Relação cinemática em um trator 4x2 com tração dianteira auxiliar equipado com pneus radiais na eficiência de tração Kinematic relation on radial tires in a front wheel assist tractor on traction efficience

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Mauro Fernando Ferreira

2000-12-01

Full Text Available Diferentes combinações de pressões internas dos pneus do trator pode afetar a interferência entre eixos motrizes dos tratores agrícolas, principalmente com pneus do tipo radial. Um trator 4x2 com tração dianteira auxiliar foi analisado quanto a seu desempenho em tração. Pneus de carcaça radial com diferentes pressões internas foram utilizados, com o objetivo de variar as relações cinemá ticas entre os eixos. Mediram-se o patinamento das rodas dianteiras e traseiras, a resistência ao rolamento e a força de tração, em duas condições de solo (firme e solto. Os resultados obtidos permitiram verificar que a eficiência de tração não foi significativamente influenciada pela variação das relações cinemáticas de 0,962 a 1,102. As máximas eficiências de tração ocorreram com relaçõ es cinemáticas variáveis dentro da faixa estudada e de acordo com as cargas impostas à barra de tração.Different combinations of tractor tire inflating pressure may affect interference between tractor axles, mainly with radial tires type. A front wheel assist tractor was studied in its traction performance. Radial tires with different inflation pressure were used, changing kinematic relations between axles. The measured parameters were: front and rear slip, rolling resistence and drawbar pull in two soil conditions (firm and loose. The results indicate that traction efficience was not significantly influenced by kinematic relations variation between 0.962 to 1.102. The maximum traction efficiency ocurred within the range studied and according to drawbar pull.

Desempenho de um trator em função do tipo de pneu, da lastragem e da velocidade de trabalho Performance of an tractor as a function of tire type, ballasting and forward speed

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Afonso Lopes

2005-04-01

Full Text Available O trabalho comparou o desempenho de um trator agrícola 4x2 TDA de 89 kW (121cv em função do tipo de pneus (radial, diagonal e de baixa pressão, a condição de lastragem (com e sem água nos pneus e quatro velocidades [V1 (1,84km h-1, V2 (3,18km h-1, V3 (4,57km h-1, V4 (5,04km h-1]. O experimento foi realizado na UNESP-Jaboticabal-SP, em condição de preparo do solo com escarificador de sete hastes a 30cm de profundidade. Os pneus foram do tipo R1, com as seguintes características: [radial (dianteiros-14.9 R 26; traseiros-620/75 R 30 diagonal (dianteiros-14.9-26, traseiros-23.1-30 e BPAF (dianteiros-500/60-26.5; traseiros-700/55-34]. O delineamento experimental foi blocos casualizados, em esquema fatorial 3x2x4, com 24 tratamentos e três repetições. Os resultados evidenciaram vantagens para o trator equipado com pneus radiais.The objective of this study was to compare the performance of the FWD agricultural tractor, equipped with three types of tires (bias ply, radial and low pressure, with and without tire water ballasting, operating in four forward speed. The research was carried out at UNESP, SP, Brazil, with the tractor pulling a chisel plow. A tractor with 89kW (121cv engine power equipped with FWD, was used in the experiment, and the tires used had the following characteristics: radial (front: 14.9R26 and rear: 620/75R30, bias ply (front: 14.9-26 and rear: 23.1-30 and low pressure (front: 500/60-26.5 and rear: 700/55-34. The experiment was conducted in a completely randomized block, design (3x2x4, with 24 treatments and three replications. The results evidenced advantages for the tractor equipped with radial tires.

Prioridades de requisitos para projeto de postos de operação de tratores quanto à ergonomia e segurança Requirement priorities for the design of tractor workplaces related to ergonomics and safety

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Paula Machado dos Santos

2008-07-01

Full Text Available O objetivo deste trabalho foi identificar as prioridades de requisitos de projeto, de postos de operação de tratores agrícolas do mercado nacional brasileiro, conforme as normas de ergonomia e segurança. Compuseram a amostragem os tratores agrícolas de pneus de borracha novos, com bitola externa superior a 1.150 mm, sem quaisquer alterações em suas características originais por parte do fabricante ou revendedor, em comercialização em território nacional, quanto à disposição interna dos comandos de operação, aos assentos e aos acessos dos postos de operação. Como análise comparativa dos requisitos dos clientes destas máquinas e, conseqüentemente, a hierarquização dos requisitos necessários ao projeto de postos de operação, que são atendidos pelos fabricantes de tratores agrícolas, foram utilizadas as ferramentas para o desenvolvimento de projetos diagrama de Mudge e a primeira matriz do "quality function deployment", respectivamente. As marcas de tratores agrícolas nacionais apresentam a mesma prioridade quanto ao atendimento aos requisitos de projeto de ergonomia e segurança em postos de operação. O assento representa a prioridade de maior ordem, seguido dos comandos e, em última posição, os acessos.The objective of this work was to characterize the requirement priorities for workplace design of agricultural tractors of the national market, as per standards of ergonomics and safety. The patterns were composed by agricultural new tractors rubber tires, with minimum gauge of 1,150 mm, without any alterations in their original characteristics on the part of the manufacturer or reselling, in commercialization in national territory, related to the internal disposition of the operation commands, to the seats and to the accesses of the workplaces. As comparative analysis of the customer requirements for of these machines and, consequently, the hierarchization of the necessary requirements for the project of workplaces

Características ergonômicas dos tratores agrícolas utilizados na região central do Rio Grande do Sul Ergonomic characteristics of agricultural tractors used in central region of Rio Grande do Sul State, Brazil

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Henrique Debiasi

2004-12-01

Full Text Available A utilização de tratores agrícolas com boas condições ergonômicas reduz a probabilidade de ocorrência de acidentes e doenças ocupacionais, aumentando a eficiência dos trabalhadores. Neste trabalho, objetivou-se verificar a presença de itens relacionados à ergonomia de tratores agrícolas usados, bem como avaliar o comportamento destas características em função do tempo de uso das referidas máquinas. Foram analisados 175 tratores agrícolas pertencentes às microrregiões gaúchas de Santa Maria, Restinga Seca e Cachoeira do Sul, presentes em 114 propriedades aleatoriamente amostradas. Os resultados mostraram que apenas 3% dos espécimes avaliados eram equipados com cabina, sendo que a maior parte dos mesmos não apresentava isolamento do calor gerado pelo motor e transmissão. Com relação à ergonomia dos comandos, mais de 70% dos tratores tinham alavancas de câmbio centrais, enquanto que apenas 8% eram equipados com volante de direção regulável. Da mesma forma, mais de 20% dos exemplares amostrados possuíam bancos sem estofamento. Além disso, a presença dos itens avaliados foi menor para os tratores mais antigos.It is possible to reduce the probability of work accidents, diseases occurrence and increase the work efficiency using agricultural tractors with good ergonomic conditions. The objective of this research was to verify the presence of ergonomic items in used agricultural tractors and also to evaluate the influence of tractor age in these characteristics. 175 agricultural tractors belonging to 3 regions of Rio Grande do Sul State (Santa Maria, Restinga Seca and Cachoeira do Sul, Brazil, present in 114 farms randomly sampled, were evaluated. The results showed that only 3% of sampled specimens were equipped with a cab, and most part of the tractors did not have protection against the heat produced by tractor transmission and engine. With regard to ergonomics of commands, more than 70% of the tractors had gear levers

Desempenho operacional de trator com tração dianteira auxiliar na subsolagem de um inceptisol Performance of a front wheel drive tractor in the subsoiling operation in an inceptisol

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Neyton de Oliveira Miranda

2000-04-01

Full Text Available Na subsolagem de um solo da ordem dos Inceptisol (Cambissolos usando um trator com tração dianteira auxiliar, foram comparados pneus de duas idades, duas rotações do motor e duas marchas, além do uso ou não do bloqueio do diferencial. Mediram-se velocidade de deslocamento, patinagem das rodas traseiras, tempo operacional teórico e consumo de combustível por hora e por área trabalhada. O uso do bloqueio do diferencial não influiu significativamente em nenhum parâmetro estudado e o de pneus novos resultou em desempenho do trator superior em relação aos pneus desgastados, para todos os parâmetros estudados. A rotação do motor de 1.800 rpm reduziu a patinagem e o consumo de combustível por hora e por área trabalhada em relação a 2.000 rpm, enquanto o uso da quarta marcha reduziu o tempo operacional teórico e o consumo de combustível por área trabalhada em relação à terceira marcha.In the subsoiling operation in an Inceptisol with a front wheel drive tractor, worn and new tyres, two engine speeds, two gear ratios and the use or not of the differential lock, were compared. Travel speed, rear wheel slip, theoretical field time, and fuel consumption per hour as well as per worked area were measured. The differential lock did not influence significantly any studied parameter. New tires were superior to worn ones for all parameters. Engine speed of 1800 rpm reduced wheel slip, fuel consumption per hour and per hectare compared with 2000 rpm. Fourth gear reduced the theoretical field time and fuel consumption per hectare compared to third gear.

Operando research in heterogeneous catalysis

CERN Document Server

Groot, Irene

2017-01-01

This book is devoted to the emerging field of techniques for visualizing atomic-scale properties of active catalysts under actual working conditions, i.e. high gas pressures and high temperatures. It explains how to understand these observations in terms of the surface structures and dynamics and their detailed interplay with the gas phase. This provides an important new link between fundamental surface physics and chemistry, and applied catalysis. The book explains the motivation and the necessity of operando studies, and positions these with respect to the more traditional low-pressure investigations on the one hand and the reality of industrial catalysis on the other. The last decade has witnessed a rapid development of new experimental and theoretical tools for operando studies of heterogeneous catalysis. The book has a strong emphasis on the new techniques and illustrates how the challenges introduced by the harsh, operando conditions are faced for each of these new tools. Therefore, one can also read th...

Pressão de insuflagem dos pneus no desempenho do conjunto trator-grade de discos Tire inflation pressure effects on tractor disc harrow performance

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João Manuel Pereira Ramalho Serrano

2008-02-01

Full Text Available O objetivo deste trabalho foi avaliar o efeito da pressão de insuflagem dos pneus nos parâmetros de desempenho do conjunto trator-grade de discos. As pressões avaliadas foram: 100 kPa nos pneus da frente e 70 kPa nos pneus atrás; 140 kPa nos quatro pneus; 190 kPa nos quatro pneus. Os testes de um trator com grades de discos foram desenvolvidos em condições de campo, em solos de textura franca, mobilizados e secos. Os parâmetros de avaliação foram: o patinamento, a velocidade, a capacidade de trabalho, a eficiência energética global e o consumo de combustível por hectare. Entre as situações de pressão de insuflagem dos pneus indicadas pelo fabricante do trator e a pressão de insuflagem indicada pelo fabricante dos pneus, não se verificam diferenças significativas, tanto na capacidade de trabalho como no consumo de combustível por hectare. A utilização de elevadas pressões de insuflagem dos pneus conduz a uma redução da ordem de 3 a 5% na capacidade de trabalho e um aumento significativo entre 10 e 25% do consumo de combustível por hectare, mesmo em condições de boa aderência dos pneus, refletidas no intervalo de 7 a 15% de patinamento registrados.The objective of this work was to evaluate the tire inflation pressure effects on tractor disc harrow performance. The pressures tested were: 100 kPa in front tires and 70 kPa in rear tires; 140 kPa in the tires of both axles; 190 kPa in the tires of both axles. Field tests with disc harrow in secondary tillage were performed under real working conditions, in tilled and dry medium textured soils. The evaluation parameters were: the slip, the actual forward speed, the work capacity, the overall energy efficiency and the fuel consumption per hectare. Concerning the situations of tire inflation pressure specified by the tractor manufacturer and the inflation pressure specified by the tire manufacturer, there were no significant differences, both in work capacity and in fuel

Análise comparativa do peso específico dos tratores agrícolas fabricados no Brasil e seus efeitos sobre a seleção e uso

OpenAIRE

Schlosser José Fernando; Debiasi Henrique; Willes Jorge Alex; Machado Otávio Dias da C.

2005-01-01

O peso do trator influi diretamente na recomendação e no seu desempenho a campo. Esta variável é, muitas vezes, característica do fabricante, induzindo a necessidade de informações comparativas entre os modelos. O objetivo deste trabalho foi estudar os tratores agrícolas brasileiros no que se refere ao peso, visando obter dados que auxiliem na seleção e no seu uso adequado. O levantamento englobou 103 modelos de tratores comerciais das marcas Massey Ferguson, Agrale, New Holland, John Deere, ...

Avaliação de alguns fatores ergonômicos nos tratores "Feller-buncher" e "Skidder" utilizados na colheita de madeira Evaluation of some ergonomic factors in Feller-buncher and Skidder tractors used in wood harvesting

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Julião Soares de Souza Lima

2005-04-01

Full Text Available Este trabalho foi realizado com tratores florestais utilizados em um sistema mecanizado de colheita de madeira em povoamento de eucalipto, tendo como objetivo avaliar quantiqualitativamente as dimensões de acesso, assento, comandos, campo visual, condições térmicas e vibração no posto dos operadores. O acesso ao posto do operador no trator "Feller-buncher" apresentou um grau de dificuldade, sendo classificado, na avaliação qualitativa, como médio e, no "Skidder", como bom. A abertura das portas de acesso apresenta ângulo menor que 90º, dificultando, assim, a entrada e saída do operador. O posto do operador do trator "Feller-buncher" foi classificado como médio na avaliação qualitativa, em virtude de o espaço livre da plataforma de apoio ser de 30% da área total e, no "Skidder", de 55% da área total, sendo classificado como bom. O campo visual frontal do "Feller-buncher", mesmo tendo uma área do pára-brisa maior, é limitado pela presença do cabeçote, tanto em operações diurnas quanto noturnas, sendo, portanto, inferior ao do "Skidder".This work was carried out in forest tractors used in a mechanized system for wood harvesting in a stand of eucalyptus, to evaluate quanti-qualitatively the dimensions of access, seat, commands, field view, thermal conditions and vibration in the operators' station. The access to the operator's station in the Feller-Buncher tractor presented a degree of difficulty classified in the qualitative evaluation as average and the Skidder as good. The opening of the access doors presents an angle smaller than 90º, thus rendering the entrance and exit of the operator more difficult. The operators station of the Feller-Buncher tractor was classified as medium in the qualitative evaluation, due to the free space of the support platform being 30% of the total area, and in the Skidder 55%, therefore being classified as good. The front field view in Feller-Buncher, even having a wider windscreen area, is

Utilização de um sistema de aquisição automática de dados para avaliação dos níveis de ruído de um trator agrícola de pneus Utilization of a data automatic acquisition system for noise level evaluation of an agricultural tractor with tires

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Paulo Fernando dos Santos Filho

2004-06-01

Full Text Available Este trabalho foi realizado na Faculdade de Engenharia de Guaratinguetá (FEG-UNESP, SP, no Laboratório de Vibração e Acústica, e numa área experimental localizada no município de Guaratinguetá, com os objetivos de determinar os níveis de ruído emitidos por um trator agrícola executando a operação de gradagem em diferentes velocidades de trabalho e analisar o conforto do operador, comparando os níveis obtidos com os recomendados pelas principais normas vigentes. Na avaliação dos níveis de ruído, utilizaram-se um trator de pneus de 55,2 kW (75 cv e uma grade destorroadora-niveladora "off-set" de 28 discos. O sistema de aquisição de dados foi constituído por sensores de ruído, condicionadores e amplificadores e um conversor analógico-digital instalados em um microcomputador e embarcados no trator ensaiado. Posteriormente, os dados foram tratados pelo Programa ORIGIN 50. Com base nos resultados, concluiu-se que o sistema trator-implemento emitiu níveis de ruído acima dos limites estipulados pelas normas, em todas as velocidades testadas.A study was carried out at the Faculdade de Engenharia de Guaratinguetá -FEG-UNESP, SP, in the acoustics and vibration laboratory as well as in an experimental area located in Guaratinguetá county. The objectives were to determine the noise levels emitted by an agricultural tire tractor during harrowing operation at different speeds and analyze the operator's comfort, by comparing the actual levels with the main effective norms. When evaluating noise levels, a 55.2 kW (75 hp tire tractor and an off-set 28-disk harrow were used. The data acquisition system consisted of some noise sensors, conditioners, amplifiers, and a digital-analogical converter plugged to a microcomputer and connected to the tractor tested. Later, the software ORIGIN 50 treated the data. Based on the obtained results, it was concluded that the noise levels emitted by the tractor-implement system exceeded the limits

Desempenho operacional de um trator agrícola equipado alternadamente com pneus radiais e diagonais Operational performance of an agricultural tractor equipped alternately with radial and diagonal tires

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Jackson A. Barbosa

2005-08-01

Full Text Available A utilização de pneu radial em tratores agrícolas na década de 1950 resultou em redução das perdas de potência oriundas da resistência ao rolamento e patinagem, com conseqüente melhoria no desenvolvimento da tração. Este trabalho teve como objetivo comparar o desempenho operacional de um trator agrícola equipado alternadamente com pneus radiais e diagonais. A avaliação foi realizada a partir de análises de parâmetros indicadores do desempenho dos referidos pneus sob condições específicas de trabalho. O uso de pneus radiais proporcionou incrementos nos valores de capacidade de tração e potência na barra, diminuição nos valores de consumo específico de combustível e não causou variações no consumo horário de combustível.The use of radial tire in agricultural tractors in the decade of 1950 resulted in the reduction of the potency losses originated from the rolling resistance and slippage, with consequent improvement in the traction development. This work had as objective to compare the operational performance of an agricultural tractor, equipped alternately with radial and diagonal tires. The evaluation was accomplished, starting from analyses of indicative parameters of the performance of the referred tires under specific conditions of work. The use of radial tires provided increments in the values of traction capacity and drawbar pull, decrease in values of specific consumption of fuel, and didn't cause variations in the hourly consumption of fuel.

Desempenho de um trator agrícola de pneus, funcionando com misturas de óleo diesel e óleo de soja reutilizado

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Wagner da Cunha Siqueira

2011-10-01

Full Text Available No Brasil, a forma de energia alternativa mais atraente tem sido a biomassa e, mais recentemente, os óleos vegetais residuais e in natura. Portanto, objetivou-se, com este trabalho, avaliar o desempenho na tomada de potência de um trator agrícola de pneus, utilizando misturas de óleo Diesel (OD com óleo de soja reutilizádo (OSR. Primeiramente, foi realizado um estudo de densidade das misturas, comportamento da temperatura do óleo Diesel no sistema de alimentação de combustível do motor e análises de viscosidades das misturas em estudo. Após as análises, verificou-se, por meio de ensaios dinamométricos, o desempenho do motor alimentado com misturas de OD com OSR, em diferentes proporções. As principais conclusões deste trabalho foram: a para as avaliações na tomada de potência, a mistura de 25% OD com 75% OSR apresentou a maior potência entre as demais misturas; b o consumo especifico e os torques demonstraram tendência a maiores valores com o acréscimo da percentagem de OSR às misturas.

Desempenho na barra de tração de um trator agrícola de pneus, alimentado com misturas de óleo diesel e óleo de soja reutilizado

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Wagner da Cunha Siqueira

2013-12-01

Full Text Available O petróleo é a principal fonte de energia para motores de combustão interna, possibilitando sua transformação em energia mecânica. A dependência do petróleo conduz à necessidade de alternativas, mediante o cultivo de matérias-primas renováveis. Os problemas atuais são os custos dos biocombustíveis, que são maiores que dos derivados do petróleo, e o fato de que não existem muitos motores de combustão adequados ao uso de óleos vegetais. Em vista disso, são necessárias mais investigações quanto às técnicas de produção e de refino dos biocombustíveis e, ainda, à adequação de motores ao uso de óleos vegetais, para que estes possam ser uma alternativa viável. O objetivo deste trabalho foi caracterizar as diferentes misturas e avaliar o desempenho de um trator agrícola de pneus, utilizando misturas de óleo Diesel (OD com óleo de soja reutilizável (OSR. Primeiramente, foi realizado um estudo de densidade, viscosidade das misturas e comportamento da temperatura do OD no sistema de alimentação de combustível no motor. Após as análises, verificou-se, por meio de ensaios na barra de tração, o desempenho das misturas de OD e OSR. As principais conclusões deste trabalho foram: a densidade e viscosidade das misturas sofrem variações com o aumento da quantidade de OSR e com a variação da temperatura. Para as avaliações na barra de tração, os melhores resultados observados no rendimento do trator foram verificados com o aumento das percentagens de mistura (25% OSR, para carga N, 25, 75 e 100% OSR, para a quarta marcha, como carga, e 75 e 100% OSR, para a terceira, segunda e primeira marcha, como carga.

An electrochemical cell for <em>in operando sem>tudies of lithium/sodium batteries using a conventional x-ray powder diffractometer

DEFF Research Database (Denmark)

Shen, Yanbin; Pedersen, Erik Ejler; Christensen, Mogens

2014-01-01

An electrochemical cell has been designed for powder X-ray diffraction (PXRD) studies of lithium ion batteries (LIB) and sodium ion batteries (SIB) in operando with high time resolution using conventional powder X-ray diffractometer. The cell allows for studies of both anode and cathode electrode...... to operate and maintain. Test examples on lithium insertion/extraction in two spinel-type LIB electrode materials (Li4Ti5O12 anode and LiMn2O4 cathode) are presented as well as first results on sodium extraction from a layered SIB cathode material (Na0.84Fe0.56Mn0.44O2)....

Desempenho de um motor de trator agrícola em bancada dinamométrica com biodiesel de óleo de frango e misturas binárias com óleo diesel Performance of an agricultural tractor engine in dynamometer with chicken oil biodiesel and binary mixtures with diesel oil

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Diego Augusto Fiorese

2012-04-01

Full Text Available O Brasil, terceiro maior produtor de biodiesel do mundo e terceiro maior produtor mundial de frango, pode incrementar, na sua matriz energética, o uso de óleo oriundo de aves como alternativa aos combustíveis fósseis e à redução da dependência do óleo de soja para esse fim. O país dispõe de mais de 350 milhões de litros de óleo de frango por ano. Considerando a aplicação dos combustíveis alternativos para os motores a diesel, em máquinas agrícolas, o trabalho teve por objetivo avaliar o desempenho do motor de um trator agrícola de 53kW acoplado pela TDP em bancada dinamométrica, operando com biodiesel metílico de óleo de frango e misturas com óleo diesel, sendo: B5 (testemunha, B20, B40, B60, B80 e B100. Avaliaram-se a potência, o torque, a reserva de torque, o consumo de combustível, o consumo de energia e a eficiência térmica do motor. O ensaio foi instalado com delineamento inteiramente casualizado (DIC em esquema fatorial com seis tratamentos. Os resultados foram submetidos à análise de variância e as médias ajustadas por equações de regressão. Foram observadas perdas na geração de potência e torque, aumento no consumo de combustível, redução do consumo energético e melhoria na eficiência térmica do motor, de acordo com o aumento da proporção de biodiesel na mistura.Brazil, the world third largest producer of biodiesel, and also the third largest producer of chicken, may increase the energy matrix, using oil derived from chicken, as an alternative to fossil fuels and reduce dependence on soybean oil for this purpose. The country can produce over 350 million liters of chicken oil per year. Considering the application of alternative fuels on diesel engines in agricultural machinery. The study aimed to evaluate the performance of a engine agricultural tractor with 53kW coupled by PTO in dynamometer bench operating with methyl biodiesel oil chicken and mix with diesel oil. Fuels B5 (reference, B20, B

ANÁLISE DOS PARÂMETROS DE FUNCIONAMENTO E SIMULAÇÃO COMPUTACIONAL EM UM PROTÓTIPO DE TURBINA OPERANDO A AR COMPRIMIDO

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Wesley Saldanha Nogueira Oliveira

2016-12-01

Full Text Available RESUMO. Este trabalho apresenta os resultados iniciais da comparação de alguns parâmetros de funcionamento do protótipo de uma turbina de ação simples, operando com ar comprimido como fluido de trabalho, realizados na unidade do SENAI de Barra do Piraí/RJ. O protótipo foi desenvolvido integralmente no Centro Universitário Geraldo Di Biase - UGB - Campus de Barra do Piraí/RJ, que inicialmente teve como o fluido de trabalho o vapor d’água, que nos testes inicias se mostrou ineficiente. A simulação computacional do sistema foi feita através do software SolidWorks na Universidade Federal Fluminense - UFF - Campus de Volta Redonda/RJ, o que permitiu determinar a faixa de trabalho que apresentou maior eficiência nos resultados experimentais do sistema por meio da relação entre pressão de operação, velocidade angular transmitida pelo fluido ao eixo da turbina e a potência da mesma. Os valores nas simulações em velocidade tangencial na região rotacional apresentaram-se convergentes aos valores experimentais medidos no protótipo.

AVALIAÇÃO DO NÍVEL DE RUÍDO, ITENS DE SEGURANÇA E ERGONOMIA EM TRATORES AGRÍCOLAS / NOISE LEVEL EVALUATION, ITEMS SECURITY AND ERGONOMIC IN AGRICULTURAL TRACTORS

OpenAIRE

M. M. Baesso; M. Gazzola; S. Bernardes; E. Brandelero; A. Modolo

2015-01-01

O ruído das máquinas agrícolas, com o passar do tempo, pode provocar problemas auditivos nos operadores. De acordo com as normas regulamentadoras do Ministério do Trabalho e Emprego (NR 15), a exposição diária máxima permitida, durante uma jornada de trabalho de 8 horas, é de 85 decibels (dB (A)). Baseado neste contexto, este trabalho teve como objetivo avaliar os níveis de ruído emitidos por 12 tratores agrícolas de diferentes modelos e potências, bem como avaliar a existência de itens de er...

Sistema de controle de velocidade sincronizada entre dois veículos agrícolas Synchronized speed control system between two agricultural vehicles

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Rodrigo Fernando Galzerano Baldo

2012-02-01

Full Text Available Este trabalho apresenta uma proposta para o controle automático de velocidade entre dois veículos que necessitam trafegar em paralelo durante operações agrícolas. É descrito o desenvolvimento e os testes de campo de um sistema de controle de velocidade para um trator escravo baseado na velocidade de um trator mestre, utilizando um controlador desenvolvido em lógica fuzzy. Para esses testes, os tratores foram instrumentados com GPS, encoder, computador e transmissor de radiofrequência, sendo instalado ainda no trator escravo um motor de passo para o controle da velocidade de deslocamento. Para avaliar o sistema, realizaram-se dois testes: no primeiro, a resposta do trator escravo à variação de velocidade foi avaliada a partir de simulações de variação na velocidade de entrada; no segundo, foram utilizados dois tratores variando a velocidade do trator mestre e observando a resposta do trator escravo. No primeiro teste, o trator escravo acompanhou a simulação da variação da velocidade com um erro quadrático médio (EQM não significativo e erro médio percentual (EMP máximo de 1,3%. No segundo teste, o trator escravo acompanhou a variação de velocidade do trator mestre com o (EMP de deslocamento variando em módulo de 0,2% a 2,9%.This paper presents a proposal for automatic speed control of vehicles that requires working in synchronism with each other during agricultural operations. It describes the development and field tests of a control system for a slave tractor based on the master tractor speed, using a fuzzy controller. For the tests the master tractor was instrumented with GPS, encoders, computer and radio transmitter. The slave tractor was instrumented in the same way, and included also a stepper motor to act on the tractor throttle. To evaluate the system two tests were conducted. In the first, the master tractor speed was simulated using only the slave tractor. In the second test, two tractors were used varying the

Desenvolvimento de metodologia para previsão do fenômeno de vibrações decorrentes da interferência entre eixos de um trator com tração dianteira auxiliar (TDA Development of methodology to predict power hop of the axle interference of a front wheel assist tractor (FWA

Directory of Open Access Journals (Sweden)

José Fernando Schlosser

2001-12-01

Full Text Available Foi desenvolvido um ensaio de campo com o objetivo de avaliar as condições da ocorrência do fenômeno do "galope" do trator, que consiste em vibrações de baixa freqüência e grande amplitude. Este fenômeno físico é muito comum nos tratores de tração integral, principalmente nos que possuem pneus de diferentes diâmetros no eixo dianteiro e traseiro. Para provocar o "galope", determinaram-se diferentes condições de distribuição de peso, pressão interna dos pneus e da magnitude da carga na barra de tração. Ao final dos ensaios, determinaram-se as condições de ocorrência do fenômeno por meio de uma metodologia bastante simples em função dos raios dos pneus. O método utilizado para a determinação das condições de ocorrência do galope foi plenamente satisfatório, pois pôde prever com bastante precisão as condições em que iria ocorrer o fenômeno.A field experiment was carried out to evaluate the conditions for the appeareance of the power hope phenomenon. It consists in low frequency vibrations and great amplitude. This physical phenomenon is very common in FWA tractors, mainly with unequal tires diameter in front and rear axle. To promote power hope, different weight distribution conditions, different tire pressure and different drawbar force were used. Power hope occurence conditions were determined using simple methodology, which uses tire radio in the calculations.

Requirement priorities for the design of tractor workplaces related to ergonomics and safety

OpenAIRE

Santos, Paula Machado dos; Schlosser, José Fernando; Romano, Leonardo Nabaes; Rozin, Dinorvan; Turatti, Jeferson da Costa; Witter, Maiquel

2008-01-01

O objetivo deste trabalho foi identificar as prioridades de requisitos de projeto, de postos de operação de tratores agrícolas do mercado nacional brasileiro, conforme as normas de ergonomia e segurança. Compuseram a amostragem os tratores agrícolas de pneus de borracha novos, com bitola externa superior a 1.150 mm, sem quaisquer alterações em suas características originais por parte do fabricante ou revendedor, em comercialização em território nacional, quanto à disposição interna dos comand...

Need for In Operando Characterization of Electrochemical Interface Features

DEFF Research Database (Denmark)

Traulsen, Marie Lund; Chatzichristodoulou, Christodoulos; Hansen, Karin Vels

2015-01-01

and changing experimental conditions with respect to electrical, structural and chemical properties at the nano-scale. Going through the various known techniques, it becomes clear that there are not sufficient in operando techniques available to make a comprehensive electrode characterization, and therefore...... during the recent 2 decades. This progress has to a large extent been based on combination of electrochemical characterization and in situ and in operando and in situ surface analysis techniques, which so far have been less developed for high temperature electrochemistry above 300 °C. In spite...... that such techniques have only recently started becoming available for SOC electrochemistry, they are strongly needed. The high temperature solid-solid and solid-gas interfaces tend to change a lot over time due to segregation of electrolyte and electrode constituents and unavoidable trace impurities on a level of few...

Need for In Operando Characterization of Electrochemical Interface Features

DEFF Research Database (Denmark)

Traulsen, Marie Lund; Chatzichristodoulou, Christodoulos; Hansen, Karin Vels

2015-01-01

The problems of understanding the electrode reaction kinetics and in particular the degradation of the kinetics destroying the electrode performance, is briefly described. This is followed by an analysis of information that is needed and which knowledge may be acquired by available in operando...

Equipamento para medição do consumo de combustível em experimentos agrícolas

OpenAIRE

Gonzalez Maziero,José Valdemar; Corrêa,Ila Maria; Yanai,Kiyoshi; Menezes,João Floriano de

1992-01-01

É descrito e aferido (em condições de laboratório) um equipamento para medição de consumo de combustível para uso em experimentos com máquinas agrícolas. O medidor, construído com tubos-reservatórios de PVC, tubo de vidro graduado, tanque plástico de combustível e eletroválvulas (12 VCC), é ligado ao sistema de alimentação do trator com mangueiras de plástico de baixa pressão, controlando-se o fluxo de combustível mediante uma chave elétrica liga/desliga. Faz parte do conjunto um medidor de t...

Manutenção de tratores agrícolas e condição técnica dos operadores

OpenAIRE

Reis,Gustavo N. dos; Lopes,Afonso; Furlani,Carlos E. A.; Silva,Rouverson P. da; Grotta,Danilo C. C.; Câmara,Felipe T. da

2005-01-01

A manutenção dos tratores agrícolas pode ser considerada um conjunto de procedimentos que visa a manter o equipamento nas melhores condições de funcionamento, propiciando aumento da vida útil, evitando danos prematuros, eliminando os já observados e concorrendo para maior segurança no trabalho. Essa conduta, apesar de simples, exige atenção e cuidado semelhante ou até maior quando comparado a outro veículo automotor. O presente trabalho teve por objetivo analisar a regularidade e a qualidade ...

Avaliação técnica do trator florestal arrastador "skidder" com diferentes tipos de rodados na extração de madeira em povoamentos de pinus Technical evalution of a skidder with different wheeled types in log extraction activies of pine plantation

Directory of Open Access Journals (Sweden)

Eduardo da Silva Lopes

2007-12-01

Full Text Available Este trabalho teve como principal objetivo a avaliação técnica das atividades de extração de madeira usando tratores florestais arrastadores skidders equipados com rodado de pneus e com rodado de pneus recoberto com semi-esteiras. A avaliação técnica consistiu em determinar os índices de produtividade da operação de extração da madeira por meio de um estudo de tempos e movimentos, em que a operação foi dividida em fases do ciclo de trabalho. Foram determinadas as produtividades das máquinas em diferentes situações de distâncias de extração e declividades de terreno. Os resultados indicaram que o tempo médio do ciclo operacional do skidder com rodado de pneus foi 7,1% menor em relação ao skidder de pneus recobertos por esteiras, o que explicado se pela maior eficiência dos pneus sobre a superfície do terreno. O skidder de pneus apresentou melhor eficiência na situação de declividade entre 10 e 20%, devido à maior agilidade do rodado de pneus e capacidade em desenvolver maior velocidade, enquanto o skidder com rodado de pneus recoberto por esteiras apresentou velocidade operacional constante. Em declividade acima de 20%, o skidder de pneus recoberto com esteiras realizou normalmente o arraste da madeira, enquanto o skidder de pneus não entrou em operação devido à elevada patinagem dos pneus e diminuição da capacidade de tração.The objective of this study was to evaluate technical log extraction activities using a skidder with tires and a skidder with tracks over the tires. Technical evaluation consisted in determining log extraction productivity indexes based on motion and time study, in which the extraction activities were grouped into work cycle phases. Machine productivity was determined in different extraction distances and slope degree situations. The results showed that the operational cycle average time of the tire skidder was 7.1% smaller that the skidder with tracks over the tires, explained by the

Quantitative operando visualization of the energy band depth profile in solar cells.

Science.gov (United States)

Chen, Qi; Mao, Lin; Li, Yaowen; Kong, Tao; Wu, Na; Ma, Changqi; Bai, Sai; Jin, Yizheng; Wu, Dan; Lu, Wei; Wang, Bing; Chen, Liwei

2015-07-13

The energy band alignment in solar cell devices is critically important because it largely governs elementary photovoltaic processes, such as the generation, separation, transport, recombination and collection of charge carriers. Despite the expenditure of considerable effort, the measurement of energy band depth profiles across multiple layers has been extremely challenging, especially for operando devices. Here we present direct visualization of the surface potential depth profile over the cross-sections of operando organic photovoltaic devices using scanning Kelvin probe microscopy. The convolution effect due to finite tip size and cantilever beam crosstalk has previously prohibited quantitative interpretation of scanning Kelvin probe microscopy-measured surface potential depth profiles. We develop a bias voltage-compensation method to address this critical problem and obtain quantitatively accurate measurements of the open-circuit voltage, built-in potential and electrode potential difference.

Desempenho de trator-implemento na cana-de-açúcar em sistemas de plantio direto e convencional Tractor-implement performance in sugarcane under no-tillage and conventional planting systems

Directory of Open Access Journals (Sweden)

José B. Duarte Júnior

2008-12-01

Full Text Available Com este trabalho objetivou-se avaliar o desempenho de conjuntos mecanizados, através da patinagem, da velocidade do trator e da viabilidade de operação de plantio da cana-de-açúcar (Saccharum sp. em sistema de plantio direto (SPD e convencional (PC sobre diferentes plantas de cobertura. O delineamento experimental utilizado foi o inteiramente casualizado (DIC, com três repetições, em esquema de faixas. Constituíram-se 24 tratamentos pelas combinações de parcelas: A1-PD da cana sobre crotalária; a²-PD da cana sobre feijão de porco; A3-PC da cana sobre mucuna preta incorporada; A4-PC da cana (testemunha; de subparcelas: B1-FORD 8430 DT + plantadora de duas linhas; B2-FORD 8430 DT + sulcador de três linhas; B3-FORD 5610 + sulcador de duas linhas; e de sub-subparcelas: C1 - 1ª marcha reduzida e C2 - 2ª marcha reduzida. Observou-se que as operações de sulcagem para posterior plantio manual ou sulcagem e plantio mecanizado da cana-de-açúcar em SPD sobre as plantas de cobertura sem serem manejadas anteriormente com roçadora ou rolo-faca, foram possíveis e igualmente eficientes quando comparadas ao PC, portanto, é possível reduzir o tempo de implantação da cultura e os custos operacionais devido à diminuição do número de operações no SPD da cana-de-açúcar.This research evaluated the performance of automated groups using slippage, tractor speed, and operational viability of planting sugarcane (Saccharum spp. in no-tillage (SPD and conventional (PC systems under different plant coverings. The experimental design was completely randomized, using three repetitions in a split-split plot. There were twenty four treatments: A1-SPD the sugarcane on sunnhemp (Crotalaria juncea; a²-SPD the sugarcane on the jack bean (Canavalia ensiformis; A3-PC the sugarcane on incorporated black mucuna (Stilozobium aterrimum; A4-PC the sugarcane (control; sub-plots: B1-FORD 8430 DT + two row crop planter; B2-FORD 8430 DT + three lines furrow

Anthropometrics applied to the agricultural tractors operators

OpenAIRE

Schlosser, José Fernando; Debiasi, Henrique; Parcianello, Geovano; Rambo, Lisandro

2002-01-01

O objetivo deste trabalho foi determinar o padrão antropométrico dos operadores de tratores agrícolas da Depressão Central do Rio Grande do Sul. Os operadores de tratores agrícolas foram medidos por meio de um painel constituído por duas chapas metálicas, permanecendo durante as medições em pé, eretos, com o mínimo de roupa possível e em contato com o painel. As variáveis medidas foram as seguintes: altura do corpo; altura ao nível dos olhos; altura ao nível dos olhos sentado; altura do cotov...

Application of in operando UV/Vis spectroscopy in lithium-sulfur batteries.

Science.gov (United States)

Patel, Manu U M; Dominko, Robert

2014-08-01

Application of UV/Vis spectroscopy for the qualitative and quantitative determination of differences in the mechanism of lithium-sulfur battery behavior is presented. With the help of catholytes prepared from chemically synthesized stoichiometric mixtures of lithium and sulfur, calibration curves for two different types of electrolyte can be constructed. First-order derivatives of UV/Vis spectra show five typical derivative peak positions in both electrolytes. In operando measurements show a smooth change in the UV/Vis spectra in the wavelength region between λ=650 and 400 nm. Derivatives are in agreement with derivative peak positions observed with catholytes. Recalculation of normalized reflections of UV/Vis spectra obtained in operando mode enable the formation of polysulfides and their concentrations to be followed. In such a way, it is possible to distinguish differences in the mechanism of polysulfide shuttling between two electrolytes and to correlate differences in capacity fading. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Operando X-ray diffraction analysis for a glyme-based Li-O_2 battery

International Nuclear Information System (INIS)

Yogi, C.; Takao, N.; Kubobuchi, K.; Matsumoto, M.; Mogi, M.; Imai, H.; Watanabe, T.

2016-01-01

We investigated the effect of the carbon species in the air (oxygen) electrode, electrolyte concentration, and humidity in the supplied O_2 gas on the Li-O_2 reactions by using the operando XRD analysis. Regarding carbon species, we found that the over-potentials in the galvanostatic discharge-charge process were suppressed when using the KB carbon in the air electrode. The results of operando XRD measurements revealed that the Li_2O_2 formed on the KB had the smaller crystalline or more amorphous like structures, which could be one reason for faster reaction kinetics of Li_2O_2 dissolution. The discharge-charge curves of the cells with different concentration of LiTFSI/(G4)_n electrolyte showed the slight difference but less differences in the Li_2O_2 formation and dissolution behaviors. In addition to the nature of Li_2O_2 products, reaction of Li-salts would also have ineligible effects. We also found that the higher humidity in oxygen produced more the LiOH and promoted the Li_2O_2 dissolution, which indicate that the LiOH formation could affect the Li_2O_2 morphologies or surface chemistries. Our present results demonstrated that the operando XRD measurement are useful for analyzing the reaction mechanism of Li-O_2 battery.

Operando Raman Micro Spectroscopy of Polymer Electrolyte Fuel Cells

Science.gov (United States)

2016-01-16

the cathode , transitions ion exchange sites from the sulfonic acid to the dissociated sulfonate form. Visualization of density functional theory...catalysts dispersed in an alcoholic dispersion of solubilized ionomer (e.g., Nafion). Teflon dispersion is included in cathode inks to lower the surface...tolerant of condensed water, is complementary to FTIR. Operando Raman spectroscopy of solid oxide fuel cells has been reported.28–30 Although there are

Novel sample preparation for operando TEM of catalysts

International Nuclear Information System (INIS)

Miller, Benjamin K.; Barker, Trevor M.; Crozier, Peter A.

2015-01-01

A new TEM sample preparation method is developed to facilitate operando TEM of gas phase catalysis. A porous Pyrex-fiber pellet TEM sample was produced, allowing a comparatively large amount of catalyst to be loaded into a standard Gatan furnace-type tantalum heating holder. The increased amount of catalyst present inside the environmental TEM allows quantitative determination of the gas phase products of a catalytic reaction performed in-situ at elevated temperatures. The product gas concentration was monitored using both electron energy loss spectroscopy (EELS) and residual gas analysis (RGA). Imaging of catalyst particles dispersed over the pellet at atomic resolution is challenging, due to charging of the insulating glass fibers. To overcome this limitation, a metal grid is placed into the holder in addition to the pellet, allowing catalyst particles dispersed over the grid to be imaged, while particles in the pellet, which are assumed to experience identical conditions, contribute to the overall catalytic conversion inside the environmental TEM cell. The gas within the cell is determined to be well-mixed, making this assumption reasonable. - Highlights: • High in-situ conversion of CO to CO 2 achieved by a novel TEM sample preparation method. • A 3 mm fiber pellet increases the TEM sample surface area by 50×. • Operando atomic resolution is maintained by also including a 3 mm grid in the sample. • Evidence for a well-mixed gas composition inside the ETEM cell is given

Revealing Lattice Expansion of Small-Pore Zeolite Catalysts during the Methanol-to-Olefins Process Using Combined Operando X-ray Diffraction and UV-vis Spectroscopy.

Science.gov (United States)

Goetze, Joris; Yarulina, Irina; Gascon, Jorge; Kapteijn, Freek; Weckhuysen, Bert M

2018-03-02

In small-pore zeolite catalysts, where the size of the pores is limited by eight-ring windows, aromatic hydrocarbon pool molecules that are formed inside the zeolite during the Methanol-to-Olefins (MTO) process cannot exit the pores and are retained inside the catalyst. Hydrocarbon species whose size is comparable to the size of the zeolite cage can cause the zeolite lattice to expand during the MTO process. In this work, the formation of retained hydrocarbon pool species during MTO at a reaction temperature of 400 °C was followed using operando UV-vis spectroscopy. During the same experiment, using operando X-ray Diffraction (XRD), the expansion of the zeolite framework was assessed, and the activity of the catalyst was measured using online gas chromatography (GC). Three different small-pore zeolite frameworks, i.e., CHA, DDR, and LEV, were compared. It was shown using operando XRD that the formation of retained aromatic species causes the zeolite lattice of all three frameworks to expand. Because of the differences in the zeolite framework dimensions, the nature of the retained hydrocarbons as measured by operando UV-vis spectroscopy is different for each of the three zeolite frameworks. Consequently, the magnitude and direction of the zeolite lattice expansion as measured by operando XRD also depends on the specific combination of the hydrocarbon species and the zeolite framework. The catalyst with the CHA framework, i.e., H-SSZ-13, showed the biggest expansion: 0.9% in the direction along the c -axis of the zeolite lattice. For all three zeolite frameworks, based on the combination of operando XRD and operando UV-vis spectroscopy, the hydrocarbon species that are likely to cause the expansion of the zeolite cages are presented; methylated naphthalene and pyrene in CHA, 1-methylnaphthalene and phenalene in DDR, and methylated benzene and naphthalene in LEV. Filling of the zeolite cages and, as a consequence, the zeolite lattice expansion causes the

Revealing Lattice Expansion of Small-Pore Zeolite Catalysts during the Methanol-to-Olefins Process Using Combined Operando X-ray Diffraction and UV–vis Spectroscopy

Science.gov (United States)

2018-01-01

In small-pore zeolite catalysts, where the size of the pores is limited by eight-ring windows, aromatic hydrocarbon pool molecules that are formed inside the zeolite during the Methanol-to-Olefins (MTO) process cannot exit the pores and are retained inside the catalyst. Hydrocarbon species whose size is comparable to the size of the zeolite cage can cause the zeolite lattice to expand during the MTO process. In this work, the formation of retained hydrocarbon pool species during MTO at a reaction temperature of 400 °C was followed using operando UV–vis spectroscopy. During the same experiment, using operando X-ray Diffraction (XRD), the expansion of the zeolite framework was assessed, and the activity of the catalyst was measured using online gas chromatography (GC). Three different small-pore zeolite frameworks, i.e., CHA, DDR, and LEV, were compared. It was shown using operando XRD that the formation of retained aromatic species causes the zeolite lattice of all three frameworks to expand. Because of the differences in the zeolite framework dimensions, the nature of the retained hydrocarbons as measured by operando UV–vis spectroscopy is different for each of the three zeolite frameworks. Consequently, the magnitude and direction of the zeolite lattice expansion as measured by operando XRD also depends on the specific combination of the hydrocarbon species and the zeolite framework. The catalyst with the CHA framework, i.e., H-SSZ-13, showed the biggest expansion: 0.9% in the direction along the c-axis of the zeolite lattice. For all three zeolite frameworks, based on the combination of operando XRD and operando UV–vis spectroscopy, the hydrocarbon species that are likely to cause the expansion of the zeolite cages are presented; methylated naphthalene and pyrene in CHA, 1-methylnaphthalene and phenalene in DDR, and methylated benzene and naphthalene in LEV. Filling of the zeolite cages and, as a consequence, the zeolite lattice expansion causes the

Revealing Lattice Expansion of Small-Pore Zeolite Catalysts during the Methanol-to-Olefins Process Using Combined Operando X-ray Diffraction and UV–vis Spectroscopy

KAUST Repository

Goetze, Joris

2018-02-06

In small-pore zeolite catalysts, where the size of the pores is limited by eight-ring windows, aromatic hydrocarbon pool molecules that are formed inside the zeolite during the Methanol-to-Olefins (MTO) process cannot exit the pores and are retained inside the catalyst. Hydrocarbon species whose size is comparable to the size of the zeolite cage can cause the zeolite lattice to expand during the MTO process. In this work, the formation of retained hydrocarbon pool species during MTO at a reaction temperature of 400 °C was followed using operando UV–vis spectroscopy. During the same experiment, using operando X-ray Diffraction (XRD), the expansion of the zeolite framework was assessed, and the activity of the catalyst was measured using online gas chromatography (GC). Three different small-pore zeolite frameworks, i.e., CHA, DDR, and LEV, were compared. It was shown using operando XRD that the formation of retained aromatic species causes the zeolite lattice of all three frameworks to expand. Because of the differences in the zeolite framework dimensions, the nature of the retained hydrocarbons as measured by operando UV–vis spectroscopy is different for each of the three zeolite frameworks. Consequently, the magnitude and direction of the zeolite lattice expansion as measured by operando XRD also depends on the specific combination of the hydrocarbon species and the zeolite framework. The catalyst with the CHA framework, i.e., H-SSZ-13, showed the biggest expansion: 0.9% in the direction along the c-axis of the zeolite lattice. For all three zeolite frameworks, based on the combination of operando XRD and operando UV–vis spectroscopy, the hydrocarbon species that are likely to cause the expansion of the zeolite cages are presented; methylated naphthalene and pyrene in CHA, 1-methylnaphthalene and phenalene in DDR, and methylated benzene and naphthalene in LEV. Filling of the zeolite cages and, as a consequence, the zeolite lattice expansion causes the

Operando X-ray diffraction analysis for a glyme-based Li-O{sub 2} battery

Energy Technology Data Exchange (ETDEWEB)

Yogi, C.; Takao, N.; Kubobuchi, K.; Matsumoto, M.; Mogi, M., E-mail: mogi@nissan-arc.co.jp; Imai, H. [Device-functional analysis department, NISSAN ARC Ltd., 1 Natsushima, Yokosuka Kanagawa, 237-0061 JAPAN (Japan); Watanabe, T. [Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Koto, Sayo Hyogo, 679-5198 JAPAN (Japan)

2016-08-26

We investigated the effect of the carbon species in the air (oxygen) electrode, electrolyte concentration, and humidity in the supplied O{sub 2} gas on the Li-O{sub 2} reactions by using the operando XRD analysis. Regarding carbon species, we found that the over-potentials in the galvanostatic discharge-charge process were suppressed when using the KB carbon in the air electrode. The results of operando XRD measurements revealed that the Li{sub 2}O{sub 2} formed on the KB had the smaller crystalline or more amorphous like structures, which could be one reason for faster reaction kinetics of Li{sub 2}O{sub 2} dissolution. The discharge-charge curves of the cells with different concentration of LiTFSI/(G4){sub n} electrolyte showed the slight difference but less differences in the Li{sub 2}O{sub 2} formation and dissolution behaviors. In addition to the nature of Li{sub 2}O{sub 2} products, reaction of Li-salts would also have ineligible effects. We also found that the higher humidity in oxygen produced more the LiOH and promoted the Li{sub 2}O{sub 2} dissolution, which indicate that the LiOH formation could affect the Li{sub 2}O{sub 2} morphologies or surface chemistries. Our present results demonstrated that the operando XRD measurement are useful for analyzing the reaction mechanism of Li-O{sub 2} battery.

Perspectives of in situ/operando resonant inelastic X-ray scattering in catalytic energy materials science

Energy Technology Data Exchange (ETDEWEB)

Liu, Yi-Sheng; Glans, Per-Anders [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Chuang, Cheng-Hao [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Department of Physics, Tamkang University, Tamsui 250, Taiwan, ROC (China); Kapilashrami, Mukes [Center for Engineering Concepts Development, Department of Mechanical Engineering, University of Maryland, College Park, MD 20742 (United States); Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Guo, Jinghua, E-mail: jguo@lbl.gov [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95064 (United States)

2015-04-15

Highlights: • In-situ/operando soft X-ray RXES and RIXS offer unique perspectives in the energy material science. - Abstract: Growing environmental concerns have renewed the interest for light induced catalytic reactions to synthesize cleaner chemical fuels from syngas. This, however, requires a sound understanding for the dynamics taking place at molecular level as a result of light – matter interaction. We present herein the principles of soft X-ray resonant emission spectroscopy (RXES) and resonant inelastic scattering (RIXS) and the importance of these spectroscopic techniques in materials science in light of their unique ability to emanate characteristic fingerprints on the geometric structure, chemical bonding charge and spin states in addition to chemical sensitivity. The addition of in situ/operando RXES and RIXS capability offers new opportunities to project important material properties and functionalities under conditions nearly identical to the operational modes.

Perspectives of in situ/operando resonant inelastic X-ray scattering in catalytic energy materials science

International Nuclear Information System (INIS)

Liu, Yi-Sheng; Glans, Per-Anders; Chuang, Cheng-Hao; Kapilashrami, Mukes; Guo, Jinghua

2015-01-01

Highlights: • In-situ/operando soft X-ray RXES and RIXS offer unique perspectives in the energy material science. - Abstract: Growing environmental concerns have renewed the interest for light induced catalytic reactions to synthesize cleaner chemical fuels from syngas. This, however, requires a sound understanding for the dynamics taking place at molecular level as a result of light – matter interaction. We present herein the principles of soft X-ray resonant emission spectroscopy (RXES) and resonant inelastic scattering (RIXS) and the importance of these spectroscopic techniques in materials science in light of their unique ability to emanate characteristic fingerprints on the geometric structure, chemical bonding charge and spin states in addition to chemical sensitivity. The addition of in situ/operando RXES and RIXS capability offers new opportunities to project important material properties and functionalities under conditions nearly identical to the operational modes.

Operando Spectroscopy of the Gas-Phase Aldol Condensation of Propanal over Solid Base Catalysts

NARCIS (Netherlands)

Hernández-giménez, Ana M.; Ruiz-martínez, Javier; Puértolas, Begoña; Pérez-ramírez, Javier; Bruijnincx, Pieter C. A.; Weckhuysen, Bert M.

2017-01-01

The gas-phase aldol condensation of propanal, taken as model for the aldehyde components in bio-oils, has been studied with a combined operando set-up allowing to perform FT-IR & UV–Vis diffuse reflectance spectroscopy (DRS) with on-line mass spectrometry (MS). The selected solid base catalysts, a

Produtividade de híbridos de milho em função da velocidade de semeadura Corn hibrids yield as a function of seeding speed

Directory of Open Access Journals (Sweden)

Adilson J. R. Mello

2007-08-01

Full Text Available O presente trabalho foi conduzido na área experimental do Laboratório de Máquinas e Mecanização Agrícola da UNESP - Jaboticabal, em um Latossolo Vermelho eutroférrico, em preparo convencional. Avaliaram-se o desenvolvimento e os componentes de produção de dois híbridos de milho (DKB 390, simples e DKB 435, duplo em função de três velocidades do conjunto trator-semeadora-adubadora (5,4; 6,8 e 9,8 km h-1, totalizando seis tratamentos, com quatro repetições, em delineamento em blocos ao acaso, em esquema fatorial 2 x 3. Os resultados evidenciaram que o aumento da velocidade do conjunto trator-semeadora-adubadora reduziu a produtividade de grãos para o híbrido simples e não interferiu na produtividade do híbrido duplo. Apenas na menor velocidade (5,4 km h-1, o híbrido simples apresentou maior produtividade de grãos, comparado com o híbrido duplo. O aumento da velocidade na operação de semeadura reduziu a percentagem de espaçamentos normais entre as sementes, independentemente do híbrido estudado.The present work was lead in the experimental area of the Laboratory of Machines and Agricultural Mechanization of the São Paulo State University, Jaboticabal, Brazil, in a soil classified as Haplustox, in conventional tillage. It had been evaluated the development and the components of production of two hybrids of corn (DKB 390, simple and DKB 435, double in function of three speeds of the set tractor-seeder-fertilizer (5.4; 6.8 and 9.8 km h-1, totalizing six treatments with four repetitions in a randomized block-type design, factorial 2 x 3. The results had evidenced that the increase of the speed of the tractor-seeder-fertilizer set, reduced the productivity of grains for the simple hybrid and did not interfered with the productivity of the double hybrid. But in the lower speed the simple hybrid presented greater productivity of grains when compared with the double hybrid. The increase of the speed in the operation of seeding

In operando Raman spectroscopy as a tool for investigation of solid oxide electrodes

DEFF Research Database (Denmark)

Traulsen, Marie Lund; Holtappels, Peter; Walker, Robert

potential of combining in operando Raman spectroscopy with electrochemical characterisation, DTU Energy Conversion decided in 2014 to invest in a set-up dedicated to this purpose, At the end of the talk a short description will be given of this set-up, and the future plans will be described for combined...

In situ and operando transmission electron microscopy of catalytic materials

DEFF Research Database (Denmark)

Crozier, Peter A.; Hansen, Thomas Willum

2015-01-01

measurements of gas-phase catalytic products. To overcome this deficiency, operando TEM techniques are being developed that combine atomic characterization with the simultaneous measurement of catalytic products. This article provides a short review of the current status and major developments......) is a powerful technique for revealing the atomic structures of materials at elevated temperatures in the presence of reactive gases. This approach can allow the structure-reactivity relations underlying catalyst functionality to be investigated. Thus far, ETEM has been limited by the absence of in situ...... in the application of ETEM to gas-phase catalysis over the past 10 years....

Operando x-ray photoelectron emission microscopy for studying forward and reverse biased silicon p-n junctions

Energy Technology Data Exchange (ETDEWEB)

Barrett, N., E-mail: nick.barrett@cea.fr; Gottlob, D. M.; Mathieu, C.; Lubin, C. [SPEC, CEA, CNRS, Université Paris-Saclay, CEA Saclay, 91191 Gif-sur-Yvette Cedex (France); Passicousset, J. [SPEC, CEA, CNRS, Université Paris-Saclay, CEA Saclay, 91191 Gif-sur-Yvette Cedex (France); IFP Energies nouvelles, Rond-point de l’échangeur de Solaize, BP 3, 69360 Solaize (France); Renault, O.; Martinez, E. [University Grenoble-Alpes, 38000 Grenoble, France and CEA, LETI, MINATEC Campus, 38054 Grenoble (France)

2016-05-15

Significant progress in the understanding of surfaces and interfaces of materials for new technologies requires operando studies, i.e., measurement of chemical, electronic, and magnetic properties under external stimulus (such as mechanical strain, optical illumination, or electric fields) applied in situ in order to approach real operating conditions. Electron microscopy attracts much interest, thanks to its ability to determine semiconductor doping at various scales in devices. Spectroscopic photoelectron emission microscopy (PEEM) is particularly powerful since it combines high spatial and energy resolution, allowing a comprehensive analysis of local work function, chemistry, and electronic structure using secondary, core level, and valence band electrons, respectively. Here we present the first operando spectroscopic PEEM study of a planar Si p-n junction under forward and reverse bias. The method can be used to characterize a vast range of materials at near device scales such as resistive oxides, conducting bridge memories and domain wall arrays in ferroelectrics photovoltaic devices.

Identification of a Catalytically Highly Active Surface Phase for CO Oxidation over PtRh Nanoparticles under Operando Reaction Conditions

Science.gov (United States)

Hejral, U.; Franz, D.; Volkov, S.; Francoual, S.; Strempfer, J.; Stierle, A.

2018-03-01

Pt-Rh alloy nanoparticles on oxide supports are widely employed in heterogeneous catalysis with applications ranging from automotive exhaust control to energy conversion. To improve catalyst performance, an atomic-scale correlation of the nanoparticle surface structure with its catalytic activity under industrially relevant operando conditions is essential. Here, we present x-ray diffraction data sensitive to the nanoparticle surface structure combined with in situ mass spectrometry during near ambient pressure CO oxidation. We identify the formation of ultrathin surface oxides by detecting x-ray diffraction signals from particular nanoparticle facets and correlate their evolution with the sample's enhanced catalytic activity. Our approach opens the door for an in-depth characterization of well-defined, oxide-supported nanoparticle based catalysts under operando conditions with unprecedented atomic-scale resolution.

Desempenho do trator agrícola no manejo da cultura de cobertura e pressão de inflação do pneu da semeadora Agricultural tractor performance in the management of coverage crop and tire inflation presure of sowing machine

Directory of Open Access Journals (Sweden)

Jorge W. Cortez

2009-03-01

Full Text Available O adequado manejo de culturas de cobertura no plantio direto tem-se mostrado excelente alternativa para melhorar as condições de semeadura. O objetivo do presente trabalho foi avaliar o desempenho do trator agrícola no manejo dos restos culturais do sorgo (rolo-faca e triturador de palhas e a pressão de inflação (525 e 385 kPa do pneu da semeadora-adubadora, no estabelecimento da cultura do milho em plantio direto. O experimento foi conduzido na UNESP - Jaboticabal, em delineamento de blocos ao acaso, com parcela subdividida, e os tratamentos consistiram nos manejos da cultura de cobertura do solo e pressões de inflação do pneu da semeadora, com quatro repetições. Foram mensurados nas máquinas: velocidade de deslocamento, capacidade de campo, consumo de combustível e patinhagem do trator; no solo e nas plantas, foi acrescido o tratamento de manejo com herbicida: cobertura inicial, número de dias para emergência das plântulas, população inicial e final de plantas, distribuição longitudinal e produtividade de grãos. No manejo da palhada da cultura do sorgo, o rolo-faca proporcionou maior capacidade de campo e menores consumos de combustível. Os tratamentos manejos e pressão não interferiram na cobertura do solo, no número de dias para emergência do milho e na distribuição longitudinal.The appropriate management of coverage crops in no tillage has been shown as an excellent alternative to improve seedling conditions. The aim of the present study was to evaluate the performance of the agricultural tractor in management (knife-rolls and straw shopper of the sorghum residues and the tire inflation pressure (525 and 385 kPa of sowing-fertilizer machine for establishing corn crop in no tillage. The experiment was done at the São Paulo State University in the city of Jaboticabal - SP, Brazil, with delineation in randomized blocks with split plot, and the treatments were composed by the management of coverage soil crop and

Desempenho de gotejadores operando com efluente da castanha de caju sob distintas pressões de serviço

Directory of Open Access Journals (Sweden)

Ketson Bruno da Silva

2013-06-01

Full Text Available Este trabalho objetivou analisar o efeito de distintas pressões de serviço no coeficiente de variação da vazão (CVQ de sistemas de irrigação por gotejamento, operando com água residuária da castanha de caju. O experimento foi montado no esquema de parcelas subsubdivididas, tendo, nas parcelas, as pressões de serviço (70, 140, 210 e 280 kPa, nas subparcelas, os modelos de gotejadores (G1, G2 e G3 e, nas subsubparcelas, os períodos das avaliações (0, 20, 40, 60, 80, 100, 120, 140 e 160 horas, no delineamento inteiramente casualizado, com três repetições. O CVQ das unidades de irrigação, bem como as características físico-químicas da água residuária, foram determinados a cada 20 h, até completar o tempo de operação de 160 h. Os resultados indicaram que a água residuária da castanha de caju representa risco de obstrução de gotejadores, em relação às características pH, cálcio, magnésio, manganês e sólidos suspensos. O entupimento parcial dos gotejadores acarretou aumento do CVQ, nas unidades de irrigação; e as unidades de irrigação que funcionaram na pressão de serviço P1 (70 kPa apresentaram maior nível de entupimento de gotejadores, em relação às demais, em função da menor velocidade de escoamento de efluente no interior dos emissores.

Projeto de um amplificador de transimpedancia monolitico implementado em GaAs com CAG para recepção em comunicações opticas

OpenAIRE

Valentino Corso

1998-01-01

Resumo: Este trabalho descreve o projeto e a implementação de um amplificador monolítico de transimpedância, para ser utilizado no estágio de pré-amplificação de receptores ópticos, operando em 51,84Mb/s. Protótipos do circuito projetado foram fabricados pela TriQuint Semiconductor, utilizando a tecnologia de Arseneto de Gálio (GaAs) com transistores MESFET de depleção de 0,5/mm. O amplificador desenvolvido tem características de baixo ruído, ganho de tensão de aproximadamente 30dB e baixo c...

Development of an Innovative XRD-DRIFTS Prototype Allowing Operando Characterizations during Fischer-Tropsch Synthesis over Cobalt-Based Catalysts under Representative Conditions

Directory of Open Access Journals (Sweden)

Scalbert Julien

2015-03-01

Full Text Available An original system combining both X-Ray Diffraction and diffuse reflectance infrared Fourier transform spectroscopy was developed with the aim to characterize Fischer-Tropsch catalysts in relevant reaction conditions. The catalytic properties of a model PtCo/silica catalyst tested with this prototype have shown to be in the same range of those obtained in similar conditions with classical fixed-bed reactors. No bulk cobalt oxidation nor sintering were observed on operando XRD patterns. The formation of linear carbonyls and adsorbed hydrocarbons species at the surface of the catalyst was observed on operando DRIFT spectra. The surface of the catalyst was also suspected to be covered with carbon species inducing unfavorable changes in selectivity.

Planejamento e programação da produção em plantas multipropósito operando em batelada na indústria química Short term planning and scheduling for multipurpose batch chemical plants

Directory of Open Access Journals (Sweden)

Luis Gimeno Latre

2000-12-01

Full Text Available Neste artigo, considera-se o problema de programação da produção a curto prazo em plantas químicas multipropósito operando em batelada, em que a produção da planta é determinada pela demanda a ser atendida. Nesta situação, a capacidade da planta não está bem definida porque depende do mix de produção. Propõe-se uma fase de planejamento que tem como objetivo a determinação do número de bateladas de cada tarefa necessárias para atender a produção, bem como a respectiva janela de tempo de processamento. Estas janelas permitem a análise do carregamento dos processadores e da factibilidade do plano, ou seja, o atendimento das datas de entrega, através de ferramentas desenvolvidas na área de Busca Orientada por Restrições. Esta análise é feita para uma atribuição fixa de tarefas a processadores introduzida pelo usuário. O sistema fornece informações para orientar o usuário na criação de diferentes cenários de atribuição. O resultado da fase de planejamento é formado por um conjunto de janelas de processamento que diminuem sensivelmente a dimensão do problema de programação da produção, como é discutido para duas abordagens: programação mista (Mixed Integer Linear Programming - MILP e Simulated Annealing.Short term scheduling in multipurpose batch chemical plants is specially complicated by the fact that plant capacity is not well defined due to the multipurpose nature of equipment units, allowing different routes. In order to reduce problem dimension, as well as allowing to analyze problem feasibility prior to spending time solving a large scheduling problem, a planning phase is proposed. At this level the objective is to determine a set of processing time windows for the batches necessary to fulfill final products' demand. The time windows allow analyzing equipment units load and plan feasibility in terms of satisfying final products due dates. To accomplish those tools from the area of Constrained

A fluorescence XAFS measurement instrument in the soft x-ray region toward observation under operando conditions

Energy Technology Data Exchange (ETDEWEB)

Honda, M., E-mail: honda.mitsunori@jaea.go.jp; Baba, Y.; Shimoyama, I.; Sekiguchi, T. [Quantum Beam Science Center, Japan Atomic Energy Agency (JAEA), 2-4 Shirakata-Shirane, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan)

2015-03-15

X-ray absorption fine structure (XAFS) measurements are widely used for the analysis of electronic structure. Generally, XAFS in the soft X-ray region is measured under vacuum, but chemical structures under vacuum are typically different from those under operando conditions, where chemical species exhibit their function. Here, we developed an XAFS measurement instrument, as a step toward operando fluorescent, which yields XAFS measurement using synchrotron radiation in the soft X-ray region. We applied this method to analyze the local electronic structure of the sulfur atoms in L-cysteine in different pH solutions. In water at pH 7, the hydrogen atom does not dissociate from the thiol (-SH) group in L-cysteine, which forms a structure surrounded by and interacting with water molecules. The XAFS spectrum of L-cysteine in solution was altered by changing the pH. At pH 9, the hydrogen atom dissociated and a thiolate anion was formed. Although the -SH group was oxidized to SO{sub 4}{sup 2−} when L-cysteine was adsorbed on a metal surface and dried, no oxidation was observed in solution. This may be because the water molecules were densely packed and protected the -SH group from oxidation. Our results show that this instrument aimed toward operando fluorescence XAFS measurements in the soft X-ray region is useful for structural analysis of sulfur atoms in organic molecules in air and in solution. The instrument will be applied to the structural analysis of materials containing elements that have absorption edges in soft X-ray region, such as phosphorus and alkali metals (potassium and cesium). It will be also particularly useful for the analysis of samples that are difficult to handle under vacuum and materials that have specific functions in solution.

Shedding Light on the Oxygen Reduction Reaction Mechanism in Ether-Based Electrolyte Solutions: A Study Using Operando UV-Vis Spectroscopy.

Science.gov (United States)

Hirshberg, Daniel; Sharon, Daniel; Afri, Michal; Lavi, Ronit; Frimer, Aryeh A; Metoki, Noa; Eliaz, Noam; Kwak, Won-Jin; Sun, Yang-Kook; Aurbach, Doron

2018-04-04

Using UV-vis spectroscopy in conjunction with various electrochemical techniques, we have developed a new effective operando methodology for investigating the oxygen reduction reactions (ORRs) and their mechanisms in nonaqueous solutions. We can follow the in situ formation and presence of superoxide moieties during ORR as a function of solvent, cations, anions, and additives in the solution. Thus, using operando UV-vis spectroscopy, we found evidence for the formation of superoxide radical anions during oxygen reduction in LiTFSI/diglyme electrolyte solutions. Nitro blue tetrazolium (NBT) was used to indicate the presence of superoxide moieties based on its unique spectral response. Indeed, the spectral response of NBT containing solutions undergoing ORR could provide a direct indication for the level of association of the Li cations with the electrolyte anions.

Unravelling the dependence of hydrogen oxidation kinetics on the size of Pt nanoparticles by in operando nanoplasmonic temperature sensing

DEFF Research Database (Denmark)

Wettergren, Kristina; Hellman, Anders; Cavalca, Filippo Carlo

2015-01-01

We use a noninvasive nanoscale optical-temperature measurement method based on localized surface plasmon resonance to investigate the particle size-dependence of the hydrogen oxidation reaction kinetics on model supported Pt nanocatalysts at atmospheric pressure in operando. With decreasing average...

Combined operando Raman/UV-Vis-NIR spectroscopy as a tool to study supported metal oxide catalysts at work

NARCIS (Netherlands)

Tinnemans, Stanislaus Josephus

2006-01-01

A novel set-up has been developed in which two complementary spectroscopic techniques, namely operando Raman and UV-Vis-NIR spectroscopy, are combined. With this set-up it is possible to characterize catalytic materials under reaction conditions (high temperature, normal pressure) and in this way on

Eliminação de linhas em cafeeiros adensados por meio semimecanizado Elimination of dense coffee-lines by semi mechanized ways

Directory of Open Access Journals (Sweden)

Ezequiel de Oliveira

2007-12-01

Full Text Available Buscando obter maior produtividade inicial da lavoura cafeeira é comum fazer plantio adensado, porém devido ao adensamento e outras causas a produtividade reduz-se a partir da quarta ou quinta colheita, sendo uma das causas o "fechamento" da copa das plantas, necessitando assim fazer a eliminação de linhas de café. Assim, este trabalho teve por objetivo avaliar a eficiência operacional e viabilidade econômica de diferentes métodos de eliminação das linhas de cafeeiros adensados. O trabalho foi desenvolvido no Município de Lavras, MG, em área de 1 ha, sendo os ensaios realizados utilizando o delineamento inteiramente casualizado, com três repetições, em parcelas aleatórias com 50 m de comprimento. Os tratamentos foram: palitamento e arranquio usando trator com gancho, palitamento com foice e corte com motosserra e palitamento com foice e corte com serra circular. O tratamento palitamento com foice e corte com serra circular, apresentou melhor eficiência operacional de campo, sendo 41,8 % mais eficiente que o tratamento palitamento e arranquio usando trator com gancho. O uso palitamento com serra circular ou motosserra é técnica e economicamente mais viável que o uso do palitamento e arranquio usando trator com gancho. No caso da venda dos troncos como lenha, os três métodos de eliminação das linhas dos cafeeiros resultaram em receitas líquidas, sendo maior para o palitamento e corte usando serra circular, chegando ao valor de R$ 624,98 ha-1.In order to obtain a larger initial productivity of coffee plantation it is very common to dense it, however this procedure reduces the productivity from the fourth or fifth crops on, because of the "closing" of plants tops, therefore it is necessary to eliminate some streets. The purpose of this work is evaluating the operational and economic performance of different methods of elimination of dense coffee-lines. The rehearsals were accomplished in LavrasMG considering aleatory

Tratabilidade do lodo biológico têxtil e produção de biogás em reator UASB em diferentes temperaturas

Directory of Open Access Journals (Sweden)

Júnia Schultz

Full Text Available RESUMO Neste trabalho avaliou-se o comportamento de um reator UASB em escala laboratorial (16 L no tratamento de lodo biológico têxtil com produção de biogás, operando em diferentes temperaturas, 35 (mesofílica, 45 e 55ºC (termofílica, com tempo de detenção hidráulica (TDH constante de 24 h. O reator UASB apresentou-se apto a tratar o lodo têxtil, sendo influenciado positivamente pelo incremento da temperatura, mostrando maiores remoções nas temperaturas termofílicas e com altas taxas de remoção de todos os parâmetros físico-químicos monitorados: demanda química de oxigênio (DQO (97% em 45 e 55ºC, demanda bioquímica de oxigênio (DBO (95% em 45ºC e 94% em 55ºC, fósforo total (P-total (95% a 45 e 55ºC e nitrogênio total (N-total (94% a 45 e 55ºC. Quanto à produção de biogás e à concentração de metano, os maiores valores foram observados a 45ºC. Com base nos resultados alcançados, confirmam-se a tratabilidade do lodo têxtil e a produção de biogás em UASB, com melhor performance a 45ºC.

Desempenho de três teorias de simulação do comportamento de um trator agrícola em tração Evaluation of three theories for predicting the performance of agricultural tractors

Directory of Open Access Journals (Sweden)

José F. Schlosser

2004-12-01

Full Text Available A simulação matemática é uma ferramenta importante na diminuição de custos de produção e viabilização de novos projetos de máquinas agrícolas. Este trabalho trata da comparação entre três teorias de simulação, as chamadas teorias de predição de tração clássicas, desenvolvidas por Wismer, Brixius e Gee-Clough, na simulação do desempenho de um trator agrícola de rodas. Para efetuar uma comparação entre as três teorias e apurar as condições mais apropriadas de uso das mesmas, realizou-se um experimento de campo com um trator de tração simples (4x2, com o controle de um número apreciável de variáveis relevantes, para criar condições de comparação com uma simulação posterior. No trabalho de campo, foram utilizados tratamentos que envolviam a condição do solo, preparado ou consolidado; pneus do tipo diagonal, e a deflexão desse pneu, maior e menor. Utilizando os parâmetros medidos a campo, realizou-se a comparação com os dados simulados para a variável patinamento. A teoria Cn mostrou que possui uma faixa de utilização mais restrita do que as teorias Bn e MN, sendo o índice de cone a variável que determina essas condições de uso.The simulation of machines behavior by mathematical modeling is nowadays an important tool for reducing production costs and making new projects feasible. The present study comprises a comparison among three theories for predicting the traction performance of a tractor, developed by Wismer, Brixius and Gee-Clough. In order to compare the three theories and find out the most appropriate conditions for using them, a field experiment in which all relevant variables were controlled for further simulation was conducted by using a 2WD tractor (4x2. Using the parameter obtained in field, a comparison was carried out with the results from the different simulation models. In this field study was used treatments that involved soil conditions, with grass and conventional tillage

A new high temperature reactor for operando XAS: Application for the dry reforming of methane over Ni/ZrO2 catalyst

KAUST Repository

Aguilar Tapia, Antonio; Ould-Chikh, Samy; Lahera, Eric; Prat, Alain; Delnet, William; Proux, Olivier; Kieffer, Isabelle; Basset, Jean-Marie; Takanabe, Kazuhiro; Hazemann, Jean-Louis

2018-01-01

The construction of a high-temperature reaction cell for operando X-ray absorption spectroscopy characterization is reported. A dedicated cell was designed to operate as a plug-flow reactor using powder samples requiring gas flow and thermal

Polarization Induced Changes in LSM Thin Film Electrode Composition Observed by In Operando Raman Spectroscopy and TOF-SIMS

DEFF Research Database (Denmark)

McIntyre, Melissa D.; Traulsen, Marie Lund; Norrman, Kion

2015-01-01

Polarization induced changes in LSM electrode composition were investigated by utilizing in operando Raman spectroscopy and post mortem TOF-SIMS depth profiling. Experiments were conducted on cells with 160 nm thick (La0.85Sr0.15)0.9MnO3±δ thin film electrodes in 10% O2 at 700 °C under various...

In operando study of high-performance thermoelectric materials for power generation: a case study of β-Zn4Sb3

DEFF Research Database (Denmark)

Le, Thanh Hung; Ngo, Duc-The; Han, Li

2017-01-01

of the thermal conductivity and electrical resistivity, but it is also the failure mechanism for the leg under these conditions. The in operando study brings deep insight into the dynamic behavior of nanostructured TE materials for tailoring future TE materials and devices with higher efficiency and longer......To bring current thermoelectric (TE) materials achievement into a device for power generation, a full understanding of their dynamic behavior under operating conditions is needed. Here, an in operando study is conducted on the high-performance TE material β-Zn4Sb3 under large temperature gradient...... and thermal cycling via a new approach using in situ transmission electron microscopy combined with characterization of the TE properties. It is found that after 30 thermal cycles in a low-pressure helium atmosphere the TE performance of β-Zn4Sb3 is maintained with the figure of merit, zT, value of 1.4 at 718...

High resolution in-operando microimaging of solar cells with pulsed electrically-detected magnetic resonance

Science.gov (United States)

Katz, Itai; Fehr, Matthias; Schnegg, Alexander; Lips, Klaus; Blank, Aharon

2015-02-01

The in-operando detection and high resolution spatial imaging of paramagnetic defects, impurities, and states becomes increasingly important for understanding loss mechanisms in solid-state electronic devices. Electron spin resonance (ESR), commonly employed for observing these species, cannot meet this challenge since it suffers from limited sensitivity and spatial resolution. An alternative and much more sensitive method, called electrically-detected magnetic resonance (EDMR), detects the species through their magnetic fingerprint, which can be traced in the device's electrical current. However, until now it could not obtain high resolution images in operating electronic devices. In this work, the first spatially-resolved electrically-detected magnetic resonance images (EDMRI) of paramagnetic states in an operating real-world electronic device are provided. The presented method is based on a novel microwave pulse sequence allowing for the coherent electrical detection of spin echoes in combination with powerful pulsed magnetic-field gradients. The applicability of the method is demonstrated on a device-grade 1-μm-thick amorphous silicon (a-Si:H) solar cell and an identical device that was degraded locally by an electron beam. The degraded areas with increased concentrations of paramagnetic defects lead to a local increase in recombination that is mapped by EDMRI with ∼20-μm-scale pixel resolution. The novel approach presented here can be widely used in the nondestructive in-operando three-dimensional characterization of solid-state electronic devices with a resolution potential of less than 100 nm.

Combined operando X-ray diffraction-electrochemical impedance spectroscopy detecting solid solution reactions of LiFePO4 in batteries.

Science.gov (United States)

Hess, Michael; Sasaki, Tsuyoshi; Villevieille, Claire; Novák, Petr

2015-09-08

Lithium-ion batteries are widely used for portable applications today; however, often suffer from limited recharge rates. One reason for such limitation can be a reduced active surface area during phase separation. Here we report a technique combining high-resolution operando synchrotron X-ray diffraction coupled with electrochemical impedance spectroscopy to directly track non-equilibrium intermediate phases in lithium-ion battery materials. LiFePO4, for example, is known to undergo phase separation when cycled under low-current-density conditions. However, operando X-ray diffraction under ultra-high-rate alternating current and direct current excitation reveal a continuous but current-dependent, solid solution reaction between LiFePO4 and FePO4 which is consistent with previous experiments and calculations. In addition, the formation of a preferred phase with a composition similar to the eutectoid composition, Li0.625FePO4, is evident. Even at a low rate of 0.1C, ∼20% of the X-ray diffractogram can be attributed to non-equilibrium phases, which changes our understanding of the intercalation dynamics in LiFePO4.

Avaliação da uniformidade de distribuição de um sistema de irrigação por gotejamento em pimentao

Directory of Open Access Journals (Sweden)

Célia Silva dos santos

2013-09-01

Full Text Available A produtividade agrícola em áreas irrigadas depende de uma série de fatores, dentre eles, o dimensionamento e manutenção dos sistemas. Aplicações excessivas ou insuficientes de água prejudicam o desenvolvimento das plantas e, consequentemente, a produtividade e a rentabilidade do agricultor. Este trabalho teve como objetivo avaliar a uniformidade em sistema de irrigação por gotejamento, utilizado na cultura da pimenta cultivada no município de Arapiraca-AL. Os coeficientes de uniformidade (CUC, CUD, a eficiência de aplicação, a vazão do sistema foram obtidos em avaliações de campo. Os resultados identificaram que o sistema está operando com boa uniformidade, porém a eficiência de aplicação está abaixo do recomendado.   

Distribuição longitudinal de sementes de milho com dosador de disco horizontal operando com uma ou duas saídas de sementes Longitudinal distribution of maize seeds in the disk plate seed meter operating one or two seed ejection points

Directory of Open Access Journals (Sweden)

Sandro Silva Teixeira

2009-11-01

Full Text Available O objetivo deste trabalho foi comparar os efeitos da utilização de dosador de sementes do tipo disco horizontal com orifícios circulares, operando com uma ou duas saídas de sementes sobre a precisão de distribuição longitudinal de sementes de milho. Para tanto, avaliou-se o dosador, em laboratório, com uma e duas saídas de sementes, em relação a 10 velocidades periféricas (0,03 a 0,30m s-1. O delineamento foi o inteiramente casualizado, com quatro repetições, totalizando 80 ensaios. O fator quantitativo referente à velocidade periférica do disco dosador foi estimado por meio de regressão polinomial de 2ª ordem. O comportamento do disco dosador operando com uma ou duas saídas foi semelhante, e a porcentagem de espaçamentos aceitáveis apresentou diferença significativa somente nas velocidades periféricas de 0,06 e 0,09m s-1.This study had the objective of comparing the effect of using the disk plate seed meter with circular holes operating with one or two seed ejection points in relation to the longitudinal precision of the maize seeds distribution. For the evaluation of this effect, the meter was tested in laboratory with one and two seed exits in ten peripheral disk plate speeds (0.03 to 0.30m s-1. It was employed a complete randomized design with four replications, summing up 80 experimental plots. The peripheral speed quantitative factor was estimated through a 2nd order polynomial regression. The behavior of the seed meter operating with one or two ejection points was similar, with significant difference only in peripherical speeds of 0.06 and 0.09m s-1.

Desempenho operacional e custos de um trator na irrigação pós-plantio de eucalipto em campo

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Danilo Simões

2012-04-01

Full Text Available O alto investimento em operações agroflorestais mecanizadas implica a definição segura de qual será a máquina mais preconizada para a otimização da operação, vinculada aos menores custos envolvidos. Este estudo teve como objetivo avaliar o desempenho operacional e econômico da operação silvicultural de irrigação pós-plantio de eucalipto a campo. A análise técnica englobou um estudo de tempos e movimentos e, a análise econômica, as variáveis do custo operacional, custo de produção e rendimento energético. Os resultados obtidos evidenciaram que, para áreas de reflorestamento de eucalipto em primeira e terceira rotação, não há uma diferença da capacidade de campo efetiva para a operação de irrigação pós-plantio. Em decorrência do dispêndio com tempos improdutivos, houve uma redução significativa na capacidade de campo operacional e, consequentemente, uma elevação no custo de produção.

Desempenho de uma semeadora-adubadora direta, em função da velocidade de eslocamento e do tipo de manejo da biomassa da cultura de cobertura do solo Performance of a seeding-fertilizer machine in function of the displacement speed and soil cover crop biomass management

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Klinger B. Branquinho

2004-08-01

Full Text Available O objetivo do presente trabalho foi estudar o desempenho de uma semeadora-adubadora, operando em duas velocidades sobre a palhada da cultura do milheto (Pennisetum glaucum (L. R. Brown, após diferentes manejos, na semeadura direta da cultura da soja (Glycine Max L.. O experimento foi realizado com seis tratamentos, em esquema fatorial, delineados em blocos ao acaso, com quatro repetições. Os tratamentos combinaram três manejos (triturador de palhas tratorizado, rolo- faca e herbicida com duas velocidades de deslocamento da semeadora-adubadora (5,2 e 7,3 km h-1. Foram analisadas as seguintes variáveis: acúmulo e decomposição de massa seca do milheto, índice de emergência da cultura da soja, uniformidade de distribuição longitudinal de sementes, capacidade de campo efetiva da semeadora-adubadora e produtividade da soja. Os resultados mostraram que não houve diferença na decomposição da massa de milheto após os manejos e que esses, juntamente com a velocidade de deslocamento do conjunto trator-semeadora-adubadora, não influenciaram no número de dias para a emergência das plântulas de soja e na distribuição longitudinal das sementes. A capacidade de campo efetiva da semeadora-adubadora foi maior na velocidade mais alta. O rendimento de grãos não diferiu significativamente nos tratamentos estudados.The objective of the present work was to evaluate three different managements of the Pennisetum glaucum (L. R. Brown crop and two-speed displacement in a no-tillage system of soybean (Glycine max L. crop on a typical Eutrophic Red Latosol. The experiment was arranged in six treatments, in a factorial array, in a randomized complete block design, with four replications. The treatments were constituted from three combination of crop managements (straw chopper, residue coulter and herbicide and two speed displacement of the seeding-fertilizer machine (5.2 and 7.3 km h-1. The following variables have been analyzed: emergency index of

Why does the Conductivity of a Nickel Catalyst Increase during Sulfidation? An Exemplary Study Using an In Operando Sensor Device.

Science.gov (United States)

Fremerey, Peter; Jess, Andreas; Moos, Ralf

2015-10-23

In order to study the sulfidation of a catalyst fixed bed, an in operando single pellet sensor was designed. A catalyst pellet from the fixed bed was electrically contacted and its electrical response was correlated with the catalyst behavior. For the sulfidation tests, a nickel catalyst was used and was sulfidized with H₂S. This catalyst had a very low conductivity in the reduced state. During sulfidation, the conductivity of the catalyst increased by decades. A reaction from nickel to nickel sulfide occurred. This conductivity increase by decades during sulfidation had not been expected since both nickel and nickel sulfides behave metallic. Only by assuming a percolation phenomenon that originates from a volume increase of the nickel contacts when reacting to nickel sulfides, this effect can be explained. This assumption was supported by sulfidation tests with differently nickel loaded catalysts and it was quantitatively estimated by a general effective media theory. The single pellet sensor device for in operando investigation of sulfidation can be considered as a valuable tool to get further insights into catalysts under reaction conditions.

Why does the Conductivity of a Nickel Catalyst Increase during Sulfidation? An Exemplary Study Using an In Operando Sensor Device

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Peter Fremerey

2015-10-01

Full Text Available In order to study the sulfidation of a catalyst fixed bed, an in operando single pellet sensor was designed. A catalyst pellet from the fixed bed was electrically contacted and its electrical response was correlated with the catalyst behavior. For the sulfidation tests, a nickel catalyst was used and was sulfidized with H2S. This catalyst had a very low conductivity in the reduced state. During sulfidation, the conductivity of the catalyst increased by decades. A reaction from nickel to nickel sulfide occurred. This conductivity increase by decades during sulfidation had not been expected since both nickel and nickel sulfides behave metallic. Only by assuming a percolation phenomenon that originates from a volume increase of the nickel contacts when reacting to nickel sulfides, this effect can be explained. This assumption was supported by sulfidation tests with differently nickel loaded catalysts and it was quantitatively estimated by a general effective media theory. The single pellet sensor device for in operando investigation of sulfidation can be considered as a valuable tool to get further insights into catalysts under reaction conditions.

Combined operando X-ray diffraction–electrochemical impedance spectroscopy detecting solid solution reactions of LiFePO4 in batteries

Science.gov (United States)

Hess, Michael; Sasaki, Tsuyoshi; Villevieille, Claire; Novák, Petr

2015-01-01

Lithium-ion batteries are widely used for portable applications today; however, often suffer from limited recharge rates. One reason for such limitation can be a reduced active surface area during phase separation. Here we report a technique combining high-resolution operando synchrotron X-ray diffraction coupled with electrochemical impedance spectroscopy to directly track non-equilibrium intermediate phases in lithium-ion battery materials. LiFePO4, for example, is known to undergo phase separation when cycled under low-current-density conditions. However, operando X-ray diffraction under ultra-high-rate alternating current and direct current excitation reveal a continuous but current-dependent, solid solution reaction between LiFePO4 and FePO4 which is consistent with previous experiments and calculations. In addition, the formation of a preferred phase with a composition similar to the eutectoid composition, Li0.625FePO4, is evident. Even at a low rate of 0.1C, ∼20% of the X-ray diffractogram can be attributed to non-equilibrium phases, which changes our understanding of the intercalation dynamics in LiFePO4. PMID:26345306

Novel sample preparation for operando TEM of catalysts.

Science.gov (United States)

Miller, Benjamin K; Barker, Trevor M; Crozier, Peter A

2015-09-01

A new TEM sample preparation method is developed to facilitate operando TEM of gas phase catalysis. A porous Pyrex-fiber pellet TEM sample was produced, allowing a comparatively large amount of catalyst to be loaded into a standard Gatan furnace-type tantalum heating holder. The increased amount of catalyst present inside the environmental TEM allows quantitative determination of the gas phase products of a catalytic reaction performed in-situ at elevated temperatures. The product gas concentration was monitored using both electron energy loss spectroscopy (EELS) and residual gas analysis (RGA). Imaging of catalyst particles dispersed over the pellet at atomic resolution is challenging, due to charging of the insulating glass fibers. To overcome this limitation, a metal grid is placed into the holder in addition to the pellet, allowing catalyst particles dispersed over the grid to be imaged, while particles in the pellet, which are assumed to experience identical conditions, contribute to the overall catalytic conversion inside the environmental TEM cell. The gas within the cell is determined to be well-mixed, making this assumption reasonable. Copyright © 2015 Elsevier B.V. All rights reserved.

Capacidade de suporte de carga e umidade crítica de um Latossolo induzida por diferentes manejos

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Cezar Francisco Araujo-Junior

2011-02-01

Full Text Available Os diferentes manejos de plantas invasoras em lavouras cafeeiras têm promovido alterações estruturais aos solos, comprometendo a sua qualidade física. Assim, o conhecimento da capacidade de suporte de carga do solo sob diferentes sistemas de manejo de plantas invasoras é essencial para o manejo sustentável do solo de lavouras cafeeiras. Os objetivos deste estudo foram: (a avaliar a influência da adoção, durante 30 anos, de diferentes sistemas de manejo de plantas invasoras na capacidade de suporte de carga de um Latossolo Vermelho distroférrico (LVdf cultivado com cafeeiros e localizado na Fazenda da Epamig em São Sebastião do Paraíso, MG (Latitude de 20 º 55 ' 00 " S e Longitude 47 º 07 ' 10 " W ; b determinar a tensão máxima (σmax aplicada ao solo por um trator; e c estabelecer as umidades volumétricas críticas (θcrítica para o tráfego de um trator. Os manejos de plantas invasoras avaliados foram: sem capina (SCAP; capina manual (CAPM; herbicida de pós-emergência (HPOS; roçadora (ROÇA; enxada rotativa (ENRT; grade (GRAD; e herbicida de pré-emergência (HPRE. Em cada sistema de manejo, 15 amostras indeformadas de solo foram coletadas aleatoriamente no centro das entrelinhas dos cafeeiros, nas profundidades de 0-3, 10-13 e 25-28 cm, totalizando 315 amostras. Em uma mata nativa (MATA sob LVdf, adjacente à área de estudo, foram coletadas 15 amostras adicionais por profundidade, as quais serviram de referência dos atributos avaliados. Os equipamentos utilizados no manejo da lavoura cafeeira foram tracionados por um trator cafeeiro Valmet® modelo 68. Para determinar a θcrítica para o tráfego do trator, foram consideradas apenas aquelas tensões que não excedem a resistência interna do solo expressa pela pressão de preconsolidação. As amostras indeformadas foram utilizadas para determinar a pressão de preconsolidação (σp em diferentes umidades volumétricas (θ e obtenção da densidade do solo (Ds. A

Efeito da profundidade de trabalho das hastes sulcadoras de uma semeadora-adubadora na patinagem, na força de tração e no consumo de combustível de um trator agrícola Effects of work operation depth of shanks in a seeder-fertilizer on slip, traction force and fuel consumption of a tractor

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Marcos Antonio Zambillo Palma

2010-10-01

Full Text Available A consolidação do sistema de semeadura direta trás grandes benefícios ao meio ambiente e, também, é notável a redução dos custos de produção devido a desnecessidade das operações como aração, subsolagem, escarificação e gradagem. Porém, nesse sistema se têm muitos problemas relacionados a compactação das camadas superficiais em função do tráfego de máquinas e a consorciação lavoura-pecuária. A solução encontrada pelos agricultores tem sido a substituição, na semeadora-adubadora, do sulcador disco duplo pela haste sulcadora que atua em profundidades superiores. O presente estudo teve como objetivo avaliar diferentes profundidades de trabalho da haste sulcadora, analisando o consumo de combustível, força de tração, índice de patinagem, potência na barra de tração, consumo específico de combustível e capacidade de campo teórica de um trator agrícola tracionando uma semeadora-adubadora em solo compactado pela integração lavoura-pecuária. Os tratamentos foram 100, 150, 200 e 250 mm de profundidade de trabalho da haste sulcadora, sendo os ensaios desenvolvidos no Departamento de Engenharia da Universidade Federal de Lavras, utilizando delineamento experimental de blocos, casualisados, composto por quatro tratamentos e três repetições. Dessa forma, conclui-se que o aumento da profundidade de trabalho da haste sulcadora em semeadoras-adubadoras de semeadura direta de milho em solos compactados ocorre o aumento no consumo de combustível, no índice de patinagem e no esforço de tração dos tratores agrícolas. Porém, quando a ponteira da haste sulcadora trabalhou posicionada 50 mm abaixo da camada mais compactada se teve reduções nos parâmetros força de tração e índice de patinagem, aumentando a capacidade de campo teórica.The direct sowing system brings many benefits to the environment and also reduction in production costs, since operations such as plowing, subsoiling, chiseling and harrowing

Real-Time Quantitative Operando Raman Spectroscopy of a CrOx/Al2O3 Propane Dehydrogenation Catalyst in a Pilot-Scale Reactor

NARCIS (Netherlands)

Sattler, Jesper J. H. B.; Mens, Ad M.; Weckhuysen, Bert M.

2014-01-01

Combined operando UV/vis-Raman spectroscopy has been used to study the deactivation of CrOx/Al2O3 catalyst extrudates in a pilot scale propane dehydrogenation reactor. For this purpose, UV/vis and Raman optical fiber probes have been designed, constructed and tested. The light absorption measured by

Operando investigation of Au-MnOx thin films with improved activity for the oxygen evolution reaction

DEFF Research Database (Denmark)

Frydendal, Rasmus; Seitz, Linsey C.; Sokaras, Dimosthenis

2017-01-01

The electrochemical splitting of water holds great potential as a method for producing clean fuels by storing electricity from intermittent energy sources. The efficiency of such a process would be greatly facilitated by incorporating more active catalysts based on abundant materials for the oxygen...... improvement over pure MnOx. These films are characterized with operando X-ray Absorption Spectroscopy, which reveal that Mn assumes a higher oxidation state under reaction conditions when Au is present. The magnitude of the enhancement is correlated to the size of the Au domains, where larger domains...

Characteristics of a tractor engine using mineral and biodiesel fuels blended with rapeseed oil Características de um motor de trator alimentado com combustíveis mineral e biodisel misturados com óleo de colza

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Tone Godeša

2010-10-01

medido na tomada de força do trator; porém diminuíram a potência máxima. Misturas com B100 e conteúdos de RO até 50% apresentaram correlações positivas com torque máximo e com a potência. Aumentando a proporção de RO de 0 a 50%, o consumo mínimo específico aumentou 6.6% com diesel e decresceu 3% com combustível baseado em B100.

Structural stability of naphthyl end-capped oligothiophenes in organic field-effect transistors measured by grazing-incidence X-ray diffraction in operando

DEFF Research Database (Denmark)

Huss-Hansen, Mathias K.; Lauritzen, Andreas E.; Bikondoa, Oier

2017-01-01

We report on microstructural durability of 5,5′-bis(naphth-2-yl)-2,2′-bithiophene (NaT2) in organic field-effect transistors (OFETs) in operando monitored by grazing-incidence X-ray diffraction (GIXRD). NaT2 maintains its monoclinic bulk motif in operating OFETs with a=20.31±0.06 Å, b=6.00±0.01 Å...

Operando Soft X-ray Absorption Spectroscopic Study on a Solid Oxide Fuel Cell Cathode during Electrochemical Oxygen Reduction.

Science.gov (United States)

Nakamura, Takashi; Oike, Ryo; Kimura, Yuta; Tamenori, Yusuke; Kawada, Tatsuya; Amezawa, Koji

2017-05-09

An operando soft X-ray absorption spectroscopic technique, which enabled the analysis of the electronic structures of the electrode materials at elevated temperature in a controlled atmosphere and electrochemical polarization, was established and its availability was demonstrated by investigating the electronic structural changes of an La 2 NiO 4+δ dense-film electrode during an electrochemical oxygen reduction reaction. Clear O K-edge and Ni L-edge X-ray absorption spectra could be obtained below 773 K under an atmospheric pressure of 100 ppm O 2 /He, 0.1 % O 2 /He, and 1 % O 2 /He gas mixtures. Considerable spectral changes were observed in the O K-edge X-ray absorption spectra upon changing the PO2 and application of electrical potential, whereas only small spectral changes were observed in Ni L-edge X-ray absorption spectra. A pre-edge peak of the O K-edge X-ray absorption spectra, which reflects the unoccupied partial density of states of Ni 3d-O 2p hybridization, increased or decreased with cathodic or anodic polarization, respectively. The electronic structural changes of the outermost orbital of the electrode material due to electrochemical polarization were successfully confirmed by the operando X-ray absorption spectroscopic technique developed in this study. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Operando PXD of Vanadium-Based Nanomaterials as Cathodes for Mg-ion Batteries

DEFF Research Database (Denmark)

Christensen, Christian Kolle; Sørensen, Daniel Risskov; Mathiesen, Jette

Exchanging the active specie, Li+ in Li-ion batteries by multivalent, abundant and cheap cations, such as Mg2+, are projected to boost the energy density and lower the cost per kilo-watt-hour significantly, making the Mg-ion battery technology a promising candidate for one of the battery...... with the host lattice of the electrodes and hampers facile ion transport. Therefore, development of novel electrode materials for effective Mg-ion storage is a vital step for the realization of this battery technology.3 In this study, we have synthesized series of vanadium oxides with varying chemical...... composition and varying nanotopologies, e.g. multiwalledVOx-nanotubes. The mechanism for Mg-intercalation and deintercalation is studied by operando synchrotron powder X-ray diffraction measured during battery operation. These results Mg-intercalation in the multiwalled VOx -nanotubes occurs within the space...

Desempenho operacional de semeadura-adubadora em diferentes manejos da cobertura e da velocidade Operational performance of seeder in different forward speed and winter cover crop management

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Carlos E. A. Furlani

2007-08-01

Full Text Available O presente trabalho teve como objetivo avaliar o desempenho de uma semeadora-adubadora no sistema plantio direto. Os fatores estudados foram três manejos das culturas de cobertura, selecionados em função do tamanho de fragmentos da vegetação, triturador de palhas (palha totalmente triturada, roçadora (palha parcialmente picada e rolo-facas (palha acamada, combinados com três velocidades do conjunto trator-semeadora-adubadora, sendo 4,0; 5,0 e 6,0 km h-1. O delineamento experimental foi em blocos casualizados, em esquema fatorial 3 x 3, com nove tratamentos e oito repetições, totalizando 72 observações. Para comparar os tratamentos, avaliaram-se a capacidade de campo operacional, a força de tração e a potência na barra, o consumo horário e por área, e a patinagem dos rodados do trator. O desempenho da semeadora-adubadora não foi influenciado pelos três manejos na cultura de cobertura vegetal. O aumento da velocidade provocou diminuição da força de tração, sendo o inverso para a capacidade de campo operacional e a potência na barra. O consumo horário de combustível aumentou com a velocidade, enquanto o operacional diminuiu.The present work aimed to evaluate the seeder performance in the direct sowing system. The studied factors were three cover crop managements, chosen according to the size of the vegetation fragment, such as straw (straw totally triturated, weeder (straw partially chopped and knife-rolls (straw practically entire, combined with three speeds of the seeder, being 4.0; 5.0 and 6.0 km h-1. The experimental outlining was carried out in casual blocks in factorial scheme 3 x 3, with nine treatments and eight repetitions, totalizing 72 observations. In the course of the experiment the following variants were evaluated: effective field capacity, force and power in the bar, hourly and area consumption of fuel and tractor’s pulleys sliding. The data reached were tabulated and submitted to factorial variant

Structural dynamics and activity of nanocatalysts inside fuel cells by in operando atomic pair distribution studies.

Science.gov (United States)

Petkov, Valeri; Prasai, Binay; Shan, Shiyao; Ren, Yang; Wu, Jinfang; Cronk, Hannah; Luo, Jin; Zhong, Chuan-Jian

2016-05-19

Here we present the results from a study aimed at clarifying the relationship between the atomic structure and activity of nanocatalysts for chemical reactions driving fuel cells, such as the oxygen reduction reaction (ORR). In particular, using in operando high-energy X-ray diffraction (HE-XRD) we tracked the evolution of the atomic structure and activity of noble metal-transition metal (NM-TM) nanocatalysts for ORR as they function at the cathode of a fully operational proton exchange membrane fuel cell (PEMFC). Experimental HE-XRD data were analysed in terms of atomic pair distribution functions (PDFs) and compared to the current output of the PEMFC, which was also recorded during the experiments. The comparison revealed that under actual operating conditions, NM-TM nanocatalysts can undergo structural changes that differ significantly in both length-scale and dynamics and so can suffer losses in their ORR activity that differ significantly in both character and magnitude. Therefore we argue that strategies for reducing ORR activity losses should implement steps for achieving control not only over the length but also over the time-scale of the structural changes of NM-TM NPs that indeed occur during PEMFC operation. Moreover, we demonstrate how such a control can be achieved and thereby the performance of PEMFCs improved considerably. Last but not least, we argue that the unique capabilities of in operando HE-XRD coupled to atomic PDF analysis to characterize active nanocatalysts inside operating fuel cells both in a time-resolved manner and with atomic level resolution, i.e. in 4D, can serve well the ongoing search for nanocatalysts that deliver more with less platinum.

Estudo sobre implementação de trabalho em grupos com autonomia: pesquisa quantitativa numa amostra de empresas operando no Brasil Study of the implementation of semi-autonomous groups and teamwork: survey research on a sample of enterprises operating in Brazil

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Paulo Eduardo Simonetti

2010-09-01

Full Text Available O artigo apresenta uma pesquisa sobre grupos semiautônomos e trabalho em grupos numa amostra intersetorial de 49 empresas operando no Brasil, as quais declararam utilizar equipes com autonomia em suas operações. Foi enviado um questionário com questões visando caracterizar as empresas, a abrangência da autonomia de suas equipes e os resultados obtidos a partir da sua utilização. Os dados foram submetidos a tratamento estatístico apropriado para variáveis não paramétricas, buscando encontrar possíveis correlações entre determinadas características das empresas, entre a abrangência da autonomia das equipes e respectivos resultados. Foi encontrada correlação positiva entre o grau de autonomia das equipes e resultados associados à sua capacidade superior de aprendizado, maior flexibilidade para responder a mudanças na produção e maior eficiência no fluxo de informações. O método (questionário e tratamento estatístico pode ser replicado por outros pesquisadores em outras amostras de empresas. Trata-se de pesquisa cujos resultados permitem agregar dados quantitativos para o entendimento da utilização da autonomia nas empresas brasileiras.This paper presents research on semi-autonomous groups and teamwork in an inter-sectorial sample of 49 firms operating in Brazil, which recognized the use of autonomous teams in its operations. A questionnaire was sent with questions aimed at profiling these firms, the comprehensiveness of the autonomy of their teams, and the results attained by adopting such teams with degrees of autonomy. Data were submitted to appropriate non-parametric statistical treatment, aiming to find possible correlations among characteristics of the firms, the comprehensiveness of the autonomy of the teams, and the respective results. A positive correlation was found between the degree of autonomy of teams and results linked to their superior learning ability, flexibility to respond to changes in the

Operando formation of an ultra-low friction boundary film from synthetic magnesium silicon hydroxide additive

Energy Technology Data Exchange (ETDEWEB)

Chang, Qiuying; Rudenko, Pavlo; Miller, Dean J.; Wen, Jianguo; Berman, Diana; Zhang, Yuepeng; Arey, Bruce; Zhu, Zihua; Erdemir, Ali

2017-06-01

The paper reports the operando and self-healing formation of DLC films at sliding contact surfaces by the addition of synthetic magnesium silicon hydroxide (MSH) nanoparticles to base oil. The formation of such films leads to a reduction of the coefficient of friction by nearly an order of magnitude and substantially reduces wear losses. The ultralow friction layer characterized by transmission electron microscope (TEM), electron energy loss spectroscopy (EELS), and Raman spectroscopy consists of amorphous DLC containing SiOx that forms in a continuous and self-repairing manner during operation. This environmentally benign and simple approach offers promise for significant advances in lubrication and reduced energy losses in engines and other mechanical systems.

An operando optical fiber UV–vis spectroscopic study of the catalytic decomposition of NO and N2O over Cu-ZSM-5

NARCIS (Netherlands)

Weckhuysen, B.M.; Groothaert, M.H.; Lievens, K.; Leeman, H.; Schoonheydt, R.A.

2003-01-01

The role of the bis(μ-oxo)dicopper core, i.e., [Cu2(μ-O)2]2+, in the decomposition of NO and N2O by the Cu-ZSM-5 zeolite has been studied with combined operando UV–vis monitoring of the catalyst and on-line GC analysis. An optical fiber was mounted on the outer surface of the quartz wall of the

Polarization Induced Changes in LSM Thin Film Electrode Composition Observed by In Operando Raman Spectroscopy and TOF-SIMS

DEFF Research Database (Denmark)

McIntyre, Melissa D.; Walker, Robert; Traulsen, Marie Lund

2015-01-01

an applied potential.1-3 The presented work explores the polarisation induced changes in LSM electrode composition by utilizing in operando Raman spectroscopy and post mortem ToF-SIMS depth profiling on LSM thin film model electrodes fabricated by pulsed laser deposition on YSZ substrates with a thin (200 nm...... recorded through the LSM thin film electrodes and revealed distinct compositional changes throughout the electrodes (Figure 2). The electrode elements and impurities separated into distinct layers that were more pronounced for the stronger applied polarisations. The mechanism behind this separation...

Operando XRD studies as a tool for determination of transport parameters of mobile ions in electrode materials

Science.gov (United States)

Kondracki, Łukasz; Kulka, Andrzej; Świerczek, Konrad; Ziąbka, Magdalena; Molenda, Janina

2017-11-01

In this work a detailed operando XRD investigations of structural properties of LixMn2O4 manganese spinel are shown to be a complementary, successful method of determination of diffusion coefficient D and surface exchange coefficient k in the working electrode. Kinetics of lithium ions transport are estimated on the basis of rate of structural changes of the cathode material during a relaxation stage after a high current charge, i.e. during structural relaxation of the material. The presented approach seems to be applicable as a complementary method of determination of transport coefficients for all intercalation-type electrode materials.

Understanding the Oxygen Evolution Reaction Mechanism on CoOx using Operando Ambient-Pressure X-ray Photoelectron Spectroscopy

International Nuclear Information System (INIS)

Favaro, Marco; Yang, Jinhui; Nappini, Silvia; Magnano, Elena

2017-01-01

Photoelectrochemical water splitting is a promising approach for renewable production of hydrogen from solar energy and requires interfacing advanced water-splitting catalysts with semiconductors. Understanding the mechanism of function of such electrocatalysts at the atomic scale and under realistic working conditions is a challenging, yet important, task for advancing efficient and stable function. This is particularly true for the case of oxygen evolution catalysts and, here, we study a highly active Co 3 O 4 /Co(OH) 2 biphasic electrocatalyst on Si by means of operando ambient-pressure X-ray photoelectron spectroscopy performed at the solid/liquid electrified interface. Spectral simulation and multiplet fitting reveal that the catalyst undergoes chemical-structural transformations as a function of the applied anodic potential, with complete conversion of the Co(OH) 2 and partial conversion of the spinel Co 3 O 4 phases to CoO(OH) under precatalytic electrochemical conditions. Furthermore, we observe new spectral features in both Co 2p and O 1s core-level regions to emerge under oxygen evolution reaction conditions on CoO(OH). The operando photoelectron spectra support assignment of these newly observed features to highly active Co 4+ centers under catalytic conditions. Comparison of these results to those from a pure phase spinel Co 3 O 4 catalyst supports this interpretation and reveals that the presence of Co(OH) 2 enhances catalytic activity by promoting transformations to CoO(OH). The direct investigation of electrified interfaces presented in this work can be extended to different materials under realistic catalytic conditions, thereby providing a powerful tool for mechanism discovery and an enabling capability for catalyst design.

Rede de atencao a saude bucal: organizacao em municipios de grande porte de Santa Catarina, Brasil

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Heloisa Godoi

2014-02-01

Full Text Available O estudo objetivou analisar a rede de atenção à saúde bucal em municípios com mais de 100 mil habitantes de Santa Catarina, Brasil, pela identificação e integração de seus elementos constitutivos. Dados primários foram obtidos por meio da aplicação de questionário aos gestores municipais de saúde bucal. Dados secundários foram coletados em bases de dados do SUS e fornecidos pelas Secretarias Municipais e Estadual de Saúde. Os municípios ofertam serviços de saúde bucal em todos os níveis de atenção, mas encontram-se em distintos estágios de implementação da rede. Também realizam algumas ações para consolidação desta, como inserção de ferramentas para integração dos serviços de atenção básica aos especializados e reorientação da atenção básica, como coordenadora da rede. As limitações incluem dificuldade em definir a população da rede de acordo com critérios epidemiológicos, fragilidade dos sistemas logísticos e de governança, além da necessidade de ampliação das equipes de saúde bucal na Estratégia Saúde da Família, operando segundo princípios de vigilância à saúde.

In operando PXRD study P2-NaxTMO2 cycled in a sodium ion battery

DEFF Research Database (Denmark)

Birgisson, Steinar; Shen, Yanbin; Christiansen, Troels Lindahl

Sodium ion batteries (SIB) are being considered as a cheaper and more environmentally friendly alternative to lithium ion batteries (LIB). Application of SIB is especially important in large scale electricity storage from renewable energy sources [1]. A mayor hindrance of the development of SIB...... for practical applications is that so far there are no known electrode materials with sufficiently good rate and cycling capability. Studying structural changes of electrode materials while the battery is being charged and discharged is important to gain a deeper understanding of processes affecting...... the electrode materials. This understanding can be used to optimize battery performance and understand decay mechanisms, which in turn will facilitate the development of electrode materials fit for practical application in SIB. Our research group has developed an in operando battery cell capable of following...

Simulação da uniformidade da irrigação de sistemas convencionais de aspersão operando sob diferentes condições de vento Water application uniformity simulation of solid set sprinkler systems operating under different wind conditions

Directory of Open Access Journals (Sweden)

Lessandro C. Faria

2009-03-01

Full Text Available A uniformidade de aplicação de água é um importante fator a ser considerado na avaliação dos sistemas de irrigação por aspersão. A uniformidade em sistemas convencionais de aspersão depende de fatores como: o tipo de aspersor e suas condições operacionais, a disposição e o espaçamento entre aspersores no campo, e a velocidade e a direção do vento durante o período de aplicação de água. Tendo em visa que as complexas relações entre esses fatores e a uniformidade podem ser caracterizadas de forma mais eficiente com o auxílio da modelagem matemática, neste estudo, foram avaliadas simulações, fornecidas pelo modelo semiempírico de RICHARDS & WEATHERHEAD (1993, da distribuição espacial da água aplicada pelo canhão PLONA-RL250, operando sob diferentes condições de vento. Valores de uniformidade de Christiansen (CUC, obtidos com dados de ensaios de campo e em simulações digitais, foram comparados, mostrando-se, por meio de diversos índices (R² = 0,73; desvio absoluto médio de 4,1% e índice de desempenho de 0,78, que o modelo semiempírico avaliado fornece estimativas adequadas do CUC de sistemas convencionais de irrigação. Demonstra-se que a modelagem matemática permite reduzir o esforço e o tempo requeridos em trabalhos de campo envolvendo a avaliação da distribuição de água de canhões hidráulicos operando sob condições de vento.The water application uniformity is an important factor to be considered on the sprinkler irrigation system evaluation. Solid set sprinkler system water application uniformity depends on factors such as: sprinkler type and its operational conditions, sprinkler disposition and spacing on the field, and wind velocity and direction during water application periods. Considering that the complex relationships among these factors and uniformity are more efficiently characterized by employing mathematical modeling, this study aimed to evaluate simulations, provided by the RICHARDS

In-operando elucidation of bimetallic CoNi nanoparticles during high-temperature CH 4 /CO 2 reaction

KAUST Repository

Al-Sabban, Bedour

2017-05-02

Dry reforming of methane (DRM) proceeds via CH4 decomposition to leave surface carbon species, followed by their removal with CO2-derived species. Reactivity tuning for stoichiometric CH4/CO2 reactants was attempted by alloying the non-noble metals Co and Ni, which have high affinity with CO2 and high activity for CH4 decomposition, respectively. This study was focused on providing evidence of the capturing surface coverage of the reactive intermediates and the associated structural changes of the metals during DRM at high temperature using in-operando X-ray absorption spectroscopy (XAS). On the Co catalysts, the first-order effects with respect to CH4 pressure and negative-order effects with respect to CO2 pressure on the DRM rate are consistent with the competitive adsorption of the surface oxygen species on the same sites as the CH4 decomposition reaction. The Ni surface provides comparatively higher rates of CH4 decomposition and the resultant DRM than the Co catalyst but leaves some deposited carbon on the catalyst surface. In contrast, the bimetallic CoNi catalyst exhibits reactivity towards the DRM but with kinetic orders resembling Co catalyst, producing negligible carbon deposition by balancing CH4 and CO2 activation. The in-operando X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) measurements confirmed that the Co catalyst was progressively oxidized from the surface to the bulk with reaction time, whereas CoNi and Ni remained relatively reduced during DRM. Density functional theory (DFT) calculation considering the high reaction temperature for DRM confirmed the unselective site arrangement between Co and Ni atoms in both the surface and bulk of the alloy nanoparticle (NP). The calculated heat of oxygen chemisorption became more exothermic in the order of Ni, CoNi, Co, consistent with the catalytic behavior. The comprehensive experimental and theoretical evidence provided herein clearly suggests

An equipment for measuring tractor fuel consumption in agricultural experiments

OpenAIRE

Gonzalez Maziero, José Valdemar; Corrêa, Ila Maria; Yanai, Kiyoshi; Menezes, João Floriano de

1992-01-01

É descrito e aferido (em condições de laboratório) um equipamento para medição de consumo de combustível para uso em experimentos com máquinas agrícolas. O medidor, construído com tubos-reservatórios de PVC, tubo de vidro graduado, tanque plástico de combustível e eletroválvulas (12 VCC), é ligado ao sistema de alimentação do trator com mangueiras de plástico de baixa pressão, controlando-se o fluxo de combustível mediante uma chave elétrica liga/desliga. Faz parte do conjunto um medidor de t...

Direct observation of lithium polysulfides in lithium-sulfur batteries using operando X-ray diffraction

Science.gov (United States)

Conder, Joanna; Bouchet, Renaud; Trabesinger, Sigita; Marino, Cyril; Gubler, Lorenz; Villevieille, Claire

2017-06-01

In the on going quest towards lithium-battery chemistries beyond the lithium-ion technology, the lithium-sulfur system is emerging as one of the most promising candidates. The major outstanding challenge on the route to commercialization is controlling the so-called polysulfide shuttle, which is responsible for the poor cycling efficiency of the current generation of lithium-sulfur batteries. However, the mechanistic understanding of the reactions underlying the polysulfide shuttle is still incomplete. Here we report the direct observation of lithium polysulfides in a lithium-sulfur cell during operation by means of operando X-ray diffraction. We identify signatures of polysulfides adsorbed on the surface of a glass-fibre separator and monitor their evolution during cycling. Furthermore, we demonstrate that the adsorption of the polysulfides onto SiO2 can be harnessed for buffering the polysulfide redox shuttle. The use of fumed silica as an electrolyte additive therefore significantly improves the specific charge and Coulombic efficiency of lithium-sulfur batteries.

Comparative analysis of the especific weight and its effects on the selection and use of the brazilian wheeled tractors

OpenAIRE

Schlosser, José Fernando; Debiasi, Henrique; Willes, Jorge Alex; Machado, Otávio Dias da C.

2005-01-01

O peso do trator influi diretamente na recomendação e no seu desempenho a campo. Esta variável é, muitas vezes, característica do fabricante, induzindo a necessidade de informações comparativas entre os modelos. O objetivo deste trabalho foi estudar os tratores agrícolas brasileiros no que se refere ao peso, visando obter dados que auxiliem na seleção e no seu uso adequado. O levantamento englobou 103 modelos de tratores comerciais das marcas Massey Ferguson, Agrale, New Holland, John Deere, ...

Total oxidation of VOCs on Pd and/or Au supported on TiO2/ZrO2 followed by ''operando'' Drift

International Nuclear Information System (INIS)

Hosseini, M.; Siffert, St.; Cousin, R.; Aboukais, A.; Hadj-Sadok, Z.; Bao-Lian, Su

2009-01-01

Catalytic performances of nano-structured meso-porous TiO 2 -ZrO 2 mixed oxides impregnated by Pd and/or Au were studied in toluene total oxidation in a fixed bed micro-reactor and with 'operando' DRIFT. Meso-porous TiO 2 -ZrO 2 mixed oxides with various Ti:Zr mole ratio of 80/20, 50/50 and 20/80, high surface areas were synthesised using a mixture of zirconium prop-oxide and titanium iso-prop-oxide as Zr and Ti sources and also CTMABr as surfactant. The new supports are impregnated by 0.5 or 1.5 wt% of palladium and 1 wt% of gold using impregnation and Deposition-Precipitation methods. The catalytic activity for the nano-structured meso-porous TiO 2 -ZrO 2 mixed oxides varies depending on the molar ratio of Ti:Zr and also for all series of the studied catalysts impregnated by Pd and/or Au, when the gold is loaded firstly the activity in toluene complete oxidation is higher than when Pd was deposited firstly (PdAu/TZ ≥ 1.5Pd/TZ ≥ AuPd/TZ ≥ Pd/TZ ≥ Au/TZ ≥ TZ). The highest activity of PdAu/TZ (80/20) can be related to the higher acid sites density of the support and also to the presence of a synergetic effect between palladium and gold. 'Operando' DRIFT allowed following the VOCs oxidation but also suggesting an interaction between the adsorbed molecule and the catalyst which decreases when the activity for oxidation reaction increases. (authors)

Operando studies of all-vanadium flow batteries: Easy-to-make reference electrode based on silver-silver sulfate

Science.gov (United States)

Ventosa, Edgar; Skoumal, Marcel; Vázquez, Francisco Javier; Flox, Cristina; Morante, Joan Ramon

2014-12-01

In-depth evaluation of the electrochemical performance of all-vanadium redox flow batteries (VRFBs) under operando conditions requires the insertion of a reliable reference electrode in the battery cell. In this work, an easy-to-make reference electrode based on silver-silver sulfate is proposed and described for VRFBs. The relevance and feasibility of the information obtained by inserting the reference electrode is illustrated with the study of ammoxidized graphite felts. In this case, we show that the kinetic of the electrochemical reaction VO2+/VO2+ is slower than that of V2+/V3+ at the electrode. While the slow kinetics at the positive electrode limits the voltage efficiency, the operating potential of the negative electrode, which is outside the stability widow of water, reduces the coulombic efficiency due to the hydrogen evolution.

Influence of artificially aged gas diffusion layers on the water management of polymer electrolyte membrane fuel cells analyzed with in-operando synchrotron imaging

International Nuclear Information System (INIS)

Arlt, Tobias; Klages, Merle; Messerschmidt, Matthias; Scholta, Joachim; Manke, Ingo

2017-01-01

The influence of artificial ageing of gas diffusion layers (GDLs) on the cell performance was investigated using high resolution synchrotron radiography. State-of-the-art GDLs of the type SIGRACET ® SGL 25BC were aged for 0 h, 16 h and 24 h in a hydrogen peroxide solution before they were assembled in the fuel cells. In-operando radiographic measurements were combined with voltage and contact angle measurements. Correlations between applied ageing conditions, GDL water saturation and cell performance were revealed. Hereby, all cell operating conditions were tested several times to estimate the reproducibility of in-operando radiographic fuel cell measurements. Water films at the GDL-membrane and at the GDL-flow field interfaces were found and attributed to MPL cracks and large pores in the GDL structure. The combination of these cracks and pores are assumed to play a crucial role for blocked gas paths, leading to an undersupply with reactants and an increased humidification of the membrane. It is shown that water agglomerations directly impact the membrane resistance. We assume that the hydrophobicity of the fibers inside the GDL is more important for the cell performance than water agglomerations at the membrane-GDL interface. - Highlights: • Influence of ageing of gas diffusion layers on cell performance was investigated. • Cell performance decreased using artificially aged GDLs. • Performance decrease correlated to altered water distribution. • Reproducibility of water thickness measurements with synchrotron imaging.

Propiedades termofísicas del jugo concentrado de lulo a temperaturas por encima del punto de congelación Propriedades termofísicas de suco concentrado de lulo em temperaturas acima do ponto de congelamento

Directory of Open Access Journals (Sweden)

Glória Ines Giraldo-Gómez

2010-05-01

Full Text Available En este trabajo fueron determinados experimentalmente el calor específico, conductividad térmica, difusividad térmica y densidad del jugo de lulo en el rango de contenido de agua de 0.55 a 0.90 (p/p en base húmeda y en temperaturas variando de 4 a 78.6 °C. La conductividad térmica y el calor específico fueron obtenidos utilizando el mismo aparato - una célula constituida de dos cilindros concéntricos - operando en estado estacionario y no- estacionario, respectivamente. La difusividad térmica fue obtenida a través del método de Dickerson y la densidad determinada por picnometria. Tanto la temperatura como el contenido de agua presentaron una fuerte influencia en los datos experimentales de las propiedades termofísicas del jugo de lulo. Los resultados obtenidos fueron utilizados para obtener modelos matemáticos y predecir estas propiedades en función de la concentración y la temperatura.Neste trabalho, foram determinados experimentalmente o calor específico, a condutividade térmica, difusividade térmica e densidade de suco de lulo na faixa de conteúdo de água entre 0,55 e 0,90 (p/p em base úmida e em temperaturas entre 4 e 78,6 °C. A condutividade térmica e o calor específico foram obtidos utilizando-se o mesmo equipamento - uma célula constituída de dois cilindros concêntricos - operando em estado estacionário e não estacionário, respectivamente. A difusividade térmica foi obtida através do método de Dickerson e a densidade determinada por picnometria. Tanto a temperatura como o conteúdo de água apresentaram grande influência nos dados experimentais das propriedades termofísicas do suco de lulo. Os resultados obtidos foram utilizados na obtenção de modelos matemáticos para predizer estas propriedades em função da concentração e temperatura.

Deactivation of Zeolite Catalyst H-ZSM-5 during Conversion of Methanol to Gasoline: Operando Time- and Space-Resolved X-ray Diffraction.

Science.gov (United States)

Rojo-Gama, Daniel; Mentel, Lukasz; Kalantzopoulos, Georgios N; Pappas, Dimitrios K; Dovgaliuk, Iurii; Olsbye, Unni; Lillerud, Karl Petter; Beato, Pablo; Lundegaard, Lars F; Wragg, David S; Svelle, Stian

2018-03-15

The deactivation of zeolite catalyst H-ZSM-5 by coking during the conversion of methanol to hydrocarbons was monitored by high-energy space- and time-resolved operando X-ray diffraction (XRD) . Space resolution was achieved by continuous scanning along the axial length of a capillary fixed bed reactor with a time resolution of 10 s per scan. Using real structural parameters obtained from XRD, we can track the development of coke at different points in the reactor and link this to a kinetic model to correlate catalyst deactivation with structural changes occurring in the material. The "burning cigar" model of catalyst bed deactivation is directly observed in real time.

Does Pelletizing Catalysts Influence the Efficiency Number of Activity Measurements? Spectrochemical Engineering Considerations for an Accurate Operando Study

DEFF Research Database (Denmark)

Rasmussen, Søren Birk; Perez-Ferreras, Susana; Banares, Miguel A.

2013-01-01

of, for example, support oxides might take place, which in turn affects the pore size distribution and the porosity of the catalyst, leading to the observation of lower activity values due to decreased catalyst efficiency. This phenomenon can also apply to conventional activity measurements......, in the cases that pelletizing and recrushing of samples are performed to obtain adequate particle size fractions for the catalytic bed. A case study of an operand investigation of a V2O3-WO3/TiO2-sepiolite catalyst is used as an example, and simple calculations of the influence of catalyst activity...... and internal pore diffusion properties are considered in this paper for the evaluation of catalyst performance in, for example, operando reactors. Thus, it is demonstrated that with a pelletizing pressure of...

INOVAÇÃO EM PEQUENA EMPRESA DE SERVIÇOS COM FOCO NA CAPACITAÇÃO TECNOLÓGICA

Directory of Open Access Journals (Sweden)

Emmanuel Paiva de Andrade

2015-08-01

Full Text Available Diante do atual cenário de incertezas e marcado por alta competição entre empresas, inovar se tornou imprescindível para garantir a sustentabilidade e o sucesso das organizações. Através da gestão da inovação é possível criar condições para que ocorra o processo contínuo e permanente de inovações. Com o intuito de estudar este processo em uma empresa familiar, operando em um território marcado pela presença intensa da indústria de óleo e gás, selecionou-se uma pequena empresa de serviços, analisando seu perfil, padrão de comportamento e capacidade tecnológica. Utilizou-se para tal a taxonomia de maturidade para inovar proposta por Figueiredo (2011, por meio da qual foi possível aferir o nível de inovação da empresa e propor subsídios para uma política de inovação que fosse factível de ser implementada a partir dos recursos disponíveis e acessíveis pela empresa e que pudesse nortear de forma sustentável o seu plano de crescimento.

Seleção de tratores agrícolas adequados à agricultura familiar.

OpenAIRE

Andersson, Norberto Luiz Marques

2010-01-01

Os agricultores de base familiar trabalham em suas áreas, primeiramente com culturas vegetais que garantam sua subsistência, para isso utilizam criatividade e recursos disponíveis dentro da propriedade, com a finalidade de facilitação do trabalho e diminuição de custos, utilizando a diversificação de cultivos como ação necessária para sua segurança alimentar. Na medida em que começam a existir recursos disponibilizados através de linhas de crédito governamentais, compatíveis ...

Quantifying redox-induced Schottky barrier variations in memristive devices via in operando spectromicroscopy with graphene electrodes

Science.gov (United States)

Baeumer, Christoph; Schmitz, Christoph; Marchewka, Astrid; Mueller, David N.; Valenta, Richard; Hackl, Johanna; Raab, Nicolas; Rogers, Steven P.; Khan, M. Imtiaz; Nemsak, Slavomir; Shim, Moonsub; Menzel, Stephan; Schneider, Claus Michael; Waser, Rainer; Dittmann, Regina

2016-08-01

The continuing revolutionary success of mobile computing and smart devices calls for the development of novel, cost- and energy-efficient memories. Resistive switching is attractive because of, inter alia, increased switching speed and device density. On electrical stimulus, complex nanoscale redox processes are suspected to induce a resistance change in memristive devices. Quantitative information about these processes, which has been experimentally inaccessible so far, is essential for further advances. Here we use in operando spectromicroscopy to verify that redox reactions drive the resistance change. A remarkable agreement between experimental quantification of the redox state and device simulation reveals that changes in donor concentration by a factor of 2-3 at electrode-oxide interfaces cause a modulation of the effective Schottky barrier and lead to >2 orders of magnitude change in device resistance. These findings allow realistic device simulations, opening a route to less empirical and more predictive design of future memory cells.

Avaliação técnica e econômica da extração de madeira de eucalipto com"clambunk skidder" Technical and economic evaluation of eucalyptus log extraction using a clambunk skidder

Directory of Open Access Journals (Sweden)

Robson José de Oliveira

2006-04-01

Full Text Available O presente estudo teve como objetivo avaliar técnica e economicamente atividades de extração de madeira em vários declives, utilizando-se um trator florestal arrastador ("clambunk skidder" com rodado de pneus recoberto por esteiras. A avaliação técnica consistiu em determinar os índices de produtividade, e a avaliação econômica baseou-se na determinação dos custos operacionais da máquina. O delineamento experimental foi inteiramente casualizado, no esquema fatorial 3 x 2 x 5 (três níveis de declive, duas classes de produtividade florestal e cinco níveis de distâncias de extração com três repetições. Os resultados demonstraram que os estratos situados em menores declives e distâncias de extração apresentaram maior produtividade em relação àqueles de maiores declives e distâncias de extração. A produtividade do trator florestal arrastador avaliado variou entre 18,34 m³.h-1 e 72,08 m³.h-1, com custo operacional médio de US$90,93 por hora efetiva de trabalho.The objective of this study was to evaluate technical and economic log extraction activities using a clambunk skidder with tracks over the tires. The technical evaluation consisted in determining the log extraction productivity indexes and the economic evaluation was based on operational cost determination. The experimental design was complete randomized, with a 3x2x5 factorial arrangement (three slope levels, two wood productivity classes and five ranks of extraction distance, with three repetitions. In a general way, the results showed that the equipment productivity decreases with the increase of the slope terrain and the extraction distance. Its productivity varied from 18.34 m³.h-1 to 72.08 m³.h-1. The operational cost was US$ 90.93 per effective worked hour.

Directly observing catalytic intermediates of methane dry reforming (MDR) on model Ni(111) catalyst via in operando surface techniques

Science.gov (United States)

Yuan, Kaidi

In this work, near ambient pressure x-ray photoelectron spectroscopy was used to trace the in operando catalytic intermediates of methane dry reforming on model Ni(111) catalyst. The following reactive carbon intermediates have been characterized from dissociation of CH4: *CH, *C1 (Ni3C), *Cn (n≥2) and clock-reconstructed Ni2C. They can develop into inert graphene, and the conditions for this transition have been explored. One the other hand, the oxygen intermediates from CO2 dissociation were also studied, which play an important role on restraining graphene growth. Their dynamic coverage decreases with increasing temperature, which is suggested the fundamental mechanism of regional carbon overspill and causes irreversible graphene formation. Therefore, solutions based on Ni-O stabilization were proposed in developing coking resisting catalysts.

Tráfego de máquinas e enraizamento do milho em plantio direto Traffic of machines and routing of maize in no tillage

Directory of Open Access Journals (Sweden)

Jair Seixas

2005-08-01

Full Text Available Freqüentemente a adoção do sistema plantio direto está associado ao surgimento da compactação ou adensamento da superfície do solo, quer pelo seu não revolvimento, quer pelo tráfego de máquinas e equipamentos agrícolas e de transporte. Com o objetivo de estudar alguns fatores que interferem na compactação do solo em plantio direto e seus efeitos na cultura do milho, foi instalado um experimento em Latossolo Vermelho Distroférrico Típico, na região sudoeste do Paraná, município de Dois Vizinhos, no ano agrícola de 1999. A superfície do solo foi trabalhada para atingir quatro níveis de possíveis compactações: (1 tráfego de colheitadeira carregada com peso de 12.000kgf; (2 tráfego de um trator agrícola com peso de 4.000kgf; (3 descompactação com subsolador de 4 hastes a 0,40m; (4 uma parcela testemunha. Avaliou-se o desenvolvimento do sistema radicular do milho em perfis através de trincheiras em todas as parcelas, efetuando a contagem do número de raízes e sua distribuição em profundidade no perfil, correlacionando com o rendimento de grãos de milho. Os resultados obtidos mostraram que: (1 o tratamento que sofreu tráfego do trator agrícola apresentou efeito negativo da compactação do solo demonstrada pela menor produtividade obtida; (2 os tratamentos que não sofreram compressão do solo (subsolador e testemunha apresentaram maiores produtividades e também maior densidade de raízes, com sua distribuição mais homogênea no perfil do solo. Foram observados efeitos negativos da possível compressão do solo pelo trabalho artificial produzido pelas máquinas agrícolas nas parcelas trabalhadas, o que comprometeu a distribuição e quantidade de raízes no perfil do solo, bem como o rendimento de grãos de milho.Frequently the adoption of the system of no tillage is associated with the appearance of the compacting or thickness of the ground surface, either by not revolving or by the traffic of machines, trucks

DESEMPENHO SISTEMA DE IRRIGAÇÃO FIXA EM MICROASPERSOR DE ALTA VAZÃO PARA CONDIÇÕES DO NORTE DO ESTADO DO ESPÍRITO SANTO

Directory of Open Access Journals (Sweden)

Jean Karlos Barros Galote

2017-03-01

Full Text Available Advento das mudanças climáticas, a escassez hídrica torna-se fator de risco para agricultura, responsável pela retirada de 70% da água doce dos mananciais. A fim de minimizar os desperdícios, buscam-se sistemas de irrigação eficientes bem manejados. Uma forma de verifica a eficiência de um sistema de irrigação é por meio da avaliação da uniformidade de aplicação de água. O coeficiente de uniformidade de Christiansen (CUC é uma ferramenta eficiente e bastante utilizada. A fim de avaliar o desempenho de um sistema de irrigação fixa em microaspersor de alta vazão, para as condições climáticas do norte do Espírito Santo, avaliou-se o CUC para o sistema de irrigação operando sobre as pressões de serviço de 155, 207, 258 e 310 kPa, em diferentes horários (04h00min, 12h00min, e 21h00min no período de setembro de 2015 a julho de 2016, compreendendo a estações secas e chuvosas. O CUC variou de 77,4 a 93,5% em virtude do horário e pressão utilizada.

Design and realization of a sputter deposition system for the in situ- and in operando-use in polarized neutron reflectometry experiments

Science.gov (United States)

Schmehl, Andreas; Mairoser, Thomas; Herrnberger, Alexander; Stephanos, Cyril; Meir, Stefan; Förg, Benjamin; Wiedemann, Birgit; Böni, Peter; Mannhart, Jochen; Kreuzpaintner, Wolfgang

2018-03-01

We report on the realization of a sputter deposition system for the in situ- and in operando-use in polarized neutron reflectometry experiments. Starting with the scientific requirements, which define the general design considerations, the external limitations and boundaries imposed by the available space at a neutron beamline and by the neutron and vacuum compatibility of the used materials, are assessed. The relevant aspects are then accounted for in the realization of our highly mobile deposition system, which was designed with a focus on a quick and simple installation and removability at the beamline. Apart from the general design, the in-vacuum components, the auxiliary equipment and the remote control via a computer, as well as relevant safety aspects are presented in detail.

PRELIMINARY NOTE ON FODDER PLANT CONSERVATION IN TRENCH TYPE SILOS NOTAS PRELIMINARES SOBRE CONSERVAÇÃO DE FORRAGENS EM SILOS DO TIPO TRINCHEIRA

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Anatoly Kravchenko

2007-09-01

Full Text Available

This study has the objective of evaluating the quality of silage (Napier, 60%; sorghum, 30%; and sugar-cane, 10% conserved in trench-silos. The silos were built with side and back walls made of bricks, with no waterproof or revetment process. The floor was in direct contact with the soil, and the forage was distributed in 25cm-layers and compressed with the use of a tire tractor. The biggest losses, caused by ascetic and butyric fermentation, harmful to the cattle, took place close to the walls, due to a lack of compactness and a direct contact between the forage and the soil. The poor roof also allowed the penetration of water and other agents responsible for the formation of butyric acid. It was concluded that the waterproof process is the main factor in the desirable fermentation and conservation of the silage.

Este trabalho tem como objetivo avaliar a qualidade da silagem - Napier (60%, sorgo (30% e cana (10% - conservada em silos tipo trincheira. Os silos foram construídos com paredes de tijolos nas laterais e no fundo, sem impermeabilização ou revestimento. O piso ficou em contato direto com o solo. A forragem foi distribuída em camadas de 25 cm e comprimida com trator de pneu. As perdas maiores, decorrentes das fermentações acética e butírica, prejudiciais ao rebanho, ocorreram junto às paredes, por falta de compactação e pelo contato direto da forragem com o solo. A má cobertura também favoreceu a penetração de água e os agentes formadores de ácido butírico. Concluiu-se que a impermeabilização é o fator principal para uma fermentação e conservação desejável da silagem.

PALAVRAS-CHAVE: Silo; forragem; Sorgum; Penisetum.

Partida de reator anaeróbio compartimentado em série com um reator anaeróbio de manta de lodo, utilizando parâmetros de sedimentabilidade para formação da biomassa

Directory of Open Access Journals (Sweden)

Cristine Serafine Neves

2015-12-01

Full Text Available RESUMO Este estudo objetivou avaliar a formação da biomassa de boa qualidade tanto no reator anaeróbio compartimentado (RAC quanto no reator anaeróbio de manta de lodo (UASB, aplicando parâmetros adequados à sedimentação dos sólidos sedimentáveis (SS presentes na água residuária de suinocultura (ARS. O RAC e o UASB operaram em série com os tempos de detenção hidráulica (TDHs de 15 e 9h, respectivamente, correspondendo a cargas orgânicas volumétricas (COVs médias de 53,8 e 36,2 kg.m³.d¹ em termos de DQOT, respectivamente. As eficiências médias de remoção de DBO520°C, durante o processo de partida e formação da biomassa, foram: 68% para RAC e 55% para UASB, e em termos de DQO: 78% para RAC e 70% para UASB, respectivamente. Os autores concluíram que é possível, mediante os parâmetros de sedimentação adotados, formar uma biomassa peletizada, mesmo operando o sistema com altas cargas orgânicas.

Insights into the Activity and Deactivation of the Methanol-to-Olefins Process over Different Small-Pore Zeolites As Studied with Operando UV–vis Spectroscopy

Science.gov (United States)

2017-01-01

The nature and evolution of the hydrocarbon pool (HP) species during the Methanol-to-Olefins (MTO) process for three small-pore zeolite catalysts, with a different framework consisting of large cages interconnected by small eight-ring windows (CHA, DDR, and LEV) was studied at reaction temperatures between 350 and 450 °C using a combination of operando UV–vis spectroscopy and online gas chromatography. It was found that small differences in cage size, shape, and pore structure of the zeolite frameworks result in the generation of different hydrocarbon pool species. More specifically, it was found that the large cage of CHA results in the formation of a wide variety of hydrocarbon pool species, mostly alkylated benzenes and naphthalenes. In the DDR cage, 1-methylnaphthalene is preferentially formed, while the small LEV cage generally contains fewer hydrocarbon pool species. The nature and evolution of these hydrocarbon pool species was linked with the stage of the reaction using a multivariate analysis of the operando UV–vis spectra. In the 3-D pore network of CHA, the reaction temperature has only a minor effect on the performance of the MTO catalyst. However, for the 2-D pore networks of DDR and LEV, an increase in the applied reaction temperature resulted in a dramatic increase in catalytic activity. For all zeolites in this study, the role of the hydrocarbon species changes with reaction temperature. This effect is most clear in DDR, in which diamantane and 1-methylnaphthalene are deactivating species at a reaction temperature of 350 °C, whereas at higher temperatures diamantane formation is not observed and 1-methylnaphthalene is an active species. This results in a different amount and nature of coke species in the deactivated catalyst, depending on zeolite framework and reaction temperature. PMID:28603658

Insights into the Activity and Deactivation of the Methanol-to-Olefins Process over Different Small-Pore Zeolites As Studied with Operando UV-vis Spectroscopy.

Science.gov (United States)

Goetze, Joris; Meirer, Florian; Yarulina, Irina; Gascon, Jorge; Kapteijn, Freek; Ruiz-Martínez, Javier; Weckhuysen, Bert M

2017-06-02

The nature and evolution of the hydrocarbon pool (HP) species during the Methanol-to-Olefins (MTO) process for three small-pore zeolite catalysts, with a different framework consisting of large cages interconnected by small eight-ring windows (CHA, DDR, and LEV) was studied at reaction temperatures between 350 and 450 °C using a combination of operando UV-vis spectroscopy and online gas chromatography. It was found that small differences in cage size, shape, and pore structure of the zeolite frameworks result in the generation of different hydrocarbon pool species. More specifically, it was found that the large cage of CHA results in the formation of a wide variety of hydrocarbon pool species, mostly alkylated benzenes and naphthalenes. In the DDR cage, 1-methylnaphthalene is preferentially formed, while the small LEV cage generally contains fewer hydrocarbon pool species. The nature and evolution of these hydrocarbon pool species was linked with the stage of the reaction using a multivariate analysis of the operando UV-vis spectra. In the 3-D pore network of CHA, the reaction temperature has only a minor effect on the performance of the MTO catalyst. However, for the 2-D pore networks of DDR and LEV, an increase in the applied reaction temperature resulted in a dramatic increase in catalytic activity. For all zeolites in this study, the role of the hydrocarbon species changes with reaction temperature. This effect is most clear in DDR, in which diamantane and 1-methylnaphthalene are deactivating species at a reaction temperature of 350 °C, whereas at higher temperatures diamantane formation is not observed and 1-methylnaphthalene is an active species. This results in a different amount and nature of coke species in the deactivated catalyst, depending on zeolite framework and reaction temperature.

Structural Dynamics and Activity of Nanocatalysts Inside Fuel Cells by in-operando Atomic Pair Distribution Studies

Science.gov (United States)

Prasai, Binay

We present the results from a study aimed at clarifying the relationship between the atomic structure and activity of nanocatalysts for chemical reactions driving fuel cells, such as the oxygen reduction reaction (ORR). Using in-operando high-energy X-ray diffraction we tracked the evolution of the atomic structure and activity of noble metal-transition metal(NM-TM) nanocatalysts for ORR as they function at the cathode of a fully operational proton exchange membrane fuel cell (PEMFC). Data were analyzed in terms of atomic pair distribution functions and compared to the current output of the PEMFC, which was also recorded during the experiments. The comparison revealed that under actual operating conditions, NM-TM nanocatalysts can undergo structural changes that differ significantly in both length-scale and dynamics and so can suffer losses in their ORR activity that differ significantly in both character and magnitude. Therefore, we argue that strategies for reducing ORR activity losses should implement steps for achieving control not only over the length but also over the time-scale of the structural changes of NM-TM NPs that indeed occur during PEMFC operation.

A high-temperature, ambient-pressure ultra-dry operando reactor cell for Fourier-transform infrared spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Köck, Eva-Maria; Kogler, Michaela; Pramsoler, Reinhold; Klötzer, Bernhard; Penner, Simon, E-mail: simon.penner@uibk.ac.at [Institute of Physical Chemistry, University of Innsbruck, Innrain 80-82, A-6020 Innsbruck (Austria)

2014-08-15

The construction of a newly designed high-temperature, high-pressure FT-IR reaction cell for ultra-dry in situ and operando operation is reported. The reaction cell itself as well as the sample holder is fully made of quartz glass, with no hot metal or ceramic parts in the vicinity of the high-temperature zone. Special emphasis was put on chemically absolute water-free and inert experimental conditions, which includes reaction cell and gas-feeding lines. Operation and spectroscopy up to 1273 K is possible, as well as pressures up to ambient conditions. The reaction cell exhibits a very easy and variable construction and can be adjusted to any available FT-IR spectrometer. Its particular strength lies in its possibility to access and study samples under very demanding experimental conditions. This includes studies at very high temperatures, e.g., for solid-oxide fuel cell research or studies where the water content of the reaction mixtures must be exactly adjusted. The latter includes all adsorption studies on oxide surfaces, where the hydroxylation degree is of paramount importance. The capability of the reaction cell will be demonstrated for two selected examples where information and in due course a correlation to other methods can only be achieved using the presented setup.

Evaluation of <em>HER2em> Gene Amplification in Breast Cancer Using Nuclei Microarray <em>in em>S>itu em>Hybridization

Directory of Open Access Journals (Sweden)

Xuefeng Zhang

2012-05-01

Full Text Available Fluorescence<em> em>>in situ em>hybridization (FISH assay is considered the “gold standard” in evaluating <em>HER2/neu (HER2em> gene status. However, FISH detection is costly and time consuming. Thus, we established nuclei microarray with extracted intact nuclei from paraffin embedded breast cancer tissues for FISH detection. The nuclei microarray FISH (NMFISH technology serves as a useful platform for analyzing <em>HER2em> gene/chromosome 17 centromere ratio. We examined <em>HER2em> gene status in 152 cases of invasive ductal carcinomas of the breast that were resected surgically with FISH and NMFISH. <em>HER2em> gene amplification status was classified according to the guidelines of the American Society of Clinical Oncology and College of American Pathologists (ASCO/CAP. Comparison of the cut-off values for <em>HER2em>/chromosome 17 centromere copy number ratio obtained by NMFISH and FISH showed that there was almost perfect agreement between the two methods (κ coefficient 0.920. The results of the two methods were almost consistent for the evaluation of <em>HER2em> gene counts. The present study proved that NMFISH is comparable with FISH for evaluating <em>HER2em> gene status. The use of nuclei microarray technology is highly efficient, time and reagent conserving and inexpensive.

Neonatal Phosphate Nutrition Alters <em>in em>Vivo> and <em>in em>Vitro> Satellite Cell Activity in Pigs