WorldWideScience

Sample records for thermal pair plasmas

  1. Modulation instability of ion thermal waves in a pair-ion plasma containing charged dust impurities

    Sabry, R.

    2008-01-01

    Modulation instability of ion thermal waves (ITWs) is investigated in a plasma composed of positive and negative ions as well as a fraction of stationary charged (positive or negative) dust impurities. For this purpose, a linear dispersion relation and a nonlinear Schroedinger equation are derived. The latter admits localized envelope solitary wave solutions of bright (pulses) and dark (holes, voids) type. The envelope soliton depends on the intrinsic plasma parameters. It is found that modulation instability of ITWs is significantly affected by the presence of positively/negatively charged dust grains. The findings of this investigation should be useful in understanding the stable electrostatic wave packet acceleration mechanisms in pair-ion plasma, and also enhances our knowledge on the occurrence of instability associated to the existence of charged dust impurities in pair-ion plasmas. Our results should be of relevance for laboratory plasmas.

  2. Ion Streaming Instabilities in Pair Ion Plasma and Localized Structure with Non-Thermal Electrons

    Nasir Khattak, M.; Mushtaq, A.; Qamar, A.

    2015-12-01

    Pair ion plasma with a fraction of non-thermal electrons is considered. We investigate the effects of the streaming motion of ions on linear and nonlinear properties of unmagnetized, collisionless plasma by using the fluid model. A dispersion relation is derived, and the growth rate of streaming instabilities with effect of streaming motion of ions and non-thermal electrons is calculated. A qausi-potential approach is adopted to study the characteristics of ion acoustic solitons. An energy integral equation involving Sagdeev potential is derived during this process. The presence of the streaming term in the energy integral equation affects the structure of the solitary waves significantly along with non-thermal electrons. Possible application of the work to the space and laboratory plasmas are highlighted.

  3. Ion streaming instabilities in pair ion plasma and localized structure with non-thermal electrons

    Khattak, M. Nasir; Qamar, A., E-mail: mnnasirphysics@gmail.com [Department of Physics, University of Peshawar (Pakistan); Mushtaq, A. [Department of Physics, Abdul Wali Khan University Mardan, National Center for Physics, Mardan (Pakistan)

    2015-12-15

    Pair ion plasma with a fraction of non-thermal electrons is considered. We investigate the effects of the streaming motion of ions on linear and nonlinear properties of unmagnetized, collisionless plasma by using the fluid model. A dispersion relation is derived, and the growth rate of streaming instabilities with effect of streaming motion of ions and non-thermal electrons is calculated. A quasi-potential approach is adopted to study the characteristics of ion acoustic solitons. An energy integral equation involving Sagdeev potential is derived during this process. The presence of the streaming term in the energy integral equation affects the structure of the solitary waves significantly along with non-thermal electrons. Possible application of the work to the space and laboratory plasmas are highlighted. (author)

  4. Pair plasma relaxation time scales.

    Aksenov, A G; Ruffini, R; Vereshchagin, G V

    2010-04-01

    By numerically solving the relativistic Boltzmann equations, we compute the time scale for relaxation to thermal equilibrium for an optically thick electron-positron plasma with baryon loading. We focus on the time scales of electromagnetic interactions. The collisional integrals are obtained directly from the corresponding QED matrix elements. Thermalization time scales are computed for a wide range of values of both the total-energy density (over 10 orders of magnitude) and of the baryonic loading parameter (over 6 orders of magnitude). This also allows us to study such interesting limiting cases as the almost purely electron-positron plasma or electron-proton plasma as well as intermediate cases. These results appear to be important both for laboratory experiments aimed at generating optically thick pair plasmas as well as for astrophysical models in which electron-positron pair plasmas play a relevant role.

  5. Using the Pairs of Lines Broadened by Collisions with Neutral and Charged Particles for Gas Temperature Determination of Argon Non-Thermal Plasmas at Atmospheric Pressure

    Cristina Yubero

    2017-10-01

    Full Text Available The spectroscopic method for gas temperature determination in argon non-thermal plasmas sustained at atmospheric pressure proposed recently by Spectrochimica Acta Part B 129 14 (2017—based on collisional broadening measurements of selected pairs of argon atomic lines, has been applied to other pairs of argon atomic lines, and the discrepancies found in some of these results have been analyzed. For validation purposes, the values of the gas temperature obtained using the different pairs of lines have been compared with the rotational temperatures derived from the OH ro-vibrational bands, using the Boltzmann-plot technique.

  6. (RN) pair production by photons in a hot Maxwellian plasma

    Haug, E.

    2004-01-01

    The production of electron-positron pairs by photons in the Coulomb Field of electrons and positrons (triplet production) in hot thermal plasmas is investigated. The pair production rate for this process is calculated as a function of the photon energy and compared with the rate of photon-nucleus pair production for semi-relativistic and relativistic plasma temperatures. (author)

  7. Pair plasma in pulsar magnetospheres

    Asseo, Estelle

    2003-01-01

    The main features of radiation received from pulsars imply that they are neutron stars which contain an extremely intense magnetic field and emit coherently in the radio domain. Most recent studies attribute the origin of the coherence to plasma instabilities arising in pulsar magnetospheres; they mainly concern the linear, or the nonlinear, character of the involved unstable waves. We briefly introduce radio pulsars and specify physical conditions in pulsar emission regions: geometrical properties, magnetic field, pair creation processes and repartition of relativistic charged particles. We point to the main ingredients of the linear theory, extensively explored since the 1970s: (i) a dispersion relation specific to the pulsar case; (ii) the characteristics of the waves able to propagate in relativistic pulsar plasmas; (iii) the different ways in which a two-humped distribution of particles may arise in a pulsar magnetosphere and favour the development of a two-stream instability. We sum up recent improvements of the linear theory: (i) the determination of a 'coupling function' responsible for high values of the wave field components and electromagnetic energy available; (ii) the obtention of new dispersion relations for actually anisotropic pulsar plasmas with relativistic motions and temperatures; (iii) the interaction between a plasma and a beam, both with relativistic motions and temperatures; (iv) the interpretation of observed 'coral' and 'conal' features, associated with the presence of boundaries and curved magnetic field lines in the emission region; (v) the detailed topology of the magnetic field in the different parts of the emission region and its relation to models recently proposed to interpret drifting subpulses observed from PSR 0943+10, showing 20 sub-beams of emission. We relate the nonlinear evolution of the two-stream instability and development of strong turbulence in relativistic pulsar plasmas to the emergence of relativistic solitons, able

  8. Drift wave in pair-ion plasma

    ion plasma are discussed. It is shown that the temperature and/or mass difference of both species could produce drift wave in a pair-ion plasma. The results are discussed in the context of the fullerene pair-ion plasma experiment.

  9. Pair creation and plasma oscillations

    Prozorkevich, A. V.; Vinnik, D. V.; Schmidt, S. M.; Hecht, M. B.; Roberts, C. D.

    2000-01-01

    We describe aspects of particle creation in strong fields using a quantum kinetic equation with a relaxation-time approximation to the collision term. The strong electric background field is determined by solving Maxwell's equation in tandem with the Vlasov equation. Plasma oscillations appear as a result of feedback between the background field and the field generated by the particles produced. The plasma frequency depends on the strength of the initial background fields and the collision frequency, and is sensitive to the necessary momentum-dependence of dressed-parton masses

  10. Drift wave in pair-ion plasma

    of charged particles in electromagnetic fields. The linear and nonlinear collective modes in electron-positron plasma have been investigated theoretically [3–6]. Recently, Oohara and Hatakeyama [7] have developed a novel method for generating a pair plasma con- sisting of only negative and positive ions with equal mass ...

  11. Plasma analog of particle-pair production

    Tsidulko, Yu.A.; Berk, H.L.

    1996-09-01

    It is shown that the plasma axial shear flow instability satisfies the Klein-Gordon equation. The plasma instability is then shown to be analogous to spontaneous particle-pair production when a potential energy is present that is greater than twice the particle rest mass energy. Stability criteria can be inferred based on field theoretical conservation laws

  12. Thermal plasmas: fundamental aspects

    Fauchais, P.

    2005-01-01

    This article treats of thermal plasmas, i.e. mainly produced by electric arcs and RF discharges. Their main characteristic is that they are generated at a pressure close to the atmospheric pressure (between 10 4 and 10 6 Pa) and refer to the classical kinetics of the Boltzmann equation. Because of the pressure, the collisions between particles are numerous and ionization is mainly due to a thermal effect. They correspond to electron densities between 10 20 and 10 24 m -3 and temperatures between 6000 and 25000 K. In these plasmas, the electric fields and the average free trajectories are too weak to generate a ionization state by direct inelastic collision. Ionization is thus essentially a thermal phenomenon due to elastic collisions. This article presents: 1 - the particles present in a plasma: definition, energy states; 2 - characteristic data: collisions, average free path and collision cross-section, distribution function, ionization types, charged particles mobility inside an electric field, scattering, Debye length; 3 - plasmas at the thermodynamical equilibrium: conditions of equilibrium, calculation of composition, thermodynamic properties, transport properties, radiation; 4 - thermal plasmas away from equilibrium: conditions of non-equilibrium, calculation of plasma composition, calculation of transport properties, quenching phenomenon. (J.S.)

  13. Thermal plasma waste treatment

    Heberlein, Joachim; Murphy, Anthony B

    2008-01-01

    Plasma waste treatment has over the past decade become a more prominent technology because of the increasing problems with waste disposal and because of the realization of opportunities to generate valuable co-products. Plasma vitrification of hazardous slags has been a commercial technology for several years, and volume reduction of hazardous wastes using plasma processes is increasingly being used. Plasma gasification of wastes with low negative values has attracted interest as a source of energy and spawned process developments for treatment of even municipal solid wastes. Numerous technologies and approaches exist for plasma treatment of wastes. This review summarizes the approaches that have been developed, presents some of the basic physical principles, provides details of some specific processes and considers the advantages and disadvantages of thermal plasmas in waste treatment applications. (topical review)

  14. SUPERFAST THERMALIZATION OF PLASMA

    Chang, C.C.

    1962-06-12

    A method is given for the superfast thermalization of plasma by shock conversion of the kinetic energy stored in rotating plasma rings or plasmoids colliding at near supersonic speeds in a containment field to heat energy in the resultant confined plasma mass. The method includes means for generating rotating plasmoids at the opposite ends of a Pyrotron or Astron containment field. The plasmoids are magnetically accelerated towards each other into the opposite ends of time containment field. During acceleration of the plasmoids toward the center of the containment field, the intensity of the field is sequentially increased to adiabatically compress the plasmoids and increase the plasma energy. The plasmoids hence collide with a violent shock at the eenter of the containment field, causing the substantial kinetic energy stored in the plasmoids to be converted to heat in the resultant plasma mass. (AEC)

  15. Monitoring system for thermal plasma

    Romero G, M.; Vilchis P, A.E.

    1999-01-01

    In the Thermal plasma applications laboratory it has been the degradation project of oils for isolation in transformers. These are a very hazardous residues and at this time in the country they are stored in metal barrels. It has been the intention to undergo the oils to plasma for degradate them to non-hazardous residues. The system behavior must be monitored to establish the thermal plasma behavior. (Author)

  16. Perpendicular relativistic shocks in magnetized pair plasma

    Plotnikov, Illya; Grassi, Anna; Grech, Mickael

    2018-04-01

    Perpendicular relativistic (γ0 = 10) shocks in magnetized pair plasmas are investigated using two dimensional Particle-in-Cell simulations. A systematic survey, from unmagnetized to strongly magnetized shocks, is presented accurately capturing the transition from Weibel-mediated to magnetic-reflection-shaped shocks. This transition is found to occur for upstream flow magnetizations 10-3 10-2, it leaves place to a purely electromagnetic precursor following from the strong emission of electromagnetic waves at the shock front. Particle acceleration is found to be efficient in weakly magnetized perpendicular shocks in agreement with previous works, and is fully suppressed for σ > 10-2. Diffusive Shock Acceleration is observed only in weakly magnetized shocks, while a dominant contribution of Shock Drift Acceleration is evidenced at intermediate magnetizations. The spatial diffusion coefficients are extracted from the simulations allowing for a deeper insight into the self-consistent particle kinematics and scale with the square of the particle energy in weakly magnetized shocks. These results have implications for particle acceleration in the internal shocks of AGN jets and in the termination shocks of Pulsar Wind Nebulae.

  17. Thermal Plasma decomposition of fluoriated greenhouse gases

    Choi, Soo Seok; Watanabe, Takayuki [Tokyo Institute of Technology, Yokohama (Japan); Park, Dong Wha [Inha University, Incheon (Korea, Republic of)

    2012-02-15

    Fluorinated compounds mainly used in the semiconductor industry are potent greenhouse gases. Recently, thermal plasma gas scrubbers have been gradually replacing conventional burn-wet type gas scrubbers which are based on the combustion of fossil fuels because high conversion efficiency and control of byproduct generation are achievable in chemically reactive high temperature thermal plasma. Chemical equilibrium composition at high temperature and numerical analysis on a complex thermal flow in the thermal plasma decomposition system are used to predict the process of thermal decomposition of fluorinated gas. In order to increase economic feasibility of the thermal plasma decomposition process, increase of thermal efficiency of the plasma torch and enhancement of gas mixing between the thermal plasma jet and waste gas are discussed. In addition, noble thermal plasma systems to be applied in the thermal plasma gas treatment are introduced in the present paper.

  18. Finite temperature QCD corrections to lepton-pair formation in a quark-gluon plasma

    Altherr, T.

    1989-02-01

    We discuss the O(α S ) corrections to lepton-pair production in a quark-gluon plasma in equilibrium. The corrections are found to be very small in the domain of interest for ultrarelativistic heavy ions collisions. Interesting effects, however, appear at the annihilation threshold of the thermalized quarks

  19. Thermal plasma chemical vapor deposition

    Heberlein, J.; Pfender, E.

    1993-01-01

    Thermal plasmas, with temperatures up to and even exceeding 10 4 K, are capable of producing high density vapor phase precursors for the deposition of relatively thick films. Although this technology is still in its infancy, it will fill the void between the relatively slow deposition processes such as physical vapor deposition and the high rate thermal spray deposition processes. In this chapter, the present state-of-the-art of this field is reviewed with emphasis on the various types of reactors proposed for this emerging technology. Only applications which attracted particular attention, namely diamond and high T c superconducting film deposition, are discussed in greater detail. (orig.)

  20. Tearing modes with pressure gradient effect in pair plasmas

    Cai Huishan; Li Ding; Zheng Jian

    2009-01-01

    The general dispersion relation of tearing mode with pressure gradient effect in pair plasmas is derived analytically. If the pressure gradients of positron and electron are not identical in pair plasmas, the pressure gradient has significant influence at tearing mode in both collisionless and collisional regimes. In collisionless regime, the effects of pressure gradient depend on its magnitude. For small pressure gradient, the growth rate of tearing mode is enhanced by pressure gradient. For large pressure gradient, the growth rate is reduced by pressure gradient. The tearing mode can even be stabilized if pressure gradient is large enough. In collisional regime, the growth rate of tearing mode is reduced by the pressure gradient. While the positron and electron have equal pressure gradient, tearing mode is not affected by pressure gradient in pair plasmas.

  1. Foundations of High-Pressure Thermal Plasmas

    Murphy, Anthony B.; Uhrlandt, Dirk

    2018-06-01

    An introduction to the main methods used to produce, model and measure thermal plasmas is provided, with emphasis on the differences between thermal plasmas and other types of processing plasmas. The critical properties of thermal plasmas are explained in physical terms and their importance in different applications is considered. The characteristics, and advantages and disadvantages, of the different main types of thermal plasmas (transferred and non-transferred arcs, radio-frequency inductively-coupled plasmas and microwave plasmas) are discussed. The methods by which flow is stabilized in arc plasmas are considered. The important concept of local thermodynamic equilibrium (LTE) is explained, leading into a discussion of the importance of thermophysical properties, and their calculation in LTE and two-temperature plasmas. The standard equations for modelling thermal plasmas are presented and contrasted with those used for non-equilibrium plasmas. Treatments of mixed-gas and non-LTE plasmas are considered, as well as the sheath regions adjacent to electrodes. Finally, the main methods used for electrical, optical, spectroscopic and laser diagnostics of thermal plasmas are briefly introduced, with an emphasis on the required assumptions for their reliable implementation, and the specific requirements of thermal plasmas.

  2. En route to matter-antimatter pair plasmas

    Stenson, Eve V.; Hergenhahn, Uwe; Paschkowski, Norbert; Saitoh, Haruhiko; Stanja, Juliane [Max Planck Institute for Plasma Physics, Greifswald and Garching (Germany); Niemann, Holger; Sunn Pedersen, Thomas [Max Planck Institute for Plasma Physics, Greifswald and Garching (Germany); Ernst Moritz Arndt University of Greifswald, Greifswald (Germany); Schweikhard, Lutz [Ernst Moritz Arndt University of Greifswald, Greifswald (Germany); Hugenschmidt, Christoph [Technische Universitaet Muenchen, Garching (Germany); Danielson, James R.; Surko, Clifford M. [University of California, San Diego, La Jolla (United States)

    2015-05-01

    The APEX and PAX projects have as their overarching goal the laboratory creation and confinement of the world's first positron-electron pair plasma. Plasmas of this type have been the subject of hundreds of theoretical investigations and are also believed to play a role in various astrophysical environments. In order to achieve this goal in an experimentally accessible volume (e.g., 10 liters), a record number (≥ 10{sup 10}) of cold (∝ 1 eV) positrons are to be accumulated and combined with a corresponding population of electrons. Notable requirements include a high-intensity positron beam (such as NEPOMUC), a suitable magnetic confinement device for the pair plasma (such as a levitated dipole), high-efficiency tools for bridging the two (i.e., means by which the positrons can be efficiently cooled, trapped, and injected across flux surfaces), and diagnostics not only for the pair plasma, but also for the positron beam and for intermediary non-neutral plasmas. This talk will summarize the project as a whole and recent work by the APEX/PAX team on its various elements.

  3. The energy of a moving quark-antiquark pair in an Script N = 4 SYM plasma

    Chernicoff, Mariano; García, J. Antonio; Güijosa, Alberto

    2006-09-01

    We make use of the AdS/CFT correspondence to determine the energy of an external quark-antiquark pair that moves through strongly-coupled thermal Script N = 4 super-Yang-Mills plasma, both in the rest frame of the plasma and in the rest frame of the pair. It is found that the pair feels no drag force, has an energy that reproduces the expected 1/L (or γ/L) behavior at small quark-antiquark separations, and becomes unbound beyond a certain screening length whose velocity-dependence we determine. We discuss the relation between the high-velocity limit of our results and the lightlike Wilson loop proposed recently as a definition of the jet-quenching parameter.

  4. On the rogue wave propagation in ion pair superthermal plasma

    Abdelwahed, H. G., E-mail: hgomaa-eg@yahoo.com, E-mail: hgomaa-eg@mans.edu.eg; Zahran, M. A. [Physics Department, College of Sciences and Humanities Studies Al-Kharj, Prince Sattam Bin Abdulaziz University, Al-Kharj (Saudi Arabia); Theoretical Physics Group, Physics Department, Faculty of Science, Mansoura University, Mansoura (Egypt); El-Shewy, E. K., E-mail: emadshewy@yahoo.com; Elwakil, S. A. [Theoretical Physics Group, Physics Department, Faculty of Science, Mansoura University, Mansoura (Egypt)

    2016-02-15

    Effects of superthermal electron on the features of nonlinear acoustic waves in unmagnetized collisionless ion pair plasma with superthermal electrons have been examined. The system equations are reduced in the form of the nonlinear Schrodinger equation. The rogue wave characteristics dependences on the ionic density ratio (ν = n{sub –0}/n{sub +0}), ionic mass ratio (Q = m{sub +}/m{sub −}), and superthermality index (κ) are investigated. It is worth mentioning that the results present in this work could be applicable in the Earth's ionosphere plasmas.

  5. Implosive Thermal Plasma Source for Energy Conversion

    Šonský, Jiří; Tesař, Václav; Gruber, Jan; Mašláni, Alan

    2017-01-01

    Roč. 4, č. 1 (2017), s. 87-90 ISSN 2336-2626 Institutional support: RVO:61388998 ; RVO:61389021 Keywords : implosion * thermal plasma * detonation wave Subject RIV: BL - Plasma and Gas Discharge Physics; BL - Plasma and Gas Discharge Physics (UFP-V) OBOR OECD: Fluids and plasma physics (including surface physics); Fluids and plasma physics (including surface physics) (UFP-V) https://ppt.fel.cvut.cz/ppt2017.html#number1

  6. Thermal Plasma Generators with Water Stabilized Arc

    Hrabovský, Milan

    2009-01-01

    Roč. 2, č. 1 (2009), s. 99-104 ISSN 1876-5343 R&D Projects: GA ČR GA202/08/1084 Institutional research plan: CEZ:AV0Z20430508 Keywords : Thermal plasma * plasma torch * Gerdien arc Subject RIV: BL - Plasma and Gas Discharge Physics http://www.bentham.org/open/toppj/openaccess2.htm

  7. Acoustic nonlinear periodic waves in pair-ion plasmas

    Mahmood, Shahzad; Kaladze, Tamaz; Ur-Rehman, Hafeez

    2013-09-01

    Electrostatic acoustic nonlinear periodic (cnoidal) waves and solitons are investigated in unmagnetized pair-ion plasmas consisting of same mass and oppositely charged ion species with different temperatures. Using reductive perturbation method and appropriate boundary conditions, the Korteweg-de Vries (KdV) equation is derived. The analytical solutions of both cnoidal wave and soliton solutions are discussed in detail. The phase plane plots of cnoidal and soliton structures are shown. It is found that both compressive and rarefactive cnoidal wave and soliton structures are formed depending on the temperature ratio of positive and negative ions in pair-ion plasmas. In the special case, it is revealed that the amplitude of soliton may become larger than it is allowed by the nonlinear stationary wave theory which is equal to the quantum tunneling by particle through a potential barrier effect. The serious flaws in the earlier published results by Yadav et al., [PRE 52, 3045 (1995)] and Chawla and Misra [Phys. Plasmas 17, 102315 (2010)] of studying ion acoustic nonlinear periodic waves are also pointed out.

  8. Technological challenges in thermal plasma production

    Ramakrishnan, S.

    1995-01-01

    Thermal plasmas, generated by electric arc discharges, are used in a variety of industrial applications. The electric arc is a constricted electrical discharge with a high temperature in the range 6000-25,000 K. These characteristics are useful in plasma cutting, spraying, welding and specific areas of material processing. The thermal plasma technology is an enabling process technology and its status in the market depends upon its advantages over competing technologies. A few technological challenges to enhance the status of plasma technology are to improve the utilisation of the unique characteristics of the electric arc and to provide enhanced control of the process. In particular, new solutions are required for increasing the plasma-material interaction, controlling the electrode roots and controlling the thermal power generated by the arcing process. In this paper, the advantages of plasma technology, its constraints and future challenges for technology developments are highlighted. 36 refs., 14 figs

  9. Spontaneous hole-clump pair creation in weakly unstable plasmas

    Berk, H.L.; Breizman, B.N.; Petviashvili, N.V.

    1997-03-01

    A numerical simulation of a kinetic instability near threshold shows how a hole and clump spontaneously appear in the particle distribution function. The hole and clump support a pair of Bernstein, Greene, Kruskal (BGK) nonlinear waves that last much longer than the inverse linear damping rate while they are upshifting and downshifting in frequency. The frequency shifting allows a balance between the power nonlinearly extracted from the resonant particles and the power dissipated into the background plasma. These waves eventually decay due to phase space gradient smoothing caused by collisionality

  10. Plasma sheath criterion in thermal electronegative plasmas

    Ghomi, Hamid; Khoramabadi, Mansour; Ghorannevis, Mahmod; Shukla, Padma Kant

    2010-01-01

    The sheath formation criterion in electronegative plasma is examined. By using a multifluid model, it is shown that in a collisional sheath there will be upper as well as lower limits for the sheath velocity criterion. However, the parameters of the negative ions only affect the lower limit.

  11. Progress toward the creation of magnetically confined pair plasmas

    Saitoh, Haruhiko [Max-Planck-Institut fuer Plasmaphysik (Germany); The University of Tokyo (Japan); Hergenhahn, Uwe; Paschkowski, Norbert; Stanja, Juliane; Stenson, Eve V. [Max-Planck-Institut fuer Plasmaphysik (Germany); Niemann, Holger; Sunn Pedersen, Thomas [Max-Planck-Institut fuer Plasmaphysik (Germany); Ernst-Moritz-Arndt-Universitaet Greifswald (Germany); Stoneking, Matthew R. [Max-Planck-Institut fuer Plasmaphysik (Germany); Lawrence University (United States); Hugenschmidt, Christoph; Piochacz, Christian; Vohburger, Sebastian [Technische Universitaet Muenchen (Germany); Schweikhard, Lutz [Ernst-Moritz-Arndt-Universitaet Greifswald (Germany); Danielson, James R.; Surko, Clifford M. [University of California, San Diego (United States)

    2016-07-01

    The PAX (Positron Accumulation eXperiment) and APEX (A Positron Electron eXperiment) projects aim to experimentally study the unique wave propagation and stability properties of pair plasmas. We plan to accumulate a large number of positrons in a multicell-type trap system (PAX) and to confine them with electrons in APEX, a levitated dipole or stellarator configuration, operated at the NEPOMUC facility, the world's most intense positron source. In this contribution, we report on recent results from PAX and APEX. We have conducted electron experiments with a 2.3 T Penning-Malmberg trap; confinement for more than 1 hour and observation of a collective mode were demonstrated. At NEPOMUC, we have characterized the positron beam for a wide energy range. In a prototype permanent-magnet dipole trap, efficient (38%) injection of the remoderated 5 eV positron beam was realized using E x B drifts. Based on these results, design studies on the confinement of pair-plasmas in a levitated dipole trap are ongoing.

  12. A simple, analytical model of collisionless magnetic reconnection in a pair plasma

    Hesse, Michael; Zenitani, Seiji; Kuznetsova, Masha; Klimas, Alex

    2009-01-01

    A set of conservation equations is utilized to derive balance equations in the reconnection diffusion region of a symmetric pair plasma. The reconnection electric field is assumed to have the function to maintain the current density in the diffusion region and to impart thermal energy to the plasma by means of quasiviscous dissipation. Using these assumptions it is possible to derive a simple set of equations for diffusion region parameters in dependence on inflow conditions and on plasma compressibility. These equations are solved by means of a simple, iterative procedure. The solutions show expected features such as dominance of enthalpy flux in the reconnection outflow, as well as combination of adiabatic and quasiviscous heating. Furthermore, the model predicts a maximum reconnection electric field of E * =0.4, normalized to the parameters at the inflow edge of the diffusion region.

  13. A Simple, Analytical Model of Collisionless Magnetic Reconnection in a Pair Plasma

    Hesse, Michael; Zenitani, Seiji; Kuznetova, Masha; Klimas, Alex

    2011-01-01

    A set of conservation equations is utilized to derive balance equations in the reconnection diffusion region of a symmetric pair plasma. The reconnection electric field is assumed to have the function to maintain the current density in the diffusion region, and to impart thermal energy to the plasma by means of quasi-viscous dissipation. Using these assumptions it is possible to derive a simple set of equations for diffusion region parameters in dependence on inflow conditions and on plasma compressibility. These equations are solved by means of a simple, iterative, procedure. The solutions show expected features such as dominance of enthalpy flux in the reconnection outflow, as well as combination of adiabatic and quasi-viscous heating. Furthermore, the model predicts a maximum reconnection electric field of E(sup *)=0.4, normalized to the parameters at the inflow edge of the diffusion region.

  14. Deviations from thermal equilibrium in plasmas

    Burm, K.T.A.L.

    2004-01-01

    A plasma system in local thermal equilibrium can usually be described with only two parameters. To describe deviations from equilibrium two extra parameters are needed. However, it will be shown that deviations from temperature equilibrium and deviations from Saha equilibrium depend on one another. As a result, non-equilibrium plasmas can be described with three parameters. This reduction in parameter space will ease the plasma describing effort enormously

  15. Electrical and thermal conductivities in dense plasmas

    Faussurier, G., E-mail: gerald.faussurier@cea.fr; Blancard, C.; Combis, P.; Videau, L. [CEA, DAM, DIF, F-91297 Arpajon (France)

    2014-09-15

    Expressions for the electrical and thermal conductivities in dense plasmas are derived combining the Chester-Thellung-Kubo-Greenwood approach and the Kramers approximation. The infrared divergence is removed assuming a Drude-like behaviour. An analytical expression is obtained for the Lorenz number that interpolates between the cold solid-state and the hot plasma phases. An expression for the electrical resistivity is proposed using the Ziman-Evans formula, from which the thermal conductivity can be deduced using the analytical expression for the Lorenz number. The present method can be used to estimate electrical and thermal conductivities of mixtures. Comparisons with experiment and quantum molecular dynamics simulations are done.

  16. Thermal instability in a stratified plasma

    Hermanns, D.F.M.; Priest, E.R.

    1989-01-01

    The thermal instability mechansism has been studied in connection to observed coronal features, like, e.g. prominences or cool cores in loops. Although these features show a lot of structure, most studies concern the thermal instability in an uniform medium. In this paper, we investigate the thermal instability and the interaction between thermal modes and the slow magneto-acoustic subspectrum for a stratified plasma slab. We fomulate the relevant system of equations and give some straightforward properties of the linear spectrum of a non-uniform plasma slab, i.e. the existence of continuous parts in the spectrum. We present a numerical scheme with which we can investigate the linear spectrum for equilibrium states with stratification. The slow and thermal subspectra of a crude coronal model are given as a preliminary result. (author). 6 refs.; 1 fig

  17. Cytocompatibility of Plasma and Thermally Treated Biopolymers

    Petr Slepička

    2013-01-01

    Full Text Available This paper is focused on the surface characterization of plasma and consequently thermally treated biocompatible polymers. PLLA (poly(L-lactide acid and PMP (poly-4-methyl-1-pentene are studied. The influence of Ar plasma treatment on the surface polarity of substrate measured immediately after treatment and during the polymer surface aging is studied. Surface roughness, morphology, wettability, and surface chemistry were determined. Plasma treatment leads to significant changes in PLLA surface morphology and chemistry, with the PMP being slightly affected. The higher resistance to plasma fluence results in smaller ablation of PMP than that of PLLA. The plasma treatment improves cell adhesion and proliferation on the PMP. Plasma treatment of PLLA influences mostly the homogeneity of adhered and proliferated VSMC.

  18. Thermally stimulated scattering in plasmas

    Dysthe, K. B.; Mjølhus, E.; Pécseli, H. L.

    1985-01-01

    this experiment local heat conduction is of little importance and the dynamic evolution for the electron temperature is dominated by heating and energy exchange with the ion component. These features are incorporated in the analysis. The resulting set of equations gives a growth rate and characteristic scale size......A theory for stimulated scattering of a laser beam is formulated where the dominant nonlinearity is the ohmic heating of the plasma. The analysis is carried out with particular reference to experimental investigations of CO2 laser heating of linear discharge plasma. In the conditions characterizing...

  19. Hydrogen production by thermal water splitting using a thermal plasma

    Boudesocque, N.; Lafon, C.; Girold, C.; Vandensteendam, C.; Baronnet, J.M.

    2006-01-01

    CEA has been working for more than 10 years in plasma technologies devoted to waste treatment: incineration, vitrification, gases and liquid treatment. Based on this experience, CEA experiments since several years an innovative route for hydrogen production by thermal water splitting, using a plasma as heat source. This new approach could be considered as an alternative to electrolysis for massive hydrogen production from water and electricity. This paper presents a brief state of the art of water thermal plasmas, showing the temperatures and quench velocity ranges technologically achievable today. Thermodynamic properties of a water plasma are presented and discussed. A kinetic computational model is presented, describing the behavior of splitted products during the quench in a plasma plume for various parameters, such as the quench rate. The model results are compared to gas analysis in the plasma plume obtained with in-situ sampling probe. The plasma composition measurements are issued from an Optical Emission Spectroscopic method (OES). The prediction of 30 % H 2 recovery with a 108 K.s -1 quench rate has been verified. A second experimentation has been performed: mass gas analysis, flowrate measurement and OES to study the 'behavior' and species in underwater electrical arc stricken between graphite electrodes. With this quench, a synthesis gas was produced with a content 55 % of hydrogen. (authors)

  20. Non-thermal Plasma and Oxidative Stress

    Toyokuni, Shinya

    2015-09-01

    Thermal plasmas and lasers have been used in medicine to cut and ablate tissues and for coagulation. Non-equilibrium atmospheric pressure plasma (NEAPP; non-thermal plasma) is a recently developed, non-thermal technique with possible biomedical applications. Although NEAPP reportedly generates reactive oxygen/nitrogen species, electrons, positive ions, and ultraviolet radiation, few research projects have been conducted to merge this technique with conventional free radical biology. Recently, Prof. Masaru Hori's group (Plasma Nanotechnology Research Center, Nagoya University) developed a NEAPP device with high electron density. Here electron spin resonance revealed hydroxyl radicals as a major product. To merge non-thermal plasma biology with the preexisting free radical biology, we evaluated lipid peroxidation and DNA modifications in various in vitro and ex vivo experiments. Conjugated dienes increased after exposure to linoleic and alfa-linolenic acids. An increase in 2-thiobarbituric acid-reactive substances was also increased after exposure to phosphatidylcholine, liposomes or liver homogenate. Direct exposure to rat liver in medium produced immunohistochemical evidence of 4-hydroxy-2-nonenal- and acrolein-modified proteins. Exposure to plasmid DNA induced dose-dependent single/double strand breaks and increased the amounts of 8-hydroxy-2'-deoxyguanosine and cyclobutane pyrimidine dimers. These results indicate that oxidative biomolecular damage by NEAPP is dose-dependent and thus can be controlled in a site-specific manner. Simultaneous oxidative and UV-specific DNA damage may be useful in cancer treatment. Other recent advancements in the related studies of non-thermal plasma in Nagoya University Graduate School of Medicine will also be discussed.

  1. Thermal stability of the tokamak plasma edge

    Stacey, W.M.

    1997-01-01

    The general linear, fluid, thermal instability theory for the plasma edge has been extended. An analysis of a two-dimensional fluid model of the plasma edge has identified the importance of many previously unappreciated phenomena associated with parallel and gyroviscous forces in the presence of large radial gradients, with large radial or parallel flows, with the temperature dependence of transport coefficients, and with the coupling of temperature, flow and density perturbations. The radiative condensation effect is generalized to include a further destabilizing condensation effect associated with radial heat conduction. Representative plasma edge neutral and impurity densities are found to be capable of driving thermal instabilities in the edge transport barrier and radiative mantle, respectively. (author)

  2. Thermal efficiency of a non-transferred thermal plasma cannon

    Mercado, A.; Cota, G.; Merlo, L.; Pacheco, J.; Pena, R.; Cruz, A.

    1997-01-01

    This work shows a thermal efficiency research (ν) for a plasma torch in d.c. which was carried out through the realization of an energy balance around the system under consideration. The plasma torch is manufactured in copper with a tungsten incrustations in cathode. The gas used was argon and the gas fluxes were at the rank of 10 and 40 lt/min to the total pressure of 1.2 bar (1.1 atm). With these conditions it was worked with electric currents at the rank of 40 and 180 A. The data were collected through a data acquisition card which was programmed in Windows environment. (Author)

  3. Diagnostic methods of thermal dusty plasma flows

    Nefedov, A.P.

    1995-01-01

    The presence in the high-temperature flows of condensed disperse phase (CDP) particles may lead either to an increase of the electron number density n e if the particles assume a positive charge or to its decrease if the charge is negative. The existence of CDP also may effect on optical parameters of the thermal dusty plasma flows, on heat and radiative transfer in the plasma. The entire range of states, from a Debye plasma to a highly nonideal system of charged particles, is realized in a thermal dusty plasma under standard conditions T=2000-3000 K, n e =10 8 - 10 14 cm -3 . The advanced probe and optical diagnostic instruments are needed to study the optical and electrophysical properties of thermal dusty plasma flows. The diagnostic techniques must give the data about such parameters of gas and dispersed phase as temperatures of gas and particles, number densities of electrons, atoms and ions of alkali metals, sizes, velocities and concentrations of CDP particles. It should be noted that number density of alkali metal atoms and gas temperature may be measured by the well known full absorption and generalized reversal methods. This paper describes the probe and optical techniques for diagnostic of dusty plasma flows developed in High Energy Density Research Center of Russian Academy of Sciences. The Forward Angle Scattering Transmissometer (FAST) allows measurement of the average size (Sauter diameter), mass number density, and refractive index of particles in the 0.5-15.0 gm size range. The basis of the method is a dependence of the measured extinction of radiation upon an angular acceptance aperture of the photo detector. The FAST instrument allows one to determine the mass density and the Sauter diameter of a polydispersion of particles without a priori specification of the particle size distribution model and exact data about the article refractive index

  4. Diagnostic methods of thermal dusty plasma flows

    Nefedov, A.P.

    1995-01-01

    The presence in the high-temperature flows of condensed disperse phase (CDP) particles may lead either to an increase of the electron number density n e if the particles assume a positive charge or to its decrease if the charge is negative. The existence of CDP also may effect on optical parameters of the thermal dusty plasma flows, on heat and radiative transfer in the plasma. The entire range of states, from a Debye plasma to a highly nonideal system of charged particles, is realized in a thermal dusty plasma under standard conditions T=2000-3000 K, n e =10 8 -10 14 cm -3 . The advanced probe and optical diagnostic instruments are needed to study the optical and electrophysical properties of thermal dusty plasma flows. The diagnostic techniques must give the data about such parameters of gas and dispersed phase as temperatures of gas and particles, number densities of electrons, atoms and ions of alkali metals, sizes, velocities and concentrations of CDP particles. It should be noted that number density of alkali metal atoms and gas temperature may be measured by the well known full absorption and generalized reversal methods. This paper describes the probe and optical techniques for diagnostic of dusty plasma flows developed in High Energy Density Research Center of Russian Academy of Sciences. The Forward Angle Scattering Transmissometer (FAST) allows measurement of the average size (Sauter diameter), mass number density, and refractive index of particles in the 0.5-15.0 μm size range. The basis of the method is a dependence of the measured extinction of radiation upon an angular acceptance aperture of the photo detector. The FAST instrument allows one to determine the mass density and the Sauter diameter of a polydispersion of particles without a priori specification of the particle size distribution model and exact data about the particle refractive index

  5. Development of twin cannons of thermal plasma

    Pena E, R.

    1996-01-01

    Today several service and transformation industries that generate hazardous wastes must implement programs in order to fulfill with requirements established by the present standardization. This problem is solved here for proposing the design and construction of a thermal plasma transferred torch with double cannon which is generated by an electric arc with a capacity of 50 k W, a regulable gas flow from 0-50 lt./min and thermal yield higher than 85 %. This equipment would be capable for degradating industrial and hospital wastes. (Author)

  6. Thermal radiation properties of PTFE plasma

    Liu, Xiangyang; Wang, Siyu; Zhou, Yang; Wu, Zhiwen; Xie, Kan; Wang, Ningfei

    2017-06-01

    To illuminate the thermal transfer mechanism of devices adopting polytetrafluoroethylene (PTFE) as ablation materials, the thermal radiation properties of PTFE plasma are calculated and discussed based on local thermodynamic equilibrium (LTE) and optical thin assumptions. It is clarified that line radiation is the dominant mechanism of PTFE plasma. The emission coefficient shows an opposite trend for both wavelength regions divided by 550 nm at a temperature above 15 000 K. The emission coefficient increases with increasing temperature and pressure. Furthermore, it has a good log linear relation with pressure. Equivalent emissivity varies complexly with temperature, and has a critical point between 20 000 K to 25 000 K. The equivalent cross points of the average ionic valence and radiation property are about 10 000 K and 15 000 K for fully single ionization.

  7. Drift waves and counter rotating vortices in pair-ion plasmas

    Haque, Q., E-mail: qamar_haque@hotmail.co [Theoretical Plasma Physics Division, PINSTECH P.O. Nilore, Islamabad (Pakistan)

    2010-07-19

    Linear dispersion relation has been found for drift and acoustic waves in pair-ion-electron plasmas. The stationary solution in the form of counter rotating vortices has been obtained in the presence of equilibrium potential profile. It is noticed that the speed of nonlinear structures is reduced with the increase of electrons concentration in pair-ion plasmas. Linear instability condition has also been found in the presence of shear flow. It is pointed out that the present results can be useful for future pair-ion plasma experiments.

  8. Electron thermal transport in tokamak plasmas

    Konings, J A

    1994-11-30

    The process of fusion of small nuclei thereby releasing energy, as it occurs continuously in the sun, is essential for the existence of mankind. The same process applied in a controlled way on earth would provide a clean and an abundant energy source, and be the long term solution of the energy problem. Nuclear fusion requires an extremely hot (10{sup 8} K) ionized gas, a plasma, that can only be maintained if it is kept insulated from any material wall. In the so called `tokamak` this is achieved by using magnetic fields. The termal insulation, which is essential if one wants to keep the plasma at the high `fusion` temperature, can be predicted using basic plasma therory. A comparison with experiments in tokamaks, however, showed that the electron enery losses are ten to hundred times larger than this theory predicts. This `anomalous transport` of thermal energy implies that, to reach the condition for nuclear fusion, a fusion reactor must have very large dimensions. This may put the economic feasibility of fusion power in jeopardy. Therefore, in a worldwide collaboration, physicists study tokamak plasmas in an attempt to understand and control the energy losses. From a scientific point of view, the mechanisms driving anomalous transport are one of the challenges in fudamental plasma physics. In Nieuwegein, a tokamak experiment (the Rijnhuizen Tokamak Project, RTP) is dedicated to the study of anomalous transport, in an international collaboration with other laboratories. (orig./WL).

  9. Nonlinear electrostatic structures in homogeneous and inhomogeneous pair-ion plasmas

    Mahmood, S.; Ur-Rehman, H.; Shah, A.; Haque, Q.

    2012-01-01

    The nonlinear electrostatic structures such as solitons, shocks were studied in homogeneous, unmagnetized pair-ion plasma. The dissipation in the system was taken through kinematic viscosities of both pair-ion species. The one dimensional (Korteweg-de Vries-Burgers) KdVB equation was derived using reductive perturbation method. The analytical solution of KdVB equation was obtained using tanh method. It was found that solitons and monotonic shocks structures were formed in such type of plasmas depending on the value of dissipation in the system. Both compressive and refractive structures of solitons and monotonic shocks were obtained depending on the temperatures of negative and positive ions. The oscillatory shock structures in pair-ion plasmas were also obtained and its necessary conditions of formation were discussed. The acoustic solitons were also investigated in inhomogeneous unmagnetized pair-ion plasmas. The Korteweg-de Vries (KdV) like equation with an additional term due to density gradients was obtained by employing the reductive perturbation technique. It was found that amplitude of both compressive and refractive solitons was found to be enhanced as the density gradient parameter was increased. The Landau damping rates of electrostatic ion waves were studied for non-Maxwellian or Lorentzian pair-ion plasmas. The Val sov equation was solved analytically for weak damping effects in pair-ion plasma. It was found that Landau damping rate of ion plasma wave was increased in Lorentzian case in comparison with Maxwellian pair-ion plasmas. The numerical results were obtained by taking into account the parameters of pair-ion plasmas produced in laboratory experiments in Japan. (orig./A.B.)

  10. Electron-positron pair production in a hot accretion plasma around a massive black hole

    Takahara, Fumio; Kusunose, Masaaki.

    1985-01-01

    We investigate the electron-positron pair production in a hot accretion plasma around a supermassive black hole in connection with active galactic nuclei. Assuming that an optically thin two-temperature plasma is produced in the vicinity of the central black hole, we examine the condition for the significant pair production by comparing relevant time scales. Since the pair production is dominated by collisions between hard photons, the conditions for significant pair production depend on the production rate of hard photons. We examine the case where the unsaturated Comptonization of soft photons produces hard photons as well as that of bremsstrahlung. We show that significant pair production occurs for a moderately high accretion rate with relatively slow accretion flow as compared to the free fall velocity in both cases. Possible consequences of pair production are briefly discussed. (author)

  11. Hidden vortex lattices in a thermally paired superfluid

    Dahl, E. K.; Sudboe, A.; Babaev, E.

    2008-01-01

    We study the evolution of rotational response of a statistical mechanical model of two-component superfluid with a nondissipative drag interaction as the system undergoes a transition into a paired superfluid phase at finite temperature. The transition manifests itself in a change of (i) vortex-lattice symmetry and (ii) nature of the vortex state. Instead of a vortex lattice, the system forms a highly disordered tangle which constantly undergoes merger and reconnecting processes involving different types of vortices with a 'hidden' breakdown of translation symmetry

  12. Structure functions and pair correlations of the quark-gluon plasma

    Thoma, Markus H.

    2005-01-01

    Recent experiments at RHIC and theoretical considerations indicate that the quark-gluon plasma, present in the fireball of relativistic heavy-ion collisions, might be in a liquid phase. The liquid state can be identified by characteristic correlation and structure functions. Here definitions of the structure functions and pair correlations of the quark-gluon plasma are presented as well as perturbative results. These definitions might be useful for verifying the quark-gluon-plasma liquid in QCD lattice calculations

  13. Thermal Expansion of Vacuum Plasma Sprayed Coatings

    Raj, S V.; Palczer, A. R.

    2010-01-01

    Metallic Cu-8%Cr, Cu-26%Cr, Cu-8%Cr-1%Al, NiAl and NiCrAlY monolithic coatings were fabricated by vacuum plasma spray deposition processes for thermal expansion property measurements between 293 and 1223 K. The corrected thermal expansion, (DL/L(sub 0) varies with the absolute temperature, T, as (DL/L(sub 0) = A(T - 293)(sup 3) + BIT - 293)(sup 2) + C(T - 293) + D, where, A, B, C and D are thermal, regression constants. Excellent reproducibility was observed for all of the coatings except for data obtained on the Cu-8%Cr and Cu-26%Cr coatings in the first heat-up cycle, which deviated from those determined in the subsequent cycles. This deviation is attributed to the presence of residual stresses developed during the spraying of the coatings, which are relieved after the first heat-up cycle. In the cases of Cu-8%Cr and NiAl, the thermal expansion data were observed to be reproducible for three specimens. The linear expansion data for Cu-8% Cr and Cu-26%Cr agree extremely well with rule of mixture (ROM) predictions. Comparison of the data for the Cu-8%Cr coating with literature data for Cr and Cu revealed that the thermal expansion behavior of this alloy is determined by the Cu-rich matrix. The data for NiAl and NiCrAlY are in excellent agreement with published results irrespective of composition and the methods used for processing the materials. The implications of these results on coating GRCop-84 copper alloy combustor liners for reusable launch vehicles are discussed.

  14. Industrial implementation of plasma deposition using the expanding thermal plasma technique

    Sanden, van de M.C.M.; Oever, van den P.J.; Creatore, M.; Schaepkens, M.; Miebach, T.; Iacovangelo, C.D.; Bosch, R.C.M.; Bijker, M.D.; Evers, M.F.J.; Schram, D.C.; Kessels, W.M.M.

    2004-01-01

    Two successful industrial implementations of the expanding thermal plasma setup, a novel plasma source, obtaining high deposition rate are discussed. The Ar/O2/hexamethyldisiloxane and Ar/O2/octamethyl-cyclosiloxane-fed expanding thermal plasma setup is used to deposit scratch resistant silicone

  15. Thermophysical property calculation in thermal plasmas: status, applications, and availability of basic data

    Murphy, Anthony B.

    2002-01-01

    The status of the calculation of the composition, thermodynamic properties and transport coefficients of thermal plasmas is reviewed. The availability of the required basic data, i.e., thermodynamic properties of individual species and collision integrals for pairs of species, is surveyed. The calculation of diffusion coefficients, required in mixed-gas plasmas, is discussed, and the advantages of the combined diffusion coefficient formulation are outlined. The specific application of demixing is presented. Recent work addressing the difficulties that arise in calculating the composition and transport coefficients of two-temperature plasmas is briefly reviewed. (author)

  16. What makes a thermal plasma suitable for hazardous waste disposal

    Benocci, R.; Florio, R.; Galassi, A.; Paolicchio, M.; Sindoni, E.

    1997-01-01

    The basic transport and thermodynamic characteristic of a thermal plasma are analysed in order to emphasize those properties that make a high-temperature source profitable and suitable over the conventional devices for hazardous waste treatment. In addition a survey of the basic reaction sequence and apparatus units is made together with the different approaches to thermal plasma waste treatments

  17. Gyro-viscosity and linear dispersion relations in pair-ion magnetized plasmas

    Kono, M. [Faculty of Policy Studies, Chuo University, Tokyo 192-0393 (Japan); Vranjes, J. [Instituto de Astrofisica de Canarias, Tenerife E38205 (Spain); Departamento de Astrofisica, Universidad de La Laguna, Tenerife E38205 (Spain)

    2015-11-15

    A fluid theory has been developed by taking account of gyro-viscosity to study wave propagation characteristics in a homogeneous pair-ion magnetized plasma with a cylindrical symmetry. The exact dispersion relations derived by the Hankel-Fourier transformation are shown comparable with those observed in the experiment by Oohara and co-workers. The gyro-viscosity is responsible for the change in propagation characteristics of the ion cyclotron wave from forward to backward by suppressing the effect of the thermal pressure which normally causes the forward nature of dispersion. Although the experiment has been already explained by a kinetic theory by the present authors, the kinetic derivations are so involved because of exact particle orbits in phase space, finite Lamor radius effects, and higher order ion cyclotron resonances. The present fluid theory provides a simple and transparent structure to the dispersion relations since the gyro-viscosity is renormalized into the ion cyclotron frequency which itself indicates the backward nature of dispersion. The usual disadvantage of a fluid theory, which treats only fundamental modes of eigen-waves excited in a system and is not able to describe higher harmonics that a kinetic theory does, is compensated by simple derivations and clear picture based on the renormalization of the gyro-viscosity.

  18. Interesting features of nonlinear shock equations in dissipative pair-ion-electron plasmas

    Masood, W.; Rizvi, H.

    2011-01-01

    Two dimensional nonlinear electrostatic waves are studied in unmagnetized, dissipative pair-ion-electron plasmas in the presence of weak transverse perturbation. The dissipation in the system is taken into account by incorporating the kinematic viscosity of both positive and negative ions. In the linear case, a biquadratic dispersion relation is obtained, which yields the fast and slow modes in a pair-ion-electron plasma. It is shown that the limiting cases of electron-ion and pair-ion can be retrieved from the general biquadratic dispersion relation, and the differences in the characters of the waves propagating in both the cases are also highlighted. Using the small amplitude approximation method, the nonlinear Kadomtsev Petviashvili Burgers as well as Burgers-Kadomtsev Petviashvili equations are derived and their applicability for pair-ion-electron plasma is explained in detail. The present study may have relevance to understand the formation of two dimensional electrostatic shocks in laboratory produced pair-ion-electron plasmas.

  19. Monitoring non-thermal plasma processes for nanoparticle synthesis

    Mangolini, Lorenzo

    2017-09-01

    Process characterization tools have played a crucial role in the investigation of dusty plasmas. The presence of dust in certain non-thermal plasma processes was first detected by laser light scattering measurements. Techniques like laser induced particle explosive evaporation and ion mass spectrometry have provided the experimental evidence necessary for the development of the theory of particle nucleation in silane-containing non-thermal plasmas. This review provides first a summary of these early efforts, and then discusses recent investigations using in situ characterization techniques to understand the interaction between nanoparticles and plasmas. The advancement of such monitoring techniques is necessary to fully develop the potential of non-thermal plasmas as unique materials synthesis and processing platforms. At the same time, the strong coupling between materials and plasma properties suggest that it is also necessary to advance techniques for the measurement of plasma properties while in presence of dust. Recent progress in this area will be discussed.

  20. Development of plasma properties along thermal plasma jet generated by hybrid water-argon torch

    Kavka, Tetyana; Hrabovský, Milan

    2002-01-01

    Roč. 52, supplement D (2002), s. 637-642 ISSN 0011-4626. [Symposium on Plasma Physics and Technology/20th./. Prague, 10.06.2002-13.06.2002] Institutional research plan: CEZ:AV0Z2043910 Keywords : thermal plasma, plasma jet, enthalpy probe Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 0.311, year: 2002

  1. Antibacterial characteristics of thermal plasma spray system.

    Goudarzi, M; Saviz, Sh; Ghoranneviss, M; Salar Elahi, A

    2018-03-15

    The objective of this study is to investigate antibacterial characteristics of a thermal plasma spray system. For this purpose, copper powder was coated on a handmade atmospheric plasma spraying system made by the stainless steel 316 substrate, which is preheated at different temperatures before spraying. A number of deposition characteristics such as antibacterial characteristics, adhesion strength and hardness of coating, was investigated. All of the spray parameters are fixed except the substrate temperature. The chemical composition was analyzed by X-ray diffraction (XRD). A scanning electron microscopy (SEM) and back scattering electron microscopy (BSE) were used to show the coating microstructure, its thickness and also the powder micrograph. The energy dispersive X-ray spectroscopy (EDX) was used to analyze the coating particles. Hardness of the deposition was examined by Vickers tester (HV0.1). Its adhesion strength was declared by cross cut tester (TQC). In addition, the percentage of bactericidal coating was evidenced with Staphylococcus aurous and Escherichia coli bacteria. Study results show that as the substrates temperature increases, the number of splats in the shape of pancake increases, the greatness and percentage of the deposition porosity both decrease. The increment of the substrate temperature leads to more oxidation and makes thicker dendrites on the splat. The enhancement of the substrate temperature also enlarges thickness and efficiency of coating. The interesting results are that antibacterial properties of coatings against the Escherichia coli are more than Staphylococcus aurous bacteria. However the bactericidal percentage of the coatings against Staphylococcus aurous and Escherichia coli bacteria roughly does not change with increasing the substrate temperature. Furthermore, by increment of the substrate temperature, coatings with both high adhesion and hardness are obtained. Accordingly, the temperature of substrate can be an

  2. Treatment of hazardous wastes by DC thermal plasma arc discharge

    Toru, Iwao; Yafang, Liu; Furuta, N.; Tsuginori, Inaba

    2001-01-01

    The temperature of the DC thermal plasma arc discharge is discussed, and examples of the waste treatment for the inorganic compounds such as fly ash, asbestos, and for the organic compounds such as the toxic dioxines and TBT by using the DC plasma arc discharge are shown. In addition, the plasma treatment by using a radiant power emitted from the DC plasma arc discharge is also shown as another new kind of ones. (authors)

  3. Numerical Modelling of Wood Gasification in Thermal Plasma Reactor

    Hirka, Ivan; Živný, Oldřich; Hrabovský, Milan

    2017-01-01

    Roč. 37, č. 4 (2017), s. 947-965 ISSN 0272-4324 Institutional support: RVO:61389021 Keywords : Plasma modelling * CFD * Thermal plasma reactor * Biomass * Gasification * Syngas Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: Fluids and plasma physics (including surface physics) Impact factor: 2.355, year: 2016 https://link.springer.com/article/10.1007/s11090-017-9812-z

  4. Erratum: A Simple, Analytical Model of Collisionless Magnetic Reconnection in a Pair Plasma

    Hesse, Michael; Zenitani, Seiji; Kuznetsova, Masha; Klimas, Alex

    2011-01-01

    The following describes a list of errata in our paper, "A simple, analytical model of collisionless magnetic reconnection in a pair plasma." It supersedes an earlier erratum. We recently discovered an error in the derivation of the outflow-to-inflow density ratio.

  5. Plasma Thermal Conversion of Methane to Acetylene

    Fincke, James Russell; Anderson, Raymond Paul; Hyde, Timothy Allen; Detering, Brent Alan; Wright, Randy Ben; Bewley, Randy Lee; Haggard, Delon C; Swank, William David

    2002-01-01

    This paper describes a re-examination of a known process for the direct plasma thermal conversion of methane to acetylene. Conversion efficiencies (% methane converted) approached 100% and acetylene yields in the 90-95% range with 2-4% solid carbon production were demonstrated. Specificity for acetylene was higher than in prior work. Improvements in conversion efficiency, yield, and specificity were due primarily to improved injector design and reactant mixing, and minimization of temperature gradients and cold boundary layers. At the 60-kilowatt scale cooling by wall heat transfer appears to be sufficient to quench the product stream and prevent further reaction of acetylene resulting in the formation of heavier hydrocarbon products or solid carbon. Significantly increasing the quenching rate by aerodynamic expansion of the products through a converging-diverging nozzle led to a reduction in the yield of ethylene but had little effect on the yield of other hydrocarbon products. While greater product selectivity for acetylene has been demonstrated, the specific energy consumption per unit mass of acetylene produced was not improved upon. A kinetic model that includes the reaction mechanisms resulting in the formation of acetylene and heavier hydrocarbons, through benzene, is described

  6. The plasma wake field excitation: Recent developments from thermal to quantum regime

    Fedele, Renato; Tanjia, Fatema; de Nicola, Sergio; Jovanović, Dušan; Jovanović

    2013-12-01

    To describe the transverse nonlinear and collective self-consistent interaction of a long relativistic electron or positron beam with an unmagnetized plasma, a pair of coupled nonlinear differential equations were proposed by Fedele and Shukla in 1992 (Fedele, R. and Shukla, P. K. 1992a Phys. Rev. A 45, 4045). They were obtained within the quantum-like description provided by the thermal wave model and the theory of plasma wake field excitation. The pair of equations comprises a 2D Schrödinger-like equation for a complex wave function (whose squared modulus is proportional to beam density) and a Poisson-like equation for the plasma wake potential. The dispersion coefficient of the Schrödinger-like equation is proportional to the beam thermal emittance. More recently, Fedele-Shukla equations have been further applied to magnetized plasmas, and solutions were found in the form of nonlinear vortex states and ring solitons. They have been also applied to plasma focusing problems and extended from thermal to quantum regimes. We present here a review of the original approach, and subsequent developments.

  7. High resolution X-ray spectroscopy of thermal plasmas

    Canizares, C.R.

    1990-01-01

    This paper concentrates on reviewing highlights of the Focal Plane Crystal Spectrometer (FPCS) results on thermal plasmas, particularly supernova remnants (SNRs) and clusters of galaxies from the Einstein observatory. During Einstein's short but happy life, we made over 400 observations with the FPCS of 40 different objects. Three quarters of these were objects in which the emission was primarily from optically thin thermal plasma, primarily supernova remnants (SNRs) and clusters of galaxies. Thermal plasmas provide an excellent illustration of how spectral data, particularly high resolution spectral data, can be an important tool for probing the physical properties of astrophysical objects. (author)

  8. Anisotropic Thermal Diffusivities of Plasma-Sprayed Thermal Barrier Coatings

    Akoshima, Megumi; Takahashi, Satoru

    2017-09-01

    Thermal barrier coatings (TBCs) are used to shield the blades of gas turbines from heat and wear. There is a pressing need to evaluate the thermal conductivity of TBCs in the thermal design of advanced gas turbines with high energy efficiency. These TBCs consist of a ceramic-based top coat and a bond coat on a superalloy substrate. Usually, the focus is on the thermal conductivity in the thickness direction of the TBC because heat tends to diffuse from the surface of the top coat to the substrate. However, the in-plane thermal conductivity is also important in the thermal design of gas turbines because the temperature distribution within the turbine cannot be ignored. Accordingly, a method is developed in this study for measuring the in-plane thermal diffusivity of the top coat. Yttria-stabilized zirconia top coats are prepared by thermal spraying under different conditions. The in-plane and cross-plane thermal diffusivities of the top coats are measured by the flash method to investigate the anisotropy of thermal conduction in a TBC. It is found that the in-plane thermal diffusivity is higher than the cross-plane one for each top coat and that the top coats have significantly anisotropic thermal diffusivity. The cross-sectional and in-plane microstructures of the top coats are observed, from which their porosities are evaluated. The thermal diffusivity and its anisotropy are discussed in detail in relation to microstructure and porosity.

  9. Kinetics of electron-positron pair plasmas using an adaptive Monte Carlo method

    Pilla, R.P.; Shaham, J.

    1997-01-01

    A new algorithm for implementing the adaptive Monte Carlo method is given. It is used to solve the Boltzmann equations that describe the time evolution of a nonequilibrium electron-positron pair plasma containing high-energy photons. These are coupled nonlinear integro-differential equations. The collision kernels for the photons as well as pairs are evaluated for Compton scattering, pair annihilation and creation, bremsstrahlung, and Coulomb collisions. They are given as multidimensional integrals which are valid for all energies. For an homogeneous and isotropic plasma with no particle escape, the equilibrium solution is expressed analytically in terms of the initial conditions. For two specific cases, for which the photon and the pair spectra are initially constant or have a power-law distribution within the given limits, the time evolution of the plasma is analyzed using the new method. The final spectra are found to be in a good agreement with the analytical solutions. The new algorithm is faster than the Monte Carlo scheme based on uniform sampling and more flexible than the numerical methods used in the past, which do not involve Monte Carlo sampling. It is also found to be very stable. Some astrophysical applications of this technique are discussed. copyright 1997 The American Astronomical Society

  10. Non-Thermal Sanitation By Atmospheric Pressure Plasma, Phase I

    National Aeronautics and Space Administration — ORBITEC proposes to develop a non-thermal technology based on atmospheric-pressure (AP) cold plasma to sanitize foods, food packaging materials, and other hardware...

  11. Synthesis of functional nanocrystallites through reactive thermal plasma processing

    Takamasa Ishigaki and Ji-Guang Li

    2007-01-01

    Full Text Available A method of synthesizing functional nanostructured powders through reactive thermal plasma processing has been developed. The synthesis of nanosized titanium oxide powders was performed by the oxidation of solid and liquid precursors. Quench gases, either injected from the shoulder of the reactor or injected counter to the plasma plume from the bottom of the reactor, were used to vary the quench rate, and therefore the particle size, of the resultant powders. The experimental results are well supported by numerical analysis on the effects of the quench gas on the flow pattern and temperature field of the thermal plasma as well as on the trajectory and temperature history of the particles. The plasma-synthesized TiO2 nanoparticles showed phase preferences different from those synthesized by conventional wet-chemical processes. Nanosized particles of high crystallinity and nonequilibrium chemical composition were formed in one step via reactive thermal plasma processing.

  12. Non-thermal plasma mills bacteria: Scanning electron microscopy observations

    Lunov, O.; Churpita, O.; Zablotskii, V.; Jäger, A.; Dejneka, A.; Deyneka, I. G.; Meshkovskii, I. K.; Syková, E.; Kubinová, Š.

    2015-01-01

    Non-thermal plasmas hold great promise for a variety of biomedical applications. To ensure safe clinical application of plasma, a rigorous analysis of plasma-induced effects on cell functions is required. Yet mechanisms of bacteria deactivation by non-thermal plasma remain largely unknown. We therefore analyzed the influence of low-temperature atmospheric plasma on Gram-positive and Gram-negative bacteria. Using scanning electron microscopy, we demonstrate that both Gram-positive and Gram-negative bacteria strains in a minute were completely destroyed by helium plasma. In contrast, mesenchymal stem cells (MSCs) were not affected by the same treatment. Furthermore, histopathological analysis of hematoxylin and eosin–stained rat skin sections from plasma–treated animals did not reveal any abnormalities in comparison to control ones. We discuss possible physical mechanisms leading to the shred of bacteria under non-thermal plasma irradiation. Our findings disclose how helium plasma destroys bacteria and demonstrates the safe use of plasma treatment for MSCs and skin cells, highlighting the favorability of plasma applications for chronic wound therapy

  13. Preliminary experiments on wastes degradation by thermal plasma

    Cota S, G.; Pacheco S, J.; Segovia R, A.; Pena E, R.; Merlo S, L.

    1996-01-01

    This work presents the fundamental aspects involved in the installation and start up of an experimental equipment for the hazardous wastes degradation using the thermal plasma technology. It is mentioned about the form in which the thermal plasma is generated and the characteristics that its make to be an appropriate technology for the hazardous wastes degradation. Just as the installed structures for to realize the experiments and results of the first studies on degradation, using nylon as problem sample. (Author)

  14. Monitoring system for thermal plasma; Sistema de monitoreo para plasma termico

    Romero G, M.; Vilchis P, A.E. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1999-07-01

    In the Thermal plasma applications laboratory it has been the degradation project of oils for isolation in transformers. These are a very hazardous residues and at this time in the country they are stored in metal barrels. It has been the intention to undergo the oils to plasma for degradate them to non-hazardous residues. The system behavior must be monitored to establish the thermal plasma behavior. (Author)

  15. Multi-Directional Optical Diagnostics of Thermal Plasma Jets

    Hlína, Jan; Chvála, František; Šonský, Jiří; Gruber, Jan

    2008-01-01

    Roč. 19, č. 1 (2008), s. 1-6 ISSN 0957-0233 R&D Projects: GA ČR(CZ) GA202/05/0728 Institutional research plan: CEZ:AV0Z20570509 Keywords : thermal plasma jet * optical diagnostics * Radon transform Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.493, year: 2008

  16. Formation of thermal eddies during rf heating of plasma

    Motley, R.W.; Hooke, W.M.; Anania, G.

    1979-07-01

    Moderate power (approx.1 kW) excitation of lower hybrid waves in a linear plasma column is found to increase the reflectivity of the phased waveguide exciter and to change the vertical position of the resonance cone. Probing of the plasma near the mouth of the waveguide reveals that the increased reflection results from an undulation in the plasma surface. We present evidence that this surface distortion is driven by thermal eddies associated with asymmetrical electron heating

  17. Modeling of thermalization phenomena in coaxial plasma accelerators

    Subramaniam, Vivek; Panneerchelvam, Premkumar; Raja, Laxminarayan L.

    2018-05-01

    Coaxial plasma accelerators are electromagnetic acceleration devices that employ a self-induced Lorentz force to produce collimated plasma jets with velocities ~50 km s‑1. The accelerator operation is characterized by the formation of an ionization/thermalization zone near gas inlet of the device that continually processes the incoming neutral gas into a highly ionized thermal plasma. In this paper, we present a 1D non-equilibrium plasma model to resolve the plasma formation and the electron-heavy species thermalization phenomena that take place in the thermalization zone. The non-equilibrium model is based on a self-consistent multi-species continuum description of the plasma with finite-rate chemistry. The thermalization zone is modelled by tracking a 1D gas-bit as it convects down the device with an initial gas pressure of 1 atm. The thermalization process occurs in two stages. The first is a plasma production stage, associated with a rapid increase in the charged species number densities facilitated by cathode surface electron emission and volumetric production processes. The production stage results in the formation of a two-temperature plasma with electron energies of ~2.5 eV in a low temperature background gas of ~300 K. The second, a temperature equilibration stage, is characterized by the energy transfer between the electrons and heavy species. The characteristic length scale for thermalization is found to be comparable to axial length of the accelerator thus putting into question the equilibrium magnetohydrodynamics assumption used in modeling coaxial accelerators.

  18. A new purely growing instability in a strongly magnetized nonuniform pair plasma

    Shukla, Nitin; Shukla, P.K.

    2007-01-01

    It is shown that a strongly magnetized nonuniform electron-positron (hereafter referred to as e-p or pair) plasma is unstable against low-frequency (in comparison with the electron gyrofrequency) electrostatic oscillations. For this purpose, a dispersion relation is derived by using the Poisson equation as well as the electron and positron continuity equations with the guiding center drifts for the electron and positron fluids. The dispersion relation admits a purely growing instability in the presence of the equilibrium density and magnetic field inhomogeneities. Physically, instability arises because of the inhomogeneous magnetic field induced differential electron and positron density fluctuations, which do not keep in phase with the electrostatic potential arising from the charge separation in our nonuniform pair plasmas

  19. Ion acoustic waves in pair-ion plasma: Linear and nonlinear analyses

    Saeed, R.; Mushtaq, A.

    2009-01-01

    Linear and nonlinear properties of low frequency ion acoustic wave (IAW) in pair-ion plasma in the presence of electrons are investigated. The dispersion relation and Kadomtsev-Petviashvili equation for linear/nonlinear IAW are derived from sets of hydrodynamic equations where the ion pairs are inertial while electrons are Boltzmannian. The dispersion curves for various concentrations of electrons are discussed and compared with experimental results. The predicted linear IAW propagates at the same frequencies as those of the experimentally observed IAW if n e0 ∼10 4 cm -3 . It is found that nonlinear profile of the ion acoustic solitary waves is significantly affected by the percentage ratio of electron number density and temperature. It is also determined that rarefactive solitary waves can propagate in this system. It is hoped that the results presented in this study would be helpful in understanding the salient features of the finite amplitude localized ion acoustic solitary pulses in a laboratory fullerene plasma.

  20. Electron cyclotron emission from thermal plasmas

    Fidone, I.; Granata, G.

    1978-02-01

    Electron cyclotron radiation from a warm inhomogeneous plasma is investigated. A direct calculation of the emissive power of a plasma slab is performed using Rytov's method and the result is compared with the solution of the transfer equation. It is found that, for arbitrary directions of emission, the two results differ, which reflects the fact that Kirchhoff's law is not generally obeyed

  1. On thermalization of electron-positron-photon plasma

    Siutsou, I. A., E-mail: siutsou@icranet.org [CAPES–ICRANet program, ICRANet–Rio, CBPF 22290-180, Rua Dr. Xavier Sigaud, 150, Urca, Rio de Janeiro, RJ (Brazil); Aksenov, A. G. [Institute for Computer-Aided Design, Russian Academy of Sciences 123056, 2nd Brestskaya st., 19/18, Moscow (Russian Federation); Vereshchagin, G. V. [ICRANet 65122, p.le della Republica, 10, Pescara (Italy)

    2015-12-17

    Recently a progress has been made in understanding thermalization mechanism of relativistic plasma starting from a non-equilibrium state. Relativistic Boltzmann equations were solved numerically for homogeneous isotropic plasma with collision integrals for two- and three-particle interactions calculated from the first principles by means of QED matrix elements. All particles were assumed to fulfill Boltzmann statistics. In this work we follow plasma thermalization by accounting for Bose enhancement and Pauli blocking in particle interactions. Our results show that particle in equilibrium reach Bose-Einstein distribution for photons, and Fermi-Dirac one for electrons, respectively.

  2. Analytical method for thermal stress analysis of plasma facing materials

    You, J. H.; Bolt, H.

    2001-10-01

    The thermo-mechanical response of plasma facing materials (PFMs) to heat loads from the fusion plasma is one of the crucial issues in fusion technology. In this work, a fully analytical description of the thermal stress distribution in armour tiles of plasma facing components is presented which is expected to occur under typical high heat flux (HHF) loads. The method of stress superposition is applied considering the temperature gradient and thermal expansion mismatch. Several combinations of PFMs and heat sink metals are analysed and compared. In the framework of the present theoretical model, plastic flow and the effect of residual stress can be quantitatively assessed. Possible failure features are discussed.

  3. Analytical method for thermal stress analysis of plasma facing materials

    You, J.H.; Bolt, H.

    2001-01-01

    The thermo-mechanical response of plasma facing materials (PFMs) to heat loads from the fusion plasma is one of the crucial issues in fusion technology. In this work, a fully analytical description of the thermal stress distribution in armour tiles of plasma facing components is presented which is expected to occur under typical high heat flux (HHF) loads. The method of stress superposition is applied considering the temperature gradient and thermal expansion mismatch. Several combinations of PFMs and heat sink metals are analysed and compared. In the framework of the present theoretical model, plastic flow and the effect of residual stress can be quantitatively assessed. Possible failure features are discussed

  4. On thermalization of electron-positron-photon plasma

    Siutsou, I. A.; Aksenov, A. G.; Vereshchagin, G. V.

    2015-12-01

    Recently a progress has been made in understanding thermalization mechanism of relativistic plasma starting from a non-equilibrium state. Relativistic Boltzmann equations were solved numerically for homogeneous isotropic plasma with collision integrals for two- and three-particle interactions calculated from the first principles by means of QED matrix elements. All particles were assumed to fulfill Boltzmann statistics. In this work we follow plasma thermalization by accounting for Bose enhancement and Pauli blocking in particle interactions. Our results show that particle in equilibrium reach Bose-Einstein distribution for photons, and Fermi-Dirac one for electrons, respectively.

  5. Modeling of thermal plasma arc technology FY 1994 report

    Hawkes, G.L.; Nguyen, H.D.; Paik, S.; McKellar, M.G.

    1995-03-01

    The thermal plasma arc process is under consideration to thermally treat hazardous and radioactive waste. A computer model for the thermal plasma arc technology was designed as a tool to aid in the development and use of the plasma arc-Joule beating process. The value of this computer model is to: (a) aid in understanding the plasma arc-Joule beating process as applied to buried waste or exhumed buried waste, (b) help design melter geometry and electrode configuration, (c) calculate the process capability of vitrifying waste (i.e., tons/hour), (d) develop efficient plasma and melter operating conditions to optimize the process and/or reduce safety hazards, (e) calculate chemical reactions during treatment of waste to track chemical composition of off-gas products, and composition of final vitrified waste form and (f) help compare the designs of different plasma-arc facilities. A steady-state model of a two-dimensional axisymmetric transferred plasma arc has been developed and validated. A parametric analysis was performed that studied the effects of arc length, plasma gas composition, and input power on the temperatures and velocity profiles of the slag and plasma gas. A two-dimensional transient thermo-fluid model of the US Bureau of Mines plasma arc melter has been developed. This model includes the growth of a slag pool. The thermo-fluid model is used to predict the temperature and pressure fields within a plasma arc furnace. An analysis was performed to determine the effects of a molten metal pool on the temperature, velocity, and voltage fields within the slag. A robust and accurate model for the chemical equilibrium calculations has been selected to determine chemical composition of final waste form and off-gas based on the temperatures and pressures within the plasma-arc furnace. A chemical database has been selected. The database is based on the materials to be processed in the plasma arc furnaces

  6. Thermal detection of single e-h pairs in a biased silicon crystal detector

    Romani, R. K.; Brink, P. L.; Cabrera, B.; Cherry, M.; Howarth, T.; Kurinsky, N.; Moffatt, R. A.; Partridge, R.; Ponce, F.; Pyle, M.; Tomada, A.; Yellin, S.; Yen, J. J.; Young, B. A.

    2018-01-01

    We demonstrate that individual electron-hole pairs are resolved in a 1 cm2 by 4 mm thick silicon crystal (0.93 g) operated at ˜35 mK. One side of the detector is patterned with two quasiparticle-trap-assisted electro-thermal-feedback transition edge sensor arrays held near ground potential. The other side contains a bias grid with 20% coverage. Bias potentials up to ±160 V were used in the work reported here. A fiber optic provides 650 nm (1.9 eV) photons that each produce an electron-hole (e- h+) pair in the crystal near the grid. The energy of the drifting charges is measured with a phonon sensor noise σ ˜0.09 e- h+ pair. The observed charge quantization is nearly identical for h+s or e-s transported across the crystal.

  7. Non-thermal gamma-ray emission from delayed pair breakdown in a magnetized and photon-rich outflow

    Gill, Ramandeep; Thompson, Christopher, E-mail: rgill@cita.utoronto.ca [Canadian Institute for Theoretical Astrophysics, 60 St. George Street, Toronto, ON M5S 3H8 (Canada)

    2014-12-01

    We consider delayed, volumetric heating in a magnetized outflow that has broken out of a confining medium and expanded to a high Lorentz factor (Γ ∼ 10{sup 2}-10{sup 3}) and low optical depth to scattering (τ {sub T} ∼ 10{sup –3}-10{sup –2}). The energy flux at breakout is dominated by the magnetic field, with a modest contribution from quasi-thermal gamma rays whose spectrum was calculated in Paper I. We focus on the case of extreme baryon depletion in the magnetized material, but allow for a separate baryonic component that is entrained from a confining medium. Dissipation is driven by relativistic motion between these two components, which develops once the photon compactness drops below 4 × 10{sup 3}(Y{sub e} /0.5){sup –1}. We first calculate the acceleration of the magnetized component following breakout, showing that embedded MHD turbulence provides significant inertia, the neglect of which leads to unrealistically high estimates of flow Lorentz factor. After reheating begins, the pair and photon distributions are evolved self-consistently using a one-zone kinetic code that incorporates an exact treatment of Compton scattering, pair production and annihilation, and Coulomb scattering. Heating leads to a surge in pair creation, and the scattering depth saturates at τ {sub T} ∼ 1-4. The plasma maintains a very low ratio of particle to magnetic pressure, and can support strong anisotropy in the charged particle distribution, with cooling dominated by Compton scattering. High-energy power-law spectra with photon indices in the range observed in gamma-ray bursts (GRBs; –3 < β < –3/2) are obtained by varying the ratio of heat input to the seed energy in quasi-thermal photons. We contrast our results with those for continuous heating across an expanding photosphere, and show that the latter model produces soft-to-hard evolution that is inconsistent with observations of GRBs.

  8. Thermal condensation mode in a dusty plasma

    We find that the charge variability of the grain reduces the growth rate ..... Thus, in the short wavelength regime, thermal conductivity has stabilizing effect .... dynamics is retained, and the reason being that the momentum exchange of the grain ...

  9. Silver-mediated base pairings: towards dynamic DNA nanostructures with enhanced chemical and thermal stability

    Swasey, Steven M; Gwinn, Elisabeth G

    2016-01-01

    The thermal and chemical fragility of DNA nanomaterials assembled by Watson–Crick (WC) pairing constrain the settings in which these materials can be used and how they can be functionalized. Here we investigate use of the silver cation, Ag + , as an agent for more robust, metal-mediated self-assembly, focusing on the simplest duplex building blocks that would be required for more elaborate Ag + –DNA nanostructures. Our studies of Ag + -induced assembly of non-complementary DNA oligomers employ strands of 2–24 bases, with varied base compositions, and use electrospray ionization mass spectrometry to determine product compositions. High yields of duplex products containing narrowly distributed numbers of Ag + can be achieved by optimizing solution conditions. These Ag + -mediated duplexes are stable to at least 60 mM Mg 2+ , higher than is necessary for WC nanotechnology schemes such as tile assemblies and DNA origami, indicating that sequential stages of Ag + -mediated and WC-mediated assembly may be feasible. Circular dichroism spectroscopy suggests simple helical structures for Ag + -mediated duplexes with lengths to at least 20 base pairs, and further indicates that the structure of cytosine-rich duplexes is preserved at high urea concentrations. We therefore propose an approach towards dynamic DNA nanomaterials with enhanced thermal and chemical stability through designs that combine sturdy silver-mediated ‘frames’ with WC paired ‘pictures’. (paper)

  10. Plasma processes and film growth of expanding thermal plasma deposited textured zinc oxide

    Groenen, R.; Linden, J.L.; Sanden, van de M.C.M.

    2005-01-01

    Plasma processes and film growth of textured zinc oxide deposited from oxygen and diethyl zinc utilizing expanding thermal argon plasma created by a cascaded arc is discussed. In all conditions explored, an excess of argon ions and low temperature electrons is available, which represent the

  11. Therapeutic plasma exchange: a paired comparison of Fresenius AS104 vs. COBE Spectra.

    Burgstaler, E A; Pineda, A A

    2001-01-01

    For therapeutic plasma exchange (TPE), continuous flow separators are known to be efficient as exemplified by Fresenius AS104 and COBE Spectra. The AS104 uses an interface monitoring system in the centrifuge during TPE, whereas Spectra uses computer algorithms to establish the plasma-cell interface. To determine the plasma collection efficiency (PLCE), anticoagulant (AC) volumes used, and platelets (PLT) lost of the AS104 and the Spectra, we performed a prospective paired comparison of 20 TPE (each machine). The study included 17 patients, 1.3 plasma volume exchanges (without AC), equal inlet rates, and AC ratio of 13:1. Processing times did not include reinfuse mode. Platelet loss was determined by sampling the collection bags. Inlet rates were between 60-110 ml/min. Diagnosis included peripheral neuropathies, TTP and cryoglobulinemia. The AS104 had significantly (P<0.0001) lower average whole blood processed (F:6,601 vs. S:8,584 ml), AC volume (F:532 vs. S:719 ml), and processing time (F:80 vs. S:102 minutes) than Spectra. The AS104 had significantly (P<0.0001) higher average plasma flow rates (F:53 vs. S:44 ml/minute), plasma collection efficiency (F:90 vs. S:69%), and platelet loss (F:2.0 vs. S:0.14 x 10(11) plt) than Spectra. Platelet loss correlated with inlet flow rate with the AS104 but not with the Spectra. The AS104 has a significantly higher collection efficiency than Spectra allowing it to remove the same amount of plasma in significantly less time, by processing significantly less blood, using significantly less AC, but removing significantly more platelets than Spectra. Copyright 2001 Wiley-Liss, Inc.

  12. Statistics of turbulent structures in a thermal plasma jet

    Hlína, Jan; Šonský, Jiří; Něnička, Václav; Zachar, Andrej

    2005-01-01

    Roč. 38, - (2005), s. 1760-1768 ISSN 0022-3727 R&D Projects: GA AV ČR(CZ) IAA1057202; GA ČR(CZ) GA202/05/0728 Institutional research plan: CEZ:AV0Z20570509 Keywords : turbulent structures * thermal plasma jet Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.957, year: 2005

  13. Spatial Dynamics of Coherent Structures in a Thermal Plasma Jet

    Hlína, Jan; Sekerešová, Zuzana; Šonský, Jiří

    2008-01-01

    Roč. 36, č. 4 (2008), s. 1066-1067 ISSN 0093-3813 R&D Projects: GA ČR GA202/05/0728 Institutional research plan: CEZ:AV0Z20570509 Keywords : charge-coupled-device (CCD) camera * coherent structure * thermal plasma jet * turbulence Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.447, year: 2008

  14. Thermal fluctuations and critical behavior in a magnetized, anisotropic plasma

    Hazeltine, R. D.; Mahajan, S. M.

    2013-01-01

    Thermal fluctuations in a magnetized, anisotropic plasma are studied by applying standard methods, based on the Einstein rule, to the known thermodynamic potential of the system. It is found in particular that magnetic fluctuations become critical when the anisotropy p ∥ −p ⊥ changes sign. By examining the critical region, additional insight on the equations of state for near-critical anisotropic plasma is obtained

  15. Reflection of oblique electron thermal modes in an inhomogeneous plasma

    Ohnuma, T.; Watanabe, T.; Sanuki, H.

    1980-04-01

    In an inhomogeneous magnetoplasma, reflection of an oblique electron thermal mode radiated from a local source is investigated experimentally and theoretically near the electron plasma frequency layer. The experimental observation of reflection in the lower plasma density region than the f sub(p)-layer is found to be in qualitative accord with the theoretical reflection, which is obtained from a kinetic theory in an inhomogeneous magnetoplasma. The reflection of the thermal mode is also compared with that of an electromagnetic mode at the f sub(p)-layer. (author)

  16. Plasma thermal energy transport: theory and experiments

    Coppi, B.

    Experiments on the transport across the magnetic field of electron thermal energy are reviewed (Alcator, Frascati Torus). In order to explain the experimental results, a transport model is described that reconfirmed the need to have an expression for the local diffusion coefficient with a negative exponent of the electron temperature

  17. Remelting of metallurgical fines using thermal plasma

    Vicente, L.C.; Neto F, J.B.F.; Bender, O.W.; Collares, M.P.

    1992-01-01

    A plasma furnace was developed for remelting of ferro alloys and silicon fines. The furnace capacity was about 4 Kg of silicon and power about 50 kW. The fine (20 to 100 mesh) was fed into the furnace directly at the high temperature zone. This system was tested for remelting silicon fines and the results in the recovery of silicon was about 95% and it took place a refine of aluminium and calcium. (author)

  18. Influence of Microstructure on Thermal Properties of Axial Suspension Plasma-Sprayed YSZ Thermal Barrier Coatings

    Ganvir, A.; Curry, N.; Markocsan, N.; Nylen, P.; Joshi, S.; Vilémová, Monika; Pala, Zdeněk

    2016-01-01

    Roč. 25, 1-2 (2016), s. 202-212 ISSN 1059-9630. [ITSC 2015: International Thermal Spray Conference and Exposition. Long Beach, California, 11.05.2015-14.05.2015] Institutional support: RVO:61389021 Keywords : axial injection * column ar microstructure * porosity * suspension plasma spraying * thermal conductivity * thermal diffusivity Subject RIV: JK - Corrosion ; Surface Treatment of Materials Impact factor: 1.488, year: 2016 http://link.springer.com/article/10.1007%2Fs11666-015-0355-7

  19. Optimal control theory applied to fusion plasma thermal stabilization

    Sager, G.; Miley, G.; Maya, I.

    1985-01-01

    Many authors have investigated stability characteristics and performance of various burn control schemes. The work presented here represents the first application of optimal control theory to the problem of fusion plasma thermal stabilization. The objectives of this initial investigation were to develop analysis methods, demonstrate tractability, and present some preliminary results of optimal control theory in burn control research

  20. Applying chemical engineering concepts to non-thermal plasma reactors

    Pedro AFFONSO, NOBREGA; Alain, GAUNAND; Vandad, ROHANI; François, CAUNEAU; Laurent, FULCHERI

    2018-06-01

    Process scale-up remains a considerable challenge for environmental applications of non-thermal plasmas. Undersanding the impact of reactor hydrodynamics in the performance of the process is a key step to overcome this challenge. In this work, we apply chemical engineering concepts to analyse the impact that different non-thermal plasma reactor configurations and regimes, such as laminar or plug flow, may have on the reactor performance. We do this in the particular context of the removal of pollutants by non-thermal plasmas, for which a simplified model is available. We generalise this model to different reactor configurations and, under certain hypotheses, we show that a reactor in the laminar regime may have a behaviour significantly different from one in the plug flow regime, often assumed in the non-thermal plasma literature. On the other hand, we show that a packed-bed reactor behaves very similarly to one in the plug flow regime. Beyond those results, the reader will find in this work a quick introduction to chemical reaction engineering concepts.

  1. Treatment of mixed wastes by thermal plasma discharges

    Diaz A, L.V.

    2007-01-01

    The present study has as purpose to apply the technology of thermal plasma in the destruction of certain type of waste generated in the ININ. As first instance, origin, classification and disposition of the radioactive waste generated in the ININ is identified. Once identified the waste, the waste to treat is determined based on: the easiness of treating him with plasma, classification and importance. Later on, a substance or compound settles down (sample model) that serves as indicative of the waste for its physical-chemical characteristics, this is made because in the Thermal Plasma Applications Laboratory is not had the license to work with radioactive material. The sample model and the material to form the vitreous matrix are characterized before and after the treatment in order to evaluating their degradation and vitrification. During the treatment by means of the thermal plasma, the appropriate conditions are determined for the degradation and vitrification of the waste. Also, it is carried out an energy balance in the system to know the capacity to fuse the material depending the transfer of existent heat between the plasma and the material to treat. Obtaining favorable results, it thought about to climb in the project and by this way to help to solve one of the environmental problems in Mexico, as they are it the mixed wastes. (Author)

  2. Recoil Induced Room Temperature Stable Frenkel Pairs in a-Hafnium Upon Thermal Neutron Capture

    Butz, Tilman; Das, Satyendra K.; Dey, Chandi C.; Ghoshal, Shamik

    2013-11-01

    Ultrapure hafnium metal (110 ppm zirconium) was neutron activated with a thermal neutron flux of 6:6 · 1012 cm-2s-1 in order to obtain 181Hf for subsequent time differential perturbed angular correlation (TDPAC) experiments using the nuclear probe 181Hf(β-) 181Ta. Apart from the expected nuclear quadrupole interaction (NQI) signal for a hexagonal close-packed (hcp) metal, three further discrete NQIs were observed with a few percent fraction each. The TDPAC spectra were recorded for up to 11 half lives with extreme statistical accuracy. The fitted parameters vary slightly within the temperature range between 248 K and 373 K. The signals corresponding to the three additional sites completely disappear after `annealing' at 453 K for one minute. Based on the symmetry of the additional NQIs and their temperature dependencies, they are tentatively attributed to Frenkel pairs produced by recoil due to the emission of a prompt 5:694 MeV -ray following thermal neutron capture and reported by the nuclear probe in three different positions. These Frenkel pairs are stable up to at least 373 K.

  3. Ion turbulence and thermal transport in laser-produced plasmas

    Barr, H.C.; Boyd, T.J.M.

    1982-01-01

    In the interaction of high-intensity lasers with target plasmas the transport of thermal energy from the region in which the radiation is absorbed, to the cold dense plasma in the interior of the target, is an issue of central importance. The role of ion turbulence as a flux limiter is addressed with particular regard to recent experiments in which target plasmas were irradiated by 1.06 μm neodymium laser light at irradiances of 10 15 W cm - 2 and greater. Saturation levels of the ion-acoustic turbulence driven by a combination of a suprathermal electron current and a heat flux are calculated on the basis of perturbed orbit theory. The levels of turbulence are found to be markedly lower than those commonly estimated from simple trapping arguments and too low to explain the thermal flux inhibition observed in the experiments used as a basis for the model. (author)

  4. Thermal plasma reduction of UF6

    Fincke, J.R.; Swank, W.D.; Haggard, D.C.

    1995-01-01

    This paper describes the experimental demonstration of a process for the direct plasma reduction of depleted uranium hexafluoride to uranium metal. The process exploits the large departures from equilibrium that can be achieved in the rapid supersonic expansion of a totally dissociated and partially ionized mixture of UF 6 , Ar, He, and H 2 . The process is based on the rapid condensation of subcooled uranium vapor and the relatively slow rate of back reaction between metallic uranium and HF to F 2 to reform stable fluorides. The high translational velocities and rapid cooling result in an overpopulation of atomic hydrogen which persists throughout the expansion process. Atomic hydrogen shifts the equilibrium composition by inhibiting the reformation of uranium-fluorine compounds. This process has the potential to reduce the cost of reducing UF 6 to uranium metal with the added benefit of being a virtually waste free process. The dry HF produced is a commodity which has industrial value

  5. Gravitational instability of thermally anisotropic plasma

    Singh, B.; Kalra, G.L.

    1986-01-01

    The equations of Chew, Goldberger, and Low (1956) modified to include the heat flux vector and self-gravitation are used to study the gravitational instability of unbounded plasma placed in a uniform static magnetic field. The linear stability analysis shows that some of the additional terms which arise as a result of higher moments are of the same order of magnitude as the terms in the original Chew, Goldberger, and Low theory. The influence of these terms on the gravitational instability has been specially examined. It is found that the gravitational instability sets in at a comparatively shorter wavelength and the growth rate is enhanced owing to the inclusion of these terms in the case where the propagation vector is along the magnetic field. The condition for instability is, however, unaltered when the direction of propagation is transverse to the direction of magnetic field. 19 references

  6. Thermal equilibrium criteria in a nitrogen plasma

    Cilliers, W.A.; Hey, J.D.; Rash, J.P.S.

    1975-01-01

    A method for obtaining the lower electron density limit for LTE in a nitrogen plasma is described, whereby the experimentally determined ratio of the collisional-radiative ionization and recombination coefficients (S/α) is compared with the corresponding LTE value (Saha ratio). It is argued that if the electron density is increased from values of about 10 16 cm -3 , S/α should tend to the Saha ratio as LTE is approached For NII and NIII spectral lines, this is found to happen at an electron density of a few times 10 16 cm -3 when the electron temperature is about 3 eV, in good agreement with the LTE criterion of Griem. (author)

  7. A dc non-thermal atmospheric-pressure plasma microjet

    Zhu, WeiDong; Lopez, Jose L.

    2012-06-01

    A direct current (dc), non-thermal, atmospheric-pressure plasma microjet is generated with helium/oxygen gas mixture as working gas. The electrical property is characterized as a function of the oxygen concentration and show distinctive regions of operation. Side-on images of the jet were taken to analyze the mode of operation as well as the jet length. A self-pulsed mode is observed before the transition of the discharge to normal glow mode. Optical emission spectroscopy is employed from both end-on and side-on along the jet to analyze the reactive species generated in the plasma. Line emissions from atomic oxygen (at 777.4 nm) and helium (at 706.5 nm) were studied with respect to the oxygen volume percentage in the working gas, flow rate and discharge current. Optical emission intensities of Cu and OH are found to depend heavily on the oxygen concentration in the working gas. Ozone concentration measured in a semi-confined zone in front of the plasma jet is found to be from tens to ˜120 ppm. The results presented here demonstrate potential pathways for the adjustment and tuning of various plasma parameters such as reactive species selectivity and quantities or even ultraviolet emission intensities manipulation in an atmospheric-pressure non-thermal plasma source. The possibilities of fine tuning these plasma species allows for enhanced applications in health and medical related areas.

  8. A dc non-thermal atmospheric-pressure plasma microjet

    Zhu Weidong; Lopez, Jose L

    2012-01-01

    A direct current (dc), non-thermal, atmospheric-pressure plasma microjet is generated with helium/oxygen gas mixture as working gas. The electrical property is characterized as a function of the oxygen concentration and show distinctive regions of operation. Side-on images of the jet were taken to analyze the mode of operation as well as the jet length. A self-pulsed mode is observed before the transition of the discharge to normal glow mode. Optical emission spectroscopy is employed from both end-on and side-on along the jet to analyze the reactive species generated in the plasma. Line emissions from atomic oxygen (at 777.4 nm) and helium (at 706.5 nm) were studied with respect to the oxygen volume percentage in the working gas, flow rate and discharge current. Optical emission intensities of Cu and OH are found to depend heavily on the oxygen concentration in the working gas. Ozone concentration measured in a semi-confined zone in front of the plasma jet is found to be from tens to ∼120 ppm. The results presented here demonstrate potential pathways for the adjustment and tuning of various plasma parameters such as reactive species selectivity and quantities or even ultraviolet emission intensities manipulation in an atmospheric-pressure non-thermal plasma source. The possibilities of fine tuning these plasma species allows for enhanced applications in health and medical related areas. (paper)

  9. Temperature of thermal plasma jets: A time resolved approach

    Sahasrabudhe, S N; Joshi, N K; Barve, D N; Ghorui, S; Tiwari, N; Das, A K, E-mail: sns@barc.gov.i [Laser and Plasma Technology Division, Bhabha Atomic Research Centre, Mumbai - 400 094 (India)

    2010-02-01

    Boltzmann Plot method is routinely used for temperature measurement of thermal plasma jets emanating from plasma torches. Here, it is implicitly assumed that the plasma jet is 'steady' in time. However, most of the experimenters do not take into account the variations due to ripple in the high current DC power supplies used to run plasma torches. If a 3-phase transductor type of power supply is used, then the ripple frequency is 150 Hz and if 3- phase SCR based power supply is used, then the ripple frequency is 300 Hz. The electrical power fed to plasma torch varies at ripple frequency. In time scale, it is about 3.3 to 6.7 ms for one cycle of ripple and it is much larger than the arc root movement times which are within 0.2 ms. Fast photography of plasma jets shows that the luminosity of plasma jet also varies exactly like the ripple in the power supply voltage and thus with the power. Intensity of line radiations varies nonlinearly with the instantaneous power fed to the torch and the simple time average of line intensities taken for calculation of temperature is not appropriate. In this paper, these variations and their effect on temperature determination are discussed and a method to get appropriate data is suggested. With a small adaptation discussed here, this method can be used to get temperature profile of plasma jet within a short time.

  10. Plasmon dispersion and dynamic exchange-correlation potential from two-pair excitations in degenerate plasmas

    Boehm, H.M.; Conti, S.; Tosi, M.P.

    1995-11-01

    Electron energy loss experiments have shown a rapid softening of the bulk plasmon dispersion across the series of the alkali metals. Motivated by these observations, we reconsider the evaluation of the dynamic, long-wavelength exchange-correlation potential f xc (ω) in the electron fluid, which is of interest for applications in time-dependent density functional theory. The value of Re[f xc (ω pl )] at the plasma frequency ω pl determines the exchange-correlation contribution to the leading plasmon dispersion coefficient in the homogeneous electron fluid. Whereas an interpolation scheme originally proposed by Gross and Kohn assumes a monotonic increase of Re[f xc (ω) - f xc (0)] across the plasma frequency, we examine the possibility of strongly non-monotonic behaviour arising from a resonance process between plasmons and two-pair excitations. This process is evaluated with the help of sum rules and selfconsistency requirements with a single-pole approximation of the dielectric function. The cases of a fermion plasma and of a boson plasma are treated in parallel and the reliability of the results for the fermion plasma at low coupling is tested by calculations within a random phase approximation for the dielectric function. In all cases it is found that the resonance process accumulates oscillator strength in the neighbourhood of 2ω pl , thus decreasing the value of Re[f xc (ω pl )] below the static value f xc (0) fixed by the compressibility sum rule. Although this lowering does not suffice to account by itself for the measured plasmon dispersion coefficient in the low-density alkali metals, our results provide useful input for combined band-structure and exchange-correlation calculations. (author). 40 refs, 9 figs, 2 tabs

  11. A stability analysis of electron-positron pair equilibria of a two-temperature plasma cloud

    Sikora, M [Colorado Univ., Boulder, CO (USA); Zbyszewska, M [Polska Akademia Nauk, Warsaw (Poland). Centrum Astronomiczne

    1986-01-01

    The stability of a two-temperature homogeneous static plasma cloud against pair density perturbations is examined. We assumed that the electrons and positrons, cooled via radiation process, are reheated via Coulomb interactions with much hotter protons. Pair equilibrium plasma states are shown to be unstable if deltan{sub e}/deltan{sub p}<0 and deltan{sub e}/deltaT{sub p}<0 on the equilibrium surface n{sub e}{sup eq}(n{sub p},T{sub p}), where n{sub e}=n{sub +}+n{sub -}, n{sub p} and T{sub p} denote electron plus positron density, proton density and proton temperature, respectively. The minimum proton temperature and maximum proton density for which unstable states can appear are: (kT{sub p}){sub min} approx few x m{sub e}c{sup 2} and (n{sub p}){sub max} approx few/Rsigma{sub T}, where R is the plasma cloud radius. We discuss our results in the context of an accreting black hole model assuming that the proton temperature is close to its virial value, kT{sub p}{sup vir} approx GMm{sub p}/R and that subsonic accretion flow is realized at R < tens Schwarzschild radii. The unstable states then correspond to the luminosity range 0.01 L{sub Edd}

  12. Response to ''Comment on 'Acoustic solitons in inhomogenous pair-ion plasmas''' [Phys. Plasmas 18, 054701 (2011)

    Shah, Asif; Mahmood, S.; Haque, Q.

    2011-01-01

    The quantity n p0 (0) is different from n p0 (x) and same is true for v p0 (0), v p0 (x). Taking these differences into account and considering the mathematical relation v p0 (x)= 1/n p0 (x), it can easily be shown that derivatives of these space dependent densities and velocities are linked through the relation ∂v p0 (x)/∂η=-1/n p0 2 (x)∂n p0 (x)/∂η. We show that constraint (1) of the comment can also be transformed to derivative transformation relation. This derivative transformation relation can be used in the derivation of the KdV like equation and our model is valid for inhomogenous pair ion plasma. We mathematically and physically prove that the objections in the comment are false and baseless.

  13. Powder processing and spheroidizing with thermal inductively coupled plasma

    Nutsch, G.; Linke, P.; Zakharian, S.; Dzur, B.; Weiss, K.-H.

    2001-01-01

    Processing of advanced powder materials for the spraying industry is one of the most promising applications of the thermal RF inductively coupled plasma. By selecting the feedstock carefully and adjusting the RF plasma parameters, unique materials with high quality can be achieved. Powders injected in the hot plasma core emerge with modified shapes, morphology, crystal structure and chemical composition. Ceramic oxide powders such as Al 2 O 3 , ZrO 2 , SiO 2 are spheroidized with a high spheroidization rate. By using the RF induction plasma spheroidizing process tungsten melt carbide powders are obtained with a high spheroidization rate at high feeding rates by densification of agglomerated powders consisting of di-tungsten carbide and monocarbide with a definite composition. This kind of ball-like powders is particularly suited for wear resistant applications. (author)

  14. Inductive thermal plasma generation applied for the materials coating

    Pacheco, J.; Pena, R.; Cota, G.; Segovia, A.; Cruz, A.

    1996-01-01

    The coatings by thermal plasma are carried out introducing particles into a plasma system where they are accelerated and melted (total or partially) before striking the substrate to which they adhere and are suddenly cooled down. The nature of consolidation and solidification of the particles allows to have control upon the microstructure of the deposit. This technique is able to deposit any kind of material that is suitable to be merged (metal, alloy, ceramic, glass) upon any type of substrate (metal, graphite, ceramic, wood) with an adjustable thickness ranging from a few microns up to several millimeters. The applications are particularly focused to the coating of materials in order to improve their properties of resistance to corrosion, thermal and mechanical efforts as well as to preserve the properties of the so formed compound. In this work the electromagnetic induction phenomenon in an ionized medium by means of electric conductivity, is described. Emphasis is made on the devices and control systems employed in order to generate the thermal plasma and in carrying out the coatings of surfaces by the projection of particles based on plasma

  15. Thermal cycling characteristics of plasma synthesized mullite films

    Monteiro, O.R.; Hou, P.Y.; Brown, I.G. [Lawrence Berkeley National Lab., CA (United States)

    1997-12-01

    The authors have developed a plasma-based technique for the synthesis of mullite and mullite-like films on silicon carbide substrate material. The method, which they refer to as MePIIID (for Metal Plasma Immersion Ion Implantation and Deposition), uses two vacuum arc plasma sources and simultaneous pulse biasing of the substrate in a low pressure oxygen atmosphere. The Al:Si ratio can be controlled via the separate plasma guns, and the film adhesion, structure and morphology can be controlled via the ion energy which in turn is controlled by the pulse bias voltage. The films are amorphous as-deposited, and crystalline mullite is formed by subsequent annealing at 1000 C for 2 hours in air. Adhesion between the aluminum-silicon oxide film and the substrate increases after this first annealing. They have tested the behavior of films when subjected to repetitive thermal cycling between room temperature and 1100 C, and found that the films retain their adhesion and quality. Here they review the plasma synthesis technique and the characteristics of the mullite films prepared in this way, and summarize the status of the thermal cycling experiments.

  16. Thermal consequences of plasma disruptions in TFTR and ETF

    Budny, R.; Ludescher, C.

    1981-01-01

    We studied thermal responses of first walls for TFTR and ETF during plasma disruptions. To model the flux, we assumed the entire kinetic energy is deposited by axisymmetric horizontal displacement of the plasma. The deposition time is a free parameter. In TFTR, the minimum deposition time which does not cause the toroidal limiter to melt is 7 or 14 ms depending on whether or not the limiter is actively cooled. In ETF, the minimum time which does not cause surface melting of the cooling tubes is 80 ms. (author)

  17. Non-thermal plasma mills bacteria: scanning electron microscopy observations

    Lunov, Oleg; Churpita, Olexandr; Zablotskyy, Vitaliy A.; Deyneka, I.G.; Meshkovskii, I.K.; Jäger, Aleš; Syková, Eva; Kubinová, Šárka; Dejneka, Alexandr

    2015-01-01

    Roč. 106, č. 5 (2015), "053703-1"-"053703-5" ISSN 0003-6951 R&D Projects: GA MŠk(CZ) LM2011029; GA MŠk(CZ) LM2011026; GA MŠk LO1309 Grant - others:AV ČR(CZ) M100101219; SAFMAT(XE) CZ.2.16/3.1.00/22132 Institutional support: RVO:68378271 ; RVO:68378041 Keywords : non-thermal plasma * plasma medicine * bacteria * cells Subject RIV: BO - Biophysics Impact factor: 3.142, year: 2015

  18. Screening of metal hydride pairs for closed thermal energy storage systems

    Aswin, N.; Dutta, Pradip; Murthy, S. Srinivasa

    2016-01-01

    Thermal energy storage systems based on metal/hydrides usually are closed systems composed of two beds of metal/alloy – one meant for energy storage and the other for hydrogen storage. It can be shown that a feasible operating cycle for such a system using a pair of metals/alloys operating between specified temperature values can be ensured if the equilibrium hydrogen intake characteristics satisfy certain criteria. In addition, application of first law of thermodynamics to an idealized operating cycle can provide the upper bounds of selected performance indices, namely volumetric energy storage density, energy storage efficiency and peak discharge temperature. This is demonstrated for a representative system composed of LaNi 4.7 Al 0.3 –LaNi 5 operating between 353 K and 303 K which gave values of about 56 kW h m −3 for volumetric storage density, about 85% for energy storage efficiency and 343 K for peak discharge temperature. A system level heat and mass transfer study considering the reaction kinetics, hydrogen flow between the beds and heat exchanger models is presented which gave second level estimates of about 40 kW h m −3 for volumetric energy storage density, 73% for energy storage efficiency and 334 K for peak temperature for the representative system. The results from such studies lead to identifying metal/alloy pairs which can be shortlisted for detailed studies.

  19. Plasma thermal conversion of bio-oil for hydrogen production

    Guenadou, David; Lorcet, Helene; Peybernes, Jean; Catoire, Laurent; Osmont, Antoine; Gokalp, Iskender

    2012-01-01

    Numerous processes exist or are proposed for the energetic conversion of biomass. The use of thermal plasma is proposed in the frame of the GALACSY project for the conversion of bio-oil to hydrogen and carbon monoxide. For this purpose, an experimental apparatus has been built. The feasibility of this conversion at very high temperature, as encountered in thermal plasma, is examined both experimentally and numerically. This zero dimensional study tends to show that a high temperature (around 2500 K or above) is needed to ensure a high yield of hydrogen (about 50 mol%) and about 95 mol% of CO+H 2 . Predicted CO+H 2 yield and CO/H 2 ratio are consistent with measurements. It is also expected that the formation of particles and tars is hampered. Thermodynamic data of selected bio-oil components are provided in the CHEMKINNASA format. (authors)

  20. Non thermal plasma surface cleaner and method of use

    Neophytou, Marios

    2017-09-14

    Described herein are plasma generation devices and methods of use of the devices. The devices can be used for the cleaning of various surfaces and/or for inhibiting or preventing the accumulation of particulates, such as dust, or moisture on various surfaces. The devices can be used to remove dust and other particulate contaminants from solar panels and windows, or to avoid or minimize condensation on various surfaces. In an embodiment a plasma generation device is provided. The plasma generation device can comprise: a pair of electrodes (1,2) positioned in association with a surface of a dielectric substrate (3). The pair of electrodes (1,2) can comprise a first electrode (1) and a second electrode (2). The first electrode and second electrode can be of different sizes, one of the electrodes being smaller than the other of the electrodes. The first electrode and second electrode can be separated by a distance and electrically connected to a voltage source (4,5).

  1. Non thermal plasma surface cleaner and method of use

    Neophytou, Marios; Lacoste, Deanna A.; Kirkus, Mindaugas

    2017-01-01

    Described herein are plasma generation devices and methods of use of the devices. The devices can be used for the cleaning of various surfaces and/or for inhibiting or preventing the accumulation of particulates, such as dust, or moisture on various surfaces. The devices can be used to remove dust and other particulate contaminants from solar panels and windows, or to avoid or minimize condensation on various surfaces. In an embodiment a plasma generation device is provided. The plasma generation device can comprise: a pair of electrodes (1,2) positioned in association with a surface of a dielectric substrate (3). The pair of electrodes (1,2) can comprise a first electrode (1) and a second electrode (2). The first electrode and second electrode can be of different sizes, one of the electrodes being smaller than the other of the electrodes. The first electrode and second electrode can be separated by a distance and electrically connected to a voltage source (4,5).

  2. Recent progress in the modelling of thermal plasma systems

    Xi Chen

    2002-01-01

    Plasma flow and heat transfer in thermal plasma systems are often of three-dimensional (3-D) features and cannot be well studied by use of a two-dimensional modelling approach. 3-D modelling studies are recently performed in our group. It is found that appreciable 3-D effects exist within non-transferred DC arc plasma torches even for the case with axisymmetrical external conditions. The key for the successful 3-D modelling of the non-transferred arc plasma torch is that the anode-nozzle wall is included in the computational domain. The predicted results are favorably compared with experimental observation. 3-D modelling of the plasma jets with lateral injection of particulate matter and its carrier gas also reveals distinct 3-D effects with the injection velocity and the distance between the carrier-gas injection-tube tip and the jet edge as critical parameters. The 3-D effects appreciably influence the trajectories and heating histories of particles injected into the plasma jet. (author)

  3. Oblique non-neutral solitary Alfven modes in weakly nonlinear pair plasmas

    Verheest, Frank; Lakhina, G S

    2005-01-01

    The equal charge-to-mass ratio for both species in pair plasmas induces a decoupling of the linear eigenmodes between waves that are charge neutral or non-neutral, also at oblique propagation with respect to a static magnetic field. While the charge-neutral linear modes have been studied in greater detail, including their weakly and strongly nonlinear counterparts, the non-neutral mode has received less attention. Here the nonlinear evolution of a solitary non-neutral mode at oblique propagation is investigated in an electron-positron plasma. Employing the framework of reductive perturbation analysis, a modified Korteweg-de Vries equation (with cubic nonlinearity) for the lowest-order wave magnetic field is obtained. In the linear approximation, the non-neutral mode has its magnetic component orthogonal to the plane spanned by the directions of wave propagation and of the static magnetic field. The linear polarization is not maintained at higher orders. The results may be relevant to the microstructure in pulsar radiation or to the subpulses

  4. Pre-treating water with non-thermal plasma

    Cho, Young I.; Fridman, Alexander; Rabinovich, Alexander; Cho, Daniel J.

    2017-07-04

    The present invention consists of a method of pre-treatment of adulterated water for distillation, including adulterated water produced during hydraulic fracturing ("fracking") of shale rock during natural gas drilling. In particular, the invention is directed to a method of treating adulterated water, said adulterated water having an initial level of bicarbonate ion in a range of about 250 ppm to about 5000 ppm and an initial level of calcium ion in a range of about 500 ppm to about 50,000 ppm, said method comprising contacting the adulterated water with a non-thermal arc discharge plasma to produce plasma treated water having a level of bicarbonate ion of less than about 100 ppm. Optionally, the plasma treated water may be further distilled.

  5. Application of non-thermal plasmas to pollution control

    Penetrante, B.M.; Vogtlin, G.E.; Bardsley, J.N.; Vitello, P.A.; Wallman, P.H.

    1993-06-01

    Non-thermal plasma techniques can be used to destroy many types of hazardous molecules. They are particularly efficient when the toxic materials are present in very small concentrations. This paper discusses three particular applications of non-thermal plasmas: (1) decomposition of hydrogen sulfide (H 2 S), (2) removal of trichloroethylene (TCE), and (3) removal of nitrogen oxides (NO x ). Emphasis is placed on the energy cost for implementing the decomposition or removal of these pollutants. Some of the factors affecting the energy cost are discussed. The authors discuss in detail their work at LLNL on pulsed plasma processing for the treatment of NO x in diesel engine exhaust. The results suggest that their plasma reactor can remove up to 70% of NO with relatively high initial concentrations (up to 500 ppM) at a power consumption cost of 2.5% for an engine with an output of 14 kW and an exhaust gas flow rate of 1,200 liters per minute

  6. Application of non-thermal plasmas to pollution control

    Penetrante, B.M.; Vogtlin, G.E.; Bardsley, J.N.; Vitello, P.A.; Wallman, P.H.

    1993-01-01

    Non-thermal plasma techniques can be used to destroy many types of hazardous molecules. They are particularly efficient when the toxic materials are present in very small concentrations. This paper discusses three particular applications of non-thermal plasmas: (1) decomposition of hydrogen sulfide (H 2 S), (2) removal of trichloroethylene (TCE), and (3) removal of nitric oxides (NO x ) Emphasis is placed on the energy cost for implementing the decomposition or removal of these pollutants. Some of the factors affecting the energy cost are discussed. We discuss in detail our work at LLNL on pulsed plasma processing for the treatment of NO x in diesel engine exhaust. Our results suggest that our plasma reactor can remove up to 70% of NO x with relatively high initial concentrations (up to 500 ppM) at a power consumption cost of 2.5% for an engine with an output of 14 kill and an exhaust gas flow rate of 1200 liters per minute

  7. Nonlinear structure formation in ion-temperature-gradient driven drift waves in pair-ion plasma with nonthermal electron distribution

    Razzaq, Javaria; Haque, Q.; Khan, Majid; Bhatti, Adnan Mehmood; Kamran, M.; Mirza, Arshad M.

    2018-02-01

    Nonlinear structure formation in ion-temperature-gradient (ITG) driven waves is investigated in pair-ion plasma comprising ions and nonthermal electrons (kappa, Cairns). By using the transport equations of the Braginskii model, a new set of nonlinear equations are derived. A linear dispersion relation is obtained and discussed analytically as well as numerically. It is shown that the nonthermal population of electrons affects both the linear and nonlinear characteristics of the ITG mode in pair-ion plasma. This work will be useful in tokamaks and stellarators where non-Maxwellian population of electrons may exist due to resonant frequency heating, electron cyclotron heating, runaway electrons, etc.

  8. Porous materials produced from incineration ash using thermal plasma technology.

    Yang, Sheng-Fu; Chiu, Wen-Tung; Wang, To-Mai; Chen, Ching-Ting; Tzeng, Chin-Ching

    2014-06-01

    This study presents a novel thermal plasma melting technique for neutralizing and recycling municipal solid waste incinerator (MSWI) ash residues. MSWI ash residues were converted into water-quenched vitrified slag using plasma vitrification, which is environmentally benign. Slag is adopted as a raw material in producing porous materials for architectural and decorative applications, eliminating the problem of its disposal. Porous materials are produced using water-quenched vitrified slag with Portland cement and foaming agent. The true density, bulk density, porosity and water absorption ratio of the foamed specimens are studied here by varying the size of the slag particles, the water-to-solid ratio, and the ratio of the weights of the core materials, including the water-quenched vitrified slag and cement. The thermal conductivity and flexural strength of porous panels are also determined. The experimental results show the bulk density and the porosity of the porous materials are 0.9-1.2 g cm(-3) and 50-60%, respectively, and the pore structure has a closed form. The thermal conductivity of the porous material is 0.1946 W m(-1) K(-1). Therefore, the slag composite materials are lightweight and thermal insulators having considerable potential for building applications. Copyright © 2013 Elsevier Ltd. All rights reserved.

  9. Operational features and air plasma characteristics of a thermal plasma torch with hollow electrodes

    Hur, Min; Kim, Keun Su; Hong, Sang Hee

    2003-01-01

    The operational features and thermal plasma characteristics of a plasma torch with hollow electrodes are investigated based on their dependence on input current, gas flow rate and electrode diameter when air is used as a plasma gas. A plasma torch with a hollow cathode and anode has been designed and fabricated, and the arc voltages and thermal efficiencies are measured from its discharge. The newly modified similarity criteria are derived from the measured data related to torch performances. From the fact that these criteria successfully describe both the arc voltage and thermal efficiency behaviour of the torch, depending on its operating and geometrical parameters, it is proved that they can be usefully applied to the design and operation of high power torches. For the numerical modelling of the interior region of the torch, a cold flow analysis is employed along with a simplified balance equation of the Lorentz and gas dynamic drag forces in order to determine a cathode spot position on the cathode surface. The validity of this method is confirmed by comparison of the calculated and measured net powers. As a practically useful result of this analysis, carried out through this numerical and experimental work, it is suggested that low input current, high gas flow rate and relatively large electrode diameter are more favourable as appropriate operating conditions of the torch for the efficient treatment of hazardous organic wastes

  10. Destruction studies of hazardous wastes by thermal plasma

    Cota S, G.

    1998-01-01

    Plasma technology appears promising because its high degree of controllability, capability to process waste without the adverse effects of combustion, and a very wide temperature range of operation. The goal of this work was to develop a process for a high throughput system to turn hazardous waste into inert stable products, which can be safely stored and to greatly reduce air pollution relative to incineration. The experiments have shown that the thermal plasma reactor can provide a high degree of decomposition of CCl 4 , C 6 H 6 , C 2 Cl 4 and commercial oil at low gas input speeds, with modest power requirements. Decomposition of 99.9999 % has been obtained in our laboratory and all the organic components are decomposed in base molecules (C, CO, CO 2 , H 2 , HCl). The analysis of exhaust gases was made by using a mass filter quadrupole. The equipment consist of a cylindrical reactor hermetically sealed, double-walled and water-cooled container made of special steel, this container in halt the crucible which serves to receive the waste materials. The whole system is designed for a maximal internal temperature of 2000 Centigrade. The gaseous result components of the material are transferred to a scrubber unit through an exit arranged on the top of reactor. The thermal efficiency evaluation of the plasma torch was also realized, obtaining a reasonable agreement between measurements and predictions in temperature profiles. (Author)

  11. Waste cell phone recycling by thermal plasma techniques

    Inaba, T.; Kunimoto, N.; Abe, S. [Chuo Univ., Bunkyo-Ku, Tokyo (Japan). Dept. of Electrical, Electronics, and Communication Engineering; Li, O.L.; Chang, J.S.; Ruj, B. [McMaster Univ., Hamilton, ON (Canada). Faculty of Engineering

    2010-07-01

    Due to the cost-effective nature of wireless networks, the number of cell phones used around the world has increased significantly. However, a major problem of this technology is the generation of a great deal of complex electronics wastes, such as cell phones. The typical average life of a cell phone is around 2 years. Therefore, inexpensive recycling techniques must be developed for valuable resources such as real metals and plastics used in cell phones. Thermal plasma has been used for many different waste treatments since it has the capability to detoxify waste by-products. This paper presented a preliminary investigation for cell phone recycling by a thermal plasma technology. Recyclable resource material was identified by neutron activation analyses. Then, the cell phone waste was first crashed and treated by Ar twin torch plasmas to remove the majority of organic materials. The paper described the experimental apparatus and results. It was concluded that styrene (C{sub 8}H{sub 8}) and benzene (C{sub 6}H{sub 6}O) may be two major by-products in on-line by-products gas. The molecule becomes a much heavier by-product gas after cooling down. 6 refs., 6 figs.

  12. Thermal Fatigue Behavior of Air-Plasma Sprayed Thermal Barrier Coating with Bond Coat Species in Cyclic Thermal Exposure

    Ungyu Paik

    2013-08-01

    Full Text Available The effects of the bond coat species on the delamination or fracture behavior in thermal barrier coatings (TBCs was investigated using the yclic thermal fatigue and thermal-shock tests. The interface microstructures of each TBC showed a good condition without cracking or delamination after flame thermal fatigue (FTF for 1429 cycles. The TBC with the bond coat prepared by the air-plasma spray (APS method showed a good condition at the interface between the top and bond coats after cyclic furnace thermal fatigue (CFTF for 1429 cycles, whereas the TBCs with the bond coats prepared by the high-velocity oxygen fuel (HVOF and low-pressure plasma spray (LPPS methods showed a partial cracking (and/or delamination and a delamination after 780 cycles, respectively. The TBCs with the bond coats prepared by the APS, HVOF and LPPS methods were fully delaminated (>50% after 159, 36, and 46 cycles, respectively, during the thermal-shock tests. The TGO thickness in the TBCs was strongly dependent on the both exposure time and temperature difference tested. The hardness values were found to be increased only after the CFTF, and the TBC with the bond coat prepared by the APS showed the highest adhesive strength before and after the FTF.

  13. Thermal Conductivity Analysis and Lifetime Testing of Suspension Plasma-Sprayed Thermal Barrier Coatings

    Nicholas Curry

    2014-08-01

    Full Text Available Suspension plasma spraying (SPS has become an interesting method for the production of thermal barrier coatings for gas turbine components. The development of the SPS process has led to structures with segmented vertical cracks or column-like structures that can imitate strain-tolerant air plasma spraying (APS or electron beam physical vapor deposition (EB-PVD coatings. Additionally, SPS coatings can have lower thermal conductivity than EB-PVD coatings, while also being easier to produce. The combination of similar or improved properties with a potential for lower production costs makes SPS of great interest to the gas turbine industry. This study compares a number of SPS thermal barrier coatings (TBCs with vertical cracks or column-like structures with the reference of segmented APS coatings. The primary focus has been on lifetime testing of these new coating systems. Samples were tested in thermo-cyclic fatigue at temperatures of 1100 °C for 1 h cycles. Additional testing was performed to assess thermal shock performance and erosion resistance. Thermal conductivity was also assessed for samples in their as-sprayed state, and the microstructures were investigated using SEM.

  14. Numerical investigation of kinetic turbulence in relativistic pair plasmas - I. Turbulence statistics

    Zhdankin, Vladimir; Uzdensky, Dmitri A.; Werner, Gregory R.; Begelman, Mitchell C.

    2018-02-01

    We describe results from particle-in-cell simulations of driven turbulence in collisionless, magnetized, relativistic pair plasma. This physical regime provides a simple setting for investigating the basic properties of kinetic turbulence and is relevant for high-energy astrophysical systems such as pulsar wind nebulae and astrophysical jets. In this paper, we investigate the statistics of turbulent fluctuations in simulations on lattices of up to 10243 cells and containing up to 2 × 1011 particles. Due to the absence of a cooling mechanism in our simulations, turbulent energy dissipation reduces the magnetization parameter to order unity within a few dynamical times, causing turbulent motions to become sub-relativistic. In the developed stage, our results agree with predictions from magnetohydrodynamic turbulence phenomenology at inertial-range scales, including a power-law magnetic energy spectrum with index near -5/3, scale-dependent anisotropy of fluctuations described by critical balance, lognormal distributions for particle density and internal energy density (related by a 4/3 adiabatic index, as predicted for an ultra-relativistic ideal gas), and the presence of intermittency. We also present possible signatures of a kinetic cascade by measuring power-law spectra for the magnetic, electric and density fluctuations at sub-Larmor scales.

  15. Generation of electromagnetic waves and Alfven waves during coalescence of magnetic islands in pair plasmas

    Sakai, J.I.; Haruki, T.; Kazimura, Y.

    2000-01-01

    It is shown by using a 2-D fully relativistic electromagnetic particle-in-cell (PIC) code that the tearing instability in a current sheet of pair plasmas is caused by Landau resonances of both electrons and positrons. Strong magnetic flux can be generated during coalescence of magnetic islands in the nonlinear phase of the tearing instability. The magnetic flux produced in an O-type magnetic island is caused from the counter-streaming instability found by Kazimura et al. (1998). It is also shown that charge separation with a quadrupole-like structure is generated from the localized strong magnetic flux. During the decay of the quadrupole-like charge structure as well as the magnetic flux, there appear wave emission with high-frequency electromagnetic waves and Alfven waves as well as Langmuir waves. We also show by using a 3-D PIC code that current filaments associated with the O-type magnetic islands become unstable against the kink instability during the coalescence of current filaments. (orig.)

  16. Paracetamol degradation in aqueous solution by non-thermal plasma

    Baloul, Yasmine; Aubry, Olivier; Rabat, Hervé; Colas, Cyril; Maunit, Benoît; Hong, Dunpin

    2017-08-01

    This study deals with paracetamol degradation in water using a non-thermal plasma (NTP) created by a dielectric barrier discharge (DBD). The effects of the NTP operating conditions on the degradation were studied, showing that the treatment efficiency of the process was highly dependent on the electrical parameters and working gas composition in the reactor containing the aqueous solution. A conversion rate higher than 99% was reached with an energy yield of 12 g/kWh. High resolution mass spectrometry (HRMS) measurements showed that the main species produced in water during the process were nitrogen compounds, carboxylic acids and aromatic compounds. Contribution to the topical issue "The 15th International Symposium on High Pressure Low Temperature Plasma Chemistry (HAKONE XV)", edited by Nicolas Gherardi and Tomáš Hoder

  17. HNS steelmaking process using thermal plasma in a ceramic crucible

    Siwka, J.; Svyazhin, A.G.; Jowsa, J.; Derda, W.

    1999-01-01

    The problems related to HNS (high nitrogen steels) steelmaking technology in a laboratory plasma furnace (100 kW DC, 25 kg liquid metal) are discussed in the paper. Results of investigations on mass transfer in the bath, modelling of the temperature fields by the FEM method, the dynamics of nitriding and refining of the liquid metal are presented. The results show many advantageous features of this technology and identify the necessary modifications. Realization of the one-stage production process of HNS is possible using thermal plasma. This means that any kind of metallic scrap can be used with simultaneous nitriding of liquid metal by nitrogen gas phase and its refining. A technological scheme of the discussed process is presented. (orig.)

  18. Dispersion in thermal plasma including arbitrary degeneracy and quantum recoil

    Mushtaq, A.; Melrose, D.B.

    2012-01-01

    The longitudinal response function for a thermal electron gas was calculated including two quantum effects exactly, degeneracy and the quantum recoil. The Fermi-Dirac distribution was expanded in powers of a parameter that is small in the non-degenerate limit and the response function was evaluated in terms of the conventional plasma dispersion function to arbitrary order in this parameter. The infinite sum was performed in terms of poly logarithms in the long-wavelength and quasi-static limits, giving results that apply for arbitrary degeneracy. The results were applied to the dispersion relations for Langmuir waves and to screening, reproducing known results in the non-degenerate and completely degenerate limits], and generalizing them to arbitrary degeneracy. The occupation number for the completely degenerate limit is shown. The importance of the results regarding to semiconductor plasmas were highlighted. (orig./A.B.)

  19. Cancer therapy using non-thermal atmospheric pressure plasma with ultra-high electron density

    Tanaka, Hiromasa; Mizuno, Masaaki; Toyokuni, Shinya; Maruyama, Shoichi; Kodera, Yasuhiro; Terasaki, Hiroko; Adachi, Tetsuo; Kato, Masashi; Kikkawa, Fumitaka; Hori, Masaru

    2015-01-01

    Cancer therapy using non-thermal atmospheric pressure plasma is a big challenge in plasma medicine. Reactive species generated from plasma are key factors for treating cancer cells, and thus, non-thermal atmospheric pressure plasma with high electron density has been developed and applied for cancer treatment. Various cancer cell lines have been treated with plasma, and non-thermal atmospheric plasma clearly has anti-tumor effects. Recent innovative studies suggest that plasma can both directly and indirectly affect cells and tissues, and this observation has widened the range of applications. Thus, cancer therapy using non-thermal atmospheric pressure plasma is promising. Animal experiments and understanding the mode of action are essential for clinical application in the future. A new academic field that combines plasma science, the biology of free radicals, and systems biology will be established

  20. Cancer therapy using non-thermal atmospheric pressure plasma with ultra-high electron density

    Tanaka, Hiromasa [Institute of Innovation for Future Society, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Center for Advanced Medicine and Clinical Research, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Mizuno, Masaaki [Center for Advanced Medicine and Clinical Research, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Toyokuni, Shinya [Department of Pathology and Biological Responses, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Maruyama, Shoichi [Department of Nephrology, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Kodera, Yasuhiro [Department of Gastroenterological Surgery (Surgery II), Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Terasaki, Hiroko [Department of Ophthalmology, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Adachi, Tetsuo [Laboratory of Clinical Pharmaceutics, Gifu Pharmaceutical University, 501-1196 Gifu (Japan); Kato, Masashi [Department of Occupational and Environmental Health, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Kikkawa, Fumitaka [Department of Obstetrics and Gynecology, Nagoya University Graduate School of Medicine, Tsurumai-cho 65, Showa-ku, Nagoya 466-8550 (Japan); Hori, Masaru [Institute of Innovation for Future Society, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan)

    2015-12-15

    Cancer therapy using non-thermal atmospheric pressure plasma is a big challenge in plasma medicine. Reactive species generated from plasma are key factors for treating cancer cells, and thus, non-thermal atmospheric pressure plasma with high electron density has been developed and applied for cancer treatment. Various cancer cell lines have been treated with plasma, and non-thermal atmospheric plasma clearly has anti-tumor effects. Recent innovative studies suggest that plasma can both directly and indirectly affect cells and tissues, and this observation has widened the range of applications. Thus, cancer therapy using non-thermal atmospheric pressure plasma is promising. Animal experiments and understanding the mode of action are essential for clinical application in the future. A new academic field that combines plasma science, the biology of free radicals, and systems biology will be established.

  1. Development of twin cannons of thermal plasma; Desarrollo de canones gemelos de plasma termico.

    Pena E, R [Instituto Nacional de Investigaciones Nucleares, Mexico D.F. (Mexico)

    1997-12-31

    Today several service and transformation industries that generate hazardous wastes must implement programs in order to fulfill with requirements established by the present standardization. This problem is solved here for proposing the design and construction of a thermal plasma transferred torch with double cannon which is generated by an electric arc with a capacity of 50 k W, a regulable gas flow from 0-50 lt./min and thermal yield higher than 85 %. This equipment would be capable for degradating industrial and hospital wastes. (Author).

  2. Thermal Plasma Decomposition Of Nickel And Cobalt Compounds

    Woch M.

    2015-06-01

    Full Text Available The paper presents the study on manufacturing of nickel and cobalt powders by thermal plasma decomposition of the carbonates of these metals. It was shown the dependence of process parameters and grain size of initial powder on the composition of final product which was ether metal powder, collected in the container as well as the nanopowder with crystallite size of 70 - 90 nm, collected on the inner wall of the reaction chamber. The occurrence of metal oxides in the final products was confirmed and discussed.

  3. Thermal fatigue behavior of thermal barrier coatings by air plasma spray

    Lee, Han Sang; Kim, Eui Hyun [Korea Electric Power Research Institute, Daejeon (Korea, Republic of); Lee, Jung Hyuk [Korea Plant Service and Engineering Co. Ltd., Incheon (Korea, Republic of)

    2008-06-15

    Effects of top coat morphology and thickness on thermal fatigue behavior of Thermal Barrier Coatings (TBC) were investigated in this study. Thermal fatigue tests were conducted on three coating specimens with different top coat morphology and thickness, and then the test data were compared via microstructures, cycles to failure, and fracture surfaces. In the air plasma spray specimens (APS1, APS2), top coat were 200 and 300 {mu}m respectively. The thickness of top coat was about 700 {mu}m in the Perpendicular Cracked Specimen (PCS). Under thermal fatigue condition at 1,100 .deg. C, the cycles to top coat failure of APS1, APS2, and PCS were 350, 560 and 480 cycles, respectively. The cracks were initiated at the interface of top coat and Thermally Grown Oxide (TGO) and propagated into TGO or top coat as the number of thermal fatigue cycles increased. For the PCS specimen, additive cracks were initiated and propagated at the starting points of perpendicular cracks in the top coat. Also, the thickness of TGO and the decrease of aluminium concentration in bond coat do not affect the cycles to failure.

  4. Magnetic field approaches in dc thermal plasma modelling

    Freton, P; Gonzalez, J J; Masquere, M; Reichert, Frank

    2011-01-01

    The self-induced magnetic field has an important role in thermal plasma configurations generated by electric arcs as it generates velocity through Lorentz forces. In the models a good representation of the magnetic field is thus necessary. Several approaches exist to calculate the self-induced magnetic field such as the Maxwell-Ampere formulation, the vector potential approach combined with different kinds of boundary conditions or the Biot and Savart (B and S) formulation. The calculation of the self-induced magnetic field is alone a difficult problem and only few papers of the thermal plasma community speak on this subject. In this study different approaches with different boundary conditions are applied on two geometries to compare the methods and their limitations. The calculation time is also one of the criteria for the choice of the method and a compromise must be found between method precision and computation time. The study shows the importance of the current carrying path representation in the electrode on the deduced magnetic field. The best compromise consists of using the B and S formulation on the walls and/or edges of the calculation domain to determine the boundary conditions and to solve the vector potential in a 2D system. This approach provides results identical to those obtained using the B and S formulation over the entire domain but with a considerable decrease in calculation time.

  5. On reliability of 3D reconstructions of thermal plasma jet radiation by inverse Radon transform

    Sekerešová, Zuzana; Hlína, Jan

    2011-01-01

    Roč. 56, č. 2 (2011), s. 171-183 ISSN 0001-7043 Institutional research plan: CEZ:AV0Z20570509 Keywords : thermal plasma jet * tomography * image reconstruction Subject RIV: BL - Plasma and Gas Discharge Physics

  6. Role of thermo-physical properties on design and development of thermal plasma devices

    Ghorui, S.

    2014-01-01

    Thermal plasma devices find wide application in variety of technological areas like cutting, welding, spray coating, waste management, material processing, chemical reduction, nano-synthesis, novel material synthesis etc. Highly non-linear behavior of the plasma properties coupled with inherent instabilities, extremely high temperature, high gradients in thermal, and flow field, presence of thermal and chemical non-equilibrium make design and development of the plasma generating devices a challenging task as power levels of the devices increase

  7. Thermal energy and bootstrap current in fusion reactor plasmas

    Becker, G.

    1993-01-01

    For DT fusion reactors with prescribed alpha particle heating power P α , plasma volume V and burn temperature i > ∼ 10 keV specific relations for the thermal energy content, bootstrap current, central plasma pressure and other quantities are derived. It is shown that imposing P α and V makes these relations independent of the magnitudes of the density and temperature, i.e. they only depend on P α , V and shape factors or profile parameters. For model density and temperature profiles analytic expressions for these shape factors and for the factor C bs in the bootstrap current formula I bs ∼ C bs (a/R) 1/2 β p I p are given. In the design of next-step devices and fusion reactors, the fusion power is a fixed quantity. Prescription of the alpha particle heating power and plasma volume results in specific relations which can be helpful for interpreting computer simulations and for the design of fusion reactors. (author) 5 refs

  8. Thermal nucleation of kink-antikink pairs in a deformable chain: Influence of the non-Gaussian correction

    Woulache, R.L.; Kofane, T.C.; Yemele, D.

    2005-08-01

    Thermal nucleation of kink-antikink pairs in a nonlinear Klein- Gordon model with Remoissenet-Peyrard substrate potential coupled to an applied field is analyzed in the limits of moderate temperature and strong damping. We derive analytically the non- Gaussian correction to the nucleation rate formula of kink- antikink pairs previously calculated by Yemele and Kofane and show that the correction factor depends on the intensity of the applied field, the temperature of the system and the shape of the substrate potential. (author)

  9. Three-dimensional relativistic pair plasma reconnection with radiative feedback in the Crab Nebula

    Cerutti, B. [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); Werner, G. R.; Uzdensky, D. A. [Center for Integrated Plasma Studies, Physics Department, University of Colorado, UCB 390, Boulder, CO 80309-0390 (United States); Begelman, M. C., E-mail: bcerutti@astro.princeton.edu, E-mail: greg.werner@colorado.edu, E-mail: uzdensky@colorado.edu, E-mail: mitch@jila.colorado.edu [JILA, University of Colorado and National Institute of Standards and Technology, UCB 440, Boulder, CO 80309-0440 (United States)

    2014-02-20

    The discovery of rapid synchrotron gamma-ray flares above 100 MeV from the Crab Nebula has attracted new interest in alternative particle acceleration mechanisms in pulsar wind nebulae. Diffuse shock-acceleration fails to explain the flares because particle acceleration and emission occur during a single or even sub-Larmor timescale. In this regime, the synchrotron energy losses induce a drag force on the particle motion that balances the electric acceleration and prevents the emission of synchrotron radiation above 160 MeV. Previous analytical studies and two-dimensional (2D) particle-in-cell (PIC) simulations indicate that relativistic reconnection is a viable mechanism to circumvent the above difficulties. The reconnection electric field localized at X-points linearly accelerates particles with little radiative energy losses. In this paper, we check whether this mechanism survives in three dimension (3D), using a set of large PIC simulations with radiation reaction force and with a guide field. In agreement with earlier works, we find that the relativistic drift kink instability deforms and then disrupts the layer, resulting in significant plasma heating but few non-thermal particles. A moderate guide field stabilizes the layer and enables particle acceleration. We report that 3D magnetic reconnection can accelerate particles above the standard radiation reaction limit, although the effect is less pronounced than in 2D with no guide field. We confirm that the highest-energy particles form compact bunches within magnetic flux ropes, and a beam tightly confined within the reconnection layer, which could result in the observed Crab flares when, by chance, the beam crosses our line of sight.

  10. State of the art in medical applications using non-thermal atmospheric pressure plasma

    Tanaka, Hiromasa; Ishikawa, Kenji; Mizuno, Masaaki; Toyokuni, Shinya; Kajiyama, Hiroaki; Kikkawa, Fumitaka; Metelmann, Hans-Robert; Hori, Masaru

    2017-12-01

    Plasma medical science is a novel interdisciplinary field that combines studies on plasma science and medical science, with the anticipation that understanding the scientific principles governing plasma medical science will lead to innovations in the field. Non-thermal atmospheric pressure plasma has been used for medical treatments, such as for cancer, blood coagulation, and wound healing. The interactions that occur between plasma and cells/tissues have been analyzed extensively. Direct and indirect treatment of cells with plasma has broadened the applications of non-thermal atmospheric pressure plasma in medicine. Examples of indirect treatment include plasma-assisted immune-therapy and plasma-activated medium. Controlling intracellular redox balance may be key in plasma cancer treatment. Animal studies are required to test the effectiveness and safety of these treatments for future clinical applications.

  11. Timescale and magnitude of plasma thermal energy loss before and during disruptions in JET

    Riccardo, V.; Loarte, A.

    2005-01-01

    In this paper we analyse and discuss the thermal energy loss dynamics before and during JET disruptions that occurred between 2002 and 2004 in discharges which reached >4.5 MJ of thermal energy. We observe the slow thermal energy transients with diamagnetic loops and the fast ones with electron cyclotron emission and soft x-ray diagnostics. For most disruption types in JET, the plasma thermal energy at the time of the thermal quench is substantially less than that of the full performance plasma, typically in the range of 10-50% depending on plasma conditions and disruption type. The exceptions to this observation are disruptions in plasmas with a strong internal transport barrier (ITB) and in discharges terminating in a pure vertical displacement event, in which the plasma conserves a very high energy content up to the thermal quench. These disruption types are very sudden, leaving little scope for the combined action of soft plasma landing strategies and intrinsic performance degradation, both requiring >500 ms to be effective, to decrease the available thermal energy. The characteristic time for the loss of energy from the main plasma towards the PFCs in the thermal quench of JET disruptions is in the range 0.05-3.0 ms. The shortest timescales are typical of disruptions caused by excessive pressure peaking in ITB discharges. The available thermal energy fraction and thermal quench duration observed in JET can be processed (with due caution) into estimates for the projected PFC lifetime of the ITER target

  12. Finite length thermal equilibria of a pure electron plasma column

    Prasad, S.A.; O'Neil, T.M.

    1979-01-01

    The electrons of a pure electron plasma may be in thermal equilibrium with each other and still be confined by static magnetic and electric fields. Since the electrons make a significant contribution to the electric field, only certain density profiles are consistent with Poisson's equation. The class of such distributions for a finite length cylindrical column is investigated. In the limit where the Debye length is small compared with the dimensions of the column, the density is essentially constant out to some surface of revolution and then falls off abruptly. The falloff in density is a universal function when measured along the local normal to the surface of revolution and scaled in terms of the Debye length. The solution for the shape of the surface of revolution is simplified by passage to the limit of zero Debye length

  13. Synthesis of cobalt boride nanoparticles using radio frequency thermal plasma

    Lapitan, Jr. Lorico DS.; Ying Ying Chen; Seesoek Choe; Watanabe, Takayuki

    2012-01-01

    Nano size cobalt boride particles were synthesized from vapor phase using a 30 kw-4 MHz radio frequency (RF) thermal plasma. Cobalt and boron powder mixtures used as precursors in different composition and feed rate were evaporated immediately in the high temperature plasma and cobalt boride nanoparticles were produced through the quenching process. The x-ray diffractometry (XRD) patterns of cobalt boride nanoparticles prepared from the feed powder ratio of 1:2 and 1:3 for Co: B showed peaks that are associated with the Co 2 B and CoB crystal phases of cobalt boride. The XRD analysis revealed that increasing the powder feed rate results in a higher mass fraction and a larger crystalline diameter of cobalt boride nanoparticles. The images obtained by field emission scanning electron microscopy (FE-SEM) revealed that cobalt boride nanoparticles have a spherical morphology. The crystallite size of the particles estimated with XRD was found to be 18-22 nm. (author)

  14. Coulomb thermal properties and stability of the Io plasma torus

    Barbosa, D. D.; Coroniti, F. V.; Eviatar, A.

    1983-01-01

    Coulomb collisional energy exchange rates are computed for a model of the Io plasma torus consisting of newly created pickup ions, a background of thermally degraded intermediary ions, and a population of cooler electrons. The electrons are collisionally heated by both the pickup ions and background ions and are cooled by electron impact excitation of plasma ions which radiate in the EUV. It is found that a relative concentration of S III pickup ions forbidden S III/electrons = 0.1 with a temperature of 340 eV can deliver energy to the electrons at a rate of 3 x 10 to the -13th erg/cu cm per sec, sufficient to power the EUV emissions in the Io torus. The model predicts a background ion temperature Ti of about 53 eV and an electron temperature Te of about 5.5 eV on the basis of steady-state energy balance relations at Coulomb rates. The model also predicts electron temperature fluctuations at the 30 percent level on a time scale of less than 11 hours, consistent with recent observations of this phenomenon.

  15. Final treatment of spent batteries by thermal plasma.

    Cubas, Anelise Leal Vieira; Machado, Marina de Medeiros; Machado, Marília de Medeiros; Dutra, Ana Regina de Aguiar; Moecke, Elisa Helena Siegel; Fiedler, Haidi D; Bueno, Priscila

    2015-08-15

    The growth in the use of wireless devices, notebooks and other electronic products has led to an ever increasing demand for batteries, leading to these products being commonly found in inappropriate locations, with adverse effects on the environment and human health. Due to political pressure and according to the environmental legislation which regulates the destination of spent batteries, in several countries the application of reverse logistics to hazardous waste is required. Thus, some processes have been developed with the aim of providing an appropriate destination for these products. In this context, a method for the treatment of spent batteries using thermal plasma technology is proposed herein. The efficiency of the method was tested through the determination of parameters, such as total organic carbon, moisture content and density, as well as analysis by atomic absorption spectrometry, scanning electron microscopy and X-ray fluorescence using samples before and after inertization. The value obtained for the density was 19.15%. The TOC results indicated 8.05% of C in the batteries prior to pyrolisis and according to the XRF analysis Fe, S, Mn and Zn were the most stable elements in the samples (highest peaks). The efficiency of the paste inertization was 97% for zinc and 99.74% for manganese. The results also showed that the most efficient reactor was that with the DC transferred arc plasma torch and quartzite sand positively influenced by the vitrification during the pyrolysis of the electrolyte paste obtain from batteries. Copyright © 2015. Published by Elsevier Ltd.

  16. Thermal plasma spraying for SOFCs: Applications, potential advantages, and challenges

    Hui, Rob; Wang, Zhenwei; Jankovic, Jasna; Yick, Sing; Maric, Radenka; Ghosh, Dave [National Research Council Institute for Fuel Cell Innovation, 4250 Wesbrook Mall, Vancouver, BC V6T 1W5 (Canada); Kesler, Olivera [National Research Council Institute for Fuel Cell Innovation, 4250 Wesbrook Mall, Vancouver, BC V6T 1W5 (Canada); Department of Mechanical Engineering, University of British Columbia, 2054-6250 Applied Science Lane, Vancouver, BC V6T 1Z4 (Canada); Rose, Lars [National Research Council Institute for Fuel Cell Innovation, 4250 Wesbrook Mall, Vancouver, BC V6T 1W5 (Canada); Department of Materials Engineering, University of British Columbia, 309-6350 Stores Road, Vancouver, BC V6T 1Z4 (Canada)

    2007-07-10

    In this article, the applications, potential advantages, and challenges of thermal plasma spray (PS) processing for nanopowder production and cell fabrication of solid oxide fuel cells (SOFCs) are reviewed. PS processing creates sufficiently high temperatures to melt all materials fed into the plasma. The heated material can either be quenched into oxide powders or deposited as coatings. This technique has been applied to directly deposit functional layers as well as nanopowder for SOFCs application. In particularly, low melting point and highly active electrodes can be directly fabricated on zirconia-based electrolytes. This is a simple processing technique that does not require the use of organic solvents, offering the opportunity for flexible adjustment of process parameters, and significant time saving in production of the cell and cost reduction compared with tape casting, screen printing and sintering processing steps. Most importantly, PS processing shows strong potential to enable the deposition of metal-supported SOFCs through the integrated fabrication of membrane-electrode assemblies (MEA) on porous metallic substrates with consecutive deposition steps. On the other hand, the application of PS processing to produce SOFCs faces some challenges, such as insufficient porosity of the electrodes, the difficulty of obtaining a thin (<10 {mu}m) and dense electrolyte layer. Fed with H{sub 2} as the fuel gas and oxygen as the oxidant gas, the plasma sprayed cell reached high power densities of 770 mW cm{sup -2} at 900 C and 430 mW cm{sup -2} at 800 C at a cell voltage of 0.7 V. (author)

  17. Using plasma-fuel systems at Eurasian coal-fired thermal power stations

    Karpenko, E. I.; Karpenko, Yu. E.; Messerle, V. E.; Ustimenko, A. B.

    2009-06-01

    The development of plasma technology for igniting solid fuels at coal-fired thermal power stations in Russia, Kazakhstan, China, and other Eurasian countries is briefly reviewed. Basic layouts and technical and economic characteristics of plasma-fuel systems installed in different coal-fired boiles are considered together with some results from using these systems at coal-fired thermal power stations.

  18. Monte Carlo studies of thermalization of electron-hole pairs in spin-polarized degenerate electron gas in monolayer graphene

    Borowik, Piotr; Thobel, Jean-Luc; Adamowicz, Leszek

    2018-02-01

    Monte Carlo method is applied to the study of relaxation of excited electron-hole (e-h) pairs in graphene. The presence of background of spin-polarized electrons, with high density imposing degeneracy conditions, is assumed. To such system, a number of e-h pairs with spin polarization parallel or antiparallel to the background is injected. Two stages of relaxation: thermalization and cooling are clearly distinguished when average particles energy and its standard deviation σ _E are examined. At the very beginning of thermalization phase, holes loose energy to electrons, and after this process is substantially completed, particle distributions reorganize to take a Fermi-Dirac shape. To describe the evolution of and σ _E during thermalization, we define characteristic times τ _ {th} and values at the end of thermalization E_ {th} and σ _ {th}. The dependence of these parameters on various conditions, such as temperature and background density, is presented. It is shown that among the considered parameters, only the standard deviation of electrons energy allows to distinguish between different cases of relative spin polarizations of background and excited electrons.

  19. Bournonite PbCuSbS3 : Stereochemically Active Lone-Pair Electrons that Induce Low Thermal Conductivity.

    Dong, Yongkwan; Khabibullin, Artem R; Wei, Kaya; Salvador, James R; Nolas, George S; Woods, Lilia M

    2015-10-26

    An understanding of the structural features and bonding of a particular material, and the properties these features impart on its physical characteristics, is essential in the search for new systems that are of technological interest. For several relevant applications, the design or discovery of low thermal conductivity materials is of great importance. We report on the synthesis, crystal structure, thermal conductivity, and electronic-structure calculations of one such material, PbCuSbS3 . Our analysis is presented in terms of a comparative study with Sb2 S3 , from which PbCuSbS3 can be derived through cation substitution. The measured low thermal conductivity of PbCuSbS3 is explained by the distortive environment of the Pb and Sb atoms from the stereochemically active lone-pair s(2) electrons and their pronounced repulsive interaction. Our investigation suggests a general approach for the design of materials for phase-change-memory, thermal-barrier, thermal-rectification and thermoelectric applications, as well as other functions for which low thermal conductivity is purposefully sought. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Thermal analysis of the in-vessel components of the ITER plasma-position reflectometry

    Quental, P. B., E-mail: pquental@ipfn.tecnico.ulisboa.pt; Policarpo, H.; Luís, R.; Varela, P. [Instituto de Plasmas e Fusão Nuclear, Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisboa (Portugal)

    2016-11-15

    The ITER plasma position reflectometry system measures the edge electron density profile of the plasma, providing real-time supplementary contribution to the magnetic measurements of the plasma-wall distance. Some of the system components will be in direct sight of the plasma and therefore subject to plasma and stray radiation, which may cause excessive temperatures and stresses. In this work, thermal finite element analysis of the antenna and adjacent waveguides is conducted with ANSYS V17 (ANSYS® Academic Research, Release 17.0, 2016). Results allow the identification of critical temperature points, and solutions are proposed to improve the thermal behavior of the system.

  1. PLASMA EFFECTS ON FAST PAIR BEAMS. II. REACTIVE VERSUS KINETIC INSTABILITY OF PARALLEL ELECTROSTATIC WAVES

    Schlickeiser, R.; Krakau, S.; Supsar, M.

    2013-01-01

    The interaction of TeV gamma-rays from distant blazars with the extragalactic background light produces relativistic electron-positron pair beams by the photon-photon annihilation process. Using the linear instability analysis in the kinetic limit, which properly accounts for the longitudinal and the small but finite perpendicular momentum spread in the pair momentum distribution function, the growth rate of parallel propagating electrostatic oscillations in the intergalactic medium is calculated. Contrary to the claims of Miniati and Elyiv, we find that neither the longitudinal nor the perpendicular spread in the relativistic pair distribution function significantly affect the electrostatic growth rates. The maximum kinetic growth rate for no perpendicular spread is even about an order of magnitude greater than the corresponding reactive maximum growth rate. The reduction factors in the maximum growth rate due to the finite perpendicular spread in the pair distribution function are tiny and always less than 10 –4 . We confirm earlier conclusions by Broderick et al. and our group that the created pair beam distribution function is quickly unstable in the unmagnetized intergalactic medium. Therefore, there is no need to require the existence of small intergalactic magnetic fields to scatter the produced pairs, so that the explanation (made by several authors) for the Fermi non-detection of the inverse Compton scattered GeV gamma-rays by a finite deflecting intergalactic magnetic field is not necessary. In particular, the various derived lower bounds for the intergalactic magnetic fields are invalid due to the pair beam instability argument

  2. CONDENSED MATTER: STRUCTURE, THERMAL AND MECHANICAL PROPERTIES: Pair interaction of bilayer-coated nanoscopic particles

    Zhang, Qi-Yi

    2009-02-01

    The pair interaction between bilayer membrane-coated nanosized particles has been explored by using the self-consistent field (SCF) theory. The bilayer membranes are composed of amphiphilic polymers. For different system parameters, the pair-interaction free energies are obtained. Particular emphasis is placed on the analysis of a sequence of structural transformations of bilayers on spherical particles, which occur during their approaching processes. For different head fractions of amphiphiles, the asymmetrical morphologies between bilayers on two particles and the inverted micellar intermediates have been found in the membrane fusion pathway. These results can benefit the fabrication of vesicles as encapsulation vectors for drug and gene delivery.

  3. Thermal plasma treatment of cell-phone waste : preliminary result

    Ruj, B. [Central Mechanical Engineering Research Inst., Durgapur (India). Thermal Engineering Group; Chang, J.S.; Li, O.L. [McMaster Univ., Hamilton, ON (Canada). Dept. of Engineering Physics; Pietsch, G. [RWTH Aachen Univ., Aachen (Germany)

    2010-07-01

    The cell phone is an indispensable service facilitator, however, the disposal and recycling of cell phones is a major problem. While the potential life span of a mobile phone, excluding batteries, is over 10 years, most of the users upgrade their phones approximately four times during this period. Cell phone waste is significantly more hazardous than many other municipal wastes as it contains thousands of components made of toxic chemicals and metals like lead, cadmium, chromium, mercury, polyvinyl chlorides (PVC), brominated flame retardants, beryllium, antimony and phthalates. Cell phones also use many expensive rare metals. Since cell phones are made up of plastics, metals, ceramics, and trace other substances, primitive recycling or disposal of cell phone waste to landfills and incinerators creates irreversible environmental damage by polluting water and soil, and contaminating air. In order to minimize releases into the environment and threat to human health, the disposal of cell phones needs to be managed in an environmentally friendly way. This paper discussed a safer method of reducing the generation of syngas and hydrocarbons and metal recovery through the treatment of cell phone wastes by a thermal plasma. The presentation discussed the experiment, with particular reference to sample preparation; experimental set-up; and results four samples with different experimental conditions. It was concluded that the plasma treatment of cell phone waste in reduced condition generates gaseous components such as hydrogen, carbon monoxide, and hydrocarbons which are combustible. Therefore, this system is an energy recovery system that contributes to resource conservation and reduction of climate change gases. 5 refs., 2 tabs., 2 figs.

  4. INTERACTION OF IRON(II MIXED-LIGAND COMPLEXES WITH DNA: BASE-PAIR SPECIFICITY AND THERMAL DENATURATION STUDIES

    Mudasir Mudasir

    2010-06-01

    Full Text Available A research about base-pair specificity of the DNA binding of [Fe(phen3]2+, [Fe(phen2(dip]2+ and [Fe(phen(dip2]2+ complexes and the effect of calf-thymus DNA (ct-DNA binding of these metal complexes on thermal denaturation of ct-DNA has been carried out. This research is intended to evaluate the preferential binding of the complexes to the sequence of DNA (A-T or G-C sequence and to investigate the binding strength and mode upon their interaction with DNA. Base-pair specificity of the DNA binding of the complexes was determined by comparing the equilibrium binding constant (Kb of each complex to polysynthetic DNA that contain only A-T or G-C sequence. The Kb value of the interaction was determined by spectrophotometric titration and thermal denaturation temperature (Tm was determined by monitoring the absorbance of the mixture solution of each complex and ct-DNA at λ =260 nm as temperature was elevated in the range of 25 - 100 oC. Results of the study show that in general all iron(II complexes studied exhibit a base-pair specificity in their DNA binding to prefer the relatively facile A-T sequence as compared to the G-C one. The thermal denaturation experiments have demonstrated that Fe(phen3]2+ and [Fe(phen2(dip]2+ interact weakly with double helical DNA via electrostatic interaction as indicated by insignificant changes in melting temperature, whereas [Fe(phen2(dip]2+  most probably binds to DNA in mixed modes of interaction, i.e.: intercalation and electrostatic interaction. This conclusion is based on the fact that the binding of [Fe(phen2(dip]2+ to ct-DNA moderately increase the Tm value of ct- DNA   Keywords: DNA Binding, mixed-ligand complexes

  5. Optimization of Non-Thermal Plasma Treatment in an In Vivo Model Organism.

    Amanda Lee

    Full Text Available Non-thermal plasma is increasingly being recognized for a wide range of medical and biological applications. However, the effect of non-thermal plasma on physiological functions is not well characterized in in vivo model systems. Here we use a genetically amenable, widely used model system, Drosophila melanogaster, to develop an in vivo system, and investigate the role of non-thermal plasma in blood cell differentiation. Although the blood system in Drosophila is primitive, it is an efficient system with three types of hemocytes, functioning during different developmental stages and environmental stimuli. Blood cell differentiation in Drosophila plays an essential role in tissue modeling during embryogenesis, morphogenesis and also in innate immunity. In this study, we optimized distance and frequency for a direct non-thermal plasma application, and standardized doses to treat larvae and adult flies so that there is no effect on the viability, fertility or locomotion of the organism. We discovered that at optimal distance, time and frequency, application of plasma induced blood cell differentiation in the Drosophila larval lymph gland. We articulate that the augmented differentiation could be due to an increase in the levels of reactive oxygen species (ROS upon non-thermal plasma application. Our studies open avenues to use Drosophila as a model system in plasma medicine to study various genetic disorders and biological processes where non-thermal plasma has a possible therapeutic application.

  6. Stationary self-focusing of Gaussian laser beam in relativistic thermal quantum plasma

    Patil, S. D.; Takale, M. V.

    2013-01-01

    In the present paper, we have employed the quantum dielectric response in thermal quantum plasma to model relativistic self-focusing of Gaussian laser beam in a plasma. We have presented an extensive parametric investigation of the dependence of beam-width parameter on distance of propagation in relativistic thermal quantum plasma. We have studied the role of Fermi temperature in the phenomenon of self-focusing. It is found that the quantum effects cause much higher oscillations of beam-width parameter and better relativistic focusing of laser beam in thermal quantum plasma in comparison with that in the relativistic cold quantum plasma and classical relativistic plasma. Our computations show more reliable results in comparison to the previous works

  7. In situ observation of thermal relaxation of interstitial-vacancy pair defects in a graphite gap

    Urita, Koki; Suenaga, Kazu; Iijima, Sumio; Sugai, Toshiki; Shinohara, Hisanori

    2005-01-01

    Direct observation of individual defects during formation and annihilation in the interlayer gap of double-wall carbon nanotubes (DWNT) is demonstrated by high-resolution transmission electron microscopy. The interlayer defects that bridge two adjacent graphen layers in DWNT are stable for a macroscopic time at the temperature below 450 K. These defects are assigned to a cluster of one or two interstitial-vacancy pairs (I-V pairs) and often disappear just after their formation at higher temperatures due to an instantaneous recombination of the interstitial atom with vacancy. Systematic observations performed at the elevated temperatures find a threshold for the defect annihilation at 450-500 K, which, indeed, corresponds to the known temperature for the Wigner energy release

  8. In situ observation of thermal relaxation of interstitial-vacancy pair defects in a graphite gap.

    Urita, Koki; Suenaga, Kazu; Sugai, Toshiki; Shinohara, Hisanori; Iijima, Sumio

    2005-04-22

    Direct observation of individual defects during formation and annihilation in the interlayer gap of double-wall carbon nanotubes (DWNT) is demonstrated by high-resolution transmission electron microscopy. The interlayer defects that bridge two adjacent graphen layers in DWNT are stable for a macroscopic time at the temperature below 450 K. These defects are assigned to a cluster of one or two interstitial-vacancy pairs (I-V pairs) and often disappear just after their formation at higher temperatures due to an instantaneous recombination of the interstitial atom with vacancy. Systematic observations performed at the elevated temperatures find a threshold for the defect annihilation at 450-500 K, which, indeed, corresponds to the known temperature for the Wigner energy release.

  9. Heavy metals behavior during thermal plasma vitrification of incineration residues

    Cerqueira, N.; Vandensteendam, C.; Baronnet, J.M.

    2005-01-01

    In the developed world, incineration of wastes is widely and increasingly practiced. Worldwide, a total of approximately 100 millions of tons of municipal solid waste (MSW) material is incinerated annually. Incineration of one ton of MSW leads to the formation of 30 to 50 kg of fly ash, depending on the type of incinerator. The waste disposal of these dusts already causes great problems today; they are of low bulk density, they contain high concentrations of hazardous water-soluble heavy metal compounds, organohalogen compounds (dioxines, furanes), sulfur, and chlorinated compounds. Thermal processes, based mainly on electrical arc processes, show great promise: the residues are melted at high temperature and converted in a relatively inert glass. A few tens of plants, essentially in Japan and Taiwan, have been in industrial operation for a few years. To be authorized to be dumped in a common landfill, the glassy product has to satisfy the leaching test procedure to ensure long-term durability. But to satisfy the regulation to be reused, for example as a nonhazardous standard material in road building, the glassy product would probably include contents in some heavy metals lower than critical limits. So today, there are two alternatives: the first one is to improve the heavy toxic metals evaporation to get a 'light' glassy product and to recycle separately the said separated metals; the second is on the contrary to improve the incorporation of a maximum of heavy metals into the vitreous silicate matrix. Whatever, it is highly required to control, in situ and in real time, volatility of these metals during ash melting under electrical arc. The objective of this work was to reach basic data about metals volatility under the plasma column of an electrical arc transferred on the melt: an experiment has been designed to examine the effects of processing conditions, such as melt temperature, melt composition, and furnace atmosphere, upon volatilization and glassy slag

  10. Synthesis of {gamma}-aluminium oxynitride spinel using thermal plasma technique

    Panda, Pravuram; Singh, S. K.; Sinha, S. P. [School of Applied Science (Physics), KIIT University, Bhubaneswar 751024 (India); Advanced Materials Technology Department, IMMT (CSIR), Bhubaneswar 751013 (India); School of Applied Science (Physics), KIIT University, Bhubaneswar 751024 (India)

    2012-07-23

    The synthesis technique of {gamma}-AlON in NH{sub 3} plasma using extended arc thermal plasma reactor have been reported. Dense cubic AlON spinel was synthesized in liquid state by fusion of mixture of Al{sub 2}O{sub 3} and AlN powder under thermal plasma. The density of the fused AlON was found to be 3.64 g/cc which is 98.11% of theoretical value. The formation of AlON was confirmed from XRD and Raman studies. Well faceted structure of plasma fused AlON was observed in FE-SEM micrograph.

  11. PAIR INFLUENCE OF WIND SPEED AND MEAN RADIANT TEMPERATURE ON OUTDOOR THERMAL COMFORT OF HUMID TROPICAL ENVIRONMENT

    Sangkertadi Sangkertadi

    2016-01-01

    Full Text Available The purposes of this article is to explore knowledge of outdoor thermal comfort in humid tropical environment for urban activities especially for people in walking activity, and those who stationary/seated with moderate action. It will be characterized the pair influence of wind speed and radiant temperature on the outdoor thermal comfort. Many of researchers stated that those two microclimate variables give significant role on outdoor thermal comfort in tropical humid area. Outdoor Tropical Comfort (OTC model was used for simulation in this study. The model output is comfort scale that refers on ASHRAE definition. The model consists of two regression equations with variables of air temperature, globe temperature, wind speed, humidity and body posture, for two types of activity: walking and seated. From the results it can be stated that there is significant role of wind speed to reduce mean radiant temperature and globe temperature, when the velocity is elevated from 0.5 m/s to 2 m/s. However, the wind has not play significant role when the speed is changed from 2 m/s to 3.5 m/s. The results of the study may inspire us to implement effectiveness of electrical-fan equipment for outdoor space in order to get optimum wind speed, coupled with optimum design of shading devices to minimize radiant temperature for thermal comfort.

  12. Comparative analysis of turbulent effects on thermal plasma characteristics inside the plasma torches with rod- and well-type cathodes

    Hur, Min; Hong, Sang Hee

    2002-01-01

    The thermal plasma characteristics inside the two non-transferred plasma torches with rod-type cathode (RTC) and well-type cathode (WTC) are analysed in conjunction with turbulent effects on them in the atmospheric-pressure conditions. A control volume method and a modified semi-implicit pressure linked equations revised algorithm are used for solving the governing equations, i.e. conservation equations of mass, momentum, and energy together with a current continuity equation for arc discharge. A cold flow analysis is introduced to find the cathode spot position in the WTC torch, and both the laminar and turbulent models are employed to gain a physical insight into the turbulent effects on the thermal plasma characteristics produced inside the two torches. The numerical analysis for an RTC torch shows that slightly different values of plasma temperature and velocity between the laminar and turbulent calculations occur and the radial temperature profiles are constricted at the axis with increasing the gas flow rate, and that the large turbulent viscosities appear mostly near the anode wall. These calculated results indicate that the turbulent effects on the thermal plasma characteristics are very weak in the whole discharge region inside the RTC torch. On the other hand, the calculated results of the two numerical simulations for a WTC torch present that the significantly different values of plasma characteristics between the two models appear in the whole torch region and the plasma temperatures decrease with increasing the gas flow rate because the relatively strong turbulent effects are prevailing in the entire interior region of the WTC torch. From the comparisons of plasma net powers calculated and measured in this work, the turbulent modelling turns out to provide the more accurately calculated results close to the measured ones compared with the laminar one, especially for the torch with WTC. This is because the turbulent effects are considerably strong in

  13. Nonthermal Particle Acceleration in 3D Relativistic Magnetic Reconnection in Pair Plasma

    Werner, Gregory R.; Uzdensky, Dmitri A., E-mail: Greg.Werner@colorado.edu [Center for Integrated Plasma Studies, Physics Department, University of Colorado, 390 UCB, Boulder, CO 80309 (United States)

    2017-07-10

    As a fundamental process converting magnetic to plasma energy in high-energy astrophysical plasmas, relativistic magnetic reconnection is a leading explanation for the acceleration of particles to the ultrarelativistic energies that are necessary to power nonthermal emission (especially X-rays and gamma-rays) in pulsar magnetospheres and pulsar wind nebulae, coronae and jets of accreting black holes, and gamma-ray bursts. An important objective of plasma astrophysics is therefore the characterization of nonthermal particle acceleration (NTPA) effected by reconnection. Reconnection-powered NTPA has been demonstrated over a wide range of physical conditions using large 2D kinetic simulations. However, its robustness in realistic 3D reconnection—in particular, whether the 3D relativistic drift-kink instability (RDKI) disrupts NTPA—has not been systematically investigated, although pioneering 3D simulations have observed NTPA in isolated cases. Here, we present the first comprehensive study of NTPA in 3D relativistic reconnection in collisionless electron–positron plasmas, characterizing NTPA as the strength of 3D effects is varied systematically via the length in the third dimension and the strength of the guide magnetic field. We find that, while the RDKI prominently perturbs 3D reconnecting current sheets, it does not suppress particle acceleration, even for zero guide field; fully 3D reconnection robustly and efficiently produces nonthermal power-law particle spectra closely resembling those obtained in 2D. This finding provides strong support for reconnection as the key mechanism powering high-energy flares in various astrophysical systems. We also show that strong guide fields significantly inhibit NTPA, slowing reconnection and limiting the energy available for plasma energization, yielding steeper and shorter power-law spectra.

  14. Thermal structure of atmospheric pressure non-equilibrium plasmas

    Nozaki, Tomohiro; Unno, Yasuko; Okazaki, Ken

    2002-01-01

    The thermal structure of a methane-fed dielectric barrier discharge (DBD) and a atmospheric pressure glow-discharge (APG) has been extensively investigated in terms of time-averaged gas temperature profile between two parallel-plate electrodes separated by 1.0 mm. Emission spectroscopy of the rotational band of CH ((0, 0) A 2 Δ→X 2 Π:431 nm) was performed for this purpose. In order to minimize average temperature increase in the reaction field, DBD and APG were activated by 10 kHz with 2% duty cycle pulsed voltage (2 μs pulse width/100 μs interval). In DBD, temperature increase of a single microdischarge, on a time average, reached 200 K. It suddenly decreased below 100 K associated with the dark space formation near the dielectric barrier. Also, gas temperature in the surface discharge was fairly low because emission in these regions was limited within the initial stages of propagation (∼5 ns), whereas energy deposition would continue until microdischarge extinction; these facts implied that rotational temperature seemed to be far below the actual gas temperature in these regions. In APG, gas temperature was uniformly increased by positive column formation. In addition, a remarkable temperature increase due to negative glow formation was obtained only near the metallic electrode. For practical interest, we also investigated the net temperature increase with high frequency operations (AC-80 kHz), which depends not only on plasma properties, but also various engineering factors such as flow field, external cooling conditions, and total input power. In DBD, gas temperature in the middle of gas gap was significantly increased with increasing input power because of poor cooling conditions. In APG, in contrast, gas temperature near the electrodes was significantly increased associated with negative glow formation

  15. Thermal plasma synthesis of Fe1−xNix alloy nanoparticles

    Raut, Suyog A.; Kanhe, Nilesh S.; Bhoraskar, S. V.; Mathe, V. L.; Das, A. K.

    2014-01-01

    Fe-Ni alloy nanoparticles are of great interest because of diverse practical applications in the fields such as magnetic fluids, high density recording media, catalysis and medicine. We report the synthesis of Fe-Ni nanoparticles via thermal plasma route. Thermal plasma assisted synthesis is a high temperature process and gives high yields of production. Here, we have used direct arc thermal plasma plume of 6kw as a source of energy at operating pressure 500 Torr. The mixture of Fe-Ni powder in required proportion (Fe 1−x Ni x ; x=0.30, 0.32, 0.34, 0.36, 0.38 and 0.40) was made to evaporate simultaneously from the graphite anode in thermal plasma reactor to form Fe-Ni bimetallic nanoparticles. The as synthesized particles were characterized by X-Ray Diffraction (XRD), Thermo-Gravimetric Analysis/Differential Scanning Calorimtry (TGA/DSC)

  16. Complementary variational principle method applied to thermal conductivities of a plasma in a uniform magnetic field

    Sehgal, A K; Gupta, S C [Punjabi Univ., Patiala (India). Dept. of Physics

    1982-12-14

    The complementary variational principles method (CVP) is applied to the thermal conductivities of a plasma in a uniform magnetic field. The results of computations show that the CVP derived results are very useful.

  17. Kinetic theory for radiation interacting with sound waves in ultrarelativistic pair plasmas

    Marklund, Mattias; Shukla, Padma K.; Stenflo, Lennart

    2006-01-01

    A kinetic theory for radiation interacting with sound waves in an ultrarelativistic electron-positron plasma is developed. It is shown that the effect of a spatial spectral broadening of the electromagnetic pulse is to introduce a reduction of the growth rates for the decay and modulational instabilities. Such spectral broadening could be due to a finite pulse coherence length, or through the use of random phase filters, and would stabilize the propagation of electromagnetic pulses

  18. First on-line positron experiments en route to pair-plasma creation

    Stanja, Juliane; Hergenhahn, Uwe; Stenson, Eve V. [Max-Planck-Institut fuer Plasmaphysik (Germany); Niemann, Holger; Sunn Pedersen, Thomas [Max-Planck-Institut fuer Plasmaphysik (Germany); Ernst-Moritz-Arndt Universitaet Greifswald (Germany); Saitoh, Haruhiko [Max-Planck-Institut fuer Plasmaphysik (Germany); The University of Tokyo (Japan); Stoneking, Matthew R. [Lawrence University (United States); Hugenschmidt, Christoph; Piochacz, Christian [Technische Universitaet Muenchen (Germany); Schweikhard, Lutz [Ernst-Moritz-Arndt Universitaet Greifswald (Germany)

    2016-07-01

    Electron-positron plasmas are predicted to show a fundamentally different behavior from traditional ion-electron plasmas, because of the equal masses of the two species. Using up to 10{sup 9} positrons per second provided by the NEPOMUC (Neutron-Induced Positron Source Munich) facility, the APEX/PAX team aims to create the first such plasma confined in a toroidal magnetic trap. Positron beam parameters as well as efficient injection and confinement schemes for both species in toroidal geometries are fundamental to the project. In this contribution we present results from first on-line positron experiments. Besides characterizing the NEPOMUC beam we conducted positron injection experiments into a dipole magnetic field configuration. Using static electric fields, a 5-eV positron beam was transported across magnetic field lines into the confinement region. With this method, up to 38% of the incoming particles reach the confinement region and make at least a 180 revolution around the magnet. Under dedicated experimental conditions confinement on the order of 1 ms was realized.

  19. Plasma diagnostic techniques in thermal-barrier tandem-mirror fusion experiments

    Silver, E.H.; Clauser, J.F.; Carter, M.R.; Failor, B.H.; Foote, J.H.; Hornady, R.S.; James, R.A.; Lasnier, C.J.; Perkins, D.E.

    1986-01-01

    We review two classes of plasma diagnostic techniques used in thermal-barrier tandem-mirror fusion experiments. The emphasis of the first class is to study mirror-trapped electrons at the thermal-barrier location. The focus of the second class is to measure the spatial and temporal behavior of the plasma space potential at various axial locations. The design and operation of the instruments in these two categories are discussed and data that are representative of their performance is presented

  20. Dynamics and control of the vortex flow behind a slender conical forebody by a pair of plasma actuators

    Meng, Xuanshi; Long, Yuexiao; Wang, Jianlei; Liu, Feng; Luo, Shijun

    2018-02-01

    Detailed particle-image-velocimetry (PIV) and surface pressure measurements are presented to study the vortex flow behind a slender conical forebody at high angles of attack. The results confirm the existence of two randomly appearing mirror imaged asymmetric bi-stable states of the separation vortices, giving rise to large side force and moment. A pair of carefully designed dielectric barrier discharge plasma actuators mounted near the apex and on both sides of the conical body are used to manipulate the vortex flow and thus provide control of the side forces on the body without using flaps. By making use of a duty-cycle actuation scheme that alternately actuates the port and starboard plasma actuators and optimizing the duty-cycle frequency, the present work demonstrates the feasibility of achieving a nearly perfect linear proportional control of the side force and moment in response to the duty-cycle ratio. Phase-locked PIV and surface pressure measurements are used to study the unsteady dynamic evolution of the flow within one duty-cycle actuation to reveal the flow control mechanism. It is found that under the duty-cycle actuation with the optimized frequency, the vortex flow essentially follows the plasma actuation by alternating between the two bi-stable states controlled directly by the duty-cycle ratio.

  1. Thermal equilibrium of pure electron plasmas across a central region of magnetic surfaces

    Hahn, Michael; Pedersen, Thomas Sunn

    2009-06-01

    Measurements of the equilibria of plasmas created by emission from a biased filament located off the magnetic axis in the Columbia Non-neutral Torus (CNT) [T. S. Pedersen, J. P. Kremer, R. G. Lefrancois et al., Fusion Sci. Technol. 50, 372 (2006)] show that such plasmas have equilibrium properties consistent with the inner surfaces being in a state of cross-surface thermal equilibrium. Numerical solutions to the equilibrium equation were used to fit the experimental data and demonstrate consistency with cross-surface thermal equilibrium. Previous experiments in CNT showed that constant temperatures across magnetic surfaces are characteristic of CNT plasmas, implying thermal confinement times much less than particle confinement times. These results show that when emitting off axis there is a volume of inner surfaces where diffusion into that region is balanced by outward transport, producing a Boltzmann distribution of electrons. When combined with the low thermal energy confinement time this is a cross-surface thermal equilibrium.

  2. Thermal equilibrium of pure electron plasmas across a central region of magnetic surfaces

    Hahn, Michael; Pedersen, Thomas Sunn

    2009-01-01

    Measurements of the equilibria of plasmas created by emission from a biased filament located off the magnetic axis in the Columbia Non-neutral Torus (CNT) [T. S. Pedersen, J. P. Kremer, R. G. Lefrancois et al., Fusion Sci. Technol. 50, 372 (2006)] show that such plasmas have equilibrium properties consistent with the inner surfaces being in a state of cross-surface thermal equilibrium. Numerical solutions to the equilibrium equation were used to fit the experimental data and demonstrate consistency with cross-surface thermal equilibrium. Previous experiments in CNT showed that constant temperatures across magnetic surfaces are characteristic of CNT plasmas, implying thermal confinement times much less than particle confinement times. These results show that when emitting off axis there is a volume of inner surfaces where diffusion into that region is balanced by outward transport, producing a Boltzmann distribution of electrons. When combined with the low thermal energy confinement time this is a cross-surface thermal equilibrium.

  3. Study of the thermal and suprathermal electron density fluctuations of the plasma in the Focus experiment

    Jolas, A.

    1981-10-01

    An experiment on Thomson scattering of ruby laser light by the electrons of a plasma produced by an intense discharge between the electrodes of a coaxial gun in a gas at low pressure has been carried out. It is shown that the imploding plasma is made up of layers with different characteristics: a dense plasma layer where the density fluctuations are isotropic and have a thermal level, and a tenuous plasma layer where the fluctuations are anisotropic, and strongly suprathermal. The suprathermal fluctuations are attributed to microscopic instabilities generated by the electric current circulating in the transition zone where the magnetic field penetrates the plasma [fr

  4. Transition Region Emission and the Energy Input to Thermal Plasma in Solar Flares

    Holman, Gordon D.; Holman, Gordon D.; Dennis, Brian R.; Haga, Leah; Raymond, John C.; Panasyuk, Alexander

    2005-01-01

    Understanding the energetics of solar flares depends on obtaining reliable determinations of the energy input to flare plasma. X-ray observations of the thermal bremsstrahlung from hot flare plasma provide temperatures and emission measures which, along with estimates of the plasma volume, allow the energy content of this hot plasma to be computed. However, if thermal energy losses are significant or if significant energy goes directly into cooler plasma, this is only a lower limit on the total energy injected into thermal plasma during the flare. We use SOHO UVCS observations of O VI flare emission scattered by coronal O VI ions to deduce the flare emission at transition region temperatures between 100,000 K and 1 MK for the 2002 July 23 and other flares. We find that the radiated energy at these temperatures significantly increases the deduced energy input to the thermal plasma, but by an amount that is less than the uncertainty in the computed energies. Comparisons of computed thermal and nonthermal electron energies deduced from RHESSI, GOES, and UVCS are shown.

  5. Thermal Plasma Synthesis of Crystalline Gallium Nitride Nanopowder from Gallium Nitrate Hydrate and Melamine

    Tae-Hee Kim

    2016-02-01

    Full Text Available Gallium nitride (GaN nanopowder used as a blue fluorescent material was synthesized by using a direct current (DC non-transferred arc plasma. Gallium nitrate hydrate (Ga(NO33∙xH2O was used as a raw material and NH3 gas was used as a nitridation source. Additionally, melamine (C3H6N6 powder was injected into the plasma flame to prevent the oxidation of gallium to gallium oxide (Ga2O3. Argon thermal plasma was applied to synthesize GaN nanopowder. The synthesized GaN nanopowder by thermal plasma has low crystallinity and purity. It was improved to relatively high crystallinity and purity by annealing. The crystallinity is enhanced by the thermal treatment and the purity was increased by the elimination of residual C3H6N6. The combined process of thermal plasma and annealing was appropriate for synthesizing crystalline GaN nanopowder. The annealing process after the plasma synthesis of GaN nanopowder eliminated residual contamination and enhanced the crystallinity of GaN nanopowder. As a result, crystalline GaN nanopowder which has an average particle size of 30 nm was synthesized by the combination of thermal plasma treatment and annealing.

  6. Experimental Study On Thermal Wave Type Adsorption Refrigeration System Working On A Pair Of Activated Carbon And Methanol

    Grzebielec Andrzej

    2015-12-01

    Full Text Available The aim of the study was to examine the efficiency of the thermal wave type adsorption refrigerating equipment working on a pair of activated carbon and methanol. Adsorption units can work in trigeneration systems and in applications driven by waste heat. They can be built also as a part of hybrid sorption-compressor systems, and they are very popular in solar refrigeration systems and energy storage units. The device examined in this study operates in a special mode called thermal wave. This mode allows to achieve higher efficiency rates than the normal mode of operation, as a significant contributor to transport heat from one to the other adsorber. To carry out the experiment a test bench was built, consisting of two cylindrical adsorbers filled with activated carbon, condenser, evaporator, oil heater and two oil coolers. Thermal oil circulation was responsible for providing and receiving heat from adsorbers. In order to perform the correct action a special control algorithm device was developed and implemented to keep the temperature in the evaporator at a preset level. The experimental results show the operating parameters changes in both adsorbers. Obtained COP (coefficient of performance for the cycle was 0.13.

  7. THERMODYNAMIC REASONS OF AGGLOMERATION OF DUST PARTICLES IN THE THERMAL DUSTY PLASMA

    V.I.Vishnyakov

    2003-01-01

    Full Text Available The thermodynamic equilibrium of thermal dusty plasmas consisting of ionized gas (plasma and solid particles (dust grains, which interact with each other, is studied. The tendency of grains in dusty plasmas to agglomerate corresponds to the tendency of dusty plasmas to balanced states. When grains agglomerate, electrical perturbations generated by each grain concentrate inside the agglomerate. The plasma is perturbed only by the agglomerate's exterior surface. The greater number of possible states for electrons and ions in plasma depends on the volume of perturbation of grains. The fewer are the perturbations the greater is the amount of possible states for electrons and ions in plasma. If the grains collected from a distance smaller than 8 Debye lengths, the total volume of perturbations is minimized; the free energy of the plasma is also minimized.

  8. Development of innovative thermal plasma and particle diagnostics

    Bachmann, Benjamin-Leon

    2013-09-24

    Three original plasma diagnostic systems have been developed to investigate transient three-dimensional plasma processes with high spatial and temporal resolution. The developed diagnostics have been analyzed and tested by increasing the complexity from a stationary free burning Argon arc to a dc pulsed process and finally to a transient gas metal arc including droplet transfer through the plasma. The transient plasma parameters that have been determined include three-dimensional axially symmetric plasma densities (n{sub e}, n{sub A}, n{sub A+}, n{sub A++}), electron temperatures (T{sub e}), electrical conductivities (σ{sub el}), magnetic flux densities (B) and current densities (j{sub el}). In the case of a droplet transfer through an arc consisting of an Iron/Argon plasma, the droplet density, surface tension, viscosity, and temperature have been determined.

  9. Dust ion-acoustic shock waves in magnetized pair-ion plasma with kappa distributed electrons

    Kaur, B.; Singh, M.; Saini, N. S.

    2018-01-01

    We have performed a theoretical and numerical analysis of the three dimensional dynamics of nonlinear dust ion-acoustic shock waves (DIASWs) in a magnetized plasma, consisting of positive and negative ion fluids, kappa distributed electrons, immobile dust particulates along with positive and negative ion kinematic viscosity. By employing the reductive perturbation technique, we have derived the nonlinear Zakharov-Kuznetsov-Burgers (ZKB) equation, in which the nonlinear forces are balanced by dissipative forces (associated with kinematic viscosity). It is observed that the characteristics of DIASWs are significantly affected by superthermality of electrons, magnetic field strength, direction cosines, dust concentration, positive to negative ions mass ratio and viscosity of positive and negative ions.

  10. Oblique propagation of electron thermal modes below the electron plasma frequency without boundary effects

    Ohnuma, T.; Watanabe, T.; Sanuki, H.

    1981-08-01

    Propagation characteristics and refractive effects of an oblique electron thermal mode without boundary effects below the electron plasma frequency are studied experimentally and theoretically in an inhomogeneous magnetized plasma. The behavior of this mode observed experimentally was confirmed by the theoretical analysis based on a new type of ray theory. (author)

  11. Analysis of the expanding thermal argon-oxygen plasma gas phase

    Hest, van M.F.A.M.; Haartsen, J.R.; Weert, van M.H.M.; Schram, D.C.; Sanden, van de M.C.M.

    2003-01-01

    An expanding thermal argon plasma into which oxygen is injected has been analyzed by means of Langmuir and Pitot probe measurements. Information is obtained on the ion d. profile and the flow pattern in the downstream plasma. A combination of Langmuir and Pitot probe measurements provide information

  12. Investigations of a thermal plasma jet structure by generalized correlation dimension

    Gruber, Jan; Hlína, Jan; Šonský, Jiří

    2013-01-01

    Roč. 46, č. 1 (2013), s. 1-8 ISSN 0022-3727 Institutional research plan: CEZ:AV0Z20570509 Keywords : correlation dimension * turbulence * thermal plasma Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.521, year: 2013

  13. Time-resolved tomographic measurements of temperatures in a thermal plasma jet

    Hlína, Jan; Šonský, Jiří

    2010-01-01

    Roč. 43, č. 5 (2010), s. 1-9 ISSN 0022-3727 Institutional research plan: CEZ:AV0Z20570509 Keywords : thermal plasma jet * optical diagnostics * temperature distribution Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.105, year: 2010

  14. Novel Prospects for Plasma Spray-Physical Vapor Deposition of Columnar Thermal Barrier Coatings

    Anwaar, Aleem; Wei, Lianglinag; Guo, Qian; Zhang, Baopeng; Guo, Hongbo

    2017-12-01

    Plasma spray-physical vapor deposition (PS-PVD) is an emerging coating technique that can produce columnar thermal barrier coatings from vapor phase. Feedstock treatment at the start of its trajectory in the plasma torch nozzle is important for such vapor-phase deposition. This study describes the effects of the plasma composition (Ar/He) on the plasma characteristics, plasma-particle interaction, and particle dynamics at different points spatially distributed inside the plasma torch nozzle. The results of calculations show that increasing the fraction of argon in the plasma gas mixture enhances the momentum and heat flow between the plasma and injected feedstock. For the plasma gas combination of 45Ar/45He, the total enthalpy transferred to a representative powder particle inside the plasma torch nozzle is highest ( 9828 kJ/kg). Moreover, due to the properties of the plasma, the contribution of the cylindrical throat, i.e., from the feed injection point (FIP) to the start of divergence (SOD), to the total transferred energy is 69%. The carrier gas flow for different plasma gas mixtures was also investigated by optical emission spectroscopy (OES) measurements of zirconium emissions. Yttria-stabilized zirconia (YSZ) coating microstructures were produced when using selected plasma gas compositions and corresponding carrier gas flows; structural morphologies were found to be in good agreement with OES and theoretical predictions. Quasicolumnar microstructure was obtained with porosity of 15% when applying the plasma composition of 45Ar/45He.

  15. Microstructural evolution and growth kinetics of thermally grown oxides in plasma sprayed thermal barrier coatings

    Xiaoju Liu

    2016-02-01

    Full Text Available The formation of thermally grown oxide (TGO during high temperature is a key factor to the degradation of thermal barrier coatings (TBCs applied on hot section components. In the present study both the CoNiCrAlY bond coat and ZrO2-8 wt.% Y2O3 (8YSZ ceramic coat of TBCs were prepared by air plasma spraying (APS. The composition and microstructure of TGO in TBCs were investigated using scanning electron microscopy (SEM, energy dispersive spectroscopy (EDS and X-ray diffraction (XRD analysis. The growth rate of TGO for TBC and pure BC were gained after isothermal oxidation at 1100 °C for various times. The results showed that as-sprayed bond coat consisted of β and γ/γ′phases, β phase reducesd as the oxidation time increased. The TGO comprised α-Al2O3 formed in the first 2 h. CoO, NiO, Cr2O3 and spinel oxides appeared after 20 h of oxidation. Contents of CoO and NiO reduced while that of Cr2O3 and spinel oxides increased in the later oxidation stage. The TGO eventually consisted of a sub-Al2O3 layer with columnar microstructure and the upper porous CS clusters. The TGO growth kinetics for two kinds of samples followed parabolic laws, with oxidation rate constant of 0.344 μm/h0.5 for TBCs and 0.354 μm/h0.5 for pure BCs.

  16. Electrical conductivity of the thermal dusty plasma under the conditions of a hybrid plasma environment simulation facility

    Zhukhovitskii, Dmitry I.; Petrov, Oleg F.; Hyde, Truell W.; Herdrich, Georg; Laufer, Rene; Dropmann, Michael; Matthews, Lorin S.

    2015-05-01

    We discuss the inductively heated plasma generator (IPG) facility in application to the generation of the thermal dusty plasma formed by the positively charged dust particles and the electrons emitted by them. We develop a theoretical model for the calculation of plasma electrical conductivity under typical conditions of the IPG. We show that the electrical conductivity of dusty plasma is defined by collisions with the neutral gas molecules and by the electron number density. The latter is calculated in the approximations of an ideal and strongly coupled particle system and in the regime of weak and strong screening of the particle charge. The maximum attainable electron number density and corresponding maximum plasma electrical conductivity prove to be independent of the particle emissivity. Analysis of available experiments is performed, in particular, of our recent experiment with plasma formed by the combustion products of a propane-air mixture and the CeO2 particles injected into it. A good correlation between the theory and experimental data points to the adequacy of our approach. Our main conclusion is that a level of the electrical conductivity due to the thermal ionization of the dust particles is sufficiently high to compete with that of the potassium-doped plasmas.

  17. Simulations of planar non-thermal plasma assisted ignition at atmospheric pressure

    Casey, Tiernan A.; Han, Jie; Belhi, Memdouh; Arias, Paul G.; Bisetti, Fabrizio; Im, Hong G.; Chen, Jyh Yuan

    2016-01-01

    neutrals and ions to the non-thermal electrons. A two-temperature plasma mechanism describing gas phase combustion, excitation of neutral species, and high-energy electron kinetics is employed to account for non-thermal effects. Charged species transported

  18. Non-thermal Plasma Exposure Rapidly Attenuates Bacterial AHL-Dependent Quorum Sensing and Virulence

    Flynn, Padrig B.; Busetti, Alessandro; Wielogorska, Ewa; Chevallier, Olivier P.; Elliott, Christopher T.; Laverty, Garry; Gorman, Sean P.; Graham, William G.; Gilmore, Brendan F.

    2016-01-01

    The antimicrobial activity of atmospheric pressure non-thermal plasma has been exhaustively characterised, however elucidation of the interactions between biomolecules produced and utilised by bacteria and short plasma exposures are required for optimisation and clinical translation of cold plasma technology. This study characterizes the effects of non-thermal plasma exposure on acyl homoserine lactone (AHL)-dependent quorum sensing (QS). Plasma exposure of AHLs reduced the ability of such molecules to elicit a QS response in bacterial reporter strains in a dose-dependent manner. Short exposures (30–60 s) produce of a series of secondary compounds capable of eliciting a QS response, followed by the complete loss of AHL-dependent signalling following longer exposures. UPLC-MS analysis confirmed the time-dependent degradation of AHL molecules and their conversion into a series of by-products. FT-IR analysis of plasma-exposed AHLs highlighted the appearance of an OH group. In vivo assessment of the exposure of AHLs to plasma was examined using a standard in vivo model. Lettuce leaves injected with the rhlI/lasI mutant PAO-MW1 alongside plasma treated N-butyryl-homoserine lactone and n-(3-oxo-dodecanoyl)-homoserine lactone, exhibited marked attenuation of virulence. This study highlights the capacity of atmospheric pressure non-thermal plasma to modify and degrade AHL autoinducers thereby attenuating QS-dependent virulence in P. aeruginosa. PMID:27242335

  19. Thermal-neutron capture by protons accompanied by e+e- pair production

    Rekalo, M.P.

    1985-01-01

    Viewing the deuteron as an elementary particle with unit spin and positive spatial parity, we introduce five electromagnetic form factors (three transverse and two longitudinal) characterizing thermal-neutron capture in the reaction n+p→d+e + +e - . All of the observable characteristics of the process n+p→d+e + +e - involving polarized nucleons are calculated in terms of these form factors. The form factors of the transition n+p→d+γ* (γ* is a virtual photon) are related to the nucleon electromagnetic form factors and the characteristics of the dnp vertex using the relativistic impulse approximation. Here only two form factors (one transverse and one longitudinal) turn out to be leading

  20. Perturbative study in quantum field theory at finite temperature, application to lepton pair production from a quark-gluon plasma

    Altherr, T.

    1989-12-01

    The main topic of this thesis is a perturbative study of Quantum Field Theory at Finite Temperature. The real-time formalism is used throughout this work. We show the cancellation of infrared and mass singularities in the case of the first order QCD corrections to lepton pair production from a quark-gluon plasma. Two methods of calculation are presented and give the same finite result in the limit of vanishing quark mass. These finite terms are analysed and give small corrections in the region of interest for ultra-relativistic heavy ions collisions, except for a threshold factor. Specific techniques for finite temperature calculations are explicited in the case of the fermionic self-energy in QED [fr

  1. Binary collision rates of relativistic thermal plasmas. I Theoretical framework

    Dermer, C. D.

    1985-01-01

    Binary collision rates for arbitrary scattering cross sections are derived in the case of a beam of particles interacting with a Maxwell-Boltzmann (MB) plasma, or in the case of two MB plasmas interacting at generally different temperatures. The expressions are valid for all beam energies and plasma temperatures, from the nonrelativistic to the extreme relativistic limits. The calculated quantities include the reaction rate, the energy exchange rate, and the average rate of change of the squared transverse momentum component of a monoenergetic particle beam as a result of scatterings with particles of a MB plasma. Results are specialized to elastic scattering processes, two-temperature reaction rates, or the cold plasma limit, reproducing previous work.

  2. Characterization of thermal plasmas by laser light scattering

    Snyder, S.C.; Lassahn, G.D.; Reynolds, L.D.; Fincke, J.R.

    1993-01-01

    Characterization of an atmospheric pressure free-burning arc discharge and a plasma jet by lineshape analysis of scattered laser light is described. Unlike emission spectroscopy, this technique provides direct measurement of plasma gas temperature, electron temperature and electron density without the assumption of local thermodynamic equilibrium (LTE). Plasma gas velocity can also be determined from the Doppler shift of the scattered laser light. Radial gas temperature, electron temperature and electron density profiles are presented for an atmospheric pressure argon free-burning arc discharge. These results show a significant departure from LTE in the arc column, contradicting results obtained from emission spectroscopy. Radial gas temperature and gas velocity profiles in the exit plane of a subsonic atmospheric pressure argon plasma jet are also presented. In this case, the results show the plasma jet is close to LTE in the center, but not in the fringes. The velocity profile is parabolic

  3. Numerical study of divertor plasma transport with thermal force due to temperature gradient

    Ohtsu, Shigeki; Tanaka, Satoru; Yamawaki, Michio

    1992-01-01

    A one-dimensional, steady state divertor plasma model is developed in order to study the carbon impurity transport phenomena considering thermal force. The divertor plasma is composed of four regions in terms of momentum transport between hydrogen and carbon impurity: Momentum transferring region, equilibrium region, hydrogen recycling region and carbon recycling region. In the equilibrium region where the friction force is counterbalanced by the thermal force, the localization of carbon impurity occurs. The sufficient condition to avoid the reverse of carbon velocity due to the thermal force is evaluated. (orig.)

  4. Revisiting the thermal effect on shock wave propagation in weakly ionized plasmas

    Zhou, Qianhong; Dong, Zhiwei; Yang, Wei

    2016-01-01

    Many researchers have investigated shock propagation in weakly ionized plasmas and observed the following anomalous effects: shock acceleration, shock recovery, shock weakening, shock spreading, and splitting. It was generally accepted that the thermal effect can explain most of the experimental results. However, little attention was paid to the shock recovery. In this paper, the shock wave propagation in weakly ionized plasmas is studied by fluid simulation. It is found that the shock acceleration, weakening, and splitting appear after it enters the plasma (thermal) region. The shock splits into two parts right after it leaves the thermal region. The distance between the splitted shocks keeps decreasing until they recover to one. This paper can explain a whole set of features of the shock wave propagation in weakly ionized plasmas. It is also found that both the shock curvature and the splitting present the same photoacoustic deflection (PAD) signals, so they cannot be distinguished by the PAD experiments.

  5. Use of residual hydrocarbons treated by Thermal Plasma (recovery of energy by-products)

    Carreno B, J.A.; Pacheco S, J.O.; Ramos F, F.; Cruz A, A.; Duran G, M.

    2001-01-01

    The emergence of new technologies is getting greater importance for the control of pollution. One of them is the destruction of hazardous wastes treated by thermal plasma, which is of special interest for the efficient treatment of the hazardous wastes since the heat generated by thermal plasma is able to destroy the molecular bonds generating solids and gaseous products which do not represent danger for the human being and the environment. The thermal plasma is the suitable technology for treating a wide range of hazardous wastes, including the residual hydrocarbons from the refinement process of petroleum, plasma exceeds the barrier of 3000 Centigrade. The efficiency of the degradation of residues is greater than 99.99%. Toxic emissions are not generated to environment as SO 2 , NO x and CO 2 neither dioxins and furans by being a pyrolysis process. The use of hydrogen as fuel does not generate pollution to environment. (Author)

  6. DC Thermal Plasma Design and Utilization for the Low Density Polyethylene to Diesel Oil Pyrolysis Reaction

    Hossam A. Gabbar

    2017-06-01

    Full Text Available The exponential increase of plastic production produces 100 million tonnes of waste plastics annually which could be converted into hydrocarbon fuels in a thermal cracking process called pyrolysis. In this research work, a direct current (DC thermal plasma circuit is designed and used for conversion of low density polyethylene (LDPE into diesel oil in a laboratory scale pyrolysis reactor. The experimental setup uses a 270 W DC thermal plasma at operating temperatures in the range of 625 °C to 860 °C for a low density polyethylene (LDPE pyrolysis reaction at pressure = −0.95, temperature = 550 °C with τ = 30 min at a constant heating rate of 7.8 °C/min. The experimental setup consists of a vacuum pump, closed system vessel, direct current (DC plasma circuit, and a k-type thermocouple placed a few millimeters from the reactant sample. The hydrocarbon products are condensed to diesel oil and analyzed using flame ionization detector (FID gas chromatography. The analysis shows 87.5% diesel oil, 1,4-dichlorobenzene (Surr, benzene, ethylbenzene and traces of toluene and xylene. The direct current (DC thermal plasma achieves 56.9 wt. % of diesel range oil (DRO, 37.8 wt. % gaseous products and minimal tar production. The direct current (DC thermal plasma shows reliability, better temperature control, and high thermal performance as well as the ability to work for long operation periods.

  7. Properties of thermal air plasma with admixing of copper and carbon

    Fesenko, S; Veklich, A; Boretskij, V; Cressault, Y; Gleizes, A; Teulet, Ph

    2014-01-01

    This paper deals with investigations of air plasma with admixing of copper and carbon. Model plasma source unit with real breaking arc was used for the simulation of real discharges, which can be occurred during sliding of Cu-C composite electrodes on copper wire at electromotive vehicles. The complex technique of plasma property studies is developed. From one hand, the radial profiles of temperature and electron density in plasma of electric arc discharge in air between Cu-C composite and copper electrodes in air flow were measured by optical spectroscopy techniques. From another hand, the radial profiles of electric conductivity of plasma mixture were calculated by solution of energy balance equation. It was assumed that the thermal conductivity of air plasma is not depending on copper or carbon vapor admixtures. The electron density is obtained from electric conductivity profiles by calculation in assumption of local thermodynamic equilibrium in plasma. Computed in such way radial profiles of electron density in plasma of electric arc discharge in air between copper electrodes were compared with experimentally measured profiles. It is concluded that developed techniques of plasma diagnostics can be reasonably used in investigations of thermal plasma with copper and carbon vapors

  8. Non-thermal atmospheric-pressure plasma possible application in wound healing.

    Haertel, Beate; von Woedtke, Thomas; Weltmann, Klaus-Dieter; Lindequist, Ulrike

    2014-11-01

    Non-thermal atmospheric-pressure plasma, also named cold plasma, is defined as a partly ionized gas. Therefore, it cannot be equated with plasma from blood; it is not biological in nature. Non-thermal atmospheric-pressure plasma is a new innovative approach in medicine not only for the treatment of wounds, but with a wide-range of other applications, as e.g. topical treatment of other skin diseases with microbial involvement or treatment of cancer diseases. This review emphasizes plasma effects on wound healing. Non-thermal atmospheric-pressure plasma can support wound healing by its antiseptic effects, by stimulation of proliferation and migration of wound relating skin cells, by activation or inhibition of integrin receptors on the cell surface or by its pro-angiogenic effect. We summarize the effects of plasma on eukaryotic cells, especially on keratinocytes in terms of viability, proliferation, DNA, adhesion molecules and angiogenesis together with the role of reactive oxygen species and other components of plasma. The outcome of first clinical trials regarding wound healing is pointed out.

  9. Radioactive waste combustion-vitrification under arc plasma: thermal and dynamic modelling

    Barthelemy, B.

    2003-06-01

    This thesis concerns the thermal and dynamic modelling for a combustion/vitrification process of surrogate radioactive waste under transferred arc plasma. The writer presents the confinement processes for radioactive waste using arc plasma and the different software used to model theses processes. This is followed by a description of our experimental equipment including a plasma arc reactor and an inductive system allowing the homogenization of glass temperature. A combustion/vitrification test is described. Thermal and material balances were discussed. The temperature fields of plasma arc and the glass frit conductivity are measured. Finally, the writer describes and clarifies the equations solved for the simulations of the electrically plasma arc and the glass melting including the thin layer of glass frit coating the crucible cold walls. The modelling results are presented in the form of spatial distribution of temperature, velocity and voluminal power... (author)

  10. Radioactive waste combustion / vitrification under arc plasma: thermal and dynamic modelling

    Barthelemy, B.

    2003-01-01

    This thesis concerns the thermal and dynamic modelling for a combustion/vitrification process of surrogate radioactive waste under transferred arc plasma. The writer presents the confinement processes for radioactive waste using arc plasma and the different software used to model theses processes. This is followed by a description of our experimental equipment including a plasma arc reactor and an inductive system allowing the homogenization of glass temperature. A combustion/vitrification test is described. Thermal and material balances were discussed. The temperature fields of plasma arc and the glass frit conductivity are measured. Finally, the writer describes and clarifies the equations solved for the simulations of the electrically plasma arc and the glass melting including the thin layer of glass frit coating the crucible cold walls. The modelling results are presented in the form of spatial distribution of temperature, velocity and volume power... (author)

  11. An investigation of non-equilibrium effects in thermal argon plasmas

    Rosado, R.J.

    1981-01-01

    This thesis deals with the study of the validity of the assumption of Local Thermal Equilibrium (LTE) in the description of the parameters of a thermal argon plasma. The aim is twofold. As the studied plasma is close to, but not completely in equilibrium, the author first attempts to obtain a simple description of the plasma in terms of an LTE model in which suitable corrections for the deviations of the plasma parameters from their LTE values is introduced. To this end the plasma parameters are studied by means of a diagnostic method in which the assumption of LTE is not made. The evaluation of the usefulness of this method is the second aim of this thesis. (Auth.)

  12. Propagation of sound and thermal waves in an ionizing-recombining hydrogen plasma: Revision of results

    Di Sigalotti, Leonardo G.; Sira, Eloy; Tremola, Ciro

    2002-01-01

    The propagation of acoustic and thermal waves in a heat conducting, hydrogen plasma, in which photoionization and photorecombination [H + +e - H+hν(χ)] processes are progressing, is re-examined here using linear analysis. The resulting dispersion equation is solved analytically and the results are compared with previous solutions for the same plasma model. In particular, it is found that wave propagation in a slightly and highly ionized hydrogen plasma is affected by crossing between acoustic and thermal modes. At temperatures where the plasma is partially ionized, waves of all frequencies propagate without the occurrence of mode crossing. These results disagree with those reported in previous work, thereby leading to a different physical interpretation of the propagation of small linear disturbances in a conducting, ionizing-recombining, hydrogen plasma

  13. Investigation of non-thermal plasma effects on lung cancer cells within 3D collagen matrices

    Karki, Surya B.; Thapa Gupta, Tripti; Yildirim-Ayan, Eda; Eisenmann, Kathryn M.; Ayan, Halim

    2017-08-01

    Recent breakthroughs in plasma medicine have identified a potential application for the non-thermal plasma in cancer therapy. Most studies on the effects of non-thermal plasma on cancer cells have used traditional two-dimensional (2D) monolayer cell culture. However, very few studies are conducted employing non-thermal plasma in animal models. Two dimensional models do not fully mimic the three-dimensional (3D) tumor microenvironment and animal models are expensive and time-consuming. Therefore, we used 3D collagen matrices that closely resemble the native geometry of cancer tissues and provide more physiologically relevant results than 2D models, while providing a more cost effective and efficient precursor to animal studies. We previously demonstrated a role for non-thermal plasma application in promoting apoptotic cell death and reducing the viability of A549 lung adenocarcinoma epithelial cells cultured upon 2D matrices. In this study, we wished to determine the efficacy of non-thermal plasma application in driving apoptotic cell death of A549 lung cancer cells encapsulated within a 3D collagen matrix. The percentage of apoptosis increased as treatment time increased and was time dependent. In addition, the anti-viability effect of plasma was demonstrated. Twenty-four hours post-plasma treatment, 38% and 99% of cell death occurred with shortest (15 s) and longest treatment time (120 s) respectively at the plasma-treated region. We found that plasma has a greater effect on the viability of A549 lung cancer cells on the superficial surface of 3D matrices and has diminishing effects as it penetrates the 3D matrix. We also identified the nitrogen and oxygen species generated by plasma and characterized their penetration in vertical and lateral directions within the 3D matrix from the center of the plasma-treated region. Therefore, the utility of non-thermal dielectric barrier discharge plasma in driving apoptosis and reducing the viability of lung cancer cells

  14. Investigation of non-thermal plasma effects on lung cancer cells within 3D collagen matrices

    Karki, Surya B; Gupta, Tripti Thapa; Yildirim-Ayan, Eda; Ayan, Halim; Eisenmann, Kathryn M

    2017-01-01

    Recent breakthroughs in plasma medicine have identified a potential application for the non-thermal plasma in cancer therapy. Most studies on the effects of non-thermal plasma on cancer cells have used traditional two-dimensional (2D) monolayer cell culture. However, very few studies are conducted employing non-thermal plasma in animal models. Two dimensional models do not fully mimic the three-dimensional (3D) tumor microenvironment and animal models are expensive and time-consuming. Therefore, we used 3D collagen matrices that closely resemble the native geometry of cancer tissues and provide more physiologically relevant results than 2D models, while providing a more cost effective and efficient precursor to animal studies. We previously demonstrated a role for non-thermal plasma application in promoting apoptotic cell death and reducing the viability of A549 lung adenocarcinoma epithelial cells cultured upon 2D matrices. In this study, we wished to determine the efficacy of non-thermal plasma application in driving apoptotic cell death of A549 lung cancer cells encapsulated within a 3D collagen matrix. The percentage of apoptosis increased as treatment time increased and was time dependent. In addition, the anti-viability effect of plasma was demonstrated. Twenty-four hours post-plasma treatment, 38% and 99% of cell death occurred with shortest (15 s) and longest treatment time (120 s) respectively at the plasma-treated region. We found that plasma has a greater effect on the viability of A549 lung cancer cells on the superficial surface of 3D matrices and has diminishing effects as it penetrates the 3D matrix. We also identified the nitrogen and oxygen species generated by plasma and characterized their penetration in vertical and lateral directions within the 3D matrix from the center of the plasma-treated region. Therefore, the utility of non-thermal dielectric barrier discharge plasma in driving apoptosis and reducing the viability of lung cancer cells

  15. Collisional Thermalization in Strongly Coupled Ultracold Neutral Plasmas

    2017-01-25

    calculated collisions rates in a strongly coupled plasma. From Bannasch et al., PRL 109, 185008 (2012). DISTRIBUTION A: Distribution approved for public...applicability to other plasmas.) We use a Green- Kubo relation to extract the diffusion constant from our measurements of the relaxation towards...strongly coupled systems. Our measurements (data symbols) agree with numerical calculations (solid lines) from J. Daligault, PRL 108, 225004 (2012

  16. Plasma effects on the passive external thermal control coating of Space Station Freedom

    Carruth, Ralph, Jr.; Vaughn, Jason A.; Holt, James M.; Werp, Richard; Sudduth, Richard D.

    1992-01-01

    The current baseline chromic acid anodized thermal control coating on 6061-T6 aluminum meteoroid debris (M/D) shields for SSF has been evaluated. The degradation of the solar absorptance, alpha, and the thermal emittance, epsilon, of chromic acid anodized aluminum due to dielectric breakdown in plasma was measured to predict the on-orbit lifetime of the SSF M/D shields. The lifetime of the thermal control coating was based on the surface temperatures achieved with degradation of the thermal control properties, alpha and epsilon. The temperatures of each M/D shield from first element launch (FEL) through FEL+15 years were analyzed. It is shown that the baseline thermal control coating cannot withstand the -140 V potential between the conductive structure of the SSF and the current plasma environment.

  17. Thermal shock fracture of graphite armor plate under the heat load of plasma disruption

    Horie, Tomoyoshi; Seki, Masahiro; Ohmori, Junji

    1989-01-01

    Experiments on the thermal shock brittle fracture of graphite plates were performed. Thermal loading which simulated a plasma disruption was produced by an electron beam facility. Pre-cracks produced on the surface propagated to the inside of the specimen even if the thermal stress on the surface was compressive. Two mechanisms are possible to produce tensile stress around the crack tip under thermal shock conditions. Temperature, thermal stress, and the stress intensity factor for the specimen were analyzed based on the finite element method for various heating conditions. The trend of experimental results under the asymmetric heating agrees qualitatively with the analytical results. This phenomenon is important for the design of plasma facing components made of graphite. Establishment of a lifetime prediction procedure including fatigue, fatigue crack growth, and brittle fracture is needed for graphite armors. (orig.)

  18. 2-Methoxypyridine as a Thymidine Mimic in Watson-Crick Base Pairs of DNA and PNA: Synthesis, Thermal Stability, and NMR Structural Studies.

    Novosjolova, Irina; Kennedy, Scott D; Rozners, Eriks

    2017-11-02

    The development of nucleic acid base-pair analogues that use new modes of molecular recognition is important both for fundamental research and practical applications. The goal of this study was to evaluate 2-methoxypyridine as a cationic thymidine mimic in the A-T base pair. The hypothesis was that including protonation in the Watson-Crick base pairing scheme would enhance the thermal stability of the DNA double helix without compromising the sequence selectivity. DNA and peptide nucleic acid (PNA) sequences containing the new 2-methoxypyridine nucleobase (P) were synthesized and studied by using UV thermal melting and NMR spectroscopy. Introduction of P nucleobase caused a loss of thermal stability of ≈10 °C in DNA-DNA duplexes and ≈20 °C in PNA-DNA duplexes over a range of mildly acidic to neutral pH. Despite the decrease in thermal stability, the NMR structural studies showed that P-A formed the expected protonated base pair at pH 4.3. Our study demonstrates the feasibility of cationic unnatural base pairs; however, future optimization of such analogues will be required. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Effects of plasma jet parameters, ionization, thermal conduction, and radiation on stagnation conditions of an imploding plasma liner

    Stanic, Milos

    The disciplines of High Energy Density Physics (HEDP) and Inertial Confinement Fusion (ICF) are characterized by hypervelocity implosions and strong shocks. The Plasma Liner Experiment (PLX) is focused on reaching HEDP and/or ICF relevant regimes in excess of 1 Mbar peak pressure by the merging and implosion of discrete plasma jets, as a potentially efficient path towards these extreme conditions in a laboratory. In this work we have presented the first 3D simulations of plasma liner, formation, and implosion by the merging of discrete plasma jets in which ionization, thermal conduction, and radiation are all included in the physics model. The study was conducted by utilizing a smoothed particle hydrodynamics code (SPHC) and was a part of the plasma liner experiment (PLX). The salient physics processes of liner formation and implosion are studied, namely vacuum propagation of plasma jets, merging of the jets (liner forming), implosion (liner collapsing), stagnation (peak pressure), and expansion (rarefaction wave disassembling the target). Radiative transport was found to significantly reduce the temperature of the liner during implosion, thus reducing the thermal expansion rates and leaving more pronounced gradients in the plasma liner during the implosion compared with ideal hydrodynamic simulations. These pronounced gradients lead to a greater sensitivity of initial jet geometry and symmetry on peak pressures obtained. Accounting for ionization and transport, many cases gave higher peak pressures than the ideal hydrodynamic simulations. Scaling laws were developed accordingly, creating a non-dimensional parameter space in which performance of an imploding plasma jet liner can be estimated. It is shown that HEDP regimes could be reached with ≈ 5 MJ of liner energy, which would translate to roughly 10 to 20 MJ of stored (capacitor) energy. This is a potentially significant improvement over the currently available means via ICF of achieving HEDP and nuclear

  20. Non-thermal dielectric barrier discharge plasma induces angiogenesis through reactive oxygen species.

    Arjunan, Krishna Priya; Friedman, Gary; Fridman, Alexander; Clyne, Alisa Morss

    2012-01-07

    Vascularization plays a key role in processes such as wound healing and tissue engineering. Non-thermal plasma, which primarily produces reactive oxygen species (ROS), has recently emerged as an efficient tool in medical applications including blood coagulation, sterilization and malignant cell apoptosis. Liquids and porcine aortic endothelial cells were treated with a non-thermal dielectric barrier discharge plasma in vitro. Plasma treatment of phosphate-buffered saline (PBS) and serum-free medium increased ROS concentration in a dose-dependent manner, with a higher concentration observed in serum-free medium compared with PBS. Species concentration inside cells peaked 1 h after treatment, followed by a decrease 3 h post treatment. Endothelial cells treated with a plasma dose of 4.2 J cm(-2) had 1.7 times more cells than untreated samples 5 days after plasma treatment. The 4.2 J cm(-2) plasma dose increased two-dimensional migration distance by 40 per cent compared with untreated control, while the number of cells that migrated through a three-dimensional collagen gel increased by 15 per cent. Tube formation was also enhanced by plasma treatment, with tube lengths in plasma-treated samples measuring 2.6 times longer than control samples. A fibroblast growth factor-2 (FGF-2) neutralizing antibody and ROS scavengers abrogated these angiogenic effects. These data indicate that plasma enhanced proliferation, migration and tube formation is due to FGF-2 release induced by plasma-produced ROS. Non-thermal plasma may be used as a potential tool for applying ROS in precise doses to enhance vascularization.

  1. Ion thermal conductivity for a pure tokamak plasma

    Bolton, C.W. III.

    1981-06-01

    The ion thermal conductivity is calculated for a wide range of aspect ratios and collision frequencies. The calculation is done by solving the drift kinetic equation, with a model collision operator, using a finite element method, and then calculating the energy weighted friction force to determine the heat flux. The thermal conductivity, determined from the heat flux, is then curve fitted to analytic formulas. These formulas allow the conductivity to be calculated at all collision frequencies and aspect ratios down to about 3

  2. Thermal efficiency of a non-transferred thermal plasma cannon; Eficiencia termica de un canon de plasma termico no-transferido

    Mercado, A; Cota, G; Merlo, L; Pacheco, J; Pena, R; Cruz, A [Instituto nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1997-07-01

    This work shows a thermal efficiency research ({nu}) for a plasma torch in d.c. which was carried out through the realization of an energy balance around the system under consideration. The plasma torch is manufactured in copper with a tungsten incrustations in cathode. The gas used was argon and the gas fluxes were at the rank of 10 and 40 lt/min to the total pressure of 1.2 bar (1.1 atm). With these conditions it was worked with electric currents at the rank of 40 and 180 A. The data were collected through a data acquisition card which was programmed in Windows environment. (Author)

  3. Thermal de-isolation of silicon microstructures in a plasma etching environment

    Lee, Yong-Seok; Jang, Yun-Ho; Kim, Yong-Kweon; Kim, Jung-Mu

    2013-01-01

    This paper presents a theoretical and experimental strategy for thermal de-isolation of silicon microstructures during a plasma etching process. Heat sinking blocks and thin metal layers are implemented around a thermally isolated mass to avoid severe spring width losses by a steep temperature rise. Thermal de-isolation significantly reduces the fabrication errors from −51.0% to −9.0% and from −39.5% to −6.7% for spring widths and resonant frequencies, respectively. Thermal de-isolation also reduces the standard deviation of resonant frequencies from 8.7% to 1.5% across a wafer, which clearly demonstrates the proposed method. (paper)

  4. Thermal catastrophe in the plasma sheet boundary layer

    Smith, R.A.; Goertz, C.K.; Grossmann, W.

    1986-01-01

    This letter presents a first step towards a substorm model including particle heating and transport in the plasma sheet boundary layer (PSBL). The heating mechanism discussed is resonant absorption of Alfven waves. For some assumed MHD perturbation incident from the tail lobes onto the plasma sheet, the local heating rate in the PSBL has the form of a resonance function of the one-fluid plasma temperature. Balancing the local heating by convective transport of the heated plasma toward the central plasma sheet, and ''equation of state'' is found for the steady-state PSBL whose solution has the form of a mathematical catastrophe: at a critical value of a parameter containing the incident power flux, the local density, and the convection velocity, the equilibrium temperature jumps discontinuously. Associating this temperature increase with the abrupt onset of the substorm expansion phase, the catastrophe model indicates at least three ways in which the onset may be triggered. Several other consequences related to substorm dynamics are suggested by the simple catastrophe model

  5. Studying the non-thermal plasma jet characteristics and application on bacterial decontamination

    Al-rawaf, Ali F.; Fuliful, Fadhil Khaddam; Khalaf, Mohammed K.; Oudah, Husham. K.

    2018-04-01

    Non-thermal atmospheric-pressure plasma jet represents an excellent approach for the decontamination of bacteria. In this paper, we want to improve and characterize a non-thermal plasma jet to employ it in processes of sterilization. The electrical characteristics was studied to describe the discharge of the plasma jet and the development of plasma plume has been characterized as a function of helium flow rate. Optical emission spectroscopy was employed to detect the active species inside the plasma plume. The inactivation efficiency of non-thermal plasma jet was evaluated against Staphylococcus aureus bacteria by measuring the diameter of inhibition zone and the number of surviving cells. The results presented that the plasma plume temperature was lower than 34° C at a flow rate of 4 slm, which will not cause damage to living tissues. The diameter of inhibition zone is directly extended with increased exposure time. We confirmed that the inactivation mechanism was unaffected by UV irradiation. In addition, we concluded that the major reasons for the inactivation process of bacteria is because of the action of the reactive oxygen and nitrogen species which formed from ambient air, while the charged particles played a minor role in the inactivation process.

  6. Thermal plasma synthesis of transition metal nitrides and alloys

    Ronsheim, P.; Christensen, A.N.; Mazza, A.

    1981-01-01

    Applications of arc plasma processing to high-temperature chemistry of Group V nitrides and Si and Ge alloys are studied. The transition metal nitrides 4f-VN, 4f-NbN, and 4f-TaN are directly synthesized in a dc argon-nitrogen plasma from powders of the metals. A large excess of N 2 is required to form stoichiometric 4f-VN, while the Nb and Ta can only be synthesized with a substoichiometric N content. In a dc argon plasma the alloys V 3 Si, VSi 2 , NbSi 2 , NbGe 2 , Cr 3 Si, and Mo 3 Si are obtained from powder mixtures of the corresponding elements. The compounds are identified by x-ray diffraction patterns and particle shape and size are studied by electron microscopy

  7. Periodic pulling of the drift instability in a thermal plasma

    Abrams, R.H. Jr.

    1970-01-01

    The primary objective of this thesis is to show that a mode of oscillation in a plasma can be represented by a van der Pol oscillator. The results of an experiment performed on a drift wave in a Q-machine are interpreted in terms of a mechanism developed by Lashinsky. The mechanism, called periodic pulling, predicts a specific kind of spectrum for certain experimental conditions when a van der Pol oscillator is perturbed by a small signal. The observed spectrum, along with other observations, lends credence to the van der Pol oscillator model of a plasma mode

  8. Advanced oxidation technology for H2S odor gas using non-thermal plasma

    Tao, ZHU; Ruonan, WANG; Wenjing, BIAN; Yang, CHEN; Weidong, JING

    2018-05-01

    Non-thermal plasma technology is a new type of odor treatment processing. We deal with H2S from waste gas emission using non-thermal plasma generated by dielectric barrier discharge. On the basis of two criteria, removal efficiency and absolute removal amount, we deeply investigate the changes in electrical parameters and process parameters, and the reaction process of the influence of ozone on H2S gas removal. The experimental results show that H2S removal efficiency is proportional to the voltage, frequency, power, residence time and energy efficiency, while it is inversely proportional to the initial concentration of H2S gas, and ozone concentration. This study lays the foundations of non-thermal plasma technology for further commercial application.

  9. Spheroidization of molybdenum powder by radio frequency thermal plasma

    Liu, Xiao-ping; Wang, Kuai-she; Hu, Ping; Chen, Qiang; Volinsky, Alex A.

    2015-11-01

    To control the morphology and particle size of dense spherical molybdenum powder prepared by radio frequency (RF) plasma from irregular molybdenum powder as a precursor, plasma process parameters were optimized in this paper. The effects of the carrier gas flow rate and molybdenum powder feeding rate on the shape and size of the final products were studied. The molybdenum powder morphology was examined using high-resolution scanning electron microscopy. The powder phases were analyzed by X-ray diffraction. The tap density and apparent density of the molybdenum powder were investigated using a Hall flow meter and a Scott volumeter. The optimal process parameters for the spherical molybdenum powder preparation are 50 g/min powder feeding rate and 0.6 m3/h carrier gas rate. In addition, pure spherical molybdenum powder can be obtained from irregular powder, and the tap density is enhanced after plasma processing. The average size is reduced from 72 to 62 µm, and the tap density is increased from 2.7 to 6.2 g/cm3. Therefore, RF plasma is a promising method for the preparation of high-density and high-purity spherical powders.

  10. Chemical and physical reactions under thermal plasmas conditions

    Fauchais, P.; Vardelle, A.; Vardelle, M.; Coudert, J.F.

    1987-01-01

    Basic understanding of the involved phenomena lags far behind industrial development that requires now a better knowledge of the phenomena to achieve a better control of the process allowing to improve the quality of the products. Thus the authors try to precise what is their actual knowledge in the fields of: plasma generators design; plasma flow models with the following key points: laminar or turbulent flow, heat transfer to walls, 2D or 3D models, non equilibrium effects, mixing problems when chemical reactions are to be taken into account with very fast kinetics, electrode regions, data for transport properties and kinetic rates; nucleation problems; plasma flow characteristics measurements: temperature or temperatures and population of excited states (automatized emission spectroscopy, LIF, CARS) as well as flow velocity (LDA with small particles, Doppler effects...); plasma and particles momentum and heat transfer either with models taking into account particles size and injection velocity distributions, heat propagation, vaporization, Kundsen effect, turbulences ... or with measurements: particles velocity and flux distributions (Laser Anemometry) as well as surface temperature distributions (two colour pyrometry in flight statistical or not)

  11. Microscopic electrical conductivity of nanodiamonds after thermal and plasma treatments

    Čermák, Jan; Kozak, Halyna; Stehlík, Štěpán; Švrček, V.; Pichot, V.; Spitzer, D.; Kromka, Alexander; Rezek, Bohuslav

    2016-01-01

    Roč. 1, č. 16 (2016), s. 1105-1111 ISSN 2059-8521 R&D Projects: GA ČR GA15-01809S Institutional support: RVO:68378271 Keywords : atomic force microscopy * conductive AFM * diamond * nanoparticles * plasma Subject RIV: BM - Solid Matter Physics ; Magnetism

  12. Inactivation of human pathogenic dermatophytes by non-thermal plasma

    Scholtz, V.; Soušková, H.; Hubka, Vít; Švarcová, M.; Julák, J.

    2015-01-01

    Roč. 119, DEC 2015 (2015), s. 53-58 ISSN 0167-7012 R&D Projects: GA MŠk(CZ) ED1.1.00/02.0109 Institutional support: RVO:61388971 Keywords : Corona discharge * Cometary discharge * Decontamination of surfaces Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.857, year: 2015

  13. Polybrominated diphenyl ethers in paired samples of maternal and umbilical cord blood plasma and associations with house dust in a Danish cohort

    Frederiksen, Marie; Thomsen, Cathrine; Frøshaug, May

    2010-01-01

    determined in placental tissue from the same individuals, and the relationship with the external exposure from house dust from the participants' homes was explored. Samples of maternal and umbilical cord plasma from a cohort of 51 pregnant women from the Copenhagen area were collected. Paired maternal...... and umbilical cord plasma were analysed for BDE-28, 37, 47, 85, 99, 100, 119, 138, 153, 154, 183, 209 and the brominated biphenyl BB-153 using automated SPE extraction and GC-HRMS for the tri- to hepta-BDEs and GC-LRMS (ECNI) for BDE-209. PBDEs were detected in all maternal and umbilical cord plasma samples...

  14. Experimental investigation of thermal conduction and related phenomena in a laser heated plasma

    Gray, D.R.

    1979-02-01

    Thermal conduction in plasmas is of major importance especially in controlled nuclear fusion studies. Direct measurements are rare. When the temperature gradient in a plasma becomes large enough classical thermal conduction (Heat flux q = -kΔT) no longer applies and it is thought that q is limited to some fraction of the free streaming limit qsub(m). The main experiment is the heating of a z-pinch plasma by a fast rising, intense carbon dioxide laser pulse. Electron temperature and density in time and space are diagnosed by ruby laser scattering. The profiles obtained were consistent with a flux limited to approximately 3% of the free streaming limit. Ion acoustic turbulence is observed along the temperature gradient. It is shown that the observed turbulence level is consistent with the heat flux limitation. At electron densities > 10 17 cm -3 backscattered light is observed from the plasma whose growth rate implies that it is Brillouin scattered. (author)

  15. Plasma spheroidization of iron powders in a non-transferred DC thermal plasma jet

    Kumar, S.; Selvarajan, V.

    2008-01-01

    In this paper, the results of plasma spheroidization of iron powders using a DC non-transferred plasma spray torch are presented. The morphology of the processed powders was characterized through scanning electron microscopy (SEM) and optical microscopy (OM). The percentages of spheroidized powders were calculated by the shape factors such as the Irregularity Parameter (IP) and Roundness (RN). A maximum of 83% of spheroidization can be achieved. The spheroidization results are compared with the theoretical estimation and they are found to be in good agreement. The phase composition of the spheroidized powder was analyzed by XRD. The effect of plasma jet temperature and plasma gas flow rate on spheroidization is discussed. At low plasma gas flow rates and at high plasma jet temperatures, the percentage of spheroidization is high

  16. Research on electric and thermal characteristics of plasma torch based on similarity theory

    Cheng Changming; Tang Deli; Lan Wei

    2007-01-01

    Configuration and working principle of a DC non-transferred plasma torch have been introduced. Based on similarity theory, connections between the electric-thermal characteristics and operational parameter such as flowing gas rate and arc power have been investigated. Calculation and experiment are compared. The results indicate that the calculation results are in agreement with experimental ones. The formulas can be used for plasma torch improvement and optimization. (authors)

  17. Non-thermal Plasma Activates Human Keratinocytes by Stimulation of Antioxidant and Phase II Pathways

    Schmidt, Anke; Dietrich, Stephan; Steuer, Anna; Weltmann, Klaus-Dieter; von Woedtke, Thomas; Masur, Kai; Wende, Kristian

    2015-01-01

    Non-thermal atmospheric pressure plasma provides a novel therapeutic opportunity to control redox-based processes, e.g. wound healing, cancer, and inflammatory diseases. By spatial and time-resolved delivery of reactive oxygen and nitrogen species, it allows stimulation or inhibition of cellular processes in biological systems. Our data show that both gene and protein expression is highly affected by non-thermal plasma. Nuclear factor erythroid-related factor 2 (NRF2) and phase II enzyme pathway components were found to act as key controllers orchestrating the cellular response in keratinocytes. Additionally, glutathione metabolism, which is a marker for NRF2-related signaling events, was affected. Among the most robustly increased genes and proteins, heme oxygenase 1, NADPH-quinone oxidoreductase 1, and growth factors were found. The roles of NRF2 targets, investigated by siRNA silencing, revealed that NRF2 acts as an important switch for sensing oxidative stress events. Moreover, the influence of non-thermal plasma on the NRF2 pathway prepares cells against exogenic noxae and increases their resilience against oxidative species. Via paracrine mechanisms, distant cells benefit from cell-cell communication. The finding that non-thermal plasma triggers hormesis-like processes in keratinocytes facilitates the understanding of plasma-tissue interaction and its clinical application. PMID:25589789

  18. Preliminary degradation process study of infectious biological waste in a 5 k W thermal plasma equipment

    Xochihua S M, M.C.

    1997-01-01

    This work is a preliminary study of infectious biological waste degradation process by thermal plasma and was made in Thermal Plasma Applications Laboratory of Environmental Studies Department of the National Institute of Nuclear Research (ININ). Infectious biological waste degradation process is realized by using samples such polyethylene, cotton, glass, etc., but the present study scope is to analyze polyethylene degradation process with mass and energy balances involved. Degradation method is realized as follow: a polyethylene sample is put in an appropriated crucible localized inside a pyrolysis reactor chamber, the plasma jet is projected to the sample, by the pyrolysis phenomena the sample is degraded into its constitutive particles: carbon and hydrogen. Air was utilized as a recombination gas in order to obtain the higher percent of CO 2 if amount of O 2 is greater in the recombination gas, the CO generation is reduced. The effluent gases of exhaust pyrolysis reactor through are passed through a heat exchanger to get cooled gases, the temperature water used is 15 Centigrade degrees. Finally the gases was tried into absorption tower with water as an absorbent fluid. Thermal plasma degradation process is a very promising technology, but is necessary to develop engineering process area to avail all advantages of thermal plasma. (Author)

  19. Low temperature synthesis of silicon quantum dots with plasma chemistry control in dual frequency non-thermal plasmas.

    Sahu, Bibhuti Bhusan; Yin, Yongyi; Han, Jeon Geon; Shiratani, Masaharu

    2016-06-21

    The advanced materials process by non-thermal plasmas with a high plasma density allows the synthesis of small-to-big sized Si quantum dots by combining low-temperature deposition with superior crystalline quality in the background of an amorphous hydrogenated silicon nitride matrix. Here, we make quantum dot thin films in a reactive mixture of ammonia/silane/hydrogen utilizing dual-frequency capacitively coupled plasmas with high atomic hydrogen and nitrogen radical densities. Systematic data analysis using different film and plasma characterization tools reveals that the quantum dots with different sizes exhibit size dependent film properties, which are sensitively dependent on plasma characteristics. These films exhibit intense photoluminescence in the visible range with violet to orange colors and with narrow to broad widths (∼0.3-0.9 eV). The observed luminescence behavior can come from the quantum confinement effect, quasi-direct band-to-band recombination, and variation of atomic hydrogen and nitrogen radicals in the film growth network. The high luminescence yields in the visible range of the spectrum and size-tunable low-temperature synthesis with plasma and radical control make these quantum dot films good candidates for light emitting applications.

  20. Enhanced active aluminum content and thermal behaviour of nano-aluminum particles passivated during synthesis using thermal plasma route

    Mathe, Vikas L.; Varma, Vijay; Raut, Suyog; Nandi, Amiya Kumar; Pant, Arti; Prasanth, Hima; Pandey, R.K.; Bhoraskar, Sudha V.; Das, Asoka K.

    2016-01-01

    Graphical abstract: - Highlights: • Synthesis of nano crystalline Al (nAl) using DC thermal plasma reactor. • In situ passivation of nAl by palmitic acid and air. • Enhanced active aluminum content obtained for palmitic acid passivated nAl. • Palmitic acid passivated nAl are quite stable in humid atmospheres. - Abstract: Here, we report synthesis and in situ passivation of aluminum nanoparticles using thermal plasma reactor. Both air and palmitc acid passivation was carried out during the synthesis in the thermal plasma reactor. The passivated nanoparticles have been characterized for their structural and morphological properties using X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques. In order to understand nature of passivation vibrational spectroscopic analysis have been carried out. The enhancement in active aluminum content and shelf life for a palmitic acid passivated nano-aluminum particles in comparison to the air passivated samples and commercially available nano Al powder (ALEX) has been observed. Thermo-gravimetric analysis was used to estimate active aluminum content of all the samples under investigation. In addition cerimetric back titration method was also used to estimate AAC and the shelf life of passivated aluminum particles. Structural, microstructural and thermogravomateric analysis of four year aged passivated sample also depicts effectiveness of palmitic acid passivation.

  1. Enhanced active aluminum content and thermal behaviour of nano-aluminum particles passivated during synthesis using thermal plasma route

    Mathe, Vikas L., E-mail: vlmathe@physics.unipune.ac.in [Department of Physics, Savitribai Phule Pune University, Pune 411007, Maharashtra (India); Varma, Vijay; Raut, Suyog [Department of Physics, Savitribai Phule Pune University, Pune 411007, Maharashtra (India); Nandi, Amiya Kumar; Pant, Arti; Prasanth, Hima; Pandey, R.K. [High Energy Materials Research Lab, Sutarwadi, Pune 411021, Maharashtra (India); Bhoraskar, Sudha V. [Department of Physics, Savitribai Phule Pune University, Pune 411007, Maharashtra (India); Das, Asoka K. [Utkal University, VaniVihar, Bhubaneswar, Odisha 751004 (India)

    2016-04-15

    Graphical abstract: - Highlights: • Synthesis of nano crystalline Al (nAl) using DC thermal plasma reactor. • In situ passivation of nAl by palmitic acid and air. • Enhanced active aluminum content obtained for palmitic acid passivated nAl. • Palmitic acid passivated nAl are quite stable in humid atmospheres. - Abstract: Here, we report synthesis and in situ passivation of aluminum nanoparticles using thermal plasma reactor. Both air and palmitc acid passivation was carried out during the synthesis in the thermal plasma reactor. The passivated nanoparticles have been characterized for their structural and morphological properties using X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques. In order to understand nature of passivation vibrational spectroscopic analysis have been carried out. The enhancement in active aluminum content and shelf life for a palmitic acid passivated nano-aluminum particles in comparison to the air passivated samples and commercially available nano Al powder (ALEX) has been observed. Thermo-gravimetric analysis was used to estimate active aluminum content of all the samples under investigation. In addition cerimetric back titration method was also used to estimate AAC and the shelf life of passivated aluminum particles. Structural, microstructural and thermogravomateric analysis of four year aged passivated sample also depicts effectiveness of palmitic acid passivation.

  2. Thermal plasma treatment of stormwater sediments: comparison between DC non-transferred and partially transferred arc plasma.

    Li, O L; Guo, Y; Chang, J S; Saito, N

    2015-01-01

    The disposal of enormous amount of stormwater sediments becomes an emerging worldwide problem. Stormwater sediments are contaminated by heavy metals, phosphorus, trace organic and hydrocarbons, and cannot be disposed without treatment. Thermal plasma decontamination technology offers a high decomposition rate in a wide range of toxic organic compound and immobilization of heavy metal. In this study, we compared the treatment results between two different modes of thermal plasma: (1) a non-transferred direct current (DC) mode and (2) a partial DC-transferred mode. The reductions of total organic carbon (TOC) were, respectively, 25% and 80% for non-transferred and partially transferred plasma, respectively. Most of the toxic organic compounds were converted majorly to CxHy. In the gaseous emission, the accumulated CxHy, CO, NO and H2S were significantly higher in partially transferred mode than in non-transferred mode. The solid analysis demonstrated that the concentrations of Ca and Fe were enriched by 500% and 40%, respectively. New chemical compositions such as KAlSi3O8, Fe3O4, NaCl and CaSO4 were formed after treatment in partially DC-transferred mode. The power inputs were 1 and 10 kW, respectively, for non-transferred DC mode and a partially DC-transferred mode. With a lower energy input, non-transferred plasma treatment can be used for decontamination of sediments with low TOC and metal concentration. Meanwhile, partially transferred thermal plasma with higher energy input is suitable for treating sediments with high TOC percentage and volatile metal concentration. The organic compounds are converted into valuable gaseous products which can be recycled as an energy source.

  3. Self-consistent Langmuir waves in resonantly driven thermal plasmas

    Lindberg, R. R.; Charman, A. E.; Wurtele, J. S.

    2007-12-01

    The longitudinal dynamics of a resonantly driven Langmuir wave are analyzed in the limit that the growth of the electrostatic wave is slow compared to the bounce frequency. Using simple physical arguments, the nonlinear distribution function is shown to be nearly invariant in the canonical particle action, provided both a spatially uniform term and higher-order spatial harmonics are included along with the fundamental in the longitudinal electric field. Requirements of self-consistency with the electrostatic potential yield the basic properties of the nonlinear distribution function, including a frequency shift that agrees closely with driven, electrostatic particle simulations over a range of temperatures. This extends earlier work on nonlinear Langmuir waves by Morales and O'Neil [G. J. Morales and T. M. O'Neil, Phys. Rev. Lett. 28, 417 (1972)] and Dewar [R. L. Dewar, Phys. Plasmas 15, 712 (1972)], and could form the basis of a reduced kinetic treatment of plasma dynamics for accelerator applications or Raman backscatter.

  4. Self-consistent Langmuir waves in resonantly driven thermal plasmas

    Lindberg, R. R.; Charman, A. E.; Wurtele, J. S.

    2007-01-01

    The longitudinal dynamics of a resonantly driven Langmuir wave are analyzed in the limit that the growth of the electrostatic wave is slow compared to the bounce frequency. Using simple physical arguments, the nonlinear distribution function is shown to be nearly invariant in the canonical particle action, provided both a spatially uniform term and higher-order spatial harmonics are included along with the fundamental in the longitudinal electric field. Requirements of self-consistency with the electrostatic potential yield the basic properties of the nonlinear distribution function, including a frequency shift that agrees closely with driven, electrostatic particle simulations over a range of temperatures. This extends earlier work on nonlinear Langmuir waves by Morales and O'Neil [G. J. Morales and T. M. O'Neil, Phys. Rev. Lett. 28, 417 (1972)] and Dewar [R. L. Dewar, Phys. Plasmas 15, 712 (1972)], and could form the basis of a reduced kinetic treatment of plasma dynamics for accelerator applications or Raman backscatter

  5. Maximum thermal energy density in magnetically confined plasmas

    Coppi, B.

    1977-01-01

    The consequences of the limiting value of β that follows from analyzing the onset of high temperature ballooning modes is examined in high temperature regimes where the ideal MHD approximation is not strictly valid and for finite-β configurations exhibiting the main features of those that are obtained by magnetic flux conservation. These modes are localized over periodically space intervals of a given magnetic field line and are driven by the combined effects of finite plasma pressure and the locally unfavorable magnetic curvature. The effects of finite β, insofar as they shorten the effective connection length, steepen the pressure gradient, and influence the magnetic well dug by the plasma, are studied using a model dispersion relation. 14 references

  6. Investigation of non thermal effects from the Dα line wings in edge plasmas

    Marandet, Y.; Godbert-Mouret, L.; Koubiti, M.; Stamm, R.; Capes, H.; Guirlet, R.

    2002-01-01

    The far wings of intense Dα lines measured at the edge of the Tore Supra Tokamak are found to exhibit a power-law behavior. The characteristic exponent is not far from two. Since the low density rules out thermal Stark broadening, we discuss non thermal effects which may arise from the edge plasma drift-wave turbulence. We suggest that both the Stark and the Doppler profile could be affected by the turbulence

  7. In-situ observations of flux ropes formed in association with a pair of spiral nulls in magnetotail plasmas

    Guo, Ruilong; Xie, Lun; He, Jiansen [School of Earth and Space Sciences, Peking University, Beijing 100871 (China); Pu, Zuyin; Fu, Suiyan [School of Earth and Space Sciences, Peking University, Beijing 100871 (China); PKU/UCLA Joint Research Institute in Science and Engineering, Peking University, Beijing (China); Chen, Li-Jen [NASA Goddard Space Flight Center, Greenbelt, Maryland 20771 (United States); Wang, Xiaogang [Harbin Institute of Technology, Harbin 150001 (China); Dunlop, Malcolm [School of Astronautics, Beihang University, Beijing 100191 (China); RAL Space, Rutherford Appleton Laboratory, STFC, Didcot OX11 0QX (United Kingdom); Bogdanova, Yulia V. [RAL Space, Rutherford Appleton Laboratory, STFC, Didcot OX11 0QX (United Kingdom); Yao, Zhonghua; Fazakerley, Andrew N. [UCL Mullard Space Science Laboratory, Dorking RH5 6NT (United Kingdom); Xiao, Chijie [School of Physics, Peking University, Beijing 100871 (China)

    2016-05-15

    Signatures of secondary islands are frequently observed in the magnetic reconnection regions of magnetotail plasmas. In this paper, magnetic structures with the secondary-island signatures observed by Cluster are reassembled by a fitting-reconstruction method. The results show three-dimensionally that a secondary island event can manifest the flux rope formed with an A{sub s}-type null and a B{sub s}-type null paired via their spines. We call this A{sub s}-spine-B{sub s}-like configuration the helically wrapped spine model. The reconstructed field lines wrap around the spine to form the flux rope, and an O-type topology is therefore seen on the plane perpendicular to the spine. Magnetized electrons are found to rotate on and cross the fan surface, suggesting that both the torsional-spine and the spine-fan reconnection take place in the configuration. Furthermore, detailed analysis implies that the spiral nulls and flux ropes were locally generated nearby the spacecraft in the reconnection outflow region, indicating that secondary reconnection may occur in the exhaust away from the primary reconnection site.

  8. In-situ observations of flux ropes formed in association with a pair of spiral nulls in magnetotail plasmas

    Guo, Ruilong; Xie, Lun; He, Jiansen; Pu, Zuyin; Fu, Suiyan; Chen, Li-Jen; Wang, Xiaogang; Dunlop, Malcolm; Bogdanova, Yulia V.; Yao, Zhonghua; Fazakerley, Andrew N.; Xiao, Chijie

    2016-01-01

    Signatures of secondary islands are frequently observed in the magnetic reconnection regions of magnetotail plasmas. In this paper, magnetic structures with the secondary-island signatures observed by Cluster are reassembled by a fitting-reconstruction method. The results show three-dimensionally that a secondary island event can manifest the flux rope formed with an A_s-type null and a B_s-type null paired via their spines. We call this A_s-spine-B_s-like configuration the helically wrapped spine model. The reconstructed field lines wrap around the spine to form the flux rope, and an O-type topology is therefore seen on the plane perpendicular to the spine. Magnetized electrons are found to rotate on and cross the fan surface, suggesting that both the torsional-spine and the spine-fan reconnection take place in the configuration. Furthermore, detailed analysis implies that the spiral nulls and flux ropes were locally generated nearby the spacecraft in the reconnection outflow region, indicating that secondary reconnection may occur in the exhaust away from the primary reconnection site.

  9. Thermal plasma spheroidization and spray deposition of barium titanate powder and characterization of the plasma sprayable powder

    Pakseresht, A.H., E-mail: amirh_pak@yahoo.com [Department of Ceramics, Materials and Energy Research Center, P.O. Box 31787-316, Karaj (Iran, Islamic Republic of); Rahimipour, M.R. [Department of Ceramics, Materials and Energy Research Center, P.O. Box 31787-316, Karaj (Iran, Islamic Republic of); Vaezi, M.R. [Department of Nanotechnology and Advanced Materials, Materials and Energy Research Center, P.O. Box 31787-316, Karaj (Iran, Islamic Republic of); Salehi, M. [Department of Materials Engineering, Isfahan University of Technology, P.O. Box 84156-83111, Isfahan (Iran, Islamic Republic of)

    2016-04-15

    In this paper, atmospheric plasma spray method was used to produce dense plasma sprayable powder and thick barium titanate film. In this regard, the commercially feedstock powders were granulated and spheroidized by the organic binder and the thermal spray process, respectively. Scanning electron microscopy was used to investigate the microstructure of the produced powders and the final deposits. X-ray diffraction was also implemented to characterize phase of the sprayed powder. The results indicated that spheroidized powder had suitable flowability as well as high density. The micro-hardness of the film produced by the sprayed powders was higher than that of the film deposited by the irregular granules. Additionally, relative permittivity of the films was increased by decreasing the defects from 160 to 293 for film deposited using spheroidized powder. The reduction in the relative permittivity of deposits, in comparison with the bulk material, was due to the existence of common defects in the thermal spray process. - Highlights: • We prepare sprayable BaTiO{sub 3} powder with no or less inside voids for plasma spray application for first time. • The sprayable powder has good flow characteristics and high density. • Powder spheroidization via plasma spray improves the hardness and dielectric properties of the deposited film.

  10. Thermal plasma spheroidization and spray deposition of barium titanate powder and characterization of the plasma sprayable powder

    Pakseresht, A.H.; Rahimipour, M.R.; Vaezi, M.R.; Salehi, M.

    2016-01-01

    In this paper, atmospheric plasma spray method was used to produce dense plasma sprayable powder and thick barium titanate film. In this regard, the commercially feedstock powders were granulated and spheroidized by the organic binder and the thermal spray process, respectively. Scanning electron microscopy was used to investigate the microstructure of the produced powders and the final deposits. X-ray diffraction was also implemented to characterize phase of the sprayed powder. The results indicated that spheroidized powder had suitable flowability as well as high density. The micro-hardness of the film produced by the sprayed powders was higher than that of the film deposited by the irregular granules. Additionally, relative permittivity of the films was increased by decreasing the defects from 160 to 293 for film deposited using spheroidized powder. The reduction in the relative permittivity of deposits, in comparison with the bulk material, was due to the existence of common defects in the thermal spray process. - Highlights: • We prepare sprayable BaTiO_3 powder with no or less inside voids for plasma spray application for first time. • The sprayable powder has good flow characteristics and high density. • Powder spheroidization via plasma spray improves the hardness and dielectric properties of the deposited film.

  11. Non-thermal plasma destruction of allyl alcohol in waste gas: kinetics and modelling

    DeVisscher, A.; Dewulf, J.; Van Durme, J.; Leys, C.; Morent, R.; Van Langenhove, H.

    2008-02-01

    Non-thermal plasma treatment is a promising technique for the destruction of volatile organic compounds in waste gas. A relatively unexplored technique is the atmospheric negative dc multi-pin-to-plate glow discharge. This paper reports experimental results of allyl alcohol degradation and ozone production in this type of plasma. A new model was developed to describe these processes quantitatively. The model contains a detailed chemical degradation scheme, and describes the physics of the plasma by assuming that the fraction of electrons that takes part in chemical reactions is an exponential function of the reduced field. The model captured the experimental kinetic data to less than 2 ppm standard deviation.

  12. Non-thermal plasma destruction of allyl alcohol in waste gas: kinetics and modelling

    Visscher, A de; Dewulf, J; Durme, J van; Leys, C; Morent, R; Langenhove, H Van

    2008-01-01

    Non-thermal plasma treatment is a promising technique for the destruction of volatile organic compounds in waste gas. A relatively unexplored technique is the atmospheric negative dc multi-pin-to-plate glow discharge. This paper reports experimental results of allyl alcohol degradation and ozone production in this type of plasma. A new model was developed to describe these processes quantitatively. The model contains a detailed chemical degradation scheme, and describes the physics of the plasma by assuming that the fraction of electrons that takes part in chemical reactions is an exponential function of the reduced field. The model captured the experimental kinetic data to less than 2 ppm standard deviation

  13. The structure and thermal properties of plasma-sprayed beryllium for the International Thermonuclear Experimental Reactor (ITER)

    Castro, R.G.; Bartlett, A.; Elliott, K.E.; Hollis, K.J.

    1996-01-01

    Plasma spraying is being studied for in situ repair of damaged Be and W plasma facing surfaces for ITER, the next generation magnetic fusion energy device, and is also being considered for fabricating Be and W plasma-facing components for the first wall of ITER. Investigators at LANL's Beryllium Atomization and Thermal Spray Facility have concentrated on investigating the structure-property relation between as-deposited microstructures of plasma sprayed Be coatings and resulting thermal properties. In this study, the effect of initial substrate temperature on resulting thermal diffusivity of Be coatings and the thermal diffusivity at the coating/Be substrate interface (interface thermal resistance) was investigated. Results show that initial Be substrate temperatures above 600 C can improve the thermal diffusivity of the Be coatings and minimize any thermal resistance at the interface between the Be coating and Be substrate

  14. Thermal shock problems of bonded structure for plasma facing components

    Shibui, M.; Kuroda, T.; Kubota, Y.

    1991-01-01

    Thermal shock tests have been performed on W(Re)/Cu and Mo/Cu duplex structures with a particular emphasis on two failure modes: failure on the heated surface and failure near the bonding interface. The results indicate that failure of the duplex structure largely depends on the constraint of thermal strain on the heated surface and on the ductility changes of armour materials. Rapid debonding of the bonding interface may be attributed to the yielding of armour materials. This leads to a residual bending deformation when the armour cools down. Arguments are also presented in this paper on two parameter characterization of the failure of armour materials and on stress distribution near the free edge of the bonding interface. (orig.)

  15. Measurement of thermal plasma jet temperature and velocity by laser light lineshape analysis

    Snyder, S.C.; Reynolds, L.D.

    1991-01-01

    Two important parameters of thermal plasma jets are kinetic or gas temperatures and flow velocity. Gas temperatures have been traditionally measured using emission spectroscopy, but this method depends on either the generally unrealistic assumption of the existence of local thermodynamic equilibrium (LTE) within the plasma, or the use of various non-LTE or partial LTE models to relate the intensity of the emission lines to the gas temperature. Plasma jet velocities have been measured using laser Doppler velocimetry on particles injected into the plasma. However, this method is intrusive and it is not known how well the particle velocities represent the gas velocity. Recently, plasma jet velocities have been measured from the Doppler shift of laser light scattered by the plasma. In this case, the Doppler shift was determined from the difference in the transmission profile of a high resolution monochromator between red shifted and blue shifted scattered light. A direct approach to measuring localized temperatures and velocities is afforded by high resolution scattered light lineshape measurements. The linewidth of laser light scattered by atoms and ions can be related to the kinetic temperature without LTE assumptions, while a shift in the peak position relative to the incident laser lineshape yields the gas velocity. We report in this paper work underway to measure gas temperatures and velocities in an argon thermal plasma jet using high resolution lineshape analysis of scattered laser light

  16. Departures from thermal equilibrium in a dense Z-pinch plasma

    Neufeld, C.R.

    1979-01-01

    This paper presents on analysis of several features of the emission spectrum obtained from a dense hydrogen Z-pinch plasma. The spectrum is characterized by an extremely broad H/sub β/ line and by the absence of an emission line at the H/sub b/ wavelength. Comparison with theory shows that the spectrum is inconsistent with the assumption of a thermal or collision-dominated plasma. The assumption of a substantial overpopulation of the atomic-hydrogen excited levels, ascribed to a rising degree of plasma ionization, provides a satisfactory description of the observed spectrum. This result illustrates the difficulty of establishing valid equilibrium criteria for transient plasmas, even in the case of plasma densities as high as 10 19 cm -3

  17. Ignition phase and steady-state structures of a non-thermal air plasma

    Lu Xin Pei

    2003-01-01

    An AC-driven, non-thermal, atmospheric pressure air plasma is generated within the gap separating a disc-shaped metal electrode and a water electrode. The ignition phase and the steady-state are studied by a high-speed CCD camera. It is found that the plasma always initiates at the surface of the water electrode. The plasma exhibits different structures depending on the polarity of the water electrode: when the water electrode plays the role of cathode, a relatively wide but visibly dim plasma column is generated. At the maximum driving voltage, the gas temperature is between 800 and 900 K, and the peak current is 67 mA; when the water electrode is anode, the plasma column narrows but increases its light emission. The gas temperature in this case is measured to be in the 1400-1500 K range, and the peak current is 81 mA.

  18. Non-local thermodynamic equilibrium effects on isentropic coefficient in argon and helium thermal plasmas

    Sharma, Rohit; Singh, Kuldip

    2014-01-01

    In the present work, two cases of thermal plasma have been considered; the ground state plasma in which all the atoms and ions are assumed to be in the ground state and the excited state plasma in which atoms and ions are distributed over various possible excited states. The variation of Zγ, frozen isentropic coefficient and the isentropic coefficient with degree of ionization and non-equilibrium parameter θ(= T e /T h ) has been investigated for the ground and excited state helium and argon plasmas at pressures 1 atm, 10 atm, and 100 atm in the temperature range from 6000 K to 60 000 K. For a given value of non-equilibrium parameter, the relationship of Zγ with degree of ionization does not show any dependence on electronically excited states in helium plasma whereas in case of argon plasma this dependence is not appreciable till degree of ionization approaches 2. The minima of frozen isentropic coefficient shifts toward lower temperature with increase of non-equilibrium parameter for both the helium and argon plasmas. The lowering of non-equilibrium parameter decreases the frozen isentropic coefficient more emphatically in helium plasma at high pressures in comparison to argon plasma. The increase of pressure slightly reduces the ionization range over which isentropic coefficient almost remains constant and it does not affect appreciably the dependence of isentropic coefficient on non-equilibrium parameter

  19. Analysis of the expanding thermal argon-oxygen plasma gas phase

    Hest, M F A M van; Haartsen, J R; Weert, M H M van; Schram, D C; Sanden, M C M van de

    2003-01-01

    An expanding thermal argon plasma into which oxygen is injected has been analysed by means of Langmuir and Pitot probe measurements. Information is obtained on the ion density profile and the flow pattern in the downstream plasma. A combination of Langmuir and Pitot probe measurements provide information on the total ion flux generated by the plasma source (cascaded arc). It has been found that the ion diffusion is mainly determined by the background pressure in the expansion vessel and the arc current. The ion density is determined by the total power input into the plasma as well as the gas flow in the plasma source. There is an optimum in the power transfer used for ionization from plasma source to the feed gas. Interaction of oxygen with the plasma results in a decrease in the argon ion density and the plasma beam radius. The recirculation pattern of the downstream plasma has been investigated experimentally using the Pitot probe. Due to the low downstream pressure (10-30 Pa), the conventional compressible Pitot probe theory no longer applies. It is concluded that viscous effects start to play an important role at these low pressures and should be taken into account in the analysis of the Pitot probe measurements

  20. Thermal effects in intense laser-plasma interactions

    Shadwick, B.A.; Tarkenton, G.M.; Esarey, E.H.

    2004-01-01

    We present an overview of a new warm fluid model that incorporates leading-order kinetic corrections to the cold fluid model without making any near-equilibrium assumptions. In the quasi-static limit we obtain analytical expressions for the momentum spread and show excellent agreement with solutions of the full time-dependant equations. It is shown that over a large range of initial plasma temperatures, the fields are relatively insensitive to the pressure force. We discuss implications of this work for model validation

  1. Spontaneous generation of electromagnetic waves in plasmas with electron thermal flux

    Okada, Toshio

    1977-01-01

    Spontaneous generation of propagating electromagnetic fields due to a microinstability is investigated for plasmas which convey electron thermal fluxes. The following two cases are examined: 1) Electromagnetic fields spontaneously excited by electrons in a velocity distribution of skewed Maxwellian type. 2) Electromagnetic waves generated by electrons in a velocity distribution which consists of a main part and a high energy part. In this case, the electron thermal flux can be very high. In both cases, induced electromagnetic waves with relatively low frequencies propagate parallel to the direction of Thermal flux. (auth.)

  2. Performance of plasma facing materials under intense thermal loads in tokamaks and stellarators

    Linke, J.; Hirai, T.; Roedig, M.; Singheiser, L. [Forschungszentrum Juelich GmbH, EURATOM Association, Juelich (Germany)

    2003-07-01

    Beside quasi-stationary plasma operation, short transient thermal pulses with deposited energy densities in the order of several ten MJm{sup -2} are a serious concern for next step devices, in particular for tokamak devices such as ITER. The most serious of these transient events are plasma disruptions. Here a considerable fraction of the plasma energy is deposited on a localized surface area in the divertor strike zone region; the time scale of these events is typically in the order of 1 ms. In spite of the fact that a dense cloud of ablation vapour will form above the strike zone, only partial shielding of the divertor armour from incident plasma particles will occur. As a consequence, thermal shock induced crack formation, vaporization, surface melting, melt layer ejection, and particle emission induced by brittle destruction processes will limit the lifetime of the components. In addition, dust particles (neutron activated metals or tritium enriched carbon) are a serious concern form a safety point of view. Other transient heat loads which occasionally occur in magnetic confinement experiments such as instabilities in the plasma positioning (vertical displacement events) also may cause irreversible damage to plasma facing components (PFC), particularly to metals such as beryllium and tungsten. Another serious damage to PFCs is due to intense fluxes of 14 MeV neutrons in D-T-burning plasma devices. Integrated neutron fluence of several ten dpa in future thermonuclear fusion reactors will degrade essential physical properties of the components (e.g. thermal conductivity); another serious concern is the embrittlement of the heat sink and the plasma facing materials (PFM). (orig.)

  3. Thermal history of the plasma and high-frequency gravitons

    Giovannini, Massimo

    2009-01-01

    Possible deviations from a radiation-dominated evolution, occurring prior the synthesis of light nuclei, impacted on the spectral energy density of high-frequency gravitons. For a systematic scrutiny of this situation, the $\\Lambda$CDM paradigm must be complemented by (at least two) physical parameters describing, respectively, a threshold frequency and a slope. The supplementary frequency scale sets the lower border of a high-frequency domain where the spectral energy grows with a slope which depends, predominantly, upon the total sound speed of the plasma right after inflation. While the infra-red region of the graviton energy spectrum is nearly scale-invariant, the expected signals for typical frequencies larger than 0.01 nHz are hereby analyzed in a model-independent framework by requiring that the total sound speed of the post-inflationary plasma is smaller than the speed of light. Current (e.g. low-frequency) upper limits on the tensor power spectra (determined from the combined analysis of the three la...

  4. High Temperature Oxidation of Spark Plasma Sintered and Thermally Sprayed FeAl-Based Iron Aluminides

    Haušild, P.; Karlík, M.; Skiba, T.; Sajdl, P.; Dubský, Jiří; Palm, M.

    2012-01-01

    Roč. 122, č. 3 (2012), s. 465-468 ISSN 0587-4246. [International Symposium on Physics of Materials (ISPMA)/12./. Prague, 04.09.2011-08.09.2011] Institutional support: RVO:61389021 Keywords : thermal spraying * plasma sintering Subject RIV: JH - Ceramics, Fire-Resistant Materials and Glass Impact factor: 0.531, year: 2012

  5. Experimental studies on removal of airborne haloanisoles by non-thermal plasma air purifiers

    Fang, Lei; Hallam, David; Bermúdez, Raúl

    2016-01-01

    A laboratory study was conducted to test the performance of non-thermal plasma air purifiers on its removal effectiveness of two haloanisoles – 2,4,6-trichloroanisole (TCA) and 2,4,6-Tribromoanisole (TBA). TCA and TBA are the two major compounds found in wine cellars that can contaminate wine to ...

  6. The conversion of the thermal energy of plasma in the SOL of tokamaks

    Nedospasov, A.V.; Nenova, N.V.

    2008-01-01

    When the plasma expands across the confining magnetic field, a part of its thermal energy is converted to electrical energy. In the SOL of tokamaks, the motion of the plasma across the field due to turbulent processes is accompanied by its departure along the open lines of the magnetic field. The conversion of thermal energy is taken into account in theoretical studies devoted to the physics of plasma in the SOL; however, this conversion is ignored in numerical models, for example, in B2-SOLPS4.0. This paper deals with thermal-to-electrical energy conversion in the SOL of tokamaks. It is demonstrated that the part of the thermal energy subjected to conversion to electrical energy forms an appreciable part of the total energy flowing in the SOL. In ITER, this fraction may be as high as 20-25%. The electrical energy generated in the SOL volume is liberated in the form of Joule heat in a relatively cold plasma in the vicinity of diverter plates or directly on these plates. (letter)

  7. Analysis of the step responses of laminar premixed flames to forcing by non-thermal plasma

    Lacoste, Deanna; Moeck, Jonas P.; Roberts, William L.; Chung, Suk-Ho; Cha, Min

    2016-01-01

    The step responses of lean methane-air flames to non-thermal plasma forcing is reported. The experimental setup consists of an axisymmetric burner, with a nozzle made of a quartz tube. The equivalence ratio is 0.95, allowing stabilization

  8. Expanding thermal plasma chemical vapour deposition of ZnO:Al layers for CIGS solar cells

    Sharma, K.; Williams, B.L.; Mittal, A.; Knoops, H.C.M.; Kniknie, B.J.; Bakker, N.J.; Kessels, W.M.M.; Schropp, R.E.I.; Creatore, M.

    2014-01-01

    Aluminium-doped zinc oxide (ZnO:Al) grown by expanding thermal plasma chemical vapour deposition (ETP-CVD) has demonstrated excellent electrical and optical properties, which make it an attractive candidate as a transparent conductive oxide for photovoltaic applications. However, when depositing

  9. The interplay between biological and physical scenarios of bacterial death induced by non-thermal plasma

    Lunov, O.; Zablotskyy, V.; Churpita, O.; Jäger, A.; Polívka, L.; Syková, Eva; Dejneka, A.; Kubinová, Šárka

    2016-01-01

    Roč. 82, mar. (2016), s. 71-83 ISSN 0142-9612 R&D Projects: GA MŠk(CZ) LO1309 Institutional support: RVO:68378041 Keywords : non-thermal plasma * bacteria * cytotoxicity Subject RIV: FP - Other Medical Disciplines Impact factor: 8.402, year: 2016

  10. Chemically different non-thermal plasmas target distinct cell death pathways

    Lunov, O.; Zablotskyy, V.; Chrupina, O.; Lunova, M.; Jirsa, M.; Dejneka, A.; Kubinová, Šárka

    2017-01-01

    Roč. 7, apr (2017), s. 600 ISSN 2045-2322 R&D Projects: GA MŠk(CZ) LO1309 Institutional support: RVO:68378041 Keywords : chemically different * non-thermal plasmas * target distinct cell death pathways Subject RIV: FP - Other Medical Disciplines OBOR OECD: Biophysics Impact factor: 4.259, year: 2016

  11. Optoelectronic properties of expanding thermal plasma deposited textured zinc oxide : effect of aluminum doping

    Groenen, R.; Kieft, E.R.; Linden, J.L.; Sanden, van de M.C.M.

    2006-01-01

    Aluminum-doped zinc oxide films exhibiting a rough surface morphol. are deposited on glass substrates utilizing expanding thermal plasma. Spectroscopic ellipsometry is used to evaluate optical and electronic film properties. The presence of aluminum donors in doped films is confirmed by a shift in

  12. High throughput deposition of hydrogenated amorphous carbon coatings on rubber with expanding thermal plasma

    Pei, Y.T.; Eivani, A.R.; Zaharia, T.; Kazantis, A.V.; Sanden, van de M.C.M.; De Hosson, J.T.M.

    2014-01-01

    Flexible hydrogenated amorphous carbon (a-C:H) thin film coated on rubbers has shown outstanding protection of rubber seals from friction and wear. This work concentrates on the potential advances of expanding thermal plasma (ETP) process for a high throughput deposition of a-C:H thin films in

  13. Effects of nitrogen seeding on core ion thermal transport in JET ILW L-mode plasmas

    Bonanomi, N.; Mantica, P.; Citrin, J.; Giroud, C.; Lerche, E.; Sozzi, C.; Taylor, D.; Tsalas, M.; Van Eester, D.; JET Contributors,

    2018-01-01

    A set of experiments was carried out in JET ILW (Joint European Torus with ITER-Like Wall) L-mode plasmas in order to study the effects of light impurities on core ion thermal transport. N was puffed into some discharges and its profile was measured by active Charge Exchange diagnostics, while ICRH

  14. Antimicrobial properties of uncapped silver nanoparticles synthesized by DC arc thermal plasma technique.

    Shinde, Manish; Patil, Rajendra; Karmakar, Soumen; Bhoraskar, Sudha; Rane, Sunit; Gade, Wasudev; Amalnerkar, Dinesh

    2012-02-01

    We, herein, report the antimicrobial properties of uncapped silver nanoparticles for a Gram positive model organism, Bacillus subtilis. Uncapped silver nanoparticles have been prepared using less-explored DC arc thermal plasma technique by considering its large scale generation capability. It is observed that the resultant nanoparticles show size as well as optical property dependent antimicrobial effect.

  15. Thermal instabilities in magnetically confined plasmas: Solar coronal loops

    Habbal, S.R.; Rosner, R.

    1979-01-01

    The thermal stability of confined solar coronal structures (''loops'') is investigated, following both normal mode and a new, global instability analysis. We demonstrate that: (a) normal mode analysis shows modes with size scales comparable to that of loops to be unstable, but to be strongly affected by the loop boundary conditions; (b) a global analysis, based upon variation of the total loop energy losses and gains, yields loop stability conditions for global modes dependent upon the coronal loop heating process, with magnetically coupled heating processes giving marginal stability. The connection between the present analysis and the minimum flux corona of Hearn is also discussed

  16. Treatment of mixed wastes by thermal plasma discharges; Tratamiento de desechos mixtos por descargas de plasma termico

    Diaz A, L.V.; Pacheco S, J.O.; Pacheco P, M.; Monroy G, F.; Emeterio H, M. [ININ, 52750 La Marquesa, Estado de Mexico (Mexico)]. e-mail: lauradiazarch@yahoo.com.mx

    2007-07-01

    The National Institute of Nuclear Research (ININ) uses an ion exchange resin: IRN 150 (copolymer styrene Divynilbencene) in the TRIGA Mark III reactor to absorb polluted particles with heavy metals and radioactive particles of low level. Once the capacity of filtrate of the resin is exceeded, it is replaced and considered with a mixed waste. This work is based on taking advantage of the advantages of the technique of the thermal plasma in a unique process: (high energy density 105W/cm{sup 3} high enthalpy, high reactivity chemical, high operation temperatures 6000-11500K and quick quenching 106K/s) for the degradation and vitrification of the resin IRN 150. The reactor of plasma is compact and it works to atmospheric pressure and reduced thermal inertia. Therefore, the main parameters involved during the degradation tests and vitrification are: plasma current, voltage, gas flow and distance among the electrodes. The used vitreous matrix, is obtained from a ceramic clay composed by an oxides mixture which are characterized by their good resistance to mechanical impacts and erosion caused by the water. The ceramic clay and the resin IRN 150 were analyzed before the treatment by Scanning Electron Microscopy (MEB), X-ray Diffraction (DRX), Thermal gravimetry (TGA) once vitrified the materials were also analyzed by MEB and DRX. It is obtained as a result that the material more appropriate to be used as vitreous matrix it is a ceramic clay formed by several oxides, being operated the plasma system with a current of 115A, voltage of 25V, flow of the argon gas of 5 l/m and a distance among electrodes of 10mm. With the development of the proposed technology and the material for the vitreous matrix, be rotted to try in a future a great variety of mixed waste. (Author)

  17. Studies of thermal energy confinement scaling in PDX plasmas: D0 → H+ limiter discharges

    Kaye, S.M.; Goldston, R.J.; Bell, M.

    1984-06-01

    Experiments were performed on the PDX tokamak to study plasma heating and β scaling with higher power, near-perpendicular neutral beam injection. The data taken during these experiments were analyzed using a time-dependent data interpretation code (TRANSP) to study the transport and thermal confinement scaling over a wide range of plasma parameters. This study focuses on results from experiments with D 0 injection into H + plasmas using graphite rail limiters, a = 40 to 44 cm, R = 143 cm, I/sub p/ = 200 to 480 kA, B/sub T/ = 0.7 to 2.2 T, and typically anti n/sub e/ = 2.5 to 4.2 x 10 13 cm -3 . The results of this study indicate that for both ohmic and neutral beam heated discharges the energy flow out of the plasma is dominated by anomalous electron losses, attributed to electron thermal conduction. The ion conduction losses are well described to electron thermal conduction. The ion conduction losses are well described by neoclassical theory; however, the total ion loss influences the power balance significantly only at high toroidal fields and high plasma currents

  18. Self-organization process of a magnetohydrodynamic plasma in the presence of thermal conduction

    Zhu, Shao-ping; Horiuchi, Ritoku; Sato, Tetsuya; Watanabe, K.; Hayashi, T.; Todo, Y.; Watanabe, T.H.; Kageyama, A.; Takamaru, H.

    1995-12-01

    A self-organization process of a magnetohydrodynamic(MHD) plasma with a finite thermal conductivity is investigated by means of a three-dimensional MHD simulation. With no thermal conduction an MHD system self-organizes to a non-Taylor's state in which the electric current perpendicular to the magnetic field remains comparable to the parallel electric current. In the presence of thermal conductivity the perpendicular component of electric current and the nonuniformity of thermal pressure generated by driven reconnection tend to be smoothened. Thus, the self-organized state approaches to a force-free minimum energy state under the influence of thermal conduction. Detailed energy conversion processes are also studied to find that the rapid decay of magnetic energy during the self-organization process is caused not only through the ohmic heating, but also through the work done by the j x B force. (author)

  19. Stress hysteresis during thermal cycling of plasma-enhanced chemical vapor deposited silicon oxide films

    Thurn, Jeremy; Cook, Robert F.

    2002-02-01

    The mechanical response of plasma-enhanced chemical vapor deposited SiO2 to thermal cycling is examined by substrate curvature measurement and depth-sensing indentation. Film properties of deposition stress and stress hysteresis that accompanied thermal cycling are elucidated, as well as modulus, hardness, and coefficient of thermal expansion. Thermal cycling is shown to result in major plastic deformation of the film and a switch from a compressive to a tensile state of stress; both athermal and thermal components of the net stress alter in different ways during cycling. A mechanism of hydrogen incorporation and release from as-deposited silanol groups is proposed that accounts for the change in film properties and state of stress.

  20. Modeling of thermal effects on TIBER II divertor during plasma disruptions

    Bruhn, M.L.; Perkins, L.J.

    1987-01-01

    Mapping the disruption power flow from the mid-plane of the TIBER Engineering Test Reactor to its divertor and calculating the resulting thermal effects are accomplished through the modification and coupling of three presently existing computer codes. The resulting computer code TADDPAK (Thermal Analysis Divertor during Disruption PAcKage) provides three-dimensional graphic presentations of time and positional dependent thermal effects on a poloidal cross section of the double-null-divertor configured reactor. These thermal effects include incident heat flux, surface temperature, vaporization rate, total vaporization, and melting depth. The dependence of these thermal effects on material choice, disruption pulse shape, and the characteristic thickness of the plasma scrape-off layer is determined through parametric analysis with TADDPAK. This computer code is designed to be a convenient, rapid, and user-friendly modeling tool which can be easily adapted to most tokamak double-null-divertor reactor designs

  1. Plasma Reforming of Liquid Hydrocarbon Fuels in Non-Thermal Plasma-Liquid Systems

    2010-04-30

    channel with liquid wall in the microporous media under the ultrasound cavitations has shown the following: · The action of the ultrasound field in the...microporous liquid which has a very large ratio of the plasma-liquid contact surface to the plasma volume. As is known the ultrasonic (US) cavitation is a very...2) and it ran over a flat dielectric surface of the magnetostrictive transmitter (5) which produced ultrasonic (US) cavitations , so the discharge

  2. Characteristics and Thermal Efficiency of a Non-transferred DC Plasma Spraying Torch Under Low Pressure

    Bao Shicong; Ye Minyou; Zhang Xiaodong; Guo Wenkang; Xu Ping

    2008-01-01

    Current-voltage (I-V) characteristics of a non-transferred DC arc plasma spray torch operated in argon at vacuum are reported. The arc voltage is of negative characteristics for a current below 200 A, flat for a current between 200 A to 250 A and positive for a current beyond 250 A. The voltage increases slowly with the increase in carrier gas of arc. The rate of change in voltage with currents is about 3∼4 V/100 A at a gas flow rate of about 1∼1.5 V/10 standard liter per minute (slpm). The I-V characteristics of the DC plasma torch are of a shape of hyperbola. Arc power increases with the argon flow rate, and the thermal efficiency of the torch acts in a similar way. The thermal efficiency of the non-transferred DC plasmatron is about 65∼78%. (low temperature plasma)

  3. Thermal radiation from an evolving viscous quark gluon plasma

    Mitra, Sukanya; Mohanty, Payal; Sarkar, Sourav; Alam, Jan-E

    2013-01-01

    The effects of viscosity on the space-time evolution of quark gluon plasma produced in nuclear collisions at relativistic heavy ion collider energies have been studied. The entropy generated due to the viscous motion of the fluid has been taken into account in constraining the initial temperature by the final multiplicity (measured at the freeze-out point). The viscous effects on the photon spectra has been introduced consistently through the evolution dynamics and phase space factors of all the participating partons/hadrons in the production process. In contrast to some of the recent calculations the present work includes the contribution from the hadronic phase. A small change in the transverse momentum (p T ) distribution of photons is observed due to viscous effects. (author)

  4. Finite element thermal study of the Linac4 plasma generator

    Faircloth, D.; Kronberger, M.; Kuechler, D.; Lettry, J.; Scrivens, R.

    2010-01-01

    The temperature distribution and heat flow at equilibrium of the plasma generator of the rf-powered noncesiated Linac4 H - ion source have been studied with a finite element model. It is shown that the equilibrium temperatures obtained in the Linac4 nominal operation mode (100 kW rf power, 2 Hz repetition rate, and 0.4 ms pulse duration) are within material specifications except for the magnet cage, where a redesign may be necessary. To assess the upgrade of the Linac4 source for operation in the high-power operation mode of the Superconducting Proton Linac (SPL), an extrapolation of the heat load toward 100 kW rf power, 50 Hz repetition rate, and 0.4 ms pulse duration has been performed. The results indicate that a significant improvement of the source cooling is required to allow for operation in the high-power mode of SPL.

  5. Finite element thermal study of the Linac4 plasma generator

    Faircloth, D. [STFC, Rutherford Appleton Laboratory, Chilton, Oxon OX11 0QX (United Kingdom); Kronberger, M.; Kuechler, D.; Lettry, J.; Scrivens, R. [BE-ABP, Hadron Sources and Linacs, CERN, CH-1211 Geneva (Switzerland)

    2010-02-15

    The temperature distribution and heat flow at equilibrium of the plasma generator of the rf-powered noncesiated Linac4 H{sup -} ion source have been studied with a finite element model. It is shown that the equilibrium temperatures obtained in the Linac4 nominal operation mode (100 kW rf power, 2 Hz repetition rate, and 0.4 ms pulse duration) are within material specifications except for the magnet cage, where a redesign may be necessary. To assess the upgrade of the Linac4 source for operation in the high-power operation mode of the Superconducting Proton Linac (SPL), an extrapolation of the heat load toward 100 kW rf power, 50 Hz repetition rate, and 0.4 ms pulse duration has been performed. The results indicate that a significant improvement of the source cooling is required to allow for operation in the high-power mode of SPL.

  6. Finite Element Thermal Study of the Linac4 Plasma Generatora

    Faircloth, D; Kuchler, D; Lettry, L; Scrivens, R; CERN. Geneva. BE Department

    2010-01-01

    The temperature distribution and heat flow at equilibrium of the plasma generator of the RF-powered non-cesiated Linac4 H- ion source have been studied with a finite element model. It is shown that the equilibrium temperatures obtained in the Linac4 nominal operation mode (100 kW RF power, 2 Hz, 0.4 ms pulse duration) are within material specifications except for the magnet cage, where a redesign may be necessary. To assess the upgrade of the Linac4 source for operation in the high-power operation mode of SPL, an extrapolation of the heat load towards 100 kW RF power, 50 Hz repetition rate and 0.4 ms pulse duration has been performed. The results indicate that a significant improvement of the source cooling is required to allow for operation in HP-SPL.

  7. Half bridge resonant converter for ignition of thermal plasmas

    Pena E, L.

    1997-01-01

    In this work the background, design, implementation and performance of a half bridge resonant converter (HBRC) used as an electronic ignition system for arc plasma torch generation is presented. The significance of the design lies in its simplicity, versatility and low cost. The system operates like a high voltage supply attached to electrodes before gaseous breakdown and like open circuit when electric arc is established. Resonant converter is implemented with a high voltage and high speed power driver intended for control the power MOSFET transistors connected in half bridge topology with L C load. The HBRC operates besides interference into domestic electric supply line (120 V, 60 Hz) as well electric measurement devices. Advantages and limitations of the converter are reviewed. Experimental impedance variation in the medium as a function of frequency operation and some experiences in striking arcs are also presented. (Author)

  8. Molecular Dynamics study of the effects of non-stoichiometry and oxygen Frenkel pairs on the thermal conductivity of uranium dioxide

    Nichenko, Sergii; Staicu, Dragos

    2013-01-01

    In the present work, calculations of the thermal conductivity of UO 2 were carried out applying classical Molecular Dynamics for the isothermal-isobaric (NPT) statistical ensemble, using the Green–Kubo approach. The thermal conductivity calculated for perfect stoichiometric UO 2 is in good agreement with the literature data over the temperature range corresponding to heat transfer by phonons (up to 1700 K). The effect of non-stoichiometry on the thermal conductivity was calculated taking into account the presence of polarons. It was found that for the same value of the stoichiometry deviation, the effect of oxygen vacancies (hypo-stoichiometry) is more pronounced than the effect of oxygen interstitials (hyper-stoichiometry). Then the influence of the oxygen Frenkel pairs on the thermal conductivity was calculated. The simultaneous impact of non-stoichiometry and OFP on the thermal conductivity was investigated and it was shown that the two effects can be combined using the interpretation obtained with the classical phonons scattering theory. Finally, simplified correlations were deduced for the calculation of the thermal conductivity of UO 2 taking into account the effect of non-stoichiometry and of Frenkel pairs, these two effects being present during irradiation

  9. Thermalization of mini-jets in a quark–gluon plasma

    Iancu, Edmond, E-mail: edmond.iancu@cea.fr; Wu, Bin, E-mail: bin.wu.phys@gmail.com [Institut de Physique Théorique, CEA Saclay, CNRS UMR 3681, F-91191 Gif-sur-Yvette (France); Department of Physics, The Ohio State University, Columbus, OH 43210 (United States)

    2016-12-15

    We present the complete physical picture for the evolution of a high-energy jet propagating through a weakly-coupled quark-gluon plasma (QGP) by analytical and numerical investigation of thermalization of the soft components of the jet. Our results support the following physical picture: the leading particle emits a significant number of mini-jets which promptly evolve via multiple branching and thus degrade into a myriad of soft gluons, with energies of the order of the medium temperature T. Via elastic collisions with the medium constituents, these soft gluons relax to local thermal equilibrium with the plasma over a time scale which is considerably shorter than the typical lifetime of the mini-jet. The thermalized gluons form a tail which lags behind the hard components of the jet. Together with the background QGP, they behave hydrodynamically.

  10. Time-resolved probing of electron thermal conduction in femtosecond-laser-pulse-produced plasmas

    Vue, B.T.V.

    1993-06-01

    We present time-resolved measurements of reflectivity, transmissivity and frequency shifts of probe light interacting with the rear of a disk-like plasma produced by irradiation of a transparent solid target with 0.1ps FWHM laser pulses at peak intensity 5 x 10 l4 W/CM 2 . Experimental results show a large increase in reflection, revealing rapid formation of a steep gradient and overdense surface plasma layer during the first picosecond after irradiation. Frequency shifts due to a moving ionization created by thermal conduction into the solid target are recorded. Calculations using a nonlinear thermal heat wave model show good agreement with the measured frequency shifts, further confining the strong thermal transport effect

  11. Novel fragmentation model for pulverized coal particles gasification in low temperature air thermal plasma

    Jovanović Rastko D.

    2016-01-01

    Full Text Available New system for start-up and flame support based on coal gasification by low temperature air thermal plasma is planned to supplement current heavy oil system in Serbian thermal power plants in order to decrease air pollutions emission and operational costs. Locally introduced plasma thermal energy heats up and ignites entrained coal particles, thus starting chain process which releases heat energy from gasified coal particles inside burner channel. Important stages during particle combustion, such as particle devolatilisation and char combustion, are described with satisfying accuracy in existing commercial CFD codes that are extensively used as powerful tool for pulverized coal combustion and gasification modeling. However, during plasma coal gasification, high plasma temperature induces strong thermal stresses inside interacting coal particles. These stresses lead to “thermal shock” and extensive particle fragmentation during which coal particles with initial size of 50-100 m disintegrate into fragments of at most 5-10 m. This intensifies volatile release by a factor 3-4 and substantially accelerates the oxidation of combustible matter. Particle fragmentation, due to its small size and thus limited influence on combustion process is commonly neglected in modelling. The main focus of this work is to suggest novel approach to pulverized coal gasification under high temperature conditions and to implement it into commercial comprehensive code ANSYS FLUENT 14.0. Proposed model was validated against experimental data obtained in newly built pilot scale D.C plasma burner test facility. Newly developed model showed very good agreement with experimental results with relative error less than 10%, while the standard built-in gasification model had error up to 25%.

  12. Non-thermal plasma instabilities induced by deformation of the electron energy distribution function

    Dyatko, N. A.; Kochetov, I. V.; Napartovich, A. P.

    2014-08-01

    Non-thermal plasma is a key component in gas lasers, microelectronics, medical applications, waste gas cleaners, ozone generators, plasma igniters, flame holders, flow control in high-speed aerodynamics and others. A specific feature of non-thermal plasma is its high sensitivity to variations in governing parameters (gas composition, pressure, pulse duration, E/N parameter). This sensitivity is due to complex deformations of the electron energy distribution function (EEDF) shape induced by variations in electric field strength, electron and ion number densities and gas excitation degree. Particular attention in this article is paid to mechanisms of instabilities based on non-linearity of plasma properties for specific conditions: gas composition, steady-state and decaying plasma produced by the electron beam, or by an electric current pulse. The following effects are analyzed: the negative differential electron conductivity; the absolute negative electron mobility; the stepwise changes of plasma properties induced by the EEDF bi-stability; thermo-current instability and the constriction of the glow discharge column in rare gases. Some of these effects were observed experimentally and some of them were theoretically predicted and still wait for experimental confirmation.

  13. Non-thermal plasmas for non-catalytic and catalytic VOC abatement

    Vandenbroucke, Arne M.; Morent, Rino; De Geyter, Nathalie; Leys, Christophe

    2011-01-01

    Highlights: → We review the current status of catalytic and non-catalytic VOC abatement based on a vast number of research papers. → The underlying mechanisms of plasma-catalysis for VOC abatement are discussed. → Critical process parameters that determine the influent are discussed and compared. - Abstract: This paper reviews recent achievements and the current status of non-thermal plasma (NTP) technology for the abatement of volatile organic compounds (VOCs). Many reactor configurations have been developed to generate a NTP at atmospheric pressure. Therefore in this review article, the principles of generating NTPs are outlined. Further on, this paper is divided in two equally important parts: plasma-alone and plasma-catalytic systems. Combination of NTP with heterogeneous catalysis has attracted increased attention in order to overcome the weaknesses of plasma-alone systems. An overview is given of the present understanding of the mechanisms involved in plasma-catalytic processes. In both parts (plasma-alone systems and plasma-catalysis), literature on the abatement of VOCs is reviewed in close detail. Special attention is given to the influence of critical process parameters on the removal process.

  14. Destruction studies of hazardous wastes by thermal plasma; Estudios de degradacion de residuos peligrosos mediante plasma termico

    Cota S, G

    1998-11-01

    Plasma technology appears promising because its high degree of controllability, capability to process waste without the adverse effects of combustion, and a very wide temperature range of operation. The goal of this work was to develop a process for a high throughput system to turn hazardous waste into inert stable products, which can be safely stored and to greatly reduce air pollution relative to incineration. The experiments have shown that the thermal plasma reactor can provide a high degree of decomposition of CCl{sub 4} , C{sub 6} H{sub 6}, C{sub 2} Cl{sub 4} and commercial oil at low gas input speeds, with modest power requirements. Decomposition of 99.9999 % has been obtained in our laboratory and all the organic components are decomposed in base molecules (C, CO, CO{sub 2}, H{sub 2}, HCl). The analysis of exhaust gases was made by using a mass filter quadrupole. The equipment consist of a cylindrical reactor hermetically sealed, double-walled and water-cooled container made of special steel, this container in halt the crucible which serves to receive the waste materials. The whole system is designed for a maximal internal temperature of 2000 Centigrade. The gaseous result components of the material are transferred to a scrubber unit through an exit arranged on the top of reactor. The thermal efficiency evaluation of the plasma torch was also realized, obtaining a reasonable agreement between measurements and predictions in temperature profiles. (Author)

  15. Thermal Conductivity and Erosion Durability of Composite Two-Phase Air Plasma Sprayed Thermal Barrier Coatings

    Schmitt, Michael P.; Rai, Amarendra K.; Zhu, Dongming; Dorfman, Mitchell R.; Wolfe, Douglas E.

    2015-01-01

    To enhance efficiency of gas turbines, new thermal barrier coatings (TBCs) must be designed which improve upon the thermal stability limit of 7 wt% yttria stabilized zirconia (7YSZ), approximately 1200 C. This tenant has led to the development of new TBC materials and microstructures capable of improved high temperature performance. This study focused on increasing the erosion durability of cubic zirconia based TBCs, traditionally less durable than the metastable t' zirconia based TBCs. Composite TBC microstructures composed of a low thermal conductivity/high temperature stable cubic Low-k matrix phase and a durable t' Low-k secondary phase were deposited via APS. Monolithic coatings composed of cubic Low-k and t' Low-k were also deposited, in addition to a 7YSZ benchmark. The thermal conductivity and erosion durability were then measured and it was found that both of the Low-k materials have significantly reduced thermal conductivities, with monolithic t' Low-k and cubic Low-k improving upon 7YSZ by approximately 13 and approximately 25%, respectively. The 40 wt% t' Low-k composite (40 wt% t' Low-k - 60 wt% cubic Low-k) showed a approximately 22% reduction in thermal conductivity over 7YSZ, indicating even at high levels, the t' Low-k secondary phase had a minimal impact on thermal in the composite coating. It was observed that a mere 20 wt% t' Low-k phase addition can reduce the erosion of a cubic Low-k matrix phase composite coating by over 37%. Various mixing rules were then investigated to assess this non-linear composite behavior and suggestions were made to further improve erosion durability.

  16. On the propagation of hydromagnetic waves in a plasma of thermal and suprathermal components

    Kumar, Nagendra; Sikka, Himanshu

    2007-12-01

    The propagation of MHD waves is studied when two ideal fluids, thermal and suprathermal gases, coupled by magnetic field are moving with the steady flow velocity. The fluids move independently in a direction perpendicular to the magnetic field but gets coupled along the field. Due to the presence of flow in suprathermal and thermal fluids there appears forward and backward waves. All the forward and backward modes propagate in such a way that their rate of change of phase speed with the thermal Mach number is same. It is also found that besides the usual hydromagnetic modes there appears a suprathermal mode which propagates with faster speed. Surface waves are also examined on an interface formed with composite plasma (suprathermal and thermal gases) on one side and the other is a non-magnetized plasma. In this case, the modes obtained are two or three depending on whether the sound velocity in thermal gas is equal to or greater than the sound velocity in suprathermal gas. The results lead to the conclusion that the interaction of thermal and suprathermal components may lead to the occurrence of an additional mode called suprathermal mode whose phase velocity is higher than all the other modes.

  17. Estimation of the thermal diffusion coefficient in fusion plasmas taking frequency measurement uncertainties into account

    Van Berkel, M; Hogeweij, G M D; Van den Brand, H; De Baar, M R; Zwart, H J; Vandersteen, G

    2014-01-01

    In this paper, the estimation of the thermal diffusivity from perturbative experiments in fusion plasmas is discussed. The measurements used to estimate the thermal diffusivity suffer from stochastic noise. Accurate estimation of the thermal diffusivity should take this into account. It will be shown that formulas found in the literature often result in a thermal diffusivity that has a bias (a difference between the estimated value and the actual value that remains even if more measurements are added) or have an unnecessarily large uncertainty. This will be shown by modeling a plasma using only diffusion as heat transport mechanism and measurement noise based on ASDEX Upgrade measurements. The Fourier coefficients of a temperature perturbation will exhibit noise from the circular complex normal distribution (CCND). Based on Fourier coefficients distributed according to a CCND, it is shown that the resulting probability density function of the thermal diffusivity is an inverse non-central chi-squared distribution. The thermal diffusivity that is found by sampling this distribution will always be biased, and averaging of multiple estimated diffusivities will not necessarily improve the estimation. Confidence bounds are constructed to illustrate the uncertainty in the diffusivity using several formulas that are equivalent in the noiseless case. Finally, a different method of averaging, that reduces the uncertainty significantly, is suggested. The methodology is also extended to the case where damping is included, and it is explained how to include the cylindrical geometry. (paper)

  18. Radial thermal diffusivity of toroidal plasma affected by resonant magnetic perturbations

    Kanno, Ryutaro; Nunami, Masanori; Satake, Shinsuke; Takamaru, Hisanori; Okamoto, Masao

    2012-04-01

    We investigate how the radial thermal diffusivity of an axisymmetric toroidal plasma is modified by effect of resonant magnetic perturbations (RMPs), using a drift kinetic simulation code for calculating the thermal diffusivity in the perturbed region. The perturbed region is assumed to be generated on and around the resonance surfaces, and is wedged in between the regular closed magnetic surfaces. It has been found that the radial thermal diffusivity χ r in the perturbed region is represented as χ r = χ r (0) {1 + c r parallel 2 >}. Here r parallel 2 > 1/2 is the strength of the RMPs in the radial directions, means the flux surface average defined by the unperturbed (i.e., original) magnetic field, χ r (0) is the neoclassical thermal diffusivity, and c is a positive coefficient. In this paper, dependence of the coefficient c on parameters of the toroidal plasma is studied in results given by the δ f simulation code solving the drift kinetic equation under an assumption of zero electric field. We find that the dependence of c is given as c ∝ ω b /ν eff m in the low collisionality regime ν eff b , where ν eff is the effective collision frequency, ω b is the bounce frequency and m is the particle mass. In case of ν eff > ω b , the thermal diffusivity χ r evaluated by the simulations becomes close to the neoclassical thermal diffusivity χ r (0) . (author)

  19. Strongly coupled Coulomb systems with positive dust grains: thermal and UV-induced plasmas

    Samarian, A.A.

    2000-01-01

    Full text: A plasma containing macroscopic dust particles or grains (often referred to as a dusty or colloidal or complex plasma) has the feature that grains may be charged by electron or ion flux or by photo- or thermoelectron emission. Electron emission from a grain surface produces a positive charge; capture of electrons produces the reverse effect making the dust grains negatively charged. Most dusty plasma research is concerned with the ordered dust structures (so-called 'plasma crystal') in glow discharges. The dust grains in these experiments were found to carry a negative charge due to the higher mobility of electrons as compared to ions in the discharge plasma. In recent years, in parallel with the study of the properties of plasma crystals under discharge conditions, attempts to obtain a structure from positively charged dust grains have been made, and structure formation processes for various charging mechanisms, particularly thermoelectron emission and photoemission, have been investigated. In this paper we review the essential features of strongly coupled plasmas with positive dust grains. An ordered structure of CeO 2 grains has been experimentally observed in a combustion products jet. The grains were charged positively and suspended in the plasma flow. Their charge is about 10 3 a and the calculated value of a Coulomb coupling parameter Γ is >10, corresponding to a plasma liquid. The ordered structures of Al 2 O 3 dust grains in propellant combustion products plasma have been observed for the first time. These structures were found in the sheath boundary of condensation region. The obtained data let us estimate the value of parameter Γ =3-40, corresponding to the plasma liquid state. The possibility is studied of the formation of ordered dust grain structures in thermal plasma. The range of the required values of the coupling parameter Γ is calculated using the results of diagnostic measurements carried out in thermal plasma with grains of

  20. Non-thermal plasma exhaust aftertreatment: Are all plasmas the same?

    Whealton, J.H.; Hanson, G.R.; Storey, J.M.; Raridon, R.J.; Armfield, J.S.; Bigelow, T.S.; Graves, R.L. [Oak Ridge National Lab., TN (United States)

    1997-12-31

    The authors describe initial experiments employing 5.5 GHz pulsed microwave power, which should result in enhanced chemistry compared to present state-of-the-art plasma aftertreatments by; reducing plasma electric field shielding, increasing availability of atomic nitrogen, exploiting surface charging of dielectrics, avoiding (low field) threshold initiated discharges, and achieving a higher high energy tail on the electron distribution function. As an example, the authors decided to test for NO reduction in N{sub 2}. While this reaction is not a complete description of the exhaust issues by any means, they thought it would demonstrate the technology proposed.

  1. Ion-pair cloud-point extraction: a new method for the determination of water-soluble vitamins in plasma and urine.

    Heydari, Rouhollah; Elyasi, Najmeh S

    2014-10-01

    A novel, simple, and effective ion-pair cloud-point extraction coupled with a gradient high-performance liquid chromatography method was developed for determination of thiamine (vitamin B1 ), niacinamide (vitamin B3 ), pyridoxine (vitamin B6 ), and riboflavin (vitamin B2 ) in plasma and urine samples. The extraction and separation of vitamins were achieved based on an ion-pair formation approach between these ionizable analytes and 1-heptanesulfonic acid sodium salt as an ion-pairing agent. Influential variables on the ion-pair cloud-point extraction efficiency, such as the ion-pairing agent concentration, ionic strength, pH, volume of Triton X-100, extraction temperature, and incubation time have been fully evaluated and optimized. Water-soluble vitamins were successfully extracted by 1-heptanesulfonic acid sodium salt (0.2% w/v) as ion-pairing agent with Triton X-100 (4% w/v) as surfactant phase at 50°C for 10 min. The calibration curves showed good linearity (r(2) > 0.9916) and precision in the concentration ranges of 1-50 μg/mL for thiamine and niacinamide, 5-100 μg/mL for pyridoxine, and 0.5-20 μg/mL for riboflavin. The recoveries were in the range of 78.0-88.0% with relative standard deviations ranging from 6.2 to 8.2%. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Validity of Saha's equation of thermal ionization for negatively charged spherical particles in complex plasmas in thermal equilibrium

    Sodha, M. S.; Mishra, S. K.

    2011-01-01

    The authors have discussed the validity of Saha's equation for the charging of negatively charged spherical particles in a complex plasma in thermal equilibrium, even when the tunneling of the electrons, through the potential energy barrier surrounding the particle is considered. It is seen that the validity requires the probability of tunneling of an electron through the potential energy barrier surrounding the particle to be independent of the direction (inside to outside and vice versa) or in other words the Born's approximation should be valid.

  3. Characteristics of ceramic oxide nanoparticles synthesized using radio frequency produced thermal plasma

    Dhamale, Gayatri D.; Mathe, V.L.; Bhoraskar, S.V.; Ghorui, S.

    2015-01-01

    Thermal plasma devices with their unique processing capabilities due to extremely high temperature and steep temperature gradient play an important role in synthesis of ultrafine powders in the range of 100nm or less. High temperature gas phase synthesis in Radio Frequency (RF) thermal plasma reactor is an attractive route for mass production of refractory nanoparticles, especially in the case of rare earth oxides. Here we report synthesis of Yttrium Oxide (Y_2O_3), Neodymium Oxide (Nd_2O_3) and Aluminum Oxide (Al_2O_3) in an inductively coupled radio frequency thermal plasma reactor. Synthesized nanoparticles find wide application in various fields like gate dielectrics, photocatalytic applications, laser devices and photonics. Nano sized Yttrium oxide, Neodymium Oxide and Aluminum oxide powders were separately synthesized in an RF plasma reactor starting with micron sized irregular shaped precursor powders. The system was operated at 3MHz in atmospheric pressure at different power levels. Synthesized powders were scrapped out from different deposition locations inside the reactor and characterized for their phase, morphology, particle size, crystallinity and other characteristic features. Highly crystalline nature of the synthesized particles, narrow size distribution, location dependent phase formation, and distinct variation in the inherent defect states compared to the bulk are some of the important characteristic features observed

  4. Energy and costs scoping study for plasma pyrolysis thermal processing system

    Sherick, K.E.; Findley, J.E.

    1992-01-01

    The purpose of this study was to provide information in support of an investigation of thermal technologies as possible treatment process for buried wastes at the INEL. Material and energy balances and a cost estimate were generated for a representative plasma torch-based thermal waste treatment system operating in a pyrolysis mode. Two waste streams were selected which are representative of INEL buried wastes, large in volume, and difficult to treat by other technologies. These streams were a solidified nitrate sludge waste stream and a waste/soil mix of other buried waste components. The treatment scheme selected includes a main plasma chamber operating under pyrolyzing conditions; a plasma afterburner to provide additional residence time at high temperature to ensure complete destruction of hazardous organics; an off-gas treatment system; and a incinerator and stack to oxidize carbon monoxide to carbon dioxide and vent the clean, oxidized gases to atmosphere. The material balances generated provide materials flow and equipment duty information of sufficient accuracy to generate initial rough-order-of-magnitude (ROM) system capital and operating cost estimates for a representative plasma thermal processing system

  5. Incineration/vitrification of radioactive wastes and combustion of pyrolysis gases in thermal plasmas

    Girold, Ch.

    1997-03-01

    Two thermal plasma processes used for incineration of radioactive technological wastes (cellulose, plastics, rubber...) have been investigated. First, the different types of radioactive wastes are presented, with a special attention to those which may benefit from a high temperature thermal treatment. The most significant thermal plasma processes, suitable for this goal, are described. Then, the author deals with the post-combustion, in an oxygen plasma jet reactor, of gases from burnable radioactive waste pyrolysis. An experimental planning method as been used to evaluate the combustion performances in the reactor, with a wide range of gas composition and running parameters such as oxygen excess and electrical power. The results of a modeling of kinetics, based on 116 chemicals reactions between 25 species, are compared with experimental values. Finally, an oxygen plasma reactor where the arc is transferred on a basalt melt is experimented. The efficiency of the combustion and the homogeneity of the glass are discussed. The volatility of some glass elements and tracers added to the wastes is also approached in two different ways: by post-trial material balance and by an optical emission spectroscopic method. The author built a diagnostic method that allows the following versus time of the metallic vapours above the melt. (author)

  6. Impact of the thermal effect on the load-carrying capacity of a slipper pair for an aviation axial-piston pump

    Hesheng TANG

    2018-02-01

    Full Text Available A thermal hydraulic model based on the lumped parameter method is presented to analyze the load-carrying capacity of a slipper pair in an aviation axial-piston pump under specified operating conditions. Both theoretical and experimental results are presented to demonstrate the validity of the thermal hydraulic model. The results illustrate that the squeezing force and thermal wedge bearing force are the main factors that affect the film thickness and load-carrying capacity. At high oil temperature and high load pressure, the film thickness decreases with increasing clamping force due to a combined action of the squeezing bearing force and the thermal wedge bearing force, but the load-carrying capacity will increase. An increase of the film thickness is proven to be beneficial under high shaft rotational speed but especially dangerous as it strongly increases the ripple amplitude of the film thickness, which leads to decreasing the load-carrying capacity. The structural parameters of the slipper can be optimized to achieve desired performance, such as the slipper radius ratio and orifice length diameter ratio. To satisfy the requirement of the load-carrying capacity, the slipper radius ratio should be selected from 1.4 to 1.8, and the orifice length diameter ratio should be selected from 4 to 5. Keywords: Aviation axial piston pump, Fluid lubrication, Load-carrying capacity, Slipper pair, Thermal effect

  7. Theoretical investigation of thermophysical properties in two-temperature argon-helium thermal plasma

    Sharma, Rohit; Singh, Kuldip; Singh, Gurpreet

    2011-01-01

    The thermophysical properties of argon-helium thermal plasma have been studied in the temperature range from 5000 to 40 000 K at atmospheric pressure in local thermodynamic equilibrium and non-local thermodynamic equilibrium conditions. Two cases of thermal plasma considered are (i) ground state plasma in which all the atoms and ions are assumed to be in the ground state and (ii) excited state plasma in which atoms and ions are distributed over various possible excited states. The influence of electronic excitation and non-equilibrium parameter θ = T e /T h on thermodynamic properties (composition, degree of ionization, Debye length, enthalpy, and total specific heat) and transport properties (electrical conductivity, electron thermal conductivity, and thermal diffusion ratio) have been studied. Within the framework of Chapman-Enskog method, the higher-order contributions to transport coefficient and their convergence are studied. The influence of different molar compositions of argon-helium plasma mixture on convergence of higher-orders is investigated. Furthermore, the effect of different definitions of Debye length has also been examined for electrical conductivity and it is observed that electrical conductivity with the definition of Debye length (in which only electrons participate in screening) is less than that of the another definition (in which both the electrons and ions participate in screening) and this deviation increases with electron temperature. Finally, the effect of lowering of ionization energy is examined on electron number density, Debye length, and higher-order contribution to electrical conductivity. It is observed that the lowering of the ionization energy affects the electron transport-properties and consequently their higher-order contributions depending upon the value of the non-equilibrium parameter θ.

  8. Growth and male reproduction improvement of non-thermal dielectric barrier discharge plasma treatment on chickens

    Jiao Zhang, Jiao; Luong Huynh, Do; Chandimali, Nisansala; Kang, Tae Yoon; Kim, Nameun; Mok, Young Sun; Kwon, Taeho; Jeong, Dong Kee

    2018-05-01

    This study investigated whether plasma treatment of fertilized eggs before hatching could affect the growth and reproduction of chickens. Three point five-day-incubated fertilized eggs exposed to non-thermal dielectric barrier discharge plasma at 2.81 W of power for 2 min resulted in the highest growth in chickens. Plasma growth-promoting effect was regulated by the reactive oxygen species homeostasis and the improvement of energy metabolism via increasing serum hormones and adenosine triphosphate levels which were resulted from the regulation of genes involved in antioxidant defense, hormone biosynthesis and energetic metabolism. Interestingly, plasma-treated male chickens conspicuously grew faster than females. Further, aspects of male reproductive system (testosterone level and sperm quality) were improved by the plasma treatment but female reproduction (estradiol and progesterone levels, egg-laying rate and egg weight) had no significant changes. Unfortunately, offspring whose parents were the optimal plasma-treated chickens did not show any difference on growth characteristics and failed to inherit excellent growth features from their parents. Our results suggest a new method to improve the growth rate and male reproductive capacity in poultry but it is only effective in the plasma direct-treated generation.

  9. Covariant kinetic dispersion theory of linear transverse waves parallel propagating in magnetized plasmas with thermal anisotropy

    Lazar, M.; Schlickeiser, R.

    2006-01-01

    The properties of transverse waves parallel propagating in magnetized plasmas with arbitrary composition and thermally anisotropic, are investigated on the basis of relativistic Vlasov-Maxwell equations. The transverse dispersion relations for plasmas with arbitrary distribution functions are derived. These dispersion relations describe the linear response of the system to the initial perturbations and thus define all existing linear (transverse) plasma modes in the system. By analytic continuation the dispersion relations in the whole complex frequency plane are constructed. Further analysis is restricted to the important case of anisotropic bi-Maxwellian equilibrium plasma distribution functions. Explicit forms of the relativistically correct transverse dispersion relations are derived that hold for any values of the plasma temperatures and the temperature anisotropy. In the limit of nonrelativistic plasma temperatures the dispersion relations are expressed in terms of plasma dispersion function, however, the dependence on frequency and wave numbers is markedly different from the standard noncovariant nonrelativistic analysis. Only in the strictly unphysical formal limit of an infinitely large speed of light, c→∞, does the nonrelativistic dispersion relations reduce to the standard noncovariant dispersion relations

  10. Near-surface thermal characterization of plasma facing components using the 3-omega method

    Dechaumphai, Edward; Barton, Joseph L.; Tesmer, Joseph R.; Moon, Jaeyun; Wang, Yongqiang; Tynan, George R.; Doerner, Russell P.; Chen, Renkun

    2014-01-01

    Near-surface regime plays an important role in thermal management of plasma facing components in fusion reactors. Here, we applied a technique referred to as the ‘3ω’ method to measure the thermal conductivity of near-surface regimes damaged by ion irradiation. By modulating the frequency of the heating current in a micro-fabricated heater strip, the technique enables the probing of near-surface thermal properties. The technique was applied to measure the thermal conductivity of a thin ion-irradiated layer on a tungsten substrate, which was found to decrease by nearly 60% relative to pristine tungsten for a Cu ion dosage of 0.2 dpa

  11. Propagation of thermal and hydromagnetic waves in an ionizing-recombining hydrogen plasma

    Di Sigalotti, Leonardo G.; Sira, Eloy; Rendon, Otto; Tremola, Ciro; Mendoza-Briceno, Cesar A.

    2004-01-01

    The propagation of thermal and magnetohydrodynamic (MHD) waves in a heat-conducting, hydrogen plasma, threaded by an external uniform magnetic field (B) and in which photoionization and photorecombination [H + +e - H+hν(χ)] processes are progressing, is investigated here using linear analysis. The resulting dispersion equation is solved analytically for varied strength (β<<1 and ∼1) and orientation of the magnetic field, where β denotes the ratio of plasma to magnetic pressures. Application of this model to the interstellar medium shows that heat conduction governs the propagation of thermal waves only at relatively high frequencies regardless of the plasma temperature, strength, and orientation of the magnetic field. When the direction of wave propagation is held perpendicular to B (i.e., k perpendicular B), the magnetosonic phase velocity is closely Alfvenic for β<<1, while for β∼1 both the hydrostatic and magnetic pressures determine the wave velocity. As long as k parallel B, the fast (transverse) magnetosonic wave becomes an Alfven wave for all frequencies independent of the plasma temperature and field strength, while the slow (longitudinal) magnetosonic wave becomes a pure sound wave. Amplification of thermal and MHD waves always occur at low frequencies and preferentially at temperatures for which the plasma is either weakly or partially ionized. Compared to previous analysis for the same hydrogen plasma model with B=0, the presence of the magnetic field makes the functional dependence of the physical quantities span a longer range of frequencies, which becomes progressively longer as the field strength is increased

  12. Atmospheric non-thermal argon-oxygen plasma for sunflower seedling growth improvement

    Matra, Khanit

    2018-01-01

    Seedling growth enhancement of sunflower seeds by DC atmospheric non-thermal Ar-O2 plasma has been proposed. The plasma reactor was simply designed by the composition of multi-pin electrodes bonded on a solderable printed circuit board (PCB) anode. A stable plasma was exhibited in the non-periodical self-pulsing discharge mode during the seed treatment. The experimental results showed that non-thermal plasma treatment had a significant positive effect on the sunflower seeds. Ar-O2 mixed gas ratio, treatment time and power source voltage are the important parameters affecting growth stimulation of sunflower sprouts. In this research, the sunflower seeds treated with 3:3 liters per minute (LPM) of Ar-O2 plasma at a source voltage of 8 kV for 1 min showed the best results in stimulating the seedling growth. The results in this case showed that the dry weight and average shoot length of the sunflower sprouts were 1.79 and 2.69 times higher and heavier than those of the untreated seeds, respectively.

  13. Thermal fluctuation levels of magnetic and electric fields in unmagnetized plasma: The rigorous relativistic kinetic theory

    Yoon, P. H.; Schlickeiser, R.; Kolberg, U.

    2014-01-01

    Any fully ionized collisionless plasma with finite random particle velocities contains electric and magnetic field fluctuations. The fluctuations can be of three different types: weakly damped, weakly propagating, or aperiodic. The kinetics of these fluctuations in general unmagnetized plasmas, governed by the competition of spontaneous emission, absorption, and stimulated emission processes, is investigated, extending the well-known results for weakly damped fluctuations. The generalized Kirchhoff radiation law for both collective and noncollective fluctuations is derived, which in stationary plasmas provides the equilibrium energy densities of electromagnetic fluctuations by the ratio of the respective spontaneous emission coefficient and the true absorption coefficient. As an illustrative example, the equilibrium energy densities of aperiodic transverse collective electric and magnetic fluctuations in an isotropic thermal electron-proton plasmas of density n e are calculated as |δB|=√((δB) 2 )=2.8(n e m e c 2 ) 1/2 g 1/2 β e 7/4 and |δE|=√((δE) 2 )=3.2(n e m e c 2 ) 1/2 g 1/3 β e 2 , where g and β e denote the plasma parameter and the thermal electron velocity in units of the speed of light, respectively. For densities and temperatures of the reionized early intergalactic medium, |δB|=6·10 −18 G and |δE|=2·10 −16 G result

  14. The thermalization of soft modes in non-expanding isotropic quark gluon plasmas

    Blaizot, Jean-Paul, E-mail: jean-paul.blaizot@cea.fr [Institut de Physique Théorique, CNRS/UMR 3681, CEA Saclay, F-91191 Gif-sur-Yvette (France); Liao, Jinfeng [Physics Department and Center for Exploration of Energy and Matter, Indiana University, 2401 N Milo B. Sampson Lane, Bloomington, IN 47408 (United States); RIKEN BNL Research Center, Bldg. 510A, Brookhaven National Laboratory, Upton, NY 11973 (United States); Mehtar-Tani, Yacine [Institute for Nuclear Theory, University of Washington, Seattle, WA 98195-1550 (United States)

    2017-05-15

    We discuss the role of elastic and inelastic collisions and their interplay in the thermalization of the quark–gluon plasma. We consider a simplified situation of a static plasma, spatially uniform and isotropic in momentum space. We focus on the small momentum region, which equilibrates first, and on a short time scale. We obtain a simple kinetic equation that allows for an analytic description of the most important regimes. The present analysis suggests that the formation of a Bose condensate, expected when only elastic collisions are present, is strongly hindered by the inelastic, radiative, processes.

  15. IAEA consultants' meeting on thermal response of plasma facing materials and components

    Janev, R.K.

    1990-07-01

    The present Summary Report contains brief proceedings and the main conclusions and recommendations of the IAEA Consultants' Meeting on ''Thermal Response of Plasma Facing Materials and Components'', which was organized by the IAEA Atomic and Molecular Data Unit and held on June 11-13, 1990, in Vienna, Austria. The Report also includes a categorization and assessment of currently studied plasma facing materials, a classification scheme of material properties data, required in fusion reactor design, and a survey of the urgently needed material properties data. (author)

  16. Development and evaluation of suspension plasma sprayed yttria stabilized zirconia coatings as thermal barriers

    van Every, Kent J.

    The insulating effects from thermal barrier coatings (TBCs) in gas turbine engines allow for increased operational efficiencies and longer service lifetimes. Consequently, improving TBCs can lead to enhanced gas turbine engine performance. This study was conducted to investigate if yttria-stabilized zirconia (YSZ) coatings, the standard industrial choice for TBCs, produced from nano-sized powder could provide better thermal insulation than current commericial YSZ coatings generated using micron-sized powders. The coatings for this research were made via the recently developed suspension plasma spraying (SPS) process. With SPS, powders are suspended in a solvent containing dispersing agents; the suspension is then injected directly into a plasma flow that evaporates the solvent and melts the powder while transporting it to the substrate. Although related to the industrial TBC production method of air plasma spraying (APS), SPS has two important differences---the ability to spray sub-micron diameter ceramic particles, and the ability to alloy the particles with chemicals dissolved in the solvent. These aspects of SPS were employed to generate a series of coatings from suspensions containing ˜100 nm diameter YSZ powder particles, some of which were alloyed with neodymium and ytterbium ions from the solvent. The SPS coatings contained columnar structures not observed in APS TBCs; thus, a theory was developed to explain the formation of these features. The thermal conductivity of the coatings was tested to evaluate the effects of these unique microstructures and the effects of the alloying process. The results for samples in the as-sprayed and heat-treated conditions were compared to conventional YSZ TBCs. This comparison showed that, relative to APS YSZ coatings, the unalloyed SPS samples typically exhibited higher as-sprayed and lower heat-treated thermal conductivities. All thermal conductivity values for the alloyed samples were lower than conventional YSZ TBCs

  17. Study of the thermal effect on silicon surface induced by ion beam from plasma focus device

    Ahmad, Z., E-mail: pscientific5@aec.org.sy [Scientific Service Department, Atomic Energy Commission of Syria, P.O. Box: 6091, Damascus (Syrian Arab Republic); Ahmad, M. [IBA Laboratory, Atomic Energy Commission of Syria, P.O. Box: 6091, Damascus (Syrian Arab Republic); Chemistry Department, Atomic Energy Commission of Syria, P.O. Box: 6091, Damascus (Syrian Arab Republic); Al-Hawat, Sh.; Akel, M. [Physics Department, Atomic Energy Commission of Syria, P.O. Box: 6091, Damascus (Syrian Arab Republic)

    2017-04-01

    Structural modifications in form of ripples and cracks are induced by nitrogen ions from plasma focus on silicon surface. The investigation of such structures reveals correlation between ripples and cracks formation in peripheral region of the melt spot. The reason of such correlation and structure formation is explained as result of thermal effect. Melting and resolidification of the center of irradiated area occur within one micro second of time. This is supported by a numerical simulation used to investigate the thermal effect induced by the plasma focus ion beams on the silicon surface. This simulation provides information about the temperature profile as well as the dynamic of the thermal propagation in depth and lateral directions. In accordance with the experimental observations, that ripples are formed in latter stage after the arrival of last ion, the simulation shows that the thermal relaxation takes place in few microseconds after the end of the ion beam arrival. Additionally, the dependency of thermal propagation and relaxation on the distance of the silicon surface from the anode is presented.

  18. Remelting of metallurgical fines using thermal plasma; Refusao de finos metalurgicos via plasma termico

    Vicente, L C; Neto F, J B.F.; Bender, O W; Collares, M P

    1993-12-31

    A plasma furnace was developed for remelting of ferro alloys and silicon fines. The furnace capacity was about 4 Kg of silicon and power about 50 kW. The fine (20 to 100 mesh) was fed into the furnace directly at the high temperature zone. This system was tested for remelting silicon fines and the results in the recovery of silicon was about 95% and it took place a refine of aluminium and calcium. (author) 10 refs., 4 figs., 2 tabs.

  19. Fundamental limitations of non-thermal plasma processing for internal combustion engine NOx control

    Penetrante, B.M.

    1993-01-01

    This paper discusses the physics and chemistry of non-thermal plasma processing for post-combustion NO x control in internal combustion engines. A comparison of electron beam and electrical discharge processing is made regarding their power consumption, radical production, NO x removal mechanisms, and by product formation. Can non-thermal deNO x operate efficiently without additives or catalysts? How much electrical power does it cost to operate? What are the by-products of the process? This paper addresses these fundamental issues based on an analysis of the electron-molecule processes and chemical kinetics

  20. Synthesis of Ni2B nanoparticles by RF thermal plasma for fuel cell catalyst

    Cheng, Y; Tanaka, M; Watanabe, T; Choi, S Y; Shin, M S; Lee, K H

    2014-01-01

    The catalyst of Ni 2 B nanoparticles was successfully prepared using nickel and boron as precursors with the quenching gas in radio frequency thermal plasmas. The generating of Ni 2 B needs adequate reaction temperature and boron content in precursors. The quenching gas is beneficial for the synthesis of Ni 2 B in RF thermal plasma. The effect of quenching rate, powder feed rate and boron content in feeding powders on the synthesis of nickel boride nanoparticles was studied in this research. The high mass fraction of 28 % of Ni 2 B nanoparticles can be generated at the fixed initial composition of Ni:B = 2:3. Quenching gas is necessary in the synthesis of Ni 2 B nanoaprticles. In addition, the mass fraction of Ni 2 B increases with the increase of quenching gas flow rate and powder feed rate

  1. Thermal responses of tokamak reactor first walls during cyclic plasma burns

    Smith, D.L.; Charak, I.

    1978-01-01

    The CINDA-3G computer code has been adapted to analyze the thermal responses and operating limitations of two fusion reactor first-wall concepts under normal cyclic operation. A component of an LMFBR computer code has been modified and adapted to analyze the ablative behavior of first-walls after a plasma disruption. The first-wall design concepts considered are a forced-circulation water-cooled stainless steel panel with and without a monolithic graphite liner. The thermal gradients in the metal wall and liner have been determined for several burn-cycle scenarios and the extent of surface ablation that results from a plasma disruption has been determined for stainless steel and graphite first surfaces

  2. Production of coloured glass-ceramics from incinerator ash using thermal plasma technology.

    Cheng, T W; Huang, M Z; Tzeng, C C; Cheng, K B; Ueng, T H

    2007-08-01

    Incineration is a major treatment process for municipal solid waste in Taiwan. It is estimated that over 1.5 Mt of incinerator ash are produced annually. This study proposes using thermal plasma technology to treat incinerator ash. Sintered glass-ceramics were produced using quenched vitrified slag with colouring agents added. The experimental results showed that the major crystalline phases developed in the sintered glass-ceramics were gehlenite and wollastonite, but many other secondary phases also appeared depending on the colouring agents added. The physical/mechanical properties, chemical resistance and toxicity characteristic leaching procedure of the coloured glass-ceramics were satisfactory. The glass-ceramic products obtained from incinerator ash treated with thermal plasma technology have great potential for building applications.

  3. Thermal responses of tokamak reactor first walls during cyclic plasma burns

    Smith, D.L.; Charak, I.

    1977-01-01

    The CINDA-3G computer code has been adapted to analyze the thermal responses and operating limitations of two fusion reactor first-wall concepts under normal cyclic operation. A component of an LMFBR computer has been modified and adapted to analyze the ablative behavior of first-walls after a plasma disruption. The first-wall design concepts considered are a forced-circulation water-cooled stainless steel panel with and without a monolithic graphite liner. The thermal gradients in the metal wall and liner have been determined for several burn-cycle scenarios and the extent of surface ablation that results from a plasma disruption has been determined for stainless steel and graphite first surfaces

  4. Thermal loads on tokamak plasma-facing components during normal operation and disruptions

    McGrath, R.T.

    1990-01-01

    Power loadings experienced by tokamak plasma-facing components during normal operation and during off-normal events are discussed. A model for power and particle flow in the tokamak boundary layer is presented and model predictions are compared to infrared measurements of component heating. The inclusion of the full three-dimensional geometry of the components and of the magnetic flux surface is very important in the modeling. Experimental measurements show that misalignment of component armour tile surfaces by only a millimeter can lead to significant localized heating. An application to the design of plasma-facing components for future machines is presented. Finally, thermal loads expected during tokamak disruptions are discussed. The primary problems are surface melting and vaporization due to localized intense heating during the disruption thermal quench and volumetric heating of the component armour and structure due to localised impact of runaway electrons. (author)

  5. Induction of Immunogenic Cell Death with Non-Thermal Plasma for Cancer Immunotherapy

    Lin, Abraham G.

    Even with the recent advancements in cancer immunotherapy, treatments are still associated with debilitating side effects and unacceptable fail rates. Induction of immunogenic cell death (ICD) in tumors is a promising approach to cancer treatment that may overcome these deficiencies. Cells undergoing ICD pathways enhance the interactions between cancerous cells and immune cells of the patient, resulting in the generation of anti-cancer immunity. The goal of this therapy relies on the engagement and reestablishment of the patient's natural immune processes to target and eliminate cancerous cells systemically. The main objective of this research was to determine if non-thermal plasma could be used to elicit immunogenic cancer cell death for cancer immunotherapy. My hypothesis was that plasma induces immunogenic cancer cell death through oxidative stress pathways, followed by development of a specific anti-tumor immune response. This was tested by investigating the interactions between plasma and multiple cancerous cells in vitro and validating anti-tumor immune responses in vivo. Following plasma treatment, two surrogate ICD markers, secreted adenosine triphosphate (ATP) and surface exposed calreticulin (ecto-CRT), were emitted from all three cancerous cell lines tested: A549 lung carcinoma cell line, CNE-1 radiation-resistant nasopharyngeal cell line and CT26 colorectal cancer cell line. When these cells were co-cultured with macrophages, cells of the innate immune system, the tumoricidal activity of macrophages was enhanced, thus demonstrating the immunostimulatory activity of cells undergoing ICD. The underlying mechanisms of plasma-induced ICD were also evaluated. When plasma is generated, four major components are produced: electromagnetic fields, ultraviolet radiation, and charged and neutral reactive species. Of these, we determined that plasma-generated charged and short-lived reactive oxygen species (ROS) were the major effectors of ICD. Following plasma

  6. Analysis of the biological effects of a non-thermal plasma on saccharomyces cerevisiae

    Park, Gyung S.; Baik, Ku Y.; Kim, Jung G.; Kim, Yun J.; Lee, Kyung A.; Jung, Ran J.; Cho, Guang S.

    2012-01-01

    The cellular and the molecular responses of eukaryotic yeast (Saccharomyces cerevisiae) to a non-thermal plasma at atmospheric pressure are analyzed. A plasma device with a dielectric barrier discharge is used in order to understand the mechanisms of the plasma action on eukaryotic microbes. When the yeast cells are exposed to a plasma (at a 2-mm distance) and then cultured on a YPD (yeast extract, peptone, and dextrose) - agar plate, the number of surviving cells is reduced over exposure time. More than a 50% reduction in number is observed after two exposures of 5 minutes' duration. In addition, very small whitish colonies appear after the two exposures. The microscopic analysis indicates that the yeast cells treated with this plasma exposure have rough and shrunken shapes in comparison to the oval shapes with smooth surfaces of the control cells. The profile of proteins analyzed by using 2-dimentional electrophoresis demonstrates that the level of proteins with high molecular weights is increased in plasma-treated cells.

  7. Numerical modeling of disperse material evaporation in axisymmetric thermal plasma reactor

    Stefanović Predrag Lj.

    2003-01-01

    Full Text Available A numerical 3D Euler-Lagrangian stochastic-deterministic (LSD model of two-phase flow laden with solid particles was developed. The model includes the relevant physical effects, namely phase interaction, panicle dispersion by turbulence, lift forces, particle-particle collisions, particle-wall collisions, heat and mass transfer between phases, melting and evaporation of particles, vapour diffusion in the gas flow. It was applied to simulate the processes in thermal plasma reactors, designed for the production of the ceramic powders. Paper presents results of extensive numerical simulation provided (a to determine critical mechanism of interphase heat and mass transfer in plasma flows, (b to show relative influence of some plasma reactor parameters on solid precursor evaporation efficiency: 1 - inlet plasma temperature, 2 - inlet plasma velocity, 3 - particle initial diameter, 4 - particle injection angle a, and 5 - reactor wall temperature, (c to analyze the possibilities for high evaporation efficiency of different starting solid precursors (Si, Al, Ti, and B2O3 powder, and (d to compare different plasma reactor configurations in conjunction with disperse material evaporation efficiency.

  8. Influence of ECR-RF plasma modification on surface and thermal properties of polyester copolymer

    Fray Miroslawa El

    2015-12-01

    Full Text Available In this paper we report a study on influence of radio-frequency (RF plasma induced with electron cyclotron resonance (ECR on multiblock copolymer containing butylene terephthalate hard segments (PBT and butylene dilinoleate (BDLA soft segments. The changes in thermal properties were studied by DSC. The changes in wettability of PBT-BDLA surfaces were studied by water contact angle (WCA. We found that ECR-RF plasma surface treatment for 60 s led to decrease of WCA, while prolonged exposure of plasma led to increase of WCA after N2 and N2O2 treatment up to 70°–80°. The O2 reduced the WCA to 50°–56°. IR measurements confirmed that the N2O2 plasma led to formation of polar groups. SEM investigations showed that plasma treatment led to minor surfaces changes. Collectively, plasma treatment, especially O2, induced surface hydrophilicity what could be beneficial for increased cell adhesion in future biomedical applications of these materials.

  9. Analysis of the step responses of laminar premixed flames to forcing by non-thermal plasma

    Lacoste, Deanna A.

    2016-07-16

    The step responses of lean methane-air flames to non-thermal plasma forcing is reported. The experimental setup consists of an axisymmetric burner, with a nozzle made of a quartz tube. The equivalence ratio is 0.95, allowing stabilization of the flame in a V-shape or an M-shape geometry, over a central stainless steel rod. The plasma is produced by short pulses of 10-ns duration, 8-kV maximum voltage amplitude, applied at 10 kHz. The central rod is used as a cathode, while the anode is a stainless steel ring, fixed on the outer surface of the quartz tube. Plasma forcing is produced by positive or negative steps of plasma. The step response of the flame is investigated through heat release rate (HRR) fluctuations, to facilitate comparisons with flame response to acoustic perturbations. The chemiluminescence of CH* between two consecutive pulses was recorded using an intensified camera equipped with an optical filter to estimate the HRR fluctuations. First, the results show that the flame does not respond to each single plasma pulse, but is affected only by the average plasma power, confirming the step nature of the forcing. The temporal evolutions of HRR are analyzed and the flame transfer functions are determined. A forcing mechanism, as a local increase in the reactivity of the fluid close to the rod, is proposed and compared with numerical simulations. Experiments and numerical simulations are in good qualitative agreement. © 2016.

  10. Thermalization of the quark-gluon plasma and dynamical formation of Bose-Einstein Condensate

    Liao, Jinfeng

    2012-01-01

    We report recent progress on understanding the thermalization of the quark-gluon plasma during the early stage in a heavy ion collision. The initially high overpopulation in the pre-equilibrium gluonic matter (``glasma'') is shown to play a crucial role. The strongly interacting nature (and thus fast evolution) naturally arises as an {\\em emergent property} of this pre-equilibrium matter where the intrinsic coupling is weak but the highly occupied gluon states coherently amplify the scatterin...

  11. Application of Structure-Based Models of Mechanical and Thermal Properties on Plasma Sprayed Coatings

    Vilémová, Monika; Matějíček, Jiří; Mušálek, Radek; Nohava, J.

    2012-01-01

    Roč. 21, 3-4 (2012), s. 372-382 ISSN 1059-9630 R&D Projects: GA MŠk ME 901 Institutional research plan: CEZ:AV0Z20430508 Keywords : analytical model * elastic modulus * finite element modeling * image analysis * modeling of properties * thermal conductivity * water stabilized plasma Subject RIV: JK - Corrosion ; Surface Treatment of Materials Impact factor: 1.481, year: 2012 http://www.springerlink.com/content/3m24812367315142/fulltext. pdf

  12. Chemically different non-thermal plasmas target distinct cell death pathways

    Lunov, Oleg; Zablotskyy, Vitaliy A.; Churpita, Olexandr; Lunova, M.; Jirsa, M.; Dejneka, Alexandr; Kubinová, Šárka

    2017-01-01

    Roč. 7, č. 1 (2017), s. 1-17, č. článku 600. ISSN 2045-2322 Grant - others:AV ČR(CZ) Fellowship J. E. Purkyně Institutional support: RVO:68378271 Keywords : chemically different * non-thermal plasmas * target distinct cell death pathways Subject RIV: BO - Biophysics OBOR OECD: Biophysics Impact factor: 4.259, year: 2016

  13. Cell death induced by ozone and various non-thermal plasmas: therapeutic perspectives and limitations

    Lunov, Oleg; Zablotskyy, Vitaliy A.; Churpita, Olexandr; Chánová, Eliška; Syková, Eva; Dejneka, Alexandr; Kubinová, Šárka

    2014-01-01

    Roč. 4, NOV (2014), "7129-1"-"7129-11" ISSN 2045-2322 R&D Projects: GA MŠk LO1309 Grant - others:AV ČR(CZ) M100101219 Institutional support: RVO:68378271 ; RVO:61389013 ; RVO:68378041 Keywords : cell death * non-thermal plasma * therapeutic perspectives Subject RIV: BO - Biophysics; FH - Neurology (UEM-P); CD - Macromolecular Chemistry (UMCH-V) Impact factor: 5.578, year: 2014

  14. Relativistic self-focusing of intense laser beam in thermal collisionless quantum plasma with ramped density profile

    S. Zare

    2015-04-01

    Full Text Available Propagation of a Gaussian x-ray laser beam has been analyzed in collisionless thermal quantum plasma with considering a ramped density profile. In this density profile due to the increase in the plasma density, an earlier and stronger self-focusing effect is noticed where the beam width oscillates with higher frequency and less amplitude. Moreover, the effect of the density profile slope and the initial plasma density on the laser propagation has been studied. It is found that, by increasing the initial density and the ramp slope, the laser beam focuses faster with less oscillation amplitude, smaller laser spot size and more oscillations. Furthermore, a comparison is made among the laser self-focusing in thermal quantum plasma, cold quantum plasma and classical plasma. It is realized that the laser self-focusing in the quantum plasma becomes stronger in comparison with the classical regime.

  15. Synthesis of ZnO nanopowders by DC thermal plasma for dye-sensitized solar cells

    Lee, Soo-Jung; Choi, Jinsub [Department of Chemical Engineering, Inha University, 253 Yonghyun-dong, Nam-gu, Incheon 402-751 (Korea, Republic of); Park, Dong-Wha, E-mail: dwpark@inha.ac.kr [Department of Chemical Engineering, Inha University, 253 Yonghyun-dong, Nam-gu, Incheon 402-751 (Korea, Republic of)

    2013-05-01

    Highlights: ► ZnO nanopowders were synthesized using DC thermal plasma process. ► Type and flow rate of reaction gas were controlled as experimental variables. ► Various morphologies were identified by changing the reaction gas. ► The photovoltaic performances were promoted by removing the unreacted precursors. ► DSSCs based on 1D nanostructure ZnO show the enhanced energy conversion efficiency. -- Abstract: Zinc oxide (ZnO) nanopowders were synthesized from commercially available micro-sized zinc powders (Aldrich Co., 98%, 10 μm) by a DC thermal plasma process at atmospheric pressure. The micro-sized zinc powders were vaporized in the plasma region, after which the plasma processing equipment was rapidly quenched, resulting in the formation of ZnO nanopowders with a size of less than 300 nm. Two different reaction gases of oxygen and carbon dioxide were used as the oxygen source and each gas flow rate was controlled as a process variable. The obtained ZnO nanopowders were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). All synthesized ZnO nanopowders showed high crystalline wurtzite structures and the differences in their morphologies were strongly dependent on the operating variables. The photocurrent–voltage (J–V) curve of the ZnO nanopowders with a dye of ruthenium (II) 535 bis-TBA (N719, Solaronix) in redox electrolyte showed an overall energy conversion efficiency (η) of 2.54%, demonstrating that the application of the mass-producible ZnO nanopowders by thermal plasma processing to DSSC was feasible.

  16. Parametric analysis of the thermal effects on the divertor in tokamaks during plasma disruptions

    Bruhn, M.L.

    1988-04-01

    Plasma disruptions are an ever present danger to the plasma-facing components in today's tokamak fusion reactors. This threat results from our lack of understanding and limited ability to control this complex phenomenon. In particular, severe energy deposition occurs on the divertor component of the double-null configured tokamak reactor during such disruptions. A hybrid computational model developed to estimate and graphically illustrate global thermal effects of disruptions on the divertor plates is described in detail. The quasi-two-dimensional computer code, TADDPAK (Thermal Analysis Divertor during Disruptions PAcKage), is used to conduct parametric analysis for the TIBER II Tokamak Engineering Test Reactor Design. The dependence of these thermal effects on divertor material choice, disruption pulse length, disruption pulse shape, and the characteristic thickness of the plasma scrape-off layer is investigated for this reactor design. Results and conclusions from this analysis are presented. Improvements to this model and issues that require further investigation are discussed. Cursory analysis for ITER (International Thermonuclear Experimental Reactor) is also presented in the appendix. 75 refs., 49 figs., 10 tabs

  17. Non-thermal plasma technology for the development of antimicrobial surfaces: a review

    Nikiforov, Anton; Deng, Xiaolong; Xiong, Qing; Cvelbar, U.; DeGeyter, N.; Morent, R.; Leys, Christophe

    2016-05-01

    Antimicrobial coatings are in high demand in many fields including the biomaterials and healthcare sectors. Within recent progress in nanoscience and engineering at the nanoscale, preparation of nanocomposite films containing metal nanoparticles (such as silver nanoparticles, copper nanoparticles, zinc oxide nanoparticles) is becoming an important step in manufacturing biomaterials with high antimicrobial activity. Controlled release of antibiotic agents and eliminating free nanoparticles are of equal importance for engineering antimicrobial nanocomposite materials. Compared to traditional chemical ‘wet’ methods, plasma deposition and plasma polymerization are promising approaches for the fabrication of nanocomposite films with the advantages of gas phase dry processes, effective use of chemicals and applicability to various substrates. In this article, we present a short overview of state-of-the-art engineering of antimicrobial materials based on the use of non-thermal plasmas at low and atmospheric pressure.

  18. Richtmyer–Meshkov instability of a thermal interface in a two-fluid plasma

    Bond, D.

    2017-11-03

    We computationally investigate the Richtmyer–Meshkov instability of a density interface with a single-mode perturbation in a two-fluid, ion–electron plasma with no initial magnetic field. Self-generated magnetic fields arise subsequently. We study the case where the density jump across the initial interface is due to a thermal discontinuity, and select plasma parameters for which two-fluid plasma effects are expected to be significant in order to elucidate how they alter the instability. The instability is driven via a Riemann problem generated precursor electron shock that impacts the density interface ahead of the ion shock. The resultant charge separation and motion generates electromagnetic fields that cause the electron shock to degenerate and periodically accelerate the electron and ion interfaces, driving Rayleigh–Taylor instability. This generates small-scale structures and substantially increases interfacial growth over the hydrodynamic case.

  19. Simulation and Experimental Study on Thermal Conductivity of [EMIM][DEP] + H_2 O + SWCNTs Nanofluids as a New Working Pairs

    Li, Chang; Zhao, Zongchang; Zhang, Xiaodong; Li, Tianyu

    2018-03-01

    In this paper, the single-wall carbon nanotubes (SWCNTs) were dispersed into ionic liquid, 1-ethyl-3-methylimidazolium diethylphosphate ([EMIM][DEP]), and its aqueous solution [EMIM][DEP](1) + H2O(2) to enhance the thermal conductivity of base liquids, which will be the promising working pairs for absorption heat pumps and refrigerators. The enhancement effects on thermal conductivity were studied by experiment and molecular dynamic simulation (MD) methods. The thermal conductivities of [EMIM][DEP] + SWCNTs (INF) and [EMIM][DEP](1) + H2O(2) + SWCNT(SNF) both with SWCNT mass fraction of 0.5, 1, and 2 (wt%) were measured by transient hot-wire method. The results indicate that the enhancement ratio of thermal conductivity of INF, and SNF can approach 1.30 when SWCNT is 2 (wt%). Moreover, SWCNTs has a higher enhancement ratio than multi-wall carbon nanotubes (MWCNTs). Density and thermal conductivity of [EMIM][DEP], [EMIM][DEP](1) + H2O(2), INF and SNF systems, together with self-diffusion coefficients of [EMIM]+, [DEP]-, [EMIM][DEP] and water in solution [EMIM][DEP](1) + H2O(2), were investigated by MD simulations. The results indicate that the maximum relative error between the simulated and experimental densities is about 2 %, and the simulated self-diffusion coefficient of [EMIM][DEP] is in the order of magnitude of 10^{-11} m2\\cdot s^{-1}. The average relative deviation for the simulated thermal conductivity of [EMIM][DEP](1) + H2O(2), INF and SNF from experimental ones are 23.57 %, 5 %, and 5 %, respectively. In addition, the contributions of kinetic energy, potential energy, and virial and partial enthalpy terms to thermal conductivity were also calculated. The results indicate that virial term's contribution to thermal conductivity is the maximum, which accounts for 75 % to 80 % of total thermal conductivity.

  20. Thermal conductivity reduction of tungsten plasma facing material due to helium plasma irradiation in PISCES using the improved 3-omega method

    Cui, Shuang [Department of Mechanical and Aerospace Engineering, University of California, San Diego, La Jolla, CA 92093 (United States); Simmonds, Michael [Department of Physics, University of California, San Diego, La Jolla, CA 92093 (United States); Center for Energy Research, University of California, San Diego, La Jolla, CA 92093 (United States); Qin, Wenjing; Ren, Feng [School of Physics and Technology, Wuhan University, Wuhan, Hubei 430072 (China); Tynan, George R. [Department of Mechanical and Aerospace Engineering, University of California, San Diego, La Jolla, CA 92093 (United States); Center for Energy Research, University of California, San Diego, La Jolla, CA 92093 (United States); Doerner, Russell P. [Center for Energy Research, University of California, San Diego, La Jolla, CA 92093 (United States); Chen, Renkun, E-mail: rkchen@ucsd.edu [Department of Mechanical and Aerospace Engineering, University of California, San Diego, La Jolla, CA 92093 (United States); Center for Energy Research, University of California, San Diego, La Jolla, CA 92093 (United States)

    2017-04-01

    The near-surface region of plasma facing material (PFM) plays an important role in thermal management of fusion reactors. In this work, we measured thermal conductivity of tungsten (W) surface layers damaged by He plasma in PISCES at UCSD. We studied the damage effect on both bulk, and thin film, W. We observed that the surface morphology of both bulk and thin film was altered after exposure to He plasma with the fluence of 1 × 10{sup 26} m{sup −2} (bulk) and 2 × 10{sup 24} m{sup −2} (thin film). Transmission electron microscopy (TEM) analysis reveals that the depth of the irradiation damaged layer was approximately 20 nm on the bulk W exposed to He plasma at 773 K for 2000 s. In order to measure the thermal conductivity of this exceedingly thin damaged layer in the bulk W, we adopted the well-established ‘3-omega’ method and employed novel nanofabrication techniques to improve the measurement sensitivity. For the damaged W thin film sample, we measured the reduction in electrical conductivity and used the Wiedemann-Franz (W-F) law to extract the thermal conductivity. Results from both measurements show that thermal conductivity in the damaged layers was reduced by at least ∼80% compared to that of undamaged W. This large reduction in thermal conductivity can be attributed to the scattering of electrons, the dominant heat carriers in W, caused by defects introduced by He plasma irradiation.

  1. The energy partitioning of non-thermal particles in a plasma: the Coulomb logarithm revisited

    Singleton, Robert L Jr; Brown, Lowell S

    2008-01-01

    The charged particle stopping power in a highly ionized and weakly to moderately coupled plasma has been calculated exactly to leading and next-to-leading accuracy in the plasma density by Brown, Preston and Singleton (BPS). Since the calculational techniques of BPS might be unfamiliar to some, and since the same methodology can also be used for other energy transport phenomena, we will review the main ideas behind the calculation. BPS used their stopping power calculation to derive a Fokker-Planck equation, also accurate to leading and next-to-leading orders, and we will also review this. We use this Fokker-Planck equation to compute the electron-ion energy partitioning of a charged particle traversing a plasma. The motivation for this application is ignition for inertial confinement fusion-more energy delivered to the ions means a better chance of ignition, and conversely. It is therefore important to calculate the fractional energy loss to electrons and ions as accurately as possible. One method by which one calculates the electron-ion energy splitting of a charged particle traversing a plasma involves integrating the stopping power dE/dx. However, as the charged particle slows down and becomes thermalized into the background plasma, this method of calculating the electron-ion energy splitting breaks down. As a result, it suffers a systematic error that may be as large as T/E 0 , where T is the plasma temperature and E 0 is the initial energy of the charged particle. The formalism presented here is designed to account for the thermalization process and it provides results that are near-exact.

  2. Thermal-hydraulic and thermo-mechanical design of plasma facing components for SST-1 tokamak

    Chaudhuri, Paritosh; Santra, P.; Chenna Reddy, D.; Parashar, S.K.S.

    2014-01-01

    The Plasma Facing Components (PFCs) are one of the major sub-systems of ssT-1 tokamak. PFC of ssT-1 consisting of divertors, passive stabilizers, baffles and limiters are designed to be compatible for steady state operation. The main consideration in the design of the PFC cooling is the steady state heat removal of up to 1 MW/m 2 . The PFC has been designed to withstand the peak heat fluxes and also without significant erosion such that frequent replacement of the armor is not necessary. Design considerations included 2-D steady state and transient tile temperature distribution and resulting thermal loads in PFC during baking, and cooling, coolant parameters necessary to maintain optimum thermal-hydraulic design, and tile fitting mechanism. Finite Element (FE) models using ANSYS have been developed to carry out the heat transfer and stress analyses of the PFC to understand its thermal and mechanical behaviors. The results of the calculation led to a good understanding of the coolant flow behavior and the temperature distribution in the tube wall and the different parts of the PFC. Thermal analysis of the PFC is carried out with the purpose of evaluating the thermal mechanical behavior of PFCs. The detailed thermal-hydraulic and thermo-mechanical designs of PFCs of ssT-1 are discussed in this paper. (authors)

  3. Simulations of planar non-thermal plasma assisted ignition at atmospheric pressure

    Casey, Tiernan A.

    2016-10-21

    The opportunity for ignition assistance by a pulsed applied voltage is investigated in a canonical one-dimensional configuration. An incipient ignition kernel, formed by localized energy deposition into a lean mixture of methane and air at atmospheric pressure, is subjected to sub-breakdown electric fields (E/N ≈ 100 Td) by a DC potential applied across the domain, resulting in non-thermal behavior of the plasma formed during the discharge. A two-fluid approach is employed to couple thermal neutrals and ions to the non-thermal electrons. A two-temperature plasma mechanism describing gas phase combustion, excitation of neutral species, and high-energy electron kinetics is employed to account for non-thermal effects. Charged species transported from the ignition zone drift rapidly through the domain, augmenting the magnitude of the electric field in the fresh gas during the pulse through a dynamic-electrode effect, which results in an increase in the energy of the electrons in the fresh mixture with increasing time. Enhanced fuel and oxidizer decomposition due to electron impact dissociation and interaction with excited neutrals generate a pool of radicals, mostly O and H, in the fresh gas ahead of the flame\\'s preheat zone. In the configuration considered, the effect of the nanosecond pulse is to increase the mass of fuel burned at equivalent times relative to the unsupported ignition through enhanced radical generation, resulting in an increased heat release rate in the immediate aftermath of the pulse.

  4. Failure Analysis of Multilayered Suspension Plasma-Sprayed Thermal Barrier Coatings for Gas Turbine Applications

    Gupta, M.; Markocsan, N.; Rocchio-Heller, R.; Liu, J.; Li, X.-H.; Östergren, L.

    2018-02-01

    Improvement in the performance of thermal barrier coatings (TBCs) is one of the key objectives for further development of gas turbine applications. The material most commonly used as TBC topcoat is yttria-stabilized zirconia (YSZ). However, the usage of YSZ is limited by the operating temperature range which in turn restricts the engine efficiency. Materials such as pyrochlores, perovskites, rare earth garnets are suitable candidates which could replace YSZ as they exhibit lower thermal conductivity and higher phase stability at elevated temperatures. The objective of this work was to investigate different multilayered TBCs consisting of advanced topcoat materials fabricated by suspension plasma spraying (SPS). The investigated topcoat materials were YSZ, dysprosia-stabilized zirconia, gadolinium zirconate, and ceria-yttria-stabilized zirconia. All topcoats were deposited by TriplexPro-210TM plasma spray gun and radial injection of suspension. Lifetime of these samples was examined by thermal cyclic fatigue and thermal shock testing. Microstructure analysis of as-sprayed and failed specimens was performed with scanning electron microscope. The failure mechanisms in each case have been discussed in this article. The results show that SPS could be a promising route to produce multilayered TBCs for high-temperature applications.

  5. A non-equilibrium simulation of thermal constriction in a cascaded arc hydrogen plasma

    Peerenboom, K S C; Goedheer, W J; Van Dijk, J; Kroesen, G M W

    2014-01-01

    The cascaded arc hydrogen plasma of Pilot-PSI is studied in a non-LTE model. We demonstrate that the effect of vibrationally excited molecules on the heavy-particle-assisted dissociation is crucial for obtaining thermal constriction. To the best of our knowledge, thermal constriction has not been obtained before in a non-LTE simulation. Probably, realistic numerical studies of this type of plasma were hindered by numerical problems, preventing the non-LTE simulations to show characteristic physical mechanisms such as thermal constriction. In this paper we show that with the help of appropriate numerical strategies thermal constriction can be obtained in a non-LTE simulation. To this end, a new source term linearization technique is developed, which ensures physical solutions even near chemical equilibrium where the composition is dominated by chemical source terms. Results of the model are compared with experiments on Pilot-PSI and show good agreement with pressure and voltage measurements in the source. (paper)

  6. Performance Testing of Suspension Plasma Sprayed Thermal Barrier Coatings Produced with Varied Suspension Parameters

    Nicholas Curry

    2015-07-01

    Full Text Available Suspension plasma spraying has become an emerging technology for the production of thermal barrier coatings for the gas turbine industry. Presently, though commercial systems for coating production are available, coatings remain in the development stage. Suitable suspension parameters for coating production remain an outstanding question and the influence of suspension properties on the final coatings is not well known. For this study, a number of suspensions were produced with varied solid loadings, powder size distributions and solvents. Suspensions were sprayed onto superalloy substrates coated with high velocity air fuel (HVAF -sprayed bond coats. Plasma spray parameters were selected to generate columnar structures based on previous experiments and were maintained at constant to discover the influence of the suspension behavior on coating microstructures. Testing of the produced thermal barrier coating (TBC systems has included thermal cyclic fatigue testing and thermal conductivity analysis. Pore size distribution has been characterized by mercury infiltration porosimetry. Results show a strong influence of suspension viscosity and surface tension on the microstructure of the produced coatings.

  7. The Role of Higher-Order Modes on the Electromagnetic Whistler-Cyclotron Wave Fluctuations of Thermal and Non-Thermal Plasmas

    Vinas, Adolfo F.; Moya, Pablo S.; Navarro, Roberto; Araneda, Jamie A.

    2014-01-01

    Two fundamental challenging problems of laboratory and astrophysical plasmas are the understanding of the relaxation of a collisionless plasmas with nearly isotropic velocity distribution functions and the resultant state of nearly equipartition energy density with electromagnetic plasma turbulence. Here, we present the results of a study which shows the role that higher-order-modes play in limiting the electromagnetic whistler-like fluctuations in a thermal and non-thermal plasma. Our main results show that for a thermal plasma the magnetic fluctuations are confined by regions that are bounded by the least-damped higher order modes. We further show that the zone where the whistler-cyclotron normal modes merges the electromagnetic fluctuations shifts to longer wavelengths as the beta(sub e) increases. This merging zone has been interpreted as the beginning of the region where the whistler-cyclotron waves losses their identity and become heavily damped while merging with the fluctuations. Our results further indicate that in the case of nonthermal plasmas, the higher-order modes do not confine the fluctuations due to the effective higher-temperature effects and the excess of suprathermal plasma particles. The analysis presented here considers the second-order theory of fluctuations and the dispersion relation of weakly transverse fluctuations, with wave vectors parallel to the uniform background magnetic field, in a finite temperature isotropic bi-Maxwellian and Tsallis-kappa-like magnetized electron-proton plasma. Our results indicate that the spontaneously emitted electromagnetic fluctuations are in fact enhanced over these quasi modes suggesting that such modes play an important role in the emission and absorption of electromagnetic fluctuations in thermal or quasi-thermal plasmas.

  8. The subtle interplay of elastic and inelastic collisions in the thermalization of the quark–gluon plasma

    Blaizot, Jean-Paul [Theoretical Physics, CEA, Saclay (France); Liao, Jinfeng [Physics Department and Center for Exploration of Energy and Matter, Indiana University, 2401 N Milo B. Sampson Lane, Bloomington, IN 47408 (United States); RIKEN BNL Research Center, Bldg. 510A, Brookhaven National Laboratory, Upton, NY 11973 (United States); Mehtar-Tani, Yacine [Institute for Nuclear Theory, University of Washington, Seattle, WA 98195-1550 (United States)

    2016-12-15

    Using kinetic theory, we analyze the interplay of elastic and inelastic collisions in the thermalization of the quark-gluon plasma. The main focus is the dynamics and equilibration of long wavelength modes.

  9. Application of a plasma-jet for skin antisepsis: analysis of the thermal action of the plasma by laser scanning microscopy

    Lademann, O; Kramer, A; Richter, H; Patzelt, A; Alborova, A; Humme, D; Weltmann, K-D; Hartmann, B; Hinz, P; Koch, S

    2010-01-01

    Recently, it was reported that a plasma-jet could be efficiently applied for the antisepsis of wounds. In this case, the discharge in an argon gas stream was used to produce a so-called ''cold plasma'' on the skin surface. The thermal action of the plasma on the skin was investigated in the present study by means of laser scanning microscopy (LSM) and by histological analysis. Consequently, the plasma beam was moved with a definite velocity at an optimal distance over the skin surface. The structural changes of the tissue were analyzed. It was found by LSM that a thermal damage could be detected only in the upper cell layers of the stratum corneum (SC) at moving velocities of the plasma beam, usually applied in clinical practice. Deeper parts of the SC were not damaged. The structural changes were so superficial that they could be detected only by LSM but not by analysis of the histological sections

  10. Application of pulsed power and power modulation to the non-thermal plasma treatment of hazardous gaseous wastes

    Penetrante, B.M.

    1992-10-01

    Acid rain, global warming, ozone depletion, and smog are preeminent environmental problems facing the world today. Non-thermal plasma techniques offer an innovative approach to the cost-effective solution of these problems. Many potential applications of non-thermal plasmas to air pollution control have already been demonstrated. The use of pulsed power and power modulation is essential to the successful implementation of non-thermal plasma techniques. This paper provides an overview of the most recent developments in non-thermal plasma systems that have been applied to gaseous waste treatment. In the non-thermal plasma approach, the nonequilibrium properties of the plasma are fully exploited. These plasmas are characterized by high electron temperatures, while the gas remains at near ambient temperature and pressure. The energy is directed preferentially to the undesirable components, which are often present in very small concentrations. These techniques utilize the dissociation and ionization of the background gas to produce radicals which, in turn, decompose the toxic compounds. The key to success in the non-thermal plasma approach is to produce a discharge in which the majority of the electrical energy goes into the production of energetic electrons, rather than into gas heating. For example, in a typical application to flue gas cleanup, these electrons produce radicals, such as O and OH, through the dissociation or ionization of molecules such as H 2 O or O 2 . The radicals diffuse through the gas and preferentially oxidize the nitrogen oxides and sulfur oxides to form acids that can then be easily neutralized to form non-toxic, easily-collectible (and commercially salable) compounds. Non-thermal plasmas can be created in essentially two different ways: by electron-beam irradiation, and by electrical discharges

  11. The impact of transient thermal loads on beryllium as plasma facing material

    Spilker, Benjamin Christof

    2017-01-24

    The rising global energy consumption requires a broad research and development approach in the field of energy technology. Besides renewables, nuclear fusion promises an efficient, CO{sub 2} free, no long-term radioactive waste producing, and safe energy source using only deuterium and lithium as primary resources, which are widely abundant. However, several technical challenges have to be overcome before a nuclear fusion power plant can be built. For this purpose, the experimental reactor ITER is currently under construction in France. ITER is intended to demonstrate the scientific and technological feasibility of net energy generation via nuclear fusion. The most heavily loaded components inside a fusion reactor, which are directly facing the fusion plasma, have to be armoured with well suited materials, which need to be able to withstand the high thermal and particle loads for an economically reasonable lifetime. For ITER, beryllium is chosen as plasma facing material for the largest fraction of the inner vacuum vessel, the so called first wall. Tungsten will be applied in the bottom region of the vacuum vessel, the so called divertor, which acts as the exhaust system of the machine. The choice of beryllium as plasma facing material was driven by its outstanding advantages, e.g. the low atomic number assures that eroded wall material does not strongly decrease the fusion plasma performance, while it combines a high thermal conductivity with low chemical sputtering characteristics. However, the relatively low melting temperature of beryllium of 1287 C comprises the risk of amour damage by melting during transient plasma events, such as edge localized modes or plasma disruptions. Even when mitigated, these events put tremendous power densities in the GW m{sup -2} range with durations in the ms scale onto the plasma facing materials. Hence, the performance of the ITER reference beryllium grade S-65 under transient thermal loads was studied within this work. Thereby

  12. The impact of transient thermal loads on beryllium as plasma facing material

    Spilker, Benjamin Christof

    2017-01-01

    The rising global energy consumption requires a broad research and development approach in the field of energy technology. Besides renewables, nuclear fusion promises an efficient, CO_2 free, no long-term radioactive waste producing, and safe energy source using only deuterium and lithium as primary resources, which are widely abundant. However, several technical challenges have to be overcome before a nuclear fusion power plant can be built. For this purpose, the experimental reactor ITER is currently under construction in France. ITER is intended to demonstrate the scientific and technological feasibility of net energy generation via nuclear fusion. The most heavily loaded components inside a fusion reactor, which are directly facing the fusion plasma, have to be armoured with well suited materials, which need to be able to withstand the high thermal and particle loads for an economically reasonable lifetime. For ITER, beryllium is chosen as plasma facing material for the largest fraction of the inner vacuum vessel, the so called first wall. Tungsten will be applied in the bottom region of the vacuum vessel, the so called divertor, which acts as the exhaust system of the machine. The choice of beryllium as plasma facing material was driven by its outstanding advantages, e.g. the low atomic number assures that eroded wall material does not strongly decrease the fusion plasma performance, while it combines a high thermal conductivity with low chemical sputtering characteristics. However, the relatively low melting temperature of beryllium of 1287 C comprises the risk of amour damage by melting during transient plasma events, such as edge localized modes or plasma disruptions. Even when mitigated, these events put tremendous power densities in the GW m"-"2 range with durations in the ms scale onto the plasma facing materials. Hence, the performance of the ITER reference beryllium grade S-65 under transient thermal loads was studied within this work. Thereby, the

  13. Thermal Plasma Spheroidization of High-Nitrogen Stainless Steel Powder Alloys Synthesized by Mechanical Alloying

    Razumov, Nikolay G.; Popovich, Anatoly A.; Wang, QingSheng

    2018-03-01

    This paper presents the results of experimental studies on the treatment of Fe-23Cr-11Mn-1N high-nitrogen stainless steel powder alloys, synthesized by the mechanical alloying (MA) of elemental powders in the flow of a thermal plasma. Fe-23Cr-11Mn-1N high-nitrogen stainless steel powder alloys were prepared by MA in the attritor under an argon atmosphere. For spheroidization of Fe-23Cr-11Mn-1N high-nitrogen stainless steel powder alloys, the TekSphero 15 plant manufactured by Tekna Plasma Systems Inc was used. The studies have shown the possibility of obtaining Fe-23Cr-11Mn-1N high-nitrogen spherical powders steel alloys from the powder obtained by MA. According to the results of a series of experiments, it was found that the results of plasma spheroidization of powders essentially depend on the size of the fraction due to some difference in the particle shape and flowability, and on the gas regime of the plasma torch. It is established that during the plasma spheroidization process, some of the nitrogen leaves the alloy. The loss rate of nitrogen depends on the size of the initial particles.

  14. Optimizing Compliance and Thermal Conductivity of Plasma Sprayed Thermal Barrier Coatings via Controlled Powders and Processing Strategies

    Tan, Yang; Srinivasan, Vasudevan; Nakamura, Toshio; Sampath, Sanjay; Bertrand, Pierre; Bertrand, Ghislaine

    2012-09-01

    The properties and performance of plasma-sprayed thermal barrier coatings (TBCs) are strongly dependent on the microstructural defects, which are affected by starting powder morphology and processing conditions. Of particular interest is the use of hollow powders which not only allow for efficient melting of zirconia ceramics but also produce lower conductivity and more compliant coatings. Typical industrial hollow spray powders have an assortment of densities resulting in masking potential advantages of the hollow morphology. In this study, we have conducted process mapping strategies using a novel uniform shell thickness hollow powder to control the defect microstructure and properties. Correlations among coating properties, microstructure, and processing reveal feasibility to produce highly compliant and low conductivity TBC through a combination of optimized feedstock and processing conditions. The results are presented through the framework of process maps establishing correlations among process, microstructure, and properties and providing opportunities for optimization of TBCs.

  15. A preliminary inter-centre comparison study for photon, thermal neutron and epithermal neutron responses of two pairs of ionisation chambers used for BNCT

    Roca, Antoaneta; Liu, Yuan-Hao; Wojnecki, Cecile; Green, Stuart; Nievaart, Sander; Ghani, Zamir; Moss, Ray

    2009-01-01

    The dual ionisation chamber technique is the recommended method for mixed field dosimetry of epithermal neutron beams. This paper presents initial data from an ongoing inter-comparison study involving two identical pairs of ionisation chambers used at the BNCT facilities of Petten, NL and of University of Birmingham, UK. The goal of this study is to evaluate the photon, thermal neutron and epithermal neutron responses of both pairs of TE(TE) (Exradin T2 type) and Mg(Ar) (Exradin M2 type) ionisation chambers in similar experimental conditions. At this stage, the work has been completed for the M2 type chambers and is intended to be completed for the T2 type chambers in the near future.

  16. Thermal nucleation of kink-antikink pairs in the presence of impurities: The case of a Remoissenet-Peyrard substrate potential

    Woulache, R.L.; Yemele, D.; Kofane, T.

    2005-09-01

    Thermal nucleation of kink-antikink pairs in a nonlinear Klein- Gordon (NKG) model with a Remoissenet-Peyrard (RP) substrate potential in the presence of impurities and coupled to an applied field is analyzed in the limits of moderate temperature and strong damping. Using the Kolmogorov method, the average velocity of particles of the lattice is calculated and its dependence on the intensity of impurities is discussed in connection with the deformability parameter or the shape of the RP substrate potential. Numerical values are carried out by making use of parameters of the hydrogen atom adsorbed in the tungsten and ruthenium substrates. We show that, for large values of the applied field, the presence of impurities in the system makes the nucleation process of kink-antikink pairs more favorable in the high-temperature regime while they contribute to make it less favorable in the low-temperature regime. (author)

  17. The thermal evolution of targets under plasma focus pulsed ion implantation

    Sanchez, G.; Feugeas, J.

    1997-01-01

    Pulsed ion beam implantation with plasma focus has proved to be an effective method of metal surface treatment for tribological purposes. Nevertheless, the pulsed nature and the continuous energy spectrum of the ion beams differ from those of the standard ion implantation processes. In this paper a model of the thermal evolution of the surface layers of stainless steel, titanium and copper, during and after nitrogen and argon ion beam incidence, is presented using the finite-difference method. In the calculations, the geometry and physical characteristics of the ion beams, the single-ion-solid interaction process and the thermal properties of the materials were used. The results showed a strong thermal effect consisting in the generation of transitory heating slopes and heating speeds as high as ∼3600 K μm -1 and ∼40 K ns -1 respectively, with maximum temperatures that can reach even the material evaporation point at the surface layers. The cooling down process, through the thermal conduction mechanism at the target bulk, turns out to be fast enough to produce the complete thermal relaxation of the target in only a few microseconds after the end of the ion beam incidence. The results presented are contrasted with experiments performed in similar conditions to those used in the numerical model. (Author)

  18. Mueller matrix polarimetry on plasma sprayed thermal barrier coatings for porosity measurement.

    Luo, David A; Barraza, Enrique T; Kudenov, Michael W

    2017-12-10

    Yttria-stabilized zirconia (YSZ) is the most widely used material for thermal plasma sprayed thermal barrier coatings (TBCs) used to protect gas turbine engine parts in demanding operation environments. The superior material properties of YSZ coatings are related to their internal porosity level. By quantifying the porosity level, tighter control on the spraying process can be achieved to produce reliable coatings. Currently, destructive measurement methods are widely used to measure the porosity level. In this paper, we describe a novel nondestructive approach that is applicable to classify the porosity level of plasma sprayed YSZ TBCs via Mueller matrix polarimetry. A rotating retarder Mueller matrix polarimeter was used to measure the polarization properties of the plasma sprayed YSZ coatings with different porosity levels. From these measurements, it was determined that a sample's measured depolarization ratio is dependent on the sample's surface roughness and porosity level. To this end, we correlate the depolarization ratio with the samples' surface roughness, as measured by a contact profilometer, as well as the total porosity level, in percentage measured using a micrograph and stereological analysis. With the use of this technique, a full-field and rapid measurement of porosity level can be achieved.

  19. Toluene degradation by non-thermal plasma combined with a ferroelectric catalyst.

    Liang, Wen-Jun; Ma, Lin; Liu, Huan; Li, Jian

    2013-08-01

    Degradation of toluene in a gas by non-thermal plasma with a ferroelectric catalyst was studied at normal temperature and atmospheric pressure. Spontaneous polarization material (BaTiO3) and photocatalyst (TiO2) were added into plasma system simultively. Toluene degradation efficiency and specific energy density during the discharge process were investigated. Furthermore, byproducts and degradation mechanisms of toluene were also investigated. The toluene degradation efficiency increased when non-thermal plasma technology was combined with the catalyst. The toluene degradation efficiencies of the different catalysts tested were in the following order: BaTiO3/TiO2>BaTiO3>TiO2>no catalyst. A mass ratio of 2.38:1 was optimum for the BaTiO3 and TiO2 catalyst. The outlet gas was analyzed by gas chromatography and Fourier transform infrared spectroscopy, and the main compounds detected were CO2, H2O, O3 and benzene ring derivatives. Copyright © 2013 Elsevier Ltd. All rights reserved.

  20. Modelling of ion thermal transport in ergodic region of collisionless toroidal plasma

    Kanno, Ryutaro; Nunami, Masanori; Satake, Shinsuke; Ohyabu, Nobuyoshi; Takamaru, Hisanori; Okamoto, Masao

    2009-09-01

    In recent tokamak experiments it has been found that so-called diffusion theory based on the 'diffusion of magnetic field lines' overestimates the radial energy transport in the ergodic region of the collisionless plasma affected by resonant magnetic perturbations (RMPs), though the RMPs induce chaotic behavior of the magnetic field lines. The result implies that the modelling of the transport should be reconsidered for low collisionality cases. A computer simulation study of transport in the ergodic region is required for understanding fundamental properties of collisionless ergodized-plasmas, estimating the transport coefficients, and reconstructing the modelling of the transport. In this paper, we report the simulation study of thermal transport in the ergodic region under the assumption of neglecting effects of an electric field, impurities and neutrals. Because of the simulations neglecting interactions with different particle-species and saving the computational time, we treat ions (protons) in our numerical-study of the transport. We find that the thermal diffusivity in the ergodic region is extremely small compared to the one predicted by the theory of field-line diffusion and that the diffusivity depends on both the collision frequency and the strength of RMPs even for the collisionless ergodized-plasma. (author)

  1. Preparation of boron-rich aluminum boride nanoparticles by RF thermal plasma

    Choi, Sooseok [Inha University, Department of Chemical Engineering and Regional Innovation Center for Environmental Technology of Thermal Plasma (Korea, Republic of); Matsuo, Jiro; Cheng, Yingying [Tokyo Institute of Technology, Department of Environmental Chemistry and Engineering (Japan); Watanabe, Takayuki, E-mail: watanabe@chemenv.titech.ac.jp [Kyushu University, Department of Chemical Engineering (Japan)

    2013-08-15

    Boron-rich compounds of AlB{sub 12} and AlB{sub 10} nanoparticles were synthesized by a radiofrequency thermal plasma. Aluminum and boron raw powders were evaporated in virtue of high enthalpy of the thermal plasma in upstream region, followed by the formation of aluminum boride nanoparticles in the tail region of plasma flame with rapid quenching. A high production rate of aluminum boride was confirmed by the X-ray diffraction measurement in the case of high input power, high boron content in raw material and helium inner gas. Polyhedral nanoparticles of 20.8 nm in mean size were observed by a transmission electron microscope. In the raw powder mixture of aluminum, titanium, and boron, titanium-boride nanoparticles were synthesized preferentially, because the Gibbs free energy for the boridation of titanium is lower than that of aluminum. Since the nucleation temperature of boron is higher than that of aluminum, the condensation of metal monomers onto boron nuclei results in the formation of boron-rich aluminum boride nanoparticles.

  2. Net emission coefficient for CO–H2 thermal plasmas with the consideration of molecular systems

    Billoux, T.; Cressault, Y.; Gleizes, A.

    2015-01-01

    This paper deals with the calculation of net emission coefficients (NECs) for CO–H 2 thermal plasmas. This task required the elaboration of a complete spectroscopic database including atoms and molecules formed by carbon, oxygen and hydrogen elements. We have used a systematic line by line method to calculate all the main radiative contributions which are the atomic and molecular continua, the atomic lines and the molecular (diatomic and polyatomic) lines. The main diatomic electronic systems for CO–H 2 plasmas and the triatomic molecular bands were considered. We present some variations of the net emission coefficient versus temperature, for various pressures and for two relative proportions of the components. The role of the diatomic molecules is important at temperatures lower than 5000 K whereas the net emission coefficient presents an unusual peak at temperature around 1000 K, due to the presence of the CO 2 molecule presenting a strong infrared radiation. Finally, the results show that the NEC slightly depends on the relative proportion of CO and H 2 . - highlights: • We calculate radiative losses from CO–H 2 thermal plasmas. • We use the up-to-date atomic and molecular databases. • The influence of CO 2 molecule is very important at low temperature. • The relative maximum of the net emission coefficient at low temperature is unusual

  3. Utilize the spectral line pair of the same ionized state ion to measure the ion temperature of tokamak plasma

    Lin Xiaodong

    2000-01-01

    Making use of a Fabry-Perot interferometer driven by a piezoelectric crystal and selecting the suitable separation of plates, the ion temperature is defined by measuring the superimposed profile of the spectral line pair of the same ionized state ions in Tokamak. The advantage of this method is to higher spectral resolution and wider spectral range select

  4. Transport of thermal plasma above the auroral ionosphere in the presence of electrostatic ion-cyclotron turbulence

    V. E. Zakharov

    Full Text Available The electron component of intensive electric currents flowing along the geomagnetic field lines excites turbulence in the thermal magnetospheric plasma. The protons are then scattered by the excited electromagnetic waves, and as a result the plasma is stable. As the electron and ion temperatures of the background plasma are approximately equal each other, here electrostatic ion-cyclotron (EIC turbulence is considered. In the nonisothermal plasma the ion-acoustic turbulence may occur additionally. The anomalous resistivity of the plasma causes large-scale differences of the electrostatic potential along the magnetic field lines. The presence of these differences provides heating and acceleration of the thermal and energetic auroral plasma. The investigation of the energy and momentum balance of the plasma and waves in the turbulent region is performed numerically, taking the magnetospheric convection and thermal conductivity of the plasma into account. As shown for the quasi-steady state, EIC turbulence may provide differences of the electric potential of ΔV≈1–10 kV at altitudes of 500 < h < 10 000 km above the Earth's surface. In the turbulent region, the temperatures of the electrons and protons increase only a few times in comparison with the background values.

    Key words. Magnetospheric physics (electric fields; plasma waves and instabilities

     

  5. An automated method for the analysis of phenolic acids in plasma based on ion-pairing micro-extraction coupled on-line to gas chromatography/mass spectrometry with in-liner derivatisation

    Peters, S.; Kaal, E.; Horsting, I.; Janssen, H.-G.

    2012-01-01

    A new method is presented for the analysis of phenolic acids in plasma based on ion-pairing ‘Micro-extraction in packed sorbent’ (MEPS) coupled on-line to in-liner derivatisation-gas chromatography-mass spectrometry (GC-MS). The ion-pairing reagent served a dual purpose. It was used both to improve

  6. Changing the surface properties on naval steel as result of non-thermal plasma treatment

    Hnatiuc, B.; Sabău, A.; Dumitrache, C. L.; Hnatiuc, M.; Crețu, M.; Astanei, D.

    2016-08-01

    The problem of corrosion, related to Biofouling formation, is an issue with very high importance in the maritime domain. According to new rules, the paints and all the technologies for the conditioning of naval materials must fulfil more restrictive environmental conditions. In order to solve this issue, different new clean technologies have been proposed. Among them, the use of non-thermal plasmas produced at atmospheric pressure plays a very important role. This study concerns the opportunity of plasma treatment for preparation or conditioning of naval steel OL36 type. The plasma reactors chosen for the experiments can operate at atmospheric pressure and are easy to use in industrial conditions. They are based on electrical discharges GlidArc and Spark, which already proved their efficiency for the surface activation or even for coatings of the surface. The non-thermal character of the plasma is ensured by a gas flow blown through the electrical discharges. One power supply has been used for reactors that provide a 5 kV voltage and a maximum current of 100 mA. The modifications of the surface properties and composition have been studied by XPS technique (X-ray Photoelectron Spectroscopy). There were taken into consideration 5 samples: 4 of them undergoing a Mini-torch plasma, a Gliding Spark, a GlidArc with dry air and a GlidArc with CO2, respectively the fifth sample which is the untreated witness. Before the plasma treatment, samples of naval steel were processed in order to obtain mechanical gloss. The time of treatment was chosen to 12 minutes. In the spectroscopic analysis, done on a ULVAC-PHI, Inc. PHI 5000 Versa Probe scanning XPS microprobe, a monocromated Al Kα X-ray source with a spot size of 100 μm2 was used to scan each sample while the photoelectrons were collected at a 45-degree take-off angle. Differences were found between atomic concentrations in each individual case, which proves that the active species produced by each type of plasma affects

  7. Determination of antazoline hydrochloride in rat plasma and excreta by reversed-phase ion-pair chromatography and its application to pharmacokinetics.

    Wang, Rui; Chu, Yanle; Li, Xiaotian; Wan, Baoluo; Yu, Tong; Wang, Linxi; Hao, Lianqi; Guo, Maowen

    2013-12-01

    A reversed-phase ion pair chromatography method with liquid-liquid extraction analytical method was developed and validated for the determination of antazoline hydrochloride in plasma and excreta of rat. The aim of our study was to characterize the preclinical pharmacokinetics and excretion profiles of antazoline hydrochloride in rats after intravenous injection at the dose of 10 mg/kg. Plasma and excreta samples were extracted with ethyl acetate, and phenacetin was used as the internal standard. The result showed that the method is suitable for the quantification of antazoline hydrochloride in plasma and excreta samples. Analysis of accuracy (90.89-112.33%), imprecision (82.5%) showed adequate values. After a single intravenous administration at 10 mg/kg to rats, plasma concentration profile showed a relative fast elimination proceeding with a terminal elimination half-life of 3.53 h. Approximately 61.8 and 14.2% of the administered dose were recovered in urine and bile after 72 and 24 h post-dosing respectively; 5.9% of the administered dose was recovered in feces after 72 h post-dosing. The above results show that the major elimination route is urinary excretion. Copyright © 2013 John Wiley & Sons, Ltd.

  8. Hyper-resistivity and electron thermal conductivity due to destroyed magnetic surfaces in axisymmetric plasma equilibria

    Weening, R. H. [Department of Radiologic Sciences, Thomas Jefferson University, 901 Walnut Street, Philadelphia, Pennsylvania 19107-5233 (United States)

    2012-06-15

    In order to model the effects of small-scale current-driven magnetic fluctuations in a mean-field theoretical description of a large-scale plasma magnetic field B(x,t), a space and time dependent hyper-resistivity {Lambda}(x,t) can be incorporated into the Ohm's law for the parallel electric field E Dot-Operator B. Using Boozer coordinates, a theoretical method is presented that allows for a determination of the hyper-resistivity {Lambda}({psi}) functional dependence on the toroidal magnetic flux {psi} for arbitrary experimental steady-state Grad-Shafranov axisymmetric plasma equilibria, if values are given for the parallel plasma resistivity {eta}({psi}) and the local distribution of any auxiliary plasma current. Heat transport in regions of plasma magnetic surfaces destroyed by resistive tearing modes can then be modeled by an electron thermal conductivity k{sub e}({psi})=({epsilon}{sub 0}{sup 2}m{sub e}/e{sup 2}){Lambda}({psi}), where e and m{sub e} are the electron charge and mass, respectively, while {epsilon}{sub 0} is the permittivity of free space. An important result obtained for axisymmetric plasma equilibria is that the {psi}{psi}-component of the metric tensor of Boozer coordinates is given by the relation g{sup {psi}{psi}}({psi}){identical_to}{nabla}{psi} Dot-Operator {nabla}{psi}=[{mu}{sub 0}G({psi})][{mu}{sub 0}I({psi})]/{iota}({psi}), with {mu}{sub 0} the permeability of free space, G({psi}) the poloidal current outside a magnetic surface, I({psi}) the toroidal current inside a magnetic surface, and {iota}({psi}) the rotational transform.

  9. A numerical model of non-equilibrium thermal plasmas. I. Transport properties

    Zhang, Xiao-Ning; Li, He-Ping; Murphy, Anthony B.; Xia, Wei-Dong

    2013-03-01

    A self-consistent and complete numerical model for investigating the fundamental processes in a non-equilibrium thermal plasma system consists of the governing equations and the corresponding physical properties of the plasmas. In this paper, a new kinetic theory of the transport properties of two-temperature (2-T) plasmas, based on the solution of the Boltzmann equation using a modified Chapman-Enskog method, is presented. This work is motivated by the large discrepancies between the theories for the calculation of the transport properties of 2-T plasmas proposed by different authors in previous publications. In the present paper, the coupling between electrons and heavy species is taken into account, but reasonable simplifications are adopted, based on the physical fact that me/mh ≪ 1, where me and mh are, respectively, the masses of electrons and heavy species. A new set of formulas for the transport coefficients of 2-T plasmas is obtained. The new theory has important physical and practical advantages over previous approaches. In particular, the diffusion coefficients are complete and satisfy the mass conversation law due to the consideration of the coupling between electrons and heavy species. Moreover, this essential requirement is satisfied without increasing the complexity of the transport coefficient formulas. Expressions for the 2-T combined diffusion coefficients are obtained. The expressions for the transport coefficients can be reduced to the corresponding well-established expressions for plasmas in local thermodynamic equilibrium for the case in which the electron and heavy-species temperatures are equal.

  10. Interaction of supra-thermal ions with turbulence in a magnetized toroidal plasma

    Plyushchev, G.

    2009-01-01

    This thesis addresses the interaction of a supra-thermal ion beam with turbulence in the simple magnetized toroidal plasma of TORPEX. The first part of the Thesis deals with the ohmic assisted discharges on TORPEX. The aim of these discharges is the investigation of the open to closed magnetic field line transition. The relevant magnetic diagnostics were developed. Ohmic assisted discharges with a maximum plasma current up to 1 kA are routinely obtained. The equilibrium conditions on the vacuum magnetic field configuration were investigated. In the second part of the Thesis, the design of the fast ion source and detector are discussed. The accelerating electric field needed for the fast ion source was optimized. The fast ion source was constructed and commissioned. To detect the fast ions a specially designed gridded energy analyzer was used. The electron energy distribution function was obtained to demonstrate the efficiency of the detector. The experiments with the fast ion beam were conducted in different plasma regions of TORPEX. In the third part of the Thesis, numerical simulations are used to interpret the measured fast ion beam behavior. It is shown that a simple single particle equation of motion explains the beam behavior in the experiments in the absence of plasma. To explain the fast ion beam experiments with the plasma a turbulent electric field must be used. The model that takes into account this turbulent electrical field qualitatively explains the shape of the fast ion current density profile in the different plasma regions of TORPEX. The vertically elongated fast ion current density profiles are explained by a spread in the fast ion velocity distribution. The theoretically predicted radial fast ion beam spreading due to the turbulent electric field was observed in the experiment. (author)

  11. A numerical model of non-equilibrium thermal plasmas. I. Transport properties

    Zhang XiaoNing; Xia WeiDong [Department of Thermal Science and Energy Engineering, University of Science and Technology of China, Hefei, Anhui Province 230026 (China); Li HePing [Department of Engineering Physics, Tsinghua University, Beijing 100084 (China); Murphy, Anthony B. [CSIRO Materials Science and Engineering, PO Box 218, Lindfield NSW 2070 (Australia)

    2013-03-15

    A self-consistent and complete numerical model for investigating the fundamental processes in a non-equilibrium thermal plasma system consists of the governing equations and the corresponding physical properties of the plasmas. In this paper, a new kinetic theory of the transport properties of two-temperature (2-T) plasmas, based on the solution of the Boltzmann equation using a modified Chapman-Enskog method, is presented. This work is motivated by the large discrepancies between the theories for the calculation of the transport properties of 2-T plasmas proposed by different authors in previous publications. In the present paper, the coupling between electrons and heavy species is taken into account, but reasonable simplifications are adopted, based on the physical fact that m{sub e}/m{sub h} Much-Less-Than 1, where m{sub e} and m{sub h} are, respectively, the masses of electrons and heavy species. A new set of formulas for the transport coefficients of 2-T plasmas is obtained. The new theory has important physical and practical advantages over previous approaches. In particular, the diffusion coefficients are complete and satisfy the mass conversation law due to the consideration of the coupling between electrons and heavy species. Moreover, this essential requirement is satisfied without increasing the complexity of the transport coefficient formulas. Expressions for the 2-T combined diffusion coefficients are obtained. The expressions for the transport coefficients can be reduced to the corresponding well-established expressions for plasmas in local thermodynamic equilibrium for the case in which the electron and heavy-species temperatures are equal.

  12. RACLETTE: a model for evaluating the thermal response of plasma facing components to slow high power plasma transients. Pt. II. Analysis of ITER plasma facing components

    Federici, G.; Raffray, A.R.

    1997-01-01

    For pt.I see ibid., p.85-100, 1997. The transient thermal model RACLETTE (acronym of Rate Analysis Code for pLasma Energy Transfer Transient Evaluation) described in part I of this paper is applied here to analyse the heat transfer and erosion effects of various slow (100 ms-10 s) high power energy transients on the actively cooled plasma facing components (PFCs) of the International Thermonuclear Experimental Reactor (ITER). These have a strong bearing on the PFC design and need careful analysis. The relevant parameters affecting the heat transfer during the plasma excursions are established. The temperature variation with time and space is evaluated together with the extent of vaporisation and melting (the latter only for metals) for the different candidate armour materials considered for the design (i.e., Be for the primary first wall, Be and CFCs for the limiter, Be, W, and CFCs for the divertor plates) and including for certain cases low-density vapour shielding effects. The critical heat flux, the change of the coolant parameters and the possible severe degradation of the coolant heat removal capability that could result under certain conditions during these transients, for example for the limiter, are also evaluated. Based on the results, the design implications on the heat removal performance and erosion damage of the various ITER PFCs are critically discussed and some recommendations are made for the selection of the most adequate protection materials and optimum armour thickness. (orig.)

  13. RACLETTE: a model for evaluating the thermal response of plasma facing components to slow high power plasma transients. Part II: Analysis of ITER plasma facing components

    Federici, Gianfranco; Raffray, A. René

    1997-04-01

    The transient thermal model RACLETTE (acronym of Rate Analysis Code for pLasma Energy Transfer Transient Evaluation) described in part I of this paper is applied here to analyse the heat transfer and erosion effects of various slow (100 ms-10 s) high power energy transients on the actively cooled plasma facing components (PFCs) of the International Thermonuclear Experimental Reactor (ITER). These have a strong bearing on the PFC design and need careful analysis. The relevant parameters affecting the heat transfer during the plasma excursions are established. The temperature variation with time and space is evaluated together with the extent of vaporisation and melting (the latter only for metals) for the different candidate armour materials considered for the design (i.e., Be for the primary first wall, Be and CFCs for the limiter, Be, W, and CFCs for the divertor plates) and including for certain cases low-density vapour shielding effects. The critical heat flux, the change of the coolant parameters and the possible severe degradation of the coolant heat removal capability that could result under certain conditions during these transients, for example for the limiter, are also evaluated. Based on the results, the design implications on the heat removal performance and erosion damage of the variuos ITER PFCs are critically discussed and some recommendations are made for the selection of the most adequate protection materials and optimum armour thickness.

  14. Investigation of EBW Thermal Emission and Mode Conversion Physics in H-Mode Plasmas on NSTX

    Diem, S.J.; Taylor, G.; Efthimion, P.C.; Kugel, H.W.; LeBlanc, B.P.; Phillips, C.K.; Caughman, J.B.; Wilgen, J.B.; Harvey, R.W.; Preinhaelter, J.; Urban, J.; Sabbagh, S.A.

    2008-01-01

    High β plasmas in the National Spherical Torus Experiment (NSTX) operate in the overdense regime, allowing the electron Bernstein wave (EBW) to propagate and be strongly absorbed/emitted at the electron cyclotron resonances. As such, EBWs may provide local electron heating and current drive. For these applications, efficient coupling between the EBWs and electromagnetic waves outside the plasma is needed. Thermal EBW emission (EBE) measurements, via oblique B-X-O double mode conversion, have been used to determine the EBW transmission efficiency for a wide range of plasma conditions on NSTX. Initial EBE measurements in H-mode plasmas exhibited strong emission before the L-H transition, but the emission rapidly decayed after the transition. EBE simulations show that collisional damping of the EBW prior to the mode conversion (MC) layer can significantly reduce the measured EBE for T e < 20 eV, explaining the observations. Lithium evaporation was used to reduce EBE collisional damping near the MC layer. As a result, the measured B-X-O transmission efficiency increased from < 10% (no Li) to 60% (with Li), consistent with EBE simulations.

  15. Partial local thermal equilibrium in a low-temperature hydrogen plasma

    Hey, J.D.; Chu, C.C.; Rash, J.P.S.

    1999-01-01

    If the degree of ionisation is sufficient, competition between de-excitation by electron collisions and radiative decay determines the smallest principal quantum number (the so-called 'thermal limit') above which partial local thermodynamic equilibrium (PLTE) holds under the particular conditions of electron density and temperature. The LTE (PLTE) criteria of Wilson (JQSRT 1962;2:477-90), Griem (Phys Rev 1963;131:1170-6; Plasma Spectroscopy. New York: McGraw-Hill, 1964), Drawin (Z Physik 1969;228: 99-119), Hey (JQSRT 1976;16:69-75), and Fujimoto and McWhirter (Phys Rev A 1990;42:6588-601) are examined as regards their applicability to neutral atoms. For these purposes, we consider for simplicity an idealised, steady-state, homogeneous and primarily optically thin plasma, with some additional comments and numerical estimates on the roles of opacity and of atom-atom collisions. Particularly for atomic states of lower principal quantum number, the first two of the above criteria should be modified quite appreciably before application to neutral radiators in plasmas of low temperature, because of the profoundly different nature of the near-threshold collisional cross-sections for atoms and ions, while the most recent criterion should be applied with caution to PLTE of atoms in cold plasmas in ionisation balance. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  16. The Quark-Gluon Plasma Collective Dynamics and Hard Thermal Loops

    Blaizot, J P; Blaizot, Jean-Paul; Iancu, Edmond

    2002-01-01

    We present a unified description of the high temperature phase of QCD, the so-called quark-gluon plasma, in a regime where the effective gauge coupling $g$ is sufficiently small to allow for weak coupling calculations. The main focuss is the construction of the effective theory for the collective excitations which develop at a typical scale $gT$, which is well separated from the typical energy of single particle excitations which is the temperature $T$. We show that the plasma particles provide a source for long wavelength oscillations of average fields which carry the quantum numbers of the plasma constituents, the quarks and the gluons. To leading order in $g$, the plasma particles obey simple gauge-covariant kinetic equations, whose derivation from the general Dyson-Schwinger equations is outlined. As a by-product, the ``hard thermal loops'' emerge naturally in a physically transparent framework. We show that the collective excitations can be described in terms of classical fields, and develop for these a ...

  17. Non-thermal Power-Law Distributions in Solar and Space Plasmas

    Oka, M.; Battaglia, M.; Birn, J.; Chaston, C. C.; Effenberger, F.; Eriksson, E.; Fletcher, L.; Hatch, S.; Imada, S.; Khotyaintsev, Y. V.; Kuhar, M.; Livadiotis, G.; Miyoshi, Y.; Retino, A.

    2017-12-01

    Particles are accelerated to very high, non-thermal energies in solar and space plasma environments. While energy spectra of accelerated particles often exhibit a power-law and are characterized by the power-law index δ, it remains unclear how particles are accelerated to high energies and how δ is determined. Here, we review previous observations of the power-law index δ in a variety of different plasma environments with a particular focus on sub-relativistic electrons. It appears that in regions more closely related to magnetic reconnection (such as the "above-the-looptop" solar hard X-ray source and the plasma sheet in Earth's magnetotail), the spectra are typically soft (δ> 4). This is in contrast to the typically hard spectra (δuniform in the plasma sheet, while power-law distributions still exist even in quiet times. The role of magnetotail reconnection in the electron power-law formation could therefore be confounded with these background conditions. Because different regions have been studied with different instrumentations and methodologies, we point out a need for more systematic and coordinated studies of power-law distributions for a better understanding of possible scaling laws in particle acceleration as well as their universality.

  18. Plasma fluorination of vertically aligned carbon nanotubes: functionalization and thermal stability.

    Struzzi, Claudia; Scardamaglia, Mattia; Hemberg, Axel; Petaccia, Luca; Colomer, Jean-François; Snyders, Rony; Bittencourt, Carla

    2015-01-01

    Grafting of fluorine species on carbon nanostructures has attracted interest due to the effective modification of physical and chemical properties of the starting materials. Various techniques have been employed to achieve a controlled fluorination yield; however, the effect of contaminants is rarely discussed, although they are often present. In the present work, the fluorination of vertically aligned multiwalled carbon nanotubes was performed using plasma treatment in a magnetron sputtering chamber with fluorine diluted in an argon atmosphere with an Ar/F2 ratio of 95:5. The effect of heavily diluted fluorine in the precursor gas mixture is investigated by evaluating the modifications in the nanotube structure and the electronic properties upon plasma treatment. The existence of oxygen-based grafted species is associated with background oxygen species present in the plasma chamber in addition to fluorine. The thermal stability and desorption process of the fluorine species grafted on the carbon nanotubes during the fluorine plasma treatment were evaluated by combining different spectroscopic techniques.

  19. Plasma fluorination of vertically aligned carbon nanotubes: functionalization and thermal stability

    Claudia Struzzi

    2015-12-01

    Full Text Available Grafting of fluorine species on carbon nanostructures has attracted interest due to the effective modification of physical and chemical properties of the starting materials. Various techniques have been employed to achieve a controlled fluorination yield; however, the effect of contaminants is rarely discussed, although they are often present. In the present work, the fluorination of vertically aligned multiwalled carbon nanotubes was performed using plasma treatment in a magnetron sputtering chamber with fluorine diluted in an argon atmosphere with an Ar/F2 ratio of 95:5. The effect of heavily diluted fluorine in the precursor gas mixture is investigated by evaluating the modifications in the nanotube structure and the electronic properties upon plasma treatment. The existence of oxygen-based grafted species is associated with background oxygen species present in the plasma chamber in addition to fluorine. The thermal stability and desorption process of the fluorine species grafted on the carbon nanotubes during the fluorine plasma treatment were evaluated by combining different spectroscopic techniques.

  20. Non-thermal hydrogen plasma processing effectively increases the antibacterial activity of graphene oxide

    Ke, Zhigang; Ma, Yulong; Zhu, Zhongjie; Zhao, Hongwei; Wang, Qi; Huang, Qing

    2018-01-01

    Graphene-based materials (GMs) are promising antibacterial agents which provide an alternative route to treat pathogenic bacteria with resistance to conventional antibiotics. To further improve their antibacterial activity, many methods have been developed to functionalize the GMs with chemicals. However, the application of additional chemicals may pose potential risks to the environment and human being. Herein, a radio-frequency-driven inductively coupled non-thermal hydrogen plasma was used to treat and reduce graphene oxide (GO) without using any other chemicals, and we found that the plasma-reduced GO (prGO) is with significantly higher bactericidal activity against Escherichia coli. The mechanism of the increased antibacterial activity of prGO is due to that plasma processing breaks down the GO sheets into smaller layers with more rough surface defects, which can thus induce more destructive membrane damages to the bacteria. This work sets another good example, showing that plasma processing is a green and low-cost alternative for GM modification for biomedical applications.

  1. A thermal transport coefficient for ohmic and ICRF plasmas in alcator C-mode

    Daughton, W.; Coppi, B.; Greenwald, M.

    1996-01-01

    The energy confinement in plasmas produced by Alcator C-Mod machine is markedly different from that observed by previous high field compact machines such as Alcator A and C, FT, and more recently FTU. For ohmic plasmas at low and moderate densities, the confinement times routinely exceed those expected from the so-called open-quotes neo-Alcatorclose quotes scaling by a factor as high as three. For both ohmic and ICRF heated plasmas, the energy confinement time increases with the current and is approximately independent of the density. The similarity in the confinement between the ohmic and ICRF regimes opens the possibility that the thermal transport in Alcator C-Mod may be described by one transport coefficient for both regimes. We introduce a modified form of a transport coefficient previously used to describe ohmic plasmas in Alcator C-Mod. The coefficient is inspired by the properties of the so-called open-quotes ubiquitousclose quotes mode that can be excited in the presence of a significant fraction of trapped electrons and also includes the constraint of profile consistency. A detailed series of transport simulations are used to show that the proposed coefficient can reproduce the observed temperature profiles, loop voltage and energy confinement time for both ohmic and ICRF discharges. A total of nearly two dozen ohmic and ICRF Alcator C-Mod discharges have been fit over the range of parameter space available using this transport coefficient

  2. Thermal Structure of Supra-Arcade Plasma in Two Solar Flares

    Reeves, Katharine K.; Savage, Sabrina; McKenzie, David E.; Weber, Mark A.

    2012-01-01

    In this work, we use Hinode/XRT and SDO/AIA data to determine the thermal structure of supra-arcade plasma in two solar flares. The first flare is a Ml.2 flare that occurred on November 5, 2010 on the east limb. This flare was one of a series of flares from AR 11121, published in Reeves & Golub (2011). The second flare is an XI.7 flare that occurred on January 27, 2012 on the west limb. This flare exhibits visible supra-arcade downflows (SADs), where the November 2010 flare does not. For these two flares we combine XRT and AlA data to calculate DEMs of each pixel in the supra-arcade plasma, giving insight into the temperature and density structures in the fan of plasma above the post-flare arcade. We find in each case that the supra-arcade plasma is around 10 MK, and there is a marked decrease in the emission measure in the SADs. We also compare the DEMs calculated with the combined AIA/XRT dataset to those calculated using AIA alone.

  3. Improved oxidation of air pollutants in a non-thermal plasma

    Roland, U.; Holzer, F.; Kopinke, F.-D.

    2002-01-01

    The performance of non-thermal plasma (NTP) for the removal of organic air pollutants (especially in low concentrations) is improved by the introduction of ferroelectric and catalytically active materials into the discharge zone of an NTP reactor. Experiments with model systems (various contaminants and packed-bed materials) have shown that such a modification of a homogeneous gas-phase plasma can overcome the most serious restrictions of the NTP technique at its present state of the art: the incomplete total oxidation (i.e. the low selectivity to CO 2 ) and the energetic inefficiency. Placing a ferroelectric packed-bed material in the discharge zone was shown to result in a lowering of the energy input required. The main effects of plasma catalysis enabled by the introduction of a catalytically active material were an enhanced conversion of pollutants and a higher CO 2 selectivity. These improvements are based on the presence of short-lived oxidising species in the inner volume of porous catalysts. Additionally, the formation of a reservoir of adsorbed oxidants in the NTP zone could be shown. The combination of both modifications (ferroelectric packed-bed materials and plasma catalysis) is a promising method to support the NTP-initiated oxidation of air pollutants

  4. A universal mirror wave-mode threshold condition for non-thermal space plasma environments

    M. P. Leubner

    2002-01-01

    Full Text Available Magnetic fluctuations are recognized in a large variety of space plasmas by increasingly high resolution, in situ observations as mirror wave mode structures. A typical requirement for the excitation of mirror modes is a dominant perpendicular pressure in a high-beta plasma environment. Contrary, we demonstrate from a realistic kinetic analysis how details of the velocity space distributions are of considerable significance for the instability threshold. Introducing the most common characteristics of observed ion and electron distributions by a mixed suprathermal-loss-cone, we derive a universal mirror instability criterion from an energy principle for collisionless plasmas. As a result, the transition from two temperature Maxwellians to realistic non-thermal features provides a strong source for the generation of mirror wave mode activity, reducing drastically the instability threshold. In particular, a number of space-related examples illuminate how the specific structure of the velocity space distribution dominates as a regulating excitation mechanism over the effects related to changes in the plasma parameters.

  5. Improvement of Polytetrafluoroethylene Surface Energy by Repetitive Pulse Non-Thermal Plasma Treatment in Atmospheric Air

    Yang Guoqing; Zhang Guanjun; Zhang Wenyuan

    2011-01-01

    Improvement of polytetrafluoroethylene surface energy by non-thermal plasma treatment is presented, using a nanosecond-positive-edge repetitive pulsed dielectric barrier discharge generator in atmospheric air. The electrical parameters including discharging power, peak and density of micro-discharge current were calculated, and the electron energy was estimated. Surface treatment experiments of polytetrafluoroethylene films were conducted for both different applied voltages and different treating durations. Results show that the surface energy of polytetrafluoroethylene film could be improved to 40 mJ/m 2 or more by plasma treatment. Surface roughness measurement and surface X-ray photoelectron spectroscopy analysis indicate that there are chemical etching and implantation of polar oxygen groups in the sample surface treating process, resulting in the improvement of the sample surface energy. Compared with an AC source of 50 Hz, the dielectric barrier discharges generated by a repetitive pulsed source could provide higher peak power, lower mean power, larger micro-discharge current density and higher electron energy. Therefore, with the same applied peak voltage and treating duration, the improvement of polytetrafluoroethylene surface energy using repetitive pulsed plasma is more effective, and the plasma treatment process based on repetitive pulsed dielectric barrier discharges in air is thus feasible and applicable.

  6. Temperature simulation of thermal plasma melting furnace for disposal of radioactive waste and preliminary research of vitrification formula

    Lin Peng; Lu Yonghong; Xiang Wenyuan; Chen Mingzhou; Liu Xiajie; Qin Yuxin

    2013-01-01

    Radioactive waste treatment techniques currently used in nuclear power plant increase the volume greatly and bring much pressure on final disposal; Thermal plasma treatment as a crucial technique to reduce the waste volume is introduced. How to improve the efficiency of the plasma energy is the limiting factor of concern. In this paper, the temperature field of thermal plasma melting furnace is simulated, the maximal temperature of fixed bed melting furnace is calculated (about 1445 ℃). According to the optional fire-resistant materials, the feasibility of furnace fabrication is discussed. Vitrification formulas for three typical radioactive wastes are tested with their feasibilities being analyzed then. Finally, the prospect of thermal plasma techniques of radioactive waste is discussed, and issues for future study are raised. (authors)

  7. Lyapunov stability and thermal stability of partially relaxed fluids and plasmas

    Elsaesser, K.; Spiess, P.

    1996-01-01

    The relation between the Lyapunov stability of a Hamiltonian system and the thermal stability of a fluid whose temperature is controlled from outside is explored: The free energy as a functional of the correct variables (specific volume, local entropy, and some Clebsch potentials of the velocity) may serve as a Lyapunov functional, depending on the open-quote open-quote Casimirs close-quote close-quote as exchanged quantities. For a multi-species plasma one obtains a sufficient condition for stability: γ(v 2 /c 2 s )-1 s the sound speed. Some features of partially relaxed (T=const) cylindrical plasmas are also discussed. copyright 1996 American Institute of Physics

  8. Non-thermal plasma ethanol reforming in bubbles immersed in liquids

    Levko, Dmitry; Sharma, Ashish; Raja, Laxminarayan L

    2017-01-01

    Ethanol reforming in non-thermal plasma generated in atmospheric-pressure argon bubbles immersed in liquid ethanol/water solution is studied using a self-consistent multi-species fluid model. The influence of the dielectric constant of the liquid on the plasma dynamics and its effect on the generation of active species is analyzed. Several modes of discharge are obtained for large liquid dielectric constant. In these modes, we obtain either an axial streamer or a combination of two simultaneous streamers propagating along the bubble axis and near the liquid wall. The influence of these modes on the production of active species is also studied. The main reactions responsible for the generation of molecular hydrogen and light hydrocarbon species are analyzed. A possible mechanism of hydrogen generation in liquid phase is discussed. (paper)

  9. Synthesis of nanocrystalline magnesium nitride (Mg3N2) powder using thermal plasma

    Kim, Dong-Wook; Kim, Tae-Hee; Park, Hyun-Woo; Park, Dong-Wha

    2011-01-01

    Nanocrystalline magnesium nitride (Mg 3 N 2 ) powder was synthesized from bulk magnesium by thermal plasma at atmospheric pressure. Magnesium vapor was generated through heating the bulk magnesium by DC plasma jet and reacted with ammonia gas. Injecting position and flow rates of ammonia gas were controlled to investigate an ideal condition for Mg 3 N 2 synthesis. The synthesized Mg 3 N 2 was cooled and collected on the chamber wall. Characteristics of the synthesized powders for each experimental condition were analyzed by X-ray diffractometer (XRD), scanning electron microscopy (SEM) and thermogravity analysis (TGA). In absence of NH 3 , magnesium metal powder was formed. The synthesis with NH 3 injection in low temperature region resulted in a formation of crystalline magnesium nitride with trigonal morphology, whereas the mixture of magnesium metal and amorphous Mg 3 N 2 was formed when NH 3 was injected in high temperature region. Also, vaporization process of magnesium was discussed.

  10. A statistical approach for predicting thermal diffusivity profiles in fusion plasmas as a transport model

    Yokoyama, Masayuki

    2014-01-01

    A statistical approach is proposed to predict thermal diffusivity profiles as a transport “model” in fusion plasmas. It can provide regression expressions for the ion and electron heat diffusivities (χ i and χ e ), separately, to construct their radial profiles. An approach that this letter is proposing outstrips the conventional scaling laws for the global confinement time (τ E ) since it also deals with profiles (temperature, density, heating depositions etc.). This approach has become possible with the analysis database accumulated by the extensive application of the integrated transport analysis suite to experiment data. In this letter, TASK3D-a analysis database for high-ion-temperature (high-T i ) plasmas in the LHD (Large Helical Device) is used as an example to describe an approach. (author)

  11. Intermittent thermal plasma acceleration linked to sporadic motions of the magnetopause, first Cluster results

    J.-A. Sauvaud

    Full Text Available This paper presents the first observations with Cluster of a very dense population of thermal ionospheric ions (H+, He+, O+ locally "accelerated" perpendicularly to the local magnetic field in a region adjacent to the magnetopause and on its magnetospheric side. The observation periods follow a long period of very weak magnetic activity. Recurrent motions of the magnetopause are, in the presented cases, unexpectedly associated with the appearance inside closed field lines of recurrent energy structures of ionospheric ions with energies in the 5 eV to  ~1000 eV range. The heaviest ions were detected with the highest energies. Here, the ion behaviour is interpreted as resulting from local electric field enhancements/decreases which adiabatically enhance/lower the bulk energy of a local dense thermal ion population. This drift effect, which is directly linked to magnetopause motions caused by pressure changes, allows for the thermal ions to overcome the satellite potential and be detected by the suprathermal CIS Cluster experiment. When fast flowing, i.e. when detectable, the density (~ 1 cm-3 of these ions from a terrestrial origin is (in the cases presented here largely higher than the local density of ions from magnetospheric/plasma sheet origin which poses again the question of the relative importance of solar and ionospheric sources for the magnetospheric plasma even during very quiet magnetic conditions.

    Key words. Ionosphere (planetary ionosphere; plasma convection Magnetospheric physics (magnetopause, cusp and boundary layers

  12. Application of the thermal plasma technique in the treatment of stone surfaces

    Gonzalez A, Z.I.

    2000-01-01

    The stone materials which form part of the cultural heritage of Mexico, are degraded under the united action of water, atmospheric gases, air pollution, temperature changes and the microorganisms action; provoking on the stone: fissures, crevices, scalings, fragmentations, pulverizations, etc. Therefore, the purpose of this work is to study the possibilities to apply a protective coating on the stone surfaces, previously clean and consolidated, through the thermal plasma technique. The purpose is to analyse the physical and chemical properties of three types of stone materials: quarry, tezontle and chiluca, usually used in constructions of cultural interest such as: historical monuments, churches, sculptures, etc., before and after to be submitted to the action of thermal plasma in order to examine the feasibility in the use of this coating technique in this type of applications. The application of conventional techniques to determine: porosity, density, absorption, low pressure water absorption and crystallization by total immersion of nuclear techniques such as: neutron activation analysis, x-ray diffraction and scanning electron microscopy as well as of instrumental techniques: optical microscopy, mechanical assays of compression, flexure and surface area calculations, allowed to know the chemical and physical properties of the stone material before and after to be treated through the thermal plasma technique, projecting quartz on the stones surface at different distances and current intensity and showing the effect caused by the modifications or surface alterations present by cause of the application of that coating. the obtained results provide a general panorama of the application of this technique as an alternative to the maintenance of the architectural inheritance built in stone. (Author)

  13. The interplay between biological and physical scenarios of bacterial death induced by non-thermal plasma

    Lunov, Oleg; Zablotskyy, Vitaliy A.; Churpita, Olexandr; Jäger, Aleš; Polívka, Leoš; Syková, E.; Dejneka, Alexandr; Kubinová, Šárka

    2016-01-01

    Roč. 82, Mar (2016), s. 71-83 ISSN 0142-9612 R&D Projects: GA MŠk LO1409; GA MŠk(CZ) LM2011026 Grant - others:FUNBIO(XE) CZ.2.16/3.1.00/21568; AV ČR(CZ) Fellowship J. E. Purkyně Institutional support: RVO:68378271 Keywords : non-thermal plasma * bacteria * cytotoxicity * apoptosis * bacterial inactivation * reactive oxygen species (ROS) Subject RIV: BO - Biophysics Impact factor: 8.402, year: 2016

  14. Treatment of the oily waste sludges through thermal plasma in absence of oxygen

    Castaneda J, G.; Pacheco S, J.

    2001-01-01

    The thermal plasma process in absence of oxygen for the degradation of oily waste sludges was evaluated. These residues are commonly generated in the petrochemical industry and are considered hazardous wastes according to the present environmental regulations. The process was operated using difference residence times and the characteristics of the gaseous by products and residual soils were determined. The efficiency of organic matter degradation was 99.99%. The attained volume reduction, under the best conditions was 95.5%. The residual soils were composed of carbon and clays. The residual gases have low molecular weight. The resulting final wastes were non-hazardous and could be disposed of in landfills. (Author)

  15. Transport coefficients for the plasma thermal energy and empirical scaling ''laws''

    Coppi, B.

    1989-01-01

    A set of transport coefficients has been identified for the electron and nuclei thermal energy of plasmas with temperatures in the multi-keV range, taking into account the available experimental information including the temperature spatial profiles and the inferred scaling ''laws'' for the measured energy replacement times. The specific form of these coefficients is suggested by the theory of a mode, so-called ''ubiquitous,'' that can be excited when a significant fraction of the electron population has magnetically trapped orbits. (author)

  16. Modeling and experimental validation of TCE abatement and ozone formation with non thermal plasma

    Vandenbroucke, Arne; Aerts, Robby; Morent, Rino; De Geyter, Nathalie; Bogaerts, Annemie; Leys, Christophe

    2012-01-01

    In this study, the formation of ozone and the abatement of trichloroethylene (TCE) with non thermal plasma was experimentally and theoretically investigated. The model predicts that the ozone formation increases with the energy deposition and decreases with the relative humidity (RH) of the air, which is qualitatively in agreement with experimental data. For an energy deposition of 0.136 J/cm³, the abatement of 1000 ppm TCE in air with 5 % RH is dominated by atomic oxygen and to a lesser exte...

  17. The effect of electron thermal conduction on plasma pressure gradient during reconnection of magnetic field lines

    Chu, T.K.

    1987-12-01

    The interplay of electron cross-field thermal conduction and the reconnection of magnetic field lines around an m = 1 magnetic island prior to a sawtooth crash can generate a large pressure gradient in a boundary layer adjacent to the reconnecting surface, leading to an enhanced gradient of poloidal beta to satisfy the threshold condition for ideal MHD modes. This narrow boundary layer and the short onset time of a sawtooth crash can be supported by fine-grained turbulent processes in a tokamak plasma. 11 refs

  18. Thermal shock tests to qualify different tungsten grades as plasma facing material

    Wirtz, M.; Linke, J.; Loewenhoff, Th; Pintsuk, G.; Uytdenhouwen, I.

    2016-02-01

    The electron beam device JUDITH 1 was used to establish a testing procedure for the qualification of tungsten as plasma facing material. Absorbed power densities of 0.19 and 0.38 GW m-2 for an edge localized mode-like pulse duration of 1 ms were chosen. Furthermore, base temperatures of room temperature, 400 °C and 1000 °C allow investigating the thermal shock performance in the brittle, ductile and high temperature regime. Finally, applying 100 pulses under all mentioned conditions helps qualifying the general damage behaviour while with 1000 pulses for the higher power density the influence of thermal fatigue is addressed. The investigated reference material is a tungsten product produced according to the ITER material specifications. The obtained results provide a general overview of the damage behaviour with quantified damage characteristics and thresholds. In particular, it is shown that the damage strongly depends on the microstructure and related thermo-mechanical properties.

  19. Failure analysis of thermally cycled columnar thermal barrier coatings produced by high-velocity-air fuel and axial-suspension-plasma spraying: A design perspective

    Ganvir, A.; Vaidhyanathan, V.; Markocsan, N.; Gupta, M.; Pala, Zdeněk; Lukáč, František

    2018-01-01

    Roč. 44, č. 3 (2018), s. 3161-3172 ISSN 0272-8842 Institutional support: RVO:61389021 Keywords : Columnar Thermal Barrier Coatings * Axial Suspension Plasma spraying * Thermal Cyclic Fatigue * High Velocity Air Fuel Spraying Subject RIV: JK - Corrosion ; Surface Treatment of Materials OBOR OECD: Coating and films Impact factor: 2.986, year: 2016 https://www.sciencedirect.com/science/article/pii/S0272884217325403

  20. THERMAL PLASMA IN THE GIANT LOBES OF THE RADIO GALAXY CENTAURUS A

    O' Sullivan, S. P.; Feain, I. J.; McClure-Griffiths, N. M.; Ekers, R. D.; Carretti, E. [CSIRO Astronomy and Space Science, ATNF, P.O. Box 76, Epping, NSW 1710 (Australia); Robishaw, T. [Herzberg Institute of Astrophysics, Dominion Radio Astrophysical Observatory, P.O. Box 248, Penticton, BC V2A 6J9 (Canada); Mao, S. A. [National Radio Astronomy Observatory, P.O. Box O, Socorro, NM 87801 (United States); Gaensler, B. M.; Bland-Hawthorn, J. [Sydney Institute for Astronomy, School of Physics, The University of Sydney, NSW 2006 (Australia); Stawarz, L. [Institute of Space and Astronautical Science, JAXA, 3-1-1 Yoshinodai, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan)

    2013-02-20

    We present a Faraday rotation measure (RM) study of the diffuse, polarized, radio emission from the giant lobes of the nearest radio galaxy, Centaurus A. After removal of the smooth Galactic foreground RM component, using an ensemble of background source RMs located outside the giant lobes, we are left with a residual RM signal associated with the giant lobes. We find that the most likely origin of this residual RM is from thermal material mixed throughout the relativistic lobe plasma. The alternative possibility of a thin-skin/boundary layer of magnetoionic material swept up by the expansion of the lobes is highly unlikely since it requires, at least, an order of magnitude enhancement of the swept-up gas over the expected intragroup density on these scales. Strong depolarization observed from 2.3 to 0.96 GHz also supports the presence of a significant amount of thermal gas within the lobes; although depolarization solely due to RM fluctuations in a foreground Faraday screen on scales smaller than the beam cannot be ruled out. Considering the internal Faraday rotation scenario, we find a thermal gas number density of {approx}10{sup -4} cm{sup -3}, implying a total gas mass of {approx}10{sup 10} M {sub Sun} within the lobes. The thermal pressure associated with this gas (with temperature kT {approx} 0.5 keV, obtained from recent X-ray results) is approximately equal to the non-thermal pressure, indicating that over the volume of the lobes, there is approximate equipartition between the thermal gas, radio-emitting electrons, and magnetic field (and potentially any relativistic protons present).

  1. Analysis of phosphorus herbicides by ion-pairing reversed-phase liquid chromatography coupled to inductively coupled plasma mass spectrometry with octapole reaction cell.

    Sadi, Baki B M; Vonderheide, Anne P; Caruso, Joseph A

    2004-09-24

    A reversed phase ion-pairing high performance liquid chromatographic (RPIP-HPLC) method is developed for the separation of two phosphorus herbicides, Glufosinate and Glyphosate as well as Aminomethylphosphonic acid (AMPA), the major metabolite of Glyphosate. Tetrabutylammonium hydroxide is used as the ion-pairing reagent in conjunction with an ammonium acetate/acetic acid buffering system at pH 4.7. An inductively coupled plasma mass spectrometer (ICP-MS) is coupled to the chromatographic system to detect the herbicides at m/z = 31P. Historically, phosphorus has been recognized as one of the elements difficult to analyze in argon plasma. This is due to its relatively high ionization potential (10.5 eV) as well as the inherent presence of the polyatomic interferences 14N16O1H+ and 15N16O+ overlapping its only isotope at m/z = 31. An octapole reaction cell is utilized to minimize the isobaric polyatomic interferences and to obtain the highest signal-to-background ratio. Detection limits were found to be in the low ppt range (25-32 ng/l). The developed method is successfully applied to the analysis of water samples collected from the Ohio River and spiked with a standard compounds at a level of 20 microg/l.

  2. Microstructural modifications induced by rapid thermal annealing in plasma deposited SiOxNyHz films

    Prado, A. del; San Andres, E.; Martil, I.; Gonzalez-Diaz, G.; Bravo, D.; Lopez, F.J.; Fernandez, M.; Martinez, F.L.

    2003-01-01

    The effect of rapid thermal annealing (RTA) processes on the structural properties of SiO x N y H z films was investigated. The samples were deposited by the electron cyclotron resonance plasma method, using SiH 4 , O 2 and N 2 as precursor gases. For SiO x N y H z films with composition close to that of SiO 2 , which have a very low H content, RTA induces thermal relaxation of the lattice and improvement of the structural order. For films of intermediate composition and of compositions close to SiN y H z , the main effect of RTA is the release of H at high temperatures (T>700 deg. C). This H release is more significant in films containing both Si-H and N-H bonds, due to cooperative reactions between both kinds of bonds. In these films the degradation of structural order associated to H release prevails over thermal relaxation, while in those films with only N-H bonds, thermal relaxation predominates. For annealing temperatures in the 500-700 deg. C range, the passivation of dangling bonds by the nonbonded H in the films and the transition from the paramagnetic state to the diamagnetic state of the K center result in a decrease of the density of paramagnetic defects. The H release observed at high annealing temperatures is accompanied by an increase of density of paramagnetic defects

  3. Practical Aspects of Suspension Plasma Spray for Thermal Barrier Coatings on Potential Gas Turbine Components

    Ma, X.; Ruggiero, P.

    2018-04-01

    Suspension plasma spray (SPS) process has attracted extensive efforts and interests to produce fine-structured and functional coatings. In particular, thermal barrier coatings (TBCs) applied by SPS process gain increasing interest due to its potential for superior thermal protection of gas turbine hot sections as compared to conventional TBCs. Unique columnar architectures and nano- and submicrometric grains in the SPS-TBC demonstrated some advantages of thermal shock durability, low thermal conductivity, erosion resistance and strain-tolerant microstructure. This work aimed to look into some practical aspects of SPS processing for TBC applications before it becomes a reliable industry method. The spray capability and applicability of SPS process to achieve uniformity thickness and microstructure on curved substrates were emphasized in designed spray trials to simulate the coating fabrication onto industrial turbine parts with complex configurations. The performances of the SPS-TBCs were tested in erosion, falling ballistic impact and indentational loading tests as to evaluate SPS-TBC performances in simulated turbine service conditions. Finally, a turbine blade was coated and sectioned to verify SPS sprayability in multiple critical sections. The SPS trials and test results demonstrated that SPS process is promising for innovative TBCs, but some challenges need to be addressed and resolved before it becomes an economic and capable industrial process, especially for complex turbine components.

  4. The spherical segmented Langmuir probe in a flowing thermal plasma: numerical model of the current collection

    E. Séran

    2005-07-01

    Full Text Available The segmented Langmuir probe (SLP has been recently proposed by one of the authors (Lebreton, 2002 as an instrument to derive the bulk velocity of terrestrial or planetary plasmas, in addition to the electron density and temperature that are routinely measured by Langmuir probes. It is part of the scientific payload on the DEMETER micro-satellite developed by CNES. The basic concept of this probe is to measure the current distribution over the surface using independent collectors under the form of small spherical caps and to use the angular anisotropy of these currents to obtain the plasma bulk velocity in the probe reference frame. In order to determine the SLP capabilities, we have developed a numerical PIC (Particles In Cell model which provides a tool to compute the distribution of the current collected by a spherical probe. Our model is based on the simultaneous determination of the charge densities in the probe sheath and on the probe surface, from which the potential distribution in the sheath region can be obtained. This method is well adapted to the SLP problem and has some advantages since it provides a natural control of the charge neutrality inside the simulation box, allows independent mesh sizes in the sheath and on the probe surface, and can be applied to complex surfaces. We present in this paper initial results obtained for plasma conditions corresponding to a Debye length equal to the probe radius. These plasma conditions are observed along the Demeter orbit. The model results are found to be in very good agreement with those published by Laframboise (1966 for a spherical probe in a thermal non-flowing plasma. This demonstrates the adequacy of the computation method and of the adjustable numerical parameters (size of the numerical box and mesh, time step, number of macro-particles, etc. for the considered plasma-probe configuration. We also present the results obtained in the case of plasma flowing with mesothermal conditions

  5. The spherical segmented Langmuir probe in a flowing thermal plasma: numerical model of the current collection

    E. Séran

    2005-07-01

    Full Text Available The segmented Langmuir probe (SLP has been recently proposed by one of the authors (Lebreton, 2002 as an instrument to derive the bulk velocity of terrestrial or planetary plasmas, in addition to the electron density and temperature that are routinely measured by Langmuir probes. It is part of the scientific payload on the DEMETER micro-satellite developed by CNES. The basic concept of this probe is to measure the current distribution over the surface using independent collectors under the form of small spherical caps and to use the angular anisotropy of these currents to obtain the plasma bulk velocity in the probe reference frame. In order to determine the SLP capabilities, we have developed a numerical PIC (Particles In Cell model which provides a tool to compute the distribution of the current collected by a spherical probe. Our model is based on the simultaneous determination of the charge densities in the probe sheath and on the probe surface, from which the potential distribution in the sheath region can be obtained. This method is well adapted to the SLP problem and has some advantages since it provides a natural control of the charge neutrality inside the simulation box, allows independent mesh sizes in the sheath and on the probe surface, and can be applied to complex surfaces. We present in this paper initial results obtained for plasma conditions corresponding to a Debye length equal to the probe radius. These plasma conditions are observed along the Demeter orbit. The model results are found to be in very good agreement with those published by Laframboise (1966 for a spherical probe in a thermal non-flowing plasma. This demonstrates the adequacy of the computation method and of the adjustable numerical parameters (size of the numerical box and mesh, time step, number of macro-particles, etc. for the considered plasma-probe configuration. We also present the results obtained in the case of plasma flowing with mesothermal conditions

  6. Light-induced racemization: artifacts in the analysis of the diastereoisomeric pairs of thioridazine 5-sulfoxide in the plasma and urine of patients treated with thioridazine.

    Eap, C B; Souche, A; Koeb, L; Baumann, P

    1991-07-01

    The ring sulfoxidation of thioridazine (THD), a widely used neuroleptic agent, yields two diastereoisomeric pairs, fast- and slow-eluting (FE and SE) thioridazine 5-sulfoxide (THD 5-SO). Until now, studies in which concentrations of these metabolites were measured in THD-treated patients have revealed no significant differences in their concentrations. Preliminary experiments in our laboratory had shown that sunlight and, to a lesser extent, dim daylight led to racemization and probably also to photolysis of the diastereoisomeric pairs as measured by high-performance liquid chromatography. Similar results were also obtained with direct UV light (UV lamp). In appropriate light-protected conditions, THD, northioridazine, mesoridazine, sulforidazine, and FE and SE THD 5-SO were measured in 11 patients treated with various doses of THD for at least 1 week. Significantly higher concentrations of the FE stereoisomeric pair were found. The concentration ratios THD 5-SO (FE)/THD 5-SO (SE) ranged from 0.89 to 1.75 in plasma and from 1.15 to 2.05 in urine. Because it is known that the ring sulfoxide contributes to the cardiotoxicity of the drug even more potently than the parent compound does, these results justify further studies to determine whether there is stereoselectivity in the cardiotoxicity of THD 5-SO.

  7. Method and Process Development of Advanced Atmospheric Plasma Spraying for Thermal Barrier Coatings

    Mihm, Sebastian; Duda, Thomas; Gruner, Heiko; Thomas, Georg; Dzur, Birger

    2012-06-01

    Over the last few years, global economic growth has triggered a dramatic increase in the demand for resources, resulting in steady rise in prices for energy and raw materials. In the gas turbine manufacturing sector, process optimizations of cost-intensive production steps involve a heightened potential of savings and form the basis for securing future competitive advantages in the market. In this context, the atmospheric plasma spraying (APS) process for thermal barrier coatings (TBC) has been optimized. A constraint for the optimization of the APS coating process is the use of the existing coating equipment. Furthermore, the current coating quality and characteristics must not change so as to avoid new qualification and testing. Using experience in APS and empirically gained data, the process optimization plan included the variation of e.g. the plasma gas composition and flow-rate, the electrical power, the arrangement and angle of the powder injectors in relation to the plasma jet, the grain size distribution of the spray powder and the plasma torch movement procedures such as spray distance, offset and iteration. In particular, plasma properties (enthalpy, velocity and temperature), powder injection conditions (injection point, injection speed, grain size and distribution) and the coating lamination (coating pattern and spraying distance) are examined. The optimized process and resulting coating were compared to the current situation using several diagnostic methods. The improved process significantly reduces costs and achieves the requirement of comparable coating quality. Furthermore, a contribution was made towards better comprehension of the APS of ceramics and the definition of a better method for future process developments.

  8. Analysis of the flow structure of a turbulent thermal plasma jet

    Spores, R.A.

    1989-01-01

    The goal of this research project is to attain a better understanding of the fluid mechanics associated with the high temperature jet of a thermal plasma torch. The analysis of a plasma, which has the ability to vaporize anything placed inside it without proper cooling, presents a unique research challenge. Several types of non-intrusive diagnostic techniques has been used to examine the jet from different perspectives. To actually map out the mean gas velocities and turbulence intensities throughout the jet, laser Doppler anemometry has been employed. The plasma gas and entrained air him been seeded separately in order to conditionally sample the two fluids and attain information about the gas mixing process. Both radial and axial turbulence levels have been measured in order to analyze the non-isotropic nature of the jet. A parabolic numerical code has been modified and compared with the obtained experimental results. A new diagnostic technique for plasma torches, which involves the spectral analysis of voltage, optical (temperature), and acoustical (pressure) fluctuations, has been implemented. The acoustical spectrum can provide information about the existence of coherent structures in the flow while the cross correlation of the acoustical signal with the voltage fluctuations can tell one to what extent perturbations of the internal arc affect the external flow. Since temperature is a scalar that is dependent on the flow field, observing temperature fluctuations can likewise help one to understand the mechanics of the flow. Flow visualization of the plasma jet using a high speed video camera has also been undertaken in order to better understand the entrainment process

  9. Ion-pair vortex assisted liquid-liquid microextraction with back extraction coupled with high performance liquid chromatography-UV for the determination of metformin in plasma.

    Alshishani, Anas; Makahleh, Ahmad; Yap, Hui Fang; Gubartallah, Elbaleeq Adam; Salhimi, Salizawati Muhamad; Saad, Bahruddin

    2016-12-01

    A new sample preparation method, ion-pair vortex assisted liquid-liquid microextraction (VALLME-BE), for the determination of a highly polar anti-diabetic drug (metformin) in plasma sample was developed. The VALLME-BE was performed by diluting the plasma in borate buffer and extracted to 150µL 1-octanol containing 0.2M di-(2-ethylhexyl)phosphoric acid as intermediate phase. The drug was next back-extracted into 20µL of 0.075M HCl solution. The effects of pH, ion-pair concentration, type of organic solvent, volume of extraction phases, ionic strength, vortexing and centrifugation times on the extraction efficiency were investigated. The optimum conditions were at pH 9.3, 60s vortexing and 2min centrifugation. The microextract, contained metformin and buformin (internal standard), was directly injected into a HPLC unit using C1 column (250mm×4.6mm×10µm) and detected at 235nm. The method was validated and calibration curve was linear with r 2 >0.99 over the range of 20-2000µgL -1 . The limits of detection and quantitation were 1.4 and 4.1µgL -1 , respectively. The accuracy was within 94.8-108% of the nominal concentration. The relative standard deviation for inter- and intra-day precision was less than 10.8%. The method was conveniently applied for the determination of metformin in plasma samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. Expected energy fluxes onto ITER Plasma Facing Components during disruption thermal quenches from multi-machine data comparisons

    Loarte, A.; Andrew, P.; Matthews, G.F.; Paley, J.; Riccardo, V.; Counsell, G.; Eich, T.; Fuchs, C.; Gruber, O.; Herrmann, A.; Pautasso, G.; Federici, G.; Finken, K.H.; Maddaluno, G.; Whyte, D.

    2005-01-01

    A comparison of the power flux characteristics during the thermal quench of plasma disruptions among various tokamak experiments has been carried out and conclusions for ITER have been drawn. It is generally observed that the energy of the plasma at the thermal quench is much smaller than that of a full performance plasma. The timescales for power fluxes onto PFCs during the thermal quench, as determined by IR measurements, are found to scale with device size but not to correlate with pre-disruptive plasma characteristics. The profiles of the thermal quench power fluxes are very broad for diverted discharges, typically a factor of 5-10 broader than that measured during 'normal' plasma operation, while for limiter discharges this broadening is absent. The combination of all the above factors is used to derive the expected range of power fluxes on the ITER divertor target during the thermal quench. The new extrapolation derived in this paper indicates that the average disruption in ITER will deposit an energy flux approximately one order of magnitude lower than previously thought. The evaluation of the ITER divertor lifetime with these revised specifications is carried out. (author)

  11. Reversible switching of wetting properties and erasable patterning of polymer surfaces using plasma oxidation and thermal treatment

    Rashid, Zeeshan; Atay, Ipek; Soydan, Seren; Yagci, M. Baris; Jonáš, Alexandr; Yilgor, Emel; Kiraz, Alper; Yilgor, Iskender

    2018-05-01

    Polymer surfaces reversibly switchable from superhydrophobic to superhydrophilic by exposure to oxygen plasma and subsequent thermal treatment are demonstrated. Two inherently different polymers, hydrophobic segmented polydimethylsiloxane-urea copolymer (TPSC) and hydrophilic poly(methyl methacrylate) (PMMA) are modified with fumed silica nanoparticles to prepare superhydrophobic surfaces with roughness on nanometer to micrometer scale. Smooth TPSC and PMMA surfaces are also used as control samples. Regardless of their chemical structure and surface topography, all surfaces display completely reversible wetting behavior changing from hydrophobic to hydrophilic and back for many cycles upon plasma oxidation followed by thermal annealing. Influence of plasma power, plasma exposure time, annealing temperature and annealing time on the wetting behavior of polymeric surfaces are investigated. Surface compositions, textures and topographies are characterized by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and white light interferometry (WLI), before and after oxidation and thermal annealing. Wetting properties of the surfaces are determined by measuring their static, advancing and receding water contact angle. We conclude that the chemical structure and surface topography of the polymers play a relatively minor role in reversible wetting behavior, where the essential factors are surface oxidation and migration of polymer molecules to the surface upon thermal annealing. Reconfigurable water channels on polymer surfaces are produced by plasma treatment using a mask and thermal annealing cycles. Such patterned reconfigurable hydrophilic regions can find use in surface microfluidics and optofluidics applications.

  12. Magnetogravitational stability of resistive plasma through porous medium with thermal conduction and FLR corrections

    Vaghela, D.S.; Chhajlani, R.K.

    1989-01-01

    The problem of stability of self gravitating magnetized plasma in porous medium is studied incorporating electrical resistivity, thermal conduction and FLR corrections. Normal mode analysis is applied to derive the dispersion relation. Wave propagation is discussed for parallel and perpendicular directions to the magnetic field. Applying Routh Hurwitz Criterion the stability of the medium is discussed and it is found that Jeans' criterion determines the stability of the medium. Magnetic field, porosity and resistivity of the medium have no effect on Jeans' Criterion in longitudinal direction. For perpendicular direction, in case of resistive medium Jeans' expression remains unaffected by magnetic field but for perfectly conducting medium magnetic field modifies the Jeans' expression to show the stabilizing effect. Thermal conductivity affects the sonic mode by making the process isothermal instead of adiabatic. Porosity of the medium is effective only in case of perpendicular direction to magnetic field for perfectly conducting plasma as it reduces the stabilizing effect of magnetic field. For longitudinal wave propagation, though Finite Larmor Radius (FLR) corrections have no effect on sonic mode but it changes the growth rate for Alfven mode. For transverse wave propagation FLR corrections and porosity affect the Jeans' expression in case of non-viscous medium but viscosity of the medium removes the effect of FLR and porosity on Jeans' condition. (author)

  13. Electrochemical performance of Si-multiwall carbon nanotube nanocomposite anode synthesized by thermal plasma

    Na, Ye-Seul; Yoo, Hyeonseok; Kim, Tae-Hee; Choi, Jinsub; Lee, Wan In; Choi, Sooseok, E-mail: sooseok@jejunu.ac.kr; Park, Dong-Wha, E-mail: dwpark@inha.ac.kr

    2015-07-31

    Lithium-ion (Li-ion) batteries are widely used in electric devices and vehicles. Silicon is a promising material for the anode of Li-ion battery due to high theoretical specific capacity. However, it shows large volume changes during charge–discharge cycles leading to the pulverization of electrode. In order to improve such disadvantage, a multiwall carbon nanotube (MWCNT) has been used with silicon as composite material. In this work, Si-MWCNT nanocomposite was prepared in thermal plasma by attaching silicon nanoparticles to MWCNT column. Electrochemical tests for raw materials and synthesized nanocomposites were carried out. The discharge capacities of silicon, MWCNT, synthesized nanocomposites collected from a reaction tube, and a chamber were 4000, 310, 200, and 1447 mAh/g, respectively. - Highlights: • Si-Multiwall carbon nanotube nanocomposite was synthesized by thermal plasma. • The effect on the collection position of product after experiment was examined. • Cycle performance of electrodes was measured. • Product collected from chamber showed good electrochemical performance.

  14. Understanding CO2 decomposition by thermal plasma with supersonic expansion quench

    Tao, YANG; Jun, SHEN; Tangchun, RAN; Jiao, LI; Pan, CHEN; Yongxiang, YIN

    2018-04-01

    CO2 pyrolysis by thermal plasma was investigated, and a high conversion rate of 33% and energy efficiency of 17% were obtained. The high performance benefited from a novel quenching method, which synergizes the converging nozzle and cooling tube. To understand the synergy effect, a computational fluid dynamics simulation was carried out. A quick quenching rate of 107 K s‑1 could be expected when the pyrolysis gas temperature decreased from more than 3000 to 1000 K. According to the simulation results, the quenching mechanism was discussed as follows: first, the compressible fluid was adiabatically expanded in the converging nozzle and accelerated to sonic speed, and parts of the heat energy converted to convective kinetic energy; second, the sonic fluid jet into the cooling tube formed a strong eddy, which greatly enhanced the heat transfer between the inverse-flowing fluid and cooling tube. These two mechanisms ensure a quick quenching to prevent the reverse reaction of CO2 pyrolysis gas when it flows out from the thermal plasma reactor.

  15. Hydrogen and Carbon Black Production from the Degradation of Methane by Thermal Plasma

    Leila Cottet

    2014-05-01

    Full Text Available Methane gas (CH4 is the main inducer of the so called greenhouse gases effect. Recent scientific research aims to minimize the accumulation of this gas in the atmosphere and to develop processes capable of producing stable materials with added value. Thermal plasma technology is a promising alternative to these applications, since it allows obtaining H2 and solid carbon from CH4, without the parallel formation of byproducts such as CO2 and NOx. In this work, CH4 was degraded by thermal plasma in order to produce hydrogen (H2 and carbon black. The degradation efficiency of CH4, selectivity for H2 production as well as the characterization of carbon black were studied. The best results were obtained in the CH4 flow rate of 5 L min-1 the degradation percentage and the selectivity for H2 production reached 98.8 % and 48.4 %, respectively. At flow rates of less than 5 L min-1 the selectivity for H2 production increases and reaches 91.9 %. The carbon black has obtained amorphous with hydrophobic characteristics and can be marketed to be used in composite material, and can also be activated chemically and/or physically and used as adsorbent material.

  16. The thermal response of the first wall of a fusion reactor blanket to plasma disruptions

    Klippel, H.Th.

    1983-09-01

    Major plasma disruptions in Tokamak power reactors are potentially dangerous because high thermal overloading of the first wall may occur, resulting in melting and evaporation. The present uncertainties of the disruption characteristics, in particular the space and time dependence of the energy deposition, lead to a wide variation in the prospective surface energy loads. The thermal response of a first wall of aluminium, stainless steel and of graphite subjected to disruption energy loads up to 1000 J cm -2 has been analysed including the effects of melting and surface evaporation, vapour recondensation, vapour shielding, and the moving of the surface boundary caused by the evaporation. A special calculation model has been developed for this purpose. The main results are the following: by values of local transient energy depositions over 1500 J cm -2 bare stainless steel walls are damaged severely. Further calculations are needed to estimate the endurance limit of several candidate first wall materials. Applications of coatings on surfaces need special attention. For the reference INTOR disruption (approx. 100 J cm -2 ) evaporation is not significant. The effect of vapour shielding on evaporation has been found to be significant. The effect on melting is less pronounced. In a complete analysis the stability and dynamic behaviour of the melted layer under electromagnetic forces should be included. Also a reliable set of plasma disruption characteristics should be gathered

  17. Influence of Bondcoat Spray Process on Lifetime of Suspension Plasma-Sprayed Thermal Barrier Coatings

    Gupta, M.; Markocsan, N.; Li, X.-H.; Östergren, L.

    2018-01-01

    Development of thermal barrier coatings (TBCs) manufactured by suspension plasma spraying (SPS) is of high commercial interest as SPS has been shown capable of producing highly porous columnar microstructures similar to the conventionally used electron beam-physical vapor deposition. However, lifetime of SPS coatings needs to be improved further to be used in commercial applications. The bondcoat microstructure as well as topcoat-bondcoat interface topography affects the TBC lifetime significantly. The objective of this work was to investigate the influence of different bondcoat deposition processes for SPS topcoats. In this work, a NiCoCrAlY bondcoat deposited by high velocity air fuel (HVAF) was compared to commercial vacuum plasma-sprayed NiCoCrAlY and PtAl diffusion bondcoats. All bondcoat variations were prepared with and without grit blasting the bondcoat surface. SPS was used to deposit the topcoats on all samples using the same spray parameters. Lifetime of these samples was examined by thermal cyclic fatigue testing. Isothermal heat treatment was performed to study bondcoat oxidation over time. The effect of bondcoat deposition process and interface topography on lifetime in each case has been discussed. The results show that HVAF could be a suitable process for bondcoat deposition in SPS TBCs.

  18. Surface modification of biphasic calcium phosphate scaffolds by non-thermal atmospheric pressure nitrogen and air plasma treatment for improving osteoblast attachment and proliferation

    Choi, Yu-Ri; Kwon, Jae-Sung; Song, Doo-Hoon; Choi, Eun Ha; Lee, Yong-Keun; Kim, Kyoung-Nam; Kim, Kwang-Mahn

    2013-01-01

    Surface modifications induced by non-thermal plasma have been used extensively in biomedical applications. The attachment and proliferation of osteoblast cells are important in bone tissue engineering using scaffolds. Hence the effect of non-thermal plasma on hydroxyapatite/β-tri-calcium phosphate (HA/β-TCP) scaffolds in terms of improving osteoblast attachment and proliferation was investigated. Experimental groups were treated with non-thermal plasma for 10 min and 20 min and a control group was not treated with non-thermal plasma. For surface chemistry analysis, X-ray photoelectron spectroscopy (XPS) analysis was carried out. The hydrophilicity was determined from contact angle measurement on the surface. Atomic force microscopy analysis (AFM) was used to test the change in surface roughness and cell attachment and proliferation were evaluated using MC3T3-E1 osteoblast cells. XPS spectra revealed a decreased amount of carbon on the surface of the plasma-treated sample. The contact angle was also decreased following plasma treatment, indicating improved hydrophilicity of plasma-treated surfaces compared to the untreated disc. A significant increase in MC3T3E-1 cell attachment and proliferation was noted on plasma-treated samples as compared to untreated specimens. The results suggest that non-thermal atmospheric pressure nitrogen and air plasma treatments provide beneficial surface characteristics on HA/β-TCP scaffolds. - Highlights: ► Non-thermal plasma increased OH- and decreased C on biphasic scaffold. ► Non-thermal plasma had no effect on surface roughness. ► Non-thermal plasma resulted in hydrophilic surface. ► Non-thermal plasma resulted in better cell attachment and proliferation. ► Non-thermal plasma treatment on biphasic scaffold is useful for tissue engineering

  19. Effects of background fluid on the efficiency of inactivating yeast with non-thermal atmospheric pressure plasma.

    Young-Hyo Ryu

    Full Text Available Non-thermal plasma at atmospheric pressure has been actively applied to sterilization. However, its efficiency for inactivating microorganisms often varies depending on microbial species and environments surrounding the microorganisms. We investigated the influence of environmental factors (surrounding media on the efficiency of microbial inactivation by plasma using an eukaryotic model microbe, Saccharomyces cerevisiae, to elucidate the mechanisms for differential efficiency of sterilization by plasma. Yeast cells treated with plasma in water showed the most severe damage in viability and cell morphology as well as damage to membrane lipids, and genomic DNA. Cells in saline were less damaged compared to those in water, and those in YPD (Yeast extract, Peptone, Dextrose were least impaired. HOG1 mitogen activated protein kinase was activated in cells exposed to plasma in water and saline. Inactivation of yeast cells in water and saline was due to the acidification of the solutions by plasma, but higher survival of yeast cells treated in saline may have resulted from the additional effect related to salt strength. Levels of hydroxyl radical (OH· produced by plasma were the highest in water and the lowest in YPD. This may have resulted in differential inactivation of yeast cells in water, saline, and YPD by plasma. Taken together, our data suggest that the surrounding media (environment can crucially affect the outcomes of yeast cell plasma treatment because plasma modulates vital properties of media, and the toxic nature of plasma can also be altered by the surrounding media.

  20. Pyrite-enhanced methylene blue degradation in non-thermal plasma water treatment reactor

    Benetoli, Luis Otavio de Brito, E-mail: luskywalcker@yahoo.com.br [Departamento de Quimica, Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil); Cadorin, Bruno Mena; Baldissarelli, Vanessa Zanon [Departamento de Quimica, Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil); Geremias, Reginaldo [Departamento de Ciencias Rurais, Universidade Federal de Santa Catarina (UFSC), Curitibanos, SC (Brazil); Goncalvez de Souza, Ivan [Departamento de Quimica, Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil); Debacher, Nito Angelo, E-mail: debacher@qmc.ufsc.br [Departamento de Quimica, Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2012-10-30

    Highlights: Black-Right-Pointing-Pointer We use O{sub 2} as the feed gas and pyrite was added to the non-thermal plasma reactor. Black-Right-Pointing-Pointer The methylene blue removal by NTP increased in the presence of pyrite. Black-Right-Pointing-Pointer The total organic carbon content decreased substantially. Black-Right-Pointing-Pointer The acute toxicity test showed that the treated solution is not toxic. Black-Right-Pointing-Pointer The dye degradation occurs via electron impact as well as successive hydroxylation. - Abstract: In this study, methylene blue (MB) removal from an aqueous phase by electrical discharge non-thermal plasma (NTP) over water was investigated using three different feed gases: N{sub 2}, Ar, and O{sub 2}. The results showed that the dye removal rate was not strongly dependent on the feed gas when the electrical current was kept the same for all gases. The hydrogen peroxide generation in the water varied according to the feed gas (N{sub 2} < Ar < O{sub 2}). Using O{sub 2} as the feed gas, pyrite was added to the reactor in acid medium resulting in an accentuated increase in the dye removal, which suggests that pyrite acts as a Fenton-like catalyst. The total organic carbon (TOC) content of the dye solution decreased slightly as the plasma treatment time increased, but in the presence of the pyrite catalyst the TOC removal increased substantially. The acute toxicity test using Artemia sp. microcrustaceans showed that the treated solution is not toxic when Ar, O{sub 2} or O{sub 2}-pyrite is employed. Electrospray ionization mass spectrometry analysis (ESI-MS) of the treated samples indicated that the dye degradation occurs via high energy electron impact as well as successive hydroxylation in the benzene rings of the dye molecules.

  1. Saturated Resin Ectopic Regeneration by Non-Thermal Dielectric Barrier Discharge Plasma

    Chunjing Hao

    2017-11-01

    Full Text Available Textile dyes are some of the most refractory organic compounds in the environment due to their complex and various structure. An integrated resin adsorption/Dielectric Barrier Discharge (DBD plasma regeneration was proposed to treat the indigo carmine solution. It is the first time to report ectopic regeneration of the saturated resins by non-thermal Dielectric Barrier Discharge. The adsorption/desorption efficiency, surface functional groups, structural properties, regeneration efficiency, and the intermediate products between gas and liquid phase before and after treatment were investigated. The results showed that DBD plasma could maintain the efficient adsorption performance of resins while degrading the indigo carmine adsorbed by resins. The degradation rate of indigo carmine reached 88% and the regeneration efficiency (RE can be maintained above 85% after multi-successive regeneration cycles. The indigo carmine contaminants were decomposed by a variety of reactive radicals leading to fracture of exocyclic C=C bond, which could cause decoloration of dye solution. Based on above results, a possible degradation pathway for the indigo carmine by resin adsorption/DBD plasma treatment was proposed.

  2. Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layers

    G. Kalacska

    2016-05-01

    Full Text Available Tribological performance of the materials greatly depends on the temperature of the contacting zones and surfaces and hence on the heat conducting behaviour of the materials. Heat conduction of polymers is, however, greatly affected even by a very narrow (few tens of nm modified layer formed on the surface after subjecting the polymer to plasma treatment. In this article the heat flow inhibiting properties of plasma modified surface layers were investigated on polyethylene terephthalate (PET and polyamide-6 (PA6 engineering polymers. Nitrogen Plasma Immersion Ion Implantation gave rise to compositional and structural changes of the polymers in a depth of 110 nm. It was found that even this thin layer exhibited significant heat flow inhibiting effect. The modified layer considerably decreased the thermal conductivity coefficient of the treated polymer and resulted in a reduced heat transmission for PET and PA6 by 33 and 28%, respectively. This new information supports and is in accordance with the former tribological results about extra friction heat generation experienced under NPIII surface layer of PA6 and PET during dry sliding.

  3. Non-thermal plasma-induced photocatalytic degradation of 4-chlorophenol in water

    Hao Xiaolong [Institute of Environmental Pollution Control Technologies, Xixi Campus, Zhejiang University, Hangzhou 310028, Zhejiang (China); Zhou Ming Hua [Institute of Environmental Pollution Control Technologies, Xixi Campus, Zhejiang University, Hangzhou 310028, Zhejiang (China); Lei Lecheng [Institute of Environmental Pollution Control Technologies, Xixi Campus, Zhejiang University, Hangzhou 310028, Zhejiang (China)]. E-mail: lclei@zju.edu.cn

    2007-03-22

    TiO{sub 2} photocatalyst (P-25) (50 mg L{sup -1}) was tentatively introduced into pulsed high-voltage discharge process for non-thermal plasma-induced photocatalytic degradation of the representative mode organic pollutant parachlorophenol (4-CP), including other compounds phenol and methyl red in water. The experimental results showed that rate constant of 4-CP degradation, energy efficiency for 4-CP removal and TOC removal with TiO{sub 2} were obviously increased. Pulsed high-voltage discharge process with TiO{sub 2} had a promoted effect for the degradation of these pollutants under a broad range of liquid conductivity. Furthermore, the apparent formation rates of chemically active species (e.g., ozone and hydrogen peroxide) were increased, the hydrogen peroxide formation rate from 1.10 x 10{sup -6} to 1.50 x 10{sup -6} M s{sup -1}, the ozone formation rate from 1.99 x 10{sup -8} to 2.35 x 10{sup -8} M s{sup -1}, respectively. In addition, this process had no influence on the photocatalytic properties of TiO{sub 2}. The introduction of TiO{sub 2} photocatalyst into pulsed discharge plasma process in the utilizing of ultraviolet radiation and electric field in pulsed discharge plasma process enhanced the yields of chemically active species, which were available for highly efficient removal and mineralization of organic pollutants.

  4. Non-thermal plasma-induced photocatalytic degradation of 4-chlorophenol in water.

    Hao, Xiao Long; Zhou, Ming Hua; Lei, Le Cheng

    2007-03-22

    TiO(2) photocatalyst (P-25) (50mgL(-1)) was tentatively introduced into pulsed high-voltage discharge process for non-thermal plasma-induced photocatalytic degradation of the representative mode organic pollutant parachlorophenol (4-CP), including other compounds phenol and methyl red in water. The experimental results showed that rate constant of 4-CP degradation, energy efficiency for 4-CP removal and TOC removal with TiO(2) were obviously increased. Pulsed high-voltage discharge process with TiO(2) had a promoted effect for the degradation of these pollutants under a broad range of liquid conductivity. Furthermore, the apparent formation rates of chemically active species (e.g., ozone and hydrogen peroxide) were increased, the hydrogen peroxide formation rate from 1.10x10(-6) to 1.50x10(-6)Ms(-1), the ozone formation rate from 1.99x10(-8) to 2.35x10(-8)Ms(-1), respectively. In addition, this process had no influence on the photocatalytic properties of TiO(2). The introduction of TiO(2) photocatalyst into pulsed discharge plasma process in the utilizing of ultraviolet radiation and electric field in pulsed discharge plasma process enhanced the yields of chemically active species, which were available for highly efficient removal and mineralization of organic pollutants.

  5. Thermal and nonthermal electron cyclotron emission by high-temperature tokamak plasmas

    Airoldi, A.; Ramponi, G.

    1997-01-01

    An analysis of the electron cyclotron emission (ECE) spectra emitted by a high-temperature tokamak plasma in the frequency range of the second and third harmonic of the electron cyclotron frequency is made, both in purely Maxwellian and in non-Maxwellian cases (i.e., in the presence of a current-carrying superthermal tail). The work is motivated mainly by the experimental observations made in the supershot plasmas of the Tokamak Fusion Test Reactor (TFTR), where a systematic disagreement is found between the T e measurements by second-harmonic ECE and Thomson scattering. We show that, by properly taking into account the overlap of superthermals-emitted third harmonic with second-harmonic bulk emission, the radiation temperature observed about the central frequency of the second harmonic may be enhanced up to 30%endash 40% compared to the corresponding thermal value. Moreover we show that, for parameters relevant to the International Thermonuclear Experimental Reactor (ITER) with T e (0)>7 keV, the overlap between the second and the downshifted third harmonic seriously affects the central plasma region, so that the X-mode emission at the second harmonic becomes unsuitable for local T e measurements. copyright 1997 American Institute of Physics

  6. Non-thermal plasma-induced photocatalytic degradation of 4-chlorophenol in water

    Hao Xiaolong; Zhou Ming Hua; Lei Lecheng

    2007-01-01

    TiO 2 photocatalyst (P-25) (50 mg L -1 ) was tentatively introduced into pulsed high-voltage discharge process for non-thermal plasma-induced photocatalytic degradation of the representative mode organic pollutant parachlorophenol (4-CP), including other compounds phenol and methyl red in water. The experimental results showed that rate constant of 4-CP degradation, energy efficiency for 4-CP removal and TOC removal with TiO 2 were obviously increased. Pulsed high-voltage discharge process with TiO 2 had a promoted effect for the degradation of these pollutants under a broad range of liquid conductivity. Furthermore, the apparent formation rates of chemically active species (e.g., ozone and hydrogen peroxide) were increased, the hydrogen peroxide formation rate from 1.10 x 10 -6 to 1.50 x 10 -6 M s -1 , the ozone formation rate from 1.99 x 10 -8 to 2.35 x 10 -8 M s -1 , respectively. In addition, this process had no influence on the photocatalytic properties of TiO 2 . The introduction of TiO 2 photocatalyst into pulsed discharge plasma process in the utilizing of ultraviolet radiation and electric field in pulsed discharge plasma process enhanced the yields of chemically active species, which were available for highly efficient removal and mineralization of organic pollutants

  7. Negative ion beam formation using thermal contact ionization type plasma source

    Fukuura, Yoshiyuki; Murakami, Kazutugu; Masuoka, Toshio; Katsumata, Itsuo [Osaka City Univ. (Japan). Faculty of Engineering

    1997-02-01

    The small ion sources utilizing thermal ionization have been already developed, and at present, in order to increase ion yield, that being developed to the cylindrical plasma prototype having the inner surface of a Re foil cylinder as the ionization surface, and stably functioning at 3,000 K has been developed, and by using this plasma source, the research on the formation of various ions has been carried out. At present, the research on the formation of Li negative ion beam is carried out. The separation of negative ions from electrons is performed with the locally limited magnetic field using a small iron core electromagnet placed behind the electrostatic accelerating lens system. So for, the formation of about 2 {mu}A at maximum of negative ions was confirmed. It was decided to identify the kinds of ions by time of flight (TOF) process, and the various improvements for this purpose were carried out. The experimental setup, the structure of the plasma source, the circuits for TOF measurement and so on are explained. The experimental results are reported. The problems are the possibility of the formation of alkali metals, the resolution of the time axis of the TOF system and so on. (K.I.)

  8. Engineering design and thermal hydraulics of plasma facing components of SST-1

    Pragash, N. Ravi; Chaudhuri, P.; Santra, P.; Chenna Reddy, D.; Khirwadkar, S.; Saxena, Y.C.

    2001-01-01

    SST-1 is a medium size tokamak with super conducting magnetic field coils. All the subsystems of SST-1 are designed for quasi steady state (∼1000 s) operation. Plasma Facing Components (PFCs) of SST-1 consisting of divertors, passive stabilizers, baffles and poloidal limiters are also designed to be compatible for steady state operation. As SST-1 is designed to run double null divertor plasmas, these components also have up-down symmetry. A closed divertor configuration is chosen to produce high recycling and high pumping speed in the divertor region. All the PFC are made of copper alloys (CuCrZr and CuZr) on which graphite tiles are mechanically attached. These copper alloy back plates are actively cooled with water flowing in the channels grooved on them with the main consideration in the design of PFCs as the steady state heat removal of about 1.0 MW/m 2 . In addition to be able to remove high heat fluxes, the PFCs are also designed to be compatible for baking at 350 degree sign C. Extensive studies, involving different flow parameters and various cooling layouts, have been done to select the final cooling parameters and layout. Thermal response of the PFCs and vacuum vessel during baking, has been calculated using a FORTRAN code and a 2-D finite element analysis. The PFCs and their supports are also designed to withstand large electro-magnetic forces. Finite element analysis using ANSYS software package is used in this and other PFCs design. The engineering design including thermal hydraulics for cooling and baking of all the PFCs is completed. Poloidal limiters are being fabricated. The remaining PFCs, viz. divertors, stabilizers and baffles are likely to go for fabrication in the next few months. The detailed engineering design, the finite element calculations in the structural and thermal designs are presented in this paper

  9. Expanding Thermal Plasma Chemical Vapour Deposition of ZnO:Al Layers for CIGS Solar Cells

    K. Sharma

    2014-01-01

    Full Text Available Aluminium-doped zinc oxide (ZnO:Al grown by expanding thermal plasma chemical vapour deposition (ETP-CVD has demonstrated excellent electrical and optical properties, which make it an attractive candidate as a transparent conductive oxide for photovoltaic applications. However, when depositing ZnO:Al on CIGS solar cell stacks, one should be aware that high substrate temperature processing (i.e., >200°C can damage the crucial underlying layers/interfaces (such as CIGS/CdS and CdS/i-ZnO. In this paper, the potential of adopting ETP-CVD ZnO:Al in CIGS solar cells is assessed: the effect of substrate temperature during film deposition on both the electrical properties of the ZnO:Al and the eventual performance of the CIGS solar cells was investigated. For ZnO:Al films grown using the high thermal budget (HTB condition, lower resistivities, ρ, were achievable (~5 × 10−4 Ω·cm than those grown using the low thermal budget (LTB conditions (~2 × 10−3 Ω·cm, whereas higher CIGS conversion efficiencies were obtained for the LTB condition (up to 10.9% than for the HTB condition (up to 9.0%. Whereas such temperature-dependence of CIGS device parameters has previously been linked with chemical migration between individual layers, we demonstrate that in this case it is primarily attributed to the prevalence of shunt currents.

  10. Effects of thermal plasma on self-absorbed synchrotron sources in active galactic nuclei

    De Kool, M.; Begelman, M.C.

    1989-01-01

    The observable effects of a thermal background plasma in a self-absorbed synchrotron source are reviewed, in the context of a model for the central engine of an active galactic nucleus (AGN). Considering the effects of free-free absorption and emission, Thomson and Compton scattering, and spatial stratification, it is found that the observations set an upper limit on the thermal electron scattering optical depth in the central synchrotron-emitting region of an AGN. The upper limit, tau(max) about 1, results mainly from the apparent absence of induced Compton scattering and inverse thermal Comptonization effects. The low value of tau(max) poses some problems for nonthermal models of the AGN continuum that can be partly resolved by assuming a thin disk or layer-like geometry for the source, with (h/R) less than about 0.01. A likely site for the synchrotron-producing region seems to be the surface of an accretion disk or torus. 20 refs

  11. Two dimensional PMMA nanofluidic device fabricated by hot embossing and oxygen plasma assisted thermal bonding methods

    Yin, Zhifu; Sun, Lei; Zou, Helin; Cheng, E.

    2015-05-01

    A method for obtaining a low-cost and high-replication precision two-dimensional (2D) nanofluidic device with a polymethyl methacrylate (PMMA) sheet is proposed. To improve the replication precision of the 2D PMMA nanochannels during the hot embossing process, the deformation of the PMMA sheet was analyzed by a numerical simulation method. The constants of the generalized Maxwell model used in the numerical simulation were calculated by experimental compressive creep curves based on previously established fitting formula. With optimized process parameters, 176 nm-wide and 180 nm-deep nanochannels were successfully replicated into the PMMA sheet with a replication precision of 98.2%. To thermal bond the 2D PMMA nanochannels with high bonding strength and low dimensional loss, the parameters of the oxygen plasma treatment and thermal bonding process were optimized. In order to measure the dimensional loss of 2D nanochannels after thermal bonding, a dimension loss evaluating method based on the nanoindentation experiments was proposed. According to the dimension loss evaluating method, the total dimensional loss of 2D nanochannels was 6 nm and 21 nm in width and depth, respectively. The tensile bonding strength of the 2D PMMA nanofluidic device was 0.57 MPa. The fluorescence images demonstrate that there was no blocking or leakage over the entire microchannels and nanochannels.

  12. Temperature diagnostics of a non-thermal plasma jet at atmospheric pressure

    Schäfer, Jan

    2013-09-01

    The study reflects the concept of the temperature as a physical quantity resulting from the second thermodynamic law. The reliability of different approaches of the temperature diagnostics of open non-equilibrium systems is discussed using examples of low temperature atmospheric pressure discharges. The focus of this work is a miniaturized non-thermal atmospheric pressure plasma jet for local surface treatment at ambient atmosphere. The micro-discharge is driven with a capacitively coupled radio frequency electric field at 27.12 MHz and fed with argon at rates of about 1 slm through the capillary with an inner diameter of 4 mm. The discharge consists of several contracted filaments with diameter around 300 μm which are rotating azimuthally in the capillary in a self-organized manner. While the measured temperatures of the filament core exceed 700 K, the heat impact on a target below the plasma jet remains limited leading to target temperatures below 400 K. Different kinds of temperatures and energy transport processes are proposed and experimentally investigated. Nevertheless, a reliable and detailed temperature diagnostics is a challenge. We report on a novel diagnostics approach for the spatially and temporally resolved measurement of the gas temperature based on the optical properties of the plasma. Laser Schlieren Deflectometry is adapted to explore temperature profiles of filaments and their behaviour. In parallel, the method demonstrates a fundamental Fermat's principle of minimal energy. Information acquired with this method plays an important role for the optimization of local thin film deposition and surface functionalization by means of the atmospheric pressure plasma jet. The work was supported in part by the Deutsche Forschungsgemeinschaft within SFB-TR 24.

  13. Understanding the growth of micro and nano-crystalline AlN by thermal plasma process

    Kanhe, Nilesh S.; Nawale, Ashok B.; Gawade, Rupesh L.; Puranik, Vedavati G.; Bhoraskar, Sudha V.; Das, Asoka K.; Mathe, Vikas L.

    2012-01-01

    We report the studies related to the growth of crystalline AlN in a DC thermal plasma reactor, operated by a transferred arc plasma torch. The reactor is capable of producing the nanoparticles of Al and AlN depending on the composition of the reacting gas. Al and AlN micro crystals are formed at the anode placed on the graphite and nano crystalline Al and AlN gets deposited on the inner surface of the plasma reactor. X-ray diffraction, Raman spectroscopy analysis, single crystal X-ray diffraction and TGA-DTA techniques are used to infer the purity of post process crystals as a hexagonal AlN. The average particle size using SEM was found to be around 30 μm. The morphology of nanoparticles of Al and AlN, nucleated by gas phase condensation in a homogeneous medium were studied by transmission electron microscopy analysis. The particle ranged in size between 15 and 80 nm in diameter. The possible growth mechanism of crystalline AlN at the anode has been explained on the basis of non-equilibrium processes in the core of the plasma and steep temperature gradient near its periphery. The gas phase species of AlN and various constituent were computed using Murphy code based on minimization of free energy. The process provides 50% yield of microcrystalline AlN and remaining of Al at anode and that of nanocrystalline h-AlN and c-Al collected from the walls of the chamber is about 33% and 67%, respectively.

  14. RACLETTE: a model for evaluating the thermal response of plasma facing components to slow high power plasma transients. Part I: Theory and description of model capabilities

    Raffray, A. René; Federici, Gianfranco

    1997-04-01

    RACLETTE (Rate Analysis Code for pLasma Energy Transfer Transient Evaluation), a comprehensive but relatively simple and versatile model, was developed to help in the design analysis of plasma facing components (PFCs) under 'slow' high power transients, such as those associated with plasma vertical displacement events. The model includes all the key surface heat transfer processes such as evaporation, melting, and radiation, and their interaction with the PFC block thermal response and the coolant behaviour. This paper represents part I of two sister and complementary papers. It covers the model description, calibration and validation, and presents a number of parametric analyses shedding light on and identifying trends in the PFC armour block response to high plasma energy deposition transients. Parameters investigated include the plasma energy density and deposition time, the armour thickness and the presence of vapour shielding effects. Part II of the paper focuses on specific design analyses of ITER plasma facing components (divertor, limiter, primary first wall and baffle), including improvements in the thermal-hydraulic modeling required for better understanding the consequences of high energy deposition transients in particular for the ITER limiter case.

  15. RACLETTE: a model for evaluating the thermal response of plasma facing components to slow high power plasma transients. Pt. I. Theory and description of model capabilities

    Raffray, A.R.; Federici, G.

    1997-01-01

    For pt.II see ibid., p.101-30, 1997. RACLETTE (Rate Analysis Code for pLasma Energy Transfer Transient Evaluation), a comprehensive but relatively simple and versatile model, was developed to help in the design analysis of plasma facing components (PFCs) under 'slow' high power transients, such as those associated with plasma vertical displacement events. The model includes all the key surface heat transfer processes such as evaporation, melting, and radiation, and their interaction with the PFC block thermal response and the coolant behaviour. This paper represents part I of two sister and complementary papers. It covers the model description, calibration and validation, and presents a number of parametric analyses shedding light on and identifying trends in the PFC armour block response to high plasma energy deposition transients. Parameters investigated include the plasma energy density and deposition time, the armour thickness and the presence of vapour shielding effects. Part II of the paper focuses on specific design analyses of ITER plasma facing components (divertor, limiter, primary first wall and baffle), including improvements in the thermal-hydraulic modeling required for better understanding the consequences of high energy deposition transients in particular for the ITER limiter case. (orig.)

  16. To a question on thermal protection of constructional elements of vacuum-plasma devices

    Borisko, V.N.; Borisko, S.V.; Zinovev, D.V.; Lapshin, V.I.; Tselujko, A.F.

    2005-01-01

    The progress in development of vacuum-plasma devices is connected with the design and creation of constructional elements from materials, which have a high erosion resistance and can maintain the large specific flux of energy per effective area. Recently as the materials of such constructional elements it was offered to use the reversible sorbents of hydrogen of Zr-V system, which have high-rates of sorption-desorption and large thermal effect of the hydride phases decomposition. In the paper an experimental research of the thermal conditions features of the metal-hydride electrodes, which subjected of the energy loads in the vacuum-plasma devices, are given. The simulation of the energy loads on the electrodes was carried out with the help of gas discharge plasma as there is an possibility to vary the energy spectrum of the bombarding particles and to gather a necessary radiation dose to the material surface. For comparative examinations of various materials under the irradiation by high-energy heavy particles it is the most convenient to use the Penning discharge. In this case, the cathodes made of different materials are under the identical conditions even at the change of working discharge modes. Therefore in the device on the basis of the Penning discharge the cathodes of metal-hydride and stainless steel were set. It was detected, that the increase of the temperature gradient of metal-hydride cathode goes down with the increase of discharge current value. The dependence of operating temperatures difference of cathodes from exposure time has shown that the temperature of the metal-hydride cathode is sufficiently lower than the temperature of the stainless steel cathode. Such a softening of the thermal operation conditions of the metal hydride cathode is caused by thermal decomposition of hydride phases. Besides there is the energy flow dissipation of bombarding particles on the protective gas target formed by desorbed hydrogen. The considerable decrease of

  17. Realization of thermally durable close-packed 2D gold nanoparticle arrays using self-assembly and plasma etching

    Sivaraman, Sankar K; Santhanam, Venugopal

    2012-01-01

    Realization of thermally and chemically durable, ordered gold nanostructures using bottom-up self-assembly techniques are essential for applications in a wide range of areas including catalysis, energy generation, and sensing. Herein, we describe a modular process for realizing uniform arrays of gold nanoparticles, with interparticle spacings of 2 nm and above, by using RF plasma etching to remove ligands from self-assembled arrays of ligand-coated gold nanoparticles. Both nanoscale imaging and macroscale spectroscopic characterization techniques were used to determine the optimal conditions for plasma etching, namely RF power, operating pressure, duration of treatment, and type of gas. We then studied the effect of nanoparticle size, interparticle spacing, and type of substrate on the thermal durability of plasma-treated and untreated nanoparticle arrays. Plasma-treated arrays showed enhanced chemical and thermal durability, on account of the removal of ligands. To illustrate the application potential of the developed process, robust SERS (surface-enhanced Raman scattering) substrates were formed using plasma-treated arrays of silver-coated gold nanoparticles that had a silicon wafer or photopaper as the underlying support. The measured value of the average SERS enhancement factor (2 × 10 5 ) was quantitatively reproducible on both silicon and paper substrates. The silicon substrates gave quantitatively reproducible results even after thermal annealing. The paper-based SERS substrate was also used to swab and detect probe molecules deposited on a solid surface. (paper)

  18. Nonlinear electron-acoustic rogue waves in electron-beam plasma system with non-thermal hot electrons

    Elwakil, S. A.; El-hanbaly, A. M.; Elgarayh, A.; El-Shewy, E. K.; Kassem, A. I.

    2014-11-01

    The properties of nonlinear electron-acoustic rogue waves have been investigated in an unmagnetized collisionless four-component plasma system consisting of a cold electron fluid, non-thermal hot electrons obeying a non-thermal distribution, an electron beam and stationary ions. It is found that the basic set of fluid equations is reduced to a nonlinear Schrodinger equation. The dependence of rogue wave profiles on the electron beam and energetic population parameter are discussed. The results of the present investigation may be applicable in auroral zone plasma.

  19. First-principles thermal conductivity of warm-dense deuterium plasmas for inertial confinement fusion applications.

    Hu, S X; Collins, L A; Boehly, T R; Kress, J D; Goncharov, V N; Skupsky, S

    2014-04-01

    Thermal conductivity (κ) of both the ablator materials and deuterium-tritium (DT) fuel plays an important role in understanding and designing inertial confinement fusion (ICF) implosions. The extensively used Spitzer model for thermal conduction in ideal plasmas breaks down for high-density, low-temperature shells that are compressed by shocks and spherical convergence in imploding targets. A variety of thermal-conductivity models have been proposed for ICF hydrodynamic simulations of such coupled and degenerate plasmas. The accuracy of these κ models for DT plasmas has recently been tested against first-principles calculations using the quantum molecular-dynamics (QMD) method; although mainly for high densities (ρ > 100 g/cm3), large discrepancies in κ have been identified for the peak-compression conditions in ICF. To cover the wide range of density-temperature conditions undergone by ICF imploding fuel shells, we have performed QMD calculations of κ for a variety of deuterium densities of ρ = 1.0 to 673.518 g/cm3, at temperatures varying from T = 5 × 103 K to T = 8 × 106 K. The resulting κQMD of deuterium is fitted with a polynomial function of the coupling and degeneracy parameters Γ and θ, which can then be used in hydrodynamic simulation codes. Compared with the "hybrid" Spitzer-Lee-More model currently adopted in our hydrocode lilac, the hydrosimulations using the fitted κQMD have shown up to ∼20% variations in predicting target performance for different ICF implosions on OMEGA and direct-drive-ignition designs for the National Ignition Facility (NIF). The lower the adiabat of an imploding shell, the more variations in predicting target performance using κQMD. Moreover, the use of κQMD also modifies the shock conditions and the density-temperature profiles of the imploding shell at early implosion stage, which predominantly affects the final target performance. This is in contrast to the previous speculation that κQMD changes mainly the

  20. Mechanism of acute depletion of plasma fibronectin following thermal injury in rats. Appearance of a gelatinlike ligand in plasma

    Deno, D.C.; McCafferty, M.H.; Saba, T.M.; Blumenstock, F.A.

    1984-01-01

    Plasma fibronectin was depleted within 15 min following sublethal burn, followed by partial recovery at 8 h and complete restoration by 24 h in anesthetized rats. Radiolabeled 75 Se-plasma fibronectin, injected intravenously before burn, was rapidly sequestered in burn skin as well as the liver. Fibronectin levels at 2 h postburn as detected by immunoassay vs. 75 Se-plasma fibronectin indicated that more fibronectin was in the plasma than detected by electroimmunoassay. Crossed immunoelectrophoretic analysis of fibronectin in early postburn plasma demonstrated a reduced electrophoretic mobility of the fibronectin antigen. Addition of heparin or fibrin, both of which have affinity for fibronectin, to normal plasma was unable to reproduce this altered fibronectin electrophoretic pattern. In contrast, addition of gelatin or native collagen to normal plasma reproduced the abnormal electrophoretic pattern of fibronectin seen in burn plasma. Extracts of burned skin, but not extracts of normal skin, when added to normal plasma, elicited a similar altered electrophoretic pattern for fibronectin. By gel filtration, fibronectin in burn plasma had an apparent molecular weight approximately 40% greater than that observed in normal plasma. These data suggest the release into the blood of a gelatinlike ligand from burned skin, which complexes with plasma fibronectin. Thus, fibronectin deficiency acutely postburn appears mediated by (a) its accumulation at the site of burn injury; (b) its removal from the circulation by the liver; and (c) its presence in the plasma in a form that is less detectable by immunoassay

  1. Effect of non-thermal air atmospheric pressure plasma jet treatment on gingival wound healing

    Lee, Jung-Hwan; Choi, Eun-Ha; Kim, Kwang-Mahn; Kim, Kyoung-Nam

    2016-01-01

    Non-thermal atmospheric pressure plasmas have been applied in the biomedical field for the improvement of various cellular activities. In dentistry, the healing of gingival soft tissue plays an important role in health and aesthetic outcomes. While the biomedical application of plasma has been thoroughly studied in dentistry, a detailed investigation of plasma-mediated human gingival fibroblast (HGF) migration for wound healing and its underlying biological mechanism is still pending. Therefore, the aim of this study is to apply a non-thermal air atmospheric pressure plasma jet (NTAAPPJ) to HGF to measure the migration and to reveal the underlying biological mechanisms involved in the migration. After the characterization of NTAAPPJ by optical emission spectroscopy, the adherent HGF was treated with NTAAPPJ or air with a different flow rate. Cell viability, lipid peroxidation, migration, intracellular reactive oxygen species (ROS), and the expression of migration-related genes (EGFR, PAK1, and MAPK3) were investigated. The level of statistical significance was set at 0.05. NTAAPPJ and air treatment with a flow rate of 250–1000 standard cubic centimetres per minute (sccm) for up to 30 s did not induce significant decreases in cell viability or membrane damage. A significant increase in the migration of mitomycin C-treated HGF was observed after 30 s of NTAAPPJ treatment compared to 30 s air-only treatment, which was induced by high levels of intracellular reactive oxygen species (ROS). An increase in migration-related gene expression and EGFR activation was observed following NTAAPPJ treatment in an air flow rate-dependent manner. This is the first report that NTAAPPJ treatment induces an increase in HGF migration without changing cell viability or causing membrane damage. HGF migration was related to an increase in intracellular ROS, changes in the expression of three of the migration-related genes (EGFR, PAK1, and MAPK1), and EGFR activation. Therefore

  2. Formation of hydrophobic coating on glass surface using atmospheric pressure non-thermal plasma in ambient air

    Fang, Z; Qiu, Y; Kuffel, E

    2004-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in material surface processing because of their convenience, effectiveness and low cost. In this paper, the treatment of a glass surface for improving hydrophobicity using a non-thermal plasma generated by a dielectric barrier corona discharge (DBCD) with a needle array-to-plane electrode arrangement in atmospheric air is conducted, and the surface properties of the glass before and after the DBCD treatment are studied using contact angle measurement, surface resistance measurement and the wet flashover voltage test. The effects of the plasma dose (the product of average discharge power and treatment time) of DBCD on the surface modification are studied, and the mechanism of interaction between the plasma and glass surface is discussed. It is found that a layer of hydrophobic coating is formed on the glass surface through DBCD treatment, and the improvement of hydrophobicity depends on the plasma dose of the DBCD. It seems that there is an optimum plasma dose for the surface treatment. The test results of thermal ageing and chemical ageing show that the hydrophobic layer has quite stable characteristics

  3. A simple spectroscopic method for determining the temperature in H2O-Ar thermal plasma jet

    Sember, Viktor; Mašláni, Alan

    2009-01-01

    Roč. 13, č. 2 (2009), s. 217-228 ISSN 1093-3611. [European High Temperature Plasma Processes (HTPP)/10th./. Patras (Patras University), 07.07.2008-11.07.2008] R&D Projects: GA ČR GA202/08/1084; GA MPO FT-TA4/050 Institutional research plan: CEZ:AV0Z20430508 Keywords : Thermal plasma jets * spectroscopic diagnostics * mole-fraction gradients Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 0.333, year: 2009

  4. Electron thermal capacity in plasma generated at cavitation bubble collapse in D-acetone

    Kostenko, B.F.; Pribis, J.

    2004-01-01

    The latest experimental data on nuclear reaction product registration at cavitation bubble collapse in deuterated acetone (C 3 D 6 O) still argue in favour of existence of a new possibility to realize the thermonuclear synthesis. Theoretical description based on numerical solution of simultaneous conservation equations for gaseous and liquid phases also confirms this possibility, although it requires further more precise definitions. In particular, description of electron degrees of freedom in dense nonequilibrium plasma generated at the final stage of bubble collapse need specification. Calculations of electron thermal capacity in the deuterated acetone multiple ionization region at electron temperatures T e ≅ 10 4 K and above and compression range ρ/ρ 0 ≅ 1 - 100 have been fulfilled on the basis of direct numerical solution of equation for chemical potential. (author)

  5. Comparison of Two Models for Radiative Heat Transfer in High Temperature Thermal Plasmas

    Matthieu Melot

    2011-01-01

    Full Text Available Numerical simulation of the arc-flow interaction in high-voltage circuit breakers requires a radiation model capable of handling high-temperature participating thermal plasmas. The modeling of the radiative transfer plays a critical role in the overall accuracy of such CFD simulations. As a result of the increase of computational power, CPU intensive methods based on the radiative transfer equation, leading to more accurate results, are now becoming attractive alternatives to current approximate models. In this paper, the predictive capabilities of the finite volume method (RTE-FVM and the P1 model are investigated. A systematic comparison between these two models and analytical solutions are presented for a variety of relevant test cases. Two implementations of each approach are compared, and a critical evaluation is presented.

  6. Thermalization of the quark-gluon plasma and dynamical formation of Bose-Einstein Condensate

    Liao, Jinfeng

    2013-01-01

    We report recent progress on understanding the thermalization of the quark-gluon plasma during the early stage in a heavy ion collision. The initially high overpopulation in the pre-equilibrium gluonic matter ( g lasma ) is shown to play a crucial role. The strongly interacting nature (and thus fast evolution) naturally arises as an emergent property of this pre-equilibrium matter where the intrinsic coupling is weak but the highly occupied gluon states coherently amplify the scattering. A possible transient Bose-Einstein Condensate is argued to form dynamically on a rather general ground. We develop the kinetic approach for describing this highly overpopulated system and find approximate scaling solutions as well as numerically study the onset of condensation. Finally we also discuss possible phenomenological implications.

  7. Thermal stability of a thermonuclear plasma for different confinement scaling laws

    Johner, J.

    1985-10-01

    The thermal stability of the ignition curve is investigated using a simple OD model for a temperature dependent energy confinement time (tausub(E) is proportional to 1/Tsup(γ)). The stability limit in the (ntausub(E),T) plane is also calculated for a plasma with external heating. The degradation of confinement time with increasing temperature is found to be favourable for divergence temperature and minimum temperature for stable ignition. It also decreases the external power per unit volume necessary to reach divergence. On the contrary, it is extremely unfavourable for the required μsub(E) for divergence and ignition. Detailed results are given for the special case of the Kaye-Goldston scaling (γ=1.38)

  8. Dispersion in a thermal plasma including arbitrary degeneracy and quantum recoil.

    Melrose, D B; Mushtaq, A

    2010-11-01

    The longitudinal response function for a thermal electron gas is calculated including two quantum effects exactly, degeneracy, and the quantum recoil. The Fermi-Dirac distribution is expanded in powers of a parameter that is small in the nondegenerate limit and the response function is evaluated in terms of the conventional plasma dispersion function to arbitrary order in this parameter. The infinite sum is performed in terms of polylogarithms in the long-wavelength and quasistatic limits, giving results that apply for arbitrary degeneracy. The results are applied to the dispersion relations for Langmuir waves and to screening, reproducing known results in the nondegenerate and completely degenerate limits, and generalizing them to arbitrary degeneracy.

  9. Electron Thermal Capacity in Plasma Generated at Cavitation Bubble Collapse in D-acetone

    Kostenko, B F

    2004-01-01

    The latest experimental data on nuclear reaction product registration at cavitation bubble collapse in deuterated acetone (C$_3$D$_6$O) still argue in favour of existence of a new possibility to realize the thermonuclear synthesis. Theoretical description based on numerical solution of simultaneous conservation equations for gaseous and liquid phases also confirms this possibility, although it requires further more precise definitions. In particular, description of electron degrees of freedom in very dense nonequilibrium plasma generated at the final stage of bubble collapse needs specification. In the present paper, calculations of electron thermal capacity in the deuterated acetone multiple ionization region at electron temperatures $T_e \\simeq 10^4 $ K and above and compression range $\\rho/\\rho_0 \\simeq 1 \\div 100$ have been fulfilled on the basis of direct numerical solution of equation for chemical potential.

  10. Mechanical characterization of W-armoured plasma-facing components after thermal fatigue

    Serret, D; Richou, M; Missirlian, M; Loarer, T

    2011-01-01

    The future fusion device ITER is aimed at demonstrating the scientific and technical feasibility of fusion power. Tens of thousands of W-armoured plasma-facing components (PFCs) will be installed in the vertical targets of the ITER divertor and subjected to a high heat flux. The purpose of this paper is to present the results of mechanical and microstructural characterization of tungsten PFCs after thermal fatigue tests. On each component, Vickers hardness measurements are made. In parallel, the mean grain diameter in the corresponding zone of tungsten material is determined. The empirical Hall-Petch relation was adapted to experimental data. However, due to the plateau effect on recrystallization hardness, this relation does not seem to be relevant once recrystallization is complete: a new approach is proposed for predicting the margin to the tungsten melting onset.

  11. Uncapped silver nanoparticles synthesized by DC arc thermal plasma technique for conductor paste formulation

    Shinde, Manish; Pawar, Amol; Karmakar, Soumen; Seth, Tanay; Raut, Varsha; Rane, Sunit; Bhoraskar, Sudha; Amalnerkar, Dinesh

    2009-11-01

    Uncapped silver nanoparticles were synthesized by DC arc thermal plasma technique. The synthesized nanoparticles were structurally cubic and showed wide particle size variation (between 20-150 nm). Thick film paste formulated from such uncapped silver nanoparticles was screen-printed on alumina substrates and the resultant `green' films were fired at different firing temperatures. The films fired at 600 °C revealed better microstructure properties and also yielded the lowest value of sheet resistance in comparison to those corresponding to conventional peak firing temperature of 850 °C. Our findings directly support the role of silver nanoparticles in substantially depressing the operative peak firing temperature involved in traditional conductor thick films technology.

  12. Constrained sintering of an air-plasma-sprayed thermal barrier coating

    Cocks, A.C.F.; Fleck, N.A.

    2010-01-01

    A micromechanical model is presented for the constrained sintering of an air-plasma-sprayed, thermal barrier coating upon a thick superalloy substrate. The coating comprises random splats with intervening penny-shaped cracks. The crack faces make contact at asperities, which progressively sinter in-service by interfacial diffusion, accommodated by bulk creep. Diffusion is driven by the reduction in interfacial energy at the developing contacts and by the local asperity contact stress. At elevated operating temperature, both sintering and creep strains accumulate within the plane of the coating. The sensitivities of sintering rate and microstructure evolution rate to the kinetic parameters and thermodynamic driving forces are explored. It is demonstrated that the sintering response is governed by three independent timescales, as dictated by the material and geometric properties of the coating. Finally, the role of substrate constraint is assessed by comparing the rate of constrained sintering with that for free sintering.

  13. Non-thermal plasma at atmospheric pressure for ozone generation and volatile organic compounds decomposition

    Pekarek, S.; Khun, J.

    2006-01-01

    The non-thermal plasma technologies based on electrical discharges play an important role in ecological applications. The classical corona discharge is however relatively low power discharge. With the aim to extend its current-voltage range we studied hollow needle-to-plate DC corona discharge enhanced by the flow of a gas through the needle electrode. With this type of the discharge we performed an extensive study of ozone generation and volatile organic compounds decomposition. We found that supply of air through the needle substantially increases current-voltage range of the discharge in comparison with classical pin-to-plate corona discharge. Consequently the ozone generation as well as toluene decomposition efficiency was increased (Authors)

  14. Measurement of the non-thermal properties in a low-pressure spraying plasma

    Jung, Yong Ho; Chung, Kyu Sun

    2002-01-01

    The non-thermal properties of a low-pressure spraying plasma have been characterized by using optical emission spectroscopy and single probes installed in a fast scanning probe system. A two-temperature model of the electrons is introduced to explain their non-isothermal properties, which are measured using single probes. The excitation temperatures of the atomic and the ionic lines are calculated from measurements of the emission intensities of Ar (I) and Ar (II), and those temperatures can be explained by using a local thermodynamic equilibrium (LTE) or a non-local thermodynamic equilibrium (non-LTE) model. In order to deduce more reasonable values (excitation temperatures), we introduce a multi-thermodynamic equilibrium (MTE) model, which gives different temperatures, depending upon the atomic excitation states

  15. Removal of dimethyl sulfide by the combination of non-thermal plasma and biological process.

    Wei, Z S; Li, H Q; He, J C; Ye, Q H; Huang, Q R; Luo, Y W

    2013-10-01

    A bench scale system integrated with a non-thermal plasma (NTP) and a biotricking filtration (BTF) unit for the treatment of gases containing dimethyl sulfide (DMS) was investigated. DMS removal efficiency in the integrated system was up to 96%. Bacterial communities in the BTF were assessed by PCR-DGGE, which play the dominant role in the biological processes of metabolism, sulfur oxidation, sulfate-reducing and carbon oxidation. The addition of ozone from NTP made microbial community in BTF more complicated and active for DMS removal. The NTP oxidize DMS to simple compounds such as methanol and carbonyl sulfide; the intermediate organic products and DMS are further oxidized to sulfate, carbon dioxide, water vapors by biological degradation. These results show that NTP-BTF is achievable and open new possibilities for applying the integrated with NTP and BTF to odour gas treatment. Copyright © 2013 The Authors. Published by Elsevier Ltd.. All rights reserved.

  16. Dentin surface treatment using a non-thermal argon plasma brush for interfacial bonding improvement in composite restoration

    Ritts, Andy Charles; Li, Hao; Yu, Qingsong; Xu, Changqi; Yao, Xiaomei; Hong, Liang; Wang, Yong

    2010-01-01

    The objective of this study is to investigate the treatment effects of non-thermal atmospheric gas plasmas on dentin surfaces for composite restoration. Extracted unerupted human third molars were used by removing the crowns and etching the exposed dentin surfaces with 35% phosphoric acid gel. The dentin surfaces were treated by using a non-thermal atmospheric argon plasma brush for various durations. The molecular changes of the dentin surfaces were analyzed using FTIR/ATR and an increase in carbonyl groups on dentin surfaces was detected with plasma treated dentin. Adper Single Bond Plus adhesive and Filtek Z250 dental composite were applied as directed. To evaluate the dentin/composite interfacial bonding, the teeth thus prepared were sectioned into micro-bars as the specimens for tensile test. Student Newman Keuls tests showed that the bonding strength of the composite restoration to peripheral dentin was significantly increased (by 64%) after 30 s plasma treatment. However, the bonding strength to plasma treated inner dentin did not show any improvement. It was found that plasma treatment of peripheral dentin surface up to 100 s gave an increase in interfacial bonding strength, while a prolong plasma treatment of dentin surfaces, e.g., 5 min treatments, showed a decrease in interfacial bonding strength. PMID:20831586

  17. Wiedemann-Franz ratio in high-pressure and low-temperature thermal xenon plasma with 10% caesium

    Novakovic, N.V.; Milic, B.S.; Stojilkovic, S.M.

    1995-01-01

    Theoretical investigations of various transport properties of low-temperature noble-gas plasmas with additives has aroused a continuous interest over a considerable spall of time, due to numerous applications. In this paper the results of a theoretical evaluation of electrical conductivity, thermal conductivity and their ratio (the Wiedemann-Franz ratio) in xenon plasma with 10% of argon and 10% of caesium are presented, for the temperature range from 2000 K to 20000 K, and for pressures equal to or 5, 10, and 15 time higher than the normal atmospheric pressure. The plasma was regarded as weakly non-ideal and in the state of local thermodynamical equilibrium with the assumption that the equilibrium is attained with the pressure kept constant. The plasma composition was determined on the ground of a set of Saha equations; the ionization energy lowerings were expressed with the aid of a modified plasma Debye radius r* D (rather than the standard r D ), as proposed previously

  18. Ion-pair chromatography coupled to inductively coupled plasma-mass spectrometry (IPC-ICP-MS) as a method for thiomolybdate speciation in natural waters.

    Lohmayer, Regina; Reithmaier, Gloria Maria Susanne; Bura-Nakić, Elvira; Planer-Friedrich, Britta

    2015-03-17

    Molybdenum precipitates preferentially under reducing conditions; therefore, its occurrence in sediment records is used as an indicator of paleoredox conditions. Although thiomolybdates (MoO4-xSx(2-) with x = 1-4) supposedly are necessary intermediates in the process of molybdenum precipitation under anoxic conditions, there is no information about their abundance in natural environments, because of a lack of element-specific methods with sufficiently low detection limits. Here, we optimized ion-pair chromatographic separation for coupling to an inductively coupled plasma-mass spectrometry detector (IPC-ICP-MS). 2-Propanol (10%-25% gradient) replaced the previously used acetonitrile (25%-75%) as the solvent, to reduce the carbon load into the plasma. In synthetic solutions, formation of thiomolybdates was found to occur spontaneously in the presence of excess sulfide and the degree of thiolation was highest at pH 7. Excess hydroxyl led to a transformation of thiomolybdates to molybdate. Under acidic to neutral conditions, precipitation of molybdenum and hydrolysis of tetrathiomolybdate were observed. Flash-freezing was found to be suitable to stabilize tetrathiomolybdate, with 2 mM) negatively affected the detection of molybdate, which eluted mainly in the dead volume, but had no negative effect on higher thiolated molybdates. Detection limits were ∼10 nM. With the newly developed IPC-ICP-MS method, thiomolybdates were found to form spontaneously in euxinic marine waters after adding a molybdate spike and occur naturally in sulfidic geothermal waters.

  19. Use of emission spectroscopy as a tool for optimization of plasma hearth operation for hazardous waste thermal treatment

    Monts, D.L.; Bauman, L.E.; Lengel, R.K.; Wang, W.; Lin, J.; Cook, R.L.; Shepard, W.S.

    1994-01-01

    Thermal processing of mixed wastes by plasma hearth vitrification requires optimization of and continuous monitoring of plasma hearth operation. A series of investigations utilizing emission spectroscopy has been initiated to characterize the plasma of a 96 kW plasma hearth in order to determine optimum conditions for monitoring and hence controlling plasma hearth performance. The plasma hearth test stand is based upon a 96 kW, transferred arc plasma torch. The torch is mounted in a vacuum vessel through an electrically operated XYZ Gimbal mount. The peak operating power depends on the gas used for the plasma. The operational limits for DC voltage are 180 V to 550 V; and the current is operated at a constant value, selectable in the range from 72 to 200 amps. The plasma arc length can be varied from 2.5 cm to 25 cm, and is dependent on the supply voltage and the process gas used. The arc current and voltage, gas pressure, cooling water flow, and cooling water temperature are monitored and stored by a PC-based data acquisition system. Five optical ports are available for making optical diagnostic measurements

  20. Effect of Non Thermal Plasma on Alfalfa (Medicago sativa L.) Forage Production

    Abd El-Daem, G.A.N.A.; El-Aragi, G.M.; Tarrad, M.M.; Zayed, E.M.

    2013-01-01

    Field experiments were conducted at Atomic Energy Authority (AEA) Farm, at Inshas, Egypt during 2011–2012 on alfalfa. The aim of this investigation to caused mutation in alfalfa to obtain new variation. Seeds of the alfalfa were subjected to six doses of non-thermal plasma pulse. The plasma (consisting of ozone, UV and visible light) was injected into the seed samples for different durations or number of pulses. The doses used treatments were 2, 4, 6, 8, and 10 pulses (P) and non-treated control. The results showed difference seeds in both level field performances from cut 1st to cut 10th in the forage production. The results showed differences between the Control and treatment (number of pulses (P)) in each of all cuts for the productivity. The results showed the impact of plant height, Number of leaves/plant and number of branches/leaf and stem diameter as well as fresh weight of plant, fresh/weight (t/fed), dry yield (t/fed) in some cuts for Pulses 2, 4 and 10, and the ten pulses were the best for the majority of the qualities and cuts.

  1. Plasma exhaust purification by thermal swing adsorption: Experimental results and modeling

    Ricapito, I.; Malara, R.C.

    1996-01-01

    For several years at the Joint Research Centre-Ispra laboratories, cyclic adsorption processes have been developed for the purification of the plasma exhaust stream of a deuterium-tritium fusion reactor. A purification process consisting of two coupled thermal swing adsorption systems seemed to be the most convenient process. In this context, a screening study was carried out to select the most suitable adsorbent materials and appropriate working temperatures. This was mainly done by experimental measurements of adsorption isotherms of the single components of the plasma exhaust stream and by a careful evaluation of the multicomponent adsorption equilibria. Experiments on adsorption dynamics were carried out in a pilot plant to demonstrate the feasibility and to evaluate the performance of the process. The experimental apparatus was designed to treat gas mixture flow rates up to 20 to 30 standard temperature and pressure l/h. A mathematical model was developed and tested against the experimental results to describe the adsorption process and, in particular, to evaluate and to optimize the process cycle time. 27 refs., 4 figs., 9 tabs

  2. Modelling and experimentation of the SO2 remotion through a plasma out of thermal equilibrium

    Moreno S, H.; Pacheco P, M.; Pacheco S, J.; Cruz A, A.

    2005-01-01

    In spite of the measures that have taken for the decrease of the emitted pollution by mobile sources ( T oday it doesn't Circulate , implementation of catalysts in those exhaust pipes,...), the pollution in the Valley of Mexico area overcomes the limits fixed by Mexican standards several days each year. It is foreseen that for 2020 those emissions of pollutants will be increase considerably, as example we can mention to the sulfur oxides which will be increase a 48% with regard to 1998. The purpose of this work is of proposing a technique for the degradation of the sulfur dioxide (SO 2 ) that consists in introducing this gas to a plasma out of thermal equilibrium where its were formed key radicals (O, OH) for its degradation. The proposed reactor has the advantage of combining the kindness of the dielectric barrier discharge and of corona discharge, besides working to atmospheric pressure and having small dimensions. The first obtained results of the modelling of the degradation of the SO 2 in plasma as well as those experimentally obtained are presented. (Author)

  3. Thermal response of plasma sprayed tungsten coating to high heat flux

    Liu, X.; Yang, L.; Tamura, S.; Tokunaga, K.; Yoshida, N.; Noda, N.; Xu, Z.

    2004-01-01

    In order to investigate the thermal response of tungsten coating on carbon and copper substrates by vacuum plasma spray (VPS) or inert gas plasma spray (IPS), annealing and cyclic heat load experiments of these coatings were conducted. It is indicated that the multi-layered tungsten and rhenium interface of VPS-W/CFC failed to act as a diffusion barrier at elevated temperature and tungsten carbides were developed after 1 h incubation time when annealing temperature was higher than 1600 deg. C. IPS-W/Cu and W/C without an intermediate bonding layer were failed by the detachment of the tungsten coating at 900 and 1200 deg. C annealing for several hours, respectively. Cyclic heat load of electron beam with 35 MW/m 2 and 3-s pulse duration indicated that IPS-W/Cu samples failed with local detachment of the tungsten coating within 200 cycles and IPS-W/C showed local cracks by 300 cycles, but VPS-W/CFC withstood 1000 cycles without visible damages. However, crack creation and propagation in VPS-W/CFC were also observed under higher heat load

  4. Novel Therapeutic Effects of Non-thermal atmospheric pressure plasma for Muscle Regeneration and Differentiation

    Choi, Jae Won; Kang, Sung Un; Kim, Yang Eun; Park, Ju Kyeong; Yang, Sang Sik; Kim, Yeon Soo; Lee, Yun Sang; Lee, Yuijina; Kim, Chul-Ho

    2016-01-01

    Skeletal muscle can repair muscle tissue damage, but significant loss of muscle tissue or its long-lasting chronic degeneration makes injured skeletal muscle tissue difficult to restore. It has been demonstrated that non-thermal atmospheric pressure plasma (NTP) can be used in many biological areas including regenerative medicine. Therefore, we determined whether NTP, as a non-contact biological external stimulator that generates biological catalyzers, can induce regeneration of injured muscle without biomaterials. Treatment with NTP in the defected muscle of a Sprague Dawley (SD) rat increased the number of proliferating muscle cells 7 days after plasma treatment (dapt) and rapidly induced formation of muscle tissue and muscle cell differentiation at 14 dapt. In addition, in vitro experiments also showed that NTP could induce muscle cell proliferation and differentiation of human muscle cells. Taken together, our results demonstrated that NTP promotes restoration of muscle defects through control of cell proliferation and differentiation without biological or structural supporters, suggesting that NTP has the potential for use in muscle tissue engineering and regenerative therapies. PMID:27349181

  5. Study of thermal and electrical parameters of workpieces during spray coating by electrolytic plasma jet

    Khafizov, A A; Shakirov, Yu I; Valiev, R A; Valiev, R I; Khafizova, G M

    2016-01-01

    In this paper the results are presented of thermal and electrical parameters of products in the system bottom layer - intermediate layer when applying protective coatings of ferromagnetic powder by plasma spray produced in an electric discharge with a liquid cathode, on steel samples. Temperature distribution and gradients in coating and intermediate coating were examined. Detailed descriptions of spray coating with ferromagnetic powder by plasma jet obtained in electrical discharge with liquid cathode and the apparatus for obtaining thereof is provided. Problem has been solved by using of Fourier analysis. Initial data for calculations is provided. Results of numerical analysis are provided as temporal functions of temperature in contiguity between coating and intermediate coating as well as temporal function of the value Q=q-φ; where q is density of heat current directed to the free surface of intermediate coating, φ is density of heat current in contiguity between coating and intermediate coating. The analysis of data given shows that in the systems of contact heat exchange bottom layer-intermediate layer with close values of the thermophysical characteristics of constituting materials is observed a slow increase of the temperature of the contact as a function of time. (paper)

  6. Functionalization of polymer surfaces by medium frequency non-thermal plasma

    Felix, T.; Trigueiro, J. S.; Bundaleski, N.; Teodoro, O. M. N. D.; Sério, S.; Debacher, N. A.

    2018-01-01

    This work addresses the surface modification of different polymers by argon dielectric barrier discharge, using bromoform vapours. Atomic Force Microscopy and Scanning Electron Microscopy showed that plasma etching occurs in stages and may be related to the reach of the species generated and obviously the gap between the electrodes. In addition, the stages of flatten surface or homogeneity may be the result of the transient crosslinking promoted by the intense UV radiation generated by the non- thermal plasma. X-ray Photoelectron Spectroscopy analysis showed that bromine was inserted on the polymer surface as Csbnd Br bonds and as adsorbed HBr. The obtained results demonstrate that the highest degree of bromofunctionalization was achieved on polypropylene surface, which contains about 8,5% of Br. After its derivatization in ammonia, Br disappeared and about 6% of nitrogen in the form of amine group was incorporated at the surface. This result can be considered as a clear fingerprint of the Br substitution by the amine group, thus illustrating the efficiency of the proposed method for functionalization of polymer surfaces.

  7. Non-thermal plasma-activated water inactivation of food-borne pathogen on fresh produce

    Ma, Ruonan; Wang, Guomin; Tian, Ying; Wang, Kaile; Zhang, Jue; Fang, Jing

    2015-01-01

    Highlights: • We propose a new approach to treat S. aureus inoculated on strawberries by PAW. • PAW could inactivate S. aureus on strawberries via the Log Reduction results, further confirmed by CLSM and SEM. • The short-lived ROS in PAW are considered the most important agents in inactivation process. • No significant change was found in color, firmness and pH of the PAW treated strawberries. - Abstract: Non-thermal plasma has been widely considered to be an effective method for decontamination of foods. Recently, numerous studies report that plasma-activated water (PAW) also has outstanding antibacterial ability. This study presents the first report on the potential of PAW for the inactivation of Staphylococcus aureus (S. aureus) inoculated on strawberries. PAW treatments achieved a reduction of S. aureus ranging from 1.6 to 2.3 log at day-0 storage, while 1.7 to 3.4 log at day-4 storage. The inactivation efficiency depended on the plasma-activated time for PAW generation and PAW-treated time of strawberries inoculated with S. aureus. LIVE/DEAD staining and scanning electron microscopy results confirm that PAW could damage the bacterial cell wall. Moreover, optical emission spectra and oxidation reduction potential results demonstrate the inactivation is mainly attributed to oxidative stress induced by reactive oxygen species in PAW. In addition, no significant change was found in color, firmness and pH of the PAW treated strawberries. Thus, PAW can be a promising alternative to traditional sanitizers applied in the fresh produce industry.

  8. Non-thermal plasma-activated water inactivation of food-borne pathogen on fresh produce

    Ma, Ruonan; Wang, Guomin; Tian, Ying; Wang, Kaile [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); Zhang, Jue, E-mail: zhangjue@pku.edu.cn [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); College of Engineering, Peking University, Beijing 100871 (China); Fang, Jing [Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871 (China); College of Engineering, Peking University, Beijing 100871 (China)

    2015-12-30

    Highlights: • We propose a new approach to treat S. aureus inoculated on strawberries by PAW. • PAW could inactivate S. aureus on strawberries via the Log Reduction results, further confirmed by CLSM and SEM. • The short-lived ROS in PAW are considered the most important agents in inactivation process. • No significant change was found in color, firmness and pH of the PAW treated strawberries. - Abstract: Non-thermal plasma has been widely considered to be an effective method for decontamination of foods. Recently, numerous studies report that plasma-activated water (PAW) also has outstanding antibacterial ability. This study presents the first report on the potential of PAW for the inactivation of Staphylococcus aureus (S. aureus) inoculated on strawberries. PAW treatments achieved a reduction of S. aureus ranging from 1.6 to 2.3 log at day-0 storage, while 1.7 to 3.4 log at day-4 storage. The inactivation efficiency depended on the plasma-activated time for PAW generation and PAW-treated time of strawberries inoculated with S. aureus. LIVE/DEAD staining and scanning electron microscopy results confirm that PAW could damage the bacterial cell wall. Moreover, optical emission spectra and oxidation reduction potential results demonstrate the inactivation is mainly attributed to oxidative stress induced by reactive oxygen species in PAW. In addition, no significant change was found in color, firmness and pH of the PAW treated strawberries. Thus, PAW can be a promising alternative to traditional sanitizers applied in the fresh produce industry.

  9. Modelling of thermal removal of tars in a high temperature stage fed by a plasma torch

    Fourcault, A.; Marias, F.; Michon, U.

    2010-01-01

    The thermal degradation of tars in a chamber fed by a non-transferred plasma torch is theoretically examined in this study. The input of this reactor is a product gas coming from a gasification unit with a temperature of about 800 o C. According to literature, naphthalene and toluene are chosen as model compounds to represent the behaviour of their classes. According to this choice and to the data available in the literature, a reaction pathway for the thermal degradation of tars and its associated kinetics are proposed in this study. This mechanism is introduced in a CSTR model in order to check the influence of the operating parameters of the reactor on the degradation efficiency. These computations clearly show that a complete conversion of toluene (>99.9%) and an important conversion of naphthalene (96.7%) can be reached in the reactor, with concentration levels compatible with the further use of gas engines for electricity production. This theoretical study requires to be validated by comparison with experimental results.

  10. Modelling of thermal removal of tars in a high temperature stage fed by a plasma torch

    Fourcault, A. [Laboratoire Thermique Energetique et Procedes, LaTEP-ENSGTI, rue Jules Ferry, BP 7511, 64075 Pau Cedex (France); Europlasma, 21 rue Daugere, 33520 Bruges (France); Marias, F. [Laboratoire Thermique Energetique et Procedes, LaTEP-ENSGTI, rue Jules Ferry, BP 7511, 64075 Pau Cedex (France); Michon, U. [Europlasma, 21 rue Daugere, 33520 Bruges (France)

    2010-09-15

    The thermal degradation of tars in a chamber fed by a non-transferred plasma torch is theoretically examined in this study. The input of this reactor is a product gas coming from a gasification unit with a temperature of about 800 C. According to literature, naphthalene and toluene are chosen as model compounds to represent the behaviour of their classes. According to this choice and to the data available in the literature, a reaction pathway for the thermal degradation of tars and its associated kinetics are proposed in this study. This mechanism is introduced in a CSTR model in order to check the influence of the operating parameters of the reactor on the degradation efficiency. These computations clearly show that a complete conversion of toluene (>99.9%) and an important conversion of naphthalene (96.7%) can be reached in the reactor, with concentration levels compatible with the further use of gas engines for electricity production. This theoretical study requires to be validated by comparison with experimental results. (author)

  11. Overview on Recent Developments of Bondcoats for Plasma-Sprayed Thermal Barrier Coatings

    Naumenko, D.; Pillai, R.; Chyrkin, A.; Quadakkers, W. J.

    2017-12-01

    The performance of MCrAlY (M = Ni, Co) bondcoats for atmospheric plasma-sprayed thermal barrier coatings (APS-TBCs) is substantially affected by the contents of Co, Ni, Cr, and Al as well as minor additions of Y, Hf, Zr, etc., but also by manufacturing-related properties such as coating thickness, porosity, surface roughness, and oxygen content. The latter properties depend in turn on the exact technology and set of parameters used for bondcoat deposition. The well-established LPPS process competes nowadays with alternative technologies such as HVOF and APS. In addition, new technologies have been developed for bondcoats manufacturing such as high-velocity APS or a combination of HVOF and APS for application of a flashcoat. Future developments of the bondcoat systems will likely include optimization of thermal spraying methods for obtaining complex bondcoat roughness profiles required for extended APS-TBC lifetimes. Introduction of the newest generation single-crystal superalloys possessing low Cr and high Al and refractory metals (Re, Ru) contents will require definition of new bondcoat compositions and/or multilayered bondcoats to minimize interdiffusion issues. The developments of new bondcoat compositions may be substantially facilitated using thermodynamic-kinetic modeling, the vast potential of which has been demonstrated in recent years.

  12. Suitability of thermal plasmas for large-area bacteria inactivation on temperature-sensitive surfaces – first results with Geobacillus stearothermophilus spores

    Szulc, M; Schein, S; Schaup, J; Zimmermann, S; Schein, J

    2017-01-01

    The application of thermal plasma for large-area bacteria inactivation on temperature-sensitive surfaces is not a common one. Nonetheless, there are thermal plasma generators which offer a high sheath homogeneity and have proven to be suitable for treatment of thermally sensitive materials in the past. To investigate the suitability of such plasmas, agar dishes plated with endospores of Geobacillus stearothermophilus have been treated with a long arc plasma generator called LARGE. The achieved results have been compared with a commercially available non-thermal plasma generator. A significant inactivation of the endospores could be observed only after 60 s of treatment with the thermal plasma source. This was not possible with the non-thermal generator. Moreover, no temperature damage or increase of the specimen could be detected. An attempt to determine the main agents responsible for the microbicidal effects have been made – the influence of plasma gas composition, discharge current and treatment time has been investigated. Significant improvements in the disinfection rates after adding small amounts of nitrogen to the plasma gas could be observed. A first discussion regarding the suitability of thermal plasmas for bacteria inactivation has been given. (paper)

  13. Study of mixed radiative thermal mass transfer in the case of spherical liquide particle evaporation in a high temperature thermal air plasma

    Garandeau, S.

    1984-01-01

    Radiative transfer in a semi-transparent non-isothermal medium with spherical configuration has been studied. Limit conditions have been detailed, among which the semi-transparent inner sphere case is a new case. Enthalpy and matter transfer equations related to these different cases have been established. An adimensional study of local conservation laws allowed to reveal a parameter set characteristic of radiation coupled phenomena thermal conduction, convection, diffusion. Transfer equations in the case of evaporation of a liquid spherical particle in an air thermal plasma have been simplified. An analytical solution for matter transfer is proposed. Numerical solution of radiative problems and matter transfer has been realized [fr

  14. Performance evaluation of non-thermal plasma on particulate matter, ozone and CO2 correlation for diesel exhaust emission reduction

    Babaie, Meisam; Davari, Pooya; Talebizadeh, Poyan

    2015-01-01

    This study is seeking to investigate the effect of non-thermal plasma technology in the abatement of particulate matter (PM) from the actual diesel exhaust. Ozone (O3) strongly promotes PM oxidation, the main product of which is carbon dioxide (CO2). PM oxidation into the less harmful product (CO2...

  15. Absorption and stimulated emission between the electronic states of C and C_2 radicals in an expanding thermal plasma

    Otorbaev, D.K.; Sanden, van de M.C.M.; Buuron, A.J.M.; Schram, D.C.

    1995-01-01

    Using the method of reabsorption the absolute densities of argon, atomic and molecular carbon are determined during the deposition of amorphous hydrogenated (diamond-like) carbon coatings by an expanding thermal are plasma. Depending on the gas mixture argon/methane or argon/acetylene and the manner

  16. Modeling of thermal effects on TIBER II [Tokamak Ignition/Burn Experimental Reactor] divertor during plasma disruption

    Bruhn, M.L.; Perkins, L.J.

    1987-01-01

    Mapping the disruption power flow from the mid-plane of the TIBER Engineering Test Reactor to its divertor and calculating the resulting thermal effects are accomplished through the modification and coupling of three presently existing computer codes. The resulting computer code TADDPAK (Thermal Analysis Divertor during Disruption PAcKage) provides three-dimensional graphic presentations of time and positional dependent thermal effects on a poloidal cross section of the double-null-divertor configured reactor. These thermal effects include incident heat flux, surface temperature, vaporization rate, total vaporization, and melting depth. The dependence of these thermal effects on material choice, disruption pulse shape, and the characteristic thickness of the plasma scrape-off layer is determined through parametric analysis with TADDPAK. This computer code is designed to be a convenient, rapid, and user-friendly modeling tool which can be easily adapted to most tokamak double-null-divertor reactor designs. 14 refs

  17. Perfluoroalkyl substances in polar bear mother-cub pairs: a comparative study based on plasma levels from 1998 and 2008.

    Bytingsvik, Jenny; van Leeuwen, Stefan P J; Hamers, Timo; Swart, Kees; Aars, Jon; Lie, Elisabeth; Nilsen, Else Mari Espseth; Wiig, Oystein; Derocher, Andrew E; Jenssen, Bjørn M

    2012-11-15

    Perfluoroalkyl substances (PFASs) are protein-binding blood-accumulating contaminants that may have detrimental toxicological effects on the early phases of mammalian development. To enable an evaluation of the potential health risks of PFAS exposure for polar bears (Ursus maritimus), an exposure assessment was made by examining plasma levels of PFASs in polar bear mothers in relation to their suckling cubs-of-the-year (~4 months old). Samples were collected at Svalbard in 1998 and 2008, and we investigated the between-year differences in levels of PFASs. Seven perfluorinated carboxylic acids (∑₇PFCAs: PFHpA, PFOA, PFNA, PFDA, PFUnDA, PFDoDA, and PFTrDA) and two perfluorinated sulfonic acids (∑₂PFSAs: PFHxS and PFOS) were detected in the majority of the mothers and cubs from both years. In mothers and cubs, most PFCAs were detected in higher concentrations in 2008 than in 1998. On the contrary, levels of PFOS were lower in 2008 than in 1998, while levels of PFHxS did not differ between the two sampling years. PFOS was the dominating compound in mothers and cubs both in 1998 and in 2008. Concentration of PFHpA did not differ between mothers and cubs, while concentrations of PFOA, PFNA, PFDA, PFUnDA, PFDoDA, PFTrDA, PFHxS, and PFOS were higher in mothers than in their cubs. Except from PFHpA, all compounds correlated significantly between mothers and their cubs. The mean cub to mother ratios ranged from 0.15 for PFNA to 1.69 for PFHpA. On average (mean±standard error of mean), the levels of ∑₇PFCAs and ∑₂PFSAs in cubs were 0.24±0.01 and 0.22±0.01 times the levels in their mothers, respectively. Although maternal transfer appears to be a substantial source of exposure for the cubs, the low cub to mother ratios indicate that maternal transfer of PFASs in polar bears is relatively low in comparison with hydrophobic contaminants (e.g. PCBs). Because the level of several PFASs in mothers and cubs from both sampling years exceeded the levels associated

  18. Man-made vitreous fiber produced from incinerator ash using the thermal plasma technique and application as reinforcement in concrete.

    Yang, Sheng-Fu; Wang, To-Mai; Lee, Wen-Cheng; Sun, Kin-Seng; Tzeng, Chin-Ching

    2010-10-15

    This study proposes using thermal plasma technology to treat municipal solid waste incinerator ashes. A feasible fiberization method was developed and applied to produce man-made vitreous fiber (MMVF) from plasma vitrified slag. MMVF were obtained through directly blending the oxide melt stream with high velocity compressed air. The basic technological characteristics of MMVF, including morphology, diameter, shot content, length and chemical resistance, are described in this work. Laboratory experiments were conducted on the fiber-reinforced concrete. The effects of fibrous content on compressive strength and flexural strength are presented. The experimental results showed the proper additive of MMVF in concrete can enhance its mechanical properties. MMVF products produced from incinerator ashes treated with the thermal plasma technique have great potential for reinforcement in concrete. 2010 Elsevier B.V. All rights reserved.

  19. DIAGNOSTICS OF HYBRID WATER/ARGON THERMAL PLASMA JET WITH WATER, ETHANOL AND THEIR MIXTURE INJECTION TO PLASMA

    Hlína, Michal; Mašláni, Alan; Medřický, Jan; Kotlan, Jiří; Mušálek, Radek; Hrabovský, Milan

    2016-01-01

    Roč. 3, č. 2 (2016), s. 62-65 ISSN 2336-2626. [SPPT 2016 - 27th Symposium on Plasma Physics and Technology/27./. Prague, 20.06.2016-23.06.2016] R&D Projects: GA ČR GA15-12145S Institutional support: RVO:61389021 Keywords : plasma spraying * suspension * enthalpy probe * spectroscopy * air entrainment Subject RIV: BL - Plasma and Gas Discharge Physics http://ppt.fel.cvut.cz/

  20. Laser schlieren deflectometry for temperature analysis of filamentary non-thermal atmospheric pressure plasma.

    Schäfer, J; Foest, R; Reuter, S; Kewitz, T; Šperka, J; Weltmann, K-D

    2012-10-01

    The heat convection generated by micro filaments of a self-organized non-thermal atmospheric pressure plasma jet in Ar is characterized by employing laser schlieren deflectometry (LSD). It is demonstrated as a proof of principle, that the spatial and temporal changes of the refractive index n in the optical beam path related to the neutral gas temperature of the plasma jet can be monitored and evaluated simultaneously. The refraction of a laser beam in a high gradient field of n(r) with cylindrical symmetry is given for a general real refraction index profile. However, the usually applied Abel approach represents an ill-posed problem and in particular for this plasma configuration. A simple analytical model is proposed in order to minimize the statistical error. Based on that, the temperature profile, specifically the absolute temperature in the filament core, the FWHM, and the frequencies of the collective filament dynamics are obtained for non-stationary conditions. For a gas temperature of 700 K inside the filament, the presented model predicts maximum deflection angles of the laser beam of 0.3 mrad which is in accordance to the experimental results obtained with LSD. Furthermore, the experimentally obtained FWHM of the temperature profile produced by the filament at the end of capillary is (1.5 ± 0.2) mm, which is about 10 times wider than the visual radius of the filament. The obtained maximum temperature in the effluent is (450 ± 30) K and is in consistence with results of other techniques. The study demonstrates that LSD represents a useful low-cost method for monitoring the spatiotemporal behaviour of microdischarges and allows to uncover their dynamic characteristics, e.g., the temperature profile even for challenging diagnostic conditions such as moving thin discharge filaments. The method is not restricted to the miniaturized and self-organized plasma studied here. Instead, it can be readily applied to other configurations that produce measurable

  1. Laser schlieren deflectometry for temperature analysis of filamentary non-thermal atmospheric pressure plasma

    Schaefer, J.; Foest, R.; Reuter, S.; Weltmann, K.-D. [INP Greifswald, Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany); Kewitz, T. [Institute of Experimental and Applied Physics, University Kiel, 24098 Kiel (Germany); Sperka, J. [Department of Physical Electronics, Masaryk University, 61137 Brno (Czech Republic)

    2012-10-15

    The heat convection generated by micro filaments of a self-organized non-thermal atmospheric pressure plasma jet in Ar is characterized by employing laser schlieren deflectometry (LSD). It is demonstrated as a proof of principle, that the spatial and temporal changes of the refractive index n in the optical beam path related to the neutral gas temperature of the plasma jet can be monitored and evaluated simultaneously. The refraction of a laser beam in a high gradient field of n(r) with cylindrical symmetry is given for a general real refraction index profile. However, the usually applied Abel approach represents an ill-posed problem and in particular for this plasma configuration. A simple analytical model is proposed in order to minimize the statistical error. Based on that, the temperature profile, specifically the absolute temperature in the filament core, the FWHM, and the frequencies of the collective filament dynamics are obtained for non-stationary conditions. For a gas temperature of 700 K inside the filament, the presented model predicts maximum deflection angles of the laser beam of 0.3 mrad which is in accordance to the experimental results obtained with LSD. Furthermore, the experimentally obtained FWHM of the temperature profile produced by the filament at the end of capillary is (1.5 {+-} 0.2) mm, which is about 10 times wider than the visual radius of the filament. The obtained maximum temperature in the effluent is (450 {+-} 30) K and is in consistence with results of other techniques. The study demonstrates that LSD represents a useful low-cost method for monitoring the spatiotemporal behaviour of microdischarges and allows to uncover their dynamic characteristics, e.g., the temperature profile even for challenging diagnostic conditions such as moving thin discharge filaments. The method is not restricted to the miniaturized and self-organized plasma studied here. Instead, it can be readily applied to other configurations that produce measurable

  2. Ions and electrons thermal effects on the fast-slow mode conversion process in a three components plasma

    Fidone, I.; Gomberoff, L.

    1977-07-01

    Fast-slow mode conversion in a deuterium plasma with a small amount of hydrogen impurity, for frequencies close to the two-ion hybrid frequency, is investigated. It is shown that while electron thermal effects tend to inhibit the wave conversion process, ion thermal effects tend to restore, qualitatively, the cold plasma properties, favouring therefore, the energy exchange between the two modes. The aforementioned effects are competitive for zetasub(o)sup(e)=1/nsub(parall).vsub(e)>=1. For zetasub(o)sup(e)<=1, electron thermal effects, in particular Landau damping, dominate over ion Larmor radius effects, drastically diminishing the wave conversion efficacy. For zetasub(o)sup(e)<<1, the coupling between the modes disappears altogether

  3. Fabrication of TiC-TiO{sub 2} composite powders by thermal plasma oxidation of titanium carbide powder; Tanka chitan funmatsu no plasma sanka hanno ni yori seiseishita TiC-TiO{sub 2} fukugo funmatsu

    Ishigaki, T.; Li, Y.; Haneda, H. [National institute for Research Inorganic materials, Tsukuba (Japan); Kataoka, E. [Showa Cabot Supermetals K.K., Tokyo (Japan)

    2000-09-15

    TiC-TiO{sub 2} composite powders were prepared by in-flight oxidation of titanium carbide powder in RF induction thermal plasmas. Original titanium carbide powder of 20 - 38 {mu}m in particle size was axially injected into the center of argon-oxygen plasma. The powders were partially spheroidized and evaporated through the plasma treatment. X-ray diffraction of plasma-treated powders showed the formation of titanium dioxides, both rutile and anatase phases. The phase content of the plasma-prepared powders strongly depended on the plasma conditions, such as the plasma generating pressure and the oxygen flow rate in plasma generating gas. Especially, the increase of oxygen flow rate in plasma gas gave rise to the increase of heat transfer from plasma to powder particles, exothermic heat of oxidation reaction and cooling rate of plasma, giving the increase of spheroidization ratio, formation ratio of titanium dioxides, and content of anatase phases. (author)

  4. Calcium titanate (CaTiO{sub 3}) dielectrics prepared by plasma spray and post-deposition thermal treatment

    Ctibor, Pavel [Materials Engineering Department, Institute of Plasma Physics ASCR, v.v.i., Za Slovankou 3, Prague 8 (Czech Republic); Kotlan, Jiri, E-mail: kotlan@ipp.cas.cz [Materials Engineering Department, Institute of Plasma Physics ASCR, v.v.i., Za Slovankou 3, Prague 8 (Czech Republic); Department of Electrotechnology, Faculty of Electrical Engineering, Czech Technical University in Prague, Technicka 2, Prague 6 (Czech Republic); Pala, Zdenek [Materials Engineering Department, Institute of Plasma Physics ASCR, v.v.i., Za Slovankou 3, Prague 8 (Czech Republic); Sedlacek, Josef [Department of Electrotechnology, Faculty of Electrical Engineering, Czech Technical University in Prague, Technicka 2, Prague 6 (Czech Republic); Hajkova, Zuzana; Grygar, Tomas Matys [Institute of Inorganic Chemistry ASCR, v.v.i., Husinec-Rez 1001, Rez (Czech Republic)

    2015-12-15

    Highlights: • Calcium titanate was sprayed by two different plasma spray systems. • Significant improvement of dielectric properties after annealing was observed. • Calcium titanate self-supporting parts can be fabricated by plasma spraying. - Abstract: This paper studies calcium titanate (CaTiO{sub 3}) dielectrics prepared by plasma spray technology. A water stabilized plasma gun (WSP) as well as a widely used gas stabilized plasma gun (GSP) were employed in this study to deposit three sample sets at different spray conditions. Prepared specimens were annealed in air at atmospheric pressure for 2 h at various temperatures from 530 to 1170 °C. X-ray diffraction (XRD), Raman spectroscopy and porosity measurements were used for sample characterization. Dielectric spectroscopy was applied to obtain relative permittivity, conductivity and loss factor frequency dependence. Band gap energy was estimated from reflectance measurements. The work is focused on the explanation of changes in microstructure and properties of a plasma sprayed deposit after thermal annealing. Obtained results show significant improvement of dielectric properties after thermal annealing.

  5. Development of non-thermal plasma jet and its potential application for color degradation of organic pollutant in wastewater treatment

    Pirdo Kasih, Tota; Kharisma, Angel; Perdana, Muhammad Kevin; Murphiyanto, Richard Dimas Julian

    2017-12-01

    This paper presents the development of non-thermal plasma-based AOPs for color degradation in wastewater treatment. The plasma itself was generated by an in-house high voltage power supply (HVPS). Instead of gas-phase plasma system, we applied plasma jet system underwater during wastewater treatment without additional any chemicals (chemical-free processing). The method is thought to maximize the energy transfer and increase the efficient interaction between plasma and solution during the process. Our plasma jet system could proceed either by using helium (He), argon (Ar) and air as the medium in an open air atmosphere. Exploring the developed plasma to be applied in organic wastewater treatment, we demonstrated that the plasma jet could be generated underwater and yields in color degradation of methylene blue (MB) wastewater model. When using Ar gas as a medium, the color degradation of MB could be achieved within 90 minutes. Whereas, by using Ar with an admixing of oxygen (O2) gas, the similar result could be accomplished within 60 minutes. Additional O2 gas in the latter might produce more hydroxyl radicals and oxygen-based species which speed up the oxidative reaction with organic pollutants, and hence accelerate the process of color degradation.

  6. Rocket-borne thermal plasma instrument "MIPEX" for the ionosphere D, E layer in-situ measurements

    Fang, H. K.; Chen, A. B. C.; Lin, C. C. H.; Wu, T. J.; Liu, K. S.; Chuang, C. W.

    2017-12-01

    In this presentation, the design concepts, performances and status of a thermal plasma particle instrument package "Mesosphere and Ionosphere Plasma Exploration complex (MIPEX)", which is going to be installed onboard a NSPO-funded hybrid rocket, to investigate the electrodynamic processes in ionosphere D, E layers above Taiwan are reported. MIPEX is capable of measuring plasma characteristics including ion temperature, ion composition, ion drift, electron temperature and plasma density at densities as low as 1-10 cm-1. This instrument package consists of an improved retarding potential analyzer with a channel electron multiplier (CEM), a simplified ion drift meter and a planar Langmuir probe. To achieve the working atmospheric pressure of CEM at the height of lower D layer ( 70km), a portable vacuum pump is also placed in the package. A prototype set of the MIPEX has been developed and tested in the Space Plasma Operation Chamber (SPOC) at NCKU, where in ionospheric plasma is generated by back-diffusion plasma sources. A plasma density of 10-106 cm-1, ion temperature of 300-1500 K and electron temperature of 1000-3000K is measured and verified. Limited by the flight platform and the performance of the instruments, the in-situ plasma measurements at the Mesosphere and lower Thermosphere is very challenging and rare. MIPEX is capable of extending the altitude of the effective plasma measurement down to 70 km height and this experiment can provide unique high-quality data of the plasma environment to explore the ion distribution and the electrodynamic processes in the Ionosphere D, E layers at dusk.

  7. Time-resolved electron thermal conduction by probing of plasma formation in transparent solids with high power subpicosecond laser pulses

    Vu, Brian -Tinh Van [Univ. of California, Davis, CA (United States)

    1994-02-01

    This dissertation work includes a series of experimental measurements in a search for better understanding of high temperature (104-106K) and high density plasmas (1022-1024cm-3) produced by irradiating a transparent solid target with high intensity (1013 - 1015W/cm2) and subpicosecond (10-12-10-13s) laser pulses. Experimentally, pump and probe schemes with both frontside (vacuum-plasma side) and backside (plasma-bulk material side) probes are used to excite and interrogate or probe the plasma evolution, thereby providing useful insights into the plasma formation mechanisms. A series of different experiments has been carried out so as to characterize plasma parameters and the importance of various nonlinear processes. Experimental evidence shows that electron thermal conduction is supersonic in a time scale of the first picosecond after laser irradiation, so fast that it was often left unresolved in the past. The experimental results from frontside probing demonstrate that upon irradiation with a strong (pump) laser pulse, a thin high temperature (~40eV) super-critical density (~1023/cm3) plasma layer is quickly formed at the target surface which in turn becomes strongly reflective and prevents further transmission of the remainder of the laser pulse. In the bulk region behind the surface, it is also found that a large sub-critical (~1018/cm3) plasma is produced by inverse Bremsstrahlung absorption and collisional ionization. The bulk underdense plasma is evidenced by large absorption of the backside probe light. A simple and analytical model, modified from the avalanche model, for plasma evolution in transparent materials is proposed to explain the experimental results. Elimination of the bulk plasma is then experimentally illustrated by using targets overcoated with highly absorptive films.

  8. Time-resolved electron thermal conduction by probing of plasma formation in transparent solids with high power subpicosecond laser pulses

    Vu, B.T.V.

    1994-02-01

    This dissertation work includes a series of experimental measurements in a search for better understanding of high temperature (10 4 -10 6 K) and high density plasmas (10 22 -10 24 cm -3 ) produced by irradiating a transparent solid target with high intensity (10 13 - 10 15 W/cm 2 ) and subpicosecond (10 -12 -10 -13 s) laser pulses. Experimentally, pump and probe schemes with both frontside (vacuum-plasma side) and backside (plasma-bulk material side) probes are used to excite and interrogate or probe the plasma evolution, thereby providing useful insights into the plasma formation mechanisms. A series of different experiments has been carried out so as to characterize plasma parameters and the importance of various nonlinear processes. Experimental evidence shows that electron thermal conduction is supersonic in a time scale of the first picosecond after laser irradiation, so fast that it was often left unresolved in the past. The experimental results from frontside probing demonstrate that upon irradiation with a strong (pump) laser pulse, a thin high temperature (∼40eV) super-critical density (∼10 23 /cm 3 ) plasma layer is quickly formed at the target surface which in turn becomes strongly reflective and prevents further transmission of the remainder of the laser pulse. In the bulk region behind the surface, it is also found that a large sub-critical (∼10 18 /cm 3 ) plasma is produced by inverse Bremsstrahlung absorption and collisional ionization. The bulk underdense plasma is evidenced by large absorption of the backside probe light. A simple and analytical model, modified from the avalanche model, for plasma evolution in transparent materials is proposed to explain the experimental results. Elimination of the bulk plasma is then experimentally illustrated by using targets overcoated with highly absorptive films

  9. Thermal and mechanical design of the plasma core CXRS diagnostics for the fusion reactor ITER; Thermische und mechanische Auslegung der Plasma Core CXRS Diagnostik des ITER Kernfusionsreaktors

    Greza, H. [WTI Wissenschaftlich-Technische Ingenieurberatung GmbH, Juelich (Germany); Neubauer, O.; Wolters, J. [Forschungszentrum Juelich GmbH (Germany)

    2009-07-01

    In the frame of the research project ITER (international thermonuclear experimental reactor) the plasma state is monitored using the plasma core diagnostics CXRS (charge exchange recombination spectroscopy).The authors describe the thermal and mechanical design of the first mirror of the CXRS diagnostics. The components of the first mirror are exposed to high heat and neutron irradiation. The surface temperature will be 300 to 400 deg C. The misalignment tolerance is plus or minus 0.1 degree. The maximum mechanical stresses in the mirror have to be minimized. The design calculations use the finite element code ANSYS. The results indicate that the heat input from the plasma can be removed by the coolant flow. Further calculation shave to concern the brazed joints between mirror and cooling block.

  10. Thermal and mechanical design of the plasma core CXRS diagnostics for the fusion reactor ITER; Thermische und mechanische Auslegung der Plasma Core CXRS Diagnostik des ITER Kernfusionsreaktors

    Greza, H.; Knauff, R. [Wissenschaftlich-Technische Ingenieurberatung GmbH (WTI), Juelich (Germany); Neubauer, O.; Wolters, J.; Offermanns, G.; Biel, W. [Forschungszentrum Juelich GmbH (Germany)

    2011-07-01

    In the frame of the research project ITER (international thermonuclear experimental reactor) the plasma state is monitored using the plasma core diagnostics CXRS (charge exchange recombination spectroscopy).The authors describe the thermal and mechanical design of the first mirror of the CXRS diagnostics. The components of the first mirror are exposed to high heat and neutron irradiation. The surface temperature will be 300 to 400 deg C. The misalignment tolerance is plus or minus 0.1 degree. The maximum mechanical stresses in the mirror have to be minimized. The design calculations use the finite element code ANSYS. The results indicate that the heat input from the plasma can be removed by the coolant flow. Further calculation shave to concern the brazed joints between mirror and cooling block.

  11. Optimized functionally graded La2Zr2O7/8YSZ thermal barrier coatings fabricated by suspension plasma spraying

    Wang, Chaohui; Wang, You; Fan, Shan; You, Yuan; Wang, Liang; Yang, Changlong; Sun, Xiaoguang; Li, Xuewei

    2015-01-01

    In this paper, an optimized functionally graded coating (OFGC) was successfully fabricated by suspension plasma spraying (SPS) with feedstocks of the suspension of nanoparticles. La 2 Zr 2 O 7 /8YSZ OFGC with gradual compositional variation along the through-thickness direction is proposed to mitigate spallation and crack formation owing to the high residual stresses caused by frequent thermal cycling for TBCs. The single ceramic layer coatings (SCLC) of LZ and double ceramic layer coatings (DCLC) of LZ/8YSZ were fabricated by SPS as comparison. The phase composition and microstructure of the SCLC, OFGC and DCLC were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and Energy Dispersive Spectrometer (EDS). Moreover, the thermal cycling tests were carried out to evaluate their thermal shock behavior. Changes in weight and morphology of specimens were analyzed during thermal cycling tests. The results showed that OFGC has extended lifetime compared with SCLC and DCLC. The failure of DCLC with clear interface between different ceramic layers occurred via delamination mode, as a result of crack initiation and propagation generated by thermal mismatch between LZ and 8YSZ. While the failure of OFGC occurred in thermally grown oxide (TGO) layers, indicating that the gradual compositional variation avoided thermal stress concentration in the top ceramic layers. - Highlights: • Optimized functionally graded coatings and double ceramic layer coatings were deposited by suspension plasma spray. • The graded area of OFGC is continuously changed from inner 8YSZ to outer La 2 Zr 2 O 7 (LZ). • The OFGC shows a more extended thermal cycling life than the LZ SCLC and LZ/8YSZ DCLC. • Various failure mechanisms were proposed to explain thermal cycling behavior

  12. PREFACE: 1st International Symposium on Electrical Arc and Thermal Plasmas in Africa (ISAPA)

    Andre, Pascal; Koalaga, Zacharie

    2012-02-01

    Logos of the University of Ouagadougou, ISAPA and Universite Blaise Pascal Africa (especially Sub-Saharan Africa) is a continent where electrification is at a low level. However, the development of the electrical power sector is a prerequisite for the growth of other industrial activities, that is to say for the social and economic development of African countries. Consequently, a large number of electrification projects (rural electrification, interconnection of different country's grids) takes place in many countries. These projects need expertise and make Africa a continent of opportunity for companies in different domains for business and research: energy; energetic production, transmission, distribution and protection of electricity; the supply of cable; the construction, engineering and expertise in the field of solar and wind power. The first International Symposium on electrical Arc and thermal Plasma in Africa (ISAPA) was held for the first time in Ouagadougou, Burkina Faso to progress and develop the research of new physical developments, technical breakthroughs, and ideas in the fields of electrical production and electrical applications. The ISAPA aims to encourage the advancement of the science and applications of electrical power transformation in Africa by bringing together specialists from many areas in Africa and the rest of the world. Such considerations have led us to define a Scientific Committee including representatives from many countries. This first meeting was an innovative opportunity for researchers and engineers from academic and industrial sectors to exchange views and knowledge. Both fundamental aspects such as thermal plasma, electrical arc, diagnostics and applied aspects as circuit breakers, ICP analyses, photovoltaic energy conversion and alternative energies, as well as space applications were covered. The Laboratory of Material and Environment (LAME) from Ouagadougou University and the Laboratory of Electric Arc and Thermal

  13. EFFECT OF FINITE LARMOR RADIUS CORRECTIONS ON THE THERMAL INSTABILITY OF THERMALLY CONDUCTING VISCOUS PLASMA WITH HALL CURRENT AND ELECTRON INERTIA

    Jain, Shweta; Sharma, Prerana [Physics Department, Ujjain Engineering College, Ujjain, MP-456010 (India); Kaothekar, Sachin [Physics Department, Mahakal Institute of Technology, Ujjain, MP-456664 (India); Chhajlani, R. K., E-mail: sackaothekar@gmail.com [Retired, School of Studies in Physics, Vikram University Ujjain, MP-456010 (India)

    2016-10-01

    The thermal instability of an infinite homogeneous, thermally conducting, and rotating plasma, incorporating finite electrical resistivity, finite electron inertia, and an arbitrary radiative heat-loss function in the presence of finite Larmor radius corrections and Hall current, has been studied. Analysis has been made with the help of linearized magnetohydrodynamics (MHD) equations. A general dispersion relation is obtained using the normal mode analysis method, and the dispersion relation is discussed for longitudinal propagation and transverse propagation separately. The dispersion relation has been solved numerically to obtain the dependence of the growth rate on the various parameters involved. The conditions of modified thermal instability and stability are discussed in the different cases of interest.

  14. Ion-pairing reversed-phase chromatography coupled to inductively coupled plasma mass spectrometry as a tool to determine mercurial species in freshwater fish.

    Cheng, Heyong; Chen, Xiaopan; Shen, Lihuan; Wang, Yuanchao; Xu, Zigang; Liu, Jinhua

    2018-01-05

    Most of analytical community is focused on reversed phase high performance liquid chromatography (RP-HPLC) for mercury speciation by employing mobile phases comprising of high salts and moderate amounts of organic solvents. This study aims at rapid mercury speciation analysis by ion-pairing RP-HPLC with inductively coupled plasma mass spectrometry (ICP-MS) detection only using low salts for the sake of green analytical chemistry. Two ion-pairing HPLC methods were developed on individual usage of positively and negatively charged ion-pairing reagents (tetrabutylammonium hydroxide -TBAH and sodium dodecylbenzene sulfonate -SDBS), where sodium 3-mercapto-1-propysulfonate (MPS) and l-cysteine (Cys) were individually added in mobile phases to transform mercury species into negative and positive Hg-complexes for good resolution. Addition of phenylalanine was also utilized for rapid baseline separation in combination of short C 18 guard columns. Optimum mobile phases of 2.0mM SDBS+2.0mM Cys+1.0mM Phe (pH 3.0) and 4.0mM TBAH+2.0mM MPS+2.0mM Phe (pH 6.0) both achieved baseline separation of inorganic mercury (Hg 2+ ), methylmercury (MeHg), ethylmercury (EtHg) and phenylmercury (PhHg) on two consecutive 12.5-mm C 18 columns. The former mobile phase was selected for mercury speciation in freshwater fish because of short separation time (3.0min). Detection limits of 0.015 for Hg 2+ , 0.014 for MeHg, 0.028 for EtHg and 0.042μgL -1 for PhHg were obtained along with satisfactory precisions of peak height and area (1.0-2.8% for 5.0μgL -1 Hg-mixture standard). Good accordance of determined values of MeHg and total mercury in certified reference materials of fish tissue (GBW 10029) and tuna fish (BCR-463) with certified values as well as good recoveries (91-106%) proved good accuracy of the proposed method. An example application to freshwater fish indicated its potential in routine analysis, where MeHg was presented at 3.7-20.3μgkg -1 as the dominate species. Copyright © 2017

  15. Super-Gaussian transport theory and the field-generating thermal instability in laser–plasmas

    Bissell, J J; Ridgers, C P; Kingham, R J

    2013-01-01

    Inverse bremsstrahlung (IB) heating is known to distort the electron distribution function in laser–plasmas from a Gaussian towards a super-Gaussian, thereby modifying the equations of classical transport theory (Ridgers et al 2008 Phys. Plasmas 15 092311). Here we explore these modified equations, demonstrating that super-Gaussian effects both suppress traditional transport processes, while simultaneously introducing new effects, such as isothermal (anomalous Nernst) magnetic field advection up gradients in the electron number density n e , which we associate with a novel heat-flow q n ∝∇n e . Suppression of classical phenomena is shown to be most pronounced in the limit of low Hall-parameter χ, in which case the Nernst effect is reduced by a factor of five, the ∇T e × ∇n e field generation mechanism by ∼30% (where T e is the electron temperature), and the diffusive and Righi–Leduc heat-flows by ∼80 and ∼90% respectively. The new isothermal field advection phenomenon and associated density-gradient driven heat-flux q n are checked against kinetic simulation using the Vlasov–Fokker–Planck code impact, and interpreted in relation to the underlying super-Gaussian distribution through simplified kinetic analysis. Given such strong inhibition of transport at low χ, we consider the impact of IB on the seeding and evolution of magnetic fields (in otherwise un-magnetized conditions) by examining the well-known field-generating thermal instability in the light of super-Gaussian transport theory (Tidman and Shanny 1974 Phys. Fluids 12 1207). Estimates based on conditions in an inertial confinement fusion (ICF) hohlraum suggest that super-Gaussian effects can reduce the growth-rate of the instability by ≳80%. This result may be important for ICF experiments, since by increasing the strength of IB heating it would appear possible to inhibit the spontaneous generation of large magnetic fields. (paper)

  16. Super-Gaussian transport theory and the field-generating thermal instability in laser-plasmas

    Bissell, J. J.; Ridgers, C. P.; Kingham, R. J.

    2013-02-01

    Inverse bremsstrahlung (IB) heating is known to distort the electron distribution function in laser-plasmas from a Gaussian towards a super-Gaussian, thereby modifying the equations of classical transport theory (Ridgers et al 2008 Phys. Plasmas 15 092311). Here we explore these modified equations, demonstrating that super-Gaussian effects both suppress traditional transport processes, while simultaneously introducing new effects, such as isothermal (anomalous Nernst) magnetic field advection up gradients in the electron number density ne, which we associate with a novel heat-flow qn∝∇ne. Suppression of classical phenomena is shown to be most pronounced in the limit of low Hall-parameter χ, in which case the Nernst effect is reduced by a factor of five, the ∇Te × ∇ne field generation mechanism by ˜30% (where Te is the electron temperature), and the diffusive and Righi-Leduc heat-flows by ˜80 and ˜90% respectively. The new isothermal field advection phenomenon and associated density-gradient driven heat-flux qn are checked against kinetic simulation using the Vlasov-Fokker-Planck code impact, and interpreted in relation to the underlying super-Gaussian distribution through simplified kinetic analysis. Given such strong inhibition of transport at low χ, we consider the impact of IB on the seeding and evolution of magnetic fields (in otherwise un-magnetized conditions) by examining the well-known field-generating thermal instability in the light of super-Gaussian transport theory (Tidman and Shanny 1974 Phys. Fluids 12 1207). Estimates based on conditions in an inertial confinement fusion (ICF) hohlraum suggest that super-Gaussian effects can reduce the growth-rate of the instability by ≳80%. This result may be important for ICF experiments, since by increasing the strength of IB heating it would appear possible to inhibit the spontaneous generation of large magnetic fields.

  17. Plasma arc and thermal lance techniques for cutting concrete and steel

    Bargagliotti, A.; Caprile, L.; Piana, F.; Tolle, E.

    1986-01-01

    The plasma arc technique is used today in industrial practice for any metal, but mainly for cutting stainless steel, carbon steel and aluminium. In air the maximum thickness that was cut in the performed tests was 150 mm, both with ferritic and austenitic steel. Underwater the maximum thickness cut was 103 mm. The two types of torch used in the tests are those used today: the plasma-shaped electrode torch (WIPC) and the pointed electrode torch (DMC-GRUEN). Two different types of gas were compared: an argon-nitrogen mixture and an argon-hydrogen mixture. The second mixture adopted results in less dust emission. The production of dust and aerosols also depends on the cutting speed, on the kind of steel, but mainly on the environmental conditions; it is reduced up to 500 times under water. Dust and aerosols can, jeopardize the efficiency of the system; moreover, the ambient air can have high-level radiation fields. Indirect and direct protections are needed (shields, remote control, robots, etc.). Tentative procedures for dismantling two types of BWR reactor are examined. Two series of tests demonstrated the feasibility of cutting the most geometrically difficult parts of the reactor internals. The thermal lance technique is used in industrial practice mainly for dismantling large reinforced concrete structures. This technique can be applied to dismantle nuclear facilities, even though it can cause some problems due to the gases, fumes and lapilli produced. In addition, the cost of this technique seems to be generally higher than the cost of other techniques. From the analyses done, the conclusion seems that both the above techniques are feasible for dismantling a nuclear power plant (NPP). The best solution is probably to analyse the different dismantling possibilities and problems and problems of each case

  18. Cell death induced on cell cultures and nude mouse skin by non-thermal, nanosecond-pulsed generated plasma.

    Arnaud Duval

    Full Text Available Non-thermal plasmas are gaseous mixtures of molecules, radicals, and excited species with a small proportion of ions and energetic electrons. Non-thermal plasmas can be generated with any high electro-magnetic field. We studied here the pathological effects, and in particular cell death, induced by nanosecond-pulsed high voltage generated plasmas homogeneously applied on cell cultures and nude mouse skin. In vitro, Jurkat cells and HMEC exhibited apoptosis and necrosis, in dose-dependent manner. In vivo, on nude mouse skin, cell death occurred for doses above 113 J/cm(2 for the epidermis, 281 J/cm(2 for the dermis, and 394 J/cm(2 for the hypodermis. Using electron microscopy, we characterized apoptosis for low doses and necrosis for high doses. We demonstrated that these effects were not related to thermal, photonic or pH variations, and were due to the production of free radicals. The ability of cold plasmas to generate apoptosis on cells in suspension and, without any sensitizer, on precise skin areas, opens new fields of application in dermatology for extracorporeal blood cell treatment and the eradication of superficial skin lesions.

  19. Investigating the Plasma-Assisted and Thermal Catalytic Dry Methane Reforming for Syngas Production: Process Design, Simulation and Evaluation

    Evangelos Delikonstantis

    2017-09-01

    Full Text Available The growing surplus of green electricity generated by renewable energy technologies has fueled research towards chemical industry electrification. By adapting power-to-chemical concepts, such as plasma-assisted processes, cheap resources could be converted into fuels and base chemicals. However, the feasibility of those electrified processes at large scale has not been investigated yet. Thus, the current work strives to compare, for first time in the literature, plasma-assisted production of syngas, from CH4 and CO2 (dry methane reforming, with thermal catalytic dry methane reforming. Specifically, both processes are conceptually designed to deliver syngas suitable for methanol synthesis (H2/CO ≥ 2 in mole. The processes are simulated in the Aspen Plus process simulator where different process steps are investigated. Heat integration and equipment cost estimation are performed for the most promising process flow diagrams. Collectively, plasma-assisted dry methane reforming integrated with combined steam/CO2 methane reforming is an effective way to deliver syngas for methanol production. It is more sustainable than combined thermal catalytic dry methane reforming with steam methane reforming, which has also been proposed for syngas production of H2/CO ≥ 2; in the former process, 40% more CO2 is captured, while 38% less H2O is consumed per mol of syngas. Furthermore, the plasma-assisted process is less complex than the thermal catalytic one; it requires higher amount of utilities, but comparable capital investment.

  20. Low cycle thermal fatigue testing of beryllium grades for ITER plasma facing components

    Watson, R.D.; Youchison, D.L.; Dombrowski, D.E.; Guiniatouline, R.N.; Kupriynov, I.B.

    1996-01-01

    A novel technique has been used to test the relative low cycle thermal fatigue resistance of different grades of US and Russian beryllium, which is proposed as plasma facing armor for fusion reactor first wall, limiter, and divertor components. The 30 kW electron beam test system at Sandia National Laboratories was used to sweep the beam spot along one direction at 1 Hz. This produces a localized temperature ''spike'' of 750 degree C for each pass of the beam. Large thermal stresses in excess of the yield strength are generated due to very high spot heat flux, 250 MW/m 2 . Cyclic plastic strains on the order of 0.6% produced visible cracking on the heated surface in less than 3000 cycles. An in-vacuo fiber optic borescope was used to visually inspect the beryllium surfaces for crack initiation. Grades of US beryllium tested included: S-65C, S- 65H, S-200F, S-200F-H, SR-200, I-400, extruded high purity, HIP'd spherical powder, porous beryllium (94% and 98% dense), Be/30% BeO, Be/60% BeO, and TiBe 12 . Russian grades included: TGP-56, TShGT, DShG-200, and TShG-56. Both the number of cycles to crack initiation, and the depth of crack propagation, were measured. The most fatigue resistant grades were S-65C, DShG-200, TShGT, and TShG-56. Rolled sheet Be (SR-200) showed excellent crack propagation resistance in the plane of rolling, despite early formation of delamination cracks. Only one sample showed no evidence of surface melting, Extruded (T). Metallographic and chemical analyses are provided. Good agreement was found between the measured depth of cracks and a 2-D elastic-plastic finite element stress analysis