Sample records for transfer theory analysis

  1. Oxygen atom transfer reactions from Mimoun complexes to sulfides and sulfoxides. A bonding evolution theory analysis. (United States)

    González-Navarrete, Patricio; Sensato, Fabricio R; Andrés, Juan; Longo, Elson


    In this research, a comprehensive theoretical investigation has been conducted on oxygen atom transfer (OAT) reactions from Mimoun complexes to sulfides and sulfoxides. The joint use of the electron localization function (ELF) and Thom's catastrophe theory (CT) provides a powerful tool to analyze the evolution of chemical events along a reaction pathway. The progress of the reaction has been monitored by structural stability domains from ELF topology while the changes between them are controlled by turning points derived from CT which reveal that the reaction mechanism can be separated in several steps: first, a rupture of the peroxo O1-O2 bond, then a rearrangement of lone pairs of the sulfur atom occurs and subsequently the formation of S-O1 bond. The OAT process involving the oxidation of sulfides and sulfoxides is found to be an asynchronous process where O1-O2 bond breaking and S-O1 bond formation processes do not occur simultaneously. Nucleophilic/electrophilic characters of both dimethyl sulfide and dimethyl sulfoxide, respectively, are sufficiently described by our results, which hold the key to unprecedented insight into the mapping of electrons that compose the bonds while the bonds change.

  2. Game Analysis on Rural Land Transfer from the Perspective of Stakeholder Theory

    Directory of Open Access Journals (Sweden)

    Gen Zhang


    Full Text Available The key—to maintaining social stability in rural areas, promoting rural economic development and building a new socialist countryside—is handling correctly the issues of rural land transfer and ironing out the conflicts resulting from the benefits imbalance. In this paper, rural land transfer is categorized into two types: land transfer caused by the collective behavior and land transfer caused by the individual behavior. In the process of land transfer caused by the collective behavior, the conflicts root in the convergence of interest among various rural social strata; while in the process of land transfer caused by the individual behavior, the game between interests and human relationship, reflects the dilemma between rationality and sensibility, which villagers are confronted with.

  3. Full correction of scattering effects by using the radiative transfer theory for improved quantitative analysis of absorbing species in suspensions. (United States)

    Steponavičius, Raimundas; Thennadil, Suresh N


    Sample-to-sample photon path length variations that arise due to multiple scattering can be removed by decoupling absorption and scattering effects by using the radiative transfer theory, with a suitable set of measurements. For samples where particles both scatter and absorb light, the extracted bulk absorption spectrum is not completely free from nonlinear particle effects, since it is related to the absorption cross-section of particles that changes nonlinearly with particle size and shape. For the quantitative analysis of absorbing-only (i.e., nonscattering) species present in a matrix that contains a particulate species that absorbs and scatters light, a method to eliminate particle effects completely is proposed here, which utilizes the particle size information contained in the bulk scattering coefficient extracted by using the Mie theory to carry out an additional correction step to remove particle effects from bulk absorption spectra. This should result in spectra that are equivalent to spectra collected with only the liquid species in the mixture. Such an approach has the potential to significantly reduce the number of calibration samples as well as improve calibration performance. The proposed method was tested with both simulated and experimental data from a four-component model system.

  4. 3rd International Conference on Numerical Analysis and Optimization : Theory, Methods, Applications and Technology Transfer

    CERN Document Server

    Grandinetti, Lucio; Purnama, Anton


    Presenting the latest findings in the field of numerical analysis and optimization, this volume balances pure research with practical applications of the subject. Accompanied by detailed tables, figures, and examinations of useful software tools, this volume will equip the reader to perform detailed and layered analysis of complex datasets. Many real-world complex problems can be formulated as optimization tasks. Such problems can be characterized as large scale, unconstrained, constrained, non-convex, non-differentiable, and discontinuous, and therefore require adequate computational methods, algorithms, and software tools. These same tools are often employed by researchers working in current IT hot topics such as big data, optimization and other complex numerical algorithms on the cloud, devising special techniques for supercomputing systems. The list of topics covered include, but are not limited to: numerical analysis, numerical optimization, numerical linear algebra, numerical differential equations, opt...

  5. Theory of Periodic Conjugate Heat Transfer

    CERN Document Server

    Zudin, Yuri B


    This book presents the theory of periodic conjugate heat transfer in a detailed way. The effects of thermophysical properties and geometry of a solid body on the commonly used and experimentally determined heat transfer coefficient are analytically presented from a general point of view. The main objective of the book is a simplified description of the interaction between a solid body and a fluid as a boundary value problem of the heat conduction equation for the solid body. At the body surface, the true heat transfer coefficient is composed of two parts: the true mean value resulting from the solution of the steady state heat transfer problem and a periodically variable part, the periodic time and length to describe the oscillatory hydrodynamic effects. The second edition is extended by (i) the analysis of stability boundaries in helium flow at supercritical conditions in a heated channel with respect to the interaction between a solid body and a fluid; (ii) a periodic model and a method of heat transfer sim...

  6. Theory of coherent resonance energy transfer

    International Nuclear Information System (INIS)

    Jang, Seogjoo; Cheng, Y.-C.; Reichman, David R.; Eaves, Joel D.


    A theory of coherent resonance energy transfer is developed combining the polaron transformation and a time-local quantum master equation formulation, which is valid for arbitrary spectral densities including common modes. The theory contains inhomogeneous terms accounting for nonequilibrium initial preparation effects and elucidates how quantum coherence and nonequilibrium effects manifest themselves in the coherent energy transfer dynamics beyond the weak resonance coupling limit of the Foerster and Dexter (FD) theory. Numerical tests show that quantum coherence can cause significant changes in steady state donor/acceptor populations from those predicted by the FD theory and illustrate delicate cooperation of nonequilibrium and quantum coherence effects on the transient population dynamics.

  7. Theory of electron transfer and ionization

    International Nuclear Information System (INIS)

    Becker, R.L.


    The main effort reported is directed toward charge transfer and ionization in high energy atomic collisions. The research may be divided into classical trajectory calculations, quantum - mechanical collision theory, and phenomenological treatments of quantal interference effects in heavy ion collisions

  8. Predicting High or Low Transfer Efficiency of Photovoltaic Systems Using a Novel Hybrid Methodology Combining Rough Set Theory, Data Envelopment Analysis and Genetic Programming

    Directory of Open Access Journals (Sweden)

    Lee-Ing Tong


    Full Text Available Solar energy has become an important energy source in recent years as it generates less pollution than other energies. A photovoltaic (PV system, which typically has many components, converts solar energy into electrical energy. With the development of advanced engineering technologies, the transfer efficiency of a PV system has been increased from low to high. The combination of components in a PV system influences its transfer efficiency. Therefore, when predicting the transfer efficiency of a PV system, one must consider the relationship among system components. This work accurately predicts whether transfer efficiency of a PV system is high or low using a novel hybrid model that combines rough set theory (RST, data envelopment analysis (DEA, and genetic programming (GP. Finally, real data-set are utilized to demonstrate the accuracy of the proposed method.

  9. Transfer across Second Language Acquisition Theories (United States)

    Daftarifard, Parisa; Shirkhani, Servat


    Transfer has been discussed from different points of view since the advent of Contrastive Analysis Hypothesis [13], [8]. Mishina-Mori [19] has defied transfer as merging grammatical properties from one language to another. The effect of transfer from a first language (L1) to a second language (L2) or a third language (L3) has been viewed…

  10. Theory of periodic conjugate heat transfer

    CERN Document Server

    Zudin, Yuri B


    This book presents the theory of periodic conjugate heat transfer in detail. It offers a simplified description of the interaction between a solid body and a fluid as a boundary value problem of the heat conduction equation for the solid body.

  11. Neutron signal transfer analysis

    CERN Document Server

    Pleinert, H; Lehmann, E


    A new method called neutron signal transfer analysis has been developed for quantitative determination of hydrogenous distributions from neutron radiographic measurements. The technique is based on a model which describes the detector signal obtained in the measurement as a result of the action of three different mechanisms expressed by signal transfer functions. The explicit forms of the signal transfer functions are determined by Monte Carlo computer simulations and contain only the distribution as a variable. Therefore an unknown distribution can be determined from the detector signal by recursive iteration. This technique provides a simple and efficient tool for analysis of this type while also taking into account complex effects due to the energy dependency of neutron interaction and single and multiple scattering. Therefore this method provides an efficient tool for precise quantitative analysis using neutron radiography, as for example quantitative determination of moisture distributions in porous buil...

  12. Analysis of Heat Transfer Phenomenon in Magnetohydrodynamic Casson Fluid Flow Through Cattaneo–Christov Heat Diffusion Theory (United States)

    Ramesh, G. K.; Gireesha, B. J.; Shehzad, S. A.; Abbasi, F. M.


    Heat transport phenomenon of two-dimensional magnetohydrodynamic Casson fluid flow by employing Cattaneo–Christov heat diffusion theory is described in this work. The term of heat absorption/generation is incorporated in the mathematical modeling of present flow problem. The governing mathematical expressions are solved for velocity and temperature profiles using RKF 45 method along with shooting technique. The importance of arising nonlinear quantities namely velocity, temperature, skin-friction and temperature gradient are elaborated via plots. It is explored that the Casson parameter retarded the liquid velocity while it enhances the fluid temperature. Further, we noted that temperature and thickness of temperature boundary layer are weaker in case of Cattaneo–Christov heat diffusion model when matched with the profiles obtained for Fourier’s theory of heat flux.

  13. Theory of interrelated electron and proton transfer processes

    DEFF Research Database (Denmark)

    Kuznetsov, A.M.; Ulstrup, Jens


    A simple theory of elementary act of interrelated reactions of electron and proton transfer is developed. Mechanisms of synchronous and multistage transfer and coherent transitions via a dynamically populated intermediate state are discussed. Formulas for rate constants of adiabatic and nonadiaba......A simple theory of elementary act of interrelated reactions of electron and proton transfer is developed. Mechanisms of synchronous and multistage transfer and coherent transitions via a dynamically populated intermediate state are discussed. Formulas for rate constants of adiabatic...

  14. Thermal Stress Analysis of a Continuous and Pulsed End-Pumped Nd:YAG Rod Crystal Using Non-Classic Conduction Heat Transfer Theory (United States)

    Mojahedi, Mahdi; Shekoohinejad, Hamidreza


    In this paper, temperature distribution in the continuous and pulsed end-pumped Nd:YAG rod crystal is determined using nonclassical and classical heat conduction theories. In order to find the temperature distribution in crystal, heat transfer differential equations of crystal with consideration of boundary conditions are derived based on non-Fourier's model and temperature distribution of the crystal is achieved by an analytical method. Then, by transferring non-Fourier differential equations to matrix equations, using finite element method, temperature and stress of every point of crystal are calculated in the time domain. According to the results, a comparison between classical and nonclassical theories is represented to investigate rupture power values. In continuous end pumping with equal input powers, non-Fourier theory predicts greater temperature and stress compared to Fourier theory. It also shows that with an increase in relaxation time, crystal rupture power decreases. Despite of these results, in single rectangular pulsed end-pumping condition, with an equal input power, Fourier theory indicates higher temperature and stress rather than non-Fourier theory. It is also observed that, when the relaxation time increases, maximum amounts of temperature and stress decrease.

  15. Theory of light transfer in food and biological materials (United States)

    In this chapter, we first define the basic radiometric quantities that are needed for describing light propagation in food and biological materials. Radiative transfer theory is then derived, according to the principle of the conservation of energy. Because the radiative transfer theory equation is ...

  16. Light scattering by multiple spheres: comparison between Maxwell theory and radiative-transfer-theory calculations. (United States)

    Voit, Florian; Schäfer, Jan; Kienle, Alwin


    We present a methodology to compare results of classical radiative transfer theory against exact solutions of Maxwell theory for a high number of spheres. We calculated light propagation in a cubic scattering region (20 x 20 x 20 microm(3)) consisting of different concentrations of polystyrene spheres in water (diameter 2 microm) by an analytical solution of Maxwell theory and by a numerical solution of radiative transfer theory. The relative deviation of differential as well as total scattering cross sections obtained by both approaches was evaluated for each sphere concentration. For the considered case, we found that deviations due to radiative transfer theory remain small, even for concentrations up to ca. 20 vol. %.

  17. Year 7 Students, Information Literacy, and Transfer: A Grounded Theory (United States)

    Herring, James E.


    This study examined the views of year 7 students, teacher librarians, and teachers in three state secondary schools in rural New South Wales, Australia, on information literacy and transfer. The aims of the study included the development of a grounded theory in relation to information literacy and transfer in these schools. The study's perspective…

  18. Paths to Förster's resonance energy transfer (FRET) theory (United States)

    Masters, B. R.


    Theodor Förster (1910-1974) developed a phenomenological theory of nonradiative resonance energy transfer which proved to be transformative in the fields of chemistry, biochemistry, and biology. This paper explores the experimental and the theoretical antecedents of Förster's theory of resonance energy transfer (FRET). Early studies of sensitized fluorescence, fluorescence depolarization, and photosynthesis demonstrated the phenomena of long-range energy transfer. At the same time physicists developed theoretical models which contained common physical mechanisms and parameters: oscillating dipoles as models for the atoms or molecules, dipole-dipole coupling for the interaction, and a distance R0 that is optimal for resonance energy transfer. Early theories predicted R0 that was too large as compared to experiments. Finally, in 1946 Förster developed a classical theory and in 1948 he developed a quantum mechanical theory; both theories predicted an inverse sixth power dependence of the rate of energy transfer and a R0 that agreed with experiments. This paper attempts to determine why Förster succeeded when the other theoreticians failed to develop the correct theory. The putative roles of interdisciplinary education and collaborative research are discussed. Furthermore, I explore the role of science journals and their specific audiences in the popularization of FRET to a broad interdisciplinary community.

  19. Radiative Transfer Reconsidered as a Quantum Kinetic Theory ...

    Indian Academy of Sciences (India)

    Abstract. We revisit the radiative transfer theory from first principles approach, inspired from quantum kinetic theory. The radiation field is described within the second quantization formalism. A master equation for the radiation density operator is derived and transformed into a bal- ance relation in the phase space, which ...

  20. Radiative Transfer Reconsidered as a Quantum Kinetic Theory ...

    Indian Academy of Sciences (India)


    Jan 27, 2016 ... We revisit the radiative transfer theory from first principles approach, inspired from quantum kinetic theory. The radiation field is described within the second quantization formalism. A master equation for the radiation density operator is derived and transformed into a balance relation in the phase space, ...

  1. Radiative Transfer Reconsidered as a Quantum Kinetic Theory

    Indian Academy of Sciences (India)

    Abstract. We revisit the radiative transfer theory from first principles approach, inspired from quantum kinetic theory. The radiation field is described within the second quantization formalism. A master equation for the radiation density operator is derived and transformed into a bal- ance relation in the phase space, which ...

  2. Theory of nuclear heavy-ion direct transfer reactions

    International Nuclear Information System (INIS)

    Crowley, B.J.B.


    We review the distorted-wave approach to direct transfer reactions and draw attention to some of the shortcomings of current theories. We show that a reformulated form of the distorted-wave Born approximation (DWBA) for transfer can lead to important simplifications of the theory, which are valid for nuclear heavy-ion induced reactions at energies > or approx. =MeV/nucleon. In particular, in the semiclassical limit, it leads to a new and simple formula for the transfer t-matrix which includes all the essential physics while offering several important advantages over standard ''full-recoil finite-range'' DWBA. One such advantage is that the new formula is more transparent in that it is amendable to interpretation and analytical manipulation. At high-energy it is shown to reduce to one earlier deduced using eikonal-DWBA. The conditions for the validity of the new theory are discussed in detail. They are shown to be generally well satisfied for small-mass transfer between heavy-ions at energies at or above those particularly favour transfer (> or approx. =10 MeV/nucleon for transfer of valence nucleons). The restriction to small mass is not due to any recoil approximation; in fact, it is only a necessary restriction at certain energies. The theory treats recoil exactly. Consideration of the optimum dynamical conditions for transfer leads to a set of matching conditions. The presence of hitherto neglected absorption, arising from dynamical effects of poor matching, it suggested and qualitatively discussed. Condition under which such absorption may be neglected are derived. Results of numerical calculations are presented showing that the theory is capable of good agreement with standard full-recoil finite-range DWBA, and that it is capable of giving at least as good an account of experimental data for nucleon-transfer between heavy-ions at energies approx.10 MeV/nucleon

  3. Testing Theories of Transfer Using Error Rate Learning Curves. (United States)

    Koedinger, Kenneth R; Yudelson, Michael V; Pavlik, Philip I


    We analyze naturally occurring datasets from student use of educational technologies to explore a long-standing question of the scope of transfer of learning. We contrast a faculty theory of broad transfer with a component theory of more constrained transfer. To test these theories, we develop statistical models of them. These models use latent variables to represent mental functions that are changed while learning to cause a reduction in error rates for new tasks. Strong versions of these models provide a common explanation for the variance in task difficulty and transfer. Weak versions decouple difficulty and transfer explanations by describing task difficulty with parameters for each unique task. We evaluate these models in terms of both their prediction accuracy on held-out data and their power in explaining task difficulty and learning transfer. In comparisons across eight datasets, we find that the component models provide both better predictions and better explanations than the faculty models. Weak model variations tend to improve generalization across students, but hurt generalization across items and make a sacrifice to explanatory power. More generally, the approach could be used to identify malleable components of cognitive functions, such as spatial reasoning or executive functions. Copyright © 2016 Cognitive Science Society, Inc.

  4. Discourse theory and analysis

    NARCIS (Netherlands)

    Molder, te H.F.M.


    Available in both print and electronic formats, the Encyclopedia of Communication Theory provides students and researchers with a comprehensive two-volume overview of contemporary communication theory. Reference librarians report that students frequently approach them seeking a source that will

  5. A conceptual analysis of transfer of learning in Health Sciences ...

    African Journals Online (AJOL)

    All educators in vocational training aim to promote transfer of learning in their students. However, studies on transfer of learning or theory-practice gap in the health professions are criticized for being anecdotal and not viewed as a systemic process. The analysis was done according to Walker and Avant's (2005) eight steps.

  6. Program Theory Evaluation: Logic Analysis (United States)

    Brousselle, Astrid; Champagne, Francois


    Program theory evaluation, which has grown in use over the past 10 years, assesses whether a program is designed in such a way that it can achieve its intended outcomes. This article describes a particular type of program theory evaluation--logic analysis--that allows us to test the plausibility of a program's theory using scientific knowledge.…

  7. Critical Race Theory and the Transfer Function: Introducing a Transfer Receptive Culture (United States)

    Jain, Dimpal; Herrera, Alfred; Bernal, Santiago; Solorzano, Daniel


    In California, the majority of students of color who enter postsecondary education do so in the community colleges. However large numbers of them leave and do not transfer to four-year institutions; in particular to highly selective pubic four-year colleges and universities. By using the theoretical perspective of critical race theory, transfer…

  8. Multiple scattering theory of radiative transfer in inhomogeneous atmospheres. (United States)

    Kanal, M.


    In this paper we treat the multiple scattering theory of radiative transfer in plane-parallel inhomogeneous atmospheres. The treatment presented here may be adopted to model atmospheres characterized by an optical depth dependent coherent scattering phase function. For the purpose of illustration we consider the semi-infinite medium in which the absorption property of the atmosphere is characterized by an exponential function. The methodology employed here is the extension of the case treated previously by the author for homogeneous atmospheres.

  9. Electron transfer dynamics: Zusman equation versus exact theory

    International Nuclear Information System (INIS)

    Shi Qiang; Chen Liping; Nan Guangjun; Xu Ruixue; Yan Yijing


    The Zusman equation has been widely used to study the effect of solvent dynamics on electron transfer reactions. However, application of this equation is limited by the classical treatment of the nuclear degrees of freedom. In this paper, we revisit the Zusman equation in the framework of the exact hierarchical equations of motion formalism, and show that a high temperature approximation of the hierarchical theory is equivalent to the Zusman equation in describing electron transfer dynamics. Thus the exact hierarchical formalism naturally extends the Zusman equation to include quantum nuclear dynamics at low temperatures. This new finding has also inspired us to rescale the original hierarchical equations and incorporate a filtering algorithm to efficiently propagate the hierarchical equations. Numerical exact results are also presented for the electron transfer reaction dynamics and rate constant calculations.

  10. Quasispecies theory for horizontal gene transfer and recombination (United States)

    Muñoz, Enrique; Park, Jeong-Man; Deem, Michael W.


    We introduce a generalization of the parallel, or Crow-Kimura, and Eigen models of molecular evolution to represent the exchange of genetic information between individuals in a population. We study the effect of different schemes of genetic recombination on the steady-state mean fitness and distribution of individuals in the population, through an analytic field theoretic mapping. We investigate both horizontal gene transfer from a population and recombination between pairs of individuals. Somewhat surprisingly, these nonlinear generalizations of quasispecies theory to modern biology are analytically solvable. For two-parent recombination, we find two selected phases, one of which is spectrally rigid. We present exact analytical formulas for the equilibrium mean fitness of the population, in terms of a maximum principle, which are generally applicable to any permutation invariant replication rate function. For smooth fitness landscapes, we show that when positive epistatic interactions are present, recombination or horizontal gene transfer introduces a mild load against selection. Conversely, if the fitness landscape exhibits negative epistasis, horizontal gene transfer or recombination introduces an advantage by enhancing selection towards the fittest genotypes. These results prove that the mutational deterministic hypothesis holds for quasispecies models. For the discontinuous single sharp peak fitness landscape, we show that horizontal gene transfer has no effect on the fitness, while recombination decreases the fitness, for both the parallel and the Eigen models. We present numerical and analytical results as well as phase diagrams for the different cases.

  11. A Bayesian Theory of Sequential Causal Learning and Abstract Transfer. (United States)

    Lu, Hongjing; Rojas, Randall R; Beckers, Tom; Yuille, Alan L


    Two key research issues in the field of causal learning are how people acquire causal knowledge when observing data that are presented sequentially, and the level of abstraction at which learning takes place. Does sequential causal learning solely involve the acquisition of specific cause-effect links, or do learners also acquire knowledge about abstract causal constraints? Recent empirical studies have revealed that experience with one set of causal cues can dramatically alter subsequent learning and performance with entirely different cues, suggesting that learning involves abstract transfer, and such transfer effects involve sequential presentation of distinct sets of causal cues. It has been demonstrated that pre-training (or even post-training) can modulate classic causal learning phenomena such as forward and backward blocking. To account for these effects, we propose a Bayesian theory of sequential causal learning. The theory assumes that humans are able to consider and use several alternative causal generative models, each instantiating a different causal integration rule. Model selection is used to decide which integration rule to use in a given learning environment in order to infer causal knowledge from sequential data. Detailed computer simulations demonstrate that humans rely on the abstract characteristics of outcome variables (e.g., binary vs. continuous) to select a causal integration rule, which in turn alters causal learning in a variety of blocking and overshadowing paradigms. When the nature of the outcome variable is ambiguous, humans select the model that yields the best fit with the recent environment, and then apply it to subsequent learning tasks. Based on sequential patterns of cue-outcome co-occurrence, the theory can account for a range of phenomena in sequential causal learning, including various blocking effects, primacy effects in some experimental conditions, and apparently abstract transfer of causal knowledge. Copyright © 2015

  12. New theory of radiative energy transfer in free electromagnetic fields

    International Nuclear Information System (INIS)

    Wolf, E.


    A new theory of radiative energy transfer in free, statistically stationary electromagnetic fields is presented. It provides a model for energy transport that is rigorous both within the framework of the stochastic theory of the classical field as well as within the framework of the theory of the quantized field. Unlike the usual phenomenological model of radiative energy transfer that centers around a single scalar quantity (the specific intensity of radiation), our theory brings into evidence the need for characterizing the energy transport by means of two (related) quantities: a scalar and a vector that may be identified, in a well-defined sense, with ''angular components'' of the average electromagnetic energy density and of the average Poynting vector, respectively. Both of them are defined in terms of invariants of certain new electromagnetic correlation tensors. In the special case when the field is statistically homogeneous, our model reduces to the usual one and our angular component of the average electromagnetic energy density, when multiplied by the vacuum speed of light, then acquires all the properties of the specific intensity of radiation. When the field is not statistically homogeneous our model approximates to the usual phenomenological one, provided that the angular correlations between plane wave modes of the field extend over a sufficiently small solid angle of directions about the direction of propagation of each mode. It is tentatively suggested that, when suitably normalized, our angular component of the average electromagnetic energy density may be interpreted as a quasi-probability (general quantum-mechancial phase-space distribution function, such as Wigner's) for the position and the momentum of a photon

  13. Waste Feed Delivery Transfer System Analysis

    International Nuclear Information System (INIS)

    JULYK, L.J.


    This document provides a documented basis for the required design pressure rating and pump pressure capacity of the Hanford Site waste-transfer system in support of the waste feed delivery to the privatization contractor for vitrification. The scope of the analysis includes the 200 East Area double-shell tank waste transfer pipeline system and the associated transfer system pumps for a11 Phase 1B and Phase 2 waste transfers from AN, AP, AW, AY, and A2 Tank Farms

  14. Waste Feed Delivery Transfer System Analysis

    Energy Technology Data Exchange (ETDEWEB)

    JULYK, L.J.


    This document provides a documented basis for the required design pressure rating and pump pressure capacity of the Hanford Site waste-transfer system in support of the waste feed delivery to the privatization contractor for vitrification. The scope of the analysis includes the 200 East Area double-shell tank waste transfer pipeline system and the associated transfer system pumps for a11 Phase 1B and Phase 2 waste transfers from AN, AP, AW, AY, and A2 Tank Farms.

  15. Functional analysis theory and applications

    CERN Document Server

    Edwards, RE


    ""The book contains an enormous amount of information - mathematical, bibliographical and historical - interwoven with some outstanding heuristic discussions."" - Mathematical Reviews.In this massive graduate-level study, Emeritus Professor Edwards (Australian National University, Canberra) presents a balanced account of both the abstract theory and the applications of linear functional analysis. Written for readers with a basic knowledge of set theory, general topology, and vector spaces, the book includes an abundance of carefully chosen illustrative examples and excellent exercises at the

  16. Multiple scattering of polarized light: comparison of Maxwell theory and radiative transfer theory. (United States)

    Voit, Florian; Hohmann, Ansgar; Schäfer, Jan; Kienle, Alwin


    For many research areas in biomedical optics, information about scattering of polarized light in turbid media is of increasing importance. Scattering simulations within this field are mainly performed on the basis of radiative transfer theory. In this study a polarization sensitive Monte Carlo solution of radiative transfer theory is compared to exact Maxwell solutions for all elements of the scattering Müller matrix. Different scatterer volume concentrations are modeled as a multitude of monodisperse nonabsorbing spheres randomly positioned in a cubic simulation volume which is irradiated with monochromatic incident light. For all Müller matrix elements effects due to dependent scattering and multiple scattering are analysed. The results are in overall good agreement between the two methods with deviations related to dependent scattering being prominent for high volume concentrations and high scattering angles.

  17. Dimensional analysis in field theory

    International Nuclear Information System (INIS)

    Stevenson, P.M.


    Dimensional Transmutation (the breakdown of scale invariance in field theories) is reconciled with the commonsense notions of Dimensional Analysis. This makes possible a discussion of the meaning of the Renormalisation Group equations, completely divorced from the technicalities of renormalisation. As illustrations, I describe some very farmiliar QCD results in these terms

  18. Mathematical theory of sedimentation analysis

    CERN Document Server

    Fujita, Hiroshi; Van Rysselberghe, P


    Mathematical Theory of Sedimentation Analysis presents the flow equations for the ultracentrifuge. This book is organized into two parts encompassing six chapters that evaluate the systems of reacting components, the differential equations for the ultracentrifuge, and the case of negligible diffusion. The first chapters consider the Archibald method for molecular weight determination; pressure-dependent sedimentation; expressions for the refractive index and its gradient; relation between refractive index and concentration; and the analysis of Gaussian distribution. Other chapters deal with th

  19. Transfer of Training After an Organizational Intervention in Swedish Sports Clubs: A Self-Determination Theory Perspective. (United States)

    Stenling, Andreas; Tafvelin, Susanne


    Leadership development programs are common in sports, but seldom evaluated; hence, we have limited knowledge about what the participants actually learn and the impact these programs have on sports clubs' daily operations. The purpose of the current study was to integrate a transfer of training model with self-determination theory to understand predictors of learning and training transfer, following a leadership development program among organizational leaders in Swedish sports clubs. Bayesian multilevel path analysis showed that autonomous motivation and an autonomy-supportive implementation of the program positively predicted near transfer (i.e., immediately after the training program) and that perceiving an autonomy-supportive climate in the sports club positively predicted far transfer (i.e., 1 year after the training program). This study extends previous research by integrating a transfer of training model with self-determination theory and identified important motivational factors that predict near and far training transfer.

  20. Dynamic Wireless Power Transfer - Grid Impacts Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Markel, Tony; Meintz, Andrew; Gonder, Jeff


    This presentation discusses the current status of analysis of the electricity grid impacts of a dynamic wireless power transfer system deployed to the Atlanta region on select high traffic roadway segments.

  1. Approximate models for broken clouds in stochastic radiative transfer theory

    International Nuclear Information System (INIS)

    Doicu, Adrian; Efremenko, Dmitry S.; Loyola, Diego; Trautmann, Thomas


    This paper presents approximate models in stochastic radiative transfer theory. The independent column approximation and its modified version with a solar source computed in a full three-dimensional atmosphere are formulated in a stochastic framework and for arbitrary cloud statistics. The nth-order stochastic models describing the independent column approximations are equivalent to the nth-order stochastic models for the original radiance fields in which the gradient vectors are neglected. Fast approximate models are further derived on the basis of zeroth-order stochastic models and the independent column approximation. The so-called “internal mixing” models assume a combination of the optical properties of the cloud and the clear sky, while the “external mixing” models assume a combination of the radiances corresponding to completely overcast and clear skies. A consistent treatment of internal and external mixing models is provided, and a new parameterization of the closure coefficient in the effective thickness approximation is given. An efficient computation of the closure coefficient for internal mixing models, using a previously derived vector stochastic model as a reference, is also presented. Equipped with appropriate look-up tables for the closure coefficient, these models can easily be integrated into operational trace gas retrieval systems that exploit absorption features in the near-IR solar spectrum. - Highlights: • Independent column approximation in a stochastic setting. • Fast internal and external mixing models for total and diffuse radiances. • Efficient optimization of internal mixing models to match reference models


    Directory of Open Access Journals (Sweden)



    Full Text Available This paper analyses potential mechanism of regional knowledge transfer in region with poorly developed innovation infrastructure (the Autonomous Territorial Unit Gagauzia, Republic of Moldova through interactions between regional major players of the Regional Innovation System - the educational and research institutions, small and medium enterprises (SMEs and local authorities. Solution of this problem can be found in modern studies of territories innovation development through the clustering processes. Through the empirical study - innovation potential analysis of local SMEs - we proposed advantage mechanism which focused on the one type of knowledge cluster – Innovation and Educational Cluster. The symbiosis of entrepreneurs, government agencies, educational institutions and business service providers with the regional core - University, allows to increasing exchange flows of innovative knowledge between all members of the cluster and distributing them to the entire region and beyond. The results and proposals of this study formed the basis of the “Program of increasing the innovation potential of Gagauz SMEs”.

  3. Transfer Function and Biosignal Analysis

    Czech Academy of Sciences Publication Activity Database

    Halámek, Josef; Jurák, Pavel; Kára, T.; Souček, M.


    Roč. 1, č. 1 (2001), s. 51-54 ISSN 1335-8871 R&D Projects: GA ČR GA102/00/1262 Institutional research plan: CEZ:AV0Z2065902 Keywords : baroreflex sensitivity * biosingnal analysis Subject RIV: JA - Electronics ; Optoelectronics, Electrical Engineering

  4. Mission analysis for cross-site transfer

    International Nuclear Information System (INIS)

    Riesenweber, S.D.; Fritz, R.L.; Shipley, L.E.


    The Mission Analysis Report describes the requirements and constraints associated with the Transfer Waste Function as necessary to support the Manage Tank Waste, Retrieve Waste, and Process Tank Waste Functions described in WHC-SD-WM-FRD-020, Tank Waste Remediation System (TWRS) Functions and Requirements Document and DOE/RL-92-60, Revision 1, TWRS Functions and Requirements Document, March 1994. It further assesses the ability of the ''initial state'' (or current cross-site transfer system) to meet the requirements and constraints

  5. Mathematical analysis, approximation theory and their applications

    CERN Document Server

    Gupta, Vijay


    Designed for graduate students, researchers, and engineers in mathematics, optimization, and economics, this self-contained volume presents theory, methods, and applications in mathematical analysis and approximation theory. Specific topics include: approximation of functions by linear positive operators with applications to computer aided geometric design, numerical analysis, optimization theory, and solutions of differential equations. Recent and significant developments in approximation theory, special functions and q-calculus along with their applications to mathematics, engineering, and social sciences are discussed and analyzed. Each chapter enriches the understanding of current research problems and theories in pure and applied research.

  6. Analysis of heat and mass transfer

    International Nuclear Information System (INIS)

    Eckert, E.R.G.; Drake, R.M. Jr.


    The contents of this book are: Theory of Heat Conduction and Heat-conduction Equations; Thermal Conductivity; Steady Heat Conduction; Unsteady Heat Conduction; Forced Convection in Laminar Flow; Forced Convection in Turbulent Flow; Dimensional Analysis; Forced Convection in Separated Flow; Natural Convection; Radiation of Strongly Absorbing Media; and Radiation of Weakly Absorbing Media

  7. Nobel Prize 1992: Rudolph A. Marcus: theory of electron transfer reactions in chemical systems

    International Nuclear Information System (INIS)

    Ulate Segura, Diego Guillermo


    A review of the theory developed by Rudolph A. Marcus is presented, who for his rating to the theory of electron transfer in chemical systems was awarded the Nobel Prize in Chemistry in 1992. Marcus theory has constituted not only a good extension of the use of a spectroscopic principle, but also has provided an energy balance and the application of energy conservation for electron transfer reactions. A better understanding of the reaction coordinate is exposed in terms energetic and establishing the principles that govern the transfer of electrons, protons and some labile small molecular groups as studied at present. Also, the postulates and equations described have established predictive models of reaction time, very useful for industrial environments, biological, metabolic, and others that involve redox processes. Marcus theory itself has also constituted a large contribution to the theory of complex transition [es

  8. Transference and countertransference: two concepts specific to psychoanalytic theory and practice. (United States)

    Ladame, F


    The development of the theory of transference and countertransference from Freud to post-Freudian authors is described. It is concluded that the concepts of transference and countertransference are pertinent only within a definite psychoanalytic setting. They cannot be applied in every therapeutic situation.

  9. Domain adaptation via transfer component analysis. (United States)

    Pan, Sinno Jialin; Tsang, Ivor W; Kwok, James T; Yang, Qiang


    Domain adaptation allows knowledge from a source domain to be transferred to a different but related target domain. Intuitively, discovering a good feature representation across domains is crucial. In this paper, we first propose to find such a representation through a new learning method, transfer component analysis (TCA), for domain adaptation. TCA tries to learn some transfer components across domains in a reproducing kernel Hilbert space using maximum mean miscrepancy. In the subspace spanned by these transfer components, data properties are preserved and data distributions in different domains are close to each other. As a result, with the new representations in this subspace, we can apply standard machine learning methods to train classifiers or regression models in the source domain for use in the target domain. Furthermore, in order to uncover the knowledge hidden in the relations between the data labels from the source and target domains, we extend TCA in a semisupervised learning setting, which encodes label information into transfer components learning. We call this extension semisupervised TCA. The main contribution of our work is that we propose a novel dimensionality reduction framework for reducing the distance between domains in a latent space for domain adaptation. We propose both unsupervised and semisupervised feature extraction approaches, which can dramatically reduce the distance between domain distributions by projecting data onto the learned transfer components. Finally, our approach can handle large datasets and naturally lead to out-of-sample generalization. The effectiveness and efficiency of our approach are verified by experiments on five toy datasets and two real-world applications: cross-domain indoor WiFi localization and cross-domain text classification.

  10. Antenna theory analysis and design

    CERN Document Server

    Balanis, Constantine A


    The discipline of antenna theory has experienced vast technological changes. In response, Constantine Balanis has updated his classic text, Antenna Theory, offering the most recent look at all the necessary topics. New material includes smart antennas and fractal antennas, along with the latest applications in wireless communications. Multimedia material on an accompanying CD presents PowerPoint viewgraphs of lecture notes, interactive review questions, Java animations and applets, and MATLAB features. Like the previous editions, Antenna Theory, Third Edition meets the needs of e

  11. Students' Misconceptions about Heat Transfer Mechanisms and Elementary Kinetic Theory (United States)

    Pathare, S. R.; Pradhan, H. C.


    Heat and thermodynamics is a conceptually rich area of undergraduate physics. In the Indian context in particular there has been little work done in this area from the point of view of misconceptions. This prompted us to undertake a study in this area. We present a study of students' misconceptions about heat transfer mechanisms, i.e. conduction,…

  12. Generic mechanism of optimal energy transfer efficiency: a scaling theory of the mean first-passage time in exciton systems. (United States)

    Wu, Jianlan; Silbey, Robert J; Cao, Jianshu


    An asymptotic scaling theory is presented using the conceptual basis of trapping-free subspace (i.e., orthogonal subspace) to establish the generic mechanism of optimal efficiency of excitation energy transfer in light-harvesting systems. A quantum state orthogonal to the trap will exhibit noise-assisted transfer, clarifying the significance of initial preparation. For such an initial state, the efficiency is enhanced in the weak damping limit (⟨t⟩ ∼ 1/Γ), and suppressed in the strong damping limit (⟨t⟩ ∼ Γ), analogous to Kramers turnover in classical rate theory. An interpolating expression ⟨t⟩ = A/Γ + B + CΓ quantitatively describes the trapping time over the entire range of the dissipation strength, and predicts the optimal efficiency at Γ(opt) ∼ J for homogenous systems. In the presence of static disorder, the scaling law of transfer time with respect to dephasing rate changes from linear to square root, suggesting a weaker dependence on the environment. The prediction of the scaling theory is verified in a symmetric dendrimer system by numerically exact quantum calculations. Though formulated in the context of excitation energy transfer, the analysis and conclusions apply in general to open quantum processes, including electron transfer, fluorescence emission, and heat conduction.

  13. Theory of thermal stresses

    CERN Document Server

    Boley, Bruno A


    Highly regarded text presents detailed discussion of fundamental aspects of theory, background, problems with detailed solutions. Basics of thermoelasticity, heat transfer theory, thermal stress analysis, more. 1985 edition.

  14. Morphing continuum analysis of energy transfer in compressible turbulence (United States)

    Cheikh, Mohamad Ibrahim; Wonnell, Louis B.; Chen, James


    A shock-preserving finite volume solver with the generalized Lax-Friedrichs splitting flux for morphing continuum theory (MCT) is presented and verified. The numerical MCT solver is showcased in a supersonic turbulent flow with Mach 2.93 over an 8∘ compression ramp. The simulation results validated MCT with experiments as an alternative for modeling compressible turbulence. The required size of the smallest mesh cell for the MCT simulation is shown to be almost an order larger than that in a similar direct numerical simulation study. The comparison shows MCT is a much more computationally friendly theory than the classical Navier-Stokes equations. The dynamics of energy cascade at the length scale of individual eddies is illuminated through the subscale rotation introduced by MCT. In this regard, MCT provides a statistical averaging procedure for capturing energy transfer in compressible turbulence, not found in classical fluid theories. Analysis of the MCT results show the existence of a statistical coupling of the internal and translational kinetic energy fluctuations with the corresponding eddy rotational energy fluctuations, indicating a multiscale transfer of energy. In conclusion, MCT gives a new characterization of the energy cascade within compressible turbulence without the use of excessive computational resources.

  15. Similarity Theory and Dimensionless Numbers in Heat Transfer (United States)

    Marin, E.; Calderon, A.; Delgado-Vasallo, O.


    We present basic concepts underlying the so-called similarity theory that in our opinion should be explained in basic undergraduate general physics courses when dealing with heat transport problems, in particular with those involving natural or free convection. A simple example is described that can be useful in showing a criterion for neglecting…

  16. Experimental tests of FTE theories. [Flux Transfer Event (United States)

    Sonnerup, B. U. O.


    A brief overview is presented of a number of qualitative geometrical models as well as simulation models of flux transfer events (FTEs) and an attempt is made to identify critical observational tests that would help discriminate between these models. These tests are concerned with flux tube orientation, speed and structure. Available single and multiple spacecraft observations are discussed in the context of these tests. Particular attention is given to the problem of determining flux-tube orientation and speed from a single spacecraft.

  17. Number Theory, Analysis and Geometry

    CERN Document Server

    Goldfeld, Dorian; Jones, Peter


    Serge Lang was an iconic figure in mathematics, both for his own important work and for the indelible impact he left on the field of mathematics, on his students, and on his colleagues. Over the course of his career, Lang traversed a tremendous amount of mathematical ground. As he moved from subject to subject, he found analogies that led to important questions in such areas as number theory, arithmetic geometry, and the theory of negatively curved spaces. Lang's conjectures will keep many mathematicians occupied far into the future. In the spirit of Lang's vast contribution to mathematics, th

  18. Multiconfiguration Pair-Density Functional Theory Outperforms Kohn-Sham Density Functional Theory and Multireference Perturbation Theory for Ground-State and Excited-State Charge Transfer. (United States)

    Ghosh, Soumen; Sonnenberger, Andrew L; Hoyer, Chad E; Truhlar, Donald G; Gagliardi, Laura


    The correct description of charge transfer in ground and excited states is very important for molecular interactions, photochemistry, electrochemistry, and charge transport, but it is very challenging for Kohn-Sham (KS) density functional theory (DFT). KS-DFT exchange-correlation functionals without nonlocal exchange fail to describe both ground- and excited-state charge transfer properly. We have recently proposed a theory called multiconfiguration pair-density functional theory (MC-PDFT), which is based on a combination of multiconfiguration wave function theory with a new type of density functional called an on-top density functional. Here we have used MC-PDFT to study challenging ground- and excited-state charge-transfer processes by using on-top density functionals obtained by translating KS exchange-correlation functionals. For ground-state charge transfer, MC-PDFT performs better than either the PBE exchange-correlation functional or CASPT2 wave function theory. For excited-state charge transfer, MC-PDFT (unlike KS-DFT) shows qualitatively correct behavior at long-range with great improvement in predicted excitation energies.

  19. Functional analysis, spectral theory, and applications

    CERN Document Server

    Einsiedler, Manfred


    This textbook provides a careful treatment of functional analysis and some of its applications in analysis, number theory, and ergodic theory. In addition to discussing core material in functional analysis, the authors cover more recent and advanced topics, including Weyl’s law for eigenfunctions of the Laplace operator, amenability and property (T), the measurable functional calculus, spectral theory for unbounded operators, and an account of Tao’s approach to the prime number theorem using Banach algebras. The book further contains numerous examples and exercises, making it suitable for both lecture courses and self-study. Functional Analysis, Spectral Theory, and Applications is aimed at postgraduate and advanced undergraduate students with some background in analysis and algebra, but will also appeal to everyone with an interest in seeing how functional analysis can be applied to other parts of mathematics.

  20. Transfer of Japanese Human Resource Management to US Subsidiaries: Resource Dependence Theory and Institutionalism

    Directory of Open Access Journals (Sweden)

    Hisako Matsuo, Ph.D.


    Full Text Available Japanese corporations are characterized by distinctive management practices which have been nurtured in a culturally homogeneous environment. The transferability of these practices to foreign subsidiaries has been a subject of debate among management scholars. Drawing on resource dependence theory and institutionalism, this study examines the impact of homogeneity in management and parent company control on the degree of presence of Japanese human resource management (HRM in U.S. subsidiaries. The study uses Walton and Lawrence’s classification (reward, selection and promotion, employee influence mechanism, and job design to measure uniquely Japanese HRM and a sample survey of 138 U.S. subsidiaries of Japanese multinational corporations for data collection. A principal component analysis reveals that three dimensions of HRM (reward system, selection and promotion, and job design, rather than four, are salient among these establishments. An OLS regression analysis also reveals that the degree of homogeneity in management and parent company control has impact on the transfer of these dimensions of HRM. Some implications for future study are discussed.

  1. Methods of Fourier analysis and approximation theory

    CERN Document Server

    Tikhonov, Sergey


    Different facets of interplay between harmonic analysis and approximation theory are covered in this volume. The topics included are Fourier analysis, function spaces, optimization theory, partial differential equations, and their links to modern developments in the approximation theory. The articles of this collection were originated from two events. The first event took place during the 9th ISAAC Congress in Krakow, Poland, 5th-9th August 2013, at the section “Approximation Theory and Fourier Analysis”. The second event was the conference on Fourier Analysis and Approximation Theory in the Centre de Recerca Matemàtica (CRM), Barcelona, during 4th-8th November 2013, organized by the editors of this volume. All articles selected to be part of this collection were carefully reviewed.

  2. Information theory-based automatic multimodal transfer function design. (United States)

    Bramon, Roger; Ruiz, Marc; Bardera, Anton; Boada, Imma; Feixas, Miquel; Sbert, Mateu


    In this paper, we present a new framework for multimodal volume visualization that combines several information-theoretic strategies to define both colors and opacities of the multimodal transfer function. To the best of our knowledge, this is the first fully automatic scheme to visualize multimodal data. To define the fused color, we set an information channel between two registered input datasets, and afterward, we compute the informativeness associated with the respective intensity bins. This informativeness is used to weight the color contribution from both initial 1-D transfer functions. To obtain the opacity, we apply an optimization process that minimizes the informational divergence between the visibility distribution captured by a set of viewpoints and a target distribution proposed by the user. This distribution is defined either from the dataset features, from manually set importances, or from both. Other problems related to the multimodal visualization, such as the computation of the fused gradient and the histogram binning, have also been solved using new information-theoretic strategies. The quality and performance of our approach are evaluated on different datasets.

  3. Adversarial Stain Transfer for Histopathology Image Analysis. (United States)

    Bentaieb, Aicha; Hamarneh, Ghassan


    It is generally recognized that color information is central to the automatic and visual analysis of histopathology tissue slides. In practice, pathologists rely on color, which reflects the presence of specific tissue components, to establish a diagnosis. Similarly, automatic histopathology image analysis algorithms rely on color or intensity measures to extract tissue features. With the increasing access to digitized histopathology images, color variation and its implications have become a critical issue. These variations are the result of not only a variety of factors involved in the preparation of tissue slides but also in the digitization process itself. Consequently, different strategies have been proposed to alleviate stain-related tissue inconsistencies in automatic image analysis systems. Such techniques generally rely on collecting color statistics to perform color matching across images. In this work, we propose a different approach for stain normalization that we refer to as stain transfer. We design a discriminative image analysis model equipped with a stain normalization component that transfers stains across datasets. Our model comprises a generative network that learns data set-specific staining properties and image-specific color transformations as well as a task-specific network (e.g., classifier or segmentation network). The model is trained end-to-end using a multi-objective cost function. We evaluate the proposed approach in the context of automatic histopathology image analysis on three data sets and two different analysis tasks: tissue segmentation and classification. The proposed method achieves superior results in terms of accuracy and quality of normalized images compared to various baselines.

  4. Radiative Transfer Theory Verified by Controlled Laboratory Experiments (United States)

    Mishchenko, Michael I.; Goldstein, Dennis H.; Chowdhary, Jacek; Lompado, Arthur


    We report the results of high-accuracy controlled laboratory measurements of the Stokes reflection matrix for suspensions of submicrometer-sized latex particles in water and compare them with the results of a numerically exact computer solution of the vector radiative transfer equation (VRTE). The quantitative performance of the VRTE is monitored by increasing the volume packing density of the latex particles from 2 to 10. Our results indicate that the VRTE can be applied safely to random particulate media with packing densities up to 2. VRTE results for packing densities of the order of 5 should be taken with caution, whereas the polarized bidirectional reflectivity of suspensions with larger packing densities cannot be accurately predicted. We demonstrate that a simple modification of the phase matrix entering the VRTE based on the so-called static structure factor can be a promising remedy that deserves further examination.

  5. Insight into the kinetics and thermodynamics of the hydride transfer reactions between quinones and lumiflavin: a density functional theory study. (United States)

    Reinhardt, Clorice R; Jaglinski, Tanner C; Kastenschmidt, Ashly M; Song, Eun H; Gross, Adam K; Krause, Alyssa J; Gollmar, Jonathan M; Meise, Kristin J; Stenerson, Zachary S; Weibel, Tyler J; Dison, Andrew; Finnegan, Mackenzie R; Griesi, Daniel S; Heltne, Michael D; Hughes, Tom G; Hunt, Connor D; Jansen, Kayla A; Xiong, Adam H; Hati, Sanchita; Bhattacharyya, Sudeep


    The kinetics and equilibrium of the hydride transfer reaction between lumiflavin and a number of substituted quinones was studied using density functional theory. The impact of electron withdrawing/donating substituents on the redox potentials of quinones was studied. In addition, the role of these substituents on the kinetics of the hydride transfer reaction with lumiflavin was investigated in detail under the transition state (TS) theory assumption. The hydride transfer reactions were found to be more favorable for an electron-withdrawing substituent. The activation barrier exhibited a quadratic relationship with the driving force of these reactions as derived under the formalism of modified Marcus theory. The present study found a significant extent of electron delocalization in the TS that is stabilized by enhanced electrostatic, polarization, and exchange interactions. Analysis of geometry, bond-orders, and energetics revealed a predominant parallel (Leffler-Hammond) effect on the TS. Closer scrutiny reveals that electron-withdrawing substituents, although located on the acceptor ring, reduce the N-H bond order of the donor fragment in the precursor complex. Carried out in the gas-phase, this is the first ever report of a theoretical study of flavin's hydride transfer reactions with quinones, providing an unfiltered view of the electronic effect on the nuclear reorganization of donor-acceptor complexes.

  6. Fixed point theory, variational analysis, and optimization

    CERN Document Server

    Al-Mezel, Saleh Abdullah R; Ansari, Qamrul Hasan


    ""There is a real need for this book. It is useful for people who work in areas of nonlinear analysis, optimization theory, variational inequalities, and mathematical economics.""-Nan-Jing Huang, Sichuan University, Chengdu, People's Republic of China

  7. Glimpses of Learning Theory in Transactional Analysis. (United States)

    Thompson, Henry O.


    Concepts drawn from Transactional Analysis concerning memory, association, and related components of learning theory are discussed. Ego States (Child, Parent, Adult) are described, along with the patterns and responses characteristic of each state. (PP)


    International Nuclear Information System (INIS)

    Tamburello, D.; Dimenna, Richard; Lee, Si


    The transfer of liquid salt solution from Tank 32 to an evaporator is to be accomplished by activating the evaporator feed pump, with the supernate surface at a minimum height of approximately 74.4 inches above the sludge layer, while simultaneously turning on the downcomer with a flow rate of 110 gpm. Previously, activation of the evaporator feed pump was an isolated event without any other components running at the same time. An analysis of the dissolved solution transfer has been performed using computational fluid dynamics (CFD) methods to determine the amount of entrained sludge solids pumped out of the tank toward the evaporator with the downcomer turned on. The analysis results shows that, for the minimum tank liquid level of 105 inches above the tank bottom (which corresponds to a liquid depth of 74.4 inches above the sludge layer), the evaporator feed pump will contain less than 0.1 wt% sludge solids in the discharge stream, which is an order of magnitude less than the 1.0 wt% undissolved solids (UDS) loading criteria to feed the evaporator. Lower liquid levels with respect to the sludge layer will result in higher amounts of sludge entrainment due to the increased plunging jet velocity from the downcomer disturbing the sludge layer


    International Nuclear Information System (INIS)

    Tamburello, D; Si Lee, S; Richard Dimenna, R


    The transfer of liquid salt solution from Tank 26 to an evaporator is to be accomplished by activating the evaporator feed pump, located approximately 72 inches above the sludge layer, while simultaneously turning on the downcomer. Previously, activation of the evaporator feed pump was an isolated event without any other components running at the same time. An analysis of the dissolved solution transfer has been performed using computational fluid dynamics methods to determine the amount of entrained sludge solids pumped out of the tank to the evaporator with the downcomer turned on. The analysis results showed that, for the maximum and minimum supernate levels in Tank 26 (252.5 and 72 inches above the sludge layer, respectively), the evaporator feed pump will entrain between 0.05 and 0.1 wt% sludge solids weight fraction into the eductor, respectively. Lower tank liquid levels, with respect to the sludge layer, result in higher amounts of sludge entrainment due to the increased velocity of the plunging jets from the downcomer and evaporator feed pump bypass as well as decreased dissipation depth

  10. A formal derivation of the local energy transfer (LET) theory of homogeneous turbulence (United States)

    McComb, W. D.; Yoffe, S. R.


    A statistical closure of the Navier-Stokes hierarchy which leads to equations for the two-point, two-time covariance of the velocity field for stationary, homogeneous isotropic turbulence is presented. It is a generalisation of the self-consistent field method due to Edwards (1964) for the stationary, single-time velocity covariance. The probability distribution functional P≤ft[\\mathbf{u},t\\right] is obtained, in the form of a series, from the Liouville equation by means of a perturbation expansion about a Gaussian distribution, which is chosen to give the exact two-point, two-time covariance. The triple moment is calculated in terms of an ensemble-averaged infinitesimal velocity-field propagator, and shown to yield the Edwards result as a special case. The use of a Gaussian zero-order distribution has been found to justify the introduction of a fluctuation-response relation, which is in accord with modern dynamical theories. In a sense this work completes the analogy drawn by Edwards between turbulence and Brownian motion. Originally Edwards had shown that the noise input was determined by the correlation of the velocity field with the externally applied stirring forces but was unable to determine the system response. Now we find that the system response is determined by the correlation of the velocity field with internal quasi-entropic forces. This analysis is valid to all orders of perturbation theory, and allows the recovery of the local energy transfer (LET) theory, which had previously been derived by more heuristical methods. The LET theory is known to be in good agreement with experimental results. It is also unique among two-point statistical closures in displaying an acceptable (i.e. non-Markovian) relationship between the transfer spectrum and the system response, in accordance with experimental results. As a result of the latter property, it is compatible with the Kolmogorov (K41) spectral phenomenology. In memory of Professor Sir Sam Edwards F

  11. Examining depletion theories under conditions of within-task transfer. (United States)

    Brewer, Gene A; Lau, Kevin K H; Wingert, Kimberly M; Ball, B Hunter; Blais, Chris


    In everyday life, mental fatigue can be detrimental across many domains including driving, learning, and working. Given the importance of understanding and accounting for the deleterious effects of mental fatigue on behavior, a growing body of literature has studied the role of motivational and executive control processes in mental fatigue. In typical laboratory paradigms, participants complete a task that places demand on these self-control processes and are later given a subsequent task. Generally speaking, decrements to subsequent task performance are taken as evidence that the initial task created mental fatigue through the continued engagement of motivational and executive functions. Several models have been developed to account for negative transfer resulting from this "ego depletion." In the current study, we provide a brief literature review, specify current theoretical approaches to ego-depletion, and report an empirical test of current models of depletion. Across 4 experiments we found minimal evidence for executive control depletion along with strong evidence for motivation mediated ego depletion. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

  12. Heat Transfer Analysis of Fin Tube

    International Nuclear Information System (INIS)

    Jeon, Woo-Jin; Choi, Cheng-Ryul


    This paper describes a preliminary numerical analysis of fin tube used for a heat exchanger of the air-water cooling system. The internal flow in a fin tube is steam and the external of the fin is cooled by air. Cooling system in a nuclear power plant can be divided into two categories; 1) active pump driven system powered by alternating current and 2) passive cooling system drived by natural circulation phenomena. After the accident in Hukushima Nuclear Power Plants, the importance of the passive cooling system that can provide a long-term cooling of reactor decay heat during station blackout condition is emphasized. However, the effectiveness of passive cooling system based on cooling water is limited by the capacity of water storage tank. To overcome the limit due to the exhaustion of the cooling water, an natural convection air cooling system is proposed. As the air operated cooling system utilizes natural circulation phenomena of air, it does not require cooling water. However, the heat transfer area of the air operated cooling system should be increased much as the heat removal capacity per unit area is much lower than that of water cooling system. The air-water combined cooling system can resolve this excess increase of the heat transfer area in the air operated cooling system. This air-water cooling system can be also used in the passive containment cooling system. The effect of design parameters such as fin tube arrangement, the fin height, and pitch has been analyzed and the chimney effect on the simulation of heat transfer in a heat exchanger is evaluated. The internal flows in a fin tube heat exchanger for natural circulation flow condition and forced convection (suction) condition were investigated

  13. Application of the theory of local potential to some hydrodynamics and heat transfer problems

    International Nuclear Information System (INIS)

    Delhaye, Jean-Marc


    This short research thesis addresses the field of thermodynamics of irreversible phenomena. The author first recalls the fundamentals of conservation laws, as well as initial postulates of thermodynamics of irreversible phenomena. He reports the study of the conditions of application of the principle of minimum entropy production, and presents the main characteristics of the theory of the local potential. He briefly presents some applications of this theory to hydrodynamics and heat transfer problems in fluid flows [fr

  14. Resonance energy transfer and interface forces: quantum electrodynamical analysis (United States)

    Bradshaw, David S.; Leeder, Jamie M.; Rodríguez, Justo; Andrews, David L.


    On the propagation of radiation with a suitably resonant optical frequency through a dense chromophoric system - a doped solid for example - photon capture is commonly followed by one or more near-field transfers of the resulting optical excitation, usually to closely neighboring chromophores. Since the process results in a change to the local electronic environment, it can be expected to also shift the electromagnetic interactions between the participant optical units, producing modified inter-particle forces. Significantly, it emerges that energy transfer, when it occurs between chromophores or particles with electronically dissimilar properties (such as differing polarizabilities), engenders hitherto unreported changes in the local potential energy landscape. This paper reports the results of quantum electrodynamical calculations which cast a new light on the physical link between these features. The theory also elucidates a significant relationship with Casimir-Polder forces; it transpires that there are clear and fundamental links between dispersion forces and resonance energy transfer. Based on the results, we highlight specific effects that can be anticipated when laser light propagates through an interface between two absorbing media. Both steady-state and pulsed excitation conditions are modeled and the consequences for interface forces are subjected to detailed analysis.

  15. Fringe pattern analysis for optical metrology theory, algorithms, and applications

    CERN Document Server

    Servin, Manuel; Padilla, Moises


    The main objective of this book is to present the basic theoretical principles and practical applications for the classical interferometric techniques and the most advanced methods in the field of modern fringe pattern analysis applied to optical metrology. A major novelty of this work is the presentation of a unified theoretical framework based on the Fourier description of phase shifting interferometry using the Frequency Transfer Function (FTF) along with the theory of Stochastic Process for the straightforward analysis and synthesis of phase shifting algorithms with desired properties such

  16. Spectral theory and nonlinear functional analysis

    CERN Document Server

    Lopez-Gomez, Julian


    This Research Note addresses several pivotal problems in spectral theory and nonlinear functional analysis in connection with the analysis of the structure of the set of zeroes of a general class of nonlinear operators. It features the construction of an optimal algebraic/analytic invariant for calculating the Leray-Schauder degree, new methods for solving nonlinear equations in Banach spaces, and general properties of components of solutions sets presented with minimal use of topological tools. The author also gives several applications of the abstract theory to reaction diffusion equations and systems.The results presented cover a thirty-year period and include recent, unpublished findings of the author and his coworkers. Appealing to a broad audience, Spectral Theory and Nonlinear Functional Analysis contains many important contributions to linear algebra, linear and nonlinear functional analysis, and topology and opens the door for further advances.

  17. Drivers for liquidation and transfer in small firms : Theory of Planned Behavior and firm conditions

    NARCIS (Netherlands)

    H. Leory; Lex van Teeffelen


    Recently Leroy et al. (2008) tested if the Theory of Planned Behavior (TPB) predicts exit behavior of entrepreneurs: liquidation or transfer. He added the purchasers view to the TPB: firm viability and intangible assets. We retested Leroy et al. hypotheses on a more refined dataset of 136 firms in

  18. Local Control Theory in Trajectory Surface Hopping Dynamics Applied to the Excited-State Proton Transfer of 4-Hydroxyacridine. (United States)

    Curchod, Basile F E; Penfold, Thomas J; Rothlisberger, Ursula; Tavernelli, Ivano


    The application of local control theory combined with nonadiabatic ab initio molecular dynamics to study the photoinduced intramolecular proton transfer reaction in 4-hydroxyacridine was investigated. All calculations were performed within the framework of linear-response time-dependent density functional theory. The computed pulses revealed important information about the underlying excited-state nuclear dynamics highlighting the involvement of collective vibrational modes that would normally be neglected in a study performed on model systems constrained to a subset of the full configuration space. This study emphasizes the strengths of local control theory for the design of pulses that can trigger chemical reactions associated with the population of a given molecular excited state. In addition, analysis of the generated pulses can help to shed new light on the photophysics and photochemistry of complex molecular systems. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. The influence of cognitive load on transfer with error prevention training methods: a meta-analysis. (United States)

    Hutchins, Shaun D; Wickens, Christopher D; Carolan, Thomas F; Cumming, John M


    The objective was to conduct research synthesis for the U.S.Army on the effectiveness of two error prevention training strategies (training wheels and scaffolding) on the transfer of training. Motivated as part of an ongoing program of research on training effectiveness, the current work presents some of the program's research into the effects on transfer of error prevention strategies during training from a cognitive load perspective. Based on cognitive load theory, two training strategies were hypothesized to reduce intrinsic load by supporting learners early in acquisition during schema development. A transfer ratio and Hedges' g were used in the two meta-analyses conducted on transfer studies employing the two training strategies. Moderators relevant to cognitive load theory and specific to the implemented strategies were examined.The transfer ratio was the ratio of treatment transfer performance to control transfer. Hedges' g was used in comparing treatment and control group standardized mean differences. Both effect sizes were analyzed with versions of sample weighted fixed effect models. Analysis of the training wheels strategy suggests a transfer benefit. The observed benefit was strongest when the training wheels were a worked example coupled with a principle-based prompt. Analysis of the scaffolding data also suggests a transfer benefit for the strategy. Both training wheels and scaffolding demonstrated positive transfer as training strategies.As error prevention techniques, both support the intrinsic load--reducing implications of cognitive load theory. The findings are applicable to the development of instructional design guidelines in professional skill-based organizations such as the military.

  20. Risk Analysis Methods for Deepwater Port Oil Transfer Systems (United States)


    This report deals with the risk analysis methodology for oil spills from the oil transfer systems in deepwater ports. Failure mode and effect analysis in combination with fault tree analysis are identified as the methods best suited for the assessmen...

  1. Forster Energy Transfer Theory as Reflected in the Structures of Photosynthetic Light-Harvesting Systems

    Energy Technology Data Exchange (ETDEWEB)

    Sener, Melih [Univ. of Illinois, Urbana-Champaign, IL (United States); Strumpfer, Johan [Univ. of Illinois, Urbana-Champaign, IL (United States); Hsin, Jen [Univ. of Illinois, Urbana-Champaign, IL (United States); Chandler, Danielle [Univ. of Illinois, Urbana-Champaign, IL (United States); Scheuring, Simon [Institut National de la Sante Et Recherche Medicale, Paris (France); Hunter, C. Neil [Univ. of Sheffield (United Kingdom); Schulten, Klaus [Univ. of Illinois, Urbana-Champaign, IL (United States)


    Förster's theory of resonant energy transfer underlies a fundamental process in nature, namely the harvesting of sunlight by photosynthetic life forms. The theoretical framework developed by Förster and others describes how electronic excitation migrates in the photosynthetic apparatus of plants, algae, and bacteria from light absorbing pigments to reaction centers where light energy is utilized for the eventual conversion into chemical energy. The demand for highest possible efficiency of light harvesting appears to have shaped the evolution of photosynthetic species from bacteria to plants which, despite a great variation in architecture, display common structural themes founded on the quantum physics of energy transfer as described first by Förster. Herein, Förster’s theory of excitation transfer is summarized, including recent extensions, and the relevance of the theory to photosynthetic systems as evolved in purple bacteria, cyanobacteria, and plants is demonstrated. Förster's energy transfer formula, as used widely today in many fields of science, is also derived.

  2. Transfer of learning between 2D and 3D sources during infancy: Informing theory and practice. (United States)

    Barr, Rachel


    The ability to transfer learning across contexts is an adaptive skill that develops rapidly during early childhood. Learning from television is a specific instance of transfer of learning between a 2-Dimensional (2D) representation and a 3-Dimensional (3D) object. Understanding the conditions under which young children might accomplish this particular kind of transfer is important because by 2 years of age 90% of US children are viewing television on a daily basis. Recent research shows that children can imitate actions presented on television using the corresponding real-world objects, but this same research also shows that children learn less from television than they do from live demonstrations until they are at least 3 years old; termed the video deficit effect. At present, there is no coherent theory to account for the video deficit effect; how learning is disrupted by this change in context is poorly understood. The aims of the present review are (1) to review the conditions under which children transfer learning between 2D images and 3D objects during early childhood, and (2) to integrate developmental theories of memory processing into the transfer of learning from media literature using Hayne's (2004) developmental representational flexibility account. The review will conclude that studies on the transfer of learning between 2D and 3D sources have important theoretical implications for general developmental theories of cognitive development, and in particular the development of a flexible representational system, as well as policy implications for early education regarding the potential use and limitations of media as effective teaching tools during early childhood.

  3. Rhetorical Structure Theory and Text Analysis (United States)


    NO. NO. ACCESSION NO. 11. TITLE (include Security Clasification ) Rhetorical Structure Theory and Text Analysis (Unclassified) 12. PERSONAL AUTHOR(S...34Antithesis: A Study in Clause Combining and Discourse Structure ," in Ross Steele and Terry Threadgold (eds.), Language Topics: Essays in Honour of M

  4. Non-Markovian theory for the waiting time distributions of single electron transfers. (United States)

    Welack, Sven; Yan, YiJing


    We derive a non-Markovian theory for waiting time distributions of consecutive single electron transfer events. The presented microscopic Pauli rate equation formalism couples the open electrodes to the many-body system, allowing to take finite bias and temperature into consideration. Numerical results reveal transient oscillations of distinct system frequencies due to memory in the waiting time distributions. Memory effects can be approximated by an expansion in non-Markovian corrections. This method is employed to calculate memory landscapes displaying preservation of memory over multiple consecutive electron transfers.

  5. Correspondence analysis theory, practice and new strategies

    CERN Document Server

    Beh, Eric J


    A comprehensive overview of the internationalisation of correspondence analysis Correspondence Analysis: Theory, Practice and New Strategies examines the key issues of correspondence analysis, and discusses the new advances that have been made over the last 20 years. The main focus of this book is to provide a comprehensive discussion of some of the key technical and practical aspects of correspondence analysis, and to demonstrate how they may be put to use.  Particular attention is given to the history and mathematical links of the developments made. These links include not just those majo

  6. An Introduction to Wavelet Theory and Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Miner, N.E.


    This report reviews the history, theory and mathematics of wavelet analysis. Examination of the Fourier Transform and Short-time Fourier Transform methods provides tiormation about the evolution of the wavelet analysis technique. This overview is intended to provide readers with a basic understanding of wavelet analysis, define common wavelet terminology and describe wavelet amdysis algorithms. The most common algorithms for performing efficient, discrete wavelet transforms for signal analysis and inverse discrete wavelet transforms for signal reconstruction are presented. This report is intended to be approachable by non- mathematicians, although a basic understanding of engineering mathematics is necessary.

  7. Dimensional analysis and group theory in astrophysics

    CERN Document Server

    Kurth, Rudolf


    Dimensional Analysis and Group Theory in Astrophysics describes how dimensional analysis, refined by mathematical regularity hypotheses, can be applied to purely qualitative physical assumptions. The book focuses on the continuous spectral of the stars and the mass-luminosity relationship. The text discusses the technique of dimensional analysis, covering both relativistic phenomena and the stellar systems. The book also explains the fundamental conclusion of dimensional analysis, wherein the unknown functions shall be given certain specified forms. The Wien and Stefan-Boltzmann Laws can be si

  8. Sensitivity Analysis of the Gap Heat Transfer Model in BISON.

    Energy Technology Data Exchange (ETDEWEB)

    Swiler, Laura Painton; Schmidt, Rodney C.; Williamson, Richard (INL); Perez, Danielle (INL)


    This report summarizes the result of a NEAMS project focused on sensitivity analysis of the heat transfer model in the gap between the fuel rod and the cladding used in the BISON fuel performance code of Idaho National Laboratory. Using the gap heat transfer models in BISON, the sensitivity of the modeling parameters and the associated responses is investigated. The study results in a quantitative assessment of the role of various parameters in the analysis of gap heat transfer in nuclear fuel.

  9. In the eye of the beholder: Helmholtzian perception and the origins of Freud's 1900 theory of transference. (United States)

    Makari, G J


    Freud's 1900 theory of transference was indebted to the convergence of philosophy and physiology found in nineteenth-century theories of visual perception. The author maps out the post-Kantian philosophical and German physiological currents that gave rise to Hermann von Helmholtz's influential work on perception, and proposes that Freud's 1900 theory of transference was a creative synthesis of novel notions like unconscious wishing and psychic defense with a Helmholtzian model of visual illusion.

  10. Interior point algorithms theory and analysis

    CERN Document Server

    Ye, Yinyu


    The first comprehensive review of the theory and practice of one of today's most powerful optimization techniques. The explosive growth of research into and development of interior point algorithms over the past two decades has significantly improved the complexity of linear programming and yielded some of today's most sophisticated computing techniques. This book offers a comprehensive and thorough treatment of the theory, analysis, and implementation of this powerful computational tool. Interior Point Algorithms provides detailed coverage of all basic and advanced aspects of the subject.

  11. Noncommutative analysis, operator theory and applications

    CERN Document Server

    Cipriani, Fabio; Colombo, Fabrizio; Guido, Daniele; Sabadini, Irene; Sauvageot, Jean-Luc


    This book illustrates several aspects of the current research activity in operator theory, operator algebras and applications in various areas of mathematics and mathematical physics. It is addressed to specialists but also to graduate students in several fields including global analysis, Schur analysis, complex analysis, C*-algebras, noncommutative geometry, operator algebras, operator theory and their applications. Contributors: F. Arici, S. Bernstein, V. Bolotnikov, J. Bourgain, P. Cerejeiras, F. Cipriani, F. Colombo, F. D'Andrea, G. Dell'Antonio, M. Elin, U. Franz, D. Guido, T. Isola, A. Kula, L.E. Labuschagne, G. Landi, W.A. Majewski, I. Sabadini, J.-L. Sauvageot, D. Shoikhet, A. Skalski, H. de Snoo, D. C. Struppa, N. Vieira, D.V. Voiculescu, and H. Woracek.

  12. Radiative Transfer Theory and Diffusion of Light in Nematic Liquid Crystals


    Stark, Holger


    In nematic liquid crystals light is strongly scattered from director fluctuations. We are interested in the limit where the incoming light wave is scattered many times. Then, the light transport can be described by a diffusion equation for the energy density of light with diffusion constants $D_{\\|}$ and $D_{\\perp}$, respectively, parallel and perpendicular to the director. We start from a radiative transfer theory, connect the diffusion constants to the dynamic structure factor of director f...

  13. Theoretical Study of the Charge-Transfer State Separation within Marcus Theory

    DEFF Research Database (Denmark)

    Volpi, Riccardo; Nassau, Racine; Nørby, Morten Steen


    We study, within Marcus theory, the possibility of the charge-transfer (CT) state splitting at organic interfaces and a subsequent transport of the free charge carriers to the electrodes. As a case study we analyze model anthracene-C60 interfaces. Kinetic Monte Carlo (KMC) simulations on the cold...... behavior with respect to both applied field strength and applied field angle. The importance of the hot CT in helping the charge carrier dissociation is also analyzed in our scheme....

  14. Convection Heat Transfer Modeling of Ag Nanofluid Using Different Viscosity Theories

    Directory of Open Access Journals (Sweden)

    Ali Bakhsh Kasaeian


    Full Text Available ABSTRACT: In this paper, the effects of adding nanoparticles (including Ag to a fluid media for improving free convection heat transfer were analysed. The free convective heat transfer was assumed to be in laminar flow regime, and the corresponding calculations and solutions were all done by the integral method. Water, as a Newtonian fluid, was considered as the base and all relevant thermo physical properties of the nanofluids were considered to be unvarying. The calculations performed and the graphs generated showed that, in general, the addition of nanoparticles to the fluid media resulted in an increment or improvement of its heat transfer coefficient. With increase in the concentration of the nanoparticles, the heat transfer rate of the fluid also increased. The increment in heat transfer is also dependent on the nanoparticles’ thermal conductivity and the viscosity theory which was utilized in the calculations. In this study, four different theories were used to calculate the viscosities of the nanofluids. The effects of viscosity on the nanofluids’ thermal conductivity were apparent from the calculations which were performed for nanoparticle concentrations of 4% or less. ABSTRAK: Kajian ini menganalisis kesan penambahan nanopartikel Ag ke dalam media bendalir bagi tujuan pembaikkan pemindahan haba perolakan bebas. Perolakan bebas diandaikan berada di zon aliran laminar, di mana penyelesaian dan pengiraan telah dilakukan mengunakan kaedah kamilan. Air yang merupakan cecair Newtonian, dianggap sebagai asas dan sifat terma fizikal nanocecair dianggapkan tidak berubah. Mengikut pengiraan yang dilakukan dan graf yang diplotkan, umumnya penambahan nanopartikel kepada media bendalir menyebabkan peningkatan dan pengembangan pekali pemindahan haba. Kadar pemindahan haba meningkat dengan nanopartikel. Peningkatan pemindahan haba juga bergantung kepada pengalir haba nanopartikel dan teori kelikatan yang digunakan. Di dalam kajian ini, empat

  15. Transfer of Training: Adding Insight through Social Network Analysis (United States)

    Van den Bossche, Piet; Segers, Mien


    This article reviews studies which apply a social network perspective to examine transfer of training. The theory behind social networks focuses on the interpersonal mechanisms and social structures that exist among interacting units such as people within an organization. A premise of this perspective is that individual's behaviors and outcomes…


    Directory of Open Access Journals (Sweden)

    Alexey S. Besfamilnyy


    Full Text Available The article outlines the basics of using transfer pricing methods applied to the financial analysis of the enterprise. It focuses on the application of transfer pricing methods not only over prices control between related organizations, but for analysis of the financial performance of companies. It proposes to use comparison of profitability of comparable companies during the reporting period. Shows an approach for the search and selection of comparable companies using information systems SPARKS or Bureau van Dijk. It analysis some examples in which the methodology is applicable transfer pricing as a tool of financial analysis.

  17. Application of adult attachment theory to group member transference and the group therapy process. (United States)

    Markin, Rayna D; Marmarosh, Cheri


    Although clinical researchers have applied attachment theory to client conceptualization and treatment in individual therapy, few researchers have applied this theory to group therapy. The purpose of this article is to begin to apply theory and research on adult dyadic and group attachment styles to our understanding of group dynamics and processes in adult therapy groups. In particular, we set forth theoretical propositions on how group members' attachment styles affect relationships within the group. Specifically, this article offers some predictions on how identifying group member dyadic and group attachment styles could help leaders predict member transference within the therapy group. Implications of group member attachment for the selection and composition of a group and the different group stages are discussed. Recommendations for group clinicians and researchers are offered. PsycINFO Database Record (c) 2010 APA, all rights reserved

  18. Theory and applications of numerical analysis

    CERN Document Server

    Phillips, G M


    This text is a self-contained Second Edition, providing an introductory account of the main topics in numerical analysis. The book emphasizes both the theorems which show the underlying rigorous mathematics andthe algorithms which define precisely how to program the numerical methods. Both theoretical and practical examples are included.* a unique blend of theory and applications* two brand new chapters on eigenvalues and splines* inclusion of formal algorithms* numerous fully worked examples* a large number of problems, many with solutions

  19. Charge Transfer Enhancement in the D-π-A Type Porphyrin Dyes: A Density Functional Theory (DFT) and Time-Dependent Density Functional Theory (TD-DFT) Study. (United States)

    Kang, Guo-Jun; Song, Chao; Ren, Xue-Feng


    The electronic geometries and optical properties of two D-π-A type zinc porphyrin dyes (NCH₃-YD2 and TPhe-YD) were systematically investigated by density functional theory (DFT) and time-dependent density functional theory (TD-DFT) to reveal the origin of significantly altered charge transfer enhancement by changing the electron donor of the famous porphyrin-based sensitizer YD2-o-C8. The molecular geometries and photophysical properties of dyes before and after binding to the TiO₂ cluster were fully investigated. From the analyses of natural bond orbital (NBO), extended charge decomposition analysis (ECDA), and electron density variations (Δρ) between the excited state and ground state, it was found that the introduction of N(CH₃)₂ and 1,1,2-triphenylethene groups enhanced the intramolecular charge-transfer (ICT) character compared to YD2-o-C8. The absorption wavelength and transition possess character were significantly influenced by N(CH₃)₂ and 1,1,2-triphenylethene groups. NCH₃-YD2 with N(CH₃)₂ groups in the donor part is an effective way to improve the interactions between the dyes and TiO₂ surface, light having efficiency (LHE), and free energy change (ΔG inject ), which is expected to be an efficient dye for use in dye-sensitized solar cells (DSSCs).

  20. Charge Transfer Enhancement in the D-π-A Type Porphyrin Dyes: A Density Functional Theory (DFT and Time-Dependent Density Functional Theory (TD-DFT Study

    Directory of Open Access Journals (Sweden)

    Guo-Jun Kang


    Full Text Available The electronic geometries and optical properties of two D-π-A type zinc porphyrin dyes (NCH3-YD2 and TPhe-YD were systematically investigated by density functional theory (DFT and time-dependent density functional theory (TD-DFT to reveal the origin of significantly altered charge transfer enhancement by changing the electron donor of the famous porphyrin-based sensitizer YD2-o-C8. The molecular geometries and photophysical properties of dyes before and after binding to the TiO2 cluster were fully investigated. From the analyses of natural bond orbital (NBO, extended charge decomposition analysis (ECDA, and electron density variations (Δρ between the excited state and ground state, it was found that the introduction of N(CH32 and 1,1,2-triphenylethene groups enhanced the intramolecular charge-transfer (ICT character compared to YD2-o-C8. The absorption wavelength and transition possess character were significantly influenced by N(CH32 and 1,1,2-triphenylethene groups. NCH3-YD2 with N(CH32 groups in the donor part is an effective way to improve the interactions between the dyes and TiO2 surface, light having efficiency (LHE, and free energy change (ΔGinject, which is expected to be an efficient dye for use in dye-sensitized solar cells (DSSCs.

  1. Mercury Methylation by HgcA: Theory Supports Carbanion Transfer to Hg(II)

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Jing [University of Tennessee (UT); Riccardi, Demian M [ORNL; Beste, Ariana [ORNL; Smith, Jeremy C [ORNL; Parks, Jerry M [ORNL


    Many proteins use corrinoid cofactors to facilitate methyl transfer reactions. Recently, a corrinoid protein, HgcA, has been shown to be required for the production of the neurotoxin methylmercury by anaerobic bacteria. A strictly conserved Cys residue in HgcA was predicted to be a lower-axial ligand to Co(III), which has never been observed in a corrinoid protein. Here, we use density functional theory to study homolytic and heterolytic Co-C bond dissociation and methyl transfer to Hg(II) substrates with model methylcobalamin complexes containing a lower-axial Cys or His ligand to cobalt, the latter of which is commonly found in other corrinoid proteins. We find that Cys thiolate coordination to Co facilitates both methyl radical and methyl carbanion transfer to Hg(II) substrates, but carbanion transfer is more favorable overall in the condensed phase. Thus, our findings are consistent with HgcA representing a new class of corrinoid protein capable of transferring methyl groups to electrophilic substrates.

  2. Information theory applications for biological sequence analysis. (United States)

    Vinga, Susana


    Information theory (IT) addresses the analysis of communication systems and has been widely applied in molecular biology. In particular, alignment-free sequence analysis and comparison greatly benefited from concepts derived from IT, such as entropy and mutual information. This review covers several aspects of IT applications, ranging from genome global analysis and comparison, including block-entropy estimation and resolution-free metrics based on iterative maps, to local analysis, comprising the classification of motifs, prediction of transcription factor binding sites and sequence characterization based on linguistic complexity and entropic profiles. IT has also been applied to high-level correlations that combine DNA, RNA or protein features with sequence-independent properties, such as gene mapping and phenotype analysis, and has also provided models based on communication systems theory to describe information transmission channels at the cell level and also during evolutionary processes. While not exhaustive, this review attempts to categorize existing methods and to indicate their relation with broader transversal topics such as genomic signatures, data compression and complexity, time series analysis and phylogenetic classification, providing a resource for future developments in this promising area.

  3. Theory of nanolaser devices: Rate equation analysis versus microscopic theory

    DEFF Research Database (Denmark)

    Lorke, Michael; Skovgård, Troels Suhr; Gregersen, Niels


    A rate equation theory for quantum-dot-based nanolaser devices is developed. We show that these rate equations are capable of reproducing results of a microscopic semiconductor theory, making them an appropriate starting point for complex device simulations of nanolasers. The input...

  4. Compositional Data Analysis Theory and Applications

    CERN Document Server

    Pawlowsky-Glahn, Vera


    This book presents the state-of-the-art in compositional data analysis and will feature a collection of papers covering theory, applications to various fields of science and software. Areas covered will range from geology, biology, environmental sciences, forensic sciences, medicine and hydrology. Key features:Provides the state-of-the-art text in compositional data analysisCovers a variety of subject areas, from geology to medicineWritten by leading researchers in the fieldIs supported by a website featuring R code

  5. Rethinking World System Theory: A Historical and Conceptual Analysis


    Agussalim, Burhanuddin


    - This article is a historical and conceptual analysis of World Systems Theory which proposed by Immanuel Wallerstein. This paper aims to explore historical framework of world system theory, explain the unit of analysis, and describe its relationship with other social science theories. Historical exploration of Wallerstein and this theory show a strong influence of historical study were obtained from Wallerstein background and people around him. Conceptual analysis to this theory shows tha...

  6. Heat transfer and thermal stress analysis in grooved tubes

    Indian Academy of Sciences (India)

    Heat transfer and thermal stresses, induced by temperature differencesin the internally grooved tubes of heat transfer equipment, have been analysed numerically. The analysis has been conducted for four different kinds of internally grooved tubes and three different mean inlet water velocities. Constant temperature was ...

  7. Analysis of transference in Gestalt group psychotherapy. (United States)

    Frew, J E


    In Gestalt therapy, transference is viewed as a contact boundary disturbance which impairs the patient's ability to accurately perceive the present therapy situation. The boundary disturbances in Gestalt therapy most closely related to the analytic notion of transference are projection, introjection, and confluence. In Gestalt group psychotherapy, group members interfere with the process of need identification and satisfaction by distorting their contact with each other through projecting, introjecting, and being confluent. The Gestalt group therapist uses interventions directed to individuals and to the group to increase participants' awareness of these boundary disturbances and of the present contact opportunities available to them when these disturbances are resolved. In formulating interventions, the leader is mindful of the function of boundary disturbances to the group-as-a-whole as well as to individuals.

  8. Modeling energy transfer in molecular collisions: Statistical theory versus experiment for highly excited toluene and azulene (United States)

    Nilsson, Daniel; Nordholm, Sture


    The recent development and application of the method of kinetically controlled selective ionization has produced detailed and reliable data on the collisional energy transfer kernel P(E',E) entering master equation theories of unimolecular reaction rates. Here we test the ability of our partially ergodic collision theory (PECT) to predict the functional form of the observed kernel leaving only one parameter, the first moment of the distribution , to be input from other sources. The data explored here include two reactant molecules, toluene and azulene, in collisions with 18 and 8 medium molecules, respectively, ranging from inert gas atoms to n-heptane. The initial energy of the reactant molecule is varied from 10 000 cm-1 to 49 000 cm-1 and 30 000 cm-1, respectively. The energy transfer efficiency βE is about one-tenth of its ergodic collision limit of unity. The PECT is found to fit the monoexponential form of the kernel determined from the experimental data over a broad range of initial energies E including tail regions of very low probability. A minor but systematic deviation is observed for nearly elastic collisions of large medium molecules. The functional fit is good enough to effectively allow the three parameters of the monoexponential experimental kernel to be replaced by a single parameter representing energy transfer efficiency.

  9. Theory of interfacial charge-transfer complex photophysics in π-conjugated polymer-fullerene blends (United States)

    Aryanpour, K.; Psiachos, D.; Mazumdar, S.


    We present a theory of the electronic structure and photophysics of 1:1 blends of derivatives of polyparaphenylenevinylene and fullerenes [1]. Within the same Coulomb-correlated Hamiltonian applied previously to interacting chains of single-component π-conjugated polymers [2], we find an exciplex state that occurs below the polymer's optical exciton. Weak absorption from the ground state occurs to the exciplex. We explain transient photoinduced absorptions in the blend [3], observed for both above-gap and below-gap photoexcitations, within our theory. Photoinduced absorptions for above-gap photoexcitation are from the optical exciton as well as the exciplex, while for below-gap photoexcitation induced absorptions are from the exciplex alone. In neither case are free polarons generated in the time scale of the experiment. Importantly, the photophysics of films of single-component π-conjugated polymers and blends can both be understood by extending Mulliken's theory of ground state charge-transfer to the case of excited state charge-transfer. [1] K. Aryanpour, D. Psiachos, and S. Mazumdar, arXiv:0908.0366 [2] D. Psiachos and S. Mazumdar, Phys. Rev. B. 79 155106 (2009) [3] T. Drori et al., Phys. Rev. Lett. 101, 037402 (2008)

  10. Intermolecular Singlet and Triplet Exciton Transfer Integrals from Many-Body Green's Functions Theory. (United States)

    Wehner, Jens; Baumeier, Björn


    A general approach to determine orientation and distance-dependent effective intermolecular exciton transfer integrals from many-body Green's functions theory is presented. On the basis of the GW approximation and the Bethe-Salpeter equation (BSE), a projection technique is employed to obtain the excitonic coupling by forming the expectation value of a supramolecular BSE Hamiltonian with electron-hole wave functions for excitations localized on two separated chromophores. Within this approach, accounting for the effects of coupling mediated by intermolecular charge transfer (CT) excitations is possible via perturbation theory or a reduction technique. Application to model configurations of pyrene dimers shows an accurate description of short-range exchange and long-range Coulomb interactions for the coupling of singlet and triplet excitons. Computational parameters, such as the choice of the exchange-correlation functional in the density-functional theory (DFT) calculations that underly the GW-BSE steps and the convergence with the number of included CT excitations, are scrutinized. Finally, an optimal strategy is derived for simulations of full large-scale morphologies by benchmarking various approximations using pairs of dicyanovinyl end-capped oligothiophenes (DCV5T), which are used as donor material in state-of-the-art organic solar cells.

  11. Theory of Excitation Transfer between Two-Dimensional Semiconductor and Molecular Layers (United States)

    Specht, Judith F.; Verdenhalven, Eike; Bieniek, Björn; Rinke, Patrick; Knorr, Andreas; Richter, Marten


    The geometry-dependent energy transfer rate from an electrically pumped inorganic semiconductor quantum well into an organic molecular layer is studied theoretically. We focus on Förster-type nonradiative excitation transfer between the organic and inorganic layers and include quasimomentum conservation and intermolecular coupling between the molecules in the organic film. (Transition) partial charges calculated from density-functional theory are used to calculate the coupling elements. The partial charges describe the spatial charge distribution and go beyond the common dipole-dipole interaction. We find that the transfer rates are highly sensitive to variations in the geometry of the hybrid inorganic-organic system. For instance, the transfer efficiency is improved by up to 2 orders of magnitude by tuning the spatial arrangement of the molecules on the surface: Parameters of importance are the molecular packing density along the effective molecular dipole axis and the distance between the molecules and the surface. We also observe that the device performance strongly depends on the orientation of the molecular dipole moments relative to the substrate dipole moments determined by the inorganic crystal structure. Moreover, the operating regime is identified where inscattering dominates over unwanted backscattering from the molecular layer into the substrate.

  12. Experimental verification of bioheat transfer theories: measurement of temperature profiles around large artificial vessels in perfused tissue

    NARCIS (Netherlands)

    Crezee, J.; Lagendijk, J. J.


    The verification of thermal models for use in hyperthermia treatment planning is essential. We investigated the heat transfer between a single vessel and the surrounding vascularised tissue, comparing the conventional bioheat transfer theory and the recently developed keff model using analytical and

  13. Laboratory theory and methods for sediment analysis (United States)

    Guy, Harold P.


    The diverse character of fluvial sediments makes the choice of laboratory analysis somewhat arbitrary and the pressing of sediment samples difficult. This report presents some theories and methods used by the Water Resources Division for analysis of fluvial sediments to determine the concentration of suspended-sediment samples and the particle-size distribution of both suspended-sediment and bed-material samples. Other analyses related to these determinations may include particle shape, mineral content, and specific gravity, the organic matter and dissolved solids of samples, and the specific weight of soils. The merits and techniques of both the evaporation and filtration methods for concentration analysis are discussed. Methods used for particle-size analysis of suspended-sediment samples may include the sieve pipet, the VA tube-pipet, or the BW tube-VA tube depending on the equipment available, the concentration and approximate size of sediment in the sample, and the settling medium used. The choice of method for most bed-material samples is usually limited to procedures suitable for sand or to some type of visual analysis for large sizes. Several tested forms are presented to help insure a well-ordered system in the laboratory to handle the samples, to help determine the kind of analysis required for each, to conduct the required processes, and to assist in the required computations. Use of the manual should further 'standardize' methods of fluvial sediment analysis among the many laboratories and thereby help to achieve uniformity and precision of the data.

  14. Constructivism theory analysis and application to curricula. (United States)

    Brandon, Amy F; All, Anita C


    Today's nursing programs are struggling to accommodate the changing needs of the health care environment and need to make changes in how students are taught. Using constructivism theory, whereby learning is an active process in which learners construct new ideas or concepts based upon their current or past knowledge, leaders in nursing education can make a paradigm shift toward concept-based curricula. This article presents a summary and analysis of constructivism and an innovative application of its active-learning principles to curriculum development, specifically for the education of nursing students.

  15. Application of Marcus theory for modeling proton transfer in cytochrome c oxidase (United States)

    Garbuz, A. A.; Boronovskiy, S. E.; Nartsissov, Ya R.


    The process of proton transport in cytochrome c oxidase is studied in the framework of stochastic modeling. The activation energies are calculated using Marcus theory. This model allows to define the key amino acid residues and water molecules which form the main H+ transduction pathway. According to the simulation results, Asn-207 and Asn-121 are not involved in direct proton translocation. The estimated rate of the proton transfer through the D-channel of cytochrome c oxidase is (1.43±0.18)·104 s-1.

  16. High-energy, large-momentum-transfer processes: Ladder diagrams in φ3 theory. Pt. 2

    International Nuclear Information System (INIS)

    Osland, P.; Wu, T.T.; Harvard Univ., Cambridge, MA


    The scattering amplitude for the four-rung ladder diagram in φ 3 theory is evaluated at high energies and for large momentum transfers. The result takes the form of s -1 vertical stroketvertical stroke -3 multiplied by a homogeneous sixth-order polynomial in ln s and 1nvertical stroketvertical stroke. The novel and unexpected feature is that this polynomial is different depending on whether 1n vertical stroketvertical stroke is larger or less than 1/2 1n s. Thus the asymptotic formula is not analytic at 1n vertical stroketvertical stroke=1/2 1n s, although the first five derivatives are continuous. (orig.)

  17. The Frustrations of Reader Generalizability and Grounded Theory: Alternative Considerations for Transferability

    Directory of Open Access Journals (Sweden)

    Thomas Misco


    Full Text Available In this paper I convey a recurring problem and possible solution that arose during my doctoral research on the topic of cross-cultural Holocaust curriculum development for Latvian schools. Specifically, as I devised the methodology for my research, I experienced a number of frustrations concerning the issue of transferability and the limitations of both reader generalizability and grounded theory. Ultimately, I found a more appropriate goal for the external applicability of this and other highly contextual research studies in the form of "grounded understandings," which are tentative apprehensions of the importance or significance of phenomena and conceptualizations that hold meaning and explanatory power, but are only embryonic in their potential to generate theory.

  18. Fundamental Neutron Physics: Theory and Analysis

    International Nuclear Information System (INIS)

    Gudkov, Vladimir


    The goal of the proposal was to study the possibility of searching for manifestations of new physics beyond the Standard model in fundamental neutron physics experiments. This involves detailed theoretical analyses of parity- and time reversal invariance-violating processes in neutron-induced reactions, properties of neutron β-decay, and the precise description of properties of neutron interactions with nuclei. To describe neutron-nuclear interactions, we use both the effective field theory approach and the theory of nuclear reaction with phenomenological nucleon potentials for the systematic description of parity- and time reversal-violating effects in the consistent way. A major emphasis of our research during the funding period has been the study of parity violation (PV) and time reversal invariance violation (TRIV) in few-body systems. We studied PV effects in non-elastic processes in three-nucleon system using both ''DDH-like'' and effective field theory (EFT) approaches. The wave functions were obtained by solving three-body Faddeev equations in configuration space for a number of realistic strong potentials. The observed model dependence for the DDH approach indicates intrinsic difficulty in the description of nuclear PV effects, and it could be the reason for the observed discrepancies in the nuclear PV data analysis. It shows that the DDH approach could be a reasonable approach for analysis of PV effects only if exactly the same strong and weak potentials are used in calculating all PV observables in all nuclei. However, the existing calculations of nuclear PV effects were performed using different potentials; therefore, strictly speaking, one cannot compare the existing results of these calculations among themselves.

  19. A Comparative Analysis of Three Unique Theories of Organizational Learning (United States)

    Leavitt, Carol C.


    The purpose of this paper is to present three classical theories on organizational learning and conduct a comparative analysis that highlights their strengths, similarities, and differences. Two of the theories -- experiential learning theory and adaptive -- generative learning theory -- represent the thinking of the cognitive perspective, while…

  20. Blocking layer modeling for temperature analysis of electron transfer ...

    African Journals Online (AJOL)

    In this article, we simulate thermal effects on the electron transfer rate from three quantum dots CdSe, CdS and CdTe to three metal oxides TiO2, SnO2 and ZnO2 in the presence of four blocking layers ZnS, ZnO, TiO2 and Al2O3, in a porous quantum dot sensitized solar cell (QDSSC) structure, using Marcus theory.

  1. Perturbative analysis in higher-spin theories

    Energy Technology Data Exchange (ETDEWEB)

    Didenko, V.E. [I.E. Tamm Department of Theoretical Physics, Lebedev Physical Institute,Leninsky prospect 53, 119991, Moscow (Russian Federation); Misuna, N.G. [Moscow Institute of Physics and Technology,Institutsky lane 9, 141700, Dolgoprudny, Moscow region (Russian Federation); Vasiliev, M.A. [I.E. Tamm Department of Theoretical Physics, Lebedev Physical Institute,Leninsky prospect 53, 119991, Moscow (Russian Federation)


    A new scheme of the perturbative analysis of the nonlinear HS equations is developed giving directly the final result for the successive application of the homotopy integrations which appear in the standard approach. It drastically simplifies the analysis and results from the application of the standard spectral sequence approach to the higher-spin covariant derivatives, allowing us in particular to reduce multiple homotopy integrals resulting from the successive application of the homotopy trick to a single integral. Efficiency of the proposed method is illustrated by various examples. In particular, it is shown how the Central on-shell theorem of the free theory immediately results from the nonlinear HS field equations with no intermediate computations.

  2. Nonlinear analysis approximation theory, optimization and applications

    CERN Document Server


    Many of our daily-life problems can be written in the form of an optimization problem. Therefore, solution methods are needed to solve such problems. Due to the complexity of the problems, it is not always easy to find the exact solution. However, approximate solutions can be found. The theory of the best approximation is applicable in a variety of problems arising in nonlinear functional analysis and optimization. This book highlights interesting aspects of nonlinear analysis and optimization together with many applications in the areas of physical and social sciences including engineering. It is immensely helpful for young graduates and researchers who are pursuing research in this field, as it provides abundant research resources for researchers and post-doctoral fellows. This will be a valuable addition to the library of anyone who works in the field of applied mathematics, economics and engineering.

  3. A coherent modified Redfield theory for excitation energy transfer in molecular aggregates

    Energy Technology Data Exchange (ETDEWEB)

    Hwang-Fu, Yu-Hsien; Chen, Wei; Cheng, Yuan-Chung, E-mail:


    Highlights: • A CMRT method for coherent energy transfer in molecular aggregates was developed. • Applicability of the method was verified in two-site systems with various parameters. • CMRT accurately describes population dynamics in the FMO-complex. • The method is accurate in a large parameter space and computationally efficient. - Abstract: Excitation energy transfer (EET) is crucial in photosynthetic light harvesting, and quantum coherence has been recently proven to be a ubiquitous phenomenon in photosynthetic EET. In this work, we derive a coherent modified Redfield theory (CMRT) that generalizes the modified Redfield theory to treat coherence dynamics. We apply the CMRT method to simulate the EET in a dimer system and compare the results with those obtained from numerically exact path integral calculations. The comparison shows that CMRT provides excellent computational efficiency and accuracy within a large EET parameter space. Furthermore, we simulate the EET dynamics in the FMO complex at 77 K using CMRT. The results show pronounced non-Markovian effects and long-lasting coherences in the ultrafast EET, in excellent agreement with calculations using the hierarchy equation of motion approach. In summary, we have successfully developed a simple yet powerful framework for coherent EET dynamics in photosynthetic systems and organic materials.

  4. The liquidity preference theory: a critical analysis


    Giancarlo Bertocco; Andrea Kalajzic


    Keynes in the General Theory, explains the monetary nature of the interest rate by means of the liquidity preference theory. The objective of this paper is twofold. First, to point out the limits of the liquidity preference theory. Second, to present an explanation of the monetary nature of the interest rate based on the arguments with which Keynes responded to the criticism levelled at the liquidity preference theory by supporters of the loanable funds theory such as Ohlin and Robertson. It ...

  5. Application of Stochastic Radiative Transfer Theory to the ARM Cloud-Radiative Parameterization Problem

    Energy Technology Data Exchange (ETDEWEB)

    Veron, Dana E


    This project had two primary goals: 1) development of stochastic radiative transfer as a parameterization that could be employed in an AGCM environment, and 2) exploration of the stochastic approach as a means for representing shortwave radiative transfer through mixed-phase layer clouds. To achieve these goals, an analysis of the performance of the stochastic approach was performed, a simple stochastic cloud-radiation parameterization for an AGCM was developed and tested, a statistical description of Arctic mixed phase clouds was developed and the appropriateness of stochastic approach for representing radiative transfer through mixed-phase clouds was assessed. Significant progress has been made in all of these areas and is detailed below.

  6. Theory of chemical kinetics and charge transfer based on nonequilibrium thermodynamics. (United States)

    Bazant, Martin Z


    Advances in the fields of catalysis and electrochemical energy conversion often involve nanoparticles, which can have kinetics surprisingly different from the bulk material. Classical theories of chemical kinetics assume independent reactions in dilute solutions, whose rates are determined by mean concentrations. In condensed matter, strong interactions alter chemical activities and create variations that can dramatically affect the reaction rate. The extreme case is that of a reaction coupled to a phase transformation, whose kinetics must depend not only on the order parameter but also on its gradients at phase boundaries. Reaction-driven phase transformations are common in electrochemistry, when charge transfer is accompanied by ion intercalation or deposition in a solid phase. Examples abound in Li-ion, metal-air, and lead-acid batteries, as well as metal electrodeposition-dissolution. Despite complex thermodynamics, however, the standard kinetic model is the Butler-Volmer equation, based on a dilute solution approximation. The Marcus theory of charge transfer likewise considers isolated reactants and neglects elastic stress, configurational entropy, and other nonidealities in condensed phases. The limitations of existing theories recently became apparent for the Li-ion battery material LixFePO4 (LFP). It has a strong tendency to separate into Li-rich and Li-poor solid phases, which scientists believe limits its performance. Chemists first modeled phase separation in LFP as an isotropic "shrinking core" within each particle, but experiments later revealed striped phase boundaries on the active crystal facet. This raised the question: What is the reaction rate at a surface undergoing a phase transformation? Meanwhile, dramatic rate enhancement was attained with LFP nanoparticles, and classical battery models could not predict the roles of phase separation and surface modification. In this Account, I present a general theory of chemical kinetics, developed over

  7. Predecessor-Successor Transitions in Institutional and Interpersonal Contexts. On the Development of a Theory of the Transfer of Personal Objects

    Directory of Open Access Journals (Sweden)

    Franz Breuer


    Full Text Available This article outlines the development of a theory of predecessor-successor transitions in social contexts using a grounded theory approach. The theory can be applied to such diverse phenomena as the transfer of family businesses to the next generation, university chair succession, the passing on of parental roles (for example in the case of adoption or remarriage, and organ transplantation. The core conceptual category that emerged was "the transfer of personal objects". This concept refers to the transfer of the power of disposal over objects that are fundamental to the identity and the identification of the owner. A number of theoretical dimensions of the category were identified. Methodologically speaking, the theory generated can be classified as a formal grounded theory. In other words, the comparison of different empirical fields and cases using hermeneutical analysis yielded a transdisciplinary social science category that can be employed to conceptualise the dynamics of the development of interpersonal, social, or institutional structures, especially with regard to the links and the interplay between material and symbolic components, between the individual and the social, and the past and the present. URN:

  8. Did you have an impact? A theory-based method for planning and evaluating knowledge-transfer and exchange activities in occupational health and safety. (United States)

    Kramer, Desré M; Wells, Richard P; Carlan, Nicolette; Aversa, Theresa; Bigelow, Philip P; Dixon, Shane M; McMillan, Keith


    Few evaluation tools are available to assess knowledge-transfer and exchange interventions. The objective of this paper is to develop and demonstrate a theory-based knowledge-transfer and exchange method of evaluation (KEME) that synthesizes 3 theoretical frameworks: the promoting action on research implementation of health services (PARiHS) model, the transtheoretical model of change, and a model of knowledge use. It proposes a new term, keme, to mean a unit of evidence-based transferable knowledge. The usefulness of the evaluation method is demonstrated with 4 occupational health and safety knowledge transfer and exchange (KTE) implementation case studies that are based upon the analysis of over 50 pre-existing interviews. The usefulness of the evaluation model has enabled us to better understand stakeholder feedback, frame our interpretation, and perform a more comprehensive evaluation of the knowledge use outcomes of our KTE efforts.

  9. Attachment theory as a guide to understanding and working with transference and the real relationship in psychotherapy. (United States)

    Gelso, Charles J; Palma, Beatriz; Bhatia, Avantika


    Recent decades have witnessed an extraordinary amount of conceptual and empirical work on attachment theory in psychology and psychotherapy. Attachment theory is discussed in the present article as a way of understanding and fostering therapeutic work with 2 other key relationship constructs that have been theorized to be elements of all psychotherapies: client transference and the real relationship existing between the therapist and patient. Fundamental features of attachment, transference, and the real relationship are summarized. Particular emphasis is given to the role of the therapist as a secure base and a safe haven within the real relationship, and to the patient's internal working model as it relates to transference. A case of long-term psychodynamic psychotherapy conducted by the first author is presented to illuminate the 3 main constructs. The case demonstrates both the usefulness of attachment theory and the fact that any single theory cannot explain all of the complex features of a given treatment. © 2013 Wiley Periodicals, Inc.

  10. Density functional theory for the description of charge-transfer processes at TTF/TCNQ interfaces

    KAUST Repository

    Van Regemorter, Tanguy


    In the field of organic electronics, a central issue is to assess how the frontier electronic levels of two adjacent organic layers align with respect to one another at the interface. This alignment can be driven by the presence of a partial charge transfer and the formation of an interface dipole; it plays a key role for instance in determining the rates of exciton dissociation or exciton formation in organic solar cells or light-emitting diodes, respectively. Reliably modeling the processes taking place at these interfaces remains a challenge for the computational chemistry community. Here, we review our recent theoretical work on the influence of the choice of density functional theory (DFT) methodology on the description of the charge-transfer character in the ground state of TTF/ TCNQ model complexes and interfaces. Starting with the electronic properties of the isolated TTF and TCNQ molecules and then considering the charge transfer and resulting interface dipole in TTF/TCNQ donor-acceptor stacks and bilayers, we examine the impact of the choice of DFT functional in describing the interfacial electronic structure. Finally, we employ computations based on periodic boundary conditions to highlight the impact of depolarization effects on the interfacial dipole moment. © Springer-Verlag 2012.

  11. Transfer representation learning for medical image analysis. (United States)

    Chuen-Kai Shie; Chung-Hisang Chuang; Chun-Nan Chou; Meng-Hsi Wu; Chang, Edward Y


    There are two major challenges to overcome when developing a classifier to perform automatic disease diagnosis. First, the amount of labeled medical data is typically very limited, and a classifier cannot be effectively trained to attain high disease-detection accuracy. Second, medical domain knowledge is required to identify representative features in data for detecting a target disease. Most computer scientists and statisticians do not have such domain knowledge. In this work, we show that employing transfer learning can remedy both problems. We use Otitis Media (OM) to conduct our case study. Instead of using domain knowledge to extract features from labeled OM images, we construct features based on a dataset entirely OM-irrelevant. More specifically, we first learn a codebook in an unsupervised way from 15 million images collected from ImageNet. The codebook gives us what the encoders consider being the fundamental elements of those 15 million images. We then encode OM images using the codebook and obtain a weighting vector for each OM image. Using the resulting weighting vectors as the feature vectors of the OM images, we employ a traditional supervised learning algorithm to train an OM classifier. The achieved detection accuracy is 88.5% (89.63% in sensitivity and 86.9% in specificity), markedly higher than all previous attempts, which relied on domain experts to help extract features.

  12. Multiple and dependent scattering by densely packed discrete spheres: Comparison of radiative transfer and Maxwell theory

    International Nuclear Information System (INIS)

    Ma, L.X.; Tan, J.Y.; Zhao, J.M.; Wang, F.Q.; Wang, C.A.


    The radiative transfer equation (RTE) has been widely used to deal with multiple scattering of light by sparsely and randomly distributed discrete particles. However, for densely packed particles, the RTE becomes questionable due to strong dependent scattering effects. This paper examines the accuracy of RTE by comparing with the exact electromagnetic theory. For an imaginary spherical volume filled with randomly distributed, densely packed spheres, the RTE is solved by the Monte Carlo method combined with the Percus–Yevick hard model to consider the dependent scattering effect, while the electromagnetic calculation is based on the multi-sphere superposition T-matrix method. The Mueller matrix elements of the system with different size parameters and volume fractions of spheres are obtained using both methods. The results verify that the RTE fails to deal with the systems with a high-volume fraction due to the dependent scattering effects. Apart from the effects of forward interference scattering and coherent backscattering, the Percus–Yevick hard sphere model shows good accuracy in accounting for the far-field interference effects for medium or smaller size parameters (up to 6.964 in this study). For densely packed discrete spheres with large size parameters (equals 13.928 in this study), the improvement of dependent scattering correction tends to deteriorate. The observations indicate that caution must be taken when using RTE in dealing with the radiative transfer in dense discrete random media even though the dependent scattering correction is applied. - Highlights: • The Muller matrix of randomly distributed, densely packed spheres are investigated. • The effects of multiple scattering and dependent scattering are analyzed. • The accuracy of radiative transfer theory for densely packed spheres is discussed. • Dependent scattering correction takes effect at medium size parameter or smaller. • Performance of dependent scattering correction

  13. General theory of excitation energy transfer in donor-mediator-acceptor systems. (United States)

    Kimura, Akihiro


    General theory of the excitation energy transfer (EET) in the case of donor-mediator-acceptor system was constructed by using generalized master equation (GME). In this theory, we consider the direct and indirect transitions in the EET consistently. Hence, our theory includes the quantum mechanical interference between the direct and indirect transitions automatically. Memory functions in the GME were expressed by the overlap integrals among the time-dependent emission spectrum of the donor, the absorption spectrum of the mediator, the time-dependent emission spectrum of the mediator, and the absorption spectrum of the acceptor. In the Markov limit of the memory functions, we obtained the rate of EET which consists of three terms due to the direct transition, the indirect transition, and the interference between them. We found that the interference works effectively in the limit of slow thermalization at the intermediate state. The formula of EET rate in this limit was expressed by the convolution of the EET interaction and optical spectra. The interference effect strongly depends on the width of the absorption spectrum of mediator molecule and the energy gap between the donor and the mediator molecules.

  14. Electronic energy transfer through non-adiabatic vibrational-electronic resonance. I. Theory for a dimer. (United States)

    Tiwari, Vivek; Peters, William K; Jonas, David M


    Non-adiabatic vibrational-electronic resonance in the excited electronic states of natural photosynthetic antennas drastically alters the adiabatic framework, in which electronic energy transfer has been conventionally studied, and suggests the possibility of exploiting non-adiabatic dynamics for directed energy transfer. Here, a generalized dimer model incorporates asymmetries between pigments, coupling to the environment, and the doubly excited state relevant for nonlinear spectroscopy. For this generalized dimer model, the vibrational tuning vector that drives energy transfer is derived and connected to decoherence between singly excited states. A correlation vector is connected to decoherence between the ground state and the doubly excited state. Optical decoherence between the ground and singly excited states involves linear combinations of the correlation and tuning vectors. Excitonic coupling modifies the tuning vector. The correlation and tuning vectors are not always orthogonal, and both can be asymmetric under pigment exchange, which affects energy transfer. For equal pigment vibrational frequencies, the nonadiabatic tuning vector becomes an anti-correlated delocalized linear combination of intramolecular vibrations of the two pigments, and the nonadiabatic energy transfer dynamics become separable. With exchange symmetry, the correlation and tuning vectors become delocalized intramolecular vibrations that are symmetric and antisymmetric under pigment exchange. Diabatic criteria for vibrational-excitonic resonance demonstrate that anti-correlated vibrations increase the range and speed of vibronically resonant energy transfer (the Golden Rule rate is a factor of 2 faster). A partial trace analysis shows that vibronic decoherence for a vibrational-excitonic resonance between two excitons is slower than their purely excitonic decoherence.

  15. Theoretical and methodological analysis of personality theories of leadership


    Оксана Григорівна Гуменюк


    The psychological analysis of personality theories of leadership, which is the basis for other conceptual approaches to understanding the nature of leadership, is conducted. Conceptual approach of leadership is analyzed taking into account the priority of personality theories, including: heroic, psychoanalytic, «trait» theory, charismatic and five-factor. It is noted that the psychological analysis of personality theories are important in understanding the nature of leadership

  16. Heat and mass transfer analysis of a desiccant dehumidifier matrix

    Energy Technology Data Exchange (ETDEWEB)

    Pesaran, A.A.


    This report documents the SERI Single-Blow Test Facility's design, fabrication, and testing for characterizing desiccant dehumidifiers for solar cooling applications. The first test article, a silica-gel parallel-plate dehumidifier with highly uniform passages, was designed and fabricated. Transient heat and mass transfer data and pressure drop data across the dehumidifier were obtained. Available heat and mass transfer models were extended to the parallel-place geometry, and the experimental data were compared with model predictions. Pressure drop measurements were also compared with model predictions of the fully developed laminar flow theory. The comparisons between the lumped-capacitance model and the experimental data were satisfactory. The pressure drop data compared satisfactorily with the theory (within 15%). A solid-side resistance model that is more detailed and does not assume symmetrical diffusion in particles was recommended for performance. This study has increased our understanding of the heat and mass transfer in silica gel parallel-plate dehumidifiers.

  17. Childhood obesity in transition zones: an analysis using structuration theory. (United States)

    Chan, Christine; Deave, Toity; Greenhalgh, Trisha


    Childhood obesity is particularly prevalent in areas that have seen rapid economic growth, urbanisation, cultural transition, and commodification of food systems. Structuration theory may illuminate the interaction between population and individual-level causes of obesity. We conducted in-depth ethnographies of six overweight/obese and four non-overweight preschool children in Hong Kong, each followed for 12-18 months. Analysis was informed by Stones' strong structuration theory. Risk factors played out differently for different children as social structures were enacted at the level of family and preschool. The network of caregiving roles and relationships around the overweight/obese child was typically weak and disjointed, and the primary caregiver appeared confused by mixed messages about what is normal, expected and legitimate behaviour. In particular, external social structures created pressure to shift childcare routines from the logic of nurturing to the logic of consumption. Our findings suggest that threats to what Giddens called ontological security in the primary caregiver may underpin the poor parenting, family stress and weak mealtime routines that mediate the relationship between an obesogenic environment and the development of obesity in a particular child. This preliminary study offers a potentially transferable approach for studying emerging epidemics of diseases of modernity in transition societies.

  18. Monovalent counterion distributions at highly charged water interfaces: Proton-transfer and Poisson-Boltzmann theory

    Energy Technology Data Exchange (ETDEWEB)

    Bu, W.; Vaknin, D.; Travesset, A. (Iowa State)


    Surface sensitive synchrotron-x-ray scattering studies reveal the distributions of monovalent ions next to highly charged interfaces. A lipid phosphate (dihexadecyl hydrogen phosphate) was spread as a monolayer at the air-water interface, containing CsI at various concentrations. Using anomalous reflectivity off and at the L{sub 3} Cs{sup +} resonance, we provide spatial counterion distributions (Cs{sup +}) next to the negatively charged interface over a wide range of ionic concentrations. We argue that at low salt concentrations and for pure water the enhanced concentration of hydroniums H{sub 3}O{sup +} at the interface leads to proton transfer back to the phosphate group by a high contact potential, whereas high salt concentrations lower the contact potential resulting in proton release and increased surface charge density. The experimental ionic distributions are in excellent agreement with a renormalized-surface-charge Poisson-Boltzmann theory without fitting parameters or additional assumptions.

  19. Monovalent counterion distributions at highly charged water interfaces: proton-transfer and Poisson-Boltzmann theory. (United States)

    Bu, Wei; Vaknin, David; Travesset, Alex


    Surface sensitive synchrotron-x-ray scattering studies reveal the distributions of monovalent ions next to highly charged interfaces. A lipid phosphate (dihexadecyl hydrogen phosphate) was spread as a monolayer at the air-water interface, containing CsI at various concentrations. Using anomalous reflectivity off and at the L3 Cs+ resonance, we provide spatial counterion distributions (Cs+) next to the negatively charged interface over a wide range of ionic concentrations. We argue that at low salt concentrations and for pure water the enhanced concentration of hydroniums H3O+ at the interface leads to proton transfer back to the phosphate group by a high contact potential, whereas high salt concentrations lower the contact potential resulting in proton release and increased surface charge density. The experimental ionic distributions are in excellent agreement with a renormalized-surface-charge Poisson-Boltzmann theory without fitting parameters or additional assumptions.

  20. Viscous potential flow analysis of magnetohydrodynamic capillary instability with heat and mass transfer

    Directory of Open Access Journals (Sweden)

    D.K. Tiwari


    Full Text Available A linear analysis of capillary instability of a cylindrical interface in the presence of axial magnetic field has been carried out when there is heat and mass transfer across the interface. Both fluids are taken as incompressible, viscous and magnetic with different kinematic viscosities and different magnetic permeabilities. Viscous potential flow theory is used for the investigation and a dispersion relation that accounts for the growth of axisymmetric waves is derived. Stability criterion is given by critical value of applied magnetic field as well as critical wave number and stability is discussed theoretically as well as numerically. Various graphs are drawn showing the effect of various physical parameters such as magnetic field strength, heat transfer capillary number, and permeability ratio, on the stability of the system. It has been observed that the axial magnetic field and heat and mass transfer both have stabilizing effect on the stability of the system.

  1. Toward a Theory of Adaptive Transfer: Expanding Disciplinary Discussions of "Transfer" in Second-Language Writing and Composition Studies (United States)

    DePalma, Michael-John; Ringer, Jeffrey M.


    In this paper, we argue that discussions of transfer in L2 writing and composition studies have focused primarily on the reuse of past learning and thus have not adequately accounted for the adaptation of learned writing knowledge in unfamiliar situations. In an effort to expand disciplinary discussions of transfer in L2 writing and composition…

  2. Speeding up the aerosol optical thickness retrieval using analytical solutions of radiative transfer theory

    Directory of Open Access Journals (Sweden)

    I. L. Katsev


    Full Text Available We present here the aerosol retrieval technique FAR that uses radiative transfer computations in the process of retrieval rather than look-up tables (LUT. This approach provides operational satellite data processing due to the use of the accurate and extremely fast radiative transfer code RAY previously developed by authors along with approximate analytical solutions of the radiative transfer theory. The model of the stratified atmosphere is taken as two coupled layers. Both layers include aerosol scattering and absorption, molecular scattering and gas absorption. The atmosphere parameters are assumed to change from pixel to pixel in the lower atmosphere layer, but the upper stratified layer of the atmosphere over 2–3 km is supposed to be horizontally homogenous for the frame under retrieval. The model of the land spectral albedo is taken as a weighted sum of two a priory chosen basic spectra.

    The aerosol optical thickness (AOT, Angström exponent and the weight in the land spectral albedo are optimized in the iteration process using the least-squares technique with fast computations of the derivatives of radiative characteristics with respect to retrieved values. The aerosol model and, hence, the aerosol phase function and single scattering albedo, is predefined and does not change in the iteration process. The presented version of FAR is adjusted to process the MERIS data. But it is important that the developed technique can be adapted for processing data of various satellite instruments (including any spectral multi-angle polarization-sensitive sensors.

    The use of approximate analytical radiative transfer solutions considerably speeds up data processing but may lead to about 15–20% increase of AOT retrieval errors. This approach is advantageous when just the satellite data processing time rather than high accuracy of the AOT retrieval is crucial. A good example is monitoring the trans-boundary transfer of aerosol

  3. Category Theory Approach to Solution Searching Based on Photoexcitation Transfer Dynamics

    Directory of Open Access Journals (Sweden)

    Makoto Naruse


    Full Text Available Solution searching that accompanies combinatorial explosion is one of the most important issues in the age of artificial intelligence. Natural intelligence, which exploits natural processes for intelligent functions, is expected to help resolve or alleviate the difficulties of conventional computing paradigms and technologies. In fact, we have shown that a single-celled organism such as an amoeba can solve constraint satisfaction problems and related optimization problems as well as demonstrate experimental systems based on non-organic systems such as optical energy transfer involving near-field interactions. However, the fundamental mechanisms and limitations behind solution searching based on natural processes have not yet been understood. Herein, we present a theoretical background of solution searching based on optical excitation transfer from a category-theoretic standpoint. One important indication inspired by the category theory is that the satisfaction of short exact sequences is critical for an adequate computational operation that determines the flow of time for the system and is termed as “short-exact-sequence-based time.” In addition, the octahedral and braid structures known in triangulated categories provide a clear understanding of the underlying mechanisms, including a quantitative indication of the difficulties of obtaining solutions based on homology dimension. This study contributes to providing a fundamental background of natural intelligence.

  4. Momentum transfer theory of non-conservative charged particle transport in crossed electric and magnetic fields

    International Nuclear Information System (INIS)

    Vrhovac, S.B.; Petrovic, Z.Lj.


    Momentum - transfer approximation is applied to momentum and energy balance equations describing reacting particle swarms in gases in crossed electric and magnetic fields. Transport coefficients of charged particles undergoing both inelastic and reactive, non-particle-conserving collisions with a gas of neutral molecules are calculated. Momentum - transfer theory (MTT) has been developed mainly by Robson and collaborators. It has been applied to a single reactive gas and mixtures of reactive gases in electric field only. MTT has also been applied in crossed electric and magnetic fields recently and independently of our work but the reactive collisions were not considered. Consider a swarm of electrons of charge e and mass m moving with velocity rvec v through a neutral gas under the influence of an applied electric rvec E and magnetic rvec B field. The collision processes which we shall investigate are limited to elastic, inelastic and reactive collisions of electrons with gas molecules. Here we interpret reactive collisions as collisions which produce change in number of the swarm particles. Reactive collisions involve creation (ionization by electron impact) or loss (electron attachment) of swarm particles. We consider only single ionization in approximation of the mass ratio m/m 0 0 are masses of electrons and neutral particles, respectively. We assume that the stage of evolution of the swarm is the hydrodynamic limit (HDL). In HDL, the space - time dependence of all properties is carried by the number density n of swarm particles

  5. Grounded theory approach in sermon analysis of sermons on ...

    African Journals Online (AJOL)

    In this article, I am going to discuss the place of grounded theory in qualitative research and the application of Charmaz's approach to it in homiletics. The process of sermon analysis in its different phases will be discussed as well as the interaction of this bottom-up theory with existing homiletic theories in relation to the ...

  6. The Mayaguez Incident: An Organizational Theory Analysis

    National Research Council Canada - National Science Library

    Lengel, Edward J; Rambo, Charles R; Rodriguez, Shelley A; Tyynismaa, Michael D


    .... Henry Mintzberg's structural contingency model and Lee Bowman and Terrence Deal's frames model within organizational theory are applied to the executive-level decisions made during the operation...

  7. Information Theory Analysis of Cascading Process in a Synthetic Model of Fluid Turbulence

    Directory of Open Access Journals (Sweden)

    Massimo Materassi


    Full Text Available The use of transfer entropy has proven to be helpful in detecting which is the verse of dynamical driving in the interaction of two processes, X and Y . In this paper, we present a different normalization for the transfer entropy, which is capable of better detecting the information transfer direction. This new normalized transfer entropy is applied to the detection of the verse of energy flux transfer in a synthetic model of fluid turbulence, namely the Gledzer–Ohkitana–Yamada shell model. Indeed, this is a fully well-known model able to model the fully developed turbulence in the Fourier space, which is characterized by an energy cascade towards the small scales (large wavenumbers k, so that the application of the information-theory analysis to its outcome tests the reliability of the analysis tool rather than exploring the model physics. As a result, the presence of a direct cascade along the scales in the shell model and the locality of the interactions in the space of wavenumbers come out as expected, indicating the validity of this data analysis tool. In this context, the use of a normalized version of transfer entropy, able to account for the difference of the intrinsic randomness of the interacting processes, appears to perform better, being able to discriminate the wrong conclusions to which the “traditional” transfer entropy would drive.

  8. Water transfers, agriculture, and groundwater management: a dynamic economic analysis. (United States)

    Knapp, Keith C; Weinberg, Marca; Howitt, Richard; Posnikoff, Judith F


    Water transfers from agricultural to urban and environmental uses will likely become increasingly common worldwide. Many agricultural areas rely heavily on underlying groundwater aquifers. Out-of-basin surface water transfers will increase aquifer withdrawals while reducing recharge, thereby altering the evolution of the agricultural production/groundwater aquifer system over time. An empirical analysis is conducted for a representative region in California. Transfers via involuntary surface water cutbacks tilt the extraction schedule and lower water table levels and net benefits over time. The effects are large for the water table but more modest for the other variables. Break-even prices are calculated for voluntary quantity contract transfers at the district level. These prices differ considerably from what might be calculated under a static analysis which ignores water table dynamics. Canal-lining implies that districts may gain in the short-run but lose over time if all the reduction in conveyance losses is transferred outside the district. Water markets imply an evolving quantity of exported flows over time and a reduction in basin net benefits under common property usage. Most aquifers underlying major agricultural regions are currently unregulated. Out-of-basin surface water transfers increase stress on the aquifer and management benefits can increase substantially in percentage terms but overall continue to remain small. Conversely, we find that economically efficient management can mitigate some of the adverse consequences of transfers, but not in many circumstances or by much. Management significantly reduced the water table impacts of cutbacks but not annual net benefit impacts. Neither the break-even prices nor the canal-lining impacts were altered by much. The most significant difference is that regional water users gain from water markets under efficient management.

  9. Variational analysis of regular mappings theory and applications

    CERN Document Server

    Ioffe, Alexander D


    This monograph offers the first systematic account of (metric) regularity theory in variational analysis. It presents new developments alongside classical results and demonstrates the power of the theory through applications to various problems in analysis and optimization theory. The origins of metric regularity theory can be traced back to a series of fundamental ideas and results of nonlinear functional analysis and global analysis centered around problems of existence and stability of solutions of nonlinear equations. In variational analysis, regularity theory goes far beyond the classical setting and is also concerned with non-differentiable and multi-valued operators. The present volume explores all basic aspects of the theory, from the most general problems for mappings between metric spaces to those connected with fairly concrete and important classes of operators acting in Banach and finite dimensional spaces. Written by a leading expert in the field, the book covers new and powerful techniques, whic...

  10. Analytical analysis of the CELIV theory

    Energy Technology Data Exchange (ETDEWEB)

    Lorrmann, Jens; Deibel, Carsten [Experimental Physics VI, Physical Institute, Julius-Maximilians University of Wuerzburg (Germany); Badada, Bekele Homa; Inganaes, Olle [Biomolecular and Organic Electronics, IFM, Linkoeping University (Sweden); Dyakonov, Vladimir [Experimental Physics VI, Physical Institute, Julius-Maximilians University of Wuerzburg (Germany); ZAE Bayern, Div. Functional Materials for Energy Technology, Wuerzburg (Germany)


    Charge extraction by linearly increasing voltage (CELIV) has attracted much interest in organic semiconductor research, due to its feature of measuring charge carrier mobility and density directly and simultaneously. Up to now the theoretical description of this method has been solved for a low mobility approximation only, because the general solution was impeded by a Ricatti type first order differential equation. In this contribution we present the analytical solution for this Ricatti equation, thus completing the analytical framework of the CELIV method. We compare it with the approximated theory and show that especially for standard organic solar cell materials the low mobility approach is hardly valid. The evaluation of photo-CELIV measurements on poly(3-hexyl thiophene-2,5-diyl):[6,6]-phenyl-C{sub 61} butyric acid methyl ester solar cells can then be done by fitting the current transients. Surprisingly the fit results are only in a good agreement with the experimental currents, if two extraction currents are taken into account - the origin of which we will discuss. Furthermore we present a new equation for mobility evaluation from numerical analysis within our framework, which can be applied over the entire experimental range.

  11. Transference system of gaseous fluoride compounds for infrared spectrofotometric analysis

    International Nuclear Information System (INIS)

    Prado, L.


    A vacuum line design for transference of gaseous fluoride compounds involved in the uranium hexafluoride infrared analysis is presented. The text include specific comments about the characteristics of each component and about the possibilities of its acquisition in the national market. (author) [pt

  12. Theory and analysis of partial diallel crosses

    Directory of Open Access Journals (Sweden)

    Viana José Marcelo Soriano


    Full Text Available This study presents theory and analysis of partial diallel crosses based on Hayman's methods. This genetic design consists of crosses among two parental groups. It should be used when there are two groups of parents, for example, dent and flint maize inbred lines, and the breeder is not interested in the assessment of crosses between parents of the same group. Analyses are carried out using data from the parents and their F1 hybrids allowing a detailed characterization of the polygenic systems under study and the choice of parents for hybridization. Diallel analysis allows the estimation of genetic and non-genetic components of variation and genetic parameters and to assess the following: genetic variability in each group; genotypic differences between parents of distinct groups; if a parent has a common or a rare genotype in the group to which it does not belong; if there is dominance; if dominant genes increase or decrease trait expression (direction of dominance; average degree of dominance in each group; the relative importance of mean effects of genes and dominance in determining a trait; if, in each group, the allelic genes have the same frequency; if genes are equally frequent in the two groups; the group with the greatest frequency of favorable genes; the group in which dominant genes are most frequent; the relative number of dominant and recessive genes in each parent; if a parent has a common or a rare genotype in the group to which it belongs, and the genotypic differences between parents of the same group. An example with common bean varieties is considered.

  13. A Critical Analysis of Transactional Distance Theory (United States)

    Gorsky, Paul; Caspi, Avner


    This investigation reviews published empirical studies that attempted to support or to validate transactional distance theory (Moore, 1993). It was found that either data only partially supported the theory or, that if they apparently did so, the studies lacked reliability, construct validity, or both. It was concluded that the basic propositions…

  14. Particle Transfer Reactions with the Time-Dependent Hartree-Fock Theory Using a Particle Number Projection Technique

    International Nuclear Information System (INIS)

    Simenel, Cedric


    A particle-number projection technique is used to calculate transfer probabilities in the 16 O+ 208 Pb reaction below the fusion barrier. The time evolution of the many-body wave function is obtained with the time-dependent Hartree-Fock (TDHF) mean-field theory. The agreement with experimental data for the sum of the proton-transfer channels is good, considering that TDHF has no parameter adjusted on the reaction mechanism. Some perspectives for extensions beyond TDHF to include cluster transfers are discussed.

  15. Organizational Theories and Analysis: A Feminist Perspective (United States)

    Irefin, Peace; Ifah, S. S.; Bwala, M. H.


    This paper is a critique of organization theories and their failure to come to terms with the fact of the reproduction of labour power within a particular form of the division of labour. It examines feminist theory and its aims to understand the nature of inequality and focuses on gender, power relations and sexuality part of the task of feminists which organizational theories have neglected is to offer an account of how the different treatments of the sexes operate in our culture. The paper concludes that gender has been completely neglected within the organizational theory which result in a rhetorical reproduction of males as norms and women as others. It is recommended that only radical form of organization theory can account for the situation of women in organisational setting

  16. Control of pneumatic transfer system for neutron activation analysis

    International Nuclear Information System (INIS)

    Jung, H. S.; Chung, Y. S.; Wu, J. S.; Kim, H. K.; Choi, Y. S.; Kim, S. H.; Moon, J. H.; Baek, S. Y.


    Pneumatic transfer system(PTS) is one of the facilities to be used in irradiation of target materials for neutron activation analysis(NAA) in the research reactor. There are two systems the manual and the automatic system in PTS of HANARO research reactor. The pneumatic transfer system consists of many devices, sends and loads the capsules from NAA laboratory into three holes in the reflector tank of reactor and retrieves irradiated capsules after irradiation. This report describes the part's design, control system and the operation procedures. All the algorithm described in the text will be used for maintenance and upgrading

  17. Control of pneumatic transfer system for neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jung, H. S.; Chung, Y. S.; Wu, J. S.; Kim, H. K.; Choi, Y. S.; Kim, S. H.; Moon, J. H.; Baek, S. Y


    Pneumatic transfer system(PTS) is one of the facilities to be used in irradiation of target materials for neutron activation analysis(NAA) in the research reactor. There are two systems the manual and the automatic system in PTS of HANARO research reactor. The pneumatic transfer system consists of many devices, sends and loads the capsules from NAA laboratory into three holes in the reflector tank of reactor and retrieves irradiated capsules after irradiation. This report describes the part's design, control system and the operation procedures. All the algorithm described in the text will be used for maintenance and upgrading.

  18. Standard Test Method for Calculation of Stagnation Enthalpy from Heat Transfer Theory and Experimental Measurements of Stagnation-Point Heat Transfer and Pressure

    CERN Document Server

    American Society for Testing and Materials. Philadelphia


    1.1 This test method covers the calculation from heat transfer theory of the stagnation enthalpy from experimental measurements of the stagnation-point heat transfer and stagnation pressure. 1.2 Advantages 1.2.1 A value of stagnation enthalpy can be obtained at the location in the stream where the model is tested. This value gives a consistent set of data, along with heat transfer and stagnation pressure, for ablation computations. 1.2.2 This computation of stagnation enthalpy does not require the measurement of any arc heater parameters. 1.3 Limitations and ConsiderationsThere are many factors that may contribute to an error using this type of approach to calculate stagnation enthalpy, including: 1.3.1 TurbulenceThe turbulence generated by adding energy to the stream may cause deviation from the laminar equilibrium heat transfer theory. 1.3.2 Equilibrium, Nonequilibrium, or Frozen State of GasThe reaction rates and expansions may be such that the gas is far from thermodynamic equilibrium. 1.3.3 Noncat...

  19. Analysis of Multidimensional Poverty: Theory and Case Studies ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Analysis of Multidimensional Poverty: Theory and Case Studies. Couverture du livre Analysis of Multidimensional Poverty: Theory and Case Studies. Auteur(s):. Louis-Marie Asselin. Maison(s) d'édition: Springer, CRDI. 18 août 2009. ISBN : 9781441909053. 228 pages. e-ISBN : 9781552504604. Téléchargez le PDF.

  20. "Parallel Leadership in an "Unparallel" World"--Cultural Constraints on the Transferability of Western Educational Leadership Theories across Cultures (United States)

    Goh, Jonathan Wee Pin


    With the global economy becoming more integrated, the issues of cross-cultural relevance and transferability of leadership theories and practices have become increasingly urgent. Drawing upon the concept of parallel leadership in schools proposed by Crowther, Kaagan, Ferguson, and Hann as an example, the purpose of this paper is to examine the…

  1. Modern Theory of Gratings Resonant Scattering: Analysis Techniques and Phenomena

    CERN Document Server

    Sirenko, Yuriy K


    Diffraction gratings are one of the most popular objects of analysis in electromagnetic theory. The requirements of applied optics and microwave engineering lead to many new problems and challenges for the theory of diffraction gratings, which force us to search for new methods and tools for their resolution. In Modern Theory of Gratings, the authors present results of the electromagnetic theory of diffraction gratings that will constitute the base of further development of this theory, which meet the challenges provided by modern requirements of fundamental and applied science. This volume covers: spectral theory of gratings (Chapter 1) giving reliable grounds for physical analysis of space-frequency and space-time transformations of the electromagnetic field in open periodic resonators and waveguides; authentic analytic regularization procedures (Chapter 2) that, in contradistinction to the traditional frequency-domain approaches, fit perfectly for the analysis of resonant wave scattering processes; paramet...

  2. Crustal Seismic Attenuation in Germany Measured with Acoustic Radiative Transfer Theory (United States)

    Gaebler, Peter J.; Eulenfeld, Tom; Wegler, Ulrich


    This work is carried out in the context of the Comprehensive Nuclear-Test-Ban Treaty (CTBT). As part of this treaty a verification regime was introduced to detect, locate and characterize nuclear explosion testings. The study of seismology can provide essential information in the form of broadband waveform recordings for the identification and verification of these critical events. A profound knowledge of the Earth's subsurface between source and receiver is required for a detailed description of the seismic wave field. In addition to underground parameters such as seismic velocity or anisotropy, information about seismic attenuation values of the medium are required. Goal of this study is the creation of a comprehensive model of crustal seismic attenuation in Germany and adjacent areas. Over 20 years of earthquake data from the German Central Seismological Observatory data archive is used to estimate the spatial dependent distribution of seismic intrinsic and scattering attenuation of S-waves for frequencies between 0.5 and 20 Hz. The attenuation models are estimated by fitting synthetic seismogram envelopes calculated with acoustic radiative transfer theory to observed seismogram envelopes. This theory describes the propagation of seismic S-energy under the assumption of multiple isotropic scattering, the crustal structure of the scattering medium is hereby represented by a half-space model. We present preliminary results of the spatial distribution of intrinsic attenuation represented by the absorption path length, as well as of scattering attenuation in terms of the mean free path and compare the outcomes to results from previous studies. Furthermore catalog magnitudes are compared to moment magnitudes estimated during the inversion process. Additionally site amplification factors of the stations are presented.

  3. Modeling of high‐frequency seismic‐wave scattering and propagation using radiative transfer theory (United States)

    Zeng, Yuehua


    This is a study of the nonisotropic scattering process based on radiative transfer theory and its application to the observation of the M 4.3 aftershock recording of the 2008 Wells earthquake sequence in Nevada. Given a wide range of recording distances from 29 to 320 km, the data provide a unique opportunity to discriminate scattering models based on their distance‐dependent behaviors. First, we develop a stable numerical procedure to simulate nonisotropic scattering waves based on the 3D nonisotropic scattering theory proposed by Sato (1995). By applying the simulation method to the inversion of M 4.3 Wells aftershock recordings, we find that a nonisotropic scattering model, dominated by forward scattering, provides the best fit to the observed high‐frequency direct S waves and S‐wave coda velocity envelopes. The scattering process is governed by a Gaussian autocorrelation function, suggesting a Gaussian random heterogeneous structure for the Nevada crust. The model successfully explains the common decay of seismic coda independent of source–station locations as a result of energy leaking from multiple strong forward scattering, instead of backscattering governed by the diffusion solution at large lapse times. The model also explains the pulse‐broadening effect in the high‐frequency direct and early arriving S waves, as other studies have found, and could be very important to applications of high‐frequency wave simulation in which scattering has a strong effect. We also find that regardless of its physical implications, the isotropic scattering model provides the same effective scattering coefficient and intrinsic attenuation estimates as the forward scattering model, suggesting that the isotropic scattering model is still a viable tool for the study of seismic scattering and intrinsic attenuation coefficients in the Earth.

  4. Concept analysis and the building blocks of theory: misconceptions regarding theory development. (United States)

    Bergdahl, Elisabeth; Berterö, Carina M


    The purpose of this article is to discuss the attempts to justify concepts analysis as a way to construct theory - a notion often advocated in nursing. The notion that concepts are the building blocks or threads from which theory is constructed is often repeated. It can be found in many articles and well-known textbooks. However, this notion is seldom explained or defended. The notion of concepts as building blocks has also been questioned by several authors. However, most of these authors seem to agree to some degree that concepts are essential components from which theory is built. Discussion paper. Literature was reviewed to synthesize and debate current knowledge. Our point is that theory is not built by concepts analysis or clarification and we will show that this notion has its basis in some serious misunderstandings. We argue that concept analysis is not a part of sound scientific method and should be abandoned. The current methods of concept analysis in nursing have no foundation in philosophy of science or in language philosophy. The type of concept analysis performed in nursing is not a way to 'construct' theory. Rather, theories are formed by creative endeavour to propose a solution to a scientific and/or practical problem. The bottom line is that the current style and form of concept analysis in nursing should be abandoned in favour of methods in line with modern theory of science. © 2016 John Wiley & Sons Ltd.

  5. Heat transfer and performance analysis of thermoelectric stoves

    International Nuclear Information System (INIS)

    Najjar, Yousef S.H.; Kseibi, Musaab M.


    Highlights: • Design and testing of a thermo electric stove. • Three biofuels namely: wood, peat and manure are used. • Heat transfer analysis is detailed. • Resulting thermoelectric energy for vital purposes in remote poor regions. • Evaluation of performance of the stove subcomponents. - Abstract: Access to electricity is one of the important challenges for remote poor regions of the world. Adding TEG (thermoelectric generators) to stoves can provide electricity for the basic benefits such as: operating radio, light, phones, medical instruments and other small electronic devices. Heat transfer analysis of a multi-purpose stove coupled with 12 TEG modules is presented. This analysis comprises a well aerodynamically designed combustor, finned TEG base plate, cooker and water heater beside the outer surface for space heating. Heat transfer analysis was also carried out for all the subcomponents of the stove, and performance predicted against the experimental results. It was found that the maximum power obtained is about 7.88 W using wood, manure or peat with an average overall efficiency of the stove about 60%.

  6. Experimental sensitivity analysis of oxygen transfer in the capillary fringe. (United States)

    Haberer, Christina M; Cirpka, Olaf A; Rolle, Massimo; Grathwohl, Peter


    Oxygen transfer in the capillary fringe (CF) is of primary importance for a wide variety of biogeochemical processes occurring in shallow groundwater systems. In case of a fluctuating groundwater table two distinct mechanisms of oxygen transfer within the capillary zone can be identified: vertical predominantly diffusive mass flux of oxygen, and mass transfer between entrapped gas and groundwater. In this study, we perform a systematic experimental sensitivity analysis in order to assess the influence of different parameters on oxygen transfer from entrapped air within the CF to underlying anoxic groundwater. We carry out quasi two-dimensional flow-through experiments focusing on the transient phase following imbibition to investigate the influence of the horizontal flow velocity, the average grain diameter of the porous medium, as well as the magnitude and the speed of the water table rise. We present a numerical flow and transport model that quantitatively represents the main mechanisms governing oxygen transfer. Assuming local equilibrium between the aqueous and the gaseous phase, the partitioning process from entrapped air can be satisfactorily simulated. The different experiments are monitored by measuring vertical oxygen concentration profiles at high spatial resolution with a noninvasive optode technique as well as by determining oxygen fluxes at the outlet of the flow-through chamber. The results show that all parameters investigated have a significant effect and determine different amounts of oxygen transferred to the oxygen-depleted groundwater. Particularly relevant are the magnitude of the water table rise and the grain size of the porous medium. © 2013, National Ground Water Association.

  7. Spectral theory and nonlinear analysis with applications to spatial ecology

    CERN Document Server

    Cano-Casanova, S; Mora-Corral , C


    This volume details some of the latest advances in spectral theory and nonlinear analysis through various cutting-edge theories on algebraic multiplicities, global bifurcation theory, non-linear Schrödinger equations, non-linear boundary value problems, large solutions, metasolutions, dynamical systems, and applications to spatial ecology. The main scope of the book is bringing together a series of topics that have evolved separately during the last decades around the common denominator of spectral theory and nonlinear analysis - from the most abstract developments up to the most concrete applications to population dynamics and socio-biology - in an effort to fill the existing gaps between these fields.

  8. Donation and back-donation analyzed through a charge transfer model based on density functional theory. (United States)

    Orozco-Valencia, Ulises; Gázquez, José L; Vela, Alberto


    The net charge transfer process that occurs between two species, A and B, interacting with each other, may be decomposed into two processes: one in which A receives charge from B, which can be identified as the electrophilic channel for A or the nucleophilic channel for B, and a second in which A donates charge to B, which can be identified as the nucleophilic channel for A or the electrophilic channel for B. By determining the amount of charge associated with both processes through the minimization of the interaction energy associated with each case, the expressions for the amount of charge involved in each case can be expressed in terms of the directional chemical potentials and the hardnesses of the interacting species. The correlation between the charges obtained for the interaction between phosphine ligands of the type PRR'R'' and Ni, and the A 1 carbonyl stretching frequency provides support for their interpretation as measures of the electrophilicity and nucleophilicity of a chemical species, and, at the same time, allows one to describe the donation and back-donation processes in terms of the density functional theory of chemical reactivity.

  9. Mean-deviation analysis in the theory of choice. (United States)

    Grechuk, Bogdan; Molyboha, Anton; Zabarankin, Michael


    Mean-deviation analysis, along with the existing theories of coherent risk measures and dual utility, is examined in the context of the theory of choice under uncertainty, which studies rational preference relations for random outcomes based on different sets of axioms such as transitivity, monotonicity, continuity, etc. An axiomatic foundation of the theory of coherent risk measures is obtained as a relaxation of the axioms of the dual utility theory, and a further relaxation of the axioms are shown to lead to the mean-deviation analysis. Paradoxes arising from the sets of axioms corresponding to these theories and their possible resolutions are discussed, and application of the mean-deviation analysis to optimal risk sharing and portfolio selection in the context of rational choice is considered. © 2012 Society for Risk Analysis.

  10. Network reliability analysis based on percolation theory

    International Nuclear Information System (INIS)

    Li, Daqing; Zhang, Qiong; Zio, Enrico; Havlin, Shlomo; Kang, Rui


    In this paper, we propose a new way of looking at the reliability of a network using percolation theory. In this new view, a network failure can be regarded as a percolation process and the critical threshold of percolation can be used as network failure criterion linked to the operational settings under control. To demonstrate our approach, we consider both random network models and real networks with different nodes and/or edges lifetime distributions. We study numerically and theoretically the network reliability and find that the network reliability can be solved as a voting system with threshold given by percolation theory. Then we find that the average lifetime of random network increases linearly with the average lifetime of its nodes with uniform life distributions. Furthermore, the average lifetime of the network becomes saturated when system size is increased. Finally, we demonstrate our method on the transmission network system of IEEE 14 bus. - Highlights: • Based on percolation theory, we address questions of practical interest such as “how many failed nodes/edges will break down the whole network?” • The percolation threshold naturally gives a network failure criterion. • The approach based on percolation theory is suited for calculations of large-scale networks

  11. Multi-scale symbolic transfer entropy analysis of EEG (United States)

    Yao, Wenpo; Wang, Jun


    From both global and local perspectives, we symbolize two kinds of EEG and analyze their dynamic and asymmetrical information using multi-scale transfer entropy. Multi-scale process with scale factor from 1 to 199 and step size of 2 is applied to EEG of healthy people and epileptic patients, and then the permutation with embedding dimension of 3 and global approach are used to symbolize the sequences. The forward and reverse symbol sequences are taken as the inputs of transfer entropy. Scale factor intervals of permutation and global way are (37, 57) and (65, 85) where the two kinds of EEG have satisfied entropy distinctions. When scale factor is 67, transfer entropy of the healthy and epileptic subjects of permutation, 0.1137 and 0.1028, have biggest difference. And the corresponding values of the global symbolization is 0.0641 and 0.0601 which lies in the scale factor of 165. Research results show that permutation which takes contribution of local information has better distinction and is more effectively applied to our multi-scale transfer entropy analysis of EEG.

  12. Critical analysis of leadership theory in “American Sniper”

    Directory of Open Access Journals (Sweden)

    Brad C. Wedlock


    Full Text Available This analysis examined the film “American Sniper” and identified five leadership theories/approaches that were represented by the leading actor. These theories and approaches were classified as the following: trait approach, skills approach, style approach, situational approach, and path-goal theory. Being military themed, this film falls into the areas of dedication, sacrifice, and moral ethics, which are considered major capacities of the leadership paradigm.

  13. Critical analysis of leadership theory in “American Sniper”


    Brad C. Wedlock


    This analysis examined the film “American Sniper” and identified five leadership theories/approaches that were represented by the leading actor. These theories and approaches were classified as the following: trait approach, skills approach, style approach, situational approach, and path-goal theory. Being military themed, this film falls into the areas of dedication, sacrifice, and moral ethics, which are considered major capacities of the leadership paradigm.

  14. Deep Learning in Intermediate Microeconomics: Using Scaffolding Assignments to Teach Theory and Promote Transfer (United States)

    Green, Gareth P.; Bean, John C.; Peterson, Dean J.


    Intermediate microeconomics is typically viewed as a theory and tools course that relies on algorithmic problems to help students learn and apply economic theory. However, the authors' assessment research suggests that algorithmic problems by themselves do not encourage students to think about where the theory comes from, why the theory is…

  15. Analyzing availability using transfer function models and cross spectral analysis

    International Nuclear Information System (INIS)

    Singpurwalla, N.D.


    The paper shows how the methods of multivariate time series analysis can be used in a novel way to investigate the interrelationships between a series of operating (running) times and a series of maintenance (down) times of a complex system. Specifically, the techniques of cross spectral analysis are used to help obtain a Box-Jenkins type transfer function model for the running times and the down times of a nuclear reactor. A knowledge of the interrelationships between the running times and the down times is useful for an evaluation of maintenance policies, for replacement policy decisions, and for evaluating the availability and the readiness of complex systems


    Directory of Open Access Journals (Sweden)

    RAUCHOVÁ, Tereza


    Full Text Available Texts are an important way to share and transfer knowledge. In this paper we analyse the impact of a specific form of texts, so called “knowledge texts”, on the efficiency of knowledge transfer. The objective is to verify or reject several hypotheses on the relationships among the style of educational texts (standard or knowledge styles, learning outcomes (performance of the students after learning and subjective evaluation of conformity of working with individual styles of the texts. For this purpose, we carry out experiment with a homogeneous group of the students (n = 41 divided into an experimental group and a control group. We use statistical methods to process the results of the experiments; ability of the students to solve specific tasks and their opinions on readability and understandability of the texts subject to the time spent for learning. Even if we determine statistically significant relationships between the style of texts and accuracy of the problem solving in the experimental group only, the results allow us to improve the experiment and apply the methodology developed in a less structured branch than the Operational Research (Graph Theory is. The methodology is another benefit of the paper, because it can be applied independently on a particular domain.

  17. Finite element analysis theory and application with ANSYS

    CERN Document Server

    Moaveni, Saeed


    For courses in Finite Element Analysis, offered in departments of Mechanical or Civil and Environmental Engineering. While many good textbooks cover the theory of finite element modeling, Finite Element Analysis: Theory and Application with ANSYS is the only text available that incorporates ANSYS as an integral part of its content. Moaveni presents the theory of finite element analysis, explores its application as a design/modeling tool, and explains in detail how to use ANSYS intelligently and effectively. Teaching and Learning Experience This program will provide a better teaching and learning experience-for you and your students. It will help: *Present the Theory of Finite Element Analysis: The presentation of theoretical aspects of finite element analysis is carefully designed not to overwhelm students. *Explain How to Use ANSYS Effectively: ANSYS is incorporated as an integral part of the content throughout the book. *Explore How to Use FEA as a Design/Modeling Tool: Open-ended design problems help stude...

  18. Symmetry analysis for anisotropic field theories

    International Nuclear Information System (INIS)

    Parra, Lorena; Vergara, J. David


    The purpose of this paper is to study with the help of Noether's theorem the symmetries of anisotropic actions for arbitrary fields which generally depend on higher order spatial derivatives, and to find the corresponding current densities and the Noether charges. We study in particular scale invariance and consider the cases of higher derivative extensions of the scalar field, electrodynamics and Chern-Simons theory.

  19. Theory analysis of the Dental Hygiene Human Needs Conceptual Model. (United States)

    MacDonald, L; Bowen, D M


    Theories provide a structural knowing about concept relationships, practice intricacies, and intuitions and thus shape the distinct body of the profession. Capturing ways of knowing and being is essential to any professions' practice, education and research. This process defines the phenomenon of the profession - its existence or experience. Theory evaluation is a systematic criterion-based assessment of a specific theory. This study presents a theory analysis of the Dental Hygiene Human Needs Conceptual Model (DH HNCM). Using the Walker and Avant Theory Analysis, a seven-step process, the DH HNCM, was analysed and evaluated for its meaningfulness and contribution to dental hygiene. The steps include the following: (i) investigate the origins; (ii) examine relationships of the theory's concepts; (iii) assess the logic of the theory's structure; (iv) consider the usefulness to practice; (v) judge the generalizability; (vi) evaluate the parsimony; and (vii) appraise the testability of the theory. Human needs theory in nursing and Maslow's Hierarchy of Need Theory prompted this theory's development. The DH HNCM depicts four concepts based on the paradigm concepts of the profession: client, health/oral health, environment and dental hygiene actions, and includes validated eleven human needs that evolved overtime to eight. It is logical, simplistic, allows scientific predictions and testing, and provides a unique lens for the dental hygiene practitioner. With this model, dental hygienists have entered practice, knowing they enable clients to meet their human needs. For the DH HNCM, theory analysis affirmed that the model is reasonable and insightful and adds to the dental hygiene professions' epistemology and ontology. © 2016 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  20. The transient heat transfer analysis of solids with radiative boundary condition using finite element analysis

    International Nuclear Information System (INIS)

    Reddy, B.S.; Sharan, A.M.


    The heat transfer process in some of the metallurgical processes is quite involved; for example, during the cooling of castings or heating of ingots before forging. These castings or ingots can be very complicated shapes. Therefore, the solution of heat transfer problems by exact methods is not possible. In such situations, the heat transfer process is studied either by finite difference or finite element method. The heat transfer process in this problem involves all the three modes of heat transfer which are: the conduction, convection and radiation. In this paper, the equations for the heat transfer process of a solid subjected to nonlinear boundary conditions using the finite element analysis have been derived. Then, these equations are solved using the Gauss-Seidel iteration technique. (author)

  1. Rigorous theory of graded thermoelectric converters including finite heat transfer coefficients (United States)

    Gerstenmaier, York Christian; Wachutka, Gerhard


    Maximization of thermoelectric (TE) converter performance with an inhomogeneous material and electric current distribution has been investigated in previous literature neglecting thermal contact resistances to the heat reservoirs. The heat transfer coefficients (HTCs), defined as inverse thermal contact resistances per unit area, are thus infinite, whereas in reality, always parasitic thermal resistances, i.e., finite HTCs, are present. Maximization of the generated electric power and of cooling power in the refrigerator mode with respect to Seebeck coefficients and heat conductivity for a given profile of the material's TE figure of merit Z are mathematically ill-posed problems in the presence of infinite HTCs. As will be shown in this work, a fully self consistent solution is possible for finite HTCs, and in many respects, the results are fundamentally different. A previous theory for 3D devices will be extended to include finite HTCs and is applied to 1D devices. For the heat conductivity profile, an infinite number of solutions exist leading to the same device performance. Cooling power maximization for finite HTCs in 1D will lead to a strongly enhanced corresponding efficiency (coefficient of performance), whereas results with infinite HTCs lead to a non-monotonous temperature profile and coefficient of performance tending to zero for the prescribed heat conductivities. For maximized generated electric power, the corresponding generator efficiency is nearly a constant independent from the finite HTC values. The maximized efficiencies in the generator and cooling mode are equal to the efficiencies for the infinite HTC, provided that the corresponding powers approach zero. These and more findings are condensed in 4 theorems in the conclusions.

  2. Spectral analysis and filter theory in applied geophysics

    CERN Document Server

    Buttkus, Burkhard


    This book is intended to be an introduction to the fundamentals and methods of spectral analysis and filter theory and their appli­ cations in geophysics. The principles and theoretical basis of the various methods are described, their efficiency and effectiveness eval­ uated, and instructions provided for their practical application. Be­ sides the conventional methods, newer methods arediscussed, such as the spectral analysis ofrandom processes by fitting models to the ob­ served data, maximum-entropy spectral analysis and maximum-like­ lihood spectral analysis, the Wiener and Kalman filtering methods, homomorphic deconvolution, and adaptive methods for nonstation­ ary processes. Multidimensional spectral analysis and filtering, as well as multichannel filters, are given extensive treatment. The book provides a survey of the state-of-the-art of spectral analysis and fil­ ter theory. The importance and possibilities ofspectral analysis and filter theory in geophysics for data acquisition, processing an...

  3. Gaussian-beam-propagation theory for nonlinear optics involving an analytical treatment of orbital-angular-momentum transfer (United States)

    Lanning, R. Nicholas; Xiao, Zhihao; Zhang, Mi; Novikova, Irina; Mikhailov, Eugeniy E.; Dowling, Jonathan P.


    We present a general, Gaussian spatial-mode propagation formalism for describing the generation of higher-order multi-spatial-mode beams generated during nonlinear interactions. Furthermore, to implement the theory, we simulate optical angular momentum transfer interactions and show how one can optimize the interaction to reduce the undesired modes. Past theoretical treatments of this problem have often been phenomenological, at best. Here we present an exact solution for the single-pass no-cavity regime, in which the nonlinear interaction is not overly strong. We apply our theory to two experiments, with very good agreement, and give examples of several more configurations, easily tested in the laboratory.

  4. A modified principal component analysis-based utility theory ...

    African Journals Online (AJOL)


    modified PCA-based utility theory (UT) approach for optimization of correlated responses. ... Keywords: EDM; Correlated responses; Optimization; Principal component analysis; Proportion of quality loss reduction; ...... On stochastic optimization: Taguchi MethodsTM demystified; its limitations and fallacy clarified.

  5. An Integrated Theory of Discourse Analysis, (United States)


    N, *"J*.*~~~ ~ . .,N. L. ;4 With the sentences in (5) we see what is called " pragmatic presupposition". By the - use of the aspectual modifying verb...Strawson’s theory, this translates to the lack of a truth-value for this statement). There are two other types of pragmatic presuppostions that should Wcbber (1979) and Grosz (1978, 1981) was aimed at identifying the contexts within which discourse anaphora was licensed. The of focus and topic was

  6. A First-Order Analytical Theory for Optimal Low-Thrust Limited-Power Transfers between Arbitrary Elliptical Coplanar Orbits

    Directory of Open Access Journals (Sweden)

    Sandro da Silva Fernandes


    Full Text Available A complete first-order analytical solution, which includes the short periodic terms, for the problem of optimal low-thrust limited-power transfers between arbitrary elliptic coplanar orbits in a Newtonian central gravity field is obtained through canonical transformation theory. The optimization problem is formulated as a Mayer problem of optimal control theory with Cartesian elements—position and velocity vectors—as state variables. After applying the Pontryagin maximum principle and determining the maximum Hamiltonian, classical orbital elements are introduced through a Mathieu transformation. The short periodic terms are then eliminated from the maximum Hamiltonian through an infinitesimal canonical transformation built through Hori method. Closed-form analytical solutions are obtained for the average canonical system by solving the Hamilton-Jacobi equation through separation of variables technique. For transfers between close orbits a simplified solution is straightforwardly derived by linearizing the new Hamiltonian and the generating function obtained through Hori method.

  7. CFD simulation of direct contact condensation with ANSYS CFX using surface renewal theory based heat transfer coefficients

    Energy Technology Data Exchange (ETDEWEB)

    Wanninger, Andreas; Ceuca, Sabin Cristian; Macian-Juan, Rafael [Technische Univ. Muenchen, Garching (Germany). Dept. of Nuclear Engineering


    Different approaches for the calculation of Direct Contact Condensation (DCC) using Heat Transfer Coefficients (HTC) based on the Surface Renewal Theory (SRT) are tested using the CFD simulation tool ANSYS CFX. The present work constitutes a preliminary study of the flow patterns and conditions observed using different HTC models. A complex 3D flow pattern will be observed in the CFD simulations as well as a strong coupling between the condensation rate and the two-phase flow dynamics. (orig.)

  8. Numerical Analysis of Heat Transfer During Quenching Process (United States)

    Madireddi, Sowjanya; Krishnan, Krishnan Nambudiripad; Reddy, Ammana Satyanarayana


    A numerical model is developed to simulate the immersion quenching process of metals. The time of quench plays an important role if the process involves a defined step quenching schedule to obtain the desired characteristics. Lumped heat capacity analysis used for this purpose requires the value of heat transfer coefficient, whose evaluation requires large experimental data. Experimentation on a sample work piece may not represent the actual component which may vary in dimension. A Fluid-Structure interaction technique with a coupled interface between the solid (metal) and liquid (quenchant) is used for the simulations. Initial times of quenching shows boiling heat transfer phenomenon with high values of heat transfer coefficients (5000-2.5 × 105 W/m2K). Shape of the work piece with equal dimension shows less influence on the cooling rate Non-uniformity in hardness at the sharp corners can be reduced by rounding off the edges. For a square piece of 20 mm thickness, with 3 mm fillet radius, this difference is reduced by 73 %. The model can be used for any metal-quenchant combination to obtain time-temperature data without the necessity of experimentation.

  9. Comparison of alpha decay and alpha transfer reactions in the lead region. [R matrix theory, absolute alpha widths, cross sections, 93 MeV

    Energy Technology Data Exchange (ETDEWEB)

    DeVries, R.M.


    Data were taken for five transitions in the lead region allowing a quantitative comparison with corresponding alpha-decay data via R-matrix theory using the same target + alpha nuclear potential. Good agreement between the absolute reduced widths determined from the two sets of data suggests that in transfer reactions, as in alpha decay, an alpha particle in its ground state is transferred in a one-step process. In a separate analysis, elastic and total reaction cross sections for the systems ..cap alpha.. + /sup 208/Pb, /sup 209/Bi were analyzed to obtain a limited set of potentials which, in turn, were used to calculate absolute alpha widths. Existing shell model calculations give ..gamma../sub ..cap alpha..//sup 2/ values three orders of magnitude smaller.

  10. Comparison of electron-ion energy transfer in dense plasmas obtained from numerical simulations and quantum kinetic theory (United States)

    Vorberger, J.; Gericke, D. O.


    We evaluate various analytical models for the electron-ion energy transfer and compare the results to data from molecular dynamics (MD) simulations. The models tested include energy transfer via strong binary collisions, Landau-Spitzer rates with different choices for the cut-off parameters in the Coulomb logarithm, rates based on Fermi's golden rule (FGR) and theories taking coupled collective modes (CM) into account. In search of a model easy to apply, we first analyze different approximations of the FGR energy transfer rate. Then, we investigate several numerical studies using MD simulations and try to uncover CM effects in the data obtained. Most MD data published so far, except one study by Murillo et al. [23], show no distinct CM effects and, thus, can be interpreted within a FGR or binary collision approach. We show that this finding is related to the parameter regime, in particular the initial temperature difference, considered in these investigations.

  11. Analysis of transferred fragrance and its forensic implications. (United States)

    Gherghel, Simona; Morgan, Ruth M; Blackman, Christopher S; Karu, Kersti; Parkin, Ivan P


    Perfumes are widely used by many people in developed countries, and a large number of both men and women wear perfumes on a daily basis. Analysis of perfume trace materials from clothing is not commonly employed within forensic casework, yet as a form of trace evidence it has the potential to provide valuable intelligence. In order to appreciate the value of trace evidence there is a fundamental need for an evidence base that can both offer insight into how a trace material behaves under different scenarios and activities, and from which inferences can be made. With this purpose a gas chromatography-mass spectrometry method for trace analysis of perfumes was developed. This paper presents two different series of experiments that investigate the dynamics of perfume transfer as a factor of perfume ageing time, and as a factor of perfume contact time. Empirical data showed that both perfume ageing time, and perfume contact time play a key role in the number of perfume components transferred. These studies have implication for forensic protocols, specifically for perfume trace evidence collection, analysis, interpretation, and presentation, and there is potentially great value in analysing perfumes from clothing exhibits in forensic enquiries that involve close contact between individuals, such as sexual assaults. Copyright © 2016 The Authors. Published by Elsevier Ireland Ltd.. All rights reserved.

  12. Transferring Literacy Skills from L1 to L2: From Theory to Practice. (United States)

    Roberts, Cheryl A.


    Definitions of literacy are discussed, and research related to the transfer of literacy skills is reviewed. Some practical applications of research findings are suggested. (Contains 32 references.) (LB)

  13. Advanced Wireless Power Transfer Vehicle and Infrastructure Analysis (Presentation)

    Energy Technology Data Exchange (ETDEWEB)

    Gonder, J.; Brooker, A.; Burton, E.; Wang, J.; Konan, A.


    This presentation discusses current research at NREL on advanced wireless power transfer vehicle and infrastructure analysis. The potential benefits of E-roadway include more electrified driving miles from battery electric vehicles, plug-in hybrid electric vehicles, or even properly equipped hybrid electric vehicles (i.e., more electrified miles could be obtained from a given battery size, or electrified driving miles could be maintained while using smaller and less expensive batteries, thereby increasing cost competitiveness and potential market penetration). The system optimization aspect is key given the potential impact of this technology on the vehicles, the power grid and the road infrastructure.

  14. [A new calibration transfer method based on target factor analysis]. (United States)

    Wang, Yan-bin; Yuan, Hong-fu; Lu, Wan-zhen


    A new calibration transfer method based on target factor analysis is proposed.The performance of the new method compared with the piecewise direct standardization method. This method was applied to two data sets, of which one is a simulation data set, and the other is an NIR data set composed of benzene, toluene, xylene and isooctane. The results obtained with this new method are at least as well as those obtained by PDS with the biggest improvement occurring when the spectra have some non-linear responses.

  15. Effective field theory analysis of Higgs naturalness

    Energy Technology Data Exchange (ETDEWEB)

    Bar-Shalom, Shaouly [Technion-Israel Inst. of Tech., Haifa (Israel); Soni, Amarjit [Brookhaven National Lab. (BNL), Upton, NY (United States); Wudka, Jose [Univ. of California, Riverside, CA (United States)


    Assuming the presence of physics beyond the Standard Model ( SM) with a characteristic scale M ~ O (10) TeV, we investigate the naturalness of the Higgs sector at scales below M using an effective field theory (EFT) approach. We obtain the leading 1 -loop EFT contributions to the Higgs mass with a Wilsonian-like hard cutoff, and determine t he constraints on the corresponding operator coefficients for these effects to alleviate the little hierarchy problem up to the scale of the effective action Λ < M , a condition we denote by “EFT-naturalness”. We also determine the types of physics that can lead to EFT-naturalness and show that these types of new physics are best probed in vector-boson and multiple-Higgs production. The current experimental constraints on these coefficients are also discussed.

  16. Kinematic analysis of parallel manipulators by algebraic screw theory

    CERN Document Server

    Gallardo-Alvarado, Jaime


    This book reviews the fundamentals of screw theory concerned with velocity analysis of rigid-bodies, confirmed with detailed and explicit proofs. The author additionally investigates acceleration, jerk, and hyper-jerk analyses of rigid-bodies following the trend of the velocity analysis. With the material provided in this book, readers can extend the theory of screws into the kinematics of optional order of rigid-bodies. Illustrative examples and exercises to reinforce learning are provided. Of particular note, the kinematics of emblematic parallel manipulators, such as the Delta robot as well as the original Gough and Stewart platforms are revisited applying, in addition to the theory of screws, new methods devoted to simplify the corresponding forward-displacement analysis, a challenging task for most parallel manipulators. Stands as the only book devoted to the acceleration, jerk and hyper-jerk (snap) analyses of rigid-body by means of screw theory; Provides new strategies to simplify the forward kinematic...

  17. Thermal analysis of isotropic plates using hyperbolic shear deformation theory

    Directory of Open Access Journals (Sweden)

    Shinde B.M.


    Full Text Available In this paper, thermal analysis of a thick isotropic rectangular plate is carried out using the hyperbolic shear deformation theory (HYSDT. The displacement field of the theory contains three variables. The hyperbolic sine and cosine functions are used in the displacement field in-terms of thickness coordinate to represent the effect of shear deformation. The most important feature of the theory is that, the transverse shear stresses can be obtained directly from the use of constitutive relations, hence the theory does not need shear correction factor. The theory accounts for parabolic distribution of transverse shear stresses across the thickness satisfying the stress free boundary conditions at top and bottom surfaces of the plate. Governing differential equations and boundary conditions of the theory are obtained using the principle of virtual work. The results obtained for bending analysis of isotropic plates subjected to uniformly distributed thermal load are compared with those obtained by other theories, to validate the accuracy of the presented theory.

  18. On uncertainty and local sensitivity analysis for transient conjugate heat transfer problems

    International Nuclear Information System (INIS)

    Rauch, Christian


    The need for simulating real-world behavior of automobiles has led to more and more sophisticated models being added of various physical phenomena for being coupled together. This increases the number of parameters to be set and, consequently, the required knowledge of their relative importance for the solution and the theory behind them. Sensitivity and uncertainty analysis provides the knowledge of parameter importance. In this paper a thermal radiation solver is considered that performs conduction calculations and receives heat transfer coefficient and fluid temperate at a thermal node. The equations of local, discrete, and transient sensitivities for the conjugate heat transfer model solved by the finite difference method are being derived for some parameters. In the past, formulations for the finite element method have been published. This paper builds on the steady-state formulation published previously by the author. A numerical analysis on the stability of the solution matrix is being conducted. From those normalized sensitivity coefficients are calculated dimensionless uncertainty factors. On a simplified example the relative importance of the heat transfer modes at various locations is then investigated by those uncertainty factors and their changes over time

  19. Combined Heat Transfer in High-Porosity High-Temperature Fibrous Insulations: Theory and Experimental Validation (United States)

    Daryabeigi, Kamran; Cunnington, George R.; Miller, Steve D.; Knutson, Jeffry R.


    Combined radiation and conduction heat transfer through various high-temperature, high-porosity, unbonded (loose) fibrous insulations was modeled based on first principles. The diffusion approximation was used for modeling the radiation component of heat transfer in the optically thick insulations. The relevant parameters needed for the heat transfer model were derived from experimental data. Semi-empirical formulations were used to model the solid conduction contribution of heat transfer in fibrous insulations with the relevant parameters inferred from thermal conductivity measurements at cryogenic temperatures in a vacuum. The specific extinction coefficient for radiation heat transfer was obtained from high-temperature steady-state thermal measurements with large temperature gradients maintained across the sample thickness in a vacuum. Standard gas conduction modeling was used in the heat transfer formulation. This heat transfer modeling methodology was applied to silica, two types of alumina, and a zirconia-based fibrous insulation, and to a variation of opacified fibrous insulation (OFI). OFI is a class of insulations manufactured by embedding efficient ceramic opacifiers in various unbonded fibrous insulations to significantly attenuate the radiation component of heat transfer. The heat transfer modeling methodology was validated by comparison with more rigorous analytical solutions and with standard thermal conductivity measurements. The validated heat transfer model is applicable to various densities of these high-porosity insulations as long as the fiber properties are the same (index of refraction, size distribution, orientation, and length). Furthermore, the heat transfer data for these insulations can be obtained at any static pressure in any working gas environment without the need to perform tests in various gases at various pressures.

  20. Heat Transfer Analysis in Wire Bundles for Aerospace Vehicles (United States)

    Rickman, S. L.; Iamello, C. J.


    Design of wiring for aerospace vehicles relies on an understanding of "ampacity" which refers to the current carrying capacity of wires, either, individually or in wire bundles. Designers rely on standards to derate allowable current flow to prevent exceedance of wire temperature limits due to resistive heat dissipation within the wires or wire bundles. These standards often add considerable margin and are based on empirical data. Commercial providers are taking an aggressive approach to wire sizing which challenges the conventional wisdom of the established standards. Thermal modelling of wire bundles may offer significant mass reduction in a system if the technique can be generalized to produce reliable temperature predictions for arbitrary bundle configurations. Thermal analysis has been applied to the problem of wire bundles wherein any or all of the wires within the bundle may carry current. Wire bundles present analytical challenges because the heat transfer path from conductors internal to the bundle is tortuous, relying on internal radiation and thermal interface conductance to move the heat from within the bundle to the external jacket where it can be carried away by convective and radiative heat transfer. The problem is further complicated by the dependence of wire electrical resistivity on temperature. Reduced heat transfer out of the bundle leads to higher conductor temperatures and, hence, increased resistive heat dissipation. Development of a generalized wire bundle thermal model is presented and compared with test data. The steady state heat balance for a single wire is derived and extended to the bundle configuration. The generalized model includes the effects of temperature varying resistance, internal radiation and thermal interface conductance, external radiation and temperature varying convective relief from the free surface. The sensitivity of the response to uncertainties in key model parameters is explored using Monte Carlo analysis.

  1. Film scoring today - Theory, practice and analysis


    Flach, Paula Sophie


    This thesis considers film scoring by taking a closer look at the theoretical discourse throughout the last decades, examining current production practice of film music and showcasing a musical analysis of the film Inception (2010).

  2. All-Atom Multiscale Molecular Dynamics Theory and Simulation of Self-Assembly, Energy Transfer and Structural Transition in Nanosystems (United States)

    Espinosa Duran, John Michael

    The study of nanosystems and their emergent properties requires the development of multiscale computational models, theories and methods that preserve atomic and femtosecond resolution, to reveal details that cannot be resolved experimentally today. Considering this, three long time scale phenomena were studied using molecular dynamics and multiscale methods: self-assembly of organic molecules on graphite, energy transfer in nanosystems, and structural transition in vault nanoparticles. Molecular dynamics simulations of the self-assembly of alkoxybenzonitriles with different tail lengths on graphite were performed to learn about intermolecular interactions and phases exhibited by self-organized materials. This is important for the design of ordered self-assembled organic photovoltaic materials with greater efficiency than the disordered blends. Simulations revealed surface dynamical behaviors that cannot be resolved experimentally today due to the lack of spatiotemporal resolution. Atom-resolved structures predicted by simulations agreed with scanning tunneling microscopy images and unit cell measurements. Then, a multiscale theory based on the energy density as a field variable is developed to study energy transfer in nanoscale systems. For applications like photothermal microscopy or cancer phototherapy is required to understand how the energy is transferred to/from nanosystems. This multiscale theory could be applied in this context and here is tested for cubic nanoparticles immersed in water for energy being transferred to/from the nanoparticle. The theory predicts the energy transfer dynamics and reveals phenomena that cannot be described by current phenomenological theories. Finally, temperature-triggered structural transitions were revealed for vault nanoparticles using molecular dynamics and multiscale simulations. Vault is a football-shaped supramolecular assembly very distinct from the commonly observed icosahedral viruses. It has very promising

  3. Caring theory and practice--entering a simultaneous concept analysis. (United States)

    Ranheim, Albertine; Kärner, Anita; Berterö, Carina


    To better understand the approach of caring in nursing and the role of theory in practice, we wanted to consolidate the caring theory of Watson with the empirical findings from the three studies performed to reveal nurses' caring intentions and their lived experience of reflecting caring theory in practice. Through a simultaneous concept analysis of nine concepts, caring science theory was consolidated with the findings of the three empirical studies to reveal the dynamics of caring theory and caring practice. These nine concepts were found to be interrelated with the advanced concept of mediating care, which emphasizes that mediating care calls for an authenticity of being and ability--an ability to be present to self and others in the dynamism of openness and frames of thought. © 2012 Wiley Periodicals, Inc.

  4. Analysis and evaluation of the moral distress theory. (United States)

    Wilson, Melissa A


    Moral distress is a pervasive problem in nursing resulting in a detriment to patient care, providers, and organizations. Over a decade ago, the moral distress theory (MDT) was proposed and utilized in multiple research studies. This middle range theory explains and predicts the distress that occurs in a nurse because of moral conflict. The research findings born from this theory have been substantial. Since inception of this theory, moral distress has been extensively examined which has further elaborated its understanding. This paper provides an analysis and evaluation of the MDT according to applicable guidelines. Current understanding of the phenomenon indicates that a new theory may be warranted to better predict, treat, and manage moral distress. © 2017 Wiley Periodicals, Inc.

  5. The heat transfer analysis of the first stage blade

    International Nuclear Information System (INIS)

    Hong, Yong Ju; Choi, Bum Seog; Park, Byung Gyu; Yoon, Eui Soo


    To get higher efficiency of gas turbine, the designer should have more higher Turbine Inlet Temperature(TIT). Today, modern gas turbine having sophisticated cooling scheme has TIT above 1,700 .deg. C. In the Korea, many gas turbine having TIT above 1,300 .deg. C was imported and being operated, but the gas with high TIT above 1,300 .deg. C in the turbine will give damage to liner of combustor, and blade of turbine and etc. So frequently maintenance for parts enduring high temperature was performed. In this study, the heat transfer analysis of cooling air in the internal cooling channel (network analysis) and temperature analysis of the blade (Finite Element Analysis) in the first stage rotor was conducted for development of the optimal cooling passage design procedure. The results of network analysis and FEM analysis of blade show that the high temperature spot are occurred at the leading edge, trailing edge near tip, and platform. So to get more reliable performance of gas turbine, the more efficient cooling method should be applied at the leading edge and tip section and the thermal barrier coating on the blade surface has important role in cooling blade

  6. Effective field theory analysis of Higgs naturalness (United States)

    Bar-Shalom, Shaouly; Soni, Amarjit; Wudka, Jose


    Assuming the presence of physics beyond the Standard Model (SM) with a characteristic scale M ˜O (10 ) TeV , we investigate the naturalness of the Higgs sector at scales below M using an effective field theory (EFT) approach. We obtain the complete set of higher-dimensional effective operators (at any dimension n ≥5 ) that give the leading one-loop EFT contributions to the Higgs mass with a Wilsonian-like hard cutoff and discuss the (fine-) tuning between these terms and the SM one-loop contribution, which is required in order to alleviate the little hierarchy problem. We then show that this tuning can be translated into a condition for naturalness in the underlying new physics, a condition we denote by "EFT naturalness" and which we express as constraints on the corresponding higher-dimensional operator coefficients up to the scale of the effective action Λ

  7. Studying Policy Transfer through the Lens of Social Network Analysis

    DEFF Research Database (Denmark)

    Staunæs, Dorthe; Brøgger, Katja; Steiner-Khamsi, Gita

    Studying Policy Transfer through the Lens of Social Network Analysis The panelists present the findings of a joint empirical research project carried out at Aarhus University (DPU/Copenhagen) and at Teachers College, Columbia University (New York). The research project succeeded to identify...... discursive networks of political stakeholders and policy advisors that were considered key actors in the Danish school reform. The research team investigated how these networks interrelate, change over time, and represent different constituents (government, academe, business), at times contradicting...... or collaborating with each other, respectively. Against the backdrop of globalization studies in comparative education, the research project attempted to identify borrowers, translators, and brokers of educational reform drawing on a complementary set of expertise from social network analysis methodology (Oren...

  8. Analysis of room transfer function and reverberant signal statistics

    DEFF Research Database (Denmark)

    Georganti, Eleftheria; Mourjopoulos, John; Jacobsen, Finn


    For some time now, statistical analysis has been a valuable tool in analyzing room transfer functions (RTFs). This work examines existing statistical time-frequency models and techniques for RTF analysis (e.g., Schroeder's stochastic model and the standard deviation over frequency bands for the RTF...... smoothing (e.g., as in complex smoothing) with respect to the original RTF statistics. More specifically, the RTF statistics, derived after the complex smoothing calculation, are compared to the original statistics across space inside typical rooms, by varying the source, the receiver position...... and the corresponding ratio of the direct and reverberant signal. In addition, this work examines the statistical quantities for speech and audio signals prior to their reproduction within rooms and when recorded in rooms. Histograms and other statistical distributions are used to compare RTF minima of typical...

  9. Recurrence quantification analysis theory and best practices

    CERN Document Server

    Jr, Jr; Marwan, Norbert


    The analysis of recurrences in dynamical systems by using recurrence plots and their quantification is still an emerging field.  Over the past decades recurrence plots have proven to be valuable data visualization and analysis tools in the theoretical study of complex, time-varying dynamical systems as well as in various applications in biology, neuroscience, kinesiology, psychology, physiology, engineering, physics, geosciences, linguistics, finance, economics, and other disciplines.   This multi-authored book intends to comprehensively introduce and showcase recent advances as well as established best practices concerning both theoretical and practical aspects of recurrence plot based analysis.  Edited and authored by leading researcher in the field, the various chapters address an interdisciplinary readership, ranging from theoretical physicists to application-oriented scientists in all data-providing disciplines.

  10. Biomechanical Analysis of Contemporary Throwing Technique Theory

    Directory of Open Access Journals (Sweden)

    Chen Jian


    Full Text Available Based on the movement process of throwing and in order to further improve the throwing technique of our country, this paper will first illustrate the main influence factors which will affect the shot distance via the mutual combination of movement equation and geometrical analysis. And then, it will give the equation of the acting force that the throwing athletes have to bear during throwing movement; and will reach the speed relationship between each arthrosis during throwing and batting based on the kinetic analysis of the throwing athletes’ arms while throwing. This paper will obtain the momentum relationship of the athletes’ each arthrosis by means of rotational inertia analysis; and then establish a restricted particle dynamics equation from the Lagrange equation. The obtained result shows that the momentum of throwing depends on the momentum of the athletes’ wrist joints while batting.

  11. Interaction Analysis: Theory, Research and Application. (United States)

    Amidon, Edmund J., Ed.; Hough, John J., Ed.

    This volume of selected readings developed for students and practitioners at various levels of sophistication is intended to be representative of work done to date on interaction analysis. The contents include journal articles, papers read at professional meetings, abstracts of doctoral dissertations, and selections from larger monographs, plus 12…

  12. Operator theory a comprehensive course in analysis, part 4

    CERN Document Server

    Simon, Barry


    A Comprehensive Course in Analysis by Poincaré Prize winner Barry Simon is a five-volume set that can serve as a graduate-level analysis textbook with a lot of additional bonus information, including hundreds of problems and numerous notes that extend the text and provide important historical background. Depth and breadth of exposition make this set a valuable reference source for almost all areas of classical analysis. Part 4 focuses on operator theory, especially on a Hilbert space. Central topics are the spectral theorem, the theory of trace class and Fredholm determinants, and the study of

  13. Network analysis and synthesis a modern systems theory approach

    CERN Document Server

    Anderson, Brian D O


    Geared toward upper-level undergraduates and graduate students, this book offers a comprehensive look at linear network analysis and synthesis. It explores state-space synthesis as well as analysis, employing modern systems theory to unite the classical concepts of network theory. The authors stress passive networks but include material on active networks. They avoid topology in dealing with analysis problems and discuss computational techniques. The concepts of controllability, observability, and degree are emphasized in reviewing the state-variable description of linear systems. Explorations

  14. Population Transfer between Two Quantum States by Piecewise Chirping of Femtosecond Pulses: Theory and Experiment

    International Nuclear Information System (INIS)

    Zhdanovich, S.; Shapiro, E. A.; Shapiro, M.; Hepburn, J. W.; Milner, V.


    We propose and experimentally demonstrate the method of population transfer by piecewise adiabatic passage between two quantum states. Coherent excitation of a two-level system with a train of ultrashort laser pulses is shown to reproduce the effect of an adiabatic passage, conventionally achieved with a single frequency-chirped pulse. By properly adjusting the amplitudes and phases of the pulses in the excitation pulse train, we achieve complete and robust population transfer to the target state. The piecewise nature of the process suggests a possibility for the selective population transfer in complex quantum systems

  15. Molecular theory of mass transfer kinetics and dynamics at gas-water interface

    International Nuclear Information System (INIS)

    Morita, Akihiro; Garrett, Bruce C


    The mass transfer mechanism across gas-water interface is studied with molecular dynamics (MD) simulation. The MD results provide a robust and qualitatively consistent picture to previous studies about microscopic aspects of mass transfer, including interface structure, free energy profiles for the uptake, scattering dynamics and energy relaxation of impinging molecules. These MD results are quantitatively compared with experimental uptake measurements, and we find that the apparent inconsistency between MD and experiment could be partly resolved by precise decomposition of the observed kinetics into elemental steps. Remaining issues and future perspectives toward constructing a comprehensive multi-scale description of interfacial mass transfer are summarized.

  16. A network analysis of leadership theory : the infancy of integration.


    Meuser, J. D.; Gardner, W. L.; Dinh, J. E.; Hu, J.; Liden, R. C.; Lord, R. G.


    We investigated the status of leadership theory integration by reviewing 14 years of published research (2000 through 2013) in 10 top journals (864 articles). The authors of these articles examined 49 leadership approaches/theories, and in 293 articles, 3 or more of these leadership approaches were included in their investigations. Focusing on these articles that reflected relatively extensive integration, we applied an inductive approach and used graphic network analysis as a guide for drawi...

  17. grounded theory approach in sermon analysis of sermons

    African Journals Online (AJOL)

    The process of sermon analysis in its different phases will be discussed as well as the interaction of this ... explanation of the process of grounded theory research in stages of the sermon analysis of sermons on ..... During this creative and theoretically sensitive phase, reading of relevant literature can shed new light on the ...

  18. Law and Technology Theory: Bringing in Some Economic Analysis (United States)

    Trosow, Samuel


    The author argues economic analysis needs to be explicitly included in an overall theory of law and technology. Differing approaches to the economics of information are considered, and the copyright policy environment of the 1990s is taken as an example of how the lack of substantive economic analysis resulted in poor policy-making.

  19. The Constant Comparative Analysis Method Outside of Grounded Theory (United States)

    Fram, Sheila M.


    This commentary addresses the gap in the literature regarding discussion of the legitimate use of Constant Comparative Analysis Method (CCA) outside of Grounded Theory. The purpose is to show the strength of using CCA to maintain the emic perspective and how theoretical frameworks can maintain the etic perspective throughout the analysis. My…

  20. Transferring and practicing the correspondence principle in the old quantum theory: Franck, Hund and the Ramsauer effect

    Energy Technology Data Exchange (ETDEWEB)

    Jaehnert, Martin [MPIWG, Berlin (Germany)


    In 1922 Niels Bohr wrote a letter to Arnold Sommerfeld complaining that: ''[i]n the last years my attempts to develop the principles of quantum theory were met with very little understanding.'' Looking for the correspondence idea in publications, one finds that the principle was indeed hardly applied by physicists outside of Copenhagen. Only by 1922 physicists from wider research networks of quantum theory started to transfer the principle into their research fields, often far removed from its initial realm of atomic spectroscopy. How and why did physicists suddenly become interested in the idea that Bohr*s writings had been promoting since 1918? How was the correspondence principle transferred to these fields and how did its transfer affect these fields and likewise the correspondence principle itself? To discuss these questions, my talk focuses on the work of James Franck and Friedrich Hund on the Ramsauer effect in 1922 and follows the interrelation of the developing understanding of a newly found effect and the adaptation of the correspondence idea in a new conceptual and sociological context.


    International Nuclear Information System (INIS)

    Lee, S


    In support of a small column ion exchange (SCIX) process for the Savannah River Site waste processing program, transient and steady state two-dimensional heat transfer models have been constructed for columns loaded with cesium-saturated crystalline silicotitanate (CST) or spherical Resorcinol-Formaldehyde (RF) beads and 6 molar sodium tank waste supernate. Radiolytic decay of sorbed cesium results in heat generation within the columns. The models consider conductive heat transfer only with no convective cooling and no process flow within the columns (assumed column geometry: 27.375 in ID with a 6.625 in OD center-line cooling pipe). Heat transfer at the column walls was assumed to occur by natural convection cooling with 35 C air. A number of modeling calculations were performed using this computational heat transfer approach. Minimal additional calculations were also conducted to predict temperature increases expected for salt solution processed through columns of various heights at the slowest expected operational flow rate of 5 gpm. Results for the bounding model with no process flow and no active cooling indicate that the time required to reach the boiling point of ∼130 C for a CST-salt solution mixture containing 257 Ci/liter of Cs-137 heat source (maximum expected loading for SCIX applications) at 35 C initial temperature is about 6 days. Modeling results for a column actively cooled with external wall jackets and the internal coolant pipe (inlet coolant water temperature: 25 C) indicate that the CST column can be maintained non-boiling under these conditions indefinitely. The results also show that the maximum temperature of an RF-salt solution column containing 133 Ci/liter of Cs-137 (maximum expected loading) will never reach boiling under any conditions (maximum predicted temperature without cooling: 88 C). The results indicate that a 6-in cooling pipe at the center of the column provides the most effective cooling mechanism for reducing the maximum

  2. Heat Transfer Analysis for a Fixed CST Column

    International Nuclear Information System (INIS)

    Lee, S.Y.


    In support of a small column ion exchange (SCIX) process for the Savannah River Site waste processing program, a transient two-dimensional heat transfer model that includes the conduction process neglecting the convection cooling mechanism inside the crystalline silicotitanate (CST) column has been constructed and heat transfer calculations made for the present design configurations. For this situation, a no process flow condition through the column was assumed as one of the reference conditions for the simulation of a loss-of-flow accident. A series of the modeling calculations has been performed using a computational heat transfer approach. Results for the baseline model indicate that transit times to reach 130 degrees Celsius maximum temperature of the CST-salt solution column are about 96 hours when the 20-in CST column with 300 Ci/liter heat generation source and 25 degrees Celsius initial column temperature is cooled by natural convection of external air as a primary heat transfer mechanism. The modeling results for the 28-in column equipped with water jacket systems on the external wall surface of the column and water coolant pipe at the center of the CST column demonstrate that the column loaded with 300 Ci/liter heat source can be maintained non-boiling indefinitely. Sensitivity calculations for several alternate column sizes, heat loads of the packed column, engineered cooling systems, and various ambient conditions at the exterior wall of the column have been performed under the reference conditions of the CST-salt solution to assess the impact of those parameters on the peak temperatures of the packed column for a given transient time. The results indicate that a water-coolant pipe at the center of the CST column filled with salt solution is the most effective one among the potential design parameters related to the thermal energy dissipation of decay heat load. It is noted that the cooling mechanism at the wall boundary of the column has significant


    Energy Technology Data Exchange (ETDEWEB)

    Lee, S


    In support of a small column ion exchange (SCIX) process for the Savannah River Site waste processing program, transient and steady state two-dimensional heat transfer models have been constructed for columns loaded with cesium-saturated crystalline silicotitanate (CST) or spherical Resorcinol-Formaldehyde (RF) beads and 6 molar sodium tank waste supernate. Radiolytic decay of sorbed cesium results in heat generation within the columns. The models consider conductive heat transfer only with no convective cooling and no process flow within the columns (assumed column geometry: 27.375 in ID with a 6.625 in OD center-line cooling pipe). Heat transfer at the column walls was assumed to occur by natural convection cooling with 35 C air. A number of modeling calculations were performed using this computational heat transfer approach. Minimal additional calculations were also conducted to predict temperature increases expected for salt solution processed through columns of various heights at the slowest expected operational flow rate of 5 gpm. Results for the bounding model with no process flow and no active cooling indicate that the time required to reach the boiling point of {approx}130 C for a CST-salt solution mixture containing 257 Ci/liter of Cs-137 heat source (maximum expected loading for SCIX applications) at 35 C initial temperature is about 6 days. Modeling results for a column actively cooled with external wall jackets and the internal coolant pipe (inlet coolant water temperature: 25 C) indicate that the CST column can be maintained non-boiling under these conditions indefinitely. The results also show that the maximum temperature of an RF-salt solution column containing 133 Ci/liter of Cs-137 (maximum expected loading) will never reach boiling under any conditions (maximum predicted temperature without cooling: 88 C). The results indicate that a 6-in cooling pipe at the center of the column provides the most effective cooling mechanism for reducing the

  4. Radiative Transfer Analysis of Neptune’s New Dark Vortex (United States)

    Tollefson, Joshua; Luszcz-Cook, Statia H.; Wong, Michael H.; de Pater, Imke


    A new dark spot on Neptune was discovered in late 2015, named: "SDS-2015" for "Southern Dark Spot discovered in 2015". Subsequent observations from Hubble Space Telescope Mid-Cycle 23 (PI: Wong) and the Outer Planetary Atmospheres Legacy (OPAL) programs (PI: Simon-Miller) took the first multispectral data over multiple viewing geometries of a Neptunian dark spot, spanning wavelengths from 336 to 763nm. SDS-2015 is visible at blue wavelengths, with contrast from the background atmosphere peaking at 467nm. In this abstract, we present a radiative transfer analysis of the dark spot and surrounding background atmosphere. We summarize our retrieved properties of Neptune's background atmosphere, including its aerosol structure and methane profile, and compare our findings in the optical wavelengths to those in the near-infrared. We then discuss various hypotheses about the make up of SDS-2015 and its interaction with the background atmosphere.

  5. Knowledge transfer in pair programming: An in-depth analysis

    DEFF Research Database (Denmark)

    Plonka, Laura; Sharp, Helen; van der Linden, Janet


    Whilst knowledge transfer is one of the most widely-claimed benefits of pair programming, little is known about how knowledge transfer is achieved in this setting. This is particularly pertinent for novice−expert constellations, but knowledge transfer takes place to some degree in all constellati...

  6. Polarimetric signatures of a canopy of dielectric cylinders based on first and second order vector radiative transfer theory (United States)

    Tsang, Leung; Chan, Chi Hou; Kong, Jin AU; Joseph, James


    Complete polarimetric signatures of a canopy of dielectric cylinders overlying a homogeneous half space are studied with the first and second order solutions of the vector radiative transfer theory. The vector radiative transfer equations contain a general nondiagonal extinction matrix and a phase matrix. The energy conservation issue is addressed by calculating the elements of the extinction matrix and the elements of the phase matrix in a manner that is consistent with energy conservation. Two methods are used. In the first method, the surface fields and the internal fields of the dielectric cylinder are calculated by using the fields of an infinite cylinder. The phase matrix is calculated and the extinction matrix is calculated by summing the absorption and scattering to ensure energy conservation. In the second method, the method of moments is used to calculate the elements of the extinction and phase matrices. The Mueller matrix based on the first order and second order multiple scattering solutions of the vector radiative transfer equation are calculated. Results from the two methods are compared. The vector radiative transfer equations, combined with the solution based on method of moments, obey both energy conservation and reciprocity. The polarimetric signatures, copolarized and depolarized return, degree of polarization, and phase differences are studied as a function of the orientation, sizes, and dielectric properties of the cylinders. It is shown that second order scattering is generally important for vegetation canopy at C band and can be important at L band for some cases.

  7. Complex analysis a modern first course in function theory

    CERN Document Server

    Muir, Jerry R


    A thorough introduction to the theory of complex functions emphasizing the beauty, power, and counterintuitive nature of the subject Written with a reader-friendly approach, Complex Analysis: A Modern First Course in Function Theory features a self-contained, concise development of the fundamental principles of complex analysis. After laying groundwork on complex numbers and the calculus and geometric mapping properties of functions of a complex variable, the author uses power series as a unifying theme to define and study the many rich and occasionally surprising properties of analytic fun

  8. Analysis of General Power Counting Rules in Effective Field Theory

    CERN Document Server

    Gavela, B M; Manohar, A V; Merlo, L


    We derive the general counting rules for a quantum effective field theory (EFT) in $\\mathsf{d}$ dimensions. The rules are valid for strongly and weakly coupled theories, and predict that all kinetic energy terms are canonically normalized. They determine the energy dependence of scattering cross sections in the range of validity of the EFT expansion. The size of cross sections is controlled by the $\\Lambda$ power counting of EFT, not by chiral counting, even for chiral perturbation theory ($\\chi$PT). The relation between $\\Lambda$ and $f$ is generalized to $\\mathsf{d}$ dimensions. We show that the naive dimensional analysis $4\\pi$ counting is related to $\\hbar$ counting. The EFT counting rules are applied to $\\chi$PT, to Standard Model EFT and to the non-trivial case of Higgs EFT, which combines the $\\Lambda$ and chiral counting rules within a single theory.

  9. Towards a Design Theory for Collaborative Qualitative Data Analysis

    DEFF Research Database (Denmark)

    Nielsen, Peter Axel


    This position paper addresses how to develop a design theory to support the collaborative practice of qualitative data analysis. Qualitative researchers face several challenges in making sense of their empirical data and IS-support for this practice can be found in software applications...... such as NVivo, Atlas.ti, and DeDoose. While these software tools have utility and are valuable, they are also limiting – and they are particularly limiting researchers in their collaborative efforts with their co-researchers. In this paper, we investigate a design theory to extend it to support collaboration....... We use this as a stepping stone to discuss how to use a design theory to problematize existing applications and how to extend a design theory by abduction....

  10. Resurgent Analysis of Localizable Observables in Supersymmetric Gauge Theories

    CERN Document Server

    Aniceto, Inês; Schiappa, Ricardo


    Localization methods have recently led to a plethora of new exact results in supersymmetric gauge theories, as certain observables may be computed in terms of matrix integrals. These can then be evaluated by making use of standard large N techniques, or else via perturbative expansions in the gauge coupling. Either approximation often leads to observables given in terms of asymptotic series, which need to be properly defined in order to obtain nonperturbative results. At the same time, resurgent analysis has recently been successfully applied to several problems, e.g., in quantum, field and string theories, precisely to overcome this issue and construct nonperturbative answers out of asymptotic perturbative expansions. The present work uses exact results from supersymmetric localization to address the resurgent structure of the free energy and partition function of Chern-Simons and ABJM gauge theories in three dimensions, and of N=2 supersymmetric Yang-Mills theories in four dimensions. For each case, the com...

  11. [Peplau's theory of interpersonal relations: an analysis based of Barnum]. (United States)

    de Almeida, Vitória de Cássia Félix; Lopes, Marcos Venícios de Oliveira; Damasceno, Marta Maria Coelho


    The use of theories in Nursing reflects a movement in the profession towards the autonomy and delimitation of its actions. It is, therefore, extremely relevant that theories may be analyzed as for their applicability to practice. The object of this study is to make an analytical-descriptive study of Peplau's Theory of Interpersonal Relations in Nursing from the model of analysis proposed by Barbara Barnum. Among the structural components that may be analyzed in a theory was chosen the element "process", a method recommended for the development of nursing' actions, which was submitted to Barnum's criteria of usefulness. The assessment showed that Peplau's theoretical presuppositions are operational and may serve as a basis in any situation in which nurses communicate and interact with his/her patients.

  12. Video Game Characters. Theory and Analysis

    Directory of Open Access Journals (Sweden)

    Felix Schröter


    Full Text Available This essay develops a method for the analysis of video game characters based on a theoretical understanding of their medium-specific representation and the mental processes involved in their intersubjective construction by video game players. We propose to distinguish, first, between narration, simulation, and communication as three modes of representation particularly salient for contemporary video games and the characters they represent, second, between narrative, ludic, and social experience as three ways in which players perceive video game characters and their representations, and, third, between three dimensions of video game characters as ‘intersubjective constructs’, which usually are to be analyzed not only as fictional beings with certain diegetic properties but also as game pieces with certain ludic properties and, in those cases in which they function as avatars in the social space of a multiplayer game, as representations of other players. Having established these basic distinctions, we proceed to analyze their realization and interrelation by reference to the character of Martin Walker from the third-person shooter Spec Ops: The Line (Yager Development 2012, the highly customizable player-controlled characters from the role-playing game The Elder Scrolls V: Skyrim (Bethesda 2011, and the complex multidimensional characters in the massively multiplayer online role-playing game Star Wars: The Old Republic (BioWare 2011-2014.

  13. Cross-species gene transfer; implications for a new theory of evolution. (United States)

    Syvanen, M


    It has been established that genes can be transferred and expressed among procaryotes of different species. I am hypothesizing--and there is mounting evidence for this conclusion--that genes are transferred and expressed among all species, and that such exchange is facilitated by, and can help account for, the existence of the biological unities, from the uniform genetic code to the cross-species similarity of the stages of embryological development. If this idea is correct, the uniformity of the genetic code would allow organisms to decipher and use genes transposed from chromosomes of foreign species, and the shared sequence of embryological development within each phylum would allow the organism to integrate these genes, particularly when the genes affect complex morphological traits. The cross-species gene transfer model could help explain many observations which have puzzled evolutionists, such as rapid bursts in evolution and the widespread occurrence of parallelism in the fossil record.

  14. Using dual-process theory and analogical transfer to explain facilitation on a hypothetico-deductive reasoning task. (United States)

    Koenig, Cynthia S; Platt, Richard D; Griggs, Richard A


    Using the analogical transfer paradigm, the present study investigated the competing explanations of Girotto and Legrenzi (Psychological Research 51: 129-135, 1993) and Griggs, Platt, Newstead, and Jackson (Thinking and Reasoning 4: 1-14, 1998) for facilitation on the SARS version of the THOG problem, a hypothetico-deductive reasoning task. Girotto and Legrenzi argue that facilitation is based on logical analysis of the task [System 2 reasoning in Evans's (Trends in Cognitive Sciences 7: 454-459, 2003) dual-process account of reasoning] while Griggs et al. maintain that facilitation is due to an attentional heuristic produced by the wording of the problem (System 1 reasoning). If Girotto and Legrenzi are correct, then System 2 reasoning, which is volitional and responsible for deductive reasoning, should be elicited, and participants should comprehend the solution principle of the THOG task and exhibit analogical transfer. However, if Griggs et al. are correct, then System 1 reasoning, which is responsible for heuristic problem solving strategies such as an attentional heuristic, should occur, and participants should not abstract the solution principle and transfer should not occur. Significant facilitation (68 and 82% correct) was only observed for the two SARS source problems, but significant analogical transfer did not occur. This lack of transfer suggests that System 1 reasoning was responsible for the facilitation observed in the SARS problem, supporting Griggs et al.'s attentional heuristic explanation. The present results also underscore the explanatory value of using analogical transfer rather than facilitation as the criterion for problem understanding.

  15. Convex analysis and monotone operator theory in Hilbert spaces

    CERN Document Server

    Bauschke, Heinz H


    This reference text, now in its second edition, offers a modern unifying presentation of three basic areas of nonlinear analysis: convex analysis, monotone operator theory, and the fixed point theory of nonexpansive operators. Taking a unique comprehensive approach, the theory is developed from the ground up, with the rich connections and interactions between the areas as the central focus, and it is illustrated by a large number of examples. The Hilbert space setting of the material offers a wide range of applications while avoiding the technical difficulties of general Banach spaces. The authors have also drawn upon recent advances and modern tools to simplify the proofs of key results making the book more accessible to a broader range of scholars and users. Combining a strong emphasis on applications with exceptionally lucid writing and an abundance of exercises, this text is of great value to a large audience including pure and applied mathematicians as well as researchers in engineering, data science, ma...

  16. Analysis of reactor power oscillation based on nonlinear dynamic theory

    International Nuclear Information System (INIS)

    Suzudo, Tomoaki


    Reactor power oscillations are discussed based on nonlinear dynamic theory with reference to stability problem of boiling water reactors (BWRs). The reactor noise from an actual plant is, firstly, analyzed by a method originally used for the analysis of chaotic phenomenon. The results show that this method gives better dynamic descriptor of oscillatory motion than those from previous methods, and that it is applicable to real-time monitoring system of the reactor core. Next, the low-dimensional phenomenological model of BWR power oscillation is analytically studied using bifurcation theory, a branch of nonlinear dynamic theory. From this analysis are derived explicit expressions for the steady state's linear stability and weak stability not given by numerical analyses, and the qualitative properties of the power oscillation can be better understood. (author)

  17. Educational Policy Transfer in an Era of Globalization: Theory--History--Comparison. Comparative Studies Series. Volume 23 (United States)

    Rappleye, Jeremy


    As education becomes increasingly global, the processes and politics of transfer have become a central focus of research. This study provides a comprehensive analysis of contemporary theoretical and analytical work aimed at exploring international educational reform and reveals the myriad ways that globalization is now fundamentally altering our…

  18. Lyapunov analysis: from dynamical systems theory to applications (United States)

    Cencini, Massimo; Ginelli, Francesco


    mathematical development and only provide access to partial pieces of information. Moreover, the scattered state of the present literature, with key contributions published in journals read by different communities (mathematicians, nonlinear and statistical physicists, fluid dynamicists and geophysicists), makes it difficult to develop a general picture. This special issue aims to offer an up-to-date view of current research on Lyapunov analysis, discussing both its mathematical theory and its applications to a number of different problems. Moreover, in order to facilitate the comparison and exchange of ideas and tools among different fields of research, contributions (either original or topical reviews) from researchers working in different disciplines have been selected for this issue. After the compact review of the basic mathematical results on Lyapunov exponents by Lai-Sang Young, the special issue is organized into nine sections broadly focused on the following topics: Large deviations and rare trajectories. Lyapunov exponents are mean quantities which characterize the sensitivity to initial conditions of typical trajectories. A large deviation theory of their finite time fluctuations, however, is relevant for the construction of a thermodynamic formalism of deterministic chaos. Moreover, the weighted sampling of extreme fluctuations allows one to access rare trajectories and phase-space topological structures. Random matrices. Lyapunov exponents are suitable quantities to statistically characterize products of random matrices, with a number of applications to transfer matrix methods and, more generally, to the statistical mechanics of disordered systems. In particular, Lyapunov exponents have long played a central role in the theory of Anderson localization. These aspects are reviewed here, together with an original application to the transfer matrix. Covariant Lyapunov vectors: theory and applications. CLVs constitute an intrinsic tangent space decomposition into

  19. Avenues to improve success in SME business transfers: reflections on theories, research and policies

    NARCIS (Netherlands)

    Lex van Teeffelen


    Every year I talk to many entrepreneurs about business transfers and acquisitions. Only rarely do they tell me that it was a cinch. Buying or selling a business is complex. For a start, a business should be shipshape from an organizational and administrative perspective, while several legal

  20. International technology transfer: building theory from a multiple case-study in the aircraft industry

    NARCIS (Netherlands)

    Steenhuis, H.J.; de Bruijn, E.J.


    International technology transfer occurs frequently in international operations, for example in cases of foreign direct investment where companies set-up existing manufacturing lines in new locations. It also occurs in situations of international outsourcing where a new supplier receives product

  1. The Import of Knowledge Export: Connecting Findings and Theories of Transfer of Learning (United States)

    Day, Samuel B.; Goldstone, Robert L.


    After more than 100 years of interest and study, knowledge transfer remains among the most challenging, contentious, and important issues for both psychology and education. In this article, we review and discuss many of the more important ideas and findings from the existing research and attempt to bridge this body of work with the exciting new…

  2. Theory of radiative transfer models applied in optical remote sensing of vegetation canopies

    NARCIS (Netherlands)

    Verhoef, W.


    In this thesis the work of the author on the modelling of radiative transfer in vegetation canopies and the terrestrial atmosphere is summarized. The activities span a period of more than fifteen years of research in this field carried out at the National Aerospace Laboratory

  3. Certification of CFD heat transfer software for turbine blade analysis (United States)

    Jordan, William A.


    Accurate modeling of heat transfer effects is a critical component of the Turbine Branch of the Turbomachinery and Propulsion Systems Division. Being able to adequately predict and model heat flux, coolant flows, and peak temperatures are necessary for the analysis of high pressure turbine blades. To that end, the primary goal of my internship this summer will be to certify the reliability of the CFD program GlennHT for the purpose of turbine blade heat transfer analysis. GlennHT is currently in use by the engineers in the Turbine Branch who use the FORTRAN 77 version of the code for analysis. The program, however, has been updated to a FORTRAN 90 version which is more robust than the older code. In order for the new code to be distributed for use, its reliability must first be certified. Over the course of my internship I will create and run test cases using the FORTRAN 90 version of GlennHT and compare the results to older cases which are known to be accurate, If the results of the new code match those of the sample cases then the newer version will be one step closer to certification for distribution. In order to complete these it will first be necessary to become familiar with operating a number of other programs. Among them are GridPro, which is used to create a grid mesh around a blade geometry, and FieldView, whose purpose is to graphically display the results from the GlennHT program. Once enough familiarity is established with these programs to render them useful, then the work of creating and running test scenarios will begin. The work is additionally complicated by a transition in computer hardware. Most of the working computers in the Turbine Branch are Silicon Graphics machines, which will soon be replaced by LINUX PC's. My project is one of the first to make use the new PC's. The change in system architecture however, has created several software related issues which have greatly increased the time and effort investments required by the project

  4. Analysis and technology transfer report, 1989 and 1990

    Energy Technology Data Exchange (ETDEWEB)


    The buildings sector used 29.6 quadrillion Btus (quads) of energy in 1989, or 36 percent of the total primary energy consumed in the United States. The major uses are for space heating and cooling, water heating, refrigeration, and lighting. Electricity is the dominant fuel, followed by natural gas, petroleum, and other fuels. Although there were dramatic improvements in energy efficiency in this sector from 1975 to 1985, in recent years energy use has grown rapidly. The large growth expected in commercial building floor space and in residential units means that total building-sector energy consumption could increase dramatically by the year 2030. The mission of the US DOE's Office of Building Technologies (OBT) is to lead a national program supporting private sector efforts to improve the energy efficiency of the nation's buildings and to increase their utilization of renewable energy sources. The Office is also responsible for energy efficiency planning and management for Federal buildings as well as buildings-related associated information, financial incentives, and regulatory functions that are determined to be appropriate for the Federal government. To accomplish its goals, OBT plans and conducts research and development to make technologies available and provides information on their effectiveness. The selection and management of OBT research activities requires an understanding of where and how energy is used within the buildings sectors, how energy use is expected to change in the future, and the potential impact of new and emerging technologies on energy use. Analysis activities serve to collect energy use information, provide the analysis necessary to apply this information to research and development planning, and develop analysis tools which the program uses to set priorities for research projects. This report summarizes analysis and technology transfer activities undertaken by OBT during 1989 and 1990. 101 refs., 19 figs., 9 tabs.

  5. Variational analysis and generalized differentiation I basic theory

    CERN Document Server

    Mordukhovich, Boris S


    Contains a study of the basic concepts and principles of variational analysis and generalized differentiation in both finite-dimensional and infinite-dimensional spaces. This title presents many applications to problems in optimization, equilibria, stability and sensitivity, control theory, economics, mechanics, and more.

  6. Analysis of Generation Y Workforce Motivation Using Multiattribute Utility Theory (United States)


    Generation Y are “ Millennials ” (Howe & Strauss, 2000), “Net Generation ” (Shaw & Fairhurst, 2008), and “ Generation ... Generation   Y , Motivational Factors, Utility Measurement ANALYSIS OF GENERATION Y WORKFORCE MOTIVATION USING MULTIATTRIBUTE UTILITY THEORY Ian N...government workforce members of Generation Y versus Generation X and Baby Boomers. Thirty hypotheses were tested, and 11 were found to be

  7. Buckling Analysis of Laminate Short Beams by High Order Theory

    Directory of Open Access Journals (Sweden)

    hamza madjid berrabah


    Full Text Available The transverse shear behavior of the composite beams can be critical and must therefore be properly represented by the various models of structures normally used to predict their behavior or to identify their properties. We propose in this work, a warpage analysis in short laminated beams using a simple analytical approach based on the theories of higher order.

  8. Low heat transfer oxidizer heat exchanger design and analysis (United States)

    Kanic, P. G.; Kmiec, T. D.; Peckham, R. J.


    The RL10-IIB engine, a derivative of the RLIO, is capable of multi-mode thrust operation. This engine operates at two low thrust levels: tank head idle (THI), which is approximately 1 to 2 percent of full thrust, and pumped idle (PI), which is 10 percent of full thrust. Operation at THI provides vehicle propellant settling thrust and efficient engine thermal conditioning; PI operation provides vehicle tank pre-pressurization and maneuver thrust for log-g deployment. Stable combustion of the RL10-IIB engine at THI and PI thrust levels can be accomplished by providing gaseous oxygen at the propellant injector. Using gaseous hydrogen from the thrust chamber jacket as an energy source, a heat exchanger can be used to vaporize liquid oxygen without creating flow instability. This report summarizes the design and analysis of a United Aircraft Products (UAP) low-rate heat transfer heat exchanger concept for the RL10-IIB rocket engine. The design represents a second iteration of the RL10-IIB heat exchanger investigation program. The design and analysis of the first heat exchanger effort is presented in more detail in NASA CR-174857. Testing of the previous design is detailed in NASA CR-179487.

  9. Scaled-particle theory analysis of cylindrical cavities in solution. (United States)

    Ashbaugh, Henry S


    The solvation of hard spherocylindrical solutes is analyzed within the context of scaled-particle theory, which takes the view that the free energy of solvating an empty cavitylike solute is equal to the pressure-volume work required to inflate a solute from nothing to the desired size and shape within the solvent. Based on our analysis, an end cap approximation is proposed to predict the solvation free energy as a function of the spherocylinder length from knowledge regarding only the solvent density in contact with a spherical solute. The framework developed is applied to extend Reiss's classic implementation of scaled-particle theory and a previously developed revised scaled-particle theory to spherocylindrical solutes. To test the theoretical descriptions developed, molecular simulations of the solvation of infinitely long cylindrical solutes are performed. In hard-sphere solvents classic scaled-particle theory is shown to provide a reasonably accurate description of the solvent contact correlation and resulting solvation free energy per unit length of cylinders, while the revised scaled-particle theory fitted to measured values of the contact correlation provides a quantitative free energy. Applied to the Lennard-Jones solvent at a state-point along the liquid-vapor coexistence curve, however, classic scaled-particle theory fails to correctly capture the dependence of the contact correlation. Revised scaled-particle theory, on the other hand, provides a quantitative description of cylinder solvation in the Lennard-Jones solvent with a fitted interfacial free energy in good agreement with that determined for purely spherical solutes. The breakdown of classical scaled-particle theory does not result from the failure of the end cap approximation, however, but is indicative of neglected higher-order curvature dependences on the solvation free energy.

  10. Analysis of longwall face-to-face transfers

    International Nuclear Information System (INIS)

    Patrick, C.; Topuz, E.


    A non-producing longwall costs the mine owner from $45 to over $100 per minute in lost production time. Face-to-face equipment transfers, which involve disassembling longwall equipment in a panel, transporting, and then reassembling it in a new longwall panel, are second only to system availability as a source of longwall non-productive time. This, in addition to a move cost of over $100,000, makes reduction and control of face transfer times essential. This paper will report a segment of on-going VPI research to analyze and model longwall transfers through the use of operations research techniques. The purpose is to reduce overall transfer time and the variation of transfer times among U.S. longwall operations. This research is expected to contribute to the longwall mining industry by offering an objective approach that can be used in the prediction, planning, preparation, and implementation of longwall face equipment transfers

  11. Real analysis measure theory, integration, and Hilbert spaces

    CERN Document Server

    Stein, Elias M


    Real Analysis is the third volume in the Princeton Lectures in Analysis, a series of four textbooks that aim to present, in an integrated manner, the core areas of analysis. Here the focus is on the development of measure and integration theory, differentiation and integration, Hilbert spaces, and Hausdorff measure and fractals. This book reflects the objective of the series as a whole: to make plain the organic unity that exists between the various parts of the subject, and to illustrate the wide applicability of ideas of analysis to other fields of mathematics and science. After

  12. Processes of local alcohol policy-making in England: Does the theory of policy transfer provide useful insights into public health decision-making? (United States)

    Gavens, Lucy; Holmes, John; Buykx, Penny; de Vocht, Frank; Egan, Matt; Grace, Daniel; Lock, Karen; Mooney, John D; Brennan, Alan


    Recent years have seen a rise in new and innovative policies to reduce alcohol consumption and related harm in England, which can be implemented by local, as opposed to national, policy-makers. The aim of this paper is to explore the processes that underpin the adoption of these alcohol policies within local authorities. In particular, it aims to assess whether the concept of policy transfer (i.e. a process through which knowledge about policies in one place is used in the development of policies in another time or place) provides a useful model for understanding local alcohol policy-making. Qualitative data generated through in-depth interviews and focus groups from five case study sites across England were used to explore stakeholder experiences of alcohol policy transfer between local authorities. The purposive sample of policy actors included representatives from the police, trading standards, public health, licensing, and commissioning. Thematic analysis was used inductively to identify key features in the data. Themes from the policy transfer literature identified in the data were: policy copying, emulating, hybridization, and inspiration. Participants described a multitude of ways in which learning was shared between places, ranging from formal academic evaluation to opportunistic conversations in informal settings. Participants also described facilitators and constraints to policy transfer, such as the historical policy context and the local cultural, economic, and bureaucratic context, which influenced whether or not a policy that was perceived to work in one place might be transferred successfully to another context. Theories of policy transfer provide a promising framework for characterising processes of local alcohol policy-making in England, extending beyond debates regarding evidence-informed policy to account for a much wider range of considerations. Applying a policy transfer lens enables us to move beyond simple (but still important) questions of

  13. Theory of charge transfer at the high-Tc superconductor/electrolyte interface

    DEFF Research Database (Denmark)

    Gluzman, Sasha; Kuznetsov, Alexander M.


    , involving a gap in the electronic spectrum. The height of the hump should be much less in the case of the unconventional d-wave pairing, while the absence of the hump is a signal about the importance of pair-breaking processes typical of the strong-coupling theories or even about bipolaron (bosonic...

  14. Analysis of accelerated motion in the theory of relativity (United States)

    Jones, R. T.


    Conventional treatments of accelerated motion in the theory of relativity have led to certain difficulties of interpretation. Certain reversals in the apparent gravitational field of an accelerated body may be avoided by simpler analysis based on the use of restricted conformal transformations. In the conformal theory the velocity of light remains constant even for experimenters in accelerated motion. The problem considered is that of rectilinear motion with a variable velocity. The motion takes place along the x or x' axis of two coordinate systems.

  15. Energy decomposition analysis of single bonds within Kohn-Sham density functional theory. (United States)

    Levine, Daniel S; Head-Gordon, Martin


    An energy decomposition analysis (EDA) for single chemical bonds is presented within the framework of Kohn-Sham density functional theory based on spin projection equations that are exact within wave function theory. Chemical bond energies can then be understood in terms of stabilization caused by spin-coupling augmented by dispersion, polarization, and charge transfer in competition with destabilizing Pauli repulsions. The EDA reveals distinguishing features of chemical bonds ranging across nonpolar, polar, ionic, and charge-shift bonds. The effect of electron correlation is assessed by comparison with Hartree-Fock results. Substituent effects are illustrated by comparing the C-C bond in ethane against that in bis(diamantane), and dispersion stabilization in the latter is quantified. Finally, three metal-metal bonds in experimentally characterized compounds are examined: a [Formula: see text]-[Formula: see text] dimer, the [Formula: see text]-[Formula: see text] bond in dizincocene, and the Mn-Mn bond in dimanganese decacarbonyl.

  16. Conceptual density functional theory for electron transfer and transport in mesoscopic systems. (United States)

    Bueno, Paulo R; Miranda, David A


    Molecular and supramolecular systems are essentially mesoscopic in character. The electron self-exchange, in the case of energy fluctuations, or electron transfer/transport, in the case of the presence of an externally driven electrochemical potential, between mesoscopic sites is energetically driven in such a manner where the electrochemical capacitance (C [small mu, Greek, macron] ) is fundamental. Thus, the electron transfer/transport through channels connecting two distinct energetic (ΔE [small mu, Greek, macron] ) and spatially separated mesoscopic sites is capacitively modulated. Remarkably, the relationship between the quantum conductance (G) and the standard electrochemical rate constant (k r ), which is indispensable to understanding the physical and chemical characteristics governing electron exchange in molecular scale systems, was revealed to be related to C [small mu, Greek, macron] , that is, C [small mu, Greek, macron] = G/k r . Accordingly, C [small mu, Greek, macron] is the proportional missing term that controls the electron transfer/transport in mesoscopic systems in a wide-range, and equally it can be understood from first principles density functional quantum mechanical approaches. Indeed the differences in energy between states is calculated (or experimentally accessed) throughout the electrochemical capacitance as ΔE [small mu, Greek, macron] = β/C [small mu, Greek, macron] , and thus constitutes the driving force for G and/or k r , where β is only a proportional constant that includes the square of the unit electron charge times the square of the number of electron particles interchanged.

  17. Examination of the teaching styles of nursing professional development specialists, part I: best practices in adult learning theory, curriculum development, and knowledge transfer. (United States)

    Curran, Mary K


    The American Nurses Association advocates for nursing professional development (NPD) specialists to have an earned graduate degree, as well as educational and clinical expertise. However, many NPD specialists have limited exposure to adult learning theory. Limited exposure to adult learning theory may affect NPD educational practices, learning outcomes, organizational knowledge transfer, and subsequently, the professional development of the nurses they serve and quality of nursing care. An examination of current teaching practices may reveal opportunities for NPD specialists to enhance educational methods to promote learning, learning transfer, and organizational knowledge and excellence. This article, the first in a two-part series, examines best practices of adult learning theories, nursing professional development, curriculum design, and knowledge transfer. Part II details the results of a correlational study that examined the effects of four variables on the use of adult learning theory to guide curriculum development for NPD specialists in hospitals. Copyright 2014, SLACK Incorporated.

  18. Effects of Computer Support, Collaboration, and Time Lag on Performance Self-Efficacy and Transfer of Training: A Longitudinal Meta-Analysis (United States)

    Gegenfurtner, Andreas; Veermans, Koen; Vauras, Marja


    This meta-analysis (29 studies, k = 33, N = 4158) examined the longitudinal development of the relationship between performance self-efficacy and transfer before and after training. A specific focus was on training programs that afforded varying degrees of computer-supported collaborative learning (CSCL). Consistent with social cognitive theory,…

  19. Computational heat transfer analysis and combined ANN–GA ...

    Indian Academy of Sciences (India)

    structures have significant effect on heat transfer characteristics and proposed correlations for the same. Siw et al ... studied the permissible number of fins for heat transfer enhancement and solved the energy equa- ..... The high temperature region is represented by red colour which is the base plate temperature and from ...

  20. Trainee Perceptions of Training Transfer: An Empirical Analysis (United States)

    Nikandrou, Irene; Brinia, Vassiliki; Bereri, Elissavet


    Purpose: The purpose of the paper is to present an empirical study based on a trainee-oriented systemic model for training transfer. The paper examines trainee characteristics which affect the motivation to learn and transfer and determine the trainees entry behavior. Then, during the training process, the complex interactions among the trainer,…

  1. Heat transfer analysis of liquid piston compressor for hydrogen applications

    DEFF Research Database (Denmark)

    Kermani, Nasrin Arjomand; Rokni, Masoud


    A hydrogen compression technology using liquid as the compression piston is investigated from heat transfer point of view. A thermodynamic model, simulating a single compression stroke, is developed to investigate the heat transfer phenomena inside the compression chamber. The model is developed...

  2. Heat transfer and thermal stress analysis in grooved tubes

    Indian Academy of Sciences (India)

    The maximum thermal stress ratio positions inside the tube have been indicated as MX for all investigated cases. In the light of the thermal stress values, various designs can be applied to reduce thermal stress in grooved tubes. Keywords. Heat transfer; thermal stress; grooved tubes. 1. Introduction. Heat transfer in pipe flow ...

  3. Analysis of adiabatic transfer in cavity quantum electrodynamics

    Indian Academy of Sciences (India)

    These results lend themselves to experimental tests. Our exact computations, when applied to slow variations of the control intensity for strong atom–photon couplings, are in very good agreement with Berry's superadiabatic transfer results without dissipation. Keywords. Cavity quantum electrodynamics; adiabatic transfer; ...

  4. Computational heat transfer analysis and combined ANN–GA ...

    Indian Academy of Sciences (India)

    Jones & Smith (1970) studied the optimal arrangement of rectangular fins on horizontal surfaces for free-convection heat transfer for maximum heat trans- fer rate and proposed correlations to obtain optimum fin spacing. Khaled (2010) numerically studied the permissible number of fins for heat transfer enhancement and ...

  5. Methods of Approximation Theory in Complex Analysis and Mathematical Physics

    CERN Document Server

    Saff, Edward


    The book incorporates research papers and surveys written by participants ofan International Scientific Programme on Approximation Theory jointly supervised by Institute for Constructive Mathematics of University of South Florida at Tampa, USA and the Euler International Mathematical Instituteat St. Petersburg, Russia. The aim of the Programme was to present new developments in Constructive Approximation Theory. The topics of the papers are: asymptotic behaviour of orthogonal polynomials, rational approximation of classical functions, quadrature formulas, theory of n-widths, nonlinear approximation in Hardy algebras,numerical results on best polynomial approximations, wavelet analysis. FROM THE CONTENTS: E.A. Rakhmanov: Strong asymptotics for orthogonal polynomials associated with exponential weights on R.- A.L. Levin, E.B. Saff: Exact Convergence Rates for Best Lp Rational Approximation to the Signum Function and for Optimal Quadrature in Hp.- H. Stahl: Uniform Rational Approximation of x .- M. Rahman, S.K. ...

  6. Improving Power System Stability Using Transfer Function: A Comparative Analysis

    Directory of Open Access Journals (Sweden)

    G. Shahgholian


    Full Text Available In this paper, a small-signal dynamic model of a single-machine infinite-bus (SMIB power system that includes IEEE type-ST1 excitation system and PSS based on transfer fu¬n¬c¬¬tion structure is presented. The changes in the operating co¬n¬dition of a power system on dynamic performance have been exa¬m¬ined. The dynamic performance of the closed-loop system is ana¬lyzed base on its eigenvalues. The effectiveness of the par¬a¬m¬e¬t¬ers changes on dynamic stability is verified by simulation res¬u¬l¬ts. Three types of PSS have been considered for analysis: (a the derivative PSS, (b the lead-lag PSS or conventional PSS, and (c the proportional-integral-derivative PSS. The objective fu¬nc¬t¬i¬o¬n is formulated to increase the dam¬¬ping ratio of the electromechanical mode eigenvalues. Simu¬la¬tion results show that the PID-PSS performs better for less ov¬e¬r¬shoot and less settling time comp¬ared with the CPSS and DPSS un¬der different load ope¬ration and the significant system pa¬r¬am¬eter variation conditions.

  7. Analysis of Health Behavior Theories for Clustering of Health Behaviors. (United States)

    Choi, Seung Hee; Duffy, Sonia A

    The objective of this article was to review the utility of established behavior theories, including the Health Belief Model, Theory of Reasoned Action, Theory of Planned Behavior, Transtheoretical Model, and Health Promotion Model, for addressing multiple health behaviors among people who smoke. It is critical to design future interventions for multiple health behavior changes tailored to individuals who currently smoke, yet it has not been addressed. Five health behavior theories/models were analyzed and critically evaluated. A review of the literature included a search of PubMed and Google Scholar from 2010 to 2016. Two hundred sixty-seven articles (252 studies from the initial search and 15 studies from the references of initially identified studies) were included in the analysis. Most of the health behavior theories/models emphasize psychological and cognitive constructs that can be applied only to one specific behavior at a time, thus making them not suitable to address multiple health behaviors. However, the Health Promotion Model incorporates "related behavior factors" that can explain multiple health behaviors among persons who smoke. Future multiple behavior interventions guided by the Health Promotion Model are necessary to show the utility and applicability of the model to address multiple health behaviors.

  8. B1 -sensitivity analysis of quantitative magnetization transfer imaging. (United States)

    Boudreau, Mathieu; Stikov, Nikola; Pike, G Bruce


    To evaluate the sensitivity of quantitative magnetization transfer (qMT) fitted parameters to B 1 inaccuracies, focusing on the difference between two categories of T 1 mapping techniques: B 1 -independent and B 1 -dependent. The B 1 -sensitivity of qMT was investigated and compared using two T 1 measurement methods: inversion recovery (IR) (B 1 -independent) and variable flip angle (VFA), B 1 -dependent). The study was separated into four stages: 1) numerical simulations, 2) sensitivity analysis of the Z-spectra, 3) healthy subjects at 3T, and 4) comparison using three different B 1 imaging techniques. For typical B 1 variations in the brain at 3T (±30%), the simulations resulted in errors of the pool-size ratio (F) ranging from -3% to 7% for VFA, and -40% to > 100% for IR, agreeing with the Z-spectra sensitivity analysis. In healthy subjects, pooled whole-brain Pearson correlation coefficients for F (comparing measured double angle and nominal flip angle B 1 maps) were ρ = 0.97/0.81 for VFA/IR. This work describes the B 1 -sensitivity characteristics of qMT, demonstrating that it varies substantially on the B 1 -dependency of the T 1 mapping method. Particularly, the pool-size ratio is more robust against B 1 inaccuracies if VFA T 1 mapping is used, so much so that B 1 mapping could be omitted without substantially biasing F. Magn Reson Med 79:276-285, 2018. © 2017 International Society for Magnetic Resonance in Medicine. © 2017 International Society for Magnetic Resonance in Medicine.

  9. The parametric resonance features for theory of energy transfer in dusty plasma (United States)

    Semyonov, V. P.; Timofeev, A. V.


    One of the mechanisms of energy transfer between degrees of freedom of dusty plasma system can be described by equations similar to Mathieu equation with account of stochastic forces. Such equation is studied by analytical approach. The solutions for higher order of accuracy are obtained. The method for numerical solution and resonance zone detection is proposed. The solution for the extended Mathieu equation is obtained for wide range of parameter values. The results of numerical solution are compared with analytical solutions of different order and known analytical results for Mathieu equation.

  10. Transport theory for femtosecond laser-induced spin-transfer torques (United States)

    Baláž, Pavel; Žonda, Martin; Carva, Karel; Maldonado, Pablo; Oppeneer, Peter M.


    Ultrafast demagnetization of magnetic layers pumped by a femtosecond laser pulse is accompanied by a nonthermal spin-polarized current of hot electrons. These spin currents are studied here theoretically in a spin valve with noncollinear magnetizations. To this end, we introduce an extended model of superdiffusive spin transport that enables the treatment of noncollinear magnetic configurations, and apply it to the perpendicular spin valve geometry. We show how spin-transfer torques arise due to this mechanism and calculate their action on the magnetization present, as well as how the latter depends on the thicknesses of the layers and other transport parameters. We demonstrate that there exists a certain optimum thickness of the out-of-plane magnetized spin-current polarizer such that the torque acting on the second magnetic layer is maximal. Moreover, we study the magnetization dynamics excited by the superdiffusive spin-transfer torque due to the flow of hot electrons employing the Landau–Lifshitz–Gilbert equation. Thereby we show that a femtosecond laser pulse applied to one magnetic layer can excite small-angle precessions of the magnetization in the second magnetic layer. We compare our calculations with recent experimental results.

  11. Transport theory for femtosecond laser-induced spin-transfer torques. (United States)

    Baláž, Pavel; Žonda, Martin; Carva, Karel; Maldonado, Pablo; Oppeneer, Peter M


    Ultrafast demagnetization of magnetic layers pumped by a femtosecond laser pulse is accompanied by a nonthermal spin-polarized current of hot electrons. These spin currents are studied here theoretically in a spin valve with noncollinear magnetizations. To this end, we introduce an extended model of superdiffusive spin transport that enables the treatment of noncollinear magnetic configurations, and apply it to the perpendicular spin valve geometry. We show how spin-transfer torques arise due to this mechanism and calculate their action on the magnetization present, as well as how the latter depends on the thicknesses of the layers and other transport parameters. We demonstrate that there exists a certain optimum thickness of the out-of-plane magnetized spin-current polarizer such that the torque acting on the second magnetic layer is maximal. Moreover, we study the magnetization dynamics excited by the superdiffusive spin-transfer torque due to the flow of hot electrons employing the Landau-Lifshitz-Gilbert equation. Thereby we show that a femtosecond laser pulse applied to one magnetic layer can excite small-angle precessions of the magnetization in the second magnetic layer. We compare our calculations with recent experimental results.

  12. Training older adults on Theory of Mind (ToM): transfer on metamemory. (United States)

    Lecce, Serena; Bottiroli, Sara; Bianco, Federica; Rosi, Alessia; Cavallini, Elena


    Research on aging has shown a significant decline in ToM after 65 years of age. Despite these age-related difficulties, no study has yet investigated the possibility to improve ToM in older adults. To address this gap we tested the efficacy of a conversation-based ToM training with age-appropriate ToM tasks and its transfer effects on metamemory. We examined 72 older adults (Mage=67.61 years, SD=6.39 years) assigned to three training conditions: a ToM training, a physical-conversation training and a social-contact group. All participants took part in two 2-h testing and to two 2-h training sessions. Results showed that after the intervention, older adults in the ToM training group improved their mental states' understanding significantly more than participants in the physical-conversation training and in the social-contact groups. Crucially, the positive effect of the ToM intervention generalized to metamemory knowledge. This is the first study investigating the efficacy of a ToM training and its transfer effect on metacognition in older adults. From a theoretical point of view, it supports the relation between ToM and metamemory. Practical implications of these data are discussed. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

  13. Influences of system uncertainties on the numerical transfer path analysis of engine systems (United States)

    Acri, A.; Nijman, E.; Acri, A.; Offner, G.


    Practical mechanical systems operate with some degree of uncertainty. In numerical models uncertainties can result from poorly known or variable parameters, from geometrical approximation, from discretization or numerical errors, from uncertain inputs or from rapidly changing forcing that can be best described in a stochastic framework. Recently, random matrix theory was introduced to take parameter uncertainties into account in numerical modeling problems. In particular in this paper, Wishart random matrix theory is applied on a multi-body dynamic system to generate random variations of the properties of system components. Multi-body dynamics is a powerful numerical tool largely implemented during the design of new engines. In this paper the influence of model parameter variability on the results obtained from the multi-body simulation of engine dynamics is investigated. The aim is to define a methodology to properly assess and rank system sources when dealing with uncertainties. Particular attention is paid to the influence of these uncertainties on the analysis and the assessment of the different engine vibration sources. Examples of the effects of different levels of uncertainties are illustrated by means of examples using a representative numerical powertrain model. A numerical transfer path analysis, based on system dynamic substructuring, is used to derive and assess the internal engine vibration sources. The results obtained from this analysis are used to derive correlations between parameter uncertainties and statistical distribution of results. The derived statistical information can be used to advance the knowledge of the multi-body analysis and the assessment of system sources when uncertainties in model parameters are considered.

  14. Free convection film flows and heat transfer laminar free convection of phase flows and models for heat-transfer analysis

    CERN Document Server

    Shang, De-Yi


    This book presents recent developments in our systematic studies of hydrodynamics and heat and mass transfer in laminar free convection, accelerating film boiling and condensation of Newtonian fluids, as well as accelerating film flow of non-Newtonian power-law fluids (FFNF). These new developments provided in this book are (i) novel system of analysis models based on the developed New Similarity Analysis Method; (ii) a system of advanced methods for treatment of gas temperature- dependent physical properties, and liquid temperature- dependent physical properties; (iii) the organically combined models of the governing mathematical models with those on treatment model of variable physical properties; (iv) rigorous approach of overcoming a challenge on accurate solution of three-point boundary value problem related to two-phase film boiling and condensation; and (v) A pseudo-similarity method of dealing with thermal boundary layer of FFNF for greatly simplifies the heat-transfer analysis and numerical calculati...

  15. Utilization of graph theory in security analysis of power grid

    Directory of Open Access Journals (Sweden)

    Dalibor Válek


    Full Text Available This paper describes way how to use graph theory in security analysis. As an environment is used network of power lines and devices which are included here. Power grid is considered as a system of nodes which make together graph (network. On the simple example is applied Fiedler´s theory which is able to select the most important power lines of whole network. Components related to these lines are logicly ordered and considered by author´s modified analysis. This method has been improved and optimalized for risks related with illegal acts. Each power grid component has been connected with possible kind of attack and every of this device was gradually evaluated by five coefficients which takes values from 1 to 10. On the coefficient basis was assessed the level of risk. In the last phase the most risky power grid components have been selected. On the selected devices have been proposed security measures.

  16. Mathematical theory of compressible viscous fluids analysis and numerics

    CERN Document Server

    Feireisl, Eduard; Pokorný, Milan


    This book offers an essential introduction to the mathematical theory of compressible viscous fluids. The main goal is to present analytical methods from the perspective of their numerical applications. Accordingly, we introduce the principal theoretical tools needed to handle well-posedness of the underlying Navier-Stokes system, study the problems of sequential stability, and, lastly, construct solutions by means of an implicit numerical scheme. Offering a unique contribution – by exploring in detail the “synergy” of analytical and numerical methods – the book offers a valuable resource for graduate students in mathematics and researchers working in mathematical fluid mechanics. Mathematical fluid mechanics concerns problems that are closely connected to real-world applications and is also an important part of the theory of partial differential equations and numerical analysis in general. This book highlights the fact that numerical and mathematical analysis are not two separate fields of mathematic...

  17. An introduction to queueing theory modeling and analysis in applications

    CERN Document Server

    Bhat, U Narayan


    This introductory textbook is designed for a one-semester course on queueing theory that does not require a course on stochastic processes as a prerequisite. By integrating the necessary background on stochastic processes with the analysis of models, the work provides a sound foundational introduction to the modeling and analysis of queueing systems for a wide interdisciplinary audience of students in mathematics, statistics, and applied disciplines such as computer science, operations research, and engineering. This edition includes additional topics in methodology and applications. Key features: • An introductory chapter including a historical account of the growth of queueing theory in more than 100 years. • A modeling-based approach with emphasis on identification of models. • Rigorous treatment of the foundations of basic models commonly used in applications with appropriate references for advanced topics. • Applications in manufacturing and, computer and communication systems. • A chapter on ...

  18. Computer aided heat transfer analysis in a laboratory scaled heat exchanger unit

    International Nuclear Information System (INIS)

    Gunes, M.


    In this study. an explanation of a laboratory scaled heat exchanger unit and a software which is developed to analyze heat transfer. especially to use it in heat transfer courses, are represented. Analyses carried out in the software through sample values measured in the heat exchanger are: (l) Determination of heat transfer rate, logarithmic mean temperature difference and overall heat transfer coefficient; (2)Determination of convection heat transfer coefficient inside and outside the tube and the effect of fluid velocity on these; (3)Investigation of the relationship between Nusselt Number. Reynolds Number and Prandtl Number by using multiple non-linear regression analysis. Results are displayed on the screen graphically

  19. Conceptual and critical analysis of the Implicit Leadership Theory


    Hernández Avilés, Omar David; García Ramos, Tania


    The purpose of this essay is to present a conceptual and critical analysis of the Implicit Leadership Theory (ILT). The objectives are: 1) explaining the main concepts of the ILT; 2) explaining the main processes of the ILT; 3) identifying constructivist assumptions in the ILT; 4) identifying constructionist assumptions in the ILT, and 5) analyzing critically theoretical assumptions of the ILT. At analyzing constructivism and constructionism assumptions in the ILP, the constructivist leadersh...

  20. Theory analysis and simple calculation of travelling wave burnup scheme

    International Nuclear Information System (INIS)

    Zhang Jian; Yu Hong; Gang Zhi


    Travelling wave burnup scheme is a new burnup scheme that breeds fuel locally just before it burns. Based on the preliminary theory analysis, the physical imagine was found. Through the calculation of a R-z cylinder travelling wave reactor core with ERANOS code system, the basic physical characteristics of this new burnup scheme were concluded. The results show that travelling wave reactor is feasible in physics, and there are some good features in the reactor physics. (authors)

  1. Does Working Memory Training Transfer? A Meta-Analysis Including Training Conditions as Moderators (United States)

    Schwaighofer, Matthias; Fischer, Frank; Bühner, Markus


    A meta-analysis was undertaken to reexamine near- and far-transfer effects following working-memory training and to consider potential moderators more systematically. Forty-seven studies with 65 group comparisons were included in the meta-analysis. Results showed near-transfer effects to short-term and working-memory skills that were sustained at…

  2. Developing interprofessional education online: An ecological systems theory analysis. (United States)

    Bluteau, Patricia; Clouder, Lynn; Cureton, Debra


    This article relates the findings of a discourse analysis of an online asynchronous interprofessional learning initiative involving two UK universities. The impact of the initiative is traced over three intensive periods of online interaction, each of several-weeks duration occurring over a three-year period, through an analysis of a random sample of discussion forum threads. The corpus of rich data drawn from the forums is interpreted using ecological systems theory, which highlights the complexity of interaction of individual, social and cultural elements. Ecological systems theory adopts a life course approach to understand how development occurs through processes of progressively more complex reciprocal interaction between people and their environment. This lens provides a novel approach for analysis and interpretation of findings with respect to the impact of pre-registration interprofessional education and the interaction between the individual and their social and cultural contexts as they progress through 3/4 years of their programmes. Development is mapped over time (the chronosystem) to highlight the complexity of interaction across microsystems (individual), mesosystems (curriculum and institutional/care settings), exosystems (community/wider local context), and macrosystems (national context and culture). This article illustrates the intricacies of students' interprofessional development over time and the interactive effects of social ecological components in terms of professional knowledge and understanding, wider appreciation of health and social care culture and identity work. The implications for contemporary pre-registration interprofessional education and the usefulness and applicability of ecological systems theory for future research and development are considered.

  3. About Navier-Stokes Equation in the Theory of Convective Heat Transfer (United States)

    Davidzon, M. Y.


    A system of differential equations (Navier-Stokes, continuity, heat conductivity) is used to solve convective heat transfer problems. While solving Navier-Stokes equation, it is usually assumed that tangent stress is proportional to the velocity gradient. This assumption is valid with a small velocity gradient, for example, near an axis of the channel, but velocity gradient can be very large near the channel wall. Our paper shows that if we accept power law instead of linear law for tangential stress, then the velocity profile for creeping, laminar, and turbulent flow in the channel can be calculated without using Navier-Stokes equation. Also, in this case Navier-Stokes equation itself changes: the coefficient of dynamic viscosity changes its value from normal (in case of the creeping flow) to tending to infinity (in case of the well-developed turbulent flow).

  4. Transfer matrix theory of monolayer graphene/bilayer graphene heterostructure superlattice

    International Nuclear Information System (INIS)

    Wang, Yu


    We have formulated a transfer matrix method to investigate electronic properties of graphene heterostructure consisting of monolayer graphene and bilayer counterpart. By evaluating transmission, conductance, and band dispersion, we show that, irrespective of the different carrier chiralities in monolayer graphene and bilayer graphene, superlattice consisting of biased bilayer graphene barrier and monolayer graphene well can mimic the electronic properties of conventional semiconductor superlattice, displaying the extended subbands in the quantum tunneling regime and producing anisotropic minigaps for the classically allowed transport. Due to the lateral confinement, the lowest mode has shifted away from the charge neutral point of monolayer graphene component, opening a sizeable gap in concerned structure. Following the gate-field and geometry modulation, all electronic states and gaps between them can be externally engineered in an electric-controllable strategy.

  5. Communicating through Probabilities: Does Quantum Theory Optimize the Transfer of Information?

    Directory of Open Access Journals (Sweden)

    William K. Wootters


    Full Text Available A quantum measurement can be regarded as a communication channel, in which the parameters of the state are expressed only in the probabilities of the outcomes of the measurement. We begin this paper by considering, in a non-quantum-mechanical setting, the problem of communicating through probabilities. For example, a sender, Alice, wants to convey to a receiver, Bob, the value of a continuous variable, θ, but her only means of conveying this value is by sending Bob a coin in which the value of θ is encoded in the probability of heads. We ask what the optimal encoding is when Bob will be allowed to flip the coin only a finite number of times. As the number of tosses goes to infinity, we find that the optimal encoding is the same as what nature would do if we lived in a world governed by real-vector-space quantum theory. We then ask whether the problem might be modified, so that the optimal communication strategy would be consistent with standard, complex-vector-space quantum theory.

  6. Extending stakeholder theory to promote resource management initiatives to key stakeholders: a case study of water transfers in Alberta, Canada. (United States)

    Lafreniere, Katherine C; Deshpande, Sameer; Bjornlund, Henning; Hunter, M Gordon


    Many attempts to implement resource management initiatives in Canadian and international communities have been resisted by stakeholders despite inclusion of their representatives in the decision-making process. Managers' failure to understand stakeholders' perspectives when proposing initiatives is a potential cause of this resistance. Our study uses marketing thought to enhance stakeholder theory by bringing in an audience-centric perspective. We attempt to understand how stakeholders perceive their interests in an organization and consequently decide how to influence that organization. By doing so, we investigate whether a disconnect exists between the perceptions of managers and those of stakeholders. Natural resource managers can utilize this knowledge to garner stakeholder support for the organization and its activities. We support this claim with findings from a water transfer plebiscite held in the Canadian province of Alberta. Sixteen personal interviews employing narrative inquiry were conducted to document voters' (i.e., irrigators') interpretations. Copyright © 2013 Elsevier Ltd. All rights reserved.

  7. Solution of functional equations and reduction of dimension in the local energy transfer theory of incompressible, three-dimensional turbulence (United States)

    Oberlack, M.; McComb, W. D.; Quinn, A. P.


    It is shown that the set of integrodifferential and algebraic functional equations of the local energy transfer theory may be considerably reduced in dimension for the case of isotropic turbulence. This is achieved without restricting the solution space. The basis for this is a complete analytical solution to the functional equations Q(kt,t')=H(kt,t')Q(kt',t') and H(kt,s)H(ks,t')=H(kt,t'). The solution is proved to depend only on a single function φ(kt) solely determining Q and H. Hence the dimension of both the dependent and the independent variables is reduced by one. From the latter, the corresponding two integrodifferential equations are lowered to a single integrodifferential equation for φ(kt), extended by an integral side condition on the k dependence of φ(kt). In the limit ν-->0, a partial solution to the reduced set of equations is presented in the Appendix.

  8. Pattern theory the stochastic analysis of real-world signals

    CERN Document Server

    Mumford, David


    Pattern theory is a distinctive approach to the analysis of all forms of real-world signals. At its core is the design of a large variety of probabilistic models whose samples reproduce the look and feel of the real signals, their patterns, and their variability. Bayesian statistical inference then allows you to apply these models in the analysis of new signals. This book treats the mathematical tools, the models themselves, and the computational algorithms for applying statistics to analyze six representative classes of signals of increasing complexity. The book covers patterns in text, sound

  9. Discrete ordinate theory of radiative transfer. 2: Scattering from maritime haze (United States)

    Kattawar, G. W.; Plass, G. N.; Catchings, F. E.


    Discrete ordinate theory was used to calculate the reflected and transmitted radiance of photons which have interacted with plane parallel maritime haze layers. The results are presented for three solar zenith angles, three values of the surface albedo, and a range of optical thicknesses from very thin to very thick. The diffuse flux at the lower boundary and the cloud albedo were tabulated. The forward peak and other features in the single scattered phase function caused the radiance in many cases to be very different from that for Rayleigh scattering. The variation of the radiance with both the zenith or nadir angle and the azimuthal angle is more marked, and the relative limb darkening under very thick layers is greater, for haze than for Rayleigh scattering. The downward diffuse flux at the lower boundary for A = O is always greater and the cloud albedo is always less for haze than for Rayleigh layers.

  10. The Theory of Laser Materials Processing Heat and Mass Transfer in Modern Technology

    CERN Document Server

    Dowden, John


    The purpose of the book is to show how general principles can be used to obtain insight into laser processes. The principles used may come from fundamental physical theory or from direct observation of experimental results, but an understanding of the general characteristics of the behaviour of a process is essential for intelligent investigation and implementation, whether the approach is experimental, observational, numerical or analytical. The last two have a special value since the associated costs can be relatively low and may be used as a starting point for more expensive techniques. The construction of simple models whose underlying principles are easy to see is therefore of special value, and an understanding of their strengths and limitations is essential. The applications considered in detail are cutting, keyhole welding, drilling, arc and hybrid laser-arc welding, hardening, cladding, forming and cutting, but the general principles have a very wide application; metallurgical aspects are considered,...

  11. The theory of laser materials processing heat and mass transfer in modern technology

    CERN Document Server

    Schulz, Wolfgang


    The revised edition of this important reference volume presents an expanded overview of the analytical and numerical approaches employed when exploring and developing modern laser materials processing techniques. The book shows how general principles can be used to obtain insight into laser processes, whether derived from fundamental physical theory or from direct observation of experimental results. The book gives readers an understanding of the strengths and limitations of simple numerical and analytical models that can then be used as the starting-point for more elaborate models of specific practical, theoretical or commercial value. Following an introduction to the mathematical formulation of some relevant classes of physical ideas, the core of the book consists of chapters addressing key applications in detail: cutting, keyhole welding, drilling, arc and hybrid laser-arc welding, hardening, cladding and forming. The second edition includes a new a chapter on glass cutting with lasers, as employed in the ...

  12. Density functional theory of electron transfer beyond the Born-Oppenheimer approximation: Case study of LiF. (United States)

    Li, Chen; Requist, Ryan; Gross, E K U


    We perform model calculations for a stretched LiF molecule, demonstrating that nonadiabatic charge transfer effects can be accurately and seamlessly described within a density functional framework. In alkali halides like LiF, there is an abrupt change in the ground state electronic distribution due to an electron transfer at a critical bond length R = R c , where an avoided crossing of the lowest adiabatic potential energy surfaces calls the validity of the Born-Oppenheimer approximation into doubt. Modeling the R-dependent electronic structure of LiF within a two-site Hubbard model, we find that nonadiabatic electron-nuclear coupling produces a sizable elongation of the critical R c by 0.5 bohr. This effect is very accurately captured by a simple and rigorously derived correction, with an M -1 prefactor, to the exchange-correlation potential in density functional theory, M = reduced nuclear mass. Since this nonadiabatic term depends on gradients of the nuclear wave function and conditional electronic density, ∇ R χ(R) and ∇ R n(r, R), it couples the Kohn-Sham equations at neighboring R points. Motivated by an observed localization of nonadiabatic effects in nuclear configuration space, we propose a local conditional density approximation-an approximation that reduces the search for nonadiabatic density functionals to the search for a single function y(n).

  13. Do pattern recognition skills transfer across sports? A preliminary analysis. (United States)

    Smeeton, Nicholas J; Ward, Paul; Williams, A Mark


    The ability to recognize patterns of play is fundamental to performance in team sports. While typically assumed to be domain-specific, pattern recognition skills may transfer from one sport to another if similarities exist in the perceptual features and their relations and/or the strategies used to encode and retrieve relevant information. A transfer paradigm was employed to compare skilled and less skilled soccer, field hockey and volleyball players' pattern recognition skills. Participants viewed structured and unstructured action sequences from each sport, half of which were randomly represented with clips not previously seen. The task was to identify previously viewed action sequences quickly and accurately. Transfer of pattern recognition skill was dependent on the participant's skill, sport practised, nature of the task and degree of structure. The skilled soccer and hockey players were quicker than the skilled volleyball players at recognizing structured soccer and hockey action sequences. Performance differences were not observed on the structured volleyball trials between the skilled soccer, field hockey and volleyball players. The skilled field hockey and soccer players were able to transfer perceptual information or strategies between their respective sports. The less skilled participants' results were less clear. Implications for domain-specific expertise, transfer and diversity across domains are discussed.

  14. Principle-based concept analysis: intentionality in holistic nursing theories. (United States)

    Aghebati, Nahid; Mohammadi, Eesa; Ahmadi, Fazlollah; Noaparast, Khosrow Bagheri


    This is a report of a principle-based concept analysis of intentionality in holistic nursing theories. A principle-based concept analysis method was used to analyze seven holistic theories. The data included eight books and 31 articles (1998-2011), which were retrieved through MEDLINE and CINAHL. Erickson, Kriger, Parse, Watson, and Zahourek define intentionality as a capacity, a focused consciousness, and a pattern of human being. Rogers and Newman do not explicitly mention intentionality; however, they do explain pattern and consciousness (epistemology). Intentionality has been operationalized as a core concept of nurse-client relationships (pragmatic). The theories are consistent on intentionality as a noun and as an attribute of the person-intentionality is different from intent and intention (linguistic). There is ambiguity concerning the boundaries between intentionality and consciousness (logic). Theoretically, intentionality is an evolutionary capacity to integrate human awareness and experience. Because intentionality is an individualized concept, we introduced it as "a matrix of continuous known changes" that emerges in two forms: as a capacity of human being and as a capacity of transpersonal caring. This study has produced a theoretical definition of intentionality and provides a foundation for future research to further investigate intentionality to better delineate its boundaries. © The Author(s) 2014.

  15. Analysis of forced convection heat transfer to supercritical carbon dioxide

    International Nuclear Information System (INIS)

    Ko, H.S.; Sakurai, Katsumi; Okamoto, Koji; Madarame, Haruki


    The supercritical carbon dioxide flow has been visualized under forced convection by a Mach-Zehnder interferometry system. The forced convection heat transfer has been examined by an one-sided wall heater in the vertical rectangular test section. Temperature and density distributions of the heated carbon dioxide inside the test section have been calculated from the measured interferometry projections for the visible interferograms conditions. The relationship of the temperature distributions with the physical conditions has been analyzed to inspect the forced convection heat transfer of the supercritical carbon dioxide flow. (author)

  16. A cooperative game theory analysis for transmission loss allocation

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Delberis A.; Padilha-Feltrin, Antonio [Universidade Estadual Paulista, Campus de Ilha Solteira, Av. Brasil 56, CEP 15385-000 Ilha Solteira, SP (Brazil); Contreras, Javier [Universidad de Castilla-La Mancha, E.T.S. de Ingenieros Industriales, Campus Universitario s/n, 13071 Ciudad Real (Spain)


    This paper presents an analysis and discussion, based on cooperative game theory, for the allocation of the cost of losses to generators and demands in transmission systems. We construct a cooperative game theory model in which the players are represented by equivalent bilateral exchanges and we search for a unique loss allocation solution, the Core. Other solution concepts, such as the Shapley Value, the Bilateral Shapley Value and the Kernel are also explored. Our main objective is to illustrate why is not possible to find an optimal solution for allocating the cost of losses to the users of a network. Results and relevant conclusions are presented for a 4-bus system and a 14-bus system. (author)

  17. Thought analysis on self-organization theories of MHD plasma

    International Nuclear Information System (INIS)

    Kondoh, Yoshiomi; Sato, Tetsuya.


    A thought analysis on the self-organization theories of dissipative MHD plasma is presented to lead to three groups of theories that lead to the same relaxed state of ∇ x B = λB, in order to find an essential physical picture embedded in the self-organization phenomena due to nonlinear and dissipative processes. The self-organized relaxed state due to the dissipation by the Ohm loss is shown to be formulated generally as the state such that yields the minimum dissipation rate of global auto-and/or cross-correlations between two quantities in j, B, and A for their own instantaneous values of the global correlations. (author)


    Directory of Open Access Journals (Sweden)

    Andreea IANCU


    Full Text Available This paper analyzes the Responsibility to protect principle as the paradigm that reinforces the just war theory in the current international relations. The importance of this analysis is given by the fact that in the current change of source of international conflicts, the Responsibility to protect principle affirms the responsibility of the international community to protect all the citizens of the world. In this context we witness a translation toward a Post-Westphalian international system, which values the individual as a security referent. This article discusses the origins of the responsibility to protect principle and problematizes (discusses the legitimacy of use of violence and force in the current international system. Moreover, the paper analyzes the possible humanization of the current international relations and, simultaneously, the persistency of conflict and warfare in the international system. The conclusion of this research states that the Responsibility to protect principle revises the just war theory by centering it on the individual.

  19. A game theory analysis of green infrastructure stormwater management policies (United States)

    William, Reshmina; Garg, Jugal; Stillwell, Ashlynn S.


    Green stormwater infrastructure has been demonstrated as an innovative water resources management approach that addresses multiple challenges facing urban environments. However, there is little consensus on what policy strategies can be used to best incentivize green infrastructure adoption by private landowners. Game theory, an analysis framework that has historically been under-utilized within the context of stormwater management, is uniquely suited to address this policy question. We used a cooperative game theory framework to investigate the potential impacts of different policy strategies used to incentivize green infrastructure installation. The results indicate that municipal regulation leads to the greatest reduction in pollutant loading. However, the choice of the "best" regulatory approach will depend on a variety of different factors including politics and financial considerations. Large, downstream agents have a disproportionate share of bargaining power. Results also reveal that policy impacts are highly dependent on agents' spatial position within the stormwater network, leading to important questions of social equity and environmental justice.

  20. Human factors and fuzzy set theory for safety analysis

    International Nuclear Information System (INIS)

    Nishiwaki, Y.


    Human reliability and performance is affected by many factors: medical, physiological and psychological, etc. The uncertainty involved in human factors may not necessarily be probabilistic, but fuzzy. Therefore, it is important to develop a theory by which both the non-probabilistic uncertainties, or fuzziness, of human factors and the probabilistic properties of machines can be treated consistently. In reality, randomness and fuzziness are sometimes mixed. From the mathematical point of view, probabilistic measures may be considered a special case of fuzzy measures. Therefore, fuzzy set theory seems to be an effective tool for analysing man-machine systems. The concept 'failure possibility' based on fuzzy sets is suggested as an approach to safety analysis and fault diagnosis of a large complex system. Fuzzy measures and fuzzy integrals are introduced and their possible applications are also discussed. (author)

  1. Sensitivity theory for reactor burnup analysis based on depletion perturbation theory

    International Nuclear Information System (INIS)

    Yang, Wonsik.


    The large computational effort involved in the design and analysis of advanced reactor configurations motivated the development of Depletion Perturbation Theory (DPT) for general fuel cycle analysis. The work here focused on two important advances in the current methods. First, the adjoint equations were developed for using the efficient linear flux approximation to decouple the neutron/nuclide field equations. And second, DPT was extended to the constrained equilibrium cycle which is important for the consistent comparison and evaluation of alternative reactor designs. Practical strategies were formulated for solving the resulting adjoint equations and a computer code was developed for practical applications. In all cases analyzed, the sensitivity coefficients generated by DPT were in excellent agreement with the results of exact calculations. The work here indicates that for a given core response, the sensitivity coefficients to all input parameters can be computed by DPT with a computational effort similar to a single forward depletion calculation

  2. The Contributions of Applied Behavior Analysis and Behavior Theory to Innovative Research and Practice Cultures in Social Work. (United States)

    Briggs, Harold Eugene; Sharkey, Caroline; Briggs, Adam Christopher


    In this article the authors tie the emergence of an empirical practice research culture, which enabled the rise in evidence-based practice in social work to the introduction of applied behavior analysis and behavioral theory to social work practice and research. The authors chronicle the: (1) scientific foundations of social work, (2) influence and push by corporatized university cultures for higher scholarship productivity among faculty, (3) significance of theory in general, (4) importance of behavioral theory in particular as a major trigger of the growth in research on effective social work practice approaches, and (5) commonalities between applied behavior analysis and evidence-based practice. The authors conclude with implications for addressing the dual challenges of building an enhanced research culture in schools of social work and the scholarship of transferring practice research to adoption in real world practice settings.

  3. Identifying and Retaining Quality Naval Officers: A Quantitative Analysis of Job Matching and Lateral Transfers (United States)


    complete a lateral transfer. Additionally, his research does not support any differences in promotion rates between genders , reflecting similar promotion ...accurate approach to assess job match would be to compare officers’ relative outcomes (in terms of retention and promotion ) pre-lateral transfer versus...RETAINING QUALITY NAVAL OFFICERS: A QUANTITATIVE ANALYSIS OF JOB MATCHING AND LATERAL TRANSFERS by Giuliana M. Vellucci March 2017 Thesis

  4. Reverse Transfer: Paving the Pathway. ECS Education Policy Analysis (United States)

    Anderson, Lexi


    States are taking several distinct approaches to implement reverse transfer policies. Although contextualized by state-specific factors, approaches to policy implementation commonly include determination of a group or regulatory body responsible for policy oversight, technology, funding and identification of students eligible to participate in…

  5. Analysis of adiabatic transfer in cavity quantum electrodynamics

    Indian Academy of Sciences (India)

    A three-level atom in a configuration trapped in an optical cavity forms a basic unit in a number of proposed protocols for quantum information processing. This system allows for efficient storage of cavity photons into long-lived atomic excitations, and their retrieval with high fidelity, in an adiabatic transfer process through ...

  6. Analysis of slip flow heat transfer between two unsymmetrically ...

    Indian Academy of Sciences (India)

    This paper presents an analytical investigation to study the heat transfer and fluid flow characteristics in the slip flow region for hydrodynamically and thermally fully developed flow between parallel plates.Both upper and lower plates are subjected to asymmetric heat flux boundary conditions. The effect of first ordervelocity ...

  7. Analysis of adiabatic transfer in cavity quantum electrodynamics

    Indian Academy of Sciences (India)

    study the full quantum mechanics of this transfer process with a view to examine the non-adiabatic effects arising from inevitable excitations of the system to states involving the upper level of , which is radiative. We find that the fidelity of storage is better, the stronger the control field and the slower the rate of its switching off.

  8. Computational heat transfer analysis and combined ANN–GA ...

    Indian Academy of Sciences (India)


    Aug 26, 2016 ... In the devices like laptops, microprocessors, the electric circuits generate heat while performing work which necessitates the use of fins. In the present work, the heat transfer characteristics of hollow cylindrical pin fin array on a vertical rectangular base plate is studied using commercial CFD code ANSYS ...

  9. Computational heat transfer analysis and combined ANN–GA ...

    Indian Academy of Sciences (India)

    In the devices like laptops, microprocessors, the electric circuits generate heat while performing work which necessitates the use of fins. In the present work, the heat transfer characteristics of hollow cylindrical pin fin array on a vertical rectangular base plate is studied using commercial CFD code ANSYS FLUENT© .

  10. Mass transfer analysis for terephthalic acid biodegradation by ...

    African Journals Online (AJOL)

    Biodegradation of terephthalic acid (TA) by polyvinyl alcohol (PVA)-alginate immobilized Pseudomonas sp. was carried out in a packed-bed reactor. The effect of inlet TA concentration on biodegradation was investigated at 30°C, pH 7 and flow rate of 20 ml/min. The effects of flow rate on mass transfer and biodegradation ...

  11. Phenomenological Analysis of Rationale for School Transfer Credit Policies (United States)

    Melton, Amye M.


    Students face challenges when attempting to transfer college credits; sometimes, the process results in having to retake classes already completed at another institution. A qualitative phenomenological study, grounded in an advocacy/participatory worldview, was used to explore how leaders of higher learning institutions determined reasons academic…

  12. Combining UV photodissociation with electron transfer for peptide structure analysis

    Czech Academy of Sciences Publication Activity Database

    Shaffer, C. J.; Marek, Aleš; Pepin, R.; Slováková, K.; Tureček, F.


    Roč. 50, č. 3 (2015), s. 470-475 ISSN 1076-5174 Institutional support: RVO:61388963 Keywords : electron transfer dissociation * laser photodissociation * peptide ions * cation radical * chromophores * isomer distinction Subject RIV: CE - Biochemistry Impact factor: 2.541, year: 2015

  13. Building Technology Transfer Capacity in Turkish Universities: A Critical Analysis (United States)

    Ranga, Marina; Temel, Serdal; Ar, Ilker Murat; Yesilay, Rustem Baris; Sukan, Fazilet Vardar


    University technology transfer has been receiving significant government funding since 2012. Results of this major investment are now expected by the Turkish government and society, not only in terms of better teaching and research performance, but also of new jobs, new products and services, enhanced regional development and contribution to…

  14. Development of platform to compare different wall heat transfer packages for system analysis codes

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Min-Gil; Lee, Won Woong; Lee, Jeong Ik [KAIST, Daejeon (Korea, Republic of); Shin, Sung Gil [Hanyang University, Seoul (Korea, Republic of)


    System thermal hydraulic (STH) analysis code is used for analyzing and evaluating the safety of a designed nuclear system. The system thermal hydraulic analysis code typically solves mass, momentum and energy conservation equations for multiple phases with sets of selected empirical constitutive equations to close the problem. Several STH codes are utilized in academia, industry and regulators, such as MARS-KS, SPACE, RELAP5, COBRA-TF, TRACE, and so on. Each system thermal hydraulic code consists of different sets of governing equations and correlations. However, the packages and sets of correlations of each code are not compared quantitatively yet. Wall heat transfer mode transition maps of SPACE and MARS-KS have a little difference for the transition from wall nucleate heat transfer mode to wall film heat transfer mode. Both codes have the same heat transfer packages and correlations in most region except for wall film heat transfer mode. Most of heat transfer coefficients calculated for the range of selected variables of SPACE are the same with those of MARS-KS. For the intervals between 500K and 540K of wall temperature, MARS-KS selects the wall film heat transfer mode and Bromley correlation but SPACE select the wall nucleate heat transfer mode and Chen correlation. This is because the transition from nucleate boiling to film boiling of MARS-KS is earlier than SPACE. More detailed analysis of the heat transfer package and flow regime package will be followed in the near future.

  15. Development of platform to compare different wall heat transfer packages for system analysis codes

    International Nuclear Information System (INIS)

    Kim, Min-Gil; Lee, Won Woong; Lee, Jeong Ik; Shin, Sung Gil


    System thermal hydraulic (STH) analysis code is used for analyzing and evaluating the safety of a designed nuclear system. The system thermal hydraulic analysis code typically solves mass, momentum and energy conservation equations for multiple phases with sets of selected empirical constitutive equations to close the problem. Several STH codes are utilized in academia, industry and regulators, such as MARS-KS, SPACE, RELAP5, COBRA-TF, TRACE, and so on. Each system thermal hydraulic code consists of different sets of governing equations and correlations. However, the packages and sets of correlations of each code are not compared quantitatively yet. Wall heat transfer mode transition maps of SPACE and MARS-KS have a little difference for the transition from wall nucleate heat transfer mode to wall film heat transfer mode. Both codes have the same heat transfer packages and correlations in most region except for wall film heat transfer mode. Most of heat transfer coefficients calculated for the range of selected variables of SPACE are the same with those of MARS-KS. For the intervals between 500K and 540K of wall temperature, MARS-KS selects the wall film heat transfer mode and Bromley correlation but SPACE select the wall nucleate heat transfer mode and Chen correlation. This is because the transition from nucleate boiling to film boiling of MARS-KS is earlier than SPACE. More detailed analysis of the heat transfer package and flow regime package will be followed in the near future

  16. Stepped-frequency radar sensors theory, analysis and design

    CERN Document Server

    Nguyen, Cam


    This book presents the theory, analysis and design of microwave stepped-frequency radar sensors. Stepped-frequency radar sensors are attractive for various sensing applications that require fine resolution. The book consists of five chapters. The first chapter describes the fundamentals of radar sensors including applications followed by a review of ultra-wideband pulsed, frequency-modulated continuous-wave (FMCW), and stepped-frequency radar sensors. The second chapter discusses a general analysis of radar sensors including wave propagation in media and scattering on targets, as well as the radar equation. The third chapter addresses the analysis of stepped-frequency radar sensors including their principles and design parameters. Chapter 4 presents the development of two stepped-frequency radar sensors at microwave and millimeter-wave frequencies based on microwave integrated circuits (MICs), microwave monolithic integrated circuits (MMICs) and printed-circuit antennas, and discusses their signal processing....

  17. Dimensional analysis, similarity, analogy, and the simulation theory

    International Nuclear Information System (INIS)

    Davis, A.A.


    Dimensional analysis, similarity, analogy, and cybernetics are shown to be four consecutive steps in application of the simulation theory. This paper introduces the classes of phenomena which follow the same formal mathematical equations as models of the natural laws and the interior sphere of restraints groups of phenomena in which one can introduce simplfied nondimensional mathematical equations. The simulation by similarity in a specific field of physics, by analogy in two or more different fields of physics, and by cybernetics in nature in two or more fields of mathematics, physics, biology, economics, politics, sociology, etc., appears as a unique theory which permits one to transport the results of experiments from the models, convenably selected to meet the conditions of researches, constructions, and measurements in the laboratories to the originals which are the primary objectives of the researches. Some interesting conclusions which cannot be avoided in the use of simplified nondimensional mathematical equations as models of natural laws are presented. Interesting limitations on the use of simulation theory based on assumed simplifications are recognized. This paper shows as necessary, in scientific research, that one write mathematical models of general laws which will be applied to nature in its entirety. The paper proposes the extent of the second law of thermodynamics as the generalized law of entropy to model life and its activities. This paper shows that the physical studies and philosophical interpretations of phenomena and natural laws cannot be separated in scientific work; they are interconnected and one cannot be put above the others

  18. Statistical Analysis of Designed Experiments Theory and Applications

    CERN Document Server

    Tamhane, Ajit C


    A indispensable guide to understanding and designing modern experiments The tools and techniques of Design of Experiments (DOE) allow researchers to successfully collect, analyze, and interpret data across a wide array of disciplines. Statistical Analysis of Designed Experiments provides a modern and balanced treatment of DOE methodology with thorough coverage of the underlying theory and standard designs of experiments, guiding the reader through applications to research in various fields such as engineering, medicine, business, and the social sciences. The book supplies a foundation for the

  19. Linearly Polarized IR Spectroscopy Theory and Applications for Structural Analysis

    CERN Document Server

    Kolev, Tsonko


    A technique that is useful in the study of pharmaceutical products and biological molecules, polarization IR spectroscopy has undergone continuous development since it first emerged almost 100 years ago. Capturing the state of the science as it exists today, "Linearly Polarized IR Spectroscopy: Theory and Applications for Structural Analysis" demonstrates how the technique can be properly utilized to obtain important information about the structure and spectral properties of oriented compounds. The book starts with the theoretical basis of linear-dichroic infrared (IR-LD) spectroscop

  20. Quality of life in contemporary nursing theory: a concept analysis. (United States)

    Plummer, Marilyn; Molzahn, Anita E


    A critical appraisal of the concept, quality of life, as used in nursing theories, is presented in a historically situated context. This approach to concept analysis was selected to illuminate the subjective, contextual, and fluid nature of the concept. Based on this review, quality of life is defined as an intangible, subjective perception of one's lived experience. From a review of Peplau's, Rogers', Leininger's, King's, and Parse's conceptualizations of quality of life, it is concluded that it may be viable to replace health with quality of life as a metaparadigm concept for nursing.

  1. Correlation analysis of transient heat transfer characteristics for air precooling aggregate (United States)

    Guo, Chaohong; Zeng, Miao; Lu, Fei; Tang, Dawei; Guan, Wei; Li, Li; Fu, Tingwu


    In dam works, air precooling of aggregate is a common and effective method to avoid temperature cracks in concrete structure. In order to offer a reliable design theory for the air precooling process to avoid unreasonable energy consumption, the transient heat transfer characteristics of the aggregate are intensively analyzed. The combined structure of the aggregate and the interstitial space in the hopper is treated as a porous structure, and the space-average method is used to simulate the transient heat transfer process. Simulation results show that size of the hopper and the average air velocity in the cross section have great influence on the transient heat transfer process of the aggregate, while the porosity in the range of 0.4‒0.5 has little influence. Nomograms are abstracted from simulation results, and then correlations of the compared excess temperature are precisely fitted to predict the air precooling transient heat transfer process of the aggregate.

  2. Effects of Small-Group Learning on Transfer: A Meta-Analysis (United States)

    Pai, Hui-Hua; Sears, David A.; Maeda, Yukiko


    This study investigated the potential benefit of small-group learning on transfer performance using the method of meta-analysis. Results showed positive support for the hypothesis that small-group learning can increase students' transfer performance (average effect size of 0.30). Unlike reviews of effects of cooperation on learning, this…

  3. Heat Transfer Analysis of Thermal Protection Structures for Hypersonic Vehicles (United States)

    Zhou, Chen; Wang, Zhijin; Hou, Tianjiao


    This research aims to develop an analytical approach to study the heat transfer problem of thermal protection systems (TPS) for hypersonic vehicles. Laplace transform and integral method are used to describe the temperature distribution through the TPS subject to aerodynamic heating during flight. Time-dependent incident heat flux is also taken into account. Two different cases with heat flux and radiation boundary conditions are studied and discussed. The results are compared with those obtained by finite element analyses and show a good agreement. Although temperature profiles of such problems can be readily accessed via numerical simulations, analytical solutions give a greater insight into the physical essence of the heat transfer problem. Furthermore, with the analytical approach, rapid thermal analyses and even thermal optimization can be achieved during the preliminary TPS design.

  4. Analysis of the Coupling Coefficient in Inductive Energy Transfer Systems

    Directory of Open Access Journals (Sweden)

    Rafael Mendes Duarte


    Full Text Available In wireless energy transfer systems, the energy is transferred from a power source to an electrical load without the need of physical connections. In this scope, inductive links have been widely studied as a way of implementing these systems. Although high efficiency can be achieved when the system is operating in a static state, it can drastically decrease if changes in the relative position and in the coupling coefficient between the coils occur. In this paper, we analyze the coupling coefficient as a function of the distance between two planar and coaxial coils in wireless energy transfer systems. A simple equation is derived from Neumann’s equation for mutual inductance, which is then used to calculate the coupling coefficient. The coupling coefficient is computed using CST Microwave Studio and compared to calculation and experimental results for two coils with an excitation signal of up to 10 MHz. The results showed that the equation presents good accuracy for geometric parameters that do not lead the solution of the elliptic integral of the first kind to infinity.

  5. Assessment of GIC Based On Transfer Function Analysis (United States)

    Ingham, M.; Rodger, C. J.; Divett, T.; Dalzell, M.; Petersen, T.


    Transfer functions are calculated for periods between 2 and 1,000 min between geomagnetically induced currents (GIC) measured at three transformers in the South Island of New Zealand and variations in the horizontal components of the geomagnetic field measured at the Eyrewell Observatory near Christchurch. Using an inverse Fourier transform, the transfer functions allow the GIC expected in these transformers to be estimated for any variation of the inducing magnetic field. Comparison of the predicted GIC with measured GIC for individual geomagnetic storms shows remarkable agreement, although the lack of high-frequency measurements of GIC and the need for interpolation of the measurements lead to a degree of underestimation of the peak GIC magnitude. An approximate correction for this is suggested. Calculation of the GIC for a magnetic storm in November 2001 that led to the failure of a transformer in Dunedin suggests that peak GIC were as large as about 80 A. Use of spectral scaling to estimate the likely GIC associated with a geomagnetic storm of the magnitude of the 1859 Carrington Event indicates that GIC of at least 10 times this magnitude may occur at some locations. Although the impact of changes to the transmission network on calculated transfer functions remains to be explored, it is suggested that the use of this technique may provide a useful check on estimates of GIC produced by other methods such as thin sheet modeling.

  6. Mass transfer models analysis for the structured packings

    International Nuclear Information System (INIS)

    Suastegui R, A.O.


    The models that have been developing, to understand the mechanism of the mass transfer through the structured packings, present limitations for their application, existing then uncertainty in order to use them in the chemical industrial processes. In this study the main parameters used in the mass transfer are: the hydrodynamic of the bed of the column, the geometry of the bed, physical-chemical properties of the mixture and the flow regime of the operation between the flows liquid-gas. The sensibility of each one of these parameters generate an arduous work to develop right proposals and good interpretation of the phenomenon. With the purpose of showing the importance of these parameters mentioned in the mass transfer, this work is analyzed the process of absorption for the system water-air, using the models to the structured packings in packed columns. The models selected were developed by Bravo and collaborators in 1985 and 1992, in order to determine the parameters previous mentioned for the system water-air, using a structured packing built in the National Institute of Nuclear Research. In this work is showed the results of the models application and their discussion. (Author)

  7. Modelling of simultaneous mass and heat transfer with chemical reaction using the Maxwell-Stefan theory II. Non-isothermal study

    NARCIS (Netherlands)

    Frank, M.J.W.; Frank, M.J.W.; Kuipers, J.A.M.; Krishna, R.; van Swaaij, Willibrordus Petrus Maria


    In Part I a general applicable model has been developed which calculates mass and heat transfer fluxes through a vapour/gas-liquid interface in case a reversible chemical reaction with associated heat effect takes place in the liquid phase. In this model the Maxwell-Stefan theory has been used to

  8. The Transfer of Knowledge in Intra-Organizational Networks: A Case Study Analysis

    Directory of Open Access Journals (Sweden)

    Sroka Włodzimierz


    Full Text Available `Background: In today’s business environment, a company is able to maintain its competitive position if it constantly generates knowledge and disseminates this knowledge within the organization, as well as transforms it into new competences. The ability to transfer knowledge becomes one of the key factors in the improvement of a company’s competitive position. This hypothesis is applicable particularly in the case of cooperation within networks, as they are an excellent opportunity for mutual learning between partners. Objectives: The purpose of the paper is to analyse the process of knowledge transfer in intra-organizational networks. Method: Due to the specificity of the research object, the case study method has been chosen. In order to make an in-depth analysis of the case study, we selected a group of several criteria based on the theory which we believe to be fundamental to the effectiveness of knowledge management in networks, and compared them with the situation in the ArcelorMittal Group. Results: Our research show that ArcelorMittal Group has met almost all the criteria of effective knowledge management in its intra-organizational network. Some exceptions, albeit merely to an extent, are mostly the result of historical circumstances, , i.e. the process of growth through acquisitions, and the acquisition of companies at different stages of organizational development, as well as organizational culture. Conclusion: Based on theoretical assumptions, the study analysed in details the components of knowledge management applied by the corporation in question. Therefore this study might be utilised to formulate a refutable hypothesis and verify them on a larger group of companies from different sectors of the economy. The main limitations of the paper are mostly related to the inherent approach therein

  9. The analysis and evaluation of legal argumentation: approaches from legal theory and argumentation theory

    NARCIS (Netherlands)

    Feteris, E.; Kloosterhuis, H.


    In the past thirty years legal argumentation has become an important interdisciplinary field of interest. The study of legal argumentation draws its data, assumptions and methods from disciplines such as legal theory, legal philosophy, logic, argumentation theory, rhetoric, linguistics, literary

  10. Cultural-Historical Activity Theory and Domain Analysis: Metatheoretical Implications for Information Science (United States)

    Wang, Lin


    Background: Cultural-historical activity theory is an important theory in modern psychology. In recent years, it has drawn more attention from related disciplines including information science. Argument: This paper argues that activity theory and domain analysis which uses the theory as one of its bases could bring about some important…

  11. From hybridization theory to microarray data analysis: performance evaluation

    Directory of Open Access Journals (Sweden)

    Berger Fabrice


    Full Text Available Abstract Background Several preprocessing methods are available for the analysis of Affymetrix Genechips arrays. The most popular algorithms analyze the measured fluorescence intensities with statistical methods. Here we focus on a novel algorithm, AffyILM, available from Bioconductor, which relies on inputs from hybridization thermodynamics and uses an extended Langmuir isotherm model to compute transcript concentrations. These concentrations are then employed in the statistical analysis. We compared the performance of AffyILM and other traditional methods both in the old and in the newest generation of GeneChips. Results Tissue mixture and Latin Square datasets (provided by Affymetrix were used to assess the performances of the differential expression analysis depending on the preprocessing strategy. A correlation analysis conducted on the tissue mixture data reveals that the median-polish algorithm allows to best summarize AffyILM concentrations computed at the probe-level. Those correlation results are equivalent to the best correlations observed using popular preprocessing methods relying on intensity values. The performances of each tested preprocessing algorithm were quantified using the Latin Square HG-U133A dataset, thanks to the comparison of differential analysis results with the list of spiked genes. The figures of merit generated illustrates that the performances associated to AffyILM(medianpolish, inferred from the present statistical analysis, are comparable to the best performing strategies previously reported. Conclusions Converting probe intensities to estimates of target concentrations prior to the statistical analysis, AffyILM(medianpolish is one of the best performing strategy currently available. Using hybridization theory, probe-level estimates of target concentrations should be identically distributed. In the future, a probe-level multivariate analysis of the concentrations should be compared to the univariate analysis of

  12. Vulnerability Analysis of CSP Based on Stochastic Game Theory

    Directory of Open Access Journals (Sweden)

    Jiajun Shen


    Full Text Available With the development of industrial informatization, the industrial control network has gradually become much accessible for attackers. A series of vulnerabilities will therefore be exposed, especially the vulnerability of exclusive industrial communication protocols (ICPs, which has not yet been attached with enough emphasis. In this paper, stochastic game theory is applied on the vulnerability analysis of clock synchronization protocol (CSP, one of the pivotal ICPs. The stochastic game model is built strictly according to the protocol with both Man-in-the-Middle (MIM attack and dependability failures being taken into account. The situation of multiple attack routes is considered for depicting the practical attack scenarios, and the introduction of time aspect characterizes the success probabilities of attackers actions. The vulnerability analysis is then realized through determining the optimal strategies of attacker under different states of system, respectively.

  13. Nodal equivalence theory for hexagonal geometry, thermal reactor analysis

    International Nuclear Information System (INIS)

    Zika, M.; Downar, T.


    An important aspect of advanced nodal methods is the determination of equivalent few-group parameters for the relatively large homogenized regions used in the nodal flux solution. The theoretical foundation for light water reactor (LWR) assembly homogenization methods has been clearly established, and during the last several years, its successes have secured its position in the stable of dependable LWR analysis methods. Groupwise discontinuity factors that correct for assembly homogenization errors are routinely generated along with the group constants during lattice physics analysis. During the last several years, there has been interest in applying equivalence theory to other reactor types and other geometries. A notable effort has been the work at Argonne National Laboratory to incorporate nodal equivalence theory (NET) for hexagonal lattices into the nodal diffusion option of the DIF3D code. This work was originally intended to improve the neutronics methods used for the analysis of the Experimental Breeder Reactor II (EBR-II), and Ref. 4 discusses the success of that application. More recently, however, attempts were made to apply NET to advanced, thermal reactor designs such as the modular high-temperature gas reactor (MHTGR) and the new production heavy water reactor (NPR/HWR). The same methods that were successful for EBR-II have encountered problems for these reactors. Our preliminary analysis indicates that the sharp global flux gradients in these cores requires large discontinuity factors (greater than 4 or 5) to reproduce the reference solution. This disrupts the convergence of the iterative methods used to solve for the node-wise flux moments and partial currents. Several attempts to remedy the problem have been made over the last few years, including bounding the discontinuity factors and providing improved initial guesses for the flux solution, but nothing has been satisfactory

  14. Vibrational spectroscopy and density functional theory analysis of 3-O-caffeoylquinic acid (United States)

    Mishra, Soni; Tandon, Poonam; Eravuchira, Pinkie J.; El-Abassy, Rasha M.; Materny, Arnulf


    Density functional theory (DFT) calculations are being performed to investigate the geometric, vibrational, and electronic properties of the chlorogenic acid isomer 3-CQA (1R,3R,4S,5R)-3-{[(2E)-3-(3,4-dihydroxyphenyl)prop-2-enoyl]oxy}-1,4,5-trihydroxycyclohexanecarboxylic acid), a major phenolic compound in coffee. DFT calculations with the 6-311G(d,p) basis set produce very good results. The electrostatic potential mapped onto an isodensity surface has been obtained. A natural bond orbital analysis (NBO) has been performed in order to study intramolecular bonding, interactions among bonds, and delocalization of unpaired electrons. HOMO-LUMO studies give insights into the interaction of the molecule with other species. The calculated HOMO and LUMO energies indicate that a charge transfer occurs within the molecule.

  15. Numerical verification of composite rods theory on multi-story buildings analysis (United States)

    El-Din Mansour, Alaa; Filatov, Vladimir; Gandzhuntsev, Michael; Ryasny, Nikita


    In the article, a verification proposal of the composite rods theory on the structural analysis of skeletons for high-rise buildings. A testing design model been formed on which horizontal elements been represented by a multilayer cantilever beam operates on transverse bending on which slabs are connected with a moment-non-transferring connections and a multilayer columns represents the vertical elements. Those connections are sufficiently enough to form a shearing action can be approximated by a certain shear forces function, the thing which significantly reduces the overall static indeterminacy degree of the structural model. A system of differential equations describe the operation mechanism of the multilayer rods that solved using the numerical approach of successive approximations method. The proposed methodology to be used while preliminary calculations for the sake of determining the rigidity characteristics of the structure; are needed. In addition, for a qualitative assessment of the results obtained by other methods when performing calculations with the verification aims.

  16. Clarifying and illustrating the electronic energy transfer pathways in trimeric and hexameric aggregation state of cyanobacteria allophycocyanin within the framework of Förster theory. (United States)

    Ren, Yanliang; Melhem, Osama; Li, Yongjian; Chi, Bo; Han, Xinya; Zhu, Hao; Feng, Lingling; Wan, Jian; Xu, Xin


    Within the framework of the Förster theory, the electronic excitation energy transfer pathways in the cyanobacteria allophycocyanin (APC) trimer and hexamer were studied. The associated physical quantities (i.e., excitation energy, oscillator strength, and transition dipole moments) of the phycocyanobilins (PCBs) located in APC were calculated at time-dependent density functional theory (TDDFT) level of theory. To estimate the influence of protein environment on the preceding calculated physical quantities, the long-range interactions were approximately considered with the polarizable continuum model at the TDDFT level of theory, and the short-range interaction caused by surrounding aspartate residue of PCBs were taken into account as well. The shortest energy transfer time calculated in the framework of the Förster model at TDDFT/B3LYP/6-31+G* level of theory are about 0.10 ps in the APC trimer and about 170 ps in the APC monomer, which are in qualitative agreement with the experimental finding that a very fast lifetime of 0.43-0.44 ps in APC trimers, whereas its monomers lacked any corresponding lifetime. These results suggest that the lifetime of 0.43-0.44 ps in the APC trimers determined by Sharkov et al. was most likely attributed to the energy transfer of α(1) -84 ↔ β(3) -84 (0.23 ps), β(1) -84 ↔ α(2) -84 (0.11 ps) or β(2) -84 ↔ α(3) -84 (0.10 ps). So far, no experimental or theoretical energy transfer rates between two APC trimmers were reported, our calculations predict that the predominate energy transfer pathway between APC trimers is likely to occur from α(3) -84 in one trimer to α(5) -84 in an adjacent trimer with a rate of 32.51 ps. © 2014 Wiley Periodicals, Inc.

  17. Anomalous heat transfer modes of nanofluids: a review based on statistical analysis (United States)


    This paper contains the results of a concise statistical review analysis of a large amount of publications regarding the anomalous heat transfer modes of nanofluids. The application of nanofluids as coolants is a novel practise with no established physical foundations explaining the observed anomalous heat transfer. As a consequence, traditional methods of performing a literature review may not be adequate in presenting objectively the results representing the bulk of the available literature. The current literature review analysis aims to resolve the problems faced by researchers in the past by employing an unbiased statistical analysis to present and reveal the current trends and general belief of the scientific community regarding the anomalous heat transfer modes of nanofluids. The thermal performance analysis indicated that statistically there exists a variable enhancement for conduction, convection/mixed heat transfer, pool boiling heat transfer and critical heat flux modes. The most popular proposed mechanisms in the literature to explain heat transfer in nanofluids are revealed, as well as possible trends between nanofluid properties and thermal performance. The review also suggests future experimentation to provide more conclusive answers to the control mechanisms and influential parameters of heat transfer in nanofluids. PMID:21711932


    Directory of Open Access Journals (Sweden)



    Full Text Available In this study, we proposed a newly designed sulfuric acid transfer system for the sulfur-iodine (SI thermochemical cycle. The proposed sulfuric acid transfer system was evaluated using a computational fluid dynamics (CFD analysis for investigating thermodynamic/hydrodynamic characteristics and material properties. This analysis was conducted to obtain reliable continuous operation parameters; in particular, a thermal analysis was performed on the bellows box and bellows at amplitudes and various frequencies (0.1, 0.5, and 1.0 Hz. However, the high temperatures and strongly corrosive operating conditions of the current sulfuric acid system present challenges with respect to the structural materials of the transfer system. To resolve this issue, we designed a novel transfer system using polytetrafluoroethylene (PTFE, Teflon® as a bellows material for the transfer of sulfuric acid. We also carried out a CFD analysis of the design. The CFD results indicated that the maximum applicable temperature of PTFE is about 533 K (260 °C, even though its melting point is around 600 K. This result implies that the PTFE is a potential material for the sulfuric acid transfer system. The CFD simulations also confirmed that the sulfuric acid transfer system was designed properly for this particular investigation.

  19. Game theory based models to analyze water conflicts in the Middle Route of the South-to-North Water Transfer Project in China. (United States)

    Wei, Shouke; Yang, Hong; Abbaspour, Karim; Mousavi, Jamshid; Gnauck, Albrecht


    This study applied game theory based models to analyze and solve water conflicts concerning water allocation and nitrogen reduction in the Middle Route of the South-to-North Water Transfer Project in China. The game simulation comprised two levels, including one main game with five players and four sub-games with each containing three sub-players. We used statistical and econometric regression methods to formulate payoff functions of the players, economic valuation methods (EVMs) to transform non-monetary value into economic one, cost-benefit Analysis (CBA) to compare the game outcomes, and scenario analysis to investigate the future uncertainties. The validity of game simulation was evaluated by comparing predictions with observations. The main results proved that cooperation would make the players collectively better off, though some player would face losses. However, players were not willing to cooperate, which would result in a prisoners' dilemma. Scenarios simulation results displayed that players in water scare area could not solve its severe water deficit problem without cooperation with other players even under an optimistic scenario, while the uncertainty of cooperation would come from the main polluters. The results suggest a need to design a mechanism to reduce the risk of losses of those players by a side payment, which provides them with economic incentives to cooperate. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  20. Analysis of Charge Transfer for in Situ Li Intercalated Carbon Nanotubes

    KAUST Repository

    Rana, Kuldeep


    Vertically aligned carbon nanotube (VA-CNT) arrays have been synthesized with lithium (Li) intercalation through an alcohol-catalyzed chemical vapor deposition technique by using a Li-containing catalyst. Scanning electron microscopy images display that synthesized carbon nanotubes (CNTs) are dense and vertically aligned. The effect of the Li-containing catalyst on VA-CNTs has been studied by using Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and electron energy loss spectroscopy (EELS). XPS results show the change in binding energy of Li 1s and C 1s peaks, which indicates that Li is inserted in VA-CNTs during growth. Analysis of Raman spectra reveals that the G-band profile of CNTs synthesized with the Li-containing catalyst is shifted, suggesting an electronic interaction between Li and neighboring C atoms of the CNTs. The EELS spectra of the C K edge and Li K edge from CNTs also confirmed that Li is inserted into CNTs during synthesis. We have performed ab inito calculations based on density functional theory for a further understanding of the structural and electronic properties of Li intercalated CNTs, especially addressing the controversial charge-transfer state between Li and C. © 2012 American Chemical Society.

  1. A photoemission moments model using density functional and transfer matrix methods applied to coating layers on surfaces: Theory (United States)

    Jensen, Kevin L.; Finkenstadt, Daniel; Shabaev, Andrew; Lambrakos, Samuel G.; Moody, Nathan A.; Petillo, John J.; Yamaguchi, Hisato; Liu, Fangze


    Recent experimental measurements of a bulk material covered with a small number of graphene layers reported by Yamaguchi et al. [NPJ 2D Mater. Appl. 1, 12 (2017)] (on bialkali) and Liu et al. [Appl. Phys. Lett. 110, 041607 (2017)] (on copper) and the needs of emission models in beam optics codes have lead to substantial changes in a Moments model of photoemission. The changes account for (i) a barrier profile and density of states factor based on density functional theory (DFT) evaluations, (ii) a Drude-Lorentz model of the optical constants and laser penetration depth, and (iii) a transmission probability evaluated by an Airy Transfer Matrix Approach. Importantly, the DFT results lead to a surface barrier profile of a shape similar to both resonant barriers and reflectionless wells: the associated quantum mechanical transmission probabilities are shown to be comparable to those recently required to enable the Moments (and Three Step) model to match experimental data but for reasons very different than the assumption by conventional wisdom that a barrier is responsible. The substantial modifications of the Moments model components, motivated by computational materials methods, are developed. The results prepare the Moments model for use in treating heterostructures and discrete energy level systems (e.g., quantum dots) proposed for decoupling the opposing metrics of performance that undermine the performance of advanced light sources like the x-ray Free Electron Laser. The consequences of the modified components on quantum yield, emittance, and emission models needed by beam optics codes are discussed.

  2. Analysis of Heat Transfer of a Speed Reducer

    Directory of Open Access Journals (Sweden)

    Vanessa Lourenço Pierini


    Full Text Available This study aims to analyze the heat transfer fin efficiency and a speed reducer Crown / Endless. The material is aluminum reducer and the reduction is 15:1. We used a ½ HP motor and gearbox coupled to tests conducted with and without load. The experiments were performed on a test bench electromagnetic brake (brake Foucault in natural convection. To perform the temperature measurements, we used the device HBM QUANTUM MX-840A and a contact thermocouple type K. The calculation of the convection coefficient was performed by experimental and theoretical mathematical model, and the experimental method prevailed at work, because the theoretical method has some restrictions. The fin efficiency was calculated by one-dimensional. For a more efficient heat transfer, it was proposed to change the geometry of the flap and conducted tests on forced convection, thus, there was obtained a reduction of the surface temperature. The values of fin efficiency obtained were all close due to small temperature ranges that occurred in the experiment. For all testing a thermal imager was used to obtain thermal images and comparing the results.

  3. Three-Dimensional Heat Transfer Analysis of Metal Fasteners in Roofing Assemblies

    Directory of Open Access Journals (Sweden)

    Manan Singh


    Full Text Available Heat transfer analysis was performed on typical roofing assemblies using HEAT3, a three-dimensional heat transfer analysis software. The difference in heat transferred through the roofing assemblies considered is compared between two cases—without any steel fasteners and with steel fasteners. In the latter case, the metal roofing fasteners were arranged as per Factor Mutual Global (FMG approvals, in the field, perimeter, and corner zones of the roof. The temperature conditions used for the analysis represented summer and winter conditions for three separate Climate Zones (CZ namely Climate Zone 2 or CZ2 represented by Orlando, FL; CZ3 represented by Atlanta, GA; and CZ6 zone represented by St. Paul, MN. In all the climatic conditions, higher energy transfer was observed with increase in the number of metal fasteners attributed to high thermal conductivity of metals as compared to the insulation and other materials used in the roofing assembly. This difference in heat loss was also quantified in the form of percentage change in the overall or effective insulation of the roofing assembly for better understanding of the practical aspects. Besides, a comparison of 2D heat transfer analysis (using THERM software and 3D analysis using HEAT3 is also discussed proving the relevance of 3D over 2D heat transfer analysis.

  4. Vent System Analysis for the Cryogenic Propellant Storage Transfer Ground Test Article (United States)

    Hedayat, A


    To test and validate key capabilities and technologies required for future exploration elements such as large cryogenic propulsion stages and propellant depots, NASA is leading the efforts to develop and design the Cryogenic Propellant Storage and Transfer (CPST) Cryogenic Fluid Management (CFM) payload. The primary objectives of CPST payload are to demonstrate: 1) in-space storage of cryogenic propellants for long duration applications; and 2) in-space transfer of cryogenic propellants. The Ground Test Article (GTA) is a technology development version of the CPST payload. The GTA consists of flight-sized and flight-like storage and transfer tanks, liquid acquisition devices, transfer, and pressurization systems with all of the CPST functionality. The GTA is designed to perform integrated passive and active thermal storage and transfer performance testing with liquid hydrogen (LH2) in a vacuum environment. The GTA storage tank is designed to store liquid hydrogen and the transfer tank is designed to be 5% of the storage tank volume. The LH2 transfer subsystem is designed to transfer propellant from one tank to the other utilizing pressure or a pump. The LH2 vent subsystem is designed to prevent over-pressurization of the storage and transfer tanks. An in-house general-purpose computer program was utilized to model and simulate the vent subsystem operation. The modeling, analysis, and the results will be presented in the final paper.

  5. XPS analysis of the effect of fillers on PTFE transfer film development in sliding contacts (United States)

    Blanchet, T. A.; Kennedy, F. E.; Jayne, D. T.


    The development of transfer films atop steel counterfaces in contact with unfilled and bronze-filled PTFE has been studied using X-ray photoelectron spectroscopy. The sliding apparatus was contained within the vacuum of the analytical system, so the effects of the native oxide, hydrocarbon, and adsorbed gaseous surface layers of the steel upon the PTFE transfer behavior could be studied in situ. For both the filled and the unfilled PTFE, cleaner surfaces promoted greater amounts of transfer. Metal fluorides, which formed at the transfer film/counterface interface, were found solely in cases where the native oxide had been removed to expose the metallic surface prior to sliding. These fluorides also were found at clean metal/PTFE interfaces formed in the absence of frictional contact. A fraction of these fluorides resulted from irradiation damage inherent in XPS analysis. PTFE transfer films were found to build up with repeated sliding passes, by a process in which strands of transfer filled in the remaining counterface area. Under these reported test conditions, the transfer process is not expected to continue atop previously deposited transfer films. The bronze-filled composite generated greater amounts of transfer than the unfilled PTFE. The results are discussed relative to the observed increase in wear resistance imparted to PTFE by a broad range of inorganic fillers.

  6. Heat Transfer in a Gas Mixture Between Two Parallel Plates: Finite-difference Analysis of the Boltzmann Equation

    National Research Council Canada - National Science Library

    Kosuge, Shingo


    The problem of heat transfer and temperature distribution in a binary mixture of rarefied gases between two parallel plates with different temperatures is investigated on the basis of kinetic theory...

  7. Heat transfer characteristics and limitations analysis of heat-pipe-cooled thermal protection structure

    International Nuclear Information System (INIS)

    Guangming, Xiao; Yanxia, Du; Yewei, Gui; Lei, Liu; Xiaofeng, Yang; Dong, Wei


    The theories of heat transfer, thermodynamics and fluid dynamics are employed to develop the coupled heat transfer analytical methods for the heat-pipe-cooled thermal protection structure (HPC TPS), and a three-dimensional numerical method considering the sonic limit of heat pipe is proposed. To verify the calculation correctness, computations are carried out for a typical heat pipe and the results agree well with experimental data. Then, the heat transfer characteristics and limitations of HPC TPS are mainly studied. The studies indicate that the use of heat pipe can reduce the temperature at high heat flux region of structure efficiently. However, there is a frozen startup period before the heat pipe reaching a steady operating state, and the sonic limit will be a restriction on the heat transfer capability. Thus, the effects of frozen startup must be considered for the design of HPC TPS. The simulation model and numerical method proposed in this paper can predict the heat transfer characteristics of HPC TPS quickly and exactly, and the results will provide important references for the design or performance evaluation of HPC TPS. - Highlights: • Numerical methods for the heat-pipe-cooled thermal protection structure are studied. • Three-dimensional simulation model considering sonic limit of heat pipe is proposed. • The frozen startup process of the embedded heat pipe can be predicted exactly. • Heat transfer characteristics of TPS and limitations of heat pipe are discussed

  8. Magnetization transfer analysis of cartilage repair tissue: a preliminary study

    Energy Technology Data Exchange (ETDEWEB)

    Palmieri, F. [University ' Federico II' , Department of Radiology, Naples (Italy); Keyzer, F. de [University Hospitals Leuven, Department of Radiology, Leuven (Belgium); Maes, F. [Catholic University Leuven, Department of Electrotechnics, Faculty of Engineering, Leuven (Belgium); Breuseghem, I. van [Ghent University Hospital, Department of Radiology, Gent (Belgium)


    To evaluate the magnetization transfer ratio (MTR) after two different cartilage repair procedures, and to compare these data with the MTR of normal cartilage. Twenty-seven patients with a proven cartilage defect were recruited: 13 were treated with autologous chondrocyte implantation (ACI) and 14 were treated with the microfracture technique (MFR). All patients underwent MRI examinations with MT-sequences before the surgical treatment, after 12 months (26 patients) and after 24 months (11 patients). Eleven patients received a complete follow-up study at all three time points (five of the ACI group and six of the MFR group). All images were transferred to a workstation to calculate MTR images. For every MT image set, different ROIs were delineated by two radiologists. Means were calculated per ROI type in the different time frames and in both groups of cartilage repair. The data were analyzed with unpaired t- and ANOVA tests, and by calculating Pearson's correlation coefficient. No significant differences were found in the MTR of fatty bone marrow, muscle and normal cartilage in the different time frames. There was a significant but small difference between the MTR of normal cartilage and the cartilage repair area after 12 months for both procedures. After 24 months, the MTR of ACI repaired cartilage (0.31{+-}0.07) was not significantly different from normal cartilage MTR (0.34{+-}0.05). The MTR of MFR repaired cartilage (0.28{+-}0.02), still showed a significant difference from normal cartilage. The differences between damaged and repaired cartilage MTR are too small to enable MT-imaging to be a useful tool for postoperative follow-up of cartilage repair procedures. There is, however, an evolution towards normal MTR-values in the cartilage repair tissue (especially after ACI repair). (orig.)

  9. Magnetization transfer analysis of cartilage repair tissue: a preliminary study

    International Nuclear Information System (INIS)

    Palmieri, F.; Keyzer, F. de; Maes, F.; Breuseghem, I. van


    To evaluate the magnetization transfer ratio (MTR) after two different cartilage repair procedures, and to compare these data with the MTR of normal cartilage. Twenty-seven patients with a proven cartilage defect were recruited: 13 were treated with autologous chondrocyte implantation (ACI) and 14 were treated with the microfracture technique (MFR). All patients underwent MRI examinations with MT-sequences before the surgical treatment, after 12 months (26 patients) and after 24 months (11 patients). Eleven patients received a complete follow-up study at all three time points (five of the ACI group and six of the MFR group). All images were transferred to a workstation to calculate MTR images. For every MT image set, different ROIs were delineated by two radiologists. Means were calculated per ROI type in the different time frames and in both groups of cartilage repair. The data were analyzed with unpaired t- and ANOVA tests, and by calculating Pearson's correlation coefficient. No significant differences were found in the MTR of fatty bone marrow, muscle and normal cartilage in the different time frames. There was a significant but small difference between the MTR of normal cartilage and the cartilage repair area after 12 months for both procedures. After 24 months, the MTR of ACI repaired cartilage (0.31±0.07) was not significantly different from normal cartilage MTR (0.34±0.05). The MTR of MFR repaired cartilage (0.28±0.02), still showed a significant difference from normal cartilage. The differences between damaged and repaired cartilage MTR are too small to enable MT-imaging to be a useful tool for postoperative follow-up of cartilage repair procedures. There is, however, an evolution towards normal MTR-values in the cartilage repair tissue (especially after ACI repair). (orig.)

  10. Nerve transfer versus muscle transfer to restore elbow flexion after pan-brachial plexus injury: a cost-effectiveness analysis. (United States)

    Wali, Arvin R; Santiago-Dieppa, David R; Brown, Justin M; Mandeville, Ross


    OBJECTIVE Pan-brachial plexus injury (PBPI), involving C5-T1, disproportionately affects young males, causing lifelong disability and decreased quality of life. The restoration of elbow flexion remains a surgical priority for these patients. Within the first 6 months of injury, transfer of spinal accessory nerve (SAN) fascicles via a sural nerve graft or intercostal nerve (ICN) fascicles to the musculocutaneous nerve can restore elbow flexion. Beyond 1 year, free-functioning muscle transplantation (FFMT) of the gracilis muscle can be used to restore elbow flexion. The authors present the first cost-effectiveness model to directly compare the different treatment strategies available to a patient with PBPI. This model assesses the quality of life impact, surgical costs, and possible income recovered through restoration of elbow flexion. METHODS A Markov model was constructed to simulate a 25-year-old man with PBPI without signs of recovery 4.5 months after injury. The management options available to the patient were SAN transfer, ICN transfer, delayed FFMT, or no treatment. Probabilities of surgical success rates, quality of life measurements, and disability were derived from the published literature. Cost-effectiveness was defined using incremental cost-effectiveness ratios (ICERs) defined by the ratio between costs of a treatment strategy and quality-adjusted life years (QALYs) gained. A strategy was considered cost-effective if it yielded an ICER less than a willingness-to-pay of $50,000/QALY gained. Probabilistic sensitivity analysis (PSA) was performed to address parameter uncertainty. RESULTS The base case model demonstrated a lifetime QALYs of 22.45 in the SAN group, 22.0 in the ICN group, 22.3 in the FFMT group, and 21.3 in the no-treatment group. The lifetime costs of income lost through disability and interventional/rehabilitation costs were $683,400 in the SAN group, $727,400 in the ICN group, $704,900 in the FFMT group, and $783,700 in the no

  11. Comparison of small scale effect theories for buckling analysis of nanobeams

    Directory of Open Access Journals (Sweden)

    Kadir Mercan


    Full Text Available Theories which consider small scale effect have a great importance on analysis in micro and nano scale. In present paper, three kind of nanotubes (Carbon Nanotube (CNT, Boron Nitride Nanotube (BNNT, and Silicon Carbide Nanotube (SiCNT are analyzed in case of buckling on two parameters elastic foundation. Three different small scale theories (Nonlocal Elasticity Theory (NET, Surface Elasticity Theory (SET, and Nonlocal Surface Elasticity Theory (NET&SET are applied to calculate the buckling loads. Also Classical Euler-Bernoulli Beam Theory (CT is used to see the effect of small scale effective theories. Comparative results are given for simply supported nanotubes in figures.


    Directory of Open Access Journals (Sweden)



    Full Text Available Most times the current situation of one or another country depends on the historical development of own tax system. A practical question of any governance is to determine the optimal taxation rate level, bringing to the state the highest tax revenues. A good place to start is with what is popularly known as the Laffer curve. This paper aims to determine in graphical terms the level where European economies ranks by using Laffer curve based on the data series provided by the European Commission and the World Bank. Graphical analysis of Laffer's theory can emphasize only the positioning on one or another side of point for maximum tax revenues, a position that can influence fiscal policy decisions. Conclusions at European Union level are simple. Value of taxation rate for fiscal optimal point varies from one Member State to another, from 48.9% in Denmark to 28% in Romania, with an average of 37.1% for the EU-27.

  13. Empathy from the client's perspective: A grounded theory analysis. (United States)

    MacFarlane, Peter; Anderson, Timothy; McClintock, Andrew S


    Although empathy is one of most robust predictors of client outcome, there is little consensus about how best to conceptualize this construct. The aim of the present research was to investigate clients' perceptions and in-session experiences of empathy. Semi-structured, video-assisted interpersonal process recall interviews were used to collect data from nine clients receiving individual psychotherapy at a university psychology clinic. Grounded theory analysis yielded a model consisting of three clusters: (1) relational context of empathy (i.e., personal relationship and professional relationship), (2) types of empathy (i.e., psychotherapists' cognitive empathy, psychotherapists' emotional empathy, and client attunement to psychotherapist), and (3) utility of empathy (i.e., process-related benefits and client-related benefits). These results suggest that empathy is a multi-dimensional, interactional process that affects-and is affected by-the broader relationship between client and psychotherapist.

  14. Single phase-change analysis of two different PCMs filled in a heat transfer module

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Dong Gyu; Kang, Chae Dong [Chonbuk National University, Jeonju (Korea, Republic of); Kim, Hyung Kuk [Hyundai Heavy Industries Co., Ulsan (Korea, Republic of)


    Phase change material(PCM) is tried to secondary heat source in solar heat pump system. A numerical study of the phase change dominant heat transfer is done with a heat transfer module, which consists of a water path(BRINE), heat transfer plates(HTP), and PCM layers of high-temperature one(HPCM, 78-79 .deg. C) and low-temperature one(LPCM, 28-29 .deg. C). There are five arrangements consisting of BRINE, HTP, HPCM, and LPCM layers in the heat transfer module. The time and heat transfer rate for PCM melting/solidification are compared between arrangements. And the numerical time without convection is compared to the experimental one for melting/solidification. From the numerical analysis, the time for melting/solidification is different to 10 hours, depending on the arrangement.

  15. Application of Extreme Value Theory to Crash Data Analysis. (United States)

    Xu, Lan; Nusholtz, Guy


    A parametric model obtained by fitting a set of data to a function generally uses a procedure such as maximum likelihood or least squares. In general this will generate the best estimate for the distribution of the data overall but will not necessarily generate a reasonable estimation for the tail of the distribution unless the function fitted resembles the underlying distribution function. A distribution function can represent an estimate that is significantly different from the actual tail data, while the bulk of the data is reasonably represented by the central part of the fitted distribution. Extreme value theory can be used to improve the predictive capabilities of the fitted function in the tail region. In this study the peak-over-threshold approach from the extreme value theory was utilized to show that it is possible to obtain a better fit of the tail of a distribution than the procedures that use the entire distribution only. Additional constraints, on the current use of the extreme value approach with respect to the selection of the threshold (an estimate of the beginning of the tail region) that minimize the sensitivity to individual data samples associated with the tail section as well as contamination from the central distribution are used. Once the threshold is determined, the maximum likelihood method was used to fit the exceedances with the Generalized Pareto Distribution to obtain the tail distribution. The approach was then used in the analysis of airbag inflator pressure data from tank tests, crash velocity distribution and mass distribution from the field crash data (NASS). From the examples, the extreme (tail) distributions were better estimated with the Generalized Pareto Distribution, than a single overall distribution, along with the probability of the occurrence for a given extreme value, or a rare observation such as a high speed crash. It was concluded that the peak-over-threshold approach from extreme value theory can be a useful tool in

  16. Electron-Transfer-Enhanced Cation-Cation Interactions in Homo- and Heterobimetallic Actinide Complexes: A Relativistic Density Functional Theory Study. (United States)

    Zheng, Ming; Chen, Fang-Yuan; Tian, Jia-Nan; Pan, Qing-Jiang


    To provide deep insight into cation-cation interactions (CCIs) involving hexavalent actinyl species that are major components in spent nuclear fuel and pose important implications for the effective removal of radiotoxic pollutants in the environment, a series of homo- and heterobimetallic actinide complexes supported by cyclopentadienyl (Cp) and polypyrrolic macrocycle (H 4 L) ligands were systematically investigated using relativistic density functional theory. The metal sort in both parts of (THF)(H 2 L)(OAn VI O) and (An') III Cp 3 from U to Np to Pu, as well as the substituent bonding to Cp from electron-donating Me to H to electron-withdrawing Cl, SiH 3 , and SiMe 3 , was changed. Over 0.70 electrons are unraveled to transfer from the electron-rich U III to the electron-deficient An VI of the actinyl moiety, leading to a more stable An V -U IV isomer; in contrast, uranylneptunium and uranylplutonium complexes behave as electron-resonance structures between VI-III and V-IV. These were further corroborated by geometrical and electronic structures. The energies of CCIs (i.e., O exo -An' bonds) were calculated to be -19.6 to -41.2 kcal/mol, affording those of OUO-Np (-23.9 kcal/mol) and OUO-Pu (-19.6 kcal/mol) with less electron transfer (ET) right at the low limit. Topological analyses of the electron density at the O exo -An' bond critical points demonstrate that the CCIs are ET or dative bonds in nature. A positive correlation has been built between the CCIs' strength and corresponding ET amount. It is concluded that the CCIs of O exo -An' are driven by the electrostatic attraction between the actinyl oxo atom (negative) and the actinide ion (positive) and enhanced by their ET. Finally, experimental syntheses of (THF)(H 2 L)(OU VI O)(An') III Cp 3 (An' = U and Np) were well reproduced by thermodynamic calculations that yielded negative free energies in a tetrahydrofuran solution but a positive one for their uranylplutonium analogue, which was synthetically


    NARCIS (Netherlands)

    Cornelissen, J.P.; Durand, R.; Fiss, P.C.; Lammers, J.C.; Vaara, E.


    We conceptualize the roots of cognitive, linguistic, and communicative theories of institutions and outline the promise and potential of a stronger communication focus for institutional theory. In particular, we outline a theoretical approach that puts communication at the heart of theories of

  18. Critical Theory & Textual Arguments: Expanding Habermas's Analysis of Literary Claims. (United States)

    Stroud, Scott R.

    Jurgen Habermas's theory of communicative action has held much promise for critical theory and its examination of the structure of society. This theory, however, has been accused by some as being limited in regard to other forms of discourse, especially fictional, mythical, and religious texts. Habermas has argued that literature (i.e., fictive…

  19. Upper limb kinetic analysis of three sitting pivot wheelchair transfer techniques. (United States)

    Koontz, Alicia M; Kankipati, Padmaja; Lin, Yen-Sheng; Cooper, Rory A; Boninger, Michael L


    The objective of this study was to investigate differences in shoulder, elbow and hand kinetics while performing three different SPTs that varied in terms of hand and trunk positioning. Fourteen unimpaired individuals (8 male and 6 female) performed three variations of sitting pivot transfers in a random order from a wheelchair to a level tub bench. Two transfers involved a forward flexed trunk (head-hips technique) and the third with the trunk remaining upright. The two transfers involving a head hips technique were performed with two different leading hand initial positions. Motion analysis equipment recorded upper body movements and force sensors recorded hand reaction forces. Shoulder and elbow joint and hand kinetics were computed for the lift phase of the transfer. Transferring using either of the head hips techniques compared to the trunk upright style of transferring resulted in reduced superior forces at the shoulder (Pforces in the leading elbow (P=0.049) for both head hip transfers and the trailing hand for the head hip technique with the arm further away from the body (P<0.028). The head hip techniques resulted in higher shoulder external rotation, flexion and extension moments compared to the trunk upright technique (P<0.021). Varying the hand placement and trunk positioning during transfers changes the load distribution across all upper limb joints. The results of this study may be useful for determining a technique that helps preserve upper limb function overtime. Published by Elsevier Ltd.

  20. A multi-layer discrete-ordinate method for vector radiative transfer in a vertically-inhomogeneous, emitting and scattering atmosphere. I - Theory. II - Application (United States)

    Weng, Fuzhong


    A theory is developed for discretizing the vector integro-differential radiative transfer equation including both solar and thermal radiation. A complete solution and boundary equations are obtained using the discrete-ordinate method. An efficient numerical procedure is presented for calculating the phase matrix and achieving computational stability. With natural light used as a beam source, the Stokes parameters from the model proposed here are compared with the analytical solutions of Chandrasekhar (1960) for a Rayleigh scattering atmosphere. The model is then applied to microwave frequencies with a thermal source, and the brightness temperatures are compared with those from Stamnes'(1988) radiative transfer model.

  1. Axial Static Load Dependence Free Vibration Analysis of Helical Springs Based on the Theory of Spatially Curved Bars

    Directory of Open Access Journals (Sweden)

    Vebil Yildirim

    Full Text Available Abstract This work addresses an accurate and detailed axial static load dependence linearly elastic free vibration analysis of cylindrical helical springs based on the theory of spatially curved bars and the transfer matrix method. For a continuous system, governing equations comprise coupled vibration modes namely transverse vibrations in two orthogonal planes, torsional and axial vibrations. The axial and shear deformation effects together with the rotatory inertia effects are all considered based on the first order shear deformation theory and their effects on the frequencies are investigated. The effects of the initial stress resultants on the frequencies are also studied. After buckling, forward-shifting phenomenon of higher frequencies is noticeably demonstrated. It is also revealed that a free/forced vibration analysis with an axial static load should not be performed individually without checking buckling loads.

  2. Dynamical modeling and lifetime analysis of geostationary transfer orbits (United States)

    Wang, Yue; Gurfil, Pini


    The dynamics and lifetime reduction of geostationary transfer orbits (GTOs) are of great importance to space debris mitigation. The orbital dynamics, subjected to a complex interplay of multiple perturbations, are complicated and sensitive to the initial conditions and model parameters. In this paper, a simple but effective non-singular orbital dynamics model in terms of Milankovitch elements is derived. The orbital dynamics, which include the Earth oblateness, luni-solar perturbations, and atmospheric drag, are averaged over the orbital motion of the GTO object, or, as needed, also over the orbital motions of the Moon and Sun, to eliminate the short-period terms. After the averaging process, the effect of the atmospheric drag assumes a simple analytical form. The averaged orbital model is verified through a numerical simulation compared with commercial orbit propagators. GTO lifetime reduction by using the luni-solar perturbations is studied. It is shown that the long-period luni-solar perturbation is induced by the precession of the GTO orbital plane and apsidal line, whereas the short-period perturbation is induced by the periodic luni-solar orbital motions. The long- and short-period perturbations are isolated and studied separately, and their global distribution with respect to the orbital geometry is given. The desired initial orbital geometry with a short orbital lifetime is found and verified by a numerical simulation.

  3. Sensible Heat Transfer during Droplet Cooling: Experimental and Numerical Analysis

    Directory of Open Access Journals (Sweden)

    Emanuele Teodori


    Full Text Available This study presents the numerical reproduction of the entire surface temperature field resulting from a water droplet spreading on a heated surface, which is compared with experimental data. High-speed infrared thermography of the back side of the surface and high-speed images of the side view of the impinging droplet were used to infer on the solid surface temperature field and on droplet dynamics. Numerical reproduction of the phenomena was performed using OpenFOAM CFD toolbox. An enhanced volume of fluid (VOF model was further modified for this purpose. The proposed modifications include the coupling of temperature fields between the fluid and the solid regions, to account for transient heat conduction within the solid. The results evidence an extremely good agreement between the temporal evolution of the measured and simulated spreading factors of the considered droplet impacts. The numerical and experimental dimensionless surface temperature profiles within the solid surface and along the droplet radius, were also in good agreement. Most of the differences were within the experimental measurements uncertainty. The numerical results allowed relating the solid surface temperature profiles with the fluid flow. During spreading, liquid recirculation within the rim, leads to the appearance of different regions of heat transfer that can be correlated with the vorticity field within the droplet.

  4. Heat transfer modelling and stability analysis of selective laser melting

    International Nuclear Information System (INIS)

    Gusarov, A.V.; Yadroitsev, I.; Bertrand, Ph.; Smurov, I.


    The process of direct manufacturing by selective laser melting basically consists of laser beam scanning over a thin powder layer deposited on a dense substrate. Complete remelting of the powder in the scanned zone and its good adhesion to the substrate ensure obtaining functional parts with improved mechanical properties. Experiments with single-line scanning indicate, that an interval of scanning velocities exists where the remelted tracks are uniform. The tracks become broken if the scanning velocity is outside this interval. This is extremely undesirable and referred to as the 'balling' effect. A numerical model of coupled radiation and heat transfer is proposed to analyse the observed instability. The 'balling' effect at high scanning velocities (above ∼20 cm/s for the present conditions) can be explained by the Plateau-Rayleigh capillary instability of the melt pool. Two factors stabilize the process with decreasing the scanning velocity: reducing the length-to-width ratio of the melt pool and increasing the width of its contact with the substrate

  5. Transferability and accuracy by combining dispersionless density functional and incremental post-Hartree-Fock theories: Noble gases adsorption on coronene/graphene/graphite surfaces

    International Nuclear Information System (INIS)

    Lara-Castells, María Pilar de; Bartolomei, Massimiliano; Mitrushchenkov, Alexander O.; Stoll, Hermann


    The accuracy and transferability of the electronic structure approach combining dispersionless density functional theory (DFT) [K. Pernal et al., Phys. Rev. Lett. 103, 263201 (2009)] with the method of increments [H. Stoll, J. Chem. Phys. 97, 8449 (1992)], are validated for the interaction between the noble-gas Ne, Ar, Kr, and Xe atoms and coronene/graphene/graphite surfaces. This approach uses the method of increments for surface cluster models to extract intermonomer dispersion-like (2- and 3-body) correlation terms at coupled cluster singles and doubles and perturbative triples level, while periodic dispersionless density functionals calculations are performed to estimate the sum of Hartree-Fock and intramonomer correlation contributions. Dispersion energy contributions are also obtained using DFT-based symmetry-adapted perturbation theory [SAPT(DFT)]. An analysis of the structure of the X/surface (X = Ne, Ar, Kr, and Xe) interaction energies shows the excellent transferability properties of the leading intermonomer correlation contributions across the sequence of noble-gas atoms, which are also discussed using the Drude oscillator model. We further compare these results with van der Waals-(vdW)-corrected DFT-based approaches. As a test of accuracy, the energies of the low-lying nuclear bound states supported by the laterally averaged X/graphite potentials (X = 3 He, 4 He, Ne, Ar, Kr, and Xe) are calculated and compared with the best estimations from experimental measurements and an atom-bond potential model using the ab initio-assisted fine-tuning of semiempirical parameters. The bound-state energies determined differ by less than 6–7 meV (6%) from the atom-bond potential model. The crucial importance of including incremental 3-body dispersion-type terms is clearly demonstrated, showing that the SAPT(DFT) approach effectively account for these terms. With the deviations from the best experimental-based estimations smaller than 2.3 meV (1.9%), the accuracy of

  6. Transferability and accuracy by combining dispersionless density functional and incremental post-Hartree-Fock theories: Noble gases adsorption on coronene/graphene/graphite surfaces. (United States)

    de Lara-Castells, María Pilar; Bartolomei, Massimiliano; Mitrushchenkov, Alexander O; Stoll, Hermann


    The accuracy and transferability of the electronic structure approach combining dispersionless density functional theory (DFT) [K. Pernal et al., Phys. Rev. Lett. 103, 263201 (2009)] with the method of increments [H. Stoll, J. Chem. Phys. 97, 8449 (1992)], are validated for the interaction between the noble-gas Ne, Ar, Kr, and Xe atoms and coronene/graphene/graphite surfaces. This approach uses the method of increments for surface cluster models to extract intermonomer dispersion-like (2- and 3-body) correlation terms at coupled cluster singles and doubles and perturbative triples level, while periodic dispersionless density functionals calculations are performed to estimate the sum of Hartree-Fock and intramonomer correlation contributions. Dispersion energy contributions are also obtained using DFT-based symmetry-adapted perturbation theory [SAPT(DFT)]. An analysis of the structure of the X/surface (X = Ne, Ar, Kr, and Xe) interaction energies shows the excellent transferability properties of the leading intermonomer correlation contributions across the sequence of noble-gas atoms, which are also discussed using the Drude oscillator model. We further compare these results with van der Waals-(vdW)-corrected DFT-based approaches. As a test of accuracy, the energies of the low-lying nuclear bound states supported by the laterally averaged X/graphite potentials (X = (3)He, (4)He, Ne, Ar, Kr, and Xe) are calculated and compared with the best estimations from experimental measurements and an atom-bond potential model using the ab initio-assisted fine-tuning of semiempirical parameters. The bound-state energies determined differ by less than 6-7 meV (6%) from the atom-bond potential model. The crucial importance of including incremental 3-body dispersion-type terms is clearly demonstrated, showing that the SAPT(DFT) approach effectively account for these terms. With the deviations from the best experimental-based estimations smaller than 2.3 meV (1.9%), the accuracy of

  7. Transferability and accuracy by combining dispersionless density functional and incremental post-Hartree-Fock theories: Noble gases adsorption on coronene/graphene/graphite surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Lara-Castells, María Pilar de, E-mail:; Bartolomei, Massimiliano [Instituto de Física Fundamental (C.S.I.C.), Serrano 123, E-28006 Madrid (Spain); Mitrushchenkov, Alexander O. [Laboratoire Modélisation et Simulation Multi Echelle, Université Paris-Est, MSME UMR 8208 CNRS, 5 bd Descartes, 77454 Marne-la-Vallée (France); Stoll, Hermann [Institut für Theoretische Chemie, Universität Stuttgart, D-70550 Stuttgart (Germany)


    The accuracy and transferability of the electronic structure approach combining dispersionless density functional theory (DFT) [K. Pernal et al., Phys. Rev. Lett. 103, 263201 (2009)] with the method of increments [H. Stoll, J. Chem. Phys. 97, 8449 (1992)], are validated for the interaction between the noble-gas Ne, Ar, Kr, and Xe atoms and coronene/graphene/graphite surfaces. This approach uses the method of increments for surface cluster models to extract intermonomer dispersion-like (2- and 3-body) correlation terms at coupled cluster singles and doubles and perturbative triples level, while periodic dispersionless density functionals calculations are performed to estimate the sum of Hartree-Fock and intramonomer correlation contributions. Dispersion energy contributions are also obtained using DFT-based symmetry-adapted perturbation theory [SAPT(DFT)]. An analysis of the structure of the X/surface (X = Ne, Ar, Kr, and Xe) interaction energies shows the excellent transferability properties of the leading intermonomer correlation contributions across the sequence of noble-gas atoms, which are also discussed using the Drude oscillator model. We further compare these results with van der Waals-(vdW)-corrected DFT-based approaches. As a test of accuracy, the energies of the low-lying nuclear bound states supported by the laterally averaged X/graphite potentials (X = {sup 3}He, {sup 4}He, Ne, Ar, Kr, and Xe) are calculated and compared with the best estimations from experimental measurements and an atom-bond potential model using the ab initio-assisted fine-tuning of semiempirical parameters. The bound-state energies determined differ by less than 6–7 meV (6%) from the atom-bond potential model. The crucial importance of including incremental 3-body dispersion-type terms is clearly demonstrated, showing that the SAPT(DFT) approach effectively account for these terms. With the deviations from the best experimental-based estimations smaller than 2.3 meV (1.9%), the

  8. Strain transfer analysis of optical fiber based sensors embedded in an asphalt pavement structure (United States)

    Wang, Huaping; Xiang, Ping


    Asphalt pavement is vulnerable to random damage, such as cracking and rutting, which can be proactively identified by distributed optical fiber sensing technology. However, due to the material nature of optical fibers, a bare fiber is apt to be damaged during the construction process of pavements. Thus, a protective layer is needed for this application. Unfortunately, part of the strain of the host material is absorbed by the protective layer when transferring the strain to the sensing fiber. To account for the strain transfer error, in this paper a theoretical analysis of the strain transfer of a three-layered general model has been carried out by introducing Goodman’s hypothesis to describe the interfacial shear stress relationship. The model considers the viscoelastic behavior of the host material and protective layer. The effects of one crack in the host material and the sensing length on strain transfer relationship are been discussed. To validate the effectiveness of the strain transfer analysis, a flexible asphalt-mastic packaged distributed optical fiber sensor was designed and tested in a laboratory environment to monitor the distributed strain and appearance of cracks in an asphalt concrete beam at two different temperatures. The experimental results indicated that the developed strain transfer formula can significantly reduce the strain transfer error, and that the asphalt-mastic packaged optical fiber sensor can successfully monitor the distributed strain and identify local cracks.

  9. Strain transfer analysis of optical fiber based sensors embedded in an asphalt pavement structure

    International Nuclear Information System (INIS)

    Wang, Huaping; Xiang, Ping


    Asphalt pavement is vulnerable to random damage, such as cracking and rutting, which can be proactively identified by distributed optical fiber sensing technology. However, due to the material nature of optical fibers, a bare fiber is apt to be damaged during the construction process of pavements. Thus, a protective layer is needed for this application. Unfortunately, part of the strain of the host material is absorbed by the protective layer when transferring the strain to the sensing fiber. To account for the strain transfer error, in this paper a theoretical analysis of the strain transfer of a three-layered general model has been carried out by introducing Goodman’s hypothesis to describe the interfacial shear stress relationship. The model considers the viscoelastic behavior of the host material and protective layer. The effects of one crack in the host material and the sensing length on strain transfer relationship are been discussed. To validate the effectiveness of the strain transfer analysis, a flexible asphalt-mastic packaged distributed optical fiber sensor was designed and tested in a laboratory environment to monitor the distributed strain and appearance of cracks in an asphalt concrete beam at two different temperatures. The experimental results indicated that the developed strain transfer formula can significantly reduce the strain transfer error, and that the asphalt-mastic packaged optical fiber sensor can successfully monitor the distributed strain and identify local cracks. (paper)

  10. Analysis of radiative heat transfer impact in cross-flow tube and fin heat exchangers

    Directory of Open Access Journals (Sweden)

    Hanuszkiewicz-Drapała Małgorzata


    Full Text Available A cross-flow, tube and fin heat exchanger of the water – air type is the subject of the analysis. The analysis had experimental and computational form and was aimed for evaluation of radiative heat transfer impact on the heat exchanger performance. The main element of the test facility was an enlarged recurrent segment of the heat exchanger under consideration. The main results of measurements are heat transfer rates, as well as temperature distributions on the surface of the first fin obtained by using the infrared camera. The experimental results have been next compared to computational ones coming from a numerical model of the test station. The model has been elaborated using computational fluid dynamics software. The computations have been accomplished for two cases: without radiative heat transfer and taking this phenomenon into account. Evaluation of the radiative heat transfer impact in considered system has been done by comparing all the received results.

  11. Development of a UF{sub 6} cylinder transient heat transfer/stress analysis model

    Energy Technology Data Exchange (ETDEWEB)

    Williams, W.R. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States)


    A heat transfer/stress analysis model is being developed to simulate the heating to a point of rupture of a cylinder containing UF{sub 6} when it is exposed to a fire. The assumptions underlying the heat transfer portion of the model, which has been the focus of work to date, will be discussed. A key aspect of this model is a lumped parameter approach to modeling heat transfer. Preliminary results and future efforts to develop an integrated thermal/stress model will be outlined.

  12. Extraction of chemical information of suspensions using radiative transfer theory to remove multiple scattering effects: application to a model two-component system. (United States)

    Steponavicius, Raimundas; Thennadil, Suresh N


    An approach for removing multiple light scattering effects using the radiative transfer theory (RTE) in order to improve the performance of multivariate calibration models is proposed. This approach is then applied to the problem of building calibration models for predicting the concentration of a scattering (particulate) component. Application of this approach to a simulated four component system showed that it will lead to calibration models which perform appreciably better than when empirically scatter corrected measurements of diffuse transmittance (T(d)) or reflectance (R(d)) are used. The validity of the method was also tested experimentally using a two-component (polystyrene-water) system. While the proposed method led to a model that performed better than the one built using R(d), its performance was worse compared to when T(d) measurements were used. Analysis indicates that this is because the model built using T(d) benefits from the strong secondary correlation between particle concentration and path length traveled by the photons which occurs due to the system containing only two components. On the other hand, the model arising from the proposed methodology uses essentially only the chemical (polystyrene) signal. Thus, this approach can be expected to work better in multicomponent systems where the path length correlation would not exist.

  13. Electron transfer from plant phenolates to carotenoid radical cations. Antioxidant interaction entering the Marcus theory inverted region. (United States)

    Cheng, Hong; Han, Rui-Min; Zhang, Jian-Ping; Skibsted, Leif H


    β-Carotene, lycopene, and zeaxanthin are maximally regenerated by plant phenolates from their radical cations formed during laser flash photolysis in 9:1 (v/v) chloroform/methanol for a driving force corresponding to the reorganization energy according to the Marcus theory. For β-carotene, the reorganization energy has values of 0.41 ± 0.04 and 0.40 ± 0.04 eV for the plant phenols in the presence of 1 and 2 equiv of base, respectively, at 23 °C. For a driving force lower than the reorganization energy, regeneration of the carotenoids is less efficient as is seen for m-hydroxybenzoic acid, vanillic acid, and p-coumaric acid. For a driving force above the maximum rate as determined to have kET = 6.3 × 10(9) L·mol(-1)·s(-1) for syringic acid and β-carotene, the reaction becomes gradually slower and regeneration less efficient as is seen for the more reducing caffeic acid, rutin, and quercetin corresponding to an inverted region for the rate of electron transfer. Lycopene and zeaxanthin show a similar behavior for the same series of plant phenols with slightly lower reorganization energy, in agreement with the lower reduction potential of their radical cations, while, for the ketocarotenoids astaxanthin and canthaxanthin, fast reactions with a solvent of radical cations inhibit regeneration from being detected. Intermediate reducing plant phenols accordingly yield maximal protection of carotenoids against photobleaching in foods and beverages.

  14. Calibration model transfer for near-infrared spectra based on canonical correlation analysis. (United States)

    Fan, Wei; Liang, Yizeng; Yuan, Dalin; Wang, Jiajun


    In order to solve the calibration transformation problem in near-infrared (NIR) spectroscopy, a method based on canonical correlation analysis (CCA) for calibration model transfer is developed in this work. Two real NIR data sets were tested. A comparative study between the proposed method and piecewise direct standardization (PDS) was conducted. It is shown that the transfer results obtained with the proposed method based on CCA were better than those obtained by PDS when the subset had sufficient samples.

  15. Who uses nursing theory? A univariate descriptive analysis of five years' research articles. (United States)

    Bond, A Elaine; Eshah, Nidal Farid; Bani-Khaled, Mohammed; Hamad, Atef Omar; Habashneh, Samira; Kataua', Hussein; al-Jarrah, Imad; Abu Kamal, Andaleeb; Hamdan, Falastine Rafic; Maabreh, Roqia


    Since the early 1950s, nursing leaders have worked diligently to build the Scientific Discipline of Nursing, integrating Theory, Research and Practice. Recently, the role of theory has again come into question, with some scientists claiming nurses are not using theory to guide their research, with which to improve practice. The purposes of this descriptive study were to determine: (i) Were nursing scientists' research articles in leading nursing journals based on theory? (ii) If so, were the theories nursing theories or borrowed theories? (iii) Were the theories integrated into the studies, or were they used as organizing frameworks? Research articles from seven top ISI journals were analysed, excluding regularly featured columns, meta-analyses, secondary analysis, case studies and literature reviews. The authors used King's dynamic Interacting system and Goal Attainment Theory as an organizing framework. They developed consensus on how to identify the integration of theory, searching the Title, Abstract, Aims, Methods, Discussion and Conclusion sections of each research article, whether quantitative or qualitative. Of 2857 articles published in the seven journals from 2002 to, and including, 2006, 2184 (76%) were research articles. Of the 837 (38%) authors who used theories, 460 (55%) used nursing theories, 377 (45%) used other theories: 776 (93%) of those who used theory integrated it into their studies, including qualitative studies, while 51 (7%) reported they used theory as an organizing framework for their studies. Closer analysis revealed theory principles were implicitly implied, even in research reports that did not explicitly report theory usage. Increasing numbers of nursing research articles (though not percentagewise) continue to be guided by theory, and not always by nursing theory. Newer nursing research methods may not explicitly state the use of nursing theory, though it is implicitly implied. © 2010 The Authors. Scandinavian Journal of Caring

  16. In defense of psychosomatic theory: A critical analysis of Allison and Heshkas critical analysis

    NARCIS (Netherlands)

    Strien, T. van


    This article analyses Allison and Heshka's (International Journal of Eating Disorders, 13, 289–295, 1993.) critical analysis of studies supporting psychosomatic theory. Questionned first is, Allison and Heshka's contention that the obese overreport emotional eating as a result of effects of demand

  17. In defense of psychosomatic theory : a critical analysis of Allison and Heshka's critical analysis

    NARCIS (Netherlands)

    Van Strien, T

    This article analyses Allison and Heshka's (Internal Journal of Eating Disorders, 13, 289-295, 1993.) critical analysis of studies supporting psychosomatic theory. Questionned first is, Allison and Heshka's contention that the obese overreport emotional eating as a result of effects of demand

  18. Structural analysis of DNA sequence: evidence for lateral gene transfer in Thermotoga maritima

    DEFF Research Database (Denmark)

    Worning, Peder; Jensen, Lars Juhl; Nelson, K. E.


    The recently published complete DNA sequence of the bacterium Thermotoga maritima provides evidence, based on protein sequence conservation, for lateral gene transfer between Archaea and Bacteria. We introduce a new method of periodicity analysis of DNA sequences, based on structural parameters......, which brings independent evidence for the lateral gene transfer in the genome of T.maritima, The structural analysis relates the Archaea-like DNA sequences to the genome of Pyrococcus horikoshii. Analysis of 24 complete genomic DNA sequences shows different periodicity patterns for organisms...

  19. Analysis of Human Swing Movement and Transferring into Robot (United States)

    Shimodaira, Jun; Amaoka, Yuki; Hamatani, Shinsuke; Takeuchi, Masahiro; Hirai, Hiroaki; Miyazaki, Fumio

    Based on Generalized Motor Program, we analyzed the skill of human's table-tennis movement We hypothesized that it can be divided into arm swing and translational movements by upper and lower body movements, respectively. We expressed 3D position of the racket by only one parameter resulted from the analysis using Principal Component Analysis. Body trunk position measurement attested the lower body plays the role of keeping fixed relative-position between the ball and the body trunk at any hitting time. By applying human skills in upper and lower body movements, we could make the robot properly play table-tennis with a human.

  20. Statistical Analysis of Hypercalcaemia Data related to Transferability

    DEFF Research Database (Denmark)

    Frølich, Anne; Nielsen, Bo Friis


    In this report we describe statistical analysis related to a study of hypercalcaemia carried out in the Copenhagen area in the ten year period from 1984 to 1994. Results from the study have previously been publised in a number of papers [3, 4, 5, 6, 7, 8, 9] and in various abstracts and posters...... at conferences during the late eighties and early nineties. In this report we give a more detailed description of many of the analysis and provide some new results primarily by simultaneous studies of several databases....

  1. Improving Family Forest Knowledge Transfer through Social Network Analysis (United States)

    Gorczyca, Erika L.; Lyons, Patrick W.; Leahy, Jessica E.; Johnson, Teresa R.; Straub, Crista L.


    To better engage Maine's family forest landowners our study used social network analysis: a computational social science method for identifying stakeholders, evaluating models of engagement, and targeting areas for enhanced partnerships. Interviews with researchers associated with a research center were conducted to identify how social network…


    African Journals Online (AJOL)

    development, data visualization, data analysis and numerical computing are faster than traditional programming languages sueh as C, C++ and. Journal of EEA, VoL 23, 2006. The resulting discretisation Eqs, (10), (11) and'(12) were solved using the computer code developed with MATLAB programming, The solution of the.

  3. Electronic hole transfer in rutile and anatase TiO2: Effect of a delocalization error in the density functional theory on the charge transfer barrier height

    DEFF Research Database (Denmark)

    Zawadzki, Pawel; Rossmeisl, Jan; Jacobsen, Karsten Wedel


    where charge localization is strongly coupled to lattice distortion. As an example we calculate the adiabatic PES for the hole transfer process in rutile and anatase TiO2. (Semi) local DFT leads to qualitatively wrong, barrierless curves. Removal of the nonlinearity improves the PES shape and allows us...

  4. Contrast and Critique of Two Approaches to Discourse Analysis: Conversation Analysis and Speech Act Theory

    Directory of Open Access Journals (Sweden)

    Nguyen Van Han


    Full Text Available Discourse analysis, as Murcia and Olshtain (2000 assume, is a vast study of language in use that extends beyond sentence level, and it involves a more cognitive and social perspective on language use and communication exchanges. Holding a wide range of phenomena about language with society, culture and thought, discourse analysis contains various approaches: speech act, pragmatics, conversation analysis, variation analysis, and critical discourse analysis. Each approach works in its different domain to discourse. For one dimension, it shares the same assumptions or general problems in discourse analysis with the other approaches: for instance, the explanation on how we organize language into units beyond sentence boundaries, or how language is used to convey information about the world, ourselves and human relationships (Schiffrin 1994: viii. For other dimensions, each approach holds its distinctive characteristics contributing to the vastness of discourse analysis. This paper will mainly discuss two approaches to discourse analysis- conversation analysis and speech act theory- and will attempt to point out some similarities as well as contrasting features between the two approaches, followed by a short reflection on their strengths and weaknesses in the essence of each approach. The organizational and discourse features in the exchanges among three teachers at the College of Finance and Customs in Vietnam will be analysed in terms of conversation analysis and speech act theory.

  5. IMMAN: free software for information theory-based chemometric analysis. (United States)

    Urias, Ricardo W Pino; Barigye, Stephen J; Marrero-Ponce, Yovani; García-Jacas, César R; Valdes-Martiní, José R; Perez-Gimenez, Facundo


    The features and theoretical background of a new and free computational program for chemometric analysis denominated IMMAN (acronym for Information theory-based CheMoMetrics ANalysis) are presented. This is multi-platform software developed in the Java programming language, designed with a remarkably user-friendly graphical interface for the computation of a collection of information-theoretic functions adapted for rank-based unsupervised and supervised feature selection tasks. A total of 20 feature selection parameters are presented, with the unsupervised and supervised frameworks represented by 10 approaches in each case. Several information-theoretic parameters traditionally used as molecular descriptors (MDs) are adapted for use as unsupervised rank-based feature selection methods. On the other hand, a generalization scheme for the previously defined differential Shannon's entropy is discussed, as well as the introduction of Jeffreys information measure for supervised feature selection. Moreover, well-known information-theoretic feature selection parameters, such as information gain, gain ratio, and symmetrical uncertainty are incorporated to the IMMAN software ( ), following an equal-interval discretization approach. IMMAN offers data pre-processing functionalities, such as missing values processing, dataset partitioning, and browsing. Moreover, single parameter or ensemble (multi-criteria) ranking options are provided. Consequently, this software is suitable for tasks like dimensionality reduction, feature ranking, as well as comparative diversity analysis of data matrices. Simple examples of applications performed with this program are presented. A comparative study between IMMAN and WEKA feature selection tools using the Arcene dataset was performed, demonstrating similar behavior. In addition, it is revealed that the use of IMMAN unsupervised feature selection methods improves the performance of both IMMAN and WEKA

  6. Offense-Defense Theory Analysis of Russian Cyber Capability (United States)


    out of rational self-interest.22 These fundamental assumptions and how they govern neorealist and neoliberal theory remain the subject of...Theory: The Neorealist- Neoliberal Debate Neorealism and its Critics. by Robert O. Keohane; Neorealism and Neoliberalism : The Contemporary Debate. by...10.1080/09592310902975539. Powell, Robert. “Anarchy in International Relations Theory: The Neorealist- Neoliberal Debate Neorealism and its Critics. by

  7. Analysis of elastic scattering at low momentum transfer

    International Nuclear Information System (INIS)

    Pumplin, J.


    A method for analyzing high energy elastic scattering data is described, which improves on previous methods to extract σ tot , σ el , B, and ρ=ReM(0)/ImM(0) from experiment by properly allowing for the curvature of 1ndσ/dt with t. The method is used to make a critical analysis of data at √s=19.4, 546, and 1800 GeV. It is found that previous analyses systematically underestimate the forward slope B. The large value of ρ obtained by UA4 at √s=546 GeV is shown to be doubtful. The method described here should aid in the analysis of forthcoming data from UA4/2 and E710. (orig.)

  8. International Migration, Income Taxes and Transfers: A Welfare Analysis


    Michael S. Michael


    An important issue in public policy debates is the effect of international migration on welfare in source and host countries. We address this issue by constructing a general equilibrium model of a two-class source or host country. Each country produces many traded and non-traded goods, uses income taxes and distributes the tax receipts equally to all individuals. The analysis examines the effects of permanent migration on class, and national welfare. We show, among other things, that marginal...

  9. Nuclear analysis software. Pt. 1: Spectrum transfer and reformatting (SPEDAC)

    International Nuclear Information System (INIS)


    GANAAS (Gamma, Activity, and Neutron Activation Analysis System) is one in the family of software packages developed under the auspices of the International Atomic Energy Agency. Primarily, the package was intended to support the IAEA Technical Assistance and Cooperation projects in developing countries. However, it is open domain software that can be copied and used by anybody, except for commercial purposes. All the nuclear analysis software provided by the IAEA has the same design philosophy and similar structure. The intention was to provide the user with maximum flexibility, at the same time with a simple and logical organization that requires minimum digging through the manuals. GANAAS is a modular system. It consists of several programmes that can be installed on the hard disk as the are needed. Obviously, some parts of they system are required in all cases. Those are installed at the beginning, without consulting the operator. GANAAS offers the opportunity to expand and improve the system. The gamma spectrum evaluation programmes using different fitting algorithms can be added to GANAAS, under the condition that the format of their input and output files corresponds to the rules of GANAAS. The same applies to the quantitative analysis parts of the programme

  10. Electronic Coupling Calculations for Bridge-Mediated Charge Transfer Using Constrained Density Functional Theory (CDFT) and Effective Hamiltonian Approaches at the Density Functional Theory (DFT) and Fragment-Orbital Density Functional Tight Binding (FODFTB) Level. (United States)

    Gillet, Natacha; Berstis, Laura; Wu, Xiaojing; Gajdos, Fruzsina; Heck, Alexander; de la Lande, Aurélien; Blumberger, Jochen; Elstner, Marcus


    In this article, four methods to calculate charge transfer integrals in the context of bridge-mediated electron transfer are tested. These methods are based on density functional theory (DFT). We consider two perturbative Green's function effective Hamiltonian methods (first, at the DFT level of theory, using localized molecular orbitals; second, applying a tight-binding DFT approach, using fragment orbitals) and two constrained DFT implementations with either plane-wave or local basis sets. To assess the performance of the methods for through-bond (TB)-dominated or through-space (TS)-dominated transfer, different sets of molecules are considered. For through-bond electron transfer (ET), several molecules that were originally synthesized by Paddon-Row and co-workers for the deduction of electronic coupling values from photoemission and electron transmission spectroscopies, are analyzed. The tested methodologies prove to be successful in reproducing experimental data, the exponential distance decay constant and the superbridge effects arising from interference among ET pathways. For through-space ET, dedicated π-stacked systems with heterocyclopentadiene molecules were created and analyzed on the basis of electronic coupling dependence on donor-acceptor distance, structure of the bridge, and ET barrier height. The inexpensive fragment-orbital density functional tight binding (FODFTB) method gives similar results to constrained density functional theory (CDFT) and both reproduce the expected exponential decay of the coupling with donor-acceptor distances and the number of bridging units. These four approaches appear to give reliable results for both TB and TS ET and present a good alternative to expensive ab initio methodologies for large systems involving long-range charge transfers.

  11. Calibration transfer based on maximum margin criterion for qualitative analysis using Fourier transform infrared spectroscopy. (United States)

    Hu, Yong; Peng, Silong; Bi, Yiming; Tang, Liang


    A traditional multivariate calibration transfer method such as piecewise direct standardization (PDS) is usually applied to quantitative analysis. To make the method apply to qualitative analysis of Fourier Transform Infrared spectroscopy (FTIR), we propose an improved calibration transfer method based on the maximum margin criterion (CTMMC). The new method not only considers the spectral changes under different conditions, but also takes into account the geometric characteristics of spectra from different classes, so the transformed spectra from different classes will be separated as far as possible, and this will improve the performance of the follow-up qualitative analysis. A comparative study is provided between the proposed method CTMMC and other traditional calibration transfer methods on two data sets. Experimental results show that the proposed method can achieve better performance than previous methods.

  12. Commercial non-aerospace technology transfer program for the 2000s: Strategic analysis and implementation (United States)

    Horsham, Gary A. P.


    This report presents a strategic analysis and implementation plan for NASA's Office of Commercial Programs (OCP), Technology Transfer Division's (TTD), Technology Transfer Program. The main objectives of this study are to: (1) characterize the NASA TTD's environment and past organizational structure; (2) clearly identify current and prospective programmatic efforts; (3) determine an evolutionary view of an organizational structure which could lead to the accomplishment of NASA's future technology transfer aims; and (4) formulate a strategy and plan to improve NASA's (and other federal agencies) ability to transfer technology to the non-aerospace sectors of the U.S. economy. The planning horizon for this study extends through the remainder of the 1990s to the year 2000.

  13. Theoretical Analysis for Heat Transfer Optimization in Subcritical Electrothermal Energy Storage Systems

    Directory of Open Access Journals (Sweden)

    Peng Hu


    Full Text Available Electrothermal energy storage (ETES provides bulk electricity storage based on heat pump and heat engine technologies. A subcritical ETES is described in this paper. Based on the extremum principle of entransy dissipation, a geometry model is developed for heat transfer optimization for subcritical ETES. The exergy during the heat transfer process is deduced in terms of entropy production. The geometry model is validated by the extremum principle of entropy production. The theoretical analysis results show that the extremum principle of entransy dissipation is an effective criterion for the optimization, and the optimum heat transfer for different cases with the same mass flux or pressure has been discussed. The optimum heat transfer can be achieved by adjusting the mass flux and pressure of the working fluid. It also reveals that with the increase of mass flux, there is a minimum exergy in the range under consideration, and the exergy decreases with the increase of the pressure.

  14. [Factors affecting activation and transference of soil colloidal phosphorus and related analysis technologies]. (United States)

    Zhao, Yue; Liang, Xin-qiang; Fu, Chao-dong; Zhu, Si-rui; Zhang, Yi-xiang; Ji, Yuan-jing


    Colloids play a key role in the transference process of phosphorus (P) in soil. Activation and transference of soil colloidal phosphorus have great effect on soil P pool and the surrounding water quality. This paper summarized the current studies on soil colloidal P, discussing the effects of the various factors (e. g., soil physical and chemical properties, fertilization, rainfall and soil amendments) on the transference of soil colloidal P. Some advanced analysis technologies (e.g., flow field-flow fractionation, transmission electron microscope-energy dispersive X-ray spectrometer, X-ray absorption near-edge structure and nuclear magnetic resonance) and methods of reducing soil colloidal P were also involved. This review would provide important information on the mechanism of soil colloidal P transference.

  15. Multicell slug flow heat transfer analysis of finite LMFBR bundles

    Energy Technology Data Exchange (ETDEWEB)

    Yeung, M.K.; Wolf, L.


    An analytical two-dimensional, multi-region, multi-cell technique has been developed for the thermal analysis of LMFBR rod bundles. Local temperature fields of various unit cells were obtained for 7, 19, and 37-rod bundles of different geometries and power distributions. The validity of the technique has been verified by its excellent agreement with the THTB calculational result. By comparing the calculated fully-developed circumferential clad temperature distribution with those of the experimental measurements, an axial correction factor has been derived to account for the entrance effect for practical considerations. Moreover, the knowledge of the local temperature field of the rod bundle leads to the determination of the effective mixing lengths L/sub ij/ for adjacent subchannels of various geometries. It was shown that the implementation of the accurately determined L/sub ij/ into COBRA-IIIC calculations has fairly significant effects on intersubchannel mixing. In addition, a scheme has been proposed to couple the 2-D distributed and lumped parameter calculation by COBRA-IIIC such that the entrance effect can be implanted into the distributed parameter analysis. The technique has demonstrated its applicability for a 7-rod bundle and the results of calculation were compared to those of three-dimensional analyses and experimental measurements.

  16. Thermal radiation heat transfer

    CERN Document Server

    Howell, John R; Mengüç, M Pinar


    Providing a comprehensive overview of the radiative behavior and properties of materials, the fifth edition of this classic textbook describes the physics of radiative heat transfer, development of relevant analysis methods, and associated mathematical and numerical techniques. Retaining the salient features and fundamental coverage that have made it popular, Thermal Radiation Heat Transfer, Fifth Edition has been carefully streamlined to omit superfluous material, yet enhanced to update information with extensive references. Includes four new chapters on Inverse Methods, Electromagnetic Theory, Scattering and Absorption by Particles, and Near-Field Radiative Transfer Keeping pace with significant developments, this book begins by addressing the radiative properties of blackbody and opaque materials, and how they are predicted using electromagnetic theory and obtained through measurements. It discusses radiative exchange in enclosures without any radiating medium between the surfaces-and where heat conduction...

  17. Theories of conduct disorder: a causal modelling analysis

    NARCIS (Netherlands)

    Krol, N.P.C.M.; Morton, J.; Bruyn, E.E.J. De


    Background: If a clinician has to make decisions on diagnosis and treatment, he or she is confronted with a variety of causal theories. In order to compare these theories a neutral terminology and notational system is needed. The Causal Modelling framework involving three levels of description –

  18. An Analysis of Stochastic Game Theory for Multiagent Reinforcement Learning

    National Research Council Canada - National Science Library

    Bowling, Michael


    .... In this paper we contribute a comprehensive presentation of the relevant techniques for solving stochastic games from both the game theory community and reinforcement learning communities. We examine the assumptions and limitations of these algorithms, and identify similarities between these algorithms, single agent reinforcement learners, and basic game theory techniques.

  19. Strategic analysis in evolutionary genetics and the theory of games

    Indian Academy of Sciences (India)


    This paper is written in memory of John Maynard Smith. In a brief survey it discusses essential aspects of how game theory in biology relates to its counterpart in eco- nomics, the major transition in game theory initiated by. Maynard Smith, the discrepancies between genetic and phenotypic models in evolutionary biology, ...

  20. An analysis of the concept of equilibrium in organization theory

    NARCIS (Netherlands)

    Gazendam, H.W.M.; Simons, John L.


    This article analyzes how the equilibrium concept is used in four organization theories: the theories of Fayol, Mintzberg, Morgan, and Volberda. Equilibrium can be defined as balance, fit or requisite variety. Equilibrium is related to observables dependent on the definition of organization as work

  1. An Analysis of Gardner's Theory of Multiple Intelligence. (United States)

    Morgan, Harry


    Howard Gardner's hypothesis of seven distinct types of intelligence is explained and each of the theorized intelligences is related to the theory of cognitive style. The article concludes that multiple intelligence theory is not about new "intelligences," but rather, a reframing of what others have defined as cognitive styles. (DB)

  2. Application of grounded theory approach in the analysis of ...

    African Journals Online (AJOL)

    This study examined the application of grounded theory in analyzing integrated primary health care (IPHC) in KwaZulu-Natal province. A description of the similarities and differences between the two approaches to grounded theory research, namely the Glaserian (after Barney Glaser) and the Straussian (after Anselm ...

  3. Strategic analysis in evolutionary genetics and the theory of games

    Indian Academy of Sciences (India)


    the theory of games. PETER HAMMERSTEIN*. Institute for Theoretical Biology, Humboldt University Berlin,. Invalidenstrasse 43, D-10115 Berlin, Germany ... John Maynard Smith; game theory; evolutionarily stable strategy; population genetics; genetic constraint; phenotypic ..... redundant activation signalling paths. If one of ...

  4. Analysis of trace gases at ppb levels by proton transfer reaction mass spectrometry (PTR-MS)

    International Nuclear Information System (INIS)

    Lindinger, W.; Hansel, A.


    A proton transfer reaction mass spectrometry (PTR-MS) system has been developed which allows for on-line measurements of trace gas components with concentrations as low as 1 ppb. The method is based on reactions of H 3 O + ions, which perform non-dissociative proton transfer to most of the common organic trace constituents but do not react with any of the components present in clean air. Examples of medical information obtained by means of breath analysis, of environmental trace analysis, and examples in the field of food chemistry demonstrate the wide applicability of the method. (Authors)

  5. Transferring the Incremental Capacity Analysis to Lithium-Sulfur Batteries

    DEFF Research Database (Denmark)

    Knap, Vaclav; Kalogiannis, Theodoros; Purkayastha, Rajlakshmi


    In order to investigate the battery degradation and to estimate their health, various techniques can be applied. One of them, which is widely used for Lithium-ion batteries, is the incremental capacity analysis (ICA). In this work, we apply the ICA to Lithium-Sulfur batteries, which differ in many...... aspects from Lithium-ion batteries and possess unique behavior. One of the challenges of applying the ICA to Lithium-Sulfur batteries is the representation of the IC curves, as their voltage profiles are often non-monotonic, resulting in more complex IC curves. The ICA is at first applied to charge...... and discharge processes at various temperature levels and afterward the technique is applied to a cell undergoing cycling degradation. It is shown that the ageing processes are trackable from the IC curves and it opens a possibility for their utilization for state-of-health estimation....

  6. Heat and Mass Transfer of Vacuum Cooling for Porous Foods-Parameter Sensitivity Analysis

    Directory of Open Access Journals (Sweden)

    Zhijun Zhang


    Full Text Available Based on the theory of heat and mass transfer, a coupled model for the porous food vacuum cooling process is constructed. Sensitivity analyses of the process to food density, thermal conductivity, specific heat, latent heat of evaporation, diameter of pores, mass transfer coefficient, viscosity of gas, and porosity were examined. The simulation results show that the food density would affect the vacuum cooling process but not the vacuum cooling end temperature. The surface temperature of food was slightly affected and the core temperature is not affected by the changed thermal conductivity. The core temperature and surface temperature are affected by the changed specific heat. The core temperature and surface temperature are affected by the changed latent heat of evaporation. The core temperature is affected by the diameter of pores. But the surface temperature is not affected obviously. The core temperature and surface temperature are not affected by the changed gas viscosity. The parameter sensitivity of mass transfer coefficient is obvious. The core temperature and surface temperature are affected by the changed mass transfer coefficient. In all the simulations, the end temperature of core and surface is not affected. The vacuum cooling process of porous medium is a process controlled by outside process.

  7. Vibration Analysis of a Framework Structure by Generalized Transfer Stiffness Coefficient Method (United States)

    Bonkobara, Yasuhiro; Kondou, Takahiro; Ayabe, Takashi; Choi, Myung-Soo

    A generalized transfer stiffness coefficient method using graph theory is developed in order to improve the applicability of the transfer stiffness coefficient method. In the new method, an analytical model is expressed by a weighted signal-flow graph, and the graph is contracted according to the series and parallel contraction rules. The computational complexity and the memory requirement for the contraction process are both minimized by choosing the optimal contraction route. In addition, it is possible to develop a data-driving program that is applicable to various structures without updating the source program. An algorithm based on the present method is formulated for the in-plane longitudinal and flexural coupled free and forced vibration analyses of a two-dimensional framework structure. Furthermore, an overview for applying the method to a three-dimensional framework structure is briefly presented. The validity of the present algorithm is confirmed by the results of numerical computations.

  8. Asymptotic equilibrium diffusion analysis of time-dependent Monte Carlo methods for grey radiative transfer

    International Nuclear Information System (INIS)

    Densmore, Jeffery D.; Larsen, Edward W.


    The equations of nonlinear, time-dependent radiative transfer are known to yield the equilibrium diffusion equation as the leading-order solution of an asymptotic analysis when the mean-free path and mean-free time of a photon become small. We apply this same analysis to the Fleck-Cummings, Carter-Forest, and N'kaoua Monte Carlo approximations for grey (frequency-independent) radiative transfer. Although Monte Carlo simulation usually does not require the discretizations found in deterministic transport techniques, Monte Carlo methods for radiative transfer require a time discretization due to the nonlinearities of the problem. If an asymptotic analysis of the equations used by a particular Monte Carlo method yields an accurate time-discretized version of the equilibrium diffusion equation, the method should generate accurate solutions if a time discretization is chosen that resolves temperature changes, even if the time steps are much larger than the mean-free time of a photon. This analysis is of interest because in many radiative transfer problems, it is a practical necessity to use time steps that are large compared to a mean-free time. Our asymptotic analysis shows that: (i) the N'kaoua method has the equilibrium diffusion limit, (ii) the Carter-Forest method has the equilibrium diffusion limit if the material temperature change during a time step is small, and (iii) the Fleck-Cummings method does not have the equilibrium diffusion limit. We include numerical results that verify our theoretical predictions

  9. Activity Analysis: Bridging the Gap between Production Economics Theory and Practical Farm Management Procedures


    Longworth, John W.; Menz, Kenneth M.


    This paper is addressed to the traditional problem of demonstrating the relevance of production theory to management-oriented people. Activity analysis, it is argued, is the most appropriate pedagogic framework within which to commence either a production economics or a farm management course. Production economics theory has not been widely accepted as a useful method for the analysis of practical management problems. The theory has been traditionally presented in terms of continuous function...


    Directory of Open Access Journals (Sweden)

    Putu Weddha Savitri


    Full Text Available In order to show and promote Balinese culture to the incoming tourists, many specific terms, especially in arts terms, must be well translated. This paper aims at analyzing the meaning transfer of Balinese Arts Terms into English and French found in Tourism Promotion Book published by Bali Government Tourism Department in two languages versions. The analysis focused on the techniques or procedures applied in transferring Balinese art terms into English (TL1 and French (TL2. Besides, it is also to figure out the most common technique used by the translator in transferring the meanings. The findings showed that there are three techniques used to transfer the meaning of the SL into the TL 1, those are descriptive, transcription, and functional equivalence, meanwhile, there are three translation techniques: transcription, functional equivalence, and formal equivalence and one translation procedure: cultural equivalence used in transferring the SL meaning to TL 2. Transcription technique, usually called borrowing was mostly used by the translator in the meaning transfer from the SL to both the target languages in order to retain the SL meaning in the TL.

  11. Inertial Sensor Based Analysis of Lie-to-Stand Transfers in Younger and Older Adults. (United States)

    Schwickert, Lars; Boos, Ronald; Klenk, Jochen; Bourke, Alan; Becker, Clemens; Zijlstra, Wiebren


    Many older adults lack the capacity to stand up again after a fall. Therefore, to analyse falls it is relevant to understand recovery patterns, including successful and failed attempts to get up from the floor in general. This study analysed different kinematic features of standing up from the floor. We used inertial sensors to describe the kinematics of lie-to-stand transfer patterns of younger and healthy older adults. Fourteen younger (20-50 years of age, 50% men) and 10 healthy older community dwellers (≥60 years; 50% men) conducted four lie-to-stand transfers from different initial lying postures. The analysed temporal, kinematic, and elliptic fitting complexity measures of transfer performance were significantly different between younger and older subjects (i.e., transfer duration, angular velocity (RMS), maximum vertical acceleration, maximum vertical velocity, smoothness, fluency, ellipse width, angle between ellipses). These results show the feasibility and potential of analysing kinematic features to describe the lie-to-stand transfer performance, to help design interventions and detection approaches to prevent long lies after falls. It is possible to describe age-related differences in lie-to-stand transfer performance using inertial sensors. The kinematic analysis remains to be tested on patterns after real-world falls.

  12. Geophysical Field Theory

    International Nuclear Information System (INIS)

    Eloranta, E.


    The geophysical field theory includes the basic principles of electromagnetism, continuum mechanics, and potential theory upon which the computational modelling of geophysical phenomena is based on. Vector analysis is the main mathematical tool in the field analyses. Electrostatics, stationary electric current, magnetostatics, and electrodynamics form a central part of electromagnetism in geophysical field theory. Potential theory concerns especially gravity, but also electrostatics and magnetostatics. Solid state mechanics and fluid mechanics are central parts in continuum mechanics. Also the theories of elastic waves and rock mechanics belong to geophysical solid state mechanics. The theories of geohydrology and mass transport form one central field theory in geophysical fluid mechanics. Also heat transfer is included in continuum mechanics. (orig.)

  13. Management Versus Non-Management Knowledge Transfer from Training to Real Work Environments: A Meta-Analysis

    National Research Council Canada - National Science Library


    .... A meta-analysis was performed with training transfer as a dependent variable and post-training independent variables of supervisor support, subordinate support, peer support, workplace support...

  14. New Analysis and Theory of Deployable Folded Structures, Phase I (United States)

    National Aeronautics and Space Administration — A recently developed mathematical theory has great value for deployable space structures and in situ manufacture of large beams, panels, cylinders and other...

  15. New Analysis and Theory of Deployable Folded Structures, Phase II (United States)

    National Aeronautics and Space Administration — A recently developed mathematical folding theory has great value for deployable space structures and in situ manufacture of large beams, panels and cylinders. The...

  16. Mokken scale analysis : Between the Guttman scale and parametric item response theory

    NARCIS (Netherlands)

    van Schuur, Wijbrandt H.


    This article introduces a model of ordinal unidimensional measurement known as Mokken scale analysis. Mokken scaling is based on principles of Item Response Theory (IRT) that originated in the Guttman scale. I compare the Mokken model with both Classical Test Theory (reliability or factor analysis)

  17. Using Molecular Modeling in Teaching Group Theory Analysis of the Infrared Spectra of Organometallic Compounds (United States)

    Wang, Lihua


    A new method is introduced for teaching group theory analysis of the infrared spectra of organometallic compounds using molecular modeling. The main focus of this method is to enhance student understanding of the symmetry properties of vibrational modes and of the group theory analysis of infrared (IR) spectra by using visual aids provided by…

  18. Chiral symmetry breaking in gauge theories from Reggeon diagram analysis

    International Nuclear Information System (INIS)

    White, A.R.


    It is argued that reggeon diagrams can be used to study dynamical properties of gauge theories containing a large number of massless fermions. SU(2) gauge theory is studied in detail and it is argued that there is a high energy solution which is analogous to the solution of the massless Schwinger model. A generalized winding-number condensate produces the massless pseudoscalar spectrum associated with chiral symmetry breaking and a ''trivial'' S-Matrix

  19. Conflict Analysis and Resolution Theories for Professional Military Education (United States)


    translating the diagnostic portion of the theory into useful action. In the above-mentioned case of Iraq this might have meant more detailed plans to manage ...34Nested Theory of Conflict." Leadership Journal: Women in Leadership - Sharing the Vision 1 (July 1996): 9-20. Gurr, Ted Robert. Why Men Rebel...Highway, Suits 1204, Arlington, VA 22202-4302, and to the Offloe of Management and Budget, Paperwork Reduclion Projecl (0704·0188) Washington, DC 20503

  20. The filmic emotion. A comparative analysis of film theories

    Directory of Open Access Journals (Sweden)

    Imanol Zumalde-Arregi, Ph.D.


    Full Text Available This article tries to explain the origins of the filmic emotion. Due to the lack of a widely agreed idea about the way film texts play with the emotional world of the empirical spectator, this work outlines the diverse arguments and approaches through which film theory has tried to explain the catalogue of emotions that a film can provoke in the spectator. This review reveals a conflict between the theories oriented to the spectator and context, and the theories focused on the text. There are, in fact, two approaches to evaluate the emotional effects provoked by films: the cultural studies approach, which is based on pragmatics and gender oriented theories, and focuses on the social and subjective conditions through which cinema is experienced, and the approach of structural semiotics and cognitive theory, which focuses on the way a film text tries to direct the spectator’s emotional experience. In the middle of these two approaches, the psychoanalytical theory conceives the filmic experience as a simulation of daily life.

  1. Phylogeny of nodulation and nitrogen-fixation genes in Bradyrhizobium: supporting evidence for the theory of monophyletic origin, and spread and maintenance by both horizontal and vertical transfer. (United States)

    Menna, Pâmela; Hungria, Mariangela


    /housekeeping genes, in addition to shorter nodY/K sequences and the absence of nodZ, highlights a co-evolution process. Additionally, in a group of B. japonicum strains that were symbionts of soybean, vertical transfer seemed to represent the main genetic event. In conclusion, clustering of nodA and nifH gives additional support to the theory of monophyletic origin of the symbiotic genes in Bradyrhizobium and, in addition to the analysis of nodY/K and nodZ, indicates spread and maintenance of nod and nif genes through both vertical and horizontal transmission, apparently with the dominance of one or other of these events in some groups of strains.

  2. Bending and free vibration analysis of thick isotropic plates by using exponential shear deformation theory

    Directory of Open Access Journals (Sweden)

    Sayyad A. S.


    Full Text Available This paper presents a variationally consistent an exponential shear deformation theory for the bi-directional bending and free vibration analysis of thick plates. The theory presented herein is built upon the classical plate theory. In this displacement-based, refined shear deformation theory, an exponential functions are used in terms of thickness co-ordinate to include the effect of transverse shear deformation and rotary inertia. The number of unknown displacement variables in the proposed theory are same as that in first order shear deformation theory. The transverse shear stress can be obtained directly from the constitutive relations satisfying the shear stress free surface conditions on the top and bottom surfaces of the plate, hence the theory does not require shear correction factor. Governing equations and boundary conditions of the theory are obtained using the dynamic version of principle of virtual work. The simply supported thick isotropic square and rectangular plates are considered for the detailed numerical studies. Results of displacements, stresses and frequencies are compared with those of other refined theories and exact theory to show the efficiency of proposed theory. Results obtained by using proposed theory are found to be agree well with the exact elasticity results. The objective of the paper is to investigate the bending and dynamic response of thick isotropic square and rectangular plates using an exponential shear deformation theory.

  3. Transfers, non-traded goods, and unemployment: an analysis of the Keynes – Ohlin debate

    NARCIS (Netherlands)

    S. Brakman (Steven); J.G.M. van Marrewijk (Charles)


    textabstractIn the famous debate between Keynes and Ohlin on the transfer problem, the interaction between non-traded goods and unemployment complicates the analysis considerably. We analyze these issues using four different models to conclude that Keynes’s concern regarding the large burden imposed

  4. Inter-subchannel heat transfer modeling for a subchannel analysis of liquid metal-cooled reactors

    International Nuclear Information System (INIS)

    Hae-Yong, Jeong; Kwi-Seok, Ha; Young-Min, Kwon; Yong-Bum, Lee; Dohee, Hahn


    In a subchannel approach, the temperature, pressure and velocity in a subchannel are averaged, and one representative thermal-hydraulic condition specifies the state of a subchannel. To enhance the predictability of a subchannel analysis code, it is required to model the inter-subchannel heat transfer between the adjacent subchannels as accurately as possible. One of the critical parameters which determine the thermal-hydraulic behavior of the coolant in subchannels is the heat conduction between two neighboring sub-channels. This portion of a heat transfer becomes more important in the design of an LMR (Liquid Metal-cooled Reactor) because of the high heat capacity of the liquid metal coolant. The other important part of heat transfer is the mixing of flow as a form of cross flow. Especially, the turbulent mixing caused by the eddy motion of fluid across the gap between the subchannels enhances the exchange of the momentum and the energy through the gap with no net transport of the mass. Major results of recent efforts on these modeling have been implemented in a subchannel analysis code MATRA-LMR-FB. The analysis shows that the accuracy of a subchannel analysis code is improved by enhancing the models describing the conduction heat transfer and the cross-flow mixing, especially at low flow rate. (authors)

  5. Noise and ac impedance analysis of ion transfer kinetics at the micro liquid/liquid interface

    Czech Academy of Sciences Publication Activity Database

    Josypčuk, Oksana; Holub, Karel; Mareček, Vladimír


    Roč. 56, JUL 2015 (2015), s. 43-45 ISSN 1388-2481 R&D Projects: GA ČR GA13-04630S Institutional support: RVO:61388955 Keywords : noise analysis * liquid/liquid interface * ion transfer kinetics Subject RIV: CG - Electrochemistry Impact factor: 4.569, year: 2015

  6. Numerical analysis of fluid flow and heat transfer in a helical ...

    African Journals Online (AJOL)

    DR OKE

    exchanger and analysis is done on ten helical ducts by changing the flow rates of four different fluids like water, ethanol, kerosene and Nano ... numerical study on double-pipe helical heat exchanger modeled for laminar fluid flow and heat transfer characteristics under different fluid flow .... Dynamic viscosity of fluid. Q. Heat ...

  7. Numerical analysis of inter-phase mass transfer with chemical reaction

    African Journals Online (AJOL)

    The numerical analysis in the present study simulates inter-phase mass transfer with chemical reaction of two immiscible liquids by simultaneously solving the Higbie Penetration model. The transport equations are solved numerically for concentration and temperature profiles at the inter-phase using finite volume method ...

  8. Visual to Print Transfer: A Literacy Strategy for Theme Analysis of Text (United States)

    Buelow, Stephanie


    This article shares a literacy strategy to support students' analysis of the theme of text and provide evidence to support their assertion. The strategy is called Visual to Print Transfer (VPT). The VPT strategy leverages students' out-of-school literacy practices involving media images of Hollywood icons as a way to support their understanding of…

  9. Microelectrode voltammetry of multi-electron transfers complicated by coupled chemical equilibria: a general theory for the extended square scheme. (United States)

    Laborda, Eduardo; Gómez-Gil, José María; Molina, Angela


    A very general and simple theoretical solution is presented for the current-potential-time response of reversible multi-electron transfer processes complicated by homogeneous chemical equilibria (the so-called extended square scheme). The expressions presented here are applicable regardless of the number of electrons transferred and coupled chemical processes, and they are particularized for a wide variety of microelectrode geometries. The voltammetric response of very different systems presenting multi-electron transfers is considered for the most widely-used techniques (namely, cyclic voltammetry, square wave voltammetry, differential pulse voltammetry and steady state voltammetry), studying the influence of the microelectrode geometry and the number and thermodynamics of the (electro)chemical steps. Most appropriate techniques and procedures for the determination of the 'interaction' between successive transfers are discussed. Special attention is paid to those situations where homogeneous chemical processes, such as protonation, complexation or ion association, affect the electrochemical behaviour of the system by different stabilization of the oxidation states.

  10. Single particle transfer for quantitative analysis with total-reflection X-ray fluorescence spectrometry

    International Nuclear Information System (INIS)

    Esaka, Fumitaka; Esaka, Konomi T.; Magara, Masaaki; Sakurai, Satoshi; Usuda, Shigekazu; Watanabe, Kazuo


    The technique of single particle transfer was applied to quantitative analysis with total-reflection X-ray fluorescence (TXRF) spectrometry. The technique was evaluated by performing quantitative analysis of individual Cu particles with diameters between 3.9 and 13.2 μm. The direct quantitative analysis of the Cu particle transferred onto a Si carrier gave a discrepancy between measured and calculated Cu amounts due to the absorption effects of incident and fluorescent X-rays within the particle. By the correction for the absorption effects, the Cu amounts in individual particles could be determined with the deviation within 10.5%. When the Cu particles were dissolved with HNO 3 solution prior to the TXRF analysis, the deviation was improved to be within 3.8%. In this case, no correction for the absorption effects was needed for quantification

  11. Visualizing context through theory deconstruction: a content analysis of three bodies of evaluation theory literature. (United States)

    Vo, Anne T


    While the evaluation field collectively agrees that contextual factors bear on evaluation practice and related scholarly endeavors, the discipline does not yet have an explicit framework for understanding evaluation context. To address this gap in the knowledge base, this paper explores the ways in which evaluation context has been addressed in the practical-participatory, values-engaged, and emergent realist evaluation literatures. Five primary dimensions that constitute evaluation context were identified for this purpose: (1) stakeholder; (2) program; (3) organization; (4) historical/political; and (5) evaluator. Journal articles, book chapters, and conference papers rooted in the selected evaluation approaches were compared along these dimensions in order to explore points of convergence and divergence in the theories. Study results suggest that the selected prescriptive theories most clearly explicate stakeholder and evaluator contexts. Programmatic, organizational, and historical/political contexts, on the other hand, require further clarification. Copyright © 2012 Elsevier Ltd. All rights reserved.

  12. Verification of radiation heat transfer analysis in KSTAR PFC and vacuum vessel during baking

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, S.Y. [Chungnam National University, 79 Daehak-ro, Yuseong-gu, Daejeon 34167 (Korea, Republic of); Kim, Y.J., E-mail: [National Fusion Research Institute, 169-148 Gwahang-ro, Yuseong-gu, Daejeon 34133 (Korea, Republic of); Kim, S.T.; Jung, N.Y.; Im, D.S.; Gong, J.D.; Lee, J.M.; Park, K.R.; Oh, Y.K. [National Fusion Research Institute, 169-148 Gwahang-ro, Yuseong-gu, Daejeon 34133 (Korea, Republic of)


    Highlights: • Thermal network is used to analyze heat transfer from PFC to VV. • Three heat transfer rate equations are derived based on the thermal network. • The equations is verified using Experimental data and design documents. • Most of the heat lost in tokamak is transferred to experimental room air. • The heat loss to the air is 101 kW of the total heat loss of 154 kW in tokamak. - Abstract: KSTAR PFC (Plasma Facing Component) and VV (Vacuum Vessel) were not arrived at the target temperatures in bake-out phase, which are 300 °C and 110 °C, respectively. The purpose of this study is to find out the reason why they have not been reached the target temperature. A thermal network analysis is used to investigate the radiation heat transfer from PFC to VV, and the thermal network is drawn up based on the actual KSTAR tokamak. The analysis model consists of three equations, and is solved using the EES (Engineering Equation Solver). The heat transfer rates obtained with the analysis model is verified using the experimental data at the KSTAR bake-out phase. The analyzed radiation heat transfer rates from PFC to VV agree quite well with those of experiment throughout the bake-out phase. Heat loss from PFC to experimental room air via flange of VV is also calculated and compared, which is found be the main reason of temperature gap between the target temperature and actually attained temperature of KSTAR PFC.

  13. K-shell Analysis Reveals Distinct Functional Parts in an Electron Transfer Network and Its Implications for Extracellular Electron Transfer. (United States)

    Ding, Dewu; Li, Ling; Shu, Chuanjun; Sun, Xiao


    Shewanella oneidensis MR-1 is capable of extracellular electron transfer (EET) and hence has attracted considerable attention. The EET pathways mainly consist of c-type cytochromes, along with some other proteins involved in electron transfer processes. By whole genome study and protein interactions inquisition, we constructed a large-scale electron transfer network containing 2276 interactions among 454 electron transfer related proteins in S. oneidensis MR-1. Using the k-shell decomposition method, we identified and analyzed distinct parts of the electron transfer network. We found that there was a negative correlation between the k s (k-shell values) and the average DR_100 (disordered regions per 100 amino acids) in every shell, which suggested that disordered regions of proteins played an important role during the formation and extension of the electron transfer network. Furthermore, proteins in the top three shells of the network are mainly located in the cytoplasm and inner membrane; these proteins can be responsible for transfer of electrons into the quinone pool in a wide variety of environmental conditions. In most of the other shells, proteins are broadly located throughout the five cellular compartments (cytoplasm, inner membrane, periplasm, outer membrane, and extracellular), which ensures the important EET ability of S. oneidensis MR-1. Specifically, the fourth shell was responsible for EET and the c-type cytochromes in the remaining shells of the electron transfer network were involved in aiding EET. Taken together, these results show that there are distinct functional parts in the electron transfer network of S. oneidensis MR-1, and the EET processes could achieve high efficiency through cooperation through such an electron transfer network.

  14. Low-noise hydraulic power unit design based on vibration modal and transfer function analysis


    SUN Yinghui; LI Zhiyin; LI Jia; PENG Wenbo


    The hydraulic power unit is the power source of a hydraulic system, and also the source causing hydraulic system vibration and noise. In order to further reduce the vibration and noise level of hydraulic systems, this paper presents a low-noise hydraulic station design method based on modal analysis and Vibration Transfer Function(VTF) analysis. The finite element model of the hydraulic station is established, the mode of the oil station solved and the modal superposition method used to optim...

  15. Theory of proton coupled electron transfer reactions: Assessing the Born-Oppenheimer approximation for the proton motion using an analytically solvable model

    International Nuclear Information System (INIS)

    Zheng Renhui; Jing Yuanyuan; Chen Liping; Shi Qiang


    Graphical abstract: An analytically solvable model was employed to study proton coupled electron transfer reactions. Approximated theories are assessed, and vibrational coherence is observed in case of small reorganization energy. Research highlights: → The Duschinsky rotation effect in PCET reactions. → Assessment of the BO approx. for proton motion using an analytically solvable model. → Vibrational coherence in PCET in the case of small reorganization energy. - Abstract: By employing an analytically solvable model including the Duschinsky rotation effect, we investigated the applicability of the commonly used Born-Oppenheimer (BO) approximation for separating the proton and proton donor-acceptor motions in theories of proton coupled electron transfer (PCET) reactions. Comparison with theories based on the BO approximation shows that, the BO approximation for the proton coordinate is generally valid while some further approximations may become inaccurate in certain range of parameters. We have also investigated the effect of vibrationally coherent tunneling in the case of small reorganization energy, and shown that it plays an important role on the rate constant and kinetic isotope effect.

  16. Extension of the diffusion controlled electron transfer theory for intermittent fluorescence of quantum dots: inclusion of biexcitons and the difference of "on" and "off" time distributions. (United States)

    Zhu, Zhaoyan; Marcus, R A


    The equations for the diffusion controlled electron transfer (DCET) theory of quantum dot blinking are extended to include biexcitons. In contrast to excitons, which undego resonant light to dark transitions, the biexcitons, having a much larger total energy, undergo a Fermi's Golden rule type transfer (many acceptance states). The latter immediately gives rise to an exponential tail for the light state, and it is explained why the dark state power law behavior is unaffected. Results are given for both continuous and pulsed excitation. The typical -3/2 power law for the light state at low light intensities, and for the dark state at all intensities, as well as dependence of the exponential tail on the square of the light intensity, and a decrease of the power in the power law for the light state from -3/2 to less negative values with increasing light intensity are all consistent with the theory. The desirability of measuring the dependence of the spectral diffusion coefficient on light intensity at room temperature as a test of several aspects of the theory is noted.

  17. Modelling the heat and mass transfer analysis during oil-frying of cylindrical sausages

    Energy Technology Data Exchange (ETDEWEB)

    Yildiz, Mustafa [Tubitak-Marmara Research Center, Kocaeli (Turkey). Dept. of Food and Refrigeration Technology; Dincer, Ibrahim [Victoria Univ., BC (Canada). Dept. of Mechanical Engineering


    An analytical and experimental study was performed on the analysis of the heat and mass transfer within cylindrically shaped sausages during deep-oil frying. Experiments were conducted to determine temperature distribution at the centre of an individual sample and the changes in the weight, moisture and oil contents of the samples. The proposed approach was used to estimate these parameters theoretically. Good agreement was found between the experimental and theoretical results. The results of this study indicates that the proposed approach is capable of analysing the heat and mass transfer during frying of the cylindrical sample. (author)

  18. Fire hazards analysis for the replacement cross-site transfer system, project W-058

    International Nuclear Information System (INIS)

    Sepahpur, J.B.


    The fire hazards analysis assess the risk from fire and determines compliance with the applicable criteria of DOE 5480.7A, DOE 6430.1A, and RLID 5480.7. (Project W-058 will provide encased pipelines to connect the SY Tank Farms in 200 West Area with the tank farms in 200 East Area via an interface with the 244-A lift station. Function of the cross-site transfer system will be to transfer radioactive waste from the SY Tank Farm to treatment, storage, and disposal facilities in 200 East Area.)

  19. Finite element analysis of the middle ear transfer functions and related pathologies. (United States)

    Zhao, Fei; Koike, Takuji; Wang, Jie; Sienz, Hans; Meredith, Rhys


    With developments in software and micro-measurement technology, a three-dimensional middle ear finite element (FE) model can now be more easily constructed to study sound transfer function. Many FE models of the middle ear have been constructed to date, and each has its own particular advantages and disadvantages. In this article, we review the latest developments and technologies in the field of the FE models of the middle ear, and the use of FE in the study of middle ear pathology. Proposals are made for future developments in the field of finite element analysis of middle ear transfer function.

  20. Analysis of the Influence of Compensation Capacitance Errors of a Wireless Power Transfer System with SS Topology

    Directory of Open Access Journals (Sweden)

    Yi Wang


    Full Text Available In this study, in order to determine the reasonable accuracy of the compensation capacitances satisfying the requirements on the output characteristics for a wireless power transfer (WPT system, taking the series-series (SS compensation structure as an example, the calculation formulas of the output characteristics, such as the power factor, output power, coil transfer efficiency, and capacitors’ voltage stress, are given under the condition of incomplete compensation according to circuit theory. The influence of compensation capacitance errors on the output characteristics of the system is then analyzed. The Taylor expansions of the theoretical formulas are carried out to simplify the formulas. The influence degrees of compensation capacitance errors on the output characteristics are calculated according to the simplified formulas. The reasonable error ranges of the compensation capacitances are then determined according to the requirements of the output characteristics of the system in the system design. Finally, the validity of the theoretical analysis and the simplified processing is verified through experiments. The proposed method has a certain guiding role for practical engineering design, especially in mass production.

  1. Between practice and theory: Melanie Klein, Anna Freud and the development of child analysis. (United States)

    Donaldson, G


    An examination of the early history of child analysis in the writings of Melanie Klein and Anna Freud reveals how two different and opposing approaches to child analysis arose at the same time. The two methods of child analysis are rooted in a differential emphasis on psychoanalytic theory and practice. The Kleinian method derives from the application of technique while the Anna Freudian method is driven by theory. Furthermore, by holding to the Freudian theory of child development Anna Freud was forced to limit the scope of child analysis, while Klein's application of Freudian practice has led to new discoveries about the development of the infant psyche.

  2. Nurse-surgeon object transfer: video analysis of communication and situation awareness in the operating theatre. (United States)

    Korkiakangas, Terhi; Weldon, Sharon-Marie; Bezemer, Jeff; Kneebone, Roger


    One of the most central collaborative tasks during surgical operations is the passing of objects, including instruments. Little is known about how nurses and surgeons achieve this. The aim of the present study was to explore what factors affect this routine-like task, resulting in fast or slow transfer of objects. A qualitative video study, informed by an observational ethnographic approach, was conducted in a major teaching hospital in the UK. A total of 20 general surgical operations were observed. In total, approximately 68 h of video data have been reviewed. A subsample of 225 min has been analysed in detail using interactional video-analysis developed within the social sciences. Two factors affecting object transfer were observed: (1) relative instrument trolley position and (2) alignment. The scrub nurse's instrument trolley position (close to vs. further back from the surgeon) and alignment (gaze direction) impacts on the communication with the surgeon, and consequently, on the speed of object transfer. When the scrub nurse was standing close to the surgeon, and "converged" to follow the surgeon's movements, the transfer occurred more seamlessly and faster (1.0 s). The smoothness of object transfer can be improved by adjusting the scrub nurse's instrument trolley position, enabling a better monitoring of surgeon's bodily conduct and affording early orientation (awareness) to an upcoming request (changing situation). Object transfer is facilitated by the surgeon's embodied practices, which can elicit the nurse's attention to the request and, as a response, maximise a faster object transfer. A simple intervention to highlight the significance of these factors could improve communication in the operating theatre. Copyright © 2014 Elsevier Ltd. All rights reserved.

  3. Does theory influence the effectiveness of health behavior interventions? Meta-analysis. (United States)

    Prestwich, Andrew; Sniehotta, Falko F; Whittington, Craig; Dombrowski, Stephan U; Rogers, Lizzie; Michie, Susan


    To systematically investigate the extent and type of theory use in physical activity and dietary interventions, as well as associations between extent and type of theory use with intervention effectiveness. An in-depth analysis of studies included in two systematic reviews of physical activity and healthy eating interventions (k = 190). Extent and type of theory use was assessed using the Theory Coding Scheme (TCS) and intervention effectiveness was calculated using Hedges's g. Metaregressions assessed the relationships between these measures. Fifty-six percent of interventions reported a theory base. Of these, 90% did not report links between all of their behavior change techniques (BCTs) with specific theoretical constructs and 91% did not report links between all the specified constructs with BCTs. The associations between a composite score or specific items on the TCS and intervention effectiveness were inconsistent. Interventions based on Social Cognitive Theory or the Transtheoretical Model were similarly effective and no more effective than interventions not reporting a theory base. The coding of theory in these studies suggested that theory was not often used extensively in the development of interventions. Moreover, the relationships between type of theory used and the extent of theory use with effectiveness were generally weak. The findings suggest that attempts to apply the two theories commonly used in this review more extensively are unlikely to increase intervention effectiveness. PsycINFO Database Record (c) 2014 APA, all rights reserved.

  4. Risk Contagion in Chinese Banking Industry: A Transfer Entropy-Based Analysis

    Directory of Open Access Journals (Sweden)

    Jianping Li


    Full Text Available What is the impact of a bank failure on the whole banking industry? To resolve this issue, the paper develops a transfer entropy-based method to determine the interbank exposure matrix between banks. This method constructs the interbank market structure by calculating the transfer entropy matrix using bank stock price sequences. This paper also evaluates the stability of Chinese banking system by simulating the risk contagion process. This paper contributes to the literature on interbank contagion mainly in two ways: it establishes a convincing connection between interbank market and transfer entropy, and exploits the market information (stock price rather than presumptions to determine the interbank exposure matrix. Second, the empirical analysis provides an in depth understanding of the stability of the current Chinese banking system.

  5. Transcriptional analysis of the leading region in F plasmid DNA transfer. (United States)

    Cram, D; Ray, A; O'Gorman, L; Skurray, R


    Transcriptional activity associated with the leading region (53.8-66.7F) in F DNA transfer has been shown by RNA-DNA hybridization studies to occur on the anterior segment extending from 59.4 to 66.7F. Promoter-probe analysis of cloned leading region segments detected two promoters within the transcribed portion of the leading region. The promoter active across the 64.7F EcoRI site on the transferred F strand was associated with the expression of two polypeptides, 6d and 13.5p, located between 64.7-66.6F. However, no definite role could be ascribed to the second promoter operative through the 66.6F Bg/II site located in close proximity to oriT, the origin of transfer.

  6. Analysis and hazard evaluation of heat-transfer fluids for the direct contact cooling system

    International Nuclear Information System (INIS)

    Hong, Joo Hi; Lee, Yeon Hee; Shin, You Hwan; Karng, Sarng Woo; Kim, Seo Young; Kim, Young Gil


    This paper discusses several low-temperature heat-transfer fluids, including water-based inorganic salt, organic salt, alcohol/glycol mixtures, silicones, and halogenated hydrocarbons in order to choose the best heat-transfer fluid for the newly designed direct contact refrigeration system. So, it contains a survey on commercial products such as propylene glycol and potassium formate as newly used in super market and food processing refrigeration. The stability of commercial fluids at the working temperature of -20 .deg. C was monitored as a function of time up to two months. And organic and inorganic compositions of candidate fluids were obtained by analytical instruments such as ES, XRF, AAS, ICP-AES, GC, and GC-MS. Analysis results indicate that commercial propylene glycol is very efficient and safe heat transfer fluids for the direct cooling system with liquid phase

  7. On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. V. Comparison and Properties of Electrochemical and Chemical Rate Constants (United States)

    Marcus, R. A.


    Using a theory of electron transfers which takes cognizance of reorganization of the medium outside the inner coordination shell and of changes of bond lengths inside it, relations between electrochemical and related chemical rate constants are deduced and compared with the experimental data. A correlation is found, without the use of arbitrary parameters. Effects of weak complexes with added electrolytes are included under specified conditions. The deductions offer a way of coordinating a variety of data in the two fields, internally as well as with each those in another. For example, the rate of oxidation or reduction of a series of related reactants by one reagent is correlated with that of another and with that of the corresponding electrochemical oxidation-reduction reaction, under certain specified conditions. These correlations may also provide a test for distinguishing an electron from an atom transfer mechanism. (auth)

  8. Complete Relaxation and Conformational Exchange Matrix (CORCEMA) Analysis of NOESY Spectra of Interacting Systems; Two-Dimensional Transferred NOESY (United States)

    Moseley, H. N. B.; Curto, E. V.; Krishna, N. R.


    A very general procedure entitled complete relaxation and conformational exchange matrix (CORCEMA) analysis has been developed to analyze the 2D-NOESY spectra of interacting systems undergoing multistate conformational exchange. This is an extension of earlier work from this laboratory on the methodological treatment of multistate conformational exchange [Krishna et al., Biopolymers19, 2003 (1980)] and the theory of transferred NOESY for finite exchange off-rates [Lee and Krishna, J. Magn. Reson.98, 36 (1992)]. The current theory is based on generalized rate matrices for relaxation and conformational exchange, The CORCEMA algorithm explicitly incorporates intermolecular dipolar cross relaxation between the molecules when they are complexed. It permits an analysis of NOESY intensities for the intra- as well as intermolecular contacts between the interacting molecules under a variety of binding conditions, Its application is illustrated on two examples of transferred NOESY simulations: (1) a two-state system involving a ligand and an enzyme forming a ligand-enzyme complex, and (2) a three-state system in which the ligand-enzyme complex can undergo a conformational transition from an "open state" to a "closed state," and can include conformational changes in both the complexed ligand and the complexed enzyme, such as hinge-bending motions, Simplifying expressions for generalized matrix analyses are derived for three limiting cases of the three-state system, This three-state example is illustrated using a hypothetical model of the hinge-bending motion in a thermolysin-inhibitor complex. It is shown that: (1) The neglect of cross relaxation between the interacting species in their complexed forms can lead to misleading conclusions on the "bound" conformation of the ligand. (2) If protein-mediated spin diffusion is dominant, caution is needed in analyses based on initial slopes alone due to one‧s inability to identify the exact range of the initial growth curve under

  9. Exergy loss analysis of heat transfer across the wall of the dividing-wall distillation column

    International Nuclear Information System (INIS)

    Suphanit, B.; Bischert, A.; Narataruksa, P.


    The dividing-wall distillation column is thermodynamically equivalent to the Petlyuk column on the condition that no heat transfer is allowed across the dividing wall. However, better energy efficiency of the column may be obtained if heat transfer occurs within a certain part of the wall. The effects of heat transfer across the dividing wall can be analyzed by using the column grand composite curve (CGCC). The heat transfer potential across the wall can be observed by looking at the CGCC of both column sections alongside the dividing wall. However, the possibility of whether heat should be added or rejected at any stage is not clearly known ahead of the CGCC. Consequently, in this work, the exergy analysis is applied to the dividing-wall column in order to determine whether heat should be added or rejected at any particular stage. Also, the minimum exergy loss value in the column is set as the criterion for determining the heat load targets at any stage. These load targets can then be plotted as a T-H profile similar to the CGCC. This methodology was reported to successfully apply to the column with multiple feeds and products. After having identified the locations and quantities of the feasible heat transfer across the dividing wall, the benefits are discussed via three case studies

  10. A heat transfer analysis of the CCI experiments 1-3

    International Nuclear Information System (INIS)

    Sevon, Tuomo


    This paper presents an attempt to evaluate the heat transfer rates and gas release rates in the CCI core-concrete interaction experiments 1-3, performed within the OECD MCCI project. A new method for calculating the heat transfer rates has been developed. It is based on calculating integrals of the concrete enthalpies with the help of piecewise exponential interpolation curves. The new method takes into account heat conduction in the concrete. Compared to traditional methods, the new method gives better results during slow concrete ablation, and its time resolution is significantly better. The gas release rates from the concrete were also calculated. A regression analysis was conducted for the heat transfer coefficients and gas release rates. Three correlations for the bubbling-enhanced heat transfer were developed. For the basemat, a single correlation can be used for both siliceous and limestone/common sand (LCS) concrete types. For the sidewall, two different correlations are needed for the two concrete types. With the same superficial gas velocity, the heat transfer rate to siliceous sidewalls is higher than to LCS sidewalls. This suggests that the reason for the different radial ablation rates of the concrete types observed in the tests is not the lower gas content of siliceous concrete

  11. Alternative definitions of the frozen energy in energy decomposition analysis of density functional theory calculations. (United States)

    Horn, Paul R; Head-Gordon, Martin


    In energy decomposition analysis (EDA) of intermolecular interactions calculated via density functional theory, the initial supersystem wavefunction defines the so-called "frozen energy" including contributions such as permanent electrostatics, steric repulsions, and dispersion. This work explores the consequences of the choices that must be made to define the frozen energy. The critical choice is whether the energy should be minimized subject to the constraint of fixed density. Numerical results for Ne2, (H2O)2, BH3-NH3, and ethane dissociation show that there can be a large energy lowering associated with constant density orbital relaxation. By far the most important contribution is constant density inter-fragment relaxation, corresponding to charge transfer (CT). This is unwanted in an EDA that attempts to separate CT effects, but it may be useful in other contexts such as force field development. An algorithm is presented for minimizing single determinant energies at constant density both with and without CT by employing a penalty function that approximately enforces the density constraint.

  12. Buckling analysis of thick plates using refined trigonometric shear deformation theory

    Directory of Open Access Journals (Sweden)

    Sachin Madhavrao Gunjal


    Full Text Available In this paper, a refined trigonometric shear deformation plate theory is applied for the buckling analysis of thick isotropic square and rectangular plates. The theory involves only two unknowns, as against three in first order shear deformation theory and other higher order theories. The theory involves sinusoidal function in the in-plane displacement. The transverse displacement involves bending and shear components. Governing equations and boundary conditions of the theory are obtained using the principle of virtual work. A simply supported isotropic rectangular plate subjected to uniaxial and biaxial compression is considered for the detailed numerical study. Results of critical buckling load for simply supported isotropic rectangular plates are compared with those of other refined theories.

  13. The use of Theory in Family Therapy Research: Content Analysis and Update. (United States)

    Chen, Ruoxi; Hughes, Alexandria C; Austin, Jason P


    In this study, we evaluated 275 empirical studies from Journal of Marital and Family Therapy and Family Process from 2010 to 2015 on their use of theory, and compared our findings to those of a similar previous analysis (Hawley & Geske, 2000). Overall, theory seems to have become much better incorporated in empirical family therapy research, with only 16.4% of the articles not using theory in either their introductory or discussion sections. Theory appeared better incorporated in the introductory sections than in the discussion sections. Systems theory remained the most commonly used conceptual framework, followed by attachment theory. We discuss areas for improving theory incorporation in family therapy research, and offer suggestions for both family therapy researchers and educators. © 2017 American Association for Marriage and Family Therapy.

  14. Analysis of the radical hydrogen transfer pathway for cleaving strong bonds in coal

    Energy Technology Data Exchange (ETDEWEB)

    Autrey, S.T.; Camaioni, D.M.; Ferris, K.F.; Franz, J.A.


    Hydrogen transfer processes involving radical intermediates are of key importance in the liquefaction of coal. While the primary function of donor solvents is to transfer H{lg_bullet} to coal-derived radicals that form when weak bonds are cleaved thermolytically, growing evidence suggests that the donor solvent can play a role in promoting cleavage of strong {alpha}-bonds. McMillen and Malhotra have explained the results in terms of a single-step mechanism referred to as radical H-transfer (RHT). Mechanistic kinetic models have been used to suggest the importance of RHT pathways in anthracene- and pyrene-based solvent systems. However, we question the reliability of these approaches because little experimental data exists to support the 16.5 kcal/mol intrinsic barriers they assume for RHT reactions. Unambiguous evidence for RHT is very difficult to obtain experimentally because at the temperatures required to activate the RHT reaction, a suite of multistep reactions can occur, which yield the same products, i.e. H-elimination from hydroaryl radicals followed by ipso addition. For this reason, we have sought to gain insight to barrier heights for RHT from theory. This paper reports our use of Marcus theory in combination with ab initio and semiempirical molecular orbital methods to show how the intrinsic barriers for RHT reactions depend on structural and thermodynamic properties of the reacting partners. In addition, reactions thought to be mediated by RHT are reexamined using mechanistic kinetic modeling (MKM) to determine the extent to which these reactions can be explained by conventional pathways.

  15. Conference on Geometric Analysis &Conference on Type Theory, Homotopy Theory and Univalent Foundations : Extended Abstracts Fall 2013

    CERN Document Server

    Yang, Paul; Gambino, Nicola; Kock, Joachim


    The two parts of the present volume contain extended conference abstracts corresponding to selected talks given by participants at the "Conference on Geometric Analysis" (thirteen abstracts) and at the "Conference on Type Theory, Homotopy Theory and Univalent Foundations" (seven abstracts), both held at the Centre de Recerca Matemàtica (CRM) in Barcelona from July 1st to 5th, 2013, and from September 23th to 27th, 2013, respectively. Most of them are brief articles, containing preliminary presentations of new results not yet published in regular research journals. The articles are the result of a direct collaboration between active researchers in the area after working in a dynamic and productive atmosphere. The first part is about Geometric Analysis and Conformal Geometry; this modern field lies at the intersection of many branches of mathematics (Riemannian, Conformal, Complex or Algebraic Geometry, Calculus of Variations, PDE's, etc) and relates directly to the physical world, since many natural phenomena...

  16. Quantitative analysis of transformed ray transferences of optical systems in a space of augmented Hamiltonian matrices*

    Directory of Open Access Journals (Sweden)

    W. F. Harris


    Full Text Available There is a need for methods for quantitative analysis of the first-order optical character of optical systems including the eye and components of the eye.  Because of their symplectic nature ray transferences themselves are not closed under addition and multiplication by ascalar and, hence, are not amenable to conventional quantitative analysis such as the calculation of an arithmetic mean.  However transferences can be transformed into augmented Hamiltonian matrices which are amenable to such analysis.  This paper provides a general methodology and in particular shows how to calculate means and variance-covariances representing the first-order optical character of optical systems.  The systems may be astigmatic and may have decentred elements.  An accompanying paper shows application to the cornea of the human eye with allowance for thickness.

  17. The Analysis of the Relationship between Clean Technology Transfer and Chinese Intellectual Property Countering the Climate Changes

    DEFF Research Database (Denmark)

    Min, Hao

    This report discusses the relationship between the Chinese intellectual property systems which counter with the climate change and the transfer of clean technology, and states how to encourage the developed countries transfer the clean technology to the developing countries according...... to the relative international climate convention program. The report also proposes the current hindrances and developing strategies according to Chinese current situation at this field. The report is mainly divided into three subjects: the relationship between clean technology transfer and the intellectual...... property countering the climate changes; the analysis of current technology transfer modes relating to the climate; the difficulties of Chinese countering climate changes technology transfer and strategic thinking....

  18. Charts Adapted from Van Driest's Turbulent Flat-plate Theory for Determining Values of Turbulent Aerodynamic Friction and Heat-transfer Coefficients (United States)

    Lee, Dorothy B; Faget, Maxime A


    A modified method of Van Driest's flat-plate theory for turbulent boundary layer has been found to simplify the calculation of local skin-friction coefficients which, in turn, have made it possible to obtain through Reynolds analogy theoretical turbulent heat-transfer coefficients in the form of Stanton number. A general formula is given and charts are presented from which the modified method can be solved for Mach numbers 1.0 to 12.0, temperature ratios 0.2 to 6.0, and Reynolds numbers 0.2 times 10 to the 6th power to 200 times 10 to the 6th power.

  19. Thermodynamic Models from Fluctuation Solution Theory Analysis of Molecular Simulations

    DEFF Research Database (Denmark)

    Christensen, Steen; Peters, Günther H.j.; Hansen, Flemming Yssing


    Fluctuation solution theory (FST) is employed to analyze results of molecular dynamics (MD) simulations of liquid mixtures. The objective is to generate parameters for macroscopic GE-models, here the modified Margules model. We present a strategy for choosing the number of parameters included...

  20. Bond energy decomposition analysis for subsystem density functional theory

    NARCIS (Netherlands)

    Beyhan, S.M.; Gotz, A.W.; Visscher, L.


    We employed an explicit expression for the dispersion (D) energy in conjunction with Kohn-Sham (KS) density functional theory and frozen-density embedding (FDE) to calculate interaction energies between DNA base pairs and a selected set of amino acid pairs in the hydrophobic core of a small protein

  1. Classical Stasis Theory and the Analysis of Public Policy. (United States)

    Hatch, Gary Layne

    In classical Greece, there was a close tie between rhetoric and the practice and theory of public policy. Gradually, however, rhetoric became increasingly concerned with style and literary criticism, while philosophers began to debate political issues apart from the practical affairs of the polis. Because rhetoric provides a model that can still…

  2. Accurate analysis of planar metamaterials using the RLC theory

    DEFF Research Database (Denmark)

    Malureanu, Radu; Lavrinenko, Andrei


    In this work we will present an accurate description of metallic pads response using RLC theory. In order to calculate such response we take into account several factors including the mutual inductances, precise formula for determining the capacitance and also the pads’ resistance considering the...

  3. Discussion: The Forward Search: Theory and Data Analysis

    DEFF Research Database (Denmark)

    Johansen, Søren; Nielsen, Bent


    The Forward Search Algorithm is a statistical algorithm for obtaining robust estimators of regression coefficients in the presence of outliers. The algorithm selects a succession of subsets of observations from which the parameters are estimated. The present note shows how the theory of empirical...

  4. Analysis Of Chemical Bonding Using Ab Initio Valence Bond Theory

    NARCIS (Netherlands)

    Engelberts, J.J.


    In this thesis, theoretical chemical research is presented in which the Valence Bond (VB) Theory plays a central role. For the last three chapters, the VB method is used, in combination with Magnetically Induced Ring Currents, to analyze the aromaticity of several conjugated molecules. The

  5. Bridging Levels of Analysis: Learning, Information Theory, and the Lexicon (United States)

    Dye, Melody


    While information theory is typically considered in the context of modern computing and engineering, its core mathematical principles provide a potentially useful lens through which to consider human language. Like the artificial communication systems such principles were invented to describe, natural languages involve a sender and receiver, a…

  6. Item Response Data Analysis Using Stata Item Response Theory Package (United States)

    Yang, Ji Seung; Zheng, Xiaying


    The purpose of this article is to introduce and review the capability and performance of the Stata item response theory (IRT) package that is available from Stata v.14, 2015. Using a simulated data set and a publicly available item response data set extracted from Programme of International Student Assessment, we review the IRT package from…

  7. Grounded Theory and Educational Ethnography: A Methodological Analysis and Critique. (United States)

    Smith, Louis M.; Pohland, Paul A.

    This paper analyzes and evaluates the methodological approach developed by B. G. Glaser and A. L. Strauss in THE DISCOVERY OF GROUNDED THEORY (Chicago: Aldine, 1967). Smith and Pohland's major intent is to raise Glaser and Strauss' most significant concepts and issues, analyze them in the context of seven of their own studies, and in conclusion…

  8. Multiple Intelligences Theory and Iranian Textbooks: An Analysis (United States)

    Taase, Yoones


    The purpose of this study is to investigate locally designed ELT textbooks in the light of multiple intelligences theory. Three textbooks (grade 1.2.3) used in guidance school of Iranian educational system were analyzed using MI checklist developed by Botelho, Mario do Rozarioand. Catered for kinds of intelligences in the activities and exercises…

  9. A critical analysis of the quantum theory of measurement

    International Nuclear Information System (INIS)

    Fer, F.


    Keeping strictly in the positivist and probabilistic, hence hilbertian frame of Quantum Mechanics, the author tries to ascertain whether or not Quantum Mechanics, starting from its axioms, reaches the aim of any physical theory, that is, comparison with experiment. The answer is: no, as long as it keeps close to the existing axiomatics, and also to accurate mathematics. (Auth.)

  10. A Grounded Theory Analysis of Introductory Computer Science Pedagogy

    Directory of Open Access Journals (Sweden)

    Jonathan Wellons


    Full Text Available Planning is a critical, early step on the path to successful program writing and a skill that is often lacking in novice programmers. As practitioners we are continually searching for or creating interventions to help our students, particularly those who struggle in the early stages of their computer science education. In this paper we report on our ongoing research of novice programming skills that utilizes the qualitative research method of grounded theory to develop theories and inform the construction of these interventions. We describe how grounded theory, a popular research method in the social sciences since the 1960’s, can lend formality and structure to the common practice of simply asking students what they did and why they did it. Further, we aim to inform the reader not only about our emerging theories on interventions for planning but also how they might collect and analyze their own data in this and other areas that trouble novice programmers. In this way those who lecture and design CS1 interventions can do so from a more informed perspective.

  11. Men's passage to fatherhood: an analysis of the contemporary relevance of transition theory


    Draper, Janet


    This paper presents a theoretical analysis of men's experiences of pregnancy, birth and early fatherhood. It does so using a framework of ritual transition theory and argues that despite its earlier structural-functionalist roots, transition theory remains a valuable framework, illuminating contemporary transitions across the life course. The paper discusses the historical development of transition or ritual theory and, drawing upon data generated during longitudinal ethnographic interviews w...

  12. Measurement of multi-bunch transfer functions using time-domain data and Fourier analysis

    International Nuclear Information System (INIS)

    Hindi, H.; Sapozhnikov, L.; Fox, J.; Prabhakar, S.; Oxoby, G.; Linscott, I.; Drago, A.


    Multi-bunch transfer functions are principal ingredients in understanding both the behavior of high-current storage rings as well as control of their instabilities. The measurement of transfer functions on a bunch-by-bunch basis is particularly important in the design of active feedback systems. Traditional methods of network analysis that work well in the single bunch case become difficult to implement for many bunches. We have developed a method for obtaining empirical estimates of the multi-bunch longitudinal transfer functions from the time-domain measurements of the bunches' phase oscillations. This method involves recording the response of the bunch of interest to a white-noise excitation. The transfer function can then be computed as the ratio of the fast Fourier transforms (FFTs) of the response and excitation sequences, averaged over several excitations. The calculation is performed off-line on bunch-phase data and is well-suited to the multi-bunch case. A description of this method and an analysis of its performance is presented with results obtained using the longitudinal quick prototype feedback system developed at SLAC

  13. Application of the penetration theory for gas - Liquid mass transfer without liquid bulk : Differences with system with a bulk

    NARCIS (Netherlands)

    van Elk, E. P.; Knaap, M. C.; Versteeg, G. F.


    Frequently applied micro models for gas-liquid mass transfer all assume the presence of a liquid bulk. However, some systems are characterized by the absence of a liquid bulk, a very thin layer of liquid flows over a solid surface. An example of such a process is absorption in a column equipped with

  14. Multiple scattering effects with cyclical terms in active remote sensing of vegetated surface using vector radiative transfer theory (United States)

    The energy transport in a vegetated (corn) surface layer is examined by solving the vector radiative transfer equation using a numerical iterative approach. This approach allows a higher order that includes the multiple scattering effects. Multiple scattering effects are important when the optical t...

  15. Sensitivity analysis: Theory and practical application in safety cases

    International Nuclear Information System (INIS)

    Kuhlmann, Sebastian; Plischke, Elmar; Roehlig, Klaus-Juergen; Becker, Dirk-Alexander


    The projects described here aim at deriving an adaptive and stepwise approach to sensitivity analysis (SA). Since the appropriateness of a single SA method strongly depends on the nature of the model under study, a top-down approach (from simple to sophisticated methods) is suggested. If simple methods explain the model behaviour sufficiently well then there is no need for applying more sophisticated ones and the SA procedure can be considered complete. The procedure is developed and tested using a model for a LLW/ILW repository in salt. Additionally, a new model for the disposal of HLW in rock salt will be available soon for SA studies within the MOSEL/NUMSA projects. This model will address special characteristics of waste disposal in undisturbed rock salt, especially the case of total confinement, resulting in a zero release which is indeed the objective of radioactive waste disposal. A high proportion of zero-output realisations causes many SA methods to fail, so special treatment is needed and has to be developed. Furthermore, the HLW disposal model will be used as a first test case for applying the procedure described above, which was and is being derived using the LLW/ILW model. How to treat dependencies in the input, model conservatism and time-dependent outputs will be addressed in the future project programme: - If correlations or, more generally, dependencies between input parameters exist, the question arises about the deeper meaning of sensitivity results in such cases: A strict separation between inputs, internal states and outputs is no longer possible. Such correlations (or dependencies) might have different reasons. In some cases correlated input parameters might have a common physically (well-)known fundamental cause but there are reasons why this fundamental cause cannot or should not be integrated into the model, i.e. the cause might generate a very complex model which cannot be calculated in appropriate time. In other cases the correlation may

  16. Technical conditions for sustainable growth in economic theory. An analysis

    International Nuclear Information System (INIS)

    Granda C, Catalina


    Economic theory and its models point out returns to scale, substitution among productive factors and technological progress as conditions for sustainable growth. This work aims at a critical appraisal of these conditions, particularly the ones related to substitution between natural resources and manmade capital and technical change, by recognizing the inevitable physical scarcity of resources concomitant to the human actions in a world governed by hemodynamic restrictions. To do so, the role that the mentioned conditions play in the theories of economic growth with resources is analyzed, and its limitations and objections from a biophysical perspective are indicated as well. Finally, a brief consideration as to how inappropriate the theoretical representations of economic activities are to take account of growth in spite of resource exhaustion or degradation is carried out

  17. Technology transfer by multinationals


    Kostyantyn Zuzik


    The paper analyses the issue of technology transfer by multinational corporations. The following questions are explored: (a) world market of technologies, the role of MNCs (b) Choice of the technology transfer mode, Dunning's OLI-theory as a factor of the choice of the mode of transfer (c) measurement and profitability of technology transfer (d) transfer of technology through partnerships, JVs, alliances and through M&As (e) aspects of technology transfer by services multinationals. Paper uti...

  18. An Institutional Theory Analysis of Charter Schools: Addressing Institutional Challenges to Scale (United States)

    Huerta, Luis A.; Zuckerman, Andrew


    This article presents a conceptual framework derived from institutional theory in sociology that offers two competing policy contexts in which charter schools operate--a bureaucratic frame versus a decentralized frame. An analysis of evolving charter school types based on three underlying theories of action is considered. As charter school leaders…

  19. Insult in Context: Incorporating Speech Act Theory in Doctrinal Legal Analysis of Interpretative Discussions

    NARCIS (Netherlands)

    H.T.M. Kloosterhuis (Harm)


    textabstractIn this article, I want to show that some doctrinal problems of legal interpretation and argumentation can be analysed in a more precise way than a standard doctrinal analysis, when we use insights from speech act theory and argumentation theory. Taking a discussion about the accusation

  20. Assessing Coverage of Maslow's Theory in Educational Psychology Textbooks: A Content Analysis (United States)

    Wininger, Steven R.; Norman, Antony D.


    Although Maslow's hierarchy of needs theory (HNT) is one of the most prevalent theories in psychology, the authors argued that it is also one of the most misinterpreted or misrepresented, particularly in educational psychology textbooks. Therefore, after carefully reading Maslow's writings on HNT they conducted a content analysis of 18 educational…

  1. Cumulative prospect theory and mean variance analysis. A rigorous comparison


    Hens, Thorsten; Mayer, Janos


    We compare asset allocations derived for cumulative prospect theory(CPT) based on two different methods: Maximizing CPT along the mean–variance efficient frontier and maximizing it without that restriction. We find that with normally distributed returns the difference is negligible. However, using standard asset allocation data of pension funds the difference is considerable. Moreover, with derivatives like call options the restriction to the mean-variance efficient frontier results in a siza...

  2. Kinetic theory analysis of electron attachment cooling in oxygen

    International Nuclear Information System (INIS)

    Skullerud, H.R.


    The attachment cooling effect observed by Hegerberg and Crompton (1983) has been analysed theoretically and numerically in a Boltzmann equation eigenvalue approach. The effect is highly sensitive to the shape and magnitude of the rotational excitation cross sections. When due account is taken of the rotational excitations associated with the (O 2 - ) negative ion resonances, good agreement between theory and experiment can be obtained with reasonable input cross-section data

  3. Analysis of North Korea's Nuclear Tests under Prospect Theory

    International Nuclear Information System (INIS)

    Lee, Han Myung; Ryu, Jae Soo; Lee, Kwang Seok; Lee, Dong Hoon; Jun, Eunju; Kim, Mi Jin


    North Korea has chosen nuclear weapons as the means to protect its sovereignty. Despite international society's endeavors and sanctions to encourage North Korea to abandon its nuclear ambition, North Korea has repeatedly conducted nuclear testing. In this paper, the reason for North Korea's addiction to a nuclear arsenal is addressed within the framework of cognitive psychology. The prospect theory addresses an epistemological approach usually overlooked in rational choice theories. It provides useful implications why North Korea, being under a crisis situation has thrown out a stable choice but taken on a risky one such as nuclear testing. Under the viewpoint of prospect theory, nuclear tests by North Korea can be understood as follows: The first nuclear test in 2006 is seen as a trial to escape from loss areas such as financial sanctions and regime threats; the second test in 2009 was interpreted as a consequence of the strategy to recover losses by making a direct confrontation against the United States; and the third test in 2013 was understood as an attempt to strengthen internal solidarity after Kim Jong-eun inherited the dynasty, as well as to enhance bargaining power against the United States. Thus, it can be summarized that Pyongyang repeated its nuclear tests to escape from a negative domain and to settle into a positive one. In addition, in the future, North Korea may not be willing to readily give up its nuclear capabilities to ensure the survival of its own regime

  4. Transfer function analysis of positron-emitting tracer imaging system (PETIS) data

    International Nuclear Information System (INIS)

    Keutgen, N.; Matsuhashi, S.; Mizuniwa, C.; Ito, T.; Fujimura, T.; Ishioka, N.S.; Watanabe, S.; Sekine, T.; Uchida, H.; Hashimoto, S.


    Quantitative analysis of the two-dimensional image data obtained with the positron-emitting tracer imaging system (PETIS) for plant physiology has been carried out using a transfer function analysis method. While a cut leaf base of Chinese chive (Allium tuberosum Rottler) or a cut stem of soybean (Glycine max L.) was immersed in an aqueous solution containing the [ 18 F] F - ion or [ 13 N]NO 3 - ion, tracer images of the leaf of Chinese chive and the trifoliate of soybean were recorded with PETIS. From the time sequence of images, the tracer transfer function was estimated from which the speed of tracer transport and the fraction moved between specified image positions were deduced

  5. Analysis of bone marrow stromal cell transferred bacterial {beta}-galactosidase gene by PIXE

    Energy Technology Data Exchange (ETDEWEB)

    Kumakawa, Toshiro [Tokyo Metropolitan Geriatric Hospital, Tokyo (Japan). Dept. of Blood Transfusion and Hematology; Hibino, Hitoshi; Tani, Kenzaburo; Asano, Shigetaka; Futatugawa, Shouji; Sera, Kouichiro


    PIXE, Particle Induced X-ray Emission, is a powerful, multi-elemental analysis method which has many distinguishing features and has been used in varies research fields. Recently the method of applying baby cyclotrons for nuclear medicine to PIXE has been developed. This enables us to study biomedical phenomena from the physical point of view. Mouse bone marrow stromal cells were transferred bacterial {beta}-galactosidase gene (LacZ gene) by murine retroviral vectors. Analysis of the bone marrow stromal cells with the LacZ gene by PIXE revealed remarkable changes of intracellular trace elements compared with the normal control cells. These results indicate that gene transfer by retroviral vectors may bring about a dynamic change of intracellular circumstances of the target cell. (author)

  6. An analysis of the inter-project knowledge transfer in the petrochemical industry

    Directory of Open Access Journals (Sweden)

    Marcelo Müller Beuren


    Full Text Available This paper presents a knowledge transfer (KT analysis in an operational project management environment of the petrochemical industry. The main objective of this paper is to identify the major barriers and to suggest improvements activities aiming to foster the KT process. To this end, interviews with members of the project department were conducted by means of a questionnaire. Results were analyzed to identify the most problematic barriers and to propose improvements. The study concluded that the greatest difficulties are related to the transfer of tacit knowledge between different teams. The main contribution of this paper is that it presents an analysis of an unexplored environment and it proposes an improvement of the adapted method for KT study, by using a relationship matrix between the questionnaire and the barriers, so that problems can be identified in an easier manner.

  7. Sludge Treatment Project Engineered Container Retrieval And Transfer System Preliminary Design Hazard Analysis Supplement 1

    International Nuclear Information System (INIS)

    Franz, G.R.; Meichle, R.H.


    This 'What/If' Hazards Analysis addresses hazards affecting the Sludge Treatment Project Engineered Container Retrieval and Transfer System (ECRTS) NPH and external events at the preliminary design stage. In addition, the hazards of the operation sequence steps for the mechanical handling operations in preparation of Sludge Transport and Storage Container (STSC), disconnect STSC and prepare STSC and Sludge Transport System (STS) for shipping are addressed.

  8. Lie group analysis of flow and heat transfer of non-Newtonian ...

    Indian Academy of Sciences (India)


    Jan 9, 2017 ... Moreover, the skin friction coefficient and the rate of heat transfer increase with an increase in Biot number. Keywords. Lie group analysis; boundary layer; nanofluid; non-Newtonian power-law fluid; variable viscosity; convective boundary conditions. PACS Nos 44.20.+b; 65.80.−g; 02.20.−a; 47.50.−d. 1.


    Energy Technology Data Exchange (ETDEWEB)



    This 'What/If' Hazards Analysis addresses hazards affecting the Sludge Treatment Project Engineered Container Retrieval and Transfer System (ECRTS) NPH and external events at the preliminary design stage. In addition, the hazards of the operation sequence steps for the mechanical handling operations in preparation of Sludge Transport and Storage Container (STSC), disconnect STSC and prepare STSC and Sludge Transport System (STS) for shipping are addressed.

  10. Transfer Pricing In Transnational Operations: A Case- And Literature-Based Analysis


    Virginia A. Taylor; E.J. (Roy) Knaus; William E. Matthews


    This paper represents a combined case- and literature-based analysis of transnational pricing and highlights the difference in the issues and perspectives of the business and academic environments. Following an introduction to the issue (noting the growing importance of the transfer of goods from one organizational entity to another within a multinational firm), a short case - The Henderson Company - illustrates how a relatively simple announcement can lead to a lengthy and heated discussion ...

  11. Ultra high vacuum fracture and transfer device for AES analysis of irradiated austenitic stainless steel

    International Nuclear Information System (INIS)

    Urie, M.W.; Panayotou, N.F.; Robinson, J.E.


    An ultrahigh vacuum fracture and transfer device for analysis of irradiated and non-irradiated SS 316 fuel cladding is described. Mechanical property tests used to study the behavior of cladding during reactor transient over-power conditions are reported. The stress vs temperature curves show minimal differences between unirradiated cladding and unfueled cladding. The fueled cladding fails at a lower temperature. All fueled specimens failed in an intergranular mode

  12. Analysis of Atmospheric Aerosol Data Sets and Application of Radiative Transfer Models to Compute Aerosol Effects (United States)

    Schmid, Beat; Bergstrom, Robert W.; Redemann, Jens


    This report is the final report for "Analysis of Atmospheric Aerosol Data Sets and Application of Radiative Transfer Models to Compute Aerosol Effects". It is a bibliographic compilation of 29 peer-reviewed publications (published, in press or submitted) produced under this Cooperative Agreement and 30 first-authored conference presentations. The tasks outlined in the various proposals are listed below with a brief comment as to the research performed. Copies of title/abstract pages of peer-reviewed publications are attached.

  13. Analysis of risk management during AP1000 equipment technology transfer and localization

    International Nuclear Information System (INIS)

    Gao Yongjun; Guan Rui


    This article analyzes the risk factors existing in AP1000 equipment technology transfer and localization process by describing the invitation for bid, tender evaluation and contract negotiation process of the third-generation nuclear power plant technology introduction project of China and discusses the classification, evaluation and analysis methods of risks, and puts forward some referential suggestions for the successful introduction of equipment technology for AP1000 nuclear project. (authors)

  14. PORFLO - a continuum model for fluid flow, heat transfer, and mass transport in porous media. Model theory, numerical methods, and computational tests

    International Nuclear Information System (INIS)

    Runchal, A.K.; Sagar, B.; Baca, R.G.; Kline, N.W.


    Postclosure performance assessment of the proposed high-level nuclear waste repository in flood basalts at Hanford requires that the processes of fluid flow, heat transfer, and mass transport be numerically modeled at appropriate space and time scales. A suite of computer models has been developed to meet this objective. The theory of one of these models, named PORFLO, is described in this report. Also presented are a discussion of the numerical techniques in the PORFLO computer code and a few computational test cases. Three two-dimensional equations, one each for fluid flow, heat transfer, and mass transport, are numerically solved in PORFLO. The governing equations are derived from the principle of conservation of mass, momentum, and energy in a stationary control volume that is assumed to contain a heterogeneous, anisotropic porous medium. Broad discrete features can be accommodated by specifying zones with distinct properties, or these can be included by defining an equivalent porous medium. The governing equations are parabolic differential equations that are coupled through time-varying parameters. Computational tests of the model are done by comparisons of simulation results with analytic solutions, with results from other independently developed numerical models, and with available laboratory and/or field data. In this report, in addition to the theory of the model, results from three test cases are discussed. A users' manual for the computer code resulting from this model has been prepared and is available as a separate document. 37 refs., 20 figs., 15 tabs

  15. A Comparative Analysis of Three Major Transfer Airports in Northeast Asia Focusing on Incheon International Airport Using a Conjoint Analysis

    Directory of Open Access Journals (Sweden)

    Tae Won Chung


    Full Text Available Due mainly to the privatization and commercialization of airline companies and deregulation of the aviation rules, the demand for air transport has continuously been increasing. Airport authorities state that transfer passengers, who contribute to the large portion of the airports’ profits, are gaining much more importance, particularly in the Northeast Asia region where the air transport industry is very vital. Therefore, this study aims to investigate the competitiveness of IIA (Incheon International Airport with other major airports located in Northeast Asia in passenger transfers made between Southeast Asia and China to North America using Conjoint Analysis. Results have indicated that airport brand is the most important attribute for the competitiveness of airport, followed by cost, connectivity and duty free shops. In further analysis focusing on brand value of the three airports measured by the use of transfer passengers, it was revealed that IIA needs more effort in developing their brand identity to become the leading transfer hub airport. Based on the results, recommendations for increasing the brand value have also been suggested.

  16. A Foundational Analysis of Dorothea Orem's Self-Care Theory and Evaluation of Its Significance for Nursing Practice and Research. (United States)

    Younas, Ahtisham


    In-depth understanding of the ontological and epistemological assumptions of nursing theories can be achieved through theory analysis. Several theory analysis criteria have been proposed for examining ontological and epistemological assumptions, but there are limited examples of actual analysis of these assumptions. This article presents an analysis of the ontological and epistemological assumptions of Dorothea Orem's selfcare theory and evaluates its significance for nursing practice and research.

  17. The dynamics of information-driven coordination phenomena: A transfer entropy analysis. (United States)

    Borge-Holthoefer, Javier; Perra, Nicola; Gonçalves, Bruno; González-Bailón, Sandra; Arenas, Alex; Moreno, Yamir; Vespignani, Alessandro


    Data from social media provide unprecedented opportunities to investigate the processes that govern the dynamics of collective social phenomena. We consider an information theoretical approach to define and measure the temporal and structural signatures typical of collective social events as they arise and gain prominence. We use the symbolic transfer entropy analysis of microblogging time series to extract directed networks of influence among geolocalized subunits in social systems. This methodology captures the emergence of system-level dynamics close to the onset of socially relevant collective phenomena. The framework is validated against a detailed empirical analysis of five case studies. In particular, we identify a change in the characteristic time scale of the information transfer that flags the onset of information-driven collective phenomena. Furthermore, our approach identifies an order-disorder transition in the directed network of influence between social subunits. In the absence of clear exogenous driving, social collective phenomena can be represented as endogenously driven structural transitions of the information transfer network. This study provides results that can help define models and predictive algorithms for the analysis of societal events based on open source data.

  18. Non-invasive baroreflex sensitivity assessment using wavelet transfer function-based time–frequency analysis

    International Nuclear Information System (INIS)

    Keissar, K; Gilad, O; Maestri, R; Pinna, G D; La Rovere, M T


    A novel approach for the estimation of baroreflex sensitivity (BRS) is introduced based on time–frequency analysis of the transfer function (TF). The TF method (TF-BRS) is a well-established non-invasive technique which assumes stationarity. This condition is difficult to meet, especially in cardiac patients. In this study, the classical TF was replaced with a wavelet transfer function (WTF) and the classical coherence was replaced with wavelet transform coherence (WTC), adding the time domain as an additional degree of freedom with dynamic error estimation. Error analysis and comparison between WTF-BRS and TF-BRS were performed using simulated signals with known transfer function and added noise. Similar comparisons were performed for ECG and blood pressure signals, in the supine position, of 19 normal subjects, 44 patients with a history of previous myocardial infarction (MI) and 45 patients with chronic heart failure. This yielded an excellent linear association (R > 0.94, p < 0.001) for time-averaged WTF-BRS, validating the new method as consistent with a known method. The additional advantage of dynamic analysis of coherence and TF estimates was illustrated in two physiological examples of supine rest and change of posture showing the evolution of BRS synchronized with its error estimations and sympathovagal balance

  19. The Theory and Practice of the Six-Step Method in EFL and Its Transferability to Engineering Programmes (United States)

    Ntombela, Berrington X. S.


    This paper outlines the theory of the six-step method developed by personnel in the Language and Learning department at Caledonian College of Engineering, Oman. The paper further illustrates the application of this method in teaching Project, Listening, Reading, Writing, and Speaking & Debate at Foundation level. The assumption in applying the…

  20. Young Children's Near and Far Transfer of the Basic Theory of Natural Selection: An Analogical Storybook Intervention (United States)

    Emmons, Natalie; Lees, Kristin; Kelemen, Deborah


    Misconceptions about adaptation by natural selection are widespread among adults and likely stem, in part, from cognitive biases and intuitive theories observable in early childhood. Current educational guidelines that recommend delaying comprehensive instruction on the topic of adaptation until adolescence, therefore, raise concerns because…