltage shifts observable in the drain current versus gate voltage characteristics, attributable to the introduction of defect centers in the Al{sub 0.33}Ga{sub 0.67}N layer and/or at the gate-AlGaN interface. The 2DEG mobility-concentration profiles are shown to remain approximately unchanged for doses up to 20 Mrad(Si). Device failure, evidenced as loss of gate control over the channel and/or excessive gate leakage, occurred after exposure to 30 Mrad(Si) for device A, whereas sample B failed after 20 Mrad(Si) total dose due to failure of half of the gate contact. Degradation of gate and source/drain contacts characteristics with total dose appears to limit the tolerance of the studied HEMTs to {sup 60}Co gamma-irradiation. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Xia, Dan; Gao, Lirong; Zhu, Shuai; Zheng, Minghui
2014-11-01
Short-chain chlorinated paraffins (SCCPs) are highly complex technical mixtures with thousands of isomers and numerous homologs. They are classified as priority candidate persistent organic pollutants under the Stockholm Convention for their persistence, bioaccumulation, and toxicity. Analyzing SCCPs is challenging because of the complexity of the mixtures. Chromatograms of SCCPs acquired using one-dimensional (1D) gas chromatography (GC) contain a large characteristic "peak" with a broad and unresolved profile. Comprehensive two-dimensional GC (GC×GC) shows excellent potential for separating complex mixtures. In this study, GC×GC coupled with micro electron capture detection (μECD) was used to separate and screen SCCPs. The chromatographic parameters, including the GC column types, oven temperature program, and modulation period, were systematically optimized. The SCCP congeners were separated into groups using a DM-1 column connected to a BPX-50 column. The SCCP congeners in technical mixtures were separated according to the number of chlorine substituents for a given carbon chain length and according to the number of carbon atoms plus chlorine atoms for different carbon chain lengths. A fish tissue sample was analyzed to illustrate the feasibility of the GC×GC-μECD method in analyzing biological samples. Over 1,500 compounds were identified in the fish extract, significantly more than were identified using 1D GC. The detection limits for five selected SCCP congeners were between 1 and 5 pg/L using the GC×GC method, and these were significantly lower than those achieved using 1D GC. This method is a good choice for analysis of SCCPs in environmental samples, exhibiting good separation and good sensitivity.
Energy Technology Data Exchange (ETDEWEB)
Kalachova, Kamila; Pulkrabova, Jana; Cajka, Tomas; Drabova, Lucie; Hajslova, Jana [Institute of Chemical Technology, Prague (Czech Republic). Department of Food Chemistry and Analysis, Faculty of Food and Biochemical Technology
2012-07-15
In the presented study, comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC x GC-TOFMS) was shown to be a powerful tool for the simultaneous determination of various groups of contaminants including 18 polychlorinated biphenyls (PCBs), seven polybrominated diphenyl ethers (PBDEs), and 16 polycyclic aromatic hydrocarbons (PAHs). Since different groups of analytes (traditionally analyzed separately) were included into one instrumental method, significant time savings were achieved. Following the development of an integrated sample preparation procedure for an effective and rapid isolation of several groups of contaminants from fish tissue, the GC x GC-TOFMS instrumental method was optimized to obtain the best chromatographic resolution and low quantification limits (LOQs) of all target analytes in a complex mixture. Using large-volume programmable temperature vaporization, the following LOQs were achieved - PCBs, 0.01-0.25 {mu}g/kg; PBDEs, 0.025-5 {mu}g/kg; PAHs 0.025-0.5 {mu}g/kg. Furthermore, several capillary column combinations (BPX5, BPX50, and Rxi-17Sil-ms in the first dimension and BPX5, BPX50, Rt-LC35, and HT8 in the second dimension) were tested during the experiments, and the optimal separation of all target analytes even of critical groups of PAHs (group (a): benz[a]anthracene, cyclopenta[cd]pyrene and chrysene; group (b): benzo[b]fluoranthene, benzo[j]fluoranthene and benzo[k]fluoranthene; group (c): dibenz[ah]anthracene, indeno[1,2,3-cd]pyrene and benzo[ghi]perylene) was observed on BPX5 x BPX50 column setup. Moreover, since the determination of target analytes was performed using TOFMS detector, further identification of other non-target compounds in real life samples was also feasible. (orig.)
Horii, Yuichi; Kannan, Kurunthachalam; Petrick, Gert; Gamo, Toshitaka; Falandysz, Jerzy; Yamashita, Nobuyoshi
2005-06-01
Analysis of stable carbon isotope fractionation is a useful method to study the sources and fate of anthropogenic organic contaminants such as polychlorinated biphenyls (PCBs) in the environment. To evaluate the utility of carbon isotopes, determination of isotopic ratios of 13C/12C in source materials, for example, technical PCB preparations, is needed. In this study, we determined delta13C values of 31 chlorobiphenyl (CB) congeners in 18 technical PCB preparations and 15 chloronaphthalene (CN) congeners in 6 polychlorinated naphthalene preparations using two-dimensional gas chromatography-combustion furnace-isotope ratio mass spectrometry (2DGC-C-IRMS). Development of 2DGC-IRMS enabled improved resolution and sensitivity of compound-specific carbon isotope analysis (CSIA) of CB or CN congeners. Delta13C values of PCB congeners ranged from -34.4 (Delors) to -22.0/1000 (Sovol). Analogous PCB preparations with similar chlorine content, but different geographical origin, had different delta13C values. PCB preparations from Eastern European countries--Delors, Sovol, Trichlorodiphenyl, and Chlorofen--had distinct delta13C values. PCB mixtures showed increased 13C depletion with increasing chlorine content. Delta13C values for individual CB congeners varied depending on the degree of chlorination in technical mixtures. Delta13C values of CN congeners in Halowaxes ranged from -26.3 to -21.7/1000 and these values are within the ranges observed for PCBs. This study establishes the range of delta13C values in technical PCB and PCN preparations, which may prove to be useful in the determination of sources of these compounds in the environment. This is the first study to employ 2DGC-IRMS analysis of delta13C values in technical PCB and PCN preparations.
Nemšák, S.; Conti, G.; Gray, A. X.; Palsson, G. K.; Conlon, C.; Eiteneer, D.; Keqi, A.; Rattanachata, A.; Saw, A. Y.; Bostwick, A.; Moreschini, L.; Rotenberg, E.; Strocov, V. N.; Kobayashi, M.; Schmitt, T.; Stolte, W.; Ueda, S.; Kobayashi, K.; Gloskovskii, A.; Drube, W.; Jackson, C. A.; Moetakef, P.; Janotti, A.; Bjaalie, L.; Himmetoglu, B.; Van de Walle, C. G.; Borek, S.; Minar, J.; Braun, J.; Ebert, H.; Plucinski, L.; Kortright, J. B.; Schneider, C. M.; Balents, L.; de Groot, F. M. F.; Stemmer, S.; Fadley, C. S.
2016-06-01
The interfaces between two condensed phases often exhibit emergent physical properties that can lead to new physics and novel device applications and are the subject of intense study in many disciplines. We here apply experimental and theoretical techniques to the characterization of one such interesting interface system: the two-dimensional electron gas (2DEG) formed in multilayers consisting of SrTi O3 (STO) and GdTi O3 (GTO). This system has been the subject of multiple studies recently and shown to exhibit very high carrier charge densities and ferromagnetic effects, among other intriguing properties. We have studied a 2DEG-forming multilayer of the form [6unit cells (u .c .) STO /3 u .c .of GTO ] 20 using a unique array of photoemission techniques including soft and hard x-ray excitation, soft x-ray angle-resolved photoemission, core-level spectroscopy, resonant excitation, and standing-wave effects, as well as theoretical calculations of the electronic structure at several levels and of the actual photoemission process. Standing-wave measurements below and above a strong resonance have been exploited as a powerful method for studying the 2DEG depth distribution. We have thus characterized the spatial and momentum properties of this 2DEG in detail, determining via depth-distribution measurements that it is spread throughout the 6 u.c. layer of STO and measuring the momentum dispersion of its states. The experimental results are supported in several ways by theory, leading to a much more complete picture of the nature of this 2DEG and suggesting that oxygen vacancies are not the origin of it. Similar multitechnique photoemission studies of such states at buried interfaces, combined with comparable theory, will be a very fruitful future approach for exploring and modifying the fascinating world of buried-interface physics and chemistry.