Search for Rayleigh-Taylor instability in laser irradiated layered thin foil targets

International Nuclear Information System (INIS)

Kilkenny, J.D.; Hares, J.D.; Rumsby, P.T.

1980-01-01

An experiment to measure the Rayleigh-Taylor instability at the vacuum-ablation surface of laser irradiated layered targets by time resolved x-ray spectroscopy is described. The time taken to burn through a layer of material is measured to be the same for massive targets as for thin foil accelerating targets. It is inferred that the thin foil targets might be Rayleigh-Taylor stable despite the values of γtauapproximately equal to15 calculated from classical theory. (author)

Fabrication of free-standing copper foils covered with highly-ordered copper nanowire arrays

Science.gov (United States)

Zaraska, Leszek; Sulka, Grzegorz D.; Jaskuła, Marian

2012-07-01

The through-hole nanoporous anodic aluminum oxide (AAO) membranes with relatively large surface area (ca. 2 cm2) were employed for fabrication of free-standing and mechanically stable copper foils covered with close-packed and highly-ordered copper nanowire arrays. The home-made AAO membranes with different pore diameters and interpore distances were fabricated via a two-step self-organized anodization of aluminum performed in sulfuric acid, oxalic acid and phosphoric acid followed by the pore opening/widening procedure. The direct current (DC) electrodeposition of copper was performed efficiently on both sides of AAO templates. The bottom side of the AAO templates was not insulated and consequently Cu nanowire arrays on thick Cu layers were obtained. The proposed template-assisted fabrication of free-standing copper nanowire array electrodes is a promising method for synthesis of nanostructured current collectors. The composition of Cu nanowires was confirmed by energy dispersive X-Ray spectroscopy (EDS) and X-ray diffraction (XRD) analyses. The structural features of nanowires were evaluated from field emission scanning electron microscopy (FE-SEM) images and compared with the characteristic parameters of anodic alumina membranes.

Fabrication of free-standing copper foils covered with highly-ordered copper nanowire arrays

International Nuclear Information System (INIS)

Zaraska, Leszek; Sulka, Grzegorz D.; Jaskuła, Marian

2012-01-01

The through-hole nanoporous anodic aluminum oxide (AAO) membranes with relatively large surface area (ca. 2 cm 2 ) were employed for fabrication of free-standing and mechanically stable copper foils covered with close-packed and highly-ordered copper nanowire arrays. The home-made AAO membranes with different pore diameters and interpore distances were fabricated via a two-step self-organized anodization of aluminum performed in sulfuric acid, oxalic acid and phosphoric acid followed by the pore opening/widening procedure. The direct current (DC) electrodeposition of copper was performed efficiently on both sides of AAO templates. The bottom side of the AAO templates was not insulated and consequently Cu nanowire arrays on thick Cu layers were obtained. The proposed template-assisted fabrication of free-standing copper nanowire array electrodes is a promising method for synthesis of nanostructured current collectors. The composition of Cu nanowires was confirmed by energy dispersive X-Ray spectroscopy (EDS) and X-ray diffraction (XRD) analyses. The structural features of nanowires were evaluated from field emission scanning electron microscopy (FE-SEM) images and compared with the characteristic parameters of anodic alumina membranes.

Solid state impact welding of BMG and copper by vaporizing foil actuator welding

Energy Technology Data Exchange (ETDEWEB)

Vivek, Anupam, E-mail: vivek.4@osu.edu [Department of Materials Science and Engineering, The Ohio State University, 2041 College Road, Columbus, OH 43210 (United States); Presley, Michael [Department of Materials Science and Engineering, The Ohio State University, 2041 College Road, Columbus, OH 43210 (United States); Flores, Katharine M. [Department of Materials Science and Engineering, The Ohio State University, 2041 College Road, Columbus, OH 43210 (United States); Department of Mechanical Engineering and Materials Science, Institute of Materials Science and Engineering, Washington University, One Brookings Drive, St. Louis, MO 63130 (United States); Hutchinson, Nicholas H.; Daehn, Glenn S. [Department of Materials Science and Engineering, The Ohio State University, 2041 College Road, Columbus, OH 43210 (United States)

2015-05-14

The objective of this study was to create impact welds between a Zr-based Bulk Metallic Glass (BMG) and copper at a laboratory scale and subsequently investigate the relationship between interfacial structure and mechanical properties. Vaporizing Foil Actuator (VFA) has recently been demonstrated as a versatile tool for metalworking applications: impact welding of dissimilar materials being one of them. Its implementation for welding is termed as VFA Welding or VFAW. With 8 kJ input energy into an aluminum foil actuator, a 0.5 mm thick Cu110 alloy sheet was launched toward a BMG target resulting in an impact at a velocity of nearly 600 m/s. For this experiment, the welded interface was straight with a few BMG fragments embedded in the copper sheet in some regions. Hardness tests across the interface showed increase in strength on the copper side. Instrumented peel test resulted in failure in the parent copper sheet. A slower impact velocity during a separate experiment resulted in a weld, which had wavy regions along the interface and in peel failure again happened in the parent copper sheet. Some through-thickness cracks were observed in the BMG plate and there was some spall damage in the copper flyers. TEM electron diffraction on a sample, cut out from the wavy weld interface region using a focused ion beam, showed that devitrification of the BMG was completely avoided in this welding process.

The transmission of fast molecular ions through thin foils

International Nuclear Information System (INIS)

Pietsch, W.J.; Gemmell, D.S.; Cooney, P.J.; Kanter, E.P.; Kurath, D.; Ratkowski, A.J.; Vager, Z.; Zabransky, B.J.

1980-01-01

We present new results on the transmission of fast molecular ions through thin foils and propose a mechanism for the transmission process. The main feature of the postulated mechanism is that a finite fraction of the incident molecular beam does not undergo a strong Coulomb explosion while traversing the foil. Because the emerging fragments are at large internuclear separations, there is an enhanced probability for the formation of bound, long-range, excited electronic states following electron capture at the rear surface of the target. (orig.)

Acceleration{endash}deceleration process of thin foils confined in water and submitted to laser driven shocks

Energy Technology Data Exchange (ETDEWEB)

Romain, J.P.; Auroux, E. [Laboratoire de Combustion et de Detonique (UPR 9028 CNRS), ENSMA, BP 109, Teleport 2, Chasseneuil du Poitou, 86960 Futuroscope Cedex (France)

1997-08-01

An experimental, numerical, and analytical study of the acceleration and deceleration process of thin metallic foils immersed in water and submitted to laser driven shocks is presented. Aluminum and copper foils of 20 to 120 {mu}m thickness, confined on both sides by water, have been irradiated at 1.06 {mu}m wavelength by laser pulses of {approximately}20ns duration, {approximately}17J energy, and {approximately}4GW/cm{sup 2} incident intensity. Time resolved velocity measurements have been made, using an electromagnetic velocity gauge. The recorded velocity profiles reveal an acceleration{endash}deceleration process, with a peak velocity up to 650 m/s. Predicted profiles from numerical simulations reproduce all experimental features, such as wave reverberations, rate of increase and decrease of velocity, peak velocity, effects of nature, and thickness of the foils. A shock pressure of about 2.5 GPa is inferred from the velocity measurements. Experimental points on the evolution of plasma pressure are derived from the measurements of peak velocities. An analytical description of the acceleration{endash}deceleration process, involving multiple shock and release waves reflecting on both sides of the foils, is presented. The space{endash}time diagrams of waves propagation and the successive pressure{endash}particle velocity states are determined, from which theoretical velocity profiles are constructed. All characteristics of experimental records and numerical simulations are well reproduced. The role of foil nature and thickness, in relation with the shock impedance of the materials, appears explicitly. {copyright} {ital 1997 American Institute of Physics.}

X-ray scattering measurements from thin-foil x-ray mirrors

DEFF Research Database (Denmark)

Christensen, Finn Erland; BYRNAK, BP; Hornstrup, Allan

1992-01-01

Thin foil X-ray mirrors are to be used as the reflecting elements in the telescopes of the X-ray satellites Spectrum-X-Gamma (SRG) and ASTRO-D. High resolution X-ray scattering measurements from the Au coated and dip-lacquered Al foils are presented. These were obtained from SRG mirrors positioned...... in a test quadrant of the telescope structure and from ASTRO-D foils held in a simple fixture. The X-ray data is compared with laser data and other surface structure data such as STM, atomic force microscopy (AFM), TEM, and electron micrography. The data obtained at Cu K-alpha(1), (8.05 keV) from all...

Development of highly faceted reduced graphene oxide-coated copper oxide and copper nanoparticles on a copper foil surface

Directory of Open Access Journals (Sweden)

Rebeca Ortega-Amaya

2016-07-01

Full Text Available This work describes the formation of reduced graphene oxide-coated copper oxide and copper nanoparticles (rGO-Cu2ONPs, rGO-CuNPs on the surface of a copper foil supporting graphene oxide (GO at annealing temperatures of 200–1000 °C, under an Ar atmosphere. These hybrid nanostructures were developed from bare copper oxide nanoparticles which grew at an annealing temperature of 80 °C under nitrogen flux. The predominant phase as well as the particle size and shape strongly depend on the process temperature. Characterization with transmission electron microscopy and scanning electron microscopy indicates that Cu or Cu2O nanoparticles take rGO sheets from the rGO network to form core–shell Cu–rGO or Cu2O–rGO nanostructures. It is noted that such ones increase in size from 5 to 800 nm as the annealing temperature increases in the 200–1000 °C range. At 1000 °C, Cu nanoparticles develop a highly faceted morphology, displaying arm-like carbon nanorods that originate from different facets of the copper crystal structure.

Resonance effects of transition radiation emitted from thin foil stacks using electron beam

Energy Technology Data Exchange (ETDEWEB)

Awata, Takaaki; Yajima, Kazuaki; Tanaka, Takashi [Kyoto Univ. (Japan). Faculty of Engineering; and others

1997-03-01

Transition Radiation(TR) X rays are expected to be a high brilliant X-ray source because the interference among TR X rays emitted from many thin foils placed periodically in vacuum can increase their intensity and make them quasi-monochromatic. In order to study the interference (resonance) effects of TR, we measured the energy spectra of TR for several sets of thin-foil stacks at various emission angles. It was found that the resonance effects of TR are classified into intrafoil and interfoil resonances and the intensity of TR X rays increases nonlinearly with increasing foil number, attributing to the interfoil resonance. It became evident that the brilliance of TR is as high as that of SR. (author)

Determination of low-energy ion-induced electron yields from thin carbon foils

International Nuclear Information System (INIS)

Allegrini, Frederic; Wimmer-Schweingruber, Robert F.; Wurz, Peter; Bochsler, Peter

2003-01-01

Ion beams crossing thin carbon foils can cause electron emission from the entrance and exit surface. Thin carbon foils are used in various types of time-of-flight (TOF) mass spectrometers to produce start pulses for TOF measurements. The yield of emitted electrons depends, among other parameters, on the energy of the incoming ion and its mass, and it has been experimentally determined for a few projectile elements. The electron emission yield is of great importance for deriving abundance ratios of elements and isotopes in space plasmas using TOF mass spectrometers. We have developed a detector for measuring ion-induced electron yields, and we have extended the electron yield measurements for oxygen to energies relevant for solar wind research. We also present first measurements of the carbon foil electron emission yield for argon and iron in the solar wind energy range

Interaction of relativistic H- ions with thin foils

International Nuclear Information System (INIS)

Mohagheghi, A.H.

1990-09-01

The response of relativistic H - ions to thin carbon foils was investigated for beam energies ranging from 226 MeV to 800 MeV. For the foil thicknesses we have studied, ranging from 15 to 300 μg/cm 2 , an appreciable fraction of the H - beam survives intact, some H - ions are stripped down to protons, and the remainder is distributed over the states of H 0 . This experiment is different from the low energy studies in that the projectile velocity is comparable to the speed of light, leading to an interaction time of typically less than a femtosecond. The present results challenge the theoretical understanding of the interaction mechanisms. An electron spectrometer was used to selectively field-ionize the Rydberg states, 9 < n < 17, at beam energies of 581 MeV and 800 MeV. The yield of low-lying states were measured by Doppler tuning a Nd:YAG laser to excite transitions to a Rydberg state which was then field-ionized and detected. A simple model is developed to fit the yield of each state as a function of foil thickness. The simple model is successful in predicting the general features of the yield data. However, the data are suggestive of a more complex structure in the yield curves. The yield of a given state depends strongly on the foil thickness, demonstrating that the excited states are formed during the passage of the ions through a foil. The optimum thickness to produce a given state increases with the principal quantum number of the state suggesting an excitation process which is at least pratially stepwise. The results of a Monte Carlo simulation are compared with the experimental data to estimate the distribution of the excited states coming out of a foil. The distributions of the excited states and their dependence on foil thickness are discussed

Thin foil expansion into a vacuum

International Nuclear Information System (INIS)

Mora, P.

2005-01-01

Plasma expansion into a vacuum is an old problem which has been renewed recently in various contexts: expansion of ultra-cold plasmas, cluster expansion, of dust grains, expansion of thin foils. In this presentation I will first discuss the physics of the expansion of a thin foil irradiated by an ultra-short ultra-intense laser pulse. The expansion results in the formation of high energy ions. For an infinitely steep plasma-vacuum interface the fastest ions are located in the outer part of the expansion and their velocity is given by ν m ax∼ 2 C s (In ω p it) where c s (Zk B T e /m i )''1/2 is the ion-acoustic velocity ω p i=(n e 0Ze''2/m i e 0 )''1/2 is the ion plasma frequency, n e 0 is the electron density in the unperturbed plasma, Z is the ion charge number. In the above expression, t is either the pulse duration or the effective acceleration time (in particular t∼L/2c s , where L is the width of the foil, when the electron cooling is taken into account). A salient characteristic of the expansion is the occurrence of a double layer structure and a peak of the accelerating electric field at the ion front. I will explain the origin of the peak and predict its temporal behavior. This peak has been diagnosed in recent experiments. I will also discuss the effect of a 2-temperatures electron distribution function on the expansion, showing the dominant role of the hot electron component. Finally I will discuss the occurrence of ion spikes in the expansion when the initial density profile is smooth. The ion spike is due to a wave breaking which cannot be handled in a satisfactory way by a fluid code and requires a kinetic description. A. simple collisionless particle code has been used to treat the evolution of the spike after the wave breaking and the results will be shown. (Author)

Monte Carlo simulation of positron induced secondary electrons in thin carbon foils

International Nuclear Information System (INIS)

Cai, L H; Yang, B; Ling, C C; Beling, C D; Fung, S

2011-01-01

Emission of secondary electrons induced by the passage of low energy positrons through thin carbon foils was studied by the Monte Carlo method. The positron and electron elastic cross sections were calculated by partial wave analysis. The inelastic positron-valence-electron was described by the energy loss function obtained from dielectric theory. The positron-core-electron interaction was modelled by the Gryzinski's excitation function. Positron transport inside the carbon foil was simulated in detail. Secondary electrons created by positrons and high energy secondary electrons through inelastic interactions were tracked through the foil. The positron transmission coefficient and secondary electron yielded in forward and backward geometry are calculated and dependences on positron energy and carbon foil thickness are discussed.

Thin silicon foils produced by epoxy-induced spalling of silicon for high efficiency solar cells

Energy Technology Data Exchange (ETDEWEB)

Martini, R., E-mail: roberto.martini@imec.be [Department of Electrical Engineering, KU Leuven, Kasteelpark 10, 3001 Leuven (Belgium); imec, Kapeldreef 75, 3001 Leuven (Belgium); Kepa, J.; Stesmans, A. [Department of Physics, KU Leuven, Celestijnenlaan 200 D, 3001 Leuven (Belgium); Debucquoy, M.; Depauw, V.; Gonzalez, M.; Gordon, I. [imec, Kapeldreef 75, 3001 Leuven (Belgium); Poortmans, J. [Department of Electrical Engineering, KU Leuven, Kasteelpark 10, 3001 Leuven (Belgium); imec, Kapeldreef 75, 3001 Leuven (Belgium); Universiteit Hasselt, Martelarenlaan 42, B-3500 Hasselt (Belgium)

2014-10-27

We report on the drastic improvement of the quality of thin silicon foils produced by epoxy-induced spalling. In the past, researchers have proposed to fabricate silicon foils by spalling silicon substrates with different stress-inducing materials to manufacture thin silicon solar cells. However, the reported values of effective minority carrier lifetime of the fabricated foils remained always limited to ∼100 μs or below. In this work, we investigate epoxy-induced exfoliated foils by electron spin resonance to analyze the limiting factors of the minority carrier lifetime. These measurements highlight the presence of disordered dangling bonds and dislocation-like defects generated by the exfoliation process. A solution to remove these defects compatible with the process flow to fabricate solar cells is proposed. After etching off less than 1 μm of material, the lifetime of the foil increases by more than a factor of 4.5, reaching a value of 461 μs. This corresponds to a lower limit of the diffusion length of more than 7 times the foil thickness. Regions with different lifetime correlate well with the roughness of the crack surface which suggests that the lifetime is now limited by the quality of the passivation of rough surfaces. The reported values of the minority carrier lifetime show a potential for high efficiency (>22%) thin silicon solar cells.

Thin silicon foils produced by epoxy-induced spalling of silicon for high efficiency solar cells

International Nuclear Information System (INIS)

Martini, R.; Kepa, J.; Stesmans, A.; Debucquoy, M.; Depauw, V.; Gonzalez, M.; Gordon, I.; Poortmans, J.

2014-01-01

We report on the drastic improvement of the quality of thin silicon foils produced by epoxy-induced spalling. In the past, researchers have proposed to fabricate silicon foils by spalling silicon substrates with different stress-inducing materials to manufacture thin silicon solar cells. However, the reported values of effective minority carrier lifetime of the fabricated foils remained always limited to ∼100 μs or below. In this work, we investigate epoxy-induced exfoliated foils by electron spin resonance to analyze the limiting factors of the minority carrier lifetime. These measurements highlight the presence of disordered dangling bonds and dislocation-like defects generated by the exfoliation process. A solution to remove these defects compatible with the process flow to fabricate solar cells is proposed. After etching off less than 1 μm of material, the lifetime of the foil increases by more than a factor of 4.5, reaching a value of 461 μs. This corresponds to a lower limit of the diffusion length of more than 7 times the foil thickness. Regions with different lifetime correlate well with the roughness of the crack surface which suggests that the lifetime is now limited by the quality of the passivation of rough surfaces. The reported values of the minority carrier lifetime show a potential for high efficiency (>22%) thin silicon solar cells.

Electronic excitation in transmission of relativistic H- ions through thin foils

International Nuclear Information System (INIS)

Reinhold, C.O.; Kuerpick, P.; Burgdoerfer, J.; Yoshida, S.

1998-01-01

The authors describe a theoretical model to study the transmission of relativistic H - ions through thin carbon foils. The approach is based on a Monte Carlo solution of the Langevin equation describing electronic excitations of the atoms during the transport through the foil. Calculations for the subshell populations of outgoing hydrogen atoms are found to be in good agreement with recent experimental data on an absolute scale and show that there exists a propensity for populating extreme Stark states

Comparison between bulk and thin foil ion irradiation of ultra high purity Fe

Energy Technology Data Exchange (ETDEWEB)

Prokhodtseva, A., E-mail: anna.prokhodtseva@psi.ch [Ecole Polytechnique Fédérale de Lausanne (EPFL), Centre de Recherches en Physique des Plasmas, Association Euratom-Confédération Suisse, 5232 Villigen PSI (Switzerland); Décamps, B. [Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), CNRS-IN2P3-Univ. Paris-Sud 11, UMR 8609, Bât. 108, 91405 Orsay (France); Schäublin, R. [Ecole Polytechnique Fédérale de Lausanne (EPFL), Centre de Recherches en Physique des Plasmas, Association Euratom-Confédération Suisse, 5232 Villigen PSI (Switzerland)

2013-11-15

Accumulation of radiation damage in ultra high purity iron under self ion irradiation without and with simultaneous He implantation was investigated in bulk and thin foil form to assess, on the one hand, the effect of free surfaces and, on the other hand, the influence of He. Specimens were irradiated at room temperature to a dose of 0.8 dpa and ∼900 appm He content. We found in thin foils after irradiation with single beam a majority of a{sub 0} 〈1 0 0〉 type loops, while in the presence of He it is the ½ a{sub 0} 〈1 1 1〉 type loops that prevail. In single beam irradiated bulk samples most of the loops are of ½ a{sub 0} 〈1 1 1〉 type. In both bulk and thin foils density of defects visible in transmission electron microscope is considerably higher when He is implanted with prevailing ½ a{sub 0} 〈1 1 1〉 dislocation loops, indicating that He stabilizes them.

Method of stabilizing Nb3Sn superconducting foils

International Nuclear Information System (INIS)

Kruzliak, J.; Lences, P.; Allarova, H.

1982-01-01

The stabilization of niobium-tin Nb 3 Sn superconducting foils with copper is carried out by deposition or by diffusion in pure copper or in a tin bath containing different copper levels, with the surface etched or unetched. The foils are covered with a copper film at a temperature of 300 to 5O0 degC using a tin solder, spread on a copper, silver or nickel layer deposited on the foil surface from solutions for electroless plating. The bond between the surface of the superconducting foil and the electroless plated metal layer is annealed in a controlled atmosphere or in a vacuum at a temperature of 200 to 500 degC for over 20 to 60 minutes. The copper stabilization layer can also be produced electrolytically. (J.B.)

The effects of deoxidation practice on the quality of thin foil low-carbon steel

Directory of Open Access Journals (Sweden)

Pereira Batista R.

2017-01-01

Full Text Available In converter steelmaking of AISI 1006 steel for thin foil products, two tapping practices are used with respect to deoxidation: silicon and manganese additions during tapping and aluminum deoxidation after complete tapping (“semikilled practice” and aluminum deoxidation during tapping, “fully killed practice”. There is a perception that the semikilled practice may be more economical and result in the same quality as the fully killed practice. In this work, the effects of the tapping practice on steel quality and cost variables were evaluated for thin foils of AISI 1006 steel. Oxygen and aluminum content, aluminum and ferro-alloy yield, the type of alumina inclusions formed, and the quality of the steel during thin foil rolling were evaluated and compared. It is shown that the fully killed practice leads to less reoxidation from slag, lower soluble oxygen, and lower total oxygen at the caster as well as better morphology of the remaining alumina inclusions than the semi-killed practice. Thus, the higher quality of the steel produced via the fully killed tapping deoxidation practice when compared with semi-killed tapping is demonstrated. It is also shown that a complete cost evaluation favors this practice in the case of products rolled for tin foil production.

Piezoelectric characterization of Pb(Zr,Ti)O3 thin films deposited on metal foil substrates by dip coating

Science.gov (United States)

Hida, Hirotaka; Hamamura, Tomohiro; Nishi, Takahito; Tan, Goon; Umegaki, Toshihito; Kanno, Isaku

2017-10-01

We fabricated the piezoelectric bimorphs composed of Pb(Zr,Ti)O3 (PZT) thin films on metal foil substrates. To efficiently inexpensively manufacture piezoelectric bimorphs with high flexibility, 1.2-µm-thick PZT thin films were directly deposited on both surfaces of 10- and 20-µm-thick bare stainless-steel (SS) foil substrates by dip coating with a sol-gel solution. We confirmed that the PZT thin films deposited on the SS foil substrates at 500 °C or above have polycrystalline perovskite structures and the measured relative dielectric constant and dielectric loss were 323-420 and 0.12-0.17, respectively. The PZT bimorphs were demonstrated by comparing the displacements of the cantilever specimens driven by single- and double-side PZT thin films on the SS foil substrates under the same applied voltage. We characterized the piezoelectric properties of the PZT bimorphs and the calculated their piezoelectric coefficient |e 31,f| to be 0.3-0.7 C/m2.

Interaction of positron beams with thin silver foils and surfaces

International Nuclear Information System (INIS)

Rysholt Poulsen, M.

1994-01-01

Experimental investigations of positron interactions with solid silver and the necessary platform to analyse the data have been presented. The main objective was to study Ps formation at a Ag(100) surface. The different ingredients of the scenario, including thermalization and diffusion of positrons and emission of Ps, were analysed and quantified in whatever way appropriate. The scattering and possible thermalization were described. The parametrization of Monte-Carlo simulated implantation profiles for semi-infinite materials were presented and the applicability of such profiles to thin foils assessed. The latter was done in conjunction with an analysis of experimental data on thermalization and diffusion in 1900 Aa Ag(100) foils. The necessity for MC simulated rather than parametrized implantation profiles was argued. The velocity of thermally desorbed Ps from a Ag(100) surface at ∼800 K appeared to obey and one-dimensional Maxwell Boltzmann distribution multiplied by a velocity dependent factor. More experimental investigations are needed before firm conclusions can be made on the nature of the emission process. The velocity distribution, though, was found to be near-thermal and indicative of the sample temperature. It has been shown that positrons can be converted into Ps atoms in the transmission geometry of a thin 1900 Aa Ag(100) foil with a high efficiency. Furthermore, 61% of the emitted Ps will have a mean velocity of v z =1.2x10 5 m/sec and 39% will have a maximum kinetic energy of 1.5 eV (v z =5.1x10 5 m/sec) at a foil temperature of 800 K, all velocities that are suitable for producing a 'dense' Ps gas target. (EG) 12 refs

Plastic deformation mechanism of polycrystalline copper foil shocked with femtosecond laser

International Nuclear Information System (INIS)

Ye, Y.X.; Feng, Y.Y.; Lian, Z.C.; Hua, Y.Q.

2014-01-01

Plastic deformation mechanism of polycrystalline copper foil shocked with femtosecond (fs) laser has been characterized through optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Experiments of ns laser shocking copper (Cu) and fs laser shocking aluminum (Al) were also conducted for comparison. Dislocations arranged in multiple forms, profuse twins and stacking faults (SFs) coexist in the fs laser shocked copper. At small strain condition, dislocation slip is the dominant deformation mode and small amount of SFs act as complementary mechanism. With strain increasing, profuse twins and SFs form to accommodate the plastic deformation. Furthermore, new formed SFs incline to locate around the old ones because the dislocation densities there are more higher. So there is a high probability for new SFs overlapping on old ones to form twins, or connecting old ones to lengthen them, which eventually produce the phenomena that twins connect with each other or twins connect with SFs. Strain greatly influences the dislocation density. Twins and SFs are more dependent on strain rate and shock pressure. Medium stacking fault energy (SFE) of copper helps to extend partial dislocations and provides sources for forming SFs and twins.

Tungsten foil laminate for structural divertor applications - Joining of tungsten foils

Science.gov (United States)

Reiser, Jens; Rieth, Michael; Möslang, Anton; Dafferner, Bernhard; Hoffmann, Jan; Mrotzek, Tobias; Hoffmann, Andreas; Armstrong, D. E. J.; Yi, Xiaoou

2013-05-01

This paper is the fourth in our series on tungsten laminates. The aim of this paper is to discuss laminate synthesis, meaning the joining of tungsten foils. It is obvious that the properties of the tungsten laminate strongly depend on the combination of (i) interlayer and (ii) joining technology, as this combination defines (i) the condition of the tungsten foil after joining (as-received or recrystallised) as well as (ii) the characteristics of the interface between the tungsten foil and the interlayer (wettability or diffusion leading to a solid solution or the formation of intermetallics). From the example of tungsten laminates joined by brazing with (i) an eutectic silver copper brazing filler, (ii) copper, (iii) titanium, and (iv) zirconium, the microstructure will be discussed, with special focus on the interface. Based on our assumptions of the mechanism of the extraordinary ductility of tungsten foil we present three syntheses strategies and make recommendations for the synthesis of high temperature tungsten laminates.

A novel application of the CuI thin film for preparing thin copper nanowires

International Nuclear Information System (INIS)

Shi Shuo; Sun Jialin; Zhang Jianhong; Cao Yang

2005-01-01

We present a novel application of the CuI thin film for preparing thin copper nanowires under a direct current electric field (DCEF). The CuI thin film was used as a medium for transmitting cuprous ions during the growing process of copper nanowires. As electrodes are the source of cuprous ions, high-purity copper films were deposited on both ends of the CuI thin film. At 353 K, under whole solid condition, without any templates, and having applied a DCEF of 1.5x10 4 V/m, cuprous ions were generated at the anode and migrated towards the cathode through the CuI film. At the edge of the cathode, cuprous ions obtained electrons and congregated to form a disordered thin copper nanowires bundle. The SEM images showed that these copper nanowires were from 10 to 20 nm in diameter and several hundred nanometers in length. The effect of the electric field intensity and the growth temperature on the diameter of the nanowires was also studied

Monte Carlo transport of electrons and positrons through thin foils

International Nuclear Information System (INIS)

Legarda, F.; Idoeta, R.

2000-01-01

In the different measurements made with electrons traversing matter it becomes useful the knowledge of its transmission through that medium, their paths and their angular distribution through matter so as to process and get information about the traversed medium and to improve and innovate the techniques that employ electrons, as medical applications or materials irradiation. This work presents a simulation of the transport of beams of electrons and positrons through thin foils using an analog Monte Carlo code that simulates in a detailed way every electron movement or interaction in matter. As those particles penetrate thin absorbers it has been assumed that they interact with matter only through elastic scattering, with negligible energy loss. This type of interaction has been described quite precisely because its angular form influences very much the angular distribution of electrons and positrons in matter. With this code it has been calculated the number of particles, with energies between 100 and 3000 keV, that are transmitted through different media of various thicknesses as well as its angular distribution, showing a good agreement with experimental data. The discrepancies are less than 5% for thicknesses lower than about 30% of the corresponding range in the tested material. As elastic scattering is very anisotropic, angular distributions resemble a collimated incident beam for very thin foils becoming slowly more isotropic when absorber thickness is increased. (author)

Tungsten foil laminate for structural divertor applications – Joining of tungsten foils

Energy Technology Data Exchange (ETDEWEB)

Reiser, Jens, E-mail: jens.reiser@kit.edu [Karlsruhe Institute of Technology (KIT), Institute for Applied Materials (IAM-AWP) (Germany); Rieth, Michael; Möslang, Anton; Dafferner, Bernhard; Hoffmann, Jan [Karlsruhe Institute of Technology (KIT), Institute for Applied Materials (IAM-AWP) (Germany); Mrotzek, Tobias; Hoffmann, Andreas [PLANSEE SE, Reutte (Austria); Armstrong, D.E.J.; Yi, Xiaoou [University of Oxford, Department of Materials (United Kingdom)

2013-05-15

This paper is the fourth in our series on tungsten laminates. The aim of this paper is to discuss laminate synthesis, meaning the joining of tungsten foils. It is obvious that the properties of the tungsten laminate strongly depend on the combination of (i) interlayer and (ii) joining technology, as this combination defines (i) the condition of the tungsten foil after joining (as-received or recrystallised) as well as (ii) the characteristics of the interface between the tungsten foil and the interlayer (wettability or diffusion leading to a solid solution or the formation of intermetallics). From the example of tungsten laminates joined by brazing with (i) an eutectic silver copper brazing filler, (ii) copper, (iii) titanium, and (iv) zirconium, the microstructure will be discussed, with special focus on the interface. Based on our assumptions of the mechanism of the extraordinary ductility of tungsten foil we present three syntheses strategies and make recommendations for the synthesis of high temperature tungsten laminates.

Development of surface perturbation target and thin silicon foil target used to research Rayleigh-Taylor instability in inertial confinement fusion experiment

International Nuclear Information System (INIS)

Zhou Bin; Sun Qi; Huang Yaodong; Shen Jun; Wu Guangming; Wang Jue

2004-01-01

The developments of the surface perturbation target and the thin silicon foil target used to research Rayleigh-Taylor instability in the resolved experiments of Inertial Confinement Fusion (ICF) are carried out. Based on the laser interference process combined with the figure-transfer process, the surface perturbation target with sine modulated perturbation is gotten, the wavelength is in the range of 20-100 μm and the amplitude is several micrometers. The thin silicon foil within the thickness about 3-4 μm is prepared by semiconductor process together with heavy-doped self-stop etching. Combined with ion beam etching, the check or the stripe patterns are transferred to the surface of thin silicon foils, and then the silicon grating foil is obtained

Room temperature thin foil SLIM-cut using an epoxy paste: experimental versus theoretical results

International Nuclear Information System (INIS)

Bellanger, Pierre; Serra, Joao; Bouchard, Pierre-Olivier; Bernacki, Marc

2015-01-01

The stress induced lift-off method (SLIM) -cut technique allows the detachment of thin silicon foils using a stress inducing layer. In this work, results of SLIM-cut foils obtained using an epoxy stress inducing layer at room temperature are presented. Numerical analyses were performed in order to study and ascertain the important experimental parameters. The experimental and simulation results are in good agreement. Indeed, large area (5 × 5 cm 2 ) foils were successfully detached at room temperature using an epoxy thickness of 900 μm and a curing temperature of 150 °C. Moreover, three foils (5 × 3 cm 2 ) with thickness 135, 121 and 110 μm were detached from the same monocrystalline substrate. Effective minority carrier lifetimes of 46, 25 and 20 μs were measured using quasi-steady-state photoconductance technique in these foils after iodine ethanol surface passivation. (paper)

Measurement of the thickness and homogeneity of thin foils by slowing down alpha particles

International Nuclear Information System (INIS)

Bimbot, R.; Della Negra, S.; Deprun, C.; Gardes, D.; Rivet, M.F.

1979-01-01

The energy loss of 8.785 MeV α particles passing through a thin foil is used to measure the foil thickness. The measurement is performed in various points of the target, the abscissa and ordinate of which are set with precision from the outside of the chamber. This gives a thickness map of the target. The working up of the data, and the use of energy loss tables are made in a standard way. The absolute uncertainty is of some percent for 100 μg/cm 2 foils. The technique has been refined to reach the same precision for 10 μg/cm 2 targets [fr

In situ observations of crack arrest and bridging by nanoscale twins in copper thin films

International Nuclear Information System (INIS)

Kim, Seong-Woong; Li Xiaoyan; Gao Huajian; Kumar, Sharvan

2012-01-01

In situ tensile experiments in a transmission electron microscope revealed that micro-cracks in ultrafine grained, free-standing, thin copper foils containing nanoscale twins initiated in matrix domains separated by the twins and then arrested at twin boundaries as twin boundary sliding proceeded. The adjacent microcracks eventually coalesced through shear failure of the bridging twins. To investigate the atomic mechanism of this rarely seen nanoscale crack bridging behavior, molecular dynamics simulations were performed to show that during crack propagation twin boundaries are impinged upon by numerous dislocations from the plastically deforming matrix. These dislocations react at the interface and evolve into substantially impenetrable dislocation walls that strongly confine crack nucleation and resist crack propagation, leading to the experimentally observed crack bridging behavior. The present results raise an approach to significantly toughening polycrystalline thin films by incorporating nanoscale twin structures into individual grains that serve as crack bridging ligaments.

Influence of copper foil polycrystalline structure on graphene anisotropic etching

Energy Technology Data Exchange (ETDEWEB)

Sharma, Kamal P. [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Mahyavanshi, Rakesh D. [Department of Physical Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Kalita, Golap, E-mail: kalita.golap@nitech.ac.jp [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Department of Physical Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Tanemura, Masaki [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Department of Physical Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan)

2017-01-30

Graphical abstract: Hexagonal hole formation with anisotropic etching independent of the stripes and wrinkles in the synthesized graphene. We also observed variation in etched pattern of the graphene depending on the base Cu grain orientations, attributing to difference in nucleation and growth process. - Highlights: • Reveal the influence of copper polycrystalline structure on anisotropic etching of graphene. • Hexagonal hole formation with etching is observed to be independent of stripes and wrinkles in graphene. • Variation in etched pattern of graphene depending on the base Cu grain is confirmed. • This finding will help to understand the nature of microscopic etched pattern in graphene. - Abstract: Anisotropic etching of graphene and other two dimensional materials is an important tool to understand the growth process as well as enabling fabrication of various well-defined structures. Here, we reveal the influence of copper foil polycrystalline structure on anisotropic etching process of as-synthesized graphene. Graphene crystals were synthesized on the polycrystalline Cu foil by a low-pressure chemical vapor deposition (LPCVD) system. Microscopic analysis shows difference in shape, size and stripes alignment of graphene crystals with dissimilar nucleation within closure vicinity of neighboring Cu grains. Post-growth etching of such graphene crystals also significantly affected by the crystallographic nature of Cu grains as observed by the field emission scanning electron microscope (FE-SEM) and electron back scattered diffraction (EBSD) analysis. Hexagonal hole formation with anisotropic etching is observed to be independent of the stripes and wrinkles in the synthesized graphene. We also observed variation in etched pattern of the graphene depending on the base Cu grain orientations, attributing to difference in nucleation and growth process. The findings can facilitate to understand the nature of microscopic etched pattern depending on metal

Influence of copper foil polycrystalline structure on graphene anisotropic etching

International Nuclear Information System (INIS)

Sharma, Kamal P.; Mahyavanshi, Rakesh D.; Kalita, Golap; Tanemura, Masaki

2017-01-01

Graphical abstract: Hexagonal hole formation with anisotropic etching independent of the stripes and wrinkles in the synthesized graphene. We also observed variation in etched pattern of the graphene depending on the base Cu grain orientations, attributing to difference in nucleation and growth process. - Highlights: • Reveal the influence of copper polycrystalline structure on anisotropic etching of graphene. • Hexagonal hole formation with etching is observed to be independent of stripes and wrinkles in graphene. • Variation in etched pattern of graphene depending on the base Cu grain is confirmed. • This finding will help to understand the nature of microscopic etched pattern in graphene. - Abstract: Anisotropic etching of graphene and other two dimensional materials is an important tool to understand the growth process as well as enabling fabrication of various well-defined structures. Here, we reveal the influence of copper foil polycrystalline structure on anisotropic etching process of as-synthesized graphene. Graphene crystals were synthesized on the polycrystalline Cu foil by a low-pressure chemical vapor deposition (LPCVD) system. Microscopic analysis shows difference in shape, size and stripes alignment of graphene crystals with dissimilar nucleation within closure vicinity of neighboring Cu grains. Post-growth etching of such graphene crystals also significantly affected by the crystallographic nature of Cu grains as observed by the field emission scanning electron microscope (FE-SEM) and electron back scattered diffraction (EBSD) analysis. Hexagonal hole formation with anisotropic etching is observed to be independent of the stripes and wrinkles in the synthesized graphene. We also observed variation in etched pattern of the graphene depending on the base Cu grain orientations, attributing to difference in nucleation and growth process. The findings can facilitate to understand the nature of microscopic etched pattern depending on metal

Study of graphene growth on copper foil by pulsed laser deposition at reduced temperature

Science.gov (United States)

Abd Elhamid, Abd Elhamid M.; Hafez, Mohamed A.; Aboulfotouh, Abdelnaser M.; Azzouz, Iftitan M.

2017-01-01

Graphene has been successfully grown on commercial copper foil at low temperature of 500 °C by pulsed laser deposition (PLD). X-ray diffraction patterns showed that films have been grown in the presence of Cu(111) and Cu(200) facets. Raman spectroscopy was utilized to study the effects of temperature, surface structure, and cooling rate on the graphene growth. Raman spectra indicate that the synthesis of graphene layers rely on the surface quality of the Cu substrate together with the proper cooling profile coupled with graphene growth temperature. PLD-grown graphene film on Cu has been verified by transmission electron microscopy. Surface mediated growth of graphene on Cu foil substrate revealed to have a favorable catalytic effect. High growth rate of graphene and less defects can be derived using fast cooling rate.

Characterization of laser-cut copper foil X-pinches

Science.gov (United States)

Collins, G. W.; Valenzuela, J. C.; Hansen, S. B.; Wei, M. S.; Reed, C. T.; Forsman, A. C.; Beg, F. N.

2016-10-01

Quantitative data analyses of laser-cut Cu foil X-pinch experiments on the 150 ns quarter-period, ˜250 kA GenASIS driver are presented. Three different foil designs are tested to determine the effects of initial structure on pinch outcome. Foil X-pinch data are also presented alongside the results from wire X-pinches with comparable mass. The X-ray flux and temporal profile of the emission from foil X-pinches differed significantly from that of wire X-pinches, with all emission from the foil X-pinches confined to a ˜3 ns period as opposed to the delayed, long-lasting electron beam emission common in wire X-pinches. Spectroscopic data show K-shell as well as significant L-shell emission from both foil and wire X-pinches. Fits to synthetic spectra using the SCRAM code suggest that pinching foil X's produced a ˜1 keV, ne ≥ 1023 cm-3 plasma. The spectral data combined with the improved reliability of the source timing, flux, and location indicate that foil X-pinches generate a reproducible, K-shell point-projection radiography source that can be easily modified and tailored to suit backlighting needs across a variety of applications.

Production of thin carbon stripper foils using heated-substrates in a cathodic arc deposition system

International Nuclear Information System (INIS)

Merchant, A.R.; Lobanov, N.; Elliman, R.G.; Ophel, T.R.; Rode, A.; Weisser, D.C.; Turkentine, R.B.

1998-01-01

The lifetime of carbon stripper foil can have a marked impact on the successful running of a beam line. Standard techniques for production of carbon stripper foils include evaporation of carbon (ec) and laser-pulsed ablation (Ipa). Recent work by a using Ipa has been successful in substantially increasing the lifetime of a very thin foil. The suspected mechanism for the increased lifetime of the foil is that the amorphous carbon foil is density-matched to that of graphite (around 2.26g/cc). In this work, we attempt to reproduce this result by producing carbon stripper foils with a mass-density similar to graphite using a cathodic arc deposition system. The cathodic arc is well known for the production of tetrahedral amorphous carbon: a high density, high stress form of carbon with over 90% sp 3 -like bonds; to reduce the density of the carbon and promote more graphitic structure, a high bias was initially attempted but this proved unsuccessful. Another method is to use a heated-substrate holder to reduce compressive stress within the deposited film. The performance of the density-matched carbon stripper foils and the implications for future production of high-quality carbon stripper foils in our laboratory will be discussed. (authors)

Laser Radiation Pressure Acceleration of Monoenergetic Protons in an Ultra-Thin Foil

Science.gov (United States)

Eliasson, Bengt; Liu, Chuan S.; Shao, Xi; Sagdeev, Roald Z.; Shukla, Padma K.

2009-11-01

We present theoretical and numerical studies of the acceleration of monoenergetic protons in a double layer formed by the laser irradiation of an ultra-thin film. The stability of the foil is investigated by direct Vlasov-Maxwell simulations for different sets of laser-plasma parameters. It is found that the foil is stable, due to the trapping of both electrons and ions in the thin laser-plasma interaction region, where the electrons are trapped in a potential well composed of the ponderomo-tive potential of the laser light and the electrostatic potential due to the ions, and the ions are trapped in a potential well composed of the inertial potential in an accelerated frame and the electrostatic potential due to the electrons. The result is a stable double layer, where the trapped ions are accelerated to monoenergetic energies up to 100 MeV and beyond, which makes them suitable for medical applications cancer treatment. The underlying physics of trapped and untapped ions in a double layer is also investigated theoretically and numerically.

Ablative acceleration of thin foil targets by intense proton beams

International Nuclear Information System (INIS)

Miyamoto, S.; Ozaki, T.; Imasaki, K.; Higaki, S.; Nakai, S.

1981-01-01

A focused proton beam of up to 2 x 10 10 w/cm 2 was obtained using pinch-reflex ion diode connected to Reiden IV generator. Experiments of beam target interaction have been done using thin foil targets. In this power range the interaction was explained classically. The experimental dependence of ablation pressure on proton beam intensity was obtained as P sub(a) = 3 x 10 -3 I sup(0.7) bar (I in w/cm 2 ). (author)

Hydrodynamic simulations of light ion beam-matter interactions: ablative acceleration of thin foils

International Nuclear Information System (INIS)

Devore, C.R.; Gardner, J.H.; Boris, J.P.; Mosher, D.

1984-01-01

A one-dimensional model is used to study the hydrodynamic response of thin foils to bombardment by an intense proton beam. The beam targets are single- and multilayer planar foils of gold and polystyrene. The main conclusion is that the efficiency of conversion of incident beam energy to directed kinetic energy of the target is maximized by using a multilayer design. For beam parameters associated with the Gamble II device at the Naval Research Laboratory, the simulations yield payload velocities of over 5 cm/μs and energy conversion efficiencies of over 30%. The implications of these results for inertial confinement fusion research are discussed. (author)

Silicon-Light: a European FP7 Project Aiming at High Efficiency Thin Film Silicon Solar Cells on Foil

DEFF Research Database (Denmark)

Soppe, W.; Haug, F.-J.; Couty, P.

2011-01-01

Silicon-Light is a European FP7 project, which started January 1st, 2010 and aims at development of low cost, high-efficiency thin film silicon solar cells on foil. Three main routes are explored to achieve these goals: a) advanced light trapping by implementing nanotexturization through UV Nano...... calculations of ideal nanotextures for light trapping in thin film silicon solar cells; the fabrication of masters and the replication and roll-to-roll fabrication of these nanotextures. Further, results on ITO variants with improved work function are presented. Finally, the status of cell fabrication on foils...

Advances in copper-chalcopyrite thin films for solar energy conversion

Energy Technology Data Exchange (ETDEWEB)

Kaneshiro, Jess; Gaillard, Nicolas; Rocheleau, Richard; Miller, Eric [Hawaii Natural Energy Institute, University of Hawaii at Manoa, 1680 East-West Road, Post 109, Honolulu, HI 96822 (United States)

2010-01-15

Promising alternatives to crystalline silicon as the basic building block of solar cells include copper-chalcopyrite thin films such as copper indium gallium diselenide, a class of thin films exhibiting bandgap-tunable semiconductor behavior, direct bandgaps and high absorption coefficients. These properties allow for the development of novel solar-energy conversion configurations like ultra-high efficiency multi-junction solar cells utilizing combinations of photovoltaic and photoelectrochemical junctions for hydrogen production. This paper discusses the current worldwide status as well as the development and optimization of copper-chalcopyrite thin films deposited onto various substrate types for different photovoltaic and photoelectrochemical applications at the Hawaii Natural Energy Institute. (author)

Low temperature plasma-enhanced atomic layer deposition of thin vanadium nitride layers for copper diffusion barriers

Energy Technology Data Exchange (ETDEWEB)

Rampelberg, Geert; Devloo-Casier, Kilian; Deduytsche, Davy; Detavernier, Christophe [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, B-9000 Ghent (Belgium); Schaekers, Marc [IMEC, Kapeldreef 75, B-3001 Leuven (Belgium); Blasco, Nicolas [Air Liquide Electronics US, L.P., 46401 Landing Parkway, Fremont, California 94538 (United States)

2013-03-18

Thin vanadium nitride (VN) layers were grown by atomic layer deposition using tetrakis(ethylmethylamino)vanadium and NH{sub 3} plasma at deposition temperatures between 70 Degree-Sign C and 150 Degree-Sign C on silicon substrates and polymer foil. X-ray photoelectron spectroscopy revealed a composition close to stoichiometric VN, while x-ray diffraction showed the {delta}-VN crystal structure. The resistivity was as low as 200 {mu}{Omega} cm for the as deposited films and further reduced to 143 {mu}{Omega} cm and 93 {mu}{Omega} cm by annealing in N{sub 2} and H{sub 2}/He/N{sub 2}, respectively. A 5 nm VN layer proved to be effective as a diffusion barrier for copper up to a temperature of 720 Degree-Sign C.

UV-transmission and fluorescence properties of polymer thin foils for use in microlens array fabrication

International Nuclear Information System (INIS)

Silvano, Donati; Wei, Mao-Kuo; Cai, Jhih-Hao; Lee, Jiun-Haw

2010-01-01

There is a report of measurements of optical transmission and fluorescence of thin foils of polyethylene terephthalate polymer, data that are unavailable in literature to the best of our knowledge. The foils are those commonly used as substrate and lens material in microlens arrays designed for use in multi-pixel image photodetectors with the purpose of fill-factor recovery. The wavelength range covered by the measurements is 200 to 800 nm and the thickness of polyethylene terephthalate foils is 40-80 μm. It was found a UV-transmission cutoff of 320 nm for polyethylene terephthalate and 330 nm for cured epoxy on polyethylene terephthalate. Fluorescence of the samples is peaked at 385 nm and the wavelength of most effective fluorescence is 340 nm

An Experimental Study on Micro Clinching of Metal Foils with Cutting by Laser Shock Forming.

Science.gov (United States)

Wang, Xiao; Li, Cong; Ma, Youjuan; Shen, Zongbao; Sun, Xianqing; Sha, Chaofei; Gao, Shuai; Li, Liyin; Liu, Huixia

2016-07-13

This paper describes a novel technique for joining similar and dissimilar metal foils, namely micro clinching with cutting by laser shock forming. A series of experiments were conducted to study the deformation behavior of single layer material, during which many important process parameters were determined. The process window of the 1060 pure aluminum foils and annealed copper foils produced by micro clinching with cutting was analyzed. Moreover, similar material combination (annealed copper foils) and dissimilar material combination (1060 pure aluminum foils and 304 stainless steel foils) were successfully achieved. The effect of laser energy on the interlock and minimum thickness of upper foils was investigated. In addition, the mechanical strength of different material combinations joined by micro clinching with cutting was measured in single lap shearing tests. According to the achieved results, this novel technique is more suitable for material combinations where the upper foil is thicker than lower foil. With the increase of laser energy, the interlock increased while the minimum thickness of upper foil decreased gradually. The shear strength of 1060 pure aluminum foils and 304 stainless steel foils combination was three times as large as that of 1060 pure aluminum foils and annealed copper foils combination.

X-ray spectroscopy of a thin foil plasma produced by a short-pulse high-intensity laser

International Nuclear Information System (INIS)

Audebert, P.; Nagels, V.; Geindre, J.P.; Dorchies, F.; Peyrusse, O.; Gary, S.; Girard, F.; Shepherd, R.; Gauthier, J.C.; Chenais-Popovics, C.

2003-01-01

High density and temperature plasmas have been generated by irradiating thin foils of various elements with a high-energy subpicosecond laser pulse. The X-ray emission duration was studied by time-resolved X-ray spectroscopy. Frequency domain interferometry provided a measurement of the hydrodynamic expansion of the back of the foil as a function of time. The effect of longitudinal temperature gradients, i.e., gradients perpendicular to the surface, were decreased using very thin foil targets. Additionally, radial gradients effects, i.e., gradients parallel to the surface, were limited by using a 50 μm pinhole on target. The Al, Se and Sm spectra, recorded in the range 7.7-8 Angst. using a conical crystal spectrometer coupled to an 800 fs resolution streak camera, lasted a few picoseconds. Sm spectra showed no spectral features in this wavelength range, providing a spectrally homogeneous backlighter for future experiments. The main features of the experimental time-resolved spectra have been well reproduced with one-dimensional hydrodynamic simulations of the free expansion of a plasma heated at a given initial temperature obtained from the expansion velocity of the rear critical surface of the plasma

Excimer laser assisted re-oxidation of BaTiO3 thin films on Ni metal foils

International Nuclear Information System (INIS)

Bharadwaja, S. S. N.; Ko, S. W.; Qu, W.; Clark, T.; Rajashekhar, A.; Motyka, M.; Podraza, N.; Randall, C. A.; Trolier-McKinstry, S.

2016-01-01

Excimer laser assisted re-oxidation for reduced, crystallized BaTiO 3 thin films on Ni-foils was investigated. It was found that the BaTiO 3 can be re-oxidized at an oxygen partial pressure of ∼50 mTorr and substrate temperature of 350 °C without forming a NiO x interface layer between the film and base metal foil. The dielectric permittivity of re-oxidized films was >1000 with loss tangent values <2% at 100 Hz, 30 mV rms excitation signal. Electron Energy Loss Spectroscopy indicated that BaTiO 3 thin films can be re-oxidized to an oxygen stoichiometry close to ∼3 (e.g., stoichiometric). High resolution cross sectional transmission electron microscopy showed no evidence of NiO x formation between the BaTiO 3 and the Ni foil upon excimer laser re-oxidation. Spectroscopic ellipsometry studies on laser re-oxidized [001] C and [111] C BaTiO 3 single crystals indicate that the re-oxidation of BaTiO 3 single crystals is augmented by photo-excitation of the ozone, as well as laser pulse induced temperature and local stress gradients

An Experimental Study on Micro Clinching of Metal Foils with Cutting by Laser Shock Forming

Directory of Open Access Journals (Sweden)

Xiao Wang

2016-07-01

Full Text Available This paper describes a novel technique for joining similar and dissimilar metal foils, namely micro clinching with cutting by laser shock forming. A series of experiments were conducted to study the deformation behavior of single layer material, during which many important process parameters were determined. The process window of the 1060 pure aluminum foils and annealed copper foils produced by micro clinching with cutting was analyzed. Moreover, similar material combination (annealed copper foils and dissimilar material combination (1060 pure aluminum foils and 304 stainless steel foils were successfully achieved. The effect of laser energy on the interlock and minimum thickness of upper foils was investigated. In addition, the mechanical strength of different material combinations joined by micro clinching with cutting was measured in single lap shearing tests. According to the achieved results, this novel technique is more suitable for material combinations where the upper foil is thicker than lower foil. With the increase of laser energy, the interlock increased while the minimum thickness of upper foil decreased gradually. The shear strength of 1060 pure aluminum foils and 304 stainless steel foils combination was three times as large as that of 1060 pure aluminum foils and annealed copper foils combination.

Simulation of the molecular recombination yield for swift H2+ ions through thin carbon foils

International Nuclear Information System (INIS)

Garcia-Molina, Rafael; Barriga-Carrasco, Manuel D.

2003-01-01

We have calculated the recombination yield for swift H 2 + molecular ions at the exit of thin amorphous carbon foils, as a function of the dwell time and incident energy. Our results are based on a detailed simulation of the motion through the target of the H 2 + molecular ion (before dissociation takes place) and its constituent fragments (after dissociation), including the following effects: Coulomb repulsion, nuclear scattering, electron capture and loss, as well as self-retarding and wake forces, which provide the relative distance and velocity of the dissociated fragments at the foil exit. The recombination of an H 2 + ion at the exit of the foil depends on the interproton separation and internal energy of the dissociated fragments, and on their probability to capture an electron. Comparison of our results with the available experimental data shows a good agreement

Polarity influence on the indentation punching of thin {111} GaAs foils at elevated temperatures

International Nuclear Information System (INIS)

Patriarche, G; Largeau, L; Riviere, J P; Bourhis, E Le

2005-01-01

Thin {111} GaAs substrates were deformed by a Vickers indenter at 350 deg. C-370 deg. C under loads ranging between 0.4 and 1.9 N. Optical microscopy and interferometry were used to observe the indented and opposite faces of the thin foils and hence to investigate the plastic flow through the samples. Attention was paid to the polarity (A or B) of the specimen surface, as GaAs is known to show a large difference between α and β dislocations mobilities. A model considering the influence of polarity is proposed to describe the material flow throughout thin samples

Thin Foil Acceleration Method for Measuring the Unloading Isentropes of Shock-Compressed Matter

International Nuclear Information System (INIS)

Asay, J.R.; Chhabildas, L.C.; Fortov, V.E.; Kanel, G.I.; Khishchenko, K.V.; Lomonosov, I.V.; Mehlhorn, T.; Razorenov, S.V.; Utkin, A.V.

1999-01-01

This work has been performed as part of the search for possible ways to utilize the capabilities of laser and particle beams techniques in shock wave and equation of state physics. The peculiarity of these techniques is that we have to deal with micron-thick targets and not well reproducible incident shock wave parameters, so all measurements should be of a high resolution and be done in one shot. Besides the Hugoniots, the experimental basis for creating the equations of state includes isentropes corresponding to unloading of shock-compressed matter. Experimental isentrope data are most important in the region of vaporization. With guns or explosive facilities, the unloading isentrope is recovered from a series of experiments where the shock wave parameters in plates of standard low-impedance materials placed behind the sample are measured [1,2]. The specific internal energy and specific volume are calculated from the measured p(u) release curve which corresponds to the Riemann integral. This way is not quite suitable for experiments with beam techniques where the incident shock waves are not well reproducible. The thick foil method [3] provides a few experimental points on the isentrope in one shot. When a higher shock impedance foil is placed on the surface of the material studied, the release phase occurs by steps, whose durations correspond to that for the shock wave to go back and forth in the foil. The velocity during the different steps, connected with the knowledge of the Hugoniot of the foil, allows us to determine a few points on the isentropic unloading curve. However, the method becomes insensitive when the low pressure range of vaporization is reached in the course of the unloading. The isentrope in this region can be measured by recording the smooth acceleration of a thin witness plate foil. With the mass of the foil known, measurements of the foil acceleration will give us the vapor pressure

Design of large size segmented GEM foils and Drift PCB for CBM MUCH

International Nuclear Information System (INIS)

Saini, J.; Dubey, A.K.; Chattopadhyay, S.

2016-01-01

Triple GEM (Gas Electron Multiplier), sector shaped detectors will be used for Muon tracking in the Compressed Baryonic Matter (CBM) experiment at Anti-proton Ion Research (FAIR) facility at Darmstadt, Germany. The sizes of the detectors modules in the Muon Chambers (MUCH) are of the order of 1 meter with active area of about 75cms. Progressive pad geometry is chosen for the readout from these detectors. In construction of these chambers, three GEM foils are stacked on top of each other in a 3/2/2/2 gap configuration. The GEM foils are double layered copper clad 50μm thin Kapton foil. Each GEM foil has millions of holes on it. Foils of large surface area are prone to damages due to discharges owing to the high capacitance of the foil. Hence, these foils have their top surfaces divided into segments of about 100 sq.cm. Further segmentation may be necessary when there are high rate requirements, as in the case of CBM. For the GEM foils of CBM MUCH, a 24 segment layout has been adopted. Short-circuit in any of the GEM-holes will make entire foil un-usable. To reduce such occurrences, segment to segment isolation using opto-coupler in series with the GEM-foil segments has been introduced. Hence, a novel design for GEM chamber drift-PCB and foils has been made. In this scheme, each segment is powered and controlled individually. At the same time, the design takes into account, the space constraints, not only in x-y plane, but also in the z, due to compact assembly of MUCH detector layers

Spot size dependence of laser accelerated protons in thin multi-ion foils

International Nuclear Information System (INIS)

Liu, Tung-Chang; Shao, Xi; Liu, Chuan-Sheng; Eliasson, Bengt; Wang, Jyhpyng; Chen, Shih-Hung

2014-01-01

We present a numerical study of the effect of the laser spot size of a circularly polarized laser beam on the energy of quasi-monoenergetic protons in laser proton acceleration using a thin carbon-hydrogen foil. The used proton acceleration scheme is a combination of laser radiation pressure and shielded Coulomb repulsion due to the carbon ions. We observe that the spot size plays a crucial role in determining the net charge of the electron-shielded carbon ion foil and consequently the efficiency of proton acceleration. Using a laser pulse with fixed input energy and pulse length impinging on a carbon-hydrogen foil, a laser beam with smaller spot sizes can generate higher energy but fewer quasi-monoenergetic protons. We studied the scaling of the proton energy with respect to the laser spot size and obtained an optimal spot size for maximum proton energy flux. Using the optimal spot size, we can generate an 80 MeV quasi-monoenergetic proton beam containing more than 10 8 protons using a laser beam with power 250 TW and energy 10 J and a target of thickness 0.15 wavelength and 49 critical density made of 90% carbon and 10% hydrogen

A thin foil Faraday collector as a lost alpha detector for high yield d-t tokamak fusion plasmas

International Nuclear Information System (INIS)

Cecil, F. Ed

2011-01-01

This report summarizes the accomplishment of sixteen years of work toward the development of thin foil Faraday collectors as a lost energetic ion diagnostic for high temperature magnetic confinement fusion plasmas. Following initial, proof of principle accelerator based studies, devices have been tested on TFTR, NSTX, ALCATOR, DIII-D, and JET (KA-1 and KA-2). The reference numbers refer to the attached list of publications. The JET diagnostic KA-2 continues in operation and hopefully will provide valuable diagnostic information during a possible d-t campaign on JET in the coming years. A thin Faraday foil spectrometer, by virtue of its radiation hardness, may likewise provide a solution to the very challenging problem of lost alpha particle measurements on ITER and other future burning plasma machines.

Moving foil stripper for a particle accelerator

International Nuclear Information System (INIS)

Gorka, A.J. Jr.

1975-01-01

Thin foils for stripping a particle beam are stored on the edge of a disk spinning in the accelerator vacuum. Cutting a foil at one edge releases the foil to project beyond the disk for insertion into the beam at a time determined by controlling the phase of the disk. A wiper removes a spent foil from the disk. The foil release and wiper are operable from a remote location. (U.S.)

Thin-foil phase transformations of tetragonal ZrO/sub 2/ in a ZrO/sub 2/-8 wt% Y/sub 2/O/sub 3/ alloy

International Nuclear Information System (INIS)

Bestgen, H.; Chaim, R.; Heuer, A.H.

1988-01-01

Tetragonal zirconia (t-ZrO/sub 2/) grains in an annealed ZrO/sub 2/-8 wt% Y/sub 2/O/sub 3/ alloy transformed to orthorhombic (o) or mono-clinic (m) symmetry by stresses induced by localized electron beam heating in the transmission electron microscope. Different transformation mechanisms were observed, depending on foil thickness and orientation of individual grains. In thicker grains (≥150 nm), the transformation proceeded by a burst-like growth of m laths, and this is believed to approximate bulk behavior. In thinner grains near the edge of the foil, usually those with a [100]/sub t/ orientation perpendicular to the thin-foil surface, continuous growth of an o or m phase with an antiphase-boundary-containing microstructure was observed. The o phase is believed to be a high-pressure polymorph of ZrO/sub 2/, which forms (paradoxically) as a thin-foil artifact because it is less dense than t-ZrO/sub 2/, but more dense than m-ZrO/sub 2/. In some very thin grains, the t → m transformation was thermoelastic. Furthermore, a mottled structure often occurred just before the t → m or t → o transformation, which is attributed to surface transformation. Aside from the lath formation, the observed transformation modes are a result of the reduced constraints in thin foils

Effects of laser power density and initial grain size in laser shock punching of pure copper foil

Science.gov (United States)

Zheng, Chao; Zhang, Xiu; Zhang, Yiliang; Ji, Zhong; Luan, Yiguo; Song, Libin

2018-06-01

The effects of laser power density and initial grain size on forming quality of holes in laser shock punching process were investigated in the present study. Three different initial grain sizes as well as three levels of laser power densities were provided, and then laser shock punching experiments of T2 copper foil were conducted. Based upon the experimental results, the characteristics of shape accuracy, fracture surface morphology and microstructures of punched holes were examined. It is revealed that the initial grain size has a noticeable effect on forming quality of holes punched by laser shock. The shape accuracy of punched holes degrades with the increase of grain size. As the laser power density is enhanced, the shape accuracy can be improved except for the case in which the ratio of foil thickness to initial grain size is approximately equal to 1. Compared with the fracture surface morphology in the quasistatic loading conditions, the fracture surface after laser shock can be divided into three zones including rollover, shearing and burr. The distribution of the above three zones strongly relates with the initial grain size. When the laser power density is enhanced, the shearing depth is not increased, but even diminishes in some cases. There is no obvious change of microstructures with the enhancement of laser power density. However, while the initial grain size is close to the foil thickness, single-crystal shear deformation may occur, suggesting that the ratio of foil thickness to initial grain size has an important impact on deformation behavior of metal foil in laser shock punching process.

Structural damage in thin SLIM-Cut c-Si foils fabricated for solar cell purposes: atomic assessment by electron spin resonance

International Nuclear Information System (INIS)

Kepa, J; Stesmans, A; Martini, R

2015-01-01

Within the context of reducing production costs, thin (<90 μm) silicon foils intended for photovoltaic applications have been fabricated from standard (100)Si wafers using a low-temperature (<150 °C) stress-induced lift-off process. A multi-frequency electron spin resonance (ESR) study was performed in order to evaluate, at atomic scale, the quality of the material in terms of defects, including identification and quantification. Generally, a complex ESR spectrum is observed, disentangled as the superposition of three separate signals. This includes, most prominently (∼91% of total density) the D-line (Si 3  ≡ Si· dangling bonds in a disordered Si environment), a set (∼6%) of highly anisotropic signals ascribed to dislocations (K1-like), and a triplet, identified as the Si-SL5 N-donor defect. Defect density depth profiling from the lift-off side shows all signals disappear in tandem after etching off a ∼33 μm thick Si layer, indicating a highly correlated−equal in relative terms−distribution of the three types of defects over the affected top part of the Si foil. The defect density is found to be highly non-uniform laterally, with the density peaking near the crack initiation point, from which defect generation spreads. It is thus found that the SLIM-Cut method for fabrication of thin Si foils results in the introduction of defects that would unacceptably impair the functionality of photovoltaic cells built on these substrates. Fortunately, this may be cured by etching off a thin top Si layer, resulting in a most useful thin Si foil of standard high quality. (paper)

Microstructure based procedure for process parameter control in rolling of aluminum thin foils

Science.gov (United States)

Johannes, Kronsteiner; Kabliman, Evgeniya; Klimek, Philipp-Christoph

2018-05-01

In present work, a microstructure based procedure is used for a numerical prediction of strength properties for Al-Mg-Sc thin foils during a hot rolling process. For this purpose, the following techniques were developed and implemented. At first, a toolkit for a numerical analysis of experimental stress-strain curves obtained during a hot compression testing by a deformation dilatometer was developed. The implemented techniques allow for the correction of a temperature increase in samples due to adiabatic heating and for the determination of a yield strength needed for the separation of the elastic and plastic deformation regimes during numerical simulation of multi-pass hot rolling. At the next step, an asymmetric Hot Rolling Simulator (adjustable table inlet/outlet height as well as separate roll infeed) was developed in order to match the exact processing conditions of a semi-industrial rolling procedure. At each element of a finite element mesh the total strength is calculated by in-house Flow Stress Model based on evolution of mean dislocation density. The strength values obtained by numerical modelling were found in a reasonable agreement with results of tensile tests for thin Al-Mg-Sc foils. Thus, the proposed simulation procedure might allow to optimize the processing parameters with respect to the microstructure development.

Atomic layer deposition of copper thin film and feasibility of deposition on inner walls of waveguides

Science.gov (United States)

Yuqing, XIONG; Hengjiao, GAO; Ni, REN; Zhongwei, LIU

2018-03-01

Copper thin films were deposited by plasma-enhanced atomic layer deposition at low temperature, using copper(I)-N,N‧-di-sec-butylacetamidinate as a precursor and hydrogen as a reductive gas. The influence of temperature, plasma power, mode of plasma, and pulse time, on the deposition rate of copper thin film, the purity of the film and the step coverage were studied. The feasibility of copper film deposition on the inner wall of a carbon fibre reinforced plastic waveguide with high aspect ratio was also studied. The morphology and composition of the thin film were studied by atomic force microscopy and x-ray photoelectron spectroscopy, respectively. The square resistance of the thin film was also tested by a four-probe technique. On the basis of on-line diagnosis, a growth mechanism of copper thin film was put forward, and it was considered that surface functional group played an important role in the process of nucleation and in determining the properties of thin films. A high density of plasma and high free-radical content were helpful for the deposition of copper thin films.

Simulation of the energy spectra of original versus recombined H2+ molecular ions transmitted through thin foils

International Nuclear Information System (INIS)

Barriga-Carrasco, Manuel D.; Garcia-Molina, Rafael

2004-01-01

This work presents the results of computer simulations for the energy spectra of original versus recombined H 2 + molecular ions transmitted through thin amorphous carbon foils, for a broad range of incident energies. A detailed description of the projectile motion through the target has been done, including nuclear scattering and Coulomb repulsion as well as electronic self-retarding and wake forces; the two latter are calculated in the dielectric formalism framework. Differences in the energy spectra of recombined and original transmitted H 2 + molecular ions clearly appear in the simulations, in agreement with the available experimental data. Our simulation code also differentiates the contributions due to original and to recombined H 2 + molecular ions when the energy spectra contain both contributions, a feature that could be used for experimental purposes in estimating the ratio between the number of original and recombined H 2 + molecular ions transmitted through thin foils

Envelope model for passive magnetic focusing of an intense proton or ion beam propagating through thin foils

Directory of Open Access Journals (Sweden)

Steven M. Lund

2013-04-01

Full Text Available Ion beams (including protons with low emittance and high space-charge intensity can be propagated with normal incidence through a sequence of thin metallic foils separated by vacuum gaps of order the characteristic transverse beam extent to transport/collimate the beam or to focus it to a small transverse spot. Energetic ions have sufficient range to pass through a significant number of thin foils with little energy loss or scattering. The foils reduce the (defocusing radial electric self-field of the beam while not altering the (focusing azimuthal magnetic self-field of the beam, thereby allowing passive self-beam focusing if the magnetic field is sufficiently strong relative to the residual electric field. Here we present an envelope model developed to predict the strength of this passive (beam generated focusing effect under a number of simplifying assumptions including relatively long pulse duration. The envelope model provides a simple criterion for the necessary foil spacing for net focusing and clearly illustrates system focusing properties for either beam collimation (such as injecting a laser-produced proton beam into an accelerator or for magnetic pinch focusing to a small transverse spot (for beam driven heating of materials. An illustrative example is worked for an idealization of a recently performed laser-produced proton-beam experiment to provide guidance on possible beam focusing and collimation systems. It is found that foils spaced on the order of the characteristic transverse beam size desired can be employed and that envelope divergence of the initial beam entering the foil lens must be suppressed to limit the total number of foils required to practical values for pinch focusing. Relatively modest proton-beam current at 10 MeV kinetic energy can clearly demonstrate strong magnetic pinch focusing achieving a transverse rms extent similar to the foil spacing (20–50  μm gaps in beam propagation distances of tens of mm

solution growth and characterization of copper oxide thin films ...

African Journals Online (AJOL)

Thin films of copper oxide (CuO) were grown on glass slides by using the solution growth technique. Copper cloride (CuCl ) and potassium telluride (K T O ) were used. Buffer 2 2e 3 solution was used as complexing agent. The solid state properties and optical properties were obtained from characterization done using PYE ...

Numerical Analysis of Thermal Stresses around Fasteners in Composite Metal Foils

Science.gov (United States)

Nammi, S. K.; Butt, J.; –L Mauricette, J.; Shirvani, H.

2017-12-01

The process of composite metal foil manufacturing (CMFM) has reduced a number of limitations associated with commercial additive manufacturing (AM) methods. The existing metal AM machines are restricted by their build envelope and there is a growing market for the manufacture of large parts using AM. These parts are subsequently manufactured in fragments and are fastened together. This paper analyses the thermal stresses around cylindrical fasteners for three layered metal composite parts consisting of aluminium foil, brazing paste and copper foil layers. The investigation aims to examine the mechanical integrity of the metallurgically bonded aluminium/copper foils of 100 micron thickness manufactured in a disc shape. A cylindrical fastener set at an elevated temperature of 100 °C is fitted in the middle of the disc which results in a steady-state thermal distribution. Radial and shear stresses are computed using finite element method which shows that non-zero shear stresses developed by the copper layer inhibit the axial slippage of the fastener and thereby establishing the suitability of rivet joints for CMFM parts.

Radiation lifetimes and failure mechanisms of carbon stripper foils

International Nuclear Information System (INIS)

Auble, R.L.

1981-01-01

Measurements of lifetimes of thin carbon foils under heavy-ion irradiation are compiled and recent advances in stripper foil technology are reviewed. The impact of recent foil lifetime improvements, many by more than an order of magnitude, on heavy-ion electrostatic accelerators is discussed. Foil inhomogeneities, particularly those caused by sputtering are suggested to be a prime factor in usable foil lifetimes

Influence of titanium oxide films on copper nucleation during electrodeposition

International Nuclear Information System (INIS)

Chang, Hyun K.; Choe, Byung-Hak; Lee, Jong K.

2005-01-01

Copper electrodeposition has an important industrial role because of various interconnects used in electronic devices such as printed wire boards. With an increasing trend in device miniaturization, in demand are void-free, thin copper foils of 10 μm thick or less with a very low surface profile. In accordance, nucleation kinetics of copper was studied with titanium cathodes that were covered with thin, passive oxide films of 2-3 nm. Such an insulating oxide layer with a band gap of 3 eV is supposed to nearly block charge transfer from the cathode to the electrolyte. However, significant nucleation rates of copper were observed. Pipe tunneling mechanism along a dislocation core is reasoned to account for the high nucleation kinetics. A dislocation core is proposed to be a high electron tunneling path with a reduced energy barrier and a reduced barrier thickness. In supporting the pipe tunneling mechanism, both 'in situ' and 'ex situ' scratch tests were performed to introduce extra dislocations into the cathode surface, that is, more high charge paths via tunneling, before electrodeposition

Gas permeability through thin-foil x-ray filters

Science.gov (United States)

Tveekrem, June L.; Keski-Kuha, Ritva A.; Webb, Andrew T.

1997-10-01

We have measured the permeation rates of helium and water through thin-foil UV-blocking filters used in the ASTRO-E/x- ray spectrometer (XRS) instrument. In the XRS program, there is a concern that outgassed contaminants such as water could permeate through the outermost filter which will be at room temperature and freeze on the inner filters which will be at cryogenic temperatures. The filters tested consisted of approximately 1000 angstroms Al on approximately 1000 angstroms of either Lexan or polyimide. Measurements were made using a vacuum apparatus consisting essentially of two small chambers separated by the filter under test. A helium leak detector was used to measure helium permeation rates, and a residual gas analyzer (RGA) was used to detect water. Results discussed include permeation rate as a function of pressure difference across a filter, the ratio of helium permeation rate over water permeation rate, and the effect of the aluminum layer thickness on permeation.

Foil changer for the Chalk River superconducting cyclotron

International Nuclear Information System (INIS)

Hoffmann, C.R.; Kilborn, R.I.; Mouris, J.E.; Proulx, D.R.; Weaver, J.F.

1985-01-01

Capture of an injected beam in the Chalk River superconducting cyclotron requires that a carbon stripping foil be accurately placed in a dee to intercept the incoming beam. Foil radial position must be precisely adjustable and foils must be easily replaced. A foil changing apparatus has been designed, built and tested to meet these requirements. The main components are a supply magazine, a transport system, and unloading and loading mechanisms. The magazine is on top of the cyclotron. It holds 300 foils and can be isolated from machine vacuum for refilling. Each foil is mounted on a stainless steel frame. A stainless steel roller chain fitted with 33 copper sleeves (shrouds) carries foils, one per shroud, down a dee stem to the midplane. A 12-bit absolute optical shaft encoder senses foil position. To replace a foil a shroud is positioned at the top of the cyclotron, a foil is removed, and another is transferred from the magazine to the empty shroud. Three stepping motors and associated electronics provide mechanical drive and are interfaced with a CAMAC control system

Thermal Stability of Copper-Aluminum Alloy Thin Films for Barrierless Copper Metallization on Silicon Substrate

Science.gov (United States)

Wang, C. P.; Dai, T.; Lu, Y.; Shi, Z.; Ruan, J. J.; Guo, Y. H.; Liu, X. J.

2017-08-01

Copper thin films with thickness of about 500 nm doped with different aluminum concentrations have been prepared by magnetron sputtering on Si substrate and their crystal structure, microstructure, and electrical resistivity after annealing at various temperatures (200°C to 600°C) for 1 h or at 400°C for different durations (1 h to 11 h) investigated by grazing-incidence x-ray diffraction (GIXRD) analysis, scanning electron microscopy (SEM), and four-point probe (FPP) measurements. Cu-1.8Al alloy thin film exhibited good thermal stability and low electrical resistivity (˜5.0 μΩ cm) after annealing at 500°C for 1 h or 400°C for 7 h. No copper silicide was observed at the Cu-Al/Si interface by GIXRD analysis or SEM for this sample. This result indicates that doping Cu thin film with small amounts of Al can achieve high thermal stability and low electrical resistivity, suggesting that Cu-1.8Al alloy thin film could be used for barrierless Cu metallization on Si substrate.

Surface enhanced Raman scattering of gold nanoparticles supported on copper foil with graphene as a nanometer gap

International Nuclear Information System (INIS)

Xiang, Quan; Zhu, Xupeng; Chen, Yiqin; Duan, Huigao

2016-01-01

Gaps with single-nanometer dimensions (<10 nm) between metallic nanostructures enable giant local field enhancements for surface enhanced Raman scattering (SERS). Monolayer graphene is an ideal candidate to obtain a sub-nanometer gap between plasmonic nanostructures. In this work, we demonstrate a simple method to achieve a sub-nanometer gap by dewetting a gold film supported on monolayer graphene grown on copper foil. The Cu foil can serve as a low-loss plasmonically active metallic film that supports the imaginary charge oscillations, while the graphene can not only create a stable sub-nanometer gap for massive plasmonic field enhancements but also serve as a chemical enhancer. We obtained higher SERS enhancements in this graphene-gapped configuration compared to those in Au nanoparticles on Cu film or on graphene–SiO 2 –Si. Also, the Raman signals measured maintained their fine features and intensities over a long time period, indicating the stability of this Au–graphene–Cu hybrid configuration as an SERS substrate. (paper)

Methods of making copper selenium precursor compositions with a targeted copper selenide content and precursor compositions and thin films resulting therefrom

Science.gov (United States)

Curtis, Calvin J [Lakewood, CO; Miedaner, Alexander [Boulder, CO; van Hest, Marinus Franciscus Antonius Maria; Ginley, David S [Evergreen, CO; Leisch, Jennifer [Denver, CO; Taylor, Matthew [West Simsbury, CT; Stanbery, Billy J [Austin, TX

2011-09-20

Precursor compositions containing copper and selenium suitable for deposition on a substrate to form thin films suitable for semi-conductor applications. Methods of forming the precursor compositions using primary amine solvents and methods of forming the thin films wherein the selection of temperature and duration of heating controls the formation of a targeted species of copper selenide.

Laser Acceleration of Quasi-Monoenergetic Protons via Radiation Pressure Driven Thin Foil

International Nuclear Information System (INIS)

Liu, Chuan S.; Shao Xi; Liu, T. C.; Dudnikova, Galina; Sagdeev, Roald Z.; Eliasson, Bengt

2011-01-01

We present a theoretical and simulation study of laser acceleration of quasi-monoenergetic protons in a thin foil irradiated by high intensity laser light. The underlying physics of radiation pressure acceleration (RPA) is discussed, including the importance of optimal thickness and circularly polarized light for efficient acceleration of ions to quasi-monoenergetic beams. Preliminary two-dimensional simulation studies show that certain parameter regimes allow for stabilization of the Rayleigh-Taylor instability and possibility of acceleration of monoenergetic ions to an excess of 200 MeV, making them suitable for important applications such as medical cancer therapy and fast ignition.

Collodion-reinforcement and plasma-cleaning of target foils

Science.gov (United States)

Stoner, John O.

2002-03-01

The preparation of evaporated target foils can often be facilitated by use of collodion coatings either on the substrate sides or on the exterior surfaces of the foils. Later, such coatings must usually be removed. Cleaning of a foil is necessary if thin layers of adhesives have crept onto the foil. Removal and/or cleaning can often be done satisfactorily with an oxygen plasma. Apparatus and procedures used for this are described. Foils that were cleaned successfully, and some that were incompatible with the cleaning process are listed.

Collodion-reinforcement and plasma-cleaning of target foils

International Nuclear Information System (INIS)

Stoner, John O.

2002-01-01

The preparation of evaporated target foils can often be facilitated by use of collodion coatings either on the substrate sides or on the exterior surfaces of the foils. Later, such coatings must usually be removed. Cleaning of a foil is necessary if thin layers of adhesives have crept onto the foil. Removal and/or cleaning can often be done satisfactorily with an oxygen plasma. Apparatus and procedures used for this are described. Foils that were cleaned successfully, and some that were incompatible with the cleaning process are listed

Polymer-ZnO nanocomposites foils and thin films for UV protection

International Nuclear Information System (INIS)

Shanshool, Haider Mohammed; Yahaya, Muhammad; Abdullah, Ibtisam Yahya; Yunus, Wan Mahmood Mat

2014-01-01

The damage of UV radiation on human eye and skin is extensively studied. In the present work, the nanocomposites foils and thin films have been prepared by using casting method and spin coating, respectively. Nanocomposites were prepared by mixing ZnO nanoparticles with Polymethyl methacrylate (PMMA) and Polyvinylidene fluoride (PVDF) as polymer matrix. Different contents of ZnO nanoparticles were used as filler in the nanocomposites. UV-Vis spectra showed very low transmittance in UV region that decreases with increase content of ZnO. PVDF/ZnO samples showed the lowest transmittance. The rough surface of PVDF was observed from SEM image. While a homogeneous dispersion of ZnO nanoparticles in PMMA were indicated by FESEM images

Polymer-ZnO nanocomposites foils and thin films for UV protection

Energy Technology Data Exchange (ETDEWEB)

Shanshool, Haider Mohammed; Yahaya, Muhammad; Abdullah, Ibtisam Yahya [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Yunus, Wan Mahmood Mat [Department of Physics, Faculty of Science, University Putra Malaysia, 43400 UPM, Serdang (Malaysia)

2014-09-03

The damage of UV radiation on human eye and skin is extensively studied. In the present work, the nanocomposites foils and thin films have been prepared by using casting method and spin coating, respectively. Nanocomposites were prepared by mixing ZnO nanoparticles with Polymethyl methacrylate (PMMA) and Polyvinylidene fluoride (PVDF) as polymer matrix. Different contents of ZnO nanoparticles were used as filler in the nanocomposites. UV-Vis spectra showed very low transmittance in UV region that decreases with increase content of ZnO. PVDF/ZnO samples showed the lowest transmittance. The rough surface of PVDF was observed from SEM image. While a homogeneous dispersion of ZnO nanoparticles in PMMA were indicated by FESEM images.

Foil changer for the Chalk River superconducting cyclotron

International Nuclear Information System (INIS)

Hoffmann, C.R.; Kilborn, R.I.; Mouris, J.F.; Proulx, D.R.; Weaver, J.F.

1985-01-01

Capture of an injected beam in the Chalk River superconducting cyclotron requires that a carbon stripping foil be accurately placed in a dee to intercept the incoming beam. Foil radial position must be precisely adjustable and foils must be easily replaced. A foil changing apparatus has been designed, built and tested to meet these requirements. The main components are a supply magazine, a transport system, and unloading and loading mechanisms. The magazine is on top of the loading mechanisms. The magazine is on top of the cyclotron. It holds 300 foils and can be isolated from machine vacuum for refilling. Each foil is mounted on a stainless steel frame. A stainless steel roller chain fitted with 33 copper sleeves (shrouds) carries foils, one per shroud, down a dee stem to the midplane. A 12-bit absolute optical shaft encoder senses foil position. To replace a foil a shroud is positioned at the top of the cyclotron, a foil is removed, and another is transferred from the magazine to the empty shroud. Three stepping motors and associated electronics provide mechanical drive and are interfaced with a CAMAC control system

Copper contamination in thin stainless steel sheet

International Nuclear Information System (INIS)

Holbert, R.K. Jr.; Dobbins, A.G.; Bennett, R.K. Jr.

1986-01-01

The standard welding technique used at Oak Ridge Y-12 Plant for joining thin stainless sheet is the gas tungsten arc (GTA) welding process. One of the reoccurring problems with the sheet welds is surface cracking in the heat-affected zone (HAZ). Metallography shows that the cracks are only about 0.05 mm (0.002 in.) deep which is significant in a 0.25 mm (0.01 in.) thick sheet. Thus, welding requirements do not permit any surfacing cracking as detected by a fluorescent dye penetrant test conducted on every part after welding. Surface cracks have been found in both of the two most common weld designs in the thin sheet fabricated at the Oak Ridge Y-12 Plant. These butt joints are welded between two 0.25 mm thick stainless steel sheets and a tube with eyelet welded to a 25 mm (0.98 in.) thick sheet. The weld between the two sheets is made on a semiautomatic seam welding unit, whereas the tube-to-eyelet-to-sheet welds are done manually. The quality of both welds is very dependent on the welding procedure and the way the parts are placed in the weld fixturing. Metallographic examination has indicated that some welded parts with surface cracking in the weld region had copper particles on the surface, and the question of copper contamination has been raised. With the aid of a scanning electron microscope and an electron microprobe, the existence of copper in an around the surface cracks has been verified. The copper is on the surface of the parts prior to welding in the form of small dust particles

Time-resolved plasma spectroscopy of thin foils heated by a relativistic-intensity short-pulse laser

International Nuclear Information System (INIS)

Audebert, P.; Gauthier, J.-C.; Shepherd, R.; Fournier, K.B.; Price, D.; Lee, R.W.; Springer, P.; Peyrusse, O.; Klein, L.

2002-01-01

Time-resolved K-shell x-ray spectra are recorded from sub-100 nm aluminum foils irradiated by 150-fs laser pulses at relativistic intensities of Iλ 2 =2x10 18 W μm 2 /cm 2 . The thermal penetration depth is greater than the foil thickness in these targets so that uniform heating takes place at constant density before hydrodynamic motion occurs. The high-contrast, high-intensity laser pulse, broad spectral band, and short time resolution utilized in this experiment permit a simplified interpretation of the dynamical evolution of the radiating matter. The observed spectrum displays two distinct phases. At early time, ≤500 fs after detecting target emission, a broad quasicontinuous spectral feature with strong satellite emission from multiply excited levels is seen. At a later time, the He-like resonance line emission is dominant. The time-integrated data is in accord with previous studies with time resolution greater than 1 ps. The early time satellite emission is shown to be a signature of an initial large area, high density, low-temperature plasma created in the foil by fast electrons accelerated by the intense radiation field in the laser spot. We conclude that, because of this early time phenomenon and contrary to previous predictions, a short, high-intensity laser pulse incident on a thin foil does not create a uniform hot and dense plasma. The heating mechanism has been studied as a function of foil thickness, laser pulse length, and intensity. In addition, the spectra are found to be in broad agreement with a hydrodynamic expansion code postprocessed by a collisional-radiative model based on superconfiguration average rates and on the unresolved transition array formalism

Simultaneous laser cutting and welding of metal foil to edge of a plate

Science.gov (United States)

Pernicka, J.C.; Benson, D.K.; Tracy, C.E.

1996-03-19

A method is described for welding an ultra-thin foil to the edge of a thicker sheet to form a vacuum insulation panel comprising the steps of providing an ultra-thin foil having a thickness less than 0.002, providing a top plate having an edge and a bottom plate having an edge, clamping the foil to the edge of the plate wherein the clamps act as heat sinks to distribute heat through the foil, providing a laser, moving the laser relative to the foil and the plate edges to form overlapping weld beads to weld the foil to the plate edges while simultaneously cutting the foil along the weld line formed by the overlapping beads. 7 figs.

Copper thin film for RFID UHF antenna on flexible substrate

International Nuclear Information System (INIS)

Tran, Nhan Ai; Tran, Huy Nam; Dang, Mau Chien; Fribourg-Blanc, Eric

2010-01-01

A process flow using photolithography and sputtering was studied for copper antenna fabrication on thin poly(ethylene terephthalate) (PET) substrate. The lift-off route was chosen for its flexibility at laboratory scale. It was clarified that the cleaning of PET is an important step that necessitates mild oxygen plasma etching. Then copper is sputter deposited after photolithographic definition of the antenna. Care is necessary since PET, as a very flexible substrate, is temperature sensitive. The temperature increase generated by the impact of deposited copper should be maintained below the glass transition temperature of the polymer to avoid detrimental deformation. dc power of 40 to 50 W was found to be the maximum possible sputtering power for commercial PET. It was found that the resistivity of the thin film is below two times the bulk resistivity of copper for a deposition pressure below 4×10 −3  mbar and thickness above 450 nm. These results enable the reliable fabrication of copper RFID UHF antennae on a PET substrate for further testing of new tag designs. The present paper summarizes the effort to test new designs of antennae for RadioFrequency IDentification (RFID) Ultra High Frequency (UHF) tags, for use in various applications (e.g. object tracking and environment monitoring) in Vietnam

Characterizing convective heat transfer using infrared thermography and the heated-thin-foil technique

International Nuclear Information System (INIS)

Stafford, Jason; Walsh, Ed; Egan, Vanessa

2009-01-01

Convective heat transfer, due to axial flow fans impinging air onto a heated flat plate, is investigated with infrared thermography to assess the heated-thin-foil technique commonly used to quantify two-dimensional heat transfer performance. Flow conditions generating complex thermal profiles have been considered in the analysis to account for dominant sources of error in the technique. Uncertainties were obtained in the measured variables and the influences on the resultant heat transfer data are outlined. Correction methods to accurately account for secondary heat transfer mechanisms were developed and results show that as convective heat transfer coefficients and length scales decrease, the importance of accounting for errors increases. Combined with flow patterns that produce large temperature gradients, the influence of heat flow within the foil on the resultant heat transfer becomes significant. Substantial errors in the heat transfer coefficient are apparent by neglecting corrections to the measured data for the cases examined. Methods to account for these errors are presented here, and demonstrated to result in an accurate measurement of the local heat transfer map on the surface

Low-energy foil aberration corrector

International Nuclear Information System (INIS)

Aken, R.H. van; Hagen, C.W.; Barth, J.E.; Kruit, P.

2002-01-01

A spherical and chromatic aberration corrector for electron microscopes is proposed, consisting of a thin foil sandwiched between two apertures. The electrons are retarded at the foil to almost zero energy, so that they can travel ballistically through the foil. It is shown that such a low-voltage corrector has a negative spherical aberration for not too large distances between aperture and foil, as well as a negative chromatic aberration. For various distances the third- and fifth-order spherical aberration coefficients and the first- and second-order chromatic aberration coefficients are calculated using ray tracing. Provided that the foils have sufficient electron transmission the corrector is able to correct the third-order spherical aberration and the first-order chromatic aberration of a typical low-voltage scanning electron microscope. Preliminary results show that the fifth-order spherical aberration and the second-order chromatic aberration can be kept sufficiently low

Electron microscope observation of single - crystalline beryllium thin foils

International Nuclear Information System (INIS)

Antolin, J.; Poirier, J.P.; Dupouy, J.M.

1965-01-01

Thin foils prepared from single crystalline beryllium simples deformed at room temperature, have been observed by transmission electron microscopy. The various deformation modes have been investigated separately, from their early stages and their characteristic dislocation configurations have been observed. Basal slip is characterized at is outset by the presence of numerous dipoles and elongated prismatic loops. More pronounced cold work leads to the formation of dislocation tangles and bundles which eventually give a cellular structure. Prismatic slip begins by the cross-slip of dislocations from the basal plane into the prismatic plane. A cellular structure is equally observed in heavily deformed samples. Sessile dislocations have been observed in twin boundaries; they are produced by reactions between slip dislocations and twin dislocations. Finally, the study of samples quenched from 1100 deg. C and annealed at 200 deg. C has shown that the observed loops lie in prismatic planes and have a Burgers vector b 1/3 . (authors) [fr

Reducing the cost of MWT module technology based on conductive back-sheet foils

Energy Technology Data Exchange (ETDEWEB)

Bennett, I.J.; Goris, M.J.A.A.; Eerenstein, W. [ECN Solar Energy, P.O. Box 1, 1755 ZG Petten (Netherlands)

2013-10-15

MWT cell and module technology has shown to result in modules with a higher power output than H-pattern modules and to be suitable for use with thin and fragile cells. In this work, the use of low-cost module materials and their effect on module performance and reliability has been assessed. These materials include a conductive back-sheet patterned by milling with no silver plating at the contacts on the foil and no isolation coating on the copper and a low-silver content conductive adhesive. The sensitivity of module performance for the anti-corrosion coating on the copper of the conductive back-sheet is measured, as is the reliability in climate chamber testing of mini-modules made with these materials. The results show that these low cost materials can be used to manufacture module with good performance and reliability. Options are given for further cost reduction.

Analytical model for release calculations in solid thin-foils ISOL targets

Energy Technology Data Exchange (ETDEWEB)

Egoriti, L. [Belgian Nuclear Research Centre (SCK-CEN), Boeretang 200, B-2400 Mol (Belgium); Politecnico di Milano, Department of Energy, CeSNEF-Nuclear Engineering Division, Via Ponzio, 34/3, 20133 Milano (Italy); Boeckx, S. [Belgian Nuclear Research Centre (SCK-CEN), Boeretang 200, B-2400 Mol (Belgium); ICTEAM Inst., Univ. Catholique de Louvain, Louvain-la-Neuve (Belgium); Ghys, L. [Belgian Nuclear Research Centre (SCK-CEN), Boeretang 200, B-2400 Mol (Belgium); Houngbo, D., E-mail: donald.houngbo@sckcen.be [Belgian Nuclear Research Centre (SCK-CEN), Boeretang 200, B-2400 Mol (Belgium); Department of Flow, Heat and Combustion Mechanics, Gent University (UGent), St.-Pietersnieuwstraat 41, B-9000 Gent (Belgium); Popescu, L. [Belgian Nuclear Research Centre (SCK-CEN), Boeretang 200, B-2400 Mol (Belgium)

2016-10-01

A detailed analytical model has been developed to simulate isotope-release curves from thin-foils ISOL targets. It involves the separate modeling of diffusion and effusion inside the target. The former has been modeled using both first and second Fick's law. The latter, effusion from the surface of the target material to the end of the ionizer, was simulated with the Monte Carlo code MolFlow+. The calculated delay-time distribution for this process was then fitted using a double-exponential function. The release curve obtained from the convolution of diffusion and effusion shows good agreement with experimental data from two different target geometries used at ISOLDE. Moreover, the experimental yields are well reproduced when combining the release fraction with calculated in-target production.

Investigation of interdiffusion in copper-nickel bilayer thin films

Energy Technology Data Exchange (ETDEWEB)

Abdul-Lettif, Ahmed M. [Physics Department, College of Science, Babylon University, Hilla (Iraq)]. E-mail: abdullettif@yahoo.com

2007-01-15

Auger depth profiling technique and X-ray diffraction analysis have been employed to study the interdiffusion in vacuum-deposited copper-nickel bilayer thin films. An adaptation of the Whipple model was used to determine the diffusion coefficients of both nickel in copper and copper in nickel. The calculated diffusion coefficient is (2.0x10{sup -7} cm{sup 2}/s)exp(-1.0 eV/kT) for nickel in copper, and (6x10{sup -8} cm{sup 2}/s)exp(-0.98 eV/kT) for copper in nickel. The difference between the diffusion parameters obtained in the present work and those extracted by other investigators is attributed essentially to the difference in the films microstructure and to the annealing ambient. It is concluded that interdiffusion in the investigated films is described by type-B kinetics in which rapid grain-boundary diffusion is coupled to defect-enhanced diffusion into the grain interior. The present data raise a question about the effectiveness of nickel as a diffusion barrier between copper and the silicon substrate.

Copper zinc tin sulfide-based thin film solar cells

CERN Document Server

Ito, Kentaro

2014-01-01

Beginning with an overview and historical background of Copper Zinc Tin Sulphide (CZTS) technology, subsequent chapters cover properties of CZTS thin films, different preparation methods of CZTS thin films, a comparative study of CZTS and CIGS solar cell, computational approach, and future applications of CZTS thin film solar modules to both ground-mount and rooftop installation. The semiconducting compound (CZTS) is made up earth-abundant, low-cost and non-toxic elements, which make it an ideal candidate to replace Cu(In,Ga)Se2 (CIGS) and CdTe solar cells which face material scarcity and tox

Angular scattering of 1–50 keV ions through graphene and thin carbon foils: Potential applications for space plasma instrumentation

International Nuclear Information System (INIS)

Ebert, Robert W.; Allegrini, Frédéric; Fuselier, Stephen A.; Nicolaou, Georgios; Bedworth, Peter; Sinton, Steve; Trattner, Karlheinz J.

2014-01-01

We present experimental results for the angular scattering of ∼1–50 keV H, He, C, O, N, Ne, and Ar ions transiting through graphene foils and compare them with scattering through nominal ∼0.5 μg cm −2 carbon foils. Thin carbon foils play a critical role in time-of-flight ion mass spectrometers and energetic neutral atom sensors in space. These instruments take advantage of the charge exchange and secondary electron emission produced as ions or neutral atoms transit these foils. This interaction also produces angular scattering and energy straggling for the incident ion or neutral atom that acts to decrease the performance of a given instrument. Our results show that the angular scattering of ions through graphene is less pronounced than through the state-of-the-art 0.5 μg cm −2 carbon foils used in space-based particle detectors. At energies less than 50 keV, the scattering angle half width at half maximum, ψ 1/2 , for ∼3–5 atoms thick graphene is up to a factor of 3.5 smaller than for 0.5 μg cm −2 (∼20 atoms thick) carbon foils. Thus, graphene foils have the potential to improve the performance of space-based plasma instruments for energies below ∼50 keV

Process for producing molybdenum foil and collapsible tubing

Science.gov (United States)

Bretts, G. R.; Gavert, R. B.; Groschke, G. F.

1971-01-01

Manufacturing process produces molybdenum foil 0.002 cm thick and 305 m long, and forms foil into high-strength, thin-walled tubing which can be flattened for storage on a spool. Desirable metal properties include high thermal conductivity stiffness, yield and tensile stress, and low thermal expansion coeffecient.

XPS studies of short pulse laser interaction with copper

International Nuclear Information System (INIS)

Stefanov, P.; Minkovski, N.; Balchev, I.; Avramova, I.; Sabotinov, N.; Marinova, Ts.

2006-01-01

The effect of laser ablation on copper foil irradiated by a short 30 ns laser pulse was investigated by X-ray photoelectron spectroscopy. The laser fluence was varied from 8 to 16.5 J/cm 2 and the velocity of the laser beam from 10 to 100 mm/s. This range of laser fluence is characterized by a different intensity of laser ablation. The experiments were done in two kinds of ambient atmosphere: air and argon jet gas. The chemical state and composition of the irradiated copper surface were determined using the modified Auger parameter (α') and O/Cu intensity ratio. The ablation atmosphere was found to influence the size and chemical state of the copper particles deposited from the vapor plume. During irradiation in air atmosphere the copper nanoparticles react with oxygen and water vapor from the air and are deposited in the form of a CuO and Cu(OH) 2 thin film. In argon atmosphere the processed copper surface is oxidized after exposure to air

Development of thin foil Faraday collector as a lost alpha particle diagnostic for high yield D-T tokamak fusion plasmas

Energy Technology Data Exchange (ETDEWEB)

Van Belle, P; Jarvis, O N; Sadler, G J [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking; Cecil, F E [Colorado School of Mines, Golden, CO (United States)

1994-07-01

Alpha particle confinement is necessary for ignition of a D-T tokamak fusion plasma and for first wall protection. Due to high radiation backgrounds and temperatures, scintillators and semiconductor detectors may not be used to study alpha particles which are lost to the first wall during the D-T programs on JET and ITER. An alternative method of charged particle spectrometry capable of operation in these harsh environments, is proposed: it consists of thin foils of electrically isolated conductors with the flux of alpha particles determined by the positive current flowing from the foils. 2 refs., 3 figs.

Buffer Film Assisted Growth of Dense MWCNTs on Copper Foils for Flexible Electrochemical Applications

Directory of Open Access Journals (Sweden)

Udomdej Pakdee

2017-01-01

Full Text Available The novel Inconel buffer films were prepared on copper foils using unbalance direct current (DC magnetron sputtering. These films were employed as buffer layers for supporting the dense growth of multiwalled carbon nanotubes (MWCNTs. Thermal chemical vapor deposition (CVD with metal alloys such as stainless steel (SS type 304 films was considered to synthesize MWCNTs. To understand the effectiveness of these buffer films, the MWCNTs grown on buffer-free layer were carried out as a comparison. The main problem such as the diffusion of catalysts into the oxide layer of metal substrate during the CVD process was solved together with a creation of good electrical contact between substrate and nanotubes. The morphologies, crystallinities, and electrochemical behaviors of MWCNTs grown on Inconel buffer films with 304 SS catalysts revealed the better results for applying in flexible electrochemical applications.

Proton probing of ultra-thin foil dynamics in high intensity regime

Science.gov (United States)

Prasad, Rajendra; Aktan, Esin; Aurand, Bastian; Cerchez, Mirela; Willi, Oswald

2017-10-01

The field of laser driven ion acceleration has been enriched significantly over the past decade, thanks to the advanced laser technologies. Already, from 100s TW class systems, laser driven sources of particles and radiations are being considered in number of potential applications in science and medicine due to their unique properties. New physical effects unearthed at these systems may help understand and conduct successful experiments at several PW class multi-beam facilities with high rep rate systems, e.g. ELI. Here we present the first experimental results on ultra-thin foil dynamics irradiated by an ultra-high intensity (1020 W/cm2) , ultra-high contrast (10-12) laser pulse at ARCTURUS laser facility at HHU Duesseldorf. By employing the elegant proton probing technique it is observed that for the circular polarization of laser light, a 100nm thin target is pushed forward as a compressed layer due to the radiation pressure of light. Whereas, the linear polarization seems to decompress the target drastically. 2D particle-in-cell simulations corroborate the experimental findings. Our results confirm the previous simulation studies investigating the fundamental role played by light polarization, finite focus spot size effect and eventually electron heating including the oblique incidence at the target edges.

Effect of acetic acid on wet patterning of copper/molybdenum thin films in phosphoric acid solution

International Nuclear Information System (INIS)

Seo, Bo.-Hyun; Lee, Sang-Hyuk; Park, In-Sun; Seo, Jong Hyun; Choe, HeeHwan; Jeon, Jae-Hong; Hong, Munpyo; Lee, Yong Uk; Winkler, Joerg

2011-01-01

Copper metallization is a key issue for high performance thin film transistor (TFT) technology. A phosphoric acid based copper etchant is a potentially attractive alternative to the conventional hydrogen peroxide based etchant due to its longer-life expectancy time and higher stability in use. In this paper, it is shown that amount of the acetic acid in the phosphoric based copper etchant plays an important role in controlling the galvanic reaction between the copper and the molybdenum. As the concentration of acetic acid in the phosphoric mixture solution increased from 0 M to 0.4 M, the measured galvanic current density dropped from 32 mA/cm 2 to 26 mA/cm 2 , indicating that the acetic acid induces the lower galvanic reaction between the copper and the molybdenum in the solution. From the XPS analysis, with the addition of the acetic acid, the thickness of the protective MoO 2 passive film covering the molybdenum surface grew and the dissolution rate of the molybdenum thin film decreased. However, the dissolution rate of the copper thin film increased as the concentration of acetic acid in the mixture solution increased.

Effect of acetic acid on wet patterning of copper/molybdenum thin films in phosphoric acid solution

Energy Technology Data Exchange (ETDEWEB)

Seo, Bo.-Hyun; Lee, Sang-Hyuk; Park, In-Sun [Department of Materials Engineering, Korea Aerospace University, Hwajeon, Goyang, Gyonggi-do 412-791 (Korea, Republic of); Seo, Jong Hyun, E-mail: jhseo@kau.ac.kr [Department of Materials Engineering, Korea Aerospace University, Hwajeon, Goyang, Gyonggi-do 412-791 (Korea, Republic of); Choe, HeeHwan; Jeon, Jae-Hong [School of Electronics, Telecommunications and Computer Engineering, Korea Aerospace University, Hwajeon, Goyang, Gyonggi-do 412-791 (Korea, Republic of); Hong, Munpyo [Display and Semiconductor Physics, Korea University (Korea, Republic of); Lee, Yong Uk [PETEC (The Printable Electronics Technology Centre) (United Kingdom); Winkler, Joerg [PLANSEE Metal GmbH, Metallwerk-Plansee-Str. 71A-6600, Reutte (Austria)

2011-08-01

Copper metallization is a key issue for high performance thin film transistor (TFT) technology. A phosphoric acid based copper etchant is a potentially attractive alternative to the conventional hydrogen peroxide based etchant due to its longer-life expectancy time and higher stability in use. In this paper, it is shown that amount of the acetic acid in the phosphoric based copper etchant plays an important role in controlling the galvanic reaction between the copper and the molybdenum. As the concentration of acetic acid in the phosphoric mixture solution increased from 0 M to 0.4 M, the measured galvanic current density dropped from 32 mA/cm{sup 2} to 26 mA/cm{sup 2}, indicating that the acetic acid induces the lower galvanic reaction between the copper and the molybdenum in the solution. From the XPS analysis, with the addition of the acetic acid, the thickness of the protective MoO{sub 2} passive film covering the molybdenum surface grew and the dissolution rate of the molybdenum thin film decreased. However, the dissolution rate of the copper thin film increased as the concentration of acetic acid in the mixture solution increased.

Preparation of location-specific thin foils from Fe-3%Si bi- and tri- crystals for examination in a FEG-STEM

Czech Academy of Sciences Publication Activity Database

Sorbello, F.; Hughes, G.M.; Lejček, Pavel; Heard, P.J.; Flewitt, P.E.J.

2009-01-01

Roč. 109, č. 2 (2009), 147-153 ISSN 0304-3991 R&D Projects: GA AV ČR IAA1010414 Institutional research plan: CEZ:AV0Z10100520 Keywords : FEG-STEM * Fe-3%Si * Thin foils * focused ion beam Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.067, year: 2009

Solution-processed p-type copper(I) thiocyanate (CuSCN) for low-voltage flexible thin-film transistors and integrated inverter circuits

KAUST Repository

Petti, Luisa

2017-03-17

We report on low operating voltage thin-film transistors (TFTs) and integrated inverters based on copper(I) thiocyanate (CuSCN) layers processed from solution at low temperature on free-standing plastic foils. As-fabricated coplanar bottom-gate and staggered top-gate TFTs exhibit hole-transporting characteristics with average mobility values of 0.0016 cm2 V−1 s−1 and 0.013 cm2 V−1 s−1, respectively, current on/off ratio in the range 102–104, and maximum operating voltages between −3.5 and −10 V, depending on the gate dielectric employed. The promising TFT characteristics enable fabrication of unipolar NOT gates on flexible free-standing plastic substrates with voltage gain of 3.4 at voltages as low as −3.5 V. Importantly, discrete CuSCN transistors and integrated logic inverters remain fully functional even when mechanically bent to a tensile radius of 4 mm, demonstrating the potential of the technology for flexible electronics.

Birefringence and dichroism of poly(vinyl-alcohol) foils containing phthalazinium ylids

Science.gov (United States)

Rogojanu, Alina; Dascalu, Carmen Felicia; Zelinschi, Beatrice Carmen; Caprosu, Maria; Dorohoi, Dana Ortansa

2011-10-01

Pure and colored with phthalazinium ylids poly(vinyl-alcohol) (PVA) foils were stretched under gentile heating. The birefringence of the thin foils was determined with a Babinet compensator standardized for yellow radiation of a Sodium lamp. The determined birefringence of the colored PVA foils is higher than that of the pure PVA foils. This fact indicates that the phthalazinium ylids facilitate the increase in the anisotropy of the stretched foils. The visible absorption electronic band of phthalazinium ylids was used to estimate the dichroic ratio and the degree of order of the ylid molecules in the stretched PVA foils. An increase in dichroism and birefringence with the degree of stretching has been evidenced for uncolored and colored PVA foils.

Method of fabricating a uranium-bearing foil

Science.gov (United States)

Gooch, Jackie G [Seymour, TN; DeMint, Amy L [Kingston, TN

2012-04-24

Methods of fabricating a uranium-bearing foil are described. The foil may be substantially pure uranium, or may be a uranium alloy such as a uranium-molybdenum alloy. The method typically includes a series of hot rolling operations on a cast plate material to form a thin sheet. These hot rolling operations are typically performed using a process where each pass reduces the thickness of the plate by a substantially constant percentage. The sheet is typically then annealed and then cooled. The process typically concludes with a series of cold rolling passes where each pass reduces the thickness of the plate by a substantially constant thickness amount to form the foil.

Effects of crystalline structure in the transmission of ions through thin foils

International Nuclear Information System (INIS)

Archubi, Claudio

2005-01-01

Two fundamental aspects of ion transmission through thin foils are analyzed in this thesis.1) Energy loss.2) Angular distribution.The subject is studied in three different approaches: Theoretically, experimentally and by numerical simulations.In the theoretical approach, the models for the calculation of the energy loss and angular distribution are discussed.They are showed to be unsatisfactory to explain the effects of crystalline structure at low energies.A model is developed to estimate the angular dispersion due to the elastic scattering between the projectile and the target electrons. Simultaneously, angular distribution and energy loss measurements have been performed bombarding polycrystalline and monocrystalline gold and polycrystalline aluminum targets with protons and helium ions with energies in the range of 4-10 keV, together with a detailed study of the foils by electron transmission microscopy techniques.The experimental results are compared with the results of a numerical simulation code, modified and extended in the scope of this thesis.The results show an important influence of crystalline structure and the different targets defects in the angular distribution.This influence is much lower in the case of the angular behaviour of the energy loss (being almost negligible in the case of protons).The most relevant characteristic of the angular behaviour of the energy loss in the case of helium ions is that it is necessary to assume in the simulation method an impact parameter dependence of the stopping coefficient to obtain an agreement between simulation and experimental results [es

Dual-chamber/dual-anode proportional counter incorporating an intervening thin-foil solid neutron converter

International Nuclear Information System (INIS)

Boatner, Lynn A.; Neal, John S.; Blackston, Matthew A.; Kolopus, James A.; Ramey, Joanne O.

2012-01-01

A dual-chamber/dual-anode gas proportional counter utilizing thin solid 6 LiF or 10 B neutron converters coated on a 2-micon-thick Mylar film that is positioned between the two counter chambers and anodes has been designed, fabricated, and tested using a variety of fill gases—including naturally abundant helium. In this device, neutron conversion products emitted from both sides of the coated converter foil are detected—rather than having half of the products absorbed in the wall of a conventional tube-type counter where the solid neutron converter is deposited on the tube wall. Geant4-based radiation transport calculations were used to determine the optimum neutron converter coating thickness for both isotopes. Solution methods for applying these optimized-thickness coatings on a Mylar film were developed that were carried out at room temperature without any specialized equipment and that can be adapted to standard coating methods such as silk screen or ink jet printing. The performance characteristics of the dual-chamber/dual-anode neutron detector were determined for both types of isotopically enriched converters. The experimental performance of the 6 LiF-converter-based detector was described well by modeling results from Geant4. Additional modeling studies of multiple-foil/multiple-chamber/anode configurations addressed the basic issue of the relatively longer absorption range of neutrons versus the shorter range of the conversion products for 6 LiF and 10 B. Combined with the experimental results, these simulations indicate that a high-performance neutron detector can be realized in a single device through the application of these multiple-foil/solid converter, multiple-chamber detector concepts.

Growth and Characterisation of Pulsed-Laser Deposited Tin Thin Films on Cube-Textured Copper at Different Temperatures

Directory of Open Access Journals (Sweden)

Szwachta G.

2016-06-01

Full Text Available High-quality titanium nitride thin films have been grown on a cube-textured copper surface via pulsed laser deposition. The growth of TiN thin films has been very sensitive to pre-treatment procedure and substrate temperature. It is difficult to grow heteroexpitaxial TiN films directly on copper tape due to large differences in lattice constants, thermal expansion coefficients of the two materials as well as polycrystalline structure of substrate. The X-Ray diffraction measurement revealed presence of high peaks belonged to TiN(200 and TiN(111 thin films, depending on used etcher of copper surface. The electron diffraction patterns of TiN(200/Cu films confirmed the single-crystal nature of the films with cube-on-cube epitaxy. The high-resolution microscopy on our films revealed sharp interfaces between copper and titanium nitride with no presence of interfacial reaction.

Fragmentation of copper current collectors in Li-ion batteries during spherical indentation

International Nuclear Information System (INIS)

Wang, Hsin; Watkins, Thomas R.; Simunovic, Srdjan; Bingham, Philip R.; Allu, Srikanth; Turner, John A.

2017-01-01

Large, areal, brittle fracture of copper current collector foils was observed by 3D x-ray computed tomography (XCT) of a spherically indented Li-ion cell. This fracture was hidden and non-catastrophic to a degree because the graphite layers deformed plastically, and held the materials together so that the cracks in the foils could not be seen under optical and electron microscopy. 3D XCT on the indented cell showed “mud cracks” within the copper layer. The cracking of copper foils could not be immediately confirmed when the cell was opened for post-mortem examination. However, an X-ray radiograph on a single foil of the Cu anode showed clearly that the copper foil had broken into multiple pieces similar to the brittle cracking of a ceramic under indentation. This new failure mode of anodes on Li-ion cell has very important implications on the behavior of Li-ion cells under mechanical abuse conditions. Furthermore, the fragmentation of current collectors in the anode must be taken into consideration for the electrochemical responses which may lead to capacity loss and affect thermal runaway behavior of the cells.

Hyaluronan-lecithin foils and their properties

International Nuclear Information System (INIS)

BiaIopiotrowicz, Tomasz; Janczuk, BronisIaw; Fiedorowicz, Maciej; Khachatryan, Gohar; Tomasik, Piotr; Bakos, Dusan

2006-01-01

Thin, elastic foils of good resistance to the air exposure, patented as wound healing aids, were prepared by evaporation of a blend of lecithin (L) and sodium hyaluronan (H) taken under varying proportions. The contact angle for water, glycerol, formamide, ethylene glycol and diiodomethane, was determined for these foils. The contact angle was correlated against the H:L foil composition. For all liquids but formamide the highest contact angle was noted for the H:L = 2:1 (g g -1 ) ratio. The contact angles provided estimation of the work of adhesion. At the same L:H ratio the work of adhesion was the lowest. It was suggested that lecithin cross-linked hyaluronan. Since the work of adhesion of the studied liquids was similar to that of diiodomethane, it could be concluded that almost all functional groups on the foil surface were completely blocked. Perhaps, at H:L = 2:1 (g g -1 ) a stoichiometric complex of hyaluronic acid with lecithin was formed, and polar functional groups from both reagents were involved. Foils seem to be electrostatic complexes of H with L. Foils with the H:L equal to 2:1 exhibited specific properties confirmed by the IR reflectance spectra of the foils. The thermogravimetry (TG/DTG) also revealed unique thermal behaviour confirming other specific properties of the foil of this composition. For the same ratio a thorough inspection of the scanning electron micrographs (SEM) revealed few irregularly distributed perforations of 1-2 μm in diameter seen as black points, which can be recognized as pores. Properties of the foils determined in the contact angle measurements are nicely backed by the results from thermogravimetric and scanning electron microscopic studies

New intensifier foils in roentgenologic diagnostics

Energy Technology Data Exchange (ETDEWEB)

Beyer, H K; Schulze, B

1981-09-01

The main components of the foils are the carrier layer and the luminescent layer, which are in direct contact through an adhesive layer. Carrier layer and adhesive layer absorb and reflect parts of the light. In order to reduce this effect, modern foils are slightly dyed, mostly in the complementary colour of the emitted light. The luminescent layer is attached to the carrier layer by means of a binder. The mean binder content of the luminescent layer is about 10% of the weight of the luminescent material. The particle or crystal range between 5 and 10 ..mu..m. The luminescent layer thickness varies between 0.1 and 0.5 mm, according to the intensification. The imposing with luminescents consequently increases from 20 up to 100 mg/cm/sup 2/. In most cases the luminescent layer is protected by a thin layer (10 to 20 ..mu..m thick) of a very resistant and well-transparent synthetic resin. A foil combination consists of a front and a rear foil, the rear foil often providing a higher degree of intensification than the front foil. Foil quality is mainly defined by the intensification factor, quality on its part is characterized by the modulation transmission function and by the particle structure of the luminescent layer. Quality indicators are also the durability of the foils and the steadiness of the crystal arrangement in the luminescent layer. The representation quality is deteriorated also by the irregular blackening of the roentgen film, resulting from the statistic fluctuations of the roentgen quantums, which are absorbed in the luminescent layer. This unfavourable feature, termed quantum noise, increases with decreasing irradiation intensity, with increasing film gradation, and with increasing sensivity of the film-foil-system. Moreover, an optimal image quality is only possible when film and foil are in good contact conditions (in the cassette).

Optical and infrared spectroscopic studies of chemical sensing by copper phthalocyanine thin films

International Nuclear Information System (INIS)

Singh, Sukhwinder; Tripathi, S.K.; Saini, G.S.S.

2008-01-01

Thin films of copper phthalocyanine have been deposited on KBr and glass substrates by thermal evaporation method and characterized by the X-ray diffraction and optical absorption techniques. The observed X-ray pattern suggests the presence of α crystalline phase of copper phthalocyanine in the as-deposited thin films. Infrared spectra of thin films on the KBr pallet before and after exposure to the vapours of ammonia and methanol have been recorded in the wavenumber region of 400-1650 cm -1 . The observed infrared bands also confirm the α crystalline phase. On exposure, change in the intensity of some bands is observed. A new band at 1385 cm -1 , forbidden under ideal D 4h point group symmetry, is also observed in the spectra of exposed thin films. These changes in the spectra are interpreted in terms of the lowering of molecular symmetry from D 4h to C 4v . Axial ligation of the vapour molecules on fifth coordination site of the metal ion is responsible for lowering of the molecular symmetry

Copper(II) Schiff base complexes and their mixed thin layers with ...

Indian Academy of Sciences (India)

Thin layer; ZnO nanoparticles; copper complexes; AFM; SEM; fluorescence. 1. Introduction ... ZnO nanopowders29,30 and ZnO nanoparticles doped by different metal ...... Roy S, Choubey S, Bhar K, Khan S, Mitra P and Ghosh. B K 2013 J. Mol ...

Investigation of hexagonal boron nitride as an atomically thin corrosion passivation coating in aqueous solution.

Science.gov (United States)

Zhang, Jing; Yang, Yingchao; Lou, Jun

2016-09-09

Hexagonal boron nitride (h-BN) atomic layers were utilized as a passivation coating in this study. A large-area continuous h-BN thin film was grown on nickel foil using a chemical vapor deposition method and then transferred onto sputtered copper as a corrosion passivation coating. The corrosion passivation performance in a Na2SO4 solution of bare and coated copper was investigated by electrochemical methods including cyclic voltammetry (CV), Tafel polarization and electrochemical impedance spectroscopy (EIS). CV and Tafel analysis indicate that the h-BN coating could effectively suppress the anodic dissolution of copper. The EIS fitting result suggests that defects are the dominant leakage source on h-BN films, and improved anti-corrosion performances could be achieved by further passivating these defects.

Investigation into high-frequency-vibration assisted micro-blanking of pure copper foils

Directory of Open Access Journals (Sweden)

Wang Chunju

2015-01-01

Full Text Available The difficulties encountered during the manufacture of microparts are often associated with size effects relating to material, process and tooling. Utilizing acoustoplastic softening, achieved through a high-frequency vibration assisted micro-blanking process, was introduced to improve the surface finish in micro-blanking. A frequency of 1.0 kHz was chosen to activate the longitudinal vibration mode of the horn tip, using a piezoelectric actuator. A square hole with dimensions of 0.5 mm × 0.5 mm was made, successfully, from a commercial rolled T2 copper foil with 100 μm in thickness. It was found that the maximum blanking force could be reduced by 5% through utilizing the high-frequency vibration. Proportion of the smooth, burnished area in the cut cross-section increases with an increase of the plasticity to fracture, under the high-frequency vibration, which suggests that the vibration introduced is helpful for inhibiting evolution of the crack due to its acoustoplastic softening effect. During blanking, roughness of the burnished surface could be reduced by increasing the vibration amplitude of the punch, which played a role as surface polishing. The results obtained suggest that the high-frequency vibration can be adopted in micro-blanking in order to improve quality of the microparts.

CuO nanostructures on copper foil by a simple wet chemical route at room temperature

International Nuclear Information System (INIS)

Jana, S.; Das, S.; Das, N.S.; Chattopadhyay, K.K.

2010-01-01

Uniform CuO nanostructures have been synthesized on copper foil substrates by oxidation of Cu in alkaline condition by a simple wet chemical route at room temperature. By controlling the alkaline condition (pH value) different CuO nanostructures like nanoneedles, self-assembled nanoflowers and staking of flake-like structures were achieved. The phase formation and the composition of the films were characterized by X-ray diffraction and energy dispersive analysis of X-ray studies. X-ray photoelectron spectroscopic studies indicated that the samples were composed of CuO. The morphologies of the films were investigated by scanning electron microscopy. A possible growth mechanism is also proposed here. Band gap energies of the nanostructures were determined from the optical reflectance spectra. The different CuO nanostructures showed good electron field emission properties with turn-on fields in the range 6-11.3 V μm -1 . The field emission current was significantly affected by the morphologies of the CuO films.

Magazine for handling stripping foils in a particle accelerator

International Nuclear Information System (INIS)

Gorka, A.J. Jr.

1975-01-01

Thin foils for stripping a particle beam are stored in a magazine that is operable remotely to display an individual foil, release it when it is spent, and repeat this process. The magazine is operable in the high-vacuum, high-radiation environment in the interior of a particle accelerator, and it uses the magnetic field of the accelerator to operate the display and dropping mechanism. (U.S.)

DYNAMIC PROPERTIES OF SHOCK LOADED THIN URANIUM FOILS

International Nuclear Information System (INIS)

Robbins, D.L.; Kelly, A.M.; Alexander, D.J.; Hanrahan, R.J.; Snow, R.C.; Gehr, R.J.; Rupp, Ted Dean; Sheffield, S.A.; Stahl, D.B.

2001-01-01

A series of spall experiments has been completed with thin depleted uranium targets, nominally 0.1 mm thick. The first set of uranium spall targets was cut and ground to final thickness from electro-refined, high-purity, cast uranium. The second set was rolled to final thickness from low purity uranium. The impactors for these experiments were laser-launched 0.05-mm thick copper flyers, 3 mm in diameter. Laser energies were varied to yield a range of flyer impact velocities. This resulted in varying degrees of damage to the uranium spall targets, from deformation to complete spall or separation at the higher velocities. Dynamic measurements of the uranium target free surface velocities were obtained with dual velocity interferometers. Uranium targets were recovered and sectioned after testing. Free surface velocity profiles were similar for the two types of uranium, but spall strengths (estimated from the magnitude of the pull-back signal) are higher for the high-purity cast uranium. Velocity profiles and microstructural evidence of spall from the sectioned uranium targets are presented.

Convergent beam thickness determination of thin foil zirconium specimens

International Nuclear Information System (INIS)

Cann, C.D.

1978-07-01

The use of convergent beam patterns to determine the thickness of zirconium foils observed in the electron microscope has been investigated both theoretically and experimentally. On the basis of many-beam dynamical theory calculations, the [1012], [1013], and [1120] reflections at an accelerating voltage of 100 kV and the [1013], [1120], and [1122] reflections at 200 kV were found most suitable for convergent beam thickness determinations. Experimental convergent beam patterns were obtained in the JEOL-200B electron microscope under two different sets of conditions based on the size of the pattern desired. Computer assisted analysis of the patterns obtained gave foil thicknesses in good agreement with those determined from thickness extinction contours. (author)

Allotropic effects on the energy loss of swift H+ and He+ ion beams through thin foils

International Nuclear Information System (INIS)

Garcia-Molina, Rafael; Abril, Isabel; Denton, Cristian D.; Heredia-Avalos, Santiago

2006-01-01

We have developed a theoretical treatment and a simulation code to study the energy loss of swift H + and He + ion beams interacting with thin foils of different carbon allotropes. The former is based on the dielectric formalism, and the latter combines Monte Carlo with the numerical solution of the motion equation for each projectile to describe its trajectory and interactions through the target. The capabilities of both methods are assessed by the reasonably good agreement between their predictions and the experimental results, for a wide range of projectile energies and target characteristics. Firstly, we apply the theoretical procedure to calculate the stopping cross sections for H + and He + beams in foils of different allotropic forms of carbon (such as diamond, graphite, amorphous carbon, glassy carbon and C 60 -fullerite), as a function of the projectile energy. We take into account the electronic structure of the projectile, as well as the different charge states it can acquire, the energy loss associated to the electronic capture and loss processes, the polarization of the projectile, and a realistic description of the target. On the other hand, the simulation code is used to evaluate the energy distributions of swift H + and He + ion beams when traversing several foils of the above mentioned allotropic forms of carbon, in order to analyze the influence of the chemical and physical state of the target in the projectile energy loss. These allotropic effects are found to become more important around the maximum of the stopping cross-section

Sensing of volatile organic compounds by copper phthalocyanine thin films

Science.gov (United States)

Ridhi, R.; Saini, G. S. S.; Tripathi, S. K.

2017-02-01

Thin films of copper phthalocyanine have been deposited by thermal evaporation technique. We have subsequently exposed these films to the vapours of methanol, ethanol and propanol. Optical absorption, infrared spectra and electrical conductivities of these films before and after exposure to chemical vapours have been recorded in order to study their sensing mechanisms towards organic vapours. These films exhibit maximum sensing response to methanol while low sensitivities of the films towards ethanol and propanol have been observed. The changes in sensitivities have been correlated with presence of carbon groups in the chemical vapours. The effect of different types of electrodes on response-recovery times of the thin film with organic vapours has been studied and compared. The electrodes gap distance affects the sensitivity as well as response-recovery time values of the thin films.

Surface structure deduced differences of copper foil and film for graphene CVD growth

Energy Technology Data Exchange (ETDEWEB)

Tian, Junjun [School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China); Hu, Baoshan, E-mail: hubaoshan@cqu.edu.cn [School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China); Wei, Zidong; Jin, Yan [School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China); Luo, Zhengtang [Department of Chemical and Biomolecular Engineering, The Hongkong University of Science and Technology, Kowloon (Hong Kong); Xia, Meirong [School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China); Pan, Qingjiang [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080 (China); Liu, Yunling [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)

2014-05-01

Highlights: • We demonstrate the significant differences between Cu foil and film in the surface morphology and crystal orientation distribution. • The different surface structure leads to the distinctive influences of the CH₄ and H₂ concentrations on the thickness and quality of as-grown graphene. • Nucleation densities and growth rate differences at the initial growth stages on the Cu foil and film were investigated and discussed. Abstract: Graphene was synthesized on Cu foil and film by atmospheric pressure chemical vapor deposition (CVD) with CH₄ as carbon source. Electron backscattered scattering diffraction (EBSD) characterization demonstrates that the Cu foil surface after the H₂-assisted pre-annealing was almost composed of Cu(1 0 0) crystal facet with larger grain size of ~100 μm; meanwhile, the Cu film surface involved a variety of crystal facets of Cu(1 1 1), Cu(1 0 0), and Cu(1 1 0), with the relatively small grain size of ~10 μm. The different surface structure led to the distinctive influences of the CH₄ and H₂ concentrations on the thickness and quality of as-grown graphene. Further data demonstrate that the Cu foil enabled more nucleation densities and faster growth rates at the initial growth stages than the Cu film. Our results are beneficial for understanding the relationship between the metal surface structure and graphene CVD growth.

Additional security features for optically variable foils

Science.gov (United States)

Marshall, Allan C.; Russo, Frank

1998-04-01

For thousands of years, man has exploited the attraction and radiance of pure gold to adorn articles of great significance. Today, designers decorate packaging with metallic gold foils to maintain the prestige of luxury items such as perfumes, chocolates, wine and whisky, and to add visible appeal and value to wide range of products. However, today's products do not call for the hand beaten gold leaf of the Ancient Egyptians, instead a rapid production technology exists which makes use of accurately coated thin polymer films and vacuum deposited metallic layers. Stamping Foils Technology is highly versatile since several different layers may be combined into one product, each providing a different function. Not only can a foil bring visual appeal to an article, it can provide physical and chemical resistance properties and also protect an article from human forms of interference, such as counterfeiting, copying or tampering. Stamping foils have proved to be a highly effective vehicle for applying optical devices to items requiring this type of protection. Credit cards, bank notes, personal identification documents and more recently high value packaged items such as software and perfumes are protected by optically variable devices applied using stamping foil technology.

Expeditious low-temperature sintering of copper nanoparticles with thin defective carbon shells

Science.gov (United States)

Kim, Changkyu; Lee, Gyoungja; Rhee, Changkyu; Lee, Minku

2015-04-01

The realization of air-stable nanoparticles, well-formulated nanoinks, and conductive patterns based on copper is a great challenge in low-cost and large-area flexible printed electronics. This work reports the synthesis of a conductively interconnected copper structure via thermal sintering of copper inks at a low temperature for a short period of time, with the help of thin defective carbon shells coated onto the copper nanoparticles. Air-stable copper/carbon core/shell nanoparticles (typical size ~23 nm, shell thickness ~1.0 nm) are prepared by means of an electric explosion of wires. Gaseous oxidation of the carbon shells with a defective structure occurs at 180 °C, impacting the choice of organic solvents as well as the sintering conditions to create a crucial neck formation. Isothermal oxidation and reduction treatment at 200 °C for only about 10 min yields an oxide-free copper network structure with an electrical resistivity of 25.1 μΩ cm (14.0 μΩ cm at 250 °C). Finally, conductive copper line patterns are achieved down to a 50 μm width with an excellent printing resolution (standard deviation ~4.0%) onto a polyimide substrate using screen printing of the optimized inks.The realization of air-stable nanoparticles, well-formulated nanoinks, and conductive patterns based on copper is a great challenge in low-cost and large-area flexible printed electronics. This work reports the synthesis of a conductively interconnected copper structure via thermal sintering of copper inks at a low temperature for a short period of time, with the help of thin defective carbon shells coated onto the copper nanoparticles. Air-stable copper/carbon core/shell nanoparticles (typical size ~23 nm, shell thickness ~1.0 nm) are prepared by means of an electric explosion of wires. Gaseous oxidation of the carbon shells with a defective structure occurs at 180 °C, impacting the choice of organic solvents as well as the sintering conditions to create a crucial neck formation

Automatic spark counting of alpha-tracks in plastic foils

International Nuclear Information System (INIS)

Somogyi, G.; Medveczky, L.; Hunyadi, I.; Nyako, B.

1976-01-01

The possibility of alpha-track counting by jumping spark counter in cellulose acetate and polycarbonate nuclear track detectors was studied. A theoretical treatment is presented which predicts the optimum residual thickness of the etched foils in which completely through-etched tracks (i.e. holes) can be obtained for alpha-particles of various energies and angles of incidence. In agreement with the theoretical prediction it is shown that a successful spark counting of alpha-tracks can be performed even in polycarbonate foils. Some counting characteristics, such as counting efficiency vs particle energy at various etched foil thicknesses, surface spark density produced by electric breakdowns in unexposed foils vs foil thickness, etc. have been determined. Special attention was given to the spark counting of alpha-tracks entering thin detectors at right angle. The applicability of the spark counting technique is demonstrated in angular distribution measurements of the 27 Al(p,α 0 ) 24 Mg nuclear reaction at Ep = 1899 keV resonance energy. For this study 15 μm thick Makrofol-G foils and a jumping spark counter of improved construction were used. (orig.) [de

Secondary electron emission of thin carbon foils under the impact of hydrogen atoms, ions and molecular ions, under energies within the MeV range

International Nuclear Information System (INIS)

Vidovic, Z.

1997-06-01

This work focuses on the study of the emission statistics of secondary electrons from thin carbon foils bombarded with H 0 , H 2 + and H 3 + projectiles in the 0.25-2.2 MeV energy range. The phenomenon of secondary electron emission from solids under the impact of swift ions is mainly due to inelastic interactions with target electrons. The phenomenological and theoretical descriptions, as well as a summary of the main theoretical models are the subject of the first chapter. The experimental set-up used to measure event by event the electron emission of the two faces of a thin carbon foil traversed by an energetic projectile is described in the chapter two. In this chapter are also presented the method and algorithms used to process experimental spectra in order to obtain the statistical distribution of the emitted electrons. Chapter three presents the measurements of secondary electron emission induced by H atoms passing through thin carbon foils. The secondary electron yields are studied in correlation with the emergent projectile charge state. We show the peculiar role of the projectile electron, whether it remains or not bound to the incident proton. The fourth chapter is dedicated to the secondary electron emission induced by H 2 + and H 3 + polyatomic ions. The results are interpreted in terms of collective effects in the interactions of these ions with solids. The role of the proximity of the protons, molecular ion fragments, upon the amplitude of these collective effects is evidenced from the study of the statistics of forward emission. These experiences allowed us to shed light on various aspects of atom and polyatomic ion inter-actions with solid surfaces. (author)

Tension Tests of Copper Thin Films

Energy Technology Data Exchange (ETDEWEB)

Park, Kyung Jo; Kim, Chung Youb [Chonnam Nat’l Univ., Gwangju (Korea, Republic of)

2017-08-15

Tension tests for copper thin films with thickness of 12 μm were performed by using a digital image correlation method based on consecutive digital images. When calculating deformation using digital image correlation, a large deformation causes errors in the calculated result. In this study, the calculation procedure was improved to reduce the error, so that the full field deformation and the strain of the specimen could be accurately and directly measured on its surface. From the calculated result, it can be seen that the strain distribution is not uniform and its variation is severe, unlike the distribution in a common bulk specimen. This might result from the surface roughness introduced in the films during the fabrication process by electro-deposition.

The effect of the cooling rate during quenching, electron bombardment and plastic deformation on the kinetics of a solid solution disintegration in iron-copper alloys

International Nuclear Information System (INIS)

Fedorov, G.B.; Zhukov, V.P.; Braun, A.G.; Smirnov, E.A.

1974-01-01

From the electroresistivity variation at 77 0 K, the influence of nonequilibrium point defect density and of complexes and dislocations on the decay process of the iron-copper solid solution is determined. Owing to high quenching rate of thin foils, isochrones of their electroconductivity curves appear shifted by about 200 0 C to lower temperatures. For quenched and irradiated specimens at 200-250 0 C a sharp retardation of electroconductivity decline is observed due to a zone stage. The plastic deformation (15%) leads to a partial suppression of that stage. Both irradiation and deformation initiate the process of copper separation from the solid solution, the latter being the stronger, the more copper is in the solid solution

Bi-Directional Ion Emission from Massive Gold Cluster Impacts on Nanometric Carbon Foils

OpenAIRE

DeBord, J. Daniel; Della-Negra, Serge; Fernandez-Lima, Francisco A.; Verkhoturov, Stanislav V.; Schweikert, Emile A.

2012-01-01

Carbon cluster emission from thin carbon foils (5–40 nm) impacted by individual Aun+q cluster projectiles (95–125 qkeV, n/q = 3–200) reveals features regarding the energy deposition, projectile range, and projectile fate in matter as a function of the projectile characteristics. For the first time, the secondary ion emission from thin foils has been monitored simultaneously in both forward and backward emission directions. The projectile range and depth of emission were examined as a function...

Charged-particle acceleration through laser irradiation of thin foils at Prague Asterix Laser System

International Nuclear Information System (INIS)

Torrisi, Lorenzo; Cutroneo, Maria; Cavallaro, Salvatore; Musumeci, Paolo; Calcagno, Lucia; Wolowski, Jerzy; Rosinski, Marcin; Zaras-Szydlowska, Agnieszka; Ullschmied, Jiri; Krousky, Eduard; Pfeifer, Miroslav; Skala, Jiri; Velyhan, Andreiy

2014-01-01

Thin foils, 0.5–50 μm in thickness, have been irradiated in vacuum at Prague Asterix Laser System in Prague using 10 15–16  W cm −2 laser intensity, 1315 nm wavelength, 300 ps pulse duration and different focal positions. Produced plasmas from metals and polymers films have been monitored in the forward and backward directions. Ion and electron accelerations have been investigated by using Thomson parabola spectrometer, x-ray streak camera, ion collectors and SiC semiconductor detectors, the latter employed in time-of-flight configuration. Ion acceleration up to about 3 MeV per charge state was measured in the forward direction. Ion and electron emissions were detected at different angles as a function of the irradiation conditions. (paper)

Large-area thin self-supporting carbon foils with MgO coatings

Science.gov (United States)

Stolarz, Anna; Maier-Komor, Peter

2002-03-01

Large area self-supporting carbon foils in the thickness of range of 8-22 μg/cm 2, coated with approximately 4 μg/cm 2 MgO have been prepared by e-gun evaporation. They were mounted on frames with apertures of 130 cm 2. Problems related to the parting agent preparation, floating procedure, and mounting onto frames are discussed. Special precautions necessary to avoid damage during foil drying, storage and transportation are suggested.

Process for forming a nickel foil with controlled and predetermined permeability to hydrogen

Science.gov (United States)

Engelhaupt, Darell E.

1981-09-22

The present invention provides a novel process for forming a nickel foil having a controlled and predetermined hydrogen permeability. This process includes the steps of passing a nickel plating bath through a suitable cation exchange resin to provide a purified nickel plating bath free of copper and gold cations, immersing a nickel anode and a suitable cathode in the purified nickel plating bath containing a selected concentration of an organic sulfonic acid such as a napthalene-trisulfonic acid, electrodepositing a nickel layer having the thickness of a foil onto the cathode, and separating the nickel layer from the cathode to provide a nickel foil. The anode is a readily-corrodible nickel anode. The present invention also provides a novel nickel foil having a greater hydrogen permeability than palladium at room temperature.

Process for forming a nickel foil with controlled and predetermined permeability to hydrogen

International Nuclear Information System (INIS)

Engelhaupt, D. E.

1981-01-01

The present invention provides a novel process for forming a nickel foil having a controlled and predetermined hydrogen permeability. This process includes the steps of passing a nickel plating bath through a suitable cation exchange resin to provide a purified nickel plating bath free of copper and gold cations, immersing a nickel anode and a suitable cathode in the purified nickel plating bath containing a selected concentration of an organic sulfonic acid such as a napthalene-trisulfonic acid, electrodepositing a nickel layer having the thickness of a foil onto the cathode, and separating the nickel layer from the cathode to provide a nickel foil. The anode is a readilycorrodible nickel anode. The present invention also provides a novel nickel foil having a greater hydrogen permeability than palladium at room temperature

Large-area thin self-supporting carbon foils with MgO coatings

CERN Document Server

Stolarz, A

2002-01-01

Large area self-supporting carbon foils in the thickness of range of 8-22 mu g/cm sup 2 , coated with approximately 4 mu g/cm sup 2 MgO have been prepared by e-gun evaporation. They were mounted on frames with apertures of 130 cm sup 2. Problems related to the parting agent preparation, floating procedure, and mounting onto frames are discussed. Special precautions necessary to avoid damage during foil drying, storage and transportation are suggested.

Large-area thin self-supporting carbon foils with MgO coatings

Energy Technology Data Exchange (ETDEWEB)

Stolarz, Anna E-mail: anna@slcj.uw.edu.pl; Maier-Komor, Peter

2002-03-11

Large area self-supporting carbon foils in the thickness of range of 8-22 {mu}g/cm{sup 2}, coated with approximately 4 {mu}g/cm{sup 2} MgO have been prepared by e-gun evaporation. They were mounted on frames with apertures of 130 cm{sup 2}. Problems related to the parting agent preparation, floating procedure, and mounting onto frames are discussed. Special precautions necessary to avoid damage during foil drying, storage and transportation are suggested.

Dry Etching of Copper Phthalocyanine Thin Films: Effects on Morphology and Surface Stoichiometry

Directory of Open Access Journals (Sweden)

Michael J. Brett

2012-08-01

Full Text Available We investigate the evolution of copper phthalocyanine thin films as they are etched with argon plasma. Significant morphological changes occur as a result of the ion bombardment; a planar surface quickly becomes an array of nanopillars which are less than 20 nm in diameter. The changes in morphology are independent of plasma power, which controls the etch rate only. Analysis by X-ray photoelectron spectroscopy shows that surface concentrations of copper and oxygen increase with etch time, while carbon and nitrogen are depleted. Despite these changes in surface stoichiometry, we observe no effect on the work function. The absorbance and X-ray diffraction spectra show no changes other than the peaks diminishing with etch time. These findings have important implications for organic photovoltaic devices which seek nanopillar thin films of metal phthalocyanine materials as an optimal structure.

Properties of Spray Pyrolysied Copper Oxide Thin Films

Directory of Open Access Journals (Sweden)

S. S. Roy

2017-02-01

Full Text Available Copper oxide (CuO thin films were deposited on well cleaned glass substrates by spray pyrolysis technique (SPT from cupric acetate (Cu(CH3COO2.H2O precursor solutions of 0.05 – 0.15 M molar concentrations (MC at a substrate temperature of 350 °C and at an air pressure of 1 bar. Effect of varying MC on the surface morphology, structural optical and electrical properties of CuO thin films were investigated. XRD patterns of the prepared films revealed the formation of CuO thin films having monoclinic structure with the main CuO (111 orientation and crystalline size ranging from 8.02 to 9.05 nm was observed. The optical transmission of the film was found to decrease with the increase of MC. The optical band gap of the thin films for 0.10 M was fond to be 1.60 eV. The room temperature electrical resistivity varies from 31 and 24 ohm.cm for the films grown with MC of 0.05 and 0.10 M respectively. The change in resistivity of the films was studied with respect to the change in temperature was shown that semiconductor nature is present. This information is expected to underlie the successful development of CuO films for solar windows and other semi-conductor applications including gas sensors.

Foil focusing of relativistic electron beams

Energy Technology Data Exchange (ETDEWEB)

Ekdahl, Jr., Carl August [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2017-10-26

When an intense relativistic electron beams (IREB) passes through a grounded metal foil, the transverse electric field due to the beam space charge is locally shorted out, and the beam is focused by the magnetic field of its current. The effect can be treated as focusing by a thin lens with first order aberration. Expressions for the focal length and aberration coefficient of the equivalent thin lens are developed in this note. These are then applied to practical examples representative of IREB research at Los Alamos National Laboratory.

Dissociation of fast HeH+ ions in foils and gases

International Nuclear Information System (INIS)

Gemmell, D.S.; Cooney, P.J.; Pietsch, W.J.; Ratkowski, A.J.; Vager, Z.

1978-01-01

To gain understanding of phenomena observed when very simple light diatomic ions are incident at high velocities upon thin foils and gaseous targets, an extensive set of measurements on the dissociation products arising from beams of HeH + was made. Experimental and calculated joint distributions in energy and angle for protons emerging (near the beam direction) from an 85-A carbon foil bombarded by 2.0-MeV HeH + ions are presented

Effect of copper concentration on the physical properties of copper doped NiO thin films deposited by spray pyrolysis

Energy Technology Data Exchange (ETDEWEB)

Mani Menaka, S., E-mail: manimenaka.phy@gmail.com [PG and Research Department of Physics, Government Arts College, Coimbatore, 641018, Tamilnadu (India); Umadevi, G. [PG and Research Department of Physics, Government Arts College, Coimbatore, 641018, Tamilnadu (India); Manickam, M. [SRMV College of Arts and Science, Coimbatore, 641020, Tamilnadu (India)

2017-04-15

The spray pyrolysis (SP) technique is an important and powerful method for the preparation of nickel oxide (NiO) and copper-doped nickel oxide thin films. The best films were obtained when the substrate temperature, T{sub s} = 450 °C on glass substrates. Copper (Cu) concentrations in the films were varied from 0 to 8%. The effect of Cu concentration on the structural, morphological, spectral, optical, and electrical properties of the thin films were studied by X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier transformed infrared spectroscopy (FTIR), UV–vis–NIR spectrophotometer, Hot probe and Hall system. The X-ray diffraction result shows the polycrystalline cubic structure of sprayed films with (200) preferred orientation. The variations of the structural parameters such as lattice parameters and grain sizes were investigated. The SEM image displays the surface morphology of the NiO and Cu:NiO thin films. The FTIR of the as-deposited films were associated with chemical identification. The optical transmittance and absorbance spectra of the films were measured by UV–vis–NIR spectrophotometer. The absorption coefficient and band gaps of the films were calculated using the optical method. All the NiO and Cu:NiO films were p-type. The resistivity of the above films decreases with the increase in copper concentration and so the conductivity of the films depend on the precursor concentration. - Highlights: • Pure and Cu:NiO films were deposited by Spray pyrolysis technique. • The XRD result shows the polycrystalline nature of pure and Cu:NiO films. • The formation of pure and Cu:NiO were confirmed by FTIR analysis. • Band gap values of pure and Cu:NiO decreases. • All the pure and Cu:NiO films were p-type.

Effect of copper concentration on the physical properties of copper doped NiO thin films deposited by spray pyrolysis

International Nuclear Information System (INIS)

Mani Menaka, S.; Umadevi, G.; Manickam, M.

2017-01-01

The spray pyrolysis (SP) technique is an important and powerful method for the preparation of nickel oxide (NiO) and copper-doped nickel oxide thin films. The best films were obtained when the substrate temperature, T_s = 450 °C on glass substrates. Copper (Cu) concentrations in the films were varied from 0 to 8%. The effect of Cu concentration on the structural, morphological, spectral, optical, and electrical properties of the thin films were studied by X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier transformed infrared spectroscopy (FTIR), UV–vis–NIR spectrophotometer, Hot probe and Hall system. The X-ray diffraction result shows the polycrystalline cubic structure of sprayed films with (200) preferred orientation. The variations of the structural parameters such as lattice parameters and grain sizes were investigated. The SEM image displays the surface morphology of the NiO and Cu:NiO thin films. The FTIR of the as-deposited films were associated with chemical identification. The optical transmittance and absorbance spectra of the films were measured by UV–vis–NIR spectrophotometer. The absorption coefficient and band gaps of the films were calculated using the optical method. All the NiO and Cu:NiO films were p-type. The resistivity of the above films decreases with the increase in copper concentration and so the conductivity of the films depend on the precursor concentration. - Highlights: • Pure and Cu:NiO films were deposited by Spray pyrolysis technique. • The XRD result shows the polycrystalline nature of pure and Cu:NiO films. • The formation of pure and Cu:NiO were confirmed by FTIR analysis. • Band gap values of pure and Cu:NiO decreases. • All the pure and Cu:NiO films were p-type.

A new, simple and precise method for measuring cyclotron proton beam energies using the activity vs. depth profile of zinc-65 in a thick target of stacked copper foils

International Nuclear Information System (INIS)

Asad, A.H.; Chan, S.; Cryer, D.; Burrage, J.W.; Siddiqui, S.A.; Price, R.I.

2015-01-01

The proton beam energy of an isochronous 18 MeV cyclotron was determined using a novel version of the stacked copper-foils technique. This simple method used stacked foils of natural copper forming ‘thick’ targets to produce Zn radioisotopes by the well-documented (p,x) monitor-reactions. Primary beam energy was calculated using the "6"5Zn activity vs. depth profile in the target, with the results obtained using "6"2Zn and "6"3Zn (as comparators) in close agreement. Results from separate measurements using foil thicknesses of 100, 75, 50 or 25 µm to form the stacks also concurred closely. Energy was determined by iterative least-squares comparison of the normalized measured activity profile in a target-stack with the equivalent calculated normalized profile, using ‘energy’ as the regression variable. The technique exploits the uniqueness of the shape of the activity vs. depth profile of the monitor isotope in the target stack for a specified incident energy. The energy using "6"5Zn activity profiles and 50-μm foils alone was 18.03±0.02 [SD] MeV (95%CI=17.98–18.08), and 18.06±0.12 MeV (95%CI=18.02–18.10; NS) when combining results from all isotopes and foil thicknesses. When the beam energy was re-measured using "6"5Zn and 50-μm foils only, following a major upgrade of the ion sources and nonmagnetic beam controls the results were 18.11±0.05 MeV (95%CI=18.00–18.23; NS compared with ‘before’). Since measurement of only one Zn monitor isotope is required to determine the normalized activity profile this indirect yet precise technique does not require a direct beam-current measurement or a gamma-spectroscopy efficiency calibrated with standard sources, though a characteristic photopeak must be identified. It has some advantages over published methods using the ratio of cross sections of monitor reactions, including the ability to determine energies across a broader range and without need for customized beam degraders. - Highlights: • Simple

Substrate considerations for graphene synthesis on thin copper films

International Nuclear Information System (INIS)

Howsare, Casey A; Robinson, Joshua A; Weng Xiaojun; Bojan, Vince; Snyder, David

2012-01-01

Chemical vapor deposition on copper substrates is a primary technique for synthesis of high quality graphene films over large areas. While well-developed processes are in place for catalytic growth of graphene on bulk copper substrates, chemical vapor deposition of graphene on thin films could provide a means for simplified device processing through the elimination of the layer transfer process. Recently, it was demonstrated that transfer-free growth and processing is possible on SiO 2 . However, the Cu/SiO 2 /Si material system must be stable at high temperatures for high quality transfer-free graphene. This study identifies the presence of interdiffusion at the Cu/SiO 2 interface and investigates the influence of metal (Ni, Cr, W) and insulating (Si 3 N 4 , Al 2 O 3 , HfO 2 ) diffusion barrier layers on Cu–SiO 2 interdiffusion, as well as graphene structural quality. Regardless of barrier choice, we find the presence of Cu diffusion into the silicon substrate as well as the presence of Cu–Si–O domains on the surface of the copper film. As a result, we investigate the choice of a sapphire substrate and present evidence that it is a robust substrate for synthesis and processing of high quality, transfer-free graphene. (paper)

Effects of vacuum annealing on the optical and electrical properties of p-type copper-oxide thin-film transistors

International Nuclear Information System (INIS)

Sohn, Joonsung; Song, Sang-Hun; Kwon, Hyuck-In; Nam, Dong-Woo; Cho, In-Tak; Lee, Jong-Ho; Cho, Eou-Sik

2013-01-01

We have investigated the effects of vacuum annealing on the optical and electrical properties of the p-type copper-oxide thin-film transistors (TFTs). The vacuum annealing of the copper-oxide thin-film was performed using the RF magnetron sputter at various temperatures. From the x-ray diffraction and UV-vis spectroscopy, it is demonstrated that the high-temperature vacuum annealing reduces the copper-oxide phase from CuO to Cu 2 O, and increases the optical transmittance in the visible part of the spectrum. The fabricated copper-oxide TFT does not exhibit the switching behavior under low-temperature vacuum annealing conditions. However, as the annealing temperature increases, the drain current begins to be modulated by a gate voltage, and the TFT exhibits a high current on–off ratio over 10 4 as the vacuum annealing temperature increases over 450 °C. These results show that the vacuum annealing process can be an effective method of simultaneously improving the optical and electrical performances in p-type copper-oxide TFTs. (paper)

Intense heavy ion beam-induced effects in carbon-based stripper foils

Energy Technology Data Exchange (ETDEWEB)

Kupka, Katharina

2016-08-15

Amorphous carbon or carbon-based stripper foils are commonly applied in accelerator technology for electron stripping of ions. At the planned facility for antiproton and ion research (FAIR) at the Helmholtzzentrum fuer Schwerionenforschung (GSI), Darmstadt, thin carbon stripper foils provide an option for directly delivering ions of intermediate charge states to the heavy ion synchrotron, SIS 18, in order to mitigate space charge limitations during high-intensity operation. In case of desired high end-energies in the synchrotron, a second stripping process by a thicker carbon foil provides ions of higher charge states for injection into the SIS18. High beam intensities and a pulsed beam structure as foreseen at FAIR pose new challenges to the stripper foils which experience enhanced degradation by radiation damage, thermal effects, and stress waves. In order to ensure reliable accelerator operation, radiation-hard stripper foils are required. This thesis aims to a better understanding of processes leading to degradation of carbon-based thin foils. Special focus is placed on ion-beam induced structure and physical property changes and on the influence of different beam parameters. Irradiation experiments were performed at the M3-beamline of the universal linear accelerator (UNILAC) at GSI, using swift heavy ion beams with different pulse lengths and repetition rates. Tested carbon foils were standard amorphous carbon stripper foils produced by the GSI target laboratory, as well as commercial amorphous and diamond-like carbon foils and buckypaper foils. Microstructural changes were investigated with various methods such as optical microscopy, scanning electron microscopy (SEM), profilometry and chromatic aberration measurements. For the investigation of structural changes X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, high resolution transmission electron microscopy (HRTEM), in-situ Fourier-transform infrared spectroscopy (FTIR) and small angle X

Intense heavy ion beam-induced effects in carbon-based stripper foils

International Nuclear Information System (INIS)

Kupka, Katharina

2016-08-01

Amorphous carbon or carbon-based stripper foils are commonly applied in accelerator technology for electron stripping of ions. At the planned facility for antiproton and ion research (FAIR) at the Helmholtzzentrum fuer Schwerionenforschung (GSI), Darmstadt, thin carbon stripper foils provide an option for directly delivering ions of intermediate charge states to the heavy ion synchrotron, SIS 18, in order to mitigate space charge limitations during high-intensity operation. In case of desired high end-energies in the synchrotron, a second stripping process by a thicker carbon foil provides ions of higher charge states for injection into the SIS18. High beam intensities and a pulsed beam structure as foreseen at FAIR pose new challenges to the stripper foils which experience enhanced degradation by radiation damage, thermal effects, and stress waves. In order to ensure reliable accelerator operation, radiation-hard stripper foils are required. This thesis aims to a better understanding of processes leading to degradation of carbon-based thin foils. Special focus is placed on ion-beam induced structure and physical property changes and on the influence of different beam parameters. Irradiation experiments were performed at the M3-beamline of the universal linear accelerator (UNILAC) at GSI, using swift heavy ion beams with different pulse lengths and repetition rates. Tested carbon foils were standard amorphous carbon stripper foils produced by the GSI target laboratory, as well as commercial amorphous and diamond-like carbon foils and buckypaper foils. Microstructural changes were investigated with various methods such as optical microscopy, scanning electron microscopy (SEM), profilometry and chromatic aberration measurements. For the investigation of structural changes X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, high resolution transmission electron microscopy (HRTEM), in-situ Fourier-transform infrared spectroscopy (FTIR) and small angle X

A study of molecular effects in beam-foil spectroscopy

International Nuclear Information System (INIS)

Andresen, B.; Veje, E.

1979-01-01

Relative populations of ns + nd levels in hydrogen as functions of the principal quantum number n have been measured with beams of H + , H 2 + , and H 3 + impinging on thin carbon foils at 25 keV/amu and 100 keV/amu. Enhancements of 20% and 45% for dimer and trimer clusters are observed uniformly for all levels. A possible explanation in terms of screening of the Coulomb repulsion between the protons inside the foil, thus reducing the effective thickness of the foil, is given. All relative populations closely follow an nsup(P) power law with p = -4.0 and -3.7 at 25 keV/amu and 100 keV/amu, respectively, in perfect analogy with atomic collision experiments. O + /O 2 + -foil excitations at 100 keV and 155 keV show a simular molecular effect, but in reverse with a larger mean charge produced by the dimer. (Auth.)

Effect of native oxide layers on copper thin-film tensile properties: A reactive molecular dynamics study

Energy Technology Data Exchange (ETDEWEB)

Skarlinski, Michael D., E-mail: michael.skarlinski@rochester.edu [Materials Science Program, University of Rochester, Rochester, New York 14627 (United States); Quesnel, David J. [Materials Science Program, University of Rochester, Rochester, New York 14627 (United States); Department of Mechanical Engineering, University of Rochester, Rochester, New York 14627 (United States)

2015-12-21

Metal-oxide layers are likely to be present on metallic nano-structures due to either environmental exposure during use, or high temperature processing techniques such as annealing. It is well known that nano-structured metals have vastly different mechanical properties from bulk metals; however, difficulties in modeling the transition between metallic and ionic bonding have prevented the computational investigation of the effects of oxide surface layers. Newly developed charge-optimized many body [Liang et al., Mater. Sci. Eng., R 74, 255 (2013)] potentials are used to perform fully reactive molecular dynamics simulations which elucidate the effects that metal-oxide layers have on the mechanical properties of a copper thin-film. Simulated tensile tests are performed on thin-films while using different strain-rates, temperatures, and oxide thicknesses to evaluate changes in yield stress, modulus, and failure mechanisms. Findings indicate that copper-thin film mechanical properties are strongly affected by native oxide layers. The formed oxide layers have an amorphous structure with lower Cu-O bond-densities than bulk CuO, and a mixture of Cu{sub 2}O and CuO charge character. It is found that oxidation will cause modifications to the strain response of the elastic modulii, producing a stiffened modulii at low temperatures (<75 K) and low strain values (<5%), and a softened modulii at higher temperatures. While under strain, structural reorganization within the oxide layers facilitates brittle yielding through nucleation of defects across the oxide/metal interface. The oxide-free copper thin-film yielding mechanism is found to be a tensile-axis reorientation and grain creation. The oxide layers change the observed yielding mechanism, allowing for the inner copper thin-film to sustain an FCC-to-BCC transition during yielding. The mechanical properties are fit to a thermodynamic model based on classical nucleation theory. The fit implies that the oxidation of the

Deposition of thermal and hot-wire chemical vapor deposition copper thin films on patterned substrates.

Science.gov (United States)

Papadimitropoulos, G; Davazoglou, D

2011-09-01

In this work we study the hot-wire chemical vapor deposition (HWCVD) of copper films on blanket and patterned substrates at high filament temperatures. A vertical chemical vapor deposition reactor was used in which the chemical reactions were assisted by a tungsten filament heated at 650 degrees C. Hexafluoroacetylacetonate Cu(I) trimethylvinylsilane (CupraSelect) vapors were used, directly injected into the reactor with the aid of a liquid injection system using N2 as carrier gas. Copper thin films grown also by thermal and hot-wire CVD. The substrates used were oxidized silicon wafers on which trenches with dimensions of the order of 500 nm were formed and subsequently covered with LPCVD W. HWCVD copper thin films grown at filament temperature of 650 degrees C showed higher growth rates compared to the thermally ones. They also exhibited higher resistivities than thermal and HWCVD films grown at lower filament temperatures. Thermally grown Cu films have very uniform deposition leading to full coverage of the patterned substrates while the HWCVD films exhibited a tendency to vertical growth, thereby creating gaps and incomplete step coverage.

Measurements of direct drive laser imprint in thin foils by radiography using an x-ray laser backlighter

International Nuclear Information System (INIS)

Kalantar, D.H.; Key, M.H.; Da Silva, L.B.; Glendinning, S.G.; Remington, B.A.; Rothenberg, J.E.; Weber, F.; Weber, S.V.; Wolfrum, E.; Kim, N.S.; Neely, D.; Zhang, J.; Wark, J.S.; Demir, A.; Lin, J.; Smith, R.; Tallents, G.J.; Lewis, C.L.; MacPhee, A.; Warwick, J.; Knauer, J.P.

1997-01-01

In direct drive inertial confinement fusion, the residual speckle pattern remaining after beam smoothing plays an important role in the seeding of instabilities at the ablation front. An x-ray laser is used as an extreme ultraviolet backlighter to characterize the imprinted modulation in thin foils for smoothing by random phase plate and by spectral dispersion for both 0.35 and 0.53 μm irradiation, and by induced spatial incoherence for 0.53 μm irradiation. Measurements of the imprinted modulation due to a single optical mode generated by two beam interference, and modification of the imprint with a superposed smooth irradiation to study time dependence of the imprinting process are demonstrated. copyright 1997 American Institute of Physics

Temperature dependence of the beam-foil interaction

International Nuclear Information System (INIS)

Gay, T.J.; Berry, H.G.

1978-01-01

The beam energy dependence between 50 and 200 keV of the linear polarization fraction (M/I) of the 2s 1 S--3p 1 P, 5016 A transition in He I on temperature was measured. The thin carbon exciter foils were heated externally by nichrome resistance elements. The measurements of Hight et al. are duplicated; the energy and current dependences are the same for corresponding between beam heating and external heating. It was also observed that γ, the number of slow secondary electrons produced per incident ion, decreases with increasing foil temperature. These two effects, in conjunction, offer a plausible explanation for the variation of polarization with beam current density. 5 figures

Highly sensitive urea sensing with ion-irradiated polymer foils

International Nuclear Information System (INIS)

Fink, Dietmar; Muñoz Hernandez, Gerardo; Alfonta, Lital

2012-01-01

Recently we prepared urea-sensors by attaching urease to the inner walls of etched ion tracks within thin polymer foil. Here, alternative track-based sensor configurations are examined where the enzyme remained in solution. The conductivities of systems consisting of two parallel irradiated polymer foils and confining different urea/urease mixtures in between were examined. The correlations between conductivity and urea concentration differed strongly for foils with unetched and etched tracks, which points at different sensing mechanisms – tentatively attributed to the adsorption of enzymatic reaction products on the latent track entrances and to the enhanced conductivity of reaction product-filled etched tracks, respectively. All examined systems enable in principle, urea sensing. They point at the possibility of sensor cascade construction for more sensitive or selective sensor systems.

Study of copper doping effects on structural, optical and electrical properties of sprayed ZnO thin films

International Nuclear Information System (INIS)

Mhamdi, A.; Mimouni, R.; Amlouk, A.; Amlouk, M.; Belgacem, S.

2014-01-01

Highlights: • The sprayed Cu-doped ZnO thin layers films were well crystallised in hexagonal wurtzite phase. • Nanoncrystallites on clusters were observed whose density decreases especially at 2% Cu content. • This parallel circuit R–C represents the contribution of the grain boundaries delineating the oriented columnar microcrystallites along c-axis. - Abstract: Copper-doped zinc oxide thin films (ZnO:Cu) at different percentages (1–3%) were deposited on glass substrates using a chemical spray technique. The effect of Cu concentration on the structural, morphology and optical properties of the ZnO:Cu thin films were investigated. XRD analysis revealed that all films consist of single phase ZnO and were well crystallised in würtzite phase with the crystallites preferentially oriented towards (0 0 2) direction parallel to c-axis. The Film surface was analyzed by contact atomic force microscopy (AFM) in order to understand the effect of the doping on the surface structure. Doping by copper resulted in a slight decrease in the optical band gap energy of the films and a noticeably change in optical constants. From the spectroscopy impedance analysis we investigated the frequency relaxation phenomenon and the circuit equivalent circuit of such thin layers. Finally, all results have been discussed in terms of the copper doping concentration

Bi-Directional Ion Emission from Massive Gold Cluster Impacts on Nanometric Carbon Foils.

Science.gov (United States)

Debord, J Daniel; Della-Negra, Serge; Fernandez-Lima, Francisco A; Verkhoturov, Stanislav V; Schweikert, Emile A

2012-04-12

Carbon cluster emission from thin carbon foils (5-40 nm) impacted by individual Au(n) (+q) cluster projectiles (95-125 qkeV, n/q = 3-200) reveals features regarding the energy deposition, projectile range, and projectile fate in matter as a function of the projectile characteristics. For the first time, the secondary ion emission from thin foils has been monitored simultaneously in both forward and backward emission directions. The projectile range and depth of emission were examined as a function of projectile size, energy, and target thickness. A key finding is that the massive cluster impact develops very differently from that of a small polyatomic projectile. The range of the 125 qkeV Au(100q) (+q) (q ≈ 4) projectile is estimated to be 20 nm (well beyond the range of an equal velocity Au(+)) and projectile disintegration occurs at the exit of even a 5 nm thick foil.

Mode-locking of an InAs Quantum Dot Based Vertical External Cavity Surface Emitting Laser Using Atomic Layer Graphene

Science.gov (United States)

2015-07-16

catalyzed on either a copper foil or on nickel coated substrates. The graphene must be transferred off of these substrates and then on to the DBR/spacer to...properties of graphene in both the exfoliated single layer graphene (SLG) and few layer graphene (FLG) flakes . Sun et al. make use of bile salts to...semiconductors and dielectrics is the transfer of CVD graphene grown on copper foils. The graphene is grown on thin Cu-foils by CVD using methane and

An ice rink refrigeration system based on CO{sub 2} as secondary fluid in copper tubes

Energy Technology Data Exchange (ETDEWEB)

Shahzad, Khuram [Royal Inst. of Technology, Stockholrn (Sweden). Dept. of Energy Technology

2006-06-15

This report is a study of the use of copper tubes with CO{sub 2} as heat transfer fluid in ice rink applications. Copper tubes can be rolled rather easily up to the required length which decreases installation cost and simplifies the procedure. A test ice rink was built at IUC Ref Centre, Katrineholm with copper tubes. FEMLAB and EES are two softwares that were used for analysis. The comparison between 12.7 mm diameter copper tubes with and without plastic foil cover, 9.5 mm diameter copper tubes with and without plastic foil cover, 21.3 mm diameter steel pipes and 25 mm diameter plastic pipes is presented in the report. The reason to have plastic foil over copper tubes is to avoid the minor risk of chemical corrosion. Furthermore the foil serves as mechanical wear protection as well, which in this case could appear if rubbing would occur due to thermal expansion and contraction. It is found that 12.7 mm copper tube with plastic foil is good choice in terms of heat transfer. At rated heat flux of 100 W/m{sup 2} and with a pitch of 100 mm, it is 0.18 deg C better than 9.5 mm copper tube with plastic foil. This report includes the investigation which shows that there is no danger of movement of copper tubes inside the rink bed due to thermal expansion and contraction during operation. It also includes the comparison of average Friedel pressure drop model and average homogeneous pressure drop model with experimental results. Average Friedel pressure drop method gave good results. It predicted 20 to 25 % higher pressure drop at lower CR and about 60 % at higher CR than the experimental results for 120 meter long and 12.7 mm diameter copper tubes. 120 meter long copper tubes are good choice; as header can be placed on short side of the ice rink. It will reduce the header length and connections to half. FEMLAB modelling for conduction heat transfer gave good results and can be used as a tool for design and optimization. The optimization of the pitch of the copper tubes

Microcutting and forming of thin aluminium foils for MEMS

DEFF Research Database (Denmark)

Damsgaard, Christian Danvad; Mortensen, Dennis; Rombach, Pirmin

2011-01-01

. The relation between applied pressure and forming and cutting features has been characterized for a specific set of stamp geometries and boundary conditions. The results show that 10 μm forming features can be transferred to 4 m thick Al foils, which simultaneously can be cut into products by 25 μm wide cut...

Acceleration of polyethelene foils by laser driven ablation

International Nuclear Information System (INIS)

Ahlstrom, H.G.; Burginyon, G.A.; Haas, R.A.

1974-01-01

The production of thermonuclear energy, by laser driven implosion of spherical DT shells, with achievable laser technology, requires the development of an efficient and stable implosion. Certain aspects of the acceleration of the spherical shells can be studied experimentally by irradiating thin, 5 to 25 μm, polyethelene foils. The results of foil acceleration experiments performed using a Nd:YAG-Glass laser capable of producing 150 J, 1 nsec pulses will be discussed. The dynamics of the accelerated foil, the ion blow off, high energy electron spectrum (6 to 180 keV), x-ray spectrum (1 to 150 keV) the spatial distribution of the x-ray emission, the laser beam focal spot energy distribution, the laser temporal pulse shape and spectrum for reflected and transmitted radiation have all been measured simultaneously. The results of these measurements are compared with detailed numerical simulations. (U.S.)

Photoconductivity in reactively evaporated copper indium selenide thin films

Science.gov (United States)

Urmila, K. S.; Asokan, T. Namitha; Pradeep, B.; Jacob, Rajani; Philip, Rachel Reena

2014-01-01

Copper indium selenide thin films of composition CuInSe2 with thickness of the order of 130 nm are deposited on glass substrate at a temperature of 423 ±5 K and pressure of 10-5 mbar using reactive evaporation, a variant of Gunther's three temperature method with high purity Copper (99.999%), Indium (99.999%) and Selenium (99.99%) as the elemental starting materials. X-ray diffraction (XRD) studies shows that the films are polycrystalline in nature having preferred orientation of grains along the (112) plane. The structural type of the film is found to be tetragonal with particle size of the order of 32 nm. The structural parameters such as lattice constant, particle size, dislocation density, number of crystallites per unit area and strain in the film are also evaluated. The surface morphology of CuInSe2 films are studied using 2D and 3D atomic force microscopy to estimate the grain size and surface roughness respectively. Analysis of the absorption spectrum of the film recorded using UV-Vis-NIR Spectrophotometer in the wavelength range from 2500 nm to cutoff revealed that the film possess a direct allowed transition with a band gap of 1.05 eV and a high value of absorption coefficient (α) of 106 cm-1 at 570 nm. Photoconductivity at room temperature is measured after illuminating the film with an FSH lamp (82 V, 300 W). Optical absorption studies in conjunction with the good photoconductivity of the prepared p-type CuInSe2 thin films indicate its suitability in photovoltaic applications.

Development of super thin foil metal supported catalyst; Chousuhaku metal tantai shokubai no kaihatsu

Energy Technology Data Exchange (ETDEWEB)

Sanji, F; Takada, T [Toyota Motor Corp., Aichi (Japan)

1997-10-01

In order to improve warm-up performance, high heat resistance and long life durability of catalysts, the reduction of the metal support heat capacity has been focused. The effects of both reducing foil thickness and lowering cell density on low heat capacity have been investigated. As a result of engine bench and vehicle test, it was apparent that the reduction of foil thickness has greater effects. Newly developed 30 {mu} m foil thickness metal supported catalyst has quicker warm-up performance, and its structural durability up to 950degC is confirmed. 3 refs., 11 figs., 1 tab.

Electrophoretically applied dielectrics for amorphous metal foils used in pulsed power saturable reactors

International Nuclear Information System (INIS)

Sharp, D.J.; Harjes, H.C.; Mann, G.A.

1989-01-01

Amorphous metal foil-wound inductors have been tested as ferromagnetic saturable inductive elements for pulsed-power (multi-terawatt) switching modules in the inertial confinement fusion program at Sandia National Laboratories. In simulated capacitor testing premature dielectric breakdown of thin polyethylene terephthalate film insulation in the inductor windings occurs at considerably below 2500 V. This appears to be due to inadvertant dielectric damage from micro-spikes on the amorphous foil surface. Electron micrographs and dielectric breakdown data illustrate that electrophoretically-applied dielectric coatings, deposited from organic aqueous colloid dispersions, can be used to provide insulating coatings on the foil which provide a 240% improvement (6000 V) in the breakdown strength of wound amorphous foil inductors. The theory and operation of a dedicated electrophoretic continuous coating system is described. The machine was constructed and successfully applied for dielectric coating of amorphous metal foil. Additional possible applications exist for practical dielectric coating of metallic films or foils used in various commercial wound-type capacitor structures. 7 refs., 9 figs

Preparation and electrochemical performance of copper foam-supported amorphous silicon thin films for rechargeable lithium-ion batteries

International Nuclear Information System (INIS)

Li Haixia; Cheng Fangyi; Zhu Zhiqiang; Bai Hongmei; Tao Zhanliang; Chen Jun

2011-01-01

Research highlights: → Amorphous Si thin films have been deposited on copper foam substrate by radio-frequency (rf) magnetron sputtering. → The as-prepared Si/Cu films with interconnected 3-dimensional structure are employed as anode materials of rechargeable lithium-ion batteries, showing that the electrode properties are greatly affected by the deposition temperature. → The film electrode deposited at an optimum temperature of 300 deg. C delivers a specific capacity of ∼2900 mAh/g and a coulombic efficiency above 95% at charge/discharge current density of 0.2C after 30 cycles. → The Li + diffusion coefficiency in copper foam-supported Si thin films is determined to be 2.36 x 10 -9 cm 2 /s. → The combination of rf magnetron sputtering and cooper foam substrate is an efficient route to prepare amorphous Si films with high capacity and cyclability due to the efficient ionic diffusion and interface contact with a good conductive current collector. - Abstract: Amorphous Si thin films, which have been deposited on copper foam by radio-frequency (rf) magnetron sputtering, are employed as anode materials of rechargeable lithium-ion batteries. The morphologies and structures of the as-prepared Si thin films are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray powder diffraction (XRD). Electrochemical performance of lithium-ion batteries with the as-prepared Si films as the anode materials is investigated by cyclic voltammetry and charge-discharge measurements. The results show that the electrode properties of the prepared amorphous Si films are greatly affected by the deposition temperature. The film electrode deposited at an optimum temperature of 300 deg. C can deliver a specific capacity of ∼2900 mAh/g and a coulombic efficiency above 95% at charge/discharge current density of 0.2C after 30 cycles. The Li + diffusion coefficiency in copper foam-supported Si thin films is determined to be 2.36 x 10 -9 cm

Optical observations of molecular dissociation in thin foils

International Nuclear Information System (INIS)

Berry, H.G.; Gay, T.J.; Brooks, R.L.

1981-01-01

We have measured the intensity and polarizations of light emitted from atomic excited states of dissociated molecular ions. Using HeH + projectiles, we have observed factors of 1-5 enhancements of the light from n=3, sup(1,3)P,D states of He I and some He II and H I emissions. Observations of Lyman alpha emission after dissociation of H 2 + and H 3 + show rapid variations in light yield for small internuclear separations at the foil surface. (author)

Creative Copper Crests

Science.gov (United States)

Knab, Thomas

2011-01-01

In this article, the author discusses how to create an art activity that would link the computer-created business cards of fourth-grade students with an upcoming school-wide medieval event. Creating family crests from copper foil would be a great connection, since they, like business cards, are an individual's way to identify themselves to others.…

Work function measurements of copper nanoparticle intercalated polyaniline nanocomposite thin films

Science.gov (United States)

Patil, U. V.; Ramgir, Niranjan S.; Bhogale, A.; Debnath, A. K.; Muthe, K. P.; Gadkari, S. C.; Kothari, D. C.

2017-05-01

The nature of contact between the electrode and the sensing material plays a crucial role in governing the sensing mechanism. Thin films of polyaniline (PANI) and copper-polyaniline nanocomposite (NC) have been deposited at room temperatures by in-situ oxidative polymerization of aniline in the presence of Cu nanoparticles. For sensing applications a thin film Au (gold) ˜100 nm is deposited and used as a conducting electrode. To understand the nature of contact (i.e., ohmic or Schottky) the work function of the conducting polyaniline and nanocomposite films were measured using Kelvin Probe method. I-V characteristics of PANI and NC films investigated at room temperatures further corroborates and confirms the formation of Ohmic contact as evident from work function measurements.

Measurements of direct drive laser imprint in thin foils by XUV radiography using an X-ray laser backlighter

International Nuclear Information System (INIS)

Kalantar, D.H.; Key, M.H.; DaSilva, L.B.

1996-11-01

In direct drive inertial confinement fusion, the residual speckle pattern remaining after beam smoothing plays an important role in the seeding of instabilities at the ablation front. We have used an x-ray laser as an XUV backlighter to characterize the imprinted modulation in thin foils for smoothing by random phase plate and spectral dispersion at both 0.35 pm and 0.53 pm irradiation, and induced spatial incoherence at 0.53 pm irradiation. We also demonstrate measurements of the modulation due to a single mode optical imprint generated by a narrow slit interference pattern, and modification of the imprint with a superposed smooth irradiation to study time dependence of the imprinting process. 8 refs., 10 figs

Influence of post-deposition annealing on structural, morphological and optical properties of copper (II) acetylacetonate thin films.

Science.gov (United States)

Abdel-Khalek, H; El-Samahi, M I; El-Mahalawy, Ahmed M

2018-05-21

In this study, the effect of thermal annealing under vacuum conditions on structural, morphological and optical properties of thermally evaporated copper (II) acetylacetonate, cu(acac) 2 , thin films were investigated. The copper (II) acetylacetonate thin films were deposited using thermal evaporation technique at vacuum pressure ~1 × 10 -5  mbar. The deposited films were thermally annealed at 323, 373, 423, and 473 K for 2 h in vacuum. The thermogravimetric analysis of cu(acac) 2 powder indicated a thermal stability of cu(acac) 2 up to 423 K. The effects of thermal annealing on the structural properties of cu(acac) 2 were evaluated employing X-ray diffraction method and the analysis showed a polycrystalline nature of the as-deposited and annealed films with a preferred orientation in [1¯01] direction. Fourier transformation infrared (FTIR) technique was used to negate the decomposition of copper (II) acetylacetonate during preparation or/and annealing up to 423 K. The surface morphology of the prepared films was characterized by means of field emission scanning electron microscopy (FESEM). A significant enhancement of the morphological properties of cu(acac) 2 thin films was obtained till the annealing temperature reaches 423 K. The variation of optical constants that estimated from spectrophotometric measurements of the prepared thin films was investigated as a function of annealing temperature. The annealing process presented significantly impacted the nonlinear optical properties such as third-order optical susceptibility χ (3) and nonlinear refractive index n 2 of cu(acac) 2 thin films. Copyright © 2018 Elsevier B.V. All rights reserved.

Scanning tunneling microscopy studies of thin foil x-ray mirrors

DEFF Research Database (Denmark)

Christensen, Finn Erland; Besenbacher, Flemming; Garnaes, Jorgen

1990-01-01

In this paper scanning tunneling microscopy (STM) measurements of x-ray mirrors are presented. The x-ray mirrors are 0.3 mm thick dip-lacquered aluminum foils coated with gold by evaporation, as well as state-of-the-art polished surfaces coated with gold, platinum, or iridium. The measurements...

Bath parameter dependence of chemically deposited Copper Selenide thin film

International Nuclear Information System (INIS)

Al-Mamun; Islam, A.B.M.O.

2004-09-01

In this article, a low cost chemical bath deposition (CBD) technique has been used for the preparation Of Cu 2-x Se thin films on to glass substrate. Different thin fms (0.2-0.6/μm) were prepared by adjusting the bath parameter like concentration of ammonia, deposition time, temperature of the solution, and the ratios of the mixing composition between copper and selenium in the reaction bath. From these studies, it reveals that at low concentration of ammonia or TEA, the terminal thicknesses of the films are less, which gradually increases with the increase of concentrations and then drop down at still higher concentrations. It has been found that completing the Cu 2+ ions with EA first, and then addition of ammonia yields better results than the reverse process. The film thickness increases with the decrease of value x of Cu 2-x Se. (author)

Effect of copper surface pre-treatment on the properties of CVD grown graphene

Directory of Open Access Journals (Sweden)

Min-Sik Kim

2014-12-01

Full Text Available Here, we report the synthesis of high quality monolayer graphene on the pre-treated copper (Cu foil by chemical vapor deposition method. The pre-treatment process, which consists of pre-annealing in a hydrogen ambient, followed by diluted nitric acid etching of Cu foil, helps in removing impurities. These impurities include native copper oxide and rolling lines that act as a nucleation center for multilayer graphene. Raman mapping of our graphene grown on pre-treated Cu foil primarily consisted of ∼98% a monolayer graphene with as compared to 75 % for the graphene grown on untreated Cu foil. A high hydrogen flow rate during the pre-annealing process resulted in an increased I2D/IG ratio of graphene up to 3.55. Uniform monolayer graphene was obtained with a I2D/IG ratio and sheet resistance varying from 1.84 – 3.39 and 1110 – 1290 Ω/□, respectively.

Copper corrosion in pure oxygen-free water

International Nuclear Information System (INIS)

Moeller, K.

1995-12-01

The study was initiated following reports on corrosion of Copper in water in absence of Oxygen. Quartz glass tubes containing pure water and Copper plates were sealed in two different ways, using Palladium or Platinum foils, respectively. Tests were also performed with Copper wires. The insulated systems contained Oxygen initially. The Oxygen was dissolved in the water, and in the air column between the water surface and the Palladium/Platinum foils. The tubes were kept in a hot cabinet at 50 C for a total of two years. The exposed plates were analyzed in different ways, e g using reflectance FTIR. The amounts of oxide formed were also weighed. The following conclusions could be drawn: No difference in color was observed for the Pd and Pt seals except in one case for the Copper wire, where only a slight difference was noticed. No significant difference in oxidation between the plates with Pd or Pt seals in quartz glass tubes. No oxide growth was observed during the last year. The corrosion rate at 50 C is below 2.3 micrograms Copper/cm 2 /year. A certain imbalance was noted between the amounts of oxides formed, and expected amount estimated from the original amount of oxygen in the system. A significant amount of water has 'disappeared' from the tubes. 17 refs, 10 figs, 3 tabs

SBA-15 mesoporous silica free-standing thin films containing copper ions bounded via propyl phosphonate units - preparation and characterization

Energy Technology Data Exchange (ETDEWEB)

Laskowski, Lukasz, E-mail: lukasz.laskowski@kik.pcz.pl [Czestochowa University of Technology, Institute of Computational Intelligence, Unit of Microelectronics and Nanotechnology, Al. Armii Krajowej 36, 42–201 Czestochowa (Poland); Laskowska, Magdalena, E-mail: magdalena.laskowska@onet.pl [H. Niewodniczanski Institute of Nuclear Physics, Polish Academy of Sciences, 31-342 Krakow, ul. Radzikowskiego 152 (Poland); Jelonkiewicz, Jerzy, E-mail: jerzy.jelonkiewicz@kik.pcz.pl [Czestochowa University of Technology, Institute of Computational Intelligence, Unit of Microelectronics and Nanotechnology, Al. Armii Krajowej 36, 42–201 Czestochowa (Poland); Dulski, Mateusz, E-mail: mateusz.dulski@us.edu.pl [University of Silesia, Faculty of Computer Science and Materials Science, Institute of Materials Science, Silesian Center for Education and Interdisciplinary Research, ul. 75 Pułku Piechoty 1A, 41–500 Chorzów (Poland); Wojtyniak, Marcin, E-mail: marcin.wojtyniak@us.edu.pl [University of Silesia, Institute of Physics, Silesian Center for Education and Interdisciplinary Research, ul. 75 Pułku Piechoty 1A, 41–500 Chorzów (Poland); Fitta, Magdalena, E-mail: magdalena.fitta@ifj.edu.pl [H. Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, 31–342 Krakow, ul. Radzikowskiego 152 (Poland); Balanda, Maria, E-mail: Maria.Balanda@ifj.edu.pl [H. Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, 31–342 Krakow, ul. Radzikowskiego 152 (Poland)

2016-09-15

The SBA-15 silica thin films containing copper ions anchored inside channels via propyl phosphonate groups are investigated. Such materials were prepared in the form of thin films, with hexagonally arranged pores, laying rectilinear to the substrate surface. However, in the case of our thin films, their free standing form allowed for additional research possibilities, that are not obtainable for typical thin films on a substrate. The structural properties of the samples were investigated by X-ray reflectometry, atomic force microscopy (AFM) and transmission electron microscopy (TEM). The molecular structure was examined by Raman spectroscopy supported by numerical simulations. Magnetic measurements (SQUID magnetometry and EPR spectroscopy) showed weak antiferromagnetic interactions between active units inside silica channels. Consequently, the pores arrangement was determined and the process of copper ions anchoring by propyl phosphonate groups was verified in unambiguous way. Moreover, the type of interactions between magnetic atoms was determined. - Highlights: • Functionalized free-standing SBA-15 thin films were synthesized for a first time. • Thin films synthesis procedure was described in details. • Structural properties of the films were thoroughly investigated and presented. • Magnetic properties of the novel material was investigated and presented.

Use of Kelvin probe force microscopy for identification of CVD grown graphene flakes on copper foil

Science.gov (United States)

Kumar, Rakesh; Mehta, B. R.; Kanjilal, D.

2017-05-01

Graphene flakes have been grown by chemical vapour deposition (CVD) method on Cu foils. The obtained graphene flakes have been characterized by optical microscopy, field emission scanning electron microscopy, Kelvin probe force microscopy (KPFM) and Raman spectroscopy. The graphene flakes grown on Cu foil comprise mainly single layer graphene and confirm that the nucleation for graphene growth starts very quickly. Moreover, KPFM has been found to be a valuable technique to differentiate between covered and uncovered portion of Cu foil by graphene flakes deposited for shorter duration. The results show that KPFM can be a very useful technique in understanding the mechanism of graphene growth.

Structural and magnetic characterization of martensitic Ni-Mn-Ga thin films deposited on Mo foil

International Nuclear Information System (INIS)

Chernenko, V.A.; Anton, R. Lopez; Kohl, M.; Barandiaran, J.M.; Ohtsuka, M.; Orue, I.; Besseghini, S.

2006-01-01

Three martensitic Ni 51.4 Mn 28.3 Ga 20.3 thin films sputter-deposited on a Mo foil were investigated with regard to their crystal and magnetic domain structures, as well as their magnetic and magnetostrain properties. The film thicknesses, d, were 0.1, 0.4 and 1.0μm. X-ray and electron diffraction patterns revealed a tetragonal modulated martensitic phase (10M) in the films. The surface topography and micromagnetic structure were studied by scanning probe microscopy. A maze magnetic domain structure featuring a large out-of-plane magnetization component was found in all films. The domain width, δ, depends on the film thickness as δ∼d. The thickness dependencies of the saturation magnetization, saturation magnetic field and magnetic anisotropy were clarified. Beam cantilever tests on the Ni-Mn-Ga/Mo composite as a function of magnetic field showed reversible strains, which are larger than ordinary magnetostriction

Niobium thin film coating on a 500-MHz copper cavity by plasma deposition

Energy Technology Data Exchange (ETDEWEB)

Haipeng Wang; Genfa Wu; H. Phillips; Robert Rimmer; Anne-Marie Valente; Andy Wu

2005-05-16

A system using an Electron Cyclotron Resonance (ECR) plasma source for the deposition of a thin niobium film inside a copper cavity for superconducting accelerator applications has been designed and is being constructed. The system uses a 500-MHz copper cavity as both substrate and vacuum chamber. The ECR plasma will be created to produce direct niobium ion deposition. The central cylindrical grid is DC biased to control the deposition energy. This paper describes the design of several subcomponents including the vacuum chamber, RF supply, biasing grid and magnet coils. Operational parameters are compared between an operating sample deposition system and this system. Engineering work progress toward the first plasma creation will be reported here.

Investigation of high- k yttrium copper titanate thin films as alternative gate dielectrics

International Nuclear Information System (INIS)

Monteduro, Anna Grazia; Ameer, Zoobia; Rizzato, Silvia; Martino, Maurizio; Caricato, Anna Paola; Maruccio, Giuseppe; Tasco, Vittorianna; Lekshmi, Indira Chaitanya; Hazarika, Abhijit; Choudhury, Debraj; Sarma, D D

2016-01-01

Nearly amorphous high- k yttrium copper titanate thin films deposited by laser ablation were investigated in both metal–oxide–semiconductor (MOS) and metal–insulator–metal (MIM) junctions in order to assess the potentialities of this material as a gate oxide. The trend of dielectric parameters with film deposition shows a wide tunability for the dielectric constant and AC conductivity, with a remarkably high dielectric constant value of up to 95 for the thick films and conductivity as low as 6  ×  10 −10 S cm −1 for the thin films deposited at high oxygen pressure. The AC conductivity analysis points out a decrease in the conductivity, indicating the formation of a blocking interface layer, probably due to partial oxidation of the thin films during cool-down in an oxygen atmosphere. Topography and surface potential characterizations highlight differences in the thin film microstructure as a function of the deposition conditions; these differences seem to affect their electrical properties. (paper)

X-ray emission, ablation pressure, and preheating for foils irradiated at 0. 26. mu. m wavelength

Energy Technology Data Exchange (ETDEWEB)

Pepin, H.; Fabbro, R.; Faral, B.; Amiranoff, F.; Virmont, J.; Cottet, F.; Romain, J.P.

1985-11-01

The x-ray emission, ablation pressure, and preheating for foils irradiated with a 0.26 ..mu..m laser at intensities approx.10/sup 15/ W cm/sup -2/ are studied. The foils are Al with various thicknesses, coated or uncoated with CH or Au. The x-ray emission and conversion efficiency are obtained with a multichannel x-ray diode spectrometer, the ablation pressures are deduced from shock transit times, and the rear temperatures are inferred from x-ray pyrometry. For thin foils (<<12 ..mu..m), the rear temperatures can be predicted reasonably well with the use of the front x-ray spectra. For thick foils shock preheating is dominant.

X-ray emission, ablation pressure, and preheating for foils irradiated at 0.26 μm wavelength

International Nuclear Information System (INIS)

Pepin, H.; Fabbro, R.; Faral, B.; Amiranoff, F.; Virmont, J.; Cottet, F.; Romain, J.P.

1985-01-01

The x-ray emission, ablation pressure, and preheating for foils irradiated with a 0.26 μm laser at intensities approx.10 15 W cm -2 are studied. The foils are Al with various thicknesses, coated or uncoated with CH or Au. The x-ray emission and conversion efficiency are obtained with a multichannel x-ray diode spectrometer, the ablation pressures are deduced from shock transit times, and the rear temperatures are inferred from x-ray pyrometry. For thin foils (<<12 μm), the rear temperatures can be predicted reasonably well with the use of the front x-ray spectra. For thick foils shock preheating is dominant

Electron emission resulting from fast ion impact on thin metal foils: Implications of these data for development of track structure models

Energy Technology Data Exchange (ETDEWEB)

DuBois, R.D.; Drexler, C.G.

1993-04-01

Experimental information useful in improving and testing theoretical models of energy deposition and redistribution in particle-condensed phase media is discussed. An overview of information available from previous, and ongoing, studies of the electron emission from thin foils is presented and the need for doubly differential electron energy and angular distribution data stressed. Existing data are used to demonstrate that precisely known, and controllable, surface and bulk conditions of the condensed-phase media are required for experimental studies of this type. Work in progress and improvements planned for future studies at the Pacific Northwest Laboratory are outlined.

Nanodiamond Foils for H- Stripping to Support the Spallation Neutron Source (SNS) and Related Applications

Energy Technology Data Exchange (ETDEWEB)

Vispute, R D [Blue Wave Semiconductors; Ermer, Henry K [Blue Wave Semiconductors; Sinsky, Phillip [Blue Wave Semiconductors; Seiser, Andrew [Blue Wave Semiconductors; Shaw, Robert W [ORNL; Wilson, Leslie L [ORNL; Harris, Gary [Howard University; Piazza, Fabrice [Pontifica Universidad Catolica Madre y Maestra, Dominican Republic

2013-01-01

Thin diamond foils are needed in many particle accelerator experiments regarding nuclear and atomic physics, as well as in some interdisciplinary research. Particularly, nanodiamond texture is attractive for this purpose as it possesses a unique combination of diamond properties such as high thermal conductivity, mechanical strength and high radiation hardness; therefore, it is a potential material for energetic ion beam stripper foils. At the ORNL Spallation Neutron Source (SNS), the installed set of foils must be able to survive a nominal five-month operation period, without the need for unscheduled costly shutdowns and repairs. Thus, a single nanodiamond foil about the size of a postage stamp is critical to the entire operation of SNS and similar sources in U.S. laboratories and around the world. We are investigating nanocrystalline, polycrystalline and their admixture films fabricated using a hot filament chemical vapor deposition (HFCVD) system for H- stripping to support the SNS at Oak Ridge National Laboratory. Here we discuss optimization of process variables such as substrate temperature, process gas ratio of H2/Ar/CH4, substrate to filament distance, filament temperature, carburization conditions, and filament geometry to achieve high purity diamond foils on patterned silicon substrates with manageable intrinsic and thermal stresses so that they can be released as free standing foils without curling. An in situ laser reflectance interferometry tool (LRI) is used for monitoring the growth characteristics of the diamond thin film materials. The optimization process has yielded free standing foils with no pinholes. The sp3/sp2 bonds are controlled to optimize electrical resistivity to reduce the possibility of surface charging of the foils. The integrated LRI and HFCVD process provides real time information on the growth of films and can quickly illustrate growth features and control over film thickness. The results are discussed in the light of development

Advanced foil activation techniques for the measurement of within-pin distributions of the 63Cu(n,γ)64Cu reaction rate in nuclear fuel

International Nuclear Information System (INIS)

Macku, K.; Jatuff, F.; Murphy, M.F.; Joneja, O.P.; Bischofberger, R.; Chawla, R.

2006-01-01

Different foil activation techniques have been used for measuring spatial distributions of the 63 Cu(n,γ) 64 Cu reaction within two pins of a SVEA-96 Optima2 boiling water reactor fuel assembly, at the critical facility PROTEUS. This reaction is of interest because its 1/v cross-section gives it a good representation of the 235 U fission rate. Initially, radial capture rate profiles were measured with mechanically punched copper foils. More detailed profiles were then determined by using a 0.2 mm copper wire spiral (∼200 μm resolution), as well as 5-, 10-, and 20-ring UV-lithography, electroplating, and molding (UV-LIGA) foils (up to a 100 μm resolution). For azimuthal measurements, apart from manually cut activation foils (into 8 sectors), 8- and 12-sector LIGA foils were used. The highly versatile LIGA foils have the additional advantage of being very easily separated into individual pieces after irradiation without the use of punches or other cutting tools. In order to account for the invasive character of the foil activation techniques, corrections to account for sample perturbations and for self-shielding effects were determined via simplified Monte Carlo (MCNP4C) modeling of the experimental setup. The final results from the various measurements of 63 Cu(n,γ) 64 Cu within-pin distributions have been compared with MCNP computations employing a detailed model of the full SVEA Optima2 fuel assembly

MULPEX: A compact multi-layered polymer foil collector for micrometeoroids and orbital debris

Science.gov (United States)

Kearsley, A. T.; Graham, G. A.; Burchell, M. J.; Taylor, E. A.; Drolshagen, G.; Chater, R. J.; McPhail, D.

Detailed studies of preserved hypervelocity impact residues on spacecraft multi-layer insulation foils have yielded important information about the flux of small particles from different sources in low-Earth orbit (LEO). We have extended our earlier research on impacts occurring in LEO to design and testing of a compact capture device. MUlti- Layer Polymer EXperiment (MULPEX) is simple, cheap to build, lightweight, of no power demand, easy to deploy, and optimised for the efficient collection of impact residue for analysis on return to Earth. The capture medium is a stack of very thin (8 and 40 μm) polyimide foils, supported on poly-tetrafluoroethylene sheet frames, surrounded by a protective aluminium casing. The uppermost foil has a very thin metallic coating for thermal protection and resistance to atomic oxygen and ultra-violet exposure. The casing provides a simple detachable interface for deployment on the spacecraft, facing into the desired direction for particle collection. On return to the laboratory, the stacked foils are separated for examination in a variable pressure scanning electron microscope, without need for surface coating. Analysis of impact residue is performed using energy dispersive X-ray spectrometers. Our laboratory experiments, utilising buck-shot firings of analogues to micrometeoroids (35-38 μm olivine) and space debris (4 μm alumina and 1 mm stainless steel) in a light gas gun, have shown that impact residue is abundant within the foil layers, and preserves a record of the impacting particle, whether of micrometer or millimetre dimensions. Penetrations of the top foil are easily recognised, and act as a proxy for dimensions of the penetrating particle. Impact may cause disruption and melting, but some residue retains sufficient crystallographic structure to show clear Raman lines, diagnostic of the original mineral.

Influence of UV and Gamma radiations on the induced birefringence of stretched poly(vinyl) alcohol foils

Science.gov (United States)

Nechifor, Cristina-Delia; Zelinschi, Carmen Beatrice; Dorohoi, Dana-Ortansa

2014-03-01

The aim of our paper is to evidence the influence of Gamma and UV radiations on the induced birefringence of poly(vinyl alcohol) stretched foils. Thin foils of PVA were prepared and dried without modifying their surfaces. The polymeric foils were irradiated from 15 min to 6 h using UV and Gamma radiations. The induced by stretching under heating birefringence of PVA films was measured at λ = 589.3 nm with a Babinet Compensator. Physico-chemical processes (photo stabilization, photo degradation, oxidation) induced by irradiation of polymer matrix influence both the stretching degree and the anisotropy of etired foils. An increase of birefringence versus the stretching ratio of the PVA foils was evidenced for all studied samples. The dependence of the birefringence on the exposure time, stretching ratio and nature of radiation was also confirmed.

Thrust augmentation in tandem flapping foils by foil-wake interaction

Science.gov (United States)

Anderson, Erik; Lauder, George

2006-11-01

Propulsion by pitching and heaving airfoils and hydrofoils has been a focus of much research in the field of biologically inspired propulsion. Organisms that use this sort of propulsion are self-propelled, so it is difficult to use standard experimental metrics such as thrust and drag to characterize performance. We have constructed a flapping foil robot mounted in a flume on air-bearings that allows for the determination of self-propelled speed as a metric of performance. We have used a pair of these robots to examine the impact of an upstream flapping foil on a downstream flapping foil as might apply to tandem fins of a swimming organism or in-line swimming of schooling organisms. Self-propelled speed and a force transducer confirmed significant thrust augmentation for particular foil-to-foil spacings, phase differences, and flapping frequencies. Flow visualization shows the mechanism to be related to the effective angle of attack of the downstream foil due to the structure of the wake of the upstream foil. This confirms recent computational work and the hypotheses by early investigators of fish fluid dynamics.

An efficient fabrication of vertically aligned carbon nanotubes on flexible aluminum foils by catalyst-supported chemical vapor deposition

International Nuclear Information System (INIS)

Yoshikawa, Naoki; Kishi, Naoki; Sugai, Toshiki; Shinohara, Hisanori; Asari, Takuma; Hayashi, Shigeo

2008-01-01

An efficient and versatile growth of thin-layer carbon nanotubes on a flexible aluminum foil (for kitchen use) by catalyst-supported chemical vapor deposition is reported. The aluminum foil used in the present experiment is commercially available for kitchen use. The electron-beam vapor deposition and dip-coating have been used for preparing catalysts on the aluminum foil. Vertically aligned thin-layer CNTs with typical diameters of 2.5-6.0 nm and lengths up to 90 μm are obtained when ethanol is used in combination with Fe and Co catalyst particles at a growth temperature of around 650 deg. C under an Ar/H 2 gas flow. Thermo-gravimetric analyses together with HR-TEM observations indicate that the purity of the CNTs synthesized by the current technique is very high

Magnetic collimation and metal foil filtering for electron range and fluence modulation

International Nuclear Information System (INIS)

Phaisangittisakul, N.; D'Souza, W.D.; Ma Lijun

2004-01-01

We investigated the use of magnetically collimated electron beams together with metal filters for electron fluence and range modulation. A longitudinal magnetic field collimation method was developed to reduce skin dose and to improve the electron beam penumbra. Thin metal foils were used to adjust the energies of magnetically collimated electrons. The effects for different types of foils such as Al, Be, Cu, Pb, and Ti were studied using Monte Carlo calculations. An empirical pencil beam dose calculation model was developed to calculate electron dose distributions under magnetic collimation and foil modulation. An optimization method was developed to produce conformal dose distributions for simulated targets such as a horseshoe-shaped target. Our results show that it is possible to produce an electron depth dose enhancement peak using similar techniques of producing a spread-out Bragg peak. In conclusion, our study demonstrates new aspects of using magnetic collimation and foil filtration for producing fluence and range modulated electron dose distributions

A Wirelessly-Powered Homecage With Segmented Copper Foils and Closed-Loop Power Control.

Science.gov (United States)

Mirbozorgi, S Abdollah; Jia, Yaoyao; Canales, Daniel; Ghovanloo, Maysam

2016-10-01

A new wireless electrophysiology data acquisition system, built around a standard homecage, is presented in this paper, which can power up and communicate with sensors and actuators/stimulators attached to or implanted in small freely behaving animal subjects, such as rodents. Key abilities of the energized homecage (EnerCage) system is enabling longitudinal experiments with minimal operator involvement or interruption, while providing test subjects with an enriched environment closer to their natural habitat, without the burden of being tethered or carrying bulky batteries. The magnetic resonant multi-coil design used in the new EnerCage-HC2 automatically localizes the transmitted electromagnetic power from a single transmitter (Tx) coil at the bottom of the cage toward the receiver coil (Rx), carried on/in the animal body, obviating the need for tracking the animal or switching the coils. In order to increase the resonators' quality factor (Q > 166) at the desired operating frequency of 13.56 MHz, while maintaining a high self-resonance frequency [Formula: see text], they are made of wide copper foils and optimally segmented based on a set of design rules that can be adopted for experimental arenas with different shapes and dimensions. The Rx rectified voltage is regulated at a user-defined window [Formula: see text] by a Tx-Rx closed-loop power control (CLPC) mechanism that creates a volume inside the homecage with 42 mW of power delivered to the load (PDL), and a homogeneous power transfer efficiency (PTE) plane of 14% on average at ∼7 cm height, plus stability against angular mis-alignments of up to 80°.

Foil changing apparatus

International Nuclear Information System (INIS)

Crist, C.E.; Ives, H.C.; Leifeste, G.T.; Miller, R.B.

1988-01-01

A self-contained foil changer apparatus for replenishing foil material across the path of a high energy particle beam is described comprising: a cylindrical hermetically sealed housing comprising an end plate having an aperture defining a beam passageway therethrough; foil supply means disposed inside the housing for storing a foil web and supporting a portion of the web across the beam passageway to form a plane perpendicular to the beam path; a barrel assembly disposed inside the housing; web control means extending through the housing and operably connected to the foil supply means for selectively advancing the foil web to replenish a portion across the beam passageway; and barrel control means extending through the housing and operably connected to the barrel assembly for selectively moving the barrel to and from the advanced and retracted positions

Chromatic annuli formation and sample oxidation on copper thin films by femtosecond laser

Energy Technology Data Exchange (ETDEWEB)

He, Shutong [Ultrafast Laser Laboratory, Key Laboratory of Opto-Electronic Information Technical Science of Ministry of Education, College of Precision Instruments and Opto-Electronics Engineering, Tianjin University, Tianjin 300072 (China); Dipartimento di Fisica, Università di Napoli Federico II, Complesso Universitario di Monte S. Angelo, Via Cintia, I-80126 Napoli (Italy); Amoruso, Salvatore [Dipartimento di Fisica, Università di Napoli Federico II, Complesso Universitario di Monte S. Angelo, Via Cintia, I-80126 Napoli (Italy); Pang, Dongqing; Wang, Chingyue; Hu, Minglie, E-mail: huminglie@tju.edu.cn [Ultrafast Laser Laboratory, Key Laboratory of Opto-Electronic Information Technical Science of Ministry of Education, College of Precision Instruments and Opto-Electronics Engineering, Tianjin University, Tianjin 300072 (China)

2016-04-28

We report an experimental investigation on the irradiation of copper thin films with high repetition rate femtosecond laser pulses (1040 nm, 50 MHz), in ambient air and liquid water. We observe a novel, striking phenomenon of chromatic copper oxides (CuO and Cu{sub 2}O) annuli generation. The characteristic features of the chromatic copper oxide annuli are studied by exploiting micro-Raman spectroscopy, optical and scanning electron microscopies. In the case of irradiation in water, the seldom investigated effects of the immersion time, t{sub w}, after irradiation with a fixed number of pulses are analyzed, and an intriguing dependence of the color of the chromatic annuli on t{sub w} is observed. This remarkable behavior is explained by proposing an interpretation scenario addressing the various processes involved in the process. Our experimental findings show that Cu{sub 2}O nanoparticles (size of ≈20 nm) and Cu{sub 2}O nanocubes (nanocube edges of ≈30, ≈60 nm) can be effectively generated by exploiting high repetition rate laser-assisted oxidation.

Highly conductive grain boundaries in copper oxide thin films

Energy Technology Data Exchange (ETDEWEB)

Deuermeier, Jonas, E-mail: j.deuermeier@campus.fct.unl.pt [Department of Materials Science, Faculty of Science and Technology, i3N/CENIMAT, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516 Caparica (Portugal); Department of Materials and Earth Sciences, Technische Universität Darmstadt, Jovanka-Bontschits-Straße 2, D-64287 Darmstadt (Germany); Wardenga, Hans F.; Morasch, Jan; Siol, Sebastian; Klein, Andreas, E-mail: aklein@surface.tu-darmstadt.de [Department of Materials and Earth Sciences, Technische Universität Darmstadt, Jovanka-Bontschits-Straße 2, D-64287 Darmstadt (Germany); Nandy, Suman; Calmeiro, Tomás; Martins, Rodrigo; Fortunato, Elvira [Department of Materials Science, Faculty of Science and Technology, i3N/CENIMAT, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516 Caparica (Portugal)

2016-06-21

High conductivity in the off-state and low field-effect mobility compared to bulk properties is widely observed in the p-type thin-film transistors of Cu{sub 2}O, especially when processed at moderate temperature. This work presents results from in situ conductance measurements at thicknesses from sub-nm to around 250 nm with parallel X-ray photoelectron spectroscopy. An enhanced conductivity at low thickness is explained by the occurrence of Cu(II), which is segregated in the grain boundary and locally causes a conductivity similar to CuO, although the surface of the thick film has Cu{sub 2}O stoichiometry. Since grains grow with an increasing film thickness, the effect of an apparent oxygen excess is most pronounced in vicinity to the substrate interface. Electrical properties of Cu{sub 2}O grains are at least partially short-circuited by this effect. The study focuses on properties inherent to copper oxide, although interface effects cannot be ruled out. This non-destructive, bottom-up analysis reveals phenomena which are commonly not observable after device fabrication, but clearly dominate electrical properties of polycrystalline thin films.

Fission fragment assisted reactor concept for space propulsion: Foil reactor

International Nuclear Information System (INIS)

Wright, S.A.

1991-01-01

The concept is to fabricate a reactor using thin films or foils of uranium, uranium oxide and then to coat them on substrates. These coatings would be made so thin as to allow the escaping fission fragments to directly heat a hydrogen propellant. The idea was studied of direct gas heating and direct gas pumping in a nuclear pumped laser program. Fission fragments were used to pump lasers. In this concept two substrates are placed opposite each other. The internal faces are coated with thin foil of uranium oxide. A few of the advantages of this technology are listed. In general, however, it is felt that if one look at all solid core nuclear thermal rockets or nuclear thermal propulsion methods, one is going to find that they all pretty much look the same. It is felt that this reactor has higher potential reliability. It has low structural operating temperatures, very short burn times, with graceful failure modes, and it has reduced potential for energetic accidents. Going to a design like this would take the NTP community part way to some of the very advanced engine designs, such as the gas core reactor, but with reduced risk because of the much lower temperatures

Backward and forward electron emission induced by helium projectiles incident on thin carbon foils: Influence of charge changing processes

Energy Technology Data Exchange (ETDEWEB)

Pauly, N. [Universite Libre de Bruxelles, Service de Metrologie Nucleaire (CP 165/84), 50 av. FD Roosevelt, B-1050 Brussels (Belgium)]. E-mail: nipauly@ulb.ac.be; Dubus, A. [Universite Libre de Bruxelles, Service de Metrologie Nucleaire (CP 165/84), 50 av. FD Roosevelt, B-1050 Brussels (Belgium); Roesler, M. [Karl-Pokern-Str. 12, D-12587 Berlin (Germany)

2007-03-15

The backward and forward electron emission yields {gamma} {sub B} and {gamma} {sub F} have been calculated by Monte Carlo simulations for helium (He{sup ++}, He{sup +} or He{sup 0}) ions incident on thin amorphous carbon foils with energies around the electronic stopping power maximum (0.2-2 MeV). Besides the direct excitation of target electrons by the incident projectile, we have taken into account the different charge changing processes (He{sup ++} {r_reversible} He{sup +} {r_reversible} He{sup 0}) undergone by the helium ion in the target. We discuss in particular the connection between the electron emission yield {gamma} and the electronic stopping power (dE/dx){sub e}. We compare our results with previously published experimental results.

Novel p-n heterojunction copper phosphide/cuprous oxide photocathode for solar hydrogen production.

Science.gov (United States)

Chen, Ying-Chu; Chen, Zhong-Bo; Hsu, Yu-Kuei

2018-08-01

A Copper phosphide (Cu 3 P) micro-rod (MR) array, with coverage by an n-Cu 2 O thin layer by electrodeposition as a photocathode, has been directly fabricated on copper foil via simple electro-oxidation and phosphidation for photoelectrochemical (PEC) hydrogen production. The morphology, structure, and composition of the Cu 3 P/Cu 2 O heterostructure are systematically analyzed using a scanning electron microscope (SEM), X-ray diffraction and X-ray photoelectron spectra. The PEC measurements corroborate that the p-Cu 3 P/n-Cu 2 O heterostructural photocathode illustrates efficient charge separation and low charge transfer resistance to achieve the highest photocurrent of 430 μA cm -2 that is greater than other transition metal phosphide materials. In addition, a detailed energy diagram of the p-Cu 3 P/n-Cu 2 O heterostructure was investigated using Mott-Schottky analysis. Our study paves the way to explore phosphide-based materials in a new class for solar energy applications. Copyright © 2018 Elsevier Inc. All rights reserved.

The measurement of conductivity of copper indium disulphide thin films against temperature and thickness

International Nuclear Information System (INIS)

Yussof Wahab; Roslinda Zainal; Samsudi Sakrani

1996-01-01

Ternary semiconductor copper indium disulphide (CuInS sub 2) thin films have been prepared by thermal evaporation. Three stacked layers of film starting with copper, indium and finally sulphur was deposited on glass substrate in the thickness ratio of 1: 1: I0. The films were then annealed in carbon block by method known as encapsulated sulphurization at 350 degree C for 4 hours. The XRD analysis for four samples of thickness of 449.5, 586, 612 and 654 nm showed that stoichiometric CuInS sub 2, were formed at this annealing condition. The electrical conductivity of CuInS sub 2 thin films were measured against temperature from 150K to 300K. The conductivity values were between 76.6 Sm sup -1 to 631.26 Sm sup -1 and the result showed that it increase exponentially with temperature for the above temperature range. The resulting activation energies were found to be in the range 0.05 to 0.08 eV. This suggested that hopping mechanism predominant to the conducting process. It also found that the conductivity decreased with increasing film thickness

The use of the foil technique for the elimination of charging, and for beam monitoring in microbeam analysis of thick insulating samples

International Nuclear Information System (INIS)

Chaudhri, M.A.; Melbourne Univ., Austin

1982-01-01

It has been demonstrated that the 'thin-foil-technique' for the elimination of charging and accurate beam current/charge measurement, first developed by us, can also be conveniently applied to microbeam analysis of thick insulating samples. We have calculated the spatial broadening of proton microbeams of 1-20 MeV energies at the target, due to thin carbon foils of different thicknesses ranging from 10-40 μg/cm 2 placed either 2 or 5 mm in front of the target by using Moliere's theory of multiple scattering. The results show that at higher proton energies there is very little broadening of the incident beam even from thicker foils. But for lower energy protons (1 and 2 MeV) this broadening or worsening of the spatial resolution is relatively larger, especially from thicker foils. However, we have further shown that, even at these energies, the beam broadening can be minimized to acceptable limits by selecting a suitable thickness of carbon foil and placing it as close to the insulating target as possible. A comprehensive table is provided, which would help in selecting the most suitable carbon-foil thickness and the distance in front of the target where this foil should be placed, for microprobe application requiring different beam spots and proton energies. The advantages of this foil technique are described. (orig.)

The Chevron Foil Thrust Bearing: Improved Performance Through Passive Thermal Management and Effective Lubricant Mixing

Science.gov (United States)

Bruckner, Robert

2013-01-01

An improved foil thrust bearing is described that eliminates or reduces the need for forced cooling of the bearing foils while at the same time improves the load capacity of the bearing, enhances damping, provides overload tolerance, and eliminates the high speed load capacity drop-off that plagues the current state of the art. The performance improvement demonstrated by the chevron foil thrust bearing stems from a novel trailing edge shape that splays the hot lubricant in the thin film radially, thus preventing hot lubricant carry-over into the ensuing bearing sector. Additionally, the chevron shaped trailing edge induces vortical mixing of the hot lubricant with the gas that is naturally resident within the inter-pad region of a foil thrust bearing. The elimination of hot gas carry-over in combination with the enhanced mixing has enabled a completely passive thermally managed foil bearing design. Laboratory testing at NASA has confirmed the original analysis and reduced this concept to practice.

Synthesizing photovoltaic thin films of high quality copper-zinc-tin alloy with at least one chalcogen species

Science.gov (United States)

Teeter, Glenn; Du, Hui; Young, Matthew

2013-08-06

A method for synthesizing a thin film of copper, zinc, tin, and a chalcogen species ("CZTCh" or "CZTSS") with well-controlled properties. The method includes depositing a thin film of precursor materials, e.g., approximately stoichiometric amounts of copper (Cu), zinc (Zn), tin (Sn), and a chalcogen species (Ch). The method then involves re-crystallizing and grain growth at higher temperatures, e.g., between about 725 and 925 degrees K, and annealing the precursor film at relatively lower temperatures, e.g., between 600 and 650 degrees K. The processing of the precursor film takes place in the presence of a quasi-equilibrium vapor, e.g., Sn and chalcogen species. The quasi-equilibrium vapor is used to maintain the precursor film in a quasi-equilibrium condition to reduce and even prevent decomposition of the CZTCh and is provided at a rate to balance desorption fluxes of Sn and chalcogens.

Three-dimensional thermal simulations of thin solid carbon foils for charge stripping of high current uranium ion beams at a proposed new heavy-ion linac at GSI

Directory of Open Access Journals (Sweden)

N. A. Tahir

2014-04-01

Full Text Available This paper presents an extensive numerical study of heating of thin solid carbon foils by 1.4  MeV/u uranium ion beams to explore the possibility of using such a target as a charge stripper at the proposed new Gesellschaft für Schwerionenforschung high energy heavy–ion linac. These simulations have been carried out using a sophisticated 3D computer code that accounts for physical phenomena that are important in this problem. A variety of beam and target parameters have been considered. The results suggest that within the considered parameter range, the target will be severely damaged by the beam. Thus, a carbon foil stripper does not seem to be a reliable option for the future Gesellschaft für Schwerionenforschung high energy heavy–ion linac, in particular, at FAIR design beam intensities.

Solar cell fabricated on welded thin flexible silicon

Directory of Open Access Journals (Sweden)

Hessmann Maik Thomas

2015-01-01

Full Text Available We present a thin-film crystalline silicon solar cell with an AM1.5 efficiency of 11.5% fabricated on welded 50 μm thin silicon foils. The aperture area of the cell is 1.00 cm2. The cell has an open-circuit voltage of 570 mV, a short-circuit current density of 29.9 mA cm-2 and a fill factor of 67.6%. These are the first results ever presented for solar cells on welded silicon foils. The foils were welded together in order to create the first thin flexible monocrystalline band substrate. A flexible band substrate offers the possibility to overcome the area restriction of ingot-based monocrystalline silicon wafers and the feasibility of a roll-to-roll manufacturing. In combination with an epitaxial and layer transfer process a decrease in production costs can be achieved.

Photo-Induced Room-Temperature Gas Sensing with a-IGZO Based Thin-Film Transistors Fabricated on Flexible Plastic Foil.

Science.gov (United States)

Knobelspies, Stefan; Bierer, Benedikt; Daus, Alwin; Takabayashi, Alain; Salvatore, Giovanni Antonio; Cantarella, Giuseppe; Ortiz Perez, Alvaro; Wöllenstein, Jürgen; Palzer, Stefan; Tröster, Gerhard

2018-01-26

We present a gas sensitive thin-film transistor (TFT) based on an amorphous Indium-Gallium-Zinc-Oxide (a-IGZO) semiconductor as the sensing layer, which is fabricated on a free-standing flexible polyimide foil. The photo-induced sensor response to NO₂ gas at room temperature and the cross-sensitivity to humidity are investigated. We combine the advantages of a transistor based sensor with flexible electronics technology to demonstrate the first flexible a-IGZO based gas sensitive TFT. Since flexible plastic substrates prohibit the use of high operating temperatures, the charge generation is promoted with the help of UV-light absorption, which ultimately triggers the reversible chemical reaction with the trace gas. Furthermore, the device fabrication process flow can be directly implemented in standard TFT technology, allowing for the parallel integration of the sensor and analog or logical circuits.

Photo-Induced Room-Temperature Gas Sensing with a-IGZO Based Thin-Film Transistors Fabricated on Flexible Plastic Foil

Directory of Open Access Journals (Sweden)

Stefan Knobelspies

2018-01-01

Full Text Available We present a gas sensitive thin-film transistor (TFT based on an amorphous Indium–Gallium–Zinc–Oxide (a-IGZO semiconductor as the sensing layer, which is fabricated on a free-standing flexible polyimide foil. The photo-induced sensor response to NO2 gas at room temperature and the cross-sensitivity to humidity are investigated. We combine the advantages of a transistor based sensor with flexible electronics technology to demonstrate the first flexible a-IGZO based gas sensitive TFT. Since flexible plastic substrates prohibit the use of high operating temperatures, the charge generation is promoted with the help of UV-light absorption, which ultimately triggers the reversible chemical reaction with the trace gas. Furthermore, the device fabrication process flow can be directly implemented in standard TFT technology, allowing for the parallel integration of the sensor and analog or logical circuits.

Resonant absorption effects induced by polarized laser ligth irradiating thin foils in the tnsa regime of ion acceleration

International Nuclear Information System (INIS)

Torrisi, L.; Badziak, J.; Rosinski, M.; Zaras-Szydlowska, A.; Pfeifer, M.; Torrisi, A.

2016-01-01

Thin foils were irradiated by short pulsed lasers at intensities of 10 16−19 W/cm 2 in order to produce non-equilibrium plasmas and ion acceleration from the target-normal-sheath-acceleration (TNSA) regime. Ion acceleration in forward direction was measured by SiC detectors and ion collectors used in the time-of-flight configuration. Laser irradiations were employed using p-polarized light at different incidence angles with respect to the target surface and at different focal distances from the target surface. Measurements demonstrate that resonant absorption effects, due to the plasma wave excitations, enhance the plasma temperature and the ion acceleration with respect to those performed without to use of p-polarized light. Dependences of the ion flux characteristics on the laser energy, wavelength, focal distance and incidence angle will be reported and discussed

Evaluation of a new laser-resistant fabric and copper foil-wrapped endotracheal tube.

Science.gov (United States)

Sosis, M B; Braverman, B; Caldarelli, D D

1996-07-01

The risk of an endotracheal tube's combustion during laser airway surgery necessitates the use of special anesthetic techniques and equipment to prevent this complication. This study was designed to evaluate the Laser-Trach(TM), a new laser-resistant rubber endotracheal tube for use during laser airway surgery. The Laser-Trach endotracheal tubes that were evaluated were size 6.0 mm internal diameter (ID) red rubber endotracheal tubes which had been commercially wrapped by Kendall-Sheridan (Mansfield, Mass.) with copper foil tape and overwrapped with fabric. The fabric layer was saturated with water prior to our tests, as recommended by the manufacturer. The Laser-Trach endotracheal tubes were compared with plain (bare) size 6.0 mm ID Rusch red rubber endotracheal tubes. The tubes under study were positioned horizontally on wet towels in air and had 5 L x min(-1) of oxygen flowing through them. They were subjected to continuous laser radiation at 40 W from either a CO2 or an Nd-YAG laser. The Nd-YAG laser was propagated via a 600-micron fiber bundle. Each laser was directed perpendicularly at the shaft of the endotracheal tube being studied, and its output was continued until a blowtorch fire occurred or 60 seconds had elapsed. Sixty seconds of CO2 laser fire did not ignite any of the eight Laser-Trach endotracheal tubes tested. However, blowtorch ignition of all eight bare rubber tubes tested occurred after 0.87 +/- 0.21 (mean +/- SD) seconds of CO2 laser fire. Nd-YAG laser contact with the Laser-Trach endotracheal tubes caused the perforation and blowtorch ignition of all eight tubes tested after 18.79 +/- 7.83 seconds. This was a significantly (Presistant to the C02 laser. However, this endotracheal tube is not recommended for use with the Nd-YAG laser.

Thin films of copper antimony sulfide: A photovoltaic absorber material

Energy Technology Data Exchange (ETDEWEB)

Ornelas-Acosta, R.E. [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Mecánica y Eléctrica, San Nicolás de los Garza, Nuevo León 66450 (Mexico); Shaji, S. [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Mecánica y Eléctrica, San Nicolás de los Garza, Nuevo León 66450 (Mexico); Universidad Autónoma de Nuevo León-CIIDIT, Apodaca, Nuevo León (Mexico); Avellaneda, D.; Castillo, G.A.; Das Roy, T.K. [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Mecánica y Eléctrica, San Nicolás de los Garza, Nuevo León 66450 (Mexico); Krishnan, B., E-mail: kbindu_k@yahoo.com [Universidad Autónoma de Nuevo León, Facultad de Ingeniería Mecánica y Eléctrica, San Nicolás de los Garza, Nuevo León 66450 (Mexico); Universidad Autónoma de Nuevo León-CIIDIT, Apodaca, Nuevo León (Mexico)

2015-01-15

Highlights: • CuSbS{sub 2} thin films were prepared by heating Sb{sub 2}S{sub 3}/Cu layers. • Analyzed the structure, composition, optical, and electrical properties. • PV structures: glass/SnO{sub 2}:F/n-CdS/p-CuSbS{sub 2}/C/Ag were formed at different conditions. • The PV parameters (J{sub sc}, V{sub oc}, and FF) were evaluated from the J–V characteristics. • J{sub sc}: 0.52–3.20 mA/cm{sup 2}, V{sub oc}:187–323 mV, FF: 0.27–0.48 were obtained. - Abstract: In this work, we report preparation and characterization of CuSbS{sub 2} thin films by heating glass/Sb{sub 2}S{sub 3}/Cu layers and their use as absorber material in photovoltaic structures: glass/SnO{sub 2}:F/n-CdS/p-CuSbS{sub 2}/C/Ag. The Sb{sub 2}S{sub 3} thin films of 600 nm were prepared by chemical bath deposition on which copper thin films of 50 nm were thermally evaporated, and the glass/Sb{sub 2}S{sub 3}/Cu multilayers were heated in vacuum at different temperatures. X-ray diffraction analysis showed the formation of orthorhombic CuSbS{sub 2} after heating the precursor layers. Studies on identification and chemical state of the elements were done using X-ray photoelectron spectroscopy. The optical band gap of the CuSbS{sub 2} thin films was 1.55 eV and the thin films were photoconductive. The photovoltaic parameters of the devices using CuSbS{sub 2} as absorber and CdS as window layer were evaluated from the J–V curves, yielding J{sub sc}, V{sub oc}, and FF values in the range of 0.52–3.20 mA/cm{sup 2}, 187–323 mV, and 0.27–0.48, respectively, under illumination of AM1.5 radiation.

Synthesis and characterization of copper antimony tin sulphide thin films for solar cell applications

Energy Technology Data Exchange (ETDEWEB)

Ali, N., E-mail: nisar.ali@utm.my [Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, UTM Skudai, 81310 Johor (Malaysia); Department of Physics, Govt. Post Graduate Jehanzeb College Saidu Sharif, Swat, 19200 (Pakistan); Hussain, A. [Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, UTM Skudai, 81310 Johor (Malaysia); Ahmed, R., E-mail: rashidahmed@utm.my [Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, UTM Skudai, 81310 Johor (Malaysia); Wan Shamsuri, W.N. [Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, UTM Skudai, 81310 Johor (Malaysia); Fu, Y.Q., E-mail: richard.fu@northumbria.ac.uk [Department of Physics and Electrical Engineering, Faculty of Engineering & Environment, University of Northumbria, Newcastle upon Tyne, NE1 8ST (United Kingdom)

2016-12-30

Highlights: • A new and novel material for solar cell applications is demonstrated as a replacement for toxic and expansive compounds. • The materials used in this compound are abundant and low cost. • Compound exhibit unusual optical and electrical properties. • The band gap was found to be comparable with that of GaAs. - Abstract: Low price thin film modules based on Copper antimony tin sulphide (CATS) are introduced for solar harvesting to compete for the already developed compound semiconductors. Here, CATS thin films were deposited on soda lime glass by thermal evaporation technique followed by a rapid thermal annealing in an argon atmosphere. From Our XRD analysis, it was revealed that the annealed samples were poly-crystalline and their crystallinity was improved with increasing annealing temperature. The constituent elements and their corresponding chemical states were identified using X-ray photoelectron spectroscopy. The obtained optical band gap of 1.4 eV for CATS thin film is found nearly equal to GaAs – one of the highly efficient thin film material for solar cell technology. Furthermore, our observed good optical absorbance and low transmittance for the annealed CATS thin films in the visible region of light spectrum assured the aptness of the CATS thin films for solar cell applications.

Development of microforming process combined with thin film transfer printing

Directory of Open Access Journals (Sweden)

Koshimizu Kazushi

2015-01-01

Full Text Available Microforming receives a lot of attentions in the recent years due to the increased use of microparts in electronics and medical sectors. For the further functionalization of these micro devices, high functional surface with noble metals are strongly required for the devices in bio- and medical fields, such as bio-sensors. To realize the submillimeter structure of metal foils and micro to nanometer structures in one forming process, the present study proposes a combined process of microforming for metal foils and transfer printing of gold (Au thin films. To clarify the availability of the proposed combined process, transferability of Au thin films under micro bulging deformation are investigated. 0.1 mm-thick pure titanium (Ti foils and 100 nm-thick Au films were used as blank and functional materials, respectively. The forming tests of the proposed process were conducted. With increasing strain of Ti foils, Au TP areas increase. By this experiment, it’s confirmed that the hydrogen reduction of oxidation layers and the strain of Ti foil are significant factor for Au TP on Ti foils.

Preparation of thin nuclear targets

International Nuclear Information System (INIS)

Muggleton, A.H.F.

1979-03-01

Thin film backings, sources and targets are needed for many applications in low energy nuclear physics and nuclear chemistry experiments. A survey of techniques used in the preparation of nuclear targets is first briefly discussed. These are classified as chemical, mechanical and physical preparations. Vacuum evaporation, being the most generally used technique, is discussed in detail. It is highly desirable to monitor the film thickness and control the deposition rate during evaporation and to measure the final target thickness after deposition has concluded. The relative merits of various thickness measuring techniques are described. Stages in the fabrication and mounting of self-supporting foils are described in detail, with emphasis given to the preparation of thin self-supporting carbon foils used as target backings and stripper foils. Various target backings, and the merits of the more generally used release agents are described in detail. The preparations of more difficult elemental targets are discussed, and a comprehensive list of the common targets is presented

Post-foil interaction in foil-induced molecular dissociation

International Nuclear Information System (INIS)

Faibis, A.; Kanter, E.P.; Koenig, W.; Plesser, I.; Vager, Z.

1985-01-01

The authors have investigated the foil-induced dissociation of 175- 250- keV/amu CH + , NH + , and OH + , FH + and NeH + ions by coincident detection of the fragment atoms. The dissociation energies corresponding to in-foil and post-foil interactions were deduced from the measured relative flight times of the fragment pairs to a set of detectors downstream from the target. The authors considered final states consisting of a) a proton and a heavy-ion and, b) a hydrogen atom and a heavy-ion. Surprisingly, in both cases the energy released in the post-target interaction shows a similar linear increase with the charge state of the heavy partner

A discrete-time amplifier based on Thin-Film Trans-Capacitors for sensor systems on foil

OpenAIRE

Raiteri, D.; Roermund, van, A.H.M.; Cantatore, E.

2014-01-01

Organic materials can be used to fabricate sensors for physical and chemical quantities, and also to make electronics. The integration of these two elements holds the promise to enable novel smart-sensors on foil. In this paper, we deal with the design of the first stage of a signal conditioning chain on foil: the amplifier. The poor electrical performance of organic TFTs hampers the design of complex circuits, and negatively affects the characteristics of continuous-time amplifiers. In order...

A thin two-phase foils deformed by an interfacial dislocation in anisotropic elasticity

Directory of Open Access Journals (Sweden)

Madani, Salah

2005-04-01

Full Text Available The purpose of this work is the numerical resolution, in the case of anisotropic elasticity, of the problem of a dislocation parallel and near to the two free surfaces of a thin bicrystal. This case is obtained while making the period of a network of misfit dislocations much greater than the thickness of the two foils. As a result, in the vicinity of the dislocation, the limiting bondary conditions will be close to that of Volterra translation dislocation. The elastic fields of displacement and stress are calculated for various orientations of the burgers vector. Before this calculation, we tested the precision of the results of the program by comparing the interfacial relative displacement obtained from this one to the results of the analytical expression describing this same displacement. The thin bicristal Al/Al2Cu, that made the object of several investigations, is treated like example. The results obtained are compared to those obtained in isotropic elasticity.

Este trabajo aborda la resolución numérica en anisotropía elástica, del problema de una dislocación paralela cercana a las superficies libres de un bi-cristal delgado. Este problema se genera cuando el periodo de la red de dislocaciones desplazadas es mucho mayor que el espesor de la bi-lámina. Como resultados, en la vecindad de la dislocación, las condiciones de contorno estarán cercanas a la dislocación de traslación de Volterra. Los campos elásticos de desplazamiento y las tensiones se calcularon para distintas orientaciones del vector de burgers. Como paso previo a los cálculos, se comprobó la precisión de los resultados del programa comparando le desplazamiento relativo interracial obtenido con los resultados de la expresión analítica que describen dicho desplazamiento. Se emplearon como ejemplo bi-cristales de Al/Al2Cu, debido a su empleo en varias investigaciones. Los resultados fueron comparados con los obtenidos en elasticidad isótropa.

Fabricating 40 µm-thin silicon solar cells with different orientations by using SLiM-cut method

Science.gov (United States)

Wang, Teng-Yu; Chen, Chien-Hsun; Shiao, Jui-Chung; Chen, Sung-Yu; Du, Chen-Hsun

2017-10-01

Thin silicon foils with different crystal orientations were fabricated using the stress induced lift-off (SLiM-cut) method. The thickness of the silicon foils was approximately 40 µm. The ≤ft foil had a smoother surface than the ≤ft foil. With surface passivation, the minority carrier lifetimes of the ≤ft and ≤ft silicon foil were 1.0 µs and 1.6 µs, respectively. In this study, 4 cm2-thin silicon solar cells with heterojunction structures were fabricated. The energy conversion efficiencies were determined to be 10.74% and 14.74% for the ≤ft and ≤ft solar cells, respectively. The surface quality of the silicon foils was determined to affect the solar cell character. This study demonstrated that fabricating the solar cell by using silicon foil obtained from the SLiM-cut method is feasible.

The anodization synthesis of copper oxide nanosheet arrays and their photoelectrochemical properties

Energy Technology Data Exchange (ETDEWEB)

Shu, Xia [School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); Zheng, Hongmei [School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); Key Laboratory of Advanced Functional Materials and Devices of Anhui Province, Hefei 230009 (China); Xu, Guangqing, E-mail: gqxu1979@hfut.edu.cn [School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); Key Laboratory of Advanced Functional Materials and Devices of Anhui Province, Hefei 230009 (China); Zhao, Jiebo [School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); Cui, Lihua [School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); School of Materials Science and Engineering, Beifang University of Nationalities, Yinchuan 750021 (China); Cui, Jiewu; Qin, Yongqiang; Wang, Yan [School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); Zhang, Yong [School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); Key Laboratory of Advanced Functional Materials and Devices of Anhui Province, Hefei 230009 (China); Wu, Yucheng, E-mail: ycwu@hfut.edu.cn [School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China); Key Laboratory of Advanced Functional Materials and Devices of Anhui Province, Hefei 230009 (China)

2017-08-01

Graphical abstract: Current-time and potential-time curves of the copper foil anodization process, CV of copper substrate in anodization solution and SEM morphologies of anodization products on Cu substrates obtained at different time. - Highlights: • Copper oxides nanosheet arrays were achieved via anodization method. • The growth mechanisms of the copper anodization process were studied. • Photoelectrochemical performances of copper oxides NSAs were studied. - Abstract: We studied the growth of copper oxide nanosheet arrays on copper foil via a simple anodization method. The structures, morphologies, and elemental compositions of the specimens were characterized with an X-ray diffractometer, scanning electron microscope, high resolution transmission electron microscope, and X-ray photoelectron spectrometer. The copper oxide (Cu{sub 2}O and CuO) nanosheet arrays were comprised of 30-nm-thick nanosheets that stand vertically on the Cu substrate. The anodizing parameters, such as the current density, temperature, and polyethylene glycol concentration, were optimized to obtain the regular nanosheet arrays. The optical absorption properties of the anodized products were evaluated using a diffuse reflectance spectrometer, and broad and strong optical absorption bands arising from the UV to visible region were observed. The photoelectrochemical performance of the nanosheet arrays was measured with chronoamperometry and cyclic voltammetry on an electrochemical workstation equipped with a Xe lamp (wavelength >400 nm). A negative photocurrent was obtained due to the p-type semiconductor of the copper oxides. The copper oxide nanosheet arrays achieve the highest photocurrent of 0.4 mA/cm{sup 2} at the current density of 1.0 A/dm{sup 2}, temperature of 70 °C, and polyethylene glycol concentration of 0.5 g/L.

Nonlinear Dynamics of a Foil Bearing Supported Rotor System: Simulation and Analysis

Science.gov (United States)

Li, Feng; Flowers, George T.

1996-01-01

Foil bearings provide noncontacting rotor support through a number of thin metal strips attached around the circumference of a stator and separated from the rotor by a fluid film. The resulting support stiffness is dominated by the characteristics of the foils and is a nonlinear function of the rotor deflection. The present study is concerned with characterizing this nonlinear effect and investigating its influence on rotordynamical behavior. A finite element model is developed for an existing bearing, the force versus deflection relation characterized, and the dynamics of a sample rotor system are studied. Some conclusions are discussed with regard to appropriate ranges of operation for such a system.

High-resolution x-ray imaging of planar foils irradiated by the Nike KrF laser

International Nuclear Information System (INIS)

Brown, C.; Seely, J.; Feldman, U.; Obenschain, S.; Bodner, S.; Pawley, C.; Gerber, K.; Sethian, J.; Mostovych, A.; Aglitskiy, Y.; Lehecka, T.; Holland, G.

1997-01-01

Thin plastic (CH) foils were irradiated by the Naval Research Laboratory Nike [Obenschain et al., Phys. Plasmas 3, 2098 (1996)] KrF laser and were imaged in the x-ray and extreme ultraviolet regions with two-dimensional spatial resolution in the 3 endash 10 μm range. The CH foils were backlit by a silicon plasma. A spherically curved quartz crystal produced monochromatic images of the Si +12 resonance line radiation with energy 1865 eV that was transmitted by the CH foils. Instabilities that were seeded by linear ripple patterns on the irradiated sides of CH foils were observed. The ripple patterns had periods in the 31 endash 125 μm range and amplitudes in the 0.25 endash 5.0 μm range. The silicon backlighter emission was recorded by an x-ray spectrometer, and the 1865 eV resonance line emission was recorded by a fast x-ray diode. The multilayer mirror telescope recorded images of the C +3 1550 Angstrom emission (energy 8.0 eV) from the backside of the CH foils. copyright 1997 American Institute of Physics

Experimental study of relative level populations in beam-foil excited Ar+7 and Kr+7

International Nuclear Information System (INIS)

Bashkin, S.; Oona, H.; Veje, E.

1981-01-01

The relative level populations in beam-foil excited sodium-like argon (Ar VIII) and copper-like krypton (Kr VIII) have been studied at 2 MeV projectile energy. In Ar VIII, the 3p and the 3d terms are strongly excited. The level population decreases rapidly with increasing value of the principal quantum number n, reaches a minimum for levels with n = 5 or 6, but increases then and reaches a strong maximum for levels with n approximately 11. Also the Kr VIII data show a population maximum for levels with n = 11. The strong 3p and 3d level excitations in Ar VIII are explained as selective inner-shell processes which can be understood in the molecular-orbital electron-promotion picture. The preferential population of high-flying Rydberg states is explained as resulting from a near-resonance electron transfer from the valence band of the carbon foil to the projectile. This process takes place when the projectile leaves the back of the foil. (Auth.)

n-Type Conductivity of Cu2O Thin Film Prepared in Basic Aqueous Solution Under Hydrothermal Conditions

Science.gov (United States)

Ursu, Daniel; Miclau, Nicolae; Miclau, Marinela

2018-03-01

We report for the first time in situ hydrothermal synthesis of n-type Cu2O thin film using strong alkaline solution. The use of copper foil as substrate and precursor material, low synthesis temperature and short reaction time represent the arguments of a new, simple, inexpensive and high field synthesis method for the preparation of n-type Cu2O thin film. The donor concentration of n-type Cu2O thin film obtained at 2 h of reaction time has increased two orders of magnitude than previous reported values. We have demonstrated n-type conduction in Cu2O thin film prepared in strong alkaline solution, in the contradiction with the previous works. Based on experimental results, the synthesis mechanism and the origin of n-type photo-responsive behavior of Cu2O thin film were discussed. We have proposed that the unexpected n-type character could be explained by H doping of Cu2O thin film in during of the hydrothermal synthesis that caused the p-to-n conductivity-type conversion. Also, this work raises new questions about the origin of n-type conduction in Cu2O thin film, the influence of the synthesis method on the nature of the intrinsic defects and the electrical conduction behavior.

Stainless Steel Foil with Improved Creep-Resistance for Use in Primary Surface Recuperators for Gas Turbine Engines

International Nuclear Information System (INIS)

Browning, P.F.; Fitzpatrick, M.; Grubb, J.F.; Klug, R.C.; Maziasz, P.J.; Montague, J.P.; Painter, R.A.; Swindeman, R.W.

1998-01-01

Primary surface recuperators (PSRs) are compact heat-exchangers made from thin-foil type 347 austenitic stainless steel, which boost the efficiency of land-based gas turbine engines. Solar Turbines uses foil folded into a unique corrugated pattern to maximize the primary surface area for efficient heat transfer between hot exhaust gas on one side, and the compressor discharge air on the other side of the foil. Allegheny-Ludlum produces 0.003 - 0.0035 in. thick foil for a range of current turbine engines using PSRs that operate at up to 660 degrees C. Laboratory-scale processing modification experiments recently have demonstrated that dramatic improvements can be achieved in the creep resistance of such typical 347 stainless steel foils. The modified processing enables fine NbC carbide precipitates to develop during creep at 650-700 degrees C, which provides strength even with a fine grain size. Such improved creep-resistance is necessary for advanced turbine systems that will demand greater materials performance and reliability at higher operating conditions. The next challenges are to better understand the nature of the improved creep resistance in these 347 stainless steel foil, and to achieve similar improvements with scale-up to commercial foil production

Effect of the neutral charge fraction in the Coulomb explosion of H2+ ions through aluminum foils

International Nuclear Information System (INIS)

Denton, Cristian D.; Abril, Isabel; Barriga-Carrasco, Manuel D.; Garcia-Molina, Rafael; Lantschner, Gerardo H.; Eckardt, Juan C.; Arista, Netor R.

2002-01-01

The Coulomb explosion of the proton fragments dissociated from H 2 + molecules moving through thin aluminum foils has been studied by means of their energy spectra, measured in the forward direction, and by computer simulations. The covered energy range goes from 25 to 100 keV/u. Estimations of the neutral charge fraction of the fragments inside the foil have been obtained by comparison of the experimental energy spectra with the computer simulations

Optical and Electrical Properties of Copper Oxide Thin Films Synthesized by Spray Pyrolysis Technique

Directory of Open Access Journals (Sweden)

S. S. Roy

2015-08-01

Full Text Available Copper oxide (CuO thin films have been synthesized on to glass substrates at different temperatures in the range 250-450 °C by spray pyrolysis technique from aqueous solution using cupric acetate Cu(CH3COO2·H2O as a precursor. The structure of the deposited CuO thin films characterized by X-ray diffraction, the surface morphology was observed by a scanning electron microscope, the presence of elements was detected by energy dispersive X-ray analysis, the optical transmission spectra was recorded by ultraviolet-visible spectroscopy and electrical resistivity was studied by Van-der Pauw method. All the CuO thin films, irrespective of growth temperature, showed a monoclinic structure with the main CuO (111 orientation, and the crystallite size was about 8.4784 Å for the thin film synthesized at 350 °C. The optical transmission of the as-deposited film is found to decrease with the increase of substrate temperature, the optical band gap of the thin films varies from 1.90 to 1.60 eV and the room temperature electrical resistivity varies from 30 to18 Ohm·cm for the films grown at different substrate temperatures.

Environmental and health aspects of copper-indium-diselenide thin-film photovoltaic modules

International Nuclear Information System (INIS)

Steinberger, H.; Thumm, W.; Freitag, R.; Moskowitz, P.D.; Chapin, R.

1994-01-01

Copper-indium-diselenide (CIS) is a semiconductor compound that can be used to produce thin-film photovoltaic modules. There is on-going research being conducted by various federal agencies and private industries to demonstrate the commercial viability of this material. Because this is a new technology, and because scant information about the health and environmental hazards associated with the use of this material is available, studies have been initiated to characterize the environmental mobility and environmental toxicology of this compound. The objective of these studies is to identify the environmental and health hazards associated with the production, use, and disposal of CIS thin-film photovoltaic modules. The program includes both experimental and theoretical components. Theoretical studies are being undertaken to estimate material flows through the environment for a range of production options as well as use and disposal scenarios. The experimental programs characterize the physical, chemical e.g. leachability and biological parameters e.g. EC 50 in daphnia and algae, and feeding studies in rats

Oxidative fabrication of patterned, large, non-flaking CuO nanowire arrays

International Nuclear Information System (INIS)

Mumm, F; Sikorski, P

2011-01-01

We report a simple and fast approach to fabricate large, non-flaking arrays of CuO nanowires by oxidizing thin copper substrates in air. Oxidative CuO nanowire growth is commonly accompanied by oxide layer flaking due to stress at the copper-copper oxide interface. Using thin substrates is shown to prevent this flaking by introducing favourable material thickness ratios in the samples after oxidation. Additionally, thin foils allow larger scale topographic patterns to be transferred from an underlying mould to realize non-flat, nanowire-decorated surfaces. Further patterning is possible by electrodeposition of a nickel layer, which restricts nanowire growth to specific areas of the sample.

Dependency of the band gap of electrodeposited Copper oxide thin films on the concentration of copper sulfate (CuSO4.5H2O) and pH in bath solution for photovoltaic applications

KAUST Repository

Islam, Md. Anisul

2016-03-10

In this study, Copper oxide thin films were deposited on copper plate by electrodeposition process in an electrolytic bath containing CuSO4.5H2O, 3M lactic acid and NaOH. Copper oxide films were electrodeposited at different pH and different concentration of CuSO4.5H2O and the optical band gap was determined from their absorption spectrum which was obtained from UV-Vis absorption spectroscopy. It was found that copper oxide films which were deposited at low concentration of CuSO4.5H2O have higher band gap than those deposited at higher bath concentration. The band gap of copper oxide films also significantly changes with pH of the bath solution. It was also observed that with the increase of the pH of bath solution band gap of copper oxide film decreased. © 2015 IEEE.

Process for anodizing aluminum foil

International Nuclear Information System (INIS)

Ball, J.A.; Scott, J.W.

1984-01-01

In an integrated process for the anodization of aluminum foil for electrolytic capacitors including the formation of a hydrous oxide layer on the foil prior to anodization and stabilization of the foil in alkaline borax baths during anodization, the foil is electrochemically anodized in an aqueous solution of boric acid and 2 to 50 ppm phosphate having a pH of 4.0 to 6.0. The anodization is interrupted for stabilization by passing the foil through a bath containing the borax solution having a pH of 8.5 to 9.5 and a temperature above 80 0 C. and then reanodizing the foil. The process is useful in anodizing foil to a voltage of up to 760 V

The use of polyimide foils to prevent contamination from self-sputtering of {sup 252}Cf deposits in high-accuracy fission counting

Energy Technology Data Exchange (ETDEWEB)

Gilliam, David M. [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States)], E-mail: david.gilliam@nist.gov; Yue, Andrew [Department of Physics and Astronomy, University of Tennessee, Knoxville, TN (United States); Scott Dewey, M. [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States)

2008-06-01

It is demonstrated that a thin polyimide foil can be employed to prevent contamination from the self-sputtering of a {sup 252}Cf source under vacuum, with small energy loss of the emitted fission fragments, with very small effect on the efficiency of counting the fission fragments, and with a long lifetime of the plastic foils.

Tungsten foil laminate for structural divertor applications – Analyses and characterisation of tungsten foil

International Nuclear Information System (INIS)

Reiser, Jens; Rieth, Michael; Dafferner, Bernhard; Hoffmann, Andreas; Yi Xiaoou; Armstrong, David E.J.

2012-01-01

It has been attempted for several years to synthesise a tungsten material with a low brittle-to-ductile transition temperature and a high fracture toughness that can be used for structural parts. It was shown in our previous work that tungsten foil is ductile at room temperature and that this ductility can be transformed to bulk by synthesising a tungsten laminate. In this work we want to focus on tungsten foil and assess the microstructure as well as the mechanical properties of the foil. The assessment of the microstructure of 0.1 mm tungsten foil will be performed using electron microscopy. It will be shown that the grains of the tungsten foil have a dimension of 0.5 μm × 3 μm × 15 μm and a clear texture in (1 0 0) 〈0 1 1〉. This texture becomes even more pronounced by annealing. Three-point-bending tests with tungsten foil, as-received, will define the barriers: ductile at room temperature and brittle in liquid nitrogen (−196 °C). This shows that the ductility is a thermally activated process. Recrystallised tungsten foil (annealed for 1 h/2700 °C) shows ductile material behaviour at 200 °C. The paper closes with a discussion on the reasons of the ductility of 0.1 mm tungsten foil. These might be the ultra fine grained (UFG) microstructure or, in other words, a nano microstructure (see tungsten foil as-received), the high amount of mobile edge dislocations, and/or the foil effect, which means that dislocations can move to the surface and are annihilated (see tungsten foil recrystallised).

A Systems Approach to the Solid Lubrication of Foil Air Bearings for Oil-Free Turbomachinery

Science.gov (United States)

DellaCorte, Christopher; Zaldana, Antonio R.; Radil, Kevin C.

2002-01-01

Foil air bearings are self-acting hydrodynamic bearings which rely upon solid lubricants to reduce friction and minimize wear during sliding which occurs at start-up and shut-down when surface speeds are too low to allow the formation of a hydrodynamic air film. This solid lubrication is typically accomplished by coating the non-moving foil surface with a thin, soft polymeric film. The following paper introduces a systems approach in which the solid lubrication is provided by a combination of self lubricating shaft coatings coupled with various wear resistant and lubricating foil coatings. The use of multiple materials, each providing different functions is modeled after oil-lubricated hydrodynamic sleeve bearing technology which utilizes various coatings and surface treatments in conjunction with oil lubricants to achieve optimum performance. In this study, room temperature load capacity tests are performed on journal foil air bearings operating at 14,000 rpm. Different shaft and foil coating technologies such as plasma sprayed composites, ceramic, polymer and inorganic lubricant coatings are evaluated as foil bearing lubricants. The results indicate that bearing performance is improved through the individual use of the lubricants and treatments tested. Further, combining several solid lubricants together yielded synergistically better results than any material alone.

Secondary electron emission from a thin carbon foil induced by H+, He2+ and Li3+ at fixed velocity of 1 MeV/u

International Nuclear Information System (INIS)

Ogawa, H.; Sorai, K.; Amano, S.; Ishii, K.; Kaneko, T.

2013-01-01

The statistical distributions of the number of forward- and backward-emitted secondary electrons (SE’s) from a thin carbon foil have been measured simultaneously in coincidence with foil-transmitted H + , He 2+ and Li 3+ ions of 1 MeV/u in order to examine the forward–backward correlation of the SE emission (refer to as ‘FB correlation’ hereafter). With these projectiles, we have also measured the energy spectrum of SEs emitted from another carbon foil of similar thickness in the direction around 0° with respect to the incident beams. From the emission statistics data, it is found that both of the inclusive forward and backward SE yields divided by the square of the projectile atomic number (Z p ) decrease with increasing Z p . This trend is qualitatively consistent with previous works by other authors. On the other hand, it has been certified from the energy spectra that the yields of binary electron scale well with Z p 2 . As for the FB correlation, the forward- or backward-emitted SE yield decreases gradually with increasing the number of SEs emitted in the opposite directions. This so-called ‘negative FB correlation’ appears to be pronounced for He 2+ and Li 3+ ions compared with that for H + ions. Since low energy internal SEs do not contribute to the FB correlation, the observed Z p -dependent FB correlation seems to be consistent with the well Z p 2 -scaled production of high energy internal SEs and the decrease of the inclusive forward and backward SE yields with respect to this scaling

The stopping powers and energy straggling of heavy ions in polymer foils

Energy Technology Data Exchange (ETDEWEB)

Mikšová, R., E-mail: miksova@ujf.cas.cz [Nuclear Physics Institute of the Academy of Sciences of the Czech Republic, v.v.i., 250 68 Rez (Czech Republic); Department of Physics, Faculty of Science, J.E. Purkinje University, Ceske Mladeze 8, 400 96 Usti nad Labem (Czech Republic); Macková, A.; Malinský, P. [Nuclear Physics Institute of the Academy of Sciences of the Czech Republic, v.v.i., 250 68 Rez (Czech Republic); Department of Physics, Faculty of Science, J.E. Purkinje University, Ceske Mladeze 8, 400 96 Usti nad Labem (Czech Republic); Hnatowicz, V. [Nuclear Physics Institute of the Academy of Sciences of the Czech Republic, v.v.i., 250 68 Rez (Czech Republic); Slepička, P. [Department of Solid State Engineering, Institute of Chemical Technology, 166 28 Prague (Czech Republic)

2014-07-15

The stopping power and energy straggling of {sup 7}Li, {sup 12}C and {sup 16}O ions in thin poly(etheretherketone) (PEEK), polyethylene terephthalate (PET) and polycarbonate (PC) foils were measured in the incident beam energy range of 9.4–11.8 MeV using an indirect transmission method. Ions scattered from a thin gold target at an angle of 150° were registered by a partially depleted PIPS detector, partly shielded with a polymer foil placed in front of the detector. Therefore, the signals from both direct and slowed down ions were visible in the same energy spectrum, which was evaluated by the ITAP code, developed at our laboratory. The ITAP code was employed to perform a Gaussian-fitting procedure to provide a complete analysis of each measured spectrum. The measured stopping powers were compared with the predictions obtained from the SRIM-2008 and MSTAR codes and with previous experimental data. The energy straggling data were compared with those calculated by using Bohr’s, Lindhard–Scharff and Bethe–Livingston theories.

The stopping powers and energy straggling of heavy ions in polymer foils

International Nuclear Information System (INIS)

Mikšová, R.; Macková, A.; Malinský, P.; Hnatowicz, V.; Slepička, P.

2014-01-01

The stopping power and energy straggling of 7 Li, 12 C and 16 O ions in thin poly(etheretherketone) (PEEK), polyethylene terephthalate (PET) and polycarbonate (PC) foils were measured in the incident beam energy range of 9.4–11.8 MeV using an indirect transmission method. Ions scattered from a thin gold target at an angle of 150° were registered by a partially depleted PIPS detector, partly shielded with a polymer foil placed in front of the detector. Therefore, the signals from both direct and slowed down ions were visible in the same energy spectrum, which was evaluated by the ITAP code, developed at our laboratory. The ITAP code was employed to perform a Gaussian-fitting procedure to provide a complete analysis of each measured spectrum. The measured stopping powers were compared with the predictions obtained from the SRIM-2008 and MSTAR codes and with previous experimental data. The energy straggling data were compared with those calculated by using Bohr’s, Lindhard–Scharff and Bethe–Livingston theories

Tandem accelerator transmission and life measurement of 50 keV/amu Au ions using stripper foil made by INS

Energy Technology Data Exchange (ETDEWEB)

Ishii, Satoshi; Takahashi, Tsutomu; Shima, Kunihiro [Tsukuba Univ., Ibaraki (Japan). Tandem Accelerator Center; Sugai, Isamu; Oyaizu, Mitsuhiro

1996-12-01

The role of stripper foil is the charge exchange of ions. The thickness for attaining equilibrium in charge exchange becomes thinner as ions become lower speed and heavier. Accordingly, for the stripper foil, thin foil thickness is demanded in addition to the demand of long life. The stripper foil made by INS, University of Tokyo, is recognized as its long life. In the 12 UD PELETRON tandem accelerator in University of Tsukuba, in order to meet the demand of users to use heavy ions, the use of long life stripper foil has become urgent necessity. Therefore, as for the foil made by INS, the life by Au ion irradiation and the Au ion transmission were measured four times. As to the features of the test of this time, irradiation was carried out under the severe condition for the foil of low speed Au ions, and the change of beam transmission with time lapse was observed in addition to the life. The method of measurement is explained. The preparation of foils and the determination of their thickness are reported. As the results, the lifetime of the foils made by INS and the thickness dependence and time dependence or dose dependence of the transmission of low speed, heavy Au-197 ions are described. (K.I.)

Recent progress in particle acceleration from the interaction between thin-foil targets and J-KAREN laser pulses

Science.gov (United States)

Nishiuchi, Mamiko; Pirozhkov, Alexander S.; Sakaki, Hironao; Ogura, Koichi; Esirkepov, Timur Zh; Tanimoto, Tsuyoshi; Yogo, Akifumi; Hori, Toshihiko; Sagisaka, Akito; Fukuda, Yuji; Kanasaki, Masato; Kiriyama, Hiromitsu; Shimomura, Takuya; Tanoue, Manabu; Nakai, Yoshiki; Sasao, Hajime; Sasao, Fumitaka; Kanazawa, Shuhei; Kondo, Shuji; Matsumoto, Yoshihiro; Sakai, Seiji; Brenner, Ceri; Neely, David; Bulanov, Sergei V.; Kondo, Kiminori

2012-07-01

From the interaction between the high-contrast (˜more than 1010) 130 TW Ti:sapphire laser pulse and Stainless Steel-2.5 um-thick tape target, proton beam with energies up to 23 MeV with the conversion efficiency of ˜1% is obtained. After plasma mirror installation for contrast improvement, from the interaction between the 30 TW laser pulse and thin-foil target installed on the target holder with the hole whose shape is associated with the design of the well-known Wehnelt electrode of electron-gun, a 7 MeV intense proton beam is controlled dynamically and energy selected by the self-induced quasi-static electric field on the target holder. From the highly divergent beam having continuous spectrum, which are the typical features of the laser-driven proton beams from the interactions between the short-pulse laser and solid target, the spatial distribution of 7 MeV proton bunch is well manipulated to be focused to an small spots with an angular distribution of ˜10 mrad. The number of protons included in the bunch is >106.

Development of nanodiamond foils for H- stripping to Support the Spallation Neutron Source (SNS) using hot filament chemical vapor deposition

Energy Technology Data Exchange (ETDEWEB)

Vispute, R D [Blue Wave Semiconductors; Ermer, Henry K [Blue Wave Semiconductors; Sinsky, Phillip [Blue Wave Semiconductors; Seiser, Andrew [Blue Wave Semiconductors; Shaw, Robert W [ORNL; Wilson, Leslie L [ORNL

2014-01-01

Thin diamond foils are needed in many particle accelerator experiments regarding nuclear and atomic physics, as well as in some interdisciplinary research. Particularly, nanodiamond texture is attractive for this purpose as it possesses a unique combination of diamond properties such as high thermal conductivity, mechanical strength and high radiation hardness; therefore, it is a potential material for energetic ion beam stripper foils. At the ORNL Spallation Neutron Source (SNS), the installed set of foils must be able to survive a nominal five-month operation period, without the need for unscheduled costly shutdowns and repairs. Thus, a small foil about the size of a postage stamp is critical to the operation of SNS and similar sources in U.S. laboratories and around the world. We are investigating nanocrystalline, polycrystalline and their admixture films fabricated using a hot filament chemical vapor deposition (HFCVD) system for H- stripping to support the SNS at Oak Ridge National Laboratory. Here we discuss optimization of process variables such as substrate temperature, process gas ratio of H2/Ar/CH4, substrate to filament distance, filament temperature, carburization conditions, and filament geometry to achieve high purity diamond foils on patterned silicon substrates with manageable intrinsic and thermal stresses so that they can be released as free standing foils without curling. An in situ laser reflectance interferometry tool (LRI) is used for monitoring the growth characteristics of the diamond thin film materials. The optimization process has yielded free standing foils with no pinholes. The sp3/sp2 bonds are controlled to optimize electrical resistivity to reduce the possibility of surface charging of the foils. The integrated LRI and HFCVD process provides real time information on the growth of films and can quickly illustrate growth features and control film thickness. The results are discussed in the light of development of nanodiamond foils that

Preparation and investigation of diamond-like carbon stripper foils by filtered cathodic vacuum arc

International Nuclear Information System (INIS)

Fan, Qiwen; Du, Yinghui; Zhang, Rong; Xu, Guoji

2013-01-01

Thin diamond-like carbon (DLC) stripper foils ∼5μg/cm 2 in thickness were produced and evaluated as heavy-ion strippers for the Beijing HI-13 Tandem Accelerator. The DLC layers ∼4μg/cm 2 in thickness were produced by the filtered cathodic vacuum arc technology onto glass slides coated with betaine–saccharose as releasing agent, which were previously covered with evaporated carbon layers ∼1μg/cm 2 in thickness by the controlled ac arc-discharge method. Irradiation lifetimes of the DLC stripper foils were tested using the heavy-ion beams at the terminal of the Beijing HI-13 Tandem Accelerator, and compared with those of the standard carbon stripper foils made by the combined dc and ac arc-discharge method. The measurements indicate that the DLC stripper foils outlast the standard combined dc and ac arc-discharge carbon stripper foils by a factor of at least 13 and 4 for the 197 Au − (∼9MeV, ∼1μA) and 63 Cu − (∼9MeV, ∼1μA) ion beams, respectively. The structure and properties of the DLC foils deposited onto silicon substrates by the filtered cathodic vacuum arc technology were also evaluated and analyzed by scanning electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. The scanning electron microscopy images show that the DLC foils contain hardly droplets through the double 90° filters. The X-ray photoelectron spectrum indicates that sp 3 bonds of the DLC foils exceed 70%. The integral intensity ratio of the D peak to the G peak (I D /I G ) measured by the Raman spectroscopy is 0.78

Material Parameters for Creep Rupture of Austenitic Stainless Steel Foils

Science.gov (United States)

Osman, H.; Borhana, A.; Tamin, M. N.

2014-08-01

Creep rupture properties of austenitic stainless steel foil, 347SS, used in compact recuperators have been evaluated at 700 °C in the stress range of 54-221 MPa to establish the baseline behavior for its extended use. Creep curves of the foil show that the primary creep stage is brief and creep life is dominated by tertiary creep deformation with rupture lives in the range of 10-2000 h. Results are compared with properties of bulk specimens tested at 98 and 162 MPa. Thin foil 347SS specimens were found to have higher creep rates and higher rupture ductility than their bulk specimen counterparts. Power law relationship was obtained between the minimum creep rate and the applied stress with stress exponent value, n = 5.7. The value of the stress exponent is indicative of the rate-controlling deformation mechanism associated with dislocation creep. Nucleation of voids mainly occurred at second-phase particles (chromium-rich M23C6 carbides) that are present in the metal matrix by decohesion of the particle-matrix interface. The improvement in strength is attributed to the precipitation of fine niobium carbides in the matrix that act as obstacles to the movement of dislocations.

Thin copper oxide films prepared by ion beam sputtering with subsequent thermal oxidation: Application in chemiresistors

Energy Technology Data Exchange (ETDEWEB)

Horak, P., E-mail: phorak@ujf.cas.cz [Nuclear Physics Institute, Academy of Sciences of the Czech Republic, 250 68 Řež (Czech Republic); Bejsovec, V.; Vacik, J.; Lavrentiev, V. [Nuclear Physics Institute, Academy of Sciences of the Czech Republic, 250 68 Řež (Czech Republic); Vrnata, M. [Department of Physics and Measurements, The University of Chemistry and Technology, Prague, Technická 5, 166 28 Prague 6 (Czech Republic); Kormunda, M. [Department of Physics, Jan Evangelista Purkyně University in Ústí nad Labem, České mládeže 8, 400 96 Ústí nad Labem (Czech Republic); Danis, S. [Department of Condensed Matter Physics, Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 5, 121 16 Prague 2 (Czech Republic)

2016-12-15

Highlights: • A rapid oxidation process of thin copper films. • Sheet resistance up to 10{sup 9} Ω/◊. • Mixed oxide phase at 200 °C with significant hydroxide presence. • Gas sensing response to 1000 ppm of hydrogen and methanol vapours. • Increased sensitivity with Pd and Au catalyst to hydrogen and methanol, respectively. - Abstract: Copper oxide films were prepared by thermal oxidation of thin Cu films deposited on substrates by ion beam sputtering. The subsequent oxidation was achieved in the temperature range of 200 °C–600 °C with time of treatment from 1 to 7 h (with a 1-h step) in a furnace open to air. At temperatures 250 °C–600 °C, the dominant phase formed was CuO, while at 200 °C mainly the Cu{sub 2}O phase was identified. However, the oxidation at 200 °C led to a more complicated composition − in the depth Cu{sub 2}O phase was observed, though in the near-surface layer the CuO dominant phase was found with a significant presence of Cu(OH){sub 2}. A limited amount of Cu{sub 2}O was also found in samples annealed at 600 °C. The sheet resistance R{sub S} of the as-deposited Cu sample was 2.22 Ω/□, after gradual annealing R{sub S} was measured in the range 2.64 MΩ/□–2.45 GΩ/□. The highest R{sub S} values were obtained after annealing at 300 °C and 350 °C, respectively. Oxygen depth distribution was studied using the {sup 16}O(α,α) nuclear reaction with the resonance at energy 3032 keV. It was confirmed that the higher oxidation degree of copper is located in the near-surface region. Preliminary tests of the copper oxide films as an active layer of a chemiresistor were also performed. Hydrogen and methanol vapours, with a concentration of 1000 ppm, were detected by the sensor at an operating temperature of 300 °C and 350 °C, respectively. The response of the sensors, pointed at the p-type conductivity, was improved by the addition of thin Pd or Au catalytic films to the oxidic film surface. Pd-covered films showed

Effect of hydroxyl bond formation on the adhesion improvement of a polyethylene copper thin film system

International Nuclear Information System (INIS)

Camacho, M.; Blantocas, G.; Ramos, H.

2009-01-01

Formation of hydroxyl bonds on the surface of a gas plasma treated high density polyethylene (HDPE) sheets significantly enhanced the adhesion strength of the polyethylene copper thin film system. Surface treatments using oxygen gas plasmas at varying plasma parameters are applied in this study to identify the most effective plasma parameters that would promote the best adhesion strength. Analysis of gas plasma adulterated HDPE sheets showed best enhancement of polyethylene copper adhesion after an oxygen gas plasma treatment for 60 minutes at 5mA discharge current. Scanning Electron Microscopy Analysis, Fourier Transform Infrared Spectroscopy and Adhesion measurements using Pull out Force Analysis were used to measure the changes in the surface chemistry and surface topology of the HDPE sheets. (author)

Plasma flow switch and foil implosion experiments on Pegasus II

International Nuclear Information System (INIS)

Cochrane, J.C.; Bartsch, R.R.; Benage, J.R.; Forman, P.R.; Gribble, R.F.; Ladish, J.S.; Oona, H.; Parker, J.V.; Scudder, D.W.; Shlachter, J.S.; Wysocki, F.J.

1993-01-01

Pegasus II is the upgraded version of Pegasus, a pulsed power machine used in the Los Alamos AGEX (Above Ground EXperiments) program. A goal of the program is to produce an intense (> 100 TW) source of soft x-rays from the thermalization of the kinetic energy of a 1 to 10 MJ plasma implosion. The radiation pulse should have a maximum duration of several 10's of nanoseconds and will be used in the study of fusion conditions and material properties. The radiating plasma source will be generated by the thermalization of the kinetic energy of an imploding cylindrical, thin, metallic foil. This paper addresses experiments done on a capacitor bank to develop a switch (plasma flow switch) to switch the bank current into the load at peak current. This allows efficient coupling of bank energy into foil kinetic energy

Effect of the neutral charge fraction in the Coulomb explosion of H{sub 2}{sup +} ions through aluminum foils

Energy Technology Data Exchange (ETDEWEB)

Denton, Cristian D. E-mail: cdenton@fis.utfsm.cl; Abril, Isabel; Barriga-Carrasco, Manuel D.; Garcia-Molina, Rafael; Lantschner, Gerardo H.; Eckardt, Juan C.; Arista, Netor R

2002-06-01

The Coulomb explosion of the proton fragments dissociated from H{sub 2}{sup +} molecules moving through thin aluminum foils has been studied by means of their energy spectra, measured in the forward direction, and by computer simulations. The covered energy range goes from 25 to 100 keV/u. Estimations of the neutral charge fraction of the fragments inside the foil have been obtained by comparison of the experimental energy spectra with the computer simulations.

Nanocarbon-copper thin film as transparent electrode

International Nuclear Information System (INIS)

Isaacs, R. A.; Zhu, H.; Preston, Colin; LeMieux, M.; Jaim, H. M. Iftekhar; Hu, L.; Salamanca-Riba, L. G.; Mansour, A.; Zavalij, P. Y.; Rabin, O.

2015-01-01

Researchers seeking to enhance the properties of metals have long pursued incorporating carbon in the metallic host lattice in order to combine the strongly bonded electrons in the metal lattice that yield high ampacity and the free electrons available in carbon nanostructures that give rise to high conductivity. The incorporation of carbon nanostructures into the copper lattice has the potential to improve the current density of copper to meet the ever-increasing demands of nanoelectronic devices. We report on the structure and properties of carbon incorporated in concentrations up to 5 wt. % (∼22 at. %) into the crystal structure of copper. Carbon nanoparticles of 5 nm–200 nm in diameter in an interconnecting carbon matrix are formed within the bulk Cu samples. The carbon does not phase separate after subsequent melting and re-solidification despite the absence of a predicted solid solution at such concentrations in the C-Cu binary phase diagram. This material, so-called, Cu covetic, makes deposition of Cu films containing carbon with similar microstructure to the metal possible. Copper covetic films exhibit greater transparency, higher conductivity, and resistance to oxidation than pure copper films of the same thickness, making them a suitable choice for transparent conductors

Nanocarbon-copper thin film as transparent electrode

Energy Technology Data Exchange (ETDEWEB)

Isaacs, R. A.; Zhu, H.; Preston, Colin; LeMieux, M.; Jaim, H. M. Iftekhar; Hu, L., E-mail: binghu@umd.edu; Salamanca-Riba, L. G., E-mail: riba@umd.edu [Materials Science and Engineering Department, University of Maryland, College Park, Maryland 20742 (United States); Mansour, A. [Carderock Division, Naval Surface Warfare Center, West Bethesda, Maryland 20817 (United States); Zavalij, P. Y. [Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742 (United States); Rabin, O. [Materials Science and Engineering Department, University of Maryland, College Park, Maryland 20742 (United States); Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, Maryland 20742 (United States)

2015-05-11

Researchers seeking to enhance the properties of metals have long pursued incorporating carbon in the metallic host lattice in order to combine the strongly bonded electrons in the metal lattice that yield high ampacity and the free electrons available in carbon nanostructures that give rise to high conductivity. The incorporation of carbon nanostructures into the copper lattice has the potential to improve the current density of copper to meet the ever-increasing demands of nanoelectronic devices. We report on the structure and properties of carbon incorporated in concentrations up to 5 wt. % (∼22 at. %) into the crystal structure of copper. Carbon nanoparticles of 5 nm–200 nm in diameter in an interconnecting carbon matrix are formed within the bulk Cu samples. The carbon does not phase separate after subsequent melting and re-solidification despite the absence of a predicted solid solution at such concentrations in the C-Cu binary phase diagram. This material, so-called, Cu covetic, makes deposition of Cu films containing carbon with similar microstructure to the metal possible. Copper covetic films exhibit greater transparency, higher conductivity, and resistance to oxidation than pure copper films of the same thickness, making them a suitable choice for transparent conductors.

Direct synthesis of RGO/Cu{sub 2}O composite films on Cu foil for supercapacitors

Energy Technology Data Exchange (ETDEWEB)

Dong, Xiangmao; Wang, Kun [Key Laboratory for Ultrafine Materials of the Ministry of Education, Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237 (China); Zhao, Chongjun, E-mail: chongjunzhao@ecust.edu.cn [Key Laboratory for Ultrafine Materials of the Ministry of Education, Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237 (China); Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong 2500 (Australia); Qian, Xiuzhen [Key Laboratory for Ultrafine Materials of the Ministry of Education, Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237 (China); Chen, Shi [School of Information Engineering, Wuhan University of Technology, Wuhan 430070 (China); Li, Zhen, E-mail: zhenl@uow.edu.au [Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong 2500 (Australia); Liu, Huakun; Dou, Shixue [Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong 2500 (Australia)

2014-02-15

Graphical abstract: RGO/Cu{sub 2}O/Cu composites were synthesized by simple hydrothermal treatment of copper foils with graphene oxide, in which the reduction of graphene oxide and the formation of Cu{sub 2}O nanoparticles simultaneously happened in one-pot reaction. These composites can be directly used as electrodes of supercapacitors with the highest specific capacitance of 98.5 F/g at 1 A g{sup −1}, which is much better than that of CuO or Cu{sub 2}O electrodes. -- Highlights: • The RGO/Cu{sub 2}O/Cu composites were obtained by a friendly method in one step. • Improved capacitance performance is realized by the hydrothermal treatment of graphene oxides with Cu foils. • RGO/Cu{sub 2}O/Cu-200 composites exhibit the largest specific capacitance of 98.5 F g{sup −1} at 1 A g{sup −1}. -- Abstract: Reduced graphene oxide/cuprous oxide (RGO/Cu{sub 2}O) composite films were directly synthesized on the surface of copper foil substrates through a straight redox reaction between GO and Cu foil via a hydrothermal approach. Characterization of the resultant composites with X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and field emission scanning electron microscope (FESEM) confirms the formation of Cu{sub 2}O and reduction of GO, in which Cu{sub 2}O nanoparticles were well covered by RGO. The resultant composites (referred to as RGO/Cu{sub 2}O/Cu) were directly used as electrodes for supercapacitors, and their electrochemical performance was assessed by cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectrometry (EIS) in 1 M KOH aqueous solution. A specific capacitance of 98.5 F g{sup −1} at 1 A g{sup −1} was obtained, which is much higher than that of pure Cu{sub 2}O prepared under the same conditions, due to the presence of RGO.

The use of radioisotopic methods to characterize metal foil monolith catalytic converters

International Nuclear Information System (INIS)

Schneider, E.W.; Vaneman, G.L.

1986-01-01

Radioisotopic methods have been applied to nondestructive measurements on experimental automotive catalytic converters. These converters consist of thin corrugated metal foil which supports an alumina coating impregnated with noble metals. A radiogauging system, using gamma radiation from a gadolinium-153 source, was developed to determine the total quantity and distribution of alumina coating applied to the foil substrate. The radiogauging apparatus was also used to provide axial and radial profiles of lead deposited in the catalytic converter when leaded fuel was used. During dynamometer aging, iron-59 was used as a radiotracer in the alumina to monitor the coating attrition as a function of operating time. These studies demonstrate the capability of radiotracer and radiogauging techniques for rapid, nondestructive measurements on prototype catalytic converters during performance testing

Modelling the effects of the radiation reaction force on the interaction of thin foils with ultra-intense laser fields

Science.gov (United States)

Duff, M. J.; Capdessus, R.; Del Sorbo, D.; Ridgers, C. P.; King, M.; McKenna, P.

2018-06-01

The effects of the radiation reaction (RR) force on thin foils undergoing radiation pressure acceleration (RPA) are investigated. Using QED-particle-in-cell simulations, the influence of the RR force on the collective electron dynamics within the target can be examined. The magnitude of the RR force is found to be strongly dependent on the target thickness, leading to effects which can be observed on a macroscopic scale, such as changes to the distribution of the emitted radiation and the target dynamics. This suggests that such parameters may be controlled in experiments at multi-PW laser facilities. In addition, the effects of the RR force are characterized in terms of an average radiation emission angle. We present an analytical model which, for the first time, describes the effect of the RR force on the collective electron dynamics within the ‘light-sail’ regime of RPA. The predictions of this model can be tested in future experiments with ultra-high intensity lasers interacting with solid targets.

A comparison of EDS microanalysis in FIB-prepared and electropolished TEM thin foils

International Nuclear Information System (INIS)

Hutchinson, C.R.; Hackenberg, R.E.; Shiflet, G.J.

2003-01-01

This paper reports the results of a fine-probe EDS microanalytical study of cellular precipitation in a Cu-Ti binary alloy. Compositional profiles across the solute depleted Cu-rich FCC lamellae and the Cu 4 Ti lamellae within isothermally formed cellular colonies were measured in a FEG-TEM from thin-foil specimens prepared by conventional electropolishing and by a technique using a Ga + focused ion-beam (FIB). The Cliff-Lorimer ratio method, with an absorption correction, was employed to quantify the compositions. Two FIB samples were prepared with different orientations of the lamellae with respect to the ion-milling direction. The compositional profiles across the Cu-rich FCC lamellae and the Cu 4 Ti compound lamellae in both the FIB-prepared samples and the electropolished sample were, within experimental error, numerically equivalent. The composition of the Cu 4 Ti compound phase lamellae was very close to the ideal stoichiometric composition of 20 at% Ti. It is concluded that for this system, and for the specimen preparation procedures used in this study, the Ga + ion-milling process has had no detectable effect on the chemistry changes across the interlamellar interface at the scale studied. These results indicate that the possible sources of chemical artifacts which include redeposition, preferential sputtering and ion-induced atomic migration can be minimized if several precautions are taken during milling in the FIB. Consistent with previous investigators, it was also found that the ion-milling process does introduce significant structural artifacts (e.g., dislocations) into the softer FCC Cu-rich phase compared with a specimen produced by conventional electropolishing

Growing Cu2S Thin Films by Exposing a Copper Substrate to Gas-Phase Products of Brown Coal Hydrothermal Desulfurization

Science.gov (United States)

Savitskii, D. P.; Stanishevskii, Ya. M.

2018-01-01

Thin films of copper(I) sulfide (Cu2S) are synthesized on a copper substrate by exposing it to vapor-phase sulfur-containing products resulting from the hydrothermal desulfurization of brown coal. The synthesized 0.1-mm-thick films have grain sizes in the range of 10‒20 μm, electrical resistivity ρ = 0.92 Ω cm at T = 300 K, and bang gap E g = 1.91 eV. The roughness of the films, in terms of the arithmetic mean deviation of the assessed profile, is R a = 2.46 μm.

The feed-out process: Rayleigh-Taylor and Richtmyer-Meshkov instabilities in thin, laser-driven foils

Energy Technology Data Exchange (ETDEWEB)

Smitherman, D.P.

1998-04-01

Eight beams carrying a shaped pulse from the NOVA laser were focused into a hohlraum with a total energy of about 25 kJ. A planar foil was placed on the side of the hohlraum with perturbations facing away from the hohlraum. All perturbations were 4 {micro}m in amplitude and 50 {micro}m in wavelength. Three foils of pure aluminum were shot with thicknesses and pulse lengths respectively of 86 {micro}m and 2. 2 ns, 50 {micro}m and 4.5 ns, and 35 {micro}m with both 2.2 ns and 4. 5 ns pulses. Two composite foils constructed respectively of 32 and 84 {micro}m aluminum on the ablative side and 10 {micro}m beryllium on the cold surface were also shot using the 2.2 ns pulse. X-ray framing cameras recorded perturbation growth using both face- and side-on radiography. The LASNEX code was used to model the experiments. A shock wave interacted with the perturbation on the cold surface generating growth from a Richtmyer-Meshkov instability and a strong acoustic mode. The cold surface perturbation fed-out to the Rayleigh-Taylor unstable ablation surface, both by differential acceleration and interface coupling, where it grew. A density jump did not appear to have a large effect on feed-out from interface coupling. The Rayleigh-Taylor instability`s vortex pairs overtook and reversed the direction of flow of the Richtmyer-Meshkov vortices, resulting in the foil moving from a sinuous to a bubble and spike configuration. The Rayleigh-Taylor instability may have acted as an ablative instability on the hot surface, and as a classical instability on the cold surface, on which grew second and third order harmonics.

Development of CIGS2 thin film solar cells

International Nuclear Information System (INIS)

Dhere, Neelkanth G.; Gade, Vivek S.; Kadam, Ankur A.; Jahagirdar, Anant H.; Kulkarni, Sachin S.; Bet, Sachin M.

2005-01-01

Research and development of CuIn 1-x Ga x Se 2-y S y (CIGSS) thin-film solar cells on ultralightweight flexible metallic foil substrates is being carried out at FSEC PV Materials Lab for space applications. Earlier, the substrate size was limited to 3 cm x 2.5 cm. Large-area sputtering systems and scrubber for hydrogen selenide and sulfide have been designed and constructed for preparation of CIGSS thin-films on large (15 cm x 10 cm) substrates. A selenization/sulfurization furnace donated by Shell (formerly Siemens) Solar has also been refurbished and upgraded. The sputtering target assembly design was modified for proper clamping of targets and effective cooling. A new design of the magnetic assembly for large-area magnetron sputtering sources was implemented so as to achieve uniform deposition on large area. Lightweight stainless steel foil and ultralightweight titanium foil substrates were utilized to increase the specific power of solar cells. Sol-gel derived SiO 2 layers were coated on titanium foil by dip coating method. Deposition parameters for the preparation of molybdenum back contact layers were optimized so as to minimize the residual stress as well as reaction with H 2 S. Presently large (15 cm x 10 cm) CuIn 1-x Ga x S 2 (CIGS2) thin film solar cells are being prepared on Mo-coated titanium and stainless steel foil by sulfurization of CuGa/In metallic precursors in diluted Ar:H 2 S(4%). Heterojunction partner CdS layers are deposited by chemical bath deposition. The regeneration sequence of ZnO/ZnO:Al targets was optimized for obtaining consistently good-quality, transparent and conducting ZnO/ZnO:Al bilayer by RF magnetron-sputter deposition. Excellent facilities at FSEC PV Materials Lab are one of its kinds and could serve as a nucleus of a small pilot plant for CIGSS thin film solar cell fabrication

Metallic copper corrosion rates, moisture content, and growth medium influence survival of copper ion-resistant bacteria

DEFF Research Database (Denmark)

Elguindi, J; Moffitt, S; Hasman, Henrik

2010-01-01

of both copper ion-resistant E. coli and E. faecium strains when samples in rich medium were spread in a thin, moist layer on copper alloys with 85% or greater copper content. E. coli strains were rapidly killed under dry conditions, while E. faecium strains were less affected. Electroplated copper...... on electroplated copper surfaces with benzotriazole coating and thermal oxide coating compared to surfaces without anti-corrosion treatment. Control of surface corrosion affected the level of copper ion influx into bacterial cells, which contributed directly to bacterial killing....

Antimicrobial activities of CuO films deposited on Cu foils by solution chemistry

Energy Technology Data Exchange (ETDEWEB)

Ekthammathat, Nuengruethai [Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Thongtem, Titipun, E-mail: ttpthongtem@yahoo.com [Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Thongtem, Somchai, E-mail: schthongtem@yahoo.com [Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand)

2013-07-15

Monoclinic CuO thin films on Cu foils were successfully synthesized by a simple wet chemical method in alkaline solution with the pH of 13 at room temperature for different lengths of time. The as-synthesized thin films were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and selected area electron diffraction (SAED). Formation mechanism of the phase and morphologies was also discussed according to the experimental results. In this research, assemblies of pure CuO nanospindles with different orientations containing in the thin film synthesized for 2 weeks with 400 nm and 413 nm violet emissions showed better antimicrobial activity against S. aureus than E. coli.

Antimicrobial activities of CuO films deposited on Cu foils by solution chemistry

International Nuclear Information System (INIS)

Ekthammathat, Nuengruethai; Thongtem, Titipun; Thongtem, Somchai

2013-01-01

Monoclinic CuO thin films on Cu foils were successfully synthesized by a simple wet chemical method in alkaline solution with the pH of 13 at room temperature for different lengths of time. The as-synthesized thin films were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and selected area electron diffraction (SAED). Formation mechanism of the phase and morphologies was also discussed according to the experimental results. In this research, assemblies of pure CuO nanospindles with different orientations containing in the thin film synthesized for 2 weeks with 400 nm and 413 nm violet emissions showed better antimicrobial activity against S. aureus than E. coli.

Chromic acid anodizing of aluminum foil

Science.gov (United States)

Dursch, H.

1988-01-01

The success of the Space Station graphite/epoxy truss structure depends on its ability to endure long-term exposure to the LEO environment, primarily the effects of atomic oxygen and the temperture cycling resulting from the 94 minute orbit. This report describes the development and evaluation of chromic acid anodized (CAA) aluminum foil as protective coatings for these composite tubes. Included are: development of solar absorptance and thermal emittance properties required of Al foil and development of CAA parameters to achieve these optical properties; developing techniques to CAA 25 ft lengths of Al foil; developing bonding processes for wrapping the Al foil to graphite/epoxy tubes; and atomic oxygen testing of the CAA Al foil. Two specifications were developed and are included in the report: Chromic Acid Anodizing of Aluminum Foil Process Specification and Bonding of Anodized Aluminum Foil to Graphite/Epoxy Tubes. Results show that CAA Al foil provides and excellent protective and thermal control coating for the Space Station truss structure.

Preparation of Copper Iodide (CuI) Thin Film by In-Situ Spraying and Its Properties

International Nuclear Information System (INIS)

Rahmi, G H; Pratiwi, P; Aimon, A H; Winata, T; Iskandar, F; Nuryadi, B W

2016-01-01

Perovskite based solar cells have attracted interest as low-cost and high-efficiency solar cells due to their great performance, with efficiency up to 20.1%. One type of hole transport material (HTM) used in perovskite based solar cells is copper iodide (CuI) thin film. CuI is inexpensive and has high mobility compared to other HTMs commonly used in perovskite based solar cells. However, diisopropylsulfide solvent, which is used to dissolve CuI in the preparation process, is a malodorous and toxic compound. Therefore, the objective of this research was to develop a synthesis method for CuI thin film with in-situ spraying, a low- cost, safe and easy fabrication method. As precursor solution, CuSO 45 H 2 O was dissolved in ammonia and KI aqueous solution. The precursor solution was then sprayed directly onto a glass substrate with appropriate temperature to form CuI film. The prepared thin films were characterized by X-ray diffractometer, UV-Vis spectrophotometer, scanning electron microscope and four-point probes to study their properties. (paper)

Preparation of selenium coatings onto beryllium foils

International Nuclear Information System (INIS)

Erikson, E.D.; Tassano, P.L.; Reiss, R.H.; Griggs, G.E.

1984-09-01

A technique for preparing selenium films onto 50.8 microns thick beryllium foils is described. The selenium was deposited in vacuum from a resistance heated evaporation source. Profilometry measurements of the coatings indicate deposit thicknesses of 5.5, 12.9, 37.5, 49.8 and 74.5 microns. The control of deposition rate and of coating thickness was facilitated using a commercially available closed-loop programmable thin film controller. The x-ray transmission of the coated substrates was measured using a tritiated zirconium source. The transmissivities of the film/substrate combination are presented for the range of energies from 4 to 20 keV. 15 references, 3 figures

A simple method for determining the activity of large-area beta sources constructed from anodized aluminum foils

International Nuclear Information System (INIS)

Stanga, D.

2014-01-01

A simple method has been developed for determining the activity of large-area beta reference sources in anodized aluminum foils. It is based on the modeling of the transmission of beta rays through thin foils in planar geometry using Monte Carlo simulation. The method was checked experimentally and measurement results show that the activity of large-area beta reference sources in anodized aluminum foils can be measured with standard uncertainties smaller than the limit of 10% required by ISO 8769. - Highlights: • A method for determining the activity of large-area beta sources is presented. • The method is based on a model of electron transport in planar geometry. • The method makes use of linear programming for determining the activity. • The uncertainty of the method is smaller than 10%

Phase and Texture of Solution-Processed Copper Phthalocyanine Thin Films Investigated by Two-Dimensional Grazing Incidence X-Ray Diffraction

Directory of Open Access Journals (Sweden)

Lulu Deng

2011-07-01

Full Text Available The phase and texture of a newly developed solution-processed copper phthalocyanine (CuPc thin film have been investigated by two-dimensional grazing incidence X-ray diffraction. The results show that it has β phase crystalline structure, with crystallinity greater than 80%. The average size of the crystallites is found to be about 24 nm. There are two different arrangements of crystallites, with one dominating the diffraction pattern. Both of them have preferred orientation along the thin film normal. Based on the similarities to the vacuum deposited CuPc thin films, the new solution processing method is verified to offer a good alternative to vacuum process, for the fabrication of low cost small molecule based organic photovoltaics.

Deposition techniques for the preparation of thin film nuclear targets

International Nuclear Information System (INIS)

Muggleton, A.H.F.

1987-07-01

This review commences with a brief description of the basic principles that regulate vacuum evaporation and the physical processes involved in thin film formation, followed by a description of the experimental methods used. The principle methods of heating the evaporant are detailed and the means of measuring and controlling the film thickness are elucidated. Types of thin film nuclear targets are considered and various film release agents are listed. Thin film nuclear target behaviour under ion-bombardment is described and the dependence of nuclear experimental results upon target thickness and uniformity is outlined. Special problems associated with preparing suitable targets for lifetime measurements are discussed. The causes of stripper-foil thickening and breaking under heavy-ion bombardment are considered. A comparison is made between foils manufactured by a glow discharge process and those produced by vacuum sublimation. Consideration is given to the methods of carbon stripper-foil manufacture and to the characteristics of stripper-foil lifetimes are considered. Techniques are described that have been developed for the fabrication of special targets, both from natural and isotopically enriched material, and also of elements that are either chemically unstable, or thermally unstable under irradiation. The reduction of metal oxides by the use of hydrogen or by utilising a metallothermic technique, and the simultaneous evaporation of reduced rare earth elements is described. A comprehensive list of the common targets is presented

THIN DIAMOND FILMS FOR SNS H INJECTIONS STRIPPING

International Nuclear Information System (INIS)

SHAW, R.W.; HERR, A.D.; FEIGERLE, C.S.; CUTLER, R.J.; LIAW, C.J.; LEE, Y.Y.

2004-01-01

We have investigated the preparation and testing of thin diamond foils for use in stripping the SNS H - Linac beam. A long useful lifetime for these foils is desirable to improve operational efficiency. Preliminary data presented at PAC 2001 indicated that diamond foils were superior to conventional evaporated carbon foils, exhibiting lifetimes approximately five-fold longer [1]. That work employed a fully supported diamond foil, a format that is not acceptable for the SNS application; at least two edges of the approximately 1 x 1 cm foils must be free standing to allow for beam rastering. Residual stress in a chemical vapor deposited (CVD) diamond foil results in film distortion (scrolling) when the film is released from its silicon growth substrate. We have attacked this problem by initially patterning the surface of CVD growth substrates with a 50 or 100 line/inch trapezoidal grating, followed by conformal diamond film growth on the patterned substrate. Then removal of the substrate by chemical etching produced a foil that possessed improved mechanical integrity due to its corrugation. The high nucleation density required to grow continuous, pinhole free diamond foils of the desired thickness (1 (micro)m, 350 (micro)g/cm 2 ) was achieved by a combination of substrate surface scratching and seeding. A variety of diamond foils have been tested using the BNL 750 keV Radio Frequency Quadrupole H - beam to simulate energy loss in the SNS. Those include flat, corrugated, microcrystalline, and nanocrystalline foils. Foil lifetimes are reported

Measurements of Wake-Riding Electrons in Antiproton-Carbon-Foil Collisions

CERN Multimedia

2002-01-01

When a charged particle passes through dielectric media, e.g. a thin carbon foil, a ``wake'' is induced. The characteristic wake-potential shows an oscillatory behaviour, with a wavelength of about $ 2 \\pi v _{p} / \\omega _{p} _{l} $ where $ v _{p} $ is the projectile velocity and $ \\omega _{p} _{l} $ the plasmon energy of the target. This induced wake potential is superimposed on the Coulomb potential of the projectile, the latter leading to a pronounced ``cusp'' of electrons leaving the solid at $ v _{e} app v _{p} $ for positively charged projectiles in the MeV region. Correspondingly, an ``anti-cusp'' is expected for antiprotons. \\\\ \\\\ In the solid, the wake-potential leads to an attractive force on electrons, and a dynamic electronic state is predicted both for proton and antiproton projectiles. In the solid, the wake-riding electrons are travelling with the projectile speed $ v _{p} $ Upon exit of the foil, the electron released from the wake-riding state of an antiproton will suddenly find itself in th...

Study of the crystallographic phase change on copper (I) selenide thin films prepared through chemical bath deposition by varying the pH of the solution

Energy Technology Data Exchange (ETDEWEB)

Sandoval-Paz, M.G., E-mail: myrnasandoval@udec.cl [Departament of Physics, Faculty of Physical Sciences and Mathematics, University of Concepcion, Box 160-C, Concepción (Chile); Rodríguez, C.A. [Department of Materials Engineering, Faculty of Engineering, University of Concepción, Edmundo Larenas 270, Concepción 4070409 (Chile); Porcile-Saavedra, P.F. [Departament of Physics, Faculty of Physical Sciences and Mathematics, University of Concepcion, Box 160-C, Concepción (Chile); Trejo-Cruz, C. [Department of Physics, Faculty of Science, University of Biobío, Avenue Collao 1202, Box 5C, Concepción 4051381 (Chile)

2016-07-15

Copper (I) selenide thin films with orthorhombic and cubic structure were deposited on glass substrates by using the chemical bath deposition technique. The effects of the solution pH on the films growth and subsequently the structural, optical and electrical properties of the films were studied. Films with orthorhombic structure were obtained from baths wherein both metal complex and hydroxide coexist; while films with cubic structure were obtained from baths where the metal hydroxide there is no present. The structural modifications are accompanied by changes in bandgap energy, morphology and electrical resistivity of the films. - Graphical abstract: “Study of the crystallographic phase change on copper (I) selenide thin films prepared through chemical bath deposition by varying the pH of the solution” by M. G. Sandoval-Paz, C. A. Rodríguez, P. F. Porcile-Saavedra, C. Trejo-Cruz. Display Omitted - Highlights: • Copper (I) selenide thin films were obtained by chemical bath deposition. • Orthorhombic to cubic phase change was induced by varying the reaction solution pH. • Orthorhombic phase is obtained mainly from a hydroxides cluster mechanism. • Cubic phase is obtained mainly from an ion by ion mechanism. • Structural, optical and electrical properties are presented as a function of pH.

Study of the structure and electrical properties of the copper nitride thin films deposited by pulsed laser deposition

International Nuclear Information System (INIS)

Gallardo-Vega, C.; Cruz, W. de la

2006-01-01

Copper nitride thin films were prepared on glass and silicon substrates by ablating a copper target at different pressure of nitrogen. The films were characterized in situ by X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) and ex situ by X-ray diffraction (XRD). The nitrogen content in the samples, x = [N]/[Cu], changed between 0 and 0.33 for a corresponding variation in nitrogen pressure of 9 x 10 -2 to 1.3 x 10 -1 Torr. Using this methodology, it is possible to achieve sub-, over- and stoichiometric films by controlling the nitrogen pressure. The XPS results show that is possible to obtain copper nitride with x = 0.33 (Cu 3 N) and x = 0.25 (Cu 4 N) when the nitrogen pressure is 1.3 x 10 -1 and 5 x 10 -2 Torr, respectively. The lattice constants obtained from XRD results for copper nitride with x = 0.25 is of 3.850 A and with x = 0.33 have values between 3.810 and 3.830 A. The electrical properties of the films were studied as a function of the lattice constant. These results show that the electrical resistivity increases when the lattice parameter is decreasing. The electrical resistivity of copper nitride with x = 0.25 was smaller than samples with x = 0.33

Study of the structure and electrical properties of the copper nitride thin films deposited by pulsed laser deposition

Energy Technology Data Exchange (ETDEWEB)

Gallardo-Vega, C. [Centro de Investigacion Cientifica y de Educacion Superior de Ensenada (CICESE), Km. 107 Carretera Tijuana-Ensenada, A. Postal 2732, 22860, Ensenada B.C. (Mexico)]. E-mail: gallardo@ccmc.unam.mx; Cruz, W. de la [Centro de Ciencias de la Materia Condensada, UNAM, Km. 107 Carretera Tijuana-Ensenada, A. Postal 2681, 22860, Ensenada B.C. (Mexico)

2006-09-15

Copper nitride thin films were prepared on glass and silicon substrates by ablating a copper target at different pressure of nitrogen. The films were characterized in situ by X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES) and ex situ by X-ray diffraction (XRD). The nitrogen content in the samples, x = [N]/[Cu], changed between 0 and 0.33 for a corresponding variation in nitrogen pressure of 9 x 10{sup -2} to 1.3 x 10{sup -1} Torr. Using this methodology, it is possible to achieve sub-, over- and stoichiometric films by controlling the nitrogen pressure. The XPS results show that is possible to obtain copper nitride with x = 0.33 (Cu{sub 3}N) and x = 0.25 (Cu{sub 4}N) when the nitrogen pressure is 1.3 x 10{sup -1} and 5 x 10{sup -2} Torr, respectively. The lattice constants obtained from XRD results for copper nitride with x = 0.25 is of 3.850 A and with x = 0.33 have values between 3.810 and 3.830 A. The electrical properties of the films were studied as a function of the lattice constant. These results show that the electrical resistivity increases when the lattice parameter is decreasing. The electrical resistivity of copper nitride with x = 0.25 was smaller than samples with x = 0.33.

QED effects induced harmonics generation in extreme intense laser foil interaction

Science.gov (United States)

Yu, J. Y.; Yuan, T.; Liu, W. Y.; Chen, M.; Luo, W.; Weng, S. M.; Sheng, Z. M.

2018-04-01

A new mechanism of harmonics generation (HG) induced by quantum electrodynamics (QED) effects in extreme intense laser foil interaction is found and investigated by particle-in-cell (PIC) simulations. When two laser pulses with identical intensities of 1.6× {10}24 {{W}} {{{cm}}}-2 are counter-incident on a thin foil target, harmonics emission is observed in their reflected electromagnetic waves. Such harmonics radiation is excited due to transversely oscillating electric currents coming from the vibration of QED effect generated {e}-{e}+ pairs. The effects of laser intensity and polarization were studied. By distinguishing the cascade depth of generated photons and pairs, the influence of QED cascades on HG was analyzed. Although the current HG is not an efficient way for radiation source applications, it may provide a unique way to detect the QED processes in the near future ultra-relativistic laser solid interactions.

Experimental thin-target and thick-target yields for natOs(α, xn)Pt, natOs(α, X)Os, Ir and natMo(p, xn)Tc nuclear reactions from threshold up to 38 and 45 MeV, by combined single and stacked foil techniques

International Nuclear Information System (INIS)

Birattari, Claudio; Bonardi, Mauro; Gini, Luigi; Groppi, Flavia; Menapace, Enzo

2002-01-01

The experimental values of thin-target excitation functions for the nuclear reactions: nat Os(α, X) 188,189,191 Pt, 192g,194m Ir in the energy range 11 - 38 MeV and nat Mo(p, xn) 94g,95g,95m,96(m+g) Tc in the energy range 5 - 44 MeV are presented. The experimental values were obtained by cyclotron activation followed by off-line HPGe γ-spectrometry and corrected at the End Of an Instantaneous Bombardment, EOIB. In different cases use was made of single foil and stacked foil techniques, which present significantly different advantages and disadvantages. The thin-target yield values can be easily either numerically or analytically integrated, as a function of both incoming particle energy and energy loss in target itself, in order to calculate apriori the thick-target yield of various radionuclides under any different experimental condition. Moreover, the thin-target yields are directly related to the effective cross-sections of various nuclear reaction channels involved. The data are of relevant interest for optimizing cyclotron production of platinum and technetium radionuclides to be used as radiotracers for metallo-biochemical, biomedical, toxicological and environmental studies. (author)

System requirements for the Los Alamos foil-implosion project

International Nuclear Information System (INIS)

Brownell, J.; Bowers, R.; Greene, A.; Lindemuth, I.; Nickel, G.; Oliphant, T.; Weiss, D.

1983-01-01

The goal of the Los Alamos imploding foil project is the development of an intense source of soft x rays and hot plasma produced from the thermalization of 1 to 10 MJ of plasma kinetic energy. The source will be used for material studies and fusion experiments. Specifically, thin, current-carrying cylindrical metallic plasmas are imploded via their self-magnetic forces. Features of this project are the use of high-explosive-driven flux-compression generators as the prime power source to achieve very high energies and fast opening switches to shorten the electrical pulses. To reach a load kinetic energy of 10 MJ, it is expected that the foil-plasma must carry about 50 MA of current and must implode in less than 1/2 μsec. This imposes the requirements that switch opening times must be less than 1/2 μsec and the transmission line must withstand voltages of about 1 MV. The system being pursued at Los Alamos is described, and model calculations are presented

The Anomalous Currents In The Front Foils of the JET Lost Alpha Diagnostic KA-2

International Nuclear Information System (INIS)

Cecil, F.E.; Kiptily, V.; Salmi, A.; Horton, A.; Fullard, K.; Murari, A.; Darrow, D.; Hill, K.

2011-01-01

We have examined the observed currents in the front foils of the JET Faraday cup lost alpha particle diagnostic KA-2. In particular, we have sought to understand the currents during Ohmic plasmas for which the ion flux at the detectors was initially assumed to be negligible. We have considered two sources of this current: plasma ions (both deuterium and impurity) in the vicinity of the detector (including charge exchange neutrals) and photoemission from scattered UV radiation. Based upon modeling and empirical observation, the latter source appears most likely and, moreover, seems to be applicable to the currents in the front foil during ELMy H-mode plasmas. A very thin gold or nickel foil attached to the present detector aperture is proposed as a solution to this problem, and realistic calculations of expected fluxes of lost energetic neutral beam ions during TF ripple experiments are presented as justification of this proposed solution.

The Anomalous Currents In The Front Foils of the JET Lost Alpha Diagnostic KA-2

Energy Technology Data Exchange (ETDEWEB)

Cecil, F. E.; Kiptily, V.; Salmi, A.; Horton, A.; Fullard, K.; Murari, A.; Darrow, D.; Hill, K.

2011-05-04

We have examined the observed currents in the front foils of the JET Faraday cup lost alpha particle diagnostic KA-2. In particular, we have sought to understand the currents during Ohmic plasmas for which the ion flux at the detectors was initially assumed to be negligible. We have considered two sources of this current: plasma ions both deuterium and impurity in the vicinity of the detector including charge exchange neutrals and photoemission from scattered UV radiation. Based upon modeling and empirical observation, the latter source appears most likely and, moreover, seems to be applicable to the currents in the front foil during ELMy H-mode plasmas. A very thin gold or nickel foil attached to the present detector aperture is proposed as a solution to this problem, and realistic calculations of expected fluxes of lost energetic neutral beam ions during TF ripple experiments are presented as justification of this proposed solution.

Spallation Neutron Source SNS Diamond Stripper Foil Development

International Nuclear Information System (INIS)

Shaw, Robert W.; Plum, Michael A.; Wilson, Leslie L.; Feigerle, Charles S.; Borden, Michael J.; Irie, Y.; Sugai, I.; Takagi, A.

2007-01-01

Diamond stripping foils are under development for the SNS. Freestanding, flat 300 to 500 (micro)g/cm 2 foils as large as 17 x 25 mm 2 have been prepared. These nano-textured polycrystalline foils are grown by microwave plasma-assisted chemical vapor deposition in a corrugated format to maintain their flatness. They are mechanically supported on a single edge by a residual portion of their silicon growth substrate; fine foil supporting wires are not required for diamond foils. Six foils were mounted on the SNS foil changer in early 2006 and have performed well in commissioning experiments at reduced operating power. A diamond foil was used during a recent experiment where 15 (micro)C of protons, approximately 64% of the design value, were stored in the ring. A few diamond foils have been tested at LANSCE/PSR, where one foil was in service for a period of five months (820 C of integrated injected charge) before it was replaced. Diamond foils have also been tested in Japan at KEK (640 keV H - ) where their lifetimes slightly surpassed those of evaporated carbon foils, but fell short of those for Sugai's new hybrid boron carbon (HBC) foils.

The strength limits of ultra-thin copper films

Energy Technology Data Exchange (ETDEWEB)

Wiederhirn, Guillaume

2007-07-02

Elucidating size effects in ultra-thin films is essential to ensure the performance and reliability of MEMS and electronic devices. In this dissertation, the influence of a capping layer on the mechanical behavior of copper (Cu) films was analyzed. Passivation is expected to shut down surface diffusion and thus to alter the contributions of dislocation- and diffusion-based plasticity in thin films. Experiments were carried out on 25 nm to 2 {mu}m thick Cu films magnetron-sputtered onto amorphous-silicon nitride coated silicon (111) substrates. These films were capped with 10 nm of aluminum oxide or silicon nitride passivation without breaking vacuum either directly after Cu deposition or after a 500 C anneal. The evolution of thermal stresses in these films was investigated mainly by the substrate curvature method between -160 C and 500 C. Negligible differences were detected for the silicon nitride vs. the aluminum oxide passivated Cu films. The processing parameters associated with the passivation deposition also had no noticeable effect on the stress-temperature behavior of the Cu. However, the thermomechanical behavior of passivated Cu films strongly depended on the Cu film thickness. For films in the micrometer range, the influence of the passivation layer was not significant, which suggests that the Cu deformed mainly by dislocation plasticity. However, diffusional creep plays an increasing role with decreasing film thickness since it becomes increasingly difficult to nucleate dislocations in smaller grains. Size effects were investigated by plotting the stress at room temperature after thermal cycling as a function of the inverse film thickness. Between 2 {mu}m and 200 nm, the room temperature stress was inversely proportional to the film thickness. The passivation exerted a strong effect on Cu films thinner than 100 nm by effectively shutting down surface diffusion mechanisms. Since dislocation processes were also shut off in these ultra-thin films, they

Correction of a Space Telescope Active Primary Mirror Using Adaptive Optics in a Woofer-Tweeter Configuration

Science.gov (United States)

2015-09-01

zirconium and zirconium/copper to form the laminate foil [21]. The substrate bonds directly to the foil while attached to the mandrel. Figure 5...fabrication process uses a negative shape polished mandrel to form the mirror surface. The manufacturer layers CFRP prepreg over the mandrel and after...thin shell made from CFRP. The reflective 17 layer is a nano- laminate bonded to the front of the CFRP substrate. An active layer is bonded to the

Study on lifetime of C stripping foils

International Nuclear Information System (INIS)

Zhang Hongbin; Lu Ziwei; Zhao Yongtao; Li Zhankui; Xu Hushan; Xiao Guoqing; Wang Yuyu; Zhang Ling; Li Longcai; Fang Yan

2007-01-01

The carbon stripping foils can be prepared with the AC and DC arc discharge methods, or even sandwiched with AC-DC alternative layers. The lifetime of the carbon stripping foils of 19 μg/cm 2 prepared with different methods and/or structures was measured. The factors affecting the bombarding lifetime of the carbon stripping foils, especially the method of the foil preparation and the structure of the carbon stripping foils, were discussed. It is observed that the foils prepared with the DC arc discharge method have a longer bombarding lifetime than those prepared with the AC arc discharge method. (authors)

Surface Functionalization of Thin-Film Composite Membranes with Copper Nanoparticles for Antimicrobial Surface Properties

KAUST Repository

Ben-Sasson, Moshe

2014-01-07

Biofouling is a major operational challenge in reverse osmosis (RO) desalination, motivating a search for improved biofouling control strategies. Copper, long known for its antibacterial activity and relatively low cost, is an attractive potential biocidal agent. In this paper, we present a method for loading copper nanoparticles (Cu-NPs) on the surface of a thin-film composite (TFC) polyamide RO membrane. Cu-NPs were synthesized using polyethyleneimine (PEI) as a capping agent, resulting in particles with an average radius of 34 nm and a copper content between 39 and 49 wt.%. The positive charge of the Cu-NPs imparted by the PEI allowed a simple electrostatic functionalization of the negatively charged RO membrane. We confirmed functionalization and irreversible binding of the Cu-NPs to the membrane surface with SEM and XPS after exposing the membrane to bath sonication. We also demonstrated that Cu-NP functionalization can be repeated after the Cu-NPs dissolve from the membrane surface. The Cu-NP functionalization had minimal impact on the intrinsic membrane transport parameters. Surface hydrophilicity and surface roughness were also maintained, and the membrane surface charge became positive after functionalization. The functionalized membrane exhibited significant antibacterial activity, leading to an 80-95% reduction in the number of attached live bacteria for three different model bacterial strains. Challenges associated with this functionalization method and its implementation in RO desalination are discussed. © 2013 American Chemical Society.

Interfacial Microstructure and Its Influence on Resistivity of Thin Layers Copper Cladding Steel Wires

Science.gov (United States)

Li, Hongjuan; Ding, Zhimin; Zhao, Ruirong

2018-04-01

The interfacial microstructure and resistivity of cold-drawn and annealed thin layers copper cladding steel (CCS) wires have been systematically investigated by the methods of scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and resistivity testing. The results showed that the Cu and Fe atoms near interface diffused into each other matrixes. The Fe atoms diffused into Cu matrixes and formed a solid solution. The mechanism of solid solution is of substitution type. When the quantity of Fe atoms exceeds the maximum solubility, the supersaturated solid solution would form Fe clusters and decompose into base Cu and α-Fe precipitated phases under certain conditions. A few of α-Fe precipitates was observed in the copper near Cu/Fe interfaces of cold-drawn CCS wires, with 1-5 nm in size. A number of α-Fe precipitates of 1-20 nm in size can be detected in copper near Cu/Fe interfaces of CCS wires annealed at 850°C. When annealing temperature was less than 750°C, the resistivity of CCS wires annealed was lower than that of cold-drawn CCS wires. However, when annealing temperature was above 750°C, the resistivity of CCS wires was greater than that of cold-drawn CCS wires and increased with rising the annealing temperature. The relationship between nanoscale α-Fe precipitation and resistivity of CCS wires has been well discussed.

Surface Functionalization of Thin-Film Composite Membranes with Copper Nanoparticles for Antimicrobial Surface Properties

KAUST Repository

Ben-Sasson, Moshe; Zodrow, Katherine R.; Genggeng, Qi; Kang, Yan; Giannelis, Emmanuel P.; Elimelech, Menachem

2014-01-01

Biofouling is a major operational challenge in reverse osmosis (RO) desalination, motivating a search for improved biofouling control strategies. Copper, long known for its antibacterial activity and relatively low cost, is an attractive potential biocidal agent. In this paper, we present a method for loading copper nanoparticles (Cu-NPs) on the surface of a thin-film composite (TFC) polyamide RO membrane. Cu-NPs were synthesized using polyethyleneimine (PEI) as a capping agent, resulting in particles with an average radius of 34 nm and a copper content between 39 and 49 wt.%. The positive charge of the Cu-NPs imparted by the PEI allowed a simple electrostatic functionalization of the negatively charged RO membrane. We confirmed functionalization and irreversible binding of the Cu-NPs to the membrane surface with SEM and XPS after exposing the membrane to bath sonication. We also demonstrated that Cu-NP functionalization can be repeated after the Cu-NPs dissolve from the membrane surface. The Cu-NP functionalization had minimal impact on the intrinsic membrane transport parameters. Surface hydrophilicity and surface roughness were also maintained, and the membrane surface charge became positive after functionalization. The functionalized membrane exhibited significant antibacterial activity, leading to an 80-95% reduction in the number of attached live bacteria for three different model bacterial strains. Challenges associated with this functionalization method and its implementation in RO desalination are discussed. © 2013 American Chemical Society.

Computational modeling of plasma-flow switched foil implosions

International Nuclear Information System (INIS)

Lindemuth, I.R.

1985-01-01

A ''plasma-flow'', or ''commutator'', switch has been proposed as a means of achieving high dI/dt in a radially imploding metallic foil plasma. In this concept, an axially moving foil provides the initial coaxial gun discharge path for the prime power source and provides and ''integral'' inductive storage of magnetic energy. As the axially moving foil reaches the end of the coaxial gun, a radially imploding load foil is switched into the circuit. The authors have begun two-dimensional computer modeling of the two-foil implosion system. They use a magnetohydrodynamic (MHD) model which includes tabulated state and transport properties of the metallic foil material. Moving numerical grids are used to achieve adequate resolution of the moving foils. A variety of radiation models are used to compute the radiation generated when the imploding load foil converges on axis. These computations are attempting to examine the interaction of the switching foil with the load foil. In particular, they examine the relationship between foil placement and implosion quality

Evolution of sausage and helical modes in magnetized thin-foil cylindrical liners driven by a Z-pinch

Science.gov (United States)

Yager-Elorriaga, D. A.; Lau, Y. Y.; Zhang, P.; Campbell, P. C.; Steiner, A. M.; Jordan, N. M.; McBride, R. D.; Gilgenbach, R. M.

2018-05-01

In this paper, we present experimental results on axially magnetized (Bz = 0.5 - 2.0 T), thin-foil (400 nm-thick) cylindrical liner-plasmas driven with ˜600 kA by the Michigan Accelerator for Inductive Z-Pinch Experiments, which is a linear transformer driver at the University of Michigan. We show that: (1) the applied axial magnetic field, irrespective of its direction (e.g., parallel or anti-parallel to the flow of current), reduces the instability amplitude for pure magnetohydrodynamic (MHD) modes [defined as modes devoid of the acceleration-driven magneto-Rayleigh-Taylor (MRT) instability]; (2) axially magnetized, imploding liners (where MHD modes couple to MRT) generate m = 1 or m = 2 helical modes that persist from the implosion to the subsequent explosion stage; (3) the merging of instability structures is a mechanism that enables the appearance of an exponential instability growth rate for a longer than expected time-period; and (4) an inverse cascade in both the axial and azimuthal wavenumbers, k and m, may be responsible for the final m = 2 helical structure observed in our experiments. These experiments are particularly relevant to the magnetized liner inertial fusion program pursued at Sandia National Laboratories, where helical instabilities have been observed.

Lifetimes of carbon foils deposited on etched substrates

International Nuclear Information System (INIS)

Stoner, J.O. Jr.; Bashkin, S.; Hartog, P.D.; Thomas, G.; Yntema, J.L.

1981-01-01

The methods currently in use for producing long-lived carbon foils are listed. The possible common factors which are important in making long lasting foils are a) making a strong, coherent, continuous layer, b) making a foil slack, loose, or baggy, and c) making a foil whose molecular structure minimizes shrinkage. The behavior of foils deposited on etched substrates is compared with foils deposited upon conventional microscope slides

Influence of sulfurization temperature on Cu2ZnSnS4 absorber layer on flexible titanium substrates for thin film solar cells

Science.gov (United States)

Gokcen Buldu, Dilara; Cantas, Ayten; Turkoglu, Fulya; Gulsah Akca, Fatime; Meric, Ece; Ozdemir, Mehtap; Tarhan, Enver; Ozyuzer, Lutfi; Aygun, Gulnur

2018-02-01

In this study, the effect of sulfurization temperature on the morphology, composition and structure of Cu2ZnSnS4 (CZTS) thin films grown on titanium (Ti) substrates has been investigated. Since Ti foils are flexible, they were preferred as a substrate. As a result of their flexibility, they allow large area manufacturing and roll-to-roll processes. To understand the effects of sulfurization temperature on the CZTS formation on Ti foils, CZTS films fabricated with various sulfurization temperatures were investigated with several analyses including x-ray diffraction (XRD), scanning electron microscopy (SEM), x-ray photoelectron spectroscopy and Raman scattering. XRD measurements showed a sharp and intense peak coming from the (112) planes of the kesterite type lattice structure (KS), which is strong evidence for good crystallinity. The surface morphologies of our thin films were investigated using SEM. Electron dispersive spectroscopy was also used for the compositional analysis of the thin films. According to these analysis, it is observed that Ti foils were suitable as substrates for the growth of CZTS thin films with desired properties and the sulfurization temperature plays a crucial role for producing good quality CZTS thin films on Ti foil substrates.

Application of HTSC-thin films in microwave bandpass filters

International Nuclear Information System (INIS)

Jha, A.R.

1993-01-01

This paper reveals unique performance capabilities of High-Temperature Superconducting Thin-Film (HTSCTFs) for possible applications in microwave bandpass filters (BPFs). Microwave filters fabricated with HTSCTFs have demonstrated lowest insertion loss, highest rejection, and sharpest skirt selectivity. Thin films of Yttrium Barium Copper Oxide (YBCO), Bismuth Strontium Calcium Copper Oxide (BSCCO) and Thallium Calcium Barium Copper Oxide (TCBCO) will be most attractive for filters

Differential reflectometry of thin film metal oxides on copper, tungsten, molybdenum and chromium

International Nuclear Information System (INIS)

Urban, F.K. III; Hummel, R.E.; Verink, E.D. Jr.

1982-01-01

A differential reflectometry study was undertaken to investigate the characteristics of thin oxide films on metal substrates. The oxides were produced by heating pure metals of copper, tungsten, molybdenum and chromium in dry oxygen. A new 'halfpolishing' technique was applied to obtain specimens with a step in oxide thickness in order to make them suitable for differential reflectometry. It was found that oxides formed this way yielded the same differential reflectograms as by electrochemical oxidation. A mathematical model involving the interaction of light with a thin corrosion product on metal substrates was applied to generate computer calculated differential reflectograms utilizing various optical constants and thicknesses of the assumed film. Three different thickness ranges have been identified. (a) For large film thicknesses, the differential reflectograms are distinguished by a sequence of interference peaks. (b) If the product of thickness and refraction index of the films is smaller than about 40 nm, no interference peaks are present. Any experimentally observed peaks in differential reflectograms of these films are caused entirely by electron interband transitions. (c) In an intermediate thickness range, superposition of interference and interband peaks are observed. (author)

Copper substrate as a catalyst for the oxidation of chemical vapor deposition-grown graphene

International Nuclear Information System (INIS)

Li, Zhiting; Zhou, Feng; Parobek, David; Shenoy, Ganesh J.; Muldoon, Patrick; Liu, Haitao

2015-01-01

We report the catalytic effect of copper substrate on graphene–oxygen reaction at high temperature. Previous studies showed that graphene grown on copper are mostly defect-free with strong oxidation resistance. We found that a freshly prepared copper-supported graphene sample can be completely oxidized in trace amount of oxygen (<3 ppm) at 600 °C within 2 h. Both X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES) suggest that upon ambient air exposure, oxygen molecules diffuse into the space between graphene and copper, resulting in the formation of copper oxide which acts as catalytic sites for the graphene-oxygen reaction. This result has important implications for the characterization, processing, and storage of copper-supported graphene samples. - Graphical abstract: The copper substrate enhances the thermel oxidation of single-layer graphene. - Highlights: • A copper-supported graphene can be oxidized in Ar (O 2 <3 ppm, 600 °C, 2 h). • O 2 intercalates between graphene and copper upon exposure to air. • The copper foil should not be considered as an inert substrate

Enhancement of absorption in vertically-oriented graphene sheets growing on a thin copper layer

Energy Technology Data Exchange (ETDEWEB)

Rozouvan, Tamara; Poperenko, Leonid [Taras Shevchenko National University of Kyiv, Department of Physics 4, Prospect Glushkova, Kyiv, 03187 (Ukraine); Kravets, Vasyl, E-mail: vasyl_kravets@yahoo.com [School of Physics and Astronomy, University of Manchester, Manchester, M13 9PL (United Kingdom); Shaykevich, Igor [Taras Shevchenko National University of Kyiv, Department of Physics 4, Prospect Glushkova, Kyiv, 03187 (Ukraine)

2017-02-28

Highlights: • The optical properties and surface structure of graphene films. • Chemical vapour deposition method. • Scanning tunneling microscopy revealed vertical crystal lattice structure of graphene layer. • We report a significant enhancement of the absorption band in the vertically-oriented graphene sheets. - Abstract: The optical properties and surface structure of graphene films grown on thin copper Cu (1 μm) layer using chemical vapour deposition method were investigated via spectroscopic ellipsometry and nanoscopic measurements. Angle variable ellipsometry measurements were performed to analyze the features of dispersion of the complex refractive index and optical conductivity. It was observed significant enhancement of the absorption band in the vertically-oriented graphene sheets layer with respect to the bulk graphite due to interaction between excited localized surface plasmon at surface of thin Cu layer and graphene’s electrons. Scanning tunneling microscopy measurements with atomic spatial resolution revealed vertical crystal lattice structure of the deposited graphene layer. The obtained results provide direct evidence of the strong influence of the growing condition and morphology of nanostructure on electronic and optical behaviours of graphene film.

Load regulating expansion fixture

International Nuclear Information System (INIS)

Wagner, L.M.; Strum, M.J.

1998-01-01

A free standing self contained device for bonding ultra thin metallic films, such as 0.001 inch beryllium foils is disclosed. The device will regulate to a predetermined load for solid state bonding when heated to a bonding temperature. The device includes a load regulating feature, whereby the expansion stresses generated for bonding are regulated and self adjusting. The load regulator comprises a pair of friction isolators with a plurality of annealed copper members located there between. The device, with the load regulator, will adjust to and maintain a stress level needed to successfully and economically complete a leak tight bond without damaging thin foils or other delicate components. 1 fig

Copper corrosion experiments under anoxic conditions

Energy Technology Data Exchange (ETDEWEB)

Ollila, Kaija [VTT Technical Research Centre of Finland, Espoo (Finland)

2013-06-15

This report gives results from the corrosion experiments with copper under anoxic conditions. The objective was to study whether hydrogen-evolving corrosion reaction could occur. Copper foil samples were exposed in deaerated deionized water in Erlenmeyer flasks in the glove box with inert atmosphere. Four corrosion experiments (Cu1, Cu2, Cu3 and Cu4) were started, as well as a reference test standing in air. Cu1 and Cu2 had gas tight seals, whereas Cu3 and Cu4 had palladium foils as hydrogen permeable enclosure. The test vessels were stored during the experiments in a closed stainless steel vessel to protect them from the trace oxygen of the gas atmosphere and light. After the reaction time of three and a half years, there were no visible changes in the copper surfaces in any of the tests in the glove box, in contrast the Cu surfaces looked shiny and unaltered. The Cu3 test was terminated after the reaction time of 746 days. The analysis of the Pd-membrane showed the presence of H2 in the test system. If the measured amount of 7.2{center_dot}10{sup 5} mol H{sub 2} was the result of formation of Cu{sub 2}O this would correspond to a 200 nm thick corrosion layer. This was not in agreement with the measured layer thickness with SIMS, which was 6{+-}1 nm. A clear weight loss observed for the Cu3 test vessel throughout the test period suggests the evaporation of water through the epoxy sealing to the closed steel vessel. If this occurred, the anaerobic corrosion of steel surface in humid oxygen-free atmosphere could be a source of hydrogen. A similar weight loss was not observed for the parallel test (Cu4). The reference test standing in air showed visible development of corrosion products.

Zinc-oxide nanorod / copper-oxide thin-film heterojunction for a nitrogen-monoxide gas sensor

International Nuclear Information System (INIS)

Yoo, Hwansu; Kim, Hyojin; Kim, Dojin

2014-01-01

A novel p - n oxide heterojunction structure was fabricated by employing n-type zinc-oxide (ZnO) nanorods grown on an indium-tin-oxide-coated glass substrate by using the hydrothermal method and a p-type copper-oxide (CuO) thin film deposited onto the ZnO nanorod array by using the sputtering method. The crystallinities and microstructures of the heterojunction materials were examined by using X-ray diffraction and scanning electron microscopy. The observed current - voltage characteristics of the p - n oxide heterojunction showed a nonlinear diode-like rectifying behavior. The effects of an oxidizing or electron acceptor gas, such as nitrogen monoxide (NO), on the ZnO nanorod/CuO thin-film heterojunction were investigated to determine the potential applications of the fabricated material for use in gas sensors. The forward current of the p - n heterojunction was remarkably reduced when NO gas was introduced into dry air at temperatures from 100 to 250 .deg. C. The NO gas response of the oxide heterojunction reached a maximum value at an operating temperature of 180 .deg. C and linearly increased as the NO gas concentration was increased from 5 to 30 ppm. The sensitivity value was observed to be as high as 170% at 180 .deg. C when biased at 2 V in the presence of 20-ppm NO. The ZnO nanorod/CuO thin-film heterojunction also exhibited a stable and repeatable response to NO gas. The experimental results suggest that the ZnO nanorod/CuO thin-film heterojunction structure may be a novel candidate for gas sensors.

Zinc-oxide nanorod / copper-oxide thin-film heterojunction for a nitrogen-monoxide gas sensor

Energy Technology Data Exchange (ETDEWEB)

Yoo, Hwansu; Kim, Hyojin; Kim, Dojin [Chungnam National University, Daejeon (Korea, Republic of)

2014-11-15

A novel p - n oxide heterojunction structure was fabricated by employing n-type zinc-oxide (ZnO) nanorods grown on an indium-tin-oxide-coated glass substrate by using the hydrothermal method and a p-type copper-oxide (CuO) thin film deposited onto the ZnO nanorod array by using the sputtering method. The crystallinities and microstructures of the heterojunction materials were examined by using X-ray diffraction and scanning electron microscopy. The observed current - voltage characteristics of the p - n oxide heterojunction showed a nonlinear diode-like rectifying behavior. The effects of an oxidizing or electron acceptor gas, such as nitrogen monoxide (NO), on the ZnO nanorod/CuO thin-film heterojunction were investigated to determine the potential applications of the fabricated material for use in gas sensors. The forward current of the p - n heterojunction was remarkably reduced when NO gas was introduced into dry air at temperatures from 100 to 250 .deg. C. The NO gas response of the oxide heterojunction reached a maximum value at an operating temperature of 180 .deg. C and linearly increased as the NO gas concentration was increased from 5 to 30 ppm. The sensitivity value was observed to be as high as 170% at 180 .deg. C when biased at 2 V in the presence of 20-ppm NO. The ZnO nanorod/CuO thin-film heterojunction also exhibited a stable and repeatable response to NO gas. The experimental results suggest that the ZnO nanorod/CuO thin-film heterojunction structure may be a novel candidate for gas sensors.

Release studies of a thin foil tantalum target for the production of short-lived radioactive nuclei

CERN Document Server

Bennett, J R J; Drumm, P V; Lettry, Jacques; Nilsson, T; Catherall, R; Jonsson, O C; Ravn, H L; Simon, H

2002-01-01

Measurements have been made at ISOLDE, of the release curves and yields of radioactive beams of lithium, sodium and beryllium from a target constructed from 2 $\\mu$m thick foils. The release curves have been analysed by fitting to a mathematical model to determine the coefficients of diffusion of the particles in the foils and effusion through the target and ionizer at several temperatures. Through a better understanding of the rate of transport of the particles, it is possible to design targets and ionizers with improved yields. This is most important for the rare, short-lived isotopes in which there is considerable interest for physics experiments. This target has demonstrated large increases in the yields of $^{11}$Li and $^{12}$Be, in agreement with the predictions of the model. (11 refs).

Experiments with activated metal foils

Energy Technology Data Exchange (ETDEWEB)

Malati, M A [Medway and Maidstone Coll. of Tech., Chatham (UK)

1978-09-01

Experiments based on the activation of metal foils by slow neutron bombardment which can be used to demonstrate various aspects of artificial radioactivity are described and discussed. Suitable neutron sources and foils are considered.

Uniformly Distributed Graphene Domain Grows on Standing Copper via Low-Pressure Chemical Vapor Deposition

Directory of Open Access Journals (Sweden)

Shih-Hao Chan

2013-01-01

Full Text Available Uniformly distributed graphene domains were synthesized on standing copper foil by a low-pressure chemical vapor deposition system. This method improved the distribution of the graphene domains at different positions on the same piece of copper foil along the forward direction of the gas flow. Scanning electron microscopy (SEM showed the average size of the graphene domains to be about ~20 m. This results show that the sheet resistance of monolayer graphene on a polyethylene terephthalate (PET substrate is about ~359 /□ whereas that of the four-layer graphene films is about ~178 /□, with a transmittance value of 88.86% at the 550 nm wavelength. Furthermore, the sheet resistance can be reduced with the addition of HNO3 resulting in a value of 84 /□. These values meet the absolute standard for touch sensor applications, so we believe that this method can be a candidate for some transparent conductive electrode applications.

Thin copper oxide films prepared by ion beam sputtering with subsequent thermal oxidation: Application in chemiresistors

Science.gov (United States)

Horak, P.; Bejsovec, V.; Vacik, J.; Lavrentiev, V.; Vrnata, M.; Kormunda, M.; Danis, S.

2016-12-01

Copper oxide films were prepared by thermal oxidation of thin Cu films deposited on substrates by ion beam sputtering. The subsequent oxidation was achieved in the temperature range of 200 °C-600 °C with time of treatment from 1 to 7 h (with a 1-h step) in a furnace open to air. At temperatures 250 °C-600 °C, the dominant phase formed was CuO, while at 200 °C mainly the Cu2O phase was identified. However, the oxidation at 200 °C led to a more complicated composition - in the depth Cu2O phase was observed, though in the near-surface layer the CuO dominant phase was found with a significant presence of Cu(OH)2. A limited amount of Cu2O was also found in samples annealed at 600 °C. The sheet resistance RS of the as-deposited Cu sample was 2.22 Ω/□, after gradual annealing RS was measured in the range 2.64 MΩ/□-2.45 GΩ/□. The highest RS values were obtained after annealing at 300 °C and 350 °C, respectively. Oxygen depth distribution was studied using the 16O(α,α) nuclear reaction with the resonance at energy 3032 keV. It was confirmed that the higher oxidation degree of copper is located in the near-surface region. Preliminary tests of the copper oxide films as an active layer of a chemiresistor were also performed. Hydrogen and methanol vapours, with a concentration of 1000 ppm, were detected by the sensor at an operating temperature of 300 °C and 350 °C, respectively. The response of the sensors, pointed at the p-type conductivity, was improved by the addition of thin Pd or Au catalytic films to the oxidic film surface. Pd-covered films showed an increased response to hydrogen at 300 °C, while Au-covered films were more sensitive to methanol vapours at 350 °C.

Dissociation of dilute immiscible copper alloy thin films

International Nuclear Information System (INIS)

Barmak, K.; Lucadamo, G. A.; Cabral, C. Jr.; Lavoie, C.; Harper, J. M. E.

2000-01-01

The dissociation behavior of dilute, immiscible Cu-alloy thin films is found to fall into three broad categories that correlate most closely with the form of the Cu-rich end of the binary alloy phase diagrams. Available thermodynamic and tracer diffusion data shed further light on alloy behavior. Eight alloying elements were selected for these studies, with five elements from groups 5 and 6, two from group 8, and one from group 11 of the periodic table. They are respectively V, Nb, Ta, Cr, Mo, Fe, Ru, and Ag. The progress of precipitation in approximately 500-nm-thick alloy films, containing 2.5-3.8 at. % solute, was followed with in situ resistance and stress measurements as well as with in situ synchrotron x-ray diffraction. In addition, texture analysis and transmission electron microscopy were used to investigate the evolution of microstructure and texture of Cu(Ta) and Cu(Ag). For all eight alloys, dissociation occurred upon heating, with the rejection of solute and evolution of microstructure often occurring in multiple steps that range over several hundred degrees between approximately 100 and 900 degree sign C. However, in most cases, substantial reductions in resistivity of the films took place below 400 degree sign C, at temperatures of interest to copper metallization schemes for silicon chip technology. (c) 2000 American Institute of Physics

Experimental evidence of beam-foil plasma creation during ion-solid interaction

Energy Technology Data Exchange (ETDEWEB)

Sharma, Prashant, E-mail: prashant@iuac.res.in; Nandi, Tapan [Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110067 (India)

2016-08-15

Charge state evolution of the energetic projectile ions during the passage through thin carbon foils has been revisited using the X-ray spectroscopy technique. Contributions from the bulk and the solid surface in the charge changing processes have been segregated by measuring the charge state distribution of the projectile ions in the bulk of the target during the ion–solid interaction. Interestingly, the charge state distribution measured in the bulk exhibits Lorentzian profile in contrast to the well-known Gaussian structure observed using the electromagnetic methods and the theoretical predictions. The occurrence of such behavior is a direct consequence of the imbalance between charge changing processes, which has been seen in various cases of the laboratory plasma. It suggests that the ion-solid collisions constitute high-density, localized plasma in the bulk of the solid target, called the beam-foil plasma. This condensed beam-foil plasma is similar to the high-density solar and stellar plasma which may have practical implementations in various fields, in particular, plasma physics and nuclear astrophysics. The present work suggests further modification in the theoretical charge state distribution calculations by incorporating the plasma coupling effects during the ion–solid interactions. Moreover, the multi-electron capture from the target exit surface has been confirmed through comparison between experimentally measured and theoretically predicted values of the mean charge state of the projectile ions.

High efficiency graphene coated copper based thermocells connected in series

Science.gov (United States)

Sindhuja, Mani; Indubala, Emayavaramban; Sudha, Venkatachalam; Harinipriya, Seshadri

2018-04-01

Conversion of low-grade waste heat into electricity had been studied employing single thermocell or flowcells so far. Graphene coated copper electrodes based thermocells connected in series displayed relatively high efficiency of thermal energy harvesting. The maximum power output of 49.2W/m2 for normalized cross sectional electrode area is obtained at 60ºC of inter electrode temperature difference. The relative carnot efficiency of 20.2% is obtained from the device. The importance of reducing the mass transfer and ion transfer resistance to improve the efficiency of the device is demonstrated. Degradation studies confirmed mild oxidation of copper foil due to corrosion caused by the electrolyte.

Beam-foil study of neon in the EUV with foils of carbon, silver and gold

International Nuclear Information System (INIS)

Demarest, J.A.; Watson, R.L.; Texas A and M Univ., College Station

1988-01-01

A beam-foil study of 40 MeV neon was conducted in the EUV with a 1-meter grazing incidence spectrometer configured with a position sensitive microchannel plate detector. A number of new lines of Ne IX, mainly from transitions to n = 3 levels, were detected in the wavelength region covering 50-350 A. Comparison of the spectra obtained using the different foils revealed that the average charge state of the neon projectiles was nearly one unit higher with carbon than with either of the two metals. Measurements of line intensities versus distance from the foils showed that cascade contributions were greatly reduced for the metals. It was also found that n = 3 states of low l were overpopulated relative to a statistical distribution, irrespective of the foil material. (orig.)

Cu-Doped ZnO Thin Films Deposited by a Sol-Gel Process Using Two Copper Precursors: Gas-Sensing Performance in a Propane Atmosphere

Directory of Open Access Journals (Sweden)

Heberto Gómez-Pozos

2016-01-01

Full Text Available A study on the propane gas-sensing properties of Cu-doped ZnO thin films is presented in this work. The films were deposited on glass substrates by sol-gel and dip coating methods, using zinc acetate as a zinc precursor, copper acetate and copper chloride as precursors for doping. For higher sensitivity values, two film thickness values are controlled by the six and eight dippings, whereas for doping, three dippings were used, irrespective of the Cu precursor. The film structure was analyzed by X-ray diffractometry, and the analysis of the surface morphology and film composition was made through scanning electron microscopy (SEM and secondary ion mass spectroscopy (SIMS, respectively. The sensing properties of Cu-doped ZnO thin films were then characterized in a propane atmosphere, C3H8, at different concentration levels and different operation temperatures of 100, 200 and 300 °C. Cu-doped ZnO films doped with copper chloride presented the highest sensitivity of approximately 6 × 104, confirming a strong dependence on the dopant precursor type. The results obtained in this work show that the use of Cu as a dopant in ZnO films processed by sol-gel produces excellent catalysts for sensing C3H8 gas.

Quantitative damage and detwinning analysis of nanotwinned copper foil under cyclic loading

International Nuclear Information System (INIS)

Yoo, Byung-Gil; Boles, Steven T.; Liu, Y.; Zhang, X.; Schwaiger, Ruth; Eberl, Christoph; Kraft, Oliver

2014-01-01

High-purity Cu samples containing parallel columns of highly aligned nanotwins with median spacing of ∼25 nm were subjected to tension–compression cyclic loading by a high-throughput cyclic testing method. The methodology utilizes gradients in surface strain amplitude of a vibrating cantilever: one along the beam axis, with decreasing strain from the fixed to the free end of the beam, and the other through the foil thickness with decreasing strain from the surface to the neutral axis. Systematic microstructural investigations indicate that nanotwins are not stable under cyclic loading and that the applied strain amplitude has a strong influence on the resulting twin structure. In the highly stressed regions the detwinning process produces a twin free microstructure, allowing for subsequent extrusion and crack formation, and introduces fatal defects into structural parts

Beam-foil spectroscopy of chlorine and sulfur ions

International Nuclear Information System (INIS)

Frot, D.; Barchewitz, R.; Cukier, M.; Bruneau, J.

1987-01-01

We report on the measurement of spectra of highly stripped chlorine and sulfur ions in the energy ranges of, respectively, 2900 - 3500 eV and 2300 - 2600 eV. The spectra have been obtained after excitation of ions travelling through a thin carbon foil. X-rays emitted by the emerging beam are analysed with a Johann-type bent crystal spectrometer. The observation angle with respect to the beam axis is 54 0 . The interpretation of the spectra is performed by comparing experimental results with Multiconfiguration Dirac-Fock (MCDF) calculated energies and intensities. All the lines are interpreted by 2p - ls transitions (K α spectrum) in excited ions with, respectively, H-, He-, Li-, Be- and B-like electron structures

Neutral hydrogen from the foil-induced dissociation of 4HeH+, 3HeH+, and H2+

International Nuclear Information System (INIS)

Cooney, P.J.; Gemmell, D.S.; Kanter, E.P.; Pietsch, W.J.; Zabransky, B.J.

1979-01-01

High resolution energy spectra and angular distributions of H 0 from the dissociation of 4 HeH + , 3 HeH + , and H 2 + in thin carbon foils are presented for incident ion energies ranging from 170 to 1800 keV/amu. For the range of dwell times inside the target foils studied (about 1 to 10 fsec), the dominant mechanism for such dissociation is the Coulomb explosion of the ions inside the target followed by electron capture near the rear surface of the foil. At the shortest of these dwell times, the yield of H 0 for incident ions oriented perpendicular to the beam relative to that for ions aligned with the beam is a factor of two greater than at longer dwell times. These data indicate that, for ion fragments which emerge from the rear surface of the target within a few angstroms of one another, those in the perpendicular orientation have a greater electron capture probability than those emerging in other orientations. 9 references

A discrete-time amplifier based on Thin-Film Trans-Capacitors for sensor systems on foil

NARCIS (Netherlands)

Raiteri, D.; Roermund, van A.H.M.; Cantatore, E.

2014-01-01

Organic materials can be used to fabricate sensors for physical and chemical quantities, and also to make electronics. The integration of these two elements holds the promise to enable novel smart-sensors on foil. In this paper, we deal with the design of the first stage of a signal conditioning

Thin-layer heap bioleaching of copper flotation tailings containing high levels of fine grains and microbial community succession analysis

Science.gov (United States)

Hao, Xiao-dong; Liang, Yi-li; Yin, Hua-qun; Liu, Hong-wei; Zeng, Wei-min; Liu, Xue-duan

2017-04-01

Thin-layer heap bioleaching of copper flotation tailings containing high levels of fine grains was carried out by mixed cultures on a small scale over a period of 210 d. Lump ores as a framework were loaded at the bottom of the ore heap. The overall copper leaching rates of tailings and lump ores were 57.10wt% and 65.52wt%, respectively. The dynamic shifts of microbial community structures about attached microorganisms were determined using the Illumina MiSeq sequencing platform based on 16S rRNA amplification strategy. The results indicated that chemolithotrophic genera Acidithiobacillus and Leptospirillum were always detected and dominated the microbial community in the initial and middle stages of the heap bioleaching process; both genera might be responsible for improving the copper extraction. However, Thermogymnomonas and Ferroplasma increased gradually in the final stage. Moreover, the effects of various physicochemical parameters and microbial community shifts on the leaching efficiency were further investigated and these associations provided some important clues for facilitating the effective application of bioleaching.

Chemical Vapour Deposition of Large Area Graphene

DEFF Research Database (Denmark)

Larsen, Martin Benjamin Barbour Spanget

Chemical Vapor Deposition (CVD) is a viable technique for fabrication of large areas of graphene. CVD fabrication is the most prominent and common way of fabricating graphene in industry. In this thesis I have attempted to optimize a growth recipe and catalyst layer for CVD fabrication of uniform......, single layer, and high carrier mobility large area graphene. The main goals of this work are; (1) explore the graphene growth mechanics in a low pressure cold-wall CVD system on a copper substrate, and (2) optimize the process of growing high quality graphene in terms of carrier mobility, and crystal...... structure. Optimization of a process for graphene growth on commercially available copper foil is limited by the number of aluminium oxide particles on the surface of the catalyst. By replacing the copper foil with a thin deposited copper film on a SiO2/Si or c-plane sapphire wafer the particles can...

Investigating the foil-generated deuteron beam interaction with a DT target in degenerate and classical plasma

Science.gov (United States)

Mehrangiz, M.; Ghasemizad, A.

2017-06-01

Deuteron fast ignition of a conically guided pre-compressed DT fuel is investigated. For this purpose, the acceleration of the deuterated thin foil by the intense laser beam is evaluated. The acceleration values and the number of foil-generated deuterons are calculated in terms of the laser pulse duration. Using the created deuterons as the fast ignitors, we investigate the fast ignition scheme by comparing fully degenerate, partial degenerate and classical types of DT plasma. The total energy gain of deuterons "beam fusion" is calculated to show the efficiency of beam reactions in increasing fusion rate. Besides, the stopping time and stopping range of incident deuterons are evaluated. Our numerical results indicate that degeneracy increases the beam-target collisions. Thus, it prepares the ignition situation sooner than the classical plasma. Moreover, the number of generated deuterons and their acceleration depend on the foil thickness and laser parameters. We show that when a 4ps laser with intensity of 10^{19} W/cm^2 focused onto a 20μm foil, 35× 10^{15} deuterons are generated. Moreover, under our analysis, in order to have a practicable fast ignition, 18% of the laser energy is necessary to convert into a deuteron driver.

Damage of copper by low energy xenon ions

International Nuclear Information System (INIS)

Babad-Zakhryapin, A.A.; Popenko, V.A.

1988-01-01

Changes in the copper crystal structure bombarded by xenon ions with 30-150 eV energy are studied. Foils of MOb copper mark, 10 mm in diameter and 100 μm thickness, are irradiated. The initial specimens are annealed in vacuum during 1 h at 900 K temperature. The specimens are bombarded by xenon ions in a water-cooled holder. A TE-O type accelerator serves as a xenon ion source. The ion energy varies within 30 to 150 eV range. The ion flux density is 8x10 16 ion/(cm 2 xs). It is shown that crystal structure variations at deep depths are observed not only at high (>1 keV), but at low ion energies down to several dozens of electronvolt as well. The crystal structure variation on copper irradiation by xenon ions with 30-150 eV energy is followed by formation of defects like dislocation loops, point defects in the irradiated target bulk

Theoretical evaluation of self-shielding factors due to scattering resonances in foils

International Nuclear Information System (INIS)

Selander, W.N.

1960-06-01

A semi-analytical method is given for evaluating self-shielding factors for activation measurements which use thin foils having neutron scattering resonances. The energy loss by scattering in the foil is taken into account. The energy-dependent neutron angular distribution is expanded as a double series, the coefficients of which are (energy dependent) solutions of an infinite set of coupled integral equations. These are truncated in some suitable manner and solved numerically. The leading term of the series is proportional to the average, or effective flux in the activation sample. The product of this terra and the neutron capture cross-section is integrated numerically over the resonance to give the resonance self-shielding correction. Figure 4 shows resonance self-shielding factors derived in this mariner for the 132ev resonance in Co-59 and figure 5 shows similar results for the two Mn-55 resonances at 337ev and 1080ev. Self-shielding factors for 1/v capture are not significantly different from unity. (author)

SR-XRD and SR-FTIR study of the alteration of silver foils in medieval paintings.

Science.gov (United States)

Salvadó, Nati; Butí, Salvador; Labrador, Ana; Cinque, Gianfelice; Emerich, Hermann; Pradell, Trinitat

2011-03-01

Altarpieces and polychrome carved wood from the fifteenth century AD usually exhibit golden and silvery areas by the application of a very thin foil of metal. The metal foils were normally protected from the atmosphere by a varnish or resin which maybe either preserved or absent. Moreover, they were glued to the background surface by adhesive substances (egg yolk, drying oil or animal glue). The high proportion of the glueing substances often renders the development of reaction compounds. With time, silver alters blacken or simply disappear completely. In this paper, we study the alterations to metal foils from a selection of fifteenth century artworks showing different glueing agents, organic coatings and several degrees of conservation of the organic coatings and metal leafs. The submillimetric layered structure and the high variability and low amount of most of the compounds present in the different layers, as well as their differing nature (organic and inorganic) make the use of micron-sensitive high-resolution techniques essential for their study. In particular, the high resolution, high brilliance and small footprint renders synchrotron radiation most adequate for their study. SR-XRD was performed to identify the reaction compounds formed in the different layers; μFTIR was used at to identify the silver protecting organic coatings, the metal foil glueing layers and the corresponding reaction compounds. The results obtained suggest that atmospheric corrosion is the dominant mechanism, and therefore that the degree of corrosion of the metal foils is mainly related to the conservation state of the protecting coatings.

Interaction of fast Hn+ with the last layers of carbon foils

International Nuclear Information System (INIS)

Farizon, M.; Faria, N.V.C. de; Mazuy-Farizon, B.; Gaillard, M.J.

1993-03-01

A Monte Carlo program describing the penetration of H n + hydrogen clusters in thin foils has been used to build a model of charge exchange for protons resulting from the breakup of these clusters. The total neutral fractions observed at emergence with cluster projectiles H n + , n < 23 in the energy range 40-120 keV/u, as well as the number of 2p excited states are well reproduced by these calculations taking into account geometrical structures of the projectiles and vicinity effects. (author) 8 refs.; 2 figs

Quantum beats study of the 4He+ beam-carbon foil interaction

International Nuclear Information System (INIS)

Denis, A.; Desesquelles, J.

1979-01-01

Excitation cross-sections are deduced from the analysis of quantum beats in an electric field for an 4 He + (n=4) ion beam scattering through a thin carbon foil. The population distribution obtained at 1 MeV for 4S, 4P, 4D and 4F levels is in good agreement with a second-order Born approximation calculation of the electronic capture He ++ +C→He + (n=4) + C + . The alignment is found to be negative for P, D and F levels. The coherences Δl=+-1 have been measured, for amplitudes and phases [fr

Effects of differently hardened brass foil laminate on the electromechanical property of externally laminated CC tapes

Energy Technology Data Exchange (ETDEWEB)

Bautista, Zhierwinjay; Shin, Hyung Seop [Dept. of Mechanical Design Engineering, Andong National University, Andong (Korea, Republic of); Mean, Byoung Jean; Lee, Jae Hun [SuNAM Co Ltd., Anseong (Korea, Republic of)

2016-12-15

The mechanical properties of REBCO coated conductor (CC) wires under uniaxial tension are largely determined by the thick component layers in the architecture, namely, the substrate and the stabilizer or even the reinforcement layer. Depending on device applications of the CC tapes, it is necessary to reinforce thin metallic foils externally to one-side or both sides of the CC tapes. Due to the external reinforcement of brass foils, it was found that this could increase the reversible strain limit from the Cu-stabilized CC tapes. In this study, the effects of differently hardened brass foil laminate on the electromechanical property of CC tapes were investigated under uniaxial tension loading. The tensile strain dependence of the critical current (I{sub c}) was measured at 77 K and self-field. Depending on whether the I{sub c} of CC tapes were measured during loading or after unloading, a reversible strain (or stress) limit could be determined, respectively. The both-sides of the Cu-stabilized CC tapes were laminated with brass foils with different hardness, namely 1/4H, 1H and EH. From the obtained results, it showed that the yield strength of the brass laminated CC tapes with EH brass foil laminate was comparable to the one of the Cu-stabilized CC tape due to its large yield strength even though its large volume fraction. It was found that the brass foil with different hardness was mainly sensitive on the stress dependence of I{sub c}, but not on the strain sensitivity due to the residual strain induced in the laminated CC tapes during unloading.

Test of the fast thin-film ferromagnetic shutters for ultracold neutrons

International Nuclear Information System (INIS)

Pokotilovskij, Yu.N.; Novopol'tsev, M.I.; Geltenbort, P.

2008-01-01

Test of thin-film ferromagnetic shutters of two types for ultracold neutrons has been performed. The first type is based on neutron reflection from the sequence of successively placed thin ferromagnetic layers with oppositely directed magnetization. The second one is based on neutron refraction in ferromagnetic foils inserted in the beam

Single-jet gas cooling of in-beam foils or specimens: Prediction of the convective heat-transfer coefficient

Science.gov (United States)

Steyn, Gideon; Vermeulen, Christiaan

2018-05-01

An experiment was designed to study the effect of the jet direction on convective heat-transfer coefficients in single-jet gas cooling of a small heated surface, such as typically induced by an accelerated ion beam on a thin foil or specimen. The hot spot was provided using a small electrically heated plate. Heat-transfer calculations were performed using simple empirical methods based on dimensional analysis as well as by means of an advanced computational fluid dynamics (CFD) code. The results provide an explanation for the observed turbulent cooling of a double-foil, Havar beam window with fast-flowing helium, located on a target station for radionuclide production with a 66 MeV proton beam at a cyclotron facility.

Sol-gel prepared B2O3-SiO2 thin films for protection of copper substrates

International Nuclear Information System (INIS)

Gouda, M.; Ahmed, M.S.; Shahin, M.A.

2000-01-01

Full text.Borosilicate coating has potential for applications in the field of electronics, e.g., as passivation layers. One of the main difficulties for applying these films by the conventional melting process is the extensive volatilization of B 2 O 3 from the melt. In this work transparent borosilicate films of 2OB 2 O3.8OSiO 2 (in mole %). Prepared by the sole gel method, were applied onto copper substrates by dip-coating technique. The transparency of these films was very sensitive to the humidity of the atmosphere during the coating process. Transparent films were obtained below 20% relative humidity at 20 celsius degree. High temperature oxidation tests, at about 585 celsius degree stream of air, showed that the sol-gel prepared 2OB 2 O 3 .8OSiO 2 thin films are protective coating for copper substrates under fairly severe temperature gradient and oxidizing atmosphere. It was found that the protective action of these films depends on the film thickness

Foil fabrication for the ROMANO event. Revision 1

International Nuclear Information System (INIS)

Romo, J.G. Jr.; Weed, J.W.; Griggs, G.E.; Brown, T.G.; Tassano, P.L.

1984-01-01

The Vacuum Processes Lab (VPL), of LLNL's M.E. Dept. - Material Fabrication Division (MFD), conducted various vacuum related support activities for the ROMANO nuclear physics experiment. This report focuses on the foil fabrication activities carried out between July and November 1983 for the ROMANO event. Other vacuum related activities for ROMANO, such as outgassing tests of materials, are covered in separate documentation. VPL was asked to provide 270 coated Parylene foils for the ROMANO event. However, due to the developmental nature of some of the procedures, approximately 400 coated foils were processed. In addition, VPL interacted with MFD's Plastics Shop to help supply Parylene substrates to other organizations (i.e., LBL and commercial vendors) which had also been asked to provide coated foils for ROMANO. The purposes of this report are (A) to document the processes developed and the techniques used to produce the foils, and (B) to suggest future directions. The report is divided into four sections describing: (1) nuclear target foil fabrication, (2) Parylene substrate preparation and production, (3) calibration foil fabrication, and (4) foil and substrate inspections

INJECTION CARBON STRIPPING FOIL ISSUES IN THE SNS ACCUMULATOR RING

International Nuclear Information System (INIS)

BEEBE-WANG, J.; LEE, Y.Y.; RAPARIA, D.; WEI, J.

2001-01-01

We are reporting the results of studies on issues related to the injection stripping foil in the Spallation Neutron Source (SNS) accumulator ring. The problems related to foil heating and foil lifetime, such as current density distribution and temperature distribution in the foil, are investigated. The impact of injection errors on the beam losses at the foil is studied. The particle traversal rate and the beam losses due to scattering in the foil are summarized. Finally, SNS end-to-end simulation results of the foil-missing rate, the foil-hitting rate and the maximum foil temperature are presented

Characterization of beryllium foil produced by hot rolling

International Nuclear Information System (INIS)

Wittenauer, J.; Nieh, T.G.; Waychunas, G.

1992-01-01

Beryllium foil is important for a number of aerospace applications including honeycomb structures and metal-matrix composites. In this study, a method of producing beryllium foil directly from powder or flake is demonstrated. A variety of foils were produced in the thickness range 90-300 μm, free from defects such as pinholes and excessive surface roughness, and exhibiting sufficient formability for honeycomb manufacture. Foil produced directly from powder or flake exhibits crystallographic texture, microstructure, and formability equivalent to foil produced from more massive precursors. (Author)

Monitoring the degradation of partly decomposable plastic foils

Directory of Open Access Journals (Sweden)

Rétháti Gabriella

2014-11-01

Full Text Available We have monitored the behaviour of different polyethylene foils including virgin medium density polyethylene (MDPE, MDPE containing pro-oxydative additives (238, 242 and MDPE with pro-oxydative additives and thermoplastic starch (297 in the soil for a period of one year. A foil based on a blend of polyester and polylactic acid (BASF Ecovio served as degradable control. The experiment was carried out by weekly measurements of conductivity and capacity of the soil, since the setup was analogous to a condenser, of which the insulating layer was the foil itself. The twelve replications allowed monthly sampling; the specimen taken out from the soil each month were tested visually for thickness, mechanical properties, morphological and structural changes, and molecular mass. Based on the obtained capacity values, we found that among the polyethylene foils, the one that contained thermoplastic starch extenuated the most. This foil had the greatest decrease in tensile strength and elongation at break due to the presence of thermoplastic starch. The starch can completely degrade in the soil; thus, the foil had cracks and pores. The polyethylene foils that contained pro-oxydant additives showed smaller external change compared to the virgin foil, since there was no available UV radiation and oxygen for their degradation. The smallest change occurred in the virgin polyethylene foil. Among the five examined samples, the commercially available BASF foil showed the largest extenuation and external change, and it deteriorated the most in the soil.

Thin film analysis by instrumental heavy ion activation analysis using distributed recoil ranges of isotopic products

International Nuclear Information System (INIS)

Chowdhury, D.P.; Guin, R.; Saha, S.K.; Sudersanan, M.

2006-01-01

Thin foils (0.1 to 10 μm), metallic or polymeric, are frequently used in nuclear physics and chemistry experiments using ion beams from an accelerator. Very often it is important to know the major, minor and trace element composition of the foil. Several nuclear analytical techniques, namely RBS, ERDA, etc. are available for the near surface analysis. We have applied heavy ion activation analysis (HIAA) to explore the bulk composition of thin films. One of the difficulties in this method of thin film analysis is that the product nuclides from nuclear reaction come out of the sample surface due to high recoil energy. In thick sample, the recoiled nuclides are absorbed in the sample itself. This effect has been used to employ heavy ion activation for the analysis of thin films

Particle velocity measurements in laser irradiated foils using ORVIS

International Nuclear Information System (INIS)

Sheffield, S.A.; Fisk, G.A.

1983-01-01

Aluminum foils from 2- to 200-μm thick have been subjected to a Nd:YAG laser pulse of low irradiance (10 9 W/cm 2 , approx. 10 ns pulse) to produce laser-driven shocks in the foils. The particle velocity history of the foil side opposite the laser deposition was monitored with nanosecond resolution by a velocity interferometer system called ORVIS. These histories indicate a shock reverberation process accelerates the foil. Peak foil velocities can be adequately calculated using a ricket propulsion model developed from experiments at much higher irradiances. A velocity of 1 km/s was developed in a 2-μm-thick free foil in a time of 50 ns. Water-confined foils attained peak particle velocities about three times higher than those of free foils

Deposition of Antimicrobial Copper-Rich Coatings on Polymers by Atmospheric Pressure Jet Plasmas

Directory of Open Access Journals (Sweden)

Jana Kredl

2016-04-01

Full Text Available Inanimate surfaces serve as a permanent reservoir for infectious microorganisms, which is a growing problem in areas in everyday life. Coating of surfaces with inorganic antimicrobials, such as copper, can contribute to reduce the adherence and growth of microorganisms. The use of a DC operated air plasma jet for the deposition of copper thin films on acrylonitrile butadiene styrene (ABS substrates is reported. ABS is a widespread material used in consumer applications, including hospitals. The influence of gas flow rate and input current on thin film characteristics and its bactericidal effect have been studied. Results from X-ray photoelectron spectroscopy (XPS and atomic force microscopy confirmed the presence of thin copper layers on plasma-exposed ABS and the formation of copper particles with a size in the range from 20 to 100 nm, respectively. The bactericidal properties of the copper-coated surfaces were tested against Staphylococcus aureus. A reduction in growth by 93% compared with the attachment of bacteria on untreated samples was observed for coverage of the surface with 7 at. % copper.

Weld Repair of Thin Aluminum Sheet

Science.gov (United States)

Beuyukian, C. S.; Mitchell, M. J.

1986-01-01

Weld repairing of thin aluminum sheets now possible, using niobium shield and copper heat sinks. Refractory niobium shield protects aluminum adjacent to hole, while copper heat sinks help conduct heat away from repair site. Technique limits tungsten/inert-gas (TIG) welding bombardment zone to melt area, leaving surrounding areas around weld unaffected. Used successfully to repair aluminum cold plates on Space Shuttle, Commercial applications, especially in sealing fractures, dents, and holes in thin aluminum face sheets or clad brazing sheet in cold plates, heat exchangers, coolers, and Solar panels. While particularly suited to thin aluminum sheet, this process also used in thicker aluminum material to prevent surface damage near weld area.

Physical, optical and electrical properties of copper selenide (CuSe) thin films deposited by solution growth technique at room temperature

International Nuclear Information System (INIS)

Gosavi, S.R.; Deshpande, N.G.; Gudage, Y.G.; Sharma, Ramphal

2008-01-01

Copper selenide (CuSe) thin films are grown onto amorphous glass substrate from an aqueous alkaline medium using solution growth technique (SGT) at room temperature. The preparative parameters were optimized to obtain good quality of thin films. The as-deposited films were characterized for physical, optical and electrical properties. X-ray diffraction (XRD) pattern reveals that the films are polycrystalline in nature. Energy dispersive analysis by X-ray (EDAX) shows formation of stoichiometric CuSe compound. Uniform deposition of CuSe thin films on glass substrate was observed from scanning electron microscopy (SEM) and atomic force microscopy (AFM) micrographs. Average grain size was determined to 144.53 ± 10 nm using atomic force microscopy. The band gap was found to be 2.03 eV with direct band-to-band transition. Semi-conducting behaviour was observed from resistivity measurements. Ohmic behaviour was seen from I-V curve with good electrical conductivity

High Efficiency Graphene Coated Copper Based Thermocells Connected in Series

Directory of Open Access Journals (Sweden)

Mani Sindhuja

2018-04-01

Full Text Available Conversion of low-grade waste heat into electricity had been studied employing single thermocell or flowcells so far. Graphene coated copper electrodes based thermocells connected in series displayed relatively high efficiency of thermal energy harvesting. The maximum power output of 49.2 W/m2 for normalized cross sectional electrode area is obtained at 60°C of inter electrode temperature difference. The relative carnot efficiency of 20.2% is obtained from the device. The importance of reducing the mass transfer and ion transfer resistance to improve the efficiency of the device is demonstrated. Degradation studies confirmed mild oxidation of copper foil due to corrosion caused by the electrolyte.

Wafer-level hermetic vacuum packaging by bonding with a copper-tin thin film sealing ring

Science.gov (United States)

Akashi, Teruhisa; Funabashi, Hirofumi; Takagi, Hideki; Omura, Yoshiteru; Hata, Yoshiyuki

2018-04-01

A wafer-level hermetic vacuum packaging technology intended for use with MEMS devices was developed based on a copper-tin (CuSn) thin film sealing ring. To allow hermetic packaging, the shear strength of the CuSn thin film bond was improved by optimizing the pretreatment conditions. As a result, an average shear strength of 72.3 MPa was obtained and a cavity that had been hermetically sealed using wafer-level packaging (WLP) maintained its vacuum for 1.84 years. The total pressures in the cavities and the partial pressures of residual gases were directly determined with an ultra-low outgassing residual gas analyzer (RGA) system. Hermeticity was evaluated based on helium leak rates, which were calculated from helium pressures determined with the RGA system. The resulting data showed that a vacuum cavity following 1.84 years storage had a total pressure of 83.1 Pa, contained argon as the main residual gas and exhibited a helium leak rate as low as 1.67  ×  10-17 Pa · m3 s-1, corresponding to an air leak rate of 6.19  ×  10-18 Pa · m3 s-1. The RGA data demonstrate that WLP using a CuSn thin film sealing ring permits ultra-high hermeticity in conjunction with long-term vacuum packaging that is applicable to MEMS devices.

Densities of carbon foils

International Nuclear Information System (INIS)

Stoner, J.O. Jr.

1991-01-01

The densities of arc-evaporated carbon target foils have been measured by several methods. The density depends upon the method used to measure it; for the same surface density, values obtained by different measurement techniques may differ by fifty percent or more. The most reliable density measurements are by flotation, yielding a density of 2.01±0.03 g cm -3 , and interferometric step height with the surface density known from auxiliary measurements, yielding a density of 2.61±0.4 g cm -3 . The difference between these density values mayy be due in part to the compressive stresses that carbon films have while still on their substrates, uncertainties in the optical calibration of surface densities of carbon foils, and systematic errors in step-height measurements. Mechanical thickness measurements by micrometer caliper are unreliable due to nonplanarity of these foils. (orig.)

Characterization of U-Mo Foils for AFIP-7

Energy Technology Data Exchange (ETDEWEB)

Edwards, Danny J.; Ermi, Ruby M.; Schemer-Kohrn, Alan L.; Overman, Nicole R.; Henager, Charles H.; Burkes, Douglas; Senor, David J.

2012-11-07

Twelve AFIP in-process foil samples, fabricated by either Y-12 or LANL, were shipped from LANL to PNNL for potential characterization using optical and scanning electron microscopy techniques. Of these twelve, nine different conditions were examined to one degree or another using both techniques. For this report a complete description of the results are provided for one archive foil from each source of material, and one unirradiated piece of a foil of each source that was irradiated in the Advanced Test Reactor. Additional data from two other LANL conditions are summarized in very brief form in an appendix. The characterization revealed that all four characterized conditions contained a cold worked microstructure to different degrees. The Y-12 foils exhibited a higher degree of cold working compared to the LANL foils, as evidenced by the highly elongated and obscure U-Mo grain structure present in each foil. The longitudinal orientations for both of the Y-12 foils possesses a highly laminar appearance with such a distorted grain structure that it was very difficult to even offer a range of grain sizes. The U-Mo grain structure of the LANL foils, by comparison, consisted of a more easily discernible grain structure with a mix of equiaxed and elongated grains. Both materials have an inhomogenous grain structure in that all of the characterized foils possess abnormally coarse grains.

Numerical and experimental investigation of bump foil mechanical behaviour

DEFF Research Database (Denmark)

Larsen, Jon Steffen; Cerda Varela, Alejandro Javier; Santos, Ilmar

2014-01-01

Corrugated foils are utilized in air foil bearings to introduce compliance and damping thus accurate mathematical predictions are important. A corrugated foil behaviour is investigated experimentally as well as theoretically. The experimental investigation is performed by compressing the foil...

FOIL ELEMENT FOR NUCLEAR REACTOR

Science.gov (United States)

Noland, R.A.; Walker, D.E.; Spinrad, B.I.

1963-07-16

A method of making a foil-type fuel element is described. A foil of fuel metal is perforated in; regular design and sheets of cladding metal are placed on both sides. The cladding metal sheets are then spot-welded to each other through the perforations, and the edges sealed. (AEC)

Nuclear target foil fabrication for the Romano Event

International Nuclear Information System (INIS)

Weed, J.W.; Romo, J.G. Jr.; Griggs, G.E.

1984-01-01

The Vacuum Processes Lab, of LLNL's M.E. Dept. - Material Fabrication Division, was requested to provide 250 coated Parylene target foils for a nuclear physics experiment titled the ROMANO Event. Due to the developmental nature of some of the fabrication procedures, approximately 400 coated foils were produced to satisfy the event's needs. The foils were used in the experiment as subkilovolt x-ray, narrow band pass filters, and wide band ultraviolet filters. This paper is divided into three sections describing: (1) nuclear target foil fabrication, (2) Parylene substrate preparation and production, and (3) foil and substrate inspections

Controlling the Performance of P-type Cu2O/SnO Bilayer Thin-Film Transistors by Adjusting the Thickness of the Copper Oxide Layer

KAUST Repository

Al-Jawhari, Hala A.; Caraveo-Frescas, Jesus Alfonso; Hedhili, Mohamed N.

2014-01-01

The effect of copper oxide layer thickness on the performance of Cu2O/SnO bilayer thin-film transistors was investigated. By using sputtered Cu2O films produced at an oxygen partial pressure, Opp, of 10% as the upper layer and 3% Opp SnO films

The direct determination, by differential pulse anodic-stripping voltammetry at the thin mercury-film electrode, of cadmium, lead and copper

International Nuclear Information System (INIS)

Lee, A.F.

1981-01-01

This report describes the development and application of a voltammetric procedure for the direct, simultaneous determination of cadmium, lead, and copper in three SAROC reference materials (carbonatite, magnesite, and quartz). The electrolyte was a mixture of 1 M ammonium chloride, 0,1 M citric acid, and 0,025 M ascorbic acid. No interferences were encountered from Fe(III), As(III), Sb(V), Tl(I), or In(III) at the concentrations present in the samples. Intermetallic interferences were eliminated by the use of thin mercury-film electrodes not less than 80nm thick. Limits of detection were determined by the degree to which the supporting electrolyte could be purified, and were estimated to be 10ng/g, 250ng/g, and 150ng/g for cadmium, lead, and copper respectively

An RBS study of thin PLD and MOCVD strontium copper oxide layers

Energy Technology Data Exchange (ETDEWEB)

Kantor, Z. [Institute of Physics, University of Pannonia, H-8200 Veszprem (Hungary); Papadopoulou, E.L.; Aperathitis, E. [Inst. Electronic Struture and Laser, Foundation for Research and Technology - Hellas, P.O. Box 1527, Heraklion 71110 (Greece); Deschanvres, J.-L. [LMPG INP Grenoble-Minatec, BP 257, 38016 Grenoble Cedex 1 (France); Somogyi, K. [MicroVacuum Ltd., Kerekgyarto u.: 10, H-1147 Budapest (Hungary)], E-mail: karoly.somogyi@microvacuum.com; Szendro, I. [MicroVacuum Ltd., Kerekgyarto u.: 10, H-1147 Budapest (Hungary)

2008-09-30

Strontium copper oxide (SCO) has been studied as p-type transparent (VIS) conductive oxide material. Also theoretical studies suggested p-type conductivity of the SrCu{sub 2}O{sub 2} composition. SCO thin layers, with thicknesses of 30-2000 nm, were deposited on glass and silicon substrates both by pulsed laser deposition (PLD) and by MOCVD method. The as-grown layers showed high electrical resistance. Due to an annealing process, the resistivity significantly decreased and the layers showed p-type conductivity. Optical transparency measured on samples grown on glass substrates was found about or above 80%, including also thickness dependence. RBS measurements were applied for the determination of the chemical composition profile of the layers. A comparison revealed some specific differences between as-grown and annealed PLD samples. Due to the annealing, the ratio of oxide phases was changed and a vertical inhomogeneity in chemical composition was observed. Our measurements revealed also the influence of the deposition technique and of the substrate.

Technical Development Path for Gas Foil Bearings

Science.gov (United States)

Dellacorte, Christopher

2016-01-01

Foil gas bearings are in widespread commercial use in air cycle machines, turbocompressors and microturbine generators and are emerging in more challenging applications such as turbochargers, auxiliary power units and propulsion gas turbines. Though not well known, foil bearing technology is well over fifty years old. Recent technological developments indicate that their full potential has yet to be realized. This paper investigates the key technological developments that have characterized foil bearing advances. It is expected that a better understanding of foil gas bearing development path will aid in future development and progress towards more advanced applications.

Radioactivity analysis in niobium activation foils

Energy Technology Data Exchange (ETDEWEB)

Mueller, G.E.

1995-06-01

The motivation for this study was to measure and analyze the activity of six (6) niobium (Nb) foils (the x-rays from an internal transition in Nb-93m) and apply this information with previously obtained activation foil data. The niobium data was used to determine the epithermal to MeV range for the neutron spectrum and fluence. The foil activation data was re-evaluated in a spectrum analysis code (STAY`SL) to provide new estimates of the exposure at the Los Alamos Spallation Radiation Effect Facility (LASREF). The activity of the niobium foils was measured and analyzed at the University of Missouri-Columbia (UMC) under the direction of Professor William Miller. The spectrum analysis was performed at the University of Missouri-Rolla (UMR) by Professor Gary Mueller.

Graphene-based copper oxide thin film nanostructures as high-efficiency photocathode for p-type dye-sensitized solar cells

Science.gov (United States)

Kilic, Bayram; Turkdogan, Sunay; Astam, Aykut; Baran, Sümeyra Seniha; Asgin, Mansur; Cebeci, Hulya; Urk, Deniz

2017-10-01

Graphene-based p-type dye-sensitized solar cells (p-DSSCs) have been proposed and fabricated using copper oxide urchin-like nanostructures (COUN) as photocathode with an FeS2 counter electrode (CE). COUN composed of Cu2O core sphere and CuO shell nanorods with overall diameters of 2 to 4 μm were grown by a simple hydrothermal method with self-assemble nucleation. It was figured out that the formation of copper oxide core/shell structures could be adjusted by an ammonia additive leading to pH change of the precursor solution. In addition to a photocathode, we also demonstrated FeS2 thin films as an efficient CE material alternative to the conventional Pt CEs in DSSCs. FeS2 nanostructures, with diameters of 50 to 80 nm, were synthesized by a similar hydrothermal approach. FeS2 nanostructures are demonstrated to be an outstanding CE material in p-DSSCs. We report graphene/COUN as photocathode and Pt/FeS2 as CE in p-DSSCs, and results show that the synergetic combination of electrodes in each side (increased interconnectivity between COUN and graphene layer, high surface area, and high catalytic activity of FeS2) increased the power conversion efficiency from 1.56% to 3.14%. The excellent performances of COUN and FeS2 thin film in working and CEs, respectively, make them unique choices among the various photocathode and CE materials studied.

High-voltage electron-microscope investigation of point-defect agglomerates in irradiated copper during in-situ annealing

International Nuclear Information System (INIS)

Jaeger, W.; Urban, K.; Frank, W.

1980-01-01

Thin copper foils were irradiated with 650 keV electrons at 10 K in a high-voltage electron microscope (HVEM) to doses phi in the range 2 x 10 23 electrons/m 2 approximately 25 electrons /m 2 and then annealed in situ up to room temperature and outside the HVEM between room temperature and 470 K. During irradiation visible defect clusters were formed only at phi >= 2.5 x 10 24 electrons/m 2 . At smaller doses defect clusters became visible after annealing at 50 K. Between 50 K and 120 K further clusters, mainly dislocation loops on brace111 planes, appeared. Above 120 K, particularly between 160 K and 300 K, some of the dislocation loops became glissile. They glided out of the specimens or agglomerated to larger clusters of frequently complex shapes. As a consequence between 160 K and 300 K the cluster density decreased strongly, whereas the mean cluster size increased monotonously through the entire range of annealing temperatures covered. Contrast analyses between 180 K and 400 K revealed that the great majority of the dislocation loops were of interstitial type. At 470 K a new type of small clusters emerged, presumably of vacancy type. These observations are compared with other studies on electron-irradiated copper and with the current models of radiation damage in metals. (author)

STRUCTURAL, PHOTO-FUNCTIONAL AND SEMICONDUCTOR PROPERTIES OF COPPER OXIDE THIN FILMS PREPARED BY DC REACTIVE METHOD UNDER VARIOUS THICKNESSES Anmar H. Shukur

Directory of Open Access Journals (Sweden)

Anmar H. Shukur

2018-01-01

Full Text Available Cuprous oxide (Cu2O has been formed on glass substrates by dc reactive magnetron sputtering method, whereas pure target of the solid copper was sputtered with a mixture of plasma for argon gas and oxygen gas was used to form these films. Under vacuum chamber pressure of 1.2×10-5 Pa, thin film thickness was changed from 100 nm to 300 nm while other deposition parameters were fixed. The influence of changing the thickness of thin films on the electrical and the optical properties was investigated in this study. X-ray photoelectron spectroscopy (XPS, X-ray Diffractions system XRD, Atomic Force Microscopy (AFM, hall effect measurement system, UV–VIS spectrophotometer were employed to determine the characteristic of the deposited thin films. Thin film of 200 nm has observed low resistivity of 60.63 Ω cm and direct band gap of 2.5eV. This study has demonstrated that the thickness has direct influence on electrical and optical properties.

Conformable wearable systems comprising organic electronics on foil for well being and healthcare (presentation video)

Science.gov (United States)

de Kok, Margreet M.

2014-10-01

Integration of electronics into materials and objects that have not been functionalized with electronics before, open up extensive possibilities to support mankind. By adding intelligence and/or operating power to materials in close skin contact like clothing, furniture or bandages the health of people can be monitored or even improved. Foil based electronics are interesting components to be integrated as they are thin, large area and cost effective available components Our developed technology of printed electronic structures to which components are reliably bonded, fulfills the promise. We have integrated these components into textiles and built wearable encapsulated products with foil based electronics. Foil components with organic and inorganic LEDs are interconnected and laminated onto electronic textiles by using conductive adhesives to bond the contact pads of the component to conductive yarns in the textile. Modelling and reliability testing under dynamic circumstances provided important insights in order to optimise the technology. The design of the interconnection and choice of conductive adhesive / underfill and lamination contributed to the durability of the system. Transition zones from laminated foil to textile are engineered to withstand dynamic use. As an example of a product, we have realized an electronic wristband that is encapsulated in rubber and has a number of sensor functionalities integrated on stretchable electronic circuits based on Cu and Ag. The encapsulation with silicone or polyurethanes was performed such, that charging and sensor/skin contacts are possible while simultaneously protecting the electronics from mechanical and environmental stresses.

Part 1, Angular distribution measurement of beam-foil muonium, Part 2, Muon injection simulation for a new muon g-2 experiment

International Nuclear Information System (INIS)

Ahn, H.E.

1992-10-01

The angular and energy distributions of positive muons μ + and muonium M produced by the beam-foil method have been measured for the first time. A 7 MeV/c subsurface μ + beam was delivered to our apparatus from the Stopped Muon Channel at the Los Alamos Clinton P. Anderson Meson Physics Facility (LAMPF). The μ + formed M by electron capture in a thin Al target foil. A low pressure multi-wire proportional chamber upstream of the target foil was used both as a moderator and as a muon counter. To observe muonium, muons sere swept away by a bending magnet which was placed downstream of the target foil. This magnet was turned off while measuring the μ + distribution. Beyond the magnetic field, particles were collimated and then stopped by a microchannel plate detector located at various angles to the incident muon beam axis. Two pairs of scintillators mounted above (St) and below (Sb) the MC-P were used to detect the decay positrons to verify from the lifetime spectrum that the particles detected by the MCP are muons. The intensities of μ + and M emerging from the Al foil at different angles were obtained from both a time-of-flight spectrum and a lifetime spectrum

Carbon stripper foils held in place with carbon fibers

International Nuclear Information System (INIS)

Jolivet, Connie S.; Miller, Shawn A.; Stoner, John O.; Ladd, Peter

2008-01-01

The Spallation Neutron Source (SNS) currently under construction at Oak Ridge National Laboratory, Oak Ridge, Tennessee, is planned to initially utilize carbon stripper foils having areal densities approximately 260 μg/cm 2 . The projected design requires that each foil be supported by only one fixed edge. For stability of the foil, additional support is to be provided by carbon fibers. The feasibility of manufacturing and shipping such mounted carbon foils produced by arc evaporation was studied using two prototypes. Production of the foils is described. Fibers were chosen for satisfactory mechanical strength consistent with minimal interference with the SNS beam. Mounting of the fibers, and packaging of the assemblies for shipping are described. Ten completed assemblies were shipped to SNS for further testing. Preliminary evaluation of the survivability of the foils in the SNS foil changer is described

Obtention of thin depositions by the vacuum evaporation technique

International Nuclear Information System (INIS)

Gonzalez Mateu, D.; Labrada, A.; Voronin, A.

1991-01-01

The vacuum evaporating technique used to prepare thin depositions, and the technical characteristics of the constructed installation are described. 235 U y 238 U nuclear target for the fission researches were obtained. Aluminium and gold self-supporting foils were obtained too

Copper-vapor-catalyzed chemical vapor deposition of graphene on dielectric substrates

Science.gov (United States)

Yang, Chao; Wu, Tianru; Wang, Haomin; Zhang, Xuefu; Shi, Zhiyuan; Xie, Xiaoming

2017-07-01

Direct synthesis of high-quality graphene on dielectric substrates is important for its application in electronics. In this work, we report the process of copper-vapor-catalyzed chemical vapor deposition of high-quality and large graphene domains on various dielectric substrates. The copper vapor plays a vital role on the growth of transfer-free graphene. Both single-crystal domains that are much larger than previous reports and high-coverage graphene films can be obtained by adjusting the growth duration. The quality of the obtained graphene was verified to be comparable with that of graphene grown on Cu foil. The progress reported in this work will aid the development of the application of transfer-free graphene in the future.

Dark-field study of rear-side density structure in laser-accelerated foils

International Nuclear Information System (INIS)

Stamper, J.A.; Gold, S.H.; Obenschain, S.P.; McLean, E.A.; Sica, L.

1981-01-01

A dark-field, laser-probing diagnostic has produced the first high-resolution photographs of density structure on the rear side of laser-accelerated foils. This diagnostic allows the preferential sampling of the steep-gradient region of an expanding plasma and permits two-dimensional, multiple-time recordings on a single photograph. The studies are aimed at understanding the early-time physics of target implosions for inertial-confinement fusion. Both long (500 psec) and short (150 psec) probe pulses were used to study the rear-side plasmas of thin foils accelerated by the rocket-like reaction to a hot plasma ablated from the front side by the laser radiation. The longer pulse results, both for angular scatter and the life-time of small, transverse structure, imply a relatively cold (1 eV) rear side plasma. The short pulses provide high resolution photographs of the complete structure. One of these was a vortex-like structure, suggestive of the remnants of a hydrodynamic instability. These observations are relevant to two of the basic requirements of inertial-confinement fusion: cold fuel isentrope and implosion symmetry

Q-switch Nd:YAG laser welding of AISI 304 stainless steel foils

Energy Technology Data Exchange (ETDEWEB)

P' ng, Danny [Laboratory for Lasers, MEMS and Nanotechnology, Department of Mechanical Engineering, Iowa State University, Ames, IA 50011-2161 (United States); Molian, Pal [Laboratory for Lasers, MEMS and Nanotechnology, Department of Mechanical Engineering, Iowa State University, Ames, IA 50011-2161 (United States)], E-mail: molian@iastate.edu

2008-07-15

Conventional fusion welding of stainless steel foils (<100 {mu}m thickness) used in computer disk, precision machinery and medical device applications suffer from excessive distortion, formation of discontinuities (pore, void and hot crack), uncontrolled melting (melt-drop through) and poor aesthetics. In this work, a 15 ns pulsed, 400 mJ Nd:YAG laser beam was utilized to overcome these barriers in seam welding of 60 {mu}m thin foil of AISI 304 stainless steel. Transmission electron microscopy was used to characterize the microstructures while hardness and tensile-shear tests were used to evaluate the strengths. Surface roughness was measured using a DekTak profilometer while porosity content was estimated using the light microscope. Results were compared against the data obtained from resistance seam welding. Laser welding, compared to resistance seam welding, required nearly three times less heat input and produced welds having 50% narrower seam, 15% less porosity, 25% stronger and improved surface aesthetics. In addition, there was no evidence of {delta}-ferrite in laser welds, supporting the absence of hot cracking unlike resistance welding.

SMA Foils for MEMS: From Material Properties to the Engineering of Microdevices

Science.gov (United States)

Kohl, Manfred; Ossmer, Hinnerk; Gueltig, Marcel; Megnin, Christof

2018-03-01

In the early nineties, microelectromechanical systems (MEMS) technology has been still in its infancy. As silicon (Si) is not a transducer material, it was clear at the very beginning that mechanically active materials had to be introduced to MEMS in order to enable functional microdevices with actuation capability beyond electrostatics. At that time, shape memory alloys (SMAs) have been available in bulk form, mainly as SMA wires and SMA plates. On the macro scale, these materials show highest work densities compared to other actuation principles in the order of 107 J/m3, which stimulated research on the integration of SMA to MEMS. Subsequently, two approaches for producing planar materials have been initiated (1) magnetron sputtering of SMA thin films and (2) the integration of rolled SMA foils, which both turned out to be very successful creating a paradigm change in microactuation technology. The following review covers important milestones of the research and development of SMA foil-based microactuators including materials characterization, design engineering, technology, and demonstrator development as well as first commercial products.

SMA Foils for MEMS: From Material Properties to the Engineering of Microdevices

Science.gov (United States)

Kohl, Manfred; Ossmer, Hinnerk; Gueltig, Marcel; Megnin, Christof

2017-12-01

In the early nineties, microelectromechanical systems (MEMS) technology has been still in its infancy. As silicon (Si) is not a transducer material, it was clear at the very beginning that mechanically active materials had to be introduced to MEMS in order to enable functional microdevices with actuation capability beyond electrostatics. At that time, shape memory alloys (SMAs) have been available in bulk form, mainly as SMA wires and SMA plates. On the macro scale, these materials show highest work densities compared to other actuation principles in the order of 107 J/m3, which stimulated research on the integration of SMA to MEMS. Subsequently, two approaches for producing planar materials have been initiated (1) magnetron sputtering of SMA thin films and (2) the integration of rolled SMA foils, which both turned out to be very successful creating a paradigm change in microactuation technology. The following review covers important milestones of the research and development of SMA foil-based microactuators including materials characterization, design engineering, technology, and demonstrator development as well as first commercial products.

Flexible CIGS solar cells on large area polymer foils with in-line deposition methods and application of alternative back contacts - Final report

Energy Technology Data Exchange (ETDEWEB)

Tiwari, A. N.

2009-08-15

This illustrated report for the Swiss Federal Office of Energy (SFOE) summarises the work performed within this project and also reports on synergies with other projects that helped to make a significant contribution to the development of CIGS thin film solar cells on flexible substrates such as polymer foils. The project's aims were to learn more about up-scaling issues and to demonstrate the abilities required for the processing of layers on large area polyimide foils for flexible CIGS solar cells. Custom-built evaporators that were designed and constructed in-house are described. A CIGS system for in-line deposition was also modified for roll-to-roll deposition and alternative electrical back contacts to conventional ones were evaluated on flexible polyimide foils. The objectives of the project and the results obtained are looked at and commented on in detail.

Microfabricated Segmented-Involute-Foil Regenerator for Stirling Engines

Science.gov (United States)

Ibrahim, Mounir; Danila, Daniel; Simon, Terrence; Mantell, Susan; Sun, Liyong; Gedeon, David; Qiu, Songgang; Wood, Gary; Kelly, Kevin; McLean, Jeffrey

2010-01-01

An involute-foil regenerator was designed, microfabricated, and tested in an oscillating-flow test rig. The concept consists of stacked involute-foil nickel disks (see figure) microfabricated via a lithographic process. Test results yielded a performance of about twice that of the 90-percent random-fiber currently used in small Stirling converters. The segmented nature of the involute- foil in both the axial and radial directions increases the strength of the structure relative to wrapped foils. In addition, relative to random-fiber regenerators, the involute-foil has a reduced pressure drop, and is expected to be less susceptible to the release of metal fragments into the working space, thus increasing reliability. The prototype nickel involute-foil regenerator was adequate for testing in an engine with a 650 C hot-end temperature. This is lower than that required by larger engines, and high-temperature alloys are not suited for the lithographic microfabrication approach.

Properties of polymer foils used as solid-state track detectors

International Nuclear Information System (INIS)

Spurny, F.

1973-05-01

Polymer foils were studied with a view to their application as solid-state alpha track detectors. The detection efficiency was determined as was its alpha energy dependence and the quality of the surface and the natural background of the foils were evaluated. The kinetics of etching was studied in three selected type of foils. Characteristic constants for the selected foils and methods of etching were calculated. The possible applications of the foils as track detectors are discussed and the effect is dealt with of the selected foil and of the method of chemical etching on the foil applicability in nuclear sciences, especially in fast neutron dosimetry and in alpha spectrometry. (author)

Corrosion and biofouling resistance evaluation of 90-10 copper-nickel

Energy Technology Data Exchange (ETDEWEB)

Powell, Carol [Consultant to Copper Development Association, UK, Square Covert, Caynham, Ludlow, Shropshire (United Kingdom)

2004-07-01

Copper-nickel alloys for marine use were developed for naval applications in the early part of the 20. century with a view to improving the corrosion resistance of condenser tubes and seawater piping. They still enjoy widespread use today not only for many navies but also in commercial shipping, floating production, storage and off loading vessels (FPSOs), and in multistage flash desalination. The two popular alloys contain 90% or 70% copper and differ in strength and maximum sea water velocity levels they can handle but it is the 90-10 copper-nickel (CuNi10Fe1Mn) which is the more economic and extensively used. An additional benefit of this alloy is its high resistance to biofouling: in recent years this has led to sheathing developments particularly for structures and boat hulls. This paper provides a review of the corrosion and biofouling resistance of 90-10 copper-nickel based on laboratory test data and documented experience of the alloy in marine environments. Particular attention is given to exposure trials over 8 years in Langstone Harbour, UK, which have recently been completed by Portsmouth University on behalf of the Nickel Institute. These examined four sheathing products; plate and foil as well as two composite products with rubber backing. The latter involved copper-nickel granules and slit sheet. The trial results are consistent with the behaviour of the alloy in the overall review. There is an inherent high resistance to marine biofouling when freely exposed. Prolonged exposure to quiet conditions can result in some growth of marine organisms but this is loosely attached and can readily be removed by wiping or a light scraping. The good corrosion resistance of 90-10 copper-nickel in sea water is also confirmed and associated with the formation of a thin, complex, protective and predominantly cuprous oxide surface film, which forms and matures naturally on exposure to seawater. Sound initial oxide film formation is also known to help protect against

Thin Film Energy Storage Device with Spray‐Coated Sliver Paste Current Collector

Directory of Open Access Journals (Sweden)

Seong Man Yoon

2017-12-01

Full Text Available This paper challenges the fabrication of a thin film energy storage device on a flexible polymer substrate specifically by replacing most commonly used metal foil current collectors with coated current collectors. Mass‐manufacturable spray‐coating technology enables the fabrication of two different half‐cell electric double layer capacitors (EDLC with a spray‐coated silver paste current collector and a Ni foil current collector. The larger specific capacitances of the half‐cell EDLC with the spray‐coated silver current collector are obtained as 103.86 F/g and 76.8 F/g for scan rates of 10 mV/s and 500 mV/s, respectively. Further, even though the half‐cell EDLC with the spray‐coated current collector is heavier than that with the Ni foil current collector, smaller Warburg impedance and contact resistance are characterized from Nyquist plots. For the applied voltages ranging from −0.5 V to 0.5 V, the spray‐coated thin film energy storage device exhibits a better performance.

High efficiency copper indium gallium diselenide (CIGS) thin film solar cells

Science.gov (United States)

Rajanikant, Ray Jayminkumar

The generation of electrical current from the solar radiation is known as the photovoltaic effect. Solar cell, also known as photovoltaic (PV) cell, is a device that works on the principle of photovoltaic effect, and is widely used for the generation of electricity. Thin film polycrystalline solar cells based on copper indium gallium diselenide (CIGS) are admirable candidates for clean energy production with competitive prices in the near future. CIGS based polycrystalline thin film solar cells with efficiencies of 20.3 % and excellent temperature stability have already been reported at the laboratory level. The present study discusses about the fabrication of CIGS solar cell. Before the fabrication part of CIGS solar cell, a numerical simulation is carried out using One-Dimensional Analysis of Microelectronic and Photonic Structures (AMPS-ID) for understanding the physics of a solar cell device, so that an optimal structure is analyzed. In the fabrication part of CIGS solar cell, Molybdenum (Mo) thin film, which acts as a 'low' resistance metallic back contact, is deposited by RF magnetron sputtering on organically cleaned soda lime glass substrate. The major advantages for using Mo are high temperature, (greater than 600 °C), stability and inertness to CIGS layer (i.e., no diffusion of CIGS into Mo). Mo thin film is deposited at room temperature (RT) by varying the RF power and the working pressure. The Mo thin films deposited with 100 W RF power and 1 mTorr working pressure show a reflectivity of above average 50 % and the low sheet resistance of about 1 O/□. The p-type CIGS layer is deposited on Mo. Before making thin films of CIGS, a powder of CIGS material is synthesized using melt-quenching method. Thin films of CIGS are prepared by a single-stage flash evaporation process on glass substrates, initially, for optimization of deposition parameters and than on Mo coated glass substrates for device fabrication. CIGS thin film is deposited at 250 °C at a

A Microfabricated Involute-Foil Regenerator for Stirling Engines

Science.gov (United States)

Tew, Roy; Ibrahim, Mounir; Danila, Daniel; Simon, Terrence; Mantell, Susan; Sun, Liyong; Gedeon, David; Kelly, Kevin; McLean, Jeffrey; Qiu, Songgang

2007-01-01

A segmented involute-foil regenerator has been designed, microfabricated and tested in an oscillating-flow rig with excellent results. During the Phase I effort, several approximations of parallel-plate regenerator geometry were chosen as potential candidates for a new microfabrication concept. Potential manufacturers and processes were surveyed. The selected concept consisted of stacked segmented-involute-foil disks (or annular portions of disks), originally to be microfabricated from stainless-steel via the LiGA (lithography, electroplating, and molding) process and EDM. During Phase II, re-planning of the effort led to test plans based on nickel disks, microfabricated via the LiGA process, only. A stack of nickel segmented-involute-foil disks was tested in an oscillating-flow test rig. These test results yielded a performance figure of merit (roughly the ratio of heat transfer to pressure drop) of about twice that of the 90 percent random fiber currently used in small approx.100 W Stirling space-power convertors-in the Reynolds Number range of interest (50 to 100). A Phase III effort is now underway to fabricate and test a segmented-involute-foil regenerator in a Stirling convertor. Though funding limitations prevent optimization of the Stirling engine geometry for use with this regenerator, the Sage computer code will be used to help evaluate the engine test results. Previous Sage Stirling model projections have indicated that a segmented-involute-foil regenerator is capable of improving the performance of an optimized involute-foil engine by 6 to 9 percent; it is also anticipated that such involute-foil geometries will be more reliable and easier to manufacture with tight-tolerance characteristics, than random-fiber or wire-screen regenerators. Beyond the near-term Phase III regenerator fabrication and engine testing, other goals are (1) fabrication from a material suitable for high temperature Stirling operation (up to 850 C for current engines; up to 1200 C

An application of computer image-processing and filmy replica technique to the copper electroplating method of stress analysis

Science.gov (United States)

Sugiura, M.; Seika, M.

1994-02-01

In this study, a new technique to measure the density of slip-bands automatically is developed, namely, a TV image of the slip-bands observed through a microscope is directly processed by an image-processing system using a personal computer and an accurate value of the density of slip-bands is measured quickly. In the case of measuring the local stresses in machine parts of large size with the copper plating foil, the direct observation of slip-bands through an optical microscope is difficult. In this study, to facilitate a technique close to the direct microscopic observation of slip-bands in the foil attached to a large-sized specimen, the replica method using a platic film of acetyl cellulose is applied to replicate the slip-bands in the attached foil.

Compatibility of copper-electroplated cells with Metal Wrap Through module materials

Energy Technology Data Exchange (ETDEWEB)

Bennett, I.J.; Geerligs, L.J.; Olson, C.L.; Goris, M.J.A.A. [ECN Solar Energy, Petten (Netherlands)

2013-10-16

As part of the European FP7 RandD project 'Cu-PV', the compatibility of copper-electroplated metal wrapthrough (MWT) cells with conductive adhesives has been investigated. The objectives of this project include to reduce, by the use of copper plating, the amount of silver utilized in cell manufacturing, and to demonstrate the compatibility of high-power n-type back-contact module technology with copper-plated cells. The overall goal is to reduce the impact on the environment of cell and module manufacture. MWT module technology as developed by ECN uses conductive adhesive to make the interconnection between cells and a conductive backsheet foil. These adhesives have been proved to result in very reliable modules in the case of cells with fired silver metallization. To determine the compatibility of conductive adhesive with copper-plated cells, component tests were performed, followed by the manufacture of modules with copperplated cells and conductive adhesive interconnections. Climate chamber testing of these modules showed that the adhesive is compatible with the copper-plated cells. The next steps include further optimization of the plating process and additional testing at the module level.

Method for providing uranium with a protective copper coating

Science.gov (United States)

Waldrop, Forrest B.; Jones, Edward

1981-01-01

The present invention is directed to a method for providing uranium metal with a protective coating of copper. Uranium metal is subjected to a conventional cleaning operation wherein oxides and other surface contaminants are removed, followed by etching and pickling operations. The copper coating is provided by first electrodepositing a thin and relatively porous flash layer of copper on the uranium in a copper cyanide bath. The resulting copper-layered article is then heated in an air or inert atmosphere to volatilize and drive off the volatile material underlying the copper flash layer. After the heating step an adherent and essentially non-porous layer of copper is electro-deposited on the flash layer of copper to provide an adherent, multi-layer copper coating which is essentially impervious to corrosion by most gases.

Laser Welding of Silicon Foils for Thin-Film Solar Cell Manufacturing

OpenAIRE

Heßmann, Maik

2014-01-01

Thin-film solar module manufacturing is one of the most promising recent developments in photovoltaic research and has the potential to reduce production costs. As the necessity for competitive prices on the world market increases and manufacturers endeavor to bring down the cost of solar modules, thin-film technology is becoming more and more attractive. In this work a special technique was investigated which makes solar cell manufacturing more compatible with an industrial roll-to-roll proc...

Energy loss measurements of {sup 63}Cu, {sup 28}Si and {sup 27}Al heavy ions crossing thin Polyvinylchloride (PVC) foil

Energy Technology Data Exchange (ETDEWEB)

Dib, A.; Ammi, H. [Centre de Recherche Nucléaire d’Alger, 2 Bd. Frantz Fanon, B.P. 399, Alger-Gare, Algiers (Algeria); Guesmia, A., E-mail: guesmia@tlabs.ac.za [Departement de physique, Faculté des Sciences, Université Saad Dahlab, B. P. 270, Route de Soumaa, Blida (Algeria); Departement de physique, Faculté des Sciences, Université M’hamed Bougara, Boumerdes (Algeria); iThemba LABS, National Research Foundation, P.O. Box 722, Somerset West 7129 (South Africa); Msimanga, M. [Department of Physics, Arcadia Campus, Tshwane University of Technology, P. Bag X680, Pretoria (South Africa); Mammeri, S. [Centre de Recherche Nucléaire d’Alger, 2 Bd. Frantz Fanon, B.P. 399, Alger-Gare, Algiers (Algeria); Hedibel, M. [Departement de physique, Faculté des Sciences, Université M’hamed Bougara, Boumerdes (Algeria); Guedioura, B. [Centre de Recherche Nucléaire de Draria, B.P. 43, Sebala-Draria, Algiers (Algeria); Pineda-Vargas, C.A. [iThemba LABS, National Research Foundation, P.O. Box 722, Somerset West 7129 (South Africa); Faculty of Health and Wellness Sciences, CPUT, P.O. Box 1906, Bellville 7535 (South Africa)

2015-11-15

Experimental stopping data of, {sup 63}Cu, {sup 28}Si and {sup 27}Al heavy ions in thin Polyvinylchloride (H{sub 3}C{sub 2}Cl{sub 1}) foil have been obtained over the 0.045–0.50 MeV/nucleon energy range. The measured energy losses were carried out by Heavy Ion Elastic Recoil Detection Analysis (HI-ERDA) technique coupled with time of flight (ToF) spectrometer. A continuous stopping power data obtained in this work are well fitted by our proposed semi-empirical formula and the results are compared to those calculated by LSS formula or generated by SRIM-2013 and MSTAR predictions. Calculations using our formula agree well with the obtained experimental stopping powers, while the LSS formula underestimates the experimental data in the whole investigated energy range. In this work a simple expression for electronic stopping power of heavy ions at low energy in solid targets is introduced. This formula is based on the Firsov and Lindhard–Sharff stopping power models with a small modification made to the original expression, by incorporating the effective charge of moving ions concept and with exponential fit function.

Design considerations for foil windows for PET radioisotope targets

International Nuclear Information System (INIS)

Hughey, B.J.; Shefer, R.E.; Klinkowstein, R.E.; Welch, M.J.

1992-01-01

This paper describes the results of a study performed at SRL to develop analytical and computational techniques for optimizing the design of conduction-cooled foil windows for PET targets. Single foil conduction cooled windows have been found to be good target entrance windows for both low energy accelerators and medium energy cyclotrons. Detailed thermal analysis has given an approximate analytical expression for the maximum temperature reached in a foil window under conditions of realistic ion beam bombardment. The effects of 'hot spots' in the beam density profile were investigated. It was shown that a factor of two safety margin in window design should be adequate to compensate for any possible beam hot spots. In addition, the reduction of foil stress by slack mounting was verified by experiments. The properties of conventional and novel foil materials were investigated for use in conduction cooled windows. Novel foil materials include two-component Al/Ti and Al/Havar foil. Results on the testing of candidate foil materials for thermal conductivity and mechanical strength at elevated temperature were presented. Two optimum foil window geometries were analyzed: a high aspect ratio window and a multiply slotted window. The multiply slotted window combines the advantages of a high aspect ratio foil window with a circular beam strike and is a promising window design for both TCA and cyclotron targets. A multiply slotted window for a N 2 gas target for 15 O production was designed using the methodologies discussed above. This prototype target was successfully tested using the TCA beam at SRL. (author) 6 figs., 3 tabs., 10 refs

A simple method for the measurement of reflective foil emissivity

International Nuclear Information System (INIS)

Ballico, M. J.; Ham, E. W. M. van der

2013-01-01

Reflective metal foil is widely used to reduce radiative heat transfer within the roof space of buildings. Such foils are typically mass-produced by vapor-deposition of a thin metallic coating onto a variety of substrates, ranging from plastic-coated reinforced paper to 'bubble-wrap'. Although the emissivity of such surfaces is almost negligible in the thermal infrared, typically less than 0.03, an insufficiently thick metal coating, or organic contamination of the surface, can significantly increase this value. To ensure that the quality of the installed insulation is satisfactory, Australian building code AS/NZS 4201.5:1994 requires a practical agreed method for measurement of the emissivity, and the standard ASTM-E408 is implied. Unfortunately this standard is not a 'primary method' and requires the use of specified expensive apparatus and calibrated reference materials. At NMIA we have developed a simple primary technique, based on an apparatus to thermally modulate the sample and record the apparent modulation in infra-red radiance with commercially available radiation thermometers. The method achieves an absolute accuracy in the emissivity of approximately 0.004 (k=2). This paper theoretically analyses the equivalence between the thermal emissivity measured in this manner, the effective thermal emissivity in application, and the apparent emissivity measured in accordance with ASTM-E408

A simple method for the measurement of reflective foil emissivity

Science.gov (United States)

Ballico, M. J.; van der Ham, E. W. M.

2013-09-01

Reflective metal foil is widely used to reduce radiative heat transfer within the roof space of buildings. Such foils are typically mass-produced by vapor-deposition of a thin metallic coating onto a variety of substrates, ranging from plastic-coated reinforced paper to "bubble-wrap". Although the emissivity of such surfaces is almost negligible in the thermal infrared, typically less than 0.03, an insufficiently thick metal coating, or organic contamination of the surface, can significantly increase this value. To ensure that the quality of the installed insulation is satisfactory, Australian building code AS/NZS 4201.5:1994 requires a practical agreed method for measurement of the emissivity, and the standard ASTM-E408 is implied. Unfortunately this standard is not a "primary method" and requires the use of specified expensive apparatus and calibrated reference materials. At NMIA we have developed a simple primary technique, based on an apparatus to thermally modulate the sample and record the apparent modulation in infra-red radiance with commercially available radiation thermometers. The method achieves an absolute accuracy in the emissivity of approximately 0.004 (k=2). This paper theoretically analyses the equivalence between the thermal emissivity measured in this manner, the effective thermal emissivity in application, and the apparent emissivity measured in accordance with ASTM-E408.

Auger electron and X-ray photoelectron spectroscopic study of the biocorrosion of copper by alginic acid polysaccharide

Science.gov (United States)

Jolley, John G.; Geesey, Gill G.; Hankins, Michael R.; Wright, Randy B.; Wichlacz, Paul L.

1989-08-01

Thin films (3.4 nm) of copper on germanium substrates were exposed to 2% alginic acid polysaccharide aqueous solution. Pre- and post-exposure characterization were done by Auger electron spectroscopy and X-ray photoelectron spectroscopy. Ancillary graphite furnace atomic absorption spectroscopy was used to monitor the removal process of the copper thin film from the germanium substrate. Results indicate that some of the copper was oxidized by the alginic acid solution. Some of the copper was removed from the Cu/Ge interface and incorporated into the polymer matrix. Thus, biocorrosion of copper was exhibited by the alginic acid polysaccharide.

Actinide Foil Production for MPACT Research

Energy Technology Data Exchange (ETDEWEB)

Beller, Denis

2012-10-30

or UO2 in extremely thin layers (1 to 2 mg/cm2) on various media such as films, foils, or discs. After many months of investigation and trials in FY10 and 11, UNLV researchers developed a new method to produce pure UO2 deposits on foils using a unique approach, which has never been demonstrated, that involves dissolution of U3O8 directly into room temperature ionic liquid (RTIL) followed by electrodeposition from the RTIL-uDU solution (Th deposition from RTIL had been previously demonstrated). The high-purity dissolution of the U3O8 permits the use of RTIL solutions for deposition of U on metal foils in layers without introducing contamination. In FY10 and early FY11 a natural U surrogate for the uDU was used to investigate this and other techniques. In this research project UNLV will deposit directly from RTIL to produce uDU and Th foils devoid of possible contaminants. After these layers have been deposited, they will be examined for purity and uniformity. UNLV will complete the development and demonstration of the RTIL technology/ methodology to prepare uDU and Th samples for use in constructing fast-neutron detectors. Although this material was purchased for use in research using fast-fission chamber detectors for active inspection techniques for MPACT, it could also contribute to R&D for other applications, such as cross section measurements or neutron spectroscopy for national security

Reversible and nonvolatile ferroelectric control of two-dimensional electronic transport properties of ZrCuSiAs-type copper oxyselenide thin films with a layered structure

Science.gov (United States)

Zhao, Xu-Wen; Gao, Guan-Yin; Yan, Jian-Min; Chen, Lei; Xu, Meng; Zhao, Wei-Yao; Xu, Zhi-Xue; Guo, Lei; Liu, Yu-Kuai; Li, Xiao-Guang; Wang, Yu; Zheng, Ren-Kui

2018-05-01

Copper-based ZrCuSiAs-type compounds of LnCuChO (Ln =Bi and lanthanides, Ch =S , Se, Te) with a layered crystal structure continuously attract worldwide attention in recent years. Although their high-temperature (T ≥ 300 K) electrical properties have been intensively studied, their low-temperature electronic transport properties are little known. In this paper, we report the integration of ZrCuSiAs-type copper oxyselenide thin films of B i0.94P b0.06CuSeO (BPCSO) with perovskite-type ferroelectric Pb (M g1 /3N b2 /3 ) O3-PbTi O3 (PMN-PT) single crystals in the form of ferroelectric field effect devices that allow us to control the electronic properties (e.g., carrier density, magnetoconductance, dephasing length, etc.) of BPCSO films in a reversible and nonvolatile manner by polarization switching at room temperature. Combining ferroelectric gating and magnetotransport measurements with the Hikami-Larkin-Nagaoka theory, we demonstrate two-dimensional (2D) electronic transport characteristics and weak antilocalization effect as well as strong carrier-density-mediated competition between weak antilocalization and weak localization in BPCSO films. Our results show that ferroelectric gating using PMN-PT provides an effective and convenient approach to probe the carrier-density-related 2D electronic transport properties of ZrCuSiAs-type copper oxyselenide thin films.

Multilayer TiC/TiN diffusion barrier films for copper

International Nuclear Information System (INIS)

Yoganand, S.N.; Raghuveer, M.S.; Jagannadham, K.; Wu, L.; Karoui, A.; Rozgonyi, G.

2002-01-01

TiC/TiN thin films deposited by reactive magnetron sputtering on Si (100) substrates were investigated by transmission electron microscopy for microstructure and by deep level transient spectroscopy (DLTS) for diffusion barrier against copper. TiN thin films deposited on Si substrates at a substrate temperature of 600 deg. C were textured, and TiC thin films deposited at the same temperature were polycrystalline. TiC/TiN multilayer films also showed the same characteristics with the formation of an additional interaction layer. The diffusion barrier characteristics of the TiC/TiN/Si were determined by DLTS and the results showed that the films completely prevented diffusion of copper into Si

Stripping foils for the PSB H- injection system

CERN Document Server

Aiba, M; Goddard, B; Weterings, W

2009-01-01

Beam physics considerations for the stripping foil of the PSB H- injection system are described, including the arguments for the foil type, thickness, geometry and positioning. The foil performance considerations are described, including expected stripping efficiency, emittance growth, energy straggling, temperature and lifetime. The required movement ranges and tolerances are detailed, together with the assumptions used.

Capillary self-alignment of mesoscopic foil components for sensor-systems-in-foil

International Nuclear Information System (INIS)

Arutinov, Gari; Smits, Edsger C P; Van Heck, Gert; Van den Brand, Jeroen; Schoo, Herman F M; Mastrangeli, Massimo; Dietzel, Andreas

2012-01-01

This paper reports on the effective use of capillary self-alignment for low-cost and time-efficient assembly of heterogeneous foil components into a smart electronic identification label. Particularly, we demonstrate the accurate (better than 50 µm) alignment of cm-sized functional foil dies. We investigated the role played by the assembly liquid, by the size and the weight of assembling dies and by their initial offsets in the self-alignment performance. It was shown that there is a definite range of initial offsets allowing dies to align with high accuracy and within approximately the same time window, irrespective of their initial offset. (paper)

Decomposition of poly(amide-imide) film enameled on solid copper wire using atmospheric pressure non-equilibrium plasma.

Science.gov (United States)

Sugiyama, Kazuo; Suzuki, Katsunori; Kuwasima, Shusuke; Aoki, Yosuke; Yajima, Tatsuhiko

2009-01-01

The decomposition of a poly(amide-imide) thin film coated on a solid copper wire was attempted using atmospheric pressure non-equilibrium plasma. The plasma was produced by applying microwave power to an electrically conductive material in a gas mixture of argon, oxygen, and hydrogen. The poly(amide-imide) thin film was easily decomposed by argon-oxygen mixed gas plasma and an oxidized copper surface was obtained. The reduction of the oxidized surface with argon-hydrogen mixed gas plasma rapidly yielded a metallic copper surface. A continuous plasma heat-treatment process using a combination of both the argon-oxygen plasma and argon-hydrogen plasma was found to be suitable for the decomposition of the poly(amide-imide) thin film coated on the solid copper wire.

Effect of self purification on the structural optical and electrical properties of copper doped oxidized Zn films

International Nuclear Information System (INIS)

Koshy, Obey; Abdul Khadar, M.

2015-01-01

The effect of self purification mechanism is studied on oxidized Cu–Zn thin films. Oxidized Cu–Zn thin films were prepared by thermal evaporation on glass substrates. XRD studies indicate that the oxidized Cu–Zn thin films are of hexagonal wurtzite structure. AFM images shows that with increase in copper wt. percent the nanoparticle morphology of oxidized Zn film turned to one dimensional nanorod morphology. XPS spectra of the oxidized Cu–Zn thin films shows the oxidized state of zinc and copper. The PL spectra of oxidized Zn film showed a strong and narrow near band edge emission at 380 nm whereas in the case of oxidized Cu–Zn thin films the emission showed peak near 410 nm corresponding to peak related to copper. With increase in copper content, the intensity of the defect emission decreased due to the self purification mechanism in nanomaterials. In addition the resistivity of doped films increased due to the self purification mechanism in nanomaterials. - Highlights: • Copper doping in ZnO resulted in the increase in blue emission due to defect levels formed. • The intensity of the luminescence peak of the doped film sample decreased and resistivity increased due to the self purification mechanism in nanomaterials.

Practical and research aspects of beam-foil spectroscopy

International Nuclear Information System (INIS)

Bashkin, S.

1975-01-01

The application of a heavy-ion accelerator to research in beam-foil spectroscopy requires certain capital equipment which is somewhat unorthodox when viewed from the standpoint of conventional, low-energy nuclear physics. It is necessary that people who wish to expand their accelerator work to include beam-foil studies understand the nature and cost of such major apparatus. We will survey the equipment needs, starting with the particle analyzer at the output of the accelerator and including the equipment used in a variety of beam-foil experiments. Electronic and computer devices will not be discussed since they are essentially identical with those employed in nuclear studies. Considerable attention will be given to optical spectrometers and spectographs including simple instruments which might be used by a laboratory just getting started in beam-foil research, or which has limited financial resources. Attention will be given to the production and use of the exciter foils. We will then discuss some typical beam-foil experiments having to do with the excitation, detection, and analysis of spectral lines from electronic levels in multiply-ionized atoms, and also with the measurement of the mean lives of such levels. Finally, we will review some of the special properties of the beam-foil light source as regards the population of the magnetic sub-states of a given level. Recent work on the character of the emitted light will be presented. That work will deal specifically with the origin of the polarization of the light. The relevant experiments involve varying the angle between the plane of the exciter foil and the particle velocity. (author)

Design of Faraday cup ion detectors built by thin film deposition

Energy Technology Data Exchange (ETDEWEB)

Szalkowski, G.A., E-mail: gszalkowski3@gatech.edu [Department of Nuclear Engineering, Georgia Institute of Technology, 770 State St., Atlanta, GA 30332 (United States); Darrow, D.S., E-mail: ddarrow@pppl.gov [Princeton Plasma Physics Laboratory, P. O. Box 451, Princeton, NJ 08543 (United States); Cecil, F.E., E-mail: fcecil@mines.edu [Department of Physics, Colorado School of Mines, Golden, CO 80401 (United States)

2017-03-11

Thin film Faraday cup detectors can provide measurements of fast ion loss from magnetically confined fusion plasmas. These multilayer detectors can resolve the energy distribution of the lost ions in addition to giving the total loss rate. Prior detectors were assembled from discrete foils and insulating sheets. Outlined here is a design methodology for creating detectors using thin film deposition that are suited to particular scientific goals. The intention is to use detectors created by this method on the Joint European Torus (JET) and the National Spherical Torus Experiment-Upgrade (NSTX-U). The detectors will consist of alternating layers of aluminum and silicon dioxide, with layer thicknesses chosen to isolate energies of interest. Thin film deposition offers the advantage of relatively simple and more mechanically robust construction compared to other methods, as well as allowing precise control of film thickness. Furthermore, this depositional fabrication technique places the layers in intimate thermal contact, providing for three-dimensional conduction and dissipation of the ion-produced heating in the layers, rather than the essentially two-dimensional heat conduction in the discrete foil stack implementation.

Highly efficient growth of vertically aligned carbon nanotubes on Fe-Ni based metal alloy foils for supercapacitors

Science.gov (United States)

Amalina Raja Seman, Raja Noor; Asyadi Azam, Mohd; Ambri Mohamed, Mohd

2016-12-01

Supercapacitors are highly promising energy devices with superior charge storage performance and a long lifecycle. Construction of the supercapacitor cell, especially electrode fabrication, is critical to ensure good performance in applications. This work demonstrates direct growth of vertically aligned carbon nanotubes (CNTs) on Fe-Ni based metal alloy foils, namely SUS 310S, Inconel 600 and YEF 50, and their use in symmetric vertically aligned CNT supercapacitor electrodes. Alumina and cobalt thin film catalysts were deposited onto the foils, and then CNT growth was performed using alcohol catalytic chemical vapour deposition. By this method, vertically aligned CNTs were successfully grown and used directly as a binder-free supercapacitor electrode to deliver excellent electrochemical performance. The device showed relatively good specific capacitance, a superior rate capability and excellent cycle stability, maintaining about 96% capacitance up to 1000 cycles.

A Manganin Thin Film Ultra-High Pressure Sensor for Microscale Detonation Pressure Measurement

Directory of Open Access Journals (Sweden)

Guodong Zhang

2018-03-01

Full Text Available With the development of energetic materials (EMs and microelectromechanical systems (MEMS initiating explosive devices, the measurement of detonation pressure generated by EMs in the microscale has become a pressing need. This paper develops a manganin thin film ultra-high pressure sensor based on MEMS technology for measuring the output pressure from micro-detonator. A reliable coefficient is proposed for designing the sensor’s sensitive element better. The sensor employs sandwich structure: the substrate uses a 0.5 mm thick alumina ceramic, the manganin sensitive element with a size of 0.2 mm × 0.1 mm × 2 μm and copper electrodes of 2 μm thick are sputtered sequentially on the substrate, and a 25 μm thick insulating layer of polyimide is wrapped on the sensitive element. The static test shows that the piezoresistive coefficient of manganin thin film is 0.0125 GPa−1. The dynamic experiment indicates that the detonation pressure of micro-detonator is 12.66 GPa, and the response time of the sensor is 37 ns. In a word, the sensor developed in this study is suitable for measuring ultra-high pressure in microscale and has a shorter response time than that of foil-like manganin gauges. Simultaneously, this study could be beneficial to research on ultra-high-pressure sensors with smaller size.

Superior light trapping in thin film silicon solar cells through nano imprint lithography

Energy Technology Data Exchange (ETDEWEB)

Soppe, W.J.; Dorenkamper, M.S.; Schropp, R.E.I.; Pex, P.P.A.C.

2013-10-15

ECN and partners have developed a fabrication process based on nanoimprint lithography (NIL) of textures for light trapping in thin film solar cells such as thin-film silicon, OPV, CIGS and CdTe. The process can be applied in roll-to-roll mode when using a foil substrate or in roll-to-plate mode when using a glass substrate. The lacquer also serves as an electrically insulating layer for cells if steel foil is used as substrate, to enable monolithic series interconnection. In this paper we will show the superior light trapping in thin film silicon solar cells made on steel foil with nanotextured back contacts. We have made single junction a-Si and {mu}c-Si and a-Si/{mu}c-Si tandem cells, where we applied several types of nano-imprints with random and periodic structures. We will show that the nano-imprinted back contact enables more than 30% increase of current in comparison with non-textured back contacts and that optimized periodic textures outperform state-of-the-art random textures. For a-Si cells we obtained Jsc of 18 mA/cm{sup 2} and for {mu}c-Si cells more than 24 mA/cm{sup 2}. Tandem cells with a total Si absorber layer thickness of only 1350 nm have an initial efficiency of 11%.

Hybrid-type long-lived carbon stripper foils

International Nuclear Information System (INIS)

Sugai, Isao; Kato, Hajime

1989-01-01

A new method for the preparation of hybrid-type long-lived carbon stripper foils was developed. The new procedure is based on a modification of our controlled dc arc-discharge method. The carbon foils are of the multilayer type and the layers are composed of carbon particles emitted from the electrodes in the ac arc-discharge and from the cathode in the dc arc-discharge. With this simple and powerful method long lived carbon stripper foils can be prepared with higher reliability and reproducibility than with the previous procedure. (orig.)

Thin-film solar cells

International Nuclear Information System (INIS)

Aberle, Armin G.

2009-01-01

The rapid progress that is being made with inorganic thin-film photovoltaic (PV) technologies, both in the laboratory and in industry, is reviewed. While amorphous silicon based PV modules have been around for more than 20 years, recent industrial developments include the first polycrystalline silicon thin-film solar cells on glass and the first tandem solar cells based on stacks of amorphous and microcrystalline silicon films ('micromorph cells'). Significant thin-film PV production levels are also being set up for cadmium telluride and copper indium diselenide.

Beam-foil lifetimes of highly ionized silicon

International Nuclear Information System (INIS)

Traebert, E.; Heckmann, P.H.; Buttlar, H. v.

1977-01-01

Electronically excited states of Si ions are created by passing a 20 MeV Si 5+ beam through a thin carbon foil. The EUV-radiation (lambda = 13-61 nm) emitted by the beam is analyzed using a grazing-incidence spectrometer. From the decay curves, lifetimes of 24 low lying levels in Si VIII to Si XII and of the 4f and 5g levels of Si XI and Si XII are derived. Cascades from doubly excited states turn out to be an important contribution to the radiation observed. The lifetime values of this work are compared to theoretical data mainly of Wiese, Sinanoglu and Dankwort/Trefftz. Most experimental values agree with at least one of the theoretical values. The decay time 560 ps of the 2s2p 3 3 D 0 3 state of Si IX is clearly longer than the theoretical prediction (highest value 455 ps by Sinanoglu). (orig.) [de

Comparative study of the mechanical properties of nanostructured thin films on stretchable substrates

Energy Technology Data Exchange (ETDEWEB)

Djaziri, S. [Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Straße 1, 40237 Düsseldorf (Germany); Institut P' (UPR 3346 CNRS), Université de Poitiers, ENSMA, Bd Pierre et Marie Curie, 86962 Futuroscope Cedex (France); Renault, P.-O.; Le Bourhis, E.; Goudeau, Ph., E-mail: Philippe.goudeau@univ-poitiers.fr [Institut P' (UPR 3346 CNRS), Université de Poitiers, ENSMA, Bd Pierre et Marie Curie, 86962 Futuroscope Cedex (France); Faurie, D. [LSPM, (UPR 3407 CNRS), Université Paris 13, Institut Galilée, 99 avenue Jean-Baptiste Clément, 93430 Villetaneuse (France); Geandier, G. [Institut Jean Lamour (UMR 3079 CNRS), Université de Lorraine, Parc de Saurupt, CS 50840, 54011 NANCY Cedex (France); Mocuta, C.; Thiaudière, D. [Synchrotron SOLEIL, L' Orme des Merisiers, Saint-Aubin, BP 48, 91192 Gif-sur-Yvette Cedex (France)

2014-09-07

Comparative studies of the mechanical behavior between copper, tungsten, and W/Cu nanocomposite based on copper dispersoïd thin films were performed under in-situ controlled tensile equi-biaxial loadings using both synchrotron X-ray diffraction and digital image correlation techniques. The films first deform elastically with the lattice strain equal to the true strain given by digital image correlation measurements. The Cu single thin film intrinsic elastic limit of 0.27% is determined below the apparent elastic limit of W and W/Cu nanocomposite thin films, 0.30% and 0.49%, respectively. This difference is found to be driven by the existence of as-deposited residual stresses. Above the elastic limit on the lattice strain-true strain curves, we discriminate two different behaviors presumably footprints of plasticity and fracture. The Cu thin film shows a large transition domain (0.60% true strain range) to a plateau with a smooth evolution of the curve which is associated to peak broadening. In contrast, W and W/Cu nanocomposite thin films show a less smooth and reduced transition domain (0.30% true strain range) to a plateau with no peak broadening. These observations indicate that copper thin film shows some ductility while tungsten/copper nanocomposites thin films are brittle. Fracture resistance of W/Cu nanocomposite thin film is improved thanks to the high compressive residual stress and the elimination of the metastable β-W phase.

BANGERTER FOILS IN THE POSTOPERATIVE MANAGEMENT OF ESOTROPIA.

Directory of Open Access Journals (Sweden)

Galina G. Dimitrova

2014-12-01

Full Text Available Purpose: To evaluate the application of Bangerter foils in the postoperative management of esotropia Methods: A retrospective study of 200 patients who underwent bimedial recessions for various forms of alternating/alternated esotropia in the period of 2000-2013. In the cases of residual postoperative angle, tendency of recurrence of strabismus and preferred fixation, Bangerter foil was fixed on the corrective glass of the dominant eye- either on the next day of surgery, or on the 10-th postoperative day and was in use for at least 6 months. Results: Bangerter foils were applied in 67(35,1% under corrected patients with a mean residual angle for near 7,01±3,51Δ. Mean residual angle in patients without foils was 3,47±4,06Δ (p<0,001. Statistically significant factors in patients with filters were amblyopia treatment before surgery (p<0,001, anisometropia (p=0,003 and type of esotropia (accommodative vs. non accommodative (p<0,001. Within the group without filters there was a significant increase of the residual angle for near on the third (p<0,001 and sixth month (p=0,036, while within the group with foils angle was not significantly changed (p=0,325; p=0,058 with time. In the group with foils no cases with relapse of strabismus and amblyopia were recorded and even a decrease of the postoperative angle was clinically observed in some patients. Conclusion: To our experience Bangerter foils are a reliable tool in the postoperative management of undercorrected esotropia.

Analysis of Mechanical Properties for GEM Foil

CERN Document Server

Chin, Yuk Ming

2016-01-01

In view of new assembly technique of the GEM detector; in which three foils stack is stretched to get the uniform gaps among the foils. We studied the mechanical properties of the foil material. We conditioned the samples in different environments to make them extra dry and wet. As holes are the major source of the charge amplification their deformation can effect the detector performance. Therefore in our studies we also studied at which level of the stress the holes deformation is seen. These tensile and holes deformation studies can help to optimize the stress during detector assembly.

Hydrogen permeation through metallic foils

International Nuclear Information System (INIS)

Bernardi, M.I.B.; Rodrigues, J.A.

1987-01-01

The process of electrolytic permeation of hydrogen through metallic foils is studied. A double electrolytic cell, in glass, in which the two compartments of reaction are separated by a metallic foil to be studied, was built. As direct result, the hydrogen diffusion coefficient in the metal is obtained. The hydrogen diffusion coefficients in the palladium and, in austenitic stainless steels 304 and 304 L, used in the Angra-1 reactor, were obtained. Samples of stainless steels with and without welding, were used. (Author) [pt

P-type diamond stripper foils for tandem ion accelerators

International Nuclear Information System (INIS)

Phelps, A.W.; Koba, R.

1989-01-01

The authors are developing a stripper foil composed of a p-type diamond membrane. This diamond stripper foil should have a significantly longer lifetime than any conventional stripper foil material. To be useful for stripper foils, the boron-doped blue diamond films must be thinner than 0.8 μm and pore-free. Two methods are compared for their ability to achieve a high nucleation areal density on a W substrate. Some W substrates were first coated with think layer of boron (≤20 nm) in order to enhance nucleation. Other W substrates were scratched with submicron diamond particles. A schematic diagram of the stripper foil is shown. Stripper foils were created by etching away the central area of W substrates. The diamond membrane was then supported by an annulus of W. Tungsten was selected as a ring-support material because of its high electrical and thermal conductivity, relatively low thermal expansion, and proven suitability as a substrate for diamond CVD. Warping or fracture of the diamond film after substrate etch-back was investigated

Structural, optical and electrical properties of copper antimony sulfide thin films grown by a citrate-assisted single chemical bath deposition

Science.gov (United States)

Loranca-Ramos, F. E.; Diliegros-Godines, C. J.; Silva González, R.; Pal, Mou

2018-01-01

Copper antimony sulfide (CAS) has been proposed as low toxicity and earth abundant absorber materials for thin film photovoltaics due to their suitable optical band gap, high absorption coefficient and p-type electrical conductivity. The present work reports the formation of copper antimony sulfide by chemical bath deposition using sodium citrate as a complexing agent. We show that by tuning the annealing condition, one can obtain either chalcostibite or tetrahedrite phase. However, the main challenge was co-deposition of copper and antimony as ternary sulfides from a single chemical bath due to the distinct chemical behavior of these metals. The as-deposited films were subjected to several trials of thermal treatment using different temperatures and time to find the optimized annealing condition. The films were characterized by different techniques including Raman spectroscopy, X-ray diffraction (XRD), profilometer, scanning electron microscopy (SEM), UV-vis spectrophotometer, and Hall Effect measurements. The results show that the formation of chalcostibite and tetrahedrite phases is highly sensitive to annealing conditions. The electrical properties obtained for the chalcostibite films varied as the annealing temperature increases from 280 to 350 °C: hole concentration (n) = 1017-1018 cm-3, resistivity (ρ) = 1.74-2.14 Ωcm and carrier mobility (μ) = 4.7-9.26 cm2/Vseg. While for the tetrahedrite films, the electrical properties were n = 5 × 1019 cm-3, μ = 18.24 cm2/Vseg, and ρ = 5.8 × 10-3 Ωcm. A possible mechanism for the formation of ternary copper antimony sulfide has also been proposed.

Forming of electron beams from a betatron by foils scatterers

Energy Technology Data Exchange (ETDEWEB)

Kozlov, A P; Shishov, V A [N.N. Petrov Research Inst. of Oncology, Leningrad (USSR). Laboratory of High Energics

1976-12-01

The technique of forming electron beams by one scattering foil and one compensating foil is discussed. This method provides a means for producing large-size uniform dose distributions with much smaller losses in dose rate as compared with conventional beam forming by ine foil. Moreover, the energy losses involved in this process and the background of concomitant bremsstrahlung are much less. A techinque of calculation to determine approximate parameters of the compensating foils is described.

Light Barrier for Non-Foil Packaging

Science.gov (United States)

2010-12-16

foil and all-plastic materials were retorted and a second set of all-plastic packaged entrees were Microwave Sterilized on the Washington State...Copolymers for Retort Applications; SPE Polyolefins and Flexible Packaging Conference: Society of Plastics Engineers. Newtown. CT, 43pp. Thellen C...Final Scientific Report Light Barrier for Non-Foil Packaging Contract No. W911QY-08-C-0132 Final Scientific Report Contract No. W911QY-08-C-0132

Comparison of oxidation resistance of copper treated by beam-line ion implantation and plasma immersion ion implantation

International Nuclear Information System (INIS)

An Quanzhang; Li Liuhe; Hu Tao; Xin Yunchang; Fu, Ricky K.Y.; Kwok, D.T.K.; Cai Xun; Chu, Paul K.

2009-01-01

Copper which has many favorable properties such as low cost, high thermal and electrical conductivity, as well as easy fabrication and joining is one of the main materials in lead frames, interconnects, and foils in flexible circuits. Furthermore, copper is one of the best antibacterial materials. However, unlike aluminum oxide or chromium oxide, the surface copper oxide layer does not render sufficient protection against oxidation. In this work, in order to improve the surface oxidation resistance of Cu, Al and N were introduced into copper by plasma immersion ion implantation (PIII) and beam-line ion implantation (BII). The implantation fluences of Al and N were 2 x 10 17 ions cm -2 and 5 x 10 16 ions cm -2 , respectively. The implanted and untreated copper samples were oxidized in air at 260 deg. C for 1 h. The X-ray diffraction (XRD), scanning electron microscopy (SEM), as well as X-ray photoelectron spectroscopy (XPS) results indicate that both implantation methods can enhance the oxidation resistance of copper but to different extent. PIII is superior to BII in enhancing the oxidation resistance of copper. The effects and possible mechanisms are discussed.

The stripping foil test stand in the Linac4 transfer line

CERN Document Server

Weterings, W; Noulibos, R; Sillanoli, Y; van Trappen, P

2015-01-01

The 160 MeV H− beam from the Linac4 (L4) linear accelerator at CERN will be injected into the proton synchrotron booster (PSB) with a new H− charge-exchange injection system. It will include a stripping foil, to convert H− into protons by stripping off the electrons. To gain experience with these very fragile foils, prior to the installation in the PSB, and test different foil materials and thicknesses, lifetimes of the foils, the foil changing mechanism and interlocking functions, a stripping foil test stand will be installed in the L4 transfer line in 2015. This paper describes the mechanical design of the system and discusses the test possibilities and parameters.

The stripping foil test stand in the Linac4 transfer line

International Nuclear Information System (INIS)

Weterings, W.; Bracco, C.; Noulibos, R.; Sillanoli, Y.; Trappen van, P.

2015-01-01

The 160 MeV H - beam from the Linac4 (L4) linear accelerator at CERN will be injected into the proton synchrotron booster (PSB) with a new H - charge-exchange injection system. It will include a stripping foil, to convert H - into protons by stripping off the electrons. To gain experience with these very fragile foils, prior to the installation in the PSB, and test different foil materials and thicknesses, lifetimes of the foils, the foil changing mechanism and interlocking functions, a stripping foil test stand will be installed in the L4 transfer line in 2015. This paper describes the mechanical design of the system and discusses the test possibilities and parameters. (author)

Gas electron multiplier (GEM) foil test, repair and effective gain calculation

Science.gov (United States)

Tahir, Muhammad; Zubair, Muhammad; Khan, Tufail A.; Khan, Ashfaq; Malook, Asad

2018-06-01

The focus of my research is based on the gas electron multiplier (GEM) foil test, repairing and effective gain calculation of GEM detector. During my research work define procedure of GEM foil testing short-circuit, detection short-circuits in the foil. Study different ways to remove the short circuits in the foils. Set and define the GEM foil testing procedures in the open air, and with nitrogen gas. Measure the leakage current of the foil and applying different voltages with specified step size. Define the Quality Control (QC) tests and different components of GEM detectors before assembly. Calculate the effective gain of GEM detectors using 109Cd and 55Fe radioactive source.

Copper benchmark experiment at the Frascati Neutron Generator for nuclear data validation

Energy Technology Data Exchange (ETDEWEB)

Angelone, M., E-mail: maurizio.angelone@enea.it; Flammini, D.; Loreti, S.; Moro, F.; Pillon, M.; Villari, R.

2016-11-01

Highlights: • A benchmark experiment was performed using pure copper with 14 MeV neutrons. • The experiment was performed at the Frascati Neutron Generator (FNG). • Activation foils, thermoluminescent dosimeters and scintillators were used to measure reactions rates (RR), nuclear heating and neutron spectra. • The paper presents the RR measurements and the post analysis using MCNP5 and JEFF-3.1.1, JEFF-3.2 and FENDL-3.1 libraries. • C/Es are presented showing the need for deep revision of Cu cross sections. - Abstract: A neutronics benchmark experiment on a pure Copper block (dimensions 60 × 70 × 60 cm{sup 3}), aimed at testing and validating the recent nuclear data libraries for fusion applications, was performed at the 14-MeV Frascati Neutron Generator (FNG) as part of a F4E specific grant (F4E-FPA-395-01) assigned to the European Consortium on Nuclear Data and Experimental Techniques. The relevant neutronics quantities (e.g., reaction rates, neutron flux spectra, doses, etc.) were measured using different experimental techniques and the results were compared to the calculated quantities using fusion relevant nuclear data libraries. This paper focuses on the analyses carried-out by ENEA through the activation foils techniques. {sup 197}Au(n,γ){sup 198}Au, {sup 186}W(n,γ){sup 187}W, {sup 115}In(n,n′){sup 115}In, {sup 58}Ni(n,p){sup 58}Co, {sup 27}Al(n,α){sup 24}Na, {sup 93}Nb(n,2n){sup 92}Nb{sup m} activation reactions were used. The foils were placed at eight different positions along the Cu block and irradiated with 14 MeV neutrons. Activation measurements were performed by means of High Purity Germanium (HPGe) detector. Detailed simulation of the experiment was carried-out using MCNP5 Monte Carlo code and the European JEFF-3.1.1 and 3.2 nuclear cross-sections data files for neutron transport and IRDFF-v1.05 library for the reaction rates in activation foils. The calculated reaction rates (C) were compared to the experimental quantities (E) and

Controlling the Performance of P-type Cu2O/SnO Bilayer Thin-Film Transistors by Adjusting the Thickness of the Copper Oxide Layer

KAUST Repository

Al-Jawhari, Hala A.

2014-11-11

The effect of copper oxide layer thickness on the performance of Cu2O/SnO bilayer thin-film transistors was investigated. By using sputtered Cu2O films produced at an oxygen partial pressure, Opp, of 10% as the upper layer and 3% Opp SnO films as the lower layer we built a matrix of bottom-gate Cu2O/SnO bilayer thin-film transistors of different thickness. We found that the thickness of the Cu2O layer is of major importance in oxidation of the SnO layer underneath. The thicker the Cu2O layer, the more the underlying SnO layer is oxidized, and, hence, the more transistor mobility is enhanced at a specific temperature. Both device performance and the annealing temperature required could be adjusted by controlling the thickness of each layer of Cu2O/SnO bilayer thin-film transistors.

Manufacturing and characterization of magnesium alloy foils for use as anode materials in rechargeable magnesium ion batteries

Science.gov (United States)

Schloffer, Daniel; Bozorgi, Salar; Sherstnev, Pavel; Lenardt, Christian; Gollas, Bernhard

2017-11-01

The fabrication of thin foils of magnesium for use as anode material in rechargeable magnesium ion batteries is described. In order to improve its workability, the magnesium was alloyed by melting metallurgy with zinc and/or gadolinium, producing saturated solid solutions. The material was extruded to thin foils and rolled to a thickness of approximately 100 μm. The electrochemical behavior of Mg-1.63 wt% Zn, Mg-1.55 wt% Gd and Mg-1.02 wt% Zn-1.01 wt% Gd was studied in (PhMgCl)2-AlCl3/THF electrolyte by cyclic voltammetry and galvanostatic cycling in symmetrical cells. Analysis of the current-potential curves in the Tafel region and the linear region close to the equilibrium potential show almost no effect of the alloying elements on the exchange current densities (5-45 μA/cm2) and the transfer coefficients. Chemical analyses of the alloy surfaces and the electrolyte demonstrate that the alloying elements not only dissolve with the magnesium during the anodic half-cycles, but also re-deposit during the cathodic half-cycles together with the magnesium and aluminum from the electrolyte. Given the negligible corrosion rate in aprotic electrolytes under such conditions, no adverse effects of alloying elements are expected for the performance of magnesium anodes in secondary batteries.

Copper oxide thin films anchored on glass substrate by sol gel spin coating technique

Science.gov (United States)

Krishnaprabha, M.; Venu, M. Parvathy; Pattabi, Manjunatha

2018-05-01

Owing to the excellent optical, thermal, electrical and photocatalytic properties, copper oxide nanoparticles/films have found applications in optoelectronic devices like solar/photovoltaic cells, lithium ion batteries, gas sensors, catalysts, magnetic storage media etc. Copper oxide is a p-type semiconductor material having a band gap energy varying from 1.2 eV-2.1 eV. Syzygium Samarangense fruit extract was used as reducing agent to synthesize copper oxide nanostructures at room temperature from 10 mM copper sulphate pentahydrate solution. The synthesized nanostructures are deposited onto glass substrate by spin coating followed by annealing the film at 200 °C. Both the copper oxide colloid and films are characterized using UV-Vis spectroscopy, field emission scanning electron microscopy (FESEM) and energy dispersive spectroscopy (EDS) techniques. Presence of 2 peaks at 500 nm and a broad peak centered around 800 nm in the UV-Vis absorbance spectra of copper oxide colloid/films is indicative of the formation of anisotropic copper oxide nanostructures is confirmed by the FESEM images which showed the presence of triangular shaped and rod shaped particles. The rod shaped particles inside island like structures were found in unannealed films whereas the annealed films contained different shaped particles with reduced sizes. The elemental analysis using EDS spectra of copper oxide nanoparticles/films showed the presence of both copper and oxygen. Electrical properties of copper oxide nanoparticles are affected due to quantum size effect. The electrical studies carried out on both unannealed and annealed copper oxide films revealed an increase in resistivity with annealing of the films.

Electrically continuous graphene from single crystal copper verified by terahertz conductance spectroscopy and micro four-point probe

DEFF Research Database (Denmark)

Buron, Jonas Christian Due; Pizzocchero, Filippo; Jessen, Bjarke Sørensen

2014-01-01

The electrical performance of graphene synthesized by chemical vapor deposition and transferred to insulating surfaces may be compromised by extended defects, including for instance grain boundaries, cracks, wrinkles, and tears. In this study, we experimentally investigate and compare the nano......- and microscale electrical continuity of single layer graphene grown on centimeter-sized single crystal copper with that of previously studied graphene films, grown on commercially available copper foil, after transfer to SiO2 surfaces. The electrical continuity of the graphene films is analyzed using two...... for measurement of the complex conductance response in the frequency range 1-15 terahertz, covering the entire intraband conductance spectrum, and reveals that the conductance response for the graphene grown on single crystalline copper intimately follows the Drude model for a barrier-free conductor. In contrast...

Electrically continuous graphene from single crystal copper verified by terahertz conductance spectroscopy and micro four-point probe

DEFF Research Database (Denmark)

Buron, Jonas Christian Due; Pizzocchero, Filippo; Jessen, Bjarke Sørensen

2014-01-01

noninvasive conductance characterization methods: ultrabroadband terahertz time-domain spectroscopy and micro four-point probe, which probe the electrical properties of the graphene film on different length scales, 100 nm and 10 μm, respectively. Ultrabroadband terahertz time-domain spectroscopy allows......- and microscale electrical continuity of single layer graphene grown on centimeter-sized single crystal copper with that of previously studied graphene films, grown on commercially available copper foil, after transfer to SiO2 surfaces. The electrical continuity of the graphene films is analyzed using two....... Micro four-point probe resistance values measured on graphene grown on single crystalline copper in two different voltage-current configurations show close agreement with the expected distributions for a continuous 2D conductor, in contrast with previous observations on graphene grown on commercial...

Comparison of carbon stripper foils produced by ARC discharge and laser ablation

Energy Technology Data Exchange (ETDEWEB)

Ophel, T.R.; Rhode, A.; Lobanov, N.; Weisser, D.C.; Turkentine, R.; Wolf, B.; Wlliman, R.G. [Australian National Univ. Canberra, ACT (Australia). Research School of Physical Sciences and Engineering

1998-06-01

The present work describes a series of investigations which compared the arc-deposited foils, prepared at ANU with a batch of foils from Munich, prepared by laser-ablation. The two foil types were bombarded with a beam of 6.8 MeV of {sup 197}Au recording their behaviour and monitoring the total stripped current. Optical and electron spectroscopy was carried out and indicate that the arc-deposited foils were relatively amorphous and smooth, while the laser-ablated foils appears to be much more crystalline. It was found that the average useful lifetimes of the Munich foils were at least ten times longer than arc-deposited foils. Furthermore, they maintained a constant beam output during the time in marked contrast to the arc-deposited foils, for which the output decreased quite rapidly. The longevity, and no less importantly, the constant beam output of the laser-ablated foils have emerged as critical to the continuance of the ERDA program. More significantly though, such qualities have provoked re-examination of likely energies for heavy beams that could be obtained with the Linac booster if foil stripping were used in the 14UD terminal, rather than gas that had previously been considered the only viable option. A program is in progress to explore the means to produce laser-ablated foils, or their equivalent, locally. Extended abstract. 1 ref., 2 figs.

Comparison of carbon stripper foils produced by ARC discharge and laser ablation

International Nuclear Information System (INIS)

Ophel, T.R.; Rhode, A.; Lobanov, N.; Weisser, D.C.; Turkentine, R.; Wolf, B.; Wlliman, R.G.

1998-01-01

The present work describes a series of investigations which compared the arc-deposited foils, prepared at ANU with a batch of foils from Munich, prepared by laser-ablation. The two foil types were bombarded with a beam of 6.8 MeV of 197 Au recording their behaviour and monitoring the total stripped current. Optical and electron spectroscopy was carried out and indicate that the arc-deposited foils were relatively amorphous and smooth, while the laser-ablated foils appears to be much more crystalline. It was found that the average useful lifetimes of the Munich foils were at least ten times longer than arc-deposited foils. Furthermore, they maintained a constant beam output during the time in marked contrast to the arc-deposited foils, for which the output decreased quite rapidly. The longevity, and no less importantly, the constant beam output of the laser-ablated foils have emerged as critical to the continuance of the ERDA program. More significantly though, such qualities have provoked re-examination of likely energies for heavy beams that could be obtained with the Linac booster if foil stripping were used in the 14UD terminal, rather than gas that had previously been considered the only viable option. A program is in progress to explore the means to produce laser-ablated foils, or their equivalent, locally

Development of 99Mo isotope production targets employing uranium metal foils

International Nuclear Information System (INIS)

Hofman, G.L.; Wiencek, T.C.; Wood, E.L.; Snelgrove, J.L.

1997-01-01

The Reduced Enrichment Research and Test Reactor Program has continued its effort in the past 3 yr to develop use of low-enriched uranium (LEU) to produce the fission product 99 Mo. This work comprises both target and chemical processing development and demonstration. Two major target systems are now being used to produce 99 Mo with highly enriched uranium-one employing research reactor fuel technology (either uranium-aluminum alloy or uranium aluminide-aluminum dispersion) and the other using a thin deposit of UO 2 on the inside of a stainless steel (SST) tube. This paper summarizes progress in irradiation testing of targets based on LEU uranium metal foils. Several targets of this type have been irradiated in the Indonesian RSG-GAS reactor operating at 22.5 MW

Experimental analysis of a rigid rotor supported on aerodynamic foil journal bearings

Directory of Open Access Journals (Sweden)

Arghir M.

2014-01-01

Full Text Available Aerodynamic foil bearings are highly non linear components used or intending to be used for supporting high speed rotors (>30 krpm of low size rotating machines (<400 kW. The non linear character comes from the highly deformable structure of the bearing made of thin steel sheets and from the Coulomb friction forces arising during dynamic displacements. The present work shows the non linear response of a rigid rotor supported by a pair of such bearings and entrained at 82 krpm. The measurements performed during the coast down revealed sub synchronous and asynchronous vibrations of the rotor and their multiples. A simplified theoretical model reproduces qualitatively some of these non linear characteristics.

Design of foil implosion system for Pioneer I experiments

International Nuclear Information System (INIS)

Erickson, D.J.; Caird, R.S.; Fowler, C.M.

1985-01-01

A foil implosion system is described that integrates an explosive flux-compression generator, a flat plate feed section with power conditioning switches, and a vacuum electrode region containing a cylindrical foil/plasma load. Power conditioning, obtained with an explosive-driven plasma compression opening switch and explosive-actuated closing switches, provides a submicrosecond multimegampere pulse for the implosion of an aluminum plasma. The flat plate section is configured for bidirectional feed to the coaxial vacuum electrodes. Important considerations in the design of the vacuum power flow region include gap failure, feed symmetry, and radial diagnostic access. The system presently accommodates a foil radius of 3 cm. Innovative foil insertion and clamping techniques are also described

Effects of film/foil interactions on X-ray image quality - experimental studies

International Nuclear Information System (INIS)

Maurer, H.J.; Goos, F.

1985-01-01

When assessing the quality of X-ray images, the interaction between film and foil should never be left out of account. Except for the case of green-emitting foils which require green-emitting films, films and foils are normally regarded separately, so that many variations are possible. The authors review the interaction between film and foil under practical aspects. Studies published so far have concentrated either on the amplification factor of foils or an the object imaging characteristics of certain films. Systematic studies on the interaction between film and foil have never been carried out. (orig.) [de

Secondary electron emission of thin carbon foils under the impact of hydrogen atoms, ions and molecular ions, under energies within the MeV range; Multiplicite des electrons secondaires emis par des cibles minces de carbone sous l'impact de projectiles H0, H2+, H3+ d'energie de l'ordre du MeV

Energy Technology Data Exchange (ETDEWEB)

Vidovic, Z

1997-06-15

This work focuses on the study of the emission statistics of secondary electrons from thin carbon foils bombarded with H{sup 0}, H{sub 2}{sup +} and H{sub 3}{sup +} projectiles in the 0.25-2.2 MeV energy range. The phenomenon of secondary electron emission from solids under the impact of swift ions is mainly due to inelastic interactions with target electrons. The phenomenological and theoretical descriptions, as well as a summary of the main theoretical models are the subject of the first chapter. The experimental set-up used to measure event by event the electron emission of the two faces of a thin carbon foil traversed by an energetic projectile is described in the chapter two. In this chapter are also presented the method and algorithms used to process experimental spectra in order to obtain the statistical distribution of the emitted electrons. Chapter three presents the measurements of secondary electron emission induced by H atoms passing through thin carbon foils. The secondary electron yields are studied in correlation with the emergent projectile charge state. We show the peculiar role of the projectile electron, whether it remains or not bound to the incident proton. The fourth chapter is dedicated to the secondary electron emission induced by H{sub 2}{sup +} and H{sub 3}{sup +} polyatomic ions. The results are interpreted in terms of collective effects in the interactions of these ions with solids. The role of the proximity of the protons, molecular ion fragments, upon the amplitude of these collective effects is evidenced from the study of the statistics of forward emission. These experiences allowed us to shed light on various aspects of atom and polyatomic ion inter-actions with solid surfaces. (author)

Scaling laws for radial foil bearings

Science.gov (United States)

Honavara Prasad, Srikanth

The effects of fluid pressurization, structural deformation of the compliant members and heat generation in foil bearings make the design and analysis of foil bearings very complicated. The complex fluid-structural-thermal interactions in foil bearings also make modeling efforts challenging because these phenomena are governed by highly non-linear partial differential equations. Consequently, comparison of various bearing designs require detailed calculation of the flow fields (velocities, pressures), bump deflections (structural compliance) and heat transfer phenomena (viscous dissipation in the fluid, frictional heating, temperature profile etc.,) resulting in extensive computational effort (time/hardware). To obviate rigorous computations and aid in feasibility assessments of foil bearings of various sizes, NASA developed the "rule of thumb" design guidelines for estimation of journal bearing load capacity. The guidelines are based on extensive experimental data. The goal of the current work is the development of scaling laws for radial foil bearings to establish an analytical "rule of thumb" for bearing clearance and bump stiffness. The use of scale invariant Reynolds equation and experimentally observed NASA "rule of thumb" yield scale factors which can be deduced from first principles. Power-law relationships between: a. Bearing clearance and bearing radius, and b. bump stiffness and bearing radius, are obtained. The clearance and bump stiffness values obtained from scaling laws are used as inputs for Orbit simulation to study various cases. As the clearance of the bearing reaches the dimensions of the material surface roughness, asperity contact breaks the fluid film which results in wear. Similarly, as the rotor diameter increases (requiring larger bearing diameters), the load capacity of the fluid film should increase to prevent dry rubbing. This imposes limits on the size of the rotor diameter and consequently bearing diameter. Therefore, this thesis aims

Health status of cows fed maize silage covered with oxo-biodegradable foil

OpenAIRE

Piotr SZTERK; Piotr DORSZEWSKI; Małgorzata GRABOWICZ; Lucyna PODKÓWKA

2017-01-01

In agricultural practice, silage production uses pure, low density polyethylene foil. This foil, after use, becomes farm waste, having a negative impact on the environment. Instead of conventional foil, an environmentally safe biodegradable foil can be used, made from naturally occurring polymers or from synthetic multiparticulates, easily degradable by microorganisms. Silage covered with this type of foil should be safe for animal health. The purpose of the study was to determine whether oxo...

Nonlinear interaction of ultraintense laser pulse with relativistic thin ...

Indian Academy of Sciences (India)

2016-10-13

Oct 13, 2016 ... Today the laser drive of relativistic ions, i.e. ions whose kinetic energy exceeds their rest energy, is an ... this intense electric field, the ions are accelerated and rush towards the electrons with almost the same veloc ... incident laser electric field EL on thin plasma foil of thickness l must satisfy the condition EL ...

Thin films of copper oxide and copper grown by atomic layer deposition for applications in metallization systems of microelectronic devices

Energy Technology Data Exchange (ETDEWEB)

Waechtler, Thomas

2010-05-25

Copper-based multi-level metallization systems in today's ultralarge-scale integrated electronic circuits require the fabrication of diffusion barriers and conductive seed layers for the electrochemical metal deposition. Such films of only several nanometers in thickness have to be deposited void-free and conformal in patterned dielectrics. The envisaged further reduction of the geometric dimensions of the interconnect system calls for coating techniques that circumvent the drawbacks of the well-established physical vapor deposition. The atomic layer deposition method (ALD) allows depositing films on the nanometer scale conformally both on three-dimensional objects as well as on large-area substrates. The present work therefore is concerned with the development of an ALD process to grow copper oxide films based on the metal-organic precursor bis(trin- butylphosphane)copper(I)acetylacetonate [({sup n}Bu{sub 3}P){sub 2}Cu(acac)]. This liquid, non-fluorinated {beta}-diketonate is brought to react with a mixture of water vapor and oxygen at temperatures from 100 to 160 C. Typical ALD-like growth behavior arises between 100 and 130 C, depending on the respective substrate used. On tantalum nitride and silicon dioxide substrates, smooth films and selfsaturating film growth, typical for ALD, are obtained. On ruthenium substrates, positive deposition results are obtained as well. However, a considerable intermixing of the ALD copper oxide with the underlying films takes place. Tantalum substrates lead to a fast self-decomposition of the copper precursor. As a consequence, isolated nuclei or larger particles are always obtained together with continuous films. The copper oxide films grown by ALD can be reduced to copper by vapor-phase processes. If formic acid is used as the reducing agent, these processes can already be carried out at similar temperatures as the ALD, so that agglomeration of the films is largely avoided. Also for an integration with subsequent

Thin films of copper oxide and copper grown by atomic layer deposition for applications in metallization systems of microelectronic devices

Energy Technology Data Exchange (ETDEWEB)

Waechtler, Thomas

2010-05-25

Copper-based multi-level metallization systems in today's ultralarge-scale integrated electronic circuits require the fabrication of diffusion barriers and conductive seed layers for the electrochemical metal deposition. Such films of only several nanometers in thickness have to be deposited void-free and conformal in patterned dielectrics. The envisaged further reduction of the geometric dimensions of the interconnect system calls for coating techniques that circumvent the drawbacks of the well-established physical vapor deposition. The atomic layer deposition method (ALD) allows depositing films on the nanometer scale conformally both on three-dimensional objects as well as on large-area substrates. The present work therefore is concerned with the development of an ALD process to grow copper oxide films based on the metal-organic precursor bis(trin- butylphosphane)copper(I)acetylacetonate [({sup n}Bu{sub 3}P){sub 2}Cu(acac)]. This liquid, non-fluorinated {beta}-diketonate is brought to react with a mixture of water vapor and oxygen at temperatures from 100 to 160 C. Typical ALD-like growth behavior arises between 100 and 130 C, depending on the respective substrate used. On tantalum nitride and silicon dioxide substrates, smooth films and selfsaturating film growth, typical for ALD, are obtained. On ruthenium substrates, positive deposition results are obtained as well. However, a considerable intermixing of the ALD copper oxide with the underlying films takes place. Tantalum substrates lead to a fast self-decomposition of the copper precursor. As a consequence, isolated nuclei or larger particles are always obtained together with continuous films. The copper oxide films grown by ALD can be reduced to copper by vapor-phase processes. If formic acid is used as the reducing agent, these processes can already be carried out at similar temperatures as the ALD, so that agglomeration of the films is largely avoided. Also for an integration with subsequent

Large local lattice expansion in graphene adlayers grown on copper

Science.gov (United States)

Chen, Chaoyu; Avila, José; Arezki, Hakim; Nguyen, Van Luan; Shen, Jiahong; Mucha-Kruczyński, Marcin; Yao, Fei; Boutchich, Mohamed; Chen, Yue; Lee, Young Hee; Asensio, Maria C.

2018-05-01

Variations of the lattice parameter can significantly change the properties of a material, and, in particular, its electronic behaviour. In the case of graphene, however, variations of the lattice constant with respect to graphite have been limited to less than 2.5% due to its well-established high in-plane stiffness. Here, through systematic electronic and lattice structure studies, we report regions where the lattice constant of graphene monolayers grown on copper by chemical vapour deposition increases up to 7.5% of its relaxed value. Density functional theory calculations confirm that this expanded phase is energetically metastable and driven by the enhanced interaction between the substrate and the graphene adlayer. We also prove that this phase possesses distinctive chemical and electronic properties. The inherent phase complexity of graphene grown on copper foils revealed in this study may inspire the investigation of possible metastable phases in other seemingly simple heterostructure systems.

Comparative Assessment of Copper-Coated Kapton: Analysis of Microclad from Several Manufacturing Lots

Energy Technology Data Exchange (ETDEWEB)

Martz, Joseph Christopher [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Spearing, Dane Robert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Labouriau, Andrea [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Judge, Elizabeth [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Kelly, Daniel [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dirmyer, Matthew R. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Milenski, Helen Marie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Patterson, Brian M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Sandoval, Cynthia Wathen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Usov, Igor Olegovich [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Beaux, Miles Frank II [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Henderson, Kevin C. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Torres, Joseph Angelo [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Edwards, Stephanie Lynn [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Vodnik, Douglas R. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Keller, Jennie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mccabe, Rodney James [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Livescu, Veronica [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Cowan, Joseph Sarno [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Aragonez, Robert J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Tokash, Justin Charles [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Lawrence, Samantha Kay [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Leon Brito, Neliza [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2017-04-03

Microclad is a composite material consisting of a thin copper coating applied on a single side over a Kapton substrate. Kapton is the commercial designator for polyimide supplied by DuPont. Microclad is a key material in detonator manufacture and function. Detonators which utilize Microclad function when a large current applied through a thin bridge etched into the copper produces a plasma, accelerating a Kapton flyer into an explosive (PETN) pellet. The geometry and properties of the Microclad are a critical element of this process.

Intense pulsed light annealing of copper zinc tin sulfide nanocrystal coatings

Energy Technology Data Exchange (ETDEWEB)

Williams, Bryce A.; Smeaton, Michelle A.; Holgate, Collin S.; Trejo, Nancy D.; Francis, Lorraine F., E-mail: francis@umn.edu; Aydil, Eray S., E-mail: aydil@umn.edu [Department of Chemical Engineering and Materials Science, University of Minnesota, 151 Amundson Hall, 421 Washington Avenue SE, Minneapolis, Minnesota 55455 (United States)

2016-09-15

A promising method for forming the absorber layer in copper zinc tin sulfide [Cu{sub 2}ZnSnS{sub 4} (CZTS)] thin film solar cells is thermal annealing of coatings cast from dispersions of CZTS nanocrystals. Intense pulsed light (IPL) annealing utilizing xenon flash lamps is a potential high-throughput, low-cost, roll-to-roll manufacturing compatible alternative to thermal annealing in conventional furnaces. The authors studied the effects of flash energy density (3.9–11.6 J/cm{sup 2}) and number of flashes (1–400) during IPL annealing on the microstructure of CZTS nanocrystal coatings cast on molybdenum-coated soda lime glass substrates (Mo-coated SLG). The annealed coatings exhibited cracks with two distinct linear crack densities, 0.01 and 0.2 μm{sup −1}, depending on the flash intensity and total number of flashes. Low density cracking (0.01 μm{sup −1}, ∼1 crack per 100 μm) is caused by decomposition of CZTS at the Mo-coating interface. Vapor decomposition products at the interface cause blisters as they escape the coating. Residual decomposition products within the blisters were imaged using confocal Raman spectroscopy. In support of this hypothesis, replacing the Mo-coated SLG substrate with quartz eliminated blistering and low-density cracking. High density cracking is caused by rapid thermal expansion and contraction of the coating constricted on the substrate as it is heated and cooled during IPL annealing. Finite element modeling showed that CZTS coatings on low thermal diffusivity materials (i.e., SLG) underwent significant differential heating with respect to the substrate with rapid rises and falls of the coating temperature as the flash is turned on and off, possibly causing a build-up of tensile stress within the coating prompting cracking. Use of a high thermal diffusivity substrate, such as a molybdenum foil (Mo foil), reduces this differential heating and eliminates the high-density cracking. IPL annealing in presence of sulfur

Atmospheric Pressure Plasma Jet as a Dry Alternative to Inkjet Printing in Flexible Electronics

Science.gov (United States)

Gandhiraman, Ram Prasad; Lopez, Arlene; Koehne, Jessica; Meyyappan, M.

2016-01-01

We have developed an atmospheric pressure plasma jet printing system that works at room temperature to 50 deg C unlike conventional aerosol assisted techniques which require a high temperature sintering step to obtain desired thin films. Multiple jets can be configured to increase throughput or to deposit multiple materials, and the jet(s) can be moved across large areas using a x-y stage. The plasma jet has been used to deposit carbon nanotubes, graphene, silver nanowires, copper nanoparticles and other materials on substrates such as paper, cotton, plastic and thin metal foils.

Electrodeposition of nano-sized bismuth on copper foil as electrocatalyst for reduction of CO{sub 2} to formate

Energy Technology Data Exchange (ETDEWEB)

Lv, Weixin; Zhou, Jing; Bei, Jingjing [School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, 224051 (China); Zhang, Rui, E-mail: zhangrui@ycit.cn [School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, 224051 (China); Wang, Lei [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People’s Republic of China, Heilongjiang University, Harbin, 150080 (China); Xu, Qi [School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, 224051 (China); Wang, Wei, E-mail: wangw@ycit.edu.cn [School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, 224051 (China)

2017-01-30

Highlights: • Bi/Cu electrode was prepared by depositing nano-sized Bi catalyst on Cu foil. • The Bi/Cu electrode can reduce CO{sub 2} to formate with a low overpotential. • The energy efficiency for reduction of CO{sub 2} to formate can reach to 50%. • A Tafel slope of 128 mV decade{sup −1} was observed for producing formate. - Abstract: Electrochemical reduction of carbon dioxide (CO{sub 2}) to formate is energetically inefficient because high overpotential is required for reduction of CO{sub 2} to formate on most traditional catalysts. In this paper, a novel nano-sized Bi-based electrocatalyst deposited on a Cu foil has been synthesized, which can be used as a cathode for electrochemical reduction of CO{sub 2} to formate with a low overpotential (0.69 V) and a high selectivity (91.3%). The electrocatalyst can show excellent catalytic performance toward reduction of CO{sub 2} which can probably be attributed to the nano-sized structure and the surface oxide layer. The energy efficiency for reduction of CO{sub 2} to formate can reach to 50% when an Ir{sub x}Sn{sub y}Ru{sub z}O{sub 2}/Ti electrode is used as anode, it is one of the highest values found in the literatures and very practicable for sustainable fuel synthesis.

Rapid and highly efficient growth of graphene on copper by chemical vapor deposition of ethanol

Energy Technology Data Exchange (ETDEWEB)

Lisi, Nicola, E-mail: nicola.lisi@enea.it [ENEA, Materials Technology Unit, Surface Technology Laboratory, Casaccia Research Centre, Via Anguillarese 301, 00123 Rome (Italy); Buonocore, Francesco; Dikonimos, Theodoros; Leoni, Enrico [ENEA, Materials Technology Unit, Surface Technology Laboratory, Casaccia Research Centre, Via Anguillarese 301, 00123 Rome (Italy); Faggio, Giuliana; Messina, Giacomo [Dipartimento di Ingegneria dell' Informazione, delle Infrastrutture e dell' Energia Sostenibile (DIIES), Università “Mediterranea” di Reggio Calabria, 89122 Reggio Calabria (Italy); Morandi, Vittorio; Ortolani, Luca [CNR-IMM Bologna, Via Gobetti 101, 40129 Bologna (Italy); Capasso, Andrea [ENEA, Materials Technology Unit, Surface Technology Laboratory, Casaccia Research Centre, Via Anguillarese 301, 00123 Rome (Italy)

2014-11-28

The growth of graphene by chemical vapor deposition on metal foils is a promising technique to deliver large-area films with high electron mobility. Nowadays, the chemical vapor deposition of hydrocarbons on copper is the most investigated synthesis method, although many other carbon precursors and metal substrates are used too. Among these, ethanol is a safe and inexpensive precursor that seems to offer favorable synthesis kinetics. We explored the growth of graphene on copper from ethanol, focusing on processes of short duration (up to one min). We investigated the produced films by electron microscopy, Raman and X-ray photoemission spectroscopy. A graphene film with high crystalline quality was found to cover the entire copper catalyst substrate in just 20 s, making ethanol appear as a more efficient carbon feedstock than methane and other commonly used precursors. - Highlights: • Graphene films were grown by fast chemical vapor deposition of ethanol on copper. • High-temperature/short-time growth produced highly crystalline graphene. • The copper substrate was entirely covered by a graphene film in just 20 s. • Addition of H{sub 2} had a negligible effect on the crystalline quality.

A suspended boron foil multi-wire proportional counter neutron detector

Energy Technology Data Exchange (ETDEWEB)

Nelson, Kyle A.; Edwards, Nathaniel S.; Hinson, Niklas J.; Wayant, Clayton D.; McGregor, Douglas S.

2014-12-11

Three natural boron foils, approximately 1.0 cm in diameter and 1.0 µm thick, were obtained from The Lebow Company and suspended in a multi-wire proportional counter. Suspending the B foils allowed the alpha particle and Li ion reaction products to escape simultaneously, one on each side of the foil, and be measured concurrently in the gas volume. The thermal neutron response pulse-height spectrum was obtained and two obvious peaks appear from the 94% and 6% branches of the {sup 10}B(n,α){sup 7}Li neutron reaction. Scanning electron microscope images were collected to obtain the exact B foil thicknesses and MCNP6 simulations were completed for those same B thicknesses. Pulse-height spectra obtained from the simulations were compared to experimental data and matched well. The theoretical intrinsic thermal–neutron detection efficiency for enriched {sup 10}B foils was calculated and is presented. Additionally, the intrinsic thermal neutron detection efficiency of the three natural B foils was calculated to be 3.2±0.2%.

A suspended boron foil multi-wire proportional counter neutron detector

Science.gov (United States)

Nelson, Kyle A.; Edwards, Nathaniel S.; Hinson, Niklas J.; Wayant, Clayton D.; McGregor, Douglas S.

2014-12-01

Three natural boron foils, approximately 1.0 cm in diameter and 1.0 μm thick, were obtained from The Lebow Company and suspended in a multi-wire proportional counter. Suspending the B foils allowed the alpha particle and Li ion reaction products to escape simultaneously, one on each side of the foil, and be measured concurrently in the gas volume. The thermal neutron response pulse-height spectrum was obtained and two obvious peaks appear from the 94% and 6% branches of the 10B(n,α)7Li neutron reaction. Scanning electron microscope images were collected to obtain the exact B foil thicknesses and MCNP6 simulations were completed for those same B thicknesses. Pulse-height spectra obtained from the simulations were compared to experimental data and matched well. The theoretical intrinsic thermal-neutron detection efficiency for enriched 10B foils was calculated and is presented. Additionally, the intrinsic thermal neutron detection efficiency of the three natural B foils was calculated to be 3.2±0.2%.

Dosimetric response of united, commercially available CTA foils for 60Co gamma rays

International Nuclear Information System (INIS)

Peimel-Stuglik, Z.

2001-01-01

The usefulness of two kinds of untinted CTA foils: Fuji CTR-125 dosimetric foil and technical CTA-T foil, produced by 'Zaklady Chemiczne, 'Gorzow Wielkopolski' as support for light-sensitive layers of amateur photo-films, for 60 Co gamma ray dosimetry was investigated. In spite of rather bad physical parameters of the technical foil (spread of foil thickness, high and different initial absorbance) the dosimetric response of both foils for 60 Co gamma rays was similar. The CTA-T foil can be used for routine dosimetry providing that dosimetric signals have to be calculated exactly as recommended by the ASTM (American Society for Testing and Materials) standard, i.e. as the difference of absorbance of irradiated and (the same) non-irradiated foil. Any other approach may lead to high errors of dose evaluation. The last is true also for other CTA foils, especially after long self-life. (author)

Application and Continued Development of Thin Faraday Collectors as a Lost Ion Diagnostic for Tokamak Fusion Plasmas

Energy Technology Data Exchange (ETDEWEB)

F. Ed Cecil

2011-06-30

This report summarizes the accomplishment of sixteen years of work toward the development of thin foil Faraday collectors as a lost energetic ion diagnostic for high temperature magnetic confinement fusion plasmas. Following initial, proof of principle accelerator based studies, devices have been tested on TFTR, NSTX, ALCATOR, DIII-D, and JET (KA-1 and KA-2). The reference numbers refer to the attached list of publications. The JET diagnostic KA-2 continues in operation and hopefully will provide valuable diagnostic information during a possible d-t campaign on JET in the coming years. A thin Faraday foil spectrometer, by virtue of its radiation hardness, may likewise provide a solution to the very challenging problem of lost alpha particle measurements on ITER and other future burning plasma machines.

Crystallization of copper metaphosphate glass

Science.gov (United States)

Bae, Byeong-Soo; Weinberg, Michael C.

1993-01-01

The effect of the valence state of copper in copper metaphosphate glass on the crystallization behavior and glass transition temperature has been investigated. The crystallization of copper metaphosphate is initiated from the surface and its main crystalline phase is copper metaphosphate (Cu(PO)3),independent of the (Cu sup 2+)/(Cu(total)). However, the crystal morphology, the relative crystallization rates, and their temperature dependences are affected by the (Cu sup 2+)/(Cu (total)) ratio in the glass. On the other hand, the totally oxidized glass crystallizes from all over the surface. The relative crystallization rate of the reduced glass to the totally oxidized glass is large at low temperature, but small at high temperature. The glass transition temperature of the glass increases as the (Cu sup 2+)/(Cu(total)) ratio is raised. It is also found that the atmosphere used during heat treatment does not influence the crystallization of the reduced glass, except for the formation of a very thin CuO surface layer when heated in air.

Copper tin sulfide (CTS) absorber thin films obtained by co-evaporation: Influence of the ratio Cu/Sn

Energy Technology Data Exchange (ETDEWEB)

Robles, V., E-mail: victor.robles@ciemat.es; Trigo, J.F.; Guillén, C.; Herrero, J.

2015-09-05

Highlights: • Copper tin sulfide (CTS) thin films were grown by co-evaporation at different Cu/Sn atomic ratios. • Smooth Cu{sub 2}SnS{sub 3} layers with large grains are obtained at Cu/Sn ⩾ 1.5 and T ⩾ 350 °C. • At 450 °C, the cubic Cu{sub 2}SnS{sub 3} phase changes to tetragonal phase. • Cu{sub 2}SnS{sub 3} presents suitable optical and electrical properties for use as photovoltaic absorbers. - Abstract: Copper tin sulfide thin films have been grown on soda-lime glass substrates from the elemental constituents by co-evaporation. The synthesis was performed at substrate temperatures of 350 °C and 450 °C and different Cu/Sn ratios, adjusting the deposition time in order to obtain thicknesses above 1000 nm. The evolution of the morphological, structural, chemical, optical and electrical properties has been analyzed as a function of the substrate temperature and the Cu/Sn ratio. For the samples with Cu/Sn ⩽ 1, Cu{sub 2}Sn{sub 3}S{sub 7} and Cu{sub 2}SnS{sub 3} have been observed by XRD. Increasing the Cu/Sn to 1.5, the Cu{sub 2}SnS{sub 3} phase was the majority, being the formation completed at Cu/Sn ratio around 2. The increment of the substrate temperature leads to a change of cubic structure to tetragonal of the Cu{sub 2}SnS{sub 3} phase. The chemical treatment with KCN was effective to eliminate CuS excess detected in the samples with Cu/Sn > 2.2. The samples with Cu{sub 2}SnS{sub 3} structure show a band gap energy increasing from 0.9 to 1.25 eV and an electrical resistivity decreasing from 7 ∗ 10{sup −2} Ω cm to 3 ∗ 10{sup −3} Ω cm when the Cu/Sn atomic ratio increases from 1.5 to 2.2.

Development, characterization and qualification of first GEM foils produced in India

Science.gov (United States)

Shah, Aashaq; Ahmed, Asar; Gola, Mohit; Sharma, Ram Krishna; Malhotra, Shivali; Kumar, Ashok; Naimuddin, Md.; Menon, Pradeep; Srinivasan, K.

2018-06-01

The increasing demand for Gas Electron Multiplier (GEM) foils has been driven by their application in many current and proposed high-energy physics experiments. Micropack, a Bengaluru-based company, has established and commercialized GEM foils for the first time in India. Micropack used the double-mask etching technique to successfully produce 10 cm × 10 cm GEM foil. In this paper, we report on the development as well as the geometrical and electrical properties of these foils, including the size uniformity of the holes and leakage current measurements. Our characterization studies show that the foils are of good quality and satisfy all the necessary quality control criteria.

Impulse Hydroforming Method for Very Thin Sheets from Metallic or Hybrid Materials

OpenAIRE

Beerwald, C.; Beerwald, M.; Dirksen, U.; Henselek, A.

2010-01-01

Forming of very thin metallic and hybrid material foils is a demanding task in several application areas as for example in food or pharmaceutical packaging industries. Narrow forming limits of very thin sheet metals as well as minor process reliability due to necessary exact tool manufacturing (small punch-die clearance), both, causes abiding interest in new and innovative forming processes. In this contribution a new method using high pressure pulses will be introduced to form small geometry...

Ti foil light in the ATA [Advanced Test Accelerator] beam

International Nuclear Information System (INIS)

Slaughter, D.R.; Chong, Y.P.; Goosman, D.R.; Rule, D.W.; Fiorito, R.B.

1987-09-01

An experiment is in progress to characterize the visible light produced when a Ti foil is immersed in the ATA 2 kA, 43 MeV beam. Results obtained to date indicate that the optical condition of the foil surface is a critical determinant of these characteristics, with a very narrow angular distribution obtained when a highly polished and flat foil is used. These data are consistent with the present hypothesis that the light is produced by transition radiation. Incomplete experiments to determine the foil angle dependence of the detected light and its polarization are summarized and remaining experiments are described

Apparatus and process for ultrasonic seam welding stainless steel foils

Science.gov (United States)

Leigh, Richard W.

1992-01-01

An ultrasonic seam welding apparatus having a head which is rotated to form contact, preferably rolling contact, between a metallurgically inert coated surface of the head and an outside foil of a plurality of layered foils or work materials. The head is vibrated at an ultrasonic frequency, preferably along a longitudinal axis of the head. The head is constructed to transmit vibration through a contacting surface of the head into each of the layered foils. The contacting surface of the head is preferably coated with aluminum oxide to prevent the head from becoming welded to layered stainless steel foils.

Thermohydrodynamic analysis of airfoil bearing based on bump foil structure

Directory of Open Access Journals (Sweden)

S.Y. Maraiy

2016-09-01

Full Text Available The load carrying capacity of the gas foil bearing depends on the material properties and the configuration of the underlying bump strip’s structure. This paper presents three different cases for selecting the dimensions of the foil bearing to guarantee the highest possible load carrying capacity. It focuses on three main parameters that affect the compliance number; these parameters are the length of bump in θ direction, the pitch of bump foil, and the thickness of bump foil. It also studies the effect of changing these parameters on load carrying capacity according to both isothermal and thermohydrodynamic approaches.

Pulsed Laser Deposition of BaTiO3 Thin Films on Different Substrates

Directory of Open Access Journals (Sweden)

Yaodong Yang

2010-01-01

Full Text Available We have studied the deposition of BaTiO3 (BTO thin films on various substrates. Three representative substrates were selected from different types of material systems: (i SrTiO3 single crystals as a typical oxide, (ii Si wafers as a semiconductor, and (iii Ni foils as a magnetostrictive metal. We have compared the ferroelectric properties of BTO thin films obtained by pulsed laser deposition on these diverse substrates.

LENA Conversion Foils Using Single-Layer Graphene, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Our key innovation will be the use of single-layer graphene as LENA conversion foils, with appropriate microgrids and nanogrids to support the foils. Phase I...

21 CFR 189.301 - Tin-coated lead foil capsules for wine bottles.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Tin-coated lead foil capsules for wine bottles. 189... SERVICES (CONTINUED) FOOD FOR HUMAN CONSUMPTION (CONTINUED) SUBSTANCES PROHIBITED FROM USE IN HUMAN FOOD... lead foil capsules for wine bottles. (a) Tin-coated lead foil is composed of a lead foil coated on one...

Transient oxidation of Al-deposited Fe-Cr-Al alloy foil

International Nuclear Information System (INIS)

Andoh, A.

1997-01-01

The oxide phases formed on an Al-deposited Fe-Cr-Al alloy foil and an Fe-Cr-Al alloy foil of the same levels of Al and (La+Ce) contents, and their oxidation kinetics have been studied in air at 1173 and 1373 K using TGA, XRD and SEM. Al deposition promotes the growth of metastable aluminas (θ-Al 2 O 3 , γ-Al 2 O 3 ). Scales consisting of θ-Al 2 O 3 and a small amount of α-Al 2 O 3 develop on the Al-deposited foil at 1173 K and exhibit the whisker-type morphology. In the early stage of oxidation at 1373 K, thick scales consisting of θ-Al 2 O 3 and α-Al 2 O 3 grow rapidly on the Al-deposited foil. The transformation from θ-Al 2 O 3 to α-Al 2 O 3 is very fast, and the scales result in only α-Al 2 O 3 . In contrast, α-Al 2 O 3 scales containing a minor amount of FeAl 2 O 4 develop on the alloy foil. The growth rate of α-Al 2 O 3 scales on the Al-deposited foil is smaller than that on the alloy foil and very close to that on NiAl at 1373 K. (orig.)

Modification of surface layers of copper under the action of the volumetric discharge initiated by an avalanche electron beam in nitrogen and CO2 at atmospheric pressure

Science.gov (United States)

Shulepov, M. A.; Akhmadeev, Yu. Kh.; Tarasenko, V. F.; Kolubaeva, Yu. A.; Krysina, O. V.; Kostyrya, I. D.

2011-05-01

The results of experimental investigations of the action of the volumetric discharge initiated by an avalanche electron beam on the surface of copper specimens are presented. The volumetric (diffuse) discharge in nitrogen and CO2 at atmospheric pressure was initiated by applying high voltage pulses of nanosecond duration to a tubular foil cathode. It has been found that the treatment of a copper surface by this type of discharge increases the hardness of the surface layer due to oxidation.

A dilute Cu(Ni) alloy for synthesis of large-area Bernal stacked bilayer graphene using atmospheric pressure chemical vapour deposition

Energy Technology Data Exchange (ETDEWEB)

Madito, M. J.; Bello, A.; Dangbegnon, J. K.; Momodu, D. Y.; Masikhwa, T. M.; Barzegar, F.; Manyala, N., E-mail: ncholu.manyala@up.ac.za [Department of Physics, Institute of Applied Materials, SARCHI Chair in Carbon Technology and Materials, University of Pretoria, Pretoria 0028 (South Africa); Oliphant, C. J.; Jordaan, W. A. [National Metrology Institute of South Africa, Private Bag X34, Lynwood Ridge, Pretoria 0040 (South Africa); Fabiane, M. [Department of Physics, Institute of Applied Materials, SARCHI Chair in Carbon Technology and Materials, University of Pretoria, Pretoria 0028 (South Africa); Department of Physics, National University of Lesotho, P.O. Roma 180 (Lesotho)

2016-01-07

A bilayer graphene film obtained on copper (Cu) foil is known to have a significant fraction of non-Bernal (AB) stacking and on copper/nickel (Cu/Ni) thin films is known to grow over a large-area with AB stacking. In this study, annealed Cu foils for graphene growth were doped with small concentrations of Ni to obtain dilute Cu(Ni) alloys in which the hydrocarbon decomposition rate of Cu will be enhanced by Ni during synthesis of large-area AB-stacked bilayer graphene using atmospheric pressure chemical vapour deposition. The Ni doped concentration and the Ni homogeneous distribution in Cu foil were confirmed with inductively coupled plasma optical emission spectrometry and proton-induced X-ray emission. An electron backscatter diffraction map showed that Cu foils have a single (001) surface orientation which leads to a uniform growth rate on Cu surface in early stages of graphene growth and also leads to a uniform Ni surface concentration distribution through segregation kinetics. The increase in Ni surface concentration in foils was investigated with time-of-flight secondary ion mass spectrometry. The quality of graphene, the number of graphene layers, and the layers stacking order in synthesized bilayer graphene films were confirmed by Raman and electron diffraction measurements. A four point probe station was used to measure the sheet resistance of graphene films. As compared to Cu foil, the prepared dilute Cu(Ni) alloy demonstrated the good capability of growing large-area AB-stacked bilayer graphene film by increasing Ni content in Cu surface layer.

Annealing of (DU-10Mo)-Zr Co-Rolled Foils

International Nuclear Information System (INIS)

Pacheco, Robin Montoya; Alexander, David John; Mccabe, Rodney James; Clarke, Kester Diederik; Scott, Jeffrey E.; Montalvo, Joel Dwayne; Papin, Pallas; Ansell, George S.

2017-01-01

Producing uranium-10wt% molybdenum (DU-10Mo) foils to clad with Al first requires initial bonding of the DU-10Mo foil to zirconium (Zr) by hot rolling, followed by cold rolling to final thickness. Rolling often produces wavy (DU-10Mo)-Zr foils that should be flattened before further processing, as any distortions could affect the final alignment and bonding of the Al cladding to the Zr co-rolled surface layer; this bonding is achieved by a hot isostatic pressing (HIP) process. Distortions in the (DU-10Mo)-Zr foil may cause the fuel foil to press against the Al cladding and thus create thinner or thicker areas in the Al cladding layer during the HIP cycle. Post machining is difficult and risky at this stage in the process since there is a chance of hitting the DU-10Mo. Therefore, it is very important to establish a process to flatten and remove any waviness. This study was conducted to determine if a simple annealing treatment could flatten wavy foils. Using the same starting material (i.e. DU-10Mo coupons of the same thickness), five different levels of hot rolling and cold rolling, combined with five different annealing treatments, were performed to determine the effect of these processing variables on flatness, bonding of layers, annealing response, microstructure, and hardness. The same final thickness was reached in all cases. Micrographs, textures, and hardness measurements were obtained for the various processing combinations. Based on these results, it was concluded that annealing at 650°C or higher is an effective treatment to appreciably reduce foil waviness.

Annealing of (DU-10Mo)-Zr Co-Rolled Foils

Energy Technology Data Exchange (ETDEWEB)

Pacheco, Robin Montoya [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Alexander, David John [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mccabe, Rodney James [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Clarke, Kester Diederik [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Scott, Jeffrey E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Montalvo, Joel Dwayne [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Papin, Pallas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ansell, George S. [Colorado School of Mines, Golden, CO (United States)

2017-01-20

Producing uranium-10wt% molybdenum (DU-10Mo) foils to clad with Al first requires initial bonding of the DU-10Mo foil to zirconium (Zr) by hot rolling, followed by cold rolling to final thickness. Rolling often produces wavy (DU-10Mo)-Zr foils that should be flattened before further processing, as any distortions could affect the final alignment and bonding of the Al cladding to the Zr co-rolled surface layer; this bonding is achieved by a hot isostatic pressing (HIP) process. Distortions in the (DU-10Mo)-Zr foil may cause the fuel foil to press against the Al cladding and thus create thinner or thicker areas in the Al cladding layer during the HIP cycle. Post machining is difficult and risky at this stage in the process since there is a chance of hitting the DU-10Mo. Therefore, it is very important to establish a process to flatten and remove any waviness. This study was conducted to determine if a simple annealing treatment could flatten wavy foils. Using the same starting material (i.e. DU-10Mo coupons of the same thickness), five different levels of hot rolling and cold rolling, combined with five different annealing treatments, were performed to determine the effect of these processing variables on flatness, bonding of layers, annealing response, microstructure, and hardness. The same final thickness was reached in all cases. Micrographs, textures, and hardness measurements were obtained for the various processing combinations. Based on these results, it was concluded that annealing at 650°C or higher is an effective treatment to appreciably reduce foil waviness.

Spectra from foil-excited molybdenum ions

International Nuclear Information System (INIS)

Johnson, B.M.; Jones, K.W.; Cecchi, J.L.; Kruse, T.H.

1978-01-01

The extreme-ultraviolet spectra (5 to 55 nm) for foil-excited molybdenum ions have been measured using 22 to 200 MeV beams from the Brookhaven National Laboratory MP tandem Van de Graaff accelerator facility, 20 μg/cm 2 C stripping foils, and a grazing incidence spectrometer. The mean ion charge states (13 to 28) and the narrow distribution widths (about 2 charge states) were accurately predictable from experimental parameters. Where possible, comparisons are given with Mo radiation from tokamaks, vacuum sparks, and laser-excited plasmas

Copper Benzenetricarboxylate Metal-Organic Framework Nucleation Mechanisms on Metal Oxide Powders and Thin Films formed by Atomic Layer Deposition.

Science.gov (United States)

Lemaire, Paul C; Zhao, Junjie; Williams, Philip S; Walls, Howard J; Shepherd, Sarah D; Losego, Mark D; Peterson, Gregory W; Parsons, Gregory N

2016-04-13

Chemically functional microporous metal-organic framework (MOF) crystals are attractive for filtration and gas storage applications, and recent results show that they can be immobilized on high surface area substrates, such as fiber mats. However, fundamental knowledge is still lacking regarding initial key reaction steps in thin film MOF nucleation and growth. We find that thin inorganic nucleation layers formed by atomic layer deposition (ALD) can promote solvothermal growth of copper benzenetricarboxylate MOF (Cu-BTC) on various substrate surfaces. The nature of the ALD material affects the MOF nucleation time, crystal size and morphology, and the resulting MOF surface area per unit mass. To understand MOF nucleation mechanisms, we investigate detailed Cu-BTC MOF nucleation behavior on metal oxide powders and Al2O3, ZnO, and TiO2 layers formed by ALD on polypropylene substrates. Studying both combined and sequential MOF reactant exposure conditions, we find that during solvothermal synthesis ALD metal oxides can react with the MOF metal precursor to form double hydroxy salts that can further convert to Cu-BTC MOF. The acidic organic linker can also etch or react with the surface to form MOF from an oxide metal source, which can also function as a nucleation agent for Cu-BTC in the mixed solvothermal solution. We discuss the implications of these results for better controlled thin film MOF nucleation and growth.

Enhanced Absorption in Organic Thin-Films from Imprinted Concave Nanostructures

DEFF Research Database (Denmark)

Goszczak, Arkadiusz Jaroslaw; Rubahn, Horst-Günter; Madsen, Morten

2017-01-01

In this work, a rapid, replicable method for imprinting concave nanostructures to be used as functional light-trapping nanostructures in organic thin-films is presented. Porous anodic alumina templates were fabricated both by anodization of thick Al foils and by anodization of submicrometer thin Al...... patterns and used for imprinting of spin coated photoresist on glass substrates. We have investigated semi-periodic and aperiodic imprinted large concave patterns fabricated from rigid masters after anodization of Al in H3PO4. We show that metal covered imprinted concaves show enhancement in absorption...

Secondary electron emission of thin carbon foils under the impact of hydrogen atoms, ions and molecular ions, under energies within the MeV range; Multiplicite des electrons secondaires emis par des cibles minces de carbone sous l'impact de projectiles H0, H2+, H3+ d'energie de l'ordre du MeV

Energy Technology Data Exchange (ETDEWEB)

Vidovic, Z

1997-06-15

This work focuses on the study of the emission statistics of secondary electrons from thin carbon foils bombarded with H{sup 0}, H{sub 2}{sup +} and H{sub 3}{sup +} projectiles in the 0.25-2.2 MeV energy range. The phenomenon of secondary electron emission from solids under the impact of swift ions is mainly due to inelastic interactions with target electrons. The phenomenological and theoretical descriptions, as well as a summary of the main theoretical models are the subject of the first chapter. The experimental set-up used to measure event by event the electron emission of the two faces of a thin carbon foil traversed by an energetic projectile is described in the chapter two. In this chapter are also presented the method and algorithms used to process experimental spectra in order to obtain the statistical distribution of the emitted electrons. Chapter three presents the measurements of secondary electron emission induced by H atoms passing through thin carbon foils. The secondary electron yields are studied in correlation with the emergent projectile charge state. We show the peculiar role of the projectile electron, whether it remains or not bound to the incident proton. The fourth chapter is dedicated to the secondary electron emission induced by H{sub 2}{sup +} and H{sub 3}{sup +} polyatomic ions. The results are interpreted in terms of collective effects in the interactions of these ions with solids. The role of the proximity of the protons, molecular ion fragments, upon the amplitude of these collective effects is evidenced from the study of the statistics of forward emission. These experiences allowed us to shed light on various aspects of atom and polyatomic ion inter-actions with solid surfaces. (author)

Development of a new foil compounded from carbon nanotubes and sputter-deposition carbon

International Nuclear Information System (INIS)

Hiroo Hasebe; Hironori Kuboki; Hiroki Okuno; Isao Yamane; Hiroshi Imao; Nobuhisa Fukunishi; Masayuki Kase; Osamu Kamigaito

2014-01-01

New carbon-nanotube-sputter-deposition-carbon (CNT-SDC) foils were developed and used in the U beam time at the RIKEN RI Beam Factory (RIBF) from October to December 2011. The lifetimes of these new foils were drastically extended, and stable, high-intensity U beams were successfully provided to users. The lifetime of the CNT-SDC foils was 2-5 C, which was 100 times longer than those of static C-foils previously used. The qualitative analysis of the CNT-SDC foils clearly showed that the CNT structure and bundles were broken by beam irradiation. In addition, it was found that CNT bundles in the CNT-SDC foil were grown after the carbon deposition procedure. This structure was considered to be the reason that the CNT-SDC foils maintain advantages of both CNT and SDC foils. (author)

Decontamination with pasty pickling agents forming a strippable foil

International Nuclear Information System (INIS)

Weichselgartner, H.

1991-01-01

This paper describes the development of an in-situ decontamination procedure by applying onto the contaminated surface (in an one-step or multi-step process) pasty, chemically aggressive agents causing dilution and adsorption of the contaminant and then hardening to form a strippable foil. The use of such a foil will result in following advantages, with respect to usual techniques: - sensibly shorter operation duration resulting in lower personnel doses; - reduction of the arising secondary waste volume because there is no need for washing; the volume of the spent strippable foil is much smaller than currently used water volumes; - optimal conditioning of the radioactive waste due to its fixation in a solid (foil); - an accidental contamination in a controlled area can easily be fixed and covered avoiding its propagation

Measurements of laser generated soft X-ray emission from irradiated gold foils

Energy Technology Data Exchange (ETDEWEB)

Davis, J. S.; Keiter, P. A.; Klein, S. R.; Drake, R. P.; Shvarts, D. [University of Michigan, 2455 Hayward St., Ann Arbor, Michigan 48109 (United States); Frank, Y.; Raicher, E.; Fraenkel, M. [Soreq Nuclear Research Center, Yavne (Israel)

2016-11-15

Soft x-ray emission from laser irradiated gold foils was measured at the Omega-60 laser system using the Dante photodiode array. The foils were heated with 2 kJ, 6 ns laser pulses and foil thicknesses were varied between 0.5, 1.0, and 2.0 μm. Initial Dante analysis indicates peak emission temperatures of roughly 100 eV and 80 eV for the 0.5 μm and 1.0 μm thick foils, respectively, with little measurable emission from the 2.0 μm foils.

Transmission Electron Microscopy of Amorphous Tandem Thin-Film Silicon Modules Produced by A Roll-to-Roll Process on Plastic Foil

DEFF Research Database (Denmark)

Couty, P.; Duchamp, Martial; Söderström, K.

2011-01-01

An improvement of the photo-current is expected when amorphous silicon solar cells are grown on a ZnO texture. A full understanding of the relationship between cell structure and electrical performance is essential for the rapid development of high efficiency VHF-tandem cells on textured substrates...... a control-lost of shape fidelity is used to smooth the texture and make it compatible with subsequent layer growth. Then, we present the electrical performances of the most promising reference solar cell single junction which was obtained on a roll-to-roll foil. Finally, a tandem amorphous/amorphous Si....... At first, we present the systematic study where amorphous cells are grown on ZnO based textures. For varying the texture, the same original master LPCVD ZnO was successively transferred to nickel molds and finally transferred to the plastic foil by roll-to-roll process. From TEM images, we show how...

Flower-Like CuO/ZnO Hybrid Hierarchical Nanostructures Grown on Copper Substrate: Glycothermal Synthesis, Characterization, Hydrophobic and Anticorrosion Properties.

Science.gov (United States)

Beshkar, Farshad; Khojasteh, Hossein; Salavati-Niasari, Masoud

2017-06-25

In this work we have demonstrated a facile formation of CuO nanostructures on copper substrates by the oxidation of copper foil in ethylene glycol (EG) at 80 °C. On immersing a prepared CuO film into a solution containing 0.1 g Zn(acac)₂ in 20 mL EG for 8 h, ZnO flower-like microstructures composed of hierarchical three-dimensional (3D) aggregated nanoparticles and spherical architectures were spontaneously formed at 100 °C. The as-synthesized thin films and 3D microstructures were characterized using XRD, SEM, and EDS techniques. The effects of sodium dodecyl sulphate (SDS), cetyltrimethylammonium bromide (CTAB), and polyethylene glycol (PEG) 6000 as surfactants and stabilizers on the morphology of the CuO and ZnO structures were discussed. Possible growth mechanisms for the controlled organization of primary building units into CuO nanostructures and 3D flower-like ZnO architectures were proposed. The hydrophobic property of the products was characterized by means of water contact angle measurement. After simple surface modification with stearic acid and PDMS, the resulting films showed hydrophobic and even superhydrophobic characteristics due to their special surface energy and nano-microstructure morphology. Importantly, stable superhydrophobicity with a contact angle of 153.5° was successfully observed for CuO-ZnO microflowers after modification with PDMS. The electrochemical impedance measurements proved that the anticorrosion efficiency for the CuO/ZnO/PDMS sample was about 99%.

Flower-Like CuO/ZnO Hybrid Hierarchical Nanostructures Grown on Copper Substrate: Glycothermal Synthesis, Characterization, Hydrophobic and Anticorrosion Properties

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Farshad Beshkar

2017-06-01

Full Text Available In this work we have demonstrated a facile formation of CuO nanostructures on copper substrates by the oxidation of copper foil in ethylene glycol (EG at 80 °C. On immersing a prepared CuO film into a solution containing 0.1 g Zn(acac2 in 20 mL EG for 8 h, ZnO flower-like microstructures composed of hierarchical three-dimensional (3D aggregated nanoparticles and spherical architectures were spontaneously formed at 100 °C. The as-synthesized thin films and 3D microstructures were characterized using XRD, SEM, and EDS techniques. The effects of sodium dodecyl sulphate (SDS, cetyltrimethylammonium bromide (CTAB, and polyethylene glycol (PEG 6000 as surfactants and stabilizers on the morphology of the CuO and ZnO structures were discussed. Possible growth mechanisms for the controlled organization of primary building units into CuO nanostructures and 3D flower-like ZnO architectures were proposed. The hydrophobic property of the products was characterized by means of water contact angle measurement. After simple surface modification with stearic acid and PDMS, the resulting films showed hydrophobic and even superhydrophobic characteristics due to their special surface energy and nano-microstructure morphology. Importantly, stable superhydrophobicity with a contact angle of 153.5° was successfully observed for CuO-ZnO microflowers after modification with PDMS. The electrochemical impedance measurements proved that the anticorrosion efficiency for the CuO/ZnO/PDMS sample was about 99%.

Numerical simulations of energy deposition caused by 50 MeV—50 TeV proton beams in copper and graphite targets

Science.gov (United States)

Nie, Y.; Schmidt, R.; Chetvertkova, V.; Rosell-Tarragó, G.; Burkart, F.; Wollmann, D.

2017-08-01

The conceptual design of the Future Circular Collider (FCC) is being carried out actively in an international collaboration hosted by CERN, for the post-Large Hadron Collider (LHC) era. The target center-of-mass energy of proton-proton collisions for the FCC is 100 TeV, nearly an order of magnitude higher than for LHC. The existing CERN accelerators will be used to prepare the beams for FCC. Concerning beam-related machine protection of the whole accelerator chain, it is critical to assess the consequences of beam impact on various accelerator components in the cases of controlled and uncontrolled beam losses. In this paper, we study the energy deposition of protons in solid copper and graphite targets, since the two materials are widely used in magnets, beam screens, collimators, and beam absorbers. Nominal injection and extraction energies in the hadron accelerator complex at CERN were selected in the range of 50 MeV-50 TeV. Three beam sizes were studied for each energy, corresponding to typical values of the betatron function. Specifically for thin targets, comparisons between fluka simulations and analytical Bethe equation calculations were carried out, which showed that the damage potential of a few-millimeter-thick graphite target and submillimeter-thick copper foil can be well estimated directly by the Bethe equation. The paper provides a valuable reference for the quick evaluation of potential damage to accelerator elements over a large range of beam parameters when beam loss occurs.

A new method for making long-lived carbon stripper foils

International Nuclear Information System (INIS)

Sugai, Isao; Ishii, Sabro; Hattori, Toshiyuki; Muto, Hideshi; Takahashi, Yohsuke; Kato, Hajime; Yamazaki, Kuniaki.

1989-01-01

We have developed a new method for preparation of long-lived carbon stripper foils, based on the modification of our 'controlled DC arc-discharge method'. The carbon foils consist of multi-layers, and carbon particles in each layer are emitted from the electrode in AC arc-discharge or from the cathode electrode in DC arc-discharge. The lifetimes of the carbon foils made by the new method are equal to or longer than those prepared by the controlled DC arc-discharge method. The new method is simple and powerful to make long-lived carbon stripper foils with higher reliability and reproducibility than the previous method. (author)

Simulated Thin-Film Growth and Imaging

Science.gov (United States)

Schillaci, Michael