Advanced Hydrogen Turbine Development

Energy Technology Data Exchange (ETDEWEB)

Joesph Fadok

2008-01-01

advanced hydrogen turbine that meets the aggressive targets set forth for the advanced hydrogen turbine, including increased rotor inlet temperature (RIT), lower total cooling and leakage air (TCLA) flow, higher pressure ratio, and higher mass flow through the turbine compared to the baseline. Maintaining efficiency with high mass flow Syngas combustion is achieved using a large high AN2 blade 4, which has been identified as a significant advancement beyond the current state-of-the-art. Preliminary results showed feasibility of a rotor system capable of increased power output and operating conditions above the baseline. In addition, several concepts were developed for casing components to address higher operating conditions. Rare earth modified bond coat for the purpose of reducing oxidation and TBC spallation demonstrated an increase in TBC spallation life of almost 40%. The results from Phase 1 identified two TBC compositions which satisfy the thermal conductivity requirements and have demonstrated phase stability up to temperatures of 1850 C. The potential to join alloys using a bonding process has been demonstrated and initial HVOF spray deposition trials were promising. The qualitative ranking of alloys and coatings in environmental conditions was also performed using isothermal tests where significant variations in alloy degradation were observed as a function of gas composition. Initial basic system configuration schematics and working system descriptions have been produced to define key boundary data and support estimation of costs. Review of existing materials in use for hydrogen transportation show benefits or tradeoffs for materials that could be used in this type of applications. Hydrogen safety will become a larger risk than when using natural gas fuel as the work done to date in other areas has shown direct implications for this type of use. Studies were conducted which showed reduced CO{sub 2} and NOx emissions with increased plant efficiency. An approach to

Film Presentation: Projekt Zukunft/Tomorrow Today

CERN Multimedia

Carolyn Lee

2010-01-01

Projekt Zukunft/Tomorrow Today, by Deutsche Welle (2009)   Deutsche Welle TV’s weekly science journal explores the LHC at CERN with host Ingolf Baur. Please note that we will show both the German and English versions of this broadcast. Each episode is about 27 minutes long. Projekt Zukunft/Tomorrow Today will be presented on Friday, 29 October from 13:00 to 14:00 in the Main Auditorium Language: German version followed by the English version      

Metal hydride hydrogen compression: recent advances and future prospects

Science.gov (United States)

Yartys, Volodymyr A.; Lototskyy, Mykhaylo; Linkov, Vladimir; Grant, David; Stuart, Alastair; Eriksen, Jon; Denys, Roman; Bowman, Robert C.

2016-04-01

Metal hydride (MH) thermal sorption compression is one of the more important applications of the MHs. The present paper reviews recent advances in the field based on the analysis of the fundamental principles of this technology. The performances when boosting hydrogen pressure, along with two- and three-step compression units, are analyzed. The paper includes also a theoretical modelling of a two-stage compressor aimed at describing the performance of the experimentally studied systems, their optimization and design of more advanced MH compressors. Business developments in the field are reviewed for the Norwegian company HYSTORSYS AS and the South African Institute for Advanced Materials Chemistry. Finally, future prospects are outlined presenting the role of the MH compression in the overall development of the hydrogen-driven energy systems. The work is based on the analysis of the development of the technology in Europe, USA and South Africa.

Hydrogen production from water: Recent advances in photosynthesis research

Energy Technology Data Exchange (ETDEWEB)

Greenbaum, E.; Lee, J.W. [Oak Ridge National Lab., TN (United States). Chemical Technology Div.

1997-12-31

The great potential of hydrogen production by microalgal water splitting is predicated on quantitative measurement of the algae`s hydrogen-producing capability, which is based on the following: (1) the photosynthetic unit size of hydrogen production; (2) the turnover time of photosynthetic hydrogen production; (3) thermodynamic efficiencies of conversion of light energy into the Gibbs free energy of molecular hydrogen; (4) photosynthetic hydrogen production from sea water using marine algae; (5) the potential for research advances using modern methods of molecular biology and genetic engineering to maximize hydrogen production. ORNL has shown that sustained simultaneous photoevolution of molecular hydrogen and oxygen can be performed with mutants of the green alga Chlamydomonas reinhardtii that lack a detectable level of the Photosystem I light reaction. This result is surprising in view of the standard two-light reaction model of photosynthesis and has interesting scientific and technological implications. This ORNL discovery also has potentially important implications for maximum thermodynamic conversion efficiency of light energy into chemical energy by green plant photosynthesis. Hydrogen production performed by a single light reaction, as opposed to two, implies a doubling of the theoretically maximum thermodynamic conversion efficiency from {approx}10% to {approx}20%.

Efficiency and cost advantages of an advanced-technology nuclear electrolytic hydrogen-energy production facility

Science.gov (United States)

Donakowski, T. D.; Escher, W. J. D.; Gregory, D. P.

1977-01-01

The concept of an advanced-technology (viz., 1985 technology) nuclear-electrolytic water electrolysis facility was assessed for hydrogen production cost and efficiency expectations. The facility integrates (1) a high-temperature gas-cooled nuclear reactor (HTGR) operating a binary work cycle, (2) direct-current (d-c) electricity generation via acyclic generators, and (3) high-current-density, high-pressure electrolyzers using a solid polymer electrolyte (SPE). All subsystems are close-coupled and optimally interfaced for hydrogen production alone (i.e., without separate production of electrical power). Pipeline-pressure hydrogen and oxygen are produced at 6900 kPa (1000 psi). We found that this advanced facility would produce hydrogen at costs that were approximately half those associated with contemporary-technology nuclear electrolysis: $5.36 versus $10.86/million Btu, respectively. The nuclear-heat-to-hydrogen-energy conversion efficiency for the advanced system was estimated as 43%, versus 25% for the contemporary system.

Which research for tomorrow's energy? 2012 Energy Colloquium 2. release

International Nuclear Information System (INIS)

Antonini, Gerard; Arrif, Teddy; Bain, Pascal; Beguin, Francois; Bruneaux, Gilles; Cetin, Derya; Czernichowski, Isabelle; Escudie, Dany; Folacci, Marie-Ange; Gosse, Kevin; Hareux, Sylvie; Metaye, Romain; Morel, Herve; Odru, Pierre; Oukacine, Linda; Pons, Liz; Tournier, Aline; Corgier, David; Thollin, Jacques; Barret, Mickael; Mosdale, Renaut; Hervouet, Veronique; Pourcelly, Gerald; Brousse, Thierry; Lincot, Daniel; Schmidt-Laine, Claudine; Artero, Vincent; Robinson, Darren; Bigot, Bernard; Salha, Bernard; Minster, Jean-Francois; Hauet, Bertrand

2012-01-01

This huge publication gathers interventions and contributions of a colloquium which notably addressed the following issues: bio-energies, hydrogen and fuel cells, energy storage, photovoltaic solar energy, energy efficiency in buildings, transports and industry, CO 2 capture and storage. On the first day, after two interventions on Energies Programmes at the ANR and an overview of R and D world challenges regarding energy, the contributions addressed the above mentioned issues. During the next day, besides these issues, contributions addressed challenges for tomorrow's society and perspectives for research. Thematic sessions addressed bio-energies (optimized production of cellulose ethanol, the third generation, technological deadlocks for the thermal-chemical route), photovoltaic solar energy (new concepts, massive crystalline silicon and photovoltaic thin layers), high energy efficiency buildings, energetic equipment and climate engineering, CO 2 storage, CO 2 capture, fuel cells, hydrogen production, transport and storage, electrochemical and non-electrochemical storage of energy, transports (internal combustion engine and power units, electric transports)

Bringing Tomorrow's Technology to You Today: School Board of Tomorrow Resource Guide.

Science.gov (United States)

National School Boards Association, Alexandria, VA.

The National School Boards Association (NSBA), the National School Boards Foundation, NSBA's Institute for the Transfer of Technology to Education, and Apple Computer, Inc., launched "The School Board of Tomorrow Exhibit" at NSBA's 1996 annual conference and exposition in Orlando, Florida. This handbook summarizes the communication technologies…

Storage of hydrogen in advanced high pressure container. Appendices

International Nuclear Information System (INIS)

Bentzen, J.J.; Lystrup, A.

2005-07-01

The objective of the project has been to study barriers for a production of advanced high pressure containers especially suitable for hydrogen, in order to create a basis for a container production in Denmark. The project has primarily focused on future Danish need for hydrogen storage in the MWh area. One task has been to examine requirement specifications for pressure tanks that can be expected in connection with these stores. Six potential storage needs have been identified: (1) Buffer in connection with start-up/regulation on the power grid. (2) Hydrogen and oxygen production. (3) Buffer store in connection with VEnzin vision. (4) Storage tanks on hydrogen filling stations. (5) Hydrogen for the transport sector from 1 TWh surplus power. (6) Tanker transport of hydrogen. Requirements for pressure containers for the above mentioned use have been examined. The connection between stored energy amount, pressure and volume compared to liquid hydrogen and oil has been stated in tables. As starting point for production technological considerations and economic calculations of various container concepts, an estimation of laminate thickness in glass-fibre reinforced containers with different diameters and design print has been made, for a 'pure' fibre composite container and a metal/fibre composite container respectively. (BA)

Hydrogen retention behavior of beryllides as advanced neutron multipliers

Directory of Open Access Journals (Sweden)

Y. Fujii

2016-12-01

Full Text Available Beryllium intermetallic compounds (beryllides are the most promising candidate materials for use as advanced neutron multipliers in future fusion reactors because of their low swelling and high stability at high temperatures. Recently, beryllium–titanium beryllide pebbles such as Be12Ti have been successfully fabricated using a novel granulation process. In this study, the fundamental aspects of the behavior of hydrogen isotopes in Be12Ti pebbles were investigated via thermal desorption spectroscopy and transmission electron microscopy. In addition, atomistic calculations using first principles electronic-structure methods were applied to determine the solution energy of hydrogen in Be12Ti. The results showed simpler and weaker hydrogen-trapping efficiency for Be12Ti than for pure Be.

Validation test of advanced technology for IPV nickel-hydrogen flight cells: Update

Science.gov (United States)

Smithrick, John J.; Hall, Stephen W.

1992-01-01

Individual pressure vessel (IPV) nickel-hydrogen technology was advanced at NASA Lewis and under Lewis contracts with the intention of improving cycle life and performance. One advancement was to use 26 percent potassium hydroxide (KOH) electrolyte to improve cycle life. Another advancement was to modify the state-of-the-art cell design to eliminate identified failure modes. The modified design is referred to as the advanced design. A breakthrough in the low-earth-orbit (LEO) cycle life of IPV nickel-hydrogen cells has been previously reported. The cycle life of boiler plate cells containing 26 percent KOH electrolyte was about 40,000 LEO cycles compared to 3,500 cycles for cells containing 31 percent KOH. The boiler plate test results are in the process of being validated using flight hardware and real time LEO testing at the Naval Weapons Support Center (NWSC), Crane, Indiana under a NASA Lewis Contract. An advanced 125 Ah IPV nickel-hydrogen cell was designed. The primary function of the advanced cell is to store and deliver energy for long-term, LEO spacecraft missions. The new features of this design are: (1) use of 26 percent rather than 31 percent KOH electrolyte; (2) use of a patented catalyzed wall wick; (3) use of serrated-edge separators to facilitate gaseous oxygen and hydrogen flow within the cell, while still maintaining physical contact with the wall wick for electrolyte management; and (4) use of a floating rather than a fixed stack (state-of-the-art) to accommodate nickel electrode expansion due to charge/discharge cycling. The significant improvements resulting from these innovations are: extended cycle life; enhanced thermal, electrolyte, and oxygen management; and accommodation of nickel electrode expansion. The advanced cell design is in the process of being validated using real time LEO cycle life testing of NWSC, Crane, Indiana. An update of validation test results confirming this technology is presented.

Transition to a hydrogen fuel cell transit bus fleet for Canadian urban transit system

International Nuclear Information System (INIS)

Ducharme, P.

2004-01-01

'Full text:' The Canadian Transportation Fuel Cell Alliance (CTFCA), created by the Canadian Government as part of its 2000 Climate Change Action Plan, has commissioned MARCON-DDM's Hydrogen Intervention Team (HIT) to provide a roadmap for urban transit systems that wish to move to hydrogen fuel cell-powered bus fleets. HIT is currently in the process of gathering information from hydrogen technology providers, bus manufacturers, fuelling system providers and urban transit systems in Canada, the US and Europe. In September, HIT will be in a position to provide a preview of its report to the CTFCA, due for October 2004. The planned table of contents includes: TOMORROW'S FUEL CELL (FC) URBAN TRANSIT BUS - Powertrain, on-board fuel technologies - FC engine system manufacturers - Bus technical specifications, performances, operating characteristics - FC bus manufacturers TOMORROW'S FC TRANSIT PROPERTY - Added maintenance, facilities and fuelling infrastructure requirements - Supply chain implications - Environmental and safety issues - Alternative operational concepts PATHWAYS TO THE FUTURE - Choosing the future operational concept - 'Gap' assessment - how long from here to there? - Facilities and fleet adjustments, including fuelling infrastructure - Risk mitigation, code compliance measures TRANSITIONAL CONSIDERATIONS - Cost implications - Transition schedule (author)

Advanced IGCC/Hydrogen Gas Turbine Development

Energy Technology Data Exchange (ETDEWEB)

York, William [General Electric Company, Schenectady, NY (United States); Hughes, Michael [General Electric Company, Schenectady, NY (United States); Berry, Jonathan [General Electric Company, Schenectady, NY (United States); Russell, Tamara [General Electric Company, Schenectady, NY (United States); Lau, Y. C. [General Electric Company, Schenectady, NY (United States); Liu, Shan [General Electric Company, Schenectady, NY (United States); Arnett, Michael [General Electric Company, Schenectady, NY (United States); Peck, Arthur [General Electric Company, Schenectady, NY (United States); Tralshawala, Nilesh [General Electric Company, Schenectady, NY (United States); Weber, Joseph [General Electric Company, Schenectady, NY (United States); Benjamin, Marc [General Electric Company, Schenectady, NY (United States); Iduate, Michelle [General Electric Company, Schenectady, NY (United States); Kittleson, Jacob [General Electric Company, Schenectady, NY (United States); Garcia-Crespo, Andres [General Electric Company, Schenectady, NY (United States); Delvaux, John [General Electric Company, Schenectady, NY (United States); Casanova, Fernando [General Electric Company, Schenectady, NY (United States); Lacy, Ben [General Electric Company, Schenectady, NY (United States); Brzek, Brian [General Electric Company, Schenectady, NY (United States); Wolfe, Chris [General Electric Company, Schenectady, NY (United States); Palafox, Pepe [General Electric Company, Schenectady, NY (United States); Ding, Ben [General Electric Company, Schenectady, NY (United States); Badding, Bruce [General Electric Company, Schenectady, NY (United States); McDuffie, Dwayne [General Electric Company, Schenectady, NY (United States); Zemsky, Christine [General Electric Company, Schenectady, NY (United States)

2015-07-30

The objective of this program was to develop the technologies required for a fuel flexible (coal derived hydrogen or syngas) gas turbine for IGCC that met DOE turbine performance goals. The overall DOE Advanced Power System goal was to conduct the research and development (R&D) necessary to produce coal-based IGCC power systems with high efficiency, near-zero emissions, and competitive capital cost. To meet this goal, the DOE Fossil Energy Turbine Program had as an interim objective of 2 to 3 percentage points improvement in combined cycle (CC) efficiency. The final goal is 3 to 5 percentage points improvement in CC efficiency above the state of the art for CC turbines in IGCC applications at the time the program started. The efficiency goals were for NOx emissions of less than 2 ppm NOx (@15 % O2). As a result of the technologies developed under this program, the DOE goals were exceeded with a projected 8 point efficiency improvement. In addition, a new combustion technology was conceived of and developed to overcome the challenges of burning hydrogen and achieving the DOE’s NOx goal. This report also covers the developments under the ARRA-funded portion of the program that include gas turbine technology advancements for improvement in the efficiency, emissions, and cost performance of gas turbines for industrial applications with carbon capture and sequestration. Example applications could be cement plants, chemical plants, refineries, steel and aluminum plants, manufacturing facilities, etc. The DOE’s goal for more than 5 percentage point improvement in efficiency was met with cycle analyses performed for representative IGCC Steel Mill and IGCC Refinery applications. Technologies were developed in this program under the following areas: combustion, larger latter stage buckets, CMC and EBC, advanced materials and coatings, advanced configurations to reduce cooling, sealing and rotor purge flows, turbine aerodynamics, advanced sensors, advancements in first

House of tomorrow today

NARCIS (Netherlands)

Lichtenberg, J.J.N.; Ham, M.; Hensen, J.L.M.

2011-01-01

The House of Tomorrow Today is a project focussing on a healthy, energy producing dwelling to be realized with today¿s proven technology. The project aims at an energy plus level based on the principles as formulated in SmartBuilding (Slimbouwen) [1] ActiveHouse [2] and HoTT [3] It can be seen as

Validation test of advanced technology for IPV nickel-hydrogen flight cells - Update

Science.gov (United States)

Smithrick, John J.; Hall, Stephen W.

1992-01-01

Individual pressure vessel (IPV) nickel-hydrogen technology was advanced at NASA Lewis and under Lewis contracts with the intention of improving cycle life and performance. One advancement was to use 26 percent potassium hydroxide (KOH) electrolyte to improve cycle life. Another advancement was to modify the state-of-the-art cell design to eliminate identified failure modes. The modified design is referred to as the advanced design. A breakthrough in the LEO cycle life of IPV nickel-hydrogen cells has been previously reported. The cycle life of boiler plate cells containing 26 percent KOH electrolyte was about 40,000 LEO cycles compared to 3,500 cycles for cells containing 31 percent KOH. The boiler plate test results are in the process of being validated using flight hardware and real time LEO testing. The primary function of the advanced cell is to store and deliver energy for long-term, LEO spacecraft missions. The new features of this design are: (1) use of 26 percent rather than 31 percent KOH electrolyte; (2) use of a patented catalyzed wall wick; (3) use of serrated-edge separators to facilitate gaseous oxygen and hydrogen flow within the cell, while still maintaining physical contact with the wall wick for electrolyte management; and (4) use of a floating rather than a fixed stack (state-of-the-art) to accommodate nickel electrode expansion due to charge/discharge cycling. The significant improvements resulting from these innovations are: extended cycle life; enhanced thermal, electrolyte, and oxygen management; and accommodation of nickel electrode expansion.

Advanced materials for solid state hydrogen storage: “Thermal engineering issues”

International Nuclear Information System (INIS)

Srinivasa Murthy, S.; Anil Kumar, E.

2014-01-01

Hydrogen has been widely recognized as the “Energy Carrier” of the future. Efficient, reliable, economical and safe storage and delivery of hydrogen form important aspects in achieving success of the “Hydrogen Economy”. Gravimetric and volumetric storage capacities become important when one considers portable and mobile applications of hydrogen. In the case of solid state hydrogen storage, the gas is reversibly embedded (by physisorption and/or chemisorption) in a solid matrix. A wide variety of materials such as intermetallics, physisorbents, complex hydrides/alanates, metal organic frameworks, etc. have been investigated as possible storage media. This paper discusses the feasibility of lithium– and sodium–aluminum hydrides with emphasis on their thermodynamic and thermo-physical properties. Drawbacks such as poor heat transfer characteristics and poor kinetics demand special attention to the thermal design of solid state storage devices. - Highlights: • Advanced materials suitable for solid state hydrogen storage are discussed. • Issues related to thermodynamic and thermo-physical properties of hydriding materials are brought out. • Hydriding and dehydriding behavior including sorption kinetics of complex hydrides with emphasis on alanates are explained

Advances and bottlenecks in microbial hydrogen production.

Science.gov (United States)

Stephen, Alan J; Archer, Sophie A; Orozco, Rafael L; Macaskie, Lynne E

2017-09-01

Biological production of hydrogen is poised to become a significant player in the future energy mix. This review highlights recent advances and bottlenecks in various approaches to biohydrogen processes, often in concert with management of organic wastes or waste CO 2 . Some key bottlenecks are highlighted in terms of the overall energy balance of the process and highlighting the need for economic and environmental life cycle analyses with regard also to socio-economic and geographical issues. © 2017 The Authors. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

Advanced chemical hydride-based hydrogen generation/storage system for fuel cell vehicles

Energy Technology Data Exchange (ETDEWEB)

Breault, R.W.; Rolfe, J. [Thermo Power Corp., Waltham, MA (United States)

1998-08-01

Because of the inherent advantages of high efficiency, environmental acceptability, and high modularity, fuel cells are potentially attractive power supplies. Worldwide concerns over clean environments have revitalized research efforts on developing fuel cell vehicles (FCV). As a result of intensive research efforts, most of the subsystem technology for FCV`s are currently well established. These include: high power density PEM fuel cells, control systems, thermal management technology, and secondary power sources for hybrid operation. For mobile applications, however, supply of hydrogen or fuel for fuel cell operation poses a significant logistic problem. To supply high purity hydrogen for FCV operation, Thermo Power`s Advanced Technology Group is developing an advanced hydrogen storage technology. In this approach, a metal hydride/organic slurry is used as the hydrogen carrier and storage media. At the point of use, high purity hydrogen will be produced by reacting the metal hydride/organic slurry with water. In addition, Thermo Power has conceived the paths for recovery and regeneration of the spent hydride (practically metal hydroxide). The fluid-like nature of the spent hydride/organic slurry will provide a unique opportunity for pumping, transporting, and storing these materials. The final product of the program will be a user-friendly and relatively high energy storage density hydrogen supply system for fuel cell operation. In addition, the spent hydride can relatively easily be collected at the pumping station and regenerated utilizing renewable sources, such as biomass, natural, or coal, at the central processing plants. Therefore, the entire process will be economically favorable and environmentally friendly.

Integrated Refrigeration and Storage for Advanced Liquid Hydrogen Operations

Science.gov (United States)

Swanger, A. M.; Notardonato, W. U.; Johnson, W. L.; Tomsik, T. M.

2016-01-01

NASA has used liquefied hydrogen (LH2) on a large scale since the beginning of the space program as fuel for the Centaur and Apollo upper stages, and more recently to feed the three space shuttle main engines. The LH2 systems currently in place at the Kennedy Space Center (KSC) launch pads are aging and inefficient compared to the state-of-the-art. Therefore, the need exists to explore advanced technologies and operations that can drive commodity costs down, and provide increased capabilities. The Ground Operations Demonstration Unit for Liquid Hydrogen (GODU-LH2) was developed at KSC to pursue these goals by demonstrating active thermal control of the propellant state by direct removal of heat using a cryocooler. The project has multiple objectives including zero loss storage and transfer, liquefaction of gaseous hydrogen, and densification of liquid hydrogen. The key technology challenge was efficiently integrating the cryogenic refrigerator into the LH2 storage tank. A Linde LR1620 Brayton cycle refrigerator is used to produce up to 900W cooling at 20K, circulating approximately 22 g/s gaseous helium through the hydrogen via approximately 300 m of heat exchanger tubing. The GODU-LH2 system is fully operational, and is currently under test. This paper will discuss the design features of the refrigerator and storage system, as well as the current test results.

Let us fish4tomorrow

OpenAIRE

J.D., Farrugia

2015-01-01

All over the world, governments and stakeholders are trying to cope with overfishing. Overfishing is when too much fish is caught which leads to an overall degradation of the marine ecosystem. It is the non-sustainable use of ocean resources. http://www.um.edu.mt/think/let-us-fish4tomorrow/

The AFIT of Today is the Air Force of Tomorrow

Science.gov (United States)

2012-05-11

marketing 5/11/2012 9 The AFIT of today is the Air Force of tomorrow. 1 Air University: The Intellectual and Leadership Center of the Air Force Aim High...Center of the Air Force Aim High…Fly - Fight - Win The AFIT of Today is the Air Force of Tomorrow. LS Accomplishments • Initiated market -based, fee-for...USAFA Swarming Formation Flying Sponsor: SMC Space Traffic Control Iridium and Globalstar Modems Sponsor: AFRL/RV; SMC/ STP CubeSat Plume Detector

Preparing tomorrow's transportation workforce : a Midwest summit.

Science.gov (United States)

2010-08-01

Preparing Tomorrows Transportation Workforce: A Midwest Summit, held April 2728, 2010, in Ames, Iowa, was one of several : regional transportation workforce development summits held across the United States in 2009 and 2010 as part of a coordin...

Evolving Technologies: A View to Tomorrow

Science.gov (United States)

Tamarkin, Molly; Rodrigo, Shelley

2011-01-01

Technology leaders must participate in strategy creation as well as operational delivery within higher education institutions. The future of higher education--the view to tomorrow--is irrevocably integrated and intertwined with evolving technologies. This article focuses on two specific evolving technologies: (1) alternative IT sourcing; and (2)…

Which climate for tomorrow?

International Nuclear Information System (INIS)

Huet, S.

2000-01-01

This book explains in a clear way todays scientific knowledge about climate change and presents the method used by scientists to study climate and its evolution. It stresses on the urgency for an efficient international policy in order to fight against the striking increase of the Earth's greenhouse effect. However, it remains unbiased about the numerous uncertainties that exist in the possible scenarios proposed for tomorrows climate, despite the important progresses made in climatology these last years. (J.S.)

Advanced hydrogen electrode for hydrogen-bromide battery

Science.gov (United States)

Kosek, Jack A.; Laconti, Anthony B.

1987-01-01

Binary platinum alloys are being developed as hydrogen electrocatalysts for use in a hydrogen bromide battery system. These alloys were varied in terms of alloy component mole ratio and heat treatment temperature. Electrocatalyst evaluation, performed in the absence and presence of bromide ion, includes floating half cell polarization studies, electrochemical surface area measurements, X ray diffraction analysis, scanning electron microscopy analysis and corrosion measurements. Results obtained to date indicate a platinum rich alloy has the best tolerance to bromide ion poisoning.

The Genetic Code: Yesterday, Today and Tomorrow

Indian Academy of Sciences (India)

Home; Journals; Resonance – Journal of Science Education; Volume 17; Issue 12. The Genetic Code: Yesterday, Today and Tomorrow. Jiqiang Ling Dieter Söll. General Article Volume 17 Issue 12 December 2012 pp 1136-1142. Fulltext. Click here to view fulltext PDF. Permanent link:

Recent Advances in the Use of Sodium Borohydride as a Solid State Hydrogen Store

Directory of Open Access Journals (Sweden)

Jianfeng Mao

2015-01-01

Full Text Available The development of new practical hydrogen storage materials with high volumetric and gravimetric hydrogen densities is necessary to implement fuel cell technology for both mobile and stationary applications. NaBH4, owing to its low cost and high hydrogen density (10.6 wt%, has received extensive attention as a promising hydrogen storage medium. However, its practical use is hampered by its high thermodynamic stability and slow hydrogen exchange kinetics. Recent developments have been made in promoting H2 release and tuning the thermodynamics of the thermal decomposition of solid NaBH4. These conceptual advances offer a positive outlook for using NaBH4-based materials as viable hydrogen storage carriers for mobile applications. This review summarizes contemporary progress in this field with a focus on the fundamental dehydrogenation and rehydrogenation pathways and properties and on material design strategies towards improved kinetics and thermodynamics such as catalytic doping, nano-engineering, additive destabilization and chemical modification.

Can anything better come along? Reflections on the deep future of hydrogen-electricity systems

International Nuclear Information System (INIS)

Scott, D. S.

2006-01-01

Sometimes, for some things, we can project the deep future better than tomorrow. This is particularly relevant to our energy system where, if we focus on energy currencies, looking further out allows us to leap the tangles of today's conventional wisdom, vested mantras and ill-found hopes. We will first recall the rationale that sets out why - by the time the 22. century rolls around - hydrogen and electricity will have become civilizations staple energy currencies. Building on this dual-currency inevitability we'll then evoke the wisdom that, while we never know everything about the future we always know something. For future energy systems that 'something' is the role and nature of the energy currencies. From this understanding, our appreciation of the deep future can take shape - at least for infrastructures, energy sources and some imbedded technologies - but not service-delivery widgets. The long view provides more than mere entertainment. It should form the basis of strategies for today that, in turn, will avoid setbacks and blind alleys on our journey to tomorrow. Some people accept that hydrogen and electricity will be our future, but only 'until something better comes along.' The talk will conclude with logic that explains the response: 'No! Nothing better will ever come along.'. (authors)

Can anything better come along? Reflections on the deep future of hydrogen-electricity systems

International Nuclear Information System (INIS)

Scott, D.S.

2004-01-01

'Full text:' Sometimes, for some things, we can project the deep future better than tomorrow. This is particularly relevant to our energy system where, if we focus on energy currencies, looking further out allows us to leap the tangles of today's conventional wisdom, vested mantras and ill-found hopes. We will first recall the rationale that sets out why - by the time the 22nd century rolls around - hydrogen and electricity will have become civilization's staple energy currencies. Building on this dual-currencies inevitability we'll then evoke the wisdom that, we never know everything about the future but we always know something. For future energy systems that 'something' is the role and nature of the energy currencies. From this understanding, our appreciation of the deep future can take shape - at least for infrastructures, energy sources and some imbedded technologies-but not service-delivery widgets. The long view provides more than mere entertainment. It should form the basis of strategies for today that, in turn, will avoid blind alleys on our journey to tomorrow. Some people accept that hydrogen and electricity will be our future, but only 'until something better comes along.' The talk will conclude with logic that explains the response: No, nothing better will ever come along. (author)

The energy of today and tomorrow

International Nuclear Information System (INIS)

Bauquis, E.; Bauquis, P.R.

2007-01-01

The authors present a today state of the art concerning the energy domain in the world, offering perspectives on what could be the tomorrow world in matter of energy. They define fundamental notions, the different sources of energy and their price, the energy policies of the different countries and the problem of the consumption impact on the environment. (A.L.B.)

Advanced nickel/hydrogen dependent pressure vessel (DPV) cell and battery concepts

Energy Technology Data Exchange (ETDEWEB)

Caldwell, D.B. [Technologies Div., Eagle Picher Industries, Inc., Joplin, MO (United States); Fox, C.L. [Technologies Div., Eagle Picher Industries, Inc., Joplin, MO (United States); Miller, L.E. [Technologies Div., Eagle Picher Industries, Inc., Joplin, MO (United States)

1997-03-01

The dependent pressure vessel (DPV) nickel/hydrogen (NiH{sub 2}) design is being developed by Eagle-Picher industries, Inc. (EPI) as an advanced battery for military and commercial aerospace and terrestrial applications. The DPV cell design offers high specific energy and energy density as well as reduced cost, while retaining the established individual pressure vessel (IPV) technology, flight heritage and database. This advanced DPV design also offers a more efficient mechanical, electrical and thermal cell and battery configuration and a reduced parts count. The DPV battery design promotes compact, minimum volume packaging and weight efficiency, and delivers cost and weight savings with minimal design risks. (orig.)

Sensitivity Studies of Advanced Reactors Coupled to High Temperature Electrolysis (HTE) Hydrogen Production Processes

International Nuclear Information System (INIS)

Edwin A. Harvego; Michael G. McKellar; James E. O'Brien; J. Stephen Herring

2007-01-01

High Temperature Electrolysis (HTE), when coupled to an advanced nuclear reactor capable of operating at reactor outlet temperatures of 800 C to 950 C, has the potential to efficiently produce the large quantities of hydrogen needed to meet future energy and transportation needs. To evaluate the potential benefits of nuclear-driven hydrogen production, the UniSim process analysis software was used to evaluate different reactor concepts coupled to a reference HTE process design concept. The reference HTE concept included an Intermediate Heat Exchanger and intermediate helium loop to separate the reactor primary system from the HTE process loops and additional heat exchangers to transfer reactor heat from the intermediate loop to the HTE process loops. The two process loops consisted of the water/steam loop feeding the cathode side of a HTE electrolysis stack, and the steam or air sweep loop used to remove oxygen from the anode side. The UniSim model of the process loops included pumps to circulate the working fluids and heat exchangers to recover heat from the oxygen and hydrogen product streams to improve the overall hydrogen production efficiencies. The reference HTE process loop model was coupled to separate UniSim models developed for three different advanced reactor concepts (a high-temperature helium cooled reactor concept and two different supercritical CO2 reactor concepts). Sensitivity studies were then performed to evaluate the affect of reactor outlet temperature on the power cycle efficiency and overall hydrogen production efficiency for each of the reactor power cycles. The results of these sensitivity studies showed that overall power cycle and hydrogen production efficiencies increased with reactor outlet temperature, but the power cycle producing the highest efficiencies varied depending on the temperature range considered

Hydrogen production by high-temperature gas-cooled reactor. Conceptual design of advanced process heat exchangers of the HTTR-IS hydrogen production system

International Nuclear Information System (INIS)

Sakaba, Nariaki; Ohashi, Hirofumi; Sato, Hiroyuki; Hara, Teruo; Kato, Ryoma; Kunitomi, Kazuhiko

2008-01-01

Nuclear hydrogen production is necessary in an anticipated hydrogen society that demands a massive quantity of hydrogen without economic disadvantage. Japan Atomic Energy Agency (JAEA) has launched the conceptual design study of a hydrogen production system with a near-term plan to connect it to Japan's first high-temperature gas-cooled reactor HTTR. The candidate hydrogen production system is based on the thermochemical water-splitting iodine sulphur (IS) process.The heat of 10 MWth at approximately 900degC, which can be provided by the secondary helium from the intermediate heat exchanger of the HTTR, is the energy input to the hydrogen production system. In this paper, we describe the recent progresses made in the conceptual design of advanced process heat exchangers of the HTTR-IS hydrogen production system. A new concept of sulphuric acid decomposer is proposed. This involves the integration of three separate functions of sulphuric acid decomposer, sulphur trioxide decomposer, and process heat exchanger. A new mixer-settler type of Bunsen reactor is also designed. This integrates three separate functions of Bunsen reactor, phase separator, and pump. The new concepts are expected to result in improved economics through construction and operation cost reductions because the number of process equipment and complicated connections between the equipment has been substantially reduced. (author)

Conference on hydrogen-energy in France and Germany

International Nuclear Information System (INIS)

Bodineau, Luc; Menzen, Georg; Arnold, Peter Erich; Mauberger, Pascal; Roentzsch, Lars; Poggi, Philippe; Gervais, Thierry; Schneider, Guenther; Colomar, David; Buenger, Ulrich; Nieder, Babette; Zimmer, Rene; Jeanne, Fabrice; Le Grand, Jean-Francois

2014-01-01

The French-German office for Renewable energies (OFAEnR) organised a conference on hydrogen-energy in France and Germany. In the framework of this French-German exchange of experience, about 200 participants exchanged views on the different perspectives for use of hydrogen, in particular in transportation and energy storage applications. The technical production, transport and storage means were addressed too, as well as the technological models and the conditions for a large-scale industrial deployment. The economic prospects of hydrogen-energy in tomorrow's energy mix were also considered during the conference. This document brings together the available presentations (slides) made during this event: 1 - Hydrogen energy and Fuel Cells in France Today, and prospective (Luc Bodineau); 2 - The situation of energy Policy in Germany and the challenges for the Hydrogen Technology (Georg Menzen); 3 - Unlocking the Hydrogen Potential for Transport and Industry (Peter Erich Arnold); 4 - Hydrogen, a new energy for our planet - Hydrogen storage possibilities: example of solid storage (Pascal Mauberger); 5 - Innovative Materials and Manufacturing Technologies for H 2 Production and H 2 Storage (Lars Roentzsch); 6 - Scientific development and industrial strategy: experience feedback from the Myrte platform and energy transition-related perspectives (Philippe Poggi, Thierry Gervais); 7 - 'Power to Gas' - Important partner for renewables with big impact potential (Guenther Schneider) 8 - Developing a Hydrogen Infrastructure for Transport in France and Germany - A Comparison (David Colomar, Ulrich Buenger); 9 - H 2 and Fuel-Cells as Key Technologies for the Transition to Renewable energies - The example of Herten (Babette Nieder); 10 - Social acceptance of hydrogen mobility in Germany (Rene Zimmer); 11 - Hydrogen - A development opportunity for regions? (Fabrice Jeanne)

Employee Engagement: Motivating and Retaining Tomorrow's Workforce

Science.gov (United States)

Shuck, Michael Bradley; Wollard, Karen Kelly

2008-01-01

Tomorrow's workforce is seeking more than a paycheck; they want their work to meet their needs for affiliation, meaning, and self-development. Companies willing to meet these demands will capture the enormous profit potential of a workforce of fully engaged workers. This piece explores what engagement is, why it matters, and how human resource…

Summary - Advanced high-temperature reactor for hydrogen and electricity production

International Nuclear Information System (INIS)

Forsberg, Charles W.

2001-01-01

Historically, the production of electricity has been assumed to be the primary application of nuclear energy. That may change. The production of hydrogen (H 2 ) may become a significant application. The technology to produce H 2 using nuclear energy imposes different requirements on the reactor, which, in turn, may require development of new types of reactors. Advanced High Temperature reactors can meet the high temperature requirements to achieve this goal. This alternative application of nuclear energy may necessitate changes in the regulatory structure

Older People of Tomorrow: A Psychosocial Profile.

Science.gov (United States)

Silverstone, Barbara

1996-01-01

Attempts to narrow the scope of present uncertainties about the older population by sketching a psychosocial profile of the older people of tomorrow based on what is known today. Focuses on the baby boom generation and the interplay between personal attributes they could bring to late life and the social and physical environment in which they…

Challenging today's nuclear industry to be competitive in a changing tomorrow

International Nuclear Information System (INIS)

Plug, B.

1996-01-01

As the millennium approaches, the future of the nuclear power generation appears desolate. Today's nuclear executives are facing challenges resulting from worldwide change and have forced utilities to reevaluate their corporation's future directions. The nuclear industry must be competitive more than ever to address today's rapid changing marketplace and pressures exerted from: regulatory reformation; increased competition; changes in technology; customer evolution; and globalization. These factors have compelled nuclear executives to address questions such as: What impact will these changes have on today's marketplace, and on my corporation? What will characterize tomorrow's successful nuclear facility? How can today's nuclear corporation compete in tomorrow's marketplace? Will my corporation survive? (author)

Living on the Future Edge: Windows on Tomorrow

Science.gov (United States)

Jukes, Ian; McCain, Ted; Crockett, Lee

2010-01-01

"Living on the Future Edge" challenges school leaders to rethink longstanding paradigms and transform pedagogy for tomorrow's learners. Apple Computer, Inc. co-founder Steve Wozniak's foreword underscores the overwhelming need to adjust traditional instruction to fit today's high-tech world. The book explores this new landscape and…

Hydrogen production methods efficiency coupled to an advanced high temperature accelerator driven system

International Nuclear Information System (INIS)

Rodríguez, Daniel González; Lira, Carlos Alberto Brayner de Oliveira

2017-01-01

The hydrogen economy is one of the most promising concepts for the energy future. In this scenario, oil is replaced by hydrogen as an energy carrier. This hydrogen, rather than oil, must be produced in volumes not provided by the currently employed methods. In this work two high temperature hydrogen production methods coupled to an advanced nuclear system are presented. A new design of a pebbled-bed accelerator nuclear driven system called TADSEA is chosen because of the advantages it has in matters of transmutation and safety. For the conceptual design of the high temperature electrolysis process a detailed computational fluid dynamics model was developed to analyze the solid oxide electrolytic cell that has a huge influence on the process efficiency. A detailed flowsheet of the high temperature electrolysis process coupled to TADSEA through a Brayton gas cycle was developed using chemical process simulation software: Aspen HYSYS®. The model with optimized operating conditions produces 0.1627 kg/s of hydrogen, resulting in an overall process efficiency of 34.51%, a value in the range of results reported by other authors. A conceptual design of the iodine-sulfur thermochemical water splitting cycle was also developed. The overall efficiency of the process was calculated performing an energy balance resulting in 22.56%. The values of efficiency, hydrogen production rate and energy consumption of the proposed models are in the values considered acceptable in the hydrogen economy concept, being also compatible with the TADSEA design parameters. (author)

Hydrogen production methods efficiency coupled to an advanced high temperature accelerator driven system

Energy Technology Data Exchange (ETDEWEB)

Rodríguez, Daniel González; Lira, Carlos Alberto Brayner de Oliveira [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Departamento de Energia Nuclear; Fernández, Carlos García, E-mail: danielgonro@gmail.com, E-mail: mmhamada@ipen.br [Instituto Superior de Tecnologías y Ciencias aplicadas (InSTEC), La Habana (Cuba)

2017-07-01

The hydrogen economy is one of the most promising concepts for the energy future. In this scenario, oil is replaced by hydrogen as an energy carrier. This hydrogen, rather than oil, must be produced in volumes not provided by the currently employed methods. In this work two high temperature hydrogen production methods coupled to an advanced nuclear system are presented. A new design of a pebbled-bed accelerator nuclear driven system called TADSEA is chosen because of the advantages it has in matters of transmutation and safety. For the conceptual design of the high temperature electrolysis process a detailed computational fluid dynamics model was developed to analyze the solid oxide electrolytic cell that has a huge influence on the process efficiency. A detailed flowsheet of the high temperature electrolysis process coupled to TADSEA through a Brayton gas cycle was developed using chemical process simulation software: Aspen HYSYS®. The model with optimized operating conditions produces 0.1627 kg/s of hydrogen, resulting in an overall process efficiency of 34.51%, a value in the range of results reported by other authors. A conceptual design of the iodine-sulfur thermochemical water splitting cycle was also developed. The overall efficiency of the process was calculated performing an energy balance resulting in 22.56%. The values of efficiency, hydrogen production rate and energy consumption of the proposed models are in the values considered acceptable in the hydrogen economy concept, being also compatible with the TADSEA design parameters. (author)

The Need For Technology And Approaches Of Tomorrow

NARCIS (Netherlands)

De Zeeuw, C.J.; Lemmen, C.H.J.

2018-01-01

Having land rights for all at the short term at affordable cost and with an acceptable quality is a clear ambition that has been defined by many national and international organizations worldwide. In speeding up the development of land registration, the knowledge and technology of tomorrow are key

Just What Are Tomorrow's SME Employees Looking For?

Science.gov (United States)

Szamosi, Leslie T.

2006-01-01

Purpose: The paper seeks to determine what tomorrow's employees (i.e. graduates) are seeking from SMEs in terms of organizational satisfaction and value characteristics. Design/methodology/approach: A survey of 55 university students who identified SMEs as their best opportunity for their career goals is shown. The survey utilized tested measures…

Entrepreneurialism for Canadian Principals: Yesterday, Today, and Tomorrow

Science.gov (United States)

Scott, Shelleyann; Webber, Charles F.

2013-01-01

This article explores the various elements of Canadian educational entrepreneurialism as manifested yesterday, today, and tomorrow and in relation to the social and political influences of the time. This discussion is informed by the findings of the International Study of the Preparation of Principals (ISPP) and represents an expansion of the…

FY2009 Annual Progress Report for Advanced Power Electronics

Energy Technology Data Exchange (ETDEWEB)

Rogers, Susan A. [Dept. of Energy (DOE), Washington DC (United States)

2010-01-01

The Advanced Power Electronics and Electric Machines (APEEM) subprogram within the Vehicle Technologies Program provides support and guidance for many cutting-edge automotive technologies now under development. Research is focused on understanding and improving the way the various new components of tomorrow's automobiles will function as a unified system to improve fuel efficiency.

EURO - Before Yesterday, Yesterday, Today, Tomorrow...

OpenAIRE

Sylwia Pangsy-Kania

2002-01-01

The article was divided into four integrally connected parts concerning the EURO: before yesterday, yesterday, today and tomorrow. On the 1st January 2002 the common European currency became a fact. In eleven European countries there appeared jointly over 13 billion banknotes and 76 billion coins. The introduction of a common currency in the countries of the European Union is the greatest financial operation in world history with such a huge scale and degree of complication. Before yesterdayŠ...

76 FR 29769 - Healthy Tomorrows Partnership for Children Program

Science.gov (United States)

2011-05-23

...: Notice of a Noncompetitive Replacement Award to the University of Nevada School of Medicine, Department... University of Nevada School of Medicine, Department of Pediatrics, in order to continue Healthy Tomorrows supported prevention and intervention services to low-income, underserved women, children and adolescents in...

Annex 15 of the IEA Hydrogen Implementing Agreement : Photobiological hydrogen production

Energy Technology Data Exchange (ETDEWEB)

Lindblad, P. [Uppsala Univ., Uppsala (Sweden)]|[International Energy Agency, Paris (France)

2004-07-01

Task 15 of the Hydrogen Implementation Agreement of the International Energy Agency is to advance the science of biophotosynthesis of hydrogen, which is the biological production of hydrogen from water and sunlight using microalgal photosynthesis. A practical process for biophotolysis would result in an innovative biological source of sustainable and environmentally benign renewable energy source. Japan, Norway, Sweden and the United States initially committed to the project. Since then Canada, the Netherlands and the United Kingdom have joined. The current task is to produce hydrogen from both green algae and cyanobacteria with focus on early-stage applied research on biophotolysis processes with intermediate carbon dioxide fixation. Significant advances have also occurred in the scientific field of cyanobacterial biohydrogen. Cyanobacteria has enzymes that metabolise hydrogen. Photosynthetic cyanobacteria have simple nutritional requirements and can grow in air, water, or mineral salts with light as the only source of energy. This research will help provide the advances needed to achieve practical efficiencies and cost objectives of biological hydrogen production. tabs., figs.

Chemistry Today and Tomorrow-The Central, Useful, and Creative ...

Indian Academy of Sciences (India)

Home; Journals; Resonance – Journal of Science Education; Volume 2; Issue 5. Chemistry Today and Tomorrow – The Central, Useful and Creative Science. Uday Maitra. Book Review Volume 2 ... Author Affiliations. Uday Maitra1. Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India.

Effect of LEO cycling on 125 Ah advanced design IPV nickel-hydrogen battery cells

Science.gov (United States)

Smithrick, John J.; Hall, Stephen W.

1990-01-01

An advanced 125 Ah individual pressure vessel (IPV) nickel-hydrogen cell was designed. The primary function of the advanced cell is to store and deliver energy for long-term, low earth-orbit (LEO) spacecraft missions. The new features of this design are: (1) use of 26 percent rather than 31 percent potassium hydroxide (KOH) electrolyte, (2) use of a patented catalyzed wall wick, (3) use of serrated-edge separators to facilitate gaseous oxygen and hydrogen flow within the cell, while still maintaining physical contact with the wall wick for electrolyte management, and (4) use of a floating rather than a fixed stack (state-of-the-art) to accommodate nickel electrode expansion. Six 125-Ah flight cells based on this design were fabricated by Eagle-Picher. Three of the cells contain all of the advanced features (test cells) and three are the same as the test cells except they don't have catalyst on the wall wick (control cells). All six cells are in the process of being evaluated in a LEO cycle life test. The cells have accumulated about 4700 LEO cycles (60 percent DOD 10 C). There have been no cell failures; the catalyzed wall wick cells, however, are performing better.

Solar Hydrogen Reaching Maturity

Directory of Open Access Journals (Sweden)

Rongé Jan

2015-09-01

Full Text Available Increasingly vast research efforts are devoted to the development of materials and processes for solar hydrogen production by light-driven dissociation of water into oxygen and hydrogen. Storage of solar energy in chemical bonds resolves the issues associated with the intermittent nature of sunlight, by decoupling energy generation and consumption. This paper investigates recent advances and prospects in solar hydrogen processes that are reaching market readiness. Future energy scenarios involving solar hydrogen are proposed and a case is made for systems producing hydrogen from water vapor present in air, supported by advanced modeling.

The Engineering Workforce of Tomorrow - The Integrated Space Engineer

DEFF Research Database (Denmark)

Nielsen, Jens Frederik Dalsgaard

2007-01-01

The space engineer of tomorrow needs a variety of skills ranging from high specialized knowledge to cooperative capacities and the ability to understand and even to a certain degree to be productive outside their specialized skills. Newly educated engineers often lack many of these skills due...

77 FR 26019 - Healthy Tomorrows Partnership for Children Program

Science.gov (United States)

2012-05-02

..., effectiveness and impact of community-based projects post HTPCP funding, and the ability of projects to develop... communities. HTPCP has long encouraged Healthy Tomorrows projects involved in case management/care... Pediatrics (AAP). Up to $176,855 will be awarded over a one-year extended project period. The National...

Technology and Changing Lifestyles. Teacher's Guide. Preparing for Tomorrow's World.

Science.gov (United States)

Iozzi, Louis A.

"Technology and Changing Lifestyles" is one of the "Preparing for Tomorrow's World" (PTW) program modules. PTW is an interdisciplinary, future-oriented program incorporating information from the sciences and social sciences and addressing societal concerns which interface science/technology/society. The program promotes…

Blueprint for Tomorrow: Redesigning Schools for Student-Centered Learning

Science.gov (United States)

Nair, Prakash

2014-01-01

The United States has about $2 trillion tied up in aging school facilities. School districts throughout the country spend about $12 billion every year keeping this infrastructure going. Yet almost all of the new money we pour into school facilities reinforces an existing--and obsolete--model of schooling. In "Blueprint for Tomorrow,"…

Studies of hydrogen absorption and desorption processes in advanced intermetallic hydrides

Energy Technology Data Exchange (ETDEWEB)

Sato, Masashi

2005-07-01

This work is a part of the research program performed in the Department of Energy Systems, Institute for Energy Technology (Kjeller, Norway), which is focused on the development of the advanced hydrogen storage materials. The activities are aimed on studies of the mechanisms of hydrogen interactions with intermetallic alloys with focus on establishing an interrelation between the crystal structure, thermodynamics and kinetics of the processes in the metal-hydrogen systems, on the one hand, and hydrogen storage properties (capacity, rates of desorption, hysteresis). Many of the materials under investigation have potential to be applied in applications, whereas some already have been commercialised in the world market. A number of metals take up considerable amounts of hydrogen and form chemical compounds with H, metal hydrides. Unfortunately, binary hydrides are either very stable (e.g. for the rare earth metals [RE], Zr, Ti, Mg: metal R) or are formed at very high applied pressures of hydrogen gas (e.g. for the transition metals, Ni, Co, Fe, etc.: Metal T). However, hydrogenation process becomes easily reversible at very convenient from practical point of view conditions, around room temperature and at H2 pressures below 1 MPa for the two-component intermetallic alloys R{sub x}T{sub y}. This raised and maintains further interest to the intermetallic hydrides as solid H storage materials. Materials science research of this thesis is focused on studies of the reasons staying behind the beneficial effect of two non-transition elements M(i.e., In and Sn) contributing to the formation of the ternary intermetallic alloys R{sub x}T{sub y}M{sub 2}., on the hydrogen storage behaviours. Particular focus is on two aspects where the remarkable improvement of ordinary metal hydrides is achieved via introduction of In and Sn: a) Increase of the volume density of stored hydrogen in solid materials to the record high level. b) Improvement of the kinetics of hydrogen charge and

Doctors of tomorrow: An innovative curriculum connecting underrepresented minority high school students to medical school.

Science.gov (United States)

Derck, Jordan; Zahn, Kate; Finks, Jonathan F; Mand, Simanjit; Sandhu, Gurjit

2016-01-01

Racial minorities continue to be underrepresented in medicine (URiM). Increasing provider diversity is an essential component of addressing disparity in health delivery and outcomes. The pool of students URiM that are competitive applicants to medical school is often limited early on by educational inequalities in primary and secondary schooling. A growing body of evidence recognizing the importance of diversifying health professions advances the need for medical schools to develop outreach collaborations with primary and secondary schools to attract URiMs. The goal of this paper is to describe and evaluate a program that seeks to create a pipeline for URiMs early in secondary schooling by connecting these students with support and resources in the medical community that may be transformative in empowering these students to be stronger university and medical school applicants. The authors described a medical student-led, action-oriented pipeline program, Doctors of Tomorrow, which connects faculty and medical students at the University of Michigan Medical School with 9th grade students at Cass Technical High School (Cass Tech) in Detroit, Michigan. The program includes a core curriculum of hands-on experiential learning, development, and presentation of a capstone project, and mentoring of 9th grade students by medical students. Cass Tech student feedback was collected using focus groups, critical incident written narratives, and individual interviews. Medical student feedback was collected reviewing monthly meeting minutes from the Doctors of Tomorrow medical student leadership. Data were analyzed using thematic analysis. Two strong themes emerged from the Cass Tech student feedback: (i) Personal identity and its perceived effect on goal achievement and (ii) positive affect of direct mentorship and engagement with current healthcare providers through Doctors of Tomorrow. A challenge noted by the medical students was the lack of structured curriculum beyond the 1st

Parametric Evaluation of Large-Scale High-Temperature Electrolysis Hydrogen Production Using Different Advanced Nuclear Reactor Heat Sources

International Nuclear Information System (INIS)

Harvego, Edwin A.; McKellar, Michael G.; O'Brien, James E.; Herring, J. Stephen

2009-01-01

High Temperature Electrolysis (HTE), when coupled to an advanced nuclear reactor capable of operating at reactor outlet temperatures of 800 C to 950 C, has the potential to efficiently produce the large quantities of hydrogen needed to meet future energy and transportation needs. To evaluate the potential benefits of nuclear-driven hydrogen production, the UniSim process analysis software was used to evaluate different reactor concepts coupled to a reference HTE process design concept. The reference HTE concept included an Intermediate Heat Exchanger and intermediate helium loop to separate the reactor primary system from the HTE process loops and additional heat exchangers to transfer reactor heat from the intermediate loop to the HTE process loops. The two process loops consisted of the water/steam loop feeding the cathode side of a HTE electrolysis stack, and the sweep gas loop used to remove oxygen from the anode side. The UniSim model of the process loops included pumps to circulate the working fluids and heat exchangers to recover heat from the oxygen and hydrogen product streams to improve the overall hydrogen production efficiencies. The reference HTE process loop model was coupled to separate UniSim models developed for three different advanced reactor concepts (a high-temperature helium cooled reactor concept and two different supercritical CO2 reactor concepts). Sensitivity studies were then performed to evaluate the affect of reactor outlet temperature on the power cycle efficiency and overall hydrogen production efficiency for each of the reactor power cycles. The results of these sensitivity studies showed that overall power cycle and hydrogen production efficiencies increased with reactor outlet temperature, but the power cycles producing the highest efficiencies varied depending on the temperature range considered

Hydrogen in metals

CSIR Research Space (South Africa)

Carter, TJ

2001-04-01

Full Text Available .J. Cartera,*, L.A. Cornishb aAdvanced Engineering & Testing Services, MATTEK, CSIR, Private Bag X28, Auckland Park 2006, South Africa bSchool of Process and Materials Engineering, University of the Witwatersrand, Private Bag 3, P.O. WITS 2050, South Africa... are contrasted, and an unusual case study of hydrogen embrittlement of an alloy steel is presented. 7 2001 Published by Elsevier Science Ltd. Keywords: Hydrogen; Hydrogen-assisted cracking; Hydrogen damage; Hydrogen embrittlement 1. Introduction Hydrogen suC128...

HOGEN{trademark} proton exchange membrane hydrogen generators: Commercialization of PEM electrolyzers

Energy Technology Data Exchange (ETDEWEB)

Smith, W.F.; Molter, T.M. [Proton Energy Systems, Inc., Rocky Hill, CT (United States)

1997-12-31

PROTON Energy Systems` new HOGEN series hydrogen generators are Proton Exchange Membrane (PEM) based water electrolyzers designed to generate 300 to 1000 Standard Cubic Feet Per Hour (SCFH) of high purity hydrogen at pressures up to 400 psi without the use of mechanical compressors. This paper will describe technology evolution leading to the HOGEN, identify system design performance parameters and describe the physical packaging and interfaces of HOGEN systems. PEM electrolyzers have served US and UK Navy and NASA needs for many years in a variety of diverse programs including oxygen generators for life support applications. In the late 1970`s these systems were advocated for bulk hydrogen generation through a series of DOE sponsored program activities. During the military buildup of the 1980`s commercial deployment of PEM hydrogen generators was de-emphasized as priority was given to new Navy and NASA PEM electrolysis systems. PROTON Energy Systems was founded in 1996 with the primary corporate mission of commercializing PEM hydrogen generators. These systems are specifically designed and priced to meet the needs of commercial markets and produced through manufacturing processes tailored to these applications. The HOGEN series generators are the first step along the path to full commercial deployment of PEM electrolyzer products for both industrial and consumer uses. The 300/1000 series are sized to meet the needs of the industrial gases market today and provide a design base that can transition to serve the needs of a decentralized hydrogen infrastructure tomorrow.

Storage of hydrogen in advanced high pressure container. Appendices; Lagring af brint i avancerede hoejtryksbeholdere. Appendiks 1

Energy Technology Data Exchange (ETDEWEB)

Bentzen, J.J.; Lystrup, A. [Forskningscenter Risoe, Roskilde (Denmark)

2005-07-15

The objective of the project has been to study barriers for a production of advanced high pressure containers especially suitable for hydrogen, in order to create a basis for a container production in Denmark. The project has primarily focused on future Danish need for hydrogen storage in the MWh area. One task has been to examine requirement specifications for pressure tanks that can be expected in connection with these stores. Six potential storage needs have been identified: (1) Buffer in connection with start-up/regulation on the power grid. (2) Hydrogen and oxygen production. (3) Buffer store in connection with VEnzin vision. (4) Storage tanks on hydrogen filling stations. (5) Hydrogen for the transport sector from 1 TWh surplus power. (6) Tanker transport of hydrogen. Requirements for pressure containers for the above mentioned use have been examined. The connection between stored energy amount, pressure and volume compared to liquid hydrogen and oil has been stated in tables. As starting point for production technological considerations and economic calculations of various container concepts, an estimation of laminate thickness in glass-fibre reinforced containers with different diameters and design print has been made, for a 'pure' fibre composite container and a metal/fibre composite container respectively. (BA)

Hydrogen & fuel cells: advances in transportation and power

National Research Council Canada - National Science Library

Hordeski, Michael F

2009-01-01

... race, it became more of an economics issue since as long as petroleum was available and cheap there was no need to develop a hydrogen technology. Now, we see much more investment in fuel cell technology, hydrogen fueled vehicles and even hydrogen fuel stations. The technology is being pushed by economics as oil prices continue to rise with dwind...

Hydrogen Contractors Meeting

Energy Technology Data Exchange (ETDEWEB)

Fitzsimmons, Tim [Dept. of Energy (DOE), Washington DC (United States). Office of Basic Energy Sciences. Division of Materials Sciences and Engineering

2006-05-16

This volume highlights the scientific content of the 2006 Hydrogen Contractors Meeting sponsored by the Division of Materials Sciences and Engineering (DMS&E) on behalf of the Office of Basic Energy Sciences (BES) of the U. S. Department of Energy (DOE). Hydrogen Contractors Meeting held from May 16-19, 2006 at the Crystal Gateway Marriott Hotel Arlington, Virginia. This meeting is the second in a series of research theme-based Contractors Meetings sponsored by DMS&E held in conjunction with our counterparts in the Office of Energy Efficiency and Renewable Energy (EERE) and the first with the Hydrogen, Fuel Cells and Infrastructure Technologies Program. The focus of this year’s meeting is BES funded fundamental research underpinning advancement of hydrogen storage. The major goals of these research efforts are the development of a fundamental scientific base in terms of new concepts, theories and computational tools; new characterization capabilities; and new materials that could be used or mimicked in advancing capabilities for hydrogen storage.

Latino Educators of Tomorrow: Culture-Specific Mentoring for the College Transition

Science.gov (United States)

Treviño, Anna; Hite, Julie M.; Hallam, Pamela R.; Ferrin, Scott E.

2014-01-01

This qualitative study examines the perspectives of high school-and college-age students who participated in an educational program designed to increase the number of Latino students entering teaching as a profession: Latino Educators of Tomorrow. Using open-ended surveys and semistructured interviews, this study identified themes regarding the…

A Framework for Instructional Innovation in the Preparation of Tomorrow's Teachers

Science.gov (United States)

Dilworth, Paulette; Donaldson, Ana; George, Marshall; Knezek, Don; Searson, Mike; Starkweather, Kendall; Strutchens, Marilyn; Tillotson, John; Robinson, Sharon

2012-01-01

Emergent technologies offer opportunities to understand concepts in deeper, often different, and more meaningful ways. However, this growth in understanding will occur only if teachers learn to use these technologies in effective ways. The federal initiative Preparing Tomorrow's Teachers to Use Technology (PT3) was launched in 1999 to address this…

Recent advances on enzymatic glucose/oxygen and hydrogen/oxygen biofuel cells: Achievements and limitations

Science.gov (United States)

Cosnier, Serge; J. Gross, Andrew; Le Goff, Alan; Holzinger, Michael

2016-09-01

The possibility of producing electrical power from chemical energy with biological catalysts has induced the development of biofuel cells as viable energy sources for powering portable and implanted electronic devices. These power sources employ biocatalysts, called enzymes, which are highly specific and catalytic towards the oxidation of a biofuel and the reduction of oxygen or hydrogen peroxide. Enzymes, on one hand, are promising candidates to replace expensive noble metal-based catalysts in fuel cell research. On the other hand, they offer the exciting prospect of a new generation of fuel cells which harvest energy from body fluids. Biofuel cells which use glucose as a fuel are particularly interesting for generating electricity to power electronic devices inside a living body. Hydrogen consuming biofuel cells represent an emerging alternative to platinum catalysts due to comparable efficiencies and the capability to operate at lower temperatures. Currently, these technologies are not competitive with existing commercialised fuel cell devices due to limitations including insufficient power outputs and lifetimes. The advantages and challenges facing glucose biofuel cells for implantation and hydrogen biofuel cells will be summarised along with recent promising advances and the future prospects of these exotic energy-harvesting devices.

Advanced dependent pressure vessel (DPV) nickel-hydrogen spacecraft battery design

Energy Technology Data Exchange (ETDEWEB)

Coates, D.K.; Grindstaff, B.; Swaim, O.; Fox, C. [Eagle-Picher Industries, Inc., Joplin, MO (United States). Advanced Systems Operation

1995-12-31

The dependent pressure vessel (DPV) nickel-hydrogen (NiH{sub 2}) battery is being developed as a potential spacecraft battery design for both military and commercial satellites. The limitations of standard NiH{sub 2} individual pressure vessel (IPV) flight battery technology are primarily related to the internal cell design and the battery packaging issues associated with grouping multiple cylindrical cells. The DPV cell design offers higher energy density and reduced cost, while retaining the established IPV technology flight heritage and database. The advanced cell design offers a more efficient mechanical, electrical and thermal cell configuration and a reduced parts count. The geometry of the DPV cell promotes compact, minimum volume packaging and weight efficiency. The DPV battery design offers significant cost and weight savings advantages while providing minimal design risks.

A Century of John and Evelyn Dewey's "Schools of To-Morrow": Rousseau, Recorded Knowledge, and Race in the Philosopher's Most Problematic Text

Science.gov (United States)

Fallace, Thomas; Fantozzi, Victoria

2015-01-01

A century ago, John Dewey and his daughter Evelyn published "Schools of To-morrow" to nearly universal acclaim. However, over the course of the 20th century, critics of Dewey have drawn upon "Schools of To-morrow" to accuse him of being an uncritical disciple of French philosopher, Jean Rousseau, of being opposed to the…

Liquid-phase chemical hydrogen storage: catalytic hydrogen generation under ambient conditions.

Science.gov (United States)

Jiang, Hai-Long; Singh, Sanjay Kumar; Yan, Jun-Min; Zhang, Xin-Bo; Xu, Qiang

2010-05-25

There is a demand for a sufficient and sustainable energy supply. Hence, the search for applicable hydrogen storage materials is extremely important owing to the diversified merits of hydrogen energy. Lithium and sodium borohydride, ammonia borane, hydrazine, and formic acid have been extensively investigated as promising hydrogen storage materials based on their relatively high hydrogen content. Significant advances, such as hydrogen generation temperatures and reaction kinetics, have been made in the catalytic hydrolysis of aqueous lithium and sodium borohydride and ammonia borane as well as in the catalytic decomposition of hydrous hydrazine and formic acid. In this Minireview we briefly survey the research progresses in catalytic hydrogen generation from these liquid-phase chemical hydrogen storage materials.

An advanced liquid hydrogen cold source for the NIST research reactor

International Nuclear Information System (INIS)

Williams, R.E.; Kopetka, P.; Rowe, J.M.

1999-01-01

A second-generation liquid hydrogen cold neutron source is currently being fabricated and will be installed in the NIST reactor early next year. The existing source has operated very successfully over the last four years, providing a six-fold increase in the cold neutron yield compared to the previous heavy ice source. The design of the new source is based on our operating experience with the existing LH 2 source and extensive neutron transport calculations using improved MCNP modeling and computational capabilities. Enhanced mechanical design and manufacturing tools are exploited in the fabrication of the advanced source, which is expected to nearly double the yield of the existing LH 2 source. (author)

Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose

International Nuclear Information System (INIS)

Li, Yuping; Liao, Yuhe; Cao, Xiaofeng; Wang, Tiejun; Ma, Longlong; Long, Jinxing; Liu, Qiying; Xua, Ying

2015-01-01

In this review, recent advances in the one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose to value-added polyols, including hexitols (sorbitol, mannitol, and isosorbide) and 1,2-alkanediols (ethylene glycol and 1,2-propylene glycol), are summarized. Methods for the generation of H + in the first step of cellulose hydrolysis to form intermediate sugars, such as the use of soluble acids (mineral acids and heteropoly acids) and H + produced in situ from functional supports and H 2 dissociation, are classified and analyzed, considering its combination with active metals for the subsequent hydrogenation or hydrogenolysis of sugars to polyols. The interaction of non-noble metals such as nickel, bimetals, and tungsten with support materials in the catalytic conversion of intermediate sugars to hexitols and ethylene glycol is reviewed. The corresponding reaction pathways and mechanisms are discussed, including the conversion process using basic supports and solution conditions. Major challenges and promising routes are also suggested for the future development of the chemocatalytic conversion of cellulose. - Highlights: • Advances in the one-pot hydrolytic hydrogenation/hydrogenolysis of cellulose are summarized. • The interaction of non-noble metals with support materials for cellulose conversion is reviewed. • Method for the generation of in situ H + and effects of the acidic groups on supports are discussed. • Incomplete identification of intermediates/products causes mechanism complications. • Efficient conversion, separation and purification are other concerns for cellulose degrading

Apple Classrooms of Tomorrow: Philosophy and Structure [and] What's Happening Where.

Science.gov (United States)

Apple Computer, Inc., Cupertino, CA.

Apple Classrooms of Tomorrow (ACOT) is a long-term research project sponsored by Apple Computer, Inc., to explore how learning and teaching change when teachers and students have access to interactive computer technologies. ACOT adheres to a philosophy that instruction should be learner controlled; i.e., students take responsibility for their own…

Advanced nanostructured materials as media for hydrogen storage

International Nuclear Information System (INIS)

David, E.; Niculescu, V.; Armeanu, A.; Sandru, C.; Constantinescu, M.; Sisu, C.

2005-01-01

Full text: In a future sustainable energy system based on renewable energy, environmentally harmless energy carriers like hydrogen, will be of crucial importance. One of the major impediments for the transition to a hydrogen based energy system is the lack of satisfactory hydrogen storage alternatives. Hydrogen storage in nanostructured materials has been proposed as a solution for adequate hydrogen storage for a number of applications, in particular for transportation. This paper is a preliminary study with the focus on possibilities for hydrogen storage in zeolites, alumina and nanostructured carbon materials. The adsorption properties of these materials were evaluated in correlation with their internal structure. From N 2 physisorption data the BET surface area (S BET ) , total pore volume (PV), micropore volume (MPV) and total surface area (S t ) were derived. H 2 physisorption measurements were performed at 77 K and a pressure value of 1 bar. From these data the adsorption capacities of sorbent materials were determined. Apparently the microporous adsorbents, e.g activated carbons, display appreciable sorption capacities. Based on their micropore volume, carbon-based sorbents have the largest adsorption capacity for H 2 , over 230 cm 3 (STP)/g, at the previous conditions. By increasing the micropore volume (∼ 1 cm 3 /g) of sorbents and optimizing the adsorption conditions it is expected to obtain an adsorption capacity of ∼ 560 cm 3 (STP)/g, close to targets set for mobile applications. (authors)

Advanced IGCC-Hypogen concepts for a developing hydrogen market

Energy Technology Data Exchange (ETDEWEB)

Starr, F.; Cormos, C.-C.; Tzimas, E.; Brown, A. [European Commission, Petten (Netherlands). DG Joint Research Centre, Institute for Energy

2007-07-01

With FP6 the EU is funding a project called 'Dynamis' which aims to design plants to generate electricity, plus a limited amount of hydrogen from fossil fuels, in which the CO{sub 2} is captured and stored underground. Such plants have been characterised as being of the 'HYPOGEN' type since they generate both hydrogen and electric power. As the hydrogen market develops IGCC-Hypogen based systems will need to produce much greater amounts of hydrogen. It is also desirable that such plants should be able to vary the proportion of hydrogen-to-electricity. This will enable IGCC-Hypogen plants to load follow and two-shift as electricity demand from the grid changes. Such variations in power output are not always practical with existing designs of electricity-only IGCCs. This paper reviews the technical issues involved in providing a high-flexibility IGCC-Hypogen plant. Three such concepts are discussed (1) very limited flexibility in which the changes from a fixed hydrogen-electricity ratio concept are minor, (2) moderate level of flexibility in which the limit is imposed by the CCGT gas turbine turndown (3) complete flexibility, the plant being able produce the energy as all-electricity or all-hydrogen. 9 refs., 2 figs., 1 tab.

'Post-carbon cities', the driving force in tomorrow's green economy?

International Nuclear Information System (INIS)

Theys, Jacques

2011-01-01

In early 2009, ADEME (Agence de l'Environnement et de la Maitrise de l'energie) and the French Ministry of Ecology, Sustainable Development, Transportation and Housing launched a major program for exploring realistic - acceptable and efficient - approaches to the transition toward 'post-carbon' cities. What happens in cities will determine to a large and durable degree the scope and structure of tomorrow's green economy

Electrochemical advanced oxidation processes: today and tomorrow. A review.

Science.gov (United States)

Sirés, Ignasi; Brillas, Enric; Oturan, Mehmet A; Rodrigo, Manuel A; Panizza, Marco

2014-01-01

In recent years, new advanced oxidation processes based on the electrochemical technology, the so-called electrochemical advanced oxidation processes (EAOPs), have been developed for the prevention and remediation of environmental pollution, especially focusing on water streams. These methods are based on the electrochemical generation of a very powerful oxidizing agent, such as the hydroxyl radical ((•)OH) in solution, which is then able to destroy organics up to their mineralization. EAOPs include heterogeneous processes like anodic oxidation and photoelectrocatalysis methods, in which (•)OH are generated at the anode surface either electrochemically or photochemically, and homogeneous processes like electro-Fenton, photoelectro-Fenton, and sonoelectrolysis, in which (•)OH are produced in the bulk solution. This paper presents a general overview of the application of EAOPs on the removal of aqueous organic pollutants, first reviewing the most recent works and then looking to the future. A global perspective on the fundamentals and experimental setups is offered, and laboratory-scale and pilot-scale experiments are examined and discussed.

Advanced mass spectrometers for hydrogen-isotope analyses

International Nuclear Information System (INIS)

Chastagner, P.; Daves, H.L.; Hess, W.B.

1982-01-01

Two advanced mass spectrometers for the accurate analysis of mixtures of the hydrogen isotopes were evaluated by Du Pont personnel at the Savannah River Laboratory. One is a large double-focusing instrument with a resolution of 2000 at mass 4 and an abundance sensitivity of >100,000 for the HT-D 2 doublet. The second is a smaller, simpler, stigmatic focusing instrument with exceptionally high ion intensities (>1 x 10 - 9 A at 600 resolution and about 1 x 10 - 10 A at 1300 resolution) for high signal-to-noise ratios. Both instruments are computer controlled. Once a scan is started, peak switching, scanning, mass discrimination control, data collection, and data reduction are done without operator intervention. Utility routines control hysteresis effects and instrument calibration. A containment facility, with dual inlet systems and a standard distribution system, permits testing with tritium mixtures. Helium flow standards and tritium activity meters provide independent verification of the mass spectrometer calibrations. A recovery system prevents the release of tritium to the environment. The performance of the mass spectrometers was essentially equal under simulated process control conditions. Precision and accuracy for the D/T ratio was <0.5% (rel 2sigma limits). Performance factors were: sample equilibration <300 ppM; linearity within +-0.3%; and gas interference <0.1%. Mass discrimination was controlled reliably by the computers

Prospects for hydrogen storage in graphene.

Science.gov (United States)

Tozzini, Valentina; Pellegrini, Vittorio

2013-01-07

Hydrogen-based fuel cells are promising solutions for the efficient and clean delivery of electricity. Since hydrogen is an energy carrier, a key step for the development of a reliable hydrogen-based technology requires solving the issue of storage and transport of hydrogen. Several proposals based on the design of advanced materials such as metal hydrides and carbon structures have been made to overcome the limitations of the conventional solution of compressing or liquefying hydrogen in tanks. Nevertheless none of these systems are currently offering the required performances in terms of hydrogen storage capacity and control of adsorption/desorption processes. Therefore the problem of hydrogen storage remains so far unsolved and it continues to represent a significant bottleneck to the advancement and proliferation of fuel cell and hydrogen technologies. Recently, however, several studies on graphene, the one-atom-thick membrane of carbon atoms packed in a honeycomb lattice, have highlighted the potentialities of this material for hydrogen storage and raise new hopes for the development of an efficient solid-state hydrogen storage device. Here we review on-going efforts and studies on functionalized and nanostructured graphene for hydrogen storage and suggest possible developments for efficient storage/release of hydrogen under ambient conditions.

IEA Hydrogen Implementing Agreement's Second Generation R and D and the Hydrogen Economy

Energy Technology Data Exchange (ETDEWEB)

Beck, N.; Garcia-Conde, A. G.; Riis, T. U.; Luzzi, A.; Valladares, M. R. de

2005-07-01

Since its creation by the International Energy Agency in the late 1970's, the IEA Hydrogen Implementing Agreement (HIA) has been at the forefront of collaborative international hydrogen research and development (R and D) (http://www.ieahia.org. ) The collective body of HIA hydrogen R and D will contribute to definition of the hydrogen economy. The five-year [2004-2009) mission of the IEA HIA is to advance the adoption of a Hydrogen Economy through strategic implementation of collaborative R and D and outreach programs that address key issues and barriers. The three goals for the Second Generation HIA are: Advancement of science and technology via pre-commercial collaborative RD and D programs; Assessment of market environment, including the non-energy sector; and Implementation of outreach program, aimed at community acceptance and support. The HIA launched its Second Generation of hydrogen R and D in the latter part of 2004. The HIA's anniversary report: In Pursuit of the Future: 25 Years of IEA Research towards the realization of Hydrogen Energy Systems (http://ieahia.org/pdfs/IEA_AnniversaryReport_HIA.pdf) chronicles its contributions to hydrogen R and D. As the hydrogen economy takes shape, the HIA is pleased to share highlights of its R and D history together with progress on planned activities and its six current annexes, listed below: Task 15 Photobiological Production of Hydrogen Task 16 Hydrogen from Carbon-Containing Materials Task 17 Solid and Liquid Storage Task 18 Integrated Systems Evaluation Task 19 Safety Task 20 Hydrogen from Waterphotolysis Planned successor annexes in storage and photobiological hydrogen production will also be discussed, along with a task on high temperature hydrogen production that is now in the definition phase. Over 250 experts from the sixteen member HIA countries and the European Union contribute to this portfolio of cutting edge hydrogen R and D and analysis activities. Several other countries are expected to

Recent advances on membranes and membrane reactors for hydrogen production

NARCIS (Netherlands)

Gallucci, F.; Fernandez Gesalaga, E.; Corengia, P.; Sint Annaland, van M.

2013-01-01

Membranes and membrane reactors for pure hydrogen production are widely investigated not only because of the important application areas of hydrogen, but especially because mechanically and chemically stable membranes with high perm-selectivity towards hydrogen are available and are continuously

Evaluating the Effectiveness of NASA's Destination Tomorrow(Trademark) 2000-2001 Program

Science.gov (United States)

Pinelli, Thomas E.; Perry, Jeannine

2002-01-01

NASA's Destination Tomorrow(trademark) series consists of 30-minute educational television programs that focus on NASA research, past, present, and future and are designed for educators, parents, and adult (lifelong) learners. Programs in this award-winning series follow a magazine style format with segments ranging from 3-5 minutes to 6-8 minutes. An associated web site provides summaries of stories and links to related program material. The development of the programs is based on educational theory, principles, and research as they pertain to how adults learn and apply knowledge. The five programs in the 2000-2001 season were produced in English and dubbed in Spanish. Telephone interviews with managers of cable access television stations were conducted in January 2002. NASA's Destination Tomorrow(trademark) interviewees reported that (1) from a programming standpoint, the most appealing aspects of the series are its production quality and educational value, (2) programs in the series are 'better than average' when compared to other education programming, (3) the programs are very credible, (4) the programs are successful in educating people about what NASA does, and (5) the programs have been 'very well received' by their audiences.

Considerations for restoring temperate forests of tomorrow: Forest restoration, assisted migration, and bioengineering

Science.gov (United States)

Kas Dumroese; Mary I. Williams; John A. Stanturf; Brad St. Clair

2015-01-01

Tomorrow’s forests face extreme pressures from contemporary climate change, invasive pests, and anthropogenic demands for other land uses. These pressures, collectively, demand land managers to reassess current and potential forest management practices. We discuss three considerations, functional restoration, assisted migration, and bioengineering, which are currently...

Magnetic liquefier for hydrogen

International Nuclear Information System (INIS)

1992-01-01

This document summarizes work done at the Astronautics Technology Center of the Astronautics Corporation of America (ACA) in Phase 1 of a four phase program leading to the development of a magnetic liquefier for hydrogen. The project involves the design, fabrication, installation, and operation of a hydrogen liquefier providing significantly reduced capital and operating costs, compared to present liquefiers. To achieve this goal, magnetic refrigeration, a recently developed, highly efficient refrigeration technology, will be used for the liquefaction process. Phase 1 project tasks included liquefier conceptual design and analysis, preliminary design of promising configurations, design selection, and detailed design of the selected design. Fabrication drawings and vendor specifications for the selected design were completed during detailed design. The design of a subscale, demonstration magnetic hydrogen liquefier represents a significant advance in liquefaction technology. The cost reductions that can be realized in hydrogen liquefaction in both the subscale and, more importantly, in the full-scale device are expected to have considerable impact on the use of liquid hydrogen in transportation, chemical, and electronic industries. The benefits to the nation from this technological advance will continue to have importance well into the 21st century

Educating the Interprofessionals of tomorrow

DEFF Research Database (Denmark)

Mortensen, Hanne Franciska

Abstract 7th International Nurse Education Conference, Banff, CANADA, May 2018 Theme: Curriculum innovation & development. Preferred presentation form: Poster Title: Educating the Interprofessionals of tomorrow Author: Mortensen, Hanne Franciska, Senior Lecturer, Metropolitan University College, ...... (2013): Introducing Interprofessional Education. Caipe 2013. www.caipe.org.uk IPEC (2011) Core competencies for interprofessional collaborative practice: Report of an expert panel. IPEC Report, USA ...... courses since 2015 to develop students’ Common competencies, Complementary competencies and Collaborative competencies (Barr, 1998). The course is a 10-week program where up to 1.200 students and 150 lecturers from 12 different welfare educations participate. The students select and follow one of 12......’ collaboration with other professionals. Results: The students evaluated the outcome of the course as follows: Excellent (20 %), very good (37%) or good (29%). The lecturers evaluated how competent they felt delivering the course: excellent (45%), very good (35%) and good (18%), which is an increase. Conclusion...

IEA hydrogen agreement, task 15: photobiological hydrogen production - an international collaboration

International Nuclear Information System (INIS)

Lindblad, P.; Asada, Y.; Benemann, J.; Hallenbeck, P.; Melis, A.; Miyake, J.; Seibert, M.; Skulberg, O.

2000-01-01

Biological hydrogen production, the production of H 2 by microorganisms, has been an active field of basic and applied research for many years. Realization of practical processes for photobiological hydrogen production from water using solar energy would result in a major, novel source of sustainable and renewable energy, without greenhouse gas emissions or environmental pollution. However, development of such processes requires significant scientific and technological advances, and long-term basic and applied R and D. This International Energy Agency (lEA) Task covers research areas and needs at the interface of basic and applied R and D which are of mutual interest to the countries and researchers participating in the lEA Hydrogen Agreement. The overall objective is to sufficiently advance the basic and early-stage applied science in this area of research over the next five years to allow an evaluation of the potential of such a technology to be developed as a practical renewable energy source for the 21st Century. (author)

Hydrogen production from algal biomass - Advances, challenges and prospects.

Science.gov (United States)

Show, Kuan-Yeow; Yan, Yuegen; Ling, Ming; Ye, Guoxiang; Li, Ting; Lee, Duu-Jong

2018-06-01

Extensive effort is being made to explore renewable energy in replacing fossil fuels. Biohydrogen is a promising future fuel because of its clean and high energy content. A challenging issue in establishing hydrogen economy is sustainability. Biohydrogen has the potential for renewable biofuel, and could replace current hydrogen production through fossil fuel thermo-chemical processes. A promising source of biohydrogen is conversion from algal biomass, which is abundant, clean and renewable. Unlike other well-developed biofuels such as bioethanol and biodiesel, production of hydrogen from algal biomass is still in the early stage of development. There are a variety of technologies for algal hydrogen production, and some laboratory- and pilot-scale systems have demonstrated a good potential for full-scale implementation. This work presents an elucidation on development in biohydrogen encompassing biological pathways, bioreactor designs and operation and techno-economic evaluation. Challenges and prospects of biohydrogen production are also outlined. Copyright © 2018 Elsevier Ltd. All rights reserved.

Vaccination ecosystem health check: achieving impact today and sustainability for tomorrow.

Science.gov (United States)

Saadatian-Elahi, Mitra; Bloom, David; Plotkin, Stanley; Picot, Valentina; Louis, Jacques; Watson, Michael

2017-01-01

Vaccination is a complex ecosystem with several components that interact with one another and with the environment. Today's vaccine ecosystem is defined by the pursuit of polio eradication, the drive to get as many of the new vaccines to as many people as possible and the research and development against immunologically challenging diseases. Despite these successes, vaccine ecosystem is facing keys issues with regard to supply/distribution and cost/profitability asymmetry that risk slowing its global growth. The conference "Vaccination ecosystem health check: achieving impact today and sustainability for tomorrow" held in Annecy-France (January 19-21, 2015) took stock of the health of today's vaccination ecosystem and its ability to reliably and sustainably supply high-quality vaccines while investing in tomorrow's needed innovation. Small and decreasing numbers of suppliers/manufacturing facilities; paucity of research-driven companies; regulatory pressures; market uncertainties; political prioritization; anti-vaccine movements/complacency; and technological and programmatic issues were acknowledged as the major challenges that could weaken today's vaccination ecosystem. The expert panel discussed also drivers and barriers to a sustainable vaccination ecosystem; the metrics of a vaccination ecosystem; and what should be added, removed, increased, or reduced to maintain the health of the vaccination ecosystem.

Advanced reactors and future energy market needs

International Nuclear Information System (INIS)

Paillere, Henri; )

2017-01-01

Based on the results of a very well-attended international workshop on 'Advanced Reactor Systems and Future Energy Market Needs' that took place in April 2017, the NEA has embarked on a two-year study with the objective of analysing evolving energy market needs and requirements, as well as examining how well reactor technologies under development today will fit into tomorrow's low-carbon world. The NEA Expert Group on Advanced Reactor Systems and Future Energy Market Needs (ARFEM) held its first meeting on 5-6 July 2017 with experts from Canada, France, Italy, Japan, Korea, Poland, Romania, Russia and the United Kingdom. The outcome of the study will provide much needed insight into how well nuclear can fulfil its role as a key low-carbon technology, and help identify challenges related to new operational, regulatory or market requirements

Is there a tomorrow for nuclear power generation?

International Nuclear Information System (INIS)

Kanoh, T.

1996-01-01

Critical comments are publicly made about nuclear power generation and the nuclear fuel cycle. This criticism is directed at three areas of concern: accidents, radioactive waste disposal, and proliferation of nuclear weapons. In addition, there are other comments that ask 'Why are there countries pushing for nuclear power generation when other countries around the world are giving it up?' and 'Will further efforts to develop new energy sources and energy conservation not eliminate the nneed for nuclear power generation?' Such critical comments appear in some media more often than those expressing other opinions. Is there really no tomorrow for nuclear power? This question is studied below. (author)

Today's Realities for Tomorrow's Image Makers: How Practitioners Can Prepare Students for Communication Careers.

Science.gov (United States)

Ceperley, Andrew T.

1999-01-01

Communication internships and jobs abound in a world that responds to images. Students who can design, articulate, and create may be the image-makers of tomorrow. Article discusses how career centers can assist students. Describes National Communication Career Services Network founded at the University of Texas-Austin's Communication Career…

Civil nuclear. Which abilities for tomorrow?

International Nuclear Information System (INIS)

Anon.

2010-01-01

As the nuclear sector is entering a revival period with tens of reactors under construction and hundreds of projects, this sector is also facing recruitment challenges as an important part of its personnel will be retired (in 2009, EDF stated that nearly forty per cent of its nuclear engineers and technicians will be retired in a five year time), and as young generations seem less interested in scientific education and more particularly in nuclear science. Therefore, some of the main actors like EDF and GDF Suez organize information campaigns towards students and young graduates. As France exports to China its teaching expertise in the field of nuclear energy, and as EDF has created a European Foundation for tomorrow's energies to develop and value energy education, some suggest the creation of an international institute for nuclear education

Daily Affective and Behavioral Forecasts in Romantic Relationships: Seeing Tomorrow Through the Lens of Today.

Science.gov (United States)

Lemay, Edward P; Lin, Jonathan L; Muir, Heather J

2015-07-01

The current research examined accuracy and bias in daily forecasts within romantic relationships. Results of an extensive daily report study involving 200 romantic dyads and 4,822 daily observations suggested that predictions regarding affect and partner behavior that will occur tomorrow are somewhat accurate, predicted by actual experiences tomorrow, but are largely biased by current experiences. Participants appeared to project the current state of their relationship into the future, a temporal projection bias. This bias predicted forecasters' pro-relationship motivation and behavior. Forecasters were less likely to exhibit the temporal projection bias when they were high in relationship commitment, and they were more likely to exhibit the bias when they were high in need for cognitive closure, suggesting that motivation can constrain or amplify tendencies to project the present into the future. Implications for interpersonal relationships are discussed. © 2015 by the Society for Personality and Social Psychology, Inc.

Electrochemical Hydrogen Compressor

Energy Technology Data Exchange (ETDEWEB)

Lipp, Ludwig [FuelCell Energy, Inc., Torrington, CT (United States)

2016-01-21

Conventional compressors have not been able to meet DOE targets for hydrogen refueling stations. They suffer from high capital cost, poor reliability and pose a risk of fuel contamination from lubricant oils. This project has significantly advanced the development of solid state hydrogen compressor technology for multiple applications. The project has achieved all of its major objectives. It has demonstrated capability of Electrochemical Hydrogen Compression (EHC) technology to potentially meet the DOE targets for small compressors for refueling sites. It has quantified EHC cell performance and durability, including single stage hydrogen compression from near-atmospheric pressure to 12,800 psi and operation of EHC for more than 22,000 hours. Capital cost of EHC was reduced by 60%, enabling a path to meeting the DOE cost targets for hydrogen compression, storage and delivery ($2.00-2.15/gge by 2020).

Serving the fuel cycle: preparing tomorrow's packagings

International Nuclear Information System (INIS)

Roland, V.

2001-01-01

The main fleet of transport packagings serving today the fuel cycle was born more than 20 years ago. Or was it they? The present paper will show that serving the fuel cycle by preparing tomorrow's logistics is actually an on-going process, rather than a rupture. We shall review the great packagings of the fuel cycle: In the front end, the major actors are the UF 4 , UF 6 , enriched UF 6 , UO 2 powders, fresh fuel packagings. In the back end of the fuel cycle, we find the dry transport casks of the TN-12, TN-17, TN-13, family and also the Excellox wet flasks. In the waste management, a whole fleet of containers, culminating in the TN Gemini, are available or being created. (author)

Creating load for new hydrogen production

International Nuclear Information System (INIS)

Smith, R.

2006-01-01

This presentation provides an update of the activities of the Hydrogen Village. The Hydrogen Village is a public-private partnership of approximately 40 companies with the goal of advancing awareness of the environmental, economic and social benefits of hydrogen and fuel cell technologies. The intent of the hydrogen village is to create a sustainable commercial market for these technologies within the Greater Toronto Area and to help to catalyze such markets in other areas

"School of Tomorrow" kuulutati lindpriiks / Ülo Tikk ; kommenteerivad haridusministeeriumi peainspektorid Natalja Lapikova ja Kristi Mere

Index Scriptorium Estoniae

Tikk, Ülo, 1941-

2000-01-01

Ameerika inglise keele süvaõppeprogramm "School of Tomorrow", mille järgi õpetati Sillamäe, Jõhvi jt. Eesti venekeelsetes koolides, jäeti tunniplaanist välja, sest programm ei vasta Eestis kehtestatud riiklikule õppekavale

Collision cascades enhanced hydrogen redistribution in cobalt implanted hydrogenated diamond-like carbon films

International Nuclear Information System (INIS)

Gupta, P.; Becker, H.-W.; Williams, G.V.M.; Hübner, R.; Heinig, K.-H.; Markwitz, A.

2017-01-01

Highlights: • This paper reports for the first time redistribution of hydrogen atoms in diamond like carbon thin films during ion implantation of low energy magnetic ions. • The results point towards new routes of controlling the composition and distribution of elements at the nanoscale within a base matrix without using any heat treatment methods. • Exploring these opportunities can lead to a new horizon of materials and device engineering needed for enabling advanced technologies and applications. - Abstract: Hydrogenated diamond-like carbon films produced by C_3H_6 deposition at 5 kV and implanted at room temperature with 30 keV Co atoms to 12 at.% show not only a bimodal distribution of Co atoms but also a massive redistribution of hydrogen in the films. Resonant nuclear reaction analysis was used to measure the hydrogen depth profiles (15N-method). Depletion of hydrogen near the surface was measured to be as low as 7 at.% followed by hydrogen accumulation from 27 to 35 at.%. A model is proposed considering the thermal energy deposited by collision cascade for thermal insulators. In this model, sufficient energy is provided for dissociated hydrogen to diffuse out of the sample from the surface and diffuse into the sample towards the interface which is however limited by the range of the incoming Co ions. At a hydrogen concentration of ∼35 at.%, the concentration gradient of the mobile unbounded hydrogen atoms is neutralised effectively stopping diffusion towards the interface. The results point towards new routes of controlling the composition and distribution of elements at the nanoscale within a base matrix without using any heat treatment methods. Exploring these opportunities can lead to a new horizon of materials and device engineering needed for enabling advanced technologies and applications.

Collision cascades enhanced hydrogen redistribution in cobalt implanted hydrogenated diamond-like carbon films

Energy Technology Data Exchange (ETDEWEB)

Gupta, P. [National Isotope Centre, GNS Science, Lower Hutt (New Zealand); The MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, Wellington (New Zealand); Becker, H.-W. [RUBION, Ruhr-University Bochum (Germany); Williams, G.V.M. [The MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, Wellington (New Zealand); Hübner, R.; Heinig, K.-H. [Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (Germany); Markwitz, A., E-mail: a.markwitz@gns.cri.nz [National Isotope Centre, GNS Science, Lower Hutt (New Zealand); The MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, Wellington (New Zealand)

2017-03-01

Highlights: • This paper reports for the first time redistribution of hydrogen atoms in diamond like carbon thin films during ion implantation of low energy magnetic ions. • The results point towards new routes of controlling the composition and distribution of elements at the nanoscale within a base matrix without using any heat treatment methods. • Exploring these opportunities can lead to a new horizon of materials and device engineering needed for enabling advanced technologies and applications. - Abstract: Hydrogenated diamond-like carbon films produced by C{sub 3}H{sub 6} deposition at 5 kV and implanted at room temperature with 30 keV Co atoms to 12 at.% show not only a bimodal distribution of Co atoms but also a massive redistribution of hydrogen in the films. Resonant nuclear reaction analysis was used to measure the hydrogen depth profiles (15N-method). Depletion of hydrogen near the surface was measured to be as low as 7 at.% followed by hydrogen accumulation from 27 to 35 at.%. A model is proposed considering the thermal energy deposited by collision cascade for thermal insulators. In this model, sufficient energy is provided for dissociated hydrogen to diffuse out of the sample from the surface and diffuse into the sample towards the interface which is however limited by the range of the incoming Co ions. At a hydrogen concentration of ∼35 at.%, the concentration gradient of the mobile unbounded hydrogen atoms is neutralised effectively stopping diffusion towards the interface. The results point towards new routes of controlling the composition and distribution of elements at the nanoscale within a base matrix without using any heat treatment methods. Exploring these opportunities can lead to a new horizon of materials and device engineering needed for enabling advanced technologies and applications.

History Made for Tomorrow: Hakka Tulou

Directory of Open Access Journals (Sweden)

Richard M. Yelland

2013-11-01

Full Text Available The documentary film, History Made for Tomorrow: Hakka Tulou was an October 2010 release by History Channel International. This film is an in-depth study on the green building techniques and sustainable lifestyle of the Hakka people of Southern China with a focus on the ancient Tulou rammed earth structures. The television program follows West Virginia University research professor, Ruifeng Liang, as he initiates scientific studies to back claims that the rammed earth Tulou structures are “the greenest buildings in the world”, and Canadian architect, Jorg Ostrowski, of Autonomous Sustainable Housing Inc., who has been researching the ecological footprint of Hakka communities since August 2007, to promote them as “eco-villages” of best practices for planet Earth’s sustainability. The author is credited as Director, Writer, and Producer of this film. This paper is based on the script of the production.

Recent advances in SRS on hydrogen isotope separation using thermal cycling absorption process

Energy Technology Data Exchange (ETDEWEB)

Xiao, X.; Kit Heung, L.; Sessions, H.T. [Savannah River National Laboratory - SRNL, Aiken, SC (United States)

2015-03-15

TCAP (Thermal Cycling Absorption Process) is a gas chromatograph in principle using palladium in the column packing, but it is unique in the fact that the carrier gas, hydrogen, is being isotopically separated and the system is operated in a semi-continuous manner. TCAP units are used to purify tritium. The recent TCAP advances at Savannah River Site (SRS) include compressor-free concept for heating/cooling, push and pull separation using an active inverse column, and compact column design. The new developments allow significantly higher throughput and better reliability from 1/10 of the current production system's footprint while consuming 60% less energy. Various versions are derived in the meantime for external customers to be used in fusion energy projects.

Texaco, carbide form hydrogen plant venture

International Nuclear Information System (INIS)

Anon.

1992-01-01

This paper reports that Texaco Inc. and Union Carbide Industrial Gases Inc. (UCIG) have formed a joint venture to develop and operate hydrogen plants. The venture, named HydroGEN Supply Co., is owned by Texaco Hydrogen Inc., a wholly owned subsidiary of Texaco, and UCIG Hydrogen Services Inc., a wholly owned subsidiary of UCIG. Plants built by HydroGEN will combine Texaco's HyTEX technology for hydrogen production with UCIG's position in cryogenic and advanced air separation technology. Texaco the U.S. demand for hydrogen is expected to increase sharply during the next decade, while refinery hydrogen supply is expected to drop. The Clean Air Act amendments of 1990 require U.S. refiners to lower aromatics in gasoline, resulting in less hydrogen recovered by refiners from catalytic reforming units. Meanwhile, requirements to reduce sulfur in diesel fuel will require more hydrogen capacity

Enhancing the Pediatric Drug Development Framework to Deliver Better Pediatric Therapies Tomorrow.

Science.gov (United States)

Bucci-Rechtweg, Christina

2017-10-01

Health care professionals involved in the clinical management of children have long appreciated the limited number of therapies suitably evaluated for their optimal use in the pediatric population. In the past century, advances in regulatory policy significantly evolved adult drug evaluation. The scarcity of available patient populations, practical complexities of drug development research, and minimal financial returns have hampered pharmaceutical investment in the study of therapies for children. More recently, pediatric policy and legislation in the United States and Europe have instituted a system of obligations and incentives to stimulate investment in pediatric drug development. These initiatives, in conjunction with a more sophisticated process of drug discovery and development, have led to significant advancements in the labeling of drugs for pediatric use. Facilitated by the emergence of new targets, precision medicine, and innovations in regulatory science, there is now a subtle shift in focus toward drug development research for children rather than simply in children. Although there has been an increase in pediatric studies of investigational agents and labeling of pediatric information for use, there have been unintended consequences of existing policies. As a result, limited progress has been made in certain therapeutic areas and for off-patent therapies. Future policy reform to enhance the availability and accessibility of pediatric medicines should not only reflect an understanding not only of the successes of existing policy and legislative initiatives but also constructively address failures and unintended consequences. Taken together, policy reform, global cooperation, and innovation in regulatory science will more ably deliver better pediatric therapies tomorrow. Copyright © 2017 Elsevier HS Journals, Inc. All rights reserved.

Storage of hydrogen in advanced high pressure container. Final report for PSO projekt; Lagring af brint i avancerede hoejtryksbeholdere. Slutrapport for PSO-projekt

Energy Technology Data Exchange (ETDEWEB)

Christiansen, Jens

2006-04-15

The objective of the project has been to study barriers for a production of advanced high pressure containers especially suitable for hydrogen, in order to create a basis for a container production in Denmark. The project has primarily focused on future Danish need for hydrogen storage in the MWh area. One task has been to examine requirement specifications for pressure tanks that can be expected in connection with these stores. Six potential storage needs have been identified: (1) Buffer in connection with start-up/regulation on the power grid. (2) Hydrogen and oxygen production. (3) Buffer store in connection with VEnzin vision. (4) Storage tanks on hydrogen filling stations. (5) Hydrogen for the transport sector from 1 TWh surplus power. (6) Tanker transport of hydrogen. Requirements for pressure containers for the above mentioned use have been examined. The connection between stored energy amount, pressure and volume compared to liquid hydrogen and oil has been stated in tables. As starting point for production technological considerations and economic calculations of various container concepts, an estimation of laminate thickness in glass-fibre reinforced containers with different diameters and design print has been made, for a 'pure' fibre composite container and a metal/fibre composite container respectively. (BA)

Training Tomorrow's Nuclear Workforce

International Nuclear Information System (INIS)

2013-01-01

Training tomorrow's Nuclear Workforce Start with the children. That is the message Brian Molloy, a human resources expert in the IAEA's Nuclear Power Engineering Section, wants to convey to any country considering launching or expanding a nuclear power programme. Mathematics and science curricular and extra-curricular activities at secondary and even primary schools are of crucial importance to future recruiting efforts at nuclear power plants, he says:''You need to interest children in science and physics and engineering. The teaching needs to be robust enough to teach them, but it must also gain their interest.'' Recruiting high-calibre engineers needed for the operation of nuclear power plants is a growing challenge, even for existing nuclear power programmes, because of a wave of retirements combined with increasing global demand. But essential as engineers are, they are only a component of the staff at any nuclear power plant. In fact, most employees at nuclear power plants are not university graduates - they are skilled technicians, electricians, welders, fitters, riggers and people in similar trades. Molloy argues that this part of the workforce needs more focus. ''It's about getting a balance between focusing on the academic and the skilled vocational'', he says, adding that countries considering nuclear power programmes often initially place undue focus on nuclear engineers.

Hydrogen storage technology materials and applications

CERN Document Server

Klebanoff, Lennie

2012-01-01

Zero-carbon, hydrogen-based power technology offers the most promising long-term solution for a secure and sustainable energy infrastructure. With contributions from the world's leading technical experts in the field, Hydrogen Storage Technology: Materials and Applications presents a broad yet unified account of the various materials science, physics, and engineering aspects involved in storing hydrogen gas so that it can be used to provide power. The book helps you understand advanced hydrogen storage materials and how to build systems around them. Accessible to nonscientists, the first chapt

Hydrogen economy: a little bit more effort

International Nuclear Information System (INIS)

Pauron, M.

2008-01-01

In few years, the use of hydrogen in economy has become a credible possibility. Today, billions of euros are invested in the hydrogen industry which is strengthened by technological advances in fuel cells development and by an increasing optimism. However, additional research efforts and more financing will be necessary to make the dream of an hydrogen-based economy a reality

Hydrogen energy stations: along the roadside to the hydrogen economy

International Nuclear Information System (INIS)

Clark, W.W.; Rifkin, J.; O'Connor, T.; Swisher, J.; Lipman, T.; Rambach, G.

2005-01-01

Hydrogen has become more than an international topic of discussion within government and among industry. With the public announcements from the European Union and American governments and an Executive Order from the Governor of California, hydrogen has become a ''paradigm change'' targeted toward changing decades of economic and societal behaviours. The public demand for clean and green energy as well as being ''independent'' or not located in political or societal conflict areas, has become paramount. The key issues are the commitment of governments through public policies along with corporations. Above all, secondly, the advancement of hydrogen is regional as it depends upon infrastructure and fuel resources. Hence, the hydrogen economy, to which the hydrogen highway is the main component, will be regional and creative. New jobs, businesses and opportunities are already emerging. And finally, the costs for the hydrogen economy are critical. The debate as to hydrogen being 5 years away from being commercial and available in the marketplace versus needing more research and development contradicts the historical development and deployment of any new technology be it bio-science, flat panel displays, computers or mobile phones. The market drivers are government regulations and standards soon thereafter matched by market forces and mass production. Hydrogen is no different. What this paper does is describes is how the hydrogen highway is the backbone to the hydrogen economy by becoming, with the next five years, both regional and commercial through supplying stationary power to communities. Soon thereafter, within five to ten years, these same hydrogen stations will be serving hundreds and then thousands of hydrogen fuel powered vehicles. Hydrogen is the fuel for distributed energy generation and hence positively impacts the future of public and private power generators. The paradigm has already changed. (author)

NATO Advanced Study Institute on Hydrogen in Disordered and Amorphous Solids

CERN Document Server

Bowman, Robert

1986-01-01

This is the second volume in the NATO ASI series dealing with the topic of hydrogen in solids. The first (V. B76, Metal Hydrides) appeared five years ago and focussed primarily on crystalline phases of hydrided metallic systems. In the intervening period, the amorphous solid state has become an area of intense research activity, encompassing both metallic and non-metallic, e.g. semiconducting, systems. At the same time the problem of storage of hydrogen, which motivated the first ASI, continues to be important. In the case of metallic systems, there were early indications that metallic glasses and disordered alloys may be more corrosion resistant, less susceptible to embrittlement by hydrogen and have a higher hydrogen mobility than ordered metals or intermetallics. All of these properties are desirable for hydrogen storage. Subsequent research has shown that thermodynamic instability is a severe problem in many amorphous metal hydrides. The present ASI has provided an appropriate forum to focus on these issu...

Recent advances in visible-light-responsive photocatalysts for hydrogen production and solar energy conversion--from semiconducting TiO2 to MOF/PCP photocatalysts.

Science.gov (United States)

Horiuchi, Yu; Toyao, Takashi; Takeuchi, Masato; Matsuoka, Masaya; Anpo, Masakazu

2013-08-28

The present perspective describes recent advances in visible-light-responsive photocatalysts intended to develop novel and efficient solar energy conversion technologies, including water splitting and photofuel cells. Water splitting is recognized as one of the most promising techniques to convert solar energy as a clean and abundant energy resource into chemical energy in the form of hydrogen. In recent years, increasing concern is directed to not only the development of new photocatalytic materials but also the importance of technologies to produce hydrogen and oxygen separately. Photofuel cells can convert solar energy into electrical energy by decomposing bio-related compounds and livestock waste as fuels. The advances of photocatalysts enabling these solar energy conversion technologies have been going on since the discovery of semiconducting titanium dioxide materials and have extended to organic-inorganic hybrid materials, such as metal-organic frameworks and porous coordination polymers (MOF/PCP).

New advances in hydrogen production via the catalytic decomposition of wax by-products using nanoparticles of SBA frame-worked MoO_3

International Nuclear Information System (INIS)

El Naggar, Ahmed M.A.; Gobara, Heba M.; El Sayed, Hussien A.; Soliman, Fathi S.

2015-01-01

Graphical abstract: Feedstock-to-gases & hydrogen conversion using the Mo-SBA15 catalyst compared to commercial catalysts. - Highlights: • Synthesis of meso-porous molybdenum oxide catalyst in SBA framework. • Confirming the structural characteristics of this catalyst by different analyses. • New trend for the H_2 & CH_4, production is revealed in this work. • Nano-carbon species of well-ordered structure was produced. • In-situ non-pressurized-low temperature wax isomerization was imposed. - Abstract: The alternative energy sources in general and hydrogen based energy in particular have been currently grabbing great attention. Hydrogen is an efficient green source for power generation owing to its huge energy content. The operational costs and the hydrogen output are the key factors in the selection of a certain technique for the hydrogen production industrially. This study summarizes a new route for hydrogen production starting from a bit complicated hydrogen-containing molecules. Particular attention is given during this work towards a direct pyrrolysis catalytic conversion of long chains n-paraffin into hydrogen with in-situ production of nano-structured carbon particles. The simultaneous isomerization of the n-paraffin contented in the feedstock is also discussed during this process. This research study had provided new advances in the hydrogen production based on carrying out the production process at non-severe conditions namely; low operational temperatures and no pressure was applied. The introduction of a meso-porous molybdenum oxide catalyst for the catalytic hydrogen production is also a point of novelty for the presented work. Promising results have been disclosed at the end of this investigation; approximately 60 wt.% of the feedstock was converted to fuel gases while nearly 30 wt.% of the feed had turned as nano-carbon species. The hydrogen productivity had been detected as high as 42 wt.% of the original feedstock. This in fact might

FY 2007 Progress Report for Advanced Combustion Engine Technologies

Energy Technology Data Exchange (ETDEWEB)

None, None

2007-12-01

Advanced combustion engines have great potential for achieving dramatic energy efficiency improvements in light-duty vehicle applications, where it is suited to both conventional and hybrid- electric powertrain configurations. Light-duty vehicles with advanced combustion engines can compete directly with gasoline engine hybrid vehicles in terms of fuel economy and consumer-friendly driving characteristics; also, they are projected to have energy efficiencies that are competitive with hydrogen fuel cell vehicles when used in hybrid applications.Advanced engine technologies being researched and developed by the Advanced Combustion Engine R&D Sub-Program will also allow the use of hydrogen as a fuel in ICEs and will provide an energy-efficient interim hydrogen-based powertrain technology during the transition to hydrogen/fuelcell-powered transportation vehicles.

Hydrogen Filling Station

Energy Technology Data Exchange (ETDEWEB)

Boehm, Robert F; Sabacky, Bruce; Anderson II, Everett B; Haberman, David; Al-Hassin, Mowafak; He, Xiaoming; Morriseau, Brian

2010-02-24

Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. The Freedom CAR and Freedom FUEL initiatives emphasize the importance of hydrogen as a future transportation fuel. Presently, Las Vegas has one hydrogen fueling station powered by natural gas. However, the use of traditional sources of energy to produce hydrogen does not maximize the benefit. The hydrogen fueling station developed under this grant used electrolysis units and solar energy to produce hydrogen fuel. Water and electricity are furnished to the unit and the output is hydrogen and oxygen. Three vehicles were converted to utilize the hydrogen produced at the station. The vehicles were all equipped with different types of technologies. The vehicles were used in the day-to-day operation of the Las Vegas Valley Water District and monitoring was performed on efficiency, reliability and maintenance requirements. The research and demonstration utilized for the reconfiguration of these vehicles could lead to new technologies in vehicle development that could make hydrogen-fueled vehicles more cost effective, economical, efficient and more widely used. In order to advance the development of a hydrogen future in Southern Nevada, project partners recognized a need to bring various entities involved in hydrogen development and deployment together as a means of sharing knowledge and eliminating duplication of efforts. A road-mapping session was held in Las Vegas in June 2006. The Nevada State Energy Office, representatives from DOE, DOE contractors and LANL, NETL, NREL were present. Leadership from the National hydrogen Association Board of Directors also attended. As a result of this session, a roadmap for hydrogen development was created. This roadmap has the ability to become a tool for use by other road-mapping efforts in the hydrogen community. It could also become a standard template for other states or even countries to approach planning for a hydrogen

NRCan's hydrogen storage R and D program

International Nuclear Information System (INIS)

Scepanovic, V.

2004-01-01

'Full text:' Natural Resources Canada (NRCan) has been working in partnership with industry, other government departments and academia to expedite the development of hydrogen technologies. NRCan's Hydrogen and Fuel Cell R and D Program covers all aspects of hydrogen technologies: production, storage, utilization and codes and standards. Hydrogen storage is a key enabling technology for the advancement of fuel cell power systems in transportation, stationary, and portable applications. NRCan's storage program has been focused on developing storage materials and technologies for a range of applications with the emphasis on transportation. An overview of most recent hydrogen storage projects including pressurized hydrogen, liquid hydrogen and storage in hydrides and carbon-based materials will be given. (author)

HTTR workshop (workshop on hydrogen production technology)

International Nuclear Information System (INIS)

Shiina, Yasuaki; Takizuka, Takakazu

2004-12-01

Various research and development efforts have been performed to solve the global energy and environmental problems caused by large consumption of fossil fuels. Research activities on advanced hydrogen production technology by the use of nuclear heat from high temperature gas cooled reactors, for example, have been flourished in universities, research institutes and companies in many countries. The Department of HTTR Project and the Department of Advanced Nuclear Heat Technology of JAERI held the HTTR Workshop (Workshop on Hydrogen Production Technology) on July 5 and 6, 2004 to grasp the present status of R and D about the technology of HTGR and the nuclear hydrogen production in the world and to discuss about necessity of the nuclear hydrogen production and technical problems for the future development of the technology. More than 110 participants attended the Workshop including foreign participants from USA, France, Korea, Germany, Canada and United Kingdom. In the Workshop, the presentations were made on such topics as R and D programs for nuclear energy and hydrogen production technologies by thermo-chemical or other processes. Also, the possibility of the nuclear hydrogen production in the future society was discussed. The workshop showed that the R and D for the hydrogen production by the thermo-chemical process has been performed in many countries. The workshop affirmed that nuclear hydrogen production could be one of the competitive supplier of hydrogen in the future. The second HTTR Workshop will be held in the autumn next year. (author)

Design, methods and demographics from phase I of Alberta's Tomorrow Project cohort: a prospective cohort profile.

Science.gov (United States)

Robson, Paula J; Solbak, Nathan M; Haig, Tiffany R; Whelan, Heather K; Vena, Jennifer E; Akawung, Alianu K; Rosner, William K; Brenner, Darren R; Cook, Linda S; Csizmadi, Ilona; Kopciuk, Karen A; McGregor, S Elizabeth; Friedenreich, Christine M

2016-01-01

Prospective cohorts have the potential to support multifactorial, health-related research, particularly if they are drawn from the general population, incorporate active and passive follow-up and permission is obtained to allow access by researchers to data repositories. This paper describes Phase I of the Alberta's Tomorrow Project cohort, a broad-based research platform designed to support investigations into factors that influence cancer and chronic disease risk. Adults aged 35-69 years living in Alberta, Canada, with no previous cancer diagnosis other than nonmelanoma skin cancer were recruited to the project by telephone-based random digit dialling. Participants were enrolled if they returned a Health and Lifestyle Questionnaire. Past year diet and physical activity questionnaires were mailed 3 months after enrolment. Consent was sought for active follow-up and linkage with administrative databases. Depending on enrolment date, participants were invited to complete up to 2 follow-up questionnaires (2004 and 2008). Between 2001 and 2009, 31 072 (39% men) participants (mean age 50.2 [± 9.2] yr) were enrolled and 99% consented to linkage with administrative databases. Participants reported a wide range of educational attainment and household income. Compared with provincial surveillance data from the Canadian Community Health Survey, Alberta's Tomorrow Project participants had higher body mass index, lower prevalence of smoking and similar distribution of chronic health conditions. Follow-up questionnaires were completed by 83% and 72% of participants in 2004 and 2008, respectively. Robust quality control measures resulted in low frequencies of missing data. Alberta's Tomorrow Project provides a robust platform, based on a prospective cohort design, to support research into risk factors for cancer and chronic disease.

Advanced Therapeutic Gastrointestinal Endoscopy in Children – Today and Tomorrow

Directory of Open Access Journals (Sweden)

Zaheer Nabi

2018-03-01

Full Text Available Gastrointestinal (GI endoscopy plays an indispensable role in the diagnosis and management of various pediatric GI disorders. While the pace of development of pediatric GI endoscopy has increased over the years, it remains sluggish compared to the advancements in GI endoscopic interventions available in adults. The predominant reasons that explain this observation include lack of formal training courses in advanced pediatric GI interventions, economic constraints in establishing a pediatric endoscopy unit, and unavailability of pediatric-specific devices and accessories. However, the situation is changing and more pediatric GI specialists are now performing complex GI procedures such as endoscopic retrograde cholangiopancreatography and endoscopic ultrasonography for various pancreatico-biliary diseases and more recently, per-oral endoscopic myotomy for achalasia cardia. Endoscopic procedures are associated with reduced morbidity and mortality compared to open surgery for GI disorders. Notable examples include chronic pancreatitis, pancreatic fluid collections, various biliary diseases, and achalasia cardia for which previously open surgery was the treatment modality of choice. A solid body of evidence supports the safety and efficacy of endoscopic management in adults. However, additions continue to be made to literature describing the pediatric population. An important consideration in children includes size of children, which in turn determines the selection of endoscopes and type of sedation that can be used for the procedure.

Impact of hydrogen onboard storage technologies on the performance of hydrogen fuelled vehicles: A techno-economic well-to-wheel assessment

NARCIS (Netherlands)

de Wit, M.P.; Faaij, A.P.C.

2007-01-01

Hydrogen onboard storage technologies form an important factor in the overall performance of hydrogen fuelled transportation, both energetically and economically. Particularly, advanced storage options such as metal hydrides and carbon nanotubes are often hinted favourable to conventional, liquid

Technology Development of an Advanced Small-scale Microchannel-type Process Heat Exchanger (PHE) for Hydrogen Production in Iodine-sulfur Cycle

Energy Technology Data Exchange (ETDEWEB)

Sah, Injin; Kim, Chan Soo; Kim, Yong Wan; Park, Jae-Won; Kim, Eung-Seon; Kim, Min-Hwan [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2015-10-15

In this study, ongoing manufacturing processes of the components employed in an advanced small-scale microchannel-type PHE are presented. The components, such as mechanically machined microchannels and a diffusion-bonded stack are introduced. Also, preliminary studies on surface treatment techniques for improving corrosion resistance from the corrosive sulfuric environment will be covered. Ongoing manufacturing process for an advanced small-size microchannel-type PHE in KAERI is presented. Through the preliminary studies for optimizing diffusion bonding condition of Hastelloy-X, a diffusion-bonded stack, consisting of primary and secondary side layer by layer, is scheduled to be fabricated in a few months. Also, surface treatment for enhancing the corrosion resistance from the sulfuric acid environment is in progress for the plates with microchannels. A massive production of hydrogen with electricity generation is expected in a Process Heat Exchanger (PHE) in a Very High Temperature gas-cooled Reactor (VHTR) system. For the application of hydrogen production, a small-scale gas loop for feasibility testing of a laboratory-scale has constructed and operated in Korea Atomic Energy Research Institute (KAERI) as a precursor to an experimental- and a pilot-scale gas loops.

Hydrogen fueling stations in Japan hydrogen and fuel cell demonstration project

International Nuclear Information System (INIS)

Koseki, K.; Tomuro, J.; Sato, H.; Maruyama, S.

2004-01-01

A new national demonstration project of fuel cell vehicles, which is called Japan Hydrogen and Fuel Cell Demonstration Project (JHFC Project), has started in FY2002 on a four-year plan. In this new project, ten hydrogen fueling stations have been constructed in Tokyo and Kanagawa area in FY2002-2003. The ten stations adopt the following different types of fuel and fueling methods: LPG reforming, methanol reforming, naphtha reforming, desulfurized-gasoline reforming, kerosene reforming, natural gas reforming, water electrolysis, liquid hydrogen, by-product hydrogen, and commercially available cylinder hydrogen. Approximately fifty fuel cell passenger cars and a fuel cell bus are running on public roads using these stations. In addition, two hydrogen stations will be constructed in FY2004 in Aichi prefecture where The 2005 World Exposition (EXPO 2005) will be held. The stations will service eight fuel cell buses used as pick-up buses for visitors. We, Engineering Advancement Association of Japan (ENAA), are commissioned to construct and operate a total of twelve stations by Ministry of Economy Trade and Industry (METI). We are executing to demonstrate or identify the energy-saving effect, reduction of the environmental footprint, and issues for facilitating the acceptance of hydrogen stations on the basis of the data obtained from the operation of the stations. (author)

Modeling and analysis of hydrogen detonation events in the Advanced Neutron Source reactor containment

International Nuclear Information System (INIS)

Taleyarkhan, R.P.; Georgevich, V.; Kim, S.H.; Valenti, S.N.; Simpson, D.B.; Sawruk, W.

1994-07-01

This paper describes salient aspects of the modeling, analyses, and evaluations for hydrogen detonation in selected regions of the Advanced Neutron Source (ANS) containment during hypothetical severe accident conditions. Shock wave generation and transport modeling and analyses were conducted for two stratified configurations in the dome region of the high bay. Principal tools utilized for these purposes were the CTH and CET89 computer codes. Dynamic pressure loading functions were generated for key locations and used for evaluating structural response behavior for which a finite-element model was developed using the ANSYS code. For the range of conditions analyzed in the two critical dome regions, it was revealed that the ANS containment would be able to withstand detonation loads without failure

Modeling and analysis of hydrogen detonation events in the advanced neutron source reactor containment

International Nuclear Information System (INIS)

Taleyarkhan, R.P.; Georgevich, V.; Kim, S.H.; Valenti, S.; Simpson, D.B.; Sawruk, W.

1994-01-01

This paper describes salient aspects of the modeling, analyses, and evaluations for hydrogen detonation in selected regions of the Advanced Neutron Source (ANS) containment during hypothetical severe accident conditions. Shock wave generation and transport modeling and analyses were conducted for two stratified configurations in the dome region of the high bay. Principal tools utilized for these purposes were the CTH and CET89 computer codes. Dynamic pressure loading functions were generated for key locations and used for evaluating structural response behavior for which a finite-element model was developed using the ANSYS code. For the range of conditions analyzed in the two critical dome regions, it was revealed that the ANS containment would be able to withstand detonation loads without failure. (author)

Cities of tomorrow: low energy cities with a high quality of life for all

International Nuclear Information System (INIS)

Magnin, Gerard

2010-11-01

Just as hard as describing the city of today, describing the city of tomorrow represents a real challenge. Energy Cities is active at both local and European levels, therefore we will only address the European-type cities in our reflection. Central to the vision of Energy Cities is of course the (sustainable and livable) energy issue. Therefore, our starting point is the consideration of energy issue as an essential component of urban and regional development as well as an excellent scanner of how the city and its periphery/region are organised. In 2050, cities will not look that much different than those of the beginning of the century. However, a lot of invisible radical changes will have occurred. These changes are already underway in an increasing number of cities, especially some which are committed with the Covenant of Mayors. These are 'weak signals' that pave the way for tomorrow. This paper aims at understanding these logics and at showing up paths of improvement in the domains of energy supply, urban form, buildings, mobility, public space, economy, consumption, governance, local authorities, multilevel governance and Territorial cohesion, quality of Life, peace and security

Development of advanced manufacturing technologies for low cost hydrogen storage vessels

Energy Technology Data Exchange (ETDEWEB)

Leavitt, Mark [Quantum Fuel Systems Technologies Worldwide, Inc., Irvine, CA (United States); Lam, Patrick [Boeing Research and Technology (BR& T), Seattle, WA (United States)

2014-12-29

The U.S. Department of Energy (DOE) defined a need for low-cost gaseous hydrogen storage vessels at 700 bar to support cost goals aimed at 500,000 units per year. Existing filament winding processes produce a pressure vessel that is structurally inefficient, requiring more carbon fiber for manufacturing reasons, than would otherwise be necessary. Carbon fiber is the greatest cost driver in building a hydrogen pressure vessel. The objective of this project is to develop new methods for manufacturing Type IV pressure vessels for hydrogen storage with the purpose of lowering the overall product cost through an innovative hybrid process of optimizing composite usage by combining traditional filament winding (FW) and advanced fiber placement (AFP) techniques. A numbers of vessels were manufactured in this project. The latest vessel design passed all the critical tests on the hybrid design per European Commission (EC) 79-2009 standard except the extreme temperature cycle test. The tests passed include burst test, cycle test, accelerated stress rupture test and drop test. It was discovered the location where AFP and FW overlap for load transfer could be weakened during hydraulic cycling at 85°C. To design a vessel that passed these tests, the in-house modeling software was updated to add capability to start and stop fiber layers to simulate the AFP process. The original in-house software was developed for filament winding only. Alternative fiber was also investigated in this project, but the added mass impacted the vessel cost negatively due to the lower performance from the alternative fiber. Overall the project was a success to show the hybrid design is a viable solution to reduce fiber usage, thus driving down the cost of fuel storage vessels. Based on DOE’s baseline vessel size of 147.3L and 91kg, the 129L vessel (scaled to DOE baseline) in this project shows a 32% composite savings and 20% cost savings when comparing Vessel 15 hybrid design and the Quantum

Taking Sides: Ethics, Politics and Fieldwork in Anthropology & All Tomorrow's Cultures: Anthropological Engagements with the Future

Directory of Open Access Journals (Sweden)

Aimar Ventsel

2011-12-01

Full Text Available Review of the publications Taking Sides: Ethics, Politics and Fieldwork in Anthropology. Edited by Heidi Armbruster and Anna Lærke. New York, Oxford: Berghahn Books 2008, 258 pages; and Samuel Gerald Collins, All Tomorrow's Cultures: Anthropological Engagements with the Future. New York, Oxford: Berghahn Books 2008, 140 pages.

Taking Sides: Ethics, Politics and Fieldwork in Anthropology & All Tomorrow's Cultures: Anthropological Engagements with the Future

Directory of Open Access Journals (Sweden)

Aimar Ventsel

2012-10-01

Full Text Available Review of the publications Taking Sides: Ethics, Politics and Fieldwork in Anthropology. Edited by Heidi Armbruster and Anna Lærke. New York, Oxford: Berghahn Books 2008, 258 pages; and Samuel Gerald Collins, All Tomorrow's Cultures: Anthropological Engagements with the Future. New York, Oxford: Berghahn Books 2008, 140 pages.

Primary energy sources for hydrogen production

International Nuclear Information System (INIS)

Hassmann, K.; Kuehne, H.-M.

1993-01-01

The cost of hydrogen from water electrolysis is estimated, assuming that the electricity was produced from solar, hydro-, fossil, or nuclear power. The costs for hydrogen end-use in the sectors of power generation, heat and transportation are calculated, based on a state-of-the-art technology and a more advanced technology expected to represent the state by the year 2010. The cost of hydrogen utilization (without energy taxes) is higher than the current price of fossil fuels (including taxes). Without restrictions imposed on fossil fuel consumption, hydrogen will not gain a significant market share in either of the cases discussed. (Author)

They invent tomorrow's nuclear technologies

International Nuclear Information System (INIS)

Hurel, T.; Le Ngoc, B.

2017-01-01

3 leaders working in the nuclear industry for 3 different French entities: AREVA, EDF and CEA detail the role of innovation for tomorrow's nuclear energy. For AREVA, innovation is the response to the 4 challenges facing nuclear industry: improving the current business models, getting more modern and reliable plants, anticipating customers' wishes, and luring new young talents to ensure the future of the nuclear industry. As for EDF, innovation is the tool that will make nuclear energy absolutely necessary to counter-balance the intermittency of most renewable energies. EDF sees 3 main challenges to overcome: reactor safety, load following and developing a broader offer of reactors including small and modular reactors. For CEA, it is necessary to get a broad view of new nuclear systems and the nature of innovations can be very varied and for instance it can focus on a particular spot like fuel cladding or metal corrosion or on a complete new type of reactor. Innovation should also lead towards more predictive simulations. In all cases nuclear industry requires a better public financing for accelerating the implementation of innovations. (A.C.)

ORGANIZATIONS AND MANAGERS OF TOMORROW

Directory of Open Access Journals (Sweden)

ROMANESCU MARCEL LAURENTIU

2011-03-01

Full Text Available It explores a comparison between the transition from rational manager to intuitively manager so that the speed on which complexity increases is greater than the speed of developing our ability to manipulate facts and objective information. The qualities and characteristics of future manager specific that no doubt the new profile manager will change, because he will need to adapt to changing market needs, managers will begin to invest in themselves. Innovations can only come from people with a strong entrepreneurial and intuitive spirit. Characteristics of tomorrow's organizations states that the need to organize, for change, requires achieving a structure in order to take decisions quickly. And the decisions must be based on approximation of current activity, market, technology and all the changes in society, in environment, those related to population and knowledge providing opportunities for innovation, if they are seen and valued. In this world, which increasingly focuses more on knowledge, not have time to gradually acquire knowledge and ideas, and the application of knowledge on geographically area is intensifying, acquisition, synthesis and systematic dissemination of knowledge and experience are becoming essential for many organizations’ success.

LARGE-SCALE PRODUCTION OF HYDROGEN BY NUCLEAR ENERGY FOR THE HYDROGEN ECONOMY

International Nuclear Information System (INIS)

SCHULTZ, K.R.; BROWN, L.C.; BESENBRUCH, G.E.; HAMILTON, C.J.

2003-01-01

OAK B202 LARGE-SCALE PRODUCTION OF HYDROGEN BY NUCLEAR ENERGY FOR THE HYDROGEN ECONOMY. The ''Hydrogen Economy'' will reduce petroleum imports and greenhouse gas emissions. However, current commercial hydrogen production processes use fossil fuels and releases carbon dioxide. Hydrogen produced from nuclear energy could avoid these concerns. The authors have recently completed a three-year project for the US Department of Energy whose objective was to ''define an economically feasible concept for production of hydrogen, by nuclear means, using an advanced high-temperature nuclear reactor as the energy source''. Thermochemical water-splitting, a chemical process that accomplishes the decomposition of water into hydrogen and oxygen, met this objective. The goal of the first phase of this study was to evaluate thermochemical processes which offer the potential for efficient, cost-effective, large-scale production of hydrogen and to select one for further detailed consideration. The authors selected the Sulfur-Iodine cycle, In the second phase, they reviewed all the basic reactor types for suitability to provide the high temperature heat needed by the selected thermochemical water splitting cycle and chose the helium gas-cooled reactor. In the third phase they designed the chemical flowsheet for the thermochemical process and estimated the efficiency and cost of the process and the projected cost of producing hydrogen. These results are summarized in this paper

Hydrogen and Hydrogen/Natural Gas Station and Vehicle Operations - 2006 Summary Report

Energy Technology Data Exchange (ETDEWEB)

Francfort; Donald Karner; Roberta Brayer

2006-09-01

This report is a summary of the operations and testing of internal combustion engine vehicles that were fueled with 100% hydrogen and various blends of hydrogen and compressed natural gas (HCNG). It summarizes the operations of the Arizona Public Service Alternative Fuel Pilot Plant, which produces, compresses, and dispenses hydrogen fuel. Other testing activities, such as the destructive testing of a CNG storage cylinder that was used for HCNG storage, are also discussed. This report highlights some of the latest technology developments in the use of 100% hydrogen fuels in internal combustion engine vehicles. Reports are referenced and WWW locations noted as a guide for the reader that desires more detailed information. These activities are conducted by Arizona Public Service, Electric Transportation Applications, the Idaho National Laboratory, and the U.S. Department of Energy’s Advanced Vehicle Testing Activity.

Assessment of hydrogen risk using advanced methodology for lumped parameter code-MELCOR

International Nuclear Information System (INIS)

Duspiva, Jiri; Kujal, Bohumir

2007-01-01

The hydrogen risk is one of the most important containment integrity challenge during a severe accident progression at the VVER type reactors installed at the Czech NPPs. On the basis of recent comprehensive research results the general flame acceleration (FA) and deflagration-to-detonation transition (DDT) criteria were formulated. The main objective of the new methodology developed in the NRI Rez was to prepare an analytical tool for the assessment of the hydrogen risk at the Czech NPPs in the course of a severe accident and also for the design of hydrogen removal system which should be able to prevent or at least minimize the threats of hydrogen detonation in containments. The major idea on which the development of models for the FA and DDT criteria was based is described in OECD state-of-art report (NEA, 2000). The module for the computation of FA criterion (often named σ-criterion) and DDT one (also named λ or Dorofeev criterion) was linked to the MELCOR 1.8.5 model of VVER-1000 containment. The most important feature of new model is that it makes possible to evaluate the both of the criteria for all compartments in the containment continuously during severe accident scenario progression. The containment model, which could be used for such a calculation, has to be very detailed owing to appropriate description of hydrogen distribution. New model was tested by calculation of hydrogen detonation risk in the VVER-1000 containment during severe accident scenario initiated by medium break LOCA. At present two more VVER-1000 severe accident scenarios have been analyzed. The mapping of a hydrogen detonation risk in individual compartments inside containment was performed. The results of analysis confirm that the risk of hydrogen detonation in the great majority of containment compartments during severe accidents is very high if the hydrogen removal system is not installed. (author)

Experimental characterization of the Advanced Liquid Hydrogen Cold Neutron Source spectrum of the NBSR reactor at the NIST Center for Neutron Research

Science.gov (United States)

Cook, J. C.; Barker, J. G.; Rowe, J. M.; Williams, R. E.; Gagnon, C.; Lindstrom, R. M.; Ibberson, R. M.; Neumann, D. A.

2015-08-01

The recent expansion of the National Institute of Standards and Technology (NIST) Center for Neutron Research facility has offered a rare opportunity to perform an accurate measurement of the cold neutron spectrum at the exit of a newly-installed neutron guide. Using a combination of a neutron time-of-flight measurement, a gold foil activation measurement, and Monte Carlo simulation of the neutron guide transmission, we obtain the most reliable experimental characterization of the Advanced Liquid Hydrogen Cold Neutron Source brightness to date. Time-of-flight measurements were performed at three distinct fuel burnup intervals, including one immediately following reactor startup. Prior to the latter measurement, the hydrogen was maintained in a liquefied state for an extended period in an attempt to observe an initial radiation-induced increase of the ortho (o)-hydrogen fraction. Since para (p)-hydrogen has a small scattering cross-section for neutron energies below 15 meV (neutron wavelengths greater than about 2.3 Å), changes in the o- p hydrogen ratio and in the void distribution in the boiling hydrogen influence the spectral distribution. The nature of such changes is simulated with a continuous-energy, Monte Carlo radiation-transport code using 20 K o and p hydrogen scattering kernels and an estimated hydrogen density distribution derived from an analysis of localized heat loads. A comparison of the transport calculations with the mean brightness function resulting from the three measurements suggests an overall o- p ratio of about 17.5(±1) % o- 82.5% p for neutron energies<15 meV, a significantly lower ortho concentration than previously assumed.

Experimental characterization of the Advanced Liquid Hydrogen Cold Neutron Source spectrum of the NBSR reactor at the NIST Center for Neutron Research

Energy Technology Data Exchange (ETDEWEB)

Cook, J.C.; Barker, J.G.; Rowe, J.M.; Williams, R.E. [NIST Center for Neutron Research, National Institute of Standards and Technology, 100 Bureau Drive, Mail Stop 6100, Gaithersburg, MD 20899-6100 (United States); Gagnon, C. [Department of Materials Science and Engineering, University of Maryland, College Park, MD 20742 (United States); Lindstrom, R.M. [Scientist Emeritus, Chemical Sciences Division, National Institute of Standards and Technology, 100 Bureau Drive, Mail Stop 8395, Gaithersburg, MD 20899-8395 (United States); Ibberson, R.M.; Neumann, D.A. [NIST Center for Neutron Research, National Institute of Standards and Technology, 100 Bureau Drive, Mail Stop 6100, Gaithersburg, MD 20899-6100 (United States)

2015-08-21

The recent expansion of the National Institute of Standards and Technology (NIST) Center for Neutron Research facility has offered a rare opportunity to perform an accurate measurement of the cold neutron spectrum at the exit of a newly-installed neutron guide. Using a combination of a neutron time-of-flight measurement, a gold foil activation measurement, and Monte Carlo simulation of the neutron guide transmission, we obtain the most reliable experimental characterization of the Advanced Liquid Hydrogen Cold Neutron Source brightness to date. Time-of-flight measurements were performed at three distinct fuel burnup intervals, including one immediately following reactor startup. Prior to the latter measurement, the hydrogen was maintained in a liquefied state for an extended period in an attempt to observe an initial radiation-induced increase of the ortho (o)-hydrogen fraction. Since para (p)-hydrogen has a small scattering cross-section for neutron energies below 15 meV (neutron wavelengths greater than about 2.3 Å), changes in the o- p hydrogen ratio and in the void distribution in the boiling hydrogen influence the spectral distribution. The nature of such changes is simulated with a continuous-energy, Monte Carlo radiation-transport code using 20 K o and p hydrogen scattering kernels and an estimated hydrogen density distribution derived from an analysis of localized heat loads. A comparison of the transport calculations with the mean brightness function resulting from the three measurements suggests an overall o- p ratio of about 17.5(±1) % o- 82.5% p for neutron energies<15 meV, a significantly lower ortho concentration than previously assumed.

Advanced Electrochemical Technologies for Hydrogen Production by Alternative Thermochemical Cycles

Energy Technology Data Exchange (ETDEWEB)

Lvov, Serguei; Chung, Mike; Fedkin, Mark; Lewis, Michele; Balashov, Victor; Chalkova, Elena; Akinfiev, Nikolay; Stork, Carol; Davis, Thomas; Gadala-Maria, Francis; Stanford, Thomas; Weidner, John; Law, Victor; Prindle, John

2011-01-06

Hydrogen fuel is a potentially major solution to the problem of climate change, as well as addressing urban air pollution issues. But a key future challenge for hydrogen as a clean energy carrier is a sustainable, low-cost method of producing it in large capacities. Most of the world's hydrogen is currently derived from fossil fuels through some type of reforming processes. Nuclear hydrogen production is an emerging and promising alternative to the reforming processes for carbon-free hydrogen production in the future. This report presents the main results of a research program carried out by a NERI Consortium, which consisted of Penn State University (PSU) (lead), University of South Carolina (USC), Tulane University (TU), and Argonne National Laboratory (ANL). Thermochemical water decomposition is an emerging technology for large-scale production of hydrogen. Typically using two or more intermediate compounds, a sequence of chemical and physical processes split water into hydrogen and oxygen, without releasing any pollutants externally to the atmosphere. These intermediate compounds are recycled internally within a closed loop. While previous studies have identified over 200 possible thermochemical cycles, only a few have progressed beyond theoretical calculations to working experimental demonstrations that establish scientific and practical feasibility of the thermochemical processes. The Cu-Cl cycle has a significant advantage over other cycles due to lower temperature requirements – around 530 °C and below. As a result, it can be eventually linked with the Generation IV thermal power stations. Advantages of the Cu-Cl cycle over others include lower operating temperatures, ability to utilize low-grade waste heat to improve energy efficiency, and potentially lower cost materials. Another significant advantage is a relatively low voltage required for the electrochemical step (thus low electricity input). Other advantages include common chemical agents and

Hydrogen Production from Nuclear Energy

Science.gov (United States)

Walters, Leon; Wade, Dave

2003-07-01

During the past decade the interest in hydrogen as transportation fuel has greatly escalated. This heighten interest is partly related to concerns surrounding local and regional air pollution from the combustion of fossil fuels along with carbon dioxide emissions adding to the enhanced greenhouse effect. More recently there has been a great sensitivity to the vulnerability of our oil supply. Thus, energy security and environmental concerns have driven the interest in hydrogen as the clean and secure alternative to fossil fuels. Remarkable advances in fuel-cell technology have made hydrogen fueled transportation a near-term possibility. However, copious quantities of hydrogen must be generated in a manner independent of fossil fuels if environmental benefits and energy security are to be achieved. The renewable technologies, wind, solar, and geothermal, although important contributors, simply do not comprise the energy density required to deliver enough hydrogen to displace much of the fossil transportation fuels. Nuclear energy is the only primary energy source that can generate enough hydrogen in an energy secure and environmentally benign fashion. Methods of production of hydrogen from nuclear energy, the relative cost of hydrogen, and possible transition schemes to a nuclear-hydrogen economy will be presented.

East Meets West: Using Multi-Cultural Groupwork to Develop the Cross-Cultural Capability of Tomorrow's International Managers.

Science.gov (United States)

Ottewill, Roger; Laughton, David

2000-01-01

Increasing globalization of business means that those educating tomorrow's managers must prioritize the development of cross-cultural capability. Presents a case study of a British international business program at one university that successfully used multicultural groupwork for this purpose. Though it resulted in enhanced capability, it may have…

Microalgal hydrogen production - A review.

Science.gov (United States)

Khetkorn, Wanthanee; Rastogi, Rajesh P; Incharoensakdi, Aran; Lindblad, Peter; Madamwar, Datta; Pandey, Ashok; Larroche, Christian

2017-11-01

Bio-hydrogen from microalgae including cyanobacteria has attracted commercial awareness due to its potential as an alternative, reliable and renewable energy source. Photosynthetic hydrogen production from microalgae can be interesting and promising options for clean energy. Advances in hydrogen-fuel-cell technology may attest an eco-friendly way of biofuel production, since, the use of H 2 to generate electricity releases only water as a by-product. Progress in genetic/metabolic engineering may significantly enhance the photobiological hydrogen production from microalgae. Manipulation of competing metabolic pathways by modulating the certain key enzymes such as hydrogenase and nitrogenase may enhance the evolution of H 2 from photoautotrophic cells. Moreover, biological H 2 production at low operating costs is requisite for economic viability. Several photobioreactors have been developed for large-scale biomass and hydrogen production. This review highlights the recent technological progress, enzymes involved and genetic as well as metabolic engineering approaches towards sustainable hydrogen production from microalgae. Copyright © 2017 Elsevier Ltd. All rights reserved.

Academic dishonesty today, unethical practices tomorrow?

Science.gov (United States)

LaDuke, Rebekah D

2013-01-01

The purpose of this article was to review the most current published literature on the topics of academic dishonesty, unethical professional practices, and research that studied the correlation between these 2 areas of interest. Literature was retrieved by utilizing key words such as academic dishonesty, cheating, workplace dishonesty, and unethical behavior. Multiple research databases were used and a reference librarian in locating relevant research studies resulting in 16 research articles reviewed and 7 articles referenced within the literature review. Upon completion, it became apparent that nursing educators should be concerned that nursing students found to be academically dishonest today may have a higher incidence of displaying unethical practices as a registered nurse tomorrow. It also became clear that the nursing profession needs to conduct its own research in this field to verify findings discovered by other professions such as engineering, business, and psychology. Finally, recommendations were given on how nursing educators should handle the topic of ethics in nursing programs. Copyright © 2013 Elsevier Inc. All rights reserved.

Calculations concerning the capability of passive recombiners to control hydrogen concentration in the containment of an advanced PWR

International Nuclear Information System (INIS)

Fineschi, F.; Vanini, P.

1997-01-01

The Department of Mechanical and Nuclear Constructions of the University of Pisa has developed a computer code, HOCRA, which is able to make an initial evaluation of the capability of catalytic recombiners to remove hydrogen from the atmosphere of the safety containments of nuclear reactors in accident conditions. The code allows the analysis of the average concentration transient of hydrogen in a generic compartment of a safety containment in a nuclear reactor. The software is structured into two groups. The first, mode-1, analyses the average concentration in all the free volume of the containment before a possible venting., whereas the second, mode-2, analyses the average concentration transient in a containment compartment, assuming input and output flow rates into and from the compartment itself The first part of this paper outlines the physical and mathematical model of the code, the second part reports calculations made for an advanced PWR in cooperation with ENEL. (author)

The homes of tomorrow: service composition and advanced user interfaces

Directory of Open Access Journals (Sweden)

Claudio Di Ciccio

2011-12-01

Full Text Available Home automation represents a growing market in the industrialized world. Today’s systems are mainly based on ad hoc and proprietary solutions, with little to no interoperability and smart integration. However, in a not so distant future, our homes will be equipped with many sensors, actuators and devices, which will collectively expose services, able to smartly interact and integrate, in order to offer complex services providing even richer functionalities. In this paper we present the approach and results of SM4ALL- Smart hoMes for All, a project investigating automatic service composition and advanced user interfaces applied to domotics.

Hydrogen Storage for Aircraft Applications Overview

Science.gov (United States)

Colozza, Anthony J.; Kohout, Lisa (Technical Monitor)

2002-01-01

Advances in fuel cell technology have brought about their consideration as sources of power for aircraft. This power can be utilized to run aircraft systems or even provide propulsion power. One of the key obstacles to utilizing fuel cells on aircraft is the storage of hydrogen. An overview of the potential methods of hydrogen storage was compiled. This overview identifies various methods of hydrogen storage and points out their advantages and disadvantages relative to aircraft applications. Minimizing weight and volume are the key aspects to storing hydrogen within an aircraft. An analysis was performed to show how changes in certain parameters of a given storage system affect its mass and volume.

Primary energy sources for hydrogen production

International Nuclear Information System (INIS)

Hassmann, K.; Kuehne, H.M.

1993-01-01

The costs for hydrogen production through water electrolysis are estimated, assuming the electricity is produced from solar, hydro-, fossil, or nuclear power. The costs for hydrogen end-use in the power generation, heat and transportation sectors are also calculated, based on a state of the art technology and a more advanced technology expected to represent the state by the year 2010. The costs for hydrogen utilization (without energy taxes) are shown to be higher than current prices for fossil fuels (including taxes). Without restrictions imposed on fossil fuel consumption, hydrogen shall not gain a significant market share in either of the cases discussed. 2 figs., 3 tabs., 4 refs

FY17 Transportation and Hydrogen Systems Center Journal Publication Highlights

Energy Technology Data Exchange (ETDEWEB)

2017-12-08

NREL's Transportation and Hydrogen Systems Center published 39 journal articles in fiscal year 2017 highlighting recent research in advanced vehicle technology, alternative fuels, and hydrogen systems.

Proceedings of the DOE chemical energy storage and hydrogen energy systems contracts review

Energy Technology Data Exchange (ETDEWEB)

1980-02-01

Sessions were held on electrolysis-based hydrogen storage systems, hydrogen production, hydrogen storage systems, hydrogen storage materials, end-use applications and system studies, chemical heat pump/chemical energy storage systems, systems studies and assessment, thermochemical hydrogen production cycles, advanced production concepts, and containment materials. (LHK)

Hydrogen-Assisted IC Engine Combustion as a Route to Hydrogen Implementation

Energy Technology Data Exchange (ETDEWEB)

Andre Boehman; Daniel Haworth

2008-09-30

composition and utilization through laboratory studies of spark-ignition engine operation on H{sub 2}-NG and numerical simulation of the impact of hydrogen blending on the physical and chemical processes within the engine; and (2) Examination of hydrogen-assisted combustion in advanced compression-ignition engine processes. To that end, numerical capabilities were applied to the study of hydrogen assisted combustion and experimental facilities were developed to achieve the project objectives.

Florida Hydrogen Initiative

Energy Technology Data Exchange (ETDEWEB)

Block, David L

2013-06-30

. Politano, Florida Institute of Technology, Melbourne, FL This project developed a hydrogen and fuel cell technology academic program at Florida Institute of Technology in Melbourne, Florida. Design and Development of an Advanced Hydrogen Storage System using Novel Materials ? E. Stefanakos, University of South Florida The goal of this project was to design and develop novel conducting polymeric nanomaterials for on-board hydrogen storage. The project approach was to examine synthesis of polyaniline solid state hydrogen storage materials. Advanced HiFoil ? Bipolar Plates ? J. Braun, M. Fuchs, EnerFuel, Inc. The goal of this project was to provide a durable, low cost bipolar plate for high temperature proton exchange membrane fuel cells. The project results produced a durable, low cost bipolar plate with very high in-plane thermal conductivity.

34 CFR 614.1 - What is the purpose of the Preparing Tomorrow's Teachers to Use Technology program?

Science.gov (United States)

2010-07-01

... 34 Education 3 2010-07-01 2010-07-01 false What is the purpose of the Preparing Tomorrow's Teachers to Use Technology program? 614.1 Section 614.1 Education Regulations of the Offices of the... Use Technology program? (a) This program provides grants to help future teachers become proficient in...

Progress in hydrogen fueled busses

International Nuclear Information System (INIS)

Scott, P.B.; Mazaika, D.M.; Tyler, T.

2004-01-01

'Full text:' The Thor/ISE fuel cell bus has been in demonstration and revenue service during 2002-2003 at sites including SunLine Transit, Chula Vista Transit, Los Angeles County Metropolitan Transit Authority, and AC Transit in Oakland. By taking advantage of ISE's advanced hybrid-electric drive technology, this 30-foot bus operates with a much smaller fuel cell than those used in other buses of this class. Further, stress on the fuel cell is diminished. Based on the exceptional performance of this prototype bus, the transit agencies listed above have concluded that hybrid electric hydrogen fueled buses are attractive. Two types of hydrogen fueled hybrid electric buses will be described: - fuel cell powered, and - HICE (Hydrogen Internal Combustion Engine) This progress report will include: 1. Experience with the Thor/ISE fuel cell bus, including results from revenue service at two transit locations, 2. Design and fabrication status of the advanced fuel cell buses being built for AC Transit and SunLine Transit, 3. Design and fabrication status of the prototype HHICE (Hybrid electric Hydrogen fueled Internal Combustion Engine) bus that uses a Ford hydrogen burning engine, mated to a generator, rather than a fuel cell. Other than the engine, the drive train in the HHICE bus is nearly identical to that of a fuel cell hybrid-electric bus. Canadian participation in the HHICE bus is extensive, it is a New Flyer platform and will be winter tested in Winnipeg. (author)

I'll Save the World from Global Warming--Tomorrow: Using Procrastination Management to Combat Global Warming

Science.gov (United States)

Malott, Richard W.

2010-01-01

In the provocatively titled "I'll Save the World from Global Warming--Tomorrow," Dick Malott says that although we all want to do the right thing to help the environment, whether it's buying and installing compact fluorescent light bulbs (CFLs) or replacing an energy-guzzling appliance with a more efficient one, we put it off because there's no…

Proceedings of a USGS Workshop on Facing Tomorrow's Challenges Along the U.S.-Mexico Border - Monitoring, Modeling, and Forecasting Change Within the Arizona-Sonora Transboundary Watersheds

Science.gov (United States)

Norman, Laura M.; Hirsch, Derrick D.; Ward, A. Wesley

2008-01-01

INTRODUCTION TO THE WORKSHOP PROCEEDINGS Competition for water resources, habitats, and urban areas in the Borderlands has become an international concern. In the United States, Department of Interior Bureaus, Native American Tribes, and other State and Federal partners rely on the U.S. Geological Survey (USGS) to provide unbiased science and leadership in the Borderlands region. Consequently, the USGS hosted a workshop, ?Facing Tomorrow?s Challenges along the U.S.-Mexico Border,? on March 20?22, 2007, in Tucson, Ariz., focused specifically on monitoring, modeling, and forecasting change within the Arizona-Sonora Transboundary Watersheds

Hydrogen bonded supramolecular materials

CERN Document Server

Li, Zhan-Ting

2015-01-01

This book is an up-to-date text covering topics in utilizing hydrogen bonding for constructing functional architectures and supramolecular materials. The first chapter addresses the control of photo-induced electron and energy transfer. The second chapter summarizes the formation of nano-porous materials. The following two chapters introduce self-assembled gels, many of which exhibit unique functions. Other chapters cover the advances in supramolecular liquid crystals and the versatility of hydrogen bonding in tuning/improving the properties and performance of materials. This book is designed

When Disney Meets the Research Park: Metaphors and Models for Engineering an Online Learning Community of Tomorrow

Science.gov (United States)

Chenail, Ronald J.

2004-01-01

It is suggested that educators look to an environment in which qualitative research can be learned in more flexible and creative ways--an online learning community known as the Research Park Online (RPO). This model, based upon Walt Disney's 1966 plan for his "Experimental Prototype Community of Tomorrow" (EPCOT) and university cooperative…

Advances in interactive supported electro-catalysis for hydrogen and oxygen electrode reactions

Energy Technology Data Exchange (ETDEWEB)

Nedeljko V Krstajic; Ljiljana M Vracar; Jelena M Jaksic; Milan M Jaksic [Faculty of Technology and Metallurgy, University of Belgrade, Belgrade, Serbia and Montenegro (Yugoslavia); Stelios G Neophytides; Miranda Labou; Jelena M Jaksic; Milan M Jaksic [Institute of Chemical Engineering and High Temperature Chemical Processes FORTH, and Department of Chemistry, University of Patras, 26500 Patras, (Greece); Reidar Tunold [University of Trondheim, NTNU, Institute of Industrial Electrochemistry, Trondheim, (Norway); Polycarpos Falaras [Institute of Physical Chemistry, NCSR Demokritos, Attikis, Athens, (Greece)

2006-07-01

Magneli phases have been introduced as an unique electron conductive and interactive support for electro-catalysis both in hydrogen (HELR) and oxygen (OELR) electrode reactions in water electrolysis and Low Temperature PEM Fuel Cells (LT PEM FC). The Strong Metal-Support Interaction (SMSI) that imposes the former implies: (i) the hypo-hyper-d inter-bonding effect and its catalytic consequences, and (ii) the interactive primary oxide (M-OH) spillover from the hypo-d-oxide support as a dynamic electrocatalytic contribution. The stronger the bonding, the more strained appear d-orbitals, thereby the less strong the intermediate adsorptive strength in the rate determining step (RDS), and consequently, the faster the facilitated catalytic electrode reaction arises. At the same time the primary oxide spillover transferred from the hypo-d-oxide support directly interferes and reacts either individually and directly to contribute to finish the oxygen reduction, or with other interactive species, like CO to contribute to the CO tolerance. In such a respect, the conditions to provide Au to act as the reversible hydrogen electrode have been proved either by its potentiodynamic surface reconstruction in a heavy water solution, or by the nano-structured SMSI Au on anatase titania with characteristic strained d-orbitals in such a hypo-hyper-d-interactive bonding (Au/TiO{sub 2}). In the same context, the monoatomic network dispersion of Pt upon Magneli phases makes it possible to produce an advanced interactive supported electro-catalyst for cathodic oxygen reduction (ORR). The strained hypo-hyper-d-inter-electronic and inter-d-orbital metal/hypo-d-oxide support bonding relative to the strength of the latter, has been inferred to be the basis of the synergistic electrocatalytic effect both in the HELR and ORR. (authors)

Alcohol consumption and low-risk drinking guidelines among adults: a cross-sectional analysis from Alberta's Tomorrow Project.

Science.gov (United States)

Brenner, Darren R; Haig, Tiffany R; Poirier, Abbey E; Akawung, Alianu; Friedenreich, Christine M; Robson, Paula J

2017-12-01

Moderate to heavy alcohol consumption is a risk factor for all-cause mortality and cancer incidence. Although cross-sectional data are available through national surveys, data on alcohol consumption in Alberta from a large prospective cohort were not previously available. The goal of these analyses was to characterize the levels of alcohol consumption among adults from the Alberta's Tomorrow Project in the context of cancer prevention guidelines. Furthermore, we conducted analyses to examine the relationships between alcohol consumption and other high-risk or risk-related behaviours. Between 2001 and 2009, 31 072 men and women aged 35 to 69 years were enrolled into Alberta's Tomorrow Project, a large provincial cohort study. Data concerning alcohol consumption in the past 12 months were obtained from 26 842 participants who completed self-administered health and lifestyle questionnaires. We conducted cross-sectional analyses on daily alcohol consumption and cancer prevention guidelines for alcohol use in relation to sociodemographic factors. We also examined the combined prevalence of alcohol consumption and tobacco use, obesity and comorbidities. Approximately 14% of men and 12% of women reported alcohol consumption exceeding recommendations for cancer prevention. Higher alcohol consumption was reported in younger age groups, urban dwellers, those with higher incomes and those who consumed more red meat. Moreover, volume of daily alcohol consumption was positively associated with current tobacco use in both men and women. Overall, men were more likely to fall in the moderate and high-risk behavioural profiles and show higher daily alcohol consumption patterns compared to women. Despite public health messages concerning the adverse impact of alcohol consumption, a sizeable proportion of Alberta's Tomorrow Project participants consumed alcohol in excess of cancer prevention recommendations. Continued strategies to promote low-risk drinking among those who choose to

The Challenges of Catholic Education: Evidence from the Responses to the Instrumentum Laboris "Educating Today and Tomorrow"

Science.gov (United States)

Paletta, Angelo; Fiorin, Italo

2016-01-01

This article is based on the analysis of the responses to the questionnaires submitted for the Instrumentum Laboris 'Educating today and tomorrow. A renewing passion' and sets out to offer a synthesis of the main challenges facing Catholic education around the world, key criticalities as well as more positive aspects and the strategic and…

Hydrogen: Adding Value and Flexibility to the Nuclear Power Industry

International Nuclear Information System (INIS)

Lee, J.; Bhatt, V.; Friley, P.; Horak, W.; Reisman, A.

2004-01-01

The objective of this study was to assess potential synergies between the hydrogen economy and nuclear energy options. Specifically: to provide a market analysis of advanced nuclear energy options for hydrogen production in growing hydrogen demand; to conduct an impact evaluation of nuclear-based hydrogen production on the economics of the energy system, environmental emissions, and energy supply security; and to identify competing technologies and challenges to nuclear options

Pure energy solutions - pure tomorrows

International Nuclear Information System (INIS)

Allison, J.

2006-01-01

HTC is an energy technology company whose mandate is to deliver 'Carbon Clear Solutions' to address the pending challenges the energy sector is facing in meeting the environmental impact of Greenhouse Gas emissions, and energy security. HTC will speak on its comprehensive suite of technologies including hydrogen production, CO 2 capture and CO 2 sequestration. HTC has patented technologies that produce H 2 from a broad variety of feedstocks such as Natural gas, Diesel, Gasoline, Bio-fuels i.e. ethanol, methanol and Coal Gasification. HTC Hydrogen reformation systems are unique in their method of delivering pure Hydrogen. Dry Reformation Reactor - New catalyst system designed to eliminate contamination problems (i.e. coking) while at the same time operate at a low temperature. Water Gas Shift Reactor - Plus - improved and redesigned catalyst that improves operating temperature and hydrogen production efficiency. Two stage catalyst reactor that provides near balance of the endothermic and exothermic reaction temperatures for efficient energy balance

Advanced hydrogen technologies for FC applications and PGM beneficiation in SA: Presentation

CSIR Research Space (South Africa)

Langmi, Henrietta W

2013-03-01

Full Text Available developing hydrogen storage systems for fuel cell applications, and developing applications and solutions for small- and medium-scale hydrogen production through innovative research and development to promote beneficiation of Platinum-Group Metals (PGMs)....

Hydrogen pickup and redistribution in alpha-annealed Zircaloy-4

International Nuclear Information System (INIS)

Kammenzind, B.F.; Franklin, D.G.; Duffin, W.J.; Peters, H.R.

1996-01-01

Zircaloy-4, which is widely used as a core structural material in Pressurized-Water Reactors (PWR), picks up hydrogen during service. Hydrogen solubility in Zircaloy-4 is low and hydrides precipitate after the Zircaloy-4 matrix becomes supersaturated with hydrogen. These hydrides embrittle the Zircaloy-4. To study hydrogen pickup and concentration, a postirradiation nondestructive radiographic technique for measuring hydrogen concentration was developed and qualified. Experiments on hydrogen pickup were conducted in the Advanced Test Reactor (ATR). Ex-reactor tests were conducted to determine the conditions for which hydrogen would dissolve, migrate, and precipitate. Finally, a phenomenological model for hydrogen diffusion was indexed to the data. This presentation describes the equipment and the model, presents the results of experiments, and compares the model predictions to experimental results

Catalysis and Downsizing in Mg-Based Hydrogen Storage Materials

Directory of Open Access Journals (Sweden)

Jianding Li

2018-02-01

Full Text Available Magnesium (Mg-based materials are promising candidates for hydrogen storage due to the low cost, high hydrogen storage capacity and abundant resources of magnesium for the realization of a hydrogen society. However, the sluggish kinetics and strong stability of the metal-hydrogen bonding of Mg-based materials hinder their application, especially for onboard storage. Many researchers are devoted to overcoming these challenges by numerous methods. Here, this review summarizes some advances in the development of Mg-based hydrogen storage materials related to downsizing and catalysis. In particular, the focus is on how downsizing and catalysts affect the hydrogen storage capacity, kinetics and thermodynamics of Mg-based hydrogen storage materials. Finally, the future development and applications of Mg-based hydrogen storage materials is discussed.

Design and Development of an Advanced Liquid Hydrogen Turbopump

National Research Council Canada - National Science Library

Minick, A

1998-01-01

.... These benefits will be accomplished and demonstrated through design, development, and test of this high speed, high efficiency, two stage hydrogen turbopump capable of supplying 16 lbm/sec (7.3 kg/sec...

Arizona Public Service - Alternative Fuel (Hydrogen) Pilot Plant Design Report

Energy Technology Data Exchange (ETDEWEB)

James E. Francfort

2003-12-01

Hydrogen has promise to be the fuel of the future. Its use as a chemical reagent and as a rocket propellant has grown to over eight million metric tons per year in the United States. Although use of hydrogen is abundant, it has not been used extensively as a transportation fuel. To assess the viability of hydrogen as a transportation fuel and the viability of producing hydrogen using off-peak electric energy, Pinnacle West Capital Corporation (PNW) and its electric utility subsidiary, Arizona Public Service (APS) designed, constructed, and operates a hydrogen and compressed natural gas fueling station—the APS Alternative Fuel Pilot Plant. This report summarizes the design of the APS Alternative Fuel Pilot Plant and presents lessons learned from its design and construction. Electric Transportation Applications prepared this report under contract to the U.S. Department of Energy’s Advanced Vehicle Testing Activity. The Idaho National Engineering and Environmental Laboratory manages these activities for the Advanced Vehicle Testing Activity.

Scenarios for multi-unit inertial fusion energy plants producing hydrogen fuel

International Nuclear Information System (INIS)

Logan, B.G.

1993-12-01

This work describes: (a) the motivation for considering fusion in general, and Inertial Fusion Energy (IFE) in particular, to produce hydrogen fuel powering low-emission vehicles; (b) the general requirements for any fusion electric plant to produce hydrogen by water electrolysis at costs competitive with present consumer gasoline fuel costs per passenger mile, for advanced car architectures meeting President Clinton's 80 mpg advanced car goal, and (c) a comparative economic analysis for the potential cost of electricity (CoE) and corresponding cost of hydrogen (CoH) from a variety of multi-unit IFE plants with one to eight target chambers sharing a common driver and target fab facility. Cases with either heavy-ion or diode-pumped, solid-state laser drivers are considered, with ''conventional'' indirect drive target gains versus ''advanced, e.g. Fast Ignitor'' direct drive gain assumptions, and with conventional steam balance-of-plant (BoP) versus advanced MHD plus steam combined cycle BoP, to contrast the potential economics under ''conventional'' and ''advanced'' IFE assumptions, respectively

Innovations for Tomorrow: Summary of the 2016 Disaster Health Education Symposium.

Science.gov (United States)

Gulley, Kelly; Strauss-Riggs, Kandra; Kirsch, Thomas D; Goolsby, Craig

2017-04-01

In an effort to enhance education, training, and learning in the disaster health community, the National Center for Disaster Medicine and Public Health (NCDMPH) gathered experts from around the nation in Bethesda, Maryland, on September 8, 2016, for the 2016 Disaster Health Education Symposium: Innovations for Tomorrow. This article summarizes key themes presented during the disaster health symposium including innovations in the following areas: training and education that saves lives, practice, teaching, sharing knowledge, and our communities. This summary article provides thematic content for those unable to attend. Please visit http://ncdmph.usuhs.edu/ for more information. (Disaster Med Public Health Preparedness. 2017;11:160-162).

An Analysis of Methanol and Hydrogen Production via High-Temperature Electrolysis Using the Sodium Cooled Advanced Fast Reactor

Energy Technology Data Exchange (ETDEWEB)

Shannon M. Bragg-Sitton; Richard D. Boardman; Robert S. Cherry; Wesley R. Deason; Michael G. McKellar

2014-03-01

Integration of an advanced, sodium-cooled fast spectrum reactor into nuclear hybrid energy system (NHES) architectures is the focus of the present study. A techno-economic evaluation of several conceptual system designs was performed for the integration of a sodium-cooled Advanced Fast Reactor (AFR) with the electric grid in conjunction with wind-generated electricity. Cases in which excess thermal and electrical energy would be reapportioned within an integrated energy system to a chemical plant are presented. The process applications evaluated include hydrogen production via high temperature steam electrolysis and methanol production via steam methane reforming to produce carbon monoxide and hydrogen which feed a methanol synthesis reactor. Three power cycles were considered for integration with the AFR, including subcritical and supercritical Rankine cycles and a modified supercritical carbon dioxide modified Brayton cycle. The thermal efficiencies of all of the modeled power conversions units were greater than 40%. A thermal efficiency of 42% was adopted in economic studies because two of the cycles either performed at that level or could potentially do so (subcritical Rankine and S-CO2 Brayton). Each of the evaluated hybrid architectures would be technically feasible but would demonstrate a different internal rate of return (IRR) as a function of multiple parameters; all evaluated configurations showed a positive IRR. As expected, integration of an AFR with a chemical plant increases the IRR when “must-take” wind-generated electricity is added to the energy system. Additional dynamic system analyses are recommended to draw detailed conclusions on the feasibility and economic benefits associated with AFR-hybrid energy system operation.

Advances of zeolite based membrane for hydrogen production via water gas shift reaction

Science.gov (United States)

Makertihartha, I. G. B. N.; Zunita, M.; Rizki, Z.; Dharmawijaya, P. T.

2017-07-01

Hydrogen is considered as a promising energy vector which can be obtained from various renewable sources. However, an efficient hydrogen production technology is still challenging. One technology to produce hydrogen with very high capacity with low cost is through water gas shift (WGS) reaction. Water gas shift reaction is an equilibrium reaction that produces hydrogen from syngas mixture by the introduction of steam. Conventional WGS reaction employs two or more reactors in series with inter-cooling to maximize conversion for a given volume of catalyst. Membrane reactor as new technology can cope several drawbacks of conventional reactor by removing reaction product and the reaction will favour towards product formation. Zeolite has properties namely high temperature, chemical resistant, and low price makes it suitable for membrane reactor applications. Moreover, it has been employed for years as hydrogen selective layer. This review paper is focusing on the development of membrane reactor for efficient water gas shift reaction to produce high purity hydrogen and carbon dioxide. Development of membrane reactor is discussed further related to its modification towards efficient reaction and separation from WGS reaction mixture. Moreover, zeolite framework suitable for WGS membrane reactor will be discussed more deeply.

Final Scientifc Report - Hydrogen Education State Partnership Project

Energy Technology Data Exchange (ETDEWEB)

Leon, Warren

2012-02-03

Under the leadership of the Department of Energy Hydrogen and Fuel Cells program, Clean Energy States Alliance (CESA) educated and worked with state leaders to encourage wider deployment of fuel cell and hydrogen technologies. Through outreach to state policymakers, legislative leaders, clean energy funds, energy agencies, and public utility commissions, CESA worked to accomplish the following objectives of this project: 1. Provide information and technical assistance to state policy leaders and state renewable energy programs in the development of effective hydrogen fuel cell programs. 2. Identify and foster hydrogen program best practices. 3. Identify and promote strategic opportunities for states and the Department of Energy (DOE) to advance hydrogen technology deployment through partnerships, collaboration, and targeted activities. Over the three years of this project, CESA, with our partner National Conference of State Legislatures (NCSL), was able to provide credible information on fuel cell policies, finance, and technical assistance to hundreds of state officials and other stakeholders. CESA worked with its membership network to effectively educate state clean energy policymakers, program managers, and decision makers about fuel cell and hydrogen technologies and the efforts by states to advance those technologies. With the assistance of NCSL, CESA gained access to an effective forum for outreach and communication with state legislators from all 50 states on hydrogen issues and policies. This project worked to educate policymakers and stakeholders with the potential to develop and deploy stationary and portable fuel cell technologies.

Breeding of tomorrow's chickens to improve well-being.

Science.gov (United States)

Cheng, H-W

2010-04-01

Chickens, as well as other animals, have the ability to change their behavior (behavioral plasticity) and physiology (physiological plasticity) based on the costs and benefits to fit their environment (adaptation). Through natural selection, the population preserves and accumulates traits that are beneficial and rejects those that are detrimental in their prevailing environments. The surviving populations are able to contribute more genes associated with beneficial traits for increased fitness to subsequent generations. Natural selection is slow but constant; working over multiple generations, the changes to the population often appear silent or undetectable at a given point in history. Chickens were domesticated from the wild red jungle fowl. The principle of domestication of chickens, as well as other farm animals, by humans is similar to that of natural selection: selecting the best animals with the highest survivability and reproducibility (artificial selection). Compared with natural selection, the process of artificial selection is motivated by human needs and acts more rapidly with more visible results over a short time period. This process has been further accelerated following the development of current breeding programs and the emergence of specialized breeding companies. A laying hen, for example, produces more than 300 hundred eggs a year, whereas a jungle fowl lays 4 to 6 eggs in a year. During the domestication process, chickens retained their capability to adapt to their housing environments, which is usually achieved by genetic changes occurring with each subsequent generation. Genes control the behavioral, physiological, immunological, and psychological responses of animals to stressors, including environmental stimulations. With advances in understanding of genetic mediation of animal physiology and behavior and the discovery of the genome sequences of many species, animal production breeding programs can be improved in both speed and efficiency

Advancement of Systems Designs and Key Engineering Technologies for Materials Based Hydrogen Storage

Energy Technology Data Exchange (ETDEWEB)

van Hassel, Bart A. [United Technologies Research Center, East Hartford, CT (United States)

2015-09-18

UTRC lead the development of the Simulink Framework model that enables a comparison of different hydrogen storage systems on a common basis. The Simulink Framework model was disseminated on the www.HSECoE.org website that is hosted by NREL. UTRC contributed to a better understanding of the safety aspects of the proposed hydrogen storage systems. UTRC also participated in the Failure Mode and Effect Analysis of both the chemical- and the adsorbent-based hydrogen storage system during Phase 2 of the Hydrogen Storage Engineering Center of Excellence. UTRC designed a hydrogen storage system with a reversible metal hydride material in a compacted form for light-duty vehicles with a 5.6 kg H2 storage capacity, giving it a 300 miles range. It contains a heat exchanger that enables efficient cooling of the metal hydride material during hydrogen absorption in order to meet the 3.3 minute refueling time target. It has been shown through computation that the kinetics of hydrogen absorption of Ti-catalyzed NaAlH4 was ultimately limiting the rate of hydrogen absorption to 85% of the material capacity in 3.3 minutes. An inverse analysis was performed in order to determine the material property requirements in order for a metal hydride based hydrogen storage system to meet the DOE targets. Work on metal hydride storage systems was halted after the Phase 1 to Phase 2 review due to the lack of metal hydride materials with the required material properties. UTRC contributed to the design of a chemical hydrogen storage system by developing an adsorbent for removing the impurity ammonia from the hydrogen gas, by developing a system to meter the transport of Ammonia Borane (AB) powder to a thermolysis reactor, and by developing a gas-liquid-separator (GLS) for the separation of hydrogen gas from AB slurry in silicone oil. Stripping impurities from hydrogen gas is essential for a long life of the fuel cell system on board of a vehicle. Work on solid transport of AB was halted after the

HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER

Energy Technology Data Exchange (ETDEWEB)

BROWN,LC; BESENBRUCH,GE; LENTSCH,RD; SCHULTZ,KR; FUNK,JF; PICKARD,PS; MARSHALL,AC; SHOWALTER,SK

2003-06-01

OAK B202 HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER. Combustion of fossil fuels, used to power transportation, generate electricity, heat homes and fuel industry provides 86% of the world's energy. Drawbacks to fossil fuel utilization include limited supply, pollution, and carbon dioxide emissions. Carbon dioxide emissions, thought to be responsible for global warming, are now the subject of international treaties. Together, these drawbacks argue for the replacement of fossil fuels with a less-polluting potentially renewable primary energy such as nuclear energy. Conventional nuclear plants readily generate electric power but fossil fuels are firmly entrenched in the transportation sector. Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. Hydrogen will be particularly advantageous when coupled with fuel cells. Fuel cells have higher efficiency than conventional battery/internal combustion engine combinations and do not produce nitrogen oxides during low-temperature operation. Contemporary hydrogen production is primarily based on fossil fuels and most specifically on natural gas. When hydrogen is produced using energy derived from fossil fuels, there is little or no environmental advantage. There is currently no large scale, cost-effective, environmentally attractive hydrogen production process available for commercialization, nor has such a process been identified. The objective of this work is to find an economically feasible process for the production of hydrogen, by nuclear means, using an advanced high-temperature nuclear reactor as the primary energy source. Hydrogen production by thermochemical water-splitting (Appendix A), a chemical process that accomplishes the decomposition of water into hydrogen and oxygen using only heat or, in the case of a hybrid thermochemical process, by a combination of heat and electrolysis, could meet these goals. Hydrogen produced from

SEPARATION OF HYDROGEN AND CARBON DIOXIDE USING A NOVEL MEMBRANE REACTOR IN ADVANCED FOSSIL ENERGY CONVERSION PROCESS

Energy Technology Data Exchange (ETDEWEB)

Shamsuddin Ilias

2005-02-03

Inorganic membrane reactors offer the possibility of combining reaction and separation in a single operation at high temperatures to overcome the equilibrium limitations experienced in conventional reactor configurations. Such attractive features can be advantageously utilized in a number of potential commercial opportunities, which include dehydrogenation, hydrogenation, oxidative dehydrogenation, oxidation and catalytic decomposition reactions. However, to be cost effective, significant technological advances and improvements will be required to solve several key issues which include: (a) permselective thin solid film, (b) thermal, chemical and mechanical stability of the film at high temperatures, and (c) reactor engineering and module development in relation to the development of effective seals at high temperature and high pressure. In this project, we are working on the development and application of palladium and palladium-silver alloy thin-film composite membranes in membrane reactor-separator configuration for simultaneous production and separation of hydrogen and carbon dioxide at high temperature. From our research on Pd-composite membrane, we have demonstrated that the new membrane has significantly higher hydrogen flux with very high perm-selectivity than any of the membranes commercially available. The steam reforming of methane by equilibrium shift in Pd-composite membrane reactor is being studied to demonstrate the potential application of this new development. A two-dimensional, pseudo-homogeneous membrane-reactor model was developed to investigate the steam-methane reforming (SMR) reactions in a Pd-based membrane reactor. Radial diffusion was taken into consideration to account for the concentration gradient in the radial direction due to hydrogen permeation through the membrane. With appropriate reaction rate expressions, a set of partial differential equations was derived using the continuity equation for the reaction system. The equations were

Students today…educators tomorrow.

Science.gov (United States)

Moore, Keri; Vaughan, Brett

2017-10-01

The article describes the use of the mini clinical examination (mini-CEX) in a pilot study to introduce peer assessment in one allied health programme to explore students' capacity as clinical educators. Preparing today's pre-professional health students to be clinical educators by engaging them in peer teaching, learning and assessment may encourage them to become tomorrow's clinical educators. Peer assessment is common among many undergraduate medical and allied health programmes, and is typically used as a means of providing students with feedback on their clinical skill development. We argue that peer assessment ought to be focused not only on the development of learners' clinical skills and knowledge, but also on preparing learners for their responsibilities as clinical educators. Final-year Australian osteopathy students in our on-campus university clinic undertook, without training, peer assessment and provision of feedback related to clinical performance using a discipline-specific adaptation of the mini-CEX. The current study suggests that students are able to judge another's consultation skills and case management in that they identify what we know are common learning issues for students at this level. Peer assessment ought to be focused on preparing learners for their responsibilities as clinical educators IMPLICATION: Students may be willing to engage in peer assessment if they see the exercise as a way to improve patient care and to develop their skills as educators - potentially encouraging them to become clinical educators in the future. © 2016 John Wiley & Sons Ltd and The Association for the Study of Medical Education.

Alcohol consumption and low-risk drinking guidelines among adults: a cross-sectional analysis from Alberta’s Tomorrow Project

Science.gov (United States)

Darren R., Brenner; Tiffany R., Haig; Abbey E, Poirier; Alianu, Akawung; Christine M., Friedenreich; Paula J., Robson

2017-01-01

Abstract Introduction: Moderate to heavy alcohol consumption is a risk factor for all-cause mortality and cancer incidence. Although cross-sectional data are available through national surveys, data on alcohol consumption in Alberta from a large prospective cohort were not previously available. The goal of these analyses was to characterize the levels of alcohol consumption among adults from the Alberta’s Tomorrow Project in the context of cancer prevention guidelines. Furthermore, we conducted analyses to examine the relationships between alcohol consumption and other high-risk or risk-related behaviours. Methods: Between 2001 and 2009, 31 072 men and women aged 35 to 69 years were enrolled into Alberta’s Tomorrow Project, a large provincial cohort study. Data concerning alcohol consumption in the past 12 months were obtained from 26 842 participants who completed self-administered health and lifestyle questionnaires. We conducted cross-sectional analyses on daily alcohol consumption and cancer prevention guidelines for alcohol use in relation to sociodemographic factors. We also examined the combined prevalence of alcohol consumption and tobacco use, obesity and comorbidities. Results: Approximately 14% of men and 12% of women reported alcohol consumption exceeding recommendations for cancer prevention. Higher alcohol consumption was reported in younger age groups, urban dwellers, those with higher incomes and those who consumed more red meat. Moreover, volume of daily alcohol consumption was positively associated with current tobacco use in both men and women. Overall, men were more likely to fall in the moderate and high-risk behavioural profiles and show higher daily alcohol consumption patterns compared to women. Conclusion: Despite public health messages concerning the adverse impact of alcohol consumption, a sizeable proportion of Alberta’s Tomorrow Project participants consumed alcohol in excess of cancer prevention recommendations. Continued

Hydrogen production by nuclear heat

International Nuclear Information System (INIS)

Crosbie, Leanne M.; Chapin, Douglas

2003-01-01

A major shift in the way the world obtains energy is on the horizon. For a new energy carrier to enter the market, several objectives must be met. New energy carriers must meet increasing production needs, reduce global pollution emissions, be distributed for availability worldwide, be produced and used safely, and be economically sustainable during all phases of the carrier lifecycle. Many believe that hydrogen will overtake electricity as the preferred energy carrier. Hydrogen can be burned cleanly and may be used to produce electricity via fuel cells. Its use could drastically reduce global CO 2 emissions. However, as an energy carrier, hydrogen is produced with input energy from other sources. Conventional hydrogen production methods are costly and most produce carbon dioxide, therefore, negating many of the benefits of using hydrogen. With growing concerns about global pollution, alternatives to fossil-based hydrogen production are being developed around the world. Nuclear energy offers unique benefits for near-term and economically viable production of hydrogen. Three candidate technologies, all nuclear-based, are examined. These include: advanced electrolysis of water, steam reforming of methane, and the sulfur-iodine thermochemical water-splitting cycle. The underlying technology of each process, advantages and disadvantages, current status, and production cost estimates are given. (author)

City of Portland: Businesses for an environmentally sustainable tomorrow

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-12-01

The sustainable business development program in Portland (OR) is known as BEST. BEST stands for Businesses for an Environmentally Sustainable Tomorrow. The Portland Energy Office operates BEST as a {open_quotes}one-stop service center{close_quotes} for business owners and managers. BEST provides information and assistance on resource efficient buildings and business practices. The results of BEST`s two years of operation have been generally impressive. Nearly 150 new or expanding businesses have been connected with utility design assistance programs. Businesses have also received assistance with water conservation, telecommuting, construction debris recycling, and alternative fuel vehicles. BEST has received local and national publicity and BEST services have been the topic at more than a dozen conferences, meetings, or other speaking engagements. A guidebook for communities wishing to start a similar program will be available in early 1996.

Solar Hydrogen Energy Systems Science and Technology for the Hydrogen Economy

CERN Document Server

Zini, Gabriele

2012-01-01

It is just a matter of time when fossil fuels will become unavailable or uneconomical to retrieve. On top of that, their environmental impact is already too severe. Renewable energy sources can be considered as the most important substitute to fossil energy, since they are inexhaustible and have a very low, if none, impact on the environment. Still, their unevenness and unpredictability are drawbacks that must be dealt with in order to guarantee a reliable and steady energy supply to the final user. Hydrogen can be the answer to these problems. This book presents the readers with the modeling, functioning and implementation of solar hydrogen energy systems, which efficiently combine different technologies to convert, store and use renewable energy. Sources like solar photovoltaic or wind, technologies like electrolysis, fuel cells, traditional and advanced hydrogen storage are discussed and evaluated together with system management and output performance. Examples are also given to show how these systems are ...

Composite metal-hydrogen electrodes for metal-hydrogen batteries. Final report, October 1, 1993 - April 15, 1997

International Nuclear Information System (INIS)

Ruckman, M.W.; Strongin, M.; Weismann, H.

1997-04-01

The purpose of this project is to develop and conduct a feasibility study of metallic thin films (multilayered and alloy composition) produced by advanced sputtering techniques for use as anodes in Ni-metal hydrogen batteries that would be deposited as distinct anode, electrolyte and cathode layers in thin film devices. The materials could also be incorporated in secondary consumer batteries (i.e. type AF(4/3 or 4/5)) which use electrodes in the form of tapes. The project was based on pioneering studies of hydrogen uptake by ultra-thin Pd-capped Nb films, these studies suggested that materials with metal-hydrogen ratios exceeding those of commercially available metal hydride materials and fast hydrogen charging and discharging kinetics could be produced. The project initially concentrated on gas phase and electrochemical studies of Pd-capped niobium films in laboratory-scale NiMH cells. This extended the pioneering work to the wet electrochemical environment of NiMH batteries and exploited advanced synchrotron radiation techniques not available during the earlier work to conduct in-situ studies of such materials during hydrogen charging and discharging. Although batteries with fast charging kinetics and hydrogen-metal ratios approaching unity could be fabricated, it was found that oxidation, cracking and corrosion in aqueous solutions made pure Nb films and multilayers poor candidates for battery application. The project emphasis shifted to alloy films based on known elemental materials used for NiMH batteries. Although commercial NiMH anode materials contain many metals, it was found that 0.24 μm thick sputtered Zr-Ni films cycled at least 50 times with charging efficiencies exceeding 95% and [H]/[M] ratios of 0.7-1.0. Multilayered or thicker Zr-Ni films could be candidates for a thin film NiMH battery that may have practical applications as an integrated power source for modern electronic devices

Students and Teachers Accessing Tomorrow (STAT): Baltimore County Public School's One-to-One Digital Conversion Case in Practice

Science.gov (United States)

Imbriale, Ryan; Schiner, Nicholas; Elmendorf, Douglas

2017-01-01

Baltimore County Public Schools is in the midst of a transformation of teaching and learning; the goal being the creation of student-centered classrooms supported by a one-to-one computer for every student. This transformation, known as Students and Teachers Accessing Tomorrow, began in 2014 and is now in its third academic year. We present this…

FY 2005 Annual Progress Report for the DOE Hydrogen Program

Energy Technology Data Exchange (ETDEWEB)

None

2005-10-01

In cooperation with industry, academia, national laboratories, and other government agencies, the Department of Energy's Hydrogen Program is advancing the state of hydrogen and fuel cell technologies in support of the President's Hydrogen Fuel Initiative. The initiative seeks to develop hydrogen, fuel cell, and infrastructure technologies needed to make it practical and cost-effective for Americans to choose to use fuel cell vehicles by 2020. Significant progress was made in fiscal year 2005 toward that goal.

Ground Operations Demonstration Unit for Liquid Hydrogen Initial Test Results

Science.gov (United States)

Notardonato, W. U.; Johnson, W. L.; Swanger, A. M.; Tomsik, T.

2015-01-01

NASA operations for handling cryogens in ground support equipment have not changed substantially in 50 years, despite major technology advances in the field of cryogenics. NASA loses approximately 50% of the hydrogen purchased because of a continuous heat leak into ground and flight vessels, transient chill down of warm cryogenic equipment, liquid bleeds, and vent losses. NASA Kennedy Space Center (KSC) needs to develop energy-efficient cryogenic ground systems to minimize propellant losses, simplify operations, and reduce cost associated with hydrogen usage. The GODU LH2 project has designed, assembled, and started testing of a prototype storage and distribution system for liquid hydrogen that represents an advanced end-to-end cryogenic propellant system for a ground launch complex. The project has multiple objectives including zero loss storage and transfer, liquefaction of gaseous hydrogen, and densification of liquid hydrogen. The system is unique because it uses an integrated refrigeration and storage system (IRAS) to control the state of the fluid. This paper will present and discuss the results of the initial phase of testing of the GODU LH2 system.

Advanced Technology and Alternative Fuel Vehicles

International Nuclear Information System (INIS)

Tuttle, J.

2001-01-01

This fact sheet provides a basic overview of today's alternative fuel choices--including biofuels, biodiesel, electricity, and hydrogen--alternative fuel vehicles, and advanced vehicle technology, such as hybrid electric vehicles, fuel cells and advanced drive trains

Long-term treatment of patients with idiopathic pulmonary fibrosis with nintedanib: results from the TOMORROW trial and its open-label extension.

Science.gov (United States)

Richeldi, Luca; Kreuter, Michael; Selman, Moisés; Crestani, Bruno; Kirsten, Anne-Marie; Wuyts, Wim A; Xu, Zuojun; Bernois, Katell; Stowasser, Susanne; Quaresma, Manuel; Costabel, Ulrich

2017-10-09

The TOMORROW trial of nintedanib comprised a randomised, placebo-controlled, 52-week period followed by a further blinded treatment period and an open-label extension. We assessed outcomes across these periods in patients randomised to nintedanib 150 mg twice daily or placebo at the start of TOMORROW. The annual rate of decline in FVC was -125.4 mL/year (95% CI -168.1 to -82.7) in the nintedanib group and -189.7 mL/year (95% CI -229.8 to -149.6) in the comparator group. The adverse event profile of nintedanib remained consistent throughout the studies. These results support a benefit of nintedanib on slowing progression of idiopathic pulmonary fibrosis beyond 52 weeks. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2017. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

ALTERNATIVE MATERIALS TO PD MEMBRANES FOR HYDROGEN PURIFICATION

Energy Technology Data Exchange (ETDEWEB)

Korinko, P; T. Adams

2008-09-12

Development of advanced hydrogen separation membranes in support of hydrogen production processes such as coal gasification and as front end gas purifiers for fuel cell based system is paramount to the successful implementation of a national hydrogen economy. Current generation metallic hydrogen separation membranes are based on Pd-alloys. Although the technology has proven successful, at issue is the high cost of palladium. Evaluation of non-noble metal based dense metallic separation membranes is currently receiving national and international attention. The focal point of the reported work was to evaluate two different classes of materials for potential replacement of conventional Pd-alloy purification/diffuser membranes. Crystalline V-Ni-Ti and Amorphous Fe- and Co-based metallic glass alloys have been evaluated using gaseous hydrogen permeation testing techniques.

An Affordable Autonomous Hydrogen Flame Detection System for Rocket Propulsion, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — NASA has long used liquid hydrogen as a fuel and plans to continue using it in association with their advanced nuclear thermal propulsion technology. Hydrogen fire...

Microfabricated hydrogen sensitive membranes

Energy Technology Data Exchange (ETDEWEB)

Naddaf, A.; Kraetz, L. [Lehrstuhl fuer Thermische Verfahrenstechnik, Technische Universitaet Kaiserslautern (Germany); Detemple, P.; Schmitt, S.; Hessel, V. [Institut fuer Mikrotechnik Mainz GmbH, Mainz (Germany); Faqir, N. [University of Jordan, Amman (Jordan); Bart, H.J.

2009-01-15

Thin, defect-free palladium, palladium/copper and palladium/silver hydrogen absorbing membranes were microfabricated. A dual sputtering technique was used to deposit the palladium alloy membranes of only 1 {mu}m thickness on a nonporous silicon substrate. Advanced silicon etching (ASE) was applied on the backside to create a mechanically stable support structure for the thin films. Performance evaluation was carried out for different gases in a temperature range of 20 C to 298 C at a constant differential pressure of 110 kPa at the two sides of the membrane. The composite membranes show an excellent permeation rate of hydrogen, which appears to be 0.05 Pa m{sup 3} s{sup -1} and 0.01.10{sup -3} Pa m{sup 3} s{sup -1} at 20 C for the microfabricated 23 % silver and the 53 % copper composite membranes, respectively. The selectivity to hydrogen over a gas mixture containing, in addition to hydrogen, carbon monoxide, carbon dioxide and nitrogen was measured. The mass spectrometer did not detect any CO{sub 2} or CO, showing that the membrane is completely hydrogen selective. The microfabricated membranes exhibit both high mechanical strength (they easily withstand pressures up to 4 bar) and high thermal stability (up to 650 C). (Abstract Copyright [2009], Wiley Periodicals, Inc.)

Hafnia-Based Nanostructured Thermal Barrier Coatings for Advanced Hydrogen Turbine Technology

Energy Technology Data Exchange (ETDEWEB)

Ramana, Chintalapalle; Choudhuri, Ahsan

2013-01-31

Thermal barrier coatings (TBCs) are critical technologies for future gas turbine engines of advanced coal based power generation systems. TBCs protect engine components and allow further increase in engine temperatures for higher efficiency. In this work, nanostructured HfO{sub 2}-based coatings, namely Y{sub 2}O{sub 3}-stabilized HfO{sub 2} (YSH), Gd{sub 2}O{sub 3}-stabilized HfO{sub 2} (GSH) and Y{sub 2}O{sub 3}-stabilized ZrO{sub 2}-HfO{sub 2} (YSZH) were investigated for potential TBC applications in hydrogen turbines. Experimental efforts are aimed at creating a fundamental understanding of these TBC materials. Nanostructured ceramic coatings of YSH, GSH and YSZH were grown by physical vapor deposition methods. The effects of processing parameters and ceramic composition on the microstructural evolution of YSH, GSH and YSZH nanostructured coatings was studied using combined X-ray diffraction (XRD) and Electron microscopy analyses. Efforts were directed to derive a detailed understanding of crystal-structure, morphology, and stability of the coatings. In addition, thermal conductivity as a function of composition in YSH, YSZH and GSH coatings was determined. Laboratory experiments using accelerated test environments were used to investigate the relative importance of various thermo-mechanical and thermo-chemical failure modes of TBCs. Effects of thermal cycling, oxidation and their complex interactions were evaluated using a syngas combustor rig.

Astronomie spatiale infrarouge, aujourd’hui et demain = Infrared space astronomy, today and tomorrow

CERN Document Server

Lequeux, J; David, F

2000-01-01

This book brings together the lectures given at the Les Houches summer school "Infrared space astronomy, today and tomorrow". It gives a wide overview of infrared astronomy, a wavelength domain crucial for studies of the solar system, stars at the beginning and end of their lives, interstellar matter and galaxies at all distances. Recent developments in observational techniques have been tremendous. The first contributions give an introduction to the basic physical processes and methods of detection and data processing. They are followed by a series of lectures dealing with the wide variety of astronomical objects that can be seen in the infrared.

OTEC to hydrogen fuel cells - A solar energy breakthrough

Science.gov (United States)

Roney, J. R.

Recent advances in fuel cell technology and development are discussed, which will enhance the Ocean Thermal Energy Conversion (OTEC)-hydrogen-fuel cell mode of energy utilization. Hydrogen obtained from the ocean solar thermal resources can either be liquified or converted to ammonia, thus providing a convenient mode of transport, similar to that of liquid petroleum. The hydrogen fuel cell can convert hydrogen to electric power at a wide range of scale, feeding either centralized or distributed systems. Although this system of hydrogen energy production and delivery has been examined with respect to the U.S.A., the international market, and especially developing countries, may represent the greatest opportunity for these future generating units.

An Advanced Wet Expansion Turbine for Hydrogen Liquefaction, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — This proposal is responsive to NASA SBIR Topic X10.01, specifically, the need for efficient small- to medium-scale hydrogen liquefaction technologies including...

Formic Acid as a Hydrogen Energy Carrier

KAUST Repository

Eppinger, Jö rg; Huang, Kuo-Wei

2016-01-01

The high volumetric capacity (S3 g H-2/L) and its low toxicity and flammability under ambient conditions make formic acid a promising hydrogen energy carrier. Particularly, in the past decade, significant advancements have been achieved in catalyst development for selective hydrogen generation from formic acid. This Perspective highlights the advantages of this approach with discussions focused on potential applications in the transportation sector together with analysis of technical requirements, limitations, and costs.

Formic Acid as a Hydrogen Energy Carrier

KAUST Repository

Eppinger, Jorg

2016-12-15

The high volumetric capacity (S3 g H-2/L) and its low toxicity and flammability under ambient conditions make formic acid a promising hydrogen energy carrier. Particularly, in the past decade, significant advancements have been achieved in catalyst development for selective hydrogen generation from formic acid. This Perspective highlights the advantages of this approach with discussions focused on potential applications in the transportation sector together with analysis of technical requirements, limitations, and costs.

Advanced Hydrogen Transport Membranes for Vision 21 Fossil Fuel Plants

Energy Technology Data Exchange (ETDEWEB)

Carl R. Evenson; Shane E. Roark

2006-03-31

The objective of this project was to develop an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. A family of hydrogen separation membranes was developed including single phase mixed conducting ceramics, ceramic/ceramic composites, cermet membranes, cermet membranes containing a hydrogen permeable metal, and intermediate temperature composite layered membranes. Each membrane type had different operating parameters, advantages, and disadvantages that were documented over the course of the project. Research on these membranes progressed from ceramics to cermets to intermediate temperature composite layered membranes. During this progression performance was increased from 0.01 mL x min{sup -1} x cm{sup -2} up to 423 mL x min{sup -1} x cm{sup -2}. Eltron and team membranes not only developed each membrane type, but also membrane surface catalysis and impurity tolerance, creation of thin film membranes, alternative applications such as membrane promoted alkane dehydrogenation, demonstration of scale-up testing, and complete engineering documentation including process and mechanical considerations necessary for inclusion of Eltron membranes in a full scale integrated gasification combined cycle power plant. The results of this project directly led to a new $15 million program funded by the Department of Energy. This new project will focus exclusively on scale-up of this technology as part of the FutureGen initiative.

It's the system, stupid! The architecture, the services, the currencies, the sources and 'why hydrogen'

Energy Technology Data Exchange (ETDEWEB)

Scott, D.S. [International Association for Hydrogen Energy, Victoria, British Columbia (Canada)

2009-07-01

'Full text:' Drawing from Smelling Land: The Hydrogen Defense Against Climate Catastrophe, the talk will introduce a novel view of energy system architecture, to use as a platform from which to better appreciate where we were yesterday, are today and, with luck, will be tomorrow. We will introduce and explain the key concept of energy 'currencies' - whose place in the energy system is seen from the figure below: Services - Services Technologies - Currencies - Transformer Technologies - Sources. The talk will review tragicomic Canadian examples of what happens when we forget the system, to focus only on its bits and piece. Many persist today. The discussion will explain why hydrogen systems are essential if we're to have a chance to escape climate catastrophe. Almost all today's proposals for deflecting climate disruption are, at best, bandaids. Any comprehensive solution must ultimately lead to zero CO{sub 2} emissions. That will require not just non-carbon energy sources but also non-carbon energy currencies. We already have the non-carbon currency electricity. But electricity can't fly airplanes, or push ships, and is a poor currency for road or rail. For these we'll need the non-carbon currency, hydrogen. Only hydrogen can allow the energy from non-carbon sources like hydraulic, nuclear, sunlight or wind, to fly airplanes - further, faster, safer and with larger payloads without the system emitting (in principle) a drop of CO{sub 2}. The synergies apparent with liquid-hydrogen fuelled aircraft exemplify the synergies of all hydrogen-fuelled transportation vehicles. On the way to this brilliant future, 'tether' hydrogen must play a vital role harvesting Canada's heavy oil reserves while minimizing collateral CO{sub 2} emissions. Later, 'neat' hydrogen systems will bring the brilliant future that will be the Hydrogen Age. The 20th century bequeathed us the wonders of the Electricity Age. The 21st

It's the system, stupid! The architecture, the services, the currencies, the sources and 'why hydrogen'

International Nuclear Information System (INIS)

Scott, D.S.

2009-01-01

'Full text:' Drawing from Smelling Land: The Hydrogen Defense Against Climate Catastrophe, the talk will introduce a novel view of energy system architecture, to use as a platform from which to better appreciate where we were yesterday, are today and, with luck, will be tomorrow. We will introduce and explain the key concept of energy 'currencies' - whose place in the energy system is seen from the figure below: Services - Services Technologies - Currencies - Transformer Technologies - Sources. The talk will review tragicomic Canadian examples of what happens when we forget the system, to focus only on its bits and piece. Many persist today. The discussion will explain why hydrogen systems are essential if we're to have a chance to escape climate catastrophe. Almost all today's proposals for deflecting climate disruption are, at best, bandaids. Any comprehensive solution must ultimately lead to zero CO 2 emissions. That will require not just non-carbon energy sources but also non-carbon energy currencies. We already have the non-carbon currency electricity. But electricity can't fly airplanes, or push ships, and is a poor currency for road or rail. For these we'll need the non-carbon currency, hydrogen. Only hydrogen can allow the energy from non-carbon sources like hydraulic, nuclear, sunlight or wind, to fly airplanes - further, faster, safer and with larger payloads without the system emitting (in principle) a drop of CO 2 . The synergies apparent with liquid-hydrogen fuelled aircraft exemplify the synergies of all hydrogen-fuelled transportation vehicles. On the way to this brilliant future, 'tether' hydrogen must play a vital role harvesting Canada's heavy oil reserves while minimizing collateral CO 2 emissions. Later, 'neat' hydrogen systems will bring the brilliant future that will be the Hydrogen Age. The 20th century bequeathed us the wonders of the Electricity Age. The 21st century is filled

Advanced CSiC composites for high-temperature nuclear heat transport with helium, molten salts, and sulphur-iodine thermochemical hydrogen process fluids

International Nuclear Information System (INIS)

Peterson, P.F.; Forsberg, Ch.W.; Pickard, P.S.

2004-01-01

This paper discusses the use of liquid-silicon-impregnated (LSI) carbon-carbon composites for the development of compact and inexpensive heat exchangers, piping, vessels and pumps capable of operating in the temperature range of 800 to 1 100 deg C with high-pressure helium, molten fluoride salts, and process fluids for sulfur-iodine thermochemical hydrogen production. LSI composites have several potentially attractive features, including ability to maintain nearly full mechanical strength to temperatures approaching 1 400 deg C, inexpensive and commercially available fabrication materials, and the capability for simple forming, machining and joining of carbon-carbon performs, which permits the fabrication of highly complex component geometries. In the near term, these materials may prove to be attractive for use with a molten-salt intermediate loop for the demonstration of hydrogen production with a gas-cooled high temperature reactor. In the longer term, these materials could be attractive for use with the molten-salt cooled advanced high temperature reactor, molten salt reactors, and fusion power plants. (author)

Hydrogen: it's now. Hydrogen, essential today, indispensable tomorrow. Power-to-Gas or how to meet the challenge of electricity storage. To develop hydrogen mobility. Hydrogen production modes and scope of application of the IED directive - Interview. Regulatory evolutions needed for an easier deployment of hydrogen energy technologies for a clean mobility. Support of the Community's policy to hydrogen and to fuel cells

International Nuclear Information System (INIS)

Mauberger, Pascal; Boucly, Philippe; Quint, Aliette; Pierre, Helene; Lucchese, Paul; Bouillon-Delporte, Valerie; Chauvet, Bertrand; Ferrari, Fabio; Boivin, Jean-Pierre

2015-01-01

Published by the French Association for Hydrogen and Fuel Cells (AFHYPAC), this document first outlines how hydrogen can reduce our dependence on fossil energies, how it supports the development of electric mobility to reduce CO 2 emissions by transports, how it enables a massive storage of energy as a support to renewable energies deployment and integration, and how hydrogen can be a competitiveness driver. Then two contributions address technical solutions, the first one being Power-to-Gas as a solution to energy storage (integration of renewable energies, a mean for massive storage of electricity, economic conditions making the first deployments feasible, huge social and economical benefits, necessity of creation of an adapted legal and economic framework), and the second one being the development of hydrogen-powered mobility (a major societal concern for air quality, strategies of car manufacturers in the world, necessity of a favourable framework, the situation of recharging infrastructures). Two contributions address the legal framework regarding hydrogen production modes and the scope of application of the European IED directive on industrial emissions, and the needed regulatory evolutions for an easier deployment of Hydrogen-energy technologies for a clean mobility. A last article comments the evolution of the support of European policies to hydrogen and fuel cells through R and d programs, presents the main support program (FCH JU) and its results, other European financing and support policy, and discusses perspectives, notably for possible financing mechanisms

Advanced High-Temperature Reactor for Production of Electricity and Hydrogen: Molten-Salt-Coolant, Graphite-Coated-Particle-Fuel

International Nuclear Information System (INIS)

Forsberg, C.W.

2002-01-01

The objective of the Advanced High-Temperature Reactor (AHTR) is to provide the very high temperatures necessary to enable low-cost (1) efficient thermochemical production of hydrogen and (2) efficient production of electricity. The proposed AHTR uses coated-particle graphite fuel similar to the fuel used in modular high-temperature gas-cooled reactors (MHTGRs), such as the General Atomics gas turbine-modular helium reactor (GT-MHR). However, unlike the MHTGRs, the AHTR uses a molten salt coolant with a pool configuration, similar to that of the PRISM liquid metal reactor. A multi-reheat helium Brayton (gas-turbine) cycle, with efficiencies >50%, is used to produce electricity. This approach (1) minimizes requirements for new technology development and (2) results in an advanced reactor concept that operates at essentially ambient pressures and at very high temperatures. The low-pressure molten-salt coolant, with its high heat capacity and natural circulation heat transfer capability, creates the potential for (1) exceptionally robust safety (including passive decay-heat removal) and (2) allows scaling to large reactor sizes [∼1000 Mw(e)] with passive safety systems to provide the potential for improved economics

Chemochromic Hydrogen Leak Detectors

Science.gov (United States)

Roberson, Luke; Captain, Janine; Williams, Martha; Smith, Trent; Tate, LaNetra; Raissi, Ali; Mohajeri, Nahid; Muradov, Nazim; Bokerman, Gary

2009-01-01

At NASA, hydrogen safety is a key concern for space shuttle processing. Leaks of any level must be quickly recognized and addressed due to hydrogen s lower explosion limit. Chemo - chromic devices have been developed to detect hydrogen gas in several embodiments. Because hydrogen is odorless and colorless and poses an explosion hazard, there is an emerging need for sensors to quickly and accurately detect low levels of leaking hydrogen in fuel cells and other advanced energy- generating systems in which hydrogen is used as fuel. The device incorporates a chemo - chromic pigment into a base polymer. The article can reversibly or irreversibly change color upon exposure to hydrogen. The irreversible pigment changes color from a light beige to a dark gray. The sensitivity of the pigment can be tailored to its application by altering its exposure to gas through the incorporation of one or more additives or polymer matrix. Furthermore, through the incorporation of insulating additives, the chemochromic sensor can operate at cryogenic temperatures as low as 78 K. A chemochromic detector of this type can be manufactured into any feasible polymer part including injection molded plastic parts, fiber-spun textiles, or extruded tapes. The detectors are simple, inexpensive, portable, and do not require an external power source. The chemochromic detectors were installed and removed easily at the KSC launch pad without need for special expertise. These detectors may require an external monitor such as the human eye, camera, or electronic detector; however, they could be left in place, unmonitored, and examined later for color change to determine whether there had been exposure to hydrogen. In one type of envisioned application, chemochromic detectors would be fabricated as outer layers (e.g., casings or coatings) on high-pressure hydrogen storage tanks and other components of hydrogen-handling systems to provide visible indications of hydrogen leaks caused by fatigue failures or

Hydrogen control in the System 80+TM ALWR design

International Nuclear Information System (INIS)

Schneider, R.E.; Jacob, M.C.; Carpentino, F.L.; Wachowiak, R.M.

2004-01-01

This paper provides an assessment of the features built into the System 80 +TM Advanced Light Water Reactor (ALWR) design for controlling hydrogen concentration during a hypothetical severe accident. Although the significantly larger System 80 + containment volume serves to passively maintain the global average below detonable limits, the design incorporates a Hydrogen Mitigation System (HMS) to further reduce the local hydrogen concentration. The HMS consists of a large number of hydrogen ignitors distributed within the containment to selectively burn-off hydrogen at low concentrations. The criteria for the placement of these igniters are discussed along with an assessment of the effectiveness of the igniters to control the hydrogen concentrations. This assessment, which was performed using the generalized containment model of the MAAP 4 code, evaluated the potential for hydrogen build-up in the containment and calculated the best-estimate response of the igniters. (author)

Overview of the U.S. DOE Hydrogen Safety, Codes and Standards Program. Part 4: Hydrogen Sensors; Preprint

Energy Technology Data Exchange (ETDEWEB)

Buttner, William J.; Rivkin, Carl; Burgess, Robert; Brosha, Eric; Mukundan, Rangachary; James, C. Will; Keller, Jay

2016-12-01

Hydrogen sensors are recognized as a critical element in the safety design for any hydrogen system. In this role, sensors can perform several important functions including indication of unintended hydrogen releases, activation of mitigation strategies to preclude the development of dangerous situations, activation of alarm systems and communication to first responders, and to initiate system shutdown. The functionality of hydrogen sensors in this capacity is decoupled from the system being monitored, thereby providing an independent safety component that is not affected by the system itself. The importance of hydrogen sensors has been recognized by DOE and by the Fuel Cell Technologies Office's Safety and Codes Standards (SCS) program in particular, which has for several years supported hydrogen safety sensor research and development. The SCS hydrogen sensor programs are currently led by the National Renewable Energy Laboratory, Los Alamos National Laboratory, and Lawrence Livermore National Laboratory. The current SCS sensor program encompasses the full range of issues related to safety sensors, including development of advance sensor platforms with exemplary performance, development of sensor-related code and standards, outreach to stakeholders on the role sensors play in facilitating deployment, technology evaluation, and support on the proper selection and use of sensors.

Purdue Hydrogen Systems Laboratory

Energy Technology Data Exchange (ETDEWEB)

Jay P Gore; Robert Kramer; Timothee L Pourpoint; P. V. Ramachandran; Arvind Varma; Yuan Zheng

2011-12-28

The Hydrogen Systems Laboratory in a unique partnership between Purdue University's main campus in West Lafayette and the Calumet campus was established and its capabilities were enhanced towards technology demonstrators. The laboratory engaged in basic research in hydrogen production and storage and initiated engineering systems research with performance goals established as per the USDOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program. In the chemical storage and recycling part of the project, we worked towards maximum recycling yield via novel chemical selection and novel recycling pathways. With the basic potential of a large hydrogen yield from AB, we used it as an example chemical but have also discovered its limitations. Further, we discovered alternate storage chemicals that appear to have advantages over AB. We improved the slurry hydrolysis approach by using advanced slurry/solution mixing techniques. We demonstrated vehicle scale aqueous and non-aqueous slurry reactors to address various engineering issues in on-board chemical hydrogen storage systems. We measured the thermal properties of raw and spent AB. Further, we conducted experiments to determine reaction mechanisms and kinetics of hydrothermolysis in hydride-rich solutions and slurries. We also developed a continuous flow reactor and a laboratory scale fuel cell power generation system. The biological hydrogen production work summarized as Task 4.0 below, included investigating optimal hydrogen production cultures for different substrates, reducing the water content in the substrate, and integrating results from vacuum tube solar collector based pre and post processing tests into an enhanced energy system model. An automated testing device was used to finalize optimal hydrogen production conditions using statistical procedures. A 3 L commercial fermentor (New Brunswick, BioFlo 115) was used to finalize testing of larger samples and to consider issues related to scale up

Purdue Hydrogen Systems Laboratory

International Nuclear Information System (INIS)

Gore, Jay P.; Kramer, Robert; Pourpoint, Timothee L.; Ramachandran, P.V.; Varma, Arvind; Zheng, Yuan

2011-01-01

The Hydrogen Systems Laboratory in a unique partnership between Purdue University's main campus in West Lafayette and the Calumet campus was established and its capabilities were enhanced towards technology demonstrators. The laboratory engaged in basic research in hydrogen production and storage and initiated engineering systems research with performance goals established as per the USDOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program. In the chemical storage and recycling part of the project, we worked towards maximum recycling yield via novel chemical selection and novel recycling pathways. With the basic potential of a large hydrogen yield from AB, we used it as an example chemical but have also discovered its limitations. Further, we discovered alternate storage chemicals that appear to have advantages over AB. We improved the slurry hydrolysis approach by using advanced slurry/solution mixing techniques. We demonstrated vehicle scale aqueous and non-aqueous slurry reactors to address various engineering issues in on-board chemical hydrogen storage systems. We measured the thermal properties of raw and spent AB. Further, we conducted experiments to determine reaction mechanisms and kinetics of hydrothermolysis in hydride-rich solutions and slurries. We also developed a continuous flow reactor and a laboratory scale fuel cell power generation system. The biological hydrogen production work summarized as Task 4.0 below, included investigating optimal hydrogen production cultures for different substrates, reducing the water content in the substrate, and integrating results from vacuum tube solar collector based pre and post processing tests into an enhanced energy system model. An automated testing device was used to finalize optimal hydrogen production conditions using statistical procedures. A 3 L commercial fermentor (New Brunswick, BioFlo 115) was used to finalize testing of larger samples and to consider issues related to scale up. Efforts

Hydrogen at extreme pressures (Review Article)

International Nuclear Information System (INIS)

Goncharov, Alexander F.; Howie, Ross T.; Gregoryanz Eugene

2013-01-01

Here we review recent experimental and theoretical studies of hydrogen approaching metallization regime. Experimental techniques have made great advances over the last several years making it possible to reach previously unachievable conditions of pressure and temperature and to probe hydrogen at these conditions. Theoretical methods have also greatly improved; exemplified through the prediction of new structural and ordered quantum states. Recently, a new solid phase of hydrogen, phase IV, has been discovered in a high-pressure high-temperature domain. This phase is quite unusual structurally and chemically as it represents an intermediate state between common molecular and monatomic configurations. Moreover, it shows remarkable fluxional characteristics related to its quantum nature, which makes it unique among the solid phases, even of light elements. However, phase IV shows the presence of a band gap and exhibits distinct phonon and libron characteristic of classical solids. The quantum behavior of hydrogen in the limit of very high pressure remains an open question. Prospects of studying hydrogen at more extreme conditions by static and combined static-dynamic methods are also presented.

Physical activity education in the undergraduate curricula of all UK medical schools: are tomorrow's doctors equipped to follow clinical guidelines?

Science.gov (United States)

Weiler, Richard; Chew, Stephen; Coombs, Ngaire; Hamer, Mark; Stamatakis, Emmanuel

2012-11-01

Physical activity (PA) is a cornerstone of disease prevention and treatment. There is, however, a considerable disparity between public health policy, clinical guidelines and the delivery of physical activity promotion within the National Health Service in the UK. If this is to be addressed in the battle against non-communicable diseases, it is vital that tomorrow's doctors understand the basic science and health benefits of physical activity. The aim of this study was to assess the provision of physical activity teaching content in the curricula of all medical schools in the UK. Our results, with responses from all UK medical schools, uncovered some alarming findings, showing that there is widespread omission of basic teaching elements, such as the Chief Medical Officer recommendations and guidance on physical activity. There is an urgent need for physical activity teaching to have dedicated time at medical schools, to equip tomorrow's doctors with the basic knowledge, confidence and skills to promote physical activity and follow numerous clinical guidelines that support physical activity promotion.

Bringing Real World Underwater Science, Engineering and Technology in Tomorrow's Classroom

Science.gov (United States)

Livingston, C.

2012-04-01

What do Remotely Operated Vehicles (ROVs), Ocean Science, Engineering and Technology have in common with science education in today's classroom? They all meet the growing demand for science, technology, engineering, and mathematics (STEM) professionals in tomorrow's U.S. workforce. Engaging students in real world science experiences will help them develop skills such as critical thinking, problem solving, collaboration, communication, innovation, and creativity. These skills are crucial to building a strong, competitive workforce in an integrated global economy. Fifth grade students from St. Andrew's School of Math and Science in Charleston, SC, USA science classes were introduced to engineering and robotics by using a combination of two underwater ROVs programs from the Office of Naval Research (SeaPerch) and Marine Advanced Technology Education (MATE). Students were grouped in teams as "real scientists" to design and construct a ROV. Students selected their role from a list of engineering positions, and researched how to construct the best ROV. Students created blueprints and models of their ROV design. Scientists/engineers from various local agencies were scheduled to come and share their expertise with the students. On World Ocean Day, a presentation was planned for fifth grade students to work closely with kindergarten through fourth grade students. The purpose of the day was two-fold; it provided students the opportunity to peer teach and the opportunity to present their experiences to a wide audience. All students presented their designs and demonstrated their ROV's movement capabilities in child size pools. They also modeled how submersible pilots communicate with scientists and other researchers while operating their newly designed ROV. As a culminating event, students visited a local marine science high school class with similar ROVs and evaluated their engineering designs in a fresh water pond.

'Will I want these stickers tomorrow?' Preschoolers' ability to predict current and future needs.

Science.gov (United States)

Martin-Ordas, Gema

2017-11-01

Between 3 and 5 years of age, children develop the ability to plan for their own and others' future needs; however, they have great difficulty predicting future needs that conflict with current ones. Importantly, this ability has only been tested in the domain of physiological states (e.g., thirst). Therefore, it is still an open question whether in a different context preschoolers can disengage from their current needs to secure a different future one. In a Resource Allocation task, 4- and 5-year-olds had to distribute three types of rewards between themselves and another child for either 'right now' or 'tomorrow'. Children's current needs were manipulated by providing them (or not) with their preferred reward at beginning of the task. Only 5-year-olds could predict future needs that conflict with their current ones and act accordingly. Younger children's performance is discussed in the context of temporal and social distance. Statement of contribution What is already known on this subject? By the age of 4, children can plan for their own and others' future needs. Seven-year-old children still have difficulty predicting future physiological needs that conflict with their current ones. What does this study add? In a Resource Allocation task, preschoolers had to share rewards with another child for 'right now' or 'tomorrow'. Children's current needs were manipulated by providing them (or not) with their preferred reward. This study shows that 5-year-olds can predict future (non-physiological) needs that conflict with their current ones. © 2017 The British Psychological Society.

Photovoltaic hydrogen production

Energy Technology Data Exchange (ETDEWEB)

Hiser, H.W.; Memory, S.B.; Veziroglu, T.N.; Padin, J. [Univ. of Miami, Coral Gables, FL (United States)

1996-10-01

This is a new project, which started in June 1995, and involves photovoltaic hydrogen production as a fuel production method for the future. In order to increase the hydrogen yield, it was decided to use hybrid solar collectors to generate D.C. electricity, as well as high temperature steam for input to the electrolyzer. In this way, some of the energy needed to dissociate the water is supplied in the form of heat (or low grade energy), to generate steam, which results in a reduction of electrical energy (or high grade energy) needed. As a result, solar to hydrogen conversion efficiency is increased. In the above stated system, the collector location, the collector tracking sub-system (i.e., orientation/rotation), and the steam temperature have been taken as variables. Five locations selected - in order to consider a variety of latitudes, altitudes, cloud coverage and atmospheric conditions - are Atlanta, Denver, Miami, Phoenix and Salt Lake City. Plain PV and hybrid solar collectors for a stationary south facing system and five different collector rotation systems have been analyzed. Steam temperatures have been varied between 200{degrees}C and 1200{degrees}C. During the first year, solar to hydrogen conversion efficiencies have been considered. The results show that higher steam temperatures, 2 dimensional tracking system, higher elevations and dryer climates causes higher conversion efficiencies. Cost effectiveness of the sub-systems and of the overall system will be analyzed during the second year. Also, initial studies will be made of an advanced high efficiency hybrid solar hydrogen production system.

Hydrogen Production Using Nuclear Energy

Energy Technology Data Exchange (ETDEWEB)

Verfondern, K. [Research Centre Juelich (Germany)

2013-03-15

One of the IAEA's statutory objectives is to 'seek to accelerate and enlarge the contribution of atomic energy to peace, health and prosperity throughout the world.' One way this objective is achieved is through the publication of a range of technical series. Two of these are the IAEA Nuclear Energy Series and the IAEA Safety Standards Series. According to Article III.A.6 of the IAEA Statute, the safety standards establish 'standards of safety for protection of health and minimization of danger to life and property'. The safety standards include the Safety Fundamentals, Safety Requirements and Safety Guides. These standards are written primarily in a regulatory style, and are binding on the IAEA for its own programmes. The principal users are the regulatory bodies in Member States and other national authorities. The IAEA Nuclear Energy Series comprises reports designed to encourage and assist R and D on, and application of, nuclear energy for peaceful uses. This includes practical examples to be used by owners and operators of utilities in Member States, implementing organizations, academia, and government officials, among others. This information is presented in guides, reports on technology status and advances, and best practices for peaceful uses of nuclear energy based on inputs from international experts. The IAEA Nuclear Energy Series complements the IAEA Safety Standards Series. Nuclear generated hydrogen has important potential advantages over other sources that will be considered for a growing hydrogen share in a future world energy economy. Still, there are technical uncertainties in nuclear hydrogen processes that need to be addressed through a vigorous research and development effort. Safety issues as well as hydrogen storage and distribution are important areas of research to be undertaken to support a successful hydrogen economy in the future. The hydrogen economy is gaining higher visibility and stronger political support in several parts of the

Young community of EACVI: the transition from EACVI Club 35 to Heart Imagers of Tomorrow: a promising yet challenging step.

Science.gov (United States)

Grapsa, Julia; Cameli, Matteo; Granier, Camille; Muraru, Denisa; Ernande, Laura; Popescu, Bogdan A; Lancellotti, Patrizio; Habib, Gilbert

2016-02-01

The purpose of this review is to summarize the activity and potential of the young community of European Association of Cardiovascular Imaging and to highlight the transition from Club 35 to 'Heart Imagers of tomorrow'. Published on behalf of the European Society of Cardiology. All rights reserved. © The Author 2015. For permissions please email: journals.permissions@oup.com.

Progress of Nuclear Hydrogen Program in Korea

International Nuclear Information System (INIS)

Lee, Won Jae

2009-01-01

To cope with dwindling fossil fuels and climate change, it is clear that a clean alternative energy that can replace fossil fuels is required. Hydrogen is considered a promising future energy solution because it is clean, abundant and storable and has a high energy density. As other advanced countries, the Korean government had established a long-term vision for transition to the hydrogen economy in 2005. One of the major challenges in establishing a hydrogen economy is how to produce massive quantities of hydrogen in a clean, safe and economical way. Among various hydrogen production methods, the massive, safe and economic production of hydrogen by water splitting using a very high temperature gas-cooled reactor (VHTR) can provide a success path to the hydrogen economy. Particularly in Korea, where usable land is limited, the nuclear production of hydrogen is deemed a practical solution due to its high energy density. To meet the expected demand for hydrogen, the Korea Atomic Energy Institute (KAERI) launched a nuclear hydrogen program in 2004 together with Korea Institute of Energy Research (KIER) and Korea Institute of Science and Technology (KIST). Then, the nuclear hydrogen key technologies development program was launched in 2006, which aims at the development and validation of key and challenging technologies required for the realization of the nuclear hydrogen production demonstration system. In 2008, Korean Atomic Energy Commission officially approved a long-term development plan of the nuclear hydrogen system technologies as in the figure below and now the nuclear hydrogen program became the national agenda. This presentation introduces the current status of nuclear hydrogen projects in Korea and the progress of the nuclear hydrogen key technologies development. Perspectives of nuclear process heat applications are also addressed

Blockbuster starring ESO Paranal opens tomorrow

Science.gov (United States)

2008-10-01

The 22nd James Bond adventure is due for release tomorrow, 31 October 2008, in the UK and a week later in the rest of the world. A key location in the movie is the Residencia, the hotel for astronomers and staff at ESO's Paranal Observatory. Blockbuster starring ESO Paranal opens tomorrow ESO PR Photo 38/08 The James Bond "Quantum of Solace" filmmakers Quantum of Solace is the latest film in one of most successful movie franchises -- that of renowned 007 Agent James Bond of the British Secret Service MI6. The agent "on Her Majesty's secret service" is once again played by Daniel Craig. Key scenes of the movie were filmed at Paranal, the home of ESO's Very Large Telescope, and the most advanced optical telescope in the world. Usually occupied by no more than 100 astronomers, engineers and technicians, Paranal welcomed the 300-strong film crew for several days of shooting at the end of March 2008. The crew travelled from their hotel base in Antofagasta for up to two hours each morning to reach the filming locations. "We are delighted to have a movie like this filmed at Paranal and it was extremely good to see how careful the crew were with the surroundings and how mindful they were of the fact that they were in an operating, working observatory", says Tim de Zeeuw, ESO Director General. "Paranal is a unique observatory in a unique setting and it is no real surprise that it plays a major part in a James Bond movie", he adds. The filmmakers were mostly interested in filming exterior scenes at the Paranal Residencia, the accommodation for staff operating the Very Large Telescope. In the movie, the Residencia is supposedly the "Perla de Las Dunas", a unique hotel in the desert. Cerro Paranal is a 2600 m high mountain in the Chilean Atacama Desert, perhaps the driest on Earth. The high altitude site and extreme dryness make excellent conditions for astronomical observations. To make it possible for people to live and work here, a hotel, or Residencia, was built at the

Advances in ethanol reforming for the production of hydrogen

Directory of Open Access Journals (Sweden)

Laura Guerrero

2014-06-01

Full Text Available Catalytic steam reforming of ethanol (SRE is a promising route for the production of renewable hydrogen (H2. This article reviews the influence of doping supported-catalysts used in SRE on the conversion of ethanol, selectivity for H2, and stability during long reaction periods. In addition, promising new technologies such as membrane reactors and electrochemical reforming for performing SRE are presented.

Advances in nickel hydrogen technology at Yardney Battery Division

Science.gov (United States)

Bentley, J. G.; Hall, A. M.

1987-01-01

The current major activites in nickel hydrogen technology being addressed at Yardney Battery Division are outlined. Five basic topics are covered: an update on life cycle testing of ManTech 50 AH NiH2 cells in the LEO regime; an overview of the Air Force/industry briefing; nickel electrode process upgrading; 4.5 inch cell development; and bipolar NiH2 battery development.

Revisiting the solar hydrogen alternative

Energy Technology Data Exchange (ETDEWEB)

Tomkiewicz, M. [Brooklyn College of CUNY, NY (United States)

1996-09-01

Research aimed at the development of technology to advance the solar-hydrogen alternative is per definition mission oriented. The priority that society puts on such research rise and fall with the priorities that we associate with the mission. The mission that we associate with the hydrogen economy is to provide a technological option for an indefinitely sustainable energy and material economies in which society is in equilibrium with its environment. In this paper we try to examine some global aspects of the hydrogen alternative and recommend formulation of a {open_quotes}rational{close_quotes} tax and regulatory system that is based on efforts needed to restore the ecological balance. Such a system, once entered into the price structure of the alternative energy schemes, will be used as a standard to compare energy systems that in turn will serve as a base for prioritization of publicly supported research and development.

Hydrogen by electrolysis of water

Science.gov (United States)

1975-01-01

Hydrogen production by electrolytic decomposition of water is explained. Power efficiency, efficient energy utilization, and costs were emphasized. Four systems were considered: two were based on current electrolyzer technology using present efficiency values for electrical generation by fossil fired and nuclear thermal stations, and two using projected electrolyzer technology with advanced fossil and nuclear plants.

In France, 37 nuclear reactors out of 58 can be stopped right away tomorrow without electricity outage. How is it possible? Mathematical demonstration of an electric scenario 'right-away Tomorrow'

International Nuclear Information System (INIS)

Houpert, Sylvain

2013-12-01

According to the 'Des demain' (right-away tomorrow), this document indicates data related to nuclear electric power in France (production, export, self-consumption, loss due to Fessenheim shut down, to the production of other electricity production plants (from coal, gas, oil, biomass, wind, sun). From these data, it states that France could operate with 1 nuclear reactor out of 3 (whereas Japan has stopped 98 pc of its reactors after the Fukushima accident). This result and its possible consequences are then discussed, and the 'Des demain' scenario is then presented in terms of electric power production for the 20 years to come, CO 2 emissions for the next 20 years, energy transition and renewable energies in France in 2012

Advanced gasifier and water gas shift technologies for low cost coal conversion to high hydrogen syngas

Energy Technology Data Exchange (ETDEWEB)

Kramer, Andrew Kramer [Gas Technology Inst., Des Plaines, IL (United States)

2016-09-30

The Gas Technology Institute (GTI) and team members RTI International (RTI), Coanda Research and Development, and Nexant, are developing and maturing a portfolio of technologies to meet the United States Department of Energy (DOE) goals for lowering the cost of producing high hydrogen syngas from coal for use in carbon capture power and coal-to-liquids/chemicals. This project matured an advanced pilot-scale gasifier, with scalable and commercially traceable components, to readiness for use in a first-of-a-kind commercially-relevant demonstration plant on the scale of 500-1,000 tons per day (TPD). This was accomplished through cold flow simulation of the gasifier quench zone transition region at Coanda and through an extensive hotfire gasifier test program on highly reactive coal and high ash/high ash fusion temperature coals at GTI. RTI matured an advanced water gas shift process and catalyst to readiness for testing at pilot plant scale through catalyst development and testing, and development of a preliminary design basis for a pilot scale reactor demonstrating the catalyst. A techno-economic analysis was performed by Nexant to assess the potential benefits of the gasifier and catalyst technologies in the context of power production and methanol production. This analysis showed an 18%reduction in cost of power and a 19%reduction in cost of methanol relative to DOE reference baseline cases.

Hydrogen problems related to reactor accidents

International Nuclear Information System (INIS)

Bujor, A.

1993-09-01

At reactor accidents, the combustion of hydrogen causes pressure and temperature transients which pose supplementary loads in containment. In certain conditions, they could reach hazardous levels and impair the integrity of the containment and the operability of the safety systems. The mechanisms of chemical reactions specific for the hydrogen-oxygen system are presented. Conditions in which combustion can occur and the various combustion modes, including the transition to detonation are also described. The related safety aspects and mitigation methods are discussed. Examples for particular applications and safety approaches for various types of reactors, included those promoted for the advanced reactors are also given. Presentation of the experimental research completed at AECL-Research, Whiteshell Laboratory is given, where the multi-point ignition effects for constant volume and for vented combustion of dry hydrogen-air mixtures in various geometries have been investigated. Various aspects of modelling and simulation of hydrogen combustion are discussed. The adaptations and the new models implemented in the codes VENT and CONTAIN, aimed to widen the simulation capabilities of hydrogen combustion models are described. The capabilities and limitations of the modelling assumptions of these two codes are also evaluated. (EG) (11 tabs., 39 ills., 82 refs.)

Curricular Critique of an Environmental Education Policy Framework: Acting Today, Shaping Tomorrow

Directory of Open Access Journals (Sweden)

Douglas D. Karrow

2015-10-01

Full Text Available The following paper is a curricular critique of an environmental education policy framework called Acting Today, Shaping Tomorrow (2009. It is founded upon: (a an examination of the conventional argument for integrated curriculum models and its relevance to K-12 environmental education; and (b utilization of a typology of integrated curriculum models to analyze an environmental education policy framework within the jurisdiction of Ontario, Canada. In conclusion, Ontario’s environmental education policy framework tends toward an integrated curriculum model referred to as ‘selective infusion.’  The implications for integrated curricular practice are identified, with recommendations for improving the policy framework from an integrated curricular perspective.     Key Words: environmental education, integrated curriculum, curriculum critique, education policy.

A strategy for introducing hydrogen into transportation

International Nuclear Information System (INIS)

Farrell, A.E.; Keith, D.W.; Corbett, J.J.

2003-01-01

Considerable effort is being expended on research and demonstration projects aimed at introducing hydrogen into the transportation sector as a fuel, generally motivated by concerns about carbon dioxide emissions and petroleum imports (or scarcity). In this paper we focus on one aspect of strategy for introducing hydrogen--the choice of transportation mode. Our analysis suggests that cost of introducing hydrogen can be reduced by selecting a mode that uses a small number of relatively large vehicles that are operated by professional crews along a limited number of point-to-point routes or within a small geographic area. In addition, technological innovation in vehicle design will take place most quickly in modes where individual vehicles are produced to order and each receives significant engineering attention (not those manufactured in vast quantities on assembly lines). The immediate environmental benefits of introducing hydrogen fuel will occur in modes that have relatively less stringent pollution regulations applied to them. These insights, suggest that heavy-duty freight modes would be a less costly way to introduce hydrogen as a transportation fuel and a more effective way to advance hydrogen-related technologies so that they could subsequently be used more widely in light-duty vehicles

Prospects on hydrogen production for a generalized domestic, industrial and automotive, usage

Science.gov (United States)

Dini, D.

Assuming the availability of advanced nuclear and solar systems as prime energy sources for electrolytic production of hydrogen, an assessment is made of high pressure electrolytic gasification, liquefaction and storage work requirements. Also, a pipeline network and associated equipment for the delivery and storage of hydrogen are considered in the context of a future replacement of all fossil fuels by hydrogen. Attention is given to space-based systems and terrestrial photovoltaics.

Applied hydrogen storage research and development: A perspective from the U.S. Department of Energy

International Nuclear Information System (INIS)

O’Malley, Kathleen; Ordaz, Grace; Adams, Jesse; Randolph, Katie; Ahn, Channing C.; Stetson, Ned T.

2015-01-01

Highlights: • Overview of U.S. DOE-supported hydrogen storage technology development efforts. • Physical and materials-based strategy for developing hydrogen storage systems. • Materials requirements for automotive storage systems. • Key R&D developments. - Abstract: To enable the wide-spread commercialization of hydrogen fuel cell technologies, the U.S. Department of Energy, through the Office of Energy Efficiency and Renewable Energy’s Fuel Cell Technology Office, maintains a comprehensive portfolio of R&D activities to develop advanced hydrogen storage technologies. The primary focus of the Hydrogen Storage Program is development of technologies to meet the challenging onboard storage requirements for hydrogen fuel cell electric vehicles (FCEVs) to meet vehicle performance that consumers have come to expect. Performance targets have also been established for materials handling equipment (e.g., forklifts) and low-power, portable fuel cell applications. With the imminent release of commercial FCEVs by automobile manufacturers in regional markets, a dual strategy is being pursued to (a) lower the cost and improve performance of high-pressure compressed hydrogen storage systems while (b) continuing efforts on advanced storage technologies that have potential to surpass the performance of ambient compressed hydrogen storage

Applied hydrogen storage research and development: A perspective from the U.S. Department of Energy

Energy Technology Data Exchange (ETDEWEB)

O’Malley, Kathleen [SRA International, Inc., Fairfax, VA 22033 (United States); Ordaz, Grace; Adams, Jesse; Randolph, Katie [U.S. Department of Energy, 1000 Independence Ave., SW, EE-3F, Washington, DC 20585 (United States); Ahn, Channing C. [U.S. Department of Energy, 1000 Independence Ave., SW, EE-3F, Washington, DC 20585 (United States); California Institute of Technology, Pasadena, CA 91125 (United States); Stetson, Ned T., E-mail: Ned.Stetson@ee.doe.gov [U.S. Department of Energy, 1000 Independence Ave., SW, EE-3F, Washington, DC 20585 (United States)

2015-10-05

Highlights: • Overview of U.S. DOE-supported hydrogen storage technology development efforts. • Physical and materials-based strategy for developing hydrogen storage systems. • Materials requirements for automotive storage systems. • Key R&D developments. - Abstract: To enable the wide-spread commercialization of hydrogen fuel cell technologies, the U.S. Department of Energy, through the Office of Energy Efficiency and Renewable Energy’s Fuel Cell Technology Office, maintains a comprehensive portfolio of R&D activities to develop advanced hydrogen storage technologies. The primary focus of the Hydrogen Storage Program is development of technologies to meet the challenging onboard storage requirements for hydrogen fuel cell electric vehicles (FCEVs) to meet vehicle performance that consumers have come to expect. Performance targets have also been established for materials handling equipment (e.g., forklifts) and low-power, portable fuel cell applications. With the imminent release of commercial FCEVs by automobile manufacturers in regional markets, a dual strategy is being pursued to (a) lower the cost and improve performance of high-pressure compressed hydrogen storage systems while (b) continuing efforts on advanced storage technologies that have potential to surpass the performance of ambient compressed hydrogen storage.

Well-to-Wheel Analysis of Solar Hydrogen Production and Utilization for Passenger Car Transportation

Energy Technology Data Exchange (ETDEWEB)

Felder, R.; Meier, A.

2006-07-01

A well-to-wheel analysis is conducted for solar hydrogen production, transport, and usage in future passenger car transportation. Solar hydrogen production methods and selected conventional production Technologies are examined using a life cycle assessment (LCA). Utilization of hydrogen in fuel cells is compared with advanced gasoline and diesel power trains. Solar scenarios show distinctly lower greenhouse gas (GHG) emissions than fossil-based scenarios. For example, using solar hydrogen in fuel cell cars reduces life cycle GHG emissions by 75% compared to advanced fossil fuel power trains and by more than 90% if car and road infrastructure are not considered. Solar hydrogen production allows a reduction of fossil energy requirements by a factor of up to 10 compared to using conventional Technologies. Major environmental impacts are associated with the construction of the steel-intensive infrastructure for solar energy collection due to mineral and fossil resource consumption as well as discharge of pollutants related to today's steel production technology. (Author)

Novel, Ceramic Membrane System For Hydrogen Separation

Energy Technology Data Exchange (ETDEWEB)

Elangovan, S.

2012-12-31

Separation of hydrogen from coal gas represents one of the most promising ways to produce alternative sources of fuel. Ceramatec, teamed with CoorsTek and Sandia National Laboratories has developed materials technology for a pressure driven, high temperature proton-electron mixed conducting membrane system to remove hydrogen from the syngas. This system separates high purity hydrogen and isolates high pressure CO{sub 2} as the retentate, which is amenable to low cost capture and transport to storage sites. The team demonstrated a highly efficient, pressure-driven hydrogen separation membrane to generate high purity hydrogen from syngas using a novel ceramic-ceramic composite membrane. Recognizing the benefits and limitations of present membrane systems, the all-ceramic system has been developed to address the key technical challenges related to materials performance under actual operating conditions, while retaining the advantages of thermal and process compatibility offered by the ceramic membranes. The feasibility of the concept has already been demonstrated at Ceramatec. This project developed advanced materials composition for potential integration with water gas shift rectors to maximize the hydrogenproduction.

A study on the hydrogen distributions in a containment for nuclear plant severe accidents

Energy Technology Data Exchange (ETDEWEB)

Park, Kweon Ha; Kim, Ju Youn; Bae, Kyung Hyo [The Korea Maritime Univ., Busan (Korea, Republic of)

2012-10-15

Hydrogen explosion has been considered as one of the major issues since Fukushima nuclear accident. The cause of the explosion has not been discovered, but it is clear that the explosion strongly depends on hydrogen distributions in a containment. In this study hydrogen distributions are calculated and analyzed in the containment of APR 1400(Advanced Power Reactor 1400)

Surface hardening of Ti-6Al-4V alloy by hydrogenation

International Nuclear Information System (INIS)

Wu, T.I.; Wu, J.K.

1991-01-01

Thermochemical processing is an advanced method to enhance the fabricability and mechanical properties of titanium alloys. In this process hydrogen is added to the titanium alloy as a temporary alloying element. Hydrogen addition lowers the β transus temperature of titanium alloy and stabilizes the β phase. The increased amount of β phase in hydrogen-modified titanium alloys reduces the grain growth rate during eutectoid β → α + hydride reaction. Hydrogen was added to the titanium alloy by holding it at a relatively high temperature in a hydrogen gaseous environment in previous studies. Pattinato reported that Ti-6Al-4V alloy can react with hydrogen gas at ambient temperature and cause a serious hydrogen embrittlement problem. The hydrogen must be removed to a low allowable concentration in a vacuum system after the hydrogenation process. The present study utilized an electrochemical technique to dissolve hydrogen into titanium alloy to replace the hydrogen environment in thermochemical processing. In this paper microstructures and hardnesses of this new processed Ti-6Al-4V alloy are reported

Biomass of tomorrow: Banknotes. Two new disposal methods as an alternative to combustion. Die Biomasse von morgen: Banknoten. Zwei neue Verwertungsverfahren als Alternative zur Verbrennung

Energy Technology Data Exchange (ETDEWEB)

Franken, M.

1999-06-01

Old banknotes may be tomorrow's biomass. Experts on biowaste are investigating two new processes for disposal of the 1000 tonnes of old bills sorted out every year which may be an alternative to combustion. The author presents details.

Schrodinger Equation Solutions that Lead to the Solution for the Hydrogen Atom

Science.gov (United States)

Newhouse, Paul F.; McGill, K.C.

2004-01-01

Two exercises that would provide beginning quantum theory students with an introduction to more advanced quantum mechanical treatments, especially the hydrogen atom are given. The exercises are stepwise in difficulty, leading naturally to the full hydrogen atom development and greatly extend the pedagogy of most multidimensional Cartesian systems…

Hydrogen Production from Semiconductor-based Photocatalysis via Water Splitting

Directory of Open Access Journals (Sweden)

Jeffrey C. S. Wu

2012-10-01

Full Text Available Hydrogen is the ideal fuel for the future because it is clean, energy efficient, and abundant in nature. While various technologies can be used to generate hydrogen, only some of them can be considered environmentally friendly. Recently, solar hydrogen generated via photocatalytic water splitting has attracted tremendous attention and has been extensively studied because of its great potential for low-cost and clean hydrogen production. This paper gives a comprehensive review of the development of photocatalytic water splitting for generating hydrogen, particularly under visible-light irradiation. The topics covered include an introduction of hydrogen production technologies, a review of photocatalytic water splitting over titania and non-titania based photocatalysts, a discussion of the types of photocatalytic water-splitting approaches, and a conclusion for the current challenges and future prospects of photocatalytic water splitting. Based on the literatures reported here, the development of highly stable visible–light-active photocatalytic materials, and the design of efficient, low-cost photoreactor systems are the key for the advancement of solar-hydrogen production via photocatalytic water splitting in the future.

Recent Advances on Hydrogenic Retention in ITER's Plasma-Facing Materials: BE, C, W

International Nuclear Information System (INIS)

Skinner, C.H.; Haasz, A.A.; Alimov, V.Kh.; Bekris, N.; Causey, R.A.; Clark, R.E.H.; Coad, J.P.; Davis, J.W.; Doerner, R.P.; Mayer, M.; Pisarev, A.; Roth, J.; Tanabe, T.

2008-01-01

Management of tritium inventory remains one of the grand challenges in the development of fusion energy and the choice of plasma-facing materials is a key factor for in-vessel tritium retention. The Atomic and Molecular Data Unit of the International Atomic Energy Agency organized a Coordinated Research Project (CRP) on the overall topic of tritium inventory in fusion reactors during the period 2001-2006. This dealt with hydrogenic retention in ITER's plasma-facing materials, Be, C, W, and in compounds (mixed materials) of these elements as well as tritium removal techniques. The results of the CRP are summarized in this article together with recommendations for ITER. Basic parameters of diffusivity, solubility and trapping in Be, C and W are reviewed. For Be, the development of open porosity can account for transient hydrogenic pumping but long term retention will be dominated by codeposition. Codeposition is also the dominant retention mechanism for carbon and remains a serious concern for both Be and C containing layers. Hydrogenic trapping in unirradiated tungsten is low but will increase with ion and neutron damage. Mixed materials will be formed in a tokamak and these can also retain significant amounts of hydrogen isotopes. Oxidative and photon-based techniques for detritiation of plasma-facing components are described

Recent Advances on Hydrogenic Retention in ITER's Plasma-Facing Materials: BE, C, W.

Energy Technology Data Exchange (ETDEWEB)

Skinner, C H; Alimov, Kh; Bekris, N; Causey, R A; Clark, R.E.H.; Coad, J P; Davis, J W; Doerner, R P; Mayer, M; Pisarev, A; Roth, J

2008-03-29

Management of tritium inventory remains one of the grand challenges in the development of fusion energy and the choice of plasma-facing materials is a key factor for in-vessel tritium retention. The Atomic and Molecular Data Unit of the International Atomic Energy Agency organized a Coordinated Research Project (CRP) on the overall topic of tritium inventory in fusion reactors during the period 2001-2006. This dealt with hydrogenic retention in ITER's plasma-facing materials, Be, C, W, and in compounds (mixed materials) of these elements as well as tritium removal techniques. The results of the CRP are summarized in this article together with recommendations for ITER. Basic parameters of diffusivity, solubility and trapping in Be, C and W are reviewed. For Be, the development of open porosity can account for transient hydrogenic pumping but long term retention will be dominated by codeposition. Codeposition is also the dominant retention mechanism for carbon and remains a serious concern for both Be and C containing layers. Hydrogenic trapping in unirradiated tungsten is low but will increase with ion and neutron damage. Mixed materials will be formed in a tokamak and these can also retain significant amounts of hydrogen isotopes. Oxidative and photon-based techniques for detritiation of plasma-facing components are described.

Beyond Depression Commentary: Wherefore Art Thou, Depression Clinic of Tomorrow?

Science.gov (United States)

Siegle, Greg J.

2013-01-01

An exciting review in this issue (Forgeard et al., 2011) highlights a number of emerging themes in contemporary translational research in this area. A primary challenge for the next generation of researchers reading this work will be how to carry out the grand charges levied by Forgeard et al., on the ground, i.e., to lay the foundations for moving the emerging basic science of depression into the Depression Clinic of Tomorrow. Addressing these challenges could suggest changes in the nature of the basic science, and questions that are being asked, and employed approaches in contemporary depression research. Preconditions for clinical adoption discussed in the review include 1) beginning to hold neuroscience-based measures of features of depression to the same standards held for other depression measures in the clinic, 2) attending to how the proposed methods might actually end up being feasibly imported into the clinic, and 3) what interventions targeted at mechanisms of depression might look like in the next decade. PMID:24634570

Hydrogen system (hydrogen fuels feasibility)

International Nuclear Information System (INIS)

Guarna, S.

1991-07-01

This feasibility study on the production and use of hydrogen fuels for industry and domestic purposes includes the following aspects: physical and chemical properties of hydrogen; production methods steam reforming of natural gas, hydrolysis of water; liquid and gaseous hydrogen transportation and storage (hydrogen-hydride technology); environmental impacts, safety and economics of hydrogen fuel cells for power generation and hydrogen automotive fuels; relevant international research programs

Advances in Propulsive Bionic Feet and Their Actuation Principles

Directory of Open Access Journals (Sweden)

Pierre Cherelle

2014-07-01

Full Text Available In the past decades, researchers have deeply studied pathological and nonpathological gait to understand the human ankle function during walking. These efforts resulted in the development of new lower limb prosthetic devices aiming at raising the 3C-level (control, comfort, and cosmetics of amputees. Thanks to the technological advances in engineering and mechatronics, challenges in the field of prosthetics have become an important source of interest for roboticists. Currently, most of the bionic feet are still on a research level but show promising results and a preview of tomorrow's commercial prosthetic devices. In this paper, the authors present the current state-of-the-art and the latest advances in propulsive bionic feet with its actuation principles. The context of this review study is outlined followed by a brief description of the basics in human biomechanics and criteria for new prosthetic designs. A new categorization based on the actuation principle of propulsive ankle-foot prostheses is proposed. Based on simulations, the general principles and benefits of each actuation method are explained. The corresponding latest advances in propulsive bionic feet are presented together with their main characteristics and scientific outcomes. The authors also propose to the reader a comparison analysis of the presented devices with a discussion of the general tendencies in new prosthetic feet.

DEVELOPMENT OF DOPED NANOPOROUS CARBONS FOR HYDROGEN STORAGE

Energy Technology Data Exchange (ETDEWEB)

Lueking, Angela D.; Li, Qixiu; Badding, John V.; Fonseca, Dania; Gutierrez, Humerto; Sakti, Apurba; Adu, Kofi; Schimmel, Michael

2010-03-31

Hydrogen storage materials based on the hydrogen spillover mechanism onto metal-doped nanoporous carbons are studied, in an effort to develop materials that store appreciable hydrogen at ambient temperatures and moderate pressures. We demonstrate that oxidation of the carbon surface can significantly increase the hydrogen uptake of these materials, primarily at low pressure. Trace water present in the system plays a role in the development of active sites, and may further be used as a strategy to increase uptake. Increased surface density of oxygen groups led to a significant enhancement of hydrogen spillover at pressures less than 100 milibar. At 300K, the hydrogen uptake was up to 1.1 wt. % at 100 mbar and increased to 1.4 wt. % at 20 bar. However, only 0.4 wt% of this was desorbable via a pressure reduction at room temperature, and the high lowpressure hydrogen uptake was found only when trace water was present during pretreatment. Although far from DOE hydrogen storage targets, storage at ambient temperature has significant practical advantages oner cryogenic physical adsorbents. The role of trace water in surface modification has significant implications for reproducibility in the field. High-pressure in situ characterization of ideal carbon surfaces in hydrogen suggests re-hybridization is not likely under conditions of practical interest. Advanced characterization is used to probe carbon-hydrogen-metal interactions in a number of systems and new carbon materials have been developed.

Sustainable Materials Management (SMM) Web Academy Webinar: Changing How We Think About Our Resources for a Better Tomorrow: How to Donate Surplus Food from K-12 Schools

Science.gov (United States)

This is a webinar page for the Sustainable Management of Materials (SMM) Web Academy webinar titled Changing How We Think About Our Resources for a Better Tomorrow: How to Donate Surplus Food from K-12 Schools

Assessment of MHR-based hydrogen energy systems

International Nuclear Information System (INIS)

Richards, Matthew; Shenoy, Arkal; Schultz, Kenneth; Brown, Lloyd; Besenbruch, Gottfried; Handa, Norihiko; Das, Jadu

2004-01-01

Process heat from a high-temperature nuclear reactor can be used to drive a set of chemical reactions, with the net result of splitting water into hydrogen and oxygen. For example, process heat at temperatures in the range 850degC to 950degC can drive the sulfur-iodine (SI) thermochemical process to produce hydrogen with high efficiency. The SI process produces highly pure hydrogen and oxygen, with formation, decomposition, regeneration, and recycle of the intermediate chemical reagents and low-temperature heat as the only waste product. Electricity can also be used directly to split water, using conventional, low-temperature electrolysis (LTE). Hydrogen can also be produced with hybrid processes that use both process heat and electricity to generate hydrogen. An example of a hybrid process is high-temperature electrolysis (HTE), in which process heat is used to generate steam, which is then supplied to an electrolyzer to generate hydrogen. This process is of interest because the efficiency of electrolysis increases with temperature. Because of its high-temperature capability, advanced of development relative to other high-temperature reactor concepts, and passive-safety features, the Modular Helium Reactor (MHR) is well suited for producing hydrogen using nuclear energy. In this paper we investigate concepts for coupling the MHR to the SI process, LTE, and HTE. These concepts are referred to as the H2-MHR. (author)

Trapping hydrogen atoms from a neon-gas matrix: a theoretical simulation.

Science.gov (United States)

Bovino, S; Zhang, P; Kharchenko, V; Dalgarno, A

2009-08-07

Hydrogen is of critical importance in atomic and molecular physics and the development of a simple and efficient technique for trapping cold and ultracold hydrogen atoms would be a significant advance. In this study we simulate a recently proposed trap-loading mechanism for trapping hydrogen atoms released from a neon matrix. Accurate ab initio quantum calculations are reported of the neon-hydrogen interaction potential and the energy- and angular-dependent elastic scattering cross sections that control the energy transfer of initially cold atoms are obtained. They are then used to construct the Boltzmann kinetic equation, describing the energy relaxation process. Numerical solutions of the Boltzmann equation predict the time evolution of the hydrogen energy distribution function. Based on the simulations we discuss the prospects of the technique.

Development of advanced PEM water electrolysers

International Nuclear Information System (INIS)

A Deschamps; C Etievant; C Puyenchet; V Fateev; S Grigoriev; A Kalinnikov; V Porembsky; P Millet

2006-01-01

Concerning the production of electrolytic hydrogen, the goal of present R and D is to develop advanced hydrogen generator based on proton exchange membrane (PEM) water electrolysers. PEM-based water electrolysis offers a number of advantages, such as ecological safety, high gas purity (more than 99.99% for hydrogen), the possibility of producing compressed gases (up to 200 bar) for direct pressurized storage without additional power inputs, etc. PEM electrolysers are considered as rather attractive devices to accelerate the transition to the hydrogen economy and develop a hydrogen infrastructure network (for example for the development of re-filling stations for cars, using electric power stations at night hours and renewable energy sources). The work presented here result from a cooperation between Hydrogen Energy and Plasma Technology Institute (HEPTI) of Russian Research Center (RRC) 'Kurchatov Institute', Universite Paris - Sud XI and Compagnie d'Etudes des Technologies de l'Hydrogene. This project is supported by the Commission of the European Communities within the frame of the 6. Framework Programme (GenHyPEM, STREP no 019802). (authors)

New perspectives on potential hydrogen storage materials using high pressure.

Science.gov (United States)

Song, Yang

2013-09-21

In addressing the global demand for clean and renewable energy, hydrogen stands out as the most suitable candidate for many fuel applications that require practical and efficient storage of hydrogen. Supplementary to the traditional hydrogen storage methods and materials, the high-pressure technique has emerged as a novel and unique approach to developing new potential hydrogen storage materials. Static compression of materials may result in significant changes in the structures, properties and performance that are important for hydrogen storage applications, and often lead to the formation of unprecedented phases or complexes that have profound implications for hydrogen storage. In this perspective article, 22 types of representative potential hydrogen storage materials that belong to four major classes--simple hydride, complex hydride, chemical hydride and hydrogen containing materials--were reviewed. In particular, their structures, stabilities, and pressure-induced transformations, which were reported in recent experimental works together with supporting theoretical studies, were provided. The important contextual aspects pertinent to hydrogen storage associated with novel structures and transitions were discussed. Finally, the summary of the recent advances reviewed and the insight into the future research in this direction were given.

High Efficiency Solar Thermochemical Reactor for Hydrogen Production.

Energy Technology Data Exchange (ETDEWEB)

McDaniel, Anthony H. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2017-09-30

This research and development project is focused on the advancement of a technology that produces hydrogen at a cost that is competitive with fossil-based fuels for transportation. A twostep, solar-driven WS thermochemical cycle is theoretically capable of achieving an STH conversion ratio that exceeds the DOE target of 26% at a scale large enough to support an industrialized economy [1]. The challenge is to transition this technology from the laboratory to the marketplace and produce hydrogen at a cost that meets or exceeds DOE targets.

Final Technical Report: Hydrogen Energy in Engineering Education (H2E3)

Energy Technology Data Exchange (ETDEWEB)

Lehman, Peter A.; Cashman, Eileen; Lipman, Timothy; Engel, Richard A.

2011-09-15

Schatz Energy Research Center's Hydrogen Energy in Engineering Education curriculum development project delivered hydrogen energy and fuel cell learning experiences to over 1,000 undergraduate engineering students at five California universities, provided follow-on internships for students at a fuel cell company; and developed commercializable hydrogen teaching tools including a fuel cell test station and a fuel cell/electrolyzer experiment kit. Monitoring and evaluation tracked student learning and faculty and student opinions of the curriculum, showing that use of the curriculum did advance student comprehension of hydrogen fundamentals. The project web site (hydrogencurriculum.org) provides more information.

Measures of excess body weight and anthropometry among adult Albertans: cross-sectional results from Alberta’s tomorrow project cohort

OpenAIRE

Brenner, Darren R.; Poirier, Abbey E.; Haig, Tiffany R.; Akawung, Alianu; Friedenreich, Christine M.; Robson, Paula J.

2017-01-01

Background Excess body weight during adulthood has been consistently associated with all-cause mortality, cardiovascular disease, and cancer at multiple sites among other chronic diseases. We describe the prevalence of excess body weight and abdominal obesity reported by participants enrolled in Alberta’s Tomorrow Project (ATP). Methods ATP is a geographically-based cohort study conducted among adults aged 35–69 years from across the province of Alberta. Participants completed anthropometric ...

Comparative costs and benefits of hydrogen vehicles

Energy Technology Data Exchange (ETDEWEB)

Berry, G.D. [Lawrence Livermore National Lab., CA (United States)

1996-10-01

The costs and benefits of hydrogen as a vehicle fuel are compared to gasoline, natural gas, and battery-powered vehicles. Costs, energy, efficiency, and tail-pipe and full fuel cycle emissions of air pollutants and greenhouse gases were estimated for hydrogen from a broad range of delivery pathways and scales: from individual vehicle refueling systems to large stations refueling 300 cars/day. Hydrogen production from natural gas, methanol, and ammonia, as well as water electrolysis based on alkaline or polymer electrolytes and steam electrolysis using solid oxide electrolytes are considered. These estimates were compared to estimates for competing fuels and vehicles, and used to construct oil use, air pollutant, and greenhouse gas emission scenarios for the U.S. passenger car fleet from 2005-2050. Fuel costs need not be an overriding concern in evaluating the suitability of hydrogen as a fuel for passenger vehicles. The combined emissions and oil import reduction benefits of hydrogen cars are estimated to be significant, valued at up to {approximately}$400/yr for each hydrogen car when primarily clean energy sources are used for hydrogen production. These benefits alone, however, become tenuous as the basis supporting a compelling rationale for hydrogen fueled vehicles, if efficient, advanced fossil-fuel hybrid electric vehicles (HEV`s) can achieve actual on-road emissions at or below ULEV standards in the 2005-2015 timeframe. It appears a robust rationale for hydrogen fuel and vehicles will need to also consider unique, strategic, and long-range benefits of hydrogen vehicles which can be achieved through the use of production, storage, delivery, and utilization methods for hydrogen which are unique among fuels: efficient use of intermittent renewable energy sources, (e,g, wind, solar), small-scale feasibility, fuel production at or near the point of use, electrolytic production, diverse storage technologies, and electrochemical conversion to electricity.

Current Development in Treatment and Hydrogen Energy Conversion of Organic Solid Waste

Science.gov (United States)

Shin, Hang-Sik

2008-02-01

This manuscript summarized current developments on continuous hydrogen production technologies researched in Korea advanced institute of science and technology (KAIST). Long-term continuous pilot-scale operation of hydrogen producing processes fed with non-sterile food waste exhibited successful results. Experimental findings obtained by the optimization processes of growth environments for hydrogen producing bacteria, the development of high-rate hydrogen producing strategies, and the feasibility tests for real field application could contribute to the progress of fermentative hydrogen production technologies. Three major technologies such as controlling dilution rate depending on the progress of acidogenesis, maintaining solid retention time independently from hydraulic retention time, and decreasing hydrogen partial pressure by carbon dioxide sparging could enhance hydrogen production using anaerobic leaching beds reactors and anaerobic sequencing batch reactors. These findings could contribute to stable, reliable and effective performances of pilot-scale reactors treating organic wastes.

Multi-unit Inertial Fusion Energy (IFE) plants producing hydrogen fuel

International Nuclear Information System (INIS)

Logan, B.G.

1993-12-01

A quantitative energy pathway comparison is made between a modern oil refinery and genetic fusion hydrogen plant supporting hybrid-electric cars powered by gasoline and hydrogen-optimized internal combustion engines, respectively, both meeting President Clinton's goal for advanced car goal of 80 mpg gasoline equivalent. The comparison shows that a fusion electric plant producing hydrogen by water electrolysis at 80% efficiency must have an electric capacity of 10 GWe to support as many hydrogen-powered hybrid cars as one modern 200,000 bbl/day-capacity oil refinery could support in gasoline-powered hybrid cars. A 10 GWe fusion electric plant capital cost is limited to 12.5 B$ to produce electricity at 2.3 cents/kWehr, and hydrogen production by electrolysis at 8 $/GJ, for equal consumer fuel cost per passenger mile as in the oil-gasoline-hybrid pathway

Advanced materials for energy storage.

Science.gov (United States)

Liu, Chang; Li, Feng; Ma, Lai-Peng; Cheng, Hui-Ming

2010-02-23

Popularization of portable electronics and electric vehicles worldwide stimulates the development of energy storage devices, such as batteries and supercapacitors, toward higher power density and energy density, which significantly depends upon the advancement of new materials used in these devices. Moreover, energy storage materials play a key role in efficient, clean, and versatile use of energy, and are crucial for the exploitation of renewable energy. Therefore, energy storage materials cover a wide range of materials and have been receiving intensive attention from research and development to industrialization. In this Review, firstly a general introduction is given to several typical energy storage systems, including thermal, mechanical, electromagnetic, hydrogen, and electrochemical energy storage. Then the current status of high-performance hydrogen storage materials for on-board applications and electrochemical energy storage materials for lithium-ion batteries and supercapacitors is introduced in detail. The strategies for developing these advanced energy storage materials, including nanostructuring, nano-/microcombination, hybridization, pore-structure control, configuration design, surface modification, and composition optimization, are discussed. Finally, the future trends and prospects in the development of advanced energy storage materials are highlighted.

Hydrogen Production by Homogeneous Catalysis: Alcohol Acceptorless Dehydrogenation

DEFF Research Database (Denmark)

Nielsen, Martin

2015-01-01

in hydrogen production from biomass using homogeneous catalysis. Homogeneous catalysis has the advance of generally performing transformations at much milder conditions than traditional heterogeneous catalysis, and hence it constitutes a promising tool for future applications for a sustainable energy sector...

Hydrogen Sensors Boost Hybrids; Today's Models Losing Gas?

Science.gov (United States)

2005-01-01

Advanced chemical sensors are used in aeronautic and space applications to provide safety monitoring, emission monitoring, and fire detection. In order to fully do their jobs, these sensors must be able to operate in a range of environments. NASA has developed sensor technologies addressing these needs with the intent of improving safety, optimizing combustion efficiencies, and controlling emissions. On the ground, the chemical sensors were developed by NASA engineers to detect potential hydrogen leaks during Space Shuttle launch operations. The Space Shuttle uses a combination of hydrogen and oxygen as fuel for its main engines. Liquid hydrogen is pumped to the external tank from a storage tank located several hundred feet away. Any hydrogen leak could potentially result in a hydrogen fire, which is invisible to the naked eye. It is important to detect the presence of a hydrogen fire in order to prevent a major accident. In the air, the same hydrogen-leak dangers are present. Stress and temperature changes can cause tiny cracks or holes to form in the tubes that line the Space Shuttle s main engine nozzle. Such defects could allow the hydrogen that is pumped through the nozzle during firing to escape. Responding to the challenges associated with pinpointing hydrogen leaks, NASA endeavored to improve propellant leak-detection capabilities during assembly, pre-launch operations, and flight. The objective was to reduce the operational cost of assembling and maintaining hydrogen delivery systems with automated detection systems. In particular, efforts have been focused on developing an automated hydrogen leak-detection system using multiple, networked hydrogen sensors that are operable in harsh conditions.

after tomorrow

Directory of Open Access Journals (Sweden)

Elena Grigoryeva

2011-05-01

prediction (81. Modern forecasting has acquired all the attributes of a serious science and even a technology. Should we take the contemporary futurists’ prognoses so serious? Won’t our today prognoses, foresights and strategies show the same naivety in several decades?Only one thing can be confidently said about the future: it will happen. The day after tomorrow will come. What the day will be like? Which trends will be realized and which ones will be considered just as funny illusions? Among other things, it all depends on us, living today.

Energy for tomorrow. The World Energy Council calls for global action

International Nuclear Information System (INIS)

Doucet, G.

2000-01-01

In April 2000, the World Energy Council (WEC) issued a statement that reexamined the world energy situation, revising its Energy for Tomorrow report published in 1993. The WEC Statement 2000 critically reviews the earlier scenarios and proposes a new set of goals and policy actions. The objective was to draw on actual experience during the last eight years, both in terms of analysis and clearer set of policy actions. The WEC dedicated its statement to help overcome energy poverty wherever it occurs; enhance the quality and reliability of delivered energy; and minimize negative environmental and health impacts of energy development. The WEC Statement sets the energy goals and defines the policy actions which, if taken now, would provide grounds for reasonable optimism in facing the task ahead. This article is based on the Statement's executive summary and highlights the main points in the context of major developments over past eight years

An integrated approach to hydrogen economy in Sicilian islands

Energy Technology Data Exchange (ETDEWEB)

Matera, Fabio V.; Sapienza, C.; Andaloro, L.; Dispensa, G.; Ferraro, M.; Antonucci, V. [Italian National Research Council, Institute of Advanced Energy Technologies ' ' Nicola Giordano' ' , salita S. Lucia sopra Contesse, 5, Messina 98126 (Italy)

2009-08-15

CNR-ITAE is developing several hydrogen and fuel cell demonstration and research projects, each intended to be part of a larger strategy for hydrogen communities settling in small Sicilian islands. These projects involve vehicle design, hydrogen production from renewable energy sources and methane, as well as implementation strategies to develop a hydrogen and renewable energy economy. These zero emission lightweight vehicles feature regenerative braking and advanced power electronics to increase efficiency. Moreover, to achieve a very easy-to-use technology, a very simple interface between driver and the system is under development, including fault-recovery strategies and GPS positioning for car-rental fleets. Also marine applications have been included, with tests on PEFC applied on passenger ships and luxury yacht as power system for on-board loads. In marine application, it is under study also an electrolysis hydrogen generator system using seawater as hydrogen carrier. For stationary and automotive applications, the project includes a hydrogen refuelling station powered by renewable energy (wind or/and solar) and test on fuel processors fed with methane, in order to make the power generation self-sufficient, as well as to test the technology and increase public awareness toward clean energy sources. (author)

Hierarchical sulfur-impregnated hydrogenated TiO2 mesoporous spheres comprising anatase nanosheets with highly exposed (001) facets for advanced Li-S batteries

Science.gov (United States)

Yuan, Changzhou; Zhu, Siqi; Cao, Hui; Hou, Linrui; Lin, Jingdong

2016-01-01

In this contribution, we purposefully designed hierarchical hydrogenated TiO2 spheres (HTSs) constructed from ultrathin anatase nanosheets with highly exposed (001) facets, and further utilized them as an efficient encapsulated host of sulfur species for advanced Li-S batteries (LSBs). Strikingly, the as-fabricated hybrid S/HTSs cathode exhibited high Coulombic efficiency (>94%), exceptional long cycling performance (capacity decay of ˜0.399% per cycle at 0.5 C), and large reversible discharge capacity (˜579 mAh g-1 at 2.0 C) at high C rates, benefiting from better electronic conductivity, smaller charge transfer resistance and strong chemical bonding between {{{{S}}}n}2- and the reduced (001) facets of HTSs, according to experimental measurements and systematical theoretical calculations. More significantly, our in-depth insights into the mechanism involved in the hybrid S/HTSs could efficiently guide future design, optimization and synthesis of other metal oxide-based matrixes with specific exposed crystal facets for next-generation advanced LSBs.

The future of nuclear engineering

International Nuclear Information System (INIS)

Beeden, Jeffrey

2003-01-01

Today, nuclear power refers to the splitting of large uranium atoms into smaller atoms with a net release of energy. Tomorrow, nuclear power will refer to the combining of hydrogen into larger atoms with a net release of energy. Nuclear power's future is fusion. The Mechanical Engineers of tomorrow will need to be familiar with the process of creating and harnessing the energy from a fusion reaction. During the oil shortage in the 1970's, America scrambled to initiate alternative methods of producing power. Nuclear fusion was one of them. As time passes, the solution to the world's energy crisis presses the countries of the world to find alternative forms of energy; nuclear fusion may contain the answer. In the near future, the field of fusion will open up and a new wave of engineers will flood into this field. Mechanical engineers will lead the way with advances in materials, computational fluid dynamics, finite element analysis for thermal and structural systems, and heat transfer designs to optimize nuclear fusion reactors and power plants. All this effort is in anticipation of creating a sustained fusion reaction that can generate enough heat to transfer to steam in order to generate electric power to sustain the fusion reaction and introduce power to the grid. (author)

Hydrogen Research for Spaceport and Space-Based Applications: Fuel Cell Projects

Science.gov (United States)

Anderson, Tim; Balaban, Canan

2008-01-01

The activities presented are a broad based approach to advancing key hydrogen related technologies in areas such as fuel cells, hydrogen production, and distributed sensors for hydrogen-leak detection, laser instrumentation for hydrogen-leak detection, and cryogenic transport and storage. Presented are the results from research projects, education and outreach activities, system and trade studies. The work will aid in advancing the state-of-the-art for several critical technologies related to the implementation of a hydrogen infrastructure. Activities conducted are relevant to a number of propulsion and power systems for terrestrial, aeronautics and aerospace applications. Fuel cell research focused on proton exchange membranes (PEM), solid oxide fuel cells (SOFC). Specific technologies included aircraft fuel cell reformers, new and improved electrodes, electrolytes, interconnect, and seals, modeling of fuel cells including CFD coupled with impedance spectroscopy. Research was conducted on new materials and designs for fuel cells, along with using embedded sensors with power management electronics to improve the power density delivered by fuel cells. Fuel cell applications considered were in-space operations, aviation, and ground-based fuel cells such as; powering auxiliary power units (APUs) in aircraft; high power density, long duration power supplies for interplanetary missions (space science probes and planetary rovers); regenerative capabilities for high altitude aircraft; and power supplies for reusable launch vehicles.

Recipe for a Better Tomorrow: A Food Industry Perspective on Sustainability and Our Food System

Science.gov (United States)

Wasserman, Arlin

2009-01-01

The food and agriculture sector is central to efforts to improve public health today and protect and restore natural systems necessary to support good health in the future. The sector has a greater direct impact on land and water resources, employment, and economic activity than any other. And, from a finite resource base, it is underpinning not only food and fiber production but is increasingly relied upon to provide the raw materials for energy, building materials, packaging, and nonfood consumable products. This commentary reviews consumer attitudes and the transformational changes required in the food and agriculture sector to meet today's needs and ensure a better tomorrow. PMID:23144679

Recipe for a Better Tomorrow: A Food Industry Perspective on Sustainability and Our Food System.

Science.gov (United States)

Wasserman, Arlin

2009-07-01

The food and agriculture sector is central to efforts to improve public health today and protect and restore natural systems necessary to support good health in the future. The sector has a greater direct impact on land and water resources, employment, and economic activity than any other. And, from a finite resource base, it is underpinning not only food and fiber production but is increasingly relied upon to provide the raw materials for energy, building materials, packaging, and nonfood consumable products. This commentary reviews consumer attitudes and the transformational changes required in the food and agriculture sector to meet today's needs and ensure a better tomorrow.

The Modular Helium Reactor for Hydrogen Production

International Nuclear Information System (INIS)

E. Harvego; M. Richards; A. Shenoy; K. Schultz; L. Brown; M. Fukuie

2006-01-01

For electricity and hydrogen production, an advanced reactor technology receiving considerable international interest is a modular, passively-safe version of the high-temperature, gas-cooled reactor (HTGR), known in the U.S. as the Modular Helium Reactor (MHR), which operates at a power level of 600 MW(t). For hydrogen production, the concept is referred to as the H2-MHR. Two concepts that make direct use of the MHR high-temperature process heat are being investigated in order to improve the efficiency and economics of hydrogen production. The first concept involves coupling the MHR to the Sulfur-Iodine (SI) thermochemical water splitting process and is referred to as the SI-Based H2-MHR. The second concept involves coupling the MHR to high-temperature electrolysis (HTE) and is referred to as the HTE-Based H2-MHR

The hydrogen; L'hydrogene

Energy Technology Data Exchange (ETDEWEB)

NONE

2004-07-01

The hydrogen as an energy system represents nowadays a main challenge (in a scientific, economical and environmental point of view). The physical and chemical characteristics of hydrogen are at first given. Then, the challenges of an hydrogen economy are explained. The different possibilities of hydrogen production are described as well as the distribution systems and the different possibilities of hydrogen storage. Several fuel cells are at last presented: PEMFC, DMFC and SOFC. (O.M.)

Advanced Cell Development and Degradation Studies

International Nuclear Information System (INIS)

O'Brien, J.E.; Stoots, C.M.; Herring, J.S.; O'Brien, R.C.; Condie, K.G.; Sohal, M.; Housley, G.K.; Hartvigsen, J.J.; Larsen, D.; Tao, G.; Yildiz, B.; Sharma, V.; Singh, P.; Petigny, N.; Cable, T.L.

2010-01-01

The Idaho National Laboratory (INL) has been researching the application of solid-oxide electrolysis cells for large-scale hydrogen production from steam over a temperature range of 800 to 900 C. From 2003-2009, this work was sponsored by the DOE Nuclear Hydrogen Initiative (NHI). Starting in 2010, the HTE research program has been sponsored by the Next Generation Nuclear Plant (NGNP) program. HTSE research priorities in FY10 are centered on understanding and reducing cell and stack performance degradation to an acceptable level to advance the technology readiness level of HTSE and to justify further large-scale demonstration activities. This report provides a summary of our FY10 experimental program, which has been focused on advanced cell and stack development and degradation studies. Advanced cell and stack development activities are under way at five technology partners: MSRI, Versa Power, Ceramatec, NASA Glenn, and St. Gobain. Performance evaluation of the advanced technology cells and stacks has been performed by the technology partners, by MIT and the University of Connecticut and at the INL HTE Laboratory. Summaries of these development activities and test results are presented.

Advanced Cell Development and Degradation Studies

Energy Technology Data Exchange (ETDEWEB)

J. E. O' Brien; C. M. Stoots; J. S. Herring; R. C. O' Brien; K. G. Condie; M. Sohal; G. K. Housley; J. J. Hartvigsen; D. Larsen; G. Tao; B. Yildiz; V. Sharma; P. Singh; N. Petigny; T. L. Cable

2010-09-01

The Idaho National Laboratory (INL) has been researching the application of solid-oxide electrolysis cells for large-scale hydrogen production from steam over a temperature range of 800 to 900ºC. From 2003 – 2009, this work was sponsored by the DOE Nuclear Hydrogen Initiative (NHI). Starting in 2010, the HTE research program has been sponsored by the Next Generation Nuclear Plant (NGNP) program. HTSE research priorities in FY10 are centered on understanding and reducing cell and stack performance degradation to an acceptable level to advance the technology readiness level of HTSE and to justify further large-scale demonstration activities. This report provides a summary of our FY10 experimental program, which has been focused on advanced cell and stack development and degradation studies. Advanced cell and stack development activities are under way at five technology partners: MSRI, Versa Power, Ceramatec, NASA Glenn, and St. Gobain. Performance evaluation of the advanced technology cells and stacks has been performed by the technology partners, by MIT and the University of Connecticut and at the INL HTE Laboratory. Summaries of these development activities and test results are presented.

Effect of Hydrogen Addition on Methane HCCI Engine Ignition Timing and Emissions Using a Multi-zone Model

Science.gov (United States)

Wang, Zi-han; Wang, Chun-mei; Tang, Hua-xin; Zuo, Cheng-ji; Xu, Hong-ming

2009-06-01

Ignition timing control is of great importance in homogeneous charge compression ignition engines. The effect of hydrogen addition on methane combustion was investigated using a CHEMKIN multi-zone model. Results show that hydrogen addition advances ignition timing and enhances peak pressure and temperature. A brief analysis of chemical kinetics of methane blending hydrogen is also performed in order to investigate the scope of its application, and the analysis suggests that OH radical plays an important role in the oxidation. Hydrogen addition increases NOx while decreasing HC and CO emissions. Exhaust gas recirculation (EGR) also advances ignition timing; however, its effects on emissions are generally the opposite. By adjusting the hydrogen addition and EGR rate, the ignition timing can be regulated with a low emission level. Investigation into zones suggests that NOx is mostly formed in core zones while HC and CO mostly originate in the crevice and the quench layer.

Study and Development of Face-Contact, Bellows Mechanical Seal for Liquid Hydrogen Turbopump

OpenAIRE

NOSAKA, Masataka; SUZUKI, Mineo; MIYAKAWA, Yukio; KAMIJO, Kenjiro; KIKUCHI, Masataka; MORI, Masahiro; 野坂, 正隆; 鈴木, 峰男; 宮川, 行雄; 上絛, 謙二郎; 菊池, 正孝; 森, 雅裕

1981-01-01

The development of a 10-ton thrust liquid oxygen and liquid hydrogen (LOX and LH2) rocket engine is under way at the National Space Development Agency. In advance of the development of a liquid hydrogen turbopump, the National Aerospace Laboratory carried out study and development of a face-contact, bellows mechanical seal for a liquid hydrogen turbopump in co-operation with the National Space Development Agency. The present report describes the fundamental experiments of the mechanical seal ...

Nano-design of quantum dot-based photocatalysts for hydrogen generation using advanced surface molecular chemistry

KAUST Repository

Yu, Weili; Noureldine, Dalal; Isimjan, Tayirjan T.; Lin, Bin; Del Gobbo, Silvano; Abulikemu, Mutalifu; Hedhili, Mohamed N.; Anjum, Dalaver H.; Takanabe, Kazuhiro

2015-01-01

Efficient photocatalytic hydrogen generation in a suspension system requires a sophisticated nano-device that combines a photon absorber with effective redox catalysts. This study demonstrates an innovative molecular linking strategy for fabricating photocatalytic materials that allow effective charge separation of excited carriers, followed by efficient hydrogen evolution. The method for the sequential replacement of ligands with appropriate molecules developed in this study tethers both quantum dots (QDs), as photosensitizers, and metal nanoparticles, as hydrogen evolution catalysts, to TiO2 surfaces in a controlled manner at the nano-level. Combining hydrophobic and hydrophilic interactions on the surface, CdSe-ZnS core-shell QDs and an Au-Pt alloy were attached to TiO2 without overlapping during the synthesis. The resultant nano-photocatalysts achieved substantially high-performance visible-light-driven photocatalysis for hydrogen evolution. All syntheses were conducted at room temperature and in ambient air, providing a promising route for fabricating visible-light-responsive photocatalysts.

HYSOLAR an overview on the German-Saudi Arabian program on solar hydrogen

International Nuclear Information System (INIS)

Steeb, H.; Seeger, W.

1993-01-01

The first phase of HYSOLAR, which ended in 1991, was focusing mainly on investigation, test and improvement of hydrogen production technologies. This paper shortly reviews the most important results: a 2 kW test and research facility in Jeddah; fundamental research in the fields of photo-electrochemistry, advanced alkaline electrolysis and alkaline fuel cells; system studies and decentralized hydrogen utilization; program for education. An outlook into the second phase program, where more emphasis is laid on hydrogen utilization technologies, is also included. 1 tab., 93 refs

High-energy-density hydrogen-halogen fuel cells for advanced military applications

International Nuclear Information System (INIS)

Balko, E.N.; McElroy, J.F.

1981-01-01

It is pointed out that hydrogen-halogen fuel cell systems are particularly suited for an employment as ground power sources for military applications. The large cell potential and reversible characteristics of the H 2 Cl 2 and H 2 Br 2 couples permit high energy storage density and efficient energy conversion. When used as flow batteries, the fluid nature of the reactants in the hydrogen-halogen systems has several advantages over power sources which involve solid phases. Very deep discharge is possible without degradation of subsequent performance, and energy storage capacity is limited only by the external reactant storage volume. Very rapid chemical recharging is possible through replenishment of the reactant supply. A number of H 2 Cl 2 and H 2 Br 2 fuel cell systems have been studied. These systems use the same solid polymer electrolyte (SPE) cell technology originally developed for H2/O2 fuel cells. The results of the investigation are illustrated with the aid of a number of graphs

Advanced Intermediate Heat Transport Loop Design Configurations for Hydrogen Production Using High Temperature Nuclear Reactors

International Nuclear Information System (INIS)

Chang Oh; Cliff Davis; Rober Barner; Paul Pickard

2005-01-01

The US Department of Energy is investigating the use of high-temperature nuclear reactors to produce hydrogen using either thermochemical cycles or high-temperature electrolysis. Although the hydrogen production processes are in an early stage of development, coupling either of these processes to the high-temperature reactor requires both efficient heat transfer and adequate separation of the facilities to assure that off-normal events in the production facility do not impact the nuclear power plant. An intermediate heat transport loop will be required to separate the operations and safety functions of the nuclear and hydrogen plants. A next generation high-temperature reactor could be envisioned as a single-purpose facility that produces hydrogen or a dual-purpose facility that produces hydrogen and electricity. Early plants, such as the proposed Next Generation Nuclear Plant (NGNP), may be dual-purpose facilities that demonstrate both hydrogen and efficient electrical generation. Later plants could be single-purpose facilities. At this stage of development, both single- and dual-purpose facilities need to be understood. A number of possible configurations for a system that transfers heat between the nuclear reactor and the hydrogen and/or electrical generation plants were identified. These configurations included both direct and indirect cycles for the production of electricity. Both helium and liquid salts were considered as the working fluid in the intermediate heat transport loop. Methods were developed to perform thermal-hydraulic evaluations and cycle-efficiency evaluations of the different configurations and coolants. The thermal-hydraulic evaluations estimated the sizes of various components in the intermediate heat transport loop for the different configurations. The relative sizes of components provide a relative indication of the capital cost associated with the various configurations. Estimates of the overall cycle efficiency of the various

U.S. Department of Energy Hydrogen Storage Cost Analysis

Energy Technology Data Exchange (ETDEWEB)

Law, Karen; Rosenfeld, Jeffrey; Han, Vickie; Chan, Michael; Chiang, Helena; Leonard, Jon

2013-03-11

The overall objective of this project is to conduct cost analyses and estimate costs for on- and off-board hydrogen storage technologies under development by the U.S. Department of Energy (DOE) on a consistent, independent basis. This can help guide DOE and stakeholders toward the most-promising research, development and commercialization pathways for hydrogen-fueled vehicles. A specific focus of the project is to estimate hydrogen storage system cost in high-volume production scenarios relative to the DOE target that was in place when this cost analysis was initiated. This report and its results reflect work conducted by TIAX between 2004 and 2012, including recent refinements and updates. The report provides a system-level evaluation of costs and performance for four broad categories of on-board hydrogen storage: (1) reversible on-board metal hydrides (e.g., magnesium hydride, sodium alanate); (2) regenerable off-board chemical hydrogen storage materials(e.g., hydrolysis of sodium borohydride, ammonia borane); (3) high surface area sorbents (e.g., carbon-based materials); and 4) advanced physical storage (e.g., 700-bar compressed, cryo-compressed and liquid hydrogen). Additionally, the off-board efficiency and processing costs of several hydrogen storage systems were evaluated and reported, including: (1) liquid carrier, (2) sodium borohydride, (3) ammonia borane, and (4) magnesium hydride. TIAX applied a bottom-up costing methodology customized to analyze and quantify the processes used in the manufacture of hydrogen storage systems. This methodology, used in conjunction with ® software and other tools, developed costs for all major tank components, balance-of-tank, tank assembly, and system assembly. Based on this methodology, the figure below shows the projected on-board high-volume factory costs of the various analyzed hydrogen storage systems, as designed. Reductions in the key cost drivers may bring hydrogen storage system costs closer to this DOE target

Review of Solid State Hydrogen Storage Methods Adopting Different Kinds of Novel Materials

Directory of Open Access Journals (Sweden)

Renju Zacharia

2015-01-01

Full Text Available Overview of advances in the technology of solid state hydrogen storage methods applying different kinds of novel materials is provided. Metallic and intermetallic hydrides, complex chemical hydride, nanostructured carbon materials, metal-doped carbon nanotubes, metal-organic frameworks (MOFs, metal-doped metal organic frameworks, covalent organic frameworks (COFs, and clathrates solid state hydrogen storage techniques are discussed. The studies on their hydrogen storage properties are in progress towards positive direction. Nevertheless, it is believed that these novel materials will offer far-reaching solutions to the onboard hydrogen storage problems in near future. The review begins with the deficiencies of current energy economy and discusses the various aspects of implementation of hydrogen energy based economy.

Study on transient hydrogen behavior and effect on passive containment cooling system of the advanced PWR

International Nuclear Information System (INIS)

Wang Yan

2014-01-01

A certain amount of hydrogen will be generated due to zirconium-steam reaction or molten corium concrete interaction during severe accidents in the pressurized water reactor (PWR). The generated hydrogen releases into the containment, and the formed flammable mixture might cause deflagration or detonation to produce high thermal and pressure loads on the containment, which may threaten the integrity of the containment. The non-condensable hydrogen in containment may also reduce the steam condensation on the containment surface to affect the performance of the passive containment cooling system (PCCS). To study the transient hydrogen behavior in containment with the PCCS performance during the accidents is significant for the further study on the PCCS design and the hydrogen risk mitigation. In this paper, a new developed PCCS analysis code with self-reliance intellectual property rights, which had been validated by comparison on the transients in the containment during the design basis accidents with other developed PCCS analysis code, is brief introduced and used for the transient simulation in the containment under a postulated small break LOCA of cold-leg. The results show that the hydrogen will flow upwards with the coolant released from the break and spread in the containment by convection and diffusion, and it results in the increase of the pressure in the containment due to reducing the heat removal capacity of the PCCS. (author)

8. annual U.S. hydrogen meeting: Proceedings

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-01-01

The proceedings contain 35 papers arranged under the following topical sections: Government`s partnership role for hydrogen technology development; Government/industry partnerships -- Demonstrations; Entering the market -- Partnerships in transportation; Hydrogen -- The aerospace fuel; Codes and Standards; Advanced technologies; and Opportunities for partnerships in the utility market. Of the three markets identified (transportation, power production, and village power) papers are presented dealing with the first two. Three parts of the transportation market were covered: cars, trucks, and buses. Progress was reported in both fuel cell and internal combustion engine vehicle propulsion systems. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

Energy for the world of tomorrow. The time for action

International Nuclear Information System (INIS)

Ailleret, F.

2000-01-01

This article introduces 'Energy for the world of tomorrow' which is the year 2000 version of the study bearing the same title published in 1993 by the World Energy Council. This version also has the sub-heading 'The time for action'. Seven years after the first study, major changes have affected the energy sector and new challenges have arisen. This new study examines these changes and introduces the statistical bases and economic forecasting scenarios used today by the WEC. It deliberately focuses upon the strategy to be adopted in order to meet the three main objectives of accessibility, availability and acceptability which the energy system needs to achieve between now and 2020. The strategy is defined by an action plan containing 10 main priority areas recommended by the WEC and submitted to political and economic decision-makers in order to put the energy system on the path to sustainable development. These objectives and actions are briefly presented in this article, which also makes use of significant extracts taken from this report. (author)

National hydrogen technology competitiveness analysis with an integrated fuzzy AHP and TOPSIS approaches: In case of hydrogen production and storage technologies

Science.gov (United States)

Lee, Seongkon; Mogi, Gento

2017-02-01

The demand of fossil fuels, including oil, gas, and coal has been increasing with the rapid development of developing countries such as China and India. U.S., Japan, EU, and Korea have been making efforts to transfer to low carbon and green growth economics for sustainable development. And they also have been measuring to cope with climate change and the depletion of conventional fuels. Advanced nations implemented strategic energy technology development plans to lead the future energy market. Strategic energy technology development is crucial alternative to address the energy issues. This paper analyze the relative competitiveness of hydrogen energy technologies in case of hydrogen production and storage technologies from 2006 to 2010. Hydrogen energy technology is environmentally clean technology comparing with the previous conventional energy technologies and will play a key role to solve the greenhouse gas effect. Leading nations have increasingly focused on hydrogen technology R&D. This research is carried out the relative competitiveness of hydrogen energy technologies employed by an integrated fuzzy analytic hierarchy process (Fuzzy AHP) and The Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) approaches. We make four criteria, accounting for technological status, R&D budget, R&D human resource, and hydrogen infra. This research can be used as fundamental data for implementing national hydrogen energy R&D planning for energy policy-makers.

Thermodynamically Tuned Nanophase Materials for reversible Hydrogen storage

Energy Technology Data Exchange (ETDEWEB)

Ping Liu; John J. Vajo

2010-02-28

This program was devoted to significantly extending the limits of hydrogen storage technology for practical transportation applications. To meet the hydrogen capacity goals set forth by the DOE, solid-state materials consisting of light elements were developed. Many light element compounds are known that have high capacities. However, most of these materials are thermodynamically too stable, and they release and store hydrogen much too slowly for practical use. In this project we developed new light element chemical systems that have high hydrogen capacities while also having suitable thermodynamic properties. In addition, we developed methods for increasing the rates of hydrogen exchange in these new materials. The program has significantly advanced (1) the application of combined hydride systems for tuning thermodynamic properties and (2) the use of nanoengineering for improving hydrogen exchange. For example, we found that our strategy for thermodynamic tuning allows both entropy and enthalpy to be favorably adjusted. In addition, we demonstrated that using porous supports as scaffolds to confine hydride materials to nanoscale dimensions could improve rates of hydrogen exchange by > 50x. Although a hydrogen storage material meeting the requirements for commercial development was not achieved, this program has provided foundation and direction for future efforts. More broadly, nanoconfinment using scaffolds has application in other energy storage technologies including batteries and supercapacitors. The overall goal of this program was to develop a safe and cost-effective nanostructured light-element hydride material that overcomes the thermodynamic and kinetic barriers to hydrogen reaction and diffusion in current materials and thereby achieve > 6 weight percent hydrogen capacity at temperatures and equilibrium pressures consistent with DOE target values.

Advances in Hydrogen, Carbon Dioxide, and Hydrocarbon Gas Sensor Technology Using GaN and ZnO-Based Devices

Directory of Open Access Journals (Sweden)

Jenshan Lin

2009-06-01

Full Text Available In this paper, we review our recent results in developing gas sensors for hydrogen using various device structures, including ZnO nanowires and GaN High Electron Mobility Transistors (HEMTs. ZnO nanowires are particularly interesting because they have a large surface area to volume ratio, which will improve sensitivity, and because they operate at low current levels, will have low power requirements in a sensor module. GaN-based devices offer the advantage of the HEMT structure, high temperature operation, and simple integration with existing fabrication technology and sensing systems. Improvements in sensitivity, recoverability, and reliability are presented. Also reported are demonstrations of detection of other gases, including CO2 and C2H4 using functionalized GaN HEMTs. This is critical for the development of lab-on-a-chip type systems and can provide a significant advance towards a market-ready sensor application.

Advances in Hydrogen, Carbon Dioxide, and Hydrocarbon Gas Sensor Technology Using GaN and ZnO-Based Devices.

Science.gov (United States)

Anderson, Travis; Ren, Fan; Pearton, Stephen; Kang, Byoung Sam; Wang, Hung-Ta; Chang, Chih-Yang; Lin, Jenshan

2009-01-01

In this paper, we review our recent results in developing gas sensors for hydrogen using various device structures, including ZnO nanowires and GaN High Electron Mobility Transistors (HEMTs). ZnO nanowires are particularly interesting because they have a large surface area to volume ratio, which will improve sensitivity, and because they operate at low current levels, will have low power requirements in a sensor module. GaN-based devices offer the advantage of the HEMT structure, high temperature operation, and simple integration with existing fabrication technology and sensing systems. Improvements in sensitivity, recoverability, and reliability are presented. Also reported are demonstrations of detection of other gases, including CO(2) and C(2)H(4) using functionalized GaN HEMTs. This is critical for the development of lab-on-a-chip type systems and can provide a significant advance towards a market-ready sensor application.

18th world hydrogen energy conference 2010. Proceedings

Energy Technology Data Exchange (ETDEWEB)

NONE

2010-07-01

This CD-ROM contains lectures, power points slides and posters presented on the 18th World Hydrogen Energy Conference. The topics of the conference are: (A). Fuel Cell Basics: 1. Electrochemistry of PEM Fuell Cells; 2. PEM/HT-PEM Fuel Cells: Electrolytes, Stack Components; 3. Direct Fuel Cells; 4. High-Temperature Fuel Cells; 5. Advanced Modelling (B). Existing and Emerging Markets: 1. Off-Grid Power Supply and Premium Power Generation; 2. Space and Aeronautic Applications; 3. APUs for LDV, Trucks, Ships and Airplanes; 4. Portable Applications and Light Traction. (C). Stationary Applications: 1. High-Temperature Fuel Cells; 2. Fuell Cells for Buildings. (D). Transportation Applications: 1. Fuel-Cell Power Trains; 3. Hydrogen Internal Combustion Engines; 4. Systems Analysis and Well-to-Wheel Studies; 5. Demonstration Projects, Costs and Market Introduction; 6 Electrification in Transportation Systems. (E). Fuel Infrastructures: 1. Hydrogen Distribution Technologies; 2. Hydrogen Deployment; 3. Fuel Provision for Early Market Applications. (G). Hydrogen Production Technologies: 1a. Photobiological Hydrogen Production; 1b. Fermentative Hydrogen Production; 1c. The HYVOLUTION Project. (H). Thermochemical Cycles: 3a. Hydrogen from Renewable Electricity; 3b. High-Temperature Electrolysis; 3c Alcaline Electrolysis; 3d PEM Electrolysis; 4a Reforming and Gasification-Fossil Energy Carriers; 4b Reforming and Gasification-Biomass; 5. Hydrogen-Separation Membranes; 6. Hydrogen Systems Assessment;.7. Photocatalysis (I). Storages: 1. Physical Hydrogen Storage; 2a. Metal Hydrides; 2b. Complex Hydrides; 3. Adsorption Technologies; (J). Strategic Analyses: 1. Research + Development Target and Priorities; 2. Life-Cycle Assessment and Economic Impact; 3. Socio-Economic Studies; 4. Education and Public Awareness; 5. Market Introduction; 7. Regional Activities; 8. The Zero Regio Project. (K). Safety Issues: 1. Vehicle and Infrastructural Safety; 2. Regulations, Codes, Standards and Test

18th world hydrogen energy conference 2010. Proceedings

International Nuclear Information System (INIS)

2010-01-01

This CD-ROM contains lectures, power points slides and posters presented on the 18th World Hydrogen Energy Conference. The topics of the conference are: (A). Fuel Cell Basics: 1. Electrochemistry of PEM Fuell Cells; 2. PEM/HT-PEM Fuel Cells: Electrolytes, Stack Components; 3. Direct Fuel Cells; 4. High-Temperature Fuel Cells; 5. Advanced Modelling (B). Existing and Emerging Markets: 1. Off-Grid Power Supply and Premium Power Generation; 2. Space and Aeronautic Applications; 3. APUs for LDV, Trucks, Ships and Airplanes; 4. Portable Applications and Light Traction. (C). Stationary Applications: 1. High-Temperature Fuel Cells; 2. Fuell Cells for Buildings. (D). Transportation Applications: 1. Fuel-Cell Power Trains; 3. Hydrogen Internal Combustion Engines; 4. Systems Analysis and Well-to-Wheel Studies; 5. Demonstration Projects, Costs and Market Introduction; 6 Electrification in Transportation Systems. (E). Fuel Infrastructures: 1. Hydrogen Distribution Technologies; 2. Hydrogen Deployment; 3. Fuel Provision for Early Market Applications. (G). Hydrogen Production Technologies: 1a. Photobiological Hydrogen Production; 1b. Fermentative Hydrogen Production; 1c. The HYVOLUTION Project. (H). Thermochemical Cycles: 3a. Hydrogen from Renewable Electricity; 3b. High-Temperature Electrolysis; 3c Alcaline Electrolysis; 3d PEM Electrolysis; 4a Reforming and Gasification-Fossil Energy Carriers; 4b Reforming and Gasification-Biomass; 5. Hydrogen-Separation Membranes; 6. Hydrogen Systems Assessment;.7. Photocatalysis (I). Storages: 1. Physical Hydrogen Storage; 2a. Metal Hydrides; 2b. Complex Hydrides; 3. Adsorption Technologies; (J). Strategic Analyses: 1. Research + Development Target and Priorities; 2. Life-Cycle Assessment and Economic Impact; 3. Socio-Economic Studies; 4. Education and Public Awareness; 5. Market Introduction; 7. Regional Activities; 8. The Zero Regio Project. (K). Safety Issues: 1. Vehicle and Infrastructural Safety; 2. Regulations, Codes, Standards and Test

CO2-free hydrogen as a substitute to fossil fuels: What are the targets? Prospective assessment of the hydrogen market attractiveness

International Nuclear Information System (INIS)

Mansilla, C.; Avril, S.; Imbach, J.; Le Duigou, A.

2012-01-01

Hydrogen is usually presented as a promising energy carrier that has a major role to play in low carbon mobility, through the use of fuel cells. However, such a market is not expected in the short term. In the meantime, hydrogen may also contribute to reduce carbon emissions in diverse sectors: oil refining, low carbon mobility through the industrial deployment of advanced bio-fuels, natural gas consumption, and methanol production. According to the targeted market, objective costs are rather different; and so is the reachable mitigated CO 2 amount. This paper assesses the dynamics of these markets' attractiveness, in order to provide target costs for CO 2 -free hydrogen production. The potential of the markets of hydrogen as a fuel and hydrogen for the biomass-to-liquid production is highlighted, as they could represent significant volumes by 2050, as well as interesting perspectives for CO 2 emission reduction. However the targets are very sensitive to the CO 2 price, thus highlighting the requirement for economic instruments in order to facilitate the penetration of such technologies. Hydrogen is then highlighted as a key player of the energy system in the years to come, as the connection of the energy and mobility sectors. (authors)

Advanced thermal barrier coatings for operation in high hydrogen content fueled gas turbines.

Energy Technology Data Exchange (ETDEWEB)

Sampath, Sanjay [Stony Brook Univ., NY (United States)

2015-04-02

The Center for Thermal Spray Research (CTSR) at Stony Brook University in partnership with its industrial Consortium for Thermal Spray Technology is investigating science and technology related to advanced metallic alloy bond coats and ceramic thermal barrier coatings for applications in the hot section of gasified coal-based high hydrogen turbine power systems. In conjunction with our OEM partners (GE and Siemens) and through strategic partnership with Oak Ridge National Laboratory (ORNL) (materials degradation group and high temperature materials laboratory), a systems approach, considering all components of the TBC (multilayer ceramic top coat, metallic bond coat & superalloy substrate) is being taken during multi-layered coating design, process development and subsequent environmental testing. Recent advances in process science and advanced in situ thermal spray coating property measurement enabled within CTSR has been incorporated for full-field enhancement of coating and process reliability. The development of bond coat processing during this program explored various aspects of processing and microstructure and linked them to performance. The determination of the bond coat material was carried out during the initial stages of the program. Based on tests conducted both at Stony Brook University as well as those carried out at ORNL it was determined that the NiCoCrAlYHfSi (Amdry) bond coats had considerable benefits over NiCoCrAlY bond coats. Since the studies were also conducted at different cycling frequencies, thereby addressing an associated need for performance under different loading conditions, the Amdry bond coat was selected as the material of choice going forward in the program. With initial investigations focused on the fabrication of HVOF bond coats and the performance of TBC under furnace cycle tests , several processing strategies were developed. Two-layered HVOF bond coats were developed to render optimal balance of density and surface roughness

Advanced materials for energy storage

Energy Technology Data Exchange (ETDEWEB)

Liu, Chang; Li, Feng; Ma, Lai-Peng; Cheng, Hui-Ming [Shenyang National Laboratory for Materials Science Institute of Metal Research, Chinese Academy of Sciences 72 Wenhua Road, Shenyang 110016 (China)

2010-02-23

Popularization of portable electronics and electric vehicles worldwide stimulates the development of energy storage devices, such as batteries and supercapacitors, toward higher power density and energy density, which significantly depends upon the advancement of new materials used in these devices. Moreover, energy storage materials play a key role in efficient, clean, and versatile use of energy, and are crucial for the exploitation of renewable energy. Therefore, energy storage materials cover a wide range of materials and have been receiving intensive attention from research and development to industrialization. In this review, firstly a general introduction is given to several typical energy storage systems, including thermal, mechanical, electromagnetic, hydrogen, and electrochemical energy storage. Then the current status of high-performance hydrogen storage materials for on-board applications and electrochemical energy storage materials for lithium-ion batteries and supercapacitors is introduced in detail. The strategies for developing these advanced energy storage materials, including nanostructuring, nano-/microcombination, hybridization, pore-structure control, configuration design, surface modification, and composition optimization, are discussed. Finally, the future trends and prospects in the development of advanced energy storage materials are highlighted. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

Test Concept for Advanced Oxidation Techniques

DEFF Research Database (Denmark)

Bennedsen, Lars Rønn; Søgaard, Erik Gydesen; Mortensen, Lars

advanced on-site oxidation tests. The remediation techniques included are electrochemical oxidation, photochemical/photocatalytic oxidation, ozone, hydrogen peroxide, permanganate, and persulfate among others. A versatile construction of the mobile test unit makes it possible to combine different...

The Advanced High-Temperature Reactor (AHTR) for Producing Hydrogen to Manufacture Liquid Fuels

International Nuclear Information System (INIS)

Forsberg, C.W.; Peterson, P.F.; Ott, L.

2004-01-01

Conventional world oil production is expected to peak within a decade. Shortfalls in production of liquid fuels (gasoline, diesel, and jet fuel) from conventional oil sources are expected to be offset by increased production of fuels from heavy oils and tar sands that are primarily located in the Western Hemisphere (Canada, Venezuela, the United States, and Mexico). Simultaneously, there is a renewed interest in liquid fuels from biomass, such as alcohol; but, biomass production requires fertilizer. Massive quantities of hydrogen (H2) are required (1) to convert heavy oils and tar sands to liquid fuels and (2) to produce fertilizer for production of biomass that can be converted to liquid fuels. If these liquid fuels are to be used while simultaneously minimizing greenhouse emissions, nonfossil methods for the production of H2 are required. Nuclear energy can be used to produce H2. The most efficient methods to produce H2 from nuclear energy involve thermochemical cycles in which high-temperature heat (700 to 850 C) and water are converted to H2 and oxygen. The peak nuclear reactor fuel and coolant temperatures must be significantly higher than the chemical process temperatures to transport heat from the reactor core to an intermediate heat transfer loop and from the intermediate heat transfer loop to the chemical plant. The reactor temperatures required for H2 production are at the limits of practical engineering materials. A new high-temperature reactor concept is being developed for H2 and electricity production: the Advanced High-Temperature Reactor (AHTR). The fuel is a graphite-matrix, coated-particle fuel, the same type that is used in modular high-temperature gas-cooled reactors (MHTGRs). The coolant is a clean molten fluoride salt with a boiling point near 1400 C. The use of a liquid coolant, rather than helium, reduces peak reactor fuel and coolant temperatures 100 to 200 C relative to those of a MHTGR. Liquids are better heat transfer fluids than gases

Factors related to use of prostate cancer screening: the Alberta Tomorrow Project

Science.gov (United States)

Aronson, Kristan J; James, Alison; McGregor, Elizabeth S; Bryant, Heather

2007-01-01

Background Very few data are available on the determinants of PSA testing in Canada, and it is a matter of debate whether prostate-specific antigen (PSA) screening in asymptomatic men age 50 and older with no risk factors for prostate cancer is useful. If PSA screening is introduced into the periodic health examination, it will be important to know what factors influence its use. Objectives The purpose of this study is to determine the factors associated with PSA testing among asymptomatic men age 50 and older participating in the Tomorrow Project in Alberta. Methods The Tomorrow Project is a population-based cohort study with over 11,000 participants accrued in Alberta since February 2003. Information was collected on medical history, sociodemographic factors, health status and lifestyle characteristics. This analysis includes 2136 men 50 years of age and older. The independent association between various factors and recent PSA screening is estimated using logistic regression. Results Approximately 50% of of the study group had received one or more PSA tests in their lifetime. Of these, 58% were asymptomatic for prostate disease at the time of their most recent PSA test. Variables independently associated with recent PSA screening for prostate cancer in this population include older age (≥ 65 versus < 55 years: adjusted odds ratio [OR] 2.60; 95% confidence interval [CI] 1.77–3.83), higher income (≥ $80,000 versus < $20,000, OR 1.97; 95% CI 1.09–3.55), region of health care delivery, perception of health status (good versus excellent health status; OR 0.65, CI 0.43–0.96], increased number of chronic health conditions (OR 1.73, 95% CI 1.10–2.71), and history of colorectal cancer screening with fecal occult blood test (OR 2.21; 95% CI 1.73–2.83). Conclusions An increasing proportion of men in Alberta are receiving a PSA test. A number of significant predictors of having a PSA test were identified, suggesting that factors other than having a clinical

Hydrogen production processes; Procedes de production d'hydrogene

Energy Technology Data Exchange (ETDEWEB)

NONE

2003-07-01

The goals of this first Gedepeon workshop on hydrogen production processes are: to stimulate the information exchange about research programs and research advances in the domain of hydrogen production processes, to indicate the domains of interest of these processes and the potentialities linked with the coupling of a nuclear reactor, to establish the actions of common interest for the CEA, the CNRS, and eventually EDF, that can be funded in the framework of the Gedepeon research group. This document gathers the slides of the 17 presentations given at this workshop and dealing with: the H{sub 2} question and the international research programs (Lucchese P.); the CEA's research program (Lucchese P., Anzieu P.); processes based on the iodine/sulfur cycle: efficiency of a facility - flow-sheets, efficiencies, hard points (Borgard J.M.), R and D about the I/S cycle: Bunsen reaction (Colette S.), R and D about the I/S cycle: the HI/I{sub 2}/H{sub 2}O system (Doizi D.), demonstration loop/chemical engineering (Duhamet J.), materials and corrosion (Terlain A.); other processes under study: the Westinghouse cycle (Eysseric C.), other processes under study at the CEA (UT3, plasma,...) (Lemort F.), database about thermochemical cycles (Abanades S.), Zn/ZnO cycle (Broust F.), H{sub 2} production by cracking, high temperature reforming with carbon trapping (Flamant G.), membrane technology (De Lamare J.); high-temperature electrolysis: SOFC used as electrolyzers (Grastien R.); generic aspects linked with hydrogen production: technical-economical evaluation of processes (Werkoff F.), thermodynamic tools (Neveu P.), the reactor-process coupling (Aujollet P.). (J.S.)

Alberta's Tomorrow Project: adherence to cancer prevention recommendations pertaining to diet, physical activity and body size.

Science.gov (United States)

Whelan, Heather K; Xu, Jian-Yi; Vaseghi, Sanaz; Lo Siou, Geraldine; McGregor, S Elizabeth; Robson, Paula J

2017-05-01

To explore cross-sectional adherence to cancer prevention recommendations by adults enrolled in a prospective cohort in Alberta, Canada. Questionnaire data were used to construct a composite cancer prevention adherence score for each participant, based on selected personal recommendations published by the World Cancer Research Fund/American Institute for Cancer Research (2007). Data were self-reported on health and lifestyle, past-year physical activity and past-year FFQ. The scores accounted for physical activity, dietary supplement use, body size, and intakes of alcohol, fruit, vegetables and red meat. Tobacco exposure was also included. Scores ranged from 0 (least adherent) to 7 (most adherent). Alberta's Tomorrow Project; a research platform based on a prospective cohort. Adult men and women (n 24 988) aged 35-69 years recruited by random digit dialling and enrolled in Alberta's Tomorrow Project between 2001 and 2009. Of the cohort, 14 % achieved adherence scores ≥5 and 60 % had scores ≤3. Overall adherence scores were higher in women (mean (sd): 3·4 (1·1)) than in men (3·0 (1·2)). The extent of overall adherence was also associated with level of education, employment status, annual household income, personal history of chronic disease, family history of chronic disease and age. Reported adherence to selected personal recommendations for cancer prevention was low in this cohort of adults. In the short to medium term, these results suggest that more work is required to identify behaviours to target with cancer prevention strategies at a population level. Future work will explore the associations between adherence scores and cancer risk in this cohort.

The Earth Science for Tomorrows Classroom

Science.gov (United States)

Shanskiy, Merrit

2015-04-01

The Earth sciences comprises many fascinating topics that is teached to different age level pupils/students in order to bring hard core science closer to their daily life. With developing possibilities in IT, multimedia overall electronic sector the teachers/lecturers have continuous possibilities to accomplish novel approaches and utilize new ideas to make science more interesting for students in all ages. Emerging, from personal experiences, the teaching of our surrounding Environment can be very enjoyable. In our everyday life the SOIL remains invisible. The soil is covered by plant cover which makes the topic somewhat in distant that is not "visible" to an eye and its importance is underestimated. In other hand, the SOIL is valuable primary resource for food production and basis of life for healthy environment. From several studies have found that because its complications, SOIL related topics are not very often chosen topic for course or diploma works by students. The lower-school students are very open to environmental topics accordingly to the grades. Here, the good results can be obtained through complimentary materials creation, like story telling and drawing books and puzzles. The middle/ and upper/school students will experience "real science" being able to learn what the science is about which often can play a important role on making choices for future curriculum completion at university level. Current presentation shares the ideas of selected methods that had showed successful results on different Earth Science topics teaching (biodiversity, growing substrates, green house gas emissions). For some ideas the presentation introduces also the further developmental possibilities to be used in teaching at Tomorrows Classroom.

Meeting report - Which role for hydrogen in the energy system?

International Nuclear Information System (INIS)

Dupre La Tour, Stephane; Raimondo, E.

2015-01-01

Before giving some general information about the activities of the SFEN, about some events regarding the energy sector, and about meetings to come, a contribution is proposed on the role of hydrogen in the energy system. The author recalls the industrial methods used to produce hydrogen (water electrolysis, reforming of fossil fuels), indicates the main applications (fuel cells, power-to-gas, industrial applications, fuel for transport). He discusses the potential of hydrogen as a good energy vector for the future. Required technical advances are identified, as well as potential industrial applications. The competitiveness of the different hydrogen production technologies is discussed, and the different uses are more precisely described and discussed (principle of fuel cell, French researches on hybrid vehicle, application to heavy vehicles, perspectives for air transport). Other technological issues are briefly addressed: direct injection of hydrogen in gas distribution network or production of synthetic methane, combined hydrolysis of CO 2 and H 2 O, hydrogen storage. After having outlined some remaining questions about the exploitation of hydrogen as energy vector, the author proposes some guidelines for the future: development of tools to analyse the competitiveness of hydrogen uses, improvement of existing technologies in terms of performance and costs, development of breakthrough technologies

Physical activity education in the undergraduate curricula of all UK medical schools. Are tomorrow's doctors equipped to follow clinical guidelines?

OpenAIRE

Weiler, Richard; Chew, Stephen; Coombs, Ngaire; Hamer, Mark; Stamatakis, Emmanuel

2012-01-01

Physical activity (PA) is a cornerstone of disease prevention and treatment. There is, however, a considerable disparity between public health policy, clinical guidelines and the delivery of physical activity promotion within the National Health Service in the UK. If this is to be addressed in the battle against non-communicable diseases, it is vital that tomorrow's doctors understand the basic science and health benefits of physical activity. The aim of this study was to assess the provision...

Carbon-coated Li3 N nanofibers for advanced hydrogen storage.

Science.gov (United States)

Xia, Guanglin; Li, Dan; Chen, Xiaowei; Tan, Yingbin; Tang, Ziwei; Guo, Zaiping; Liu, Huakun; Liu, Zongwen; Yu, Xuebin

2013-11-20

3D porous carbon-coated Li3 N nanofibers are successfully fabricated via the electrospinning technique. The as-prepared nanofibers exhibit a highly improved hydrogen-sorption performance in terms of both thermodynamics and kinetics. More interestingly, a stable regeneration can be achieved due to the unique structure of the nanofibers, over 10 cycles of H2 sorption at a temperature as low as 250 °C. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hydrogen energy

International Nuclear Information System (INIS)

2005-03-01

This book consists of seven chapters, which deals with hydrogen energy with discover and using of hydrogen, Korean plan for hydrogen economy and background, manufacturing technique on hydrogen like classification and hydrogen manufacture by water splitting, hydrogen storage technique with need and method, hydrogen using technique like fuel cell, hydrogen engine, international trend on involving hydrogen economy, technical current for infrastructure such as hydrogen station and price, regulation, standard, prospect and education for hydrogen safety and system. It has an appendix on related organization with hydrogen and fuel cell.

Global Assessment of Hydrogen Technologies – Tasks 3 & 4 Report Economic, Energy, and Environmental Analysis of Hydrogen Production and Delivery Options in Select Alabama Markets: Preliminary Case Studies

Energy Technology Data Exchange (ETDEWEB)

Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Gillette, Jerry; Elgowainy, Amgad; Mintz, Marianne

2007-12-01

This report documents a set of case studies developed to estimate the cost of producing, storing, delivering, and dispensing hydrogen for light-duty vehicles for several scenarios involving metropolitan areas in Alabama. While the majority of the scenarios focused on centralized hydrogen production and pipeline delivery, alternative delivery modes were also examined. Although Alabama was used as the case study for this analysis, the results provide insights into the unique requirements for deploying hydrogen infrastructure in smaller urban and rural environments that lie outside the DOE’s high priority hydrogen deployment regions. Hydrogen production costs were estimated for three technologies – steam-methane reforming (SMR), coal gasification, and thermochemical water-splitting using advanced nuclear reactors. In all cases examined, SMR has the lowest production cost for the demands associated with metropolitan areas in Alabama. Although other production options may be less costly for larger hydrogen markets, these were not examined within the context of the case studies.

Hydrogen Process Coupling to Modular Helium Reactors

International Nuclear Information System (INIS)

Shenoy, Arkal; Richards, Matt; Buckingham, Robert

2009-01-01

The U.S. Department of Energy (DOE) has selected the helium-cooled High Temperature Gas-Cooled Reactor (HTGR) as the concept to be used for the Next Generation Nuclear Plant (NGNP), because it is the most advanced Generation IV concept with the capability to provide process heat at sufficiently high temperatures for production of hydrogen with high thermal efficiency. Concurrently with the NGNP program, the Nuclear Hydrogen Initiative (NHI) was established to develop hydrogen production technologies that are compatible with advanced nuclear systems and do not produce greenhouse gases. The current DOE schedule for the NGNP Project calls for startup of the NGNP plant by 2021. The General Atomics (GA) NGNP pre-conceptual design is based on the GA Gas Turbine Modular Helium Reactor (GT-MHR), which utilizes a direct Brayton cycle Power Conversion System (PCS) to produce electricity with a thermal efficiency of 48%. The nuclear heat source for the NGNP consists of a single 600-MW(t) MHR module with two primary coolant loops for transport of the high-temperature helium exiting the reactor core to a direct cycle PCS for electricity generation and to an Intermediate Heat Exchanger (IHX) for hydrogen production. The GA NGNP concept is designed to demonstrate hydrogen production using both the thermochemical sulfur-iodine (SI) process and high-temperature electrolysis (HTE). The two primary coolant loops can be operated independently or in parallel. The reactor design is essentially the same as that for the GT-MHR, but includes the additional primary coolant loop to transport heat to the IHX and other modifications to allow operation with a reactor outlet helium temperature of 950 .deg. C (vs. 850 .deg. C for the GT-MHR). The IHX transfers a nominal 65 MW(t) to the secondary heat transport loop that provides the high-temperature heat required by the SI-based and HTE-based hydrogen production facilities. Two commercial nuclear hydrogen plant variations were evaluated with

Passive autocatalytic recombiners for combustible gas control in advanced light water reactors

International Nuclear Information System (INIS)

Wolff, U.; Sliter, G.

2004-01-01

A key aspect of the worldwide effort to develop advanced nuclear power plants is designing to address severe accident phenomena, including the generation of hydrogen during core melt progression (metal-water and core-concrete reactions). This design work not only resolves safety concerns with hydrogen, but also supports the development of a technical basis for simplification of off-site emergency planning. The dominant challenge to any emergency planning approach is a large, early containment failure due to pressure excursions. Among the potential contributors to large and rapid increases in containment pressure is hydrogen combustion. The more improbable a containment-threatening combustion becomes, the more appropriate the argument for significant emergency planning simplification. As discussed in this paper, catalytic recombiners provide a means to passively and reliably limit hydrogen combustion to a continuous oxidation process with virtually no potential for containment failure in passive advanced light water reactors (ALWRs). (author)

California Hydrogen Infrastructure Project

Energy Technology Data Exchange (ETDEWEB)

Heydorn, Edward C

2013-03-12

Air Products and Chemicals, Inc. has completed a comprehensive, multiyear project to demonstrate a hydrogen infrastructure in California. The specific primary objective of the project was to demonstrate a model of a real-world retail hydrogen infrastructure and acquire sufficient data within the project to assess the feasibility of achieving the nation's hydrogen infrastructure goals. The project helped to advance hydrogen station technology, including the vehicle-to-station fueling interface, through consumer experiences and feedback. By encompassing a variety of fuel cell vehicles, customer profiles and fueling experiences, this project was able to obtain a complete portrait of real market needs. The project also opened its stations to other qualified vehicle providers at the appropriate time to promote widespread use and gain even broader public understanding of a hydrogen infrastructure. The project engaged major energy companies to provide a fueling experience similar to traditional gasoline station sites to foster public acceptance of hydrogen. Work over the course of the project was focused in multiple areas. With respect to the equipment needed, technical design specifications (including both safety and operational considerations) were written, reviewed, and finalized. After finalizing individual equipment designs, complete station designs were started including process flow diagrams and systems safety reviews. Material quotes were obtained, and in some cases, depending on the project status and the lead time, equipment was placed on order and fabrication began. Consideration was given for expected vehicle usage and station capacity, standard features needed, and the ability to upgrade the station at a later date. In parallel with work on the equipment, discussions were started with various vehicle manufacturers to identify vehicle demand (short- and long-term needs). Discussions included identifying potential areas most suited for hydrogen fueling

An Opportunity for Hydrogen Fueled Supersonic Airliners

Directory of Open Access Journals (Sweden)

Alex Forbes

2011-02-01

Full Text Available This paper takes a new look at the prospects for developing supersonic civil airliners, considering global demographics, climate change issues, fuel prices and technological advances. Dramatic changes have occurred in the demographics, economics, and market intensity of the Eastern Hemisphere since the 1990s. Carbon reduction imperatives provide a major incentive to invest in developing hydrogen-fueled airliners. The “point-to-point” air route architecture has proved viable with long range mid-size airliners. With a cruise Mach number of 1.4, a large number of destinations become viable for overland supersonic flight. A conceptual design process is used to estimate cost per seat mile for a range of hydrocarbon and hydrogen fuel costs. An argument based on the ideal shape for minimal wave drag, estimates the drag penalty from using hydrogen. Viable aircraft geometries are shown to exist, that match the theoretical ideal shape, showing that the drag estimate is achievable. Conservative design arguments and market estimates suggest that hydrogen-fueled airliners can achieve seat-mile costs low enough to open a large worldwide market and justify a viable fleet size.

Research on corrosion aspects of the advanced cold process canister

International Nuclear Information System (INIS)

Blackwood, D.J.; Hoch, A.R.; Naish, C.C.; Rance, A.

1994-01-01

The Advanced Cold Process Canister (ACPC) is a waste canister being developed jointly by SKB and TVO for the disposal of spent nuclear fuel. It comprises an outer copper canister, with a carbon steel canister inside. A concern regarding the use of the ACPC is that, in the unlikely event that the outer copper canister is penetrated, the anaerobic corrosion of the carbon steel container may result in the formation of hydrogen gas bubbles. These bubbles could disrupt the backfill, and thus increase water flow through the near field and the flux of radionuclides to the host geology. A number of factors that influence the rate at which hydrogen evolves as a result of the anaerobic corrosion of carbon steel in artificial granitic groundwaters have been investigated. A previously observed, time-dependent decline in the hydrogen evolution rate has been confirmed as being due to the production of magnetite film. Once the magnetite film is about 0.7-1.0 μm thick, the rate of hydrogen evolution reaches a steady state value. The pH and the ionic strength of the groundwater were both found to influence the long-term hydrogen evolution rate. The results of the experimental programme were used to update a model of the corrosion behaviour and hydrogen production from the Advanced Cold Process Canister. 36 figs, 5 tabs, 13 refs

Proceedings of the 5th International workshop on hydrogen and fuel cells WICaC 2010

Energy Technology Data Exchange (ETDEWEB)

NONE

2010-07-01

The 5th International Workshop on Hydrogen and Fuel Cells - WICaC 2010 aims to bring the most recent advances on fuel cell and hydrogen technologies. The conference will address the trends on hydrogen production, distribution, delivery, storage and infrastructure as well as fuel cell research, development, demonstration and commercialization. Some of the issues addressed at WICaC 2010 are: the official Brazilian hydrogen and fuel cell programs and its participation in the international programs and partnerships such as the IPHE (The International Partnership for Hydrogen and Fuel Cells in the Economy); the integration of renewable energy sources with hydrogen and fuel cell systems; the challenges to deploy the commercialization and use of fuel cells and hydrogen; distributed generation of energy; fuel cell uses in portable devices and in vehicles; life-cycle assessment of fuel cells and hydrogen technologies; environmental aspects; energy efficiency.

Safety risks of hydrogen fuel for applications in transportation vehicles.

Science.gov (United States)

2009-04-01

Combustion of hydrocarbon fuels in many practical applications produces pollutants that are harmful to human health and environment. Hydrogen fuel is considered to be a potential answer to the clean energy demands, especially with the advances in fue...

Hydrogen as a New Class of Radioprotective Agent

Science.gov (United States)

Qian, Liren; Shen, Jianliang; Chuai, Yunhai; Cai, Jianming

2013-01-01

It is well known that most of the ionizing radiation-induced damage is caused by hydroxyl radicals (·OH) follows radiolysis of H2O. Molecular hydrogen (H2) has antioxidant activities by selectively reducing ·OH and peroxynitrite(ONOO-). We firstly hypothesized and demonstrated the radioprotective effect of H2 in vitro and in vivo, which was also repeated on different experimental animal models by different departments. A randomized, placebo-controlled study showed that consumption of hydrogen-rich water reduces the biological reaction to radiation-induced oxidative stress without compromising anti-tumor effects. These encouraging results suggested that H2 represents a potentially novel preventative strategy for radiation-induced oxidative injuries. H2 is explosive. Therefore, administration of hydrogen-rich solution (physiological saline/pure water/other solutions saturated with H2) may be more practical in daily life and more suitable for daily consumption. This review focuses on major scientific and clinical advances of hydrogen-rich solution/H2 as a new class of radioprotective agent. PMID:24155664

Multi-criteria analysis on how to select solar radiation hydrogen production system

Energy Technology Data Exchange (ETDEWEB)

Badea, G.; Naghiu, G. S., E-mail: naghiu.george@gmail.com; Felseghi, R.-A.; Giurca, I., E-mail: giurca-ioan@yahoo.com [Technical University of Cluj-Napoca, Faculty of Building Services Engineering, Boulevard December 21, no. 128-130, Cluj-Napoca, 400604 (Romania); Răboacă, S. [National R& D Institute for Cryogenic and Isotopic Technologies, str. Uzinei, no. 4, Rm. Vălcea, 240050 (Romania); Aşchilean, I. [SC ACI Cluj SA, Avenue Dorobanţilor, no. 70, Cluj-Napoca, 400609 (Romania)

2015-12-23

The purpose of this article is to present a method of selecting hydrogen-production systems using the electric power obtained in photovoltaic systems, and as a selecting method, we suggest the use of the Advanced Multi-Criteria Analysis based on the FRISCO formula. According to the case study on how to select the solar radiation hydrogen production system, the most convenient alternative is the alternative A4, namely the technical solution involving a hydrogen production system based on the electrolysis of water vapor obtained with concentrated solar thermal systems and electrical power obtained using concentrating photovoltaic systems.

FY10 Engineering Innovations, Research and Technology Report

Energy Technology Data Exchange (ETDEWEB)

Lane, M A; Aceves, S M; Paulson, C N; Candy, J V; Bennett, C V; Carlisle, K; Chen, D C; White, D A; Bernier, J V; Puso, M A; Weisgraber, T H; Corey, B; Lin, J I; Wheeler, E K; Conway, A M; Kuntz, J D; Spadaccini, C M; Dehlinger, D A; Kotovsky, J; Nikolic, R; Mariella, R P; Foudray, A K; Tang, V; Guidry, B L; Ng, B M; Lemmond, T D; Chen, B Y; Meyers, C A; Houck, T L

2011-01-11

This report summarizes key research, development, and technology advancements in Lawrence Livermore National Laboratory's Engineering Directorate for FY2010. These efforts exemplify Engineering's nearly 60-year history of developing and applying the technology innovations needed for the Laboratory's national security missions, and embody Engineering's mission to ''Enable program success today and ensure the Laboratory's vitality tomorrow.'' Leading off the report is a section featuring compelling engineering innovations. These innovations range from advanced hydrogen storage that enables clean vehicles, to new nuclear material detection technologies, to a landmine detection system using ultra-wideband ground-penetrating radar. Many have been recognized with R&D Magazine's prestigious R&D 100 Award; all are examples of the forward-looking application of innovative engineering to pressing national problems and challenging customer requirements. Engineering's capability development strategy includes both fundamental research and technology development. Engineering research creates the competencies of the future where discovery-class groundwork is required. Our technology development (or reduction to practice) efforts enable many of the research breakthroughs across the Laboratory to translate from the world of basic research to the national security missions of the Laboratory. This portfolio approach produces new and advanced technological capabilities, and is a unique component of the value proposition of the Lawrence Livermore Laboratory. The balance of the report highlights this work in research and technology, organized into thematic technical areas: Computational Engineering; Micro/Nano-Devices and Structures; Measurement Technologies; Engineering Systems for Knowledge Discovery; and Energy Manipulation. Our investments in these areas serve not only known programmatic requirements of today and tomorrow, but

USE OF THE MODULAR HELIUM REACTOR FOR HYDROGEN PRODUCTION

International Nuclear Information System (INIS)

SCHULTZ, K.R.

2003-01-01

OAK-B135 A significant ''Hydrogen Economy'' is predicted that will reduce our dependence on petroleum imports and reduce pollution and greenhouse gas emissions. Hydrogen is an environmentally attractive fuel that has the potential to displace fossil fuels, but contemporary hydrogen production is primarily based on fossil fuels. The author has recently completed a three-year project for the US Department of Energy (DOE) whose objective was to ''define an economically feasible concept for production of hydrogen, using an advanced high-temperature nuclear reactor as the energy source''. Thermochemical water-slitting, a chemical process that accomplishes the decomposition of water into hydrogen and oxygen, met this objective. The goal of the first phase of this study was to evaluate thermochemical processes which offer the potential for efficient, cost-effective, large-scale production of hydrogen, and to select one for further detailed consideration. They selected the Sulfur-Iodine cycle. In the second phase, they reviewed all the basic reactor types for suitability to provide the high temperature heat needed by the selected thermochemical water splitting cycle and chose the helium gas-cooled reactor. In the third phase they designed the chemical flowsheet for the thermochemical process and estimated the efficiency and cost of the process and the projected cost of producing hydrogen. These results are summarized in this report

An overview—Functional nanomaterials for lithium rechargeable batteries, supercapacitors, hydrogen storage, and fuel cells

Energy Technology Data Exchange (ETDEWEB)

Liu, Hua Kun, E-mail: hua@uow.edu.au

2013-12-15

Graphical abstract: Nanomaterials play important role in lithium ion batteries, supercapacitors, hydrogen storage and fuel cells. - Highlights: • Nanomaterials play important role for lithium rechargeable batteries. • Nanostructured materials increase the capacitance of supercapacitors. • Nanostructure improves the hydrogenation/dehydrogenation of hydrogen storage materials. • Nanomaterials enhance the electrocatalytic activity of the catalysts in fuel cells. - Abstract: There is tremendous worldwide interest in functional nanostructured materials, which are the advanced nanotechnology materials with internal or external dimensions on the order of nanometers. Their extremely small dimensions make these materials unique and promising for clean energy applications such as lithium ion batteries, supercapacitors, hydrogen storage, fuel cells, and other applications. This paper will highlight the development of new approaches to study the relationships between the structure and the physical, chemical, and electrochemical properties of functional nanostructured materials. The Energy Materials Research Programme at the Institute for Superconducting and Electronic Materials, the University of Wollongong, has been focused on the synthesis, characterization, and applications of functional nanomaterials, including nanoparticles, nanotubes, nanowires, nanoporous materials, and nanocomposites. The emphases are placed on advanced nanotechnology, design, and control of the composition, morphology, nanostructure, and functionality of the nanomaterials, and on the subsequent applications of these materials to areas including lithium ion batteries, supercapacitors, hydrogen storage, and fuel cells.

An overview—Functional nanomaterials for lithium rechargeable batteries, supercapacitors, hydrogen storage, and fuel cells

International Nuclear Information System (INIS)

Liu, Hua Kun

2013-01-01

Graphical abstract: Nanomaterials play important role in lithium ion batteries, supercapacitors, hydrogen storage and fuel cells. - Highlights: • Nanomaterials play important role for lithium rechargeable batteries. • Nanostructured materials increase the capacitance of supercapacitors. • Nanostructure improves the hydrogenation/dehydrogenation of hydrogen storage materials. • Nanomaterials enhance the electrocatalytic activity of the catalysts in fuel cells. - Abstract: There is tremendous worldwide interest in functional nanostructured materials, which are the advanced nanotechnology materials with internal or external dimensions on the order of nanometers. Their extremely small dimensions make these materials unique and promising for clean energy applications such as lithium ion batteries, supercapacitors, hydrogen storage, fuel cells, and other applications. This paper will highlight the development of new approaches to study the relationships between the structure and the physical, chemical, and electrochemical properties of functional nanostructured materials. The Energy Materials Research Programme at the Institute for Superconducting and Electronic Materials, the University of Wollongong, has been focused on the synthesis, characterization, and applications of functional nanomaterials, including nanoparticles, nanotubes, nanowires, nanoporous materials, and nanocomposites. The emphases are placed on advanced nanotechnology, design, and control of the composition, morphology, nanostructure, and functionality of the nanomaterials, and on the subsequent applications of these materials to areas including lithium ion batteries, supercapacitors, hydrogen storage, and fuel cells

1999 annual summary report on results. International clean energy network using hydrogen conversion (WE-NET)

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

The R and D were conducted on the international clean network (WE-NET) which aims at producing hydrogen by using renewable energy, converting it in a form suitable for transportation and supplying the hydrogen to places of quantity consumption of energy. The FY 1999 results were summed up. In the system evaluation, study was made on sodium carbonate electrolysis by-producing hydrogen, the supply amount by coke oven by-producing hydrogen and the economical efficiency, etc. As to the safety, study was made on the design of hydrogen supply stand model. Concerning the power generation technology, study was conducted on element technologies of injection valve, exhaust gas condenser, gas/liquid separator, etc. Relating to the hydrogen fueled vehicle system, the shock destructive testing, etc. were conducted on the hydrogen tank and hydrogen storage alloys. Besides, a lot of R and D were carried out of pure water use solid polymer fuel cells, hydrogen stand, hydrogen production technology, hydrogen transportation/storage technology, low temperature materials, transportation/storage using hydrogen storage alloys, innovative advanced technology, etc. (NEDO)

Hydrogen production system coupled with high-temperature gas-cooled reactor (HTTR)

International Nuclear Information System (INIS)

Shiozawa, Shusaku

2003-01-01

On the HTTR program, R and D on nuclear reactor technology and R and D on thermal application technology such as hydrogen production and so on, are advanced. When carrying out power generation and thermal application such as hydrogen production and so on, it is, at first, necessary to supply nuclear heat safely, stably and in low cost, JAERI carries out some R and Ds on nuclear reactor technology using HTTR. In parallel to this, JAERI also carries out R and D for jointing nuclear reactor system with thermal application systems because of no experience in the world on high temperature heat of about 1,000 centigrade supplied by nuclear reactor except power generation, and R and D on thermochemical decomposition method IS process for producing hydrogen from water without exhaust of carbon dioxide. Here were described summaries on R and D on nuclear reactor technology, R and D on jointing technology using HTTR hydrogen production system, R and D on IS process hydrogen production, and comparison hydrogen production with other processes. (G.K.)

Measurement of dissolved hydrogen and hydrogen gas transfer in a hydrogen-producing reactor

Energy Technology Data Exchange (ETDEWEB)

Shizas, I.; Bagley, D.M. [Toronto Univ., ON (Canada). Dept. of Civil Engineering

2004-07-01

This paper presents a simple method to measure dissolved hydrogen concentrations in the laboratory using standard equipment and a series of hydrogen gas transfer tests. The method was validated by measuring hydrogen gas transfer parameters for an anaerobic reactor system that was purged with 10 per cent carbon dioxide and 90 per cent nitrogen using a coarse bubble diffuser stone. Liquid samples from the reactor were injected into vials and hydrogen was allowed to partition between the liquid and gaseous phases. The concentration of dissolved hydrogen was determined by comparing the headspace injections onto a gas chromatograph and a standard curve. The detection limit was 1.0 x 10{sup -5} mol/L of dissolved hydrogen. The gas transfer rate for hydrogen in basal medium and anaerobic digester sludge was used to validate the method. Results were compared with gas transfer models. In addition to monitoring dissolved hydrogen in reactor systems, this method can help improve hydrogen production potential. 1 ref., 4 figs.

From Pole to Pole: Educating Tomorrow's Leaders

Science.gov (United States)

Albert, M. R.; Virginia, R. A.

2003-12-01

The high northern and southern latitudes of the earth share an extreme climate, but are vastly different in their histories, ecological systems and human cultures. Polar regions are increasingly under threat from climate change, resource extraction, and the collapse of large-scale marine ecosystems. These systems are important indicators of human influence on global scale processes (ozone depletion, global warming) and are valued for their biodiversity and uniquely adapted cultures. Unfortunately, the polar regions are often poorly understood by our citizens. Dartmouth College offers a liberal arts undergraduate education that trains tomorrow's leaders in politics, humanities, science and medicine. Through the Dickey Institute of Arctic Studies at Dartmouth College, we designed and taught an undergraduate interdisciplinary course to introduce the major physical, ecological and human systems of high latitudes, including the circumpolar northern Arctic regions and the continent of Antarctic and its southern oceans. Using an interdisciplinary approach we examined the science, societies, politics and policies that shape our viewpoint of cold regions. The connections of the polar regions to global processes and international issues were emphasized. In this paper we will describe our use of differing viewpoints to examine varying topics of importance in the polar regions. Starting the course as a tourist, we proceeded as traveler, explorer, scientist, resident, and politician to reach our final goal as informed voter at the end of the semester. A variety of invited speakers enhanced the course. Hoping before the course to attract twenty students, the fifty students enrolled in the course gave us high ratings. .

Optimizing a High-Temperature Hydrogen Co-generation Reactor for Both Economic and Environmental Performance

International Nuclear Information System (INIS)

Weimar, Mark R.; Wood, Thomas W.; Reichmuth, Barbara A.; Johnson, Wayne L.

2003-01-01

This paper analyzes outcomes for a 3000 MWt High Temperature Gas Reaction nuclear power plant, given price and cost assumptions, and determined what level of hydrogen and electricity production would optimize the plant economically and environmentally (carbon reduction). The tradeoff between producing hydrogen through steam methane reformation and producing electricity is so disproportionate, that advanced reactors will likely be used only as peaking plants for electricity unless policymakers intervene with incentives to change the mix of electricity and hydrogen. The magnitude of the increase in electric prices or decrease in hydrogen prices required to allow electricity production indicate that substantial error in cost estimates would be required to change our analysis.

Room temperature Sieving of Hydrogen Isotopes Using 2-D Materials

Energy Technology Data Exchange (ETDEWEB)

Hitchcock, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Colon-Mercado, H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Krentz, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Serkiz, S. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Velten, J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Xiao, S. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-09-28

Hydrogen isotope separation is critical to the DOE’s mission in environmental remediation and nuclear nonproliferation. Isotope separation is also a critical technology for the NNSA, and the ability to perform the separations at room temperature with a relatively small amount of power and space would be a major advancement for their respective missions. Recent work has shown that 2-D materials such as graphene and hexagonal boron nitride can act as an isotopic sieve at room temperature; efficiently separating hydrogen isotopes in water with reported separation ratios of 10:1 for hydrogen: deuterium separation for a single pass. The work performed here suggests that this technique has merit, and furthermore, we are investigating optimization and scale up of the required 2-D material based membranes.

Texas Hydrogen Education Final Scientific/Technical Report

Energy Technology Data Exchange (ETDEWEB)

Hitchcock, David; Bullock, Dan

2011-06-30

The Texas Hydrogen Education project builds on past interest in hydrogen and fuel cells to help create better informed leaders and stakeholders and thereby improve decision making and planning for inclusion of hydrogen and fuel cell technologies as energy alternatives in Texas. In past years in Texas, there was considerable interest and activities about hydrogen and fuel cells (2000-­2004). During that time, the Houston Advanced Research Center (HARC) created a fuel cell consortium and a fuel cell testing lab. Prior to 2008, interest and activities had declined substantially. In 2008, in cooperation with the Texas H2 Coalition and the State Energy Conservation Office, HARC conducted a planning process to create the Texas Hydrogen Roadmap. It was apparent from analysis conducted during the course of this process that while Texas has hydrogen and fuel cell advantages, there was little program and project activity as compared with other key states. Outreach and education through the provision of informational materials and organizing meetings was seen as an effective way of reaching decision makers in Texas. Previous hydrogen projects in Texas had identified the five major urban regions for program and project development. This geographic targeting approach was adopted for this project. The project successfully conducted the five proposed workshops in four of the target metropolitan areas: San Antonio, Houston, Austin, and the Dallas-­Ft. Worth area. In addition, eight outreach events were included to further inform state and local government leaders on the basics of hydrogen and fuel cell technologies. The project achieved its primary objectives of developing communication with target audiences and assembling credible and consistent outreach and education materials. The major lessons learned include: (1) DOE’s Clean Cities programs are a key conduit to target transportation audiences, (2) real-­world fuel cell applications (fuel cell buses, fuel cell fork lifts

A review of nickel hydrogen battery technology

Energy Technology Data Exchange (ETDEWEB)

Smithrick, J.J.; O`Donnell, P.M. [NASA Lewis Research Center, Cleveland, OH (United States)

1995-12-31

This paper on nickel hydrogen batteries is an overview of the various nickel hydrogen battery design options, technical accomplishments, validation test results and trends. There is more than one nickel hydrogen battery design, each having its advantage for specific applications. The major battery designs are individual pressure vessel (IPV), common pressure vessel (CPV), bipolar and low pressure metal hydride. State-of-the-art (SOA) nickel hydrogen batteries are replacing nickel cadmium batteries in almost all geosynchronous orbit (GEO) applications requiring power above 1 kW. However, for the more severe low earth orbit (LEO) applications (>30,000 cycles), the current cycle life of 4,000 to 10,000 cycles at 60 percent DOD should be improved. A NASA Lewis Research Center innovative advanced design IPV nickel hydrogen cell led to a breakthrough in cycle life enabling LEO applications at deep depths of discharge (DOD). A trend for some future satellites is to increase the power level to greater than 6 kW. Another trend is to decrease the power to less than 1 kW for small low cost satellites. Hence, the challenge is to reduce battery mass, volume and cost. A key is to develop a light weight nickel electrode and alternate battery designs. A common pressure vessel (CPV) nickel hydrogen battery is emerging as a viable alternative to the IPV design. It has the advantage of reduced mass, volume and manufacturing costs. A 10 Ah CPV battery has successfully provided power on the relatively short lived Clementine Spacecraft.

Plasma-wall interaction of advanced materials

Directory of Open Access Journals (Sweden)

J.W. Coenen

2017-08-01

Full Text Available DEMO is the name for the first stage prototype fusion reactor considered to be the next step after ITER. For the realization of fusion energy especially materials questions pose a significant challenge already today. Advanced materials solution are under discussion in order to allow operation under reactor conditions [1] and are already under development used in the next step devices. Apart from issues related to material properties such as strength, ductility, resistance against melting and cracking one of the major issues to be tackled is the interaction with the fusion plasma. Advanced tungsten (W materials as discussed below do not necessarily add additional lifetime issues, they will, however, add concerns related to erosion or surface morphology changes due to preferential sputtering. Retention of fuel and exhaust species are one of the main concerns. Retention of hydrogen will be one of the major issues to be solved in advanced materials as especially composites and alloys will introduce new hydrogen interactions mechanisms. Initial calculations show these mechanisms. Especially for Helium as the main impurity species material issues arise related to surfaces modification and embrittlement. Solutions are proposed to mitigate effects on material properties and introduce new release mechanisms.

Design study of the cooling scheme for SMES system in ASPCS by using liquid hydrogen

Energy Technology Data Exchange (ETDEWEB)

Makida, Yasuhiro, E-mail: yasuhiro.makida@kek.jp [High Energy Accelerator Research Organization, Oho 1-1, Tsukuba 305-0801 (Japan); Shintomi, Takakazu [Nihon University, Chiyoda-ku, Tokyo 102-8251 (Japan); Asami, Takuya; Suzuki, Goro; Takao, Tomoaki [Sophia University, Chiyoda-ku, Tokyo 102-8554 (Japan); Hamajima, Takataro [Hachinohe Institutue of Technology, Hachinohe, Aomori 031-8501 (Japan); Tsuda, Makoto; Miyagi, Daisuke [Tohoku University, Aoba-ku, Sendai 980-8579 (Japan); Munakata, Kouhei; Kajiwara, Masataka [Iwatani Corp., Minato-ku, Tokyo 104-8058 (Japan)

2013-11-15

Highlights: •Advanced Superconducting Power Conditioning System is composed of SMES, FC–EL, H{sub 2} storage. •The ASPCS is proposed to be built beside a LH{sub 2} storage of a vehicle station to effectively use the cooling capability of liquid hydrogen. •The SMES coil, which is made from an MgB{sub 2} conductor, is indirectly cooled by LH{sub 2} through its own conduction. -- Abstract: From the point of view of environment and energy problems, the renewable energies have been attracting attention. However, fluctuating power generation by the renewable energies affects the stability of the power network. Thus, we propose a new electric power storage and stabilization system, Advanced Superconducting Power Conditioning System (ASPCS), in which a Superconducting Magnetic Energy Storage (SMES) and a hydrogen-energy-storage converge on a liquid hydrogen station for fuel cell vehicles. The ASPCS proposes that the SMES coils wound with MgB{sub 2} conductor are indirectly cooled by thermo-siphon circulation of liquid hydrogen to use its cooling capability. The conceptual design of cooling scheme of the ASPCS is presented.

Design study of the cooling scheme for SMES system in ASPCS by using liquid hydrogen

International Nuclear Information System (INIS)

Makida, Yasuhiro; Shintomi, Takakazu; Asami, Takuya; Suzuki, Goro; Takao, Tomoaki; Hamajima, Takataro; Tsuda, Makoto; Miyagi, Daisuke; Munakata, Kouhei; Kajiwara, Masataka

2013-01-01

Highlights: •Advanced Superconducting Power Conditioning System is composed of SMES, FC–EL, H 2 storage. •The ASPCS is proposed to be built beside a LH 2 storage of a vehicle station to effectively use the cooling capability of liquid hydrogen. •The SMES coil, which is made from an MgB 2 conductor, is indirectly cooled by LH 2 through its own conduction. -- Abstract: From the point of view of environment and energy problems, the renewable energies have been attracting attention. However, fluctuating power generation by the renewable energies affects the stability of the power network. Thus, we propose a new electric power storage and stabilization system, Advanced Superconducting Power Conditioning System (ASPCS), in which a Superconducting Magnetic Energy Storage (SMES) and a hydrogen-energy-storage converge on a liquid hydrogen station for fuel cell vehicles. The ASPCS proposes that the SMES coils wound with MgB 2 conductor are indirectly cooled by thermo-siphon circulation of liquid hydrogen to use its cooling capability. The conceptual design of cooling scheme of the ASPCS is presented

Hydrogen transport and storage in engineered glass microspheres

Energy Technology Data Exchange (ETDEWEB)

Rambach, G.D.

1994-04-20

New, high-strength, hollow, glass microspheres filled with pressurized hydrogen exhibit storage densities which make them attractive for bulk hydrogen storage and transport. The hoop stress at failure of our engineered glass microspheres is about 150,000 psi, permitting a three-fold increase in pressure limit and storage capacity above commercial microspheres, which fail at wall stresses of 50,000 psi. For this project, microsphere material and structure will be optimized for storage capacity and charge/discharge kinetics to improve their commercial practicality. Microsphere production scale up will be performed, directed towards large-scale commercial use. Our analysis relating glass microspheres for hydrogen transport with infrastructure and economics` indicate that pressurized microspheres can be economically competitive with other forms of bulk rail and truck transport such as hydride beds, cryocarbons and pressurized tube transports. For microspheres made from advanced materials and processes, analysis will also be performed to identify the appropriate applications of the microspheres considering property variables, and different hydrogen infrastructure, end use, production and market scenarios. This report presents some of the recent modelling results for large beds of glass microspheres in hydrogen storage applications. It includes plans for experiments to identify the properties relevant to large-bed hydrogen transport and storage applications, of the best, currently producible, glass microspheres. This work began in March, 1994. Project successes will be manifest in the matching of cur-rent glass microspheres with a useful application in hydrogen bulk transport and storage, and in developing microsphere materials and processes that increase the storage density and reduce the storage energy requirement.

Carbon nanotube materials for hydrogen storage

Energy Technology Data Exchange (ETDEWEB)

Dillon, A.C.; Parilla, P.A.; Jones, K.M.; Riker, G.; Heben, M.J. [National Renewable Energy Lab., Golden, CO (United States)

1998-08-01

Carbon single-wall nanotubes (SWNTs) are essentially elongated pores of molecular dimensions and are capable of adsorbing hydrogen at relatively high temperatures and low pressures. This behavior is unique to these materials and indicates that SWNTs are the ideal building block for constructing safe, efficient, and high energy density adsorbents for hydrogen storage applications. In past work the authors developed methods for preparing and opening SWNTs, discovered the unique adsorption properties of these new materials, confirmed that hydrogen is stabilized by physical rather than chemical interactions, measured the strength of interaction to be {approximately} 5 times higher than for adsorption on planar graphite, and performed infrared absorption spectroscopy to determine the chemical nature of the surface terminations before, during, and after oxidation. This year the authors have made significant advances in synthesis and characterization of SWNT materials so that they can now prepare gram quantities of high-purity SWNT samples and measure and control the diameter distribution of the tubes by varying key parameters during synthesis. They have also developed methods which purify nanotubes and cut nanotubes into shorter segments. These capabilities provide a means for opening the tubes which were unreactive to the oxidation methods that successfully opened tubes, and offer a path towards organizing nanotube segments to enable high volumetric hydrogen storage densities. They also performed temperature programmed desorption spectroscopy on high purity carbon nanotube material obtained from collaborator Prof. Patrick Bernier and finished construction of a high precision Seivert`s apparatus which will allow the hydrogen pressure-temperature-composition phase diagrams to be evaluated for SWNT materials.

Improvement study for the dry-low-NOx hydrogen micromix combustion technology

Directory of Open Access Journals (Sweden)

A. Haj Ayed

2015-09-01

Full Text Available The dry-low-NOx (DLN micromix combustion principle is developed for the low emission combustion of hydrogen in an industrial gas turbine APU GTCP 36-300. The further decrease of NOx emissions along a wider operation range with pure hydrogen supports the introduction of the micromix technology to industrial applications. Experimental and numerical studies show the successful advance of the DLN micromix combustion to extended DLN operation range. The impact of the hydrogen fuel properties on the combustion principle and aerodynamic flame stabilization design laws, flow field, flame structure and emission characteristics is investigated by numerical analysis using an eddy dissipation concept combustion model and validated against experimental results.

Dependence of hydrogen-induced lattice defects and hydrogen embrittlement of cold-drawn pearlitic steels on hydrogen trap state, temperature, strain rate and hydrogen content

International Nuclear Information System (INIS)

Doshida, Tomoki; Takai, Kenichi

2014-01-01

The effects of the hydrogen state, temperature, strain rate and hydrogen content on hydrogen embrittlement susceptibility and hydrogen-induced lattice defects were evaluated for cold-drawn pearlitic steel that absorbed hydrogen in two trapping states. Firstly, tensile tests were carried out under various conditions to evaluate hydrogen embrittlement susceptibility. The results showed that peak 2 hydrogen, desorbed at temperatures above 200 °C as determined by thermal desorption analysis (TDA), had no significant effect on hydrogen embrittlement susceptibility. In contrast, hydrogen embrittlement susceptibility increased in the presence of peak 1 hydrogen, desorbed from room temperature to 200 °C as determined by TDA, at temperatures higher than −30 °C, at lower strain rates and with higher hydrogen content. Next, the same effects on hydrogen-induced lattice defects were also evaluated by TDA using hydrogen as a probe. Peak 2 hydrogen showed no significant effect on either hydrogen-induced lattice defects or hydrogen embrittlement susceptibility. It was found that hydrogen-induced lattice defects formed under the conditions where hydrogen embrittlement susceptibility increased. This relationship indicates that hydrogen embrittlement susceptibility was higher under the conditions where the formation of hydrogen-induced lattice defects tended to be enhanced. Since hydrogen-induced lattice defects formed by the interaction between hydrogen and strain were annihilated by annealing at a temperature of 200 °C, they were presumably vacancies or vacancy clusters. One of the common atomic-level changes that occur in cold-drawn pearlitic steel showing higher hydrogen embrittlement susceptibility is the formation of vacancies and vacancy clusters

Hydrogen sensor

Science.gov (United States)

Duan, Yixiang; Jia, Quanxi; Cao, Wenqing

2010-11-23

A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

The cost of electrolytic hydrogen from off-peak power

International Nuclear Information System (INIS)

Stucki, S.

1991-01-01

The cost of electrolytic hydrogen depends on the capacity factor of the plant and the cost of electricity. Both these parameters are correlated if off-peak power is to be used for hydrogen production. Based on assumptions regarding the correlation between the electricity price and the availability of electric power, optimizations were run using a simple cost model for the electrolysis plant. The current density at which the electrolysis plant would be run is taken as a variable for optimization as well as the annual time of availability of electric power. The results of the optimizations show for a number of hypothetical electrolyser types that the optimum operation time or electricity price do not depend much on the technology used. Production cost of electrolytic hydrogen can, however, be cut by 30% by using advanced electrolysis technology. (author)

A review of nickel hydrogen battery technology

Energy Technology Data Exchange (ETDEWEB)

Smithrick, J.J.; Odonnell, P.M.

1995-05-01

This paper on nickel hydrogen batteries is an overview of the various nickel hydrogen battery design options, technical accomplishments, validation test results and trends. There is more than one nickel hydrogen battery design, each having its advantage for specific applications. The major battery designs are individual pressure vessel (IPV), common pressure vessel (CPV), bipolar and low pressure metal hydride. State-of-the-art (SOA) nickel hydrogen batteries are replacing nickel cadmium batteries in almost all geosynchronous orbit (GEO) applications requiring power above 1 kW. However, for the more severe low earth orbit (LEO) applications (greater than 30,000 cycles), the current cycle life of 4000 to 10,000 cycles at 60 percent DOD should be improved. A NASA Lewis Research Center innovative advanced design IPV nickel hydrogen cell led to a breakthrough in cycle life enabling LEO applications at deep depths of discharge (DOD). A trend for some future satellites is to increase the power level to greater than 6 kW. Another trend is to decrease the power to less than 1 kW for small low cost satellites. Hence, the challenge is to reduce battery mass, volume and cost. A key is to develop a light weight nickel electrode and alternate battery designs. A common pressure vessel (CPV) nickel hydrogen battery is emerging as a viable alternative to the IPV design. It has the advantage of reduced mass, volume and manufacturing costs. A 10 Ah CPV battery has successfully provided power on the relatively short lived Clementine Spacecraft. A bipolar nickel hydrogen battery design has been demonstrated (15,000 LEO cycles, 40 percent DOD). The advantage is also a significant reduction in volume, a modest reduction in mass, and like most bipolar designs, features a high pulse power capability. A low pressure aerospace nickel metal hydride battery cell has been developed and is on the market.

Properties of thermoplastic polymers used for hydrogen storage under pressure

International Nuclear Information System (INIS)

Jousse, F.; Mazabraud, P.; Icard, B.; Mosdale, R.; Serre-Combe, P.

2000-01-01

The storage of hydrogen is one of the points of development of industrial applications of fuel cells of type PEMFC ( Proton Exchange Membrane Fuel Cell). Developing an effective system of storage remains major. Ameliorations concerning the storage density of energy, the cost and facilities and the storage must be considered especially for the mobile applications. Among different approaches possible, the absorption on carbon nanotubes, the production by hydrides in the organic solutions or storage hyperbar in the gas state seem the most promising way. The storage of hydrogen gas at ambient temperature today appears as the simplest technical solution, the most advanced and the most economic solution. However, the energy density of hydrogen being weaker than that of the traditional fuels, of the quantities more important must be stored at equivalent rate. Hyperbar storage (higher pressure has 350 bar) of hydrogen makes it possible to reduce the volume of the tanks and strengthens the argument for their weights and cost

Hydrogen storage in complex hydrides

International Nuclear Information System (INIS)

Lupu, D.; Biris, A. R.; Misan, I.

2005-01-01

Full text: Hydrogen storage is a key enabling technology for the advancement of hydrogen and fuel cell power technologies in mobile and stationary applications. A relevant role of the fuel cell powered vehicles on the market of the transportation systems will be achieved only if the research and development of on-board vehicular hydrogen storage are able to allow a driving range of at least 500 km. The on-board hydrogen storage systems are more challenging due to the space, weight and cost limitations. This range of autonomy between refueling requires materials able to store at least 6.5% weight hydrogen, available at moderate pressures, at the working temperature of the fuel cells and with acceptable cycling stability. The intensive research on the hydrogen storage in alloys and intermetallic of the LaNi 5 , FeTi or Laves phase type compounds, which started more than three decades ago did not resulted in materials of more than about 3% H storage capacities. The 7.5% H content of the Mg hydride is still of attracting interest but though the absorption has been achieved at lower temperatures by ball milling magnesium with various amounts of nickel, the desorption can not be attained at 1 bar H 2 below 280 deg. C and the kinetics of the process is too slow. In the last decade, the attention is focused on another class of compounds, the complex hydrides of aluminum with alkali metals (alanates), due to their high hydrogen content. It was found that doping with Ti-based catalysts improve the hydrogenation/dehydrogenation conditions of NaAlH 4 . Later on, it was shown that ball milling with solid state catalysts greatly improve the hydrogen desorption kinetics of NaAlH 4 , and this also helps to the rehydriding process. The hydrogen desorption from NaAlH 4 occurs in three steps, it shows a reversible storage capacity of 5.5% H and this led to further research work for a better knowledge of its application relating properties. In this work, ball milling experiments on Na

Palladium mixed-metal surface-modified AB₅-type intermetallides enhance hydrogen sorption kinetics

Directory of Open Access Journals (Sweden)

Roman V. Denys

2010-09-01

Full Text Available Surface engineering approaches were adopted in the preparation of advanced hydrogen sorption materials, based on ‘low-temperature’, AB₅-type intermetallides. The approaches investigated included micro-encapsulation with palladium and mixed-metal mantles using electroless plating. The influence of micro-encapsulation on the surface morphology and kinetics of hydrogen charging were investigated. It was found that palladium-nickel (Pd-Ni co-deposition by electroless plating significantly improved the kinetics of hydrogen charging of the AB₅-type intermetallides at low hydrogen pressure and temperature, after long-term pre-exposure to air. The improvement in the kinetics of hydrogen charging was credited to a synergistic effect between the palladium and nickel atoms in the catalytic mantle and the formation of an ‘interfacial bridge’ for hydrogen diffusion by the nickel atoms in the deposited layer. The developed surface-modified materials may find application in highly selective hydrogen extraction, purification, and storage from impure hydrogen feeds.

Hydrogen production processes

International Nuclear Information System (INIS)

2003-01-01

The goals of this first Gedepeon workshop on hydrogen production processes are: to stimulate the information exchange about research programs and research advances in the domain of hydrogen production processes, to indicate the domains of interest of these processes and the potentialities linked with the coupling of a nuclear reactor, to establish the actions of common interest for the CEA, the CNRS, and eventually EDF, that can be funded in the framework of the Gedepeon research group. This document gathers the slides of the 17 presentations given at this workshop and dealing with: the H 2 question and the international research programs (Lucchese P.); the CEA's research program (Lucchese P., Anzieu P.); processes based on the iodine/sulfur cycle: efficiency of a facility - flow-sheets, efficiencies, hard points (Borgard J.M.), R and D about the I/S cycle: Bunsen reaction (Colette S.), R and D about the I/S cycle: the HI/I 2 /H 2 O system (Doizi D.), demonstration loop/chemical engineering (Duhamet J.), materials and corrosion (Terlain A.); other processes under study: the Westinghouse cycle (Eysseric C.), other processes under study at the CEA (UT3, plasma,...) (Lemort F.), database about thermochemical cycles (Abanades S.), Zn/ZnO cycle (Broust F.), H 2 production by cracking, high temperature reforming with carbon trapping (Flamant G.), membrane technology (De Lamare J.); high-temperature electrolysis: SOFC used as electrolyzers (Grastien R.); generic aspects linked with hydrogen production: technical-economical evaluation of processes (Werkoff F.), thermodynamic tools (Neveu P.), the reactor-process coupling (Aujollet P.). (J.S.)

Hail hydrogen

International Nuclear Information System (INIS)

Hairston, D.

1996-01-01

After years of being scorned and maligned, hydrogen is finding favor in environmental and process applications. There is enormous demand for the industrial gas from petroleum refiners, who need in creasing amounts of hydrogen to remove sulfur and other contaminants from crude oil. In pulp and paper mills, hydrogen is turning up as hydrogen peroxide, displacing bleaching agents based on chlorine. Now, new technologies for making hydrogen have the industry abuzz. With better capabilities of being generated onsite at higher purity levels, recycled and reused, hydrogen is being prepped for a range of applications, from waste reduction to purification of Nylon 6 and hydrogenation of specialty chemicals. The paper discusses the strong market demand for hydrogen, easier routes being developed for hydrogen production, and the use of hydrogen in the future

Status of advanced nuclear reactor development in Korea

International Nuclear Information System (INIS)

Kim, H.R.; Kim, K.K.; Kim, Y.W.; Joo, H.K.

2014-01-01

The Korean nuclear industry is facing new challenges to solve the spent fuel storage problem and meet the needs to diversify the application areas of nuclear energy. In order to provide solutions to these challenges, the Korea Atomic Energy Research Institute (KAERI) has been developing advanced nuclear reactors including a Sodium-cooled Fast Reactor, Very High Temperature Gas cooled Reactor (VHTR), and System-integrated Modular Advanced Reactor (SMART) with substantially improved safety, economics, and environment-friendly features. A fast reactor system is one of the most promising options for a reduction of radioactive wastes. The long-term plan for Advanced SFR development in conjunction with the pyro-process was authorized by the Korean Atomic Energy Commission in 2008. The development milestone includes specific design approval of a prototype SFR by 2020, and the construction of a prototype SFR by 2028. KAERI has been carrying out the preliminary design of a 150MWe SFR prototype plant system since 2012. The development of advanced SFR technologies and the basic key technologies necessary for the prototype SFR are also being carried out. By virtue of high-temperature heat, a VHTR has diverse applications including hydrogen production. KAERI launched a nuclear hydrogen project using a VHTR in 2006, which focused on four basic technologies: the development of design tools, very high-temperature experimental technology, TRISO fuel fabrication, and Sulfur-iodine thermo-chemical hydrogen production technology. The technology development project will be continued until 2017. A conceptual reactor design study was started in 2012 as collaboration between industry and government to enhance the early-launching of the nuclear hydrogen development and demonstration (NHDD) project. The goal of the NHDD project is to design and build a nuclear hydrogen demonstration system by 2030. KAERI has developed SMART which is a small-sized advanced integral reactor with a rated

Numerical Study on Hydrogen Flow Behavior in Two Compartments with Different Connecting Pipes

Directory of Open Access Journals (Sweden)

HanChen Liu

2017-01-01

Full Text Available Hydrogen accumulation in the containment compartments under severe accidents would result in high concentration, which could lead to hydrogen deflagration or detonation. Therefore, getting detailed hydrogen flow and distribution is a key issue to arrange hydrogen removal equipment in the containment compartments. In this study, hydrogen flow behavior in local compartments has been investigated in two horizontal compartments. The analysis model is built by 3-dimensional CFD code in Cartesian coordinates based on the connection structure of the Advanced Pressurized Water Reactor (PWR compartments. It consists of two cylindrical vessels, representing the Steam Generator compartment (SG and Core Makeup Tank compartment (CMT. With standard k-ε turbulence model, the effects of the connecting pipe size and location on hydrogen concentration distribution are investigated. Results show that increasing the diameter of connection pipe (IP which is located at 800 mm from 150 mm to 300 mm facilitates hydrogen flow between compartments. Decreasing the length of IP which is located at 800 mm from 1000 mm to 500 mm can also facilitate hydrogen flow between compartments. Lower IP is in favor of hydrogen mixing with air in non-source compartment. Higher IP is helpful for hydrogen flow to the non-source term compartment from source term compartment.

Study of the storage of hydrogen in carbon nanostructures

International Nuclear Information System (INIS)

Poirier, E.; Chahine, R.; Cossement, D.; Tessier, A.; Belanger, M.; Bose, T.K.; Dodelet, J-P.; Dellero, T.

2000-01-01

The storage of hydrogen is one of the points of development in industrial applications of fuel cells (CAP) of type PEMFC (Proton Exchange Membrane Fuel Cell). An effective system of storage would be a major step in the large scale utilization of this energy source. Process improvements concerning the storage density of energy, the cost, and facilities and the reliability of the storage must be sought in particular for the mobile applications. Among the different approaches possible, the absorption on carbon nanotubes, the production by hydrides in the organic solutions or storage hyperbar in the gas state seems the most promising way.The storage of hydrogen gas at ambient temperature today appears as the technical solution simplest, more advanced and more economic. However the energy density of hydrogen being weaker than that of the traditional fuels, of the quantities more important must be stored at equivalent rate. Hyperbar storage (higher pressure has 350 bar) of hydrogen makes it possible to reduce the volume of the tanks and strengthens the argument for their weights and cost

Hydrogen in Ti and Zr alloys: industrial perspective, failure modes and mechanistic understanding

Science.gov (United States)

Chapman, T. P.; Dye, D.; Rugg, D.

2017-06-01

Titanium is widely used in demanding applications, such as in aerospace. Its strength-to-weight ratio and corrosion resistance make it well suited to highly stressed rotating components. Zirconium has a no less critical application where its low neutron capture cross section and good corrosion resistance in hot water and steam make it well suited to reactor core use, including fuel cladding and structures. The similar metallurgical behaviour of these alloy systems makes it alluring to compare and contrast their behaviour. This is rarely undertaken, mostly because the industrial and academic communities studying these alloys have little overlap. The similarities with respect to hydrogen are remarkable, albeit potentially unsurprising, and so this paper aims to provide an overview of the role hydrogen has to play through the material life cycle. This includes the relationship between alloy design and manufacturing process windows, the role of hydrogen in degradation and failure mechanisms and some of the underpinning metallurgy. The potential role of some advanced experimental and modelling techniques will also be explored to give a tentative view of potential for advances in this field in the next decade or so. This article is part of the themed issue 'The challenges of hydrogen and metals'.

Which climate for tomorrow - 15 questions and answers in order not end under water

International Nuclear Information System (INIS)

Jouzel, Jean; Nouaillas, Olivier; Bernet, Lison

2015-01-01

The authors address the climate issue by answering a set of 15 questions. Why are climate and meteorology not really the same? Has climate already changed in the past? What is the anthropocene? Is mankind responsible of global warming? What is the role of the IPCC? What are tomorrow's economic impacts? What will be the weather in France during the X XI century? Can we attribute natural disasters to climate change? How is the World presently struggling against climate change? How to do without fossil energies? Is geo-engineering a solution? Shall we have to change our way of life? Will economy recover? Are we going towards a sixth extinction? Will there be always more climate refugees? Finally, the authors discuss the perspectives drawn after the COP21, and propose 10 initiatives to struggle against climate change

Cyanobacterial Hydrogenases and Hydrogen Metabolism Revisited: Recent Progress and Future Prospects

Directory of Open Access Journals (Sweden)

Namita Khanna

2015-05-01

Full Text Available Cyanobacteria have garnered interest as potential cell factories for hydrogen production. In conjunction with photosynthesis, these organisms can utilize inexpensive inorganic substrates and solar energy for simultaneous biosynthesis and hydrogen evolution. However, the hydrogen yield associated with these organisms remains far too low to compete with the existing chemical processes. Our limited understanding of the cellular hydrogen production pathway is a primary setback in the potential scale-up of this process. In this regard, the present review discusses the recent insight around ferredoxin/flavodoxin as the likely electron donor to the bidirectional Hox hydrogenase instead of the generally accepted NAD(PH. This may have far reaching implications in powering solar driven hydrogen production. However, it is evident that a successful hydrogen-producing candidate would likely integrate enzymatic traits from different species. Engineering the [NiFe] hydrogenases for optimal catalytic efficiency or expression of a high turnover [FeFe] hydrogenase in these photo-autotrophs may facilitate the development of strains to reach target levels of biohydrogen production in cyanobacteria. The fundamental advancements achieved in these fields are also summarized in this review.

Safety, codes and standards for hydrogen installations. Metrics development and benchmarking

Energy Technology Data Exchange (ETDEWEB)

Harris, Aaron P. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Dedrick, Daniel E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); LaFleur, Angela Christine [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); San Marchi, Christopher W. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2014-04-01

Automakers and fuel providers have made public commitments to commercialize light duty fuel cell electric vehicles and fueling infrastructure in select US regions beginning in 2014. The development, implementation, and advancement of meaningful codes and standards is critical to enable the effective deployment of clean and efficient fuel cell and hydrogen solutions in the energy technology marketplace. Metrics pertaining to the development and implementation of safety knowledge, codes, and standards are important to communicate progress and inform future R&D investments. This document describes the development and benchmarking of metrics specific to the development of hydrogen specific codes relevant for hydrogen refueling stations. These metrics will be most useful as the hydrogen fuel market transitions from pre-commercial to early-commercial phases. The target regions in California will serve as benchmarking case studies to quantify the success of past investments in research and development supporting safety codes and standards R&D.

Hydrogen from nuclear plus wind using real-time electricity prices. Abstract 154

International Nuclear Information System (INIS)

Miller, A.I.; Duffey, R.B.; Fairlie, M.

2004-01-01

'Full text:' During the early years of hydrogen's use as a vehicle fuel, penetration of the market will be small. This favours distributed production by electrolysis, which avoids the scale-dependent costs of distribution from centralized plants. For electrolysis actually to be the preferred option, capital equipment for electrolysis must be reasonably cheap but the dominant cost component is the electricity price. By about 2006, advanced designs of nuclear reactors should be available to produce electricity at around 30 US$/MW.h. The best approach to producing low-cost electrolytic hydrogen is shown to be use of such reactors to supply electricity to the grid at times of peak price and demand and to make hydrogen at other times. This model has been analysed using the actual prices of electricity paid by the Alberta Power Pool in 2002 and 2003 and by the Ontario Grid for 2003. The analysis shows clearly that this route electrolytic hydrogen can comfortably meet the US Department of Energy's hydrogen production-cost target of 2000$/t. Because of its low availability wind-produced electricity cannot meet this cost target. However, if wind availability can reach 35% availability, an intermittent supplementary current of wind-generated electricity may economically be fed to an electrolytic plant primarily supplied by nuclear power. Additional current raises the voltage for electrolysis but there would be only small additional capital costs. The two non-CO 2 -emitting sources, nuclear and wind (or other intermittent renewables with costs comparable to advanced nuclear) could become complementary, providing an affordable way of storing wind-generated electricity. (author)

Hydrogen molecules and hydrogen-related defects in crystalline silicon

Science.gov (United States)

Fukata, N.; Sasaki, S.; Murakami, K.; Ishioka, K.; Nakamura, K. G.; Kitajima, M.; Fujimura, S.; Kikuchi, J.; Haneda, H.

1997-09-01

We have found that hydrogen exists in molecular form in crystalline silicon treated with hydrogen atoms in the downstream of a hydrogen plasma. The vibrational Raman line of hydrogen molecules is observed at 4158 cm-1 for silicon samples hydrogenated between 180 and 500 °C. The assignment of the Raman line is confirmed by its isotope shift to 2990 cm-1 for silicon treated with deuterium atoms. The Raman intensity has a maximum for hydrogenation at 400 °C. The vibrational Raman line of the hydrogen molecules is broad and asymmetric. It consists of at least two components, possibly arising from hydrogen molecules in different occupation sites in crystalline silicon. The rotational Raman line of hydrogen molecules is observed at 590 cm-1. The Raman band of Si-H stretching is observed for hydrogenation temperatures between 100 and 500 °C and the intensity has a maximum for hydrogenation at 250 °C.

Hydrogen concentration control utilizing a hydrogen permeable membrane

International Nuclear Information System (INIS)

Keating, S.J. Jr.

1976-01-01

The concentration of hydrogen in a fluid mixture is controlled to a desired concentration by flowing the fluid through one chamber of a diffusion cell separated into two chambers by a hydrogen permeable membrane. A gradient of hydrogen partial pressure is maintained across the membrane to cause diffusion of hydrogen through the membrane to maintain the concentration of hydrogen in the fluid mixture at the predetermined level. The invention has particular utility for the purpose of injecting into and/or separating hydrogen from the reactor coolant of a nuclear reactor system

Alternative Energy Center, Final Scientific/Technical Report

Energy Technology Data Exchange (ETDEWEB)

Dillman, Howard D.; Marshall, JaNice C.

2007-09-07

The Lansing Community College Alternative Energy Center was created with several purposes in mind. The first purpose was the development of educational curricula designed to meet the growing needs of advanced energy companies that would allow students to articulate to other educational institutions or enter this growing workforce. A second purpose was the professional development of faculty and teachers to prepare them to train tomorrow's workforce and scholars. Still another purpose was to design, construct, and equip an alternative energy laboratory that could be used for education, demonstration, and public outreach. Last, the Center was to engage in community outreach and education to enhance industry partnerships, inform decision makers, and increase awareness and general knowledge of hydrogen and other alternative energy technologies and their beneficial impacts on society. This project has enabled us to accomplish all of our goals, including greater faculty understanding of advanced energy concepts, who are now able to convey this knowledge to students through a comprehensive alternative energy curriculum, in a facility well-equipped with advanced technologies, which is also being used to better educate the public on the advantages to society of exploring alternative energy technologies.

Compressed hydrogen fuelled vehicle at ENEA: Status and development

International Nuclear Information System (INIS)

Pede, G.; Ciancia, A.

1993-01-01

The world's 500 million road vehicles using internal combustion engines account for roughly half of global oil consumption and, in Italy, for about 50% of all nitrogen oxide and 90% of carbon monoxide emissions. In efforts to conserve petroleum reserves and reduce air pollution, research programs are being conducted to develop hydrogen fueled automotive engines. Hydrogen combustion products are carbon dioxide free, and when burned with a large excess of air, this fuel produces water vapour and only small amounts of nitrogen oxides. Hydrogen fueled vehicles can be made to operate in a dual fuel mode so as to allow the use of petrol or diesel fuel in travel over long distances. Currently, because technical and economic difficulties relevant to hydrogen fuel storage limit driving range and payload (there are bulk and weight problems in compressed gas and metal hydride storage systems, and cost problems in cryogenic storage), only limited research programs are being performed, mainly in Germany (by Mercedes Benz) and Japan. Some recent advances, however, relevant to research in gas storage and gaseous mixtures have been made by ENEA (the Italian Agency for New Technology, Energy and the Environment). This paper outlines the progress being made in ENEA's research efforts which include the development of an electronically controlled hydrogen fuel injection system prototype

Hydrogen loss and its improved retention in hydrogen plasma treated a-SiNx:H films: ERDA study with 100 MeV Ag7+ ions

Science.gov (United States)

Bommali, R. K.; Ghosh, S.; Khan, S. A.; Srivastava, P.

2018-05-01

Hydrogen loss from a-SiNx:H films under irradiation with 100 MeV Ag7+ ions using elastic recoil detection analysis (ERDA) experiment is reported. The results are explained under the basic assumptions of the molecular recombination model. The ERDA hydrogen concentration profiles are composed of two distinct hydrogen desorption processes, limited by rapid molecular diffusion in the initial stages of irradiation, and as the fluence progresses a slow process limited by diffusion of atomic hydrogen takes over. Which of the aforesaid processes dominates, is determined by the continuously evolving Hydrogen concentration within the films. The first process dominates when the H content is high, and as the H concentration falls below a certain threshold (Hcritical) the irradiation generated H radicals have to diffuse through larger distances before recombining to form H2, thereby significantly bringing down the hydrogen evolution rate. The ERDA measurements were also carried out for films treated with low temperature (300 °C) hydrogen plasma annealing (HPA). The HPA treated films show a clear increase in Hcritical value, thus indicating an improved diffusion of atomic hydrogen, resulting from healing of weak bonds and passivation of dangling bonds. Further, upon HPA films show a significantly higher H concentration relative to the as-deposited films, at advanced fluences. These results indicate the potential of HPA towards improved H retention in a-SiNx:H films. The study distinguishes clearly the presence of two diffusion processes in a-SiNx:H whose diffusion rates differ by an order of magnitude, with atomic hydrogen not being able to diffuse further beyond ∼ 1 nm from the point of its creation.

Mechanisms of hydrogen induced delayed cracking in hydride forming materials

International Nuclear Information System (INIS)

Dutton, R.; Nuttall, K.; Puls, M.P.; Simpson, L.A.

1977-01-01

Mechanisms which have been formulated to describe delayed hydrogen cracking in hydride-forming metals are reviewed and discussed. Particular emphasis is placed on the commercial alloy Zr--2.5% Nb (Cb) which is extensively used in nuclear reactor core components. A quantitative model for hydrogen cracking in this material is presented and compared with available experimental data. The kinetics of crack propagation are controlled by the growth of hydrides at the stressed crack tip by the diffusive ingress of hydrogen into this region. The driving force for the diffusion flux is provided by the local stress gradient which interacts with both hydrogen atoms in solution and hydrogen atoms being dissolved and reprecipitated at the crack tip. The model is developed using concepts of elastoplastic fracture mechanics. Stage I crack growth is controlled by hydrides growing in the elastic stress gradient, while Stage II is controlled by hydride growth in the plastic zone at the crack tip. Recent experimental observations are presented which indicate that the process occurs in an intermittent fashion; hydride clusters accumulate at the crack tip followed by unstable crack advance and subsequent crack arrest in repeated cycles

Mechanisms of hydrogen induced delayed cracking in hydride forming materials

International Nuclear Information System (INIS)

Dutton, R.; Nuttall, K.; Puls, M.P.; Simpson, L.A.

1977-01-01

Mechanisms which have been formulated to describe delayed hydrogen cracking in hydride-forming metals are reviewed and discussed. Particular emphasis is placed on the commercial alloy Zr-2.5 pct Nb which is extensively used in nuclear reactor core components. A quantitative model for hydrogen cracking in this material is presented and compared with available experimental data. The kinetics of crack propagation are controlled by the growth of hydrides at the stressed crack tip by the diffusive ingress of hydrogen into this region. The driving force for the diffusion flux is provided by the local stress gradient which interacts with both hydrogen atoms in solution and hydrogen atoms being dissolved and reprecipitated at the crack tip. The model is developed using concepts of elastoplastic fracture mechanics. Stage I crack growth is controlled by hydrides growing in the elastic stress gradient, while Stage II is controlled by hydride growth in the plastic zone at the crack tip. Recent experimental observations are presented which indicate that the process occurs in an intermittent fashion; hydride clusters accumulate at the crack tip followed by unstable crack advance and subsequent crack arrest in repeated cycles. 55 refs., 6 figs

Publishing and the advancement of science from selfish genes to Galileo's finger

CERN Document Server

Rodgers, Michael

2014-01-01

Popular science books, selling in their thousands - even millions - help us appreciate breakthroughs in understanding the natural world, while highlighting the cultural importance of scientific knowledge. Textbooks bring these same advances to students; the scientists of tomorrow. But how do these books come about? And why are some of them so spectacularly successful? This is the first ever insider's account of science publishing, written by an editor intimately involved in the publication of some of the most famous bestsellers in the field. Michael Rodgers reveals the stories behind these extraordinary books, providing a behind-the-scenes view of the world of books, authors and ideas. These vivid and engaging narratives illuminate not only the challenges of writing about science, but also how publishing itself works and the creative collaboration between authors and editors that lies at its heart. The book (like many of those it describes) is intended for a wide readership. It will interest people in publish...

Coupling the modular helium reactor to hydrogen production processes

International Nuclear Information System (INIS)

Richards, M.B.; Shenoy, A.S.; Schultz, K.R.

2004-01-01

Steam reforming of natural gas (methane) currently produces the bulk of hydrogen gas used in the world today. Because this process depletes natural gas resources and generates the greenhouse gas carbon dioxide as a by-product, there is a growing interest in using process heat and/or electricity generated by nuclear reactors to generate hydrogen by splitting water. Process heat from a high temperature nuclear reactor can be used directly to drive a set of chemical reactions, with the net result of splitting water into hydrogen and oxygen. For example, process heat at temperatures in the range 850 deg C to 950 deg C can drive the sulphur-iodine (S-I) thermochemical process to produce hydrogen with high efficiency. The S-I process produces highly pure hydrogen and oxygen, with formation, decomposition, regeneration, and recycle of the intermediate chemical reagents. Electricity can also 1)e used directly to split water, using conventional, low-temperature electrolysis (LTE). Hydrogen can also be produced with hybrid processes that use both process heat and electricity to generate hydrogen. An example of a hybrid process is high-temperature electrolysis (HTE), in which process heat is used to generate steam, which is then supplied to an electrolyzer to generate hydrogen. This process is of interest because the efficiency of electrolysis increases with temperature. Because of its high temperature capability, advanced stage of development relative to other high-temperature reactor concepts, and passive-safety features, the modular helium reactor (MHR) is well suited for producing hydrogen using nuclear energy. In this paper we investigate the coupling of the MHR to the S-I process, LTE, and HTE. These concepts are referred to as the H2-MHR. (author)

Well-To-Wheel Analysis of Solar Produced Hydrogen for Future Transportation Systems

International Nuclear Information System (INIS)

Remo Felder; Anton Meier

2006-01-01

Hydrogen production, transport, and usage in future passenger car transportation systems is compared for selected solar and conventional hydrogen production technologies using a comprehensive life cycle assessment (LCA) approach. Solar scenarios show distinctly lower greenhouse gas (GHG) emissions than fossil-based scenarios. For example, using solar produced hydrogen in fuel cell cars reduces life cycle GHG emissions by 75% compared to advanced gasoline vehicles and by more than 90% if car and road infrastructure are not considered. Utilization of solar produced hydrogen has the potential of reducing fossil energy requirements by a factor of up to 10 compared to conventional technologies. Environmental impacts are associated with the construction of the steel-intensive infrastructure for concentrating solar power plants due to mineral and fossil resource consumption as well as discharge of pollutants related to today's non-sustainable steel production technology. (authors)

Well-To-Wheel Analysis of Solar Produced Hydrogen for Future Transportation Systems

Energy Technology Data Exchange (ETDEWEB)

Remo Felder; Anton Meier [Solar Technology Laboratory, Paul Scherrer Institut, CH-5232 Villigen PSI, (Switzerland)

2006-07-01

Hydrogen production, transport, and usage in future passenger car transportation systems is compared for selected solar and conventional hydrogen production technologies using a comprehensive life cycle assessment (LCA) approach. Solar scenarios show distinctly lower greenhouse gas (GHG) emissions than fossil-based scenarios. For example, using solar produced hydrogen in fuel cell cars reduces life cycle GHG emissions by 75% compared to advanced gasoline vehicles and by more than 90% if car and road infrastructure are not considered. Utilization of solar produced hydrogen has the potential of reducing fossil energy requirements by a factor of up to 10 compared to conventional technologies. Environmental impacts are associated with the construction of the steel-intensive infrastructure for concentrating solar power plants due to mineral and fossil resource consumption as well as discharge of pollutants related to today's non-sustainable steel production technology. (authors)

Effect of LEO cycling on 125 Ah advanced design IPV nickel-hydrogen flight cells - An update

Science.gov (United States)

Smithrick, John J.; Hall, Stephen W.

1991-01-01

An update of validation test results confirming the breakthrough in LEO cycle life of nickel-hydrogen cells containing 26 percent potassium hydroxide (KOH) electrolyte is presented. A breakthrough in the LEO cycle life of individual pressure vessel nickel-hydrogen cells is reported. The cycle life of boiler plate cells containing 26 percent KOH electrolyte was about 40,000 LEO cycles compared to 3500 cycles for cells containing 31 percent KOH.

Liquid Hydrogen Sensor Considerations for Space Exploration

Science.gov (United States)

Moran, Matthew E.

2006-01-01

The on-orbit management of liquid hydrogen planned for the return to the moon will introduce new considerations not encountered in previous missions. This paper identifies critical liquid hydrogen sensing needs from the perspective of reliable on-orbit cryogenic fluid management, and contrasts the fundamental differences in fluid and thermodynamic behavior for ground-based versus on-orbit conditions. Opportunities for advanced sensor development and implementation are explored in the context of critical Exploration Architecture operations such as on-orbit storage, docking, and trans-lunar injection burn. Key sensing needs relative to these operations are also examined, including: liquid/vapor detection, thermodynamic condition monitoring, mass gauging, and leak detection. Finally, operational aspects of an integrated system health management approach are discussed to highlight the potential impact on mission success.

Hydrogenation study of suction-cast Ti{sub 40}Zr{sub 40}Ni{sub 20} quasicrystal

Energy Technology Data Exchange (ETDEWEB)

Huang, Huogen; Li, Rong; Yin, Chen; Zheng, Shaotao; Zhang, Pengcheng [National Key Laboratory for Surface Physics and Chemistry, P.O. Box 718-35, Mian Yang 621907, Sichuan (China)

2008-09-15

Suction casting was predicted to be an usable method for improving the hydriding kinetics of Ti/Zr-based icosahedral quasicrystals (IQCs) in our previous work. To further determine it, a suction-cast Ti{sub 40}Zr{sub 40}Ni{sub 20} IQC alloy was used for hydrogenation studies by Pressure Composition Isotherm (PCI) and Temperature Programmed Desorption (TPD) techniques. The results showed that, this alloy absorbed hydrogen rapidly with obvious hydrogen pressure plateau and some reversibility, however, displayed very limited hydrogen capacity (about 0.7 wt.%) and low equilibrium pressure. After several hydrogenation/dehydrogenation cycles, the IQC structure transformed into two hydride phases, ZrH{sub 2-x} and one unknown, both of which decomposed at above 600 C, suggesting high thermo-stability for them. On the whole, indeed the suction-casting method can increase the hydrogen absorption rate of Ti/Zr-based IQCs, however, the hydrogenation properties of the Ti{sub 40}Zr{sub 40}Ni{sub 20} IQC alloy still need a mighty advancement. (author)

Atomic hydrogen cleaning of EUV multilayer optics

Science.gov (United States)

Graham, Samuel, Jr.; Steinhaus, Charles A.; Clift, W. Miles; Klebanoff, Leonard E.; Bajt, Sasa

2003-06-01

Recent studies have been conducted to investigate the use of atomic hydrogen as an in-situ contamination removal method for EUV optics. In these experiments, a commercial source was used to produce atomic hydrogen by thermal dissociation of molecular hydrogen using a hot filament. Samples for these experiments consisted of silicon wafers coated with sputtered carbon, Mo/Si optics with EUV-induced carbon, and bare Si-capped and Ru-B4C-capped Mo/Si optics. Samples were exposed to an atomic hydrogen source at a distance of 200 - 500 mm downstream and angles between 0-90° with respect to the source. Carbon removal rates and optic oxidation rates were measured using Auger electron spectroscopy depth profiling. In addition, at-wavelength peak reflectance (13.4 nm) was measured using the EUV reflectometer at the Advanced Light Source. Data from these experiments show carbon removal rates up to 20 Å/hr for sputtered carbon and 40 Å/hr for EUV deposited carbon at a distance of 200 mm downstream. The cleaning rate was also observed to be a strong function of distance and angular position. Experiments have also shown that the carbon etch rate can be increased by a factor of 4 by channeling atomic hydrogen through quartz tubes in order to direct the atomic hydrogen to the optic surface. Atomic hydrogen exposures of bare optic samples show a small risk in reflectivity degradation after extended periods. Extended exposures (up to 20 hours) of bare Si-capped Mo/Si optics show a 1.2% loss (absolute) in reflectivity while the Ru-B4C-capped Mo/Si optics show a loss on the order of 0.5%. In order to investigate the source of this reflectivity degradation, optic samples were exposed to atomic deuterium and analyzed using low energy ion scattering direct recoil spectroscopy to determine any reactions of the hydrogen with the multilayer stack. Overall, the results show that the risk of over-etching with atomic hydrogen is much less than previous studies using RF discharge cleaning

Development of a National Center for Hydrogen Technology. A Summary Report of Activities Completed at the National Center for Hydrogen Technology - Year 6

Energy Technology Data Exchange (ETDEWEB)

Holmes, Michael [Univ. of North Dakota, Grand Forks, ND (United States)

2012-08-01

The Energy & Environmental Research Center (EERC) located in Grand Forks, North Dakota, has operated the National Center for Hydrogen Technology (NCHT) since 2005 under a Cooperative Agreement with the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL). The EERC has a long history of hydrogen generation and utilization from fossil fuels, and under the NCHT Program, the EERC has accelerated its research on hydrogen generation and utilization topics. Since the NCHT's inception, the EERC has received more than $65 million in funding for hydrogen-related projects ($24 million for projects in the NCHT, which includes federal and corporate partner development funds) involving more than 85 partners (27 with the NCHT). The NCHT Program's nine activities span a broad range of technologies that align well with the Advanced Fuels Program goals and, specifically, those described in the Hydrogen from Coal Program research, development, and demonstration (RD&D) plan that refers to realistic testing of technologies at adequate scale, process intensification, and contaminant control. A number of projects have been completed that range from technical feasibility of several hydrogen generation and utilization technologies to public and technical education and outreach tools. Projects under the NCHT have produced hydrogen from natural gas, coal, liquid hydrocarbons, and biomass. The hydrogen or syngas generated by these processes has also been purified in many of these instances or burned directly for power generation. Also, several activities are still undergoing research, development, demonstration, and commercialization at the NCHT. This report provides a summary overview of the projects completed in Year 6 of the NCHT. Individual activity reports are referenced as a source of detailed information on each activity.

LARGE-SCALE HYDROGEN PRODUCTION FROM NUCLEAR ENERGY USING HIGH TEMPERATURE ELECTROLYSIS

International Nuclear Information System (INIS)

O'Brien, James E.

2010-01-01

Hydrogen can be produced from water splitting with relatively high efficiency using high-temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high-temperature process heat. When coupled to an advanced high temperature nuclear reactor, the overall thermal-to-hydrogen efficiency for high-temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. Demand for hydrogen is increasing rapidly for refining of increasingly low-grade petroleum resources, such as the Athabasca oil sands and for ammonia-based fertilizer production. Large quantities of hydrogen are also required for carbon-efficient conversion of biomass to liquid fuels. With supplemental nuclear hydrogen, almost all of the carbon in the biomass can be converted to liquid fuels in a nearly carbon-neutral fashion. Ultimately, hydrogen may be employed as a direct transportation fuel in a 'hydrogen economy.' The large quantity of hydrogen that would be required for this concept should be produced without consuming fossil fuels or emitting greenhouse gases. An overview of the high-temperature electrolysis technology will be presented, including basic theory, modeling, and experimental activities. Modeling activities include both computational fluid dynamics and large-scale systems analysis. We have also demonstrated high-temperature electrolysis in our laboratory at the 15 kW scale, achieving a hydrogen production rate in excess of 5500 L/hr.

Final Report: Metal Perhydrides for Hydrogen Storage

Energy Technology Data Exchange (ETDEWEB)

Hwang, J-Y.; Shi, S.; Hackney, S.; Swenson, D.; Hu, Y.

2011-07-26

Hydrogen is a promising energy source for the future economy due to its environmental friendliness. One of the important obstacles for the utilization of hydrogen as a fuel source for applications such as fuel cells is the storage of hydrogen. In the infrastructure of the expected hydrogen economy, hydrogen storage is one of the key enabling technologies. Although hydrogen possesses the highest gravimetric energy content (142 KJ/g) of all fuels, its volumetric energy density (8 MJ/L) is very low. It is desired to increase the volumetric energy density of hydrogen in a system to satisfy various applications. Research on hydrogen storage has been pursed for many years. Various storage technologies, including liquefaction, compression, metal hydride, chemical hydride, and adsorption, have been examined. Liquefaction and high pressure compression are not desired due to concerns related to complicated devices, high energy cost and safety. Metal hydrides and chemical hydrides have high gravimetric and volumetric energy densities but encounter issues because high temperature is required for the release of hydrogen, due to the strong bonding of hydrogen in the compounds. Reversibility of hydrogen loading and unloading is another concern. Adsorption of hydrogen on high surface area sorbents such as activated carbon and organic metal frameworks does not have the reversibility problem. But on the other hand, the weak force (primarily the van der Waals force) between hydrogen and the sorbent yields a very small amount of adsorption capacity at ambient temperature. Significant storage capacity can only be achieved at low temperatures such as 77K. The use of liquid nitrogen in a hydrogen storage system is not practical. Perhydrides are proposed as novel hydrogen storage materials that may overcome barriers slowing advances to a hydrogen fuel economy. In conventional hydrides, e.g. metal hydrides, the number of hydrogen atoms equals the total valence of the metal ions. One Li

Hydrogen safety

International Nuclear Information System (INIS)

Frazier, W.R.

1991-01-01

The NASA experience with hydrogen began in the 1950s when the National Advisory Committee on Aeronautics (NACA) research on rocket fuels was inherited by the newly formed National Aeronautics and Space Administration (NASA). Initial emphasis on the use of hydrogen as a fuel for high-altitude probes, satellites, and aircraft limited the available data on hydrogen hazards to small quantities of hydrogen. NASA began to use hydrogen as the principal liquid propellant for launch vehicles and quickly determined the need for hydrogen safety documentation to support design and operational requirements. The resulting NASA approach to hydrogen safety requires a joint effort by design and safety engineering to address hydrogen hazards and develop procedures for safe operation of equipment and facilities. NASA also determined the need for rigorous training and certification programs for personnel involved with hydrogen use. NASA's current use of hydrogen is mainly for large heavy-lift vehicle propulsion, which necessitates storage of large quantities for fueling space shots and for testing. Future use will involve new applications such as thermal imaging

Hydrogen isotope effect through Pd in hydrogen transport pipe

International Nuclear Information System (INIS)

Tamaki, Masayoshi

1992-01-01

This investigation concerns hydrogen system with hydrogen transport pipes for transportation, purification, isotope separation and storage of hydrogen and its isotopes. A principle of the hydrogen transport pipe (heat pipe having hydrogen transport function) was proposed. It is comprised of the heat pipe and palladium alloy tubes as inlet, outlet, and the separation membrane of hydrogen. The operation was as follows: (1) gas was introduced into the heat pipe through the membrane in the evaporator; (2) the introduced gas was transported toward the condenser by the vapor flow; (3) the transported gas was swept and compressed to the end of the condenser by the vapor pressure; and (4) the compressed gas was exhausted from the heat pipe through the membrane in the condenser. The characteristics of the hydrogen transport pipe were examined for various working conditions. Basic performance concerning transportation, evacuation and compression was experimentally verified. Isotopic dihydrogen gases (H 2 and D 2 ) were used as feed gas for examining the intrinsic performance of the isotope separation by the hydrogen transport pipe. A simulated experiment for hydrogen isotope separation was carried out using a hydrogen-helium gas mixture. The hydrogen transport pipe has a potential for isotope separation and purification of hydrogen, deuterium and tritium in fusion reactor technology. (author)

Automatic orbital GTAW welding: Highest quality welds for tomorrow's high-performance systems

Science.gov (United States)

Henon, B. K.

1985-01-01

Automatic orbital gas tungsten arc welding (GTAW) or TIG welding is certain to play an increasingly prominent role in tomorrow's technology. The welds are of the highest quality and the repeatability of automatic weldings is vastly superior to that of manual welding. Since less heat is applied to the weld during automatic welding than manual welding, there is less change in the metallurgical properties of the parent material. The possibility of accurate control and the cleanliness of the automatic GTAW welding process make it highly suitable to the welding of the more exotic and expensive materials which are now widely used in the aerospace and hydrospace industries. Titanium, stainless steel, Inconel, and Incoloy, as well as, aluminum can all be welded to the highest quality specifications automatically. Automatic orbital GTAW equipment is available for the fusion butt welding of tube-to-tube, as well as, tube to autobuttweld fittings. The same equipment can also be used for the fusion butt welding of up to 6 inch pipe with a wall thickness of up to 0.154 inches.

Technoeconomic analysis of renewable hydrogen production, storage, and detection systems

Energy Technology Data Exchange (ETDEWEB)

Mann, M.K.; Spath, P.L.; Kadam, K. [National Renewable Energy Lab., Golden, CO (United States)

1996-10-01

Technical and economic feasibility studies of different degrees of completeness and detail have been performed on several projects being funded by the Department of Energy`s Hydrogen Program. Work this year focused on projects at the National Renewable Energy Laboratory, although analyses of projects at other institutions are underway or planned. Highly detailed analyses were completed on a fiber optic hydrogen leak detector and a process to produce hydrogen from biomass via pyrolysis followed by steam reforming of the pyrolysis oil. Less detailed economic assessments of solar and biologically-based hydrogen production processes have been performed and focused on the steps that need to be taken to improve the competitive position of these technologies. Sensitivity analyses were conducted on all analyses to reveal the degree to which the cost results are affected by market changes and technological advances. For hydrogen storage by carbon nanotubes, a survey of the competing storage technologies was made in order to set a baseline for cost goals. A determination of the likelihood of commercialization was made for nearly all systems examined. Hydrogen from biomass via pyrolysis and steam reforming was found to have significant economic potential if a coproduct option could be co-commercialized. Photoelectrochemical hydrogen production may have economic potential, but only if low-cost cells can be modified to split water and to avoid surface oxidation. The use of bacteria to convert the carbon monoxide in biomass syngas to hydrogen was found to be slightly more expensive than the high end of currently commercial hydrogen, although there are significant opportunities to reduce costs. Finally, the cost of installing a fiber-optic chemochromic hydrogen detection system in passenger vehicles was found to be very low and competitive with alternative sensor systems.

Research opportunities in photochemical sciences for the DOE Hydrogen Program

Energy Technology Data Exchange (ETDEWEB)

Padro, C.E.G. [National Renewable Energy Laboratory, Golden, CO (United States)

1996-09-01

For several decades, interest in hydrogen has ebbed and flowed. With the OPEC oil embargo of the 1970`s and the promise of inexpensive nuclear power, hydrogen research focused on fuel applications. The economics and the realities of nuclear power shifted the emphasis to hydrogen as an energy carrier. Environmental benefits took center stage as scientists and politicians agreed on the potential threat of carbon dioxide emissions to global climate change. The U.S. Department of Energy (DOE) Office of Utility Technologies manages the National Hydrogen Program. In this role, the DOE provides national leadership and acts as a catalyst through partnerships with industry. These partnerships are needed to assist in the transition of sustainable hydrogen systems from a government-supported research and development phase to commercial successes in the marketplace. The outcome of the Program is expected to be the orderly phase-out of fossil fuels as a result of market-driven technology advances, with a least-cost, environmentally benign energy delivery system. The program seeks to maintain its balance of high-risk, long-term research in renewable based technologies that address the environmental benefits, with nearer-term, fossil based technologies that address infrastructure and market issues. National laboratories, universities, and industry are encouraged to participate, cooperate, and collaborate in the program. The U.S. Hydrogen Program is poised to overcome the technical and economic challenges that currently limit the impact of hydrogen on our energy picture, through cooperative research, development, and demonstrations.

Development Potentials for LH2 Storage System with Advanced Boil-off Management

International Nuclear Information System (INIS)

Takashi Maemura; Takanobu Kamiya; Shuichi Kawasaki; Ryo Nakamura; Kenji Nakamichi

2006-01-01

This paper describes our R and D until 2004 for liquid hydrogen components and system, and current development status summary from 2005 for the LH2 storing, transporting, and refuelling system with the advanced boil-off management using 'slush hydrogen', sponsored by NEDO (domestic projects). The objectives of our study from 2005 are to prove the reduction of the evaporation loss (BOG loss) by utilizing the slush hydrogen, which is the mixture of solids and triple point liquid hydrogen. Use of slush hydrogen rather than atmospheric pressure liquid hydrogen provides the advantage in density and cooling capacity. Assuming a vehicle storage tank size such as 100 to 200 litter ones, the BOG rate can be reduced to 30 percent less than the atmospheric pressure liquid hydrogen is. Present execution plan is to develop, built, and test experimental equipments composed of a slush hydrogen generator, a transfer line, and a storage tank during three years from 2005 to 2007. (authors)

Which energies for tomorrow? The perspectives of development of nuclear energy

International Nuclear Information System (INIS)

Sicard, Bruno; Regaldo, Jacques; Salvatores, Stephano; Bigot, Bernard; Billot, Philippe; Kert, Christian; Blisson, Yves; Beslu, Pierre

2016-03-01

This document first proposes a brief synthesis of opening speeches and of contributions, and then Power Point presentations of these contributions. These interventions proposed an overview of development perspectives and safety challenges for nuclear energy in the world (current evolution of the world nuclear fleet, international cooperation, role and mission of the World Association of Nuclear Operators or WANO, new tools, a first assessment 5 years after the Fukushima accident), an overview of perspectives on the medium and long terms for EDF nuclear fleet in view of a fourth decennial inspection of 900 MWe reactors (continuous improvement of safety in the operated fleet, orientations proposed for the fourth decennial inspections in terms of conformity control and of peculiarities for this safety re-assessment with respect to different accidents and threats), an overview according the CEA of what is at stake for research as far as tomorrow's energies are concerned (CEA global strategy, CEA missions in the field of civil nuclear, R and D on reactors of second and third generation, industrial challenges of R and D, R and D as a support to reactor lifetime extension, presentation of various research platforms and projects)

Hydrogen Analysis with the Sandia ParaChoice Model.

Energy Technology Data Exchange (ETDEWEB)

Levinson, Rebecca Sobel [Sandia National Lab. (SNL-CA), Livermore, CA (United States); West, Todd H. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2017-07-01

In the coming decades, light-duty vehicle options and their supporting infrastructure must undergo significant transformations to achieve aggressive national targets for reducing petroleum consumption and lowering greenhouse gas emissions. FCEVs, battery and hybrid electric vehicles, and biofuels are among the promising advanced technology options. This project examines the market penetration of FCEVs in a range of market segments, and in different energy, technology, and policy futures. Analyses are conducted in the context of varying hydrogen production and distribution pathways, as well as public infrastructure availability, fuel (gasoline, ethanol, hydrogen) and electricity costs, vehicle costs and fuel economies to better understand under what conditions, and for which market segments, FCEVs can best compete with battery electric and other alternative fuel vehicles.

Potential Applications of Friction Stir Welding to the Hydrogen Economy. Hydrogen Regional Infrastructure Program In Pennsylvania, Materials Task

Energy Technology Data Exchange (ETDEWEB)

Brendlinger, Jennifer [Concurrent Technologies Corporation, Johnstown, PA (United States)

2009-07-17

Friction Stir Welding (FSW) is a solid-state welding technique developed by The Welding Institute (TWI) of Cambridge, UK in the early 1990’s. The process uses a non-consumable rotating tool to develop frictional heat and plastically deform workpieces to be joined, resulting in a solid-state weld on the trailing side of the advancing tool. Since the materials to be joined are not melted, FSW results in a finer grain structure and therefore enhanced properties, relative to fusion welds. And unlike fusion welding, a relatively small number of key process parameters exist for FSW: tool rotational speed, linear weld velocity and force perpendicular to the joining surface. FSW is more energy efficient than fusion welding and can be accomplished in one or two passes, versus many more passes required of fusion welding thicker workpieces. Reduced post-weld workpiece distortion is another factor that helps to reduce the cost of FSW relative to fusion welding. Two primary areas have been identified for potential impact on the hydrogen economy: FSW of metallic pipes for hydrogen transmission and FSW of aluminum pressure vessels for hydrogen storage. Both areas have been under active development and are explored in this paper.

Future hydrogen markets for large-scale hydrogen production systems

International Nuclear Information System (INIS)

Forsberg, Charles W.

2007-01-01

The cost of delivered hydrogen includes production, storage, and distribution. For equal production costs, large users (>10 6 m 3 /day) will favor high-volume centralized hydrogen production technologies to avoid collection costs for hydrogen from widely distributed sources. Potential hydrogen markets were examined to identify and characterize those markets that will favor large-scale hydrogen production technologies. The two high-volume centralized hydrogen production technologies are nuclear energy and fossil energy with carbon dioxide sequestration. The potential markets for these technologies are: (1) production of liquid fuels (gasoline, diesel and jet) including liquid fuels with no net greenhouse gas emissions and (2) peak electricity production. The development of high-volume centralized hydrogen production technologies requires an understanding of the markets to (1) define hydrogen production requirements (purity, pressure, volumes, need for co-product oxygen, etc.); (2) define and develop technologies to use the hydrogen, and (3) create the industrial partnerships to commercialize such technologies. (author)

Hydrogen embrittlement due to hydrogen-inclusion interactions

International Nuclear Information System (INIS)

Yu, H.Y.; Li, J.C.M.

1976-01-01

Plastic flow around inclusions creates elastic misfit which attracts hydrogen towards the regions of positive dilatation. Upon decohesion of the inclusion-matrix interface, the excess hydrogen escapes into the void and can produce sufficient pressure to cause void growth by plastic deformation. This mechanism of hydrogen embrittlement can be used to understand the increase of ductility with temperature, the decrease of ductility with hydrogen content, and the increase of ductility with the ultimate strength of the matrix. An examination of the effect of the shape of spheroid inclusion reveals that rods are more susceptible to hydrogen embrittlement than disks. The size of the inclusion is unimportant while the volume fraction of inclusions plays the usual role

Mechanochemical synthesis of nanostructured chemical hydrides in hydrogen alloying mills

International Nuclear Information System (INIS)

Wronski, Z.; Varin, R.A.; Chiu, C.; Czujko, T.; Calka, A.

2007-01-01

Mechanical alloying of magnesium metal powders with hydrogen in specialized hydrogen ball mills can be used as a direct route for mechanochemical synthesis of emerging chemical hydrides and hydride mixtures for advanced solid-state hydrogen storage. In the 2Mg-Fe system, we have successfully synthesized the ternary complex hydride Mg 2 FeH 6 in a mixture with nanometric Fe particles. The mixture of complex magnesium-iron hydride and nano-iron released 3-4 wt.%H 2 in a thermally programmed desorption experiment at the range 285-295 o C. Milling of the Mg-2Al powder mixture revealed a strong competition between formation of the Al(Mg) solid solution and the β-MgH 2 hydride. The former decomposes upon longer milling as the Mg atoms react with hydrogen to form the hydride phase, and drive the Al out of the solid solution. The mixture of magnesium dihydride and nano-aluminum released 2.1 wt.%H 2 in the temperature range 329-340 o C in the differential scanning calorimetry experiment. The formation of MgH 2 was suppressed in the Mg-B system; instead, a hydrogenated amorphous phase (Mg,B)H x , was formed in a mixture with nanometric MgB 2 . Annealing of the hydrogen-stabilized amorphous mixture produced crystalline MgB 2

Large scale production of densified hydrogen to the triple point and below

Science.gov (United States)

Swanger, A. M.; Notardonato, W. U.; E Fesmire, J.; Jumper, K. M.; Johnson, W. L.; Tomsik, T. M.

2017-12-01

Recent demonstration of advanced liquid hydrogen storage techniques using Integrated Refrigeration and Storage technology at NASA Kennedy Space Center led to the production of large quantities of densified liquid and slush hydrogen in a 125,000 L tank. Production of densified hydrogen was performed at three different liquid levels and LH2 temperatures were measured by twenty silicon diode temperature sensors. Overall densification performance of the system is explored, and solid mass fractions are calculated. Experimental data reveal hydrogen temperatures dropped well below the triple point during testing, and were continuing to trend downward prior to system shutdown. Sub-triple point temperatures were seen to evolve in a time dependent manner along the length of the horizontal, cylindrical vessel. The phenomenon, observed at two fill levels, is detailed herein. The implications of using IRAS for energy storage, propellant densification, and future cryofuel systems are discussed.

Hydrogen molecules and hydrogen-related defects in crystalline silicon

OpenAIRE

Fukata, N.; Sasak, S.; Murakami, K.; Ishioka, K.; Nakamura, K. G.; Kitajima, M.; Fujimura, S.; Kikuchi, J.; Haneda, H.

1997-01-01

We have found that hydrogen exists in molecular form in crystalline silicon treated with hydrogen atoms in the downstream of a hydrogen plasma. The vibrational Raman line of hydrogen molecules is observed at 4158cm-1 for silicon samples hydrogenated between 180 and 500 °C. The assignment of the Raman line is confirmed by its isotope shift to 2990cm-1 for silicon treated with deuterium atoms. The Raman intensity has a maximum for hydrogenation at 400 °C. The vibrational Raman line of the hydro...

Why hydrogen; Pourquoi l'hydrogene?

Energy Technology Data Exchange (ETDEWEB)

NONE

2004-02-01

The energy consumption increase and the associated environmental risks, led to develop new energy sources. The authors present the potentialities of the hydrogen in this context of energy supply safety. They detail the today market and the perspectives, the energy sources for the hydrogen production (fossils, nuclear and renewable), the hydrogen transport, storage, distribution and conversion, the application domains, the associated risks. (A.L.B.)

Development of a national center for hydrogen technology. A summary report of activities completed at the national center hydrogen technology from 2005 to 2010

Energy Technology Data Exchange (ETDEWEB)

Holmes, Michael J. [Univ. of North Dakota, Grand Forks, ND (United States)

2011-06-01

The Energy & Environmental Research Center (EERC) located in Grand Forks, North Dakota, has operated the National Center for Hydrogen Technology® (NCHT®) since 2005 under a Cooperative Agreement with the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL). The EERC has a long history of hydrogen generation and utilization from fossil fuels, and under the NCHT Program, the EERC has accelerated its research of hydrogen generation and utilization topics. Since the NCHT's inception, the EERC has received more than $65 million in funding of hydrogen-related projects ($20 million for the NCHT project which includes federal and corporate development partner funds) involving more than 85 partners (27 with the NCHT). The NCHT project's 19 activities span a broad range of technologies that align well with the Advanced Fuels Program goals and, specifically, those described in the Hydrogen from Coal Program research, development, and demonstration (RD&D) plan. A number of projects have been completed which range from technical feasibility of several hydrogen generation and utilization technologies to public and technical education and outreach tools. Projects under the NCHT have produced hydrogen from natural gas, coal, liquid hydrocarbons, and biomass. The hydrogen or syngas generated by these processes has also been purified to transportation-grade quality in many of these instances or burned directly for power generation. Also, several activities are still undergoing research, development, demonstration, and commercialization at the NCHT. This report provides a summary overview of the projects completed in the first 5 years of the NCHT. Individual activity reports are referenced as a source of detailed information on each activity.

Dislocation/hydrogen interaction mechanisms in hydrided nanocrystalline palladium films

International Nuclear Information System (INIS)

Amin-Ahmadi, Behnam; Connétable, Damien; Fivel, Marc; Tanguy, Döme; Delmelle, Renaud; Turner, Stuart; Malet, Loic; Godet, Stephane; Pardoen, Thomas; Proost, Joris; Schryvers, Dominique

2016-01-01

The nanoscale plasticity mechanisms activated during hydriding cycles in sputtered nanocrystalline Pd films have been investigated ex-situ using advanced transmission electron microscopy techniques. The internal stress developing within the films during hydriding has been monitored in-situ. Results showed that in Pd films hydrided to β-phase, local plasticity was mainly controlled by dislocation activity in spite of the small grain size. Changes of the grain size distribution and the crystallographic texture have not been observed. In contrast, significant microstructural changes were not observed in Pd films hydrided to α-phase. Moreover, the effect of hydrogen loading on the nature and density of dislocations has been investigated using aberration-corrected TEM. Surprisingly, a high density of shear type stacking faults has been observed after dehydriding, indicating a significant effect of hydrogen on the nucleation energy barriers of Shockley partial dislocations. Ab-initio calculations of the effect of hydrogen on the intrinsic stable and unstable stacking fault energies of palladium confirm the experimental observations.

Hydrogen Embrittlement

Science.gov (United States)

Woods, Stephen; Lee, Jonathan A.

2016-01-01

Hydrogen embrittlement (HE) is a process resulting in a decrease in the fracture toughness or ductility of a metal due to the presence of atomic hydrogen. In addition to pure hydrogen gas as a direct source for the absorption of atomic hydrogen, the damaging effect can manifest itself from other hydrogen-containing gas species such as hydrogen sulfide (H2S), hydrogen chloride (HCl), and hydrogen bromide (HBr) environments. It has been known that H2S environment may result in a much more severe condition of embrittlement than pure hydrogen gas (H2) for certain types of alloys at similar conditions of stress and gas pressure. The reduction of fracture loads can occur at levels well below the yield strength of the material. Hydrogen embrittlement is usually manifest in terms of singular sharp cracks, in contrast to the extensive branching observed for stress corrosion cracking. The initial crack openings and the local deformation associated with crack propagation may be so small that they are difficult to detect except in special nondestructive examinations. Cracks due to HE can grow rapidly with little macroscopic evidence of mechanical deformation in materials that are normally quite ductile. This Technical Memorandum presents a comprehensive review of experimental data for the effects of gaseous Hydrogen Environment Embrittlement (HEE) for several types of metallic materials. Common material screening methods are used to rate the hydrogen degradation of mechanical properties that occur while the material is under an applied stress and exposed to gaseous hydrogen as compared to air or helium, under slow strain rates (SSR) testing. Due to the simplicity and accelerated nature of these tests, the results expressed in terms of HEE index are not intended to necessarily represent true hydrogen service environment for long-term exposure, but rather to provide a practical approach for material screening, which is a useful concept to qualitatively evaluate the severity of

A review of nickel hydrogen battery technology

Science.gov (United States)

Smithrick, John J.; Odonnell, Patricia M.

1995-01-01

This paper on nickel hydrogen batteries is an overview of the various nickel hydrogen battery design options, technical accomplishments, validation test results and trends. There is more than one nickel hydrogen battery design, each having its advantage for specific applications. The major battery designs are individual pressure vessel (IPV), common pressure vessel (CPV), bipolar and low pressure metal hydride. State-of-the-art (SOA) nickel hydrogen batteries are replacing nickel cadmium batteries in almost all geosynchronous orbit (GEO) applications requiring power above 1 kW. However, for the more severe low earth orbit (LEO) applications (greater than 30,000 cycles), the current cycle life of 4000 to 10,000 cycles at 60 percent DOD should be improved. A NASA Lewis Research Center innovative advanced design IPV nickel hydrogen cell led to a breakthrough in cycle life enabling LEO applications at deep depths of discharge (DOD). A trend for some future satellites is to increase the power level to greater than 6 kW. Another trend is to decrease the power to less than 1 kW for small low cost satellites. Hence, the challenge is to reduce battery mass, volume and cost. A key is to develop a light weight nickel electrode and alternate battery designs. A common pressure vessel (CPV) nickel hydrogen battery is emerging as a viable alternative to the IPV design. It has the advantage of reduced mass, volume and manufacturing costs. A 10 Ah CPV battery has successfully provided power on the relatively short lived Clementine Spacecraft. A bipolar nickel hydrogen battery design has been demonstrated (15,000 LEO cycles, 40 percent DOD). The advantage is also a significant reduction in volume, a modest reduction in mass, and like most bipolar designs, features a high pulse power capability. A low pressure aerospace nickel metal hydride battery cell has been developed and is on the market. It is a prismatic design which has the advantage of a significant reduction in volume and a

A comparative analysis of the cryo-compression and cryo-adsorption hydrogen storage methods

Energy Technology Data Exchange (ETDEWEB)

Petitpas, G [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Benard, P [Universite du Quebec a Trois-Rivieres (Canada); Klebanoff, L E [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Xiao, J [Universite du Quebec a Trois-Rivieres (Canada); Aceves, S M [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2014-07-01

While conventional low-pressure LH₂ dewars have existed for decades, advanced methods of cryogenic hydrogen storage have recently been developed. These advanced methods are cryo-compression and cryo-adsorption hydrogen storage, which operate best in the temperature range 30–100 K. We present a comparative analysis of both approaches for cryogenic hydrogen storage, examining how pressure and/or sorbent materials are used to effectively increase onboard H₂ density and dormancy. We start by reviewing some basic aspects of LH₂ properties and conventional means of storing it. From there we describe the cryo-compression and cryo-adsorption hydrogen storage methods, and then explore the relationship between them, clarifying the materials science and physics of the two approaches in trying to solve the same hydrogen storage task (~5–8 kg H₂, typical of light duty vehicles). Assuming that the balance of plant and the available volume for the storage system in the vehicle are identical for both approaches, the comparison focuses on how the respective storage capacities, vessel weight and dormancy vary as a function of temperature, pressure and type of cryo-adsorption material (especially, powder MOF-5 and MIL-101). By performing a comparative analysis, we clarify the science of each approach individually, identify the regimes where the attributes of each can be maximized, elucidate the properties of these systems during refueling, and probe the possible benefits of a combined “hybrid” system with both cryo-adsorption and cryo-compression phenomena operating at the same time. In addition the relationships found between onboard H₂ capacity, pressure vessel and/or sorbent mass and dormancy as a function of rated pressure, type of sorbent material and fueling conditions are useful as general designing guidelines in future engineering efforts using these two hydrogen storage approaches.

Using energy efficiency and alternative energy to extend fossil resources or what if tomorrow actually comes

International Nuclear Information System (INIS)

Moore, M.C.

2003-01-01

This PowerPoint presentation outlined the role of energy in maintaining and advancing society, and what happens if we run out of energy. The author provided a glimpse into the energy world through the display of a series of graphs depicting world energy consumption, world energy production, world population distribution, growth rates in Asia, coal use per capita, the United States energy consumption by source, percent of air emissions in the United States from fossil fuel use, and others. It was argued that alternative energy and energy efficiency diminish growth in demand and peak load, supports portfolio diversity, lowers cost, and diminishes environmental impacts. The advances in wind power and solar power were reviewed, as well as advances in bioenergy and hydrogen. The author also argued the case for energy efficiency and conservation. A discussion of various pricing schemes was offered. The first option examined was time of use price, defined as 3 time blocks published in advance for entire seasons. The second option was critical peak pricing, involving a high price imposed for a few days per year when system conditions are critical or near critical. The third option discussed was real-time prices, implying an hourly real-time marginal cost of a kilowatt hour. It was suggested that the system should be changed, since subsidizing energy consumption distorts demand. Energy efficiency and renewables extend fossil energy availability, helping in the transition to a more sustainable world. refs., tabs., figs

Fuel Cell and Hydrogen Technology Validation | Hydrogen and Fuel Cells |

Science.gov (United States)

NREL Fuel Cell and Hydrogen Technology Validation Fuel Cell and Hydrogen Technology Validation The NREL technology validation team works on validating hydrogen fuel cell electric vehicles; hydrogen fueling infrastructure; hydrogen system components; and fuel cell use in early market applications such as

Hydrogen program overview

Energy Technology Data Exchange (ETDEWEB)

Gronich, S. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies

1997-12-31

This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

The prospects for hydrogen as an energy carrier: an overview of hydrogen energy and hydrogen energy systems

International Nuclear Information System (INIS)

Rosen, Marc A.; Koohi-Fayegh, Seama

2016-01-01

Hydrogen is expected to play a key role as an energy carrier in future energy systems of the world. As fossil-fuel supplies become scarcer and environmental concerns increase, hydrogen is likely to become an increasingly important chemical energy carrier and eventually may become the principal chemical energy carrier. When most of the world's energy sources become non-fossil based, hydrogen and electricity are expected to be the two dominant energy carriers for the provision of end-use services. In such a ''hydrogen economy,'' the two complementary energy carriers, hydrogen and electricity, are used to satisfy most of the requirements of energy consumers. A transition era will bridge the gap between today's fossil-fuel economy and a hydrogen economy, in which non-fossil-derived hydrogen will be used to extend the lifetime of the world's fossil fuels - by upgrading heavy oils, for instance - and the infrastructure needed to support a hydrogen economy is gradually developed. In this paper, the role of hydrogen as an energy carrier and hydrogen energy systems' technologies and their economics are described. Also, the social and political implications of hydrogen energy are examined, and the questions of when and where hydrogen is likely to become important are addressed. Examples are provided to illustrate key points. (orig.)

Hydrogen economy

Energy Technology Data Exchange (ETDEWEB)

Pahwa, P.K.; Pahwa, Gulshan Kumar

2013-10-01

In the future, our energy systems will need to be renewable and sustainable, efficient and cost-effective, convenient and safe. Hydrogen has been proposed as the perfect fuel for this future energy system. The availability of a reliable and cost-effective supply, safe and efficient storage, and convenient end use of hydrogen will be essential for a transition to a hydrogen economy. Research is being conducted throughout the world for the development of safe, cost-effective hydrogen production, storage, and end-use technologies that support and foster this transition. This book discusses hydrogen economy vis-a-vis sustainable development. It examines the link between development and energy, prospects of sustainable development, significance of hydrogen energy economy, and provides an authoritative and up-to-date scientific account of hydrogen generation, storage, transportation, and safety.

Hydrogen detector

International Nuclear Information System (INIS)

Kumagaya, Hiromichi; Yoshida, Kazuo; Sanada, Kazuo; Chigira, Sadao.

1994-01-01

The present invention concerns a hydrogen detector for detecting water-sodium reaction. The hydrogen detector comprises a sensor portion having coiled optical fibers and detects hydrogen on the basis of the increase of light transmission loss upon hydrogen absorption. In the hydrogen detector, optical fibers are wound around and welded to the outer circumference of a quartz rod, as well as the thickness of the clad layer of the optical fiber is reduced by etching. With such procedures, size of the hydrogen detecting sensor portion can be decreased easily. Further, since it can be used at high temperature, diffusion rate is improved to shorten the detection time. (N.H.)

IAEA Activities on Application of Nuclear Techniques in Development and Characterization of Materials for Hydrogen Economy

International Nuclear Information System (INIS)

Salame, P.; Zeman, A.; Mulhauser, F.

2011-01-01

Hydrogen and fuel cells can greatly contribute to a more sustainable less carbon-dependent global energy system. An effective and safe method for storage of hydrogen in solid materials is one of the greatest technologically challenging barriers of widespread introduction of hydrogen in global energy systems. However, aspects related to the development of effective materials for hydrogen storage and fuel cells are facing considerable technological challenges. To reach these goals, research efforts using a combination of advanced modeling, synthesis methods and characterization tools are required. Nuclear methods can play an effective role in the development and characterization of materials for hydrogen storage. Therefore, the IAEA initiated a coordinated research project to promote the application of nuclear techniques for investigation and characterization of new/improved materials relevant to hydrogen and fuel cell technologies. This paper gives an overview of the IAEA activities in this subject. (author)

Advanced Vehicle Testing and Evaluation

Energy Technology Data Exchange (ETDEWEB)

Garetson, Thomas [The Clarity Group, Incorporated, Chicago, IL (United States)

2013-03-31

The objective of the United States (U.S.) Department of Energy's (DOEs) Advanced Vehicle Testing and Evaluation (AVTE) project was to provide test and evaluation services for advanced technology vehicles, to establish a performance baseline, to determine vehicle reliability, and to evaluate vehicle operating costs in fleet operations.Vehicles tested include light and medium-duty vehicles in conventional, hybrid, and all-electric configurations using conventional and alternative fuels, including hydrogen in internal combustion engines. Vehicles were tested on closed tracks and chassis dynamometers, as well as operated on public roads, in fleet operations, and over prescribed routes. All testing was controlled by procedures developed specifically to support such testing.

Advanced Thin Ionization Calorimeter (ATIC)

Science.gov (United States)

Wefel, John P.

1998-01-01

This is the final report for NASA grant NAGW-4577, "Advanced Thin Ionization Calorimeter (ATIC)". This grant covered a joint project between LSU and the University of Maryland for a Concept Study of a new type of fully active calorimeter to be used to measure the energy spectra of very high energy cosmic rays, particularly Hydrogen and Helium, to beyond 1014 eV. This very high energy region has been studied with emulsion chamber techniques, but never investigated with electronic calorimeters. Technology had advanced to the point that a fully active calorimeter based upon Bismuth Germanate (BGO) scintillating crystals appeared feasible for balloon flight (and eventually space) experiments.

The prospects for hydrogen as an energy carrier: an overview of hydrogen energy and hydrogen energy systems

Energy Technology Data Exchange (ETDEWEB)

Rosen, Marc A.; Koohi-Fayegh, Seama [Ontario Univ., Oshawa, ON (Canada). Inst. of Technology

2016-02-15

Hydrogen is expected to play a key role as an energy carrier in future energy systems of the world. As fossil-fuel supplies become scarcer and environmental concerns increase, hydrogen is likely to become an increasingly important chemical energy carrier and eventually may become the principal chemical energy carrier. When most of the world's energy sources become non-fossil based, hydrogen and electricity are expected to be the two dominant energy carriers for the provision of end-use services. In such a ''hydrogen economy,'' the two complementary energy carriers, hydrogen and electricity, are used to satisfy most of the requirements of energy consumers. A transition era will bridge the gap between today's fossil-fuel economy and a hydrogen economy, in which non-fossil-derived hydrogen will be used to extend the lifetime of the world's fossil fuels - by upgrading heavy oils, for instance - and the infrastructure needed to support a hydrogen economy is gradually developed. In this paper, the role of hydrogen as an energy carrier and hydrogen energy systems' technologies and their economics are described. Also, the social and political implications of hydrogen energy are examined, and the questions of when and where hydrogen is likely to become important are addressed. Examples are provided to illustrate key points. (orig.)

Advances in magnetic resonance 2

CERN Document Server

Waugh, John S

2013-01-01

Advances in Magnetic Resonance, Volume 2, features a mixture of experimental and theoretical contributions. The book contains four chapters and begins with an ambitious and general treatment of the problem of signal-to-noise ratio in magnetic resonance. This is followed by separate chapters on the interpretation of nuclear relaxation in fluids, with special reference to hydrogen; and various aspects of molecular theory of importance in NMR.

Final Technical Report for GO15056 Millennium Cell: Development of an Advanced Chemical Hydrogen Storage and Generation System

Energy Technology Data Exchange (ETDEWEB)

Moreno, Oscar [Millennium Cell Inc., Eatontown, NJ (United States)

2017-02-22

The objectives of this project are to increase system storage capacity by improving hydrogen generation from concentrated sodium borohydride, with emphasis on reactor and system engineering; to complete a conceptual system design based on sodium borohydride that will include key technology improvements to enable a hydrogen fuel system that will meet the systembased storage capacity of 1.2 kWh/L (36 g H2/L) and 1.5 kWh/kg (45 g H2/kg), by the end of FY 2007; and to utilize engineering expertise to guide Center research in both off-board chemical hydride regeneration and on-board hydrogen generation systems.

Hydrogen Safety Sensor Performance and Use Gap Analysis: Preprint

Energy Technology Data Exchange (ETDEWEB)

Buttner, William J [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Burgess, Robert M [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Schmidt, Kara [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Hartmann, Kevin S [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Wright, Hannah [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Weidner, Eveline [Joint Research Centre, Petten, the Netherlands; Cebolla, Rafael O. [Joint Research Centre, Petten, the Netherlands; Bonato, Christian [Joint Research Centre, Petten, the Netherlands; Moretto, Pietro [Joint Research Centre, Petten, the Netherlands

2017-11-15

Hydrogen sensors are recognized as an important technology for facilitating the safe implementation of hydrogen as an alternative fuel, and there are numerous reports of a sensor alarm successfully preventing a potentially serious event. However, gaps in sensor metrological specifications, as well as in their performance for some applications, exist.The U.S. Department of Energy (DOE) Fuel Cell Technology Office published a short list of critical gaps in the 2007 and 2012 multiyear project plans; more detailed gap analyses were independently performed by the JRC and NREL. There have been, however, some significant advances in sensor technologies since these assessments, including the commercial availability of hydrogen sensors with fast response times (t90 less than 1 s, which had been an elusive DOE target since 2007), improved robustness to chemical poisons, improved selectivity, and improved lifetime and stability. These improvements, however, have not been universal and typically pertain to select platforms or models. Moreover, as hydrogen markets grow and new applications are being explored, more demands will be imposed on sensor performance. The hydrogen sensor laboratories at NREL and JRC are currently updating the hydrogen safety sensor gap analysis through direct interaction with international stakeholders in the hydrogen community, especially end-users. NREL and the JRC are currently organizing a series of workshops (in Europe and the U.S.) with sensor developers, end-users, and other stakeholders in 2017 to identify technology gaps and to develop a path forward to address them. One workshop is scheduled for May 10 in Brussels, Belgium at the Headquarters of the Fuel Cell and Hydrogen Joint Undertaking. A second workshop is planned at the National Renewable Energy Laboratory in Golden, CO, USA. This presentation will review improvements in sensor technologies in the past 5 to 10 years, identify gaps in sensor performance and use requirements, and identify

Hydrogen systems : a Canadian strategy for greenhouse gas reduction and economic growth

International Nuclear Information System (INIS)

2005-01-01

Rising concerns about the depletion of fossil fuels and climate change have led to the search for new energy sources. This paper outlines the mission of the Canadian Hydrogen Association, which is to build on Canada's energy resource base and expertise in hydrogen technologies in order to deploy sustainable hydrogen energy systems. Basic strategies needed to develop hydrogen systems in Canada were outlined, with specific reference to the establishment of low cost energy sources with low life-cycle emissions. The current hydrogen infrastructure produces marginal life-cycle emissions benefits, particularly when compared with improvements in technologies expected in the next 10 years. It was noted that regional development of hydrogen systems was likely to be an effective strategy, due to high transportation costs. Several potential locations were discussed for the development of a hydrogen energy infrastructure. Opportunities arising from hydrogen vehicle penetration of consumer markets and the broad commercialization of fuel cells were examined. Feasible transition strategies were reviewed, to be built in the near term around pathways such as hydrogen internal combustion engines and fuel cell vehicles designed for high-value niche applications. Strategies addressing the preparation of the market to express the value proposition for hydrogen were discussed, with reference to the fact that the existing energy market places no value on environmental factors. Several recommendations were made to conclude the discussion, and included: the necessity of government action to establish national goals; the creation of a stakeholder base for hydrogen systems; a government and industry partnership towards the development of a near-term commercialization plan; and the establishment of a long-term direction for the development of hydrogen systems in terms of advancing technology and public education. refs., tabs., figs

Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials

Energy Technology Data Exchange (ETDEWEB)

None

2010-03-01

This is a reference guide to common methodologies and protocols for measuring critical performance properties of advanced hydrogen storage materials. It helps users to communicate clearly the relevant performance properties of new materials as they are discovered and tested.

Multi-Disciplinary Multi-Fidelity Design Environment, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — To meet the design challenges of tomorrow, NASA and industry require advancements in the state-of-the-art for physics-based design and analysis frameworks. In...

Hydrogen Storage Engineering Center of Excellence Metal Hydride Final Report

Energy Technology Data Exchange (ETDEWEB)

Motyka, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2014-05-31

The Hydrogen Storage Engineering Center of Excellence (HSECoE) was established in 2009 by the U.S. Department of Energy (DOE) to advance the development of materials-based hydrogen storage systems for hydrogen-fueled light-duty vehicles. The overall objective of the HSECoE is to develop complete, integrated system concepts that utilize reversible metal hydrides, adsorbents, and chemical hydrogen storage materials through the use of advanced engineering concepts and designs that can simultaneously meet or exceed all the DOE targets. This report describes the activities and accomplishments during Phase 1 of the reversible metal hydride portion of the HSECoE, which lasted 30 months from February 2009 to August 2011. A complete list of all the HSECoE partners can be found later in this report but for the reversible metal hydride portion of the HSECoE work the major contributing organizations to this effort were the United Technology Research Center (UTRC), General Motors (GM), Pacific Northwest National Laboratory (PNNL), the National Renewable Energy Laboratory (NREL) and the Savannah River National Laboratory (SRNL). Specific individuals from these and other institutions that supported this effort and the writing of this report are included in the list of contributors and in the acknowledgement sections of this report. The efforts of the HSECoE are organized into three phases each approximately 2 years in duration. In Phase I, comprehensive system engineering analyses and assessments were made of the three classes of storage media that included development of system level transport and thermal models of alternative conceptual storage configurations to permit detailed comparisons against the DOE performance targets for light-duty vehicles. Phase 1 tasks also included identification and technical justifications for candidate storage media and configurations that should be capable of reaching or exceeding the DOE targets. Phase 2 involved bench-level testing and

Breath Hydrogen Produced by Ingestion of Commercial Hydrogen Water and Milk

OpenAIRE

Shimouchi, Akito; Nose, Kazutoshi; Yamaguchi, Makoto; Ishiguro, Hiroshi; Kondo, Takaharu

2009-01-01

Objective: To compare how and to what extent ingestion of hydrogen water and milk increase breath hydrogen in adults.Methods: Five subjects without specific diseases, ingested distilled or hydrogen water and milk as a reference material that could increase breath hydrogen. Their end-alveolar breath hydrogen was measured.Results: Ingestion of hydrogen water rapidly increased breath hydrogen to the maximal level of approximately 40 ppm 10–15 min after ingestion and thereafter rapidly decrease...

Hydrogen - From hydrogen to energy production

International Nuclear Information System (INIS)

Klotz, Gregory

2005-01-01

More than a century ago, Jules Verne wrote in 'The Mysterious Island' that water would one day be employed as fuel: 'Hydrogen and oxygen, which constitute it, used singly or together, will furnish an inexhaustible source of heat and light'. Today, the 'water motor' is not entirely the dream of a writer. Fiction is about to become fact thanks to hydrogen, which can be produced from water and when burned in air itself produces water. Hydrogen is now at the heart of international research. So why do we have such great expectations of hydrogen? 'Hydrogen as an energy system is now a major challenge, both scientifically and from an environmental and economic point of view'. Dominated as it is by fossil fuels (oil, gas and coal), our current energy system has left a dual threat hovering over our environment, exposing the planet to the exhaustion of its natural reserves and contributing to the greenhouse effect. If we want sustainable development for future generations, it is becoming necessary to diversify our methods of producing energy. Hydrogen is not, of course, a source of energy, because first it has to be produced. But it has the twofold advantage of being both inexhaustible and non-polluting. So in the future, it should have a very important role to play. (author)

Hydrogen fuel. Uses

International Nuclear Information System (INIS)

Darkrim-Lamari, F.; Malbrunot, P.

2006-01-01

Hydrogen is a very energetic fuel which can be used in combustion to generate heat and mechanical energy or which can be used to generate electricity and heat through an electrochemical reaction with oxygen. This article deals with the energy conversion, the availability and safety problems linked with the use of hydrogen, and with the socio-economical consequences of a generalized use of hydrogen: 1 - hydrogen energy conversion: hydrogen engines, aerospace applications, fuel cells (principle, different types, domains of application); 2 - hydrogen energy availability: transport and storage (gas pipelines, liquid hydrogen, adsorbed and absorbed hydrogen in solid materials), service stations; 3 - hazards and safety: flammability, explosibility, storage and transport safety, standards and regulations; 4 - hydrogen economy; 5 - conclusion. (J.S.)

A polymer electrolyte fuel cell stack for stationary power generation from hydrogen fuel

Energy Technology Data Exchange (ETDEWEB)

Gottesfeld, S. [Los Alamos National Lab., NM (United States)

1995-09-01

The fuel cell is the most efficient device for the conversion of hydrogen fuel to electric power. As such, the fuel cell represents a key element in efforts to demonstrate and implement hydrogen fuel utilization for electric power generation. The low temperature, polymer electrolyte membrane fuel cell (PEMFC) has recently been identified as an attractive option for stationary power generation, based on the relatively simple and benign materials employed, the zero-emission character of the device, and the expected high power density, high reliability and low cost. However, a PEMFC stack fueled by hydrogen with the combined properties of low cost, high performance and high reliability has not yet been demonstrated. Demonstration of such a stack will remove a significant barrier to implementation of this advanced technology for electric power generation from hydrogen. Work done in the past at LANL on the development of components and materials, particularly on advanced membrane/electrode assemblies (MEAs), has contributed significantly to the capability to demonstrate in the foreseeable future a PEMFC stack with the combined characteristics described above. A joint effort between LANL and an industrial stack manufacturer will result in the demonstration of such a fuel cell stack for stationary power generation. The stack could operate on hydrogen fuel derived from either natural gas or from renewable sources. The technical plan includes collaboration with a stack manufacturer (CRADA). It stresses the special requirements from a PEMFC in stationary power generation, particularly maximization of the energy conversion efficiency, extension of useful life to the 10 hours time scale and tolerance to impurities from the reforming of natural gas.

The dream of freedom and fear of it (Tyranny and vassalage in The Master is Coming Tomorrow by Petar Sarić

Directory of Open Access Journals (Sweden)

Jeftimijević-Mihajlović Marija S.

2017-01-01

Full Text Available The history of Serbian literature originating in Kosovo and Metohija during the second half of the previous century values Peter Sarić the most by his novel The Master is Coming Tomorrow, although he penned seven novels. The Master is Coming Tomorrow is the image of power which, instead of protecting human rights, is transformed into the instrument of violence. It is the image of tyrant and tyranny, and it is at the same time a caricature of people - vassals, who out of fear, rather humbly languish in the so-called freedom, zealously shouting the Master's name. One gets the impression that the writer wanted to portray vassalage in a satirical way more than tyranny. This thoroughly psychological characteristic of vassals, and power-holders of strong autocracy, makes Sarić a modern story-teller who has the courage and literary talent to dive into the deepest secrets of human nature, exposing the darkest corners of human psyche, something people are not willing to speak about. It is the novelty in the literature created in this area during the second half of the previous century; no other literary creation so clearly and precisely profiles the collective consciousness of one nation or the individuality of a ruler. In this novel, Sarić reveals a new face of patriarchal culture and the patriarchal system of the Montenegrin community. At the same time, Sarić confirms a known face of history, since each absolute power is based on identical levers of unscrupulous tyrants and humiliated, obedient people who resigned themselves to such a system.

Solar hydrogen production: renewable hydrogen production by dry fuel reforming

Science.gov (United States)

Bakos, Jamie; Miyamoto, Henry K.

2006-09-01

SHEC LABS - Solar Hydrogen Energy Corporation constructed a pilot-plant to demonstrate a Dry Fuel Reforming (DFR) system that is heated primarily by sunlight focusing-mirrors. The pilot-plant consists of: 1) a solar mirror array and solar concentrator and shutter system; and 2) two thermo-catalytic reactors to convert Methane, Carbon Dioxide, and Water into Hydrogen. Results from the pilot study show that solar Hydrogen generation is feasible and cost-competitive with traditional Hydrogen production. More than 95% of Hydrogen commercially produced today is by the Steam Methane Reformation (SMR) of natural gas, a process that liberates Carbon Dioxide to the atmosphere. The SMR process provides a net energy loss of 30 to 35% when converting from Methane to Hydrogen. Solar Hydrogen production provides a 14% net energy gain when converting Methane into Hydrogen since the energy used to drive the process is from the sun. The environmental benefits of generating Hydrogen using renewable energy include significant greenhouse gas and criteria air contaminant reductions.

Carbon Dioxide-Free Hydrogen Production with Integrated Hydrogen Separation and Storage.

Science.gov (United States)

Dürr, Stefan; Müller, Michael; Jorschick, Holger; Helmin, Marta; Bösmann, Andreas; Palkovits, Regina; Wasserscheid, Peter

2017-01-10

An integration of CO 2 -free hydrogen generation through methane decomposition coupled with hydrogen/methane separation and chemical hydrogen storage through liquid organic hydrogen carrier (LOHC) systems is demonstrated. A potential, very interesting application is the upgrading of stranded gas, for example, gas from a remote gas field or associated gas from off-shore oil drilling. Stranded gas can be effectively converted in a catalytic process by methane decomposition into solid carbon and a hydrogen/methane mixture that can be directly fed to a hydrogenation unit to load a LOHC with hydrogen. This allows for a straight-forward separation of hydrogen from CH 4 and conversion of hydrogen to a hydrogen-rich LOHC material. Both, the hydrogen-rich LOHC material and the generated carbon on metal can easily be transported to destinations of further industrial use by established transport systems, like ships or trucks. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Sensor for Measuring Hydrogen Partial Pressure in Parabolic Trough Power Plant Expansion Tanks

Energy Technology Data Exchange (ETDEWEB)

Glatzmaier, Greg C.; Cooney, Daniel A.

2017-06-27

The National Renewable Energy Laboratory and Acciona Energy North America are working together to design and implement a process system that provides a permanent solution to the issue of hydrogen buildup at parabolic trough power plants. We are pursuing a method that selectively removes hydrogen from the expansion tanks that serve as reservoirs for the heat transfer fluid (HTF) that circulates in the collector field and power block components. Our modeling shows that removing hydrogen from the expansion tanks at a design rate reduces and maintains dissolved hydrogen in the circulating HTF to a selected target level. Our collaborative work consists of several tasks that are needed to advance this process concept to a development stage, where it is ready for implementation at a commercial power plant. Our main effort is to design and evaluate likely process-unit operations that remove hydrogen from the expansion tanks at a specified rate. Additionally, we designed and demonstrated a method and instrumentation to measure hydrogen partial pressure and concentration in the expansion-tank headspace gas. We measured hydrogen partial pressure in the headspace gas mixture using a palladium-alloy membrane, which is permeable exclusively to hydrogen. The membrane establishes a pure hydrogen gas phase that is in equilibrium with the hydrogen in the gas mixture. We designed and fabricated instrumentation, and demonstrated its effectiveness in measuring hydrogen partial pressures over a range of three orders of magnitude. Our goal is to install this instrument at the Nevada Solar One power plant and to demonstrate its effectiveness in measuring hydrogen levels in the expansion tanks under normal plant operating conditions.

Production of hydrogen from organic waste via hydrogen sulfide

International Nuclear Information System (INIS)

McMahon, M.; Davis, B.R.; Roy, A.; Daugulis, A.

2007-01-01

In this paper an integrated process is proposed that converts organic waste to hydrogen via hydrogen sulphide. The designed bioreactor has achieved high volumetric productivities comparable to methanogenic bioreactors. Proposed process has advantages of bio-methane production and is more resilient to process upset. Thermochemical conversion of hydrogen sulphide to hydrogen is exothermic and also requires smaller plant infrastructure

Large Scale Production of Densified Hydrogen Using Integrated Refrigeration and Storage

Science.gov (United States)

Notardonato, William U.; Swanger, Adam Michael; Jumper, Kevin M.; Fesmire, James E.; Tomsik, Thomas M.; Johnson, Wesley L.

2017-01-01

Recent demonstration of advanced liquid hydrogen storage techniques using Integrated Refrigeration and Storage (IRAS) technology at NASA Kennedy Space Center led to the production of large quantities of solid densified liquid and slush hydrogen in a 125,000 L tank. Production of densified hydrogen was performed at three different liquid levels and LH2 temperatures were measured by twenty silicon diode temperature sensors. System energy balances and solid mass fractions are calculated. Experimental data reveal hydrogen temperatures dropped well below the triple point during testing (up to 1 K), and were continuing to trend downward prior to system shutdown. Sub-triple point temperatures were seen to evolve in a time dependent manner along the length of the horizontal, cylindrical vessel. Twenty silicon diode temperature sensors were recorded over approximately one month for testing at two different fill levels (33 67). The phenomenon, observed at both two fill levels, is described and presented detailed and explained herein., and The implications of using IRAS for energy storage, propellant densification, and future cryofuel systems are discussed.

Hydrogen as the solar energy translator. [in photochemical and photovoltaic processes

Science.gov (United States)

Kelley, J. H.

1979-01-01

Many concepts are being investigated to convert sunlight to workable energy forms with emphasis on electricity and thermal energy. The electrical alternatives include direct conversion of photons to electricity via photovoltaic solar cells and solar/thermal production of electricity via heat-energy cycles. Solar cells, when commercialized, are expected to have efficiencies of about 12 to 14 percent. The cells would be active about eight hours per day. However, solar-operated water-splitting process research, initiated through JPL, shows promise for direct production of hydrogen from sunlight with efficiencies of up to 35 to 40 percent. The hydrogen, a valuable commodity in itself, can also serve as a storable energy form, easily and efficiently converted to electricity by fuel cells and other advanced-technology devices on a 24-hour basis or on demand with an overall efficiency of 25 to 30 percent. Thus, hydrogen serves as the fundamental translator of energy from its solar form to electrical form more effectively, and possibly more efficiently, than direct conversion. Hydrogen also can produce other chemical energy forms using solar energy.

Neutron-induced hydrogen and helium production in iron

Energy Technology Data Exchange (ETDEWEB)

Haight, Robert C.

2004-01-01

In support of the Advanced Fuel Cycle Initiative, cross sections for hydrogen and helium production by neutrons are being investigated on structural materials from threshold to 100 MeV with the continuous-in-energy spallation neutron source at the Los Alamos Neutron Science Center (LANSCE). The present measurements are for elemental iron. The results are compared with values from the ENDF/B-VI library and its extension with LA150 evaluations. For designs in the Advanced Fuel Cycle Initiative, structural materials will be subjected to very large fluences of neutrons, and the selection of these materials will be guided by their resistance to radiation damage. The macroscopic effects of radiation damage result both from displacement of atoms in the materials as well as nuclear transmutation. We are studying the production of hydrogen and helium by neutrons, because these gases can lead to significant changes in materials properties such as embrittlement and swelling. Our experiments span the full range from threshold to 100 MeV. The lower neutron energies are those characteristic of fission neutrons, whereas the higher energies are relevant for accelerator-based irradiation test facilities. Results for the nickel isotopes, {sup 58,60}Ni, have been reported previously. The present studies are on natural iron.

Towards an energy transition? Which energies for tomorrow and for all, on the territory. Research-action, problematic note - Activity report 2012-2014 - Final report. Citizen recommendations

International Nuclear Information System (INIS)

Aubin, Samuel; Lemoult, Bernard; Allagnat, Bernard; Cohu, Sylvie; Gadoin, Emilie; Crochet, Moise; Dothee, Jean-Luc; Gauduchon, Marie-Veronique; Gendre, Nicolas; Musard, Denis; Retiere, Alain; Vacher, Pierre; Vilbert, Christine; Petillon, Xavier; Damerose, Clotilde

2014-11-01

This document first presents a project launched on the issue of energy choice for tomorrow for the territory, and more particularly on a shared regional diagnosis and principles for action. A second document reports activities of this research-action project which aimed at making citizen recommendations emerge, and at elaborating an operational territorial tool for energy transition. Then comes the final report of this project. After an introduction which outlines that energy transition is a major stake for the territory, a first chapter discusses which are tomorrow's energies by outlining the climatic emergency, the energy situation at the world level, the perspective of smart cities and communities, national energetic stakes, the role given to citizen, and the perspective of a new relationship to the world and to the nature. The second chapter briefly evokes the perspective for 2050. The next part discusses the societal dimension of energy transition, and examines what could be the engines for change. The next chapter identifies and discusses various debates to be held: on climate situation, on energy resource availability, on human development and on the economic model. The last chapter outlines the role of the territorial scale and of collective dynamics to elaborate and implement scenarios of energy transition

The Australian Hydrogen and Fuel Cells Education Program

International Nuclear Information System (INIS)

Luigi Bonadio

2006-01-01

The next generation of engineers and scientists will face great technical, economic and political challenges to satisfy increasing demands for a secure, reliable and affordable global energy system that maintains and enhances current standards of living. The Australian Hydrogen and Fuel Cells Education Program aims to bolster the quality and relevance of primary and secondary school teaching in emerging areas of science, technology and environmental/sustainability studies using hydrogen, in its capacity as a versatile energy carrier, as the educational basis for teacher and student learning. Critical advances in specific areas of hydrogen production, distribution, storage and end-use technologies arise when students are engaged to develop and apply a broad range of disciplinary and interdisciplinary knowledge and practical skills. A comprehensive hydrogen and fuel cell technology teaching module will be developed to complement existing fuels and energy curricula across Australian schools. The pilot program will be delivered via the collaboration of nine trial schools, a broad range of technical and pedagogy experts and representatives of professional bodies and industry. The program features essential and extensive teacher consultation, a professional learning and development course, industry site visits and a dedicated research and evaluation study. This initiative aims to bolster teacher literacy and student participation in the design, construction and operation of various hydrogen and fuel cell devices and extended activities. Students will reflect on and formally present their learning experiences via several dedicated fora including an awards ceremony where outstanding performance of leading schools, teachers and student groups within the cluster will be acknowledged. (authors)

The Australian Hydrogen and Fuel Cells Education Program

Energy Technology Data Exchange (ETDEWEB)

Luigi Bonadio [Senior Consultant Luigi Bonadio and Associates (Australia)

2006-07-01

The next generation of engineers and scientists will face great technical, economic and political challenges to satisfy increasing demands for a secure, reliable and affordable global energy system that maintains and enhances current standards of living. The Australian Hydrogen and Fuel Cells Education Program aims to bolster the quality and relevance of primary and secondary school teaching in emerging areas of science, technology and environmental/sustainability studies using hydrogen, in its capacity as a versatile energy carrier, as the educational basis for teacher and student learning. Critical advances in specific areas of hydrogen production, distribution, storage and end-use technologies arise when students are engaged to develop and apply a broad range of disciplinary and interdisciplinary knowledge and practical skills. A comprehensive hydrogen and fuel cell technology teaching module will be developed to complement existing fuels and energy curricula across Australian schools. The pilot program will be delivered via the collaboration of nine trial schools, a broad range of technical and pedagogy experts and representatives of professional bodies and industry. The program features essential and extensive teacher consultation, a professional learning and development course, industry site visits and a dedicated research and evaluation study. This initiative aims to bolster teacher literacy and student participation in the design, construction and operation of various hydrogen and fuel cell devices and extended activities. Students will reflect on and formally present their learning experiences via several dedicated fora including an awards ceremony where outstanding performance of leading schools, teachers and student groups within the cluster will be acknowledged. (authors)

Fuel Cell and Hydrogen Technologies Program | Hydrogen and Fuel Cells |

Science.gov (United States)

NREL Fuel Cell and Hydrogen Technologies Program Fuel Cell and Hydrogen Technologies Program Through its Fuel Cell and Hydrogen Technologies Program, NREL researches, develops, analyzes, and validates fuel cell and hydrogen production, delivery, and storage technologies for transportation

Advances in BWR water chemistry

International Nuclear Information System (INIS)

Garcia, Susan E.; Giannelli, Joseph F.; Jarvis, Mary L.

2012-09-01

This paper reviews recent advances in Boiling Water Reactor (BWR) water chemistry control with examples of plant experiences at U.S. designed BWRs. Water chemistry advances provide some of the most effective methods for mitigating materials degradation, reducing fuel performance concerns and lowering radiation fields. Mitigation of stress corrosion cracking (SCC) of materials remains a high priority and improved techniques that have been demonstrated in BWRs will be reviewed, specifically hydrogen injection combined with noble metal chemical addition (NMCA) and the newer on-line noble metal application process (OLNC). Hydrogen injection performance, an important part of SCC mitigation, will also be reviewed for the BWR fleet, highlighting system improvements that have enabled earlier injection of hydrogen including the potential for hydrogen injection during plant startup. Water chemistry has been significantly improved by the application of pre-filtration and optimized use of ion exchange resins in the CP (condensate polishing) and reactor water cleanup (RWCU) systems. EPRI has monitored and supported water treatment improvements to meet water chemistry goals as outlined in the EPRI BWR Water Chemistry Guidelines, particularly those for SCC mitigation of reactor internals and piping, minimization of fuel risk due to corrosion and crud deposits and chemistry control for radiation field reduction. In recent years, a significant reduction has occurred in feedwater corrosion product input, particularly iron. A large percentage of plants are now reporting <0.1 ppb feedwater iron. The impacts to plant operation and chemistry of lower feedwater iron will be explored. Depleted zinc addition is widely practiced across the fleet and the enhanced focus on radiation reduction continues to emphasize the importance of controlling radiation source term. In addition, shutdown chemistry control is necessary to avoid excessive release of activated corrosion products from fuel

Methods for evaluation of hydrogen effect on service behaviour of titanium base alloys

International Nuclear Information System (INIS)

Mal'kov, A.V.; Kolachev, B.A.

1979-01-01

A comparative evaluation of the effect of hydrogen upon the service ability of α, β, α+β and pseudo-α titanium alloys is carried out using the results of various mechanical tests. Presented are the values of the critical concentration of hydrogen, determined by impact strength tests, tensile tests of notched specimens, fracture toughness tests, slow failure tests and the determination of the energy of failure. A hypothesis is advanced that the failure energy of titanium alloys depends directly upon the type of stressed state. This hypothesis explains the S shapes of the curves describing the dependences of the impact strength, the coefficient of stress intensity and the ratios of the tensile strength of smooth and notched specimens upon the hydrogen content

Energy recovery during advanced wastewater treatment: simultaneous estrogenic activity removal and hydrogen production through solar photocatalysis.

Science.gov (United States)

Zhang, Wenlong; Li, Yi; Wang, Chao; Wang, Peifang; Wang, Qing

2013-03-01

Simultaneous estrogenic activity removal and hydrogen production from secondary effluent were successfully achieved using TiO(2) microspheres modified with both platinum nanoparticles and phosphates (P-TiO(2)/Pt) for the first time. The coexistence of platinum and phosphate on the surface of TiO(2) microspheres was confirmed by transmission electron microscope, energy-dispersive X-ray and X-ray photoelectron spectroscopy analyses. P-TiO(2)/Pt microspheres showed a significantly higher photocatalytic activity than TiO(2) microspheres and TiO(2) powders (P25) for the removal of estrogenic activity from secondary effluent with the removal ratio of 100%, 58.2% and 48.5% in 200 min, respectively. Moreover, the marked production of hydrogen (photonic efficiency: 3.23 × 10(-3)) was accompanied by the removal of estrogenic activity only with P-TiO(2)/Pt as photocatalysts. The hydrogen production rate was increasing with decreased DO concentration in secondary effluent. Results of reactive oxygen species (ROS) evaluation during P-TiO(2)/Pt photocatalytic process showed that O(2)(-)and OH were dominant ROS in aerobic phase, while OH was the most abundant ROS in anoxic phase. Changes of effluent organic matter (EfOM) during photocatalysis revealed that aromatic, hydrophobic, and high molecular weight fractions of EfOM were preferentially transformed into non-humic, hydrophilic, and low MW fractions (e.g. aldehydes and carboxylic acids), which were continuously utilized as electron donors in hydrogen production process. Copyright © 2012 Elsevier Ltd. All rights reserved.

Hydrogen Village : creating hydrogen and fuel cell communities

International Nuclear Information System (INIS)

Smith, G.R.

2009-01-01

The Hydrogen Village (H2V) is a collaborative public-private partnership administered through Hydrogen and Fuel Cells Canada and funded by the Governments of Canada and Ontario. This end user-driven, market development program accelerates the commercialization of hydrogen and fuel cell (FC) technologies throughout the Greater Toronto Area (GTA). The program targets 3 specific aspects of market development, notably deployment of near market technologies in community based stationary and mobile applications; development of a coordinated hydrogen delivery and equipment service infrastructure; and societal factors involving corporate policy and public education. This presentation focused on lessons learned through outreach programs and the deployment of solid oxide fuel cell (SOFC) heat and power generation; indoor and outdoor fuel cell back up power systems; fuel cell-powered forklifts, delivery vehicles, and utility vehicles; hydrogen internal combustion engine powered shuttle buses, sedans, parade float; hydrogen production/refueling stations in the downtown core; and temporary fuel cell power systems

Hydrogen energy assessment

Energy Technology Data Exchange (ETDEWEB)

Salzano, F J; Braun, C [eds.

1977-09-01

The purpose of this assessment is to define the near term and long term prospects for the use of hydrogen as an energy delivery medium. Possible applications of hydrogen are defined along with the associated technologies required for implementation. A major focus in the near term is on industrial uses of hydrogen for special applications. The major source of hydrogen in the near term is expected to be from coal, with hydrogen from electric sources supplying a smaller fraction. A number of potential applications for hydrogen in the long term are identified and the level of demand estimated. The results of a cost benefit study for R and D work on coal gasification to hydrogen and electrolytic production of hydrogen are presented in order to aid in defining approximate levels of R and D funding. A considerable amount of data is presented on the cost of producing hydrogen from various energy resources. A key conclusion of the study is that in time hydrogen is likely to play a role in the energy system; however, hydrogen is not yet competitive for most applications when compared to the cost of energy from petroleum and natural gas.

A hydrogen infrastructure - what, why, when and how - an oil industry perspective

International Nuclear Information System (INIS)

Livesey, A.

1999-01-01

Shell Oil's exploration of profitable business opportunities afforded by fuel cells and by the emergence of a viable hydrogen economy is discussed. The emphasis in this paper is on the transportation sector, particularly the importance of a refueling infrastructure and the influence that consumer attitudes will have on which technological solution will gain the upper hand in hydrogen-powered vehicle development. Key issues facing the oil industry with regard to development of hydrogen as the new energy carrier are also reviewed. Methanol reformer fuel cell cars are the most likely to gain acceptability in the short term, but the probability of methanol fuel cell vehicles being replaced by gasoline or hydrogen fuelled fuel cell vehicles or be superseded by advances in internal combustion engine and after-treatment technology, are very real. Government regulations, fiscal incentives and societal pressures will be the principal determinants of development. Beyond hydrogen energy there are a number of other potentially game-changing technologies that also have to be reckoned with. Among these possibilities are lightweight vehicles, direct methanol fuel cells, new proton exchange membrane fuel cells and driverless highways

A hydrogen infrastructure - what, why, when and how - an oil industry perspective

Energy Technology Data Exchange (ETDEWEB)

Livesey, A. [Shell International Ltd., Shell Hydrogen, Cheshire (United Kingdom)

1999-07-01

Shell Oil's exploration of profitable business opportunities afforded by fuel cells and by the emergence of a viable hydrogen economy is discussed. The emphasis in this paper is on the transportation sector, particularly the importance of a refueling infrastructure and the influence that consumer attitudes will have on which technological solution will gain the upper hand in hydrogen-powered vehicle development. Key issues facing the oil industry with regard to development of hydrogen as the new energy carrier are also reviewed. Methanol reformer fuel cell cars are the most likely to gain acceptability in the short term, but the probability of methanol fuel cell vehicles being replaced by gasoline or hydrogen fuelled fuel cell vehicles or be superseded by advances in internal combustion engine and after-treatment technology, are very real. Government regulations, fiscal incentives and societal pressures will be the principal determinants of development. Beyond hydrogen energy there are a number of other potentially game-changing technologies that also have to be reckoned with. Among these possibilities are lightweight vehicles, direct methanol fuel cells, new proton exchange membrane fuel cells and driverless highways.

A hydrogen infrastructure - what, why, when and how - an oil industry perspective

Energy Technology Data Exchange (ETDEWEB)

Livesey, A. [Shell International Ltd., Shell Hydrogen, Cheshire (United Kingdom)

1999-12-01

Shell Oil`s exploration of profitable business opportunities afforded by fuel cells and by the emergence of a viable hydrogen economy is discussed. The emphasis in this paper is on the transportation sector, particularly the importance of a refueling infrastructure and the influence that consumer attitudes will have on which technological solution will gain the upper hand in hydrogen-powered vehicle development. Key issues facing the oil industry with regard to development of hydrogen as the new energy carrier are also reviewed. Methanol reformer fuel cell cars are the most likely to gain acceptability in the short term, but the probability of methanol fuel cell vehicles being replaced by gasoline or hydrogen fuelled fuel cell vehicles or be superseded by advances in internal combustion engine and after-treatment technology, are very real. Government regulations, fiscal incentives and societal pressures will be the principal determinants of development. Beyond hydrogen energy there are a number of other potentially game-changing technologies that also have to be reckoned with. Among these possibilities are lightweight vehicles, direct methanol fuel cells, new proton exchange membrane fuel cells and driverless highways.

Performance of a 10-kJ SMES model cooled by liquid hydrogen thermo-siphon flow for ASPCS study

International Nuclear Information System (INIS)

Makida, Y; Shintomi, T; Hamajima, T; Tsuda, M; Miyagi, D; Ota, N; Katsura, M; Ando, K; Takao, T; Tsujigami, H; Fujikawa, S; Hirose, J; Iwaki, K; Komagome, T

2015-01-01

We propose a new electrical power storage and stabilization system, called an Advanced Superconducting Power Conditioning System (ASPCS), which consists of superconducting magnetic energy storage (SMES) and hydrogen energy storage, converged on a liquid hydrogen station for fuel cell vehicles. A small 10- kJ SMES system, in which a BSCCO coil cooled by liquid hydrogen was installed, was developed to create an experimental model of an ASPCS. The SMES coil is conductively cooled by liquid hydrogen flow through a thermo-siphon line under a liquid hydrogen buffer tank. After fabrication of the system, cooldown tests were carried out using liquid hydrogen. The SMES coil was successfully charged up to a nominal current of 200 A. An eddy current loss, which was mainly induced in pure aluminum plates pasted onto each pancake coils for conduction cooling, was also measured. (paper)

Hydrogen production through photovoltaic processes: Italian ENEA and other research projects

International Nuclear Information System (INIS)

Barra, L.; Coiante, D.

1992-01-01

Brief arguments favouring greater emphasis by government R ampersand D strategies on commercialization efforts to further develop hydrogen production processes involving the use of renewable energy sources are presented. These include the worsening global greenhouse effect problems due to the intensified use of fossil fuels and recent technological advances being made in photovoltaic energy conversion. A world-wide review is then made of on-going research programs in hydrogen production through the use of hydroelectric and solar energy sources. This review provides outlines of project objectives, schedules and financing schemes. Attention is given to the commercialization programs and strategies of ENEA (Italian Commission for New Technologies, Energy and the Environment)

Estimation of the hydrogen flux from a PEM electrolyzer, based in the solar irradiation measured in Zacatecas Mexico

Energy Technology Data Exchange (ETDEWEB)

Duron-Torres, S.M.; Villagrana-Munoz, L.E.; Garcia-Saldivar, V.M.; Escalante-Garcia, I.L. [Univ. Autonoma de Zacatecas, Zacatecas (Mexico). Unidad Academica de Ciencias Quimicas; Arriaga-Hurtado, L.G. [Centro de Investigacion y Desarrollo Tecnologico en Electroquimica, Pedro Escobedo (Mexico)

2010-07-15

The current cost of obtaining hydrogen from electrolyzers is higher than the cost of producing fossil fuels. However, with advances in technology and greater use of alternative energy sources, the cost of electrolytic hydrogen production may decrease to the point of being competitive. This study calculated how much hydrogen can be produced in a typical polymer exchange membrane (PEM) electrolyzer. Local solar irradiation measurements were carried out from November 2007 to April 2008 at the Campus Siglo 21 Solarimetric Station at Zacatecas University in Mexico. The mean irradiation measured was 6.6 kW-h per m{sup 2}. Based on the solar data obtained at the station, the hydrogen produced by a typical solar-hydrogen (SH) system was evaluated. The study showed that an important quantity of hydrogen as an energy vector could be obtained from solar radiation. April was determined to be the month of maximum hydrogen production. The lowest hydrogen production was in November. The data obtained during this study can be used to evaluate the solar renewable energy resource expressed as hydrogen production. 19 refs., 1 tab., 4 figs.

An Overview of Natural Gas Conversion Technologies for Co-Production of Hydrogen and Value-Added Solid Carbon Products

Energy Technology Data Exchange (ETDEWEB)

Dagle, Robert A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Dagle, Vanessa [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Bearden, Mark D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Holladay, Jamelyn D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Krause, Theodore R. [Argonne National Lab. (ANL), Argonne, IL (United States); Ahmed, Shabbir [Argonne National Lab. (ANL), Argonne, IL (United States)

2017-11-16

This report was prepared in response to the U.S. Department of Energy Fuel Cell Technologies Office Congressional Appropriation language to support research on carbon-free production of hydrogen using new chemical processes that utilize natural gas to produce solid carbon and hydrogen. The U.S. produces 9-10 million tons of hydrogen annually with more than 95% of the hydrogen produced by steam-methane reforming (SMR) of natural gas. SMR is attractive because of its high hydrogen yield; but it also converts the carbon to carbon dioxide. Non-oxidative thermal decomposition of methane to carbon and hydrogen is an alternative to SMR and produces CO₂-free hydrogen. The produced carbon can be sold as a co-product, thus providing economic credit that reduces the delivered net cost of hydrogen. The combination of producing hydrogen with potentially valuable carbon byproducts has market value in that this allows greater flexibility to match the market prices of hydrogen and carbon. That is, the higher value product can subsidize the other in pricing decisions. In this report we highlight the relevant technologies reported in the literature—primarily thermochemical and plasma conversion processes—and recent research progress and commercial activities. Longstanding technical challenges include the high energetic requirements (e.g., high temperatures and/or electricity requirements) necessary for methane activation and, for some catalytic processes, the separation of solid carbon product from the spent catalyst. We assess current and new carbon product markets that could be served given technological advances, and we discuss technical barriers and potential areas of research to address these needs. We provide preliminary economic analysis for these processes and compare to other emerging (e.g., electrolysis) and conventional (e.g., SMR) processes for hydrogen production. The overarching conclusion of this study is that the cost of hydrogen can be potentially

Hydrogen separation process

Science.gov (United States)

Mundschau, Michael [Longmont, CO; Xie, Xiaobing [Foster City, CA; Evenson, IV, Carl; Grimmer, Paul [Longmont, CO; Wright, Harold [Longmont, CO

2011-05-24

A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

Evaluation of advanced containment features proposed to Korean SNPP

International Nuclear Information System (INIS)

Jin, Y.; Park, S.Y.; Kim, S.D.; Kim, D.H.

1997-01-01

Korean Standard Nuclear Power Plant (KSNP) has adopted many advanced design features to enhance its containment performance during severe accidents as well as to reduce changes of core damage. Robust design of containment and hydrogen mixing capability reduced containment failure probability significantly. In addition to these features, new systems are proposed for KSNP: advanced design of cavity geometry, reactor cavity flooding system, hydrogen igniter, and containment filtered venting system. Before these proposals are adopted to the KSNP, their effectiveness on containment performance has been assessed systematically. Containment event tree and sensitivity analysis are used to quantify the effectiveness of these design features. The overall results indicate that these new features do not improve the containment performance significantly except the containment filtered venting system. But adoption of the containment filtered venting system should be examined carefully because accidental failure of this system may result in undue risk to public. (author)

NATO Advanced Study Institute on Metal Hydrides

CERN Document Server

1981-01-01

In the last five years, the study of metal hydrides has ex­ panded enormously due to the potential technological importance of this class of materials in hydrogen based energy conversion schemes. The scope of this activity has been worldwide among the industrially advanced nations. There has been a consensus among researchers in both fundamental and applied areas that a more basic understanding of the properties of metal/hydrogen syster;,s is required in order to provide a rational basis for the selection of materials for specific applications. The current worldwide need for and interest in research in metal hydrides indicated the timeliness of an Advanced Study Insti­ tute to provide an in-depth view of the field for those active in its various aspects. The inclusion of speakers from non-NATO coun­ tries provided the opportunity for cross-fertilization of ideas for future research. While the emphasis of the Institute was on basic properties, there was a conscious effort to stimulate interest in the applic...

Use of nuclear energy for hydrogen production

International Nuclear Information System (INIS)

Axente, Damian

2006-01-01

Full text: The potentials of three hydrogen production processes under development for the industrial production of hydrogen using nuclear energy, namely the advanced electrolysis the steam reforming, the sulfur-iodine water splitting cycle, are compared and evaluated in this paper. Water electrolysis and steam reforming of methane are proven and used extensively today for the production of hydrogen. The overall thermal efficiency of the electrolysis includes the efficiency of the electrical power generation and of the electrolysis itself. The electrolysis process efficiency is about 75 % and of electrical power generation is only about 30 %, the overall thermal efficiency for H 2 generation being about 25 %. Steam reforming process consists of reacting methane (or natural gas) and steam in a chemical reactor at 800-900 deg. C, with a thermal efficiency of about 70 %. In a reforming process, with heat supplied by nuclear reactor, the heat must be supplied by a secondary loop from the nuclear side and be transferred to the methane/steam mixture, via a heat exchanger type reactor. The sulfur-iodine cycle, a thermochemical water splitting, is of particular interest because it produces hydrogen efficiently with no CO 2 as byproduct. If heated with a nuclear source it could prove to be an ideal environmental solution to hydrogen production. Steam reforming remains the cheapest hydrogen production method based on the latest estimates, even when implemented with nuclear reactor. The S-I cycle offers a close second solution and the electrolysis is the most expensive of the options for industrial H 2 production. The nuclear plant could power electrolysis operations right away; steam reforming with nuclear power is a little bit further off into the future, the first operation with nuclear facility is expected to have place in Japan in 2008. The S-I cycle implementation is still over the horizon, it will be more than 10 years until we will see that cycle in full scale

Deliberate ignition of hydrogen-air-steam mixtures in condensing steam environments

International Nuclear Information System (INIS)

Blanchat, T.K.; Stamps, D.W.

1997-05-01

Large scale experiments were performed to determine the effectiveness of thermal glow plug igniters to burn hydrogen in a condensing steam environment due to the presence of water sprays. The experiments were designed to determine if a detonation or accelerated flame could occur in a hydrogen-air-steam mixture which was initially nonflammable due to steam dilution but was rendered flammable by rapid steam condensation due to water sprays. Eleven Hydrogen Igniter Tests were conducted in the test vessel. The vessel was instrumented with pressure transducers, thermocouple rakes, gas grab sample bottles, hydrogen microsensors, and cameras. The vessel contained two prototypic engineered systems: (1) a deliberate hydrogen ignition system and (2) a water spray system. Experiments were conducted under conditions scaled to be nearly prototypic of those expected in Advanced Light Water Reactors (such as the Combustion Engineering (CE) System 80+), with prototypic spray drop diameter, spray mass flux, steam condensation rates, hydrogen injection flow rates, and using the actual proposed plant igniters. The lack of any significant pressure increase during the majority of the burn and condensation events signified that localized, benign hydrogen deflagration(s) occurred with no significant pressure load on the containment vessel. Igniter location did not appear to be a factor in the open geometry. Initially stratified tests with a stoichiometric mixture in the top showed that the water spray effectively mixes the initially stratified atmosphere prior to the deflagration event. All tests demonstrated that thermal glow plugs ignite hydrogen-air-steam mixtures under conditions with water sprays near the flammability limits previously determined for hydrogen-air-steam mixtures under quiescent conditions. This report describes these experiments, gives experimental results, and provides interpretation of the results. 12 refs., 127 figs., 16 tabs

Canadian Hydrogen Association workshop on building Canadian strength with hydrogen systems. Proceedings

International Nuclear Information System (INIS)

2006-01-01

The Canadian Hydrogen Association workshop on 'Building Canadian Strength with Hydrogen Systems' was held in Montreal, Quebec, Canada on October 19-20, 2006. Over 100 delegates attended the workshop and there were over 50 presentations made. The Canadian Hydrogen Association (CHA) promotes the development of a hydrogen infrastructure and the commercialization of new, efficient and economic methods that accelerate the adoption of hydrogen technologies that will eventually replace fossil-based energy systems to reduce greenhouse gas emissions. This workshop focused on defining the strategic direction of research and development that will define the future of hydrogen related energy developments across Canada. It provided a forum to strengthen the research, development and innovation linkages among government, industry and academia to build Canadian strength with hydrogen systems. The presentations described new technologies and the companies that are making small scale hydrogen and hydrogen powered vehicles. Other topics of discussion included storage issues, hydrogen safety, competition in the hydrogen market, hydrogen fuel cell opportunities, nuclear-based hydrogen production, and environmental impacts

Homogeneous Catalysis for Sustainable Hydrogen Storage in Formic Acid and Alcohols.

Science.gov (United States)

Sordakis, Katerina; Tang, Conghui; Vogt, Lydia K; Junge, Henrik; Dyson, Paul J; Beller, Matthias; Laurenczy, Gábor

2018-01-24

Hydrogen gas is a storable form of chemical energy that could complement intermittent renewable energy conversion. One of the main disadvantages of hydrogen gas arises from its low density, and therefore, efficient handling and storage methods are key factors that need to be addressed to realize a hydrogen-based economy. Storage systems based on liquids, in particular, formic acid and alcohols, are highly attractive hydrogen carriers as they can be made from CO 2 or other renewable materials, they can be used in stationary power storage units such as hydrogen filling stations, and they can be used directly as transportation fuels. However, to bring about a paradigm change in our energy infrastructure, efficient catalytic processes that release the hydrogen from these molecules, as well as catalysts that regenerate these molecules from CO 2 and hydrogen, are required. In this review, we describe the considerable progress that has been made in homogeneous catalysis for these critical reactions, namely, the hydrogenation of CO 2 to formic acid and methanol and the reverse dehydrogenation reactions. The dehydrogenation of higher alcohols available from renewable feedstocks is also described. Key structural features of the catalysts are analyzed, as is the role of additives, which are required in many systems. Particular attention is paid to advances in sustainable catalytic processes, especially to additive-free processes and catalysts based on Earth-abundant metal ions. Mechanistic information is also presented, and it is hoped that this review not only provides an account of the state of the art in the field but also offers insights into how superior catalytic systems can be obtained in the future.

Research Progress on the Indirect Hydrogenation of Carbon Dioxide to Methanol.

Science.gov (United States)

Du, Xian-Long; Jiang, Zheng; Su, Dang Sheng; Wang, Jian-Qiang

2016-02-19

Methanol is a sustainable source of liquid fuels and one of the most useful organic chemicals. To date, most of the work in this area has focused on the direct hydrogenation of CO2 to methanol. However, this process requires high operating temperatures (200-250 °C), which limits the theoretical yield of methanol. Thus, it is desirable to find a new strategy for the efficient conversion of CO2 to methanol at relatively low reaction temperatures. This Minireview seeks to outline the recent advances on the indirect hydrogenation of CO2 to methanol. Much emphasis is placed on discussing specific systems, including hydrogenation of CO2 derivatives (organic carbonates, carbamates, formates, cyclic carbonates, etc.) and cascade reactions, with the aim of critically highlighting both the achievements and remaining challenges associated with this field. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hydrogen Production System with High Temperature Electrolysis for Nuclear Power Plant

International Nuclear Information System (INIS)

Kentaro, Matsunaga; Eiji, Hoashi; Seiji, Fujiwara; Masato, Yoshino; Taka, Ogawa; Shigeo, Kasai

2006-01-01

Steam electrolysis with solid oxide cells is one of the most promising methods for hydrogen production, which has the potential to be high efficiency. Its most parts consist of environmentally sound and common materials. Recent development of ceramics with high ionic conductivity suggests the possibility of widening the range of operating temperature with maintaining the high efficiency. Toshiba is constructing a hydrogen production system with solid oxide electrolysis cells for nuclear power plants. Tubular-type cells using YSZ (Yttria-Stabilized- Zirconia) as electrolyte showed good performance of steam electrolysis at 800 to 900 deg C. Larger electrolysis cells with present configuration are to be combined with High Temperature Reactors. The hydrogen production efficiency on the present designed system is expected around 50% at 800 to 900 deg C of operating temperature. For the Fast Reactors, 'advanced cell' with higher efficiency at lower temperature are to be introduced. (authors)

Mode Conversion of High-Field-Side-Launched Fast Waves at the Second Harmonic of Minority Hydrogen in Advanced Tokamak Reactors

International Nuclear Information System (INIS)

Sund, R.; Scharer, J.

2003-01-01

Under advanced tokamak reactor conditions, the Ion-Bernstein wave (IBW) can be generated by mode conversion of a fast magnetosonic wave incident from the high-field side on the second harmonic resonance of a minority hydrogen component, with near 100% efficiency. IBWs have the recognized capacity to create internal transport barriers through sheared plasma flows resulting from ion absorption. The relatively high frequency (around 200 MHz) minimizes parasitic electron absorption and permits the converted IBW to approach the 5th tritium harmonic. It also facilitates compact antennas and feeds, and efficient fast wave launch. The scheme is applicable to reactors with aspect ratios < 3 such that the conversion and absorption layers are both on the high field side of the magnetic axis. Large machine size and adequate separation of the mode conversion layer from the magnetic axis minimize poloidal field effects in the conversion zone and permit a 1-D full-wave analysis. 2-D ray tracing of the IBW indicates a slightly bean-shaped equilibrium allows access to the tritium resonance

Vanadium alloy membranes for high hydrogen permeability and suppressed hydrogen embrittlement

International Nuclear Information System (INIS)

Kim, Kwang Hee; Park, Hyeon Cheol; Lee, Jaeho; Cho, Eunseog; Lee, Sang Mock

2013-01-01

The structural properties and hydrogen permeation characteristics of ternary vanadium–iron–aluminum (V–Fe–Al) alloy were investigated. To achieve not only high hydrogen permeability but also strong resistance to hydrogen embrittlement, the alloy composition was modulated to show high hydrogen diffusivity but reduced hydrogen solubility. We demonstrated that matching the lattice constant to the value of pure V by co-alloying lattice-contracting and lattice-expanding elements was quite effective in maintaining high hydrogen diffusivity of pure V