WorldWideScience

Sample records for temperature ceramic superconductors

  1. Ceramic high-temperature superconductors

    International Nuclear Information System (INIS)

    Marquart, R.

    1989-01-01

    The contribution presents an overview treatment of the structure of the new superconductors (YBa 2 Cu 3 O 7-x ). Methods of powder production and processing technology are described, with current development projects by Dornier being taken into consideration. (orig.) [de

  2. Ceramic high temperature superconductor levitating motor with laser commutator

    International Nuclear Information System (INIS)

    Roslan Abd Shukor; Lee Keng Heong

    1996-01-01

    The design of a magnetically levitating motor using a ceramic high temperature superconductor with laser commutator is discussed. A YBa sub 2 Cu sub 3 O sub 7-δ high temperature superconductor with 25 mm diameter and 6 mm thickness is used to levitate a Nd-Fe-B magnet (19.0 mm diameter and 4.8 mm thickness) which is attached symmetrically to a 150 mm long graphite rod. A smaller magnet (5.5 mm diameter and 2.0 mm thickness) is attached at each end of the rod with the appropriate poles arrangements. A suitable laser beam chopper is used to optically drive a solenoid which repels the smaller magnets thus driving the motor. A simple and efficient liquid nitrogen supply system is designed to cool the superconductor. The stability of the bearing is provided by the flux pinning in this type-II superconductor. Some characteristics of the motor are discussed

  3. Dense high temperature ceramic oxide superconductors

    Science.gov (United States)

    Landingham, Richard L.

    1993-01-01

    Dense superconducting ceramic oxide articles of manufacture and methods for producing these articles are described. Generally these articles are produced by first processing these superconducting oxides by ceramic processing techniques to optimize materials properties, followed by reestablishing the superconducting state in a desired portion of the ceramic oxide composite.

  4. Sealed glass coating of high temperature ceramic superconductors

    Science.gov (United States)

    Wu, Weite; Chu, Cha Y.; Goretta, Kenneth C.; Routbort, Jules L.

    1995-01-01

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

  5. Ceramic superconductors II

    International Nuclear Information System (INIS)

    Yan, M.F.

    1988-01-01

    This volume compiles papers on ceramic superconductors. Topics include: structural patterns in High-Tc superconductors, phase equilibria of barium oxide superconductors, localized electrons in tetragonal YBa/sub 2/Cu/sub 3/O/sub 7-δ/, lattice and defect structure and properties of rare earth/alkaline earth-copper-oxide superconductors, alternate candidates for High-Tc superconductors, perovskite-structure superconductors; superconductive thin film fabrication, and superconductor/polymer composites

  6. Application of high temperature ceramic superconductors (CSC) to commercial tokamak reactors

    International Nuclear Information System (INIS)

    Ehst, D.A.; Kim, S.; Gohar, Y.; Turner, L.; Smith, D.L.; Mattas, R.

    1987-10-01

    Ceramic superconductors operating near liquid nitrogen temperature may experience higher heating rates without losing stability, compared to conventional superconductors. This will permit cable design with less stabilizer, reducing fabrication costs for large fusion magnets. Magnet performance is studied for different operating current densities in the superconductor, and cost benefits to commercial tokamak reactors are estimated. It appears that 10 kA . cm -2 (at 77 K and ∼10 T) is a target current density which must be achieved in order for the ceramic superconductors to compete with conventional materials. At current densities around 50 kA . cm -2 most potential benefits have already been gained, as magnet structural steel begins to dominate the cost at this point. For a steady state reactor reductions of ∼7% are forecast for the overall capital cost of the power plant in the best case. An additional ∼3% cost saving is possible for pulsed tokamaks. 9 refs., 4 figs., 8 tabs

  7. Oxide glass to high temperature ceramic superconductors - a novel route

    International Nuclear Information System (INIS)

    Chaudhuri, B.K.; Som, K.K.

    1992-01-01

    Recently it has been discovered that many of transition metal oxide (TMO) glasses like Bi-Sr-Ca-Cu-O, Y-Ba-Cu-O, Bi-Pb-Sr-Ca-Cu-O etc. can be directly converted to the corresponding high temperature superconducting phases by properly annealing the respective glasses. In this review recent developements in this field are summarised. The structural, electrical, dielectrical, magnetic, optical, and other properties of these new type of (TMO) glass systems have been elucidated comparing them with the corresponding results of already known (TMO) glasses which do not become superconductors on annealing above their glass transition temperatures (T g ). The electrical properties of this novel glass system have been analysed with reference to the various existing theoretical models based on polaron hopping conduction mechanism. The electrical, magnetic, and other properties of the respective superconductors obtained from their corresponding glass phases by annealing above (T g ) and the possibility of drawing wires, ribbons etc. from these glass matrices and then converting them to their high T c superconducting phases have also been discussed. (author). 107 refs., 32 figs., 5 tabs

  8. Nonaqueous slip casting of high temperature ceramic superconductors using an investment casting technique

    Science.gov (United States)

    Hooker, Matthew W. (Inventor); Taylor, Theodore D. (Inventor); Wise, Stephanie A. (Inventor); Buckley, John D. (Inventor); Vasquez, Peter (Inventor); Buck, Gregory M. (Inventor); Hicks, Lana P. (Inventor)

    1993-01-01

    A process for slip casting ceramic articles that does not employ parting agents and affords the casting of complete, detailed, precision articles that do not possess parting lines is presented. This process is especially useful for high temperature superconductors and water-sensitive ceramics. A wax pattern for a shell mold is provided, and an aqueous mixture of a calcium sulfate-bonded investment material is applied as a coating to the wax pattern. The coated wax pattern is then dried, followed by curing to vaporize the wax pattern and leave a shell mold of the calcium sulfate-bonded investment material. The shell mold is cooled to room temperature, and a ceramic slip, created by dispersing a ceramic powder in an organic liquid, is poured therein. After a ceramic shell of desired thickness or a solid article has set up in the shell mold, excess ceramic slip is poured out. The shell mold is misted with water and peeled away from the ceramic article, after which the ceramic is fired to provide a complete, detailed, precision, high temperature superconductive ceramic article without parting lines. The casting technique may take place in the presence of a magnetic field to orient the ceramic powders during the casting process.

  9. Hard-Wired Dopant Networks and the Prediction of High Transition Temperatures in Ceramic Superconductors

    International Nuclear Information System (INIS)

    Phillips, J.C.

    2010-01-01

    The review multiple successes of the discrete hard-wired dopant network model ZZIP, and comment on the equally numerous failures of continuum models, in describing and predicting the properties of ceramic superconductors. The prediction of transition temperatures can be regarded in several ways, either as an exacting test of theory, or as a tool for identifying theoretical rules for defining new homology models. Popular first principle methods for predicting transition temperatures in conventional crystalline superconductors have failed for cuprate HTSC, as have parameterized models based on CuO2 planes (with or without apical oxygen). Following a path suggested by Bayesian probability, it was found that the glassy, self-organized dopant network percolative model is so successful that it defines a new homology class appropriate to ceramic superconductors. The reasons for this success in an exponentially complex (non-polynomial complete, NPC) problem are discussed, and a critical comparison is made with previous polynomial (PC) theories. The predictions are successful for the superfamily of all ceramics, including new non-cuprates based on FeAs in place of CuO2.

  10. Application of high temperature ceramic superconductors (CSC) to commercial tokamak reactors

    International Nuclear Information System (INIS)

    Ehst, D.A.; Kim, S.; Gohar, Y.; Turner, L.; Smith, D.L.; Mattas, R.

    1988-08-01

    Ceramic superconductors operating near liquid nitrogen temperature may experience higher heating rates without losing stability, compared conventional superconductors. This will permit cable design with less stabilizer, reducing fabrication costs for large fusion magnets. Magnet performance is studied for different operating current densities in the superconductor, and cost benefits to commercial tokamak reactors are estimated. It appears that 10 kA /center dot/ cm/sup /minus/2/ (at 77 K and /approximately/10 T) is a target current density which must be achieved in order for the ceramic superconductors to compete with conventional materials. At current densities around 50 kA /center dot/ cm/sup /minus/2/ most potential benefits have already been gained, as magnet structural steel begins to dominate the cost at this point. For a steady state reactor reductions of /approximately/7% are forecast for the overall capital cost of the power plant in the best case. An additional /approximately/3% cost saving is possible for pulsed tokamaks. 9 refs., 4 figs., 8 tabs

  11. Ceramic high temperature superconductors for high current applications

    Energy Technology Data Exchange (ETDEWEB)

    Christiansen, J

    1997-12-31

    Composite Reaction Texturing (CRT) is a technique which uses a fine distribution of pre-aligned seeds as nucleating sites for texturing oxide superconductors. It has successfully been applied to the texturing of Bi-2212 compounds. A furhter application of CRT is reported in which Y-123 is biaxially textured using seeds of other Rare Earth-123 compounds with higher melting points as nucleating sites. The resultant textured microstructure exhibits mainly low angle grain boundaries (up to 5 deg. misorientation). Results will be presented on the seed alignment techniques, the development of microstructure during reaction of the composite preform and preliminary measurements of electromagnetic properties. (au). 111 refs.

  12. Ceramic high temperature superconductors for high current applications

    Energy Technology Data Exchange (ETDEWEB)

    Christiansen, J.

    1996-12-31

    Composite Reaction Texturing (CRT) is a technique which uses a fine distribution of pre-aligned seeds as nucleating sites for texturing oxide superconductors. It has successfully been applied to the texturing of Bi-2212 compounds. A furhter application of CRT is reported in which Y-123 is biaxially textured using seeds of other Rare Earth-123 compounds with higher melting points as nucleating sites. The resultant textured microstructure exhibits mainly low angle grain boundaries (up to 5 deg. misorientation). Results will be presented on the seed alignment techniques, the development of microstructure during reaction of the composite preform and preliminary measurements of electromagnetic properties. (au). 111 refs.

  13. Ceramic high temperature superconductors for high current applications

    International Nuclear Information System (INIS)

    Christiansen, J.

    1996-01-01

    Composite Reaction Texturing (CRT) is a technique which uses a fine distribution of pre-aligned seeds as nucleating sites for texturing oxide superconductors. It has successfully been applied to the texturing of Bi-2212 compounds. A furhter application of CRT is reported in which Y-123 is biaxially textured using seeds of other Rare Earth-123 compounds with higher melting points as nucleating sites. The resultant textured microstructure exhibits mainly low angle grain boundaries (up to 5 deg. misorientation). Results will be presented on the seed alignment techniques, the development of microstructure during reaction of the composite preform and preliminary measurements of electromagnetic properties. (au)

  14. Method of depositing thin films of high temperature Bi-Sr-Ca-Cu-O-based ceramic oxide superconductors

    International Nuclear Information System (INIS)

    Budd, K.D.

    1991-01-01

    This patent describes a method. It comprises preparing a liquid precursor of a Bi-Sr-Ca-Cu-O- based ceramic oxide superconductor phase, wherein the liquid precursor comprises an alkoxyalkanol, copper acrylate, strontium acrylate, bismuth nitrate, and calcium nitrate, wherein the liquid precursor has a cation ratio sufficient to form the desired stoichiometry in the ceramic oxide superconductor phase when the liquid precursor is heated to a temperature and for a time sufficient to provide the desired ceramic oxide superconductor phase, and wherein the copper acrylate, strontium acrylate, bismuth nitrate, and calcium nitrate are mutually soluble in the alkoxyalkanol; applying the liquid precursor to a substrate, wherein the substrate is one of an oxide ceramic, a metal selected from the group consisting of Ag and Ni, and Si; and heating the substrate in an oxygen-containing atmosphere with the liquid precursor applied thereon to a temperature and for a time sufficient to form a thin film comprising at least one Bi-Sr- Ca-Cu-O-based high temperature ceramic oxide superconductor phase

  15. Studies on ceramic superconductors

    International Nuclear Information System (INIS)

    Chaklader, A.C.D.; Roemer, G.; Hardy, W.N.; Brewer, J.H.; Carolan, J.F.; Parsons, R.R.

    1987-01-01

    The superconducting properties of both bulk specimens and sputtered thin films of the YBa 2 Cu 3 O x compound have been studied. The bulk specimens were fabricated by cold pressing and sintering, and also by hot-pressing (subsequent reheating). The dc resistivity measurements showed a sharp drop in the temperature range 92-87K in this material. Muon spin relaxation (μSR) measurements of sintered discs in 3.4 kOe revealed the formation of a mixed state with an effective magnetic penetration depth λ ∼ 1365 angstrom at 6K, implying an effective charge carrier density of 6 x 10 21 cm -3 . The temperature dependence λ(T) is that of an ordinary s-wave superconductor. The resistivity of the thin film prepared from the compound by dc planar magnetron sputtering, showed a sharp drop to a very low value near 80K. The compound YBa 2 Cu 3 O x loses its superconducting properties, when either hot-pressed (in air) or oxidized at 500 degree C in high O 2 pressure, but this property can be restored when reheated in one atmosphere of O 2 above 900 degree C

  16. Chemistry of high temperature superconductors

    CERN Document Server

    1991-01-01

    This review volume contains the most up-to-date articles on the chemical aspects of high temperature oxide superconductors. These articles are written by some of the leading scientists in the field and includes a comprehensive list of references. This is an essential volume for researchers working in the fields of ceramics, materials science and chemistry.

  17. Far infrared reflectivity study of ceramic superconductors

    International Nuclear Information System (INIS)

    Memon, A.; Khan, M.N.; Al-Dallal, S.; Tanner, D.B.; Porter, C.D.

    1992-01-01

    In this paper, the authors report on a study of the far-infrared reflectivity of mixed rare earths and lanthnides ceramic superconductors RBa 2 Cu 3 O 7 in the normal state. The authors' results show that the strength of the phonon modes is reduced when yttrium is partially replaced by gadolinium and europium. Also the critical temperature of these mixed materials is reduced as indicated by the four probe technique

  18. Processing and characterization of ceramic superconductor/polymer composites

    International Nuclear Information System (INIS)

    Kander, R.G.; Namboodri, S.L.

    1993-01-01

    One way to more easily process a brittle high-temperature ceramic superconductor into a useful structure is to combine it with a polymer to form a composite material. Processing of polymer-based composites into complex shapes is well established and relatively easy when compared with traditional ceramic processing unit operations. In addition, incorporating a ceramic superconductor into a polymer matrix can improve mechanical performance as compared with a monolithic ceramic. Finally, because ceramic superconductors are susceptible to attack by moisture, a polymer-based composite structure can also provide protection from deleterious environmental effects. This paper focuses on the processing and subsequent characterization of ceramic superconductor/polymer composites designed primarily for electromagnetic shielding and diamagnetic applications. YBa 2 Cu 3 O 7-x [YBCO] ceramic superconductor is combined with poly(methyl methacrylate) [PMMA] to form novel composite structures. Composite structures have been molded with both a discontinuous superconducting phase (i.e., ceramic particulate reinforced polymers) and with a continuous superconducting phase (i.e., polymer infiltrated porous ceramics). Characterization of these composite structures includes the determination of diamagnetic strength, electromagnetic shielding effectiveness, mechanical performance, and environmental resistance. The goal of this program is to produce a composite structure with increased mechanical integrity and environmental resistance at liquid nitrogen temperatures without compromising the electromagnetic shielding and diamagnetic properties of the superconducting phase. Composites structures of this type are potentially useful in numerous magnetic applications including electromagnetic shielding, magnetic sensors, energy storage, magnetic levitation, and motor windings

  19. Room temperature superconductors

    International Nuclear Information System (INIS)

    Sleight, A.W.

    1995-01-01

    If the Holy Grail of room temperature superconductivity could be achieved, the impact on could be enormous. However, a useful room temperature superconductor for most applications must possess a T c somewhat above room temperature and must be capable of sustaining superconductivity in the presence of magnetic fields while carrying a significant current load. The authors will return to the subject of just what characteristics one might seek for a compound to be a room temperature superconductor. 30 refs., 3 figs., 1 tab

  20. Electronic structure of the Y Ba2 Cu3 O7-x high temperature superconductor ceramic

    International Nuclear Information System (INIS)

    Lima, G.A.R.

    1990-01-01

    We investigate the electronic structure of superconductor Y Ba 2 Cu 3 O 7-x through a molecular cluster approach. The calculations are performed self consistently through a semi empirical L.C.A.O. technique, where different charge states are considered. The correlation effects are taken into account by configuration interaction procedure (INDO/CI). The results for the larger cluster yield a density of states showing a strong p-d covalency resulting in a width of around 8,0 eV for the valence band. The optical excitations is analyzed in detail and compared with the experimental data. (author)

  1. High temperature superconductor accelerator magnets

    NARCIS (Netherlands)

    van Nugteren, J.

    2016-01-01

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding 20T. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and

  2. Integration of semiconductor and ceramic superconductor devices for microwave applications

    NARCIS (Netherlands)

    Klopman, B.B.G.; Klopman, B.B.G.; Wijers, H.W.; Gao, J.; Gao, J.; Gerritsma, G.J.; Rogalla, Horst

    1991-01-01

    Due to the very-low-loss properties of ceramic superconductors, high-performance microwave resonators and filters can be realized. The fact that these devices may be operated at liquid nitrogen temperature facilitates integration with semiconductor devices. Examples are bandpass amplifiers,

  3. Preparation of high temperature superconductor ceramics using cuban reactives. Optimization of the synthesis method

    International Nuclear Information System (INIS)

    Leyva Fabelo, A.; Cruz, C.; Aragon, B.; Suarez, J.C.; Mora, M.

    1991-01-01

    Results of the crystallographic characterization of a group of Cuban Products, which are evaluated to be employed in HTSC fabrication are presented in this paper. The first results on the synthesis of HTSC (RBa 2 Cu 3 0 7δ , R= Y, La, Nd) using Cuban reactives, are presented. The so called 'solid state reaction method of synthesis' was optimized, obtaining a critical temperature of more than 93 k

  4. Studies of high temperature superconductors

    International Nuclear Information System (INIS)

    Narlikar, A.

    1989-01-01

    The high temperature superconductors (HTSCs) discovered are from the family of ceramic oxides. Their large scale utilization in electrical utilities and in microelectronic devices are the frontal challenges which can perhaps be effectively met only through consolidated efforts and expertise of a multidisciplinary nature. During the last two years the growth of the new field has occurred on an international scale and perhaps has been more rapid than in most other fields. There has been an extraordinary rush of data and results which are continually being published as short texts dispersed in many excellent journals, some of which were started to ensure rapid publication exclusively in this field. As a result, the literature on HTSCs has indeed become so massive and so diffuse that it is becoming increasingly difficult to keep abreast with the important and reliable facets of this fast-growing field. This provided the motivation to evolve a process whereby both professional investigators and students can have ready access to up-to- date in-depth accounts of major technical advances happening in this field. The present series Studies of High Temperature Superconductors has been launched to, at least in part, fulfill this need

  5. High Temperature Superconductor Resonator Detectors

    Data.gov (United States)

    National Aeronautics and Space Administration — High Temperature Superconductor (HTS) infrared detectors were studied for years but never matured sufficiently for infusion into instruments. Several recent...

  6. High temperature superconductors

    CERN Document Server

    Paranthaman, Parans

    2010-01-01

    This essential reference provides the most comprehensive presentation of the state of the art in the field of high temperature superconductors. This growing field of research and applications is currently being supported by numerous governmental and industrial initiatives in the United States, Asia and Europe to overcome grid energy distribution issues. The technology is particularly intended for densely populated areas. It is now being commercialized for power-delivery devices, such as power transmission lines and cables, motors and generators. Applications in electric utilities include current limiters, long transmission lines and energy-storage devices that will help industries avoid dips in electric power.

  7. High Temperature Superconductor Machine Prototype

    DEFF Research Database (Denmark)

    Mijatovic, Nenad; Jensen, Bogi Bech; Træholt, Chresten

    2011-01-01

    A versatile testing platform for a High Temperature Superconductor (HTS) machine has been constructed. The stationary HTS field winding can carry up to 10 coils and it is operated at a temperature of 77K. The rotating armature is at room temperature. Test results and performance for the HTS field...

  8. High temperature superconductor current leads

    International Nuclear Information System (INIS)

    Zeimetz, B.; Liu, H.K.; Dou, S.X.

    1996-01-01

    Full text: The use of superconductors in high electrical current applications (magnets, transformers, generators etc.) usually requires cooling with liquid Helium, which is very expensive. The superconductor itself produces no heat, and the design of Helium dewars is very advanced. Therefore most of the heat loss, i.e. Helium consumption, comes from the current lead which connects the superconductor with its power source at room temperature. The current lead usually consists of a pair of thick copper wires. The discovery of the High Temperature Superconductors makes it possible to replace a part of the copper with superconducting material. This drastically reduces the heat losses because a) the superconductor generates no resistive heat and b) it is a very poor thermal conductor compared with the copper. In this work silver-sheathed superconducting tapes are used as current lead components. The work comprises both the production of the tapes and the overall design of the leads, in order to a) maximize the current capacity ('critical current') of the superconductor, b) minimize the thermal conductivity of the silver clad, and c) optimize the cooling conditions

  9. Integration of semiconductor and ceramic superconductor devices for microwave applications

    International Nuclear Information System (INIS)

    Klopman, B.B.G.; Weijers, H.W.; Gao, J.; Gerritsma, G.J.; Rogalla, H.

    1991-01-01

    Due to the very low-loss properties of ceramic superconductors high-performance microwave resonators and filters can be realized. The fact that these devices may be operated at liquid nitrogen temperature, facilitates the integration with semiconductor devices. Examples are bandpass amplifiers, microwave-operated SQUIDs combined with GaAs preamplifiers, detectors, and MOSFET low-frequency amplifiers. This paper discusses the design of such circuits on a single one inch alumina substrate using surface mount techniques. Furthermore data on circuits that have been realized in our laboratory will be presented

  10. Impact of radiation exposure on mechanical and superconducting properties of Bi-2212 superconductor ceramics

    International Nuclear Information System (INIS)

    Azlan Abdul Rahman; Nasri Abdul Hamid; Abdul Aziz Mohamed; Mohd Shahrul Nizam Abdullah; Samsul Isman; Hidayah Zainal

    2013-01-01

    Full-text: For practical applications of high-temperature superconductor ceramics, the compounds must be able to sustain extreme mechanical stress and external magnetic field. Bi-2212 superconductor is one of the existing superconductors that are commonly used in various applications. Improvement in the microstructure enhanced the connectivity of the adjacent grains within the superconducting grains, and as such improved the mechanical strength of the ceramics. The ability of the superconductor ceramics to sustain superconducting properties in external magnetic field is also required. The compounds must be able to maintain high transport critical current density (Jc) in magnetic field. Another potential application of superconductors is at the nuclear facilities. Thus, study on the impact of radiation exposure on the mechanical and superconducting properties is very important to gauge the viability of superconductor ceramics in such environment. In this study, the mechanical and superconducting properties between exposure and non-irradiated samples are compared. Characterization will be done by the temperature dependence on electrical resistance measurements, X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and measurements of transport critical current (Jc) dependence on temperature in magnetic field. (author)

  11. Filters for mobile radio from high Tc ceramic superconductors

    International Nuclear Information System (INIS)

    Peterson, G.E.; Wong, E.; Alford, N.McN.

    1990-01-01

    Mobile radio frequencies lie between 30 MHz and 1,000 MHz. This frequency range is ideal for ceramic high T c superconductors. We have designed Chebyshev, Butterworth and interdigital filters that can employ high T c superconductors in the form of rods, tubes and helices. In general, the performance of these filters at milliwatt power levels is excellent. We will describe fabrication of the superconductors and filter design

  12. Superconductivity and ceramic superconductors II; Proceedings of the Symposium, Orlando, FL, Nov. 12-15, 1990. Ceramic transactions. Vol. 18

    International Nuclear Information System (INIS)

    Nair, K.M.; Balachandran, U.; Chiang, Y.-M.; Bhalla, A.S.

    1991-01-01

    The present symposium on superconductivity and ceramic superconductors discusses fundamentals and general principles, powder processing and properties, fabrication and properties, and device reliability and applications. Attention is given to phase formation in the Tl-Ca-Ba-Cu-O system, comparative defect studies in La2CuO4 and La2NiO4, solid solution and defect behavior in high Tc oxides, oxygen ion transport and disorder in cuprates, and Sr-free Bi-Ln-Ca-Cu-O superconductors. Topics addressed include the preparation of superconductor Y-Ba-Cu-O powder by single-step calcining in air, low-temperature synthesis of YBa2Cu3O(7-x), synthesis of high-phase purity ceramic oxide superconductors by the xerogel method, and the preparation and characterization of the BYa2Cu4O8 superconductor. Also discussed are optical studies of humidity-based corrosion effects on thin film and bulk ceramic YBa2Cu3O(7-delta), thermomechanical processing of YBa2Cu3O(x)/Ag sheathed wires, and the expansion of high-Tc superconducting ceramics

  13. Electrochemical investigations of high-Tc superconductors - low-temperature electrochemistry

    International Nuclear Information System (INIS)

    Lorenz, W.J.

    1992-01-01

    This research report presents a summary of results obtained by electrochemical investigations of high-Tc superconductors at room temperature and below the critical temperature (Tc). The studies were to reveal the behaviour of the ceramic superconducting materials at the interface between superconductor and ionic conductor. (MM) With 4 tabs., 8 figs [de

  14. High-temperature materials and structural ceramics

    International Nuclear Information System (INIS)

    1990-01-01

    This report gives a survey of research work in the area of high-temperature materials and structural ceramics of the KFA (Juelich Nuclear Research Center). The following topics are treated: (1) For energy facilities: ODS materials for gas turbine blades and heat exchangers; assessment of the remaining life of main steam pipes, material characterization and material stress limits for First-Wall components; metallic and graphitic materials for high-temperature reactors. (2) For process engineering plants: composites for reformer tubes and cracking tubes; ceramic/ceramic joints and metal/ceramic and metal/metal joints; Composites and alloys for rolling bearing and sliding systems up to application temperatures of 1000deg C; high-temperature corrosion of metal and ceramic material; porous ceramic high-temperature filters and moulding coat-mix techniques; electrically conducting ceramic material (superconductors, fuel cells, solid electrolytes); high-temperature light sources (high-temperature chemistry); oil vapor engines with caramic components; ODS materials for components in diesel engines and vehicle gas turbines. (MM) [de

  15. NSSEFF Designing New Higher Temperature Superconductors

    Science.gov (United States)

    2017-04-13

    AFRL-AFOSR-VA-TR-2017-0083 NSSEFF - DESIGINING NEW HIGHER TEMPERATURE SUPERCONDUCTORS Meigan Aronson THE RESEARCH FOUNDATION OF STATE UNIVERSITY OF...2015 4. TITLE AND SUBTITLE NSSEFF - DESIGINING NEW HIGHER TEMPERATURE SUPERCONDUCTORS 5a.  CONTRACT NUMBER 5b.  GRANT NUMBER FA9550-10-1-0191 5c...materials, identifying the most promising candidates. 15. SUBJECT TERMS TEMPERATURE, SUPERCONDUCTOR 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF

  16. Fabrication of high temperature superconductors

    Science.gov (United States)

    Balachandran, Uthamalingam; Dorris, Stephen E.; Ma, Beihai; Li, Meiya

    2003-06-17

    A method of forming a biaxially aligned superconductor on a non-biaxially aligned substrate substantially chemically inert to the biaxially aligned superconductor comprising is disclosed. A non-biaxially aligned substrate chemically inert to the superconductor is provided and a biaxially aligned superconductor material is deposited directly on the non-biaxially aligned substrate. A method forming a plume of superconductor material and contacting the plume and the non-biaxially aligned substrate at an angle greater than 0.degree. and less than 90.degree. to deposit a biaxially aligned superconductor on the non-biaxially aligned substrate is also disclosed. Various superconductors and substrates are illustrated.

  17. Passivation of high temperature superconductors

    Science.gov (United States)

    Vasquez, Richard P. (Inventor)

    1991-01-01

    The surface of high temperature superconductors such as YBa2Cu3O(7-x) are passivated by reacting the native Y, Ba and Cu metal ions with an anion such as sulfate or oxalate to form a surface film that is impervious to water and has a solubility in water of no more than 10(exp -3) M. The passivating treatment is preferably conducted by immersing the surface in dilute aqueous acid solution since more soluble species dissolve into the solution. The treatment does not degrade the superconducting properties of the bulk material.

  18. High Temperature Superconductor Accelerator Magnets

    CERN Document Server

    AUTHOR|(CDS)2079328; de Rijk, Gijs; Dhalle, Marc

    2016-11-10

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding $20T$. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and development before they can be applied in a practical accelerator magnet. In order to study HTS in detail, a five tesla demonstrator magnet named Feather-M2 is designed and constructed. The magnet is based on ReBCO coated conductor, which is assembled into a $10kA$ class Roebel cable. A new and optimized Aligned Block layout is used, which takes advantage of the anisotropy of the conductor. This is achieved by providing local alignment of the Roebel cable in the coil windings with the magnetic field lines. A new Network Model capable of analyzing transient electro-magnetic and thermal phenomena in coated conductor cables and coils is developed. This model is necessary to solve critical issues in coated conductor ac...

  19. Melt processed high-temperature superconductors

    CERN Document Server

    1993-01-01

    The achievement of large critical currents is critical to the applications of high-temperature superconductors. Recent developments have shown that melt processing is suitable for producing high J c oxide superconductors. Using magnetic forces between such high J c oxide superconductors and magnets, a person could be levitated.This book has grown largely out of research works on melt processing of high-temperature superconductors conducted at ISTEC Superconductivity Research Laboratory. The chapters build on melt processing, microstructural characterization, fundamentals of flux pinning, criti

  20. Passivation Of High-Temperature Superconductors

    Science.gov (United States)

    Vasquez, Richard P.

    1991-01-01

    Surfaces of high-temperature superconductors passivated with native iodides, sulfides, or sulfates formed by chemical treatments after superconductors grown. Passivating compounds nearly insoluble in and unreactive with water and protect underlying superconductors from effects of moisture. Layers of cuprous iodide and of barium sulfate grown. Other candidate passivating surface films: iodides and sulfides of bismuth, strontium, and thallium. Other proposed techniques for formation of passivating layers include deposition and gas-phase reaction.

  1. Oxide superconductors

    International Nuclear Information System (INIS)

    Cava, R.J.

    2000-01-01

    This article briefly reviews ceramic superconductors from historical and materials perspectives. It describes the factors that distinguish high-temperature cuprate superconductors from most electronic ceramics and places them in the context of other families of superconducting materials. Finally, it describes some of the scientific issues presently being actively pursued in the search for the mechanism for high-temperature superconductivity and the directions of research into new superconducting ceramics in recent years

  2. Investigation on the bisoliton mechanism of high-temperature superconductors

    International Nuclear Information System (INIS)

    Zhang Lingyun; Li Bozang; Pu Fucho; Lin Jiatih

    1996-01-01

    Microscopic parameters in the Davydov model are calculated on the basis of the bisoliton idea. The energy gap is obtained from combining the condition for the solution of Davydov's equation with the condensation energy of the superconductive state in zero field, and some characteristic parameters of high-temperature superconductors such as coherence length, penetration depth, and density of critical current for a thin film in weak magnetic field are given. It is also proved that lattice displacement in Davydov's equation satisfies the φ 4 field form. The critical temperature and the coefficient of linear specific heat of high-temperature superconductors are studied from the statistics of lattice kinks. The agreement between theoretical and experimental values for YBaCuO oxide ceramics suggests that the bisoliton model gives a reasonable explanation of high-temperature superconductivity. (orig.)

  3. The defect structure of ceramic high Tc superconductors

    International Nuclear Information System (INIS)

    Van Tendeloo, G.; Amelinckx, S.; Zandbergen, H.W.; Verwerft, M.

    1989-01-01

    In this paper an overview is given of electron microscopy studies on the different ceramic superconductors: YBa 2 Cu 3 O 7 , Bi(Tl)-Sr(Ba)- Ca-Cu-O and Pb 2 Sr 2 Y 0.5 Ca 0.5 Cu 3 O x . Planar defects in these materials play an important role in the superconducting properties. Their structural characteristics are discussed

  4. High Temperature Superconductor Bolometers for Planetary Science

    Data.gov (United States)

    National Aeronautics and Space Administration — This work is a design study of an instrument optimized for JPL's novel high temperature superconductor bolometers. The work involves designing an imaging...

  5. The development of research on high temperature superconductors in Malaysia

    International Nuclear Information System (INIS)

    Shaari, A.H.; Hashim, M.; Dalimin, M.N.

    1989-01-01

    The background of the recent discovery of high-temperature oxide superconductor is given. This new discovery has driven scientists of different disciplines from many parts of the world into the race. Even those researchers from the developing countries are able to join the band wagon of the frontier research due to the convenience of working at temperatures well above that of liquid nitrogen. In Malaysia, some aspects of preparations and characterization of Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O ceramics are studied. The 90 K transition temperature is observed in Y-Ba-Cu-O. (Auth.). 10 figs.; 5 refs

  6. High temperature superconductors and other superfluids

    CERN Document Server

    Alexandrov, A S

    2017-01-01

    Written by eminent researchers in the field, this text describes the theory of superconductivity and superfluidity starting from liquid helium and a charged Bose-gas. It also discusses the modern bipolaron theory of strongly coupled superconductors, which explains the basic physical properties of high-temperature superconductors. This book will be of interest to fourth year graduate and postgraduate students, specialist libraries, information centres and chemists working in high-temperature superconductivity.

  7. Searching for superconductors with high critical temperature

    Energy Technology Data Exchange (ETDEWEB)

    Chao, C

    1977-08-18

    Critical temperature of superconductors can be and must be raised so that their range of application can be broadened. It was estimated that, in 3 to 5 years, superconductor electric generators might be used in nuclear submarines and/or other applications where the requirements of small volume and light weight are critical. The BCS theory was recapitulated. Possible methods of achieving higher critical temperature were proposed and discussed.

  8. Processing of high-temperature superconductors at high strain rates

    International Nuclear Information System (INIS)

    Mamalis, A.G.; Pantazsopoulos, G.; Manolakos, D.E.; Szalay, A.

    2000-01-01

    This new book provides, for the first time, a systematic, unified presentation of all steps in the processing of high-temperature superconductor materials, ranging from synthesis of various systems to fabrication and industrial applications. Also covered are characterization techniques and current directions in research and development. The authors are leading specialists who bring to this new book their many years of experience in research, education and industrial engineering work in superconductor materials. This book is primarily focused on the bulk-fabrication techniques of high-temperature ceramic superconducting components, especially on the combination of dynamic powder-consolidation and subsequent deformation processing. The properties of these ceramics, which are difficult-to-form materials by applying conventional techniques, are combined for the net-shape manufacturing of such components for the construction of HTS deviceshor e llipsis. However, very important topics such as superconducting structures, chemical synthesis, film fabrication and characterization techniques are also reviewedhor e llipsis to provide a complete, comprehensive view of superconductors engineering

  9. Ceramic superconductor/metal composite materials employing the superconducting proximity effect

    Science.gov (United States)

    Holcomb, Matthew J.

    2002-01-01

    Superconducting composite materials having particles of superconducting material disposed in a metal matrix material with a high electron-boson coupling coefficient (.lambda.). The superconducting particles can comprise any type of superconductor including Laves phase materials, Chevrel phase materials, A15 compounds, and perovskite cuprate ceramics. The particles preferably have dimensions of about 10-500 nanometers. The particles preferably have dimensions larger than the superconducting coherence length of the superconducting material. The metal matrix material has a .lambda. greater than 0.2, preferably the .lambda. is much higher than 0.2. The metal matrix material is a good proximity superconductor due to its high .lambda.. When cooled, the superconductor particles cause the metal matrix material to become superconducting due to the proximity effect. In cases where the particles and the metal matrix material are chemically incompatible (i.e., reactive in a way that destroys superconductivity), the particles are provided with a thin protective metal coating. The coating is chemically compatible with the particles and metal matrix material. High Temperature Superconducting (HTS) cuprate ceramic particles are reactive and therefore require a coating of a noble metal resistant to oxidation (e.g., silver, gold). The proximity effect extends through the metal coating. With certain superconductors, non-noble metals can be used for the coating.

  10. Nonmonotonic critical temperature in superconductor ferromagnet bilayers

    NARCIS (Netherlands)

    Fominov, Ya. V.; Fominov, I.V.; Chtchelkatchev, N.M.; Golubov, Alexandre Avraamovitch

    2002-01-01

    The critical temperature Tc of a superconductor/ferromagnet (SF) bilayer can exhibit nonmonotonic dependence on the thickness df of the F layer. SF systems have been studied for a long time; according to the experimental situation, a ¿dirty¿ limit is often considered which implies that the mean free

  11. Application of High Temperature Superconductors to Accelerators

    CERN Document Server

    Ballarino, A

    2000-01-01

    Since the discovery of high temperature superconductivity, a large effort has been made by the scientific community to investigate this field towards a possible application of the new oxide superconductors to different devices like SMES, magnetic bearings, flywheels energy storage, magnetic shielding, transmission cables, fault current limiters, etc. However, all present day large scale applications using superconductivity in accelerator technology are based on conventional materials operating at liquid helium temperatures. Poor mechanical properties, low critical current density and sensitivity to the magnetic field at high temperature are the key parameters whose improvement is essential for a large scale application of high temperature superconductors to such devices. Current leads, used for transferring currents from the power converters, working at room temperature, into the liquid helium environment, where the magnets are operating, represent an immediate application of the emerging technology of high t...

  12. Deformation of high-temperature superconductors

    International Nuclear Information System (INIS)

    Goretta, K.C.; Routbort, J.L.; Miller, D.J.; Chen, N.; Dominguez-Rodriguez, A.; Jimenez-Melendo, M.; De Arellano-Lopez, A.R.

    1994-08-01

    Of the many families of high-temperature superconductors, only the properties of those discovered prior to 1989 - Y-Ba-Cu-O, Tl-Ba(Sr)-Ca-Cu-O, and Bi(Pb)-Sr-Ca-Cu-O - have been studied extensively. Deformation tests have been performed on YBa 2 Cu 3 O x (Y-123), YBa 2 Cu 4 O x (Y-124), TlBa 2 Ca 2 Cu 3 O x (Bi-2223). The tests have revealed that plasticity is generally limited in these compounds and that the rate-controlling diffusional kinetics for creep are very slow. Nevertheless, hot forming has proved to be quite successful for fabrication of bulk high-temperature superconductors, so long as deformation rates are low or large hydrostatic stresses are applied. Steady-state creep data have proved to be useful in designing optimal heat treatments for superconductors and in support of more-fundamental diffusion experiments. The high-temperature superconductors are highly complex oxides, and it is a challenge to understand their deformation responses. In this paper, results of interest and operant creep mechanisms will be reviewed

  13. Published assessments bearing on the future use of ceramic superconductors by the electric power sector

    International Nuclear Information System (INIS)

    Giese, R.F.; Wolsky, A.M.

    1992-01-01

    Much has been written about ceramic superconductors since their discovery in 1986. Most of this writing reports and describes scientific research. However, some authors have sought to put this research in context: to assess where the field stands, what might be technically feasible, what might be economically feasible, and what potential impacts ceramic superconductors will bring to the electric power sector. This report's purpose is to make the results of already published assessments readily available. To that end, this report lists and provides abstracts for various technical and economic assessments related to applications of High-Temperature Superconductors (HTS) to the electric power sector. Those studies deemed most important are identified and summarized. These assessments were identified by two means. First, members of the Executive Committee identified some reports as worthy of consideration and forwarded them to Argonne National Laboratory. Twelve assessments were selected. Each of these is listed and summarized in the following section. Second, a bibliographic search was performed on five databases: INSPEC, NTIS, COMPENDEX, Energy Science ampersand Technology, and Electric Power Database. The search consisted of first selecting all papers related to High Temperature Superconductors. Then papers related to SMES, cables, generators, motors, fault current limiters, or electric utilities were selected. When suitable variants of the above terms were included, this resulted in a selection of 493 citations. These citations were subjected to review by the authors. A number of citations were determined to be inappropriate (e.g. a number referred to digital transmission lines for electronics and communications applications). The reduced list consisted of 200 entries. Each of these citations, with an abstract, is presented in the following sections

  14. Published assessments bearing on the future use of ceramic superconductors by the electric power sector

    Energy Technology Data Exchange (ETDEWEB)

    Giese, R.F.; Wolsky, A.M.

    1992-08-25

    Much has been written about ceramic superconductors since their discovery in 1986. Most of this writing reports and describes scientific research. However, some authors have sought to put this research in context: to assess where the field stands, what might be technically feasible, what might be economically feasible, and what potential impacts ceramic superconductors will bring to the electric power sector. This report's purpose is to make the results of already published assessments readily available. To that end, this report lists and provides abstracts for various technical and economic assessments related to applications of High-Temperature Superconductors (HTS) to the electric power sector. Those studies deemed most important are identified and summarized. These assessments were identified by two means. First, members of the Executive Committee identified some reports as worthy of consideration and forwarded them to Argonne National Laboratory. Twelve assessments were selected. Each of these is listed and summarized in the following section. Second, a bibliographic search was performed on five databases: INSPEC, NTIS, COMPENDEX, Energy Science Technology, and Electric Power Database. The search consisted of first selecting all papers related to High Temperature Superconductors. Then papers related to SMES, cables, generators, motors, fault current limiters, or electric utilities were selected. When suitable variants of the above terms were included, this resulted in a selection of 493 citations. These citations were subjected to review by the authors. A number of citations were determined to be inappropriate (e.g. a number referred to digital transmission lines for electronics and communications applications). The reduced list consisted of 200 entries. Each of these citations, with an abstract, is presented in the following sections.

  15. Published assessments bearing on the future use of ceramic superconductors by the electric power sector

    Energy Technology Data Exchange (ETDEWEB)

    Giese, R.F.; Wolsky, A.M.

    1992-08-25

    Much has been written about ceramic superconductors since their discovery in 1986. Most of this writing reports and describes scientific research. However, some authors have sought to put this research in context: to assess where the field stands, what might be technically feasible, what might be economically feasible, and what potential impacts ceramic superconductors will bring to the electric power sector. This report`s purpose is to make the results of already published assessments readily available. To that end, this report lists and provides abstracts for various technical and economic assessments related to applications of High-Temperature Superconductors (HTS) to the electric power sector. Those studies deemed most important are identified and summarized. These assessments were identified by two means. First, members of the Executive Committee identified some reports as worthy of consideration and forwarded them to Argonne National Laboratory. Twelve assessments were selected. Each of these is listed and summarized in the following section. Second, a bibliographic search was performed on five databases: INSPEC, NTIS, COMPENDEX, Energy Science & Technology, and Electric Power Database. The search consisted of first selecting all papers related to High Temperature Superconductors. Then papers related to SMES, cables, generators, motors, fault current limiters, or electric utilities were selected. When suitable variants of the above terms were included, this resulted in a selection of 493 citations. These citations were subjected to review by the authors. A number of citations were determined to be inappropriate (e.g. a number referred to digital transmission lines for electronics and communications applications). The reduced list consisted of 200 entries. Each of these citations, with an abstract, is presented in the following sections.

  16. Superconductors

    International Nuclear Information System (INIS)

    1988-01-01

    The chapter 6.3 p. 143 to 153 of this book deals with superconductors 19 items are briefly presented with address of manufacturer or laboratory to contact, mainly in the USA or Japan. In particular magnets, films, high temperature superconductors and various applications are presented [fr

  17. Weak links in high critical temperature superconductors

    Science.gov (United States)

    Tafuri, Francesco; Kirtley, John R.

    2005-11-01

    The traditional distinction between tunnel and highly transmissive barriers does not currently hold for high critical temperature superconducting Josephson junctions, both because of complicated materials issues and the intrinsic properties of high temperature superconductors (HTS). An intermediate regime, typical of both artificial superconductor-barrier-superconductor structures and of grain boundaries, spans several orders of magnitude in the critical current density and specific resistivity. The physics taking place at HTS surfaces and interfaces is rich, primarily because of phenomena associated with d-wave order parameter (OP) symmetry. These phenomena include Andreev bound states, the presence of the second harmonic in the critical current versus phase relation, a doubly degenerate state, time reversal symmetry breaking and the possible presence of an imaginary component of the OP. All these effects are regulated by a series of transport mechanisms, whose rules of interplay and relative activation are unknown. Some transport mechanisms probably have common roots, which are not completely clear and possibly related to the intrinsic nature of high-TC superconductivity. The d-wave OP symmetry gives unique properties to HTS weak links, which do not have any analogy with systems based on other superconductors. Even if the HTS structures are not optimal, compared with low critical temperature superconductor Josephson junctions, the state of the art allows the realization of weak links with unexpectedly high quality quantum properties, which open interesting perspectives for the future. The observation of macroscopic quantum tunnelling and the qubit proposals represent significant achievements in this direction. In this review we attempt to encompass all the above aspects, attached to a solid experimental basis of junction concepts and basic properties, along with a flexible phenomenological background, which collects ideas on the Josephson effect in the presence

  18. Weak links in high critical temperature superconductors

    International Nuclear Information System (INIS)

    Tafuri, Francesco; Kirtley, John R

    2005-01-01

    The traditional distinction between tunnel and highly transmissive barriers does not currently hold for high critical temperature superconducting Josephson junctions, both because of complicated materials issues and the intrinsic properties of high temperature superconductors (HTS). An intermediate regime, typical of both artificial superconductor-barrier-superconductor structures and of grain boundaries, spans several orders of magnitude in the critical current density and specific resistivity. The physics taking place at HTS surfaces and interfaces is rich, primarily because of phenomena associated with d-wave order parameter (OP) symmetry. These phenomena include Andreev bound states, the presence of the second harmonic in the critical current versus phase relation, a doubly degenerate state, time reversal symmetry breaking and the possible presence of an imaginary component of the OP. All these effects are regulated by a series of transport mechanisms, whose rules of interplay and relative activation are unknown. Some transport mechanisms probably have common roots, which are not completely clear and possibly related to the intrinsic nature of high-T C superconductivity. The d-wave OP symmetry gives unique properties to HTS weak links, which do not have any analogy with systems based on other superconductors. Even if the HTS structures are not optimal, compared with low critical temperature superconductor Josephson junctions, the state of the art allows the realization of weak links with unexpectedly high quality quantum properties, which open interesting perspectives for the future. The observation of macroscopic quantum tunnelling and the qubit proposals represent significant achievements in this direction. In this review we attempt to encompass all the above aspects, attached to a solid experimental basis of junction concepts and basic properties, along with a flexible phenomenological background, which collects ideas on the Josephson effect in the presence

  19. Positron annihilation studies on high temperature superconductors

    International Nuclear Information System (INIS)

    Sundar, C.S.; Bharathi, A.

    1996-01-01

    A survey of the positron annihilation studies on high temperature superconductors (HTSC), with results drawn mainly from our work, is presented. These include results of the studies on the temperature dependence of positron lifetime across T c , which have been carried out in the whole gamut of oxide superconductors. These experimental results are discussed in conjunction with the results of theoretically calculated positron density distribution, and it is shown that the observed temperature dependence of lifetime is intimately linked to the probing of the Cu-O network by the positrons. Results on the investigation of oxygen defects, which play a crucial role in HTSC, are presented. The most significant contribution of positrons to HTSC relates to the investigation of Fermi surface and the results of these studies, drawn from literature, are indicated. Some of our recent results in other novel superconducting materials, viz., the fullerenes and borocarbides are also presented. (author). 69 refs., 15 figs

  20. Electron microscopic observation at low temperature on superconductors

    International Nuclear Information System (INIS)

    Yokota, Yasuhiro; Hashimoto, Hatsujiro; Yoshida, Hiroyuki.

    1991-01-01

    The authors have observed superconducting materials with a high resolution electron microscope at liquid helium temperature. First, observation was carried out on Nb system intermetallic compounds such as Nb 3 Al and Nb 3 Sn of Al 5 type and Nb 3 Ge of 11 type at extremely low temperature. Next, the observation of high temperature superconductive ceramics in the state of superconductivity was attempted. In this paper, first the development of the liquid helium sample holder for a 400 kV electron microscope to realize the observation is reported. Besides, the sample holder of Gatan Co. and an extremely low temperature, high resolution electron microscope with a superconducting lens are described. The purpose of carrying out the electron microscope observation of superconductors at low temperature is the direct observation of the crystalline lattice image in the state of superconductivity. Also the structural transformation from tetragonal crystals to rhombic crystals in Al 5 type superconductors can be observed. The results of observation are reported. (K.I.)

  1. Shape-forming and densification of ceramic superconductors

    International Nuclear Information System (INIS)

    Prakash, Om; Thomas, C.A.; Magadum, A.P.; Anklekar, R.M.; Khosla, N.K.; Kumar, Sunil; Chaudhuri, B.; Ramesh, M.; Rao, B.T.; Rama Mohan, T.R.

    1991-01-01

    Processing studies on varied shape-forming and densification of bulk ceramic superconductor, YBa 2 Cu 3 Osub(7-δ), are reported in this paper. Polyvinyl butyral-polyethylene glycol-trichloroethylene has been found to be the best binder-plasticizer-solvent system in plastic shape-forming. The effect of initial particle morphology on final densification has been the most sensitive single parameter as compared to compaction pressure and final sintering durations at ∼930degC. 1-2-3 powders of mean particle size ∼1.94μm have yielded sintered densities ∼92%T.D. albeit with lower oxygen intake Osub(6.7). (author). 8 refs., 8 figs

  2. High temperature superconductors applications in telecommunications

    International Nuclear Information System (INIS)

    Kumar, A.A.; Li, J.; Zhang, M.F.

    1994-01-01

    The purpose of this paper is twofold: to discuss high temperature superconductors with specific reference to their employment in telecommunications applications; and to discuss a few of the limitations of the normally employed two-fluid model. While the debate on the actual usage of high temperature superconductors in the design of electronic and telecommunications devices-obvious advantages versus practical difficulties-needs to be settled in the near future, it is of great interest to investigate the parameters and the assumptions that will be employed in such designs. This paper deals with the issue of providing the microwave design engineer with performance data for such superconducting waveguides. The values of conductivity and surface resistance, which are the primary determining factors of a waveguide performance, are computed based on the two-fluid model. A comparison between two models-a theoretical one in terms of microscopic parameters (termed Model A) and an experimental fit in terms of macroscopic parameters (termed Model B)-shows the limitations and the resulting ambiguities of the two-fluid model at high frequencies and at temperatures close to the transition temperature. The validity of the two-fluid model is then discussed. Our preliminary results show that the electrical transport description in the normal and superconducting phases as they are formulated in the two-fluid model needs to be modified to incorporate the new and special features of high temperature superconductors. Parameters describing the waveguide performance-conductivity, surface resistance and attenuation constant-will be computed. Potential applications in communications networks and large scale integrated circuits will be discussed. Some of the ongoing work will be reported. In particular, a brief proposal is made to investigate of the effects of electromagnetic interference and the concomitant notion of electromagnetic compatibility (EMI/EMC) of high T c superconductors

  3. High temperature superconductors applications in telecommunications

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, A.A.; Li, J.; Zhang, M.F. [Prairie View A& M Univ., Texas (United States)

    1994-12-31

    The purpose of this paper is twofold: to discuss high temperature superconductors with specific reference to their employment in telecommunications applications; and to discuss a few of the limitations of the normally employed two-fluid model. While the debate on the actual usage of high temperature superconductors in the design of electronic and telecommunications devices-obvious advantages versus practical difficulties-needs to be settled in the near future, it is of great interest to investigate the parameters and the assumptions that will be employed in such designs. This paper deals with the issue of providing the microwave design engineer with performance data for such superconducting waveguides. The values of conductivity and surface resistance, which are the primary determining factors of a waveguide performance, are computed based on the two-fluid model. A comparison between two models-a theoretical one in terms of microscopic parameters (termed Model A) and an experimental fit in terms of macroscopic parameters (termed Model B)-shows the limitations and the resulting ambiguities of the two-fluid model at high frequencies and at temperatures close to the transition temperature. The validity of the two-fluid model is then discussed. Our preliminary results show that the electrical transport description in the normal and superconducting phases as they are formulated in the two-fluid model needs to be modified to incorporate the new and special features of high temperature superconductors. Parameters describing the waveguide performance-conductivity, surface resistance and attenuation constant-will be computed. Potential applications in communications networks and large scale integrated circuits will be discussed. Some of the ongoing work will be reported. In particular, a brief proposal is made to investigate of the effects of electromagnetic interference and the concomitant notion of electromagnetic compatibility (EMI/EMC) of high T{sub c} superconductors.

  4. Preparation of silver doped high temperature superconductors

    International Nuclear Information System (INIS)

    Stavek, Jiri; Zapletal, Vladimir

    1989-01-01

    High temperature superconductors were prepared by the controlled double-jet precipitation to manipulate the chemical composition, composition gradients, average grain size, grain size distribution, and other factors which contribute to the actual properties and performance of HTSC. The cations (Y-Ba-Cu or Bi-Pb-Ca-Sr-Cu) and oxalic anions solutions were simultaneously separately introduced to the crystallizer with a stirred solution of gelatin under conditions where the temperature, excess of oxalic anions in solution, pH, reactant addition rate, and other reaction conditions were tightly controlled to prepare the high sinterability powder. To increase the sinterability of submicron particles of produced precursor, the silver ions were introduced at the end of the controlled double-jet precipitation. This approach improves the electrical and mechanical properties of produced HTSC specimens. The controlled double jet precipitation provides a viable technique for preparation of oxide superconductors and the process is amenable for scaling up

  5. Transport measurements in superconductors: critical current of granular high TC ceramic superconductor samples

    International Nuclear Information System (INIS)

    Passos, W.A.C.

    2016-01-01

    This work presents a method to obtain critical current of granular superconductors. We have carried out transport measurements (ρxT curves and VxI curves) in a YBa_2Cu_3O_7_-_δ sample to determine critical current density of it. Some specimens reveal a 'semiconductor-like' behavior (electrical resistivity decreases with increasing temperatures above critical temperature T_c of material) competing with superconductor behavior. Due to high granular fraction of the sample, these competition is clearly noted in ρxT curves. Measurements carried out from 0 to 8500 Oe of applied field show the same behavior, and the critical current density of the samples is shown. (author)

  6. Recrystallization of high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Kouzoudis, Dimitris [Iowa State Univ., Ames, IA (United States)

    1996-05-09

    Currently one of the most widely used high Tc superconductors is the Bi-based compounds Bi2Sr2CaCu2Oz and Bi2Sr2Ca2Cu3Oz (known as BSCCO 2212 and 2223 compounds) with Tc values of about 85 K and 110 K respectively. Lengths of high performance conductors ranging from 100 to 1000 m long are routinely fabricated and some test magnets have been wound. An additional difficulty here is that although Bi-2212 and Bi-2223 phases exist over a wide range of stoichiometries, neither has been prepared in phase-pure form. So far the most successful method of constructing reliable and robust wires or tapes is the so called powder-in-tube (PIT) technique [1, 2, 3, 4, 5, 6, 7] in which oxide powder of the appropriate stoichiometry and phase content is placed inside a metal tube, deformed into the desired geometry (round wire or flat tape), and annealed to produce the desired superconducting properties. Intermediate anneals are often incorporated between successive deformation steps. Silver is the metal used in this process because it is the most compatible with the reacting phase. In all of the commercial processes for BSCCO, Ag seems to play a special catalytic role promoting the growth of high performance aligned grains that grow in the first few micrometers near the Ag/BSCCO interface. Adjacent to the Ag, the grain alignment is more perfect and the current density is higher than in the center of the tape. It is known that Ag lowers the melting point of several of the phases but the detailed mechanism for growth of these high performance grains is not clearly understood. The purpose of this work is to study the nucleation and growth of the high performance material at this interface.

  7. High temperature superconductor cable concepts for fusion magnets

    CERN Document Server

    AUTHOR|(CDS)2078397

    2013-01-01

    Three concepts of high temperature superconductor cables carrying kA currents (RACC, CORC and TSTC) are investigated, optimized and evaluated in the scope of their applicability as conductor in fusion magnets. The magnetic field and temperature dependence of the cables is measured; the thermal expansion and conductivity of structure, insulation and filling materials are investigated. High temperature superconductor winding packs for fusion magnets are calculated and compared with corresponding low temperature superconductor cases.

  8. Alloy model for high temperature superconductors

    International Nuclear Information System (INIS)

    Weissmann, M.; Saul, A.

    1991-07-01

    An alloy model is proposed for the electronic structure of high temperature superconductors. It is based on the assumption that holes and extra electrons are localized in small copper oxygen clusters, that would be the components of such alloy. This model, when used together with quantum chemical calculations on small clusters, can explain the structure observed in the experimental densities of states of both hole and electron superconductors close to the Fermi energy. The main point is the strong dependence of the energy level distribution and composition on the number of electrons in a cluster. The alloy model also suggests a way to correlate Tc with the number of holes, or extra electrons, and the number of adequate clusters to locate them. (author). 21 refs, 4 figs, 1 tab

  9. Chemical stability of high-temperature superconductors

    Science.gov (United States)

    Bansal, Narottam P.

    1992-01-01

    A review of the available studies on the chemical stability of the high temperature superconductors (HTS) in various environments was made. The La(1.8)Ba(0.2)CuO4 HTS is unstable in the presence of H2O, CO2, and CO. The YBa2Cu3O(7-x) superconductor is highly susceptible to degradation in different environments, especially water. The La(2-x)Ba(x)CuO4 and Bi-Sr-Ca-Cu-O HTS are relatively less reactive than the YBa2Cu3O(7-x). Processing of YBa2Cu3O(7-x) HTS in purified oxygen, rather than in air, using high purity noncarbon containing starting materials is recommended. Exposure of this HTS to the ambient atmosphere should also be avoided at all stages during processing and storage. Devices and components made out of these oxide superconductors would have to be protected with an impermeable coating of a polymer, glass, or metal to avoid deterioration during use.

  10. Positron annihilation studies on high temperature superconductors

    International Nuclear Information System (INIS)

    Sundar, C.S.; Bharathi, A.

    1991-01-01

    The results of positron annihilation measurements as a function of temperature, across Tc, in a variety of high temperature superconductors such as Y-Ba-Cu-O (Y1237), Y-Ba-Cu-O (Y1248), Bi-Sr-Ca-Cu-O, Tl-Ba-Ca-Cu-O, Ba-K-Bi-O and Nd-Ce-Cu-O are presented. It is shown that the variation of annihilation parameters in the superconducting state is correlated with the diposition of the positron density distribution with respect to the superconducting CuO planes. An increase in positron lifetime is observed below Tc when the positrons probe the CuO planes whereas a decrease in lifetime is observed when the positron density overlaps predominantly with the apical oxygen atom. With this correlation, the different temperature variation of annihilation parameters, seen in the various high temperature superconductors, is understood in terms of a local charge transfer from the planar oxygen atom to the apical oxygen atom. The significance of these results in the context of various theoretical models of high temperature superconductivity is discussed. In addition, the application of positron annihilation spectroscopy to the study of oxygen defects in the Y-Ba-Cu-O, Bi-Sr-Ca-Cu-O and Nd-Ce-Cu-O is presented. (author). 53 refs., 17 figs., 2 tabs

  11. AC susceptibility response of bulk YBCO superconductors in the presence of a temperature gradient

    International Nuclear Information System (INIS)

    Bodi, A.C.; Kirschner, I.

    1997-01-01

    Low-frequency AC susceptibility measurements on ceramic YBCO superconductors carried out at the presence of a quasi-one-dimensional temperature gradient are compared with those made without the temperature gradient. The values of the different characteristic temperatures measured on samples without and with a temperature gradient are identical but in the second case its characteristic temperature is a medium value. When the temperature gradient is constant on the sample the arithmetic medium value of the local temperatures is the effective characteristic temperature different phenomena. (orig.)

  12. High temperature superconductors and method

    International Nuclear Information System (INIS)

    Ruvalds, J.J.

    1977-01-01

    This invention comprises a superconductive compound having the formula: Ni/sub 1-x/M/sub x/Z/sub y/ wherein M is a metal which will destroy the magnetic character of nickel (preferably copper, silver or gold); Z is hydrogen or deuterium; x is 0.1 to 0.9; and y, correspondingly, 0.9 to 0.1, and method of conducting electric current with no resistance at relatively high temperature of T>1 0 K comprising a conductor consisting essentially of the superconducting compound noted above

  13. Resistive current limiter with high-temperature superconductors. Final report

    International Nuclear Information System (INIS)

    Schubert, M.

    1995-12-01

    Fundamental results of the possibility of using high temperature superconductors (HTSC) in resistive fault current limiters are discussed. Measurement of the homogeneity of BSCCO-powder-in-tube materials were made. In addition, investigations of the transition from superconducting to normalconducting state under AC-current conditions were carried out. Based on these results, simulations of HTSC-materials on ceramic substrate were made and recent results are presented. Important results of the investigations are: 1. Current-limiting without external trigger only possible when the critical current density of HTSC exceeds 10 4 A/cm 2 . 2. Inhomogeneities sometimes cause problems with local destruction. This can be solved by parallel-elements or external trigger. 3. Fast current-limiting causes overvoltages which can be reduced by using parallel-elements. (orig.) [de

  14. Study of the glass formation of high temperature superconductors

    Science.gov (United States)

    Ethridge, Edwin C.; Kaukler, William F.; Rolin, Terry

    1992-01-01

    A number of compositions of ceramic oxide high T(sub c) superconductors were elevated for their glass formation ability by means of rapid thermal analysis during quenching, optical, and electron microscopy of the quenched samples, and with subsequent DSC measurements. Correlations between experimental measurements and the methodical composition changes identified the formulations of superconductors that can easily form glass. The superconducting material was first formed as a glass; then, with subsequent devitrification, it was formed into a bulk crystalline superconductor by a series of processing methods.

  15. Application of high temperature superconductors for fusion

    International Nuclear Information System (INIS)

    Fietz, W.H.; Heller, R.; Schlachter, S.I.; Goldacker, W.

    2011-01-01

    The use of High Temperature Superconductor (HTS) materials in future fusion machines can increase the efficiency drastically. For ITER, W7-X and JT-60SA the economic benefit of HTS current leads was recognized after a 70 kA HTS current lead demonstrator was designed, fabricated and successfully tested by Karlsruhe Institute of Technology (KIT, which is a merge of former Forschungszentrum Karlsruhe and University of Karlsruhe). For ITER, the Chinese Domestic Agency will provide the current leads as a part of the superconducting feeder system. KIT is in charge of design, construction and test of HTS current leads for W7-X and JT-60SA. For W7-X 14 current leads with a maximum current of 18.2 kA are required that are oriented with the room temperature end at the bottom. JT60-SA will need 26 current leads (20 leads - 20 kA and 6 leads - 25.7 kA) which are mounted in vertical, normal position. These current leads are based on BiSCCO HTS superconductors, demonstrating that HTS material is now state of the art for highly efficient current leads. With respect to future fusion reactors, it would be very promising to use HTS material not only in current leads but also in coils. This would allow a large increase of efficiency if the coils could be operated at temperatures ≥65 K. With such a high temperature it would be possible to omit the radiation shield of the coils, resulting in a less complex cryostat and a size reduction of the machine. In addition less refrigeration power is needed saving investment and operating costs. However, to come to an HTS fusion coil it is necessary to develop low ac loss HTS cables for currents well above 20 kA at high fields well above 10 T. The high field rules BiSCCO superconductors out at temperatures above 50 K, but RE-123 superconductors are promising. The development of a high current, high field RE-123 HTS fusion cable will not be targeted outside fusion community and has to be in the frame of a long term development programme for

  16. High density high-TC ceramic superconductors by hot pressing

    International Nuclear Information System (INIS)

    Mak, S.; Chaklader, A.C.D.

    1989-01-01

    High density and high T C superconductor specimens, YBa 2 Cu 3 O x , have been produced by hot-pressing. The factors studied are the effect of hot pressing on the density, the oxygen stoichiometry, the crystal structure, and the critical temperature. Hot pressing followed by heat treatment increased the density of the specimen to 93%. The hot pressing itself did not significantly affect the oxygen content in the specimen, and although the crystal structure appeared to be orthorhombic, the specimens were not superconducting above liquid nitrogen temperature. The superconductivity was restored after head treatment in oxygen. The highest critical temperature (T C ) of the hot pressed pellets was 82K, which was slightly lower than the T C that could be obtained with the cold pressed/sintered pellets. (6 refs., 5 figs., tab.)

  17. Modeling forces in high-temperature superconductors

    International Nuclear Information System (INIS)

    Turner, L. R.; Foster, M. W.

    1997-01-01

    We have developed a simple model that uses computed shielding currents to determine the forces acting on a high-temperature superconductor (HTS). The model has been applied to measurements of the force between HTS and permanent magnets (PM). Results show the expected hysteretic variation of force as the HTS moves first toward and then away from a permanent magnet, including the reversal of the sign of the force. Optimization of the shielding currents is carried out through a simulated annealing algorithm in a C++ program that repeatedly calls a commercial electromagnetic software code. Agreement with measured forces is encouraging

  18. Microstructural analysis of high-temperature superconductors

    International Nuclear Information System (INIS)

    Passing, H.

    1987-01-01

    At present, research concentrates on the composition YBa 2 Cu 3 O 7-δ , which, in the appropriate synthesis, shows a transition from the state of normal conductivity to superconductivity at a temperature of 91 K. An exact control of the oxygen content of the composition is necessary so that the super-conducting orthorhombic structure develops. Depending on the composition and the sintering temperature, it is possible to produce fine-grained and coarse-grained ceramics with a directed crystal structure. Under the light-optical microscope in polarized light, coarse-grained ceramics show twinning, which occurs during cooling down from the sintering temperature because of a phase change combined with a variation in volume. (orig./MM) [de

  19. Method of manufacture of single phase ceramic superconductors

    Science.gov (United States)

    Singh, Jitrenda P.; Poeppel, Roger B.; Goretta, Kenneth C.; Chen, Nan

    1995-01-01

    A ceramic superconductor is produced by close control of oxygen partial pressure during sintering of the material. The resulting microstructure of YBa.sub.2 Cu.sub.3 O.sub.x indicates that sintering kinetics are enhanced at reduced p(O.sub.2) and that because of second phase precipitates, grain growth is prevented. The density of specimens sintered at 910.degree. C. increased from 79 to 94% theoretical when p(O.sub.2) was decreased from 0.1 to 0.0001 MPa. The increase in density with decrease in p(O.sub.2) derives from enhanced sintering kinetics, due to increased defect concentration and decreased activation energy of the rate-controlling species undergoing diffusion. Sintering at 910.degree. C resulted in a fine-grain microstructure, with an average grain size of about 4 .mu.m. Post sintering annealing in a region of stability for the desired phase converts the second phases and limits grain growth. The method of pinning grain boundaries by small scale decompositive products and then annealing to convert its product to the desired phase can be used for other complex asides. Such a microstructure results in reduced microcracking, strengths as high as 230 MPa and high critical current density capacity.

  20. Potential aerospace applications of high temperature superconductors

    Science.gov (United States)

    Selim, Raouf

    1994-01-01

    The recent discovery of High Temperature Superconductors (HTS) with superconducting transition temperature, T(sub c), above the boiling point of liquid nitrogen has opened the door for using these materials in new and practical applications. These materials have zero resistance to electric current, have the capability of carrying large currents and as such have the potential to be used in high magnetic field applications. One of the space applications that can use superconductors is electromagnetic launch of payloads to low-earth-orbit. An electromagnetic gun-type launcher can be used in small payload systems that are launched at very high velocity, while sled-type magnetically levitated launcher can be used to launch larger payloads at smaller velocities. Both types of launchers are being studied by NASA and the aerospace industry. The use of superconductors will be essential in any of these types of launchers in order to produce the large magnetic fields required to obtain large thrust forces. Low Temperature Superconductor (LTS) technology is mature enough and can be easily integrated in such systems. As for the HTS, many leading companies are currently producing HTS coils and magnets that potentially can be mass-produced for these launchers. It seems that designing and building a small-scale electromagnetic launcher is the next logical step toward seriously considering this method for launching payloads into low-earth-orbit. A second potential application is the use of HTS to build sensitive portable devices for the use in Non Destructive Evaluation (NDE). Superconducting Quantum Interference Devices (SQUID's) are the most sensitive instruments for measuring changes in magnetic flux. By using HTS in SQUID's, one will be able to design a portable unit that uses liquid nitrogen or a cryocooler pump to explore the use of gradiometers or magnetometers to detect deep cracks or corrosion in structures. A third use is the replacement of Infra-Red (IR) sensor leads on

  1. Two decades on[Research into high-temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Durrani, M. [Physics World (United Kingdom)

    2006-04-15

    Research into high-temperature superconductors should focus on experiment, not theory. While the world looked on in horror at the events unfolding at the Chernobyl nuclear-power plant in the Soviet Union 20 years ago this month, another significant - but far less reported - development in the world of physics had just taken place. On 17 April 1986 a short paper by Georg Bednorz and Alexander Mueller arrived at the offices of Zeitschrift fuer Physik in Heidelberg, Germany. The two physicists, based at IBM's Zurich Research Laboratory in Switzerland, announced they had made a material from barium, lanthanum, copper and oxygen that could conduct electricity without resistance when cooled below a transition temperature, T{sub c}, of about 30 K. It was the world's first 'high-temperature' superconductor. Driven by the dream of materials that can superconduct at room temperature, experimentalists scurried back to their labs. Within a year, a T{sub c} of 90 K in another material had been reported and by October 1987 Bednorz and Mueller had been crowned with a Nobel prize. While papers on high-temperature superconductivity have continued to stream out since those heady days, progress has been slower than expected. Applications like levitating trains and resistance-free power cables are only now starting to come to market. Scientists have been unable to make superconducting wires that work much above 130 K, while a reliable theory of high-temperature superconductivity remains elusive. Even if we had such a theory, it is not clear that it would predict which materials might superconduct at room temperature. After all, the Bardeen-Cooper-Schrieffer theory, which explains the behaviour of low-temperature superconductors with admirable success, said nothing about the superconducting properties of Bednorz and Mueller's copper-oxide ceramics. What successes there have been over the last 20 years - such as the recent discoveries that iron, single crystals

  2. High-temperature superconductors make major progress

    CERN Multimedia

    CERN Bulletin

    2014-01-01

    This month's Nature Materials featured an important breakthrough for high-temperature superconductors. A new method has been found for processing Bi-2212 high-temperature superconducting round wire in order to drastically increase its critical current density. The result confirms that this conductor is a serious candidate for future very-high-field magnets.   This image shows the cross-section of two Bi-2212 wires. The bottom wire has less leakage and void porosity due to a heat treatment done at an overpressure of 100 bar - about 100 times the pressure used to produce the top wire (image from [Nature Materials, Vol. 13 (2014), 10.1038/nmat3887]). The workhorse for building superconducting accelerator magnets has been, so far, the Niobium-Titanium (Nb-Ti) alloy superconductor. But with Nb-Ti having reached its full potential, other conductors must be used to operate in higher magnetic fields beyond those reached with the LHC magnets. Today, the intermetallic Niobium-Tin (Nb3Sn) is th...

  3. Critical fields in high temperature superconductors

    International Nuclear Information System (INIS)

    Finnemore, D.K.

    1991-01-01

    An analysis of various methods to obtain the critical fields of the high temperature superconductors from experimental data is undertaken in order to find definitions of these variables that are consistent with the models used to define them. Characteristic critical fields of H c1 , H c2 and H c that occur in the Ginsburg-Landau theory are difficult to determine experimentally in the high temperature superconductors because there are additional physical phenomena that obscure the results. The lower critical field is difficult to measure because there are flux pinning and surface barrier effects to flux entry; the upper critical field is difficult because fluctuation effects are large at this phase boundary; the thermodynamic critical field is difficult because fluctuations make it difficult to know the field where the magnetization integral should be terminated. In addition to these critical fields there are at least two other cross-over fields. There is the so called irreversibility line where the vortices transform from a rigid flux line lattice to a fluid lattice and there is a second cross-over field associated with the transition from the fluctuation to the Abrikosov vortex regime. The presence of these new physical effects may require new vocabulary

  4. Electronic phase separation and high temperature superconductors

    International Nuclear Information System (INIS)

    Kivelson, S.A.

    1994-01-01

    The authors review the extensive evidence from model calculations that neutral holes in an antiferromagnet separate into hole-rich and hole-poor phases. All known solvable limits of models of holes in a Heisenberg antiferromagnet exhibit this behavior. The authors show that when the phase separation is frustrated by the introduction of long-range Coulomb interactions, the typical consequence is either a modulated (charge density wave) state or a superconducting phase. The authors then review some of the strong experimental evidence supporting an electronically-driven phase separation of the holes in the cuprate superconductors and the related Ni oxides. Finally, the authors argue that frustrated phase separation in these materials can account for many of the anomalous normal state properties of the high temperature superconductors and provide the mechanism of superconductivity. In particular, it is shown that the T-linear resistivity of the normal state is a paraconductivity associated with a novel composite pairing, although the ordered superconducting state is more conventional

  5. Panel report on high temperature ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Nolet, T C [ed.

    1979-01-01

    Fundamental research is reported concerning high temperature ceramics for application in turbines, engines, batteries, gasifiers, MHD, fuel cells, heat exchangers, and hot wall combustors. Ceramics microstructure and behavior are included. (FS)

  6. Preparation of a ceramic superconductor from ultrafine particles by freeze-dry process in Ba-Y-Cu-O system

    International Nuclear Information System (INIS)

    Chen Zuyao; Qian Yitai; Wan Yanjian; Rong Jingfang; Zhang Han; Pan Guoqiang; Zhao Yong; Zhang Qirui

    1989-01-01

    Freeze-dry technique is first reported for preparing ceramic ultrafines. The single-phase complex oxide Ba 2 YCu 3 O/sub 9-δ/, a poly-crystallized compound, and ceramic superconductor have been synthesized successfully. The experimental results show that not only is the ceramic superconductor obtained uniform with fine particles and excellent superconductivity, but the conditions for solid reactions are relatively limited

  7. Low critical temperature superconductors for electromagnets

    International Nuclear Information System (INIS)

    Devred, A.

    2002-01-01

    After a brief history of the main discoveries in applied superconductivity (section 1), we discuss the structure and properties of NbTi and Nb3 Sn (section 2). Then, we explain why low critical-temperature superconductors are produced under the form of multifilamentary composites (section 3), and we review the manufacturing processes of NbTi and Nb3Sn wires (section 4). We follow by a description of the transition from the superconducting to the normal resistive state of multifilamentary composite wires (section 5) and we detail their magnetization properties section 6). Last, we present the most commonly used cable configurations (section 7) and we provide simple formulae illustrating on a few examples the computation of losses generated under time-varying magnetic fields (section 8). (author)

  8. High-temperature superconductors in application - fight for the top

    International Nuclear Information System (INIS)

    Anon.

    1990-01-01

    For the superconductor market two-digit growth rates are predicted until after the year 2000. The decrosslinking of the high temperature superconductors initiated a worldwide race for first applications. The report considers the situation of raw materials and the application potentials in the USA, Japan and Western Europe. (orig.) [de

  9. Magnetic properties of high temperature superconductors and their interaction with high energy permanent magnets

    International Nuclear Information System (INIS)

    Agarwala, A.K.

    1990-01-01

    Magnetic properties of sintered samples of YBCO ceramic superconductors at various temperatures were measured using a vibrating sample magnetometer (VSM). Also, measurements of forces experienced by a well characterized rare earth-transition metal (RE-TM) permanent magnet (PM) interacting with the superconducting YBCO sample cooled in liquid nitrogen, were performed. Based upon the observed hysteretic magnetization properties of these high temperature superconductors (HTS), the HTS-PM interaction force at liquid nitrogen temperature was calculated from first principle, and finally correlated to the force measurement results. With this analysis, magnetic forces between the same HTS and PM system including the levitation as well as suspension effects at liquid-helium temperature are predicted

  10. MHD oxidant intermediate temperature ceramic heater study

    Science.gov (United States)

    Carlson, A. W.; Chait, I. L.; Saari, D. P.; Marksberry, C. L.

    1981-09-01

    The use of three types of directly fired ceramic heaters for preheating oxygen enriched air to an intermediate temperature of 1144K was investigated. The three types of ceramic heaters are: (1) a fixed bed, periodic flow ceramic brick regenerative heater; (2) a ceramic pebble regenerative heater. The heater design, performance and operating characteristics under conditions in which the particulate matter is not solidified are evaluated. A comparison and overall evaluation of the three types of ceramic heaters and temperature range determination at which the particulate matter in the MHD exhaust gas is estimated to be a dry powder are presented.

  11. High critical temperature superconductors: Progress achieved after two years

    International Nuclear Information System (INIS)

    Maillard, J.M.; Rammal, R.; Vittorge, M.C.

    1989-01-01

    Progress concerning the theory of high temperature superconductors and activity of laboratories of the CNRS (France) are reviewed and news on strategy, budgets, theoretical research, materials characterization, fabrication process technology transfers, commercialisation, uses and data bases are given [fr

  12. Leaders in high temperature superconductivity commercialization win superconductor industry award

    CERN Multimedia

    2007-01-01

    CERN's Large Hadron Collider curretn leads project head Amalia Ballarino named superconductor industry person of the year 2006. Former high temperature superconductivity program manager at the US Department of energy James Daley wins lifetime achievement award. (1,5 page)

  13. Use of the inverse temperature profile in microwave processing of advanced ceramics

    International Nuclear Information System (INIS)

    Binner, J.G.P.; Al-Dawery, I.A.; Aneziris, C.; Cross, T.E.

    1992-01-01

    Attempts are being made to exploit the inverse temperature profile which can be developed with microwave heating with respect to the processing of certain advanced ceramics. This paper discusses the results obtained to date during the microwave sintering of YBCO high-T c superconductors and the microwave reaction bonding of silicon nitride

  14. Enhancement of critical temperature in fractal metamaterial superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Smolyaninov, Igor I., E-mail: smoly@umd.edu [Department of Electrical and Computer Engineering, University of Maryland, College Park, MD 20742 (United States); Smolyaninova, Vera N. [Department of Physics Astronomy and Geosciences, Towson University, 8000 York Road, Towson, MD 21252 (United States)

    2017-04-15

    Fractal metamaterial superconductor geometry has been suggested and analyzed based on the recently developed theoretical description of critical temperature increase in epsilon near zero (ENZ) metamaterial superconductors. Considerable enhancement of critical temperature has been predicted in such materials due to appearance of large number of additional poles in the inverse dielectric response function of the fractal. Our results agree with the recent observation (Fratini et al. Nature 466, 841 (2010)) that fractal defect structure promotes superconductivity.

  15. Potentialities in electronics of new high critical temperature superconductors

    International Nuclear Information System (INIS)

    Hartemann, P.

    1989-01-01

    The main electronic applications of superconductors involve the signal processing, the electromagnetic wave detection and the magnetometry. Characteristics of devices based on conventional superconductors cooled by liquid helium are given and the changes induced by incorporating high-temperature superconductors are estimated. After a survey of new superconductor properties, the superconducting devices for analog or digital signal processing are reviewed. The gains predicted for high-temperature superconducting analog devices are considered in greater detail. Different sections deal with the infrared or (sub)millimeter wave detection. The most sensitive apparatuses for magnetic measurements are based on SQUIDs. Features of SQUIDs made of granular high-temperature superconducting material samples (grain boundaries behave as barriers of intrinsic junctions) are discussed [fr

  16. High temperature superconductors at optimal doping

    Directory of Open Access Journals (Sweden)

    W. E. Pickett

    2006-09-01

    Full Text Available   Intensive study of the high temperature superconductors has been ongoing for two decades. A great deal of this effort has been devoted to the underdoped regime, where the new and difficult physics of the doped Mott insulator has met extra complications including bilayer coupling/splitting, shadow bands, and hot spots. While these complications continue to unfold, in this short overview the focus is moved to the region of actual high-Tc, that of optimal doping. The focus here also is not on the superconducting state itself, but primarily on the characteristics of the normal state from which the superconducting instability arises, and even these can be given only a broad-brush description. A reminder is given of two issues,(i why the “optimal Tc” varies,for n-layered systems it increases for n up to 3, then decreases for a given n, Tc increases according to the ‘basis’ atom in the order Bi, Tl, Hg (ii how does pressure, or a particular uniaxial strain, increase Tc when the zero-strain system is already optimally doped?

  17. Magnetic memory effects in high temperature superconductors

    International Nuclear Information System (INIS)

    Rockenbauer, A.

    1989-01-01

    Microwave absorption of high temperature oxide superconductors MBa 2 Cu 3 O 7 (M = Y, Er, Dy, Ho, Lu, Tm, Gd) at 77 K have been studied by ESR. In granular samples diamagnetic zero-field resonance and strong ESR baseline hysteresis have been observed: for increasing field sweep - a high, for decreasing one - a low, while in constant field the baseline approaches the middle position with kinetics typical of spin-glasses. The hysteresis amplitude, i.e. the deviation of high and low baselines, possesses maximum at zero field if the sample is cooled down in zero field. In case of field cooling both the diamagnetic resonance and hysteresis maximum are shifted as a function of relative direction of the fields where the samples are cooled and measured, respectively. The shift is caused by the remanent diamagnetism of trapped fluxons. The hysteresis critically depends on the modulation amplitude of magnetic field, and no hysteresis can be observed if the microwave absorption is detected without field modulation. By applying saw-tooth sweep the spin-glass can be driven between two extreme hysteresis states, and the ESR response is rectangular for large saw-tooth amplitude and linear - for small one, while for intermediate amplitudes the recording shows characteristic memory effects. The hysteresis memory is explained in terms of loop distribution of fluxons. In the single crystal the fluxon absorptions are also detected and the separation of fluxon lines can be related to the hysteresis in granular samples. (author)

  18. High point for CERN and high-temperature superconductors

    CERN Multimedia

    2007-01-01

    Amalia Ballarino is named the Superconductor Industry Person of the year 2006. Amalia Ballarino showing a tape of high-superconducting material used for the LHC current leads.The CERN project leader for the high-temperature superconducting current leads for the LHC, Amalia Ballarino, has received the award for "Superconductor Industry Person of the Year". This award, the most prestigious international award in the development and commercialization of superconductors, is presented by the leading industry newsletter "Superconductor Week". Amalia Ballarino was selected from dozens of nominations from around the world by a panel of recognized leading experts in superconductivity. "It is a great honour for me," says Amalia Ballarino. "It has been many years of hard work, and it’s a great satisfaction to see that the work has been completed successfully." Amalia Ballarino has been working on high-temperature superconducting materials sin...

  19. High temperature alloys and ceramic heat exchanger

    International Nuclear Information System (INIS)

    Okamoto, Masaharu

    1984-04-01

    From the standpoint of energy saving, the future operating temperatures of process heat and gas turbine plants will become higher. For this purpose, ceramics is the most promissing candidate material in strength for application to high-temperature heat exchangers. This report deals with a servey of characteristics of several high-temperature metallic materials and ceramics as temperature-resistant materials; including a servey of the state-of-the-art of ceramic heat exchanger technologies developed outside of Japan, and a study of their application to the intermediate heat exchanger of VHTR (a very-high-temperature gas-cooled reactor). (author)

  20. High temperature fracture of ceramic materials

    International Nuclear Information System (INIS)

    Wiederhorn, S.M.

    1979-01-01

    A review is presented of fracture mechanisms and methods of lifetime prediction in ceramic materials. Techniques of lifetime prediction are based on the science of fracture mechanics. Application of these techniques to structural ceramics is limited by our incomplete understanding of fracture mechanisms in these materials, and by the occurrence of flaw generation in these materials at elevated temperatures. Research on flaw generation and fracture mechanisms is recommended as a way of improving the reliability of structural ceramics

  1. Superconductors

    International Nuclear Information System (INIS)

    Ekin, J.W.

    1983-01-01

    This chapter attempts to provide an introductory guide to interpreting handbook data on practical, high-current, superconducting materials, principally for magnet applications. An overview is given of the properties and operational limits of superconductive materials, as well as techniques used to fabricate practical superconducting wires. Topics considered include critical temperature, critical magnetic field, Type I and Type II superconductors, upper critical field values for practical materials, the temperature dependence of critical field and upper critical field, critical current, critical current density values for practical materials, the measurement of critical current, composite fabrication, stability, ac losses, eddy current loss, hysteretic loss, mechanical properties, critical current degradation, and superconducting materals selection and composite design

  2. Signature of electron-phonon interaction in high temperature superconductors

    Directory of Open Access Journals (Sweden)

    Vinod Ashokan

    2011-09-01

    Full Text Available The theory of thermal conductivity of high temperature superconductors (HTS based on electron and phonon line width (life times formulation is developed with Quantum dynamical approach of Green's function. The frequency line width is observed as an extremely sensitive quantity in the transport phenomena of HTS as a collection of large number of scattering processes. The role of resonance scattering and electron-phonon interaction processes is found to be most prominent near critical temperature. The theory successfully explains the spectacular behaviour of high Tc superconductors in the vicinity of transition temperature. A successful agreement between theory and experiment has been obtained by analyzing the thermal conductivity data for the sample La1.8Sr0.2CuO4 in the temperature range 0 − 200K. The theory is equally and successfully applicable to all other high Tc superconductors.

  3. Probing High Temperature Superconductors with Magnetometry in Ultrahigh Magnetic Fields

    Energy Technology Data Exchange (ETDEWEB)

    Li, Lu [Univ. of Michigan, Ann Arbor, MI (United States)

    2017-07-26

    The objective of this research is to investigate the high-field magnetic properties of high temperature superconductors, materials that conduct electricity without loss. A technique known as high-resolution torque magnetometry that was developed to directly measure the magnetization of high temperature superconductors. This technique was implemented using the 65 Tesla pulsed magnetic field facility that is part of the National High Magnetic Field Laboratory at Los Alamos National Laboratory. This research addressed unanswered questions about the interplay between magnetism and superconductivity, determine the electronic structure of high temperature superconductors, and shed light on the mechanism of high temperature superconductivity and on potential applications of these materials in areas such as energy generation and power transmission. Further applications of the technology resolve the novel physical phenomena such as correlated topological insulators, and spin liquid state in quantum magnets.

  4. Thermal conductivity in high critical temperature superconductors

    International Nuclear Information System (INIS)

    Castello, D.J.

    1990-01-01

    A measuring procedure to obtain the electrical resistivity, thermal conductivity and thermoelectric power of samples of low conductivity has been developed. The setup was designed to allow the removal of the sample in clean fashion, so that further heat treatments could be performed, and therefore no adhesives were used in the mounting of the thermocouples or heat sinks, etc. The heat equation has been analyzed with time-dependent boundary conditions, with the purpose of developing a dynamic measuring method which avoids the long delays involved in reaching thermal equilibrium above 30K. Based on this analysis, the developed measuring method allows a precise and reliable measurements, in a continuous fashion, for temperatures above 25K. The same setup is used in a stationary mode at low temperatures, so the sample needs to be mounted only once. κ(T) has been measured in two ceramic samples of La 2 CuO 4 : the first semiconducting, the other superconducting (SC) as a consequence of an oxygen annealing. Both exhibit a strong thermal resistivity due to defects, though lower in the SC, where two maxima are observed and are attributed to an AF ordering: T N ' ≅ 40K and T N '' ≅ 240K. The low temperature dependence is T 1 .6 and T 2 .3 respectively. It was interpreted that the former sample presents a greater dispersion due to localized excitations, characteristic of amorphouus materials, 'tunneling two-level systems' (TS). A third syntherized sample of CuO exhibits a typical behaviour of an insulator, with T 2 .6 at low temperatures, a maximum at 40K and a decrease in T -1 at high temperatures. κ(T) in a SC sample of La 1 .85Sr 1 .15CuO 4 with T c =35.5K has also been measured, observing a small increase below T c because of the diminishing of the phonon dispersion due to the condensating electrons. κ(T) is lower than in the previous samples and thus a greater number of defects was inferred. At low temperatures, its dependence is T 1 .4 in agreement with the

  5. Research On Bi-Based High-Temperature Superconductors

    Science.gov (United States)

    Banks, Curtis; Doane, George B., III; Golben, John

    1993-01-01

    Brief report describes effects of melt sintering on Bi-based high-temperature superconductor system, as well as use of vibrating-sample magnetometer to determine hysteresis curves at 77 K for partially melt-sintered samples. Also discussed is production of high-temperature superconducting thin films by laser ablation: such films potentially useful in detection of signals of very low power.

  6. High-Temperature Cuprate Superconductors Experiment, Theory, and Applications

    CERN Document Server

    Plakida, Nikolay Maksimilianovich

    2010-01-01

    High-Temperature Cuprate Superconductors provides an up-to-date and comprehensive review of the properties of these fascinating materials. The essential properties of high-temperature cuprate superconductors are reviewed on the background of their theoretical interpretation. The experimental results for structural, magnetic, thermal, electric, optical and lattice properties of various cuprate superconductors are presented with respect to relevant theoretical models. A critical comparison of various theoretical models involving strong electron correlations, antiferromagnetic spin fluctuations, phonons and excitons provides a background for understanding of the mechanism of high-temperature superconductivity. Recent achievements in their applications are also reviewed. A large number of illustrations and tables gives valuable information for specialists. A text-book level presentation with formulation of a general theory of strong-coupling superconductivity will help students and researches to consolidate their...

  7. High-temperature cuprate superconductors. Experiment, theory, and applications

    International Nuclear Information System (INIS)

    Plakida, Nikolay

    2010-01-01

    High-Temperature Cuprate Superconductors provides an up-to-date and comprehensive review of the properties of these fascinating materials. The essential properties of high-temperature cuprate superconductors are reviewed on the background of their theoretical interpretation. The experimental results for structural, magnetic, thermal, electric, optical and lattice properties of various cuprate superconductors are presented with respect to relevant theoretical models. A critical comparison of various theoretical models involving strong electron correlations, antiferromagnetic spin fluctuations, phonons and excitons provides a background for understanding of the mechanism of high-temperature superconductivity. Recent achievements in their applications are also reviewed. A large number of illustrations and tables gives valuable information for specialists. A text-book level presentation with formulation of a general theory of strong-coupling superconductivity will help students and researches to consolidate their knowledge of this remarkable class of materials. (orig.)

  8. TECHNICAL TRAINING SEMINAR: High Temperature Superconductors: Progress and Issues

    CERN Multimedia

    Davide Vitè

    2002-01-01

    Monday 24 June from 14:30 to 15:30 - Training Centre Auditorium - bldg. 593-11 High Temperature Superconductors: Progress and Issues Prof. Jan Evetts / UNIVERSITY OF CAMBRIDGE, Department of Materials Science and Metallurgy, UK Grappling with grain boundaries: Current transport processes in granular High Temperature Superconductors (HTS) The development of High Temperature Superconductors, seen from a materials scientist's point of view, is relevant to the superconductivity community at CERN: their possible high current applications can include high performance magnets for future accelerators. There is an urgent need to develop a quantitative description of HTS conductors in terms of their complex anisotropy, inhomogeneity and dimensionality. This is essential both for the practical specification of a conductor and for charting routes to conductor optimisation. The critical current, the n-value, dissipation and quenching characteristics are amongst most important parameters that make up an engineering specifi...

  9. The Born-Mayer-Huggins potential in high temperature superconductors

    Science.gov (United States)

    Singh, Hempal; Singh, Anu; Indu, B. D.

    2016-07-01

    The Born-Mayer-Huggins potential which has been found the best suitable potential to study the YBa2Cu3O7-δ type high temperature superconductors is revisited in a new framework. A deeper insight in it reveals that the Born-Mayer parameters for different interactions in high temperature superconductor are not simple quantities but several thermodynamic and spatial functions enter the problem. Based on the new theory, the expressions for pressure, bulk modulus and Born-Mayer parameters have been derived and it is established that these quantities depend upon Gruneisen parameter which is the measure of the strength of anharmonic effects in high temperature superconductors. This theory has been applied to a specific model YBa2Cu3O7-δ crystal for the purpose of numerical estimates to justify the new results.

  10. Theory of tunneling in metal--superconductor devices: Supercurrents in the superconductor gap at zero temperature

    International Nuclear Information System (INIS)

    Garcia, N.; Flores, F.; Guinea, F.

    1988-01-01

    Tunneling experiments in metal-oxide superconductor have shown the existence of ''leakage'' currents for applied voltages V smaller than one-half of the superconductor gap Δ. These currents are independent of temperature T. Recently experiments with scanning tunneling microscopy (STM) and squeezable tunnel junctions have shown that the observation of the superconductor gap depends strongly on the resistance in the junction. In fact only for resistances larger than ∼10 6 Ω the gap is clearly observable. These experiments have been explained in terms of the perturbative Hamiltonian formalism of Bardeen. However, it may happen that this theory while applicable for very large resistances may not be so for small tunnel resistances. We present here a nonperturbative theory in all orders of the transmitivity chemical bondTochemical bond 2 and show the existence of supercurrents for values of V 2 . We believe that experiments in STM and other junctions should be interpreted in the frame of this theory

  11. Targets on the basis of ferrites and high-temperature superconductors for ion-plasma sputtering

    International Nuclear Information System (INIS)

    Lepeshev, A.A.; Saunin, V.N.; Telegin, S.V.; Polyakova, K.P.; Seredkin, V.A.; Pol'skij, A.I.

    2000-01-01

    Paper describes a method to produce targets for ion-plasma sputtering using plasma splaying of the appropriate powders on a cooled metal basis. Application of the plasma process was demonstrated to enable to produce complex shaped targets under the controlled atmosphere on the basis of ceramic materials ensuring their high composition homogeneity, as well as, reliable mechanical and thermal contact of the resultant coating with the base. One carried out experiments in ion-plasma sputtering of targets to prepare ferrite polycrystalline films to be used in magnetooptics and to prepare high-temperature superconductor epitaxial films [ru

  12. Temperature measurement of RE123 bulk superconductors on magnetizing process

    International Nuclear Information System (INIS)

    Yokoyama, K.; Kaneyama, M.; Oka, T.; Fujishiro, H.; Noto, K.

    2004-01-01

    We study on the magnetization behavior of to magnetize RE123 bulk superconductors to apply it as strong magnets. Through magnetizing process, the temperature of bulk superconductors is raised by pinning loss caused by the magnetic fluxes motion (e.g. flux jump of flux flow), and the trapped field is decreased. This paper presents the measurement of temperature changes of Sm123 bulk superconductors during the exciting process by iteratively magnetizing pulsed-field operation with reducing amplitudes (IMRA) method. Five thermocouples are put on the surface of Sm123 bulk superconductor of 46 mm in diameter. The temperatures at the center, on the growth sector boundary (GSB) line and in the sector region surrounded by GSB's line (inter-GSB region) are monitored. The temperature at a cold stage is also measured. A Hall sensor is attached near the center thermocouple to measure the trapped field. After a bulk superconductor is cooled by the GM type refrigerator until 40 K, iterative pulsed-fields of 2.32-5.42 T are applied by a magnetizing coil. When high magnetic field of 5.42 T is applied, a temperature of bulk superconductor reaches to 72.4 K and the magnetic field distribution has C form with which a part of circle is dented, and then, a trapped field is 2.28 T. When a lower magnetic field of 4.64 T is applied, a maximum temperature is 68.3 K and a trapped field is raised to 2.70 T, and moreover, the distribution becomes round shape like field-cooling method (FC). We showed clearly that heat generation by pinning loss was related to the mechanism of magnetic field capture

  13. Evaluation of oxygenation time in SmBa2Cu3O7-δ superconductors ceramics in air and ozone atmospheres

    International Nuclear Information System (INIS)

    Viana, P.R.P; Cunha, A.G.

    2010-01-01

    High temperature superconductors (HTSC) represent a major milestone in science. During the preparation of superconductors, oxygenation plays a key role, because oxygenation determines the distribution of charge carriers in these plans through the superconducting Cu-O and hence superconductivity. This paper proposes the preparation of polycrystalline superconductors using the ceramic method, and the step of oxygenation made with ozone gas (O 3 ). Ozone exerts chemical pressure on the compound, which has oxygen vacancies in its structure after the step of synthesis. The work was performed by varying the time between oxygenation 20, 40, 80 and 160 hours, with samples going through a process of oxygenation at 350 deg C after the step of synthesis. This study evaluates the time effect as oxygen can improve the superconducting properties such as resistivity and magnetic susceptibility. (author)

  14. Method for fabrication of high temperature superconductors

    Science.gov (United States)

    Balachandran, Uthamalingam [Hinsdale, IL; Ma, Beihai [Naperville, IL; Miller, Dean [Darien, IL

    2009-07-14

    A layered article of manufacture and a method of manufacturing same is disclosed. A substrate has a biaxially textured MgO crystalline layer having the c-axes thereof inclined with respect to the plane of the substrate deposited thereon. A layer of one or more of YSZ or Y.sub.2O.sub.3 and then a layer of CeO.sub.2 is deposited on the MgO. A crystalline superconductor layer with the c-axes thereof normal to the plane of the substrate is deposited on the CeO.sub.2 layer. Deposition of the MgO layer on the substrate is by the inclined substrate deposition method developed at Argonne National Laboratory. Preferably, the MgO has the c-axes thereof inclined with respect to the normal to the substrate in the range of from about 10.degree. to about 40.degree. and YBCO superconductors are used.

  15. Spins in the vortices of a high-temperature superconductor

    DEFF Research Database (Denmark)

    Lake, B.; Aeppli, G.; Clausen, K.N.

    2001-01-01

    Neutron scattering is used to characterize the magnetism of the vortices for the optimally doped high-temperature superconductor La2-xSrxCuO4 (x = 0.163) in an applied magnetic field. As temperature is reduced, Low-frequency spin fluctuations first disappear with the loss of vortex mobility......, but then reappear. We find that the vortex state can be regarded as an inhomogeneous mixture of a superconducting spin fluid and a material containing a nearly ordered antiferromagnet. These experiments show that as for many other properties of cuprate superconductors, the important underlying microscopic forces...

  16. High temperature superconductors for fusion magnets -influence of neutron irradiation

    International Nuclear Information System (INIS)

    Chudy, M.; Eisterer, M.; Weber, H. W.

    2010-01-01

    In this work authors present the results of study of influence of neutron irradiation of high temperature superconductors for fusion magnets. High temperature superconductors (type of YBCO (Yttrium-Barium-Copper-Oxygen)) are strong candidates to be applied in the next step of fusion devices. Defects induced by fast neutrons are effective pinning centres, which can significantly improve critical current densities and reduce J c anisotropy. Due to induced lattice disorder, T c is reduced. Requirements for ITER (DEMO) are partially achieved at 64 K.

  17. High Temperature Characterization of Ceramic Pressure Sensors

    National Research Council Canada - National Science Library

    Fonseca, Michael A; English, Jennifer M; Von Arx, Martin; Allen, Mark G

    2001-01-01

    This work reports functional wireless ceramic micromachined pressure sensors operating at 450 C, with demonstrated materials and readout capability indicating potential extension to temperatures in excess of 600 C...

  18. Proceedings, phenomenology and applications of high temperature superconductors

    International Nuclear Information System (INIS)

    Bedell, K.S.

    1991-01-01

    Phenomenology and Applications of High Temperature Superconductors, The Los Alamos Symposium: 1991, was sponsored by the Los Alamos National Laboratory, Center for Materials Science, the Advanced Studies Program on High Temperature Superconductivity Theory (ASP) and the Exploratory Research and Development Center. This is the second symposium in the series. High Temperature Superconductivity, The Los Alamos Symposium: 1989, also published by Addison Wesley, focused on the cutting-edge theoretical and experimental issues in high temperature superconductors. This symposium, with its focus on the phenomenology and applications of high temperature superconductors, gives a complementary review of the aspects of the field closely related to the impact of high temperature superconductors on technology. The objective of ASP is to advance the field on a broad front with no specific point of view by bringing a team of leading academic theorists into a joint effort with the theoretical and experimental scientists of a major DOE national laboratory. The ASP consisted of fellows led by Robert Schrieffer (UCSB and now FSU) joined by David Pines (University of illinois), Elihu Abrahams (Rutgers), Sebastian Doniach (Stanford), and Maurice Rice (ETH, Zurich) and theoretical and experimental staff of Los Alamos National Laboratory. This synergism of academic, laboratory, theoretical and experimental research produced a level of interaction and excitement that would not be possible otherwise. This publication and the previous one in the series are just examples of how this approach to advancing science can achieve significant contributions

  19. Theoretical modeling of critical temperature increase in metamaterial superconductors

    Science.gov (United States)

    Smolyaninov, Igor; Smolyaninova, Vera

    Recent experiments have demonstrated that the metamaterial approach is capable of drastic increase of the critical temperature Tc of epsilon near zero (ENZ) metamaterial superconductors. For example, tripling of the critical temperature has been observed in Al-Al2O3 ENZ core-shell metamaterials. Here, we perform theoretical modelling of Tc increase in metamaterial superconductors based on the Maxwell-Garnett approximation of their dielectric response function. Good agreement is demonstrated between theoretical modelling and experimental results in both aluminum and tin-based metamaterials. Taking advantage of the demonstrated success of this model, the critical temperature of hypothetic niobium, MgB2 and H2S-based metamaterial superconductors is evaluated. The MgB2-based metamaterial superconductors are projected to reach the liquid nitrogen temperature range. In the case of an H2S-based metamaterial Tc appears to reach 250 K. This work was supported in part by NSF Grant DMR-1104676 and the School of Emerging Technologies at Towson University.

  20. Contact spectroscopy of high-temperature superconductors. Review

    International Nuclear Information System (INIS)

    Yanson, I.K.

    1991-01-01

    We have attempted to systematize the research of high temperature superconductors by means of tunneling and point-contact spectroscopy. The theoretical grounds of the methods are briefly described. The deviations of current-voltage characteristics from ordinary superconductors are considered. The properties of point contacts with direct energy gap measurfements and the fine structure of derivatives of i(v) curves at the overlap energies are reviewed for the high-T c La 2-x Sr x CuO 4 materials

  1. Survey of potential electronic applications of high temperature superconductors

    International Nuclear Information System (INIS)

    Hammond, R.B.; Bourne, L.C.

    1991-01-01

    In this paper the authors present a survey of the potential electronic applications of high temperature superconductor (HTSC) thin films. During the past four years there has been substantial speculation on this topic. The authors will cover only a small fraction of the potential electronic applications that have been identified. Their treatment is influenced by the developments over the past few years in materials and device development and in market analysis. They present their view of the most promising potential applications. Superconductors have two important properties that make them attractive for electronic applications. These are (a) low surface resistance at high frequencies, and (b) the Josephson effect

  2. Weak coupling theory of high temperature superconductors

    International Nuclear Information System (INIS)

    Labbe, J.

    1990-01-01

    Many theories of the high T c superconductors are founded on the hypothesis that the electron-electron correlations are so strong in these materials that, in the absence of doping or internal charge transfer, they should be Mott insulators. The authors consider this hypothesis as unlikely for the following reasons. At first, very strong correlations would arise from a very large repulsive Coulomb energy between electrons within each atom. This would be the case only with very strongly localized atomic orbitals, as for instance the f orbitals in the rare earths, leading to very narrow energy bands. But in the copper oxides, the d orbitals of copper, or the p orbitals of oxygen, are not so strongly localized, and thus the intra-atomic repulsive Coulomb energy has no reason to be much larger than in the simple transitional metals or their other compounds

  3. Macroscopic phase separation in high-temperature superconductors

    Science.gov (United States)

    Wen, Hai-Hu

    2000-01-01

    High-temperature superconductivity is recovered by introducing extra holes to the Cu-O planes, which initially are insulating with antiferromagnetism. In this paper I present data to show the macroscopic electronic phase separation that is caused by either mobile doping or electronic instability in the overdoped region. My results clearly demonstrate that the electronic inhomogeneity is probably a general feature of high-temperature superconductors. PMID:11027323

  4. Time dependence of magnetization of high temperature superconductors

    International Nuclear Information System (INIS)

    Larkin, A.I.; Geshkenbein, V.B.

    1988-10-01

    Magnetization of high T c superconductors logarithmically decreases with time. There is a maximum in the temperature dependence of the coefficient at this logarithm. If one assumes that there do exist two kinds of pinning centers, then this dependence can be described in the Anderson theory of thermal creeps of Abrikosov's vortices. The temperature dependence of the critical current is also discussed. (author). 23 refs

  5. Cryocooler applications for high-temperature superconductor magnetic bearings

    International Nuclear Information System (INIS)

    Niemann, R. C.

    1998-01-01

    The efficiency and stability of rotational magnetic suspension systems are enhanced by the use of high-temperature superconductor (HTS) magnetic bearings. Fundamental aspects of the HTS magnetic bearings and rotational magnetic suspension are presented. HTS cooling can be by liquid cryogen bath immersion or by direct conduction, and thus there are various applications and integration issues for cryocoolers. Among the numerous cryocooler aspects to be considered are installation; operating temperature; losses; and vacuum pumping

  6. Electronic ceramics in high-temperature environments

    International Nuclear Information System (INIS)

    Searcy, A.W.; Meschi, D.J.

    1982-01-01

    Simple thermodynamic means are described for understanding and predicting the influence of temperature changes, in various environments, on electronic properties of ceramics. Thermal gradients, thermal cycling, and vacuum annealing are discussed, as well as the variations of ctivities and solubilities with temperature. 7 refs

  7. Electronic Structure of the Bismuth Family of High Temperature Superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Dunn, Lisa

    2002-03-07

    High temperature superconductivity remains the central intellectual problem in condensed matter physics fifteen years after its discovery. Angle resolved photoemission spectroscopy (ARPES) directly probes the electronic structure, and has played an important role in the field of high temperature superconductors. With the recent advances in sample growth and the photoemission technique, we are able to study the electronic structure in great detail, and address regimes that were previously inaccessible. This thesis work contains systematic photoemission studies of the electronic structure of the Bi-family of high temperature superconductors, which include the single-layer system (Bi2201), the bi-layer system (Bi2212), and the tri-layer system (Bi2223). We show that, unlike conventional BCS superconductors, phase coherence information emerges in the single particle excitation spectrum of high temperature superconductors as the superconducting peak in Bi2212. The universality and various properties of this superconducting peak are studied in various systems. We argue that the origin of the superconducting peak may provide the key to understanding the mechanism of High-Tc superconductors. In addition, we identified a new experimental energy scale in the bilayer material, the anisotropic intra-bilayer coupling energy. For a long time, it was predicted that this energy scale would cause bilayer band splitting. We observe this phenomenon, for the first time, in heavily overdoped Bi2212. This new observation requires the revision of the previous picture of the electronic excitation in the Brillouin zone boundary. As the first ARPES study of a trilayer system, various detailed electronic proper- ties of Bi2223 are examined. We show that, comparing with Bi2212, both superconducting gap and relative superconducting peak intensity become larger in Bi2223, however, the strength of the interlayer coupling within each unit cell is possibly weaker. These results suggest that the

  8. Identifying the genes of unconventional high temperature superconductors.

    Science.gov (United States)

    Hu, Jiangping

    We elucidate a recently emergent framework in unifying the two families of high temperature (high [Formula: see text]) superconductors, cuprates and iron-based superconductors. The unification suggests that the latter is simply the counterpart of the former to realize robust extended s-wave pairing symmetries in a square lattice. The unification identifies that the key ingredients (gene) of high [Formula: see text] superconductors is a quasi two dimensional electronic environment in which the d -orbitals of cations that participate in strong in-plane couplings to the p -orbitals of anions are isolated near Fermi energy. With this gene, the superexchange magnetic interactions mediated by anions could maximize their contributions to superconductivity. Creating the gene requires special arrangements between local electronic structures and crystal lattice structures. The speciality explains why high [Formula: see text] superconductors are so rare. An explicit prediction is made to realize high [Formula: see text] superconductivity in Co/Ni-based materials with a quasi two dimensional hexagonal lattice structure formed by trigonal bipyramidal complexes.

  9. Low-energy physics of high-temperature superconductors

    International Nuclear Information System (INIS)

    Emery, V.J.; Kivelson, S.A.

    1992-01-01

    It is argued that the low-energy properties of high temperature superconductors are dominated by the interaction between the mobile holes and a particular class of collective modes, corresponding to local large-amplitude low-energy fluctuations in the hole density. The latter are a consequence of the competition between the effects of long-range Coulomb interactions and the tendency of a low concentration of holes in an antiferromagnet to phase separate. The low-energy behavior of the system is governed by the same fixed point as the two-channel Kondo problem, which accounts for the ''universality'' of the properties of the cuprate superconductors. Predictions of the optical properties and the spin dynamics are compared with experiment. The pairing resonance of the two Kondo problem gives a mechanism of high temperature superconductivity with an unconventional symmetry of the order parameter

  10. Boundary conditions in Ginsburg Landau theory and critical temperature of high-T superconductors

    Science.gov (United States)

    Lykov, A. N.

    2008-06-01

    New mixed boundary conditions to the Ginsburg-Landau equations are found to limit the critical temperature ( T) of high- T superconductors. Moreover, the value of the pseudogap in these superconductors can be explained by using the method. As a result, the macroscopic approach is proposed to increase T of cuprate superconductors.

  11. Boundary conditions in Ginsburg-Landau theory and critical temperature of high-Tc superconductors

    International Nuclear Information System (INIS)

    Lykov, A.N.

    2008-01-01

    New mixed boundary conditions to the Ginsburg-Landau equations are found to limit the critical temperature (T c ) of high-T c superconductors. Moreover, the value of the pseudogap in these superconductors can be explained by using the method. As a result, the macroscopic approach is proposed to increase T c of cuprate superconductors

  12. Electron spectroscopy on high-temperature superconductors and related compounds

    International Nuclear Information System (INIS)

    Knupfer, M.

    1994-01-01

    In the last two classes of materials have been discovered which distinguish themselves due to a transition into the superconducting state at relatively high temperatures. These are the cuprate superconductors and the alkali metal doped fullerenes. In this work the electronic structure of representatives of these materials, undoped and Ca-doped YBa 2 Cu 4 O 8 and A 3 C 60 (A=K, Rb), has been investigated using electron energy-loss spectroscopy and photoemission spectroscopy. (orig.) [de

  13. Low-Temperature Synthesis Routes to Intermetallic Superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Schaak, Raymond E

    2008-01-08

    Over the past few years, our group has gained expertise at developing low-temperature solution-based synthetic pathways to complex nanoscale solids, with particular emphasis on nanocrystalline intermetallic compounds. Our synthetic capabilities are providing tools to reproducibly generate intermetallic nanostructures with simultaneous control over crystal structure, composition, and morphology. This DOE-funded project aims to expand these capabilities to intermetallic superconductors. This could represent an important addition to the tools that are available for the synthesis and processing of intermetallic superconductors, which traditionally utilize high-temperature, high-pressure, thin film, or gas-phase vacuum deposition methods. Our current knowledge of intermetallic superconductors suggests that significant enhancements could result from the inherent benefits of low-temperature solution synthesis, e.g. metastable phase formation, control over nanoscale morphology to facilitate size-dependent property studies, robust and inexpensive processability, low-temperature annealing and consolidation, and impurity incorporation (for doping, stoichiometry control, flux pinning, and improving the critical fields). Our focus is on understanding the superconducting properties as a function of synthetic route, crystal structure, crystallite size, and morphology, and developing the synthetic tools necessary to accomplish this. This research program can currently be divided into two classes of superconducting materials: intermetallics (transition metal/post transition metal) and metal carbides/borides. Both involve the development and exploitation of low-temperature synthesis routes followed by detailed characterization of structures and properties, with the goal of understanding how the synthetic pathways influence key superconducting properties of selected target materials. Because of the low-temperature methods used to synthesize them and the nanocrystalline morphologies

  14. American superconductor technology to help CERN to explore the mysteries of matter company's high temperature superconductor wire to be used in CERN's Large Hadron Collider

    CERN Multimedia

    2003-01-01

    American Superconductor Corporation has been selected by CERN, to provide 14,000 meters of high temperature superconductor (HTS) wire for current lead devices that will be used in CERN's Large Hadron Collider (1 page).

  15. Processing of bulk Bi-2223 high-temperature superconductor

    Directory of Open Access Journals (Sweden)

    Alexander Polasek

    2005-12-01

    Full Text Available The Bi2Sr2Ca2Cu3 O10+x (Bi-2223 is one of the main high temperature superconductors for applications. One of these applications is the Superconductor Fault Current Limiter (SCFCL, which is a very promising high temperature superconducting device. SCFCL's can be improved by using bulk superconductors with high critical currents, which requires a sufficiently dense and textured material. In the present work, a process for improving the microstructure of Bi-2223 bulk samples is investigated. Pressed precursor blocks are processed by sintering with a further partial melting step, in order to enhance the Bi-2223 grain texture and to healing cracks induced by pressing. In order to improve the microstructure, the precursor is mixed with silver powder before pressing. Samples with and without silver powder have been studied, with the aim of investigating the influence of silver on the microstructure evolution. The phase contents and the microstructure obtained have been analyzed through XRD and SEM/EDS. The electromagnetic characterization has been performed by Magnetic Susceptibility Analysis. We present and discuss the process and the properties of the superconducting blocks. High fractions of textured Bi-2223 grains have been obtained.

  16. The local structure of high-temperature superconductors

    International Nuclear Information System (INIS)

    Mustre de Leon, J.; Conradson, S.D.; Bishop, A.R.; Raistrick, I.D.

    1992-01-01

    We show how x-ray absorption fine structure (XAFS) has been successfully used in the determination of the local crystal structure of high-temperature superconductors, with advantages over traditional diffraction techniques. We review the experimental results that yielded the first evidence for an axial-oxygen-centered lattice instability connected with the superconductivity transition. The interpretation of this instability in terms of a dynamical tunneling model suggests the presence of polarons in these materials. XAFS on Tl 2 Ba 2 CuO 6 and other Tl-based superconductors indicate the presence of local instabilities in the CuO 2 planes of these materials, in addition to axial-oxygen instabilities

  17. Design of High Field Solenoids made of High Temperature Superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Bartalesi, Antonio; /Pisa U.

    2010-12-01

    This thesis starts from the analytical mechanical analysis of a superconducting solenoid, loaded by self generated Lorentz forces. Also, a finite element model is proposed and verified with the analytical results. To study the anisotropic behavior of a coil made by layers of superconductor and insulation, a finite element meso-mechanic model is proposed and designed. The resulting material properties are then used in the main solenoid analysis. In parallel, design work is performed as well: an existing Insert Test Facility (ITF) is adapted and structurally verified to support a coil made of YBa{sub 2}Cu{sub 3}O{sub 7}, a High Temperature Superconductor (HTS). Finally, a technological winding process was proposed and the required tooling is designed.

  18. High-temperature superconductors. Les supraconducteurs a haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Bontemps, N; Combescot, R; Monod, P [Ecole Normale Superieure, 75 - Paris (France)

    1992-02-01

    High-tc superconductivity was discovered in 1986. The prospects of being able to dispose of superconductors cooled by liquid nitrogen instead of liquid helium, and fundamental physics questions raised by these new compounds drag an unprecedented scientific mobilization. Today, the super conductive state nature become clearer. But, to all expectations, their normal state nature is proved to present quite more difficulties. 20 refs., 5 figs.

  19. Temperature dependence of the phonon structure in the high-temperature superconductor Bi2Sr2CaCu2O8 studied by infrared reflectance spectroscopy

    International Nuclear Information System (INIS)

    Kamaras, K.; Herr, S.L.; Porter, C.D.; Tanner, D.B.; Etemad, S.; Tarascon, J.

    1991-01-01

    We have investigated a ceramic sample of the high-temperature superconductor Bi 2 Sr 2 CaCu 2 O 8 (T c =85 K) by infrared and visible reflectance spectroscopy at several temperatures both below and above the superconducting transition. We find that the temperature variation in the vibrational region is associated with minima or antiresonance features of the optical conductivity, instead of maxima, indicating strong Fano-type electron-phonon interaction and implying that the phonon structure in the infrared is strongly affected by the ab-plane response

  20. Superconductors

    CERN Document Server

    Narlikar, A V

    2014-01-01

    Superconductors is neither about basic aspects of superconductivity nor about its applications, but its mainstay is superconducting materials. Unusual and unconventional features of a large variety of novel superconductors are presented and their technological potential as practical superconductors assessed. The book begins with an introduction to basic aspects of superconductivity. The presentation is readily accessible to readers from a diverse range of scientific and technical disciplines, such as metallurgy, materials science, materials engineering, electronic and device engineering, and chemistry. The derivation of mathematical formulas and equations has been kept to a minimum and, wherever necessary, short appendices with essential mathematics have been added at the end of the text. The book is not meant to serve as an encyclopaedia, describing each and every superconductor that exists, but focuses on important milestones in their exciting development.

  1. Metallic substrates for high temperature superconductors

    Science.gov (United States)

    Truchan, Thomas G.; Miller, Dean J.; Goretta, Kenneth C.; Balachandran, Uthamalingam; Foley, Robert

    2002-01-01

    A biaxially textured face-centered cubic metal article having grain boundaries with misorientation angles greater than about 8.degree. limited to less than about 1%. A laminate article is also disclosed having a metal substrate first rolled to at least about 95% thickness reduction followed by a first annealing at a temperature less than about 375.degree. C. Then a second rolling operation of not greater than about 6% thickness reduction is provided, followed by a second annealing at a temperature greater than about 400.degree. C. A method of forming the metal and laminate articles is also disclosed.

  2. Permanent magnets composed of high temperature superconductors

    Science.gov (United States)

    Weinstein, Roy; Chen, In-Gann; Liu, Jay; Lau, Kwong

    1991-01-01

    A study of persistent, trapped magnetic field has been pursued with high-temperature superconducting (HTS) materials. The main effort is to study the feasibility of utilization of HTS to fabricate magnets for various devices. The trapped field, when not in saturation, is proportional to the applied field. Thus, it should be possible to replicate complicated field configurations with melt-textured YBa2Cu3O7 (MT-Y123) material, bypassing the need for HTS wires. Presently, materials have been developed from which magnets of 1.5 T, at 77 K, can be fabricated. Much higher field is available at lower operating temperature. Stability of a few percent per year is readily attainable. Results of studies on prototype motors and minimagnets are reported.

  3. Pairing theory of high and low temperature superconductors

    International Nuclear Information System (INIS)

    Nam, Sang Boo

    1997-01-01

    A scenario which can account for all observed features of both high-Tc superconductors (HTS) and low-Tc superconductors (LTS) is discussed. This scenario is based on the fact that a finite pairing interaction energy range Td is required to have a finite value of Tc and that not all carriers participate in pairings, yielding multiconnected superconductors (MS). A new density of states, derived by keeping the order parameter zero outside of Td, is shown to account for the observed low energy states in HTS and for the temperature dependences in the specific heat, the penetration depth, the optical conductivity, and the tunneling conductance data. I argue that the notion of MS can account for the tunneling data along the a(or b)-, ab-, and c-axis, and the 1/2 flux quantum observed in HTS. The region occupied by unpaired carriers can be considered as a vortex with a fluxoid quantum number equal to 1 (VF), 0 (VZF), or -1 (VAF) when the magnetic flux around the vortex is greater than, equal to, or less than the effective flux produced by the supercurrent, respectively. The Hall anomaly depends on the relative strengths of the contributions via VF and VAF. The fact that the present scenario can account for all observed features of HTS and LTS suggests that the symmetry of the order parameter in HTS may not be different from one in LTS. (author)

  4. Epitaxial heterojunctions of oxide semiconductors and metals on high temperature superconductors

    Science.gov (United States)

    Vasquez, Richard P. (Inventor); Hunt, Brian D. (Inventor); Foote, Marc C. (Inventor)

    1994-01-01

    Epitaxial heterojunctions formed between high temperature superconductors and metallic or semiconducting oxide barrier layers are provided. Metallic perovskites such as LaTiO3, CaVO3, and SrVO3 are grown on electron-type high temperature superconductors such as Nd(1.85)Ce(0.15)CuO(4-x). Alternatively, transition metal bronzes of the form A(x)MO(3) are epitaxially grown on electron-type high temperature superconductors. Also, semiconducting oxides of perovskite-related crystal structures such as WO3 are grown on either hole-type or electron-type high temperature superconductors.

  5. Structural relationships in high temperature superconductors

    International Nuclear Information System (INIS)

    Schuller, I.K.; Segre, C.U.; Hinks, D.G.; Jorgensen, J.D.; Soderholm, L.; Beno, M.; Zhang, K.

    1987-09-01

    The recent discovery of two types of metallic copper oxide compounds which are superconducting to above 90 0 K has renewed interest in the search for new high temperature superconducting materials. It is significant that both classes of compounds, La/sub 2-x/Sr/sub x/CuO/sub 4-y/ and YBa 2 Cu 3 O/sub 7-δ/ are intimately related to the extensively studied perovskite family. Both compounds contain highly oxidized, covalently bonded Cu-O sublattices, however, they differ in geometry. In this paper we discuss the relationship of these features to the superconducting properties. 30 refs., 6 figs

  6. On the critical temperature of superconductors

    International Nuclear Information System (INIS)

    Poon, S.J.

    1975-06-01

    An exact expression for the superconducting transition temperature is derived from the Eliashberg equation at T = T/sub c/ taking the energy gap function in the two-square-well form. The expression is improved for self-consistency by using available tunneling data. It is found to give more restricted values of T/sub c/ than the McMillan equation. The prospects of obtaining high T/sub c/ in alloy systems are discussed within the framework of the new equation. (6 figures, 2 tables) (U.S.)

  7. Electron Sources of the Diode Type with Cathode and Anode of High Temperature Superconductors

    International Nuclear Information System (INIS)

    Korenev, S.A.

    1994-01-01

    The planar electron sources of the diode type with cathode and anode of high temperature superconductors (HTSC) are considered. Explosive emission cathode on the basis of bismuth ceramics (Bi-Ca-Sr-Cu-O) allows forming microsecond pulse (duration > 1 μs) and low energy electron beams (10-25 keV). Tube anode of HTSC in superconducting phase compresses the pulsed electron beam (K = 2-8). It leads to an increase of the beam power density. The high voltage of the generator of Arkad'ev-Marx type (U = 100-600 kV) and the generator with double L C-line are used for experiments. The pulsed method of measuring of the HTSC critical current with the help of pulsed high current electron beam is described. (author). 16 refs., 13 figs

  8. Reproducible, large-scale production of thallium-based high-temperature superconductors

    International Nuclear Information System (INIS)

    Gay, R.L.; Stelman, D.; Newcomb, J.C.; Grantham, L.F.; Schnittgrund, G.D.

    1990-01-01

    This paper reports on the development of a large scale spray-calcination technique generic to the preparation of ceramic high-temperature superconductor (HTSC) powders. Among the advantages of the technique is that of producing uniformly mixed metal oxides on a fine scale. Production of both yttrium and thallium-based HTSCs has been demonstrated using this technique. In the spray calciner, solutions of the desired composition are atomized as a fine mist into a hot gas. Evaporation and calcination are instantaneous, yielding an extremely fine, uniform oxide powder. The calciner is 76 cm in diameter and can produce metal oxide powder at relatively large rates (approximately 100 g/h) without contamination

  9. High temperature resistant cermet and ceramic compositions

    Science.gov (United States)

    Phillips, W. M. (Inventor)

    1978-01-01

    Cermet compositions having high temperature oxidation resistance, high hardness and high abrasion and wear resistance, and particularly adapted for production of high temperature resistant cermet insulator bodies are presented. The compositions are comprised of a sintered body of particles of a high temperature resistant metal or metal alloy, preferably molybdenum or tungsten particles, dispersed in and bonded to a solid solution formed of aluminum oxide and silicon nitride, and particularly a ternary solid solution formed of a mixture of aluminum oxide, silicon nitride and aluminum nitride. Also disclosed are novel ceramic compositions comprising a sintered solid solution of aluminum oxide, silicon nitride and aluminum nitride.

  10. High temperature superconductivity: Concept, preparation and testing of high Tc superconductor compounds, and applications

    International Nuclear Information System (INIS)

    Harara, Wafik

    1992-06-01

    Many studies have been carried out on high temperature superconductors with transition temperature above that of the liquid nitrogen. In this scientific study the concept and the mechanism of this phenomena are discussed, in addition the examples of preparation and testing of high temperature superconductors compounds are shown. Also the most important applications in industry are explained. (author). 15 refs., 2 tabs., 18 figs

  11. Charge ordering phenomena in high temperature superconductors

    International Nuclear Information System (INIS)

    Tassini, Leonardo; Prestel, Wolfgang; Hackl, Rudi; Erb, Andreas; Lambacher, Michael

    2007-01-01

    The electronic Raman effect has been studied in single crystals of Y 1-x Ca x Ba 2 Cu 3 O 6 (Y-123) and La 2-x Sr x CuO 4 (LSCO) at different doping. The experimental results provide evidences of an anomalous contribution to the response at low energies and temperatures. In LSCO the additional excitation is in B 2g symmetry for x = 0.02 and in B 1g symmetry for x = 0.10. In Y-123, we observed the additional feature in B 2g symmetry at 1.5% doping. Mainly on the basis of the selection rules we conclude that the additional peaks are the response of a dynamical charge modulation (stripes) in the two-dimensional CuO 2 planes. The selection rules allow us to determine the orientation of the stripes to be along the diagonal of the CuO 2 planes in Y-123 and LSCO at x = 0.02, and along the principal axes in LSCO at x = 0.10

  12. Ceramics for high temperature applications

    International Nuclear Information System (INIS)

    Mocellin, A.

    1977-01-01

    Problems related to materials, their fabrication, properties, handling, improvements are examined. Silicium nitride and silicium carbide are obtained by vacuum hot-pressing, reaction sintering and chemical vapour deposition. Micrographs are shown. Mechanical properties i.e. room and high temperature strength, creep resistance fracture mechanics and fatigue resistance. Recent developments of pressureless sintered Si C and the Si-Al-O-N quaternary system are mentioned

  13. An investigation of high-temperature irradiation test program of new ceramic materials

    International Nuclear Information System (INIS)

    Ishino, Shiori; Terai, Takayuki; Oku, Tatsuo

    1999-08-01

    The Japan Atomic Energy Research Institute entrusted the Atomic Energy Society of Japan with an investigation into the trend of irradiation processing/damage research on new ceramic materials. The present report describes the result of the investigation, which was aimed at effective execution of irradiation programs using the High Temperature Engineering Test Reactor (HTTR) by examining preferential research subjects and their concrete research methods. Objects of the investigation were currently on-going preliminary tests of functional materials (high-temperature oxide superconductor and high-temperature semiconductor) and structural materials (carbon/carbon and SiC/SiC composite materials), together with newly proposed subjects of, e.g., radiation effects on ceramics-coated materials and super-plastic ceramic materials as well as microscopic computer simulation of deformation and fracture of ceramics. These works have revealed 1) the background of each research subject, 2) its objective and significance from viewpoints of science and engineering, 3) research methodology in stages from preliminary tests to real HTTR irradiation, and 4) concrete HTTR-irradiation methods which include main specifications of test specimens, irradiation facilities and post-irradiation examination facilities and apparatuses. The present efforts have constructed the important fundamentals in the new ceramic materials field for further planning and execution of the innovative basic research on high-temperature engineering. (author)

  14. Flux motion and dissipation in high-temperature superconductors

    International Nuclear Information System (INIS)

    Gray, K.E.; Kim, D.H.

    1991-08-01

    The effects on flux motion and dissipation of interlayer coupling of the Cu-O planes along the c-axis are considered for the high- temperature superconductors (HTS). It is argued that for the highly-anisotropic HTS, the weak interlayer coupling plays a dominant role that can be described by incoherent Josephson tunneling between superconducting Cu-O bi- or tri-layers. In YBa 2 Cu 3 O 7 , the layers are strongly coupled, presumably because the conducting Cu-O chains short circuit the Josephson tunneling, so that these effects are weak or missing

  15. Nickel W14 substrates for high-temperature superconductors

    International Nuclear Information System (INIS)

    Kolb-Telieps, Angelika; Gehrmann, Bodo

    2008-01-01

    High-temperature superconductivity is on the threshold of market launch. Starting from the results of a research project, ThyssenKrupp VDM has successfully developed an industrial-scale production process for nickel W14, which is used as substrate strip in superconductors destined for applications such as generators for wind turbines. The deoxidation of the melt presented a particular challenge. On the one hand, this is required in order to avoid fractures during the hot forming, on the other, the usual deoxidation elements have negative effects on the nanoscale texture and surface roughness needed for the substrate strip. (orig.)

  16. Thermoelectric and thermomagnetic effects in high-temperature superconductors

    International Nuclear Information System (INIS)

    Huebener, R.P.; Ri, H.C.; Gross, R.; Kober, F.

    1992-01-01

    In the mixed state of high-temperature superconductors the dominant part of the Seebeck and Nernst effect is due to the thermal diffusion of quasiparticles and vortices, respectively. The authors' understanding of the Seebeck effect is based on the two-fluid counterflow model of Ginzburg and its extension to the mixed state with the presence of vortices. From the Nernst effect the transport entropy of the vortices is obtained. In this paper summarize the recent thermoelectric and thermomagnetic experiments, paying also attention to the role of the Magnus force (Hall effect) and to the thermal fluctuation effects near T c

  17. Quenched disorder and thermopower fluctuations in high temperature superconductors

    International Nuclear Information System (INIS)

    Khalil, A.E.

    1997-01-01

    Thermopower behavior in high temperature superconductors YBa 2 Cu 3 O 7-δ single crystals near the transition temperature was examined. An expression for the thermoelectric power containing the divergent term (1-T/T c ) -s , where s is a scaling exponent that does not appear in Maki's calculations, was derived. This divergent term is the result of contributions due to the flow of currents across disordered conduction paths in the sample. These currents are driven by the density gradients of the conductivity fluctuations as a result of the increased disorder due to the existence of amorphous regions in the two-dimensional lattice. The present calculations include the most divergent effects to the thermopower due to the conductivity fluctuations near the transition temperature. The model predictions are in good agreement with recent experimental measurements reported in the literature. (orig.)

  18. High-temperature superconductors induced by ion implantation. Final report

    International Nuclear Information System (INIS)

    Greenwald, A.C.; Johnson, E.

    1988-08-01

    High dose oxygen ion implantation (10 to the 17th power ions per sq. cm.) at elevated temperatures (300 C) has been shown to adjust the critical temperature of gamma-Y-Ba-Cu-O and Bi-Ca-Sr-Cu-O materials. These results are in marked contrast to earlier work which showed complete destruction of superconducting properties for similar radiation doses, and marked reduction in superconducting properties at one-tenth this dose in the 1-2-3- compound only. Experiments also showed that the superconducting materials can be patterned into conducting and nonconducting areas without etching by ion implantation, allowing maintenance of planar geometries required for microcircuit fabrication. Experiments on deposition of thin films of high temperature superconductors for use with the ion implantation experiments showed that ion beam sputtering from a single target could achieve the correct stoichiometry. Variations of composition with ion beam energy and angle of sputtered ions were studied

  19. High-temperature superconductors learn from heavy fermions

    International Nuclear Information System (INIS)

    Varma, C.

    1998-01-01

    Physicists have been intrigued by the nature of high-temperature superconductors since they were discovered 12 years ago. Superconducting materials lose their electrical resistance below a transition temperature, T c , and certain copper-oxide compounds remain superconducting at temperatures up to 160 K. Research into these materials has been driven by fundamental, yet intractable, questions about the basic concepts of condensed-matter physics and the mechanisms of superconductivity. A key question is how the electrons come together to form the Cooper pairs responsible for superconductivity. Physicists at Cambridge University have now studied two heavy-fermion compounds experimentally, and have found that the electron pairing is caused by magnetic effects (N Mathur et al. 1998 Nature 394 39). In this article the author describes their research. (UK)

  20. Advanced technologies related to a high temperature superconductor for small laboratory experiments

    International Nuclear Information System (INIS)

    Ogawa, Yuichi; Mito, Toshiyuki; Yanagi, Nagato

    2006-01-01

    Advanced technologies related to a high temperature superconductor materials and small refrigerator are reviewed. Mini-RT/RT-1 is designed and constructed as a plasma examination device. The element technology of low temperature apparatus, the results of performance tests and application examples are explained. The superconductors such as Bi 2 Sr 2 CaCu 2 O 8 (Bi-2212) for the low temperature phase, Bi 2 Sr 2 Ca 2 Cu 3 O 10 (Bi-2223) for the high temperature phase, and YBa 2 Cu 3 O y (YBCO or Y123) are described. Advanced 4K-Giford-Mcmahon (GM) refrigerator on the market put superconductor coil made of low temperature superconductor metals to practical use and extends its application field. Small laboratory is able to experiment on the high temperature superconductor materials. (S.Y.)

  1. XES studies of density of states of high temperature superconductors

    Science.gov (United States)

    Jasiolek, Gabriel

    1991-01-01

    X-ray emission spectroscopic studies concerning the superconducting crystals, thin films, and ceramics of the Y-Ba-Cu-O, Tm-Ba-Cu-O, Bi-Sr-Ca-Cu-O, Bi-Pb-Sr-Ca-Cu-O, and Tl-Ba-Ca-Cu-O types are presented. The contributions of the 13d(9)L, 13d(10)L, 13d(10)LL, and 13d(10)L(2) configurations, where L denotes a ligand hole at the oxygen orbitals in the spectroscopic pattern of these superconductors are discussed. An attempt to connect the x-ray 'as registered' Cu L(alpha) emission spectra with the density of states close to the Fermi level, considering an influence of the CuL3 absorption edge, is presented. The corrected intensity distributions below the Fermi level are found to correspond to the theoretical density of states. Furthermore, an approach to the average valence of copper basing on the account of the self-absorption and fluorescence effects and on the configurations listed above is shown. The average valence of copper in the materials investigated is estimated to lie in the range of +2.10 to 2.32 when the formal trivalent copper is considered as that characterized by the 13d(9)L configuration. The density of states at the Fermi level was estimated to be 2.4 states/eV-cell for a Bi-Sr-Ca-Cu-O crystal and 3.6 states/eV-cell for a Tl-Ba-Ca-CU-O ceramic.

  2. Electron-beam damaged high-temperature superconductor Josephson junctions

    International Nuclear Information System (INIS)

    Pauza, A.J.; Booij, W.E.; Herrmann, K.; Moore, D.F.; Blamire, M.G.; Rudman, D.A.; Vale, L.R.

    1997-01-01

    Results are presented on the fabrication and characterization of high critical temperature Josephson junctions in thin films of YBa 2 Cu 3 O 7-δ produced by the process of focused electron-beam irradiation using 350 keV electrons. The junctions so produced have uniform spatial current densities, can be described in terms of the resistive shunted junction model, and their current densities can be tailored for a given operating temperature. The physical properties of the damaged barrier can be described as a superconducting material of either reduced or zero critical temperature (T c ), which has a length of ∼15nm. The T c reduction is caused primarily by oxygen Frenkel defects in the Cu - O planes. The large beam currents used in the fabrication of the junctions mean that the extent of the barrier is limited by the incident electron-beam diameter, rather than by scattering within the film. The properties of the barrier can be calculated using a superconductor/normal/superconductor (SNS) junction model with no boundary resistance. From the SNS model, we can predict the scaling of the critical current resistance (I c R n ) product and gain insight into the factors controlling the junction properties, T c , and reproducibility. From the measured I c R n scaling data, we can predict the I c R n product of a junction at a given operating temperature with a given current density. I c R n products of ∼2mV can be achieved at 4.2 K. The reproducibility of several junctions in a number of samples can be characterized by the ratio of the maximum-to-minimum critical currents on the same substrate of less than 1.4. Stability over several months has been demonstrated at room and refrigerator temperatures (297 and 281 K) for junctions that have been initially over damaged and then annealed at temperatures ∼380K. (Abstract Truncated)

  3. Flux motion and dissipation in high-temperature superconductors

    International Nuclear Information System (INIS)

    Gray, K.E.; Kim, D.H.

    1991-01-01

    The effects on flux motion and dissipation of interlayer coupling of the Cu-O planes along the c-axis are considered for the high-temperature superconductors (HTS). It is argued that for the highly-anisotropic HTS, the weak interlayer coupling plays a dominant role that can be described by incoherent Josephson tunneling between superconducting Cu-O bi- or tri-layers. In YBa 2 Cu 3 O 7 , the layers are strongly coupled, presumably because the conducting Cu-O chains short circuit the Josephson tunneling, so that these effects are weak or missing. Recently, the effects of anisotropy and fluctuations on critical current densities, J c (T,H) and the field-induced broadening of resistivity transitions, ρ(T,H), have been studied in high-temperature superconductors (HTS). Although the broadening looks similar for the applied field, H, oriented either parallel to the superconducting Cu-O layers (H parallel ab) or parallel to the c-axis (H parallel c), its width and the detailed shape of ρ(T,H) are different. The explanations given in this paper for the highly anisotropic HTS differ in detail for the two cases, but have a crucial feature in common: they result from fluctuations affecting the Josephson coupling across the interlayer junctions

  4. Design study of SMES system using high temperature superconductors

    International Nuclear Information System (INIS)

    Yoshihara, T.; Masuda, M.; Shintomi, T.; Hasegawa, J.

    1988-01-01

    Various studies of high Tc superconductors are being energetically pursued all over the world, since IBM Zurich Research Laboratory reported on the superconducting oxide. A new design using a high Tc superconductor is under study for 5000 MWh, on the assumption that it is available like conventional superconductors. Problems related to the Tc SMES system, mainly thermal insulation, refrigeration system, stability of superconductors, etc., are considered. Some design examples of high Tc SMES system are proposed

  5. Single Crystal Synthesis and STM Studies of High Temperature Superconductors

    Science.gov (United States)

    Barrientos, Alfonso

    1997-01-01

    This is a final report for the work initiated in September of 1994 under the grant NAG8-1085 - NASA/OMU, on the fabrication of bulk and single crystal synthesis, specific heat measuring and STM studies of high temperature superconductors. Efforts were made to fabricate bulk and single crystals of mercury based superconducting material. A systematic thermal analysis on the precursors for the corresponding oxides and carbonates were carried out to synthesized bulk samples. Bulk material was used as seed in an attempt to grow single crystals by a two-step self flux process. On the other hand bulk samples were characterized by x-ray diffraction, electrical resistivity and magnetic susceptibility, We studied the specific heat behavior in the range from 80 to 300 K. Some preliminary attempts were made to study the atomic morphology of our samples. As part of our efforts we built an ac susceptibility apparatus for measuring the transition temperature of our sintered samples.

  6. Dynamics of the vortex state in high temperature superconductors

    International Nuclear Information System (INIS)

    Kapitulnik, A.

    1991-01-01

    The large thermal energy available, the strong anisotropy, and short coherence lengths of high temperature superconductors give rise to new phenomena in the mixed state. The author discusses transport and thermodynamic measurements of high-Tc materials and of model systems. In particular, he uses experiments on two dimensional films to compare and isolate two dimensional effects in the cuprates. By using multilayer systems with similar parameters, he identifies decoupling of the superconducting planes in magnetic fields at temperatures much above the irreversibility line. He shows that if the irreversibility line is to be considered a melting transition line, it implies melting of the solid state into a liquid of three dimensional flux lines. He further uses Monte Carlo simulations to study the structure of the vortex state as well as melting

  7. Applications of high-temperature superconductors in power technology

    International Nuclear Information System (INIS)

    Hull, John R

    2003-01-01

    Since the discovery of the first high-temperature superconductors (HTSs) in the late 1980s, many materials and families of materials have been discovered that exhibit superconductivity at temperatures well above 20 K. Of these, several families of HTSs have been developed for use in electrical power applications. Demonstration of devices such as motors, generators, transmission lines, transformers, fault-current limiters, and flywheels in which HTSs and bulk HTSs have been used has proceeded to ever larger scales. First-generation wire, made from bismuth-based copper oxides, was used in many demonstrations. The rapid development of second-generation wire, made by depositing thin films of yttrium-based copper oxide on metallic substrates, is expected to further accelerate commercial applications. Bulk HTSs, in which large single-grain crystals are used as basic magnetic components, have also been developed and have potential for electrical power applications

  8. Charge redistribution and properties of high-temperature superconductors

    International Nuclear Information System (INIS)

    Khomskii, D.I.; Kusmartsev, F.V.

    1992-01-01

    We show that in high-T c superconductors (HTSC) with two groups of electrons (e.g., holes in CuO 2 planes and in a ''reservoir'') there should exist a charge redistribution with the temperature: the hole concentration N h in ''active'' superconducting CuO 2 planes increases below T c . This effect may explain structural changes such as the shift of the apical oxygen atom, anomalous thermal expansion, the shift of nuclear quadrupole resonance lines, the change of the positron lifetime, and the modification of the ion channeling below T c . Some other possible consequences of the charge redistribution (the modification of the temperature dependence of a gap Δ and of the ratio 2Δ 0 /T c , the phenomena at a contact of HTSC with normal metals and semiconductors) are discussed

  9. Two classes of superconductors discovered in our material research: Iron-based high temperature superconductor and electride superconductor

    International Nuclear Information System (INIS)

    Hosono, Hideo

    2009-01-01

    We discovered two new classes of superconductors in the course of material exploration for electronic-active oxides. One is 12CaO . 7Al 2 O 3 crystal in which electrons accomodate in the crystallographic sub-nanometer-sized cavities. This material exhibiting metal-superconductor transition at 0.2 K is the first electride superconductor. The other is iron oxypnicitides with a layered structure. This superconductor is rather different from high T c cuprates in several respects. The high T c is emerged by doping carriers to the metallic parent phases which undergo crystallographic transition (tetra to ortho) and Pauli para to antiferromagnetic transition at ∼150 K. The T c is robust to impurity doping to the Fe sites or is induced by partial substitution of the Fe 2+ sites with Co 2+ or Ni 2+ . This article gives a brief summary of these discoveries and recent advances.

  10. Ceramic membranes for high temperature hydrogen separation

    Energy Technology Data Exchange (ETDEWEB)

    Fain, D.E.; Roettger, G.E. [Oak Ridge K-25 Site, TN (United States)

    1996-08-01

    Ceramic gas separation membranes can provide very high separation factors if the pore size is sufficiently small to separate gas molecules by molecular sieving and if oversized pores are adequately limited. Ceramic membranes typically have some pores that are substantially larger than the mean pore size and that should be regarded as defects. To assess the effects of such defects on the performance of ceramic membranes, a simple mathematical model has been developed to describe flow through a gas separation membrane that has a primary mode of flow through very small pores but that has a secondary mode of flow through undesirably large pores. This model permits separation factors to be calculated for a specified gas pair as a function of the molecular weights and molecular diameters of the gases, the membrane pore diameter, and the diameter and number of defects. This model will be described, and key results from the model will be presented. The separation factors of the authors membranes continue to be determined using a permeance test system that measures flows of pure gases through a membrane at temperatures up to 275{degrees}C. A primary goal of this project for FY 1996 is to develop a mixed gas separation system for measuring the separation efficiency of membranes at higher temperatures. Performance criteria have been established for the planned mixed gas separation system and design of the system has been completed. The test system is designed to measure the separation efficiency of membranes at temperatures up to 600{degrees}C and pressures up to 100 psi by separating the constituents of a gas mixture containing hydrogen. The system will accommodate the authors typical experimental membrane that is tubular and has a diameter of about 9 mm and a length of about 23 cm. The design of the new test system and its expected performance will be discussed.

  11. Studies of nonlinear electrodynamics of high-temperature superconductors

    International Nuclear Information System (INIS)

    Lam, Q.H.

    1991-01-01

    Nonlinear electrodynamics of high-Tc superconductors are studied theoretically and experimentally. For powdered samples, a novel model is presented in which the metallographically observed superconducting grains in the powder are modeled as superconducting current loops of various areas with weak links. Surprising harmonic generation behavior in an ac field, H 1 cos(ωt), is predicted by the model; the power at high harmonics show sharp dips almost periodic in a super-posing dc magnetic field, revealing flux quantization in the prototype loops in the model. Such oscillation of the harmonic power in dc magnetic field, P nf (H dc ), is experimentally observed in powdered YBa 2 Cu 3 O 7 . For bulk sintered cylindrical samples, a generalized critical state model is presented. The nonlinear electrodynamics are due to flux-pinning. Experiments in ac and dc magnetic fields on a sintered cylindrical rod of YBa 2 Cu 3 O 7 yield unambiguous evidence of independent inter- and intragranular contributions to the complex harmonic permeability μ n = μ' n - iμ double-prime n . These data, together with P nf (H dc ), are explained quantitatively by the generalized critical state model, yielding a dependence on magnetic field of J c (H) ∼ H 02 local for the intergranular component, a steeper field dependence than for conventional type-II superconductors. Temperature-dependence measurements reveal that, while the intragranular supercurrents disappear at T c ≥ 91.2 K, the intergranular supercurrents disappear at T ≥ 86.6 K

  12. High temperature ceramic-tubed reformer

    Science.gov (United States)

    Williams, Joseph J.; Rosenberg, Robert A.; McDonough, Lane J.

    1990-03-01

    The overall objective of the HiPHES project is to develop an advanced high-pressure heat exchanger for a convective steam/methane reformer. The HiPHES steam/methane reformer is a convective, shell and tube type, catalytic reactor. The use of ceramic tubes will allow reaction temperature higher than the current state-of-the-art outlet temperatures of about 1600 F using metal tubes. Higher reaction temperatures increase feedstock conversion to synthesis gas and reduce energy requirements compared to currently available radiant-box type reformers using metal tubes. Reforming of natural gas is the principal method used to produce synthesis gas (primarily hydrogen and carbon monoxide, H2 and CO) which is used to produce hydrogen (for refinery upgrading), methanol, as well as several other important materials. The HiPHES reformer development is an extension of Stone and Webster's efforts to develop a metal-tubed convective reformer integrated with a gas turbine cycle.

  13. Status of high temperature superconductor cable and fault current limiter projects at American Superconductor

    International Nuclear Information System (INIS)

    Maguire, J.F.; Yuan, J.

    2009-01-01

    This paper will describe the status of three key programs currently underway at American Superconductor Corp. The first program is the LIPA project which is a transmission voltage high temperature superconducting cable program, with funding support from the US Department of Energy. The 600 m cable, capable of carrying 574 MVA, was successfully installed and commissioned in LIPA grid on April 22, 2008. An overview of the project, system level design details and operational data will be provided. In addition, the status of the newly awarded LIPA II project will be described. The second program is Project Hydra, with funding support from the US Department of Homeland Security, to design, develop and demonstrate an HTS cable with fault current limiting functionality. The cable is 300 m long and is being designed to carry 96 MVA at a distribution level voltage of 13.8 kV. The cable will be permanently installed and energized in Manhattan, New York in 2010. The initial status of Project Hydra will be presented. The final program to be discussed is a transmission voltage, high temperature superconducting fault current limiter funded by the US DOE. The project encompasses the design, construction and test of a 115 kV FCL for power transmission within a time frame of 4-5 years. Installation and testing are planned for a Southern California Edison substation. A project overview and progress under the first phase will be reported.

  14. Status of high temperature superconductor cable and fault current limiter projects at American Superconductor

    Energy Technology Data Exchange (ETDEWEB)

    Maguire, J.F., E-mail: jmaguire@amsc.co [American Superconductor Co., 64 Jackson Road, Devens, MA 01434 (United States); Yuan, J. [American Superconductor Co., 64 Jackson Road, Devens, MA 01434 (United States)

    2009-10-15

    This paper will describe the status of three key programs currently underway at American Superconductor Corp. The first program is the LIPA project which is a transmission voltage high temperature superconducting cable program, with funding support from the US Department of Energy. The 600 m cable, capable of carrying 574 MVA, was successfully installed and commissioned in LIPA grid on April 22, 2008. An overview of the project, system level design details and operational data will be provided. In addition, the status of the newly awarded LIPA II project will be described. The second program is Project Hydra, with funding support from the US Department of Homeland Security, to design, develop and demonstrate an HTS cable with fault current limiting functionality. The cable is 300 m long and is being designed to carry 96 MVA at a distribution level voltage of 13.8 kV. The cable will be permanently installed and energized in Manhattan, New York in 2010. The initial status of Project Hydra will be presented. The final program to be discussed is a transmission voltage, high temperature superconducting fault current limiter funded by the US DOE. The project encompasses the design, construction and test of a 115 kV FCL for power transmission within a time frame of 4-5 years. Installation and testing are planned for a Southern California Edison substation. A project overview and progress under the first phase will be reported.

  15. Status of high temperature superconductor cable and fault current limiter projects at American Superconductor

    Science.gov (United States)

    Maguire, J. F.; Yuan, J.

    2009-10-01

    This paper will describe the status of three key programs currently underway at American Superconductor Corp. The first program is the LIPA project which is a transmission voltage high temperature superconducting cable program, with funding support from the US Department of Energy. The 600 m cable, capable of carrying 574 MVA, was successfully installed and commissioned in LIPA grid on April 22, 2008. An overview of the project, system level design details and operational data will be provided. In addition, the status of the newly awarded LIPA II project will be described. The second program is Project Hydra, with funding support from the US Department of Homeland Security, to design, develop and demonstrate an HTS cable with fault current limiting functionality. The cable is 300 m long and is being designed to carry 96 MVA at a distribution level voltage of 13.8 kV. The cable will be permanently installed and energized in Manhattan, New York in 2010. The initial status of Project Hydra will be presented. The final program to be discussed is a transmission voltage, high temperature superconducting fault current limiter funded by the US DOE. The project encompasses the design, construction and test of a 115 kV FCL for power transmission within a time frame of 4-5 years. Installation and testing are planned for a Southern California Edison substation. A project overview and progress under the first phase will be reported.

  16. Impact of high temperature superconductors on the possibility of radio-frequency confinement

    International Nuclear Information System (INIS)

    Dean, S.O.

    1989-01-01

    Recent discoveries of superconducting materials that operate at high temperatures may have both technical and economic consequences for magnetic confinement fusion. In addition, they could also open up the possibility of plasma confinement by radio-frequency fields. The new, high temperature superconductors may impact the feasibility of rf confinement in two important ways: (1) higher temperature superconductors should have higher critical B fields and consequently may allow higher critical electric fields to be sustained in the cavity, thus allowing the necessary confining pressure to be achieved; and (2) the higher temperature superconductors lower the refrigeration power necessary to maintain the superconducting cavity, thus allowing a favorable energy balance

  17. Superconductors with low critical temperature for electro-magnets

    International Nuclear Information System (INIS)

    Devred, A.

    2002-07-01

    Among the superconductors with low critical temperature that are used to build magnets, NbTi has reached a development state that allows a massive production for big equipment of physics and an industrial production in the domain of medicine imaging. The material that might challenge the supremacy of NbTi is Nb 3 Sn but some technical difficulties have yet to be overcome. This report begins with a review of the different industrial processes used to produce superconducting wires based on the NbTi and Nb 3 Sn materials. The transition from the superconducting state to the resistive normal state is described for both materials, the magnetizing of multi-wire superconducting cables is also presented. The author details the different patterns of wires in cables and proposes a formulary that allows the determination, in some simple cases,of energy losses that are generated in a superconducting cable by a variable magnetic field. (A.C.)

  18. Interlayer vortices and edge dislocations in high-temperature superconductors

    International Nuclear Information System (INIS)

    Kuklov, A.B.; Krakovsky, A.; Birman, J.L.

    1995-01-01

    The interaction of an edge dislocation made of half the superconducting plane with a magnetic interlayer vortex is considered within the framework of the Lawrence-Doniach model with negative as well as positive Josephson interlayer coupling. In the first case the binding energy of the vortex and the dislocation has been calculated by employing a variational procedure. The current distribution around the bound vortex turns out to be asymmetric. In the second case the dislocation carries a spontaneous magnetic half vortex, whose binding energy with the dislocation turns out to be infinite. The half-vortex energy has been calculated by the same variational procedure. Implications of the possible presence of such half vortices for the properties of high-temperature sueprconductors are discussed. We suggest employing artificially made superconductor-ferromagnet superlattices with the half plane removed to observe fractional vortices

  19. Microstructure and Properties of High-Temperature Superconductors

    CERN Document Server

    Parinov, Ivan A

    2007-01-01

    The main features of high-temperature superconductors (HTSC) that define their properties are intrinsic brittleness of oxide cuprates, the layered anisotropic structure and the supershort coherence length. Taking into account these features, this treatise presents research into HTSC microstructure and properties, and also explores the possibilities of optimization of the preparation techniques and superconducting compositions. The "composition-technique-experiment-theory-model," employed here, assumes considerable HTSC defectiveness and structure heterogeneity and helps to draw a comprehensive picture of modern representations of the microstructure, strength and the related structure-sensitive properties of the materials considered. Special attention is devoted to the Bi-Sr-Ca-Cu-O and Y-Ba-Cu-O families, which currently offer the most promising applications. Including a great number of illustrations and references, this monograph addresses students, post-graduate students and specialists, taking part in the ...

  20. Microstructure and Properties of High-Temperature Superconductors

    CERN Document Server

    Parinov, I A

    2012-01-01

    The main features of high-temperature superconductors (HTSC) that define their properties are intrinsic brittleness of oxide cuprates, the layered anisotropic structure and the supershort coherence length. Taking into account these features, this treatise presents research into HTSC microstructure and properties, and also explores the possibilities of optimization of the preparation techniques and superconducting compositions. The "composition-technique-experiment-theory-model," employed here, assumes considerable HTSC defectiveness and structure heterogeneity and helps to draw a comprehensive picture of modern representations of the microstructure, strength and the related structure-sensitive properties of the materials considered. Special attention is devoted to the Bi-Sr-Ca-Cu-O and Y-Ba-Cu-O families, which currently offer the most promising applications. Including a great number of illustrations and references, this monograph addresses students, post-graduate students and specialists, taking part in the ...

  1. Engineering design of a high-temperature superconductor current lead

    International Nuclear Information System (INIS)

    Niemann, R.C.; Cha, Y.S.; Hull, J.R.; Daugherty, M.A.; Buckles, W.E.

    1993-01-01

    As part of the US Department of Energy's Superconductivity Pilot Center Program, Argonne National Laboratory and Superconductivity, Inc., are developing high-temperature superconductor (HTS) current leads suitable for application to superconducting magnetic energy storage systems. The principal objective of the development program is to design, construct, and evaluate the performance of HTS current leads suitable for near-term applications. Supporting objectives are to (1) develop performance criteria; (2) develop a detailed design; (3) analyze performance; (4) gain manufacturing experience in the areas of materials and components procurement, fabrication and assembly, quality assurance, and cost; (5) measure performance of critical components and the overall assembly; (6) identify design uncertainties and develop a program for their study; and (7) develop application-acceptance criteria

  2. Flux motion and dissipation in high temperature superconductors

    International Nuclear Information System (INIS)

    Tinkham, M.

    1991-01-01

    Two quite different motivations spark the study of flux motion and resistance in the new high-temperature superconductors. Achievement of usefully low resistance at usefully large current densities is the key to most practical applications, but conceptual understanding of the idealized resistive behavior in the O current limit motivates much theoretical work. Some analyses emphasize the pinning of individual flux lines to inhomogeneities in the underlying material; others emphasize the collective aspects of the interacting flux lines, whether liquid, solid, crystalline, or glassy; still others emphasize the concept of percolative Josephson coupling between grains. In this paper an overview is given of these various approaches, their interrelation, and the experiment evidence, including some new results on flux motion in large SNS arrays, treated as a model system

  3. Engineering design of a high-temperature superconductor current lead

    Science.gov (United States)

    Niemann, R. C.; Cha, Y. S.; Hull, J. R.; Daugherty, M. A.; Buckles, W. E.

    As part of the US Department of Energy's Superconductivity Pilot Center Program, Argonne National Laboratory and Superconductivity, Inc., are developing high-temperature superconductor (HTS) current leads suitable for application to superconducting magnetic energy storage systems. The principal objective of the development program is to design, construct, and evaluate the performance of HTS current leads suitable for near-term applications. Supporting objectives are to (1) develop performance criteria; (2) develop a detailed design; (3) analyze performance; (4) gain manufacturing experience in the areas of materials and components procurement, fabrication and assembly, quality assurance, and cost; (5) measure performance of critical components and the overall assembly; (6) identify design uncertainties and develop a program for their study; and (7) develop application-acceptance criteria.

  4. Irradiation effects of high temperature superconductor of lanthanoid oxides

    Energy Technology Data Exchange (ETDEWEB)

    Ueda, Koh-ichi; Kohara, Takao [Himeji Inst. of Tech., Hyogo (Japan)

    1996-04-01

    Neutron irradiation effects on excess oxygen were studied by neutron irradiation on La{sub 2}CuO{sub 4} treated with high pressure oxygen. La{sub 2}CuO{sub 4} was prepared by the usual method and annealed for 10 h under the oxygen pressure of 800-2000 atm. at 600degC. The superconducting transition temperature (Tc) is 27-32K before irradiation (La{sub 2}CuO{sub 4+d}, amount of excess oxygen d=0.03-0.12). Neutron irradiation was carried out by two kinds of experiments. Low irradiation dose test at low temperature (LTL: {approx}20-200K, storage in LN{sub 2}) showed Tc decreased more slowly than that of high temperature range. Experiment at high temperature (Hyd:{approx}80deg{yields}, storage at room temperature) showed -10K/10{sup 18}n/cm{sup 2}, the decrease of Tc was three times larger than that of YBCO type superconductor. (S.Y.)

  5. Superconductors: The long road ahead

    International Nuclear Information System (INIS)

    Foner, S.; Orlando, T.P.

    1988-01-01

    Before the discovery of high-temperature superconductors, progress in superconductivity was measured by quite small increases in critical temperature, often of less than one degree. Today, there is no reason to believe that the dramatic leaps in critical temperature inaugurated by superconducting ceramics are over. Researchers may find new high-temperature superconducting materials with less severe technical limitations than the ceramics we know today. And if the day ever comes when a superconductor can be reliably manufactured to operate effectively at room temperature, then superconductors will be incorporated in a broad range of everyday household devices - motors, appliances, even children's toys - with a large consumer market. High-temperature superconductors may also cause us to extensively revise our traditional theories about how superconductivity works. Should it run out that superconductivity in ceramics involves new physical mechanisms, then these mechanisms could lead to applications never considered before. The recent discoveries have already reinvigorated superconductivity research. What was once largely the domain of a relatively small group of scientists has become a genuinely multidisciplinary realm. Now physicists, materials scientists, chemists, metallurgists, ceramists, and solid-state electronics engineers are all focusing on superconductivity. The cross-fertilization of these disciplines should contribute to further discoveries of importance to the practical application of superconductors

  6. Critical transport current in granular high temperature superconductors

    International Nuclear Information System (INIS)

    Bogolyubov, N.A.

    1999-01-01

    The temperature and size dependence of the critical current in a zero magnetic field of three bismuth-based ceramic samples with round cross section and one sample with rectangular triangle cross section have been studied by a contactless technique. It is shown that the critical current can be presented as a product of the temperature and size dependent factors. The temperature-dependent multiplier reflects the individual peculiarities of the Josephson net of each sample, while the size factor is a homogeneous function of the cross-section sizes. The index of this function is independent of the cross-section form, the temperature and individual properties of HTSC samples. The radial distribution of critical current density in round samples and dependence of the critical current density on the magnetic conduction in granular HTSC have been found from the analysis of experimental data

  7. High temperature resistive phase transition in A15 high temperature superconductors

    International Nuclear Information System (INIS)

    Chu, C.W.; Huang, C.Y.; Schmidt, P.H.; Sugawara, K.

    1976-01-01

    Resistive measurements were made on A15 high temperature superconductors. Anomalies indicative of a phase transition were observed at 433 0 K in a single crystal Nb 3 Sn and at 485 0 K in an unbacked Nb 3 Ge sputtered thin film. Results are compared with the high temperature transmission electron diffraction studies of Nb 3 Ge films by Schmidt et al. A possible instability in the electron energy spectrum is discussed

  8. Low temperature X-ray imaging of magnetic flux patterns in high temperature superconductors

    Science.gov (United States)

    Stahl, Claudia; Ruoß, Stephen; Weigand, Markus; Bechtel, Michael; Schütz, Gisela; Albrecht, Joachim

    2015-05-01

    We present X-ray magnetic circular dichroism (XMCD) microscopy results obtained at liquid nitrogen temperatures on the high-Tc superconductor YBCO (YBa2Cu3O7-δ). The magnetic flux distribution arising from electric currents in the superconductor is detected and visualized using soft-magnetic Co40Fe40B20 (CoFeB) as sensor layer and XMCD as contrast mechanism. It has been shown that the XMCD contrast in the sensor layer directly corresponds to magnetic flux distribution of the superconductor and hence can be used to image magnetic structures in superconductors [Stahl et al., Phys. Rev. B 90, 104515 (2014)]. The existing scanning UHV X-ray microscopy setup MAXYMUS at the synchrotron BESSY II in Berlin has been upgraded for that purpose: we use a nitrogen based MMR Micro Miniature Joule-Thompson Cryostat with temperature range from 75 K to 580 K. The capability of the method is demonstrated on two different superconducting samples, an optimally doped thin film and a melt-textured block.

  9. Testing and evaluation of high temperature superconductor current leads

    International Nuclear Information System (INIS)

    Yadav, Anand; Puntambekar, Avinash; Manekar, M.A.

    2009-01-01

    National Institute for Inter-disciplinary Science and Technology (NIIST), Council of Scientific and Industrial Research, Trivandrum (formerly Regional Research Laboratory) has accomplished a DAE-BRNS project with Raja Ramanna Centre for Advanced Technology (RRCAT) as principal collaborator for the development of high temperature superconductor (HTS) current leads. These HTS current leads have self-field critical currents (Ic) ranging from 50 A to 1000 A at liquid nitrogen (LN 2 ) temperature. These HTS are made out of silver sheathed Bismuth Strontium Calcium Copper Oxide (BSCCO-2223), for direct application in superconducting (SC) systems involving transportation of high electric currents from power sources at room temperature to superconducting devices at cryogenic temperatures. RRCAT has participated in this project by testing and evaluation of these HTS current leads and carried out actual load trials. In this paper, we will describe the HTS testing setup, tests performed with their testing procedure and the test results. The testing of these HTS has been done with joint effort of Materials Advanced Accelerator Science and Cryogenics Div. and Superconducting Technology Lab (SCT Lab), Advanced Accelerator Module Development Div., using the test facility available at the SCT Lab. (author)

  10. Transport properties of Pb-doped Bi4Sr3Ca3Cu4Ox semiconducting glasses and glass-ceramic superconductors

    International Nuclear Information System (INIS)

    Chatterjee, S.; Banerjee, S.; Mollah, S.; Chaudhuri, B.K.

    1996-01-01

    Electrical conductivity and thermoelectric power (TEP) of the as-quenched and annealed (at 500 degree C for 10 h and 840 degree C for 24 h) Bi 4-n Pb n Sr 3 Ca 3 Cu 4 O x (x = 0 endash 1.0) glasses have been measured. The dc conductivity data of the as-quenched and the partially annealed (at 500 degree C) glasses can be explained by considering the small-polaron hopping conduction mechanism which is found to change from the nonadiabatic to the adiabatic regime with annealing the glasses at 500 degree C. This change over is due to the presence of microcrystals in the partially annealed glasses as observed from x-ray-diffraction and scanning electron microscopic studies. This adiabatic behavior is also visualized even for some as-quenched glasses having a very small amount of the more conducting microcrystalline phase. All the 840 degree C annealed glasses are superconductors with T c between 110 and 115 K. The Seebeck coefficient (S) of the partially annealed glass system is found to be positive and increases linearly with temperature. The S values of the corresponding glass-ceramic superconductors showing broad peaks around T c . A change over in the values of S from positive (below ∼290 K) to negative (above ∼290 K) indicates the coexistence of both electrons and holes in these superconductors. The TEP data can be fitted with both the two-band model of Forro et al. [Solid State Commun. 73, 501 (1990)] and the Nagaosa-Lee model [Phys. Rev. Lett. 64, 2450 (1990)]. Therefore, the bosonic contribution in the transport properties of these superconductors, as suggested by the Nagaosa-Lee model, is supported. copyright 1996 The American Physical Society

  11. Surface electrostatic waves in bounded high temperature superconductors

    International Nuclear Information System (INIS)

    Averkov, Yu.O.; Yakovenko, V.M.

    2008-01-01

    The dispersion relations of surface electrostatic waves propagating along the surface of semi bounded layered superconductor and in the slab of layered superconductor are theoretically investigated. An arbitrary inclination of superconductor layers to the interface of a vacuum - crystal and an arbitrary direction of propagation of surface waves in the plane of the interface are taking into account. The possibility of initiation of an absolute instability during the propagation of a non-relativistic plasma stream above the surface of the layered superconductor is shown

  12. ASM Inaugural Lecture 2009: High temperature superconductors: Materials, mechanisms and applications

    International Nuclear Information System (INIS)

    Roslan Abdul Shukor

    2009-01-01

    A surprising variety of new superconducting materials has been discovered in recent years. Many compounds with light elements such as fullerenes, oxides, borides, nitrides, some organic materials and also heavy fermions have been found to superconductor at various temperatures. Hitherto, superconductors have proven to be highly varied in composition but elusive and mysterious. The juxtaposition of superconductivity and magnetism at the nano scale in some of these new materials has paved the way to a rich and exciting new field in condensed matter and materials research. An overview of superconductor research in Malaysian institutions is presented in this paper. Some of the new superconducting materials and their possible mechanisms, conventional and exotic, are presented. The possible role of lattice vibrations in the mechanisms of high temperature superconductivity and the study of this via acoustic methods are discussed. Frozen flux superconductors in a nano magnet-superconductor hybrid system are also discussed. (author)

  13. Mottness in high-temperature copper-oxide superconductors

    International Nuclear Information System (INIS)

    Phillips, Philip; Choy, T.-P.; Leigh, Robert G

    2009-01-01

    The standard theory of metals, Fermi liquid theory, hinges on the key assumption that although the electrons interact, the low-energy excitation spectrum stands in a one-to-one correspondence with that of a non-interacting system. In the normal state of the copper-oxide high-temperature superconductors, drastic deviations from the Fermi liquid picture are obtained, highlighted by a pseudogap, broad spectral features and T-linear resistivity. A successful theory in this context must confront the highly constraining scaling argument which establishes that all 4-Fermi interactions are irrelevant (except for pairing) at a Fermi surface. This argument lays plain that new low-energy degrees of freedom are necessary. This paper focuses on the series of experiments on copper-oxide superconductors which reveal that the number of low-energy addition states per electron per spin exceeds unity, in direct violation of the key Fermi liquid tenet. These experiments point to new degrees of freedom, not made out of the elemental excitations, as the key mechanism by which Fermi liquid theory breaks down in the cuprates. A recent theoretical advance which permits an explicit integration of the high-energy scale in the standard model for the cuprates reveals the source of the new dynamical degrees of freedom at low energies, a charge 2e bosonic field which has nothing to do with pairing but rather represents the mixing with the high-energy scales. We demonstrate explicitly that at half-filling, this new degree of freedom provides a dynamical mechanism for the generation of the charge gap and antiferromagnetism in the insulating phase. At finite doping, many of the anomalies of the normal state of the cuprates including the pseudogap, T-linear resistivity and the mid-infrared band are reproduced. A possible route to superconductivity is explored

  14. High pressure study of high-temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Souliou, Sofia-Michaela

    2014-09-29

    The current thesis studies experimentally the effect of high external pressure on high-T{sub c} superconductors. The structure and lattice dynamics of several members of the high-T{sub c} cuprate and Fe-based superconductors families were investigated by means of Raman spectroscopy and X-ray diffraction under well-controlled, hydrostatic high pressure and low temperature conditions. The lattice dynamics of the high-T{sub c} superconductor YBa{sub 2}Cu{sub 3}O{sub 6+x} have been investigated systematically by Raman spectroscopy as a function of doping (x = 0.95, 0.75, 0.60, 0.55, and 0.45) and external pressure. Under ambient pressure conditions, in addition to the Raman modes expected from group theory, we observe new Raman active phonons upon cooling the underdoped samples, at temperatures well above the superconducting transition temperature. The doping dependence and the onset temperatures of the new Raman features suggest that they are associated with the incommensurate charge density wave (CDW) state recently discovered in underdoped cuprates using synchrotron X-ray scattering techniques. Under high pressure conditions (from 2 to 12 GPa), our Raman measurements on highly ordered underdoped YBa{sub 2}Cu{sub 3}O{sub 6.55} samples do not show any of the new Raman phonons seen at ambient pressure. High pressure and low temperature Raman measurements have been performed on the underdoped superconductor YBa{sub 2}Cu{sub 4}O{sub 8}. A clear renormalization of some of the Raman phonons is seen below T{sub c} as a result of the changes in the phonon self-energy upon the opening of the superconducting gap, with the most prominent one being that of the B{sub 1g}-like buckling phonon mode. The amplitude of this renormalization strongly increases with pressure, resembling the effect of hole doping in YBa{sub 2}Cu{sub 3}O{sub 6+x}. At ∝ 10 GPa, the system undergoes a reversible pressure-induced structural phase transition to a non-centrosymmmetric structure (space group

  15. High pressure study of high-temperature superconductors

    International Nuclear Information System (INIS)

    Souliou, Sofia-Michaela

    2014-01-01

    The current thesis studies experimentally the effect of high external pressure on high-T c superconductors. The structure and lattice dynamics of several members of the high-T c cuprate and Fe-based superconductors families were investigated by means of Raman spectroscopy and X-ray diffraction under well-controlled, hydrostatic high pressure and low temperature conditions. The lattice dynamics of the high-T c superconductor YBa 2 Cu 3 O 6+x have been investigated systematically by Raman spectroscopy as a function of doping (x = 0.95, 0.75, 0.60, 0.55, and 0.45) and external pressure. Under ambient pressure conditions, in addition to the Raman modes expected from group theory, we observe new Raman active phonons upon cooling the underdoped samples, at temperatures well above the superconducting transition temperature. The doping dependence and the onset temperatures of the new Raman features suggest that they are associated with the incommensurate charge density wave (CDW) state recently discovered in underdoped cuprates using synchrotron X-ray scattering techniques. Under high pressure conditions (from 2 to 12 GPa), our Raman measurements on highly ordered underdoped YBa 2 Cu 3 O 6.55 samples do not show any of the new Raman phonons seen at ambient pressure. High pressure and low temperature Raman measurements have been performed on the underdoped superconductor YBa 2 Cu 4 O 8 . A clear renormalization of some of the Raman phonons is seen below T c as a result of the changes in the phonon self-energy upon the opening of the superconducting gap, with the most prominent one being that of the B 1g -like buckling phonon mode. The amplitude of this renormalization strongly increases with pressure, resembling the effect of hole doping in YBa 2 Cu 3 O 6+x . At ∝ 10 GPa, the system undergoes a reversible pressure-induced structural phase transition to a non-centrosymmmetric structure (space group Imm2). The structural transition is clearly reflected in the high pressure

  16. High temperature bismuth cuprate superconductors synthesis and characterization

    International Nuclear Information System (INIS)

    Mansori, M.; Satre, P.; Breandon, C.; Roubin, M.; Sebaoun, A.

    1993-01-01

    High temperature superconductor phases synthesis by coprecipitation in alkaline solution is reported. (Bi 1.6 Pb 0.4 )Sr 2 Ca 1 Cu 2 O 8+x and (Bi 1.6 Pb 0.4 )Sr 2 Ca 2 Cu 3 O 10+y noted (2212) and (2223) have been prepared and studied. From aqueous nitrate solutions of Bi, Pb, Sr, Ca and Cu and oxalic acid aqueous solution as well as ethylene glycol, using an organic base (the triethylamine), the pH was increased up to the path of the precipitation zone (pH = 10.5-11.2). This method assures a good granulometric homogeneity of powders. Thermal analysis and characterization of the different components produced during the synthesis have been studied by DTA (differential thermal analysis)- TGA (thermogravimetric analysis), X-ray diffraction at different temperatures and by Infrared spectroscopy with a Fourier transformation. The measurements of magnetic susceptibility for the 2212 (with and without lead) and 2223 (with lead) phases have permitted us to observe the critical temperatures of 84 K, 87 K and 114 K. (author). 29 refs., 2 figs., 4 tabs

  17. Glass precursor approach to high-temperature superconductors

    Science.gov (United States)

    Bansal, Narottam P.

    1992-01-01

    The available studies on the synthesis of high T sub c superconductors (HTS) via the glass precursor approach were reviewed. Melts of the Bi-Sr-Ca-Cu-O system as well as those doped with oxides of some other elements (Pb, Al, V, Te, Nb, etc.) could be quenched into glasses which, on further heat treatments under appropriate conditions, crystallized into the superconducting phase(s). The nature of the HTS phase(s) formed depends on the annealing temperature, time, atmosphere, and the cooling rate and also on the glass composition. Long term annealing was needed to obtain a large fraction of the 110 K phase. The high T sub c phase did not crystallize out directly from the glass matrix, but was preceded by the precipitation of other phases. The 110 K HTS was produced at high temperatures by reaction between the phases formed at lower temperatures resulting in multiphase material. The presence of a glass former such as B2O3 was necessary for the Y-Ba-Cu-O melt to form a glass on fast cooling. A discontinuous YBa2Cu3O(7-delta) HTS phase crystallized out on heat treatment of this glass. Attempts to prepare Tl-Ba-Ca-Cu-O system in the glassy state were not successful.

  18. Risk Mitigaion for HTS Motors: Intermediate Temperature (27 K) Strain Effects in Reinforced Bi-Sr-Ca-Cu-O Superconductors

    National Research Council Canada - National Science Library

    Schwartz, Justin

    2004-01-01

    High temperature superconductors , known for their high critical temperatures, also have very high upper critical fields and thus have received significant attention for superconducting magnets (SCMs...

  19. Multilayer ultra-high-temperature ceramic coatings

    Science.gov (United States)

    Loehman, Ronald E [Albuquerque, NM; Corral, Erica L [Tucson, AZ

    2012-03-20

    A coated carbon-carbon composite material with multiple ceramic layers to provide oxidation protection from ultra-high-temperatures, where if the carbon-carbon composite material is uninhibited with B.sub.4C particles, then the first layer on the composite material is selected from ZrB.sub.2 and HfB.sub.2, onto which is coated a layer of SiC coated and if the carbon-carbon composite material is inhibited with B.sub.4C particles, then protection can be achieved with a layer of SiC and a layer of either ZrB.sub.2 and HfB.sub.2 in any order.

  20. An investigation of texturing by magnetic and mechanical techniques in high critical temperature superconducting ceramics

    International Nuclear Information System (INIS)

    Deschanels, X.

    1992-11-01

    The principal goal of this work is to quantify the influence of texture of ceramic superconductors ReBaCuO (Re=Dy, Y) on their critical current density (Jc). The magnetic alignment of particles at ambient temperature is the first technique who has allowed us to produce superconducting (Meissner effect) and textured ceramics. However, these materials are very brittle because of their porosity and this makes it impossible to measure their Jc. Press-forging (or creep sintering) is the second technique who has allowed us to prepare highly textured ceramics materials which are also dense. We have studied the influence of various conditions of thermomechanical treatment (sintering time and temperature, applied load, rate of deformation, density of the material at the beginning) on the texture quality. We have shown that at 900 deg, the eutectic liquid formed by BaCuO 2 , CuO and YBa 2 Cu 3 0 7-Y various mechanisms that help explain the formation of observed texture. After the oxidation stage which requires heat treatment under controlled atmospheres, we obtain superconducting ceramics (Tc=85 K). Moreover, this study also shows that the texture can improve the Jc by 400%, to 750 A/cm 2 at 77 K in the best specimens. This low value is explained by the presence of non-superconducting secondary phases and amorphous phases at the grain boundaries. (Author). 120 refs., figs., tabs

  1. Development of high temperature superconductors having high critical current density

    International Nuclear Information System (INIS)

    Hong, Gye Wong; Kim, C. J.; Lee, H.G.; Kwon, S. C.; Lee, H. J.; Kim, K. B.; Park, J. Y.; Jung, C. H.

    2000-08-01

    Fabrication of high T c superconductors and its applications for electric power device were carried out for developing superconductor application technologies. High quality YBCO superconductors was fabricated by melt texture growth, top-seeded melt growth process and multi-seeded melt growth process and the properties was compared. The critical current density of the melt processed YBCO superconductors was about few 10,000 A/cm 2 and the levitation force was 50 N. The processing time needed for the growth of the 123 single grain was greatly reduced by applying multi-seeding without no significant degradation of the levitation force. The multi-seeded melt growth process was confirmed as a time-saving and cost-effective method for the fabrication of bulk superconductors with controlled crystallographic orientation

  2. Development of high temperature superconductors having high critical current density

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Gye Wong; Kim, C. J.; Lee, H.G.; Kwon, S. C.; Lee, H. J.; Kim, K. B.; Park, J. Y.; Jung, C. H

    2000-08-01

    Fabrication of high T{sub c} superconductors and its applications for electric power device were carried out for developing superconductor application technologies. High quality YBCO superconductors was fabricated by melt texture growth, top-seeded melt growth process and multi-seeded melt growth process and the properties was compared. The critical current density of the melt processed YBCO superconductors was about few 10,000 A/cm{sup 2} and the levitation force was 50 N. The processing time needed for the growth of the 123 single grain was greatly reduced by applying multi-seeding without no significant degradation of the levitation force. The multi-seeded melt growth process was confirmed as a time-saving and cost-effective method for the fabrication of bulk superconductors with controlled crystallographic orientation.

  3. Open questions in the magnetic behaviour of high-temperature superconductors

    International Nuclear Information System (INIS)

    Cohen, L.F.; Jensen, Henrik Jeldtoft

    1997-01-01

    A principally experimental review of vortex behaviour in high-temperature superconductors is presented. The reader is first introduced to the basic concepts needed to understand the magnetic properties of type II superconductors. The concepts of vortex melting, the vortex glass, vortex creep, etc are also discussed briefly. The bulk part of the review relates the theoretical predictions proposed for the vortex system in high temperature superconductors to experimental findings. The review ends with an attempt to direct the reader to those areas which still require further clarification. (author)

  4. On the stability of critical state in hard superconductors with nonhomogeneous temperature profile

    CERN Document Server

    Tajlanov, N A

    2002-01-01

    One studied the problem on thermal and magnetic breaking of critical state in hard superconductors. One assumes that initial distribution of temperature and of electrical field is very nonhomogeneous one. In quasi-stationary approximation one determined the limit of occurrence of thermal and magnetic instability in a superconductor. The derived integral criterion is shown to take account of the effect of each segment of a superconductor on the threshold of occurrence of critical state instability on contrast to similar criterion for homogeneous temperature profile

  5. Formation of hot spots in a superconductor observed by low-temperature scanning electron microscopy

    International Nuclear Information System (INIS)

    Eichele, R.; Seifert, H.; Huebener, R.P.

    1981-01-01

    Low-temperature scanning electron microscopy can be used for the direct observation of hot spots in a superconductor. Experiments performed at 2.10 K with tim films demonstrating the method are reported

  6. Theoretical study of cathode surfaces and high-temperature superconductors

    Science.gov (United States)

    Mueller, Wolfgang

    1995-01-01

    Calculations are presented for the work functions of BaO on W, Os, Pt, and alloys of Re-W, Os-W, and Ir-W that are in excellent agreement with experiment. The observed emission enhancement for alloy relative to tungsten dispenser cathodes is attributed to properties of the substrate crystal structure and explained by the smaller depolarization of the surface dipole on hexagonal as compared to cubic substrates. For Ba and BaO on W(100), the geometry of the adsorbates has been determined by a comparison of inverse photoemission spectra with calculated densities of unoccupied states based on the fully relativistic embedded cluster approach. Results are also discussed for models of scandate cathodes and the electronic structure of oxygen on W(100) at room and elevated temperatures. A detailed comparison is made for the surface electronic structure of the high-temperature superconductor YBa2Cu3O7 as obtained with non-, quasi-, and fully relativistic cluster calculations.

  7. Use of high temperature superconductors for future fusion magnet systems

    Energy Technology Data Exchange (ETDEWEB)

    Fietz, W H [Forschungszentrum Karlsruhe, Institut fuer Technische Physik, Karlsruhe (Germany); Celentano, G; Della Corte, A [Superconductivity Division, ENEA - Frascati Research Center, Frascati (Italy); Goldacker, W; Heller, R; Komarek, P; Kotzyba, G; Nast, R; Obst, B; Schlachter, S I; Schmidt, C; Zahn, G [Forschungszentrum Karlsruhe, Institut fuer Technische Physik, Karlsruhe (Germany); Pasztor, G; Wesche, R [Centre de Recherches en Physique des Plasmas, Villingen (Switzerland); Salpietro, E; Vostner, A [European Fusion Development Agreement, Close Support Unit, Garching (Germany)

    2005-01-01

    With the construction of ITER the feasibility of a fusion machine will be demonstrated. To commercialize fusion it is essential to keep losses as small as possible in future fusion power plants. One major component where losses can be strongly reduced is the cooling system. For example in ITER where efficiency is not a major goal, a cooling power of 64 kW at 4.4 K is foreseen taking more than 20 MW electric power. Considering the size of future commercial fusion machines this consumption of electric power for cooling will even be higher. With a magnet system working at 20 K a fusion machine would work more efficient by a factor of 5-10 with respect to electric power consumption for cryogenics. Even better than that, would be a machine with a magnet system operating at 65 K to 77 K. In this case liquid nitrogen could be used as coolant saving money for investment and operation costs. Such an increase in the operating temperature of the magnet system can be achieved by the use of High- Temperature Superconductors (HTS). In addition the use of HTS would allow much smaller efforts for thermal shielding and alternative thermal insulation concepts may be possible, e.g. for an HTS bus bar system. This contribution will give an overview about status, promises and challenges of HTS conductors on the way to an HTS fusion magnet system beyond ITER. (author)

  8. Tribology of selected ceramics at temperatures to 900 C

    Science.gov (United States)

    Sliney, H. E.; Jacobson, T. P.; Deadmore, D.; Miyoshi, K.

    1986-01-01

    Results of fundamental and focused research on the tribological properties of ceramics are discussed. The basic friction and wear characteristics are given for ceramics of interest for use in gas turbine, adiabatic diesel, and Stirling engine applications. The importance of metal oxides in ceramic/metal sliding combinations is illustrated. The formulation and tribological additives are described. Friction and wear data are given for carbide and oxide-based composite coatings for temperatures to at least 900 C.

  9. Pseudogap temperature T* of cuprate superconductors from the Nernst effect

    Science.gov (United States)

    Cyr-Choinière, O.; Daou, R.; Laliberté, F.; Collignon, C.; Badoux, S.; LeBoeuf, D.; Chang, J.; Ramshaw, B. J.; Bonn, D. A.; Hardy, W. N.; Liang, R.; Yan, J.-Q.; Cheng, J.-G.; Zhou, J.-S.; Goodenough, J. B.; Pyon, S.; Takayama, T.; Takagi, H.; Doiron-Leyraud, N.; Taillefer, Louis

    2018-02-01

    We use the Nernst effect to delineate the boundary of the pseudogap phase in the temperature-doping phase diagram of hole-doped cuprate superconductors. New data for the Nernst coefficient ν (T ) of YBa2Cu3Oy (YBCO), La1.8 -xEu0.2SrxCuO4 (Eu-LSCO), and La1.6 -xNd0.4SrxCuO4 (Nd-LSCO) are presented and compared with previously published data on YBCO, Eu-LSCO, Nd-LSCO, and La2 -xSrxCuO4 (LSCO). The temperature Tν at which ν /T deviates from its high-temperature linear behavior is found to coincide with the temperature at which the resistivity ρ (T ) deviates from its linear-T dependence, which we take as the definition of the pseudogap temperature T★—in agreement with the temperature at which the antinodal spectral gap detected in angle-resolved photoemission spectroscopy (ARPES) opens. We track T★ as a function of doping and find that it decreases linearly vs p in all four materials, having the same value in the three LSCO-based cuprates, irrespective of their different crystal structures. At low p ,T★ is higher than the onset temperature of the various orders observed in underdoped cuprates, suggesting that these orders are secondary instabilities of the pseudogap phase. A linear extrapolation of T★(p ) to p =0 yields T★(p →0 ) ≃TN (0), the Néel temperature for the onset of antiferromagnetic order at p =0 , suggesting that there is a link between pseudogap and antiferromagnetism. With increasing p ,T★(p ) extrapolates linearly to zero at p ≃pc 2 , the critical doping below which superconductivity emerges at high doping, suggesting that the conditions which favor pseudogap formation also favor pairing. We also use the Nernst effect to investigate how far superconducting fluctuations extend above the critical temperature Tc, as a function of doping, and find that a narrow fluctuation regime tracks Tc, and not T★. This confirms that the pseudogap phase is not a form of precursor superconductivity, and fluctuations in the phase of the

  10. Thermal conductivity in high critical temperature superconductors. Conductividad termica en los superconductores de alta temperatura critica

    Energy Technology Data Exchange (ETDEWEB)

    Castello, D J

    1990-01-01

    A measuring procedure to obtain the electrical resistivity, thermal conductivity and thermoelectric power of samples of low conductivity has been developed. The setup was designed to allow removal of the sample in clean fashion so that further heat treatments could be performed. The heat equation has been analyzed with time-dependent boundary conditions, with the purpose of developing a dynamic measuring method which avoids the long delays involved in reaching thermal equilibrium above 30K. The developed measuring method allows precise, reliable measurements in a continuous fashion for temperatures above 25K. The same setup is used in a stationary mode at low temperatures. {kappa}(T) has been measured in two ceramic samples of La{sub 2}CuO{sub 4}: the first semiconducting, the other superconducting (SC) as a consequence of an oxygen annealing. Both exhibit strong thermal resistivity due to defects, though lower in the SC, where two maxima are observed and are attributed to an AF ordering: T{sub N}' {approx equal} 40K and T{sub N}'' {approx equal} 240K. A third synthesized sample of CuO exhibits a typical behavior of an insulator, with T{sup 2}.6 at low temperatures, a maximum at 40K and a decrease in T{sup -1} at high temperatures. {kappa}(T) in a SC sample of La{sub 1}.85Sr{sub 1}.15CuO{sub 4} with T{sub c}=35.5K has also been measured. {kappa}(T) is lower than in the previous samples and thus a greater number of defects was inferred.

  11. Ceramic membranes for high temperature hydrogen separation

    Energy Technology Data Exchange (ETDEWEB)

    Adcock, K.D.; Fain, D.E.; James, D.L.; Powell, L.E.; Raj, T.; Roettger, G.E.; Sutton, T.G. [East Tennessee Technology Park, Oak Ridge, TN (United States)

    1997-12-01

    The separative performance of the authors` ceramic membranes has been determined in the past using a permeance test system that measured flows of pure gases through a membrane at temperatures up to 275 C. From these data, the separation factor was determined for a particular gas pair from the ratio of the pure gas specific flows. An important project goal this year has been to build a Mixed Gas Separation System (MGSS) for measuring the separation efficiencies of membranes at higher temperatures and using mixed gases. The MGSS test system has been built, and initial operation has been achieved. The MGSS is capable of measuring the separation efficiency of membranes at temperatures up to 600 C and pressures up to 100 psi using a binary gas mixture such as hydrogen/methane. The mixed gas is fed into a tubular membrane at pressures up to 100 psi, and the membrane separates the feed gas mixture into a permeate stream and a raffinate stream. The test membrane is sealed in a stainless steel holder that is mounted in a split tube furnace to permit membrane separations to be evaluated at temperatures up to 600 C. The compositions of the three gas streams are measured by a gas chromatograph equipped with thermal conductivity detectors. The test system also measures the temperatures and pressures of all three gas streams as well as the flow rate of the feed stream. These data taken over a range of flows and pressures permit the separation efficiency to be determined as a function of the operating conditions. A mathematical model of the separation has been developed that permits the data to be reduced and the separation factor for the membrane to be determined.

  12. Magnetization studies in high temperature and conventional superconductors

    International Nuclear Information System (INIS)

    Grover, A.K.; Chaddah, P.

    1991-01-01

    In this paper, the authors state the contemporary view of the physical basis of a celebrated phenomenological model for hard superconductors. The authors highlight the qualitative and general predictions of this model relevant to various magnetic measurements. The authors give prescriptions to correlate data of different experiments with the predictions of the model with the intention of extracting information on material parameters, like J c (H), pinning potential, etc. These prescriptions will be illustrated with the data on both conventional and HTSC superconductors. The correlation of these data with the predictions of the model underscores the similarity in behaviour between the two classes of hard superconductors

  13. Transport measurements in superconductors: critical current of granular high TC ceramic superconductor samples; Medidas de transporte em supercondutores: corrente critica de supercondutores granulares de alta temperatura critica

    Energy Technology Data Exchange (ETDEWEB)

    Passos, W.A.C., E-mail: wagner.passos@univasf.edu.br [Universidade Federal do Vale do Sao Francisco (IPCM/UNIVASF), Juazeiro do Norte, BA (Brazil). Instituto de Pesquisas em Ciencia dos Materiais; Silva, E.B. [Companhia Energetica do Sao Francisco (CHESF), Recife, PE (Brazil)

    2016-07-01

    This work presents a method to obtain critical current of granular superconductors. We have carried out transport measurements (ρxT curves and VxI curves) in a YBa{sub 2}Cu{sub 3}O{sub 7-δ} sample to determine critical current density of it. Some specimens reveal a 'semiconductor-like' behavior (electrical resistivity decreases with increasing temperatures above critical temperature T{sub c} of material) competing with superconductor behavior. Due to high granular fraction of the sample, these competition is clearly noted in ρxT curves. Measurements carried out from 0 to 8500 Oe of applied field show the same behavior, and the critical current density of the samples is shown. (author)

  14. Temperature dependence of the upper critical field of type II superconductors with fluctuation effects

    International Nuclear Information System (INIS)

    Mikitik, G.P.

    1992-01-01

    Fluctuations of the order parameter are taken into consideration in an analysis of the temperature dependence of the upper critical field of a type II superconductor with a three-dimensional superconductivity. This temperature dependence is of universal applicability, to all type II superconductors, if the magnetic fields and temperatures are expressed in appropriate units. This dependence is derived explicitly for the regions of strong and weak magnetic fields. The results are applied to high T c superconductors, for which fluctuation effects are important. For these superconductors, the H c2 (T) dependence is quite different from the linear dependence characteristic of the mean-field theory, over a broad range of magnetic fields

  15. High temperature strengthening of zirconium-toughened ceramics

    International Nuclear Information System (INIS)

    Claussen, N.

    1986-01-01

    Transformation-toughened (i.e. ZrO/sub 2/-toughened) ceramics represent a new class of high performance ceramics with spectacular strength properties at low and intermediate temperatures. However, at temperatures above about 700 0 C, most of these tough oxide-base ceramics can no longer be used as load-bearing engineering parts because of characteristic deficiencies. The aim of the present paper is to provide and discuss microstructural design strategies which may enable ZrO/sub 2/-toughened ceramics to be applied at higher temperatures. From the various strategies suggested, three appear to show good prospects, namely (a) the prevention of glassy intergranular films, (b) the addition of hard high modulus particles and (c) whikser or fibre reinforcement. Experimental approaches are presented from some ZrO/sub 2/-toughened ceramics, elg. tetragonal ZrO/sub 2/ polycrystals and ZrO/sub 2/-toughened cordierite, spinel and mullite

  16. Synthesis and Microstructure Properties of (Bi,Pb2Sr2Ca1Cu2Oy Ceramic Superconductor

    Directory of Open Access Journals (Sweden)

    nurmalita .

    2015-11-01

    Full Text Available Properties of (Bi, Pb2Sr2Ca1Cu2Oy ceramic superconductors were prepared by the melt textured growth methods in order to investigate the effects of the slow cooling time on the microstructur.  Phase analyses of the samples by X-ray diffraction (XRD has been carried out to assess the effects of the slow cooling time. From XRD analyses, the addition to the sample of  the slow cooling time degrades formation of the high-Tc Bi-2212 phase. The possible reasons for the observed degradation in the microstructure properties due to the slow cooling time addition were discussed.

  17. Manufacturing of superconductive silver/ceramic composites

    DEFF Research Database (Denmark)

    Seifi, Behrouz; Bech, Jakob Ilsted; Eriksen, Morten

    2000-01-01

    Manufacturing of superconducting metal/ceramic composites is a rather new discipline within materials forming processes. High Temperature SuperConductors, HTSC, are manufactured applying the Oxide-Powder-In-Tube process, OPIT. A ceramic powder containing lead, calcium, bismuth, strontium, and cop......Manufacturing of superconducting metal/ceramic composites is a rather new discipline within materials forming processes. High Temperature SuperConductors, HTSC, are manufactured applying the Oxide-Powder-In-Tube process, OPIT. A ceramic powder containing lead, calcium, bismuth, strontium...

  18. Temperature Induced Degradation of Nb Ti/Cu Composite Superconductors

    CERN Document Server

    Scheuerlein, C; Senatore, C; Di Michiel, M; Thilly, L; Gerardin, A; Reluner, B; Oberli, L; Willering, G; Bottura, L

    2009-01-01

    The degradation mechanisms of state-of-the-art Nb-Ti/Cu superconductors are described, based on in-situ synchrotron X-ray diffraction measurements during heat treatment. A quantitative description of the Nb-Ti/Cu degradation in terms of critical current density, Cu stabiliser resistivity and mechanical composite strength is presented. In an applied magnetic field a significant critical current degradation is already observed after a 5-minute 400 °C heat treatment, due to variations of a-Ti precipitate size and distribution within the Nb-Ti alloy filaments. A strong degradation of the strand mechanical properties is observed after several minutes heating above 550 °C, which is also the temperature at which the formation of Cu Ti intermetallic phases is detected. Several minutes heating at 250 °C are sufficient to increase the RRR of the strongly cold work strands inside a Rutherford type cable from about 80 to about 240. Heating for several minutes at 400 °C does not cause a significant conductor degradati...

  19. Growth of high-temperature superconductor crystals from flux

    International Nuclear Information System (INIS)

    Demianets, L.N.; Bykov, A.B.; Melnikov, O.K.; Stishov, S.M.

    1991-01-01

    Crystallization of high-temperature superconductors was studied in La-Sr-Cu-O, Y-Ba-Cu-O and Bi-Sr-Ca-Cu-O systems. Platelet crystals YBa 2 Cu 3 Osub(6.5+x) were obtained by spontaneous crystallization from homogeneous nonstoichiometric melts enriched in barium and copper oxides. Lasub(2-x)Sr x CuO 4 was prepared by slow cooling of melts enriched in copper oxide. Bi 2 (Sr, Ca)sub(n+1)Cu n O y , (n=1;2) was obtained by melting zone travelling. The crystals show transition to superconducting state at T=93K, ΔT 0.2-0.5 K (Y, Ba cuprate), T=87K, ΔT 2K (Bi, Sr, Ca-cuprate). La, Sr-cuprate single crystals obtained by Czochralski method did not show transition to superconducting state. For flux-grown crystals T c was 5-26 K depending on the composition, growth and heat treatment. The short characterization of some accessory phases (Ba 3 Y 2 Cu 3 PtO 10 , Casub(1.75)Srsub(1.5)Cusub(0.75)PtO 6 , BaCuO 2 , Ba 41 Cu 44 O 84 Cl 2 ) is reported. (author). 15 ref s., 8 figs

  20. Development of high temperature superconductors for magnetic field applications

    International Nuclear Information System (INIS)

    Larbalestier, D.C.

    1991-01-01

    The key requirement for magnetic field applications of high temperature superconductor (HTS) materials is to have conductors with high transport critical current density available for magnet builders. After 3 or 4 years of being without any such object, conductor makers have had recent success in producing simple conductor prototypes. These have permitted the construction of simple HTS magnets having self fields exceeding 1 tesla at 4K. Thus the scientific feasibility of making powerful HTS magnets has been demonstrated. Attention to the technological aspects of making HTS conductors for magnets with strong flux pinning and reduced superconducting granularity is now sensible and attractive. However, extrinsic defects such as filament sausaging, cracking, misaligned grains and other perturbations to long range current flow must be controlled at a low level if the benefit of intrinsic improvements to the critical current density is to be maintained in the conductor form. Due to the great complexity of HTS materials, there is sometimes confusion as to whether a given sample has an intrinsically or extrinsically limited critical current density. Systematic microstructure variation experiments and resistive transition analysis are shown to be particularly helpful in this phase of conductor development

  1. Small magnetic energy storage systems using high temperature superconductors

    International Nuclear Information System (INIS)

    Kumar, B.

    1991-01-01

    This paper reports on magnetic energy storage for power systems that has been considered for commercial utility power, air and ground mobile power sources, and spacecraft applications. Even at the current technology limits of energy storage (100 KJ/Kg*), superconducting magnetic energy storage inductors do not offer a strong advantage over state-of-the-art batteries. The commercial utility application does not have a weight and volume limitation, and is under intense study in several countries for diurnal cycle energy storage and high power delivery. The advent of high temperature superconductors has reduced one of the penalties of superconducting magnetic energy storage in that refrigeration and cryocontainers become greatly simplified. Still, structural and current density issues that limit the energy density and size of superconducting inductors do not change. Cold weather starting of aircraft engines is an application where these limitations are not as significant, and where current systems lack performance. The very cold environments make it difficult to achieve high power densities in state-of-the-art batteries and hydraulically activated starters. The same cold environments make it possible to cool superconducting systems for weeks using a single charge of liquid nitrogen. At the same, the ground carts can handle the size and weight of superconducting magnetic storage (SMES) devices

  2. The Discovery of a Class of High-Temperature Superconductors.

    Science.gov (United States)

    Muller, K. Alex; Bednorz, J. Georg

    1987-01-01

    Describes the new class of oxide superconductors, the importance of these materials, and the concepts that led to its discovery. Summarizes the discovery itself and its early confirmation. Discusses the observation of a superconductive glass state in percolative samples. (TW)

  3. Potentialities in electronics of new high critical temperature superconductors. Potentialites en electronique des nouveaux supraconducteurs a haute temperature critique

    Energy Technology Data Exchange (ETDEWEB)

    Hartemann, P [Thomson-CSF, 75 - Paris (FR)

    1989-09-01

    The main electronic applications of superconductors involve the signal processing, the electromagnetic wave detection and the magnetometry. Characteristics of devices based on conventional superconductors cooled by liquid helium are given and the changes induced by incorporating high-temperature superconductors are estimated. After a survey of new superconductor properties, the superconducting devices for analog or digital signal processing are reviewed. The gains predicted for high-temperature superconducting analog devices are considered in greater detail. Different sections deal with the infrared or (sub)millimeter wave detection. The most sensitive apparatuses for magnetic measurements are based on SQUIDs. Features of SQUIDs made of granular high-temperature superconducting material samples (grain boundaries behave as barriers of intrinsic junctions) are discussed.

  4. Anisotropic magnetoresistance and thermodynamic fluctuations in high-temperature superconductors

    International Nuclear Information System (INIS)

    Heine, G.

    1999-05-01

    Measurements of the in-plane and out-of-plane resistivity and the transverse and longitudinal in-plane and out-of-plane magnetoresistance above T, are reported in the high-temperature superconductors Bi2Sr2CaCu208+' and YBa2CU307 b . The carrier concentration of the Bi2Sr2CaCu208+' single crystals covers a broad range of the phase diagram from the slightly under doped to the moderately over doped region. The doping concentration of the thin films ranges from strongly under doped to optimally doped. The in-plane resistivities obey a metallic-like temperature dependence with a positive magnetoresistance in the transverse and the longitudinal orientation of the magnetic field. The out-of-plane resistivities show an activated behavior above T, with a metallic region at higher temperatures and negative magnetoresistance. The data were analyzed in the framework of a model for superconducting order parameter fluctuations. The positive in-plane magnetoresistance of the highly anisotropic Bi2Sr2CaCu208+x single crystals is interpreted as the suppression of the fluctuation-conductivity enhancement including orbital and spin contributions, whereas the negative magnetoresistance arises from the reduction of the fluctuation-induced pseudogap in the single-electron density-of-states by the magnetic field. For higher temperatures a transition to the normal-state magnetoresistance occurs for the in-plane transport. In the less anisotropic YBa2CU307 b thin films the positive out-of-plane magnetoresistance near T, changes sign to a negative magnetoresistance at higher temperatures. This behavior is also consistent with predictions from the theory of thermodynamic order-parameter fluctuations. The agreement of the fluctuation theory with the experimental findings is excellent for samples from the over doped side of the phase diagram, but deteriorate with decreasing carrier concentration. This behavior is interpreted by the dominating d-wave symmetry of the superconducting order

  5. The study of some physical properties of high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Ismail, Atif Mahmoud

    2008-07-01

    The phenomenon of superconductivity, the discovery of high temperature superconductivity in the Cuprates and the properties of these materials is described in the introductory chapter. It also includes a discussion of the pseudogap, which has remained a mystery as has the high transition temperature. Possible applications of high temperature superconductivity are reviewed before the theories by Bardeen, Cooper, and Schrieffer (BCS) and Ginzburg and Landau are briefly sketched. The last section gives excerpts of the by now vast literature on this subject, focussing on the role impurities play in this context. The second chapter develops the mathematical tools and the theoretical background for the description of many-body systems. Various Green's functions are introduced which are then used to describe scattering of quasiparticles off defects of arbitrary strength. They are also required to calculate the a.c. conductivity, for which an expression is derived using linear response theory. The convergence problems one encounters when actually calculating the conductivity are briefly discussed. Detailed calculations for the normal state are presented in the third chapter and in the appendix. The third Chapter begins with a detailed presentation of the tight binding model for the energy dispersion because this model appears to give a more accurate description of the electronic properties of high temperature superconductors than the nearly free electron model. The shape of the two-dimensional Fermi surface is calculated and displayed as function of band filling and the next-nearest neighbor hopping integral B, assuming a rigid band. B plays an important role in the formation of so-called hot spots. The quasiparticle density of states and its Hilbert transform F({omega}) are solved by means of complete elliptic integrals formalism. These results are used to obtain impurity bound states. A simple model for the superconductivity in the cuprate materials is developed on the

  6. The study of some physical properties of high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Ismail, Atif Mahmoud

    2008-07-01

    The phenomenon of superconductivity, the discovery of high temperature superconductivity in the Cuprates and the properties of these materials is described in the introductory chapter. It also includes a discussion of the pseudogap, which has remained a mystery as has the high transition temperature. Possible applications of high temperature superconductivity are reviewed before the theories by Bardeen, Cooper, and Schrieffer (BCS) and Ginzburg and Landau are briefly sketched. The last section gives excerpts of the by now vast literature on this subject, focussing on the role impurities play in this context. The second chapter develops the mathematical tools and the theoretical background for the description of many-body systems. Various Green's functions are introduced which are then used to describe scattering of quasiparticles off defects of arbitrary strength. They are also required to calculate the a.c. conductivity, for which an expression is derived using linear response theory. The convergence problems one encounters when actually calculating the conductivity are briefly discussed. Detailed calculations for the normal state are presented in the third chapter and in the appendix. The third Chapter begins with a detailed presentation of the tight binding model for the energy dispersion because this model appears to give a more accurate description of the electronic properties of high temperature superconductors than the nearly free electron model. The shape of the two-dimensional Fermi surface is calculated and displayed as function of band filling and the next-nearest neighbor hopping integral B, assuming a rigid band. B plays an important role in the formation of so-called hot spots. The quasiparticle density of states and its Hilbert transform F({omega}) are solved by means of complete elliptic integrals formalism. These results are used to obtain impurity bound states. A simple model for the superconductivity in the cuprate materials is developed on

  7. The study of some physical properties of high temperature superconductors

    International Nuclear Information System (INIS)

    Ismail, Atif Mahmoud

    2008-01-01

    The phenomenon of superconductivity, the discovery of high temperature superconductivity in the Cuprates and the properties of these materials is described in the introductory chapter. It also includes a discussion of the pseudogap, which has remained a mystery as has the high transition temperature. Possible applications of high temperature superconductivity are reviewed before the theories by Bardeen, Cooper, and Schrieffer (BCS) and Ginzburg and Landau are briefly sketched. The last section gives excerpts of the by now vast literature on this subject, focussing on the role impurities play in this context. The second chapter develops the mathematical tools and the theoretical background for the description of many-body systems. Various Green's functions are introduced which are then used to describe scattering of quasiparticles off defects of arbitrary strength. They are also required to calculate the a.c. conductivity, for which an expression is derived using linear response theory. The convergence problems one encounters when actually calculating the conductivity are briefly discussed. Detailed calculations for the normal state are presented in the third chapter and in the appendix. The third Chapter begins with a detailed presentation of the tight binding model for the energy dispersion because this model appears to give a more accurate description of the electronic properties of high temperature superconductors than the nearly free electron model. The shape of the two-dimensional Fermi surface is calculated and displayed as function of band filling and the next-nearest neighbor hopping integral B, assuming a rigid band. B plays an important role in the formation of so-called hot spots. The quasiparticle density of states and its Hilbert transform F(ω) are solved by means of complete elliptic integrals formalism. These results are used to obtain impurity bound states. A simple model for the superconductivity in the cuprate materials is developed on the basis

  8. Stress analysis in high-temperature superconductors under pulsed field magnetization

    Science.gov (United States)

    Wu, Haowei; Yong, Huadong; Zhou, Youhe

    2018-04-01

    Bulk high-temperature superconductors (HTSs) have a high critical current density and can trap a large magnetic field. When bulk superconductors are magnetized by the pulsed field magnetization (PFM) technique, they are also subjected to a large electromagnetic stress, and the resulting thermal stress may cause cracking of the superconductor due to the brittle nature of the sample. In this paper, based on the H-formulation and the law of heat transfer, we can obtain the distributions of electromagnetic field and temperature, which are in qualitative agreement with experiment. After that, based on the dynamic equilibrium equations, the mechanical response of the bulk superconductor is determined. During the PFM process, the change in temperature has a dramatic effect on the radial and hoop stresses, and the maximum radial and hoop stress are 24.2 {{MPa}} and 22.6 {{MPa}}, respectively. The mechanical responses of a superconductor for different cases are also studied, such as the peak value of the applied field and the size of bulk superconductors. Finally, the stresses are also presented for different magnetization methods.

  9. Cluster-assembled overlayers and high-temperature superconductors

    International Nuclear Information System (INIS)

    Ohno, T.R.; Yang, Y.; Kroll, G.H.; Krause, K.; Schmidt, L.D.; Weaver, J.H.; Kimachi, Y.; Hidaka, Y.; Pan, S.H.; de Lozanne, A.L.

    1991-01-01

    X-ray photoemission results for interfaces prepared by cluster assembly with nanometer-size clusters deposited on high-T c superconductors (HTS's) show a reduction in reactivity because atom interactions with the surface are replaced by cluster interactions. Results for conventional atom deposition show the formation of overlayer oxides that are related to oxygen depletion and disruption of the near-surface region of the HTS's. For cluster assembly of Cr and Cu, there is a very thin reacted region on single-crystal Bi 2 Sr 2 CaCu 2 O 8 . Reduced reactivity is observed for Cr cluster deposition on single-crystal YBa 2 Cu 3 O 7 -based interfaces. There is no evidence of chemical modification of the surface for Ge and Au cluster assembly on Bi 2 Sr 2 CaCu 2 O 8 (100). The overlayer grown by Au cluster assembly on Bi 2 Sr 2 CaCu 2 O 8 covers the surface at low temperature but roughening occurs upon warming to 300 K. Scanning-tunneling-microscopy results for the Au(cluster)/Bi 2 Sr 2 CaCu 2 O 8 system warmed to 300 K shows individual clusters that have coalesced into large clusters. These results offer insight into the role of surface energies and cluster interactions in determining the overlayer morphology. Transmission-electron-microscopy results for Cu cluster assembly on silica show isolated irregularly shaped clusters that do not interact at low coverage. Sintering and labyrinth formation is observed at intermediate coverage and, ultimately, a continuous film is achieved at high coverage. Silica surface wetting by Cu clusters demonstrates that dispersive force are important for these small clusters

  10. Microwave impedance of epitaxial high-temperature superconductor films

    International Nuclear Information System (INIS)

    Melkov, G.A.; Malyshev, V.Yu.; Bagada, A.V.

    1995-01-01

    In the 3 cm band dependences of the epitaxial HTS film surface resistance on the magnitude of ac and dc magnetic fields have been measured. YBa 2 Cu 3 O 7-σ films on sapphire were investigated. It was established that alternating magnetic field produces a stronger impact on the surface resistance than dc field. To explain experimental results the assumption is made that a HTS film is not an ideal superconductor and consists of series-connected sections of various types: sections of an ideal superconductor, sections of low and large resistance intragranular Josephson junctions, shunted by the ideal superconductor, and finally, sections of intergranular Josephson junctions few for epitaxial films. In these conditions the dependences of the surface resistance on dc magnetic field are caused by Abrikosov's vortices moving in ideal superconductive sections, and dependences on the amplitude of ac magnetic field are caused by switching of large resistance junctions to a low resistance state

  11. Temperature dependence of piezoelectric properties for textured SBN ceramics.

    Science.gov (United States)

    Kimura, Masahiko; Ogawa, Hirozumi; Kuroda, Daisuke; Sawada, Takuya; Higuchi, Yukio; Takagi, Hiroshi; Sakabe, Yukio

    2007-12-01

    Temperature dependences of piezoelectric properties were studied for h001i textured ceramics of bismuth layer-structured ferroelectrics, SrBi(2)Nb(2)O(9) (SBN). The textured ceramics with varied orientation degrees were fabricated by templated, grain-growth method, and the temperature dependences of resonance frequency were estimated. Excellent temperature stability of resonance frequency was obtained for the 76% textured ceramics. The resonance frequency of the 76% textured specimens varied almost linearly over a wide temperature range. Therefore, the variation was slight, even in a high temperature region above 150 degrees C. Temperature stability of a quartz crystal oscillator is generally higher than that of a ceramic resonator around room temperature. The variation of resonance frequency for the 76% textured SrBi(2)Nb(2)O(9) was larger than that of oscillation frequency for a typical quartz oscillator below 150 degrees C also in this study. However, the variation of the textured SrBi(2)Nb(2)O(9) was smaller than that of the quartz oscillator over a wide temperature range from -50 to 250 degrees C. Therefore, textured SrBi(2)Nb(2)O(9) ceramics is a major candidate material for the resonators used within a wide temperature range.

  12. Superconductors

    International Nuclear Information System (INIS)

    Newkirk, L.R.; Valencia, F.A.

    1977-01-01

    The structural quality of niobium germanide as a high-transition-temperature superconducting material is substantially improved by the presence of about 5 at. percent oxygen. Niobium germanide having this oxygen content may readily be prepared as a bulk coating bonded to a metallic substrate by chemical vapor deposition techniques. 2 figures, 1 table

  13. Superconductors

    Science.gov (United States)

    Newkirk, Lawrence R.; Valencia, Flavio A.

    1977-02-01

    The structural quality of niobium germanide as a high-transition-temperature superconducting material is substantially improved by the presence of about 5 at. % oxygen. Niobium germanide having this oxygen content may readily be prepared as a bulk coating bonded to a metallic substrate by chemical vapor deposition techniques.

  14. Quantum oscillations and key theoretical issues in high temperature superconductors from the perspective of density waves

    International Nuclear Information System (INIS)

    Chakravarty, Sudip

    2011-01-01

    High temperature superconductivity in cuprate superconductors remains an unsolved problem in theoretical physics. The same statement can also be made about a number of other superconductors that have been dubbed novel. What makes these superconductors so elusive is an interesting question in itself. This paper focuses on the recent magnetic oscillation experiments and how they fit into the broader picture. Many aspects of these experiments can be explained by Fermi liquid theory; the key issue is the extent to which this is true. If true, the entire paradigm developed over the past three decades must be reexamined. A critical analysis of this issue has necessitated a broader analysis of questions about distinct ground states of matter, which may be useful in understanding other novel superconductors.

  15. Second-Generation High-Temperature Superconductor Wires for the Electric Power Grid

    Science.gov (United States)

    Malozemoff, A. P.

    2012-08-01

    Superconductors offer major advantages for the electric power grid, including high current and power capacity, high efficiency arising from the lossless current flow, and a unique current-limiting functionality arising from a superconductor-to-resistive transition. These advantages can be brought to bear on equipment such as underground power cables, fault current limiters, rotating machinery, transformers, and energy storage. The first round of significant commercial-scale superconductor power-equipment demonstrations, carried out during the past decade, relied on a first-generation high-temperature superconductor (HTS) wire. However, during the past few years, with the recent commercial availability of high-performance second-generation HTS wires, power-equipment demonstrations have increasingly been carried out with these new wires, which bring important advantages. The foundation is being laid for commercial expansion of this important technology into the power grid.

  16. Current and field distribution in high temperature superconductors

    International Nuclear Information System (INIS)

    Johnston, M.D.

    1998-01-01

    The manufacture of wires from HTS materials containing copper-oxide planes is difficult because their physical and electrical properties are highly anisotropic. The electrical connectivity depends on the nearest-neighbour grain alignment and although a high degree of grain texture is achieved through processing, the tape microstructure is generally far from uniform, with weak links and porosity also complicating the picture. In order to optimise the processing, the microstructural features common to good tapes must be identified, requiring knowledge of the local properties. The preferential path taken by transport current is determined by the properties of the local microstructure and as such can be used to measure the variation in quality across the tape cross-section. By measuring the self-field profile generated by a current-carrying tape, it is possible to extract the associated current distribution. I have designed and built a Scanning Hall Probe Microscope to measure the normal field distribution above superconductor tapes carrying DC currents, operating at liquid nitrogen temperature and zero applied magnetic field. It has a spatial resolution of 50*50 μm and a field sensitivity of 5 μT, and can scan over a distance of 6 mm. The current extraction is performed by means of a deconvolution procedure based on Legendre functions. This allows a nondestructive, non-invasive method of evaluating the effects of the processing on the tapes - especially when correlated with transport and magnetisation measurement data. Conductors fabricated from Bi 2 Sr 2 Ca 2 Cu 3 O 10 , Bi 2 Sr 2 CaCu 2 O 8 and (Tl 0.78 Bi 0.22 )(Sr 0.8 Ba 0.2 ) 2 Ca 2 Cu 3 O x , have been investigated. I have confirmed the reports that in Bi-2223/Ag mono-core conductors produced by the oxide-powder-in-tube (OPIT) technique, the current flows predominantly at the edges of the tape, where the grains are long and well-aligned. This is in contrast to Bi-2212 ribbons, where the better microstructure

  17. Temperature Measurement of Ceramic Materials Using a Multiwavelength Pyrometer

    Science.gov (United States)

    Ng, Daniel; Fralick, Gustave

    1999-01-01

    The surface temperatures of several pure ceramic materials (alumina, beryllia, magnesia, yittria and spinel) in the shape of pellets were measured using a multiwavelength pyrometer. In one of the measurements, radiation signal collection is provided simply by an optical fiber. In the other experiments, a 4.75 inch (12 cm) parabolic mirror collects the signal for the spectrometer. Temperature measurement using the traditional one- and two-color pyrometer for these ceramic materials is difficult because of their complex optical properties, such as low emissivity which varies with both temperature and wavelength. In at least one of the materials, yittria, the detected optical emission increased as the temperature was decreased due to such emissivity variation. The reasons for such changes are not known. The multiwavelength pyrometer has demonstrated its ability to measure surface temperatures under such conditions. Platinum electrodes were embedded in the ceramic pellets for resistance measurements as the temperature changed.

  18. Fracture peculiarities in ceramic tungsten at different temperatures in vacuum

    International Nuclear Information System (INIS)

    Uskov, E.I.; Babak, A.V.

    1981-01-01

    Stress-strain diagrams and results of metallographic analyses are presented for the ceramic tungsten samples tested for fracture toughness under conditions of eccentric tension at different temperatures (20...1600 deg C) in vacuum. The tungsten fracture is shown to be of brittle nature within the whole temperature range studied, but the fracture process has its own peculiarities at different test temperatures

  19. WOHLLEBEN EFFECT (PARAMAGNETIC MEISSNER EFFECT) IN HIGH-TEMPERATURE SUPERCONDUCTORS

    NARCIS (Netherlands)

    KHOMSKII, D

    Recently a quite unexpected phenomenon was observed during the study of the magnetic properties of High-T(c) superconductors: In the field-cooled regime the magnetic response of some HTSC at very low fields (less than or similar to 1 Oe), instead of being diamagnetic, becomes paramagnetic. Such

  20. PR IN HIGH-TEMPERATURE SUPERCONDUCTORS - INSULATING PLANES, METALLIC CHAINS

    NARCIS (Netherlands)

    KHOMSKII, D

    Critical discussion is given of the properties of Pr-containing high-T(c) superconductors, especially Y1-xPrxBa2Cu3O7. It is argued that the models proposed to explain suppression of T(c) and other properties of this system (pairbreaking; hole filling; strong p-f hybridization) are inadequate and

  1. 4TH International Conference on High-Temperature Ceramic Matrix Composites

    National Research Council Canada - National Science Library

    2001-01-01

    .... Topic to be covered include fibers, interfaces, interphases, non-oxide ceramic matrix composites, oxide/oxide ceramic matrix composites, coatings, and applications of high-temperature ceramic matrix...

  2. The interaction between the permanent magnet and ceramic superconductor with organic filler

    International Nuclear Information System (INIS)

    Woźny, L; Kisiel, A; Garbera, A

    2016-01-01

    The aim of the study was to examine the phenomenon of magnetic levitation for YBaCuO superconducting samples in pure form and with epoxy resin content of 40%. Samples of superconductors were prepared by the standard reaction in the solid state. The forces of interaction between the superconductor and neodymium permanent magnet were measured. Samples with epoxy resin fillers had significantly smaller levitation force than the sample of the sintered superconductors. This is due to a much lower content of pure superconducting material in the sample volume (about 60% of the YBaCuO). However, the obvious advantage of such samples is the possibility of preparation superconductors with complicated shapes, eg. for use in a superconducting bearings or other devices. (paper)

  3. Measurement of relative permittivity of LTCC ceramic at different temperatures

    Directory of Open Access Journals (Sweden)

    Qiulin Tan

    2014-02-01

    Full Text Available Devices based on LTCC (low-temperature co-fired ceramic technology are more widely applied in high temperature environments, and the temperature-dependent properties of the LTCC material play an important role in measurements of the characteristics of these devices at high temperature. In this paper, the temperature-dependence of the relative permittivity of DuPont 951 LTCC ceramic is studied from room temperature to 500 °C. An expression for relative permittivity is obtained, which relates the relative permittivity to the resonant frequency, inductance, parasitic capacitance and electrode capacitance of the LTCC sample. Of these properties, the electrode capacitance is the most strongly temperature-dependent. The LTCC sample resonant frequency, inductance and parasitic capacitance were measured (from room temperature to 500 °C with a high temperature measurement system comprising a muffle furnace and network analyzer. We found that the resonant frequency reduced and the inductance and parasitic capacitance increased slightly as the temperature increases. The relative permittivity can be calculated from experimental frequency, inductance and parasitic capacitance measurements. Calculating results show that the relative permittivity of DuPont 951 LTCC ceramic ceramic increases to 8.21 from room temperature to 500 °C.

  4. Universal linear-temperature resistivity: possible quantum diffusion transport in strongly correlated superconductors.

    Science.gov (United States)

    Hu, Tao; Liu, Yinshang; Xiao, Hong; Mu, Gang; Yang, Yi-Feng

    2017-08-25

    The strongly correlated electron fluids in high temperature cuprate superconductors demonstrate an anomalous linear temperature (T) dependent resistivity behavior, which persists to a wide temperature range without exhibiting saturation. As cooling down, those electron fluids lose the resistivity and condense into the superfluid. However, the origin of the linear-T resistivity behavior and its relationship to the strongly correlated superconductivity remain a mystery. Here we report a universal relation [Formula: see text], which bridges the slope of the linear-T-dependent resistivity (dρ/dT) to the London penetration depth λ L at zero temperature among cuprate superconductor Bi 2 Sr 2 CaCu 2 O 8+δ and heavy fermion superconductors CeCoIn 5 , where μ 0 is vacuum permeability, k B is the Boltzmann constant and ħ is the reduced Planck constant. We extend this scaling relation to different systems and found that it holds for other cuprate, pnictide and heavy fermion superconductors as well, regardless of the significant differences in the strength of electronic correlations, transport directions, and doping levels. Our analysis suggests that the scaling relation in strongly correlated superconductors could be described as a hydrodynamic diffusive transport, with the diffusion coefficient (D) approaching the quantum limit D ~ ħ/m*, where m* is the quasi-particle effective mass.

  5. Chapter 27. Superconductors

    International Nuclear Information System (INIS)

    Vavra, O.

    2007-01-01

    In this chapter author deals with superconductors and superconductivity. Different chemical materials used as high-temperature superconductors are presented. Some applications of superconductivity are presented.

  6. Methodological approach of load sintering of ceramics (superconductor, alumina, alumina-aluminium nitride-magnesia system)

    International Nuclear Information System (INIS)

    Roy, J.F.

    1993-05-01

    Sintering parameters knowledge of ceramic powders by improvements of a high temperature pressing (computer piloting and data acquiring) allow a better control of fabrication and of the desired properties (mechanical, electro-magnetic...). By using experiences plan, maximum of informations are obtained with a minimum of experimental tests. This is applied to the sintering of three compounds; for YBaCuO, the superconductive phase is obtained at 450 deg and without post heat treatment; for Al 2 O 3 , mechanical properties and a partial microstructure controls are obtained; for the Al 2 O 3 -AlN-MgO system, an optimization of the mechanical properties is obtained. (A.B.). 63 refs., figs., tabs

  7. Vortex lines in layered superconductors. II. Pinning and critical currents in high temperature superconductors

    Science.gov (United States)

    Manuel, P.

    1994-02-01

    In this article, a qualitative survey is given on the various phenomena which influence the critical current of high temperature superconductors. Critical current is defined as a property related to a non-zero electric field criterion, the level of which is fixed by experimental considerations, or efficiency requirements of applications. The presentation is restricted to extrinsic intragranular critical current, which depends in a complex way on the interplay between the characteristics of pinning centres and the properties of the vortex lattice. The discussion is focussed on the configuration {B} / / {c}, which contains the main elements of this problem. Differences of behaviour between Y(123) and BSCCO (Bi(2212) or Bi(2223)) are analysed in the context of their respective anisotropy factors. Possible regimes for pinning and creep are discussed in various temperature domains. From critical current results, a strong pinning regime is found to occur in BSCCO, whereas the pinning strength in Y(123) is still an open question. The thermal decrease of critical current allows a collective creep regime to appear in both materials, but at different temperature ranges. The disappearance of correlation effects near the irreversibility line results in a fall of the effective pinning energy. We show that in BSCCO, the effective pinning energy deduced from experimental results is not in agreement with pinning by randomly dispersed oxygen vacancies. Finally, we shortly describe the microstructures which could allow a more efficient pinning in future materials. On effectue une présentation qualitative des divers phénomènes qui contrôlent la valeur du courant critique dans les supraconducteurs à haute température. La notion de courant critique qui est utilisée est reliée à un critère de champ électrique non nul, fixé par des considérations expérimentales ou des exigences de rendement pour les applications. On se restreint au problème des courants critiques

  8. Local antiferromagnetic exchange and collaborative Fermi surface as key ingredients of high temperature superconductors

    Science.gov (United States)

    Hu, Jiangping; Ding, Hong

    2012-01-01

    Cuprates, ferropnictides and ferrochalcogenides are three classes of unconventional high temperature superconductors, who share similar phase diagrams in which superconductivity develops after a magnetic order is suppressed, suggesting a strong interplay between superconductivity and magnetism, although the exact picture of this interplay remains elusive. Here we show that there is a direct bridge connecting antiferromagnetic exchange interactions determined in the parent compounds of these materials to the superconducting gap functions observed in the corresponding superconducting materials: in all high temperature superconductors, the Fermi surface topology matches the form factor of the pairing symmetry favored by local magnetic exchange interactions. We suggest that this match offers a principle guide to search for new high temperature superconductors. PMID:22536479

  9. An explanation of the irreversibility behavior in the highly- anisotropic high-temperature superconductors

    International Nuclear Information System (INIS)

    Gray, K.E.; Kim, D.H.

    1991-01-01

    The wide temperature range of the reversible, lossy state of the new high-temperature superconductors in a magnetic field was recognized soon after their discovery. This behavior, which had gone virtually undetected in conventional superconductors, has generated considerable interest, both for a fundamental understanding of the HTS and because it degrades the performance of HTS for finite-field applications. We show that recently proposed explanation of this behavior for the highly-anisotropic high-temperature superconductors, as a dimensional crossover of the magnetic vortices, is strongly supported by recent experiments on a Bi 2 Sr 2 CaCu 2 O x single crystal using the high-Q mechanical oscillator techniques

  10. Localized temperature stability in Low Temperature Cofired Ceramics (LTCC).

    Energy Technology Data Exchange (ETDEWEB)

    Dai, Steven Xunhu; Hsieh, Lung-Hwa.

    2012-04-01

    The base dielectrics of commercial low temperature cofired ceramics (LTCC) systems have a temperature coefficient of resonant frequency ({tau}{sub f}) in the range -50 {approx} -80 ppm/C. In this research we explored a method to realize zero or near zero {tau}{sub f} resonators by incorporating {tau}{sub f} compensating materials locally into a multilayer LTCC structure. To select composition for {tau}{sub f} adjustment, {tau}{sub f} compensating materials with different amount of titanates were formulated, synthesized, and characterized. Chemical interactions and physical compatibility between the {tau}{sub f} modifiers and the host LTCC dielectrics were investigated. Studies on stripline (SL) resonator panels with multiple compensating dielectrics revealed that: 1) compositions using SrTiO{sub 3} provide the largest {tau}{sub f} adjustment among titanates, 2) the {tau}{sub f} compensation is proportional to the amount of SrTiO{sub 3} in compensating materials, as well as the thickness of the compensating layer, and 3) the most effective {tau}{sub f} compensation is achieved when the compensating dielectric is integrated next to the SL. Using the effective dielectric constant of a heterogeneous layered dielectric structure, results from Method of Momentum (MoM) electromagnetic simulations are consistent with the experimental observations.

  11. The superconductor

    International Nuclear Information System (INIS)

    Lad, J.K.

    1979-01-01

    Techniques for fabrication of a few important superconductors like Nb, Ti and Nb 3 Sn are described. Copper or bronze or both can be used as a matrix in the superconductor. Current densities obtained for different ratios of copper to superconductor are studied. The specifications of multi-filament Nb 3 Sn superconductors are given. The relative merits of the two superconductors are discussed. The temperature range obtained is approximately 3 0 K and a magnetic field of 9T(tesla) can be achieved. (A.K.)

  12. Levitation experiment using a high-temperature superconductor coil for a plasma confinement device

    Energy Technology Data Exchange (ETDEWEB)

    Morikawa, Junji; Ogawa, Yuichi [Tokyo Univ., High Temperature Plasma Center, Tokyo (Japan); Ozawa, Daisaku [Tokyo Univ., School of Engineering, Tokyo (Japan); Yanagi, Nagato; Hamaguchi, Sinji; Mito, Toshiyuki [National Institute for Fusion Science, Toki, Gifu (Japan)

    2001-10-01

    Levitation experiments using a high-temperature superconductor coil have been carried out. A coil with a minor radius of 42 mm was fabricated with a Bi-2223 tape conductor, and immersed in the liquid nitrogen. The coil current was induced by the field-cooling method up to the critical current value. The current decay of the coil can be accounted for by the flux flow resistance and the normal resistance at the lap joint. The high-temperature superconductor coil can be levitated for 4 min or more within an accuracy of 25-30 {mu}m. (author)

  13. Levitation experiment using a high-temperature superconductor coil for a plasma confinement device

    International Nuclear Information System (INIS)

    Morikawa, Junji; Ogawa, Yuichi; Ozawa, Daisaku; Yanagi, Nagato; Hamaguchi, Sinji; Mito, Toshiyuki

    2001-01-01

    Levitation experiments using a high-temperature superconductor coil have been carried out. A coil with a minor radius of 42 mm was fabricated with a Bi-2223 tape conductor, and immersed in the liquid nitrogen. The coil current was induced by the field-cooling method up to the critical current value. The current decay of the coil can be accounted for by the flux flow resistance and the normal resistance at the lap joint. The high-temperature superconductor coil can be levitated for 4 min or more within an accuracy of 25-30 μm. (author)

  14. Levitation Experiment Using a High-Temperature Superconductor Coil for a Plasma Confinement Device

    Science.gov (United States)

    Morikawa, Junji; Ozawa, Daisaku; Ogawa, Yuichi; Yanagi, Nagato; Hamaguchi, Sinji; Mito, Toshiyuki

    2001-10-01

    Levitation experiments using a high-temperature superconductor coil have been carried out. A coil with a minor radius of 42 mm was fabricated with a Bi-2223 tape conductor, and immersed in the liquid nitrogen. The coil current was induced by the field-cooling method up to the critical current value. The current decay of the coil can be accounted for by the flux flow resistance and the normal resistance at the lap joint. The high-temperature superconductor coil can be levitated for 4 min or more within an accuracy of 25-30 μm.

  15. Microstructure and property correlations in high-temperature superconductors

    Science.gov (United States)

    Kalyanaraman, Ramakrishnan

    1998-11-01

    The work in this dissertation is intended at developing high quality device gradefilms of the high temperature (high-Tsbc) superconductor, Yttrium Barium Copper Oxide (YBCO), on MgO(001) substrates. Three approaches have been used to achieve the above goal, (i) The use of a SrTiOsb3 buffer layer, (ii) The use of Ag to enhance the growth of YBCO films and (iii) Investigation of the atomic structure-property correlations of low-angle grain boundaries in these films. Thin film heterostructures of YBCO/MgO and YBCO/SrTiOsb3/MgO were fabricated by pulsed laser deposition (PLD), using a 248 nm KrF excimer laser. Analysis of the structure and measurement of superconducting properties of the films were carried out to optimize the suitable conditions under each approach. The key findings were, (i) Single crystal-like SrTiOsb3 buffer layers can be grown and they give the highest JsbcYBCO films, (ii) An in-depth study of the role of Ag showed that it enhanced film growth of YBCO thereby improving its quality, and (iii) Low-angle boundaries in YBCO/MgO occur with two probable habit planes and the Jsbcs across them differ slightly. A systematic investigation of the crystalline quality of the SrTiOsb3 films deposited by PLD was performed as a function of oxygen partial pressure (pOsb2) and substrate temperature (Tsbc). The highest quality films were grown in the pOsb2 range of 0.1-1 mTorr at 750sp°C. The films had as-deposited x-ray diffraction rocking curve (omega) values of {˜}0.70sp° and Rutherford backscattering channeling yields (chisbmin) of 5% as compared to omega˜1.40sp° and chisbmin˜14% for the film deposited in 100 mTorr of pOsb2. The x-ray phi-scans showed epitaxial cube-on-cube alignment of the SrTiOsb3 films on MgO(001) substrates. Thermal annealing of the SrTiOsb3 films further improved the quality, and the 1 mTorr films gave omega{˜}0.13sp° and chisbmin˜2.0%. Transmission electron microscopy investigations (TEM) of these films showed that the defects in

  16. High output power reluctance electric motors with bulk high-temperature superconductor elements

    Energy Technology Data Exchange (ETDEWEB)

    Kovalev, L.K. [Moscow State Aviation Institute (Technical University) (MAI), Moscow (Russian Federation)]. E-mail: kovalev@mail.sitek.net; Ilushin, K.V.; Penkin, V.T. [Moscow State Aviation Institute (Technical University) (MAI), Moscow (RU)] [and others

    2002-05-01

    We present new types of electric machines with the rotors containing bulk high-temperature superconductor (HTS)-YBCO and Bi-Ag-elements. We discuss different schematics of hysteresis, reluctance, 'trapped field' and composed synchronous HTS machines. The two-dimensional mathematical models describing the processes in such types of HTS machines were developed on the basis of the theoretical analysis of the electrodynamic and hysteresis processes in the single-domain and polycrystal YBCO ceramic samples and plate shape Bi-Ag elements. We give the test results of the series of hysteresis, reluctance, 'trapped field' and composed with permanent magnets HTS motors with an output power rating of 0.1-18 kW and current frequencies 50 Hz and 400 Hz. These results show that in the media of liquid nitrogen the specific output power per one unit weight of the HTS motor is four to seven times better than for conventional electric machines. A comparison of the theoretical and experimental characteristics of the developed HTS motors show that they are in good agreement. We discuss the test results for a liquid nitrogen cryogenic pump system with a hysteresis 500 W HTS motor. We describe several designs of new HTS motors operating in the media of liquid nitrogen with an output power 125 kW (and more) and a power factor of more than 0.8. We discuss future applications of new types of HTS motors for aerospace technology, on-land industry and transport systems. (author)

  17. Finding new superconductors: the spin-fluctuation gateway to high Tc and possible room temperature superconductivity.

    Science.gov (United States)

    Pines, David

    2013-10-24

    We propose an experiment-based strategy for finding new high transition temperature superconductors that is based on the well-established spin fluctuation magnetic gateway to superconductivity in which the attractive quasiparticle interaction needed for superconductivity comes from their coupling to dynamical spin fluctuations originating in the proximity of the material to an antiferromagnetic state. We show how lessons learned by combining the results of almost three decades of intensive experimental and theoretical study of the cuprates with those found in the decade-long study of a strikingly similar family of unconventional heavy electron superconductors, the 115 materials, can prove helpful in carrying out that search. We conclude that, since Tc in these materials scales approximately with the strength of the interaction, J, between the nearest neighbor local moments in their parent antiferromagnetic state, there may not be a magnetic ceiling that would prevent one from discovering a room temperature superconductor.

  18. Hall viscosity of a chiral two-orbital superconductor at finite temperatures

    Science.gov (United States)

    Yazdani-Hamid, Meghdad; Shahzamanian, Mohammad Ali

    2018-06-01

    The Hall viscosity known as the anti-symmetric part of the viscosity fourth-rank tensor. Such dissipationless response which appears for systems with broken time reversal symmetry. We calculate this non-dissipative quantity for a chiral two-orbital superconductor placed in a viscoelastic magnetic field using the linear response theory and apply our calculations to the putative multiband chiral superconductor Sr2RuO4. The chirality origin of a multiband superconductor arises from the interorbital coupling of the superconducting state. This feature leads to the robustness of the Hall viscosity against temperature and impurity effects. We study the temperature effect on the Hall viscosity at the one-loop approximation.

  19. The DC Electrical Resistivity Curves of Bismuth-2212 Ceramic Superconductors: Evaluation of the Hole-Carrier Concentrations per-Cu Ion

    Directory of Open Access Journals (Sweden)

    nurmalita .

    2016-04-01

    Full Text Available In this study the samples of Bismuth ceramic superconductors were synthesized by the melt textured growth methods from a 2212 stoichiometric composition in order to obtain a large amount of pure Bi-2212. The effects of Pb substitution on the properties of Bi-based Bi2−xPbxSr2CaCu2Oy superconductor with x = 0, 0.2, and 0.4 were investigated by means of DC electrical resistivity measurements. It has been found that the hole-carrier concentrations per-Cu ion of the samples change independently of Pb content.

  20. A high temperature testing system for ceramic composites

    Science.gov (United States)

    Hemann, John

    1994-01-01

    Ceramic composites are presently being developed for high temperature use in heat engine and space power system applications. The operating temperature range is expected to be 1090 to 1650 C (2000 F to 3000 F). Very little material data is available at these temperatures and, therefore, it is desirable to thoroughly characterize the basic unidirectional fiber reinforced ceramic composite. This includes testing mainly for mechanical material properties at high temperatures. The proper conduct of such characterization tests requires the development of a tensile testing system includes unique gripping, heating, and strain measuring devices which require special considerations. The system also requires an optimized specimen shape. The purpose of this paper is to review various techniques for measuring displacements or strains, preferably at elevated temperatures. Due to current equipment limitations it is assumed that the specimen is to be tested at a temperature of 1430 C (2600F) in an oxidizing atmosphere. For the most part, previous high temperature material characterization tests, such as flexure and tensile tests, have been performed in inert atmospheres. Due to the harsh environment in which the ceramic specimen is to be tested, many conventional strain measuring techniques can not be applied. Initially a brief description of the more commonly used mechanical strain measuring techniques is given. Major advantages and disadvantages with their application to high temperature tensile testing of ceramic composites are discussed. Next, a general overview is given for various optical techniques. Advantages and disadvantages which are common to these techniques are noted. The optical methods for measuring strain or displacement are categorized into two sections. These include real-time techniques. Finally, an optical technique which offers optimum performance with the high temperature tensile testing of ceramic composites is recommended.

  1. Stiffness Evaluation of High Temperature Superconductor Bearing Stiffness for 10 kWh Superconductor Flywheel Energy Storage System

    International Nuclear Information System (INIS)

    Park, B. J.; Jung, S. Y.; Lee, J. P.; Park, B. C.; Kim, C. H.; Han, S. C.; Du, S. G.; Han, Y. H.; Sung, T. H.

    2009-01-01

    A superconductor flywheel energy storage(SFES) system is mainly act an electro-mechanical battery which transfers mechanical energy into electrical form and vice versa. SFES system consists of a pair of non-contacting High Temperature Superconductor (HTS) bearings with a very low frictional loss. But it is essential to design an efficient HTS bearing considering with rotor dynamic properties through correct calculation of stiffness in order to support a huge composite flywheel rotor with high energy storage density. Static properties of HTS bearings provide data to solve problems which may occur easily in a running system. Since stiffness to counter vibration is the main parameter in designing an HTS bearing system, we investigate HTS bearing magnetic force through static properties between the Permanent Magnet(PM) and HTS. We measured axial / radial stiffness and found bearing stiffness can be easily changed by activated vibration direction between PM and HTS bulk. These results are used to determine the optimal design for a 10 kWh SFES.

  2. Physics and Materials Science of High Temperature Superconductors

    Science.gov (United States)

    1989-08-26

    30 M. Nikolo: Effect of Texture and Density on Grain Coupling of Sintered Y-Ba-Cu-O Superconductors 11:30 - 12:00 A. SzAsz : The Symmetries and High...The Hall coefficient is always positive and obeys the RH (x T- 1 law . The I Hall mobility p2-I2 < I cm2/V.S. At T < Tc, the thermoelectric power equals...461561 80-6550 Prof. A. Szasz PP Dr. Martin Schwarz PP Eotvos University Angewandte Physik Muzeum Krt. 6-8 Hoechst AG H-1088 Budapest Hungary Gebaeude

  3. Quantum critical point in high-temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Shaginyan, V.R. [Petersburg Nuclear Physics Institute, RAS, Gatchina 188300 (Russian Federation); Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel)], E-mail: vrshag@thd.pnpi.spb.ru; Amusia, M.Ya. [Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel); Popov, K.G. [Komi Science Center, Ural Division, RAS, Syktyvkar 167982 (Russian Federation); Stephanovich, V.A. [Opole University, Institute of Mathematics and Informatics, Opole 45-052 (Poland)], E-mail: stef@math.uni.opole.pl

    2009-02-02

    Recently, in high-T{sub c} superconductors (HTSC), exciting measurements have been performed revealing their physics in superconducting and pseudogap states and in normal one induced by the application of magnetic field, when the transition from non-Fermi liquid to Landau-Fermi liquid behavior occurs. We employ a theory, based on fermion condensation quantum phase transition which is able to explain facts obtained in the measurements. We also show, that in spite of very different microscopic nature of HTSC, heavy-fermion metals and 2D {sup 3}He, the physical properties of these three classes of substances are similar to each other.

  4. Single crystal NMR studies of high temperature superconductors

    International Nuclear Information System (INIS)

    Pennington, C.H.; Durand, D.J.; Zax, D.B.; Slichter, C.P.; Rice, J.P.; Bukowski, E.D.; Ginsberg, D.M.

    1989-01-01

    The authors report Cu NMR studies in the normal state of a single crystal of the T/sub c/ = 90 K superconductor YBa 2 Cu 3 O/sub 7/minus/δ/. The authors have measured the magnetic shift tensor, the electric field gradient tensor, the nuclear spin-lattice relaxation rate tensor, and the time dependence and functional form of the transverse decay. From these data they obtain information about the charge state and magnetic state of the Cu atoms, and the existence and size of the electronic exchange coupling between spins of adjacent Cu atoms. 18 refs., 3 figs., 2 tabs

  5. Theoretical upper critical field Hc2 for inhomogeneous high temperature superconductors

    International Nuclear Information System (INIS)

    Caixeiro, E.S.; Gonzalez, J.L.; Mello, E.V.L. de

    2004-01-01

    We present the theoretical upper critical field H c2 (T) of the high temperature superconductors (HTSC), calculated through a linearized Ginzburg-Landau equation modified to consider the intrinsic inhomogeneity of the HTSC. The unusual behavior of H c2 (T) for these compounds, and other properties like the Meissner and Nernst effects detected at temperatures much higher than the critical temperature T c of the sample, are explained by the approach

  6. Experimental Consequences of Mottness in High-Temperature Copper-Oxide Superconductors

    Science.gov (United States)

    Chakraborty, Shiladitya

    2009-01-01

    It has been more than two decades since the copper-oxide high temperature superconductors were discovered. However, building a satisfactory theoretical framework to study these compounds still remains one of the major challenges in condensed matter physics. In addition to the mechanism of superconductivity, understanding the properties of the…

  7. Three-dimensionality of field-induced magnetism in a high-temperature superconductor

    DEFF Research Database (Denmark)

    Lake, B.; Lefmann, K.; Christensen, N.B.

    2005-01-01

    Many physical properties of high-temperature superconductors are two-dimensional phenomena derived from their square-planar CuO(2) building blocks. This is especially true of the magnetism from the copper ions. As mobile charge carriers enter the CuO(2) layers, the antiferromagnetism of the parent...

  8. Eight-fold quantum states blossom in a high-temperature superconductor

    CERN Multimedia

    2003-01-01

    "Researchers based at Lawrence Berkeley National Laboratory and the University of California at Berkeley have used a scanning tunneling microscope (STM) to reveal eight-fold patterns of quasiparticle interference in the high-temperature superconductor Bi-2212 (bismuth strontium calcium copper oxide)" (2 pages).

  9. Analysis of flux-flow curves in superconductors as a function of temperature

    International Nuclear Information System (INIS)

    Boboshko, N.

    1978-01-01

    A phenomenological method to analyse the experimental data of flux-flow resistivity in superconductors as a function of temperature is proposed and successfully applied to existing data for t = kappa >= 0.07. An empirical curve relating the flux-flow resistivity with the Ginsburg-Landau parameter kappa was obtained. (author)

  10. Critical currents and thermally activated flux motion in high-temperature superconductors

    NARCIS (Netherlands)

    Palstra, T.T.M.; Batlogg, B.; Dover, R.B. van; Schneemeyer, L.F.; Waszczak, J.V.

    1989-01-01

    We have measured the resistance below Tc of single crystals of the high-temperature superconductors Ba2YCu3O7 and Bi2.2Sr2Ca0.8Cu2O8+δ in magnetic fields up to 12 T. The resistive transition of both compounds is dominated by intrinsic dissipation which is thermally activated, resulting in an

  11. Low critical temperature superconductors for electromagnets; Supraconducteurs a basse temperature critique pour electroaimants

    Energy Technology Data Exchange (ETDEWEB)

    Devred, A

    2002-07-01

    After a brief history of the main discoveries in applied superconductivity (section 1), we discuss the structure and properties of NbTi and Nb3 Sn (section 2). Then, we explain why low critical-temperature superconductors are produced under the form of multifilamentary composites (section 3), and we review the manufacturing processes of NbTi and Nb3Sn wires (section 4). We follow by a description of the transition from the superconducting to the normal resistive state of multifilamentary composite wires (section 5) and we detail their magnetization properties section 6). Last, we present the most commonly used cable configurations (section 7) and we provide simple formulae illustrating on a few examples the computation of losses generated under time-varying magnetic fields (section 8). (author)

  12. Low-temperature rapid synthesis and superconductivity of Fe-based oxypnictide superconductors.

    Science.gov (United States)

    Fang, Ai-Hua; Huang, Fu-Qiang; Xie, Xiao-Ming; Jiang, Mian-Heng

    2010-03-17

    Fe-based oxypnictide superconductors were successfully synthesized at lower reaction temperatures and with shorter reaction times made possible by starting with less stable compounds, which provide a larger driving force for reactions. Using ball-milled powders of intermediate compounds, phase-pure superconductors with T(c) above 50 K were synthesized at 1173 K in 20 min. This method is particularly advantageous for retaining F, a volatile dopant that enhances superconductivity. Bulk superconductivity and high upper critical fields up to 392 T in Sm(0.85)Nd(0.15)FeAsO(0.85)F(0.15) were demonstrated.

  13. Fracture analysis of a transversely isotropic high temperature superconductor strip based on real fundamental solutions

    Science.gov (United States)

    Gao, Zhiwen; Zhou, Youhe

    2015-04-01

    Real fundamental solution for fracture problem of transversely isotropic high temperature superconductor (HTS) strip is obtained. The superconductor E-J constitutive law is characterized by the Bean model where the critical current density is independent of the flux density. Fracture analysis is performed by the methods of singular integral equations which are solved numerically by Gauss-Lobatto-Chybeshev (GSL) collocation method. To guarantee a satisfactory accuracy, the convergence behavior of the kernel function is investigated. Numerical results of fracture parameters are obtained and the effects of the geometric characteristics, applied magnetic field and critical current density on the stress intensity factors (SIF) are discussed.

  14. Maglev system concept using 20-K high-temperature superconductors and hyperconductors

    Science.gov (United States)

    Hull, J. R.; He, Jianliang

    A magnetically levitated high-speed ground transportation concept is proposed that uses high-temperature superconductors or hyperconductors, cooled by liquid hydrogen at 20 K, to provide levitation. An on-board hydrogen-powered turbine/generator provides electricity for propulsion by linear induction motors. The liquid hydrogen is used to cool the superconductors and the windings of the generator and motors before combusting in the turbine. The principal advantage of this system is the potential to greatly reduce the cost of the guideway, which is completely passive.

  15. Computer modelling of high-temperature superconductors using an A-V formulation

    International Nuclear Information System (INIS)

    Ruiz-Alonso, D; Coombs, T; Campbell, A M

    2004-01-01

    Numerical methods for calculating the current and field distribution in high-temperature superconductors under non-uniform time-varying fields are being investigated. The highly non-linear behaviour of superconductors makes them difficult to analyse and computationally expensive. This non-linear behaviour is often accounted for through a non-linear E-J constitutive law. This paper proposes a fast method based on the finite element method to solve 2D and axially symmetric problems that contain superconducting materials. An E-J power law together with an A-V formulation is used to calculate the induction of currents in the superconductor due to time-varying external magnetic fields or forced transport current. Experimental data of a magnet-above-superconductor system is obtained in order to validate the model. In the experimental set-up a magnet is brought towards a superconducting puck at different speed rates and is also vibrated on top of it. The force between the magnet and the superconductor is measured and is found to vary with both time and frequency of excitation

  16. Computer modelling of high-temperature superconductors using an A-V formulation

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz-Alonso, D; Coombs, T; Campbell, A M [Cambridge University Engineering Department, Trumpington Street, Cambridge, CB2 1PZ (United Kingdom)

    2004-05-01

    Numerical methods for calculating the current and field distribution in high-temperature superconductors under non-uniform time-varying fields are being investigated. The highly non-linear behaviour of superconductors makes them difficult to analyse and computationally expensive. This non-linear behaviour is often accounted for through a non-linear E-J constitutive law. This paper proposes a fast method based on the finite element method to solve 2D and axially symmetric problems that contain superconducting materials. An E-J power law together with an A-V formulation is used to calculate the induction of currents in the superconductor due to time-varying external magnetic fields or forced transport current. Experimental data of a magnet-above-superconductor system is obtained in order to validate the model. In the experimental set-up a magnet is brought towards a superconducting puck at different speed rates and is also vibrated on top of it. The force between the magnet and the superconductor is measured and is found to vary with both time and frequency of excitation.

  17. Spatially resolved electronic structure inside and outside the vortex cores of a high-temperature superconductor

    Science.gov (United States)

    Mitrović, V. F.; Sigmund, E. E.; Eschrig, M.; Bachman, H. N.; Halperin, W. P.; Reyes, A. P.; Kuhns, P.; Moulton, W. G.

    2001-10-01

    Puzzling aspects of high-transition-temperature (high-Tc) superconductors include the prevalence of magnetism in the normal state and the persistence of superconductivity in high magnetic fields. Superconductivity and magnetism generally are thought to be incompatible, based on what is known about conventional superconductors. Recent results, however, indicate that antiferromagnetism can appear in the superconducting state of a high-Tc superconductor in the presence of an applied magnetic field. Magnetic fields penetrate a superconductor in the form of quantized flux lines, each of which represents a vortex of supercurrents. Superconductivity is suppressed in the core of the vortex and it has been suggested that antiferromagnetism might develop there. Here we report the results of a high-field nuclear-magnetic-resonance (NMR) imaging experiment in which we spatially resolve the electronic structure of near-optimally doped YBa2Cu3O7-δ inside and outside vortex cores. Outside the cores, we find strong antiferromagnetic fluctuations, whereas inside we detect electronic states that are rather different from those found in conventional superconductors.

  18. Studies of superconductors using a low-temperature, high-field scanning tunneling microscope

    International Nuclear Information System (INIS)

    Kirtley, J.R.; Feenstra, R.M.; Fein, A.P.

    1988-01-01

    We have developed a scanning tunneling microscope (STM) capable of operating at temperatures as low as 0.4 K and fields as high as 8 T. We have used this STM to study the energy gap of the high-T/sub c/ superconductors La--Sr--Cu--O and Y--Ba--Cu--O. We find that the reduced gap for these oxide superconductors falls in the range 3<2Δ/k/sub B/T/sub c/<7, for polycrystalline, single-crystal, and thin-film samples. We have also simultaneously imaged the surface topography and superconducting energy gap for thin films of the granular superconductor NbN. We occasionally see regions with smaller best-fit gaps that correlate with surface topographical features, but have been unable so far to image flux vortices

  19. Magnetization hysteresis and history effects in conventional and high temperature superconductors

    International Nuclear Information System (INIS)

    Chaddah, P.

    1990-01-01

    The magnetization in hard superconductors is irreversible and history-dependent, and cannot be a priori compared with the equilibrium magnetization. These features have gained prominence in the high T c superconductors (HTSC) where the short coherence length presumably leads to intrinsic pinning. Various experimental features, first noticed in the HTSC, are explained by an extension of Bean's macroscopic model to include temperature variations and the field dependence of J c . This paper discusses recent measurements of history effects in niobium and show their similarities with other published data on HTSC. The authors also present our calculations of magnetization behaviour in hard superconductors of sample-shapes having a non-zero demagnetization factor

  20. Application of high temperature superconductors for optimization of regime of the electroenergetic system

    International Nuclear Information System (INIS)

    Manusov, V.Z.; Mikheev, P.A.

    2005-01-01

    Application of the phenomenon of superconductivity in the energetic systems, as in the form of longitudinal engine, also in the transverse appearance (changing of the regime of neutral) is considerate in this article. In the normal regimes of the work of net it is profitable to have less resistance for contraction loss of the capability in the network and decrease of the tension, in emergency state ground return, on the contrary, from the security and safety point of view the work of such resistance will not arrange. Major properties of superconductors are their ability to change electrical parameters (in particular electric resistance) in dependence of the size of current crossing over them, notably nonlinearity of their volt-ampere characteristics. A high temperature superconductor, on the score of economical appropriateness of cooling of superconductor with liquid nitrogen instead of liquid gel is considered

  1. Effect of texture on grain boundary misorientation distributions in polycrystalline high temperature superconductors

    International Nuclear Information System (INIS)

    Goyal, A.; Specht, E.D.; Kroeger, D.M.; Mason, T.A.

    1996-01-01

    Computer simulations were performed to determine the most probable grain boundary misorientation distribution (GBMD) in model polycrystalline superconductors. GBMDs in polycrystalline superconductors can be expected to dictate the macroscopic transport critical current density, J c . Calculations were performed by simulating model polycrystals and then determining the GBMD. Such distributions were calculated for random materials having cubic, tetragonal, and orthorhombic crystal symmetry. In addition, since most high temperature superconductors are tetragonal or pseudotetragonal, the effect of macroscopic uniaxial and biaxial grain orientation texture on the GBMD was determined for tetragonal materials. It is found that macroscopic texture drastically alters the grain boundary misorientation distribution. The fraction of low angle boundaries increases significantly with uniaxial and biaxial texture. The results of this study are important in correlating the macroscopic transport J c with the measured grain orientation texture as determined by x-ray diffraction copyright 1996 American Institute of Physics

  2. The design of high-Tc superconductors - Room-temperature superconductivity?

    International Nuclear Information System (INIS)

    Tallon, J.L.; Storey, J.G.; Mallett, B.

    2012-01-01

    This year is the centennial of the discovery of superconductivity and the 25th anniversary of the discovery of high-T c superconductors (HTS). Though we still do not fully understand how HTS work, the basic rules of design can be determined from studying their systematics. We know what to do to increase T c and, more importantly, what to do to increase critical current density J c . This in turn lays down a challenge for the chemist. Can the ideal design be synthesized? More importantly, what are the limits? Can one make a room-temperature superconductor? In fact fluctuations place strict constraints on this objective and provide important guidelines for the design of the ideal superconductor.

  3. Magneto-optical Kerr-effect at low temperatures. Investigation of superconductor/ferromagnet heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Zahn, Patrick; Bayer, Jonas [Max Planck Institute for Intelligent Systems, Heisenbergstrasse 3, 70569 Stuttgart (Germany); Institute for Innovative Surfaces FINO, Aalen University, Beethovenstrasse 1, 73430 Aalen (Germany); Stahl, Claudia; Ruoss, Stephen; Graefe, Joachim; Schuetz, Gisela [Max Planck Institute for Intelligent Systems, Heisenbergstrasse 3, 70569 Stuttgart (Germany); Albrecht, Joachim [Institute for Innovative Surfaces FINO, Aalen University, Beethovenstrasse 1, 73430 Aalen (Germany)

    2016-07-01

    With XMCD microscopy it is possible to visualize the critical current density of the superconductor YBCO with high spatial resolution. Therefore, soft magnetic CoFeB is introduced as sensor layer. The magnetic stray fields of the supercurrents lead to a local reorientation of the magnetic moments in the ferromagnet, which are then imaged via X-ray microscopy. These experiments have to be carried out at the scanning X-ray microscope MAXYMUS at the synchrotron Bessy II in Berlin. For that purpose pre-characterization of the sensor is highly desirable: Magnetic interactions between the superconductor and the ferromagnetic sensor layer have been investigated at low temperatures using Kerr-effect measurements. Therefore hysteresis loops are obtained by a sophisticated magnet and field ramping setup within the NanoMOKE3 system. The results are used to optimize the ferromagnetic sensor layer for XMCD microscopy of superconductors.

  4. Transport properties of high-temperature superconductors: Surface vs bulk effect

    International Nuclear Information System (INIS)

    Burlachkov, L.; Koshelev, A.E.; Vinokur, V.M.

    1996-01-01

    We investigate surface-related transport properties of high-temperature superconductors. We find the mean vortex velocity under applied transport current determined by the activation energies for vortex penetration and exit through the Bean-Livingston barrier. We determine the current distribution between the surfaces of superconductor and the field and current dependencies of the transport activation energies. For a three-dimensional superconductor the transport activation energy, U s 3D , is found to decrease with the external field, H, and transport current, J, as U s 3D ∝H -1/2 and U s 3D ∝J -1/2 , respectively. In the quasi-two-dimensional compounds, U s 2D decays logarithmically with field and current. The interplay between the surface and the bulk contributions to the transport properties, such as current-voltage characteristics, is discussed. copyright 1996 The American Physical Society

  5. Manufacturing of Superconductors

    DEFF Research Database (Denmark)

    Bech, Jakob Ilsted; Bay, Niels

    Superconducting tapes based on the ceramic high temperature superconductor (HTS) is a new promising product for high current applications such as electro-magnets and current transmission cables. The tapes are made by the oxide powder in tube (OPIT) method implying drawing and rolling of silver...... tubes containing ceramic powder. The final product is a composite tape, where ceramic superconducting fibres are embedded in a silver matrix. The critical current density Je [kA/cm 2 ] is the primary quality parameter of the product. The quality of the superconducting tape depends very much...... in the individual fibres. · The stresses and strains in the deformation zone are analysed. It is concluded that more detailed mechanical tests and a more detailed constitutive plasticity model is desirable in order to improve the precision of the numerical modelling. New test equipment is designed implying the new...

  6. Low temperature sintering of fluorapatite glass-ceramics

    Science.gov (United States)

    Denry, Isabelle; Holloway, Julie A.

    2014-01-01

    Fluorapatite glass-ceramics have been shown to be excellent candidates as scaffold materials for bone grafts, however, scaffold production by sintering is hindered by concurrent crystallization of the glass. Our goal was to investigate the effect of Ca/Al ratio on the sintering behavior of Nb-doped fluorapatite-based glasses in the SiO2-Al2O3-P2O5-MgO-Na2O-K2O-CaO-CaF2 system. Glass compositions with Ca/Al ratio of 1 (A), 2 (B), 4 (C) and 19 (D) were prepared by twice melting at 1525°C for 3h. Glasses were either cast as cylindrical ingots or ground into powders. Disc-shaped specimens were prepared by either sectioning from the ingots or powder-compacting in a mold, followed by heat treatment at temperatures ranging between 700 and 1050°C for 1h. The density was measured on both sintered specimens and heat treated discs as controls. The degree of sintering was determined from these measurements. XRD showed that fluorapatite crystallized in all glass-ceramics. A high degree of sintering was achieved at 775°C for glass-ceramic D (98.99±0.04%), and 900°C for glass-ceramic C (91.31±0.10). Glass-ceramics A or B were only partially sintered at 1000°C (63.6±0.8% and 74.1±1.5%, respectively). SEM revealed a unique microstructure of micron-sized spherulitic fluorapatite crystals in glass-ceramics C and D. Increasing the Ca/Al ratio promoted low temperature sintering of fluorapatite glass-ceramics, which are traditionally difficult to sinter. PMID:24252652

  7. Low temperature sintering of fluorapatite glass-ceramics.

    Science.gov (United States)

    Denry, Isabelle; Holloway, Julie A

    2014-02-01

    Fluorapatite glass-ceramics have been shown to be excellent candidates as scaffold materials for bone grafts, however, scaffold production by sintering is hindered by concurrent crystallization of the glass. Objective, our goal was to investigate the effect of Ca/Al ratio on the sintering behavior of Nb-doped fluorapatite-based glasses in the SiO2-Al2O3-P2O5-MgO-Na2O-K2O-CaO-CaF2 system. Methods, glass compositions with Ca/Al ratio of 1 (A), 2 (B), 4 (C) and 19 (D) were prepared by twice melting at 1525°C for 3h. Glasses were either cast as cylindrical ingots or ground into powders. Disk-shaped specimens were prepared by either sectioning from the ingots or powder-compacting in a mold, followed by heat treatment at temperatures ranging between 700 and 1050°C for 1h. The density was measured on both sintered specimens and heat treated discs as controls. The degree of sintering was determined from these measurements. Results and Significance XRD showed that fluorapatite crystallized in all glass-ceramics. A high degree of sintering was achieved at 775°C for glass-ceramic D (98.99±0.04%), and 900°C for glass-ceramic C (91.31±0.10). Glass-ceramics A or B were only partially sintered at 1000°C (63.6±0.8% and 74.1±1.5%, respectively). SEM revealed a unique microstructure of micron-sized spherulitic fluorapatite crystals in glass-ceramics C and D. Increasing the Ca/Al ratio promoted low temperature sintering of fluorapatite glass-ceramics, which are traditionally difficult to sinter. Copyright © 2013 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  8. Temperature dependence of high field electromechanical coupling in ferroelectric ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Weaver, P M; Cain, M G; Stewart, M, E-mail: paul.weaver@npl.co.u [National Physical Laboratory, Hampton Road, Teddington, Middlesex, TW11 0LW (United Kingdom)

    2010-04-28

    A study of the temperature dependence of the electromechanical response of ferroelectric lead zirconate titanate (PZT) ceramics at high electric fields (up to 1.3 kV mm{sup -1}) is reported. Simultaneous measurements were performed of strain, electric field and polarization to form a complete response map from room temperature up to 200 {sup 0}C. An electrostrictive model is shown to provide an accurate description of the electromechanical response to high levels of induced polarization and electric field. This provides a method for decoupling strain contributions from thermal expansion and polarization changes. Direct measurements of electrostriction and thermal expansion, above and below the Curie temperature, are reported. Electrostriction coefficients are shown to be temperature dependent in these ceramic materials, with different values above and below the Curie temperature.

  9. Mechanical Properties of Ceramics for High Temperature Applications

    Science.gov (United States)

    1976-12-01

    meets another aim of gas turbine ceramics. Temperature measuring by optical pyrometer gives here a reproducibility of approximately 150 C. The...with a similar acoustic impedence to the host material (e.g., certain inclusions, large grains) will be minimal, signal averaging instrumentation

  10. Magic Doping Fractions in High-Temperature Superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Komiya, Seiki; /CRIEPI, Tokyo; Chen, Han-Dong; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.; Ando, Yoichi; /CRIEPI, Tokyo

    2010-01-15

    We report hole-doping dependence of the in-plane resistivity {rho}{sub ab} in a cuprate superconductor La{sub 2-x}Sr{sub x}CuO{sub 4}, carefully examined using a series of high-quality single crystals. Our detailed measurements find a tendency towards charge ordering at particular rational hole doping fractions of 1/16, 3/32, 1/8, and 3/16. This observation appears to suggest a specific form of charge order and is most consistent with the recent theoretical prediction of the checkerboard-type ordering of the Cooper pairs at rational doping fractions x = (2m + 1)/2{sup n}, with integers m and n.

  11. Vortex-line fluctuations in model high-temperature superconductors

    International Nuclear Information System (INIS)

    Li, Y.; Teitel, S.

    1993-01-01

    We carry out Monte Carlo simulations of the uniformly frustrated three-dimensional XY model, as a model for vortex-line fluctuations in a high-T c superconductor in an external magnetic field. A density of vortex lines of f=1/25 is considered. We find two sharp phase transitions. The low-T superconducting phase is an ordered vortex-line lattice. The high-T normal phase is a vortex-line liquid, with much entangling, cutting, and loop excitations. An intermediate phase is found, which is characterized as a vortex-line liquid of disentangled, approximately straight, lines. In this phase, the system displays superconducting properties in the direction parallel to the magnetic field, but normal behavior in planes perpendicular to the field. A detailed analysis of the vortex structure function is carried out

  12. Introduction to the physics of high temperature superconductors

    International Nuclear Information System (INIS)

    Enz, C.P.

    1988-01-01

    For the benefit of non-specialist readers the main stations in the history of superconductivity are revisited. Against this background the physical properties believed to be crucial for the new superconductors are then reviewed. In a second step, an analysis of the main theoretical ideas is attempted. This discussion starts with a characterization of the groundstate and continues with an enumeration of the possible excitations. Finally, the proposed pairing and condensation mechanisms are reviewed. No attempt of completeness is made, neither with regard to the experimental results nor to the theoretical models. The aim is to get a glimpse at the physics behind the enormous flow of information in this new field of research. (orig.)

  13. The influence of measurement and relaxation time on flux jumps in high temperature superconductors

    International Nuclear Information System (INIS)

    Yang Xiaobin; Zhou Youhe; Tu Shandong

    2010-01-01

    The influence of the magnetization and relaxation time on flux jumps in high temperature superconductors (HTSC) under varying magnetic field is studied using the fundamental electromagnetic field equations and the thermal diffusion equation; temperature variety corresponding to flux jump is also discussed. We find that for a low sweep rate of the applied magnetic field, the measurement and relaxation times can reduce flux jump and to constrain the number of flux jumps, even stabilizing the HTSC, since much heat produced by the motion of magnetic flux can transfer into coolant during the measurement and relaxation times. As high temperature superconductors are subjected to a high sweep rate or a strong pulsed magnetic field, magnetization undergoes from stability or oscillation to jump for different pause times. And the period of temperature oscillation is equal to the measurement and relaxation time.

  14. The refrigeration of high temperature superconductors between 25K and 65K

    International Nuclear Information System (INIS)

    Richardson, R.N.; Scurlock, R.G.; Tavner, A.C.R.

    1996-01-01

    The present state of the art indicates that acceptable j - H characteristics for power applications of the new high Tc superconductors will only be achieved using materials at temperatures below liquid nitrogen temperature. A boiling point of 27.1K and high specific cooling capacity make neon an eminently suitable choice of refrigerant at these temperatures. A cryostat has been constructed which employs a two stage Gifford-McMahon cooler to liquefy neon gas. The cryostat contains up to 5 litres of liquid neon which can be used for open-quote in-situ close-quote experiments or transfer to another cryostat. Another set of cryostats are being used with liquid nitrogen/oxygen mixtures at reduced pressure for temperatures down to 50K. All these cryostats provide a core facility for characterising and operating high T c superconductors at Southampton

  15. The influence of electric discharge on the properties of high-temperature superconductors

    International Nuclear Information System (INIS)

    Parashchuk, V.V.

    1990-01-01

    The influence is studied of pulse voltage with amplitude 100 kV and duration 100 to 200 ns on the temperature dependence of diamagnetic susceptibility of yttrium ceramics. As a result of the action of spark discharge on the ceramics, the superconducting transition parameters change. As the number of voltage pulses is increased, the diamagnetic susceptibility and the critical temperature determined by it first increase rapidly, then drop slowly. At the same time the transition in the optimum becomes more sharp. In the case of treatment in the air, Tc increases by 15 K and at discharge in liquid nitrogen by 25 K. It is found that the atmospheric air under certain conditions affects the temperature dependence of the diamagnetic susceptibility of HTSC ceramics. Treatment by a high-voltage spark decreases the susceptibility of the ceramics due to atmospheric effects. The highest efficiency of spark treatment is achieved at discharge in liquid nitrogen. (orig.)

  16. NOVEL CERAMIC MEMBRANE FOR HIGH TEMPERATURE CARBON DIOXIDE SEPARATION; SEMIANNUAL

    International Nuclear Information System (INIS)

    Jerry Y.S. Lin; Jun-ichi Ida

    2001-01-01

    This project is aimed at demonstrating technical feasibility for a lithium zirconate based dense ceramic membrane for separation of carbon dioxide from flue gas at high temperature. The research work conducted in this reporting period was focused on several fundamental issues of lithium zirconate important to the development of the dense inorganic membrane. These fundamental issues include material synthesis of lithium zirconate, phases and microstructure of lithium zirconate and structure change of lithium zirconate during sorption/desorption process. The results show difficulty to prepare the dense ceramic membrane from pure lithium zirconate, but indicate a possibility to prepare the dense inorganic membrane for carbon dioxide separation from a composite lithium zirconate

  17. High temperature properties and processes in ceramics: thermomigration

    International Nuclear Information System (INIS)

    1978-01-01

    The focus of this program is on the effects of large temperature gradients on the transport processes, the defect structure and resulting physical properties of ceramics. In particular, the transport of ions due to thermal gradients is one of the least understood phenomenon in materials science and is presumably based on fundamental understanding of thermodynamics, atomistic kinetic processes, and structure-property relationships. The purpose of this research is to systematically consider each of the elements of atomic transport due to driving forces other than composition gradients in a model ceramic system

  18. The temperature dependences of electromechanical properties of PLZT ceramics

    Science.gov (United States)

    Czerwiec, M.; Zachariasz, R.; Ilczuk, J.

    2008-02-01

    The mechanical and electrical properties in lanthanum modified lead zirconate-titanate ceramics of 5/50/50 and 10/50/50 were studied by mechanical loss Q - 1, Young's modulus E, electric permittivity ɛ and tangent of dielectric loss of angle tgδ measurements. The internal friction Q - 1 and Young modulus E measured from 290 K to 600 K shows that Curie temperature TC is located at 574 K and 435 K (1st cycle of heating) respectively for ceramic samples 5/50/50 and 10/50/50. The movement of TC in second cycle of heating to lower temperature (561 K for 5/50/50 and 420 K for 10/50/50) has been observed. Together with Q - 1 and E measurements, temperature dependences of ɛ=f(T) and tgδ=f(T) were determinated in temperature range from 300 K to 730 K. The values of TC obtained during ɛ and tgδ measurements were respectively: 560 K for 5/50/50 and 419 K for 10/50/50. These temperatures are almost as high as the temperatures obtained by internal friction Q - 1 measurements in second cycle of heating. In ceramic sample 10/50/50 the additional maximum on internal friction Q - 1 curve at the temperature 316 K was observed.

  19. High density microelectronics package using low temperature cofirable ceramics

    International Nuclear Information System (INIS)

    Fu, S.-L.; Hsi, C.-S.; Chen, L.-S.; Lin, W. K.

    1997-01-01

    Low Temperature Cofired Ceramics (LTCC) is a relative new thick film process and has many engineering and manufacturing advantages over both the sequential thick film process and high temperature cofired ceramic modules. Because of low firing temperature, low sheet resistance metal conductors, commercial thick film resistors, and thick film capacitors can be buried in or printed on the substrates. A 3-D multilayer ceramic substrate can be prepared via laminating and co-firing process. The packing density of the LTCC substrates can be increased by this 3-D packing technology. At Kaohsiung Polytechnic Institute (KPI), a LTCC substrate system has been developed for high density packaging applications, which had buried surface capacitors and resistors. The developed cordierite-glass ceramic substrate, which has similar thermal expansion as silicon chip, is a promising material for microelectronic packaging. When the substrates were sintered at temperatures between 850-900 degree centigrade, a relative density higher than 96 % can be obtained. The substrate had a dielectric constant between 5.5 and 6.5. Ruthenium-based resistor pastes were used for resistors purposes. The resistors fabricated in/on the LTCC substrates were strongly depended on the microstructures developed in the resistor films. Surface resistors were laser trimmed in order to obtain specific values for the resistors. Material with composition Pb(Fe 2/3 W 1/3 ) x (Fe l/2 Nb l/2 ) y Ti 2 O 3 was used as dielectric material of the capacitor in the substrate. The material can be sintered at temperatures between 850-930 degree centigrade, and has dielectric constant as high as 26000. After cofiring, good adhesion between dielectric and substrate layers was obtained. Combing the buried resistors and capacitors together with the lamination of LTCC layer, a 3-dimensional multilayered ceramic package was fabricated. (author)

  20. High density microelectronics package using low temperature cofirable ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Fu, S -L; Hsi, C -S; Chen, L -S; Lin, W K [Kaoshiung Polytechnic Institute Ta-Hsu, Kaoshiung (China)

    1998-12-31

    Low Temperature Cofired Ceramics (LTCC) is a relative new thick film process and has many engineering and manufacturing advantages over both the sequential thick film process and high temperature cofired ceramic modules. Because of low firing temperature, low sheet resistance metal conductors, commercial thick film resistors, and thick film capacitors can be buried in or printed on the substrates. A 3-D multilayer ceramic substrate can be prepared via laminating and co-firing process. The packing density of the LTCC substrates can be increased by this 3-D packing technology. At Kaohsiung Polytechnic Institute (KPI), a LTCC substrate system has been developed for high density packaging applications, which had buried surface capacitors and resistors. The developed cordierite-glass ceramic substrate, which has similar thermal expansion as silicon chip, is a promising material for microelectronic packaging. When the substrates were sintered at temperatures between 850-900 degree centigrade, a relative density higher than 96 % can be obtained. The substrate had a dielectric constant between 5.5 and 6.5. Ruthenium-based resistor pastes were used for resistors purposes. The resistors fabricated in/on the LTCC substrates were strongly depended on the microstructures developed in the resistor films. Surface resistors were laser trimmed in order to obtain specific values for the resistors. Material with composition Pb(Fe{sub 2/3}W{sub 1/3}){sub x}(Fe{sub l/2}Nb{sub l/2}){sub y}Ti{sub 2}O{sub 3} was used as dielectric material of the capacitor in the substrate. The material can be sintered at temperatures between 850-930 degree centigrade, and has dielectric constant as high as 26000. After cofiring, good adhesion between dielectric and substrate layers was obtained. Combing the buried resistors and capacitors together with the lamination of LTCC layer, a 3-dimensional multilayered ceramic package was fabricated. (author)

  1. Ceramic matrix composites -- Advanced high-temperature structural materials

    International Nuclear Information System (INIS)

    Lowden, R.A.; Ferber, M.K.; DiPietro, S.G.

    1995-01-01

    This symposium on Ceramic Matrix Composites: Advanced High-Temperature Structural Materials was held at the 1994 MRS Fall Meeting in Boston, Massachusetts on November 28--December 2. The symposium was sponsored by the Department of Energy's Office of Industrial Technology's Continuous Fiber Ceramic Composites Program, the Air Force Office of Scientific Research, and NASA Lewis Research Center. Among the competing materials for advanced, high-temperature applications, ceramic matrix composites are leading candidates. The symposium was organized such that papers concerning constituents--fibers and matrices--were presented first, followed by composite processing, modeling of mechanical behavior, and thermomechanical testing. More stable reinforcements are necessary to enhance the performance and life of fiber-reinforced ceramic composites, and to ensure final acceptance of these materials for high-temperature applications. Encouraging results in the areas of polymer-derived SiC fibers and single crystal oxide filaments were given, suggesting composites with improved thermomechanical properties and stability will be realized in the near future. The significance of the fiber-matrix interface in the design and performance of these materials is evident. Numerous mechanical models to relate interface properties to composite behavior, and interpret test methods and data, were enthusiastically discussed. One issue of great concern for any advanced material for use in extreme environments is stability. This theme arose frequently throughout the symposium and was the topic of focus on the final day. Fifty nine papers have been processed separately for inclusion on the data base

  2. X-ray photoelectron spectroscopy of high-temperature superconductor clean surfaces and interfaces

    International Nuclear Information System (INIS)

    Hill, D.M.

    1989-01-01

    X-ray photoelectron spectroscopy was used to determine the characteristic spectra for the high temperature superconductors La 1.85 Sr 0.15 CuO 4 , YBa 2 Cu 3 O 7-x , and Bi 2 Sr 2-x Ca 1+x Cu 2 O 8+y and their impurity phases. The oxidation state of Cu in all of these materials was predominantly Cu 2+ . The O 1s emission for clean surfaces was a single broad peak near 529 eV derived from emission from inequivalent O sites in the superconductors. The valence bands were a -6 eV wide manifold of Cu 3d-O 2p hybrid bands in the ∼ 1-7 eV binding energy range, with very low emission at E F arising from antibonding Cu 3d-O 2p orbitals. Emission from grain boundary and other impurity phases appeared at 531 eV for the O 1s core level, and in general ∼ 1-2 eV higher energy than the superconductor peak for other core levels except for Cu 2p. Impurity phases appeared in the valence bands as a shoulder at ∼ 5 eV. The amount of impurities detected was shown to be dependent on the fracture properties of the superconductors. All of the materials were shown to be stable under vacuum. The products and spatial extent of chemical reactions with Ag, Al, Al oxide, Au, Bi, Bi oxide, CaF 2 , Cu, Fe, Si, and Si oxide overlayers on these materials also were examined. Au, CaF 2 , and metal oxides deposited by activated oxidation during evaporation were non-reactive and non-disruptive of the superconductor surfaces. Ag overlayers were unique in that they disrupted the superconductor during deposition, but exhibited no evidence of any chemical reactions. Overlayers with an affinity for oxygen withdrew O from the superconductor. The O loss occurred preferentially from Cu atoms in the superconductor and disrupted the planar bonding structure

  3. Electro-physical properties of superconducting ceramic thick film prepared by partial melting method.

    Science.gov (United States)

    Lee, Sang Heon

    2013-05-01

    BiSrCaCuO superconductor thick films were prepared at several curing temperatures, and their electro-physical properties were determined to find an optimum fabrication conditions. Critical temperatures of the superconductors were decreased with increasing melting temperature, which was related to the amount of equilibrium phases of the superconducting materials with temperature. The critical temperature of BiSrCaCuO bulk and thick film superconductors were 107 K and 96 K, respectively. The variation of susceptibility of the superconductor thick film formed at 950 degrees C had multi-step-type curve for 70 G externally applied field, whereas, a superconductor thick film formed at 885 degrees C had a single step-type curve like a bulk BiSrCaCuO ceramic superconductor in the temperature-susceptibility curves. A partial melting at 865 degrees C is one of optimum conditions for making a superconductor thick film with a relatively homogeneous phase.

  4. Influence of preparation technique of ceramic superconductors on structure, mechanical and electrical properties

    International Nuclear Information System (INIS)

    Tomandl, G.; Kohl, R.

    1991-01-01

    Sol-Gel-like preparation techniques using citrate-, citrate/ethylenglycol- as well as ethylhexanoate precursors and the addition of fluorine were tested with regard to homogeneity and properties of HTSC-ceramics. A few single- and polycrystalline materials were coated with YBaCuOxide- and Bi Sr Ca Cu Oxide-films using ethylhexanoate-precursors. Interdiffusion reactions were investigated affecting the electrical properties. The best results in YBaCuOxide system were obtained using polycrystalline magnesia and silver as substrate materials. Bulk ceramics with a high degree of orientation were fabricated by reaction sintering and simultaneous external pressure. (orig.) With 44 refs., 6 tabs., 81 figs [de

  5. Comparative study of irreversibility effects in Nb foil and high temperature superconducting ceramics by μSR

    International Nuclear Information System (INIS)

    Grebinnik, V.G.; Duginov, V.N.; Zhukov, V.A.

    1990-01-01

    We present the results of investigation of superconducting niobium and high temperature ceramical superconductor La 1.9 Sr 0.1 CuO 4 by the μSR technique. The experiments with the niobium sample have confirmed high reliability of the μSR-technique in determining such characteristics of type II superconductors as T c , H c1 , H c2 , the magnetic field penetration depth λ, and the critical current density J c . The analysis of the field dependences of the distribution width and mean value of the magnetic fields on the muon when the samples are magnetized was carried out. One has revealed qualitative difference in the behaviour of the magnetic dield distribution width in Nb and LaSrCuO. While the niobium data are well described in the frame of the critical state model, application of the similar approach to the high-T c superconductor did not give satisfactory description of our experimental results. 10 refs.; 4 figs

  6. High Temperature Electrostrictive Ceramics, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — TRS Technologies proposes to develop high temperature electrostrictors from bismuth-based ferroelectrics. These materials will exhibit high strain and low loss in...

  7. An EPR methodology for measuring the London penetration depth for the ceramic superconductors

    Science.gov (United States)

    Rakvin, B.; Mahl, T. A.; Dalal, N. S.

    1990-01-01

    The use is discussed of electron paramagnetic resonance (EPR) as a quick and easily accessible method for measuring the London penetration depth, lambda for the high T(sub c) superconductors. The method utilizes the broadening of the EPR signal, due to the emergence of the magnetic flux lattice, of a free radical adsorbed on the surface of the sample. The second moment, of the EPR signal below T(sub c) is fitted to the Brandt equation for a simple triangular lattice. The precision of this method compares quite favorably with those of the more standard methods such as micro sup(+)SR, Neutron scattering, and magnetic susceptibility.

  8. Of the crystal chemistry of Ruddlesden-Porter type structures in high Tc ceramic superconductors

    International Nuclear Information System (INIS)

    Dwivedi, A.; Cormack, A.N.

    1990-01-01

    This paper reports on atomistic computer simulation employed to examine the energetics and crystal chemistry of some Ruddlesden-Popper type oxide superconductors. Similar structural patterns have been noticed in the superconducting oxides. The formation of Ruddlesden-Popper type layers (alternating slabs of rocksalt and perovskite structures) is similar in many respects to that seen in the system Sr-Ti-O. However, there are some significant differences, for example, the rocksalt and perovskite blocks in the new superconducting compounds are not necessarily electrically neutral unlike in the Sr-Ti-O system and this may well lead to significant differences in their structural chemistry

  9. Three exciting areas of experimental physical sciences : high temperature superconductors, metal clusters and super molecules of carbon

    International Nuclear Information System (INIS)

    Rao, C.N.

    1992-01-01

    The author has narrated his experience in carrying out research in three exciting areas of physical sciences. These areas are : high temperature superconductors, metal clusters and super molecules of carbon. (M.G.B.)

  10. Multilayer ceramic capacitors for pulsed power, high temperature applications

    International Nuclear Information System (INIS)

    Cygan, S.; McLarney, J.; Prymak, J.; Bohn, P.

    1991-01-01

    The performance of the multilayer ceramic capacitors (MLC) in high frequency power applications has improved significantly over the last years. One of the possible applications of MLC capacitors is the automotive industry where repetitive discharging of capacitors is required. A 0.25-μF capacitor using NPO dielectric subjected to repetitive discharging with the rate of 700 pulses per second, magnitude of 600-V and 195-A peak currents showed no degradation in performance at 298 K or 398 K even after 1 billion discharge cycles. Less than a 5-K temperature rise was observed under these conditions. The most exciting, newly emerging utilization for MLC capacitors, however, might be the high temperature application (up to 473 K for underhood utilization), where ceramic capacitors with higher volumetric efficiency as compared to glass or polymer type capacitors prove very superior. Moreover ceramic capacitors, which next to glass capacitors exhibit the greatest radiation resistance among all insulating materials (Hanks and Hamman 1971), might also be best suited in the future for high temperature operation in space environment. The pulsed power performance of the 0.25-μF NPO capacitor was evaluated under repetitive discharge conditions (200 V, 700 pps) at high temperature, 473 K, and the results are presented in this paper

  11. Advanced magneto-optical Kerr effect measurements of superconductors at low temperatures

    Directory of Open Access Journals (Sweden)

    Claudia Stahl

    2017-10-01

    Full Text Available Magneto-optical Kerr-effect (MOKE measurements of superconducting films with soft-magnetic coatings are performed at low temperatures using a laser-based MOKE set-up. An elaborate measurement scheme with internal reference allows the quantitative comparison of the temperature dependent Kerr-amplitude with the magnetic field generated by supercurrents. For this purpose, an amorphous CoFeB thin film exhibiting a large Kerr-signal is deposited directly on top of the YBCO superconductor acting as field sensing layer. It is shown that the resulting magnetic hysteresis loops of the soft-magnetic film can be used to reconstruct the electric properties of the superconductor.

  12. Modeling high-temperature superconductors and metallic alloys on the Intel iPSC/860

    International Nuclear Information System (INIS)

    Geist, G.A.; Peyton, B.W.; Shelton, W.A.; Stocks, G.M.

    1990-01-01

    Oak Ridge National Laboratory has embarked on several computational grand Challenges, which require the close cooperation of physicists, mathematicians, and computer scientists. One of these projects is the determination of the material properties of alloys form first principles and, in particular, the electronic structure of high-temperature superconductors. The physical basis for high Tc superconductivity is not well understood. The design of materials with higher critical temperatures and the ability to carry higher current densities can be greatly facilitated by the modeling and detailed study of the electronic structure of existing superconductors. This paper describes the progress to data on this project. We include a description of a self-consistent KKR-CPA method, parallelization of the model, and the incorporation of a dynamic load balancing scheme into the algorithm. We also describe the development and performance of a consolidated KKR-CPA code capable of running on CRAYs, workstations, and several parallel computers without source code modification

  13. A formulation for the critical temperature T/sub c/ of Ll2-type superconductors

    International Nuclear Information System (INIS)

    Wang Rong-Yao; Zhang Xiao

    1985-01-01

    From the examination of Ll 2 type superconductors, the superconducting critical temperature T/sub b/ of Ll 2 -type superconductors is obtained by: T/sub c/ = 15.9T/sub B/V(B)G/sub A//(√M/sub m/) V(Ll 2 )/sub m/ G/sub B/ where T/sub B/ is the superconducting critical temperature of pure B, V(B) the atomic volume in pure B, V(Ll 2 )/sub m/ the average atomic volume in the Ll 2 type compound, M/sub m/ the average atomic weight of the compound, and G/sub A/, G/sub B/ are the Gordy electronegative values. (author)

  14. Proceedings of the workshop on 'anomalous electronic states and physical properties in high-temperature superconductors'

    International Nuclear Information System (INIS)

    Arai, Masatoshi; Kajimoto, Ryoichi

    2007-03-01

    A workshop entitled 'Anomalous Electronic States and Physical Properties in High-Temperature Superconductors' was held on November 7-8, 2006 at Institute for Materials Research, Tohoku University. In the workshop, leading scientists in the field of high-T c superconductivity, both experimentalists and theorists, gathered in a hall to report the recent progress of the study, clarify the problems to be solved, and discuss the future prospects. The workshop was jointly organized by Specially Promoted Research of MEXT, Development of the 4D Spaces Access Neutron Spectrometer and Elucidation of the Mechanism of Oxide High-T c Superconductivity' (repr. by M. Arai, JAEA) and by the Inter-university Cooperative Research Program of the Institute for Materials Research, Tohoku University, 'Anomalous Electronic States and Physical Properties in High-Temperature Superconductors' (repr. by T. Tohyama, Kyoto Univ.). This report includes abstracts and materials of the presentations in the workshop. (author)

  15. NASA space applications of high-temperature superconductors

    Science.gov (United States)

    Heinen, Vernon O.; Sokoloski, Martin M.; Aron, Paul R.; Bhasin, Kul B.

    1992-01-01

    The application of superconducting technology in space has been limited by the requirement of cooling to near liquid helium temperatures. The only means of attaining these temperatures has been with cryogenic fluids which severely limits mission lifetime. The development of materials with superconducting transition temperatures (T sub c) above 77 K has made superconducting technology more attractive and feasible for employment in aerospace systems. Potential applications of high-temperature superconducting technology in cryocoolers and remote sensing, communications, and power systems are discussed.

  16. New Developments in the Theory of HTSC [High Temperature Superconductors

    Science.gov (United States)

    Abrikosov, A.A.

    1994-09-01

    The superconductor is supposed to consist of alternating layers of two kinds: (1) layers with an attractive electron interaction and an effective mass of usual magnitude, (2) layers without interaction and with a large effective mass. The overlap between the layers is assumed to be small, its energy, t, being much less than {Delta}. It is shown, that such a model explains the most peculiar property found in experiments on electronic Raman light scattering in BSCCO 2212: different threshold values for the Raman satellite measured at two different polarizations of the incident and scattered light. The tunneling conductance G(V)= dJ/dV is analyzed for the same model. In order to fit the qualitative features of experimental data, it is assumed that the tunneling probability to the normal layers is much less, than to the superconducting layers. The conductance is calculated for the case t{much_lt}{Delta}. A brief analysis is given for the case t{approximately}{Delta}, which proves that such an assumption definitely contradicts the experimental data for BSCCO. The possible nature of the electronic states in the normal layers is discussed. In connection with the experimental discovery (angle resolved photoemission spectroscopy, ARPES) of the extended saddle point singularities in the electron spectrum of a variety of HTSC consequences are derived for T{sub c} and {Delta} in a simple model. A large enhancement of superconductivity is possible if the singularity has a sufficient extension and is located close to the Fermi energy. In order to explain the anisotropy of the energy gap, observed in ARPES experiments, on the basis of the "extended saddle point singularities" an assumption is done that the Coulomb interactions are weakly screened, i.e. the Debye screening radius is much larger than the lattice period; this makes the electron interaction long ranged (E-L model).

  17. High-Temperature Superconductors as Electromagnetic Deployment and Support Structures in Spacecraft. [NASA NIAC Phase I

    Science.gov (United States)

    Getliffe, Gwendolyn V.; Inamdar, Niraj K.; Masterson, Rebecca; Miller, David W.

    2012-01-01

    This report, concluding a one-year NIAC Phase I study, describes a new structural and mechanical technique aimed at reducing the mass and increasing the deployed-to-stowed length and volume ratios of spacecraft systems. This technique uses the magnetic fields generated by electrical current passing through coils of high-temperature superconductors (HTSs) to support spacecraft structures and deploy them to operational configurations from their stowed positions inside a launch vehicle fairing.

  18. Effect of parameters of a high-temperature superconductor levitation system on the lateral force

    International Nuclear Information System (INIS)

    Yang Yong; Zheng Xiaojing

    2008-01-01

    The lateral forces on a rectangular permanent magnet above a cylindrical high-temperature superconductor during lateral traverses are simulated in two cooling conditions. The simulation is based on the finite element method and critical state model of Bean. The calculations agree well with the previous experimental data, on the basis of which the effect of initial cooling conditions, physical parameters, levitating height during lateral traverses and geometrical parameters on the lateral force is presented

  19. Theory of tunneling and photoemission spectroscopy for high-temperature superconductors

    International Nuclear Information System (INIS)

    Kouznetsov, K.; Coffey, L.

    1996-01-01

    A comprehensive analysis is presented of the tunneling conductance and angle-resolved photoemission spectra in high-temperature superconductors. It is shown that unexplained features of the tunneling and photoemission spectra such as broad backgrounds, dips, and asymmetry of the tunneling conductance can arise in a model of spin-fluctuation mediated inelastic tunneling. Effects of directionality in tunneling play an important role in determining the behavior of the tunneling conductance. copyright 1996 The American Physical Society

  20. Recent advances in high-temperature superconductor wire fabrication and applications development

    International Nuclear Information System (INIS)

    Hull, J.R.; Uherka, K.L.

    1992-01-01

    In this paper, recent advances in fabrication of high-temperature superconductor wires are summarized and detailed discussion is provided on developments in near- and intermediate-term applications. Near-term applications, using presently obtainable current densities, include liquid-nitrogen depth sensors, cryostat current leads, and magnetic bearings. Intermediate-term applications, using current densities expected to be available in the near future, include fault-current limiters and short transmission lines

  1. Concepts for using trapped-flux bulk high-temperature superconductor in motors and generators

    International Nuclear Information System (INIS)

    Hull, John R; Strasik, Michael

    2010-01-01

    We review previous concepts for using bulk high-temperature superconductors (HTSs) in motors and generators and discuss methods for using trapped-flux (TF) HTSs in motors and generators that have been recently investigated in our laboratory. We examine the expected performance of a brushless motor/generator that uses TF bulk HTSs to provide magnetomotive force, where the stator windings are used to create the TF. A key feature is the use of dysprosium for the stator and rotor cores.

  2. Superconductors with low critical temperature for electro-magnets; Supraconducteurs a basse temperature critique pour electroaimants

    Energy Technology Data Exchange (ETDEWEB)

    Devred, A

    2002-07-01

    Among the superconductors with low critical temperature that are used to build magnets, NbTi has reached a development state that allows a massive production for big equipment of physics and an industrial production in the domain of medicine imaging. The material that might challenge the supremacy of NbTi is Nb{sub 3}Sn but some technical difficulties have yet to be overcome. This report begins with a review of the different industrial processes used to produce superconducting wires based on the NbTi and Nb{sub 3}Sn materials. The transition from the superconducting state to the resistive normal state is described for both materials, the magnetizing of multi-wire superconducting cables is also presented. The author details the different patterns of wires in cables and proposes a formulary that allows the determination, in some simple cases,of energy losses that are generated in a superconducting cable by a variable magnetic field. (A.C.)

  3. Filtering properties of Thue-Morse nano-photonic crystals containing high-temperature superconductor

    Science.gov (United States)

    Talebzadeh, Robabeh; Bavaghar, Mehrdad

    2018-05-01

    In this paper, we introduced new design of quasi-periodic layered structures by choosing order two of ternary Thue-Morse structure. We considered Superconductor-dielectric photonic crystal with mirror symmetric as (ABSSAB)N(BASSBA)N composed of two kinds of nano-scale dielectric layers (A and B) and high-temperature superconductor layers where N is the number of period. This structure is assumed to be the free space. By using the transfer matrix method and the two fluid model, we theoretically study the transmission spectrum of ternary Thue-Morse superconducting photonic crystals with mirror symmetry and introduce this structure as a narrow optical filter. We showed that transmission peak so-called defect mode appears itself inside the transmission spectrum of suggested structure as same as defective layered structure. Also, we analyzed the influence of various related parameters such as the operating temperature of superconductor layer on position of defect mode. The redshift of defect mode with increasing the operating temperature was observed.

  4. Tritium release from lithium ceramics at constant temperature

    International Nuclear Information System (INIS)

    Verrall, R.A.; Miller, J.M.

    1992-02-01

    Analytic methods for post-irradiation annealing tests to measure tritium release from lithium ceramics at constant temperature are examined. Modifications to the Bertone (1) relations for distinguishing diffusion-controlled release from desorption-controlled release are shown. The methods are applied to tests on sintered LiA10 2 ; first-order desorption is shown to control tritium release for these tests

  5. Preparation of high-temperature superconducting ceramics

    International Nuclear Information System (INIS)

    Causa, M.T.; Dutrus, S.M.; Esparza, Daniel; Fainstein, Carlos; Malachevsky, M.T.; Salva, Horacio; Sanchez, Rodolfo; Steren, L.B.; Tovar, Manuel; Veglio, Nestor

    1987-01-01

    We have prepared samples of the family ABa2Cu3Ox (A=Y, Gd, Eu, Dy, Sm, Er). The powdered samples were characterized by X-ray diffraction at room temperature. We have also studied the effect of Fe impurities in YBa2Cu3Ox and EuBa2Cu3Ox. Moreover, single crystals of YBa2Cu3Ox and La(1-x)SrxCuO4 were grown using cooper oxide flux. (Author) [es

  6. Power-law temperature dependence of the inelastic-scattering rate in disordered superconductors

    International Nuclear Information System (INIS)

    Devereaux, T.P.; Belitz, D.

    1991-01-01

    We present a theory of the quasiparticle inelastic lifetime τ in in disordered superconducting films. We find that both the Coulomb and the electron-phonon contribution to τ in -1 are enhanced by disorder, and that for reasonably strong electron-phonon coupling the latter is dominant. In contrast to clean superconductors, the scattering rate is larger than the recombination rate at all temperatures. This leads to a power-law temperature dependence of τ in -1 , in agreement with experimental observations. The theory quantitatively accounts for the magnitude, disorder dependence, and temperature dependence of τ in measured in recent experiments

  7. Fermionic spectral functions in backreacting p-wave superconductors at finite temperature

    Energy Technology Data Exchange (ETDEWEB)

    Giordano, G.L.; Grandi, N.E.; Lugo, A.R. [Instituto de Física de La Plata - CONICET & Departamento de Física - UNLP,C.C. 67, 1900 La Plata (Argentina)

    2017-04-14

    We investigate the spectral function of fermions in a p-wave superconducting state, at finite both temperature and gravitational coupling, using the AdS/CFT correspondence and extending previous research. We found that, for any coupling below a critical value, the system behaves as its zero temperature limit. By increasing the coupling, the “peak-dip-hump” structure that characterizes the spectral function at fixed momenta disappears. In the region where the normal/superconductor phase transition is first order, the presence of a non-zero order parameter is reflected in the absence of rotational symmetry in the fermionic spectral function at the critical temperature.

  8. Method And Apparatus For Evaluatin Of High Temperature Superconductors

    Science.gov (United States)

    Fishman, Ilya M.; Kino, Gordon S.

    1996-11-12

    A technique for evaluation of high-T.sub.c superconducting films and single crystals is based on measurement of temperature dependence of differential optical reflectivity of high-T.sub.c materials. In the claimed method, specific parameters of the superconducting transition such as the critical temperature, anisotropy of the differential optical reflectivity response, and the part of the optical losses related to sample quality are measured. The apparatus for performing this technique includes pump and probe sources, cooling means for sweeping sample temperature across the critical temperature and polarization controller for controlling a state of polarization of a probe light beam.

  9. High temperature measurements of the microwave dielectric properties of ceramics

    International Nuclear Information System (INIS)

    Baeraky, T.A.

    1999-06-01

    Equipment has been developed for the measurement of dielectric properties at high temperature from 25 to 1700 deg. C in the microwave frequency range 614.97 to 3620.66 MHz using the cavity perturbation technique, to measure the permittivity of a range of ceramic materials. The complex permittivities of the standard materials, water and methanol, were measured at low temperature and compared with the other published data. A statistical analysis was made for the permittivity measurements of water and methanol using sample holders of different diameter. Also the measurements of these materials were used to compare the simple perturbation equation with its modifications and alternation correction methods for sample shape and the holes at the two endplates of the cavity. The dielectric properties of solid materials were investigated from the permittivity measurements on powder materials, shown in table 4.7, using the dielectric mixture equations. Two kinds of ceramics, oxide and nitrides, were selected for the high temperature dielectric measurements in microwave frequency ranges. Pure zirconia, yttria-stabilised zirconia, and Magnesia-stabilised zirconia are the oxide ceramics while aluminium nitride and silicon nitride are the nitride ceramics. A phase transformation from monoclinic to tetragonal was observed in pure zirconia in terms of the complex permittivity measurements, and the conduction mechanism in three regions of temperature was suggested to be ionic in the first region and a mixture of ionic and electronic in the second. The phase transition disappeared with yttria-stabilised zirconia but it was observed with magnesia-stabilised zirconia. Yttria doped zirconia was fully stabilised while magnesia stabilised was partially stabilised zirconia. The dielectric property measurements of aluminium nitride indicated that there is a transition from AIN to AlON, which suggested that the external layer of the AIN which was exposed to the air, contains alumina. It was

  10. A Hall probe technique for characterizing high-temperature superconductors

    International Nuclear Information System (INIS)

    Zhang, J.; Sheldon, P.; Ahrenkiel, R.K.

    1992-01-01

    Thin-film GaAs Hall probes were fabricated by molecular beam epitaxy technology. A contactless technique was developed to characterize thin-film, high-temperature superconducting (HTSC) materials. The Hall probes detected the ac magnetic flux penetration through the high-temperature superconducting materials. The Hall detector has advantages over the mutual inductance magnetic flux detector

  11. Temperature control system for liquid-fed ceramic melters

    International Nuclear Information System (INIS)

    Westsik, J.H. Jr.

    1986-10-01

    A temperature-feedback system has been developed for controlling electrical power to liquid-fed ceramic melters (LFCM). Software, written for a microcomputer-based data acquisition and process monitoring system, compares glass temperatures with a temperature setpoint and adjusts the electrical power accordingly. Included in the control algorithm are steps to reject failed thermocouples, spatially average the glass temperatures, smooth the averaged temperatures over time using a digital filter, and detect foaming in the glass. The temperature control system has proved effective during all phases of melter operation including startup, steady operation, loss of feed, and shutdown. This system replaces current, power, and resistance feedback control systems used previously in controlling the LFCM process

  12. Temperature factor for magnetic instability conditions of type – II superconductors

    International Nuclear Information System (INIS)

    Romanovskii, V.

    2014-01-01

    Highlights: • Electrodynamics and thermal diffusion phenomena in superconductors have the fission-chain-reaction nature. • There exist nontrivial relations between stability conditions, allowable losses and stable superconductor’s overheating. • The magnetic stability conditions are direct consequence of the states when the heat releases exceeds the critical energy. • The critical energy of magnetic instability depends on the nature of an external disturbance. • The non-isothermal magnetic instability conditions of the critical state are formulated. - Abstract: The macroscopic development of interrelated electrodynamics and thermal states taking place both before and after instability onset in type-II superconductors are studied using the critical state and the flux creep concepts. The physical mechanisms of the non-isothermal formation of the critical state are discussed solving the set of unsteady thermo-electrodynamics equations taking into consideration the unknown moving penetration boundary of the magnetic flux. To make it, the numerical method, which allows to study diffusion phenomena with unknown moving phase-two boundary, is developed. The corresponding non-isothermal flux jump criteria are written. It is proved for the first time that, first, the diffusion phenomena in superconductors have the fission-chain-reaction nature, second, the stability conditions, losses in superconductor and its stable overheating before instability onset are mutually dependent. The results are compared with those following from the existing magnetic instability theory, which does not take into consideration the stable temperature increase of superconductor before the instability onset. It is shown that errors of isothermal approximation are significant for modes closed to adiabatic ones. Therefore, the well-known adiabatic flux jump criterion limits the range of possible stable superconducting states since a correct determination of their stability states must

  13. Novel low-temperature sintering ceramic substrate based on indialite/cordierite glass ceramics

    Science.gov (United States)

    Varghese, Jobin; Vahera, Timo; Ohsato, Hitoshi; Iwata, Makoto; Jantunen, Heli

    2017-10-01

    In this paper, a novel low-temperature sintering substrate for low temperature co-fired ceramic applications based on indialite/cordierite glass ceramics with Bi2O3 as a sintering aid showing low permittivity (εr) and ultralow dielectric loss (tan δ) is described. The fine powder of indialite was prepared by the crystallization of cordierite glass at 1000 °C/1 h. The optimized sintering temperature was 900 °C with 10 wt % Bi2O3 addition. The relative density achieved was 97%, and εr and tan δ were 6.10 and 0.0001 at 1 MHz, respectively. The composition also showed a moderately low temperature coefficient of relative permittivity of 118 ppm/°C at 1 MHz. The obtained linear coefficient of thermal expansion was 3.5 ppm/°C in the measured temperature range of 100 to 600 °C. The decreasing trend in dielectric loss, the low relative permittivity at 1 MHz, and the low thermal expansion of the newly developed composition make it an ideal choice for radio frequency applications.

  14. Finding high-temperature superconductors by metallizing the σ-bonding electrons

    International Nuclear Information System (INIS)

    Gao Miao; Lu Zhongyi; Xiang Tao

    2015-01-01

    Raising superconducting transition temperature (T_c) is an important task of fundamental research on superconductivity. It is also a prerequisite for the large scale application of superconductors. Since the microscopic mechanism of high-T_c superconductivity is unknown, the conventional approach for increasing T_c is either to apply high pressure to a material which has the potential to become superconducting, or to push it close to an antiferromagnetic or some other quantum instability point by chemical doping. In this article, the authors point out that another general approach for raising T_c is to lift the σ-bonding bands to the Fermi level, or to metallize the σ-bonding elections. This approach can increase the probability of finding a novel high-T_c superconductor because the coupling of σ-bonding electrons with phonons is generally strong and the superconducting transition induced by this interaction can occur at relatively high temperatures. After elucidating the underlying mechanism, the authors discuss a number of schemes to metallize σ-bonding electrons, and present their recent prediction for the crystalline and electronic structures of two potential high-T_c superconductors, Li_2B_3C and Li_3B_4C_2, with T_c higher than 50 K. (authors)

  15. Statistical mechanics of flux lines in high-temperature superconductors

    International Nuclear Information System (INIS)

    Dasgupta, C.

    1992-01-01

    The shortness of the low temperature coherence lengths of high T c materials leads to new mechanisms of pinning of flux lines. Lattice periodic modulations of the order parameters itself acts to pin vortex lines in regions of the unit cell were the order parameter is small. A presentation of flux creep and flux noise at low temperature and magnetic fields in terms of motion of simple metastable defects on flux lines is made, with a calculation of flux lattice melting. 12 refs

  16. Fracture analysis of a transversely isotropic high temperature superconductor strip based on real fundamental solutions

    International Nuclear Information System (INIS)

    Gao, Zhiwen; Zhou, Youhe

    2015-01-01

    Highlights: • We studied fracture problem in HTS based on real fundamental solutions. • When the thickness of HTS strip increases the SIF decrease. • A higher applied field leads to a larger stress intensity factor. • The greater the critical current density is, the smaller values of the SIF is. - Abstract: Real fundamental solution for fracture problem of transversely isotropic high temperature superconductor (HTS) strip is obtained. The superconductor E–J constitutive law is characterized by the Bean model where the critical current density is independent of the flux density. Fracture analysis is performed by the methods of singular integral equations which are solved numerically by Gauss–Lobatto–Chybeshev (GSL) collocation method. To guarantee a satisfactory accuracy, the convergence behavior of the kernel function is investigated. Numerical results of fracture parameters are obtained and the effects of the geometric characteristics, applied magnetic field and critical current density on the stress intensity factors (SIF) are discussed

  17. High temperature superconductor bulk materials. Fundamentals - processing - properties control - application aspects

    International Nuclear Information System (INIS)

    Krabbes, G.; Fuchs, G.; Canders, W.R.; May, H.; Palka, R.

    2006-01-01

    This book presents all the features of bulk high temperature superconducting materials. Starting from physical and chemical fundamentals, the authors move on to portray methods and problems of materials processing, thoroughly working out the characteristic properties of bulk superconductors in contrast to long conductors and films. The authors provide a wide range of specific materials characteristics with respect to the latest developments and future applications guiding from fundamentals to practical engineering examples. This book contains the following chapters: 1. Fundamentals 2. Growth and melt processing of YBCO 3. Pinning-relevant defects in bulk YBCO 4. Properties of bulk YBCO 5. Trapped fields 6. Improved YBCO based bulk superconductors and functional elements 7. Alternative systems 8. Peak effect 9. Very high trapped fields in YBCO permanent magnets 10. Engineering aspects: Field distribution in bulk HTSC 11. Inherently stable superconducting magnetic bearings 12. Application of bulk HTSCs in electromagnetic energy converters 13. Applications in magnet technologies and power supplies

  18. High temperature structural ceramic materials manufactured by the CNTD process

    International Nuclear Information System (INIS)

    Stiglich, J.J. Jr.; Bhat, D.G.; Holzl, R.A.

    1980-01-01

    Controlled Nucleation Thermochemical Deposition (CNTD) has emerged from classical chemical deposition (CVD) technology. This paper describes the techniques of thermochemical grain refinement. The effects of such refinement on mechanical properties of materials at room temperature and at elevated temperatures are outlined. Emphasis is given to high temperature structural ceramic materials such as SiC, Si 3 N 4 , AlN, and TiB 2 and ZrB 2 . An example of grain refinement accompanied by improvements in mechanical properties is SiC. Grain sizes of 500 to 1000 A have been observed in CNTD SiC with room temperature MOR of 1380 to 2070 MPa (4 pt bending) and MOR of 3450 to 4140 MPa (4 pt bending) at 1350 0 C. Various applications of these materials to the solution of high temperature structural problems are described. (author)

  19. High critical temperature superconductors: Progress achieved after two years. Les supraconducteurs haute temperature critique: L'etat des lieux deux ans apres

    Energy Technology Data Exchange (ETDEWEB)

    Maillard, J M; Rammal, R; Vittorge, M C

    1989-01-01

    Progress concerning the theory of high temperature superconductors and activity of laboratories of the CNRS (France) are reviewed and news on strategy, budgets, theoretical research, materials characterization, fabrication process technology transfers, commercialisation, uses and data bases are given.

  20. Elevated Temperature Testing and Modeling of Advanced Toughened Ceramic Materials

    Science.gov (United States)

    Keith, Theo G.

    2005-01-01

    The purpose of this report is to provide a final report for the period of 12/1/03 through 11/30/04 for NASA Cooperative Agreement NCC3-776, entitled "Elevated Temperature Testing and Modeling of Advanced Toughened Ceramic Materials." During this final period, major efforts were focused on both the determination of mechanical properties of advanced ceramic materials and the development of mechanical test methodologies under several different programs of the NASA-Glenn. The important research activities made during this period are: 1. Mechanical properties evaluation of two gas-turbine grade silicon nitrides. 2) Mechanical testing for fuel-cell seal materials. 3) Mechanical properties evaluation of thermal barrier coatings and CFCCs and 4) Foreign object damage (FOD) testing.

  1. Low temperature superconductor and aligned high temperature superconductor magnetic dipole system and method for producing high magnetic fields

    Science.gov (United States)

    Gupta, Ramesh; Scanlan, Ronald; Ghosh, Arup K.; Weggel, Robert J.; Palmer, Robert; Anerella, Michael D.; Schmalzle, Jesse

    2017-10-17

    A dipole-magnet system and method for producing high-magnetic-fields, including an open-region located in a radially-central-region to allow particle-beam transport and other uses, low-temperature-superconducting-coils comprised of low-temperature-superconducting-wire located in radially-outward-regions to generate high magnetic-fields, high-temperature-superconducting-coils comprised of high-temperature-superconducting-tape located in radially-inward-regions to generate even higher magnetic-fields and to reduce erroneous fields, support-structures to support the coils against large Lorentz-forces, a liquid-helium-system to cool the coils, and electrical-contacts to allow electric-current into and out of the coils. The high-temperature-superconducting-tape may be comprised of bismuth-strontium-calcium-copper-oxide or rare-earth-metal, barium-copper-oxide (ReBCO) where the rare-earth-metal may be yttrium, samarium, neodymium, or gadolinium. Advantageously, alignment of the large-dimension of the rectangular-cross-section or curved-cross-section of the high-temperature-superconducting-tape with the high-magnetic-field minimizes unwanted erroneous magnetic fields. Alignment may be accomplished by proper positioning, tilting the high-temperature-superconducting-coils, forming the high-temperature-superconducting-coils into a curved-cross-section, placing nonconducting wedge-shaped-material between windings, placing nonconducting curved-and-wedge-shaped-material between windings, or by a combination of these techniques.

  2. Method for preparing high transition temperature Nb.sub.3 Ge superconductors

    Science.gov (United States)

    Newkirk, Lawrence R.; Valencia, Flavio A.

    1977-01-01

    Bulk coatings of Nb.sub.3 Ge superconductors having transition temperatures in excess of 20 K are readily formed by a chemical vapor deposition technique involving the coreduction of NbCl.sub.5 and GeCl.sub.4 in the presence of hydrogen. The NbCl.sub.5 vapor may advantageously be formed quantitatively in the temperature range of about 250.degree. to 260.degree. C by the chlorination of Nb metal provided the partial pressure of the product NbCl.sub.5 vapor is maintained at or below about 0.1 atm.

  3. Generation of charge imbalance in a superconductor by a temperature gradient

    International Nuclear Information System (INIS)

    Entin-Wohlman, O.; Orbach, R.

    1980-01-01

    The charge-imbalance voltage in a superconductor carrying a current in the presence of a temperature gradient is calculated from the Boltzmann equation in the clean limit. We demonstrate why the Green's-function approach in the dirty limit, first performed by Schmid and Schoem, generates the same Boltzmann-like equation for the distribution function. In addition, the charge-imbalance voltage in the absence of an impressed current is calculated. It is shown to depend on del 2 T+(delT) 2 /T, and not solely on (delT) 2 . The calculations are limited to the temperature regime near T/sub c/, such that Δ<< T

  4. Positron annihilation in a high-temperature superconductor YBa2Cu3O7-δ

    International Nuclear Information System (INIS)

    Vavryshchuk, Ya.; Levandovski, M.; Rybakov, V.N.; Yutlandov, I.A.

    1988-01-01

    Positron annihilation as a function of temperature in high-temperature superconductors YBa 2 Cu 3 O 7-δ has been investigated. It is shown that a change in the annihilation capacity at the transition into superconducting state is relatively small. The change of r 1 and r 2 positron lifetimes as well as of the intensity of the component with r 2 -J 2 and Doppler broadening S parameter allows one to assume that transition into superconducting state is accompanied with a certain decrease in electron density and with decreasing number of defects or increasing size of crystalline net

  5. Design of a high-temperature superconductor current lead for electric utility SMES

    International Nuclear Information System (INIS)

    Niemann, R.C.; Cha, Y.S.; Hull, J.R.; Rey, C.M.; Dixon, K.D.

    1995-01-01

    Current leads that rely on high-temperature superconductors (HTSs) to deliver power to devices operating at liquid helium temperature have the potential to reduce refrigeration requirements to levels significantly below those achievable with conventional leads. The design of HTS current leads suitable for use in near-term superconducting magnetic energy storage (SMES) is in progress. The SMES system has an 0.5 MWh energy capacity and a discharge power of 30 MW. Lead-design considerations include safety and reliability, electrical and thermal performance, structural integrity, manufacturability, and cost. Available details of the design, including materials, configuration, and performance predictions, are presented

  6. Temperature and carrier density dependence of anisotropy in supercurrent density in layered cuprate superconductors

    International Nuclear Information System (INIS)

    Singh, M.P.; Tewari, B.S.; Ajay

    2006-01-01

    In the present work, we have studied the effect of temperature and carrier density on anisotropy in supercurrent density in bilayer cuprate superconductors. Here, we have considered a tight binding bilayered Hubbard Hamiltonian containing intra and interlayer attractive interactions. The situation considered here is similar to a SIS junction. We have got the expressions for the superconducting order parameters, carrier density and anisotropy in superconducting density (I ab /I c ) for such SIS junction. The numerical analysis show that the anisotropy in the supercurrent density depends on temperature and carrier density in layered high T c cuprates. (author)

  7. Low-temperature specific heat of the β-pyrochlore oxide superconductors under high pressure

    Science.gov (United States)

    Isono, T.; Iguchi, D.; Machida, Y.; Izawa, K.; Salce, B.; Flouquet, J.; Ogusu, H.; Yamaura, J.; Hiroi, Z.

    2011-01-01

    We report the results of the low-temperature specific heat measurements of the single crystalline β-pyrochlore oxide superconductors AOs 2O 6 (A=K, Rb, and Cs) under high pressure up to 13 GPa. We find that superconducting transition temperature ( Tc) monotonically increases for CsOs 2O 6 and RbOs 2O 6, while the one for KOs 2O 6 decreases by applying the pressure. With further increasing the pressure, Tc is suddenly suppressed at the same lattice volume for all compounds, concomitant with the first-order structural phase transition.

  8. Temperature dependence of velocity of sound in high-Tc superconductors in normal state

    International Nuclear Information System (INIS)

    Bishoyi, K.C.; Rout, G.C.; Behera, S.N.

    2002-01-01

    A microscopic theoretical calculation of temperature dependence of velocity of sound in high temperature superconductors is addressed in this paper. The influence of model parameters of the system in its normal phase is investigated through numerical calculations. The results at the room temperature as well as low temperatures (∼ 25 K), are discussed. The dimensionless parameters involved in the calculations are the electron-phonon coupling (g), staggered magnetic field (h), hybridization (V), position of the f-level (d), temperature (t) and the conduction band width (ω). The model Hamiltonian contains the antiferromagnetism in conduction electrons of cooper and the electron-phonon interaction through the hybridization between conduction electrons and f-electrons of impurity atoms. The phonon Green's functions are calculated by Zubarev's technique. The velocity of sound is calculated in the long wavelength and finite temperature limit. (author)

  9. Dynamic phases of low-temperature low-current driven vortex matter in superconductors

    International Nuclear Information System (INIS)

    Benkraouda, M; Obaidat, I M; Khawaja, U Al; Mulaa, N M J

    2006-01-01

    Using molecular dynamics simulations of vortices in a high-temperature superconductor with square periodic arrays of pinning sites, dynamic phases of the low-current driven vortices are studied at low temperatures. A rough vortex phase diagram of three distinct regimes of vortex flow is proposed. At zero temperature, we obtain a coupled-channel regime where rows of vortices flow coherently in the direction of the driving force. As the temperature is increased, a smooth crossover into an uncoupled-channel regime occurs where the coherence between the flowing rows of vortices becomes weaker. Increasing the temperature further leads to a plastic vortex regime, where the channels of flowing vortices completely disappear. The temperatures of the crossovers between these regimes were found to decrease with the driving force

  10. Relationship between Magnetic Anisotropy below Pseudogap Temperature and Short-Range Antiferromagnetic Order in High-Temperature Cuprate Superconductor

    Science.gov (United States)

    Morinari, Takao

    2018-06-01

    The central issue in high-temperature cuprate superconductors is the pseudogap state appearing below the pseudogap temperature T*, which is well above the superconducting transition temperature. In this study, we theoretically investigate the rapid increase of the magnetic anisotropy below the pseudogap temperature detected by the recent torque-magnetometry measurements on YBa2Cu3Oy [Y. Sato et al., 10.1038/nphys4205" xlink:type="simple">Nat. Phys. 13, 1074 (2017)]. Applying the spin Green's function formalism including the Dzyaloshinskii-Moriya interaction arising from the buckling of the CuO2 plane, we obtain results that are in good agreement with the experiment and find a scaling relationship. Our analysis suggests that the characteristic temperature associated with the magnetic anisotropy, which coincides with T*, is not a phase transition temperature but a crossover temperature associated with the short-range antiferromagnetic order.

  11. Problems of a transformer with high-temperature superconductors

    International Nuclear Information System (INIS)

    Mueller, W.

    1989-01-01

    Fundamental reflections are made on the demands which have to be made on the short-circuit current limitation in the network on the one hand and on the admissible magnetic boundary field strengths of high-temperature superconduction on the other hand. The aim to develop mechanically self-supporting windings led for conventional core-type transformer designs to the construction of concentric-lay winding arrangements with magnetic stray field strengths, which seem to be realizable with regard to material development. Due to the further aim of avoiding core losses, a design study on a coreless high-temperature superconduction transformer was drawn up the windings of which are united in a coaxial cable which is wound up to a toroidal coil. The factors of influence which are relevant for the rating, operating characteristics and the application of a transformer like this are discussed. (orig.) [de

  12. The potential for EMS Maglev using high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Goodall, R [Loughborough Univ. (United Kingdom); Macleod, C [Loughborough Univ. (United Kingdom); El-Abbar, A [Loughborough Univ. (United Kingdom); Jones, H [Oxford Univ. (United Kingdom); Jenkins, R [Oxford Univ. (United Kingdom); Campbell, A [Cambridge Univ. (United Kingdom)

    1996-12-31

    Various aspects relating to the use of high temperature superconducting materials in iron-cored magnets for Maglev are considered. The particular emphasis is upon direct control of the superconducting coils, and a control analysis is undertaken to assess the requirements. Experimental results form tests conducted to determine how a superconducting magnet will perform under the conditions required for Maglev are included, and the final section determines the likely effect on the magnet design of using superconducting rather than normal coils. (orig.)

  13. Preparation and Characterization of High Temperature Superconductor Film Surfaces

    Science.gov (United States)

    1993-10-27

    Lanthanum Strontium Copper Oxide (LSCO) was also tested as a normal metal overlayer because of its compatibility with the high deposition temperature for...fabricate YBCO/ISCO SEB junctions using a variety of step heights (110 nm - 330 nm) on Neodymium Gallate (NGO) substrates. NGO was chosen as a...substrate because of its excellent lattice match to YBCO and its lack of crystal twinning Twinning had been a drawback of Lanthanum Aluminate (LAO)- L

  14. Development of materials for high temperature superconductor Josephson junctions

    International Nuclear Information System (INIS)

    Houlton, R.J.; Reagor, D.W.; Hawley, M.E.; Springer, K.N.; Jia, Q.X.; Mombourquette, C.B.; Garzon, F.H.; Wu, X.D.

    1994-01-01

    We have conducted a systematic optimization of deposition parameters for fabrication of multilayered oxide films to be used in the development of high temperature superconducting SNS Functions. These films were deposited by off-axis sputtering using a custom fabricated multi-gun planar magnetron system. Each material and the various combinations of materials were optimized for epitaxial lattice match, crystal quality, film uniformity, electrical properties, and surface microstructure. In addition to the standard procedures commonly used to sputter deposit epitaxial oxide films, a variety of insitu and exsitu procedures were used to produce high quality multilayer devices, including varying the nucleation temperature from the actual film growth temperature, location of the substrate during the deposition process, constant rotation of the substrate, and timing of the oxygen anneal. The unprocessed films and devices in process were characterized with Atomic Force Microscopy and Scanning Tunneling Microscopy as well as other common materials characterization techniques. Completed multilayer devices were patterned and packaged for electrical characterization. Relation between material properties and electrical characteristics is discussed

  15. Development of materials for high temperature superconductor Josephson junctions

    Energy Technology Data Exchange (ETDEWEB)

    Houlton, R.J.; Reagor, D.W.; Hawley, M.E.; Springer, K.N.; Jia, Q.X.; Mombourquette, C.B.; Garzon, F.H.; Wu, X.D.

    1994-10-01

    We have conducted a systematic optimization of deposition parameters for fabrication of multilayered oxide films to be used in the development of high temperature superconducting SNS Functions. These films were deposited by off-axis sputtering using a custom fabricated multi-gun planar magnetron system. Each material and the various combinations of materials were optimized for epitaxial lattice match, crystal quality, film uniformity, electrical properties, and surface microstructure. In addition to the standard procedures commonly used to sputter deposit epitaxial oxide films, a variety of insitu and exsitu procedures were used to produce high quality multilayer devices, including varying the nucleation temperature from the actual film growth temperature, location of the substrate during the deposition process, constant rotation of the substrate, and timing of the oxygen anneal. The unprocessed films and devices in process were characterized with Atomic Force Microscopy and Scanning Tunneling Microscopy as well as other common materials characterization techniques. Completed multilayer devices were patterned and packaged for electrical characterization. Relation between material properties and electrical characteristics is discussed

  16. Possible antipolar pairing mechanism in high-temperature superconductors

    International Nuclear Information System (INIS)

    Cardwell, D.A.; Shorrocks, N.M.

    1989-01-01

    An antipolar pairing mechanism for free charge carriers in high-T c superconducting compounds is proposed qualitatively. This involves the establishment of a two-dimensional (2D) array of effective charge-coupling centers within the superconducting lattice via a specific phonon distortion of cation species along a nonmajor crystallographic direction. A fundamental requirement of this model is that the density of such coupling centers decreases with decreasing temperature. In the case of Y-Ba-Cu-O, it is asserted that charge carriers in a 2D oxygen band adjacent to the phonon-containing plane become localized by the resulting (local) field distortion. Cooper pairs may then form when the charge-coupling-center density falls below the charge-carrier density. Such a mechanism could be mediated by a longitudinal phonon which softens at low temperatures to produce an antipolar state, such as that incipient to an antiferroelectric distortion of the lattice (i.e., in the zero-frequency limiting case). This model, which may be investigated experimentally by low-temperature Raman spectroscopy, isotopic substitution, and x-ray diffractometry at 4.2 K, can be applied to all p-type high-T c systems. In addition, it may account for the observed lattice anisotropy and short coherence length characteristic of these materials

  17. The study on a new superconductor (oxide Ba-Y-Cu) with high critical temperature Tc by positron annihilation

    International Nuclear Information System (INIS)

    Zhang Caigu; Yu Zhuxing; Wang Zhu; Huang Zhe; Zhou Jun

    1987-01-01

    The study on a new superconductor oxide Ba-Y-Cu with high critical temperature Tc is described. The experimental results show that positron lifetime reducing reflects variable curve of resistance with temperature. A peak of positron lifetime is appeared at critical temperature

  18. AC measurements on uranium doped high temperature superconductors

    International Nuclear Information System (INIS)

    Eisterer, M.

    1999-11-01

    The subject of this thesis is the influence of fission tracks on the superconducting properties of melt textured Y-123. The critical current densities, the irreversibility lines and the transition temperature were determined by means of ac measurements. The corresponding ac techniques are explored in detail. Deviations of the ac signal from the expectations according to the Bean model were explained by the dependence of the shielding currents on the electric field. This explanation is supported by the influence of the ac amplitude and frequency on the critical current density but also by a comparison of the obtained data with other experimental techniques. Y-123 has to be doped with uranium in order to induce fission tracks. Uranium forms normal conducting clusters, which are nearly spherical, with a diameter of about 300 nm. Fission of uranium-235 by thermal neutrons creates two high energy ions with a total energy of about 160 MeV. Each of these fission products induces a linear defect with a diameter of about 10 nm. The length of one fission track is 2-4 μm. At 77 K the critical current density is enhanced by the pinning action of the uranium clusters, compared to undoped samples. With decreasing temperature this influence becomes negligible. The critical current densities are strongly enhanced due to the irradiation. At low magnetic fields we find extremely high values for melt textured materials, e.g. 2.5x10 9 Am -2 at 77 K and 0.25 T or 6x10 10 Am -2 at 5 K. Since the critical current was found to be inverse proportional to the square root of the applied magnetic field it decreases rapidly as the field increases. This behavior is predicted by simple theoretical considerations, but is only valid at low temperatures as well as in low magnetic fields at high temperatures. At high fields the critical current drops more rapidly. The irreversibility lines are only slightly changed by this irradiation technique. Only a small shift to higher fields and temperatures

  19. Mechanical behavior of high strength ceramic fibers at high temperatures

    Science.gov (United States)

    Tressler, R. E.; Pysher, D. J.

    1991-01-01

    The mechanical behavior of commercially available and developmental ceramic fibers, both oxide and nonoxide, has been experimentally studied at expected use temperatures. In addition, these properties have been compared to results from the literature. Tensile strengths were measured for three SiC-based and three oxide ceramic fibers for temperatures from 25 C to 1400 C. The SiC-based fibers were stronger but less stiff than the oxide fibers at room temperature and retained more of both strength and stiffness to high temperatures. Extensive creep and creep-rupture experiments have been performed on those fibers from this group which had the best strengths above 1200 C in both single filament tests and tests of fiber bundles. The creep rates for the oxides are on the order of two orders of magnitude faster than the polymer derived nonoxide fibers. The most creep resistant filaments available are single crystal c-axis sapphire filaments. Large diameter CVD fabricated SiC fibers are the most creep and rupture resistant nonoxide polycrystalline fibers tested to date.

  20. Relationship of electrical, magnetic, and mechanical properties to processing in high-temperature superconductors

    International Nuclear Information System (INIS)

    Blendell, J.E.; Chiang, C.K.; Cranmer, D.C.

    1987-01-01

    The interrelation between processing, microstructure, and properties is an important factor in understanding the behavior of ceramic materials. This type of understanding will be particularly important in the development of the new high T/sub c/ superconducting ceramic oxides of the type Ba/sub 2/YCu/sub 3/O/sub 7-x/. As an initial effort in understanding these relations, a number of properties have been measured for these superconducting ceramics and related to their microstructure and processing sequence. The Ba/sub 2/YCu/sub 3/O/sub 7-x/ ceramics were prepared by powder processing techniques, followed by dry pressing and sintering in both air and flowing oxygen at various temperatures. The sintered bodies were annealed at various temperatures and environments. Superconducting properties, such as the transition temperature and the width of the transition, were measured by both electrical conductivity and AC magnetic susceptibility; both of these properties show a strong sensitivity to annealing temperature and atmosphere. The microstructure and density were also strongly dependent on processing conditions. In this regard, compositional mapping proved to be an important technique for quantifying microstructural variations. Mechanical properties, such as elastic modulus, hardness, and fracture toughness, which will be important for the reliable use of these materials in large scale structures, were also determined

  1. Advanced ceramic material for high temperature turbine tip seals

    Science.gov (United States)

    Solomon, N. G.; Vogan, J. W.

    1978-01-01

    Ceramic material systems are being considered for potential use as turbine blade tip gas path seals at temperatures up to 1370 1/4 C. Silicon carbide and silicon nitride structures were selected for study since an initial analysis of the problem gave these materials the greatest potential for development into a successful materials system. Segments of silicon nitride and silicon carbide materials over a range of densities, processed by various methods, a honeycomb structure of silicon nitride and ceramic blade tip inserts fabricated from both materials by hot pressing were tested singly and in combination. The evaluations included wear under simulated engine blade tip rub conditions, thermal stability, impact resistance, machinability, hot gas erosion and feasibility of fabrication into engine components. The silicon nitride honeycomb and low-density silicon carbide using a selected grain size distribution gave the most promising results as rub-tolerant shroud liners. Ceramic blade tip inserts made from hot-pressed silicon nitride gave excellent test results. Their behavior closely simulated metal tips. Wear was similar to that of metals but reduced by a factor of six.

  2. Flux creep characteristics in high-temperature superconductors

    International Nuclear Information System (INIS)

    Zeldov, E.; Amer, N.M.; Koren, G.; Gupta, A.; McElfresh, M.W.; Gambino, R.J.

    1990-01-01

    We describe the voltage-current characteristics of YBa 2 Cu 3 O 7-δ epitaxial films within the flux creep model in a manner consistent with the resistive transition behavior. The magnitude of the activation energy, and its temperature and magnetic field dependences, are readily derived from the experimentally observed power law characteristics and show a (1-T/T c ) 3/2 type of behavior near T c . The activation energy is a nonlinear function of the current density and it enables the determination of the shape of the flux line potential well

  3. Flux-line cutting in granular high-temperature superconductors

    International Nuclear Information System (INIS)

    Perez-Rodriguez, F.; Perez-Gonzalez, A.; Clem, J.R.; Gandolfini, G.; LeBlanc, M.A.

    1997-01-01

    The magnetic response of granular high-temperature superconducting plates subjected to a dc-bias magnetic field and an increasing field perpendicular to it is studied both experimentally and theoretically. The theoretical model is based upon the double critical-state model, which considers not only flux transport but also flux-line cutting effects. Curves of magnetization for the system of grains decoupled by the applied magnetic field in sintered slabs of YBa 2 Cu 3 O 7-x and NdBa 2 Cu 3 O 7-x are analyzed. Good agreement between experimental results and theory is obtained. copyright 1997 The American Physical Society

  4. Numerical simulation of realistic high-temperature superconductors

    International Nuclear Information System (INIS)

    1997-01-01

    One of the main obstacles in the development of practical high-temperature superconducting (HTS) materials is dissipation, caused by the motion of magnetic flux quanta called vortices. Numerical simulations provide a promising new approach for studying these vortices. By exploiting the extraordinary memory and speed of massively parallel computers, researchers can obtain the extremely fine temporal and spatial resolution needed to model complex vortex behavior. The results may help identify new mechanisms to increase the current-capability capabilities and to predict the performance characteristics of HTS materials intended for industrial applications

  5. Fabrication of Nb_3Al superconductor by the optimized mechanical alloying method with low temperature

    International Nuclear Information System (INIS)

    Zhang, Y.; Lin, W.J.; Xu, L.Y.; Yang, D.W.; Chen, Y.L.; Li, P.Y.; Pan, X.F.; Yan, G.; Zhao, Y.

    2016-01-01

    Highlights: • Due to a much better strain tolerance than Nb_3Sn, Nb_3Al has been considered as an excellent candidate for making high field magnets. At present, the Nb_3Al superconducting wires were prepared mainly by the Jelly-roll method combined with a rapid heating and quenching (RHQ) heat treatment at around 2000 °C. In this study, Nb_3Al superconductor with T_c of 15.6 K is directly prepared with a mechanical alloying method followed by a low temperature annealing at 800 to 900 °C. Our results hint the possibility that Nb_3Al superconducting wire with high performance can be prepared below the melting point of Cu (1080 °C) by a conventional powder in tube (PIT) method, thus effectively avoiding high temperature heat treatment and RHQ device. - Abstract: Mechanical alloying was used to synthesize Nb_3Al superconductor successfully, and the process was optimization under various preparation conditions. In the current study, Nb_3Al superconductor with T_c of 15.6 K was directly prepared from high quality Nb (Al) solid solution by mechanical alloying method and heat treatment at a low temperature of 800 to 900 °C. The results showed that Nb_3Al superconducting wire with high performance could be prepared after heat treatment below the melting point of Cu (1080°C) and using Nb (Al) solid solution and conventional powder in tube (PIT) method, thus effectively avoiding ultra-high temperature heat treatment and special rapid heating and quenching(RHQ) device.

  6. Temperature dependence of the infrared properties of Hg–Ba–Cu–O high-temperature superconductor

    Czech Academy of Sciences Publication Activity Database

    Tomašovičová, N.; Knížek, Karel; Veverka, Miroslav

    378-380, - (2006), s. 455-456 ISSN 0921-4526 Grant - others:VEGA(SK) 2/4060/04; Science and Technology Assistence Agency(SK) APVT-51-027904 Institutional research plan: CEZ:AV0Z10100521 Keywords : mercury superconductors * infrared spectroscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.872, year: 2006

  7. A 15-pole high temperature superconductor filter for radar applications

    Science.gov (United States)

    Yu, Xiao; Xi, Weibin; Wu, Songtao

    2018-06-01

    This paper presents a compact and high first harmonic frequency resonator. The characteristics of this resonator are theoretically analyzed. A highly selective 15-pole Chebyshev high temperature superconducting ultra-high frequency narrowband filter for radar applications was fabricated by using this resonator. The filter has a center frequency of 495 MHz and a fractional bandwidth of 1%. The first harmonic frequency is more than 3.3 times the fundamental frequency. The measured filter shows excellent selectivity, better than 85 dB/1 MHz skirt slopes, and more than 85 dB of rejection at 497.5 MHz from the band edge. The filter was fabricated on a 2 inch YBCO thin film with a 0.5 mm thick MgO substrate. The experimental results are consistent with the simulations.

  8. Status and future perspective of applications of high temperature superconductors

    Science.gov (United States)

    Tanaka, Shoji

    The material research on the high temperature superconductivity for the past ten years gave us sufficient information on the new phenomena of these new materials. It seems that new applications in a very wide range of industries are increasing rapidly. In this report three main topics of the applications are given ; [a] progress of the superconducting bulk materials and their applications to the flywheel electricity storage system and others, [b] progress in the development of superconducting tapes and their applications to power cables, the high field superconducting magnet for the SMES and for the pulling system of large silicon single crystal, and [c] development of new superconducting electronic devices (SFQ) and the possiblity of the application to next generation supercomputers. These examples show the great capability of the superconductivity technology and it is expected that the real superconductivity industry will take off around the year of 2005.

  9. Ac irreversibility line of bismuth-based high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Mehdaoui, A. [Laboratoire de Physique et de Spectroscopie Electronique, URA 1435 Faculte des Sciences, Universite de Haute Alsace 4, rue des Freres Lumiere, 68093 Mulhouse Cedex (France); Beille, J. [Laboratoire Louis Neel, CNRS, BP 166, 38042 Grenoble Cedex 9 (France); Berling, D.; Loegel, B. [Laboratoire de Physique et de Spectroscopie Electronique, URA 1435 Faculte des Sciences, Universite de Haute Alsace 4, rue des Freres Lumiere, 68093 Mulhouse Cedex (France); Noudem, J.G.; Tournier, R. [EPM-MATFORMAG, Laboratoire dElaboration par Procede Magnetique, CNRS, BP 166, 38042 Grenoble Cedex 9 (France)

    1997-09-01

    We discuss the magnetic properties of lead doped Bi-2223 bulk samples obtained through combined magnetic melt texturing and hot pressing (MMTHP). The ac complex susceptibility measurements are achieved over a broad ac field range (1 Oe{lt}h{sub ac}{lt}100 Oe) and show highly anisotropic properties. The intergranular coupling is improved in the direction perpendicular to the applied stress and magnetic field direction, and an intragranular loss peak is observed for the first time. A comparison is made with other bismuth-based compounds and it is shown that the MMTHP process shifts the ac irreversibility line (ac IL) toward higher fields. It is also shown that all the ac IL{close_quote}s for quasi 2D bismuth-based compounds show a nearly quadratic temperature dependence and deviate therefore strongly from the linear behavior observed in quasi 3D compounds and expected from a critical state model.{copyright} {ital 1997 Materials Research Society.}

  10. Ac irreversibility line of bismuth-based high temperature superconductors

    International Nuclear Information System (INIS)

    Mehdaoui, A.; Beille, J.; Berling, D.; Loegel, B.; Noudem, J.G.; Tournier, R.

    1997-01-01

    We discuss the magnetic properties of lead doped Bi-2223 bulk samples obtained through combined magnetic melt texturing and hot pressing (MMTHP). The ac complex susceptibility measurements are achieved over a broad ac field range (1 Oe ac <100 Oe) and show highly anisotropic properties. The intergranular coupling is improved in the direction perpendicular to the applied stress and magnetic field direction, and an intragranular loss peak is observed for the first time. A comparison is made with other bismuth-based compounds and it is shown that the MMTHP process shifts the ac irreversibility line (ac IL) toward higher fields. It is also shown that all the ac IL close-quote s for quasi 2D bismuth-based compounds show a nearly quadratic temperature dependence and deviate therefore strongly from the linear behavior observed in quasi 3D compounds and expected from a critical state model.copyright 1997 Materials Research Society

  11. Asymptotic Slavery in the Copper Oxide High Temperature Superconductors

    Science.gov (United States)

    Phillips, Philip

    2004-05-01

    Vast progress in theoretical solid state physics has been made by constructing models which mimic the low-energy properties of solids. Essential to the success of this program is the separability of the high and low energy degrees of freedom. While it is hoped that a high energy reduction can be made to solve the problem of high temperature superconductivity in the copper oxide materials, I will show that no consistent theory is possible if the high energy scale is removed. At the heart of the problem is the mixing of all energy scales (that is, UV-IR mixing) in the copper-oxide materials. Optical experiments demonstrate that the number of low-energy degrees of freedom is derived from a high energy scale. The implications of the inseparability of the high and low energy degrees of freedom on the phase diagram of the cuprates is discussed.

  12. Room-temperature-deposited dielectrics and superconductors for integrated photonics.

    Science.gov (United States)

    Shainline, Jeffrey M; Buckley, Sonia M; Nader, Nima; Gentry, Cale M; Cossel, Kevin C; Cleary, Justin W; Popović, Miloš; Newbury, Nathan R; Nam, Sae Woo; Mirin, Richard P

    2017-05-01

    We present an approach to fabrication and packaging of integrated photonic devices that utilizes waveguide and detector layers deposited at near-ambient temperature. All lithography is performed with a 365 nm i-line stepper, facilitating low cost and high scalability. We have shown low-loss SiN waveguides, high-Q ring resonators, critically coupled ring resonators, 50/50 beam splitters, Mach-Zehnder interferometers (MZIs) and a process-agnostic fiber packaging scheme. We have further explored the utility of this process for applications in nonlinear optics and quantum photonics. We demonstrate spectral tailoring and octave-spanning supercontinuum generation as well as the integration of superconducting nanowire single photon detectors with MZIs and channel-dropping filters. The packaging approach is suitable for operation up to 160 °C as well as below 1 K. The process is well suited for augmentation of existing foundry capabilities or as a stand-alone process.

  13. Current sharing effect on the current instability and allowable temperature rise of composite high-TC superconductors

    International Nuclear Information System (INIS)

    Romanovskii, V.R.; Watanabe, K.; Awaji, S.; Nishijima, G.; Takahashi, Ken-ichiro

    2004-01-01

    To understand the basic mechanisms of the thermal runaway phenomenon, the limiting margin of the current instability, which may spontaneously occur in composite high-T C superconductors like multifilament Bi-based wire or tape, is derived under DC magnetic field. The current sharing and allowable temperature rise effects were considered. A static zero-dimensional model was utilized to describe the basic formulae dealing with the peculiarities of the non-isothermal change of superconducting composite voltage-current characteristic. The boundary of allowable stable values of the temperature, electric field and current are derived analytically. It was shown that permissible values of the current and electric field might be higher than those determined by use of the standard critical current criterion. In consequence of this feature, the noticeable allowable temperature rise of the composite superconductor before its transition to the normal state may be seen. The criterion for complete thermal stability condition is written describing the state when temperature of the composite equals critical temperature of a superconductor and the transport current flows stably only in matrix. The performed analysis also proves the existence of value of the volume fraction of a superconductor in composite at which its current-carrying capacity has minimum. These peculiarities are due to the stable current redistribution between superconductor and stabilizing matrix. Therefore, the current sharing not only leads to the matrix/superconductor ratio effect on the stable operating characteristics of the composite high-T C superconductors but also becomes important in the adequate description of quench process in the high-T C superconducting magnets

  14. High-Temperature Ceramic Matrix Composite with High Corrosion Resistance

    Science.gov (United States)

    2010-06-02

    description of high temperature oxidation processes of composite ceramic materials of ZrB2 - SiC and ZrB2-SiC-Zr(Mo)Si2 systems up to high (~1300 °C...analysis was applied using MІN-7 mineralogical microscope and a set of standard immersion liquids with the known values of refraction coefficients...2.0 V) corresponds to the simultaneous formation of ZrO2 zirconium dioxide of monoclinic modification and Zr(OH)4 zirconium hydroxide which is

  15. Temperature controlled infrared broadband cloaking with the bilayer coatings of semiconductor and superconductor

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiaohua [College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); College of Physics and Electronics, Yancheng Teachers University, Yancheng 224051 (China); Liu, Youwen, E-mail: ywliu@nuaa.edu.cn [College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); Feng, Yuncai [College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)

    2015-06-15

    Highlights: • We first propose that the cloak is composed of the bilayer of semiconductor and superconductor. • We realize the infrared broadband cloaking based on the scattering cancellation method. • The cloaking frequency can be tuned by external temperature. - Abstract: The infrared broadband tunable cloaking have been proposed and investigated with the bilayer coating materials of semiconductor (n-Ge) and high-temperature superconductor (YBa{sub 2}Cu{sub 3}O{sub 7}), whose cloaking frequency can be controlled by external temperature. The analytical solution is derived based on the scattering cancellation cloaking technique from the Mie scattering theory, and the full-wave numerical simulation is performed by the finite element method. The calculated and simulated results have demonstrated that this invisibility cloak may reduce the total scattering cross section of the composite structure of 90% over a broad frequency band of nearly 20 THz, and the infrared cloaking frequency can be tuned by the external temperature. It can provide a feasible way to design a broadband tunable cloak.

  16. High temperature microplasticity of fine-grained ceramics

    International Nuclear Information System (INIS)

    Lakki, A.; Schaller, R.

    1996-01-01

    Several fine-grained ceramics exhibit enhanced ductility or even structural superplasticity at high temperature. Grain boundaries play a dominant role in the deformation process of these materials which usually involves diffusion-accommodated grain boundary sliding. Sliding is either lubricated by an amorphous intergranular phase or takes place by glide and climb of grain boundary dislocations. At high temperature, anelastic deformation precedes plastic deformation and stems from the short range motion of lattice defects, such as dislocations and grain boundaries. The energy loss (''mechanical loss'') associated with such motion can be measured by using the technique of mechanical spectroscopy. Moreover, at the onset of plasticity (''microplasticity''), long range irrecoverable motion of defects contributes to additional mechanical loss. Mechanical loss spectra may then give an insight into mechanisms operating at the transition between anelastic and plastic deformation. As an illustration, the spectra of three fine-grained ceramics (Si 3 N 4 , ZrO 2 , Al 2 O 3 ) are presented. In all cases, anelastic relaxation phenomena (peak and background) have been observed at high temperature (> 1200 K), bearing a close relation with creep behaviour. Their analysis permits to distinguish between different types of microstructrual elements: bulk regions of amorphous intergranular phase at triple points, grain boundaries separated by a thin glassy film and ''clean'' grain boundaries. (orig.)

  17. Effect of lead content on nonstoichiometric Bi2-xPbySr2Ca2Cu3Oδ ceramic superconductors

    International Nuclear Information System (INIS)

    Diaz-Valdes, E.; Pacheco-Malagon, G.; Contreras-Puente, G.; Mejia-Garcia, C.; Andrade-Garay, G.; Ortiz-Lopez, J.; Conde-Gallardo, A.; Falcony, C.

    1993-01-01

    Ceramic superconducting samples of the type Bi 2-x Pb y Sr 2 Ca 2 Cu 3 O δ were processed with a nonstoichiometric content of Bi and Pb (x≠y) with respect to the 2223 phase in this system. The resistance vs. temperature characteristics and the presence of the 2223 and 2212 phases as a function of the sample preparation conditions and the lead content (Bi/Pb ratio) are reported. The growth of unwanted phases such as PbO was observed for those samples with a high content of Pb (y=0.9) and Bi (x=0.1). (orig.)

  18. Physical characterization and study of the electrical magnetic and thermal properties of the ceramic high Tc superconductor Y1Ba2Cu3O7-x

    International Nuclear Information System (INIS)

    Azeredo Orlando, M.T. de.

    1991-01-01

    It was built four systems for physical characterization of high Tc superconductors, with data acquisition by computer, and recent results on AC susceptibility, AC resistivity, specific heat and thermal diffusivity of the YBa 2 Cu 3 O 7-x (x ≅ 0.15) compound, in a ceramic form, could be reproduced. Our study pointed that those ceramics exhibit a preferential orientation of the grains, being the c axis of the compound parallel to the compression direction. The study of this material in the four different technics, for samples with same density and oxygen stoichiometry, has pointed also that its magnetic behavior is strongly influenced by the intergrain region. This influence can be described by the clem model for the intergrain region and by the Malozemoff proposition for the fluxoids collective behavior. (author)

  19. Temperature dependence of magnetoresistance in lanthanum manganite ceramics

    International Nuclear Information System (INIS)

    Gubkin, M.K.; Zalesskii, A.V.; Perekalina, T.M.

    1996-01-01

    Magnetoresistivity in the La0.9Na0.1Mn0.9(V,Co)0.1O3 and LaMnO3+δ ceramics was studied. The temperature dependence of magnetoresistance in these specimens was found to differ qualitatively from that in the La0.9Na0.1MnO3 single crystal (the magnetoresistance value remains rather high throughout the measurement range below the Curie temperature), with the maximum values being about the same (20-40% in the field of 20 kOe). Previously published data on magnetization, high frequency magnetic susceptibility, and local fields at the 139La nuclei of the specimens with similar properties attest to their magnetic inhomogeneity. The computation of the conductivity of the nonuniformly ordered lanthanum manganite was performed according to the mean field theory. The calculation results allow one to interpret qualitatively various types of experimental temperature dependences of magnetoresistance

  20. Topics on frustrated spin systems and high-temperature superconductors

    International Nuclear Information System (INIS)

    Lu, Yong.

    1990-01-01

    The numerical study of frustrated spin systems using the Monte Carlo simulation method and the analytic study of fluctuation phenomenon of the thermoelectric power near the superconducting transition using Green's function techniques are presented. The first frustrated system considered was the B-site antiferromagnetic (AF) spinel. Based on an Ising model, various thermodynamic and magnetic properties for both the fully frustrated structure and partially frustrated cases of a small tetragonal distortion were studied. When fully frustrated, an interesting short range order and some unusual scaling behavior were obtained. In the two tetragonally distorted cases, contracting and expanding in the crystallographic c-direction, AF long range orders and some hysteresis behavior were found. A general phase diagram was constructed as a function of the degree of the distortion. The other frustrated spin system that was studied is the magnetic phase of YBa2Cu3O(6+x). A classical spin model, was constructed, and various properties in its Ising, Heisenberg, and x-y versions were studied. The susceptibility was calculated as a function of temperature for various values of x. In the study on the thermopower fluctuation, the thermopower was determined by the linear response of the electric and heat currents to an electric field, and the linear responses were in turn calculated from correlation functions of the current

  1. Electronic structure of the high-temperature oxide superconductors

    International Nuclear Information System (INIS)

    Pickett, W.E.

    1989-01-01

    Since the discovery of superconductivity above 30 K by Bednorz and Mueller in the La copper oxide system, the critical temperature has been raised to 90 K in YBa 2 Cu 3 O 7 and to 110 and 125 K in Bi-based and Tl-based copper oxides, respectively. In the two years since this Nobel-prize-winning discovery, a large number of electronic structure calculations have been carried out as a first step in understanding the electronic properties of these materials. In this paper these calculations (mostly of the density-functional type) are gathered and reviewed, and their results are compared with the relevant experimental data. The picture that emerges is one in which the important electronic states are dominated by the copper d and oxygen p orbitals, with strong hybridization between them. Photon, electron, and positron spectroscopies provide important information about the electronic states, and comparison with electronic structure calculations indicates that, while many features can be interpreted in terms of existing calculations, self-energy corrections (''correlations'') are important for a more detailed understanding. The antiferromagnetism that occurs in some regions of the phase diagram poses a particularly challenging problem for any detailed theory. The study of structural stability, lattice dynamics, and electron-phonon coupling in the copper oxides is also discussed. Finally, a brief review is given of the attempts so far to identify interaction constants appropriate for a model Hamiltonian treatment of many-body interactions in these materials

  2. Improved high temperature superconductor materials for wind turbine generators

    Energy Technology Data Exchange (ETDEWEB)

    Mozhaev, P.B.; Khoryushin, A.V.; Mozhaeva, J.E.; Bindslev Hansen, J.; Jacobsen, Claus S. (Technical Univ. of Denmark (DTU). Physics Dept., Kgs. Lyngby (Denmark)); Andersen, Niels H.; Grivel, J.-C. (Technical Univ. of Denmark (DTU). Risoe National Lab. for Sustainable Energy, Roskilde (Denmark))

    2011-05-15

    Effects of yttria addition on the structural and electrical properties of the YBCO thin films are studied. The films were deposited on (LaAlO{sub 3}){sub .3}-(Sr{sub 2}AlTaO{sub 8}){sub .7} substrates by pulsed laser ablation from targets with different elemental composition. The contents of elements in the film depend mainly on the yttrium content in the target. An increase of yttrium content leads to formation of a porous film with significant improvement of current-carrying capabilities (critical current density reaches 35 kA/cm2 at 77 K, 5 T, and exceeds 2 MA/cm2 at 50 K, 5 T). The Y-enriched YBCO film remains c-oriented up to 600 nm thickness with no suppression of the critical current density in the film. Yttria decoration of the substrate surface prior to deposition resulted in formation of YBCO films with low strain and high crystal perfection. In contrast to the Y-enriched YBCO films, the films on yttria layers are dense. At temperatures of 77 K and above the YBCO films on yttria-decorated substrates exhibit critical current densities comparable to or better than that of the Y-enriched films. (Author)

  3. Temperature variation in metal ceramic technology analyzed using time domain optical coherence tomography

    Science.gov (United States)

    Sinescu, Cosmin; Topala, Florin I.; Negrutiu, Meda Lavinia; Duma, Virgil-Florin; Podoleanu, Adrian G.

    2014-01-01

    The quality of dental prostheses is essential in providing good quality medical services. The metal ceramic technology applied in dentistry implies ceramic sintering inside the dental oven. Every ceramic material requires a special sintering chart which is recommended by the producer. For a regular dental technician it is very difficult to evaluate if the temperature inside the oven remains the same as it is programmed on the sintering chart. Also, maintaining the calibration in time is an issue for the practitioners. Metal ceramic crowns develop a very accurate pattern for the ceramic layers depending on the temperature variation inside the oven where they are processed. Different patterns were identified in the present study for the samples processed with a variation in temperature of +30 °C to +50 °C, respectively - 30 0°C to -50 °C. The OCT imagistic evaluations performed for the normal samples present a uniform spread of the ceramic granulation inside the ceramic materials. For the samples sintered at a higher temperature an alternation between white and darker areas between the enamel and opaque layers appear. For the samples sintered at a lower temperature a decrease in the ceramic granulation from the enamel towards the opaque layer is concluded. The TD-OCT methods can therefore be used efficiently for the detection of the temperature variation due to the ceramic sintering inside the ceramic oven.

  4. Flux Pinning and AC Loss in Second Generation High Temperature Superconductor Wires

    Energy Technology Data Exchange (ETDEWEB)

    Paranthaman, Mariappan Parans [ORNL; Selvamanickam, V. [SuperPower Incorporated, Schenectady, New York

    2007-01-01

    Major advances have been made in the last 18 years in high-temperature superconductor (HTS) reserach and development, resulting in increased use of HTS materials in commerical and pre-commercial electric-power applications. This new and important book addresses the issues related to flux pinning, AC losses and thick YBCO film growth. Written by top most scientists in the world, it presents the current status and issues related to YBCO coated conductors and the need for further fundamental materials science work in YBCO coated conductor. It will be a useful handbook for years to come.

  5. Tunneling spectroscopy on grain boundary junctions in electron-doped high-temperature superconductors

    International Nuclear Information System (INIS)

    Welter, B.

    2007-01-01

    Some methods are developed anf presented, by means of which from experimental tunnel spectra, especially on symmetric SIS contacts, informations about the properties of electrodes and tunnel barriers can be obtained. Especially a procedure for the numerical unfolding of symmetric SIS spectra is proposed. Furthermore a series of models is summarized, which can explain the linear background conductivity observed in many spectra on high-temperature superconductors. The results of resistance measurements on film bridges are presented. Especially different methods for the determination of H c2 (T) respectively H c2 (0) are presented and applied to the experimental data. Finally the results of the tunnel-spectroscopy measurements are shown

  6. Production of high temperature superconductors and characteristics by infrared and Raman spectroscopy

    International Nuclear Information System (INIS)

    Thomsen, C.

    1991-01-01

    This final report, which is partly kept short, is concerned with electron/phonon interaction and the determination of the band gap in high temperature superconductors (YBa 2 Cu 3 O 7 ). The final report is divided into four parts, which reflect the individual working groups: 1. Raman spectroscopy, 2. IR spectroscopy (reflection measurements, isotope effect, superconducting energy gap, behaviour of infrared active phonons), 3. Magnetic field measurements, and 4. Theory (initial calculation of the metal/isolator transfer in BaBiO 3 ). (MM) [de

  7. Possibilities of development photodynamic therapy under high temperature superconductor magnetic field

    International Nuclear Information System (INIS)

    Sen, Mihir

    1996-01-01

    After a long extensive research work neutron photon therapy for treatment of acquired immuno-deficiency syndrome (AIDS) was developed. High temperature superconductor magnet was developed and fitted in magnetic resonance imaging system to guide the patient. By this neutron-photon therapy AIDS effected cells are identified prominently. Patient is then injected with light sensitive drug molecules, which only AIDS cell retain. Light from photon (laser) then energizes the drug, which passes that energy to oxygen, which then leads a biochemical attack on the AIDS cells. If all goes well, the AIDS affected cells die. 10 refs., 1 fig

  8. High transition temperature superconductor/insulator bilayers for the development of ultra-fast electronics

    International Nuclear Information System (INIS)

    Sirena, M.; Félix, L. Avilés; Haberkorn, N.

    2013-01-01

    High transition temperature superconductor (HTc)/SrTiO 3 (STO) bilayers were fabricated by sputtering deposition on (100) STO substrates. Their transport and morphological properties were characterized using conductive atomic force microscopy. The STO barriers present good insulating properties, with long attenuation lengths (λ ∼ 1 nm) which reduce the junction resistance and increase the operating critical current. The samples present roughness values smaller than 1 nm, with an extremely low density of surface defects (∼5 × 10 −5 defects/μm 2 ). The high control of the barrier quality over large defect free surfaces is encouraging for the development of microelectronics devices based in HTc Josephson junctions

  9. Thermally activated flux creep in strongly layered high-temperature superconductors

    International Nuclear Information System (INIS)

    Chakravarty, S.; Ivlev, B.I.; Ovchinnikov, Y.N.

    1990-01-01

    Thermal activation energies for single vortices and vortex bundles in the presence of a magnetic field parallel to the layers are calculated. The pinning considered is intrinsic and is due to the strongly layered structure of high-temperature superconductors. The magnetic field and the current dependence of the activation energy are studied in detail. The calculation of the activation energy is used to determine the current-voltage characteristic. It may be possible to observe the effects discussed in this paper in a pure enough sample

  10. Deficient by oxygen perovskites and superconductor with transition temperature 93 K

    International Nuclear Information System (INIS)

    Ross, N.L.; Angel, R.J.; Finger, L.W.; Hazen, R.M.; Prewitt, K.T.

    1988-01-01

    Structural changes in some perovskites deficient by oxygen is reviewd. The structure of the high-temperature YBa 2 Cu 3 O 7-x superconductor is shown to develop usual for perovskites properties and at the same time to possess specific features. The specific feature includes the fact that ordering of vacancies and oxygen atoms is the consequence of Ba 2+ and Y 3+ ordering in positions A. Such ordering causes the removal of oxygen atoms plane from the structure and accurrence of pyramidal-coordinated atoms Cu2 in positions B. 22 refs.; 3 figs.; 2 tabs

  11. Direct measurement of the Cu oxidation number of cuprate superconductor ceramics

    International Nuclear Information System (INIS)

    Dankhazi, Z.; Szasz, A.; Kojnok, J.; Gal, M.; Torkos, K.; Solymos, K.; Kirchmayr, H.; Mueller, H.; Watson, L.M.

    1991-01-01

    The Cu oxidation number of YBa 2 Cu 3 O 7 was measured directly by soft X-ray fluorescent spectroscopy both at room temperature and at liquid N 2 temperature. The measurements are based on a calibration curve from different Ba-O compounds. The effects of changes in oxidation number above and below the transition temperature and its role in high-T c superconductivity are discussed

  12. To Crack or Not to Crack: Strain in High Temperature Superconductors

    International Nuclear Information System (INIS)

    Godeke, Arno

    2007-01-01

    Round wire Bi 2212 is emerging as a viable successor of Nb3Sn in High Energy Physics and Nuclear Magnetic Resonance, to generate magnetic fields that surpass the intrinsic limitations of Nb3Sn. Rather bold claims are made on achievable magnetic fields in applications using Bi 2212, due to the materials' estimated critical magnetic field of 100 Tor higher. High transport currents in high magnetic fields, however, lead to large stress on, and resulting large strain in the superconductor. The effect of strain on the critical properties of Bi-2212 is far from understood, and strain is, as with Nb3Sn, often treated as a secondary parameter in the design of superconducting magnets. Reversibility of the strain induced change of the critical surface of Nb3Sn, points to an electronic origin of the observed strain dependence. Record breaking high field magnets are enabled by virtue of such reversible behavior. Strain effects on the critical surface of Bi-2212, in contrast, are mainly irreversible and suggest a non-electronic origin of the observed strain dependence, which appears to be dominated by the formation of cracks in the superconductor volumes. A review is presented of available results on the effects of strain on the critical surface of Bi-2212, Bi-2223 and YBCO. It is shown how a generic behavior emerges for the (axial) strain dependence of the critical current density, and how the irreversible reduction of the critical current density is dominated by strain induced crack formation in the superconductor. From this generic model it becomes clear that magnets using high temperature superconductors will be strain limited far before the intrinsic magnetic field limitations will be approached, or possibly even before the magnetic field limitation of Nb3Sn can be surpassed. On a positive note, in a very promising recent result from NIST on the axial strain dependence of the critical current density in extremely well aligned YBCO, reversible behavior was observed. This

  13. Josephson plasma resonance in vortex filament state of high temperature superconductors

    International Nuclear Information System (INIS)

    Matsuda, Yuji; Gaifullin, M.B.

    1996-01-01

    High temperature superconductors have the crystalline structure in which two-dimensional CuO 2 planes are piled in layers, consequently, the anisotropy of electroconductivity arises, and this brings about stable and low energy Josephson plasma in superconducting state. Also as to the vortex filament state of high temperature superconductors, the effect of thermal fluctuation due to low dimensionality, short coherence length and high transition temperature becomes conspicuous. In reality, these plasma and vortex filament state are related closely. Light reflection and plasma edge in superconducting state, Josephson plasma resonance in the vortex filament state of BiO 2 Sr 2 CaCu 2 O 8+δ , the plasma vibration in Josephson junction, Josephson plasma in magnetic field, Josephson plasma in the liquid state of vortex filament, Josephson plasma in the solid state of vortex filament, and Josephson plasma in parallel magnetic field are reported. The Josephson plasma resonance is the experimental means for exploring vortex filament state from microscopic standpoint, and its development hereafter is expected. (K.I.)

  14. Prospects of High Temperature Superconductors for fusion magnets and power applications

    International Nuclear Information System (INIS)

    Fietz, Walter H.; Barth, Christian; Drotziger, Sandra; Goldacker, Wilfried; Heller, Reinhard; Schlachter, Sonja I.; Weiss, Klaus-Peter

    2013-01-01

    Highlights: • An overview of HTS application in fusion is given. • BSCCO application for current leads is discussed. • Several approaches to come to a high current HTS cable are shown. • Open issues and benefits of REBCO high current HTS cables are discussed. -- Abstract: During the last few years, progress in the field of second-generation High Temperature Superconductors (HTS) was breathtaking. Industry has taken up production of long length coated REBCO conductors with reduced angular dependency on external magnetic field and excellent critical current density jc. Consequently these REBCO tapes are used more and more in power application. For fusion magnets, high current conductors in the kA range are needed to limit the voltage during fast discharge. Several designs for high current cables using High Temperature Superconductors have been proposed. With the REBCO tape performance at hand, the prospects of fusion magnets based on such high current cables are promising. An operation at 4.5 K offers a comfortable temperature margin, more mechanical stability and the possibility to reach even higher fields compared to existing solutions with Nb 3 Sn which could be interesting with respect to DEMO. After a brief overview of HTS use in power application the paper will give an overview of possible use of HTS material for fusion application. Present high current HTS cable designs are reviewed and the potential using such concepts for future fusion magnets is discussed

  15. Proceedings of the national symposium on materials and processing: functional glass/glass-ceramics, advanced ceramics and high temperature materials

    International Nuclear Information System (INIS)

    Ghosh, A.; Sahu, A.K.; Viswanadham, C.S.; Ramanathan, S.; Hubli, R.C.; Kothiyal, G.P.

    2012-10-01

    With the development of materials science it is becoming increasingly important to process some novel materials in the area of glass, advanced ceramics and high temperature metals/alloys, which play an important role in the realization of many new technologies. Such applications demand materials with tailored specifications. Glasses and glass-ceramics find exotic applications in areas like radioactive waste storage, optical communication, zero thermal expansion coefficient telescopic mirrors, human safety gadgets (radiation resistance windows, bullet proof apparels, heat resistance components etc), biomedical (implants, hyperthermia treatment, bone cement, bone grafting etc). Advanced ceramic materials have been beneficial in biomedical applications due to their strength, biocompatibility and wear resistance. Non-oxide ceramics such as carbides, borides, silicides, their composites, refractory metals and alloys are useful as structural and control rod components in high temperature fission/ fusion reactors. Over the years a number of novel processing techniques like selective laser melting, microwave heating, nano-ceramic processing etc have emerged. A detailed understanding of the various aspects of synthesis, processing and characterization of these materials provides the base for development of novel technologies for different applications. Keeping this in mind and realizing the need for taking stock of such developments a National Symposium on Materials and Processing -2012 (MAP-2012) was planned. The topics covered in the symposium are ceramics, glass/glass-ceramics and metals and materials. Papers relevant to INIS are indexed separately

  16. Superconductivity degradation in Gd-containing high temperature superconductors (HTSC) under thermal neutron irradiation

    International Nuclear Information System (INIS)

    Petrov, A.; Kudrenitskis, I.; Makletsov, A.; Arhipov, A.; Karklin, N.

    1999-01-01

    The physical properties of ordered crystals are extremely sensitive to the degree of order in the distribution of the various kinds of atoms over the corresponding sites in the crystal lattice. An increasingly popular means of creating disordered states is to use nuclear radiation. The type of radiation defects which appear and the nature and degree of the structural changes in ordered crystals depend on the kind of radiation and the fluence level, the irradiation temperature, the type of crystal structure, the composition and initial disorder of the material, the character of the interatomic forces, etc. There are many such scientific publications where the effects of fast neutron irradiation on high temperature superconductors (HTSC) have been studied in both polycrystalline and single crystalline superconductors. It is known also that the role of thermal neutrons in structural defects forming is negligible in comparison with fast neutrons because of their small (∼0.025 eV) energy. But it is evident enough that in superconductors containing isotopes with large thermal neutron cross sections the important results concerning the role of point defects could be obtained. Such point defects are creating due to soft displacements of isotopes having interacted with thermal neutrons. Such the possibility of creating point defects in solids including HTSC is investigating by several groups (Austria, USA, China, Latvia) and these investigations have found the support in the person of IAEA. In this review the authors consider the changes brought about by thermal-neutron irradiation (E∼0.025 eV) in the structure, superconducting and magnetic properties of gadolinium containing ordered HTSC with the structure 123, whose extreme electric and magnetic properties continue to attract both research and practical interest. All of the studies reviewed have been done on bulk polycrystalline samples RBa 2 Cu 3 O 7-δ (where R - natural mixture of Gd isotopes, 155 Gd, 157 Gd, 160

  17. Pyroelectric Ceramics as Temperature Sensors for Energy System Applications

    Science.gov (United States)

    Silva, Jorge Luis

    Temperature is continuously monitored in energy systems to ensure safe operation temperatures, increase efficiency and avoid high emissions. Most of energy systems operate at high temperature and harsh environments to achieve higher efficiencies, therefore temperature sensing devices that can operate under these conditions are highly desired. The interest has increased in temperature sensors capable to operate and in harsh environments and temperature sensors capable to transmit thermal information wirelessly. One of the solutions for developing harsh environment sensors is to use ceramic materials, especially functional ceramics such as pyroelectrics. Pyroelectric ceramics could be used to develop active sensors for both temperature and pressure due to their capabilities in coupling energy among mechanical, thermal, and electrical domains. In this study, two different pyroelectric materials were used to develop two different temperature sensors systems. First, a high temperature sensor was developed using a lithium niobate (LiNbO3) pyroelectric ceramic. With its Curie temperature of 1210 °C, lithium niobate is capable to maintain its pyroelectric properties at high temperature making it ideal for temperature sensing at high temperature applications. Lithium niobate has been studied previously in the attempt to use its pyroelectric current as the sensing mechanism to measure temperatures up to 500 °C. Pyroelectric coefficient of lithium niobate is a function of temperature as reported in a previous study, therefore a dynamic technique is utilized to measure the pyroelectric coefficient of the lithium niobate used in this study. The pyroelectric coefficient was successfully measured up to 500 °C with coefficients ranging from -8.5 x 10 -5 C/m2 °C at room temperature to -23.70 x 10 -5 C/m2 °C at 500 °C. The lithium niobate sensor was then tested at higher temperatures: 220 °C, 280 °C, 410 °C and 500 °C with 4.31 %, 2.1 %, 0.4 % and 0.6 % deviation

  18. Potential for use of high-temperature superconductors in fusion reactors

    International Nuclear Information System (INIS)

    Hull, J.R.

    1991-01-01

    The present rate of development of high-temperature superconductors (HTSs) is sufficiently rapid that there may be opportunities for their use in contemporary fusion devices such as the International Thermonuclear Experimental Reactor (ITER). The most likely 1application is for delivering power to the superconducting magnets, especially in substituting for the current leads between the temperatures of 4 K and 77K. A second possible application of HTSs is as a liquid-nitrogen-cooled power bus, connecting the power supplies to the magnets, thus reducing the ohmic heating losses over these relatively long cables. A third potential application of HTSs is as an inner high-field winding of the toroidal field coils that would operate at ∼20 K. While the use of higher temperature magnets offers significant advantages to the reactor system, it is unlikely that tested conductors of this type will be available within the ITER time frame. 23 refs., 2 figs

  19. Characterization of high-current, high-temperature superconductor current lead elements

    International Nuclear Information System (INIS)

    Niemann, R.C.; Evans, D.J.; Fisher, B.L.; Brockenborough, W.E.; Roberts, P.R.; Rodenbush, A.J.

    1996-08-01

    The refrigeration loads of current leads for superconducting magnets can be significantly reduced by using high-temperature superconductor (HTS) leads. An HTS conductor type that is well suited for this application is a laminated sintered stack of HTS powder-in-tube (PIT) tapes. The superconducting elements are normally characterized by their manufacturer by measuring critical currents at 77 K in self field. Additional characterization, which correlates electrical performance at 77 K and at lower temperatures with applied magnetic fields, provides the current lead designer and conductor element manufacturer with critical information. For HTS conductor elements comprising a laminated and sintered stack of Bi-2223 PIT tapes having an alloyed Ag sheath, this characterization uses variable applied fields and operating temperatures

  20. An unusual isotope effect in a high-transition-temperature superconductor

    International Nuclear Information System (INIS)

    Gweon, G.-H.; Sasagawa, T.; Zhou, S.Y.; Graf, J.; Takagi, H.; Lee, D.-H.; Lanzara, A.

    2004-01-01

    In conventional superconductors, the electron pairing that allows superconductivity is caused by exchange of virtual phonons, which are quanta of lattice vibration. For high-transition-temperature (high-Tc) superconductors, it is far from clear that phonons are involved in the pairing at all. For example, the negligible change in Tc of optimally doped Bi2Sr2CaCu2O8 (Bi2212) upon oxygen isotope substitution (16O to 18O leads to Tc decreasing from 92 to 91 K) has often been taken to mean that phonons play an insignificant role in this material. Here we provide a detailed comparison of the electron dynamics of Bi2212 samples containing different oxygen isotopes, using angle-resolved photoemission spectroscopy. Our data show definite and strong isotope effects. Surprisingly, the effects mainly appear in broad high-energy humps, commonly referred to as ''incoherent peaks''. As a function of temperature and electron momentum, the magnitude of the isotope effect closely correlates with the superconducting gap--that is, the pair binding energy. We suggest that these results can be explained in a dynamic spin-Peierls picture, where the singlet pairing of electrons and the electron-lattice coupling mutually enhance each other

  1. Nonempirical Calculation of Superconducting Transition Temperatures in Light-Element Superconductors.

    Science.gov (United States)

    Arita, Ryotaro; Koretsune, Takashi; Sakai, Shiro; Akashi, Ryosuke; Nomura, Yusuke; Sano, Wataru

    2017-07-01

    Recent progress in the fully nonempirical calculation of the superconducting transition temperature (T c ) is reviewed. Especially, this study focuses on three representative light-element high-T c superconductors, i.e., elemental Li, sulfur hydrides, and alkali-doped fullerides. Here, it is discussed how crucial it is to develop the beyond Migdal-Eliashberg (ME) methods. For Li, a scheme of superconducting density functional theory for the plasmon mechanism is formulated and it is found that T c is dramatically enhanced by considering the frequency dependence of the screened Coulomb interaction. For sulfur hydrides, it is essential to go beyond not only the static approximation for the screened Coulomb interaction, but also the constant density-of-states approximation for electrons, the harmonic approximation for phonons, and the Migdal approximation for the electron-phonon vertex, all of which have been employed in the standard ME calculation. It is also shown that the feedback effect in the self-consistent calculation of the self-energy and the zero point motion considerably affect the calculation of T c . For alkali-doped fullerides, the interplay between electron-phonon coupling and electron correlations becomes more nontrivial. It has been demonstrated that the combination of density functional theory and dynamical mean field theory with the ab initio downfolding scheme for electron-phonon coupled systems works successfully. This study not only reproduces the experimental phase diagram but also obtains a unified view of the high-T c superconductivity and the Mott-Hubbard transition in the fullerides. The results for these high-T c superconductors will provide a firm ground for future materials design of new superconductors. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. An active homopolar magnetic bearing with high temperature superconductor (HTS) coils and ferromagnetic cores

    Science.gov (United States)

    Brown, G. V.; Dirusso, E.; Provenza, A. J.

    1995-01-01

    A proof-of-feasibility demonstration showed that high temperature superconductor (HTS) coils can be used in a high-load, active magnetic bearing in liquid nitrogen. A homopolar radial bearing with commercially wound HTS (Bi 2223) bias and control coils produced over 200 lb (890 N) radial load capacity (measured non-rotating) and supported a shaft to 14000 rpm. The goal was to show that HTS coils can operate stably with ferromagnetic cores in a feedback controlled system at a current density similar to that in Cu in liquid nitrogen. Design compromises permitted use of circular coils with rectangular cross section. Conductor improvements will eventually permit coil shape optimization, higher current density and higher bearing load capacity. The bias coil, wound with non-twisted, multifilament HTS conductor, required negligible power to carry its direct current. The control coils were wound with monofilament HTS sheathed in Ag. These dissipated negligible power for direct current (i.e. for steady radial load components). When an alternating current (AC) was added, the AC component dissipated power which increased rapidly with frequency and quadratically with AC amplitude. In fact at frequencies above about 2 hz, the effective resistance of the control coil conductor actually exceeds that of the silver which is in electrical parallel with the oxide superconductor. This is at least qualitatively understandable in the context of a Bean-type model of flux and current penetration into a Type II superconductor. Fortunately the dynamic currents required for bearing stability are of small amplitude. These results show that while twisted multifilament conductor is not needed for stable levitation, twisted multifilaments will be required to reduce control power for sizable dynamic loads, such as those due to unbalance.

  3. Robust, high temperature-ceramic membranes for gas separation

    Science.gov (United States)

    Berchtold, Kathryn A.; Young, Jennifer S.

    2014-07-29

    A method of making ceramic membranes, and the ceramic membranes so formed, comprising combining a ceramic precursor with an organic or inorganic comonomer, forming the combination as a thin film on a substrate, photopolymerizing the thin film, and pyrolyzing the photopolymerized thin film.

  4. Electrical properties and temperature stability of a new kind of lead-free piezoelectric ceramics

    International Nuclear Information System (INIS)

    Wang Yuanyu; Wu Jiagang; Xiao Dingquan; Zhang Bin; Wu Wenjuan; Shi Wei; Zhu Jianguo

    2008-01-01

    0.995[(K 0.50 Na 0.50 ) 0.94 Li 0.06 ]NbO 3 -0.005AETiO 3 (AE=Ca, Sr, Mg, Ba) lead-free piezoelectric ceramics were prepared by normal sintering. The effects of the AETiO 3 and poling temperature on the electrical properties of the ceramics were carefully studied, and the temperature stability of the electrical properties of the ceramics was also investigated. The experimental results show that the ceramics with Li and CaTiO 3 possess the pure phase, Li and AETiO 3 improves the electrical properties of the pure (K 0.50 Na 0.50 )NbO 3 ceramics, the poling temperature near tetragonal and orthorhombic phase transition will enhance the piezoelectric properties of the ceramics and the KNLN-CT ceramics exhibit good temperature stability of electrical properties for tetragonal and orthorhombic phase transition below room temperature. The KNLN-CT ceramics exhibit relatively good properties: d 33 = 172 pC N -1 , k p = 0.43, tan δ = 0.032, ε r = 771 and T c = 465 deg. C. As a result, the KNLN-CT ceramic is promising candidate material for piezoelectric devices.

  5. An overview of rotating machine systems with high-temperature bulk superconductors

    Science.gov (United States)

    Zhou, Difan; Izumi, Mitsuru; Miki, Motohiro; Felder, Brice; Ida, Tetsuya; Kitano, Masahiro

    2012-10-01

    The paper contains a review of recent advancements in rotating machines with bulk high-temperature superconductors (HTS). The high critical current density of bulk HTS enables us to design rotating machines with a compact configuration in a practical scheme. The development of an axial-gap-type trapped flux synchronous rotating machine together with the systematic research works at the Tokyo University of Marine Science and Technology since 2001 are briefly introduced. Developments in bulk HTS rotating machines in other research groups are also summarized. The key issues of bulk HTS machines, including material progress of bulk HTS, in situ magnetization, and cooling together with AC loss at low-temperature operation are discussed.

  6. Renormalization effects and phonon density of states in high temperature superconductors

    Directory of Open Access Journals (Sweden)

    Vinod Ashokan

    2013-02-01

    Full Text Available Using the versatile double time thermodynamic Green's function approach based on many body theory the renormalized frequencies, phonon energy line widths, shifts and phonon density of states (PDOS are investigated via a newly formulated Hamiltonian (does not include BCS type Hamiltonian that includes the effects of electron-phonon, anharmonicities and that of isotopic impurities. The automatic appearance of pairons, temperature, impurity and electron-phonon coupling of renormalized frequencies, widths, shifts and PDOS emerges as a characteristic feature of present theory. The numerical investigations on PDOS for the YBa2Cu3O7 − δ crystal predicts several new feature of high temperature superconductors (HTS and agreements with experimental observations.

  7. Quantum oscillations in the parent magnetic phase of an iron arsenide high temperature superconductor

    International Nuclear Information System (INIS)

    Sebastian, Suchitra E; Gillett, J; Lau, P H C; Lonzarich, G G; Harrison, N; Mielke, C H; Singh, D J

    2008-01-01

    We report measurements of quantum oscillations in SrFe 2 As 2 -which is an antiferromagnetic parent of the iron arsenide family of superconductors-known to become superconducting under doping and the application of pressure. The magnetic field and temperature dependences of the oscillations between 20 and 55 T in the liquid helium temperature range suggest that the electronic excitations are those of a Fermi liquid. We show that the observed Fermi surface comprising small pockets is consistent with the formation of a spin-density wave. Our measurements thus demonstrate that high T c superconductivity can occur on doping or pressurizing a conventional metallic spin-density wave state. (fast track communication)

  8. Method for producing ceramic composition having low friction coefficient at high operating temperatures

    Science.gov (United States)

    Lankford, Jr., James

    1988-01-01

    A method for producing a stable ceramic composition having a surface with a low friction coefficient and high wear resistance at high operating temperatures. A first deposition of a thin film of a metal ion is made upon the surface of the ceramic composition and then a first ion implantation of at least a portion of the metal ion is made into the near surface region of the composition. The implantation mixes the metal ion and the ceramic composition to form a near surface composite. The near surface composite is then oxidized sufficiently at high oxidizing temperatures to form an oxide gradient layer in the surface of the ceramic composition.

  9. Contact spectroscopy of high-temperature superconductors (Review). I - Physical and methodological principles of the contact spectroscopy of high-temperature superconductors. Experimental results for La(2-x)Sr(x)CuO4 and their discussion

    Science.gov (United States)

    Ianson, I. K.

    1991-03-01

    Research in the field of high-temperature superconductors based on methods of tunneling and microcontact spectroscopy is reviewed in a systematic manner. The theoretical principles of the methods are presented, and various types of contacts are described and classified. Attention is given to deviations of the measured volt-ampere characteristics from those predicted by simple theoretical models and those observed for conventional superconductors. Results of measurements of the energy gap and fine structure of volt ampere characteristic derivatives are presented for La(2-x)Sr(x)CuO4.

  10. A porous ceramic membrane tailored high-temperature supercapacitor

    Science.gov (United States)

    Zhang, Xin; He, Benlin; Zhao, Yuanyuan; Tang, Qunwei

    2018-03-01

    The supercapacitor that can operate at high-temperature are promising for markedly increase in capacitance because of accelerated charge movement. However, the state-of-the-art polymer-based membranes will decompose at high temperature. Inspired by solid oxide fuel cells, we present here the experimental realization of high-temperature supercapacitors (HTSCs) tailored with porous ceramic separator fabricated by yttria-stabilized zirconia (YSZ) and nickel oxide (NiO). Using activated carbon electrode and supporting electrolyte from potassium hydroxide (KOH) aqueous solution, a category of symmetrical HTSCs are built in comparison with a conventional polymer membrane based device. The dependence of capacitance performance on temperature is carefully studied, yielding a maximized specific capacitance of 272 F g-1 at 90 °C for the optimized HTSC tailored by NiO/YSZ membrane. Moreover, the resultant HTSC has relatively high durability when suffer repeated measurement over 1000 cycles at 90 °C, while the polymer membrane based supercapacitor shows significant reduction in capacitance at 60 °C. The high capacitance along with durability demonstrates NiO/YSZ membrane tailored HTSCs are promising in future advanced energy storage devices.

  11. Electronic structure of the Y Ba{sub 2} Cu{sub 3} O{sub 7-x} high temperature superconductor ceramic; Estrutura eletronica da ceramica supercondutora de alta temperatura Y Ba{sub 2} Cu{sub 3} O{sub 7-x}

    Energy Technology Data Exchange (ETDEWEB)

    Lima, G A.R. [UNESP, Guaratingueta, SP (Brazil). Faculdade de Engenharia. Dept. de Fisica e Quimica

    1991-12-31

    We investigate the electronic structure of superconductor Y Ba{sub 2} Cu{sub 3} O{sub 7-x} through a molecular cluster approach. The calculations are performed self consistently through a semi empirical L.C.A.O. technique, where different charge states are considered. The correlation effects are taken into account by configuration interaction procedure (INDO/CI). The results for the larger cluster yield a density of states showing a strong p-d covalency resulting in a width of around 8,0 eV for the valence band. The optical excitations is analyzed in detail and compared with the experimental data. (author) 18 refs., 2 figs., 1 tab.

  12. Modeling high-temperature superconductors and metallic alloys on the Intel IPSC/860

    Science.gov (United States)

    Geist, G. A.; Peyton, B. W.; Shelton, W. A.; Stocks, G. M.

    Oak Ridge National Laboratory has embarked on several computational Grand Challenges, which require the close cooperation of physicists, mathematicians, and computer scientists. One of these projects is the determination of the material properties of alloys from first principles and, in particular, the electronic structure of high-temperature superconductors. While the present focus of the project is on superconductivity, the approach is general enough to permit study of other properties of metallic alloys such as strength and magnetic properties. This paper describes the progress to date on this project. We include a description of a self-consistent KKR-CPA method, parallelization of the model, and the incorporation of a dynamic load balancing scheme into the algorithm. We also describe the development and performance of a consolidated KKR-CPA code capable of running on CRAYs, workstations, and several parallel computers without source code modification. Performance of this code on the Intel iPSC/860 is also compared to a CRAY 2, CRAY YMP, and several workstations. Finally, some density of state calculations of two perovskite superconductors are given.

  13. A model for calculating the AC losses of second-generation high temperature superconductor pancake coils

    Energy Technology Data Exchange (ETDEWEB)

    Yuan Weijia; Campbell, A M; Coombs, T A [Electronic, Power and Energy Conversion Group, Engineering Department, University of Cambridge, Cambridge CB2 1PZ (United Kingdom)], E-mail: wy215@cam.ac.uk

    2009-07-15

    A model is presented for calculating the AC losses of a stack of second-generation high temperature superconductor tapes. This model takes as a starting point the model of Clem and co-workers for a stack in which each tape carries the same current. It is based on the assumption that the magnetic flux lines lie parallel to the tapes within the part of the stack where the flux has not penetrated. In this paper we allow for the depth of penetration of field to vary across the stack, and use the Kim model to allow for the variation of J{sub c} with B. The model is applied to the cases of a transport current and an applied field. For a transport current the calculated result differs from the Norris expression for a single tape carrying a uniform current and it does not seem possible to define a suitable average J{sub c} which could be used. Our method also gives a more accurate value for the critical current of the stack than other methods. For an applied field the stack behaves as a solid superconductor with the J{sub c} averaged locally over several tapes, but still allowed to vary throughout the stack on a larger scale. For up to about ten tapes the losses rise rapidly with the number of tapes, but in thicker stacks the tapes shield each other and the losses become that of a slab with a field parallel to the faces.

  14. Fabrication and characterization of low temperature co-fired cordierite glass–ceramics from potassium feldspar

    International Nuclear Information System (INIS)

    Wu, Jianfang; Li, Zhen; Huang, Yanqiu; Li, Fei; Yang, Qiuran

    2014-01-01

    Highlights: • Low cost cordierite glass–ceramics were fabricated from potassium feldspar. • The glass–ceramics could be highly densified below 950 °C. • The glass–ceramics exhibit extraordinary properties. • The glass–ceramics can be used as LTCC substrates. • The excess SiO 2 improved the microstructure and properties of the glass–ceramics. -- Abstract: Cordierite glass–ceramics for low temperature co-fired ceramic (LTCC) substrates were fabricated successfully using potassium feldspar as the main raw material. The sintering and crystallization behaviors of the glass–ceramics were investigated by the differential scanning calorimetry (DSC), X-ray diffraction (XRD), and field emission scanning electron microscope (FESEM). The results indicated that the glass–ceramics could be highly densified at 850 °C and the cordierite was the main crystalline phase precipitated from the glasses in the temperature range between 900 and 925 °C. The study also evaluated the physical properties including dielectric properties, thermal expansion and flexural strength of the glass–ceramics. The glass–ceramics showed low dielectric constants in the range of 6–8 and low dielectric losses in the range of 0.0025–0.01. The coefficients of thermal expansion (CTEs) are between 4.32 and 5.48 × 10 −6 K −1 and flexural strength of the glass–ceramics are 90–130 MPa. All of those qualify the glass–ceramics for further research to be used as potential LTCC substrates in the multilayer electronic substrate field. Additionally, the excess SiO 2 acted as a great role in improving the sinterability of the glasses, and the microstructure and dielectric properties of the relevant glass–ceramics

  15. Ceramic Composite Intermediate Temperature Stress-Rupture Properties Improved Significantly

    Science.gov (United States)

    Morscher, Gregory N.; Hurst, Janet B.

    2002-01-01

    Silicon carbide (SiC) composites are considered to be potential materials for future aircraft engine parts such as combustor liners. It is envisioned that on the hot side (inner surface) of the combustor liner, composites will have to withstand temperatures in excess of 1200 C for thousands of hours in oxidizing environments. This is a severe condition; however, an equally severe, if not more detrimental, condition exists on the cold side (outer surface) of the combustor liner. Here, the temperatures are expected to be on the order of 800 to 1000 C under high tensile stress because of thermal gradients and attachment of the combustor liner to the engine frame (the hot side will be under compressive stress, a less severe stress-state for ceramics). Since these composites are not oxides, they oxidize. The worst form of oxidation for strength reduction occurs at these intermediate temperatures, where the boron nitride (BN) interphase oxidizes first, which causes the formation of a glass layer that strongly bonds the fibers to the matrix. When the fibers strongly bond to the matrix or to one another, the composite loses toughness and strength and becomes brittle. To increase the intermediate temperature stress-rupture properties, researchers must modify the BN interphase. With the support of the Ultra-Efficient Engine Technology (UEET) Program, significant improvements were made as state-of-the-art SiC/SiC composites were developed during the Enabling Propulsion Materials (EPM) program. Three approaches were found to improve the intermediate-temperature stress-rupture properties: fiber-spreading, high-temperature silicon- (Si) doped boron nitride (BN), and outside-debonding BN.

  16. Annealing experiments on and high-temperature behavior of the superconductor yttrium barium copper oxide (YBa2Cu3Ox)

    NARCIS (Netherlands)

    Brabers, V.A.M.; Jonge, de W.J.M.; Bosch, L.A.; Steen, van der C.; de Groote, A.M.W.; Verheyen, A.A.; Vennix, C.W.H.M.

    1988-01-01

    The high temperature behaviour (300–1100 K) of the superconductor YBa2Cu3Ox has been studied by annealing experiments, thermal dilatation, thermogravimetry and measurements of the electrical resistance and thermoelectric power. For the fast oxidation process of this compound, reaction enthalpies

  17. Motor models and transient analysis for high-temperature, superconductor switch-based adjustable speed drive applications. Final report

    International Nuclear Information System (INIS)

    Bailey, J.M.

    1996-06-01

    New high-temperature superconductor (HTSC) technology may allow development of an energy-efficient power electronics switch for adjustable speed drive (ASD) applications involving variable-speed motors, superconducting magnetic energy storage systems, and other power conversion equipment. This project developed a motor simulation module for determining optimal applications of HTSC-based power switches in ASD systems

  18. Phase competition and anomalous thermal evolution in high-temperature superconductors

    Science.gov (United States)

    Yu, Zuo-Dong; Zhou, Yuan; Yin, Wei-Guo; Lin, Hai-Qing; Gong, Chang-De

    2017-07-01

    The interplay of competing orders is relevant to high-temperature superconductivity known to emerge upon suppression of a parent antiferromagnetic order typically via charge doping. How such interplay evolves at low temperature—in particular at what doping level the zero-temperature quantum critical point (QCP) is located—is still elusive because it is masked by the superconducting state. The QCP had long been believed to follow a smooth extrapolation of the characteristic temperature T* for the strange normal state well above the superconducting transition temperature. However, recently the T* within the superconducting dome was reported to unexpectedly exhibit back-bending likely in the cuprate Bi2Sr2CaCu2O8 +δ . Here we show that the original and revised phase diagrams can be understood in terms of weak and moderate competitions, respectively, between superconductivity and a pseudogap state such as d -density or spin-density wave, based on both Ginzburg-Landau theory and the realistic t -t'-t''-J -V model for the cuprates. We further found that the calculated temperature and doping-level dependence of the quasiparticle spectral gap and Raman response qualitatively agrees with the experiments. In particular, the T* back-bending can provide a simple explanation of the observed anomalous two-step thermal evolution dominated by the superconducting gap and the pseudogap, respectively. Our results imply that the revised phase diagram is likely to take place in high-temperature superconductors.

  19. Transition conductivity study of high temperature superconductor compounds: the role of fluctuations

    International Nuclear Information System (INIS)

    Pagnon, V.

    1991-04-01

    This memory subject is the transition conductivity study of high temperature superconductors in corelation with their anisotropy. Systematic conductivity measurements were made on YBaCuO and BaSrCaCuO in relation with temperature from 4.2 K to 1200 K, and with a magnetic field up to 8 T in several directions. Oxygen order has an effect on the characteristics at YBaCuO transition conductivity. The activation energy for oxygen absorption is about 0.5eV. One method of analysis of the conductivity fluctuations about the transition temperature is proposed. Two separate rates are noticeable in YBaCuO compound. The 3 D fluctuations rate in the immediate neighbourghood of the transition lets place to the 2 D fluctuations rate at high temperature. Transitions temperatures governing each rate are different, that's incompatible with the formula proposed by Lawrence and Doniach. On the other hand, the analogy with quasi-2 D magnetic systems seems more relevant. A magnetic field application or a lowering of oxygen concentration removes the 3 D fluctuations rate. Non ohmic effects observed at the transition conductivity foot are analysis as a non-linear 2 D excitation manifestation of the supraconductive phase. Finally, by measurements on strontium doped YBaCuO crystals, we confirm a metal-insulator transition along the C-Axe when oxygen concentration reduces. This is connected with the specific heat jump. All these results uplighten the fundamental bidimensional character of high transition temperature superconductivity [fr

  20. First principles simulation on the K0.8Fe2Se2 high-temperature structural superconductor

    International Nuclear Information System (INIS)

    Guo, Rui; Yang, Shizhong; Khosravi, Ebrahim; Zhao, Guang-Lin; Bagayoko, Diola

    2013-01-01

    Highlights: • The superconductor K 0.8 Fe 2 Se 2 super cell size, shape, and atomic positions are fully optimized using first principles density functional theory method. • Each K atom donates 0.8 |e| with K vacancies in the supercell, each Fe atom donates 0.4 |e|, while each Se atom gains 0.7 |e| ∼ 0.8 |e|. • Fe atoms show magnetic moment fluctuation and possible strong spin-orbital coupling. -- Abstract: Since the synthesis of the first ones in 2008, iron-based high temperature superconductors have been the subject of many studies. This great interest is partly due to their higher, upper magnetic field, smaller Fermi surface around the Γ point, and a larger coherence length. This work is focused on A x Fe 2 Se 2 structural superconductor (FeSe, 11 hierarchy; A = K, Cs) as recently observed. ARPES data show novel, electronic structure and a hole-free Fermi surface which is different from previously observed Fermi surface images. We use ab initio density functional theory method to simulate the electronic structure of the novel superconductor A x Fe 2 Se 2 . We compare this electronic structure with those of other Fe-based superconductors

  1. Local valence balance in the structure of a high-temperature superconductor

    International Nuclear Information System (INIS)

    Nalbandyan, V.B.

    1990-01-01

    Hitherto superconductivity of complex oxides has been observed only if the metal is present in a mixed (nonintegral) degree of oxidation. It is of interest to verify the statement that in YBa 2 Cu 3 O x there is no copper in a degree of oxidation above 2+; instead of this, part of the oxygen is in the degree of oxidation 1-. Thus, the calculations of the valence forces tell against the presence of copper in a mixed degree of oxidation between 2+ and 3+ in high-temperature superconductors of the stoichiometric composition RBa 2 Cu 3 O 7 . In two-dimensional layers, copper is in the degree of oxidation 2+ (or even lower), while the electron holes are concentrated in one-dimensional chains - either in the form Cu(3+) or in the form O(1-)

  2. Adaptive Backstepping Control Based on Floating Offshore High Temperature Superconductor Generator for Wind Turbines

    Directory of Open Access Journals (Sweden)

    Feng Yang

    2014-01-01

    Full Text Available With the rapid development of offshore wind power, the doubly fed induction generator and permanent magnet synchronous generator cannot meet the increasing request of power capacity. Therefore, superconducting generator should be used instead of the traditional motor, which can improve generator efficiency, reduce the weight of wind turbines, and increase system reliability. This paper mainly focuses on nonlinear control in the offshore wind power system which is consisted of a wind turbine and a high temperature superconductor generator. The proposed control approach is based on the adaptive backstepping method. Its main purpose is to regulate the rotor speed and generator voltage, therefore, achieving the maximum power point tracking (MPPT, improving the efficiency of a wind turbine, and then enhancing the system’s stability and robustness under large disturbances. The control approach can ensure high precision of generator speed tracking, which is confirmed in both the theoretical analysis and numerical simulation.

  3. Comparison of electromechanical properties and lattice distortions of different cuprate high temperature superconductors

    CERN Document Server

    Scheuerlein, C.; Grether, A; Rikel, M O; Hudspeth, J; Sugano, M; Ballarino, A; Bottura, L

    2016-01-01

    The electromechanical properties of different cuprate high-temperature superconductors, notably two ReBCO tapes, a reinforced and a nonreinforced Bi-2223 tape, and a Bi-2212 wire, have been studied. The axial tensile stress and strain, as well as the transverse compressive stress limits at which an irreversible critical current degradation occurs, are compared. The experimental setup has been integrated in a high-energy synchrotron beamline, and the self-field critical current and lattice parameter changes as a function of tensile stress and strain of a reinforced Bi-2223 tape have been measured simultaneously. Initially, the Bi-2223 filaments exhibit nearly linear elastic behavior up to the strain at which an irreversible degradation is observed. At 77 K, an axial Bi-2223 filament precompression of 0.09% in the composite tape and a Bi-2223 Poisson ratio ν = 0.21 have been determined.

  4. Numerical solutions to the critical state in a magnet-high temperature superconductor interaction

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz-Alonso, D; Coombs, T A; Campbell, A M [Cambridge University Engineering Department, Trumpington Street, Cambridge CB2 1PZ (United Kingdom)

    2005-02-01

    This paper presents an algorithm to simulate the electromagnetic behaviour of devices containing high temperature superconductors in axially symmetric problems. The numerical method is built within the finite element method. The electromagnetic properties of HTSCs are described through the critical-state model. Measurements of the axial force between a permanent magnet and a melt-textured YBCO puck are obtained in order to validate the method. This simple system is modelled so that the proposed method obtains the current distribution and electromagnetic fields in the HTSC. The forces in the interaction between the magnet and the HTSC puck can then be calculated. A comparison between experimental and simulation results shows good matching. The simplification of using the critical-state model and ignoring flux creep in this type of configuration is also explored.

  5. Effect of Abrikosov vortices on Josephson junction currents in high temperature superconductors

    International Nuclear Information System (INIS)

    Mitchell, E.; Mueller, K.-H.

    2000-01-01

    Full text: The current-carrying capacity of high temperature superconductors (HTS) is limited by the weak links which form between individual grains. We investigate the role of Abrikosov vortices (AV) and inhomogeneities at the intergrain boundary by examining the high magnetic field characteristics of HTS thin film grain boundary junctions. We model the effects of junction inhomogeneity, AV's and vortex pinning by solving the inhomogeneous London equation. The calculations show that both inhomogeneities and the presence of AV's improve the current-carrying capacity across grain boundaries at high magnetic fields. Our experimental measurements of the irreversibility of the junction critical current density J c (H a ) find good agreement with the model

  6. Coasting characteristic of the flywheel system under anisotropy effect of bulk high temperature superconductors

    Science.gov (United States)

    Wu, J. F.; Li, Y.

    2014-10-01

    High-temperature superconductors (HTSCs) array with aligned growth section boundary (GSB) pattern (AGSBP) exhibits larger levitation force and suppression of levitation force decay above a permanent magnet guideway (PMG) compared with misaligned GSB pattern (MGSBP) has been studied in maglev train application (Zheng et al., 2013). This result maybe helpful and support a new way for the HTS bearing design for flywheel systems. So, in this paper, we further examine this growth anisotropy effect on the maglev performance of flywheel system. Levitation force and coasting time were investigated from the point-view of HTS flywheel applications. The GS/GSB alignment of AGSBP bulk HTSCs produces larger levitation force than that of MGSBP, but the coasting time is shorter than that of MGSBP, that is to say, the electric magnetic drag force with AGSBP is larger than that of MGSBP. This result may also exist in the maglev guideline when the maglev train stops freely.

  7. A high temperature superconductor tape RF receiver coil for a low field magnetic resonance imaging system

    International Nuclear Information System (INIS)

    Cheng, M C; Yan, B P; Lee, K H; Ma, Q Y; Yang, E S

    2005-01-01

    High temperature superconductor (HTS) thin films have been applied in making a low loss RF receiver coil for improving magnetic resonance imaging image quality. However, the application of these coils is severely limited by their limited field of view (FOV). Stringent fabrication environment requirements and high cost are further limitations. In this paper, we propose a simpler method for designing and fabricating HTS coils. Using industrial silver alloy sheathed Bi (2-x) Pb x Sr 2 Ca 2 Cu 3 O 10 (Bi-2223) HTS tapes, a five-inch single-turn HTS solenoid coil has been developed, and human wrist images have been acquired with this coil. The HTS tape coil has demonstrated an enhanced FOV over a six-inch YBCO thin film surface coil at 77 K with comparable signal-to-noise ratio

  8. Interlaboratory comparison on high-temperature superconductor critical-current measurements

    International Nuclear Information System (INIS)

    Wiejaczka, J.A.; Goodrich, L.F.

    1997-01-01

    An extensive interlaboratory comparison was conducted on high temperature superconductor (HTS) critical-current measurements. This study was part of an international cooperative effort through the Versailles Project on Advanced Materials and Standards (VAMAS). The study involved six US laboratories that are recognized leaders in the field of HTS. This paper includes the complete results from this comparison of critical-current measurements on Ag-sheathed Bi 2 Sr 2 Ca 2 Cu 3 O 10-x (2223) tapes. The effects of sample characteristics, specimen mounting, measurement technique, and specimen damage were studied. The future development of a standard HTS measurement method is also discussed. Most of the evolution of this emerging technology has occurred in improvement of the performance of the conductors. The successful completion of this interlaboratory comparison is an important milestone in the evolution of HTS technology and marks a level of maturity that the technology has reached

  9. High transition temperature superconductor/insulator bilayers for the development of ultra-fast electronics

    Energy Technology Data Exchange (ETDEWEB)

    Sirena, M.; Félix, L. Avilés [Consejo Nacional de Investigaciones Científicas y Técnicas, Centro Atómico Bariloche, CNEA, Bustillo 9500, 8400 Bariloche (Argentina); Instituto Balseiro, Universidad Nacional de Cuyo and CNEA, 8400 Bariloche (Argentina); Haberkorn, N. [Consejo Nacional de Investigaciones Científicas y Técnicas, Centro Atómico Bariloche, CNEA, Bustillo 9500, 8400 Bariloche (Argentina)

    2013-07-29

    High transition temperature superconductor (HTc)/SrTiO{sub 3} (STO) bilayers were fabricated by sputtering deposition on (100) STO substrates. Their transport and morphological properties were characterized using conductive atomic force microscopy. The STO barriers present good insulating properties, with long attenuation lengths (λ ∼ 1 nm) which reduce the junction resistance and increase the operating critical current. The samples present roughness values smaller than 1 nm, with an extremely low density of surface defects (∼5 × 10{sup −5} defects/μm{sup 2}). The high control of the barrier quality over large defect free surfaces is encouraging for the development of microelectronics devices based in HTc Josephson junctions.

  10. Finite-element modelling of superconductors in over-critical regime with temperature dependent resistivity

    International Nuclear Information System (INIS)

    Duron, J; Grilli, F; Antognazza, L; Decroux, M; Stavrev, S; Dutoit, B; Fischer, Oe

    2006-01-01

    In this paper, we present a new numerical model, in which both the thermal and the electromagnetic aspects of the over-critical current regime of HTS materials are taken into account. The electromagnetic and thermal equations have been implemented in finite-element method (FEM) software in order to obtain a novel, closer to reality model for investigating the behaviour of the superconductor when the current exceeds I c . This model has been applied for studying the behaviour of strip lines of an YBCO/Au FCL with a sapphire substrate. Simulations with currents largely exceeding I c have been performed, showing that the total current limitation occurs only when the temperature dependence of the electrical parameters is taken into consideration. Such modelling can replace experiments with currents far exceeding I c which may damage or destroy the studied sample or HTS device

  11. Temperature dependence of positron annihilation parameters in Tl-Ba-Ca-Cu-O superconductors

    International Nuclear Information System (INIS)

    Sundar, C.S.; Bharathi, A.; Ching, W.Y.; Jean, Y.C.; Hor, P.H.; Meng, R.L.; Huang, Z.J.; Chu, C.W.

    1990-01-01

    The results of positron lifetime and Doppler broadened line-shape parameter measurements as a function of temperature, across T c , in the Tl-Ba-Ca-Cu-O superconductors are presented. The bulk lifetime in the normal state is found to decrease with the increase in the number of CuO 2 layers. Different temperature dependencies of the annihilation parameters are observed in the various Tl systems containing different numbers of CuO 2 layers. In the Tl 2 Ba 2 Ca 2 Cu 3 O 10 system, an increase in lifetime is observed below T c , whereas in Tl 2 Ba 2 CaCu 2 O 8 , a decrease in lifetime is seen below T c . In the Tl 2 Ba 2 CuO 6 system, the lifetime is observed to be temperature independent. The different temperature variations of positron annihilation parameters are discussed in the light of the positron density distribution, obtained with use of the results of the self-consistent orthogonalized linear combination of atomic orbitals band-structure calculations. It is argued that the different temperature dependencies of the annihilation parameters is related to the positron density distribution within the unit cell and arise due to local charge transfer in the vicinity of the CuO 2 layer in the superconducting state

  12. Dopant structural distortions in high-temperature superconductors: an active or a passive role?

    International Nuclear Information System (INIS)

    Haskel, D.; Stern, E.A.; Dogan, F.; Moodenbaugh, A.R.

    2001-01-01

    The parent compounds of high-temperature superconductors, such as YBa 2 Cu 3 O 6 and La 2 CuO 4 , are strongly interacting electron systems, rendering them insulators with Mott-Hubbard gaps of a few electron volts. Charge carriers (holes) are introduced by chemical doping, causing an insulator-metal (IM) transition and, at low temperatures, superconductivity. The role of dopants is widely seen as limited to the introduction of holes into the CuO 2 planes (i.e. occupying electronic states derived from Cu 3d x2-y2 and O 2p x,y atomic orbitals). Most theories of high-T c superconductivity deal with pairing interactions between these planar holes. Local distortions around dopants are poorly understood, because of the experimental difficulty in obtaining such information, particularly at low doping. This has resulted in the neglect, in most theories, of the effect of such distortions on the chemical and electronic structure of high-T c superconductors. Angular-resolved X-ray absorption fine structure (XAFS) spectroscopy on oriented samples is an ideal technique to elucidate the dopant distortions. Element specificity, together with a large orientation dependence of the XAFS signal in these layered structures, allows the local structure around dopants to be resolved. Results are presented here on (Sr, Ba) and Ni dopants, which substitute at the La and Cu sites, respectively, of insulating La 2 CuO 4 . The relevance of the measured local distortions for a complete understanding of the normal and superconducting properties of cuprates is discussed. (au)

  13. Fatigue limit of polycrystalline zirconium oxide ceramics: effect of grinding and low-temperature aging

    NARCIS (Netherlands)

    Pereira, G.K.R.; Silvestri, T.; Amaral, M.; Rippe, M.P.; Kleverlaan, C.J.; Valandro, L.F.

    2016-01-01

    The following study aimed to evaluate the effect of grinding and low-temperature aging on the fatigue limit of Y-TZP ceramics for frameworks and monolithic restorations. Disc specimens from each ceramic material, Lava Frame (3M ESPE) and Zirlux FC (Ivoclar Vivadent) were manufactured according to

  14. Microstructural factors influencing critical-current densities of high-temperature superconductors

    International Nuclear Information System (INIS)

    Suenaga, M.

    1992-01-01

    Microstructural defects are the primary determining factors for the values of critical current densities in superconductors. A review is made to assess, (1) what would be the maximum achievable critical-current density in the oxide superconductors if nearly ideal pinning sites were introduced? and (2) what types of pinning defects are currently introduced in these superconductors and how effective are these in pinning the vortices? Only the case where the applied field is parallel to the c-axis is considered here

  15. Technique of Critical Current Density Measurement of Bulk Superconductor with Linear Extrapolation Method

    International Nuclear Information System (INIS)

    Adi, Wisnu Ari; Sukirman, Engkir; Winatapura, Didin S.

    2000-01-01

    Technique of critical current density measurement (Jc) of HTc bulk ceramic superconductor has been performed by using linear extrapolation with four-point probes method. The measurement of critical current density HTc bulk ceramic superconductor usually causes damage in contact resistance. In order to decrease this damage factor, we introduce extrapolation method. The extrapolating data show that the critical current density Jc for YBCO (123) and BSCCO (2212) at 77 K are 10,85(6) Amp.cm - 2 and 14,46(6) Amp.cm - 2, respectively. This technique is easier, simpler, and the use of the current flow is low, so it will not damage the contact resistance of the sample. We expect that the method can give a better solution for bulk superconductor application. Key words. : superconductor, critical temperature, and critical current density

  16. Nonlocal electrodynamics and low-temperature magnetization of clean high-κ superconductors

    International Nuclear Information System (INIS)

    Kogan, V.G.; Gurevich, A.; Cho, J.H.; Johnston, D.C.; Xu, M.; Thompson, J.R.; Martynovich, A.

    1996-01-01

    We show that magnetic properties of clean superconductors with a large Ginzburg-Landau parameter κ at low temperatures are affected by the nonlocality of the microscopic current-field relation and can be described by modified London equations. We argue that for clean materials at low temperatures, the standard London formula for the reversible magnetization in intermediate fields, M∼ln(H c2 /B), should contain the field H 0 ∼φ 0 /ρ 2 instead of H c2 ∼φ 0 /ξ 2 (T), with ρ being the nonlocality range on the order of ξ 0 , the zero-T coherence length. Since ρ depends weakly on T, the magnetization should exhibit an approximate scaling M(T,B)=X(T)Y(B) as observed in Bi- and Tl-based compounds in a broad temperature domain well below T c . Our expression for the magnetization reduces to the standard London result near T c and at any temperature for the dirty case. Implications of our results for interpretation of neutron scattering data and for procedures of extracting the penetration depth are discussed. copyright 1996 The American Physical Society

  17. Effect of Au nano-particles doping on polycrystalline YBCO high temperature superconductor

    Energy Technology Data Exchange (ETDEWEB)

    Dadras, Sedigheh, E-mail: dadras@alzahra.ac.ir; Gharehgazloo, Zahra

    2016-07-01

    In this research, we prepared different Au nanoparticles (0.1–2 wt%) doped YBCO high temperature superconductor samples by sol-gel method. To characterize the samples, we used X-Ray diffraction (XRD) and scanning electron microscope (SEM) analysis. Results show the formation of orthorhombic phase of superconductivity for all prepared samples. We observed that by adding Au nanoparticles, the grains' size of the samples reduces from 76 nm to 47 nm as well. The critical current density (J{sub c}) and transition temperature (T{sub c}) were determined using current versus voltage (I–V) and resistivity versus temperature (ρ-T) measurements, respectively. We found that by increasing Au nanoparticles in the compound, in comparison to the pure YBCO sample, the transition temperature, pinning energy and critical current density will increase. Also, the highest J{sub c} is for 1 wt% Au doped YBCO compound that its critical current density is about 8 times more than the J{sub c} of pure one in 0.7 T magnetic field.

  18. High-frequency applications of high-temperature superconductor thin films

    Science.gov (United States)

    Klein, N.

    2002-10-01

    High-temperature superconducting thin films offer unique properties which can be utilized for a variety of high-frequency device applications in many areas related to the strongly progressing market of information technology. One important property is an exceptionally low level of microwave absorption at temperatures attainable with low power cryocoolers. This unique property has initiated the development of various novel type of microwave devices and commercialized subsystems with special emphasis on application in advanced microwave communication systems. The second important achievement related to efforts in oxide thin and multilayer technology was the reproducible fabrication of low-noise Josephson junctions in high-temperature superconducting thin films. As a consequence of this achievement, several novel nonlinear high-frequency devices, most of them exploiting the unique features of the ac Josephson effect, have been developed and found to exhibit challenging properties to be utilized in basic metrology and Terahertz technology. On the longer timescale, the achievements in integrated high-temperature superconductor circuit technology may offer a strong potential for the development of digital devices with possible clock frequencies in the range of 100 GHz.

  19. High-frequency applications of high-temperature superconductor thin films

    International Nuclear Information System (INIS)

    Klein, N.

    2002-01-01

    High-temperature superconducting thin films offer unique properties which can be utilized for a variety of high-frequency device applications in many areas related to the strongly progressing market of information technology. One important property is an exceptionally low level of microwave absorption at temperatures attainable with low power cryocoolers. This unique property has initiated the development of various novel type of microwave devices and commercialized subsystems with special emphasis on application in advanced microwave communication systems. The second important achievement related to efforts in oxide thin and multilayer technology was the reproducible fabrication of low-noise Josephson junctions in high-temperature superconducting thin films. As a consequence of this achievement, several novel nonlinear high-frequency devices, most of them exploiting the unique features of the ac Josephson effect, have been developed and found to exhibit challenging properties to be utilized in basic metrology and Terahertz technology. On the longer timescale, the achievements in integrated high-temperature superconductor circuit technology may offer a strong potential for the development of digital devices with possible clock frequencies in the range of 100 GHz. (author)

  20. Investigation of thin films, heterostructures and devices of ceramic superconductors by means of high-resolution electron microscopy

    International Nuclear Information System (INIS)

    Jia Chunlin.

    1993-08-01

    In this thesis a systematic study of the microstructure of YBa 2 Cu 3 O 7 thin films is presented by means of high-resolution electron microscopy (HREM). Most of the efforts are focused on the characterization of heterostructures of superconducting YBa 2 Cu 3 O 7 and non-superconducting PrBa 2 Cu 3 O 7 and on YBa 2 Cu 3 O 7 films deposited on step-edge substrates. These specially designed structures exhibit a great potential for the electronic application of high-Tc superconductors and for the investigation of the basic electric properties of the YBa 2 Cu 3 O 7 superconductor. (orig.) [de

  1. Study of the magnetic field distribution in high-temperature superconductors using muon-spin-rotation

    International Nuclear Information System (INIS)

    Zimmermann, P.R.

    1994-01-01

    Detailed and systematic μ + SR experiments have been performed in order to (i) investigate the temperature dependence of the magnetic penetration depth in various cuprate high-T c superconductors and (ii) study the vortex structures and dynamics in the highly anisotropic Bi 2 Sr 2 CaCu 2 O 8 . The μ + SR method and its application to superconductivity has been discussed. The positive muon is a microscopic probe of the local magnetic field in the bulk of a sample. The μ + SR technique can therefore measure the magnetic field distribution p(B) which is determined by the flux structure in the superconductor. The second moment (ΔB 2 ) of p(B) is closely related to the magnetic penetration depth λ, a fundamental parameter of superconductivity. It has been shown that in high-quality sintered samples a good estimate of the in-plane penetration depth λ ab can be given in terms of the muon-depolarization rate σ. Since the penetration depth is related to the superconducting order parameter, the temperature dependence of the penetration depth is a potential probe of the pairing state. Systematic measurements of the temperature dependence of σ have been performed in sintered samples of high quality in various members of the Y123 family, Pb and Y doped Tl1212 family, and also in Y124 and Bi2212. It is found that the extracted temperature behaviour of λ ab -2 is characteristic of each compound. This can be interpreted as a varying coupling strength in these systems. In well oxygenated Y123, λ ab -2 (T) is well described by the two-fluid model indicating strong coupling. The rest of the cuprates investigated show a λ ab -2 (T) which points to weaker coupling, with λ ab -2 (T) of highly oxygen deficient Y123 being similar to the weak-coupling BCS prediction. In the Y123 family the decreasing coupling strength with decreasing oxygen content is related to the increasing anisotropy. Comparison with theoretical predictions of λ ab -2 (T) revealed that the observed

  2. Influence of pulse electric current on structure and superconducting properties of high temperature superconductor

    International Nuclear Information System (INIS)

    Rajchenko, A.I.; Flis, A.A.; Chernenko, L.I.; Kryuchkova, N.I.

    1998-01-01

    The influence of high-density pulse current treatment at room temperature on structure and superconducting properties of HTSC Y Ba 2 Cu 3 O x ceramics is studied. The structures of the samples are found to undergo appreciable changes as the density of pulse current is gradually increased from its minimum value; as a certain threshold value is attained, there occurs a melting-off of coarse grains with a partial destroying of intergrain contact areas followed by superconductivity loss. A further increase in the treatment current density results in a restoration of the superconducting properties probably due to the occurrence of aligned-with-current superconducting bridges between the melted-off grains. The superconducting transition temperature in the samples does not charge but subsequent thermal treatment causes this temperature to increase

  3. Fracture Toughness of Ceramics Fired at Different Temperatures

    Directory of Open Access Journals (Sweden)

    Peter SIN

    2012-03-01

    Full Text Available The fracture toughness test was performed at room temperature on sets of 5 ceramic samples made from material for high voltage insulators (kaolin 36 wt. %, Al2O3 30 wt. %, clay 12 wt. % and feldspar 22 wt. % fired at temperatures 400, 500, 600, 700, 800, 900, 1000, 1100, 1200, 1250, 1300, 1400, 1500 °C at heating and cooling rate of 5 °C/min. The precrack was made to each sample by indentation under the loads 10 N – 200 N, the dwell time was 45 s and the loading rate was 10 N/s. Results of the fracture toughness tests were in accordance with changes of structure of the samples after the partial firings. Fracture toughness from 20 °C to 500 °C is almost constant and it varies between 0.1 MPa·m0.5and 0.2 MPa·m0.5. Dehydroxylation (420 °C – 600 °C does not influence the value of fracture toughness. At temperature interval where we assume sintering (700 °C – 1250 °C we observe exponential dependence of fracture toughness up to 1.5 MPa·m0.5. From comparison of the fracture toughness, Young’s modulus and flexural strength follows a correlation and proporcionality of these mechanical properties.DOI: http://dx.doi.org/10.5755/j01.ms.18.1.1349

  4. Processing of Mixed Oxide Superconductors

    Science.gov (United States)

    1990-07-01

    rapid changes world wide a major research centre on high Tc superconductors was awarded to Cambridge which involved moving the work and people to a...reports and paper is in the appendices. Separation Ceramic superconductors tend to be mixtures of phases, especially when first discovered. It would...properties of the superconducting state will in principle allow superconducting material to be levitated from the non superconductor and several designs

  5. Noise measurements of YBa2Cu3O7 thin film high-temperature superconductors

    International Nuclear Information System (INIS)

    Hall, J.J.

    1992-01-01

    The characteristics of thin-film YBa2Cu3O7 superconductors were studied from the superconducting region through the transition region and into the normal region. The properties studied included the resistance-temperature, current-voltage, and electrical noise with concentration of measurements in the transition region. The resistance vs. temperature measurements show a zero resistance followed by a small rise in magnitude at the onset of resistance followed by a sharp increase until the resistance tapers off in the fully normal region. The a-axis films had a larger normal resistivity, a lower critical temperature, and a broader transition than the similar c-axis films. The current(I) - voltage(V) measurements were concentrated in the transition region. A power relation between I and V was found to be V varies as I a(T) where a(T) is temperature dependent starting high the onset of vortex formation, approaches 3 at the vortex unbinding temperature, and goes to 1 when fully normal. This behavior was predicted by the Kosterlitz-Thouless theory and was found experimentally in all four films measured. The current-induced electrical noise characteristics were measured for four samples varying in thickness and axis orientation. Each film exhibited a widely varying magnitude of the noise voltage spectral density (S V ) in the transition region with a leveling off when fully normal. The normalized noise (S V /V squared) showed a sharp decrease in magnitude from the onset of measurable noise continually decreasing until flattening out when fully normal. The a-axis films exhibited S V /V squared over 3 order of magnitude larger than the c-axis films in the transition and normal regions. The normalized temperature coefficient of resistance (beta) was plotted against S V /V squared on a log-log scale to see if the noise generated was due to temperature fluctuations (slope = 2)

  6. Synthesis of Highly Uniform and Compact Lithium Zinc Ferrite Ceramics via an Efficient Low Temperature Approach.

    Science.gov (United States)

    Xu, Fang; Liao, Yulong; Zhang, Dainan; Zhou, Tingchuan; Li, Jie; Gan, Gongwen; Zhang, Huaiwu

    2017-04-17

    LiZn ferrite ceramics with high saturation magnetization (4πM s ) and low ferromagnetic resonance line widths (ΔH) represent a very critical class of material for microwave ferrite devices. Many existing approaches emphasize promotion of the grain growth (average size is 10-50 μm) of ferrite ceramics to improve the gyromagnetic properties at relatively low sintering temperatures. This paper describes a new strategy for obtaining uniform and compact LiZn ferrite ceramics (average grains size is ∼2 μm) with enhanced magnetic performance by suppressing grain growth in great detail. The LiZn ferrites with a formula of Li 0.415 Zn 0.27 Mn 0.06 Ti 0.1 Fe 2.155 O 4 were prepared by solid reaction routes with two new sintering strategies. Interestingly, results show that uniform, compact, and pure spinel ferrite ceramics were synthesized at a low temperature (∼850 °C) without obvious grain growth. We also find that a fast second sintering treatment (FSST) can further improve their gyromagnetic properties, such as higher 4πM s and lower ΔH. The two new strategies are facile and efficient for densification of LiZn ferrite ceramics via suppressing grain growth at low temperatures. The sintering strategy reported in this study also provides a referential experience for other ceramics, such as soft magnetism ferrite ceramics or dielectric ceramics.

  7. Improving superconducting properties of YBCO high temperature superconductor by Graphene Oxide doping

    Energy Technology Data Exchange (ETDEWEB)

    Dadras, S., E-mail: dadras@alzahra.ac.ir; Dehghani, S.; Davoudiniya, M.; Falahati, S.

    2017-06-01

    In this research, we report the synthesis and characterization of YBa{sub 2}Cu{sub 3}O{sub 7-δ} (YBCO) high temperature superconductor prepared by sol-gel method and doped with Graphene Oxide (GO) in different weight percentages, 0, 0.1, 0.7 and 1 % wt. The x-ray diffraction (XRD) analysis confirms the formation of orthorhombic phase of superconductivity for all the prepared samples. We found that GO doping reduces the crystalline size of the samples. We evaluated the effects of GO doping on the normal state resistivity (ρ), superconducting transition temperature (T{sub c}) and critical current density (J{sub c}). The results show that the GO doping has a positive effect on these properties. Also, the highest J{sub c} is obtained for the 0.7 %wt GO doped YBCO compound that its critical current density is about 15 times more than the J{sub c} of pure one in 0.4 T magnetic field. The scanning electron microscope (SEM) analysis shows that there are better connections between the grains of GO doped samples. - Highlights: • Graphene Oxide doping increased the YBCO critical current density. • Graphene Oxide creates a better connection between the YBCO grains. • The normal resistivity of samples were decreased by GO doping to YBCO compounds. • Graphene Oxide doping has a positive effect on the critical transition temperature.

  8. Low-temperature deuteron irradiation of differently reacted Nb3Sn superconductors

    International Nuclear Information System (INIS)

    Maier, P.; Seibt, E.

    1978-01-01

    Irradiation measurements with 50 MeV deuterons at 18 K and subsequent annealing measurements were performed on Nb 3 Sn single and multifilamentary superconductors at the Helium-Bath Irradiation Facility of the Karlsruhe Cyclotron. The critical current densities jsub(c) of Nb 3 Sn bronze-reacted wire samples at various reaction temperatures (Tsub(R)=650,700,750,800 and 850 0 C) with equal layer thickness were measured for integral deuteron fluxes up to PHIsub(t)=0.7x10 18 cm -2 . After a decrease in jsub(c) of 85% at maximum dose a relatively small annealing effect (4 to 10%) was observed at ambient temperatures. The maximum value of the normalized critical current density, jsub(c)/jsub(c0), at PHIsub(t)approximately=10 17 cm -2 increases with increasing reaction temperature. The difference in volume pinning forces before and after irradiation increases less than linear (approximately√PHIsub(t)) with the irradiation dose. An almost linear dependence between the inverse grain diameter (dsub(K) -1 )) and volume pinning force is obtained both before and after irradiation. (Auth.)

  9. Low temperature London penetration depth and superfluid density in Fe-based superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hyunsoo [Iowa State Univ., Ames, IA (United States)

    2013-01-01

    The superconducting gap symmetry of the Fe-based superconductors was studied by measurements and analysis of London penetration depth and super uid density. Tunnel diode resonator technique for these measurements was implemented in a dilution refrigerator allowing for the temperatures down to 50 mK. For the analysis of the super uid density, we used both experimental studies of Al-coated samples and original thermodynamic approach based on Rutgers relation. In three systems studied, we found that the superconducting gap at the optimal doping is best described in multi-gap full gap scenario. By performing experiments on samples with arti cially introduced disorder with heavy ion irradiation, we show that evolution of the superconducting transition temperature and of the super uid density are consistent with full-gap sign changing s superconducting state. The superconducting gap develops strong modulation both in the under-doped and the over-doped regimes. In the terminal hole-doped KFe{sub 2}As{sub 2}, both temperature dependence of the super uid density and its evolution with increase of the scattering rate are consistent with symmetry imposed vertical line nodes in the superconducting gap. By comparative studies of hole-doped (Ba,K)Fe{sub 2}As{sub 2} and electron-doped Ca10-3-8, we show that the superconducting gap modulation in the under-doped regime is intrinsic and is not induced by the coexisting static magnetic order.

  10. Effect of impurity scattering on the low temperature magnetic penetration depth of a nonlocal and nonlinear d-wave superconductor

    International Nuclear Information System (INIS)

    Yavary, H.

    2006-01-01

    The magnetic penetration depth of a quasi-two dimensional d-wave superconductor in the presence of nonlineary, nonlocality, and impurity effects is investigated by using Green's function method. It is shown that a d-wave superconductor would inevitably avoid the violation of the Nernst theorem by creating a T 2 term in its penetration depth through a competition of nonlinear, nonlocal, and impurity effects and this system may be stable at low temperatures. I also show that in the impure sample at low temperatures, T < T * ∝ γ the impurity effect determines the temperature dependence of the penetration depth, i.e., nonlocal and nonlinear effects are completely masked by impurities

  11. Evaluation of Ultra-High Temperature Ceramics for Aeropropulsion Use

    Science.gov (United States)

    Levine, Stanley R.; Opila, Elizabeth J.; Halbig, Michael C.; Kiser, James D.; Singh, Mrityunjay; Salem, Jonathan A.

    2001-01-01

    Among the ultra-high temperature ceramics (UHTC) are a group of materials consisting of zirconium diboride or hafnium diboride plus silicon carbide, and in some instances, carbon. These materials offer a good combination of properties that make them candidates for airframe leading edges on sharp-bodied reentry vehicles. These UHTC perform well in the environment for such applications, i.e., air at low pressure. The purpose of this study was to examine three of these materials under conditions more representative of a propulsion environment, i.e., higher oxygen partial pressure and total pressure. Results of strength and fracture toughness measurements, furnace oxidation and high velocity thermal shock exposures are presented for ZrB2 plus 20 volume % SiC, ZrB2 plus 14 volume % SiC plus 30 volume % C, and SCS-9a SiC fiber reinforced ZrB2 plus 20 volume % SiC. The poor oxidation resistance of UHTCs is the predominant factor limiting their applicability to propulsion applications.

  12. low temperature irradiation effects in iron-alloys and ceramics

    International Nuclear Information System (INIS)

    Kuramoto, Eiichi; Abe, Hironobu; Tanaka, Minoru; Nishi, Kazuya; Tomiyama, Noriyuki.

    1991-01-01

    Electron beam irradiation at 77K and neutron irradiation at 20K were carried out on Fe-Cr and Fe-Cr-Ni alloys and ZnO and graphite system ceramics, and by measuring positron annihilation lifetime, the micro-information about irradiation-introduced defects was obtained. The temperature of the movement of atomic vacancies in pure iron is about 200K, but it was clarified that by the addition of Cr, it was not much affected. However, in the case of high concentration Cr alloys, the number of atomic vacancies which take part in the formation of micro-voids decreased as compared with the case of pure iron. It is considered that among the irradiation defects of ZnO, O-vac. restored below 300degC. It is considered that in the samples without irradiation, the stage of restoration exists around 550degC, which copes with structural defects. By the measurement of graphite without irradiation, the positron annihilation lifetime corresponding with the interface of matrix and crystal grains, grain boundaries and internal surfaces was almost determined. The materials taken up most actively in the research and development of nuclear fusion reactor materials are austenitic and ferritic stainless steels, and their irradiation defects have been studied. (K.I.)

  13. Plastic deformation of YBa2Cu3O7-x superconductor compound

    International Nuclear Information System (INIS)

    Torres V, G.; Moreno, J.E.

    1988-01-01

    The high temperature superconductor YBa 2 Cu 3 O 7-x shown a brittle behavior when deformed under ambient conditions. If a hydrostatic state of stress is imposed with a metal matrix, it is possible to induce exttended plastic deformations as a great as 200% were achieved using this method without loosing the superconductivity in the ceramic. The observed deformations mechanisms are similar to those observed in the superplastic metals and the boundary ceramic metal matrix was found to be highly coherent. This method opens a new technique that can be apllied in the manufacture of superconductor wire. (author) [pt

  14. Ultra High Temperature and Multifunctional Ceramic Matrix Composite – Coating Systems for Light-Weight Space and Aero Systems

    Data.gov (United States)

    National Aeronautics and Space Administration — Revolutionary ultra-high temperature, high mechanical loading capable, oxidation resistant, durable ceramic coatings and light-weight fiber-reinforced Ceramic Matrix...

  15. Measurement of temperature fields in specimens of quartz ceramic during surface ablation

    Science.gov (United States)

    Frolov, G. A.; Pasichnyi, V. V.; Suzdal'Tsev, E. I.; Tsyganenko, V. S.

    1989-08-01

    The authors propose a method of mounting thermocouples and have obtained temperature fields within specimens of pure and doped quartz ceramic. The linearity of the dependenceΔ * = fleft( {sqrt tau } right) for deep isotherms has been proved experimentally.

  16. Laser treatment of dental ceramic/cement layers: transmitted energy, temperature effects and surface characterisation.

    Science.gov (United States)

    Pich, Olena; Franzen, René; Gutknecht, Norbert; Wolfart, Stefan

    2015-02-01

    In the present paper, we investigate the behaviour of different dental materials under laser irradiation. We have used e.max Ceram, e.max ZirCAD, and e.max Press dental ceramics and glass ionomer cement Ketac Cem in the present study. The dental ceramics were prepared in the form of samples with thickness of 0.5-2 mm. We used two lasers [solid-state laser (Er:YAG, Fidelis III+, Fotona) and an 810- nm diode laser (FOX, A.R.C)] for the transillumination of ceramic samples. It has been shown that the laser energy transmitted through the ceramic material decreases to 30-40% of the original values along with an increase in the thickness of the irradiated sample. Pigmented ceramic samples show more laser energy loss compared to the samples containing no pigment. We investigated the temperature evolution in composite sandwiched ceramic/cement samples under laser treatment. The increase in the irradiation time and laser power led to a temperature increase of up to 80 °C. The surfaces of irradiated ceramic samples were examined with X-ray photoelectron spectroscopy to evaluate changes in chemical composition, such as a decrease in the C signal, accompanied by a strong increase in the Zr peak for the Er:YAG laser, while the 810-nm diode laser showed no change in the ratio of elements on the surface.

  17. Spin dynamics in the pseudo-gap state of a high-temperature superconductor

    Energy Technology Data Exchange (ETDEWEB)

    Hinkov, V; Lin, C T; Chen, D P; Keimer, B [Max Planck Inst Solid State Res, D-70569 Stuttgart, (Germany); Bourges, P; Pailhes, S; Sidis, Y [CEA, CNRS, CE Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, (France); Ivanov, A [Inst Max Von Laue Paul Langevin, F-38042 Grenoble, (France); Frost, C D; Perring, T G [Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, (United Kingdom)

    2007-07-01

    The pseudo-gap is one of the most pervasive phenomena of high-temperature superconductors. It is attributed either to incoherent Cooper pairing setting in above the superconducting transition temperature, Tc, or to a hidden order parameter competing with superconductivity. Here, we use inelastic neutron scattering from under-doped YBa{sub 2}Cu{sub 3}O{sub 6.6} to show that the dispersion relations of spin excitations in the superconducting and pseudo-gap states are qualitatively different. Specifically, the extensively studied 'hour glass' shape of the magnetic dispersions in the superconducting state is no longer discernible in the pseudo-gap state and we observe an unusual 'vertical' dispersion with pronounced in-plane anisotropy. The differences between superconducting and pseudo-gap states are thus more profound than generally believed, suggesting a competition between these two states. Whereas the high-energy excitations are common to both states and obey the symmetry of the copper oxide square lattice, the low-energy excitations in the pseudo-gap state may be indicative of collective fluctuations towards a state with broken orientational symmetry predicted in theoretical work. (authors)

  18. Maglev performance of a double-layer bulk high temperature superconductor above a permanent magnet guideway

    International Nuclear Information System (INIS)

    Deng, Z; Wang, J; Zheng, J; Lin, Q; Zhang, Y; Wang, S

    2009-01-01

    In order to improve the performance of the present high temperature superconducting (HTS) maglev vehicle system, the maglev performance of single- and double-layer bulk high temperature superconductors (HTSC) was investigated above a permanent magnet guideway (PMG). It is found that the maglev performance of a double-layer bulk HTSC is not a simple addition of each layer's levitation and guidance force. Moreover, the applied magnetic field at the position of the upper layer bulk HTSC is not completely shielded by the lower layer bulk HTSC either. 53.5% of the levitation force and 27.5% of the guidance force of the upper layer bulk HTSC are excited in the double-layer bulk HTSC arrangement in the applied field-cooling condition and working gap, bringing a corresponding improvement of 16.9% and 8.8% to the conventional single-layer bulk HTSC. The present research implies that the cost performance of upper layer bulk HTSC is a little low for the whole HTS maglev system.

  19. Singularity in the positive Hall coeffcient near pre-onset temperatures in high-Tc superconductors

    Science.gov (United States)

    Vezzoli, G. C.; Chen, M. F.; Craver, F.; Moon, B. M.; Safari, A.; Burke, T.; Stanley, W.

    1990-10-01

    Hall measurements using continuous extremely slow cooling and reheating rates as well as employing eqiulibrium point-by-point conventional techniques reveals a clear anomally in RH at pre-onset temperatures near Tc in polycrystalline samples Y1Ba2Cu3O7 and Bi2Sr2Ca2Cu3O10. The anomaly has the appearance of a singularity of Dirac-delta function which parallels earlier work on La1-xSrxCuO4. Recent single crystal work on the Bi-containing high-Tc superconductor is in accord with a clearcut anomaly. The singularity is tentatively interpreted to be associated (upon cooling) with initially the removal of positive holes from the hopping conduction system of the normal state such as from the increased concentration of bound virtual excitons due to increased exciton and hole lifetimes at low temperature. Subsequently the formation of Cooper pairs by mediation from these centers (bound-holes) and/or bound excitons) may cause an ionization of these bound virtual excitons thereby re-introducing holes and electrons into the conduction system at Tc.

  20. Maglev performance of a double-layer bulk high temperature superconductor above a permanent magnet guideway

    Energy Technology Data Exchange (ETDEWEB)

    Deng, Z; Wang, J; Zheng, J; Lin, Q; Zhang, Y; Wang, S [Applied Superconductivity Laboratory, Southwest Jiaotong University, Chengdu, 610031 (China)], E-mail: asclab@asclab.cn

    2009-05-15

    In order to improve the performance of the present high temperature superconducting (HTS) maglev vehicle system, the maglev performance of single- and double-layer bulk high temperature superconductors (HTSC) was investigated above a permanent magnet guideway (PMG). It is found that the maglev performance of a double-layer bulk HTSC is not a simple addition of each layer's levitation and guidance force. Moreover, the applied magnetic field at the position of the upper layer bulk HTSC is not completely shielded by the lower layer bulk HTSC either. 53.5% of the levitation force and 27.5% of the guidance force of the upper layer bulk HTSC are excited in the double-layer bulk HTSC arrangement in the applied field-cooling condition and working gap, bringing a corresponding improvement of 16.9% and 8.8% to the conventional single-layer bulk HTSC. The present research implies that the cost performance of upper layer bulk HTSC is a little low for the whole HTS maglev system.

  1. High-temperature superconductors, as seen through the eyes of neutrons

    Directory of Open Access Journals (Sweden)

    Z. Yamani

    2006-09-01

    Full Text Available   Neutron scattering is proved to be a vital probe in unveiling the magnetic properties of high temperature superconductors (HTSC. Detailed information about the energy and momentum dependence of the magnetic dynamics of HTSC have been obtained directly by this technique. Over the past decade by improving the crystal growth methods, large and high quality single crystals of HTSC, which are essential for a neutron scattering experiment, have become available. The results of neutron scattering measurements on such crystals have considerably enhanced our understanding of the magnetism in HTSC both in the superconducting (SC and normal states. In this review, the neutron scattering results on two main HTSC families, La2-xSrxCuO4 (LSCOx and YBa2CuO3O6+x (YBCO6+x, are considered with an emphasis on the most prominent properties of these materials that are now widely accepted. These include the presence of strong antiferromagnetic (AF fluctuations even in optimally doped region of the phase diagram, neutron resonance peak that scales with SC transition temperature, Tc, incommensurate magnetic fluctuations (stripes, and a pseudogap in the normal state of underdoped materials.

  2. An exponential universal scaling law for the volume pinning force of high temperature superconductors

    International Nuclear Information System (INIS)

    Hampshire, D.P.

    1993-01-01

    The exponential magnetic field dependence of the critical current density (J c (B,T)) found in many high temperature superconductors, given by: J c (B,T) α(T)exp(-B/β(T)) where α(T) and β(T) are functions of temperature alone, necessarily implies a Universal Scaling Law for the volume pinning force (F p ) of the form: F p /F PMAX exp(+1).(B/β(T)).exp(-B/β(T)). If the Upper Critical Field is not explicitly measured but is artificially determined by smooth extrapolation of J c (B,T) to zero on a linear J c (B,T) vs B plot, this exponential scaling law can be closely approximated by the Kramer dependence given by: F p /F PMAX C.b p .(1-b) q where p = 0.5, q = 2, C ∼ 3.5 and b = B/B C2 (T). The implications for flux pinning studies are discussed. (orig.)

  3. High pressure study of high temperatures superconductors: Material base, universal Tc-behavior, and charge transfer

    International Nuclear Information System (INIS)

    Chu, C.W.; Hor, P.H.; Lin, J.G.; Xiong, Q.; Huang, Z.J.; Meng, R.L.; Xue, Y.Y.; Jean, Y.C.

    1991-01-01

    The superconducting transition temperature (T c ) has been measured in YBa 2 Cu 3 O 6.7 , YBa 2 Cu 3 O 7 , Y 2 Ba 4 Cu 7 O 15 , YBa 2 Cu 4 O 8 , Tl 2 Ba 2 Ca n-1 Cu n O n+4-δ , La 2-x Sr x CuO 4 , and La 2-x Ba x CuO 4 under high pressures. The pressure effect on the positron lifetime (τ) has also been determined in the first four compounds. Based on these and other high pressure data, the authors suggest that (1) all known cuprate high temperature superconductors (HTS's) may be no more than mere modifications of either 214-T, 214-T', 123, or a combination of 214-T' and 123, (2) a nonmonotonic T c -behavior may govern the T c -variation of all hole cuprate HTS's and (3) pressure can induce charge transfer leading to a T c -change. The implications of these suggestions will also be discussed

  4. First Results from Tests of High Temperature Superconductor Magnets on Tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Gryaznevich, M.; Todd, T.T., E-mail: mikhail.gryaznevich@ccfe.ac.uk [Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon (United Kingdom); Svoboda, V.; Markovic, T.; Ondrej, G. [Czech Technical University, Prague (Czech Republic); Stockel, J.; Duran, I.; Kovarik, K. [IPP Prague, Czech Technical University, Prague (Czech Republic); Sykes, A.; Kingham, D. [Tokamak Solutions, Culham Science Centre, Abingdon (United Kingdom); Melhem, Z.; Ball, S.; Chappell, S. [Oxford Instruments, Abingdon (United Kingdom); Lilley, M. K.; De Grouchy, P.; Kim, H. -T. [Imperial College, London (United Kingdom)

    2012-09-15

    Full text: It has long been known that high temperature superconductors (HTS) could have an important role to play in the future of tokamak fusion research. Here we report on first results of the use of HTS in a tokamak magnet and on the progress in design and construction of the first fully-HTS tokamak. In the experiment, the two copper vertical field coils of the small tokamak GOLEM were replaced by two coils each with 6 turns of HTS (Re)BCO tape. Liquid nitrogen was used to cool the coils to below the critical temperature at which HTS becomes superconducting. Little effect on the HTS critical current has been observed for perpendicular field up to 0.5 T and superconductivity has been achieved at {approx} 90.5K during bench tests. There had been concerns that the plasma pulses and pulsed magnetic fields might cause a 'quench' in the HTS, i.e., a sudden and potentially damaging transition from superconductor to normal conductor. However, many plasma pulses were fired without any quenches even when disruptions occurred with corresponding induced electrical fields. In addition, experiments without plasma have been performed to study properties of the HTS in a tokamak environment, i.e., critical current and its dependence on magnetic and electrical fields generated in a tokamak both in DC and pulsed operations, maximum current ramp-up speed, performance of the HTS tape after number of artificially induced quenches etc. No quench has been observed at DC currents up to 200 A (1.2 kA-turns through the coil). In short pulses, current up to 1 kA through the tape (6 kA-turns) has been achieved with no subsequent degradation of the HTS performance with a current ramp rate up to 0.6 MA/s. In future experiments, increases in both the plasma current and pulse duration are planned. Considerable experience has been gained during design and fabrication of the cryostat, coils, isolation and insulation, feeds and cryosystems, and GOLEM is now routinely operated with HTS coils. The

  5. Nanoscale strain-induced pair suppression as a vortex-pinning mechanism in high-temperature superconductors

    International Nuclear Information System (INIS)

    Llordes, Anna; Palau, A.; Gazquez, J.; Coll, M.; Vlad, R.; Pomar, A.; Arbiol, Jordi; Guzman, Roger; Ye, S.; Rouco, V.; Sandiumenge, Felip; Ricart, Susagna; Puig, Teresa; Varela del Arco, Maria; Chataigner, D.; Vanacken, J.; Gutierrez, J.; Moschalkov, V.; Deutscher, G.; Magen Dominguez, Cesar; Obradors, Xavier

    2012-01-01

    Boosting large-scale superconductor applications require nanostructured conductors with artificial pinning centres immobilizing quantized vortices at high temperature and magnetic fields. Here we demonstrate a highly effective mechanism of artificial pinning centers in solution-derived high-temperature superconductor nanocomposites through generation of nanostrained regions where Cooper pair formation is suppressed. The nanostrained regions identified from transmission electron microscopy devise a very high concentration of partial dislocations associated with intergrowths generated between the randomly oriented nanodots and the epitaxial YBa 2 Cu 3 O 7 matrix. Consequently, an outstanding vortex-pinning enhancement correlated to the nanostrain is demonstrated for four types of randomly oriented nanodot, and a unique evolution towards an isotropic vortex-pinning behaviour, even in the effective anisotropy, is achieved as the nanostrain turns isotropic. We suggest a new vortex-pinning mechanism based on the bond-contraction pairing model, where pair formation is quenched under tensile strain, forming new and effective core-pinning regions.

  6. Kiloampere, Variable-Temperature, Critical-Current Measurements of High-Field Superconductors.

    Science.gov (United States)

    Goodrich, L F; Cheggour, N; Stauffer, T C; Filla, B J; Lu, X F

    2013-01-01

    We review variable-temperature, transport critical-current (I c) measurements made on commercial superconductors over a range of critical currents from less than 0.1 A to about 1 kA. We have developed and used a number of systems to make these measurements over the last 15 years. Two exemplary variable-temperature systems with coil sample geometries will be described: a probe that is only variable-temperature and a probe that is variable-temperature and variable-strain. The most significant challenge for these measurements is temperature stability, since large amounts of heat can be generated by the flow of high current through the resistive sample fixture. Therefore, a significant portion of this review is focused on the reduction of temperature errors to less than ±0.05 K in such measurements. A key feature of our system is a pre-regulator that converts a flow of liquid helium to gas and heats the gas to a temperature close to the target sample temperature. The pre-regulator is not in close proximity to the sample and it is controlled independently of the sample temperature. This allows us to independently control the total cooling power, and thereby fine tune the sample cooling power at any sample temperature. The same general temperature-control philosophy is used in all of our variable-temperature systems, but the addition of another variable, such as strain, forces compromises in design and results in some differences in operation and protocol. These aspects are analyzed to assess the extent to which the protocols for our systems might be generalized to other systems at other laboratories. Our approach to variable-temperature measurements is also placed in the general context of measurement-system design, and the perceived advantages and disadvantages of design choices are presented. To verify the accuracy of the variable-temperature measurements, we compared critical-current values obtained on a specimen immersed in liquid helium ("liquid" or I c liq) at 5

  7. Microstructure and Dielectric Properties of LPCVD/CVI-SiBCN Ceramics Annealed at Different Temperatures

    Directory of Open Access Journals (Sweden)

    Jianping Li

    2017-06-01

    Full Text Available SiBCN ceramics were introduced into porous Si3N4 ceramics via a low-pressure chemical vapor deposition and infiltration (LPCVD/CVI technique, and then the composite ceramics were heat-treated from 1400 °C to 1700 °C in a N2 atmosphere. The effects of annealing temperatures on microstructure, phase evolution, dielectric properties of SiBCN ceramics were investigated. The results revealed that α-Si3N4 and free carbon were separated below 1700 °C, and then SiC grains formed in the SiBCN ceramic matrix after annealing at 1700 °C through a phase-reaction between free carbon and α-Si3N4. The average dielectric loss of composites increased from 0 to 0.03 due to the formation of dispersive SiC grains and the increase of grain boundaries.

  8. Characterization of high temperature superconductor cables for magnet toroidal field coils of the DEMO fusion power plant

    CERN Document Server

    Bayer, Christoph M

    2017-01-01

    Nuclear fusion is a key technology to satisfy the basic demand for electric energy sustainably. The official EUROfusion schedule foresees a first industrial DEMOnstration Fusion Power Plant for 2050. In this work several high temperature superconductor sub-size cables are investigated for their applicability in large scale DEMO toroidal field coils. Main focus lies on the electromechanical stability under the influence of high Lorentz forces at peak magnetic fields of up to 12 T.

  9. High-speed photography of laser ablation plasmas from the high temperature superconductor YBa2Cu3O7-δ

    International Nuclear Information System (INIS)

    Scott, K.; Huntley, J.M.; Phillips, W.A.

    1993-01-01

    The luminous plume formed by laser ablation of the high-temperature superconductor YBa 2 Cu 3 O 7-δ has been investigated using high-speed framing photography. Variation of the background oxygen pressure was found to significantly influence the velocity distribution of the ablated species, leading in particular to shock wave formation and instabilities on the shock front at higher pressures. Spectral characteristics of the plume were studied using optical interference filters, and two distinct regions of emission were identified. (orig.)

  10. Characterization of high temperature superconductor cables for magnet toroidal field coils of the DEMO fusion power plant

    Energy Technology Data Exchange (ETDEWEB)

    Bayer, Christoph M.

    2017-05-01

    Nuclear fusion is a key technology to satisfy the basic demand for electric energy sustainably. The official EUROfusion schedule foresees a first industrial DEMOnstration Fusion Power Plant for 2050. In this work several high temperature superconductor sub-size cables are investigated for their applicability in large scale DEMO toroidal field coils. Main focus lies on the electromechanical stability under the influence of high Lorentz forces at peak magnetic fields of up to 12 T.

  11. Crystallographic and electrical properties of Pr substituted Gd-123 nanometre sized high temperature superconductors

    International Nuclear Information System (INIS)

    Huse, V.R.; Mote, V.D.; Shah, S.S.; Dole, B.N.; Purushotham, Y.; Dhar, S.K.

    2011-01-01

    The samples of Gd 1-x Pr x Ba 2 Cu 3 O 7-δ with compositions x = 0.0, 0.1 and 0.3 were prepared by ceramic route. The XRD study of all samples is carried out. The XRD studies of the samples prepared by ceramic route show GdPr-123 system have an orthorhombic perovskite structure. The lattice parameters, oxygen content, volume of unit cell, orthorhombic perovskite structure. The lattice parameters, oxygen content, volume of unit cell, orthorhombic distortion, hole concentration in CuO 2 plane and charge on Cu-O plane were evaluated using XRD data. It is found that the lattice parameters, volume of unit cell increase while oxygen content orthorhombic distortion, hole concentration (Psh) and average charge (p) decrease as doping percentage of Pr increases. The resistivity measurement shows the transition temperature decreases while transition width increases with increasing Pr concentration. The suppression of superconductivity may be due to reduction in hole concentration or magnetic pair breaking. We report such qualitative results of Pr substituted Gd-123 in this paper quantitatively. (author)

  12. Abrasive wear of ceramic wear protection at ambient and high temperatures

    Science.gov (United States)

    Varga, M.; Adam, K.; Tumma, M.; Alessio, K. O.

    2017-05-01

    Ceramic wear protection is often applied in abrasive conditions due to their excellent wear resistance. This is especially necessary in heavy industries conveying large amounts of raw materials, e.g. in steel industry. Some plants also require material transport at high temperatures and velocities, making the need of temperature stable and abrasion resistant wear protection necessary. Various types and wear behaviour of ceramic protection are known. Hence, the goal of this study is to identify the best suitable ceramic materials for abrasive conditions in harsh environments at temperatures up to 950°C and severe thermal gradients. Chamottes, known for their excellent thermal shock resistance are compared to high abrasion resistant ceramic wear tiles and a cost efficient cement-bounded hard compound. Testing was done under high-stress three-body abrasion regime with a modified ASTM G65 apparatus enabling for investigations up to ~950°C. Thereto heated abrasive is introduced into the wear track and also preheated ceramic samples were used and compared to ambient temperature experiments. Results indicate a significant temperature influence on chamottes and the hard compound. While the chamottes benefit from temperature increase, the cement-bounded hard compound showed its limitation at abrasive temperatures of 950°C. The high abrasion resistant wear tiles represented the materials with the best wear resistance and less temperature influence in the investigated range.

  13. Ceramic Integration Technologies for Advanced Energy Systems: Critical Needs, Technical Challenges, and Opportunities

    Science.gov (United States)

    Singh, Mrityunjay

    2010-01-01

    Advanced ceramic integration technologies dramatically impact the energy landscape due to wide scale application of ceramics in all aspects of alternative energy production, storage, distribution, conservation, and efficiency. Examples include fuel cells, thermoelectrics, photovoltaics, gas turbine propulsion systems, distribution and transmission systems based on superconductors, nuclear power generation and waste disposal. Ceramic integration technologies play a key role in fabrication and manufacturing of large and complex shaped parts with multifunctional properties. However, the development of robust and reliable integrated systems with optimum performance requires the understanding of many thermochemical and thermomechanical factors, particularly for high temperature applications. In this presentation, various needs, challenges, and opportunities in design, fabrication, and testing of integrated similar (ceramic ceramic) and dissimilar (ceramic metal) material www.nasa.gov 45 ceramic-ceramic-systems have been discussed. Experimental results for bonding and integration of SiC based Micro-Electro-Mechanical-Systems (MEMS) LDI fuel injector and advanced ceramics and composites for gas turbine applications are presented.

  14. Possibility of the vortex-antivortex transition temperature of a thin-film superconductor being renormalized by disorder

    International Nuclear Information System (INIS)

    Hebard, A.F.; Kotliar, G.

    1989-01-01

    The universal relation between the Kosterlitz-Thouless transition temperature T/sub c/ and the superfluid sheet density of thin-film superconductors with mean-field transition temperature T/sub c/ 0 results in a monotonically decreasing dependence of the ratio T/sub c//T/sub c0/ on the normal-state sheet resistance R/sub n/. Ambiguity in the experimental definition of R/sub n/ in highly disordered thin-film superconductors is addressed by reexamining previously published data on amorphous composite In/InO/sub x/ films. Arguments are presented in favor of using the zero-temperature value of R/sub n/, a quantity obtained by extrapolation. The dependence of T/sub c//T/sub c0/ on R/sub n/ that results from such a choice is in agreement with theory for dirty superconductors and thus suggests that additional corrections to T/sub c/ in the presence of extreme disorder are not required

  15. The equilibrium magnetization of granular high temperature superconductors in low fields. Pt. 1

    International Nuclear Information System (INIS)

    Ruppel, S.; Michels, G.; Geus, H.; Kalenborn, J.; Schlabitz, W.; Wohlleben, D.

    1990-01-01

    We report the temperature and field dependence of the Meissner flux expulsion of sintered pellets of YBa 2 (Cu 1-x Fe x ) 3 O 7-y with 0≤x≤0.08. In all samples the flux expulsion remains incomplete (-4 πχ∼1/3) down to fields, which are much smaller than H c1 , but for H≤2 Oe they all finally exhibit a full Meissner effect and are therefore fully superconducting. The expulsion in 2 Oe decreases to near 30% by aging of the grain boundaries and goes back to near 100% after their reoxidation, all at a fixed and sharp T c of 93 K. The data are interpreted in terms of equilibrium properties of granular high temperature superconductors on the basis of an analysis, which is described in detail in the following paper. An average cross-section of the superconducting 'grains' in the CuO planes of 4 μm 2 is extracted from the temperature and field dependence of the spontaneous flux expulsion. These 'grains' lie within the much larger crystallographic grains and are bordered by planar defects. Superconducting loops around these planar defects are responsible for the final flux expulsion in H c can also be extracted from the data. One finds ΔT c ≤1 K in the orthorhombic phase (x ≤ 0.02), while in the quasitetragonal phase, ΔT c increases from 1 to 16 K for 0.02 < x ≤ 0.08. (orig.)

  16. Iron based superconductors and related compounds synthesized by solid state metathesis and high temperature reactions

    International Nuclear Information System (INIS)

    Frankovsky, Rainer

    2013-01-01

    The results of this thesis can be divided into three major topics, which can also be seen as different approaches of solid state chemistry to reveal interesting features of known and unknown compounds and to develop alternative synthesis routes. Firstly, known compounds with related structural motifs to the superconducting iron-arsenides were investigated regarding their structural and physical properties. In case of La 3 Pd 4 Ge 4 the influence of Fe doping on the properties was studied, whereas in the series ZrMAs (M=Ti,V) the physical properties have not yet been reported at all and were investigated for the first time. Secondly, an alternative synthesis route has been developed for the synthesis of superconducting LaFeAsO 1-x F x . This solid state metathesis reaction distinctly increased the quality of the samples compared to conventionally prepared products. Furthermore, the reaction pathway was investigated and clarified, which helps to understand the processes during high temperature solid state metathesis reactions in general. Thirdly, this alternative synthesis route was expanded to other systems and new compounds like co-substituted LaFe 1-x Mn x AsO 1-y F y were prepared and thoroughly investigated. This led to a complex study of the interplay of magnetism, electronic and structural conditions and the occurrence of superconducting properties. The investigation and understanding of such complex coherences will probably be decisive for the further understanding of the superconducting mechanism in iron based superconductors.

  17. Coasting characteristic of the flywheel system under anisotropy effect of bulk high temperature superconductors

    International Nuclear Information System (INIS)

    Wu, J.F.; Li, Y.

    2014-01-01

    Highlights: • Coasting time was investigated from the point-view of HTS flywheel applications. • The coasting time of aligned growth section boundary pattern (AGSBP) is shorter than that of MGSBP. • The electric magnetic drag force with AGSBP is larger than that of MGSBP. • This result may also exist in the maglev guideline when the maglev train stops freely. - Abstract: High-temperature superconductors (HTSCs) array with aligned growth section boundary (GSB) pattern (AGSBP) exhibits larger levitation force and suppression of levitation force decay above a permanent magnet guideway (PMG) compared with misaligned GSB pattern (MGSBP) has been studied in maglev train application (Zheng et al., 2013). This result maybe helpful and support a new way for the HTS bearing design for flywheel systems. So, in this paper, we further examine this growth anisotropy effect on the maglev performance of flywheel system. Levitation force and coasting time were investigated from the point-view of HTS flywheel applications. The GS/GSB alignment of AGSBP bulk HTSCs produces larger levitation force than that of MGSBP, but the coasting time is shorter than that of MGSBP, that is to say, the electric magnetic drag force with AGSBP is larger than that of MGSBP. This result may also exist in the maglev guideline when the maglev train stops freely

  18. Comparison study of cable geometries and superconducting tape layouts for high-temperature superconductor cables

    Science.gov (United States)

    Ta, Wurui; Shao, Tianchong; Gao, Yuanwen

    2018-04-01

    High-temperature superconductor (HTS) rare-earth-barium-copper-oxide (REBCO) tapes are very promising for use in high-current cables. The cable geometry and the layout of the superconducting tapes are directly related to the performance of the HTS cable. In this paper, we use numerical methods to perform a comparison study of multiple-stage twisted stacked-tape cable (TSTC) conductors to find better cable structures that can both improve the critical current and minimize the alternating current (AC) losses of the cable. The sub-cable geometry is designed to have a stair-step shape. Three superconducting tape layouts are chosen and their transport performance and AC losses are evaluated. The magnetic field and current density profiles of the cables are obtained. The results show that arrangement of the superconducting tapes from the interior towards the exterior of the cable based on their critical current values in descending order can enhance the cable's transport capacity while significantly reducing the AC losses. These results imply that cable transport capacity improvements can be achieved by arranging the superconducting tapes in a manner consistent with the electromagnetic field distribution. Through comparison of the critical currents and AC losses of four types of HTS cables, we determine the best structural choice among these cables.

  19. Test results of a 20 kA high temperature superconductor current lead using REBCO tapes

    Science.gov (United States)

    Heller, R.; Fietz, W. H.; Gröner, F.; Heiduk, M.; Hollik, M.; Lange, C.; Lietzow, R.

    2018-05-01

    The Karlsruhe Institute of Technology has developed a 20 kA high temperature superconductor (HTS) current lead (CL) using the second generation material REBCO, as industry worldwide concentrate on the production of this material. The aim was to demonstrate the possibility of replacing the Bi-2223/AgAu tapes by REBCO tapes, while for easy comparison of results, all other components are copies of the 20 kA HTS CL manufactured for the satellite tokamak JT-60SA. After the manufacture of all CL components including the newly developed REBCO module, the assembly of the CL has been executed at KIT and an experiment has been carried out in the CuLTKa test facility where the REBCO CL was installed and connected to a JT-60SA CL via a superconducting bus bar. The experiment covers steady state operation up to 20 kA, pulsed operation, measurement of the heat load at 4.5 K end, loss-of-flow-accident simulations, and quench performance studies. Here the results of these tests are reported and directly compared to those of the JT-60SA CL.

  20. A high temperature superconductor notch filter for the Sardinia Radio Telescope

    Science.gov (United States)

    Bolli, Pietro; Cresci, Luca; Huang, Frederick; Mariotti, Sergio; Panella, Dario

    2018-04-01

    A High Temperature Superconductor filter operating in the C-band between 4200 and 5600 MHz has been developed for one of the radio astronomical receivers of the Sardinia Radio Telescope. The motivation was to attenuate an interference from a weather radar at 5640 MHz, whose power level exceeds the linear region of the first active stages of the receiver. A very sharp transition after the nominal maximum passband frequency is reached by combining a 6th order band-pass filter with a 6th order stop-band. This solution is competitive with an alternative layout based on a cascaded triplet filter. Three units of the filter have been measured with two different calibration approaches to investigate pros and cons of each, and data repeatability. The final performance figures of the filters are: ohmic losses of the order of 0.15-0.25 dB, matching better than -15 dB, and -30 dB attenuation at 5640 MHz. Finally, a more accurate model of the connection between external connector and microstrip shows a better agreement between simulations and experimental data.

  1. Homopolar dc motor and trapped flux brushless dc motor using high temperature superconductor materials

    Science.gov (United States)

    Crapo, Alan D.; Lloyd, Jerry D.

    1991-03-01

    Two motors have been designed and built for use with high-temperature superconductor (HTSC) materials. They are a homopolar dc motor that uses HTSC field windings and a brushless dc motor that uses bulk HTSC materials to trap flux in steel rotor poles. The HTSC field windings of the homopolar dc motor are designed to operate at 1000 A/sq cm in a 0.010-T field. In order to maximize torque in the homopolar dc motor, an iron magnetic circuit with small air gaps gives maximum flux for minimum Ampere turns in the field. A copper field winding version of the homopolar dc motor has been tested while waiting for 575 A turn HTSC coils. The trapped flux brushless dc motor has been built and is ready to test melt textured bulk HTSC rings that are currently being prepared. The stator of the trapped flux motor will impress a magnetic field in the steel rotor poles with warm HTSC bulk rings. The rings are then cooled to 77 K to trap the flux in the rotor. The motor can then operate as a brushless dc motor.

  2. Coasting characteristic of the flywheel system under anisotropy effect of bulk high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Wu, J.F., E-mail: wujf@ciomp.ac.cn; Li, Y.

    2014-10-15

    Highlights: • Coasting time was investigated from the point-view of HTS flywheel applications. • The coasting time of aligned growth section boundary pattern (AGSBP) is shorter than that of MGSBP. • The electric magnetic drag force with AGSBP is larger than that of MGSBP. • This result may also exist in the maglev guideline when the maglev train stops freely. - Abstract: High-temperature superconductors (HTSCs) array with aligned growth section boundary (GSB) pattern (AGSBP) exhibits larger levitation force and suppression of levitation force decay above a permanent magnet guideway (PMG) compared with misaligned GSB pattern (MGSBP) has been studied in maglev train application (Zheng et al., 2013). This result maybe helpful and support a new way for the HTS bearing design for flywheel systems. So, in this paper, we further examine this growth anisotropy effect on the maglev performance of flywheel system. Levitation force and coasting time were investigated from the point-view of HTS flywheel applications. The GS/GSB alignment of AGSBP bulk HTSCs produces larger levitation force than that of MGSBP, but the coasting time is shorter than that of MGSBP, that is to say, the electric magnetic drag force with AGSBP is larger than that of MGSBP. This result may also exist in the maglev guideline when the maglev train stops freely.

  3. Field dependence of the current density of superconductors at high temperatures

    International Nuclear Information System (INIS)

    Hiergeist, R.; Hergt, R.; Erb, A.; Kummeth, P.; Winzer, K.

    1993-01-01

    An essential drawback of the high-T c superconductors (HTS) with respect to technical applications at liquid nitrogen temperature is the large degradation of their pinning properties in magnetic fields. For the field dependence of the volume pinning force often a high field tail due to thermally activated flux flow is observed. An exponential decay of the irreversible magnetization with increasing field was reported in the case of sintered material (YBCO) for the intergranular part of the magnetization while a power law decay was found for the intragranular part. Song et al. observed an exponential field dependence of the critical current density for proton-irradiated material which before irradiation showed a power law decay. Gladun et al. found an exponential decay for BSCCO-2223 tapes. The high field behaviour of BSCCO was shown to be governed by thermally activated flux creep with a logarithmic pinning barrier, which may result in an exponential decrease of the current with the external magnetic field, as argued recently by Ries et al. We will show in the present paper that the different HTS substance classes (YBCO, BSCCO, TBCCO) behave qualitatively in a similar way. (orig.)

  4. Critical-temperature inhomogeneities and resistivity rounding in copper oxide superconductors

    International Nuclear Information System (INIS)

    Maza, J.; Vidal, F.

    1991-01-01

    By using effective-medium approaches, we obtain the onset of the electrical-resistivity rounding, above the normal-superconducting transition, associated with inhomogeneities of the mean-field critical temperature T c0 at scales larger than the superconducting correlation length. These results are compared with available data in single-crystal and single-phase (to within 4%) polycrystalline YBa 2 Cu 3 O 7-δ samples. This comparison shows that the measured resistivity rounding cannot be explained by these types of local T c0 inhomogeneities. Complementarily, our calculations allow us to check some proposals on T c0 inhomogeneities associated with local sample strains or oxygen-content variations. The interplay between T c0 inhomogeneities and superconducting order-parameter fluctuations (SCOPF) leads to the conclusion that in the mean-field-like region (MFR) above the superconducting transition, the T c0 inhomogeneity contribution to the measured resistivity rounding in high-quality (single-phase) cuprate oxide superconductors is negligible. In contrast, our analysis confirms that in the MFR these effects may be explained quantitatively on the grounds of the Lawrence-Doniach theory for SCOPF

  5. High temperature superconductor based on thin strata reactively sputtered on metal targets. Final report

    International Nuclear Information System (INIS)

    Francke, C.; Meyer, B.; Wunderlich, R.; Mueller, J.

    1996-01-01

    SNS - Josephson contacts stable for a long period and dc SQUIDS working at 77 K were produced from the high temperature superconductor YBa 2 Cu 3 O 7-δ , where silver was used as the normal conductor. On MgO stages etched with ion beams, a defined section of the YBCO stratum can be produced and therefore a desired spacing can be set beteen the two YBCO electrodes. Structuring of the silver layer increases the normal conductive resistance of the Josephson contacts of the SQUIDs and therefore also the flux/voltage modulation stroke by up to 2 orders of mangitude. The dc SQUIDS in the so-called Ketchen design with 700 x 700 μm 2 square washers alone have a field sensitivity around 25 nT/Φ 0 . A multi-strata technology was developed from YBCO/STO/YBCO layer packages, which makes it possible to produce superconducting coils with corssovers and through contacts, which show critical currents of over 10 mA at 77 K. Using this multi-strata technology, flux transformers on 10 x 10 mm 2 STO substrates and on 20 x 20 mm 2 STO substrates were produced. Coupled to dc SQUIDs inductively in 'flip-chip' technique, such flux transformers supply a field sensitivity which is several times better than that of a flex transformer with a 10 x 10 mm 2 substrate. Field sensitivities around 0.2 nT/Φ 0 can be achieved. (orig./MM) [de

  6. Equivalent Coil Model for Computing Levitation Forces Between Permanent Magnets and High Temperatures Superconductors

    International Nuclear Information System (INIS)

    Cavia Santos, S.; Garcia-Tabares, L.

    1998-05-01

    A new simple theory has been developed for the study of levitation forces between a permanent magnet and a HTc superconductor. This theory is based on the assumption that both, the magnet and the superconductor, can be modelled by an equivalent coil placed on their surface. While the current flowing through the permanent magnet is constant, the equivalent current through the superconductor can be iether corresponding to screen the overall flux or a constant current corresponding to critical current density when the superconductor is saturated. A test facility has been designed and built for measuring levitation forces at variable approaching speeds. Comparison between theoretical and experimental measurements are presented in the report as well as a general description of the test facility. (Author)

  7. Design and manufacture of ceramic heat pipes for high temperature applications

    International Nuclear Information System (INIS)

    Meisel, Peter; Jobst, Matthias; Lippmann, Wolfgang; Hurtado, Antonio

    2015-01-01

    Heat exchangers based on ceramic heat pipes were designed for use under highly abrasive and corrosive atmospheres at temperatures in the range of 800–1200 °C for high-temperature power-engineering applications. The presented heat pipes are gravity assisted and based on a multi-layer concept comprising a ceramic cladding and an inner metal tube that contains sodium as the working fluid. Hermetical encapsulation of the working fluid was achieved by electron-beam welding of the inner metal tube. Subsequently, closure of the surrounding ceramic tube was performed by laser brazing technology using a glass solder. Temperature resistance and functionality of the manufactured ceramic thermosyphons could be confirmed experimentally in a hot combustion gas atmosphere at temperatures up to 1100 °C. The ceramic tubes used had an outer diameter of 22 mm and a total length of 770 mm. The measured axial heat transfer of the ceramic gravity assisted heat pipes at the stationary operating point with cold/hot gas temperature of 100 °C/900 °C was 400 W. The result of the calculation using the created mathematical model amounted to 459 W. - Highlights: • Heat-pipe design consists of a ceramic shell and an inner metallic tube. • Laser brazing technology is suitable to seal ceramic heat-pipes. • Thermal characteristic of double wall thermosyphon was modelled using FEM code. • Experimental investigations demonstrated functionality of double wall thermosyphons

  8. Temperature dependent dielectric relaxation and ac-conductivity of alkali niobate ceramics studied by impedance spectroscopy

    Science.gov (United States)

    Yadav, Abhinav; Mantry, Snigdha Paramita; Fahad, Mohd.; Sarun, P. M.

    2018-05-01

    Sodium niobate (NaNbO3) ceramics is prepared by conventional solid state reaction method at sintering temperature 1150 °C for 4 h. The structural information of the material has been investigated by X-ray diffraction (XRD) and Field emission scanning electron microscopy (FE-SEM). The XRD analysis of NaNbO3 ceramics shows an orthorhombic structure. The FE-SEM micrograph of NaNbO3 ceramics exhibit grains with grain sizes ranging between 1 μm to 5 μm. The surface coverage and average grain size of NaNbO3 ceramics are found to be 97.6 % and 2.5 μm, respectively. Frequency dependent electrical properties of NaNbO3 is investigated from room temperature to 500 °C in wide frequency range (100 Hz-5 MHz). Dielectric constant, ac-conductivity, impedance, modulus and Nyquist analysis are performed. The observed dielectric constant (1 kHz) at transition temperature (400 °C) are 975. From conductivity analysis, the estimated activation energy of NaNbO3 ceramics is 0.58 eV at 10 kHz. The result of Nyquist plot shows that the electrical behavior of NaNbO3 ceramics is contributed by grain and grain boundary responses. The impedance and modulus spectrum asserts that the negative temperature coefficient of resistance (NTCR) behavior and non-Debye type relaxation in NaNbO3.

  9. Fundamental studies of ceramic/metal interfacial reactions at elevated temperatures.

    Energy Technology Data Exchange (ETDEWEB)

    McDeavitt, S. M.; Billings, G. W.; Indacochea, J. E.

    2000-12-14

    This work characterizes the interfaces resulting from exposing oxide and non-oxide ceramic substrates to zirconium metal and stainless steel-zirconium containing alloys. The ceramic/metal systems together were preheated at about 600 C and then the temperatures were increased to the test maximum temperature, which exceeded 1800 C, in an atmosphere of high purity argon. Metal samples were placed onto ceramic substrates, and the system was heated to elevated temperatures past the melting point of the metallic specimen. After a short stay at the peak temperature, the system was cooled to room temperature and examined. The chemical changes across the interface and other microstructural developments were analyzed with energy dispersive spectroscopy (EDS). This paper reports on the condition of the interfaces in the different systems studied and describes possible mechanisms influencing the microstructure.

  10. Magnetic Signals of High-Temperature Superconductor Bulk During the Levitation Force Measurement Process

    Science.gov (United States)

    Huang, Huan; Zheng, Jun; Qian, Nan; Che, Tong; Zheng, Botian; Jin, Liwei; Deng, Zigang

    2017-05-01

    In order to study the commonly neglected magnetic field information in the course of levitation force measurement process in a superconducting maglev system, a multipoint magnetic field measurement platform was employed to acquire magnetic signals of a bulk high-Tc superconductor on both the top and the bottom surface. Working conditions including field cooling (FC) and zero field cooling were investigated for these vertical down and up motions above a permanent magnet guideway performed on a HTS maglev measurement system. We have discussed the magnetic flux variation process based on the Bean model. A magnetic hysteresis effect similar to the levitation force hysteresis loop of the bulk superconductor was displayed and analyzed in this paper. What is more valuable, there exists some available magnetic flux on the top surface of the bulk superconductor, and the proportion is as high as 62.42% in the FC condition, which provides an experimental hint to design the superconductor bulk and the applied field for practical use in a more efficient way. In particular, this work reveals real-time magnetic flux variation of the bulk superconductor in the levitation application, which is the other important information in contrast to the macroscopic levitation and guidance force investigations in previous studies, and it enriches the existing research methods. The results are significant for understanding the magnetic characteristic of superconductors, and they can contribute to optimize the present HTS maglev system design.

  11. Investigation of the thermophysical properties of oxide ceramic materials at liquid-helium temperatures

    International Nuclear Information System (INIS)

    Taranov, A. V.; Khazanov, E. N.

    2008-01-01

    The main regularities in the transport of thermal phonons in oxide ceramic materials are investigated at liquid-helium temperatures. The dependences of the thermophysical characteristics of ceramic materials on their structural parameters (such as the grain size R, the grain boundary thickness d, and the structure of grain boundaries) are analyzed. It is demonstrated that, in dense coarse-grained ceramic materials with qR>>1 (where q is the phonon wave vector), the grain boundaries and the grain size are the main factors responsible for the thermophysical characteristics of the material at liquid-helium temperatures. A comparative analysis of the thermophysical characteristics of optically transparent ceramic materials based on the Y 3 Al 5 O 12 (YAG) and Y 2 O 3 cubic oxides synthesized under different technological conditions is performed using the proposed criterion

  12. Thermal contact conductance of metallic coated BiCaSrCuO superconductor/copper interfaces at cryogenic temperatures

    International Nuclear Information System (INIS)

    Ochterbeck, J.M.; Peterson, G.P.; Fletcher, L.S.

    1992-01-01

    The effects of vapor deposited coatings on the thermal contact conductance of cold pressed, normal state BiCaSrCuO superconductor/oxygen-free copper interfaces were experimentally investigated over a pressure range of 200 to 2,000 kPa. Using traditional vapor deposition processes, thin coatings of indium or lead were applied to the superconductor material to determine the effect on the heat transfer occurring at the interface. The test data indicate that the contact conductance can be enhanced using these coatings, with indium providing the greater enhancement. The experimental program revealed the need for a better understanding and control of the vapor deposition process when using soft metallic coatings. Also, the temperature-dependent microhardness of copper was experimentally determined and found to increase by approximately 35 percent as the temperature decreased from 300 to 85 K. An empirical model was developed to predict the effect of soft coatings on the thermal contact conductance of the superconductor/copper interfaces. When applied, the model agreed well with the data obtained in this investigation at low coating thicknesses but overpredicted the data as the thickness increased. In addition, the model agreed very well with data obtained in a previous investigation for silvercoated nickel substrates at all coating thicknesses

  13. High temperature tribological properties of plasma-sprayed metallic coatings containing ceramic particles

    International Nuclear Information System (INIS)

    Dallaire, S.; Legoux, J.G.

    1995-01-01

    For sealing a moving metal component with a dense silica-based ceramic pre-heated at 800 C, coatings with a low coefficient of friction and moderate wear loss are required. As reported previously, plasma-sprayed coatings containing solid lubricants could reduce sliding wear in high-temperature applications. Plasma-sprayed metal-based coatings containing ceramic particles have been considered for high temperature sealing. Selected metal powders (NiCoCrAlY, CuNi, CuNiIn, Ag, Cu) and ceramic particles (boron nitride, Zeta-B ceramic) were agglomerated to form suitable spray powders. Plasma-sprayed composite coatings and reference materials were tested in a modified pin-on-disc apparatus in which the stationary disc consisted of a dense silica-based ceramic piece initially heated at 800 C and allowed to cool down during tests. The influence of single exposure and repeated contacts with a dense silica-based ceramic material pre-heated to 800 C on the coefficient of friction, wear loss and damage to the ceramic piece was evaluated. Being submitted to a single exposure at high temperature, coatings containing malleable metals such as indium, silver and copper performed well. The outstanding tribological characteristics of the copper-Zeta-B ceramic coating was attributed to the formation of a glazed layer on the surface of this coating which lasted over exposures to high temperature. This glazed layer, composed of fine oxidation products, provided a smooth and polished surface and helped maintaining the coefficient of friction low

  14. Clock-frequency and temperature margins of a high-temperature superconductor delay-line memory

    International Nuclear Information System (INIS)

    Hattori, W.; Tahara, S.

    1999-01-01

    We have developed a 10 GHz 32-bit delay-line memory, using a semiconductor crossbar switch and a YBa 2 Cu 3 O 7-δ coplanar delay line. For use in the high-speed (≥10 GHz) cell-buffer storage of large-throughput (≥1 Tbit/s) asynchronous transfer mode (ATM) switching systems, this memory must be fairly reliable. To evaluate the reliability of the operation, therefore, we measured the clock-frequency and temperature margins and the temperature dependence of the bit-error rate. At 64 K, this memory has a capacity of 32 bits with a clock frequency of 9.89±0.11 GHz. In general, clock frequencies of communication systems are strictly managed so that the margins are less than 10 -6 . Therefore, the frequency margin of this memory (∼2x10 -2 )) is wide enough for use in communication systems. The temperature margin was 71.5±4.3 K at 10 GHz and 33 bits. This memory offered error-free operation (BER -13 ) at 71.5 ±3.5 K. These temperature margins are wide enough to be controlled by a cryocooler. These results show that the memory offers reliability and that it can be applied to high-speed ATM cell-buffer storage. (author)

  15. Thermodynamic Critical Field and Superconducting Fluctuation of Vortices for High Temperature Cuprate Superconductor: La-214

    International Nuclear Information System (INIS)

    Yung Moo Huh

    2001-01-01

    Thermodynamics has been studied systematically for the high temperature cuprate superconductor La 2-x Sr x CuO 4-δ , La-214, in the entire superconductive region from strongly underdoped to strongly overdoped regimes. Magnetization studies with H(parallel)c have been made in order to investigate the changes in free energy of the system as the number of carriers is reduced. Above the superconducting transition temperature, the normal-state magnetization exhibits a two-dimensional Heisenberg antiferromagnetic behavior. Below T c , magnetization data are thermodynamically reversible over large portions of the H-T plane, so the free energy is well defined in these regions. As the Sr concentration is varied over the wide range from 0.060 (strongly underdoped) to 0.234 (strongly overdoped), the free energy change goes through a maximum at the optimum doped in a manner similar to the T c0 vs. x curve. The density of states, N(0), remains nearly constant in the overdoped and optimum doped regimes, taking a broad maximum around x = 0.188, and then drops abruptly towards zero in the underdoped regime. The La 2-x Sr x CuO 4 (La-214) system displays the fluctuating vortex behavior with the characteristic of either 2D or 3D fluctuations as indicated by clearly identifiable crossing points T* close to T c . The dimensional character of the fluctuations depends on both applied magnetic fields and the density of charge carriers. The dimensional crossover from 2D to 3D occurs in the strongly underdoped regime when the c-axis coherence distance ζ c becomes comparable to the spacing between adjacent CuO 2 layers s at sufficiently high magnetic fields near H c2

  16. Thermodynamic Critical Field and Superconducting Fluctuation of Vortices for High Temperature Cuprate Superconductor: La-214

    International Nuclear Information System (INIS)

    Finnemore, Douglas K.

    2001-01-01

    Thermodynamics has been studied systematically for the high temperature cuprate superconductor La 2-x Sr x CuO 4-δ , La-214, in the entire superconductive region from strongly underdoped to strongly overdoped regimes. Magnetization studies with H (parallel) c have been made in order to investigate the changes in free energy of the system as the number of carriers is reduced. Above the superconducting transition temperature, the normal-state magnetization exhibits a two-dimensional Heisenberg antiferromagnetic behavior. Below T c , magnetization data are thermodynamically reversible over large portions of the H-T plane, so the free energy is well defined in these regions. As the Sr concentration is varied over the wide range from 0.060 (strongly underdoped) to 0.234 (strongly overdoped), the free energy change goes through a maximum at the optimum doped in a manner similar to the T c0 vs. x curve. The density of states, N(0), remains nearly constant in the overdoped and optimum doped regimes, taking a broad maximum around x = 0.188, and then drops abruptly towards zero in the underdoped regime. The La 2-x Sr x CuO 4 (La-214) system displays the fluctuating vortex behavior with the characteristic of either 2D or 3D fluctuations as indicated by clearly identifiable crossing points T* close to T c . The dimensional character of the fluctuations depends on both applied magnetic fields and the density of charge carriers. The dimensional crossover from 2D to 3D occurs in the strongly underdoped regime when the c-axis coherence distance ξ c becomes comparable to the spacing between adjacent CuO 2 layers s at sufficiently high magnetic field near H c2

  17. Towards a 20 kA high temperature superconductor current lead module using REBCO tapes

    Science.gov (United States)

    Heller, R.; Bagrets, N.; Fietz, W. H.; Gröner, F.; Kienzler, A.; Lange, C.; Wolf, M. J.

    2018-01-01

    Most of the large fusion devices presently under construction or in operation consisting of superconducting magnets like EAST, Wendelstein 7-X (W7-X), JT-60SA, and ITER, use high temperature superconductor (HTS) current leads (CL) to reduce the cryogenic load and operational cost. In all cases, the 1st generation HTS material Bi-2223 is used which is embedded in a low-conductivity matrix of AgAu. In the meantime, industry worldwide concentrates on the production of the 2nd generation HTS REBCO material because of the better field performance in particular at higher temperature. As the new material can only be produced in a multilayer thin-film structure rather than as a multi-filamentary tape, the technology developed for Bi-2223-based current leads cannot be transferred directly to REBCO. Therefore, several laboratories are presently investigating the design of high current HTS current leads made of REBCO. Karlsruhe Institute of Technology is developing a 20 kA HTS current lead using brass-stabilized REBCO tapes—as a further development to the Bi-2223 design used in the JT-60SA current leads. The same copper heat exchanger module as in the 20 kA JT-60SA current lead will be used for simplicity, which will allow a comparison of the newly developed REBCO CL with the earlier produced and investigated CL for JT-60SA. The present paper discusses the design and accompanying test of single tape and stack REBCO mock-ups. Finally, the fabrication of the HTS module using REBCO stacks is described.

  18. Improving Erosion Resistance of Plasma-Sprayed Ceramic Coatings by Elevating the Deposition Temperature Based on the Critical Bonding Temperature

    Science.gov (United States)

    Yao, Shu-Wei; Yang, Guan-Jun; Li, Cheng-Xin; Li, Chang-Jiu

    2018-01-01

    Interlamellar bonding within plasma-sprayed coatings is one of the most important factors dominating the properties and performance of coatings. The interface bonding between lamellae significantly influences the erosion behavior of plasma-sprayed ceramic coatings. In this study, TiO2 and Al2O3 coatings with different microstructures were deposited at different deposition temperatures based on the critical bonding temperature concept. The erosion behavior of ceramic coatings was investigated. It was revealed that the coatings prepared at room temperature exhibit a typical lamellar structure with numerous unbonded interfaces, whereas the coatings deposited at the temperature above the critical bonding temperature present a dense structure with well-bonded interfaces. The erosion rate decreases sharply with the improvement of interlamellar bonding when the deposition temperature increases to the critical bonding temperature. In addition, the erosion mechanisms of ceramic coatings were examined. The unbonded interfaces in the conventional coatings act as pre-cracks accelerating the erosion of coatings. Thus, controlling interlamellar bonding formation based on the critical bonding temperature is an effective approach to improve the erosion resistance of plasma-sprayed ceramic coatings.

  19. Ternary superconductors

    International Nuclear Information System (INIS)

    Giorgi, A.L.

    1987-01-01

    Ternary superconductors constitute a class of superconducting compounds with exceptional properties such as high transition temperatures (≅ 15.2 K), extremely high critical fields (H c2 >60 Tesla), and the coexistence of superconductivity and long-range magnetic order. This has generated great interest in the scientific community and resulted in a large number of experimental and theoretical investigations in which many new ternary compounds have been discovered. A review of some of the properties of these ternary compounds is presented with particular emphasis on the ternary molybdenum chalcogenides and the ternary rare earth transition metal tetraborides. The effect of partial substitution of a second metal atom to form pseudoternary compounds is examined as well as some of the proposed correlations between the superconducting transition temperature and the structural and electronic properties of the ternary superconductors

  20. PREFACE: Special section featuring selected papers from the 3rd International Workshop on Numerical Modelling of High Temperature Superconductors Special section featuring selected papers from the 3rd International Workshop on Numerical Modelling of High Temperature Superconductors

    Science.gov (United States)

    Granados, Xavier; Sánchez, Àlvar; López-López, Josep

    2012-10-01

    The development of superconducting applications and superconducting engineering requires the support of consistent tools which can provide models for obtaining a good understanding of the behaviour of the systems and predict novel features. These models aim to compute the behaviour of the superconducting systems, design superconducting devices and systems, and understand and test the behavior of the superconducting parts. 50 years ago, in 1962, Charles Bean provided the superconducting community with a model efficient enough to allow the computation of the response of a superconductor to external magnetic fields and currents flowing through in an understandable way: the so called critical-state model. Since then, in addition to the pioneering critical-state approach, other tools have been devised for designing operative superconducting systems, allowing integration of the superconducting design in nearly standard electromagnetic computer-aided design systems by modelling the superconducting parts with consideration of time-dependent processes. In April 2012, Barcelona hosted the 3rd International Workshop on Numerical Modelling of High Temperature Superconductors (HTS), the third in a series of workshops started in Lausanne in 2010 and followed by Cambridge in 2011. The workshop reflected the state-of-the-art and the new initiatives of HTS modelling, considering mathematical, physical and technological aspects within a wide and interdisciplinary scope. Superconductor Science and Technology is now publishing a selection of papers from the workshop which have been selected for their high quality. The selection comprises seven papers covering mathematical, physical and technological topics which contribute to an improvement in the development of procedures, understanding of phenomena and development of applications. We hope that they provide a perspective on the relevance and growth that the modelling of HTS superconductors has achieved in the past 25 years.