Comparisons of the nanoparticle emission characteristics between GDI and PFI vehicles

Energy Technology Data Exchange (ETDEWEB)

Jang, Jihwan [Graduate School of Hanyang University (Korea, Republic of); Lee, Jongtae; Kim, Jeongsoo [National Institute of Environmental Research (Korea, Republic of); Park, Sungwook, E-mail: parks@hanyang.ac.kr [Hanyang University, School of Mechanical Engineering (Korea, Republic of)

2015-12-15

To compare the particle emissions of gasoline direct injection (GDI) and port fuel injection (PFI) vehicles in this study, the particulate matter of exhaust emissions was sampled from a constant volume sampler tunnel and tailpipe using a chassis dynamometer. Using the gravimetric method and a condensation particle counter, the particulate matter mass (PM) and particle number (PN) of the particle size according to the current regulations were measured. Nanometer-sized particle emissions, which are smaller than regulated particle emissions, were measured by an engine exhaust particle sizer. Four test vehicles, which included two GDI vehicles and two PFI vehicles, were tested in various driving modes. The test results show that the particle emissions from the GDI vehicles were higher than the particle emissions from the PFI vehicles. In addition, the test vehicles had the highest emissions in cold start conditions. In the GDI vehicles, the PM and PN satisfied the current regulations but PN did not satisfy the EURO 6c regulations that will be implemented in 2017. In all driving modes, the particle size distribution show that the most common particle size was approximately 50 nm, and the results according to the driving patterns of each mode were confirmed.

Private Finance Initiative (PFI for Road Projects in UK: Current Practice with a Case Study

Directory of Open Access Journals (Sweden)

Rifat Akbiyikli

2011-05-01

Full Text Available The long-term sustainable provision of new and high quality maintained road stock is vitally important, especially in times of economic constraint such as Europe is currently experiencing. The Private Finance Initiative (PFI is one method of financing such large-scale, capital intensive projects. An important aspect of this form of financing projects is that the risks are borne not only by the sponsors but are shared by different types of investors such as equity holders, debt providers, and quasi-equity investors. Consequently, a comprehensive and heuristic risk management process is essential for the success of the project. The proposition made within this paper is that the PFI mechanism provides a Value-for-Money and effective mechanism to achieve this. The structure of this PFI finance and investment on a particular road project therefore enables all project stakeholders to take a long-term perspective. This long-term perspective is reflected in the mechanism of a case study of UK – Class A trunk roads which are examined in detail. This paper presents a novel solution to a modern dilemma.

IR + VUV double resonance spectroscopy and extended density functional theory studies of ketone solvation by alcohol: 2-butanone·(methanol)n, n = 1-4 clusters.

Science.gov (United States)

Shin, Joong-Won; Bernstein, Elliot R

2017-09-28

Infrared plus vacuum ultraviolet (IR + VUV) photoionization vibrational spectroscopy of 2-butanone/methanol clusters [MEK·(MeOH) n , n = 1-4] is performed to explore structures associated with hydrogen bonding of MeOH molecules to the carbonyl functional group of the ketone. IR spectra and X3LYP/6-31++G(d,p) calculations show that multiple isomers of MEK·(MeOH) n are generated in the molecular beam as a result of several hydrogen bonding sites available to the clusters throughout the size range investigated. Isomer interconversion involving solvating MeOH rearrangement should probably occur for n = 1 and 2. The mode energy for a hydrogen bonded OH stretching transition gradually redshifts as the cluster size increases. Calculations suggest that the n = 3 cluster isomers adopt structures in which the MEK molecule is inserted into the cyclic MeOH hydrogen bond network. In larger structures, the cyclic network may be preserved.

The Missing Point Of Knowledge Management in PFI Projects

Directory of Open Access Journals (Sweden)

Kipli Kumalasari

2016-01-01

Full Text Available The Private Finance Initiative (PFI procurement model is a complex system which includes long-term commitment; customers’ satisfaction and through-life collaborative working. The projects based on this type of procurement has start from the year 1992 in the UK and year 2006 in Malaysia. Along the process, the PFI projects face few problems despite its advantages. These problem has effected the projects performance such as delay and cost overruns. It seems that the problems occurred are repeatable despite many types of research delved into solving the issues. This paper seeks, to find out the most common problems occur in PFI projects and highlights the best solution to tackle the problems. It also looks at whether similar problems occur in Malaysian construction industry. This research has summarised and critically review the literature on the repeated issues and problem in PFI projects which effect the performance of the projects in term of time, quality and money. It was found that similar problems occur and that similar suggestions were proposed. This shows that the proposed solutions have weaknesses somewhat and hence need to enhance further. This research highlighted the potential of incorporating knowledge management concept through its elements to address the problems. Finally, the paper proposes recommendations to improve the performance of PFI projects with the enhancement of knowledge management especially at the initial and planning stage up to bidding stage where the problem reviewed in the literature always occurred

Physiological frailty index (PFI): quantitative in-life estimate of individual biological age in mice.

Science.gov (United States)

Antoch, Marina P; Wrobel, Michelle; Kuropatwinski, Karen K; Gitlin, Ilya; Leonova, Katerina I; Toshkov, Ilia; Gleiberman, Anatoli S; Hutson, Alan D; Chernova, Olga B; Gudkov, Andrei V

2017-03-19

The development of healthspan-extending pharmaceuticals requires quantitative estimation of age-related progressive physiological decline. In humans, individual health status can be quantitatively assessed by means of a frailty index (FI), a parameter which reflects the scale of accumulation of age-related deficits. However, adaptation of this methodology to animal models is a challenging task since it includes multiple subjective parameters. Here we report a development of a quantitative non-invasive procedure to estimate biological age of an individual animal by creating physiological frailty index (PFI). We demonstrated the dynamics of PFI increase during chronological aging of male and female NIH Swiss mice. We also demonstrated acceleration of growth of PFI in animals placed on a high fat diet, reflecting aging acceleration by obesity and provide a tool for its quantitative assessment. Additionally, we showed that PFI could reveal anti-aging effect of mTOR inhibitor rapatar (bioavailable formulation of rapamycin) prior to registration of its effects on longevity. PFI revealed substantial sex-related differences in normal chronological aging and in the efficacy of detrimental (high fat diet) or beneficial (rapatar) aging modulatory factors. Together, these data introduce PFI as a reliable, non-invasive, quantitative tool suitable for testing potential anti-aging pharmaceuticals in pre-clinical studies.

Relaxation and excitation electronic processes in dielectrics irradiated by ultrafast IR and VUV pulses; Processus electroniques d'excitation et de relaxation dans les solides dielectriques excites par des impulsions IR et XUV ultracourtes

Energy Technology Data Exchange (ETDEWEB)

Gaudin, J

2005-11-15

We studied excitation and relaxation of electrons involved during interaction of visible and VUV femtosecond pulses with dielectrics. The generated population of hot electrons, having energy of few eV to few tens of eV above the bottom of the conduction band, is responsible of phenomena ranging to defect creation to optical breakdown. Owing to two techniques: photoemission and transient photoconductivity we improve the understanding of the The first photoemission experiments deal with dielectrics irradiated by 30 fs IR pulses. The photoemission spectra measured show a large population of electrons which energy rise up to 40 eV. We interpret this result in terms of a new absorption process: direct multi-photons inter-branch transitions. The 2. type of photoemission experiments are time resolved 'pump/probe' investigation. We study the relaxation of electrons excited by a VUV pulses. We used the high order harmonics (HOH) as light sources. We found surprisingly long decay time in the range of ps timescale. Last type of experiments is photoconductivity studies of diamond samples. Using HOH as light source we measure the displacement current induced by excited electrons in the conduction band. Those electrons relax mainly by impact ionisation creating secondary electrons. Hence by probing the number of electrons we were able to measure the efficiency of these relaxation processes. We observe a diminution of this efficiency when the energy of exciting photons is above 20 eV. Owing to Monte-Carlo simulation we interpret this result in terms of band structure effect. (author)

Rotationally resolved state-to-state photoionization and photoelectron study of titanium carbide and its cation (TiC/TiC⁺).

Science.gov (United States)

Luo, Zhihong; Huang, Huang; Chang, Yih-Chung; Zhang, Zheng; Yin, Qing-Zhu; Ng, C Y

2014-10-14

Titanium carbide and its cation (TiC/TiC(+)) have been investigated by the two-color visible (VIS)-ultraviolet (UV) resonance-enhanced photoionization and pulsed field ionization-photoelectron (PFI-PE) methods. Two visible excitation bands for neutral TiC are observed at 16,446 and 16,930 cm(-1). Based on rotational analyses, these bands are assigned as the respective TiC((3)Π1) ← TiC(X(3)Σ(+)) and TiC((3)Σ(+)) ← TiC(X(3)Σ(+)) transition bands. This assignment supports that the electronic configuration and term symmetry for the neutral TiC ground state are …7σ(2)8σ(1)9σ(1)3π(4) (X(3)Σ(+)). The rotational constant and the corresponding bond distance of TiC(X(3)Σ(+); v″ = 0) are determined to be B0″ = 0.6112(10) cm(-1) and r0″ = 1.695(2) Å, respectively. The rotational analyses of the VIS-UV-PFI-PE spectra for the TiC(+)(X; v(+) = 0 and 1) vibrational bands show that the electronic configuration and term symmetry for the ionic TiC(+) ground state are …7σ(2)8σ(1)3π(4) (X(2)Σ(+)) with the v(+) = 0 → 1 vibrational spacing of 870.0(8) cm(-1) and the rotational constants of B(e)(+) = 0.6322(28) cm(-1), and α(e)(+) = 0.0085(28) cm(-1). The latter rotational constants yield the equilibrium bond distance of r(e)(+) = 1.667(4) Å for TiC(+)(X(2)Σ(+)). The cleanly rotationally resolved VIS-UV-PFI-PE spectra have also provided a highly precise value of 53 200.2(8) cm(-1) [6.5960(1) eV] for the adiabatic ionization energy (IE) of TiC. This IE(TiC) value along with the known IE(Ti) has made possible the determination of the difference between the 0 K bond dissociation energy (D0) of TiC(+)(X(2)Σ(+)) and that of TiC(X(3)Σ(+)) to be D0(Ti(+)-C) - D0(Ti-C) = 0.2322(2) eV. Similar to previous experimental observations, the present state-to-state PFI-PE study of the photoionization transitions, TiC(+)(X(2)Σ(+); v(+) = 0 and 1, N(+)) ← TiC((3)Π1; v', J'), reveals a strong decreasing trend for the photoionization cross section as |ΔN(+)| = |N

Insight into regulation of emission color and photodeactivation process from heteroleptic to homoleptic Ir(III) complexes

Energy Technology Data Exchange (ETDEWEB)

Wang, Xin; Zheng, Danning; Feng, Songyan; Wang, Li, E-mail: chemwangl@henu.edu.cn; Li, Junfeng, E-mail: jfli@theochem.kth.se; Zhang, Jinglai, E-mail: zhangjinglai@henu.edu.cn

2017-03-15

The phosphorescent process of two heteroleptic ((DMDPI){sub 2}Ir(tftap) and (tftap){sub 2}Ir(DMDPI)) and one homoleptic (Ir(DMDPI){sub 3}) Ir(III) complexes (See ) is theoretically investigated by density functional theory (DFT) and quadratic response (QR) time-dependent density functional theory (TDDFT) calculations including spin-orbit coupling (SOC). Two or three triplet excited states are confirmed for three complexes, respectively. On the basis of the respective optimized triplet geometry, the emissive wavelength is determined by the ΔSCF-DFT method. Furthermore, the radiative rate constant (k{sub r}) is also calculated corresponding to each triplet state. Combination of k{sub r} and emissive energy, the emission rule is determined. It is found that complex (DMDPI){sub 2}Ir(tftap) follows the dual emission scenarios, while complexes (tftap){sub 2}Ir(DMDPI) and Ir(DMDPI){sub 3} obey the Kasha rule. The nonradiative rate constant (k{sub nr}) is qualitatively evaluated by the construction of triplet potential surface via metal centered ({sup 3}MC d-d) state. Finally, the sequence of quantum yield is compared by both k{sub r} and k{sub nr}. The quantum yield of homoleptic Ir(III) complex Ir(DMDPI){sub 3} is higher than that of heteroleptic Ir(III) complexes (DMDPI){sub 2}Ir(tftap) and (tftap){sub 2}Ir(DMDPI). However, the emissive wavelength of Ir(DMDPI){sub 3} is in the red color region rather than blue color.

Fluorenyl benzothiadiazole and benzoselenadiazole near-IR fluorescent probes for two-photon fluorescence imaging (Conference Presentation)

Science.gov (United States)

Belfield, Kevin D.; Yao, Sheng; Kim, Bosung; Yue, Xiling

2016-03-01

Imaging biological samples with two-photon fluorescence (2PF) microscopy has the unique advantage of resulting high contrast 3D resolution subcellular image that can reach up to several millimeters depth. 2PF probes that absorb and emit at near IR region need to be developed. Two-photon excitation (2PE) wavelengths are less concerned as 2PE uses wavelengths doubles the absorption wavelength of the probe, which means 2PE wavelengths for probes even with absorption at visible wavelength will fall into NIR region. Therefore, probes that fluoresce at near IR region with high quantum yields are needed. A series of dyes based on 5-thienyl-2, 1, 3-benzothiadiazole and 5-thienyl-2, 1, 3-benzoselenadiazole core were synthesized as near infrared two-photon fluorophores. Fluorescence maxima wavelengths as long as 714 nm and fluorescence quantum yields as high as 0.67 were achieved. The fluorescence quantum yields of the dyes were nearly constant, regardless of solvents polarity. These diazoles exhibited large Stokes shift (GM), and high two-photon fluorescence figure of merit (FM , 1.04×10-2 GM). Cells incubated on a 3D scaffold with one of the new probes (encapsulated in Pluronic micelles) exhibited bright fluorescence, enabling 3D two-photon fluorescence imaging to a depth of 100 µm.

The characterisation of two different degradable polyethylene (PE) sacks

International Nuclear Information System (INIS)

Davis, G.

2006-01-01

The compostability of two different polyethylene (PE) products on the UK market under open-windrow composting conditions is explored within this paper. Chemical analysis of the PE bags has established their constituents in order to examine how the PE bags have an increased degradability depending on additives. Weight loss of the two different PE products within open-windrow composting conditions was recorded in order to establish the percentage weight loss as an indication of the degradability of the two products and their relative suitability for open-windrow composting. Scanning electron microscopy (SEM) of the PE products over the composting duration established the degradation processes for the PE products within the compost. These analyses concluded that one of the PE product mixes was more degradable than the other. However, neither product completed degraded within the timeframe of 12-14 weeks generally accepted for open-windrow composting in the UK

VUV spectroscopy in impurity injection experiments at KSTAR using prototype ITER VUV spectrometer

Science.gov (United States)

Seon, C. R.; Hong, J. H.; Song, I.; Jang, J.; Lee, H. Y.; An, Y. H.; Kim, B. S.; Jeon, T. M.; Park, J. S.; Choe, W.; Lee, H. G.; Pak, S.; Cheon, M. S.; Choi, J. H.; Kim, H. S.; Biel, W.; Bernascolle, P.; Barnsley, R.

2017-08-01

The ITER vacuum ultra-violet (VUV) core survey spectrometer has been designed as a 5-channel spectral system so that the high spectral resolving power of 200-500 could be achieved in the wavelength range of 2.4-160 nm. To verify the design of the ITER VUV core survey spectrometer, a two-channel prototype spectrometer was developed. As a subsequent step of the prototype test, the prototype VUV spectrometer has been operated at KSTAR since the 2012 experimental campaign. From impurity injection experiments in the years 2015 and 2016, strong emission lines, such as Kr xxv 15.8 nm, Kr xxvi 17.9 nm, Ne vii 46.5 nm, Ne vi 40.2 nm, and an array of largely unresolved tungsten lines (14-32 nm) could be measured successfully, showing the typical photon number of 1013-1015 photons/cm2 s.

Novel techniques in VUV high-resolution spectroscopy

NARCIS (Netherlands)

Ubachs, W.M.G.; Salumbides, E.J.; Eikema, K.S.E.; de Oliveira, N.; Nahon, L.

2014-01-01

Novel VUV sources and techniques for VUV spectroscopy are reviewed. Laser-based VUV sources have been developed via non-linear upconversion of laser pulses in the nanosecond (ns), the picosecond (ps), and femtosecond (fs) domain, and are applied in high-resolution gas phase spectroscopic studies.

Rotationally resolved state-to-state photoionization and photoelectron study of titanium carbide and its cation (TiC/TiC+)

International Nuclear Information System (INIS)

Luo, Zhihong; Huang, Huang; Chang, Yih-Chung; Zhang, Zheng; Ng, C. Y.; Yin, Qing-Zhu

2014-01-01

Titanium carbide and its cation (TiC/TiC + ) have been investigated by the two-color visible (VIS)-ultraviolet (UV) resonance-enhanced photoionization and pulsed field ionization-photoelectron (PFI-PE) methods. Two visible excitation bands for neutral TiC are observed at 16 446 and 16 930 cm −1 . Based on rotational analyses, these bands are assigned as the respective TiC( 3 Π 1 ) ← TiC(X 3 Σ + ) and TiC( 3 Σ + ) ← TiC(X 3 Σ + ) transition bands. This assignment supports that the electronic configuration and term symmetry for the neutral TiC ground state are …7σ 2 8σ 1 9σ 1 3π 4 (X 3 Σ + ). The rotational constant and the corresponding bond distance of TiC(X 3 Σ + ; v″ = 0) are determined to be B 0 ″ = 0.6112(10) cm −1 and r 0 ″ = 1.695(2) Å, respectively. The rotational analyses of the VIS-UV-PFI-PE spectra for the TiC + (X; v + = 0 and 1) vibrational bands show that the electronic configuration and term symmetry for the ionic TiC + ground state are …7σ 2 8σ 1 3π 4 (X 2 Σ + ) with the v + = 0 → 1 vibrational spacing of 870.0(8) cm −1 and the rotational constants of B e + = 0.6322(28) cm −1 , and α e + = 0.0085(28) cm −1 . The latter rotational constants yield the equilibrium bond distance of r e + = 1.667(4) Å for TiC + (X 2 Σ + ). The cleanly rotationally resolved VIS-UV-PFI-PE spectra have also provided a highly precise value of 53 200.2(8) cm −1 [6.5960(1) eV] for the adiabatic ionization energy (IE) of TiC. This IE(TiC) value along with the known IE(Ti) has made possible the determination of the difference between the 0 K bond dissociation energy (D 0 ) of TiC + (X 2 Σ + ) and that of TiC(X 3 Σ + ) to be D 0 (Ti + −C) − D 0 (Ti−C) = 0.2322(2) eV. Similar to previous experimental observations, the present state-to-state PFI-PE study of the photoionization transitions, TiC + (X 2 Σ + ; v + = 0 and 1, N + ) ← TiC( 3 Π 1 ; v′, J′), reveals a strong decreasing trend for the photoionization cross

Financing Preference Behaviour for Private Finance Initiative (PFI Projects

Directory of Open Access Journals (Sweden)

Yati Md Lasa

2016-01-01

Full Text Available Project Financing Initiative (PFI projects require the private sector to invest an enormous amount of capital for the development of public projects. The private sector has to seek cost-effective financing sources for their survival in the long-term concession. Conventional financing uses widely; however, Islamic financing promises better financing through profit and loss sharing. This paper reviews financing preferences for PFI projects and the factors influencing the choice of funding. The results show that religious perspective, quality of services, financing facilities and reputation are the factors that are expected will influence the financing preference behaviour, either Islamic or conventional finance.

SPITZER IRS SPECTRA OF LUMINOUS 8 μm SOURCES IN THE LARGE MAGELLANIC CLOUD: TESTING COLOR-BASED CLASSIFICATIONS

International Nuclear Information System (INIS)

Buchanan, Catherine L.; Kastner, Joel H.; Hrivnak, Bruce J.; Sahai, Raghvendra

2009-01-01

We present archival Spitzer Infrared Spectrograph (IRS) spectra of 19 luminous 8 μm selected sources in the Large Magellanic Cloud (LMC). The object classes derived from these spectra and from an additional 24 spectra in the literature are compared with classifications based on Two Micron All Sky Survey (2MASS)/MSX (J, H, K, and 8 μm) colors in order to test the 'JHK8' (Kastner et al.) classification scheme. The IRS spectra confirm the classifications of 22 of the 31 sources that can be classified under the JHK8 system. The spectroscopic classification of 12 objects that were unclassifiable in the JHK8 scheme allow us to characterize regions of the color-color diagrams that previously lacked spectroscopic verification, enabling refinements to the JHK8 classification system. The results of these new classifications are consistent with previous results concerning the identification of the most infrared-luminous objects in the LMC. In particular, while the IRS spectra reveal several new examples of asymptotic giant branch (AGB) stars with O-rich envelopes, such objects are still far outnumbered by carbon stars (C-rich AGB stars). We show that Spitzer IRAC/MIPS color-color diagrams provide improved discrimination between red supergiants and oxygen-rich and carbon-rich AGB stars relative to those based on 2MASS/MSX colors. These diagrams will enable the most luminous IR sources in Local Group galaxies to be classified with high confidence based on their Spitzer colors. Such characterizations of stellar populations will continue to be possible during Spitzer's warm mission through the use of IRAC [3.6]-[4.5] and 2MASS colors.

Update on VUV and soft X-ray facilities at SSRL

International Nuclear Information System (INIS)

Waldhauer, A.

1988-01-01

The number of experimental stations at SSRL devoted to the VUV and soft X-ray region is increasing rapidly. In 1986 there were five VUV/soft X-ray beam lines in regular operation. These consisted of two grasshopper lines, a Seya-Namioka line, a white light lithography line, and the UHV double crystal line, Jumbo. By 1988 ten beam lines, including two with insertion devices, covering the spectral range 5-4000 eV in five overlapping ranges will be operational. With the addition of these new stations, SSRL will have increased dramatically its facilities for performing VUV and soft X-ray research. (orig.)

High power all solid state VUV lasers

International Nuclear Information System (INIS)

Zhang, Shen-jin; Cui, Da-fu; Zhang, Feng-feng; Xu, Zhi; Wang, Zhi-min; Yang, Feng; Zong, Nan; Tu, Wei; Chen, Ying; Xu, Hong-yan; Xu, Feng-liang; Peng, Qin-jun; Wang, Xiao-yang; Chen, Chuang-tian; Xu, Zu-yan

2014-01-01

Highlights: • Polarization and pulse repetition rate adjustable ps 177.3 nm laser was developed. • Wavelength tunable ns, ps and fs VUV lasers were developed. • High power ns 177.3 nm laser with narrow linewidth was investigated. - Abstract: We report the investigation on the high power all solid state vacuum ultra-violet (VUV) lasers by means of nonlinear frequency conversion with KBe 2 BO 3 F 2 (KBBF) nonlinear crystal. Several all solid state VUV lasers have developed in our group, including polarization and pulse repetition rate adjustable picosecond 177.3 nm VUV laser, wavelength tunable nanosecond, picosecond and femtosecond VUV lasers, high power ns 177.3 nm laser with narrow linewidth. The VUV lasers have impact, accurate and precise advantage

Photodissociation of Small Molecules and Photoionization of Free Radicals Using the VUV Velocity-Map Imaging Photoion and Photoelectron Method

Science.gov (United States)

Gao, Hong

(2012). (Chapter 2) 2. Hong Gao, Yu Song, Lei Yang, Xiaoyu Shi, Qing-Zhu Yin, C. Y. Ng and William M. Jackson. "Branching ratio measurements of the predissociation of 12C16O by time-slice velocity-map ion imaging in the energy region from 108,000 to 110,500 cm-1", the Journal of Chemical Physics, 137, 034305 (2012). (Chapter 3) 3. Hong Gao, Yu Song, Yih-Chung Chang, Xiaoyu Shi, Qing-Zhu Yin, Roger C. Wiens, William M. Jackson, C. Y. Ng, "Branching Ratio Measurements for Vacuum Ultraviolet Photodissociation of 12C16O", the Journal of Physical Chemistry A. (article online ASAP). (Chapter 4) 4. Hong Gao, Yu Song, C. Y. Ng, William M. Jackson, " Communication: State-to-state photodissociation study by the two-color VUV-VUV laser pump-probe time-slice velocity-map-imaging-photoion method", the Journal of Chemical Physics, 138, 191102(2013). (Chapter 5) 5. Hong Gao, Zhou Lu, Lei Yang, Jingang Zhou, C. Y. Ng, "Communication: A vibrational study of propargyl cation using the vacuum ultraviolet laser velocity-map imaging photoelectron method", the Journal of Chemical Physics, 137, 161101(2012). (Chapter 6)

Rydberg states of chloroform studied by VUV photoabsorption spectroscopy

International Nuclear Information System (INIS)

Singh, Param Jeet; Shastri, Aparna; D’Souza, R.; Jagatap, B.N.

2013-01-01

The VUV photoabsorption spectra of CHCl 3 and CDCl 3 in the energy region 6.2–11.8 eV (50,000–95,000 cm −1 ) have been investigated using synchrotron radiation from the Indus-1 source. Rydberg series converging to the first four ionization limits at 11.48, 11.91, 12.01 and 12.85 eV corresponding to excitation from the 1a 2 , 4a 1 , 4e, 3e, orbitals of CHCl 3 respectively are identified and analyzed. Quantum defect values are observed to be consistent with excitation from the chlorine lone pair orbitals. Vibrational progressions observed in the region of 72,500–76,500 cm −1 have been reassigned to ν 3 and combination modes of ν 3 +ν 6 belonging to the 1a 2 →4p transition in contrast to earlier studies where they were assigned to a ν 3 progression superimposed on the 3e→4p Rydberg transition. The assignments are further confirmed based on isotopic substitution studies on CDCl 3 whose VUV photoabsorption spectrum is reported here for the first time. The frequencies of the ν 3 and ν 6 modes in the 4p Rydberg state of CHCl 3 (CDCl 3 ) are proposed to be ∼454 (409) cm −1 and∼130 (129) cm −1 respectively based on the vibronic analysis. DFT calculations of neutral and ionic ground state vibrational frequencies support the vibronic analysis. Experimental spectrum is found to be in good agreement with that predicted by TDDFT calculations. This work presents a consolidated analysis of the VUV photoabsorption spectrum of chloroform. -- Highlights: •VUV photoabsorption spectra of CHCl 3 and CDCl 3 studied using synchrotron radiation. •Quantum defect analysis of Rydberg series converging to first four ionization limits. •Vibronic bands in 72,500–76,500 cm −1 region assigned to 1a 2 →4p Rydberg transition. •Vibrational progressions assigned to ν 3 and ν 3 +ν 6 using ab initio calculations. •Excellent agreement of TDDFT vertical excited energies with experimental spectrum

Chemical evolution of Titan’s aerosol analogues under VUV irradiation

Science.gov (United States)

Carrasco, Nathalie; Gavilan, Lisseth; Tigrine, Sarah; Vettier, Ludovic; Nahon, Laurent; Pernot, Pascal

2017-10-01

Since the Cassini-CAPS measurements, organic aerosols are known to be present and formed at high altitudes in the diluted and partially ionized medium that is Titan’s ionosphere [1].After production in the ionosphere, Titan’s aerosols evolve through microphysics during their sedimentation down to Titan’s surface [2]. Starting with a few nanomers size in the upper atmosphere, they reach a fractal structure of a few hundreds nanometers close to the surface [3]. During sedimentation, aerosols are also submitted to solar irradiation. As laboratory analogs of Titan’s atmospheric aerosols (tholins) show a strong UV absorption [4], we suspect that VUV irradiation could also induce a chemical evolution of Titan’s aerosols during their descent in Titan’s atmosphere.The aim of this work ist to simulate the irradiation process occuring on the aerosols in Titan’s atmosphere and to address whether this irradiation impacts the chemical composition of the organic solids. First aerosol analogues were produced in a N2-CH4 plasma discharge as thin organic films of a few hundreds of nanometers thick [5]. Then those were irradiated at Lyman-α wavelength, the strongest VUV line in the solar spectrum, with a high photon flux on a synchrotron VUV beamline. We will present and discuss the significant chemical evolutions observed on the analogues after VUV irradiation by mid-IR absorption spectroscopy.[1] Waite et al. (2009) Science , 316, p. 870[2] Lavvas et al. (2011) Astrophysical Journal, 728:80[3] Tomasko et al. (2008) Planetary and Space Science, 56, p. 669[4] Mahjoub et al. (2012) Icarus 221, P. 670[5] Carrasco et al. (2016) Planetary and Space Science, 128, p. 52

Planet Formation Imager (PFI) : science vision and key requirements

NARCIS (Netherlands)

Kraus, S.; Monnier, J.D.; Ireland, M.J.; Duchene, G.; Espaillat, C.; Honig, S.; Juhasz, A.; Mordasini, C.; Olofsson, J.; Paladini, C.; Stassun, K.; Turner, N.; Vasisht, G.; Harries, T.J.; Bate, M.R.; Gonzalez, J-F.; Matter, A.; Zhu, Z.; Panic, O.; Regaly, Z.; Morbidelli, A.; Meru, F.; Wolf, S.; Ilee, J.; Berger, J-P.; Zhao, M.; Kral, Q.; Morlok, A.; Bonsor, A.; Ciardi, D.; Kane, S.R.; Kratter, K.; Laughlin, G.; Pepper, J.; Raymond, S.; Labadie, L.; Nelson, R.P.; Weigelt, G.; Brummelaar, ten T.; Pierens, A.; Oudmaijer, R.; Kley, W.; Pope, B.; Jensen, E.L.N.; Bayo, A.; Smith, M.; Boyajian, T.; Quiroga-Nunez, L.H.; Millan-Gabet, R.; Chiavassa, A.; Gallenne, A.; Reynolds, M.; Wit, de W-J.; Wittkowski, M.; Millour, F.; Gandhi, P.; Ramos, A. C.; Alonso, H. A.; Packham, C.; Kishimoto, M.; Tristram, K.R.W.; Pott, J.-U.; Surdej, J.; Buscher, D.; Haniff, C.; Lacour, S.; Petrov, R.; Ridgway, S.; Tuthill, P.; Belle, van G.; Armitage, P.; Baruteau, C.; Benisty, M.; Bitsch, B.; Paardekooper, S-J.; Pinte, C.; Masset, F.; Rosotti, G.P.

2016-01-01

The Planet Formation Imager (PFI) project aims to provide a strong scientific vision for ground-based optical astronomy beyond the upcoming generation of Extremely Large Telescopes. We make the case that a breakthrough in angular resolution imaging capabilities is required in order to unravel the

Attosecond pulse trains generated using two color laser fields

International Nuclear Information System (INIS)

Mauritsson, J.; Louisiana State University, Baton Rouge, LA; Johnsson, P.; Gustafsson, E.; L'Hullier, A.; Schafer, K.J.; Gaarde, M.B.

2006-01-01

Complete test of publication follows. We present the generation of attosecond pulse trains from a superposition of an infrared (IR) laser field and its second harmonic. Our attosecond pulses are synthesized by selecting a number of synchronized harmonics generated in argon. By adding the second harmonic to the driving field the inversion symmetry of generation process is broken and both odd and even harmonics are generated. Consecutive half cycles in the two color field differ beyond the simple sign change that occurs in a one color field and have very different shapes and amplitudes. This sub-cycle structure of the field, which governs the generation of the attosecond pulses, depends strongly on the relative phase and intensity of the two fields, thereby providing additional control over the generation process. The generation of attosecond pulses is frequently described using the semi-classical three step model where an electron is: (1) ionized through tunneling ionization during one half cycle; (2) reaccelerated back towards the ion core by the next half cycle; where it (3) recombines with the ground-state releasing the access energy in a short burst of light. In the two color field the symmetry between the ionizing and reaccelerating field is broken, which leads to two possible scenarios: the electron can either be ionized during a strong half cycle and reaccelerated by a weaker field or vice versa. The periodicity is a full IR cycle in both cases and hence two trains of attosecond pulses are generated which are offset from each other. The generation efficiency, however, is very different for the two cases since it is determined mainly by the electric field strength at the time of tunneling and one of the trains will therefore dominate the other. We investigate experimentally both the spectral and temporal structure of the generated attosecond pulse trains as a function of the relative phase between the two driving fields. We find that for a wide range of

Degradation mechanisms of the blue-emitting phosphor BaMgAl{sub 10}O{sub 17}:Eu{sup 2+} under baking and VUV-irradiating treatments

Energy Technology Data Exchange (ETDEWEB)

Zhang Shuxiu E-mail: shuxiu_zhang@dyden.co.jp; Kono, Toshihiko; Ito, Akira; Yasaka, Taketo; Uchiike, Heiju

2004-01-01

The luminescent properties of an Eu{sup 2+}-activated hexagonal aluminate, BaMgAl{sub 10}O{sub 17} (BAM), were studied under 147- and 254-nm excitations. The BAM samples were thermally treated by baking and then irradiated in vacuum ultraviolet (VUV) rays. The results show that the emission efficiency of Eu{sup 2+} in BAM under 147-nm excitation degraded seriously after baking or VUV-irradiating treatments, while no significant degradation was observed under 254-nm excitation. The degree of degradation depended on the excitation wavelength, and the absorption edge of the BAM host was suggested to be close to 175 nm (7.2 eV). The differences between the thermal-induced and the VUV-irradiation-induced degradations, and their mechanisms are discussed for the color plasma display applications.

Rydberg states of chloroform studied by VUV photoabsorption spectroscopy

Science.gov (United States)

Singh, Param Jeet; Shastri, Aparna; D'Souza, R.; Jagatap, B. N.

2013-11-01

The VUV photoabsorption spectra of CHCl3 and CDCl3 in the energy region 6.2-11.8 eV (50,000-95,000 cm-1) have been investigated using synchrotron radiation from the Indus-1 source. Rydberg series converging to the first four ionization limits at 11.48, 11.91, 12.01 and 12.85 eV corresponding to excitation from the 1a2, 4a1, 4e, 3e, orbitals of CHCl3 respectively are identified and analyzed. Quantum defect values are observed to be consistent with excitation from the chlorine lone pair orbitals. Vibrational progressions observed in the region of 72,500-76,500 cm-1 have been reassigned to ν3 and combination modes of ν3+ν6 belonging to the 1a2→4p transition in contrast to earlier studies where they were assigned to a ν3 progression superimposed on the 3e→4p Rydberg transition. The assignments are further confirmed based on isotopic substitution studies on CDCl3 whose VUV photoabsorption spectrum is reported here for the first time. The frequencies of the ν3 and ν6 modes in the 4p Rydberg state of CHCl3 (CDCl3) are proposed to be ~454 (409) cm-1 and~130 (129) cm-1 respectively based on the vibronic analysis. DFT calculations of neutral and ionic ground state vibrational frequencies support the vibronic analysis. Experimental spectrum is found to be in good agreement with that predicted by TDDFT calculations. This work presents a consolidated analysis of the VUV photoabsorption spectrum of chloroform.

Photostability studies of prebiotic molecules at the VUV region

International Nuclear Information System (INIS)

Tanaka, H; Medina, A; Mendes, L A V; Prudente, F V; Marinho, R R T; Homem, M G P

2014-01-01

In this work we report absolute cross section studies of prebiotic molecules measured in the VUV range using the double ion chamber technique and synchrotron radiation. Absorption, ionization and neutral decay cross sections will be presented, together with the absolute ionization quantum yield. Additionally, partial ion yield spectra were measured by a TOF mass spectrometer.

VUV Processing of Polymers: Surface Modification and Deposition of Organic Thin Films

International Nuclear Information System (INIS)

Wertheimer, M.R.

2006-01-01

Materials processing based on the use of vacuum-ultraviolet (VUV) radiation has evolved from the status of 'laboratory curiosum' to that of technological reality, thanks to the availability of commercial light sources, first lasers but more recently VUV-lamps. We begin with a brief survey of application areas, still mostly 'high-tech' on account of the relatively elevated cost of the light sources. In this laboratory, we use a series of commercial VUV lamps (based on radio-frequency discharges in ampoules that are sealed with VUV-transparent MgF 2 ) that cover a broad spectral range, 120 nm 3 ) gas. This allowed us to achieve maximum bound N concentrations, [N] ∼ 25 at%, comparable to values achieved by plasma-induced nitriding. More recently, we have investigated the deposition of polymer-like ( V UV-polymer ) coatings by VUV-induced gas-phase photo-chemistry of ammonia-hydrocarbon mixtures, both gases that strongly absorb VUV photons. We use the same cylindrical high-vacuum reactor, with a VUV lamp and a VUV-sensitive photodiode detector at opposite ends; after measuring radiation intensity, the latter is replaced by a substrate holder, the frontal distance of which (with respect to the lamp) can be adjusted. For 'VUV-polymerization' experiments we have used two resonant lamps (low-pressure Kr and Xe), having 'monochromatic' emissions at λ 123.6 nm and 147.0 nm, respectively. The ammonia-hydrocarbon feed gas mixtures are characterised by their flow rate ratio, R ≡ NH 3 /C x H y , where C x H y designates methane (CH 4 ) or ethylene (C 2 H 4 ), the two 'monomers' investigated so far. Thin 'VUV-polymer' deposits were collected on MgF 2 or Si wafers placed on the substrate holder, and they were examined by a variety of physico-chemical techniques; for example, chemical structure and composition were characterized by X-ray photoelectron spectroscopy (XPS); layer thickness and refractive index, n, were determined by UV-VIS spectro-ellipsometry, and �

Future prospects for studies in the VUV-SX region

International Nuclear Information System (INIS)

Tanaka, Kenichiro; Kitajima, Yoshinori

1989-09-01

This book carries papers presented at a workshop 'Future Prospects for Studies in the VUV-SX Region' held on March 22 and 23, 1989. The workshop focussed particularly on the promotion of research in the VUV and soft X-ray regions. Three sessions were held: Session 1 for studies in peripheral areas, Session 2 for theoretical studies, and Session 3 for recent developments. Session 1 covered five studies: 'Laser Spectroscopy: High-Resolution Observation of Highly Electronically Excited Gaseous Molecule', 'High-Resolution Electron Spectroscopy: Surface Phonon Spectroscopy', 'Experimental Study on Atoms and Molecules through Ion Trap', 'Basic Mechanism of Photo-Induced CVD', and 'Application of Circularly Polarized Light'. Session 2 covered five studies: 'Electronic State of High Tc Superconducting Oxide', 'Surface Condition and Electronic State', 'XES and XAS Study of Rare Earth Compound', 'Resonance Photoelectric Spectroscopy on Strongly Correlated Electronic System', and 'Circularly Polarized Light and Atomic Process in Soft X-Ray Region'. Session 3 covered six studies: 'Prospects of Application of Supercritical Liquid to Research on Physical Characteristics', 'Application of Orbit Radiation to Polarization Spectroscopy', 'XES Research for La Compounds', 'Characteristics of Ultra-Fine Particles', 'Surface Study by Angular-Resolution Photoelectric Spectroscopy', and 'EXAFS Study of Light Element'. (N.K.)

A study of enhanced performance of VUV/UV process for the degradation of micropollutants from contaminated water

Energy Technology Data Exchange (ETDEWEB)

Bagheri, Mehdi; Mohseni, Madjid, E-mail: madjid.mohseni@ubc.ca

2015-08-30

Highlights: • Developing a comprehensive CFD simulation tool for VUV/UV photoreactors modeling. • Analysing impact of reactor hydrodynamics on the AOP performance of VUV/UV process. • Cutting the energy cost of VUV/UV process by means of improved-photoreactor design. • Experimentally verifying the CFD results using a VUV/UV prototype photoreactor. - Abstract: VUV/UV is a chemical-free and straightforward solution for the degradation of emerging contaminants from water sources. The objective of this work was to investigate the feasibility of VUV/UV advanced oxidation process for the effective degradation of a target micropollutant, atrazine, under continuous flow operation of 0.5–6.5 L/min. To provide an in-depth understanding of process, a comprehensive computational fluid dynamics (CFD) model, incorporating flow hydrodynamics, 185 nm VUV and 254 nm UV radiation propagation along with a complete kinetic scheme, was developed and validated experimentally. The experimental degradation rates and CFD predicted values showed great consistency with less than 2.9% average absolute relative deviation (AARD). Utilizing the verified model, energy-efficiency of the VUV/UV process under a wide range of reactor configurations was assessed in terms of electrical energy-per-order (EEO), ·OH concentration as well as delivered UV and VUV dose distributions. Thereby, the extent of mixing and circulation zones was found as key parameter controlling the treatment economy and energy-efficiency of the VUV/UV process. Utilizing a CFD-driven baffle design strategy, an improved VUV/UV process with up to 72% reduction in the total electrical energy requirement of atrazine degradation was introduced and verified experimentally.

Combustion synthesis and optical properties of Oxy-borate phosphors YCa4O(BO3)3:RE3+ (RE = Eu3+, Tb3+) under UV, VUV excitation

International Nuclear Information System (INIS)

Ingle, J.T.; Gawande, A.B.; Sonekar, R.P.; Omanwar, S.K.; Wang, Yuhua; Zhao, Lei

2014-01-01

Graphical abstract: VUV Photoluminescence of YCa 4 O(BO 3 ) 3 : Eu 3+ and YCa 4 O(BO 3 ) 3 : Tb 3+ for PDPs applications. Highlights: • Inorganic Oxy-borate phosphors YCa 4 O(BO 3 ) 3 :Eu 3+ ,Tb 3+ was synthesized by novel solution combustion synthesis. • This single host produces efficient and intense Red and Green color for display applications. • Good agreement with CIE co-ordinates as prescribes by NTCL, for flat panel, PDP display color. • Synthesized materials were characterized using powder XRD, FE-SEM, UV and VUV Spectophotometer. -- Abstract: The inorganic Oxy-borate host phosphors YCa 4 O(BO 3 ) 3 :RE 3+ (RE = Eu 3+ ,Tb 3+ ) were synthesized by a novel solution combustion technique. The synthesis is based on the exothermic reaction between the fuel (Urea) and Oxidizer (Ammonium nitrate). The heat generated in reaction is use for auto combustion of precursors. The structures of the prepared samples were confirmed by powder XRD technique. The photoluminescence properties of the powder samples were investigated under UV and VUV excitation; “The phosphor YCa 4 O(BO 3 ) 3 :Eu 3+ and YCa 4 O(BO 3 ) 3 :Tb 3+ shows strong absorption in UV and VUV region and exhibits intense red and green emission upon excited by 254 nm UV and 147 nm VUV radiation”

Multi-terminal Two-color ZnCdSe/ZnCdMgSe Based Quantum-well Infrared Photodetector

Science.gov (United States)

Kaya, Yasin; Ravikumar, Arvind; Chen, Guopeng; Tamargo, Maria C.; Shen, Aidong; Gmachl, Claire

Target recognition and identification applications benefits from two-color infrared (IR) detectors in the mid and long-wavelength IR regions. Currently, InGaAs/AlGaAs and GaAs/AlGaAs multiple quantum wells (QWs) grown on GaAs substrate are the most commonly used two-color QW IR photodetectors (QWIPs). However, the lattice-mismatch and the buildup of strain limit the number of QWs that can be grown, in turn increasing the dark current noise, and limiting the device detectivity.In this work, we report on two-color QWIPs based on the large conduction band offset (~1.12ev) ZnCdSe/ZnCdMgSe material system lattice matched to InP. QWIPs were designed based on a bound to quasi-bound transition, centered at 4 μm and 7 μm and each QW is repeated 50 times to eliminate the high dark current and a contact layer is inserted between the two stacks of QWs for independent electrical contacts. Wafers are processed into two step rectangular mesas by lithography and wet etching. Experiments showed absorption spectra centered at 4.9 μm and 7.6 μm at 80 K and the full width at half maximums were Δλ / λ = 21 % and Δλ / λ = 23 % , respectively. Current work studies the Johnson and the background noise limited detectivities of these QWIPs. Current address: School of Earth, Energy and Environmental Sciences, Stanford, CA 94305, USA.

New perspectives for organic chemistry and biochemistry in VUV: reaction kinetics, chirality and thermochemistry. Summaries

International Nuclear Information System (INIS)

Nahon, Laurent; Field, David; Gerber, Thomas; Knopp, Gregor; Beaud, Paul; Radi, Peter; Tulej, Marek; Dedonder-Lardeux, Claude; Jung, J.M.; Laprevote, Olivier; Thissen, Roland; Le Barbu, K.; Lahmani, F.; Zehnacker, A.; Maurizot, Jean Claude; Barbier, Bernard; Kagan, Henri B.

2001-10-01

The aim of this workshop was to examine the conditions of use of VUV for the study of complex molecular systems, and notably bio-molecules, a domain which is greatly expanding. The conclusions of this one-day workshop should allow to define new fields of utilization of the synchrotron radiation in VUV, to precise certain performances that are needed for the transferred line, to establish the complementarities with other VUV sources (lasers, free electron lasers, lamps) and to determine the eventual need for a second low energy light line at SOLEIL. The titles of the various abstract papers presented are (two papers are in English, the rest is in French): SU5, a high resolution and variable polarization VUV line that should be transferred at SOLEIL; Interstellar organic chemistry (in English); Application of spectroscopic techniques in the VUV to combustion relevant molecules (in English); Gaseous phase reaction kinetics (bi-molecular reactions in collision and in aggregates); Liquids of biological interest (excitation and relaxation close to the ionization threshold); Successes and impediments in protein mass spectrometry (the potential contribution of VUV synchrotron radiation); Stereo-specific effects; Complexes between chiral molecules; circular dichroism of biomolecules; Exobiology; asymmetric synthesis (principles and recent results)

Penning plasma based simultaneous light emission source of visible and VUV lights

Energy Technology Data Exchange (ETDEWEB)

Vyas, G. L., E-mail: glvyas27@gmail.com [Manipal University Jaipur (India); Prakash, R.; Pal, U. N. [CSIR-Central Electronics and Engineering Research Institute, Microwave Tubes Division (India); Manchanda, R. [Institute for Plasma Research (India); Halder, N. [Manipal University Jaipur (India)

2016-06-15

In this paper, a laboratory-based penning plasma discharge source is reported which has been developed in two anode configurations and is able to produce visible and VUV lights simultaneously. The developed source has simultaneous diagnostics facility using Langmuir probe and optical emission spectroscopy. The two anode configurations, namely, double ring and rectangular configurations, have been studied and compared for optimum use of the geometry for efficient light emissions and recording. The plasma is produced using helium gas and admixture of three noble gases including helium, neon, and argon. The source is capable to produce eight spectral lines for pure helium in the VUV range from 20 to 60 nm and total 24 spectral lines covering the wavelength range 20–106 nm for the admixture of gases. The large range of VUV lines is generated from gaseous admixture rather from the sputtered materials. The recorded spectrum shows that the plasma light radiations in both visible and VUV range are larger in double ring configuration than that of the rectangular configurations at the same discharge operating conditions. To clearly understand the difference, the imaging of the discharge using ICCD camera and particle-in-cell simulation using VORPAL have also been carried out. The effect of ion diffusion, metastable collision with the anode wall and the nonlinear effects are correlated to explain the results.

Effects of port fuel injection (PFI) of n-butanol and EGR on combustion and emissions of a direct injection diesel engine

International Nuclear Information System (INIS)

Chen, Zheng; Liu, Jingping; Wu, Zhenkuo; Lee, Chiafon

2013-01-01

Highlights: • A DI diesel engine with PFI of n-butanol in combination with EGR is investigated. • Butanol concentration and EGR have a coupled impact on combustion process. • A combination of butanol PFI and EGR can break through tradeoff between NOx and soot. • DI diesel with butanol PFI has lower ITE than DI of diesel–butanol blends. - Abstract: An experimental investigation was conducted on a direct injection (DI) diesel engine with exhaust gas recirculation (EGR), coupled with port fuel injection (PFI) of n-butanol. Effects of butanol concentration and EGR rate on combustion, efficiency, and emissions of the tested engine were evaluated, and also compared to a DI mode of diesel–butanol blended fuel. The results show butanol concentration and EGR rate have a coupled impact on combustion process. Under low EGR rate condition, both the peak cylinder pressure and the peak heat release rate increase with increased butanol concentration, but no visible influence was found on the ignition delay. Under high EGR rate condition, however, the peak cylinder pressure and the peak heat release rate both decrease with increased butanol concentration, accompanied by longer ignition delay and longer combustion duration. As regard to the regulated emissions, HC and CO emissions increase with increased butanol concentration, causing higher indicated specific fuel consumption (ISFC) and lower indicated thermal efficiency (ITE). It is also noted that butanol PFI in combination with EGR can change the trade-off relationship between NOx and soot, and simultaneously reduce both into a very low level. Compared with the DI mode of diesel–butanol blended fuel, however, the DI diesel engine with butanol PFI has higher HC and CO emissions and lower ITE. Therefore, future research should be focused on overcoming the identified shortcomings by an improved injection strategy of butanol PFI

Design of ITER divertor VUV spectrometer and prototype test at KSTAR tokamak

Science.gov (United States)

Seon, Changrae; Hong, Joohwan; Song, Inwoo; Jang, Juhyeok; Lee, Hyeonyong; An, Younghwa; Kim, Bosung; Jeon, Taemin; Park, Jaesun; Choe, Wonho; Lee, Hyeongon; Pak, Sunil; Cheon, MunSeong; Choi, Jihyeon; Kim, Hyeonseok; Biel, Wolfgang; Bernascolle, Philippe; Barnsley, Robin; O'Mullane, Martin

2017-12-01

Design and development of the ITER divertor VUV spectrometer have been performed from the year 1998, and it is planned to be installed in the year 2027. Currently, the design of the ITER divertor VUV spectrometer is in the phase of detail design. It is optimized for monitoring of chord-integrated VUV signals from divertor plasmas, chosen to contain representative lines emission from the tungsten as the divertor material, and other impurities. Impurity emission from overall divertor plasmas is collimated through the relay optics onto the entrance slit of a VUV spectrometer with working wavelength range of 14.6-32 nm. To validate the design of the ITER divertor VUV spectrometer, two sets of VUV spectrometers have been developed and tested at KSTAR tokamak. One set of spectrometer without the field mirror employs a survey spectrometer with the wavelength ranging from 14.6 nm to 32 nm, and it provides the same optical specification as the spectrometer part of the ITER divertor VUV spectrometer system. The other spectrometer with the wavelength range of 5-25 nm consists of a commercial spectrometer with a concave grating, and the relay mirrors with the same geometry as the relay mirrors of the ITER divertor VUV spectrometer. From test of these prototypes, alignment method using backward laser illumination could be verified. To validate the feasibility of tungsten emission measurement, furthermore, the tungsten powder was injected in KSTAR plasmas, and the preliminary result could be obtained successfully with regard to the evaluation of photon throughput. Contribution to the Topical Issue "Atomic and Molecular Data and their Applications", edited by Gordon W.F. Drake, Jung-Sik Yoon, Daiji Kato, Grzegorz Karwasz.

Rotationally resolved state-to-state photoionization and the photoelectron study of vanadium monocarbide and its cations (VC/VC(+)).

Science.gov (United States)

Chang, Yih Chung; Luo, Zhihong; Pan, Yi; Zhang, Zheng; Song, Ying-Nan; Kuang, Sophie Yajin; Yin, Qing Zhu; Lau, Kai-Chung; Ng, C Y

2015-04-21

By employing two-color visible (VIS)-ultraviolet (UV) laser photoionization and pulsed field ionization-photoelectron (PFI-PE) techniques, we have obtained highly rotationally resolved photoelectron spectra for vanadium monocarbide cations (VC(+)). The state-to-state VIS-UV-PFI-PE spectra thus obtained allow unambiguous assignments for the photoionization rotational transitions, resulting in a highly precise value for the adiabatic ionization energy (IE) of vanadium monocarbide (VC), IE(VC) = 57512.0 ± 0.8 cm(-1) (7.13058 ± 0.00010 eV), which is defined as the energy of the VC(+)(X(3)Δ1; v(+) = 0; J(+) = 1) ← VC(X(2)Δ3/2; v'' = 0; J'' = 3/2) photoionization transition. The spectroscopic constants for VC(+)(X(3)Δ1) determined in the present study include the harmonic vibrational frequency ωe(+) = 896.4 ± 0.8 cm(-1), the anharmonicity constant ωe(+)xe(+) = 5.7 ± 0.8 cm(-1), the rotational constants Be(+) = 0.6338 ± 0.0025 cm(-1) and αe(+) = 0.0033 ± 0.0007 cm(-1), the equilibrium bond length re(+) = 1.6549 ± 0.0003 Å, and the spin-orbit coupling constant A = 75.2 ± 0.8 cm(-1) for VC(+)(X(3)Δ1,2,3). These highly precise energetic and spectroscopic data are used to benchmark state-of-the-art CCSDTQ/CBS calculations. In general, good agreement is found between the theoretical predictions and experimental results. The theoretical calculations yield the values, IE(VC) = 7.126 eV; the 0 K bond dissociation energies: D0(V-C) = 4.023 eV and D0(V(+)-C) = 3.663 eV; and heats of formation: ΔH°(f0)(VC) = 835.2, ΔH°(f298)(VC) = 840.4, ΔH°(f0)(VC(+)) = 1522.8, and ΔH°(f298)(VC(+)) = 1528.0 kJ mol(-1).

SHORT COMMUNICATION: Status of Physical Fitness Index (PFI % and Anthropometric Parameters in Residential School Children Compared to Nonresidential School Children

Directory of Open Access Journals (Sweden)

Jyoti P Khodnapur

2012-07-01

Full Text Available Background: Physical fitness is the prime criterion for survival, to achieve any goal and to lead a healthy life. Effect of exercise to have a good physical fitness is well known since ancient Vedas. Physical fitness can be recorded by cardiopulmonary efficiency test like Physical Fitness Index (PFI % which is a powerful indicator of cardiopulmonary efficiency. Regular exercise increases PFI by increasing oxygen consumption. Residential school children are exposed to regular exercise and nutritious food under the guidance. Aims and Objectives: Our study is aimed to compare the physical fitness index status and anthropometric parameters in Residential Sainik (n=100 school children compared to Non-Residential (n=100 school children (aged between 12-16 years of Bijapur. Material and Methods: PFI was measured by Harvard Step Test [1]. TheAnthropometrical parameters like Height (cms, Weight (Kg, Body Surface Area (BSA in sq.mts, Body Mass Index (BMI in Kg/m2, Mid Arm Circumference (cms, Chest Circumference (cms and Abdominal Circumference (cms were recorded. Results: Mean score of PFI(%, Height(cms, Weight(Kg, BSA(sq.mts, BMI(Kg/m2, Mid Arm Circumference(cms, Chest Circumference (cms and Abdominal Circumference (cms were significantly higher (p=0.000 in Residential school children compared to Non Residential school children. In conclusion regular exercise and nutritious diet under the guidance increases the physical fitness and growth in growing children.

Recent development of VUV-based processes for air pollutants degradation

Directory of Open Access Journals (Sweden)

Haibao eHuang

2016-03-01

Full Text Available As air pollution become more and more serious nowadays, it is essential to find out a way to efficiently degrade the air pollutants. Vacuum ultraviolet (VUV-based processes are an emerging and promising technologies for environmental remediation such as air cleaning, wastewater treatment and air/water disinfection. With VUV irradiation, photolysis, photocatalyst is and ozone-assisted oxidation are involved at the same time, resulting in the fast degradation of air pollutants because of their strong oxidizing capacity. The mechanisms of how the oxidants are produced and reacted are discussed in this review. This paper mainly focuses on the three VUV-based oxidation processes including VUV photolysis, VUV combined with ozone-assisted oxidation and VUV-PCO with emphasis on their mechanisms and applications. Also, the outlooks of these processes are outlined in this paper.

Low-k films modification under EUV and VUV radiation

International Nuclear Information System (INIS)

Rakhimova, T V; Rakhimov, A T; Mankelevich, Yu A; Lopaev, D V; Kovalev, A S; Vasil'eva, A N; Zyryanov, S M; Kurchikov, K; Proshina, O V; Voloshin, D G; Novikova, N N; Krishtab, M B; Baklanov, M R

2014-01-01

Modification of ultra-low-k films by extreme ultraviolet (EUV) and vacuum ultraviolet (VUV) emission with 13.5, 58.4, 106, 147 and 193 nm wavelengths and fluences up to 6 × 10 18  photons cm −2 is studied experimentally and theoretically to reveal the damage mechanism and the most ‘damaging’ spectral region. Organosilicate glass (OSG) and organic low-k films with k-values of 1.8–2.5 and porosity of 24–51% are used in these experiments. The Si–CH 3 bonds depletion is used as a criterion of VUV damage of OSG low-k films. It is shown that the low-k damage is described by two fundamental parameters: photoabsorption (PA) cross-section σ PA and effective quantum yield φ of Si–CH 3 photodissociation. The obtained σ PA and φ values demonstrate that the effect of wavelength is defined by light absorption spectra, which in OSG materials is similar to fused silica. This is the reason why VUV light in the range of ∼58–106 nm having the highest PA cross-sections causes strong Si–CH 3 depletion only in the top part of the films (∼50–100 nm). The deepest damage is observed after exposure to 147 nm VUV light since this emission is located at the edge of Si–O absorption, has the smallest PA cross-section and provides extensive Si–CH 3 depletion over the whole film thickness. The effective quantum yield slowly increases with the increasing porosity but starts to grow quickly when the porosity exceeds the critical threshold located close to a porosity of ∼50%. The high degree of pore interconnectivity of these films allows easy movement of the detached methyl radicals. The obtained results have a fundamental character and can be used for prediction of ULK material damage under VUV light with different wavelengths. (paper)

Rotationally resolved pulsed-field ionization photoelectron bands for O{sub 2}{sup +}(A {sup 2}{pi}{sub u},v{sup +}=0-12) in the energy range of 17.0-18.2 eV

Energy Technology Data Exchange (ETDEWEB)

Song, Y. [Ames Laboratory, U.S. Department of Energy and Department of Chemistry, Iowa State University, Ames, Iowa 50011 (United States); Evans, M. [Ames Laboratory, U.S. Department of Energy and Department of Chemistry, Iowa State University, Ames, Iowa 50011 (United States); Ng, C. Y. [Ames Laboratory, U.S. Department of Energy and Department of Chemistry, Iowa State University, Ames, Iowa 50011 (United States); Hsu, C.-W. [Chemical Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Jarvis, G. K. [Chemical Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

2000-01-15

We have obtained rotationally resolved pulsed-field ionization photoelectron (PFI-PE) spectra for O{sub 2} in the energy range of 17.05-18.13 eV, covering the ionization transitions O{sub 2}{sup +}(A {sup 2}{pi}{sub u},v{sup +}=0-12,N{sup +})(<-)O{sub 2}(X {sup 3}{sigma}{sub g}{sup -},v{sup ''}=0,N{sup ''}). Although these O{sub 2}{sup +}(A {sup 2}{pi}{sub u},v{sup +}) PFI-PE bands have significant overlaps with vibrational bands for O{sub 2}{sup +}(a {sup 4}{pi}{sub u}) and O{sub 2}{sup +}(X {sup 2}{pi}{sub g}), we have identified all the O{sub 2}{sup +}(A {sup 2}{pi}{sub u},v{sup +}=0-12) bands by simulation of spectra obtained using supersonically cooled O{sub 2} samples with rotational temperatures {approx_equal}20 and 220 K. While these v{sup +}=0-12 PFI-PE bands represent the first rotationally resolved photoelectron data for O{sub 2}{sup +}(A {sup 2}{pi}{sub u}), the PFI-PE bands for O{sub 2}{sup +}(A {sup 2}{pi}{sub u},v{sup +}=9 and 10) are the first rotationally resolved spectroscopic data for these levels. The simulation also allows the determination of accurate ionization energies, vibrational constants, and rotational constants for O{sub 2}{sup +}(A {sup 2}{pi}{sub u},v{sup +}=0-12). The analysis of the PFI-PE spectra supports the conclusion of the previous emission study that the O{sub 2}{sup +}(A {sup 2}{pi}{sub u},v{sup +}=9 and 10) states are strongly perturbed by a nearby electronic state. (c) 2000 American Institute of Physics.

Analysis of energy efficiency of methane and hydrogen-methane blends in a PFI/DI SI research engine

International Nuclear Information System (INIS)

Catapano, F.; Di Iorio, S.; Sementa, P.; Vaglieco, B.M.

2016-01-01

In the last years, even more attention was paid to the alternative fuels that allow both reducing the fossil fuel consumption and the pollutant emissions. Gaseous fuels like methane and hydrogen are the most interesting in terms of engine application. This paper reports a comparison between methane and different methane/hydrogen mixtures in a single-cylinder Port Fuel/Direct Injection spark ignition (PFI/DI SI) engine operating under steady state conditions. It is representative of the gasoline engine for automotive application. Engine performance and exhaust emissions were evaluated. Moreover, 2D-digital cycle resolved imaging was performed with high spatial and temporal resolution in the combustion chamber. In particular, it allows characterizing the combustion by means of the flame propagation in terms of mean radius and velocity. Moreover, the interaction of turbulence with the local flame was evaluated. For both the engine configurations, it was observed that the addition of hydrogen results in a more efficient combustion, even though the engine configuration plays an important role. In PFI mode, the lower density of hydrogen causes a lower energy input. In DI mode, instead, the larger hydrogen diffusivity counteracts the charge stratification especially for larger hydrogen content. - Highlights: • The effect of hydrogen on methane combustion was investigated in an optical PFI/DI SI engine. • The effect of hydrogen addition for PFI and DI configurations was evaluated on the same engine. • The flame front propagation was characterized by means of 2-D digital imaging.

Laser-Based Spatio-Temporal Characterisation of Port Fuel Injection (PFI Sprays

Directory of Open Access Journals (Sweden)

C. T. N. Anand

2010-06-01

Full Text Available In the present work, detailed laser-based diagnostic experiments were conducted to characterise the spray from low pressure 2-hole and 4-hole Port Fuel Injection (PFI injectors. The main objective of the work included obtaining quantitative information of the spatio-temporal spray structure of such low-pressure gasoline sprays. A novel approach involving a combination of techniques such as Mie scattering, Granulometry, and Laser Sheet Dropsizing (LSD was used to study the spray structure. The droplet sizes, distributions with time, Sauter Mean Diameters (SMD, droplet velocities, cone angles and spray tip penetrations of the sprays from the injectors were determined. The spray from these injectors is found to be ‘pencil like’ and not dispersed as in high pressure sprays. The application of the above mentioned techniques provides two-dimensional SMD contours of the entire spray at different instants of time, with reasonable accuracy.

Studies on flame retardancy of radiation crosslinked PE foam

International Nuclear Information System (INIS)

Yang Huili; Yao Zhanhai; Xu Jun

1996-01-01

CPE, DBDPO and Sb 2 O 3 were used as flame-retardant of PE foam. Effect of CPE on PE foam under radiation and it's flame-retardancy were studied. The result showed that CPE can enhance radiation cross-linking of PE, and trinary of addition being made of CPE, DBDPO and Sb 2 O 3 made oxygen index of PE foam achieve over 30, and self-extinguish, it did not influence manufacture and mechanical properties of PE foam

INFRARED COLOR-COLOR DIAGRAMS FOR AGB STARS

Directory of Open Access Journals (Sweden)

Kyung-Won Suh

2007-09-01

Full Text Available We present infrared color-color diagrams of AGB stars from the observations at near and mid infrared bands. We compile the observations for hundreds of OH/IR stars and carbon stars using the data from the Midcourse Space Experiment (MSX, the two micron sky survey (2MASS, and the IRAS point source catalog (PSC. We compare the observations with the theoretical evolutionary tracks of AGB stars. From the new observational data base and the theoretical evolution tracks, we discuss the meaning of the infrared color-color diagrams at different wavelengths.

VUV optical ring resonator for Duke storage ring free electron laser

Energy Technology Data Exchange (ETDEWEB)

Park, S.H.; Litvinenko, V.N.; Madey, J.M.J. [Duke Univ., Durham, NC (United States)] [and others

1995-12-31

The conceptual design of the multifaceted-mirror ring resonator for Duke storage ring VUV FEL is presented. The expected performance of the OK-4 FEL with ring resonator is described. We discuss in this paper our plans to study reflectivity of VUV mirrors and their resistivity to soft X-ray spontaneous radiation from OK-4 undulator.

Experimental study of carbon materials behavior under high temperature and VUV radiation: Application to Solar Probe+ heat shield

International Nuclear Information System (INIS)

Eck, J.; Sans, J.-L.; Balat-Pichelin, M.

2011-01-01

The aim of the Solar Probe Plus (SP+) mission is to understand how the solar corona is heated and how the solar wind is accelerated. To achieve these goals, in situ measurements are necessary and the spacecraft has to approach the Sun as close as 9.5 solar radii. This trajectory induces extreme environmental conditions such as high temperatures and intense Vacuum Ultraviolet radiation (VUV). To protect the measurement and communication instruments, a heat shield constituted of a carbon material is placed on the top of the probe. In this study, the physical and chemical behavior of carbon materials is experimentally investigated under high temperatures (1600-2100 K), high vacuum (10 -4 Pa) and VUV radiation in conditions near those at perihelion for SP+. Thanks to several in situ and ex situ characterizations, it was found that VUV radiation induced modification of outgassing and of mass loss rate together with alteration of microstructure and morphology.

Experimental study of pyrolytic boron nitride at high temperature with and without proton and VUV irradiations

International Nuclear Information System (INIS)

Balat-Pichelin, M.; Eck, J.; Heurtault, S.; Glénat, H.

2014-01-01

Highlights: • New results for the high temperature study of pBN in high vacuum for the heat shield of solar probes. • Physico-chemical behavior of pBN studied up to 1700 K with proton and VUV irradiations. • Rather low effect of synergistic aggressions on the microstructure of pBN material. • The α/ε ratio of pBN coating on C/C measured up to 2200 K is 20% lower than for the C/C itself. - Abstract: In the frame of future exploration missions such as Solar Probe Plus (NASA) and PHOIBOS (ESA), research was carried out to study pyrolytic BN material envisaged as coating for their heat shields. The physico-chemical behavior of CVD pBN at very high temperature with or without hydrogen ions and VUV (Vacuum Ultra-Violet) irradiations was studied in high vacuum together with the in situ measurement of the thermal radiative properties conditioning the thermal equilibrium of the heat shield. Experimental results obtained on massive pBN samples are presented through in situ mass spectrometry and mass loss rate, and post-test microstructural characterization by XRD, SEM, AFM and nano-indentation techniques, some of them leading to mechanical properties. It could be concluded that synergistic effect of high temperature, protons and VUV radiation has an impact on the emission of gaseous species, the mass loss rate and the mechanical properties of the material

High-z X-ray Obscured Quasars in Galaxies with Extreme Mid-IR/Optical Colors

Science.gov (United States)

Piconcelli, E.; Lanzuisi, G.; Fiore, F.; Feruglio, C.; Vignali, C.; Salvato, M.; Grappioni, C.

2009-05-01

Extreme Optical/Mid-IR color cuts have been used to uncover a population of dust-enshrouded, mid-IR luminous galaxies at high redshifts. Several lines of evidence point towards the presence of an heavily absorbed, possibly Compton-thick quasar at the heart of these systems. Nonetheless, the X-ray spectral properties of these intriguing sources still remain largely unexplored. Here we present an X-ray spectroscopic study of a large sample of 44 extreme dust-obscured galaxies (EDOGs) with F24 μm/FR>2000 and F24 μm>1.3 mJy selected from a 6 deg2 region in the SWIRE fields. The application of our selection criteria to a wide area survey has been capable of unveiling a population of X-ray luminous, absorbed z>1 quasars which is mostly missed in the traditional optical/X-ray surveys performed so far. Advances in the understanding of the X-ray properties of these recently-discovered sources by Simbol-X observations will be also discussed.

Minerals from Macedonia. XII. The dependence of quartz and opal color on trace element composition - AAS, FT IR and micro-Raman spectroscopy study

International Nuclear Information System (INIS)

Makreski, Petre; Jovanovski, Gligor; Stafilov, Trajce; Boev, Blazho

2004-01-01

The dependence of the color of quartz and opal natural minerals, collected from different localities in the Republic of Macedonia (Alinci, Belutche, Budinarci, Mariovo, Sasa, Sazhdevo, Chanishte, Cheshinovo, Zletovo) on their element composition is studied using Fourier transform infrared spectroscopy (FT IR), micro-Raman spectroscopy and atomic absorption spectrometry (AAS). In order to determine the content of different trace elements (Al, Cd, Ca, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb and Zn), 15 quartz and 2 opal mineral samples, using flame atomic absorption spectrometry (FAAS) and Zeeman electrothermal atomic absorption spectrometry (ETAAS) are studied. To avoid matrix interferences, the method for elimination of silicium is proposed. Optimal instrumental parameters for ETAAS determination (temperature and time for drying, pyrolysis and atomizing) are established by extensive testing for each investigated element. It is found that the milky white color of quartz minerals is due to the presence of traces of Ca, the appearance of black color is the result of the existence of Pb, Mn and Al impurities, and the occurrence of Fe and Cr introduce appearance of red and green color, respectively. Preliminary identification of the minerals is based on the comparison of our results, obtained by using the infrared and Raman vibrational spectroscopy, with the corresponding literature data for the analogous mineral species originating all over the world. An overview of the basic morphological and physico-chemical characteristics of the quartz and opal minerals and the geology of the localities is given. The colored pictures of the studied quartz and opal minerals are presented as well. (Author)

Surface color perception under two illuminants: the second illuminant reduces color constancy

Science.gov (United States)

Yang, Joong Nam; Shevell, Steven K.

2003-01-01

This study investigates color perception in a scene with two different illuminants. The two illuminants, in opposite corners, simultaneously shine on a (simulated) scene with an opaque dividing wall, which controls how much of the scene is illuminated by each source. In the first experiment, the height of the dividing wall was varied. This changed the amount of each illuminant reaching objects on the opposite side of the wall. Results showed that the degree of color constancy decreased when a region on one side of the wall had cues to both illuminants, suggesting that cues from the second illuminant are detrimental to color constancy. In a later experiment, color constancy was found to improve when the specular highlight cues from the second illuminant were altered to be consistent with the first illuminant. This corroborates the influence of specular highlights in surface color perception, and suggests that the reduced color constancy in the first experiment is due to the inconsistent, though physically correct, cues from the two illuminants.

Two-color studies of autoionizing states of small molecules

International Nuclear Information System (INIS)

Pratt, S.T.; Dehmer, P.M.; Dehmer, J.L.; Tomkins, F.S.; O'Halloran, M.A.

1989-01-01

Two-color, resonantly enhanced multiphoton ionization is proving to be a valuable technique for the study of autoionizing states of small molecules. In this talk, results obtained by combining REMPI, photoelectron spectroscopy, and mass spectrometry will be discussed and will be illustrated by examples from our recent studies of rotational and vibrational autoionization in molecular hydrogen and rotational autoionization in nitric oxide. 2 refs., 1 fig

High sensitivity detection of desorbed biomolecules by photoionization with tunable VUV

International Nuclear Information System (INIS)

Moore, J.F.; Calaway, W.F.; Veryovkin, I.V.; Pellin, M.J.; Lewellen, J.W.; Li, Y.; Milton, S.V.; King, B.V.

2004-01-01

Full text: The spectral region from 7 to 11eV has two attributes that make it attractive for biomolecule photoionization: 1. high photoionization cross sections, leading to high detection efficiency, and 2. overlap with nearly all first ionization energies of biomolecules, allowing possible control over fragmentation by accessing different final states via tuning. The lack of available tunable lasers in this energy range has generally hindered exploitation of these features thus far. A free-electron laser in operation at Argonne National Laboratory provides high pulse energy, widely tunable VUV pulses of 300 fs duration. Coupled with a novel time-of-flight mass spectrometer, this laser is able to photoionize and detect biomolecules, including peptides and nucleosides. Either laser desorption or primary ion beams are used to desorb sample material, followed by photoionization with a VUV laser. The instrument uses novel ion optics to extract photoions from a large volume while maintaining high mass resolution. This approach is capable of yielding dramatically improved detection limits over more conventional methods such as MALDI and SIMS. In the case of the common peptide substance P, for example, a substantial improvement over the MALDI signal was observed using VUV photoionization with very little observed fragmentation of the molecule. Nucleosides and cisplatin were also measured with typically order of magnitude improvements in signal. These and other examples show clearly the benefits that can be obtained in high sensitivity mass spectrometry of biomolecules with the increasing availability of VUV laser sources

A VUV photoionization organic aerosol mass spectrometric study with synchrotron radiation

Energy Technology Data Exchange (ETDEWEB)

Fang Wenzheng; Lei Gong; Shan Xiaobin; Liu Fuyi [School of Nuclear Science and Technology, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Anhui, Hefei 230029 (China); Wang Zhenya [Laboratory of Environmental Spectroscopy, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031 (China); Sheng Liusi, E-mail: lssheng@ustc.edu.cn [School of Nuclear Science and Technology, National Synchrotron Radiation Laboratory, University of Science and Technology of China, Anhui, Hefei 230029 (China)

2011-04-15

Research highlights: {yields} A photoionization aerosol time-of-flight mass spectrometer (ATOFMS) has been developed for on-line analysis of organic compounds in aerosol particles using tunable vacuum ultraviolet (VUV) synchrotron radiation. {yields} The degree of fragmentation of molecule can be controlled either by the heater temperature or by the photon energy. {yields} The direct determination of the IEs of benzopheneone (9.07 eV), salicylic acid (8.72 eV), and urea (9.85 eV) are measured from the photoionization efficiency spectra. {yields} The species can be identified by their molecular and fragment ions weights as well as by the comparisions between their theoretical and experimental ionization energies. - Abstract: A photoionization aerosol time-of-flight mass spectrometer (ATOFMS) has been developed for on-line analysis of organic compounds in aerosol particles using tunable vacuum ultraviolet (VUV) synchrotron radiation. Aerosol particles can be sampled directly from atmospheric pressure and are focused through an aerodynamic lens assembly into the mass spectrometer. The particles are vaporized when they impact on a heater, and then the nascent vapor is softly photoionized by synchrotron radiation. The degree of fragmentation of molecule can be controlled either by the heater temperature or by the photon energy. Thus, fragment-free tunable VUV mass spectra are obtained by tuning the photon energy close to the ionization energies (IEs) of the sample molecules. The direct determination of the IEs of benzophenone (9.07 eV), salicylic acid (8.72 eV), and urea (9.85 eV) are measured from the photoionization efficiency spectra with uncertainties of {+-}50 meV. Ab initio calculations have been employed to predict the theoretical ionization energy.

VUV photo-processing of PAH cations: quantitative study on the ionization versus fragmentation processes.

Science.gov (United States)

Zhen, Junfeng; Castillo, Sarah Rodriguez; Joblin, Christine; Mulas, Giacomo; Sabbah, Hassan; Giuliani, Alexandre; Nahon, Laurent; Martin, Serge; Champeaux, Jean-Philippe; Mayer, Paul M

2016-05-10

Interstellar polycyclic aromatic hydrocarbons (PAHs) are strongly affected by the absorption of vacuum ultraviolet (VUV) photons in the interstellar medium (ISM), yet the branching ratio between ionization and fragmentation is poorly studied. This is crucial for the stability and charge state of PAHs in the ISM in different environments, affecting in turn the chemistry, the energy balance, and the contribution of PAHs to the extinction and emission curves. We studied the interaction of PAH cations with VUV photons in the 7 - 20 eV range from the synchrotron SOLEIL beamline, DESIRS. We recorded by action spectroscopy the relative intensities of photo-fragmentation and photo-ionization for a set of eight PAH cations ranging in size from 14 to 24 carbon atoms, with different structures. At photon energies below ~13.6 eV fragmentation dominates for the smaller species, while for larger species ionization is immediately competitive after the second ionization potential (IP). At higher photon energies, all species behave similarly, the ionization yield gradually increases, leveling off between 0.8 and 0.9 at ~18 eV. Among isomers, PAH structure appears to mainly affect the fragmentation cross section, but not the ionization cross section. We also measured the second IP for all species and the third IP for two of them, all are in good agreement with theoretical ones confirming that PAH cations can be further ionized in the diffuse ISM. Determining actual PAH dication abundances in the ISM will require detailed modeling. Our measured photo-ionization yields for several PAH cations provide a necessary ingredient for such models.

VUV PHOTO-PROCESSING OF PAH CATIONS: QUANTITATIVE STUDY ON THE IONIZATION VERSUS FRAGMENTATION PROCESSES

Energy Technology Data Exchange (ETDEWEB)

Zhen, Junfeng; Castillo, Sarah Rodriguez; Joblin, Christine; Mulas, Giacomo; Sabbah, Hassan [Université de Toulouse, UPS-OMP, Institut de Recherche en Astrophysique et Planétologie, Toulouse (France); Giuliani, Alexandre; Nahon, Laurent [Synchrotron SOLEIL, LOrme des Merisiers, F-91192 Gif sur Yvette Cedex (France); Martin, Serge [Institut Lumière Matière, Université Lyon 1-CNRS, Université de Lyon, F-69622 Villeurbanne cedex (France); Champeaux, Jean-Philippe [Laboratoire Collisions Agrégats Réactivité, Université de Toulouse, UPS-IRSAMC, CNRS, 118 Route de Narbonne, Bat 3R1B4, F-31062 Toulouse Cedex 9 (France); Mayer, Paul M., E-mail: christine.joblin@irap.omp.eu [Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa K1N 6N5 (Canada)

2016-05-10

Interstellar polycyclic aromatic hydrocarbons (PAHs) are strongly affected by the absorption of vacuum ultraviolet (VUV) photons in the interstellar medium (ISM), yet the branching ratio between ionization and fragmentation is poorly studied. This is crucial for the stability and charge state of PAHs in the ISM in different environments, affecting in turn the chemistry, the energy balance, and the contribution of PAHs to the extinction and emission curves. We studied the interaction of PAH cations with VUV photons in the 7–20 eV range from the synchrotron SOLEIL beamline, DESIRS. We recorded by action spectroscopy the relative intensities of photo-fragmentation and photo-ionization for a set of eight PAH cations ranging in size from 14 to 24 carbon atoms, with different structures. At photon energies below ∼13.6 eV fragmentation dominates for the smaller species, while for larger species ionization is immediately competitive after the second ionization potential (IP). At higher photon energies all species behave similarly; the ionization yield gradually increases, leveling off between 0.8 and 0.9 at ∼18 eV. Among isomers, PAH structure appears to mainly affect the fragmentation cross section but not the ionization cross section. We also measured the second IP for all species and the third IP for two of them; all are in good agreement with theoretical ones, confirming that PAH cations can be further ionized in the diffuse ISM. Determining actual PAH dication abundances in the ISM will require detailed modeling. Our measured photo-ionization yields for several PAH cations provide a necessary ingredient for such models.

VUV PHOTO-PROCESSING OF PAH CATIONS: QUANTITATIVE STUDY ON THE IONIZATION VERSUS FRAGMENTATION PROCESSES

International Nuclear Information System (INIS)

Zhen, Junfeng; Castillo, Sarah Rodriguez; Joblin, Christine; Mulas, Giacomo; Sabbah, Hassan; Giuliani, Alexandre; Nahon, Laurent; Martin, Serge; Champeaux, Jean-Philippe; Mayer, Paul M.

2016-01-01

Interstellar polycyclic aromatic hydrocarbons (PAHs) are strongly affected by the absorption of vacuum ultraviolet (VUV) photons in the interstellar medium (ISM), yet the branching ratio between ionization and fragmentation is poorly studied. This is crucial for the stability and charge state of PAHs in the ISM in different environments, affecting in turn the chemistry, the energy balance, and the contribution of PAHs to the extinction and emission curves. We studied the interaction of PAH cations with VUV photons in the 7–20 eV range from the synchrotron SOLEIL beamline, DESIRS. We recorded by action spectroscopy the relative intensities of photo-fragmentation and photo-ionization for a set of eight PAH cations ranging in size from 14 to 24 carbon atoms, with different structures. At photon energies below ∼13.6 eV fragmentation dominates for the smaller species, while for larger species ionization is immediately competitive after the second ionization potential (IP). At higher photon energies all species behave similarly; the ionization yield gradually increases, leveling off between 0.8 and 0.9 at ∼18 eV. Among isomers, PAH structure appears to mainly affect the fragmentation cross section but not the ionization cross section. We also measured the second IP for all species and the third IP for two of them; all are in good agreement with theoretical ones, confirming that PAH cations can be further ionized in the diffuse ISM. Determining actual PAH dication abundances in the ISM will require detailed modeling. Our measured photo-ionization yields for several PAH cations provide a necessary ingredient for such models.

VUV photo-processing of PAH cations: quantitative study on the ionization versus fragmentation processes

Science.gov (United States)

Zhen, Junfeng; Castillo, Sarah Rodriguez; Joblin, Christine; Mulas, Giacomo; Sabbah, Hassan; Giuliani, Alexandre; Nahon, Laurent; Martin, Serge; Champeaux, Jean-Philippe; Mayer, Paul M.

2016-01-01

Interstellar polycyclic aromatic hydrocarbons (PAHs) are strongly affected by the absorption of vacuum ultraviolet (VUV) photons in the interstellar medium (ISM), yet the branching ratio between ionization and fragmentation is poorly studied. This is crucial for the stability and charge state of PAHs in the ISM in different environments, affecting in turn the chemistry, the energy balance, and the contribution of PAHs to the extinction and emission curves. We studied the interaction of PAH cations with VUV photons in the 7 – 20 eV range from the synchrotron SOLEIL beamline, DESIRS. We recorded by action spectroscopy the relative intensities of photo-fragmentation and photo-ionization for a set of eight PAH cations ranging in size from 14 to 24 carbon atoms, with different structures. At photon energies below ~13.6 eV fragmentation dominates for the smaller species, while for larger species ionization is immediately competitive after the second ionization potential (IP). At higher photon energies, all species behave similarly, the ionization yield gradually increases, leveling off between 0.8 and 0.9 at ~18 eV. Among isomers, PAH structure appears to mainly affect the fragmentation cross section, but not the ionization cross section. We also measured the second IP for all species and the third IP for two of them, all are in good agreement with theoretical ones confirming that PAH cations can be further ionized in the diffuse ISM. Determining actual PAH dication abundances in the ISM will require detailed modeling. Our measured photo-ionization yields for several PAH cations provide a necessary ingredient for such models. PMID:27212712

Third-generation intelligent IR focal plane arrays

Science.gov (United States)

Caulfield, H. John; Jack, Michael D.; Pettijohn, Kevin L.; Schlesselmann, John D.; Norworth, Joe

1998-03-01

SBRC is at the forefront of industry in developing IR focal plane arrays including multi-spectral technology and '3rd generation' functions that mimic the human eye. 3rd generation devices conduct advanced processing on or near the FPA that serve to reduce bandwidth while performing needed functions such as automatic target recognition, uniformity correction and dynamic range enhancement. These devices represent a solution for processing the exorbitantly high bandwidth coming off large area FPAs without sacrificing systems sensitivity. SBRC's two-color approach leverages the company's HgCdTe technology to provide simultaneous multiband coverage, from short through long wave IR, with near theoretical performance. IR systems that are sensitive to different spectral bands achieve enhanced capabilities for target identification and advanced discrimination. This paper will provide a summary of the issues, the technology and the benefits of SBRC's third generation smart and two-color FPAs.

UV and VUV photolysis vs. UV/H2O2 and VUV/H2O2, treatment for removal of clofibric acid from aqueous solution.

Science.gov (United States)

Li, Wenzhen; Lu, Shuguang; Qiu, Zhaofu; Lin, Kuangfei

2011-07-01

Clofibric acid (CA), a metabolite of lipid regulators, was investigated in ultra-pure water and sewage treatment plant (STP) effluent at 10 degrees C under UV, vacuum UV (VUV), UV/H2O2 and VUV/H2O2 processes. The influences of NO3-, HCO3- and humic acid (HA) on CA photolysis in all processes were examined. The results showed that all the experimental data well fitted the pseudo-first-order kinetic model, and the apparent rate constant (k(ap)) and half-life time (t(1/2)) were calculated accordingly. Direct photolysis of CA through UV irradiation was the main process, compared with the indirect oxidation of CA due to the slight generation of hydroxyl radicals dissociated from water molecules under UV irradiation below 200 nm monochromatic wavelength emission. In contrast, indirect oxidation was the main CA degradation mechanism in UV/H2O2 and VUV/H2O2, and VUV/H2O2 was the most effective process for CA degradation. The addition of 20 mg L(-1) HA could significantly inhibit CA degradation, whereas, except for UV irradiation, the inhibitive effects of NO3- and HCO3- (1.0 x 10(-3) and 0.1 mol L(-1), respectively) on CA degradation were observed in all processes, and their adverse effects were more significant in UV/H2O2 and VUV/H2O2 processes, particularly at the high NO3- and HCO3- concentrations. The degradation rate decreased 1.8-4.9-fold when these processes were applied to a real STP effluent owing to the presence of complex constituents. Of the four processes, VUV/H2O2 was the most effective, and the CA removal efficiency reached over 99% after 40 min in contrast to 80 min in both the UV/H2O2 and VUV processes and 240 min in the UV process.

Photochemical decomposition of perfluorooctanoic acid in aqueous periodate with VUV and UV light irradiation

International Nuclear Information System (INIS)

Cao, M.H.; Wang, B.B.; Yu, H.S.; Wang, L.L.; Yuan, S.H.; Chen, J.

2010-01-01

The photochemical decomposition of perfluorooctanoic acid (PFOA) in aqueous periodate (IO 4 - ) was investigated under two types of low-pressure mercury lamps: one emits at 254 nm light (UV light) and the other emits both 254 nm and 185 nm light (VUV light). PFOA decomposed efficiently under VUV light irradiation while it decomposed poorly under UV light irradiation. The addition of IO 4 - significantly increased the rate of decomposition and defluorination of PFOA irradiated with UV light whereas it decreased both processes under VUV irradiation. Reactive radical (IO 3 ·) generated by photolysis of IO 4 - initiated the oxidation of PFOA in UV process. Aquated electrons (e aq - ), generated from water homolysis, scavenged IO 4 - resulting in decrease of reactive radical species production and PFOA decomposition. The shorter-chain perfluorocarboxylic acids (PFCAs) formed in a stepwise manner from long-chain PFCAs.

Study of the absorption and energy transfer processes in inorganic luminescent materials in the UV and VUV region

International Nuclear Information System (INIS)

Mayolet, A.

1995-01-01

In order to find a green emitting phosphor showing high quantum efficiency and a short decay time which can be used in the color Plasma Display Panels developed by Thomson-TTE-TIV company, a VUV spectrophotometer built at IPN Orsay, using the synchrotron radiation from the SUPER-ACO storage ring as an excitation source, allow us the simultaneous recording of the luminescence excitation and diffuse reflectivity spectra of the inorganic compounds in the UV-VUV range. In addition, this experimental set-up enable us to determine the luminescence quantum efficiency of phosphors in the whole energy range of investigation. The chemical synthesis of rare-earth ortho-- and metaborate and rare-earth ortho- and metaphosphate doped with trivalent lanthanide ions cerium, praseodymium, europium and terbium have been made. The energy variation of the thresholds of the luminescence excitation mechanisms in function of the nature and the structure of the host matrix is discussed. We have determined the influence of the nephelauxetic effect and the crystal field intensity on the energy of the f-d inter-configuration transitions. The variation of the luminescence quantum efficiency of the dopant ion is interpreted through the 'impurity bound exciton' model. The systematic comparison of the cerium and terbium trivalent ions spectroscopic properties in the Y(AG)G host lattice series stands to reason that the self-ionized state of the luminescent center plays an important role in the rate of the non radiative relaxation. It is the redox power of the host matrix which imposes to the luminescent center, the energy of this state. (author)

Real-time monitoring of trace-level VOCs by an ultrasensitive compact lamp-based VUV photoionization mass spectrometer

Science.gov (United States)

Sun, W. Q.; Shu, J. N.; Zhang, P.; Li, Z.; Li, N. N.; Liang, M.; Yang, B.

2015-06-01

In this study, we report on the development of a compact lamp-based vacuum ultraviolet (VUV) photoionization mass spectrometer (PIMS; hereafter referred to as VUV-PIMS) in our laboratory; it is composed of a radio frequency-powered VUV lamp, a VUV photoionizer, an ion-immigration region, and a reflection time-of-flight mass spectrometer. By utilizing the novel photoionizer consisting of a photoionization cavity and a VUV light baffle, extremely low background noise was obtained. An ultrasensitive detection limit (2σ) of 3 pptv was achieved for benzene after an acquisition time of 10 s. To examine its potential for application in real-time sample monitoring, the developed VUV-PIMS was employed for the continuous measurement of urban air for six days in Beijing, China. Strong signals of trace-level volatile organic compounds such as benzene and its alkylated derivatives were observed in the mass spectra. These initial experimental results reveal that the instrument can be used for the online monitoring of trace-level species in the atmosphere.

Probing Xe electronic structure by two-color HHG

International Nuclear Information System (INIS)

Faccialà, D; Ciriolo, A G; De Silvestri, S; Devetta, M; Negro, M; Stagira, S; Vozzi, C; Pabst, S; Bruner, B D; Dudovich, N; Soifer, H

2015-01-01

The aim of this study is probing the multi-electron behavior in xenon by two-color driven high harmonic generation. By changing the relative polarization of the two colors we were able to study different aspects of the multi-electron response. (paper)

Gas-filled cell as a narrow bandwidth bandpass filter in the VUV wavelength range

Energy Technology Data Exchange (ETDEWEB)

Geloni, Gianluca [European XFEL GmbH, Hamburg (Germany); Kocharyan, Vitali; Saldin, Evgeni [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)

2011-04-15

We propose a method for spectrally filtering radiation in the VUV wavelength range by means of a monochromator constituted by a cell filled with a resonantly absorbing rare gas. Around particular wavelengths, the gas exhibits narrow-bandwidth absorbing resonances following the Fano profile. In particular, within the photon energy range 60 eV-65 eV, the correlation index of the Fano profiles for the photoionization spectra in Helium is equal to unity, meaning that the minimum of the cross-section is exactly zero. For sufficiently large column density in the gas cell, the spectrum of the incoming radiation will be attenuated by the background cross-section of many orders of magnitude, except for those wavelengths close to the point where the cross-section is zero. Remarkable advantages of a gas monochromator based on this principle are simplicity, efficiency and narrow-bandwidth. A gas monochromator installed in the experimental hall of a VUV SASE FEL facility would enable the delivery of a single-mode VUV laser beam. The design is identical to that of already existing gas attenuator systems for VUV or X-ray FELs. We present feasibility study and exemplifications for the FLASH facility in the VUV regime. (orig.)

Young's double-slit interference with two-color biphotons.

Science.gov (United States)

Zhang, De-Jian; Wu, Shuang; Li, Hong-Guo; Wang, Hai-Bo; Xiong, Jun; Wang, Kaige

2017-12-12

In classical optics, Young's double-slit experiment with colored coherent light gives rise to individual interference fringes for each light frequency, referring to single-photon interference. However, two-photon double-slit interference has been widely studied only for wavelength-degenerate biphoton, known as subwavelength quantum lithography. In this work, we report double-slit interference experiments with two-color biphoton. Different from the degenerate case, the experimental results depend on the measurement methods. From a two-axis coincidence measurement pattern we can extract complete interference information about two colors. The conceptual model provides an intuitional picture of the in-phase and out-of-phase photon correlations and a complete quantum understanding about the which-path information of two colored photons.

Effect of various de-anodizing techniques on the surface stability of non-colored and colored nanoporous AAO films in acidic solution

Energy Technology Data Exchange (ETDEWEB)

Awad, Ahmed M. [Chemical Engineering & Pilot Plant Department, National Research Centre, Dokki, Giza (Egypt); Shehata, Omnia S. [Physical Chemistry Department, National Research Centre, Dokki, Giza (Egypt); Heakal, Fakiha El-Taib, E-mail: fakihaheakal@yahoo.com [Chemistry Department, Faculty of Science, Cairo University, Giza 12613 (Egypt)

2015-12-30

Highlights: • Three de-anodization methods were used during two-step fabrication of nanoporous AAO. • Electrolytic etching (EE), chemical etching with H{sub 3}PO{sub 4} (PE) or NaOH (HE) were adopted. • After the second anodizing step, HE film was the thinnest as compared to EE and HE. • Stability order of nanoporous AAO films in 0.5 M HCl solution was: PE > EE > HE. • For the colored films by electrodeposited Cu atoms, the order was: HE > EE > PE. - Abstract: Anodic aluminum oxide (AAO) is well known as an important nanostructured material, and a useful template in the fabrication of nanostructures. Nanoporous anodic alumina (PAA) with high open porosity was prepared by adopting three de-anodizing regimes following the first anodizing step and preceding the second one. The de-anodizing methods include electrolytic etching (EE) and chemical etching using either phosphoric acid (PE) or sodium hydroxide (HE) solutions. Three of the obtained AAO samples were black colored by electrodeposition of copper nanoparticles in their pores. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques were used to characterize the electrochemical performance of the two sets of the prepared samples. In general, the data obtained in aggressive aerated 0.5 M HCl solution demonstrated dissimilar behavior for the three prepared samples despite that the second anodizing step was the same for all of them. The data indicated that the resistance and thickness of the inner barrier part of nano-PAA film, are the main controlling factors determining its stability. On the other hand, coloring the film decreased its stability due to the galvanic effect. The difference in the electrochemical behavior of the three colored samples was discussed based on the difference in both the pore size and thickness of the outer porous part of PAA film as supported by SEM, TEM and cross-sectional micrographs. These results can thus contribute for better engineering

VUV Study of Electron-Pyrimidine Dissociative Excitation

Science.gov (United States)

Hein, Jeff; Al-Khazraji, Hajar; Tiessen, Collin; Lukic, Dragan; Trocchi, Joshuah; McConkey, William

2013-05-01

A crossed electron-gas beam system coupled to a VUV spectrometer has been used to investigate the dissociation of pyrimidine (C4H4N2) into excited atomic fragments in the electron-impact energy range from threshold to 375 eV. Data have been made absolute using Lyman- α from H2 as a secondary standard. The main features in the spectrum are the H Lyman series lines. The emission cross section of Lyman- α is measured to be (2.44 +/- 0.25) 10-18 cm2 at 100 eV impact energy. The probability of extracting C or N atoms from the ring is shown to be very small. Possible dissociation channels and excitation mechanisms in the parent molecule will be discussed. The authors thank NSERC (Canada) for financial support.

Synthesis and photophysical studies of blue phosphorescent Ir(III) complexes with dimethylphenylphospine.

Science.gov (United States)

Ham, Ho-Wan; Jung, Kyung-Yoon; Kim, Young-Sik

2012-02-01

New blue emitting mixed ligand iridium(III) complexes comprising one cyclometalating, two phosphines trans to each other such as Ir{(CF3)2Meppy}(PPhMe3)2(H)(L) [L = CI, NCMe, CN] [(CF3)2Meppy = 2-(3', 5'-bis-trifluoromethylphenyl)-4-methylpyridine] were synthesized and studied to tune the phosphorescence wavelength to the deep blue region and to enhance the luminescence efficiencies. To achieve deep blue emission, the trifluoromethyl group substituted on the phenyl ring and the methyl group substituted on the pyridyl ring increased HOMO-LUMO gap and achieved the hypsochromic shift. To gain insight into the factors responsible for the emission color change and the different luminescence efficiency, we investigate the electron-withdrawing capabilities of ancillary ligands using the DFT and TD-DFT calculations on the ground and excited states of the complexes. From these results, we discuss how the ancillary ligand influences the emission peak as well as the metal to ligand charge transfer (MLCT) transition efficiency. The maximum emission spectra of Ir{(CF3)2Meppy}(PPhMe3)2(H)(Cl), [Ir{(CF3),Meppy)(PPhMe3),(H)(NCMe)]+ and Ir{(CF3)2Meppy}(PPhMe3)2(H)(CN) were in the ranges of 441, 435, 434 nm, respectively.

VUV/UV light inducing accelerated phenol degradation with a low electric input.

Science.gov (United States)

Li, Mengkai; Wen, Dong; Qiang, Zhimin; Kiwi, John

2017-01-23

This study presents the first evidence for the accelerated degradation of phenol by Fenton's reagent in a mini-fluidic VUV/UV photoreaction system (MVPS). A low-pressure mercury lamp used in the MVPS led to a complete degradation of phenol within 4-6 min. The HO˙ and HO 2 ˙ originating from both Fenton's reagent and VUV photolysis of water were identified with suitable radical scavengers. The effects of initial concentrations of phenol, H 2 O 2 and Fe 3+ as well as solution pH on phenol degradation kinetics were examined. Increasing the initial phenol concentration slowed down the phenol degradation, whereas increasing the initial H 2 O 2 or Fe 3+ concentration accelerated the phenol degradation. The optimal solution pH was 3.7. At both 254 and 185 nm, increasing phenol concentration enhanced its absorption for the incident photons. The reaction mechanism for the degradation of phenol was suggested consistent with the results obtained. This study indicates that the VUV/UV photo-Fenton process has potential applications in the treatment of industrial wastewater containing phenol and related aromatic pollutants.

GOODS-HERSCHEL: SEPARATING HIGH-REDSHIFT ACTIVE GALACTIC NUCLEI AND STAR-FORMING GALAXIES USING INFRARED COLOR DIAGNOSTICS

Energy Technology Data Exchange (ETDEWEB)

Kirkpatrick, Allison; Pope, Alexandra [Department of Astronomy, University of Massachusetts, Amherst, MA 01002 (United States); Charmandaris, Vassilis [Department of Physics and Institute of Theoretical and Computational Physics, University of Crete, GR-71003, Heraklion (Greece); Daddi, Emmanuele; Elbaz, David; Pannella, Maurilio; Aussel, Herve; Dasyra, Kalliopi; Leiton, Roger [Laboratoire AIM, CEA/DSM-CNRS-Universite Paris Diderot, Irfu/SAp, Orme des Merisiers, F-91191 Gif-sur-Yvette (France); Hwang, Ho Seong [Smithsonian Astrophysical Observatory, 60 Garden Street, Cambridge, MA 02138 (United States); Scott, Douglas; Magnelli, Benjamin; Popesso, Paola [Max-Planck-Institut fuer Extraterrestrische Physik (MPE), Postfach 1312, D-85741, Garching (Germany); Altieri, Bruno; Coia, Daniela; Valtchanov, Ivan [Herschel Science Centre, European Space Astronomy Centre, Villanueva de la Canada, E-28691 Madrid (Spain); Dannerbauer, Helmut [Universitaet Wien, Institut fuer Astrophysik, Tuerkenschanzstrasse 17, A-1180 Wien (Austria); Dickinson, Mark; Kartaltepe, Jeyhan [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Magdis, Georgios [Department of Physics, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom)

2013-02-15

We have compiled a large sample of 151 high-redshift (z = 0.5-4) galaxies selected at 24 {mu}m (S {sub 24} > 100 {mu}Jy) in the GOODS-N and ECDFS fields for which we have deep Spitzer IRS spectroscopy, allowing us to decompose the mid-infrared spectrum into contributions from star formation and activity in the galactic nuclei. In addition, we have a wealth of photometric data from Spitzer IRAC/MIPS and Herschel PACS/SPIRE. We explore how effective different infrared color combinations are at separating our mid-IR spectroscopically determined active galactic nuclei from our star-forming galaxies. We look in depth at existing IRAC color diagnostics, and we explore new color-color diagnostics combining mid-IR, far-IR, and near-IR photometry, since these combinations provide the most detail about the shape of a source's IR spectrum. An added benefit of using a color that combines far-IR and mid-IR photometry is that it is indicative of the power source driving the IR luminosity. For our data set, the optimal color selections are S {sub 250}/S {sub 24} versus S {sub 8}/S {sub 3.6} and S {sub 100}/S {sub 24} versus S {sub 8}/S {sub 3.6}; both diagnostics have {approx}10% contamination rate in the regions occupied primarily by star-forming galaxies and active galactic nuclei, respectively. Based on the low contamination rate, these two new IR color-color diagnostics are ideal for estimating both the mid-IR power source of a galaxy when spectroscopy is unavailable and the dominant power source contributing to the IR luminosity. In the absence of far-IR data, we present color diagnostics using the Wide-field Infrared Survey Explorer mid-IR bands which can efficiently select out high-z (z {approx} 2) star-forming galaxies.

UV-VUV FEL program at DUKE storage ring with OK-4 optical klystron

International Nuclear Information System (INIS)

Litvinenko, V.N.; Madey, J.M.J.; Vinokurov, N.A.

1993-01-01

A 1 GeV electron storage ring dedicated for UV-VUV FEL operation is under construction at the Duke University Free Electron Laser Laboratory. The UV-VUV-FEL project, based on the collaboration of the Duke FEL Laboratory and Budker Institute for Nuclear Physics is described. The main parameters of the DFELL storage ring, of the OK-4 optical klystron, and the experimental set-up are presented. The parameters of UV-VUV FEL are given and the possible future upgrades to this system are discussed

VUV-soft x-ray beamline for spectroscopy and calibration

International Nuclear Information System (INIS)

Bartlett, R.J.; Trela, W.J.; Michaud, F.D.; Southworth, S.H.; Rothe, R.; Alkire, R.W.

1986-01-01

The authors describe the design and performance of the Los Alamos VUV synchrotron radiation beamline, U3C, on the VUV ring of the National Synchrotron Light Source at Brookhaven National Laboratory. The beamline uses separate function optics to collect and focus the horizontally and vertically diverging beam. The monochromator is a grazing incidence Roland circle instrument of the extended grasshopper design (ERG). A post monochromator refocusing mirror is used to focus or collimate the diverging beam from the monochromator. The beamline control and diagnostics systems are also discussed

IR emission and UV extinction in two open clusters

International Nuclear Information System (INIS)

Hackwell, J.A.; Hecht, J.H.

1989-01-01

Recent models of interstellar extinction have shown the importance of understanding both the UV and IR properties of interstellar dust grains. IRAS data have shown variations in 60 and 100 micron emissions presumably due to the presence of IR cirrus, while recent observations in the UV by Fitzpatrick and Massa have identified components in the UV extinction curve which vary in different star regions. A Draine and Anderson model connects these results by proposing that different size variations in interstellar grains would cause distinct changes in both the IR emission and the UV extinction. In order to test this model it is necessary to make observations in well defined locations away from peculiar extinction regions. In the infrared this means looking away from the galactic plane so as to limit non-local sources of IR radiation. Two open clusters that are out of the galactic plane and which contain a number of late B and early A stars suitable for UV extinction studies, and whose IRAS data show variations in the 60/100 micron ratio were studied. Based on the Drain and Anderson model, variations were expected in their UV extinction curves that correlate with the IR cirrus emission

A Study of Color Transformation on Website Images for the Color Blind

OpenAIRE

Siew-Li Ching; Maziani Sabudin

2010-01-01

In this paper, we study on color transformation method on website images for the color blind. The most common category of color blindness is red-green color blindness which is viewed as beige color. By transforming the colors of the images, the color blind can improve their color visibility. They can have a better view when browsing through the websites. To transform colors on the website images, we study on two algorithms which are the conversion techniques from RGB colo...

National synchrotron light source user's manual: Guide to the VUV and x-ray beamlines: Third edition

International Nuclear Information System (INIS)

Gmuer, N.F.; Thomlinson, W.; White-DePace, S.

1989-01-01

This report contains information on the following topics: A Word on the Writing of Beamline Descriptions; Beamline Equipment Utilization for General Users; the Vacuum Ultraviolet (VUV) Storage Ring and Beamlines; VUV Beamline Descriptions--An Explanation; VUV Beamline Descriptions; X-Ray Storage Ring and Beamlines; X-Ray Beamline Descriptions--An Explanation; and X-Ray Beamline Descriptions

Applications of UV-storage ring free electron lasers: the case of super-ACO

CERN Document Server

Nahon, L; Couprie, Marie Emmanuelle; Merola, F; Dumas, P; Marsi, M; Taleb-Ibrahimi, A; Nutarelli, D; Roux, R; Billardon, M

1999-01-01

The potential of UV-storage ring free electron lasers (SRFELs) for the performance of original application experiments is shown with a special emphasis concerning their combination with the naturally synchronized synchrotron radiation (SR). The first two-color FEL+SR experiment, performed in surface science at Super-ACO is reported. The experimental parameters found to be the most important as gathered from the acquired experience, are underlined and discussed. Finally, future prospects for the scientific program of the Super-ACO FEL are presented with two-color experiments combining the FEL with SR undulator-based XUV and VUV beamlines as well as with a SR white light bending magnet beamline emiting in the IR-UV (20 mu m-0.25 mu m).

Photodissociation and photoionization of organosulfur radicals

International Nuclear Information System (INIS)

Hsu, Chia-Wei.

1994-01-01

The dynamics of S( 3 P 2,1,0 , 1 D 2 ) production from the 193 nm photodissociation of CH 3 SCH 3 , H 2 S and CH 3 SH have been studied using 2 + 1 resonance-enhanced multiphoton ionization (REMPI) techniques. The 193 nm photodissociation cross sections for the formation of S from CH 3 S and HS initially prepared in the photodissociation of CH 3 SCH 3 and H 2 S are estimated to be 1 x 10 -18 and 1.1 x 10 -18 cm 2 , respectively. The dominant product from CH 3 S is S( 1 D), while that from SH is S( 3 P). Possible potential energy surfaces involved in the 193 nm photodissociation of CH 3 S(X) and SH(X) have been also examined. Threshold photoelectron (PE) spectra for SH and CH 3 S formed in the ultraviolet photodissociation of H 2 S and CH 3 SH, respectively, have been measured using the nonresonant two-photon pulsed field ionization (N2P-PFI) technique. The rotationally resolved N2P-PFI-PE spectrum obtained for SH indicates that photoionization dynamics favors the rotational angular momentum change ΔN 2 product 3,2 ) and CH 3 S(X 2 E 3/2 ) are determined to be 84,057.5 ± 3 cm -1 and 74,726 ± 8 cm -1 respectively. The spin-orbit splittings for SH(X 2 product 3/2,1/2 ) and CH 3 S(X 2 E 3/2,1/2 ) are found to be 377 ± 2 and 257 ± 5 cm -1 , respectively, in agreement with previous measurements. The C-S stretching frequency for CH 3 S + (X 3 A 2 ) is 733 ± 5 cm -1 . This study illustrates that the PFI-PE detection method can be a sensitive probe for the nascent internal energy distribution of photoproducts

Study of the absorption and energy transfer processes in inorganic luminescent materials in the UV and VUV region; Etude des processus d`absorption et de transfert d`energie au sein de materiaux inorganiques luminescents dans le domaine UV et VUV

Energy Technology Data Exchange (ETDEWEB)

Mayolet, A

1995-11-29

In order to find a green emitting phosphor showing high quantum efficiency and a short decay time which can be used in the color Plasma Display Panels developed by Thomson-TTE-TIV company, a VUV spectrophotometer built at IPN Orsay, using the synchrotron radiation from the SUPER-ACO storage ring as an excitation source, allow us the simultaneous recording of the luminescence excitation and diffuse reflectivity spectra of the inorganic compounds in the UV-VUV range. In addition, this experimental set-up enable us to determine the luminescence quantum efficiency of phosphors in the whole energy range of investigation. The chemical synthesis of rare-earth ortho-- and metaborate and rare-earth ortho- and metaphosphate doped with trivalent lanthanide ions cerium, praseodymium, europium and terbium have been made. The energy variation of the thresholds of the luminescence excitation mechanisms in function of the nature and the structure of the host matrix is discussed. We have determined the influence of the nephelauxetic effect and the crystal field intensity on the energy of the f-d inter-configuration transitions. The variation of the luminescence quantum efficiency of the dopant ion is interpreted through the `impurity bound exciton` model. The systematic comparison of the cerium and terbium trivalent ions spectroscopic properties in the Y(AG)G host lattice series stands to reason that the self-ionized state of the luminescent center plays an important role in the rate of the non radiative relaxation. It is the redox power of the host matrix which imposes to the luminescent center, the energy of this state. (author) 134 refs.

VUV action spectroscopy of protonated leucine-enkephalin peptide in the 6-14 eV range

Energy Technology Data Exchange (ETDEWEB)

Ranković, M. Lj. [Institute of Physics Belgrade, University of Belgrade, Pregrevica 118, 11080 Belgrade (Serbia); Canon, F. [INRA, UMR1324 Centre des Sciences du Goût et de l’Alimentation, F-21000 Dijon (France); Nahon, L. [SOLEIL, l’Orme des Merisiers, St Aubin, BP48, 91192 Gif sur Yvette Cedex (France); Giuliani, A. [SOLEIL, l’Orme des Merisiers, St Aubin, BP48, 91192 Gif sur Yvette Cedex (France); INRA, UAR1008, CEPIA, Rue de la Géraudière, BP 71627, 44316 Nantes (France); Milosavljević, A. R., E-mail: vraz@ipb.ac.rs [Institute of Physics Belgrade, University of Belgrade, Pregrevica 118, 11080 Belgrade (Serbia); Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

2015-12-28

We have studied the Vacuum Ultraviolet (VUV) photodissociation of gas-phase protonated leucine-enkephalin peptide ion in the 5.7 to 14 eV photon energy range by coupling a linear quadrupole ion trap with a synchrotron radiation source. We report VUV activation tandem mass spectra at 6.7, 8.4, and 12.8 eV photon energies and photodissociation yields for a number of selected fragments. The obtained results provide insight into both near VUV radiation damage and electronic properties of a model peptide. We could distinguish several absorption bands and assign them to particular electronic transitions, according to previous theoretical studies. The photodissociation yields appear to be very different for the various observed fragmentation channels, depending on both the types of fragments and their position along the peptide backbone. The present results are discussed in light of recent gas-phase spectroscopic data on peptides.

Design study for a two-color beta measurement system

Science.gov (United States)

1982-01-01

Design analysis of the beam splitter combined two color beta system is presented. Conventional and dichroic beam splitters are discussed. Design analysis of the beta system employing two beams with focusing at separate points is presented. Alterations and basic parameters of the two beam system are discussed. Alterations in the focus of the initial laser and the returning beams are also discussed. Heterodyne efficiencies for the on axis and off axis reflected radiation are included.

Study on Angelica and its different extracts by Fourier transform infrared spectroscopy and two-dimensional correlation IR spectroscopy

Science.gov (United States)

Liu, Hong-xia; Sun, Su-qin; Lv, Guang-hua; Chan, Kelvin K. C.

2006-05-01

In order to develop a rapid and effective analysis method for studying integrally the main constituents in the medicinal materials and their extracts, discriminating the extracts from different extraction process, comparing the categories of chemical constituents in the different extracts and monitoring the qualities of medicinal materials, we applied Fourier transform infrared spectroscopy (FT-IR) associated with second derivative infrared spectroscopy and two-dimensional correlation infrared spectroscopy (2D-IR) to study the main constituents in traditional Chinese medicine Angelica and its different extracts (extracted by petroleum ether, ethanol and water in turn). The findings indicated that FT-IR spectrum can provide many holistic variation rules of chemical constituents. Use of the macroscopical fingerprint characters of FT-IR and 2D-IR spectrum can not only identify the main chemical constituents in medicinal materials and their different extracts, but also compare the components differences among the similar samples. This analytical method is highly rapid, effective, visual and accurate for pharmaceutical research.

Imaging with Mass Spectrometry: A SIMS and VUV-Photoionization Study of Ion-Sputtered Atoms and Clusters from GaAs and Au

Energy Technology Data Exchange (ETDEWEB)

Takahashi, Lynelle; Zhou, Jia; Wilson, Kevin R.; Leone, Stephen R.; Ahmed, Musahid

2008-12-05

A new mass spectrometry surface imaging method is presented in which ion-sputtered neutrals are postionized by wavelength-tunable vacuum ultraviolet (VUV) light from a synchrotron source. Mass spectra and signal counts of the photoionized neutrals from GaAs (100) and Au are compared to those of the secondary ions. While clusters larger than dimers are more efficiently detected as secondary ions, certain species, such as As2, Au and Au2, are more efficiently detected through the neutral channel. Continuously tuning the photon wavelength allows photoionization efficiency (PIE) curves to be obtained for sputtered Asm (m=1,2) and Aun (n=1-4). From the observed ionization thresholds, sputtered neutral As and Au show no clear evidence of electronic excitation, while neutral clusters have photoionization onsets shifted to lower energies by ~;;0.3 eV. These shifts are attributed to unresolved vibrational and rotational excitations. High-spatial resolution chemical imaging with synchrotron VUV postionization is demonstrated at two different photon energies using a copper TEM grid embedded in indium. The resulting images are used to illustrate the use of tunable VUV light for verifying mass peak assignments by exploiting the unique wavelength-dependent PIE of each sputtered neutral species. This capability is valuable for identifying compounds when imaging chemically complex systems with mass spectrometry-based techniques.

VUV photoionization of acetamide studied by electron/ion coincidence spectroscopy in the 8–24 eV photon energy range

International Nuclear Information System (INIS)

Schwell, Martin; Bénilan, Yves; Fray, Nicolas; Gazeau, Marie-Claire; Es-Sebbar, Et.; Garcia, Gustavo A.; Nahon, Laurent; Champion, Norbert; Leach, Sydney

2012-01-01

Highlights: ► We study the VUV photoionization of acetamide in the 8–24 eV photon energy range. ► Electron/ion coincidence measurements are performed using synchrotron radiation. ► The adiabatic ionization energy of acetamide is determined by TPEPICO measurements. ► VUV induced fragmentation pathways of acetamide are assigned and discussed. - Abstract: A VUV photoionization study of acetamide was carried out over the 8–24 eV photon energy range using synchrotron radiation and photoelectron/photoion coincidence (PEPICO) spectroscopy. Threshold photoelectron photoion coincidence (TPEPICO) measurements were also made. Photoion yield curves and branching ratios were measured for the parent ion and six fragment ions. The adiabatic ionization energy of acetamide was determined as I.E. (1 2 A′) = (9.71 ± 0.02) eV, in agreement with an earlier reported photoionization mass spectrometry (PIMS) value. The adiabatic energy of the first excited state of the ion, 1 2 A″, was determined to be ≈10.1 eV. Assignments of the fragment ions and the pathways of their formation by dissociative photoionization were made. The neutral species lost in the principal dissociative photoionization processes are CH 3 , NH 2 , NH 3 , CO, HCCO and NH 2 CO. Heats of formation are derived for all ions detected and are compared with literature values. Some astrophysical implications of these results are discussed.

VUV Spectroscopy in DIII-D Divertor

International Nuclear Information System (INIS)

Alkesh Punjabi; Nelson Jalufka

2004-01-01

The research carried out on this grant was motivated by the high power emission from the CIV doublet at 155 nm in the DIII-D divertor and to study the characteristics of the radiative divertor. The radiative divertor is designed to reduce the heat load to the target plates of the divertor by reducing the energy in the divertor plasma using upstream scrape-off-layer (SOL) radiation. In some cases, particularly in Partially Detached Divertor (PDD) operations, this emission accounts for more than 50% of the total radiation from the divertor. In PDD operation, produced by neutral gas injection, the particle flow to the target plate and the divertor temperature are significantly reduced. A father motivation was to study the CIV emission distribution in the lower, open divertor and the upper baffled divertor. Two Vacuum Ultra Violet Tangential viewing Television cameras (VUV TTV) were constructed and installed in the upper, baffled and the lower, open divertor. The images recorded by these cameras were then inverted to produce two-dimensional distributions of CIV in the poloidal plane. Results obtained in the project are summarized in this report

A group-level approach to analyzing participative ergonomics (PE) effectiveness: The relationship between PE dimensions and employee exposure to injuries.

Science.gov (United States)

Morag, Ido; Luria, Gil

2018-04-01

Most studies concerned with participative ergonomic (PE) interventions, focus on organizational rather than group level analysis. By implementing an intervention at a manufacturing plant, the current study, utilizing advanced information systems, measured the effect of line-supervisor leadership on employee exposure to risks. The study evaluated which PE dimensions (i.e., extent of workforce involvement, diversity of reporter role types and scope of analysis) are related to such exposure at the group level. The data for the study was extracted from two separate computerized systems (workforce medical records of 791 employees and an intranet reporting system) during a two-year period. While the results did not confirm the effect of line-supervisor leadership on subordinates' exposure to risks, they did demonstrate relationships between PE dimensions and the employees' exposure to risks. The results support the suggested level of analysis and demonstrate that group-based analysis facilitates the assimilation of preventive interventions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Combined UV-C/H2O2-VUV processes for the treatment of an actual slaughterhouse wastewater.

Science.gov (United States)

Naderi, Kambiz Vaezzadeh; Bustillo-Lecompte, Ciro Fernando; Mehrvar, Mehrab; Abdekhodaie, Mohammad Jafar

2017-05-04

In this study, a three-factor, three-level Box-Behnken design with response surface methodology were used to maximize the TOC removal and minimize the H 2 O 2 residual in the effluent of the combined UV-C/H 2 O 2 -VUV system for the treatment of an actual slaughterhouse wastewater (SWW) collected from one of the meat processing plants in Ontario, Canada. The irradiation time and the initial concentrations of total organic carbon (TOC o ) and hydrogen peroxide (H 2 O 2o ) were the three predictors, as independent variables, studied in the design of experiments. The multiple response approach was used to obtain desirability response surfaces at the optimum factor settings. Subsequently, the optimum conditions to achieve the maximum percentage TOC removal of 46.19% and minimum H 2 O 2 residual of 1.05% were TOC o of 213 mg L -1 , H 2 O 2o of 450 mg L -1 , and irradiation time of 9 min. The attained optimal operating conditions were validated with a complementary test. Consequently, the TOC removal of 45.68% and H 2 O 2 residual of 1.03% were achieved experimentally, confirming the statistical model reliability. Three individual processes, VUV alone, VUV/H 2 O 2 , and UV-C/H 2 O 2 , were also evaluated to compare their performance for the treatment of the actual SWW using the optimum parameters obtained in combined UV-C/H 2 O 2 -VUV processes. Results confirmed that an adequate combination of the UV-C/H 2 O 2 -VUV processes is essential for an optimized TOC removal and H 2 O 2 residual. Finally, respirometry analyses were also performed to evaluate the biodegradability of the SWW and the BOD removal efficiency of the combined UV-C/H 2 O 2 -VUV processes.

Time resolved 3D momentum imaging of ultrafast dynamics by coherent VUV-XUV radiation

Energy Technology Data Exchange (ETDEWEB)

Sturm, F. P., E-mail: fpsturm@lbl.gov [Ultrafast X-Ray Science Lab, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Institut für Kernphysik, Universität Frankfurt, Max-von-Laue Str. 1, D-60438 Frankfurt (Germany); Wright, T. W.; Ray, D.; Zalyubovskaya, I.; Shivaram, N.; Slaughter, D. S.; Belkacem, A.; Weber, Th. [Ultrafast X-Ray Science Lab, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Ranitovic, P. [Ultrafast X-Ray Science Lab, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); ELI-ALPS, ELI-Hu Nkft, Dugonics ter 13, Szeged H6720 (Hungary)

2016-06-15

We present a new experimental setup for measuring ultrafast nuclear and electron dynamics of molecules after photo-excitation and ionization. We combine a high flux femtosecond vacuum ultraviolet (VUV) and extreme ultraviolet (XUV) source with an internally cold molecular beam and a 3D momentum imaging particle spectrometer to measure electrons and ions in coincidence. We describe a variety of tools developed to perform pump-probe studies in the VUV-XUV spectrum and to modify and characterize the photon beam. First benchmark experiments are presented to demonstrate the capabilities of the system.

Study on radiation discoloration of PE and its mechanisms

International Nuclear Information System (INIS)

Wang Huiliang; Wang Chun; Chen Wenxiu

2001-01-01

In order to find the major reason for the radiation discoloration of PE, the changes of yellow index (YI) of HDPE and LDPE under γ irradiation in air or N 2 and after irradiation are measured using colorimeter. The growth and decay of alkyl free radical formed in HDPE and LDPE, and the change of the absorbance of conjugated double bonds formed in PE are measured using ESR and UV-Visible spectrometer. The YI of HDPE is higher than that of LDPE at the same radiation dose. The YI of PE irradiated in air is higher than that of PE irradiated in N 2 at the same radiation dose. The YI of PE irradiated different dose decreases with post-irradiation storage time firstly, up to a certain time, it becomes stable. It is found that the formation and decay of free radicals is very similar to that of the change of YI, whereas, the change of the absorbance of conjugated double bonds formed in PE is different to the change of YI. The results are discussed, it is believed that the major reason for the radiation discoloration is the formation of trapped free radicals

Single vs. dual color fire detection systems: operational tradeoffs

Science.gov (United States)

Danino, Meir; Danan, Yossef; Sinvani, Moshe

2017-10-01

In attempt to supply a reasonable fire plume detection, multinational cooperation with significant capital is invested in the development of two major Infra-Red (IR) based fire detection alternatives, single-color IR (SCIR) and dual-color IR (DCIR). False alarm rate was expected to be high not only as a result of real heat sources but mainly due to the IR natural clutter especially solar reflections clutter. SCIR uses state-of-the-art technology and sophisticated algorithms to filter out threats from clutter. On the other hand, DCIR are aiming at using additional spectral band measurements (acting as a guard), to allow the implementation of a simpler and more robust approach for performing the same task. In this paper we present the basics of SCIR & DCIR architecture and the main differences between them. In addition, we will present the results from a thorough study conducted for the purpose of learning about the added value of the additional data available from the second spectral band. Here we consider the two CO2 bands of 4-5 micron and of 2.5-3 micron band as well as off peak band (guard). The findings of this study refer also to Missile warning systems (MWS) efficacy, in terms of operational value. We also present a new approach for tunable filter to such sensor.

The VUV instrument SPICE for Solar Orbiter: performance ground testing

Science.gov (United States)

Caldwell, Martin E.; Morris, Nigel; Griffin, Douglas K.; Eccleston, Paul; Anderson, Mark; Pastor Santos, Carmen; Bruzzi, Davide; Tustain, Samuel; Howe, Chris; Davenne, Jenny; Grundy, Timothy; Speight, Roisin; Sidher, Sunil D.; Giunta, Alessandra; Fludra, Andrzej; Philippon, Anne; Auchere, Frederic; Hassler, Don; Davila, Joseph M.; Thompson, William T.; Schuehle, Udo H.; Meining, Stefan; Walls, Buddy; Phelan, P.; Dunn, Greg; Klein, Roman M.; Reichel, Thomas; Gyo, Manfred; Munro, Grant J.; Holmes, William; Doyle, Peter

2017-08-01

SPICE is an imaging spectrometer operating at vacuum ultraviolet (VUV) wavelengths, 70.4 - 79.0 nm and 97.3 - 104.9 nm. It is a facility instrument on the Solar Orbiter mission, which carries 10 science instruments in all, to make observations of the Sun's atmosphere and heliosphere, at close proximity to the Sun, i.e to 0.28 A.U. at perihelion. SPICE's role is to make VUV measurements of plasma in the solar atmosphere. SPICE is designed to achieve spectral imaging at spectral resolution >1500, spatial resolution of several arcsec, and two-dimensional FOV of 11 x16arcmins. The many strong constraints on the instrument design imposed by the mission requirements prevent the imaging performance from exceeding those of previous instruments, but by being closer to the sun there is a gain in spatial resolution. The price which is paid is the harsher environment, particularly thermal. This leads to some novel features in the design, which needed to be proven by ground test programs. These include a dichroic solar-transmitting primary mirror to dump the solar heat, a high in-flight temperature (60deg.C) and gradients in the optics box, and a bespoke variable-line-spacing grating to minimise the number of reflective components used. The tests culminate in the systemlevel test of VUV imaging performance and pointing stability. We will describe how our dedicated facility with heritage from previous solar instruments, is used to make these tests, and show the results, firstly on the Engineering Model of the optics unit, and more recently on the Flight Model. For the keywords, select up to 8 key terms for a search on your manuscript's subject.

Probing colliding Calcium plasmas with emission and VUV absorption imaging

International Nuclear Information System (INIS)

Kavanagh, K.D.; Hirsch, J.S.; Kennedy, E.T.; Costello, T.; Poletto, L.; Nicolosi, P.

2004-01-01

Full text: Laser produced plasmas are formed when a short pulse and high power laser is focused onto a surface. Applications range from VUV/X-ray sources for lithography, microscopy and radiography to X-ray lasers, thin film deposition, analytical spectroscopy and electron/ion beam generation (and even acceleration). A battery of particle and optical techniques are now used to diagnose laser plasmas. One highly successful technique is gated-CCD (Charged Coupled Device) imaging of plasma plumes. It provides critical data on the early (creation) and late (expansion) phases of plasma plumes. However, this technique is limited to detecting only the excited (emitting) species in the plume. Recently, we developed a vacuum-UV (VUV) photoabsorption imaging facility called VPIF which enables one can track the evolution of dark plume matter or non-emitting plasma species residing in ground and metastable states. Although much is known about the dynamics of single laser plasma plumes expanding freely, little is known about the overlap between colliding plasma plumes. We are currently performing combined conventional gated CCD imaging and spectroscopy with VUV absorption imaging to map the evolution of the overlap volume of two colliding and interpenetrating plasma plumes. We are specifically tracking ground state singly ionized calcium in the plasmas by tuning into the inner shell 3p to 3d transition at 33.2 eV while the excited state species are tracked using transitions in the UV -NIR spectral range. The experiment may be cast as a model system for atmospheric and/or astrophysical colliding systems, e.g., when tracer elements are injected into supersonic winds at high altitude or when supernovae eject plasma into the solar wind

Investigation of properties of (U)HMW-PE under the influence of gamma irradiation

Energy Technology Data Exchange (ETDEWEB)

Ehe, K. von der; Wolff, D.; Boehning, M. [BAM Federal Institute for Materials Research and Testing, Berlin (Germany)

2012-11-01

High molecular weight polyethylene (HMW-PE) and ultra high molecular weight polyethylene (UHMW-PE) are high performance materials, which are predestinated for a wide range of applications due to characteristics like high chemical resistance, low wear, and high hydrogen content. In addition to the application of (U)HMW-PE as sports equipment (sliding surface of snowboards, skis) and in mechanical engineering (materials for spur gears and chain guides) these polymers are used in two other and even more demanding areas: as implant material in medical technology and as a component for neutron shielding purposes in casks for storage and transport of radioactive waste. In these two cases, gamma irradiation and its impact on the molecular structure of polyethylene play an important role. In the first case, irradiation is applied for sterilization purposes and in the second one it exists as a side-effect of inserting the radioactive material in the cask. Specifically concerning their use in the field of medical technology, different types of UHMW-PE have been intensively studied. It is generally accepted that two concurrent and competitive processes, based on initial chain scission and subsequent reactions of C-centered radicals and molecular fragments, occur in PE as a consequence of radiation: radical recombination accounts for crosslinking, together with some disproportionation, formation of low molecular weight fragments, and recrystallization. Furthermore, formation of oxygenated structures in the presence of traces of oxygen is a competitive process to those mentioned above. Radiation induced scission preferentially takes place in the amorphous phase and noncrystalline surface of the crystallites and results in shorter polymer chains, fewer entanglements, and consequently, increased molecular mobility. The latter enables folding of polymer segments and thus, crystal growth and increased perfection in the crystal lamellae. With regard to the long-term application of

Quantum manipulation of two-color stationary light: Quantum wavelength conversion

International Nuclear Information System (INIS)

Moiseev, S. A.; Ham, B. S.

2006-01-01

We present a quantum manipulation of a traveling light pulse using electromagnetically induced transparency-based slow light phenomenon for the generation of two-color stationary light. We theoretically discuss the two-color stationary light for the quantum wavelength conversion process in terms of pulse area, energy transfer, and propagation directions. The condition of the two-color stationary light pulse generation has been found and the quantum light dynamics has been studied analytically in the adiabatic limit. The quantum frequency conversion rate of the traveling light is dependent on the spatial spreading of the two-color stationary light pulse and can be near unity in an optically dense medium for the optimal frequencies of the control laser fields

Strategy for Realizing High-Precision VUV Spectro-Polarimeter

Science.gov (United States)

Ishikawa, R.; Narukage, N.; Kubo, M.; Ishikawa, S.; Kano, R.; Tsuneta, S.

2014-12-01

Spectro-polarimetric observations in the vacuum ultraviolet (VUV) range are currently the only means to measure magnetic fields in the upper chromosphere and transition region of the solar atmosphere. The Chromospheric Lyman-Alpha Spectro-Polarimeter (CLASP) aims to measure linear polarization at the hydrogen Lyman- α line (121.6 nm). This measurement requires a polarization sensitivity better than 0.1 %, which is unprecedented in the VUV range. We here present a strategy with which to realize such high-precision spectro-polarimetry. This involves the optimization of instrument design, testing of optical components, extensive analyses of polarization errors, polarization calibration of the instrument, and calibration with onboard data. We expect that this strategy will aid the development of other advanced high-precision polarimeters in the UV as well as in other wavelength ranges.

Visualizing Infrared (IR) Spectroscopy with Computer Animation

Science.gov (United States)

Abrams, Charles B.; Fine, Leonard W.

1996-01-01

IR Tutor, an interactive, animated infrared (IR) spectroscopy tutorial has been developed for Macintosh and IBM-compatible computers. Using unique color animation, complicated vibrational modes can be introduced to beginning students. Rules governing the appearance of IR absorption bands become obvious because the vibrational modes can be visualized. Each peak in the IR spectrum is highlighted, and the animation of the corresponding normal mode can be shown. Students can study each spectrum stepwise, or click on any individual peak to see its assignment. Important regions of each spectrum can be expanded and spectra can be overlaid for comparison. An introduction to the theory of IR spectroscopy is included, making the program a complete instructional package. Our own success in using this software for teaching and research in both academic and industrial environments will be described. IR Tutor consists of three sections: (1) The 'Introduction' is a review of basic principles of spectroscopy. (2) 'Theory' begins with the classical model of a simple diatomic molecule and is expanded to include larger molecules by introducing normal modes and group frequencies. (3) 'Interpretation' is the heart of the tutorial. Thirteen IR spectra are analyzed in detail, covering the most important functional groups. This section features color animation of each normal mode, full interactivity, overlay of related spectra, and expansion of important regions. This section can also be used as a reference.

Pump-probe study of atoms and small molecules with laser driven high order harmonics

Science.gov (United States)

Cao, Wei

A commercially available modern laser can emit over 1015 photons within a time window of a few tens of femtoseconds (10-15second), which can be focused into a spot size of about 10 mum, resulting in a peak intensity above 1014W/cm2. This paves the way for table-top strong field physics studies such as above threshold ionization (ATI), non-sequential double ionization (NSDI), high order harmonic generation (HHG), etc.. Among these strong laser-matter interactions, high order harmonic generation, which combines many photons of the fundamental laser field into a single photon, offers a unique way to generate light sources in the vacuum ultraviolet (VUV) or extreme ultraviolet (EUV) region. High order harmonic photons are emitted within a short time window from a few tens of femtoseconds down to a few hundreds of attoseconds (10 -18second). This highly coherent nature of HHG allows it to be synchronized with an infrared (IR) laser pulse, and the pump-probe technique can be adopted to study ultrafast dynamic processes in a quantum system. The major work of this thesis is to develop a table-top VUV(EUV) light source based on HHG, and use it to study dynamic processes in atoms and small molecules with the VUV(EUV)-pump IR-probe method. A Cold Target Recoil Ion Momentum Spectroscopy (COLTRIMS) apparatus is used for momentum imaging of the interaction products. Two types of high harmonic pump pulses are generated and applied for pump-probe studies. The first one consists of several harmonics forming a short attosecond pulse train (APT) in the EUV regime (around 40 eV). We demonstrate that, (1) the auto-ionization process triggered by the EUV in cation carbon-monoxide and oxygen molecules can be modified by scanning the EUV-IR delay, (2) the phase information of quantum trajectories in bifurcated high harmonics can be extracted by performing an EUV-IR cross-correlation experiment, thus disclosing the macroscopic quantum control in HHG. The second type of high harmonic source

Duke storage rink UV/VUV FEL: Status and prospects

Energy Technology Data Exchange (ETDEWEB)

Litvinenko, V.N.; Burnham, B.; Madey, J.M.J. [Duke Univ., Durham, NC (United States)] [and others

1995-12-31

The 1 GeV Duke storage ring was successfully commissioned with parameters exceeding initial specification. The OK-4 FEL has arrived at the Duke FEL laboratory from the Novosibirsk Institute of Nuclear Physics. The OK-4 installation and commissioning is in progress. In this paper we describe the up-to-date status of the Duke storage ring and the OK-4 FEL. The projected performance of the OK-4 UV/VUV FEL is presented based on the electron beam parameters achieved. Initial plans to operate the OK-4 UV/VUV FEL at the Duke 1 GeV storage ring are outlined. Future plans and prospects of both the OK-4 FEL and the Duke storage ring are discussed.

Multistabilities and symmetry-broken one-color and two-color states in closely coupled single-mode lasers.

Science.gov (United States)

Clerkin, Eoin; O'Brien, Stephen; Amann, Andreas

2014-03-01

We theoretically investigate the dynamics of two mutually coupled, identical single-mode semi-conductor lasers. For small separation and large coupling between the lasers, symmetry-broken one-color states are shown to be stable. In this case the light outputs of the lasers have significantly different intensities while at the same time the lasers are locked to a single common frequency. For intermediate coupling we observe stable symmetry-broken two-color states, where both lasers lase simultaneously at two optical frequencies which are separated by up to 150 GHz. Using a five-dimensional model, we identify the bifurcation structure which is responsible for the appearance of symmetric and symmetry-broken one-color and two-color states. Several of these states give rise to multistabilities and therefore allow for the design of all-optical memory elements on the basis of two coupled single-mode lasers. The switching performance of selected designs of optical memory elements is studied numerically.

Study of chromatic adaptation using memory color matches, Part II: colored illuminants.

Science.gov (United States)

Smet, Kevin A G; Zhai, Qiyan; Luo, Ming R; Hanselaer, Peter

2017-04-03

In a previous paper, 12 corresponding color data sets were derived for 4 neutral illuminants using the long-term memory colours of five familiar objects. The data were used to test several linear (one-step and two-step von Kries, RLAB) and nonlinear (Hunt and Nayatani) chromatic adaptation transforms (CAT). This paper extends that study to a total of 156 corresponding color sets by including 9 more colored illuminants: 2 with low and 2 with high correlated color temperatures as well as 5 representing high chroma adaptive conditions. As in the previous study, a two-step von Kries transform whereby the degree of adaptation D is optimized to minimize the DEu'v' prediction errors outperformed all other tested models for both memory color and literature corresponding color sets, whereby prediction errors were lower for the memory color set. Most of the transforms tested, except the two- and one-step von Kries models with optimized D, showed large errors for corresponding color subsets that contained non-neutral adaptive conditions as all of them tended to overestimate the effective degree of adaptation in this study. An analysis of the impact of the sensor space primaries in which the adaptation is performed was found to have little impact compared to that of model choice. Finally, the effective degree of adaptation for the 13 illumination conditions (4 neutral + 9 colored) was successfully modelled using a bivariate Gaussian in a Macleod-Boyton like chromaticity diagram.

An XUV/VUV free-electron laser oscillator

Science.gov (United States)

Goldstein, J. C.; Newnam, B. E.; Cooper, R. K.; Comly, J. C., Jr.

Problems regarding the extension of free-electron laser technology from the visible and near infrared region, where such devices are currently operating, to the ultraviolet have recently been extensively discussed. It was found that significant technical problems must be overcome before free-electron lasers (FELs) can be operated in the VUV (100-200 nm) and the XUV (50-100). However, the present lack of other intense and tunable sources of coherent radiation at these wavelengths together with the intrinsic properties of FELs make the development of such devices potentially very rewarding. The properties of FELs include continuous tunability in wavelength and output in the form of a train of picosecond pulses. An investigation is conducted regarding the feasibility of an operation of a FEL in the XUV/VUV regions, taking into account a theoretical model. It is found that modest improvements in electron beam and optical mirror technologies will make the design of a FEL for operation in the 50-200-nm range of optical wavelength possible.

VUV light induced valence degeneration in Sm over-layer on HOPG

International Nuclear Information System (INIS)

Kutluk, G; Nakatake, M; Arita, M; Namatame, H; Taniguchi, M; Ishitobi, Y; Sumida, H

2013-01-01

Systematic investigation of the influence of vacuum ultraviolet (VUV) irradiation on the valence degeneration in a Sm over-layer on a HOPG substrate was performed using in-situ photoemission spectroscopy (XPS, UPS, and ARPES) for the Sm coverage regime of 0.05-3.6 Å. This investigation confirmed that VUV irradiation-induced degeneration of divalent Sm exerts a more profound effect than Sm contamination during photoemission spectroscopy even under UHV. We found that the charge transfer occurs mainly from divalent Sm to the HOPG surface.

Determination of risk identification process employed by NHS for a PFI hospital project in the UK

Directory of Open Access Journals (Sweden)

F. E. Mohamed Ghazali

2009-12-01

Full Text Available Long-term concession contracts associated with Private Finance Initiative (PFI projects, such as National Health Service (NHS hospitals, are subject to substantial risks, which may not only emerge from project activities such as design and construction, but also from global issues beyond the control of project parties, such as commercial, legal and political risks. Therefore, the principal parties involved must manage risks effectively and efficiently, as early as the project initiation stage, in order to ensure a successful delivery. The aim of this paper is to examine the risk identification process of the NHS PFI hospital in the UK, as a case study, in order to determine the techniques used in risk identification, and their significance, based on estimated probabilities of occurrence. These objectives were achieved through interviews with key personnel within the NHS Trust involved. Results found the sole technique used in risk identification to be brainstorming, through which more than thirty risks were identified and classified under six risk categories: planning, pre-commissioning, design, land purchasing, construction and operation. Thirteen risks were identified as significant based on their estimated probability of occurrence had the project been developed via public procurement. The results of this research will enable public sector clients like the NHS Trust to not only identify the significant risks, which will allow them to focus more attention on developing appropriate mitigation strategies and contingency plans, but also to improve its risk identification process through the use of other techniques in order to support findings from the brainstorming process.

The Color Glass Condensate and the Glasma: Two Lectures.

Energy Technology Data Exchange (ETDEWEB)

McLerran,L.

2007-08-29

These two lectures concern the Color Glass Condensate and the Glasma. These are forms of matter which might be studied in high energy hadronic collisions. The Color Glass Condensate is high energy density gluonic matter. It constitutes the part of a hadron wave function important for high energy processes. The Glasma is matter produced from the Color Glass Condensate in the first instants after a collision of two high energy hadrons. Both types of matter are associated with coherent fields. The Color Glass Condensate is static and related to a hadron wavefunction, where the Glasma is transient and evolves quickly after a collision. I present the properties of such matter, and some aspects of what is known of their properties.

Poor concordance of spiral CT (SCT) and high probability ventilation-perfusion (V/Q) studies in the diagnosis of pulmonary embolism (PE)

International Nuclear Information System (INIS)

Roman, M.R.; Angelides, S.; Chen, N.

2000-01-01

Full text: Despite its limitations, V/Q scintigraphy remains the favoured non-invasive technique for the diagnosis of pulmonary embolism (PE). PE is present in 85-90% and 30-40% of high and intermediate probability V/Q studies respectively. The value of spiral CT (SCT), a newer imaging modality, has yet to be determined. The aims of this study were to determine the frequency of positive SCT for PE in high and intermediate probability V/Q studies performed within 24hr apart. 15 patients (6M, 9F, mean age - 70.2) with a high probability study were included. Six (40%) SCT were reported as positive (four with emboli present in the main pulmonary arteries), seven as negative, one equivocal and one was technically sub-optimal. Pulmonary angiography was not performed in any patient. In all seven negative studies, the SCT was performed before the V/Q study. Of these, two studies were revised to positive once the result of the V/Q study was known, while, three others had resolving mismatch V/Q defects on follow-up studies (performed 5-14 days later); two of these three also had a positive duplex scan of the lower limbs. One other was most likely due to chronic thromboembolic disease. Only three patients had a V/Q scan prior to the SCT; all were positive for PE on both imaging modalities. Of 26 patients (11M, 15F, mean age - 68.5) with an intermediate probability V/Q study, SCT was positive in only two (8%). Thus the low detection rate of PE by SCT in this albeit small series, raises doubts as to its role in the diagnosis of PE. Copyright (2000) The Australian and New Zealand Society of Nuclear Medicine Inc

Pengaruh Determinan P/e Dan P/e Rasio Terhadap Kepemilikan Institusi : Studi Di Bursa Efek Indonesia Tahun 2004-2008

OpenAIRE

Anggraini, Mita; Mahastanti, Linda Ariany

2012-01-01

Institutional investors needs analysis in making decisions for investing activities. Analysis of the most widely used is the fundamental analysis approach is through a P/E ratio. P/E (price earnings ratio) can be interpreted as an indicator of market confidence in the company's growth prospects in the future. High P/E indicates that the better performance of the company and this caught a lot of institutional investors to buy shares so that the percentage of institutional ownership in the comp...

Improvement of barrier properties of rotomolded PE containers with nanoclay

Energy Technology Data Exchange (ETDEWEB)

Jamshidi, Shadi; Sundararaj, Uttandaraman, E-mail: u.sundararaj@ucalgary.ca [Department of Chemical and Petroleum Engineering, University of Calgary, Calgary, Alberta, T2N 1N4 (Canada)

2015-05-22

Polyethylene (PE) is widely used to make bulk containers in rotational molding process. The challenge in this study is to improve permeation resistance of PE to hydrocarbon solvents and gases. Adding organomodified clay improves the thermal, barrier and mechanical properties of PE. In fact, clay layers create a tortuous path against the permeant, yielding better barrier properties. Due to the non-polar hydrophobic nature of PE and polar hydrophilic structure of clay minerals, the compatibilizer plays a crucial role to enhance the dispersion level of clay in the matrix. In this study High Density Polyethylene (HDPE) and Linear Low Density Polyethylene (LLDPE) layered silicate nanocomposite were melt-compounded with two concentrations of organomodified clay (2 and 4 wt. %). The interaction between nanoclay, compatibilizer and rotomolding grade of PE were examined by using X-ray diffraction, transmission electron microscopy (TEM) and rheology test. Rheology was used to determine the performance of our material at low shear processing condition.

PFI-ZEKE (Pulsed Field Ionization-Zero Electron Kinetic Energy) para el estudio de iones

Science.gov (United States)

Castaño, F.; Fernández, J. A.; Basterretxea, A. Longarte. F.; Sánchez Rayo, M. N.; Martínez, R.

Entre las áreas hacia donde ha evolucionado la Química en los últimos años están los estudios de sistemas con especies reactivas de alta energía y los dominados por fuerzas intermoleculares débiles, con energías de unas pocas kcal/mol. En efecto, el estudio de las propiedades de los iones, comenzando por su relación con la molécula neutra de la que procede, la energía de ionización, los estados vibracionales y rotacionales, energías de enlace de Van der Waals entre el ión y una amplia variedad de otras moléculas, sus confórmeros o isómeros y sus reacciones o semi-reacciones químicas están en la raíz de la necesidad de la espectroscopía conocida como PFI-ZEKE, Pulsed Field Ionization-Zero Electron Kinetic Energy. Entre las aplicaciones que requieren estos conocimientos se encuentran la generación de plasmas para la fabricación de semiconductores, memorias magnéticas, etc, así como los sistemas astrofísicos, la ionosfera terrestre, etc. La espectroscopía ZEKE es una evolución de las de fluorescencia inducida por láser, LIF, ionización multifotónica acrecentada por resonancia, REMPI, con uno y dos colores y acoplada a un sistema de tiempo de vuelo, REMPI-TOF-MS, y las espectroscopías de doble resonancia IR-UV y UV-UV. Sus espectros y la ayuda de cálculos ab inicio permite determinar las energías de enlace de complejos de van der Waals en estados fundamental y excitados, identificar confórmeros e isómeros, obtener energías de ionización experimentales aproximadas (100 cm-1) y otras variables de interés. Al igual que con LIF, REMPI y dobles resonancias, es posible utilizar muestras gaseosas, pero los espectros están muy saturados de bandas y su interpretación es difícil o imposible. Se evitan estas dificultades estudiando las moléculas o complejos en expansiones supersónicas, donde la T de los grados de libertad solo alcanzan unos pocos K. Para realizar experimentos de ZEKE hay que utilizar una propiedad recientemente

Swelling, ion uptake and biodegradation studies of PE film modified through radiation induced graft copolymerization

Energy Technology Data Exchange (ETDEWEB)

Kaur, Inderjeet, E-mail: ij_kaur@hotmail.com [Department Chemistry, HPU Shimla 171005 (India); Gupta, Nitika; Kumari, Vandna [Department Chemistry, HPU Shimla 171005 (India)

2011-09-15

An attempt to develop biodegradable polyethylene film grafting of mixture of hydrophilic monomers methacrylic acid (MAAc) and acrylamide (AAm) onto PE film has been carried out by preirradiation method using benzoyl peroxide as the radical initiator. Since ether linkages are susceptible to easy cleavage during degradation process, PE film was irradiated before the grafting reactions by {gamma}-rays to introduce peroxidic linkages (PE-OO-PE) that offer sites for grafting. The effect of irradiation dose, monomer concentration, initiator concentration, temperature, time and amount of water on the grafting percent was determined. Maximum percentage of grafting of binary mixture (MAAc+AAm), (1792%) was obtained at a total concentration of binary monomer mixture=204.6x10{sup -2} mol/L ([MAAc]=176.5x10{sup -2} mol/L, [AAm]=28.1x10{sup -2} mol/L), [BPO]=8.3x10{sup -2} mol/L at 100 deg. C in 70 min. The grafted PE film was characterized by the Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA) and Scanning Electron Microscopic (SEM) methods. Some selective properties of grafted films such as swelling studies, ion uptake and biodegradation studies have been investigated. The grafted films show good swelling in water, ion uptake studies shows promising results for desalination of brackish water and the soil burial test shows that PE film grafted with binary monomer mixture degrades up to 47% within 50 days. - Highlights: > Binary mixture of methacrylic acid (MAAc) and acrylamide (AAm) onto PE film by preirradiation method was carried out. > Graft copolymers of MAAc+AAm and PE film were characterized by FTIR, TGA and SEM studies and was found to be thermally stable. > Grafting of MAAc+AAm improved swelling behavior giving maximum swelling (485.71%) in water as against PE with 0% swelling. > The grafted PE-g-poly (MAAc-co-AAm) behaves as an excellent material for ion separation. > Biodegradation studies by soil burial test showed 47.19% of

STUDY OF RASPBERRY EXTRACT APPLICATIONS AS TEXTILE COLORANT ON NATURAL FIBERS

Directory of Open Access Journals (Sweden)

COMAN Diana

2014-05-01

Full Text Available The present study deals with the biomordant assisted application of natural extracts obtained from red raspberry (Rubus idaeus L. fruits onto two different cellulosic supports – flax and bamboo. The study relies on the improvement of multifunctionalities such as colour fastness, washing and rubbing fastness, due to the synergism provided by the co-assistance of both a biomordant, and the complex resulted by inclusion of the pigment molecule, in the cavity of MCT-β-CD; it is well known that natural dye molecule have a good selectivity binding to the hydrophobic monochloro-triazynil-cyclodextrin’s (MCT-β-CD cavity to form inclusion complexes. An investigation system provided the characterization of the composites: FT-IR spectroscopy stressed the main chemical bonds created between MCT-β-CD as host molecule and guest molecule represented by natural colorant molecule; Brunauer-Emmett-Teller (BET Surface Area Analysis completes the analysis, proving the positive contribution of MCT-β-cyclodextrin grafting. Dyeing fastness and colour modifications were conclusive for this research. Samples of bamboo knitting are less colorful than those of the flax fabric in terms of high absorption capacity and stability / durability of natural dye applied by inclusion within cyclodextrin’s inner. The results of analysis revealed improvement of washing and rubbing fastness (1-1.5 points. Colour modifications noticed due to the colorant deposition were quantified from up to 3 points.

The biological basis of a universal constraint on color naming: cone contrasts and the two-way categorization of colors.

Science.gov (United States)

Xiao, Youping; Kavanau, Christopher; Bertin, Lauren; Kaplan, Ehud

2011-01-01

Many studies have provided evidence for the existence of universal constraints on color categorization or naming in various languages, but the biological basis of these constraints is unknown. A recent study of the pattern of color categorization across numerous languages has suggested that these patterns tend to avoid straddling a region in color space at or near the border between the English composite categories of "warm" and "cool". This fault line in color space represents a fundamental constraint on color naming. Here we report that the two-way categorization along the fault line is correlated with the sign of the L- versus M-cone contrast of a stimulus color. Moreover, we found that the sign of the L-M cone contrast also accounted for the two-way clustering of the spatially distributed neural responses in small regions of the macaque primary visual cortex, visualized with optical imaging. These small regions correspond to the hue maps, where our previous study found a spatially organized representation of stimulus hue. Altogether, these results establish a direct link between a universal constraint on color naming and the cone-specific information that is represented in the primate early visual system.

CMFD simulation of ERCOSAM PANDA spray tests PE1 and PE2

Energy Technology Data Exchange (ETDEWEB)

Filippov, A., E-mail: phil@ibrae.ac.ru [Nuclear Safety Institute of the Russian Academy of Sciences (IBRAE RAN) (Russian Federation); Moscow Institute of Physics and Technology (Russian Federation); Grigoryev, S. [Nuclear Safety Institute of the Russian Academy of Sciences (IBRAE RAN) (Russian Federation); Moscow Institute of Physics and Technology (Russian Federation); Drobyshevsky, N.; Kiselev, A.; Shyukin, A.; Yudina, T. [Nuclear Safety Institute of the Russian Academy of Sciences (IBRAE RAN) (Russian Federation)

2016-04-01

Highlights: • Successful modeling of gas mixtures and droplet flows in multicompartment system. • For pressure, modeling of gas-wall heat transfer (and heat radiation) is important. • Dependence of gas mixing time in spray vessel on the used nozzle may be essential. • Penetration of helium-enriched mixture into another vessel due to spray operation. • Effect on pressure of sump re-evaporation and gas heating (by walls) during spray. - Abstract: The ERCOSAM project (together with the SAMARA project) includes a set of multi-stage experiments carried out at different thermal-hydraulics facilities (TOSQAN, MISTRA, PANDA, SPOT) and their numerical simulation. The test sequences aim to investigate hydrogen concentration build-up and stratification during a postulated severe accident as well as the effect of activation of Severe Accident Management systems (SAMs) on stratification. At the initial Phases I–III of the tests stratification of the injected light gases (steam, helium) is established, pressure increases. The models of SAMs are activated at the final Phase IV. In the paper, two spray tests PE1 and PE2 performed at PANDA facility are numerically investigated aiming for code validation (FLUENT) and better understanding of physical processes. Phases I–IV of the tests were simulated. A satisfactory agreement with the experimental results on gas component mole fractions was obtained. The reasons of obtained some discrepancies in pressure and temperature were studied in multivariate calculations and discussed in the paper. The tests PE1 and PE2 were performed with different spray nozzles and initial conditions. In simulation that resulted in different flow patterns during spray operation. The sensitivity to nozzle angle and some other input parameters was investigated. Possible factors of depressurization rate caused by spray operation were also studied. The key features observed in the experiments and obtained numerically being of interest in terms of

Highly Efficient Red and White Organic Light-Emitting Diodes with External Quantum Efficiency beyond 20% by Employing Pyridylimidazole-Based Metallophosphors.

Science.gov (United States)

Miao, Yanqin; Tao, Peng; Wang, Kexiang; Li, Hongxin; Zhao, Bo; Gao, Long; Wang, Hua; Xu, Bingshe; Zhao, Qiang

2017-11-01

Two highly efficient red neutral iridium(III) complexes, Ir1 and Ir2, were rationally designed and synthesized by selecting two pyridylimidazole derivatives as the ancillary ligands. Both Ir1 and Ir2 show nearly the same photoluminescence emission with the maximum peak at 595 nm (shoulder band at about 638 nm) and achieve high solution quantum yields of up to 0.47 for Ir1 and 0.57 for Ir2. Employing Ir1 and Ir2 as emitters, the fabricated red organic light-emitting diodes (OLEDs) show outstanding performance with the maximum external quantum efficiency (EQE), current efficiency (CE), and power efficiency (PE) of 20.98%, 33.04 cd/A, and 33.08 lm/W for the Ir1-based device and 22.15%, 36.89 cd/A, and 35.85 lm/W for the Ir2-based device, respectively. Furthermore, using Ir2 as red emitter, a trichromatic hybrid white OLED, showing good warm white emission with low correlated color temperature of white device also realizes excellent device efficiencies with the maximum EQE, CE, and PE reaching 22.74%, 44.77 cd/A, and 46.89 lm/W, respectively. Such high electroluminescence performance for red and white OLEDs indicates that Ir1 and Ir2 as efficient red phosphors have great potential for future OLED displays and lightings applications.

Simultaneous nitrate reduction and acetaminophen oxidation using the continuous-flow chemical-less VUV process as an integrated advanced oxidation and reduction process

Energy Technology Data Exchange (ETDEWEB)

Moussavi, Gholamreza, E-mail: moussavi@modares.ac.ir; Shekoohiyan, Sakine

2016-11-15

Highlights: • Simultaneous advanced oxidation and reduction processes were explored in VUV system. • Complete reduction of nitrate to N{sub 2} was achieved at the presence of acetaminophen. • Complete degradation of acetaminophen was achieved at the presence of nitrate. • Over 95% of acetaminophen was mineralized in the VUV photoreactor. • VUV is a chemical-less advanced process for treating water emerging contaminants. - Abstract: This work was aimed at investigating the performance of the continuous-flow VUV photoreactor as a novel chemical-less advanced process for simultaneously oxidizing acetaminophen (ACT) as a model of pharmaceuticals and reducing nitrate in a single reactor. Solution pH was an important parameter affecting the performance of VUV; the highest ACT oxidation and nitrate reduction attained at solution pH between 6 and 8. The ACT was oxidized mainly by HO· while the aqueous electrons were the main working agents in the reduction of nitrate. The performance of VUV photoreactor improved with the increase of hydraulic retention time (HRT); the complete degradation of ACT and ∼99% reduction of nitrate with 100% N{sub 2} selectivity achieved at HRT of 80 min. The VUV effluent concentrations of nitrite and ammonium at HRT of 80 min were below the drinking water standards. The real water sample contaminated with the ACT and nitrate was efficiently treated in the VUV photoreactor. Therefore, the VUV photoreactor is a chemical-less advanced process in which both advanced oxidation and advanced reduction reactions are accomplished. This unique feature possesses VUV photoreactor as a promising method of treating water contaminated with both pharmaceutical and nitrate.

Simultaneous nitrate reduction and acetaminophen oxidation using the continuous-flow chemical-less VUV process as an integrated advanced oxidation and reduction process

International Nuclear Information System (INIS)

Moussavi, Gholamreza; Shekoohiyan, Sakine

2016-01-01

Highlights: • Simultaneous advanced oxidation and reduction processes were explored in VUV system. • Complete reduction of nitrate to N_2 was achieved at the presence of acetaminophen. • Complete degradation of acetaminophen was achieved at the presence of nitrate. • Over 95% of acetaminophen was mineralized in the VUV photoreactor. • VUV is a chemical-less advanced process for treating water emerging contaminants. - Abstract: This work was aimed at investigating the performance of the continuous-flow VUV photoreactor as a novel chemical-less advanced process for simultaneously oxidizing acetaminophen (ACT) as a model of pharmaceuticals and reducing nitrate in a single reactor. Solution pH was an important parameter affecting the performance of VUV; the highest ACT oxidation and nitrate reduction attained at solution pH between 6 and 8. The ACT was oxidized mainly by HO· while the aqueous electrons were the main working agents in the reduction of nitrate. The performance of VUV photoreactor improved with the increase of hydraulic retention time (HRT); the complete degradation of ACT and ∼99% reduction of nitrate with 100% N_2 selectivity achieved at HRT of 80 min. The VUV effluent concentrations of nitrite and ammonium at HRT of 80 min were below the drinking water standards. The real water sample contaminated with the ACT and nitrate was efficiently treated in the VUV photoreactor. Therefore, the VUV photoreactor is a chemical-less advanced process in which both advanced oxidation and advanced reduction reactions are accomplished. This unique feature possesses VUV photoreactor as a promising method of treating water contaminated with both pharmaceutical and nitrate.

Atmospheric pressure photoionization using tunable VUV synchrotron radiation

International Nuclear Information System (INIS)

Giuliani, A.; Giorgetta, J.-L.; Ricaud, J.-P.; Jamme, F.; Rouam, V.; Wien, F.; Laprévote, O.; Réfrégiers, M.

2012-01-01

Highlights: ► Coupling of an atmospheric pressure photoionization source with a vacuum ultra-violet (VUV) beamline. ► The set up allows photoionization up to 20 eV. ► Compared to classical atmospheric pressure photoionization (APPI), our set up offers spectral purity and tunability. ► Allows photoionization mass spectrometry on fragile and hard to vaporize molecules. - Abstract: We report here the first coupling of an atmospheric pressure photoionization (APPI) source with a synchrotron radiation beamline in the vacuum ultra-violet (VUV). A commercial APPI source of a QStar Pulsar i from AB Sciex was modified to receive photons from the DISCO beamline at the SOLEIL synchrotron radiation facility. Photons are delivered at atmospheric pressure in the 4–20 eV range. The advantages of this new set up, termed SR-APPI, over classical APPI are spectral purity and continuous tunability. The technique may also be used to perform tunable photoionization mass spectrometry on fragile compounds difficult to vaporize by classical methods.

Phase-Sensitive Control Of Molecular Dissociation Through Attosecond Pump/Strong-Field Mid-IR Probe Spectroscopy

Science.gov (United States)

2016-04-15

splitter (consisting of a thin, uncoated, silicon plate at brewsters angle) and the beams were focused onto the OPA crystal. For this work two...experiments in the future. These technologies include • Two-color driven (EUV/mid-IR) ion spectroscopy: we designed an interferometer combining EUV...isolated single-femtosecond EUV pulse generation: combining the use of low ionization threshold gas, an annual near-IR drive beam , polarization

Comparison of gate dielectric plasma damage from plasma-enhanced atomic layer deposited and magnetron sputtered TiN metal gates

Energy Technology Data Exchange (ETDEWEB)

Brennan, Christopher J.; Neumann, Christopher M.; Vitale, Steven A., E-mail: steven.vitale@ll.mit.edu [Lincoln Laboratory, Massachusetts Institute of Technology, Lexington, Massachusetts 02420 (United States)

2015-07-28

Fully depleted silicon-on-insulator transistors were fabricated using two different metal gate deposition mechanisms to compare plasma damage effects on gate oxide quality. Devices fabricated with both plasma-enhanced atomic-layer-deposited (PE-ALD) TiN gates and magnetron plasma sputtered TiN gates showed very good electrostatics and short-channel characteristics. However, the gate oxide quality was markedly better for PE-ALD TiN. A significant reduction in interface state density was inferred from capacitance-voltage measurements as well as a 1200× reduction in gate leakage current. A high-power magnetron plasma source produces a much higher energetic ion and vacuum ultra-violet (VUV) photon flux to the wafer compared to a low-power inductively coupled PE-ALD source. The ion and VUV photons produce defect states in the bulk of the gate oxide as well as at the oxide-silicon interface, causing higher leakage and potential reliability degradation.

Future prospect of the research study using intense and bright synchrotron radiation in VUV and soft x-ray region

International Nuclear Information System (INIS)

Tanaka, Kenichiro; Miyahara, Tsuneaki

1987-02-01

This report is the summary of the contents of the study meeting 'Future prospect of the research study using intense and bright synchrotron radiation in VUV and soft x-ray region' sponsored by PF, held on October 20 and 21, 1986. This study meeting was held by inviting those who are particularly interested in the basic field among the users of VUV and soft x-ray region, and the research on the application field was excluded. The objective of the discussion of this study meeting was to talk about the dream that if a high luminance light source which is 100 - 1000 times more intense in terms of luminous flux intensity is completed, what can we do with it. Three sessions on the themes 'How the existing research fields will develop', 'What the possible new research fields are' and 'Comment from the technical aspect' were held. More than seven years elapsed since the beginning of construction of the Photon Factory. Many excellent results have been obtained. As of October, 1986, the beam lines available for experiment are 11, the themes of common utilization experiment in progress are 300, and the number of registered researchers exceeded 1000. The development of a new light emission source is to be undertaken. (Kako, I.)

VUV photoemission studies of candidate Large Hadron Collider vacuum chamber materials

CERN Document Server

Cimino, R; Baglin, V

1999-01-01

In the context of future accelerators and, in particular, the beam vacuum of the Large Hadron Collider (LHC), a 27 km circumference proton collider to be built at CERN, VUV synchrotron radiation (SR) has been used to study both qualitatively and quantitatively candidate vacuum chamber materials. Emphasis is given to show that angle and energy resolved photoemission is an extremely powerful tool to address important issues relevant to the LHC, such as the emission of electrons that contributes to the creation of an electron cloud which may cause serious beam instabilities and unmanageable heat loads on the cryogenic system. Here we present not only the measured photoelectron yields from the proposed materials, prepared on an industrial scale, but also the energy and in some cases the angular dependence of the emitted electrons when excited with either a white light (WL) spectrum, simulating that in the arcs of the LHC, or monochromatic light in the photon energy range of interest. The effects on the materials ...

Characterization of Vacuum Ultraviolet (VUV) Radiation for the Development of a Fluorescent Lamp

International Nuclear Information System (INIS)

Khatun, Hasina; Sharma, A. K.; Barhai, P. K.

2011-01-01

A negative unipolar pulsed voltage is applied to study internal electrical parameters of the xenon filled dielectric barrier discharge (DBD) sources. The VUV radiation emitted from these sources is characterized by means of the photoluminescence intensity of the red phosphor pellet. The red phosphor converts the VUV radiation into visible radiation and the emission spectra include a peak at 619.56 nm. The emission characteristics of the red phosphor are analyzed in terms of the pressure-distance (pd), rise time and frequency of the pulsed voltage waveform. The emission intensity measured at different operational conditions confirms that the formation and decay of the xenon excimer, Xe 2 *, increase with the increase in reduced electric field, E/N. After exceeding certain limits of E/N, the intensity of Xe 2 * decreases rapidly. (plasma technology)

Measurement of impurity emission profiles in CHS Plasma using AXUV photodiode arrays and VUV bandpass filters

International Nuclear Information System (INIS)

Suzuki, C.; Peterson, B.J.; Ida, K.

2004-01-01

We have designed a compact and low-cost diagnostic system for spatiotemporal distributions of specific vacuum ultraviolet (VUV) emission lines from impurities in Compact Helical System (CHS) plasmas. The system consists of 20 channel absolute extreme ultraviolet photodiode arrays combined with interchangeable thin foil filters which have passbands in the VUV region. A compact mounting module which contains all the components including an in-vacuum preamplifier for immediate current-voltage conversion has been designed and successfully fabricated. A preliminary measurement with a single module using an aluminum foil filter has been carried out for monitoring the behavior of oxygen impurity in CHS, and initial results have been obtained. Two identical modules equipped with Versa Module European bus-based analog-digital converters will be available for future tomographic measurements

Demonstration of two-electron (shake-up) photoionization and population inversions in the visible and VUV

International Nuclear Information System (INIS)

Silfvast, W.T.; Wood, O.R. II; Al-Salameh, D.Y.

1986-01-01

The two-electron (shake-up) photoionization process has been shown to be an effective mechanism for producing large population inversions in He/sup +/ with gain at 164 nm and in Ar/sup +/ with gain at 428 and 477 nm and for observing the first autoionizing states in Cd/sup +/. Such a mechanism was recently proposed as an excitation mechanism for a VUV laser in lithium. In each species the rapid excitation and detection using broadband emission from a 30-mJ 100-ps duration laser-produced plasma and a detection system with subnanosecond time resolution were essential in observing these effects. In He, gains of up to 0.8 cm/sup -1/ for durations of 2-4 ns at 164.0 nm on the He-like (n = 3-2) transition in He/sup +/ were measured by comparing the plasma emission from a well-defined volume with and without the presence of a mirror of known reflectivity. The n = 3 upper laser level is pumped not only directly via two-electron photoionization from the neutral ground state but also indirectly (in times of the order of 1-2 ns) via electron collisions from photoionization-pumped higher-lying levels. The decay rate of the photoionization-pumped radiation-trapped lower laser level is increased by a unique process involving absorption of radiation via photoionization of ground state neutral helium atoms

VUV photo-oxidation of gaseous benzene combined with ozone-assisted catalytic oxidation: Effect on transition metal catalyst

Science.gov (United States)

Huang, Haibao; Lu, Haoxian; Zhan, Yujie; Liu, Gaoyuan; Feng, Qiuyu; Huang, Huiling; Wu, Muyan; Ye, Xinguo

2017-01-01

Volatile organic compounds (VOCs) cause the major air pollution concern. In this study, a series of ZSM-5 supported transition metals were prepared by impregnation method. They were combined with vacuum UV (VUV) photo-oxidation in a continuous-flow packed-bed reactor and used for the degradation of benzene, a typical toxic VOCs. Compared with VUV photo-oxidation alone, the introduction of catalysts can greatly enhance benzene oxidation under the help of O3, the by-products from VUV irradiation, via ozone-assisted catalytic oxidation (OZCO). The catalytic activity of transition metals towards benzene oxidation followed the order: Mn > Co > Cu > Ni > Fe. Mn achieved the best catalytic activity due to the strongest capability for O3 catalytic decomposition and utilization. Benzene and O3 removal efficiency reached as high as 97% and 100% after 360 min, respectively. O3 was catalytically decomposed, generating highly reactive oxidants such as rad OH and rad O for benzene oxidation.

Opponent-Color Fusion of Multi-Sensor Imagery: Visible, IR and SAR

National Research Council Canada - National Science Library

Waxman, A

1998-01-01

.... Building on the work reported in two of our earlier papers from IRIS Passive Sensors 1996, we show how opponent-color processing and center-surround shunting neural networks can be used to develop...

P1-9: Relationship between Color Shifts in Land's Two-Color Method and Higher- and Lower-Level Visual Information

Directory of Open Access Journals (Sweden)

Saki Iwaida

2012-10-01

Full Text Available Land's two-color method gives rise to apparent full-color perception, even though only two colors (e.g., red and gray are used. Previous studies indicate that chromatic adaptation, color memory, and inductive effects contribute to the shifts of color perception from real to illusory colors (e.g., Kuriki, 2006 Vision Research 46 3055–3066. This paper investigates the relationship between the color shifts induced by Land images and the skewness of the luminance histogram. In Experiment 1, several Land images are created based on a yellow ball, and the magnitude of the color shifts of the images are measured. The results of Experiment 1 show a significant correlation between the magnitude of the color shifts and skewness, suggesting that skewness is critical for the color shifts. In Experiment 2, we test the hypothesis that color shifts depends on just skewness; the color shifts should be invariant even if the Land images are scrambled. However, the results of Experiment 2 demonstrate that scrambled Land images exhibit less intense color shifts, suggesting that color shifts are determined by the object's overall shape or surface gloss, not just skewness. Taken together, we conclude that both low-level visual processes, such as those associated with luminance histogram skew, and high-level cognitive functions, such as object interpretation or understanding of surface gloss, are involved in the color shift of Land images.

Simultaneous removal of NO and SO2 using vacuum ultraviolet light (VUV)/heat/peroxymonosulfate (PMS).

Science.gov (United States)

Liu, Yangxian; Wang, Yan; Wang, Qian; Pan, Jianfeng; Zhang, Jun

2018-01-01

Simultaneous removal process of SO 2 and NO from flue gas using vacuum ultraviolet light (VUV)/heat/peroxymonosulfate (PMS) in a VUV spraying reactor was proposed. The key influencing factors, active species, reaction products and mechanism of SO 2 and NO simultaneous removal were investigated. The results show that vacuum ultraviolet light (185 nm) achieves the highest NO removal efficiency and yield of and under the same test conditions. NO removal is enhanced at higher PMS concentration, light intensity and oxygen concentration, and is inhibited at higher NO concentration, SO 2 concentration and solution pH. Solution temperature has a double impact on NO removal. CO 2 concentration has no obvious effect on NO removal. and produced from VUV-activation of PMS play a leading role in NO removal. O 3 and ·O produced from VUV-activation of O 2 also play an important role in NO removal. SO 2 achieves complete removal under all experimental conditions due to its very high solubility in water and good reactivity. The highest simultaneous removal efficiency of SO 2 and NO reaches 100% and 91.3%, respectively. Copyright © 2017 Elsevier Ltd. All rights reserved.

VUV photo-oxidation of gaseous benzene combined with ozone-assisted catalytic oxidation: Effect on transition metal catalyst

International Nuclear Information System (INIS)

Huang, Haibao; Lu, Haoxian; Zhan, Yujie; Liu, Gaoyuan; Feng, Qiuyu; Huang, Huiling; Wu, Muyan; Ye, Xinguo

2017-01-01

Graphical abstract: Mn nanoparticles are highly dispersed on ZSM-5 and most efficient in benzene degradation in the VUV-OZCO process. - Highlights: • Vacuum UV irradiation is well combined with O_3 catalytic oxidation. • O_3 byproducts was used to enhance catalytic oxidation of VOCs. • Mn/ZSM-5 achieved the best catalytic activity for benzene degradation. - Abstract: Volatile organic compounds (VOCs) cause the major air pollution concern. In this study, a series of ZSM-5 supported transition metals were prepared by impregnation method. They were combined with vacuum UV (VUV) photo-oxidation in a continuous-flow packed-bed reactor and used for the degradation of benzene, a typical toxic VOCs. Compared with VUV photo-oxidation alone, the introduction of catalysts can greatly enhance benzene oxidation under the help of O_3, the by-products from VUV irradiation, via ozone-assisted catalytic oxidation (OZCO). The catalytic activity of transition metals towards benzene oxidation followed the order: Mn > Co > Cu > Ni > Fe. Mn achieved the best catalytic activity due to the strongest capability for O_3 catalytic decomposition and utilization. Benzene and O_3 removal efficiency reached as high as 97% and 100% after 360 min, respectively. O_3 was catalytically decomposed, generating highly reactive oxidants such as ·OH and ·O for benzene oxidation.

VUV photo-oxidation of gaseous benzene combined with ozone-assisted catalytic oxidation: Effect on transition metal catalyst

Energy Technology Data Exchange (ETDEWEB)

Huang, Haibao, E-mail: seabao8@gmail.com [School of Environmental Science and Engineering, Sun Yat-Sen University (China); Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology (Sun Yat-sen University) (China); Lu, Haoxian; Zhan, Yujie; Liu, Gaoyuan; Feng, Qiuyu; Huang, Huiling; Wu, Muyan; Ye, Xinguo [School of Environmental Science and Engineering, Sun Yat-Sen University (China)

2017-01-01

Graphical abstract: Mn nanoparticles are highly dispersed on ZSM-5 and most efficient in benzene degradation in the VUV-OZCO process. - Highlights: • Vacuum UV irradiation is well combined with O{sub 3} catalytic oxidation. • O{sub 3} byproducts was used to enhance catalytic oxidation of VOCs. • Mn/ZSM-5 achieved the best catalytic activity for benzene degradation. - Abstract: Volatile organic compounds (VOCs) cause the major air pollution concern. In this study, a series of ZSM-5 supported transition metals were prepared by impregnation method. They were combined with vacuum UV (VUV) photo-oxidation in a continuous-flow packed-bed reactor and used for the degradation of benzene, a typical toxic VOCs. Compared with VUV photo-oxidation alone, the introduction of catalysts can greatly enhance benzene oxidation under the help of O{sub 3}, the by-products from VUV irradiation, via ozone-assisted catalytic oxidation (OZCO). The catalytic activity of transition metals towards benzene oxidation followed the order: Mn > Co > Cu > Ni > Fe. Mn achieved the best catalytic activity due to the strongest capability for O{sub 3} catalytic decomposition and utilization. Benzene and O{sub 3} removal efficiency reached as high as 97% and 100% after 360 min, respectively. O{sub 3} was catalytically decomposed, generating highly reactive oxidants such as ·OH and ·O for benzene oxidation.

Validation of ATR FT-IR to identify polymers of plastic marine debris, including those ingested by marine organisms

Science.gov (United States)

Jung, Melissa R.; Horgen, F. David; Orski, Sara V.; Rodriguez, Viviana; Beers, Kathryn L.; Balazs, George H.; Jones, T. Todd; Work, Thierry M.; Brignac, Kayla C.; Royer, Sarah-Jeanne; Hyrenbach, David K.; Jensen, Brenda A.; Lynch, Jennifer M.

2018-01-01

Polymer identification of plastic marine debris can help identify its sources, degradation, and fate. We optimized and validated a fast, simple, and accessible technique, attenuated total reflectance Fourier transform infrared spectroscopy (ATR FT-IR), to identify polymers contained in plastic ingested by sea turtles. Spectra of consumer good items with known resin identification codes #1–6 and several #7 plastics were compared to standard and raw manufactured polymers. High temperature size exclusion chromatography measurements confirmed ATR FT-IR could differentiate these polymers. High-density (HDPE) and low-density polyethylene (LDPE) discrimination is challenging but a clear step-by-step guide is provided that identified 78% of ingested PE samples. The optimal cleaning methods consisted of wiping ingested pieces with water or cutting. Of 828 ingested plastics pieces from 50 Pacific sea turtles, 96% were identified by ATR FT-IR as HDPE, LDPE, unknown PE, polypropylene (PP), PE and PP mixtures, polystyrene, polyvinyl chloride, and nylon.

A quantum-rovibrational-state-selected study of the proton-transfer reaction H2+(X2Σ: v+ = 1-3; N+ = 0-3) + Ne → NeH+ + H using the pulsed field ionization-photoion method: observation of the rotational effect near the reaction threshold.

Science.gov (United States)

Xiong, Bo; Chang, Yih-Chung; Ng, Cheuk-Yiu

2017-07-19

Using the sequential electric field pulsing scheme for vacuum ultraviolet (VUV) laser pulsed field ionization-photoion (PFI-PI) detection, we have successfully prepared H 2 + (X 2 Σ: v + = 1-3; N + = 0-5) ions in the form of an ion beam in single quantum-rovibrational-states with high purity, high intensity, and narrow laboratory kinetic energy spread (ΔE lab ≈ 0.05 eV). This VUV-PFI-PI ion source, when coupled with the double-quadrupole double-octupole ion-molecule reaction apparatus, has made possible a systematic examination of the vibrational- as well as rotational-state effects on the proton transfer reaction of H 2 + (X 2 Σ: v + ; N + ) + Ne. Here, we present the integral cross sections [σ(v + ; N + )'s] for the H 2 + (v + = 1-3; N + = 0-3) + Ne → NeH + + H reaction observed in the center-of-mass kinetic energy (E cm ) range of 0.05-2.00 eV. The σ(v + = 1, N + = 1) exhibits a distinct E cm onset, which is found to agree with the endothermicity of 0.27 eV for the proton transfer process after taking into account of experimental uncertainties. Strong v + -vibrational enhancements are observed for σ(v + = 1-3, N + ) in the E cm range of 0.05-2.00 eV. While rotational excitations appear to have little effect on σ(v + = 3, N + ), a careful search leads to the observation of moderate N + -rotational enhancements at v + = 2: σ(v + = 2; N + = 0) quantum dynamics predictions. We hope that these new experimental results would further motivate more rigorous theoretical calculations on the dynamics of this prototypical ion-molecule reaction.

National Synchrotron Light Source user's manual: Guide to the VUV and x-ray beamlines

International Nuclear Information System (INIS)

Gmuer, N.F.

1993-04-01

The success of the National Synchrotron Light Source is based, in large part, on the size of the user community and the diversity of the scientific and technical disciplines represented by these users. As evidence of this success, the VUV Ring has just celebrated its 10th anniversary and the X-ray Ring will do the same in 1995. In order to enhance this success, the NSLS User's Manual: Guide to the VUV and X-Ray Beamlines - Fifth Edition, is being published. This Manual presents to the scientific community-at-large the current and projected architecture, capabilities and research programs of the various VUV and X-ray beamlines. Also detailed is the research and computer equipment a General User can expect to find and use at each beamline when working at the NSLS. The Manual is updated periodically in order to keep pace with the constant changes on these beamlines

Investigation of dynamic of unconsolidated materials using two-color digital holography

Directory of Open Access Journals (Sweden)

Boileau J.-P.

2010-06-01

Full Text Available The paper presents a two-color digital holographic interferometer. The set-up is devoted to the study of the fundamental dynamic of unconsolidated materials. Optical configuration and algorithms to recover the optical phase of two-color digitally encoded holograms are described. The method is based on a spatial-color-multiplexing scheme in which holographic reconstruction is performed using adapted wavelength zero-padding and reconstructing distance. Experimental results are presented in the case of granular media excited in the frequency range 400Hz-3000Hz and exhibits the 3D movement.

Simultaneous nitrate reduction and acetaminophen oxidation using the continuous-flow chemical-less VUV process as an integrated advanced oxidation and reduction process.

Science.gov (United States)

Moussavi, Gholamreza; Shekoohiyan, Sakine

2016-11-15

This work was aimed at investigating the performance of the continuous-flow VUV photoreactor as a novel chemical-less advanced process for simultaneously oxidizing acetaminophen (ACT) as a model of pharmaceuticals and reducing nitrate in a single reactor. Solution pH was an important parameter affecting the performance of VUV; the highest ACT oxidation and nitrate reduction attained at solution pH between 6 and 8. The ACT was oxidized mainly by HO while the aqueous electrons were the main working agents in the reduction of nitrate. The performance of VUV photoreactor improved with the increase of hydraulic retention time (HRT); the complete degradation of ACT and ∼99% reduction of nitrate with 100% N2 selectivity achieved at HRT of 80min. The VUV effluent concentrations of nitrite and ammonium at HRT of 80min were below the drinking water standards. The real water sample contaminated with the ACT and nitrate was efficiently treated in the VUV photoreactor. Therefore, the VUV photoreactor is a chemical-less advanced process in which both advanced oxidation and advanced reduction reactions are accomplished. This unique feature possesses VUV photoreactor as a promising method of treating water contaminated with both pharmaceutical and nitrate. Copyright © 2016 Elsevier B.V. All rights reserved.

PLA/Bio-PE blends: effect of the Bio-PE content on the crystallinity rheological properties

International Nuclear Information System (INIS)

Araujo, Aylanna P.M. de; Agrawal, Pankaj; Cavalcanti, Shirley N.; Alves, Amanda M.; Melo, Tomas J.A. de; Brito, Gustavo F.

2014-01-01

The aim of this work is to evaluate the effect of the Bio-PE content on the crystallinity and rheological properties of PLA/Bio-PE blend. The blends containing 05 and 15% of Bio-PE were prepared by extrusion followed by injection molding and characterized by X-Ray Diffraction (XRD) and rheological properties at low and high shear rates. XRD results indicated that the PLA present low crystallinity and this behavior was not changed with the addition of Bio-PE, regardless of Bio-PE content. Rheological properties results indicated that at low shear rates the viscosity of the PLA/Bio-PE increased with the increase in the Bio-PE content while at high shear rates the viscosities where almost similar, which may be ascribed to the orientation of Bio-PE particles in the flow direction or by the viscous dissipation. (author)

VUV spectroscopic measurement in current drive experiments in TRIAM-1M

International Nuclear Information System (INIS)

Hara, Shigemitsu; Kawasaki, Shoji; Jotaki, Eriko; Moriyama, Shin-ichi; Nagao, Akihiro; Nakamura, Kazuo; Nakamura, Yukio; Hiraki, Naoji; Itoh, Satoshi

1991-01-01

VUV spectrum and time evolution of line intensity were measured. Steady-state transport equation was solved numerically, and the solution was qualitatively compared with the experimental results. (author)

Research on LLCL Filtering Grid - Connected inverter under the Control of PFI

Science.gov (United States)

Li, Ren-qing; Zong, Ke-yong; Wang, Yan-ping; Li, Yang; Zhang, Jing

2018-03-01

This passage puts forward a kind of LLCL inverter which is based on the proportional feedback integral(PFI) control so as so satisfy the request of the grid-current outputed by the renewable energy generation system. The passage builds the topological graph of grid-connected inverter and makes an analysis of principle of linear superposition aims to reveal the essence of the problem of steady-state error that exists in proportional integral control. We use LLCL filter and the method of passive damping to solve the problem of resonant peak. We make simulation of the grid system with the software named MATLAB/Simulink. The result shows that the grid current enters steady state quickly and in the same time, which has the identical phase and frequency of grid-voltage. The harmonic content in grid current satisfies the request of grid standard.

Four therapeutic cases of RS3PE syndrome

International Nuclear Information System (INIS)

Nakajima, Naoya; Fukuda, Yukiko; Yang, Kwang-Seok; Aiba, Miyoji; Tsuda, Hiroshi

2007-01-01

RS3PE syndrome (Remitting Seronegative Symmetrical Synovitis with Pitting Edema Syndrome) is one of the disorders which present as polyarthritis. It is important to be aware of RS3PE syndrome when encountering elderly patients with polyarthritis who are negative for rheumatoid factor. We report 4 cases of RS3PE syndrome. All cases shared common clinical findings, such as acute onset, symmetrical polyarthritis, pitting edema of the hands and feet, and being negative for rheumatoid factor in serum. Treatment with corticosteroid was very effective in all cases. However, two patients showed a deteriorated clinical condition during the tapering of corticosteroid. Corticosteroid should be tapered off cautiously in patients with RS3PE syndrome. (author)

Effect of HALS on radiation discoloration of PE

International Nuclear Information System (INIS)

Wang Huiliang; Wang Chun; Chen Wenxiu

2001-01-01

The effects of hindered amine light stabilizers (HALS) on the radiation-induced discoloration of polyethylene (PE) are studied by measuring the yellowness index (YI) of PE. It is found that all the HALS used are effective in preventing PE from radiation-induced discoloration. The YI of PE added pentamethyl HALS (PMPM, PPMPM) is a little higher than that of PE added corresponding tetramethyl HALS (TMPM, PTMPM) when radiation dose is low than 100 kGy, but when the radiation dose is higher than 100 kGy, the YI of PE added pentamethyl HALS is lower. Pentamethyl HALS is more effective in preventing PE from radiation-induced discoloration when radiation dose is higher. It is also found that polymeric HALS is more effective in preventing PE from radiation-induced discoloration than corresponding monomeric HALS when radiation dose is higher than 200 kGy. The formation of alkyl free radical, carbonyl after irradiation is measured. It is found that the relative concentration of free radical formed in PE added TMPM is higher than that of PE added PMPM when radiation dose is relatively high. The carbonyl index of PE containing pentamethyl HALS is less than that of PE containing tetramethyl HALS when radiation is relatively low, but the results is contrary when radiation dose is relatively high. It is believed that HALS prevents PE from radiation-induced discoloration by scavenging free radicals formed in irradiated PE

A fast VUV light pulser for testing ring-imaging Cerenkov counters

International Nuclear Information System (INIS)

Margulies, S.; Ozelis, J.

1986-01-01

A simple, fast, VUV light pulser for testing a TMAE-based, time-projection-chamber-type photon detector for a ring-imaging Cerenkov counter is described. The pulser consists of an automobile spark plug fired in a controlled atmosphere by a relaxation oscillator. The resulting VUV spectrum, spark-current pulse, and light pulse were investigated for hydrogen, xenon, krypton, and nitrogen fills. The best pulse (3.5 ns FWHM) was obtained with hydrogen at 60 kPa absolute pressure. Xenon was, generally, unsuitable because it continued to emit light for more than a microsecond after excitation. With krypton and nitrogen, no light was emitted in the wavelength region of interest except for a series of sharp lines attributable to the electrodes

Efficient degradation of H2S over transition metal modified TiO2 under VUV irradiation: Performance and mechanism

Science.gov (United States)

Liu, Gaoyuan; Ji, Jian; Hu, Peng; Lin, Sixin; Huang, Haibao

2018-03-01

Odor pollution causes great harm to the atmospheric environment and human health. H2S, as an odor gas, is highly toxic and corrosive and thus requires removal efficiently. In this study, TiO2 catalysts modified by transition metals including Mn, Cu, Ni and Co, were prepared using a modified sol-gelatin method and tested under UV-PCO or VUV-PCO process. H2S degradation was great enhanced in VUV-PCO compared with conventional UV-PCO. Among the catalysts, 1 wt% Mn-TiO2 showed the highest removal efficiency of 89.9%, which is 30 times higher than that under 254 nm UV irradiation. Residual ozone in the outlet can be completely eliminated by Mn-TiO2. Photocatalytic oxidation, photolysis and ozone-assisted catalytic oxidation all involved in the VUV-PCO process and their contribution were determined by H2S removal efficiency.

Two-dimensional color-code quantum computation

International Nuclear Information System (INIS)

Fowler, Austin G.

2011-01-01

We describe in detail how to perform universal fault-tolerant quantum computation on a two-dimensional color code, making use of only nearest neighbor interactions. Three defects (holes) in the code are used to represent logical qubits. Triple-defect logical qubits are deformed into isolated triangular sections of color code to enable transversal implementation of all single logical qubit Clifford group gates. Controlled-NOT (CNOT) is implemented between pairs of triple-defect logical qubits via braiding.

Determining the best forecasting method to estimate unitary charges price indexes of PFI data in central region Peninsular Malaysia

Science.gov (United States)

Ahmad Kamaruddin, Saadi Bin; Md Ghani, Nor Azura; Mohamed Ramli, Norazan

2013-04-01

The concept of Private Financial Initiative (PFI) has been implemented by many developed countries as an innovative way for the governments to improve future public service delivery and infrastructure procurement. However, the idea is just about to germinate in Malaysia and its success is still vague. The major phase that needs to be given main attention in this agenda is value for money whereby optimum efficiency and effectiveness of each expense is attained. Therefore, at the early stage of this study, estimating unitary charges or materials price indexes in each region in Malaysia was the key objective. This particular study aims to discover the best forecasting method to estimate unitary charges price indexes in construction industry by different regions in the central region of Peninsular Malaysia (Selangor, Federal Territory of Kuala Lumpur, Negeri Sembilan, and Melaka). The unitary charges indexes data used were from year 2002 to 2011 monthly data of different states in the central region Peninsular Malaysia, comprising price indexes of aggregate, sand, steel reinforcement, ready mix concrete, bricks and partition, roof material, floor and wall finishes, ceiling, plumbing materials, sanitary fittings, paint, glass, steel and metal sections, timber and plywood. At the end of the study, it was found that Backpropagation Neural Network with linear transfer function produced the most accurate and reliable results for estimating unitary charges price indexes in every states in central region Peninsular Malaysia based on the Root Mean Squared Errors, where the values for both estimation and evaluation sets were approximately zero and highly significant at p Malaysia. The estimated price indexes of construction materials will contribute significantly to the value for money of PFI as well as towards Malaysian economical growth.

Intrinsic Property Forecast Index (iPFI) as a Rule of Thumb for Medicinal Chemists to Remove a Phototoxicity Liability.

Science.gov (United States)

Fournier, Jean-François; Bouix-Peter, Claire; Duvert, Denis; Luzy, Anne-Pascale; Ouvry, Gilles

2018-04-12

Phototoxicity occurs when UV irradiation causes otherwise benign compounds to become irritant, sensitizers, or even genotoxic. This toxicity is particularly a concern after topical application and in dermatological programs where skin irritation can be incompatible with the desired therapeutic outcome. This brief article establishes that the intrinsic property forecast index (iPFI) can be used to evaluate the probability of a compound being phototoxic and gives medicinal chemists a practical tool to handle this liability.

Optical microscope using an interferometric source of two-color, two-beam entangled photons

Science.gov (United States)

Dress, William B.; Kisner, Roger A.; Richards, Roger K.

2004-07-13

Systems and methods are described for an optical microscope using an interferometric source of multi-color, multi-beam entangled photons. A method includes: downconverting a beam of coherent energy to provide a beam of multi-color entangled photons; converging two spatially resolved portions of the beam of multi-color entangled photons into a converged multi-color entangled photon beam; transforming at least a portion of the converged multi-color entangled photon beam by interaction with a sample to generate an entangled photon specimen beam; and combining the entangled photon specimen beam with an entangled photon reference beam within a single beamsplitter. An apparatus includes: a multi-refringent device providing a beam of multi-color entangled photons; a condenser device optically coupled to the multi-refringent device, the condenser device converging two spatially resolved portions of the beam of multi-color entangled photons into a converged multi-color entangled photon beam; a beam probe director and specimen assembly optically coupled to the condenser device; and a beam splitter optically coupled to the beam probe director and specimen assembly, the beam splitter combining an entangled photon specimen beam from the beam probe director and specimen assembly with an entangled photon reference beam.

Recombination in pe/ppe genes contributes to genetic variation in Mycobacterium tuberculosis lineages

KAUST Repository

Phelan, Jody E.

2016-02-29

Background Approximately 10 % of the Mycobacterium tuberculosis genome is made up of two families of genes that are poorly characterized due to their high GC content and highly repetitive nature. The PE and PPE families are typified by their highly conserved N-terminal domains that incorporate proline-glutamate (PE) and proline-proline-glutamate (PPE) signature motifs. They are hypothesised to be important virulence factors involved with host-pathogen interactions, but their high genetic variability and complexity of analysis means they are typically disregarded in genome studies. Results To elucidate the structure of these genes, 518 genomes from a diverse international collection of clinical isolates were de novo assembled. A further 21 reference M. tuberculosis complex genomes and long read sequence data were used to validate the approach. SNP analysis revealed that variation in the majority of the 168 pe/ppe genes studied was consistent with lineage. Several recombination hotspots were identified, notably pe_pgrs3 and pe_pgrs17. Evidence of positive selection was revealed in 65 pe/ppe genes, including epitopes potentially binding to major histocompatibility complex molecules. Conclusions This, the first comprehensive study of the pe and ppe genes, provides important insight into M. tuberculosis diversity and has significant implications for vaccine development.

Enhancement of VUV emission from a coaxial xenon excimer ultraviolet lamp driven by distorted bipolar square voltages

Energy Technology Data Exchange (ETDEWEB)

Jou, S.Y.; Hung, C.T.; Chiu, Y.M.; Wu, J.S. [Department of Mechanical Engineering, National Chiao Tung University, Hsinchu (China); Wei, B.Y. [High-Efficiency Gas Discharge Lamps Group, Material and Chemical Research Laboratories, Hsinchu (China)

2011-12-15

Enhancement of vacuum UV emission (172 nm VUV) from a coaxial xenon excimer UV lamp (EUV) driven by distorted 50 kHz bipolar square voltages, as compared to that by sinusoidal voltages, is investigated numerically in this paper. A self-consistent radial one-dimensional fluid model, taking into consideration non-local electron energy balance, is employed to simulate the discharge physics and chemistry. The discharge is divided into two three-period portions; these include: the pre-discharge, the discharge (most intense at 172 nm VUV emission) and the post-discharge periods. The results show that the efficiency of VUV emission using the distorted bipolar square voltages is much greater than when using sinusoidal voltages; this is attributed to two major mechanisms. The first is the much larger rate of change of the voltage in bipolar square voltages, in which only the electrons can efficiently absorb the power in a very short period of time. Energetic electrons then generate a higher concentration of metastable (and also excited dimer) xenon that is distributed more uniformly across the gap, for a longer period of time during the discharge process. The second is the comparably smaller amount of ''wasted'' power deposition by Xe{sup +}{sub 2} in the post-discharge period, as driven by distorted bipolar square voltages, because of the nearly vanishing gap voltage caused by the shielding effect resulting from accumulated charges on both dielectric surfaces (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Strong ligand field effects of blue phosphorescent Ir(III) complexes with phenylpyrazole and phosphines.

Science.gov (United States)

Park, Se Won; Ham, Ho Wan; Kim, Young Sik

2012-04-01

In the paper, we describe new Ir complexes for achieving efficient blue phosphorescence. New blue-emitting mixed-ligand Ir complexes comprising one cyclometalating, two phosphines trans to each other such as Ir(dppz)(PPh3)2(H)(L) (Ll= Cl, NCMe+, CN), [dppz = 3,5-Diphenylpyrazole] were synthesized and studied to tune the phosphorescence wavelength to the deep blue region and to enhance the luminescence efficiencies. To gain insight into the factors responsible for the emission color change and the variation of luminescence efficiency, we investigate the electron-withdrawing capabilities of ancillary ligands using DFT and TD-DFT calculations on the ground and excited states of the complexes. To achieve deep blue emission and increase the emission efficiency, (1) we substitute the phenyl group on the 3-position of the pyrazole ring that lowers the triplet energy enough that the quenching channel is not thermally accessible and (2) change the ancillary ligands coordinated to iridium atom to phosphine and cyano groups known as very strong field ligands. Their inclusion in the coordination sphere can increase the HOMO-LUMO gap to achieve the hypsochromic shift in emission color and lower the HOMO and LUMO energy level, which causes a large d-orbital energy splitting and avoids the quenching effect to improve the luminescence efficiency. The maximum emission spectra of Ir(dppz)(PPh3)2(H)(CI) and Ir(dppz)(PPh3)2(H)(CN) were in the ranges of 439, 432 nm, respectively.

Experience with a high-brightness storage ring: the NSLS 750 MeV vuv ring

International Nuclear Information System (INIS)

Galayda, J.

1984-01-01

The NSLS vuv ring is the first implementation of the proposals of R. Chasman and G.K. Green for a synchrotron radiation source with enhanced brightness: its lattice is a series of achromatic bends with two zero-gradient dipoles each, giving small damped emittance; and these bends are connected by straight sections with zero dispersion to accommodate wigglers and undulators without degrading the radiation damping properties of the ring. The virtues of the Chasman-Green lattice, its small betatron and synchrotron emittances, may be understood with some generality; e.g. the electron γm 0 c 2 energy and the number of achromatic bends M sets a lower limit on the betatron emittance of e/sub x/ > 7.7 x 10 -13 γ 2 /M meter-radians. There is strong interest in extrapolation of this type of lattice to 6 GeV and to 32 achromatic bends. The subject of this report is the progress toward achieving performance in the vuv ring limited by the radiation damping parameters optimized in its design. 14 refs., 4 figs., 1 tab

FORMATION OF S-BEARING SPECIES BY VUV/EUV IRRADIATION OF H2S-CONTAINING ICE MIXTURES: PHOTON ENERGY AND CARBON SOURCE EFFECTS

International Nuclear Information System (INIS)

Chen, Y.-J.; Juang, K.-J.; Qiu, J.-M.; Chu, C.-C.; Yih, T.-S.; Nuevo, M.; Jiménez-Escobar, A.; Muñoz Caro, G. M.; Wu, C.-Y. R.; Fung, H.-S.; Ip, W.-H.

2015-01-01

Carbonyl sulfide (OCS) is a key molecule in astrobiology that acts as a catalyst in peptide synthesis by coupling amino acids. Experimental studies suggest that hydrogen sulfide (H 2 S), a precursor of OCS, could be present in astrophysical environments. In the present study, we used a microwave-discharge hydrogen-flow lamp, simulating the interstellar UV field, and a monochromatic synchrotron light beam to irradiate CO:H 2 S and CO 2 :H 2 S ice mixtures at 14 K with vacuum ultraviolet (VUV) or extreme ultraviolet (EUV) photons in order to study the effect of the photon energy and carbon source on the formation mechanisms and production yields of S-containing products (CS 2 , OCS, SO 2 , etc.). Results show that (1) the photo-induced OCS production efficiency in CO:H 2 S ice mixtures is higher than that of CO 2 :H 2 S ice mixtures; (2) a lower concentration of H 2 S enhances the production efficiency of OCS in both ice mixtures; and (3) the formation pathways of CS 2 differ significantly upon VUV and EUV irradiations. Furthermore, CS 2 was produced only after VUV photoprocessing of CO:H 2 S ices, while the VUV-induced production of SO 2 occurred only in CO 2 :H 2 S ice mixtures. More generally, the production yields of OCS, H 2 S 2 , and CS 2 were studied as a function of the irradiation photon energy. Heavy S-bearing compounds were also observed using mass spectrometry during the warm-up of VUV/EUV-irradiated CO:H 2 S ice mixtures. The presence of S-polymers in dust grains may account for the missing sulfur in dense clouds and circumstellar environments

The differing magnitude distributions of the two Jupiter Trojan color populations

Energy Technology Data Exchange (ETDEWEB)

Wong, Ian; Brown, Michael E. [Division of Geological and Planetary Sciences, California Institute of Technology Pasadena, CA 91125 (United States); Emery, Joshua P., E-mail: iwong@caltech.edu [Department of Earth and Planetary Sciences, University of Tennessee Knoxville, TN 37996 (United States)

2014-12-01

The Jupiter Trojans are a significant population of minor bodies in the middle solar system that have garnered substantial interest in recent years. Several spectroscopic studies of these objects have revealed notable bimodalities with respect to near-infrared spectra, infrared albedo, and color, which suggest the existence of two distinct groups among the Trojan population. In this paper, we analyze the magnitude distributions of these two groups, which we refer to as the red and less red color populations. By compiling spectral and photometric data from several previous works, we show that the observed bimodalities are self-consistent and categorize 221 of the 842 Trojans with absolute magnitudes in the range H<12.3 into the two color populations. We demonstrate that the magnitude distributions of the two color populations are distinct to a high confidence level (>95%) and fit them individually to a broken power law, with special attention given to evaluating and correcting for incompleteness in the Trojan catalog as well as incompleteness in our categorization of objects. A comparison of the best-fit curves shows that the faint-end power-law slopes are markedly different for the two color populations, which indicates that the red and less red Trojans likely formed in different locations. We propose a few hypotheses for the origin and evolution of the Trojan population based on the analyzed data.

Two-color walking Peregrine solitary waves.

Science.gov (United States)

Baronio, Fabio; Chen, Shihua; Mihalache, Dumitru

2017-09-15

We study the extreme localization of light, evolving upon a non-zero background, in two-color parametric wave interaction in nonlinear quadratic media. We report the existence of quadratic Peregrine solitary waves, in the presence of significant group-velocity mismatch between the waves (or Poynting vector beam walk-off), in the regime of cascading second-harmonic generation. This finding opens a novel path for the experimental demonstration of extreme rogue waves in ultrafast quadratic nonlinear optics.

How do we select multiple features? Transient costs for selecting two colors rather than one, persistent costs for color-location conjunctions.

Science.gov (United States)

Lo, Shih-Yu; Holcombe, Alex O

2014-02-01

In a previous study Lo, Howard, & Holcombe (Vision Research 63:20-33, 2012), selecting two colors did not induce a performance cost, relative to selecting one color. For example, requiring possible report of both a green and a red target did not yield a worse performance than when both targets were green. Yet a cost of selecting multiple colors was observed when selection needed be contingent on both color and location. When selecting a red target to the left and a green target to the right, superimposing a green distractor to the left and a red distractor to the right impeded performance. Possibly, participants cannot confine attention to a color at a particular location. As a result, distractors that share the target colors disrupt attentional selection of the targets. The attempt to select the targets must then be repeated, which increases the likelihood that the trial terminates when selection is not effective, even for long trials. Consistent with this, here we find a persistent cost of selecting two colors when the conjunction of color and location is needed, but the cost is confined to short exposure durations when the observer just has to monitor red and green stimuli without the need to use the location information. These results suggest that selecting two colors is time-consuming but effective, whereas selection of simultaneous conjunctions is never entirely successful.

The Effects of Storage Conditions on Lycopene Content and Color of Tomato Hot Pot Sauce

Directory of Open Access Journals (Sweden)

He Li

2018-01-01

Full Text Available Tomato hot pot sauce (THPS at different storage temperatures (0, 25, and 37°C and with two kinds of packaging for 120 days was investigated in this study. High performance liquid chromatography was employed for detecting lycopene and 5-hydroxymethylfurfural (HMF. The changes of lycopene and HMF during storage were regressed with kinetic equation of both zero-order and first-order models, and the latter fitted better. The kinetic equation constant (k value of lycopene or HMF at 37°C was higher than that at 25°C. The k value of lycopene of PET/PE (P1 packaged THPS was 1.60 times of that of PET/Al/EAA/PE (P2 packaged at 37°C, while it was 2.12 times at 25°C. The k value of HMF of P1 packaged THPS was 1.69 times of that of P2 packaged at 37°C, while it was 1.01 times at 25°C. Significant correlations between color index of L⁎, a⁎, and a⁎/b⁎ and lycopene or HMF were found at storage temperature. Browning color was attributed to both Maillard reaction and degradation of lycopene. In conclusion, lower storage temperature and stronger oxygen barrier property of package could maintain color stability and extend shelf life.

Nonvolatile two-step, two-color holography with continuous-wave lights for both congruent and near-stoichiometric LiNbO3:Fe

International Nuclear Information System (INIS)

Shen Yan; Zhang Guoquan; Fu Bo; Xu Qingjun; Xu Jingjun

2004-01-01

We have studied theoretically the steady-state nonvolatile two-step, two-color holographic recording performance for both the congruent and the near-stoichiometric LiNbO 3 :Fe based on the two-center model (the deep-trap and the shallow-trap centers are Fe 2+ /Fe 3+ and Nb Li 4+ /Nb Li 5+ , respectively). The results show that the direct electron exchange between the Fe 2+ /Fe 3+ centers and the Nb Li 4+ /Nb Li 5+ centers due to the tunneling effect dominates the charge-transfer process during the nonvolatile two-step, two-color holography and determines the two-step, two-color holography performance in LiNbO 3 :Fe. We have further studied the effects of the crystal stoichiometry on the performance of the two-step, two-color holography. It is shown that, as far as the total space-charge field is considered, the nonvolatile two-step, two-color holography performance in the near-stoichiometric LiNbO 3 :Fe is much better than that in the congruent LiNbO 3 :Fe within the intensity range reachable by the continuous-wave lights

Photofragmentation spectra of halogenated methanes in the VUV photon energy range

Energy Technology Data Exchange (ETDEWEB)

Cartoni, Antonella, E-mail: antonella.cartoni@uniroma1.it [Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza Università di Roma, P.le Aldo Moro 5, Roma 00185 (Italy); Bolognesi, Paola; Fainelli, Ettore; Avaldi, Lorenzo [CNR-IMIP, Area della Ricerca di Roma 1, Monterotondo Scalo (Rm) 00015 (Italy)

2014-05-14

In this paper an investigation of the photofragmentation of dihalomethanes CH{sub 2}X{sub 2} (X = F, Cl, Br, I) and chlorinated methanes (CH{sub n}Cl{sub 4−n} with n = 0–3) with VUV helium, neon, and argon discharge lamps is reported and the role played by the different halogen atoms is discussed. Halogenated methanes are a class of molecules used in several fields of chemistry and the study of their physical and chemical proprieties is of fundamental interest. In particular their photodissociation and photoionization are of great importance since the decomposition of these compounds in the atmosphere strongly affects the environment. The results of the present work show that the halogen-loss is the predominant fragmentation channel for these molecules in the VUV photon energy range and confirm their role as reservoir of chlorine, bromine, and iodine atoms in the atmosphere. Moreover, the results highlight the peculiar feature of CH{sub 2}F{sub 2} as a source of both fluorine and hydrogen atoms and the characteristic formation of I{sub 2}{sup +} and CH{sub 2}{sup +} ions from the photofragmentation of the CH{sub 2}I{sub 2} molecule.

FORMATION OF S-BEARING SPECIES BY VUV/EUV IRRADIATION OF H{sub 2}S-CONTAINING ICE MIXTURES: PHOTON ENERGY AND CARBON SOURCE EFFECTS

Energy Technology Data Exchange (ETDEWEB)

Chen, Y.-J.; Juang, K.-J.; Qiu, J.-M.; Chu, C.-C.; Yih, T.-S. [Department of Physics, National Central University, Jhongli City, Taoyuan County 32054, Taiwan (China); Nuevo, M. [NASA Ames Research Center, Moffett Field, CA 94035 (United States); Jiménez-Escobar, A.; Muñoz Caro, G. M. [Centro de Astrobiología, INTA-CSIC, Torrejón de Ardoz, E-28850 Madrid (Spain); Wu, C.-Y. R. [Space Sciences Center and Department of Physics and Astronomy, University of Southern California, Los Angeles, CA 90089-1341 (United States); Fung, H.-S. [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China); Ip, W.-H. [Graduate Institute of Astronomy, National Central University, Jhongli City, Taoyuan County 32049, Taiwan (China)

2015-01-10

Carbonyl sulfide (OCS) is a key molecule in astrobiology that acts as a catalyst in peptide synthesis by coupling amino acids. Experimental studies suggest that hydrogen sulfide (H{sub 2}S), a precursor of OCS, could be present in astrophysical environments. In the present study, we used a microwave-discharge hydrogen-flow lamp, simulating the interstellar UV field, and a monochromatic synchrotron light beam to irradiate CO:H{sub 2}S and CO{sub 2}:H{sub 2}S ice mixtures at 14 K with vacuum ultraviolet (VUV) or extreme ultraviolet (EUV) photons in order to study the effect of the photon energy and carbon source on the formation mechanisms and production yields of S-containing products (CS{sub 2}, OCS, SO{sub 2}, etc.). Results show that (1) the photo-induced OCS production efficiency in CO:H{sub 2}S ice mixtures is higher than that of CO{sub 2}:H{sub 2}S ice mixtures; (2) a lower concentration of H{sub 2}S enhances the production efficiency of OCS in both ice mixtures; and (3) the formation pathways of CS{sub 2} differ significantly upon VUV and EUV irradiations. Furthermore, CS{sub 2} was produced only after VUV photoprocessing of CO:H{sub 2}S ices, while the VUV-induced production of SO{sub 2} occurred only in CO{sub 2}:H{sub 2}S ice mixtures. More generally, the production yields of OCS, H{sub 2}S{sub 2}, and CS{sub 2} were studied as a function of the irradiation photon energy. Heavy S-bearing compounds were also observed using mass spectrometry during the warm-up of VUV/EUV-irradiated CO:H{sub 2}S ice mixtures. The presence of S-polymers in dust grains may account for the missing sulfur in dense clouds and circumstellar environments.

Effects of a static electric field on two-color photoassociation between different atoms

International Nuclear Information System (INIS)

Chakraborty, Debashree; Deb, Bimalendu

2014-01-01

We study non-perturbative effects of a static electric field on two-color photoassociation of different atoms. A static electric field induces anisotropy in scattering between two different atoms and hybridizes field-free rotational states of heteronuclear dimers or polar molecules. In a previous paper [D. Chakraborty et al., J. Phys. B 44, 095201 (2011)], the effects of a static electric field on one-color photoassociation between different atoms has been described through field-modified ground-state scattering states, neglecting electric field effects on heteronuclear diatomic bound states. To study the effects of a static electric field on heteronuclear bound states, and the resulting influence on Raman-type two-color photoassociation between different atoms in the presence of a static electric field, we develop a non-perturbative numerical method to calculate static electric field-dressed heteronuclear bound states. We show that the static electric field induced scattering anisotropy as well as hybridization of rotational states strongly influence two-color photoassociation spectra, leading to significant enhancement in PA rate and large shift. In particular, for static electric field strengths of a few hundred kV/cm, two-color PA rate involving high-lying bound states in electronic ground-state increases by several orders of magnitude even in the weak photoassociative coupling regime

User oriented end-station on VUV pump-probe magneto-optical ellipsometry at ELI beamlines

Science.gov (United States)

Espinoza, Shirly; Neuber, Gerd; Brooks, Christopher D.; Besner, Bastian; Hashemi, Maryam; Rübhausen, Michael; Andreasson, Jakob

2017-11-01

A state of the art ellipsometer for user operations is being implemented at ELI Beamlines in Prague, Czech Republic. It combines three of the most promising and exotic forms of ellipsometry: VUV, pump-probe and magneto-optical ellipsometry. This new ellipsometer covers a spectral operational range from the NIR up to the VUV, with high through-put between 1 and 40 eV. The ellipsometer also allows measurements of magneto-optical spectra with a 1 kHz switchable magnetic field of up to 1.5 T across the sample combining ellipsometry and Kerr spectroscopy measurements in an unprecedented spectral range. This form of generalized ellipsometry enables users to address diagonal and off-diagonal components of the dielectric tensor within one measurement. Pump-probe measurements enable users to study the dynamic behaviour of the dielectric tensor in order to resolve the time-domain phenomena in the femto to 100 ns range.

Experience with the UHV box coater and the evaporation procedure for VUV reflective coatings on the HADES RICH mirror

CERN Document Server

Maier-Komor, P; Wieser, J; Ulrich, A

1999-01-01

An UHV box coater was set up for the deposition of highly reflective layers in the vacuum ultraviolet (VUV) wavelength range on large-area mirror substrates. The VUV mirrors are needed for the ring imaging Cherenkov (RICH) detector of the high-acceptance di-electron spectrometer (HADES). The complete dry vacuum system is described. The spatial deposition distribution from the evaporation sources was measured. The reflectivity of the Al mirror layer was optimized for the wavelength range of 145-210 nm by varying the thickness of the MgF sub 2 protective layer. The setup for measuring the reflectivity in the VUV range is described and reflectivity data are presented.

DISCOVERING THE MISSING 2.2 < z < 3 QUASARS BY COMBINING OPTICAL VARIABILITY AND OPTICAL/NEAR-INFRARED COLORS

International Nuclear Information System (INIS)

Wu Xuebing; Wang Ran; Bian Fuyan; Jiang Linhua; Fan Xiaohui; Schmidt, Kasper B.

2011-01-01

The identification of quasars in the redshift range 2.2 < z < 3 is known to be very inefficient because the optical colors of such quasars are indistinguishable from those of stars. Recent studies have proposed using optical variability or near-infrared (near-IR) colors to improve the identification of the missing quasars in this redshift range. Here we present a case study combining both methods. We select a sample of 70 quasar candidates from variables in Sloan Digital Sky Survey (SDSS) Stripe 82, which are non-ultraviolet excess sources and have UKIDSS near-IR public data. They are clearly separated into two parts on the Y - K/g - z color-color diagram, and 59 of them meet or lie close to a newly proposed Y - K/g - z selection criterion for z < 4 quasars. Of these 59 sources, 44 were previously identified as quasars in SDSS DR7, and 35 of them are quasars at 2.2 < z < 3. We present spectroscopic observations of 14 of 15 remaining quasar candidates using the Bok 2.3 m telescope and the MMT 6.5 m telescope, and successfully identify all of them as new quasars at z = 2.36-2.88. We also apply this method to a sample of 643 variable quasar candidates with SDSS-UKIDSS nine-band photometric data selected from 1875 new quasar candidates in SDSS Stripe 82 given by Butler and Bloom based on the time-series selections, and find that 188 of them are probably new quasars with photometric redshifts at 2.2 < z < 3. Our results indicate that the combination of optical variability and optical/near-IR colors is probably the most efficient way to find 2.2 < z < 3 quasars and is very helpful for constructing a complete quasar sample. We discuss its implications for ongoing and upcoming large optical and near-IR sky surveys.

PE-3 - a high class pipeline; PE-3 - um oleoduto high-class

Energy Technology Data Exchange (ETDEWEB)

Hashiguchi, D Issao; Santos, J.A. Costa; Medeiros, A Roberto [GDK Engenharia, Salvador, BA (Brazil); Garcia, Amaury [TRANSPETRO - PETROBRAS Transportes, Rio de Janeiro, RJ (Brazil); Santos, F Cesar [Superpesa Transportes Especiais e Intermodais, Rio de Janeiro, RJ (Brazil)

2003-07-01

Pipeline PE-3, with a length of approximately 17 Km mainly inside of Guanabara Bay, connects the refinery of Duque de Caxias to the terminal of the Ilha D'Agua. It is used to export dark products from the refinery. Product transfer, by operational necessity, is conducted at a temperature of 75 deg C. This introduces a considerable load of tension on the pipeline, in addition to creating a fatigue-inducing thermal cycle. Because of this, and unlike almost all other existing oil and gas pipelines, PE-3 posses a zig zag configuration, alternating a straight tube with a curve of 10 degrees. This stands out as an innovative concept. Their are only two other similar installations in the world, but in very different conditions, thus conferring a pioneering aspect on this pipeline. Due to its criticality, the pipeline is predicated on complete certification in its entirety, from design to operation and in adherence with the strictest requirements. The environmental conditions encountered along its right of way, and the constructive tolerances imposed by the project, obligate the adoption of constructive and technical solutions that are themselves innovative in the terrestrial and marine realms. The principal objective of this work is to present a general overview of the methodology employed in PE-3 construction, installation and assembly. (author)

PE-3 - a high class pipeline; PE-3 - um oleoduto high-class

Energy Technology Data Exchange (ETDEWEB)

Hashiguchi, D. Issao; Santos, J.A. Costa; Medeiros, A. Roberto [GDK Engenharia, Salvador, BA (Brazil); Garcia, Amaury [TRANSPETRO - PETROBRAS Transportes, Rio de Janeiro, RJ (Brazil); Santos, F. Cesar [Superpesa Transportes Especiais e Intermodais, Rio de Janeiro, RJ (Brazil)

2003-07-01

Pipeline PE-3, with a length of approximately 17 Km mainly inside of Guanabara Bay, connects the refinery of Duque de Caxias to the terminal of the Ilha D'Agua. It is used to export dark products from the refinery. Product transfer, by operational necessity, is conducted at a temperature of 75 deg C. This introduces a considerable load of tension on the pipeline, in addition to creating a fatigue-inducing thermal cycle. Because of this, and unlike almost all other existing oil and gas pipelines, PE-3 posses a zig zag configuration, alternating a straight tube with a curve of 10 degrees. This stands out as an innovative concept. Their are only two other similar installations in the world, but in very different conditions, thus conferring a pioneering aspect on this pipeline. Due to its criticality, the pipeline is predicated on complete certification in its entirety, from design to operation and in adherence with the strictest requirements. The environmental conditions encountered along its right of way, and the constructive tolerances imposed by the project, obligate the adoption of constructive and technical solutions that are themselves innovative in the terrestrial and marine realms. The principal objective of this work is to present a general overview of the methodology employed in PE-3 construction, installation and assembly. (author)

Effects of 108 Days Tritium Exposure on UHMW-PE, PTFE, and Vespel(R)

International Nuclear Information System (INIS)

Clark, E.A.

2003-01-01

Samples of three polymers, Ultra-High Molecular Weight Polyethylene (UHMW-PE), polytetrafluoroethylene (PTFE), also known as Teflon(R), and Vespel(R) polyimide were exposed to 1 atmosphere of tritium gas at ambient temperature for 108 days. Sample mass and size measurements to calculate density, spectra-colorimetry, dynamic mechanical analysis (DMA), and Fourier-transform infrared spectroscopy (FT-IR) were employed to characterize the effects of this exposure on these samples. This technical report is the first report from this research program

Preliminary study on radiation crosslinking of PE-NBR multiple phase system

International Nuclear Information System (INIS)

Wang Hong; Zhang Wanxi; Sun Jiazhen

1989-01-01

The effect of radiation crosslinking on the structure and properties of PE-NBR (polyethylene-acrylonitrile-butadiene rubber) multiple phase system was studied in this paper. The relationship of sol fraction and irradiated dose to multiplephase system was demonstrated

Scene recognition and colorization for vehicle infrared images

Science.gov (United States)

Hou, Junjie; Sun, Shaoyuan; Shen, Zhenyi; Huang, Zhen; Zhao, Haitao

2016-10-01

In order to make better use of infrared technology for driving assistance system, a scene recognition and colorization method is proposed in this paper. Various objects in a queried infrared image are detected and labelled with proper categories by a combination of SIFT-Flow and MRF model. The queried image is then colorized by assigning corresponding colors according to the categories of the objects appeared. The results show that the strategy here emphasizes important information of the IR images for human vision and could be used to broaden the application of IR images for vehicle driving.

Tunneling ionization and harmonic generation in two-color fields

International Nuclear Information System (INIS)

Kondo, K.; Kobayashi, Y.; Sagisaka, A.; Nabekawa, Y.; Watanabe, S.

1996-01-01

Tunneling ionization and harmonic generation in two-color fields were studied with a fundamental beam (ω) and its harmonics (2ω,3ω), which were generated by a 100-fs Ti:sapphire laser. Ion yields of atoms and molecules were successfully controlled by means of a change in the relative phase between ω and 3ω pulses. Two-color interference was clearly observed in photoelectron spectra and harmonic spectra. In the ω endash 2ω field even-order harmonics were observed in which the intensity was almost equal to that of the odd harmonics because of an asymmetric optical field. These results were compared with the quasi-static model for ionization and with the quantum theory for harmonic generation. copyright 1996 Optical Society of America

Emprovador virtual : Aplicació per a canviar els colors de la roba en imatges

OpenAIRE

Estrada i Fite, Santi

2015-01-01

Aquest projecte utilitza una de les tasques més comunes en el processament d'imatges, l'alteració de color, per a crear una aplicació que permeti modificar el color de qualsevol peça de roba en una imatge, mantenint-ne les seves propietats d'il·luminació i textura originals. Per a aconseguir-ho ens servirem de l'entorn OpenCV, el qual fa possible el tractament d'imatges en temps real. L'usuari serà capaç de seleccionar qualsevol element de la imatge, podent tractar-se tant d'una peça de roba ...

Are there different requirements for trace elements in eumelanin- and pheomelanin-based color production? A case study of two passerine species.

Science.gov (United States)

Zduniak, Piotr; Surmacki, Adrian; Erciyas-Yavuz, Kiraz; Chudzińska, Maria; Barałkiewicz, Danuta

2014-09-01

Melanin is the most common pigment in animal integuments including bird plumage. It has been shown that several trace elements may play roles in the production and signaling function of melanin-colored plumage. We investigated coloration and content of various metal elements in the rectrices of two insectivorous passerines, Common Redstarts (Phoenicurus phoenicurus) and Blackcaps (Sylvia atricapilla), which have eumelanin- and pheomelanin-based coloration, respectively. We hypothesized that 1) the two species would differ in concentrations of metals important in melanin synthesis (Ca, Fe, Cu, Zn), 2) differences in metal concentration levels would be related to feather coloration. Our study confirmed the first prediction and provides the first evidence that selected elements may play a greater role in pheomelanin than in eumelanin synthesis. Concentrations of three elements considered as important in melanin synthesis (Ca, Fe, Zn) were 52% to 93% higher in rusty colored Common Redstart feathers compared to the dark gray Blackcap feathers. However, element concentrations were not correlated with feather coloration or sex in either species. Our study suggests that, of the two melanin forms, pheomelanin synthesis may bear higher costs associated with the acquisition of specific elements or limited elements may create trade-offs between ornamentation and other physiological functions. Our findings warrant further investigations designed to better understand the roles of macro- and microelements in the synthesis of both forms of melanin. Copyright © 2014 Elsevier Inc. All rights reserved.

Extended analysis of benchmark datasets for Agilent two-color microarrays

Directory of Open Access Journals (Sweden)

Kerr Kathleen F

2007-10-01

Full Text Available Abstract Background As part of its broad and ambitious mission, the MicroArray Quality Control (MAQC project reported the results of experiments using External RNA Controls (ERCs on five microarray platforms. For most platforms, several different methods of data processing were considered. However, there was no similar consideration of different methods for processing the data from the Agilent two-color platform. While this omission is understandable given the scale of the project, it can create the false impression that there is consensus about the best way to process Agilent two-color data. It is also important to consider whether ERCs are representative of all the probes on a microarray. Results A comparison of different methods of processing Agilent two-color data shows substantial differences among methods for low-intensity genes. The sensitivity and specificity for detecting differentially expressed genes varies substantially for different methods. Analysis also reveals that the ERCs in the MAQC data only span the upper half of the intensity range, and therefore cannot be representative of all genes on the microarray. Conclusion Although ERCs demonstrate good agreement between observed and expected log-ratios on the Agilent two-color platform, such an analysis is incomplete. Simple loess normalization outperformed data processing with Agilent's Feature Extraction software for accurate identification of differentially expressed genes. Results from studies using ERCs should not be over-generalized when ERCs are not representative of all probes on a microarray.

Hydrocarbons in interstellar ice analogues : UV-vis spectroscopy and VUV photochemistry

NARCIS (Netherlands)

Cuylle, Steven Hendrik

2015-01-01

This thesis treats the chemical behaviour of carbonaceous molecules in water-dominated interstellar ices. VUV photons are considered as the chemical trigger to induce solid state chemistry as it is omnipresent. Lyman- radiation occurs even in dense molecular clouds as a result of cosmic ray

Spinor Slow Light and Two-Color Qubits

Science.gov (United States)

Yu, Ite; Lee, Meng-Jung; Ruseckas, Julius; Lee, Chin-Yuan; Kudriasov, Viaceslav; Chang, Kao-Fang; Cho, Hung-Wen; Juzeliunas, Gediminas; Yu, Ite A.

2015-05-01

We report the first experimental demonstration of two-component or spinor slow light (SSL) using a double tripod (DT) atom-light coupling scheme. The scheme involves three atomic ground states coupled to two excited states by six light fields. The oscillation due to the interaction between the two components was observed. SSL can be used to achieve high conversion efficiencies in the sum frequency generation and is a better method than the widely-used double- Λ scheme. On the basis of the stored light, our data showed that the DT scheme behaves like the two outcomes of an interferometer enabling precision measurements of frequency detuning. Furthermore, the single-photon SSL can be considered as the qubit with the superposition state of two frequency modes or, simply, as the two-color qubit. We experimentally demonstrated a possible application of the DT scheme as quantum memory/rotator for the two-color qubit. This work opens up a new direction in the EIT/slow light research. yu@phys.nthu.edu.tw

Color variability and body size of larvae of two Epomis species (Coleoptera: Carabidae in Israel

Directory of Open Access Journals (Sweden)

Gil Wizen

2011-07-01

Full Text Available Species identification using the characteristics of developmental stages is challenging. However, for insect taxonomy the coloration of larval stages can be an informative feature. The use of live specimens is recommended for this because the color fades in preserved specimens. In this study we examine the possibility of using variation in coloration and color pattern of larvae in order to distinguish between two ground beetles species Epomis dejeani Dejean, 1831 and E. circumscriptus Duftschmid, 1812. We present an atlas and describe the coloration and body size of the three larval stages of the above species based on live specimens. The first instar larvae of the two Epomis species can be easily distinguished based on their color. From the second instar on, the variability in coloration and color patterns increases, creating an overlap in these attributes between larvae of the two species. Except for minor differences in color of the antennae and the base of the mandibles, larvae of the two species are indistinguishable at the second and third larval stages. To the best of our knowledge this is the first attempt to use variation in coloration and color pattern in live larvae in order to identify coleopterans. The color atlas of the larvae enables simple separation of the two Epomis species without requiring sophisticated magnifying devices, although it is less straightforward at the second and third larval stages. We found similar body lengths between the two species for all developmental stages, except for third instar larvae prior to pupation. In the two species the difference in larval body length before pupation positively correlated with that of the adult beetles. More than 70% of the adults' length can be explained by the length of the late third-instar larva; i.e. the large larvae develop into large adults. The larger specimens are the females.

Valor preditivo dos escores de SNAP e SNAP-PE na mortalidade neonatal Predictive value of SNAP and SNAP-PE for neonatal mortality

Directory of Open Access Journals (Sweden)

Rita C. Silveira

2001-12-01

results. METHODS: All newborn infants admitted to our neonatal intensive care unit from March 1997 through December 1998 were prospectively evaluated just at completion of 24 hours of life for SNAP and SNAP-PE. Exclusion criteria were: death or discharge from the neonatal intensive care unit in the first 24 hours of life, congenital malformations incompatible with life, and outborn infants. RESULTS: 553 newborn infants were included in the study and 54 died. The median SNAP and SNAP-PE values were higher in those who died. Infants were allocated to five different raising ranges of SNAP and SNAP-PE severity. SNAP: up to 6, 7-11, 12-15, 16-24, higher than 24 (mortality: 3%, 11%, 29%, 48%,75%, respectively. SNAP-PE: up to 11, 12-23, 24-32, 33-50, higher than 50 (mortality: 3%, 10%, 53%, 78%, 83%, respectively. The optimal cut off points based on ROC curve were 12 for SNAP, and 24 for SNAP-PE. Sensitivity, specificity, positive predictive value (PPV, and negative predictive value (NPV for death were figured out. SNAP 12: sensitivity 79.6%, specificity 71.7%, PPV 23.4%, NPV 97%. SNAP-PE 24: sensitivity 79.6%, specificity 80%, PPV 30%, NPV 97.3%. The area under the curve (Az were 81.4% for SNAP, and 85.1% for SNAP-PE, both statistically significant. There were no statistical differences between the two areas under the curve. CONCLUSIONS: SNAP and SNAP-PE are excellent predictors of neonatal survival. Therefore, we recommend their use in Neonatal Intensive Care Units.

Discrimination of Chinese Sauce liquor using FT-IR and two-dimensional correlation IR spectroscopy

Science.gov (United States)

Sun, Su-Qin; Li, Chang-Wen; Wei, Ji-Ping; Zhou, Qun; Noda, Isao

2006-11-01

We applied the three-step IR macro-fingerprint identification method to obtain the IR characteristic fingerprints of so-called Chinese Sauce liquor (Moutai liquor and Kinsly liquor) and a counterfeit Moutai. These fingerprints can be used for the identification and discrimination of similar liquor products. The comparison of their conventional IR spectra, as the first step of identification, shows that the primary difference in Sauce liquor is the intensity of characteristic peaks at 1592 and 1225 cm -1. The comparison of the second derivative IR spectra, as the second step of identification, shows that the characteristic absorption in 1400-1800 cm -1 is substantially different. The comparison of 2D-IR correlation spectra, as the third and final step of identification, can discriminate the liquors from another direction. Furthermore, the method was successfully applied to the discrimination of a counterfeit Moutai from the genuine Sauce liquor. The success of the three-step IR macro-fingerprint identification to provide a rapid and effective method for the identification of Chinese liquor suggests the potential extension of this technique to the identification and discrimination of other wine and spirits, as well.

Color-Blindness Study: Color Discrimination on the TICCIT System.

Science.gov (United States)

Asay, Calvin S.; Schneider, Edward W.

The question studied whether the specific seven TICCIT system colors used within color coding schemes can be a source of confusion, or not seen at all, by the color-blind segment of target populations. Subjects were 11 color-blind and three normally sighted students at Brigham Young University. After a preliminary training exercise to acquaint the…

VUV Pump and Probe of Phase Separation and Oxygen Interstitials in La2NiO4+y Using Spectromicroscopy

Directory of Open Access Journals (Sweden)

Antonio Bianconi

2018-02-01

Full Text Available While it is known that strongly correlated transition metal oxides described by a multi-band Hubbard model show microscopic multiscale phase separation, little is known about the possibility to manipulate them with vacuum ultraviolet (VUV, 27 eV lighting. We have investigated the photo-induced effects of VUV light illumination of a super-oxygenated La2NiO4+y single crystal by means of scanning photoelectron microscopy. VUV light exposure induces the increase of the density of states (DOS in the binding energy range around Eb = 1.4 eV below EF. The photo-induced states in this energy region have been predicted due to clustering of oxygen interstitials by band structure calculations for large supercell of La2CuO4.125. We finally show that it is possible to generate and manipulate oxygen rich domains by VUV illumination as it was reported for X-ray illumination of La2CuO4+y. This phenomenology is assigned to oxygen-interstitials ordering and clustering by photo-illumination forming segregated domains in the La2NiO4+y surface.

52-COLOR ASTEROID SURVEY

Data.gov (United States)

National Aeronautics and Space Administration — This data set contains 52-color IR data of asteroids, taken using a double circularly variable filter. The short wavelength portion of the CVF covered the octave...

Effect of the coherent cancellation of the two-photon resonance on the generation of vacuum ultraviolet light by two-photon reasonantly enhanced four-wave mixing

International Nuclear Information System (INIS)

Payne, M.G.; Garrett, W.R.; Judish, J.P.; Wunderlich, R.

1988-11-01

Many of the most impressive demonstrations of the efficient generation of vacuum ultraviolet (VUV) light have made use of two- photon resonantly enhanced four-wave mixing to generate light at ω/sub VUV/ = 2ω/sub L1/ +- ω/sub L2/. The two-photon resonance state is coupled to the ground state both by two photons from the first laser, or by a photon from the second laser and one from the generated VUV beam. We show here that these two coherent pathways destructively interfere once the second laser is made sufficiently intense, thereby leading to an important limiting effect on the achievable conversion efficiency. 4 refs

Ultrawide spectral broadening and compression of single extremely short pulses in the visible, uv-vuv, and middle infrared by high-order stimulated Raman scattering

International Nuclear Information System (INIS)

Kalosha, V. P.; Herrmann, J.

2003-01-01

We present the results of a comprehensive analytical and numerical study of ultrawide spectral broadening and compression of isolated extremely short visible, uv-vuv and middle infrared (MIR) pulses by high-order stimulated Raman scattering in hollow waveguides. Spectral and temporal characteristics of the output pulses and the mechanism of pulse compression using dispersion of the gas filling and output glass window are investigated without the slowly varying envelope approximation. Physical limitations due to phase mismatch, velocity walk off, and pump-pulse depletion as well as improvements through the use of pump-pulse sequences and dispersion control are studied. It is shown that phase-locked pulses as short as ∼2 fs in the visible and uv-vuv, and 6.5 fs in the MIR can be generated by coherent scattering in impulsively excited Raman media without the necessity of external phase control. Using pump-pulse sequences, shortest durations in the range of about 1 fs for visible and uv-vuv probe pulses are predicted

Study on two-color planar laser induced fluorescence thermometry

International Nuclear Information System (INIS)

Li Shaodan; Tan Sichao; Gao Puzhen; Lin Yuansheng

2014-01-01

Many of the convection heat transfer process are involved in the research of nuclear reactor thermal hydraulics. To experimentally determine the variation of the temperature field in those processes is important for the design and safety operation of the nuclear reactor. The application of the two-color planar laser induced fluorescence (PLIF) in the measurements of fluid temperature distribution is discussed in the paper. The laser dyes used here is rhodamine B (RhB) with negative temperature coefficient and fluorescein 27 (F127) with positive temperature coefficient. The beam of the laser light is adjusted to laser sheet by using the lens group. The fluid with dyes is excited by this laser sheet in a specific plane and temperature dependent fluorescence is released. The temperature field of the plane can be determined through the intensity information. Some technical aspects encountered in the application of the two-laser PLIF are discussed in the paper, such as the spectra characteristic of the dyes and the separation of the spectra. The calibration temperature is higher than the water saturation temperature (at atmosphere pressure). (authors)

Development and perspectives of PE for gas networks in Italy

International Nuclear Information System (INIS)

Bergamino, R.; Cammelli, W.; Torre, C.

1999-01-01

After comparing the result of two large surveys carried out in 1998 and 1992 on the utilization of PE pipes for gas distribution, the features of PE pipe, which allow the adoption of innovative techniques such as 'rapid trenching' for the laying of new pipelines and 'NO-DIG' for the relining of old on, are described. The technical, operational and economical fea-activities developed in this field by AMGA SpA Genoa. Besides, the time behaviour of PE pipes welding is evaluated on the basis of values taken from AMGA's database [it

An analytic approach to 2D electronic PE spectra of molecular systems

International Nuclear Information System (INIS)

Szoecs, V.

2011-01-01

Graphical abstract: The three-pulse photon echo (3P-PE) spectra of finite molecular systems using direct calculation from electronic Hamiltonians allows peak classification from 3P-PE spectra dynamics. Display Omitted Highlights: → RWA approach to electronic photon echo. → A straightforward calculation of 2D electronic spectrograms in finite molecular systems. → Importance of population time dynamics in relation to inter-site coherent coupling. - Abstract: The three-pulse photon echo (3P-PE) spectra of finite molecular systems and simplified line broadening models is presented. The Fourier picture of a heterodyne detected three-pulse rephasing PE signal in the δ-pulse limit of the external field is derived in analytic form. The method includes contributions of one and two-excitonic states and allows direct calculation of Fourier PE spectrogram from corresponding Hamiltonian. As an illustration, the proposed treatment is applied to simple systems, e.g. 2-site two-level system (TLS) and n-site TLS model of photosynthetic unit. The importance of relation between Fourier picture of 3P-PE dynamics (corresponding to nonzero population time, T) and coherent inter-state coupling is emphasized.

An Eye-Tracking Study of How Color Coding Affects Multimedia Learning

Science.gov (United States)

Ozcelik, Erol; Karakus, Turkan; Kursun, Engin; Cagiltay, Kursat

2009-01-01

Color coding has been proposed to promote more effective learning. However, insufficient evidence currently exists to show how color coding leads to better learning. The goal of this study was to investigate the underlying cause of the color coding effect by utilizing eye movement data. Fifty-two participants studied either a color-coded or…

Supplementary Material for: Recombination in pe/ppe genes contributes to genetic variation in Mycobacterium tuberculosis lineages

KAUST Repository

Phelan, Jody

2016-01-01

Abstract Background Approximately 10 % of the Mycobacterium tuberculosis genome is made up of two families of genes that are poorly characterized due to their high GC content and highly repetitive nature. The PE and PPE families are typified by their highly conserved N-terminal domains that incorporate proline-glutamate (PE) and proline-proline-glutamate (PPE) signature motifs. They are hypothesised to be important virulence factors involved with host-pathogen interactions, but their high genetic variability and complexity of analysis means they are typically disregarded in genome studies. Results To elucidate the structure of these genes, 518 genomes from a diverse international collection of clinical isolates were de novo assembled. A further 21 reference M. tuberculosis complex genomes and long read sequence data were used to validate the approach. SNP analysis revealed that variation in the majority of the 168 pe/ppe genes studied was consistent with lineage. Several recombination hotspots were identified, notably pe_pgrs3 and pe_pgrs17. Evidence of positive selection was revealed in 65 pe/ppe genes, including epitopes potentially binding to major histocompatibility complex molecules. Conclusions This, the first comprehensive study of the pe and ppe genes, provides important insight into M. tuberculosis diversity and has significant implications for vaccine development.

Comparison of different undulator schemes with superimposed alternating gradients for the VUV-FEL at the TESLA Test Facility

Energy Technology Data Exchange (ETDEWEB)

Pflueger, J.; Nikitina, Y.M. [DESY/HASYLAB, Hamburg (Germany)

1995-12-31

For the VUV-FEL at the TESLA Test Facility an undulator with a total length of 30 m is needed. In this study three different approaches to realize an undulator with a sinusoidal plus a superimposed quadrupolar field were studied with the 3D code MAFIA.

INFRARED TWO-COLOR DIAGRAMS FOR AGB STARS, POST-AGB STARS, AND PLANETARY NEBULAE

Energy Technology Data Exchange (ETDEWEB)

Suh, Kyung-Won, E-mail: kwsuh@chungbuk.ac.kr [Department of Astronomy and Space Science, Chungbuk National University, Cheongju-City, 362-763 (Korea, Republic of)

2015-08-01

We present various infrared two-color diagrams (2CDs) for asymptotic giant branch (AGB) stars, post-AGB stars, and Planetary Nebulae (PNe) and investigate possible evolutionary tracks. We use catalogs from the available literature for the sample of 4903 AGB stars (3373 O-rich; 1168 C-rich; 362 S-type), 660 post-AGB stars (326 post-AGB; 334 pre-PN), and 1510 PNe in our Galaxy. For each object in the catalog, we cross-identify the IRAS, AKARI, Midcourse Space Experiment, and 2MASS counterparts. The IR 2CDs can provide useful information about the structure and evolution of the dust envelopes as well as the central stars. To find possible evolutionary tracks from AGB stars to PNe on the 2CDs, we investigate spectral evolution of post-AGB stars by making simple but reasonable assumptions on the evolution of the central star and dust shell. We perform radiative transfer model calculations for the detached dust shells around evolving central stars in the post-AGB phase. We find that the theoretical dust shell model tracks using dust opacity functions of amorphous silicate and amorphous carbon roughly coincide with the densely populated observed points of AGB stars, post-AGB stars, and PNe on various IR 2CDs. Even though some discrepancies are inevitable, the end points of the theoretical post-AGB model tracks generally converge in the region of the observed points of PNe on most 2CDs.

Two-out-of-two color matching based visual cryptography schemes.

Science.gov (United States)

Machizaud, Jacques; Fournel, Thierry

2012-09-24

Visual cryptography which consists in sharing a secret message between transparencies has been extended to color prints. In this paper, we propose a new visual cryptography scheme based on color matching. The stacked printed media reveal a uniformly colored message decoded by the human visual system. In contrast with the previous color visual cryptography schemes, the proposed one enables to share images without pixel expansion and to detect a forgery as the color of the message is kept secret. In order to correctly print the colors on the media and to increase the security of the scheme, we use spectral models developed for color reproduction describing printed colors from an optical point of view.

Beam line design for synchrotron spectroscopy in the VUV

Energy Technology Data Exchange (ETDEWEB)

Howells, M R

1980-01-01

The character of the radiation source provided by an electron storage ring is briefly reviewed from the point of view of utilization for VUV spectroscopy. The design of beam line components is then considered with special reference to the problems of contamination of optical surfaces and vacuum protection. The issues involved in designing mirrors for use with storage rings are considered with emphasis on the questions of power dissipation, image quality and materials selection.

Beam line design for synchrotron spectroscopy in the VUV

International Nuclear Information System (INIS)

Howells, M.R.

1980-01-01

The character of the radiation source provided by an electron storage ring is briefly reviewed from the point of view of utilization for VUV spectroscopy. The design of beam line components is then considered with special reference to the problems of contamination of optical surfaces and vacuum protection. The issues involved in designing mirrors for use with storage rings are considered with emphasis on the questions of power dissipation, image quality and materials selection

Photocatalytic oxidation of indoor toluene: Process risk analysis and influence of relative humidity, photocatalysts, and VUV irradiation

International Nuclear Information System (INIS)

Zhao, Weirong; Dai, Jiusong; Liu, Feifei; Bao, Jiaze; Wang, Yan; Yang, Yong; Yang, Yanan; Zhao, Dongye

2012-01-01

Concentrations of 13 gaseous intermediates in photocatalytic oxidation (PCO) of toluene in indoor air were determined in real-time by proton transfer reaction mass spectrometry and desorption intensities of 7 adsorbed intermediates on the surface of photocatalysts were detected by temperature‐programmed desorption‐mass spectrometry. Effects of relative humidity (RH), photocatalysts, and vacuum ultraviolet (VUV) irradiation on the distribution and category of the intermediates and health risk influence index (η) were investigated. RH enhances the formation rate of hydroxide radicals, leading to more intermediates with higher oxidation states in gas phase. N doping promotes the separation of photo-generated electrons and holes and enhances PCO activity accordingly. VUV irradiation results in higher mineralization rate and more intermediates with higher oxidation states and lower toxicity e.g. carboxylic acids. Health risk analysis indicates that higher RH, N doping of TiO 2 , and VUV lead to “greener” intermediates and smaller η. Finally, a conceptual diagram was proposed to exhibit the scenario of η varied with extent of mineralization for various toxicities of inlet pollutants. Highlights: ► 13 volatile intermediates in PCO of toluene were determined in real-time by PTR-MS. ► 7 adsorbed intermediates on surface of photocatalyst were determined by TPD-MS. ► Higher RH, N doping of TiO 2 , and VUV irradiation lead to “greener” intermediates. ► Health risk index relies on extent of mineralization and toxicities of inlet VOCs.

Occupational Socialization of Sport Pedagogy Faculty: Two German Case Studies

Science.gov (United States)

Merrem, Anne M.; Curtner-Smith, Matthew D.

2018-01-01

Purpose: The purpose of this study was to describe the influence of occupational socialization on the perspectives and practices of two female German sport pedagogy faculty members, Heidi and Lisa, regarding physical education (PE) and PE teacher education (PETE). Method: The main data sources were six formal interviews. Supplementary data were…

Color Stability Assessment of Two Different Composite Resins with Variable Immersion Time Using Various Beverages: An In vitro Study.

Science.gov (United States)

Kumar, M Senthil; Ajay, R; Miskeen Sahib, S A; Chittrarasu, M; Navarasu, M; Ragavendran, N; Burhanuddin Mohammed, Omar Farooq

2017-11-01

The aim of the study was to evaluate the difference in the color of microhybrid (MH) and nanofilled (NF) composite resins after 24 and 48 h in beverages such as red wine (RW), Coca-Cola, and distilled water. The specific objective of this study was to investigate the cumulative effect of the colorant solutions on the dental composites. MH and NF composite resins (A2 shade) were used in this current study. Sixty disk-shaped material specimens (10 mm in diameter × 2 mm in thickness) were prepared using a fiber mold (ring), with the desired dimensions. The specimen surfaces were polished using super-snap polishing system. Sixty specimens were divided into two groups of 30 each (Group I: MH resin composite; Group II: NF resin composite). Both the groups divided into six subgroups (Subgroup I: RW for 24 h [RW-24]; Subgroup II: RW for 48 h; Subgroup III: Coca-Cola for 24 h [CC-24]; Subgroup IV: Coca-Cola for 48 h [CC-48]; Subgroup V: Distilled water for 24 h [DW-24]; Subgroup VI: Distilled water for 48 h [DW-48]). All the samples were immersed in respective drinks for a period of 24 h, and color differences were measured using ultraviolet spectrophotometer. Once again, all the samples were immersed for another 24 h in the same drinks. After 48 h, the color change of the samples was measured. Measurements were made according to the CIE L × a × b × color space relative to the CIE standard illuminant D65. The color changes of the specimens were evaluated using the following formula: Statistical analysis was performed. The data were analyzed using the one-way ANOVA and t -test at a significance level of 0.05. Color stability of MH composite resin was found to be inferior than the NF resin composite irrespective of immersion medium and time. In RW, the color change observed was maximum for both composite resins followed by Coca-Cola. Immersing the resin composites in distilled water for 24 and 48 h had negligible color change. A 48-h immersion of both composite resins in

Luminescent properties of (Y,Gd)BO3:Bi3+,RE3+ (RE=Eu, Tb) phosphor under VUV/UV excitation

International Nuclear Information System (INIS)

Zeng Xiaoqing; Im, Seoung-Jae; Jang, Sang-Hun; Kim, Young-Mo; Park, Hyoung-Bin; Son, Seung-Hyun; Hatanaka, Hidekazu; Kim, Gi-Young; Kim, Seul-Gi

2006-01-01

Bi 3+ - and RE 3+ -co-doped (Y,Gd)BO 3 phosphors were prepared and their luminescent properties under vacuum ultraviolet (VUV)/UV excitation were investigated. Strong red emission for (Y,Gd)BO 3 :Bi 3+ ,Eu 3+ and strong green emission for (Y,Gd)BO 3 :Bi 3+ ,Tb 3+ are observed under VUV excitation from 147 to 200 nm with a much broader excitation region than that of single Eu 3+ -doped or Tb 3+ -doped (Y,Gd)BO 3 phosphor. Strong emissions are also observed under UV excitation around 265 nm where as nearly no luminescence is observed for single Eu 3+ -doped or Tb 3+ -doped (Y,Gd)BO 3 . The luminescence enhancement of Bi 3+ - and RE 3+ -co-doped (Y,Gd)BO 3 phosphors is due to energy transfer from Bi 3+ ion to Eu 3+ or Tb 3+ ion not only in the VUV region but also in the UV region. Besides, host sensitization competition between Bi 3+ and Eu 3+ or Tb 3+ is also observed. The investigated phosphors may be preferable for devices with a VUV light 147-200 nm as an excitation source such as PDP or mercury-free fluorescent lamp

Preliminary experiments to estimate the PE.MA.M (PElagic MArine Mesocosm) offshore behaviour

Science.gov (United States)

Albani, Marta; Piermattei, Viviana; Stefanì, Chiara; Marcelli, Marco

2016-04-01

The phytoplankton community is controlled not only by local environmental conditions but also by physical processes occurring on different temporal and spatial scales. Hydrodynamic local conditions play an important role in marine ecosystems. Several studies have shown that hydrodynamic conditions can influence the phytoplankton settling velocity, vertical and horizontal distribution and formation of cyanobacterial blooms. Mesocosms are useful structures to simulate marine environment at mesoscale resolution; allowing to closely approximate biotic or abiotic parameters of interest directly in nature. In this work an innovative structure named PE.MA.M (PElagic MArine Mesocosm) is presented and tested. Laboratory experiments have been conducted in order to observe seasonal variations of biomass behaviour in two different hydrodynamic conditions: outside as well as whithin the PE.MA.M. We have evaluated whether it is possible to isolate a natural system from external water mass hydrodynamic exchanges and to assume that phytoplankton cells' transition is limited at the net and sea interface. Preliminary experiments test the isolating capacity of the net, to determine the currents' attenuation rate and to estimate the possible PE.MA.M. offshore behaviour. In the first investigation, we monitored the diffusion of phytoplankton cells. The PE.MA.M. exterior and interior were simulated using a plexiglass tank divided into two half-tanks (Aout-Bin) by a septum consisting of a net like a PE.MA.M. The tank was filled up with 10 L of water and only the half-tank Aout was filled up with 10 ml of phytoplankton culture (Clorella sp.). We monitored the chlorophyll concentrations for 24 hours. The two tanks had similar concentrations after 4 hours (2.70322 mg/m³ Aout and 2.37245 mg/m3 Bin) and this constant relationship was maintened until the end of the test. In the second investigation we used clod cards to measure water motions.We conducted two experiments within tank, the first

Temporal enhancement of two-dimensional color doppler echocardiography

Science.gov (United States)

Terentjev, Alexey B.; Settlemier, Scott H.; Perrin, Douglas P.; del Nido, Pedro J.; Shturts, Igor V.; Vasilyev, Nikolay V.

2016-03-01

Two-dimensional color Doppler echocardiography is widely used for assessing blood flow inside the heart and blood vessels. Currently, frame acquisition time for this method varies from tens to hundreds of milliseconds, depending on Doppler sector parameters. This leads to low frame rates of resulting video sequences equal to tens of Hz, which is insufficient for some diagnostic purposes, especially in pediatrics. In this paper, we present a new approach for reconstruction of 2D color Doppler cardiac images, which results in the frame rate being increased to hundreds of Hz. This approach relies on a modified method of frame reordering originally applied to real-time 3D echocardiography. There are no previous publications describing application of this method to 2D Color Doppler data. The approach has been tested on several in-vivo cardiac 2D color Doppler datasets with approximate duration of 30 sec and native frame rate of 15 Hz. The resulting image sequences had equivalent frame rates to 500Hz.

Development of two color laser diagnostics for the ITER poloidal polarimeter.

Science.gov (United States)

Kawahata, K; Akiyama, T; Tanaka, K; Nakayama, K; Okajima, S

2010-10-01

Two color laser diagnostics using terahertz laser sources are under development for a high performance operation of the Large Helical Device and for future fusion devices such as ITER. So far, we have achieved high power laser oscillation lines simultaneously oscillating at 57.2 and 47.7 μm by using a twin optically pumped CH(3)OD laser, and confirmed the original function, compensation of mechanical vibration, of the two color laser interferometer. In this article, application of the two color laser diagnostics to the ITER poloidal polarimeter and recent hardware developments will be described.

Development of two color laser diagnostics for the ITER poloidal polarimeter

International Nuclear Information System (INIS)

Kawahata, K.; Akiyama, T.; Tanaka, K.; Nakayama, K.; Okajima, S.

2010-01-01

Two color laser diagnostics using terahertz laser sources are under development for a high performance operation of the Large Helical Device and for future fusion devices such as ITER. So far, we have achieved high power laser oscillation lines simultaneously oscillating at 57.2 and 47.7 μm by using a twin optically pumped CH 3 OD laser, and confirmed the original function, compensation of mechanical vibration, of the two color laser interferometer. In this article, application of the two color laser diagnostics to the ITER poloidal polarimeter and recent hardware developments will be described.

Color stability assessment of two different composite resins with variable immersion time using various beverages: An In vitro study

Directory of Open Access Journals (Sweden)

M Senthil Kumar

2017-01-01

Full Text Available Purpose of the Study: The aim of the study was to evaluate the difference in the color of microhybrid (MH and nanofilled (NF composite resins after 24 and 48 h in beverages such as red wine (RW, Coca-Cola, and distilled water. The specific objective of this study was to investigate the cumulative effect of the colorant solutions on the dental composites. Materials and Methods: MH and NF composite resins (A2 shade were used in this current study. Sixty disk-shaped material specimens (10 mm in diameter × 2 mm in thickness were prepared using a fiber mold (ring, with the desired dimensions. The specimen surfaces were polished using super-snap polishing system. Sixty specimens were divided into two groups of 30 each (Group I: MH resin composite; Group II: NF resin composite. Both the groups divided into six subgroups (Subgroup I: RW for 24 h [RW-24]; Subgroup II: RW for 48 h; Subgroup III: Coca-Cola for 24 h [CC-24]; Subgroup IV: Coca-Cola for 48 h [CC-48]; Subgroup V: Distilled water for 24 h [DW-24]; Subgroup VI: Distilled water for 48 h [DW-48]. All the samples were immersed in respective drinks for a period of 24 h, and color differences were measured using ultraviolet spectrophotometer. Once again, all the samples were immersed for another 24 h in the same drinks. After 48 h, the color change of the samples was measured. Measurements were made according to the CIE L × a × b × color space relative to the CIE standard illuminant D65. The color changes of the specimens were evaluated using the following formula: [INSIDE:1]Statistical analysis was performed. The data were analyzed using the one-way ANOVA and t-test at a significance level of 0.05. Conclusion: Color stability of MH composite resin was found to be inferior than the NF resin composite irrespective of immersion medium and time. In RW, the color change observed was maximum for both composite resins followed by Coca-Cola. Immersing the resin composites in distilled water for 24 and

Method for numerical simulation of two-term exponentially correlated colored noise

International Nuclear Information System (INIS)

Yilmaz, B.; Ayik, S.; Abe, Y.; Gokalp, A.; Yilmaz, O.

2006-01-01

A method for numerical simulation of two-term exponentially correlated colored noise is proposed. The method is an extension of traditional method for one-term exponentially correlated colored noise. The validity of the algorithm is tested by comparing numerical simulations with analytical results in two physical applications

Color-emotion associations and color preferences: A case study for residences

OpenAIRE

Manav, Banu

2007-01-01

This study examines existing beliefs about "color" focusing on color-emotion associations by discussing how color can be used as a way of communicator to fulfill human needs in residences. Fifty people from various age groups participated in the study. They were asked to match a list of adjectives with the proper color samples from the catalogue of a quite popular color producer firm in Turkey. Results indicate that there is a strong dependency between the choice and use of green at residence...

FT-IR spectroscopy of lipoproteins—A comparative study

Science.gov (United States)

Krilov, Dubravka; Balarin, Maja; Kosović, Marin; Gamulin, Ozren; Brnjas-Kraljević, Jasminka

2009-08-01

FT-IR spectra, in the frequency region 4000-600 cm -1, of four major lipoprotein classes: very low density lipoprotein (VLDL), low density lipoprotein (LDL) and two subclasses of high density lipoproteins (HDL 2 and HDL 3) were analyzed to obtain their detailed spectral characterization. Information about the protein domain of particle was obtained from the analysis of amide I band. The procedure of decomposition and curve fitting of this band confirms the data already known about the secondary structure of two different apolipoproteins: apo A-I in HDL 2 and HDL 3 and apo B-100 in LDL and VLDL. For information about the lipid composition and packing of the particular lipoprotein the well expressed lipid bands in the spectra were analyzed. Characterization of spectral details in the FT-IR spectrum of natural lipoprotein is necessary to study the influence of external compounds on its structure.

Two-colorable graph states with maximal Schmidt measure

International Nuclear Information System (INIS)

Severini, Simone

2006-01-01

The Schmidt measure was introduced by Eisert and Briegel for quantifying the degree of entanglement of multipartite quantum systems [J. Eisert, H.-J. Briegel, Phys. Rev. A 64 (2001) 22306]. For two-colorable graph states, the Schmidt measure is related to the spectrum of the associated graph. We observe that almost all two-colorable graph states have maximal Schmidt measure and we construct specific examples. By making appeal to a result of Ehrenfeucht et al. [A. Ehrenfeucht, T. Harju, G. Rozenberg, Discrete Math. 278 (2004) 45], we point out that the graph operations called local complementation and switching form a transitive group acting on the set of all graph states of a given dimension

Topological color codes and two-body quantum lattice Hamiltonians

Science.gov (United States)

Kargarian, M.; Bombin, H.; Martin-Delgado, M. A.

2010-02-01

Topological color codes are among the stabilizer codes with remarkable properties from the quantum information perspective. In this paper, we construct a lattice, the so-called ruby lattice, with coordination number 4 governed by a two-body Hamiltonian. In a particular regime of coupling constants, in a strong coupling limit, degenerate perturbation theory implies that the low-energy spectrum of the model can be described by a many-body effective Hamiltonian, which encodes the color code as its ground state subspace. Ground state subspace corresponds to a vortex-free sector. The gauge symmetry Z2×Z2 of the color code could already be realized by identifying three distinct plaquette operators on the ruby lattice. All plaquette operators commute with each other and with the Hamiltonian being integrals of motion. Plaquettes are extended to closed strings or string-net structures. Non-contractible closed strings winding the space commute with Hamiltonian but not always with each other. This gives rise to exact topological degeneracy of the model. A connection to 2-colexes can be established via the coloring of the strings. We discuss it at the non-perturbative level. The particular structure of the two-body Hamiltonian provides a fruitful interpretation in terms of mapping onto bosons coupled to effective spins. We show that high-energy excitations of the model have fermionic statistics. They form three families of high-energy excitations each of one color. Furthermore, we show that they belong to a particular family of topological charges. The emergence of invisible charges is related to the string-net structure of the model. The emerging fermions are coupled to nontrivial gauge fields. We show that for particular 2-colexes, the fermions can see the background fluxes in the ground state. Also, we use the Jordan-Wigner transformation in order to test the integrability of the model via introducing Majorana fermions. The four-valent structure of the lattice prevents the

Time-resolved VUV spectroscopy in the EXTRAP-T2 reversed field pinch

International Nuclear Information System (INIS)

Hedqvist, A.; Rachlew-Kaellne, E.

1998-01-01

Time-resolved VUV spectroscopy has been used to investigate the effects of impurities in a reversed field pinch operating with a resistive shell. Results of electron temperature, impurity ion densities, particle confinement time and Z eff together with a description of the interpretation and the equipment are presented. (author)

An X-ray photoelectron spectroscopy study of the products of the interaction of gaseous IrF6 with fine UO2F2

Directory of Open Access Journals (Sweden)

Prusakov Vladimir N.

2007-01-01

Full Text Available Nuclear fuel reprocessing by fluorination, a dry method of regeneration of spent nuclear fuel, uses UO2F2 for the separation of plutonium from gaseous mixtures. Since plutonium requires special treatment, IrF6 was used as a thermodynamic model of PuF6. The model reaction of the interaction of gaseous IrF6 with fine UO2F2 in the sorption column revealed a change of color of the sorption column contents from pale-yellow to gray and black, indicating the formation of products of such an interaction. The X-ray photoelectron spectroscopy study showed that the interaction of gaseous IrF6 with fine UO2F2 at 125 °C results in the formation of stable iridium compounds where the iridium oxidation state is close to Ir3+. The dependence of the elemental compositions of the layers in the sorption column on the penetration depth of IrF6 was established.

Fortification of Wheat Bread with Agroindustry By-Products: Statistical Methods for Sensory Preference Evaluation and Correlation with Color and Crumb Structure.

Science.gov (United States)

Martins, Z E; Pinho, O; Ferreira, I M P L V O

2017-09-01

The use of agroindustry by-products (BP) for fortification of wheat bread can be an alternative to waste disposal because BP are appealing sources of dietary fiber. Moreover, it may also contribute to indirect income generation. In this study, sensory, color, and crumb structure properties of breads fortified with fiber rich fraction recovered from four types of agroindustry BP were tested, namely orange (OE), pomegranate (PE), elderberry (EE), and spent yeast (YE). Statistical models for sensory preference evaluation and correlation with color and crumb structure were developed. External preference mapping indicated consumer preferences and enabled selection of the concentrations of BP fibre-rich fraction with best acceptance, namely 7.0% EE, 2.5% OE, 5.0% PE, and 2.5% YE. Data collected from image analysis complemented sensory profile information, whereas multivariate PLS regression provided information on the relationship between "crust color" and "crumb color" and instrumental data. Regression models developed for both sensory attributes presented good fitting (R 2 Y > 0.700) and predictive ability (Q 2 > 0.500), with low RMSE. Crust and crumb a* parameters had a positive influence on "crust color" and "crumb color" models, while crust L* and b* had a negative influence. © 2017 Institute of Food Technologists®.

Optimal designs for one- and two-color microarrays using mixed models: a comparative evaluation of their efficiencies.

Science.gov (United States)

Lima Passos, Valéria; Tan, Frans E S; Winkens, Bjorn; Berger, Martijn P F

2009-01-01

Comparative studies between the one- and two-color microarrays provide supportive evidence for similarities of results on differential gene expression. So far, no design comparisons between the two platforms have been undertaken. With the objective of comparing optimal designs of one- and two-color microarrays in their statistical efficiencies, techniques of design optimization were applied within a mixed model framework. A- and D-optimal designs for the one- and two-color platforms were sought for a 3 x 3 factorial experiment. The results suggest that the choice of the platform will not affect the "subjects to groups" allocation, being concordant in the two designs. However, under financial constraints, the two-color arrays are expected to have a slight upper hand in terms of efficiency of model parameters estimates, once the price of arrays is more expensive than that of subjects. This statement is especially valid for microarray studies envisaging class comparisons.

Atomic and molecular effects in the VUV spectra of solids

International Nuclear Information System (INIS)

Sonntag, B.

1977-10-01

The VUV spectra of solids are often dominated by atomic or molecular effects, which clearly manifest themselves in the gross features of the spectra and the fine structure at inner shell excitation thresholds. Evidence for the influence of atomic and molecular matrix elements, multiplet-splitting and correlation is presented. Special emphasis is given to the direct experimental verification based on the comparison of atomic and solid state spectra. (orig.) [de

Superimpose of images by appending two simple video amplifier circuits to color television

International Nuclear Information System (INIS)

Kojima, Kazuhiko; Hiraki, Tatsunosuke; Koshida, Kichiro; Maekawa, Ryuichi; Hisada, Kinichi.

1979-01-01

Images are very useful to obtain diagnostic informations in medical fields. Also by superimposing two or three images obtained from the same patient, various informations, for example a degree of overlapping and anatomical land mark, which can not be found in only one image, can be often found. In this paper characteristics of our trial color television system for the purpose of superimposing x-ray images and/or radionuclide images are described. This color television system superimposing two images in each different color consists of two monochromatic vidicon cameras and 20 inches conventional color television in which only two simple video amplifier circuits are added. Signals from vidicon cameras are amplified about 40 dB and are directly applied to cathode terminals of color CRT in the television. This system is very simple and economical color displays, and enhance a degree of overlapping and displacement between images. As one of typical clinical applications, pancreas images were superimposed in color by this method. As a result, size and position of pancreas was enhanced. Also x-ray image and radionuclide image were superimposed to find exactly the position of tumors. Furthermore this system was very useful for color display of multinuclides scintigraphy. (author)

Superimpose of images by appending two simple video amplifier circuits to color television

Energy Technology Data Exchange (ETDEWEB)

Kojima, K; Hiraki, T; Koshida, K; Maekawa, R [Kanazawa Univ. (Japan). School of Paramedicine; Hisada, K

1979-09-01

Images are very useful to obtain diagnostic informations in medical fields. Also by superimposing two or three images obtained from the same patient, various informations, for example a degree of overlapping and anatomical land mark, which can not be found in only one image, can be often found. In this paper characteristics of our trial color television system for the purpose of superimposing x-ray images and/or radionuclide images are described. This color television system superimposing two images in each different color consists of two monochromatic vidicon cameras and 20 inches conventional color television in which only two simple video amplifier circuits are added. Signals from vidicon cameras are amplified about 40 dB and are directly applied to cathode terminals of color CRT in the television. This system is very simple and economical color displays, and enhance a degree of overlapping and displacement between images. As one of typical clinical applications, pancreas images were superimposed in color by this method. As a result, size and position of pancreas was enhanced. Also x-ray image and radionuclide image were superimposed to find exactly the position of tumors. Furthermore this system was very useful for color display of multinuclides scintigraphy.

Density functional study of the L10-αIrV transition in IrV and RhV

International Nuclear Information System (INIS)

Mehl, Michael J.; Hart, Gus L.W.; Curtarolo, Stefano

2011-01-01

Research highlights: → The computational determination of the ground state of a material can be a difficult task, particularly if the ground state is uncommon and so not found in usual databases. In this paper we consider the alpha-IrV structure, a low temperature structure found only in two compounds, IrV and RhV. In both cases this structure can be considered as a distorted tetragonal structure, and the tetragonal 'L1 0 ' structure is the high temperature structure for both compounds. We show, however, that the logical path for the transition from the L1 0 to the alpha-IrV structure is energetically forbidden, and find a series of unstable and metastable structures which have a lower energy than the L1 0 phase, but are higher in energy than the alpha-IrV phase. We also consider the possibility of the alpha-IrV structure appearing in neighboring compounds. We find that both IrTi and RhTi are candidates. - Abstract: Both IrV and RhV crystallize in the αIrV structure, with a transition to the higher symmetry L1 0 structure at high temperature, or with the addition of excess Ir or Rh. Here we present evidence that this transition is driven by the lowering of the electronic density of states at the Fermi level of the αIrV structure. The transition has long been thought to be second order, with a simple doubling of the L1 0 unit cell due to an unstable phonon at the R point (0 1/2 1/2). We use first-principles calculations to show that all phonons at the R point are, in fact, stable, but do find a region of reciprocal space where the L1 0 structure has unstable (imaginary frequency) phonons. We use the frozen phonon method to examine two of these modes, relaxing the structures associated with the unstable phonon modes to obtain new structures which are lower in energy than L1 0 but still above αIrV. We examine the phonon spectra of these structures as well, looking for instabilities, and find further instabilities, and more relaxed structures, all of which have

A VUV photoionization measurement and ab-initio calculation of the ionization energy of gas phase SiO2

Energy Technology Data Exchange (ETDEWEB)

Kostko, Oleg; Ahmed, Musahid; Metz, Ricardo B.

2008-12-05

In this work we report on the detection and vacuum-ultraviolet (VUV) photoionization of gas phase SiO2 generated in situ via laser ablation of silicon in a CO2 molecular beam. The resulting species are investigated by single photon ionization with tunable VUV synchrotron radiation and mass analyzed using reflectron mass spectrometry. Photoionization efficiency (PIE) curves are recorded for SiO and SiO2 and ionization energy estimates are revealed from such measurements. A state-to-state ionizationenergy of 12.60 (+-0.05) eV is recorded by fitting two prominent peaks in the PIE curve for the following process: 1SUM O-Si-O --> 2PRODg [O-Si-O]+. Electronic structure calculations aid in the interpretation of the photoionization process and allow for identification of the symmetric stretch of 2PRODg [O-Si-O]+ which is observed in the PIE spectrum to be 0.11 eV (890 cm-1) above the ground state of the cation and agrees with the 892 cm-1 symmetric stretch frequency calculated at the CCSD(T)/aug-cc-pVTZ level.

Behaviour of large-area avalanche photodiodes under intense magnetic fields for VUV- visible- and X-ray photon detection

International Nuclear Information System (INIS)

Fernandes, L.M.P.; Antognini, A.; Boucher, M.; Conde, C.A.N.; Huot, O.; Knowles, P.; Kottmann, F.; Ludhova, L.; Mulhauser, F.; Pohl, R.; Schaller, L.A.; Santos, J.M.F. dos; Taqqu, D.; Veloso, J.F.C.A.

2003-01-01

The behaviour of large-area avalanche photodiodes for X-rays, visible and vacuum-ultra-violet (VUV) light detection in magnetic fields up to 5 T is described. For X-rays and visible light detection, the photodiode pulse amplitude and energy resolution were unaffected from 0 to 5 T, demonstrating the insensitivity of this type of detector to strong magnetic fields. For VUV light detection, however, the photodiode relative pulse amplitude decreases with increasing magnetic field intensity reaching a reduction of about 24% at 5 T, and the energy resolution degrades noticeably with increasing magnetic field

Color categories and color appearance

Science.gov (United States)

Webster, Michael A.; Kay, Paul

2011-01-01

We examined categorical effects in color appearance in two tasks, which in part differed in the extent to which color naming was explicitly required for the response. In one, we measured the effects of color differences on perceptual grouping for hues that spanned the blue–green boundary, to test whether chromatic differences across the boundary were perceptually exaggerated. This task did not require overt judgments of the perceived colors, and the tendency to group showed only a weak and inconsistent categorical bias. In a second case, we analyzed results from two prior studies of hue scaling of chromatic stimuli (De Valois, De Valois, Switkes, & Mahon, 1997; Malkoc, Kay, & Webster, 2005), to test whether color appearance changed more rapidly around the blue–green boundary. In this task observers directly judge the perceived color of the stimuli and these judgments tended to show much stronger categorical effects. The differences between these tasks could arise either because different signals mediate color grouping and color appearance, or because linguistic categories might differentially intrude on the response to color and/or on the perception of color. Our results suggest that the interaction between language and color processing may be highly dependent on the specific task and cognitive demands and strategies of the observer, and also highlight pronounced individual differences in the tendency to exhibit categorical responses. PMID:22176751

Production and detection of axion-like particles at the VUV-FEL. Letter of intent

International Nuclear Information System (INIS)

Koetz, U.; Ringwald, A.; Tschentscher, T.

2006-06-01

Recently, the PVLAS collaboration has reported evidence for an anomalously large rotation of the polarization of light generated in vacuum in the presence of a transverse magnetic field. This may be explained through the production of a new light spin-zero particle coupled to two photons. In this Letter of Intent, we propose to test this hypothesis by setting up a photon regeneration experiment which exploits the photon beam of the Vacuum-UltraViolet Free-Electron Laser VUV-FEL, sent along the transverse magnetic field of a linear arrangement of dipole magnets of size B L ∼ 30 Tm. The high photon energies available at the VUV-FEL increase substantially the expected photon regeneration rate in the mass range implied by the PVLAS anomaly, in comparison to the rate expected at visible lasers of similar power. We find that the particle interpretation of the PVLAS result can be tested within a short running period. The pseudoscalar vs. scalar nature can be determined by varying the direction of the magnetic field with respect to the laser polarization. The mass of the particle can be measured by running at different photon energies. The proposed experiment offers a window of opportunity for a firm establishment or exclusion of the particle interpretation of the PVLAS anomaly before other experiments can compete. (Orig.)

The linear lattice design of an advanced VUV/SXR photon source for Daresbury

International Nuclear Information System (INIS)

Clarke, J.A.; Corlett, J.N.; Poole, M.W.; Smith, S.L.; Suller, V.P.; Welbourne, L.A.

1992-01-01

The linear lattice design of an advanced synchrotron radiation source in the VUV/SXR region, optimised to produce undulator radiation with high brilliance over the range 5-1000 eV, is discussed. The photon source is based on a 10 cell double bend achromat which will operate over the range 0.5-1.2 GeV. The linear lattice properties over the total available working region are presented for this structure. It is demonstrated that the circular lattice can be extended to a racetrack configuration by the inclusion of two long matched straights with free lengths of over 15 m each. (author) 8 refs.; 5 figs.; 1 tab

National Synchrotron Light Source users manual: Guide to the VUV and x-ray beam lines

International Nuclear Information System (INIS)

Gmuer, N.F.; White-DePace, S.M.

1987-08-01

The success of the National Synchrotron Light Source in the years to come will be based, in large part, on the size of the users community and the diversity of the scientific disciplines represented by these users. In order to promote this philosophy, this National Synchrotron Light Source (NSLS) Users Manual: Guide to the VUV and X-Ray Beam Lines, has been published. This manual serves a number of purposes. In an effort to attract new research, it will present to the scientific community-at-large the current and projected architecture and capabilities of the various VUV and x-ray beam lines and storage rings. We anticipate that this publication will be updated periodically in order to keep pace with the constant changes at the NSLS

Direct measuring of single-cycle mid-IR light bullets path length in LiF by the laser coloration method

Directory of Open Access Journals (Sweden)

Chekalin Sergey

2017-01-01

Full Text Available A colour-centre structure formed in a LiF crystal under filamentation of a femtosecond mid-IR laser pulse with a power slightly exceeding the critical power for self-focusing has been experimentally and theoretically investigated. A single-cycle light bullet was recorded for the first time by observation of strictly periodic oscillations for the density of the color centers induced in an isotropic LiF crystal under filamentation of a laser beam with a wavelength tuned in the range from 2600 to 3900 nm, which is due to the periodic change in the light field amplitude in the light bullet formed under filamentation under propagation in dispersive medium. The light bullet path length was not more than one millimeter.

Energy-beam processing studies on Ta/U and Ir/Ta systems

International Nuclear Information System (INIS)

Kaufmann, E.N.; Peercy, P.S.; Jacobson, D.C.; Draper, C.W.; Huegel, F.J.; Echer, C.J.; Makowiecki, D.M.; Balser, J.D.

1983-01-01

Films of Ta metal on uranium and of Ir metal on tantalum have been irradiated and melted by pulses from Q-switched Ruby and frequency-doubled Nd:YAG lasers to investigate the nature of the resulting mixtures in light of the very different binary-phase diagrams of the two systems. In addition, a two-phase Ir-Ta alloy has been surface-processed with CW CO 2 -laser radiation and with an electron beam in order to study microstructure refinement and test the advantage of using alloys as opposed to film-on-substrate combinations for the development of claddings

Comparison between two race/skin color classifications in relation to health-related outcomes in Brazil

Directory of Open Access Journals (Sweden)

Szwarcwald Celia L

2011-08-01

Full Text Available Abstract Background This paper aims to compare the classification of race/skin color based on the discrete categories used by the Demographic Census of the Brazilian Institute of Geography and Statistics (IBGE and a skin color scale with values ranging from 1 (lighter skin to 10 (darker skin, examining whether choosing one alternative or the other can influence measures of self-evaluation of health status, health care service utilization and discrimination in the health services. Methods This is a cross-sectional study based on data from the World Health Survey carried out in Brazil in 2003 with a sample of 5000 individuals older than 18 years. Similarities between the two classifications were evaluated by means of correspondence analysis. The effect of the two classifications on health outcomes was tested through logistic regression models for each sex, using age, educational level and ownership of consumer goods as covariables. Results Both measures of race/skin color represent the same race/skin color construct. The results show a tendency among Brazilians to classify their skin color in shades closer to the center of the color gradient. Women tend to classify their race/skin color as a little lighter than men in the skin color scale, an effect not observed when IBGE categories are used. With regard to health and health care utilization, race/skin color was not relevant in explaining any of them, regardless of the race/skin color classification. Lack of money and social class were the most prevalent reasons for discrimination in healthcare reported in the survey, suggesting that in Brazil the discussion about discrimination in the health care must not be restricted to racial discrimination and should also consider class-based discrimination. The study shows that the differences of the two classifications of race/skin color are small. However, the interval scale measure appeared to increase the freedom of choice of the respondent.

Frequency of asymptomatic pulmonary emboli (PE) in patients with a proximal profound veinal thrombosis (PVT) of inferior limbs during the FRAXODI study

International Nuclear Information System (INIS)

Gauthier, H.; Rosso, J.; Charbonnier, B.; Meignan, M.

1997-01-01

FRAXODI, an European multi-center program (n=70), allowed to compare the efficiency of Fraxiparin (20 500 UI AXa/mL) once a day with the conventional treatment by Fraxiparin (10 250 UI AXa/mL) twice a day by sub-cutaneous injection in patients with a PVT of inferior limbs without clinical signs of PE. A pulmonary scintigraphy has been performed at registration in 622 patients (delay ≤ 48 h): a sole perfusion with at least 4 incidences of which 2 were posterior oblique incidences or coupled to a ventilation scintigraphy (Xe-133, Kr-81 or aerosols) in 379 patients. Three diagnostic categories were defined: no PE in case of normal examination or under-segmentary perfusion anomalies (≤ 3); high probability (HP) of PE if at least a defect of normally ventilated segmentary perfusion existed; non-contributing examination in all the other cases. On the ensemble of the group, 367 patients have had at least a defect of segmentary perfusion, 296 patients had two or more. One hundred and forty one patients have had solely defects of sub-segmentary perfusion; 77 patients have had 3 or less then 3. One hundred and fourteen patients have had a normal examination. In the sub-group of ventilation scintigraphy, 235 patients have had at least one defect of segmentary perfusion, 88 patients have had defects of sub-segmentary perfusion and 56 patients have had a normal examination. The diagnosis analysis showed that 42% of patients have had a HP scintigraphy, 30% a non-contributive scintigraphy and the PE could be eliminated in 27% of patients. These results: 1 - demonstrated the extreme frequency of HP aspects of PE in patients afflicted with PVT; 2 - allowed estimating in this patients, as a function of the results of the PIOPED study, the frequency of asymptomatic PE in more then 50%; 3 - allowed recommending in the systematic practice a perfusion scintigraphy in case of PVT without clinical signs of PE providing the over-estimation of secondary PE occurrence during the

Time-resolved VUV spectroscopy in the EXTRAP-T2 reversed field pinch

Science.gov (United States)

Hedqvist, Anders; Rachlew-Källne, Elisabeth

1998-09-01

Time-resolved VUV spectroscopy has been used to investigate the effects of impurities in a reversed field pinch operating with a resistive shell. Results of electron temperature, impurity ion densities, particle confinement time and 0741-3335/40/9/004/img1 together with a description of the interpretation and the equipment are presented.

A study on the effect of P/E and PEG ratios on stock returns: Evidence from Tehran Stock Exchange

Directory of Open Access Journals (Sweden)

Seyyed Ali Lajevardi

2014-07-01

Full Text Available This paper studies the effect of the ratios of P/E and PEG on stock returns of the firms accepted on Tehran Stock Exchange. The study uses regression and Pearson Correlation Coefficient based on the performance of 138 firms over the period 2004- 2009 according to the Iranian calendar to investigate the effects of P/E and PEG on stock returns. The study also uses the models originally proposed by Chahin and Choudhry (2010 [Chahin, S., & Choudhry, T. (2010. Price to earnings, growth radio and value growth based strategies. Social Science Research Network, 19(4.] to discuss the strategies of investing on stocks. The results show that the ratio of P/E had more effect on stock returns than the ratio of PEG and stocks returns had a direct relationship with P/E and an inverse relationship with PEG. In addition, the returns of growth stock were more than value stock.

Storage-ring FEL for the vuv

International Nuclear Information System (INIS)

Peterson, J.M.; Bisognano, J.J.; Garren, A.A.; Halbach, K.; Kim, K.J.; Sah, R.C.

1984-09-01

A free-electron laser for the vuv operating in a storage ring requires an electron beam of high density and low energy spread and a short wavelength, narrow-gap undulator. These conditions tend to produce longitudinal and transverse beam instabilities, excessive beam growth through multiple intrabeam scattering, and a short gas-scattering lifetime. Passing the beam only occasionally through the undulator in a by-pass straight section, as proposed by Murphy and Pellegrini, allows operation in a high-gain, single-pass mode and a long gas-scattering lifetime. Several storage ring designs have been considered to see how best to satisfy the several requirements. Each features a by-pass, a low-emittance lattice, and built-in wigglers for enhanced damping to counteract the intra-beam scattering. 15 references, 3 figures, 2 tables

Single- and multi-photon ionization studies of organosulfur species

Energy Technology Data Exchange (ETDEWEB)

Cheung, Yu -San [Iowa State Univ., Ames, IA (United States)

1999-02-12

Accurate ionization energies (IE`s) for molecular species are used for prediction of chemical reactivity and are of fundamental importance to chemists. The IE of a gaseous molecule can be determined routinely in a photoionization or a photoelectron experiment. IE determinations made in conventional photoionization and photoelectron studies have uncertainties in the range of 3--100 meV (25--250 cm^-1). In the past decade, the most exciting development in the field of photoionization and photoelectron spectroscopy has been the availability of high resolution, tunable ultraviolet (UV) and vacuum ultraviolet (VUV) laser sources. The laser pulsed field ionization photoelectron (PFI-PE) scheme is currently the state-of-the-art photoelectron spectroscopic technique and is capable of providing photoelectron energy resolution close to the optical resolution. The author has focused attention on the photoionization processes of some sulfur-containing species. The studies of the photoionization and photodissociation on sulfur-containing compounds [such as CS₂, CH₃SH, CH₃SSCH₃, CH₃CH₂SCH₂CH₃, HSCH₂CH₂SH and C₄H₄S (thiophene) and sulfur-containing radicals, such as HS, CS, CH₃S, CH₃CH₂S and CH₃SS], have been the major subjects in the group because sulfur is an important species contributing to air pollution in the atmosphere. The modeling of the combustion and oxidation of sulfur compounds represents important steps for the control of both the production and the elimination of sulfur-containing pollutants. Chapter 1 is a general introduction of the thesis. Chapters 2 and 6 contain five papers published in, or accepted for publication in, academic periodicals. In Chapter 7, the progress of the construction in the laboratory of a new vacuum ultraviolet laser system equipped with a reflectron mass

Uncooled Radiation Hard SiC Schottky VUV Detectors Capable of Single Photon Sensing, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — This project seeks to design, fabricate, characterize and commercialize very large area, uncooled and radiative hard 4H-SiC VUV detectors capable of near single...

Influence of two different IR radiators on the antioxidative potential of the human skin

International Nuclear Information System (INIS)

Darvin, M E; Patzelt, A; Meinke, M; Sterry, W; Lademann, J

2009-01-01

Resonance Raman spectroscopy was used for the fast in vivo detection of the concentration of carotenoid antioxidant substances such as beta-carotene and lycopene in human skin and for the measurement of their degradation dynamics, subsequent to infrared (IR) irradiation emitted by two different IR radiators applied at the same power density. One of the radiators was equipped with a water filter in front of the radiation source (WIRA) and the other was a usual broadband system without a water filter (standard IR radiator – SIR). It was found that the SIR exerted a higher influence on the degradation of carotenoids in the skin than the WIRA. Furthermore, all twelve volunteers who participated in the study felt that the irradiation with the SIR was disagreeably warmer on the skin surface compared to the WIRA, in spite of the same power density values for both radiators on the skin surface. The average degradation magnitude of the carotenoids in the skin of all volunteers after an IR irradiation was determined at 23% for WIRA and 33% for the SIR. A correlation (R 2 ∼ 0.6) was found between the individual level of carotenoids in the skin of the volunteers and the magnitude of degradation of the carotenoids for both IR radiators. Taking the previous investigations into consideration, which clearly showed production of free radicals in the skin subsequent to IR irradiation, it can be concluded that during the application of WIRA irradiation on the skin, fewer radicals are produced in comparison to the SIR

Acute intrascrotal pathology in childhood: color Doppler study

International Nuclear Information System (INIS)

Cinta Sanguesa, C.; Muro, D.; Cortina, H.; Moreno, A.

1997-01-01

To asses the utility of color Doppler ultrasound in the study of acute intrascrotal pathology in childhood. Seventy-five boys with evidence of an acute intrascrotal abnormality were studied by means of color Doppler ultrasound. A 7.5 MHz linear transducer was used. The most common findings was inflammatory disease (60%) which was indicated by the presence of hyperemia in color Doppler. Of the nine boys with testicular torsion (12%) two presented extravaginal torsion, with a complete absence of intratesticular vascularization. Intravaginal torsion was observed in seven patients, six of whom presented reduced vascularization in the abnormal testicle with respect to the healthy testicle. There was one false negative in which testicular vascularization was normal but 360 degree centigree torsion was found at surgery. In addition, there were seven cases of hydatid torsion (9.33%), four of idiopathic scrotal swelling (5.3%). two cases of intermittent torsion (2.6%) and one case of Shcolein-Henoch purpura (1.3%). The ultrasound findings were completely nornal in seven boys. Color Doppler is a rapid, noninvasive method for assessing testicular blood flow. The elevated sensitivity and specificity (85.7 and 100%, respectively, in our series) for testicular torsion make Doppler ultrasound a highly reliable method for the study of this disorder. (Author) 18 refs

Characteristics and performance of the Los Alamos VUV beamline at the NSLS

International Nuclear Information System (INIS)

Bartlett, R.J.; Trela, W.J.; Michaud, F.D.; Southworth, S.H.; Alkire, R.W.; Roy, P.; Rothe, R.; Walsh, P.J.; Shinn, N.

1988-01-01

We describe the design and performance of the Los Alamos VUV synchrotron radiation beamline, U3C, on the VUV ring of the National Synchrotron Light Source at Brookhaven National Laboratory. The beamline uses separate function optics to collect and focus the horizontally and vertically diverging beam. The monochromator is a grazing incidence Rowland circle instrument of the extended grasshopper design (ERG). A postmonochromator refocusing mirror is used to focus or collimate the diverging beam from the monochromator. The beamline control and diagnostics systems are also discussed. Particular emphasis in the design has been placed on the reduction of stray and harmonic light. Higher order light is reduced by a grazing angle mirror low pass filter installed immediately downstream from the monochromator while stray light is reduced through the use of baffles and thin film filters. Also included in the line is a differential pumping section that permits gas phase and other experiments requiring pressures in the 10 -5 to 10 -4 Torr range to be coupled to the beamline. (orig.)

Combined two-photon excitation and d → f energy-transfer in Ir/lanthanide dyads with time-gated selection from a two-component emission spectrum.

Science.gov (United States)

Edkins, Robert M; Sykes, Daniel; Beeby, Andrew; Ward, Michael D

2012-10-14

In a pair of Ir/Eu and Ir/Tb dyads, two-photon excitation of the Ir-phenylpyridine chromophore at 780 nm is followed by partial d → f energy-transfer to give a combination of short-lived Ir-based (blue) and long-lived lanthanide-based (red or green) emission; these components can be selected separately by time-gated detection.

Two-color stabilization of atomic hydrogen in circularly polarized laser fields

International Nuclear Information System (INIS)

Bauer, D.; Ceccherini, F.

2002-01-01

The dynamic stabilization of atomic hydrogen against ionization in high-frequency single- and two-color, circularly polarized laser pulses is observed by numerically solving the three-dimensional, time-dependent Schroedinger equation. The single-color case is revisited and numerically determined ionization rates are compared with both, the exact and the approximate high-frequency Floquet rates. The positions of the peaks in the photoelectron spectra can be explained with the help of dressed initial states. In two-color laser fields of opposite circular polarization, the stabilized probability density may be shaped in various ways. For laser frequencies ω 1 and ω 2 =nω 1 , n=2,3,..., and sufficiently large excursion amplitudes (n+1) distinct probability density peaks are observed. This may be viewed as the generalization of the well-known 'dichotomy' in linearly polarized laser fields, i.e, as 'trichotomy', 'quatrochotomy', 'pentachotomy' etc. All those observed structures and their 'hula-hoop'-like dynamics can be understood with the help of high-frequency Floquet theory and the two-color Kramers-Henneberger transformation. The shaping of the probability density in the stabilization regime can be realized without additional loss in the survival probability, as compared to the corresponding single-color results

Two-color infrared detector

Science.gov (United States)

Klem, John F; Kim, Jin K

2014-05-13

A two-color detector includes a first absorber layer. The first absorber layer exhibits a first valence band energy characterized by a first valence band energy function. A barrier layer adjoins the first absorber layer at a first interface. The barrier layer exhibits a second valence band energy characterized by a second valence band energy function. The barrier layer also adjoins a second absorber layer at a second interface. The second absorber layer exhibits a third valence band energy characterized by a third valence band energy function. The first and second valence band energy functions are substantially functionally or physically continuous at the first interface and the second and third valence band energy functions are substantially functionally or physically continuous at the second interface.

Color design model of high color rendering index white-light LED module.

Science.gov (United States)

Ying, Shang-Ping; Fu, Han-Kuei; Hsieh, Hsin-Hsin; Hsieh, Kun-Yang

2017-05-10

The traditional white-light light-emitting diode (LED) is packaged with a single chip and a single phosphor but has a poor color rendering index (CRI). The next-generation package comprises two chips and a single phosphor, has a high CRI, and retains high luminous efficacy. This study employs two chips and two phosphors to improve the diode's color tunability with various proportions of two phosphors and various densities of phosphor in the silicone used. A color design model is established for color fine-tuning of the white-light LED module. The maximum difference between the measured and color-design-model simulated CIE 1931 color coordinates is approximately 0.0063 around a correlated color temperature (CCT) of 2500 K. This study provides a rapid method to obtain the color fine-tuning of a white-light LED module with a high CRI and luminous efficacy.

Use of HOMA-IR to diagnose non-alcoholic fatty liver disease: a population-based and inter-laboratory study

OpenAIRE

Isokuortti, Elina; Zhou, You; Peltonen, Markku; Bugianesi, Elisabetta; Clement, Karine; Bonnefont-Rousselot, Dominique; Lacorte, Jean-Marc; Gastaldelli, Amalia; Schuppan, Detlef; Schattenberg, Jörn M.; Hakkarainen, Antti; Lundbom, Nina; Jousilahti, Pekka; Männistö, Satu; Keinänen-Kiukaanniemi, Sirkka

2017-01-01

Aims/hypothesis\\ud \\ud Recent European guidelines for non-alcoholic fatty liver disease (NAFLD) call for reference values for HOMA-IR. In this study, we aimed to determine: (1) the upper limit of normal HOMA-IR in two population-based cohorts; (2) the HOMA-IR corresponding to NAFLD; (3) the effect of sex and PNPLA3 genotype at rs738409 on HOMA-IR; and (4) inter-laboratory variations in HOMA-IR.\\ud \\ud Methods\\ud \\ud We identified healthy individuals in two population-based cohorts (FINRISK 20...

Color change of tourmaline by heat treatment and electron beam irradiation: UV-Visible, EPR, and Mid-IR spectroscopic analyses

Science.gov (United States)

Maneewong, Apichate; Seong, Baek Seok; Shin, Eun Joo; Kim, Jeong Seog; Kajornrith, Varavuth

2016-01-01

The color of pink tourmaline gemstone changed to colorless when heating at temperature of 600 °C in air. This colorless tourmaline recovered its pink color when irradiated with an electron beam (e-beam) of 800 kGy. The origin of the color change was investigated in three types of tourmaline gemstones, two pink are from Afghanistan and one green are from Nigeria, by using Ultraviolet-visible spectroscopy (UV-Vis), Fourier-transform infrared spectroscopy (FTIR), Electron paramagnetic resonance (EPR), and Energy Dispersive X-ray Fluorescence (EDXRF). The UV-Vis absorption spectrum of the pink tourmaline with higher Mn concentration (T2, 0.24 wt%) showed characteristic absorption peaks originating from the Mn3+ color center: two absorption bands centered at wavelength of 396 and 520 nm, respectively. Both absorption bands disappeared when heated in air at 600 °C and then reappeared when irradiated with an e-beam at 800 kGy. EPR T2 spectra showed that the color change was related to the valence change of Mn3+ to Mn2+ and vice versa. The pink tourmaline of lower MnO content (T1, 0.08 wt%) also became colorless when heated, but the color was not recovered when the gemstone underwent e-beam irradiation. Instead, a yellow color was obtained. UV-Vis and FTIR spectra indicated that this yellow color originated from a decomposition of the hydroxyl group (-OH) into O- and Ho by the e-beam irradiation. Green tourmaline did not show any color change with either heat treatment or e-beam irradiation.

Pilot study of a culturally adapted psychoeducation (CaPE) intervention for bipolar disorder in Pakistan.

Science.gov (United States)

Husain, Muhammad Ishrat; Chaudhry, Imran B; Rahman, Raza R; Hamirani, Munir M; Mehmood, Nasir; Haddad, Peter M; Hodsoll, John; Young, Allan H; Naeem, Farooq; Husain, Nusrat

2017-12-01

Despite the use of maintenance medication, recurrence rates in bipolar affective disorder (BPAD) are high. To date, there are no clinical trials that have investigated the use of psychological interventions in bipolar disorder in Pakistan. The purpose of the study was to assess the feasibility and acceptability of a culturally adapted bipolar psychoeducation programme (CaPE) in Pakistan. Thirty-four euthymic bipolar I and II outpatients were randomized to either 12 weekly sessions of individual psychoeducation plus Treatment As Usual (Intervention) or Treatment As Usual (TAU) (Control). Outcomes were assessed using the Young Mania Rating Scale (YMRS), Beck Depression Inventory (BDI), EuroQoL (EQ-5D), Bipolar Knowledge and Attitudes and Questionnaire (BKAQ), and a self-reported measure of medication adherence (Morisky Medication Adherence Scale-4 items, MMAS-4). Effect sizes were derived from baseline adjusted standardized regression coefficients. Retention in the study was good, 80% of patients in the TAU follow-up assessment and 100% of patients in the CaPE group attended all 12 sessions. Patient satisfaction was higher in the CaPE group relative to control (ES = 1.41). Further, there were large effect sizes shown for CaPE versus TAU for medication adherence (MMAS-4: ES = 0.81), knowledge and attitudes towards bipolar (BKAQ: ES = 0.68), mania (YMRS: ES = 1.18), depression (BDI: ES = 1.17) and quality of life measures (EQ-5D: ES ⇒ 0.88). Culturally adapted psychoeducation intervention is acceptable and feasible, and can be effective in improving mood symptoms and knowledge and attitudes to BPAD when compared with TAU. Larger scale studies are needed to confirm our findings. Clinicaltrials.gov identifier NCT02210390.

Hydrothermal synthesis and luminescent properties of LnPO4:Tb,Bi (Ln=La,Gd) phosphors under UV/VUV excitation

International Nuclear Information System (INIS)

Wang Yuhua; Wu Chunfang; Wei Jie

2007-01-01

Monoclinic LnPO 4 :Tb,Bi (Ln=La,Gd) phosphors were prepared by hydrothermal reaction and their luminescent properties under ultraviolet (UV) and vacuum ultraviolet (VUV) excitation were investigated. LaPO 4 :Tb,Bi phosphor and GdPO 4 :Tb phosphor showed the strongest emission intensity under 254 and 147 nm excitation, respectively, because of the different energy transfer models. In UV region, Bi 3+ absorbed most energy then transferred to Tb 3+ , but in VUV region it was the host which absorbed most energy and transferred to Tb 3+

Effect of two fluoride varnishes on the color stability of three resin-based restorative materials: an in vitro study.

Science.gov (United States)

Tafaroji, Raha; Biria, Mina; Ameri, Farhad; Torabzadeh, Hassan; Qahari, Pasha; Akbarzadeh Baghban, Alireza

2016-11-01

The aim of the present study was to evaluate the effect of two fluoride varnishes on color stability of three resin-based restorative materials. Fifty-four discs (14.5 × 1.7 mm) were fabricated from A2 and A3 shades of a compomer (F2000), a flowable composite (Z350), and a hybrid composite (Z250), and incubated at 37°C for 48 h. Dura Shield (colored) and Fluor Protector (colorless) fluoride varnishes were applied onto the discs. The coating was cleaned using a low-speed handpiece and nylon bristle brush after 24 h of storage in distilled water. A second coating was then applied. A control group with no coating was immersed in distilled water and used. The CIE L*a*b* color scale was measured before the treatments and following each cleaning utilizing a spectrophotometer. The colored fluoride varnish exhibited the highest overall color change (∆E) after the first and the second cleaning procedures in all the materials. Among these, the greatest color change was observed in the A3 shade of F2000, followed by the A3 shade of Z-250. The ∆E was less than 3.3 in all groups, and was therefore clinically acceptable. Color changes following the application of fluoride varnishes were found to be clinically acceptable in all groups. © 2015 Wiley Publishing Asia Pty Ltd.

HOMA1-IR and HOMA2-IR indexes in identifying insulin resistance and metabolic syndrome: Brazilian Metabolic Syndrome Study (BRAMS).

Science.gov (United States)

Geloneze, Bruno; Vasques, Ana Carolina Junqueira; Stabe, Christiane França Camargo; Pareja, José Carlos; Rosado, Lina Enriqueta Frandsen Paez de Lima; Queiroz, Elaine Cristina de; Tambascia, Marcos Antonio

2009-03-01

To investigate cut-off values for HOMA1-IR and HOMA2-IR to identify insulin resistance (IR) and metabolic syndrome (MS), and to assess the association of the indexes with components of the MS. Nondiabetic subjects from the Brazilian Metabolic Syndrome Study were studied (n = 1,203, 18 to 78 years). The cut-off values for IR were determined from the 90th percentile in the healthy group (n = 297) and, for MS, a ROC curve was generated for the total sample. In the healthy group, HOMA-IR indexes were associated with central obesity, triglycerides and total cholesterol (p 2.7 and HOMA2-IR > 1.8; and, for MS were: HOMA1-IR > 2.3 (sensitivity: 76.8%; specificity: 66.7%) and HOMA2-IR > 1.4 (sensitivity: 79.2%; specificity: 61.2%). The cut-off values identified for HOMA1-IR and HOMA2-IR indexes have a clinical and epidemiological application for identifying IR and MS in Westernized admixtured multi-ethnic populations.

Perceived Social-Ecological Barriers of Generalist Pre-Service Teachers towards Teaching Physical Education: Findings from the GET-PE Study

Science.gov (United States)

Hyndman, Brendon P.

2017-01-01

Identifying and understanding the perceptions of pre-service teachers (PSTs) is vital to informing teaching practices. The purpose of the "Generalist Entry into Teaching Physical Education" (GET-PE) study was to investigate Australian generalist PSTs' perceptions of the barriers to teaching physical education (PE) classes. A…

Comparison of BIASI and Columbia CHF correlations using BODYFIT-2PE

International Nuclear Information System (INIS)

Chen, B.C.J.; Chien, T.H.; Sha, W.T.; Kim, J.H.

1984-01-01

This paper compares the BIASI critical heat flux (CHF) correlation with the Columbia CHF correlation by using both the homogeneous equilibrium two-phase model with algebraic slip and the drift flux model in BODYFIT-2PE. All calculations were compared with the GE 3 x 3 CHF experiment. This comparison serves as a qualification process for the CHF correlations in the framework of BODYFIT-2PE

Numerical Prediction of CCV in a PFI Engine using a Parallel LES Approach

Energy Technology Data Exchange (ETDEWEB)

Ameen, Muhsin M; Mirzaeian, Mohsen; Millo, Federico; Som, Sibendu

2017-10-15

Cycle-to-cycle variability (CCV) is detrimental to IC engine operation and can lead to partial burn, misfire, and knock. Predicting CCV numerically is extremely challenging due to two key reasons. Firstly, high-fidelity methods such as large eddy simulation (LES) are required to accurately resolve the incylinder turbulent flowfield both spatially and temporally. Secondly, CCV is experienced over long timescales and hence the simulations need to be performed for hundreds of consecutive cycles. Ameen et al. (Int. J. Eng. Res., 2017) developed a parallel perturbation model (PPM) approach to dissociate this long time-scale problem into several shorter timescale problems. The strategy is to perform multiple single-cycle simulations in parallel by effectively perturbing the initial velocity field based on the intensity of the in-cylinder turbulence. This strategy was demonstrated for motored engine and it was shown that the mean and variance of the in-cylinder flowfield was captured reasonably well by this approach. In the present study, this PPM approach is extended to simulate the CCV in a fired port-fuel injected (PFI) SI engine. Two operating conditions are considered – a medium CCV operating case corresponding to 2500 rpm and 16 bar BMEP and a low CCV case corresponding to 4000 rpm and 12 bar BMEP. The predictions from this approach are also shown to be similar to the consecutive LES cycles. Both the consecutive and PPM LES cycles are observed to under-predict the variability in the early stage of combustion. The parallel approach slightly underpredicts the cyclic variability at all stages of combustion as compared to the consecutive LES cycles. However, it is shown that the parallel approach is able to predict the coefficient of variation (COV) of the in-cylinder pressure and burn rate related parameters with sufficient accuracy, and is also able to predict the qualitative trends in CCV with changing operating conditions. The convergence of the statistics

Optimization of esterification of oleic acid and trimethylolpropane (TMP) and pentaerythritol (PE)

Energy Technology Data Exchange (ETDEWEB)

Mahmud, Hamizah Ammarah; Salimon, Jumat [School of Chemical Sciences and Food Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan (Malaysia)

2014-09-03

Vegetable oil (VO) is the most potential alternative to replace mineral oil for lubricant due to better lubricating properties and great physicochemical properties. Chemical modification has to be done to overcome low temperature performance and low oxidation instability due to the presence of β-hydrogen atoms of glycerol molecule. The optimization of esterification of oleic acid and polyhydric alcohol with sulfuric acid catalyst was carried out to find the optimum conditions with the highest yield. Reeaction variables such as; molar ratio, temperature, duration and catalyst concentration. Two types of polyhydric alcohol have been used; TMP and PE. The optimum results showed oleic acid successfully converted 91.2% ester TMP and 92.7% ester PE at duration: 5 hours (Ester TMP), 6 hours (Ester PE); temperature: 150°C (ester TMP), 180°C (Ester PE); catalyst concentration: 1.5% (w/w); and mol ratio: 3.9:1 (ester TMP), 4.9:1 (ester PE). From the data obtained, mole ratio showed most influenced factors to the increasing yields of ester conversions.. The TMP/PE ester was confirmed using gas chromatography (GC-FID), Fourier Transform Infrared Spectroscopy (FTIR) and Nuclear Magnetic Resonance (NMR)

Differentiation of Body Fluid Stains on Fabrics Using External Reflection Fourier Transform Infrared Spectroscopy (FT-IR) and Chemometrics.

Science.gov (United States)

Zapata, Félix; de la Ossa, Ma Ángeles Fernández; García-Ruiz, Carmen

2016-04-01

Body fluids are evidence of great forensic interest due to the DNA extracted from them, which allows genetic identification of people. This study focuses on the discrimination among semen, vaginal fluid, and urine stains (main fluids in sexual crimes) placed on different colored cotton fabrics by external reflection Fourier transform infrared spectroscopy (FT-IR) combined with chemometrics. Semen-vaginal fluid mixtures and potential false positive substances commonly found in daily life such as soaps, milk, juices, and lotions were also studied. Results demonstrated that the IR spectral signature obtained for each body fluid allowed its identification and the correct classification of unknown stains by means of principal component analysis (PCA) and soft independent modeling of class analogy (SIMCA). Interestingly, results proved that these IR spectra did not show any bands due to the color of the fabric and no substance of those present in daily life which were analyzed, provided a false positive. © The Author(s) 2016.

Rational choices for the wavelengths of a two color interferometer

International Nuclear Information System (INIS)

Jobes, F.C.

1995-07-01

If in a two color interferometer for plasma density measurements, the two wavelengths are chosen to have a ratio that is a rational number, and if the signals from each of the wavelengths are multiplied in frequency by the appropriate integer of the rational number and then heterodyned together, the resultant signal will have all effects of component motion nulled out. A phase measurement of this signal will have only plasma density information in it. With CO 2 lasers, it is possible to find suitable wavelength pairs which are close enough to rational numbers to produce an improvement of about 100 in density resolution, compared to standard two color interferometers

[Study on color of thermosetting resin for veneer crown].

Science.gov (United States)

Kamitomai, H

1989-02-01

Based on the viewpoint that stresses the importance of achieving natural colors and forms for veneer crown, four representative kinds of thermosetting resins were investigated colorimetrically in an attempt to clarify the relationship between the thickness and color of resins in opaque, dentin and enamel colors respectively. A spectrophotometer was used to measure the colors, the CIE colorimetric system employed to show the readings, and the CIE 1964 U*V*W* space was utilized to indicate the color differences, with the following results. 1. In the case of dentin, certain specific colors were observed for thickness of 1.3 to 1.8 mm when used alone, but when applied over opaque the range was 0.2 to 0.5 mm lower than when used alone. 2. Enamel resins were grouped into two types according to different color groups, one group similar to achromatic color with low limpidity and the other similar to the dentin color with high limpidity. The former type became more grayer with an increase in thickness when applied over dentin. The latter type showed no difference in color even when the thickness increased. This study has shown that the facing color results vary depending on the color properties of the different resins used. Therefore, it is advisable that careful consideration be given to these differencies in order to achieve the intended color facing.

Investigations of the interactions of peimine and peiminine with human serum albumin by spectroscopic methods and docking studies

International Nuclear Information System (INIS)

Xiao, Dan; Zhang, Lili; Wang, Qing; Lin, Xia; Sun, Jinyu; Li, Hui

2014-01-01

The primary objective of this study is to evaluate the interactions of human serum albumin (HSA) with peimine (PE) and peiminine (PEN) in physiological conditions by fluorescence spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, circular dichroism (CD) spectroscopy, Raman spectroscopy, and molecular modeling. PE and PEN were isolated from Bulbus Fritillariae thunbergii miq. The binding constants K a and the number of binding sites n were calculated at different temperatures. Enthalpy change (ΔH), entropy change (ΔS), and Gibbs free energy change (ΔG) were also determined. The results suggested that quenching of HSA fluorescence by PE and PEN is a static process. Three-dimensional fluorescence, FT-IR, CD, and Raman spectra showed that the binding of PE and PEN to HSA can induce conformational changes in the latter. Moreover, important differences in binding ability were observed between PE and PEN, and PE showed stronger binding affinity to HSA than PEN. -- Highlights: • This paper provides the whole separation and purification process of peimine and peiminine and their detailed structure information. • A comparative study between peimine and peiminine shows the difference of their structure affects their binding ability to HSA. • FT-IR, three-dimensional fluorescence, CD and Raman spectra were used to explain the conformational changes of HSA reasonably. • Time-resolved fluorescence was used to distinguish the quenching mechanisms

Investigations of the interactions of peimine and peiminine with human serum albumin by spectroscopic methods and docking studies

Energy Technology Data Exchange (ETDEWEB)

Xiao, Dan; Zhang, Lili; Wang, Qing; Lin, Xia; Sun, Jinyu; Li, Hui, E-mail: lihuilab@sina.com

2014-02-15

The primary objective of this study is to evaluate the interactions of human serum albumin (HSA) with peimine (PE) and peiminine (PEN) in physiological conditions by fluorescence spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, circular dichroism (CD) spectroscopy, Raman spectroscopy, and molecular modeling. PE and PEN were isolated from Bulbus Fritillariae thunbergii miq. The binding constants K{sub a} and the number of binding sites n were calculated at different temperatures. Enthalpy change (ΔH), entropy change (ΔS), and Gibbs free energy change (ΔG) were also determined. The results suggested that quenching of HSA fluorescence by PE and PEN is a static process. Three-dimensional fluorescence, FT-IR, CD, and Raman spectra showed that the binding of PE and PEN to HSA can induce conformational changes in the latter. Moreover, important differences in binding ability were observed between PE and PEN, and PE showed stronger binding affinity to HSA than PEN. -- Highlights: • This paper provides the whole separation and purification process of peimine and peiminine and their detailed structure information. • A comparative study between peimine and peiminine shows the difference of their structure affects their binding ability to HSA. • FT-IR, three-dimensional fluorescence, CD and Raman spectra were used to explain the conformational changes of HSA reasonably. • Time-resolved fluorescence was used to distinguish the quenching mechanisms.

A compact PE memory for vision chips

Science.gov (United States)

Cong, Shi; Zhe, Chen; Jie, Yang; Nanjian, Wu; Zhihua, Wang

2014-09-01

This paper presents a novel compact memory in the processing element (PE) for single-instruction multiple-data (SIMD) vision chips. The PE memory is constructed with 8 × 8 register cells, where one latch in the slave stage is shared by eight latches in the master stage. The memory supports simultaneous read and write on the same address in one clock cycle. Its compact area of 14.33 μm2/bit promises a higher integration level of the processor. A prototype chip with a 64 × 64 PE array is fabricated in a UMC 0.18 μm CMOS technology. Five types of the PE memory cell structure are designed and compared. The testing results demonstrate that the proposed PE memory architecture well satisfies the requirement of the vision chip in high-speed real-time vision applications, such as 1000 fps edge extraction.

A compact PE memory for vision chips

International Nuclear Information System (INIS)

Shi Cong; Chen Zhe; Yang Jie; Wu Nanjian; Wang Zhihua

2014-01-01

This paper presents a novel compact memory in the processing element (PE) for single-instruction multiple-data (SIMD) vision chips. The PE memory is constructed with 8 × 8 register cells, where one latch in the slave stage is shared by eight latches in the master stage. The memory supports simultaneous read and write on the same address in one clock cycle. Its compact area of 14.33 μm 2 /bit promises a higher integration level of the processor. A prototype chip with a 64 × 64 PE array is fabricated in a UMC 0.18 μm CMOS technology. Five types of the PE memory cell structure are designed and compared. The testing results demonstrate that the proposed PE memory architecture well satisfies the requirement of the vision chip in high-speed real-time vision applications, such as 1000 fps edge extraction. (semiconductor integrated circuits)

Characterization of silicon-oxide interfaces and organic monolayers by IR-UV ellipsometry and FTIR spectroscopy

Science.gov (United States)

Hess, P.; Patzner, P.; Osipov, A. V.; Hu, Z. G.; Lingenfelser, D.; Prunici, P.; Schmohl, A.

2006-08-01

VUV-laser-induced oxidation of Si(111)-(1×1):H, Si(100):H, and a-Si:H at 157 nm (F II laser) in pure O II and pure H IIO atmospheres was studied between 30°C and 250°C. The oxidation process was monitored in real time by spectroscopic ellipsometry (NIR-UV) and FTIR spectroscopy. The ellipsometric measurements could be simulated with a three-layer model, providing detailed information on the variation of the suboxide interface with the nature of the silicon substrate surface. Besides the silicon-dioxide and suboxide layer, a dense, disordered, roughly monolayer thick silicon layer was included, as found previously by molecular dynamics calculations. The deviations from the classical Deal-Grove mechanism and the self-limited growth of the ultrathin dioxide layers (TMS) groups and n-alkylthiol monolayers on gold-coated silicon. The C-H stretching vibrations of the methylene and methyl groups could be identified by FTIR spectroscopy and IR ellipsometry.

UV and VUV characteristics of (YGd)2O3:Eu phosphor particles prepared by spray pyrolysis from polymeric precursors

International Nuclear Information System (INIS)

Kim, E.J.; Kang, Y.C.; Park, H.D.; Ryu, S.K.

2003-01-01

Red-emitting (YGd) 2 O 3 :Eu phosphor particles, with high luminescence efficiency under vacuum ultraviolet (VUV) and ultraviolet (UV) excitation, were prepared by a large-scale spray pyrolysis process. To control the morphology of phosphor particles under severe preparation conditions, spray solution with polymeric precursors were introduced in spray pyrolysis. The prepared (YGd) 2 O 3 :Eu phosphor particles had spherical shape and filled morphology even after post-treatment irrespective of Gd/Y ratio. In the case of solution with polymeric precursors, long polymeric chains formed by esterification reaction in a hot tubular reactor; the droplets turned into viscous gel, which retarded the precipitation of nitrate salts and promoted the volume precipitation of droplets. The brightness of (YGd) 2 O 3 :Eu phosphor particles increased with increasing gadolinium content, and the Gd 2 O 3 :Eu phosphor had the highest luminescence intensity under UV and VUV excitation. The maximum peak intensity of Gd 2 O 3 :Eu phosphor particles under UV and VUV were 118 and 110% of the commercial Y 2 O 3 :Eu phosphor particles, respectively

Modeling human color categorization: Color discrimination and color memory

OpenAIRE

Heskes, T.; van den Broek, Egon; Lucas, P.; Hendriks, Maria A.; Vuurpijl, L.G.; Puts, M.J.H.; Wiegerinck, W.

2003-01-01

Color matching in Content-Based Image Retrieval is done using a color space and measuring distances between colors. Such an approach yields non-intuitive results for the user. We introduce color categories (or focal colors), determine that they are valid, and use them in two experiments. The experiments conducted prove the difference between color categorization by the cognitive processes color discrimination and color memory. In addition, they yield a Color Look-Up Table, which can improve c...

Global Gridded Emission Inventories of Pentabrominated Diphenyl Ether (PeBDE)

Science.gov (United States)

Li, Yi-Fan; Tian, Chongguo; Yang, Meng; Jia, Hongliang; Ma, Jianmin; Li, Dacheng

2010-05-01

Polybrominated diphenyl ethers (PBDEs) are flame retardants widely used in many everyday products such as cars, furniture, textiles, and other electronic equipment. The commercial PBDEs have three major technical mixtures: penta-(PeBDE), octa-(OBDE) and decabromodiphenyl ethers (DeBDE). PeBDE is a mixture of several BDE congeners, such as BDE-47, -99, and -100, and has been included as a new member of persistent organic pollutants (POPs) under the 2009 Stockholm Convention. In order to produce gridded emission inventories of PeBDE on a global scale, information of production, consumption, emission, and physiochemical properties of PeBDE have been searched for published papers, government reports, and internet publications. A methodology to estimate the emissions of PeBDE has been developed and global gridded emission inventories of 2 major congener in PeBDE mixture, BDE-47 and -99, on a 1 degree by 1degree latitude/longitude resolution for 2005 have been compiled. Using these emission inventories as input data, the Canadian Model for Environmental Transport of Organochlorine Pesticides (CanMETOP) model was used to simulate the transport of these chemicals and their concentrations in air were calculated for the year of 2005. The modeled air concentration of BDE-47 and -99 were compared with the monitoring air concentrations of these two congeners in the same year obtained from renowned international/national monitoring programs, such as Global Atmospheric Passive Sampling (GAPS), the Integrated Atmospheric Deposition Network (IADN), and the Chinese POPs Soil and Air Monitoring Program (SAMP), and significant correlations between the modeled results and the monitoring data were found, indicating the high quality of the produced emission inventories of BDE-47 and -99. Keywords: Pentabrominated Diphenyl Ether (PeBDE), Emission Inventories, Global, Model

Study of shifting of recombination zone in multi-emissive layer organic light emitting devices and its effect on color stability

International Nuclear Information System (INIS)

Tyagi, Priyanka; Srivastava, Ritu; Kumar, Arunandan; Tuli, Suneet; Kamalasanan, M.N.

2013-01-01

Color stability in multi-emissive layer organic light emitting devices (Me-OLEDs) has been investigated. Me-OLEDs were based on multiple emitters with a common host CBP doped with three dopants, BCzVBi, Ir(ppy) 3 and Ir(btp) 2 acac for blue, green and red emission. A major variation in CIE coordinates were found from (0.312, 0.294) to (0.236, 0.267) with increase in voltage from 6 to 9 V. This coordinate shift in Me-OLEDs has been attributed to the shifting of recombination zone with increase in voltage. In order to support our experimental observation, the EL spectrum of Me-OLEDs has been expressed as a linear combination of EL intensities of OLEDs with its individual constituting layers as emitters. In this way, the contribution of each layer in the EL spectrum of Me-OLEDs has been evaluated at each voltage. It has been observed from these calculations that the contribution of red emitter decreases from 47% to 33.33% and blue emitter increases from 38% to 51.67% with the increase in voltage from 6 to 9 V. This supports our hypothesis of shifting of recombination zone with the change in voltage. This shifting has been attributed to the field dependency of electron mobility in CBP. Me-OLED with CBP layers between the emitters was fabricated to improve the color stability. Significant improvement in color stability was achieved without changes in current efficiency in Me-OLED with interlayers. Highlights: ► Me-OLEDs have been fabricated by using three primary colors (RGB). ► CIE coordinates of these Me-OLEDs were voltage dependent. ► Analytical fitting has been performed to study the shifting of recombination zone. ► CBP interlayers have been introduced to improve the color stability. ► Color stability has been improved without any change in current efficiency

Au-nanoparticles grafted on plasma treated PE

International Nuclear Information System (INIS)

Svorcik, V.; Chaloupka, A.; Rezanka, P.; Slepicka, P.; Kolska, Z.; Kasalkova, N.; Hubacek, T.; Siegel, J.

2010-01-01

Polyethylene (PE) surface was treated with Ar plasma. Activated surface was grafted from methanol solution of 1,2-ethanedithiol. Then the sample was immersed into freshly prepared colloid solution of Au-nanoparticles. Finally Au layer was sputtered on the samples. Properties of the modified PE were studied using various methods: AFM, EPR, RBS and nanoindentation. It was shown that the plasma treatment results in degradation of polymer chain (AFM) and creation of free radicals by EPR. After grafting with dithiol, the concentration of free radicals declines. The presence of Au and S in the surface layer after the coating with Au-nanoparticles was proved by RBS. Plasma treatment changes PE surface morphology and increases surface roughness, too. Another significant change in surface morphology and roughness was observed after deposition of Au-nanoparticles. Nanoindentation measurements show that the grafting with Au-nanoparticles increases adhesion of subsequently sputtered Au layer.

Modeling human color categorization: Color discrimination and color memory

NARCIS (Netherlands)

Heskes, T.; van den Broek, Egon; Lucas, P.; Hendriks, Maria A.; Vuurpijl, L.G.; Puts, M.J.H.; Wiegerinck, W.

2003-01-01

Color matching in Content-Based Image Retrieval is done using a color space and measuring distances between colors. Such an approach yields non-intuitive results for the user. We introduce color categories (or focal colors), determine that they are valid, and use them in two experiments. The

A new approach to dual-color two-photon microscopy with fluorescent proteins

Directory of Open Access Journals (Sweden)

Rebane Aleks

2010-02-01

Full Text Available Abstract Background Two-photon dual-color imaging of tissues and cells labeled with fluorescent proteins (FPs is challenging because most two-photon microscopes only provide one laser excitation wavelength at a time. At present, methods for two-photon dual-color imaging are limited due to the requirement of large differences in Stokes shifts between the FPs used and their low two-photon absorption (2PA efficiency. Results Here we present a new method of dual-color two-photon microscopy that uses the simultaneous excitation of the lowest-energy electronic transition of a blue fluorescent protein and a higher-energy electronic transition of a red fluorescent protein. Conclusion Our method does not require large differences in Stokes shifts and can be extended to a variety of FP pairs with larger 2PA efficiency and more optimal imaging properties.

Contributions to the FEL2005 conference

Energy Technology Data Exchange (ETDEWEB)

Grimm, O. (comp.)

2005-07-01

The following topics were dealt with: First lasing at 32 nm of the VUV-FEL at DESY, properties of the radiation from VUV-FEL at DESY, accelerator lay out and physics of X-ray free-electron lasers, bunch compression stability dependence on RF parameters, undulator systems and photon diagnostic for the European XFEL project, electron beam characterization at PITZ and the VUV-FEL at DESY, high precision optical synchronization systems for X-ray free electron lasers, optical laser synnchronized for the DESY VUV-FEL for two-color pump probe experiments, properties of the third harmonic of the SASE FEL radiation, detector response and beam line transmission measurements with far-infrared radiation, upgrades of the laser beam-line at PITZ, bunch length measurements using a Martin-Puplett interferometer at the VUV-FEL, next generation synchronization system for the VUV-FEL at DESY, transverse electron beam diagnostics at the VYV-FEL at DESY, the infrared undulator project at the VUV-FEL, misconceptions regarding second harmonic generation in X-ray free-electron lasers, influence of an energy chirp on SASE FEL operation, design considerations for the 4GLS XUV-FEL, broadband single shot spectrometer, commissioning of TTF2 bunch compressors for 20 fs SASE source, observation of femtosecond bunch length using a transverse deflecting structure, measurement of slice-emittance using a transverse deflecting structure, the injector of the VUV-FEL at DESY, spectral decoding electro-optic measurements for longitudinal bunch diagnostics at the DESY VUV-FEL, longitudinal phase space studies at PITZ, modelling the transverse phase space and core emittance studies at PITZ, measurements of thermal emittance for cesium telluride photocathodes at PITZ, status and first results from the upgraded PITZ facility, commissioning of the SPARC movable emittance meter and its first operation at PITZ. (HSI)

Contributions to the FEL2005 conference

International Nuclear Information System (INIS)

Grimm, O.

2005-01-01

The following topics were dealt with: First lasing at 32 nm of the VUV-FEL at DESY, properties of the radiation from VUV-FEL at DESY, accelerator lay out and physics of X-ray free-electron lasers, bunch compression stability dependence on RF parameters, undulator systems and photon diagnostic for the European XFEL project, electron beam characterization at PITZ and the VUV-FEL at DESY, high precision optical synchronization systems for X-ray free electron lasers, optical laser synnchronized for the DESY VUV-FEL for two-color pump probe experiments, properties of the third harmonic of the SASE FEL radiation, detector response and beam line transmission measurements with far-infrared radiation, upgrades of the laser beam-line at PITZ, bunch length measurements using a Martin-Puplett interferometer at the VUV-FEL, next generation synchronization system for the VUV-FEL at DESY, transverse electron beam diagnostics at the VYV-FEL at DESY, the infrared undulator project at the VUV-FEL, misconceptions regarding second harmonic generation in X-ray free-electron lasers, influence of an energy chirp on SASE FEL operation, design considerations for the 4GLS XUV-FEL, broadband single shot spectrometer, commissioning of TTF2 bunch compressors for 20 fs SASE source, observation of femtosecond bunch length using a transverse deflecting structure, measurement of slice-emittance using a transverse deflecting structure, the injector of the VUV-FEL at DESY, spectral decoding electro-optic measurements for longitudinal bunch diagnostics at the DESY VUV-FEL, longitudinal phase space studies at PITZ, modelling the transverse phase space and core emittance studies at PITZ, measurements of thermal emittance for cesium telluride photocathodes at PITZ, status and first results from the upgraded PITZ facility, commissioning of the SPARC movable emittance meter and its first operation at PITZ. (HSI)

On Two Color and CCD Methods for the Determination of Astronomic Position.

Science.gov (United States)

1986-03-14

INTRODUCTION .................................... 2 A. Astroposition Objectives As Related to Two-Color Refractometry .................. 2 B. Results...value for the astronomic longitude and latitude.-_ A. Astroposition Objectives As Related to Two-Color Refractometry The long term objectives consist...The interior of the box was divided into 4 bays containing the telescope, the refractometry optics, the power supplies and the refralctometry

Controlling nonsequential double ionization of Ne with parallel-polarized two-color laser pulses.

Science.gov (United States)

Luo, Siqiang; Ma, Xiaomeng; Xie, Hui; Li, Min; Zhou, Yueming; Cao, Wei; Lu, Peixiang

2018-05-14

We measure the recoil-ion momentum distributions from nonsequential double ionization of Ne by two-color laser pulses consisting of a strong 800-nm field and a weak 400-nm field with parallel polarizations. The ion momentum spectra show pronounced asymmetries in the emission direction, which depend sensitively on the relative phase of the two-color components. Moreover, the peak of the doubly charged ion momentum distribution shifts gradually with the relative phase. The shifted range is much larger than the maximal vector potential of the 400-nm laser field. Those features are well recaptured by a semiclassical model. Through analyzing the correlated electron dynamics, we found that the energy sharing between the two electrons is extremely unequal at the instant of recollison. We further show that the shift of the ion momentum corresponds to the change of the recollision time in the two-color laser field. By tuning the relative phase of the two-color components, the recollision time is controlled with attosecond precision.

Study of micro-phase separation of two polystyrene-based copolymer mixture using the combination of PALS and FT-IR

International Nuclear Information System (INIS)

Jiang, Z.Y.; Jiang, X.Q.; Yang, Y.X.; Huang, Y.J.; Huang, H.B.; Hsia, Y.F.

2005-01-01

Positron annihilation lifetime (PAL) spectroscopy, Fourier transform infrared (FT-IR) and differential scanning calorimetry (DSC) have been applied to study the micro-phase separation in the blends of poly(styrene-co-methylmethacrylate) (SMMA) copolymer and poly(styrene-co-maleic anhydride) (SMA) copolymer. The DSC results indicate that the SMA/SMMA blends are miscible and weak intermolecular interactions exist between SMA and SMMA. The strength of intermolecular interactions to some degree exhibits somewhat non-monotonic variation with increasing of SMA component in the blends. The results of PAL measurement present the blend containing 20 wt% SMA is phase-separated in molecular level, which is interpreted by the results of FT-IR analysis. It was concluded that it is helpful to study the miscibility of polymer blends in molecular level by means of PAL method, accompanied with the requisite measurement of DSC and FT-IR

Digital low level RF control system for the DESY TTF VUV-FEL Linac

International Nuclear Information System (INIS)

Ayvazyan, V.; Choroba, S.; Matyushin, A.; Moeller, G.; Petrosyan, G.; Rehlich, K.; Simrock, S.N.; Vetrov, P.

2005-01-01

In the RF system for the Vacuum Ultraviolet Free Electron Laser (VUV-FEL) Linac each klystron supplies RF power to up to 32 cavities. The superconducting cavities are operated in pulsed mode and high accelerating gradients close to the performance limit. The RF control of the cavity fields to the level of 10 -4 for amplitude and 0.1 degree for phase however presents a significant technical challenge due to the narrow bandwidth of the cavities which results in high sensitivity to perturbations of the resonance frequency by mechanical vibrations (microphonics) and Lorenz force detuning. The VUV-FEL Linac RF control system employs a completely digital feedback system to provide flexibility in the control algorithms, precise calibration of the accelerating field vector-sum, and extensive diagnostics and exception handling capabilities. The RF control algorithm is implemented in DSP (Digital Signal Processor) firmware and DOOCS (Distributed Object Oriented Control System) servers. The RF control system design objectives are discussed. Hardware and software design of the DSP based RF control are presented. (orig.)

Digital low level RF control system for the DESY TTF VUV-FEL Linac

Energy Technology Data Exchange (ETDEWEB)

Ayvazyan, V.; Choroba, S.; Matyushin, A.; Moeller, G.; Petrosyan, G.; Rehlich, K.; Simrock, S.N.; Vetrov, P.

2005-07-01

In the RF system for the Vacuum Ultraviolet Free Electron Laser (VUV-FEL) Linac each klystron supplies RF power to up to 32 cavities. The superconducting cavities are operated in pulsed mode and high accelerating gradients close to the performance limit. The RF control of the cavity fields to the level of 10{sup -4} for amplitude and 0.1 degree for phase however presents a significant technical challenge due to the narrow bandwidth of the cavities which results in high sensitivity to perturbations of the resonance frequency by mechanical vibrations (microphonics) and Lorenz force detuning. The VUV-FEL Linac RF control system employs a completely digital feedback system to provide flexibility in the control algorithms, precise calibration of the accelerating field vector-sum, and extensive diagnostics and exception handling capabilities. The RF control algorithm is implemented in DSP (Digital Signal Processor) firmware and DOOCS (Distributed Object Oriented Control System) servers. The RF control system design objectives are discussed. Hardware and software design of the DSP based RF control are presented. (orig.)

Theoretical evaluation of measurement uncertainties of two-color pyrometry applied to optical diagnostics

International Nuclear Information System (INIS)

Fu Tairan; Cheng Xiaofang; Yang Zangjian

2008-01-01

We present a theoretical analysis of two-color pyrometry applied to optical diagnostics. A two-color pyrometer built with a single CCD is advantageous due to the simple system design. We evaluate the possibility and degree of ill-conditionness on the basis of measurement uncertainties for different measurement approaches of this two-color system. We classify measurement approaches. The corresponding ill-conditionness criterion is established. The greater the criterion value is, the worse the ill-conditioned degree of solution is. So, the optimum choice of measurement approach for the two-color system is achieved through intercomparison of the criterion values. Numerical examples are also given to illustrate this point. The theoretical analysis not only provides an effective way of evaluating different measurement approaches, but also may help us to better understand the influences that determine the choices between wavelength/waveband measurements and calibration/noncalibration modes for temperature and soot distribution

Photo-redox activated drug delivery systems operating under two photon excitation in the near-IR.

Science.gov (United States)

Guardado-Alvarez, Tania M; Devi, Lekshmi Sudha; Vabre, Jean-Marie; Pecorelli, Travis A; Schwartz, Benjamin J; Durand, Jean-Olivier; Mongin, Olivier; Blanchard-Desce, Mireille; Zink, Jeffrey I

2014-05-07

We report the design and synthesis of a nano-container consisting of mesoporous silica nanoparticles with the pore openings covered by "snap-top" caps that are opened by near-IR light. A photo transducer molecule that is a reducing agent in an excited electronic state is covalently attached to the system. Near IR two-photon excitation causes inter-molecular electron transfer that reduces a disulfide bond holding the cap in place, thus allowing the cargo molecules to escape. We describe the operation of the "snap-top" release mechanism by both one- and two-photon activation. This system presents a proof of concept of a near-IR photoredox-induced nanoparticle delivery system that may lead to a new type of photodynamic drug release therapy.

A review of factors affecting the attractiveness of Angola to private equity (PE investments

Directory of Open Access Journals (Sweden)

Estefania Jover

2014-11-01

Full Text Available Angola’s attractiveness to PE investors and the potential to increase PE investments in the country are explored. Primary data were collected using a survey of 18 PE funds that invest or have considered investing in Angola, followed by 10 expert interviews to gain deeper insight into the country’s institutional and economic environment, and its potential for PE investments. It is found that most PE funds are attracted to Angola by its rapid economic growth and high potential returns. The country is also vastly undersupplied, and many key economic sectors are fast developing, presenting exciting opportunities for investors. Nevertheless, PE in Angola remains limited, mainly owing to the difficulty of doing business in Angola, and owing particularly to the unfavourable regulatory environment. There is no regulation or process when it comes to the registration of PE funds in Angola, and any new regulation that applies to foreign investments is marred by unnecessary red tape, making it difficult for the investment to enter the market. Only two funds are authorised to operate in Angola: Fundo de Investimento Privado de Angola (FIPA, and BESA Activ. Streamlining regulation is critical to increasing PE flows to Angola in order to advance the country’s economic and social objectives.

Luminescence mechanism in doubly Gd, Nd-codoped fluoride crystals for VUV scintillators

Czech Academy of Sciences Publication Activity Database

Pejchal, Jan; Fukuda, K.; Babin, Vladimir; Kurosawa, S.; Yokota, Y.; Yoshikawa, A.; Nikl, Martin

2016-01-01

Roč. 169, Jan (2016), s. 682-689 ISSN 0022-2313. [International Conference on Luminescence and Optical Spectroscopy of Condensed Matter /17./. Wroclaw, 13.07.2014-18.07.2014] R&D Projects: GA MŠk(CZ) LH14266 Institutional support: RVO:68378271 Keywords : barium –lutetium–yttrium fluoride * lutetium fluoride * scintillator * VUV luminescence Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.686, year: 2016

Color dependence with horizontal-viewing angle and colorimetric characterization of two displays using different backlighting

Science.gov (United States)

Castro, José J.; Pozo, Antonio M.; Rubiño, Manuel

2013-11-01

In this work we studied the color dependence with a horizontal-viewing angle and colorimetric characterization of two liquid-crystal displays (LCD) using two different backlighting: Cold Cathode Fluorescent Lamps (CCFLs) and light-emitting diodes (LEDs). The LCDs studied had identical resolution, size, and technology (TFT - thin film transistor). The colorimetric measurements were made with the spectroradiometer SpectraScan PR-650 following the procedure recommended in the European guideline EN 61747-6. For each display, we measured at the centre of the screen the chromaticity coordinates at horizontal viewing angles of 0, 20, 40, 60 and 80 degrees for the achromatic (A), red (R), green (G) and blue (B) channels. Results showed a greater color-gamut area for the display with LED backlight, compared with the CCFL backlight, showing a greater range of colors perceptible by human vision. This color-gamut area diminished with viewing angle for both displays. Higher differences between trends for viewing angles were observed in the LED-backlight, especially for the R- and G-channels, demonstrating a higher variability of the chromaticity coordinates with viewing angle. The best additivity was reached by the LED-backlight display (a lower error percentage). LED-backlight display provided better color performance of visualization.

Two-color quark matter: U(1)A restoration, superfluidity, and quarkyonic phase

International Nuclear Information System (INIS)

Brauner, Tomas; Fukushima, Kenji; Hidaka, Yoshimasa

2009-01-01

We discuss the phase structure of quantum chromodynamics (QCD) with two colors and two flavors of light quarks. This is motivated by the increasing interest in the QCD phase diagram as follows: (1) The QCD critical point search has been under intensive dispute and its location and existence suffer from uncertainty of effective U(1) A symmetry restoration. (2) A new phase called quarkyonic matter is drawing theoretical and experimental attention but it is not clear whether it can coexist with diquark condensation. We point out that two-color QCD is nontrivial enough to contain essential ingredients for (1) and (2) both, and most importantly, is a system without the sign problem in numerical simulations on the lattice. We adopt the two-flavor Nambu-Jona-Lasinio model extended with the two-color Polyakov loop and make quantitative predictions that can be tested by lattice simulations.

Temperature measurements with two different IR sensors in a continuous-flow microwave heated system

Directory of Open Access Journals (Sweden)

Jonas Rydfjord

2013-10-01

Full Text Available In a continuous-flow system equipped with a nonresonant microwave applicator we have investigated how to best assess the actual temperature of microwave heated organic solvents with different characteristics. This is non-trivial as the electromagnetic field will influence most traditional methods of temperature measurement. Thus, we used a microwave transparent fiber optic probe, capable of measuring the temperature inside the reactor, and investigated two different IR sensors as non-contact alternatives to the internal probe. IR sensor 1 measures the temperature on the outside of the reactor whilst IR sensor 2 is designed to measure the temperature of the fluid through the borosilicate glass that constitutes the reactor wall. We have also, in addition to the characterization of the before mentioned IR sensors, developed statistical models to correlate the IR sensor reading to a correct value of the inner temperature (as determined by the internal fiber optic probe, thereby providing a non-contact, indirect, temperature assessment of the heated solvent. The accuracy achieved with these models lie well within the range desired for most synthetic chemistry applications.

Υ decay to two charm-quark jets as a probe of the color-octet mechanism

International Nuclear Information System (INIS)

Zhang Yujie; Chao Kuangta

2008-01-01

We calculate the decay rate of bottomonium to two charm-quark jets Υ→cc at the tree level and one-loop level including color-singlet and color-octet bb annihilations. We find that the short-distance coefficient of the color-octet piece is much larger than the color-singlet piece, and that the QCD correction will change the end point behavior of the charm quark jet. The color-singlet piece is strongly affected by the one-loop QCD correction. In contrast, the QCD correction to the color-octet piece is weak. Once the experiment can measure the branching ratio and energy distribution of the two charm-quark jets in the Υ decay, the result can be used to test the color-octet mechanism or give a strong constraint on the color-octet matrix elements.

VUV Spectroscopy of the Sun as a Star

Science.gov (United States)

Kankelborg, Charles; Philip, Judge; Winebarger, Amy R.; Kobayashi, Ken; Smart, Roy

2017-08-01

We describe a new sounding rocket mission to obtain the first high resolution, high quality VUV (100-200 nm) spectrum of the Sun-as-a-star. Our immediate science goal is to understand better the processes of chromospheric and coronal heating. HST data exist for a dozen or so Sun-like stars of a quality already beyond our ability to construct a comparable sun-as-a-star UV spectrum. The solar spectrum we obtain will enable us to understand the nature of magnetic energy dissipation as a Sun-like star evolves, and the dependence of magnetic activity on stellar mass and metallicity. This poster presents the instrument design, scientific prospects, and broader impacts of the proposed mission.

Separation of VUV/UV photons and reactive particles in the effluent of a He/O{sub 2} atmospheric pressure plasma jet

Energy Technology Data Exchange (ETDEWEB)

Schneider, S; Benedikt, J [Coupled plasma-solid state systems, Fakultaet fuer Physik und Astronomie, Ruhr-Universitaet Bochum, Universitaetsstr. 150, 44780 Bochum (Germany); Lackmann, J-W; Narberhaus, F; Bandow, J E [Mikrobiologie, Fakultaet fuer Biologie, Ruhr-Universitaet Bochum, Universitaetsstr. 150, 44780 Bochum (Germany); Denis, B [Institute for Electrical Engineering and Plasma Technology, Ruhr-Universitaet Bochum, Universitaetsstr. 150, 44780 Bochum (Germany)

2011-07-27

Cold atmospheric pressure plasmas can be used for treatment of living tissues or for inactivation of bacteria or biological macromolecules. The treatment is usually characterized by a combined effect of UV and VUV radiation, reactive species and ions. This combination is usually beneficial for the effectiveness of the treatment but it makes the study of fundamental interaction mechanisms very difficult. Here we report on an effective separation of VUV/UV photons and heavy reactive species in the effluent of a microscale atmospheric pressure plasma jet ({mu}-APPJ). The separation is realized by an additional flow of helium gas under well-defined flow conditions, which deflects heavy particles in the effluent without affecting the VUV and UV photons. Both components of the effluent, the photons and the reactive species, can be used separately or in combination for sample treatment. The results of treatment of a model plasma polymer film and vegetative Bacillus subtilis and Escherichia coli cells are shown and discussed. A simple model of the He gas flow and reaction kinetics of oxygen atoms in the gas phase and at the surface is used to provide a better understanding of the processes in the plasma effluent. The new jet modification, called X-Jet for its appearance, will simplify the investigation of interaction mechanisms of atmospheric pressure plasmas with biological samples.

Two-color lattice QCD with staggered quarks

Energy Technology Data Exchange (ETDEWEB)

Scheffler, David

2015-07-20

The study of quantum chromodynamics (QCD) at finite temperature and density provides important contributions to the understanding of strong-interaction matter as it is present e.g. in nuclear matter and in neutron stars or as produced in heavy-ion collision experiments. Lattice QCD is a non-perturbative approach, where equations of motion for quarks and gluons are discretized on a finite space-time lattice. The method successfully describes the behavior of QCD in the vacuum and at finite temperature, however it cannot be applied to finite baryon density due to the fermion sign problem. Various QCD-like theories, that offer to draw conclusions about QCD, allow simulations also at finite densities. In this work we investigate two-color QCD as a popular example of a QCD-like theory free from the sign problem with methods from lattice gauge theory. For the generation of gauge configurations with two dynamical quark flavors in the staggered formalism with the ''rooting trick'' we apply the Rational Hybrid Monte Carlo (RHMC) algorithm. We carry out essential preparatory work for future simulations at finite density. As a start, we concentrate on the calculation of the effective potential for the Polyakov loop, which is an order parameter for the confinement-deconfinement transition, in dependence of the temperature and quark mass. It serves as an important input for effective models of QCD. We obtain the effective potential via the histogram method from local distributions of the Polyakov loop. To study the influence of dynamical quarks on gluonic observables, the simulations are performed with large quark masses and are compared to calculations in the pure gauge theory. In the second part of the thesis we examine aspects of the chiral phase transition along the temperature axis. The symmetry group of chiral symmetry in two-color QCD is enlarged to SU(2N{sub f}). Discretized two-color QCD in the staggered formalism exhibits a chiral symmetry breaking

Near-IR Two-Photon Fluorescent Sensor for K(+) Imaging in Live Cells.

Science.gov (United States)

Sui, Binglin; Yue, Xiling; Kim, Bosung; Belfield, Kevin D

2015-08-19

A new two-photon excited fluorescent K(+) sensor is reported. The sensor comprises three moieties, a highly selective K(+) chelator as the K(+) recognition unit, a boron-dipyrromethene (BODIPY) derivative modified with phenylethynyl groups as the fluorophore, and two polyethylene glycol chains to afford water solubility. The sensor displays very high selectivity (>52-fold) in detecting K(+) over other physiological metal cations. Upon binding K(+), the sensor switches from nonfluorescent to highly fluorescent, emitting red to near-IR (NIR) fluorescence. The sensor exhibited a good two-photon absorption cross section, 500 GM at 940 nm. Moreover, it is not sensitive to pH in the physiological pH range. Time-dependent cell imaging studies via both one- and two-photon fluorescence microscopy demonstrate that the sensor is suitable for dynamic K(+) sensing in living cells.

VUV spectroscopy of pure LiCaAlF6 crystals

International Nuclear Information System (INIS)

Kirm, M.; True, M.; Vielhauer, S.; Zimmerer, G.; Shiran, N.V.; Shpinkov, I.; Spassky, D.; Shimamura, K.; Ichinose, N.

2005-01-01

Reflection, excitation and luminescence spectra of as-grown and X-ray irradiated high-purity LiCaAlF 6 crystals were studied in the temperature range of 10-300 K using synchrotron radiation in VUV. The intrinsic luminescence of samples at 10 K consists of a non-elementary broad band with maximum at 4.4 eV under excitation at 11.45 eV. It is ascribed to the radiative decay of self-trapped excitons. The energy gap is estimated to be 12.65 eV in LiCaAlF 6 . Under interband excitation a red shift of luminescence was observed. The electron-hole recombination leads to the emission peaking at 3.7 eV. The excitation processes and origin of overlapping emissions of LiCaAlF 6 are discussed

Far-IR transparency and dynamic infrared signature control with novel conducting polymer systems

Science.gov (United States)

Chandrasekhar, Prasanna; Dooley, T. J.

1995-09-01

Materials which possess transparency, coupled with active controllability of this transparency in the infrared (IR), are today an increasingly important requirement, for varied applications. These applications include windows for IR sensors, IR-region flat panel displays used in camouflage as well as in communication and sight through night-vision goggles, coatings with dynamically controllable IR-emissivity, and thermal conservation coatings. Among stringent requirements for these applications are large dynamic ranges (color contrast), 'multi-color' or broad-band characteristics, extended cyclability, long memory retention, matrix addressability, small area fabricability, low power consumption, and environmental stability. Among materials possessing the requirements for variation of IR signature, conducting polymers (CPs) appear to be the only materials with dynamic, actively controllable signature and acceptable dynamic range. Conventional CPs such as poly(alkyl thiophene), poly(pyrrole) or poly(aniline) show very limited dynamic range, especially in the far-IR, while also showing poor transparency. We have developed a number of novel CP systems ('system' implying the CP, the selected dopant, the synthesis method, and the electrolyte) with very wide dynamic range (up to 90% in both important IR regions, 3 - 5 (mu) and 8 - 12 (mu) ), high cyclability (to 105 cycles with less than 10% optical degradation), nearly indefinite optical memory retention, matrix addressability of multi-pixel displays, very wide operating temperature and excellent environmental stability, low charge capacity, and processability into areas from less than 1 mm2 to more than 100 cm2. The criteria used to design and arrive at these CP systems, together with representative IR signature data, are presented in this paper.

Secretoneurin and PE-11 immunoreactivity in the human dental pulp.

Science.gov (United States)

Steiner, René; Fischer-Colbrie, Reiner; Bletsa, Athanasia; Laimer, Johannes; Troger, Josef

2018-02-01

To explore whether there are differences in the concentration of the secretogranin II-derived peptide secretoneurin and the chromogranin B-derived peptide PE-11 between the healthy and inflamed human dental pulps. Furthermore, colocalization studies with calcitonin gene-related peptide were performed to confirm the sensory origin of the peptidergic nerves in the dental pulp. The concentrations of secretoneurin and PE-11 were determined by highly sensitive radioimmunoassays in extracts of dental pulps, the molecular form of secretoneurin immunoreactivities by RP-HPLC with subsequent radioimmunoassay and colocalization studies with calcitonin gene-related peptide were performed by double immunofluorescence. Only secretoneurin but not PE-11 was detectable by radioimmunoassays whereas nerve fibers could be made visible for both secretoneurin and PE-11. Furthermore, there was a full colocalization of secretoneurin and PE-11 with calcitonin gene-related peptide in immunohistochemical experiments. There were no differences in the concentration of secretoneurin between the healthy and inflamed human dental pulp and moreover, the characterization of the secretoneurin immunoreactivities revealed that only authentic secretoneurin was detected with the secretoneurin antibody. There is unequivocal evidence that secretoneurin and PE-11 are constituents of the sensory innervation of the human dental pulp and although not exclusively but are yet present in unmyelinated C-fibers which transmit predominantly nociceptive impulses. Secretoneurin might be involved in local effector functions as well, particularly in neurogenic inflammation, given that this is the case despite of unaltered levels in inflamed tissue. Copyright © 2017 Elsevier Ltd. All rights reserved.

The Devil’s Colors: A Comparative Study of French and Nigerian Folktales

Directory of Open Access Journals (Sweden)

Françoise Ugochukwu

2006-10-01

Full Text Available This study, largely based on five separate published collections, compares French and Nigerian folktales––focusing mainly on French Dauphiné and Nigerian Igboland––to consider the role color plays in encounters with supernatural characters from diverse color backgrounds. A study in black, white/red, and green, the paper compares the naming of colors in the two languages and illustrates their usage as a tool to communicate color-coded values. Nigeria’s history, religious beliefs, and language development offer additional clues to what at first appears to be fundamental differences in cultural approach. Attempting to trace the roots of this color-coding, the study also considers the impact of colonization on oral literature and traditional art forms.

VUV Fourier-transform absorption study of the Lyman and Werner bands in D2

Science.gov (United States)

de Lange, Arno; Dickenson, Gareth D.; Salumbides, Edcel J.; Ubachs, Wim; de Oliveira, Nelson; Joyeux, Denis; Nahon, Laurent

2012-06-01

An extensive survey of the D2 absorption spectrum has been performed with the high-resolution VUV Fourier-transform spectrometer employing synchrotron radiation. The frequency range of 90 000-119 000 cm-1 covers the full depth of the potential wells of the B sideset{^1}{+u}{Σ}, B^' } sideset{^1}{+u}{Σ}, and C 1Πu electronic states up to the D(1s) + D(2ℓ) dissociation limit. Improved level energies of rovibrational levels have been determined up to respectively v = 51, v = 13, and v = 20. Highest resolution is achieved by probing absorption in a molecular gas jet with slit geometry, as well as in a liquid helium cooled static gas cell, resulting in line widths of ≈0.35 cm-1. Extended calibration methods are employed to extract line positions of D2 lines at absolute accuracies of 0.03 cm-1. The D 1Πu and B^' ' } sideset{^1}{+u}{Σ} electronic states correlate with the D(1s) + D(3ℓ) dissociation limit, but support a few vibrational levels below the second dissociation limit, respectively, v = 0-3 and v = 0-1, and are also included in the presented study. The complete set of resulting level energies is the most comprehensive and accurate data set for D2. The observations are compared with previous studies, both experimental and theoretical.

Processing of Color Words Activates Color Representations

Science.gov (United States)

Richter, Tobias; Zwaan, Rolf A.

2009-01-01

Two experiments were conducted to investigate whether color representations are routinely activated when color words are processed. Congruency effects of colors and color words were observed in both directions. Lexical decisions on color words were faster when preceding colors matched the color named by the word. Color-discrimination responses…

Experimental Study on Color Durability of Color Asphalt Pavement

Science.gov (United States)

Ning, Shi; Huan, Su

2017-06-01

Aiming at the poor Color durability and the lack of research on Color asphalt pavement, spraying an anti-tire trace seal resin emulsion on the surface, a Color durable asphalt pavement was proposed. After long-term rolling and long-term aging test, the Color durability was evaluated by RGB function in Photoshop and trace residue rate formula. Test results proved that the Evaluation method was simple and effective. After long-term rolling, the Color of the road surface tends to a constant value. Spraying the emulsion on the road surface can resist tire traces. After long-term aging test, the resistance to tire traces was increased by 26.6% compared with the conventional type, while the former was 44.1% higher than the latter without long-term aging. The Color durable asphalt pavement can effectively improve the ability of Color asphalt pavement to resist tire traces, and significantly improve the Color durability of Color asphalt pavement.

NeuroSeek dual-color image processing infrared focal plane array

Science.gov (United States)

McCarley, Paul L.; Massie, Mark A.; Baxter, Christopher R.; Huynh, Buu L.

1998-09-01

Several technologies have been developed in recent years to advance the state of the art of IR sensor systems including dual color affordable focal planes, on-focal plane array biologically inspired image and signal processing techniques and spectral sensing techniques. Pacific Advanced Technology (PAT) and the Air Force Research Lab Munitions Directorate have developed a system which incorporates the best of these capabilities into a single device. The 'NeuroSeek' device integrates these technologies into an IR focal plane array (FPA) which combines multicolor Midwave IR/Longwave IR radiometric response with on-focal plane 'smart' neuromorphic analog image processing. The readout and processing integrated circuit very large scale integration chip which was developed under this effort will be hybridized to a dual color detector array to produce the NeuroSeek FPA, which will have the capability to fuse multiple pixel-based sensor inputs directly on the focal plane. Great advantages are afforded by application of massively parallel processing algorithms to image data in the analog domain; the high speed and low power consumption of this device mimic operations performed in the human retina.

A new instrument of VUV laser desorption/ionization mass spectrometry imaging with micrometer spatial resolution and low level of molecular fragmentation.

Science.gov (United States)

Wang, Jia; Liu, Feng; Mo, Yuxiang; Wang, Zhaoying; Zhang, Sichun; Zhang, Xinrong

2017-11-01

Mass spectrometry imaging (MSI) has important applications in material research, biology, and medicine. The MSI method based on UV laser desorption/ionization (UVLDI) can obtain images of intact samples, but has a high level of molecular fragmentation. In this work, we report a new MSI instrument that uses a VUV laser (125.3 nm) as a desorption/ionization source to exploit its advantages of high single photon energy and small focus size. The new instrument was tested by the mass spectra of Nile red and FGB (Fibrinogen beta chain) samples and mass spectrometric images of a fly brain section. For the tested samples, the VUVDI method offers lower levels of molecular fragmentations and higher sensitivities than those of the UVLDI method and second ion mass spectrometry imaging method using a Bi 3 + beam. The ablation crater produced by the focused VUV laser on a quartz plate has an area of 10 μm 2 . The VUV laser is prepared based on the four-wave mixing method using three collimated laser beams and a heated Hg cell.

A new instrument of VUV laser desorption/ionization mass spectrometry imaging with micrometer spatial resolution and low level of molecular fragmentation

Science.gov (United States)

Wang, Jia; Liu, Feng; Mo, Yuxiang; Wang, Zhaoying; Zhang, Sichun; Zhang, Xinrong

2017-11-01

Mass spectrometry imaging (MSI) has important applications in material research, biology, and medicine. The MSI method based on UV laser desorption/ionization (UVLDI) can obtain images of intact samples, but has a high level of molecular fragmentation. In this work, we report a new MSI instrument that uses a VUV laser (125.3 nm) as a desorption/ionization source to exploit its advantages of high single photon energy and small focus size. The new instrument was tested by the mass spectra of Nile red and FGB (Fibrinogen beta chain) samples and mass spectrometric images of a fly brain section. For the tested samples, the VUVDI method offers lower levels of molecular fragmentations and higher sensitivities than those of the UVLDI method and second ion mass spectrometry imaging method using a Bi3+ beam. The ablation crater produced by the focused VUV laser on a quartz plate has an area of 10 μm2. The VUV laser is prepared based on the four-wave mixing method using three collimated laser beams and a heated Hg cell.

VUV photoionization and dissociative photoionization of the prebiotic molecule acetyl cyanide: Theory and experiment

International Nuclear Information System (INIS)

Bellili, A.; Hochlaf, M.; Schwell, M.; Bénilan, Y.; Fray, N.; Gazeau, M.-C.; Mogren Al-Mogren, M.; Guillemin, J.-C.; Poisson, L.

2014-01-01

The present combined theoretical and experimental investigation concerns the single photoionization of gas-phase acetyl cyanide and the fragmentation pathways of the resulting cation. Acetyl cyanide (AC) is inspired from both the chemistry of cyanoacetylene and the Strecker reaction which are thought to be at the origin of medium sized prebiotic molecules in the interstellar medium. AC can be formed by reaction from cyanoacetylene and water but also from acetaldehyde and HCN or the corresponding radicals. In view of the interpretation of vacuum ultraviolet (VUV) experimental data obtained using synchrotron radiation, we explored the ground potential energy surface (PES) of acetyl cyanide and of its cation using standard and recently implemented explicitly correlated methodologies. Our PES covers the regions of tautomerism (between keto and enol forms) and of the lowest fragmentation channels. This allowed us to deduce accurate thermochemical data for this astrobiologically relevant molecule. Unimolecular decomposition of the AC cation turns out to be very complex. The implications for the evolution of prebiotic molecules under VUV irradiation are discussed

VUV photoionization and dissociative photoionization of the prebiotic molecule acetyl cyanide: Theory and experiment

Energy Technology Data Exchange (ETDEWEB)

Bellili, A.; Hochlaf, M., E-mail: hochlaf@univ-mlv.fr, E-mail: martin.schwell@lisa.u-pec.fr [Laboratoire Modélisation et Simulation Multi Echelle, MSME UMR 8208 CNRS, Université Paris-Est, 5 bd Descartes, 77454 Marne-la-Vallée (France); Schwell, M., E-mail: hochlaf@univ-mlv.fr, E-mail: martin.schwell@lisa.u-pec.fr; Bénilan, Y.; Fray, N.; Gazeau, M.-C. [Laboratoire Interuniversitaire des Systèmes Atmosphériques (LISA), UMR 7583 CNRS, Institut Pierre et Simon Laplace, Universités Paris-Est Créteil et Paris Diderot, 61 Avenue du Général de Gaulle, 94010 Créteil (France); Mogren Al-Mogren, M. [Chemistry Department, Faculty of Science, King Saud University, P.O. Box 2455, Riyadh 11451 (Saudi Arabia); Guillemin, J.-C. [Institut des Sciences Chimiques de Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, UMR 6226, Allée de Beaulieu, CS 50837, 35708 Rennes Cedex 7 (France); Poisson, L. [Laboratoire Francis Perrin, CNRS URA 2453, CEA, IRAMIS, Laboratoire Interactions Dynamique et Lasers, Bât 522, F-91191 Gif/Yvette (France)

2014-10-07

The present combined theoretical and experimental investigation concerns the single photoionization of gas-phase acetyl cyanide and the fragmentation pathways of the resulting cation. Acetyl cyanide (AC) is inspired from both the chemistry of cyanoacetylene and the Strecker reaction which are thought to be at the origin of medium sized prebiotic molecules in the interstellar medium. AC can be formed by reaction from cyanoacetylene and water but also from acetaldehyde and HCN or the corresponding radicals. In view of the interpretation of vacuum ultraviolet (VUV) experimental data obtained using synchrotron radiation, we explored the ground potential energy surface (PES) of acetyl cyanide and of its cation using standard and recently implemented explicitly correlated methodologies. Our PES covers the regions of tautomerism (between keto and enol forms) and of the lowest fragmentation channels. This allowed us to deduce accurate thermochemical data for this astrobiologically relevant molecule. Unimolecular decomposition of the AC cation turns out to be very complex. The implications for the evolution of prebiotic molecules under VUV irradiation are discussed.

Laser-induced plasmas in air studied using two-color interferometry

International Nuclear Information System (INIS)

Yang, Zefeng; Wu, Jian; Li, Xingwen; Han, Jiaxun; Jia, Shenli; Qiu, Aici; Wei, Wenfu

2016-01-01

Temporally and spatially resolved density profiles of Cu atoms, electrons, and compressed air, from laser-induced copper plasmas in air, are measured using fast spectral imaging and two-color interferometry. From the intensified CCD images filtered by a narrow-band-pass filter centered at 515.32 nm, the Cu atoms expansion route is estimated and used to determine the position of the fracture surface between the Cu atoms and the air. Results indicate that the Cu atoms density at distances closer to the target (0–0.4 mm) is quite low, with the maximum density appearing at the edge of the plasma's core being ∼4.6 × 10"2"4" m"−"3 at 304 ns. The free electrons are mainly located in the internal region of the plume, which is supposed to have a higher temperature. The density of the shock wave is (4–6) × 10"2"5" m"−"3, corresponding to air compression of a factor of 1.7–2.5.

Laser-induced plasmas in air studied using two-color interferometry

Energy Technology Data Exchange (ETDEWEB)

Yang, Zefeng; Wu, Jian, E-mail: jxjawj@mail.xjtu.edu.cn; Li, Xingwen; Han, Jiaxun; Jia, Shenli; Qiu, Aici [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Shaanxi 710049 (China); Wei, Wenfu [School of Electrical Engineering, Southwest Jiaotong University, Chengdu 610031 (China)

2016-08-15

Temporally and spatially resolved density profiles of Cu atoms, electrons, and compressed air, from laser-induced copper plasmas in air, are measured using fast spectral imaging and two-color interferometry. From the intensified CCD images filtered by a narrow-band-pass filter centered at 515.32 nm, the Cu atoms expansion route is estimated and used to determine the position of the fracture surface between the Cu atoms and the air. Results indicate that the Cu atoms density at distances closer to the target (0–0.4 mm) is quite low, with the maximum density appearing at the edge of the plasma's core being ∼4.6 × 10{sup 24 }m{sup −3} at 304 ns. The free electrons are mainly located in the internal region of the plume, which is supposed to have a higher temperature. The density of the shock wave is (4–6) × 10{sup 25 }m{sup −3}, corresponding to air compression of a factor of 1.7–2.5.

THE CONTRIBUTION OF TP-AGB STARS TO THE MID-INFRARED COLORS OF NEARBY GALAXIES

International Nuclear Information System (INIS)

Chisari, Nora E.; Kelson, Daniel D.

2012-01-01

We study the mid-infrared color space of 30 galaxies from the Spitzer Infrared Nearby Galaxies Survey (SINGS) survey for which Sloan Digital Sky Survey data are also available. We construct two-color maps for each galaxy and compare them to results obtained from combining Maraston evolutionary synthesis models, galactic thermally pulsating asymptotic giant branch (TP-AGB) colors, and smooth star formation histories. For most of the SINGS sample, the spatially extended mid-IR emission seen by Spitzer in normal galaxies is consistent with our simple model in which circumstellar dust from TP-AGB stars dominates at 8 and 24 μm. There is a handful of exceptions that we identify as galaxies that have high star formation rates presumably with star formation histories that cannot be assumed to be smooth, or anemic galaxies, which were depleted of their H I at some point during their evolution and have very low ongoing star formation rates.

THE CONTRIBUTION OF TP-AGB STARS TO THE MID-INFRARED COLORS OF NEARBY GALAXIES

Energy Technology Data Exchange (ETDEWEB)

Chisari, Nora E. [Department of Astrophysical Sciences, Princeton University, 4 Ivy Lane, Princeton, NJ 08544 (United States); Kelson, Daniel D., E-mail: nchisari@astro.princeton.edu [Observatories of the Carnegie Institution of Science, 813 Santa Barbara St., Pasadena, CA 91101 (United States)

2012-07-10

We study the mid-infrared color space of 30 galaxies from the Spitzer Infrared Nearby Galaxies Survey (SINGS) survey for which Sloan Digital Sky Survey data are also available. We construct two-color maps for each galaxy and compare them to results obtained from combining Maraston evolutionary synthesis models, galactic thermally pulsating asymptotic giant branch (TP-AGB) colors, and smooth star formation histories. For most of the SINGS sample, the spatially extended mid-IR emission seen by Spitzer in normal galaxies is consistent with our simple model in which circumstellar dust from TP-AGB stars dominates at 8 and 24 {mu}m. There is a handful of exceptions that we identify as galaxies that have high star formation rates presumably with star formation histories that cannot be assumed to be smooth, or anemic galaxies, which were depleted of their H I at some point during their evolution and have very low ongoing star formation rates.

A VUV prism spectrometer for RICH radiator refractometry

CERN Document Server

Moyssides, P G; Fokitis, E

2000-01-01

A prism spectrometer has been developed to operate in the VUV wavelength range from 120 to 200 nm. It can be used as a pre- disperser in conjunction with a Fabry-Perot based gas refractometer. This instrument has also been used to measure the refractive index of the liquid radiator C/sub 6/F/sub 14/ in various spectral lines. This radiator is used in the RICH detectors of the DELPHI experiment and has been proposed for ALICE, and LHCb experiments. The spectral resolution of the system is improved as the wavelength decreases and the data are consistent with a wavelength accuracy about 0.4 nm at 140 nm. The results for the dispersion curve of the above liquid are presented. (17 refs).

VUV study of impurity generation during ICRF heating experiments on the Alcator C tokamak

International Nuclear Information System (INIS)

Manning, H.L.

1986-06-01

A 2.2 meter grazing incidence VUV monochromator has been converted into a time-resolving spectrograph by the addition of a new detector system, based on a microchannel plate image intensifier linked to a 1024-element linear photodiode array. The system covers the wavelength range 15 to 1200 A (typically 40 A at a time) with resolution of up to .3 A FWHM. Time resolution is selectable down to 0.5 msec. The system sensitivity was absolutely calibrated below 150 A by a soft x-ray calibration facility. The spectrograph was installed on the Alcator C tokamak at MIT to monitor plasma impurity emission. There, cross-calibration with a calibrated EUV monochromator was performed above 400 A. Calibration results, system performance characteristics, and data from Alcator C are presented. Observations of impurity behavior are presented from a series of ICRF heating experiments (180 MHz, 50 to 400 kW) performed on the Alcator C tokamak, using graphite limiters and stainless steel antenna Faraday shields

[Factors associated with the consumption of school meals by Brazilian adolescents: results of the PeNSE survey 2012].

Science.gov (United States)

Locatelli, Nathália Tarossi; Canella, Daniela Silva; Bandoni, Daniel Henrique

2017-05-18

The aim was to study the association between socio-demographic and routine dietary variables and consumption of school meals by adolescents enrolled in public schools in Brazil. The study used data used from the National School Health Survey (PeNSE) 2012. To assess differences between schoolchildren based on whether or not they ate school meals, the study used Pearson's chi-square test, and associations were analyzed with univariate and multivariate Poisson regression models. Of the 86,660 students included in the study, 22.8% eat school meals. Higher consumption of school meals is associated with male gender, brown skin color, residence outside state capitals, working, and low maternal schooling, for those that ate breakfast and lunch with their parents. The findings are relevant for planning strategies to encourage consumption of school meals.

Segregation to grain boundaries in nimonic PE16 superalloy

International Nuclear Information System (INIS)

Nettleship, D.J.; Wild, R.K.

1990-01-01

Nimonic PE16 alloy is a nickel-based superalloy containing 34 wt.% iron and 16wt.% chromium with additions of molybdenum, titanium and aluminium. It is used in the fuel assembly of the UK advanced gas-cooled reactors (AGR). This component supports significant loads in service and its mechanical integrity is therefore of paramount importance. Mechanical properties may be influenced by the grain size and grain boundary composition, both of which can themselves alter during service. Scanning Auger microscopy is a well-established method for investigating grain boundaries, and has now been applied to the study of PE16. In order to expose PE16 grain boundary surfaces it is necessary to hydrogen charge samples and fracture by pulling in tension at a slow strain rate within the ultra-high vacuum chamber of the Auger microprobe. A series of casts of nimonic PE16 alloy that have received a range of thermal ageing treatments have been fractured in an intergranular manner and the grain boundary composition determined. Segregation of trace and minority elements, particularly Mo and P, has been detected at grain boundaries. Significant variations between different as-manufactured casts were observed, whilst ageing brought about the growth of chromium-rich particles on the grain boundaries. Ductile fracture in PE16 followed a path through Ti(C, N) particles. Many of these particles incorporated large amounts of sulphur. (author)

The effect of solid content on silylated-γ-AI2O3/PVDF-HFP-coated PE separators for lithium secondary battery

International Nuclear Information System (INIS)

Im, Jong Su; Sohn, Joon Yong; Shin, Jun Hwa; Nho, Young Chang; Kim, Jeong Soo

2009-01-01

Several PVDF-HFP/silylated γ-AI 2 O 3 -coated PE (polyethylene) separators with various solidities (various compositions of PVDF-HFP/silylated γ-AI 2 O 3 ) were prepared by a dip-coating of PE separators in PVDF-HFP/silylated γ-AI 2 O 3 /acetone mixtures. FT-IR spectroscopy was used to confirm the chemical reactions between silane coupling agent and γ-AI 2 O 3 . The SEM images of the coated separators showed that various morphologies could be produced by changing the composition of total contents of binder and solid contents. The effects of composition in inorganic material (silane coupling agent-treated γ-AI 2 O 3 ) and binder (PVDF-HFP) on the physio-chemical properties of the prepared separators such as liquid electrolyte uptake, and ion conductivity were investigated and reported in this paper

Flamenco guitarist Paco Peña tours CERN

CERN Multimedia

Pauline Gagnon

2013-01-01

CERN continues to attract a wide variety of visitors. On 5 June, it was the turn of renowned flamenco guitarist Paco Peña. With a broad interest in science, Peña was here to celebrate his 60th birthday, accompanied by friends David Ashton and Chrissie Twigg, and his wife Karin.     Paco Peña during his visit to ATLAS. Paco Peña’s most famous compositions include Misa Flamenca, a Flamenco Mass, and Requiem for the Earth. In 1997, he was named Oficial de la Cruz de la Orden del Mérito Civil by King Juan Carlos of Spain. "This is truly amazing!" said Peña after seeing the ATLAS detector. His wife confessed that she had never seen him take so many pictures. The group asked numerous questions during their visit. It is not always easy to impress world travellers, but the ATLAS detector did the trick.

Two-color QCD with non-zero chiral chemical potential

Energy Technology Data Exchange (ETDEWEB)

Braguta, V.V. [Institute for High Energy Physics NRC “Kurchatov Institute' ,142281 Protvino (Russian Federation); Far Eastern Federal University, School of Biomedicine,690950 Vladivostok (Russian Federation); Goy, V.A. [Far Eastern Federal University, School of Natural Sciences,690950 Vladivostok (Russian Federation); Ilgenfritz, E.M. [Joint Institute for Nuclear Research,BLTP, 141980 Dubna (Russian Federation); Kotov, A.Yu. [Institute of Theoretical and Experimental Physics,117259 Moscow (Russian Federation); Molochkov, A.V. [Far Eastern Federal University, School of Biomedicine,690950 Vladivostok (Russian Federation); Müller-Preussker, M.; Petersson, B. [Humboldt-Universität zu Berlin, Institut für Physik,12489 Berlin (Germany)

2015-06-16

The phase diagram of two-color QCD with non-zero chiral chemical potential is studied by means of lattice simulation. We focus on the influence of a chiral chemical potential on the confinement/deconfinement phase transition and the breaking/restoration of chiral symmetry. The simulation is carried out with dynamical staggered fermions without rooting. The dependences of the Polyakov loop, the chiral condensate and the corresponding susceptibilities on the chiral chemical potential and the temperature are presented. The critical temperature is observed to increase with increasing chiral chemical potential.

Ring ductility of irradiated Inconel 706 and Nimonic PE16

International Nuclear Information System (INIS)

Huang, F.H.; Fish, R.L.

1984-01-01

The tensile ductility of fast neutron-irradiated, precipitation-hardened alloys Inconel 706 and Nimonic PE16 has been observed to be very low for certain test conditions. Explanations for the low ductility behavior have been sought by examination of broken tensile specimens with microscopy and other similar techniques. A ring compression test provides a method of evaluating the ductility of irradiated cladding specimens. Unlike the conventional uniaxial tensile testing in which the tensile specimen is deformed uniformly, the ring specimen is subjected to localized bending where the crack is initiated. The ductility can be estimated through an analysis of the bending of a ring in terms of strain hardening. Ring sections from irradiated, solution-treated Inconel 706 and Nimonic PE16 were compressed in the diametral direction to provide load-deflection records over a wide range of irradiation and test temperatures. Results showed that ductility in both alloys decreased with increasing test temperatures. The poorest ductility was exhibited at different irradiation temperatures in the two alloys - near 550 0 C for PE16 and 460 to 520 0 C for Inconel 706. The ring ductility data indicate that the grain boundary strength is a major factor in controlling the ductility of the PE16 alloy

EFFECT OF ARTIFICIAL WEATHERING ON WOOD LAMINATES COLOR TREATED WITH TWO FINISHING PRODUCTS

Directory of Open Access Journals (Sweden)

Thais Jacob Mendes

2016-03-01

Full Text Available Weathering is one of the main reasons for the degradation of wood, especially its color. The application of finishes minimizes these effects. This study aimed to monitor the effect of artificial weathering on wood veneer of the species cumaru (Dipteryx odorata and pau marfim (Balfourodendron riedelianum with two finishes, the marine varnish and Cetol, with monitoring using a spectrophotometer. The samples were subjected to cycles of exposure to weathering for 20, 40, 52, 76, 124, 226, 430, 838 and 960 hours. The colorimetric parameters (L*, a*, b*, C and h* were measured before treatment, after application of the products and during the weathering time intervals. The application of finishes darkened veneer of cumaru wood and pau marfim in nature. However, in higher weathering times, both species returned to a lighter color, and even became lighter than the natural wood. The use of Cetol was more efficient, giving greater stability in the conservation of wood color of the species studied.

Two-Magnon Raman Scattering and Pseudospin-Lattice Interactions in Sr_{2}IrO_{4} and Sr_{3}Ir_{2}O_{7}.

Science.gov (United States)

Gretarsson, H; Sung, N H; Höppner, M; Kim, B J; Keimer, B; Le Tacon, M

2016-04-01

We have used Raman scattering to investigate the magnetic excitations and lattice dynamics in the prototypical spin-orbit Mott insulators Sr_{2}IrO_{4} and Sr_{3}Ir_{2}O_{7}. Both compounds exhibit pronounced two-magnon Raman scattering features with different energies, line shapes, and temperature dependencies, which in part reflect the different influence of long-range frustrating exchange interactions. Additionally, we find strong Fano asymmetries in the line shapes of low-energy phonon modes in both compounds, which disappear upon cooling below the antiferromagnetic ordering temperatures. These unusual phonon anomalies indicate that the spin-orbit coupling in Mott-insulating iridates is not sufficiently strong to quench the orbital dynamics in the paramagnetic state.

HOMA1-IR and HOMA2-IR indexes in identifying insulin resistance and metabolic syndrome - Brazilian Metabolic Syndrome Study (BRAMS)

OpenAIRE

Geloneze, B; Vasques, ACJ; Stabe, CFC; Pareja, JC; Rosado, LEFPD; de Queiroz, EC; Tambascia, MA

2009-01-01

Objective: To investigate cut-off values for HOMA1-IR and HOMA2-IR to identify insulin resistance (IR) and metabolic syndrome (MS), and to assess the association of the indexes with components of the MS. Methods: Nondiabetic subjects from the Brazilian Metabolic Syndrome Study were studied (n = 1,203, 18 to 78 years). The cut-off values for IR were determined from the 9011 percentile in the healthy group (n = 297) and, for MS, a ROC curve was generated for the total sample. Results: In the he...

Combined theoretical and experimental study of the valence, Rydberg, and ionic states of chlorobenzene

Energy Technology Data Exchange (ETDEWEB)

Palmer, Michael H., E-mail: m.h.palmer@ed.ac.uk; Ridley, Trevor, E-mail: tr01@staffmail.ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@shu.edu.cn, E-mail: alberto.baiardi@sns.it, E-mail: kipeters@wsu.edu [School of Chemistry, University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh EH9 3FJ, Scotland (United Kingdom); Vrønning Hoffmann, Søren, E-mail: tr01@staffmail.ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@shu.edu.cn, E-mail: alberto.baiardi@sns.it, E-mail: kipeters@wsu.edu; Jones, Nykola C., E-mail: tr01@staffmail.ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@shu.edu.cn, E-mail: alberto.baiardi@sns.it, E-mail: kipeters@wsu.edu [ISA, Department of Physics and Astronomy, Aarhus University, Ny Munkegade 120, DK-8000 Aarhus C (Denmark); Coreno, Marcello, E-mail: tr01@staffmail.ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@shu.edu.cn, E-mail: alberto.baiardi@sns.it, E-mail: kipeters@wsu.edu [CNR-ISM, Basovizza Area Science Park, 1-34149 Trieste (Italy); De Simone, Monica, E-mail: tr01@staffmail.ed.ac.uk, E-mail: vronning@phys.au.dk, E-mail: nykj@phys.au.dk, E-mail: marcello.coreno@elettra.eu, E-mail: desimone@iom.cnr.it, E-mail: malgorzata.biczysko@shu.edu.cn, E-mail: alberto.baiardi@sns.it, E-mail: kipeters@wsu.edu [CNR-IOM Laboratorio TASC, Trieste (Italy); Grazioli, Cesare [CNR-IOM Laboratorio TASC, Trieste (Italy); Department of Chemical and Pharmaceutical Sciences, University of Trieste, Trieste (Italy); Zhang, Teng [Department of Physics and Astronomy, University of Uppsala, Uppsala (Sweden); and others

2016-03-28

New photoelectron (PE) and ultra violet (UV) and vacuum UV (VUV) spectra have been obtained for chlorobenzene by synchrotron study with higher sensitivity and resolution than previous work and are subjected to detailed analysis. In addition, we report on the mass-resolved (2 + 1) resonance enhanced multiphoton ionization (REMPI) spectra of a jet-cooled sample. Both the VUV and REMPI spectra have enabled identification of a considerable number of Rydberg states for the first time. The use of ab initio calculations, which include both multi-reference multi-root doubles and singles configuration interaction (MRD-CI) and time dependent density functional theoretical (TDDFT) methods, has led to major advances in interpretation of the vibrational structure of the ionic and electronically excited states. Franck-Condon (FC) analyses of the PE spectra, including both hot and cold bands, indicate much more complex envelopes than previously thought. The sequence of ionic states can be best interpreted by our multi-configuration self-consistent field computations and also by comparison of the calculated vibrational structure of the B and C ionic states with experiment; these conclusions suggest that the leading sequence is the same as that of iodobenzene and bromobenzene, namely: X{sup 2}B{sub 1}(3b{sub 1}{sup −1}) < A{sup 2}A{sub 2}(1a{sub 2}{sup −1}) < B{sup 2}B{sub 2}(6b{sub 2}{sup −1}) < C{sup 2}B{sub 1}(2b{sub 1}{sup −1}). The absorption onset near 4.6 eV has been investigated using MRD-CI and TDDFT calculations; the principal component of this band is {sup 1}B{sub 2} and an interpretation based on the superposition of FC and Herzberg-Teller contributions has been performed. The other low-lying absorption band near 5.8 eV is dominated by a {sup 1}A{sub 1} state, but an underlying weak {sup 1}B{sub 1} state (πσ{sup ∗}) is also found. The strongest band in the VUV spectrum near 6.7 eV is poorly resolved and is analyzed in terms of two ππ{sup ∗} states of

Spectral-kinetic characteristics of Pr3+ luminescence in LiLuF4 host upon excitation in the UV-VUV range

International Nuclear Information System (INIS)

Stryganyuk, G.; Zimmerer, G.; Shiran, N.; Voronova, V.; Nesterkina, V.; Gektin, A.; Shimamura, K.; Villora, E.; Jing, F.; Shalapska, T.; Voloshinovskii, A.

2008-01-01

Spectral-kinetic study of Pr 3+ luminescence has been performed for LiLuF 4 :Pr(0.1 mol%) single crystal upon the excitation within 5-12 eV range at T=8 K. The fine-structure of Pr 3+ 4f 2 →4f 5d excitation spectra is shown for LiLuF 4 :Pr(0.1 mol%) to be affected by the efficient absorption transitions of Pr 3+ ions into 4f 5d involving 4f 1 core in the ground state. Favourable conditions have been revealed in LiLuF 4 :Pr(0.1 mol%) for the transformation of UV-VUV excitation quanta into the visible range. Lightly doped LiLuF 4 :Pr crystals are considered as the promising luminescent materials possessing the efficient Pr 3+3 P 0 visible emission upon UV-VUV excitation. The mechanism of energy transfer between Lu 3+ host ion and Pr 3+ impurity is discussed

Color ferromagnetic vacuum states in QCD and two-loop energy densities

International Nuclear Information System (INIS)

Nielsen, H.B.; Ninomiya, M.

1979-12-01

Two-loop energy densities of color ferromagnetic states are obtained using the β-function calculated to two-loop approximation and the exact formula for the energy density of such a state. This is used to derive bounds on the MIT bag constant correcting the previous bound in one-loop approximation. For a constant field color ferromagnetic ansatz state the bound on the QCD scale parameter Λsub(p) 3 -vacuum ansatz with two-loop and instanton correction gives Λsub(p)<= 0.16 GeV. Tt is stressed that the 'perturbative vacuum', which is identified with the inside bag state is a somewhat ill defined concept due to a path-dependence in the integral giving the energy density. (Auth.)

Solubility and IR studies of gamma-irradiated arabinoxylan

International Nuclear Information System (INIS)

Ebringerova, A.; Kacurakova, M.; Hromadkova, Z.; Pruzinec, J.

1989-01-01

The structural and solubility changes of a water-insoluble arabinoxylan with a low degree of branching was studied after γ-irradiation by IR spectroscopy and chemical analysis of the polysaccharide and its polymeric fractions. New functional groups like hydroperoxidic, carbonylic and endiolic ones were found after irradiation. The IR spectra shows that the structural changes involved by radiolytic treatment are reflected in the shape of the IR spectra of both polymeric fractions. The ratio of absorbance of the peaks at 1725 and 2920 cm -1 increased with radiation dose. (author) 17 refs.; 2 figs.; 2 tabs

Active Bilayer PE/PCL Films for Food Packaging Modified with Zinc Oxide and Casein

Directory of Open Access Journals (Sweden)

Ana Rešček

2015-12-01

Full Text Available This paper studies the properties of active polymer food packaging bilayer polyethylene/polycaprolactone (PE/PCL films. Such packaging material consists of primary PE layer coated with thin film of PCL coating modified with active component (zinc oxide or zinc oxide/casein complex with intention to extend the shelf life of food and to maintain the quality and health safety. The influence of additives as active components on barrier, mechanical, thermal and antimicrobial properties of such materials was studied. The results show that, in comparison to the neat PE and PE/PCL films, some of PE/PCL bilayer films with additives exhibit improved barrier properties i.e. decreased water vapour permeability. Higher thermal stability of modified PE/PCL material is obtained due to a modified mechanism of thermal degradation. The samples with the additive nanoparticles homogeneously dispersed in the polymer matrix showed good mechanical properties. Addition of higher ZnO content contributes to the enhanced antibacterial activity of a material.

PERIODIC ACCRETION INSTABILITIES IN THE PROTOSTAR L1634 IRS 7

Energy Technology Data Exchange (ETDEWEB)

Hodapp, Klaus W. [Institute for Astronomy, University of Hawaii, 640 N. Aohoku Place, Hilo, HI 96720 (United States); Chini, Rolf, E-mail: hodapp@ifa.hawaii.edu, E-mail: rolf.chini@astro.ruhr-uni-bochum.de [Astronomisches Institut, Ruhr-Universität Bochum, Universitätsstraße 150, D-44801 Bochum (Germany)

2015-11-10

The small molecular cloud Lynds 1634 contains at least three outflow sources. We found one of these, IRS 7, to be variable with a period of 37.14 ± 0.04 days and an amplitude of approximately 2 mag in the K{sub s} band. The light curve consists of a quiescent phase with little or no variation, and a rapid outburst phase. During the outburst phase, the rapid variation in brightness generates light echoes that propagate into the surrounding molecular cloud, allowing a measurement of the distance to IRS 7 of 404 pc ± 35 pc. We observed only a marginally significant change in the H − K color during the outburst phase. The K-band spectrum of IRS 7 shows CO bandhead emission but its equivalent width does not change significantly with the phase of the light curve. The H{sub 2} 1–0 S(1) line emission does not follow the variability of the continuum flux. We also used the imaging data for a proper motion study of the outflows originating from the IRS 7 and the far-infrared source IRAS 05173-0555, and confirm that these are indeed distinct outflows.

Sensory Drive, Color, and Color Vision.

Science.gov (United States)

Price, Trevor D

2017-08-01

Colors often appear to differ in arbitrary ways among related species. However, a fraction of color diversity may be explained because some signals are more easily perceived in one environment rather than another. Models show that not only signals but also the perception of signals should regularly evolve in response to different environments, whether these primarily involve detection of conspecifics or detection of predators and prey. Thus, a deeper understanding of how perception of color correlates with environmental attributes should help generate more predictive models of color divergence. Here, I briefly review our understanding of color vision in vertebrates. Then I focus on opsin spectral tuning and opsin expression, two traits involved in color perception that have become amenable to study. I ask how opsin tuning is correlated with ecological differences, notably the light environment, and how this potentially affects perception of conspecific colors. Although opsin tuning appears to evolve slowly, opsin expression levels are more evolutionarily labile but have been difficult to connect to color perception. The challenge going forward will be to identify how physiological differences involved in color vision, such as opsin expression levels, translate into perceptual differences, the selection pressures that have driven those differences, and ultimately how this may drive evolution of conspecific colors.

Application of thermal analysis methods on the study of PE thermal degradation and the influence of Mg (OH) sub 2 as fire retardant

CERN Document Server

Zarringhalam-Moghaddam, A

2002-01-01

Fire retardation effects of Mg(OH) sub 2 on PE was studied utilizing DTA, TGA and DSC methods. Reductions on reaction peak area and mass loss rate with the addition of Mg(OH) sub 2 were observed as indication of retardation effects of Mg(OH) sub 2 on PE. Cone calorimeter tests were performed on samples to verify the thermo analytical results. It was concluded that when Mg(OH) sub 2 is present it effectively modified the degradation behavior of PE and the thermal analyses are useful and rapid methods to study the retardation effects.

Variability of the Structural Coloration in Two Butterfly Species with Different Prezygotic Mating Strategies.

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Gábor Piszter

Full Text Available Structural coloration variability was investigated in two Blue butterfly species that are common in Hungary. The males of Polyommatus icarus (Common Blue and Plebejus argus (Silver-studded Blue use their blue wing coloration for conspecific recognition. Despite living in the same type of habitat, these two species display differences in prezygotic mating strategy: the males of P. icarus are patrolling, while P. argus males have sedentary behavior. Therefore, the species-specific photonic nanoarchitecture, which is the source of the structural coloration, may have been subjected to different evolutionary effects. Despite the increasing interest in photonic nanoarchitectures of biological origin, there is a lack of studies focused on the biological variability of structural coloration that examine a statistically relevant number of individuals from the same species. To investigate possible structural color variation within the same species in populations separated by large geographical distances, climatic differences, or applied experimental conditions, one has to be able to compare these variations to the normal biological variability within a single population. The structural coloration of the four wings of 25 male individuals (100 samples for each species was measured and compared using different light-collecting setups: perpendicular and with an integrating sphere. Significant differences were found in the near UV wavelength region that are perceptible by these polyommatine butterflies but are invisible to human observers. The differences are attributed to the differences in the photonic nanoarchitecture in the scales of these butterflies. Differences in the intensity of structural coloration were also observed and were tentatively attributed to the different prezygotic mating strategies of these insects. Despite the optical complexity of the scale covered butterfly wings, for sufficiently large sample batches, the averaged normal incidence

Variability of the Structural Coloration in Two Butterfly Species with Different Prezygotic Mating Strategies.

Science.gov (United States)

Piszter, Gábor; Kertész, Krisztián; Bálint, Zsolt; Biró, László Péter

2016-01-01

Structural coloration variability was investigated in two Blue butterfly species that are common in Hungary. The males of Polyommatus icarus (Common Blue) and Plebejus argus (Silver-studded Blue) use their blue wing coloration for conspecific recognition. Despite living in the same type of habitat, these two species display differences in prezygotic mating strategy: the males of P. icarus are patrolling, while P. argus males have sedentary behavior. Therefore, the species-specific photonic nanoarchitecture, which is the source of the structural coloration, may have been subjected to different evolutionary effects. Despite the increasing interest in photonic nanoarchitectures of biological origin, there is a lack of studies focused on the biological variability of structural coloration that examine a statistically relevant number of individuals from the same species. To investigate possible structural color variation within the same species in populations separated by large geographical distances, climatic differences, or applied experimental conditions, one has to be able to compare these variations to the normal biological variability within a single population. The structural coloration of the four wings of 25 male individuals (100 samples for each species) was measured and compared using different light-collecting setups: perpendicular and with an integrating sphere. Significant differences were found in the near UV wavelength region that are perceptible by these polyommatine butterflies but are invisible to human observers. The differences are attributed to the differences in the photonic nanoarchitecture in the scales of these butterflies. Differences in the intensity of structural coloration were also observed and were tentatively attributed to the different prezygotic mating strategies of these insects. Despite the optical complexity of the scale covered butterfly wings, for sufficiently large sample batches, the averaged normal incidence measurements and

Oxadiazole-carbazole polymer (POC)-Ir(ppy)3 tunable emitting composites

Science.gov (United States)

Bruno, Annalisa; Borriello, Carmela; Di Luccio, Tiziana; Sessa, Lucia; Concilio, Simona; Haque, Saif A.; Minarini, Carla

2017-04-01

POC polymer is an oxadiazole-carbazole copolymer we have previously synthetized and established as light emitting material in Organic Light Emitting Devices (OLEDs), although POC quantum yield emission efficiency and color purity still need to be enhanced. On the other hand, tris[2-phenylpyridinato-C2,N]iridium(III) (Ir(ppy)3) complexes, namely Ir(ppy)3 are among the brightest luminophores employed in green light emitting devices. Our aim, in this work, is to take advantage of Ir(ppy)3 bright emission by combining the Ir complex with blue emitting POC to obtain tunable light emitting composites over a wide range of the visible spectrum. Here we have investigated the optical proprieties POC based nanocomposites with different concentrations of Ir(ppy)3, ranging from 1 to 10 wt%. Both spectral and time resolved fluorescence measurements show an efficient energy transfer from the polymer to the dopants, resulting in white-emitting composites. The most intense and stable emission has been found when POC was doped with about 5 wt% concentration of Ir(ppy)3.

Rater reliability and concurrent validity of the Keyboard Personal Computer Style instrument (K-PeCS).

Science.gov (United States)

Baker, Nancy A; Cook, James R; Redfern, Mark S

2009-01-01

This paper describes the inter-rater and intra-rater reliability, and the concurrent validity of an observational instrument, the Keyboard Personal Computer Style instrument (K-PeCS), which assesses stereotypical postures and movements associated with computer keyboard use. Three trained raters independently rated the video clips of 45 computer keyboard users to ascertain inter-rater reliability, and then re-rated a sub-sample of 15 video clips to ascertain intra-rater reliability. Concurrent validity was assessed by comparing the ratings obtained using the K-PeCS to scores developed from a 3D motion analysis system. The overall K-PeCS had excellent reliability [inter-rater: intra-class correlation coefficients (ICC)=.90; intra-rater: ICC=.92]. Most individual items on the K-PeCS had from good to excellent reliability, although six items fell below ICC=.75. Those K-PeCS items that were assessed for concurrent validity compared favorably to the motion analysis data for all but two items. These results suggest that most items on the K-PeCS can be used to reliably document computer keyboarding style.

Comparatively Studied Color Correction Methods for Color Calibration of Automated Microscopy Complex of Biomedical Specimens

Directory of Open Access Journals (Sweden)

T. A. Kravtsova

2016-01-01

Full Text Available The paper considers a task of generating the requirements and creating a calibration target for automated microscopy systems (AMS of biomedical specimens to provide the invariance of algorithms and software to the hardware configuration. The required number of color fields of the calibration target and their color coordinates are mostly determined by the color correction method, for which coefficients of the equations are estimated during the calibration process. The paper analyses existing color calibration techniques for digital imaging systems using an optical microscope and shows that there is a lack of published results of comparative studies to demonstrate a particular useful color correction method for microscopic images. A comparative study of ten image color correction methods in RGB space using polynomials and combinations of color coordinate of different orders was carried out. The method of conditioned least squares to estimate the coefficients in the color correction equations using captured images of 217 color fields of the calibration target Kodak Q60-E3 was applied. The regularization parameter in this method was chosen experimentally. It was demonstrated that the best color correction quality characteristics are provided by the method that uses a combination of color coordinates of the 3rd order. The study of the influence of the number and the set of color fields included in calibration target on color correction quality for microscopic images was performed. Six train sets containing 30, 35, 40, 50, 60 and 80 color fields, and test set of 47 color fields not included in any of the train sets were formed. It was found out that the train set of 60 color fields minimizes the color correction error values for both operating modes of digital camera: using "default" color settings and with automatic white balance. At the same time it was established that the use of color fields from the widely used now Kodak Q60-E3 target does not

Stokes image reconstruction for two-color microgrid polarization imaging systems.

Science.gov (United States)

Lemaster, Daniel A

2011-07-18

The Air Force Research Laboratory has developed a new microgrid polarization imaging system capable of simultaneously reconstructing linear Stokes parameter images in two colors on a single focal plane array. In this paper, an effective method for extracting Stokes images is presented for this type of camera system. It is also shown that correlations between the color bands can be exploited to significantly increase overall spatial resolution. Test data is used to show the advantages of this approach over bilinear interpolation. The bounds (in terms of available reconstruction bandwidth) on image resolution are also provided.

Impaired Insulin Signaling is Associated with Hepatic Mitochondrial Dysfunction in IR+/−-IRS-1+/− Double Heterozygous (IR-IRS1dh Mice

Directory of Open Access Journals (Sweden)

Andras Franko

2017-05-01

Full Text Available Mitochondria play a pivotal role in energy metabolism, but whether insulin signaling per se could regulate mitochondrial function has not been identified yet. To investigate whether mitochondrial function is regulated by insulin signaling, we analyzed muscle and liver of insulin receptor (IR+/−-insulin receptor substrate-1 (IRS-1+/− double heterozygous (IR-IRS1dh mice, a well described model for insulin resistance. IR-IRS1dh mice were studied at the age of 6 and 12 months and glucose metabolism was determined by glucose and insulin tolerance tests. Mitochondrial enzyme activities, oxygen consumption, and membrane potential were assessed using spectrophotometric, respirometric, and proton motive force analysis, respectively. IR-IRS1dh mice showed elevated serum insulin levels. Hepatic mitochondrial oxygen consumption was reduced in IR-IRS1dh animals at 12 months of age. Furthermore, 6-month-old IR-IRS1dh mice demonstrated enhanced mitochondrial respiration in skeletal muscle, but a tendency of impaired glucose tolerance. On the other hand, 12-month-old IR-IRS1dh mice showed improved glucose tolerance, but normal muscle mitochondrial function. Our data revealed that deficiency in IR/IRS-1 resulted in normal or even elevated skeletal muscle, but impaired hepatic mitochondrial function, suggesting a direct cross-talk between insulin signaling and mitochondria in the liver.

The mechanism of PTFE and PE friction deposition: a combined scanning electron and scanning force microscopy study on highly oriented polymeric sliders

NARCIS (Netherlands)

Schönherr, Holger; Schaeben, H.; Vancso, Gyula J.

1998-01-01

The mechanism of friction deposition of polytetrafluoroethylene (PTFE) and polyethylene (PE) was studied by scanning electron (SEM) and scanning force microscopy (SFM) on the worn surfaces of PTFE and PE sliders that were used in friction deposition on glass substrates. These surfaces exhibited a

A Study on Visibility Rating of Several Representative Web-Safe Colors

Science.gov (United States)

Saito, Daisuke; Saito, Keiichi; Notomi, Kazuhiro; Saito, Masao

This paper presents the visibility ordering of several web-safe colors. The research of web site visibility is important because of the rapid dissemination of the World Wide Web. The combination of a foreground color and a background color is an important factor in providing sufficient visibility. Therefore, the rating of color combination visibility is necessary when developing accessible web sites. In this study, the visibility of several web-safe color combinations was examined using psychological methodology, i.e., a paired comparison. Eighteen chromatic web-safe colors were employed for visual stimuli. Nine students ranging from ages 21 to 29 (average 23.7) were recruited, and all were with normal color sensation. These nine subjects looked at two different colored characters simultaneously on the white background and were instructed to identify which one enabled them to see more clearly. In examining the relationship between the psychological rankings of the color combinations and the visual sensations, each color combination was first scored as to the visibility by Thurstone's paired comparisons technique. Secondly, the visual sensation was deduced by applying Weber-Fechner's law to the luminance of the foreground colors. As results, the luminance of a foreground color influenced the visibility; however the visibility rating is difficult only using the luminance of web-safe colors. These indicate that the chromaticity and chroma saturation are necessary in rating of chromatic web-safe color visibility.

Evaluation of the color stability of two techniquesfor reproducing artificial irides after microwave polymerization

Directory of Open Access Journals (Sweden)

Marcelo Coelho Goiato

2011-06-01

Full Text Available The use of ocular prostheses for ophthalmic patients aims to rebuild facial aesthetics and provide an artificial substitute to the visual organ. Natural intemperate conditions promote discoloration of artificial irides and many studies have attempted to produce irides with greater chromatic paint durability using different paint materials. OBJECTIVES: The present study evaluated the color stability of artificial irides obtained with two techniques (oil painting and digital image and submitted to microwave polymerization. MATERIAL AND METHODS: Forty samples were fabricated simulating ocular prostheses. each sample was constituted by one disc of acrylic resin N1 and one disc of colorless acrylic resin with the iris interposed between the discs. The irides in brown and blue color were obtained by oil painting or digital image. The color stability was determined by a reflection spectrophotometer and measurements were taken before and after microwave polymerization. Statistical analysis of the techniques for reproducing artificial irides was performed by applying the normal data distribution test followed by 2-way ANOVA and Tukey HSD test (α=.05. RESULTS: Chromatic alterations occurred in all specimens and statistically significant differences were observed between the oil-painted samples and those obtained by digital imaging. There was no statistical difference between the brown and blue colors. Independently of technique, all samples suffered color alterations after microwave polymerization. CONCLUSION: The digital imaging technique for reproducing irides presented better color stability after microwave polymerization.

Quantitative profiling of PE, MMPE, DMPE, and PC lipid species by multiple precursor ion scanning: A tool for monitoring PE metabolism

DEFF Research Database (Denmark)

Bilgin, Mesut; Markgraf, Daniel F; Duchoslav, Eva

2011-01-01

We report a method for the simultaneous identification and quantification of phosphatidylethanolamine (PE), monomethyl-phosphatidylethanolamine (MMPE), dimethyl-phosphatidylethanolamine (DMPE), and phosphatidylcholine (PC) species in lipid extracts. The method employs a specific "mass-tag" strategy...... where DMPE, MMPE, and PE species are chemically methylated with deuterated methyliodide (CD(3)I) to produce PC molecules having class-specific mass offsets of 3, 6 and 9Da, respectively. The derivatized aminoglycerophospholipids release characteristic phosphorylcholine-like fragment ions having specific...... and DMPE, and abundant PE and PC species in a single mass spectrometric analysis. We demonstrated the efficacy of the methodology by conducting a series of biochemical experiments using stable isotope labeled ethanolamine to survey the activities and substrate specificities of enzymes involved in PE...

A study of glasses-type color CGH using a color filter considering reduction of blurring

Science.gov (United States)

Iwami, Saki; Sakamoto, Yuji

2009-02-01

We have developed a glasses-type color computer generated hologram (CGH) by using a color filter. The proposed glasses consist of two "lenses" made of overlapping holograms and color filters. The holograms, which are calculated to reconstruct images in each primary color, are divided to small areas, which we called cells, and superimposed on one hologram. In the same way, colors of the filter correspond to the hologram cells. We can configure it very simply without a complex optical system, and the configuration yields a small and light weight system suitable for glasses. When the cell is small enough, the colors are mixed and reconstructed color images are observed. In addition, color expression of reconstruction images improves, too. However, using small cells blurrs reconstructed images because of the following reasons: (1) interference between cells because of the correlation with the cells, and (2) reduction of resolution caused by the size of the cell hologram. We are investigating in order to make a hologram that has high resolution reconstructed color images without ghost images. In this paper, we discuss (1) the details of the proposed glasses-type color CGH, (2) appropriate cell size for an eye system, (3) effects of cell shape on the reconstructed images, and (4) a new method to reduce the blurring of the images.

Two-color mid-infrared spectroscopy of optically doped semiconductors

International Nuclear Information System (INIS)

Forcales, M.; Klik, M.A.J.; Vinh, N.Q.; Phillips, J.; Wells, J-P.R.; Gregorkiewicz, T.

2003-01-01

Optical doping is an attractive method to tailor photonic properties of semiconductor matrices for development of solid-state electroluminescent structures. For practical applications, thermal stability of emission obtained from these materials is required. Thermal processes can be conveniently investigated by two-color spectroscopy in the visible and the mid-infrared. Free-electron laser is a versatile high-brilliance source of radiation in the latter spectral range. In this contribution, we briefly review some of the results obtained recently by the two-color spectroscopy with a free-electron laser in different semiconductors optically doped with rare earth and transition metal ions. Effects leading to both enhancement and quenching of emission from optical dopants will be presented. For InP:Yb, Si:Er, and Si:Cu activation of particular optically induced non-radiative recombination paths will be shown. For Si:Er and Si:Ag, observation of a low temperature optical memory effect will be reported

Melanic variation underlies aposematic color variation in two hymenopteran mimicry systems.

Directory of Open Access Journals (Sweden)

Heather M Hines

Full Text Available The stinging hymenopteran velvet ants (Mutillidae and bumble bees (Apidae: Bombus spp. have both undergone extensive diversification in aposematic color patterns, including yellow-red hues and contrasting dark-light body coloration, as a result of Müllerian mimicry. Understanding the genetic and developmental mechanisms underlying shifts in these mimetic colors requires characterization of their pigmentation. In this study, a combination of solubility, spectrophotometry, and melanin degradation analysis are applied to several color forms and species of these lineages to determine that orange-red colors in both lineages are comprised of primarily dopamine-derived pheomelanins. Until a few recent studies, pheomelanins were thought not to occur in insects. These results support their potential to occur across insects and particularly among the Hymenoptera. Shifts between black and orange-red colors, such as between mimetic color forms of bumble bee Bombus melanopygus, are inferred to involve modification of the ratios of dark eumelanins to red pheomelanins, thus implicating the melanin pathway in mimetic diversification. This discovery highlights the need to focus on how pheomelanins are synthesized in the insect melanin pathway and the potential for new pigments to be found even in some of our most well-known insect systems.

Color stability of different denture teeth materials: an in vitro study.

Science.gov (United States)

Mutlu-Sagesen, L; Ergün, G; Ozkan, Y; Bek, B

2001-09-01

The aim of this in vitro study was to compare the color stability of commercially available porcelain, reinforced acrylic, and conventional acrylic denture teeth materials used in removable prostheses. Two brands of porcelain (Unilux-Enta Lactona-Holland and Vivoperl-Ivoclar-Liechtenstein), 2 brands of reinforced acrylic (Optodent-Bayer-Germany and Ivolek-Ivoclar-Liechtenstein), and 2 brands of conventional acrylic (Isodent-Güney Diş Deposu-Turkey and Samed-Turkey), were made, for a total of 6 different denture teeth groups. Denture teeth were subjected to 3 staining solutions (filtered coffee, tea, and cola) and distilled water. From each group of denture teeth, 4 sets of maxillary anterior denture teeth were immersed in each of the 4 solutions. The color values of denture teeth were measured colorimetrically with the Gardner XL 20 Tristimulus Colorimeter (Gardner Lab. Inc., Bethesda, Maryland, USA). Color changes were characterized in the CIEL*a*b* color space. Color change values were determined after 1 day, 1 week, 2 weeks, and 4 weeks. The color difference values were calculated and then evaluated by two-way ANOVA statistically. The filtered coffee solution was found to be more chromogenic than the other 2 staining solutions, while porcelain denture teeth materials were more color stable. Assuming the color change of deltaE* < 1.0 as a discernible limit and deltaE* = 3.3 as an acceptable value, the filtered coffee, tea, and cola had slight staining effects on all 6 groups of denture teeth.

A first-principles study of oxygen adsorption on Ir(111) surface

Energy Technology Data Exchange (ETDEWEB)

Gao, Hengjiao, E-mail: gaohengjiao@163.com; Xiong, Yuqing, E-mail: xiongyq@hotmail.com; Liu, Xiaoli, E-mail: shantianzi@126.com; Zhao, Dongcai, E-mail: zhaodongc@163.com; Feng, Yudong, E-mail: yudong_feng@sina.com; Wang, Lanxi, E-mail: wanglanxi@live.com; Wang, Jinxiao, E-mail: coldwind716@gmail.com

2016-12-15

Highlights: • Adsorption of oxygen on Ir(111) surface was studied by density functional theory. • The most stable adsorption site was determined by adsorption energy calculation. • Adsorption of oxygen at bridge and top site on Ir surface was the most stable ones. • Interaction of O 2p and Ir 5d orbits is relatively strong and formed hybridization. - Abstract: In order to understand deposition mechanism of iridium thin film by atomic layer deposition, the adsorption of oxygen on Ir(111) surface was studied by use of density functional theory and a periodical slab model. By calculating the adsorption energy and structure of oxygen at four adsorption sites (top, bridge, fcc-hollow and hcp-hollow) on Ir(111) surface, the most stable adsorption site was determined. On this basis, the banding mechanism of O and Ir atoms was studied by density of states of oxygen and iridium atoms. Oxygen adsorbed at hcp(parallel) site on Ir(111) surface was the most stable one according to the adsorption energy calculation results. Orbital charge analysis indicate that charge transferred from 5p and 5d orbit to 2p orbit of adsorbed O atoms, and 6s orbit of iridium atoms. Meanwhile, density of state study indicated that adsorption of oxygen on Ir(111) surface is mainly due to the interaction between 2p orbit of O atoms and 5d orbit of iridium atoms.

Use of HOMA-IR to diagnose non-alcoholic fatty liver disease: a population-based and inter-laboratory study.

Science.gov (United States)

Isokuortti, Elina; Zhou, You; Peltonen, Markku; Bugianesi, Elisabetta; Clement, Karine; Bonnefont-Rousselot, Dominique; Lacorte, Jean-Marc; Gastaldelli, Amalia; Schuppan, Detlef; Schattenberg, Jörn M; Hakkarainen, Antti; Lundbom, Nina; Jousilahti, Pekka; Männistö, Satu; Keinänen-Kiukaanniemi, Sirkka; Saltevo, Juha; Anstee, Quentin M; Yki-Järvinen, Hannele

2017-10-01

Recent European guidelines for non-alcoholic fatty liver disease (NAFLD) call for reference values for HOMA-IR. In this study, we aimed to determine: (1) the upper limit of normal HOMA-IR in two population-based cohorts; (2) the HOMA-IR corresponding to NAFLD; (3) the effect of sex and PNPLA3 genotype at rs738409 on HOMA-IR; and (4) inter-laboratory variations in HOMA-IR. We identified healthy individuals in two population-based cohorts (FINRISK 2007 [n = 5024] and the Programme for Prevention of Type 2 Diabetes in Finland [FIN-D2D; n = 2849]) to define the upper 95th percentile of HOMA-IR. Non-obese individuals with normal fasting glucose levels, no excessive alcohol use, no known diseases and no use of any drugs were considered healthy. The optimal HOMA-IR cut-off for NAFLD (liver fat ≥5.56%, based on the Dallas Heart Study) was determined in 368 non-diabetic individuals (35% with NAFLD), whose liver fat was measured using proton magnetic resonance spectroscopy ( 1 H-MRS). Samples from ten individuals were simultaneously analysed for HOMA-IR in seven European laboratories. The upper 95th percentiles of HOMA-IR were 1.9 and 2.0 in healthy individuals in the FINRISK (n = 1167) and FIN-D2D (n = 459) cohorts. Sex or PNPLA3 genotype did not influence these values. The optimal HOMA-IR cut-off for NAFLD was 1.9 (sensitivity 87%, specificity 79%). A HOMA-IR of 2.0 corresponded to normal liver fat (HOMA-IR measured in Helsinki corresponded to 1.3, 1.6, 1.8, 1.8, 2.0 and 2.1 in six other laboratories. The inter-laboratory CV% of HOMA-IR was 25% due to inter-assay variation in insulin (25%) rather than glucose (5%) measurements. The upper limit of HOMA-IR in population-based cohorts closely corresponds to that of normal liver fat. Standardisation of insulin assays would be the first step towards definition of normal values for HOMA-IR.

SCoPE: an efficient method of Cosmological Parameter Estimation

International Nuclear Information System (INIS)

Das, Santanu; Souradeep, Tarun

2014-01-01

Markov Chain Monte Carlo (MCMC) sampler is widely used for cosmological parameter estimation from CMB and other data. However, due to the intrinsic serial nature of the MCMC sampler, convergence is often very slow. Here we present a fast and independently written Monte Carlo method for cosmological parameter estimation named as Slick Cosmological Parameter Estimator (SCoPE), that employs delayed rejection to increase the acceptance rate of a chain, and pre-fetching that helps an individual chain to run on parallel CPUs. An inter-chain covariance update is also incorporated to prevent clustering of the chains allowing faster and better mixing of the chains. We use an adaptive method for covariance calculation to calculate and update the covariance automatically as the chains progress. Our analysis shows that the acceptance probability of each step in SCoPE is more than 95% and the convergence of the chains are faster. Using SCoPE, we carry out some cosmological parameter estimations with different cosmological models using WMAP-9 and Planck results. One of the current research interests in cosmology is quantifying the nature of dark energy. We analyze the cosmological parameters from two illustrative commonly used parameterisations of dark energy models. We also asses primordial helium fraction in the universe can be constrained by the present CMB data from WMAP-9 and Planck. The results from our MCMC analysis on the one hand helps us to understand the workability of the SCoPE better, on the other hand it provides a completely independent estimation of cosmological parameters from WMAP-9 and Planck data

The UV-VIS spectrophotometry applied to color and stability study in colored mortars

Directory of Open Access Journals (Sweden)

Alejandre, F. J.

1999-06-01

Full Text Available In the field of methodologies for color studying, a research of it has been done on colored mortars by applying uv-vis spectrophotometry, instrumental technique which can be used for solid materials works, and previously applied to building materials study. Results obtained show that the mentioned technique permits to evaluate quantitatively and qualitatively colors in an easy and objective way, besides nowadays advantages of the instrumental analysis: digital color register, computerized data processing, and precision and exactness increment in chromatic comparisons.

Dentro de las metodologías existentes para el estudio del color, se ha realizado una investigación del mismo en morteros coloreados por medio de la espectrofotometría UV-VIS, técnica instrumental que es adaptable al trabajo con materiales sólidos, y que ha sido aplicada anteriormente en el estudio de diversos materiales de construcción. Los resultados obtenidos muestran cómo la citada técnica permite además de evaluar cualitativamente y cuantitativamente los colores de forma sencilla y objetiva, el disponer de las ventajas que conlleva actualmente el análisis instrumental: registro digital del color, tratamiento informatizado de datos y aumento de precisión y exactitud en las comparaciones cromáticas.

The interaction between surface color and color knowledge: behavioral and electrophysiological evidence.

Science.gov (United States)

Bramão, Inês; Faísca, Luís; Forkstam, Christian; Inácio, Filomena; Araújo, Susana; Petersson, Karl Magnus; Reis, Alexandra

2012-02-01

In this study, we used event-related potentials (ERPs) to evaluate the contribution of surface color and color knowledge information in object identification. We constructed two color-object verification tasks - a surface and a knowledge verification task - using high color diagnostic objects; both typical and atypical color versions of the same object were presented. Continuous electroencephalogram was recorded from 26 subjects. A cluster randomization procedure was used to explore the differences between typical and atypical color objects in each task. In the color knowledge task, we found two significant clusters that were consistent with the N350 and late positive complex (LPC) effects. Atypical color objects elicited more negative ERPs compared to typical color objects. The color effect found in the N350 time window suggests that surface color is an important cue that facilitates the selection of a stored object representation from long-term memory. Moreover, the observed LPC effect suggests that surface color activates associated semantic knowledge about the object, including color knowledge representations. We did not find any significant differences between typical and atypical color objects in the surface color verification task, which indicates that there is little contribution of color knowledge to resolve the surface color verification. Our main results suggest that surface color is an important visual cue that triggers color knowledge, thereby facilitating object identification. Copyright © 2011 Elsevier Inc. All rights reserved.

Two plus blue equals green: Grapheme-color synesthesia allows cognitive access to numerical information via color

Science.gov (United States)

McCarthy, J. Daniel; Barnes, Lianne N.; Alvarez, Bryan D.; Caplovitz, Gideon Paul

2013-01-01

In grapheme-color synesthesia, graphemes (e.g., numbers or letters) evoke color experiences. It is generally reported that the opposite is not true: colors will not generate experiences of graphemes or their associated information. However, recent research has provided evidence that colors can implicitly elicit symbolic representations of associated graphemes. Here, we examine if these representations can be cognitively accessed. Using a mathematical verification task replacing graphemes with color patches, we find that synesthetes can verify such problems with colors as accurately as with graphemes. Doing so, however, takes time: ~250ms per color. Moreover, we find minimal reaction time switch-costs for switching between computing with graphemes and colors. This demonstrates that given specific task demands, synesthetes can cognitively access numerical information elicited by physical colors, and they do so as accurately as with graphemes. We discuss these results in the context of possible cognitive strategies used to access the information. PMID:24100131

Radiolysis of the polyethylene/water system: Studies on the role of hydroxyl radical

Energy Technology Data Exchange (ETDEWEB)

Billamboz, Nicolas [Laboratoire de Chimie Physique et Rayonnement Alain Chambaudet, UMR CEA E4, Universite de Franche-Comte, 16 route de Gray, 25030 Besancon Cedex (France); Grivet, Manuel, E-mail: manuel.grivet@univ-fcomte.f [Laboratoire de Chimie Physique et Rayonnement Alain Chambaudet, UMR CEA E4, Universite de Franche-Comte, 16 route de Gray, 25030 Besancon Cedex (France); Foley, Sarah [Laboratoire de Chimie Physique et Rayonnement Alain Chambaudet, UMR CEA E4, Universite de Franche-Comte, 16 route de Gray, 25030 Besancon Cedex (France); Baldacchino, Gerard [CEA, IRAMIS, SIS2M, Laboratoire de Radiolyse, Bat. 546, F-91191 Gif-sur-Yvette (France); CNRS, Laboratoire Claude Frejacques, F-91191 Gif-sur-Yvette (France); Hubinois, Jean-Charles [CEA, DAM, Valduc, F-21120 Is-sur-Tille (France)

2010-01-15

The role of hydroxyl radical on polyethylene degradation under aqueous conditions has been studied. The reactivity of HO{sup .} towards PE is highlighted by pulse radiolysis experiments on a PE powder suspension in water using the thiocyanate competition technique. Infrared analysis of PE films irradiated in the presence of water is performed. Solutions have been either degassed with Ar, in order to remove O{sub 2} which would react with the PE, or N{sub 2}O which enhances the production of HO{sup .} radicals. Oxygenated groups and double bond groups created at the surface of PE are characterized using IR analysis, and the results for both saturated solution systems are compared.

Regioselective aromatic substitution reactions of cyclometalated Ir(III) complexes: synthesis and photochemical properties of substituted Ir(III) complexes that exhibit blue, green, and red color luminescence emission.

Science.gov (United States)

Aoki, Shin; Matsuo, Yasuki; Ogura, Shiori; Ohwada, Hiroki; Hisamatsu, Yosuke; Moromizato, Shinsuke; Shiro, Motoo; Kitamura, Masanori

2011-02-07

In this manuscript, the regioselective halogenation, nitration, formylation, and acylation of Ir(tpy)(3) and Ir(ppy)(3) (tpy = 2-(4'-tolyl)pyridine and ppy = 2-phenylpyridine) and the subsequent conversions are described. During attempted bromination of the three methyl groups in fac-Ir(tpy)(3) using N-bromosuccinimide (NBS) and benzoyl peroxide (BPO), three protons at the 5'-position (p-position with respect to the C-Ir bond) of phenyl rings in tpy units were substituted by Br, as confirmed by (1)H NMR spectra, mass spectra, and X-ray crystal structure analysis. It is suggested that such substitution reactions of Ir complexes proceed via an ionic mechanism rather than a radical mechanism. UV-vis and luminescence spectra of the substituted Ir(III) complexes are reported. The introduction of electron-withdrawing groups such as CN and CHO groups at the 5'-position of tpy induces a blue shift of luminescence emission to about 480 nm, and the introduction of electron-donating groups such as an amino group results in a red shift to about 600 nm. A reversible change of emission for the 5'-amino derivative of Ir(tpy)(3), Ir(atpy)(3), between red and green occurs upon protonation and deprotonation.

The interaction between surface color and color knowledge: Behavioral and electrophysiological evidence

OpenAIRE

Bramão, I.; Faísca, L.; Forkstam, C.; Inácio, F.; Araújo, S.; Petersson, K.; Reis, A.

2012-01-01

In this study, we used event-related potentials (ERPs) to evaluate the contribution of surface color and color knowledge information in object identification. We constructed two color-object verification tasks – a surface and a knowledge verification task – using high color diagnostic objects; both typical and atypical color versions of the same object were presented. Continuous electroencephalogram was recorded from 26 subjects. A cluster randomization procedure was used to explore the diffe...

Photonic band gap effect and structural color from silver nanoparticle gelatin emulsion

Science.gov (United States)

Kok, Mang Hin; Ma, Rui; Lee, Jeffrey Chi Wai; Tam, Wing Yim; Chan, C. T.; Sheng, Ping; Cheah, Kok Wai

2005-10-01

We have fabricated planar structures of silver nanoparticles in monochromatic gelatin emulsion with a continuous spacing ranging from 0.15-0.40 micron using a two-beam interference of a single laser source. Our planar holograms display a colorful “rainbow” pattern and photonic bandgaps covering the visible and IR ranges. We model the planar silver nanoparticle-gelatin composite system using an effective medium approach and good agreement is obtained between theory and experiment.

Monolayers of gold nanostars with two Near-IR LSPR capable of additive photothermal response

KAUST Repository

Pallavicini, Piersandro

2015-07-06

Monolayers of photothermally responsive gold nanostars on PEI-coated surfaces display two Localized Surface Plasmon Resonances (LSPR) in the near-IR region that can be laser-irradiated either separately, obtaining two different T jumps, or simultaneously, obtaining a T jump equal to the sum of what obtained with separate irradiations

Monolayers of gold nanostars with two Near-IR LSPR capable of additive photothermal response

KAUST Repository

Pallavicini, Piersandro; Basile, Simone; Chirico, Giuseppe; Dacarro, Giacomo; D'Alfonso, Laura; Donà , Alice; Patrini, Maddalena; Falqui, Andrea; Sironi, Laura; Taglietti, Angelo

2015-01-01

Monolayers of photothermally responsive gold nanostars on PEI-coated surfaces display two Localized Surface Plasmon Resonances (LSPR) in the near-IR region that can be laser-irradiated either separately, obtaining two different T jumps, or simultaneously, obtaining a T jump equal to the sum of what obtained with separate irradiations

Characterization of fibroblast growth factor receptor 2 overexpression in the human breast cancer cell line SUM-52PE

International Nuclear Information System (INIS)

Tannheimer, Stacey L; Rehemtulla, Alnawaz; Ethier, Stephen P

2000-01-01

The fibroblast growth factor receptor (FGFR)2 gene has been shown to be amplified in 5-10% of breast cancer patients. A breast cancer cell line developed in our laboratory, SUM-52PE, was shown to have a 12-fold amplification of the FGFR2 gene, and FGFR2 message was found to be overexpressed 40-fold in SUM-52PE cells as compared with normal human mammary epithelial (HME) cells. Both human breast cancer (HBC) cell lines and HME cells expressed two FGFR2 isoforms, whereas SUM-52PE cells overexpressed those two isoforms, as well as several unique FGFR2 polypeptides. SUM-52PE cells expressed exclusively FGFR2-IIIb isoforms, which are high-affinity receptors for fibroblast growth factor (FGF)-1 and FGF-7. Differences were identified in the expression of the extracellular Ig-like domains, acid box and carboxyl termini, and several variants not previously reported were isolated from these cells. The FGFR family of receptor tyrosine kinases includes four members, all of which are highly alternatively spliced and glycosylated. For FGFR2, alternative splicing of the second half of the third Ig-like domain, involving exons IIIb and IIIc, is a mutually exclusive choice that affects ligand binding specificity and affinity [1,2,3]. It appears that the second half of the third Ig-like domain can dictate high affinity for FGF-2 or keratinocyte growth factor (KGF), whereas affinity for FGF-1 appears to remain the same [3]. Alternative splicing of the carboxyl terminus has been shown to involve at least two different exons that can produce at least three different variants. The C1-type and C2-type carboxyl termini are encoded by the same exon, and have two different splice acceptor sites, whereas the C3-type carboxyl terminus is encoded by a separate exon [4]. The biologic significance of the C1 carboxyl terminus, as compared with the shorter C3 variant found primarily in tumorigenic samples, has been studied in NIH3T3 transfection assays, in which C3 variants were able to produce

Expression of the phycoerythrin gene of Gracilaria lemaneiformis (Rhodophyta) in E. coli and evaluation of the bioactivity of recombinant PE

Science.gov (United States)

Wen, Ruobing; Sui, Zhenghong; Zhang, Xuecheng; Zhang, Shuang; Qin, Song

2007-10-01

Phycoerythrin (PE) is one of the most important proteins involved in light capturing during photosynthesis in red algae. Its potential biological activities had gained wide concerns. In the present study, tumor cytotoxic and hydroxyl radical assay were preformed to detect the bioactivity of recombinant PE. Recombinant plasmids pGEX-PE and pBGL were transformed into E. coli BL21 to make two recombinant strains BEX (pGEX-PE) and BGL (pBGL). PE expressing in BEX (pGEX-PE) was validated by SDS-PAGE and Western blotting analysis. SDS-PAGE analysis indicated that the PE-GST fusion protein was mostly inclusion bodies. Specific expression of PE was confirmed by Western blotting analysis. The recombinant E. coli BEX (pGEX-PE) cells were collected and sonicated. The supernatants were reserved for the tumor cytotoxic experiments. The result of tumor cytotoxic assay indicated that the supernatants containing PE had the activity of inhibiting the growth of Hela cells and with the increase of protein concentration, the inhibiting rate increased from 37.31% to 63.26%, which showed significant difference from the control. Hydroxyl radical scavenging effect was tested with supernatants of BEX (pGEX-PE) and BGL (pBGL) cell lysates treated with sonication and heating. For the sonication samples, the scavenging rates of the supernatants of BEX (pGEX-PE) and BGL (pBGL) cell lysates were significantly higher than the negative control BL21(pGEX-4T) ( Pprotein content. For the heating samples, except for the 0.2 mg mL-1 BGL (pBGL) products, the scavenging effects of the supernatants of BEX (pGEX-PE) and BGL (pBGL) cell lysates were stronger than that of negative control BL21(pGEX-4T). However, the effect intensity was not positively correlated with the increase of the protein concentration. Though a partially decreased hydroxyl radical scavenging activity was led by heating, the biological activity was still retained and conspicuous. This research showed that phycoerythrin protein

Photochemical defluorination of aqueous perfluorooctanoic acid (PFOA) by Fe(0)/GAC micro-electrolysis and VUV-Fenton photolysis.

Science.gov (United States)

Zhang, Li-Hong; Cheng, Jian-Hua; You, Xia; Liang, Xiao-Yan; Hu, Yong-You

2016-07-01

Perfluorooctanoic acid (PFOA) is extremely persistent and bioaccumulative in the environment; thus, it is very urgent to investigate an effective and moderate technology to treat the pollution of PFOA. In this study, a process combined iron and granular activated carbon (Fe(0)/GAC) micro-electrolysis with VUV-Fenton system is employed for the remediation of PFOA. Approximately 50 % PFOA (10 mg L(-1)) could be efficiently defluorinated under the following conditions: pH 3.0, dosage of Fe 7.5 g L(-1), dosage of GAC 12.5 g L(-1), and concentration of H2O2 22.8 mmol L(-1). Meanwhile, during the process, evident defluorination was observed and the concentration of fluoride ion was eventually 3.23 mg L(-1). The intermediates including five shorter-chain perfluorinated carboxylic acids (PFCAs), i.e., C7, C6, C5, C4, and C3, were also analyzed by high-performance liquid chromatography tandem mass spectrometry (HPLC/MS/MS) and defluorination mechanisms of PFOA was proposed, which involved photochemical of OH·, direct photolysis (185-nm VUV), and photocatalytic degradation of PFOA in the presence of Fe(3+) (254-nm UV).

Preferred memory color difference between the deuteranomalous and normal color vision

Science.gov (United States)

Baek, YeSeul; Kwak, Youngshin; Woo, Sungjoo; Park, Chongwook

2015-01-01

The goal of this study is to evaluate the difference of the preferred hues of familiar objects between the color deficient observer and the normal observer. Thirteen test color images were chosen covering fruit colors, natural scene and human faces. It contained red, yellow, green, blue, purple and skin color. Two color deficient observer (deuteranomal) and two normal observers were participated in this experiment. They controlled the YCC hue of the objects in the images to obtain the most preferred and the most natural image. The selected images were analyzed using CIELAB values of each pixel. Data analysis results showed that in the case of naturalness, both groups selected the similar hues for the most of image, while, in the case of preference, the color deficient observer preferred more reddish or more greenish images. Since the deuteranomalous observer has relatively week perception for red and green region, they may prefer more reddish or greenish color. The color difference between natural hue and preferred hue of deuteranomal observer is bigger than those of normal observer.

THz field engineering in two-color femtosecond filaments using chirped and delayed laser pulses

Science.gov (United States)

Nguyen, A.; González de Alaiza Martínez, P.; Thiele, I.; Skupin, S.; Bergé, L.

2018-03-01

We numerically study the influence of chirping and delaying several ionizing two-color light pulses in order to engineer terahertz (THz) wave generation in air. By means of comprehensive 3D simulations, it is shown that two chirped pulses can increase the THz yield when they are separated by a suitable time delay for the same laser energy in focused propagation geometry. To interpret these results, the local current theory is revisited and we propose an easy, accessible all-optical criterion that predicts the laser-to-THz conversion efficiencies given any input laser spectrum. In the filamentation regime, numerical simulations display evidence that a chirped pulse is able to produce more THz radiation due to propagation effects, which maintain the two colors of the laser field more efficiently coupled over long distances. A large delay between two pulses promotes multi-peaked THz spectra as well as conversion efficiencies above 10‑4.

Demonstration of resonant photopumping of Mo VII by Mo XII for a VUV laser near 600 Angstrom

International Nuclear Information System (INIS)

Ilcisin, K.J.; Aumayr, F.; Schwob, J.L.; Suckewer, S.

1993-09-01

We present data of experiments on the resonant photopumping of Mo VII by Mo XII as a method of generating a coherent VUV source near 600 angstrom. The experiment is based on a scheme proposed by Feldman and Reader in which the 4p 6 -- 4p 5 6s transition in Mo VII in resonantly photopumped by the 5s 2 S 1/2 -- 4p 2 P 1/2 transition in Mo XII. Results of the laser produced plasma experiments show the successful enhancement of the population of the Mo VII 4p 5 6s upper lasing level when pumped by an adjacent Mo VII plasma. No enhancement was seen in a control experiment where the Mo VII plasma was pumped by a Zr X plasma. Improvements of the intensity of the Mo XII pump source, achieved using an additional pump laser, lead to the generation of a population inversion for the VUV transition

Color Categories and Color Appearance

Science.gov (United States)

Webster, Michael A.; Kay, Paul

2012-01-01

We examined categorical effects in color appearance in two tasks, which in part differed in the extent to which color naming was explicitly required for the response. In one, we measured the effects of color differences on perceptual grouping for hues that spanned the blue-green boundary, to test whether chromatic differences across the boundary…

The use of old and recent DSM definitions of premature ejaculation in observational studies: a contribution to the present debate for a new classification of PE in the DSM-V.

Science.gov (United States)

Waldinger, Marcel D; Schweitzer, Dave H

2008-05-01

The DSM-III definition of premature ejaculation (PE) contains the criterion "control" but not that of "ejaculation time." In contrast, the Diagnostic and Statistical Manual of Mental Disorders (4th edition, Text Revision) (DSM-IV-TR) contains the criterion "short ejaculation time," while it lacks "control." To review the adequacy and consequent use of all criteria of the DSM-IV-TR definition in previously published PE Internet surveys. Reviewing all published cohort studies on PE from 2004 to 2007. MEDLINE and EMBASE computer bibliographies were used. Definitions of DSM-III, DSM-IV-TR, and International Classification of Diseases. Five papers, of which three are original studies, reported inclusion of men with PE according to DSM-IV-TR definition but omitted to apply the required "short ejaculation time" criterion. These studies, which have defined PE according to subjective criteria such as control, actually referred to the DSM-III definition. Using DSM-III-like definitions in three different studies revealed a highly variable prevalence of PE (32.5%, 27.6%, and 13.0%). In contrast, based on studies using a 1-minute cutoff point, being the time that is required to call ejaculation time "short" or using the criterion "persistent occurrence," PE revealed to be far less prevalent (5-6%). Unacceptable discrepancies of PE definitions according to DSM-III (abandoned but still used) and DSM-IV-TR argue strongly in favor of a multidimensional new classification of PE for the DSM-V.

Effect of various de-anodizing techniques on the surface stability of non-colored and colored nanoporous AAO films in acidic solution

Science.gov (United States)

Awad, Ahmed M.; Shehata, Omnia S.; Heakal, Fakiha El-Taib

2015-12-01

Anodic aluminum oxide (AAO) is well known as an important nanostructured material, and a useful template in the fabrication of nanostructures. Nanoporous anodic alumina (PAA) with high open porosity was prepared by adopting three de-anodizing regimes following the first anodizing step and preceding the second one. The de-anodizing methods include electrolytic etching (EE) and chemical etching using either phosphoric acid (PE) or sodium hydroxide (HE) solutions. Three of the obtained AAO samples were black colored by electrodeposition of copper nanoparticles in their pores. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques were used to characterize the electrochemical performance of the two sets of the prepared samples. In general, the data obtained in aggressive aerated 0.5 M HCl solution demonstrated dissimilar behavior for the three prepared samples despite that the second anodizing step was the same for all of them. The data indicated that the resistance and thickness of the inner barrier part of nano-PAA film, are the main controlling factors determining its stability. On the other hand, coloring the film decreased its stability due to the galvanic effect. The difference in the electrochemical behavior of the three colored samples was discussed based on the difference in both the pore size and thickness of the outer porous part of PAA film as supported by SEM, TEM and cross-sectional micrographs. These results can thus contribute for better engineering applications of nanoporous AAO.

The role of peu-miR164 and its target PeNAC genes in response to abiotic stress in Populus euphratica.

Science.gov (United States)

Lu, Xin; Dun, Hui; Lian, Conglong; Zhang, Xiaofei; Yin, Weilun; Xia, Xinli

2017-06-01

Plant miR164 family is highly conserved and miR164 members regulate conserved targets belonging to NAC transcription factors. Our previous studies have revealed that peu-miR164a-e and its target gene POPTR_0007s08420 participate in abiotic stress response in Populus euphratica according to deep sequencing and degradome sequencing. In this study, miR164 family comprises six members that generate two mature products (miR164a-e and miR164f) and target seven NAC genes in P. euphratica. Co-expression in Nicotiana benthamiana and 5' RACE confirmed that peu-miR164 directs PeNAC070, PeNAC012 and PeNAC028 mRNAs cleavage. Expression profiles of primary peu-miR164 a/b/c/d/e bear similarity to those of peu-miR164a-e, whereas PeNAC070 and PeNAC081 showed inverse expression patterns with peu-miR164a-e under abiotic stresses. Existence of cis-acting elements in PeNAC070 promoter (ABRE,MBs, Box-W1, GC-motif, and W-box) and in peu-MIR164b promoter (HSE) further confirmed different responses of peu-miR164 and PeNAC070 to abiotic stresses. Histochemical β-glucuronidase (GUS) staining revealed that GUS activities increased when Pro PeNAC070 ::GUS transgenic Arabidopsis plants were exposed to NaCl, mannitol and abscisic acid (ABA), whereas GUS activity of Pro peu-MIR164b ::GUS plants decreased under ABA treatment. Subcellular localization and transactivation assays showed that PeNAC070 protein was localized to the nucleus and exhibited transactivation activity at the C-terminal. Overexpression of PeNAC070 in Arabidopsis promoted lateral root development, delayed stem elongation, and increased sensitivity of transgenic plants to drought and salt stresses. This study aids in understanding the adaptability of P. euphratica to extreme drought and salt environment by analysing tissue-specific expression patterns of miR164-regulated and specific promoter-regulated PeNAC genes. Copyright © 2017 Elsevier Masson SAS. All rights reserved.

In vitro study of color stability of polycrystalline and monocrystalline ceramic brackets

OpenAIRE

de Oliveira, Cibele Braga; Maia, Luiz Guilherme Martins; Santos-Pinto, Ary; Gandini J?nior, Luiz Gonzaga

2014-01-01

OBJECTIVE: The aim of this in vitro study was to analyze color stability of monocrystalline and polycrystalline ceramic brackets after immersion in dye solutions. METHODS: Seven ceramic brackets of four commercial brands were tested: Two monocrystalline and two polycrystalline. The brackets were immersed in four dye solutions (coffee, red wine, Coke and black tea) and in artificial saliva for the following times: 24 hours, 7, 14 and 21 days, respectively. Color changes were measured by a...

Degradation of Solar Array Components in a Combined UV/VUV High Temperature Test Environment

Directory of Open Access Journals (Sweden)

Nömayr Christel

2017-01-01

A design verification test under UV/VUV conditions of sun exposed materials and technologies on component level is presented which forms part of the overall verification and qualification of the solar array design of the MTM and MPO. The test concentrates on the self-contamination aspects and the resulting performance losses of the solar array under high intensity and elevated temperature environment representative for the photovoltaic assembly (PVA.

Making the Case for Developing New PE-for-Health Pedagogies

Science.gov (United States)

Armour, Kathleen; Harris, Jo

2013-01-01

This article argues for a new direction in research on health education within physical education (PE). Governments are increasingly looking to schools as a convenient form of public health investment. PE is implicated in health because of its core focus on physical activity, but there is little evidence to suggest that PE improves health…

Prevalence of Prostatitis-Like Symptoms and Outcomes of NIH-CPSI in Outpatients with Lifelong and Acquired PE: Based on a Large Cross-Sectional Study in China

Directory of Open Access Journals (Sweden)

Daofang Zhu

2017-01-01

Full Text Available Premature ejaculation (PE is one of the most common sexual dysfunctions, which were associated with prostatitis-like symptoms (PLS. We intended to explore the prevalence of prostatitis-like symptoms and outcomes of National Institutes of Health-Chronic Prostatitis Symptom Index (NIH-CPSI scores in outpatients with lifelong (LPE and acquired premature ejaculation (APE. From December 2013 to December 2015, a total of 498 consecutive heterosexual men with PE and 322 male healthy subjects without PE were enrolled. Each of them completed a detailed questionnaire on demographics information, sexual and medical histories, and the NIH-CPSI. Assessment of NIH-CPSI and definition of PLS and PE were used to measure the PLS and NIH-CPSI scores and ejaculatory function for all subjects. Finally, a total of 820 subjects (including 498 men in PE group and 322 men in control group were enrolled in our study. The mean ages were significantly different between PE and no PE groups. Men with PE reported worse PLS and higher NIH-CPSI scores (P < 0.001 for all. Similar findings were also observed between men with LPE and APE. Men with APE also reported higher rates of PLS and scores of NIH-CPSI (P < 0.001 for all. Multivariate analysis showed that PLS and NIH-CPSI scores were significantly associated with PE.

Prevalence of Prostatitis-Like Symptoms and Outcomes of NIH-CPSI in Outpatients with Lifelong and Acquired PE: Based on a Large Cross-Sectional Study in China.

Science.gov (United States)

Zhu, Daofang; Dou, Xianming; Tang, Liang; Tang, Dongdong; Liao, Guiyi; Fang, Weihua; Zhang, Xiansheng

2017-01-01

Premature ejaculation (PE) is one of the most common sexual dysfunctions, which were associated with prostatitis-like symptoms (PLS). We intended to explore the prevalence of prostatitis-like symptoms and outcomes of National Institutes of Health-Chronic Prostatitis Symptom Index (NIH-CPSI) scores in outpatients with lifelong (LPE) and acquired premature ejaculation (APE). From December 2013 to December 2015, a total of 498 consecutive heterosexual men with PE and 322 male healthy subjects without PE were enrolled. Each of them completed a detailed questionnaire on demographics information, sexual and medical histories, and the NIH-CPSI. Assessment of NIH-CPSI and definition of PLS and PE were used to measure the PLS and NIH-CPSI scores and ejaculatory function for all subjects. Finally, a total of 820 subjects (including 498 men in PE group and 322 men in control group) were enrolled in our study. The mean ages were significantly different between PE and no PE groups. Men with PE reported worse PLS and higher NIH-CPSI scores ( P < 0.001 for all). Similar findings were also observed between men with LPE and APE. Men with APE also reported higher rates of PLS and scores of NIH-CPSI ( P < 0.001 for all). Multivariate analysis showed that PLS and NIH-CPSI scores were significantly associated with PE.

Selected cis- and trans-3-fluorostyrene rotamers studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy

Science.gov (United States)

Wu, Pei Ying; Tzeng, Wen Bih

2015-10-01

We applied two-color resonant two-photon ionization and mass-analyzed threshold ionization techniques to record the vibronic, photoionization efficiency, and cation spectra of the selected rotamers of 3-fluorostyrene. The adiabatic ionization energies of cis- and trans-3-fluorostyrene were determined to be 69 960 ± 5 and 69 856 ± 5 cm-1, respectively. Cation vibrations 10a, 15, 6b, and 12 of both rotamers have been found to have frequencies of 218, 404, 452, and 971 cm-1, respectively. This finding shows that the relative orientation of the vinyl group with respect to the F atom does not affect these vibrations of the 3-fluorostyrene cation. Our one-dimensional potential energy surface calculations support that the cis-trans isomerization of 3-fluorostyrene does not occur under the present experimental conditions.

Targeting the Body and the Mind: Evaluation of a P.E. Curriculum Intervention for Adolescents

Science.gov (United States)

Loukaitou-Sideris, Anastasia

2015-01-01

P.E. classes are often the only opportunity for inner-city youth to engage in physical activity, but budget cuts and pressure to perform well on standardized tests has made P.E. an afterthought for many school administrators. This study evaluated the effectiveness of a new P.E. curriculum in five Los Angeles inner-city schools. Interviews were…

Crustal Strain Observation Using a Two-Color Interferometer with Accurate Correction of Refractive Index of Air

Directory of Open Access Journals (Sweden)

Souichi Telada

2014-07-01

Full Text Available A highly accurate two-color interferometer with automatic correction of the refractive index of air was developed for crustal strain observation. The two-color interferometer, which can measure a geometrical distance of approximately 70 m, with a relative resolution of 2 × 10−9, clearly detected a change in strain due to earth tides in spite of optical measurement in air. Moreover, a large strain quake due to an earthquake could be observed without disturbing the measurement. We demonstrated the advantages of the two-color interferometer in air for geodetic observation.

Effects of photoirradiation in UV and VUV regions during plasma exposure to polymers

International Nuclear Information System (INIS)

Cho, Ken; Setsuhara, Yuichi; Takenaka, Kosuke; Shiratani, Masaharu; Sekine, Makoto; Hori, Masaru

2011-01-01

Interactions between photons irradiated from Ar-O 2 mixture plasmas and polymer surfaces were investigated on the basis of depth analyses of chemical bonding states in the nano-surface layer of polyethylene terephthalate (PET) films via hard X-ray photoelectron spectroscopy (HXPES) and conventional X-ray photoelectron spectroscopy (XPS). The PET films were exposed to photons from the Ar-O 2 mixture plasmas by covering the PET samples with MgF 2 and quartz windows as optical filters for evaluation of photoirradiation effects in ultraviolet (UV) and vacuum ultraviolet (VUV) regions. The HXPES results indicated that the degradation of the chemical bonding states due to photoirradiation in regions was insignificant in deeper regions up to about 50 nm from the surface. Whereas, conventional XPS analysis showed that C-O bond, O=C-O bond and C=O bond increased after photoirradiation in UV and VUV regions. These results suggest that the increase in oxygen functionalities (C-O bond, O=C-O bond and C=O bond) may be attributed to chemical reactions and/or terminations of scissed bonds via photodecompositions of the polymer with oxygen and/or OH species (oxygen molecules and radicals during plasma exposure and/or oxygen molecules and moisture after taking the PET samples out of the plasma reactor to the ambient air) in the vicinity of the sample surface.

Earnings quality and P/E ratio: Evidence from Tehran Stock Exchange

Directory of Open Access Journals (Sweden)

Hassan Ghodrati

2014-08-01

Full Text Available This paper evaluates the impacts of earnings quality criteria on the ratio of price to earnings per share (P/E on 88 accepted companies in Tehran Stock Exchange (TSE over the period 2007- 2012. The results indicate that there was a positive and significant relationship between the P/E ratio and cash dividend. There is also a positive and significant relationship between P/E ratio as dependent variable and the gross profit ratio to sales. On the other hand, there is a significant reverse relationship between P/E ratio and the profit variability. However, no significant relationship exists between P/E as dependent variable and deferrals (accruals variable.

Ultrasonic testing standard of fusion joint for polythylene(PE) pipeline

International Nuclear Information System (INIS)

Lee, Euy Jong; Hur, Sam Suk; Chae, Gug Byeong

2006-01-01

The polyethylene(PE) pipes are widely used to transport city gas worldwide with steel pipes. Generally, Steel pipe are used for high pressure line and PE pipe for low pressure line whose pressure is less than 4 kg/m 2 . The steel pipe line are subject to 100 percent Radiographic Testing(RT) during installation stage, on the contrary, there has been no the established testing method for the welding fusion joint of polyethylene pipes, so all quality control is limited only Visual Testing(VT) or management of Fusion welding equipment. Even though PE pipeline is exposed to lower pressure than steel pipeline, the gas leakage from PE pipe may result in almost the same serious consequence from steel pipeline. So, it is necessary to develop the reliable testing standard for PE pipeline from the point of view of NDT engineers.

Amino acids grafting of Ar+ ions modified PE

International Nuclear Information System (INIS)

Svorcik, V.; Hnatowicz, V.; Stopka, P.; Bacakova, L.; Heitz, J.; Oechsner, R.; Ryssel, H.

2001-01-01

Polyethylene (PE) was irradiated with 63 keV Ar + ions to the fluences from 1x10 12 to 3x10 15 cm -2 and then grafted at room temperature from water solution with amino acids (alanine, leucine). Using various spectroscopic techniques (UV-VIS, FTIR, RBS and EPR) it was shown that the amino acids penetrate into PE where they are eventually captured either on double bonds or on free radicals created by the ion irradiation. Grafting with amino acids in the whole specimen layer modified by irradiation is observed. The ion-beam-modified and amino-acid grafted PE is supposed to exhibit increased biocompatibility. (author)

Image color reduction method for color-defective observers using a color palette composed of 20 particular colors

Science.gov (United States)

Sakamoto, Takashi

2015-01-01

This study describes a color enhancement method that uses a color palette especially designed for protan and deutan defects, commonly known as red-green color blindness. The proposed color reduction method is based on a simple color mapping. Complicated computation and image processing are not required by using the proposed method, and the method can replace protan and deutan confusion (p/d-confusion) colors with protan and deutan safe (p/d-safe) colors. Color palettes for protan and deutan defects proposed by previous studies are composed of few p/d-safe colors. Thus, the colors contained in these palettes are insufficient for replacing colors in photographs. Recently, Ito et al. proposed a p/dsafe color palette composed of 20 particular colors. The author demonstrated that their p/d-safe color palette could be applied to image color reduction in photographs as a means to replace p/d-confusion colors. This study describes the results of the proposed color reduction in photographs that include typical p/d-confusion colors, which can be replaced. After the reduction process is completed, color-defective observers can distinguish these confusion colors.

IR-IR Conformation Specific Spectroscopy of Na+(Glucose) Adducts

Science.gov (United States)

Voss, Jonathan M.; Kregel, Steven J.; Fischer, Kaitlyn C.; Garand, Etienne

2018-01-01

We report an IR-IR double resonance study of the structural landscape present in the Na+(glucose) complex. Our experimental approach involves minimal modifications to a typical IR predissociation setup, and can be carried out via ion-dip or isomer-burning methods, providing additional flexibility to suit different experimental needs. In the current study, the single-laser IR predissociation spectrum of Na+(glucose), which clearly indicates contributions from multiple structures, was experimentally disentangled to reveal the presence of three α-conformers and five β-conformers. Comparisons with calculations show that these eight conformations correspond to the lowest energy gas-phase structures with distinctive Na+ coordination. [Figure not available: see fulltext.

But I like PE: factors associated with enjoyment of physical education class in middle school girls.

Science.gov (United States)

Barr-Anderson, Daheia J; Neumark-Sztainer, Dianne; Schmitz, Kathryn H; Ward, Dianne S; Conway, Terry L; Pratt, Charlotte; Baggett, Chris D; Lytle, Leslie; Pate, Russell R

2008-03-01

The current study examined associations between physical education (PE) class enjoyment and sociodemographic, personal, and perceived school environment factors among early adolescent girls. Participants included 1,511 sixth-grade girls who completed baseline assessments for the Trial of Activity in Adolescent Girls, with 50% indicating they enjoyed PE class a lot. Variables positively associated with PE class enjoyment included physical activity level, perceived benefits of physical activity, self-efficacy for leisure time physical activity, and perceived school climate for girls' physical activity as influenced by teachers, while body mass index was inversely associated with PE class enjoyment. After adjusting for all variables in the model, PE class enjoyment was significantly greater in Blacks than in Whites. In model testing, with mutual adjustment for all variables, self-efficacy was the strongest correlate of PE class enjoyment, followed by perceived benefits, race/ethnicity, and teachers' support for girls' physical activity, as compared to boys, at school. The overall model explained 11% of the variance in PE class enjoyment. Findings suggest that efforts to enhance girls' self-efficacy and perceived benefits and to provide a supportive PE class environment that promotes gender equality can potentially increase PE class enjoyment among young girls.

Study of chromatic adaptation using memory color matches, Part I: neutral illuminants.

Science.gov (United States)

Smet, Kevin A G; Zhai, Qiyan; Luo, Ming R; Hanselaer, Peter

2017-04-03

Twelve corresponding color data sets have been obtained using the long-term memory colors of familiar objects as target stimuli. Data were collected for familiar objects with neutral, red, yellow, green and blue hues under 4 approximately neutral illumination conditions on or near the blackbody locus. The advantages of the memory color matching method are discussed in light of other more traditional asymmetric matching techniques. Results were compared to eight corresponding color data sets available in literature. The corresponding color data was used to test several linear (von Kries, RLAB, etc.) and nonlinear (Hunt & Nayatani) chromatic adaptation transforms (CAT). It was found that a simple two-step von Kries, whereby the degree of adaptation D is optimized to minimize the DEu'v' prediction errors, outperformed all other tested models for both memory color and literature corresponding color sets, whereby prediction errors were lower for the memory color sets. The predictive errors were substantially smaller than the standard uncertainty on the average observer and were comparable to what are considered just-noticeable-differences in the CIE u'v' chromaticity diagram, supporting the use of memory color based internal references to study chromatic adaptation mechanisms.

Study on IR Properties of Reduced Graphene Oxide

Science.gov (United States)

Ma, Deyue; Li, Xiaoxia; Guo, Yuxiang; Zeng, Yurun

2018-01-01

Firstly, the reduced graphene oxide was prepared by modified hummer method and characterized. Then, the complex refractive index of reduced graphene oxide in IR band was tested and its IR absorption and radiation properties were researched by correlated calculation. The results show that reduced graphene oxide prepared by hummer method are multilayered graphene with defects and functional groups on its surface. Its absorption in near and far IR bands is strong, but it’s weaker in middle IR band. At the IR atmosphere Window, its normal spectral emissivity decreases with wavelength increasing, and its total normal spectral emissivity in 3 ∼ 5μm and 8 ∼ 14μm are 0.75 and 0.625, respectively. Therefore, reduced graphene oxide can be used as IR absorption and coating materials and have a great potential in microwave and infrared compatible materials.

A validation study of the Keyboard Personal Computer Style instrument (K-PeCS) for use with children.

Science.gov (United States)

Green, Dido; Meroz, Anat; Margalit, Adi Edit; Ratzon, Navah Z

2012-11-01

This study examines a potential instrument for measurement of typing postures of children. This paper describes inter-rater, test-retest reliability and concurrent validity of the Keyboard Personal Computer Style instrument (K-PeCS), an observational measurement of postures and movements during keyboarding, for use with children. Two trained raters independently rated videos of 24 children (aged 7-10 years). Six children returned one week later for identifying test-retest reliability. Concurrent validity was assessed by comparing ratings obtained using the K-PECS to scores from a 3D motion analysis system. Inter-rater reliability was moderate to high for 12 out of 16 items (Kappa: 0.46 to 1.00; correlation coefficients: 0.77-0.95) and test-retest reliability varied across items (Kappa: 0.25 to 0.67; correlation coefficients: r = 0.20 to r = 0.95). Concurrent validity compared favourably across arm pathlength, wrist extension and ulnar deviation. In light of the limitations of other tools the K-PeCS offers a fairly affordable, reliable and valid instrument to address the gap for measurement of typing styles of children, despite the shortcomings of some items. However further research is required to refine the instrument for use in evaluating typing among children. Copyright © 2012 Elsevier Ltd and The Ergonomics Society. All rights reserved.

Environmental coupling and population dynamics in the PE545 light-harvesting complex

Energy Technology Data Exchange (ETDEWEB)

Aghtar, Mortaza; Kleinekathöfer, Ulrich, E-mail: u.kleinekathoefer@jacobs-university.de

2016-01-15

Long-lived quantum coherences have been shown experimentally in the Fenna–Matthews–Olson (FMO) complex of green sulfur bacteria as well as in the phycoerythrin 545 (PE545) photosynthetic antenna system of marine algae. A combination of classical molecular dynamics simulations, quantum chemistry and quantum dynamical calculations is employed to determine the excitation transfer dynamics in PE545. One key property of the light-harvesting system concerning the excitation transfer and dephasing phenomena is the spectral density. This quantity is determined from time series of the vertical excitation energies of the aggregate. In the present study we focus on the quantum dynamical simulations using the earlier QM/MM calculations as input. Employing an ensemble-averaged classical path-based wave packet dynamics, the excitation transfer dynamics between the different bilins in the PE545 complex is determined and analyzed. Furthermore, the nature of the environmental fluctuations determining the transfer dynamics is discussed. - Highlights: • Modeling of excitation energy transfer in the light-harvesting system PE545. • Combination of molecular dynamics simulations, quantum chemistry and quantum dynamics. • Spectral densities for bilins in the PE545 complex.

VUV photoemission studies of candidate Large Hadron Collider vacuum chamber materials

Directory of Open Access Journals (Sweden)

R. Cimino

1999-06-01

Full Text Available In the context of future accelerators and, in particular, the beam vacuum of the Large Hadron Collider (LHC, a 27 km circumference proton collider to be built at CERN, VUV synchrotron radiation (SR has been used to study both qualitatively and quantitatively candidate vacuum chamber materials. Emphasis is given to show that angle and energy resolved photoemission is an extremely powerful tool to address important issues relevant to the LHC, such as the emission of electrons that contributes to the creation of an electron cloud which may cause serious beam instabilities and unmanageable heat loads on the cryogenic system. Here we present not only the measured photoelectron yields from the proposed materials, prepared on an industrial scale, but also the energy and in some cases the angular dependence of the emitted electrons when excited with either a white light (WL spectrum, simulating that in the arcs of the LHC, or monochromatic light in the photon energy range of interest. The effects on the materials examined of WL irradiation and /or ion sputtering, simulating the SR and ion bombardment expected in the LHC, were investigated. The studied samples exhibited significant modifications, in terms of electron emission, when exposed to the WL spectrum from the BESSY Toroidal Grating Monochromator beam line. Moreover, annealing and ion bombardment also induce substantial changes to the surface thereby indicating that such surfaces would not have a constant electron emission during machine operation. Such characteristics may be an important issue to define the surface properties of the LHC vacuum chamber material and are presented in detail for the various samples analyzed. It should be noted that all the measurements presented here were recorded at room temperature, whereas the majority of the LHC vacuum system will be maintained at temperatures below 20 K. The results cannot therefore be directly applied to these sections of the machine until

Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy

Science.gov (United States)

Qu, Lei; Chen, Jian-bo; Zhang, Gui-Jun; Sun, Su-qin; Zheng, Jing

2017-03-01

As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p = 0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR.

Current Status and Prediction on Development of PE Market

Institute of Scientific and Technical Information of China (English)

Yu Jiao

2003-01-01

This article comprehensively analyzes the status of market demand/supply and import/export volumes of PE in the world and in China, and predicts the future development trends in the fields of PE production and consumption.

Magnet power supply control of the NSLS VUV and x-ray storage rings transfer lines

International Nuclear Information System (INIS)

Klein, J.D.; Ramamoorthy, S.; Singh, O.; Smith, J.D.

1985-01-01

The transfer lines for NSLS VUV and x-ray storage rings have been split. New power supplies have been incorporated with existing ones. The existing microprocessor system has been upgraded in order to control the additional functions. This system expands the input/output port of the microprocessor to an addressable serial/parallel link to each magnet power supply. The implementation of this system will be discussed

Whole-body distribution and radiation dosimetry of the dopamine transporter radioligand [11C]PE2I in healthy volunteers

International Nuclear Information System (INIS)

Ribeiro, Maria-Joao; Ricard, Marcel; Lievre, Marie-Angele; Bourgeois, Sandrine; Emond, Patrick; Gervais, Philippe; Dolle, Frederic; Syrota, Andre

2007-01-01

Introduction: This study reports on the biodistribution and radiation dosimetry of a cocaine analog, the (E)-N-(3-iodoprop-2-enyl)-2β-carbomethoxy-3β-(4'-tolyl)nortropane (PE2I), labeled with carbon 11 ([ 11 C]PE2I). [ 11 C]PE2I is used in positron emission tomography (PET) for examination of the dopamine neuronal transporter (DAT). DAT radioligands are often used to evaluate the progression of Parkinson's disease or the efficiency of neuroprotective therapeutics, and, typically, these studies required several successive PET scans. Methods: In three healthy male volunteers, whole-body scans were performed up to 2 h following intravenous injection of 321±6 MBq of [ 11 C]PE2I. For each subject, regions of interest were defined over all visible organs to generate time-activity curves and calculate the percentage of injected activity. Time-activity data were fitted to a monoexponential model, as an uptake phase followed by a mono-exponential washout, or bi-exponential model to obtain residence times. With the use of the MIRD method, several source organs were considered in estimating residence time and mean effective radiation absorbed doses. Results: Blood pressure and ECG findings remained unchanged after radioligand injection. The primary route of clearance was renal. Ten minutes after injection, high activities were observed in the kidneys, urinary-bladder, stomach, liver, salivary glands and brain. The urine bladder wall, stomach and liver received the highest absorbed doses. The average effective dose of [ 11 C]PE2I was estimated to be 6.4±0.6 μSv/MBq. Conclusion: The amount of [ 11 C]PE2I required for adequate DAT PET imaging results in an acceptable effective dose equivalent permitting two or three repeated cerebral PET studies, with the injection of 222 MBq for each study

Coupled Physics Environment (CouPE) library - Design, Implementation, and Release

Energy Technology Data Exchange (ETDEWEB)

Mahadevan, Vijay S. [Argonne National Lab. (ANL), Argonne, IL (United States)

2014-09-30

available computational resources. The design of CouPE along with motivations that led to implementation choices are also discussed. The first release of the library will be different from the current version of the code that integrates the components in SHARP and explanation on the need for forking the source base will also be provided. Enhancements in the functionality and improved user guides will be available as part of the release. CouPE v0.1 is scheduled for an open-­source release in December 2014 along with SIGMA v1.1 components that provide support for language-agnostic mesh loading, traversal and query interfaces along with scalable solution transfer of fields between different physics codes. The coupling methodology and software interfaces of the library are presented, along with verification studies on two representative fast sodium-­cooled reactor demonstration problems to prove the usability of the CouPE library.

Scintigraphic evidence for overdiagnosis of small PE on CT pulmonary angiography

International Nuclear Information System (INIS)

Lu, Yang

2017-01-01

A 68-year-old man with recent history of a fall presented with dyspnea on exertion, and underwent computed tomography pulmonary angiography (CTPA) for possible pulmonary embolism (PE). The CTPA was first read by the radiology resident as nondiagnostic for segmental PE. Subsequent planar perfusion (Q) images were normal; meanwhile, the attending radiologist revised the CTPA results as subsegmental PE in the left upper lobe. Further Q-SPECT images were obtained and fused with CTPA for clarification, which showed normal perfusion in the region of PE. The patient was monitored without anticoagulation treatment and remained uneventful for 12 months. This case illustrates that CTPA can lead to overdiagnosis and overtreatment of nonocclusive subsegmental PE

A semiclassical approach for two-color four-mode solid-state superfluorescence

International Nuclear Information System (INIS)

Lambruschini, C.L.P.

1991-05-01

A model for multilevel superfluorescence is presented. By using a parametric solution of this model we explain basic features in the two-color solid-state superfluorescence experiments of Florian, Schwan and Schmid. (author). 23 refs

Color transparency study group

International Nuclear Information System (INIS)

Appel, J.A.; Pordes, S.; Botts, J.; Bunce, G.; Farrar, G.

1990-01-01

The group studied the relatively new notion of color transparency, discussed present experimental evidence for the effect, and explored several ideas for future experiments. This write-up summarizes these discussions. 11 refs., 1 fig

Hybrid white organic light emitting diodes with low efficiency roll-off, stable color and extreme brightness

Energy Technology Data Exchange (ETDEWEB)

Liu, Baiquan; Zou, Jianhua [Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640 (China); State Key Laboratory of Luminescent Materials and Devices, Guangzhou 510640 (China); Su, Yueju; Gao, Dongyu [New Vision Opto-Electronic Technology Co., Ltd, Guangzhou 510640 (China); Lan, Linfeng [Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640 (China); State Key Laboratory of Luminescent Materials and Devices, Guangzhou 510640 (China); Tao, Hong, E-mail: tao.h@scut.edu.cn [Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640 (China); State Key Laboratory of Luminescent Materials and Devices, Guangzhou 510640 (China); Peng, Junbiao [Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640 (China); State Key Laboratory of Luminescent Materials and Devices, Guangzhou 510640 (China)

2014-07-01

Highly efficient and bright hybrid white organic light emitting diodes (WOLEDs) based on simple architectures have been successfully fabricated and characterized. The optimized device can reach a maximum forward-viewing power efficiency (PE) of 20.2 lm/W, a peak forward-viewing current efficiency (CE) of 30.7 cd/A, an extremely high brightness of 95,683 cd/m{sup 2}, and a Commission International de l’E clairage chromaticity coordinates of (0. 436, 0.425) at 12 V. Even at the illumination-relevant brightness of 1000 cd/m{sup 2}, a forward-viewing PE of 17.0 lm/W and CE of 30.7 cd/A are obtained. Moreover, it is found that the device not only suffers slight efficiency roll-off but also exhibits a stable color during a large range of brightness, indicating that the device can satisfy the future commercial requirements. Undoubtedly, the results will be beneficial to the design of both material and device architecture for high-performance WOLEDs and next-generation solid-state lighting sources. - Highlights: • A simple HWOLED with B/O/B structure has been successfully developed. • A extremely high brigthness of 95,683 cd/m{sup 2} is obtained. • A high forward-viewing CE of 30.7 cd/A and PE of 20.2 lm/W are achieved. • Efficiency roll-off is very low and color is relatively stable.

Effects of Art Therapy Using Color on Purpose in Life in Patients with Stroke and Their Caregivers

OpenAIRE

Kim, Mi Kyoung; Kang, Sung Don

2012-01-01

Purpose Patients with stroke suffer from physical disabilities, followed by mental instability. Their caregivers also suffer from mental instability. The present study attempted to address the degree and the change of the level of Purpose in Life (PIL) in patients with stroke and caregivers by applying art therapy using colors. Materials and Methods Twenty-eight stroke patients with a good functional recovery or a moderate disability and their 28 caregivers were selected and evaluated. The pe...

Physical Education Students' Ownership, Empowerment, and Satisfaction With PE and Physical Activity.

Science.gov (United States)

Moore, E Whitney G; Fry, Mary D

2017-12-01

Individuals experiencing a highly caring, task-involving, and low ego-involving exercise climate have reported greater ownership in exercise class and empowerment to exercise in general. This study examined the relationship between ownership and empowerment in exercise, with 2 context-specific outcomes, satisfaction with physical education (PE) and physical activity, respectively. Given the mission of PE to foster individuals' lifelong physical activity habit, the perceptions of high school students were collected for this study. Ownership in exercise was hypothesized to be significantly, positively correlated with students reporting satisfaction in PE more than their satisfaction in physical activity, whereas empowerment in exercise was hypothesized to be more strongly, positively correlated with students' physical activity satisfaction. A second purpose of this study was to test the measurement quality of the updated Empowerment in Exercise Scale (EES; now 13 items). High school students (N = 502, 43% female) in a Midwestern U.S. school district completed a survey. Confirmatory factor analysis supported the internal measurement structure of the EES (λ = .62-.91; McDonald's omega = .89) across student gender (strong invariance). Additionally, the structural equation modeling analysis revealed only 1 parameter moderated by the students' gender (latent mean of ownership). The hypotheses were supported, such that ownership in exercise was more strongly correlated with PE satisfaction (r = .87) and empowerment in exercise had a stronger correlation with physical activity satisfaction (r = .92). These results support the beneficial effect a satisfying experience in PE can have on students' satisfaction with physical activity outside of school.

Determination of ionization energies of CnN (n=4-12): Vacuum-ultraviolet (VUV) photoionization experiments and theoretical calculations

International Nuclear Information System (INIS)

Kostko, Oleg; Zhou, Jia; Sun, Bian Jian; Lie, Jie Shiuan; Chang, Agnes H.H.; Kaiser, Ralf I.; Ahmed, Musahid

2010-01-01

Results from single photon vacuum ultraviolet photoionization of astrophysically relevant CnN clusters, n = 4 - 12, in the photon energy range of 8.0 eV to 12.8 eV are presented. The experimental photoionization efficiency curves, combined with electronic structure calculations, provide improved ionization energies of the CnN species. A search through numerous nitrogen-terminated CnN isomers for n=4-9 indicates that the linear isomer has the lowest energy, and therefore should be the most abundant isomer in the molecular beam. Comparison with calculated results also shed light on the energetics of the linear CnN clusters, particularly in the trends of the even-carbon and the odd-carbon series. These results can help guide the search of potential astronomical observations of these neutral molecules together with their cations in highly ionized regions or regions with a high UV/VUV photon flux (ranging from the visible to VUV with flux maxima in the Lyman-a region) in the interstellar medium.

Gain length dependence on phase shake in the VUV-FEL at the TESLA Test Facility

Energy Technology Data Exchange (ETDEWEB)

Pflueger, J. [DESY/HASYLAB, Hamburg (Germany); Schneidmiller, E.A. [Automatic Systems Corporation, Samara (Russian Federation); Pierini, P. [INFN, Milano (Italy)

1995-12-31

The TTF VUV FEL, which is in its design stage at DESY, consists of a 30 m long SASE FEL which will radiate around 6 nm, driven by a superconducting linac with final energy of 1 GeV. One of the important issues in its design is the undulator performance, which is studied in this paper. The present setup, including FODO lattice, is discussed in this paper. Results of simulations, including the realistic wiggler field errors and beam stearing, are presented. Dependence of the performance, in particular the gain and saturation length as well as the saturation peak power, on the wiggler field errors is discussed.

Activity uniformity of Ir-192 seeds

International Nuclear Information System (INIS)

Ling, C.C.; Gromadzki, Z.C.

1981-01-01

A simple device that uses materials and apparatus commonly available in a radiotherapy department has been designed, fabricated and used in routine quality control relative to the activity uniformity of clinical Ir-192 seeds in ribbons. Detailed evaluation indicated that this system is easy to use and can yield relative activity measurements of individual Ir-192 seeds accurate to within 2%. With this device, activity uniformity of commercial Ir-192 seeds from two manufacturers has been assessed. For the seven shipments of Ir-192 seeds studied, the root mean square variations of individual seed strength from the average of each shipment ranged from 3.4 to 7.1%. Variation in seed activity by more than +- 10% from the average is not uncommon

Quantitative analyses of regional [{sup 11}C]PE2I binding to the dopamine transporter in the human brain: a PET study

Energy Technology Data Exchange (ETDEWEB)

Jucaite, Aurelija [Karolinska Institutet, Department of Woman and Child Health, Stockholm (Sweden); Odano, Ikuo [Niigata University, Department of Sensory and Integrative Medicine, Asahimachi-dori Niigata (Japan); Olsson, Hans; Pauli, Stefan; Halldin, Christer; Farde, Lars [Karolinska Institutet, Psychiatry Section, Department of Clinical Neuroscience, Stockholm (Sweden)

2006-06-15

The dopamine transporter (DAT) is a plasma membrane protein of central interest in the pathophysiology of neuropsychiatric disorders and is known to be a target for psychostimulant drugs. [{sup 11}C]PE2I is a new radioligand which binds selectively and with moderate affinity to central DAT, as has been demonstrated in vitro by autoradiography and in vivo by positron emission tomography (PET). The aims of the present PET study were to quantify regional [{sup 11}C]PE2I binding to DAT in the human brain and to compare quantitative methods with regard to suitability for applied clinical studies. One PET measurement was performed in each of eight healthy male subjects. The binding potential (BP) values were obtained by applying kinetic compartment analysis, which uses the metabolite-corrected arterial plasma curve as an input function. They were compared with the BP values quantified by two reference tissue approaches, using cerebellum as a reference region representing free and non-specific radioligand binding. The radioactivity concentration was highest in the striatum, lower in the midbrain and very low in the cerebellum. The regional [{sup 11}C]PE2I binding could be interpreted by kinetic compartment models. However, the BP values in the striatum obtained by the compartment analyses were about 30% higher than the BP values obtained using reference tissue methods. We suggest that the difference may be explained by the inaccurate metabolite correction, small amounts of radioactive metabolites that could account for the presence of non-specific binding in the cerebellum and insufficient data acquisition time. (orig.)

Labour Market in Lithuania: Gender Situation Darbo rinka Lietuvoje: moterų ir vyrų padėtis

Directory of Open Access Journals (Sweden)

Jūratė Guščinskienė

2011-02-01

Full Text Available

The article analyses the situation of men and women in the labour market in the globalization and economic integration into the European Union conditions and demonstrates that gender equality under the current conditions and social life, politics and economy is becoming a political priority. The aim of the paper is: to analyze the situation of men and women in the labour market and its regulation; to study the respondents’ view on the situation of men and women in the labour market. Empirical study showed that 42% of women and 26% of men have never lost their jobs and the people who have, have men-tioned several reasons for this. Respondents, both women and men, generally lose work because of inadequate working conditions and the company’s bankruptcy. Meanwhile, the response of men’s and women’s opinion on the inequality/discrimination experience is different. According to women, involved in the study, in Lithuania they mostly experienced discrimination based on sex and age, while men consider to be most discriminated on grounds of sex, disability and age. Almost one fifth of the respondents have personally experienced discrimination themselves in the labour market because of sex.

Keywords: labour market, equal opportunities, discrimination, employment, entrepre-neurship.

color: black; font-size: 10pt;">Reguliuojant Europos Sąjungos (ES plėtros tolesnę ekonominę politiką daugiausia dėmesio skiriama darbo rinkai ir pirmiausia – moterų ir vyrų lygioms galimyb

VUV/UV light inducing accelerated phenol degradation with a low electric input† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6ra26043h Click here for additional data file.

Science.gov (United States)

Li, Mengkai; Wen, Dong

2017-01-01

This study presents the first evidence for the accelerated degradation of phenol by Fenton's reagent in a mini-fluidic VUV/UV photoreaction system (MVPS). A low-pressure mercury lamp used in the MVPS led to a complete degradation of phenol within 4–6 min. The HO˙ and HO2˙ originating from both Fenton's reagent and VUV photolysis of water were identified with suitable radical scavengers. The effects of initial concentrations of phenol, H2O2 and Fe3+ as well as solution pH on phenol degradation kinetics were examined. Increasing the initial phenol concentration slowed down the phenol degradation, whereas increasing the initial H2O2 or Fe3+ concentration accelerated the phenol degradation. The optimal solution pH was 3.7. At both 254 and 185 nm, increasing phenol concentration enhanced its absorption for the incident photons. The reaction mechanism for the degradation of phenol was suggested consistent with the results obtained. This study indicates that the VUV/UV photo-Fenton process has potential applications in the treatment of industrial wastewater containing phenol and related aromatic pollutants. PMID:28496972

Non-isothermal irradiation creep of nickel alloys Inconel 706 and PE-16

International Nuclear Information System (INIS)

Gilbert, E.R.; Chin, B.A.

1984-06-01

The results of in-reactor step temperature change experiments conducted on two nickel alloys, PE-16 and Inconel 706, were evaluated to determine the creep behavior under nonisothermal conditions. The effect of the temperature changes was found to be significantly different for the two alloys. Following a step temperature change, the creep rate of PE-16 adjusted to the rate found in isothermal tests at the new temperature. In contrast for Inconel 706, a reduction in temperature from 540 to 425 0 C produced a 300% increase in creep above that measured at 540 0 C in isothermal tests. The response of in-reactor creep in Inconel 706 to temperature changes was attributed to the dissolution of the gamma double-prime phase and subsequent loss of precipitation-strengthening at temperatures below 500 C

Results of the speleological exploration on Pešter plateau

Directory of Open Access Journals (Sweden)

Nešić Dragan

2015-01-01

Full Text Available During the period 2006-2008, basic speleological research was done on Pešter Plateau in Southwestern Serbia. On that occasion, 40 caves were surveyed, 11 of which were measured in detail. Registered caves were grouped on the basis of landscape characteristics and morphogenetic relations. Based on the location and general characteristics of the Pešter karst, it is considered that the objects near Boljare and in the ponor (sinking area of Boroštica are connected to the drainage system of the Pećina nad Vražjim firovima (Vražiji firovi Cave. In morphological terms, the cave Bezdan Kaćunova ravan (Kaćunova Cave near Boljare with its imposing hall is the most important object on Pešter Plateau for the time being. Realized research on Pešter Plateau has the character of basic or initial speleological research, which should be continued in order to solve different problems of karst in this area.

VUV emission spectroscopy diagnostics of a 14 GHz ECR negative hydrogen ion source

Energy Technology Data Exchange (ETDEWEB)

Tamura, R., E-mail: duo0364@mail4.doshisha.ac.jp; Ichikawa, T.; Kasuya, T.; Wada, M. [Graduate School of Science and Engineering, Doshisha University, Kyotanabe, Kyoto 610-0394 (Japan); Nishiura, M. [Graduate School of Frontier Sciences The University of Tokyo, Kashiwara, Chiba 277-8561 (Japan); Shimozuma, T. [National lnstitute for Fusion Science, Toki, Gifu 509-5292 (Japan)

2015-04-08

Vacuum Ultra Violet(VUV) emission from a 4 cm diameter 2 cm long compact ion source excited by 14 GHz microwave has been investigated. Intensity ratio of band spectrum emission near Ly-α to Ly-α line spectrum is determined from the measured spectrum. which shows preferential excitation of molecules near the entrance of microwave input power. The ratio does not depend strongly upon pressure nor the input microwave power when the intensity is integrated over the volume of the plasma. The spatial distribution of the spectrum intensity ratio exhibits concentrations near microwave inlet and the opposite side where the microwave matching structure is located. The ratio at these peripheral regions is about two times as high as that of the central region. The ratio increased in proportion to the ion source pressure up to about 3.0 Pa, indicating efficient production of high energy electrons by ECR up to this pressure.

Performan reproduksi pada persilangan Kambing Boer dan Peranakan Etawah (PE

Directory of Open Access Journals (Sweden)

F. Parasmawati

2014-02-01

Full Text Available The study tends to evaluate the reproductive performances of Boer x PE goats crossbred in field laboratory “Sumber Sekar” of the Faculty of Animal Husbandry, Brawijaya University. Data covered the reproductive performance from 2010 – 2012 including data from 23 multipaorous does (11 does of pure Boer goats, 12 does of Boer x PE crossbred. The results shows that service per conception (S/C of the pure Boer was 3.09 ± 1.57 and 2.75± 1.35 for the crossbred (P>0.05. The days open (DO of the Boer goat was 202.71 ± 95.56 days this was not significantly difference to the crossbred goats (208.04 ±137.51days. The kidding interval (316.84 ± 125.64 days vs. 360.45 ± 148.96 days and the litter size (1.78 ±0.71 vs. 1.70 ± 0.86 were not significantly difference (P>0.05 between the respective groups. In conclusion, the crossing program between male Boer goats and male PE does did not influence the reproductive performances in both goats (pure Boer goats and their crosses with local PE goats. Key words: litter size, service per conception, days open, kidding interval, litter size

Infrared color gradient in the inner coma of Comet Halley

International Nuclear Information System (INIS)

Campins, H.; Rieke, M.J.; Rieke, G.H.

1989-01-01

A well-defined gradient is noted in the J-H and H-K colors of near-IR images obtained for Comet Halley in November, 1985, within about 8000 km of the nucleus; the bluest colors are at the photocenter, in conjunction with surface brightness profiles that are steeper than those expected. The color gradient and the brightness profiles are both explainable by the present analysis in terms of the presence of volatile, dirty-ice grains in the inner coma. An outburst of Rayleigh-scattering dust particles (unsupported by spacecraft measurements obtained to date) may also account for the observational data. 27 references

Performan reproduksi pada persilangan Kambing Boer dan Peranakan Etawah (PE)

OpenAIRE

F. Parasmawati; Suyadi Suyadi; Sri Wahyuningsih

2014-01-01

The study tends to evaluate the reproductive performances of Boer x PE goats crossbred in field laboratory “Sumber Sekar” of the Faculty of Animal Husbandry, Brawijaya University. Data covered the reproductive performance from 2010 – 2012 including data from 23 multipaorous does (11 does of pure Boer goats, 12 does of Boer x PE crossbred). The results shows that service per conception (S/C) of the pure Boer was 3.09 ± 1.57 and 2.75± 1.35 for the crossbred (P>0.05). The days open (DO) of the B...

Performan Reproduksi Pada Persilangan Kambing Boer Dan Peranakan Etawah (PE)

OpenAIRE

Parasmawati, F; Suyadi, Suyadi; Wahyuningsih, Sri

2013-01-01

The study tends to evaluate the reproductive performances of Boer x PE goats crossbred in field laboratory “Sumber Sekar” of the Faculty of Animal Husbandry, Brawijaya University. Data covered the reproductive performance from 2010 – 2012 including data from 23 multipaorous does (11 does of pure Boer goats, 12 does of Boer x PE crossbred). The results shows that service per conception (S/C) of the pure Boer was 3.09 ± 1.57 and 2.75± 1.35 for the crossbred (P>0.05). The days open (DO) of th...

Cryogenic readout for multiple VUV4 Multi-Pixel Photon Counters in liquid xenon

Science.gov (United States)

Di Giovanni, A.

2018-03-01

This work concerned the preliminary tests and characterization of a cryogenic preamplifier board for an array made of 16 S13370-3050CN (VUV4 family) Multi-Pixel Photon Counters manufactured by Hamamatsu and operated at liquid xenon temperature. The proposed prototype is based on the use of the Analog Devices AD8011 current feedback operational amplifier. The detector allows for single photon detection, making this device a promising choice for the future generation of neutrino and dark matter detectors based on liquid xenon targets.

The New P.E.

Science.gov (United States)

Vandertie, Joan; Corner, Amy B.; Corner, Kevin J.

2012-01-01

Marana Middle School in Tucson, Ariz., scrapped its traditional P.E. program that emphasized team sports and shifted to a program that focuses on lifetime fitness, student choice in activities, and nutrition and health education. The program also includes student leadership development and informal community service. As a result, Marana students…

A UV to mid-IR study of AGN selection

Energy Technology Data Exchange (ETDEWEB)

Chung, Sun Mi; Kochanek, Christopher S. [Department of Astronomy, The Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Assef, Roberto [Núcleo de Astronomía de la Facultad de Ingeniería, Universidad Diego Portales, Av. Ejército Libertador 441, Santiago (Chile); Brown, Michael J. I. [School of Physics, Monash University, Clayton, Vic 3800 (Australia); Stern, Daniel [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Mail Stop 169-221, Pasadena, CA 91109 (United States); Jannuzi, Buell T. [Department of Astronomy and Steward Observatory, University of Arizona, Tucson, AZ 85721 (United States); Gonzalez, Anthony H. [Department of Astronomy, University of Florida, Gainesville, FL 32611 (United States); Hickox, Ryan C. [Department of Physics and Astronomy, Dartmouth College, 6127 Wilder Laboratory, Hanover, NH 03755 (United States); Moustakas, John [Department of Physics and Astronomy, Siena College, 515 Loudon Road, Loudonville, NY 12211 (United States)

2014-07-20

We classify the spectral energy distributions (SEDs) of 431,038 sources in the 9 deg{sup 2} Boötes field of the NOAO Deep Wide-Field Survey (NDWFS). There are up to 17 bands of data available per source, including ultraviolet (GALEX), optical (NDWFS), near-IR (NEWFIRM), and mid-infrared (IRAC and MIPS) data, as well as spectroscopic redshifts for ∼20,000 objects, primarily from the AGN and Galaxy Evolution Survey. We fit galaxy, active galactic nucleus (AGN), stellar, and brown dwarf templates to the observed SEDs, which yield spectral classes for the Galactic sources and photometric redshifts and galaxy/AGN luminosities for the extragalactic sources. The photometric redshift precision of the galaxy and AGN samples are σ/(1 + z) = 0.040 and σ/(1 + z) = 0.169, respectively, with the worst 5% outliers excluded. On the basis of the χ{sub ν}{sup 2} of the SED fit for each SED model, we are able to distinguish between Galactic and extragalactic sources for sources brighter than I = 23.5 mag. We compare the SED fits for a galaxy-only model and a galaxy-AGN model. Using known X-ray and spectroscopic AGN samples, we confirm that SED fitting can be successfully used as a method to identify large populations of AGNs, including spatially resolved AGNs with significant contributions from the host galaxy and objects with the emission line ratios of 'composite' spectra. We also use our results to compare with the X-ray, mid-IR, optical color, and emission line ratio selection techniques. For an F-ratio threshold of F > 10, we find 16,266 AGN candidates brighter than I = 23.5 mag and a surface density of ∼1900 AGN deg{sup –2}.

Validity and reproducibility of HOMA-IR, 1/HOMA-IR, QUICKI and McAuley's indices in patients with hypertension and type II diabetes.

Science.gov (United States)

Sarafidis, P A; Lasaridis, A N; Nilsson, P M; Pikilidou, M I; Stafilas, P C; Kanaki, A; Kazakos, K; Yovos, J; Bakris, G L

2007-09-01

The aim of this study was to evaluate the validity and reliability of homeostasis model assessment-insulin resistance (HOMA-IR) index, its reciprocal (1/HOMA-IR), quantitative insulin sensitivity check index (QUICKI) and McAuley's index in hypertensive diabetic patients. In 78 patients with hypertension and type II diabetes glucose, insulin and triglyceride levels were determined after a 12-h fast to calculate these indices, and insulin sensitivity (IS) was measured with the hyperinsulinemic euglycemic clamp technique. Two weeks later, subjects had again their glucose, insulin and triglycerides measured. Simple and multiple linear regression analysis were applied to assess the validity of these indices compared to clamp IS and coefficients of variation between the two visits were estimated to assess their reproducibility. HOMA-IR index was strongly and inversely correlated with the basic IS clamp index, the M-value (r=-0.572, PHOMA-IR and QUICKI indices were positively correlated with the M-value (r=0.342, PHOMA-IR was the best fit of clamp-derived IS. Coefficients of variation between the two visits were 23.5% for HOMA-IR, 19.2% for 1/HOMA-IR, 7.8% for QUICKI and 15.1% for McAuley's index. In conclusion, HOMA-IR, 1/HOMA-IR and QUICKI are valid estimates of clamp-derived IS in patients with hypertension and type II diabetes, whereas the validity of McAuley's index needs further evaluation. QUICKI displayed better reproducibility than the other indices.

Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy.

Science.gov (United States)

Qu, Lei; Chen, Jian-Bo; Zhang, Gui-Jun; Sun, Su-Qin; Zheng, Jing

2017-03-05

As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p=0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR. Copyright © 2016 Elsevier B.V. All rights reserved.

Implementation of the Service for Radiological Emergency Response of CRCN-NE/CNEN-PE, Recife, PE, Brazil

International Nuclear Information System (INIS)

Menezes, Claudio J.M.

2005-01-01

In 1998, it was created in the Centro Regional de Ciencias Nucleares (CRCN-NE) - the Brazilian regional center of nuclear sciences -, Recife, PE, Brazil, the Service for Radiological Emergency Response with the objective of providing the population of Pernambuco and neighboring States a team of professionals specialized in emergency situations and radiological protection. This action has the purpose of decentralization of actions of the Brazilian National Nuclear Energy Commission (CNEN), an agency responsible for licensing and safety of radioactive sources in Brazil. With this study we can conclude that the settlement of SAER/CRCN came to meet initial expectations, having in the last years provided assistance in situations with suspected radioactive material and participated actively: with radioactive load simulation; of the Exercicio de Emergencia Aeronautica Completo (EXEAC) - an emergency simulated training in airports- from the Guararapes-Gilberto Freire Airport; trained, every two years, the services of emergency for accidents and participated in events of the area

Spectrally resolved measurements of the terahertz beam profile generated from a two-color air plasma

DEFF Research Database (Denmark)

Pedersen, Pernille Klarskov; Zalkovskij, Maksim; Strikwerda, Andrew

2014-01-01

Using a THz camera and THz bandpass filters, we measure the frequency - resolved beam profile emitted from a two - color air plasma. We observe a frequency - independent emission angle from the plasma .......Using a THz camera and THz bandpass filters, we measure the frequency - resolved beam profile emitted from a two - color air plasma. We observe a frequency - independent emission angle from the plasma ....

Dimensões irônicas em Ricardo III, de Shakespeare

Directory of Open Access Journals (Sweden)

Pedro Piccoli Garcia

2017-12-01

Full Text Available Analisa-se, no artigo, as diferentes formas com que a ironia se efetiva em um texto literário. Parte-se do pressuposto de que a ironia configura, ao mesmo tempo, uma figura de linguagem, como uma sentença que anula a si mesma na medida em que orienta o leitor a rejeitar seu significado literal; e uma visão de mundo, na medida em que implica uma postura de negação de uma realidade. À luz dos preceitos de D.C. Muecke e Søren Kierkegaard, busca-se identificar as dimensões irônicas da peça Ricardo III, de William Shakespeare, e refletir acerca delas.

EUV-VUV photochemistry in the upper atmospheres of Titan and the early Earth

Science.gov (United States)

Imanaka, H.; Smith, M. A.

2010-12-01

Titan, the organic-rich moon of Saturn, possesses a thick atmosphere of nitrogen, globally covered with organic haze layers. The recent Cassini’s INMS and CAPS observations clearly demonstrate the importance of complex organic chemistry in the ionosphere. EUV photon radiation is the major driving energy source there. Our previous laboratory study of the EUV-VUV photolysis of N2/CH4 gas mixtures demonstrates a unique role of nitrogen photoionization in the catalytic formation of complex hydrocarbons in Titan’s upper atmosphere (Imanaka and Smith, 2007, 2009). Such EUV photochemistry could also have played important roles in the formation of complex organic molecules in the ionosphere of the early Earth. It has been suggested that the early Earth atmosphere may have contained significant amount of reduced species (CH4, H2, and CO) (Kasting, 1990, Pavlov et al., 2001, Tian et al., 2005). Recent experimental study, using photon radiation at wavelengths longer than 110 nm, demonstrates that photochemical organic haze could have been generated from N2/CO2 atmospheres with trace amounts of CH4 or H2 (Trainer et al., 2006, Dewitt et al., 2009). However, possible EUV photochemical processes in the ionosphere are not well understood. We have investigated the effect of CO2 in the possible EUV photochemical processes in simulated reduced early Earth atmospheres. The EUV-VUV photochemistry using wavelength-tunable synchrotron light between 50 - 150 nm was investigated for gas mixtures of 13CO2/CH4 (= 96.7/3.3) and N2/13CO2/CH4 (= 90/6.7/3.3). The onsets of unsaturated hydrocarbon formation were observed at wavelengths shorter than the ionization potentials of CO2 and N2, respectively. This correlation indicates that CO2 can play a similar catalytic role to N2 in the formation of heavy organic species, which implies that EUV photochemistry might have significant impact on the photochemical generation of organic haze layers in the upper atmosphere of the early Earth.

Increase in the temperature of a laser plasma formed by two-frequency UV - IR irradiation of metal targets

International Nuclear Information System (INIS)

Antipov, A A; Grasyuk, Arkadii Z; Efimovskii, S V; Kurbasov, Sergei V; Losev, Leonid L; Soskov, V I

1998-01-01

An experimental investigation was made of a laser plasma formed by successive irradiation of a metal target with 30-ps UV and IR laser pulses. The UV prepulse, of 266 nm wavelength, was of relatively low intensity (∼ 10 12 W cm -2 ), whereas the intensity of an IR pulse, of 10.6 μm wavelength, was considerably higher (∼3 x 10 14 W cm -2 ) and it was delayed by 0 - 6 ns (the optimal delay was 2 ns). Such two-frequency UV - IR irradiation produced a laser plasma with an electron temperature 5 times higher than that of a plasma created by singe-frequency IR pulses of the same (∼3 x 10 14 W cm -2 ) intensity. (interaction of laser radiation with matter. laser plasma)

On the chiral perturbation theory for two-flavor two-color QCD at finite chemical potential

Czech Academy of Sciences Publication Activity Database

Brauner, Tomáš

2006-01-01

Roč. 21, č. 7 (2006), s. 559-569 ISSN 0217-7323 R&D Projects: GA ČR(CZ) GD202/05/H003 Institutional research plan: CEZ:AV0Z10480505 Keywords : two-color QCD * chiral perturbation theory * chemical potential Subject RIV: BE - Theoretical Physics Impact factor: 1.564, year: 2006

Whole-School Management Issues Concerning the PE Department: "A Natural Division of Labour?"

Science.gov (United States)

Williams, Gareth Mark; Williams, Dean

2013-01-01

Utilising the labour ideas of Adam Smith and Emile Durkheim as a theoretical basis, the main objective of this study was to investigate the perception that Heads of Physical Education (HoPE) face unique management and leadership challenges. Results showed that HoPE believe that they are overburdened with tasks primarily involving the delegation of…

Proton and electron impact on molecular and atomic oxygen: I. High resolution fluorescence spectra in the visible and VUV spectral range and emission cross-sections for dissociative ionisation and excitation of O2

International Nuclear Information System (INIS)

Wilhelmi, O.; Schartner, K.H.

2000-01-01

For pt.II see ibid., vol.11, p.45-58, 2000. Molecular oxygen O 2 was dissociated in collisions with protons and electrons in the intermediate velocity range (p + -energies: 17-800 keV, e - -energies: 0.2-2 keV). Fluorescence from excited atomic and singly ionised fragments and from singly ionised molecules was detected in the VUV and in the visible and near UV spectral range. Highly resolved spectra are presented for the VUV (46-131 nm) and the near UV/visible (340-605 nm) spectral range. Absolute emission cross-sections have been determined for dissociative ionisation and excitation leading to fluorescence in the VUV. Results are compared with published data. (orig.)

Whole-body distribution and radiation dosimetry of the dopamine transporter radioligand [{sup 11}C]PE2I in healthy volunteers

Energy Technology Data Exchange (ETDEWEB)

Ribeiro, Maria-Joao [Service Hospitalier Frederic Joliot, Institut d' Imagerie Biomedicale, Direction des Sciences du Vivant, Commissariat a l' Energie Atomique, F-91406 Orsay (France)]. E-mail: maria-joao.ribeiro@cea.fr; Ricard, Marcel [Service de Physique, Institut Gustave Roussy, 39 rue Camille Desmoulins, 94805 Villejuif (France); Lievre, Marie-Angele [Service Hospitalier Frederic Joliot, Institut d' Imagerie Biomedicale, Direction des Sciences du Vivant, Commissariat a l' Energie Atomique, F-91406 Orsay (France); Bourgeois, Sandrine [Service Hospitalier Frederic Joliot, Institut d' Imagerie Biomedicale, Direction des Sciences du Vivant, Commissariat a l' Energie Atomique, F-91406 Orsay (France); Emond, Patrick [INSERM U316, Laboratoire de Biophysique medicale et pharmaceutique, UFR des Sciences Pharmaceutiques, 37200 Tours (France); Gervais, Philippe [Service Hospitalier Frederic Joliot, Institut d' Imagerie Biomedicale, Direction des Sciences du Vivant, Commissariat a l' Energie Atomique, F-91406 Orsay (France); Dolle, Frederic [Service Hospitalier Frederic Joliot, Institut d' Imagerie Biomedicale, Direction des Sciences du Vivant, Commissariat a l' Energie Atomique, F-91406 Orsay (France); Syrota, Andre [Service Hospitalier Frederic Joliot, Institut d' Imagerie Biomedicale, Direction des Sciences du Vivant, Commissariat a l' Energie Atomique, F-91406 Orsay (France)

2007-05-15

Introduction: This study reports on the biodistribution and radiation dosimetry of a cocaine analog, the (E)-N-(3-iodoprop-2-enyl)-2{beta}-carbomethoxy-3{beta}-(4'-tolyl)nortropane (PE2I), labeled with carbon 11 ([{sup 11}C]PE2I). [{sup 11}C]PE2I is used in positron emission tomography (PET) for examination of the dopamine neuronal transporter (DAT). DAT radioligands are often used to evaluate the progression of Parkinson's disease or the efficiency of neuroprotective therapeutics, and, typically, these studies required several successive PET scans. Methods: In three healthy male volunteers, whole-body scans were performed up to 2 h following intravenous injection of 321{+-}6 MBq of [{sup 11}C]PE2I. For each subject, regions of interest were defined over all visible organs to generate time-activity curves and calculate the percentage of injected activity. Time-activity data were fitted to a monoexponential model, as an uptake phase followed by a mono-exponential washout, or bi-exponential model to obtain residence times. With the use of the MIRD method, several source organs were considered in estimating residence time and mean effective radiation absorbed doses. Results: Blood pressure and ECG findings remained unchanged after radioligand injection. The primary route of clearance was renal. Ten minutes after injection, high activities were observed in the kidneys, urinary-bladder, stomach, liver, salivary glands and brain. The urine bladder wall, stomach and liver received the highest absorbed doses. The average effective dose of [{sup 11}C]PE2I was estimated to be 6.4{+-}0.6 {mu}Sv/MBq. Conclusion: The amount of [{sup 11}C]PE2I required for adequate DAT PET imaging results in an acceptable effective dose equivalent permitting two or three repeated cerebral PET studies, with the injection of 222 MBq for each study.

Lifetime predictions for dimmable two-channel drivers for color tuning luminaires

Energy Technology Data Exchange (ETDEWEB)

Davis, Lynn [RTI International, Research Triangle Park, NC (United States); Smith, Aaron [Finelite Inc., Union City, CA (United States); Clark, Terry [Finelite Inc., Union City, CA (United States); Mills, Karmann [RTI International, Research Triangle Park, NC (United States); Perkins, Curtis [RTI International, Research Triangle Park, NC (United States)

2017-05-30

Two-channel tunable white lighting (TWL) systems represent the next wave of solid-state lighting (SSL) systems and promise flexibility in light environment while maintaining the high reliability and luminous efficacy expected with SSL devices. TWL systems utilize LED assemblies consisting of two different LED spectra (i.e., often a warm white assembly and a cool white assembly) that are integrated into modules. While these systems provide the ability to adjust the lighting spectrum to match the physiology needs of the task at hand, they also are a potentially more complex lighting system from a performance and reliability perspective. We report an initial study on the reliability performance of such lighting systems including an examination of the lumen maintenance and chromaticity stability of warm white and cool white LED assemblies and the multi-channel driver that provides power to the assemblies. Accelerated stress tests including operational bake tests conducted at 75°C and 95°C were used to age the LED modules, while more aggressive temperature and humidity tests were used for the drivers in this study. Small differences in the performance between the two LED assemblies were found and can be attributed to the different phosphor chemistries. The lumen maintenances of both LED assemblies were excellent. The warm white LED assemblies were found to shift slightly in the green color direction over time while the cool white LED assemblies shifted slightly in the yellow color direction. The net result of these chromaticity shifts is a small, barely perceptible reduction in the tuning range after 6,000 hours of exposure to an accelerating elevated temperature of 75°C.

Inhibition of PTP1B Restores IRS1-Mediated Hepatic Insulin Signaling in IRS2-Deficient Mice

Science.gov (United States)

González-Rodríguez, Águeda; Gutierrez, Jose A. Mas; Sanz-González, Silvia; Ros, Manuel; Burks, Deborah J.; Valverde, Ángela M.

2010-01-01

OBJECTIVE Mice with complete deletion of insulin receptor substrate 2 (IRS2) develop hyperglycemia, impaired hepatic insulin signaling, and elevated gluconeogenesis, whereas mice deficient for protein tyrosine phosphatase (PTP)1B display an opposing hepatic phenotype characterized by increased sensitivity to insulin. To define the relationship between these two signaling pathways in the regulation of liver metabolism, we used genetic and pharmacological approaches to study the effects of inhibiting PTP1B on hepatic insulin signaling and expression of gluconeogenic enzymes in IRS2−/− mice. RESEARCH DESIGN AND METHODS We analyzed glucose homeostasis and insulin signaling in liver and isolated hepatocytes from IRS2−/− and IRS2−/−/PTP1B−/− mice. Additionally, hepatic insulin signaling was assessed in control and IRS2−/− mice treated with resveratrol, an antioxidant present in red wine. RESULTS In livers of hyperglycemic IRS2−/− mice, the expression levels of PTP1B and its association with the insulin receptor (IR) were increased. The absence of PTP1B in the double-mutant mice restored hepatic IRS1-mediated phosphatidylinositol (PI) 3-kinase/Akt/Foxo1 signaling. Moreover, resveratrol treatment of hyperglycemic IRS2−/− mice decreased hepatic PTP1B mRNA and inhibited PTP1B activity, thereby restoring IRS1-mediated PI 3-kinase/Akt/Foxo1 signaling and peripheral insulin sensitivity. CONCLUSIONS By regulating the phosphorylation state of IR, PTB1B determines sensitivity to insulin in liver and exerts a unique role in the interplay between IRS1 and IRS2 in the modulation of hepatic insulin action. PMID:20028942