Glacial-interglacial variations of microbial communities in permafrost and lake deposits in the Siberian Arctic

Science.gov (United States)

Mangelsdorf, Kai; Bischoff, Juliane; Gattinger, Andreas; Wagner, Dirk

2013-04-01

The Artic regions are expected to be very sensitive to the currently observed climate change. When permafrost is thawing, the stored carbon becomes available again for microbial degradation, forming a potential source for the generation of carbon dioxide and methane with their positive feedback effect on the climate warming. For the prediction of future climate evolution it is, therefore, important to improve our knowledge about the microbial-driven greenhouse gas dynamics in the Siberian Arctic and their response to glacial-interglacial changes in the past. Sample material was drilled on Kurungnahk Island (Russian-German LENA expedition) located in the southern part of the Lena delta and in lake El'gygytgyn (ICDP-project) in the eastern part of Siberia. The Kurungnahk samples comprise Late Pleistocene to Holocene deposits, whereas the lake El'gygytgyn samples cover Middle to Late Pleistocene sediments. Samples were investigated applying a combined biogeochemical and microbiological approach. The methane profile of the Kurungnahk core reveals highest methane contents in the warm and wet Holocene and Late Pleistocene (LP) deposits and correlates largly to the organic carbon (TOC) contents. Archaeol concentrations, being a biomarker for past methanogenic archaea, are also high during the warm and wet Holocene and LP intervals and low during the cold and dry LP periods. This indicates that part of the methane might be produced and trapped in the past. However, biomarkers for living microorganisms (bacteria and archaea) and microbial activity measurements of methanogens point, especially, for the Holocene to a viable archaeal community, indicating a possible in-situ methane production. Furthermore, warm/wet-cold/dry climate cycles are recorded in the archaeal diversity as revealed by genetic fingerprint analysis. Although the overlying lake water buffers the temperature effect on the lake sediments, which never became permafrost, the bacterial and archaeal biomarker

Lithostratigraphy does not always equal lithology: lessons learned in communicating uncertainty from stochastic modelling glacial and post glacial deposits in Glasgow U.K.

Science.gov (United States)

Kearsey, Tim; Williams, John; Finlayson, Andrew; Williamson, Paul; Dobbs, Marcus; Kingdon, Andrew; Campbell, Diarmad

2014-05-01

Geological maps and 3D models usually depict lithostragraphic units which can comprise of many different types of sediment (lithologies). The lithostratigraphic units shown on maps and 3D models of glacial and post glacial deposits in Glasgow are substantially defined by the method of the formation and age of the unit rather than its lithological composition. Therefore, a simple assumption that the dominant lithology is the most common constituent of any stratigraphic unit is erroneous and is only 58% predictive of the actual sediment types seen in a borehole. This is problematic for non-geologist such as planners, regulators and engineers attempting to use these models to inform their decisions and can lead to such users viewing maps and models as of limited use in such decision making. We explore the extent to which stochastic modelling can help to make geological models more predictive of lithology in heterolithic units. Stochastic modelling techniques are commonly used to model facies variations in oil field models. The techniques have been applied to an area containing >4000 coded boreholes to investigate the glacial and fluvial deposits in the centre of the city of Glasgow. We test the predictions from this method by deleting percentages of the control data and re-running the simulations to determine how predictability varies with data density. We also explore the best way of displaying such stochastic models to and suggest that displaying the data as probability maps rather than a single definitive answer better illustrates the uncertainties inherent in the input data. Finally we address whether is it possible truly to be able to predict lithology in such geological facies. The innovative Accessing Subsurface Knowledge (ASK) network was recently established in the Glasgow are by the British Geological Survey and Glasgow City Council to deliver and exchange subsurface data and knowledge. This provides an idea opportunity to communicate and test a range of

The Glacial BuzzSaw, Isostasy, and Global Crustal Models

Science.gov (United States)

Levander, A.; Oncken, O.; Niu, F.

2015-12-01

The glacial buzzsaw hypothesis predicts that maximum elevations in orogens at high latitudes are depressed relative to temperate latitudes, as maximum elevation and hypsography of glaciated orogens are functions of the glacial equilibrium line altitude (ELA) and the modern and last glacial maximum (LGM) snowlines. As a consequence crustal thickness, density, or both must change with increasing latitude to maintain isostatic balance. For Airy compensation crustal thickness should decrease toward polar latitudes, whereas for Pratt compensation crustal densities should increase. For similar convergence rates, higher latitude orogens should have higher grade, and presumably higher density rocks in the crustal column due to more efficient glacial erosion. We have examined a number of global and regional crustal models to see if these predictions appear in the models. Crustal thickness is straightforward to examine, crustal density less so. The different crustal models generally agree with one another, but do show some major differences. We used a standard tectonic classification scheme of the crust for data selection. The globally averaged orogens show crustal thicknesses that decrease toward high latitudes, almost reflecting topography, in both the individual crustal models and the models averaged together. The most convincing is the western hemisphere cordillera, where elevations and crustal thicknesses decrease toward the poles, and also toward lower latitudes (the equatorial minimum is at ~12oN). The elevation differences and Airy prediction of crustal thickness changes are in reasonable agreement in the North American Cordillera, but in South America the observed crustal thickness change is larger than the Airy prediction. The Alpine-Himalayan chain shows similar trends, however the strike of the chain makes interpretation ambiguous. We also examined cratons with ice sheets during the last glacial period to see if continental glaciation also thins the crust toward

Late Devonian glacial deposits from the eastern United States signal an end of the mid-Paleozoic warm period

Science.gov (United States)

Brezinski, D.K.; Cecil, C.B.; Skema, V.W.; Stamm, R.

2008-01-01

A Late Devonian polymictic diamictite extends for more than 400??km from northeastern Pennsylvania across western Maryland and into east-central West Virginia. The matrix-supported, unbedded, locally sheared diamictite contains subangular to rounded clasts up to 2??m in diameter. The mostly rounded clasts are both locally derived and exotic; some exhibit striations, faceting, and polish. The diamictite commonly is overlain by laminated siltstone/mudstone facies associations (laminites). The laminites contain isolated clasts ranging in size from sand and pebbles to boulders, some of which are striated. The diamictite/laminite sequence is capped by massive, coarse-grained, pebbly sandstone that is trough cross-bedded. A stratigraphic change from red, calcic paleo-Vertisols in strata below the diamictite to non-calcic paleo-Spodosols and coal beds at and above the diamictite interval suggests that the climate became much wetter during deposition of the diamictite. The diamictite deposit is contemporaneous with regressive facies that reflect fluvial incision during the Late Devonian of the Appalachian basin. These deposits record a Late Devonian episode of climatic cooling so extreme that it produced glaciation in the Appalachian basin. Evidence for this episode of climatic cooling is preserved as the interpreted glacial deposits of diamictite, overlain by glaciolacustrine varves containing dropstones, and capped by sandstone interpreted as braided stream outwash. The Appalachian glacigenic deposits are contemporaneous with glacial deposits in South America, and suggest that Late Devonian climatic cooling was global. This period of dramatic global cooling may represent the end of the mid-Paleozoic warm interval that began in the Middle Silurian. ?? 2008 Elsevier B.V. All rights reserved.

Numerical simulation of ground-water flow through glacial deposits and crystalline bedrock in the Mirror Lake area, Grafton County, New Hampshire

Science.gov (United States)

Tiedeman, Claire; Goode, Daniel J.; Hsieh, Paul A.

1997-01-01

This report documents the development of a computer model to simulate steady-state (long-term average) flow of ground water in the vicinity of Mirror Lake, which lies at the eastern end of the Hubbard Brook valley in central New Hampshire. The 10-km2 study area includes Mirror Lake, the three streams that flow into Mirror Lake, Leeman's Brook, Paradise Brook, and parts of Hubbard Brook and the Pemigewasset River. The topography of the area is characterized by steep hillsides and relatively flat valleys. Major hydrogeologic units include glacial deposits, composed of till containing pockets of sand and gravel, and fractured crystalline bedrock, composed of schist intruded by granite, pegmatite, and lamprophyre. Ground water occurs in both the glacial deposits and bedrock. Precipitation and snowmelt infiltrate to the water table on the hillsides, flow downslope through the saturated glacial deposits and fractured bedrock, and discharge to streams and to Mirror Lake. The model domain includes the glacial deposits, the uppermost 150m of bedrock, Mirror Lake, the layer of organic sediments on the lake bottom, and streams and rivers within the study area. A streamflow routing package was included in the model to simulate baseflow in streams and interaction between streams and ground water. Recharge from precipitation is assumed to be areally uniform, and riparian evapotranspiration along stream banks is assumed negligible. The spatial distribution of hydraulic conductivity is represented by dividing the model domain into several zones, each having uniform hydraulic properties. Local variations in recharge and hydraulic conductivities are ignored; therefore, the simulation results characterize the general ground-water system, not local details of ground-water movement. The model was calibrated using a nonlinear regression method to match hydraulic heads measured in piezometers and wells, and baseflow in three inlet streams to Mirror Lake. Model calibration indicates that

THE PROBLEMS OF IDENTIFICATION OF THE NEO-PLEISTOCENE GLACIAL MEGA-FLOOD DEPOSITS IN THE ALTAI MOUNTAINS REGION

Directory of Open Access Journals (Sweden)

I. D. Zol’nikov

2012-01-01

Full Text Available Similarities and differences of glacial megaflood deposits and deposits of other genetic types of Gorny Altai are considered in the paper. Diluvial sedimentary complex includes (from bottom to top: debris flow facies of boulder-pebbles with giant boulders; floodplain facies of parallel laminated sands and gruss, fluvial cross-bedded pebbles facies, suspension facies of sands and silts; mud flow facies, facies secondary-dammed lake is thin parallel-laminated silts and sands. The deposits of different genetic types may appear similar in facies, textural and structural characteristics, but the geological structure and sedimentary facies architecture of the sediment complexes of various origins (the number of co-observed lithotypes and geologic nature of their relationship have a specific and recognizable.

The De Long Trough: a newly discovered glacial trough on the East Siberian continental margin

Directory of Open Access Journals (Sweden)

M. O'Regan

2017-09-01

Full Text Available Ice sheets extending over parts of the East Siberian continental shelf have been proposed for the last glacial period and during the larger Pleistocene glaciations. The sparse data available over this sector of the Arctic Ocean have left the timing, extent and even existence of these ice sheets largely unresolved. Here we present new geophysical mapping and sediment coring data from the East Siberian shelf and slope collected during the 2014 SWERUS-C3 expedition (SWERUS-C3: Swedish – Russian – US Arctic Ocean Investigation of Climate-Cryosphere-Carbon Interactions. The multibeam bathymetry and chirp sub-bottom profiles reveal a set of glacial landforms that include grounding zone formations along the outer continental shelf, seaward of which lies a  >  65 m thick sequence of glacio-genic debris flows. The glacial landforms are interpreted to lie at the seaward end of a glacial trough – the first to be reported on the East Siberian margin, here referred to as the De Long Trough because of its location due north of the De Long Islands. Stratigraphy and dating of sediment cores show that a drape of acoustically laminated sediments covering the glacial deposits is older than ∼ 50 cal kyr BP. This provides direct evidence for extensive glacial activity on the Siberian shelf that predates the Last Glacial Maximum and most likely occurred during the Saalian (Marine Isotope Stage (MIS 6.

Sedimentology of a surficial uranium deposit on North Flodelle Creek, Stevens County, Washington

International Nuclear Information System (INIS)

Macke, D.L.; Johnson, S.Y.; Otton, J.K.

1985-01-01

Surficial accumulations of uranium (up to 0.2 wt. % U/sub 3/O/sub 8/, dry basis) are currently forming in organic-rich, poorly drained sediments deposited in fluvial-lacustrine environments. Known occurrences are in northeastern Washington, northern Idaho, the Sierra Nevada, the Colorado Front Range, New Hampshire, and several areas in Canada. The first accumulation of this type to be mined is in postglacial sediments of a 10-acre boggy meadow along North Flodelle Creek in Stevens County, Washington. The meadow is flanked by hills of fine- to medium-grained two-mica quartz monzonite that are mantled by glacial drift of late Wisconsin age (about 18,000 to 11,500 yr B.P.). Relatively thick, hummocky deposits of this same glacial drift impede drainage at the lower end of the meadow. Following ice retreat, glacial sediments on the meadow floor were reworked by fluvial processes, and patches of organic-rich sediment may have formed in ice-melt depressions. About 6700 yr B.P., a blanket of Mazama ash from the Crater Lake eruption was deposited in the meadow. Shortly thereafter, a beaver dam across the lower end of the meadow further restricted drainage, and peat and organic mud accumulated in the pond behind the dam. The dam is preserved in the stratigraphic record as a sheet-like body of woody peat (with beaver-gnawed sticks) about 100m wide and 60 cm thick. After the gradual influx of sand and coarse silt had filled the pond, and the beavers had abandoned the site, fluvial deposition was reestablished

Comparing modeled and observed changes in mineral dust transport and deposition to Antarctica between the Last Glacial Maximum and current climates

Energy Technology Data Exchange (ETDEWEB)

Albani, Samuel [University of Siena, Graduate School in Polar Sciences, Siena (Italy); University of Milano-Bicocca, Department of Environmental Sciences, Milano (Italy); Cornell University, Department of Earth and Atmospheric Sciences, Ithaca, NY (United States); Mahowald, Natalie M. [Cornell University, Department of Earth and Atmospheric Sciences, Ithaca, NY (United States); Delmonte, Barbara; Maggi, Valter [University of Milano-Bicocca, Department of Environmental Sciences, Milano (Italy); Winckler, Gisela [Columbia University, Lamont-Doherty Earth Observatory, Palisades, NY (United States); Columbia University, Department of Earth and Environmental Sciences, New York, NY (United States)

2012-05-15

Mineral dust aerosols represent an active component of the Earth's climate system, by interacting with radiation directly, and by modifying clouds and biogeochemistry. Mineral dust from polar ice cores over the last million years can be used as paleoclimate proxy, and provide unique information about climate variability, as changes in dust deposition at the core sites can be due to changes in sources, transport and/or deposition locally. Here we present results from a study based on climate model simulations using the Community Climate System Model. The focus of this work is to analyze simulated differences in the dust concentration, size distribution and sources in current climate conditions and during the Last Glacial Maximum at specific ice core locations in Antarctica, and compare with available paleodata. Model results suggest that South America is the most important source for dust deposited in Antarctica in current climate, but Australia is also a major contributor and there is spatial variability in the relative importance of the major dust sources. During the Last Glacial Maximum the dominant source in the model was South America, because of the increased activity of glaciogenic dust sources in Southern Patagonia-Tierra del Fuego and the Southernmost Pampas regions, as well as an increase in transport efficiency southward. Dust emitted from the Southern Hemisphere dust source areas usually follow zonal patterns, but southward flow towards Antarctica is located in specific areas characterized by southward displacement of air masses. Observations and model results consistently suggest a spatially variable shift in dust particle sizes. This is due to a combination of relatively reduced en route wet removal favouring a generalized shift towards smaller particles, and on the other hand to an enhanced relative contribution of dry coarse particle deposition in the Last Glacial Maximum. (orig.)

State of the art in thin film thickness and deposition rate monitoring sensors

International Nuclear Information System (INIS)

Buzea, Cristina; Robbie, Kevin

2005-01-01

In situ monitoring parameters are indispensable for thin film fabrication. Among them, thickness and deposition rate control are often the most important in achieving the reproducibility necessary for technological exploitation of physical phenomena dependent on film microstructure. This review describes the types of thickness and deposition rate sensors and their theoretical and phenomenological background, underlining their performances, as well as advantages and disadvantages

Thickness control in electrophoretic deposition of WO3 nanofiber thin films for solar water splitting

International Nuclear Information System (INIS)

Fang, Yuanxing; Lee, Wei Cheat; Canciani, Giacomo E.; Draper, Thomas C.; Al-Bawi, Zainab F.; Bedi, Jasbir S.; Perry, Christopher C.; Chen, Qiao

2015-01-01

Graphical abstract: - Highlights: • A novel method combining electrospinning and electrophoretic deposition was established for the creation of nanostructured semiconductor thin films. • The created thin films displayed a high chemical stability with a controllable thickness. • The PEC water splitting performance of the thin films was optimized by fine-tuning the thickness of the films. • A maximum photoconversion efficiency was achieved by 18 μm nanofibrous thin films. - Abstract: Electrophoretic deposition (EPD) of ground electrospun WO 3 nanofibers was applied to create photoanodes with controlled morphology for the application of photoelectrochemical (PEC) water splitting. The correlations between deposition parameters and film thicknesses were investigated with theoretical models to precisely control the morphology of the nanostructured porous thin film. The photoconversion efficiency was further optimized as a function of film thickness. A maximum photoconversion efficiency of 0.924% from electrospun WO 3 nanofibers that EPD deposited on a substrate was achieved at a film thickness of 18 μm.

Experiment study on the thick GEM-like multiplier for X-ray photoelectrons energy deposition gaining

International Nuclear Information System (INIS)

Zhu Pengfei; Ye Yan; Long Yan; Cao Ningxiang; Jia Xing; Li Jianfeng

2009-01-01

The GEM is a novel detector with high gain,high time and location resolution. Imitating the structure of the GEM, a thick GEM-like multiplier which has the similar function with that of the GEM is designed and manufactured. The characteristics of the thick GEM-like multiplier increasing electron energy deposition in absorbing medium has been experimentally studied. The results indicate that the energy deposition gain of x-ray photoelectron in medium is apparent, and the maximum energy deposition can increase by more than 40%. Some suggestions of further increasing the energy deposition are given, and the future application of the way of increasing the x-ray photoelectron energy deposition by the thick GEM-like multiplier in hard x-ray imaging is prospected. (authors)

Vapor deposition on doublet airfoil substrates: Control of coating thickness and microstructure

Energy Technology Data Exchange (ETDEWEB)

Rodgers, Theron M.; Zhao, Hengbei; Wadley, Haydn N. G., E-mail: haydn@virginia.edu [Department of Materials Science and Engineering, University of Virginia, 395 McCormick Rd., P.O. Box 400745, Charlottesville, Virginia 22904 (United States)

2015-11-15

Gas jet assisted vapor deposition processes for depositing coatings are conducted at higher pressures than conventional physical vapor deposition methods, and have shown promise for coating complex shaped substrates including those with non-line-of-sight (NLS) regions on their surface. These regions typically receive vapor atoms at a lower rate and with a wider incident angular distribution than substrate regions in line-of-sight (LS) of the vapor source. To investigate the coating of such substrates, the thickness and microstructure variation along the inner (curved) surfaces of a model doublet airfoil containing both LS and NLS regions has been investigated. Results from atomistic simulations and experiments confirm that the coating's thickness is thinner in flux-shadowed regions than in other regions for all the coating processes investigated. They also indicated that the coatings columnar microstructure and pore volume fraction vary with surface location through the LS to NLS transition zone. A substrate rotation strategy for optimizing the thickness over the entire doublet airfoil surface was investigated, and led to the identification of a process that resulted in only small variation of coating thickness, columnar growth angle, and pore volume fraction on all doublet airfoil surfaces.

Takaka Fossil Cave : a stratified Late Glacial to Late Holocene deposit from Takaka Hill, New Zealand

International Nuclear Information System (INIS)

Worthy, T.H.; Roscoe, D.

2003-01-01

A rich terrestrial vertebrate fauna from the pitfall trap deposit of Takaka Fossil Cave on Takaka Hill, South Island, New Zealand, is described. Radiocarbon ages on moa bones bracket the onset of sedimentation in the site to between 12361 and 11354 14 C yrs BP. Euryapteryx geranoides was in the Late Glacial moa fauna that predates the onset of sedi-mentation in the site, but was absent in younger faunas. The moa Anomalopteryx didiformis was present in the Late Glacial fauna as well throughout the Holocene. A total of 1633 bones from 25 species of birds and a further 895 bones of 154 individuals of vertebrates other than birds (two species of frog, one tuatara, three lizards, two bats, and a rat) were identified in the total recovered fauna. A well-preserved partial skeleton of Haast's eagle (Harpagornis moorei) of Late Glacial age had severe arthritis. Unusually small specimens of Euryapteryx were morphologically diagnosed as E. geranoides, and confirmed as such by mitochondrial DNA analysis. The molluscan fauna contained two aquatic, troglobitic hydrobiids and 29 taxa of land snails. While there is little change in species diversity between lower and upper layers, there are marked changes in relative abundance of some taxa that suggest the environment was drier in the Early and Middle Holocene than it was in the Late Holocene. (author). 26 refs., 3 figs., 4 tabs

Sandy aeolian deposits and environments and their relation to climate during the Last Glacial Maximum and Lateglacial in northwest and central Europe

NARCIS (Netherlands)

Kasse, C.

2002-01-01

Periglacial aeolian sand sheets and dunes of the last glacial cover extensive areas of northwest and central Europe. Four sedimentary facies have been described that could be related to fluvio-aeolian and cryogenic processes, moisture content of the depositional surface and surface morphology.

Effects of glacial/post-glacial weathering compared with hydrothermal alteration - implications for matrix diffusion. Results from drillcore studies in porphyritic quartz monzodiorite from Aespoe SE Sweden

International Nuclear Information System (INIS)

Landstroem, Ove; Tullborg, Eva-Lena

2001-08-01

The effects of hydrothermal + subsequent low temperature alteration and glacial/post-glacial weathering have been studied in two cores of quartz monzodiorite. One core (YA 1192) was drilled into the hydrothermally altered wall rock of a water-conducting fracture exposed at 170 m depth in the access tunnel to the Aespoe Hard Rock Laboratory. The other one (Bas 1) was drilled from an outcrop with a glacially polished surface, 1 km north of the YA 1192 site. Both drill cores were sectioned into mm-thick slices perpendicular to the core axis. The fracture filling of the YA 1192 core, the weathered surface of the BAS 1 core and the different slices were analysed for major and trace elements and isotopes of U and Th. The altered zone of the YA 1192 core extends to approx. 2.5 cm from the fracture surface. The alteration (mainly plagioclase → albite + sericite + epidote) has resulted in a higher porosity and formation of sorbing secondary minerals (e.g. sericite), favouring matrix diffusion. Increased Br concentrations in the altered zone are indicative of saline water in pores and micro fractures i.e. the presence of a diffusion medium. 234U/238U activity ratios > 1 and increased Cs in the altered zone are then interpreted as diffusion of U and Cs from fracture groundwater and subsequent sorption. The U migration is geologically recent (< 1 Ma). The 2.5 cm altered zone (corresponding to the zone of active matrix diffusion) significantly exceeds the visible red staining zone (0.5 cm) caused by hematite/FeOOH micrograins, emphasizing the need of microscopy to identify zones of alteration. The conspicuous weathering at the BAS 1 site is confined to a narrow rim of the bedrock surface (approx. 0.2-0.5 cm thick). Mass balance calculations for this rim (based on immobility of K) indicate that mechanical erosion has dominated over chemical dissolution processes (is roughly 10 times greater). The chemical weathering has affected mainly plagioclase and chlorite resulting in

The ESR age of Portlandia arctica shells from glacial deposits of Central Latvia . an answer to a controversy on the age and genesis of their enclosing sediments

Science.gov (United States)

Molodkov, Anatoly; Dreimanis, Aleksis; ĀBoltiņš, Ojars; Raukas, Anto

The occurrence of Portlandia arctica shells in glacigenic sediments of Central Latvia had created a controversy in many publications about (1) their age ranging from the Holsteinian to the Late Weichselian and (2) the genesis of their enclosing sediments: glacial, glaciomarine or marine. Our reinvestigation of the main object of controversy, the Lı¯čupe site, leads to a conclusion that the sedimentary package of diamictons, clays and sands containing Portlandia arctica shells and marine microfossils is a large glacial raft that had been transported and deposited by the Riga lobe during the Weichselian. The electron spin resonance (ESR) ages on five sets of Portlandia arctica shells from the Lı¯čupe and Daugmales Tomēni sites range from 86.0±6.8 to 105.0±9.2 ka BP. These ESR age determinations and the cool climate indicators of the associated microflora and microfauna suggest that their source sediments, probably in the Gulf of Riga, are marine clays of Early Weichselian age, probably correlative to the Brørup Interstadial. In Central Latvia Portlandia arctica shells and their enclosing clay occur resedimented or translocated in glacial deposits during Weichselian glacial advances.

Stratigraphy and palaeoclimatic significance of Late Quaternary loess-palaeosol sequences of the Last Interglacial-Glacial cycle in central Alaska

Science.gov (United States)

Muhs, D.R.; Ager, T.A.; Bettis, E. Arthur; McGeehin, J.; Been, J.M.; Beget, J.E.; Pavich, M.J.; Stafford, Thomas W.; Stevens, D.A.S.P.

2003-01-01

Loess is one of the most widespread subaerial deposits in Alaska and adjacent Yukon Territory and may have a history that goes back 3 Ma. Based on mineralogy and major and trace element chemistry, central Alaskan loess has a composition that is distinctive from other loess bodies of the world, although it is quartz-dominated. Central Alaskan loess was probably derived from a variety of rock types, including granites, metabasalts and schists. Detailed stratigraphic data and pedologic criteria indicate that, contrary to early studies, many palaeosols are present in central Alaskan loess sections. The buried soils indicate that loess sedimentation was episodic, or at least rates of deposition decreased to the point where pedogenesis could keep ahead of aeolian input. As in China, loess deposition and pedogenesis are likely competing processes and neither stops completely during either phase of the loess/soil formation cycle. Loess deposition in central Alaska took place before, and probably during the last interglacial period, during stadials of the mid-Wisconsin period, during the last glacial period and during the Holocene. An unexpected result of our geochronological studies is that only moderate loess deposition took place during the last glacial period. Our studies lead us to conclude that vegetation plays a key role in loess accumulation in Alaska. Factors favouring loess production are enhanced during glacial periods but factors that favour loess accumulation are diminished during glacial periods. The most important of these is vegetation; boreal forest serves as an effective loess trap, but sparsely distributed herb tundra does not. Thus, thick accumulations of loess should not be expected where tundra vegetation was dominant and this is borne out by modern studies near the treeline in central Alaska. Much of the stratigraphic diversity of North American loess, including that found in the Central Lowlands, the Great Plains, and Alaska is explained by a new

Thickness control in electrophoretic deposition of WO{sub 3} nanofiber thin films for solar water splitting

Energy Technology Data Exchange (ETDEWEB)

Fang, Yuanxing; Lee, Wei Cheat; Canciani, Giacomo E.; Draper, Thomas C.; Al-Bawi, Zainab F. [Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ (United Kingdom); Bedi, Jasbir S. [School of Public Health & Zoonoses, Guru Angad Dev Veterinary and Animal Sciences University, Ludhiana 141004 Punjab (India); Perry, Christopher C. [Division of Biochemistry, School of Medicine, Loma Linda University, Loma Linda, CA 92350 (United States); Chen, Qiao, E-mail: qiao.chen@sussex.ac.uk [Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ (United Kingdom)

2015-12-15

Graphical abstract: - Highlights: • A novel method combining electrospinning and electrophoretic deposition was established for the creation of nanostructured semiconductor thin films. • The created thin films displayed a high chemical stability with a controllable thickness. • The PEC water splitting performance of the thin films was optimized by fine-tuning the thickness of the films. • A maximum photoconversion efficiency was achieved by 18 μm nanofibrous thin films. - Abstract: Electrophoretic deposition (EPD) of ground electrospun WO{sub 3} nanofibers was applied to create photoanodes with controlled morphology for the application of photoelectrochemical (PEC) water splitting. The correlations between deposition parameters and film thicknesses were investigated with theoretical models to precisely control the morphology of the nanostructured porous thin film. The photoconversion efficiency was further optimized as a function of film thickness. A maximum photoconversion efficiency of 0.924% from electrospun WO{sub 3} nanofibers that EPD deposited on a substrate was achieved at a film thickness of 18 μm.

Discovery of a landscape-wide drape of late-glacial aeolian silt in the western Northern Calcareous Alps (Austria): First results and implications

Science.gov (United States)

Gild, Charlotte; Geitner, Clemens; Sanders, Diethard

2018-01-01

Aeolian deposits record palaeoenvironmental conditions and may coin soil properties. Whereas periglacial loess is extensively investigated for 200 years, the study of the intramontane wind-blown deposits of the Alps has just stuttered along. Herein, we describe a drape of polymictic siliciclastic silt interpreted as an aeolian deposit that veneers extensive areas in the western Northern Calcareous Alps (NCA), from kames terraces near valley floors up to last-glacial nunataks. The NCA - part of the Eastern Alps mountain range - consist mainly of Triassic carbonate rocks; these are overlain by deposits of the Last Glacial Maximum (LGM) and its deglacial-paraglacial aftermath (e.g., glacial tills, fluvio-lacustrine successions, alluvial fans, scree slopes) - and a regional drape of polymictic silt newly described herein. The drape is typically a few decimeters in thickness and slightly modified by soil formation; it consists mainly of well-sorted silt of quartz, feldspars, phyllosilicates (muscovite, chlorite, biotite), amphiboles and, rarely, calcite or dolomite. The drape is unrelated to the substrate: it overlies carbonate bedrock and - in lateral continuity - abandoned deposystems such as colluvial slopes of redeposited till, kames, alluvial fans, scree slopes, and rock avalanche deposits. The drape was spotted from near the present valley floors up to LGM nunataks, over a vertical range of some 2000 m; it is also present in catchments of the NCA that were not overridden by far-travelled ice streams and that lack metamorphic rock fragments. Two OSL quartz ages of the drape from two distinct locations (18.77 ± 1.55 ka; 17.81 ± 1.68 ka) fall into the early Alpine late-glacial interval shortly after the collapse of pleniglacial ice streams; this fits with geological and geomorphological evidence, respectively, that the drape should be of early late-glacial age, and that it accumulated during a specific interval of time. In the NCA, localized minor deposition of

Glacial and Quaternary geology of the northern Yellowstone area, Montana and Wyoming

Science.gov (United States)

Pierce, Kenneth L.; Licciardi, Joseph M.; Krause, Teresa R.; Whitlock, Cathy

2014-01-01

This field guide focuses on the glacial geology and paleoecology beginning in the Paradise Valley and progressing southward into northern Yellowstone National Park. During the last (Pinedale) glaciation, the northern Yellowstone outlet glacier flowed out of Yellowstone Park and down the Yellowstone River Valley into the Paradise Valley. The field trip will traverse the following Pinedale glacial sequence: (1) deposition of the Eightmile terminal moraines and outwash 16.5 ± 1.4 10Be ka in the Paradise Valley; (2) glacial recession of ~8 km and deposition of the Chico moraines and outwash 16.1 ± 1.7 10Be ka; (3) glacial recession of 45 km to near the northern Yellowstone boundary and moraine deposition during the Deckard Flats readjustment 14.2 ± 1.2 10Be ka; and (4) glacial recession of ~37 km and deposition of the Junction Butte moraines 15.2 ± 1.3 10Be ka (this age is a little too old based on the stratigraphic sequence). Yellowstone's northern range of sagebrush-grasslands and bison, elk, wolf, and bear inhabitants is founded on glacial moraines, sub-glacial till, and outwash deposited during the last glaciation. Floods released from glacially dammed lakes and a landslide-dammed lake punctuate this record. The glacial geologic reconstruction was evaluated by calculation of basal shear stress, and yielded the following values for flow pattern in plan view: strongly converging—1.21 ± 0.12 bars (n = 15); nearly uniform—1.04 ± 0.16 bars (n = 11); and strongly diverging—0.84 ± 0.14 bars (n = 16). Reconstructed mass balance yielded accumulation and ablation each of ~3 km3/yr, with glacial movement near the equilibrium line altitude dominated by basal sliding. Pollen and charcoal records from three lakes in northern Yellowstone provide information on the postglacial vegetation and fire history. Following glacial retreat, sparsely vegetated landscapes were colonized first by spruce parkland and then by closed subalpine forests. Regional fire activity

A simple semi-empirical approach to model thickness of ash-deposits for different eruption scenarios

Directory of Open Access Journals (Sweden)

A. O. González-Mellado

2010-11-01

Full Text Available The impact of ash-fall on people, buildings, crops, water resources, and infrastructure depends on several factors such as the thickness of the deposits, grain size distribution and others. Preparedness against tephra falls over large regions around an active volcano requires an understanding of all processes controlling those factors, and a working model capable of predicting at least some of them. However, the complexity of tephra dispersion and sedimentation makes the search of an integral solution an almost unapproachable problem in the absence of highly efficient computing facilities due to the large number of equations and unknown parameters that control the process. An alternative attempt is made here to address the problem of modeling the thickness of ash deposits as a primary impact factor that can be easily communicated to the public and decision-makers. We develop a semi-empirical inversion model to estimate the thickness of non-compacted deposits produced by an explosive eruption around a volcano in the distance range 4–150 km from the eruptive source.

The model was elaborated from the analysis of the geometric distribution of deposit thickness of 14 world-wide well-documented eruptions. The model was initially developed to depict deposits of potential eruptions of Popocatépetl and Colima volcanoes in México, but it can be applied to any volcano. It has been designed to provide planners and Civil Protection authorities of an accurate perception of the ash-fall deposit thickness that may be expected for different eruption scenarios. The model needs to be fed with a few easy-to-obtain parameters, namely, height of the eruptive column, duration of the explosive phase, and wind speed and direction, and its simplicity allows it to run in any platform, including a personal computers and even a notebook. The results may be represented as tables, two dimensional thickness-distance plots, or isopach maps using any available

Thickness of Lipid Deposition on Oral Surfaces Depending on Oil Content and Its Influence on Mouthfeel Perception

Directory of Open Access Journals (Sweden)

Urška Pivk Kupirovič

2012-01-01

Full Text Available Lipid content in food strongly influences food perception on the level of textural properties. Lipids in contact with the tongue and palate are substantially responsible for the sensory impact of a product. The aim of this study is to investigate the impact of oil content on the thickness of lipid deposition on oral surface as well as on the mouthfeel perception. The fluorescent probe method was used to study the thickness of lipid deposition on oral surface. We observed an increase in the thickness of lipid deposition depending on the increase of oil content in oil/water dispersions. Clear correlation was shown between the thickness of lipid deposition on oral surfaces and the perception of mouthfeel. A direct measure of undisrupted deposition of food components on oral surface contributes to the understanding of the behaviour of food components in the mouth and their influence on mouthfeel perception.

THE ROLE OF KETTLE HOLES AS LOCAL SEDIMENTARY RESERVOIRS OF THE EARLY POST-GLACIAL LANDSCAPE OF SUWAŁKI LANDSCAPE PARK

Directory of Open Access Journals (Sweden)

Krzysztof Micun

2014-11-01

Full Text Available The study is an attempt to determine the size of sedimentation at the bottoms of the small kettle holes of Suwałki Landscape Park as well as the deposits that fill them. The size and the type of the transformations occurring in the kettle holes during the Holocene were determined on the basis of conducted analyses. The presence of allochtonic mineral deposits and autochtonic lacustrine and biogenic deposits was affirmed. The first group consisted of loam colluvium with a maximum thickness of up to 1m. The other one contains lacustrine clays and silts with a maximum thickness of several tens of centimeters and gytjas and peats with a total thickness of up to 9 m. Sediments’ sequence in Snołda, Łuśnin and Linówek depressions indicated a secondary nature of the colluvium deposition in relations to the biogenic acumulation that took place throughout the Holocene. Hillslope sediments accumulation intensified only in times of economic activity growth in the area. Steep gradients of slopes and considerable depth of kettle holes favor the development of hillslope processes. The material accumulated in the depressions remains immobilised. This limits the spatial extent of the denudation and thus stabilises the morphology of early post-glacial landscape.

The high-level marine shell-bearing deposits of Clava, Inverness-shire, and their origin as glacial rafts

Science.gov (United States)

Merritt, J. W.

The enigmatic high-level, till-covered, cold water marine shell-bearing deposits at Clava, Inverness-shire, are described systematically in the light of new observations made at sites documented in the literature. The marine deposits, named here as the Clava Shelly Formation, include three members, the unfossiliferous Clava sand, the underlying Clava shelly clay and a shelly diamicton known as the Clava shelly till. The first two members form a conformable coarsening-upwards sequence containing a shallow water, high-boreal to low-Arctic fauna and flora. The Clava shelly till is essentially glacially re-sedimented glaciomarine clay containing a sparse fauna, but its stratigraphic relationship and age are not absolutely clear. The shelly clay is ascribed to a Mid-Devensian interstadial episode on the basis of amino-acid dating. It is concluded that the Clava shelly clay, and several discrete masses of Clava sand and shelly till, are glacially transported allochthons derived from the Great Glen. The rafts were probably detached as a result of high pore water pressure building up in laterally restricted aquifers beneath a confined glacier that flowed north-eastwards across the Loch Ness basin. This glacier was deflected eastwards and upwards towards Clava by ice flowing from the northern Highlands along the Beauly Firth during the build-up of the last Scottish ice-sheet. The rafts were stacked at the ice margin when the glacier entered the Nairn Valley before being overriden by the expanding ice-sheet.

Distribution and Aggregate Thickness of Salt Deposits of the United States

Data.gov (United States)

U.S. Environmental Protection Agency — The map shows the distribution and aggregate thickness of salt deposits of the United States. This information is from contour map sheets, scanned and processed for...

Map showing thickness of saturated Quaternary deposits, Sugar House quadrangle, Salt Lake County, Utah, February 1972

Science.gov (United States)

Mower, R.W.

1973-01-01

Saturated Quaternary deposits in the Sugar Horse quadrangle supply significant quantities of water to wells from which water is withdrawn for domestic, municipal, industrial, and irrigation uses. The deposits consist of clay, silt, sand, and gravel; individual beds range from a few inches to several tens of feet thick. The principal aquifer, which is almost completely within the Quaternary deposits, supplied about 4 percent, or 9,000 acre-feet, of the municipal and industrial water used annually in Salt Lake County during 1964-68.As a general rule, more water is stored and more water will be yielded to a well where aquifers are thicker. This map can be used as a general guide to those areas where greatest amounts of water are stored in the aquifer, and where yields to wells may be greater. Local variations in the ability of saturated deposits to transmit water can alter the general relationship between aquifer thickness and yield of wells.The thickness of saturated Quaternary deposits within the area of the Sugar Horse quadrangle ranges from zero to about 650 feet, as shown on the map. The thickest section of these deposits is near the southwestern corner of the quadrangle, and the thinnest section is along the mountain front adjacent to the approximate eastern limit of saturated Quaternary deposits.The thickness of saturated Quaternary deposits shown on this map is based on drillers’ logs for 55 deep wells (which show the thickness of the Quaternary deposits) and on water-level measurements made in February 1972 in wells in unconfined shallow aquifers.Reports in the following list of selected references contain other information about the saturated Quaternary deposits in this and adjacent parts of Jordan Valley, Utah. The basic-data reports and releases contain well logs, water-level measurements, and other types of basic ground-water data. The interpretive repots contain discussions of the occurrence of ground water, tests to determine hydraulic properties of

Earth's glacial record and its tectonic setting

Science.gov (United States)

Eyles, N.

1993-09-01

clearly established glacial parentage. The same remarks apply to many successions of laminated and thin-bedded facies interpreted as "varvites". Despite suggestions of much lower values of solar luminosity (the weak young sun hypothesis), the stratigraphic record of Archean glaciations is not extensive and may be the result of non-preservation. However, the effects of very different Archean global tectonic regimes and much higher geothermal heat flows, combined with a Venus-like atmosphere warmed by elevated levels of CO 2, cannot be ruled out. The oldest unambiguous glacial succession in Earth history appears to be the Early Proterozoic Gowganda Formation of the Huronian Supergroup in Ontario; the age of this event is not well-constrained but glaciation coincided with regional rifting, and may be causally related to, oxygenation of Earth's atmosphere just after 2300 Ma. New evidence that oxygenation is tectonically, not biologically driven, stresses the intimate relationship between plate tectonics, evolution of the atmosphere and glaciation. Global geochemical controls, such as elevated atmospheric CO 2 levels, may be responsible for a long mid-Proterozoic non-glacial interval after 2000 Ma that was terminated by the Late Proterozoic glaciations just after 800 Ma. A persistent theme in both Late Proterozoic and Phanerozoic glaciations is the adiabatic effect of tectonic uplift, either along collisional margins or as a result of passive margin uplifts in areas of extended crust, as the trigger for glaciation; the process is reinforced by global geochemical feedback, principally the drawdown of atmospheric CO 2 and Milankovitch "astronomical" forcing but these are unlikely, by themselves, to inititiate glaciation. The same remarks apply to late Cenozoic glaciations. Late Proterozoic glacially-influenced strata occur on all seven continents and fall into two tectonostratigraphic types. In the first category are thick sucessions of turbidites and mass flows deposited along

The impact of lateral variations in lithospheric thickness on glacial isostatic adjustment in West Antarctica

Science.gov (United States)

Nield, Grace A.; Whitehouse, Pippa L.; van der Wal, Wouter; Blank, Bas; O'Donnell, John Paul; Stuart, Graham W.

2018-04-01

Differences in predictions of Glacial Isostatic Adjustment (GIA) for Antarctica persist due to uncertainties in deglacial history and Earth rheology. The Earth models adopted in many GIA studies are defined by parameters that vary in the radial direction only and represent a global average Earth structure (referred to as 1D Earth models). Over-simplifying actual Earth structure leads to bias in model predictions in regions where Earth parameters differ significantly from the global average, such as West Antarctica. We investigate the impact of lateral variations in lithospheric thickness on GIA in Antarctica by carrying out two experiments that use different rheological approaches to define 3D Earth models that include spatial variations in lithospheric thickness. The first experiment defines an elastic lithosphere with spatial variations in thickness inferred from seismic studies. We compare the results from this 3D model with results derived from a 1D Earth model that has a uniform lithospheric thickness defined as the average of the 3D lithospheric thickness. Irrespective of deglacial history and sub-lithospheric mantle viscosity, we find higher gradients of present-day uplift rates (i.e. higher amplitude and shorter wavelength) in West Antarctica when using the 3D models, due to the thinner-than-1D-average lithosphere prevalent in this region. The second experiment uses seismically-inferred temperature as input to a power-law rheology thereby allowing the lithosphere to have a viscosity structure. Modelling the lithosphere with a power-law rheology results in behaviour that is equivalent to a thinner-lithosphere model, and it leads to higher amplitude and shorter wavelength deformation compared with the first experiment. We conclude that neglecting spatial variations in lithospheric thickness in GIA models will result in predictions of peak uplift and subsidence that are biased low in West Antarctica. This has important implications for ice-sheet modelling

Glacial vs. Interglacial Period Contrasts in Midlatitude Fluvial Systems, with Examples from Western Europe and the Texas Coastal Plain

Science.gov (United States)

Blum, M.

2001-12-01

Mixed bedrock-alluvial valleys are the conveyor belts for sediment delivery to passive continental margins. Mapping, stratigraphic and sedimentologic investigations, and development of geochronological frameworks for large midlatitude rivers of this type, in Western Europe and the Texas Coastal Plain, provide for evaluation of fluvial responses to climate change over the last glacial-interglacial period, and the foundations for future quantitative evaluation of long profile evolution, changes through time in flood magnitude, and changes in storage and flux of sediments. This paper focuses on two issues. First, glacial vs. interglacial period fluvial systems are fundamentally different in terms of channel geometry, depositional style, and patterns of sediment storage. Glacial-period systems were dominated by coarse-grained channel belts (braided channels in Europe, large-wavelength meandering in Texas), and lacked fine-grained flood-plain deposits, whereas Holocene units, especially those of late Holocene age, contain appreciable thicknesses of flood-plain facies. Hence, extreme overbank flooding was not significant during the long glacial period, most flood events were contained within bankfull channel perimeters, and fine sediments were bypassed through the system to marine basins. By contrast, extreme overbank floods have been increasingly important during the relatively short Holocene, and a significant volume of fine sediment is sequestered in flood-plain settings. Second, glacial vs. interglacial systems exhibit different amplitudes and frequencies of fluvial adjustment to climate change. High-amplitude but low-frequency adjustments characterized the long glacial period, with 2-3 extended periods of lateral migration and sediment storage puncuated by episodes of valley incision. Low-amplitude but high-frequency adjustments have been more typical of the short Holocene, when there has been little net valley incision or net changes in sediment storage, but

A fluvioglacial and gaciolacustrine deltaic depositional model for Permo-Carboniferous coals of the northeastern Karoo Basin, South Africa

Energy Technology Data Exchange (ETDEWEB)

Smith G, Le Blanc; Eriksson, K A

1979-01-01

With the northward retreat of the late Palaeozoic Gondwana ice sheet a series of glacial valleys, partially filled with diamictite, dominated the landscape along the northern edge of the Karoo basin in South Africa. Consequent outwash sediments accumulated as fluvioglacial and glaciolacustrine deltaic deposits. Density underflow generated turbidity currents from which bottomset sediments were deposited. These comprise distal varved siltstones and shales, stratified pebbly-mudstone with dropstones, and proximal ripple drift cross-laminated sandstones and siltstones. Overlying outwash plain conglomerates and sandstones constitute the topset deposits. Upon abandonment of the outwash plain, shallow-rooted Arctic vegetation developed. Resulting peats exceeded 10 m in thickness and constituted precursors to coal seams in which variations in ash content are attributed to overbank splaying from recognisable anastomosing channels within the coal swamps. This study has illustrated a characteristic paraglacial sedimentation sequence, maximum depositional rates occur immediately after glacial retreat followed by decelerating sedimentation rates through time, leading finally to the development of extensive peats. (29 refs.)

The Arctic: Glacial Refugium or Area of Secondary Contact? Inference from the Population Genetic Structure of the Thick-Billed Murre (Uria lomvia), with Implications for Management.

Science.gov (United States)

Tigano, Anna; Damus, Martin; Birt, Tim P; Morris-Pocock, Jamie A; Artukhin, Yuri B; Friesen, Vicki L

2015-01-01

Quaternary glaciations affected the distribution of many species. Here, we investigate whether the Arctic represented a glacial refugium during the Last Glacial Maximum or an area of secondary contact following the ice retreat, by analyzing the genetic population structure of the thick-billed murre (Uria lomvia), a seabird that breeds throughout the North Atlantic, North Pacific and Arctic Oceans. The thick-billed murre is a species of socio-economic importance and faces numerous threats including hunting, oil pollution, gill netting, and climate change. We compared variation in the mitochondrial DNA (mtDNA) control region (n = 424), supplemented by 4 microsatellite loci (n = 445), among thick-billed murres sampled throughout their range. MtDNA data indicated that colonies comprise 4 genetically differentiated groups (Φst = 0.11-0.81): 1) Atlantic Ocean plus New Siberian Islands region, 2) Cape Parry, 3) Chukchi Sea, and 4) Pacific Ocean. Microsatellite variation differed between Atlantic and Pacific populations. Otherwise, little substructure was found within either ocean. Atlantic and Pacific populations appear to have been genetically isolated since the last interglacial period and should be considered separate evolutionary significant units for management. The Chukchi Sea and Cape Parry appear to represent areas of secondary contact, rather than arctic refugial populations. © The American Genetic Association 2015. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Rome in its setting. Post-glacial aggradation history of the Tiber River alluvial deposits and tectonic origin of the Tiber Island

Science.gov (United States)

Motta, Laura; Brock, Andrea L.; Macrì, Patrizia; Florindo, Fabio; Sadori, Laura; Terrenato, Nicola

2018-01-01

The Tiber valley is a prominent feature in the landscape of ancient Rome and an important element for understanding its urban development. However, little is known about the city’s original setting. Our research provides new data on the Holocene sedimentary history and human-environment interactions in the Forum Boarium, the location of the earliest harbor of the city. Since the Last Glacial Maximum, when the fluvial valley was incised to a depth of tens of meters below the present sea level, 14C and ceramic ages coupled with paleomagnetic analysis show the occurrence of three distinct aggradational phases until the establishment of a relatively stable alluvial plain at 6–8 m a.s.l. during the late 3rd century BCE. Moreover, we report evidence of a sudden and anomalous increase in sedimentation rate around 2600 yr BP, leading to the deposition of a 4-6m thick package of alluvial deposits in approximately one century. We discuss this datum in the light of possible tectonic activity along a morpho-structural lineament, revealed by the digital elevation model of this area, crossing the Forum Boarium and aligned with the Tiber Island. We formulate the hypothesis that fault displacement along this structural lineament may be responsible for the sudden collapse of the investigated area, which provided new space for the observed unusually large accumulation of sediments. We also posit that, as a consequence of the diversion of the Tiber course and the loss in capacity of transport by the river, this faulting activity triggered the origin of the Tiber Island. PMID:29590208

Late Proterozoic glacially controlled shelf sequences in western Mali (west Africa)

Science.gov (United States)

Deynoux, M.; Prousti, J. N.; Simon, B.

The Late Proterozoic deposits of the Bakoye Group (500 m) in western Mali constitute a remarkable example of a glacially influenced sedimentary record on an epicratonic platform. They are composed of alternating marine and continental formations which represent accumulation in a basin located in the vicinity of upland areas covered by ice sheets. One of these formations (the Ba4 Formation), which is the focus of this study, is composed of three major units. The basal Unit 1 is made up of carbonaceous coarse to fine grained sandstones which are organized in fining upward sequences and which comprise lenticular diamictite intercalations. This Unit is considered to represent the fore slope gravity flows of a subaqueous ice-cootact fan fed by meltwater streams (≪glacioturbidites≫). Unit 2 is made up of coarse to fine grained sandstones in a highly variable association of facies. This Unit is characterized by the abundance of wave ripples associated with convolute beddings. planar or wavy beddings and tabular or hummocky crossbeddings in a general shallowing upward trend. It also comprises evidence of gravity processes including debris flows and large slumped sandstone bodies. Unit 2 represents the progressive filling of the Ba4 basin and reflects the combined effect of glacially induced eustatism and isostacy during a phase of glacial retreat. The basal part of Unit 3 is made up of a succession (a few meters thick) of conglomerates, diamictites, sandstones, siltstones or carbonates lying on an erosional unconformity marked by periglacial frost wedges. The upper part of Unit 3 is thicker (100-150 m) and onlaps on these basal facies with a succession of sandstone bars exhibiting swaley and hummocky crossbeddings, large cut and fill structures, and planar laminations. Unit 3 is strongly transgressive, the lower shoreface and backshore deposits include algal mats and are onlapped by sand ridges emplaced in a high energy upper to middle shoreface environment. Overall

The Effect of Film Thickness on the Gas Sensing Properties of Ultra-Thin TiO₂ Films Deposited by Atomic Layer Deposition.

Science.gov (United States)

Wilson, Rachel L; Simion, Cristian Eugen; Blackman, Christopher S; Carmalt, Claire J; Stanoiu, Adelina; Di Maggio, Francesco; Covington, James A

2018-03-01

Analyte sensitivity for gas sensors based on semiconducting metal oxides should be highly dependent on the film thickness, particularly when that thickness is on the order of the Debye length. This thickness dependence has previously been demonstrated for SnO₂ and inferred for TiO₂. In this paper, TiO₂ thin films have been prepared by Atomic Layer Deposition (ALD) using titanium isopropoxide and water as precursors. The deposition process was performed on standard alumina gas sensor platforms and microscope slides (for analysis purposes), at a temperature of 200 °C. The TiO₂ films were exposed to different concentrations of CO, CH₄, NO₂, NH₃ and SO₂ to evaluate their gas sensitivities. These experiments showed that the TiO₂ film thickness played a dominant role within the conduction mechanism and the pattern of response for the electrical resistance towards CH₄ and NH₃ exposure indicated typical n -type semiconducting behavior. The effect of relative humidity on the gas sensitivity has also been demonstrated.

Measurement of thickness of film deposited on the plasma-facing wall in the QUEST tokamak by colorimetry.

Science.gov (United States)

Wang, Z; Hanada, K; Yoshida, N; Shimoji, T; Miyamoto, M; Oya, Y; Zushi, H; Idei, H; Nakamura, K; Fujisawa, A; Nagashima, Y; Hasegawa, M; Kawasaki, S; Higashijima, A; Nakashima, H; Nagata, T; Kawaguchi, A; Fujiwara, T; Araki, K; Mitarai, O; Fukuyama, A; Takase, Y; Matsumoto, K

2017-09-01

After several experimental campaigns in the Kyushu University Experiment with Steady-state Spherical Tokamak (QUEST), the originally stainless steel plasma-facing wall (PFW) becomes completely covered with a deposited film composed of mixture materials, such as iron, chromium, carbon, and tungsten. In this work, an innovative colorimetry-based method was developed to measure the thickness of the deposited film on the actual QUEST wall. Because the optical constants of the deposited film on the PFW were position-dependent and the extinction coefficient k 1 was about 1.0-2.0, which made the probing light not penetrate through some thick deposited films, the colorimetry method developed can only provide a rough value range of thickness of the metal-containing film deposited on the actual PFW in QUEST. However, the use of colorimetry is of great benefit to large-area inspections and to radioactive materials in future fusion devices that will be strictly prohibited from being taken out of the limited area.

Terminal zone glacial sediment transfer at a temperate overdeepened glacier system

Science.gov (United States)

Swift, D. A.; Cook, S. J.; Graham, D. J.; Midgley, N. G.; Fallick, A. E.; Storrar, R.; Toubes Rodrigo, M.; Evans, D. J. A.

2018-01-01

Continuity of sediment transfer through glacial systems is essential to maintain subglacial bedrock erosion, yet transfer at temperate glaciers with overdeepened beds, where subglacial fluvial sediment transport should be greatly limited by adverse slopes, remains poorly understood. Complex multiple transfer processes in temperate overdeepened systems has been indicated by the presence of large frontal moraine systems, supraglacial debris of mixed transport origin, thick basal ice sequences, and englacial thrusts and eskers. At Svínafellsjökull, thrusts comprising decimetre-thick debris-rich bands of stratified facies ice of basal origin, with a coarser size distribution and higher clast content than that observed in basal ice layers, contribute substantially to the transfer of subglacial material in the terminal zone. Entrainment and transfer of material occurs by simple shear along the upper surface of bands and by strain-induced deformation of stratified and firnified glacier ice below. Thrust material includes rounded and well-rounded clasts that are also striated, indicating that fluvial bedload is deposited as subglacial channels approach the overdeepening and then entrained along thrusts. Substantial transfer also occurs within basal ice, with facies type and debris content dependent on the hydrological connectedness of the adverse slope. A process model of transfer at glaciers with terminal overdeepenings is proposed, in which the geometry of the overdeepening influences spatial patterns of ice deformation, hydrology, and basal ice formation. We conclude that the significance of thrusting in maintaining sediment transfer continuity has likely been overlooked by glacier sediment budgets and glacial landscape evolution studies.

The Effects of Two Thick Film Deposition Methods on Tin Dioxide Gas Sensor Performance

OpenAIRE

Bakrania, Smitesh D.; Wooldridge, Margaret S.

2009-01-01

This work demonstrates the variability in performance between SnO2 thick film gas sensors prepared using two types of film deposition methods. SnO2 powders were deposited on sensor platforms with and without the use of binders. Three commonly utilized binder recipes were investigated, and a new binder-less deposition procedure was developed and characterized. The binder recipes yielded sensors with poor film uniformity and poor structural integrity, compared to the binder-less deposition meth...

Direct fabrication of integrated 3D Au nanobox arrays by sidewall deposition with controllable heights and thicknesses

Energy Technology Data Exchange (ETDEWEB)

Cha, Nam-Goo; Lee, Bong Kuk; Kanki, Teruo; Lee, Hea Yeon; Kawai, Tomoji; Tanaka, Hidekazu, E-mail: h-tanaka@sanken.osaka-u.ac.j [Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan)

2009-09-30

This paper provides a unique strategy for controlling integrated hollow nanostructure arrays such as boxes or pillars at the nanometer scale. The key merit of this technique is that it can overcome resolution limits by sidewall deposition and deposit various materials using a sputtering method. The sputtering method can be replaced by other dry deposition techniques such as pulsed laser deposition (PLD) for complex functional materials. Furthermore, it can produce low-cost large-area fabrication and high reproducibility using the NIL (nanoimprint lithograph) process. The fabrication method consists of a sequence of bilayer spin-coating, UV-NIL, RIE (reactive ion etching), sputtering, ion milling and piranha cleaning processes. By changing the deposition time and molds, various thicknesses and shapes can be fabricated, respectively. Furthermore, the fabricated Au box nanostructure has a bending zone of the top layer and a {approx}17 nm undercut of the bottom layer as observed by SEM (scanning electron microscope). The sidewall thickness was changed from 12 to 61 nm by controlling the deposition time, and was investigated to understand the relationship with blanket thicknesses and geometric effects. The calculated sidewall thickness matched well with experimental results. Using smaller hole-patterned molds, integrated nanobox arrays, with inner squares measuring {approx}160 nm, and nanopillar arrays, with inside pores measuring {approx}65 nm, were fabricated under the same conditions.

In and out of glacial extremes by way of dust‑climate feedbacks

Science.gov (United States)

Shaffer, Gary; Lambert, Fabrice

2018-03-01

Mineral dust aerosols cool Earth directly by scattering incoming solar radiation and indirectly by affecting clouds and biogeochemical cycles. Recent Earth history has featured quasi-100,000-y, glacial‑interglacial climate cycles with lower/higher temperatures and greenhouse gas concentrations during glacials/interglacials. Global average, glacial maxima dust levels were more than 3 times higher than during interglacials, thereby contributing to glacial cooling. However, the timing, strength, and overall role of dust‑climate feedbacks over these cycles remain unclear. Here we use dust deposition data and temperature reconstructions from ice sheet, ocean sediment, and land archives to construct dust‑climate relationships. Although absolute dust deposition rates vary greatly among these archives, they all exhibit striking, nonlinear increases toward coldest glacial conditions. From these relationships and reconstructed temperature time series, we diagnose glacial‑interglacial time series of dust radiative forcing and iron fertilization of ocean biota, and use these time series to force Earth system model simulations. The results of these simulations show that dust‑climate feedbacks, perhaps set off by orbital forcing, push the system in and out of extreme cold conditions such as glacial maxima. Without these dust effects, glacial temperature and atmospheric CO2 concentrations would have been much more stable at higher, intermediate glacial levels. The structure of residual anomalies over the glacial‑interglacial climate cycles after subtraction of dust effects provides constraints for the strength and timing of other processes governing these cycles.

Thickness dependent growth of low temperature atomic layer deposited zinc oxide films

International Nuclear Information System (INIS)

Montiel-González, Z.; Castelo-González, O.A.; Aguilar-Gama, M.T.; Ramírez-Morales, E.; Hu, H.

2017-01-01

Highlights: • Polycrystalline columnar ZnO thin films deposited by ALD at low temperatures. • Higher deposition temperature leads to a greater surface roughness in the ALD ZnO films. • Higher temperature originates larger refractive index values of the ALD ZnO films. • ZnO thin films were denser as the numbers of ALD deposition cycles were larger. • XPS analysis revels mayor extent of the DEZ reaction during the ALD process. - Abstract: Zinc oxide films are promising to improve the performance of electronic devices, including those based on organic materials. However, the dependence of the ZnO properties on the preparation conditions represents a challenge to obtain homogeneous thin films that satisfy specific applications. Here, we prepared ZnO films of a wide range of thicknesses by atomic layer deposition (ALD) at relatively low temperatures, 150 and 175 °C. From the results of X-ray photoelectron spectroscopy, X-ray diffraction and Spectroscopic Ellipsometry it is concluded that the polycrystalline structure of the wurtzite is the main phase of the ALD samples, with OH groups on their surface. Ellipsometry revealed that the temperature and the deposition cycles have a strong effect on the films roughness. Scanning electron micrographs evidenced such effect, through the large pyramids developed at the surface of the films. It is concluded that crystalline ZnO thin films within a broad range of thickness and roughness can be obtained for optic or optoelectronic applications.

Estimation of hydraulic parameters from an unconfined aquifer test conducted in a glacial outwash deposit, Cape Cod, Massachusetts

Science.gov (United States)

Moench, Allen F.; Garabedian, Stephen P.; LeBlanc, Denis R.

2001-01-01

An aquifer test conducted in a sand and gravel, glacial outwash deposit on Cape Cod, Massachusetts was analyzed by means of a model for flow to a partially penetrating well in a homogeneous, anisotropic unconfined aquifer. The model is designed to account for all significant mechanisms expected to influence drawdown in observation piezometers and in the pumped well. In addition to the usual fluid-flow and storage processes, additional processes include effects of storage in the pumped well, storage in observation piezometers, effects of skin at the pumped-well screen, and effects of drainage from the zone above the water table.

A glacial model for TIME4 applicable to the Sellafield and Dounreay areas

International Nuclear Information System (INIS)

Boulton, G.S.; Broadgate, M.

1992-12-01

This report provides input data for TIME4 Version 2.0 which has been developed for use at Sellafield and Dounreay. This report presents a review of the available data on the disposition of tills and other glacial deposits and landforms in the regions around Sellafield and Dounreay. This information is supplemented by the use of satellite imagery which has allowed the delineation of glacial flowlines on a regional basis. The glacial data is used as a constraint for the modelling of ice sheet behaviour. The physical basis of the model used has been developed previously but is presented for reference in this report. Modifications, notably the use of a nested topographic grid to improve resolution around the site, are described. Output from the model includes ice-front position, relative sea-level, erosion and deposition and sub-glacial discharge as a function of time and position along a transect. Additional information relating to the surface slope of the ice sheet is also included. (Author)

Growth of BaTiO3-PVDF composite thick films by using aerosol deposition

Science.gov (United States)

Cho, Sung Hwan; Yoon, Young Joon

2016-01-01

Barium titanate (BaTiO3)-polyvinylidene fluoride (PVDF) composite thick films were grown by using aerosol deposition at room temperature with BaTiO3 and PVDF powders. To produce a uniform composition in ceramic and polymer composite films, which show a substantial difference in specific gravity, we used PVDF-coated BaTiO3 powders as the starting materials. An examination of the microstructure confirmed that the BaTiO3 were well distributed in the PVDF matrix in the form of a 0 - 3 compound. The crystallite size in the BaTiO3-PVDF composite thick films was 5 ˜ 50 times higher than that in pure BaTiO3 thick films. PVDF plays a role in suppressing the fragmentation of BaTiO3 powder during the aerosol deposition process and in controlling the relative permittivity.

Obsidian hydration dates glacial loading?

Science.gov (United States)

Friedman, I; Pierce, K L; Obradovich, J D; Long, W D

1973-05-18

Three different groups of hydration rinds have been measured on thin sections of obsidian from Obsidian Cliff, Yellowstone National Park, Wyoming. The average thickness of the thickest (oldest) group of hydration rinds is 16.3 micrometers and can be related to the original emplacement of the flow 176,000 years ago (potassium-argon age). In addition to these original surfaces, most thin sections show cracks and surfaces which have average hydration rind thicknesses of 14.5 and 7.9 micrometers. These later two hydration rinds compare closely in thickness with those on obsidian pebbles in the Bull Lake and Pinedale terminal moraines in the West Yellowstone Basin, which are 14 to 15 and 7 to 8 micrometers thick, respectively. The later cracks are thought to have been formed by glacial loading during the Bull Lake and Pinedale glaciations, when an estimated 800 meters of ice covered the Obsidian Cliff flow.

Quaternary sedimentation of the Alaskan Beaufort shelf: Influence of regional tectonics, fluctuating sea levels, and glacial sediment sources

Science.gov (United States)

Dinter, D.A.

1985-01-01

The offshore stratigraphy of the Quaternary Gubik Formation of Arctic Alaska has been studied on high-resolution seismic profiles with a maximum sub-seafloor penetration of about 100 m. In general, marine transgressive subunits of the Gubik Formation are wedge-shaped on the shelf, thickening slightly seaward to the shelf break, beyond which they are offset by landslides and slumps. Beneath the eastern third of the Alaskan Beaufort shelf, active folding has created two persistent structural depressions, the Eastern and Western Wedge Terranes, in which the wedge morphology is especially well developed. The youngest transgressive marine wedge, which was deposited in such a way as to fill these depressions, leaving a generally flat present-day shelf surface, is inferred to be late Wisconsin or younger in age because it overlies a prominent disconformity interpreted to have been formed during the late Wisconsin glacial sea-level minimum. The thickness of this youngest wedge, Unit A, locally exceeds 40 m on the outer shelf, yet apparently relict gravel deposits collected from its seabed surface indicate that the depositional rate is presently quite low on the middle and outer shelf. Lithologies of the gravels are exotic to Alaska, but similar to suites exposed in the Canadian Arctic Islands. These observations suggest a depositional scenario in which the retreating Laurentide Ice Sheet shed sediment-laden icebergs from the Canadian Arctic Islands into the Arctic Ocean following the late Wisconsin glacial maximum. These bergs were then rafted westward by the Beaufort Gyre and grounded on the Alaskan shelf by northeasterly prevailing winds. Especially large numbers of bergs accumulated in the wedge terrane embayments-created as sea level rose-and melted there, filling the embayments with their sedimentary cargo. As glacial retreat slowed, depositional rates on the shelf dwindled. This mode of deposition in the Alaskan Beaufort wedge terranes may be typical of early post-glacial

Glacial lakes in Austria - Distribution and formation since the Little Ice Age

Science.gov (United States)

Buckel, J.; Otto, J. C.; Prasicek, G.; Keuschnig, M.

2018-05-01

Glacial lakes constitute a substantial part of the legacy of vanishing mountain glaciation and act as water storage, sediment traps and sources of both natural hazards and leisure activities. For these reasons, they receive growing attention by scientists and society. However, while the evolution of glacial lakes has been studied intensively over timescales tied to remote sensing-based approaches, the longer-term perspective has been omitted due a lack of suitable data sources. We mapped and analyzed the spatial distribution of glacial lakes in the Austrian Alps. We trace the development of number and area of glacial lakes in the Austrian Alps since the Little Ice Age (LIA) based on a unique combination of a lake inventory and an extensive record of glacier retreat. We find that bedrock-dammed lakes are the dominant lake type in the inventory. Bedrock- and moraine-dammed lakes populate the highest landscape domains located in cirques and hanging valleys. We observe lakes embedded in glacial deposits at lower locations on average below 2000 m a.s.l. In general, the distribution of glacial lakes over elevation reflects glacier erosional and depositional dynamics rather than the distribution of total area. The rate of formation of new glacial lakes (number, area) has continuously accelerated over time with present rates showing an eight-fold increase since LIA. At the same time the total glacier area decreased by two-thirds. This development coincides with a long-term trend of rising temperatures and a significant stepping up of this trend within the last 20 years in the Austrian Alps.

Effect of layer thickness on the thermal release from Be-D co-deposited layers

Science.gov (United States)

Baldwin, M. J.; Doerner, R. P.

2014-08-01

The results of previous work (Baldwin et al 2013 J. Nucl. Mater. 438 S967-70 and Baldwin et al 2014 Nucl. Fusion 54 073005) are extended to explore the influence of layer thickness on the thermal D2 release from co-deposited Be-(0.05)D layers produced at ˜323 K. Bake desorption of layers of thickness 0.2-0.7 µm are explored with a view to examine the influence of layer thickness on the efficacy of the proposed ITER bake procedure, to be carried out at the fixed temperatures of 513 K on the first wall and 623 K in the divertor. The results of experiment and modelling with the TMAP-7 hydrogen transport code, show that thicker Be-D co-deposited layers are relatively more difficult to desorb (time-wise) than thinner layers with the same concentrations of intrinsic traps and retained hydrogen isotope fraction.

Magnetic Signature of Glacial Flour in Sediments From Bear Lake, Utah/Idaho

Science.gov (United States)

Rosenbaum, J. G.; Dean, W. E.; Colman, S. M.; Reynolds, R. L.

2002-12-01

Variations in magnetic properties within an interval of Bear Lake sediments correlative with oxygen isotope stage 2 (OIS 2) and OIS 3 provide a record of glacial flour production for the Uinta Mountains. Like sediments of the same age from Upper Klamath Lake (OR), these Bear Lake sediments have high magnetic susceptibilities (MS) relative to non-glacial-age sediments and contain well-defined millennial-scale variations in magnetic properties. In contrast to glacial flour derived from volcanic rocks surrounding Upper Klamath Lake, glacial flour derived from the Uinta Mountains and deposited in Bear Lake by the Bear River has low magnetite content but high hematite content. The relatively low MS values of younger and older non-glacial-age sediments are due entirely to dilution by non-magnetic endogenic carbonate and to the effects of sulfidic alteration of detrital Fe-oxides. Analysis of samples from streams entering Bear Lake and from along the course of the Bear River demonstrates that, in comparison to other areas of the catchment, sediment derived from the Uinta Mountains is rich in hematite (high HIRM) and aluminum, and poor in magnetite (low MS) and titanium. Within the glacial-age lake sediments, there are strong positive correlations among HIRM, Al/Ti, and fine sediment grain size. MS varies inversely with theses three variables. These relations indicate that the observed millennial-scale variations in magnetic and chemical properties arise from varying proportions of two detrital components: (1) very fine-grained glacial flour derived from Proterozoic metasedimentary rocks in the Uinta Mountains and characterized by high HIRM and low MS, and (2) somewhat coarser material, characterized by higher MS and lower HIRM, derived from widespread sedimentary rocks along the course of the Bear River and around Bear Lake. Measurement of glacial flour incorporated in lake sediments can provide a continuous history of alpine glaciation, because the rate of accumulation

Coupled European and Greenland last glacial dust activity driven by North Atlantic climate

DEFF Research Database (Denmark)

Újvári, Gábor; Stevens, Thomas; Molnár, Mihály

2017-01-01

Centennial-scale mineral dust peaks in last glacial Greenland ice cores match the timing of lowest Greenland temperatures, yet little is known of equivalent changes in dust-emitting regions, limiting our understanding of dust−climate interaction. Here, we present the most detailed and precise age...... model for European loess dust deposits to date, based on 125 accelerator mass spectrometry14C ages from Dunaszekcso, } Hungary. The record shows that variations in glacial dust deposition variability on centennial–millennial timescales in east central Europe and Greenland were synchronous within...

[Effects of the grain size and thickness of dust deposits on soil water and salt movement in the hinterland of the Taklimakan Desert].

Science.gov (United States)

Sun, Yan-Wei; Li, Sheng-Yu; Xu, Xin-Wen; Zhang, Jian-Guo; Li, Ying

2009-08-01

By using mcirolysimeter, a laboratory simulation experiment was conducted to study the effects of the grain size and thickness of dust deposits on the soil water evaporation and salt movement in the hinterland of the Taklimakan Desert. Under the same initial soil water content and deposition thickness condition, finer-textured (grain size of dust deposits on soil water evaporation had an inflection point at the grain size 0.20 mm, i. e., increased with increasing grain size when the grain size was 0.063-0.20 mm but decreased with increasing grain size when the grain size was > 0.20 mm. With the increasing thickness of dust deposits, its inhibition effect on soil water evaporation increased, and there existed a logarithmic relationship between the dust deposits thickness and water evaporation. Surface soil salt accumulation had a negative correlation with dust deposits thickness. In sum, the dust deposits in study area could affect the stability of arid desert ecosystem.

Effects of the thickness of gold deposited on a source backing film in the 4πβ-counting

International Nuclear Information System (INIS)

Miyahara, Hiroshi; Yoshida, Makoto; Watanabe, Tamaki

1976-01-01

A gold deposited VYNS film as a source backing in the 4πβ-counting has generally been used for reducing the absorption of β-rays. The thickness of the film with the gold is usually a few times thicker than the VYNS film itself. However, Because the appropriate thickness of gold has not yet been determined, the effects of gold thickness on electrical resistivity, plateau characteristics and β-ray counting efficiency were studied. 198 Au (960 keV), 60 Co(315 keV), 59 Fe(273 keV) and 95 Nb(160 keV), which were prepared as sources by the aluminium chloride treatment method, were used. Gold was evaporated under a deposition rate of 1 - 5 μg/cm 2 /min at a pressure less than 1 x 10 -5 Torr. Results show that the gold deposition on the side opposite the source after source preparation is essential. In this case, a maximum counting efficiency is obtained at the mean thickness of 2 μg/cm 2 . When gold is deposited only on the same side as the source, a maximum counting efficiency, which is less than that in the former case, is obtained at the mean thickness of 20 μg/cm 2 . (Evans, J.)

Measuring the thickness of austenitic weld deposits on carbon steel walls using a magnetic method

International Nuclear Information System (INIS)

Wagner, K.

1988-01-01

The theoretical background is described of a magnetic method characterized by a marked compensation of the undesirable effect of δ-ferrite content in the deposit, on the accuracy of measuring deposit thickness. A description is also given of the basic types of sensors and the results are summarized of comparing measurements performed on weld deposits of WWER-type reactor pressure vessels. (author). 7 figs., 5 refs

Effect of thickness on electrical properties of SILAR deposited SnS thin films

Science.gov (United States)

Akaltun, Yunus; Astam, Aykut; Cerhan, Asena; ćayir, Tuba

2016-03-01

Tin sulfide (SnS) thin films of different thickness were prepared on glass substrates by successive ionic layer adsorption and reaction (SILAR) method at room temperature using tin (II) chloride and sodium sulfide aqueous solutions. The thicknesses of the films were determined using spectroscopic ellipsometry measurements and found to be 47.2, 65.8, 111.0, and 128.7nm for 20, 25, 30 and 35 deposition cycles respectively. The electrical properties of the films were investigated using d.c. two-point probe method at room temperature and the results showed that the resistivity was found to decrease with increasing film thickness.

Subdivision of Glacial Deposits in Southeastern Peru Based on Pedogenic Development and Radiometric Ages

Science.gov (United States)

Goodman, Adam Y.; Rodbell, Donald T.; Seltzer, Geoffrey O.; Mark, Bryan G.

2001-07-01

The Cordillera Vilcanota and Quelccaya Ice Cap region of southern Peru (13°30‧-14°00‧S; 70°40‧-71°25‧W) contains a detailed record of late Quaternary glaciation in the tropical Andes. Quantification of soil development on 19 moraine crests and radiocarbon ages are used to reconstruct the glacial history. Secondary iron and clay increase linearly in Quelccaya soils and clay accumulates at a linear rate in Vilcanota soils, which may reflect the semicontinuous addition of eolian dust enriched in secondary iron to all soils. In contrast, logarithmic rates of iron buildup in soils in the Cordillera Vilcanota reflect chemical weathering; high concentrations of secondary iron in Vilcanota tills may mask the role of eolian input to these soils. Soil-age estimates from extrapolation of field and laboratory data suggest that the most extensive late Quaternary glaciation occurred >70,000 yr B.P. This provides one of the first semiquantitative age estimates for maximum ice extent in southern Peru and is supported by a minimum-limiting age of ∼41,520 14C yr B.P. A late glacial readvance culminated ∼16,650 cal yr B.P. in the Cordillera Vilcanota. Following rapid deglaciation of unknown extent, an advance of the Quelccaya Ice Cap occurred between ∼13,090 and 12,800 cal yr B.P., which coincides approximately with the onset of the Younger Dryas cooling in the North Atlantic region. Moraines deposited <394 cal yr B.P. in the Cordillera Vilcanota and <300 cal yr B.P. on the west side of the Quelccaya Ice Cap correlate with Little Ice Age moraines of other regions.

The Effect of Film Thickness on the Gas Sensing Properties of Ultra-Thin TiO2 Films Deposited by Atomic Layer Deposition

Directory of Open Access Journals (Sweden)

Rachel L. Wilson

2018-03-01

Full Text Available Analyte sensitivity for gas sensors based on semiconducting metal oxides should be highly dependent on the film thickness, particularly when that thickness is on the order of the Debye length. This thickness dependence has previously been demonstrated for SnO2 and inferred for TiO2. In this paper, TiO2 thin films have been prepared by Atomic Layer Deposition (ALD using titanium isopropoxide and water as precursors. The deposition process was performed on standard alumina gas sensor platforms and microscope slides (for analysis purposes, at a temperature of 200 °C. The TiO2 films were exposed to different concentrations of CO, CH4, NO2, NH3 and SO2 to evaluate their gas sensitivities. These experiments showed that the TiO2 film thickness played a dominant role within the conduction mechanism and the pattern of response for the electrical resistance towards CH4 and NH3 exposure indicated typical n-type semiconducting behavior. The effect of relative humidity on the gas sensitivity has also been demonstrated.

Effect of layer thickness on the thermal release from Be–D co-deposited layers

International Nuclear Information System (INIS)

Baldwin, M.J.; Doerner, R.P.

2014-01-01

The results of previous work (Baldwin et al 2013 J. Nucl. Mater. 438 S967–70 and Baldwin et al 2014 Nucl. Fusion 54 073005) are extended to explore the influence of layer thickness on the thermal D 2 release from co-deposited Be–(0.05)D layers produced at ∼323 K. Bake desorption of layers of thickness 0.2–0.7 µm are explored with a view to examine the influence of layer thickness on the efficacy of the proposed ITER bake procedure, to be carried out at the fixed temperatures of 513 K on the first wall and 623 K in the divertor. The results of experiment and modelling with the TMAP-7 hydrogen transport code, show that thicker Be–D co-deposited layers are relatively more difficult to desorb (time-wise) than thinner layers with the same concentrations of intrinsic traps and retained hydrogen isotope fraction. (paper)

Quaternary sediment thickness and bedrock topography of the glaciated United States east of the Rocky Mountains

Science.gov (United States)

Soller, David R.; Garrity, Christopher P.

2018-01-26

Beginning roughly 2.6 million years ago, global climate entered a cooling phase known as the Pleistocene Epoch. As snow in northern latitudes compacted into ice several kilometers thick, it flowed as glaciers southward across the North American continent. These glaciers extended across the northern United States, dramatically altering the landscape they covered. East of the Rocky Mountains, the ice coalesced into continental glaciers (called the Laurentide Ice Sheet) that at times blanketed much of the north-central and northeastern United States. To the west of the Laurentide Ice Sheet, glaciers formed in the mountains of western Canada and the United States and coalesced into the Cordilleran ice sheet; this relatively smaller ice mass extended into the conterminous United States in the northernmost areas of western Montana, Idaho, and Washington. Throughout the Pleistocene, landscape alteration occurred by (1) glacial erosion of the rocks and sediments; (2) redeposition of the eroded earth materials in a form substantially different from their source rocks, in terms of texture and overall character; and (3) disruption of preexisting drainage patterns by the newly deposited sediments. In many cases, pre-glacial drainage systems (including, for example, the Mississippi River) were rerouted because their older drainage courses became blocked with glacial sediment.The continental glaciers advanced and retreated many times across those areas. During each ice advance, or glaciation, erosion and deposition occurred, and the landscape was again altered. Through successive glaciations, the landscape and the bedrock surface gradually came to resemble their present configurations. As continental ice sheets receded and the Pleistocene ended, erosion and deposition of sediment (for example in stream valleys) continued to shape the landscape up to the present day (albeit to a lesser extent than during glaciation). The interval of time since the last recession of the glaciers

Thickness determination of large-area films of yttria-stabilized zirconia produced by pulsed laser deposition

Energy Technology Data Exchange (ETDEWEB)

Pryds, N. [Materials Research Department, Riso National Laboratory, DK-4000 Roskilde (Denmark)]. E-mail: nini.pryds@risoe.dk; Toftmann, B. [Department of Optics and Plasma Research, Riso National Laboratory, DK-4000 Roskilde (Denmark); Bilde-Sorensen, J.B. [Materials Research Department, Riso National Laboratory, DK-4000 Roskilde (Denmark); Schou, J. [Department of Optics and Plasma Research, Riso National Laboratory, DK-4000 Roskilde (Denmark); Linderoth, S. [Materials Research Department, Riso National Laboratory, DK-4000 Roskilde (Denmark)

2006-04-30

Films of yttria-stabilized zirconia (YSZ) on a polished silicon substrate of diameter up to 125 mm have been produced in a large-area pulsed laser deposition (PLD) setup under typical PLD conditions. The film thickness over the full film area has been determined by energy-dispersive X-ray spectrometry in a scanning electron microscope (SEM) with use of a method similar to one described by Bishop and Poole. The attenuation of the electron-induced X-rays from the Si wafer by the film was monitored at a number of points along a diameter and the thickness was determined by Monte Carlo simulations of the attenuation for various values of film thickness with the program CASINO. These results have been compared with direct measurements in the SEM of the film thickness on a cross-section on one of the wafers. The results of these measurements demonstrate the ability of this technique to accurately determine the thickness of a large film, i.e. up to diameters of 125 mm, in a relatively short time, without destroying the substrate, without the need of a standard sample and without the need of a flat substrate. We have also demonstrated that by controlling the deposition parameters large-area YSZ films with uniform thickness can be produced.

Thickness determination of large-area films of yttria-stabilized zirconia produced by pulsed laser deposition

International Nuclear Information System (INIS)

Pryds, N.; Toftmann, B.; Bilde-Sorensen, J.B.; Schou, J.; Linderoth, S.

2006-01-01

Films of yttria-stabilized zirconia (YSZ) on a polished silicon substrate of diameter up to 125 mm have been produced in a large-area pulsed laser deposition (PLD) setup under typical PLD conditions. The film thickness over the full film area has been determined by energy-dispersive X-ray spectrometry in a scanning electron microscope (SEM) with use of a method similar to one described by Bishop and Poole. The attenuation of the electron-induced X-rays from the Si wafer by the film was monitored at a number of points along a diameter and the thickness was determined by Monte Carlo simulations of the attenuation for various values of film thickness with the program CASINO. These results have been compared with direct measurements in the SEM of the film thickness on a cross-section on one of the wafers. The results of these measurements demonstrate the ability of this technique to accurately determine the thickness of a large film, i.e. up to diameters of 125 mm, in a relatively short time, without destroying the substrate, without the need of a standard sample and without the need of a flat substrate. We have also demonstrated that by controlling the deposition parameters large-area YSZ films with uniform thickness can be produced

Glacial loess or shoreface sands: a re-interpretation of the Upper Ordovician (Ashgillian) glacial Ammar Formation, Southern Jordan

Science.gov (United States)

Turner, B. R.; Makhlouf, I. M.; Armstrong, H. A.

2003-04-01

Upper Ordovician (Ashgillian) glacial deposits of the Ammar Formation, Southern Jordan, comprise locally deformed, structureless fine sandstone, incised by glacial channels filled by braided outwash plain sandstones and transgressive marine mudstones. The structureless sandstones, previously interpreted as a glacial rock flour or loessite derived from the underlying undisturbed sandstones, differ significantly from typical loessite and contain hitherto unrecognised sedimentary structures, including hummocky cross-stratification. The sandstones, which grade laterally and vertically into stratigraphically equivalent undeformed marginal marine sandstones, are interpreted as a deformed facies of the underlying sandstones, deposited in a similar high energy shoreface environment. Although deformation of the shoreface sandstones was post-depositional, the origin of the deformation, and its confinement to the Jebel Ammar area is unknown. Deformation due to the weight of the overlying ice is unlikely as the glaciofluvial channels are now thought to have been cut by tunnel valley activity not ice. A more likely mechanism is post-glacial crustal tectonics. Melting of ice caps is commonly associated with intraplate seismicity and the development of an extensional crustal stress regime around the perimeter of ice caps; the interior is largely aseismic because the weight of the ice supresses seismic activity and faulting. Since southern Jordan lay close to the ice cap in Saudi Arabia it may have been subjected to postglacial seismicity and crustal stress, which induced ground shaking, reduced overburden pressure, increased hydrostatic pressure and possibly reactivation of existing tectonic faults. This resulted in liquefaction and extensive deformation of the sediments, which show many characteristics of seismites, generated by earthquake shocks. Since the glaciation was a very short-lived event (0.2-1 Ma), deglaciation and associated tectonism triggering deformation, lasted

Sediment core and glacial environment reconstruction - a method review

Science.gov (United States)

Bakke, Jostein; Paasche, Øyvind

2010-05-01

Alpine glaciers are often located in remote and high-altitude regions of the world, areas that only rarely are covered by instrumental records. Reconstructions of glaciers has therefore proven useful for understanding past climate dynamics on both shorter and longer time-scales. One major drawback with glacier reconstructions based solely on moraine chronologies - by far the most common -, is that due to selective preservation of moraine ridges such records do not exclude the possibility of multiple Holocene glacier advances. This problem is true regardless whether cosmogenic isotopes or lichenometry have been used to date the moraines, or also radiocarbon dating of mega-fossils buried in till or underneath the moraines themselves. To overcome this problem Karlén (1976) initially suggested that glacial erosion and the associated production of rock-flour deposited in downstream lakes could provide a continuous record of glacial fluctuations, hence overcoming the problem of incomplete reconstructions. We want to discuss the methods used to reconstruct past glacier activity based on sediments deposited in distal glacier-fed lakes. By quantifying physical properties of glacial and extra-glacial sediments deposited in catchments, and in downstream lakes and fjords, it is possible to isolate and identify past glacier activity - size and production rate - that subsequently can be used to reconstruct changing environmental shifts and trends. Changes in average sediment evacuation from alpine glaciers are mainly governed by glacier size and the mass turnover gradient, determining the deformation rate at any given time. The amount of solid precipitation (mainly winter accumulation) versus loss due to melting during the ablation-season (mainly summer temperature) determines the mass turnover gradient in either positive or negative direction. A prevailing positive net balance will lead to higher sedimentation rates and vice versa, which in turn can be recorded in downstream

In situ, real-time thickness measurement techniques for bath-deposited CdS thin films on Cu(In,Ga)Se2

International Nuclear Information System (INIS)

Mann, Jonathan R.; Noufi, Rommel

2012-01-01

A technique has been developed that can measure the thickness of a 30–70 nm thin film of cadmium sulfide on a Cu(In,Ga)Se 2 substrate, in real time, as it grows in a chemical bath. The technique does not damage the film, and can be used to monitor batch depositions and roll-to-roll depositions with equal accuracy. The technique is based on reflectance spectroscopy through the chemical bath. - Highlights: ► Reflection spectra were collected during the chemical bath deposition of CdS. ► Two algorithms were generated to extract film thickness from each spectrum. ► Two conventional techniques were used to independently verify CdS film thicknesses. ► The accuracies of the algorithms are within 7% of the actual thicknesses. ► The algorithms offer in situ, real time thicknesses through the chemical bath.

Detailed gravity survey to help seismic microzonation: Mapping the thickness of unconsolidated deposits in Ottawa, Canada

Science.gov (United States)

Lamontagne, M.; Thomas, M.; Silliker, J.; Jobin, D.

2011-11-01

In this study, measurements of gravity were made to map and model the thickness of Quaternary deposits (sand and clay) overlying Ordovician limestones in a suburb of Ottawa (Orléans, Ontario). Because ground motion amplification is partly related to the thickness of unconsolidated deposits, this work helps refine the assessment of the earthquake damage potential of the area. It also helps the mapping of clay basins, which can locally exceed 100 m in thickness, where ground motion amplification can occur. Previous work, including well log data and seismic methods, have yielded a wealth of information on near-surface geology in Orléans, thereby providing the necessary constraints to test the applicability of gravity modeling in other locations where other methods cannot always be used. Some 104 gravity stations were occupied in an 8 × 12 km test area in the Orléans. Stations were accurately located with differential GPS that provided centimetric accuracy in elevation. Densities of the unconsolidated Quaternary deposits (Champlain Sea clay) determined on core samples and densities determined on limestone samples from outcrops were used to constrain models of the clay layer overlying the higher density bedrock formations (limestone). The gravity anomaly map delineates areas where clay basins attain > 100 m depth. Assuming a realistic density for the Champlain Sea clays (1.9-2.1 g/cm 3), the thickness over the higher density bedrock formations (Ordovician carbonate rocks) was modeled and compared with well logs and two seismic reflection profiles. The models match quite well with the information determined from well logs and seismic methods. It was found that gravity and the thickness of unconsolidated deposits are correlated but the uncertainties in both data sets preclude the definition of a direct correlation between the two. We propose that gravity measurements at a local scale be used as an inexpensive means of mapping the thickness of unconsolidated deposits

Glacial flour in lacustrine sediments: Records of alpine glaciation in the western U.S.A. during the last glacial interval

Science.gov (United States)

Rosenbaum, J. G.; Reynolds, R. L.

2010-12-01

Sediments in Bear Lake (UT/ID) and Upper Klamath Lake (OR) contain glacial flour derived during the last glacial interval from the Uinta Mountains and the southern Cascade Range, respectively. Magnetic properties provide measures of glacial-flour content and, in concert with elemental and grain-size analyses, yield high-resolution records of glacial growth and decay. Creation and preservation of such records requires that (1) properties of glacial flour contrast with those of other sedimentary components and (2) magnetic minerals are neither formed nor destroyed after deposition. In the Bear Lake watershed, glaciers were confined to a small headwater area of the Bear River underlain by hematite-rich rocks of the Uinta Mountain Group (UMG), which are not exposed elsewhere in the catchment. Because UMG detritus is abundant only in Bear Lake sediments of glacial age, hard isothermal remanent magnetization (a measure of hematite content) provides a proxy for glacial flour. In contrast, the entire Upper Klamath Lake catchment, which lies to the east of the Cascade Range in southern Oregon, is underlain largely by basalt and basaltic andesite. Magnetic properties of fresh titanomagnetite-rich rock flour from glaciers on a composite volcano contrast sharply with those of detritus from unglaciated areas in which weathering destroyed some of the titanomagnetite. Ideally, well-dated records of the flux of glacial flour can be compared to ages of glacial features (e.g., moraines). For Upper Klamath Lake, quantitative measures of rock-flour content (from magnetic properties) and excellent chronology allow accurate calculation of flux. However, ages of glacial features are lacking and mafic volcanic rocks, which weather rapidly in this environment, are not well suited for cosmogenic exposure dating. At Bear Lake, estimates of glacial-flour content are less quantitative and chronology within the glacial interval must be interpolated from radiocarbon ages above and below the

Conceptual and numerical models of the glacial aquifer system north of Aberdeen, South Dakota

Science.gov (United States)

Marini, Katrina A.; Hoogestraat, Galen K.; Aurand, Katherine R.; Putnam, Larry D.

2012-01-01

This U.S. Geological Survey report documents a conceptual and numerical model of the glacial aquifer system north of Aberdeen, South Dakota, that can be used to evaluate and manage the city of Aberdeen's water resources. The glacial aquifer system in the model area includes the Elm, Middle James, and Deep James aquifers, with intervening confining units composed of glacial till. The Elm aquifer ranged in thickness from less than 1 to about 95 feet (ft), with an average thickness of about 24 ft; the Middle James aquifer ranged in thickness from less than 1 to 91 ft, with an average thickness of 13 ft; and the Deep James aquifer ranged in thickness from less than 1 to 165 ft, with an average thickness of 23 ft. The confining units between the aquifers consisted of glacial till and ranged in thickness from 0 to 280 ft. The general direction of groundwater flow in the Elm aquifer in the model area was from northwest to southeast following the topography. Groundwater flow in the Middle James aquifer was to the southeast. Sparse data indicated a fairly flat potentiometric surface for the Deep James aquifer. Horizontal hydraulic conductivity for the Elm aquifer determined from aquifer tests ranged from 97 to 418 feet per day (ft/d), and a confined storage coefficient was determined to be 2.4x10-5. Estimates of the vertical hydraulic conductivity of the sediments separating the Elm River from the Elm aquifer, determined from the analysis of temperature gradients, ranged from 0.14 to 2.48 ft/d. Average annual precipitation in the model area was 19.6 inches per year (in/yr), and agriculture was the primary land use. Recharge to the Elm aquifer was by infiltration of precipitation through overlying outwash, lake sediments, and glacial till. The annual recharge for the model area, calculated by using a soil-water-balance method for water year (WY) 1975-2009, ranged from 0.028 inch in WY 1980 to 4.52 inches in WY 1986, with a mean of 1.56 inches. The annual potential

Nanostructured MgTiO{sub 3} thick films obtained by electrophoretic deposition from nanopowders prepared by solar PVD

Energy Technology Data Exchange (ETDEWEB)

Apostol, Irina [S.C. IPEE Amiral Trading Impex S.A., 115300 Curtea de Arges (Romania); Mahajan, Amit [Department of Materials and Ceramics Engineering, Centre for Research in Ceramics and Composite Materials, CICECO, University of Aveiro, 3810-093 Aveiro (Portugal); Monty, Claude J.A. [CNRS-PROMES Laboratory, 66120 Font Romeu Odeillo (France); Venkata Saravanan, K., E-mail: venketvs@cutn.ac.in [Department of Materials and Ceramics Engineering, Centre for Research in Ceramics and Composite Materials, CICECO, University of Aveiro, 3810-093 Aveiro (Portugal); Department of Physics, School of Basic and Applied Science, Central University of Tamil Nadu, Thiruvarur 61010 (India)

2015-12-15

Highlights: • Obtaining nano-crystalline magnesium titanium oxide powders by solar physical vapor deposition (SPVD) process. And using these nano-powders to obtain thick films on conducting substrates by electrophoretic deposition (EPD). • SPVD is a core innovative, original and environmentally friendly process to prepare nano-materials in a powder form. • Sintered thick films exhibited dielectric constant, ε{sub r} ∼18.3 and dielectric loss, tan δ ∼0.0012 at 1 MHz, which is comparable to the values reported earlier. • New contributions to the pool of information on the preparation of nano-structured MgTiO{sub 3} thick films at low temperatures. • A considerable decrease in synthesis temperature of pure MgTiO{sub 3} thick film was observed by the combination of SPVD and EPD. - Abstract: A novel combination of solar physical vapor deposition (SPVD) and electrophoretic deposition (EPD) that was developed to grow MgTiO{sub 3} nanostructured thick films is presented. Obtaining nanostructured MgTiO{sub 3} thick films, which can replace bulk ceramic components, a major trend in electronic industry, is the main objective of this work. The advantage of SPVD is direct synthesis of nanopowders, while EPD is simple, fast and inexpensive technique for preparing thick films. SPVD technique was developed at CNRS-PROMES Laboratory, Odeillo-Font Romeu, France, while the EPD was performed at University of Aveiro – DeMAC/CICECO, Portugal. The nanopowders with an average crystallite size of about 30 nm prepared by SPVD were dispersed in 50 ml of acetone in basic media with addition of triethanolamine. The obtained well-dispersed and stable suspensions were used for carrying out EPD on 25 μm thick platinum foils. After deposition, films with thickness of about 22–25 μm were sintered in air for 15 min at 800, 900 and 1000 °C. The structural and microstructural characterization of the sintered thick films was carried out using XRD and SEM, respectively. The

Microbial methane in the shallow Paleozoic sediments and glacial deposits of Illinois, U.S.A.

Science.gov (United States)

Coleman, D.D.; Liu, Chao-Li; Riley, K.M.

1988-01-01

Methane formed by the microbial decomposition of buried organic matter is virtually ubiquitous in the groundwaters of Illinois. Chemical and carbon isotopic compositions are reported for gas samples collected from over 200 private and municipal water wells and from 39 small gas wells completed in glacial deposits (drift-gas wells). Carbon and hydrogen isotopic data for methane, carbon dioxide and water show that these gases were formed by the carbon dioxide reduction pathway, the same mechanism which has been previously shown to be responsible for microbial methane formation in the marine environment. The isotopic composition of methane in these samples can be closely correlated with the chemical composition of the gas and with water chemistry. The data are interpreted as indicating that isotopically very light methane is found in waters where the residence time of groundwater in the methanogenesis zone was very short relative to the methane production rate. ?? 1988.

Investigation of the electrochemical deposition of thick layers of cadmium telluride

International Nuclear Information System (INIS)

Rousset, J.

2007-04-01

This research thesis deals with the problem of electrochemical deposition of thick layers of cadmium telluride (CdTe) meeting the requirements of high energy radiation detection. The author first recalls the physicochemical properties of CdTe and the basic principles of radiology. He details the different criteria which define a material for X ray detection. He describes the experimental conditions, the nature and preparation of substrates, and the different electrochemical systems used in this research. He studies the impact of the applied potential on the material properties, and compares previously obtained results available in the literature with those obtained in the chosen pool conditions. He discusses the synthesis of CdTe thick layers for which different methods are tested: static in potential, static in intensity, pulsed. The coatings obtained with a given potential and then with a given current are investigated. Finally, the influence of a thermal treatment in presence or absence of a sintering agent on the morphology, the chemical composition, and the crystalline and electric properties of the deposited material is discussed, and the results of the behaviour under X rays of a electrodeposited layer are presented

Measurement of the thickness of a target deposited in a substrate

International Nuclear Information System (INIS)

Martinez Q, E.; Aguilera, E.F.

1990-12-01

Being based on the Elastic scattering and in the Energy losses that suffer a projectile to the interacting with the matter, a method that allows to determine the thickness of a target deposited in a more heavy substrate is presented. The obtained results are consistent with that waited and the derived errors of the method are small. The used technique allows to reduce in considerable form the systematic errors coming from the calibration of the equipment. It is considered that this method is applicable in an interval of thickness quite wide and for many materials since it is only necessary to choose the projectile type and the energy of the same one appropriately. (Author)

Thick film laser induced forward transfer for deposition of thermally and mechanically sensitive materials

International Nuclear Information System (INIS)

Kattamis, Nicholas T.; Purnick, Priscilla E.; Weiss, Ron; Arnold, Craig B.

2007-01-01

Laser forward transfer processes incorporating thin absorbing films can be used to deposit robust organic and inorganic materials but the deposition of more delicate materials has remained elusive due to contamination and stress induced during the transfer process. Here, we present the approach to high resolution patterning of sensitive materials by incorporating a thick film polymer absorbing layer that is able to dissipate shock energy through mechanical deformation. Multiple mechanisms for transfer as a function of incident laser energy are observed and we show viable and contamination-free deposition of living mammalian embryonic stem cells

A 230 ka record of glacial and interglacial events from Aurora Cave, Fiordland, New Zealand

International Nuclear Information System (INIS)

Williams, P.W.

1996-01-01

Caves overrun by glaciers are known to accumulate dateable evidence of past glacial and interglacial events. Results are reported from an investigation of Aurora Cave on the slopes above Lake Te Anau in Fiordland. The cave commenced to form before c. 230 ka B.P. Sequences of glaciofluvial sediments interbedded with speleothems are evidence of the number and timing of glacial advances and the status of intervals between them. Twenty-six uranium series dates on speleothems underpin a chronology of seven glacial advances in the last 230 ka, with the peak of the late Otira glaciation, Aurora 3 advance, at c. 19 ka B.P. With five advances in the Otiran, the last glaciation is more complex than previously recognised. Comparison of the record with that recorded offshore from DSDP Site 594 reveals little matching, but the correspondence of the Aurora sequence with that interpreted from other onshore deposits is more convincing. Glacial deposits on slopes above the cave for a further 660 m may be evidence of the 'missing' glacial events of the mid-early Pleistocene. (author). 44 refs., 12 figs., 5 tabs

Emerging Glacial Lakes in the Cordillera Blanca, Peru: A Case Study at Arteson Glacier

Science.gov (United States)

Chisolm, R. E.; Mckinney, D. C.; Gomez, J.; Voss, K.

2012-12-01

Tropical glaciers are an essential component of the water resources systems in the mountainous regions where they are located, and a warming climate has resulted in the accelerated retreat of Andean glaciers in recent decades. The shrinkage of Andean glaciers influences the flood risk for communities living downstream as new glacial lakes have begun to form at the termini of some glaciers. As these lakes continue to grow in area and volume, they pose an increasing risk of glacial lake outburst floods (GLOFs). Ice thickness measurements have been a key missing link in studying the tropical glaciers in Peru and how climate change is likely to impact glacial melt and the growth of glacial lakes. Ground penetrating radar (GPR) has rarely been applied to glaciers in Peru to measure ice thickness, and these measurements can tell us a lot about how a warming climate will affect glacier mass balance. This study presents GPR data taken in July 2012 at the Arteson glacier in the Cordillera Blanca, Peru. A new lake has begun to form at the terminus of the Arteson glacier, and this lake has key features, including overhanging ice and loose rock likely to create landslides, that could trigger a catastrophic GLOF if the lake continues to grow. This new lake is part of a series of three lakes that have formed below the Arteson glacier. The two lower lakes, Artesonraju and Paron, are much larger so that if there were an avalanche or landslide into the new lake below Arteson glacier, the impact could potentially be more catastrophic than a GLOF from one single lake. Estimates of how the lake mass balance is likely to evolve due to the retreating glacier are key to assessing the flood risk from this dynamic three-lake system. Because the glacier mass balance and lake mass balance are closely linked, the ice thickness measurements and measurements of the bed slope of the Arteson glacier and underlying bedrock give us a clue to how the lake is likely to evolve. GPR measurements of

Comparing Terrestrial Organic Carbon Cycle Dynamics in Interglacial and Glacial Climates in the South American Tropics

Science.gov (United States)

Fornace, K. L.; Galy, V.; Hughen, K. A.

2014-12-01

The application of compound-specific radiocarbon dating to molecular biomarkers has allowed for tracking of specific organic carbon pools as they move through the environment, providing insight into complex processes within the global carbon cycle. Here we use this technique to investigate links between glacial-interglacial climate change and terrestrial organic carbon cycling in the catchments of Cariaco Basin and Lake Titicaca, two tropical South American sites with well-characterized climate histories since the last glacial period. By comparing radiocarbon ages of terrestrial biomarkers (leaf wax compounds) with deposition ages in late glacial and Holocene sediments, we are able to gauge the storage time of these compounds in the catchments in soils, floodplains, etc. before transport to marine or lacustrine sediments. We are also able to probe the effects of temperature and hydrologic change individually by taking advantage of opposite hydrologic trends at the two sites: while both were colder during the last glacial period, precipitation at Titicaca decreased from the last glacial period to the Holocene, but the late glacial was marked by drier conditions at Cariaco. Preliminary data from both sites show a wide range of apparent ages of long-chain n-fatty acids (within error of 0 to >10,000 years older than sediment), with the majority showing ages on the order of several millennia at time of deposition and age generally increasing with chain length. While late glacial leaf waxes appear to be older relative to sediment than those deposited in the Holocene at both sites, at Cariaco we find a ~2-3 times larger glacial-interglacial age difference than at Titicaca. We hypothesize that at Titicaca the competing influences of wetter and colder conditions during the last glacial period, which respectively tend to increase and decrease the rate of organic carbon turnover on land, served to minimize the contrast between glacial and interglacial leaf wax storage time

Glacial origin for cave rhythmite during MIS 5d-c in a glaciokarst landscape, Picos de Europa (Spain)

Science.gov (United States)

Ballesteros, Daniel; Jiménez-Sánchez, Montserrat; Giralt, Santiago; DeFelipe, Irene; García-Sansegundo, Joaquín

2017-06-01

Laminated slackwater deposits have been identified in many karst caves related to fluvial and lacustrine sedimentation. However, sedimentological evidence rarely supports a glacial origin for these deposits, which was proposed by previous studies. The Torca La Texa shaft is located in a glaciokarst area that comprises numerous slackwater-type deposits, piled up in fining-upward sequences. A basal sandy erosive layer and millimeter-sized laminated rhythmite with interbedded flowstone characterize these sequences. Fining-upward layers of carbonate silt, clay, and minor quartz sand deposited in flooded conduits define the rhythmite lamination. The presence of allochthonous minerals indicates that the rhythmite sediment comes from the glacial erosion of nearby carbonate mountains. Two 234U/230Th radiometric ages dated the rhythmite deposits around 109 and 95 ka, coinciding with relative cold periods included in the MIS 5d-c. These cold periods were marked by a high annual seasonality, immediately after the glacial local maximum extension, in agreement with a varve-type deposit. The combination of these sedimentological mineralogical, geomorphological and paleoclimate information indicates that the rhythmite should be introduced into the studied cave during the summer melting of the glaciers, which produced the recharge of the karst aquifer, triggering cave floods. In addition, punctual glacier collapses would also have their imprint in the slackwater sequences with thicker, coarser and erosive sand deposits and the spring blocking by glaciers may have promoted floods inside the cave. Therefore, the studied rhythmite can be interpreted as glacial varves decanted during the relatively cold climate conditions.

Thick CrN/NbN multilayer coating deposited by cathodic arc technique

Energy Technology Data Exchange (ETDEWEB)

Araujo, Juliano Avelar; Tschiptschin, Andre Paulo; Souza, Roberto Martins, E-mail: antschip@usp.br [Universidade de Sao Paulo (USP), SP (Brazil); Lima, Nelson Batista de [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

2017-01-15

The production of tribological nanoscale multilayer CrN/NbN coatings up to 6 μm thick by Sputtering/HIPIMS has been reported in literature. However, high demanding applications, such as internal combustion engine parts, need thicker coatings (>30 μm). The production of such parts by sputtering would be economically restrictive due to low deposition rates. In this work, nanoscale multilayer CrN/NbN coatings were produced in a high-deposition rate, industrial-size, Cathodic Arc Physical Vapor Deposition (ARC-PVD) chamber, containing three cathodes in alternate positions (Cr/ Nb/Cr). Four 30 μm thick NbN/CrN multilayer coatings with different periodicities (20, 10, 7.5 and 4 nm) were produced. The coatings were characterized by X-Ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). The multilayer coating system was composed of alternate cubic rock salt CrN and NbN layers, coherently strained due to lattice mismatch. The film grew with columnar morphology through the entire stratified structure. The periodicities adopted were maintained throughout the entire coating. The 20 nm periodicity coating showed separate NbN and CrN peaks in the XRD patterns, while for the lower periodicity (≤10nm) coatings, just one intermediate lattice (d-spacing) was detected. An almost linear increase of hardness with decreasing bilayer period indicates that interfacial effects can dominate the hardening mechanisms. (author)

Origin of last-glacial loess in the western Yukon-Tanana Upland, central Alaska, USA

Science.gov (United States)

Muhs, Daniel; Pigati, Jeffrey S.; Budahn, James R.; Skipp, Gary L.; Bettis, E. Arthur; Jensen, Britta

2018-01-01

Loess is widespread over Alaska, and its accumulation has traditionally been associated with glacial periods. Surprisingly, loess deposits securely dated to the last glacial period are rare in Alaska, and paleowind reconstructions for this time period are limited to inferences from dune orientations. We report a rare occurrence of loess deposits dating to the last glacial period, ~19 ka to ~12 ka, in the Yukon-Tanana Upland. Loess in this area is very coarse grained (abundant coarse silt), with decreases in particle size moving south of the Yukon River, implying that the drainage basin of this river was the main source. Geochemical data show, however, that the Tanana River valley to the south is also a likely distal source. The occurrence of last-glacial loess with sources to both the south and north is explained by both regional, synoptic-scale winds from the northeast and opposing katabatic winds that could have developed from expanded glaciers in both the Brooks Range to the north and the Alaska Range to the south. Based on a comparison with recent climate modeling for the last glacial period, seasonality of dust transport may also have played a role in bringing about contributions from both northern and southern sources.

Effects of glaciological and hydro-meteorological conditions on the glacial danger in Zailiyskiy Alatau

Directory of Open Access Journals (Sweden)

A. R. Medeu

2017-01-01

Full Text Available A need to estimate a hazard of a mudflow stream appearance in the glacial-nival zone of the Northern slope of Zailiyskiy Alatau (Kasakhstan is now one of the really urgent problems. The objective of this study was to inves‑ tigate influence of glacial and hydrometeorological factors on the condition of snow-glacial zone of Zailiyskiy Alatau and find out a mudflow-forming role of the mudflow centers arising due to climate warming and degra‑ dation of glaciation: periglacial lakes, intramoraine channels and reservoirs, and also talik massifs of morainic deposits. We analyzed glacial processes in the Zailiysky Alatau over a long period using meteorological data of the Almaty weather station and its close correlations with data from weather stations in the mountains. The area of glaciations was found out to be reduced after the maximum of the Little Ice Age. A combined diagram of occurrence of the mudflow manifestations and factors causing them had been constructed on the basis of sta‑ tistical data on the landslide phenomena. Glacial mudflows were the most frequent in 1960–1990, and later on activity of them became weaker. We believe, that in the next 10–20 years, the glacial mudflow hazard in Zailiys‑ kiy Alatau can sharply decrease, but at the same time, a probability of occurrence of the rainfall mudflows can increase in the mountainous zone of the ridge due the increase of areas with melted moraine and slope deposits.

Effect of Coating Thickness on the Properties of TiN Coatings Deposited on Tool Steels Using Cathodic Arc Pvd Technique

Science.gov (United States)

Mubarak, A.; Akhter, Parvez; Hamzah, Esah; Mohd Toff, Mohd Radzi Hj.; Qazi, Ishtiaq A.

Titanium nitride (TiN) widely used as hard coating material, was coated on tool steels, namely on high-speed steel (HSS) and D2 tool steel by physical vapor deposition method. The study concentrated on cathodic arc physical vapor deposition (CAPVD), a technique used for the deposition of hard coatings for tooling applications, and which has many advantages. The main drawback of this technique, however, is the formation of macrodroplets (MDs) during deposition, resulting in films with rougher morphology. Various standard characterization techniques and equipment, such as electron microscopy, atomic force microscopy, hardness testing machine, scratch tester, and pin-on-disc machine, were used to analyze and quantify the following properties and parameters: surface morphology, thickness, hardness, adhesion, and coefficient of friction (COF) of the deposited coatings. Surface morphology revealed that the MDs produced during the etching stage, protruded through the TiN film, resulting in film with deteriorated surface features. Both coating thickness and indentation loads influenced the hardness of the deposited coatings. The coatings deposited on HSS exhibit better adhesion compared to those on D2 tool steel. Standard deviation indicates that the coating deposited with thickness around 6.7 μm showed the most stable trend of COF versus sliding distance.

Strongly seasonal Proterozoic glacial climate in low palaeolatitudes: Radically different climate system on the pre-Ediacaran Earth

Directory of Open Access Journals (Sweden)

George E. Williams

2016-07-01

Full Text Available Proterozoic (pre-Ediacaran glaciations occurred under strongly seasonal climates near sea level in low palaeolatitudes. Metre-scale primary sand wedges in Cryogenian periglacial deposits are identical to those actively forming, through the infilling of seasonal (winter thermal contraction-cracks in permafrost by windblown sand, in present-day polar regions with a mean monthly air temperature range of 40 °C and mean annual air temperatures of −20 °C or lower. Varve-like rhythmites with dropstones in Proterozoic glacial successions are consistent with an active seasonal freeze–thaw cycle. The seasonal (annual oscillation of sea level recorded by tidal rhythmites in Cryogenian glacial successions indicates a significant seasonal cycle and extensive open seas. Palaeomagnetic data determined directly for Proterozoic glacial deposits and closely associated rocks indicate low palaeolatitudes: Cryogenian deposits in South Australia accumulated at ≤10°, most other Cryogenian deposits at 54° during Proterozoic low-latitude glaciations, whereby the equator would be cooler than the poles, on average, and global seasonality would be greatly amplified.

Cosmogenic 10Be Dating of Northern Quebec-Labrador Glacial Lake Shorelines and Drainage Deposits: Implications for the Final Meltwater Discharges of the Last Deglaciation

Science.gov (United States)

Roy, M.; Dube-Loubert, H.; Schaefer, J. M.; Hébert, S.

2017-12-01

The decay of the Laurentide ice sheet played an important role in the climate variability of the last deglaciation, notably through large discharges of meltwater from glacial lakes that disturbed the Atlantic meridional overturning oceanic circulation (AMOC). These former climate-forcing events are now under focus due to growing evidence showing that the present-day increase in freshwater releases from Greenland and other Arctic glaciers may potentially lead to a slowdown of the AMOC and cause important climate feedbacks. In northern Quebec and Labrador, the end of the deglaciation led to the formation of at least 10 important glacial lakes that drained into the nearby Labrador Sea where repeated meltwater discharges could have destabilized the ocean surface conditions in this key sector of the North Atlantic Ocean. Although the drainage of these ice-dammed lakes may form a good analogue for modern processes, the lack of direct constraints on the physiographic configuration and temporal evolution of these lakes limits our understanding of the timing and climate impact of these final meltwater pulses. Here we applied cosmogenic 10Be dating to raised boulder shorelines belonging to Lake Naskaupi, one of the largest glacial lakes in northern Quebec and Labrador. We reconstructed the lake extent and meltwater volume, as well as its lake-level history by systematic mapping of geomorphic features. We sampled a total of 16 boulders at 4 sites along the valley. In addition, we dated five boulders belonging to a large-scale outburst flood deposit recording the abrupt drainage of the lake. The distribution of the 21 ages shows a remarkable consistency, yielding a mean age of 7.8 ± 0.4 ka (1 outlier excluded). The ages from the shorelines are indistinguishable from those of the outburst flood deposit, suggesting that Lake Naskaupi existed for a relatively short time span. These new chronological data constrain the timing of the lake development and attendant drainage

Kisameet Glacial Clay: an Unexpected Source of Bacterial Diversity.

Science.gov (United States)

Svensson, Sarah L; Behroozian, Shekooh; Xu, Wanjing; Surette, Michael G; Li, Loretta; Davies, Julian

2017-05-23

Widespread antibiotic resistance among bacterial pathogens is providing the impetus to explore novel sources of antimicrobial agents. Recently, the potent antibacterial activity of certain clay minerals has stimulated scientific interest in these materials. One such example is Kisameet glacial clay (KC), an antibacterial clay from a deposit on the central coast of British Columbia, Canada. However, our understanding of the active principles of these complex natural substances is incomplete. Like soils, clays may possess complex mixtures of bacterial taxa, including the Actinobacteria , a clade known to be rich in antibiotic-producing organisms. Here, we present the first characterization of both the microbial and geochemical characteristics of a glacial clay deposit. KC harbors surprising bacterial species richness, with at least three distinct community types. We show that the deposit has clines of inorganic elements that can be leached by pH, which may be drivers of community structure. We also note the prevalence of Gallionellaceae in samples recovered near the surface, as well as taxa that include medically or economically important bacteria such as Actinomycetes and Paenibacillus These results provide insight into the microbial taxa that may be the source of KC antibacterial activity and suggest that natural clays may be rich sources of microbial and molecular diversity. IMPORTANCE Identifying and characterizing the resident microbial populations (bacteria, viruses, protozoa, and fungi) is key to understanding the ecology, chemistry, and homeostasis of virtually all sites on Earth. The Kisameet Bay deposit in British Columbia, Canada, holds a novel glacial clay with a history of medicinal use by local indigenous people. We previously showed that it has potent activity against a variety of antibiotic-resistant bacteria, suggesting it could complement our dwindling arsenal of antibiotics. Here, we have characterized the microbiome of this deposit to gain insight

Thickness Dependence of Optoelectrical Properties of Mo-Doped In2O3 Films Deposited on Polyethersulfone Substrates by Ion-Beam-Assisted Evaporation

Directory of Open Access Journals (Sweden)

Chin-Chiuan Kuo

2010-01-01

Full Text Available Indium molybdenum oxide (IMO films were deposited onto the polyethersulfone (PES substrates by ion-beam-assisted evaporation (IBAE deposition at low temperature in this study. The effects of film thickness on their optical and electrical properties were investigated. The results show that the deposited IMO films exhibit a preferred orientation of B(222. The electrical resistivity of the deposited film initially reduces then subsequently increases with film thickness. The IMO film with the lowest resistivity of 7.61 × 10−4 ohm-cm has been achieved when the film thickness is 120 nm. It exhibits a satisfactory surface roughness pv of 8.75 nm and an average visible transmittance of 78.7%.

Magnetic properties of Pr-Fe-B thick-film magnets deposited on Si substrates with glass buffer layer

Science.gov (United States)

Nakano, M.; Kurosaki, A.; Kondo, H.; Shimizu, D.; Yamaguchi, Y.; Yamashita, A.; Yanai, T.; Fukunaga, H.

2018-05-01

In order to improve the magnetic properties of PLD-made Pr-Fe-B thick-film magnets deposited on Si substrates, an adoption of a glass buffer layer was carried out. The glass layer could be fabricated under the deposition rate of approximately 70 μm/h on a Si substrate using a Nd-YAG pulse laser in the vacuum atmosphere. The use of the layer enabled us to reduce the Pr content without a mechanical destruction and enhance (BH)max value by approximately 20 kJ/m3 compared with the average value of non-buffer layered Pr-Fe-B films with almost the same thickness. It is also considered that the layer is also effective to apply a micro magnetization to the films deposited on Si ones.

Glacial modulation of mid-ocean ridge magmatism and anomalous Pacific Antarctic Ridge volcanism during Termination II

Science.gov (United States)

Asimow, P. D.; Lewis, M.; Lund, D. C.; Seeley, E.; McCart, S.; Mudahy, A.

2017-12-01

Glacially-driven sea level rise and fall may modulate submarine volcanism by superposing pressure changes on the tectonic decompression that causes melt production in the mantle below mid-ocean ridges. A number of recent studies have considered whether this effect is recorded in the periodicity of ridge flank bathymetry (Tolstoy, 2015; Crowley et al., 2015) but interpretation of the bathymetric data remains controversial (Goff, 2016; Olive et al., 2016). We have pursued an independent approach using hydrothermal metals in well-dated near-ridge sediment cores. Along the full length of the East Pacific Rise, in areas of the ocean with widely variable biologic productivity, there are large and consistent rises in Fe, Mn, and As concentrations during the last two glacial terminations. We interpret these cores as records of excess hydrothermal flux due to delayed delivery to the axis of excess melt generated by the preceding falls in sea level. Here we discuss the potentially related discovery, in a core near the Pacific Antarctic Ridge (PAR), of a 10 cm thick layer of basaltic ash shards up to 250 mm in size, coincident with the penultimate deglaciation (Termination II). Although the site was 8 km off-axis at the time, the glasses have major element, volatile, and trace element composition consistent with more evolved members of the axial MORB suite from the nearby ridge axis. Their morphologies are typical of pyroclastic deposits created by explosive submarine volcanism (Clague et al., 2009). We propose that a period of low magmatic flux following a sea-level rise caused cooling of crustal magmatic systems, more advanced fractionation in the axial magma chamber, and increases in viscosity and volatile concentration. We hypothesize subsequent arrival of high magmatic flux during Termination II then reactivated the system and triggered an unusually vigorous series of explosive eruptions along this segment of the PAR. Ash layers recording large eruptions such as this one

Methane Hydrate Formation from Enhanced Organic Carbon Burial During Glacial Lowstands: Examples from the Gulf of Mexico

Science.gov (United States)

Malinverno, A.; Cook, A.; Daigle, H.; Oryan, B.

2017-12-01

Methane hydrates in fine-grained marine sediments are often found within veins and fractures occupying discrete depth intervals that are surrounded by hydrate-free sediments. As they are not connected with gas sources beneath the base of the methane hydrate stability zone (MHSZ), these isolated hydrate-bearing intervals have been interpreted as formed by in situ microbial methane. We investigate here the hypothesis that these hydrate deposits form in sediments that were deposited during glacial lowstands and contain higher amounts of labile particulate organic carbon (POC), leading to enhanced microbial methanogenesis. During Pleistocene lowstands, river loads are deposited near the steep top of the continental slope and turbidity currents transport organic-rich, fine-grained sediments to deep waters. Faster sedimentation rates during glacial periods result in better preservation of POC because of decreased exposure times to oxic conditions. The net result is that more labile POC enters the methanogenic zone and more methane is generated in these sediments. To test this hypothesis, we apply an advection-diffusion-reaction model with a time-dependent deposition of labile POC at the seafloor controlled by glacioeustatic sea level variations in the last 250 kyr. The model is run for parameters estimated at three sites drilled by the 2009 Gulf of Mexico Joint Industry Project: Walker Ridge in the Terrebonne Basin (WR313-G and WR313-H) and Green Canyon near the canyon embayment into the Sigsbee Escarpment (GC955-H). In the model, gas hydrate forms in sediments with higher labile POC content deposited during the glacial cycle between 230 and 130 kyr (marine isotope stages 6 and 7). The corresponding depth intervals in the three sites contain hydrates, as shown by high bulk electrical resistivities and resistive subvertical fracture fills. This match supports the hypothesis that enhanced POC burial during glacial lowstands can result in hydrate formation from in situ

Methane Hydrate Formation from Enhanced Organic Carbon Burial During Glacial Lowstands: Examples from the Gulf of Mexico

Energy Technology Data Exchange (ETDEWEB)

Malinverno, Alberto; Cook, Ann; Daigle, Hugh; Oryan, Bar

2017-12-15

Methane hydrates in fine-grained marine sediments are often found within veins and fractures occupying discrete depth intervals that are surrounded by hydrate-free sediments. As they are not connected with gas sources beneath the base of the methane hydrate stability zone (MHSZ), these isolated hydrate-bearing intervals have been interpreted as formed by in situ microbial methane. We investigate here the hypothesis that these hydrate deposits form in sediments that were deposited during glacial lowstands and contain higher amounts of labile particulate organic carbon (POC), leading to enhanced microbial methanogenesis. During Pleistocene lowstands, river loads are deposited near the steep top of the continental slope and turbidity currents transport organic-rich, fine-grained sediments to deep waters. Faster sedimentation rates during glacial periods result in better preservation of POC because of decreased exposure times to oxic conditions. The net result is that more labile POC enters the methanogenic zone and more methane is generated in these sediments. To test this hypothesis, we apply an advection-diffusion-reaction model with a time-dependent deposition of labile POC at the seafloor controlled by glacioeustatic sea level variations in the last 250 kyr. The model is run for parameters estimated at three sites drilled by the 2009 Gulf of Mexico Joint Industry Project: Walker Ridge in the Terrebonne Basin (WR313-G and WR313-H) and Green Canyon near the canyon embayment into the Sigsbee Escarpment (GC955-H). In the model, gas hydrate forms in sediments with higher labile POC content deposited during the glacial cycle between 230 and 130 kyr (marine isotope stages 6 and 7). The corresponding depth intervals in the three sites contain hydrates, as shown by high bulk electrical resistivities and resistive subvertical fracture fills. This match supports the hypothesis that enhanced POC burial during glacial lowstands can result in hydrate formation from in situ

Synthesis of thick diamond films by direct current hot-cathode plasma chemical vapour deposition

CERN Document Server

Jin Zeng Sun; Bai Yi Zhen; Lu Xian Yi

2002-01-01

The method of direct current hot-cathode plasma chemical vapour deposition has been established. A long-time stable glow discharge at large discharge current and high gas pressure has been achieved by using a hot cathode in the temperature range from 1100 degree C to 1500 degree C and non-symmetrical configuration of the poles, in which the diameter of the cathode is larger than that of anode. High-quality thick diamond films, with a diameter of 40-50 mm and thickness of 0.5-4.2 mm, have been synthesized by this method. Transparent thick diamond films were grown over a range of growth rates between 5-10 mu m/h. Most of the thick diamond films have thermal conductivities of 10-12 W/K centre dot cm. The thick diamond films with high thermal conductivity can be used as a heat sink of semiconducting laser diode array and as a heat spreading and isolation substrate of multichip modules. The performance can be obviously improved

Process-structure-property relationships of micron thick gadolinium oxide films deposited by reactive electron beam-physical vapor deposition (EB-PVD)

Science.gov (United States)

Grave, Daniel A.

Gadolinium oxide (Gd2O3) is an attractive material for solid state neutron detection due to gadolinium's high thermal neutron capture cross section. Development of neutron detectors based on Gd2 O3 requires sufficiently thick films to ensure neutron absorption. In this dissertation work, the process-structure-property relationships of micron thick Gd2O3 films deposited by reactive electron-beam physical vapor deposition (EB-PVD) were studied. Through a systematic design of experiments, fundamental studies were conducted to determine the effects of processing conditions such as deposition temperature, oxygen flow rate, deposition rate, and substrate material on Gd2O3 film crystallographic phase, texture, morphology, grain size, density, and surface roughness. Films deposited at high rates (> 5 A/s) were examined via x-ray diffraction (XRD) and Raman spectroscopy. Quantitative phase volume calculations were performed via a Rietveld refinement technique. All films deposited at high rates were found to be fully monoclinic or mixed cubic/monoclinic phase. Generally, increased deposition temperature and increased oxygen flow resulted in increased cubic phase volume. As film thickness increased, monoclinic phase volume increased. Grazing incidence x-ray diffraction (GIXRD) depth profiling analysis showed that cubic phase was only present under large incidence angle (large penetration depth) measurements, and after a certain point, only monoclinic phase was grown. This was confirmed by transmission electron microscopy (TEM) analysis with selected area diffraction (SAD). Based on this information, a large compressive stress was hypothesized to cause the formation of the monoclinic phase and this hypothesis was confirmed by demonstrating the existence of a stress induced phase transition. An experiment was designed to introduce compressive stress into the Gd2O 3 films via ion beam assisted deposition (IBAD). This allowed for systematic increase in compressive stress while

Model, prediction, and experimental verification of composition and thickness in continuous spread thin film combinatorial libraries grown by pulsed laser deposition

International Nuclear Information System (INIS)

Bassim, N. D.; Schenck, P. K.; Otani, M.; Oguchi, H.

2007-01-01

Pulsed laser deposition was used to grow continuous spread thin film libraries of continuously varying composition as a function of position on a substrate. The thickness of each component that contributes to a library can be empirically modeled to a bimodal cosine power distribution. We deposited ternary continuous spread thin film libraries from Al 2 O 3 , HfO 2 , and Y 2 O 3 targets, at two different background pressures of O 2 : 1.3 and 13.3 Pa. Prior to library deposition, we deposited single component calibration films at both pressures in order to measure and fit the thickness distribution. Following the deposition and fitting of the single component films, we predict both the compositional coverage and the thickness of the libraries. Then, we map the thickness of the continuous spread libraries using spectroscopic reflectometry and measure the composition of the libraries as a function of position using mapping wavelength-dispersive spectrometry (WDS). We then compare the compositional coverage of the libraries and observe that compositional coverage is enhanced in the case of 13.3 Pa library. Our models demonstrate linear correlation coefficients of 0.98 for 1.3 Pa and 0.98 for 13.3 Pa with the WDS

Temperature-dependent evolution of the wetting layer thickness during Ge deposition on Si(001).

Science.gov (United States)

Bergamaschini, R; Brehm, M; Grydlik, M; Fromherz, T; Bauer, G; Montalenti, F

2011-07-15

The evolution of the wetting layer (WL) thickness during Ge deposition on Si(001) is analyzed with the help of a rate-equation approach. The combined role of thickness, island volume and shape-dependent chemical potentials is considered. Several experimental observations, such as WL thinning following the pyramid-to-dome transformation, are captured by the model, as directly demonstrated by a close comparison with photoluminescence measurements (PL) on samples grown at three different temperatures. The limitations of the model in describing late stages of growth are critically addressed.

Predicting future glacial lakes in Austria using different modelling approaches

Science.gov (United States)

Otto, Jan-Christoph; Helfricht, Kay; Prasicek, Günther; Buckel, Johannes; Keuschnig, Markus

2017-04-01

Glacier retreat is one of the most apparent consequences of temperature rise in the 20th and 21th centuries in the European Alps. In Austria, more than 240 new lakes have formed in glacier forefields since the Little Ice Age. A similar signal is reported from many mountain areas worldwide. Glacial lakes can constitute important environmental and socio-economic impacts on high mountain systems including water resource management, sediment delivery, natural hazards, energy production and tourism. Their development significantly modifies the landscape configuration and visual appearance of high mountain areas. Knowledge on the location, number and extent of these future lakes can be used to assess potential impacts on high mountain geo-ecosystems and upland-lowland interactions. Information on new lakes is critical to appraise emerging threads and potentials for society. The recent development of regional ice thickness models and their combination with high resolution glacier surface data allows predicting the topography below current glaciers by subtracting ice thickness from glacier surface. Analyzing these modelled glacier bed surfaces reveals overdeepenings that represent potential locations for future lakes. In order to predict the location of future glacial lakes below recent glaciers in the Austrian Alps we apply different ice thickness models using high resolution terrain data and glacier outlines. The results are compared and validated with ice thickness data from geophysical surveys. Additionally, we run the models on three different glacier extents provided by the Austrian Glacier Inventories from 1969, 1998 and 2006. Results of this historical glacier extent modelling are compared to existing glacier lakes and discussed focusing on geomorphological impacts on lake evolution. We discuss model performance and observed differences in the results in order to assess the approach for a realistic prediction of future lake locations. The presentation delivers

Effect of thickness on structural, electrical, optical and magnetic properties of Co and Al doped ZnO films deposited by sol-gel route

Energy Technology Data Exchange (ETDEWEB)

Sharma, Mamta [Department of Electronic Science, University of Delhi South Campus, New Delhi 110021 (India); Mehra, R.M. [Department of Electronic Science, University of Delhi South Campus, New Delhi 110021 (India)], E-mail: rammehra2003@yahoo.com

2008-12-30

This paper reports deposition and characterization of Zn{sub 0.94}Co{sub 0.05}Al{sub 0.01}O films of thickness ranging from 70 nm to 400 nm. These films were deposited on a glass (Corning, 7059) substrate using sol-gel route. The films have been characterized to study their structural, electrical, optical and magnetic properties. X-ray diffraction (XRD) and atomic force microscopy (AFM) were used to study the crystallinity and growth mode of the films. The films deposited up to a thickness of 200 nm showed improvement in crystallinity and preferential c-axis orientation. A transition in the growth mode from vertical (c-axis) to lateral (a and b-axis) was observed with further increase in the thickness of the film. The average transmittance of the films for thickness less than 200 nm was above 80% in the visible region which decreased at higher thickness of the film. The resistivity of the film was found to decrease with increase in thickness up to 200 nm. Ferromagnetism, at room temperature, was confirmed for 200 nm and 400 nm thick films.

Effect of thickness on structural, electrical, optical and magnetic properties of Co and Al doped ZnO films deposited by sol-gel route

International Nuclear Information System (INIS)

Sharma, Mamta; Mehra, R.M.

2008-01-01

This paper reports deposition and characterization of Zn 0.94 Co 0.05 Al 0.01 O films of thickness ranging from 70 nm to 400 nm. These films were deposited on a glass (Corning, 7059) substrate using sol-gel route. The films have been characterized to study their structural, electrical, optical and magnetic properties. X-ray diffraction (XRD) and atomic force microscopy (AFM) were used to study the crystallinity and growth mode of the films. The films deposited up to a thickness of 200 nm showed improvement in crystallinity and preferential c-axis orientation. A transition in the growth mode from vertical (c-axis) to lateral (a and b-axis) was observed with further increase in the thickness of the film. The average transmittance of the films for thickness less than 200 nm was above 80% in the visible region which decreased at higher thickness of the film. The resistivity of the film was found to decrease with increase in thickness up to 200 nm. Ferromagnetism, at room temperature, was confirmed for 200 nm and 400 nm thick films.

Enhancing rates of erosion and uplift through glacial perturbations

Science.gov (United States)

Norton, Kevin; Schlunegger, Fritz; Abbühl, Luca

2010-05-01

Research over the past decade has shown that the pattern of modern rock uplift in the Swiss Alps correlates with both long-term (thermochronometers) and short-term (cosmogenic nuclide-derived denudation rates, sediment loads, lake fills) measures of erosion. This correlation has been attributed alternately to isostatic causes (compensation to erosion and/or glacial unloading) and tectonic forces (ongoing collision and partial delamination). Of these potential driving forces, only isostatic compensation to erosion fits all available structural, geodetic, and flexural models. We explore this uplift-erosion relationship by analyzing river channel steepness for Alpine rivers. Zones of oversteepening, and hence enhanced stream power, are associated with glacial erosion and deposition during LGM and earlier glaciations, resulting in the focusing of erosion into the inner gorges which connect hanging tributary valleys to the main glacial trunk valley. These inner gorges are transient zones in which fluvial and hillslope processes are in the process of re-adjusting this glacially perturbed landscape. Bedrock properties also play a major role in the response time of these adjustments. Glacially generated knickzones are located within 5 km of the trunk stream in the Rhone valley where resistant lithologies dominate (gneiss), whereas the knickzones have migrated as much as 10 km or further in the less resistant rocks (buendnerschists) of the Rhine valley. We suggest that the rock uplift pattern is controlled by surface denudation as set by the glacial-interglacial history of the Alps. Rapid, focused erosion results in rapid rock uplift rates in the Central Swiss Alps, where glaciers were most active. An interesting ramification of this reasoning is that in the absence of glacial perturbation, both rock uplift rates and denudation rates would be substantially lower in this isostatically compensated mountain belt.

Glacial cycles

DEFF Research Database (Denmark)

Kaufmann, R. K.; Juselius, Katarina

We use a statistical model, the cointegrated vector autoregressive model, to assess the degree to which variations in Earth's orbit and endogenous climate dynamics can be used to simulate glacial cycles during the late Quaternary (390 kyr-present). To do so, we estimate models of varying complexity...... and compare the accuracy of their in-sample simulations. Results indicate that strong statistical associations between endogenous climate variables are not enough for statistical models to reproduce glacial cycles. Rather, changes in solar insolation associated with changes in Earth's orbit are needed...... to simulate glacial cycles accurately. Also, results suggest that non-linear 10 dynamics, threshold effects, and/or free oscillations may not play an overriding role in glacial cycles....

Coupled Northern Hemisphere permafrost-ice-sheet evolution over the last glacial cycle

Science.gov (United States)

Willeit, M.; Ganopolski, A.

2015-09-01

Permafrost influences a number of processes which are relevant for local and global climate. For example, it is well known that permafrost plays an important role in global carbon and methane cycles. Less is known about the interaction between permafrost and ice sheets. In this study a permafrost module is included in the Earth system model CLIMBER-2, and the coupled Northern Hemisphere (NH) permafrost-ice-sheet evolution over the last glacial cycle is explored. The model performs generally well at reproducing present-day permafrost extent and thickness. Modeled permafrost thickness is sensitive to the values of ground porosity, thermal conductivity and geothermal heat flux. Permafrost extent at the Last Glacial Maximum (LGM) agrees well with reconstructions and previous modeling estimates. Present-day permafrost thickness is far from equilibrium over deep permafrost regions. Over central Siberia and the Arctic Archipelago permafrost is presently up to 200-500 m thicker than it would be at equilibrium. In these areas, present-day permafrost depth strongly depends on the past climate history and simulations indicate that deep permafrost has a memory of surface temperature variations going back to at least 800 ka. Over the last glacial cycle permafrost has a relatively modest impact on simulated NH ice sheet volume except at LGM, when including permafrost increases ice volume by about 15 m sea level equivalent in our model. This is explained by a delayed melting of the ice base from below by the geothermal heat flux when the ice sheet sits on a porous sediment layer and permafrost has to be melted first. Permafrost affects ice sheet dynamics only when ice extends over areas covered by thick sediments, which is the case at LGM.

Coupled Northern Hemisphere permafrost–ice-sheet evolution over the last glacial cycle

Directory of Open Access Journals (Sweden)

M. Willeit

2015-09-01

Full Text Available Permafrost influences a number of processes which are relevant for local and global climate. For example, it is well known that permafrost plays an important role in global carbon and methane cycles. Less is known about the interaction between permafrost and ice sheets. In this study a permafrost module is included in the Earth system model CLIMBER-2, and the coupled Northern Hemisphere (NH permafrost–ice-sheet evolution over the last glacial cycle is explored. The model performs generally well at reproducing present-day permafrost extent and thickness. Modeled permafrost thickness is sensitive to the values of ground porosity, thermal conductivity and geothermal heat flux. Permafrost extent at the Last Glacial Maximum (LGM agrees well with reconstructions and previous modeling estimates. Present-day permafrost thickness is far from equilibrium over deep permafrost regions. Over central Siberia and the Arctic Archipelago permafrost is presently up to 200–500 m thicker than it would be at equilibrium. In these areas, present-day permafrost depth strongly depends on the past climate history and simulations indicate that deep permafrost has a memory of surface temperature variations going back to at least 800 ka. Over the last glacial cycle permafrost has a relatively modest impact on simulated NH ice sheet volume except at LGM, when including permafrost increases ice volume by about 15 m sea level equivalent in our model. This is explained by a delayed melting of the ice base from below by the geothermal heat flux when the ice sheet sits on a porous sediment layer and permafrost has to be melted first. Permafrost affects ice sheet dynamics only when ice extends over areas covered by thick sediments, which is the case at LGM.

Reconnaissance map showing thickness of volcanic ash deposits in the greater Hilo area, Hawaii

Science.gov (United States)

Buchanan-Banks, Jane M.

1983-01-01

This study was undertaken to determine the thickness and distribution of volcanic ash deposits in the greater Hilo area, Hawaii, as a step toward evaluating their susceptibility to failure during earthquake shaking. On several occasions their instability has resulted in serious damage. For example, the 1868 earthquake (m=7+), following a prolonged rainy period, caused a debris flow of hillside ash deposits that killed 31 people in Wood Valley (Bringham, 1869). The 1973 Honomu earthquake (m=6.2) resulted in more damage from shaking to areas underlain by ash deposits in the older part of Hilo than in other areas, and soil slips in ash, as well as rockfalls, were common along the roads north of town (Nielsen and others, 1977). 

Hydrogeology and water quality of glacial-drift aquifers in the Bemidji-Bagley area, Beltrami, Clearwater, Cass, and Hubbard counties, Minnesota

Science.gov (United States)

Stark, J.R.; Busch, J.P.; Deters, M.H.

1991-01-01

Unconfined and the upper confined aquifers in glacial drift are the primary sources of water in a 1,600 square-mile area including parts of Beltrami, Cass, Clearwater, and Hubbard Counties, Minnesota. The unconfineddrift aquifer consists of coarse sand and gravel in the center of the study area. The total area underlain by the unconfined-drift aquifer is approximately 550 square miles. The unconfined aquifer ranges in thickness from 0 to 130 feet, and is greater than 20 feet thick over an area of 280 square miles. On the basis of scant data, the transmissivity of the unconfined aquifer ranges from less than 70 feet squared per day in the south and west to greater than 8,900 feet squared per day in an area west of Bemidji. Well yields from 10 to 300 gallons per minute are possible in some areas. The unconfined and upper confined-drift aquifers are separated by a fine-grained confining unit of till or lake deposits.

Growth of thick La2Zr2O7 buffer layers for coated conductors by polymer-assisted chemical solution deposition

International Nuclear Information System (INIS)

Zhang, Xin; Zhao, Yong; Xia, Yudong; Guo, Chunsheng; Cheng, C.H.; Zhang, Yong; Zhang, Han

2015-01-01

Highlights: • We develops a low-cost and high-efficient technology of fabricating LZO buffer layers. • Sufficient thickness LZO buffer layers have been obtained on NiW (2 0 0) alloy substrate. • Highly biaxially textured YBCO thin film has been deposited on LZO/NiW. - Abstract: La 2 Zr 2 O 7 (LZO) epitaxial films have been deposited on LaAlO 3 (LAO) (1 0 0) single-crystal surface and bi-axially textured NiW (2 0 0) alloy substrate by polymer-assisted chemical solution deposition, and afterwards studied with XRD, SEM and AFM approaches. Highly in-plane and out-of-plane oriented, dense, smooth, crack free and with a sufficient thickness (>240 nm) LZO buffer layers have been obtained on LAO (1 0 0) single-crystal surface; The films deposited on NiW (2 0 0) alloy substrate are also found with high degree in-plane and out-of-plane texturing, good density with pin-hole-free, micro-crack-free nature and a thickness of 300 nm. Highly epitaxial 500 nm thick YBa 2 Cu 3 O 7−x (YBCO) thin film exhibits the self-field critical current density (Jc) reached 1.3 MA/cm 2 at 77 K .These results demonstrate the LZO epi-films obtained with current techniques have potential to be a buffer layer for REBCO coated conductors

Glacial heritage: knowledge, inventory and promotion in the Chablais area (France, Switzerland)

Science.gov (United States)

Perret, A.; Reynard, E.; Delannoy, J.-J.

2012-04-01

This study is part of an Interreg IVA project (www.123chablais.com) dealing with the promotion of different types of natural and cultural heritage in the Chablais area (French and Swiss Prealps) and is linked to the candidature of the French Chablais territory for the European Geoparks Network. The objective of the study is to develop a strategy for the promotion of the glacial heritage (landforms, deposits) in an area where the geomorphological features are highly influenced by glacial history and where key concepts in the Quaternary sciences were developed (e.g. the theory of multiple glaciations by Morlot in 1859), but that is now nearly completely deglaciated. The challenge is to find solutions to explain why the glacial heritage is so important for the regional economy and how it influences the life of inhabitants (e.g. Evian and Thonon mineral water, extraction industry, landscape and tourism), even if glaciers are not so impressive than in other parts of the Alps. The research is divided in three parts. (1) The first one aims to enhance knowledge on glacial landforms and deposits. The study area, that is quite large, has been intensively studied for more than two centuries; nevertheless, some parts have been only poorly studied. Intensive field survey was carried out to fill in the gaps of knowledge and some landforms, such as erratic boulders, have been dated in order to establish a chronology of deglaciation. All of these different elements have been included in a Geographic Information System with the aim of establishing maps of glacial stages in the Chablais area. (2) From this, an inventory of glacial geosites has been carried out, using the assessment method developed by Reynard et al. (2007). A specific focus has been on the assessment of the potential of the selected sites for educational purposes and geotourist promotion. (3) The last part has been the preparation of adapted educational and promotional supports. In particular, an exhibition will be

Origin, Extent, and Thickness of Quaternary Geologic Units in the Willamette Valley, Oregon

Science.gov (United States)

O'Connor, Jim E.; Sarna-Wojcicki, Andrei M.; Wozniak, Karl C.; Polette, Danial J.; Fleck, Robert J.

2001-01-01

major tributaries. 3) Between 15,000 and 12,700 years ago, dozens of floods from Glacial Lake Missoula flowed up the Willamette Valley from the Columbia River, depositing up to 35 m of gravel, sand, silt, and clay. 4) Subsequent to 12,000 years ago, Willamette River sediment and flow regimes changed significantly: the Pleistocene braided river systems that had formed vast plains of sand and gravel evolved to incised and meandering rivers that are constructing today's fine-grained floodplains and gravelly channel deposits. Sub-surface channel facies of this unit are loose and unconsolidated and are highly permeable zones of substantial groundwater flow that is likely to be well connected to surface flow in the Willamette River and major tributaries. Stratigraphic exposures and drillers' logs indicate that this unit is mostly between 5 and 15 m thick.

The dispersion of fibrous amphiboles by glacial processes in the area surrounding Libby, Montana, USA

Science.gov (United States)

Langer, William H.; Van Gosen, Bradley S.; Meeker, Gregory P.; Adams, David T.; Hoefen, Todd M.

2011-01-01

Mining operations began at a world-class vermiculite deposit at Vermiculite Mountain near Libby, Montana, circa 1920 and ended in 1990. Fibrous and asbestiform amphiboles intergrown with vermiculite ore are suspected to be a causative factor in an abnormally high number of cases of respiratory diseases in former mine and mill workers, and in residents of Libby. The question addressed in this report is whether some of the amphibole from Vermiculite Mountain could have been dispersed by Pleistocene glacial processes rather than by human activity after vermiculite mining began. The history of Pinedale glaciation in the Libby area provides a framework for estimating the presence and distribution of asbestiform amphiboles derived from Vermiculite Mountain and found in naturally occurring sediments of Glacial Lake Kootenai that underlie the Libby Valley area. There were two situations where sediments derived from Vermiculite Mountain were deposited into Glacial Lake Kootenai: (1) as lake-bottom sediments derived from meltwater flowing down Rainy Creek when the valley south of Vermiculite Mountain was free of ice but active ice still covered Vermiculite Mountain; and (2) as lake-bottom sediments eroded from the Rainy Creek outwash and re-deposited during a re-advance of the Purcell Trench Glacier lobe near Moyie Springs, Idaho.

Millennial-scale variability in dust deposition, marine export production, and nutrient consumption in the glacial subantarctic ocean (Invited)

Science.gov (United States)

Martinez-Garcia, A.; Sigman, D. M.; Anderson, R. F.; Ren, H. A.; Hodell, D. A.; Straub, M.; Jaccard, S.; Eglinton, T. I.; Haug, G. H.

2013-12-01

Based on the limitation of modern Southern Ocean phytoplankton by iron and the evidence of higher iron-bearing dust fluxes to the ocean during ice ages, it has been proposed that iron fertilization of Southern Ocean phytoplankton contributed to the reduction in atmospheric CO2 during ice ages. In the Subantarctic zone of the Atlantic Southern Ocean, glacial increases in dust flux and export production have been documented, supporting the iron fertilization hypothesis. However, these observations could be interpreted alternatively as resulting from the equatorward migration of Southern Ocean fronts during ice ages if the observed productivity rise was not accompanied by an increase in major nutrient consumption. Here, new 230Th-normalized lithogenic and opal fluxes are combined with high-resolution biomarker measurements to reconstruct millennial-scale changes in dust deposition and marine export production in the subantarctic Atlantic over the last glacial cycle. In the same record foraminifera-bound nitrogen isotopes are used to reconstruct ice age changes in surface nitrate utilization, providing a comprehensive test of the iron fertilization hypothesis. Elevation in foraminifera-bound δ15N, indicating more complete nitrate consumption, coincides with times of surface cooling and greater dust flux and export production. These observations indicate that the ice age Subantarctic was characterized by iron fertilized phytoplankton growth. The resulting strengthening of the Southern Ocean's biological pump can explain the ~40 ppm lowering of CO2 that characterizes the transitions from mid-climate states to full ice age conditions as well as the millennial-scale atmospheric CO2 fluctuations observed within the last ice age

The Glacial and Relative Sea Level History of Southern Banks Island, NT, Canada

Science.gov (United States)

Vaughan, Jessica Megan

The mapping and dating of surficial glacial landforms and sediments across southern Banks Island document glaciation by the northwest Laurentide Ice Sheet (LIS) during the last glacial maximum. Geomorphic landforms confirm the operation of an ice stream at least 1000 m thick in Amundsen Gulf that was coalescent with thin, cold-based ice crossing the island's interior, both advancing offshore onto the polar continental shelf. Raised marine shorelines across western and southern Banks Island are barren, recording early withdrawal of the Amundsen Gulf Ice Stream prior to the resubmergence of Bering Strait and the re-entry of Pacific molluscs ~13,750 cal yr BP. This withdrawal resulted in a loss of ~60,000 km2 of ice --triggering drawdown from the primary northwest LIS divide and instigating changes in subsequent ice flow. The Jesse moraine belt on eastern Banks Island records a lateglacial stillstand and/or readvance of Laurentide ice in Prince of Wales Strait (13,750 -- 12,750 cal yr BP). Fossiliferous raised marine sediments that onlap the Jesse moraine belt constrain final deglaciation to ~12,600 cal yr BP, a minimum age for the breakup of the Amundsen Gulf Ice Stream. The investigation of a 30 m thick and 6 km wide stratigraphic sequence at Worth Point, southwest Banks Island, identifies an advance of the ancestral LIS during the Mid-Pleistocene (sensu lato), substantially diversifying the glacial record on Banks Island. Glacial ice emplaced during this advance has persisted through at least two glacial-interglacial cycles, demonstrating the resilience of circumpolar permafrost. Pervasive deformation of the stratigraphic sequence also records a detailed history of glaciotectonism in proglacial and subglacial settings that can result from interactions between cold-based ice and permafrost terrain. This newly recognized history rejects the long-established paleoenvironmental model of Worth Point that assumed a simple 'layer-cake' stratigraphy.

Glacial geology of the upper Wairau Valley, Marlborough, New Zealand

International Nuclear Information System (INIS)

McCalpin, J.P.

1992-01-01

Late Pleistocene glaciers in the upper Wairau Valley deposited four groups of moraines inferred to represent one Waimean ice advance, two Otiran ice advances, and an advance of early Aranuian age. The Waimean and early Otiran glaciers advanced into Tarndale Valley, deposited terminal moraines, and shed outwash down both the Alma River and Travellers Valley. The middle Otiran glacier terminated in northern Tarndale Valley and shed outwash from the southern part of its terminus down the Alma River. The north side of the terminus abutted a large ice-dammed lake in the Wairau Gorge, and fan-deltas graded to an old shore level at an elevation of 1040 m. Well-preserved moraines at the mouths of four glaciated tributaries may be middle Otiran recessional, or late Otiran terminal moraines. The latest ice advance extended 11 km down the upper Wairau Valley and deposited a subdued moraine at Island Gully. The composite chronology of the latest glacial advance based on 10 radiocarbon ages suggests it occurred between about 9.5 and 10.2 ka. This age span is similar to that of early Aranuian glacial advances dated by other workers in the Southern Alps, and may reflect Younger Dryas cooling. (author). 22 refs., 10 figs., 3 tabs

Glaciolacustrine deposits formed in an ice-dammed tributary valley in the south-central Pyrenees: New evidence for late Pleistocene climate

Science.gov (United States)

Sancho, Carlos; Arenas, Concha; Pardo, Gonzalo; Peña-Monné, José Luis; Rhodes, Edward J.; Bartolomé, Miguel; García-Ruiz, José M.; Martí-Bono, Carlos

2018-04-01

Combined geomorphic features, stratigraphic characteristics and sedimentologic interpretation, coupled with optically stimulated luminescence (OSL) dates, of a glacio-fluvio-lacustrine sequence (Linás de Broto, northern Spain) provide new information to understand the palaeoenvironmental significance of dynamics of glacier systems in the south-central Pyrenees during the Last Glacial Cycle (≈130 ka to 14 ka). The Linás de Broto depositional system consisted of a proglacial lake fed primarily by meltwater streams emanating from the small Sorrosal glacier and dammed by a lateral moraine of the Ara trunk glacier. The resulting glacio-fluvio-lacustrine sequence, around 55 m thick, is divided into five lithological units consisting of braided fluvial (gravel deposits), lake margin (gravel and sand deltaic deposits) and distal lake (silt and clay laminites) facies associations. Evolution of the depositional environment reflects three phases of progradation of a high-energy braided fluvial system separated by two phases of rapid expansion of the lake. Fluvial progradation occurred during short periods of ice melting. Lake expansion concurred with ice-dam growth of the trunk glacier. The first lake expansion occurred over a time range between 55 ± 9 ka and 49 ± 11 ka, and is consistent with the age of the Viu lateral moraine (49 ± 8 ka), which marks the maximum areal extent of the Ara glacier during the Last Glacial Cycle. These dates confirm that the maximum areal extent of the glacier occurred during Marine Isotope Stages 4 and 3 in the south-central Pyrenees, thus before the Last Glacial Maximum. The evolution of the Linás de Broto depositional system during this maximum glacier extent was modulated by climate oscillations in the northern Iberian Peninsula, probably related to latitudinal shifts of the atmospheric circulation in the southern North-Atlantic Ocean, and variations in summer insolation intensity.

Pyrite sulfur isotopes reveal glacial-interglacial environmental changes

Science.gov (United States)

Pasquier, Virgil; Sansjofre, Pierre; Rabineau, Marina; Revillon, Sidonie; Houghton, Jennifer; Fike, David A.

2017-06-01

The sulfur biogeochemical cycle plays a key role in regulating Earth’s surface redox through diverse abiotic and biological reactions that have distinctive stable isotopic fractionations. As such, variations in the sulfur isotopic composition (δ34S) of sedimentary sulfate and sulfide phases over Earth history can be used to infer substantive changes to the Earth’s surface environment, including the rise of atmospheric oxygen. Such inferences assume that individual δ34S records reflect temporal changes in the global sulfur cycle; this assumption may be well grounded for sulfate-bearing minerals but is less well established for pyrite-based records. Here, we investigate alternative controls on the sedimentary sulfur isotopic composition of marine pyrite by examining a 300-m drill core of Mediterranean sediments deposited over the past 500,000 y and spanning the last five glacial-interglacial periods. Because this interval is far shorter than the residence time of marine sulfate, any change in the sulfur isotopic record preserved in pyrite (δ34Spyr) necessarily corresponds to local environmental changes. The stratigraphic variations (>76‰) in the isotopic data reported here are among the largest ever observed in pyrite, and are in phase with glacial-interglacial sea level and temperature changes. In this case, the dominant control appears to be glacial-interglacial variations in sedimentation rates. These results suggest that there exist important but previously overlooked depositional controls on sedimentary sulfur isotope records, especially associated with intervals of substantial sea level change. This work provides an important perspective on the origin of variability in such records and suggests meaningful paleoenvironmental information can be derived from pyrite δ34S records.

Room temperature synthesis of indium tin oxide nanotubes with high precision wall thickness by electroless deposition

Directory of Open Access Journals (Sweden)

Mario Boehme

2011-02-01

Full Text Available Conductive nanotubes consisting of indium tin oxide (ITO were fabricated by electroless deposition using ion track etched polycarbonate templates. To produce nanotubes (NTs with thin walls and small surface roughness, the tubes were generated by a multi-step procedure under aqueous conditions. The approach reported below yields open end nanotubes with well defined outer diameter and wall thickness. In the past, zinc oxide films were mostly preferred and were synthesized using electroless deposition based on aqueous solutions. All these methods previously developed, are not adaptable in the case of ITO nanotubes, even with modifications. In the present work, therefore, we investigated the necessary conditions for the growth of ITO-NTs to achieve a wall thickness of around 10 nm. In addition, the effects of pH and reductive concentrations for the formation of ITO-NTs are also discussed.

Heat deposition, damage, and tritium breeding characteristics in thick liquid wall blanket concepts

International Nuclear Information System (INIS)

Youssef, M.Z.; Abdou, M.A.

2000-01-01

The advanced power extraction (APEX) study aims at exploring new and innovative blanket concepts that can efficiently extract power from fusion devices with high neutron wall load. Among the concepts under investigation is the free liquid FW/liquid blanket concept in which a fast flowing liquid FW (∼2-3 cm) is followed by thick flowing blanket (B) of ∼40-50 cm thickness with minimal amount of structure. The liquid FW/B are contained inside the vacuum vessel (VV) with a shielding zone (S) located either behind the VV and outside the vacuum boundary (case A) or placed after the FW/B and inside the VV (case B). In this paper we investigate the nuclear characteristics of this concept in terms of: (1) attenuation capability of the liquid FW/B/S and protection of the VV and magnet against radiation damage; (2) profiles of tritium production rate and tritium breeding ratio (TBR) for several liquid candidates; and (3) profiles of heat deposition rate and power multiplication. The candidate liquid breeders considered are Li, Flibe, Li-Sn, and Li-Pb. Parameters varied are (1) FW/B thickness, L, (2) Li-6 enrichment and (3) thickness of the shield

Origin and depositional environment of fine-grained sediments since the last glacial maximum in the southeastern Yellow Sea: evidence from rare earth elements

Science.gov (United States)

Um, In Kwon; Choi, Man Sik; Lee, Gwang Soo; Chang, Tae Soo

2015-12-01

Despite the well-reconstructed seismic stratigraphy of the Holocene mud deposit in the southeastern Yellow Sea, known as the Heuksan mud belt (HMB), the provenances of these sediments and their depositional environments are unclear, especially for the fine-grained sediments. According to seismic data (extracted from another article in this special issue), the HMB comprises several sedimentary units deposited since the last glacial maximum. Based on analytical results on rare earth elements, fine-grained sediments in all sedimentary units can be interpreted as mixtures of sediments discharged from Chinese and Korean rivers. The proportions of fine-grained sediments from Chinese rivers (74.5 to 80.0%) were constant and higher than those from Korean rivers in all units. This fact demonstrates that all units have the same fine-grained sediment provenance: units III-b and III-a, located in the middle and northern parts of the HMB and directly deposited from Chinese rivers during the sea-level lowstand, could be the sediment source for units II-b and II-a. Unit I, while ambiguous, is of mixed origin combining reworked sediments from nearby mud deposits and Changjiang River-borne material with those of the Keum River. The results of this study indicate that at least 18.6% of bulk sediments in the HMB clearly originate from Chinese rivers, despite its location close to the southwestern coast of Korea.

Dust fluxes and iron fertilization in Holocene and Last Glacial Maximum climates

Science.gov (United States)

Lambert, Fabrice; Tagliabue, Alessandro; Shaffer, Gary; Lamy, Frank; Winckler, Gisela; Farias, Laura; Gallardo, Laura; De Pol-Holz, Ricardo

2015-07-01

Mineral dust aerosols play a major role in present and past climates. To date, we rely on climate models for estimates of dust fluxes to calculate the impact of airborne micronutrients on biogeochemical cycles. Here we provide a new global dust flux data set for Holocene and Last Glacial Maximum (LGM) conditions based on observational data. A comparison with dust flux simulations highlights regional differences between observations and models. By forcing a biogeochemical model with our new data set and using this model's results to guide a millennial-scale Earth System Model simulation, we calculate the impact of enhanced glacial oceanic iron deposition on the LGM-Holocene carbon cycle. On centennial timescales, the higher LGM dust deposition results in a weak reduction of pump. This is followed by a further ~10 ppm reduction over millennial timescales due to greater carbon burial and carbonate compensation.

10Be dating of late-glacial moraines near the Cordillera Vilcanota and the Quelccaya Ice Cap, Peru

Science.gov (United States)

Kelly, M. A.; Thompson, L. G.

2004-12-01

The surface exposure method, based on the measurement of cosmogenic 10Be produced in quartz, is applied to determine the age of deposition of glacial moraines near the Cordillera Vilcanota and the Quelccaya Ice Cap (about 13° S, 70° W) in southeastern Peru. These data are useful for examining the timing of past glaciation in the tropical Andes and for comparison with chronologies of glaciation at higher latitudes. The preliminary data set consists of more than ten surface exposure ages. Samples used for dating are from the surfaces of boulders on a set of prominent moraines about four kilometers away from the present ice margins. The age of the moraine set was previously bracketed by radiocarbon dating of peat associated with the glacial deposits. Based on radiocarbon ages, these moraines were formed during the late-glacial period, just prior to the last glacial-interglacial transition. The surface exposure dating method enables the direct dating of the moraines. Surface exposure dates are cross-checked with the previously existing radiocarbon dates and provide a means to improve the chronology of past glaciation in the tropical Andes.

The use of multibeam backscatter intensity data as a tool for mapping glacial deposits in the Central North Sea, UK

Science.gov (United States)

Stewart, Heather; Bradwell, Tom

2014-05-01

gravelly sands and sandy gravels compared to the surrounding sandy and muddy sediments. Moraines are indicated as areas of high backscatter intensity and comprise coarse grained sediments. A range of moraine sizes have been identified from large scale moraines reflecting both frontal still stands or re-advances of the ice-sheet margin, de geer moraines and smaller moraines that may represent annual variations. Meltwater channels and tunnel valleys are revealed as areas of low backscatter intensity reflecting post-glacial soft sediment infill of the depressions incised into coarser grained and higher strength glacial deposits by these features.

Little Ice Age glacial geomorphology and sedimentology of Portage Glacier, South-Central Alaska

Directory of Open Access Journals (Sweden)

Carlos Córdova

2009-06-01

Full Text Available The study of glacial landforms and deposits is important, as it isdifficult to observe processes under modern glaciers and ice-sheets. Thus landscapes and sediments that are the product of present glaciation can give insight into processes that occurred during Pleistocene times. This study investigates the genesis of little ice age glacial landforms present in Portage Glacier, South-Central Alaska. The present day moraine morphology and sedimentology in Portage Glacier valley reveals the presence of two types of till and moraines. The clast-rich sandy diamicton present on the 1852 moraine is interpreted to be a basal till indicating this feature is a pushmoraine representing an advance or a standstill position of Portage Glacier in 1852. The moderately sorted gray sandy boulder gravel present on the 1900 and 1922 moraines is interpreted to be an ice-marginal deposit (ablation till with a mixture of supraglacial and glaciofluvial sediments deposited by slumping and stream sortingprocesses. All of these features are interpreted to be ablation moraines representing glacier retreat and moraine building in 1900 and1922.

Constraining the thickness of polar ice deposits on Mercury using the Mercury Laser Altimeter and small craters in permanently shadowed regions

Science.gov (United States)

Deutsch, Ariel N.; Head, James W.; Chabot, Nancy L.; Neumann, Gregory A.

2018-05-01

Radar-bright deposits at the poles of Mercury are located in permanently shadowed regions, which provide thermally stable environments for hosting and retaining water ice on the surface or in the near subsurface for geologic timescales. While the areal distribution of these radar-bright deposits is well characterized, their thickness, and thus their total mass and volume, remain poorly constrained. Here we derive thickness estimates for selected water-ice deposits using small, simple craters visible within the permanently shadowed, radar-bright deposits. We examine two endmember scenarios: in Case I, these craters predate the emplacement of the ice, and in Case II, these craters postdate the emplacement of the ice. In Case I, we find the difference between estimated depths of the original unfilled craters and the measured depths of the craters to find the estimated infill of material. The average estimated infilled material for 9 craters assumed to be overlain with water ice is ∼ 41-14+30 m, where 1-σ standard error of the mean is reported as uncertainty. Reported uncertainties are for statistical errors only. Additional systematic uncertainty may stem from georeferencing the images and topographic datasets, from the radial accuracy of the altimeter measurements, or from assumptions in our models including (1) ice is flat in the bowl-shaped crater and (2) there is negligible ice at the crater rims. In Case II, we derive crater excavation depths to investigate the thickness of the ice layer that may have been penetrated by the impact. While the absence of excavated regolith associated with the small craters observed suggests that impacts generally do not penetrate through the ice deposit, the spatial resolution and complex illumination geometry of images may limit the observations. Therefore, it is not possible to conclude whether the small craters in this study penetrate through the ice deposit, and thus Case II does not provide a constraint on the ice thickness

Adhesion-enhanced thick copper film deposition on aluminum oxide by an ion-beam-mixed Al seed layer

International Nuclear Information System (INIS)

Kim, Hyung-Jin; Park, Jae-Won

2012-01-01

We report a highly-adherent 30-μm Cu conductive-path coating on an aluminum-oxide layer anodized on an aluminum-alloy substrate for a metal-printed circuit-board application. A 50-nm Al layer was first coated with an e-beam evaporative deposition method on the anodized oxide, followed by ion bombardment to mix the interfacial region. Subsequently, a Cu coating was deposited onto the mixed seed layer to the designed thickness. Adhesions of the interface were tested by using tape adhesion test, and pull-off tests and showed commercially acceptable adhesions for such thick coating layers. The ion beam mixing (IBM) plays the role of fastening the thin seed coating layer to the substrate and enhancing the adhesion of the Cu conductive path on the anodized aluminum surface.

Residual stress in thick low-pressure chemical-vapor deposited polycrystalline SiC coatings on Si substrates

Science.gov (United States)

Choi, D.; Shinavski, R. J.; Steffier, W. S.; Spearing, S. M.

2005-04-01

Residual stress in thick coatings of polycrystalline chemical-vapor deposited SiC on Si substrates is a key variable that must be controlled if SiC is to be used in microelectromechanical systems. Studies have been conducted to characterize the residual stress level as a function of deposition temperature, Si wafer and SiC coating thickness, and the ratios of methyltrichlorosilane to hydrogen and hydrogen chloride. Wafer curvature was used to monitor residual stress in combination with a laminated plate analysis. Compressive intrinsic (growth) stresses were measured with magnitudes in the range of 200-300MPa; however, these can be balanced with the tensile stress due to the thermal-expansion mismatch to leave near-zero stress at room temperature. The magnitude of the compressive intrinsic stress is consistent with previously reported values of surface stress in combination with the competition between grain-boundary energy and elastic strain energy.

Cosmogenic evidence for limited local LGM glacial expansion, Denton Hills, Antarctica

Science.gov (United States)

Joy, Kurt; Fink, David; Storey, Bryan; De Pascale, Gregory P.; Quigley, Mark; Fujioka, Toshiyuki

2017-12-01

The geomorphology of the Denton Hills provides insight into the timing and magnitude of glacial retreats in a region of Antarctica isolated from the influence of the East Antarctic ice sheet. We present 26 Beryllium-10 surface exposure ages from a variety of glacial and lacustrine features in the Garwood and Miers valleys to document the glacial history of the area from 10 to 286 ka. Our data show that the cold-based Miers, Joyce and Garwood glaciers retreated little since their maximum positions at 37.2 ± 6.9 (1σ n = 4), 35.1 ± 1.5 (1σ, n = 3) and 35.6 ± 10.1 (1σ, n = 6) ka respectively. The similar timing of advance of all three glaciers and the lack of a significant glacial expansion during the global LGM suggests a local LGM for the Denton Hills between ca. 26 and 51 ka, with a mean age of 36.0 ± 7.5 (1σ, n = 13) ka. A second cohort of exposure ages provides constraints to the behaviour of Glacial Lake Trowbridge that formerly occupied Miers Valley in the late Pleistocene. These data show active modification of the landscape from ∼20 ka until the withdrawal of ice from the valley mouths, and deposition of Ross Sea Drift, at 10-14 ka.

Multiple origins of large hummock deposits in Alai Valley, Northern Pamir: Implications for palaeoclimate reconstructions

Science.gov (United States)

Reznichenko, N. V.; Andrews, G. R.; Geater, R. E.; Strom, A.

2017-05-01

This paper interprets the origin of several of the largest hummocky landform assemblages in the Alai Valley, Northern Pamir - a formerly glaciated intermontane depression. The vast hummocky deposits in the Koman-Suu and Achik-Tash river catchments are found to be of two contrasting modes of formation: glacial hummocks deposited during Koman and Lenin Glaciers withdraw and avalanche hummocks produced during catastrophic Koman and Lenin rock avalanches. The origins of the deposits we assessed through remote and field-based geomorphological mapping, as well as sedimentological investigations, which included clast analysis and the identification of micro-scale agglomerates indicative of rock avalanche emplacement. Both the Koman and Lenin rock avalanches were large, catastrophic events (with run-outs of 34 and 24 km, respectively, and a volume over 1 × 109 m3 each) that occurred subsequent to glacier withdrawal from the area. The complex conditions on the moment of the rock avalanche emplacement promoted unusual deposits geomorphology and extensive run-outs. The landslide landforms formed over the pre-existing glacial hummocks and fluvial deposits, and are geomorphologically and sedimentologically distinct from the larger glacial hummocks. The reconstruction of this sequence of events has implications for how hummock dating should be interpreted. This research illustrates large scale catastrophic landsliding in the glacial environment, and adds to the ongoing debate about the misidentification of rock avalanche deposits as of glacial origin, and their relevance to palaeoclimatological and palaeoseismological reconstructions.

Structure and corrosion behavior of sputter deposited cerium oxide based coatings with various thickness on Al 2024-T3 alloy substrates

Energy Technology Data Exchange (ETDEWEB)

Liu, Yuanyuan [College of Materials Science and Engineering, Chongqing University, Chongqing 400045 (China); Materials Research Center, Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, MO 65409 (United States); Huang, Jiamu, E-mail: huangjiamu@cqu.edu.cn [College of Materials Science and Engineering, Chongqing University, Chongqing 400045 (China); Claypool, James B.; Castano, Carlos E. [Materials Research Center, Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, MO 65409 (United States); O’Keefe, Matthew J., E-mail: mjokeefe@mst.edu [Materials Research Center, Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, MO 65409 (United States)

2015-11-15

Highlights: • Crystalline CeO{sub 2} coatings are deposited on Al 2024-T3 alloys by magnetron sputtering. • The crystal size and internal stress both increased with the thickness of CeO{sub 2} coating. • The ∼210 nm thick coating has the highest adhesion strength to the Al alloy substrate. • The ∼900 nm thick coating increased the corrosion resistance two orders of magnitude. • CeO{sub 2} coatings provide good cathodic inhibition for Al alloys by acting as physical barriers. - Abstract: Cerium oxide based coatings from ∼100 to ∼1400 nm in thickness were deposited onto Al 2024-T3 alloy substrates by magnetron sputtering of a 99.99% pure CeO{sub 2} target. The crystallite size of CeO{sub 2} coatings increased from 15 nm to 46 nm as the coating thickness increased from ∼100 nm to ∼1400 nm. The inhomogeneous lattice strain increased from 0.36% to 0.91% for the ∼100 nm to ∼900 nm thick coatings and slightly decreased to 0.89% for the ∼1400 nm thick coating. The highest adhesion strength to Al alloy substrates was for the ∼210 nm thick coating, due to a continuous film coverage and low internal stress. Electrochemical measurements indicated that sputter deposited crystalline CeO{sub 2} coatings acted as physical barriers that provide good cathodic inhibition for Al alloys in saline solution. The ∼900 nm thick CeO{sub 2} coated sample had the best corrosion performance that increased the corrosion resistance by two orders magnitude and lowered the cathodic current density 30 times compared to bare Al 2024-T3 substrates. The reduced defects and exposed surface, along with suppressed charge mobility, likely accounts for the improved corrosion performance as coating thickness increased from ∼100 nm to ∼900 nm. The corrosion performance decreased for ∼1400 nm thick coatings due in part to an increase in coating defects and porosity along with a decrease in adhesion strength.

Low-temperature plasma-enhanced atomic layer deposition of 2-D MoS2 : Large area, thickness control and tuneable morphology

NARCIS (Netherlands)

Sharma, A.; Verheijen, M.A.; Wu, L.; Karwal, S.; Vandalon, V.; Knoops, H.C.M.; Sundaram, R.S.; Hofmann, J.P.; Kessels, W.M.M.; Bol, A.A.

2018-01-01

Low-temperature controllable synthesis of monolayer-to-multilayer thick MoS2 with tuneable morphology is demonstrated by using plasma enhanced atomic layer deposition (PEALD). The characteristic self-limiting ALD growth with a growth-per-cycle of 0.1 nm per cycle and digital thickness control down

Robust TaNx diffusion barrier for Cu-interconnect technology with subnanometer thickness by metal-organic plasma-enhanced atomic layer deposition

International Nuclear Information System (INIS)

Kim, H.; Detavenier, C.; Straten, O. van der; Rossnagel, S.M.; Kellock, A.J.; Park, D.-G.

2005-01-01

TaN x diffusion barriers with good barrier properties at subnanometer thickness were deposited by plasma-enhanced atomic layer deposition (PE-ALD) from pentakis(dimethylamino)Ta. Hydrogen and/or nitrogen plasma was used as reactants to produce TaN x thin films with a different nitrogen content. The film properties including the carbon and oxygen impurity content were affected by the nitrogen flow during the process. The deposited film has nanocrystalline grains with hydrogen-only plasma, while the amorphous structure was obtained for nitrogen plasma. The diffusion barrier properties of deposited TaN films for Cu interconnects have been studied by thermal stress test based on synchrotron x-ray diffraction. The results indicate that the PE-ALD TaN films are good diffusion barriers even at a small thickness as 0.6 nm. Better diffusion barrier properties were obtained for higher nitrogen content. Based on a diffusion kinetics analysis, the nanocrystalline microstructure of the films was responsible for the better diffusion barrier properties compared to polycrystalline PE-ALD TaN films deposited from TaCl 5

Influence of the thickness of electrochemically deposited polyaniline used as hole transporting layer on the behaviour of polymer light-emitting diodes

Energy Technology Data Exchange (ETDEWEB)

Alonso, J.L. [Dpto. de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, Av. de la Universidad s/n, Ed. Torrepinet, 03202, Elche, Alicante (Spain)], E-mail: j.l.alonso@umh.es; Ferrer, J.C. [Dpto. de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, Av. de la Universidad s/n, Ed. Torrepinet, 03202, Elche, Alicante (Spain); Cotarelo, M.A.; Montilla, F. [Dpto. de Quimica Fisica e Instituto Universitario de Materiales de Alicante, Apdo. de Correos 99, E-03080, Alicante (Spain); Fernandez de Avila, S. [Dpto. de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, Av. de la Universidad s/n, Ed. Torrepinet, 03202, Elche, Alicante (Spain)

2009-02-27

An experimental study about the influence of the thickness of electrochemically deposited polyaniline (PANI), used as hole-transporting layer, on the behaviour of polymer light emitting diodes is presented. Two sets of devices with a different conjugated polymer used as active layer were prepared. Poly(9-vinylcarbazole) was used for the first type of devices, whereas Poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylene-vinylene] was used for the second type. Each set consists of five polymeric diodes in which the hole-transporting layer has been varied. In one case of each set no layer was deposited, in other one a Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) layer was deposited, and in the rest of the diodes a different thickness of electrochemically deposited PANI was employed. The optic and electronic characterization of the devices show that controlling the thickness of the PANI hole transporting layer, both the maximum emission peak of the electroluminescence curves and the driving voltage could be tuned. Furthermore, an exponential behaviour has been demonstrated for the maximum intensity of the electroluminescence curves as a function of the applied excitation voltage between anode and cathode.

Influence of the thickness of electrochemically deposited polyaniline used as hole transporting layer on the behaviour of polymer light-emitting diodes

International Nuclear Information System (INIS)

Alonso, J.L.; Ferrer, J.C.; Cotarelo, M.A.; Montilla, F.; Fernandez de Avila, S.

2009-01-01

An experimental study about the influence of the thickness of electrochemically deposited polyaniline (PANI), used as hole-transporting layer, on the behaviour of polymer light emitting diodes is presented. Two sets of devices with a different conjugated polymer used as active layer were prepared. Poly(9-vinylcarbazole) was used for the first type of devices, whereas Poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylene-vinylene] was used for the second type. Each set consists of five polymeric diodes in which the hole-transporting layer has been varied. In one case of each set no layer was deposited, in other one a Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) layer was deposited, and in the rest of the diodes a different thickness of electrochemically deposited PANI was employed. The optic and electronic characterization of the devices show that controlling the thickness of the PANI hole transporting layer, both the maximum emission peak of the electroluminescence curves and the driving voltage could be tuned. Furthermore, an exponential behaviour has been demonstrated for the maximum intensity of the electroluminescence curves as a function of the applied excitation voltage between anode and cathode

A Glacial Perspective on the Impact of Heinrich Stadials on North Atlantic Climate

Science.gov (United States)

Bromley, G. R.; Putnam, A. E.; Rademaker, K. M.; Balter, A.; Hall, B. L.

2017-12-01

The British Isles contain a rich geologic record of Late Pleistocene ice sheet behaviour in the NE North Atlantic basin. We are using cosmogenic 10Be surface-exposure dating, in conjunction with detailed glacial-geomorphic mapping, to reconstruct the timing and nature of cryospheric change - and thus climate variability - in northern Scotland since the Last Glacial Maximum. Our specific focus is Heinrich Stadial 1 (18,300-14,700 years ago), arguably the most significant abrupt climate event of the last glacial cycle and a major feature in global palaeoclimate records. Such constraint is needed because of currently conflicting models of how these events impact terrestrial environments and a recent hypothesis attributing this disparity to enhanced seasonality in the North Atlantic basin. To date, we have measured 10Be in > 30 samples from glacial erratics located on moraines deposited by the British Ice Sheet as it retreated from the continental shelf to its highland source regions. Our preliminary results indicate that the stadial was characterised by widespread deglaciation driven by atmospheric warming, a pattern that is suggestive of pronounced seasonality. Additionally, we report new exposure ages from moraines deposited during a subsequent phase of alpine glaciation (known locally as the Loch Lomond Readvance) that has long been attributed to the Younger Dryas stadial. With the growing focus on the full expression of stadials, and the inherent vulnerability of Europe to shifts in North Atlantic climate, developing the extant record of terrestrial glaciation and comparing these data to marine records is a critical step towards understanding the drivers of abrupt climate change.

Online estimation of wax deposition thickness in single-phase sub-sea pipelines based on acoustic chemometrics: A feasibility study

OpenAIRE

Halstensen, Maths; Arvoh, Benjamin Kaku; Amundsen, Lene; Hoffmann, Rainer

2012-01-01

Wax deposition in sub-sea oil producing pipelines is a concern to the oil producing companies. The deposition of wax in pipelines can cause serious economic implications if not monitored and controlled. Several researchers have developed models and investigated the deposition of wax in crude oil pipelines. As of today, there is no off the shelf instrument available for reliable online estimation of the wax depo- sition thickness in sub-sea pipelines. Acoustic chemometrics was applied to inves...

The Downstream Fate of Glacial Runoff and Groundwater in the Cordillera Blanca, Peru

Science.gov (United States)

McKenzie, J. M.; Gordon, R.; Chavez, D.; Maharaj, L.; Baraer, M.; Mark, B. G.; Lautz, L. K.

2013-12-01

Rapid glacier recession in the Cordillera Blanca, Peru, is raising concerns about current and future water resources for the inhabitants of the Rio Santa watershed. Glacier meltwater buffers stream discharge throughout the range, reducing the variability of annual runoff and maintaining stream flows during the dry season. Groundwater is also an important component of dry season runoff as it can contribute as much as 50-70% to outflow in some Rio Santa tributaries. A better understanding of groundwater dynamics in high elevation watersheds is needed, including quantification of recharge, subsurface processes, and available storage. We present the results from recent groundwater studies in the Cordillera Blanca where numerous investigative techniques have been used, including ground penetrating radar, hydraulic conductivity measurements, tracer tests, and hydrochemical mixing models. Our research focuses primarily on the low-relief pampa valley floors across which glacial-melt derived rivers flow. Across the Cordillera, these valley systems cover approximately 65 km2 and are comprised of unconsolidated glacial, talus, and lacustrine deposits and wetlands. The valleys commonly have buried, permeable, talus aquifers that are overlain by relatively impermeable, glaciolacustrine deposits. Glaciofluvial outwash deposits also act as aquifers (hydraulic conductivity of 10-4 m/s). The travel time of water stored in these systems is generally less than 3-4 years and the maximum observed dry season groundwater velocity is 60 cm/day. While groundwater represents an important component of dry season water resources source of water in the Cordillera Blanca, it is also potentially vulnerable to climate change including changes in the precipitation regime and decrease in glacially derived recharge.

Enhancement in (BHmax of PLD-made isotropic Nd-Fe-B thick film magnets deposited on Si substrates

Directory of Open Access Journals (Sweden)

M. Nakano

2017-05-01

Full Text Available Increase in Nd contents of a PLD-made isotropic Nd-Fe-B thick-film magnet enabled us to enhance the thickness of the film magnet deposited on a Si substrate because the linear expansion coefficient of Nd is an intermediate value between Nd2Fe14B and Si. The large amount of Nd, however, degraded the residual magnetic polarization and (BHmax. In the study, we reduced the Nd contents of each Nd-Fe-B film by inserting a Nd or a Nd-rich Nd-Fe-B buffer layer between a Nd-Fe-B film and a Si substrate in order to suppress the mechanical destruction together with the improvement in magnetic properties. It was found that the mechanical property of a Nd-Fe-B film comprising the Nd-Fe-B buffer layer in the thickness range from 10 to 60 μm was superior than that of a sample with the Nd buffer layer. Resultantly, an average (BHmax value of Nd-Fe-B films with each Nd-Fe-B buffer layer deposited on Si substrates could be enhanced by approximately 15 kJ/m3 compared to that of non-buffer-layered films.

Effect of precursor concentration and film thickness deposited by layer on nanostructured TiO2 thin films

Science.gov (United States)

Affendi, I. H. H.; Sarah, M. S. P.; Alrokayan, Salman A. H.; Khan, Haseeb A.; Rusop, M.

2018-05-01

Sol-gel spin coating method is used in the production of nanostructured TiO2 thin film. The surface topology and morphology was observed using the Atomic Force Microscopy (AFM) and Field Emission Scanning Electron Microscopy (FESEM). The electrical properties were investigated by using two probe current-voltage (I-V) measurements to study the electrical resistivity behavior, hence the conductivity of the thin film. The solution concentration will be varied from 14.0 to 0.01wt% with 0.02wt% interval where the last concentration of 0.02 to 0.01wt% have 0.01wt% interval to find which concentrations have the highest conductivity then the optimized concentration's sample were chosen for the thickness parameter based on layer by layer deposition from 1 to 6 layer. Based on the result, the lowest concentration of TiO2, the surface becomes more uniform and the conductivity will increase. As the result, sample of 0.01wt% concentration have conductivity value of 1.77E-10 S/m and will be advanced in thickness parameter. Whereas in thickness parameter, the 3layer deposition were chosen as its conductivity is the highest at 3.9098E9 S/m.

The effects of two thick film deposition methods on tin dioxide gas sensor performance.

Science.gov (United States)

Bakrania, Smitesh D; Wooldridge, Margaret S

2009-01-01

This work demonstrates the variability in performance between SnO(2) thick film gas sensors prepared using two types of film deposition methods. SnO(2) powders were deposited on sensor platforms with and without the use of binders. Three commonly utilized binder recipes were investigated, and a new binder-less deposition procedure was developed and characterized. The binder recipes yielded sensors with poor film uniformity and poor structural integrity, compared to the binder-less deposition method. Sensor performance at a fixed operating temperature of 330 °C for the different film deposition methods was evaluated by exposure to 500 ppm of the target gas carbon monoxide. A consequence of the poor film structure, large variability and poor signal properties were observed with the sensors fabricated using binders. Specifically, the sensors created using the binder recipes yielded sensor responses that varied widely (e.g., S = 5 - 20), often with hysteresis in the sensor signal. Repeatable and high quality performance was observed for the sensors prepared using the binder-less dispersion-drop method with good sensor response upon exposure to 500 ppm CO (S = 4.0) at an operating temperature of 330 °C, low standard deviation to the sensor response (±0.35) and no signal hysteresis.

The Effects of Two Thick Film Deposition Methods on Tin Dioxide Gas Sensor Performance

Directory of Open Access Journals (Sweden)

Smitesh D. Bakrania

2009-08-01

Full Text Available This work demonstrates the variability in performance between SnO2 thick film gas sensors prepared using two types of film deposition methods. SnO2 powders were deposited on sensor platforms with and without the use of binders. Three commonly utilized binder recipes were investigated, and a new binder-less deposition procedure was developed and characterized. The binder recipes yielded sensors with poor film uniformity and poor structural integrity, compared to the binder-less deposition method. Sensor performance at a fixed operating temperature of 330 ºC for the different film deposition methods was evaluated by exposure to 500 ppm of the target gas carbon monoxide. A consequence of the poor film structure, large variability and poor signal properties were observed with the sensors fabricated using binders. Specifically, the sensors created using the binder recipes yielded sensor responses that varied widely (e.g., S = 5 – 20, often with hysteresis in the sensor signal. Repeatable and high quality performance was observed for the sensors prepared using the binder-less dispersion-drop method with good sensor response upon exposure to 500 ppm CO (S = 4.0 at an operating temperature of 330 ºC, low standard deviation to the sensor response (±0.35 and no signal hysteresis.

Pb(Zr,Ti)O3-Pb(Mn1/3Nb2/3)O3 piezoelectric thick films by aerosol deposition

International Nuclear Information System (INIS)

Ryu, Jungho; Choi, Jong-Jin; Hahn, Byung-Dong; Yoon, Woon-Ha; Lee, Byoung-Kuk; Choi, Joon Hwan; Park, Dong-Soo

2010-01-01

Piezoelectric thick films of Pb(Zr,Ti)O 3 -Pb(Mn 1/3 Nb 2/3 )O 3 (PZT-PMnN) with Zr:Ti ratios ranging from 0.45:0.55 to 0.60:0.40 were fabricated on a platinized silicon wafer by aerosol deposition (AD). All the films were deposited with a thickness of 10 μm with high density. By adding PMnN to 57:43 PZT, a dielectric constant as low as ∼660 was achieved while the effective piezoelectric constant was over 140 pC/N. PZT-PMnN with a Zr:Ti ratio of 57:43 thus showed a maximum piezoelectric voltage constant (g 33 ) of 23.8 x 10 -3 Vm/N and is a good candidate for high quality thick films for application to high-energy density or high sensitivity, piezoelectric energy harvesters and sensors.

Origin and depositional environment of clastic deposits in the Hilo drill hole, Hawaii

Science.gov (United States)

Beeson, M.H.; Clague, D.A.; Lockwood, J.P.

1996-01-01

Volcaniclastic units cored at depths of about 87, 164, 178, 226, and 246 m below sea level and carbonate units located between depths of 27 and 53 m below sea level in the Hilo drill core were found to be deposited at or near sea level. Four of these units are hydroclastic deposits, formed when subaerially erupted Mauna Loa lava flows entered the ocean and fragmented to produce quenched, glassy fragments during hydrovolcanic explosions. Ash units 24 and 26, at 178 m depth, accumulated at sea level in a freshwater bog. They contain pyroxenes crystallized from tholeiitic magma that we infer erupted explosively at the summit of Kilauea volcano. Two carbon-rich layers from these ashes have a weighted average radiocarbon age of 38.6 ?? 0.9 ka; the ashes probably correlate with the oldest and thickest part of the Pahala ash. Ash unit 44, at the transition from Mauna Kea to Mauna Loa lava flows, was probably nearly 3.2 m thick and is inferred to be equivalent to the lower thick part of the composite Homelani ash mapped in Hilo and on the flanks of Mauna Kea. The age of this part of Homelani ash is between 128 ?? 33 and 200 ?? 10 ka; it may have erupted subglacially during the Pohakuloa glacial maxima on Mauna Kea. Beach sand units 12 and 22 were derived from nearby Mauna Loa and Mauna Kea lava flows. The middle of beach sand unit 38 was derived mainly from lava erupted near the distal end of the subaerial east rift zone of Kilauea volcano; these sands were transported about 33 km northwest to Hilo Bay by prevailing longshore currents. Combined age, depth, and sea level markers in the core allow us to determine that lava flow recurrence intervals averaged one flow every 4 kyr during the past 86 kyr and one flow every 16 kyr between 86 and 200 ka at the drill site and that major explosive eruptions that deposit thick ash in Hilo have occurred only twice in the last 400 kyr. These recurrence intervals support the moderate lava flow hazard zonation (zone 3) for coastal Hilo

Ice thickness profile surveying with ground penetrating radar at Artesonraju Glacier, Peru

Science.gov (United States)

Chisolm, Rachel; Rabatel, Antoine; McKinney, Daene; Condom, Thomas; Cochacin, Alejo; Davila Roller, Luzmilla

2014-05-01

Tropical glaciers are an essential component of the water resource systems in the mountainous regions where they are located, and a warming climate has resulted in the accelerated retreat of Andean glaciers in recent decades. The shrinkage of Andean glaciers influences the flood risk for communities living downstream as new glacial lakes have begun to form at the termini of some glaciers. As these lakes continue to grow in area and volume, they pose an increasing risk of glacial lake outburst floods (GLOFs). Ice thickness measurements have been a key missing link in studying the tropical glaciers in Peru and how climate change is likely to impact glacial melt and the growth of glacial lakes. Ground penetrating radar (GPR) has rarely been applied to glaciers in Peru to measure ice thickness, and these measurements can tell us a lot about how a warming climate will affect glaciers in terms of thickness changes. In the upper Paron Valley (Cordillera Blanca, Peru), an emerging lake has begun to form at the terminus of the Artesonraju Glacier, and this lake has key features, including overhanging ice and loose rock likely to create slides, that could trigger a catastrophic GLOF if the lake continues to grow. Because the glacier mass balance and lake mass balance are closely linked, ice thickness measurements and measurements of the bed slope of the Artesonraju Glacier and underlying bedrock can give us an idea of how the lake is likely to evolve in the coming decades. This study presents GPR data taken in July 2013 at the Artesonraju Glacier as part of a collaboration between the Unidad de Glaciologia y Recursos Hidricos (UGRH) of Peru, the Institut de Recherche pour le Développement (IRD) of France and the University of Texas at Austin (UT) of the United States of America. Two different GPR units belonging to UGRH and UT were used for subsurface imaging to create ice thickness profiles and to characterize the total volume of ice in the glacier. A common midpoint

A stable-isotope tree-ring timescale of the Late Glacial/Holocene boundary

International Nuclear Information System (INIS)

Becker, Bernd; Kromer, Bernd; Trimborn, Peter

1991-01-01

Late Glacial and Holocene tree-ring chronologies, like deep-sea sediments or polar ice cores, contain information about past environments. Changes in tree-ring growth rates can be related to past climate anomalies and changes in the isotope composition of tree-ring cellulose reflect changes in the composition of the atmosphere and the hydrosphere. We have established a 9,928-year absolutely dated dendrochronological record of Holocene oak (Quercus robur, Quercus petraea)-and a 1,604-year floating Late Glacial and Early Holocene chronology of pine (Pinus sylvestris) from subfossil tree remnants deposited in alluvial terraces of south central European rivers. The pine sequence provides records of dendro-dated 14 C, 13 C and 2 H patterns for the late Younger Dryas and the entire Preboreal (10,100-9,000 yr BP). Through the use of dendrochronology, radiocarbon age calibration and stable isotope analysis, we suggest that the Late Glacial/Holocene transition may be identified and dated by 13 C and 2 H tree-ring chronologies. (author)

The effect of sediment loading in Fennoscandia and the Barents Sea during the last glacial cycle on glacial isostatic adjustment observations

Directory of Open Access Journals (Sweden)

W. van der Wal

2017-09-01

Full Text Available Models for glacial isostatic adjustment (GIA routinely include the effects of meltwater redistribution and changes in topography and coastlines. Since the sediment transport related to the dynamics of ice sheets may be comparable to that of sea level rise in terms of surface pressure, the loading effect of sediment deposition could cause measurable ongoing viscous readjustment. Here, we study the loading effect of glacially induced sediment redistribution (GISR related to the Weichselian ice sheet in Fennoscandia and the Barents Sea. The surface loading effect and its effect on the gravitational potential is modeled by including changes in sediment thickness in the sea level equation following the method of Dalca et al. (2013. Sediment displacement estimates are estimated in two different ways: (i from a compilation of studies on local features (trough mouth fans, large-scale failures, and basin flux and (ii from output of a coupled ice–sediment model. To account for uncertainty in Earth's rheology, three viscosity profiles are used. It is found that sediment transport can lead to changes in relative sea level of up to 2 m in the last 6000 years and larger effects occurring earlier in the deglaciation. This magnitude is below the error level of most of the relative sea level data because those data are sparse and errors increase with length of time before present. The effect on present-day uplift rates reaches a few tenths of millimeters per year in large parts of Norway and Sweden, which is around the measurement error of long-term GNSS (global navigation satellite system monitoring networks. The maximum effect on present-day gravity rates as measured by the GRACE (Gravity Recovery and Climate Experiment satellite mission is up to tenths of microgal per year, which is larger than the measurement error but below other error sources. Since GISR causes systematic uplift in most of mainland Scandinavia, including GISR in GIA models

Ground-water hydrology and glacial geology of the Kalamazoo area, Michigan

Science.gov (United States)

Deutsch, Morris; Vanlier, K.E.; Giroux, P.R.

1960-01-01

The Kalamazoo report area includes about 150 square miles of Kalamazoo County, Mich. The area is principally one of industry and commerce, although agriculture also is of considerable importance. It has a moderate and humid climate and lies within the Lake Michigan “snow belt”. Precipitation averages about 35 inches per year. Snowfall averages about 55 inches. The surface features of the area were formed during and since the glacial epoch and are classified as outwash plain, morainal highlands, and glaciated channels or drainageways. The area is formed largely on the remnants of an extensive outwash plain, which is breached by the Kalamazoo River in the northeastern part and is dissected elsewhere by several small tributaries to the river. Most of the land drained by these tributaries lies within the report area. A small portion of the southern part drains to the St. Joseph River. The Coldwater shale, which underlies the glacial deposits throughout the area, and the deeper bedrock formations are not tapped for water by wells and they have little or no potential for future development. Deposits of glacial drift, which are the source of water to all the wells in the area, have considerable potential for future development. These deposits range in thickness from about 40 feet along the Kalamazoo River to 350 feet where valleys were eroded in the bedrock surface. Permeable outwash and channel deposits are the sources of water for wells of large capacity. The moraines are formed dominantly by till of lower permeability which generally yields small supplies of water, but included sand and gravel beds of higher permeability yield larger supplies locally. The aquifers of the Kalamazoo area are recharged by infiltration of rainfall and snowmelt and by infiltration of surface waters induced by pumping of wells near the surface sources. Water pumped from most of the municipal well fields is replenished in part by such induced infiltration. Many of the industrial wells

A {approx}180,000 years sedimentation history of a perialpine overdeepened glacial trough (Wehntal, N-Switzerland)

Energy Technology Data Exchange (ETDEWEB)

Anselmetti, F. S. [Eawag, Swiss Federal Institute of Aquatic Science and Technology, Duebendorf (Switzerland); Drescher-Schneider, R. [Institut fuer Pflanzenwissenschaften, Karl-Fanzen-Universitaet Graz, Graz (Austria); Furrer, H. [Palaeontologisches Institut und Museum, Universitaet Zuerich, Zuerich (Switzerland); Graf, H. R. [Matousek, Baumann und Niggli AG, Baden (Switzerland); Lowick, S. E.; Preusser, F. [Institut fuer Geologie, Universitaet Bern, Bern (Switzerland); Riedi, M. A. [Marc A. Riedi, Susenbuehlstrasse 41, Chur (Switzerland)

2010-11-15

A 30 m-deep drill core from a glacially overdeepened trough in Northern Switzerland recovered a {approx} 180 ka old sedimentary succession that provides new insights into the timing and nature of erosion-sedimentation processes in the Swiss lowlands. The luminescence-dated stratigraphic succession starts at the bottom of the core with laminated carbonate-rich lake sediments reflecting deposition in a proglacial lake between {approx} 180 and 130 ka ago (Marine Isotope Stage MIS 6). Anomalies in geotechnical properties and the occurrence of deformation structures suggest temporary ice contact around 140 ka. Up-core, organic content increases in the lake deposits indicating a warming of climate. These sediments are overlain by a peat deposit characterised by pollen assemblages typical of the late Eemian (MIS 5e). An abrupt transition following this interglacial encompasses a likely hiatus and probably marks a sudden lowering of the water level. The peat unit is overlain by deposits of a cold unproductive lake dated to late MIS 5 and MIS 4, which do not show any direct influence from glaciers. An upper peat unit, the so-called {sup M}ammoth peat{sup ,} previously encountered in construction pits, interrupts this cold lacustrine phase and marks more temperate climatic conditions between 60 and 45 ka (MIS 3). In the upper part of the core, a succession of fluvial and alluvial deposits documents the Late Glacial and Holocene sedimentation in the basin. The sedimentary succession at Wehntal confirms that the glaciation during MIS 6 did not apparently cause the overdeepening of the valley, as the lacustrine basin fill covering most of MIS 6 is still preserved. Consequently, erosion of the basin is most likely linked to an older glaciation. This study shows that new dating techniques combined with paleoenvironmental interpretations of sediments from such overdeepened troughs provide valuable insights into the past glacial history. (authors)

A ∼180,000 years sedimentation history of a perialpine overdeepened glacial trough (Wehntal, N-Switzerland)

International Nuclear Information System (INIS)

Anselmetti, F. S.; Drescher-Schneider, R.; Furrer, H.; Graf, H. R.; Lowick, S. E.; Preusser, F.; Riedi, M. A.

2010-01-01

A 30 m-deep drill core from a glacially overdeepened trough in Northern Switzerland recovered a ∼ 180 ka old sedimentary succession that provides new insights into the timing and nature of erosion-sedimentation processes in the Swiss lowlands. The luminescence-dated stratigraphic succession starts at the bottom of the core with laminated carbonate-rich lake sediments reflecting deposition in a proglacial lake between ∼ 180 and 130 ka ago (Marine Isotope Stage MIS 6). Anomalies in geotechnical properties and the occurrence of deformation structures suggest temporary ice contact around 140 ka. Up-core, organic content increases in the lake deposits indicating a warming of climate. These sediments are overlain by a peat deposit characterised by pollen assemblages typical of the late Eemian (MIS 5e). An abrupt transition following this interglacial encompasses a likely hiatus and probably marks a sudden lowering of the water level. The peat unit is overlain by deposits of a cold unproductive lake dated to late MIS 5 and MIS 4, which do not show any direct influence from glaciers. An upper peat unit, the so-called M ammoth peat , previously encountered in construction pits, interrupts this cold lacustrine phase and marks more temperate climatic conditions between 60 and 45 ka (MIS 3). In the upper part of the core, a succession of fluvial and alluvial deposits documents the Late Glacial and Holocene sedimentation in the basin. The sedimentary succession at Wehntal confirms that the glaciation during MIS 6 did not apparently cause the overdeepening of the valley, as the lacustrine basin fill covering most of MIS 6 is still preserved. Consequently, erosion of the basin is most likely linked to an older glaciation. This study shows that new dating techniques combined with paleoenvironmental interpretations of sediments from such overdeepened troughs provide valuable insights into the past glacial history. (authors)

Tensile test of a silicon microstructure fully coated with submicrometer-thick diamond like carbon film using plasma enhanced chemical vapor deposition method

Science.gov (United States)

Zhang, Wenlei; Uesugi, Akio; Hirai, Yoshikazu; Tsuchiya, Toshiyuki; Tabata, Osamu

2017-06-01

This paper reports the tensile properties of single-crystal silicon (SCS) microstructures fully coated with sub-micrometer thick diamond like carbon (DLC) film using plasma enhanced chemical vapor deposition (PECVD). To minimize the deformations or damages caused by non-uniform coating of DLC, which has high compression residual stress, released SCS specimens with the dimensions of 120 µm long, 4 µm wide, and 5 µm thick were coated from the top and bottom side simultaneously. The thickness of DLC coating is around 150 nm and three different bias voltages were used for deposition. The tensile strength improved from 13.4 to 53.5% with the increasing of negative bias voltage. In addition, the deviation in strength also reduced significantly compared to bare SCS sample.

Influence of film thickness on structural, optical, and electrical properties of spray deposited antimony doped SnO{sub 2} thin films

Energy Technology Data Exchange (ETDEWEB)

Yadav, Abhijit A., E-mail: aay_physics@yahoo.co.in

2015-09-30

Transparent conducting antimony doped SnO{sub 2} thin films with varying thickness were deposited by chemical spray pyrolysis technique from non-aqueous solvent Propan-2-ol. The effect of film thickness on the properties of antimony doped SnO{sub 2} thin films have been studied. X-ray diffraction measurements showed tetragonal crystal structure of as-deposited antimony doped SnO{sub 2} films irrespective of film thickness. The surface morphology of antimony doped SnO{sub 2} thin film is spherical with the continuous distribution of grains. Electrical and optical properties were investigated by Hall Effect and optical measurements. The average optical transmittance of films decreased from 89% to 73% within the visible range (350–850 nm) with increase in film thickness. The minimum value of sheet resistance observed is 4.81 Ω/cm{sup 2}. The lowest resistivity found is 3.76 × 10{sup −4} Ω cm at 660 nm film thickness. - Highlights: • Effect of film thickness on the properties of antimony doped SnO{sub 2} thin films • Crystalline size in the range of 34–37 nm • Average transmittance decreased from 89% to 73% in the visible region. • Minimum sheet resistance of 4.81 Ω/cm{sup 2} • Lowest resistivity is found to be 3.76 × 10{sup −4} Ω cm at 660 nm film thickness.

Deposition of SrTiO3 films by electrophoresis with thickness and particle size control

International Nuclear Information System (INIS)

Junior, W.D.M.; Pena, A.F.V.; Souza, A.E.; Santos, G.T.A.; Teixeira, S.R.; Senos, A.M.R.; Longo, E.

2012-01-01

The SrTiO3 (ST) is a material that exhibits semiconducting characteristics and interesting electrical properties. In room temperature has a structure of high cubic symmetry. The size of the crystallites of this material directly influences this symmetry, changing its network parameters. ST nanoparticles are obtained by hydrothermal method assisted by microwave (MAH). ST films are prepared by electrophoretic deposition (EPD). Approximately 1 g of the powder is dissolved in 100 ml of acetone and 1.5 ml of triethanolamine. The stainless steel substrates are arranged horizontally in the solution. The depositions are performed for 1-10 min and subjected to a potential difference of 20-100 V. The films were characterized by x-ray diffraction (XRD) and atomic force microscopy (AFM). The characterizations show that it is possible to control both the thickness and size of the crystallites of the film depending on the deposition parameters adopted. (author)

Robotic complex for the development of thick steeply-inclined coal seams and ore deposits

Science.gov (United States)

Nikitenko, M. S.; Malakhov, Yu V.; Neogi, Biswarup; Chakraborty, Pritam; Banerjee, Dipesu

2017-09-01

Proposal for the formulation of robotic complexes for steeply inclined coal seams as a basis of the supportive-enclosing walking module and power support with a controlled outlet for mining industry has been represented in this literature. In mining industry, the available resource base reserves and mineral deposits are concentrated deep down the earth crust leading towards a complicated geological condition i.e. abrupt ore bedding and steeply inclined strata with the high gas content and fire hazard of thick coal stratum, heading against an unfavorable and sometimes human labor life risk during subversive mining. Prevailing towards the development of effective robotic complexes based on the means of “unmanned technologies” for extraction of minerals from hard-to-reach deposits and make sure the safety of underground staff during sublevel mining technology.

TiN films by Atomic Layer Deposition: Growth and electrical characterization down to sub-nm thickness

NARCIS (Netherlands)

Van Hao, B.; Wolters, Robertus A.M.; Kovalgin, Alexeij Y.

2012-01-01

This study reports on the growth and characterization of TiN thib films obtained by atomic layer deposition at 350-425 ◦C. We observe a growth of the continuous layers from the very beginning of the process, i.e. for a thickness of 0.65 nm, which is equivalent to 3 monolayers of TiN. The film growth

Lower Silurian `hot shales' in North Africa and Arabia: regional distribution and depositional model

Science.gov (United States)

Lüning, S.; Craig, J.; Loydell, D. K.; Štorch, P.; Fitches, B.

2000-03-01

Lowermost Silurian organic-rich (`hot') shales are the origin of 80-90% of Palaeozoic sourced hydrocarbons in North Africa and also played a major role in petroleum generation on the Arabian Peninsula. In most cases, the shales were deposited directly above upper Ordovician (peri-) glacial sandstones during the initial early Silurian transgression that was a result of the melting of the late Ordovician icecap. Deposition of the main organic-rich shale unit in the North African/Arabian region was restricted to the earliest Silurian Rhuddanian stage ( acuminatus, atavus and probably early cyphus graptolite biozones). During this short period (1-2 m.y.), a favourable combination of factors existed which led to the development of exceptionally strong oxygen-deficiency in the area. In most countries of the study area, the post-Rhuddanian Silurian shales are organically lean and have not contributed to petroleum generation. The distribution and thickness of the basal Silurian `hot' shales have been mapped in detail for the whole North African region, using logs from some 300 exploration wells in Libya, Tunisia, Algeria and Morocco. In addition, all relevant, accessible published and unpublished surface and subsurface data of the lower Silurian shales in North Africa and Arabia have been reviewed, including sedimentological, biostratigraphic and organic geochemical data. The lowermost Silurian hot shales of northern Gondwana are laterally discontinuous and their distribution and thickness were controlled by the early Silurian palaeorelief which was shaped mainly by glacial processes of the late Ordovician ice age and by Pan-African and Infracambrian compressional and extensional tectonism. The thickest and areally most extensive basal Silurian organic-rich shales in North Africa occur in Algeria, Tunisia and western Libya, while on the Arabian Peninsula they are most prolific in Saudi Arabia, Oman, Jordan and Iraq. The hot shales were not deposited in Egypt, which was a

Optimization of the thickness of a conducting polymer, polyaniline, deposited on the surface of poly(vinyl chloride) membranes: a new way to improve their potentiometric response.

Science.gov (United States)

Shishkanova, T V; Matejka, P; Král, V; Sedenková, I; Trchová, M; Stejskal, J

2008-08-29

Repeated depositions of polyaniline (PANI) have been used to control the thickness of the polymeric film deposited on poly(vinyl chloride) (PVC) membrane surface. The oxidation of aniline was carried out in a dispersion mode, i.e. in the presence of poly(N-vinylpyrrolidone) (PVP). Two kinds of PVC were used for this purpose: a non-plasticized PVC for the study of PANI deposition and PVC, plasticized with nitrophenyl octyl ether (NPOE), as a prototype of a liquid membrane electrode. The results of UV-visible and FTIR spectroscopies and electron microscopy showed that (1) the film thickness increased by about equal increments of approximately 40 nm after each polymerization, and (2) the interface with PVC was constituted by PANI film and adhering PANI-PVP colloidal particles. The various thicknesses of the deposited PANI films affected the potentiometric response of the NPOE/PVC membrane with and without an anion-exchanger. The potentiometric anionic response was observed with a minimal thickness of PANI film on the blank NPOE/PVC membrane. Sensitivity of the PANI film to pH occurred only with a blank NPOE/PVC membrane coated with a thick polymeric film, while it was strongly suppressed by the presence of a lipophilic anion-exchanger, tridodecylmethylammonium chloride (TDDMACl), in the membrane, regardless of the thickness of the polymer film. The thickness of the PANI film did not affect the anionic selectivity pattern of TDDMACl-based membranes to any great extent, but its presence improved and stabilized their potentiometric characteristics (sensitivity, linear-response range).

Growth of thick La{sub 2}Zr{sub 2}O{sub 7} buffer layers for coated conductors by polymer-assisted chemical solution deposition

Energy Technology Data Exchange (ETDEWEB)

Zhang, Xin, E-mail: xzhang@my.swjtu.edu.cn [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity and New Energy Center (SNEC), Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); School of Electrical Engineering, Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Zhao, Yong, E-mail: yzhao@swjtu.edu.cn [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity and New Energy Center (SNEC), Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); School of Materials Science and Engineering, University of New South Wales, Sydney, 2052 NSW (Australia); Xia, Yudong [State Key Lab of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China); Guo, Chunsheng [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity and New Energy Center (SNEC), Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Cheng, C.H. [School of Materials Science and Engineering, University of New South Wales, Sydney, 2052 NSW (Australia); Zhang, Yong [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity and New Energy Center (SNEC), Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Zhang, Han [Department of Physics, Peking University, Beijing 100871 (China)

2015-06-15

Highlights: • We develops a low-cost and high-efficient technology of fabricating LZO buffer layers. • Sufficient thickness LZO buffer layers have been obtained on NiW (2 0 0) alloy substrate. • Highly biaxially textured YBCO thin film has been deposited on LZO/NiW. - Abstract: La{sub 2}Zr{sub 2}O{sub 7} (LZO) epitaxial films have been deposited on LaAlO{sub 3} (LAO) (1 0 0) single-crystal surface and bi-axially textured NiW (2 0 0) alloy substrate by polymer-assisted chemical solution deposition, and afterwards studied with XRD, SEM and AFM approaches. Highly in-plane and out-of-plane oriented, dense, smooth, crack free and with a sufficient thickness (>240 nm) LZO buffer layers have been obtained on LAO (1 0 0) single-crystal surface; The films deposited on NiW (2 0 0) alloy substrate are also found with high degree in-plane and out-of-plane texturing, good density with pin-hole-free, micro-crack-free nature and a thickness of 300 nm. Highly epitaxial 500 nm thick YBa{sub 2}Cu{sub 3}O{sub 7−x} (YBCO) thin film exhibits the self-field critical current density (Jc) reached 1.3 MA/cm{sup 2} at 77 K .These results demonstrate the LZO epi-films obtained with current techniques have potential to be a buffer layer for REBCO coated conductors.

Differences in Bacterial Diversity and Communities Between Glacial Snow and Glacial Soil on the Chongce Ice Cap, West Kunlun Mountains.

Science.gov (United States)

Yang, Guang Li; Hou, Shu Gui; Le Baoge, Ri; Li, Zhi Guo; Xu, Hao; Liu, Ya Ping; Du, Wen Tao; Liu, Yong Qin

2016-11-04

A detailed understanding of microbial ecology in different supraglacial habitats is important due to the unprecedented speed of glacier retreat. Differences in bacterial diversity and community structure between glacial snow and glacial soil on the Chongce Ice Cap were assessed using 454 pyrosequencing. Based on rarefaction curves, Chao1, ACE, and Shannon indices, we found that bacterial diversity in glacial snow was lower than that in glacial soil. Principal coordinate analysis (PCoA) and heatmap analysis indicated that there were major differences in bacterial communities between glacial snow and glacial soil. Most bacteria were different between the two habitats; however, there were some common bacteria shared between glacial snow and glacial soil. Some rare or functional bacterial resources were also present in the Chongce Ice Cap. These findings provide a preliminary understanding of the shifts in bacterial diversity and communities from glacial snow to glacial soil after the melting and inflow of glacial snow into glacial soil.

Micromorphology of modern tills in southwestern Spitsbergen – insights into depositional and post-depositional processes

Directory of Open Access Journals (Sweden)

Skolasińska Katarzyna

2016-12-01

Full Text Available Textural properties and microstructures are commonly used properties in the analysis of Pleistocene and older glacial deposits. However, contemporary glacial deposits are seldom studied, particularly in the context of post-depositional changes. This paper presents the results of a micromorphological study of recently deposited tills in the marginal zones of Hansbreen and Torellbreen, glaciers in southwestern Spitsbergen. The main objectives of this study were to compare modern tills deposited in subglacial and supraglacial conditions, as well as tills that were freshly released from ice with those laid down several decades ago. The investigated tills are primarily composed of large clasts of metamorphic rocks and represent coarse-grained, matrix-supported diamictons. The tills reveal several characteristic features for ductile (e.g. turbate structures and brittle (e.g. lineations, microshears deformations, which have been considered to be indicative of subglacial conditions. In supraglacial tills, the same structures are common as in the subglacial deposits, which points to the preservation of the primary features, though the sediment was transferred up to the glacier surface due to basal ice layer deformation and redeposited as slumps, or to formation of similar structures due to short-distance sediment re-deposition by mass flows. This study revealed that it might not be possible to distinguish subglacial and supraglacial tills on the basis of micromorphology if the latter are derived from a subglacial position. The only noted difference was the presence of iron oxide cementation zones and carbonate dissolution features in supraglacial tills. These features were found in tills that were deposited at least a few years ago and are interpreted to be induced by early post-depositional processes involving porewater/sediment interactions.

Thick Fe2O3, Fe3O4 films prepared by the chemical solution deposition method

Czech Academy of Sciences Publication Activity Database

Buršík, Josef; Košovan, P.; Šubrt, Jan

2006-01-01

Roč. 39, č. 2 (2006), s. 85-94 ISSN 0928-0707 R&D Projects: GA ČR GA203/01/0408 Institutional research plan: CEZ:AV0Z40320502 Keywords : chemical solution deposition * thick films * alpha-Fe2O3 Subject RIV: CA - Inorganic Chemistry Impact factor: 1.009, year: 2006

Holocene depositional history of a large glaciated estuary, Penobscot Bay, Maine

Science.gov (United States)

Knebel, H.J.

1986-01-01

Data from seismic-reflection profiles, sidescan sonar images, and sediment samples reveal the Holocene depositional history of the large (1100 km2) glaciated Penobscot Bay estuary of coastal Maine. Previous work has shown that the late Wisconsinan ice sheet retreated from the three main passages of the bay between 12,700 and 13,500 years ago and was accompanied by a marine transgression during which ice and sea were in contact. Isostatic recovery of the crust caused the bay to emerge during the immediate postglacial period, and relative sea level fell to at least -40 m sometime between 9000 and 11,500 years ago. During lowered sea level, the ancestral Penobscot River flowed across the subaerially exposed head of the bay and debouched into Middle Passage. Organic-matter-rich mud from the river was deposited rapidly in remnant, glacially scoured depressions in the lower reaches of Middle and West Passages behind a shallow (???20 m water depth) bedrock sill across the bay mouth. East Passage was isolated from the rest of the bay system and received only small amounts of locally derived fine-grained sediments. During the Holocene transgression that accompanied the eustatic rise of sea level, the locus of sedimentation shifted to the head of the bay. Here, heterogeneous fluvial deposits filled the ancestral valley of the Penobscot River as base level rose, and the migrating surf zone created a gently dipping erosional unconformity, marked by a thin (energy conditions and the waning influence of the Penobscot River at the head of the bay. In contrast, relatively thick (up to 25 m) silty clays accumulated within a subbottom trough in the western half of the bay head. This deposit apparently developed late in the transgression after sea level had reached -20 m and after the westward transport of fine-grained sediments from the Penobscot River had been established. During and since the late Holocene transgression of sea level, waves and currents have eroded, reworked, and

Optimization of laser energy deposition for single-shot high aspect-ratio microstructuring of thick BK7 glass

Energy Technology Data Exchange (ETDEWEB)

Garzillo, Valerio; Grigutis, Robertas [Dipartimento di Scienza e Alta Tecnologia, University of Insubria, Via Valleggio 11, I-22100 Como (Italy); Jukna, Vytautas [Centre de Physique Theorique, CNRS, Ecole Polytechnique, Université Paris-Saclay, F-91128 Palaiseau (France); LOA, ENSTA-ParisTech, CNRS, Ecole Polytechnique, Université Paris Saclay, F-91762 Palaiseau (France); Couairon, Arnaud [Centre de Physique Theorique, CNRS, Ecole Polytechnique, Université Paris-Saclay, F-91128 Palaiseau (France); Di Trapani, Paolo [Dipartimento di Scienza e Alta Tecnologia, University of Insubria and CNISM UdR Como, Via Valleggio 11, I-22100 Como (Italy); Jedrkiewicz, Ottavia, E-mail: ottavia.jedrkiewicz@ifn.cnr.it [Istituto di Fotonica e Nanotecnologie, CNR and CNISM UdR Como, Via Valleggio 11, I-22100 Como (Italy)

2016-07-07

We investigate the generation of high aspect ratio microstructures across 0.7 mm thick glass by means of single shot Bessel beam laser direct writing. We study the effect on the photoinscription of the cone angle, as well as of the energy and duration of the ultrashort laser pulse. The aim of the study is to optimize the parameters for the writing of a regular microstructure due to index modification along the whole sample thickness. By using a spectrally resolved single pulse transmission diagnostics at the output surface of the glass, we correlate the single shot material modification with observations of the absorption in different portions of the retrieved spectra, and with the absence or presence of spectral modulation. Numerical simulations of the evolution of the Bessel pulse intensity and of the energy deposition inside the sample help us interpret the experimental results that suggest to use picosecond pulses for an efficient and more regular energy deposition. Picosecond pulses take advantage of nonlinear plasma absorption and avoid temporal dynamics effects which can compromise the stationarity of the Bessel beam propagation.

A continuous record of glacial-interglacial cycles spanning more than 500 kyr from Lake Junín, Perú

Science.gov (United States)

Rodbell, D. T.; Abbott, M. B.; McGee, D.; Chen, C. Y.; Stoner, J. S.; Hatfield, R. G.; Tapia, P. M.; Bush, M. B.; Weidhaas, N.; Woods, A.; Valero-Garces, B. L.; Lehmann, S. B.; Bustamante, M. G.; Larsen, D. J.

2017-12-01

Lake Junín (11.0°S, 76.2°W) is a shallow (zmax 12 m), intermontane, high-elevation (4080 masl) lake in the inner-tropics of the Southern Hemisphere that spans 300 km2. It is dammed by coalescing alluvial fans that are >250 ka that emanate from glacial valleys. Lake Junín has not been overrun by glacial ice in several hundred thousand years and is ideally located to receive glacigenic sediment. The Junín basin is underlain by carbonate rocks that have provided a source of Ca and HCO3 ions; precipitation of CaCO3 in the western margin of the lake during the present interglacial period has occurred at 1mm yr-1. An airgun seismic survey revealed a strong reflector at 105 meters depth, which marks the base of the lacustrine section. Drilling focused on three sites. Site 1, located near the depocenter and most distal to glacial sources, yielded a composite sediment thickness of 95m; Site 2, proximal to glacial outwash fans, yielded a composite thickness of 28 m; Site 3, located at an intermediate distance yielded a sediment thickness of 55m. The stratigraphy of Site 1 is marked by 8 glacial/interglacial cycles; the latter are characterized by low bulk density and magnetic susceptibility (MS) and high CaCO3. These units are intercalated with glacigenic sediment that has high density and MS, and low CaCO3. The age model for Site 1 is based on AMS radiocarbon dates on terrestrial macrofossils and dozens of U/Th ages on authigenic CaCO3. Strong and protracted interglacial periods appear to be associated with intervals of reduced variability of solar insolation in the Southern Hemisphere tropics. During these intervals there is strong covariation (r2>0.9) between the δ13C and δ18O of authigenic calcium carbonate, and δ18O values are relatively enriched (-12 to -2‰); examples include interglacial periods correlative with marine isotope stages (MIS) 1, 13, and 15. The magnitude of tropical glaciation appears to have been greater during glacial cycles prior to the LGM

New glacial evidences at the Talacasto paleofjord (Paganzo basin, W-Argentina) and its implications for the paleogeography of the Gondwana margin

Science.gov (United States)

Aquino, Carolina Danielski; Milana, Juan Pablo; Faccini, Ubiratan Ferrucio

2014-12-01

The Talacasto paleovalley is situated in the Central Precordillera of San Juan, Argentina, where upper Carboniferous-Permian rocks (Paganzo Group) rest on Devonian sandstones of the Punta Negra Formation. This outcrop is an excellent example of a glacial valley-fill sequence that records at least two high-frequency cycles of the advance and retreat of a glacier into the valley. The paleocurrent analysis shows transport predominantly to the south, indicating that at this site the ice flow differs from the other nearby paleovalleys. Evidence of the glacial origin of this valley can be seen in the glacial striae on the valley's sides, as well as the U-shape of the valley, indicated by very steep locally overhanging valley walls. Deglaciation is indicated by a set of retransported conglomerates deposited in a shallow-water environment followed by a transgressive succession, which suggests eustatic rise due to meltwater input to the paleofjord. The complete sedimentary succession records distinct stages in the evolution of the valley-fill, represented by seven stratigraphical units. These units are identified based on facies associations and their interpreted depositional setting. Units 1 to 5 show one cycle of deglaciation and unit 6 marks the beginning of a new cycle of glacier advance which is characterized by different types of glacial deposits. All units show evidence of glacial influence such as dropstones and striated clasts, which indicates that the glaciers were always present in the valley or in adjacent areas during sedimentation. The Talacasto paleofjord provides good evidence of the Late Paleozoic Gondwana glaciation in western Argentina and examples of sedimentary successions which have been interpreted as being deposited by a confined wet-based glacier in advance and retreat cycles, with eventual release of icebergs into the basin. The outcrop is also a key for reconstructing the local glacial paleogeography, and it suggests a new interpretation that is

The genesis of the Nissi peatland (northwestern Greece) as an example of peat and lignite deposit formation in Greece

Energy Technology Data Exchange (ETDEWEB)

Christianis, K. (University of Patras, Patras (Greece). Dept of Geology)

1994-07-01

The Nissi Fen is located in a 12 km[sup 2] intramontane basin in northwestern Greece. Since the last glacial, limnotelmatic and pure telmatic conditions, controlled mainly by karstic springs and partly by surface waters, favoured peat formation in the basin, resulting in the accumulation of a peat deposit up to 15 m thick. The present fen occupies a large area of almost 9 km[sup 2]. Flora cover comprises mainly Cyperaceae ([ital Cladium mariscus] and [ital Carex] species), while [ital Phragmites australis] extend along the banks of a river flowing through the basin, as well as around a lake in the southern part of the fen. These species also contributed to the peat formation. The Nissi peatland shows many genetic similarities to the Philippi peat deposit, Eastern Macedonia, and may be considered as a recent analogue to the lignite deposits in the basins of Ptolemais, Western Macedonia and Megalopolis, the Peloponnese. 36 refs., 5 figs.

Early and late Holocene glacial fluctuations and tephrostratigraphy, Cabin Lake, Alaska

Science.gov (United States)

Zander, Paul D.; Kaufman, Darrell S.; Kuehn, Stephen C.; Wallace, Kristi L.; Anderson, R. Scott

2013-01-01

Marked changes in sediment types deposited in Cabin Lake, near Cordova, Alaska, represent environmental shifts during the early and late Holocene, including fluctuations in the terminal position of Sheridan Glacier. Cabin Lake is situated to receive meltwater during periods when the outwash plain of the advancing Sheridan Glacier had aggraded. A brief early Holocene advance from 11.2 to 11.0 cal ka is represented by glacial rock flour near the base of the sediment core. Non-glacial lake conditions were restored for about 1000 years before the water level in Cabin Lake lowered and the core site became a fen. The fen indicates drier-than-present conditions leading up to the Holocene thermal maximum. An unconformity spanning 5400 years during the mid-Holocene is overlain by peat until 1110 CE when meltwater from Sheridan Glacier returned to the basin. Three intervals of an advanced Sheridan Glacier are recorded in the Cabin Lake sediments during the late Holocene: 1110–1180, 1260–1540 and 1610–1780 CE. The sedimentary sequence also contains the first five reported tephra deposits from the Copper River delta region, and their geochemical signatures suggest that the sources are the Cook Inlet volcanoes Redoubt, Augustine and Crater Peak, and possibly Mt Churchill in the Wrangell Volcanic field.

Enhanced Self-Biased Magnetoelectric Coupling in Laser-Annealed Pb(Zr,Ti)O3 Thick Film Deposited on Ni Foil.

Science.gov (United States)

Palneedi, Haribabu; Maurya, Deepam; Geng, Liwei D; Song, Hyun-Cheol; Hwang, Geon-Tae; Peddigari, Mahesh; Annapureddy, Venkateswarlu; Song, Kyung; Oh, Yoon Seok; Yang, Su-Chul; Wang, Yu U; Priya, Shashank; Ryu, Jungho

2018-04-04

Enhanced and self-biased magnetoelectric (ME) coupling is demonstrated in a laminate heterostructure comprising 4 μm-thick Pb(Zr,Ti)O 3 (PZT) film deposited on 50 μm-thick flexible nickel (Ni) foil. A unique fabrication approach, combining room temperature deposition of PZT film by granule spray in vacuum (GSV) process and localized thermal treatment of the film by laser radiation, is utilized. This approach addresses the challenges in integrating ceramic films on metal substrates, which is often limited by the interfacial chemical reactions occurring at high processing temperatures. Laser-induced crystallinity improvement in the PZT thick film led to enhanced dielectric, ferroelectric, and magnetoelectric properties of the PZT/Ni composite. A high self-biased ME response on the order of 3.15 V/cm·Oe was obtained from the laser-annealed PZT/Ni film heterostructure. This value corresponds to a ∼2000% increment from the ME response (0.16 V/cm·Oe) measured from the as-deposited PZT/Ni sample. This result is also one of the highest reported values among similar ME composite systems. The tunability of self-biased ME coupling in PZT/Ni composite has been found to be related to the demagnetization field in Ni, strain mismatch between PZT and Ni, and flexural moment of the laminate structure. The phase-field model provides quantitative insight into these factors and illustrates their contributions toward the observed self-biased ME response. The results present a viable pathway toward designing and integrating ME components for a new generation of miniaturized tunable electronic devices.

Evidence of a low-latitude glacial buzzsaw: Progressive hypsometry reveals height-limiting glacial erosion in tropical mountain belts

Science.gov (United States)

Cunningham, M.; Stark, C. P.; Kaplan, M. R.; Schaefer, J. M.; Winckler, G.

2017-12-01

It has been widely demonstrated that glacial erosion limits the height of mid-latitude mountain ranges—a phenomenon commonly referred to as the "glacial buzzsaw." The strength of the buzzsaw is thought to diminish, or die out completely, at lower latitudes, where glacial landscapes occupy only a small part of mountain belts affected by Pleistocene glaciation. Here we argue that glacial erosion has actually truncated the rise of many tropical orogens. To elicit signs of height-limiting glacial erosion in the tropics, we employ a new take on an old tool: we identify transient geomorphic features by tracking the evolution of (sub)catchment hypsometry with increasing elevation above base level, a method we term "progressive hypsometry." In several tropical mountain belts, including the Central Range of Taiwan, the Talamanca of Costa Rica, the Finisterres of Papua New Guinea, and the Rwenzoris of East Africa, progressive hypsometry reveals transient landscapes perched at various elevations, but the highest of these transient features are consistently glacial landscapes near the lower limit of late-Pleistocene glacial equilibrium line altitude (ELA) fluctuation. We attribute this pattern to an efficient glacial buzzsaw. In many cases, these glacial landscapes are undergoing contemporary destruction by headward propagating, fluvially-driven escarpments. We deduce that a duel between glacial buzzcutting and fluvially-driven scarp propagation has been ongoing throughout the Pleistocene in these places, and that the preservation potential of tropical glacial landscapes is low. To this end, we have identified possible remnants of glacial landscapes in the final stages of scarp consumption, and use 3He surface exposure age dating of boulders and bedrock surfaces in two of these landscapes to constrain major geomorphic activity to before the onset of the Last Glacial Maximum. Our work points to a profound climatic influence on the evolution of these warm, tectonically active

Reconstruction of Last Glacial to early Holocene monsoon variability from relict lake sediments of the Higher Central Himalaya, Uttrakhand, India

DEFF Research Database (Denmark)

Juyal, N.; Pant, R.K.; Basavaiah, N.

2009-01-01

.5 ka and after14.5–13 ka. The Last Glacial phase ended with the deposition of outwash gravel dated at 11 ka indicating glacial retreat and the onset of Holocene condition. Additionally, centennial scale fluctuations between 16.5 ka and 12.7 ka in the magnetic and geochemical data are seen. A close...... instability in higher northern latitudes. However, centennial scale abrupt changes are attributed to the result of albedo changes on the Himalaya and Tibetan plateau....

Reconstruction of North American drainage basins and river discharge since the Last Glacial Maximum

Directory of Open Access Journals (Sweden)

A. D. Wickert

2016-11-01

Full Text Available Over the last glacial cycle, ice sheets and the resultant glacial isostatic adjustment (GIA rearranged river systems. As these riverine threads that tied the ice sheets to the sea were stretched, severed, and restructured, they also shrank and swelled with the pulse of meltwater inputs and time-varying drainage basin areas, and sometimes delivered enough meltwater to the oceans in the right places to influence global climate. Here I present a general method to compute past river flow paths, drainage basin geometries, and river discharges, by combining models of past ice sheets, glacial isostatic adjustment, and climate. The result is a time series of synthetic paleohydrographs and drainage basin maps from the Last Glacial Maximum to present for nine major drainage basins – the Mississippi, Rio Grande, Colorado, Columbia, Mackenzie, Hudson Bay, Saint Lawrence, Hudson, and Susquehanna/Chesapeake Bay. These are based on five published reconstructions of the North American ice sheets. I compare these maps with drainage reconstructions and discharge histories based on a review of observational evidence, including river deposits and terraces, isotopic records, mineral provenance markers, glacial moraine histories, and evidence of ice stream and tunnel valley flow directions. The sharp boundaries of the reconstructed past drainage basins complement the flexurally smoothed GIA signal that is more often used to validate ice-sheet reconstructions, and provide a complementary framework to reduce nonuniqueness in model reconstructions of the North American ice-sheet complex.

Impact of increasing antarctic glacial freshwater release on regional sea-ice cover in the Southern Ocean

Science.gov (United States)

Merino, Nacho; Jourdain, Nicolas C.; Le Sommer, Julien; Goosse, Hugues; Mathiot, Pierre; Durand, Gael

2018-01-01

The sensitivity of Antarctic sea-ice to increasing glacial freshwater release into the Southern Ocean is studied in a series of 31-year ocean/sea-ice/iceberg model simulations. Glaciological estimates of ice-shelf melting and iceberg calving are used to better constrain the spatial distribution and magnitude of freshwater forcing around Antarctica. Two scenarios of glacial freshwater forcing have been designed to account for a decadal perturbation in glacial freshwater release to the Southern Ocean. For the first time, this perturbation explicitly takes into consideration the spatial distribution of changes in the volume of Antarctic ice shelves, which is found to be a key component of changes in freshwater release. In addition, glacial freshwater-induced changes in sea ice are compared to typical changes induced by the decadal evolution of atmospheric states. Our results show that, in general, the increase in glacial freshwater release increases Antarctic sea ice extent. But the response is opposite in some regions like the coastal Amundsen Sea, implying that distinct physical mechanisms are involved in the response. We also show that changes in freshwater forcing may induce large changes in sea-ice thickness, explaining about one half of the total change due to the combination of atmospheric and freshwater changes. The regional contrasts in our results suggest a need for improving the representation of freshwater sources and their evolution in climate models.

Comparison of stress in single and multiple layer depositions of plasma-deposited amorphous silicon dioxide

International Nuclear Information System (INIS)

Au, V; Charles, C; Boswell, R W

2006-01-01

The stress in a single-layer continuous deposition of amorphous silicon dioxide (SiO 2 ) film is compared with the stress within multiple-layer intermittent or 'stop-start' depositions. The films were deposited by helicon activated reactive evaporation (plasma assisted deposition with electron beam evaporation source) to a 1 μm total film thickness. The relationships for stress as a function of film thickness for single, two, four and eight layer depositions have been obtained by employing the substrate curvature technique on a post-deposition etch-back of the SiO 2 film. At film thicknesses of less than 300 nm, the stress-thickness relationships clearly show an increase in stress in the multiple-layer samples compared with the relationship for the single-layer film. By comparison, there is little variation in the film stress between the samples when it is measured at 1 μm film thickness. Localized variations in stress were not observed in the regions where the 'stop-start' depositions occurred. The experimental results are interpreted as a possible indication of the presence of unstable, strained Si-O-Si bonds in the amorphous SiO 2 film. It is proposed that the subsequent introduction of a 'stop-start' deposition process places additional strain on these bonds to affect the film structure. The experimental stress-thickness relationships were reproduced independently by assuming a linear relationship between the measured bow and film thickness. The constants of the linear model are interpreted as an indication of the density of the amorphous film structure

Late-Quaternary glacial to postglacial sedimentation in three adjacent fjord-lakes of the Québec North Shore (eastern Canadian Shield)

Science.gov (United States)

Poiré, Antoine G.; Lajeunesse, Patrick; Normandeau, Alexandre; Francus, Pierre; St-Onge, Guillaume; Nzekwe, Obinna P.

2018-04-01

High-resolution swath bathymetry imagery allowed mapping in great detail the sublacustrine geomorphology of lakes Pentecôte, Walker and Pasteur, three deep adjacent fjord-lakes of the Québec North Shore (eastern Canada). These sedimentary basins have been glacio-isostatically uplifted to form deep steep-sided elongated lakes. Their key geographical position and limnogeological characteristics typical of fjords suggest exceptional potential for long-term high-resolution paleoenvironmental reconstitutions. Acoustic subbottom profiles acquired using a bi-frequency Chirp echosounder (3.5 & 12 kHz), together with cm- and m-long sediment core data, reveal the presence of four acoustic stratigraphic units. The acoustic basement (Unit 1) represents the structural bedrock and/or the ice-contact sediments of the Laurentide Ice Sheet and reveals V-shaped bedrock valleys at the bottom of the lakes occupied by ice-loaded sediments in a basin-fill geometry (Unit 2). Moraines observed at the bottom of lakes and in their structural valleys indicate a deglaciation punctuated by short-term ice margin stabilizations. Following ice retreat and their isolation, the fjord-lakes were filled by a thick draping sequence of rhythmically laminated silts and clays (Unit 3) deposited during glaciomarine and/or glaciolacustrine settings. These sediments were episodically disturbed by mass-movements during deglaciation due to glacial-isostatic rebound. AMS 14C dating reveal that the transition between deglaciation of the lakes Pentecôte and Walker watersheds and the development of para- and post-glacial conditions occurred around 8000 cal BP. The development of the lake-head river delta plain during the Holocene provided a constant source of fluvial sediment supply to the lakes and the formation of turbidity current bedforms on the sublacustrine delta slopes. The upper sediment succession (i.e., ∼4-∼6.5 m) consists of a continuous para-to post-glacial sediment drape (Unit 4) that contains

Generalized hydrogeologic framework and groundwater budget for a groundwater availability study for the glacial aquifer system of the United States

Science.gov (United States)

Reeves, Howard W.; Bayless, E. Randall; Dudley, Robert W.; Feinstein, Daniel T.; Fienen, Michael N.; Hoard, Christopher J.; Hodgkins, Glenn A.; Qi, Sharon L.; Roth, Jason L.; Trost, Jared J.

2017-12-14

The glacial aquifer system groundwater availability study seeks to quantify (1) the status of groundwater resources in the glacial aquifer system, (2) how these resources have changed over time, and (3) likely system response to future changes in anthropogenic and environmental conditions. The glacial aquifer system extends from Maine to Alaska, although the focus of this report is the part of the system in the conterminous United States east of the Rocky Mountains. The glacial sand and gravel principal aquifer is the largest source of public and self-supplied industrial supply for any principal aquifer and also is an important source for irrigation supply. Despite its importance for water supply, water levels in the glacial aquifer system are generally stable varying with climate and only locally from pumping. The hydrogeologic framework developed for this study includes the information from waterwell records and classification of material types from surficial geologic maps into likely aquifers dominated by sand and gravel deposits. Generalized groundwater budgets across the study area highlight the variation in recharge and discharge primarily driven by climate.

Planar structured perovskite solar cells by hybrid physical chemical vapor deposition with optimized perovskite film thickness

Science.gov (United States)

Wei, Xiangyang; Peng, Yanke; Jing, Gaoshan; Cui, Tianhong

2018-05-01

The thickness of perovskite absorber layer is a critical parameter to determine a planar structured perovskite solar cell’s performance. By modifying the spin coating speed and PbI2/N,N-dimethylformamide (DMF) solution concentration, the thickness of perovskite absorber layer was optimized to obtain high-performance solar cells. Using a PbI2/DMF solution of 1.3 mol/L, maximum power conversion efficiency (PCE) of a perovskite solar cell is 15.5% with a perovskite film of 413 nm at 5000 rpm, and PCE of 14.3% was also obtained for a solar cell with a perovskite film of 182 nm thick. It is derived that higher concentration of PbI2/DMF will result in better perovskite solar cells. Additionally, these perovskite solar cells are highly uniform. In 14 sets of solar cells, standard deviations of 11 sets of solar cells were less than 0.50% and the smallest standard deviation was 0.25%, which demonstrates the reliability and effectiveness of hybrid physical chemical vapor deposition (HPCVD) method.

Film thickness determination by grazing incidence diffraction

Energy Technology Data Exchange (ETDEWEB)

Battiston, G A; Gerbasi, R [CNR, Padua (Italy). Istituto di Chimica e Tecnologie Inorganiche e dei Materiali Avanzati

1996-09-01

Thin films deposited via MOCVD (Metal Organic Chemical Vapour Deposition) are layers in the thickness range of a few manometers to about ten micrometers. An understanding of the physics and chemistry of films is necessary for a better comprehension of the phenomena involved in the film deposition procedure and its optimisation. Together with the crystalline phase a parameter that must be determined is the thickness of the layer. In this work the authors present a method for the measurement of the film thickness. This procedure, based on diffraction intensity absorption of the X-rays, both incident and diffracted in passing through the layers, resulted quite simple, rapid and non-destructive.

Film thickness determination by grazing incidence diffraction

International Nuclear Information System (INIS)

Battiston, G. A.; Gerbasi, R.

1996-01-01

Thin films deposited via MOCVD (Metal Organic Chemical Vapour Deposition) are layers in the thickness range of a few manometers to about ten micrometers. An understanding of the physics and chemistry of films is necessary for a better comprehension of the phenomena involved in the film deposition procedure and its optimisation. Together with the crystalline phase a parameter that must be determined is the thickness of the layer. In this work the authors present a method for the measurement of the film thickness. This procedure, based on diffraction intensity absorption of the X-rays, both incident and diffracted in passing through the layers, resulted quite simple, rapid and non-destructive

Regression Methods for Virtual Metrology of Layer Thickness in Chemical Vapor Deposition

DEFF Research Database (Denmark)

Purwins, Hendrik; Barak, Bernd; Nagi, Ahmed

2014-01-01

The quality of wafer production in semiconductor manufacturing cannot always be monitored by a costly physical measurement. Instead of measuring a quantity directly, it can be predicted by a regression method (Virtual Metrology). In this paper, a survey on regression methods is given to predict...... average Silicon Nitride cap layer thickness for the Plasma Enhanced Chemical Vapor Deposition (PECVD) dual-layer metal passivation stack process. Process and production equipment Fault Detection and Classification (FDC) data are used as predictor variables. Various variable sets are compared: one most...... algorithm, and Support Vector Regression (SVR). On a test set, SVR outperforms the other methods by a large margin, being more robust towards changes in the production conditions. The method performs better on high-dimensional multivariate input data than on the most predictive variables alone. Process...

Andean glacial lakes and climate variability since the last glacial maximum

Directory of Open Access Journals (Sweden)

1995-01-01

Full Text Available LES LACS GLACIAIRES ET LA VARIABILITÉ CLIMATIQUE DANS LES ANDES DEPUIS LE DERNIER MAXIMUM GLACIAIRE. Des carottages réalisés dans des lacs glaciaires des Andes tropicales et subtropicales ont fourni des registres paléoclimatiques continus couvrant le Dernier Maximum Glaciaire et l’Holocène. Des datations 14C sur sédiments lacustres et sur tourbes indiquent que le maximum de la dernière glaciation s’est produit antérieurement au Dernier Maximum Glaciaire Global (18 ka BP. La plupart des lacs ont un âge inférieur à 13 ka BP, ce qui signifie que l’avancée des glaciers correspondant au Pleistocène terminal aurait culminé aux alentours de 14 ka BP. Des avancées durant le Tardi-glaciaire sont enregistrées dans plusieurs sites lacustres. À partir de 10 ka BP, les glaciers ont reculé au-delà de leurs limites actuelles. La sécheresse de l’Holocène moyen est repérée dans la stratigraphie de nombre de lacs, y compris le lac Titicaca. Cette phase d’aridité est suivie par une remontée des niveaux lacustres et une réavancée des glaciers à la fin de l’Holocène. LAGOS GLACIARES ANDINOS Y VARIABILIDAD CLIMÁTICA DESDE EL ÚLTIMO MÁXIMO GLACIAL. Testigos de sedimentos de los lagos glaciares en los Andes tropicales/subtropicales proporcionan registros continuos de los paleoclimas del último glacial superior y del Holoceno. Dataciones del radiocarbón de los sedimentos profundos en los lagos y de las turberas indican que el máximo del último glacial fue antes del máximo glacial global con una fecha de 18 14C ka BP. La mayoría de los lagos tienen una antigüedad menor de 13 14C ka BP, lo que significa que hubo una fase de glaciación del Pleistoceno superior culminada alrededor de 14 14C ka BP. Los avances durante el glacial superior son indicados en varios testigos de sedimentos de los lagos y, después de 10 14C ka BP, los glaciares quedaron dentro de sus límites actuales. Una sequía durante el Holoceno medio est

Geology and hydrology for environmental planning in Washtenaw County, Michigan

Science.gov (United States)

Fleck, William B.

1980-01-01

Washteaw County is underlain by glacial deposits that range in thickness from about 50 feet to about 450 feet. Underlying the glacial deposits are sedimentary rocks of Mississippian and Devonian age. The youngest of these rocks are the sandstones of the Marshall Formation in the western part of the county;  the oldest are the limestones of the Detroit River Group in the southeast corner.Sand and gravel deposits in some places in the county may yield more than 500 gallons per minute of water. Approximately 50 percent of the wells tapping the Marshall Formation, the most reliable bedrock aquifer, can yield as much as 60 gallons per minute.Washtenaw County has sand and gravel deposits that are more than 50 feet thick. The deposits are mined in several areas and are of economic importance. In addition, there may be potential for peat production in the western part of the county and for clay production in the eastern part.

Effect of laser beam parameters on magnetic properties of Nd-Fe-B thick-film magnets fabricated by pulsed laser deposition

International Nuclear Information System (INIS)

Fukunaga, H.; Nakano, M.; Yanai, T.; Kamikawatoko, T.; Yamashita, F.

2011-01-01

The effects of varying the laser power and the spot diameter of a laser beam on the magnetic properties, morphology, and deposition rate of Nd-Fe-B thick-film magnets fabricated by pulsed laser deposition (PLD) were investigated. Reducing the laser fluence on the target reduces the remanence and increases the Nd content and consequently the coercivity of the prepared films. The spot size of the laser beam was found to affect the film surface morphology, the deposition rate, and the reproducibility of the magnetic properties of the prepared films. Reducing the spot size reduces the number of droplets and the reproducibility of the magnetic properties and increases the droplet size. Controlling the spot size of the laser beam enabled us to maximize the deposition rate. Consequently, a coercivity of 1210 kA/m and a remanence of 0.51 T were obtained at a deposition rate of 11.8 μm/(h·W). This deposition rate is 30% greater than the highest previously reported deposition rate by PLD.

Preservation of a Late Glacial terrestrial and Holocene estuarine record on the margins of Kaipara Harbour, Northland, New Zealand

International Nuclear Information System (INIS)

Nichol, S.; Deng, Y.; Horrocks, M.; Zhou, W.; Hume, T.

2009-01-01

Subtidal to intertidal deposits from the margins of Kaipara Harbour in Northland preserve a c. 23,000 year incomplete sedimentary record of the transition from terrestrial to estuarine conditions. Cores are used to reconstruct the depositional setting for this transition, interpreted as a succession from dune and freshwater wetland to shallow estuarine environments. The fossil pollen record provides a proxy of Last Glacial Maximum and Late Glacial vegetation for the area. Stability of the Pleistocene dune landscape during the postglacial marine transgression is interpreted on the basis of strong dominance of tall forest taxa (Dacrydium) in the pollen record and soil development in dune sands, with preservation aided by location along the estuary margin. During the Holocene, reworking of the buried dune and wetland sediments has only reached to a depth of 1.5 m below the modern tidal flat. As such, the site provides a rare example of good preservation of Pleistocene deposits at the coast, where extensive reworking and loss of record are more typical. (author). 41 refs., 6 figs., 1 tab

Relative timing of last glacial maximum and late-glacial events in the central tropical Andes

Science.gov (United States)

Bromley, Gordon R. M.; Schaefer, Joerg M.; Winckler, Gisela; Hall, Brenda L.; Todd, Claire E.; Rademaker, Kurt M.

2009-11-01

Whether or not tropical climate fluctuated in synchrony with global events during the Late Pleistocene is a key problem in climate research. However, the timing of past climate changes in the tropics remains controversial, with a number of recent studies reporting that tropical ice age climate is out of phase with global events. Here, we present geomorphic evidence and an in-situ cosmogenic 3He surface-exposure chronology from Nevado Coropuna, southern Peru, showing that glaciers underwent at least two significant advances during the Late Pleistocene prior to Holocene warming. Comparison of our glacial-geomorphic map at Nevado Coropuna to mid-latitude reconstructions yields a striking similarity between Last Glacial Maximum (LGM) and Late-Glacial sequences in tropical and temperate regions. Exposure ages constraining the maximum and end of the older advance at Nevado Coropuna range between 24.5 and 25.3 ka, and between 16.7 and 21.1 ka, respectively, depending on the cosmogenic production rate scaling model used. Similarly, the mean age of the younger event ranges from 10 to 13 ka. This implies that (1) the LGM and the onset of deglaciation in southern Peru occurred no earlier than at higher latitudes and (2) that a significant Late-Glacial event occurred, most likely prior to the Holocene, coherent with the glacial record from mid and high latitudes. The time elapsed between the end of the LGM and the Late-Glacial event at Nevado Coropuna is independent of scaling model and matches the period between the LGM termination and Late-Glacial reversal in classic mid-latitude records, suggesting that these events in both tropical and temperate regions were in phase.

Mid-latitude trans-Pacific reconstructions and comparisons of coupled glacial/interglacial climate cycles based on soil stratigraphy of cover-beds

Science.gov (United States)

Alloway, B. V.; Almond, P. C.; Moreno, P. I.; Sagredo, E.; Kaplan, M. R.; Kubik, P. W.; Tonkin, P. J.

2018-06-01

South Westland, New Zealand, and southern Chile, are two narrow continental corridors effectively confined between the Pacific Ocean in the west and high mountain ranges in the east which impart significant influence over regional climate, vegetation and soils. In both these southern mid-latitude regions, evidence for extensive and repeated glaciations during cold phases of the Quaternary is manifested by arrays of successively older glacial drift deposits with corresponding outwash plain remnants. In South Westland, these variably aged glacial landforms are mantled by layered (multisequal) soils characterised by slow loess accretion and pedogenesis in an extreme leaching and weathering environment. These cover-bed successions have undergone repeated coupled phases of topdown and upbuilding soil formation that have been related to fluctuating cycles of interglacial/warm and glacial/cold climate during the Quaternary. In this study, we recognise multisequal soils overlying glacial landforms in southern continental Chile but, unlike the spodic (podzolic) soil sequences of South Westland, these are of dominantly volcanigenic (andic) provenance and are very similar to multisequal soils of andic provenance that predominate in, and adjacent to, areas of rhyolitic to andesitic volcanism in North Island, New Zealand. Here we develop a soil-stratigraphic model to explain the observed occurrence of multisequal soils mantling dominantly glacial landforms of southern continental Chile. Based on proxy data from southern Chile, we propose that persistent vegetation cover and high precipitation on the western side of the Andes, during colder-than-present episodes tended to suppress the widespread production of glacially-derived loessial materials despite the pervasive occurrence of glacial and glacio-fluvial deposits that have frequently inundated large tracts of this landscape during the Quaternary. Given the lack of loess cover-beds that have traditionally assisted in the

Alaska Harbor Seal Glacial Surveys

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — Floating glacial ice serves as a haul-out substrate for a significant number (10-15%) of Alaskan harbor seals, and thus surveying tidewater glacial fjords is an...

Single and Double Infrared Transitions in Rapid Vapor Deposited Parahydrogen Solids: Application to Sample Thickness Determination and Quantitative Infrared Absorption Spectroscopy

National Research Council Canada - National Science Library

Tam, Simon

2001-01-01

...) solid from its infrared (IR) absorption spectrum. Millimeters-thick pH2 solids of exceptional optical clarity can be produced by the rapid vapor deposition method M.E. Fajardo and S. Tam, J. Chem. Phys. 108, 4237 (1998...

Controlled growth of carbon nanofibers using plasma enhanced chemical vapor deposition: Effect of catalyst thickness and gas ratio

International Nuclear Information System (INIS)

Saidin, M.A.R.; Ismail, A.F.; Sanip, S.M.; Goh, P.S.; Aziz, M.; Tanemura, M.

2012-01-01

The characteristics of carbon nanofibers (CNFs) grown, using direct current plasma enhanced chemical vapor deposition system reactor under various acetylene to ammonia gas ratios and different catalyst thicknesses were studied. Nickel/Chromium-glass (Ni/Cr-glass) thin film catalyst was employed for the growth of CNF. The grown CNFs were then characterized using Raman spectroscopy, field emission scanning electron microscopy and transmission electron microscopy (TEM). Raman spectroscopy showed that the Ni/Cr-glass with thickness of 15 nm and gas ratio acetylene to ammonia of 1:3 produced CNFs with the lowest I D /I G value (the relative intensity of D-band to G-band). This indicated that this catalyst thickness and gas ratio value is the optimum combination for the synthesis of CNFs under the conditions studied. TEM observation pointed out that the CNFs produced have 104 concentric walls and the residual catalyst particles were located inside the tubes of CNFs. It was also observed that structural morphology of the grown CNFs was influenced by acetylene to ammonia gas ratio and catalyst thickness.

Controlled growth of carbon nanofibers using plasma enhanced chemical vapor deposition: Effect of catalyst thickness and gas ratio

Energy Technology Data Exchange (ETDEWEB)

Saidin, M.A.R. [Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru (Malaysia); Ismail, A.F., E-mail: afauzi@utm.my [Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru (Malaysia); Sanip, S.M.; Goh, P.S.; Aziz, M. [Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru (Malaysia); Tanemura, M. [Department of Frontier Material, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan)

2012-01-31

The characteristics of carbon nanofibers (CNFs) grown, using direct current plasma enhanced chemical vapor deposition system reactor under various acetylene to ammonia gas ratios and different catalyst thicknesses were studied. Nickel/Chromium-glass (Ni/Cr-glass) thin film catalyst was employed for the growth of CNF. The grown CNFs were then characterized using Raman spectroscopy, field emission scanning electron microscopy and transmission electron microscopy (TEM). Raman spectroscopy showed that the Ni/Cr-glass with thickness of 15 nm and gas ratio acetylene to ammonia of 1:3 produced CNFs with the lowest I{sub D}/I{sub G} value (the relative intensity of D-band to G-band). This indicated that this catalyst thickness and gas ratio value is the optimum combination for the synthesis of CNFs under the conditions studied. TEM observation pointed out that the CNFs produced have 104 concentric walls and the residual catalyst particles were located inside the tubes of CNFs. It was also observed that structural morphology of the grown CNFs was influenced by acetylene to ammonia gas ratio and catalyst thickness.

Structural Properties Characterized by the Film Thickness and Annealing Temperature for La2O3 Films Grown by Atomic Layer Deposition.

Science.gov (United States)

Wang, Xing; Liu, Hongxia; Zhao, Lu; Fei, Chenxi; Feng, Xingyao; Chen, Shupeng; Wang, Yongte

2017-12-01

La 2 O 3 films were grown on Si substrates by atomic layer deposition technique with different thickness. Crystallization characteristics of the La 2 O 3 films were analyzed by grazing incidence X-ray diffraction after post-deposition rapid thermal annealing treatments at several annealing temperatures. It was found that the crystallization behaviors of the La 2 O 3 films are affected by the film thickness and annealing temperatures as a relationship with the diffusion of Si substrate. Compared with the amorphous La 2 O 3 films, the crystallized films were observed to be more unstable due to the hygroscopicity of La 2 O 3 . Besides, the impacts of crystallization characteristics on the bandgap and refractive index of the La 2 O 3 films were also investigated by X-ray photoelectron spectroscopy and spectroscopic ellipsometry, respectively.

Development and evaluation of a long-term deposit probe for on-line monitoring of deposit growth

Energy Technology Data Exchange (ETDEWEB)

Brink, Anders; Lauren, Tor; Yrjas, Patrik; Hupa, Mikko [Process Chemistry Centre, Aabo Akademi University, Biskopsgatan 8, FI-20540 Turku (Finland); Friesenbichler, Joachim [Institute for Resource Efficient and Sustainable Systems, Technical University Graz Inffeldg. 21b, A-8010 Graz (Austria)

2007-12-15

A newly designed air-cooled probe for on-line monitoring of deposition growth has been tested in a boiler firing three woody fuels. Thermocouples are mounted on both sides of the tube wall enabling measurements of the heat flux through the probe wall. Knowing the heat flux through the probe wall, it is possible to measure the additional heat transfer resistance caused by the deposit and to estimate the properties of the deposit. Calculating the deposit thickness using the collected temperature data indicated the thinnest deposit when wood was fired, followed by bark and waste wood. The calculated deposit thickness was larger than those found when analysing the deposit thickness after the probe had been removed. Nevertheless, the ranking of fuels by deposit build-up rate was the same. (author)

An Ensemble Analysis of Antarctic Glacial Isostatic Adjustment and Sea Level

Science.gov (United States)

Lecavalier, B.; Tarasov, L.

2016-12-01

Inferences of past ice sheet evolution that lack any uncertainty assessment (implicit or explicit), have little value. A developing technique for explicit uncertainty quantification of glacial systems is Bayesian calibration of models against large observational data-sets (Tarasov et al., 2012). The foundation for a Bayesian calibration of a 3D glacial systems model (GSM) for Antarctica has recently been completed (Briggs et al., 2013; 2014; Briggs and Tarasov, 2013). Bayesian calibration thoroughly samples model uncertainties against fits to observational data to generate a probability distribution for the Antarctic Ice Sheet deglaciation with explicit and well-defined confidence intervals. To have validity as a complete inference of past ice sheet evolution, Bayesian calibration requires a model that "brackets reality".Past work has shown the GSM to have likely inadequate range of grounding line migration in certain sectors as well as persistent ice thickness biases in topographically complex regions (Briggs et al., 2014). To advance towards full calibration, these deficiencies are being addressed through a number of model developments. The grounding line scheme has been revised (Pollard and DeConto, 2012), the horizontal resolution is increased to 20 km, and boundary conditions are updated. The basal drag representation now includes the sub-grid treatment of the thermo-mechanical impacts of high basal roughness. Parametric uncertainties in basal drag for regions that are presently marine have been re-evaluated. The impact of past changes in ocean temperature on sub ice shelf melt is explicitly incorporated in the current ocean forcing parametric scheme. Uncertainties in earth rheology are also probed to robustly quantify uncertainties affiliated with glacial isostatic adjustment. The ensemble analysis of the Antarctic glacial system provides dynamical bounds on past and present Antarctica glacial isostatic adjustment and sea level contributions. This research

Tracking Organic Carbon Transport From the Stordalen Mire to Glacial Lake Tornetrask, Abisko, Sweden

Science.gov (United States)

Beck, M. A.; Hamilton, B. T.; Spry, E.; Johnson, J. E.; Palace, M. W.; McCalley, C. K.; Varner, R. K.; Bothner, W. A.

2016-12-01

In subarctic regions, labile organic carbon from thawing permafrost and productivity of terrestrial and aquatic vegetation are sources of carbon to lake sediments. Methane is produced in lake sediments from the decomposition of organic carbon at rates affected by vegetation presence and type as well as sediment temperature. Recent research in the Stordalen Mire in northern Sweden has suggested that labile organic carbon sources in young, shallow lake sediments yield the highest in situ sediment methane concentrations. Ebullition (or bubbling) of this methane is predominantly controlled by seasonal warming. In this project we sampled stream, glacial and post-glacial lake sediments along a drainage transect through the Stordalen Mire into the large glacial Lake Torneträsk. Our results indicate that the highest methane and total organic carbon (TOC) concentrations were observed in lake and stream sediments in the upper 25 centimeters, consistent with previous studies. C/N ratios range from 8 to 32, and suggest that a mix of aquatic and terrestrial vegetation sources dominate the sedimentary record. Although water transport occurs throughout the mire, major depositional centers for sediments and organic carbon occur within the lakes and prohibit young, labile TOC from entering the larger glacial Lake Torneträsk. The lack of an observed sediment fan at the outlet of the Mire to the lake is consistent with this observation. Our results suggest that carbon produced in the mire stays in the mire, allowing methane production to be greater in the mire bound lakes and streams than in the larger adjacent glacial lake.

Enhanced Performance of Nanowire-Based All-TiO2 Solar Cells using Subnanometer-Thick Atomic Layer Deposited ZnO Embedded Layer

International Nuclear Information System (INIS)

Ghobadi, Amir; Yavuz, Halil I.; Ulusoy, T. Gamze; Icli, K. Cagatay; Ozenbas, Macit; Okyay, Ali K.

2015-01-01

In this paper, the effect of angstrom-thick atomic layer deposited (ALD) ZnO embedded layer on photovoltaic (PV) performance of Nanowire-Based All-TiO 2 solar cells has been systematically investigated. Our results indicate that by varying the thickness of ZnO layer the efficiency of the solar cell can be significantly changed. It is shown that the efficiency has its maximum for optimal thickness of 1 ALD cycle in which this ultrathin ZnO layer improves device performance through passivation of surface traps without hampering injection efficiency of photogenerated electrons. The mechanisms contributing to this unprecedented change in PV performance of the cell have been scrutinized and discussed

Glacial and postglacial geology near Lake Tennyson, Clarence River, New Zealand

International Nuclear Information System (INIS)

McCalpin, J.P.

1992-01-01

Otiran valley glaciers extended 15 km down the upper Clarence Valley in central Marlborough, South Island, New Zealand. A massive Otiran terminal moraine complex, composed of moraines of three glacial advances, impounds Lake Tennyson. The moraines are early and middle Otiran, and possibly late Otiran-early Aranuian in age, based on relative position and differences in moraine morphology, weathering rinds, and soils. Radiocarbon ages from a tributary (Serpentine Creek) suggest the latest major episode of aggradation in the Clarence Valley was in progress by 11.3 ka, and had ended by 9.2 ka. Postglacial history was dominated by incision of glacial outwash, deposition of small alluvial fans, and landsliding near the trace of the Awatere Fault. Fault scarps of the Awatere Fault and of unnamed parallel splays displace early Otiran moraines up to 19 m and early Holocene terraces up to 2.6 m. (author). 25 refs., 10 figs., 3 tabs

Chronology and stratigraphy of the Magdalen Islands archipelago from the last glaciation to the early Holocene: new insights into the glacial and sea-level history of eastern Canada

DEFF Research Database (Denmark)

Rémillard, Audrey M.; St-Onge, Guillaume; Bernatchez, Pascal

2016-01-01

of the deposits and the establishment of a precise chronological framework. This study provides a detailed description of 21 stratigraphical sequences located throughout the archipelago, as well as the first comprehensive luminescence chronology from the Last Glacial Maximum (LGM) to c. 10 ka. In addition......The Magdalen Islands (Québec, Canada) are a key location for unravelling the glacial and sea-level history of the Maritime Provinces of eastern Canada. Although many sedimentary sequences have been described in the literature, absolute ages are lacking, impeding an accurate interpretation...... to the five samples collected for age control purposes, 34 luminescence samples were taken from 17 different sites in glacial, periglacial and coastal deposits. The stratigraphical and chronological data reveal that the islands were at the crossroads of two icecaps during the LGM; the southern islands were...

The glacially overdeepened trough of the Salzach Valley, Austria: Bedrock geometry and sedimentary fill of a major Alpine subglacial basin

Science.gov (United States)

Pomper, Johannes; Salcher, Bernhard C.; Eichkitz, Christoph; Prasicek, Günther; Lang, Andreas; Lindner, Martin; Götz, Joachim

2017-10-01

Overdeepened valleys are unambiguous features of glacially sculpted landscapes. They result from erosion at the bed of the glacier and their size and shape is determined by ice dynamics and the characteristics of the underlying bedrock. Major overdeepened valleys representing vertical bedrock erosion of several hundreds of meters are characteristic features of many trunk valleys in the formerly glaciated parts of the Alpine mountain belt. The thick sedimentary fill usually hinders attempts to unravel bedrock geometry, formation history and fill characteristics. Based on reflection seismic data and core-logs from multiple deep drillings we construct a detailed bedrock model of the Lower Salzach Valley trough, one of the largest overdeepened valleys in the European Alps. The analysed overdeepened structure characterized by a strongly undulating topography. Two reaches of enhanced erosion can be identified and are suggested to be related to variations in bedrock erodibility and a triple glacier confluence. The sedimentary fill shows clear characteristics of rapid infilling and subaqueous fan delta deposits indicate a strong influence of tributary streams. Associated surface lowering of the valley floor had a major impact on tributary stream incision but also on the available ice accumulation area at subsequent glaciations. The extent to which fills of earlier glaciations have been preserved from erosion during the last glacial maximum remains ambiguous and demands further exploration. To our knowledge the presented bedrock model is one of the best defined of any major overdeepened trunk valley.

A late glacial record of ice-sheet dynamics and melt supply recovered in the sediments of IODP Expedition 347 in the Baltic Sea

Science.gov (United States)

Passchier, Sandra; Jensen, Jørn Bo; Kenzler, Michael; Johnson, Sean; Andrén, Thomas; Barker Jørgensen, Bo

2015-04-01

Modern observations of increased surface ablation, meltwater routing to the bed, and increases in glacial speeds point to feedbacks between ice-sheet dynamics, melt supply, and subglacial discharge. Paleorecords have the potential to explore the decadal to centennial variability of these systems, but until recently such records were short and discontinuous in ice-proximal settings and underutilized for this specific purpose. The Integrated Ocean Drilling Program Expedition 347 in the Baltic Sea recovered annually laminated sediments that document the dynamics of the Scandinavian Ice Sheet. Hydraulic piston cores recovered from Sites M0060, M0063, M0064, and M0065 allow us to reconstruct a nearly complete record of ca. 6000 years in ice retreat history at annual to decadal resolution between ca. 17 and 11ka. The late glacial successions of these four IODP drillsites comprise of a till or proglacial fluvioglacial sediment overlain by variable thicknesses of well-laminated deglacial successions within several high-recovery holes. As the Scandinavian Ice Sheet retreated from the western Baltic Sea, and to the North, the ice-sheet's grounding line migrated across the four sites and deposited overlapping sections of high-resolution ice-proximal to ice-distal successions. Laser particle size results from Sites M0060 and M0063, and inspection of line-scan images, show shifts in sedimentary facies and lithologies that were not recognized during initial visual core description. For example, at Site M0060 in the Kattegat, ice-rafting fluxes in silty clays decrease upward and are negligible in the overlying varved succession. These characteristics are interpreted as ice retreat within a calving bay environment from ca. 17ka onward, followed by distal glacial marine deposition from sediment plumes governed by meltwater discharge. Moreover, at Site M0063 in the Baltic Sea, laser particle size distributions record an abrupt shift from interlaminated clayey silt to laminated clay

Holocene glacial fluctuations in southern South America

Science.gov (United States)

Reynhout, S.; Sagredo, E. A.; Kaplan, M. R.; Aravena, J. C.; Martini, M. A.; Strelin, J. A.; Schaefer, J. M.

2016-12-01

Understanding the timing and magnitude of former glacier fluctuations is critical to decipher long-term climatic trends and to unravel both natural cycles and human impact on the current glacial behavior. Despite more than seven decades of research efforts, a unifying model of Holocene glacial fluctuations in Southern South America remains elusive. Here, we present the state-of-the-art regarding the timing of Holocene glacial fluctuation in southern Patagonia-Tierra del Fuego, with a focus on a new generation of high-resolution radiocarbon and 10Be surface exposure dating chronologies. Recently acquired evidence suggest that after receding from advanced Late Glacial positions, Patagonian glaciers were for the most part close to, or even behind, present ice margins during the Early Holocene. On the other hand, emerging chronologies indicate that in some areas there were extensive expansions (century scale?) that punctuated the warm interval. Subsequently, we have evidence of multiple millennial timescale glacial advances starting in the middle Holocene. Several glacial maxima are defined by moraines and other landforms from 7000 years ago to the 19th century, with a gap sometime between 4,500 and 2,500 years ago. The last set of advances began around 800-600 years ago. Although glacial activity is documented in Patagonia at the same time as the European Little Ice Age, the extent of these glacial events are less prominent than those of the mid-Holocene. The causes that may explain these glacial fluctuations remain elusive. Finally, we discuss ongoing efforts to better define the timing and extent of Holocene glaciations in southern South America, and to establish the basis to test competing hypothesis of regional Holocene climate variability.

Falsifying the Sikussak-Oasis Hypothesis for the Tillite Group, East Greenland: Implications for Trezona-like Carbon Isotope Excursions Beneath Neoproterozoic Glacials

Science.gov (United States)

Hoffman, P. F.; Domack, E. W.; Maloof, A. C.; Halverson, G. P.

2006-05-01

In Neoproterozoic time, East Greenland and East Svalbard (EGES) occupied landward and seaward positions, respectively, on the southern subtropical margin of Laurentia. In both areas, thick clastic-to-carbonate successions are overlain by two discrete glacial and/or periglacial formations, separated by fine basinal clastics. In Svalbard, the younger glacial has a characteristic Marinoan (basal Ediacaran) cap dolostone, but the older glacial is underlain by a 10-permil negative carbon isotope excursion that is indistinguishable from excursions observed exclusively beneath Marinoan glacials in Australia, Namibia and western Laurentia. This led us to propose (Basin Research 16, 297-324, 2004) that the paired glacials in EGES represent the onset and climax of a single, long-lived, Marinoan glaciation. The intervening fine clastics, which contain ikaite pseudomorphs, presumptively accumulated beneath permanent shorefast sea ice (sikussak), analogous to East Greenland fjords during the Younger Dryas and Little Ice Age. In this model, the top of the older glacial signals the start of Snowball Earth. We conducted a preliminary field test of the sikussak hypothesis in Strindberg Land (SL), Andrée Land (AL) and Ella O (EO), East Greenland. We confirmed the correlation of the paired glacials and the Marinoan cap dolostone (missing on EO). In SL, the older glacial (Ulveso Fm) is a thin diamictite overlain by conglomerate lag and a set of megavarves composed of alternating siltstone and ice-rafted debris. In AL and EO, the Ulveso is a sub-glacial diamictite overlain by aeolian and/or marine sandstone. In Bastion Bugt on EO, it is a transgressive shoreface sandstone. This proves that glacial recession occurred under open-water conditions and did not result from permanent sea-ice formation, as stipulated in the sikussak model. There is no evidence that the fine clastic sequence between the glacials formed under an ice cover, or for a single glacial period. This brings us back to

An improved active contour model for glacial lake extraction

Science.gov (United States)

Zhao, H.; Chen, F.; Zhang, M.

2017-12-01

Active contour model is a widely used method in visual tracking and image segmentation. Under the driven of objective function, the initial curve defined in active contour model will evolve to a stable condition - a desired result in given image. As a typical region-based active contour model, C-V model has a good effect on weak boundaries detection and anti noise ability which shows great potential in glacial lake extraction. Glacial lake is a sensitive indicator for reflecting global climate change, therefore accurate delineate glacial lake boundaries is essential to evaluate hydrologic environment and living environment. However, the current method in glacial lake extraction mainly contains water index method and recognition classification method are diffcult to directly applied in large scale glacial lake extraction due to the diversity of glacial lakes and masses impacted factors in the image, such as image noise, shadows, snow and ice, etc. Regarding the abovementioned advantanges of C-V model and diffcults in glacial lake extraction, we introduce the signed pressure force function to improve the C-V model for adapting to processing of glacial lake extraction. To inspect the effect of glacial lake extraction results, three typical glacial lake development sites were selected, include Altai mountains, Centre Himalayas, South-eastern Tibet, and Landsat8 OLI imagery was conducted as experiment data source, Google earth imagery as reference data for varifying the results. The experiment consequence suggests that improved active contour model we proposed can effectively discriminate the glacial lakes from complex backgound with a higher Kappa Coefficient - 0.895, especially in some small glacial lakes which belongs to weak information in the image. Our finding provide a new approach to improved accuracy under the condition of large proportion of small glacial lakes and the possibility for automated glacial lake mapping in large-scale area.

Ground-water availability in the central part of Lake Ontario basin, New York

Science.gov (United States)

Miller, Todd S.; Krebs, Martha M.

1988-01-01

A set of three maps showing surficial geology, distribution of glacial aquifers, and potential well yield in the 708 sq mi central part of the Lake Ontario basin are presented at a scale of 1:125,000. The basin is parallel to Lake Ontario and extends from Rochester in the west to Oswego in the east. Aquifers consisting primarily of sand and gravel formed where meltwaters from glaciers deposited kame and outwash sand and gravel and where wave action along shores of glacial lakes eroded, reworked , and deposited beaches. Thick deposits of well-sorted sand and gravel yield relatively large quantities of water - typically more than 100 gal/min. Aquifers consisting of thin beds of sand and (or) gravel or thick gravel that contain a large proportion of silt and fine sand yield moderate amounts of water, 10 to 100 gal/min. Dug and driven wells that tap fine to medium sand deposits typically yield 1 to 10 gal/min. (USGS)

Environmental conditions of interstadial (MIS 3 and features of the last glacial maximum on the King George island (West Antarctica

Directory of Open Access Journals (Sweden)

S. R. Verkulich

2013-01-01

Full Text Available The interstadial marine deposits stratum was described in the Fildes Peninsula (King George Island due to field and laboratory investigations during 2008–2011. The stratum fragments occur in the west and north-west parts of peninsula in following forms: sections of soft sediments, containing fossil shells, marine algae, bones of marine animals and rich marine diatom complexes in situ (11 sites; fragments of shells and bones on the surface (25 sites. According to the results of radiocarbon dating, these deposits were accumulated within the period 19–50 ky BP. Geographical and altitude settings of the sites, age characteristics, taxonomy of fossil flora and fauna, and good safety of the soft deposits stratum allow to make following conclusions: during interstadial, sea water covered significant part of King George Island up to the present altitude of 40 m a.s.l., and the King George Island glaciation had smaller size then; environmental conditions for the interstadial deposit stratum accumulation were at least not colder than today; probably, the King George island territory was covered entirely by ice masses of Last glacial maximum not earlier than 19 ky BP; during Last glacial maximum, King George Island was covered by thin, «cold», not mobile glaciers, which contribute to conservation of the soft marine interstadial deposits filled with fossil flora and fauna.

Hydrochemical Regions of the Glacial Aquifer System, Northern United States, and Their Environmental and Water-Quality Characteristics

Science.gov (United States)

Arnold, Terri L.; Warner, Kelly L.; Groschen, George E.; Caldwell, James P.; Kalkhoff, Stephen J.

2008-01-01

The glacial aquifer system in the United States is a large (953,000 square miles) regional aquifer system of heterogeneous composition. As described in this report, the glacial aquifer system includes all unconsolidated geologic material above bedrock that lies on or north of the line of maximum glacial advance within the United States. Examining ground-water quality on a regional scale indicates that variations in the concentrations of major and minor ions and some trace elements most likely are the result of natural variations in the geologic and physical environment. Study of the glacial aquifer system was designed around a regional framework based on the assumption that two primary characteristics of the aquifer system can affect water quality: intrinsic susceptibility (hydraulic properties) and vulnerability (geochemical properties). The hydrochemical regions described in this report were developed to identify and explain regional spatial variations in ground-water quality in the glacial aquifer system within the hypothetical framework context. Data analyzed for this study were collected from 1991 to 2003 at 1,716 wells open to the glacial aquifer system. Cluster analysis was used to group wells with similar ground-water concentrations of calcium, chloride, fluoride, magnesium, potassium, sodium, sulfate, and bicarbonate into five unique groups. Maximum Likelihood Classification was used to make the extrapolation from clustered groups of wells, defined by points, to areas of similar water quality (hydrochemical regions) defined in a geospatial model. Spatial data that represented average annual precipitation, average annual temperature, land use, land-surface slope, vertical soil permeability, average soil clay content, texture of surficial deposits, type of surficial deposit, and potential for ground-water recharge were used in the Maximum Likelihood Classification to classify the areas so the characteristics of the hydrochemical regions would resemble the

Thick film hydrogen sensor

Science.gov (United States)

Hoffheins, Barbara S.; Lauf, Robert J.

1995-01-01

A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors.

Calculation of Al2O3 contents in Al2O3-PTFE composite thick films fabricated by using the aerosol deposition

International Nuclear Information System (INIS)

Kim, Hyung-Jun; Kim, Yoon-Hyun; Nam, Song-Min; Yoon, Young-Joon; Kim, Jong-Hee

2010-01-01

Low-temperature fabrication of Al 2 O 3 -PTFE (poly tetra fluoro ethylene) composite thick films for flexible integrated substrates was attempted by using the aerosol deposition method. For optimization of composite thick films, a novel calculation method for the ceramic contents in the composites was attempted. Generally, a thermogravimetry (TG) analysis is used to calculate the ceramic contents in the ceramic-polymer composites. However, the TG analysis requires a long measurement time in each analysis, so we studied a novel calculation method that used a simple dielectric measurement. We used Hashin-Shtrikman bounds to obtain numerical results for the relationship between the dielectric constant of the composites and the contents of Al 2 O 3 . A 3-D electrostatic simulation model similar to the deposited Al 2 O 3 -PTFE composite thick films was prepared, and the simulation result was around the lower bound of the Hashin-Shtrikman bounds. As a result, we could calculate the Al 2 O 3 contents in the composites with a low error of below 5 vol.% from convenient dielectric measurements, and the Al 2 O 3 contents ranged from 51 vol.% to 54 vol.%.

Channel layer thickness dependence of In-Ti-Zn-O thin-film transistors fabricated using pulsed laser deposition

International Nuclear Information System (INIS)

Zhang, Q.; Shan, F. K.; Liu, G. X.; Liu, A.; Lee, W. J.; Shin, B. C.

2014-01-01

Amorphous indium-titanium-zinc-oxide (ITZO) thin-film transistors (TFTs) with various channel thicknesses were fabricated at room temperature by using pulsed laser deposition. The channel layer thickness (CLT) dependence of the TFTs was investigated. All the ITZO thin films were amorphous, and the surface roughnesses decreased slightly first and then increased with increasing CLT. With increasing CLT from 35 to 140 nm, the on/off current ratio and the field-effect mobility increased, and the subthreshold swing decreased. The TFT with a CLT of 210 nm exhibited the worst performance, while the ITZO TFT with a CLT of 140 nm exhibited the best performance with a subthreshold voltage of 2.86 V, a mobility of 53.9 cm 2 V -1 s -1 , a subthreshold swing of 0.29 V/decade and an on/off current ratio of 10 9 .

Changes in Glaciers and Glacial Lakes and the Identification of Dangerous Glacial Lakes in the Pumqu River Basin, Xizang (Tibet

Directory of Open Access Journals (Sweden)

Tao Che

2014-01-01

Full Text Available Latest satellite images have been utilized to update the inventories of glaciers and glacial lakes in the Pumqu river basin, Xizang (Tibet, in the study. Compared to the inventories in 1970s, the areas of glaciers are reduced by 19.05% while the areas of glacial lakes are increased by 26.76%. The magnitudes of glacier retreat rate and glacial lake increase rate during the period of 2001–2013 are more significant than those for the period of the 1970s–2001. The accelerated changes in areas of the glaciers and glacial lakes, as well as the increasing temperature and rising variability of precipitation, have resulted in an increased risk of glacial lake outburst floods (GLOFs in the Pumqu river basin. Integrated criteria were established to identify potentially dangerous glacial lakes based on a bibliometric analysis method. It is found, in total, 19 glacial lakes were identified as dangerous. Such finding suggests that there is an immediate need to conduct field surveys not only to validate the findings, but also to acquire information for further use in order to assure the welfare of the humans.

Effect of substrates and thickness on optical properties in atomic layer deposition grown ZnO thin films

Science.gov (United States)

Pal, Dipayan; Singhal, Jaya; Mathur, Aakash; Singh, Ajaib; Dutta, Surjendu; Zollner, Stefan; Chattopadhyay, Sudeshna

2017-11-01

Atomic Layer Deposition technique was used to grow high quality, very low roughness, crystalline, Zinc Oxide (ZnO) thin films on silicon (Si) and fused quartz (SiO2) substrates to study the optical properties. Spectroscopic ellipsometry results of ZnO/Si system, staggered type-II quantum well, demonstrate that there is a significant drop in the magnitudes of both the real and imaginary parts of complex dielectric constants and in near-band gap absorption along with a blue shift of the absorption edge with decreasing film thickness at and below ∼20 nm. Conversely, UV-vis absorption spectroscopy of ZnO/SiO2, thin type-I quantum well, consisting of a narrower-band gap semiconductor grown on a wider-band gap (insulator) substrate, shows the similar thickness dependent blue-shift of the absorption edge but with an increase in the magnitude of near-band gap absorption with decreasing film thickness. Thickness dependent blue shift, energy vs. 1/d2, in two different systems, ZnO/Si and ZnO/SiO2, show a difference in their slopes. The observed phenomena can be consistently explained by the corresponding exciton (or carrier/s) deconfinement and confinement effects at the ZnO/Si and ZnO/SiO2 interface respectively, where Tanguy-Elliott amplitude pre-factor plays the key role through the electron-hole overlap factor at the interface.

Biometric estimation of chest wall thickness of females

International Nuclear Information System (INIS)

Berger, C.D.; Lane, B.H.

1985-01-01

Optimal use of whole-body counting data to estimate pulmonary deposition of many of the actinides is dependent upon accurate measurement of the thickness of the chest wall because of severe attenuation of low-energy x rays and photons associated with the decay of these radionuclides. An algorithm for estimation of female chest wall thicknesses, verified by real-time ultrasonic measurements, has been derived based on the correlation of measured chest wall thickness and other common biometric quantities. Use of this algorithm will reduce the error generally associated with estimation of internal actinide deposition previously resulting from assuming an average chest wall thickness for all female subjects

Thickness dependence of magnetic properties and giant magneto-impedance effect in amorphous Co{sub 73}Si{sub 12}B{sub 15} thin films prepared by Dual-Ion beam assisted deposition

Energy Technology Data Exchange (ETDEWEB)

Zhang, Yu [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); BISSE/BUAA-SPNEE joint Laboratory Magnetism and Sperconducting technology on Spacecraft, Beihang University, Beijing 100191 (China); Wang, San-sheng, E-mail: wangssh@buaa.edu.cn [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); BISSE/BUAA-SPNEE joint Laboratory Magnetism and Sperconducting technology on Spacecraft, Beihang University, Beijing 100191 (China); Hu, Teng [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); He, Tong-fu [School of Instrumentation Science and Opto-electronics Engineering, Beihang University, Beijing 100191 (China); Chen, Zi-yu [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); Yi, Zhong; Meng, Li-Fei [Science and Technology on Reliability and Environmental Engineering Laboratory, Beijing Institute of Spacecraft Environment Engineering, Beijing 100094 (China); BISSE/BUAA-SPNEE joint Laboratory Magnetism and Sperconducting technology on Spacecraft, Beihang University, Beijing 100191 (China)

2017-03-15

Dual-Ion Beam Assisted Deposition is a suitable method for the preparation of giant magneto-impedance (GMI) materials. In this paper, Co{sub 73}Si{sub 12}B{sub 15} thin films with different thicknesses were prepared by Dual-Ion Beam Assisted Deposition, and the influences of film thickness on magnetic properties and GMI effect were investigated. It was found that the asymmetric magnetic hysteresis loop in the prepared Co{sub 73}Si{sub 12}B{sub 15} thin films occurs at ambient temperature, and the shift behavior of hysteresis loop associated with film thickness. With the film thickness increasing, the values of shift field and coercive field and other parameters such as remanence and shift ratio appeared complex variation. At a certain frequency, the large GMI effect is only observed in some films, which have good magnetic properties including low coercivity, low remanence ratio and high shift ratio. The results indicated that the thickness dependence of magnetic properties nonlinearly determined the GMI effect in Co{sub 73}Si{sub 12}B{sub 15} thin films. - Highlights: • The relationship between film thickness and ΔZ/Z, ΔR/R, ΔX/X ratio of CoSiB film exhibits a complex behavior as the film thickness increases from 1.33 to 7.34 µm. The maximum value of GMI ratio is observed when the film thickness was 1.56, 2.48, 3.81 or 7.34 µm. • With the increase of film thickness, the peak frequency shifts to lower frequency, but does not decrease following the t-power law. • The above thickness phenomenon is due to the different magnetic properties of thin films. • The Dual-Ion Beam Assisted Deposition is introduced to prepare the GMI materials.

Glacial lakes of the Central and Patagonian Andes

Science.gov (United States)

Wilson, Ryan; Glasser, Neil F.; Reynolds, John M.; Harrison, Stephan; Anacona, Pablo Iribarren; Schaefer, Marius; Shannon, Sarah

2018-03-01

The prevalence and increased frequency of high-magnitude Glacial Lake Outburst Floods (GLOFs) in the Chilean and Argentinean Andes suggests this region will be prone to similar events in the future as glaciers continue to retreat and thin under a warming climate. Despite this situation, monitoring of glacial lake development in this region has been limited, with past investigations only covering relatively small regions of Patagonia. This study presents new glacial lake inventories for 1986, 2000 and 2016, covering the Central Andes, Northern Patagonia and Southern Patagonia. Our aim was to characterise the physical attributes, spatial distribution and temporal development of glacial lakes in these three sub-regions using Landsat satellite imagery and image datasets available in Google Earth and Bing Maps. Glacial lake water volume was also estimated using an empirical area-volume scaling approach. Results reveal that glacial lakes across the study area have increased in number (43%) and areal extent (7%) between 1986 and 2016. Such changes equate to a glacial lake water volume increase of 65 km3 during the 30-year observation period. However, glacial lake growth and emergence was shown to vary sub-regionally according to localised topography, meteorology, climate change, rate of glacier change and the availability of low gradient ice areas. These and other factors are likely to influence the occurrence of GLOFs in the future. This analysis represents the first large-scale census of glacial lakes in Chile and Argentina and will allow for a better understanding of lake development in this region, as well as, providing a basis for future GLOF risk assessments.

Growth Normal Faulting at the Western Edge of the Metropolitan Taipei Basin since the Last Glacial Maximum, Northern Taiwan

Directory of Open Access Journals (Sweden)

Chih-Tung Chen

2010-01-01

Full Text Available Growth strata analysis is an useful tool in understanding kinematics and the evolution of active faults as well as the close relationship between sedimentation and tectonics. Here we present the Shanchiao Fault as a case study which is an active normal fault responsible for the formation of the 700-m-thick late Quaternary deposits in Taipei Basin at the northern tip of the Taiwan mountain belt. We compiled a sedimentary record, particularly the depositional facies and their dated ages, at three boreholes (SCF-1, SCF-2 and WK-1, from west to east along the Wuku Profile that traverses the Shanchiao Fault at its central segment. By incorporating the global sea level change curve, we find that thickness changes of sediments and changes of depositional environments in the Wuku area are in a good agreement with a rapid sea level rise since the Last Glacial Maximum (LGM of about 23 ka. Combining depositional facies changes and their ages with their thickness, we are able to introduce a simple back-stripping method to reconstruct the evolution of growing strata across the Shanchiao Fault since the LGM. We then estimate the vertical tectonic slip rate since 23 ka, which exhibits 2.2 mm yr-1 between SCF-2 and WK-1 and 1.1 mm yr-1 between SCF-1 and SCF-2. We also obtain the Holocene tectonic subsidence rate of 2.3 mm yr-1 at WK-1 and 0.9 mm yr-1 at SCF-2 since 8.4 ka. We thus conclude that the fault zone consists of a high-angle main fault to the east between SCF-2 and WK-1 and a western lower-angle branch fault between SCF-1 and SCF-2, resembling a tulip structure developed under sinistral transtensional tectonism. We find that a short period of 600-yr time span in 9 - 8.4 ka shows important tectonic subsidence of 7.4 and 3.3 m for the main and branch fault, respectively, consistent with possible earthquake events proposed by previous studies during that time. A correlation between geomorphology and subsurface geology in the Shanchiao Fault zone shows

Effect of Ga2O3 buffer layer thickness on the properties of Cu/ITO thin films deposited on flexible substrates

International Nuclear Information System (INIS)

Zhuang Huihui; Yan Jinliang; Xu Chengyang; Meng Delan

2014-01-01

Cu and Cu/ITO films were prepared on polyethylene terephthalate (PET) substrates with a Ga 2 O 3 buffer layer using radio frequency (RF) and direct current (DC) magnetron sputtering. The effect of Cu layer thickness on the optical and electrical properties of the Cu film deposited on a PET substrate with a Ga 2 O 3 buffer layer was studied, and an appropriate Cu layer thickness of 4.2 nm was obtained. Changes in the optoelectrical properties of Cu(4.2 nm)/ITO(30 nm) films were investigated with respect to the Ga 2 O 3 buffer layer thickness. The optical and electrical properties of the Cu/ITO films were significantly influenced by the thickness of the Ga 2 O 3 buffer layer. A maximum transmission of 86%, sheet resistance of 45 Ω/□ and figure of merit of 3.96 × 10 −3 Ω −1 were achieved for Cu(4.2 nm)/ITO(30 nm) films with a Ga 2 O 3 layer thickness of 15 nm. (semiconductor materials)

Thermal release of D2 from new Be-D co-deposits on previously baked co-deposits

Science.gov (United States)

Baldwin, M. J.; Doerner, R. P.

2015-12-01

Past experiments and modeling with the TMAP code in [1, 2] indicated that Be-D co-deposited layers are less (time-wise) efficiently desorbed of retained D in a fixed low-temperature bake, as the layer grows in thickness. In ITER, beryllium rich co-deposited layers will grow in thickness over the life of the machine. Although, compared with the analyses in [1, 2], ITER presents a slightly different bake efficiency problem because of instances of prior tritium recover/control baking. More relevant to ITER, is the thermal release from a new and saturated co-deposit layer in contact with a thickness of previously-baked, less-saturated, co-deposit. Experiments that examine the desorption of saturated co-deposited over-layers in contact with previously baked under-layers are reported and comparison is made to layers of the same combined thickness. Deposition temperatures of ∼323 K and ∼373 K are explored. It is found that an instance of prior bake leads to a subtle effect on the under-layer. The effect causes the thermal desorption of the new saturated over-layer to deviate from the prediction of the validated TMAP model in [2]. Instead of the D thermal release reflecting the combined thickness and levels of D saturation in the over and under layer, experiment differs in that, i) the desorption is a fractional superposition of desorption from the saturated over-layer, with ii) that of the combined over and under -layer thickness. The result is not easily modeled by TMAP without the incorporation of a thin BeO inter-layer which is confirmed experimentally on baked Be-D co-deposits using X-ray micro-analysis.

Thermal release of D_2 from new Be-D co-deposits on previously baked co-deposits

International Nuclear Information System (INIS)

Baldwin, M.J.; Doerner, R.P.

2015-01-01

Past experiments and modeling with the TMAP code in [1, 2] indicated that Be-D co-deposited layers are less (time-wise) efficiently desorbed of retained D in a fixed low-temperature bake, as the layer grows in thickness. In ITER, beryllium rich co-deposited layers will grow in thickness over the life of the machine. Although, compared with the analyses in [1, 2], ITER presents a slightly different bake efficiency problem because of instances of prior tritium recover/control baking. More relevant to ITER, is the thermal release from a new and saturated co-deposit layer in contact with a thickness of previously-baked, less-saturated, co-deposit. Experiments that examine the desorption of saturated co-deposited over-layers in contact with previously baked under-layers are reported and comparison is made to layers of the same combined thickness. Deposition temperatures of ∼323 K and ∼373 K are explored. It is found that an instance of prior bake leads to a subtle effect on the under-layer. The effect causes the thermal desorption of the new saturated over-layer to deviate from the prediction of the validated TMAP model in [2]. Instead of the D thermal release reflecting the combined thickness and levels of D saturation in the over and under layer, experiment differs in that, i) the desorption is a fractional superposition of desorption from the saturated over-layer, with ii) that of the combined over and under -layer thickness. The result is not easily modeled by TMAP without the incorporation of a thin BeO inter-layer which is confirmed experimentally on baked Be-D co-deposits using X-ray micro-analysis.

Characterization of 13 and 30 mum thick hydrogenated amorphous silicon diodes deposited over CMOS integrated circuits for particle detection application

CERN Document Server

Despeisse, M; Commichau, S C; Dissertori, G; Garrigos, A; Jarron, P; Miazza, C; Moraes, D; Shah, A; Wyrsch, N; Viertel, Gert M; 10.1016/j.nima.2003.11.022

2004-01-01

We present the experimental results obtained with a novel monolithic silicon pixel detector which consists in depositing a n-i-p hydrogenated amorphous silicon (a-Si:H) diode straight above the readout ASIC (this technology is called Thin Film on ASIC, TFA). The characterization has been performed on 13 and 30mum thick a-Si:H films deposited on top of an ASIC containing a linear array of high- speed low-noise transimpedance amplifiers designed in a 0.25mum CMOS technology. Experimental results presented have been obtained with a 600nm pulsed laser. The results of charge collection efficiency and charge collection speed of these structures are discussed.

Residual stress analysis in thick uranium films

International Nuclear Information System (INIS)

Hodge, A.M.; Foreman, R.J.; Gallegos, G.F.

2005-01-01

Residual stress analysis was performed on thick, 1-25 μm, depleted uranium (DU) films deposited on an Al substrate by magnetron sputtering. Two distinct characterization techniques were used to measure substrate curvature before and after deposition. Stress evaluation was performed using the Benabdi/Roche equation, which is based on beam theory of a bi-layer material. The residual stress evolution was studied as a function of coating thickness and applied negative bias voltage (0, -200, -300 V). The stresses developed were always compressive; however, increasing the coating thickness and applying a bias voltage presented a trend towards more tensile stresses and thus an overall reduction of residual stresses

Glacial Features (Point) - Quad 168 (EPPING, NH)

Data.gov (United States)

University of New Hampshire — The Glacial Features (Point) layer describes point features associated with surficial geology. These glacial features include, but are not limited to, delta forsets,...

Antireflectance coating on shielding window glasses using glacial acetic acid at ambient temperature

International Nuclear Information System (INIS)

Sathi Sasidharan, N.; Deshingkar, D.S.; Wattal, P.K.

2006-01-01

High density lead glasses having thickness of several centimeters and large dimensions are used as shielding windows in hot cells. To improve visibility, the reflection of light from its optically polished surfaces needs to be minimized to improve transmission as absorption of light in the thick glasses can not be avoided. Antireflectance coating of a material having low refractive index is required for this purpose. Selective leaching of lead at ambient temperature in glacial acetic acid develops a silica rich leached layer on glass surface. Since silica has low refractive index, the leached layer serves as antireflectance coating. Two optically polished discs of shielding window glasses were leached in glacial acetic acid at ambient temperature for 2, 5 and 10 days and their reflectance and transmittance spectra were taken to find effect of leaching. For transparent glass transmittance could be improved from 78.76% to 85.31% after 10 days leaching. Reflectance from the glass could be decreased from 12.48 to 11.67%. For coloured glass transmittance improved from 87.77% to 88.24% after 5 days leaching while reflectance decreased from 12.28% to 5.6% during same period. Based on data generated, 10 days leaching time is recommended for developing anti reflectance coating on transparent shielding window glass and 5 days for coloured shielding window glass. The procedure can be used for shielding windows of any dimensions by fabrication a PVC tank of slightly high dimensions and filling with acetic acid (author)

Last Glacial Maximum Dated by Means of 10Be in the Maritime Alps (Italy)

Science.gov (United States)

Granger, D. E.; Spagnolo, M.; Federici, P.; Pappalardo, M.; Ribolini, A.; Cyr, A. J.

2006-12-01

Relatively few exposure dates of LGM moraines boulders are available for the European Alps, and none on the southern flank. Ponte Murato (PM) is a frontal moraine at 860 m asl in the Gesso Basin (Maritime Alps, SW European Alps). The PM moraine dams the 157 km2 Gesso della Barra Valley and it represents the lowermost frontal moraine of the entire Gesso Valley, near the outlet of the valley in the Po Plain. Its ELA, determined from the paleo- shape of the supposed Gesso della Barra glacier, is 1746 m asl. Tetti Bandito (TB) is a small and badly preserved glacial deposit, tentatively attributed to a lateral-frontal moraine, that is positioned 5 km downvalley from the PM deposit at 800 m asl. There are no other glacial deposits downvalley from the TB moraine in the Gesso Basin or farther NE in the piedmont region of the upper Po Plain. Boulders sampled on the PM and on the TB moraine crests gave a 10Be cosmogenic age of respectively 16300 ± 880 ka (average value) and 18798 ± 973 ka. This result constrains the PM frontal moraine within the LGM interval but also suggests that the maximum expansion of the Gesso Basin glacier was more downvalley at some point during the last glaciation. If the TB is a lateral-frontal moraine as supposed, the two TB and PM moraines would represent the outer and inner moraine crests of the same LGM stadial, with the outer moraine much less pronounced than the inner moraine, similarly to the maximalstand and the hochstand described in the Eastern Alps (Van Husen, 1997). Within this perspective, the PM and TB dates are consistent with a European Alps LGM corresponding to MIS 2 (Ivy-Ochs et al., 2004). This study of the Maritime Alps moraines is also in agreement with the Upper Würm climatic theory (Florineth and Schlüchter, 2000) of a stronger influence of the W and SW incoming humid airflows in the European Alps, differently from the nearby Vosges and Pyrenees mountain chains where more dry conditions were probably responsible for a very

Thermal release of D{sub 2} from new Be-D co-deposits on previously baked co-deposits

Energy Technology Data Exchange (ETDEWEB)

Baldwin, M.J., E-mail: m1baldwin@ucsd.edu; Doerner, R.P.

2015-12-15

Past experiments and modeling with the TMAP code in [1, 2] indicated that Be-D co-deposited layers are less (time-wise) efficiently desorbed of retained D in a fixed low-temperature bake, as the layer grows in thickness. In ITER, beryllium rich co-deposited layers will grow in thickness over the life of the machine. Although, compared with the analyses in [1, 2], ITER presents a slightly different bake efficiency problem because of instances of prior tritium recover/control baking. More relevant to ITER, is the thermal release from a new and saturated co-deposit layer in contact with a thickness of previously-baked, less-saturated, co-deposit. Experiments that examine the desorption of saturated co-deposited over-layers in contact with previously baked under-layers are reported and comparison is made to layers of the same combined thickness. Deposition temperatures of ∼323 K and ∼373 K are explored. It is found that an instance of prior bake leads to a subtle effect on the under-layer. The effect causes the thermal desorption of the new saturated over-layer to deviate from the prediction of the validated TMAP model in [2]. Instead of the D thermal release reflecting the combined thickness and levels of D saturation in the over and under layer, experiment differs in that, i) the desorption is a fractional superposition of desorption from the saturated over-layer, with ii) that of the combined over and under -layer thickness. The result is not easily modeled by TMAP without the incorporation of a thin BeO inter-layer which is confirmed experimentally on baked Be-D co-deposits using X-ray micro-analysis.

Breakthrough to Non-Vacuum Deposition of Single-Crystal, Ultra-Thin, Homogeneous Nanoparticle Layers: A Better Alternative to Chemical Bath Deposition and Atomic Layer Deposition

Directory of Open Access Journals (Sweden)

Yu-Kuang Liao

2017-04-01

Full Text Available Most thin-film techniques require a multiple vacuum process, and cannot produce high-coverage continuous thin films with the thickness of a few nanometers on rough surfaces. We present a new ”paradigm shift” non-vacuum process to deposit high-quality, ultra-thin, single-crystal layers of coalesced sulfide nanoparticles (NPs with controllable thickness down to a few nanometers, based on thermal decomposition. This provides high-coverage, homogeneous thickness, and large-area deposition over a rough surface, with little material loss or liquid chemical waste, and deposition rates of 10 nm/min. This technique can potentially replace conventional thin-film deposition methods, such as atomic layer deposition (ALD and chemical bath deposition (CBD as used by the Cu(In,GaSe2 (CIGS thin-film solar cell industry for decades. We demonstrate 32% improvement of CIGS thin-film solar cell efficiency in comparison to reference devices prepared by conventional CBD deposition method by depositing the ZnS NPs buffer layer using the new process. The new ZnS NPs layer allows reduction of an intrinsic ZnO layer, which can lead to severe shunt leakage in case of a CBD buffer layer. This leads to a 65% relative efficiency increase.

A ~20,000 year history of glacial variability in the tropical Andes recorded in lake sediments from the Cordillera Blanca, Peru

Science.gov (United States)

Stansell, N.; Rodbell, D. T.; Moy, C. M.

2010-12-01

Pro-glacial lake sediments from the Cordillera Blanca, Peru contain continuous records of climate variability spanning the Last Glacial Maximum to present day. Here we present results from two alpine lake basins in the Queshgue Valley (9.8°S, 77.3°W) that contain high-resolution records of clastic sediment deposition for the last ~20,000 years. Radiocarbon-dated sediment cores were scanned at 0.5 to 1.0 cm resolution using a profiling x-ray fluorescence scanner for major and minor element distributions. In addition, we measured down-core variations in magnetic susceptibility, organic carbon, biogenic silica and calcium carbonate. Samples of bedrock and sediments from glacial moraines in the Queshgue watershed were analyzed using an ICP-MS in order to fingerprint and trace the source of glacial sediments deposited in the lakes. The bedrock is dominated by a combination of granodiorite with high Sr concentrations and meta-sedimentary rocks with high Zr values. Because the glacial sediments proximal to the modern glacier terminus are composed mostly of the granodiorite end-member, we interpret changes in Sr and clastic sediment concentrations in the lake sediment profiles as proxies for past glacial variability. Preliminary results indicate that glaciers retreated soon after ~14,500 cal yr BP and remained less extensive during the remaining late Glacial Stage and early Holocene. Gradually increasing clastic sediments through the middle and late Holocene indicate that glaciers became progressively larger, or more erosive towards present day. However, this overall Holocene trend of increasing glacier extent was interrupted by multiple periods of centennial- to millennial-scale ice margin retreat. For example, relative peaks in clastic sediments occurred from ~14,500 to 6000, 5600 to 5000, 4600 to 4200, 3600 to 3200, 2800 to 2700, 2400 to 2200, 1750 to 1550, 1100 to 900 cal yr BP, and during the Little Ice Age (~700 to 50 cal yr BP), while periods of low clastic

14C age of the Quaternary deposits in Japan, 150

International Nuclear Information System (INIS)

Tsunoda, Kiyomi

1983-01-01

The distribution of old buried valley deposits in the Tama Valley was pointed out by investigators, and the detailed surveys were carried out formerly, but the comparison and the age of the deposits have not been clear. Terrace gravel bed which is considered as a part of old buried deposits was found in the Machiya River, one of the tributary of the Tama River, and its small branches. The peat bed in the lowest gravel bed contained small amount of wood pieces. The determination of the age of wood pieces was made, and the absolute age of more than 37,800 yBP was obtained. Generally, the formation of buried valleys progressed during glacial epoch or interglacial epoch, in which the change of climate and the change of erosion and deposit environment occurred. The Tachikawa terrace is the last terrace in Tama River Basin, and was formed during Wuerm Glacial epoch. The results of the determination of age indicated that the formation of the valley is older than the formation of the Tachikawa terrace. The distribution of buried valleys has been known in other rivers which have their sources in the mountain regions of the Kanto District. The studies of buried valleys have important meaning in the formation of mountain regions and plains. (Ishimitsu, A.)

Managing the effects of accelerated glacial melting on volcanic collapse and debris flows: Planchon-Peteroa Volcano, Southern Andes

Science.gov (United States)

Tormey, Daniel

2010-11-01

Glaciated mountains are among the most sensitive environments to climatic changes, and recent work has shown that large-scale glacial melting, including at the end of the Pleistocene, caused a significant increase in the incidence of large volcanic sector collapse and debris flows on then-active volcanoes. With current accelerated rates of glacial melting, glaciated active volcanoes are at an increasing risk of sector collapse, debris flow and landslide. These catastrophic events are Earth's most damaging erosion phenomenon, causing extensive property damage and loss of life. This paper illustrates these effects in well-studied settings, focusing on the end-Pleistocene to Holocene glaciovolcanic growth and destruction of the cone of the active volcano Planchon-Peteroa in the Andean Southern Volcanic Zone at latitude 35° 15' S, along the border between Chile and Argentina. The development of the volcano over the last 14,000 years illustrates how glacial melting and magmatic activity can trigger landslides and sector collapses. Planchon had a large sector collapse that produced a highly mobile and erosive debris avalanche 11,000 years BP, and other slope instabilities during the end-Pleistocene/early Holocene deglaciation. The summit amphitheater left after the sector collapse was subject to alternating periods of glaciation and melting-induced lake formation. Breaching of the moraine dams then formed lahars and landslides originating at the western edge of the summit amphitheater, and the deposits are preserved along the western flank of the volcano. Deep incision of moraine deposits further down the western slope of the volcano indicates that the lahars and landslides were water-rich and had high erosive power. As illustrated by Planchon-Peteroa, the interplay among glacial growth and melting, magmatic activity, and slope stability is complex, but must be accounted for in volcanic hazard assessment. Planchon-Peteroa currently has the southernmost temperate zone

The Labrador Sea during the Last Glacial Maximum: Calcite dissolution or low biogenic carbonate fluxes?

Science.gov (United States)

Marshall, Nicole; de Vernal, Anne; Mucci, Alfonso; Filippova, Alexandra; Kienast, Markus

2017-04-01

Low concentrations of biogenic carbonate characterize the sediments deposited in the Labrador Sea during the last glaciation. This may reflect poor calcite preservation and/or low biogenic carbonate productivity and fluxes. Regional bottom water ventilation was reduced during the Last Glacial Maximum (LGM), so the calcite lysocline might have been shallower than at present in the deep Labrador Sea making dissolution of calcite shells in the deep Labrador Sea possible. To address the issue, a multi-proxy approach based on micropaleontological counts (coccoliths, foraminifers, palynomorphs) and biogeochemical analyses (alkenones) was applied in the investigation of core HU2008-029-004-PC recovered in the northwestern Labrador Sea. Calcite dissolution indices based on the relative abundance benthic foraminifera shells to their organic linings as well as on fragmentation of planktonic foraminifera shells were used to evaluate changes in calcite dissolution/ preservation since the LGM. In addition, the ratio of the concentrations of coccoliths, specifically of the alkenone-producer Emiliania huxleyi, and alkenones (Emiliania huxleyi: alkenones) was explored as a potential new proxy of calcite dissolution. A sharp increase in coccoliths, foraminifers and organic linings from nearly none to substantial concentrations at 12 ka, reflect a jump to significantly greater biogenic fluxes at the glacial-interglacial transition. Furthermore, conventional dissolution indices (shells/linings of benthic foraminifera and fragmentation of planktic foraminifers) reveal that dissolution is not likely responsible for the lower glacial abundances of coccoliths and foraminifers. Only the low Emiliania huxleyi: alkenones ratios in glacial sediments could be interpreted as evidence of increased dissolution during the LGM. Given the evidence of allochthonous alkenone input into the glacial Labrador Sea, the latter observations must be treated with caution. Overall, the records indicate that

Ice thickness estimations based on multi-temporal glacier inventories - potential and challenges

Science.gov (United States)

Helfricht, Kay; Huss, Matthias; Otto, Jan-Christoph

2016-04-01

The ongoing glacier retreat exposes a large number of surface depressions in the former glacier bed that can be filled with water or act as sediment traps. This has already been observed at various sites in Austria and in other mountain areas worldwide. The formation of glacial lakes can constitute an important environmental and socio-economic impact on high mountain systems including water resource management, sediment delivery, natural hazards, energy production and tourism. In general, information on ice thickness distribution is the basis for simulating future glacier change. We used the approach proposed by Huss and Farinotti (2012) to model the ice thickness distribution and potential locations of subglacial depressions. The study is part of the FUTURELAKE project that seeks to model the formation of new glacier lakes and their possible future evolution in the Austria Alps. The required data on glacier extent, surface elevation and slope were taken from the Austrian Glacier Inventories GI1 from 1969, GI2 from 1998 and GI3 from2006 (Fischer et al., 2015). The different glacier outlines and surface elevations from the inventories enable us to evaluate (i) the robustness of the modelled bedrock depressions with respect to different glacier settings, (ii) the power of the model to simulate recently formed glacial lakes, (iii) the similarities in calculated ice thickness distributions across the inventories and (iv) the feasibility of simulating observed changes in ice thickness and glacier volume. In general, the modelled localization of large potential depressions was relatively stable using the observed glacier settings. A number of examples show that recently formed glacial lakes could be detected by the model based on previous glacier extents. The locations of maximum ice depths within different elevation zones appeared to be sensitive to changes in glacier width. However, observed ice thickness changes and, thus, volume changes between the inventories could

Influence of PECVD deposited SiNx passivation layer thickness on In0.18Al0.82N/GaN/Si HEMT

International Nuclear Information System (INIS)

Singh, Sarab Preet; Liu, Yi; Ngoo, Yi Jie; Kyaw, Lwin Min; Bera, Milan Kumar; Chor, Eng Fong; Dolmanan, S B; Tripathy, Sudhiranjan

2015-01-01

The influence of plasma enhanced chemical vapour deposited (PECVD) silicon nitride (SiN x ) passivation film thickness on In 0.18 Al 0.82 N/GaN/Si heterostructures and HEMTs has been investigated. The formation of Si 3 N 4 was confirmed by x-ray photoelectron spectroscopy (XPS) measurements. X-ray reflectivity (XRR) measurements reveal that both the density and roughness of the SiN x film increase with increasing film thickness. With an increase in SiN x film thickness, a significant increase in two-dimensional electron gas (2DEG) density, drain current, extrinsic transconductance and negative threshold voltage shift of the In 0.18 Al 0.82 /GaN/Si HEMTs are observed. An optimal thickness of SiN x is ∼100 nm and it yields a substantial increase in 2DEG density (∼30%) with a minimum sheet resistance for In 0.18 Al 0.82 N/GaN/Si heterostructures. Furthermore, we correlate the observed SiN x film thickness-dependent electrical characteristics of In 0.18 Al 0.82 /GaN/Si HEMTs with the density of the SiN x film. (paper)

Controls of tectonics and sediment source locations on along-strike variations in transgressive deposits on the northern California margin

Science.gov (United States)

Spinelli, G.A.; Field, M.E.

2003-01-01

We identify two surfaces in the shallow subsurface on the Eel River margin offshore northern California, a lowstand erosion surface, likely formed during the last glacial maximum, and an overlying surface likely formed during the most recent transgression of the shoreline. The lowstand erosion surface, which extends from the inner shelf to near the shelfbreak and from the Eel River to Trinidad Head (???80 km), truncates underlying strata on the shelf. Above the surface, inferred transgressive coastal and estuarine sedimentary units separate it from the transgressive surface on the shelf. Early in the transgression, Eel River sediment was likely both transported down the Eel Canyon and dispersed on the slope, allowing transgressive coastal sediment from the smaller Mad River to accumulate in a recognizable deposit on the shelf. The location of coastal Mad River sediment accumulation was controlled by the location of the paleo-Mad River. Throughout the remainder of the transgression, dispersed sediment from the Eel River accumulated an average of 20 m of onlapping shelf deposits. The distribution and thickness of these transgressive marine units was strongly modified by northwest-southeast trending folds. Thick sediment packages accumulated over structural lows in the lowstand surface. The thinnest sediment accumulations (0-10 m) were deposited over structural highs along faults and uplifting anticlines. The Eel margin, an active margin with steep, high sediment-load streams, has developed a thick transgressive systems tract. On this margin sediment accumulates as rapidly as the processes of uplift and downwarp locally create and destroy accommodation space. Sequence stratigraphic models of tectonically active margins should account for variations in accommodation space along margins as well as across them. ?? 2003 Elsevier Science B.V. All rights reserved.

Morphometric measurement of submucosal thickness in areas of fat deposition in the terminal ileum and colonic sections, with correlation with body mass index, weight and age: a male autopsy study.

Science.gov (United States)

Mesa, Hector; Drawz, Sarah; Dykoski, Richard; Manivel, Juan Carlos

2015-10-01

An increased amount of submucosal (SM) fat in the colon on imaging is considered to be characteristic of inflammatory bowel disease (IBD); however, a recent study in patients without IBD reported a correlation between colonic SM fat deposition and body weight (BW). The aim of this study was to perform a morphometric investigation of SM thickness in areas of fat deposition in the terminal ileum (TI), ileocaecal valve (ICV), and colonic sections, to determine whether there are variations by site, and whether it shows a correlation with BW, body mass index (BMI), or age. Representative samples of TI, ICV and colonic sections were collected prospectively from 115 autopsy cases without IBD. All of the study subjects were male (Veterans Hospital). SM thickness was measured in areas of fat deposition. Correlation analysis was performed between SM thickness and BW, BMI, and age. Fat deposition was common; however, with the exception of the ICV, it was neither consistent nor prominent, and it did not show a statistical correlation with BW, BMI, or age. SM fat deposition is common but not uniform or conspicuous in the TI or colon. In contrast to extravisceral intra-abdominal fat, it does not show a correlation with BW or BMI, and is not associated with ageing. As all study subjects were male, gender-dependent variability cannot be excluded. © 2015 John Wiley & Sons Ltd.

Characterization of 13 and 30 μm thick hydrogenated amorphous silicon diodes deposited over CMOS integrated circuits for particle detection application

International Nuclear Information System (INIS)

Despeisse, M.; Anelli, G.; Commichau, S.; Dissertori, G.; Garrigos, A.; Jarron, P.; Miazza, C.; Moraes, D.; Shah, A.; Wyrsch, N.; Viertel, G.

2004-01-01

We present the experimental results obtained with a novel monolithic silicon pixel detector which consists in depositing a n-i-p hydrogenated amorphous silicon (a-Si:H) diode straight above the readout ASIC (this technology is called Thin Film on ASIC, TFA). The characterization has been performed on 13 and 30 μm thick a-Si:H films deposited on top of an ASIC containing a linear array of high-speed low-noise transimpedance amplifiers designed in a 0.25 μm CMOS technology. Experimental results presented have been obtained with a 600 nm pulsed laser. The results of charge collection efficiency and charge collection speed of these structures are discussed

The last glacial cycle documented on the Lower Bengal Fan - chronological and paleoclimate implications

Science.gov (United States)

Weber, M. E.; Dekens, P.; Reilly, B.; Lantzsch, H.; Selkin, P. A.; Das, S. K.; Williams, T.; Martos, Y. M.; Adhikari, R. R.; Gyawali, B. R.; Jia, G.; Fox, L. R.; Ge, J.; Manoj, M. C.; Savian, J. F.; Meynadier, L.; Spiess, V.; France-Lanord, C.; Klaus, A.

2016-12-01

IODP Expedition 354 set out in February to March 2015 to drill seven sites along an east west oriented core transect of 320 km length at 8°N in the Bengal Fan (France-Lanord et al., 2015). Sediments show complex intercalation of turbiditic and hemipelagic deposits, documenting the interaction of fan evolution and paleoceanographic history. Hemipelagic sequences represent a several meter thick top layer of Late Quaternary sediment. Deposits are either rich in biogenic opal/clay or in carbonate. We studied physical, optical, geochemical, grain-size, and stable isotopic properties of this top layer to establish a time frame, estimate sedimentary properties, and assess the development of the region during the last glacial cycle. For this purpose, we sampled Site U1452C-1H continuously for the uppermost 480 cm in 2-cm increments. Preliminary results indicate the Toba Ash 1 (74 ka) is a distinct time marker in most physical property data sets. Records of wet-bulk density as well as color reflectance b* (the red-green component) and L* (the lightness) show a dominant precession cyclicity. Hence, we are able to provide an insolation-tuned chronology for the last 200 ka (MIS1 - 7). These records agree well with d18O records retrieved from Chinese caves. An independent age model is derived from records of relative paleointensity (RPI), including the assessment of the Laschamp Event ( 40 ka), and on RPI tuning to global templates. We will compare both chronologies and evaluate their chronological and paleoclimatic implications. We will also present preliminary grain-size and paleoceanographic proxy data (sea-surface temperature, sea-surface salinity, and Mg/Ca) as well as color endmember modeling to reconstruct ice volume, marine biological productivity, nutrient supply, and deep-water circulation. The sedimentologic, oceanographic and climatic conditions are linked to changes in monsoonal strength and terrestrial input, which will also be studied using sedimentary proxies

Glacial conditions in the Red Sea

Science.gov (United States)

Rohling, Eelco J.

1994-10-01

In this paper, results from previous studies on planktonic foraminifera, δ18O, and global sea level are combined to discuss climatic conditions in the Red Sea during the last glacial maximum (18,000 B.P.). First, the influence of 120-m sea level lowering on the exchange transport through the strait of Bab-el-Mandab is considered. This strait is the only natural connection of the Red Sea to the open ocean. Next, glacial Red Sea outflow salinity is estimated (about 48 parts per thousand) from the foraminiferal record. Combined, these results yield an estimate of the glacial net water deficit, which appears to have been quite similar to the present (about 2 m yr-1). Finally, budget calculation of δ18O fluxes suggests that the glacial δ18O value of evaporation was about 50% of the present value. This is considered to have resulted from substantially increased mean wind speeds over the glacial Red Sea, which would have caused a rapid drop in the kinematic fractionation factor for 18O. The sensitivity of the calculated values for water deficit and isotopic fractionation to the various assumptions and estimates is evaluated in the discussion. Improvents are to be expected especially through research on the glacial salinity contrast between the Red Sea and Gulf of Aden. It is argued, however, that such future improvement will likely result in a worsening of the isotopic discrepancy, thus increasing the need for an additional mechanism that influenced fractionation (such as mean wind speed). This study demonstrates the need for caution when calculating paleosalinities from δ18O records under the assumption that the modern S∶δ18O relation has remained constant through time. Previously overlooked factors, such as mean wind speed, may have significantly altered that relation in the past.

Glacial rebound and crustal stress in Finland

International Nuclear Information System (INIS)

Lambeck, K.; Purcell, A.

2003-11-01

The last ice age of Fennoscandinavia continues to have geological repercussions across Finland despite the last ice having retreated almost 10,000 years ago: land uplift, shoreline retreat, and the stress state of the crust continues to evolve. This report focusses on the glacial rebound signals for Finland and the Gulf of Bothnia and explores the consequences of the ongoing deformation. The rebound signals include the geological evidence as well as instrumental observations: the tide gauge and lake-level measurements of the past century, the changes in geodetic levels recorded in the repeat levelling surveys of the region and the direct measurement of crustal deformation (radial and horizontal) using high-precision space-geodesy measurements. These signals provide constraints on the Earth's rheology, its elasticity and viscosity, and the glacial history of the region. Once observationally constrained, the rebound models are used to predict both the ongoing evolution of shorelines and the changing state of stress within the crust. This report covers: (i) A review of glacial rebound modelling for Scandinavia (Sections 2 and 3). (ii) Review of observational evidence relating to sea-level change and crustal rebound (Section 4). (iii) New earth and ice-sheet model results from the inversion of the geological evidence for sea-level change, including models of shoreline evolution (Sections 5 and 6). (iv) Earth-model results from the inversion of the geodetic evidence for sea-level change (Section 7). (v) Development of crustal stress models for past and present stress states (Section 8). (vi) Conclusions and recommendations (Section 9). Specific conclusions reached pertain to: (i) Thickness of ice cover over Scandinavia since the Last Glacial Maximum, particularly for the Lateglacial period. (ii) Sea-level change and shoreline evolution for the Baltic area since the time the region became ice-free for the last time. (iii) The predicted rates of present-day crustal

Photoluminescence properties of poly (p-phenylene vinylene) films deposited by chemical vapor deposition

International Nuclear Information System (INIS)

Gedelian, Cynthia A.; Rajanna, K.C.; Premerlani, Brian; Lu, Toh-Ming

2014-01-01

Photoluminescence spectra of PPV at varying thicknesses and temperatures have been studied. A study of the quenching of the polymer film using a modified version of fluorescence spectroscopy reveals interface effects dominating at thicknesses below about 600 Å, while bulk effects dominate at higher thicknesses. The application of the Stern–Volmer equation to solid film is discussed. Stern–Volmer plots were nonlinear with downward deviations at higher thickness of the film which was explained due to self-quenching in films and larger conformational change and increased restriction from change in electron density due to electron transition during excitation in bulk polymer films over 60 nm thick. PPV deposited into porous (∼4 nm in diameter) nanostructured substrate shows a larger 0–0 than 0–1 transition peak intensity and decreased disorder in the films due to structure imposed by substrate matrix. Temperature dependent effects are measured for a film at 500 Å, right on the border between the two areas. PPV films deposited on porous methyl silsesquioxane (MSQ) were also examined in order to compare the flat film to a substrate that allows for the domination of interface effects. The enthalpies of the first two peaks are very similar, but the third peak demonstrates a lower enthalpy and a larger wavelength shift with temperature. Films deposited inside pores show a smaller amount of disorder than flat films. Calculation of the Huang–Rhys factor at varying temperatures for the flat film and film in porous MSQ shows large temperature dependence for the flat film but a smaller amount of disorder in the nanostructured film. -- Highlights: • Poly (p-phenylene vinylene) films deposited by chemical vapor deposition exhibited photoluminescence properties. • Fluorescence spectra of the polymer films revealed interface effects dominating at thicknesses below about 600 Å, while bulk effects dominate at higher thicknesses. • Stern–Volmer plots were

Late-glacial to Holocene aeolian deposition in northeastern Europe - The timing of sedimentation at the Iisaku site (NE Estonia)

DEFF Research Database (Denmark)

Kalinska-Nartisa, Edyta; Nartiss, Maris; Thiel, Christine

2015-01-01

The Late-glacial and Holocene aeolian inland dune complex at Iisaku (NE Estonia) has been investigated using an accurate and detailed compilation of the sedimentary properties and chronological framework. The quartz grains forming the dunes are very variable, reflecting aeolian, weathering...

LGM permafrost thickness and extent in the Northern Hemisphere derived from the earth system model iLOVECLIM

NARCIS (Netherlands)

Kitover, D.C.; van Balen, R.T.; Vandenberghe, J.F.; Roche, D.M.V.A.P.; Renssen, H.

2016-01-01

An estimate of permafrost extent and thickness in the northern hemisphere during the Last Glacial Maximum (LGM, ~ 21 ka) has been produced using the VU University Amsterdam Permafrost Snow (VAMPERS) model, forced by iLOVECLIM, an Earth System Model of Intermediate Complexity. We present model

Eruption and emplacement dynamics of a thick trachytic lava flow of the Sancy volcano (France)

Science.gov (United States)

Latutrie, Benjamin; Harris, Andrew; Médard, Etienne; Gurioli, Lucia

2017-01-01

A 70-m-thick, 2200-m-long (51 × 106 m3) trachytic lava flow unit underlies the Puy de Cliergue (Mt. Dore, France). Excellent exposure along a 400-m-long and 60- to 85-m-high section allows the flow interior to be accessed on two sides of a glacial valley that cuts through the unit. We completed an integrated morphological, structural, textural, and chemical analysis of the unit to gain insights into eruption and flow processes during emplacement of this thick silicic lava flow, so as to elucidate the chamber and flow dynamic processed that operate during the emplacement of such systems. The unit is characterized by an inverse chemical stratification, where there is primitive lava beneath the evolved lava. The interior is plug dominated with a thin basal shear zone overlying a thick basal breccia, with ramping affecting the entire flow thickness. To understand these characteristics, we propose an eruption model that first involves processes operating in the magma chamber whereby a primitive melt is injected into an evolved magma to create a mixed zone at the chamber base. The eruption triggered by this event first emplaced a trachytic dome, into which banded lava from the chamber base was injected. Subsequent endogenous dome growth led to flow down the shallow slope to the east on which the highly viscous (1012 Pa s) coulée was emplaced. The flow likely moved extremely slowly, being emplaced over a period of 4-10 years in a glacial manner, where a thick (>60-m) plug slid over a thin (5-m-thick) basal shear zone. Excellent exposure means that the Puy de Cliergue complex can be viewed as a case type location for understanding and defining the eruption and emplacement of thick, high-viscosity, silicic lava flow systems.

The Thickness Dependence of Optical Constants of Ultrathin Iron Films

International Nuclear Information System (INIS)

Gao Shang; Lian Jie; Wang Xiao; Li Ping; Sun Xiao-Fen; Li Qing-Hao

2013-01-01

Ultrathin iron films with different thicknesses from 7.1 to 51.7 nm are deposited by magnetron sputtering and covered by tantalum layers protecting them from being oxidized. These ultrathin iron films are studied by spectroscopic ellipsometry and transmittance measurement. An extra tantalum film is deposited under the same sputtering conditions and its optical constants and film thickness are obtained by a combination of ellipsometry and transmission measurement. After introducing these obtained optical constants and film thickness into the tantalum-iron film, the optical constants and film thicknesses of ultrathin iron films with different thicknesses are obtained. The results show that combining ellipsometry and transmission measurement improves the uniqueness of the obtained film thickness. The optical constants of ultrathin iron films depend strongly on film thicknesses. There is a broad absorption peak at about 370 nm and it shifts to 410 nm with film thickness decreasing

Erosion and filling of glacially-overdeepened troughs in the Northern Alpine Foreland as recorded in a deep drill core from Northern Switzerland

Science.gov (United States)

Dehnert, Andreas; Axel Kemna, Hans; Anselmetti, Flavio; Drescher-Schneider, Ruth; Graf, Hans Rudolf; Lowick, Sally; Preusser, Frank; Züger, Andreas; Furrer, Heinz

2010-05-01

As the major weather divide in Europe, the Alps represent one of the most interesting areas for understanding past climate change and its impact on continental environments. However, our knowledge of the Quaternary environmental history of the region is still rather limited, especially for the time preceding the last glaciation of the Alps. Geological and geophysical studies in the Wehntal, 20 km northwest of Zurich, Switzerland, in 2007 and 2008 have revealed the existence of a glacially overdeepened trough cut into Miocene molasse bedrock, which is today filled with ~90 to 180 m of Pleistocene sediments. In March 2009, a 93.6 m long sediment core (NW09/1) has been drilled east of the famous mammoth-site Niederweningen. This record is one of the very few sites in the northern Alpine Foreland that provides crucial insights into the timing of the erosion and infilling history of pre-Eemian glacially overdeepened troughs and also helps to understand the climate and environmental history. Based on chronological data deduced from the nearby, but shorter, 2007 core and on new multi-proxy data, the NW09/1 record is interpreted as: 4.1 m of in-situ molasse bedrock, overlain by 3.4 m of diamictic till. These glacial deposits were deposited by a Linth glacier lobe during Marine Isotope Stage (MIS) 6 (Rissian), although, the possibility that an even older glaciation was responsible cannot currently be excluded (e.g. MIS 8, luminescence dating, pollen interpretations, and palaeomagnetic studies in progress). It is suggested that this extensive ice advance, which once covered the entire Wehntal valley, caused the final erosion of the bedrock. The till is overlain by a 29.5 m thick sequence of laminated, carbonate-rich, fine-grained siliciclastic sediments that are interpreted as proglacial lake sediments. It is supposed that this unit was deposited in a proximal setting to a calving glacier-front confirmed by the presence of numerous dropstones. The damming of this Wehntal

Post-glacial rock avalanches in the Obersee Valley, Glarner Alps, Switzerland

Science.gov (United States)

Nagelisen, Jan; Moore, Jeffrey R.; Vockenhuber, Christoph; Ivy-Ochs, Susan

2015-06-01

The geological record of prehistoric rock avalanches provides invaluable data for assessing the hazard posed by these rare but destructive mass movements. Here we investigate two large rock avalanches in the Obersee valley of the Glarner Alps, Switzerland, providing detailed mapping of landslide and related Quaternary phenomena, revised volume estimates for each event, and surface exposure dating of rock avalanche deposits. The Rautispitz rock avalanche originated from the southern flank of the Obersee valley, releasing approximately 91 million m3 of limestone on steeply-dipping bedding planes. Debris had maximum horizontal travel distance of ~ 5000 m, a fahrboeschung angle (relating fall height to length) of 18°, and was responsible for the creation of Lake Obersee; deposits are more than 130 m thick in places. The Platten rock avalanche encompassed a source volume of 11 million m3 sliding from the northern flank of the Obersee valley on similar steeply-dipping limestone beds (bedrock forms a syncline under the valley). Debris had a maximum horizontal travel distance of 1600 m with a fahrboeschung angle of 21°, and is more than 80 m thick in places. Deposits of the Platten rock avalanche are superposed atop those from the Rautispitz event at the end of the Obersee valley where they dam Lake Haslensee. Runout for both events was simulated using the dynamic analysis code DAN3D; results showed excellent match to mapped deposit extents and thickness and helped confirm the hypothesized single-event failure scenarios. 36Cl cosmogenic nuclide surface exposure dating of 13 deposited boulders revealed a Younger Dryas age of 12.6 ± 1.0 ka for the Rautispitz rock avalanche and a mid-Holocene age of 6.1 ± 0.8 ka for the Platten rock avalanche. A seismological trigger is proposed for the former event due to potentially correlated turbidite deposits in nearby Lake Zurich.

Measurement of the thickness of a target deposited in a substrate; Medicion del grosor de un blanco depositado en un substrato

Energy Technology Data Exchange (ETDEWEB)

Martinez Q, E.; Aguilera, E.F

1990-12-15

Being based on the Elastic scattering and in the Energy losses that suffer a projectile to the interacting with the matter, a method that allows to determine the thickness of a target deposited in a more heavy substrate is presented. The obtained results are consistent with that waited and the derived errors of the method are small. The used technique allows to reduce in considerable form the systematic errors coming from the calibration of the equipment. It is considered that this method is applicable in an interval of thickness quite wide and for many materials since it is only necessary to choose the projectile type and the energy of the same one appropriately. (Author)

The glacial record of New Zealand's Southern Alps

Science.gov (United States)

Schaefer, J. M.; Denton, G.; Lowell, T.; Anderson, B.; Rinterknecht, V.; Schlosser, P.; Ivy-Ochs, S.; Kubik, P.; Schluechter, C.; Chinn, T.; Barrell, D.; Lifton, N.; Jull, T.

2004-12-01

We present detailed mapping and surface exposure dating using in-situ Be-10 and C-14 of the moraine set of Lake Pukaki, New Zealand's Southern Alps, spanning from the penultimate glaciation, over several Last Glacial Maximum (LGM) moraines, the late glacial event to Holocene glacial advances. New Zealand, a mountain ridge in the middle of the Southern Ocean, has one of the best preserved moraine records world-wide, offering the opportunity to reconstruct amplitude and timing of climate changes from Southern mid-latitudes, an area where paleoclimate data is scarce. The extensive mapping effort by G. Denton and colleagues (http://wyvern.gns.cri.nz/website/csigg/) provides a unique background for sample selection for Surface Exposure Dating. Our extensive data set (>40 samples analyzed so far) indicate that (i) the LGM in New Zealand terminated clearly prior to the Boelling/Alleroed warming, (ii) the late glacial advance is within uncertainties consistent with the timing of the Younger Dryas cold reversal; (iii) there occurred an early Holocene glacial event of the same amplitude than the Little Ice Age. This latter event is the first Holocene glacial event from the Southern Hemisphere dated by in-situ Be-10 and C-14.

Phylogeographic insights into cryptic glacial refugia.

Science.gov (United States)

Provan, Jim; Bennett, K D

2008-10-01

The glacial episodes of the Quaternary (2.6 million years ago-present) were a major factor in shaping the present-day distributions of extant flora and fauna, with expansions and contractions of the ice sheets rendering large areas uninhabitable for most species. Fossil records suggest that many species survived glacial maxima by retreating to refugia, usually at lower latitudes. Recently, phylogeographic studies have given support to the existence of previously unknown, or cryptic, refugia. Here we summarise many of these insights into the glacial histories of species in cryptic refugia gained through phylogeographic approaches. Understanding such refugia might be important as the Earth heads into another period of climate change, in terms of predicting the effects on species distribution and survival.

A synthesis of post-glacial diatom records from Lake Baikal

Science.gov (United States)

Bradbury, J. Platt; Bezrukova, E.; Chernyaeva, G.; Colman, S.M.; Khursevich, G.; King, J.W.; Likoshway, Ye. V.

1994-01-01

glacial periods, the deep basin sediments of Lake Baikal are dominated by rapidly deposited clastics entering from large rivers with possibly glaciated headwaters. On the sublacustrine Academician Ridge (depth = 300 m), however, detailed analysis of the diatom biostratigraphy indicates that diastems (hiatuses of minor duration) and (or) highly variable rates of accumulation complicate paleolimnologic and paleoclimatic reconstructions from these records.

Late Glacial and Holocene gravity deposits in the Gulf of Lions deep basin, Western Mediterranean

Science.gov (United States)

Dennielou, B.; Bonnel, C.; Sultan, N.; Voisset, M.; Berné, S.; Beaudouin, C.; Guichard, F.; Melki, T.; Méar, Y.; Droz, L.

2003-04-01

Recent investigations in the Gulf of Lions have shown that complex gravity processes and deposits occurred in the deep basin since the last Glacial period. Besides the largest western Mediterranean turbiditic system, Petit-Rhône deep-sea fan (PRDSF), whose built-up started at the end of Pliocene, several sedimentary bodies can be distinguished: (1) The turbiditic Pyreneo-Languedocian ridge (PLR), at the outlet of the Sète canyon network, whose activity is strongly connected to the sea level and the connection of the canyons with the rivers. It surface shows long wave-length sediment waves, probably in relation with the turbiditic overspill. (2) An acoustically chaotic unit, filling the topographic low between the PRDSF and the PLR, the Lower Interlobe Unit. Possible source areas are the Sète canyon and/or the Marti Canyon. (3) An acoustically transparent unit, below the neofan, filling the same topographic low, the Western Transparent Unit, interpreted as a debris-flow. Recent sediment cores have shown that this sedimentary is composed of folded, laminated mud, both in its northern and southern fringes. (4) The Petit-Rhône neofan, a channelized turbiditic lobe resulting from the last avulsion of the Petit-Rhône turbiditic channel and composed of two units. The lower, acoustically chaotic facies unit, corresponding to an initial stage of the avulsion, similar to the HARP facies found on the Amazon fan. The upper, transparent, slightly bedded, channel-levee shaped unit, corresponding to the channelized stage of the avulsion. (5) Up to ten, Deglacial to Holocene, thin, fine sand layers, probably originating from shelf-break sand accumulations, through the Sète canyon network. (6) Giant scours, in the southern, distal part of the neofan, possibly linked to turbiditic overflow from the neo-channel, probably corresponding to channel-lobe transition zone features (Wynn et al. 2002). Recent investigations have shown no evidence of bottom current features.

Timing of lake-level changes for a deep last-glacial Lake Missoula: optical dating of the Garden Gulch area, Montana, USA

Science.gov (United States)

Smith, Larry N.; Sohbati, Reza; Buylaert, Jan-Pieter; Lian, Olav B.; Murray, Andrew; Jain, Mayank

2018-03-01

Glaciolacustrine sediments in the Clark Fork River valley at Garden Gulch, near Drummond, Montana, USA record highstand positions of the ice-dammed glacial Lake Missoula and repeated subaerial exposure. During these highstands the lake was at greater than 65% of its recognized maximum capacity. The initial lake transgression deposited a basal sand unit. Subsequent cycles of lake-level fluctuations are recorded by sequences of laminated and cross laminated silt, sand, and clay deformed by periglacial processes during intervening periods of lower lake levels. Optically stimulated luminescence (OSL) dating of quartz sand grains, using single-aliquot regenerative-dose procedures, was carried out on 17 samples. Comparison of infrared stimulated luminescence (IRSL) from K-rich feldspar to OSL from quartz for all the samples suggests that they were well bleached prior to deposition and burial. Ages for the basal sand and overlying glaciolacustrine exposure surfaces are indistinguishable within one standard deviation, and give a weighted mean age of 20.9 ± 1.3 ka (n = 11). Based on sedimentological and stratigraphic analysis we infer that the initial transgression, and at least six cycles of lake-level fluctuation, occurred over time scales of decades to ∼2 ka. Bioturbated sandy slopewash dated at 10.6 ± 0.9 ka and 11.9 ± 1.2 ka unconformably overlies the upper glaciolacustrine deposits. The uppermost sediments, above the glaciolacustrine section, are younger than the Glacier Peak tephra (13.7-13.4 cal ka B.P.), which was deposited across parts of the drained lake basin, but has not been found at Garden Gulch. Our study indicates that glacial Lake Missoula reached >65 percent of maximum capacity by about 20.9 ± 1.3 ka and either partially or completely drained twelve times from this position. Rapid lowering from the lake's highstand position due to ice-dam failure likely led to scour in the downstream portions of the glacial Lake Missoula basin and megafloods in the

Control of Alq3 wetting layer thickness via substrate surface functionalization.

Science.gov (United States)

Tsoi, Shufen; Szeto, Bryan; Fleischauer, Michael D; Veinot, Jonathan G C; Brett, Michael J

2007-06-05

The effects of substrate surface energy and vapor deposition rate on the initial growth of porous columnar tris(8-hydroxyquinoline)aluminum (Alq3) nanostructures were investigated. Alq3 nanostructures thermally evaporated onto as-supplied Si substrates bearing an oxide were observed to form a solid wetting layer, likely caused by an interfacial energy mismatch between the substrate and Alq3. Wetting layer thickness control is important for potential optoelectronic applications. A dramatic decrease in wetting layer thickness was achieved by depositing Alq3 onto alkyltrichlorosilane-derivatized Si/oxide substrates. Similar effects were noted with increasing deposition rates. These two effects enable tailoring of the wetting layer thickness.

Aerial gamma ray and magnetic survey: Minnesota Project, Thief River Falls quadrangle of Minnesota/North Dakota. Final report

International Nuclear Information System (INIS)

1979-11-01

The Thief River Falls 1:250,000 scale quadrangle of Minnesota and North Dakota is almost everywhere covered with Wisconsin age glacial deposits (drift, lake sediments, etc.) of variable thickness. Where exposed, bedrock is Late Cretaceous age marine deposits. There are no uranium deposits (or occurrences) known within the quadrangle. Sixty-six groups of uranium samples were defined as anomalies and are discussed briefly. None of them are considered significant

The Permo-Triassic uranium deposits of Southern Africa within the African-South American Gondwana framework

International Nuclear Information System (INIS)

Toens, P.D.; Le Roux, J.P.

1981-01-01

The discovery of uranium in the Permo-Triassic Gondwana in South America and Africa has served to highlight the intercontinental correlations. The purpose here is to examine the uranium deposits of Southern Africa in the light of the similarities that exist between the various Gondwana formations of the two continents. This hopefully will assist in gaining some understanding of the genesis of the uranium mineralization and the sedimentary environment in which such deposits are likely to occur. Between the Upper Carboniferous and the Jurassic a tectono-sedimentary terrain existed within Gondwanaland in which broadly similar conditions prevailed over large areas, thus producing numerous partly disconnected basins practically identical in character. The basal formations are composed of glacial tillite followed by a succession of sandstone and shale which attains a thickness of up to 12,000 m. Sedimentological studies confirm that major source areas composed largely of granitic and metamorphic rocks existed to the north and south of central South America and Southern Africa, as also in the divides between the basins. Uranium mineralization occurs sporadically throughout the succession and is usually restricted to palaeoriver channels containing carbon trash. There has been little subsequent enrichment and the Colorado model does not apply. With a few exceptions, the deposits tend to have a low overall uranium tenor and individual deposits are usually not very extensive in size. Collectively, however, they may eventually assume some importance. Uraniferous coals have been recorded from a number of localities and it is suggested that the significance of these deposits has as yet not been fully appreciated or investigated. (author)

Thickness effect on the microstructure, morphology and optoelectronic properties of ZnS films

International Nuclear Information System (INIS)

Prathap, P; Revathi, N; Subbaiah, Y P Venkata; Reddy, K T Ramakrishna

2008-01-01

Thin films of ZnS with thicknesses ranging from 100 to 600 nm have been deposited on glass substrates by close spaced thermal evaporation. All the films were grown at the same deposition conditions except the deposition time. The effect of thickness on the physical properties of ZnS films has been studied. The experimental results indicated that the thickness affects the structure, lattice strain, surface morphology and optoelectronic properties of ZnS films significantly. The films deposited at a thickness of 100 nm showed hexagonal structure whereas films of thickness 300 nm or more showed cubic structure. However, coexistence of both cubic and hexagonal structures was observed in the films of 200 nm thickness. The surface roughness of the films showed an increasing trend at higher thicknesses of the films. A blue-shift in the energy band gap along with an intense UV emission band was observed with the decrease of film thickness, which are ascribed to the quantum confinement effect. The behaviour of optical constants such as refractive index and extinction coefficient were analysed. The variation of refractive index and extinction coefficient with thickness was explained on the basis of the contribution from the packing density of the layers. The electrical resistivity as well as the activation energy were evaluated and found to decrease with the increase of film thickness. The thickness had a significant influence on the optical band gap as well as the luminescence intensity

The late Pleistocene glacial sequence in the middle Maruia valley, southeast Nelson, New Zealand

International Nuclear Information System (INIS)

Mabin, M.C.G.

1983-01-01

Glacial and fluvioglacial landforms and deposits preserved in the middle reaches of the Maruia valley, southeast Nelson, New Zealand, record the activity of the Maruia glacier during the late Pleistocene Otira Glaciation. Five advances are recognised, from oldest to youngest: Creighton 1, 2, 3, and the Reid Stream 1, 2 advances. There was an interstadial interval between the Creighton 3 and Reid Stream 1 advances. The Reid Stream 1 advance occurred shortly after 14 800 years B.P. (NZ536, old T/sub 0.5/). (auths)

Stress evolution and fault stability during the Weichselian glacial cycle

International Nuclear Information System (INIS)

Lund, Bjoern; Schmidt, Peter; Hieronymus, Christoph

2009-01-01

In this report we examine how the waxing and waning of an ice sheet during a glacial cycle affects the state of stress in the Earth, and how those changes in stress influence the stability of faults. We focus on the stresses at repository depth in Forsmark and Oskarshamn, and on the stability field at seismogenic depth at the proposed repository sites and at the Paervie endglacial fault in northern Sweden. This study is a modelling study, where we use three-dimensional ice and earth models to calculate the glacial isostatic adjustment (GIA), i.e. the response of the Earth to an ice load, examining both displacements and stresses. We use a flat-earth finite element approach, based on Wu with some modifications. The result presented here is a continuation of previous studies in two dimensions and complement those studies in assessing how the three-dimensionality of the problem affects the conclusions. We use the Fennoscandian ice model of Naeslund, which is a dynamic ice sheet model based on climate reconstructions with constraints from geological observations. The ice model spans the entire Weichselian glaciation but we only use the last 68 kyr, which includes the two major periods of ice cover as depicted in this ice sheet reconstruction. For the GIA calculation we use a number of different earth models, both with flat horizontal layers and with various 3D structures of lithosphere thickness. We do not include lateral variations in the viscosity of the mantle. Comparing the current day rebound velocities predicted by our models with GPS observations from the BIFROST project, we note that in general, we can obtain a reasonable fit to the observations with our models, and that the results are rather sensitive to the assumed viscosity of the mantle. We also find that the differences between data and model results, for all earth models, have common features which we interpret as due to the ice model. These observations are in agreement with numerous other GIA studies

Stratigraphic reconstruction of two debris avalanche deposits at Colima Volcano (Mexico): Insights into pre-failure conditions and climate influence

Science.gov (United States)

Roverato, M.; Capra, L.; Sulpizio, R.; Norini, G.

2011-10-01

Throughout its history, Colima Volcano has experienced numerous partial edifice collapses with associated emplacement of debris avalanche deposits of contrasting volume, morphology and texture. A detailed stratigraphic study in the south-eastern sector of the volcano allowed the recognition of two debris avalanche deposits, named San Marcos (> 28,000 cal yr BP, V = ~ 1.3 km 3) and Tonila (15,000-16,000 cal yr BP, V = ~ 1 km 3 ). This work sheds light on the pre-failure conditions of the volcano based primarily on a detailed textural study of debris avalanche deposits and their associated pyroclastic and volcaniclastic successions. Furthermore, we show how the climate at the time of the Tonila collapse influenced the failure mechanisms. The > 28,000 cal yr BP San Marcos collapse was promoted by edifice steep flanks and ongoing tectonic and volcanotectonic deformation, and was followed by a magmatic eruption that emplaced pyroclastic flow deposits. In contrast, the Tonila failure occurred just after the Last Glacial Maximum (22,000-18,000 cal BP) and, in addition to the typical debris avalanche textural characteristics (angular to sub-angular clasts, coarse matrix, jigsaw fit) it shows a hybrid facies characterized by debris avalanche blocks embedded in a finer, homogenous and partially cemented matrix, a texture more characteristic of debris flow deposits. The Tonila debris avalanche is directly overlain by a 7-m thick hydromagmatic pyroclastic succession. Massive debris flow deposits, often more than 10 m thick and containing large amounts of tree trunk logs, represent the top unit in the succession. Fluvial deposits also occur throughout all successions; these represent periods of highly localized stream reworking. All these lines of evidence point to the presence of water in the edifice prior to the Tonila failure, suggesting it may have been a weakening factor. The Tonila failure appears to represent an anomalous event related to the particular climatic

A community-based geological reconstruction of Antarctic Ice Sheet deglaciation since the Last Glacial Maximum

Science.gov (United States)

Bentley, Michael J.; Ó Cofaigh, Colm; Anderson, John B.; Conway, Howard; Davies, Bethan; Graham, Alastair G. C.; Hillenbrand, Claus-Dieter; Hodgson, Dominic A.; Jamieson, Stewart S. R.; Larter, Robert D.; Mackintosh, Andrew; Smith, James A.; Verleyen, Elie; Ackert, Robert P.; Bart, Philip J.; Berg, Sonja; Brunstein, Daniel; Canals, Miquel; Colhoun, Eric A.; Crosta, Xavier; Dickens, William A.; Domack, Eugene; Dowdeswell, Julian A.; Dunbar, Robert; Ehrmann, Werner; Evans, Jeffrey; Favier, Vincent; Fink, David; Fogwill, Christopher J.; Glasser, Neil F.; Gohl, Karsten; Golledge, Nicholas R.; Goodwin, Ian; Gore, Damian B.; Greenwood, Sarah L.; Hall, Brenda L.; Hall, Kevin; Hedding, David W.; Hein, Andrew S.; Hocking, Emma P.; Jakobsson, Martin; Johnson, Joanne S.; Jomelli, Vincent; Jones, R. Selwyn; Klages, Johann P.; Kristoffersen, Yngve; Kuhn, Gerhard; Leventer, Amy; Licht, Kathy; Lilly, Katherine; Lindow, Julia; Livingstone, Stephen J.; Massé, Guillaume; McGlone, Matt S.; McKay, Robert M.; Melles, Martin; Miura, Hideki; Mulvaney, Robert; Nel, Werner; Nitsche, Frank O.; O'Brien, Philip E.; Post, Alexandra L.; Roberts, Stephen J.; Saunders, Krystyna M.; Selkirk, Patricia M.; Simms, Alexander R.; Spiegel, Cornelia; Stolldorf, Travis D.; Sugden, David E.; van der Putten, Nathalie; van Ommen, Tas; Verfaillie, Deborah; Vyverman, Wim; Wagner, Bernd; White, Duanne A.; Witus, Alexandra E.; Zwartz, Dan

2014-09-01

A robust understanding of Antarctic Ice Sheet deglacial history since the Last Glacial Maximum is important in order to constrain ice sheet and glacial-isostatic adjustment models, and to explore the forcing mechanisms responsible for ice sheet retreat. Such understanding can be derived from a broad range of geological and glaciological datasets and recent decades have seen an upsurge in such data gathering around the continent and Sub-Antarctic islands. Here, we report a new synthesis of those datasets, based on an accompanying series of reviews of the geological data, organised by sector. We present a series of timeslice maps for 20 ka, 15 ka, 10 ka and 5 ka, including grounding line position and ice sheet thickness changes, along with a clear assessment of levels of confidence. The reconstruction shows that the Antarctic Ice sheet did not everywhere reach the continental shelf edge at its maximum, that initial retreat was asynchronous, and that the spatial pattern of deglaciation was highly variable, particularly on the inner shelf. The deglacial reconstruction is consistent with a moderate overall excess ice volume and with a relatively small Antarctic contribution to meltwater pulse 1a. We discuss key areas of uncertainty both around the continent and by time interval, and we highlight potential priorities for future work. The synthesis is intended to be a resource for the modelling and glacial geological community.

Influence of deposition rate on the properties of tin coatings deposited on tool steels using arc method

International Nuclear Information System (INIS)

Akhtar, P.; Abbas, M.

2007-01-01

Titanium nitride (TiN) widely used as hard coating material, was coated on tool steels, namely on high-speed steel (HSS) and D2 tool steel by physical vapour deposition method. The study concentrated on cathodic arc physical vapour deposition (CAPVD), a technique used for the deposition of hard coatings for tooling applications, and which has many advantages. The main drawback of this technique, however, is the formation of macrodroplets (MD's) during deposition, resulting in films with rougher morphology. Various standard characterization techniques and equipment, such as electron microscopy, atomic force microscopy, hardness testing machine, scratch tester and pin-on-disc machine, were used to analyze and quantify the following properties and parameters, surface morphology, thickness, hardness, adhesion and coefficient of friction (COF) of the deposited coatings. Surface morphology revealed that the MD's produced during the etching stage, protruded through the thin film, resulting in film with deteriorated surface features. Both coating thickness and indentation loads influenced the hardness of the deposited coatings. The coatings deposited on HSS exhibit better adhesion compared to those on D2 tool steel. Standard deviation indicates that the coating deposited with thickness around 6.7 macro m showed the most stable trend of COF versus sliding distance. (author)

The geochemistry of loess: Asian and North American deposits compared

Science.gov (United States)

Muhs, Daniel R.

2018-01-01

Loess is widely distributed over Asia and North America and constitutes one of the most important surficial deposits that serve as terrestrial records of the Quaternary. The oldest Pleistocene loess in China is likely ∼2.6 Ma, thus spanning much or all of the Pleistocene. In North America, most loess is no older than the penultimate glacial period, with the exception of Alaska, where the record may go back to ∼3.0 Ma. On both continents, loess deposits date primarily to glacial periods, and interglacial or interstadial periods are represented by paleosols. Both glacial and non-glacial sources of silts that comprise the bulk of loess deposits are found on both continents. Although loess has been considered to be representative of the average upper continental crust, there are regionally distinctive compositions of loess in both Asia and North America. Loess deposits in Asia from Yakutia, Tajikistan, and China have compositionally distinct major element compositions, due to varying abundances of silicate minerals, carbonate minerals, and clay minerals. In North America, loess in the Mississippi River valley, the Great Plains, and Alaska are also distinguishable with regard to major element composition that reflects highly diverse source sediments. Trace element geochemistry (Sc-Th-Zr and the rare earth elements) also shows regional diversity of loess bodies, in both Asia and North America. On both continents, most loess bodies show significant contributions from later-cycle, altered sedimentary rocks, as opposed to direct derivation from igneous rocks. Further, some loess bodies have detectable contributions from mafic igneous rocks as well as major contributions from average, upper-crustal, felsic rocks. Intercalated paleosols in loess sections show geochemical compositions that differ significantly from the underlying loess parent materials. Ratios of soluble-to-insoluble elements show depletions in paleosols due to chemical weathering losses of calcite

The geochemistry of loess: Asian and North American deposits compared

Science.gov (United States)

Muhs, Daniel R.

2018-04-01

Loess is widely distributed over Asia and North America and constitutes one of the most important surficial deposits that serve as terrestrial records of the Quaternary. The oldest Pleistocene loess in China is likely ∼2.6 Ma, thus spanning much or all of the Pleistocene. In North America, most loess is no older than the penultimate glacial period, with the exception of Alaska, where the record may go back to ∼3.0 Ma. On both continents, loess deposits date primarily to glacial periods, and interglacial or interstadial periods are represented by paleosols. Both glacial and non-glacial sources of silts that comprise the bulk of loess deposits are found on both continents. Although loess has been considered to be representative of the average upper continental crust, there are regionally distinctive compositions of loess in both Asia and North America. Loess deposits in Asia from Yakutia, Tajikistan, and China have compositionally distinct major element compositions, due to varying abundances of silicate minerals, carbonate minerals, and clay minerals. In North America, loess in the Mississippi River valley, the Great Plains, and Alaska are also distinguishable with regard to major element composition that reflects highly diverse source sediments. Trace element geochemistry (Sc-Th-Zr and the rare earth elements) also shows regional diversity of loess bodies, in both Asia and North America. On both continents, most loess bodies show significant contributions from later-cycle, altered sedimentary rocks, as opposed to direct derivation from igneous rocks. Further, some loess bodies have detectable contributions from mafic igneous rocks as well as major contributions from average, upper-crustal, felsic rocks. Intercalated paleosols in loess sections show geochemical compositions that differ significantly from the underlying loess parent materials. Ratios of soluble-to-insoluble elements show depletions in paleosols due to chemical weathering losses of calcite

Jet grouting for a groundwater cutoff wall in difficult glacial soil deposits

International Nuclear Information System (INIS)

Flanagan, R.F.; Pepe, F. Jr.

1997-01-01

Jet grouting is being used as part of a groundwater cutoff wall system in a major New York City subway construction project to limit drawdowns in an adjacent PCB contamination plume. A circular test shaft of jet grout columns was conducted during the design phase to obtain wall installation parameters. The test program also included shaft wall mapping, and measurements of; inflows, piezometric levels, ground heave and temperature, and jet grout hydraulic conductivity. An axisymmetric finite element method groundwater model was established to back calculate the in-situ hydraulic conductivities of both the surrounding glacial soils and the jet grout walls by matching observed inflows and piezometric levels. The model also verified the use of packer permeability test as a tool in the field to evaluate the hydraulic conductivities of jet grout columns. Both the test program and analytic studies indicated that adjustments to the construction procedures would be required to obtain lower hydraulic conductivities of the jet grout walls for construction. A comparison is made with the conductivities estimated from the test program/analytic studies with those from the present construction

New exposure ages for the Last Glacial Cycle in the Sanabria Lake region (northwestern Spain)

Science.gov (United States)

Rodríguez-Rodríguez, Laura; Jiménez-Sánchez, Montserrat; Domínguez-Cuesta, María Jose; Rinterknecht, Vincent; Pallàs, Raimon; Braucher, Régis; Bourlès, Didier; Valero-Garcés, Blas

2013-04-01

The Sanabria Lake region is located in the Trevinca Massif, a mid-latitude mountain area up to 2128 m asl in the northwest corner of the Iberian Peninsula (42oN 6oW). An ice cap glaciation took place during the Last Glacial Cycle in this massif, with an equilibrium line altitude of 1687 m for the Tera glacial outlet at its local maximum (Cowton et al., 2009). A well preserved glacial sequence occurs on an area of 45 km2 around the present Sanabria Lake (1000 m asl) and is composed by lateral and end moraines in close relationship with glaciolacustrine deposits. This sequence shows the ice snout oscillations of the former Tera glacier during the Last Glacial Cycle and offers a good opportunity to compare radiocarbon and OSL- based chronological models with new cosmogenic isotope dates. The new dataset of 10Be exposure ages presented here for the Sanabria Lake moraines is based on measurements conducted on 23 boulders and is compared with previous radiocarbon and OSL data conducted on ice related deposits (Pérez-Alberti et al., 2011; Rodríguez-Rodríguez et al., 2011). Our results are coherent with the available deglaciation radiocarbon chronology, and support a last deglaciation origin for the whole set of end moraines that are downstream the Sanabria Lake (19.2 - 15.7 10Be ka). Discrepancies between results of the different dating methods concern the timing of the local glacial maximum, with the cosmogenic exposure method always yielding the youngest minimum ages. As proposed to explain similar observations made elsewhere (Palacios et al., 2012), reconciling the ages from different dating methods would imply the occurrence of two glacial advances close enough in extent to generate an overlapping polygenic moraine. Cowton, T., Hughes, P.D., Gibbard, P.L., 2009. Palaeoglaciation of Parque Natural Lago de Sanabria, northwest Spain. Geomorphology 108, 282-291. Rodríguez-Rodríguez, L., Jiménez-Sánchez, M., Domínguez-Cuesta, M.J., Rico, M.T., Valero-Garcés, B

Volcanic CO2 Emissions and Glacial Cycles: Coupled Oscillations

Science.gov (United States)

Burley, J. M.; Huybers, P. J.; Katz, R. F.

2016-12-01

Following the mid-Pleistocene transition, the dominant period of glacial cycles changed from 40 ka to 100 ka. It is broadly accepted that the 40 ka glacial cycles were driven by cyclical changes in obliquity. However, this forcing does not explain the 100 ka glacial cycles. Mechanisms proposed for 100 ka cycles include isostatic bed depression and proglacial lakes destabilising the Laurentide ice sheet, non-linear responses to orbital eccentricity, and Antarctic ice sheets influencing deep-ocean stratification. None of these are universally accepted. Here we investigate the hypothesis that variations in volcanic CO2 emissions can cause 100 ka glacial cycles. Any proposed mechanism for 100 ka glacial cycles must give the Earth's climate system a memory of 10^4 - 10^5years. This timescale is difficult to achieve for surface processes, however it is possible for the solid Earth. Recent work suggests volcanic CO2 emissions change in response to glacial cycles [1] and that there could be a 50 ka delay in that response [2]. Such a lagged response could drive glacial cycles from 40 ka cycles to an integer multiple of the forcing period. Under what conditions could the climate system admit such a response? To address this, we use a simplified climate model modified from Huybers and Tziperman [3]. Our version comprises three component models for energy balance, ice sheet growth and atmospheric CO2 concentration. The model is driven by insolation alone with other components varying according to a system of coupled, differential equations. The model is run for 500 ka to produce several glacial cycles and the resulting changes in global ice volume and atmospheric CO2 concentration.We obtain a switch from 40 ka to 100 ka cycles as the volcanic CO2 response to glacial cycles is increased. These 100 ka cycles are phase-locked to obliquity, lasting 80 or 120 ka. Whilst the MOR response required (in this model) is larger than plausible estimates based on [2], it illustrates the

Early Holocene (8.6 ka) rock avalanche deposits, Obernberg valley (Eastern Alps): Landform interpretation and kinematics of rapid mass movement.

Science.gov (United States)

Ostermann, Marc; Sanders, Diethard; Ivy-Ochs, Susan; Alfimov, Vasily; Rockenschaub, Manfred; Römer, Alexander

2012-10-15

In the Obernberg valley, the Eastern Alps, landforms recently interpreted as moraines are re-interpreted as rock avalanche deposits. The catastrophic slope failure involved an initial rock volume of about 45 million m³, with a runout of 7.2 km over a total vertical distance of 1330 m (fahrböschung 10°). 36 Cl surface-exposure dating of boulders of the avalanche mass indicates an event age of 8.6 ± 0.6 ka. A 14 C age of 7785 ± 190 cal yr BP of a palaeosoil within an alluvial fan downlapping the rock avalanche is consistent with the event age. The distal 2 km of the rock-avalanche deposit is characterized by a highly regular array of transverse ridges that were previously interpreted as terminal moraines of Late-Glacial. 'Jigsaw-puzzle structure' of gravel to boulder-size clasts in the ridges and a matrix of cataclastic gouge indicate a rock avalanche origin. For a wide altitude range the avalanche deposit is preserved, and the event age of mass-wasting precludes both runout over glacial ice and subsequent glacial overprint. The regularly arrayed transverse ridges thus were formed during freezing of the rock avalanche deposits.

Evolution of high-Arctic glacial landforms during deglaciation

Science.gov (United States)

Midgley, N. G.; Tonkin, T. N.; Graham, D. J.; Cook, S. J.

2018-06-01

Glacial landsystems in the high-Arctic have been reported to undergo geomorphological transformation during deglaciation. This research evaluates moraine evolution over a decadal timescale at Midtre Lovénbreen, Svalbard. This work is of interest because glacial landforms developed in Svalbard have been used as an analogue for landforms developed during Pleistocene mid-latitude glaciation. Ground penetrating radar was used to investigate the subsurface characteristics of moraines. To determine surface change, a LiDAR topographic data set (obtained 2003) and a UAV-derived (obtained 2014) digital surface model processed using structure-from-motion (SfM) are also compared. Evaluation of these data sets together enables subsurface character and landform response to climatic amelioration to be linked. Ground penetrating radar evidence shows that the moraine substrate at Midtre Lovénbreen includes ice-rich (radar velocities of 0.17 m ns-1) and debris-rich (radar velocities of 0.1-0.13 m ns-1) zones. The ice-rich zones are demonstrated to exhibit relatively high rates of surface change (mean thresholded rate of -4.39 m over the 11-year observation period). However, the debris-rich zones show a relatively low rate of surface change (mean thresholded rate of -0.98 m over the 11-year observation period), and the morphology of the debris-rich landforms appear stable over the observation period. A complex response of proglacial landforms to climatic warming is shown to occur within and between glacier forelands as indicated by spatially variable surface lowering rates. Landform response is controlled by the ice-debris balance of the moraine substrate, along with the topographic context (such as the influence of meltwater). Site-specific characteristics such as surface debris thickness and glaciofluvial drainage are, therefore, argued to be a highly important control on surface evolution in ice-cored terrain, resulting in a diverse response of high-Arctic glacial landsystems

Glacial isostatic uplift of the European Alps

Science.gov (United States)

Mey, Jürgen; Scherler, Dirk; Wickert, Andrew D.; Egholm, David L.; Tesauro, Magdala; Schildgen, Taylor F.; Strecker, Manfred R.

2016-01-01

Following the last glacial maximum (LGM), the demise of continental ice sheets induced crustal rebound in tectonically stable regions of North America and Scandinavia that is still ongoing. Unlike the ice sheets, the Alpine ice cap developed in an orogen where the measured uplift is potentially attributed to tectonic shortening, lithospheric delamination and unloading due to deglaciation and erosion. Here we show that ∼90% of the geodetically measured rock uplift in the Alps can be explained by the Earth’s viscoelastic response to LGM deglaciation. We modelled rock uplift by reconstructing the Alpine ice cap, while accounting for postglacial erosion, sediment deposition and spatial variations in lithospheric rigidity. Clusters of excessive uplift in the Rhône Valley and in the Eastern Alps delineate regions potentially affected by mantle processes, crustal heterogeneity and active tectonics. Our study shows that even small LGM ice caps can dominate present-day rock uplift in tectonically active regions. PMID:27830704

A tectonically uplifted marine shoreline deposit, Knights Point, Westland, New Zealand

International Nuclear Information System (INIS)

Cooper, A.F.; Kostro, F.

2006-01-01

An 11 m thick subhorizontal beach deposit rests on steeply dipping Cretaceous bedrock. Sediments, ranging from a basal boulder bed to upper sands, are poorly sorted and negatively skewed, indicating pronounced winnowing of fine material. Impact features on quartz grain surfaces attest to high-energy turbulent environments, and are similar to those found on clasts from modern nearby beaches. The Haast River was source to some of the sand and gravel. Heavy minerals from the Dun Mountain Ophiolite Belt were transported 85 km by fluvial/glacial and longshore drift processes, necessitating caution when using apparent lateral separation of source material for estimating strike-slip displacement rates on the Alpine Fault. An optical luminescence age estimate of 123 ± 7 ka for Knights Point beach sands dates to the last interglacial (MIS 5e). A shore-platform altitude of 113 m a.s.l. requires tectonic uplift of the Australian plate of 0.86 mm/yr, an order of magnitude less than the nearby Pacific plate. (author). 66 refs., 6 figs., 3 tabs

Late glacial ice advances in the Strait of Magellan, Southern Chile

Science.gov (United States)

Mcculloch, Robert D.; Bentley, Michael J.

During the last glacial cycle low gradient glaciers repeatedly drained north-eastward into the Strait of Magellan and dammed extensive proglacial lakes in the central section of the strait. This paper focuses on the two most recent glacial advances in the strait, culminating over 150 and 80 km from the present ice limits. The timing of the first of the two advances has, up to now, been ambiguous and depended on the interpretation of anomously older dates of 16,590-15,800 yr BP for deglaciation at Puerto del Hambre. Here, we show there is evidence from seismic data and truncated shorelines that the Puerto del Hambre basin has been tectonically displaced and that the dates do not represent minimums for deglaciation. Several other dates show that the advance occurred sometime before 14,260 yr BP. The timing of the second advance has been investigated using a refined tephrochronology for the region, which has also enabled a palaeoshoreline and glaciolacustrine sediments to be linked to a moraine limit. 14C dating of peat and a key tephra layer, above and below the glaciolacustrine deposits, respectively suggest that the advance culminated in the Strait of Magellan between 12,010 and 10,050 yr BP.

Microstructure of vapor deposited coatings on curved substrates

Energy Technology Data Exchange (ETDEWEB)

Rodgers, Theron M.; Zhao, Hengbei; Wadley, Haydn N. G., E-mail: haydn@virginia.edu [Department of Materials Science and Engineering, University of Virginia, 395 McCormick Rd., P.O. Box 400745, Charlottesville, Virginia 22904 (United States)

2015-09-15

Thermal barrier coating systems consisting of a metallic bond coat and ceramic over layer are widely used to extend the life of gas turbine engine components. They are applied using either high-vacuum physical vapor deposition techniques in which vapor atoms rarely experience scattering collisions during propagation to a substrate, or by gas jet assisted (low-vacuum) vapor deposition techniques that utilize scattering from streamlines to enable non-line-of-sight deposition. Both approaches require substrate motion to coat a substrate of complex shape. Here, direct simulation Monte Carlo and kinetic Monte Carlo simulation methods are combined to simulate the deposition of a nickel coating over the concave and convex surfaces of a model airfoil, and the simulation results are compared with those from experimental depositions. The simulation method successfully predicted variations in coating thickness, columnar growth angle, and porosity during both stationary and substrate rotated deposition. It was then used to investigate a wide range of vapor deposition conditions spanning high-vacuum physical vapor deposition to low-vacuum gas jet assisted vapor deposition. The average coating thickness was found to increase initially with gas pressure reaching a maximum at a chamber pressure of 8–10 Pa, but the best coating thickness uniformity was achieved under high vacuum deposition conditions. However, high vacuum conditions increased the variation in the coatings pore volume fraction over the surface of the airfoil. The simulation approach was combined with an optimization algorithm and used to investigate novel deposition concepts to tailor the local coating thickness.

Microstructure of vapor deposited coatings on curved substrates

International Nuclear Information System (INIS)

Rodgers, Theron M.; Zhao, Hengbei; Wadley, Haydn N. G.

2015-01-01

Thermal barrier coating systems consisting of a metallic bond coat and ceramic over layer are widely used to extend the life of gas turbine engine components. They are applied using either high-vacuum physical vapor deposition techniques in which vapor atoms rarely experience scattering collisions during propagation to a substrate, or by gas jet assisted (low-vacuum) vapor deposition techniques that utilize scattering from streamlines to enable non-line-of-sight deposition. Both approaches require substrate motion to coat a substrate of complex shape. Here, direct simulation Monte Carlo and kinetic Monte Carlo simulation methods are combined to simulate the deposition of a nickel coating over the concave and convex surfaces of a model airfoil, and the simulation results are compared with those from experimental depositions. The simulation method successfully predicted variations in coating thickness, columnar growth angle, and porosity during both stationary and substrate rotated deposition. It was then used to investigate a wide range of vapor deposition conditions spanning high-vacuum physical vapor deposition to low-vacuum gas jet assisted vapor deposition. The average coating thickness was found to increase initially with gas pressure reaching a maximum at a chamber pressure of 8–10 Pa, but the best coating thickness uniformity was achieved under high vacuum deposition conditions. However, high vacuum conditions increased the variation in the coatings pore volume fraction over the surface of the airfoil. The simulation approach was combined with an optimization algorithm and used to investigate novel deposition concepts to tailor the local coating thickness

Interactions between mafic eruptions and glacial ice or snow: implications of the 2010 Eyjafjallajökull, Iceland, eruption for hazard assessments in the central Oregon Cascades

Science.gov (United States)

McKay, D.; Cashman, K. V.

2010-12-01

The 2010 eruption of Eyjafjallajökull, Iceland, demonstrated the importance of addressing hazards specific to mafic eruptions in regions where interactions with glacial ice or snow are likely. One such region is the central Oregon Cascades, where there are hundreds of mafic vents, many of which are Holocene in age. Here we present field observations and quantitative analyses of tephra deposits from recent eruptions at Sand Mountain, Yapoah Cone, and Collier Cone (all advance, which lasted from ~2 to 8 ka in the central Oregon Cascades (Marcott et al., 2009). During the Neoglacial, winter snowfall was likely ~23% greater and summer temperatures ~1.4°C cooler than present (Marcott, 2009). Although ice did not advance to the elevation of the Sand Mountain vents during this time, the eruption could have occurred through several meters of snow. We have also seen very fine-grained tephra at Yapoah Cone, which is located at a higher elevation and may have interacted with glacial ice. In addition to being characterized by unusually fine grainsize, the Yapoah tephra blanket is deposited directly on top of hyaloclastite in several locations. Tephra from Collier Cone is not characterized by unusually fine grainsize, but several sections of the deposit exhibit features that suggest deposition on top of, or interbedding with, snow that later melted away. Identification of features in mafic tephra that suggest interactions with glacial ice or snow has significant implications for regional volcanic hazard assessments. Specifically, the unique hazards posed by Eyjafjallajökull, especially hazards to air travel caused by unusually fine-grained tephra, could be repeated in the Cascades. Although glacial ice is presently limited to elevations above ~2300 m in the central Oregon Cascades, winter snowpack can exceed 5 m at elevations of ~1800 m and above. If a cinder cone eruption were to occur during winter months, interaction with snow could generate phreatomagmatic activity and

Aerial gamma ray and magnetic survey: Minnesota Project, Grand Forks quadrangle of Minnesota/North Dakota. Final report

International Nuclear Information System (INIS)

1979-12-01

The Grand Forks 1:250,000 scale quadrangle of Minnesota and North Dakota is almost everywhere covered with Wisconsin age glacial deposits (drift, lake sediments, etc.) of variable thickness. Where exposed, bedrock is Late Cretaceous age marine deposits. There are no uranium deposits (or occurrences) known within the quadrangle. Seventy-eight (78) groups of uranium samples were defined as anomalies and are discussed briefly in this report. None of them are considered significant

Aerial gamma ray and magnetic survey: Minnesota Project, Fargo quadrangle of Minnesota/North Dakota. Final report

International Nuclear Information System (INIS)

1979-12-01

The Fargo 1:250,000 scale quadrangle of Minnesota and North Dakota is almost everywhere covered with Wisconsin age glacial deposits (drift, lake sediments, etc.) of variable thickness. Where exposed, bedrock is Late Cretaceous age marine deposits. There are no uranium deposits (or occurrences) known within the quadrangle. Eighty-two (82) groups of uranium samples were defined as anomalies and are discussed briefly in this report. None of them are considered significant

Influence of the film thickness on the structure, optical and electrical properties of ITO coatings deposited by sputtering at room temperature on glass and plastic substrates

International Nuclear Information System (INIS)

Guillén, C; Herrero, J

2008-01-01

Transparent and conductive indium tin oxide (ITO) films with thickness between 0.2 and 0.7 µm were deposited by sputtering at room temperature on glass and polyethylene terephthalate (PET) substrates. All films were polycrystalline, with crystallite size increasing and lattice distortion decreasing when the film thickness was increased. Besides, transmission in the near-infrared region is found to be decreasing and carrier concentration increasing when the film thickness was increased. For the same thickness, the lattice distortion is slightly lower and the carrier concentration higher for the layers grown on PET substrates. A direct relationship between the lattice distortion and the free carrier concentration has been established, applying to the films grown on glass and plastic substrates. By adjusting ITO coating thickness, sheet resistance below 15 Ω sq −1 and average visible transmittance about 90% have been achieved by sputtering at room temperature

Stress evolution and fault stability during the Weichselian glacial cycle

Energy Technology Data Exchange (ETDEWEB)

Lund, Bjoern; Schmidt, Peter; Hieronymus, Christoph (Dept. of Earth Sciences, Uppsala Univ., Uppsala (Sweden))

2009-10-15

In this report we examine how the waxing and waning of an ice sheet during a glacial cycle affects the state of stress in the Earth, and how those changes in stress influence the stability of faults. We focus on the stresses at repository depth in Forsmark and Oskarshamn, and on the stability field at seismogenic depth at the proposed repository sites and at the Paervie endglacial fault in northern Sweden. This study is a modelling study, where we use 3-dimensional ice and earth models to calculate the glacial isostatic adjustment (GIA), i.e. the response of the Earth to an ice load, examining both displacements and stresses. We use a flat-earth finite element approach, based on Wu with some modifications. The result presented here is a continuation of previous studies in 2 dimensions and complement those studies in assessing how the 3-dimensionality of the problem affects the conclusions. We use the Fennoscandian ice model of Naeslund, which is a dynamic ice sheet model based on climate reconstructions with constraints from geological observations. The ice model spans the entire Weichselian glaciation but we only use the last 68 kyr, which includes the 2 major periods of ice cover as depicted in this ice sheet reconstruction. For the GIA calculation we use a number of different earth models, both with flat horizontal layers and with various 3D structures of lithosphere thickness. We don't include lateral variations in the viscosity of the mantle. Comparing the current day rebound velocities predicted by our models with GPS observations from the BIFROST project, we note that in general, we can obtain a reasonable fit to the observations with our models, and that the results are rather sensitive to the assumed viscosity of the mantle. We find that the differences between data and model results, for all earth models, have common features which we interpret as due to the ice model. These observations are in agreement with numerous other GIA studies. Our flat

The anthracite of Nazar-Aylok Deposit

International Nuclear Information System (INIS)

Pachadzhanov, D.N.; Valiev, Yu.Ya.

2013-01-01

Present article is devoted to anthracite of Nazar-Aylok Deposit. The ash content, composition of coals of Nazar-Aylok Deposit and thickness of deposit were considered. The coal samples were studied by means of neutron activation analysis.

Modelling and analysis of canister and buffer for earthquake induced rock shear and glacial load

International Nuclear Information System (INIS)

Hernelind, Jan

2010-08-01

Existing fractures crossing a deposition hole may be activated and sheared by an earthquake. The effect of such a rock shear has been investigated by finite element calculations. The buffer material in a deposition hole acts as a cushion between the canister and the rock, which reduces the effect of a rock shear substantially. Lower density of the buffer yields softer material and reduced effect on the canister. However, at the high density that is suggested for a repository the stiffness of the buffer is rather high. The stiffness is also a function of the rate of shear, which means that there may be a substantial damage on the canister at very high shear rates. However, the earthquake induced rock shear velocity is lower than 1 m/s which is not considered to be very high. The rock shear has been modelled with finite element calculations with the code Abaqus. A three dimensional finite element mesh of the buffer and the canister has been created and simulation of a rock shear has been performed. The rock shear has been assumed to take place either perpendicular to the canister at the quarter point or at an inclined angle of 22.5 deg in tension. Furthermore horizontal shear has been studied using a vertical shear plane either at the centre or at 1/4-point for the canister. The shear calculations have been driven to a total shear of 10 cm. The canister also has to be designed to withstand the loads caused by a thick ice sheet. Besides rock shear the model has been used to analyse the effect of such glacial load (either combined with rock shear or without rock shear). This report also summarizes the effect when considering creep in the copper shell

Modelling and analysis of canister and buffer for earthquake induced rock shear and glacial load

Energy Technology Data Exchange (ETDEWEB)

Hernelind, Jan (5T Engineering AB (Sweden))

2010-08-15

Existing fractures crossing a deposition hole may be activated and sheared by an earthquake. The effect of such a rock shear has been investigated by finite element calculations. The buffer material in a deposition hole acts as a cushion between the canister and the rock, which reduces the effect of a rock shear substantially. Lower density of the buffer yields softer material and reduced effect on the canister. However, at the high density that is suggested for a repository the stiffness of the buffer is rather high. The stiffness is also a function of the rate of shear, which means that there may be a substantial damage on the canister at very high shear rates. However, the earthquake induced rock shear velocity is lower than 1 m/s which is not considered to be very high. The rock shear has been modelled with finite element calculations with the code Abaqus. A three dimensional finite element mesh of the buffer and the canister has been created and simulation of a rock shear has been performed. The rock shear has been assumed to take place either perpendicular to the canister at the quarter point or at an inclined angle of 22.5 deg in tension. Furthermore horizontal shear has been studied using a vertical shear plane either at the centre or at 1/4-point for the canister. The shear calculations have been driven to a total shear of 10 cm. The canister also has to be designed to withstand the loads caused by a thick ice sheet. Besides rock shear the model has been used to analyse the effect of such glacial load (either combined with rock shear or without rock shear). This report also summarizes the effect when considering creep in the copper shell

Ice flow models and glacial erosion over multiple glacial–interglacial cycles

OpenAIRE

Headley, R. M.; Ehlers, T. A.

2015-01-01

Mountain topography is constructed through a variety of interacting processes. Over glaciological timescales, even simple representations of glacial-flow physics can reproduce many of the distinctive features formed through glacial erosion. However, detailed comparisons at orogen time and length scales hold potential for quantifying the influence of glacial physics in landscape evolution models. We present a comparison using two different numerical models for glacial flow ov...

Glacial cycles: exogenous orbital changes vs. endogenous climate dynamics

Science.gov (United States)

Kaufmann, R. K.; Juselius, K.

2010-04-01

We use a statistical model, the cointegrated vector autoregressive model, to assess the degree to which variations in Earth's orbit and endogenous climate dynamics can be used to simulate glacial cycles during the late Quaternary (390 kyr-present). To do so, we estimate models of varying complexity and compare the accuracy of their in-sample simulations. Results indicate that strong statistical associations between endogenous climate variables are not enough for statistical models to reproduce glacial cycles. Rather, changes in solar insolation associated with changes in Earth's orbit are needed to simulate glacial cycles accurately. Also, results suggest that non-linear dynamics, threshold effects, and/or free oscillations may not play an overriding role in glacial cycles.

Snowball Earth: Skating on Thin Ice?

Science.gov (United States)

Roberson, A. L.; Stout, A. M.; Pollard, D.; Kasting, J. F.

2011-12-01

There is evidence of at least two intervals of widespread glaciation during the late Neoproterozoic (600-800 Myr ago), which are commonly referred to as "Snowball Earth" episodes. The global nature of these events is indicated by the fact that glacial deposits are found at low paleolatitudes during this time. Models of a global glacial event have produced a variety of solutions at low latitudes: thick ice, thin ice, slushball, and open ocean . The latter two models are similar, except that the slushball model has its ice-line at higher latitudes. To be viable, a model has to be able to account for the survival of life through the glaciations and also explain the existence of cap carbonates and other glacial debris deposited at low latitudes. The "thick-ice" model is not viable because kilometers of ice prevent the penetration of light necessary for the photosynthetic biota below. The "slushball" model is also not viable as it does not allow the formation of cap carbonates. The "thin-ice" model has been discussed previously and can account for continuation of photosynthetic life and glacial deposits at low paleolatitudes. The recently proposed "open-ocean" or "Jormungand" model also satisfies these requirements. What is it, though, that causes some models to produce thin ice near the equator and others to have open water there? We examine this question using a zonally symmetric energy balance climate model (EBM) with flowing sea glaciers to determine what parameter ranges produce each type of solution.

Pleistocene Arid and Wet Climatic Variability: Imprint of Glacial Climate, Tectonics and Oceanographic Events in the Sediments of the se Indian Ocean, Western Australia

Science.gov (United States)

McHugh, C. M.; Castaneda, J.; Kominz, M. A.; Gallagher, S. J.; Gurnis, M.; Ishiwa, T.; Mamo, B. L.; Henderiks, J.; Christensen, B. A.; Groeneveld, J.; Yokoyama, Y.; Mustaque, S.; Iqbal, F.

2017-12-01

The interaction between the evolving tectonic configuration of the Indo Pacific region as a result of the northward migration of the Australian continent, and its collision with the Banda Arc began in the Late Miocene ( 8 Ma ago). This constriction played an important role in the diversion of the Indonesian Throughflow and initiation of the Leeuwin Current. These events coupled to Pleistocene glaciations left a significant imprint in the sediments offshore western Australia. The International Ocean Discovery Program Expedition 356 drilled in shelf depths of the Carnarvon and Perth Basins recovering a thick section of Pleistocene sediment from Sites U1461 (440 m thick) and U1460 (306 m), respectively. Analyses of the lithology (logs, grain size), chemistry (X-ray elemental analyses) and an initial age model constructed from biostratigraphy and radiocarbon ages were interpreted within the framework of multichannel seismic profiles. Radiocarbon ages provide control for MIS 1-4, and the identification of glacial cycles is based on shipboard biostratigraphy best developed for Site U1460. Arid and high productivity signals are linked with glacial stages. Wet conditions are associated with river discharge, terrigenous sediments and linked with interglacial stages. Except for one very pronounced interval the productivity signal during interglacials is low. High productivity during glacial stages is related to upwelling linked to the southward flowing Leeuwin Current. Comparison of the northernmost (U1461) with southernmost (U1460) sites reveals a strong arid and wet climatic variability beginning in the Pleistocene. This variability is most pronounced in the late Pleistocene post 0.8-1.0 Ma and can be correlated with glacial-interglacial cycles, especially in the more humid southern Site that was closer to the Subantarctic Front and influenced by the Westerlies. In Site U1461 we recovered the 135m thick Gorgon slide. Its occurrence at 1 Ma coincides with a rapid tectonic

Dependences of microstructure and critical current density on the thickness of YBa2Cu3O7-x film prepared by pulsed laser deposition on buffered Ni–W tape

International Nuclear Information System (INIS)

Xu, Da; Wang, Ying; Liu, Linfei; Li, Yijie

2013-01-01

YBa 2 Cu 3 O 7−x (YBCO) films with different thicknesses were fabricated on buffered Ni–W tapes by pulsed laser deposition. The thickness dependences of microstructure and critical current density (J c ) of YBCO film were systematically investigated. The microstructure and surface morphology of YBCO film were characterized by X-ray diffraction, optical microscopy, field emission scanning electron microscopy and atomic force microscopy. And the critical current (I c ) of YBCO film was measured by the conventional four-probe method. We found that the full width at half maximum values of both omega and phi scan rocking curves, the content of a-axis oriented grain, and surface roughness of YBCO film all increased with augmenting the thickness of YBCO film. It was also found that with increasing the thickness of YBCO film from 0.3 μm to 1.5 μm, the I c of YBCO film increased from 72 A/cm to 248 A/cm and yet J c of YBCO film decreased from 2.1 × 10 6 A/cm 2 to 1.6 × 10 6 A/cm 2 . Our results indicated that the microstructure and J c of YBCO film were largely dependent on the thickness of YBCO film under the optimized deposition condition of substrate temperature. - Highlights: ► YBa 2 Cu 3 O 7−x (YBCO) films with different thicknesses were grown on metallic tapes. ► The texture and critical current were dependent on the thickness of YBCO film. ► Thickness effect was weakened by fabricating YBCO film layer by layer

Quaternary deposits and landscape evolution of the central Blue Ridge of Virginia

Science.gov (United States)

Eaton, L. Scott; Morgan, Benjamin A.; Kochel, R. Craig; Howard, Alan D.

2003-01-01

A catastrophic storm that struck the central Virginia Blue Ridge Mountains in June 1995 delivered over 775 mm (30.5 in) of rain in 16 h. The deluge triggered more than 1000 slope failures; and stream channels and debris fans were deeply incised, exposing the stratigraphy of earlier mass movement and fluvial deposits. The synthesis of data obtained from detailed pollen studies and 39 radiometrically dated surficial deposits in the Rapidan basin gives new insights into Quaternary climatic change and landscape evolution of the central Blue Ridge Mountains.The oldest depositional landforms in the study area are fluvial terraces. Their deposits have weathering characteristics similar to both early Pleistocene and late Tertiary terrace surfaces located near the Fall Zone of Virginia. Terraces of similar ages are also present in nearby basins and suggest regional incision of streams in the area since early Pleistocene–late Tertiary time. The oldest debris-flow deposits in the study area are much older than Wisconsinan glaciation as indicated by 2.5YR colors, thick argillic horizons, and fully disintegrated granitic cobbles. Radiocarbon dating indicates that debris flow activity since 25,000 YBP has recurred, on average, at least every 2500 years. The presence of stratified slope deposits, emplaced from 27,410 through 15,800 YBP, indicates hillslope stripping and reduced vegetation cover on upland slopes during the Wisconsinan glacial maximum.Regolith generated from mechanical weathering during the Pleistocene collected in low-order stream channels and was episodically delivered to the valley floor by debris flows. Debris fans prograded onto flood plains during the late Pleistocene but have been incised by Holocene stream entrenchment. The fan incision allows Holocene debris flows to largely bypass many of the higher elevation debris fan surfaces and deposit onto the topographically lower surfaces. These episodic, high-magnitude storm events are responsible for

The glacial cycles and cosmic rays

CERN Document Server

Kirkby, Jasper; Müller, R A

2004-01-01

The cause of the glacial cycles remains a mystery. The origin is widely accepted to be astronomical since paleoclimatic archives contain strong spectral components that match the frequencies of Earth's orbital modulation. Milankovitch insolation theory contains similar frequencies and has become established as the standard model of the glacial cycles. However, high precision paleoclimatic data have revealed serious discrepancies with the Milankovitch model that fundamentally challenge its validity and re-open the question of what causes the glacial cycles. We propose here that the ice ages are initially driven not by insolation cycles but by cosmic ray changes, probably through their effect on clouds. This conclusion is based on a wide range of evidence, including results presented here on speleothem growth in caves in Austria and Oman, and on a record of cosmic ray flux over the past 220 kyr obtained from the 10Be composition of deep-ocean sediments.

Electrophoretic Deposition of Gallium with High Deposition Rate

Directory of Open Access Journals (Sweden)

Hanfei Zhang

2014-12-01

Full Text Available In this work, electrophoretic deposition (EPD is reported to form gallium thin film with high deposition rate and low cost while avoiding the highly toxic chemicals typically used in electroplating. A maximum deposition rate of ~0.6 μm/min, almost one order of magnitude higher than the typical value reported for electroplating, is obtained when employing a set of proper deposition parameters. The thickness of the film is shown to increase with deposition time when sequential deposition is employed. The concentration of Mg(NO32, the charging salt, is also found to be a critical factor to control the deposition rate. Various gallium micropatterns are obtained by masking the substrate during the process, demonstrating process compatibility with microfabrication. The reported novel approach can potentially be employed in a broad range of applications with Ga as a raw material, including microelectronics, photovoltaic cells, and flexible liquid metal microelectrodes.

A genome wide association study for backfat thickness in Italian Large White pigs highlights new regions affecting fat deposition including neuronal genes

Directory of Open Access Journals (Sweden)

Fontanesi Luca

2012-11-01

Full Text Available Abstract Background Carcass fatness is an important trait in most pig breeding programs. Following market requests, breeding plans for fresh pork consumption are usually designed to reduce carcass fat content and increase lean meat deposition. However, the Italian pig industry is mainly devoted to the production of Protected Designation of Origin dry cured hams: pigs are slaughtered at around 160 kg of live weight and the breeding goal aims at maintaining fat coverage, measured as backfat thickness to avoid excessive desiccation of the hams. This objective has shaped the genetic pool of Italian heavy pig breeds for a few decades. In this study we applied a selective genotyping approach within a population of ~ 12,000 performance tested Italian Large White pigs. Within this population, we selectively genotyped 304 pigs with extreme and divergent backfat thickness estimated breeding value by the Illumina PorcineSNP60 BeadChip and performed a genome wide association study to identify loci associated to this trait. Results We identified 4 single nucleotide polymorphisms with P≤5.0E-07 and additional 119 ones with 5.0E-07 Conclusions Further investigations are needed to evaluate the effects of the identified single nucleotide polymorphisms associated with backfat thickness on other traits as a pre-requisite for practical applications in breeding programs. Reported results could improve our understanding of the biology of fat metabolism and deposition that could also be relevant for other mammalian species including humans, confirming the role of neuronal genes on obesity.

LAMBERSART "LES CONQUERANTS" (DEULE VALLEY, NORTH OF FRANCE) : A WEICHSELIAN EARLY-PLENIGLACIAL SLOPE-BOTTOM VALLEY TRANSITION

NARCIS (Netherlands)

Deschodt, Laurent; Munaut, Andre-Valentin; Limondin-Lozouet, Nicole; Boulen, Muriel

2008-01-01

The Lambersart "les Conquerants" trench sequence is made of a Shelly loam topped by coarse alluviums. The whole is covered by several meters thick pleniglacial loess. The palynological and malacological data shows that this Shelly loam deposit occured during Early Glacial, in cold and moist

Southern westerly winds: a pacemaker of Holocene glacial fluctuations in Patagonia?

Science.gov (United States)

Sagredo, E. A.; Reynhout, S.; Kaplan, M. R.; Patricio, M. I.; Aravena, J. C.; Martini, M. A.; Schaefer, J. M.

2017-12-01

A well-resolved glacial chronology is crucial to compare sequences of glacial/climate events within and between regions, and thus, to unravel mechanisms underlying past climate changes. Important efforts have been made towards understanding the Holocene climate evolution of the Southern Andes; however, the timing, patterns and causes of glacial fluctuations during this period still remain elusive. Recent advances in terrestrial cosmogenic nuclide surface exposure dating, together with the establishment of a Patagonian 10Be production rate, have opened new possibilities for establishing high-resolution glacial chronologies at centennial/decadal scale. Here we present a 10Be surface exposure chronology of fluctuations of a small, climate-sensitive mountain glacier at Mt. Fitz Roy area (49.3°S), spanning from the last glacial termination to the present. Thirty new 10Be ages show glacial advances and moraine building events at 17.1±0.9 ka, 13.5±0.5 ka, 10.2±0.7 ka or 9.9±0.5 ka, 6.9±0.2 ka, 6.1±0.3 ka, 4.5±0.2 ka and 0.5±0.1 ka. Similar to the pattern observed in New Zealand, this sequence features progressively less extensive glacial advances during the late-glacial and early Holocene, followed by advances of roughly similar extent during the mid- to late-Holocene. We suggest that while the magnitude of Holocene glacial fluctuations in Patagonia is modulated by SH summer insolation ("modulator"), the specific timing of these glacial events is influenced by centennial-scale shifts of the Southern Westerly Winds ("pacemaker").

A Simplified Analytic Investigation of the Riverside Effects of Sediment Diversions

Science.gov (United States)

2013-09-01

demonstrated that the river bed consists of a sand layer of variable thickness, underlain by erosion resistant strata (either relict glacial deposits...following analysis. Simplifications and Initial Conditions. Consider a river modeled as a wide rectangular channel of constant width (Figure 1). The...CHETN-VII-13 September 2013 14  Short term effects include the redistribution of sediment by erosion upstream of the diversion to deposition

A mechanism for overdeepenings of glacial valleys and fjords

OpenAIRE

Herman F.; Beaud F.; Champagnac J.-D.; Lemieux J.-M.; Sternai P.

2011-01-01

Most glacial erosion models assume that erosion rates are proportional to ice sliding velocity. While recent studies have shown that water plays a major role in modulating sliding velocities the impact it might have on erosion rates is still unclear. Here we incorporate subglacial hydrology into a glacial erosion model that is based on a sliding rule. Our results explicitly highlight that adding subglacial hydrology has profound impacts on the temporal and spatial patterns of glacial erosion....

Indium-Nitrogen Codoped Zinc Oxide Thin Film Deposited by Ultrasonic Spray Pyrolysis on n-(111 Si Substrate: The Effect of Film Thickness

Directory of Open Access Journals (Sweden)

Cheng-Chang Yu

2014-01-01

Full Text Available Indium-nitrogen codoped zinc oxide (INZO thin films were fabricated by spray pyrolysis deposition technique on n-(111 Si substrate with different film thicknesses at 450°C using a precursor containing zinc acetate, ammonium acetate, and indium nitrate with 1 : 3 : 0.05 at.% concentration. The morphology and structure studies were carried out by scanning electron microscopy (SEM and X-ray diffraction (XRD. The grain size of the films increased when increasing the film thickness. From XRD spectra, polycrystalline ZnO structure can be observed and the preferred orientation behavior varied from (002 to (101 as the film thickness increased. The concentration and mobility were investigated by Hall effect measurement. the p-type films with a hole mobility around 3 cm2V−1s−1 and hole concentration around 3×1019 cm−3 can be achieved with film thickness less than 385 nm. The n-type conduction with concentration 1×1020 cm−3 is observed for film with thickness 1089 nm. The defect states were characterized by photoluminescence. With temperature-dependent conductivity analysis, acceptor state with activation energy 0.139 eV dominate the p type conduction for thin INZO film. And the Zn-related shallow donors with activation energy 0.029 eV dominate the n-type conduction for the thick INZO film.

Direct current magnetron sputter-deposited ZnO thin films

International Nuclear Information System (INIS)

Hoon, Jian-Wei; Chan, Kah-Yoong; Krishnasamy, Jegenathan; Tou, Teck-Yong; Knipp, Dietmar

2011-01-01

Zinc oxide (ZnO) is a very promising electronic material for emerging transparent large-area electronic applications including thin-film sensors, transistors and solar cells. We fabricated ZnO thin films by employing direct current (DC) magnetron sputtering deposition technique. ZnO films with different thicknesses ranging from 150 nm to 750 nm were deposited on glass substrates. The deposition pressure and the substrate temperature were varied from 12 mTorr to 25 mTorr, and from room temperature to 450 deg. C, respectively. The influence of the film thickness, deposition pressure and the substrate temperature on structural and optical properties of the ZnO films was investigated using atomic force microscopy (AFM) and ultraviolet-visible (UV-Vis) spectrometer. The experimental results reveal that the film thickness, deposition pressure and the substrate temperature play significant role in the structural formation and the optical properties of the deposited ZnO thin films.

The timing and cause of glacial activity during the last glacial in central Tibet based on 10Be surface exposure dating east of Mount Jaggang, the Xainza range

Science.gov (United States)

Dong, Guocheng; Zhou, Weijian; Yi, Chaolu; Fu, Yunchong; Zhang, Li; Li, Ming

2018-04-01

Mountain glaciers are sensitive to climate change, and can provide valuable information for inferring former climates on the Tibetan Plateau (TP). The increasing glacial chronologies indicate that the timing of the local Last Glacial Maximum (LGM) recorded across the TP is asynchronous, implying different local influences of the mid-latitude westerlies and Asian Summer Monsoon in triggering glacier advances. However, the well-dated sites are still too few, especially in the transition zone between regions controlled by the two climate systems. Here we present detailed last glacial chronologies for the Mount Jaggang area, in the Xainza range, central Tibet, with forty-three apparent 10Be exposure-ages ranging from 12.4 ± 0.8 ka to 61.9 ± 3.8 ka. These exposure-ages indicate that at least seven glacial episodes occurred during the last glacial cycle east of Mount Jaggang. These include: a local LGM that occurred at ∼61.9 ± 3.8 ka, possibly corresponding to Marine Isotope Stage 4 (MIS 4); subsequent glacial advances at ∼43.2 ± 2.6 ka and ∼35.1 ± 2.1 ka during MIS 3; one glacial re-advance/standstill at MIS3/2 transition (∼29.8 ± 1.8 ka); and three glacial re-advances/standstills that occurred following MIS 3 at ∼27.9 ± 1.7 ka, ∼21.8 ± 1.3 ka, and ∼15.1 ± 0.9 ka. The timing of these glacial activities is roughly in agreement with North Atlantic millennial-scale climate oscillations (Heinrich events), suggesting the potential correlations between these abrupt climate changes and glacial fluctuations in the Mount Jaggang area. The successively reduced glacial extent might have resulted from an overall decrease in Asian Summer Monsoon intensity over this timeframe.

Connecting the records: exploiting tephra deposits to help understand abrupt climate change

Science.gov (United States)

Davies, S. M.; Abbott, P. M.; Bourne, A. J.; Chapman, M.; Pearce, N. J. G.; Griggs, A. J.; Cook, E.

2016-12-01

The causal mechanism of abrupt climate change during the last glacial period remains a key challenge. Although these events are well-documented in a wide range of proxy records, the triggers and drivers remain poorly understood, largely due to the dating uncertainties that prevent the integration of different archives. Unravelling the lead/lag responses (hence cause and effect) between the Earth's climate components is limited by the challenges of synchronising palaeoclimate records on a common timescale. Here we present the potential and the challenges of optimising the use of cryptotephra deposits to precisely correlate the Greenland ice-cores with North Atlantic marine records. A series of new cryptotephra deposits have been identified in Greenland, increasing the scope of identifying coeval isochrons in the marine environment. This new framework, however, brings new challenges in the search for unique and robust geochemical fingerprints for unequivocal tephra correlations. As such, some tephra deposits are proposed to be more valuable than others and underpin key snapshots in time during the last glacial period. The North Atlantic Ash Zone II, for instance, represents the most widespread isochron and constrains the cooling of GI-15. Some tephra deposits in the ice-core record originate from ultra-distal sources beyond the North Atlantic region and we also explore the potential for establishing North Pacific linkages.

Inhalation of nanoplatelets - Theoretical deposition simulations.

Science.gov (United States)

Sturm, Robert

2017-12-01

Primary objective of the contribution was the theoretical prediction of nanoplatelet deposition in the human respiratory tract. Modeling was founded on the hypothetical inhalation of graphene nanoplatelets (GNP) measuring 0.01 and 0.1μm in thickness and adopting a projected area diameter of 1-30μm. Particle uptake was assumed to take place with inhalation flow rates of 250, 500, 750, and 1000cm 3 s -1 , respectively. For an appropriate description of pulmonary particle behavior, transport of GNP in a stochastic lung structure and deposition formulae based on analytical and numerical studies were presupposed. The results obtained from the theoretical approach clearly demonstrate that GNP with a thickness of 0.01μm deposit in the respiratory tract by 20-50%, whereas GNP with a thickness of 0.1μm exhibit a deposition of 20-90%. Larger platelets deposit with higher probability than small ones. Increase of inhalation flow rate is accompanied by decreased deposition in the case of thin GNP, whilst thicker GNP are preferably accumulated in the extrathoracic region. Generation-specific deposition ranges from 0.05 to 7% (0.01μm) and from 0.05 to 9%, with maximum values being obtained in airway generation 20. In proximal airway generations (0-10), deposition is increased with inhalation flow rate, whereas in intermediate to distal generations a reverse effect may be observed. Health consequences of GNP deposition in different lung compartments are subjected to an intense debate. Copyright © 2017. Published by Elsevier GmbH.

Glacial modification of granite tors in the Cairngorms, Scotland

Science.gov (United States)

Hall, A.M.; Phillips, W.M.

2006-01-01

A range of evidence indicates that many granite tors in the Cairngorms have been modified by the flow of glacier ice during the Pleistocene. Comparisons with SW England and the use of a space-time transformation across 38 tor groups in the Cairngorms allow a model to be developed for progressive glacial modification. Tors with deeply etched surfaces and no, or limited, block removal imply an absence of significant glacial modification. The removal of superstructure and blocks, locally forming boulder trains, and the progressive reduction of tors to stumps and basal slabs represent the more advanced stages of modification. Recognition of some slabs as tor stumps from which glacial erosion has removed all superstructure allows the original distribution of tors to be reconstructed for large areas of the Cairngorms. Unmodified tors require covers of non-erosive, cold-based ice during all of the cold stages of the Middle and Late Pleistocene. Deformation beneath cold-based glacier ice is capable of the removal of blocks but advanced glacial modification requires former wet-based glacier ice. The depth of glacial erosion at former tor sites remains limited largely to the partial or total elimination of the upstanding tor form. Cosmogenic nuclide exposure ages (Phillips et al., 2006) together with data from weathering pit depths (Hall and Phillips, 2006), from the surfaces of tors and large erratic blocks require that the glacial entrainment of blocks from tors occurred in Marine Isotope Stages (MIS) 4-2, 6 and, probably, at least one earlier phase. The occurrence of glacially modified tors on or close to, the main summits of the Cairngorms requires full ice cover over the mountains during these Stages. Evidence from the Cairngorms indicates that tor morphology can be regarded as an important indicator of former ice cover in many formerly glaciated areas, particularly where other evidence of ice cover is sparse. Recognition of the glacial modification of tors is important

Formation and physical properties of YBCO thick films grown by using the electrophoretic deposition method

CERN Document Server

Kim, U J; Kim, Y C; Han, S K; Kang, K Y

1999-01-01

Thick films of the YBa sub 2 Cu sub 3 O subgamma sub - subdelta (YBCO) superconductor were prepared by using the electrophoretic deposition technique and a flexible wire as the substrate. The transition temperature of the wires was 91 K, the intragranular magnetic critical current density J sub c sub g sup m sup a sup g was about 10 sup 5 A/cm sup 2 at 77 K in a weak field, and the transport J sub c sup t sup r sup a sup n sup s was about 365 A/cm sup 2 at 77 K. We calculated the intergranular magnetic critical current J sub c sub J sup m sup a sup g and the activation energy from the AC-susceptibility measurements, and their values were about 444 A/cm sup 2 at 77 K and 2.02 eV, respectively.

Low temperature perovskite crystallization of highly tunable dielectric Ba0.7Sr0.3TiO3 thick films deposited by ion beam sputtering on platinized silicon substrates

Science.gov (United States)

Zhu, X. H.; Guigues, B.; Defaÿ, E.; Dubarry, C.; Aïd, M.

2009-02-01

Ba0.7Sr0.3TiO3 (BST) thick films with thickness up to 1 μm were deposited on Pt-coated silicon substrates by ion beam sputtering, followed by an annealing treatment. It is demonstrated that pure well-crystallized perovskite phase could be obtained in thick BST films by a low temperature process (535 °C). The BST thick films show highly tunable dielectric properties with tunability (at 800 kV/cm) up to 51.0% and 66.2%, respectively, for the 0.5 and 1 μm thick films. The relationship between strains and dielectric properties was systematically investigated in the thick films. The results suggest that a comparatively larger tensile thermal in-plane strain (0.15%) leads to the degradation in dielectric properties of the 0.5 μm thick film; besides, strong defect-related inhomogeneous strains (˜0.3%) make the dielectric peaks smearing and broadening in the thick films, which, however, preferably results in high figure-of-merit factors over a wide operating temperature range. Moreover, the leakage current behavior in the BST thick films was found to be dominated by the space-charge-limited-current mechanism, irrespective of the film thickness.

Low temperature perovskite crystallization of highly tunable dielectric Ba0.7Sr0.3TiO3 thick films deposited by ion beam sputtering on platinized silicon substrates

International Nuclear Information System (INIS)

Zhu, X. H.; Defaye, E.; Aied, M.; Guigues, B.; Dubarry, C.

2009-01-01

Ba 0.7 Sr 0.3 TiO 3 (BST) thick films with thickness up to 1 μm were deposited on Pt-coated silicon substrates by ion beam sputtering, followed by an annealing treatment. It is demonstrated that pure well-crystallized perovskite phase could be obtained in thick BST films by a low temperature process (535 deg. C). The BST thick films show highly tunable dielectric properties with tunability (at 800 kV/cm) up to 51.0% and 66.2%, respectively, for the 0.5 and 1 μm thick films. The relationship between strains and dielectric properties was systematically investigated in the thick films. The results suggest that a comparatively larger tensile thermal in-plane strain (0.15%) leads to the degradation in dielectric properties of the 0.5 μm thick film; besides, strong defect-related inhomogeneous strains (∼0.3%) make the dielectric peaks smearing and broadening in the thick films, which, however, preferably results in high figure-of-merit factors over a wide operating temperature range. Moreover, the leakage current behavior in the BST thick films was found to be dominated by the space-charge-limited-current mechanism, irrespective of the film thickness

Scottish landform examples : The Cairngorms - a pre-glacial upland granite landscape

OpenAIRE

Hall, A.M.; Gillespie, M.R.; Thomas, C.W.; Ebert, K.

2013-01-01

The Cairngorm massif in NE Scotland (Figure 1) is an excellent example of a preglacial upland landscape formed in granite. Glacial erosion in the mountains has been largely confined to valleys and corries (Rea, 1998) and so has acted to dissect a pre-existing upland (Figure 2). Intervening areas of the massif experienced negligible glacial erosion due to protective covers of cold-based ice (Sugden, 1968) and preserve a wide range of pre-glacial and non-glacial landforms and reg...

Uranium deposits in Proterozoic quartz-pebble conglomerates

International Nuclear Information System (INIS)

1987-09-01

This report is the result of an effort to gather together the most important information on uranium deposits in Proterozoic quartz-pebble conglomerates in the United States of America, Canada, Finland, Ghana, South Africa and Australia. The paper discusses the uranium potential (and in some cases also the gold potential in South Africa, Western Australia and Ghana) in terms of ores, sedimentation, mineralization, metamorphism, placers, geologic formations, stratigraphy, petrology, exploration, tectonics and distribution. Geologic history and application of geologic models are also discussed. Glacial outwash and water influx is also mentioned. The uranium deposits in a number of States in the USA are covered. The Witwatersrand placers are discussed in several papers. Refs, figs, tabs

Interpreting last glacial to Holocene dust changes at Talos Dome (East Antarctica: implications for atmospheric variations from regional to hemispheric scales

Directory of Open Access Journals (Sweden)

S. Albani

2012-04-01

Full Text Available Central East Antarctic ice cores preserve stratigraphic records of mineral dust originating from remote sources in the Southern Hemisphere, and represent useful indicators of climatic variations on glacial-interglacial time scales. The peripheries of the East Antarctic Ice Sheet, where ice-free areas with the potential to emit dust exist, have been less explored from this point of view. Here, we present a new profile of dust deposition flux and grain size distributions from an ice core drilled at Talos Dome (TALDICE, Northern Victoria Land, East Antarctica, where there is a significant input of dust from proximal Antarctic ice-free areas. We analyze dust and stable water isotopes variations from the Last Glacial Maximum to the Late Holocene, and compare them to the EPICA Dome C profiles from central East Antarctica. The smaller glacial-interglacial variations at Talos Dome compared to Dome C and a distinctive decreasing trend during the Holocene characterize the TALDICE dust profile. By deciphering the composite dust signal from both remote and local sources, we show the potential of this combined proxy of source activity and atmospheric transport to give information on both regional and larger spatial scales. In particular, we show how a regional signal, which we relate to the deglaciation history of the Ross Sea embayment, can be superimposed to the broader scale glacial-interglacial variability that characterizes other Antarctic sites.

Thickness-modulated tungsten-carbon superconducting nanostructures grown by focused ion beam induced deposition for vortex pinning up to high magnetic fields.

Science.gov (United States)

Serrano, Ismael García; Sesé, Javier; Guillamón, Isabel; Suderow, Hermann; Vieira, Sebastián; Ibarra, Manuel Ricardo; De Teresa, José María

2016-01-01

We report efficient vortex pinning in thickness-modulated tungsten-carbon-based (W-C) nanostructures grown by focused ion beam induced deposition (FIBID). By using FIBID, W-C superconducting films have been created with thickness modulation properties exhibiting periodicity from 60 to 140 nm, leading to a strong pinning potential for the vortex lattice. This produces local minima in the resistivity up to high magnetic fields (2.2 T) in a broad temperature range due to commensurability effects between the pinning potential and the vortex lattice. The results show that the combination of single-step FIBID fabrication of superconducting nanostructures with built-in artificial pinning landscapes and the small intrinsic random pinning potential of this material produces strong periodic pinning potentials, maximizing the opportunities for the investigation of fundamental aspects in vortex science under changing external stimuli (e.g., temperature, magnetic field, electrical current).

Phosphorus burial in the ocean over glacial-interglacial time scales

Directory of Open Access Journals (Sweden)

F. Tamburini

2009-04-01

Full Text Available The role of nutrients, such as phosphorus (P, and their impact on primary productivity and the fluctuations in atmospheric CO₂ over glacial-interglacial periods are intensely debated. Suggestions as to the importance of P evolved from an earlier proposal that P actively participated in changing productivity rates and therefore climate change, to most recent ones that changes in the glacial ocean inventory of phosphorus were important but not influential if compared to other macronutrients, such as nitrate. Using new data coming from a selection of ODP sites, we analyzed the distribution of oceanic P sedimentary phases and calculate reactive P burial fluxes, and we show how P burial fluxes changed over the last glacial-interglacial period at these sites. Concentrations of reactive P are generally lower during glacial times, while mass accumulation rates (MAR of reactive P show higher variability. If we extrapolate for the analyzed sites, we may assume that in general glacial burial fluxes of reactive P are lower than those during interglacial periods by about 8%, because the lack of burial of reactive P on the glacial shelf reduced in size, was apparently not compensated by burial in other regions of the ocean. Using the calculated changes in P burial, we evaluate their possible impact on the phosphate inventory in the world oceans. Using a simple mathematical approach, we find that these changes alone could have increased the phosphate inventory of glacial ocean waters by 17–40% compared to interglacial stages. Variations in the distribution of sedimentary P phases at the investigated sites seem to indicate that at the onset of interglacial stages, shallower sites experienced an increase in reactive P concentrations, which seems to point to P-richer waters at glacial terminations. All these findings would support the Shelf-Nutrient Hypothesis, which assumes that during glacial low stands nutrients are transferred from shallow sites

Abiotic landscape and vegetation patterns in the Netherlands during the Weichselian Late Glacial

NARCIS (Netherlands)

Hoek, W.Z.

2000-01-01

The Late Glacial landscape of the Netherlands was a landscape with changing geomorphology and vegetation. Glacial, eolian and fluvial processes in the time before the Late Glacial initially had formed the main landscape types that still existed during the Late Glacial. In these landscape types,

Loess Thickness Variations Across the Loess Plateau of China

Science.gov (United States)

Zhu, Yuanjun; Jia, Xiaoxu; Shao, Mingan

2018-01-01

The soil thickness is very important for investigating and modeling soil-water processes, especially on the Loess Plateau of China with its deep loess deposit and limited water resources. A digital elevation map (DEM) of the Loess Plateau and neighborhood analysis in ArcGIS software were used to generate a map of loess thickness, which was then validated by 162 observations across the plateau. The generated loess thickness map has a high resolution of 100 m × 100 m. The map indicates that loess is thick in the central part of the plateau and becomes gradually shallower in the southeast and northwest directions. The areas near mountains and river basins have the shallowest loess deposit. The mean loess thickness is the deepest in the zones with 400-600-mm precipitation and decreases gradually as precipitation varies beyond this range. Our validation indicates that the map just slightly overestimates loess thickness and is reliable. The loess thickness is mostly between 0 and 350 m in the Loess Plateau region. The calculated mean loess thickness is 105.7 m, with the calibrated value being 92.2 m over the plateau exclusive of the mountain areas. Our findings provide very basic data of loess thickness and demonstrate great progress in mapping the loess thickness distribution for the plateau, which are valuable for a better study of soil-water processes and for more accurate estimations of soil water, carbon, and solute reservoirs in the Loess Plateau of China.

Large Area Deposition of MoS2 by Pulsed Laser Deposition with In-Situ Thickness Control

KAUST Repository

Serna, Martha I.

2016-05-24

A scalable and catalyst-free method to deposit stoichiometric Molybdenum Disulfide (MoS2) films over large areas is reported with the maximum area limited by the size of the substrate holder. The method allows deposition of MoS2 layers on a wide range of substrates without any additional surface preparation including single crystals (sapphire and quartz), polycrystalline (HfO2), and amorphous (SiO2). The films are deposited using carefully designed MoS2 targets fabricated with excess of sulfur (S) and variable MoS2 and S particle size. Uniform and layered MoS2 films as thin as two monolayers, with an electrical resistivity of 1.54 × 104 Ω cm-1 were achieved. The MoS2 stoichiometry was as confirmed by High Resolution Rutherford Backscattering Spectrometry (HRRBS). With the method reported here, in situ graded MoS2 films ranging from ~1 to 10 monolayers can also be deposited.

Large Area Deposition of MoS2 by Pulsed Laser Deposition with In-Situ Thickness Control

KAUST Repository

Serna, Martha I.; Yoo, Seong H.; Moreno, Salvador; Xi, Yang; Oviedo, Juan Pablo; Choi, Hyunjoo; Alshareef, Husam N.; Kim, Moon J.; Minary-Jolandan, Majid; Quevedo-Lopez, Manuel A.

2016-01-01

A scalable and catalyst-free method to deposit stoichiometric Molybdenum Disulfide (MoS2) films over large areas is reported with the maximum area limited by the size of the substrate holder. The method allows deposition of MoS2 layers on a wide range of substrates without any additional surface preparation including single crystals (sapphire and quartz), polycrystalline (HfO2), and amorphous (SiO2). The films are deposited using carefully designed MoS2 targets fabricated with excess of sulfur (S) and variable MoS2 and S particle size. Uniform and layered MoS2 films as thin as two monolayers, with an electrical resistivity of 1.54 × 104 Ω cm-1 were achieved. The MoS2 stoichiometry was as confirmed by High Resolution Rutherford Backscattering Spectrometry (HRRBS). With the method reported here, in situ graded MoS2 films ranging from ~1 to 10 monolayers can also be deposited.

Lateral and vertical facies relationships of bedforms deposited by aggrading supercritical flows: From cyclic steps to humpback dunes

Science.gov (United States)

Lang, Jörg; Winsemann, Jutta

2013-10-01

The preservation of bedforms related to supercritical flows and hydraulic jumps is commonly considered to be rare in the geologic record, although these bedforms are known from a variety of depositional environments. This field-based study presents a detailed analysis of the sedimentary facies and stacking pattern of deposits of cyclic steps, chutes-and-pools, antidunes and humpback dunes from three-dimensional outcrops. The well exposed Middle Pleistocene successions from northern Germany comprise glacilacustrine ice-contact subaqueous fan and glacial lake-outburst flood deposits. The studied successions give new insights into the depositional architecture of bedforms related to supercritical flows and may serve as an analogue for other high-energy depositional environments such as fluvial settings, coarse-grained deltas or turbidite systems. Deposits of cyclic steps occur within the glacial lake-outburst flood succession and are characterised by lenticular scours infilled by gently to steeply dipping backsets. Cyclic steps formed due to acceleration and flow thinning when the glacial lake-outburst flood spilled over a push-moraine ridge. These bedforms are commonly laterally and vertically truncated and alternate with deposits of chutes-and-pools and antidunes. The subaqueous fan successions are dominated by laterally extensive sinusoidal waveforms, which are interpreted as deposits of aggrading stationary antidunes, which require quasi-steady flows at the lower limit of the supercritical flow stage and high rates of sedimentation. Humpback dunes are characterised by downflow divergent cross-stratification, displaying differentiation into topsets, foresets and bottomsets, and are interpreted as deposited at the transition from subcritical to supercritical flow conditions or vice versa. Gradual lateral and vertical transitions between humpback dunes and antidune deposits are very common. The absence of planar-parallel stratification in all studied successions

Late Pleistocene glacial fluctuations in Cordillera Oriental, subtropical Andes

Science.gov (United States)

Martini, Mateo A.; Kaplan, Michael R.; Strelin, Jorge A.; Astini, Ricardo A.; Schaefer, Joerg M.; Caffee, Marc W.; Schwartz, Roseanne

2017-09-01

The behavior of subtropical glaciers during Middle to Late Pleistocene global glacial maxima and abrupt climate change events, specifically in Earth's most arid low-latitude regions, remains an outstanding problem in paleoclimatology. The present-day climate of Cordillera Oriental, in arid northwestern Argentina, is influenced by shifts in subtropical climate systems, including the South American Summer Monsoon. To understand better past glacier-subtropical climates during the global Last Glacial Maximum (LGM, 26.5-19 ka) and other time periods, we combined geomorphic features with forty-two precise 10Be ages on moraine boulders and reconstructed paleo-equilibrium line altitudes (ELA) at Nevado de Chañi (24°S) in the arid subtropical Andes. We found a major glacial expansion at ∼23 ± 1.6 ka, that is, during the global LGM. Additional glacial expansions are observed before the global LGM (at ∼52-39 ka), and after, at 15 ± 0.5 and 12 ± 0.6 ka. The ∼15 ka glacial event was found on both sides of Chañi and the ∼12 ka event is only recorded on the east side. Reconstructed ELAs of the former glaciers exhibit a rise from east to west that resembles the present subtropical climate trajectory from the Atlantic side of the continent; hence, we infer that this climate pattern must have been present in the past. Based on comparison with other low-latitude paleoclimate records, such as those from lakes and caves, we infer that both temperature and precipitation influenced past glacial occurrence in this sector of the arid Andes. Our findings also imply that abrupt deglacial climate events associated with the North Atlantic, specifically curtailed meridional overturning circulation and regional cooling, may have had attendant impacts on low subtropical Southern Hemisphere latitudes, including the climate systems that affect glacial activity around Nevado de Chañi.

Timing of lake-level changes for a deep last-glacial Lake Missoula: optical dating of the Garden Gulch area, Montana, USA

DEFF Research Database (Denmark)

Smith, Larry N.; Sohbati, Reza; Buylaert, Jan-Pieter

2018-01-01

Glaciolacustrine sediments in the Clark Fork River valley at Garden Gulch, near Drummond, Montana, USA record highstand positions of the ice-dammed glacial Lake Missoula and repeated subaerial exposure. During these highstands the lake was at greater than 65% of its recognized maximum capacity......-level fluctuation, occurred over time scales of decades to ∼2 ka. Bioturbated sandy slopewash dated at 10.6 ± 0.9 ka and 11.9 ± 1.2 ka unconformably overlies the upper glaciolacustrine deposits. The uppermost sediments, above the glaciolacustrine section, are younger than the Glacier Peak tephra (13.7-13.4 cal ka B...... the lake's highstand position due to ice-dam failure likely led to scour in the downstream portions of the glacial Lake Missoula basin and megafloods in the Channeled Scabland....

Dissolved organic matter export in glacial and non-glacial streams along the Gulf of Alaska

Science.gov (United States)

Hood, E. W.; Scott, D.; Jeffery, A.; Schreiber, S.; Heavner, M.; Edwards, R.; D'Amore, D. V.; Fellman, J.

2009-12-01

The Gulf of Alaska drainage basin contains more than 75,000 km2 of glaciers, many of which are rapidly thinning and receding. We are using a paired watershed approach to evaluate how changes in glacier ecosystems will impact the export dissolved organic matter (DOM) into the Gulf of Alaska. Our primary study watersheds, Lemon Creek and Montana Creek, are similar in size, bedrock lithology and elevation range and extend from near sea level to the margin or interior of the Juneau Icefield. Lemon Creek has a glacial coverage of ~60%, while Montana Creek is free of glacier ice. Our goal is to evaluate seasonal differences in the quantity, chemical character and reactivity of DOM being exported from these watersheds to downstream near-shore marine ecosystems. In addition, we are monitoring a variety of physical parameters that influence instream DOM metabolism in both watersheds. Our initial results from the 2009 runoff season indicate that concentrations of dissolved organic carbon (DOC) are substantially higher in the non-glacial watershed. However, fluorescence analyses indicate that DOM from the glacier watershed has a higher protein and lower humic material content compared to DOM from the non-glacial watershed. After the spring snowmelt season, physical parameters between the two watersheds diverged, with higher streamflow and turbidity as well as colder water temperatures in the glacial watershed. Although our previous yield calculations show significantly higher DOC fluxes from the forested watershed, our results here suggest that glacier watersheds may be an important source of labile carbon to the near shore marine ecosystem. The contrast in the physical habitat between the two rivers (e.g glacier stream = cold, low light penetration, unstable substrate) supports the hypothesis that that in-stream DOM processing is limited within glacier dominated rivers, therefore delivering a higher percentage of labile DOM downstream.

An X-ray fluorescence method for the determination of metals thicknesses

International Nuclear Information System (INIS)

Vazquez, Cristina; Leyt, D.V. de; Riveros, J.A.

1987-01-01

An absolute method for the determination of the thickness of a metal film deposited on a metallic substrate is described. The method is based on the measurement of fluorescent intensity ratios for two lines from the substrate element. Additionally, the proposed method can be employed to determine the density of the deposited material or the incident angle of primary radiation and take off angle, if the metal film thickness is known. (Author) [es

Aerial gamma ray and magnetic survey: Minnesota Project, Watertown quadrangle of South Dakota/Minnesota. Final report

International Nuclear Information System (INIS)

1979-10-01

The Watertown 1:250,000 scale quadrangle of South Dakota/Minnesota is everywhere covered by variable thicknesses of Wisconsin age glacial deposits (drift). Bedrock is nowhere exposed, but is thought to be composed of primarily Cretaceous sediments. There are no known uranium deposits (or occurrences) within the quadrangle. Sixty-seven (67) groups of uranium samples were defined as anomalies and are discussed in the report. None of them are considered significant

Effect of thickness on structural, corrosion and mechanical properties of a thin ZrN film deposited by medium frequency (MF) reactive sputtering

Energy Technology Data Exchange (ETDEWEB)

Kavitha, Ayyalu; Kannan, Raman [Anna Univ., Dindigul (India). Dept. of Physics; Loganathan, Subramani [Titan Industries, Hosur, Tamilnadu (India). Ion Plating Dept.

2016-07-01

Zirconium nitride (ZrN) thin films were prepared on stainless steel (SS) substrates by medium frequency (MF) reactive sputtering with gas ion source (GIS) by varying the deposition time and obtained thickness (t{sub ZrN}) in the range of 1.25 to 3.24 μm. The effect of thickness on the structural and microstructural properties was studied using XRD and AFM. XRD characterization revealed that the texture of the ZrN thin films changes as a function of thickness. Both, the (111) and (200) peak, appear initially and (111) becomes more intense with increasing t{sub ZrN}. AFM imaging revealed that the ZrN thin film coated with t{sub ZrN} ∼ 3.24 μm shows larger grains that are uniformly distributed over the surface. An average hardness value of 19.79 GPa was observed for ZrN thin films having t{sub ZrN} ∼ 3.24 μm. The ZrN thin films having t{sub ZrN} ∼ 3.24 μm exhibits better adhesion strength up to 20 N. The electrochemical polarization studies indicated that the ZrN thin film having larger thickness shows improved corrosion resistance compared to SS in 3.5 % NaCl solution.

Controlling the resistivity gradient in chemical vapor deposition-deposited aluminum-doped zinc oxide

NARCIS (Netherlands)

Ponomarev, M. V.; Verheijen, M. A.; Keuning, W.; M. C. M. van de Sanden,; Creatore, M.

2012-01-01

Aluminum-doped ZnO (ZnO:Al) grown by chemical vapor deposition (CVD) generally exhibit a major drawback, i.e., a gradient in resistivity extending over a large range of film thickness. The present contribution addresses the plasma-enhanced CVD deposition of ZnO: Al layers by focusing on the control

Denudation of the continental shelf between Britain and France at the glacial-interglacial timescale.

Science.gov (United States)

Mellett, Claire L; Hodgson, David M; Plater, Andrew J; Mauz, Barbara; Selby, Ian; Lang, Andreas

2013-12-01

The erosional morphology preserved at the sea bed in the eastern English Channel dominantly records denudation of the continental shelf by fluvial processes over multiple glacial-interglacial sea-level cycles rather than by catastrophic flooding through the Straits of Dover during the mid-Quaternary. Here, through the integration of multibeam bathymetry and shallow sub-bottom 2D seismic reflection profiles calibrated with vibrocore records, the first stratigraphic model of erosion and deposition on the eastern English Channel continental shelf is presented. Published Optical Stimulated Luminescence (OSL) and 14 C ages were used to chronometrically constrain the stratigraphy and allow correlation of the continental shelf record with major climatic/sea-level periods. Five major erosion surfaces overlain by discrete sediment packages have been identified. The continental shelf in the eastern English Channel preserves a record of processes operating from Marine Isotope Stage (MIS) 6 to MIS 1. Planar and channelised erosion surfaces were formed by fluvial incision during lowstands or relative sea-level fall. The depth and lateral extent of incision was partly conditioned by underlying geology (rock type and tectonic structure), climatic conditions and changes in water and sediment discharge coupled to ice sheet dynamics and the drainage configuration of major rivers in Northwest Europe. Evidence for major erosion during or prior to MIS 6 is preserved. Fluvial sediments of MIS 2 age were identified within the Northern Palaeovalley, providing insights into the scale of erosion by normal fluvial regimes. Seismic and sedimentary facies indicate that deposition predominantly occurred during transgression when accommodation was created in palaeovalleys to allow discrete sediment bodies to form. Sediment reworking over multiple sea-level cycles (Saalian-Eemian-early Weichselian) by fluvial, coastal and marine processes created a multi-lateral, multi-storey succession of

Thick and low-stress PECVD amorphous silicon for MEMS applications

International Nuclear Information System (INIS)

Iliescu, Ciprian; Chen Bangtao

2008-01-01

This paper presents a solution for the deposition of thick amorphous silicon (α-Si:H) in PECVD reactors for MEMS applications, such as sacrificial layer or mask layer for dry or wet etching of glass. This achievement was possible by tuning the deposition parameters to a 'zero' value of the residual stress in the α-Si:H layer. The influence of the process parameters, such as power, frequency mode, temperature, pressure and SiH 4 /Ar flow rates for tuning the residual stress and for a good deposition rate is analyzed. The deposition of low-stress and thick (more than 12 µm in our case) α-Si:H layers was possible without generation of hillock defects (previously reported in literature for layers thicker then 2 µm). Finally, the paper presents some MEMS applications of such a deposited α-Si:H layer: masking layer for deep wet etching as well as dry etching of glass, and sacrificial layer for dry or wet release

Extraction and development of inset models in support of groundwater age calculations for glacial aquifers

Science.gov (United States)

Feinstein, Daniel T.; Kauffman, Leon J.; Haserodt, Megan J.; Clark, Brian R.; Juckem, Paul F.

2018-06-22

The U.S. Geological Survey developed a regional model of Lake Michigan Basin (LMB). This report describes the construction of five MODFLOW inset models extracted from the LMB regional model and their application using the particle-tracking code MODPATH to simulate the groundwater age distribution of discharge to wells pumping from glacial deposits. The five study areas of the inset model correspond to 8-digit hydrologic unit code (HUC8) basins. Two of the basins are tributary to Lake Michigan from the east, two are tributary to the lake from the west, and one is just west of the western boundary of the Lake Michigan topographic basin. The inset models inherited many of the inputs to the parent LMB model, including the hydrostratigraphy and layering scheme, the hydraulic conductivity assigned to bedrock layers, recharge distribution, and water use in the form of pumping rates from glacial and bedrock wells. The construction of the inset models entailed modifying some inputs, most notably the grid spacing (reduced from cells 5,000 feet on a side in the parent LMB model to 500 feet on a side in the inset models). The refined grid spacing allowed for more precise location of pumped wells and more detailed simulation of groundwater/surface-water interactions. The glacial hydraulic conductivity values, the top bedrock surface elevation, and the surface-water network input to the inset models also were modified. The inset models are solved using the MODFLOW–NWT code, which allows for more robust handling of conditions in unconfined aquifers than previous versions of MODFLOW. Comparison of the MODFLOW inset models reveals that they incorporate a range of hydrogeologic conditions relative to the glacial part of the flow system, demonstrated by visualization and analysis of model inputs and outputs and reflected in the range of ages generated by MODPATH for existing and hypothetical glacial wells. Certain inputs and outputs are judged to be candidate predictors that, if

Numerical simulation of the internal stresses of thick tungsten coating deposited by vacuum plasma spraying on copper substrate

International Nuclear Information System (INIS)

Salito, A.; Tului, M.; Casadei, F.

1998-01-01

Several Divertor components in the new generation of nuclear fusion reactors need to be protected against ion sputtering. Particularly copper based (Cu) material is very sensitive to this sputtering process. A solution to overcome such component wear and plasma contamination is to protect the copper substrate with a thick tungsten (W) functional coating. The main difficulty to produce such components is the significant difference in the coating thermomechanical properties between W and Cu. The Vacuum Plasma Spraying coating process (VPS) is a very flexible new economical way to find a solution to the above problem. To optimise the adhesion and stress release properties between the Cu-alloy substrate and the W coating, it is possible to deposit an interlayer as a bond coat between both materials. The aim of this study is to determine the maximum of the residual stresses located between the Cu substrate and the W coating using finite element analysis. The results have been used to select different types of bond coat for the experimental development of thick W coating (>3 mm) on to mock-ups for the Divertor Channel of the ITER project. (author)

Glacier melting during lava dome growth at Nevado de Toluca volcano (Mexico): Evidences of a major threat before main eruptive phases at ice-caped volcanoes

Science.gov (United States)

Capra, L.; Roverato, M.; Groppelli, G.; Caballero, L.; Sulpizio, R.; Norini, G.

2015-03-01

Nevado de Toluca volcano is one of the largest stratovolcanoes in the Trans-Mexican Volcanic Belt. During Late Pleistocene its activity was characterized by large dome growth and subsequent collapse emplacing large block and ash flow deposits, intercalated by Plinian eruptions. Morphological and paleoclimate studies at Nevado de Toluca and the surrounding area evidenced that the volcano was affected by extensive glaciation during Late Pleistocene and Holocene. During the older recognized glacial period (27-60 ka, MIS 3), the glacier was disturbed by the intense magmatic and hydrothermal activity related to two dome extrusion episodes (at 37 ka and 28 ka). Glacier reconstruction indicates maximum ice thickness of 90 m along main valleys, as at the Cano ravines, the major glacial valley on the northern slope of the volcano. Along this ravine, both 37 and 28 ka block-and-ash deposits are exposed, and they directly overlay a fluviatile sequence, up to 40 m-thick, which 14C ages clearly indicate that their emplacement occurred just before the dome collapsed. These evidences point to a clear interaction between the growing dome and its hydrothermal system with the glacier. During dome growth, a large amount of melting water was released along major glacial valleys forming thick fluvioglacial sequences that were subsequently covered by the block-and-ash flow deposits generated by the collapse of the growing dome. Even though this scenario is no longer possible at the Nevado de Toluca volcano, the data presented here indicate that special attention should be paid to the possible inundation areas from fluviatile/lahar activity prior to the main magmatic eruption at ice-capped volcanoes.

Exploration of the Key Lake uranium deposits, Saskatchewan, Canada

International Nuclear Information System (INIS)

Gatzweiler, R.; Schmeling, B.; Tan, B.

1981-01-01

In 1969, one year after the discovery of the Rabbit Lake uranium deposit, exploration started in the Key Lake area as part of a major uranium rush into Northern Saskatchewan, and within the frame of a joint venture. The area was not chosen on the basis of a particular metallogenetic concept. The lack of exploratory success in 1969 and 1970, together with the introduction in March 1970 of foreign ownership restrictions for uranium mining in Canada, discouraged six of the nine companies forming the original joint venture. In 1971 the three remaining companies decided to continue under a redefined concept, based on the knowledge obtained from the Rabbit Lake deposit (Uranerz had acquired a 49% share in 1970) and from the newly discovered uranium deposits in the Pine Creek Geosyncline, Australia. In the same year, exploration work resulted in the discovery of two high-grade mineralized boulders and significant radioactive and geochemical anomalies 5 km SW of Key Lake deposits. Subsequent exploration, aimed at finding the source of the mineralized boulders, comprised geological, glacial geological and ground radiometric surveys, boulder tracing, air-photo interpretation, lake sediment and muskeg sampling surveys, radon surveys, ground magnetic, gravity, electromagnetic and IP surveys, and drilling. The systematic exploration efforts resulted in the discovery of the Gaertner ore body in July 1975 and the Deilmann ore body in June 1976, where glacial geology, lake sediment sampling, magnetic and electromagnetic surveys were the key methods in defining the drilling targets. Three further years and a total of about 2400 drillholes were needed to fully delineate the two ore bodies. (author)

Arsenic in groundwater of Licking County, Ohio, 2012—Occurrence and relation to hydrogeology

Science.gov (United States)

Thomas, Mary Ann

2016-02-23

(2) deeper open intervals, relative to the water level.The spatial distribution of arsenic concentrations was compared to hydrogeologic characteristics of Licking County. Elevated concentrations of arsenic (and iron) were associated with areas of flat topography and thick (greater than 100 feet),clay-rich glacial deposits. These characteristics are conducive to development of strongly reducing redox conditions, which can cause arsenic associated with iron oxyhydroxides in the aquifer matrix to be released to the groundwater.Hydrogeologic characteristics conducive to the development of strongly reducing groundwater are relatively wide-spread in the western part of Licking County, which is part of the Central Lowland physiographic province. In this area, a thick layer of clay-rich glacial deposits obscures the bedrock surface and creates flat to gently rolling landscape with poorly developed drainage networks. In the eastern part of the county, which is part of the Appalachian Plateaus physiographic province, the landscape includes steep-sided valleys and bedrock uplands. In this area, elevated arsenic concentrations were detected in buried valleys but not in the bedrock uplands, where glacial deposits are thin or absent. The observation that elevated concentrations of arsenic (and iron) were more prevalent in the western part of Licking County is true for both glacial and bedrock aquifers.In Licking County, thick, clay-rich glacial deposits (and elevated concentrations of arsenic) are associated with two hydrogeologic settings—buried valley and complex thick drift. Most wells in the buried-valley setting had low arsenic concentrations, but a few samples had very high concentrations (30–44 µg/L) and very reducing redox conditions (methanogenic and near-methanogenic). For wells in the complex-thick-drift setting, elevated arsenic concentrations are more prevalent, but the maximum concentration was lower (about 21 µg/L). Similar observations were made about arsenic

Breakup of last glacial deep stratification in the South Pacific

Science.gov (United States)

Basak, Chandranath; Fröllje, Henning; Lamy, Frank; Gersonde, Rainer; Benz, Verena; Anderson, Robert F.; Molina-Kescher, Mario; Pahnke, Katharina

2018-02-01

Stratification of the deep Southern Ocean during the Last Glacial Maximum is thought to have facilitated carbon storage and subsequent release during the deglaciation as stratification broke down, contributing to atmospheric CO2 rise. Here, we present neodymium isotope evidence from deep to abyssal waters in the South Pacific that confirms stratification of the deepwater column during the Last Glacial Maximum. The results indicate a glacial northward expansion of Ross Sea Bottom Water and a Southern Hemisphere climate trigger for the deglacial breakup of deep stratification. It highlights the important role of abyssal waters in sustaining a deep glacial carbon reservoir and Southern Hemisphere climate change as a prerequisite for the destabilization of the water column and hence the deglacial release of sequestered CO2 through upwelling.

Timing of maximum glacial extent and deglaciation from HualcaHualca volcano (southern Peru), obtained with cosmogenic 36Cl.

Science.gov (United States)

Alcalá, Jesus; Palacios, David; Vazquez, Lorenzo; Juan Zamorano, Jose

2015-04-01

Andean glacial deposits are key records of climate fluctuations in the southern hemisphere. During the last decades, in situ cosmogenic nuclides have provided fresh and significant dates to determine past glacier behavior in this region. But still there are many important discrepancies such as the impact of Last Glacial Maximum or the influence of Late Glacial climatic events on glacial mass balances. Furthermore, glacial chronologies from many sites are still missing, such as HualcaHualca (15° 43' S; 71° 52' W; 6,025 masl), a high volcano of the Peruvian Andes located 70 km northwest of Arequipa. The goal of this study is to establish the age of the Maximum Glacier Extent (MGE) and deglaciation at HualcaHualca volcano. To achieve this objetive, we focused in four valleys (Huayuray, Pujro Huayjo, Mollebaya and Mucurca) characterized by a well-preserved sequence of moraines and roches moutonnées. The method is based on geomorphological analysis supported by cosmogenic 36Cl surface exposure dating. 36Cl ages have been estimated with the CHLOE calculator and were compared with other central Andean glacial chronologies as well as paleoclimatological proxies. In Huayuray valley, exposure ages indicates that MGE occurred ~ 18 - 16 ka. Later, the ice mass gradually retreated but this process was interrupted by at least two readvances; the last one has been dated at ~ 12 ka. In the other hand, 36Cl result reflects a MGE age of ~ 13 ka in Mollebaya valley. Also, two samples obtained in Pujro-Huayjo and Mucurca valleys associated with MGE have an exposure age of 10-9 ka, but likely are moraine boulders affected by exhumation or erosion processes. Deglaciation in HualcaHualca volcano began abruptly ~ 11.5 ka ago according to a 36Cl age from a polished and striated bedrock in Pujro Huayjo valley, presumably as a result of reduced precipitation as well as a global increase of temperatures. The glacier evolution at HualcaHualca volcano presents a high correlation with

The evaluation of in-situ leaching hydrological-geologic condition in a sandstone-type uranium deposits of a low-grade and thick ledge

International Nuclear Information System (INIS)

Jiang Yan

2014-01-01

The ore aquifer of a sandstone-type uranium deposits is thick, the grade, and uranium amount per square meter is low. To demonstrate the economic rationality of the in-situ leaching deposit, the Pumping test on the spot, recovery of water levels test, Pumping test and Injection test, Injection test in a Drilling hole, the pumping and injection balance test are carried out. And the hydro geological parameters of mineral aquifer are acquired. The parameters includes coefficient of transmissibility, Coefficient of permeability, Specific discharge of a well and Water injection. Radius of influence etc. The relation between discharge of drilling and Drawdown is researched. The capability of pumping and injection by a drilling hole is determined. The Hydraulic between the aquifer with mineral and the upper and lower aquifer is researched. The reasonable Mining drawdown is testified, the hydrogeological conditions of in-Situ leaching of the mining deposit is found out, this provides necessary parameters and basis for this kind of Situ-leach uranium mining wells, the designing of Spacing of wells, and the economic evaluation of In-situ leaching technology. (author)

Dust Deposition and Migration of the ITCZ through the Last Glacial Cycle in the Central Equatorial Pacific (Line Islands).

Science.gov (United States)

Reimi Sipala, M. A.; Marcantonio, F.

2014-12-01

Atmospheric dust can be used to record climate change in addition to itself playing a role in several key climate processes, such as affecting Earth's albedo, fomenting rain coalescence, encouraging biological productivity, and enhancing carbon export though particle sinks. Using deep sea sediments, it is possible to quantify and locate the sources and sinks of atmospheric dust. A key area of research is the shift in the inter-tropical converge zone (ITCZ), a thermally influenced area that shifts according to the northern and southern hemisphere temperature gradient. This ongoing project focuses on the changes of the ITCZ over the Central Equatorial Pacific (CEP) over the past ~25000 years. The research focuses on two cores taken from the Line Islands Ridge at 0° 29' N (ML1208-18GC), and 4° 41' N (ML1208-31BB). The main aim is to quantify the magnitude and provenance of windblown dust deposited in the CEP, and to address questions regarding the nature of the variations of dust through ice-age climate transitions. Radiogenic isotopes (Sr, Nd, Pb) have been successfully used to distinguish between different potential dust sources in the aluminosilicates fractions of Pacific Sediments. Our preliminary Pb isotope ratios suggest that, for modern deposition, the northern core's (31BB) detrital sediment fraction is likely sourced from Asian Loess (average ratios are 206Pb/204Pb = 18.88, 207Pb/204Pb = 15.69, 208Pb/204Pb = 39.06). The equatorial core's (18GC) detrital fraction has a less radiogenic Pb signature, which is consistent with South American dust sourcing (206Pb/204Pb = 18.62, 207Pb/204Pb = 15.63, 208Pb/204Pb = 38.62). This is indicative of a strong modern ITCZ that acts as an effective barrier for inter-hemispheric dust transport. Prior to Holocene time, the changes in Pb isotope ratios in both cores appear to be in anti-phase; the northern core becomes less radiogenic up to the LGM, while the southern core becomes more radiogenic. This is potentially due to a

Glacial evolution in King George and Livingston Islands (Antarctica) since the Last Glacial Maximum based on cosmogenic nuclide dating and glacier surface reconstruction - CRONOANTAR project

Science.gov (United States)

Ruiz Fernández, Jesús; Oliva, Marc; Fernández Menéndez, Susana del Carmen; García Hernández, Cristina; Menéndez Duarte, Rosa Ana; Pellitero Ondicol, Ramón; Pérez Alberti, Augusto; Schimmelpfennig, Irene

2017-04-01

CRONOANTAR brings together researchers from Spain, Portugal, France and United Kingdom with the objective of spatially and temporally reconstruct the deglaciation process at the two largest islands in the South Shetlands Archipelago (Maritime Antarctica), since the Global Last Glacial Maximum. Glacier retreat in polar areas has major implications at a local, regional and even planetary scale. Global average sea level rise is the most obvious and socio-economically relevant, but there are others such as the arrival of new fauna to deglaciated areas, plant colonisation or permafrost formation and degradation. This project will study the ice-free areas in Byers and Hurd peninsulas (Livingston Island) and Fildes and Potter peninsulas (King George Island). Ice-cap glacier retreat chronology will be revealed by the use of cosmogenic isotopes (mainly 36Cl) on glacially originated sedimentary and erosive records. Cosmogenic dating will be complemented by other dating methods (C14 and OSL), which will permit the validation of these methods in regions with cold-based glaciers. Given the geomorphological evidences and the obtained ages, a deglaciation calendar will be proposed and we will use a GIS methodology to reconstruct the glacier extent and the ice thickness. The results emerging from this project will allow to assess whether the high glacier retreat rates observed during the last decades were registered in the past, or if they are conversely the consequence (and evidence) of the Global Change in Antarctica. Acknowledgements This work has been funded by the Spanish Ministry of Economy, Industry and Competitiveness (Reference: CTM2016-77878-P).

The role of surface preparation in corrosion protection of copper with nanometer-thick ALD alumina coatings

Energy Technology Data Exchange (ETDEWEB)

Mirhashemihaghighi, Shadi; Światowska, Jolanta [PSL Research University, CNRS – Chimie ParisTech, Institut de Recherche de Chimie Paris (IRCP), 11 rue Pierre et Marie Curie, 75005 Paris (France); Maurice, Vincent, E-mail: vincent.maurice@chimie-paristech.fr [PSL Research University, CNRS – Chimie ParisTech, Institut de Recherche de Chimie Paris (IRCP), 11 rue Pierre et Marie Curie, 75005 Paris (France); Seyeux, Antoine; Klein, Lorena H. [PSL Research University, CNRS – Chimie ParisTech, Institut de Recherche de Chimie Paris (IRCP), 11 rue Pierre et Marie Curie, 75005 Paris (France); Salmi, Emma; Ritala, Mikko [Laboratory of Inorganic Chemistry, Department of Chemistry, University of Helsinki, P.O. Box 55, FIN-00014 Helsinki (Finland); Marcus, Philippe [PSL Research University, CNRS – Chimie ParisTech, Institut de Recherche de Chimie Paris (IRCP), 11 rue Pierre et Marie Curie, 75005 Paris (France)

2016-11-30

Highlights: • 10–50 nm thick alumina coatings were grown on copper by atomic layer deposition. • Surface smoothening by substrate annealing was studied as pre-deposition treatment. • Corrosion protection is promoted by pre-treatment for 10 nm but not for thicker films. • Local adhesion failure is assigned to the stresses accumulated in the thicker films. • Surface smoothening decreases the interfacial strength bearing the film stresses. - Abstract: Surface smoothening by substrate annealing was studied as a pre-treatment for improving the corrosion protection provided to copper by 10, 20 and 50 nm thick alumina coatings deposited by atomic layer deposition. The interplay between substrate surface state and deposited film thickness for controlling the corrosion protection provided by ultrathin barrier films is demonstrated. Pre-annealing at 750 °C heals out the dispersed surface heterogeneities left by electropolishing and reduces the surface roughness to less than 2 nm independently of the deposited film thickness. For 10 nm coatings, substrate surface smoothening promotes the corrosion resistance. However, for 20 and 50 nm coatings, it is detrimental to the corrosion protection due to local detachment of the deposited films. The weaker adherence of the thicker coatings is assigned to the stresses accumulated in the films with increasing deposited thickness. Healing out the local heterogeneities on the substrate surface diminishes the interfacial strength that is bearing the stresses of the deposited films, thereby increasing adhesion failure for the thicker films. Pitting corrosion occurs at the local sites of adhesion failure. Intergranular corrosion occurs at the initially well coated substrate grain boundaries because of the growth of a more defective and permeable coating at grain boundaries.

AN GEOLOGICAL OVERVIEW OF GLACIAL ACCUMULATION AND EROSIONAL OCCURRENCES AT THE VELEBIT AND THE BIOKOVO MTS., CROATIA

Directory of Open Access Journals (Sweden)

Josipa Velić

2017-01-01

Full Text Available Numerous accumulation and erosional forms originating from the activity of small valley glaciers or cirque glaciers occur in the highest mountains in Croatia: Velebit (1757 m and Biokovo (1762 m. They were produced during the Upper Pleistocene, in the Würm glacial stage of the Alpine classification. Accumulation forms comprise ground, terminal and recessional moraines, drumlins, eskers, glacial erratics and glaciofluvial and glaciolacustrine sediments. Single ridge eskers are often associated with areas of kame and kettle topography. Among erosional occurrences roche moutonnée (sheepback rocks, U-shaped valleys ranging in size from meso-macro, arêtes, hanging valleys, meso-sized cirques, kettles, and striations were noted. In Croatian Dinarides such forms in most cases occur between 900 and 1400 meters altitude. During the early to middle Würm glacial maximum, the snow line was above 900 m, perhaps even above 1000 m altitude, and sea levels were 120 meters lower than at present day. Considering the features of the present relief, ice cover was probably 200 to 300 m thick. Features of drumlins, eskers and kettles point to warm-based glaciers. The drumlins are small – up to 100 meters long and 50 meters wide, with the most common long axis ranging orientation from 130o – 310o. The near total absence of platy clasts, as well as their stratigraphic affiliation, largely reflects features of source rocks.

Geomorphological evidence of warm-humid and cold-dry glaciations in the dry western Cordillera of the tropical Peruvian Andes

Science.gov (United States)

Mächtle, B.; Hein, A. S.; Dunai, T.; Eitel, B.

2012-04-01

The western Cordillera of the Andes (14°30'S, 74°W) is characterized by high altitudes, strong radiation and semi-arid conditions. Therefore, glacial processes and resulting landforms differ markedly from these of the outer-tropics. However, under sub-arctic conditions similar glacial landforms occur. This congruence can be explained by comparable environmental conditions, which determine the dynamics of ice flow, glacial erosion, debris production as well as moraine deposition. Outside the higher latitudes, typical sub-arctic glacial landforms as controlled moraines and trimline moraines (Evans 2009, Ó Cofaigh et al. 2005) remained undescribed until now. These landforms result from polythermal or cold-basal ice flow, respectively, which is typical for polar conditions. Beside this, we also found steep lateral moraines, which give evidence of increased ice thickness, debris production and deposition and warm-basal ice flow, which is conceivable only for alpine-type valley glaciers. Striations of the bedrock give evidence of accompanied basal erosion. Coexisting trimline moraines and steep lateral moraines rule out the influence of topography on ice thickness and the resulting thermal regime. Therefore, we match the different moraine types to changes in ice thickness, which was controlled by considerable precipitation changes during the last glaciation. An erroneous classification of the observed boulder associations as trimline moraine due to selective erosion after deposition can be excluded due to general arid conditions, slow weathering and the chronological proximity of only a few millennia between both landforms, determined from cosmogenic nuclides. Therefore, the occurrence of different thermal regimes gives evidence of considerable changes in precipitation during the last glaciation - but furthermore requires an associated change in the thermal conditions to explain the very close spatial position of both ice margins. Changes in ice volume must have

Atomic layer deposition of a MoS₂ film.

Science.gov (United States)

Tan, Lee Kheng; Liu, Bo; Teng, Jing Hua; Guo, Shifeng; Low, Hong Yee; Tan, Hui Ru; Chong, Christy Yuen Tung; Yang, Ren Bin; Loh, Kian Ping

2014-09-21

A mono- to multilayer thick MoS₂ film has been grown by using the atomic layer deposition (ALD) technique at 300 °C on a sapphire wafer. ALD provides precise control of the MoS₂ film thickness due to pulsed introduction of the reactants and self-limiting reactions of MoCl₅ and H₂S. A post-deposition annealing of the ALD-deposited monolayer film improves the crystallinity of the film, which is evident from the presence of triangle-shaped crystals that exhibit strong photoluminescence in the visible range.

Cordão Formation: loess deposits in the southern coastal plain of the state of Rio Grande do Sul, Brazil

Directory of Open Access Journals (Sweden)

RENATO P. LOPES

Full Text Available ABSTRACT Loess consists of silt-dominated sediments that cover ~10% of the Earth's surface. In southern South America it occurs in Argentina, Bolivia, Paraguay and Uruguay, and its presence in southern Brazil was never studied in detail. Here is proposed a new lithostratigraphic unit, Cordão Formation, consisting of loess deposits in the southern Brazilian coastal plain. It consists of fine-very fine silt with subordinate sand and clay, found mostly in lowland areas between Pleistocene coastal barriers. These sediments are pale-colored (10YR hue and forms ~1,5-2,0 meter-thick stable vertical walls. The clay minerals include illite, smectite, interstratified illite/smectite and kaolinite, the coarser fraction is mostly quartz and plagioclase. Caliche and iron-manganese nodules are also present. The only fossils found so far are rodent teeth and a tooth of a camelid (Hemiauchenia paradoxa. Luminescence ages indicate that this loess was deposited in the latest Pleistocene, between ~30 and 10 kyrs ago, and its upper portion was modified by erosion and accumulation of clay and organic matter in the Holocene. The estimated accumulation rate was ~630 g/m2/year. The probable source of this loess is the Pampean Aeolian System of Argentina and it would have been deposited by the increased aeolian processes of the last glacial.

One-step aerosol synthesis of nanoparticle agglomerate films: simulation of film porosity and thickness

International Nuclear Information System (INIS)

Maedler, Lutz; Lall, Anshuman A; Friedlander, Sheldon K

2006-01-01

A method is described for designing nanoparticle agglomerate films with desired film porosity and film thickness. Nanoparticle agglomerates generated in aerosol reactors can be directly deposited on substrates to form uniform porous films in one step, a significant advance over existing technologies. The effect of agglomerate morphology and deposition mechanism on film porosity and thickness are discussed. Film porosity was calculated for a given number and size of primary particles that compose the agglomerates, and fractal dimension. Agglomerate transport was described by the Langevin equation of motion. Deposition enhancing forces such as thermophoresis are incorporated in the model. The method was validated for single spherical particles using previous theoretical studies. An S-shape film porosity dependence on the particle Peclet number typical for spherical particles was also observed for agglomerates, but films formed from agglomerates had much higher porosities than films from spherical particles. Predicted film porosities compared well with measurements reported in the literature. Film porosities increased with the number of primary particles that compose an agglomerate and higher fractal dimension agglomerates resulted in denser films. Film thickness as a function of agglomerate deposition time was calculated from the agglomerate deposition flux in the presence of thermophoresis. The calculated film thickness was in good agreement with measured literature values. Thermophoresis can be used to reduce deposition time without affecting the film porosity

ELLIPSOMETRIC STUDY OF SEMITRANSPARENT SILVER LAYERS DEPOSITED ON GLASS

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Víctor Toranzos

2014-12-01

Full Text Available Using ellipsometry, the film structure is characterized by optical indices n, k (visible region, 450 nm <  < 580 nm and the thickness (15 < d < 35 nm. The optical indices change with the quantity of silver deposited, obtaining effective indices of 1.0 < n < 1.8 and 1.6 < k < 2.6 to the smaller deposits that belong to a volumetric fraction between 0.35 and 0.5 of silver in the air. An effective optical thickness film decrease is observed when the silver volumetric fraction increases, and a thickness increase with close indices to solid silver when the deposited silver increases. Optical and effective medium theory indices are compared.

Electroplated thick-film cobalt platinum permanent magnets

International Nuclear Information System (INIS)

Oniku, Ololade D.; Qi, Bin; Arnold, David P.

2016-01-01

The material and magnetic properties of multi-micron-thick (up to 6 μm) L1 0 CoPt magnetic films electroplated onto silicon substrates are investigated as candidate materials for integration in silicon-based microsystems. The influence of various process conditions on the structure and magnetic properties of electroplated CoPt thick-films is studied in order to better understand the complex process/structure/property relationships associated with the electroplated films. Process variables studied here include different seed layers, electroplating current densities (ranging from 25–200 mA/cm 2 ), deposition times (up to 60 min), and post-deposition annealing times and temperatures. Analyses include film morphology, film thickness, composition, surface roughness, grain size, phase volume fractions, and L1 0 ordering parameter. Key correlations are found relating process and structure variations to the extrinsic magnetic properties (remanence, coercivity, squareness, and energy product). Strong hard magnetic properties (B r ~0.8 T, H ci ~800 kA/m, squareness close to 0.9, and BH max of 100 kJ/m 3 ) are obtained for films deposited on Si/TiN/Ti/Cu at current densities of 100 mA/cm 2 , pH of 7, and subsequently annealed at 675 °C for 30 min. - Highlights: • CoPt films plated up to 6 μm thick on silicon substrates. • A1 to L1 0 phase transformation by annealing in forming gas. • Various process–structure–property relationships explored. • Key results: B r ~0.8 T, H ci ~800 kA/m, squareness 0.9, and BH max ~100 kJ/m 3 .

MIDDLE MIOCENE DEPOSITIONAL MODEL IN THE DRAVA DEPRESSION DESCRIBED BY GEOSTATISTICAL POROSITY AND THICKNESS MAPS (CASE STUDY: STARI GRADAC-BARCS NYUGAT FIELD

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Tomislav Malvić

2006-12-01

Full Text Available Neogene depositional environments in the Drava depression can be classified in two groups. One group is of local alluvial fans, which were active during the period of Middle Miocene (Badenian extension through the entire Pannonian Basin. The second group is represented by continuous Pannonian and Pontian sedimentation starting with lacustrine environment of partly deep water and partly prodelta (turbidity fans and terminating at the delta plain sedimentation. The coarse-grained sediments of alluvial fans have the great hydrocarbon potential, because they often comprise reservoir rocks. Reservoir deposits are mostly overlain (as result of fan migration by pelitic seal deposits and sometimes including organic rich source facies. That Badenian sequences are often characterised by complete petroleum systems, what is confirmed by large number of oil and gas discoveries in such sediments in the Drava and other Croatian depressions. Alluvial environments are characterised by frequent changes of petrophysical properties, due to local character of depositional mechanism and material sources. In the presented paper, Stari Gradac-Barcs Nyugat field is selected as a case study for demonstrating the above mentioned heterogenic features of the Badenian sequences. Structural solutions are compared by maps of parameters related to depositional environment, i.e. porosity and thickness maps. Geostatistics were used for spatial extension of input dataset. The spatial variability of porosity values, i.e. reservoir quality, is interpreted by transition among different sub-environments (facies in the alluvial fan system.

Glacial Meltwater Contirbutions to the Bow River, Alberta, Canada

Science.gov (United States)

Bash, E. A.; Marshall, S. J.; White, E. C.

2009-12-01

Assessment of glacial melt is critical for water resource management in areas which rely on glacier-fed rivers for agricultural and municipal uses. Changes in precipitation patterns coupled with current glacial retreat are altering the glacial contribution to river flow in areas such as the Andes of South America and the high ranges of Asia, as well as the Rockies of Western Canada. Alberta’s Bow River has its headwaters in the eastern slopes of the Canadian Rockies and contributes to the Nelson drainage system feeding into Hudson Bay. The Bow River basin contains several population centers, including the City of Calgary, and is heavily taxed for agricultural use. The combined effects of rapid glacial retreat in the Canadian Rockies, higher drought frequency, and increased demand are likely to heighten water stress in Southern Alberta. However, there has been little focus to date on the extent and importance of glacial meltwater in the Bow River. The Bow River contains 74.5 km2 of glacier ice, which amounts to only 0.29% of the basin. While this number is not high compared to some glacierized areas, Hopkinson and Young (1998) report that in dry years, glacier melt can provide up to 50% of late summer flows at a station in the upper reaches of the river system. We extend this work with an assessment of monthly and annual glacial contributions to the Bow River farther downstream in Calgary. Our analysis is based on mass balance, meteorological, and hydrological data that has been collected at the Haig Glacier since 2001. This data is used in conjunction with glacier coverage and hypsometric data for the remainder of the basin to estimate seasonal snow and glacial meltwater contributions to the Bow River from the glacierized fraction of the catchment. The results of this study show the percentage of total flow attributed to glacial melt to be highly variable. Glacier runoff contributes up to an order of magnitude more water to the Bow River per unit area of

Glacial refugia and post-glacial colonization patterns in European bryophytes

OpenAIRE

Kyrkjeeide, Magni Olsen; Stenøien, Hans K.; Flatberg, Kjell Ivar; Hassel, Kristian

2014-01-01

Most species are assumed to have survived south or east of the ice sheet covering northern Europe during the last glacial maximum. Molecular and macrofossil evidence suggests, however, that some species may have survived in ice-free areas in Scandinavia. In plants, inbreeding and vegetative growth are associated with low genetic load and enhanced survival in small, isolated populations. These characteristics are often found in bryophytes, possibly allowing them to survive extreme conditions i...

Gluteal fat thickness in pelvic CT

International Nuclear Information System (INIS)

Park, Jeong Mi; Jung, Se Young; Lee, Jae Mun; Park, Seog Hee; Kim, Choon Yul; Bahk, Yong Whee

1986-01-01

Many calcifications due to fat necrosis in the buttocks detected on the pelvis roentgenograms suggest that the majority of injections intended to be intramuscular actually are delivered into fat. We measured thickness of adult gluteal fat to decide whether the injection using needle of usual length is done into fat or muscle. We measured the vertical thickness of the subcutaneous fat at a point of 2-3cm above the femoral head cut slice with randomly collected 116 cases of adults in the department of Radiology, St. Mary's Hospital, Catholic Medical College. We found that 32% female cases might actually receive on intra adipose injection when a needle of maximum 3.8cm length is inserted into the buttock. If deposition into muscle is desirable, we need to choose needle whose length is appropriate for the site of injection and the patient's deposits of fat.

Equilibrium helium film in the thick film limit

International Nuclear Information System (INIS)

Klier, J.; Schletterer, F.; Leiderer, P.; Shikin, V.

2003-01-01

For the thickness of a liquid or solid quantum film, like liquid helium or solid hydrogen, there exist still open questions about how the film thickness develops in certain limits. One of these is the thick film limit, i.e., the crossover from the thick film to bulk. We have performed measurements in this range using the surface plasmon resonance technique and an evaporated Ag film deposited on glass as substrate. The thickness of the adsorbed helium film is varied by changing the distance h of the bulk reservoir to the surface of the substrate. In the limiting case, when h > 0, the film thickness approaches about 100 nm following the van der Waals law in the retarded regime. The film thickness and its dependence on h is precisely determined and theoretically modeled. The equilibrium film thickness behaviour is discussed in detail. The agreement between theory and experiment is very good

Morphological Characteristics of Au Films Deposited on Ti: A Combined SEM-AFM Study

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Francesco Ruffino

2018-03-01

Full Text Available Deposited Au films and coatings are, nowadays, routinely used as active or passive elements in several innovative electronic, optoelectronic, sensing, and energy devices. In these devices, the physical properties of the Au films are strongly determined by the films nanoscale structure. In addition, in these devices, often, a layer of Ti is employed to promote adhesion and, so, influencing the nanoscale structure of the deposited Au film. In this work, we present experimental analysis on the nanoscale cross-section and surface morphology of Au films deposited on Ti. In particular, we sputter-deposited thick (>100 nm thickness Au films on Ti foils and we used Scanning Electron Microscopy to analyze the films cross-sectional and surface morphology as a function of the Au film thickness and deposition angle. In addition, we analyzed the Au films surface morphology by Atomic Force Microscopy which allowed quantifying the films surface roughness versus the film thickness and deposition angle. The results establish a relation between the Au films cross-sectional and surface morphologies and surface roughness to the film thickness and deposition angle. These results allow setting a general working framework to obtain Au films on Ti with specific morphological and topographic properties for desired applications in which the Ti adhesion layer is needed for Au.

Evidence for slow late-glacial ice retreat in the upper Rangitata Valley, South Island, New Zealand

Science.gov (United States)

Shulmeister, J.; Fink, D.; Winkler, S.; Thackray, G. D.; Borsellino, R.; Hemmingsen, M.; Rittenour, T. M.

2018-04-01

A suite of cosmogenic radionuclide ages taken from boulders on lateral and latero-terminal moraines in the Rangitata Valley, eastern South Island, New Zealand demonstrates that relatively thick ice occupied valley reaches inland of the Rangitata Gorge until c. 21 ka. Thereafter ice began to thin, and by c. 17 ka it had retreated 33 km up-valley of the Rangitata Gorge to the Butler-Brabazon Downs, a structurally created basin in the upper Rangitata Valley. Despite its magnitude, this retreat represents a minor ice volume reduction from 21 ka to 17 ka, and numerous lateral moraines preserved suggest a relatively gradual retreat over that 4 ka period. In contrast to records from adjacent valleys, there is no evidence for an ice-collapse at c. 18 ka. We argue that the Rangitata record constitutes a more direct record of glacial response to deglacial climate than other records where glacial dynamics were influenced by proglacial lake development, such as the Rakaia Valley to the North and the major valleys in the Mackenzie Basin to the south-west. Our data supports the concept of a gradual warming during the early deglaciation in the South Island New Zealand.

Versatile technique for assessing thickness of 2D layered materials by XPS

Science.gov (United States)

Zemlyanov, Dmitry Y.; Jespersen, Michael; Zakharov, Dmitry N.; Hu, Jianjun; Paul, Rajib; Kumar, Anurag; Pacley, Shanee; Glavin, Nicholas; Saenz, David; Smith, Kyle C.; Fisher, Timothy S.; Voevodin, Andrey A.

2018-03-01

X-ray photoelectron spectroscopy (XPS) has been utilized as a versatile method for thickness characterization of various two-dimensional (2D) films. Accurate thickness can be measured simultaneously while acquiring XPS data for chemical characterization of 2D films having thickness up to approximately 10 nm. For validating the developed technique, thicknesses of few-layer graphene (FLG), MoS2 and amorphous boron nitride (a-BN) layer, produced by microwave plasma chemical vapor deposition (MPCVD), plasma enhanced chemical vapor deposition (PECVD), and pulsed laser deposition (PLD) respectively, were accurately measured. The intensity ratio between photoemission peaks recorded for the films (C 1s, Mo 3d, B 1s) and the substrates (Cu 2p, Al 2p, Si 2p) is the primary input parameter for thickness calculation, in addition to the atomic densities of the substrate and the film, and the corresponding electron attenuation length (EAL). The XPS data was used with a proposed model for thickness calculations, which was verified by cross-sectional transmission electron microscope (TEM) measurement of thickness for all the films. The XPS method determines thickness values averaged over an analysis area which is orders of magnitude larger than the typical area in cross-sectional TEM imaging, hence provides an advanced approach for thickness measurement over large areas of 2D materials. The study confirms that the versatile XPS method allows rapid and reliable assessment of the 2D material thickness and this method can facilitate in tailoring growth conditions for producing very thin 2D materials effectively over a large area. Furthermore, the XPS measurement for a typical 2D material is non-destructive and does not require special sample preparation. Therefore, after XPS analysis, exactly the same sample can undergo further processing or utilization.

An attempt at determining Des of glacial sediments using different luminescence methods

International Nuclear Information System (INIS)

Ou Xianjiao; Lai Zhongping; Zeng Lanhua

2013-01-01

Background: Absolute dating is the key technical issue of Quaternary glacial research. Optically stimulated luminescence (OSL) has been increasingly applied to Quaternary glacial dating in recent years. However, problems such as insufficient bleaching, low luminescence sensitivity, high thermal transfer effect, etc, still remain. Purpose: In order to investigate the applicability of equivalent dose (D e ) determination of glacial sediments by different OSL methods, six samples were collected from the Yingpu Valley of eastern Qinghai-Tibetan Plateau (two samples from modern glacial sediments, three from moraines and glacial terrace attributed to Neoglacial and one from a moraine attributed to the last glaciation). Methods: The D e s were determined by SAR combined SGC technique, using three methods: quartz large aliquot (6 mm) BSL, small aliquot (2/3 mm) BSL and polymineral IRSL. Results: D e s determined by SGC are consistent with D e s determined by SAR protocol. Comparison of three methods shows that IRSL D e >large aliquot BSL D e >small aliquot BSL D e . D e s of polymineral IRSL are obviously higher than quartz BSL. Conclusions: It is obviously that feldspar is more difficult to reset than quartz, thus is not suitable for dating glacial sediments in this region. Quartz large aliquot method is suitable for well bleached glacial samples. Due to the low luminescence sensitivity of quartz, small aliquot method showed poor luminescence characteristics. Moreover, this method cannot distinguish the poor bleached grains in this measurement. However, it is possible that quartz small aliquot, even single grain method could be used to date older or brighter glacial samples. More works are required to solve the problems we have encountered in dating low sensitivity glacial sediments. (authors)

Matrix shaped pulsed laser deposition: New approach to large area and homogeneous deposition

Energy Technology Data Exchange (ETDEWEB)

Akkan, C.K.; May, A. [INM – Leibniz Institute for New Materials, CVD/Biosurfaces Group, Campus D2 2, 66123 Saarbrücken (Germany); Hammadeh, M. [Department for Obstetrics, Gynecology and Reproductive Medicine, IVF Laboratory, Saarland University Medical Center and Faculty of Medicine, Building 9, 66421 Homburg, Saar (Germany); Abdul-Khaliq, H. [Clinic for Pediatric Cardiology, Saarland University Medical Center and Faculty of Medicine, Building 9, 66421 Homburg, Saar (Germany); Aktas, O.C., E-mail: cenk.aktas@inm-gmbh.de [INM – Leibniz Institute for New Materials, CVD/Biosurfaces Group, Campus D2 2, 66123 Saarbrücken (Germany)

2014-05-01

Pulsed laser deposition (PLD) is one of the well-established physical vapor deposition methods used for synthesis of ultra-thin layers. Especially PLD is suitable for the preparation of thin films of complex alloys and ceramics where the conservation of the stoichiometry is critical. Beside several advantages of PLD, inhomogeneity in thickness limits use of PLD in some applications. There are several approaches such as rotation of the substrate or scanning of the laser beam over the target to achieve homogenous layers. On the other hand movement and transition create further complexity in process parameters. Here we present a new approach which we call Matrix Shaped PLD to control the thickness and homogeneity of deposited layers precisely. This new approach is based on shaping of the incoming laser beam by a microlens array and a Fourier lens. The beam is split into much smaller multi-beam array over the target and this leads to a homogenous plasma formation. The uniform intensity distribution over the target yields a very uniform deposit on the substrate. This approach is used to deposit carbide and oxide thin films for biomedical applications. As a case study coating of a stent which has a complex geometry is presented briefly.

ESR Dating Research of Glacial Tills in Tibetan Plateau

Science.gov (United States)

Bi, W.; Yi, C.

2016-12-01

In recent years, Quaternary Glacial-chronology has been made remarkable progress in the Tibetan Platean(TP) with the development of several numeric dating techniques, such as cosmogenic nuclides(NC), optically stimulated luminescence(OSL) and 14C. In constrast, the dating of Quaternary glacial tills in 100,000 years even more than million-year has been a challenge, just because the techniques has defects themselves and the sediments were stransformed during the geological and geomorphology progress later. Electron Spin Resonance(ESR) has been becoming one of the key methods of Quaternary Glacial-chronology with wide range of dating, expecially for the sample older than 100,000 years up to million-year scale. The accurate measurement of equivalent dose significantly impacts on accuracy and reliability of ESR dating method. Therefore, the study of the mechanisms of resetting processes is fundamental for accurate and reliable ESR dating. To understand the mechanism and characteristics of quartz ESR signal resetting of different samples, a series of laboratory simulation and field observation studies were carried out, which made lots of important breakthrough. But the research in quartz ESR signal of moraines is less and the test of ESR dating method is still in the qualitative investigation. Therefor, we use ESR dating and study on the mechanism and characteristics of quartz ESR signals in tills in the Tibetan Platean. In the adjust method of Modern, the quartz ESR signals in Modern glacial tills represent residual values which can be adjusted signals in the older glacial tills. As a consequence, ESR dating of the quartz in moraines needs to be explored in deep with building models to adjust ages which are measured by ESR dating. Therefore, ESR dating will become the trusted one of the cross dating methods in Quaternary Glacial-chronology with the adjust mothod improving the accuracy of ESR dating ages.

Spacer Thickness-Dependent Electron Transport Performance of Titanium Dioxide Thick Film for Dye-Sensitized Solar Cells

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Reda E. El-Shater

2015-01-01

Full Text Available A titanium dioxide (P25 film was deposited by cast coating as conductive photoelectrode and subsequently immersed in dye solution (N719 to fabricate the photoanode of dye-sensitized solar cells (DSSCs. A plastic spacer was used as a separation and sealant layer between the photoanode and the counter electrode. The effect of the thickness of this spacer on the transfer of electrons in the liquid electrolyte of the DSSCs was studied by means of both IV curves and electrochemical impedance. Using a spacer thickness range of 20 μm to 50 μm, efficiency ranges from 3.73% to 7.22%. The highest efficiency of 7.22% was obtained with an optimal spacer thickness of 40 μm.

Persistence of exponential bed thickness distributions in the stratigraphic record: Experiments and theory

Science.gov (United States)

Straub, K. M.; Ganti, V. K.; Paola, C.; Foufoula-Georgiou, E.

2010-12-01

Stratigraphy preserved in alluvial basins houses the most complete record of information necessary to reconstruct past environmental conditions. Indeed, the character of the sedimentary record is inextricably related to the surface processes that formed it. In this presentation we explore how the signals of surface processes are recorded in stratigraphy through the use of physical and numerical experiments. We focus on linking surface processes to stratigraphy in 1D by quantifying the probability distributions of processes that govern the evolution of depositional systems to the probability distribution of preserved bed thicknesses. In this study we define a bed as a package of sediment bounded above and below by erosional surfaces. In a companion presentation we document heavy-tailed statistics of erosion and deposition from high-resolution temporal elevation data recorded during a controlled physical experiment. However, the heavy tails in the magnitudes of erosional and depositional events are not preserved in the experimental stratigraphy. Similar to many bed thickness distributions reported in field studies we find that an exponential distribution adequately describes the thicknesses of beds preserved in our experiment. We explore the generation of exponential bed thickness distributions from heavy-tailed surface statistics using 1D numerical models. These models indicate that when the full distribution of elevation fluctuations (both erosional and depositional events) is symmetrical, the resulting distribution of bed thicknesses is exponential in form. Finally, we illustrate that a predictable relationship exists between the coefficient of variation of surface elevation fluctuations and the scale-parameter of the resulting exponential distribution of bed thicknesses.

Effect of thermal processing on silver thin films of varying thickness deposited on zinc oxide and indium tin oxide

International Nuclear Information System (INIS)

Sivaramakrishnan, K.; Ngo, A. T.; Alford, T. L.; Iyer, S.

2009-01-01

Silver films of varying thicknesses (25, 45, and 60 nm) were deposited on indium tin oxide (ITO) on silicon and zinc oxide (ZnO) on silicon. The films were annealed in vacuum for 1 h at different temperatures (300-650 deg. C). Four-point-probe measurements were used to determine the resistivity of the films. All films showed an abrupt change in resistivity beyond an onset temperature that varied with thickness. Rutherford backscattering spectrometry measurements revealed agglomeration of the Ag films upon annealing as being responsible for the resistivity change. X-ray pole figure analysis determined that the annealed films took on a preferential texturing; however, the degree of texturing was significantly higher in Ag/ZnO/Si than in Ag/ITO/Si samples. This observation was accounted for by interface energy minimization. Atomic force microscopy (AFM) measurements revealed an increasing surface roughness of the annealed films with temperature. The resistivity behavior was explained by the counterbalancing effects of increasing crystallinity and surface roughness. Average surface roughness obtained from the AFM measurements were also used to model the agglomeration of Ag based on Ostwald ripening theory

Deposition Measurements in NSTX

Science.gov (United States)

Skinner, C. H.; Kugel, H. W.; Hogan, J. T.; Wampler, W. R.

2004-11-01

Two quartz microbalances have been used to record deposition on the National Spherical Torus Experiment. The experimental configuration mimics a typical diagnostic window or mirror. An RS232 link was used to acquire the quartz crystal frequency and the deposited thickness was recorded continuously with 0.01 nm resolution. Nuclear Reaction Analysis of the deposit was consistent with the measurement of the total deposited mass from the change in crystal frequency. We will present measurements of the variation of deposition with plasma conditions. The transport of carbon impurities in NSTX has been modelled with the BBQ code. Preliminary calculations indicated a negligible fraction of carbon generated at the divertor plates in quiescent discharges directly reaches the outer wall, and that transient events are responsible for the deposition.

ESR dating of glacial tills of Baishuihe river on the southern slope of Lenglongling in the eastern part of Qilian Mountains

International Nuclear Information System (INIS)

Zhao Jingdong; Zhou Shangzhe; Shi Zhengtao; Zhang Shiqiang; Cui Jianxin; Xu Liubing; Ye Yuguang

2001-01-01

Baishuihe River is a tributary of Datong River, located on the southern slope of Lenglongling in the eastern part of the Qilian Mountains. An integral end till remains at the entrance of the valley. There is a push moraine in the till section. Three samples were derived from this section. Two samples were collected at the front of the push moraine and another sample (near the push moraine) collected from the rear of it, ESR ages were 73.0 ka, 55.8 ka, 36.7 ka respectively. The ESR ages being consistent with the relationship of deposits. The ages before the push moraine were correlated to the deep-sea oxygen isotope stage 4 within 10% deviation. Based on them, the authors could determine the till before the push moraine were formed in the early period of Last Glaciation. Comparing the ESR age of LS-5 with the results of previous 14 C, the authors found that the ESR age was older. Through the error correction, the authors concluded: the existing push moraine distorted the till around it, mixing the super-glacial till, englacial till and subglacial till together. The authors considered: the main reason influencing the ESR age was that the englacial till and the subglacial till were not exposed completely before they deposited. Although the result of LS-5 was older than the previous 14 C, combining the ESR age and the relationship of deposit and the existing 14 C ages, the authors inferred that the rear of the push moraine was deposited in the later period of the last glaciation and was correlated to the deep-sea oxygen isotope stage 2. At the same time, the conclusion once again proved the previous scholars' conclusion. This shows the ESR technique may be applied to glacial till dating

Plasma deposition by discharge in powder

International Nuclear Information System (INIS)

El-Gamal, H.A.; El-Tayeb, H.A.; Abd El-Moniem, M.; Masoud, M.M.

2000-01-01

Different types of material powders have been fed to the breach of a coaxial discharge. The coaxial discharge is powered from a 46.26 mu F, 24 KV capacitor bank. When the discharge takes place at the breach, the powder is heated and ionized to form a sheath of its material. The plasma sheath is ejected from the discharge zone with high velocity. The plasma sheath material is deposited on a glass substrate. It has been found from scanning electron microscope (SEM) analysis that the deposited material is almost homogenous for ceramic and graphite powders. The grain size is estimated to be the order of few microns. To measure the deposited material thickness the microdensitometer and a suitable arrangement of a laser interferometer and an optical microscope are used. It has also been found that deposited material thickness depends on the discharge number of shots and the capacitor bank energy

DEPOSITS AND MINING POTENTIAL OF BENTONITE IN CROATIA

Directory of Open Access Journals (Sweden)

Mario Klanfar

2012-07-01

Full Text Available Bentonite is one of the materials that is planed to be used for buffering and backfilling in spent nuclear fuel repositories, within deep crystalline rock. There are several locations in Croatia that bentonite deposits and occurrences are found on. Some were exploited in past, and others were more or less explored. This paper presents overview of bentonite deposits, basic properties and potential resources, and mining practices in Croatia. Largest exploited deposits are found in area of Poljanska luka, Gornja Jelenska and Bednja. Surface and underground methods (drift and fill, sublevel caving were used during exploitation. In the area of Svilaja and Lika are found potentially valuable deposits that were never exploited. Montmorilonite content ranges form 20-50% to 57-89%. Most deposits contain bentonite beds with thickness 0,4-1,6 m, and have plunge 10°-30°. Few exceptions are nearly horizontal and thick more than 5 m and even 12 m. One is declined at 70° and up to 40m thick. Proven reserves are about 2,3 Mt with some level of uncertainty. Average production per mine during exploitation period can be assumed to be several thousands t/y.

Glacial alteration of volcanic terrains: A chemical investigation of the Three Sisters, Oregon, USA.

Science.gov (United States)

Rutledge, Alicia; Horgan, Briony; Havig, Jeff

2017-04-01

report major anion and cation concentrations in meltwaters for the summer 2016 melt season, with emphasis on SiO2. Dissolved silica concentration (range: below detectable levels to 240 μM) tends to increase with pH (range: 4.3 to 8.5), consistent with silica solubility increasing with pH. Proglacial streams, springs, and lakes exhibit dissolved silica concentrations that are greater than observed in glacial snow/ice. The highest silica concentrations were measured in moraine-sourced springs. More mafic glaciovolcanic sites exhibit higher concentrations of dissolved silica in outwash waters compared to more felsic glaciovolcanic sites. Though basalts have lower SiO2 content than more felsic volcanic rocks, they are more susceptible to silica mobility due to their higher content of minerals such as olivine, pyroxene, and plagioclase, which are more soluble than quartz. These mineral breakdown reactions are potentially enhanced by microbial populations at the glacier bed. The measured high silica concentrations in springs are potentially due to moraines acting as sediment traps. Moraines are poorly sorted sediments with a high proportion of subglacially ground fine particles, and glacial flour further accumulates by aeolian deposition. The increased fine-grained component - and thus increased surface area - and longer residence times due to associated decreased permeability could contribute to the observed high dissolved silica concentrations.

Fabrication and characterization of vacuum deposited fluorescein thin films

Energy Technology Data Exchange (ETDEWEB)

Jalkanen, Pasi, E-mail: pasi.jalkanen@gmail.co [University of Jyvaeskylae, Department of Physics, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Kulju, Sampo, E-mail: sampo.j.kulju@jyu.f [University of Jyvaeskylae, Department of Physics, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Arutyunov, Konstantin, E-mail: konstantin.arutyunov@jyu.f [University of Jyvaeskylae, Department of Physics, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Antila, Liisa, E-mail: liisa.j.antila@jyu.f [University of Jyvaeskylae, Department of Chemistry, Nanoscience center (NSC) P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Myllyperkioe, Pasi, E-mail: pasi.myllyperkio@jyu.f [University of Jyvaeskylae, Department of Chemistry, Nanoscience center (NSC) P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Ihalainen, Teemu, E-mail: teemu.o.ihalainen@jyu.f [University of Jyvaeskylae, Department of Biology, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Kaeaeriaeinen, Tommi, E-mail: tommi.kaariainen@lut.f [Lappeenranta University of Technology, ASTRal, P.O. Box 181, FI-50101 Mikkeli (Finland); Kaeaeriaeinen, Marja-Leena, E-mail: marja-leena.kaariainen@lut.f [Lappeenranta University of Technology, ASTRal, P.O. Box 181, FI-50101 Mikkeli (Finland); Korppi-Tommola, Jouko, E-mail: jouko.korppi-tommola@jyu.f [University of Jyvaeskylae, Department of Biology, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland)

2011-03-31

Simple vacuum evaporation technique for deposition of dyes on various solid surfaces has been developed. The method is compatible with conventional solvent-free nanofabrication processing enabling fabrication of nanoscale optoelectronic devices. Thin films of fluorescein were deposited on glass, fluorine-tin-oxide (FTO) coated glass with and without atomically layer deposited (ALD) nanocrystalline 20 nm thick anatase TiO{sub 2} coating. Surface topology, absorption and emission spectra of the films depend on their thickness and the material of supporting substrate. On a smooth glass surface the dye initially forms islands before merging into a uniform layer after 5 to 10 monolayers. On FTO covered glass the absorption spectra are similar to fluorescein solution in ethanol. Absorption spectra on ALD-TiO{sub 2} is red shifted compared to the film deposited on bare FTO. The corresponding emission spectra at {lambda} = 458 nm excitation show various thickness and substrate dependent features, while the emission of films deposited on TiO{sub 2} is quenched due to the effective electron transfer to the semiconductor conduction band.

The George V Land Continental Margin (East Antarctica): new Insights Into Bottom Water Production and Quaternary Glacial Processes from the WEGA project

Science.gov (United States)

Caburlotto, A.; de Santis, L.; Lucchi, R. G.; Giorgetti, G.; Damiani, D.; Macri', P.; Tolotti, R.; Presti, M.; Armand, L.; Harris, P.

2004-12-01

The George Vth Land represents the ending of one of the largest subglacial basin (Wilkes Basin) of the East Antarctic Ice Sheet (EAIS). Furthermore, its coastal areas are zone of significant production of High Salinity Shelf Water (HSSW). Piston and gravity cores and high resolution echo-sounding (3.5 kHz) and Chirp profiles collected in the frame of the joint Australian and Italian WEGA (WilkEs Basin GlAcial History) project provide new insights into the Quaternary history of the EAIS and the HSSW across this margin: from the sediment record filling and draping valleys and banks along the continental shelf, to the continuous sedimentary section of the mound-channel system on the continental rise. The discovery of a current-lain sediment drift (Mertz Drift, MD) provides clues to understanding the age of the last glacial erosive events, as well as to infer flow-pathways of bottom-water masses changes. The MD shows disrupted, fluted reflectors due to glacial advance during the LGM (Last Glacial Maximum) in shallow water, while undisturbed sediment drift deposited at greater water depth, indicates that during the LGM the ice shelf was floating over the deep sector of the basin. The main sedimentary environment characterising the modern conditions of the continental rise is dominated by the turbiditic processes with a minor contribution of contour currents action. Nevertheless, some areas (WEGA Channel) are currently characterised by transport and settling of sediment through HSSW, originating in the shelf area. This particular environment likely persisted since pre-LGM times. It could indicate a continuous supply of sedimentary material from HSSW during the most recent both glacial and interglacial cycles. This would be consistent with the results obtained in the continental shelf suggesting that the Ice Sheet was not grounding over some parts of the continental shelf. Furthermore, the comparison of the studied area with other Antarctic margins indicate that, contrary

Design and spectroscopic reflectometry characterization of pulsed laser deposition combinatorial libraries

International Nuclear Information System (INIS)

Schenck, Peter K.; Bassim, Nabil D.; Otani, Makoto; Oguchi, Hiroyuki; Green, Martin L.

2007-01-01

The goal of the design of pulsed laser deposition (PLD) combinatorial library films is to optimize the compositional coverage of the films while maintaining a uniform thickness. The deposition pattern of excimer laser PLD films can be modeled with a bimodal cos n distribution. Deposited films were characterized using a spectroscopic reflectometer (250-1000 nm) to map the thickness of both single composition calibration films and combinatorial library films. These distribution functions were used to simulate the composition and thickness of multiple target combinatorial library films. The simulations were correlated with electron-probe microanalysis wavelength-dispersive spectroscopy (EPMA-WDS) composition maps. The composition and thickness of the library films can be fine-tuned by adjusting the laser spot size, fluence, background gas pressure, target geometry and other processing parameters which affect the deposition pattern. Results from compositionally graded combinatorial library films of the ternary system Al 2 O 3 -HfO 2 -Y 2 O 3 are discussed

Electroplated thick-film cobalt platinum permanent magnets

Energy Technology Data Exchange (ETDEWEB)

Oniku, Ololade D.; Qi, Bin; Arnold, David P., E-mail: darnold@ufl.edu

2016-10-15

The material and magnetic properties of multi-micron-thick (up to 6 μm) L1{sub 0} CoPt magnetic films electroplated onto silicon substrates are investigated as candidate materials for integration in silicon-based microsystems. The influence of various process conditions on the structure and magnetic properties of electroplated CoPt thick-films is studied in order to better understand the complex process/structure/property relationships associated with the electroplated films. Process variables studied here include different seed layers, electroplating current densities (ranging from 25–200 mA/cm{sup 2}), deposition times (up to 60 min), and post-deposition annealing times and temperatures. Analyses include film morphology, film thickness, composition, surface roughness, grain size, phase volume fractions, and L1{sub 0} ordering parameter. Key correlations are found relating process and structure variations to the extrinsic magnetic properties (remanence, coercivity, squareness, and energy product). Strong hard magnetic properties (B{sub r} ~0.8 T, H{sub ci} ~800 kA/m, squareness close to 0.9, and BH{sub max} of 100 kJ/m{sup 3}) are obtained for films deposited on Si/TiN/Ti/Cu at current densities of 100 mA/cm{sup 2}, pH of 7, and subsequently annealed at 675 °C for 30 min. - Highlights: • CoPt films plated up to 6 μm thick on silicon substrates. • A1 to L1{sub 0} phase transformation by annealing in forming gas. • Various process–structure–property relationships explored. • Key results: B{sub r} ~0.8 T, H{sub ci} ~800 kA/m, squareness 0.9, and BH{sub max} ~100 kJ/m{sup 3}.

Alpine glacial topography and the rate of rock column uplift

DEFF Research Database (Denmark)

Pedersen, Vivi Kathrine; Egholm, D.L.; Nielsen, S.B.

2010-01-01

The present study investigates the influence of alpine glacial erosion on the morphology and relief distribution of mountain regions associated with varying rock column uplift rates. We take a global approach and analyse the surface area distribution of all mountain regions affected by glacial er...

Depositional evolution of the Melville Bay trough-mouth fan, NW Greenland

Science.gov (United States)

Knutz, Paul; Gregersen, Ulrik

2015-04-01

The continental margin of NW Greenland bordering northern Baffin Bay is characterized by major sediment accumulations, known as Trough-Mouth Fans (TMF). The fan depocentres represent intense sediment dispersal at the terminus of ice streams that during cold climate periods provided major drainage routes of the northern Greenland Ice Sheet into Baffin Bay. The imprint of paleo-icestreams is seen by erosional troughs crossing a >250 km broad shelf region, which caps a series of sedimentary basins containing thick Mesozoic-Tertiary strata packages. This presentation provides an overview of the seismic stratigraphic division, depositional architecture and examples of seismic facies of the Melville Bay TMF using a 5-10 km grid of industry-quality 2D seismic data (TGS). The focus will primarily be on the inception and early stage of glacial fan development. Comparing the present-day topography with the regional geology shows that the paleo-icestreams exploited the Cenozoic infill of former rift basins that are more conducive to erosion than the adjoining ridges and structural highs. The TMF sequence is constructed by a series of progradational seismic units that represent successive steps in location of ice stream terminus and associated depocenters. The slope fronts of the prograding units show abundant signatures of sediment instability and mass-wasting but evidence of along-slope current-driven processes is also recognized presumably linked to interglacial sea level high-stands. The topset of each unit is characterized by planar erosion that merges landward into hummocky positive geometries with low internal reflectivity. These features are generally interpreted as subglacial landforms, e.g. terminal moraines and ice-contact deposits, associated with grounding zone wedges. Unlike the most recent TMF units deposited in front of the present trough, the oldest glacigenic units have built out from a Neogene sediment prism that forms the core of modern shallow-water banks

Glacial ocean circulation and stratification explained by reduced atmospheric temperature.

Science.gov (United States)

Jansen, Malte F

2017-01-03

Earth's climate has undergone dramatic shifts between glacial and interglacial time periods, with high-latitude temperature changes on the order of 5-10 °C. These climatic shifts have been associated with major rearrangements in the deep ocean circulation and stratification, which have likely played an important role in the observed atmospheric carbon dioxide swings by affecting the partitioning of carbon between the atmosphere and the ocean. The mechanisms by which the deep ocean circulation changed, however, are still unclear and represent a major challenge to our understanding of glacial climates. This study shows that various inferred changes in the deep ocean circulation and stratification between glacial and interglacial climates can be interpreted as a direct consequence of atmospheric temperature differences. Colder atmospheric temperatures lead to increased sea ice cover and formation rate around Antarctica. The associated enhanced brine rejection leads to a strongly increased deep ocean stratification, consistent with high abyssal salinities inferred for the last glacial maximum. The increased stratification goes together with a weakening and shoaling of the interhemispheric overturning circulation, again consistent with proxy evidence for the last glacial. The shallower interhemispheric overturning circulation makes room for slowly moving water of Antarctic origin, which explains the observed middepth radiocarbon age maximum and may play an important role in ocean carbon storage.

Electrochemical Sensor Coating Based on Electrophoretic Deposition of Au-Doped Self-Assembled Nanoparticles.

Science.gov (United States)

Zhang, Rongli; Zhu, Ye; Huang, Jing; Xu, Sheng; Luo, Jing; Liu, Xiaoya

2018-02-14

The electrophoretic deposition (EPD) of self-assembled nanoparticles (NPs) on the surface of an electrode is a new strategy for preparing sensor coating. By simply changing the deposition conditions, the electrochemical response for an analyte of deposited NPs-based coating can be controlled. This advantage can decrease the difference between different batches of sensor coating and ensure the reproducibility of each sensor. This work investigated the effects of deposition conditions (including deposition voltage, pH value of suspension, and deposition time) on the structure and the electrochemical response for l-tryptophan of sensor coating formed from Au-doped poly(sodium γ-glutamate) with pendant dopamine units nanohybrids (Au/γ-PGA-DA NBs) via the EPD method. The structure and thickness of the deposited sensor coating were measured by atomic force microscopy, which demonstrated that the structure and thickness of coating can be affected by the deposition voltage, the pH value of the suspension, and the deposition time. The responsive current for l-tryptophan of the deposited sensor coating were measured by differential pulse voltammetry, which showed that the responsive current value was affected by the structure and thickness of the deposited coating. These arguments suggested that a rich design-space for tuning the electrochemical response for analyte and a source of variability in the structure of sensor coating can be provided by the deposition conditions. When Au/γ-PGA-DA NBs were deposited on the electrode surface and formed a continuous coating with particle morphology and thinner thickness, the deposited sensor coating exhibited optimal electrochemical response for l-tryptophan.

A glacial record of the last termination in the southern tropical Andes

Science.gov (United States)

Bromley, G. R.; Schaefer, J. M.; Winckler, G.; Hall, B. L.; Todd, C. E.; Rademaker, K.

2012-12-01

The last glacial termination represents the highest-magnitude climate change of the last hundred thousand years. Accurate resolution of events during the termination is vital to our understanding of how - and why - the global climate system transitions from a full glacial to interglacial state, as well as the causes of abrupt climate change during the late-glacial period. Palaeoclimate data from low latitudes, though relatively sparse, are particularly valuable, since the tropical ocean and atmosphere likely play a crucial role in Quaternary climate variability on all timescales. We present a detailed glacier record from the Andes of southern Peru (15°S), resolved with 3He surface-exposure dating and spanning the last glacial maximum and termination. Our dataset reveals that glaciers in this part of the Southern Hemisphere maintained their Late Pleistocene maxima for several millennia and that the onset of the termination may have occurred relatively late. Deglaciation was punctuated by two major advances during the late-glacial period. Following the glacial-interglacial transition, our preliminary chronologic and morphologic data suggest that, in contrast to the Northern Hemisphere, glaciers in the southern tropical Andes have experienced overall shrinkage during the Holocene.

Magnetic properties and microstructure investigation of electrodeposited FeNi/ITO films with different thickness

International Nuclear Information System (INIS)

Cao, Derang; Wang, Zhenkun; Feng, Erxi; Wei, Jinwu; Wang, Jianbo; Liu, Qingfang

2013-01-01

Highlights: •FeNi alloy thin films with different thickness deposited on Indium Tin Oxides (ITOs) conductive glass substrates by electrodeposition method. •A columnar crystalline microstructure and domain structure were obtained in FeNi thin films. •Particular FMR spectra of FeNi alloy with different thickness were studied. -- Abstract: FeNi alloy thin films with different thickness deposited on Indium Tin Oxides (ITOs) conductive glass substrates from the electrolytes by electrodeposition method have been studied by magnetic force microscopy (MFM), scanning electron microscopy (SEM) and ferromagnetic resonance (FMR) technique. For these films possessing an in-plane isotropy, the remanence decreases with the increasing of film thickness and the critical thickness that a stripe domain structure emerges is about 116 nm. Characteristic differences of the FMR spectra of different thickness are also observed. The results show that the resonance field at high measured angle increases firstly then decreases with increasing thickness, which may be related to the striped domain structure

Effects of glacial meltwater on corrosion of copper canisters

International Nuclear Information System (INIS)

Ahonen, L.; Vieno, T.

1994-08-01

The composition of glacial meltwater and its reactions in the bedrock are examined. The evidences that there are or should be from past intrusions of glacial meltwater and oxygen deep in the bedrock are also considered. The study is concluded with an evaluation of the potential effects of oxygenated meltwater on the corrosion of copper canisters. (46 refs., 3 figs., 2 tabs.)

76 FR 50476 - Application To Export Electric Energy; Glacial Energy of Texas, Inc.

Science.gov (United States)

2011-08-15

... DEPARTMENT OF ENERGY [OE Docket No. EA-382] Application To Export Electric Energy; Glacial Energy... Application. SUMMARY: Glacial Energy of Texas, Inc. (Glacial) has applied for authority to transmit electric... for authority to transmit electric energy from the United States to Mexico for five years as a power...

Postglacial development of the eastern Gulf of Finland: from Pleistocene glacial lake basins to Holocene lagoon systems

Science.gov (United States)

Ryabchuk, Daria; Sergeev, Alexander; Kotilainen, Aarno; Hyttinen, Outi; Grigoriev, Andrey; Gerasimov, Dmitry; Anisimov, Mikhail; Gusentsova, Tatiana; Zhamoida, Vladimir; Amantov, Aleksey; Budanov, Leonid

2016-04-01

Despite significant amount of data, there are still lots of debatable questions and unsolved problems concerning postglacial geological history of the Eastern Gulf of Finland, the Baltic Sea. Among these problems are: 1) locations of the end moraine and glacio-fluvial deposits; 2) time and genesis of the large accretion forms (spits, bars, dunes); 3) basinwide correlations of trangression/regression culminations with the other parts of the Baltic Sea basin; 4) study of salinity, timing, frequency and intensity of Holocene saline water inflows and their links of sedimentation processes associated with climate change. Aiming to receive new data about regional postglacial development, the GIS analyses of bottom relief and available geological and geophysical data was undertaken, the maps of preQuaternary relief, moraine and Late Pleistocene surfaces, glacial moraine and Holocene sediments thicknesses were compiled. High-resolution sediment proxy study of several cores, taken from eastern Gulf of Finland bottom, allows to study grain-size distribution and geochemical features of glacial lake and Holocene sediments, to reveal sedimentation rates and paleoenvironment features of postglacial basins. Interdisciplinary geoarcheological approaches offer new opportunities for studying the region's geological history and paleogeography. Based on proxy marine geological and coastal geoarcheological studies (e.g. off-shore acoustic survey, side-scan profiling and sediment sampling, on-shore ground-penetrating radar (GPR SIR 2000), leveling, drilling, grain-size analyses and radiocarbon dating and archeological research) detailed paleogeographical reconstruction for three micro-regions - Sestroretsky and Lahta Lowlands, Narva-Luga Klint Bay and Southern Ladoga - were compiled. As a result, new high resolution models of Holocene geological development of the Eastern Gulf of Finland were received. Model calibration and verification used results from proxy geoarcheological research

Nearshore sediment thickness, Fire Island, New York

Science.gov (United States)

Locker, Stanley D.; Miselis, Jennifer L.; Buster, Noreen A.; Hapke, Cheryl J.; Wadman, Heidi M.; McNinch, Jesse E.; Forde, Arnell S.; Stalk, Chelsea A.

2017-04-03

Investigations of coastal change at Fire Island, New York (N.Y.), sought to characterize sediment budgets and determine geologic framework controls on coastal processes. Nearshore sediment thickness is critical for assessing coastal system sediment availability, but it is largely unquantified due to the difficulty of conducting geological or geophysical surveys across the nearshore. This study used an amphibious vessel to acquire chirp subbottom profiles. These profiles were used to characterize nearshore geology and provide an assessment of nearshore sediment volume. Two resulting sediment-thickness maps are provided: total Holocene sediment thickness and the thickness of the active shoreface. The Holocene sediment section represents deposition above the maximum flooding surface that is related to the most recent marine transgression. The active shoreface section is the uppermost Holocene sediment, which is interpreted to represent the portion of the shoreface thought to contribute to present and future coastal behavior. The sediment distribution patterns correspond to previously defined zones of erosion, accretion, and stability along the island, demonstrating the importance of sediment availability in the coastal response to storms and seasonal variability. The eastern zone has a thin nearshore sediment thickness, except for an ebb-tidal deposit at the wilderness breach caused by Hurricane Sandy. Thicker sediment is found along a central zone that includes shoreface-attached sand ridges, which is consistent with a stable or accretional coastline in this area. The thickest overall Holocene section is found in the western zone of the study, where a thicker lower section of Holocene sediment appears related to the westward migration of Fire Island Inlet over several hundred years.

Invariance of the carbonate chemistry of the South China Sea from the glacial period to the Holocene and its implications to the Pacific Ocean carbonate system

Science.gov (United States)

Luo, Yiming; Kienast, Markus; Boudreau, Bernard P.

2018-06-01

Substantial and correlated changes in marine carbonate (CaCO3) content of oceanic sediments commonly accompany the transitions from cold glacial periods to warm interglacial periods. The South China Sea (SCS) is said to be ocean-dominated at depth, and its CaCO3 records should reflect and preserve the effects of changes in the carbonate chemistry of the (western) Pacific Ocean. Using published and newly acquired CaCO3 data and a model for carbonate compensation dynamics, we show that a significant change with respect to carbonate saturation is unlikely to have occurred in the SCS during the last glacial-interglacial transition. Instead, the results from a carbonate deposition model argue that the saturation state of the SCS was largely invariant; a separate diagenetic model argues that changes in sediment CaCO3 content can be explained by alterations in lithogenic input. In turn, this could indicate that the carbonate ion concentration of the (western) Pacific at depths shallower than the sill to the SCS (ca. 2,400 m) has not changed appreciably between the last glacial period and the present interglacial.

The influence of fiber thickness, wall thickness and gap distance on the spiral nanofibrous scaffolds for bone tissue engineering

International Nuclear Information System (INIS)

Wang Junping; Shah, Ami; Yu Xiaojun

2011-01-01

We have developed a 3D nanofibrous spiral scaffold for bone tissue engineering which has shown enhanced cell attachment, proliferation and differentiation compared to traditional cylindrical scaffolds due to the spiral structures and the nanofiber incorporation. Some important parameters of these spiral scaffolds including gap distance, wall thickness and especially fiber thickness are crucial to the performance of the spiral structured scaffolds. In this study, we investigated the fiber thickness, gap distance and wall thickness of the spiral structure on the behavior of osteoblast cells. The human osteoblast cells are seeded on spiral structured scaffolds with various fiber thickness, gap distance and wall thickness and cell attachment, proliferation, differentiation and mineralized matrix deposition on the scaffolds are evaluated. It was found that increasing the thickness of nanofiber layer not only limited the cell infiltration into the scaffolds, but also restrained the osteoblastic cell phenotype development. Moreover, the geometric effect studies indicated that scaffolds with the thinner wall and gap distance 0.2 mm show the best bioactivity for osteoblasts.

Deposition of selenium coatings on beryllium foils. Revision 1

International Nuclear Information System (INIS)

Erikson, E.D.; Tassano, P.L.; Reiss, R.H.; Griggs, G.E.

1984-01-01

A technique for preparing selenium films on 50.8 micrometers thick beryllium foils is described. The selenium was deposited in vacuum from a resistance heated evaporation source. A water-cooled enclosure was used to minimize contamination of the vacuum system and to reduce the exposure of personnel to toxic and obnoxious materials. Profilometry measurements of the coatings indicated selenium thicknesses of 5.5, 12.9, 37.5, 49.8 and 74.5 micrometers. The control of deposition rate and of coating thickness was facilitated using a commercially available closed-loop programmable deposition controller. The x-ray transmission of the coated substrates was measured using a tritiated zirconium source. The transmissivities of the film/substrate combination are presented for the range of energies from 4 to 20 keV

Evolution of optical constants of silicon dioxide on silicon from ultrathin films to thick films

Energy Technology Data Exchange (ETDEWEB)

Cai Qingyuan; Zheng Yuxiang; Mao Penghui; Zhang Rongjun; Zhang Dongxu; Liu Minghui; Chen Liangyao, E-mail: yxzheng@fudan.edu.c [Key Laboratory of Micro and Nano Photonic Structures, Ministry of Education, Department of Optical Science and Engineering, Fudan University, Shanghai 200433 (China)

2010-11-10

A series of SiO{sub 2} films with thickness range 1-600 nm have been deposited on crystal silicon (c-Si) substrates by electron beam evaporation (EBE) method. Variable-angle spectroscopic ellipsometry (VASE) in combination with a two-film model (ambient-oxide-interlayer substrate) was used to determine the optical constants and thicknesses of the investigated films. The refractive indices of SiO{sub 2} films thicker than 60 nm are close to those of bulk SiO{sub 2}. For the thin films deposited at the rate of {approx}1.0 nm s{sup -1}, the refractive indices increase with decreasing thickness from {approx}60 to {approx}10 nm and then drop sharply with decreasing thickness below {approx}10 nm. However, for thin films deposited at the rates of {approx}0.4 and {approx}0.2 nm s{sup -1}, the refractive indices monotonically increase with decreasing thickness below 60 nm. The optical constants of the ultrathin film depend on the morphology of the film, the stress exerted on the film, as well as the stoichiometry of the oxide film.

Evolution of optical constants of silicon dioxide on silicon from ultrathin films to thick films

International Nuclear Information System (INIS)

Cai Qingyuan; Zheng Yuxiang; Mao Penghui; Zhang Rongjun; Zhang Dongxu; Liu Minghui; Chen Liangyao

2010-01-01

A series of SiO 2 films with thickness range 1-600 nm have been deposited on crystal silicon (c-Si) substrates by electron beam evaporation (EBE) method. Variable-angle spectroscopic ellipsometry (VASE) in combination with a two-film model (ambient-oxide-interlayer substrate) was used to determine the optical constants and thicknesses of the investigated films. The refractive indices of SiO 2 films thicker than 60 nm are close to those of bulk SiO 2 . For the thin films deposited at the rate of ∼1.0 nm s -1 , the refractive indices increase with decreasing thickness from ∼60 to ∼10 nm and then drop sharply with decreasing thickness below ∼10 nm. However, for thin films deposited at the rates of ∼0.4 and ∼0.2 nm s -1 , the refractive indices monotonically increase with decreasing thickness below 60 nm. The optical constants of the ultrathin film depend on the morphology of the film, the stress exerted on the film, as well as the stoichiometry of the oxide film.

Oxygen Barrier Coating Deposited by Novel Plasma-enhanced Chemical Vapor Deposition

DEFF Research Database (Denmark)

Jiang, Juan; Benter, M.; Taboryski, Rafael Jozef

2010-01-01

We report the use of a novel plasma-enhanced chemical vapor deposition chamber with coaxial electrode geometry for the SiOx deposition. This novel plasma setup exploits the diffusion of electrons through the inner most electrode to the interior samples space as the major energy source. This confi......We report the use of a novel plasma-enhanced chemical vapor deposition chamber with coaxial electrode geometry for the SiOx deposition. This novel plasma setup exploits the diffusion of electrons through the inner most electrode to the interior samples space as the major energy source...... effect of single-layer coatings deposited under different reaction conditions was studied. The coating thickness and the carbon content in the coatings were found to be the critical parameters for the barrier property. The novel barrier coating was applied on different polymeric materials...

Thermal plasma chemical vapor deposition

International Nuclear Information System (INIS)

Heberlein, J.; Pfender, E.

1993-01-01

Thermal plasmas, with temperatures up to and even exceeding 10 4 K, are capable of producing high density vapor phase precursors for the deposition of relatively thick films. Although this technology is still in its infancy, it will fill the void between the relatively slow deposition processes such as physical vapor deposition and the high rate thermal spray deposition processes. In this chapter, the present state-of-the-art of this field is reviewed with emphasis on the various types of reactors proposed for this emerging technology. Only applications which attracted particular attention, namely diamond and high T c superconducting film deposition, are discussed in greater detail. (orig.)

Glacial evolution of the Ampato Volcanic Complex (Peru)

Science.gov (United States)

Alcalá, J.; Palacios, D.; Zamorano, J. J.; Vázquez, L.

2009-04-01

Ice masses on the Western range of the Central Andes are a main source of water resources and act as a geoindicator of variations in the climate of the tropics (Mark, 2008). The study of their evolution is of particular interest since they are situated in the transition zone between the tropical and mid-latitude circulation areas of the atmosphere (Zech et al., 2007). The function of this transition area is currently under debate, and understanding it is essential for the development of global climate models (Kull et al, 2008; Mark, 2008). However our understanding of the evolution of glaciers and their paleoclimatic factors for this sector of the Central Andes is still at a very basic level. This paper presents initial results of a study on the glacial evolution of the Ampato volcanic complex (15°24´- 15° 51´ S, 71° 51´ - 73° W; 6288 m a.s.l.) located in the Western Range of the Central Andes in Southern Peru, 70 km NW of the city of Arequipa. The main objectives are to identify the number of glacial phases the complex has undergone using geomorphological criteria to define a time frame for each phase, based on cosmogenic 36Cl dating of a sequence of moraine deposits; and to estimate the glacier Equilibrium Line Altitude (ELA) of each phase. The Ampato volcanic complex is formed by 3 great andesitic stratovolcanoes, the Nevados HualcaHualca-Sabancaya-Ampato, which started forming between the late Miocene and early Quaternary (Bulmer et al., 1999), aligned N-S and with summits covered with glaciers. The Sabancaya volcano is fully active, with its latest eruption occurring in 2001. Glacial landforms were identified and mapped using photointerpretation of vertical aerial photographs from 1955 (1:35,000 scale, National Geographic Institute of Peru), oblique photographs from 1943 (Aerophotographical Service of Peru), and a geo-referenced high-resolution Mrsid satellite image from 2000 (NASA). This cartography was corrected and improved through fieldwork. It was

Optimal tuning of a GCM using modern and glacial constraints

Energy Technology Data Exchange (ETDEWEB)

Gregoire, Lauren J.; Valdes, Paul J.; Payne, Antony J.; Kahana, Ron [University of Bristol, School of Geographical Sciences, Bristol (United Kingdom)

2011-08-15

In climate models, many parameters used to resolve subgrid scale processes can be adjusted through a tuning exercise to fit the model's output to target climatologies. We present an objective tuning of a low resolution Atmosphere-Ocean General Circulation Model (GCM) called FAMOUS where ten model parameters are varied together using a Latin hypercube sampling method to create an ensemble of 100 models. The target of the tuning consists of a wide range of modern climate diagnostics and also includes glacial tropical sea surface temperature. The ensemble of models created is compared to the target using an Arcsin Mielke score. We investigate how the tuning method used and the addition of glacial constraints impact on the present day and glacial climates of the chosen models. Rather than selecting a single configuration which optimises the metric in all the diagnostics, we obtain a subset of nine 'good' models which display great differences in their climate but which, in some sense, are all better than the original configuration. In those simulations, the global temperature response to last glacial maximum forcings is enhanced compared to the control simulation and the glacial Atlantic Ocean circulation is more in agreement with observations. Our study demonstrates that selecting a single 'optimal' configuration, relying only on present day constraints may lead to misrepresenting climates different to that of today. (orig.)

Using Seismic Refraction and Ground Penetrating Radar (GPR) to Characterize the Valley Fill in Beaver Meadows, Rocky Mountain National Park

Science.gov (United States)

Kramer, N.; Harry, D. L.; Wohl, E. E.

2010-12-01

This study is one of the first to use near surface geophysical techniques to characterize the subsurface stratigraphy in a high alpine, low gradient valley with a past glacial history and to obtain a preliminary grasp on the impact of Holocene beaver activity. Approximately 1 km of seismic refraction data and 5 km of GPR data were collected in Beaver Meadows, Rocky Mountain National Park. An asymmetric wedge of sediment ranging in depth from 0-20 m transverse to the valley profile was identified using seismic refraction. Complementary analysis of the GPR data suggests that the valley fill can be subdivided into till deposited during the Pleistocene glaciations and alluvium deposited during the Holocene. Two main facies were identified in the GPR profiles through pattern recognition. Facie Fd, which consists of chaotic discontinuous reflectors with an abundance of diffractions, is interpreted to be glacial till. Facie Fc, which is a combination of packages of complex slightly continuous reflectors interfingered with continuous horizontal to subhorizontal reflectors, is interpreted to be post-glacial alluvium and includes overbank, pond and in-channel deposits. Fc consistently overlies Fd throughout the study area and is no more than 7 m thick in the middle of the valley. The thickness of Holocene sedimentation (beaver dams, a high abundance of fine sediment including silts and clays, historical records of beavers, and the name "Beaver Meadows" all suggest that Holocene beaver activity played a large role in sediment accumulation at this site, despite the lack of surficial relict beaver dams containing wood.

Lithosphere and upper-mantle structure of the southern Baltic Sea estimated from modelling relative sea-level data with glacial isostatic adjustment

Science.gov (United States)

Steffen, H.; Kaufmann, G.; Lampe, R.

2014-06-01

During the last glacial maximum, a large ice sheet covered Scandinavia, which depressed the earth's surface by several 100 m. In northern central Europe, mass redistribution in the upper mantle led to the development of a peripheral bulge. It has been subsiding since the begin of deglaciation due to the viscoelastic behaviour of the mantle. We analyse relative sea-level (RSL) data of southern Sweden, Denmark, Germany, Poland and Lithuania to determine the lithospheric thickness and radial mantle viscosity structure for distinct regional RSL subsets. We load a 1-D Maxwell-viscoelastic earth model with a global ice-load history model of the last glaciation. We test two commonly used ice histories, RSES from the Australian National University and ICE-5G from the University of Toronto. Our results indicate that the lithospheric thickness varies, depending on the ice model used, between 60 and 160 km. The lowest values are found in the Oslo Graben area and the western German Baltic Sea coast. In between, thickness increases by at least 30 km tracing the Ringkøbing-Fyn High. In Poland and Lithuania, lithospheric thickness reaches up to 160 km. However, the latter values are not well constrained as the confidence regions are large. Upper-mantle viscosity is found to bracket [2-7] × 1020 Pa s when using ICE-5G. Employing RSES much higher values of 2 × 1021 Pa s are obtained for the southern Baltic Sea. Further investigations should evaluate whether this ice-model version and/or the RSL data need revision. We confirm that the lower-mantle viscosity in Fennoscandia can only be poorly resolved. The lithospheric structure inferred from RSES partly supports structural features of regional and global lithosphere models based on thermal or seismological data. While there is agreement in eastern Europe and southwest Sweden, the structure in an area from south of Norway to northern Germany shows large discrepancies for two of the tested lithosphere models. The lithospheric

Multiple glacial culminations from the Lateglacial to the late Holocene in central and southern Peru (Invited)

Science.gov (United States)

Licciardi, J. M.; Schaefer, J. M.; Rodbell, D. T.; Stansell, N.; Schweinsberg, A.; Finkel, R. C.; Zimmerman, S. R.

2013-12-01

Fluctuations in small tropical mountain glaciers serve as sensitive indicators of variations in past and present-day climate. Most of the world's modern tropical glaciers reside in the Peruvian Andes, where a growing number of well-dated glacial records have recently been developed. As additional records are documented, regional patterns of late Pleistocene to Holocene glacial activity have begun to emerge. Here we present a compilation of new and previously obtained 10Be surface exposure ages from boulders on well-preserved moraine successions in two glaciated Andean ranges: the Cordillera Vilcabamba of southern Peru (13°20'S, 72°32'W) and the Huaguruncho massif (10°32'S, 75°56'W), located in central Peru ~450 km northwest of the Vilcabamba. A high-resolution composite chronology that merges >100 10Be measurements on moraine sequences in five glaciated drainages of the Cordillera Vilcabamba reveals the occurrence of at least five discrete glacial culminations from the Lateglacial to the late Holocene. At the Huaguruncho massif, >20 10Be exposure ages obtained from moraine sequences in a south-facing cirque indicate at least three major glacial stages spanning the Lateglacial to the Little Ice Age. The moraine ages at Huaguruncho are broadly correlative with the Vilcabamba moraine chronologies, with some dated moraine belts exhibiting geomorphic expressions that closely resemble those of their coeval counterparts in the Vilcabamba. A recurring finding in both field areas is a mismatch between basal radiocarbon ages from bog and lake sediments and 10Be exposure ages on outboard moraines, which enclose the depositional basins. These age discrepancies suggest that cosmogenic 10Be production rates scaled to high altitudes in the tropics are substantially lower than previous estimates. While we anticipate that future refinements to scaled isotope production rates may significantly affect correlation of 10Be exposure ages in the high Andes with ages derived from

ITO thin films deposited by advanced pulsed laser deposition

International Nuclear Information System (INIS)

Viespe, Cristian; Nicolae, Ionut; Sima, Cornelia; Grigoriu, Constantin; Medianu, Rares

2007-01-01

Indium tin oxide thin films were deposited by computer assisted advanced PLD method in order to obtain transparent, conductive and homogeneous films on a large area. The films were deposited on glass substrates. We studied the influence of the temperature (room temperature (RT)-180 deg. C), pressure (1-6 x 10 -2 Torr), laser fluence (1-4 J/cm 2 ) and wavelength (266-355 nm) on the film properties. The deposition rate, roughness, film structure, optical transmission, electrical conductivity measurements were done. We deposited uniform ITO thin films (thickness 100-600 nm, roughness 5-10 nm) between RT and 180 deg. C on a large area (5 x 5 cm 2 ). The films have electrical resistivity of 8 x 10 -4 Ω cm at RT, 5 x 10 -4 Ω cm at 180 deg. C and an optical transmission in the visible range, around 89%

Reconstructing temperatures in the Maritime Alps, Italy, since the Last Glacial Maximum using cosmogenic noble gas paleothermometry

Science.gov (United States)

Tremblay, Marissa; Spagnolo, Matteo; Ribolini, Adriano; Shuster, David

2016-04-01

The Gesso Valley, located in the southwestern-most, Maritime portion of the European Alps, contains an exceptionally well-preserved record of glacial advances during the late Pleistocene and Holocene. Detailed geomorphic mapping, geochronology of glacial deposits, and glacier reconstructions indicate that glaciers in this Mediterranean region responded to millennial scale climate variability differently than glaciers in the interior of the European Alps. This suggests that the Mediterranean Sea somehow modulated the climate of this region. However, since glaciers respond to changes in temperature and precipitation, both variables were potentially influenced by proximity to the Sea. To disentangle the competing effects of temperature and precipitation changes on glacier size, we are constraining past temperature variations in the Gesso Valley since the Last Glacial Maximum (LGM) using cosmogenic noble gas paleothermometry. The cosmogenic noble gases 3He and 21Ne experience diffusive loss from common minerals like quartz and feldspars at Earth surface temperatures. Cosmogenic noble gas paleothermometry utilizes this open-system behavior to quantitatively constrain thermal histories of rocks during exposure to cosmic ray particles at the Earth's surface. We will present measurements of cosmogenic 3He in quartz sampled from moraines in the Gesso Valley with LGM, Bühl stadial, and Younger Dryas ages. With these 3He measurements and experimental data quantifying the diffusion kinetics of 3He in quartz, we will provide a preliminary temperature reconstruction for the Gesso Valley since the LGM. Future work on samples from younger moraines in the valley system will be used to fill in details of the more recent temperature history.

A remote coal deposit revisited

DEFF Research Database (Denmark)

Bojesen-Kofoed, Jørgen A.; Kalkreuth, Wolfgang; Petersen, Henrik I.

2012-01-01

discovery. The outcrops found in 2009 amount to approximately 8 m of sediment including a coal seam of 2 m thickness. More outcrops and additional coal deposits most certainly are to be found, pending further fieldwork. The deposits are Middle Jurassic, Callovian, in age and were deposited in a floodplain...... environment related to meandering river channels. Spores and pollen in the lower fluvial deposits reflect abundant vegetation of ferns along the river banks. In contrast, a sparse spore and pollen flora in the coals show a mixed vegetation of ferns and gymnosperms. Based on proximate and petrographic analyses...

Nano-crystalline thin and nano-particulate thick TiO2 layer: Cost effective sequential deposition and study on dye sensitized solar cell characteristics

International Nuclear Information System (INIS)

Das, P.; Sengupta, D.; Kasinadhuni, U.; Mondal, B.; Mukherjee, K.

2015-01-01

Highlights: • Thin TiO 2 layer is deposited on conducting substrate using sol–gel based dip coating. • TiO 2 nano-particles are synthesized using hydrothermal route. • Thick TiO 2 particulate layer is deposited on prepared thin layer. • Dye sensitized solar cells are made using thin and thick layer based photo-anode. • Introduction of thin layer in particulate photo-anode improves the cell efficiency. - Abstract: A compact thin TiO 2 passivation layer is introduced between the mesoporous TiO 2 nano-particulate layer and the conducting glass substrate to prepare photo-anode for dye-sensitized solar cell (DSSC). In order to understand the effect of passivation layer, other two DSSCs are also developed separately using TiO 2 nano-particulate and compact thin film based photo-anodes. Nano-particles are prepared using hydrothermal synthesis route and the compact passivation layer is prepared by simply dip coating the precursor sol prepared through wet chemical route. The TiO 2 compact layer and the nano-particles are characterised in terms of their micro-structural features and phase formation behavior. It is found that introduction of a compact TiO 2 layer in between the mesoporous TiO 2 nano-particulate layer and the conducting substrate improves the solar to electric conversion efficiency of the fabricated cell. The dense thin passivation layer is supposed to enhance the photo-excited electron transfer and prevent the recombination of photo-excited electrons

Ground-water resources of the Alma area, Michigan

Science.gov (United States)

Vanlier, Kenneth E.

1963-01-01

The Alma area consists of 30 square miles in the northwestern part of Gratiot County, Mich. It is an area of slight relief gently rolling hills and level plains and is an important agricultural center in the State.The Saginaw formation, which forms the bedrock surface in part of the area, is of relatively low permeability and yields water containing objectionable amounts of chloride. Formations below the Saginaw are tapped for brine in and near the Alma area.The consolidated rocks of the Alma area are mantled by Pleistocene glacial deposits, which are as much as 550 feet thick where preglacial valleys were eroded into the bedrock. The glacial deposits consist of till, glacial-lake deposits, and outwash. Till deposits are at the surface along the south-trending moraines that cross the area, and they underlie other types of glacial deposits at depth throughout the area. The till deposits are of low permeability and are not a source of water to wells, though locally they include small lenses of permeable sand and gravel.In the western part of the area, including much of the city of Alma, the glacial-lake deposits consist primarily of sand and are a source of small supplies of water. In the northeastern part of the area the lake deposits are predominantly clayey and of low permeability.Sand and gravel outwash yields moderate and large supplies of water within the area. Outwash is present at the surface along the West Branch of the Pine River. A more extensive deposit of outwash buried by the lake deposits is the source of most of the ground water pumped at Alma. The presence of an additional deposit of buried outwash west and southwest of the city is inferred from the glacial history of the area. Additional water supplies that may be developed from these deposits are probably adequate for anticipated population and industrial growth.Water levels have declined generally in the vicinity of the city of Alma since 1920 in response to pumping for municipal and industrial

Hydrogeology of Valley-Fill Aquifers and Adjacent Areas in Eastern Chemung County, New York

Science.gov (United States)

Heisig, Paul M.

2015-10-19

The extent, hydrogeologic framework, and potential well yields of valley-fill aquifers within a 151-square-mile area of eastern Chemung County, New York, were investigated, and the upland distribution of till thickness over bedrock was characterized. The hydrogeologic framework of these valleyfill aquifers was interpreted from multiple sources of surficial and subsurface data and an interpretation of the origin of the glacial deposits, particularly during retreat of glacial ice from the region. Potential yields of screened wells are based on the hydrogeologic framework interpretation and existing well-yield data, most of which are from wells finished with open-ended well casing.

Expanding Greenland’s Glacial Record

DEFF Research Database (Denmark)

Bjørk, Anders Anker

. On order to expand the glacial history of Greenland, this thesis explores physical and geological archives for evidence of the glaciers’ past response to climatic variations. Using aerial photographs, the dynamic history of the Greenland Ice Sheet is extended back to 1900 C.E. Glacier changes covering...

Studies Concerning Water-Surface Deposits in Recovery Boilers

Energy Technology Data Exchange (ETDEWEB)

Strandberg, O; Arvesen, J; Dahl, L

1971-11-15

The Feed-water Committee of the Stiftelsen Svensk Cellulosaforskning (Foundation for Swedish Cellulose Research) has initiated research and investigations which aim to increase knowledge about water-surface deposits in boiler tubes, and the resulting risks of gas-surface corrosion in chemical recovery boilers (sulphate pulp industry). The Committee has arranged with AB Atomenergi, Studsvik, for investigations into the water-surface deposits on tubes from six Scandinavian boilers. These investigations have included direct measurements of the thermal conductivity of the deposits, and determinations of their quantity, thickness and structure have been carried out. Previous investigations have shown that gas-surface corrosion can occur at tube temperatures above 330 deg C. The measured values for the thermal conductivity of the deposits indicate that even with small quantities of deposit (c. 1 g/dm2 ) and a moderate boiler pressure (40 atm), certain types of deposit can give rise to the above-mentioned surface temperature, at which the risk of gas-surface corrosion becomes appreciable. For higher boiler pressures the risk is great even with a minimal layer of deposit. The critical deposit thickness can be as low as 0.1 mm

A New View of Glacial Age Coastal Wetlands from A Well-Preserved Underwater Baldcypress Forest in the Northern Gulf of Mexico

Science.gov (United States)

DeLong, K. L.; Harley, G. L.; Bentley, S. J.; Xu, K.; Reese, A.; Caporaso, A.; Obelcz, J.; Gonzalez Rodriguez, S. M.; Truong, J. T.; Shen, Z.; Raines, B.

2017-12-01

A unique site in the northern Gulf of Mexico contains well-preserved baldcypress (Taxodium distichum) stumps in life position deposited when sea level was lower during the last glacial interval presumably uncovered by Hurricane Ivan in 2004. Previous pollen and climate model studies suggest the southeastern USA was cold and dry during the glacial with boreal forests; however, little paleo-evidence for the northern gulf coast exist. Wood normally decomposes quickly in marine environments thus such sites are rare and understudied until this multi-disciplinary team began studying the site in 2012. The team has dived the site collecting 23 wood samples, conducted two geophysical surveys, and recovered 18 vibracores. Radiocarbon dating of tree stumps reveal that the trees are radiocarbon dead yet some dates from the woody fractions in the sediments above the trees have 14C ages from 37,350-41,830 years BP, which are close to the 14C dating limitations. Optically stimulated luminescence dating pushes burial of the forest back to 60-70 ka. Based on the site location (13.5 km offshore), water depth (18 m), and relative tectonic stability of this area, and geophysical surveys, these subtropical baldcypress trees lived 30 m above sea level in a backwater swamp in an area with topographic relief during a lower sea level stand in the last glacial interval (MIS 3-4) near the now buried and incised Mobile River channels. Pollen analysis from sediment core samples found an abundance of baldcypress and tupelo (Nyssa aquatic)with some pine pollen similar to the modern northern Gulf Coast. We developed a floating tree-ring chronology spanning 489 years using wood samples with bark still intact. This chronology reveals growth suppression events towards the end of their life with death occurring simultaneously and burial possibly caused by floodplain aggradation from a quick rise in sea level during the glacial interval. These large baldcypress trees and pollen results suggest the

Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

Energy Technology Data Exchange (ETDEWEB)

Gagorowska, B; Dus-Sitek, M [Institute of Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Czestochowa (Poland)

2007-08-15

The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d{sub Cu} = 2 nm) and the thickness of Ni layer - variable (1 nm {<=} d{sub Ni} {<=} 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent.

Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

International Nuclear Information System (INIS)

Gagorowska, B; Dus-Sitek, M

2007-01-01

The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d Cu = 2 nm) and the thickness of Ni layer - variable (1 nm ≤ d Ni ≤ 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent

Dynamic-speckle profilometer for online measurements of coating thickness

Energy Technology Data Exchange (ETDEWEB)

Kamshilin, A A [Laboratory of Optical Sensor Technology, Department of Physics, University of Kuopio, PO Box 1627, FIN-70211 Kuopio (Finland); Semenov, D V [Laboratory of Optical Sensor Technology, Department of Physics, University of Kuopio, PO Box 1627, FIN-70211 Kuopio (Finland); Nippolainen, E [Laboratory of Optical Sensor Technology, Department of Physics, University of Kuopio, PO Box 1627, FIN-70211 Kuopio (Finland); Miridonov, S [Optics Department, CICESE, Carr. Tijuana-Ensenada km 107, C.P. 22860, A.P. 360, Ensenada, B.C. (Mexico)

2007-10-15

Online control of thickness of as-deposited coatings is of great importance because it directly affects the quality of protective coatings. We present a novel approach that enables online, real-time and non-contact measurements thickness of thermally sprayed coatings. The proposed technique uses dynamic speckles generated by rapidly deflecting laser beam. Within 10 ms the system can scan 500 times a small area of the deposited layer thus resulting in measurement accuracy of 5 microns irrespectively of the layer roughness. In comparison with traditional optical triangulation technique of distance measurements, our system has following advantages: (i) much simpler optical scheme that includes conventional photodiode to measure the scattered light, (ii) much simpler electronics for real-time data processing, (iii) much higher speed of measurements.

Dynamic-speckle profilometer for online measurements of coating thickness

International Nuclear Information System (INIS)

Kamshilin, A A; Semenov, D V; Nippolainen, E; Miridonov, S

2007-01-01

Online control of thickness of as-deposited coatings is of great importance because it directly affects the quality of protective coatings. We present a novel approach that enables online, real-time and non-contact measurements thickness of thermally sprayed coatings. The proposed technique uses dynamic speckles generated by rapidly deflecting laser beam. Within 10 ms the system can scan 500 times a small area of the deposited layer thus resulting in measurement accuracy of 5 microns irrespectively of the layer roughness. In comparison with traditional optical triangulation technique of distance measurements, our system has following advantages: (i) much simpler optical scheme that includes conventional photodiode to measure the scattered light, (ii) much simpler electronics for real-time data processing, (iii) much higher speed of measurements

Deposition of plasmon gold-fluoropolymer nanocomposites

Science.gov (United States)

Safonov, Alexey I.; Sulyaeva, Veronica S.; Timoshenko, Nikolay I.; Kubrak, Konstantin V.; Starinskiy, Sergey V.

2016-12-01

Degradation-resistant two-dimensional metal-fluoropolymer composites consisting of gold nanoparticles coated with a thin fluoropolymer film were deposited on a substrate by hot wire chemical vapour deposition (HWCVD) and ion sputtering. The morphology and optical properties of the obtained coatings were determined. The thickness of the thin fluoropolymer film was found to influence the position of the surface plasmon resonance peak. Numerical calculations of the optical properties of the deposited materials were performed using Mie theory and the finite-difference time-domain (FDTD) method. The calculation results are consistent with the experimental data. The study shows that the position of the resonance peak can be controlled by changing the surface concentration of particles and the thickness of the fluoropolymer coating. The protective coating was found to prevent the plasmonic properties of the nanoparticles from changing for several months.

Growth and characterization of thick cBN coatings on silicon and tool substrates

International Nuclear Information System (INIS)

Bewilogua, K.; Keunecke, M.; Weigel, K.; Wiemann, E.

2004-01-01

Recently some research groups have achieved progress in the deposition of cubic boron nitride (cBN) coatings with a thickness of 2 μm and more, which is necessary for cutting tool applications. In our laboratory, thick cBN coatings were sputter deposited on silicon substrates using a boron carbide target. Following a boron carbide interlayer (few 100 nm thick), a gradient layer with continuously increasing nitrogen content was prepared. After the cBN nucleation, the process parameters were modified for the cBN film growth to a thickness of more than 2 μm. However, the transfer of this technology to technically relevant substrates, like cemented carbide cutting inserts, required some further process modifications. At first, a titanium interlayer had to be deposited followed by a more than 1-μm-thick boron carbide layer. The next steps were identical to those on silicon substrates. The total coating thickness was in the range of 3 μm with a 0.5- to nearly 1-μm-thick cBN top layer. In spite of the enormous intrinsic stress, both the coatings on silicon and on cemented carbide exhibited a good adhesion and a prolonged stability in humid air. Oxidation experiments revealed a stability of the coating system on cemented carbide up to 700 deg. C and higher. Coated cutting inserts were tested in turning operations with different metallic workpiece materials. The test results will be compared to those of well-established cutting materials, like polycrystalline cubic boron nitride (PCBN) and oxide ceramics, considering the wear of coated tools

Sink detection on tilted terrain for automated identification of glacial cirques

Science.gov (United States)

Prasicek, Günther; Robl, Jörg; Lang, Andreas

2016-04-01

Glacial cirques are morphologically distinct but complex landforms and represent a vital part of high mountain topography. Their distribution, elevation and relief are expected to hold information on (1) the extent of glacial occupation, (2) the mechanism of glacial cirque erosion, and (3) how glacial in concert with periglacial processes can limit peak altitude and mountain range height. While easily detectably for the expert's eye both in nature and on various representations of topography, their complicated nature makes them a nemesis for computer algorithms. Consequently, manual mapping of glacial cirques is commonplace in many mountain landscapes worldwide, but consistent datasets of cirque distribution and objectively mapped cirques and their morphometrical attributes are lacking. Among the biggest problems for algorithm development are the complexity in shape and the great variability of cirque size. For example, glacial cirques can be rather circular or longitudinal in extent, exist as individual and composite landforms, show prominent topographic depressions or can entirely be filled with water or sediment. For these reasons, attributes like circularity, size, drainage area and topology of landform elements (e.g. a flat floor surrounded by steep walls) have only a limited potential for automated cirque detection. Here we present a novel, geomorphometric method for automated identification of glacial cirques on digital elevation models that exploits their genetic bowl-like shape. First, we differentiate between glacial and fluvial terrain employing an algorithm based on a moving window approach and multi-scale curvature, which is also capable of fitting the analysis window to valley width. We then fit a plane to the valley stretch clipped by the analysis window and rotate the terrain around the center cell until the plane is level. Doing so, we produce sinks of considerable size if the clipped terrain represents a cirque, while no or only very small sinks

Sedimentology of Hirnantian glaciomarine deposits in the Balkan Terrane, western Bulgaria: Fixing a piece of the north peri-Gondwana jigsaw puzzle

Science.gov (United States)

Chatalov, Athanas

2017-04-01

Glaciomarine deposits of late Hirnantian age in the western part of the Palaeozoic Balkan Terrane have persistent thickness ( 7 m) and lateral uniformity in rock colour, bedding pattern, lithology, and sedimentary structures. Four lithofacies are distinguished from base to top: lonestone-bearing diamictites, interbedded structureless mudstones, crudely laminated diamictites, and finely laminated mudstones. The diamictites are clast-poor to clast-rich comprising muddy to sandy varieties. Their compositional maturity is evidenced by the very high amount of detrital quartz compared to the paucity of feldspar and unstable lithic grains. Other textural components include extraclasts derived from the local Ordovician basement, mudstone intraclasts, and sediment aggregates. Turbate structures, grain lineations, and soft sediment deformation of the matrix below larger grains are locally observed. Sedimentological analysis reveals that deposition occurred in an ice-intermediate to ice-distal, poorly agitated shelf environment by material supplied from meltwater buoyant plumes and rain-out from ice-rafted debris. Remobilization by mass-flow processes (cohesive debris flows and slumps) was an important mechanism particularly for the formation of massive diamictites. The glaciomarine deposits represent a typical deglaciation sequence reflecting retreat of the ice front (grounded or floating ice sheet), relative sea-level rise and gradually reduced sedimentation rate with increasing contribution from suspension fallout. This sequence was deposited on the non-glaciated shelf of the intracratonic North Gondwana platform along the southern margin of the Rheic Ocean. The Hirnantian strata of the Balkan Terrane can be correlated with similar glaciomarine deposits known from peri-Gondwana terranes elsewhere in Europe showing clear 'Armorican affinity'. Several lines of evidence suggest that the provenance of siliciclastic material was associated mainly with sedimentary recycling of

BaF2 POST-DEPOSITION REACTION PROCESS FOR THICK YBCO FILMS

International Nuclear Information System (INIS)

SUENAGA, M.; SOLOVYOV, V.F.; WU, L.; WIESMANN, H.J.; ZHU, Y.

2001-01-01

The basic processes of the so-called BaF 2 process for the formation of YBa 2 Cu 3 O 7 , YBCO, films as well as its advantages over the in situ formation processes are discussed in the previous chapter. The process and the properties of YBCO films by this process were also nicely described in earlier articles by R. Feenstra, (et al.) Here, we will discuss two pertinent subjects related to fabrication of technologically viable YBCO conductors using this process. These are (1) the growth of thick (>> 1 microm) c-axis-oriented YBCO films and (2) their growth rates. Before the detail discussions of these subjects are given, we first briefly discuss what geometrical structure a YBCO-coated conductor should be. Then, we will provide examples of simple arguments for how thick the YBCO films and how fast their growth rates need to be. Then, the discussions in the following two sections are devoted to: (1) the present understanding of the nucleation and the growth process for YBCO, and why it is so difficult to grow thick c-axis-oriented films (> 3 microm), and (2) our present understanding of the YBCO growth-limiting mechanism and methods to increase the growth rates. The values of critical-current densities J c in these films are of primary importance for the applications,. and the above two subjects are intimately related to the control of J c of the films. In general, the lower the temperatures of the YBCO formation are the higher the values of J c of the films. Thus, the present discussion is limited to those films which are reacted at ∼735 C. This is the lowest temperature at which c-axis-oriented YBCO films (1-3 microm thick) are comfortably grown. It is also well known that the non-c-axis oriented YBCO platelets are extremely detrimental to the values of J c such that their effects on J c dwarf essentially all of other microstructural effects which control J c . Hence, the discussion given below is mainly focused on how to avoid the growth of these crystallites

Deposition of plasmon gold–fluoropolymer nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Safonov, Alexey I., E-mail: safonov@itp.nsc.ru [Kutateladze Institute of Thermophysics SB RAS, Lavrentyev Ave. 1, 630090, Novosibirsk (Russian Federation); Sulyaeva, Veronica S. [Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentyev Ave. 3, 630090, Novosibirsk (Russian Federation); Timoshenko, Nikolay I.; Kubrak, Konstantin V.; Starinskiy, Sergey V. [Kutateladze Institute of Thermophysics SB RAS, Lavrentyev Ave. 1, 630090, Novosibirsk (Russian Federation)

2016-12-01

Degradation-resistant two-dimensional metal–fluoropolymer composites consisting of gold nanoparticles coated with a thin fluoropolymer film were deposited on a substrate by hot wire chemical vapour deposition (HWCVD) and ion sputtering. The morphology and optical properties of the obtained coatings were determined. The thickness of the thin fluoropolymer film was found to influence the position of the surface plasmon resonance peak. Numerical calculations of the optical properties of the deposited materials were performed using Mie theory and the finite-difference time-domain (FDTD) method. The calculation results are consistent with the experimental data. The study shows that the position of the resonance peak can be controlled by changing the surface concentration of particles and the thickness of the fluoropolymer coating. The protective coating was found to prevent the plasmonic properties of the nanoparticles from changing for several months. - Highlights: • The gold–fluoropolymer composites are obtained by a combination of GJD and HWCVD. • The optical properties of composites were determined by experiments and calculation. • The dependence of SPR position on filling, NPs size and FP thickness were analyzed. • The plasmonic properties of the Au NPs are saved in the fluoropolymer matrix.

Modeling the evolution of the Laurentide Ice Sheet from MIS 3 to the Last Glacial Maximum: an approach using sea level modeling and ice flow dynamics

Science.gov (United States)

Weisenberg, J.; Pico, T.; Birch, L.; Mitrovica, J. X.

2017-12-01

The history of the Laurentide Ice Sheet since the Last Glacial Maximum ( 26 ka; LGM) is constrained by geological evidence of ice margin retreat in addition to relative sea-level (RSL) records in both the near and far field. Nonetheless, few observations exist constraining the ice sheet's extent across the glacial build-up phase preceding the LGM. Recent work correcting RSL records along the U.S. mid-Atlantic dated to mid-MIS 3 (50-35 ka) for glacial-isostatic adjustment (GIA) infer that the Laurentide Ice Sheet grew by more than three-fold in the 15 ky leading into the LGM. Here we test the plausibility of a late and extremely rapid glaciation by driving a high-resolution ice sheet model, based on a nonlinear diffusion equation for the ice thickness. We initialize this model at 44 ka with the mid-MIS 3 ice sheet configuration proposed by Pico et al. (2017), GIA-corrected basal topography, and mass balance representative of mid-MIS 3 conditions. These simulations predict rapid growth of the eastern Laurentide Ice Sheet, with rates consistent with achieving LGM ice volumes within 15 ky. We use these simulations to refine the initial ice configuration and present an improved and higher resolution model for North American ice cover during mid-MIS 3. In addition we show that assumptions of ice loads during the glacial phase, and the associated reconstructions of GIA-corrected basal topography, produce a bias that can underpredict ice growth rates in the late stages of the glaciation, which has important consequences for our understanding of the speed limit for ice growth on glacial timescales.

Surficial geologic map of Berrien County, Michigan, and the adjacent offshore area of Lake Michigan

Science.gov (United States)

Stone, Byron D.; Kincare, Kevin A.; O'Leary, Dennis W.; Newell, Wayne L.; Taylor, Emily M.; Williams, Van S.; Lundstrom, Scott C.; Abraham, Jared E.; Powers, Michael H.

2017-12-13

The surficial geologic map of Berrien County, southwestern Michigan (sheet 1), shows the distribution of glacial and postglacial deposits at the land surface and in the adjacent offshore area of Lake Michigan. The geologic map differentiates surficial materials of Quaternary age on the basis of their lithologic characteristics, stratigraphic relationships, and age. Drill-hole information correlated in cross sections provides details of typical stratigraphic sequences that compose one or more penetrated geologic map units. A new bedrock geologic map (on sheet 2) includes contours of the altitude of the eroded top of bedrock and shows the distribution of middle Paleozoic shale and carbonate units in the subcrop. A sediment thickness map (also on sheet 2) portrays the extent of as much as 150 meters of surficial materials that overlie the bedrock surface.The major physical features of the county are related principally to deposits of the last Laurentide ice sheet that advanced and then retreated back through the region from about 19,000 to 14,000 radiocarbon years before present. Glacial and postglacial deposits underlie the entire county; shale bedrock crops out only in the adjacent offshore area on the bottom of Lake Michigan. All glacial deposits and glacial meltwater deposits in Berrien County are related to the late Wisconsinan glacial advances of the Lake Michigan ice lobe and its three regional recessional moraines, which cross the county as three north-northeast-trending belts.From east to west (oldest to youngest), the three moraine belts are known as the Kalamazoo, Valparaiso, and Lake Border morainic systems. The till-ridge morainic systems (Lake Border and local Valparaiso morainic systems) consist of multiple, elongate moraine ridges separated by till plains and lake-bottom plains. Tills in ground and end moraines in Berrien County are distinguished as informal units, and are correlated with three proposed regional till units in southwestern Michigan

Aerial gamma ray and magnetic survey: Minnesota Project, New Ulm quadrangle of Minnesota. Final report

International Nuclear Information System (INIS)

1979-11-01

The New Ulm 1:250,000 scale quadrangle of southwestern Minnesota is entirely covered by variable thicknesses of Late Wisconsin age glacial deposits (drift). Precambrian bedrock is primarily exposed within the Minnesota River Valley, but only in very small, scattered outcrops. Approximately 50% of the bedrock is composed of Cretaceous sediments. There are no known uranium deposits (or occurrences) within the quadrangle. One hundred forty-six (146) groups of uranium samples were defined as anomalies and are discussed. None were considered significant

Repeated Storage of Respired Carbon in the Equatorial Pacific Ocean Over the Last Three Glacial Cycles

Science.gov (United States)

Jacobel, A. W.; McManus, J. F.; Anderson, R. F.; Winckler, G.

2017-12-01

As the largest reservoir of carbon actively exchanging with the atmosphere on glacial-interglacial timescales, the deep ocean has been implicated as the likely location of carbon dioxide sequestration during Pleistocene glaciations. Despite strong theoretical underpinnings for this expectation, it has been challenging to identify unequivocal evidence for respired carbon storage in the paleoceanographic record. Data on the rate of ocean ventilation derived from paired planktonic-benthic foraminifera radiocarbon ages conflict across the equatorial Pacific, and different proxy reconstructions contradict one another about the depth and origin of the watermass containing the respired carbon. Because any change in the storage of respiratory carbon must be accompanied by corresponding changes in dissolved oxygen concentrations, proxy data reflecting bottom water oxygenation are of value in addressing these apparent inconsistencies. We present new records of the redox sensitive metal uranium from the central equatorial Pacific to qualitatively identify intervals associated with respiratory carbon storage over the past 350 kyr. Our data reveal periods of deep ocean authigenic uranium deposition in association with each of the last three glacial maxima. Equatorial Pacific export productivity data show intervals with abundant authigenic uranium are not associated with local productivity increases, indicating episodic precipitation of authigenic uranium does not directly reflect increases in situ microbial respiration, but rather occurs in response to basin-wide decreases in deep water oxygen concentrations. We combine our new data with previously published results to propose a picture of glacial carbon storage and equatorial Pacific watermass structure that is internally consistent. We conclude that respired carbon storage in the Pacific was a persistent feature of Pleistocene glaciations.

Miniaturized, Planar Ion-selective Electrodes Fabricated by Means of Thick-film Technology

Directory of Open Access Journals (Sweden)

Robert Koncki

2006-04-01

Full Text Available Various planar technologies are employed for developing solid-state sensorshaving low cost, small size and high reproducibility; thin- and thick-film technologies aremost suitable for such productions. Screen-printing is especially suitable due to itssimplicity, low-cost, high reproducibility and efficiency in large-scale production. Thistechnology enables the deposition of a thick layer and allows precise pattern control.Moreover, this is a highly economic technology, saving large amounts of the used inks. Inthe course of repetitions of the film-deposition procedure there is no waste of material dueto additivity of this thick-film technology. Finally, the thick films can be easily and quicklydeposited on inexpensive substrates. In this contribution, thick-film ion-selective electrodesbased on ionophores as well as crystalline ion-selective materials dedicated forpotentiometric measurements are demonstrated. Analytical parameters of these sensors arecomparable with those reported for conventional potentiometric electrodes. All mentionedthick-film strip electrodes have been totally fabricated in only one, fully automated thick-film technology, without any additional manual, chemical or electrochemical steps. In allcases simple, inexpensive, commercially available materials, i.e. flexible, plastic substratesand easily cured polymer-based pastes were used.

Electroless atomic layer deposition

Science.gov (United States)

Robinson, David Bruce; Cappillino, Patrick J.; Sheridan, Leah B.; Stickney, John L.; Benson, David M.

2017-10-31

A method of electroless atomic layer deposition is described. The method electrolessly generates a layer of sacrificial material on a surface of a first material. The method adds doses of a solution of a second material to the substrate. The method performs a galvanic exchange reaction to oxidize away the layer of the sacrificial material and deposit a layer of the second material on the surface of the first material. The method can be repeated for a plurality of iterations in order to deposit a desired thickness of the second material on the surface of the first material.

Scale Thickness Measurement of Steam Generator Tubing Using Eddy Current Signal of Bobbin Coil

International Nuclear Information System (INIS)

Kim, Chang Soo; Um, Ki Soo; Kim, Jae Dong

2012-01-01

Steam generator is one of the major components of nuclear power plant and steam generator tubes are the pressure boundary between primary and secondary side, which makes them critical for nuclear safety. As the operating time of nuclear power plant increases, not only damage mechanisms but also scaled deposits on steam generator tubes are known to be problematic causing tube support flow hole blockage and heat fouling. The ability to assess the extent and location of scaled deposits on tubes became essential for management and maintenance of steam generator and eddy current bobbin data can be utilized to measure thickness of scale on tubes. In this paper, tube reference standards with various thickness of scaled deposit has been set up to provide information about the overall deposit condition of steam generator tubes, providing essential tool for steam generator management and maintenance to predict and prevent future damages. Also, methodology to automatically measure scale thickness on tubes has been developed and applied to field data to estimate overall scale amount.

Glacial sequence stratigraphy reveal the Weichselian glacial history of the SE sector of the Eurasian Ice Sheet

Science.gov (United States)

Räsänen, Matti

2016-04-01

Reconstructions of the last Weichselian glacial cycle 117,000-11,700 years (kyr) ago propose that S Finland, adjacent Russia and the Baltic countries in the SE sector of the Eurasian Ice Sheet (EIS), were glaciated during the Middle Weichselian time [marine isotope stage (MIS) 4, 71-57 kyr ago] and that this glaciation was preceded in S Finland by an Early Weichselian interstadial (MIS 5c, 105-93 kyr ago) with pine forest. Here glacial sequence stratigraphy (Powell and Cooper 2002) is applied to isolated Late Pleistocene onshore outcrop sections in S Finland. The analysed sedimentary records have traditionally been investigated, interpreted and published separately by different authors without an attempt to a methodologically more systematic survey. By putting new field data and old observations into a regional sequence stratigraphic framework it is shown how previously unnoticed regularities can be found in the lithofacies and fossil successions. It is shown that the proposed Middle Weichselian glaciation or the pine dominated interstadial did not take place at all (Räsänen et al. 2015). The one Late Weichselian glaciation (MIS 2, 29-11 kyr ago) at the SE sector of EIS was preceded in S Finland by a nearly 90 kyr long still poorly known non-glacial period, featuring tundra with permafrost and probably birch forest. The new Middle Weichselian paleoenvironmental scenario revises the configuration and hydrology of the S part of EIS and gives new setting for the evolution of Scandinavian biota. References Powell, R. D., and Cooper, J. M., 2002, A glacial sequence stratigraphic model for temperate, glaciated continental shelves, in Dowdeswell, J. A., and Cofaig, C. Ó. eds., Glacier-Influenced Sedimentation on High-Latitude Continental Margins: The Geological Society of London, London, Geological Society London, Special Publication v. 203, p. 215-244. Räsänen, M.E., Huitti, J.V., Bhattarai, S. Harvey, J. and Huttunen, S. 2015, The SE sector of the Middle

Glacial Hazards in Chile: Processes, Assessment, Mitigation and Risk Management Strategies

Science.gov (United States)

Glasser, N. F.; Wilson, R.; Casassa, G., Sr.; Reynolds, J.; Harrison, S.; Shannon, S. R.; Schaefer, M.; Iribarran, P.

2017-12-01

Glacial Lake Outburst Floods (GLOFs) are capable of travelling considerable distances from their source and they represent one of the most important glacial hazards. In line with observations in other parts of the world, the frequency of GLOF events in Chile has increased in recent decades highlighting the need to quantify the flood risk posed to downstream areas. This poster presents the work of the `Glacial Hazards in Chile' project which aims to (1) better understand the processes that govern the development of GLOFs in Chile, (2) estimate the socio-economic effects of GLOFs in Chile, and (3) provide a GLOF risk assessment framework that can be applied to Chile and other lower income countries globally. As an initial step towards the completion of these aims, we have recently compiled the first glacial lake inventory for the central and Patagonian Andes, which details the temporal development of glacial lakes in this region over the past three decades. This analysis was used to identify two lakes of interest that were visited during a fieldwork expedition in February 2017. The first of these, Lago Chileno in Patagonia, has recently produced a large GLOF causing significant damage to the downstream floodplain, whilst the second was identified as one of the fastest growing lakes in the central Andes. Both these lakes were surveyed using aerial imagery acquired with a drone and a custom-built bathymetry boat, data from which will help to improve our understanding of the physical processes associated with glacial lake development and failure within the Chilean Andes.